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8606_Surry_SubtitleD_MSWLF_GW_FID1280524_20190208
Electronic Data - Email CD (data loaded: Yes / No fVG DEimm division of Waste Management - Solid Waste Doc/Event #: r r� r r o.. 1. a Forhr Notice: This form and any information attached to it are''Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instrueti®ns: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste IVlonitoring ®ata Subrnittal Information Name of entity submitting data (laboratory, consultant, facility owner): Municipal Engineering Services Co., PA Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Jonathan Pfohl E-mail: jpfohl@mesco.com Phone: NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or. iouu) October 20-24, 2006) Surry County Subtitle D Lined 237 Landfill Road 86-06 .1600 JOctober 18-19, 2018 MSWLF Mt. Airy, NC 27030 Environmental Status: (Check all that apply) Initial/Background Monitoring Q Detection Monitoring ® Assessment Monitoring � Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells Leachate monitoring data ❑ Surface water monitoring data Notification attached? Methane gas monitoring data Corrective action data (specify) Other(specify) No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 26 surface water standard or NC Solid Waste GAPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, 1 have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Steven R. Gandy, Ph.D., P.E. Senior Project Manager (919) 772-5393 Facility Repres ntativ Name (Pri ) Title (Area Code) Telephone Number (C p Affix NC Licensed/ Professional Geologist Seal Sig16 nature it 1 Date ®®'k®0®A� 181111 ® P.O. BOX 97, Garner, NC 27529 ® y.®®®� �!®.y ®;'� ® / Facility Representative Address = S� 90 C-0281 (per ®® NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 ®®®®mJ9 a Semi -Annual Water Quality Monitoring Report Prepared for Surry County Subtitle D Lined MSWLF Mt. Airy, North Carolina October 2018 Permit Number: 86-06 MESCO Project Number: G18025.0 MUNICIPAL ENGINEERING SERVICES COMPANY? P.A. 68 SHIPWASH DRIVE, GARNER, NC 27529 - PHONE: 919-772-5393 P.D. Box 349, BOONE, NC 28607 - PHONE: 828-262-1767 LICENSE NUMBER: C-0281 MUNICIPAL ENGINEERING 7n E� SERVICES COMPANY9 P.A. \ GARNER, NO AND B❑❑NE, NO February 5, 2019 Ms. Jaclynne Drummond Solid Waste Section (SWS) Division of Waste Management North Carolina Department of Environmental Quality (NCDEQ) 2090 US Highway 70 Swannanoa, NC 28778 Re: Semi -Annual Water Quality Monitoring Report Surry County Subtitle D Lined MSWLF, Phases 1 & 2 Permit No. 86-06 MESCO Project No. G18025.0 Sampling Date(s). October 18-19, 2018 and November 10, 2018 Dear Ms Drummond: Introduction On behalf of Surry County, Municipal Engineering Services Company, P.A. (MESCO) is pleased to present this Semi -Annual Water Quality Monitoring Report for an event performed at the Surry County Subtitle D Lined Municipal Solid Waste Landfill (MSWLF) in the fall of 2018. NCDEQ Solid Waste Rules 15A NCAC 13B.1632 requires that Surry County provide this report to the SWS on a semi-annual basis. This report documents the quality of the ground and surface waters during this monitoring event performed on October 18-19 and November 10, 2018. During this event several metals were detected in groundwater samples collected both upgradient and downgradient of the lined landfill. The detected metals are likely not attributed to landfill activities but rather originating from erosion of natural deposits. The lone volatile organic compound (VOC) detected above the NC 2L Standard continues to be vinyl chloride in sample MW-6R. Surface water samples did not contain constituents in levels above applicable 2B Standards. The leachate samples continue to contain a few contaminants but were in low concentrations relative to Standards and published values. Background The Surry County Subtitle D lined MSWLF, permit #86-06, is located at 237 Landfill Road, Mount Airy, Surry County, North Carolina. The site location topographic map is depicted in the attached Sheet 1. The lined MSWLF is comprised of contiguous Phases 1 & 2 which are treated as a single unit in this report. 68 Shipwash Drive * Garner, NC 27529 • ph: 919-772-5393 • fx: 919-772-1176 • www.mesco.com LICENSE NUMBER: C-0281 Water quality at this facility has been monitored at least semi-annually since 1998 with all historical data reviewed in support of this report. This event was performed in accordance with the NC SWS rules/regulations as promulgated in 15A NCAC 13B and as a condition of the permit to operate. Assessment monitoring (targeting Appendix H constituents) was initiated site -wide in response to detections above allowable Standards in the spring of 2016. Assessment monitoring will continue indefinitely which includes targeting Appendix II constituents annually at MW-2, MW-6R and MW-9 and monitoring for LFG at proximal LFG migration wells MGP-5 and MGP-12 quarterly. During this event supplemental samples from both background wells MW-1 (closed) and MW-1 (Lined) were tested in support of an Alternative Source Demonstration (ASD) for metals which is planned to be submitted to the NCDEQ as approved by the NC SWS (DIN:28729). As specified within 15A NCAC 1313.16320), the SWS Environmental Monitoring Report Form and SWS memorandums this report contains sampling procedures, field and laboratory results, groundwater and surface water characterization. Well construction summary table, field observations table, field parameter data table, sampling and analysis summary table, detections compared to Standards tables, a groundwater flow directions/rates table, potentiometric map, quality assurance/quality control data, and laboratory analytical data results are enclosed herein. MW-2 Area Investigations During this event MESCO investigated the area around MW-2 in an attempt to identify the source of low "j" qualified concentrations of VOCs detected in samples collected from MW-2. Evidence has never been found to suggest that the lagoon has ever overflowed. During this and the previous three events constituents were not detected in MW-2 above regulatory Standards. Supplemental surface water sample (SW-C), collected downgradient of MW-2 lacked detections. MW-6R Area Investigations During this event MESCO investigated the area around MW-6R in an attempt to identify the source of VOC detections. MW-6R is located in a ditch that previously conveyed stormwater originating from the lined landfill. During the construction of Phased 2 in 2009, stormwater originating near the landfill was rerouted so that it no longer flows adjacent to MW-6R. Landfill gas (LFG) was detected in shallow migration monitoring probe MGP-5, located less than 75 feet away from MW-6R during the past two quarterly events performed on August 28, 2018 and December 13, 2018. Active LFG extraction has been initiated at Lined Phase 1 which includes vacuum applied at the closest leachate collection system cleanout. Vinyl chloride was detected in sample MW-6R during this and the previous 10 events above the 2L Standard. There were no detections in groundwater sample MW-8 or surface water samples (SWN-2, SW-D) collected hydraulically downgradient of MW-6R. MW-9S Area Investigations MESCO investigated the area around MW-9S in an attempt to identify the source of VOC detections during previous events. MW-9S is located about 180 feet downgradient of the Phase 2 sump near a previous drainage feature. Low levels of chlorinated hydrocarbons have consistently been detected in samples collected from MW-9S since before waste was deposited in Phase 2. VOCs were not detected above Standards in sample MW-9S during this and the previous event. Interpretation of analytical data indicates that the adjacent deeper cluster well MW-9D remains unimpacted. LFG has never been detected from head -space of MW-9S or from adjacent migration probe MGP-12. VOCs have not been detected in supplemental samples previously collected from P-4 which is located hydraulically downgradient of MW-9S. 2 Sampling Procedure MESCO personnel performed this sampling event using portable monitoring methodology in general accordance with the site -specific Water Quality Monitoring Plan dated July 12, 2018 (DIN:1234484) which was approved by the NC SWS on August 8, 2018 (DIN:1235187). Water samples were collected from 14 downgradient groundwater monitoring wells (MW-2, MW-3R, MW-4S, MW-4D, MW-5, MW-6R, MW-8, MW-9S, MW-9D, MW-10, MW- 115, MW-11D, MW-12 and MW-13), one background well (MW-1), four downstream surface water locations (SW- 4 , SWN-2, SW-C and SW-D), four upstream surface water points (SWN-1, SW-1, SW-2 and SW-3) and a pre- treated leachate sample (LAGOON). Quality control measures included analysis of equipment blanks (EB) and field blanks (FB). MW-5 was resampled and tested for VOCs on November 10, 2018 since the original sample was lost. Sampling locations are shown on the potentiometric map (Sheet 2). A summary detailing the construction of the water monitoring wells is presented on Table 1. The function and integrity of all monitoring locations were visually evaluated and no deficiencies identified as documented on Table 2. The depth to water in each well was electronically gaged prior to purging to quantify the static water level elevation. Low -flow pumping methodology or bailing was utilized to adequately purge the wells to a minimum of three times the volume of standing water in the well or until dry. Surface water samples were collected from Stoney Creek discharge feature at previously designated locations. During well purging and surface water sample collection the required field parameters were recorded. The samples were then placed into laboratory -prepared, pre - preserved containers via a new disposable polyethylene bailer. Samples were collected, kept on ice, and transported to a NC -certified laboratory under proper C-O-C protocols within the specified hold times for each analysis. Field Parameter Data Stabilized field parameters were recorded during purging which included pH, specific conductance, temperature, methane gas and visual turbidity. A summary of the field parameter data is presented in Table 3 and the field sampling data sheet is enclosed in Appendix B. Laboratory Results Pace Analytical Services, Inc. (PACE) performed the laboratory analysis of the water and leachate samples. Groundwater and surface water samples were tested for constituents listed in 40 CFR 258 Appendix I and 1,4- dioxane. Sample MW-2 was also tested for phenol, a semi -volatile organic compound listed in 40 CFR 258 Appendix II, since it was detected during the previous semi-annual event. Groundwater samples were also tested for turbidity in support of an Alternative Source Demonstration (ASD) Addendum planned for 2020. Untreated leachate was tested for the specific parameters required by the SWS which includes VOCs, total metals, phosphorous, BOD, COD, sulfide and nitrate. A sampling and analysis table summarizing the locations, constituents and methods is presented as Table 4. Water samples were analyzed to the laboratory -established Method Detection Limits (MDL) and any value between the MDL and laboratory -established Reporting Detection Limit (RDL) is qualified by the laboratory as an estimated concentration hence qualified with a "J". Estimated concentrations are considered non -quantifiable and discretion should be made prior to making decisions based solely on an approximate value. Table 5 summarizes constituents detected in groundwater and QC samples compared to groundwater compliance standards which include SWS adopted Groundwater Protection Standards (GWP), SWS adopted Interim Maximum Allowable Concentrations (IMAC) and North Carolina Groundwater Standards (2L). Although not applicable for regulatory compliance purposes the detections are also compared to the Maximum Contaminant Level (MCL) commonly referenced as the K Federal "Drinking Water Standard". Table 6 lists the constituents detected in surface water samples compared to the North Carolina Surface Water Standards (2B) for a Class C water -body and the MCL. Table 7 presents detections of constituents and turbidity values of background samples compared to Standards which were obtained in support of a future ASD for inorganics. Quality Control Samples The only detection in a quality control blank was methylene chloride in both samples EB and FB. The laboratory flagged the detection as (C9) "common laboratory contaminant". The identified lab induced artifact contaminant is largely inconsequential as methylene chloride was not detected in any of the water samples. Groundwater Samples Detected Above Standards Metals Sample MW-9S contained quantifiable concentrations of total recoverable cobalt (1 17 uq/L) above the NC IMAC Standard (1 uq/L). Volatile Organic Compounds Vinyl chloride was detected in sample MW-6R at 1.6 uq/L which is above the NC 2L Standard 0.3 ug/L. The most recent concentration of vinyl chloride remains within it's own respective identified range (>0.15 ug/L-1.7 uq/L) which has always remained below the "Drinking Water Standard" 2.0 uq/L. Surface Water Samples Contaminants were not detected above established NC 2B Surface Water Standards in any of the surface water samples. Leachate Samples Raw leachate samples contained total recoverable cobalt and an estimated concentration of 1,2-dichloroethane above NC 2L groundwater Standards. Concentrations of contaminants in leachate remain low relative to values published from similar MSWLF's which is consistent with previous observations. Groundwater and Surface Water Characterization A potentiometric map of the uppermost aquifer constructed from groundwater elevation data recorded during this monitoring event is on Sheet 2. Groundwater flow rates and directions were calculated and are included in the hydrologic properties table (Table 8). Groundwater flow directions remain generally in a southerly direction towards the Ararat River with groundwater velocities calculated by modified Darcy's equation varied considerably due to the anisotropic geologic conditions. Streams located within the facility boundaries were observed to be of low volume and flow with low turbidity. 4 Findings The inorganic detections are not believed to have originated from an anthropogenic source rather a product of erosion of natural geologic deposits. An ASD which provides technical site specific facts and site specific analytical data including evaluations of interwell (background), intrawell (baseline), metals in leachate, dissolved compared to total metals and a discussion that substantiating evidence that the metals are not anthropogenic was not approved by the SWS. A revised time -line and workplan dated January 25, 2018 (DIN:28728) was approved by the NC SWS on January 30, 2018 (DIN: 28729). Turbidity and metal analysis is planned to be performed from a set of approved upgradient backgound wells over the next 2 years and results will be submitted within routine semi- annual water quality monitoring reports. An ASD addendum for metals is planned to be submitted in early 2020. Background well MW-1 contained levels of chromium, cobalt and vanadium above Standards. Since turbidity levels of background sample MW-1 were below 10 NTU the data may be used to statistically derive site -specific Standards in the forthcoming ASD addendum. Vinyl chloride has been detected above the 2L Standard in every sample collected from MW-6R over the past 13 events (6.5 years). Levels during this event were within the historically identified range. MW-6R is located approximately 100 feet downgradient of the Phase 2 liner and within the compliance boundary. The portion of the aquifer impacted is believed to be small as evidenced by lack of detections in MW-8 located along the downgradient flow path. The active LFG extraction system has recently been expanded proximal to MW-6R and is expected to operate indefinitely which may mitigate potential groundwater impacts. MW-2 and MW-9S have a history of VOC detections but none were above allowable Standards during this event. Phenol, an Appendix II SVOC, was not detected in sample MW-2. Interpretation of results of surface water samples collected along Stoney Creek and the Ararat River, including those instituted directly downgradient of MW-2 and MW-6R, continue to indicate the local discharge features remain unimpaired. Closing Semi-annual water quality and quarterly LFG monitoring will continue. Water quality monitoring will be performed in the spring of 2019. Construction of Phase 4, western horizontal expansion, is expected to be completed in 2019. If you have any questions or comments regarding this report, please contact us at (919) 772-5393 or by email at jpfohlkmesco.com or sgandy&mesco.com. Sincerely, MUNICIPAL ENGINEERING SERVICES CO., P.A. Jonathan Pfohl Environmental Specialist Enclosures cc: Mr. Don Mitchell Surry County Steven R. Gandy, Ph.D, P.E. Senior Project Manger 9 Sheets Topographic Map with Site Location Surry County Landfill, Mt. Airy fl 237 Landfill Road Mount Airy, NC 28621 Lat: 36-26-30.065 Long:-80-34-15.314 Northing:983356.18 Easting:1537885.48 0 Surry Co Property Line O Closed Unlined C&D Landfill O Closed Unlined Sanitary Landfill O Active Lined MSW Landfill SHEET 1 3W-2 r-T (1000'FURTHER UPSTREAM) � / I, I I /I II/,I/II(hI IIII I iII� IdIlISE vD �C�&\D�v OVER VER II CLOSED LOSED I � C MSW/11 UPPED RECEIVING C&D BEFORE JUNE 1, 2008 /hTOPPED RECEIVING MSW BY JAN. 1, 1999 \� IIIIII\ VA\ vvvvvvv ��v A AVAA \ � \ \ 1VI \ vvv vv \V \ \ \ \ \ l 1 I \ r NOW OR FORMERLY \\ - - �~ \\\\\\\ \ \\\ \\\\� I _ \\\\\\�\�\\ \ \\I \\0\\Q\\\\\\\\�\ \\�� OWNED BY BY SURRY \\ \\ \\\ \\ \1 JI l\\\ \ \\\\\\�\\ \\ \\\ \\\ � JOHNNY COX COUNTY I I r I /Ill(// /i _ `� // >) � � � \ �� - - � o � \\\\ � Il Ill/ I ✓ /���\\\ \ \� �\\ \\\ \\ �\\ ��\� \�\ ��-� ; � I I l 11 l/ 11/l// ll/ 11 lj - Ill//I I 1 l�/ll/ � l S� \ � -- ill llllllll(I �\\ll III �� �\\ \\�\ � _�%��/ ///�/ i��/�% J � �\ //� Il ) / 1 vvvvv���vvv�vv///llllll_ II IIII 11 I IJl/Ill, a I ��� a� /i�iiii// _vv ov v vv vvvv ��vvv �vvv�vv�v �i %/� Illllllll \ / /// II I v � �040 �\- \ /�/�i MW-1 OW4-22 _ . \ _ �M -2 - ////�i�/ii��-,1 PROPERTY LINE 1060 3 w- OW4-6 *_ -OW4-9/MW-28 -_ - - \\\�\\ �\ � /�l l ///l /ll//l//1 � l //�(I I 1 \\ \ � � \ � //i /�i/ / �� / // /// / / / I I ( IIII I 111 \1\ \ \ \I 1 I \I , ✓ �i� //i 1020 i /i / / /// //// / / ���� - _ �ii/i I - - / �\� J �_ I ( �- \\��\\\�✓ / //// /// /� \ \\ \ \� \_ \ \�\\� \\� 1010 00 ,990 A R 0 pFRTY N F \\ NOW OR FORMERLY OWNED vV A \\\ v v v��-� � BY SHAWNA SUMMERS ,- \ INACTIVE LINED PHASE1 PTO 12/1/98 r- Av� FUTURE LINED- 9so/STONEY CREEK v vvvvvvv vvv �ii i/i / ( /OW4-4/MW-27* PHASE 400�/ ?��- �� �- ✓I )1))> P1-- \� SW-4 l/ACTIVE LFG EXTRACTION ( III ll I / ��- \\\� IIII(\ \ I ACTIVE LINED � PHASE 2 23.43 2 �GWE= PTO 11/20/09 I— % I1 ) �- \\\\ LEGEND - -_ ---------------- ESTIMATED WASTE LIMITS UNLINED LANDFILL P-10* \ - -;_��� _ _ - - - - - _ = - / / l 111 \\ \� MW-12 �\\ \ * _= MGP-5 i / /// / / l �` (l ������ \ \\ GWE=945.37� ��� - _ - — _ _ - - ��/ / I\\ \ \ �/ //// / / //// / / WASTE LIMITS OF LINED LANDFILL /l/ /i - FACILITY OUTERMOST PROPERTY BOUNDARY \ �Sz_-- M'11\\\\ \\ \\\ \\ \\\11I\ IIIIIII II \ \ \ 250- TOPOGRAPHIC CONTOURS -EXISTING - * GWE-- 31.31_`., _ _ � /�� _ _ ��\ Vvv vvvv 1 / A\ \ \\ v v A \IIII 1 11 IIII \ \ V A- \\�� BMW-1_1S'_ MW-10 =_ MW-9S�AVA\ �A\ vim` _ // J I \�A ��1111\� IIVA \V V 11 III VAA \\ �A�/,�i RELATIVE GROUNDWATER COMPLIANCE BOUNDARY _= \\GWE=938.40_�_ , GWE=942.04 - % GWE=919.68 \ �� \ I I\\\\�\\� � \�W-6 \\\ / j am \fil nyI Chloride- 1.6 Ug/ A VA RAILROAD MGP_12 = _ A� /�� MW GWE=917.81 _��� GWE=909.86 — — — = V�\ SWN-2 II \\VA\\ \\ \\VA — i \ \ l ow OBSERVATION WELL -EXISTING -2 - \ S OVTHE RAI D' SW-D R \ M� MONITORING WELL - IN NETWORK LANDFILL GAS MONITORING WELL ROADS OWNED BY SURRY — STREAM/CREEK COUNTY A SURFACE WATER SAMPLING LOCATION 960 EQUIPOTENTIAL UPPERMOST GROUNDWATER CONTOURS (10-18-18 GWE = 941.66 GROUNDWATER POTENTIOMETRIC ELEVATION *MW- POTENTIOMETRIC ELEVATION NOT USED FOR CONTOURING GRAPHIC SCALE 200 0 100 200 400 800 ( IN FEET ) SHEET 2 ■ I1 M L9 Q N r, Z Lp N L� N W 0) 0) Q N cb W Z00 N Z zO Qz 2: a - o 00 f n o, a N 1..1 z N Ln L` . r, O L1 w w 0 N U w W m 2 L3 Z N U ZI Z J CE w Z Z w rn Q in w Z o Z w U a W � w ° M - J U L3 p Q) q ZQo rn m X a/ a m W = O En�0 rn a CL 00 Q Irl- V o a � O � � Imo' LLI L ° :�i UJI c/) Q LLI LL J CL > LL m _ O W Q SCALE: SEE SCALE BAR DATE: 0111812019 DRWN. BY: R. MOSS CHKD. BY: J.PFOHL PROJECT NUMBER G18025.0 DRAWING NO. SHEET NO. SHEET 2 1 OF 1 Tables Table 1 Groundwater Monitoring Well Construction Table October 18, 2018 Monitoring Well Date Installed Well Diameter Total Well Depth Top of Screen Depth Screen Length Geology of Screened Interval Top of Casing Elevation Ground Elevation Groundwater Elevation Depth to Water Latitude Longitude (inches) (ft bgs) (ft bgs) (ft) (ft amsl) (ft amsl) (ft amsl) (ft btoc) MW-1 8/14/98 2 68.5 53.5 15 Rock 1127.02 1124.23 1063.70 63.32 36.434494 -80.577989 MW-2 8/16/98 2 23.5 8.5 15 Rock 936.68 933.91 923.43 13.25 36.430833 -80.571161 MW-3R 12/2/98 2 20 5 15 Rock 930.00 928.15 925.46 4.54 36.430714 -80.571575 MW-4S 8/11/98 2 20 5 15 Saprolite 943.23 940.31 932.89 10.34 36.430853 -80.572400 MW-4D 8/11/98 2 45 35 10 Rock 942.80 940.31 932.71 10.09 36.430853 -80.572400 MW-5 8/18/98 2 47.5 32.5 15 Rock 977.93 971.57 933.70 44.23 36.430356 -80.572961 MW-6R 3/22/99 2 79 64 15 Fractured Rock 1004.75 1001.81 937.92 66.83 36.429958 -80.573508 MW-8 9/1/09 2 70.75 55.75 15 Fractured Rock 971.03 968.35 909.86 61.17 36.429283 -80.573453 MW-9S 6/16/06 2 42.28 27.28 15 Fractured Rock 952.83 949.75 919.68 33.15 36.429314 -80.574464 MW-9D 6/16/06 2 65.54 55.54 10 Competent Rock 952.47 949.49 917.81 34.66 36.429314 -80.574464 MW-10 6/16/06 2 47.13 27.13 20 Fractured Rock 970.24 967.35 942.04 28.20 36.429519 -80.575486 MW-11S 9/3/09 2 46.05 31.05 15 Competent Rock 969.09 965.95 938.40 30.69 36.430197 -80.577131 MW-11 D 9/3/09 2 65.31 55.31 10 Competent Rock 965.38 962.38 928.03 37.35 36.430197 -80.577131 MW-12 9/4/09 2 65 50 15 Competent Rock 996.66 993.71 945.37 51.29 36.429831 -80.576750 MW-13 9/3/09 2 36.31 21.31 15 Fractured Rock 983.13 979.83 957.12 26.01 36.430625 -80.578531 MLW-A 8/19/98 2 84 69 15 Competent Rock 1095.51 1092.51 1012.57 82.94 36.432881 -80.573539 P2-6S 6/7/06 2 66.38 51.38 15 Fractured Rock 1040.27 1037.36 NR NR 36.431019 -80.578025 P2-6D 6/7/06 2 93.98 83.98 10 Competent Rock 1040.65 1037.56 NR NR 36.431019 -80.578025 P2-11S 6/16/06 2 50.13 40.13 10 Competent Rock 1021.53 1018.40 NR NR 36.430197 -80.577131 P2-11 D 6/16/06 2 65.45 60.45 5 Competent Rock 1021.13 1018.73 NR NR 36.430197 -80.577131 P2-12 1 6/16/06 1 2 1 59.56 1 44.56 1 15 1 Competent Rock 1 986.61 1 983.54 1 NR NR 36.429831 -80.576750 NOTE: 1. Ground, datum and TOR elevations are in units of feet, well diameter are in units of inches. bgs = below ground surface amsl= above mean sea level btoc = below top of casing (PVC well casing) Surry County Subtitle D MSWLF Page 1 of 1 Table 2 Field Observations of Monitoring Locations October 18-19, 2018 Sample Location Viable Monitoring Location Lack of Any Evidence of Tampering Locked on Arrival & Departure Hinge/Hasp Operational Tagged or Labeled Concrete Surface Pad Appears Effective Comments MW-1 Yes Yes Yes Yes Yes Yes Background Well MW-2 Yes Yes Yes Yes Yes Yes MW-3R Yes Yes Yes Yes Yes Yes MW-4S Yes Yes Yes Yes Yes Yes Purge water moderately turbid MW-4D Yes Yes Yes Yes Yes Yes MW-5 Yes Yes Yes Yes Yes Yes Datum recently re -surveyed since repaired since last survey MW-6R Yes Yes Yes Yes Yes Yes County improved surface seal in September 2013 MW-8 Yes Yes Yes Yes Yes Yes Path choked off with vegeatation MW-9S Yes Yes Yes Yes Yes Yes MW-9D Yes Yes Yes Yes Yes Yes MW-10 Yes Yes Yes Yes Yes Yes MW-11S Yes Yes Yes Yes Yes Yes MW-11 D Yes Yes Yes Yes Yes Yes Very slow recharge MW-12 Yes Yes Yes Yes Yes Yes Slow recharge MW-13 Yes Yes Yes Yes Yes Yes SW-1 Yes - - - - - High gage height & flow SW-2 Yes - - - - - High gage height & flow SW-3 Yes - - - - - High gage height & flow SW N-1 Yes - - - - - High gage height & flow SW N-2 Yes - - - - - High gage height & flow SW N-3 No - - - - - Dry SWN-4 No - - - - - Dry. Always has been SW-C Yes - - - - - SW-D Yes - - - - - LAGOON Yes Yes Yes - - Yes Sample from invert which is typical MLW-A Yes Yes Yes Yes Yes Yes P2-6S Yes Yes Yes Yes Yes Yes abandoned 10/23/18 P2-6D Yes Yes Yes Yes Yes Yes abandoned 10/23/18 P2-11 S Not Observed P2-11 D Not Observed P2-12 Not Observed Any unusual field conditions, observations, or events: Dual lined leachate lagoon leak detection manhole observed to have water level below lagoon level. No evidence of liner leakage. Phase 2 has an earthen berm built w/in liner limits which may reduce any potential for overland flow from Phase 2. Paths leading to wells and around entire facility have been maintained by County. All are 4X4 accessible. Co performed well maintenance by pouring new concrete pads around several wells in the Fall of 2017. Surry County Subtitle D Lined MSWLF Page 1 of 1 Table 2 Field Observations of Monitoring Locations October 18, 2018 Sample Location Viable Monitoring Location Lack of Any Evidence of Tampering Locked on Arrival & Departure Hinge/Hasp Operational Tagged or Labeled Concrete Surface Pad Appears Effective Comments MW-1 Yes Yes Yes Yes Yes Yes Background Well MW-2 Yes Yes Yes Yes Yes Yes MW-3R Yes Yes Yes Yes Yes Yes MW-4S Yes Yes Yes Yes Yes Yes Purge water moderately turbid MW-4D Yes Yes Yes Yes Yes Yes MW-5 Yes Yes Yes Yes Yes Yes Datum recently re -surveyed since repaired since last survey MW-6R Yes Yes Yes Yes Yes Yes County improved surface seal in September 2013 MW-8 Yes Yes Yes Yes Yes Yes Path choked off with vegeatation MW-9S Yes Yes Yes Yes Yes Yes MW-9D Yes Yes Yes Yes Yes Yes MW-10 Yes Yes Yes Yes Yes Yes MW-11S Yes Yes Yes Yes Yes Yes MW-11 D Yes Yes Yes Yes Yes Yes Very slow recharge MW-12 Yes Yes Yes Yes Yes Yes Slow recharge MW-13 Yes Yes Yes Yes Yes Yes SW-1 Yes - - - - - High gage height & flow SW-2 Yes - - - - - High gage height & flow SW-3 Yes - - - - - High gage height & flow SW N-1 Yes - - - - - High gage height & flow SW N-2 Yes - - - - - High gage height & flow SW N-3 No - - - - - Dry SWN-4 No - - - - - Dry. Always has been SW-C Yes - - - - - SW-D Yes - - - - - LAGOON Yes Yes Yes - - Yes Sample from invert which is typical MLW-A Yes Yes Yes Yes Yes Yes P2-6S Yes Yes Yes Yes Yes Yes abandoned 10/23/18 P2-6D Yes Yes Yes Yes Yes Yes abandoned 10/23/18 P2-11 S Not Observed P2-11 D Not Observed P2-12 Not Observed Any unusual field conditions, observations, or events: Dual lined leachate lagoon leak detection manhole observed to have water level below lagoon level. No evidence of liner leakage. Phase 2 has an earthen berm built w/in liner limits which may reduce any potential for overland flow from Phase 2. Paths leading to wells and around entire facility have been maintained by County. All are 4X4 accessible. Co performed well maintenance by pouring new concrete pads around several wells in the Fall of 2017. Surry County Subtitle D Lined MSWLF Page 1 of 1 Table 3 Field Parameter Data Summary October 18-19, 2018 Parameter Depth to Water Water Elevation TOC Elevation Temp. pH Specific Conductance Methane Gas in Headspace Turbidity of Metals Sample Units ft (btoc) ft (amsl) ft (amsl) C SU umhos/cm (%/Vol) Visual MW-1 63.32 1063.70 1127.02 14.6 6.2 80 NR Clear MW-2 13.25 923.43 936.68 15.8 5.8 86 NR Clear MW-3R 4.54 925.46 930.00 16.3 6.1 308 NR Clear MW-4S 10.34 932.89 943.23 15.6 5.7 95 NR Slight MW-4D 10.09 932.71 942.80 14.8 6.1 123 NR Clear MW-5 44.23 933.70 977.93 14.1 5.8 119 0.0 Clear MW-6R 66.83 937.92 1004.75 14.9 5.6 192 NR Clear MW-8 61.17 909.86 971.03 14.4 6.3 133 NR Clear MW-9S 33.15 919.68 952.83 14.2 6.0 257 0.0 Clear MW-9D 34.66 917.81 952.47 14.6 7.2 523 0.0 Mod. MW-10 28.20 942.04 970.24 15.1 5.6 148 NR Slight MW-11S 30.69 938.40 969.09 14.2 6.0 96 NR Clear MW-11 D 37.35 928.03 965.38 14.1 7.4 1048 NR Slight MW-12 51.29 945.37 996.66 14.9 6.6 201 NR Clear MW-13 26.01 957.12 983.13 14.9 5.8 101 NR Clear MLW-A 82.94 1012.57 1095.51 NR NR NR NR NR Minimum 4.54 909.86 930.00 15.1 5.6 93 0.0 Clear Average 37.38 945.04 990.97 16.5 6.3 176 0.0 Slight Maximum 82.94 1063.70 1127.02 18.9 6.9 312 0.0 Mod. SW-1 - - - 9.9 6.3 86 - Clear SW-2 - - - 14.4 6.8 95 - Clear SW-3 - - - 9.9 6.6 348 - Clear SW-4 - - - 10.8 6.4 11 - Clear SWN-1 - - - 10.1 6.8 69 - Clear SWN-2 - - - 10.2 6.9 89 - Clear SW-C - - - 10.4 6.8 72 - Clear SW-D - - - 11.3 6.9 81 - Clear Minimum - - - 9.9 6.3 11 - Clear Average - - - 10.9 6.7 106 - Clear Maximum - - - 14.4 6.9 348 - Clear NR = No reading attempted btoc = Below top of casing amsl = Above mean sea level Surry County Subtitle D Lined MSWLF Page 1 of 1 Table 4 Sampling and Analysis Summary October 18-19, 2018 November 10, 2018 (MW-5 VOCs) Field App.I Other App.11 Parameter Leachate = a o U) a Q (D v �, ns ca m > � o (n g o a� ❑ m n `) m U E 0 0 ❑ m O o � o a) o 0 2 : 2 = 0 0 �- > H H H 0 H U I— Q cn n CL M U Z O 0 O o �' > o p C O O � O O O _ m ❑ N O O O O~ O O� It L6 N c) � (fl 0 O � L L CD (0 N N co QD_ < p Q Q N N iv N Q Q Q Q W W —W W W W W W (n (n W a a aJca JJ JtB Ja J IE LE L LLJ J JJJ J MW-1 x x x x x x x MW-2 x x x x x x x x MW-3R x x x x x x x MW-4S x x x x x x x MW-41D x x x x x x x MW-5 x x x x x x x MW-6R x x x x x x x MW-8 x x x x x x x MW-9S x x x x x x x MW-91D x x x x x x x MW-10 x x x x x x x MW-11 S x x x x x x x MW-11 D x x x x x x x MW-12 x x x x x x x MW-13 x x x x x x x SWN-1 x x x x x x x SWN-2 x x x x x x x SW-1 x x x x x x x SW-2 x x x x x x x SW-3 x x x x x x x SW-4 x x x x x x x SW-C x x x x x x SW-D x x x x x x LAGOON x x x x x x x x x x EB x x x FB x x TB Appendix I & II = Lists from current 40 CFR 258 Surry County Subtitle D Lined MSWLF Page 1 of 1 Table 5 Groundwater, Leachate and QC Sample Detections October 18 & 19, 2018 November 10, 2018 (MW-5 VOCs) Parameter Name MDL 2L/GWP/IMAC MCL MW-1 MW-2 MW-3R MW-4S MW-4D MW-5 MW-6R MW-8 MW-9S MW-9D MW-10 MW-11S MW-11D MW-12 MW-13 LAGOON EB FB STANDARD BG S S S S I S S S S S S S S S S S QC QC Metals (Appendix 1) Barium, total 2.5 700 2000 9.9 J 37.6 J 49.9 J 49.3 J 45 J 80.3 71.7 J 68.3 102 48.1 J 33.3 J 21.1 J 3.7 J 9.8 J 16.7 J 220 -- Cadmium, total 0.5 2 5 0.51 J 0.97 J 0.53 J 2 0.83 0.76 J 1.1 0.63 J 0.71 J -- Chromium, total 2.5 10 100 2.9 J -- Cobalt, total 2.5 1 NE 117 (N) 14.8 -- Copper, total 2.5 1000 1300 3.5 J -- Lead, total 2.5 15 15 3 J 5.2 J -- Nickel, total 2.5 100 NE 3.4 J 2.7 J 2.8 J 10.3 J 6.5 J 3.6 J -- Thallium, total 0.02 0.28 2 0.03 J 0.035 0.11 0.062 J 0.29 J (N) 0.021 J 0.064 -- Vanadium, total 2.5 0.3 NE 3.3 J -- Zinc, total 5 1000 NE 8.8 J 5.7 J 6.6 J 8.8 J 7.2 J 5.1 J 5.1 J -- VOCs (Appendix I 1,1-Dichloroethane 0.32 6 NE 2.3 J 1.5 J 1,2-Dichloroethane 0.24 0.4 5 0.62 J 1,4-Dichlorobenzene 0.33 6 75 2.1 Benzene 0.25 1 5 0.88 J 0.84 J 0.95 J 0.36 J Chlorobenzene 0.23 50 100 0.34 J cis-1,2-Dichloroethene 0.19 70 70 1.6 J 2.2 J 0.95 3.8 J 4.3 J 0.93 J 1.2 J 0.44 J Methylene Chloride 0.97 5 5 1.2 3 3.1 Tetrachloroethene 0.46 0.7 5 0.59 J 0.6 J trans- 1,2-Dichloroethene 0.49 100 100 0.97 J 0.68 J 0.68 J Trichloroethene 0.47 3 5 0.5 J 0.59 J Vinyl chloride 0.62 0.03 2 1 1 1 1.6 (L) Leachate Parameters COD 12500 NE NE -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 128000 -- -- pH 0.1 6.5-8.5 NE -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 6 -- -- Phosphorus 25 NE NE -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 31.9 J -- -- Sulfate 500 250000 NE -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 3580 J -- -- Turbidity Measured in Lab Turbidity (NTU) 0.5 NE NE 1 1 5.1 10.78 J I -- I 1 1 1.9 16.3 2.6 5.1 3.6 0.61 J 0.56 J 53.6 -- -- Units ug/L, Blank cells means Not Detected above MDL, -- means not tested Red Bold Above Established 2L/GWP/IMAC NC Groundwater compliance standard. Above Established Federal MCL Drinking Water Std. No regulatory compliance significance. MDL = Method Detection Limit 2L = NC groundwater water standards per 15A NCAC 02L .0202. IMAC = (Interim Maximum Allowable Concentrations) - Interim NC groundwater standards per 15A NCAC 02L .0202. GWP= Groundwater Standard value calculated by NC DEQ for constituents with no established 2L standard. Values are calculated using criteria 1 & 2 of the NC Groundwater standards and do not consider taste, odor, MCLs, MCLG, and secondary drinking water Standards. J = "J-qualified". Estimated concentration above the adjusted MDL and below the adjusted reporting limit (N) Preliminary source is believed to be Natural originating from erosion of natural deposits. Source not anthropogenic. (L) Prelilminary source is believed to be anthropogenic with leachate or landfill gas as transport mechanism A definitive source of the detections was not determined as part of this report. BG = Background Well Sample, QC = Quality Control Sample, S = Sentinal Well Sample Surry County Lined MSWLF, Mt. Airy Page 1 of 1 Table 6 Surface Water Sample Detections October 18 & 19, 2018 Parameter Name MDL 2" MCL SWN-1 SW-D SW-4 SWN-2 STANDARD Upstream Downstream Downstream Downstream Metals (Appendix 1) Barium, total 2.5 200000 1 2000 1 16.1 J 17 J 16 J VOCs (Appendix 1) cis-1 2-Dichloroethene 0.19 720 1 70 1 1 1.2 J Units ug/L, Blank cells means Not Detected, -- means not tested, NE means Not Established Red Bold Above Established 26 Standard Regulatory compliance Standard for Class C Waterbody Above Established Federal MCL Drinking Water Std. No regulatory compliance significance. MDL = Method Detection Limit 2B = NC Surface Water water standards per 15A NCAC 02B .0202. J = "J-qualified". Estimated concentration above the adjusted MDL and below the adjusted reporting limit. Downstream = Sample collected downstream of landfill Upstream = Sample collected upstream of landfill Surry County Lined MSWLF, Mt. Airy Page 1 of 1 Table 7 Groundwater Sample Detections (Background) Designated Background Wells and those Approved by NC SWS* to Establish Background Conditions at the Site October 18, 2018 Parameter Name MDL 2L/GWP/IMAC STANDARD MCL MW-1 (Closed) MW-1 (Lined) Metals (Appendix 1) Barium, total 2.5 700 2000 101 9.9 J Cadmium, total 0.5 2 5 3.7 0.51 J Chromium, total 2.5 10 100 3.6 J Cobalt, total 2.5 1 NE 7.3 J Copper, total 2.5 1000 1300 6.6 J Lead, total 2.5 15 15 3.1 J Nickel, total 2.5 100 NE 9.1 J 3.4 J Vanadium, total 2.5 0.3 NE 3.7 J Thallium, total 0.02 0.28 2 0.11 J 0.03 J Zinc, total 5 1000 NE 46.4 8.8 J VOCs (Appendix 1) Cis- 1,2-Dichloroethene 0.19 70 70 0.44 J Turbidity (Measured in Lab) Turbidity 0.5 NE NE <0.5 1 Units ug/L, Blank cells means Not Detected, -- means not tested Red Bold Above Established 2L/GWP/IMAC Std. Regulatory compliance Standard Above Established MCL Drinking Water Std. No regulatory compliance significance. MDL = Method Detection Limit, 2L = NC 2L Groundater Standard, GWP=Groundwater Protection Standard, IMAC=Interim Maximum Allowable Concentration, 2L, GWP & IMAC adopted by NC SWS. MCL = Maximum Contaminant Level Federal Standard for Drinking Water J = "J-qualified". Estimated concentration above the adjusted MDL and below the adjusted reporting limit. * = NC SWS Approved that data from wells MW-1 (Closed), MW-1 (Lined) and 22 other "OW42 wells may be used in support of an ASD for inorganics (DIN:28729) Surry County Landfill -Mt. Airy Page 1 of 1 Table 8 Hydrogeologic Prpoperties at Monitoring Locations October 18, 2018 Monitoring Location Hydraulic Conductivity (cm/sec) Effective porosity Hydraulic Gradient Flow Rate Flow Direction Depth to Groundwater Groundwater Potentiometric Elevation Screened Interval Lithology (cm/second) (%) (feet/feet) (feetlyear) (feet btoc) (feet amsl) MW-1 2.45E-04 3 0.154 1,304 N53E 63.32 1063.70 Rock MW-2 3.20E-04 3 0.066 732 S11 E 13.25 923.43 Rock MW-3R 3.20E-04 3 0.042 460 S18E 4.54 925.46 Rock MW-4S 1.50E-04 3 0.093 485 S23E 10.34 932.89 Sandy Silt & Fractured Rock MW-4D 1.59E-04 3 - - - 10.09 932.71 Rock MW-5 3.20E-04 3 0.110 1,213 S53E 43.70 933.70 Rock MW-6R 3.20E-04 3 0.110 1,213 S27E 66.83 937.92 Fractured Rock MW-8 1.08E-03 3 0.111 4,151 S01N 61.17 909.86 Fractured Rock MW-9S 7.45E-04 3 0.105 2,705 S23E 33.15 919.68 Fractured Rock MW-9D 1.07E-05 3 - - - 34.66 917.81 Competent Rock MW-10 1.43E-04 3 0.093 457 S02E 28.20 942.04 Fractured Rock MW-11S 6.19E-05 3 0.100 213 S13W 30.69 938.40 Competent Rock MW-11 D na 3 - - - 37.35 931.31 Competent Rock MW-12 1.91 E-06 3 0.127 8 S25W 51.29 945.37 Competent Rock MW-13 2.71E-03 3 0.130 12,138 S35W 26.01 957.12 Fractured Rock P2-12 5.91 E-07 3 0.000 - na na na Competent Rock MLW-A na 3 0.038 - N82E 82.94 1012.57 Competent Rock Minimum 5.91E-07 3 0.000 8 - 4.54 909.86 Average 4.39E-04 3 0.091 1,176 - 37.35 945.25 Maximum 2.71E-03 3 0.154 4,151 - 82.94 1063.70 NOTE: Hydraulic conductivity and effective porosity values derived from slug tests performed by MESCO. Hydrologic gradient from water levels recorded on October 18, 2018. Flow rate for MW-13 was considered an outlier; therefore not included in the average or maximum. Flow rate (Q) is defined by modified Darcy's equation: where K A Q ne dl K = hydraulic conductivity n e = effective porosity dh = head difference dl = horizontal distance Surry County Subtitle D Lined MSWLF Page 1 of 1 Appendix A Laboratory Analysis Reports Chains of Custody lacieAnalXical" www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 November 05, 2018 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on October 19, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Trey Carter trey. carter@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Maddie German, Municipal Engineering Services REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Lab ID Sample ID Matrix Date Collected Date Received 92404173001 MW-1 Water 10/18/18 17:36 10/19/18 07:22 92404173002 MW-2 Water 10/18/18 09:31 10/19/18 07:22 92404173003 MW-3R Water 10/18/18 09:22 10/19/18 07:22 92404173004 MW-4S Water 10/18/18 09:14 10/19/18 07:22 92404173005 MW-41) Water 10/18/18 09:12 10/19/18 07:22 92404173006 MW-5 Water 10/18/18 16:08 10/19/18 07:22 92404173007 MW-6R Water 10/18/18 16:06 10/19/18 07:22 92404173008 MW-8 Water 10/18/18 09:06 10/19/18 07:22 92404173009 MW-9S Water 10/18/18 08:59 10/19/18 07:22 92404173010 MW-913 Water 10/18/18 08:57 10/19/18 07:22 92404173011 MW-10 Water 10/18/18 08:55 10/19/18 07:22 92404173012 MW-11S Water 10/18/18 08:47 10/19/18 07:22 92404173013 MW-11D Water 10/18/18 08:45 10/19/18 07:22 92404173014 MW-12 Water 10/18/18 15:55 10/19/18 07:22 92404173015 MW-13 Water 10/18/18 16:00 10/19/18 07:22 92404173016 SW-D Water 10/18/18 00:00 10/19/18 07:22 92404173017 LAGOON Water 10/18/18 17:00 10/19/18 07:22 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Surry. Co. Lined MSWLF 92404173 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92404173001 MW-1 EPA 601 OD SER 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E GAW 51 PASI-C EPA 180.1 Rev 2.0 1993 RLO 1 PASI-A 92404173002 MW-2 EPA 601 OD SER 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8270D PKS 4 PASI-C EPA 8260E GAW 51 PASI-C EPA 180.1 Rev 2.0 1993 RLO 1 PASI-A 92404173003 MW-3R EPA 601 OD SER 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E GAW 51 PASI-C EPA 180.1 Rev 2.0 1993 RLO 1 PASI-A 92404173004 MW-4S EPA 601 OD SER 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E GAW 51 PASI-C EPA 180.1 Rev 2.0 1993 RLO 1 PASI-A 92404173005 MW-41) EPA 601 OD SER 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E GAW 51 PASI-C EPA 180.1 Rev 2.0 1993 RLO 1 PASI-A 92404173006 MW-5 EPA 601 OD SER 14 PASI-A EPA 6020E SER 1 PASI-A 92404173007 MW-6R EPA 601 OD SER 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E GAW 51 PASI-C EPA 180.1 Rev 2.0 1993 RLO 1 PASI-A 92404173008 MW-8 EPA 601 OD SER 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E GAW 51 PASI-C EPA 180.1 Rev 2.0 1993 RLO 1 PASI-A 92404173009 MW-9S EPA 601 OD SER 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E GAW 51 PASI-C EPA 180.1 Rev 2.0 1993 RLO 1 PASI-A 92404173010 MW-91) EPA 601 OD SER 14 PASI-A EPA 6020E SER 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 8260E GAW 51 PASI-C EPA 180.1 Rev 2.0 1993 RLO 1 PASI-A 92404173011 MW-10 EPA 601 OD SER 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E GAW 51 PASI-C EPA 180.1 Rev 2.0 1993 RLO 1 PASI-A 92404173012 MW-11S EPA 601OD SER 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E GAW 51 PASI-C EPA 180.1 Rev 2.0 1993 RLO 1 PASI-A 92404173013 MW-11D EPA 601OD SER 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E GAW 51 PASI-C EPA 180.1 Rev 2.0 1993 RLO 1 PASI-A 92404173014 MW-12 EPA 601 OD SER 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E GAW 51 PASI-C EPA 180.1 Rev 2.0 1993 RLO 1 PASI-A 92404173015 MW-13 EPA 601 OD SER 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E GAW 51 PASI-C EPA 180.1 Rev 2.0 1993 RLO 1 PASI-A 92404173016 SW-D EPA 8260E GAW 51 PASI-C 92404173017 LAGOON EPA 601 OD SER 15 PASI-A EPA 6020E SER 1 PASI-A EPA7470A JMW1 1 PASI-A EPA 8260E GAW 51 PASI-C EPA 180.1 Rev 2.0 1993 RLO 1 PASI-A SM 521OB-2011 RLO 1 PASI-A EPA 9040C SMK 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A SM 5220D-2011 GC 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-1 Lab ID: 92404173001 Collected: 10/18/18 17:36 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 11/05/2018 04:52 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 10/20/18 04:57 10/22/18 05:43 7440-36-0 ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 05:43 7440-38-2 9.9 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 05:43 7440-39-3 ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 05:43 7440-41-7 0.51J ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 05:43 7440-43-9 ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 05:43 7440-47-3 ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 05:43 7440-48-4 ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 05:43 7440-50-8 ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 05:43 7439-92-1 3.4J ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 05:43 7440-02-0 ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 05:43 7782-49-2 ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 05:43 7440-22-4 ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 05:43 7440-62-2 8.8J ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 05:43 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A 0.030J ug/L 0.10 0.020 1 10/20/18 02:45 10/25/18 01:11 7440-28-0 Analytical Method: EPA 8260E ND ug/L 25.0 10.0 1 10/30/18 20:38 67-64-1 ND ug/L 10.0 1.9 1 10/30/18 20:38 107-13-1 ND ug/L 1.0 0.25 1 10/30/18 20:38 71-43-2 ND ug/L 1.0 0.17 1 10/30/18 20:38 74-97-5 ND ug/L 1.0 0.18 1 10/30/18 20:38 75-27-4 ND ug/L 1.0 0.26 1 10/30/18 20:38 75-25-2 ND ug/L 2.0 0.29 1 10/30/18 20:38 74-83-9 ND ug/L 5.0 0.96 1 10/30/18 20:38 78-93-3 ND ug/L 2.0 1.2 1 10/30/18 20:38 75-15-0 ND ug/L 1.0 0.25 1 10/30/18 20:38 56-23-5 ND ug/L 1.0 0.23 1 10/30/18 20:38 108-90-7 ND ug/L 1.0 0.54 1 10/30/18 20:38 75-00-3 ND ug/L 1.0 0.14 1 10/30/18 20:38 67-66-3 ND ug/L 1.0 0.11 1 10/30/18 20:38 74-87-3 ND ug/L 2.0 2.0 1 10/30/18 20:38 96-12-8 ND ug/L 1.0 0.21 1 10/30/18 20:38 124-48-1 ND ug/L 1.0 0.27 1 10/30/18 20:38 106-93-4 ND ug/L 1.0 0.21 1 10/30/18 20:38 74-95-3 ND ug/L 1.0 0.30 1 10/30/18 20:38 95-50-1 ND ug/L 1.0 0.33 1 10/30/18 20:38 106-46-7 ND ug/L 1.0 1.0 1 10/30/18 20:38 110-57-6 ND ug/L 1.0 0.32 1 10/30/18 20:38 75-34-3 ND ug/L 1.0 0.24 1 10/30/18 20:38 107-06-2 ND ug/L 1.0 0.56 1 10/30/18 20:38 75-35-4 ND ug/L 1.0 0.19 1 10/30/18 20:38 156-59-2 ND ug/L 1.0 0.49 1 10/30/18 20:38 156-60-5 ND ug/L 1.0 0.27 1 10/30/18 20:38 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-1 Lab ID: 92404173001 Collected: 10/18/18 17:36 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 180.1 Turbidity Turbidity Date: 11/05/2018 04:52 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.13 1 10/30/18 20:38 10061-01-5 ND ug/L 1.0 0.26 1 10/30/18 20:38 10061-02-6 ND ug/L 150 78.4 1 10/30/18 20:38 123-91-1 ND ug/L 1.0 0.30 1 10/30/18 20:38 100-41-4 ND ug/L 5.0 0.46 1 10/30/18 20:38 591-78-6 ND ug/L 5.0 0.32 1 10/30/18 20:38 74-88-4 ND ug/L 1.0 0.97 1 10/30/18 20:38 75-09-2 ND ug/L 5.0 0.33 1 10/30/18 20:38 108-10-1 ND ug/L 1.0 0.26 1 10/30/18 20:38 100-42-5 ND ug/L 1.0 0.33 1 10/30/18 20:38 630-20-6 ND ug/L 1.0 0.40 1 10/30/18 20:38 79-34-5 ND ug/L 1.0 0.46 1 10/30/18 20:38 127-18-4 ND ug/L 1.0 0.26 1 10/30/18 20:38 108-88-3 ND ug/L 1.0 0.48 1 10/30/18 20:38 71-55-6 ND ug/L 1.0 0.29 1 10/30/18 20:38 79-00-5 ND ug/L 1.0 0.47 1 10/30/18 20:38 79-01-6 ND ug/L 1.0 0.20 1 10/30/18 20:38 75-69-4 ND ug/L 1.0 0.41 1 10/30/18 20:38 96-18-4 ND ug/L 2.0 0.35 1 10/30/18 20:38 108-05-4 ND ug/L 1.0 0.62 1 10/30/18 20:38 75-01-4 ND ug/L 1.0 0.66 1 10/30/18 20:38 1330-20-7 98 % 70-130 1 10/30/18 20:38 460-00-4 86 % 70-130 1 10/30/18 20:38 17060-07-0 98 % 70-130 1 10/30/18 20:38 2037-26-5 Analytical Method: EPA 180.1 Rev 2.0 1993 1.0 NTU 1.0 0.50 1 10/20/18 04:14 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-2 Lab ID: 92404173002 Collected: 10/18/18 09:31 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 1400111�41:49191:261.9 Thallium 8270 RVE Phenol Surrogates Phenol-d6 (S) 2-Fluorophenol (S) 2,4,6-Tribromophenol (S) 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 11/05/2018 04:52 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 10/20/18 04:57 10/22/18 06:01 7440-36-0 ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:01 7440-38-2 37.6 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:01 7440-39-3 ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:01 7440-41-7 0.97J ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:01 7440-43-9 ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:01 7440-47-3 ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:01 7440-48-4 ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:01 7440-50-8 ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:01 7439-92-1 ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:01 7440-02-0 ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:01 7782-49-2 ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:01 7440-22-4 ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:01 7440-62-2 ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:01 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.020 1 10/20/18 02:45 10/25/18 01:21 7440-28-0 Analytical Method: EPA 8270D Preparation Method: EPA 3510C ND ug/L 10.0 2.7 1 10/22/18 15:25 10/24/18 01:45 108-95-2 45 % 18-105 1 10/22/18 15:25 10/24/18 01:45 13127-88-3 53 % 13-118 1 10/22/18 15:25 10/24/18 01:45 367-12-4 63 % 31-170 1 10/22/18 15:25 10/24/18 01:45 118-79-6 Analytical Method: EPA 8260E ND ug/L 25.0 10.0 1 10/30/18 20:55 67-64-1 ND ug/L 10.0 1.9 1 10/30/18 20:55 107-13-1 ND ug/L 1.0 0.25 1 10/30/18 20:55 71-43-2 ND ug/L 1.0 0.17 1 10/30/18 20:55 74-97-5 ND ug/L 1.0 0.18 1 10/30/18 20:55 75-27-4 ND ug/L 1.0 0.26 1 10/30/18 20:55 75-25-2 ND ug/L 2.0 0.29 1 10/30/18 20:55 74-83-9 ND ug/L 5.0 0.96 1 10/30/18 20:55 78-93-3 ND ug/L 2.0 1.2 1 10/30/18 20:55 75-15-0 ND ug/L 1.0 0.25 1 10/30/18 20:55 56-23-5 ND ug/L 1.0 0.23 1 10/30/18 20:55 108-90-7 ND ug/L 1.0 0.54 1 10/30/18 20:55 75-00-3 ND ug/L 1.0 0.14 1 10/30/18 20:55 67-66-3 ND ug/L 1.0 0.11 1 10/30/18 20:55 74-87-3 ND ug/L 2.0 2.0 1 10/30/18 20:55 96-12-8 ND ug/L 1.0 0.21 1 10/30/18 20:55 124-48-1 ND ug/L 1.0 0.27 1 10/30/18 20:55 106-93-4 ND ug/L 1.0 0.21 1 10/30/18 20:55 74-95-3 ND ug/L 1.0 0.30 1 10/30/18 20:55 95-50-1 ND ug/L 1.0 0.33 1 10/30/18 20:55 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-2 Lab ID: 92404173002 Collected: 10/18/18 09:31 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 180.1 Turbidity Turbidity Date: 11/05/2018 04:52 PM Analytical Method: EPA 8260E ND ug/L 1.0 1.0 1 10/30/18 20:55 110-57-6 2.3 ug/L 1.0 0.32 1 10/30/18 20:55 75-34-3 ND ug/L 1.0 0.24 1 10/30/18 20:55 107-06-2 ND ug/L 1.0 0.56 1 10/30/18 20:55 75-35-4 1.6 ug/L 1.0 0.19 1 10/30/18 20:55 156-59-2 ND ug/L 1.0 0.49 1 10/30/18 20:55 156-60-5 ND ug/L 1.0 0.27 1 10/30/18 20:55 78-87-5 ND ug/L 1.0 0.13 1 10/30/18 20:55 10061-01-5 ND ug/L 1.0 0.26 1 10/30/18 20:55 10061-02-6 ND ug/L 150 78.4 1 10/30/18 20:55 123-91-1 ND ug/L 1.0 0.30 1 10/30/18 20:55 100-41-4 ND ug/L 5.0 0.46 1 10/30/18 20:55 591-78-6 ND ug/L 5.0 0.32 1 10/30/18 20:55 74-88-4 ND ug/L 1.0 0.97 1 10/30/18 20:55 75-09-2 ND ug/L 5.0 0.33 1 10/30/18 20:55 108-10-1 ND ug/L 1.0 0.26 1 10/30/18 20:55 100-42-5 ND ug/L 1.0 0.33 1 10/30/18 20:55 630-20-6 ND ug/L 1.0 0.40 1 10/30/18 20:55 79-34-5 0.59J ug/L 1.0 0.46 1 10/30/18 20:55 127-18-4 ND ug/L 1.0 0.26 1 10/30/18 20:55 108-88-3 ND ug/L 1.0 0.48 1 10/30/18 20:55 71-55-6 ND ug/L 1.0 0.29 1 10/30/18 20:55 79-00-5 ND ug/L 1.0 0.47 1 10/30/18 20:55 79-01-6 ND ug/L 1.0 0.20 1 10/30/18 20:55 75-69-4 ND ug/L 1.0 0.41 1 10/30/18 20:55 96-18-4 ND ug/L 2.0 0.35 1 10/30/18 20:55 108-05-4 ND ug/L 1.0 0.62 1 10/30/18 20:55 75-01-4 ND ug/L 1.0 0.66 1 10/30/18 20:55 1330-20-7 98 % 70-130 1 10/30/18 20:55 460-00-4 84 % 70-130 1 10/30/18 20:55 17060-07-0 96 % 70-130 1 10/30/18 20:55 2037-26-5 Analytical Method: EPA 180.1 Rev 2.0 1993 ND NTU 1.0 0.50 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 10/20/18 02:04 Page 9 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-3R Lab ID: 92404173003 Collected: 10/18/18 09:22 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 10/20/18 04:57 10/22/18 06:04 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:04 7440-38-2 Barium 49.9 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:04 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:04 7440-41-7 Cadmium 0.53J ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:04 7440-43-9 Chromium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:04 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:04 7440-48-4 Copper ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:04 7440-50-8 Lead ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:04 7439-92-1 Nickel 2.7J ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:04 7440-02-0 Selenium ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:04 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:04 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:04 7440-62-2 Zinc ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:04 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.020 1 10/20/18 02:45 10/25/18 01:24 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 10/30/18 21:12 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 10/30/18 21:12 107-13-1 Benzene ND ug/L 1.0 0.25 1 10/30/18 21:12 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 10/30/18 21:12 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 10/30/18 21:12 75-27-4 Bromoform ND ug/L 1.0 0.26 1 10/30/18 21:12 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 10/30/18 21:12 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 10/30/18 21:12 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 10/30/18 21:12 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 10/30/18 21:12 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 10/30/18 21:12 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 10/30/18 21:12 75-00-3 Chloroform ND ug/L 1.0 0.14 1 10/30/18 21:12 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 10/30/18 21:12 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 10/30/18 21:12 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 10/30/18 21:12 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/30/18 21:12 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 10/30/18 21:12 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 10/30/18 21:12 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 10/30/18 21:12 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 10/30/18 21:12 110-57-6 1,1-Dichloroethane 1.5 ug/L 1.0 0.32 1 10/30/18 21:12 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 10/30/18 21:12 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 10/30/18 21:12 75-35-4 cis-1,2-Dichloroethene 2.2 ug/L 1.0 0.19 1 10/30/18 21:12 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 10/30/18 21:12 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 10/30/18 21:12 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-3R Lab ID: 92404173003 Collected: 10/18/18 09:22 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 180.1 Turbidity Turbidity Date: 11/05/2018 04:52 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.13 1 10/30/18 21:12 10061-01-5 ND ug/L 1.0 0.26 1 10/30/18 21:12 10061-02-6 ND ug/L 150 78.4 1 10/30/18 21:12 123-91-1 ND ug/L 1.0 0.30 1 10/30/18 21:12 100-41-4 ND ug/L 5.0 0.46 1 10/30/18 21:12 591-78-6 ND ug/L 5.0 0.32 1 10/30/18 21:12 74-88-4 1.2 ug/L 1.0 0.97 1 10/30/18 21:12 75-09-2 ND ug/L 5.0 0.33 1 10/30/18 21:12 108-10-1 ND ug/L 1.0 0.26 1 10/30/18 21:12 100-42-5 ND ug/L 1.0 0.33 1 10/30/18 21:12 630-20-6 ND ug/L 1.0 0.40 1 10/30/18 21:12 79-34-5 ND ug/L 1.0 0.46 1 10/30/18 21:12 127-18-4 ND ug/L 1.0 0.26 1 10/30/18 21:12 108-88-3 ND ug/L 1.0 0.48 1 10/30/18 21:12 71-55-6 ND ug/L 1.0 0.29 1 10/30/18 21:12 79-00-5 ND ug/L 1.0 0.47 1 10/30/18 21:12 79-01-6 ND ug/L 1.0 0.20 1 10/30/18 21:12 75-69-4 ND ug/L 1.0 0.41 1 10/30/18 21:12 96-18-4 ND ug/L 2.0 0.35 1 10/30/18 21:12 108-05-4 ND ug/L 1.0 0.62 1 10/30/18 21:12 75-01-4 ND ug/L 1.0 0.66 1 10/30/18 21:12 1330-20-7 99 % 70-130 1 10/30/18 21:12 460-00-4 85 % 70-130 1 10/30/18 21:12 17060-07-0 97 % 70-130 1 10/30/18 21:12 2037-26-5 Analytical Method: EPA 180.1 Rev 2.0 1993 1.0 NTU 1.0 0.50 1 10/20/18 02:03 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-4S Lab ID: 92404173004 Collected: 10/18/18 09:14 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 10/20/18 04:57 10/22/18 06:07 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:07 7440-38-2 Barium 49.3 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:07 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:07 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:07 7440-43-9 Chromium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:07 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:07 7440-48-4 Copper ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:07 7440-50-8 Lead ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:07 7439-92-1 Nickel ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:07 7440-02-0 Selenium ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:07 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:07 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:07 7440-62-2 Zinc 5.7J ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:07 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium 0.035J ug/L 0.10 0.020 1 10/20/18 02:45 10/25/18 01:27 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 10/30/18 21:29 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 10/30/18 21:29 107-13-1 Benzene ND ug/L 1.0 0.25 1 10/30/18 21:29 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 10/30/18 21:29 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 10/30/18 21:29 75-27-4 Bromoform ND ug/L 1.0 0.26 1 10/30/18 21:29 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 10/30/18 21:29 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 10/30/18 21:29 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 10/30/18 21:29 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 10/30/18 21:29 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 10/30/18 21:29 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 10/30/18 21:29 75-00-3 Chloroform ND ug/L 1.0 0.14 1 10/30/18 21:29 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 10/30/18 21:29 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 10/30/18 21:29 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 10/30/18 21:29 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/30/18 21:29 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 10/30/18 21:29 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 10/30/18 21:29 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 10/30/18 21:29 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 10/30/18 21:29 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 10/30/18 21:29 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 10/30/18 21:29 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 10/30/18 21:29 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 10/30/18 21:29 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 10/30/18 21:29 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 10/30/18 21:29 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-4S Lab ID: 92404173004 Collected: 10/18/18 09:14 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 180.1 Turbidity Turbidity Date: 11/05/2018 04:52 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.13 1 10/30/18 21:29 10061-01-5 ND ug/L 1.0 0.26 1 10/30/18 21:29 10061-02-6 ND ug/L 150 78.4 1 10/30/18 21:29 123-91-1 ND ug/L 1.0 0.30 1 10/30/18 21:29 100-41-4 ND ug/L 5.0 0.46 1 10/30/18 21:29 591-78-6 ND ug/L 5.0 0.32 1 10/30/18 21:29 74-88-4 ND ug/L 1.0 0.97 1 10/30/18 21:29 75-09-2 ND ug/L 5.0 0.33 1 10/30/18 21:29 108-10-1 ND ug/L 1.0 0.26 1 10/30/18 21:29 100-42-5 ND ug/L 1.0 0.33 1 10/30/18 21:29 630-20-6 ND ug/L 1.0 0.40 1 10/30/18 21:29 79-34-5 ND ug/L 1.0 0.46 1 10/30/18 21:29 127-18-4 ND ug/L 1.0 0.26 1 10/30/18 21:29 108-88-3 ND ug/L 1.0 0.48 1 10/30/18 21:29 71-55-6 ND ug/L 1.0 0.29 1 10/30/18 21:29 79-00-5 ND ug/L 1.0 0.47 1 10/30/18 21:29 79-01-6 ND ug/L 1.0 0.20 1 10/30/18 21:29 75-69-4 ND ug/L 1.0 0.41 1 10/30/18 21:29 96-18-4 ND ug/L 2.0 0.35 1 10/30/18 21:29 108-05-4 ND ug/L 1.0 0.62 1 10/30/18 21:29 75-01-4 ND ug/L 1.0 0.66 1 10/30/18 21:29 1330-20-7 99 % 70-130 1 10/30/18 21:29 460-00-4 85 % 70-130 1 10/30/18 21:29 17060-07-0 97 % 70-130 1 10/30/18 21:29 2037-26-5 Analytical Method: EPA 180.1 Rev 2.0 1993 5.1 NTU 1.0 0.50 1 10/20/18 02:02 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-41) Lab ID: 92404173005 Collected: 10/18/18 09:12 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 10/20/18 04:57 10/22/18 06:10 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:10 7440-38-2 Barium 45.0 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:10 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:10 7440-41-7 Cadmium 2.0 ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:10 7440-43-9 Chromium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:10 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:10 7440-48-4 Copper ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:10 7440-50-8 Lead ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:10 7439-92-1 Nickel ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:10 7440-02-0 Selenium ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:10 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:10 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:10 7440-62-2 Zinc 6.6J ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:10 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.020 1 10/20/18 02:45 10/25/18 01:29 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 10/30/18 22:03 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 10/30/18 22:03 107-13-1 Benzene ND ug/L 1.0 0.25 1 10/30/18 22:03 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 10/30/18 22:03 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 10/30/18 22:03 75-27-4 Bromoform ND ug/L 1.0 0.26 1 10/30/18 22:03 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 10/30/18 22:03 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 10/30/18 22:03 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 10/30/18 22:03 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 10/30/18 22:03 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 10/30/18 22:03 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 10/30/18 22:03 75-00-3 Chloroform ND ug/L 1.0 0.14 1 10/30/18 22:03 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 10/30/18 22:03 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 10/30/18 22:03 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 10/30/18 22:03 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/30/18 22:03 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 10/30/18 22:03 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 10/30/18 22:03 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 10/30/18 22:03 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 10/30/18 22:03 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 10/30/18 22:03 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 10/30/18 22:03 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 10/30/18 22:03 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 10/30/18 22:03 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 10/30/18 22:03 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 10/30/18 22:03 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-41) Lab ID: 92404173005 Collected: 10/18/18 09:12 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 180.1 Turbidity Turbidity Date: 11/05/2018 04:52 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.13 1 10/30/18 22:03 10061-01-5 ND ug/L 1.0 0.26 1 10/30/18 22:03 10061-02-6 ND ug/L 150 78.4 1 10/30/18 22:03 123-91-1 ND ug/L 1.0 0.30 1 10/30/18 22:03 100-41-4 ND ug/L 5.0 0.46 1 10/30/18 22:03 591-78-6 ND ug/L 5.0 0.32 1 10/30/18 22:03 74-88-4 ND ug/L 1.0 0.97 1 10/30/18 22:03 75-09-2 ND ug/L 5.0 0.33 1 10/30/18 22:03 108-10-1 ND ug/L 1.0 0.26 1 10/30/18 22:03 100-42-5 ND ug/L 1.0 0.33 1 10/30/18 22:03 630-20-6 ND ug/L 1.0 0.40 1 10/30/18 22:03 79-34-5 ND ug/L 1.0 0.46 1 10/30/18 22:03 127-18-4 ND ug/L 1.0 0.26 1 10/30/18 22:03 108-88-3 ND ug/L 1.0 0.48 1 10/30/18 22:03 71-55-6 ND ug/L 1.0 0.29 1 10/30/18 22:03 79-00-5 ND ug/L 1.0 0.47 1 10/30/18 22:03 79-01-6 ND ug/L 1.0 0.20 1 10/30/18 22:03 75-69-4 ND ug/L 1.0 0.41 1 10/30/18 22:03 96-18-4 ND ug/L 2.0 0.35 1 10/30/18 22:03 108-05-4 ND ug/L 1.0 0.62 1 10/30/18 22:03 75-01-4 ND ug/L 1.0 0.66 1 10/30/18 22:03 1330-20-7 100 % 70-130 1 10/30/18 22:03 460-00-4 83 % 70-130 1 10/30/18 22:03 17060-07-0 97 % 70-130 1 10/30/18 22:03 2037-26-5 Analytical Method: EPA 180.1 Rev 2.0 1993 0.78J NTU 1.0 0.50 1 10/20/18 02:01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-5 Lab ID: 92404173006 Collected: 10/18/18 16:08 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 10/20/18 04:57 10/22/18 06:13 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:13 7440-38-2 Barium 80.3 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:13 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:13 7440-41-7 Cadmium 0.83J ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:13 7440-43-9 Chromium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:13 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:13 7440-48-4 Copper ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:13 7440-50-8 Lead ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:13 7439-92-1 Nickel ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:13 7440-02-0 Selenium ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:13 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:13 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:13 7440-62-2 Zinc ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:13 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium 0.11 ug/L 0.10 0.020 1 10/20/18 02:45 10/25/18 01:37 7440-28-0 Date: 11/05/2018 04:52 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-6R Lab ID: 92404173007 Collected: 10/18/18 16:06 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 10/20/18 04:57 10/22/18 06:16 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:16 7440-38-2 Barium 71.7 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:16 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:16 7440-41-7 Cadmium 0.76J ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:16 7440-43-9 Chromium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:16 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:16 7440-48-4 Copper ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:16 7440-50-8 Lead ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:16 7439-92-1 Nickel 2.8J ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:16 7440-02-0 Selenium ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:16 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:16 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:16 7440-62-2 Zinc ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:16 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium 0.062J ug/L 0.10 0.020 1 10/20/18 02:45 10/25/18 01:40 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 10/30/18 22:20 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 10/30/18 22:20 107-13-1 Benzene 0.881 ug/L 1.0 0.25 1 10/30/18 22:20 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 10/30/18 22:20 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 10/30/18 22:20 75-27-4 Bromoform ND ug/L 1.0 0.26 1 10/30/18 22:20 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 10/30/18 22:20 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 10/30/18 22:20 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 10/30/18 22:20 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 10/30/18 22:20 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 10/30/18 22:20 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 10/30/18 22:20 75-00-3 Chloroform ND ug/L 1.0 0.14 1 10/30/18 22:20 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 10/30/18 22:20 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 10/30/18 22:20 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 10/30/18 22:20 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/30/18 22:20 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 10/30/18 22:20 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 10/30/18 22:20 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 10/30/18 22:20 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 10/30/18 22:20 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 10/30/18 22:20 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 10/30/18 22:20 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 10/30/18 22:20 75-35-4 cis-1,2-Dichloroethene 3.8 ug/L 1.0 0.19 1 10/30/18 22:20 156-59-2 trans-1,2-Dichloroethene 0.97J ug/L 1.0 0.49 1 10/30/18 22:20 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 10/30/18 22:20 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-6R Lab ID: 92404173007 Collected: 10/18/18 16:06 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 180.1 Turbidity Turbidity Date: 11/05/2018 04:52 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.13 1 10/30/18 22:20 10061-01-5 ND ug/L 1.0 0.26 1 10/30/18 22:20 10061-02-6 ND ug/L 150 78.4 1 10/30/18 22:20 123-91-1 ND ug/L 1.0 0.30 1 10/30/18 22:20 100-41-4 ND ug/L 5.0 0.46 1 10/30/18 22:20 591-78-6 ND ug/L 5.0 0.32 1 10/30/18 22:20 74-88-4 ND ug/L 1.0 0.97 1 10/30/18 22:20 75-09-2 ND ug/L 5.0 0.33 1 10/30/18 22:20 108-10-1 ND ug/L 1.0 0.26 1 10/30/18 22:20 100-42-5 ND ug/L 1.0 0.33 1 10/30/18 22:20 630-20-6 ND ug/L 1.0 0.40 1 10/30/18 22:20 79-34-5 0.60J ug/L 1.0 0.46 1 10/30/18 22:20 127-18-4 ND ug/L 1.0 0.26 1 10/30/18 22:20 108-88-3 ND ug/L 1.0 0.48 1 10/30/18 22:20 71-55-6 ND ug/L 1.0 0.29 1 10/30/18 22:20 79-00-5 0.50J ug/L 1.0 0.47 1 10/30/18 22:20 79-01-6 ND ug/L 1.0 0.20 1 10/30/18 22:20 75-69-4 ND ug/L 1.0 0.41 1 10/30/18 22:20 96-18-4 ND ug/L 2.0 0.35 1 10/30/18 22:20 108-05-4 1.6 ug/L 1.0 0.62 1 10/30/18 22:20 75-01-4 ND ug/L 1.0 0.66 1 10/30/18 22:20 1330-20-7 100 % 70-130 1 10/30/18 22:20 460-00-4 82 % 70-130 1 10/30/18 22:20 17060-07-0 98 % 70-130 1 10/30/18 22:20 2037-26-5 Analytical Method: EPA 180.1 Rev 2.0 1993 ND NTU 1.0 0.50 1 10/20/18 04:12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-8 Lab ID: 92404173008 Collected: 10/18/18 09:06 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 10/20/18 04:57 10/22/18 06:19 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:19 7440-38-2 Barium 68.3 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:19 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:19 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:19 7440-43-9 Chromium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:19 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:19 7440-48-4 Copper ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:19 7440-50-8 Lead ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:19 7439-92-1 Nickel ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:19 7440-02-0 Selenium ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:19 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:19 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:19 7440-62-2 Zinc ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:19 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.020 1 10/20/18 02:45 10/25/18 01:43 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 10/30/18 22:37 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 10/30/18 22:37 107-13-1 Benzene ND ug/L 1.0 0.25 1 10/30/18 22:37 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 10/30/18 22:37 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 10/30/18 22:37 75-27-4 Bromoform ND ug/L 1.0 0.26 1 10/30/18 22:37 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 10/30/18 22:37 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 10/30/18 22:37 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 10/30/18 22:37 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 10/30/18 22:37 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 10/30/18 22:37 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 10/30/18 22:37 75-00-3 Chloroform ND ug/L 1.0 0.14 1 10/30/18 22:37 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 10/30/18 22:37 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 10/30/18 22:37 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 10/30/18 22:37 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/30/18 22:37 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 10/30/18 22:37 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 10/30/18 22:37 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 10/30/18 22:37 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 10/30/18 22:37 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 10/30/18 22:37 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 10/30/18 22:37 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 10/30/18 22:37 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 10/30/18 22:37 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 10/30/18 22:37 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 10/30/18 22:37 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-8 Lab ID: 92404173008 Collected: 10/18/18 09:06 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 180.1 Turbidity Turbidity Date: 11/05/2018 04:52 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.13 1 10/30/18 22:37 10061-01-5 ND ug/L 1.0 0.26 1 10/30/18 22:37 10061-02-6 ND ug/L 150 78.4 1 10/30/18 22:37 123-91-1 ND ug/L 1.0 0.30 1 10/30/18 22:37 100-41-4 ND ug/L 5.0 0.46 1 10/30/18 22:37 591-78-6 ND ug/L 5.0 0.32 1 10/30/18 22:37 74-88-4 ND ug/L 1.0 0.97 1 10/30/18 22:37 75-09-2 ND ug/L 5.0 0.33 1 10/30/18 22:37 108-10-1 ND ug/L 1.0 0.26 1 10/30/18 22:37 100-42-5 ND ug/L 1.0 0.33 1 10/30/18 22:37 630-20-6 ND ug/L 1.0 0.40 1 10/30/18 22:37 79-34-5 ND ug/L 1.0 0.46 1 10/30/18 22:37 127-18-4 ND ug/L 1.0 0.26 1 10/30/18 22:37 108-88-3 ND ug/L 1.0 0.48 1 10/30/18 22:37 71-55-6 ND ug/L 1.0 0.29 1 10/30/18 22:37 79-00-5 ND ug/L 1.0 0.47 1 10/30/18 22:37 79-01-6 ND ug/L 1.0 0.20 1 10/30/18 22:37 75-69-4 ND ug/L 1.0 0.41 1 10/30/18 22:37 96-18-4 ND ug/L 2.0 0.35 1 10/30/18 22:37 108-05-4 ND ug/L 1.0 0.62 1 10/30/18 22:37 75-01-4 ND ug/L 1.0 0.66 1 10/30/18 22:37 1330-20-7 97 % 70-130 1 10/30/18 22:37 460-00-4 82 % 70-130 1 10/30/18 22:37 17060-07-0 96 % 70-130 1 10/30/18 22:37 2037-26-5 Analytical Method: EPA 180.1 Rev 2.0 1993 ND NTU 1.0 0.50 1 10/20/18 01:59 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-9S Lab ID: 92404173009 Collected: 10/18/18 08:59 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 301 OA Antimony ND ug/L 5.0 3.9 1 10/20/18 04:57 10/22/18 06:34 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:34 7440-38-2 Barium 102 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:34 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:34 7440-41-7 Cadmium 1.1 ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:34 7440-43-9 Chromium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:34 7440-47-3 Cobalt 117 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:34 7440-48-4 Copper ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:34 7440-50-8 Lead 3.OJ ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:34 7439-92-1 Nickel 10.3 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:34 7440-02-0 Selenium ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:34 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:34 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:34 7440-62-2 Zinc 8.8J ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:34 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium 0.29 ug/L 0.10 0.020 1 10/20/18 02:45 10/25/18 01:45 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 10/30/18 22:55 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 10/30/18 22:55 107-13-1 Benzene 0.84J ug/L 1.0 0.25 1 10/30/18 22:55 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 10/30/18 22:55 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 10/30/18 22:55 75-27-4 Bromoform ND ug/L 1.0 0.26 1 10/30/18 22:55 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 10/30/18 22:55 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 10/30/18 22:55 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 10/30/18 22:55 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 10/30/18 22:55 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 10/30/18 22:55 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 10/30/18 22:55 75-00-3 Chloroform ND ug/L 1.0 0.14 1 10/30/18 22:55 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 10/30/18 22:55 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 10/30/18 22:55 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 10/30/18 22:55 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/30/18 22:55 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 10/30/18 22:55 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 10/30/18 22:55 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 10/30/18 22:55 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 10/30/18 22:55 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 10/30/18 22:55 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 10/30/18 22:55 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 10/30/18 22:55 75-35-4 cis-1,2-Dichloroethene 4.3 ug/L 1.0 0.19 1 10/30/18 22:55 156-59-2 trans-1,2-Dichloroethene 0.68J ug/L 1.0 0.49 1 10/30/18 22:55 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 10/30/18 22:55 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-9S Lab ID: 92404173009 Collected: 10/18/18 08:59 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 180.1 Turbidity Turbidity Date: 11/05/2018 04:52 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.13 1 10/30/18 22:55 10061-01-5 ND ug/L 1.0 0.26 1 10/30/18 22:55 10061-02-6 ND ug/L 150 78.4 1 10/30/18 22:55 123-91-1 ND ug/L 1.0 0.30 1 10/30/18 22:55 100-41-4 ND ug/L 5.0 0.46 1 10/30/18 22:55 591-78-6 ND ug/L 5.0 0.32 1 10/30/18 22:55 74-88-4 ND ug/L 1.0 0.97 1 10/30/18 22:55 75-09-2 ND ug/L 5.0 0.33 1 10/30/18 22:55 108-10-1 ND ug/L 1.0 0.26 1 10/30/18 22:55 100-42-5 ND ug/L 1.0 0.33 1 10/30/18 22:55 630-20-6 ND ug/L 1.0 0.40 1 10/30/18 22:55 79-34-5 ND ug/L 1.0 0.46 1 10/30/18 22:55 127-18-4 ND ug/L 1.0 0.26 1 10/30/18 22:55 108-88-3 ND ug/L 1.0 0.48 1 10/30/18 22:55 71-55-6 ND ug/L 1.0 0.29 1 10/30/18 22:55 79-00-5 0.59J ug/L 1.0 0.47 1 10/30/18 22:55 79-01-6 ND ug/L 1.0 0.20 1 10/30/18 22:55 75-69-4 ND ug/L 1.0 0.41 1 10/30/18 22:55 96-18-4 ND ug/L 2.0 0.35 1 10/30/18 22:55 108-05-4 ND ug/L 1.0 0.62 1 10/30/18 22:55 75-01-4 ND ug/L 1.0 0.66 1 10/30/18 22:55 1330-20-7 98 % 70-130 1 10/30/18 22:55 460-00-4 83 % 70-130 1 10/30/18 22:55 17060-07-0 96 % 70-130 1 10/30/18 22:55 2037-26-5 Analytical Method: EPA 180.1 Rev 2.0 1993 1.9 NTU 1.0 0.50 1 10/20/18 01:58 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-91) Lab ID: 92404173010 Collected: 10/18/18 08:57 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 10/20/18 04:57 10/22/18 06:38 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:38 7440-38-2 Barium 48.1 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:38 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:38 7440-41-7 Cadmium 0.63J ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:38 7440-43-9 Chromium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:38 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:38 7440-48-4 Copper ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:38 7440-50-8 Lead ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:38 7439-92-1 Nickel 6.5 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:38 7440-02-0 Selenium ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:38 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:38 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:38 7440-62-2 Zinc 7.2J ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:38 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium 0.021J ug/L 0.10 0.020 1 10/20/18 02:45 10/25/18 01:48 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 10/30/18 23:12 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 10/30/18 23:12 107-13-1 Benzene ND ug/L 1.0 0.25 1 10/30/18 23:12 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 10/30/18 23:12 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 10/30/18 23:12 75-27-4 Bromoform ND ug/L 1.0 0.26 1 10/30/18 23:12 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 10/30/18 23:12 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 10/30/18 23:12 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 10/30/18 23:12 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 10/30/18 23:12 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 10/30/18 23:12 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 10/30/18 23:12 75-00-3 Chloroform ND ug/L 1.0 0.14 1 10/30/18 23:12 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 10/30/18 23:12 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 10/30/18 23:12 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 10/30/18 23:12 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/30/18 23:12 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 10/30/18 23:12 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 10/30/18 23:12 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 10/30/18 23:12 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 10/30/18 23:12 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 10/30/18 23:12 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 10/30/18 23:12 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 10/30/18 23:12 75-35-4 cis-1,2-Dichloroethene 0.93J ug/L 1.0 0.19 1 10/30/18 23:12 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 10/30/18 23:12 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 10/30/18 23:12 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-91) Lab ID: 92404173010 Collected: 10/18/18 08:57 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 180.1 Turbidity Turbidity Date: 11/05/2018 04:52 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.13 1 10/30/18 23:12 10061-01-5 ND ug/L 1.0 0.26 1 10/30/18 23:12 10061-02-6 ND ug/L 150 78.4 1 10/30/18 23:12 123-91-1 ND ug/L 1.0 0.30 1 10/30/18 23:12 100-41-4 ND ug/L 5.0 0.46 1 10/30/18 23:12 591-78-6 ND ug/L 5.0 0.32 1 10/30/18 23:12 74-88-4 ND ug/L 1.0 0.97 1 10/30/18 23:12 75-09-2 ND ug/L 5.0 0.33 1 10/30/18 23:12 108-10-1 ND ug/L 1.0 0.26 1 10/30/18 23:12 100-42-5 ND ug/L 1.0 0.33 1 10/30/18 23:12 630-20-6 ND ug/L 1.0 0.40 1 10/30/18 23:12 79-34-5 ND ug/L 1.0 0.46 1 10/30/18 23:12 127-18-4 ND ug/L 1.0 0.26 1 10/30/18 23:12 108-88-3 ND ug/L 1.0 0.48 1 10/30/18 23:12 71-55-6 ND ug/L 1.0 0.29 1 10/30/18 23:12 79-00-5 ND ug/L 1.0 0.47 1 10/30/18 23:12 79-01-6 ND ug/L 1.0 0.20 1 10/30/18 23:12 75-69-4 ND ug/L 1.0 0.41 1 10/30/18 23:12 96-18-4 ND ug/L 2.0 0.35 1 10/30/18 23:12 108-05-4 ND ug/L 1.0 0.62 1 10/30/18 23:12 75-01-4 ND ug/L 1.0 0.66 1 10/30/18 23:12 1330-20-7 100 % 70-130 1 10/30/18 23:12 460-00-4 84 % 70-130 1 10/30/18 23:12 17060-07-0 96 % 70-130 1 10/30/18 23:12 2037-26-5 Analytical Method: EPA 180.1 Rev 2.0 1993 16.3 NTU 1.0 0.50 1 10/20/18 01:52 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-10 Lab ID: 92404173011 Collected: 10/18/18 08:55 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 10/20/18 04:57 10/22/18 06:41 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:41 7440-38-2 Barium 33.3 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:41 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:41 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:41 7440-43-9 Chromium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:41 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:41 7440-48-4 Copper ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:41 7440-50-8 Lead ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:41 7439-92-1 Nickel ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:41 7440-02-0 Selenium ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:41 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:41 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:41 7440-62-2 Zinc ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:41 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.020 1 10/20/18 02:45 10/25/18 01:51 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 10/30/18 23:29 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 10/30/18 23:29 107-13-1 Benzene 0.95J ug/L 1.0 0.25 1 10/30/18 23:29 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 10/30/18 23:29 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 10/30/18 23:29 75-27-4 Bromoform ND ug/L 1.0 0.26 1 10/30/18 23:29 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 10/30/18 23:29 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 10/30/18 23:29 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 10/30/18 23:29 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 10/30/18 23:29 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 10/30/18 23:29 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 10/30/18 23:29 75-00-3 Chloroform ND ug/L 1.0 0.14 1 10/30/18 23:29 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 10/30/18 23:29 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 10/30/18 23:29 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 10/30/18 23:29 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/30/18 23:29 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 10/30/18 23:29 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 10/30/18 23:29 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 10/30/18 23:29 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 10/30/18 23:29 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 10/30/18 23:29 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 10/30/18 23:29 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 10/30/18 23:29 75-35-4 cis-1,2-Dichloroethene 1.2 ug/L 1.0 0.19 1 10/30/18 23:29 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 10/30/18 23:29 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 10/30/18 23:29 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-10 Lab ID: 92404173011 Collected: 10/18/18 08:55 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 180.1 Turbidity Turbidity Date: 11/05/2018 04:52 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.13 1 10/30/18 23:29 10061-01-5 ND ug/L 1.0 0.26 1 10/30/18 23:29 10061-02-6 ND ug/L 150 78.4 1 10/30/18 23:29 123-91-1 ND ug/L 1.0 0.30 1 10/30/18 23:29 100-41-4 ND ug/L 5.0 0.46 1 10/30/18 23:29 591-78-6 ND ug/L 5.0 0.32 1 10/30/18 23:29 74-88-4 ND ug/L 1.0 0.97 1 10/30/18 23:29 75-09-2 ND ug/L 5.0 0.33 1 10/30/18 23:29 108-10-1 ND ug/L 1.0 0.26 1 10/30/18 23:29 100-42-5 ND ug/L 1.0 0.33 1 10/30/18 23:29 630-20-6 ND ug/L 1.0 0.40 1 10/30/18 23:29 79-34-5 ND ug/L 1.0 0.46 1 10/30/18 23:29 127-18-4 ND ug/L 1.0 0.26 1 10/30/18 23:29 108-88-3 ND ug/L 1.0 0.48 1 10/30/18 23:29 71-55-6 ND ug/L 1.0 0.29 1 10/30/18 23:29 79-00-5 ND ug/L 1.0 0.47 1 10/30/18 23:29 79-01-6 ND ug/L 1.0 0.20 1 10/30/18 23:29 75-69-4 ND ug/L 1.0 0.41 1 10/30/18 23:29 96-18-4 ND ug/L 2.0 0.35 1 10/30/18 23:29 108-05-4 ND ug/L 1.0 0.62 1 10/30/18 23:29 75-01-4 ND ug/L 1.0 0.66 1 10/30/18 23:29 1330-20-7 102 % 70-130 1 10/30/18 23:29 460-00-4 83 % 70-130 1 10/30/18 23:29 17060-07-0 96 % 70-130 1 10/30/18 23:29 2037-26-5 Analytical Method: EPA 180.1 Rev 2.0 1993 2.6 NTU 1.0 0.50 1 10/20/18 01:50 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 26 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-11S Lab ID: 92404173012 Collected: 10/18/18 08:47 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 10/20/18 04:57 10/22/18 06:44 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:44 7440-38-2 Barium 21.1 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:44 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:44 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:44 7440-43-9 Chromium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:44 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:44 7440-48-4 Copper ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:44 7440-50-8 Lead ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:44 7439-92-1 Nickel ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:44 7440-02-0 Selenium ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:44 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:44 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:44 7440-62-2 Zinc 5.1J ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:44 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.020 1 10/20/18 02:45 10/25/18 02:01 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 10/30/18 23:46 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 10/30/18 23:46 107-13-1 Benzene ND ug/L 1.0 0.25 1 10/30/18 23:46 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 10/30/18 23:46 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 10/30/18 23:46 75-27-4 Bromoform ND ug/L 1.0 0.26 1 10/30/18 23:46 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 10/30/18 23:46 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 10/30/18 23:46 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 10/30/18 23:46 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 10/30/18 23:46 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 10/30/18 23:46 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 10/30/18 23:46 75-00-3 Chloroform ND ug/L 1.0 0.14 1 10/30/18 23:46 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 10/30/18 23:46 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 10/30/18 23:46 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 10/30/18 23:46 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/30/18 23:46 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 10/30/18 23:46 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 10/30/18 23:46 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 10/30/18 23:46 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 10/30/18 23:46 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 10/30/18 23:46 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 10/30/18 23:46 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 10/30/18 23:46 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 10/30/18 23:46 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 10/30/18 23:46 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 10/30/18 23:46 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-11S Lab ID: 92404173012 Collected: 10/18/18 08:47 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 180.1 Turbidity Turbidity Date: 11/05/2018 04:52 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.13 1 10/30/18 23:46 10061-01-5 ND ug/L 1.0 0.26 1 10/30/18 23:46 10061-02-6 ND ug/L 150 78.4 1 10/30/18 23:46 123-91-1 ND ug/L 1.0 0.30 1 10/30/18 23:46 100-41-4 ND ug/L 5.0 0.46 1 10/30/18 23:46 591-78-6 ND ug/L 5.0 0.32 1 10/30/18 23:46 74-88-4 ND ug/L 1.0 0.97 1 10/30/18 23:46 75-09-2 ND ug/L 5.0 0.33 1 10/30/18 23:46 108-10-1 ND ug/L 1.0 0.26 1 10/30/18 23:46 100-42-5 ND ug/L 1.0 0.33 1 10/30/18 23:46 630-20-6 ND ug/L 1.0 0.40 1 10/30/18 23:46 79-34-5 ND ug/L 1.0 0.46 1 10/30/18 23:46 127-18-4 ND ug/L 1.0 0.26 1 10/30/18 23:46 108-88-3 ND ug/L 1.0 0.48 1 10/30/18 23:46 71-55-6 ND ug/L 1.0 0.29 1 10/30/18 23:46 79-00-5 ND ug/L 1.0 0.47 1 10/30/18 23:46 79-01-6 ND ug/L 1.0 0.20 1 10/30/18 23:46 75-69-4 ND ug/L 1.0 0.41 1 10/30/18 23:46 96-18-4 ND ug/L 2.0 0.35 1 10/30/18 23:46 108-05-4 ND ug/L 1.0 0.62 1 10/30/18 23:46 75-01-4 ND ug/L 1.0 0.66 1 10/30/18 23:46 1330-20-7 98 % 70-130 1 10/30/18 23:46 460-00-4 81 % 70-130 1 10/30/18 23:46 17060-07-0 96 % 70-130 1 10/30/18 23:46 2037-26-5 Analytical Method: EPA 180.1 Rev 2.0 1993 5.1 NTU 1.0 0.50 1 10/20/18 01:49 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-11D Lab ID: 92404173013 Collected: 10/18/18 08:45 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 10/20/18 04:57 10/22/18 06:47 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:47 7440-38-2 Barium 3.7J ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:47 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:47 7440-41-7 Cadmium 0.71J ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:47 7440-43-9 Chromium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:47 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:47 7440-48-4 Copper 3.5J ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:47 7440-50-8 Lead ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:47 7439-92-1 Nickel ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:47 7440-02-0 Selenium ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:47 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:47 7440-22-4 Vanadium 3.3J ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:47 7440-62-2 Zinc 5.1J ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:47 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.020 1 10/20/18 02:45 10/25/18 02:04 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 10/31/18 00:03 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 10/31/18 00:03 107-13-1 Benzene ND ug/L 1.0 0.25 1 10/31/18 00:03 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 10/31/18 00:03 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 10/31/18 00:03 75-27-4 Bromoform ND ug/L 1.0 0.26 1 10/31/18 00:03 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 10/31/18 00:03 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 10/31/18 00:03 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 10/31/18 00:03 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 10/31/18 00:03 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 10/31/18 00:03 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 10/31/18 00:03 75-00-3 Chloroform ND ug/L 1.0 0.14 1 10/31/18 00:03 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 10/31/18 00:03 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 10/31/18 00:03 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 10/31/18 00:03 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/31/18 00:03 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 10/31/18 00:03 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 10/31/18 00:03 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 10/31/18 00:03 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 10/31/18 00:03 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 10/31/18 00:03 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 10/31/18 00:03 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 10/31/18 00:03 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 10/31/18 00:03 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 10/31/18 00:03 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 10/31/18 00:03 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-11D Lab ID: 92404173013 Collected: 10/18/18 08:45 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 180.1 Turbidity Turbidity Date: 11/05/2018 04:52 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.13 1 10/31/18 00:03 10061-01-5 ND ug/L 1.0 0.26 1 10/31/18 00:03 10061-02-6 ND ug/L 150 78.4 1 10/31/18 00:03 123-91-1 ND ug/L 1.0 0.30 1 10/31/18 00:03 100-41-4 ND ug/L 5.0 0.46 1 10/31/18 00:03 591-78-6 ND ug/L 5.0 0.32 1 10/31/18 00:03 74-88-4 ND ug/L 1.0 0.97 1 10/31/18 00:03 75-09-2 ND ug/L 5.0 0.33 1 10/31/18 00:03 108-10-1 ND ug/L 1.0 0.26 1 10/31/18 00:03 100-42-5 ND ug/L 1.0 0.33 1 10/31/18 00:03 630-20-6 ND ug/L 1.0 0.40 1 10/31/18 00:03 79-34-5 ND ug/L 1.0 0.46 1 10/31/18 00:03 127-18-4 ND ug/L 1.0 0.26 1 10/31/18 00:03 108-88-3 ND ug/L 1.0 0.48 1 10/31/18 00:03 71-55-6 ND ug/L 1.0 0.29 1 10/31/18 00:03 79-00-5 ND ug/L 1.0 0.47 1 10/31/18 00:03 79-01-6 ND ug/L 1.0 0.20 1 10/31/18 00:03 75-69-4 ND ug/L 1.0 0.41 1 10/31/18 00:03 96-18-4 ND ug/L 2.0 0.35 1 10/31/18 00:03 108-05-4 ND ug/L 1.0 0.62 1 10/31/18 00:03 75-01-4 ND ug/L 1.0 0.66 1 10/31/18 00:03 1330-20-7 97 % 70-130 1 10/31/18 00:03 460-00-4 83 % 70-130 1 10/31/18 00:03 17060-07-0 97 % 70-130 1 10/31/18 00:03 2037-26-5 Analytical Method: EPA 180.1 Rev 2.0 1993 3.6 NTU 1.0 0.50 1 10/20/18 01:48 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 30 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-12 Lab ID: 92404173014 Collected: 10/18/18 15:55 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 10/20/18 04:57 10/22/18 06:50 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:50 7440-38-2 Barium 9.8 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:50 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:50 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:50 7440-43-9 Chromium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:50 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:50 7440-48-4 Copper ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:50 7440-50-8 Lead ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:50 7439-92-1 Nickel ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:50 7440-02-0 Selenium ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:50 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:50 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:50 7440-62-2 Zinc ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:50 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.020 1 10/20/18 02:45 10/25/18 02:07 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 10/31/18 00:20 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 10/31/18 00:20 107-13-1 Benzene ND ug/L 1.0 0.25 1 10/31/18 00:20 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 10/31/18 00:20 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 10/31/18 00:20 75-27-4 Bromoform ND ug/L 1.0 0.26 1 10/31/18 00:20 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 10/31/18 00:20 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 10/31/18 00:20 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 10/31/18 00:20 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 10/31/18 00:20 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 10/31/18 00:20 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 10/31/18 00:20 75-00-3 Chloroform ND ug/L 1.0 0.14 1 10/31/18 00:20 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 10/31/18 00:20 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 10/31/18 00:20 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 10/31/18 00:20 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/31/18 00:20 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 10/31/18 00:20 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 10/31/18 00:20 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 10/31/18 00:20 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 10/31/18 00:20 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 10/31/18 00:20 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 10/31/18 00:20 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 10/31/18 00:20 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 10/31/18 00:20 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 10/31/18 00:20 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 10/31/18 00:20 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-12 Lab ID: 92404173014 Collected: 10/18/18 15:55 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 180.1 Turbidity Turbidity Date: 11/05/2018 04:52 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.13 1 10/31/18 00:20 10061-01-5 ND ug/L 1.0 0.26 1 10/31/18 00:20 10061-02-6 ND ug/L 150 78.4 1 10/31/18 00:20 123-91-1 ND ug/L 1.0 0.30 1 10/31/18 00:20 100-41-4 ND ug/L 5.0 0.46 1 10/31/18 00:20 591-78-6 ND ug/L 5.0 0.32 1 10/31/18 00:20 74-88-4 ND ug/L 1.0 0.97 1 10/31/18 00:20 75-09-2 ND ug/L 5.0 0.33 1 10/31/18 00:20 108-10-1 ND ug/L 1.0 0.26 1 10/31/18 00:20 100-42-5 ND ug/L 1.0 0.33 1 10/31/18 00:20 630-20-6 ND ug/L 1.0 0.40 1 10/31/18 00:20 79-34-5 ND ug/L 1.0 0.46 1 10/31/18 00:20 127-18-4 ND ug/L 1.0 0.26 1 10/31/18 00:20 108-88-3 ND ug/L 1.0 0.48 1 10/31/18 00:20 71-55-6 ND ug/L 1.0 0.29 1 10/31/18 00:20 79-00-5 ND ug/L 1.0 0.47 1 10/31/18 00:20 79-01-6 ND ug/L 1.0 0.20 1 10/31/18 00:20 75-69-4 ND ug/L 1.0 0.41 1 10/31/18 00:20 96-18-4 ND ug/L 2.0 0.35 1 10/31/18 00:20 108-05-4 ND ug/L 1.0 0.62 1 10/31/18 00:20 75-01-4 ND ug/L 1.0 0.66 1 10/31/18 00:20 1330-20-7 99 % 70-130 1 10/31/18 00:20 460-00-4 84 % 70-130 1 10/31/18 00:20 17060-07-0 96 % 70-130 1 10/31/18 00:20 2037-26-5 Analytical Method: EPA 180.1 Rev 2.0 1993 0.61J NTU 1.0 0.50 1 10/20/18 04:09 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 32 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-13 Lab ID: 92404173015 Collected: 10/18/18 16:00 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 10/20/18 04:57 10/22/18 06:53 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:53 7440-38-2 Barium 16.7 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:53 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:53 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:53 7440-43-9 Chromium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:53 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:53 7440-48-4 Copper ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:53 7440-50-8 Lead ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:53 7439-92-1 Nickel ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:53 7440-02-0 Selenium ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:53 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:53 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:53 7440-62-2 Zinc ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:53 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium 0.064J ug/L 0.10 0.020 1 10/20/18 02:45 10/25/18 02:15 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 10/31/18 00:37 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 10/31/18 00:37 107-13-1 Benzene ND ug/L 1.0 0.25 1 10/31/18 00:37 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 10/31/18 00:37 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 10/31/18 00:37 75-27-4 Bromoform ND ug/L 1.0 0.26 1 10/31/18 00:37 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 10/31/18 00:37 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 10/31/18 00:37 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 10/31/18 00:37 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 10/31/18 00:37 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 10/31/18 00:37 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 10/31/18 00:37 75-00-3 Chloroform ND ug/L 1.0 0.14 1 10/31/18 00:37 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 10/31/18 00:37 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 10/31/18 00:37 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 10/31/18 00:37 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/31/18 00:37 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 10/31/18 00:37 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 10/31/18 00:37 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 10/31/18 00:37 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 10/31/18 00:37 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 10/31/18 00:37 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 10/31/18 00:37 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 10/31/18 00:37 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 10/31/18 00:37 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 10/31/18 00:37 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 10/31/18 00:37 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: MW-13 Lab ID: 92404173015 Collected: 10/18/18 16:00 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 180.1 Turbidity Turbidity Date: 11/05/2018 04:52 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.13 1 10/31/18 00:37 10061-01-5 ND ug/L 1.0 0.26 1 10/31/18 00:37 10061-02-6 ND ug/L 150 78.4 1 10/31/18 00:37 123-91-1 ND ug/L 1.0 0.30 1 10/31/18 00:37 100-41-4 ND ug/L 5.0 0.46 1 10/31/18 00:37 591-78-6 ND ug/L 5.0 0.32 1 10/31/18 00:37 74-88-4 ND ug/L 1.0 0.97 1 10/31/18 00:37 75-09-2 ND ug/L 5.0 0.33 1 10/31/18 00:37 108-10-1 ND ug/L 1.0 0.26 1 10/31/18 00:37 100-42-5 ND ug/L 1.0 0.33 1 10/31/18 00:37 630-20-6 ND ug/L 1.0 0.40 1 10/31/18 00:37 79-34-5 ND ug/L 1.0 0.46 1 10/31/18 00:37 127-18-4 ND ug/L 1.0 0.26 1 10/31/18 00:37 108-88-3 ND ug/L 1.0 0.48 1 10/31/18 00:37 71-55-6 ND ug/L 1.0 0.29 1 10/31/18 00:37 79-00-5 ND ug/L 1.0 0.47 1 10/31/18 00:37 79-01-6 ND ug/L 1.0 0.20 1 10/31/18 00:37 75-69-4 ND ug/L 1.0 0.41 1 10/31/18 00:37 96-18-4 ND ug/L 2.0 0.35 1 10/31/18 00:37 108-05-4 ND ug/L 1.0 0.62 1 10/31/18 00:37 75-01-4 ND ug/L 1.0 0.66 1 10/31/18 00:37 1330-20-7 97 % 70-130 1 10/31/18 00:37 460-00-4 83 % 70-130 1 10/31/18 00:37 17060-07-0 97 % 70-130 1 10/31/18 00:37 2037-26-5 Analytical Method: EPA 180.1 Rev 2.0 1993 0.56J NTU 1.0 0.50 1 10/20/18 04:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 34 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: SW-D Lab ID: 92404173016 Collected: 10/18/18 00:00 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 10/31/18 00:55 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 10/31/18 00:55 107-13-1 Benzene ND ug/L 1.0 0.25 1 10/31/18 00:55 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 10/31/18 00:55 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 10/31/18 00:55 75-27-4 Bromoform ND ug/L 1.0 0.26 1 10/31/18 00:55 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 10/31/18 00:55 74-83-9 M1 2-Butanone (MEK) ND ug/L 5.0 0.96 1 10/31/18 00:55 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 10/31/18 00:55 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 10/31/18 00:55 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 10/31/18 00:55 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 10/31/18 00:55 75-00-3 Chloroform ND ug/L 1.0 0.14 1 10/31/18 00:55 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 10/31/18 00:55 74-87-3 M1 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 10/31/18 00:55 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 10/31/18 00:55 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/31/18 00:55 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 10/31/18 00:55 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 10/31/18 00:55 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 10/31/18 00:55 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 10/31/18 00:55 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 10/31/18 00:55 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 10/31/18 00:55 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 10/31/18 00:55 75-35-4 cis-1,2-Dichloroethene 1.2 ug/L 1.0 0.19 1 10/31/18 00:55 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 10/31/18 00:55 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 10/31/18 00:55 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 10/31/18 00:55 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 10/31/18 00:55 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 10/31/18 00:55 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 10/31/18 00:55 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 10/31/18 00:55 591-78-6 lodomethane ND ug/L 5.0 0.32 1 10/31/18 00:55 74-88-4 M1 Methylene Chloride ND ug/L 1.0 0.97 1 10/31/18 00:55 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 10/31/18 00:55 108-10-1 Styrene ND ug/L 1.0 0.26 1 10/31/18 00:55 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 10/31/18 00:55 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 10/31/18 00:55 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 10/31/18 00:55 127-18-4 Toluene ND ug/L 1.0 0.26 1 10/31/18 00:55 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 10/31/18 00:55 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 10/31/18 00:55 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 10/31/18 00:55 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 10/31/18 00:55 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 10/31/18 00:55 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 10/31/18 00:55 108-05-4 M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: SW-D Lab ID: 92404173016 Collected: 10/18/18 00:00 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Vinyl chloride ND ug/L 1.0 0.62 1 10/31/18 00:55 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 10/31/18 00:55 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 10/31/18 00:55 460-00-4 1,2-Dichloroethane-d4 (S) 82 % 70-130 1 10/31/18 00:55 17060-07-0 Toluene-d8 (S) 95 % 70-130 1 10/31/18 00:55 2037-26-5 Date: 11/05/2018 04:52 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 36 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: LAGOON Lab ID: 92404173017 Collected: 10/18/18 17:00 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 10/20/18 04:57 10/22/18 06:56 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:56 7440-38-2 Barium 220 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:56 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:56 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 10/20/18 04:57 10/22/18 06:56 7440-43-9 Chromium 2.9J ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:56 7440-47-3 Cobalt 14.8 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:56 7440-48-4 Copper ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:56 7440-50-8 Lead 5.2 ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:56 7439-92-1 Nickel 3.6J ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:56 7440-02-0 Selenium ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:56 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:56 7440-22-4 Tin ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:56 7440-31-5 Vanadium ND ug/L 5.0 2.5 1 10/20/18 04:57 10/22/18 06:56 7440-62-2 Zinc ND ug/L 10.0 5.0 1 10/20/18 04:57 10/22/18 06:56 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.020 1 10/20/18 02:45 10/25/18 02:17 7440-28-0 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.10 1 10/24/1812:45 10/25/1813:19 7439-97-6 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 10/31/18 01:12 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 10/31/18 01:12 107-13-1 Benzene 0.36J ug/L 1.0 0.25 1 10/31/18 01:12 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 10/31/18 01:12 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 10/31/18 01:12 75-27-4 Bromoform ND ug/L 1.0 0.26 1 10/31/18 01:12 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 10/31/18 01:12 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 10/31/18 01:12 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 10/31/18 01:12 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 10/31/18 01:12 56-23-5 Chlorobenzene 0.34J ug/L 1.0 0.23 1 10/31/18 01:12 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 10/31/18 01:12 75-00-3 Chloroform ND ug/L 1.0 0.14 1 10/31/18 01:12 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 10/31/18 01:12 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 10/31/18 01:12 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 10/31/18 01:12 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/31/18 01:12 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 10/31/18 01:12 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 10/31/18 01:12 95-50-1 1,4-Dichlorobenzene 2.1 ug/L 1.0 0.33 1 10/31/18 01:12 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 10/31/18 01:12 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 10/31/18 01:12 75-34-3 1,2-Dichloroethane 0.62J ug/L 1.0 0.24 1 10/31/18 01:12 107-06-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: LAGOON Lab ID: 92404173017 Collected: 10/18/18 17:00 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 180.1 Turbidity Turbidity 5210B BOD, 5 day BOD, 5 day 9040 pH pH at 25 Degrees C 300.0 IC Anions 28 Days Sulfate 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate Date: 11/05/2018 04:52 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.56 1 10/31/18 01:12 75-35-4 0.44J ug/L 1.0 0.19 1 10/31/18 01:12 156-59-2 0.68J ug/L 1.0 0.49 1 10/31/18 01:12 156-60-5 ND ug/L 1.0 0.27 1 10/31/18 01:12 78-87-5 ND ug/L 1.0 0.13 1 10/31/18 01:12 10061-01-5 ND ug/L 1.0 0.26 1 10/31/18 01:12 10061-02-6 ND ug/L 150 78.4 1 10/31/18 01:12 123-91-1 ND ug/L 1.0 0.30 1 10/31/18 01:12 100-41-4 ND ug/L 5.0 0.46 1 10/31/18 01:12 591-78-6 ND ug/L 5.0 0.32 1 10/31/18 01:12 74-88-4 ND ug/L 1.0 0.97 1 10/31/18 01:12 75-09-2 ND ug/L 5.0 0.33 1 10/31/18 01:12 108-10-1 ND ug/L 1.0 0.26 1 10/31/18 01:12 100-42-5 ND ug/L 1.0 0.33 1 10/31/18 01:12 630-20-6 ND ug/L 1.0 0.40 1 10/31/18 01:12 79-34-5 ND ug/L 1.0 0.46 1 10/31/18 01:12 127-18-4 ND ug/L 1.0 0.26 1 10/31/18 01:12 108-88-3 ND ug/L 1.0 0.48 1 10/31/18 01:12 71-55-6 ND ug/L 1.0 0.29 1 10/31/18 01:12 79-00-5 ND ug/L 1.0 0.47 1 10/31/18 01:12 79-01-6 ND ug/L 1.0 0.20 1 10/31/18 01:12 75-69-4 ND ug/L 1.0 0.41 1 10/31/18 01:12 96-18-4 ND ug/L 2.0 0.35 1 10/31/18 01:12 108-05-4 ND ug/L 1.0 0.62 1 10/31/18 01:12 75-01-4 ND ug/L 1.0 0.66 1 10/31/18 01:12 1330-20-7 99 % 70-130 1 10/31/18 01:12 460-00-4 82 % 70-130 1 10/31/18 01:12 17060-07-0 96 % 70-130 1 10/31/18 01:12 2037-26-5 Analytical Method: EPA 180.1 Rev 2.0 1993 53.6 NTU 1.0 0.50 1 10/20/18 04:14 Analytical Method: SM 521OB-2011 ND ug/L 2000 2000 1 10/20/18 04:49 10/25/18 01:42 Analytical Method: EPA 9040C 6.0 Std. Units 0.10 0.10 1 10/21/18 13:44 Analytical Method: EPA 300.0 Rev 2.1 1993 3580 ug/L 1000 500 1 10/23/1813:56 14808-79-8 Analytical Method: EPA 353.2 Rev 2.0 1993 ND ug/L 20.0 10.0 1 10/20/18 00:43 14797-55-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. B2 H3 Page 38 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Sample: LAGOON Lab ID: 92404173017 Collected: 10/18/18 17:00 Received: 10/19/18 07:22 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Phosphorus 31.9J ug/L 50.0 25.0 1 10/22/18 18:11 10/22/18 20:58 7723-14-0 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Chemical Oxygen Demand 128000 ug/L 25000 12500 1 10/22/18 19:00 10/22/18 22:48 Date: 11/05/2018 04:52 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 39 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 QC Batch: 438027 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Associated Lab Samples: 92404173017 METHOD BLANK: 2408281 Matrix: Water Associated Lab Samples: 92404173017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.10 10/25/1812:17 LABORATORY CONTROL SAMPLE: 2408282 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.7 108 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2408283 2408284 MS MSD 92404451001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.6 2.7 100 103 75-125 3 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 QC Batch: 437375 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92404173001, 92404173002, 92404173003, 92404173004, 92404173005, 92404173006, 92404173007, 92404173008,92404173009,92404173010,92404173011,92404173012,92404173013,92404173014, 92404173015,92404173017 METHOD BLANK: 2405608 Matrix: Water Associated Lab Samples: 92404173001, 92404173002, 92404173003, 92404173004, 92404173005, 92404173006, 92404173007, 92404173008,92404173009,92404173010,92404173011,92404173012,92404173013,92404173014, 92404173015,92404173017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.9 10/22/18 05:36 Arsenic ug/L ND 10.0 5.0 10/22/18 05:36 Barium ug/L ND 5.0 2.5 10/22/18 05:36 Beryllium ug/L ND 1.0 0.50 10/22/18 05:36 Cadmium ug/L ND 1.0 0.50 10/22/18 05:36 Chromium ug/L ND 5.0 2.5 10/22/18 05:36 Cobalt ug/L ND 5.0 2.5 10/22/18 05:36 Copper ug/L ND 5.0 2.5 10/22/18 05:36 Lead ug/L ND 5.0 2.5 10/22/18 05:36 Nickel ug/L ND 5.0 2.5 10/22/18 05:36 Selenium ug/L ND 10.0 5.0 10/22/18 05:36 Silver ug/L ND 5.0 2.5 10/22/18 05:36 Tin ug/L ND 5.0 2.5 10/22/18 05:36 Vanadium ug/L ND 5.0 2.5 10/22/18 05:36 Zinc ug/L ND 10.0 5.0 10/22/18 05:36 LABORATORY CONTROL SAMPLE: 2405609 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 500 473 95 80-120 Arsenic ug/L 500 462 92 80-120 Barium ug/L 500 505 101 80-120 Beryllium ug/L 500 493 99 80-120 Cadmium ug/L 500 474 95 80-120 Chromium ug/L 500 484 97 80-120 Cobalt ug/L 500 465 93 80-120 Copper ug/L 500 496 99 80-120 Lead ug/L 500 461 92 80-120 Nickel ug/L 500 468 94 80-120 Selenium ug/L 500 454 91 80-120 Silver ug/L 250 242 97 80-120 Tin ug/L 500 473 95 80-120 Vanadium ug/L 500 482 96 80-120 Zinc ug/L 500 455 91 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2405610 2405611 MS MSD 92404173001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 499 507 100 101 75-125 2 20 Arsenic ug/L ND 500 500 485 494 97 99 75-125 2 20 Barium ug/L 9.9 500 500 535 539 105 106 75-125 1 20 Beryllium ug/L ND 500 500 514 517 103 103 75-125 1 20 Cadmium ug/L 0.51J 500 500 501 507 100 101 75-125 1 20 Chromium ug/L ND 500 500 507 513 101 102 75-125 1 20 Cobalt ug/L ND 500 500 489 498 97 99 75-125 2 20 Copper ug/L ND 500 500 517 527 103 105 75-125 2 20 Lead ug/L ND 500 500 482 492 96 98 75-125 2 20 Nickel ug/L 3AJ 500 500 493 502 98 100 75-125 2 20 Selenium ug/L ND 500 500 485 502 97 100 75-125 3 20 Silver ug/L ND 250 250 255 259 102 104 75-125 1 20 Tin ug/L ND 500 500 504 513 101 102 75-125 2 20 Vanadium ug/L ND 500 500 501 512 100 102 75-125 2 20 Zinc ug/L 8.8J 500 500 489 498 96 98 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 QC Batch: 437383 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92404173001, 92404173002, 92404173003, 92404173004, 92404173005, 92404173006, 92404173007, 92404173008,92404173009,92404173010,92404173011,92404173012,92404173013,92404173014, 92404173015,92404173017 METHOD BLANK: 2405641 Matrix: Water Associated Lab Samples: 92404173001, 92404173002, 92404173003, 92404173004, 92404173005, 92404173006, 92404173007, 92404173008,92404173009,92404173010,92404173011,92404173012,92404173013,92404173014, 92404173015,92404173017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.020 10/25/18 01:05 LABORATORY CONTROL SAMPLE: 2405642 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.2 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2405643 2405644 MS MSD 92404173001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L 0.030J 10 10 9.9 10.1 99 100 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 QC Batch: 439207 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill Associated Lab Samples: 92404173001, 92404173002, 92404173003, 92404173004, 92404173005, 92404173007, 92404173008, 92404173009,92404173010,92404173011,92404173012,92404173013,92404173014,92404173015, 92404173016,92404173017 METHOD BLANK: 2414016 Matrix: Water Associated Lab Samples: 92404173001, 92404173002, 92404173003, 92404173004, 92404173005, 92404173007, 92404173008, 92404173009,92404173010,92404173011,92404173012,92404173013,92404173014,92404173015, 92404173016,92404173017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.33 10/30/18 19:12 1,1,1-Trichloroethane ug/L ND 1.0 0.48 10/30/18 19:12 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.40 10/30/18 19:12 1,1,2-Trichloroethane ug/L ND 1.0 0.29 10/30/18 19:12 1,1-Dichloroethane ug/L ND 1.0 0.32 10/30/18 19:12 1,1-Dichloroethene ug/L ND 1.0 0.56 10/30/18 19:12 1,2,3-Trichloropropane ug/L ND 1.0 0.41 10/30/18 19:12 1,2-Dibromo-3-chloropropane ug/L ND 2.0 2.0 10/30/18 19:12 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 10/30/18 19:12 1,2-Dichlorobenzene ug/L ND 1.0 0.30 10/30/18 19:12 1,2-Dichloroethane ug/L ND 1.0 0.24 10/30/18 19:12 1,2-Dichloropropane ug/L ND 1.0 0.27 10/30/18 19:12 1,4-Dichlorobenzene ug/L ND 1.0 0.33 10/30/18 19:12 1,4-Dioxane (p-Dioxane) ug/L ND 150 78.4 10/30/18 19:12 2-Butanone (MEK) ug/L ND 5.0 0.96 10/30/18 19:12 2-Hexanone ug/L ND 5.0 0.46 10/30/18 19:12 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 0.33 10/30/18 19:12 Acetone ug/L ND 25.0 10.0 10/30/18 19:12 Acrylonitrile ug/L ND 10.0 1.9 10/30/18 19:12 Benzene ug/L ND 1.0 0.25 10/30/18 19:12 Bromochloromethane ug/L ND 1.0 0.17 10/30/18 19:12 Bromodichloromethane ug/L ND 1.0 0.18 10/30/18 19:12 Bromoform ug/L ND 1.0 0.26 10/30/18 19:12 Bromomethane ug/L ND 2.0 0.29 10/30/18 19:12 Carbon disulfide ug/L ND 2.0 1.2 10/30/18 19:12 Carbon tetrachloride ug/L ND 1.0 0.25 10/30/18 19:12 Chlorobenzene ug/L ND 1.0 0.23 10/30/18 19:12 Chloroethane ug/L ND 1.0 0.54 10/30/18 19:12 Chloroform ug/L ND 1.0 0.14 10/30/18 19:12 Chloromethane ug/L ND 1.0 0.11 10/30/18 19:12 cis-1,2-Dichloroethene ug/L ND 1.0 0.19 10/30/18 19:12 cis-1,3-Dichloropropene ug/L ND 1.0 0.13 10/30/18 19:12 Dibromochloromethane ug/L ND 1.0 0.21 10/30/18 19:12 Dibromomethane ug/L ND 1.0 0.21 10/30/18 19:12 Ethylbenzene ug/L ND 1.0 0.30 10/30/18 19:12 lodomethane ug/L ND 5.0 0.32 10/30/18 19:12 Methylene Chloride ug/L ND 1.0 0.97 10/30/18 19:12 Styrene ug/L ND 1.0 0.26 10/30/18 19:12 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 METHOD BLANK: 2414016 Matrix: Water Associated Lab Samples: 92404173001, 92404173002, 92404173003, 92404173004, 92404173005, 92404173007, 92404173008, 92404173009,92404173010,92404173011,92404173012,92404173013,92404173014,92404173015, 92404173016,92404173017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Tetrachloroethene ug/L ND 1.0 0.46 10/30/18 19:12 Toluene ug/L ND 1.0 0.26 10/30/18 19:12 trans-1,2-Dichloroethene ug/L ND 1.0 0.49 10/30/18 19:12 trans- 1,3-Dichloropropene ug/L ND 1.0 0.26 10/30/18 19:12 trans-1,4-Dichloro-2-butene ug/L ND 1.0 1.0 10/30/18 19:12 Trichloroethene ug/L ND 1.0 0.47 10/30/18 19:12 Trichlorofluoromethane ug/L ND 1.0 0.20 10/30/18 19:12 Vinyl acetate ug/L ND 2.0 0.35 10/30/18 19:12 Vinyl chloride ug/L ND 1.0 0.62 10/30/18 19:12 Xylene (Total) ug/L ND 1.0 0.66 10/30/18 19:12 1,2-Dichloroethane-d4 (S) % 88 70-130 10/30/18 19:12 4-Bromofluorobenzene (S) % 96 70-130 10/30/18 19:12 Toluene-d8 (S) % 98 70-130 10/30/18 19:12 LABORATORY CONTROL SAMPLE: 2414017 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 47.5 95 80-125 1,1,1-Trichloroethane ug/L 50 46.0 92 71-129 1,1,2,2-Tetrachloroethane ug/L 50 48.5 97 79-124 1,1,2-Trichloroethane ug/L 50 47.6 95 85-125 1,1-Dichloroethane ug/L 50 43.9 88 73-126 1,1-Dichloroethene ug/L 50 46.0 92 66-135 1,2,3-Trichloropropane ug/L 50 48.5 97 75-130 1,2-Dibromo-3-chloropropane ug/L 50 52.1 104 71-133 1,2-Dibromoethane (EDB) ug/L 50 48.6 97 83-124 1,2-Dichlorobenzene ug/L 50 50.8 102 80-133 1,2-Dichloroethane ug/L 50 42.6 85 67-128 1,2-Dichloropropane ug/L 50 47.9 96 75-132 1,4-Dichlorobenzene ug/L 50 49.0 98 78-130 1,4-Dioxane(p-Dioxane) ug/L 1000 975 98 13-220 2-Butanone (MEK) ug/L 100 92.4 92 61-144 2-Hexanone ug/L 100 100 100 68-143 4-Methyl-2-pentanone (MIBK) ug/L 100 97.6 98 72-135 Acetone ug/L 100 87.7 88 48-146 Acrylonitrile ug/L 250 224 90 40-160 Benzene ug/L 50 47.4 95 80-125 Bromochloromethane ug/L 50 46.2 92 71-125 Bromodichloromethane ug/L 50 46.2 92 78-124 Bromoform ug/L 50 45.9 92 71-128 Bromomethane ug/L 50 30.2 60 40-160 Carbon disulfide ug/L 50 43.0 86 50-160 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 68 Pace Analytical Services, LLC aceAnalXical� 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 LABORATORY CONTROL SAMPLE: Parameter 2414017 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Carbon tetrachloride ug/L 50 47.6 95 69-131 Chlorobenzene ug/L 50 48.4 97 81-122 Chloroethane ug/L 50 31.4 63 39-148 Chloroform ug/L 50 43.4 87 73-127 Chloromethane ug/L 50 34.3 69 44-146 cis-1,2-Dichloroethene ug/L 50 44.7 89 74-124 cis-1,3-Dichloropropene ug/L 50 48.2 96 72-132 Dibromochloromethane ug/L 50 48.9 98 78-125 Dibromomethane ug/L 50 48.3 97 82-120 Ethylbenzene ug/L 50 48.5 97 79-121 lodomethane ug/L 100 67.1 67 39-154 Methylene Chloride ug/L 50 42.7 85 64-133 Styrene ug/L 50 48.5 97 84-126 Tetrachloroethene ug/L 50 47.7 95 78-122 Toluene ug/L 50 46.9 94 80-121 trans-1,2-Dichloroethene ug/L 50 44.5 89 71-127 trans- 1,3-Dichloropropene ug/L 50 47.4 95 69-141 trans-1,4-Dichloro-2-butene ug/L 50 49.6 99 40-160 Trichloroethene ug/L 50 47.4 95 78-122 Trichlorofluoromethane ug/L 50 36.4 73 53-137 Vinyl acetate ug/L 100 87.8 88 40-160 Vinyl chloride ug/L 50 40.9 82 58-137 Xylene (Total) ug/L 150 148 99 81-126 1,2-Dichloroethane-d4 (S) % 92 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE SAMPLE: Parameter 2414019 Units 92404173016 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 18.3 91 70-130 1,1,1-Trichloroethane ug/L ND 20 15.8 79 70-130 1,1,2,2-Tetrachloroethane ug/L ND 20 18.6 93 70-130 1,1,2-Trichloroethane ug/L ND 20 17.5 88 70-130 1,1-Dichloroethane ug/L ND 20 15.7 78 70-130 1,1-Dichloroethene ug/L ND 20 16.7 83 70-166 1,2,3-Trichloropropane ug/L ND 20 18.4 92 70-130 1,2-Dibromo-3-chloropropane ug/L ND 20 17.6 88 70-130 1,2-Dibromoethane (EDB) ug/L ND 20 18.3 91 70-130 1,2-Dichlorobenzene ug/L ND 20 18.3 91 70-130 1,2-Dichloroethane ug/L ND 20 14.5 72 70-130 1,2-Dichloropropane ug/L ND 20 18.3 91 70-130 1,4-Dichlorobenzene ug/L ND 20 18.2 91 70-130 1,4-Dioxane (p-Dioxane) ug/L ND 400 376 94 70-130 2-Butanone (MEK) ug/L ND 40 31.5 79 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 46 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 MATRIX SPIKE SAMPLE: 2414019 92404173016 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 2-Hexanone ug/L ND 40 37.1 93 70-130 4-Methyl-2-pentanone (MIBK) ug/L ND 40 35.1 88 70-130 Acetone ug/L ND 40 33.0 82 70-130 Acrylonitrile ug/L ND 100 74.8 75 70-130 Benzene ug/L ND 20 18.6 93 70-148 Bromochloromethane ug/L ND 20 16.8 84 70-130 Bromodichloromethane ug/L ND 20 17.2 86 70-130 Bromoform ug/L ND 20 15.6 78 70-130 Bromomethane ug/L ND 20 11.4 57 70-130 M1 Carbon disulfide ug/L ND 20 14.9 75 70-130 Carbon tetrachloride ug/L ND 20 18.2 91 70-130 Chlorobenzene ug/L ND 20 19.0 95 70-146 Chloroethane ug/L ND 20 14.5 72 70-130 Chloroform ug/L ND 20 14.8 74 70-130 Chloromethane ug/L ND 20 12.2 61 70-130 M1 cis-1,2-Dichloroethene ug/L 1.2 20 16.9 79 70-130 cis-1,3-Dichloropropene ug/L ND 20 17.1 86 70-130 Dibromochloromethane ug/L ND 20 17.1 85 70-130 Dibromomethane ug/L ND 20 17.7 89 70-130 Ethylbenzene ug/L ND 20 19.1 95 70-130 lodomethane ug/L ND 40 12.1 30 70-130 M1 Methylene Chloride ug/L ND 20 15.0 75 70-130 Styrene ug/L ND 20 18.2 91 70-130 Tetrachloroethene ug/L ND 20 18.5 93 70-130 Toluene ug/L ND 20 18.1 91 70-155 trans-1,2-Dichloroethene ug/L ND 20 16.0 80 70-130 trans- 1,3-Dichloropropene ug/L ND 20 16.9 85 70-130 trans-1,4-Dichloro-2-butene ug/L ND 20 15.2 76 70-130 Trichloroethene ug/L ND 20 18.3 92 69-151 Trichlorofluoromethane ug/L ND 20 14.2 71 70-130 Vinyl acetate ug/L ND 40 21.4 54 70-130 M1 Vinyl chloride ug/L ND 20 14.9 75 70-130 Xylene (Total) ug/L ND 60 57.2 95 70-130 1,2-Dichloroethane-d4 (S) % 80 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 94 70-130 SAMPLE DUPLICATE: 2414018 92404173004 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 SAMPLE DUPLICATE: 2414018 Parameter Units 92404173004 Result Dup Result 1,1-Dichloroethene ug/L ND ND 1,2,3-Trichloropropane ug/L ND ND 1,2-Dibromo-3-chloropropane ug/L ND ND 1,2-Dibromoethane (EDB) ug/L ND ND 1,2-Dichlorobenzene ug/L ND ND 1,2-Dichloroethane ug/L ND ND 1,2-Dichloropropane ug/L ND ND 1,4-Dichlorobenzene ug/L ND ND 1,4-Dioxane (p-Dioxane) ug/L ND ND 2-Butanone (MEK) ug/L ND ND 2-Hexanone ug/L ND ND 4-Methyl-2-pentanone (MIBK) ug/L ND ND Acetone ug/L ND ND Acrylonitrile ug/L ND ND Benzene ug/L ND ND Bromochloromethane ug/L ND ND Bromodichloromethane ug/L ND ND Bromoform ug/L ND ND Bromomethane ug/L ND ND Carbon disulfide ug/L ND ND Carbon tetrachloride ug/L ND ND Chlorobenzene ug/L ND ND Chloroethane ug/L ND ND Chloroform ug/L ND ND Chloromethane ug/L ND ND cis-1,2-Dichloroethene ug/L ND ND cis-1,3-Dichloropropene ug/L ND ND Dibromochloromethane ug/L ND ND Dibromomethane ug/L ND ND Ethylbenzene ug/L ND ND lodomethane ug/L ND ND Methylene Chloride ug/L ND ND Styrene ug/L ND ND Tetrachloroethene ug/L ND ND Toluene ug/L ND ND trans-1,2-Dichloroethene ug/L ND ND trans- 1,3-Dichloropropene ug/L ND ND trans-1,4-Dichloro-2-butene ug/L ND ND Trichloroethene ug/L ND ND Trichlorofluoromethane ug/L ND ND Vinyl acetate ug/L ND ND Vinyl chloride ug/L ND ND Xylene (Total) ug/L ND ND 1,2-Dichloroethane-d4 (S) % 85 85 4-Bromofluorobenzene (S) % 99 99 Toluene-d8 (S) % 97 97 Max RPD RPD Qualifiers 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 48 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 QC Batch: 437659 Analysis Method: EPA 8270D QC Batch Method: EPA 351 OC Analysis Description: 8270 Water MSSV RVE Associated Lab Samples: 92404173002 METHOD BLANK: 2406690 Matrix: Water Associated Lab Samples: 92404173002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Phenol ug/L ND 10.0 2.7 10/23/18 17:44 2,4,6-Tribromophenol (S) % 9 31-170 10/23/18 17:44 SO 2-Fluorobiphenyl (S) % 86 45-139 10/23/18 17:44 2-Fluorophenol (S) % 6 13-118 10/23/18 17:44 SO Nitrobenzene-d5 (S) % 82 40-121 10/23/18 17:44 Phenol-d6 (S) % 24 18-105 10/23/18 17:44 Terphenyl-d14 (S) % 101 48-146 10/23/18 17:44 LABORATORY CONTROL SAMPLE: 2406691 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phenol ug/L 50 31.7 63 10-120 2,4,6-Tribromophenol (S) % 85 31-170 2-Fluorobiphenyl (S) % 75 45-139 2-Fluorophenol(S) % 72 13-118 Nitrobenzene-d5 (S) % 73 40-121 Phenol-d6 (S) % 62 18-105 Terphenyl-d14 (S) % 85 48-146 MATRIX SPIKE SAMPLE: Parameter 2406692 Units 92404178001 Spike MS MS Result Conc. Result % Rec % Rec Limits Qualifiers Phenol ug/L 37.5 50 49.0 23 12-110 2,4,6-Tribromophenol (S) % 15 31-170 SO 2-Fluorobiphenyl (S) % 45 45-139 2-Fluorophenol(S) % 7 13-118 SO Nitrobenzene-d5 (S) % 160 40-121 SO Phenol-d6 (S) % 25 18-105 Terphenyl-d14 (S) % 82 48-146 SAMPLE DUPLICATE: 2406693 92404178002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Phenol ug/L ND ND 30 2,4,6-Tribromophenol (S) % 79 5 175 SO 2-Fluorobiphenyl (S) % 61 55 10 2-Fluorophenol (S) % 53 2 183 SO Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 49 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 SAMPLE DUPLICATE: 2406693 Parameter Nitrobenzene-d5 (S) Phenol-d6 (S) Terphenyl-d14 (S) QUALITY CONTROL DATA 92404178002 Dup Max Units Result Result RPD RPD Qualifiers % 66 55 19 42 8 138 SO % 89 83 6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 50 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 QC Batch: 437404 Analysis Method: EPA 180.1 Rev 2.0 1993 QC Batch Method: EPA 180.1 Rev 2.0 1993 Analysis Description: 180.1 Turbidity Associated Lab Samples: 92404173002, 92404173003, 92404173004, 92404173005, 92404173008, 92404173009, 92404173010, 92404173011,92404173012,92404173013 METHOD BLANK: 2405673 Matrix: Water Associated Lab Samples: 92404173002, 92404173003, 92404173004, 92404173005, 92404173008, 92404173009, 92404173010, 92404173011,92404173012,92404173013 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Turbidity NTU ND 1.0 0.50 10/20/18 01:30 LABORATORY CONTROL SAMPLE: 2405674 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Turbidity NTU 10 10.0 100 90-110 SAMPLE DUPLICATE: 2405675 92404175002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Turbidity NTU ND 0.53J 10 SAMPLE DUPLICATE: 2405676 92404173010 Dup Max Parameter Units Result Result RPD RPD Qualifiers Turbidity NTU 16.3 17.9 9 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 51 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 QC Batch: 437407 Analysis Method: EPA 180.1 Rev 2.0 1993 QC Batch Method: EPA 180.1 Rev 2.0 1993 Analysis Description: 180.1 Turbidity Associated Lab Samples: 92404173001, 92404173007, 92404173014, 92404173015, 92404173017 METHOD BLANK: 2405681 Matrix: Water Associated Lab Samples: 92404173001, 92404173007, 92404173014, 92404173015, 92404173017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Turbidity NTU ND 1.0 0.50 10/20/18 03:56 LABORATORY CONTROL SAMPLE: 2405682 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Turbidity NTU 10 10.0 100 90-110 SAMPLE DUPLICATE: 2405683 92404212002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Turbidity NTU ND ND 10 SAMPLE DUPLICATE: 2405684 92404173015 Dup Max Parameter Units Result Result RPD RPD Qualifiers Turbidity NTU 0.56J 0.511 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 52 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 QC Batch: 437406 Analysis Method: SM 521 OB-2011 QC Batch Method: SM 521OB-2011 Analysis Description: 5210E BOD, 5 day Associated Lab Samples: 92404173017 METHOD BLANK: 2405677 Matrix: Water Associated Lab Samples: 92404173017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers BOD, 5 day ug/L ND 2000 2000 10/25/18 01:20 LABORATORY CONTROL SAMPLE: 2405678 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day ug/L 198000 178000 90 84.6-115 SAMPLE DUPLICATE: 2405680 92404183001 Dup Max Parameter Units Result Result RPD RPD Qualifiers BOD, 5 day ug/L 1320 mg/L 1340000 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 53 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 QC Batch: 437499 Analysis Method: EPA 9040C QC Batch Method: EPA 9040C Analysis Description: 9040 pH Associated Lab Samples: 92404173017 SAMPLE DUPLICATE: 2406004 Parameter pH at 25 Degrees C SAMPLE DUPLICATE: 2406005 Parameter pH at 25 Degrees C 92403601001 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 6.9 7.1 3 9 H3 92404180001 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 6.5 6.5 0 9 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 54 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 QC Batch: 437704 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92404173017 METHOD BLANK: 2406821 Matrix: Water Associated Lab Samples: 92404173017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfate ug/L ND 1000 500 10/23/18 06:00 LABORATORY CONTROL SAMPLE: 2406822 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate ug/L 50000 47700 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2406823 2406824 MS MSD 92404072009 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 276 mg/L 50000 50000 321000 300000 91 49 90-110 7 10 M6 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2407163 2407164 MS MSD 92404339001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L ND 50000 50000 48900 48700 97 96 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 55 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 QC Batch: 437366 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92404173017 METHOD BLANK: 2405577 Matrix: Water Associated Lab Samples: 92404173017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Nitrate ug/L ND 20.0 10.0 10/20/18 00:26 LABORATORY CONTROL SAMPLE: 2405578 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate ug/L 1500 1490 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2405579 2405580 MS MSD 92404104001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate ug/L 1.3 mg/L 1500 1500 2880 2850 105 103 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 56 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 QC Batch: 437631 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Associated Lab Samples: 92404173017 METHOD BLANK: 2406581 Matrix: Water Associated Lab Samples: 92404173017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Phosphorus ug/L ND 50.0 25.0 10/22/18 20:41 LABORATORY CONTROL SAMPLE: 2406582 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus ug/L 2500 2540 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2406583 2406584 MS MSD 92403829001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus ug/L 0.40 mg/L 2500 2500 2970 2960 103 103 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2406585 2406586 MS MSD 92404172001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus ug/L 0.28 mg/L 2500 2500 2850 2860 103 103 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 57 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 QC Batch: 437677 Analysis Method: SM 5220D-2011 QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD Associated Lab Samples: 92404173017 METHOD BLANK: 2406749 Matrix: Water Associated Lab Samples: 92404173017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand ug/L ND 25000 12500 10/22/18 22:43 LABORATORY CONTROL SAMPLE: 2406750 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 750000 782000 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2406751 2406752 MS MSD 92403848004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 32.9 mg/L 100000 100000 138000 148000 105 115 90-110 7 3 M1,R1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2406753 2406754 MS MSD 92403887001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 52.9 mg/L 100000 100000 156000 161000 103 108 90-110 3 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 58 of 68 Pace Analytical Services, LLC aceAnalXical� 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS B2 Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. R1 RPD value was outside control limits. SO Surrogate recovery outside laboratory control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 59 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Surry. Co. Lined MSWLF Pace Project No.: 92404173 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92404173001 MW-1 EPA 3010A 437375 EPA6010D 437420 92404173002 MW-2 EPA 3010A 437375 EPA6010D 437420 92404173003 MW-3R EPA 3010A 437375 EPA6010D 437420 92404173004 MW-4S EPA 3010A 437375 EPA6010D 437420 92404173005 MW-41) EPA 3010A 437375 EPA6010D 437420 92404173006 MW-5 EPA 3010A 437375 EPA6010D 437420 92404173007 MW-6R EPA 3010A 437375 EPA6010D 437420 92404173008 MW-8 EPA 3010A 437375 EPA6010D 437420 92404173009 MW-9S EPA 3010A 437375 EPA6010D 437420 92404173010 MW-91) EPA 3010A 437375 EPA6010D 437420 92404173011 MW-10 EPA 3010A 437375 EPA6010D 437420 92404173012 MW-11S EPA 3010A 437375 EPA6010D 437420 92404173013 MW-11D EPA 3010A 437375 EPA6010D 437420 92404173014 MW-12 EPA 3010A 437375 EPA6010D 437420 92404173015 MW-13 EPA 3010A 437375 EPA6010D 437420 92404173017 LAGOON EPA 3010A 437375 EPA6010D 437420 92404173001 MW-1 EPA 3010A 437383 EPA 6020B 437428 92404173002 MW-2 EPA 3010A 437383 EPA 6020B 437428 92404173003 MW-3R EPA 3010A 437383 EPA 6020B 437428 92404173004 MW-4S EPA 3010A 437383 EPA 6020B 437428 92404173005 MW-41) EPA 3010A 437383 EPA 6020B 437428 92404173006 MW-5 EPA 3010A 437383 EPA 6020B 437428 92404173007 MW-6R EPA 3010A 437383 EPA 6020B 437428 92404173008 MW-8 EPA 3010A 437383 EPA 6020B 437428 92404173009 MW-9S EPA 3010A 437383 EPA 6020B 437428 92404173010 MW-91) EPA 3010A 437383 EPA 6020B 437428 92404173011 MW-10 EPA 3010A 437383 EPA 6020B 437428 92404173012 MW-11S EPA 3010A 437383 EPA 6020B 437428 92404173013 MW-11 D EPA 3010A 437383 EPA 6020B 437428 92404173014 MW-12 EPA 3010A 437383 EPA 6020B 437428 92404173015 MW-13 EPA 3010A 437383 EPA 6020B 437428 92404173017 LAGOON EPA 3010A 437383 EPA 6020B 437428 92404173017 LAGOON EPA 7470A 438027 EPA 7470A 438045 92404173002 MW-2 EPA 3510C 437659 EPA 8270D 437808 92404173001 MW-1 EPA 8260B 439207 92404173002 MW-2 EPA 8260B 439207 92404173003 MW-3R EPA 8260B 439207 92404173004 MW-4S EPA 8260B 439207 92404173005 MW-41) EPA 8260B 439207 92404173007 MW-6R EPA 8260B 439207 92404173008 MW-8 EPA 8260B 439207 92404173009 MW-9S EPA 8260B 439207 92404173010 MW-91) EPA 8260B 439207 92404173011 MW-10 EPA 8260B 439207 92404173012 MW-11S EPA 8260B 439207 92404173013 MW-11D EPA 8260B 439207 92404173014 MW-12 EPA 8260B 439207 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2018 04:52 PM without the written consent of Pace Analytical Services, LLC. Page 60 of 68 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Surry. Co. Lined MSWLF 92404173 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92404173015 MW-13 EPA 8260B 439207 92404173016 SW-D EPA 8260B 439207 92404173017 LAGOON EPA 8260B 439207 92404173001 MW-1 EPA 180.1 Rev 2.0 1993 437407 92404173002 MW-2 EPA 180.1 Rev 2.0 1993 437404 92404173003 MW-3R EPA 180.1 Rev 2.0 1993 437404 92404173004 MW-4S EPA 180.1 Rev 2.0 1993 437404 92404173005 MW-41) EPA 180.1 Rev 2.0 1993 437404 92404173007 MW-6R EPA 180.1 Rev 2.0 1993 437407 92404173008 MW-8 EPA 180.1 Rev 2.0 1993 437404 92404173009 MW-9S EPA 180.1 Rev 2.0 1993 437404 92404173010 MW-91) EPA 180.1 Rev 2.0 1993 437404 92404173011 MW-10 EPA 180.1 Rev 2.0 1993 437404 92404173012 MW-11S EPA 180.1 Rev 2.0 1993 437404 92404173013 MW-11 D EPA 180.1 Rev 2.0 1993 437404 92404173014 MW-12 EPA 180.1 Rev 2.0 1993 437407 92404173015 MW-13 EPA 180.1 Rev 2.0 1993 437407 92404173017 LAGOON EPA 180.1 Rev 2.0 1993 437407 92404173017 LAGOON SM 521 OB-2011 437406 SM 521 OB-2011 437409 92404173017 LAGOON EPA 9040C 437499 92404173017 LAGOON EPA 300.0 Rev 2.1 1993 437704 92404173017 LAGOON EPA 353.2 Rev 2.0 1993 437366 92404173017 LAGOON EPA 365.1 Rev 2.0 1993 437631 EPA 365.1 Rev 2.0 1993 437680 92404173017 LAGOON SM 5220D-2011 437677 SM 5220D-2011 437692 Date: 11/05/2018 04:52 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 61 of 68 Document Name: Document Revised: February 7, 2018 Sample Condition Upon Reteipt(SCUFR) Page 1 of 2 aceAnalXical Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville [IEden❑ Greenwood ❑ Huntersville ❑' Raleigh❑ Mechanicsville❑ SampleClient Name: W0� ; 924p4173 •Receipt Project AN Courier: []Fed Ex []UPS [:JLISPS [-]Client ❑ Commercial {Pare ❑Other: i Ii I 92404173 Custody Seal Present? ❑yes ❑No Seals Intact? ❑Yes ❑No Date/Initials Person Examining Contents:'' Packing Material: ❑Bubble Wrap []Bubble Bags ❑None ❑ Other Biological Tissue Frozen? Thermometer: [-]Yes �N/A Type of Ice: ❑Wet ❑Blue ❑None ❑ )a Gun ID: 92TO45 L Gaoler Temp {°C): _� , C. , ' f Correction Factor: Add/5ubtract (°C) _D l Temp should be above freezing to fi°C Cooler Temp Corrected ('C): J ❑Samples out of temp criteria. Samples on ice, cooling process has begun USDA Regulated Soll (j] N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, COMMENTS/SAMPLE DISCREPANCY { Field Data Required? ❑Yes ❑Na C lot 10 of sdititontainers: --- ._CLIENT Person contacted: Project Manager SCURF Review: �L Project Manager SRF Review: Date/Time: Date: 06 A 3 Date: / D f `T I Page 62 of 68 Document Name: a sample Condition Upon Recell Document No.: F•CAR-CS-033•Rev,06 "Check mark top half of box if pH and/or dechlorination Is verified and within the acceptance range for preservation samples. Exceptions: VOA, Caliform, TOC, Oil and Grease, DRO/8015 (water) DOC, tLHg "Bottom half of box is to list number of bottle Document Revised: February 7, 2018 Page i of 2 Issuing Authority: Pace Carolinas Quality Office_ Project # WO# : 92404173 PM: RWC Due Date: 11/02/18 CLIENT: 92-IMunicioal E m u Z W W G a r= u e E LALn .. der d m m do d e. c u E N m a m N N N a c u E O ,n N a cc Z -a m 2 ;U a ._�+ a N V r C O N = E N n a a I*com N V Y Q M O z Y A E N rd d Z (U {9 U a z N U E N N a a u w N A _ e. 2 p m Z u E N r d cc y C �, N m t cE v a Z v a v Q `m ,-, l7 w V C u _ E Q a .ti l7 y a 0 C ¢ J E N l7 jV V Y a 7 l] N _ v ,.., 1a L7 N 2 a et a 2 a g Q E N l9 a Z 2 Z `y E ¢ E m l7 2 U x a E l7 o a ? T z J E > z n 7 a 6 E m l7 a — 2 -Cr-Cra O m z a O E a ai U' C Q Z Y ,n a r -W d A Q O > ¢ Z Y A ` = y ° > A Q z u a m J E a a Z u w a m s r f: N N a v T S N N 2 'N ! E N a m b 2 v y a 7 a ¢ E p $ tm7 C \ ? i m v, J E O vi v N v itl EE J E 4 q W 6 1 � NN' 2 X/ I \N�l 3 i \N\ I N \�\N 4 �N J j fi d\ 7 � { 1 J I 1 NN B N 1\1 NN 10 J 11 I l� 12 JNNI f' Sample ID I Typeaf Preservative ,tipkN-� I A N pH Adjustment tog for Preserved- Samples - pN upon receipt Date preservation adjusted Time preservation adjusted 5 S I [ (ct- i } Amount of Preservative added , (--), ^ L Lot # Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certiflcatian Office (Le. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 63 of 68 Document Name: Sample Condition Upon Retell Document No.: F-CAR-CS-033-Rev,06 *Check mark top half of box if pH and/or dechlorination Is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg ** Bottom half of box is to list number of bottle Document Revised: February 7, 2019 Page 1 of 2 issuing Authority: Pace Carolinas Quality Office Project # WO# : 92404173 PH: RWC Due Date: 11/02/18 CLIENT: 92-Municipal pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Rate preservation adjusted Time preservation Amount of Preservative Lot # adjusted added Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office lLe. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 64 of 68 Document Name: Sample [onditlan Upon Recell Analytical Document No.: F-CAR-CS-033•Rev-06 *Check mark top half of box if pH and/or dechlorination Is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/9015 (water) DOC, LLH9 **Bottom half of box is to list number of battle Document Revised: February 1, 2019 Page 1 of 2 Issuing Authority: Pace Carolinas Quality Office Project: IWO# : 92404173 I'M: RWC Due Date: 11/02/18 CLIENT: 92-Municipal pH Adjustment Log for Preserved Samples Sample 1D Type of Preservat{ve pH upon receipt Date preservation adjusted alma preservation Amount of added ervative Lot 0 adjusted Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will he sent to the North Cacopna DEHNR Certification Office (Le. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 65 of 68 a3 +n a o n m ° a 3 n w a� m en a w N ITEM# O -, .. m o ro N ti a - ➢ cp'i rp 3 3 3 ❑ Z O ?o m vt N ry p 'i7 ❑ rn A ❑ ni 8 O C7+ Q ] c v e N m D m v q N co �. D q .-. C1 a Y O c+ x v O N ICI o� -0 C j (4 icon 10 n v� . z R°, i ow0 b �Y 9 m © o ro r0 O C c _ r 9 a x O x m rb rn L v n' v ro � N N tp Y_`{p_NVif 4y a n o n o m n no a m n a v a ,n, r o C / a m m O a O 4 m O a O v a o _ Z MA7RIX CODE (see valftl codes to IefI) � c o � U A G 7 C O O G] SAMPLE TYPE {G=GRA9 C=COAIPJ q� Cl x m 2 - a v ❑ o a n A " -� n m z z P Y m m C�q ro n C O 3 D R 3 m m m z y r Uj m O a n° 3 N C- �' m 0 -n m m ui m SAMPLE TEMP AT COLLECTION p m # OF CONTAINERS a a a D 0 Y 5 w 0 m n 3 o O- 'C C Unpreserved o o K- ?� .N.� O m H2504 0 a ° 0 HNO3 m a n v ❑ HCI CID m n' _ 0 .. y IT Cn1 MR Na25203 ( 7 m m l a � Methanol u�� m m Q1 �= n m WOther d� D = n Analyses Test YIN Cn ro cD 70 m < tp r x x x x x x x VOCs-6260 App 1 z P x N � x x x x x x x x x x Metals-App I Z m CD m x o z xCD x x x Turbidity n c°n N N x x x x x Phenol (108-95-2) SVOC z � N ,� a �v ^ O o :7 m � N o U-1 — Q y 3 N - m a Z C ' m o S m c m (9 _ o TEMP in CLn n Received on Ice (YIN) m m n Custody Sealed Cooler(Y)NyL I- z l� fn1 Q z DL l� w Samples Intact TT (YIN) Page 66 of 68 a v 0 z z D n 0 re z N m 1� z i C r m G { n v, 3 m � UN p z z z o z z Z m m a n z O D ➢ � � W D v !� m z m m z m m A t � � 1 c ran y L O � -1 m O A n n -� m tJ ° �1 go A T 11 T a � m T ro n Z ° _ In d _ V J -3 m TEMP in C a Received on b Ice (YIN) m n C Custody Sealed Co❑ler (YJN) C z v Samples Intact - in A w ITEM# O � n c � w v O A:{_Otnv ti F U A n n u 2 A o {` m O➢ ❑ N v��� D A 9 r m F.1ATRIX CODE (See valid codes la left) SI 0 0SAF.IPLE TYPE (G=GRAB C=COMP) O D rn m In 4 a 3 m `, ' > m z m v� SAMPLE TEMP AT COLLECTION # OF CONTAINERS Unpreserved H2SC4 HNO3 a w HCI NaOH Na2S2O3 Methanol Other Analyses Test x m a n A'n m 7 a s p N N o n❑ a D ° Z n }� n C O ry �J — to con N (a 0m c n oW4 Ln � 3 _. n O r m n fn � � m ° r n _ D �Z C O VN w m m a 3 ncn m a o Er 4 .CL C: V o C)0 m m n w c m D N t� 0 C C Ls N K m (D Z n m m n m YIN � m OEM ME ME 0 ESE MEN ��■iuiiE■MEN ONE � � M ONE ME MMEME ME MOONS MESON MOEN EMEMEN 1 G �^^ :5 n Y m W o � a13 y rr C ❑ a O n 0 w 0 C N T n z c n _ O s m O n (G o m b 3 La n K N O m Page 67 of 68 m-u m o a o m m ITEIVIfi o w a 3 a ,� a cL n o O m Q V v e yy�� ID —�0 O p50 " u N N pnj N G W m a C [D n V Z n 13 m m o (. 0 c 1Crn C T 3 rn Q x O s= -z+ Ill C Ip N ut �an�ouagoo� o one omm(nn 0 m S xi O m 0 m Z a 0 a m a O M 6IATRIXCOOE Isee Valid codBS la l¢fl) z o 0 SAMPLE TYPE (G-GRAB C=COMP) L S c C O l - c m T� W n m a s n U y i n r m ic G7 m r m n Z z w CA)T us r- c C W y y C- m m m m o A 2 ❑ Vs n n z o z 2 a > { !i m m m �� m A v C SAMPLE TEMP AT COLLECTION m y m m a o D �_ p OF CONTAINERS i 1 m V m v p a m m 3 a d 9 o �y Unpreserved m o s', a ? n m H2SO4 M' n V o 7 dk -3 OS HNO3 m 0 N P C o HCI m S ! D NaOH rLj m 1Ji m Na2S203 N mMethanol W ro m o w m m Other { Test YIN TAnalyses " r Cl) 2 x VOCs-App1 z D n' Ivy X Metals-App 2 (Includes Hg) z m O x BOD z c m z x COD z N � a a x NITRATE z a X. c x PHOSPHORUS z d w U r 0 -i - x Ph z r = m x Suifate a m /Q a ti _I Z n 1+o x Turbidity m ii N z Z fA v e TEMP in C _ T d c m /� 'o $ o Uo Received on Ice (YIN) r- K m D Custody Sealed p rl Cooler {Y1N) r O z N " "� Samples Intact - a n Page 68 of 68 lacieAnalXical" www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 November 26, 2018 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: SURRY Co. LINED MSWLF Pace Project No.: 92408107 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on November 20, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Trey Carter trey. carter@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Maddie German, Municipal Engineering Services REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 15 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Project: SURRY Co. LINED MSWLF Pace Project No.: 92408107 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 South Carolina Certification #: 99006001 Louisiana/NELAP Certification # LA170028 Florida/NELAP Certification #: E87627 North Carolina Drinking Water Certification #: 37706 Kentucky UST Certification #: 84 North Carolina Field Services Certification #: 5342 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 15 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: SURRY Co. LINED MSWLF Pace Project No.: 92408107 Lab ID Sample ID Matrix Date Collected Date Received 92408107001 MW-5 Water 11/10/1811:55 11/20/1815:33 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 15 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: SURRY Co. LINED MSWLF Pace Project No.: 92408107 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92408107001 MW-5 EPA 8260E GAW 51 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 15 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY Co. LINED MSWLF Pace Project No.: 92408107 Sample: MW-5 Lab ID: 92408107001 Collected: 11/10/18 11:55 Received: 11/20/18 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Date: 11/26/2018 03:10 PM Analytical Method: EPA 8260E ND ug/L 25.0 10.0 1 11/21/1813:25 67-64-1 ND ug/L 10.0 1.9 1 11/21/1813:25 107-13-1 ND ug/L 1.0 0.25 1 11/21/1813:25 71-43-2 ND ug/L 1.0 0.17 1 11/21/1813:25 74-97-5 ND ug/L 1.0 0.18 1 11/21/1813:25 75-27-4 ND ug/L 1.0 0.26 1 11/21/1813:25 75-25-2 ND ug/L 2.0 0.29 1 11/21/1813:25 74-83-9 ND ug/L 5.0 0.96 1 11/21/1813:25 78-93-3 ND ug/L 2.0 1.2 1 11/21/1813:25 75-15-0 ND ug/L 1.0 0.25 1 11/21/1813:25 56-23-5 ND ug/L 1.0 0.23 1 11/21/1813:25 108-90-7 ND ug/L 1.0 0.54 1 11/21/1813:25 75-00-3 ND ug/L 1.0 0.14 1 11/21/1813:25 67-66-3 ND ug/L 1.0 0.11 1 11/21/1813:25 74-87-3 ND ug/L 2.0 2.0 1 11/21/1813:25 96-12-8 ND ug/L 1.0 0.21 1 11/21/1813:25 124-48-1 ND ug/L 1.0 0.27 1 11/21/1813:25 106-93-4 ND ug/L 1.0 0.21 1 11/21/1813:25 74-95-3 ND ug/L 1.0 0.30 1 11/21/1813:25 95-50-1 ND ug/L 1.0 0.33 1 11/21/1813:25 106-46-7 ND ug/L 1.0 1.0 1 11/21/1813:25 110-57-6 ND ug/L 1.0 0.32 1 11/21/1813:25 75-34-3 ND ug/L 1.0 0.24 1 11/21/1813:25 107-06-2 ND ug/L 1.0 0.56 1 11/21/1813:25 75-35-4 0.95J ug/L 1.0 0.19 1 11/21/1813:25 156-59-2 ND ug/L 1.0 0.49 1 11/21/1813:25 156-60-5 ND ug/L 1.0 0.27 1 11/21/1813:25 78-87-5 ND ug/L 1.0 0.13 1 11/21/1813:25 10061-01-5 ND ug/L 1.0 0.26 1 11/21/1813:25 10061-02-6 ND ug/L 150 78.4 1 11/21/1813:25 123-91-1 ND ug/L 1.0 0.30 1 11/21/1813:25 100-41-4 ND ug/L 5.0 0.46 1 11/21/1813:25 591-78-6 ND ug/L 5.0 0.32 1 11/21/1813:25 74-88-4 ND ug/L 1.0 0.97 1 11/21/1813:25 75-09-2 ND ug/L 5.0 0.33 1 11/21/1813:25 108-10-1 ND ug/L 1.0 0.26 1 11/21/1813:25 100-42-5 ND ug/L 1.0 0.33 1 11/21/1813:25 630-20-6 ND ug/L 1.0 0.40 1 11/21/1813:25 79-34-5 ND ug/L 1.0 0.46 1 11/21/1813:25 127-18-4 ND ug/L 1.0 0.26 1 11/21/1813:25 108-88-3 ND ug/L 1.0 0.48 1 11/21/1813:25 71-55-6 ND ug/L 1.0 0.29 1 11/21/1813:25 79-00-5 ND ug/L 1.0 0.47 1 11/21/1813:25 79-01-6 ND ug/L 1.0 0.20 1 11/21/1813:25 75-69-4 ND ug/L 1.0 0.41 1 11/21/1813:25 96-18-4 ND ug/L 2.0 0.35 1 11/21/1813:25 108-05-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 15 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY Co. LINED MSWLF Pace Project No.: 92408107 Sample: MW-5 Lab ID: 92408107001 Collected: 11/10/18 11:55 Received: 11/20/18 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Vinyl chloride ND ug/L 1.0 0.62 1 11/21/18 13:25 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 11/21/18 13:25 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 100 % 70-130 1 11/21/18 13:25 460-00-4 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 11/21/18 13:25 17060-07-0 Toluene-d8 (S) 98 % 70-130 1 11/21/18 13:25 2037-26-5 Date: 11/26/2018 03:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 15 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY Co. LINED MSWLF Pace Project No.: 92408107 QC Batch: 443622 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill Associated Lab Samples: 92408107001 METHOD BLANK: 2433977 Associated Lab Samples: 92408107001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.33 11/21/18 12:21 1,1,1-Trichloroethane ug/L ND 1.0 0.48 11/21/18 12:21 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.40 11/21/18 12:21 1,1,2-Trichloroethane ug/L ND 1.0 0.29 11/21/18 12:21 1,1-Dichloroethane ug/L ND 1.0 0.32 11/21/18 12:21 1,1-Dichloroethene ug/L ND 1.0 0.56 11/21/18 12:21 1,2,3-Trichloropropane ug/L ND 1.0 0.41 11/21/18 12:21 1,2-Dibromo-3-chloropropane ug/L ND 2.0 2.0 11/21/18 12:21 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 11/21/18 12:21 1,2-Dichlorobenzene ug/L ND 1.0 0.30 11/21/18 12:21 1,2-Dichloroethane ug/L ND 1.0 0.24 11/21/18 12:21 1,2-Dichloropropane ug/L ND 1.0 0.27 11/21/18 12:21 1,4-Dichlorobenzene ug/L ND 1.0 0.33 11/21/18 12:21 1,4-Dioxane (p-Dioxane) ug/L ND 150 78.4 11/21/18 12:21 2-Butanone (MEK) ug/L ND 5.0 0.96 11/21/18 12:21 2-Hexanone ug/L ND 5.0 0.46 11/21/18 12:21 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 0.33 11/21/18 12:21 Acetone ug/L ND 25.0 10.0 11/21/18 12:21 Acrylonitrile ug/L ND 10.0 1.9 11/21/18 12:21 Benzene ug/L ND 1.0 0.25 11/21/18 12:21 Bromochloromethane ug/L ND 1.0 0.17 11/21/18 12:21 Bromodichloromethane ug/L ND 1.0 0.18 11/21/18 12:21 Bromoform ug/L ND 1.0 0.26 11/21/18 12:21 Bromomethane ug/L ND 2.0 0.29 11/21/18 12:21 Carbon disulfide ug/L ND 2.0 1.2 11/21/18 12:21 Carbon tetrachloride ug/L ND 1.0 0.25 11/21/18 12:21 Chlorobenzene ug/L ND 1.0 0.23 11/21/18 12:21 Chloroethane ug/L ND 1.0 0.54 11/21/18 12:21 Chloroform ug/L ND 1.0 0.14 11/21/18 12:21 Chloromethane ug/L ND 1.0 0.11 11/21/18 12:21 cis-1,2-Dichloroethene ug/L ND 1.0 0.19 11/21/18 12:21 cis-1,3-Dichloropropene ug/L ND 1.0 0.13 11/21/18 12:21 Dibromochloromethane ug/L ND 1.0 0.21 11/21/18 12:21 Dibromomethane ug/L ND 1.0 0.21 11/21/18 12:21 Ethylbenzene ug/L ND 1.0 0.30 11/21/18 12:21 lodomethane ug/L ND 5.0 0.32 11/21/18 12:21 Methylene Chloride ug/L ND 1.0 0.97 11/21/18 12:21 Styrene ug/L ND 1.0 0.26 11/21/18 12:21 Tetrachloroethene ug/L ND 1.0 0.46 11/21/18 12:21 Toluene ug/L ND 1.0 0.26 11/21/18 12:21 trans-1,2-Dichloroethene ug/L ND 1.0 0.49 11/21/18 12:21 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /26/2018 03:10 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 15 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY Co. LINED MSWLF Pace Project No.: 92408107 METHOD BLANK: 2433977 Associated Lab Samples: 92408107001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL trans- 1,3-Dichloropropene ug/L ND 1.0 trans-1,4-Dichloro-2-butene ug/L ND 1.0 Trichloroethene ug/L ND 1.0 Trichlorofluoromethane ug/L ND 1.0 Vinyl acetate ug/L ND 2.0 Vinyl chloride ug/L ND 1.0 Xylene (Total) ug/L ND 1.0 1,2-Dichloroethane-d4 (S) % 98 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8(S) % 104 70-130 Analyzed 0.26 11/21/18 12:21 1.0 11/21/18 12:21 0.47 11/21/18 12:21 0.20 11/21/18 12:21 0.35 11/21/18 12:21 0.62 11/21/18 12:21 0.66 11/21/18 12:21 11/21/18 12:21 11/21/18 12:21 11/21/18 12:21 LABORATORY CONTROL SAMPLE: Parameter 2433978 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 49.2 98 70-130 1,1,1-Trichloroethane ug/L 50 49.2 98 70-130 1,1,2,2-Tetrachloroethane ug/L 50 48.7 97 70-130 1,1,2-Trichloroethane ug/L 50 50.5 101 70-130 1,1-Dichloroethane ug/L 50 48.4 97 70-130 1,1-Dichloroethene ug/L 50 48.2 96 70-130 1,2,3-Trichloropropane ug/L 50 49.3 99 70-130 1,2-Dibromo-3-chloropropane ug/L 50 46.5 93 70-130 1,2-Dibromoethane (EDB) ug/L 50 48.3 97 70-130 1,2-Dichlorobenzene ug/L 50 47.4 95 70-130 1,2-Dichloroethane ug/L 50 46.0 92 70-130 1,2-Dichloropropane ug/L 50 47.2 94 70-130 1,4-Dichlorobenzene ug/L 50 45.6 91 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1040 104 59-169 2-Butanone (MEK) ug/L 100 97.8 98 64-135 2-Hexanone ug/L 100 100 100 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 98.0 98 70-130 Acetone ug/L 100 105 105 61-157 Acrylonitrile ug/L 250 239 96 61-143 Benzene ug/L 50 50.2 100 70-130 Bromochloromethane ug/L 50 49.0 98 70-130 Bromodichloromethane ug/L 50 50.0 100 70-130 Bromoform ug/L 50 46.4 93 70-130 Bromomethane ug/L 50 39.6 79 38-128 Carbon disulfide ug/L 50 45.4 91 68-130 Carbon tetrachloride ug/L 50 50.0 100 70-130 Chlorobenzene ug/L 50 48.7 97 70-130 Chloroethane ug/L 50 50.0 100 37-142 Chloroform ug/L 50 47.7 95 70-130 Chloromethane ug/L 50 45.9 92 48-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /26/2018 03:10 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 15 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY Co. LINED MSWLF Pace Project No.: 92408107 LABORATORY CONTROL SAMPLE: Parameter 2433978 Units Spike Conc. LCS Result LCS % Rec % Rec Limits cis-1,2-Dichloroethene ug/L 50 48.5 97 70-130 cis-1,3-Dichloropropene ug/L 50 50.9 102 70-130 Dibromochloromethane ug/L 50 51.0 102 70-130 Dibromomethane ug/L 50 49.7 99 70-130 Ethylbenzene ug/L 50 48.8 98 70-130 lodomethane ug/L 100 102 102 40-124 Methylene Chloride ug/L 50 50.3 101 67-132 Styrene ug/L 50 48.9 98 70-130 Tetrachloroethene ug/L 50 48.3 97 69-130 Toluene ug/L 50 46.9 94 70-130 trans-1,2-Dichloroethene ug/L 50 48.2 96 70-130 trans- 1,3-Dichloropropene ug/L 50 50.0 100 70-130 trans-1,4-Dichloro-2-butene ug/L 50 52.1 104 35-189 Trichloroethene ug/L 50 46.5 93 70-130 Trichlorofluoromethane ug/L 50 47.6 95 63-126 Vinyl acetate ug/L 100 102 102 55-143 Vinyl chloride ug/L 50 44.7 89 70-131 Xylene (Total) ug/L 150 146 97 70-130 1,2-Dichloroethane-d4 (S) % 102 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 99 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2433979 MS 92408107001 Spike Parameter Units Result Conc. MSD Spike Conc. 2433980 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 21.0 21.5 105 107 73-134 2 30 1,1,1-Trichloroethane ug/L ND 20 20 21.1 22.8 105 114 82-143 8 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 20.9 21.8 104 109 70-136 4 30 1,1,2-Trichloroethane ug/L ND 20 20 20.5 20.6 103 103 70-135 0 30 1,1-Dichloroethane ug/L ND 20 20 20.4 22.6 102 113 72-139 10 30 1,1-Dichloroethene ug/L ND 20 20 22.4 24.3 112 121 81-154 8 30 1,2,3-Trichloropropane ug/L ND 20 20 20.7 20.7 104 103 71-137 0 30 1,2-Dibromo-3- ug/L ND 20 20 18.6 22.4 93 112 65-134 18 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 20.1 21.0 100 105 72-137 4 30 1,2-Dichlorobenzene ug/L ND 20 20 20.9 21.7 104 109 70-133 4 30 1,2-Dichloroethane ug/L ND 20 20 19.5 20.9 98 104 73-137 7 30 1,2-Dichloropropane ug/L ND 20 20 20.7 21.4 104 107 79-140 3 30 1,4-Dichlorobenzene ug/L ND 20 20 20.5 21.5 102 108 70-133 5 30 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 359 410 90 103 53-168 13 30 2-Butanone (MEK) ug/L ND 40 40 40.6 44.2 102 111 60-139 8 30 2-Hexanone ug/L ND 40 40 43.1 44.0 108 110 65-138 2 30 4-Methyl-2-pentanone ug/L ND 40 40 41.1 42.6 103 107 65-135 4 30 (MIBK) Acetone ug/L ND 40 40 41.7 47.2 104 118 60-148 12 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result Date: 11/26/2018 03:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 15 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY Co. LINED MSWLF Pace Project No.: 92408107 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2433979 2433980 MS MSD 92408107001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acrylonitrile ug/L ND 100 100 94.5 104 95 104 64-147 10 30 Benzene ug/L ND 20 20 22.3 23.0 111 115 72-151 3 30 Bromochloromethane ug/L ND 20 20 20.1 21.3 101 107 77-141 6 30 Bromodichloromethane ug/L ND 20 20 21.2 21.0 106 105 76-138 1 30 Bromoform ug/L ND 20 20 18.2 18.7 91 94 63-130 3 30 Bromomethane ug/L ND 20 20 19.4 20.4 97 102 15-152 5 30 Carbon disulfide ug/L ND 20 20 19.4 21.7 97 108 69-149 11 30 Carbon tetrachloride ug/L ND 20 20 22.1 23.0 111 115 70-143 4 30 Chlorobenzene ug/L ND 20 20 21.3 21.3 106 107 70-138 0 30 Chloroethane ug/L ND 20 20 20.3 21.8 101 109 52-163 7 30 Chloroform ug/L ND 20 20 20.2 22.0 101 110 74-139 8 30 Chloromethane ug/L ND 20 20 18.6 20.0 93 100 41-139 7 30 cis-1,2-Dichloroethene ug/L 0.95J 20 20 22.3 23.3 107 112 77-141 4 30 cis-1,3-Dichloropropene ug/L ND 20 20 21.0 22.7 105 113 74-137 8 30 Dibromochloromethane ug/L ND 20 20 21.1 21.0 105 105 70-134 0 30 Dibromomethane ug/L ND 20 20 19.8 20.8 99 104 76-138 5 30 Ethylbenzene ug/L ND 20 20 22.1 22.2 110 111 66-153 1 30 lodomethane ug/L ND 40 40 43.1 44.4 108 111 20-138 3 30 Methylene Chloride ug/L ND 20 20 21.9 23.4 110 117 42-159 7 30 Styrene ug/L ND 20 20 20.9 21.0 105 105 70-135 0 30 Tetrachloroethene ug/L ND 20 20 21.8 21.8 109 109 59-143 0 30 Toluene ug/L ND 20 20 20.9 22.3 105 112 59-148 6 30 trans-1,2-Dichloroethene ug/L ND 20 20 21.4 22.8 107 114 76-146 7 30 trans-1,3-Dichloropropene ug/L ND 20 20 20.5 21.3 102 107 71-135 4 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 19.7 19.9 99 100 47-135 1 30 Trichloroethene ug/L ND 20 20 19.9 21.3 100 107 77-147 7 30 Trichlorofluoromethane ug/L ND 20 20 21.6 23.3 108 117 76-148 8 30 Vinyl acetate ug/L ND 40 40 40.0 44.2 100 111 49-151 10 30 Vinyl chloride ug/L ND 20 20 22.1 23.2 110 116 70-156 5 30 Xylene (Total) ug/L ND 60 60 66.2 66.0 110 110 63-158 0 30 1,2-Dichloroethane-d4 (S) % 98 101 70-130 4-Bromofluorobenzene (S) % 104 97 70-130 Toluene-d8 (S) % 100 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /26/2018 03:10 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 15 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: SURRY Co. LINED MSWLF Pace Project No.: 92408107 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-C Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /26/2018 03:10 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 15 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: SURRY Co. LINED MSWLF Pace Project No.: 92408107 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92408107001 MW-5 EPA 8260B 443622 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /26/2018 03:10 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 15 aceArralytrcal � Document Name: Sample Condition Upon Receipt(SCUR) Document Revised: February 7, 2019 Page 1 of 2 Document No.: F-CAR-CS-033-Rev.06 Issuing Authority: Pace Carolinas Quality Office Laboratory receiving samples; Asheville ❑ Eden[] Greenwood ❑ Huntersville 0 Raleigh❑ Mechanicsville❑ Sample Condition Client Name: WO# • 9240s 107 Upon Receipt Project #i; `. II�II III IlIII II! II Courier: []Fed Ex ❑UPS ❑USPS []Client ❑ Commercial 'POace ❑Other; 92408107 Custody Seal Present? ❑Yes []NO seals Intact? ❑Yes ❑No G Date/Initials Person Examining Contents; A Packing Material: ❑Bubble Wrap 061ble Bags ❑None ❑ Other Thermometer; Type of Ice: []Wet [:]Blue QIR Gun 111 92TD45 Cooler Temp ('C): > . Correction Factor: Add/Subtract ('C) _0 Cooler Temp Corrected ('C); 1 -7 Biological Tissue Frozen? [:]Yes []NO RN/ -A []Noce Temp should be above freezing to 6'C ❑Samples out of temp criteria. Samples on ice, cooling process has begun USDA Regulated Soil (E)IN/A, water sample) Did samples originate in a"quaran tine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source linternatlonaUy, ❑YsN e U�Tu comments/Discrepancy: Chain of Custody Present? ❑Yes ONO ❑N/A 1, Samples Arrived within Hold Time? ❑Yes ❑No ❑N/A 2, Short Hold Time Analysts (c72 hr.I? Dyes ONO ❑N/A 3. Rush Turn Around Time Requested? ❑Yes ❑Na ❑N/A 4. Sufficient Volume? []Yes []No ❑N/A 5. Correct Containers Used? ❑Yes []No ❑N/A 6, -Pace Containers Used? be ❑Na ❑N/A Containers Intact? []Yes ❑No ❑NIA _ - 7, Dissolved analysis; Samples Field Filtered? ❑- ❑No ❑b/A B. Sample Labels Match COC? ,]Yes U yes ❑No ❑NIA 9. -Includes Date/Time/ID/Analysis Matrix: Headspace in VOA Vials (>5-6mm)? ❑Yes ❑No ❑NIA 10. Trip Blank Present? ❑Yes ❑No ❑N/A 11. Trip Blank Custody Seals Present? ❑Yes ❑ND ❑NIA COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RE50LLITION Person contacted: Date/Time: Field Data Required? ❑Yes ❑No Project Manager SCURF Review: -rL Date: 1 I /Z,A Project Manager SRF Review: - �fc Date: a I 2 PA — Page 13 of 15 Document Name: (:ondltion Upon Recel Document No.: F•CAR-CS-033•Rev,06 *Check mark top half of box if pH and/or dechlorination Is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/9015 (water) DOC, LLHg **Bottom half of box is to list number of bottle Document Revised: February 7, 2018 CUR) Page 1 of 2 Issuing Authority: Pace Carolinas Quality Office Project � IWo# ; 92408107 i3Due Dale: 12/06/18 UIENT'. 92-Municipal ua Z W a C u io E a CM 2 Gi a 7 �a a E m Q Z Ql a 5 a E m m a m u V CS In i 2 E N � m V p Z = a E N m o Z ¢ N ,o E N m V nl n 2 O Z 'a a E N M m N aZ = _m l7 o E .0 =. 3 R m `p E ¢ a a ry n `� E < m` .i a Z � c Q E O Q a v = c E Q m n 0 a a =di a O N E ¢ E n W a 2 _ Z 0 E E o ry m a z Q O E 1 l7 o Z 0 N q 0 � E °.Ni Y ~mM 0 s ? Q 0 E L9 a Q ? O } E m L9 ❑ _ Z .1L m p C. 4 O } l7 = 7 a m > a x m E Z N m E O M1 y DvY N r Z E N z T �' v a j E N c ❑ E O uaQaa z m Z v a C E i 1N\l 2 \\N 3 \\\N 4 \L,\N 5 6 7 N\N� 8 9 10 ]1 12 NN- pH Adjustment Log for Preserved Samples Sample IR Type of Preservative pH upon receipt Date preservation adjusted Tlme preservation Amount of Preservative Let a adjusted added Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will he sent to the North Carolina DEHNR Certification Office (Le. Out of hold, incorrect preservative, out of temp, incorrecT containers Page 14 of 15 m m G) a o A M -4 0 ar a w N j ITEM# o ". ° y a "- p N w o a n n g v C U En oO V7 N ^ f41 D N m 2: N ❑. O ❑ ELD= toX Ln N v .. — D o ut IV : �e� W �o ",m7 ❑ n �°; oW 0 0 ��� m a o 3 (. m c o ox v� Io N N ' — c mJ A N m 0 0 m n y Oy D O y O ? N N -4 C G p m p © p a m m MATRIX CODE (see vald codes Io li z Z Q Z 0 0 o � � o uy L) SA1.IPLE TYPE (G=G Rn6 C=COA1P) u` rr w v C% { o o — n D r Q. n 6) m r m Z D Z z A z Q rn C w > -ni G m❑ �r"I m o m m x] m 3 W G; m r z m m m A 1 ` SAh1 PILE TEAIPAT COLLECTION m m a 0 o r p OF CONTAINERS lJnpreserved O _- �, 7 m o o a i12SO4 m D o' w NG1 m m r ? O NaOH 0 a Na2S203 mfTI Methanol a� m m s N Other m 5' Analyses Test YIN ��J `y x VOCs-8280 App I z 1,4-Dioxane z z p to a N n a rj n D 7 a N � T t m n (� •R Z m m y Z o 3 w m c w LIM TEMP in C Cfs m c m Dw o w 7 > n Received an Ice{VN) m n z Custody Sealed p UUU O Cooler (YIN) O m Samples Intact (YIN) m � < (D rb a N rt _ O r0 r O CD m 3 Q m h C N r0 Page 15 of 15 lacieAnalXical" www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 November 01, 2018 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: Surry Blanks Pace Project No.: 92404409 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on October 23, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Trey Carter trey. carter@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Maddie German, Municipal Engineering Services REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Blanks Pace Project No.: 92404409 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Surry Blanks Pace Project No.: 92404409 Lab ID Sample ID Matrix Date Collected Date Received 92404409001 92404409002 EB FIB Water Water 10/19/18 05:00 10/19/18 05:10 10/23/18 07:00 10/23/18 07:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Surry Blanks 92404409 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92404409001 EB EPA 6010D SH1 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E GAW 51 PASI-C 92404409002 FIB EPA 8260E GAW 51 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Blanks Pace Project No.: 92404409 Sample: EB Lab ID: 92404409001 Collected: 10/19/18 05:00 Received: 10/23/18 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 11/01/2018 02:13 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 10/24/18 02:55 10/26/18 04:12 7440-36-0 ND ug/L 10.0 5.0 1 10/24/18 02:55 10/26/18 04:12 7440-38-2 ND ug/L 5.0 2.5 1 10/24/18 02:55 10/26/18 04:12 7440-39-3 ND ug/L 1.0 0.50 1 10/24/18 02:55 10/26/18 04:12 7440-41-7 ND ug/L 1.0 0.50 1 10/24/18 02:55 10/26/18 04:12 7440-43-9 ND ug/L 5.0 2.5 1 10/24/18 02:55 10/26/18 04:12 7440-47-3 ND ug/L 5.0 2.5 1 10/24/18 02:55 10/26/18 04:12 7440-48-4 ND ug/L 5.0 2.5 1 10/24/18 02:55 10/26/18 04:12 7440-50-8 ND ug/L 5.0 2.5 1 10/24/18 02:55 10/26/18 04:12 7439-92-1 ND ug/L 5.0 2.5 1 10/24/18 02:55 10/26/18 04:12 7440-02-0 ND ug/L 10.0 5.0 1 10/24/18 02:55 10/26/18 04:12 7782-49-2 ND ug/L 5.0 2.5 1 10/24/18 02:55 10/26/18 04:12 7440-22-4 ND ug/L 5.0 2.5 1 10/24/18 02:55 10/26/18 04:12 7440-62-2 ND ug/L 10.0 5.0 1 10/24/18 02:55 10/26/18 04:12 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.020 1 10/24/18 04:30 10/25/18 03:51 7440-28-0 Analytical Method: EPA 8260E ND ug/L 25.0 10.0 1 10/31/1816:01 67-64-1 ND ug/L 10.0 1.9 1 10/31/1816:01 107-13-1 ND ug/L 1.0 0.25 1 10/31/1816:01 71-43-2 ND ug/L 1.0 0.17 1 10/31/1816:01 74-97-5 ND ug/L 1.0 0.18 1 10/31/1816:01 75-27-4 ND ug/L 1.0 0.26 1 10/31/1816:01 75-25-2 ND ug/L 2.0 0.29 1 10/31/1816:01 74-83-9 ND ug/L 5.0 0.96 1 10/31/1816:01 78-93-3 ND ug/L 2.0 1.2 1 10/31/1816:01 75-15-0 ND ug/L 1.0 0.25 1 10/31/1816:01 56-23-5 ND ug/L 1.0 0.23 1 10/31/1816:01 108-90-7 ND ug/L 1.0 0.54 1 10/31/1816:01 75-00-3 ND ug/L 1.0 0.14 1 10/31/1816:01 67-66-3 ND ug/L 1.0 0.11 1 10/31/1816:01 74-87-3 ND ug/L 2.0 2.0 1 10/31/1816:01 96-12-8 ND ug/L 1.0 0.21 1 10/31/1816:01 124-48-1 ND ug/L 1.0 0.27 1 10/31/1816:01 106-93-4 ND ug/L 1.0 0.21 1 10/31/1816:01 74-95-3 ND ug/L 1.0 0.30 1 10/31/1816:01 95-50-1 ND ug/L 1.0 0.33 1 10/31/1816:01 106-46-7 ND ug/L 1.0 1.0 1 10/31/1816:01 110-57-6 ND ug/L 1.0 0.32 1 10/31/1816:01 75-34-3 ND ug/L 1.0 0.24 1 10/31/1816:01 107-06-2 ND ug/L 1.0 0.56 1 10/31/1816:01 75-35-4 ND ug/L 1.0 0.19 1 10/31/1816:01 156-59-2 ND ug/L 1.0 0.49 1 10/31/1816:01 156-60-5 ND ug/L 1.0 0.27 1 10/31/1816:01 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Blanks Pace Project No.: 92404409 Sample: EB Lab ID: 92404409001 Collected: 10/19/18 05:00 Received: 10/23/18 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 10/31/18 16:01 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 10/31/18 16:01 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 10/31/18 16:01 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 10/31/18 16:01 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 10/31/18 16:01 591-78-6 lodomethane ND ug/L 5.0 0.32 1 10/31/18 16:01 74-88-4 Methylene Chloride 3.0 ug/L 1.0 0.97 1 10/31/18 16:01 75-09-2 C9 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 10/31/18 16:01 108-10-1 Styrene ND ug/L 1.0 0.26 1 10/31/18 16:01 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 10/31/18 16:01 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 10/31/18 16:01 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 10/31/18 16:01 127-18-4 Toluene ND ug/L 1.0 0.26 1 10/31/18 16:01 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 10/31/18 16:01 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 10/31/18 16:01 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 10/31/18 16:01 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 10/31/18 16:01 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 10/31/18 16:01 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 10/31/18 16:01 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 10/31/18 16:01 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 10/31/18 16:01 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 10/31/18 16:01 460-00-4 1,2-Dichloroethane-d4 (S) 80 % 70-130 1 10/31/18 16:01 17060-07-0 Toluene-d8 (S) 97 % 70-130 1 10/31/18 16:01 2037-26-5 Date: 11/01/2018 02:13 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Blanks Pace Project No.: 92404409 Sample: FIB Lab ID: 92404409002 Collected: 10/19/18 05:10 Received: 10/23/18 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Date: 11/01/2018 02:13 PM Analytical Method: EPA 8260E ND ug/L 25.0 10.0 1 10/31/1816:18 67-64-1 ND ug/L 10.0 1.9 1 10/31/1816:18 107-13-1 ND ug/L 1.0 0.25 1 10/31/1816:18 71-43-2 ND ug/L 1.0 0.17 1 10/31/1816:18 74-97-5 ND ug/L 1.0 0.18 1 10/31/1816:18 75-27-4 ND ug/L 1.0 0.26 1 10/31/1816:18 75-25-2 ND ug/L 2.0 0.29 1 10/31/1816:18 74-83-9 ND ug/L 5.0 0.96 1 10/31/1816:18 78-93-3 ND ug/L 2.0 1.2 1 10/31/1816:18 75-15-0 ND ug/L 1.0 0.25 1 10/31/1816:18 56-23-5 ND ug/L 1.0 0.23 1 10/31/1816:18 108-90-7 ND ug/L 1.0 0.54 1 10/31/1816:18 75-00-3 ND ug/L 1.0 0.14 1 10/31/1816:18 67-66-3 ND ug/L 1.0 0.11 1 10/31/1816:18 74-87-3 ND ug/L 2.0 2.0 1 10/31/1816:18 96-12-8 ND ug/L 1.0 0.21 1 10/31/1816:18 124-48-1 ND ug/L 1.0 0.27 1 10/31/1816:18 106-93-4 ND ug/L 1.0 0.21 1 10/31/1816:18 74-95-3 ND ug/L 1.0 0.30 1 10/31/1816:18 95-50-1 ND ug/L 1.0 0.33 1 10/31/1816:18 106-46-7 ND ug/L 1.0 1.0 1 10/31/1816:18 110-57-6 ND ug/L 1.0 0.32 1 10/31/1816:18 75-34-3 ND ug/L 1.0 0.24 1 10/31/1816:18 107-06-2 ND ug/L 1.0 0.56 1 10/31/1816:18 75-35-4 ND ug/L 1.0 0.19 1 10/31/1816:18 156-59-2 ND ug/L 1.0 0.49 1 10/31/1816:18 156-60-5 ND ug/L 1.0 0.27 1 10/31/1816:18 78-87-5 ND ug/L 1.0 0.13 1 10/31/1816:18 10061-01-5 ND ug/L 1.0 0.26 1 10/31/1816:18 10061-02-6 ND ug/L 150 78.4 1 10/31/1816:18 123-91-1 ND ug/L 1.0 0.30 1 10/31/1816:18 100-41-4 ND ug/L 5.0 0.46 1 10/31/1816:18 591-78-6 ND ug/L 5.0 0.32 1 10/31/1816:18 74-88-4 3.1 ug/L 1.0 0.97 1 10/31 /18 16:18 75-09-2 ND ug/L 5.0 0.33 1 10/31/1816:18 108-10-1 ND ug/L 1.0 0.26 1 10/31/1816:18 100-42-5 ND ug/L 1.0 0.33 1 10/31/1816:18 630-20-6 ND ug/L 1.0 0.40 1 10/31/1816:18 79-34-5 ND ug/L 1.0 0.46 1 10/31/1816:18 127-18-4 ND ug/L 1.0 0.26 1 10/31/1816:18 108-88-3 ND ug/L 1.0 0.48 1 10/31/1816:18 71-55-6 ND ug/L 1.0 0.29 1 10/31/1816:18 79-00-5 ND ug/L 1.0 0.47 1 10/31/1816:18 79-01-6 ND ug/L 1.0 0.20 1 10/31/1816:18 75-69-4 ND ug/L 1.0 0.41 1 10/31/1816:18 96-18-4 ND ug/L 2.0 0.35 1 10/31/1816:18 108-05-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. C9 Page 7 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Blanks Pace Project No.: 92404409 Sample: FIB Lab ID: 92404409002 Collected: 10/19/18 05:10 Received: 10/23/18 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Vinyl chloride ND ug/L 1.0 0.62 1 10/31/18 16:18 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 10/31/18 16:18 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 97 % 70-130 1 10/31/18 16:18 460-00-4 1,2-Dichloroethane-d4 (S) 82 % 70-130 1 10/31/18 16:18 17060-07-0 Toluene-d8 (S) 96 % 70-130 1 10/31/18 16:18 2037-26-5 Date: 11/01/2018 02:13 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92404409 QC Batch: 437912 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92404409001 METHOD BLANK: 2407839 Associated Lab Samples: 92404409001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 5.0 3.9 10/26/18 03:35 Arsenic ug/L ND 10.0 5.0 10/26/18 03:35 Barium ug/L ND 5.0 2.5 10/26/18 03:35 Beryllium ug/L ND 1.0 0.50 10/26/18 03:35 Cadmium ug/L ND 1.0 0.50 10/26/18 03:35 Chromium ug/L ND 5.0 2.5 10/26/18 03:35 Cobalt ug/L ND 5.0 2.5 10/26/18 03:35 Copper ug/L ND 5.0 2.5 10/26/18 03:35 Lead ug/L ND 5.0 2.5 10/26/18 03:35 Nickel ug/L ND 5.0 2.5 10/26/18 03:35 Selenium ug/L ND 10.0 5.0 10/26/18 03:35 Silver ug/L ND 5.0 2.5 10/26/18 03:35 Vanadium ug/L ND 5.0 2.5 10/26/18 03:35 Zinc ug/L ND 10.0 5.0 10/26/18 03:35 LABORATORY CONTROL SAMPLE: Parameter 2407840 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 448 90 80-120 Arsenic ug/L 500 429 86 80-120 Barium ug/L 500 510 102 80-120 Beryllium ug/L 500 506 101 80-120 Cadmium ug/L 500 459 92 80-120 Chromium ug/L 500 481 96 80-120 Cobalt ug/L 500 446 89 80-120 Copper ug/L 500 484 97 80-120 Lead ug/L 500 441 88 80-120 Nickel ug/L 500 458 92 80-120 Selenium ug/L 500 432 86 80-120 Silver ug/L 250 236 95 80-120 Vanadium ug/L 500 473 95 80-120 Zinc ug/L 500 429 86 80-120 Qualifiers Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2407841 2407842 MS MSD 92404202002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 473 477 94 95 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2018 02:13 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92404409 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2407841 2407842 MS MSD 92404202002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 451 453 90 91 75-125 1 20 Barium ug/L 20.4 500 500 548 554 106 107 75-125 1 20 Beryllium ug/L ND 500 500 527 533 105 107 75-125 1 20 Cadmium ug/L ND 500 500 484 486 97 97 75-125 0 20 Chromium ug/L ND 500 500 501 503 100 101 75-125 0 20 Cobalt ug/L ND 500 500 465 468 93 94 75-125 1 20 Copper ug/L ND 500 500 497 501 99 100 75-125 1 20 Lead ug/L ND 500 500 461 465 92 93 75-125 1 20 Nickel ug/L ND 500 500 478 481 96 96 75-125 1 20 Selenium ug/L ND 500 500 465 471 93 94 75-125 1 20 Silver ug/L ND 250 250 248 250 99 100 75-125 1 20 Vanadium ug/L ND 500 500 495 496 99 99 75-125 0 20 Zinc ug/L ND 500 500 457 460 91 92 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2018 02:13 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92404409 QC Batch: 437918 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92404409001 METHOD BLANK: 2407869 Matrix: Water Associated Lab Samples: 92404409001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.020 10/25/18 03:18 LABORATORY CONTROL SAMPLE: 2407870 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.2 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2407871 2407872 MS MSD 92404202002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 9.9 10.1 99 101 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/01/2018 02:13 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92404409 QC Batch: 439513 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill Associated Lab Samples: 92404409001, 92404409002 METHOD BLANK: 2415230 Associated Lab Samples: 92404409001, 92404409002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.33 10/31/18 11:28 1,1,1-Trichloroethane ug/L ND 1.0 0.48 10/31/18 11:28 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.40 10/31/18 11:28 1,1,2-Trichloroethane ug/L ND 1.0 0.29 10/31/18 11:28 1,1-Dichloroethane ug/L ND 1.0 0.32 10/31/18 11:28 1,1-Dichloroethene ug/L ND 1.0 0.56 10/31/18 11:28 1,2,3-Trichloropropane ug/L ND 1.0 0.41 10/31/18 11:28 1,2-Dibromo-3-chloropropane ug/L ND 2.0 2.0 10/31/18 11:28 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 10/31/18 11:28 1,2-Dichlorobenzene ug/L ND 1.0 0.30 10/31/18 11:28 1,2-Dichloroethane ug/L ND 1.0 0.24 10/31/18 11:28 1,2-Dichloropropane ug/L ND 1.0 0.27 10/31/18 11:28 1,4-Dichlorobenzene ug/L ND 1.0 0.33 10/31/18 11:28 1,4-Dioxane (p-Dioxane) ug/L ND 150 78.4 10/31/18 11:28 2-Butanone (MEK) ug/L ND 5.0 0.96 10/31/18 11:28 2-Hexanone ug/L ND 5.0 0.46 10/31/18 11:28 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 0.33 10/31/18 11:28 Acetone ug/L ND 25.0 10.0 10/31/18 11:28 Acrylonitrile ug/L ND 10.0 1.9 10/31/18 11:28 Benzene ug/L ND 1.0 0.25 10/31/18 11:28 Bromochloromethane ug/L ND 1.0 0.17 10/31/18 11:28 Bromodichloromethane ug/L ND 1.0 0.18 10/31/18 11:28 Bromoform ug/L ND 1.0 0.26 10/31/18 11:28 Bromomethane ug/L ND 2.0 0.29 10/31/18 11:28 Carbon disulfide ug/L ND 2.0 1.2 10/31/18 11:28 Carbon tetrachloride ug/L ND 1.0 0.25 10/31/18 11:28 Chlorobenzene ug/L ND 1.0 0.23 10/31/18 11:28 Chloroethane ug/L ND 1.0 0.54 10/31/18 11:28 Chloroform ug/L ND 1.0 0.14 10/31/18 11:28 Chloromethane ug/L ND 1.0 0.11 10/31/18 11:28 cis-1,2-Dichloroethene ug/L ND 1.0 0.19 10/31/18 11:28 cis-1,3-Dichloropropene ug/L ND 1.0 0.13 10/31/18 11:28 Dibromochloromethane ug/L ND 1.0 0.21 10/31/18 11:28 Dibromomethane ug/L ND 1.0 0.21 10/31/18 11:28 Ethylbenzene ug/L ND 1.0 0.30 10/31/18 11:28 lodomethane ug/L ND 5.0 0.32 10/31/18 11:28 Methylene Chloride ug/L ND 1.0 0.97 10/31/18 11:28 Styrene ug/L ND 1.0 0.26 10/31/18 11:28 Tetrachloroethene ug/L ND 1.0 0.46 10/31/18 11:28 Toluene ug/L ND 1.0 0.26 10/31/18 11:28 trans-1,2-Dichloroethene ug/L ND 1.0 0.49 10/31/18 11:28 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/01/2018 02:13 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92404409 METHOD BLANK: 2415230 Associated Lab Samples: 92404409001, 92404409002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed trans- 1,3-Dichloropropene ug/L ND 1.0 0.26 10/31/18 11:28 trans-1,4-Dichloro-2-butene ug/L ND 1.0 1.0 10/31/18 11:28 Trichloroethene ug/L ND 1.0 0.47 10/31/18 11:28 Trichlorofluoromethane ug/L ND 1.0 0.20 10/31/18 11:28 Vinyl acetate ug/L ND 2.0 0.35 10/31/18 11:28 Vinyl chloride ug/L ND 1.0 0.62 10/31/18 11:28 Xylene (Total) ug/L ND 1.0 0.66 10/31/18 11:28 1,2-Dichloroethane-d4 (S) % 81 70-130 10/31/18 11:28 4-Bromofluorobenzene (S) % 96 70-130 10/31/18 11:28 Toluene-d8 (S) % 94 70-130 10/31/18 11:28 LABORATORY CONTROL SAMPLE: Parameter 2415231 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 48.8 98 80-125 1,1,1-Trichloroethane ug/L 50 43.9 88 71-129 1,1,2,2-Tetrachloroethane ug/L 50 50.3 101 79-124 1,1,2-Trichloroethane ug/L 50 49.7 99 85-125 1,1-Dichloroethane ug/L 50 43.5 87 73-126 1,1-Dichloroethene ug/L 50 47.1 94 66-135 1,2,3-Trichloropropane ug/L 50 49.2 98 75-130 1,2-Dibromo-3-chloropropane ug/L 50 52.9 106 71-133 1,2-Dibromoethane (EDB) ug/L 50 49.6 99 83-124 1,2-Dichlorobenzene ug/L 50 51.2 102 80-133 1,2-Dichloroethane ug/L 50 40.7 81 67-128 1,2-Dichloropropane ug/L 50 49.9 100 75-132 1,4-Dichlorobenzene ug/L 50 48.7 97 78-130 1,4-Dioxane (p-Dioxane) ug/L 1000 1060 106 13-220 2-Butanone (MEK) ug/L 100 91.8 92 61-144 2-Hexanone ug/L 100 103 103 68-143 4-Methyl-2-pentanone (MIBK) ug/L 100 104 104 72-135 Acetone ug/L 100 86.1 86 48-146 Acrylonitrile ug/L 250 222 89 40-160 Benzene ug/L 50 51.5 103 80-125 Bromochloromethane ug/L 50 44.6 89 71-125 Bromodichloromethane ug/L 50 48.8 98 78-124 Bromoform ug/L 50 47.6 95 71-128 Bromomethane ug/L 50 43.5 87 40-160 Carbon disulfide ug/L 50 44.3 89 50-160 Carbon tetrachloride ug/L 50 51.0 102 69-131 Chlorobenzene ug/L 50 49.4 99 81-122 Chloroethane ug/L 50 34.7 69 39-148 Chloroform ug/L 50 42.1 84 73-127 Chloromethane ug/L 50 34.3 69 44-146 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/01/2018 02:13 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92404409 LABORATORY CONTROL SAMPLE: Parameter 2415231 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,2-Dichloroethene ug/L 50 44.1 88 74-124 cis-1,3-Dichloropropene ug/L 50 50.4 101 72-132 Dibromochloromethane ug/L 50 49.8 100 78-125 Dibromomethane ug/L 50 50.5 101 82-120 Ethylbenzene ug/L 50 49.5 99 79-121 lodomethane ug/L 100 72.3 72 39-154 Methylene Chloride ug/L 50 42.5 85 64-133 Styrene ug/L 50 49.3 99 84-126 Tetrachloroethene ug/L 50 48.3 97 78-122 Toluene ug/L 50 49.7 99 80-121 trans-1,2-Dichloroethene ug/L 50 44.6 89 71-127 trans- 1,3-Dichloropropene ug/L 50 50.4 101 69-141 trans-1,4-Dichloro-2-butene ug/L 50 48.1 96 40-160 Trichloroethene ug/L 50 49.5 99 78-122 Trichlorofluoromethane ug/L 50 39.7 79 53-137 Vinyl acetate ug/L 100 85.7 86 40-160 Vinyl chloride ug/L 50 46.5 93 58-137 Xylene (Total) ug/L 150 151 101 81-126 1,2-Dichloroethane-d4 (S) % 80 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE SAMPLE: Parameter 2415232 Units 92404175018 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 22.3 111 70-130 1,1,1-Trichloroethane ug/L ND 20 20.1 101 70-130 1,1,2,2-Tetrachloroethane ug/L ND 20 22.0 110 70-130 1,1,2-Trichloroethane ug/L ND 20 22.0 110 70-130 1,1-Dichloroethane ug/L ND 20 19.7 98 70-130 1,1-Dichloroethene ug/L ND 20 21.6 108 70-166 1,2,3-Trichloropropane ug/L ND 20 21.9 110 70-130 1,2-Dibromo-3-chloropropane ug/L ND 20 21.8 109 70-130 1,2-Dibromoethane (EDB) ug/L ND 20 21.9 110 70-130 1,2-Dichlorobenzene ug/L ND 20 22.0 110 70-130 1,2-Dichloroethane ug/L ND 20 18.2 91 70-130 1,2-Dichloropropane ug/L ND 20 22.6 113 70-130 1,4-Dichlorobenzene ug/L ND 20 21.3 107 70-130 1,4-Dioxane (p-Dioxane) ug/L ND 400 467 117 70-130 2-Butanone (MEK) ug/L ND 40 39.4 98 70-130 2-Hexanone ug/L ND 40 44.4 111 70-130 4-Methyl-2-pentanone (MIBK) ug/L ND 40 44.5 111 70-130 Acetone ug/L ND 40 38.5 96 70-130 Acrylonitrile ug/L ND 100 93.5 93 70-130 Benzene ug/L ND 20 23.6 118 70-148 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/01/2018 02:13 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92404409 MATRIX SPIKE SAMPLE: 2415232 92404175018 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Bromochloromethane ug/L ND 20 20.1 101 70-130 Bromodichloromethane ug/L ND 20 21.3 106 70-130 Bromoform ug/L ND 20 18.9 94 70-130 Bromomethane ug/L ND 20 13.0 65 70-130 M1 Carbon disulfide ug/L ND 20 19.5 97 70-130 Carbon tetrachloride ug/L ND 20 23.9 119 70-130 Chlorobenzene ug/L ND 20 22.1 111 70-146 Chloroethane ug/L ND 20 16.9 84 70-130 Chloroform ug/L ND 20 18.2 91 70-130 Chloromethane ug/L ND 20 15.4 77 70-130 cis-1,2-Dichloroethene ug/L ND 20 19.7 98 70-130 cis-1,3-Dichloropropene ug/L ND 20 22.0 110 70-130 Dibromochloromethane ug/L ND 20 21.1 106 70-130 Dibromomethane ug/L ND 20 22.5 112 70-130 Ethylbenzene ug/L ND 20 22.2 111 70-130 lodomethane ug/L ND 40 19.7 49 70-130 M1 Methylene Chloride ug/L ND 20 18.7 93 70-130 Styrene ug/L ND 20 22.0 110 70-130 Tetrachloroethene ug/L ND 20 21.8 109 70-130 Toluene ug/L ND 20 22.4 112 70-155 trans-1,2-Dichloroethene ug/L ND 20 19.9 99 70-130 trans- 1,3-Dichloropropene ug/L ND 20 21.9 110 70-130 trans-1,4-Dichloro-2-butene ug/L ND 20 19.2 96 70-130 Trichloroethene ug/L ND 20 22.8 114 69-151 Trichlorofluoromethane ug/L ND 20 19.4 97 70-130 Vinyl acetate ug/L ND 40 32.9 82 70-130 Vinyl chloride ug/L ND 20 20.7 104 70-130 Xylene (Total) ug/L ND 60 68.1 114 70-130 1,2-Dichloroethane-d4 (S) % 79 70-130 4-Bromofluorobenzene (S) % 97 70-130 Toluene-d8 (S) % 98 70-130 SAMPLE DUPLICATE: 2415233 Parameter Units 92404175019 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2018 02:13 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92404409 SAMPLE DUPLICATE: 2415233 Parameter Units 92404175019 Result Dup Result 1,2-Dichloroethane ug/L ND ND 1,2-Dichloropropane ug/L ND ND 1,4-Dichlorobenzene ug/L ND ND 1,4-Dioxane (p-Dioxane) ug/L ND ND 2-Butanone (MEK) ug/L ND ND 2-Hexanone ug/L ND ND 4-Methyl-2-pentanone (MIBK) ug/L ND ND Acetone ug/L ND ND Acrylonitrile ug/L ND ND Benzene ug/L ND ND Bromochloromethane ug/L ND ND Bromodichloromethane ug/L ND ND Bromoform ug/L ND ND Bromomethane ug/L ND ND Carbon disulfide ug/L ND ND Carbon tetrachloride ug/L ND ND Chlorobenzene ug/L ND ND Chloroethane ug/L ND ND Chloroform ug/L ND ND Chloromethane ug/L ND ND cis-1,2-Dichloroethene ug/L ND ND cis-1,3-Dichloropropene ug/L ND ND Dibromochloromethane ug/L ND ND Dibromomethane ug/L ND ND Ethylbenzene ug/L ND ND lodomethane ug/L ND ND Methylene Chloride ug/L ND ND Styrene ug/L ND ND Tetrachloroethene ug/L ND ND Toluene ug/L ND ND trans-1,2-Dichloroethene ug/L ND ND trans- 1,3-Dichloropropene ug/L ND ND trans-1,4-Dichloro-2-butene ug/L ND ND Trichloroethene ug/L ND ND Trichlorofluoromethane ug/L ND ND Vinyl acetate ug/L ND ND Vinyl chloride ug/L ND ND Xylene (Total) ug/L ND ND 1,2-Dichloroethane-d4 (S) % 81 82 4-Bromofluorobenzene (S) % 96 99 Toluene-d8 (S) % 98 96 Max RPD RPD Qualifiers 1 4 2 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2018 02:13 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Surry Blanks Pace Project No.: 92404409 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS C9 Common Laboratory Contaminant. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/01/2018 02:13 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Surry Blanks 92404409 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92404409001 EB EPA 3010A 437912 EPA 6010D 437947 92404409001 EB EPA 3010A 437918 EPA 6020B 437953 92404409001 EB EPA 8260B 439513 92404409002 FB EPA 8260B 439513 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/01/2018 02:13 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 21 Document Name: Document Revised: February 7, 2018 aceAnal rca( Sample Condition Upon Recei t(SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden[—] Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑ Sample Condition Client Name: W0# : 92404409 Upon • Project tf: I IIIIII I II i IIIIi II I I III Courier: ❑Fed Ex ❑UPS ❑U5P5 ❑Client ❑ Commercial ❑Pace ❑Other: 92404409 Custody Seal Present? ❑Yes []No Seals Intact? ❑Yes ❑No Date/Initials Person Examining Contents: Packing Material: []Bubble Wrap ❑Bubble Bags ❑None ❑ Other Thermometer: g2T045 Type of Ice: ❑Wet OIR Gun ID: _]Blue Cooler Temp I'Q: 2� Correction Factor: Add/Subtract ("C) -01 l Cooler Temp Corrected ('C): USDA Regulated Soll.4❑ N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check mapsi? IF nhl., Biological Tissue Frozen? ❑None ❑Yes • ❑i o ❑N/A Temp should be above freezing to 6'C []Samples out of temp criteria. Samples on ice, cooling process hasbegun Dld samples originate from a foreign source (internationally, inrludlna Hawaii and Paprta Ricol? MYes FIND Cam ments/Olscrepancy: Chain of Custody Present? ❑Yes ❑No ❑N/A I. Samples Arrived within Hold Time? )]Yes ❑No ❑N/A 2, Short Hold Time Analysis (e72hr.)? ❑Yes QNo ❑N/A 3. flush Turn Around Time Requested? ❑Yes QNo ❑N/A 4. Sufficient Volume? DYes ❑No El N/A 5. Correct Containers Used? -Pace Containers Used? ❑Yes Dyes ❑No ❑No ❑N/A ❑NIA 61 Containers Intact? 13yes ❑No ❑NIA 7, Dissolved analysis: Samples Field Filtered? []Yes ❑No []N/A e. Sample Labels Match COC? -IncludesDate/Time/ID/Analysis Matrix: ❑Yes ,..VI []No ❑NIA 4. Headspace in VOA Vials (>S-Gmm)? []Yes []No ❑N/A 10. rip Blank Present? Frip Blank Custody Seals Present? ❑Yes ❑Yes ❑No ❑No ❑N/A ❑NIA 21, COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Date/Time: /u�-lg L _ Field Data Required? ❑Yes [:]No Lot ID of split containers: Date: 0 Date: Z31(y Page 19 of 21 Document Name: Document Revised: February 7, 2018 aceAnafl,frcal« 1' Sample Condition Upon RecefptiSCUR} Page 1 of 2 Document No : Issuing Authority: F-CAR-CS-033•Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination Is verified and within the acceptance range for preservation samples, Exceptions: VDA, Coliform, TOC, Oil and Grease, DRO/801S (water) DOC, LLHg **Bottom half of box is to list number of bottle Project p IW 0# : 92404409 PM: RWC Due Date: 11/06/18 CLIENT: 92-Municipal E m a 4 a E C a m a n 4 a E 0v^ M a m v N a m a N c m W 7 r m .�+ a m O a ,n N O a m m O Z a E fn a m _ O aZar7S 4' UM a a E ,n a m a T E to a a co w n N 61 `5 E 3 3 Z, Z '�" a E m = n �� l7 a ^(a= v = a _ n E m` = N t7 a Q a_' c E Q aE v, ry m t7 a c -' O Y a E v c t7 a v v W D 4 E nn 0 a a Z m E o �v m W d d ni 0 a Q 2 V a E 0 `f m U o 2 rn a O E q 4n l7 > _ ¢ 2 C a d E 0 i m U > M a Q E 0 4 m U" o .. �" a AS i° Y a Q > G N a ° l7 > N E 'n 4~1 a rn D a Z v v E o r~� a in\N\N a E an a m ti va d E E g 7 O 17 a Z c E 0 7 v, 5 Z a a fl ¢ E m t7 a 1 2 3 4 5 6 7 B 9 10 1i --'-Ti2 pH Adjustment Log for Preserved Samples Sample It] Type of Preservative pH upon receipt Date preservation adJusted Time preservation adJusted Amount of Preservative added Lot # Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina QEHNH Certification Office (Le. out of hold, incorrect preservative, out of temp, incorrect containers Page20 of 21 m m 'p CD Co v as en ? w ro -� ITEM# c 3 0 m 3 m, M% a o m Ca (D N 7 c D z m Cu m m n co EV r" T K 3 O m EV o cn p nO 9 m N y V -4 A N (D @ n. m o O -- L7 cn x Ol �a 11 CD CO m a z a r a b jj] m n rD rD o 3 m c 0 m a i U) m a N s rn c — m _2 Cl C n N c _ SL A_ cq u T r a m m p m a Q ip O m p MATRIX CODE (see 44 codes Well c 3 CO o C) 0 SAMPLE TYPE (G=GRAB C=COtdP) N b O � 01 m m Cn T Jn7 N N F .n y m D c_ n A z v nmi z z o n A m 3 m m pQ n n O_ 0 O D L ° {� U`l Ly `�'! SAMPLETEMP AT COLLECTON r rn r A z y C, m C m a # OF CONTAINERS t�c,. V Q S y n m n m n m 3 9 m .�. Unpresarved L ^� V .. p1 H7804 r r,� m v HNO3 T m m E-\s w m n HCI It 11 CD o w NaOH m 1 y v 0 w o Na2S203 m rp Methanol t C m m P m m ro Other { Analyses Test YIN II j y T \ r 0 t1 N m p VOCs-App1 z N Zx n c ' a x Metals-App 1 z a D v N m � — a ob � • 4 m A zN od d TEMP in C u o � a m m �, Received an 9 ^ ce (Y!N) r n O Q Custody Sealed z Cooler (YIN) y z Samples Intact C% m = p n 7 fy aZ D O C N ^ O \/ N QL p r/C///�� O Eli' V/ Cu n r Q Dv e r � ' O a D n Fn , �0 a� W `` CD �6 EL {/y N rt �v C O Q 0 rD C O 3 ro a m m a n C v a N O Page 21 of 21 Appendix B Field Sampling Parameter Data Sheet(s) ";`'. INC Project: Surry Co Subtitle D Lined MSWLF, Ph 1 & 2 Samplers: J. Pfohl Page_1_ot L ;i Sampling Parameters Water Quality Parameters (Stabilized) Monitoring Sample Sample Depth to p Lab Volume Goes Total Depth p Total Specific B CH4 Point Date Time Water Parameters Purged Sample Dry Measured Depth Comments DO ORS' pH Temp: Cond. TDS n Gas (BTOP) to be (Gal) Type During as Expected (mg/L) O (us/cm (mg/L) Vapors Static analyzed for Purge ~ (ppm) expected MW-1 �' a 70.3 �'t 'a� �,�f IVOCS&Metals ,• MW-2 r - 26.74 �t 1 5'sr Ivocs&Metal _ M W-3 R �' 1 26 9 r� - I VOcs & Metals M W-4S I VocS & Metals )w,. 22.1 MW-4D "h' 43.1 ( 41It j I VOcs &Metals M W-5 ? I vocs &Melals i 48.5 x 81.3 ,? 'i,'` <' M W -6 R ," I vocs & Metals _— M W-8 vOCs & Metals k' 70.75� ` M W-9S I 42.28 t r f'r ;� 3 ! [ VOCs &Metals _ d M W-9D 1,) 65.54 j 'flM ,", al;'i .sr IVOCs&Ntetals M W-10 S � t VOcs & Metals _ i. 47.1 3 -r. It r tjyt 3 M W-11 S IT 4x4 46.05-- AI VOCs &Melals MW-11D t vocs&Nlelns - 65.31 i , It , i\k -- 65 MW-12 �' �j,; ; vocss Metalsv , MW-13 :. h5,� nr t." 36.31 Noes&Metals MLW-A �,.' 93.5 WLRonly — -- LAGOON t �' Leachate List i SS B=Stainless Steel Baler, D B=Disposable Baler, P=Low flow Pump, PD=Purged Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Samrile Obtained Project: F Sampling Parameters Goes Total Monitoring Sample Sample Lab Visual p De th Visual Parameters to Gua e Sample Dry Measured Point Date Time Flow Rate be analyzed Ht. Type During as for Purge expected SW-1 I11 f- SW-2 SW-3 I - S W-4 S '5v I SWN-1 SWN-2 I - SVVI 3 I SW-C I - SW-D t SS B=Stainless Steel Baler, D B=Disposable Baler, P=Low flow Pump, PD=Purged Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample Obtained r;..11 s.Utk f' Samplers: J. Pfohl Page_1_0f 1 Water Quality Parameters (Stabilized) CH4 DO Specific o Gas Comments (mg/L) ORP pH Te(D p' Cond. (mg L) Vapors (us/cm (ppm) it � _