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HomeMy WebLinkAboutMO-5956_22148_CA_LSA_20190109_The Point Apartments Project Limited Site Assessment ReportMid Atlantic Engineering & Environmental Solutions January 9, 2019 Mr. Rick Blat City of Concord, North Carolina Post Office Box 308 Concord, North Carolina 28026-0308 Subject: LIMITED SITE ASSESSMENT REPORT 1.043 ACRE PROPERTY 30 MARKET STREET SW CONCORD, CABARRUS COUNTY, NORTH CAROLINA MID -ATLANTIC PROJECT NO. 0001-11324.00 Dear Mr. Blat: 1125 E. Morehead Street, Suite 104 Charlotte. NC 28204-2849 Office: 980. 585.1271 MAAUNLINE.COM Mid -Atlantic Associates, Inc. (Mid -Atlantic) is pleased to present this Limited Site Assessment Report for a 1.043 Acre Property (The Point Apartments Project) located at 30 Market Street in Concord, Cabarrus County, North Carolina. We appreciate the opportunity to provide our environmental services to the City of Concord. Please do not hesitate to contact us at 980-585-1271 if you have any questions or if we may be of further service. Sincerely, MID -ATLANTIC ASSOCIATES, INC. Carl H. Hewett Senior Project Manager Enclosure Greg D. Icenhour, P.G., MBA Principal Geologist EXPERIENCED CUSTOMER FOCUSED INNOVATIVE M*Id Engineering & Environmental Solutions Limited Site Assessment Report 1.043 Acre Property Location: 30 Market Street SW Concord, Cabarrus County, North Carolina Prepared for: City of Concord Post Office Box 308 Concord, North Carolina 28026-0308 LIMITED SITE ASSESSMENT REPORT 1.043 ACRE PROPERTY 30 MARKET STREET SW CONCORD, CABARRUS COUNTY, NORTH CAROLINA MID -ATLANTIC PROJECT NO. 0001-11324.00 Prepared For: Mr. Rick Blat City of Concord, North Carolina Post Office Box 308 Concord, North Carolina 28026-0308 Prepared By: Mid -Atlantic Associates, Inc. 1125 East Morehead Street, Suite 104 Charlotte, North Carolina 28204 Mid -Atlantic Job No. OOOH1324.00 January 9, 2019 Mid Atlantic Engineering & Environmental Solutions Mid Atlantic Engineering & Environmental Solutions 1125 E. Morehead Street, Suite 104 Charlotte, NC 28204-2849 Office: 980. 585.1271 LIMITED SITE ASSESSMENT REPORT 1.043 ACRE PROPERTY 30 MARKET STREET SW CONCORD, CABARRUS COUNTY, NORTH CAROLINA MID -ATLANTIC PROJECT NO. 0001-11324.00 January 9, 2019 Prepared For: Mr. Rick Blat City of Concord, North Carolina Post Office Box 308 Concord, North Carolina 28026-0308 Prepared By: MID -ATLANTIC ASSO vV.................... A -SEAL 2547 ' J John L. Sherrill, P.G I=-,y •.FOLpG.�'''� Staff Geologist "' ..... '�ti' JE7ET aaaa eu a as W71 _y Carl H. Hewett Senior Project Manager Greg. D. Icenhour, P.G. Principal Geologist - EXPERIENCED CUSTOMER FOCUSED INNOVATIVE TABLE OF CONTENTS 1.0 PROJECT BACKGROUND....................................................................................1 1.1 Site Information........................................................................................... 1 1.2 Site Investigation......................................................................................... 1 2.0 FIELD ACTIVITIES................................................................................................. 2 2.1 Project Organization.................................................................................... 2 2.2 Soil Investigation......................................................................................... 3 2.3 Groundwater Investigation.......................................................................... 5 3.0 LABORATORY ANALYTICAL RESULTS............................................................. 8 3.1 Soil Analytical Results.................................................................................8 3.2 Grondwater Analytical Results.................................................................... 8 4.0 SUMMARY AND RECOMMENDATIONS............................................................... 9 4.1 Project Summary......................................................................................... 9 4.2 Project Findings and Recommendations................................................... 10 FIGURES Figure 1 Site Location Map Figure 2 Site Map Figure 3 Sample Location Map Figure 4 Estimated Water Table Elevation Map TABLES Table 1 Well Construction Details and Groundwater Elevations Table 2 Summary of Soil Analytical Results Table 3 Summary of Groundwater Analytical Results APPENDICES Appendix A Mid -Atlantic Field Sampling Procedures Appendix B Boring Logs Appendix C Laboratory Analytical Reports and Chain -of -Custody Records Mid Atlantic Engineering & Environmental Solutions 1.0 PROJECT BACKGROUND 1.1 Site Information The Subject Property is a 1.043 acre tract of land located at 30 Market Street SW in Concord, Cabarrus County, North Carolina, and it is identified as Cabarrus County tax parcel 56208775910000. The Subject Property was previously operated as the headquarters for the Concord Police Department. A Site Location Map is included as Figure 1. Mid -Atlantic Associates, Inc. (Mid -Atlantic) understands that the Subject Property is being evaluated for redevelopment as The Point Apartments. In October 2018, Stewart Engineering (Stewart) of Charlotte, North Carolina conducted a geotechnical study of the property. During geotechnical field activities, petroleum odors were reported in borings B-7 and B-8 from an approximate depth of 12 feet to 27 feet below ground surface (BGS). It was also reported to Mid -Atlantic that a petroleum underground storage tank (UST) was also previously located on the Subject Property. A Site Map is provided as Figure 2. 1.2 Site Investigation Based on discussions regarding the planned development and review of geotechnical boring logs provided by Stewart, Mid -Atlantic proposed to evaluate soil and groundwater at the Subject Property for petroleum impacts. This purpose for conducting further assessment is based on the following: • Contaminated soil, if present may impact both the development approach and cost. • If soil excavation is conducted during construction at depths below the groundwater table, impacted groundwater may be encountered in certain areas of the Subject Property. If dewatering activities are required, the water may need to be collected and disposed of at a licensed facility if it cannot be directed to the municipal waste water treatment facility. • From a regulatory perspective, subsurface impacts below the vadose zone are regulated as groundwater incidents and will have to be addressed accordingly. The following text details the field activities and findings of limited assessment activities conducted at the Subject Property. Mid Atlantic Engineering & Environmental Solutions Limited Site Assessment Report January 9, 2019 1.043 Acre Property, Concord, North Carolina Page 2 City of Concord, North Carolina Mid -Atlantic Project No. 00OH1324.00 a I =1I D7_[el 11y/ 1111 *1 Mid -Atlantic was contracted by City of Concord to conduct the limited site assessment activities. Field work for the project was conducted from December 13 through December 18, 2018. The soil and groundwater sampling locations are presented on Figure 3. 2.1 Project Organization Prior to initiating field work and sampling activities, Mid -Atlantic conducted the following activities: • The North Carolina One Call (811) service was contacted on November 26, 2018 to identify and mark subsurface public utilities on the Subject Property. Subsurface locating was updated on December 11, 2018. • A site -specific health and safety plan (HASP) was prepared to identify hazards that may be present during the performance of field work on the property. The HASP was reviewed with Mid -Atlantic employees and subcontractors prior to initiating work. • Mid -Atlantic contracted with Ground Penetrating Radar Systems (GPRS) of Charlotte, North Carolina to perform subsurface utility locating in the area of each of the proposed sampling locations. GPRS used electromagnetic (EM) locating and ground penetrating radar (GPR) to clear the proposed sample locations on December 13, 2018. Mid -Atlantic personnel were on site with GPRS during the locating activities. • Mid -Atlantic contracted with Environmental Drilling and Probing Services (EDPS) of Charlotte, North Carolina, a North Carolina licensed drilling firm, to perform the drilling activities associated with this project. • Mid -Atlantic contracted with Shealy Environmental Services, Inc. (Shealy) of West Columbia, South Carolina, a North Carolina accredited laboratory, to perform analytical testing for this project. Mid Atlantic Engineering & Environmental Solutions Limited Site Assessment Report January 9, 2019 1.043 Acre Property, Concord, North Carolina Page 3 City of Concord, North Carolina Mid -Atlantic Project No. 00OH1324.00 2.2 Soil Investigation Nine soil borings (SB-1 thru SB-5, TW-1 thru TW-4) were advanced at the Subject Property on December 13, 2018. The soil borings were advanced using a combination of direct push technology (DPT) and hollow stem augurs (HSA) by EDPS. Soil boring installation information is as follows: • Soil boring SB-1 was advanced to refusal at a depth of approximately 15 feet BGS using DPT. Soil obtained from the boring was field screened in two -foot intervals with a photoionization detector (PID). Based on field screening results and observed soil conditions, a soil sample was selected from the 8 to 10 foot interval for laboratory analysis for volatile organic compounds (VOCs) by EPA Method 8260. Soil samples were also collected for possible analysis for semi - volatile compounds (SVOCs) by EPA Method 8270 and for petroleum hydrocarbon fractions by Massachusetts Department of Environmental Protection Volatile Petroleum Hydrocarbons/Extractable Petroleum Hydrocarbons (MADEP VPH/EPH). • Soil boring SB-2 was advanced to refusal at a depth of approximately 9 feet BGS using DPT. Based on the PID field screening results and observed soil conditions, a soil sample was selected from the 7 to 9 foot interval for analysis for VOCs by EPA Method 8260. Soil samples were also collected for possible analysis for SVOCs by EPA Method 8270 and by MADEP VPH/EPH. • Soil boring SB-3 was advanced to refusal at a depth of approximately 10 feet BGS, using DPT. Field screening with a PID did not indicate the presence of elevated levels of VOCs, and a soil sample was not collected from boring SB-3. • Soil boring SB-4 was advanced to a depth of approximately 22 feet BGS using DPT. Based on field screening and observed soil conditions a sample was selected from the 6 to 8 foot interval for analysis for VOCs by EPA Method 8260. Soil samples were also collected for possible analysis for SVOCs by EPA Method 8270 and by MADEP VPH/EPH. Mid Atlantic Engineering & Environmental Solutions Limited Site Assessment Report 1.043 Acre Property, Concord, North Carolina City of Concord, North Carolina Mid -Atlantic Project No. 00OH1324.00 January 9, 2019 Page 4 • Soil boring SB-5 was advanced to a depth of approximately 22 feet BGS using DPT. Field screening with a PID did not indicate the presence of elevated levels of VOCs, and a soil sample was not collected from boring SB-5. • Soil boring TW-1 was advanced to a depth of approximately 22 feet BGS using DPT and HSA. Field screening was not conducted on soil from TW-1 due to poor recovery, and a soil sample was not collected. • Soil boring TW-2 was advanced to a depth of approximately 20 feet BGS using DPT and HSA. Based on PID field screening results and observed soil conditions, a soil sample was selected from the 6 to 8 foot interval for analysis for VOCs by EPA Method 8260. Soil samples were also collected for possible analysis for SVOCs by EPA Method 8270 and by MADEP VPH/EPH. • Soil boring TW-3 was advanced to a depth of approximately 20 feet BGS using DPT and HSA. Based on field observations and strong petroleum odors, a soil sample was selected from the 17 to 20 foot interval for analysis for VOCs by EPA Method 8260. Soil samples were also collected for possible analysis for SVOCs by EPA Method 8270 and by MADEP VPH/EPH. • Soil boring TW-4 was advanced to a depth of approximately 22 feet BGS using DPT. Based on field screening and observed soil conditions a sample was selected from the 8 to 10 foot interval for analysis for VOCs by EPA Method 8260. Soil samples were also collected for possible analysis for SVOCs by EPA Method 8270 and by MADEP VPH/EPH. Soil sample locations are indicated on Figure 3. Soil samples were collected in accordance with the Mid -Atlantic Field Procedures which are provided in Appendix A. Copies of the Boring Logs for the soil samples are included in Appendix B. Upon completion of soil sampling activities, EDPS backfilled the soil borings with bentonite pellets. Soil cuttings obtained from the soil boring activities were containerized in a drum for storage prior to disposal. The Geoprobe tooling was decontaminated between sampling locations using liquinox and water. Mid Atlantic Engineering & Environmental Solutions Limited Site Assessment Report 1.043 Acre Property, Concord, North Carolina City of Concord, North Carolina Mid -Atlantic Project No. 00OH1324.00 January 9, 2019 Page 5 After collection, the soil samples were preserved in an ice -filled cooler. The EPA Method 8260 soil samples were submitted to Shealy for chemical testing under chain - of -custody control. The EPA Method 8270 and MADEP VPH/EPH samples were submitted under "Hold" status pending the VOC analytical results for the soil samples. 2.3 Groundwater Investigation Temporary Well installation Four temporary groundwater monitoring wells (TW-1, TW-2, TW-3 and TW-4) were installed at the Subject Property by EDPS on December 13 and 14, 2018. The temporary wells were installed using hollow stem augers. The borings were logged, and soil was screened in two -foot intervals with a PID for possible impacts. The temporary monitoring wells were installed as follows: • Temporary well TW-1 was installed in the western corner of the site on December 14, 2018. The two-inch diameter PVC well was set to approximately 20 feet with a 10-foot section of 0.010-inch mill slotted screen and a 10-foot solid riser. • Temporary well TW-2 was installed to the southeast of the former gasoline UST pit on the Subject Property. The temporary well was constructed on December 14, 2018. The two-inch diameter PVC well was set to approximately 20 feet with a 10-foot section of 0.010-inch mill slotted screen and a 10-foot solid riser. • Temporary well TW-3 was installed in the southern portion of the Subject Property in the general area of historical geotechnical boring B-8 on December 13, 2018. The two-inch diameter PVC well was set to approximately 18.5 feet with a 10-foot section of 0.010-inch mill slotted screen and an 8.5-foot solid riser. • Temporary well TW-4 was installed on the southern corner of the property on December 13, 2018. The two-inch diameter PVC well was set to approximately 18.5 feet with a 10-foot section of 0.010-inch mill slotted screen and an 8.5-foot solid riser. Mid Atlantic Engineering & Environmental Solutions Limited Site Assessment Report 1.043 Acre Property, Concord, North Carolina City of Concord, North Carolina Mid -Atlantic Project No. 00OH1324.00 January 9, 2019 Page 6 After installation of the well casing, a sand pack was installed in each boring by EDPS from the base of the well to approximately two feet above the top of the screen. An approximate two foot thickness of bentonite was installed on top of the sand. Water was added to the bentonite pellets, and it was allowed sufficient time to hydrate prior to well development. The soil cuttings from the drilling activities were collected and containerized in labeled 55-gallon drums for disposal. During soil sampling activities, one existing permanent groundwater monitoring well (MW-2) was observed in the parking lot to the north of the former UST pit. Well construction information is provided in Table 1. The monitoring well locations are indicated on Figure 3. Copies of the Boring Logs prepared for the temporary wells are provided in Appendix B. Well Sampling Mid -Atlantic conducted groundwater sampling activities on the Subject Property on December 17, 2018. Mid -Atlantic gauged, purged and sampled the four temporary monitoring wells (TW-1 thru TW-4) and the existing permanent well (MW-2). Groundwater samples were collected as follows: • Prior to sampling, each well was developed and purged a minimum of three well volumes or until dry using a dedicated PVC bailer. Development water and purge water were collected and containerized in labeled 55-gallon drums for storage prior to disposal. • After allowing sufficient time for recharge, groundwater samples were collected from temporary wells TW-1, TW-2, TW-3, and TW-4 for analysis for VOCs by EPA Method 8260 and for polycyclic aromatic hydrocarbons (PAHs) by EPA Method 8270. Samples were collected from monitor well MW-2 for analysis for VOCs by EPA Method 8260 and SVOCs by EPA Method 8270, and for possible analysis of petroleum hydrocarbon fractions by MADEP VPH/EPH. Each groundwater sample was collected using a dedicated PVC bailer. New nitrile gloves were worn during the collection of each sample. Mid Atlantic Engineering & Environmental Solutions Limited Site Assessment Report 1.043 Acre Property, Concord, North Carolina City of Concord, North Carolina Mid -Atlantic Project No. 00OH1324.00 January 9, 2019 Page 7 After collection, the groundwater samples were preserved in an ice -filled cooler. The groundwater samples were submitted to Shealy for chemical testing under chain -of - custody control. The MADEP VPH/EPH samples were submitted under "Hold" status pending the VOC analytical results for MW-2. Groundwater Flow Direction After sampling on December 17, 2018, the top -of -casing elevations for the four temporary wells and the permanent well were surveyed. The depth to groundwater measurements in each well were recorded on December 18, 2018. Top -of -casing information and depth to water data is provided in Table 1. Based on information obtained during field work at the Subject Property, the groundwater flow direction is generally to the west. The estimated groundwater flow direction is presented on Figure 4. Additional Field Activities The following additional activities were conducted during the field work portion of this assessment: • On December 18, 2018 EDPS abandoned the four temporary monitoring wells that had been installed at the Subject Property. The temporary wells were abandoned by removing the well materials, if possible, and plugging the borings using bentonite chips. The surfaces of temporary well locations within the parking lot were sealed with asphalt patch. Mid -Atlantic personnel were on -site to oversee well abandonment activities. • The drums of soil cuttings and water generated during this assessment were secured and labeled. The drums are stored adjacent to a wall on the west side of the Subject Property. Mid -Atlantic understands that the drums will be disposed of once waste characterization has been completed. Mid Atlantic Engineering & Environmental Solutions Limited Site Assessment Report January 9, 2019 1.043 Acre Property, Concord, North Carolina Page 8 City of Concord, North Carolina Mid -Atlantic Project No. 00OH1324.00 W_1 161:7_1 1101:V/_1 Z /_1 Wil 0 WTI 0 *411016'1 Copies of the laboratory analytical reports and chain -of -custody records for the samples collected at the site by Mid -Atlantic are provided in Appendix C. The analytical results are summarized on Table 2 and Table 3. 3.1 Soil Analytical Results Analytical testing of soil sample TW-3 by EPA Method 8260 indicated the presence of Benzene at 13 micrograms per kilogram (ug/kg), which exceeds its applicable North Carolina Maximum Soil Contaminant Concentration — Soil to Groundwater (NCMSCC- STG) standard. In addition, Cyclohexane and Methylcyclohexane were reported at concentrations above laboratory minimum detection limits in sample TW-3, and neither compound has an NCMSCC standard for Residential, Industrial/Commercial or Soil to Groundwater. No other EPA Method 8260 target compounds were reported in analysis of samples SB-1, SB-2, SB-4, TW-1, TW-3 and TW-4 at concentrations in excess of their respective NCMSCC Residential, Industrial/Commercial or Soil to Groundwater standards. The soil analytical results are summarized in Table 2. Based on the reported EPA Method 8260 analytical results, it was determined during a conversation with Mr. Blat and Mid -Atlantic that other soil samples collected during field activities would not need to be analyzed. Shealy was contacted and the EPA Method 8270 and MADEP VPH/EPH "Hold" samples were not tested. The samples were disposed of by the laboratory. 3.2 Groundwater Analytical Results Analytical testing of groundwater sample TW-3 by EPA Method 8260 indicated the presence of 1-Methyl naphthalene, Benzene, Isopropyl benzene, Methylene Chloride and Naphthalene at concentrations in excess of their respective North Carolina Groundwater Quality Standards (NCGQS). In addition, Cyclohexane and Methylcyclohexane were reported at concentrations above laboratory minimum detection limits in sample TW-3, and neither compound has a specific NCGQS. No other EPA Method 8260 target compounds were reported for samples TW-1, TW-2, TW-3, TW-4 and MW-2 at concentrations in excess of their respective NCGQS standards. Mid Atlantic Engineering & Environmental Solutions Limited Site Assessment Report 1.043 Acre Property, Concord, North Carolina City of Concord, North Carolina Mid -Atlantic Project No. 00OH1324.00 January 9, 2019 Page 9 Analytical testing of groundwater samples TW-1, TW-2, TW-3, TW-4 and MW-2 by EPA Method 8270 did not indicate concentrations of target compounds in excess of their corresponding laboratory minimum detection limits. The groundwater analytical results are summarized in Table 3. Based on the reported EPA Method 8260 and 8270 analytical results for sample MW-2, it was determined during a conversation with Mr. Blat and Mid -Atlantic that the MADEP VPH/EPH "Hold" groundwater samples at MW-2 would not be needed. Shealy was contacted and the MADEP VPH/EPH "Hold" samples were not tested. The samples were disposed of by the laboratory. 4.0 SUMMARY AND RECOMMENDATIONS 4.1 Project Summary Mid -Atlantic performed the following work during December 2018 to investigate the subsurface in selected areas at the Subject Property: • Nine soil borings (SB-1 thru SB-5, TW-1 thru TW-4) were advanced at the Subject Property. Based on field screening results and field observations, soil samples were collected from borings SB-1, SB-2, SB-4, TW-1, TW-3 and TW-4 for analysis for VOCs by EPA Method 8260. • Analytical testing of soil sample TW-3 by EPA Method 8260 collected from a depth of 17 to 20 feet BGS indicated the presence of Benzene at a concentration exceeding its NCMSCC-STG standard. In addition, Cyclohexane and Methylcyclohexane were reported at concentrations above laboratory minimum detection limits in sample TW-3, and neither compound has established North Carolina soil standards. Subsequently, soil sample TW-3 was determined to be below the vadose zone and is indicative of groundwater quality conditions as described below. No other EPA Method 8260 target compounds were reported in analysis of samples SB-1, SB-2, SB-4, TW-1, TW-3 and TW-4 at concentrations in excess of their respective North Carolina soil standards. Mid Atlantic Engineering & Environmental Solutions Limited Site Assessment Report 1.043 Acre Property, Concord, North Carolina City of Concord, North Carolina Mid -Atlantic Project No. OOOH1324.00 January 9, 2019 Page 10 • Four temporary groundwater monitoring wells (TW-1 thru TW-4) were installed at the subject site. One existing permanent groundwater monitoring well (MW-2) was observed during field activities. Groundwater samples were collected from MW-1 for analysis for VOCs by EPA Method 8260 and for SVOCs by EPA Method 8270. Groundwater samples were collected from TW-1 thru TW-4 for analysis for VOCs by EPA Method 8260 and for PAHs by EPA Method 8270. • Analytical testing of the groundwater sample TW-3 indicated by EPA Method 8260 indicated the presence of 1-Methyl naphthalene, Benzene, Isopropylbenzene, Methylene Chloride and Naphthalene at concentrations in excess of their respective NCGQS. In addition, Cyclohexane and Methylcyclohexane were reported at concentrations above laboratory minimum detection limits in sample TW-3, and neither compound has a specific NCGQS. No other EPA Method 8260 target compounds were reported in analysis of groundwater samples TW-1, TW-2, TW-3, TW-4 and MW-2 at concentrations in excess of their respective NCGQS standards. • The groundwater flow direction at the Subject Property at the time of this limited assessment was generally to the west. • The soil borings and temporary monitor well locations were abandoned by EDPS upon completion of the project. • Drums of soil cuttings and water generated during the field activities were stored adjacent to a wall on the west side of the Subject Property. 4.2 Project Findings and Recommendations The following findings were identified during the work of this investigation: • Petroleum -affected soils were not encountered above the groundwater table at the Subject Property during the site investigation. • Petroleum -impacted groundwater was identified on the southwestern portion of the Subject Property. Mid Atlantic Engineering & Environmental Solutions Limited Site Assessment Report 1.043 Acre Property, Concord, North Carolina City of Concord, North Carolina Mid -Atlantic Project No. 00OH1324.00 January 9, 2019 Page 11 Given the nature of the planned development, minor soil contamination and lack of anticipated future groundwater use at the Subject Property the following recommendations are provided based on the findings of this investigation: • While no significant soil contamination was identified, observation of soil conditions during any excavation should be conducted. If visual staining or odors are identified, field screening of the potentially affected soil should be conducted, along with additional soil sampling and analysis if field screening so indicates. Mid - Atlantic's assessment activities were limited in nature, and while conducted in areas believed to represent worst -case scenario conditions, may not be indicative of soil conditions in areas not sampled or investigated. This risk is believed to be low. • Mid -Atlantic understands that the area investigated is planned for apartment construction with a below grade parking structure. Should this construction extend below the groundwater table, dewatering may be required. If this is the case, Mid - Atlantic recommends procurement of permission from the City of Concord to discharge the groundwater generated to the local publicly owned treatment works via a permit or other mechanism as dictated by City requirements. • During excavation, should subsurface conditions differ significantly from those observed by Mid -Atlantic, a Vapor Intrusion Mitigation System (VIMS) may be considered as part of the design of any new structures to address any vapors that may collect in or beneath planned structures. The evaluation of alternatives for mitigating existing structures can include an active or passive VIMS, HVAC manipulation and/or exhaust fans as appropriate commensurate with the final design and the evaluation of potential risk. Construction of a below grade parking structure, along with adequate ventilation should mitigate any potential vapor risks. Based on our evaluation of data collected during our investigation, no known vapor intrusion condition exists based on contaminants and concentrations identified. Mid Atlantic Engineering & Environmental Solutions FIGURES Mid Atlantic Engineering & Environmental Solutions ♦ \ }�: � ,\ //y�",; o �. � � �� Ste` �.. �i !ew\ ♦.. � 1, � \� '� � � •�;�(S� :..}� ... �f Y •va � S� �-9� `� � may" \. +"� s\ 'yA1 J h� � ��r �����` � •�`'t " LEI- �Y'+ ��.• Legend SITE PROPERTY BOUNDARY ' "y �• PARCEL BOUNDARY SCALE:1:1,200 0 100 200 400 STREET CENTERLINE !;l�r' Feet SITE MAP 1.038 ACRE PARCEL DRAWN BY: f DATE: JANUARY 2019 DRAFT CHECK BY: CHH JOB NO.: 00OH1324.00 ENGINEER CHECK BY: CHH GIS NO.: 05G-H1324.00-02 id Atlantic Engineering & Environmental Solutions 30 MARKET STREET SW CONCORD, NORTH CAROLINA APPROVED GDI I FIGURE NO.: 2 REFERENCE: PARCEL AND ROAD GIS DATA FROM CABARRUS COUNTY GIS. 2015 AERIAL IMAGERY FROM NC CGIA. N MW 2 SB-5 O FORMER UST LOCATION f (APPROXIMATE) %or d SB-4* aTW 2*'� Or TW=1 * O ILIA I are f O Legend EXISTING MONITORING WELL = �� MAA SOIL BORING/TEMPORARY MONITORING WELL (12/13/2018) NOTES: O MAA SOIL BORING (12/13/2018) STEWARD GEOTECHNICAL BORING PETROLEUM ODORS WERE OBSERVED IN THE (10/2018) STEWART BORINGS (B-7/B-8) DURING THE SCALE:1:240 OCTOBER 2018 GEOTECHNICAL INVESTIGATION. d 0 10 20 40 SITE PROPERTY BOUNDARY Feet DENOTES SOIL SAMPLE COLLECTED AT LOCATION DRAWN BY: 0 DATE: JANUARY 2019 SAMPLE LOCATION MAP DRAFT CHECK 1.038 ACRE PARCEL BY: CHH JOB NO.: OOOH1324.00 M• id Atlantic 30 MARKET STREET SW ENGINEERCHECK BY GIS NO.: 05G-H1324.00-03 Engineering & Environmental Solutions CONCORD, NORTH CAROLINA BYPROVE GDI FIGURE NO.: 3 REFERENCE: PARCEL AND ROAD GIS DATA FROM CABARRUS COUNTY GIS. 2015 AERIAL IMAGERY FROM NC CGIA. ESTIMATED WATER TABLE ELEVATION MAP DRAWN BY: DATE: JANUARY2019 DRAFT CHECK 1.038 ACRE PARCEL BY: CHH JOB NO.: 0001-11324.00 Mid Atlantic 30 MARKET STREET SW ENGINEER CHECK GIS NO.: 05G-H1324.00-04 Engineering & Environmental Solutions BY: CHH CONCORD, NORTH CAROLINA APPROVED BY: GDI FIGURE NO.: 4 11 REFERENCE: PARCEL AND ROAD GIS DATA FROM CABARRUS COUNTY GIS. 2015 AERIAL IMAGERY FROM NC CGIA. MID -ATLANTIC FIELD NOTES 11 TABLES Mid Atlantic Engineering & Environmental Solutions TABLE 1 WELL CONSTRUCTION AND GROUNDWATER ELEVATIONS 1.038 ACRE PARCEL 30 MARKET STREET SW CONCORD, CABARRUS COUNTY, NORTH CAROLINA Total Depth Screen Length Screened Depth to water Well ID TOC Elevation GW Elevation (feet) (feet) Interval (feet) (feet) TW-1 18.5 10 18.5-8.5 100.00 12.93 87.07 TW-2 18.5 10 18.5-8.5 99.35 9.14 90.21 TW-3 18.5 10 18.5-8.5 101.74 11.14 90.60 TW-4 18 10 18-8 102.46 11.34 91.12 MW-2 15 10 15-5 97.89 6.88 91.01 Notes: Elevations were surveyed by Mid -Atlantic personel using a laser level and base elevation of 100.00 set at TW-1. Water level measurements were taken on December 18, 2018. MW-2 well construction data obtained from well tag. TABLE 2 SUMMARY OF SOIL ANALYTICAL RESULTS 1.038 ACRE PARCEL 30 MARKET STREET SW CONCORD, CABARRUS COUNTY, NORTH CAROLINA Sample ID SB-1 SB-2 SB-4 TW-2 TW-3 TW-4 MS NCMSCC STG NCMSCC RES NCMSCC I/C Date 12/13/2018 12/13/2018 12/13/2018 12/13/2018 12/13/2018 12/13/2018 Interval 8-10' 7-9' 6-8' 6-8' 17-20' 8-10' VOLATILE ORGANIC COMPOUNDS (VOCs) BY EPA METHOD 8260 Acetone 38 BDL BDL BDL 62 BDL 24,000 14,000,000 360,000,000 Benzene BDL BDL BDL BDL 13 BDL 6 18,000 164,000 Chloroform BDL BDL BDL BDL 15 BDL 370 20,000 180,000 Cyclohexane BDL BDL BDL BDL 1300 BDL NS NS NS Ethybenzene BDL BDL BDL BDL 980 BDL 4,900 1,560,000 40,000,000 Isopropyl benzene BDL BDL BDL BDL 130 BDL 1,700 1,564,000 40,880,000 Methylcyclohexane BDL BDL BDL BDL 4400 BDL NS NS NS Methylene Chloride 8.0 13 9.3 6.9 11 BDL 20 85,000 763,000 Toluene BDL BDL BDL BDL 7.1 BDL 4,300 1,200,000 32,000,000 Xylenes, total BDL BDL BDL BDL 290 BDL 4,600 3,129,000 81,760,000 Notes: Soil results presented in micrograms per kilogram (ug/kg). BDL = below laboratory minimum detection limits NS = no standard established Bold concentrations exceed the applicable standard for the constituent or no standard established NCMSCC I/C = North Carolina Maximum Soil Contaminant Concentration — Industrial/Commercial NCMSCC RES = North Carolina Maximum Soil Conaminant Concentration — Residential Use NCMSCC STG = North Carolina Maximum Soil Contaminant Concentration — Soil to Groundwater Sample ID Date 1-Methyl naphthalene 2-Methyl naphthalene Benzene Cyclohexane Eth (benzene Isopropylbenzene Methylcyclohexane Methylene chloride Naphthalene Toluene Xvlenes (total) TABLE 3 SUMMARY OF GROUNDWATER ANALYTICAL RESULTS 1.038 ACRE PARCEL 30 MARKET STREET SW CONCORD, CABARRUS COUNTY, NORTH CAROLINA • •- U 9 -• TW-3 TW-4 MW-2 12/17/18 12/17/18 12/17/18 )Cs) BY EPA METHOD 8260 7.2 BDL BDL 10 BDL BDL 61 BDL BDL 430 BDL BDL 360 BDL BDL 120 BDL BDL 500 BDL BDL 13 BDL BDL 54 BDL BDL 21 BDL BDL 430 BDL BDL NCGQS 1* 30 1 NS 600 70 NS 5 6 600 500 SEMI -VOLATILE ORGANIC COMPOUNDS (SVOCs) BY EPA METHOD 8270 EPA 8270 Tarqet Compounds I BDL I BDL I BDL I BDL I BDL Various (Notes: All concentrations are shown in micrograms per liter (pg/L) Bold concentrations exceed the applicable standard for the constituent or no standard established BDL = below laboratory minimum detection limits NCGQS = 15A NCAC 02L .0202 Groundwater Standards (effective April 1, 2013) 1* = Interim Maximum Allowable Concentration (IMAC) under 15A NCAC 02L .0202 NS = No standard established Only constituents with at least one detection are presented in this table. For the complete analytical report, refer to Appendix E. /_1aa411LI Q KC."I MID -ATLANTIC FIELD PROCEDURES Mid Atlantic Engineering & Environmental Solutions Soil Sampling Procedures Sample Collection Direct Push Technology (DPT, or "Geoprobe") DPT uses a truck -mounted hydraulic rig to push a steel sampling probe into the subsurface to collect soil and/or groundwater samples. The sampling device used to collect the soil samples during this investigation was the "macrocore" sampler. This sampler consists of a four -foot long, two-inch diameter stainless steel spoon containing a clear, acetate liner. When the macrocore sampler is driven into the subsurface, the soil is collected into the acetate liner and then retrieved to the land surface. The liner is then cut open and the soil lithology is characterized and soil samples are collected. Split Spoon Sampling This method of soil sampling is typically used during advancement of hollowstem augers for the construction of monitoring wells. Soil samples are obtained from the borings by driving a prewashed, 1-3/8-inch inner -diameter split -spoon sampler at five foot intervals to termination in general accordance with ASTM D-1586 (Standard Penetration Test) specifications. Blow counts for each six inches of split -spoon penetration are recorded during advancement of the spoon. Samples are then retrieved to the land surface, the split -spoon is opened, and the soil lithology is characterized and soil samples are collected. Hand Augering This method is typically used for shallow sampling in areas where access is limited or underground obstacles such as utilities may be present. A pre -washed, three-inch diameter steel auger bucket is attached to extension rods and manually turned to penetrate the subsurface to the desired sampling depth. Samples are then retrieved to the land surface and the soil lithology is characterized and soil samples are collected directly from the hand auger bucket. Excavator Bucket Sampling This method is typically used during UST excavation and soil excavation projects. The soil samples are collected from the excavator bucket when it is not safe to collect the samples by other means. Care is taken when collecting samples from the bucket to avoid soil that has come in contact with the bucket itself to avoid cross contamination. II. Headspace Field Screening A portion of each sample is removed from the sampling device and placed in a pre - labeled, plastic "ziploc" bag. After several minutes, the gas contained in the "headspace" or void area within the bag is tested with a photoionization detection (PID) and/or Flame Ionization Detector (FID). These are useful as scanning devices to detect the presence of volatile organic compounds (VOCs) but are not relied upon to determine specific levels of contamination. Typically, the samples exhibiting the highest headspace readings will be submitted to the laboratory for analysis. III. Preparation for Laboratory Analysis The sample collector dons new nitrile sampling gloves prior to handling each sample. The samples are placed into laboratory -prepared, pre -labeled, sampling containers, packed in ice, and shipped to a certified laboratory under chain -of -custody control. The sampler places an executed custody seal on the cooler prior to leaving the sampler's custody. Laboratory analyses to be performed on the samples, along with other sampling information, are specified on the chain -of -custody, which is placed in the cooler with the samples. Monitoring Well Installation Procedures Shallow Type II Monitoring Wells These wells are typically constructed in a borehole made by a power auger and penetrate the top portion of the shallow water table. The wells are typically constructed of two-inch diameter (although they can be larger), Schedule 40 PVC casing with 0.010-inch mechanically slotted well screen placed in the bottom of the well. These wells are constructed such that the well screen intersects the water table at the time of construction. A gravel pack (typically clean washed sand) is used to fill the borehole annular space around the screened interval and is usually terminated one to two feet above the top of the screen. A typically two -foot thick layer of bentonite is then placed in the annular space above the sand pack, and the remainder of the annular space is filled from bottom to top with a Portland cement/bentonite mixture pumped through a tremie pipe. The monitoring wells are equipped with locking caps and fitted with flush -mounted protective manhole covers or above -ground "stick-up" protectors. Note: for site -specific well construction details, refer to Well Construction Records II. Deep Type III Monitoring Wells Deep, Type III monitoring wells are constructed with two "telescoping" casings, an inner casing and an outer casing. The outer casing is larger in diameter (typically six-inch diameter Schedule 40 PVC) and typically extends from land surface to bedrock or a confining unit. The bottom of this casing is typically firmly set into the top of bedrock or other confining layer and then tremie-grouted into the borehole. After the grout has cured, the borehole is then advanced below the bottom of the outer casing by drilling through the outer casing to the desired depth. The inner casing (typically two-inch diameter Schedule 40 PVC) is constructed with a screened interval that monitors water within bedrock fractures or other deeper water -bearing zones. The borehole annulus is then filled with gravel pack, bentonite, and grout and finished at land surface as described above. Note: for site -specific well construction details, refer to Well Construction Records Groundwater Sampling Procedures Sample Collection A. Monitoring Wells Prior to sample collection, each well is purged of three to five standing well volumes or to dryness to remove stagnant water from the well and well bore in an effort to collect samples that are representative of the water quality in the formation surrounding each well. Purging is performed either with a new, polyethylene bailer dedicated to each well, or with a decontaminated pump. Samples are retrieved from the monitoring well using the dedicated bailer. New nylon string is used on each dedicated bailer, and new nitrile sampling gloves are donned prior to purging and sampling of each well. B. Geoprobe "Screen Point Sampler" The screen point sampler is a "grab" sampling device that is driven into the saturated zone and a surrounding metal sheath is retracted, exposing a screen. Groundwater entering the screen is then drawn to land surface through disposable tubing that is placed through the hollow push rods. The sample is collected from the tubing into the appropriate sampling glassware. C. Water -Supply Wells Water samples are typically collected from the available spigot that is nearest to the well. The water is allowed to run at a high flow from the spigot for approximately 10 to 15 minutes to allow the water in the delivery lines to be purged. The sample flow is then reduced and the samples are collected directly into pre -labeled containers as described below. New nitrile sampling gloves are donned prior to sampling of each well. D. Treatment System Influent/Effluent Samples are typically collected from the influent or effluent of pump -and -treat groundwater remediation systems using designated sampling ports in the influent and effluent water transport lines. The water is typically allowed to run for several seconds to clear potential debris in the sampling port. The sample is then collected directly into sampling containers as described below. New nitrile sampling gloves are donned prior to sample collection. II. Preparation for Laboratory Analysis Groundwater samples are decanted directly into laboratory -prepared, pre -labeled, sampling containers, packed in ice, and shipped to a certified laboratory under chain -of -custody control. Laboratory analyses performed on the samples are specified on the chain -of -custody. APPENDIX B BORING LOGS Mid Atlantic Engineering & Environmental Solutions 1115 E. Morehead Street Mid Atlantic LOG OF BORING: SB-1 Charlotteotte,, NC 28204 Engineering & E—i—nmeocal 5olocions ph: (980) 585-1271 Page: 1 of 1 Site Name: 1.038 Acre Parcel Drilling/Boring Method: DPT Total Boring Depth (ft): 15' Project Number: 000111324.00 Sampling Method: Macrocore Well Depth (ft): n/a Location: Concord, NC Subcontractor/Drillers: EDPS Screen Depth (ft): n/a Date Started: 12/13/2018 Driller : D. Demby DTW (ft): n/a Date Completed: 12/13/2018 Monitoring Equipment: MiniRae 3000 MAA Field Staff: John L. Sherrill, P.G. u, Odors a .° a. c SOIL DESCRIPTION (color, texture, mefswrc, etc.) Construction Details None 0.3 ................................. Reddish orange sandy clayey silt ..................................................................... 2 2 None 0.3 ................................. Medium grey silty clayey sand with some rock fragments .................................................................... ----- 4 4 None 0.4 ---------------- Dark brown silty sand, unconsolidated, likely fill material ---------------------------------- ----- 6 6 None 0.4 ................................. Dark brown silty sand with rock fragments ..................................................................... .... 8 8 None 0.7 x Tannish brown sandy clay .................................................................... ..... 10 10 None0.4 ................................. Tannish orange sand ..................................................................... ----- 12 12 None0.4 ................................. Tan and very light sand 14 14 None 0.4 16 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... Refusal at 15'. Boring terminated. 16 18 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 18 20 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 20 22 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 22 24 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 24 26 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 26 28 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 28 30 30 COMMENTS: in - indicates inches N/A - indicates not applicable to this boring ft - indicates depth in feet ppm - indicates parts per million ft BLS - indicates feet below land surface 1115 E. Morehead Street Mid Atlantic LOG OF BORING: SB-2 Charlotteotte,, NC 28204 Engineering & E—i—nmeocal 5olocions ph: (980) 585-1271 Page: 1 of 1 Site Name: 1.038 Acre Parcel Drilling/Boring Method: DPT Total Boring Depth (ft): 9' Project Number: 000111324.00 Sampling Method: Macrocore Well Depth (ft): n/a Location: Concord, NC Subcontractor/Drillers: EDPS Screen Depth (ft): n/a Date Started: 12/13/2018 Driller : D. Demby DTW (ft): n/a Date Completed: 12/13/2018 Monitoring Equipment: MiniRae 3000 MAA Field Staff: John L. Sherrill, P.G. u, Odors a .° a c SOIL DESCRIPTION (color, texture, mefswrc, etc.) Construction Details None0.20 ..................................................................... 2 2 None 0.10 Dark reddish brown silty sand 4 4 None 0.10 6 6 None Reddish orange silt, black rock fragments at base of boring ---- ---- ---- 8 13.90 X 8 None Refusal at 9'. Boring terminated. 10 10 12 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 12 14 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 14 16 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 16 18 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ----- 18 20 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 20 22 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 22 24 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 24 26 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 26 28 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 28 30 30 COMMENTS: in - indicates inches N/A - indicates not applicable to this boring ft - indicates depth in feet ppm - indicates parts per million ft BLS - indicates feet below land surface 1115 E. Morehead Street Mid Atlantic LOG OF BORING: SB-3 Charlotteotte,, NC 28204 Engineering & E—i—nmeocal 5olocions ph: (980) 585-1271 Page: 1 of 1 Site Name: 1.038 Acre Parcel Drilling/Boring Method: DPT Total Boring Depth (ft): 10, Project Number: 000111324.00 Sampling Method: Macrocore Well Depth (ft): n/a Location: Concord, NC Subcontractor/Drillers: EDPS Screen Depth (ft): n/a Date Started: 12/13/2018 Driller : D. Demby DTW (ft): n/a Date Completed: 12/13/2018 Monitoring Equipment: MiniRae 3000 MAA Field Staff: John L. Sherrill, P.G. u, Odors a .° a c SOIL DESCRIPTION (color, texture, mefswrc, etc.) Construction Details NoneNot analyzed ................................. ..................................................................... ..... 2 2 None0.4 ................................. ..................................................................... 4 4 Greyish brown silty sand None0.3 ................................. ..................................................................... 6 6 None0.4 ................................. ..................................................................... 8 8 None 0.2 Greyish brown silty sand, brick fragments at the base 10 10 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... Refusal at 10'. Boring terminated. ---- 12 12 14 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 14 16 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 16 18 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... --- 18 20 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 20 22 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 22 24 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 24 26 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 26 28 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 28 30 30 COMMENTS: in - indicates inches N/A - indicates not applicable to this boring ft - indicates depth in feet ppm - indicates parts per million ft BLS - indicates feet below land surface 1115 E. Morehead Street Mid Atlantic LOG OF BORING: SB-4 Charlotteotte,, NC 28204 Engineering & E—i—nmeocal 5olocions ph: (980) 585-1271 Page: 1 of 1 Site Name: 1.038 Acre Parcel Drilling/Boring Method: DPT Total Boring Depth (ft): 22' Project Number: 000111324.00 Sampling Method: Macrocore Well Depth (ft): n/a Location: Concord, NC Subcontractor/Drillers: EDPS Screen Depth (ft): n/a Date Started: 12/13/2018 Driller : D. Demby DTW (ft): 9' Date Completed: 12/13/2018 Monitoring Equipment: MiniRae 3000 MAA Field Staff: John L. Sherrill, P.G. u, Odors a .° a. c SOIL DESCRIPTION (color, texture, mefswrc, etc.) Construction Details None0.7 ................................. Brownish red slightly sandy silt ..................................................................... ..... 2 2 None.................................................................... ..... 4 4 None0.7 ................................. ..................................................................... Tannish red sandy sily 6 6 None0.8 X ..................................................................... .... 8 8 None................................. Not analyzed Greyish brown silty sand, wet 10 10 None.................................................................... ----- 12 Dark brownish grey fine to very fine sandy silt, highly micacous 12 None0.8 ................................. 14 14 None.................................................................... ----- 16 16 None.................................................................... ---- 18 Greyish brown silty sand, wet 18 None 0. .................................................................... ---- 20 20 None0.6 ................................. 22 22 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... Boring terminated at 22'. ---- 24 24 26 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 26 28 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 28 30 30 COMMENTS: in - indicates inches N/A - indicates not applicable to this boring ft - indicates depth in feet ppm - indicates parts per million ft BLS - indicates feet below land surface 1115 E. Morehead Street Mid Atlantic LOG OF BORING: SB-5 Charlotteotte,, NC 28204 Engineering & E—i—nmeocal 5olocions ph: (980) 585-1271 Page: 1 of 1 Site Name: 1.038 Acre Parcel Drilling/Boring Method: DPT Total Boring Depth (ft): 22' Project Number: 000111324.00 Sampling Method: Macrocore Well Depth (ft): n/a Location: Concord, NC Subcontractor/Drillers: EDPS Screen Depth (ft): n/a Date Started: 12/13/2018 Driller : D. Demby DTW (ft): 10, Date Completed: 12/13/2018 Monitoring Equipment: MiniRae 3000 MAA Field Staff: John L. Sherrill, P.G. u, Odors a .° a c SOIL DESCRIPTION (color, texture, mefswrc, etc.) Construction Details None0.00 ..................................................................... 2 2 Orangeish brown sandy silt None0.1 ................................. ..................................................................... 4 4 0.1 None......................................................................... 6 6 None................................. 0.1 8 8 None................................. 10 V 10 None................................. 12 12 0.2 None ................................. Brownish grey silty sand, wet at 10', poor recovery ..................................................................... ----- 14 14 None.......................................................... 16 16 None.............................. 18 18 0.1 None.............................. 20 20 None................................. Orange fine sand, wet 22 22 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... Boring terminated at 22'. --- 24 24 26 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 26 28 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 28 30 30 COMMENTS: in - indicates inches N/A - indicates not applicable to this boring ft - indicates depth in feet ppm - indicates parts per million ft BLS - indicates feet below land surface 1115 E. Morehead Street Mid Atlantic LOG OF BORING: TW-1 Charlotteotte,, NC 28204 Engineering & E—i—nmeocal 5olocions ph: (980) 585-1271 Page: 1 of 1 Site Name: 1.038 Acre Parcel Drilling/Boring Method: DPT/HSA Total Boring Depth (ft): 22' Project Number: 000111324.00 Sampling Method: Macrocore Well Depth (ft): 18.5' Location: Concord, NC Subcontractor/Drillers: EDPS Screen Depth (ft): 18.5'-8.5' Date Started: 12/13/2018 Driller : D. Demby DTW (ft): —15' Date Completed: 12/14/2018 Monitoring Equipment: MiniRae 3000 MAA Field Staff: John L. Sherrill, P.G. u, Odors a .° a. c SOIL DESCRIPTION (color, texture, mefswrc, etc.) Construction Details Nonen/a ................................. ..................................................................... 2 No recovery 2 Nonen/a ................................. ..................................................................... 4 4 Yellow/tan sily sand, unconsolidated. Very poor recovery Nonen/a ................................. ............................................................... 6 6 Nonen/a ................................. ....................................................... No recovery 8 8 Nonen/a ................................. ..................................................................... 10 10 Nonen/a ................................. 12 12 Dark grey very fine sandy silt None n/a ................................. 14 14 None n/a ................................. 16 16 None n/a ................................. 18 18 No recovery, wet Nonen/a ................................. 20 20 None n/a ................................. 22 22 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... Boring terminated at 22'. ---- 24 24 26 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 26 28 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 28 30 1 1 1 30 COMMENTS: in - indicates inches N/A - indicates not applicable to this boring ft - indicates depth in feet ppm - indicates parts per million ft BLS - indicates feet below land surface 1115 E. Morehead Street Mid Atlantic LOG OF BORING: TW-2 Charlotteotte,, NC 28204 Engineering & E—i—nmeocal 5olocions ph: (980) 585-1271 Page: 1 of 1 Site Name: 1.038 Acre Parcel Drilling/Boring Method: DPT/HSA Total Boring Depth (ft): 20' Project Number: 000111324.00 Sampling Method: Macrocore Well Depth (ft): 18.5' Location: Concord, NC Subcontractor/Drillers: EDPS Screen Depth (ft): 18.5'-8.5' Date Started: 12/13/2018 Driller : D. Demby DTW (ft): 12' Date Completed: 12/14/2018 Monitoring Equipment: MiniRae 3000 MAA Field Staff: John L. Sherrill, P.G. u, Odors a .° a. c SOIL DESCRIPTION (color, texture, mefswrc, etc.) Construction Details None0.4 ................................. ..................................................................... 2 2 Tannish red clayey sand, possibly fill material None0.4 ................................. ..................................................................... 4 4 None0.7 .............................. ............................................................... 6 6 None0.7 X ..........................................................- -- Tan fine sandy silt 8 8 None0.6 .................................................................... ---- 10 10 None0.4 ................................. 12 v 12 None 0.7 .................................................................- Darkish grey slightly sandy silt, wet at 12' 14 14 None n/a ................................. 16 16 None0 ................................. 18 Grey sandy clay, thick, dry 18 None0 ................................. Partially weathered rock 20 20 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... Boring terminated at 20'. ---- 22 22 24 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 24 26 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... 26 28 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 28 30 30 COMMENTS: in - indicates inches N/A - indicates not applicable to this boring ft - indicates depth in feet ppm - indicates parts per million ft BLS - indicates feet below land surface Mid Atlantic Engineering & E—ironmencal 1125 E. Morehead Street Suite Charlotte, NC 28204 ph: (980)585-1271 LOG OF BORING: Page: 1 V� —J 1 of 1 Site Name: 1.038 Acre Parcel Drilling/Boring Method: DPT/HSA Total Boring Depth (ft): 20' Project Number: 000111324.00 Sampling Method: Macrocore Well Depth (ft): 18.5' Location: Concord, NC Subcontractor/Drillers: EDPS Screen Depth (ft): 18.5'-8.5' Date Started: 12/13/2018 Driller : D. Demby DTW (ft): 12' Date Completed: 12/13/2018 Monitoring Equipment: MiniRae 3000 MAA Field Staff: John L. Sherrill, P.G. u, Odors a .° a. c SOIL DESCRIPTION (color, texture, mefswrc, etc.) Construction Details None 0.2 ..................... 2 None0.1 ..................... 4 None 0.2 ..................... 6 None 0.2 ..................... 8 None Not analyzed ..................... 10 None Not analyzed ...................... 12 None Not analyzed ...................... 14 Strong Not petroleum odor analyzed ...................... 16 Strong Not petroleum odor analyzed ...................... 18 Strong Not X petroleum odor analyzed 20 22 .................................................................................................................................................. 24 .................................................................................................................................................. 26 .................................................................................................................................................. 28 .................................................................................................................................................. 30 Olive brown fine sandy silt Red slightly sandy clay DPT refusal at 8'. Brick fragments into reddish brown silty clay Greyish brown silty clayey sand, wet at 12'. Petroleum odors Boring terminated at 20' 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 COMMENTS: in - indicates inches N/A - indicates not applicable to this boring ft - indicates depth in feet ppm - indicates parts per million ft BLS - indicates feet below land surface 1115 E. Morehead Street Mid Atlantic LOG OF BORING: TW-4 Charlotteotte,, NC 28204 Engineering & E—i—nmencal ph: (980)585-1271 Page: 1 of 1 Site Name: 1.038 Acre Parcel Drilling/Boring Method: DPT/HSA Total Boring Depth (ft): 22' Project Number: 000111324.00 Sampling Method: Macrocore Well Depth (ft): 18' Location: Concord, NC Subcontractor/Drillers: EDPS Screen Depth (ft): 18'-8' Date Started: 12/13/2018 Driller : D. Demby DTW (ft): 10, Date Completed: 12/13/2018 Monitoring Equipment: MiniRae 3000 MAA Field Staff: John L. Sherrill, P.G. u, Odors a .° a. c SOIL DESCRIPTION (color, texture, mefswrc, etc.) Construction Details None 0.0 ................................. Olive brown slightly sandy clayey silt ..................................................................... ..... 2 2 None0.1 ................................. ..................................................................... Reddish brown slightly sandy silt 4 4 None0.2 ................................. ..................................................................... 6 Dark brown silty fine sand 6 None0.1 ................................. Reddish brown slightly sandy clay ..................... 8 8 None 0.2 X Dark greyish brown silt into ..................................................................... --- 10 V 10 None0.2 ................................. Reddish brown silty sand, very moist to wet. 12 12 None0.2 ................................. Dark greyish silt 14 14 None0.3 ................................. 16 16 None 0.1 ................................. Brown fine sandy silt, wet ..................................................................- 18 18 None0.1 ................................. 20 20 None0.1 ................................. 22 Partially weathered rock dry. 22 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... Boring terminated at 22'. ---- 24 24 26 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... 26 28 .......................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ---- 28 30 30 COMMENTS: in - indicates inches N/A - indicates not applicable to this boring ft - indicates depth in feet ppm - indicates parts per million ft BLS - indicates feet below land surface APPENDIX C LABORATORY ANALYTICAL REPORTS AND CHAIN-OF-CUSTORY RECORDS Mid Atlantic Engineering & Environmental Solutions SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Mid -Atlantic Associates, Inc. 1125 East Morehead Street Suite # 104 Charlotte, NC 28204 Attention: Carl Hewett Project Name: Parking Lot, Concord, NC Project Number:000H1324.00 Lot Number:TL14005 Date Completed:01/02/2019 Project Manager:Kelly M. Nance A B C R E 6 1 T E d B ODD FLAP This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Mid -Atlantic Associates, Inc. Lot Number: TL14005 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPS or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" qualifier If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Volatiles Sample -005 had the surrogate recovered outside of the acceptance limits due to confirmed matrix interference. Sample -006 had cyclohexane, ethylbenzene, and 4-methyl-2-pentanone recovered above the instrument's calibration range in the initial analysis. A dilution was analyzed outside of the 14-day holding time. Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Mid -Atlantic Associates, Inc. Lot Number: TL14005 Sample Number Sample ID Matrix Date Sampled Date Received 001 313-1 Solid 12/13/2018 0930 12/14/2018 002 SB-2 Solid 12/13/20181000 12/14/2018 003 SB-4 Solid 12/13/20181315 12/14/2018 004 TW-2 Solid 12/13/20181400 12/14/2018 005 TW-4 Solid 12/13/20181500 12/14/2018 006 TW-3 Solid 12/13/20181540 12/14/2018 (6 samples) Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com SHEALY ENVIRONMENTAL SERVICES, INC. Detection Summary Mid -Atlantic Associates, Inc. Lot Number: TL14005 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 SB-1 Solid Acetone 8260B 38 ug/kg 5 001 SB-1 Solid Methylene chloride 8260B 8.0 ug/kg 5 002 SB-2 Solid Methylene chloride 8260B 13 ug/kg 7 003 SB-4 Solid Methylene chloride 8260B 9.3 ug/kg 9 004 TW-2 Solid Methylene chloride 8260B 6.9 ug/kg 11 006 TW-3 Solid Acetone 8260B 62 ug/kg 15 006 TW-3 Solid Benzene 8260B 13 ug/kg 15 006 TW-3 Solid Chloroform 8260B 15 ug/kg 15 006 TW-3 Solid Cyclohexane 8260B 1300 ug/kg 15 006 TW-3 Solid Ethylbenzene 8260B 980 ug/kg 15 006 TW-3 Solid Isopropylbenzene 8260B 130 ug/kg 15 006 TW-3 Solid Methylcyclohexane 8260B 4400 ug/kg 15 006 TW-3 Solid Methylene chloride 8260B 11 ug/kg 15 006 TW-3 Solid Toluene 8260B 7.1 ug/kg 15 006 TW-3 Solid Xylenes (total) 8260B 290 ug/kg 16 (15 detections) Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID: TL14005-001 Description: SB-1 Matrix: Solid Date Sampled:12/13/2018 0930 % Solids: 86.3 12/14/2018 2152 Date Received:12/14/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Sample Wt.(g) 1 5035 8260B 1 12/27/20181759 JM1 93475 6.01 CAS Analytical Parameter Number Method Result Q LOQ Units Run Acetone 67-64-1 8260B 38 19 ug/kg 1 Benzene 71-43-2 8260B ND 4.8 ug/kg 1 Bromodichloromethane 75-27-4 8260B ND 4.8 ug/kg 1 Bromoform 75-25-2 8260B ND 4.8 ug/kg 1 Bromomethane (Methyl bromide) 74-83-9 8260B ND 4.8 ug/kg 1 2-Butanone (MEK) 78-93-3 8260B ND 19 ug/kg 1 Carbon disulfide 75-15-0 8260B ND 4.8 ug/kg 1 Carbon tetrachloride 56-23-5 8260B ND 4.8 ug/kg 1 Chlorobenzene 108-90-7 8260B ND 4.8 ug/kg 1 Chloroethane 75-00-3 8260B ND 4.8 ug/kg 1 Chloroform 67-66-3 8260B ND 4.8 ug/kg 1 Chloromethane (Methyl chloride) 74-87-3 8260B ND 4.8 ug/kg 1 Cyclohexane 110-82-7 8260B ND 4.8 ug/kg 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260B ND 4.8 ug/kg 1 Dibromochloromethane 124-48-1 8260B ND 4.8 ug/kg 1 1,2-Dibromoethane (EDB) 106-93-4 8260B ND 4.8 ug/kg 1 1,2-Dichlorobenzene 95-50-1 8260B ND 4.8 ug/kg 1 1,3-Dichlorobenzene 541-73-1 8260B ND 4.8 ug/kg 1 1,4-Dichlorobenzene 106-46-7 8260B ND 4.8 ug/kg 1 Dichlorodifluoromethane 75-71-8 8260B ND 4.8 ug/kg 1 1,1-Dichloroethane 75-34-3 8260B ND 4.8 ug/kg 1 1,2-Dichloroethane 107-06-2 8260B ND 4.8 ug/kg 1 1,1-Dichloroethene 75-35-4 8260B ND 4.8 ug/kg 1 cis- 1,2-Dichloroethene 156-59-2 8260B ND 4.8 ug/kg 1 trans-1,2-Dichloroethene 156-60-5 8260B ND 4.8 ug/kg 1 1,2-Dichloropropane 78-87-5 8260B ND 4.8 ug/kg 1 cis- 1,3-Dichloropropene 10061-01-5 8260B ND 4.8 ug/kg 1 trans- 1,3-Dichloropropene 10061-02-6 8260B ND 4.8 ug/kg 1 Ethylbenzene 100-41-4 8260B ND 4.8 ug/kg 1 2-Hexanone 591-78-6 8260B ND 9.6 ug/kg 1 Isopropylbenzene 98-82-8 8260B ND 4.8 ug/kg 1 Methyl acetate 79-20-9 8260B ND 4.8 ug/kg 1 Methyl tertiary butyl ether (MTBE) 1634-04-4 8260B ND 4.8 ug/kg 1 4-Methyl-2-pentanone 108-10-1 8260B ND 9.6 ug/kg 1 Methylcyclohexane 108-87-2 8260B ND 4.8 ug/kg 1 Methylene chloride 75-09-2 8260B 8.0 4.8 ug/kg 1 Styrene 100-42-5 8260B ND 4.8 ug/kg 1 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 4.8 ug/kg 1 Tetrachloroethene 127-18-4 8260B ND 4.8 ug/kg 1 Toluene 108-88-3 8260B ND 4.8 ug/kg 1 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 8260B ND 4.8 ug/kg 1 1,2,4-Trichlorobenzene 120-82-1 8260B ND 4.8 ug/kg 1 1,1,1-Trichloroethane 71-55-6 8260B ND 4.8 ug/kg 1 1,1,2-Trichloroethane 79-00-5 8260B ND 4.8 ug/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID: TL14005-001 Description: SB-1 Matrix: Solid Date Sampled:12/13/2018 0930 % Solids: 86.3 12/14/2018 2152 Date Received:12/14/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Sample Wt.(g) 1 5035 8260B 1 12/27/20181759 JM1 93475 6.01 CAS Analytical Parameter Number Method Result Q LOQ Units Run Trichloroethene 79-01-6 8260B ND 4.8 ug/kg 1 Trichlorofluoromethane 75-69-4 8260B ND 4.8 ug/kg 1 Vinyl chloride 75-01-4 8260B ND 4.8 ug/kg 1 Xylenes (total) 1330-20-7 8260B ND 9.6 ug/kg 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 90 53-142 Bromofluorobenzene 94 47-138 Toluene-d8 96 68-124 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID: TL14005-002 Description: SB-2 Matrix: Solid Date Sampled:12/13/2018 1000 % Solids: 80.8 12/14/2018 2152 Date Received:12/14/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Sample Wt.(g) 1 5035 8260B 1 12/27/20181821 JM1 93475 3.92 CAS Analytical Parameter Number Method Result Q LOQ Units Run Acetone 67-64-1 8260B ND 32 ug/kg 1 Benzene 71-43-2 8260B ND 7.9 ug/kg 1 Bromodichloromethane 75-27-4 8260B ND 7.9 ug/kg 1 Bromoform 75-25-2 8260B ND 7.9 ug/kg 1 Bromomethane (Methyl bromide) 74-83-9 8260B ND 7.9 ug/kg 1 2-Butanone (MEK) 78-93-3 8260B ND 32 ug/kg 1 Carbon disulfide 75-15-0 8260B ND 7.9 ug/kg 1 Carbon tetrachloride 56-23-5 8260B ND 7.9 ug/kg 1 Chlorobenzene 108-90-7 8260B ND 7.9 ug/kg 1 Chloroethane 75-00-3 8260B ND 7.9 ug/kg 1 Chloroform 67-66-3 8260B ND 7.9 ug/kg 1 Chloromethane (Methyl chloride) 74-87-3 8260B ND 7.9 ug/kg 1 Cyclohexane 110-82-7 8260B ND 7.9 ug/kg 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260B ND 7.9 ug/kg 1 Dibromochloromethane 124-48-1 8260B ND 7.9 ug/kg 1 1,2-Dibromoethane (EDB) 106-93-4 8260B ND 7.9 ug/kg 1 1,2-Dichlorobenzene 95-50-1 8260B ND 7.9 ug/kg 1 1,3-Dichlorobenzene 541-73-1 8260B ND 7.9 ug/kg 1 1,4-Dichlorobenzene 106-46-7 8260B ND 7.9 ug/kg 1 Dichlorodifluoromethane 75-71-8 8260B ND 7.9 ug/kg 1 1,1-Dichloroethane 75-34-3 8260B ND 7.9 ug/kg 1 1,2-Dichloroethane 107-06-2 8260B ND 7.9 ug/kg 1 1,1-Dichloroethene 75-35-4 8260B ND 7.9 ug/kg 1 cis- 1,2-Dichloroethene 156-59-2 8260B ND 7.9 ug/kg 1 trans-1,2-Dichloroethene 156-60-5 8260B ND 7.9 ug/kg 1 1,2-Dichloropropane 78-87-5 8260B ND 7.9 ug/kg 1 cis- 1,3-Dichloropropene 10061-01-5 8260B ND 7.9 ug/kg 1 trans- 1,3-Dichloropropene 10061-02-6 8260B ND 7.9 ug/kg 1 Ethylbenzene 100-41-4 8260B ND 7.9 ug/kg 1 2-Hexanone 591-78-6 8260B ND 16 ug/kg 1 Isopropylbenzene 98-82-8 8260B ND 7.9 ug/kg 1 Methyl acetate 79-20-9 8260B ND 7.9 ug/kg 1 Methyl tertiary butyl ether (MTBE) 1634-04-4 8260B ND 7.9 ug/kg 1 4-Methyl-2-pentanone 108-10-1 8260B ND 16 ug/kg 1 Methylcyclohexane 108-87-2 8260B ND 7.9 ug/kg 1 Methylene chloride 75-09-2 8260B 13 7.9 ug/kg 1 Styrene 100-42-5 8260B ND 7.9 ug/kg 1 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 7.9 ug/kg 1 Tetrachloroethene 127-18-4 8260B ND 7.9 ug/kg 1 Toluene 108-88-3 8260B ND 7.9 ug/kg 1 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 8260B ND 7.9 ug/kg 1 1,2,4-Trichlorobenzene 120-82-1 8260B ND 7.9 ug/kg 1 1,1,1-Trichloroethane 71-55-6 8260B ND 7.9 ug/kg 1 1,1,2-Trichloroethane 79-00-5 8260B ND 7.9 ug/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID: TL14005-002 Description: SB-2 Matrix: Solid Date Sampled:12/13/2018 1000 % Solids: 80.8 12/14/2018 2152 Date Received:12/14/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Sample Wt.(g) 1 5035 8260B 1 12/27/20181821 JM1 93475 3.92 CAS Analytical Parameter Number Method Result Q LOQ Units Run Trichloroethene 79-01-6 8260B ND 7.9 ug/kg 1 Trichlorofluoromethane 75-69-4 8260B ND 7.9 ug/kg 1 Vinyl chloride 75-01-4 8260B ND 7.9 ug/kg 1 Xylenes (total) 1330-20-7 8260B ND 16 ug/kg 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 89 53-142 Bromofluorobenzene 73 47-138 Toluene-d8 94 68-124 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID: TL14005-003 Description: SB-4 Matrix: Solid Date Sampled:12/13/2018 1315 % Solids: 83.1 12/14/2018 2152 Date Received:12/14/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Sample Wt.(g) 1 5035 8260B 1 12/27/20181843 JM1 93475 6.15 CAS Analytical Parameter Number Method Result Q LOQ Units Run Acetone 67-64-1 8260B ND 20 ug/kg 1 Benzene 71-43-2 8260B ND 4.9 ug/kg 1 Bromodichloromethane 75-27-4 8260B ND 4.9 ug/kg 1 Bromoform 75-25-2 8260B ND 4.9 ug/kg 1 Bromomethane (Methyl bromide) 74-83-9 8260B ND 4.9 ug/kg 1 2-Butanone (MEK) 78-93-3 8260B ND 20 ug/kg 1 Carbon disulfide 75-15-0 8260B ND 4.9 ug/kg 1 Carbon tetrachloride 56-23-5 8260B ND 4.9 ug/kg 1 Chlorobenzene 108-90-7 8260B ND 4.9 ug/kg 1 Chloroethane 75-00-3 8260B ND 4.9 ug/kg 1 Chloroform 67-66-3 8260B ND 4.9 ug/kg 1 Chloromethane (Methyl chloride) 74-87-3 8260B ND 4.9 ug/kg 1 Cyclohexane 110-82-7 8260B ND 4.9 ug/kg 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260B ND 4.9 ug/kg 1 Dibromochloromethane 124-48-1 8260B ND 4.9 ug/kg 1 1,2-Dibromoethane (EDB) 106-93-4 8260B ND 4.9 ug/kg 1 1,2-Dichlorobenzene 95-50-1 8260B ND 4.9 ug/kg 1 1,3-Dichlorobenzene 541-73-1 8260B ND 4.9 ug/kg 1 1,4-Dichlorobenzene 106-46-7 8260B ND 4.9 ug/kg 1 Dichlorodifluoromethane 75-71-8 8260B ND 4.9 ug/kg 1 1,1-Dichloroethane 75-34-3 8260B ND 4.9 ug/kg 1 1,2-Dichloroethane 107-06-2 8260B ND 4.9 ug/kg 1 1,1-Dichloroethene 75-35-4 8260B ND 4.9 ug/kg 1 cis- 1,2-Dichloroethene 156-59-2 8260B ND 4.9 ug/kg 1 trans-1,2-Dichloroethene 156-60-5 8260B ND 4.9 ug/kg 1 1,2-Dichloropropane 78-87-5 8260B ND 4.9 ug/kg 1 cis- 1,3-Dichloropropene 10061-01-5 8260B ND 4.9 ug/kg 1 trans- 1,3-Dichloropropene 10061-02-6 8260B ND 4.9 ug/kg 1 Ethylbenzene 100-41-4 8260B ND 4.9 ug/kg 1 2-Hexanone 591-78-6 8260B ND 9.8 ug/kg 1 Isopropylbenzene 98-82-8 8260B ND 4.9 ug/kg 1 Methyl acetate 79-20-9 8260B ND 4.9 ug/kg 1 Methyl tertiary butyl ether (MTBE) 1634-04-4 8260B ND 4.9 ug/kg 1 4-Methyl-2-pentanone 108-10-1 8260B ND 9.8 ug/kg 1 Methylcyclohexane 108-87-2 8260B ND 4.9 ug/kg 1 Methylene chloride 75-09-2 8260B 9.3 4.9 ug/kg 1 Styrene 100-42-5 8260B ND 4.9 ug/kg 1 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 4.9 ug/kg 1 Tetrachloroethene 127-18-4 8260B ND 4.9 ug/kg 1 Toluene 108-88-3 8260B ND 4.9 ug/kg 1 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 8260B ND 4.9 ug/kg 1 1,2,4-Trichlorobenzene 120-82-1 8260B ND 4.9 ug/kg 1 1,1,1-Trichloroethane 71-55-6 8260B ND 4.9 ug/kg 1 1,1,2-Trichloroethane 79-00-5 8260B ND 4.9 ug/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID: TL14005-003 Description: SB-4 Matrix: Solid Date Sampled:12/13/2018 1315 % Solids: 83.1 12/14/2018 2152 Date Received:12/14/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Sample Wt.(g) 1 5035 8260B 1 12/27/20181843 JM1 93475 6.15 CAS Analytical Parameter Number Method Result Q LOQ Units Run Trichloroethene 79-01-6 8260B ND 4.9 ug/kg 1 Trichlorofluoromethane 75-69-4 8260B ND 4.9 ug/kg 1 Vinyl chloride 75-01-4 8260B ND 4.9 ug/kg 1 Xylenes (total) 1330-20-7 8260B ND 9.8 ug/kg 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 90 53-142 Bromofluorobenzene 78 47-138 Toluene-d8 96 68-124 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID: TL14005-004 Description: TW-2 Matrix: Solid Date Sampled:12/13/2018 1400 % Solids: 94.6 12/14/2018 2152 Date Received:12/14/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Sample Wt.(g) 1 5035 8260B 1 12/27/20181906 JM1 93475 6.25 CAS Analytical Parameter Number Method Result Q LOQ Units Run Acetone 67-64-1 8260B ND 17 ug/kg 1 Benzene 71-43-2 8260B ND 4.2 ug/kg 1 Bromodichloromethane 75-27-4 8260B ND 4.2 ug/kg 1 Bromoform 75-25-2 8260B ND 4.2 ug/kg 1 Bromomethane (Methyl bromide) 74-83-9 8260B ND 4.2 ug/kg 1 2-Butanone (MEK) 78-93-3 8260B ND 17 ug/kg 1 Carbon disulfide 75-15-0 8260B ND 4.2 ug/kg 1 Carbon tetrachloride 56-23-5 8260B ND 4.2 ug/kg 1 Chlorobenzene 108-90-7 8260B ND 4.2 ug/kg 1 Chloroethane 75-00-3 8260B ND 4.2 ug/kg 1 Chloroform 67-66-3 8260B ND 4.2 ug/kg 1 Chloromethane (Methyl chloride) 74-87-3 8260B ND 4.2 ug/kg 1 Cyclohexane 110-82-7 8260B ND 4.2 ug/kg 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260B ND 4.2 ug/kg 1 Dibromochloromethane 124-48-1 8260B ND 4.2 ug/kg 1 1,2-Dibromoethane (EDB) 106-93-4 8260B ND 4.2 ug/kg 1 1,2-Dichlorobenzene 95-50-1 8260B ND 4.2 ug/kg 1 1,3-Dichlorobenzene 541-73-1 8260B ND 4.2 ug/kg 1 1,4-Dichlorobenzene 106-46-7 8260B ND 4.2 ug/kg 1 Dichlorodifluoromethane 75-71-8 8260B ND 4.2 ug/kg 1 1,1-Dichloroethane 75-34-3 8260B ND 4.2 ug/kg 1 1,2-Dichloroethane 107-06-2 8260B ND 4.2 ug/kg 1 1,1-Dichloroethene 75-35-4 8260B ND 4.2 ug/kg 1 cis- 1,2-Dichloroethene 156-59-2 8260B ND 4.2 ug/kg 1 trans-1,2-Dichloroethene 156-60-5 8260B ND 4.2 ug/kg 1 1,2-Dichloropropane 78-87-5 8260B ND 4.2 ug/kg 1 cis- 1,3-Dichloropropene 10061-01-5 8260B ND 4.2 ug/kg 1 trans- 1,3-Dichloropropene 10061-02-6 8260B ND 4.2 ug/kg 1 Ethylbenzene 100-41-4 8260B ND 4.2 ug/kg 1 2-Hexanone 591-78-6 8260B ND 8.5 ug/kg 1 Isopropylbenzene 98-82-8 8260B ND 4.2 ug/kg 1 Methyl acetate 79-20-9 8260B ND 4.2 ug/kg 1 Methyl tertiary butyl ether (MTBE) 1634-04-4 8260B ND 4.2 ug/kg 1 4-Methyl-2-pentanone 108-10-1 8260B ND 8.5 ug/kg 1 Methylcyclohexane 108-87-2 8260B ND 4.2 ug/kg 1 Methylene chloride 75-09-2 8260B 6.9 4.2 ug/kg 1 Styrene 100-42-5 8260B ND 4.2 ug/kg 1 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 4.2 ug/kg 1 Tetrachloroethene 127-18-4 8260B ND 4.2 ug/kg 1 Toluene 108-88-3 8260B ND 4.2 ug/kg 1 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 8260B ND 4.2 ug/kg 1 1,2,4-Trichlorobenzene 120-82-1 8260B ND 4.2 ug/kg 1 1,1,1-Trichloroethane 71-55-6 8260B ND 4.2 ug/kg 1 1,1,2-Trichloroethane 79-00-5 8260B ND 4.2 ug/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID: TL14005-004 Description: TW-2 Matrix: Solid Date Sampled:12/13/2018 1400 % Solids: 94.6 12/14/2018 2152 Date Received:12/14/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Sample Wt.(g) 1 5035 8260B 1 12/27/20181906 JM1 93475 6.25 CAS Analytical Parameter Number Method Result Q LOQ Units Run Trichloroethene 79-01-6 8260B ND 4.2 ug/kg 1 Trichlorofluoromethane 75-69-4 8260B ND 4.2 ug/kg 1 Vinyl chloride 75-01-4 8260B ND 4.2 ug/kg 1 Xylenes (total) 1330-20-7 8260B ND 8.5 ug/kg 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 92 53-142 Bromofluorobenzene 90 47-138 Toluene-d8 100 68-124 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID: TL14005-005 Description: TW-4 Matrix: Solid Date Sampled:12/13/2018 1500 % Solids: 75.0 12/14/2018 2152 Date Received:12/14/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Sample Wt.(g) 1 5035 8260B 1 12/27/20181928 JM1 93475 5.47 CAS Analytical Parameter Number Method Result Q LOQ Units Run Acetone 67-64-1 8260B ND 24 ug/kg 1 Benzene 71-43-2 8260B ND 6.1 ug/kg 1 Bromodichloromethane 75-27-4 8260B ND 6.1 ug/kg 1 Bromoform 75-25-2 8260B ND 6.1 ug/kg 1 Bromomethane (Methyl bromide) 74-83-9 8260B ND 6.1 ug/kg 1 2-Butanone (MEK) 78-93-3 8260B ND 24 ug/kg 1 Carbon disulfide 75-15-0 8260B ND 6.1 ug/kg 1 Carbon tetrachloride 56-23-5 8260B ND 6.1 ug/kg 1 Chlorobenzene 108-90-7 8260B ND 6.1 ug/kg 1 Chloroethane 75-00-3 8260B ND 6.1 ug/kg 1 Chloroform 67-66-3 8260B ND 6.1 ug/kg 1 Chloromethane (Methyl chloride) 74-87-3 8260B ND 6.1 ug/kg 1 Cyclohexane 110-82-7 8260B ND 6.1 ug/kg 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260B ND 6.1 ug/kg 1 Dibromochloromethane 124-48-1 8260B ND 6.1 ug/kg 1 1,2-Dibromoethane (EDB) 106-93-4 8260B ND 6.1 ug/kg 1 1,2-Dichlorobenzene 95-50-1 8260B ND 6.1 ug/kg 1 1,3-Dichlorobenzene 541-73-1 8260B ND 6.1 ug/kg 1 1,4-Dichlorobenzene 106-46-7 8260B ND 6.1 ug/kg 1 Dichlorodifluoromethane 75-71-8 8260B ND 6.1 ug/kg 1 1,1-Dichloroethane 75-34-3 8260B ND 6.1 ug/kg 1 1,2-Dichloroethane 107-06-2 8260B ND 6.1 ug/kg 1 1,1-Dichloroethene 75-35-4 8260B ND 6.1 ug/kg 1 cis- 1,2-Dichloroethene 156-59-2 8260B ND 6.1 ug/kg 1 trans-1,2-Dichloroethene 156-60-5 8260B ND 6.1 ug/kg 1 1,2-Dichloropropane 78-87-5 8260B ND 6.1 ug/kg 1 cis- 1,3-Dichloropropene 10061-01-5 8260B ND 6.1 ug/kg 1 trans- 1,3-Dichloropropene 10061-02-6 8260B ND 6.1 ug/kg 1 Ethylbenzene 100-41-4 8260B ND 6.1 ug/kg 1 2-Hexanone 591-78-6 8260B ND 12 ug/kg 1 Isopropylbenzene 98-82-8 8260B ND 6.1 ug/kg 1 Methyl acetate 79-20-9 8260B ND 6.1 ug/kg 1 Methyl tertiary butyl ether (MTBE) 1634-04-4 8260B ND 6.1 ug/kg 1 4-Methyl-2-pentanone 108-10-1 8260B ND 12 ug/kg 1 Methylcyclohexane 108-87-2 8260B ND 6.1 ug/kg 1 Methylene chloride 75-09-2 8260B ND 6.1 ug/kg 1 Styrene 100-42-5 8260B ND 6.1 ug/kg 1 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 6.1 ug/kg 1 Tetrachloroethene 127-18-4 8260B ND 6.1 ug/kg 1 Toluene 108-88-3 8260B ND 6.1 ug/kg 1 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 8260B ND 6.1 ug/kg 1 1,2,4-Trichlorobenzene 120-82-1 8260B ND 6.1 ug/kg 1 1,1,1-Trichloroethane 71-55-6 8260B ND 6.1 ug/kg 1 1,1,2-Trichloroethane 79-00-5 8260B ND 6.1 ug/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID: TL14005-005 Description: TW-4 Matrix: Solid Date Sampled:12/13/2018 1500 % Solids: 75.0 12/14/2018 2152 Date Received:12/14/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Sample Wt.(g) 1 5035 8260B 1 12/27/20181928 JM1 93475 5.47 CAS Analytical Parameter Number Method Result Q LOQ Units Run Trichloroethene 79-01-6 8260B ND 6.1 ug/kg 1 Trichlorofluoromethane 75-69-4 8260B ND 6.1 ug/kg 1 Vinyl chloride 75-01-4 8260B ND 6.1 ug/kg 1 Xylenes (total) 1330-20-7 8260B ND 12 ug/kg 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 59 53-142 Bromofluorobenzene N 38 47-138 Toluene-d8 85 68-124 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID: TL14005-006 Description: TW-3 Matrix: Solid Date Sampled:12/13/2018 1540 % Solids: 78.8 12/14/2018 2152 Date Received:12/14/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Sample Wt.(g) 1 5035 8260B 1 12/27/20181951 JM1 93475 5.52 3 5035 High 8260B 1 12/31/2018 1927 JM1 93761 5.85 CAS Analytical Parameter Number Method Result Q LOQ Units Run Acetone 67-64-1 8260B 62 23 ug/kg 1 Benzene 71-43-2 8260B 13 5.8 ug/kg 1 Bromodichloromethane 75-27-4 8260B ND 5.8 ug/kg 1 Bromoform 75-25-2 8260B ND 5.8 ug/kg 1 Bromomethane (Methyl bromide) 74-83-9 8260B ND 5.8 ug/kg 1 2-Butanone (MEK) 78-93-3 8260B ND 23 ug/kg 1 Carbon disulfide 75-15-0 8260B ND 5.8 ug/kg 1 Carbon tetrachloride 56-23-5 8260B ND 5.8 ug/kg 1 Chlorobenzene 108-90-7 8260B ND 5.8 ug/kg 1 Chloroethane 75-00-3 8260B ND 5.8 ug/kg 1 Chloroform 67-66-3 8260B 15 5.8 ug/kg 1 Chloromethane (Methyl chloride) 74-87-3 8260B ND 5.8 ug/kg 1 Cyclohexane 110-82-7 8260B 1300 340 ug/kg 3 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260B ND 5.8 ug/kg 1 Dibromochloromethane 124-48-1 8260B ND 5.8 ug/kg 1 1,2-Dibromoethane (EDB) 106-93-4 8260B ND 5.8 ug/kg 1 1,2-Dichlorobenzene 95-50-1 8260B ND 5.8 ug/kg 1 1,3-Dichlorobenzene 541-73-1 8260B ND 5.8 ug/kg 1 1,4-Dichlorobenzene 106-46-7 8260B ND 5.8 ug/kg 1 Dichlorodifluoromethane 75-71-8 8260B ND 5.8 ug/kg 1 1,1-Dichloroethane 75-34-3 8260B ND 5.8 ug/kg 1 1,2-Dichloroethane 107-06-2 8260B ND 5.8 ug/kg 1 1,1-Dichloroethene 75-35-4 8260B ND 5.8 ug/kg 1 cis- 1,2-Dichloroethene 156-59-2 8260B ND 5.8 ug/kg 1 trans- 1,2-Dichloroethene 156-60-5 8260B ND 5.8 ug/kg 1 1,2-Dichloropropane 78-87-5 8260B ND 5.8 ug/kg 1 cis- 1,3-Dichloropropene 10061-01-5 8260B ND 5.8 ug/kg 1 trans- 1,3-Dichloropropene 10061-02-6 8260B ND 5.8 ug/kg 1 Ethylbenzene 100-41-4 8260B 980 340 ug/kg 3 2-Hexanone 591-78-6 8260B ND 12 ug/kg 1 Isopropylbenzene 98-82-8 8260B 130 5.8 ug/kg 1 Methyl acetate 79-20-9 8260B ND 5.8 ug/kg 1 Methyl tertiary butyl ether (MTBE) 1634-04-4 8260B ND 5.8 ug/kg 1 4-Methyl-2-pentanone 108-10-1 8260B ND 12 ug/kg 1 Methylcyclohexane 108-87-2 8260B 4400 340 ug/kg 3 Methylene chloride 75-09-2 8260B 11 5.8 ug/kg 1 Styrene 100-42-5 8260B ND 5.8 ug/kg 1 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 5.8 ug/kg 1 Tetrachloroethene 127-18-4 8260B ND 5.8 ug/kg 1 Toluene 108-88-3 8260B 7.1 5.8 ug/kg 1 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 8260B ND 5.8 ug/kg 1 1,2,4-Trichlorobenzene 120-82-1 8260B ND 5.8 ug/kg 1 1,1,1-Trichloroethane 71-55-6 8260B ND 5.8 ug/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID: TL14005-006 Description: TW-3 Matrix: Solid Date Sampled:12/13/2018 1540 % Solids: 78.8 12/14/2018 2152 Date Received:12/14/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Sample Wt.(g) 1 5035 8260B 1 12/27/20181951 JM1 93475 5.52 3 5035 High 8260B 1 12/31/2018 1927 JM1 93761 5.85 CAS Analytical Parameter Number Method Result Q LOQ Units Run 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes (total) Surrogate 1,2-Dichloroethane-d4 Bromofluorobenzene Toluene-d8 79-00-5 8260B ND 5.8 79-01-6 8260B ND 5.8 75-69-4 8260B ND 5.8 75-01-4 8260B ND 5.8 1330-20-7 8260B 290 12 Run 1 Acceptance Run 3 Acceptance Q % Recovery Limits Q % Recovery Limits 97 53-142 100 53-142 98 47-138 117 47-138 110 68-124 108 68-124 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com ug/kg 1 ug/kg 1 ug/kg 1 ug/kg 1 ug/kg 1 QC Summary Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS - MB Sample ID: TQ93475-001 Matrix: Solid Batch: 93475 Prep Method: 5035 Analytical Method: 8260B Parameter Result Q Dil LOQ Units Analysis Date Acetone ND 1 20 ug/kg 12/27/2018 1101 Benzene ND 1 5.0 ug/kg 12/27/2018 1101 Bromodichloromethane ND 1 5.0 ug/kg 12/27/2018 1101 Bromoform ND 1 5.0 ug/kg 12/27/2018 1101 Bromomethane (Methyl bromide) ND 1 5.0 ug/kg 12/27/2018 1101 2-Butanone (MEK) ND 1 20 ug/kg 12/27/2018 1101 Carbon disulfide ND 1 5.0 ug/kg 12/27/2018 1101 Carbon tetrachloride ND 1 5.0 ug/kg 12/27/2018 1101 Chlorobenzene ND 1 5.0 ug/kg 12/27/2018 1101 Chloroethane ND 1 5.0 ug/kg 12/27/2018 1101 Chloroform ND 1 5.0 ug/kg 12/27/2018 1101 Chloromethane (Methyl chloride) ND 1 5.0 ug/kg 12/27/2018 1101 Cyclohexane ND 1 5.0 ug/kg 12/27/2018 1101 1,2-Dibromo-3-chloropropane (DBCP) ND 1 5.0 ug/kg 12/27/2018 1101 Dibromochloromethane ND 1 5.0 ug/kg 12/27/2018 1101 1,2-Dibromoethane (EDB) ND 1 5.0 ug/kg 12/27/2018 1101 1,2-Dichlorobenzene ND 1 5.0 ug/kg 12/27/2018 1101 1,3-Dichlorobenzene ND 1 5.0 ug/kg 12/27/2018 1101 1,4-Dichlorobenzene ND 1 5.0 ug/kg 12/27/2018 1101 Dichlorodifluoromethane ND 1 5.0 ug/kg 12/27/2018 1101 1,1-Dichloroethane ND 1 5.0 ug/kg 12/27/2018 1101 1,2-Dichloroethane ND 1 5.0 ug/kg 12/27/2018 1101 1,1-Dichloroethene ND 1 5.0 ug/kg 12/27/2018 1101 cis- 1,2-Dichloroethene ND 1 5.0 ug/kg 12/27/2018 1101 trans- 1,2-Dichloroethene ND 1 5.0 ug/kg 12/27/2018 1101 1,2-Dichloropropane ND 1 5.0 ug/kg 12/27/2018 1101 cis- 1,3-Dichloropropene ND 1 5.0 ug/kg 12/27/2018 1101 trans- 1,3-Dichloropropene ND 1 5.0 ug/kg 12/27/2018 1101 Ethylbenzene ND 1 5.0 ug/kg 12/27/2018 1101 2-Hexanone ND 1 10 ug/kg 12/27/2018 1101 Isopropylbenzene ND 1 5.0 ug/kg 12/27/2018 1101 Methyl acetate ND 1 5.0 ug/kg 12/27/2018 1101 Methyl tertiary butyl ether (MTBE) ND 1 5.0 ug/kg 12/27/2018 1101 4-Methyl-2-pentanone ND 1 10 ug/kg 12/27/2018 1101 Methylcyclohexane ND 1 5.0 ug/kg 12/27/2018 1101 Methylene chloride ND 1 5.0 ug/kg 12/27/2018 1101 Styrene ND 1 5.0 ug/kg 12/27/2018 1101 1,1,2,2-Tetrachloroethane ND 1 5.0 ug/kg 12/27/2018 1101 Tetrachloroethene ND 1 5.0 ug/kg 12/27/2018 1101 Toluene ND 1 5.0 ug/kg 12/27/2018 1101 1,1,2-Trichloro-1,2,2-Trifluoroethane ND 1 5.0 ug/kg 12/27/2018 1101 1,2,4-Trichlorobenzene ND 1 5.0 ug/kg 12/27/2018 1101 1,1,1-Trichloroethane ND 1 5.0 ug/kg 12/27/2018 1101 1,1,2-Trichloroethane ND 1 5.0 ug/kg 12/27/2018 1101 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS - MB Sample ID: TQ93475-001 Matrix: Solid Batch:93475 Prep Method: 5035 Analytical Method: 8260B Parameter Result Q Dil LOQ Units Analysis Date Trichloroethene ND 1 5.0 ug/kg 12/27/2018 1101 Trichlorofluoromethane ND 1 5.0 ug/kg 12/27/2018 1101 Vinyl chloride ND 1 5.0 ug/kg 12/27/2018 1101 Xylenes (total) ND 1 10 ug/kg 12/27/2018 1101 Acceptance Surrogate Q % Rec Limit 1,2-Dichloroethane-d4 87 53-142 Bromofluorobenzene 103 47-138 Toluene-d8 99 68-124 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS - LCS Sample ID: TQ93475-002 Matrix: Solid Batch: 93475 Prep Method: 5035 Analytical Method: 8260B Spike Amount Result % Rec Parameter (ug/kg) (ug/kg) Q Dil % Rec Limit Analysis Date Acetone 100 75 1 75 60-140 12/27/2018 1017 Benzene 50 49 1 99 70-130 12/27/2018 1017 Bromodichloromethane 50 47 1 95 70-130 12/27/2018 1017 Bromoform 50 54 1 107 70-130 12/27/2018 1017 Bromomethane (Methyl bromide) 50 51 1 103 70-130 12/27/2018 1017 2-Butanone (MEK) 100 86 1 86 60-140 12/27/2018 1017 Carbon disulfide 50 53 1 106 70-130 12/27/2018 1017 Carbon tetrachloride 50 50 1 100 70-130 12/27/2018 1017 Chlorobenzene 50 52 1 105 70-130 12/27/2018 1017 Chloroethane 50 50 1 99 70-130 12/27/2018 1017 Chloroform 50 47 1 93 70-130 12/27/2018 1017 Chloromethane (Methyl chloride) 50 41 1 82 60-140 12/27/2018 1017 Cyclohexane 50 46 1 92 70-130 12/27/2018 1017 1,2-Dibromo-3-chloropropane (DBCP) 50 48 1 97 70-130 12/27/2018 1017 Dibromochloromethane 50 50 1 101 70-130 12/27/2018 1017 1,2-Dibromoethane (EDB) 50 51 1 102 70-130 12/27/2018 1017 1,2-Dichlorobenzene 50 53 1 107 70-130 12/27/2018 1017 1,3-Dichlorobenzene 50 54 1 107 70-130 12/27/2018 1017 1,4-Dichlorobenzene 50 54 1 108 70-130 12/27/2018 1017 Dichlorodifluoromethane 50 59 1 117 60-140 12/27/2018 1017 1,1-Dichloroethane 50 44 1 88 70-130 12/27/2018 1017 1,2-Dichloroethane 50 45 1 91 70-130 12/27/2018 1017 1,1-Dichloroethene 50 53 1 106 70-130 12/27/2018 1017 cis- 1,2-Dichloroethene 50 49 1 98 70-130 12/27/2018 1017 trans- 1,2-Dichloroethene 50 49 1 99 70-130 12/27/2018 1017 1,2-Dichloropropane 50 40 1 81 70-130 12/27/2018 1017 cis- 1,3-Dichloropropene 50 44 1 87 70-130 12/27/2018 1017 trans- 1,3-Dichloropropene 50 42 1 83 70-130 12/27/2018 1017 Ethylbenzene 50 55 1 110 70-130 12/27/2018 1017 2-Hexanone 100 83 1 83 70-130 12/27/2018 1017 Isopropylbenzene 50 53 1 106 70-130 12/27/2018 1017 Methyl acetate 50 38 1 75 70-130 12/27/2018 1017 Methyl tertiary butyl ether (MTBE) 50 46 1 91 70-130 12/27/2018 1017 4-Methyl-2-pentanone 100 87 1 87 70-130 12/27/2018 1017 Methylcyclohexane 50 54 1 108 70-130 12/27/2018 1017 Methylene chloride 50 48 1 96 70-130 12/27/2018 1017 Styrene 50 53 1 107 70-130 12/27/2018 1017 1,1,2,2-Tetrachloroethane 50 46 1 92 70-130 12/27/2018 1017 Tetrachloroethene 50 59 1 117 70-130 12/27/2018 1017 Toluene 50 52 1 105 70-130 12/27/2018 1017 1,1,2-Trichloro-1,2,2-Trifluoroethane 50 52 1 104 70-130 12/27/2018 1017 1,2,4-Trichlorobenzene 50 59 1 118 70-130 12/27/2018 1017 1,1,1-Trichloroethane 50 48 1 96 70-130 12/27/2018 1017 1,1,2-Trichloroethane 50 50 1 100 70-130 12/27/2018 1017 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS - LCS Sample ID: TQ93475-002 Matrix: Solid Batch:93475 Prep Method: 5035 Analytical Method: 8260B Spike Amount Result % Rec Parameter (ug/kg) (ug/kg) Q Dil % Rec Limit Analysis Date Trichloroethene 50 55 1 110 70-130 12/27/2018 1017 Trichlorofluoromethane 50 53 1 106 70-130 12/27/2018 1017 Vinyl chloride 50 49 1 97 70-130 12/27/2018 1017 Xylenes (total) 100 110 1 109 70-130 12/27/2018 1017 Acceptance Surrogate Q % Rec Limit 1,2-Dichloroethane-d4 99 53-142 Bromofluorobenzene 124 47-138 Toluene-d8 113 68-124 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS - LCSD Sample ID: TQ93475-003 Matrix: Solid Batch: 93475 Prep Method: 5035 Analytical Method: 8260B Spike Amount Result % Rec % RPD Parameter (ug/kg) (ug/kg) Q Dil % Rec % RPD Limit Limit Analysis Date Acetone 100 67 1 67 12 60-140 20 12/27/2018 1039 Benzene 50 48 1 97 2.0 70-130 20 12/27/2018 1039 Bromodichloromethane 50 47 1 93 1.6 70-130 20 12/27/2018 1039 Bromoform 50 53 1 106 0.83 70-130 20 12/27/2018 1039 Bromomethane (Methyl bromide) 50 49 1 98 5.0 70-130 20 12/27/2018 1039 2-Butanone (MEK) 100 80 1 80 6.5 60-140 20 12/27/2018 1039 Carbon disulfide 50 50 1 100 5.6 70-130 20 12/27/2018 1039 Carbon tetrachloride 50 48 1 96 4.3 70-130 20 12/27/2018 1039 Chlorobenzene 50 51 1 103 1.7 70-130 20 12/27/2018 1039 Chloroethane 50 46 1 93 6.8 70-130 20 12/27/2018 1039 Chloroform 50 45 1 91 2.4 70-130 20 12/27/2018 1039 Chloromethane (Methyl chloride) 50 39 1 78 4.4 60-140 20 12/27/2018 1039 Cyclohexane 50 44 1 87 5.2 70-130 20 12/27/2018 1039 1,2-Dibromo-3-chloropropane (DBCP) 50 48 1 96 0.66 70-130 20 12/27/2018 1039 Dibromochloromethane 50 50 1 100 0.58 70-130 20 12/27/2018 1039 1,2-Dibromoethane (EDB) 50 51 1 102 0.55 70-130 20 12/27/2018 1039 1,2-Dichlorobenzene 50 52 1 105 2.0 70-130 20 12/27/2018 1039 1,3-Dichlorobenzene 50 53 1 106 1.3 70-130 20 12/27/2018 1039 1,4-Dichlorobenzene 50 53 1 106 2.2 70-130 20 12/27/2018 1039 Dichlorodifluoromethane 50 52 1 105 11 60-140 20 12/27/2018 1039 1,1-Dichloroethane 50 43 1 86 1.9 70-130 20 12/27/2018 1039 1,2-Dichloroethane 50 45 1 89 1.6 70-130 20 12/27/2018 1039 1,1-Dichloroethene 50 50 1 100 5.1 70-130 20 12/27/2018 1039 cis- 1,2-Dichloroethene 50 48 1 95 2.6 70-130 20 12/27/2018 1039 trans- 1,2-Dichloroethene 50 48 1 97 2.0 70-130 20 12/27/2018 1039 1,2-Dichloropropane 50 40 1 81 0.13 70-130 20 12/27/2018 1039 cis- 1,3-Dichloropropene 50 43 1 87 0.79 70-130 20 12/27/2018 1039 trans- 1,3-Dichloropropene 50 41 1 82 0.97 70-130 20 12/27/2018 1039 Ethylbenzene 50 54 1 108 1.1 70-130 20 12/27/2018 1039 2-Hexanone 100 78 1 78 6.4 70-130 20 12/27/2018 1039 Isopropylbenzene 50 51 1 102 3.1 70-130 20 12/27/2018 1039 Methyl acetate 50 37 1 74 2.5 70-130 20 12/27/2018 1039 Methyl tertiary butyl ether (MTBE) 50 45 1 91 0.52 70-130 20 12/27/2018 1039 4-Methyl-2-pentanone 100 86 1 86 1.3 70-130 20 12/27/2018 1039 Methylcyclohexane 50 51 1 102 5.5 70-130 20 12/27/2018 1039 Methylene chloride 50 48 1 95 0.63 70-130 20 12/27/2018 1039 Styrene 50 53 1 105 1.3 70-130 20 12/27/2018 1039 1,1,2,2-Tetrachloroethane 50 45 1 91 0.87 70-130 20 12/27/2018 1039 Tetrachloroethene 50 56 1 112 4.3 70-130 20 12/27/2018 1039 Toluene 50 51 1 102 2.9 70-130 20 12/27/2018 1039 1,1,2-Trichloro-1,2,2-Trifluoroethane 50 48 1 96 7.5 70-130 20 12/27/2018 1039 1,2,4-Trichlorobenzene 50 57 1 114 3.7 70-130 20 12/27/2018 1039 1,1,1-Trichloroethane 50 46 1 92 4.4 70-130 20 12/27/2018 1039 1,1,2-Trichloroethane 50 49 1 99 1.1 70-130 20 12/27/2018 1039 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS - LCSD Sample ID: TQ93475-003 Matrix: Solid Batch:93475 Prep Method: 5035 Analytical Method: 8260B Spike Amount Result % Rec % RPD Parameter (ug/kg) (ug/kg) Q Dil % Rec % RPD Limit Limit Analysis Date Trichloroethene 50 53 1 107 3.0 70-130 20 12/27/2018 1039 Trichlorofluoromethane 50 49 1 98 7.7 70-130 20 12/27/2018 1039 Vinyl chloride 50 45 1 91 7.2 70-130 20 12/27/2018 1039 Xylenes (total) 100 110 1 106 2.6 70-130 20 12/27/2018 1039 Acceptance Surrogate Q % Rec Limit 1,2-Dichloroethane-d4 98 53-142 Bromofluorobenzene 121 47-138 Toluene-d8 111 68-124 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS - MB Sample ID: TQ93761-001 Matrix: Solid Batch: 93761 Prep Method: 5035 High Analytical Method: 8260B Parameter Result Q Dil LOQ Units Analysis Date Cyclohexane ND 1 250 ug/kg 12/31/20181843 Ethylbenzene ND 1 250 ug/kg 12/31/20181843 Methylcyclohexane ND 1 250 ug/kg 12/31/20181843 Surrogate Q % Rec Acceptance Limit 1,2-Dichloroethane-d4 90 53-142 Bromofluorobenzene 106 47-138 Toluene-d8 103 68-124 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Volatile Organic Compounds by GC/MS - LCS Sample ID: TQ93761-002 Matrix: Solid Batch: 93761 Prep Method: 5035 High Analytical Method: 8260B Spike Amount Result % Rec Parameter (ug/kg) (ug/kg) Q Dil % Rec Limit Analysis Date Cyclohexane 2500 2400 1 97 70-130 12/31/20181820 Ethylbenzene 2500 2900 1 117 70-130 12/31/20181820 Methylcyclohexane 2500 3000 1 118 70-130 12/31/20181820 Acceptance Surrogate Q % Rec Limit 1,2-Dichloroethane-d4 99 53-142 Bromofluorobenzene 118 47-138 Toluene-d8 107 68-124 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Chain of Custody and Miscellaneous Documents Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com SHEALY ENVIRONMENTAL SERVICES, INC. to S z I� � E C } LU C 0 ZZ E Cu . w z- 4 CL tm 0 zy CC III QD 6 Y F' CL3 cc t �►i 0 I� H R � �H Soli rx.wr GiR�C6F' . v a � 4 4 l+ n o Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com SHEALY ENVIRONMENTAL SERVICES, INC. L z 7I r� +,y i Cg z� 010 Hd9 TOP WA E k $ y D 11 Q I I Ii 6 6 r i •�i 4 Is' a Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com SHEALY ENVIRONMENTAL SERVICES, INC. 6t5€aty Envlrt r encal 9.r.im. hiG. Pape . cf i Dmwuert Pu nabu. bdbW L su- t 4 tJLeUi�w l]vle: B 2r3r�18 Sample Receipt C:he kJ� list sp Client.,. dA�1a44, f/ noler Ttiected byr'deUe: I leans of reczipt; S)ESI C] Client UPS ❑ FL,6Ex G] tether I]. Vdem C"tody seals preneni va that cooler? LI Yol Q NTu O NA 2- if custpdy seals v.etL resen ware they inia::l. and iii)troken? H Strip IT), _ . Chlorine Strip ID: Tested by: . Ck.iginal temperatur-u urN.m Teceipt.+ Der[v44( on"Wd) tednperaturc upon receipt; INDSalid Snap -{-up 15- t � (0, o,k,{ateINC .-- '+ °C I �c '++leatltcd: t�i mpcxa:ur0 k ❑AriustRotttes FR G mfl): [L 01111 treclicm Factor. ° Method of taolaut: t t ��'_I. I= El Ice Palo ❑ ]cpc ❑ None I❑ Yes �] N O 0" I 3, If tcmperatum of any cooler moeec]ed 6, 0°C, wag Pri+jec# autager Notiliad? ]'IM -rlms Nod fed by: phone 1 Mail I fuco-tO-face (ckrcle one). Ym 0 No f , NA. 4. 1s ttku wmmerctal courier's jacking atip 4twubcd to this form.') 'eg ❑Rio 5. Were pgvperuustudy procadl ryes (reIingoi!3bCdfreceireci) followed? s Q No 6- W4;Tr, sample IDS liAW on the CQC? je+jas I❑ No 7, Wcre sample IDs listed Ott all sum le containers? Yes CJ N, 9. Way wl.1[ anion date & tine listed Oti iht Co " ) es IQ No 9. W7 s collection date , tuna listed on all sample crm taiTwo? Yes Q No I ll, Did all C4utainea label infrnrtation (ID, deatp, time) agree 1vith the COC? 'fee ❑ No 11, WEM tests to be perfamod listed m the COC'� Eyes ❑ No 12. Did all sampl aariVe ill tfLe ptcrpu oontainetm Fiat' each test anWor in good canditirm (uubnolccat, lids On, etc_)' kE]YO3 ❑ No I3. 'Wras aelequates saaitpte vvIumo mailable? ❑ No 14- wuro all samples muived wKbin'/i the holding tlma or 48 llvm, whichever carer, frst? o 15. Were any s�vtlpl�s caintairners nlissur�re:xcerss (circle one samples Not listed ein (Doc'! 16, leas VOA and RSK-1?5 samples, were bubbles pragent'pr rnm in diametefi m ❑ e A arty of the VOA via]s? ) NLo NA 1?_ iJk+ere Al Lll�oAnewLafnutriaiit sam cs received 41E4 pH of < 2?LJ NO NA 18. Jere all cy�mide sam im r te4ved at a p14 > l2 and sulfide saFiirles re�dwed at a : ❑ No P19A 19. Wem all app tea e NH3,gY.N/ yanftipbmD 25 (� O,Sm�,L) satztpl�s ce of -residual chlorine? LI Yeg El No 14A 20- Rim client rematrkslrequests (ix, rcquested di Ililtons, l~MSlJh, ED dmigmtion-, etc-,.) eorrcctlg tran .ribcd from the CDC into the comment section in LLWS'? e� No 127- Wa3 flit awce number lisred on dita container labW If }yes 20it U 16 ~ Sample Fr'eservatiou (Mlm be couimpttl,�,d for any mmple(s) incorrectly preserved o; with headspace.) Sar>iple(s1 ware received inucHTectlY ]w wru d and lmilr� adjusted accrrjl ngly ill sample receiving with _.. niL ucircle mle:142SO4, HI143, HG. NatkT uS;ng SR f iiTnc o€ premnatitm _ If mare than -one pmservti4 vC is nft&d, plGaSa note irk rho comments below, arrtple(s) were reooivM with h*blas >6 m n in ilianftar. Samlites(s) _. were received wFtla TRC= 0,5 mVL (If#14 is no) mid were adjusted accordingly :n sample rectivilig witla sodium thiomiWe (Na,SaO,) with Shealy ID: SR barcode labels srpplied by- Date: _ ' Ccsmmcrrts: Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Mid -Atlantic Associates, Inc. 1125 East Morehead Street Suite # 104 Charlotte, NC 28204 Attention: Carl Hewett Project Name: Parking Lot, Concord, NC Project Number: OOOH1324.00 Lot Number:TL18048 Date Completed:12/31/2018 01/02/2019 2:47 PM Approved and released by: Project Manager: Kelly M. Nance PCCRFp d AM AC CF ED I T E D qB 11900 ELAP The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 1 of 40 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Mid -Atlantic Associates, Inc. 1125 East Morehead Street Suite # 104 Charlotte, NC 28204 Attention: Carl Hewett Project Name: Parking Lot, Concord, NC Project Number: OOOH1324.00 Lot Number:TL18047 Date Completed:12/21/2018 12/21/2018 3:27 PM Approved and released by: Project Manager: Kelly M. Nance PCCRFp d AM AC CF ED I T E D qB 11900 ELAP The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 1 of 15 SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Mid -Atlantic Associates, Inc. Lot Number: TL18047 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPS or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 2 of 15 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Mid -Atlantic Associates, Inc. Lot Number: TL18047 Sample Number Sample ID Matrix Date Sampled Date Received 001 MW-2 Aqueous 12/17/20181350 12/18/2018 (1 sample) Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 3 of 15 SHEALY ENVIRONMENTAL SERVICES, INC. Detection Summary Mid -Atlantic Associates, Inc. Lot Number: TL18047 Sample Sample ID Matrix Parameter Method Result Q Units Page (0 detections) Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 4 of 15 Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID:TL18047-001 Description: MW-2 Matrix: Aqueous Date Sampled:12/17/2018 1350 Date Received:12/18/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 12/21/20181147 BWS 93108 CAS Analytical Parameter Number Method Result Q LOQ Units Run Acetone 67-64-1 8260B ND 20 ug/L 1 Benzene 71-43-2 8260B ND 1.0 ug/L 1 Bromodichloromethane 75-27-4 8260B ND 1.0 ug/L 1 Bromoform 75-25-2 8260B ND 1.0 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260B ND 2.0 ug/L 1 2-Butanone (MEK) 78-93-3 8260B ND 10 ug/L 1 Carbon disulfide 75-15-0 8260B ND 1.0 ug/L 1 Carbon tetrachloride 56-23-5 8260B ND 1.0 ug/L 1 Chlorobenzene 108-90-7 8260B ND 1.0 ug/L 1 Chloroethane 75-00-3 8260B ND 2.0 ug/L 1 Chloroform 67-66-3 8260B ND 1.0 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260B ND 1.0 ug/L 1 Cyclohexane 110-82-7 8260B ND 1.0 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260B ND 1.0 ug/L 1 Dibromochloromethane 124-48-1 8260B ND 1.0 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260B ND 1.0 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260B ND 1.0 ug/L 1 1,3-Dichlorobenzene 541-73-1 8260B ND 1.0 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260B ND 1.0 ug/L 1 Dichlorodifluoromethane 75-71-8 8260B ND 2.0 ug/L 1 1,1-Dichloroethane 75-34-3 8260B ND 1.0 ug/L 1 1,2-Dichloroethane 107-06-2 8260B ND 1.0 ug/L 1 1,1-Dichloroethene 75-35-4 8260B ND 1.0 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260B ND 1.0 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260B ND 1.0 ug/L 1 1,2-Dichloropropane 78-87-5 8260B ND 1.0 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260B ND 1.0 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260B ND 1.0 ug/L 1 Ethylbenzene 100-41-4 8260B ND 1.0 ug/L 1 2-Hexanone 591-78-6 8260B ND 10 ug/L 1 Isopropylbenzene 98-82-8 8260B ND 1.0 ug/L 1 Methyl acetate 79-20-9 8260B ND 1.0 ug/L 1 Methyl tertiary butyl ether (MTBE) 1634-04-4 8260B ND 1.0 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260B ND 10 ug/L 1 Methylcyclohexane 108-87-2 8260B ND 5.0 ug/L 1 Methylene chloride 75-09-2 8260B ND 1.0 ug/L 1 Styrene 100-42-5 8260B ND 1.0 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1.0 ug/L 1 Tetrachloroethene 127-18-4 8260B ND 1.0 ug/L 1 Toluene 108-88-3 8260B ND 1.0 ug/L 1 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 8260B ND 1.0 ug/L 1 1,2,4-Trichlorobenzene 120-82-1 8260B ND 1.0 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260B ND 1.0 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260B ND 1.0 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 5 of 15 Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID:TL18047-001 Description: MW-2 Matrix: Aqueous Date Sampled:12/17/2018 1350 Date Received:12/18/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 12/21/20181147 BWS 93108 CAS Analytical Parameter Number Method Result Q LOQ Units Run Trichloroethene 79-01-6 8260B ND 1.0 ug/L 1 Trichlorofluoromethane 75-69-4 8260B ND 1.0 ug/L 1 Vinyl chloride 75-01-4 8260B ND 1.0 ug/L 1 Xylenes (total) 1330-20-7 8260B ND 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 89 70-130 Bromofluorobenzene 98 70-130 Toluene-d8 102 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 6 of 15 QC Summary Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 7 of 15 Volatile Organic Compounds by GC/MS - MB Sample ID: TQ93108-001 Matrix: Aqueous Batch: 93108 Prep Method: 5030E Analytical Method: 8260B Parameter Result Q Dil LOQ Units Analysis Date Acetone ND 1 20 ug/L 12/21/2018 1106 Benzene ND 1 1.0 ug/L 12/21/2018 1106 Bromodichloromethane ND 1 1.0 ug/L 12/21/2018 1106 Bromoform ND 1 1.0 ug/L 12/21/2018 1106 Bromomethane (Methyl bromide) ND 1 2.0 ug/L 12/21/2018 1106 2-Butanone (MEK) ND 1 10 ug/L 12/21/2018 1106 Carbon disulfide ND 1 1.0 ug/L 12/21/2018 1106 Carbon tetrachloride ND 1 1.0 ug/L 12/21/2018 1106 Chlorobenzene ND 1 1.0 ug/L 12/21/2018 1106 Chloroethane ND 1 2.0 ug/L 12/21/2018 1106 Chloroform ND 1 1.0 ug/L 12/21/2018 1106 Chloromethane (Methyl chloride) ND 1 1.0 ug/L 12/21/2018 1106 Cyclohexane ND 1 1.0 ug/L 12/21/2018 1106 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 ug/L 12/21/2018 1106 Dibromochloromethane ND 1 1.0 ug/L 12/21/2018 1106 1,2-Dibromoethane (EDB) ND 1 1.0 ug/L 12/21/2018 1106 1,2-Dichlorobenzene ND 1 1.0 ug/L 12/21/2018 1106 1,3-Dichlorobenzene ND 1 1.0 ug/L 12/21/2018 1106 1,4-Dichlorobenzene ND 1 1.0 ug/L 12/21/2018 1106 Dichlorodifluoromethane ND 1 2.0 ug/L 12/21/2018 1106 1,1-Dichloroethane ND 1 1.0 ug/L 12/21/2018 1106 1,2-Dichloroethane ND 1 1.0 ug/L 12/21/2018 1106 1,1-Dichloroethene ND 1 1.0 ug/L 12/21/2018 1106 cis- 1,2-Dichloroethene ND 1 1.0 ug/L 12/21/2018 1106 trans- 1,2-Dichloroethene ND 1 1.0 ug/L 12/21/2018 1106 1,2-Dichloropropane ND 1 1.0 ug/L 12/21/2018 1106 cis- 1,3-Dichloropropene ND 1 1.0 ug/L 12/21/2018 1106 trans- 1,3-Dichloropropene ND 1 1.0 ug/L 12/21/2018 1106 Ethylbenzene ND 1 1.0 ug/L 12/21/2018 1106 2-Hexanone ND 1 10 ug/L 12/21/2018 1106 Isopropylbenzene ND 1 1.0 ug/L 12/21/2018 1106 Methyl acetate ND 1 1.0 ug/L 12/21/2018 1106 Methyl tertiary butyl ether (MTBE) ND 1 1.0 ug/L 12/21/2018 1106 4-Methyl-2-pentanone ND 1 10 ug/L 12/21/2018 1106 Methylcyclohexane ND 1 5.0 ug/L 12/21/2018 1106 Methylene chloride ND 1 1.0 ug/L 12/21/2018 1106 Styrene ND 1 1.0 ug/L 12/21/2018 1106 1,1,2,2-Tetrachloroethane ND 1 1.0 ug/L 12/21/2018 1106 Tetrachloroethene ND 1 1.0 ug/L 12/21/2018 1106 Toluene ND 1 1.0 ug/L 12/21/2018 1106 1,1,2-Trichloro-1,2,2-Trifluoroethane ND 1 1.0 ug/L 12/21/2018 1106 1,2,4-Trichlorobenzene ND 1 1.0 ug/L 12/21/2018 1106 1,1,1-Trichloroethane ND 1 1.0 ug/L 12/21/2018 1106 1,1,2-Trichloroethane ND 1 1.0 ug/L 12/21/2018 1106 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 8 of 15 Volatile Organic Compounds by GC/MS - MB Sample ID: TQ93108-001 Matrix: Aqueous Batch: 93108 Prep Method: 5030E Analytical Method: 8260B Parameter Result Q Dil LOQ Units Analysis Date Trichloroethene ND 1 1.0 ug/L 12/21/2018 1106 Trichlorofluoromethane ND 1 1.0 ug/L 12/21/2018 1106 Vinyl chloride ND 1 1.0 ug/L 12/21/2018 1106 Xylenes (total) ND 1 1.0 ug/L 12/21/2018 1106 Acceptance Surrogate Q % Rec Limit 1,2-Dichloroethane-d4 88 70-130 Bromofluorobenzene 96 70-130 Toluene-d8 97 70-130 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 9 of 15 Volatile Organic Compounds by GC/MS - LCS Sample ID: TQ93108-002 Matrix: Aqueous Batch: 93108 Prep Method: 5030E Analytical Method: 8260B Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 93 1 93 60-140 12/21/2018 1010 Benzene 50 51 1 102 70-130 12/21/2018 1010 Bromodichloromethane 50 49 1 98 70-130 12/21/2018 1010 Bromoform 50 55 1 109 70-130 12/21/2018 1010 Bromomethane (Methyl bromide) 50 44 1 87 70-130 12/21/2018 1010 2-Butanone (MEK) 100 99 1 99 70-130 12/21/2018 1010 Carbon disulfide 50 47 1 94 70-130 12/21/2018 1010 Carbon tetrachloride 50 47 1 94 70-130 12/21/2018 1010 Chlorobenzene 50 50 1 101 70-130 12/21/2018 1010 Chloroethane 50 45 1 90 70-130 12/21/2018 1010 Chloroform 50 47 1 95 70-130 12/21/2018 1010 Chloromethane (Methyl chloride) 50 40 1 79 60-140 12/21/2018 1010 Cyclohexane 50 53 1 106 70-130 12/21/2018 1010 1,2-Dibromo-3-chloropropane (DBCP) 50 49 1 97 70-130 12/21/2018 1010 Dibromochloromethane 50 52 1 103 70-130 12/21/2018 1010 1,2-Dibromoethane (EDB) 50 53 1 106 70-130 12/21/2018 1010 1,2-Dichlorobenzene 50 52 1 104 70-130 12/21/2018 1010 1,3-Dichlorobenzene 50 55 1 109 70-130 12/21/2018 1010 1,4-Dichlorobenzene 50 52 1 104 70-130 12/21/2018 1010 Dichlorodifluoromethane 50 45 1 89 60-140 12/21/2018 1010 1,1-Dichloroethane 50 47 1 94 70-130 12/21/2018 1010 1,2-Dichloroethane 50 48 1 96 70-130 12/21/2018 1010 1,1-Dichloroethene 50 46 1 92 70-130 12/21/2018 1010 cis- 1,2-Dichloroethene 50 51 1 101 70-130 12/21/2018 1010 trans- 1,2-Dichloroethene 50 47 1 95 70-130 12/21/2018 1010 1,2-Dichloropropane 50 44 1 88 70-130 12/21/2018 1010 cis- 1,3-Dichloropropene 50 46 1 92 70-130 12/21/2018 1010 trans- 1,3-Dichloropropene 50 45 1 90 70-130 12/21/2018 1010 Ethylbenzene 50 51 1 102 70-130 12/21/2018 1010 2-Hexanone 100 100 1 101 70-130 12/21/2018 1010 Isopropylbenzene 50 50 1 99 70-130 12/21/2018 1010 Methyl acetate 50 48 1 96 70-130 12/21/2018 1010 Methyl tertiary butyl ether (MTBE) 50 48 1 97 70-130 12/21/2018 1010 4-Methyl-2-pentanone 100 110 1 106 70-130 12/21/2018 1010 Methylcyclohexane 50 52 1 103 70-130 12/21/2018 1010 Methylene chloride 50 43 1 86 70-130 12/21/2018 1010 Styrene 50 53 1 107 70-130 12/21/2018 1010 1,1,2,2-Tetrachloroethane 50 55 1 111 70-130 12/21/2018 1010 Tetrachloroethene 50 53 1 106 70-130 12/21/2018 1010 Toluene 50 52 1 105 70-130 12/21/2018 1010 1,1,2-Trichloro-1,2,2-Trifluoroethane 50 49 1 97 70-130 12/21/2018 1010 1,2,4-Trichlorobenzene 50 48 1 95 70-130 12/21/2018 1010 1,1,1-Trichloroethane 50 44 1 89 70-130 12/21/2018 1010 1,1,2-Trichloroethane 50 53 1 105 70-130 12/21/2018 1010 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 10 of 15 Volatile Organic Compounds by GC/MS - LCS Sample ID: TQ93108-002 Matrix: Aqueous Batch: 93108 Prep Method: 5030E Analytical Method: 8260B Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Trichloroethene 50 51 1 102 70-130 12/21/2018 1010 Trichlorofluoromethane 50 42 1 85 70-130 12/21/2018 1010 Vinyl chloride 50 43 1 86 70-130 12/21/2018 1010 Xylenes (total) 100 100 1 104 70-130 12/21/2018 1010 Acceptance Surrogate Q % Rec Limit 1,2-Dichloroethane-d4 87 70-130 Bromofluorobenzene 98 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 11 of 15 Chain of Custody and Miscellaneous Documents Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 12 of 15 SHEALY ENVIRONMENTAL SERVICES, INC. a� CD M {1 N •v L Y + cd V_ I qq m IW 3 05 Z z_ 0a M =Q U) MEOW 5 4. ea C _- ---O Z pn E LU z C1 1 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 13 of 15 SHEALY ENVIRONMENTAL SERVICES, INC. co F RS..f J 1 I • waf+ 7) TVs I� V � U Q s n a R � i I I i I x CI c } 4'F Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 14 of 15 SHEALY ENVIRONMENTAL SERVICES, INC. $h*yBn%jrGmnrmtal Ser fW , Jns. r 1 of T3nmmefAAmbx ffFfA1�U]-0 Fn"rly� mC' 6 4']9 i ► "I le receipt Checklist (SRC'} client log � ri I' o6120 T 1, ecied rim: -Tc 2 " Ily-11 Lot #, T-LO r��47,z- e eipl: LSI 0 Client ❑ l+P C7 F*JF ❑ Other a I. V4�ere Gugtrtd seals pmimt on the Cooler°2, if custad seals were sent were the intact and unbmken7 D: � 7i ChIVinc Stri n}P '�'csred by_�Ig ratme opcin rccei}n J,Derivcd (Corrected) temper,a%lm upn receipf; °7 "ldp1�Apinsttowns ]R Gun 1D- lO IR [Ttm C,ar,recri4:j fa�tur Vec-iod of coolant; — S ,a L!t Tup ❑ ICe Pricks ❑ TJr )ce 0 Noym Na we 1 T if Icr: Nrature ofany C001cr exceeded 6,0°C, wasFrojcct ManagerNotifeP ❑ Yt, A PM WaS N01itied by, phone/ em ail ! face-tc fxe (v —cie one). Y ❑ 0 4, L the mmrnr-,x,ial courier's NCking slip Atmched to LT-ki-, form? OT'a rl No S. �trc pdti+Fcr cnsmcly pruceslurex (relinquishttL�e�ived} fvllawed? 2--Gs 1'lo b. R'ere n mple Ms (islcd on the C OC7 es ❑ No 7- Wc.� earn le Ms listed oti all sample containers? es ❑ Na 9. Was Colleelinn date & time listed an Iho C UC? To % Wn collmdon date & time ijmtrd on all Sample c mmhl er5? 5 Y M El No 11). Nd all c�ontq mr- label i00=2irion (Id, date, tinne) agr,ce with Ih C'[ as, ❑ No li. Wcre tuts to be performed listed ott the COC? es� 12. Did all sainplex strive in tbepjLpCr C0JVAj0ers for eavh trst arxV-or In good condition (1mbnken, lids on, etc.)? ' 13. WEE adb:llla a Saixlplu volume available? Na 14, Were all saro.PleS rer ivcd Williin',i tho holding 621C or 4$ boors, w1riC6wYrr comes frst . v- 15. Were any xarnPlas cons filers missing!CXC<S3 (Cir-]C one) simples Not li9t;d on curl_ 7 :. If` por VOA and RSA-T75 Mmplw, were bubbles pr"ent'r i-size" ('.."Or6truu iu cli�iric any of the VO-A vials? h 6 MBA IT W— all DRa3 natalsruusicnt sam l" recdeived at a pH of <2,? K0 A 19, V1Wese all cyan idc rauoales re ivd at a A- l2 and if d ❑ Yesl CI Nuj R A P 1. i esampIG5receIveilatapi, .>9 TKNIcyani&l una f;2� (<0.5M—W- _ sample%l`tee o rastduul 'es .� Nu. - Were cl ml rcmark%tequesn (i.e. roquested dilutions, MS+M D desi ,Tdoi7s, > 9.11 - con-xtly Iran.�Ibed from the C )C into the ea IMent section in L€KIS� ❑ Yes o 21, Was the Sluow number lixW on the ountainaf label? If yes, O v # Sample Fr4'oersatinn (Mast be wmpletcd for any samples} i31Wnectly pro%Tved or with headspaoe-) RHmplew — were received iacpirectly presen sd and wm. adjusted accordij TEL n sample rct i��v,�th mL' of Circlo mire;'USC14, j'NO3. BC1 N110F1 us ing SR # Tune of preser4 afidTt _ If m ore than ooc preservapvc is net:dc 1, please mate hi the carnmerus belur y. Sarapla{s}— _were ixcciverl wish bubble~; �6 mm in diametef', 5utnpl�s(s) were mk,,ivod vo th TRC ;�- 0.5 m g1I-(lr'#19 is rrn) and were adjusted aocordiF41y in satnNe r"iuing with mWillit tlliosul fMtc (NaA0j) with Shealy 1I?: — barcodt, labels appliod by- cwmneyrs; Dntc; I r-, in Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 15 of 15 es� 12. Did all sainplex strive in tbepjLpCr C0JVAj0ers for eavh trst arxV-or In good condition (1mbnken, lids on, etc.)? ' 13. WEE adb:llla a Saixlplu volume available? Na 14, Were all saro.PleS rer ivcd Williin',i tho holding 621C or 4$ boors, w1riC6wYrr comes frst . v- 15. Were any xarnPlas cons filers missing!CXC<S3 (Cir-]C one) simples Not li9t;d on curl_ 7 :. If` por VOA and RSA-T75 Mmplw, were bubbles pr"ent'r i-size" ('.."Or6truu iu cli�iric any of the VO-A vials? h 6 MBA IT W— all DRa3 natalsruusicnt sam l" recdeived at a pH of <2,? K0 A 19, V1Wese all cyan idc rauoales re ivd at a A- l2 and if d ❑ Yesl CI Nuj R A P 1. i esampIG5receIveilatapi, .>9 TKNIcyani&l una f;2� (<0.5M—W- _ sample%l`tee o rastduul 'es .� Nu. - Were cl ml rcmark%tequesn (i.e. roquested dilutions, MS+M D desi ,Tdoi7s, > 9.11 - con-xtly Iran.�Ibed from the C )C into the ea IMent section in L€KIS� ❑ Yes o 21, Was the Sluow number lixW on the ountainaf label? If yes, O v # Sample Fr4'oersatinn (Mast be wmpletcd for any samples} i31Wnectly pro%Tved or with headspaoe-) RHmplew — were received iacpirectly presen sd and wm. adjusted accordij TEL n sample rct i��v,�th mL' of Circlo mire;'USC14, j'NO3. BC1 N110F1 us ing SR # Tune of preser4 afidTt _ If m ore than ooc preservapvc is net:dc 1, please mate hi the carnmerus belur y. Sarapla{s}— _were ixcciverl wish bubble~; �6 mm in diametef', 5utnpl�s(s) were mk,,ivod vo th TRC ;�- 0.5 m g1I-(lr'#19 is rrn) and were adjusted aocordiF41y in satnNe r"iuing with mWillit tlliosul fMtc (NaA0j) with Shealy 1I?: — barcodt, labels appliod by- cwmneyrs; Dntc; I r-, in Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 15 of 15 SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Mid -Atlantic Associates, Inc. Lot Number: TL18048 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPS or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Volatiles The matrix spike (MS) associated with sample -003 had methyl acetate recovered outside of the acceptance limits. Additionally, the RPD exceeded the acceptance limit. The laboratory control sample (LCS) was recovered within the required acceptance limits; therefore, this likely demonstrates a matrix effect. Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 2 of 40 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Mid -Atlantic Associates, Inc. Lot Number: TL18048 Sample Number Sample ID Matrix Date Sampled Date Received 001 TW-1 Aqueous 12/17/20181340 12/18/2018 002 TW-2 Aqueous 12/17/20181400 12/18/2018 003 TW-3 Aqueous 12/17/20181410 12/18/2018 004 TW-4 Aqueous 12/17/20181420 12/18/2018 005 MW-2 Aqueous 12/17/20181350 12/18/2018 (5 samples) Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 3 of 40 SHEALY ENVIRONMENTAL SERVICES, INC. Detection Summary Mid -Atlantic Associates, Inc. Lot Number: TL18048 Sample Sample ID Matrix Parameter Method Result Q Units Page 003 TW-3 Aqueous Benzene 8260B 61 ug/L 11 003 TW-3 Aqueous Cyclohexane 8260B 430 ug/L 11 003 TW-3 Aqueous Ethylbenzene 8260B 360 ug/L 11 003 TW-3 Aqueous Isopropylbenzene 8260B 120 ug/L 11 003 TW-3 Aqueous Methylcyclohexane 8260B 500 ug/L 11 003 TW-3 Aqueous Methylene chloride 8260B 13 ug/L 11 003 TW-3 Aqueous Toluene 8260B 21 ug/L 11 003 TW-3 Aqueous Xylenes (total) 8260B 430 ug/L 12 003 TW-3 Aqueous 1-Methylnaphthalene 8270D 7.2 ug/L 13 003 TW-3 Aqueous 2-Methylnaphthalene 8270D 10 ug/L 13 003 TW-3 Aqueous Naphthalene 8270D 54 ug/L 13 (11 detections) Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 4 of 40 Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID:TL18048-001 Description: TW-1 Matrix: Aqueous Date Sampled:12/17/2018 1340 Date Received:12/18/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 12/27/2018 0043 KGT 93379 CAS Analytical Parameter Number Method Result Q LOQ Units Run Acetone 67-64-1 8260B ND 20 ug/L 1 Benzene 71-43-2 8260B ND 1.0 ug/L 1 Bromodichloromethane 75-27-4 8260B ND 1.0 ug/L 1 Bromoform 75-25-2 8260B ND 1.0 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260B ND 2.0 ug/L 1 2-Butanone (MEK) 78-93-3 8260B ND 10 ug/L 1 Carbon disulfide 75-15-0 8260B ND 1.0 ug/L 1 Carbon tetrachloride 56-23-5 8260B ND 1.0 ug/L 1 Chlorobenzene 108-90-7 8260B ND 1.0 ug/L 1 Chloroethane 75-00-3 8260B ND 2.0 ug/L 1 Chloroform 67-66-3 8260B ND 1.0 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260B ND 1.0 ug/L 1 Cyclohexane 110-82-7 8260B ND 1.0 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260B ND 1.0 ug/L 1 Dibromochloromethane 124-48-1 8260B ND 1.0 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260B ND 1.0 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260B ND 1.0 ug/L 1 1,3-Dichlorobenzene 541-73-1 8260B ND 1.0 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260B ND 1.0 ug/L 1 Dichlorodifluoromethane 75-71-8 8260B ND 2.0 ug/L 1 1,1-Dichloroethane 75-34-3 8260B ND 1.0 ug/L 1 1,2-Dichloroethane 107-06-2 8260B ND 1.0 ug/L 1 1,1-Dichloroethene 75-35-4 8260B ND 1.0 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260B ND 1.0 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260B ND 1.0 ug/L 1 1,2-Dichloropropane 78-87-5 8260B ND 1.0 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260B ND 1.0 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260B ND 1.0 ug/L 1 Ethylbenzene 100-41-4 8260B ND 1.0 ug/L 1 2-Hexanone 591-78-6 8260B ND 10 ug/L 1 Isopropylbenzene 98-82-8 8260B ND 1.0 ug/L 1 Methyl acetate 79-20-9 8260B ND 1.0 ug/L 1 Methyl tertiary butyl ether (MTBE) 1634-04-4 8260B ND 1.0 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260B ND 10 ug/L 1 Methylcyclohexane 108-87-2 8260B ND 5.0 ug/L 1 Methylene chloride 75-09-2 8260B ND 1.0 ug/L 1 Styrene 100-42-5 8260B ND 1.0 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1.0 ug/L 1 Tetrachloroethene 127-18-4 8260B ND 1.0 ug/L 1 Toluene 108-88-3 8260B ND 1.0 ug/L 1 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 8260B ND 1.0 ug/L 1 1,2,4-Trichlorobenzene 120-82-1 8260B ND 1.0 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260B ND 1.0 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260B ND 1.0 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 5 of 40 Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID:TL18048-001 Description: TW-1 Matrix: Aqueous Date Sampled:12/17/2018 1340 Date Received:12/18/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 12/27/2018 0043 KGT 93379 CAS Analytical Parameter Number Method Result Q LOQ Units Run Trichloroethene 79-01-6 8260B ND 1.0 ug/L 1 Trichlorofluoromethane 75-69-4 8260B ND 1.0 ug/L 1 Vinyl chloride 75-01-4 8260B ND 1.0 ug/L 1 Xylenes (total) 1330-20-7 8260B ND 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 70-130 Bromofluorobenzene 109 70-130 Toluene-d8 103 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 6 of 40 Semivolatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID:TL18048-001 Description: TW-1 Matrix: Aqueous Date Sampled:12/17/2018 1340 Date Received:12/18/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8270D 1 12/23/2018 1253 CMP2 12/21/2018 1643 93115 CAS Analytical Parameter Number Method Result Q LOQ Units Run Acenaphthene 83-32-9 8270D ND 0.80 ug/L 1 Acenaphthylene 208-96-8 8270D ND 0.80 ug/L 1 Anthracene 120-12-7 8270D ND 0.80 ug/L 1 Benzo(a)anthracene 56-55-3 8270D ND 0.80 ug/L 1 Benzo(a)pyrene 50-32-8 8270D ND 0.80 ug/L 1 Benzo(b)fluoranthene 205-99-2 8270D ND 0.80 ug/L 1 Benzo(g,h,i)perylene 191-24-2 8270D ND 0.80 ug/L 1 Benzo(k)fluoranthene 207-08-9 8270D ND 0.80 ug/L 1 Chrysene 218-01-9 8270D ND 0.80 ug/L 1 Dibenzo(a,h)anthracene 53-70-3 8270D ND 0.80 ug/L 1 Fluoranthene 206-44-0 8270D ND 0.80 ug/L 1 Fluorene 86-73-7 8270D ND 0.80 ug/L 1 Indeno(1,2,3-c,d)pyrene 193-39-5 8270D ND 0.80 ug/L 1 1-Methylnaphthalene 90-12-0 8270D ND 0.80 ug/L 1 2-Methylnaphthalene 91-57-6 8270D ND 0.80 ug/L 1 Naphthalene 91-20-3 8270D ND 0.80 ug/L 1 Phenanthrene 85-01-8 8270D ND 0.80 ug/L 1 Pyrene 129-00-0 8270D ND 0.80 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Nitrobenzene-d5 84 38-127 2-Fluorobiphenyl 61 37-129 Terphenyl-d14 107 10-148 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 7 of 40 Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID:TL18048-002 Description: TW-2 Matrix: Aqueous Date Sampled:12/17/2018 1400 Date Received:12/18/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 12/27/2018 0106 KGT 93379 CAS Analytical Parameter Number Method Result Q LOQ Units Run Acetone 67-64-1 8260B ND 20 ug/L 1 Benzene 71-43-2 8260B ND 1.0 ug/L 1 Bromodichloromethane 75-27-4 8260B ND 1.0 ug/L 1 Bromoform 75-25-2 8260B ND 1.0 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260B ND 2.0 ug/L 1 2-Butanone (MEK) 78-93-3 8260B ND 10 ug/L 1 Carbon disulfide 75-15-0 8260B ND 1.0 ug/L 1 Carbon tetrachloride 56-23-5 8260B ND 1.0 ug/L 1 Chlorobenzene 108-90-7 8260B ND 1.0 ug/L 1 Chloroethane 75-00-3 8260B ND 2.0 ug/L 1 Chloroform 67-66-3 8260B ND 1.0 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260B ND 1.0 ug/L 1 Cyclohexane 110-82-7 8260B ND 1.0 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260B ND 1.0 ug/L 1 Dibromochloromethane 124-48-1 8260B ND 1.0 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260B ND 1.0 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260B ND 1.0 ug/L 1 1,3-Dichlorobenzene 541-73-1 8260B ND 1.0 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260B ND 1.0 ug/L 1 Dichlorodifluoromethane 75-71-8 8260B ND 2.0 ug/L 1 1,1-Dichloroethane 75-34-3 8260B ND 1.0 ug/L 1 1,2-Dichloroethane 107-06-2 8260B ND 1.0 ug/L 1 1,1-Dichloroethene 75-35-4 8260B ND 1.0 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260B ND 1.0 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260B ND 1.0 ug/L 1 1,2-Dichloropropane 78-87-5 8260B ND 1.0 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260B ND 1.0 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260B ND 1.0 ug/L 1 Ethylbenzene 100-41-4 8260B ND 1.0 ug/L 1 2-Hexanone 591-78-6 8260B ND 10 ug/L 1 Isopropylbenzene 98-82-8 8260B ND 1.0 ug/L 1 Methyl acetate 79-20-9 8260B ND 1.0 ug/L 1 Methyl tertiary butyl ether (MTBE) 1634-04-4 8260B ND 1.0 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260B ND 10 ug/L 1 Methylcyclohexane 108-87-2 8260B ND 5.0 ug/L 1 Methylene chloride 75-09-2 8260B ND 1.0 ug/L 1 Styrene 100-42-5 8260B ND 1.0 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1.0 ug/L 1 Tetrachloroethene 127-18-4 8260B ND 1.0 ug/L 1 Toluene 108-88-3 8260B ND 1.0 ug/L 1 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 8260B ND 1.0 ug/L 1 1,2,4-Trichlorobenzene 120-82-1 8260B ND 1.0 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260B ND 1.0 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260B ND 1.0 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 8 of 40 Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID:TL18048-002 Description: TW-2 Matrix: Aqueous Date Sampled:12/17/2018 1400 Date Received:12/18/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 12/27/2018 0106 KGT 93379 CAS Analytical Parameter Number Method Result Q LOQ Units Run Trichloroethene 79-01-6 8260B ND 1.0 ug/L 1 Trichlorofluoromethane 75-69-4 8260B ND 1.0 ug/L 1 Vinyl chloride 75-01-4 8260B ND 1.0 ug/L 1 Xylenes (total) 1330-20-7 8260B ND 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 91 70-130 Bromofluorobenzene 102 70-130 Toluene-d8 98 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 9 of 40 Semivolatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID:TL18048-002 Description: TW-2 Matrix: Aqueous Date Sampled:12/17/2018 1400 Date Received:12/18/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8270D 1 12/23/2018 1317 CMP2 12/21/2018 1643 93115 CAS Analytical Parameter Number Method Result Q LOQ Units Run Acenaphthene 83-32-9 8270D ND 0.80 ug/L 1 Acenaphthylene 208-96-8 8270D ND 0.80 ug/L 1 Anthracene 120-12-7 8270D ND 0.80 ug/L 1 Benzo(a)anthracene 56-55-3 8270D ND 0.80 ug/L 1 Benzo(a)pyrene 50-32-8 8270D ND 0.80 ug/L 1 Benzo(b)fluoranthene 205-99-2 8270D ND 0.80 ug/L 1 Benzo(g,h,i)perylene 191-24-2 8270D ND 0.80 ug/L 1 Benzo(k)fluoranthene 207-08-9 8270D ND 0.80 ug/L 1 Chrysene 218-01-9 8270D ND 0.80 ug/L 1 Dibenzo(a,h)anthracene 53-70-3 8270D ND 0.80 ug/L 1 Fluoranthene 206-44-0 8270D ND 0.80 ug/L 1 Fluorene 86-73-7 8270D ND 0.80 ug/L 1 Indeno(1,2,3-c,d)pyrene 193-39-5 8270D ND 0.80 ug/L 1 1-Methylnaphthalene 90-12-0 8270D ND 0.80 ug/L 1 2-Methylnaphthalene 91-57-6 8270D ND 0.80 ug/L 1 Naphthalene 91-20-3 8270D ND 0.80 ug/L 1 Phenanthrene 85-01-8 8270D ND 0.80 ug/L 1 Pyrene 129-00-0 8270D ND 0.80 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Nitrobenzene-d5 84 38-127 2-Fluorobiphenyl 63 37-129 Terphenyl-d14 111 10-148 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 10 of 40 Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID:TL18048-003 Description: TW-3 Matrix: Aqueous Date Sampled:12/17/2018 1410 Date Received:12/18/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260B 10 12/29/2018 0039 KGT 93619 CAS Analytical Parameter Number Method Result Q LOQ Units Run Acetone 67-64-1 8260B ND 200 ug/L 2 Benzene 71-43-2 8260B 61 10 ug/L 2 Bromodichloromethane 75-27-4 8260B ND 10 ug/L 2 Bromoform 75-25-2 8260B ND 10 ug/L 2 Bromomethane (Methyl bromide) 74-83-9 8260B ND 20 ug/L 2 2-Butanone (MEK) 78-93-3 8260B ND 100 ug/L 2 Carbon disulfide 75-15-0 8260B ND 10 ug/L 2 Carbon tetrachloride 56-23-5 8260B ND 10 ug/L 2 Chlorobenzene 108-90-7 8260B ND 10 ug/L 2 Chloroethane 75-00-3 8260B ND 20 ug/L 2 Chloroform 67-66-3 8260B ND 10 ug/L 2 Chloromethane (Methyl chloride) 74-87-3 8260B ND 10 ug/L 2 Cyclohexane 110-82-7 8260B 430 10 ug/L 2 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260B ND 10 ug/L 2 Dibromochloromethane 124-48-1 8260B ND 10 ug/L 2 1,2-Dibromoethane (EDB) 106-93-4 8260B ND 10 ug/L 2 1,2-Dichlorobenzene 95-50-1 8260B ND 10 ug/L 2 1,3-Dichlorobenzene 541-73-1 8260B ND 10 ug/L 2 1,4-Dichlorobenzene 106-46-7 8260B ND 10 ug/L 2 Dichlorodifluoromethane 75-71-8 8260B ND 20 ug/L 2 1,1-Dichloroethane 75-34-3 8260B ND 10 ug/L 2 1,2-Dichloroethane 107-06-2 8260B ND 10 ug/L 2 1,1-Dichloroethene 75-35-4 8260B ND 10 ug/L 2 cis- 1,2-Dichloroethene 156-59-2 8260B ND 10 ug/L 2 trans-1,2-Dichloroethene 156-60-5 8260B ND 10 ug/L 2 1,2-Dichloropropane 78-87-5 8260B ND 10 ug/L 2 cis- 1,3-Dichloropropene 10061-01-5 8260B ND 10 ug/L 2 trans- 1,3-Dichloropropene 10061-02-6 8260B ND 10 ug/L 2 Ethylbenzene 100-41-4 8260B 360 10 ug/L 2 2-Hexanone 591-78-6 8260B ND 100 ug/L 2 Isopropylbenzene 98-82-8 8260B 120 10 ug/L 2 Methyl acetate 79-20-9 8260B ND 10 ug/L 2 Methyl tertiary butyl ether (MTBE) 1634-04-4 8260B ND 10 ug/L 2 4-Methyl-2-pentanone 108-10-1 8260B ND 100 ug/L 2 Methylcyclohexane 108-87-2 8260B 500 50 ug/L 2 Methylene chloride 75-09-2 8260B 13 10 ug/L 2 Styrene 100-42-5 8260B ND 10 ug/L 2 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 10 ug/L 2 Tetrachloroethene 127-18-4 8260B ND 10 ug/L 2 Toluene 108-88-3 8260B 21 10 ug/L 2 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 8260B ND 10 ug/L 2 1,2,4-Trichlorobenzene 120-82-1 8260B ND 10 ug/L 2 1,1,1-Trichloroethane 71-55-6 8260B ND 10 ug/L 2 1,1,2-Trichloroethane 79-00-5 8260B ND 10 ug/L 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 11 of 40 Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID:TL18048-003 Description: TW-3 Matrix: Aqueous Date Sampled:12/17/2018 1410 Date Received:12/18/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260B 10 12/29/2018 0039 KGT 93619 CAS Analytical Parameter Number Method Result Q LOQ Units Run Trichloroethene 79-01-6 8260B ND 10 ug/L 2 Trichlorofluoromethane 75-69-4 8260B ND 10 ug/L 2 Vinyl chloride 75-01-4 8260B ND 10 ug/L 2 Xylenes (total) 1330-20-7 8260B 430 10 ug/L 2 Run 2 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 70-130 Bromofluorobenzene 106 70-130 Toluene-d8 104 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 12 of 40 Semivolatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID:TL18048-003 Description: TW-3 Matrix: Aqueous Date Sampled:12/17/2018 1410 Date Received:12/18/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8270D 1 12/23/2018 1341 CMP2 12/21/2018 1643 93115 CAS Analytical Parameter Number Method Result Q LOQ Units Run Acenaphthene 83-32-9 8270D ND 0.80 ug/L 1 Acenaphthylene 208-96-8 8270D ND 0.80 ug/L 1 Anthracene 120-12-7 8270D ND 0.80 ug/L 1 Benzo(a)anthracene 56-55-3 8270D ND 0.80 ug/L 1 Benzo(a)pyrene 50-32-8 8270D ND 0.80 ug/L 1 Benzo(b)fluoranthene 205-99-2 8270D ND 0.80 ug/L 1 Benzo(g,h,i)perylene 191-24-2 8270D ND 0.80 ug/L 1 Benzo(k)fluoranthene 207-08-9 8270D ND 0.80 ug/L 1 Chrysene 218-01-9 8270D ND 0.80 ug/L 1 Dibenzo(a,h)anthracene 53-70-3 8270D ND 0.80 ug/L 1 Fluoranthene 206-44-0 8270D ND 0.80 ug/L 1 Fluorene 86-73-7 8270D ND 0.80 ug/L 1 Indeno(1,2,3-c,d)pyrene 193-39-5 8270D ND 0.80 ug/L 1 1-Methylnaphthalene 90-12-0 8270D 7.2 0.80 ug/L 1 2-Methylnaphthalene 91-57-6 8270D 10 0.80 ug/L 1 Naphthalene 91-20-3 8270D 54 0.80 ug/L 1 Phenanthrene 85-01-8 8270D ND 0.80 ug/L 1 Pyrene 129-00-0 8270D ND 0.80 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Nitrobenzene-d5 79 38-127 2-Fluorobiphenyl 58 37-129 Terphenyl-d14 102 10-148 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 13 of 40 Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID:TL18048-004 Description: TW-4 Matrix: Aqueous Date Sampled:12/17/2018 1420 Date Received:12/18/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 12/27/2018 0129 KGT 93379 CAS Analytical Parameter Number Method Result Q LOQ Units Run Acetone 67-64-1 8260B ND 20 ug/L 1 Benzene 71-43-2 8260B ND 1.0 ug/L 1 Bromodichloromethane 75-27-4 8260B ND 1.0 ug/L 1 Bromoform 75-25-2 8260B ND 1.0 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260B ND 2.0 ug/L 1 2-Butanone (MEK) 78-93-3 8260B ND 10 ug/L 1 Carbon disulfide 75-15-0 8260B ND 1.0 ug/L 1 Carbon tetrachloride 56-23-5 8260B ND 1.0 ug/L 1 Chlorobenzene 108-90-7 8260B ND 1.0 ug/L 1 Chloroethane 75-00-3 8260B ND 2.0 ug/L 1 Chloroform 67-66-3 8260B ND 1.0 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260B ND 1.0 ug/L 1 Cyclohexane 110-82-7 8260B ND 1.0 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260B ND 1.0 ug/L 1 Dibromochloromethane 124-48-1 8260B ND 1.0 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260B ND 1.0 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260B ND 1.0 ug/L 1 1,3-Dichlorobenzene 541-73-1 8260B ND 1.0 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260B ND 1.0 ug/L 1 Dichlorodifluoromethane 75-71-8 8260B ND 2.0 ug/L 1 1,1-Dichloroethane 75-34-3 8260B ND 1.0 ug/L 1 1,2-Dichloroethane 107-06-2 8260B ND 1.0 ug/L 1 1,1-Dichloroethene 75-35-4 8260B ND 1.0 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260B ND 1.0 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260B ND 1.0 ug/L 1 1,2-Dichloropropane 78-87-5 8260B ND 1.0 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260B ND 1.0 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260B ND 1.0 ug/L 1 Ethylbenzene 100-41-4 8260B ND 1.0 ug/L 1 2-Hexanone 591-78-6 8260B ND 10 ug/L 1 Isopropylbenzene 98-82-8 8260B ND 1.0 ug/L 1 Methyl acetate 79-20-9 8260B ND 1.0 ug/L 1 Methyl tertiary butyl ether (MTBE) 1634-04-4 8260B ND 1.0 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260B ND 10 ug/L 1 Methylcyclohexane 108-87-2 8260B ND 5.0 ug/L 1 Methylene chloride 75-09-2 8260B ND 1.0 ug/L 1 Styrene 100-42-5 8260B ND 1.0 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1.0 ug/L 1 Tetrachloroethene 127-18-4 8260B ND 1.0 ug/L 1 Toluene 108-88-3 8260B ND 1.0 ug/L 1 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 8260B ND 1.0 ug/L 1 1,2,4-Trichlorobenzene 120-82-1 8260B ND 1.0 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260B ND 1.0 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260B ND 1.0 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 14 of 40 Volatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID:TL18048-004 Description: TW-4 Matrix: Aqueous Date Sampled:12/17/2018 1420 Date Received:12/18/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 12/27/2018 0129 KGT 93379 CAS Analytical Parameter Number Method Result Q LOQ Units Run Trichloroethene 79-01-6 8260B ND 1.0 ug/L 1 Trichlorofluoromethane 75-69-4 8260B ND 1.0 ug/L 1 Vinyl chloride 75-01-4 8260B ND 1.0 ug/L 1 Xylenes (total) 1330-20-7 8260B ND 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 70-130 Bromofluorobenzene 104 70-130 Toluene-d8 99 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 15 of 40 Semivolatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID:TL18048-004 Description: TW-4 Matrix: Aqueous Date Sampled:12/17/2018 1420 Date Received:12/18/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8270D 1 12/23/2018 1405 CMP2 12/21/2018 1643 93115 CAS Analytical Parameter Number Method Result Q LOQ Units Run Acenaphthene 83-32-9 8270D ND 0.80 ug/L 1 Acenaphthylene 208-96-8 8270D ND 0.80 ug/L 1 Anthracene 120-12-7 8270D ND 0.80 ug/L 1 Benzo(a)anthracene 56-55-3 8270D ND 0.80 ug/L 1 Benzo(a)pyrene 50-32-8 8270D ND 0.80 ug/L 1 Benzo(b)fluoranthene 205-99-2 8270D ND 0.80 ug/L 1 Benzo(g,h,i)perylene 191-24-2 8270D ND 0.80 ug/L 1 Benzo(k)fluoranthene 207-08-9 8270D ND 0.80 ug/L 1 Chrysene 218-01-9 8270D ND 0.80 ug/L 1 Dibenzo(a,h)anthracene 53-70-3 8270D ND 0.80 ug/L 1 Fluoranthene 206-44-0 8270D ND 0.80 ug/L 1 Fluorene 86-73-7 8270D ND 0.80 ug/L 1 Indeno(1,2,3-c,d)pyrene 193-39-5 8270D ND 0.80 ug/L 1 1-Methylnaphthalene 90-12-0 8270D ND 0.80 ug/L 1 2-Methylnaphthalene 91-57-6 8270D ND 0.80 ug/L 1 Naphthalene 91-20-3 8270D ND 0.80 ug/L 1 Phenanthrene 85-01-8 8270D ND 0.80 ug/L 1 Pyrene 129-00-0 8270D ND 0.80 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Nitrobenzene-d5 88 38-127 2-Fluorobiphenyl 72 37-129 Terphenyl-d14 104 10-148 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 16 of 40 Semivolatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID:TL18048-005 Description: MW-2 Matrix: Aqueous Date Sampled:12/17/2018 1350 Date Received:12/18/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8270D 1 12/23/2018 1429 CMP2 12/21/2018 1643 93116 CAS Analytical Parameter Number Method Result Q LOQ Units Run 1,1'-Biphenyl 92-52-4 8270D ND 4.0 ug/L 1 2,4,5-Trichlorophenol 95-95-4 8270D ND 4.0 ug/L 1 2,4,6-Trichlorophenol 88-06-2 8270D ND 4.0 ug/L 1 2,4-Dichlorophenol 120-83-2 8270D ND 8.0 ug/L 1 2,4-Dimethylphenol 105-67-9 8270D ND 4.0 ug/L 1 2,4-Dinitrophenol 51-28-5 8270D ND 20 ug/L 1 2,4-Dinitrotoluene 121-14-2 8270D ND 8.0 ug/L 1 2,6-Dinitrotoluene 606-20-2 8270D ND 8.0 ug/L 1 2-Chloronaphthalene 91-58-7 8270D ND 4.0 ug/L 1 2-Chlorophenol 95-57-8 8270D ND 4.0 ug/L 1 2-Methylnaphthalene 91-57-6 8270D ND 0.80 ug/L 1 2-Methylphenol 95-48-7 8270D ND 4.0 ug/L 1 2-Nitroaniline 88-74-4 8270D ND 8.0 ug/L 1 2-Nitrophenol 88-75-5 8270D ND 4.0 ug/L 1 3,3'-Dichlorobenzidine 91-94-1 8270D ND 4.0 ug/L 1 3+4-Methylphenol 106-44-5 8270D ND 4.0 ug/L 1 3-Nitroaniline 99-09-2 8270D ND 8.0 ug/L 1 4,6-Dinitro-2-methylphenol 534-52-1 8270D ND 20 ug/L 1 4-Bromophenyl phenyl ether 101-55-3 8270D ND 4.0 ug/L 1 4-Chloro-3-methyl phenol 59-50-7 8270D ND 4.0 ug/L 1 4-Chloroaniline 106-47-8 8270D ND 8.0 ug/L 1 4-Chlorophenyl phenyl ether 7005-72-3 8270D ND 4.0 ug/L 1 4-Nitroaniline 100-01-6 8270D ND 8.0 ug/L 1 4-Nitrophenol 100-02-7 8270D ND 20 ug/L 1 Acenaphthene 83-32-9 8270D ND 0.80 ug/L 1 Acenaphthylene 208-96-8 8270D ND 0.80 ug/L 1 Acetophenone 98-86-2 8270D ND 4.0 ug/L 1 Anthracene 120-12-7 8270D ND 0.80 ug/L 1 Atrazine 1912-24-9 8270D ND 4.0 ug/L 1 Benzaldehyde 100-52-7 8270D ND 8.0 ug/L 1 Benzo(a)anthracene 56-55-3 8270D ND 0.80 ug/L 1 Benzo(a)pyrene 50-32-8 8270D ND 0.80 ug/L 1 Benzo(b)fluoranthene 205-99-2 8270D ND 0.80 ug/L 1 Benzo(g,h,i)perylene 191-24-2 8270D ND 0.80 ug/L 1 Benzo(k)fluoranthene 207-08-9 8270D ND 0.80 ug/L 1 bis (2-Chloro-1-methylethyl) ether 108-60-1 8270D ND 4.0 ug/L 1 bis(2-Chloroethoxy)methane 111-91-1 8270D ND 4.0 ug/L 1 bis(2-Chloroethyl)ether 111-44-4 8270D ND 4.0 ug/L 1 bis(2-Ethylhexyl)phthalate 117-81-7 8270D ND 4.0 ug/L 1 Butyl benzyl phthalate 85-68-7 8270D ND 4.0 ug/L 1 Caprolactam 105-60-2 8270D ND 8.0 ug/L 1 Carbazole 86-74-8 8270D ND 4.0 ug/L 1 Chrysene 218-01-9 8270D ND 0.80 ug/L 1 Dibenzo(a,h)anthracene 53-70-3 8270D ND 0.80 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 17 of 40 Semivolatile Organic Compounds by GC/MS Client: Mid -Atlantic Associates, Inc. Laboratory ID:TL18048-005 Description: MW-2 Matrix: Aqueous Date Sampled:12/17/2018 1350 Date Received:12/18/2018 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8270D 1 12/23/2018 1429 CMP2 12/21/2018 1643 93116 CAS Analytical Parameter Number Method Result Q LOQ Units Run Dibenzofuran 132-64-9 8270D ND 4.0 ug/L 1 Diethylphthalate 84-66-2 8270D ND 4.0 ug/L 1 Dimethyl phthalate 131-11-3 8270D ND 4.0 ug/L 1 Di-n-butyl phthalate 84-74-2 8270D ND 4.0 ug/L 1 Di-n-octylphthalate 117-84-0 8270D ND 4.0 ug/L 1 Fluoranthene 206-44-0 8270D ND 0.80 ug/L 1 Fluorene 86-73-7 8270D ND 0.80 ug/L 1 Hexachlorobenzene 118-74-1 8270D ND 4.0 ug/L 1 Hexachlorobutadiene 87-68-3 8270D ND 4.0 ug/L 1 Hexachlorocyclopentadiene 77-47-4 8270D ND 20 ug/L 1 Hexachloroethane 67-72-1 8270D ND 4.0 ug/L 1 Indeno(1,2,3-c,d)pyrene 193-39-5 8270D ND 0.80 ug/L 1 Isophorone 78-59-1 8270D ND 4.0 ug/L 1 Naphthalene 91-20-3 8270D ND 0.80 ug/L 1 Nitrobenzene 98-95-3 8270D ND 4.0 ug/L 1 N-Nitrosodi-n-propylamine 621-64-7 8270D ND 4.0 ug/L 1 N-Nitrosodiphenylamine (Diphenylamine) 86-30-6 8270D ND 4.0 ug/L 1 Pentachlorophenol 87-86-5 8270D ND 20 ug/L 1 Phenanthrene 85-01-8 8270D ND 0.80 ug/L 1 Phenol 108-95-2 8270D ND 4.0 ug/L 1 Pyrene 129-00-0 8270D ND 0.80 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 2-Fluorobiphenyl 75 37-129 2-Fluorophenol 53 24-127 Nitrobenzene-d5 101 38-127 Phenol-d5 74 28-128 Terphenyl-d14 103 10-148 2,4,6-Tribromophenol 87 35-144 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 18 of 40 QC Summary Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 19 of 40 Volatile Organic Compounds by GC/MS - MB Sample ID: TQ93379-001 Matrix: Aqueous Batch: 93379 Prep Method: 5030E Analytical Method: 8260B Parameter Result Q Dil LOQ Units Analysis Date Acetone ND 1 20 ug/L 12/26/2018 2236 Benzene ND 1 1.0 ug/L 12/26/2018 2236 Bromodichloromethane ND 1 1.0 ug/L 12/26/2018 2236 Bromoform ND 1 1.0 ug/L 12/26/2018 2236 Bromomethane (Methyl bromide) ND 1 2.0 ug/L 12/26/2018 2236 2-Butanone (MEK) ND 1 10 ug/L 12/26/2018 2236 Carbon disulfide ND 1 1.0 ug/L 12/26/2018 2236 Carbon tetrachloride ND 1 1.0 ug/L 12/26/2018 2236 Chlorobenzene ND 1 1.0 ug/L 12/26/2018 2236 Chloroethane ND 1 2.0 ug/L 12/26/2018 2236 Chloroform ND 1 1.0 ug/L 12/26/2018 2236 Chloromethane (Methyl chloride) ND 1 1.0 ug/L 12/26/2018 2236 Cyclohexane ND 1 1.0 ug/L 12/26/2018 2236 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 ug/L 12/26/2018 2236 Dibromochloromethane ND 1 1.0 ug/L 12/26/2018 2236 1,2-Dibromoethane (EDB) ND 1 1.0 ug/L 12/26/2018 2236 1,2-Dichlorobenzene ND 1 1.0 ug/L 12/26/2018 2236 1,3-Dichlorobenzene ND 1 1.0 ug/L 12/26/2018 2236 1,4-Dichlorobenzene ND 1 1.0 ug/L 12/26/2018 2236 Dichlorodifluoromethane ND 1 2.0 ug/L 12/26/2018 2236 1,1-Dichloroethane ND 1 1.0 ug/L 12/26/2018 2236 1,2-Dichloroethane ND 1 1.0 ug/L 12/26/2018 2236 1,1-Dichloroethene ND 1 1.0 ug/L 12/26/2018 2236 cis- 1,2-Dichloroethene ND 1 1.0 ug/L 12/26/2018 2236 trans- 1,2-Dichloroethene ND 1 1.0 ug/L 12/26/2018 2236 1,2-Dichloropropane ND 1 1.0 ug/L 12/26/2018 2236 cis- 1,3-Dichloropropene ND 1 1.0 ug/L 12/26/2018 2236 trans- 1,3-Dichloropropene ND 1 1.0 ug/L 12/26/2018 2236 Ethylbenzene ND 1 1.0 ug/L 12/26/2018 2236 2-Hexanone ND 1 10 ug/L 12/26/2018 2236 Isopropylbenzene ND 1 1.0 ug/L 12/26/2018 2236 Methyl acetate ND 1 1.0 ug/L 12/26/2018 2236 Methyl tertiary butyl ether (MTBE) ND 1 1.0 ug/L 12/26/2018 2236 4-Methyl-2-pentanone ND 1 10 ug/L 12/26/2018 2236 Methylcyclohexane ND 1 5.0 ug/L 12/26/2018 2236 Methylene chloride ND 1 1.0 ug/L 12/26/2018 2236 Styrene ND 1 1.0 ug/L 12/26/2018 2236 1,1,2,2-Tetrachloroethane ND 1 1.0 ug/L 12/26/2018 2236 Tetrachloroethene ND 1 1.0 ug/L 12/26/2018 2236 Toluene ND 1 1.0 ug/L 12/26/2018 2236 1,1,2-Trichloro-1,2,2-Trifluoroethane ND 1 1.0 ug/L 12/26/2018 2236 1,2,4-Trichlorobenzene ND 1 1.0 ug/L 12/26/2018 2236 1,1,1-Trichloroethane ND 1 1.0 ug/L 12/26/2018 2236 1,1,2-Trichloroethane ND 1 1.0 ug/L 12/26/2018 2236 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 20 of 40 Volatile Organic Compounds by GC/MS - MB Sample ID: TQ93379-001 Matrix: Aqueous Batch: 93379 Prep Method: 5030E Analytical Method: 8260B Parameter Result Q Dil LOQ Units Analysis Date Trichloroethene ND 1 1.0 ug/L 12/26/2018 2236 Trichlorofluoromethane ND 1 1.0 ug/L 12/26/2018 2236 Vinyl chloride ND 1 1.0 ug/L 12/26/2018 2236 Xylenes (total) ND 1 1.0 ug/L 12/26/2018 2236 Acceptance Surrogate Q % Rec Limit 1,2-Dichloroethane-d4 90 70-130 Bromofluorobenzene 93 70-130 Toluene-d8 95 70-130 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 21 of 40 Volatile Organic Compounds by GC/MS - LCS Sample ID: TQ93379-002 Matrix: Aqueous Batch: 93379 Prep Method: 5030E Analytical Method: 8260B Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 98 1 98 60-140 12/26/2018 2150 Benzene 50 49 1 98 70-130 12/26/2018 2150 Bromodichloromethane 50 48 1 97 70-130 12/26/2018 2150 Bromoform 50 47 1 93 70-130 12/26/2018 2150 Bromomethane (Methyl bromide) 50 54 1 108 70-130 12/26/2018 2150 2-Butanone (MEK) 100 99 1 99 70-130 12/26/2018 2150 Carbon disulfide 50 52 1 104 70-130 12/26/2018 2150 Carbon tetrachloride 50 49 1 97 70-130 12/26/2018 2150 Chlorobenzene 50 49 1 98 70-130 12/26/2018 2150 Chloroethane 50 54 1 108 70-130 12/26/2018 2150 Chloroform 50 47 1 94 70-130 12/26/2018 2150 Chloromethane (Methyl chloride) 50 52 1 103 60-140 12/26/2018 2150 Cyclohexane 50 49 1 99 70-130 12/26/2018 2150 1,2-Dibromo-3-chloropropane (DBCP) 50 48 1 95 70-130 12/26/2018 2150 Dibromochloromethane 50 51 1 102 70-130 12/26/2018 2150 1,2-Dibromoethane (EDB) 50 51 1 101 70-130 12/26/2018 2150 1,2-Dichlorobenzene 50 49 1 97 70-130 12/26/2018 2150 1,3-Dichlorobenzene 50 50 1 99 70-130 12/26/2018 2150 1,4-Dichlorobenzene 50 49 1 97 70-130 12/26/2018 2150 Dichlorodifluoromethane 50 56 1 112 60-140 12/26/2018 2150 1,1-Dichloroethane 50 49 1 98 70-130 12/26/2018 2150 1,2-Dichloroethane 50 48 1 96 70-130 12/26/2018 2150 1,1-Dichloroethene 50 50 1 100 70-130 12/26/2018 2150 cis- 1,2-Dichloroethene 50 50 1 99 70-130 12/26/2018 2150 trans- 1,2-Dichloroethene 50 50 1 100 70-130 12/26/2018 2150 1,2-Dichloropropane 50 44 1 88 70-130 12/26/2018 2150 cis- 1,3-Dichloropropene 50 45 1 90 70-130 12/26/2018 2150 trans- 1,3-Dichloropropene 50 45 1 89 70-130 12/26/2018 2150 Ethylbenzene 50 50 1 101 70-130 12/26/2018 2150 2-Hexanone 100 100 1 103 70-130 12/26/2018 2150 Isopropylbenzene 50 50 1 100 70-130 12/26/2018 2150 Methyl acetate 50 48 1 97 70-130 12/26/2018 2150 Methyl tertiary butyl ether (MTBE) 50 50 1 100 70-130 12/26/2018 2150 4-Methyl-2-pentanone 100 100 1 103 70-130 12/26/2018 2150 Methylcyclohexane 50 50 1 101 70-130 12/26/2018 2150 Methylene chloride 50 47 1 95 70-130 12/26/2018 2150 Styrene 50 50 1 101 70-130 12/26/2018 2150 1,1,2,2-Tetrachloroethane 50 52 1 103 70-130 12/26/2018 2150 Tetrachloroethene 50 51 1 102 70-130 12/26/2018 2150 Toluene 50 52 1 103 70-130 12/26/2018 2150 1,1,2-Trichloro-1,2,2-Trifluoroethane 50 49 1 98 70-130 12/26/2018 2150 1,2,4-Trichlorobenzene 50 52 1 104 70-130 12/26/2018 2150 1,1,1-Trichloroethane 50 47 1 95 70-130 12/26/2018 2150 1,1,2-Trichloroethane 50 51 1 101 70-130 12/26/2018 2150 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 22 of 40 Volatile Organic Compounds by GC/MS - LCS Sample ID: TQ93379-002 Matrix: Aqueous Batch: 93379 Prep Method: 5030E Analytical Method: 8260B Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Trichloroethene 50 49 1 98 70-130 12/26/2018 2150 Trichlorofluoromethane 50 51 1 101 70-130 12/26/2018 2150 Vinyl chloride 50 56 1 111 70-130 12/26/2018 2150 Xylenes (total) 100 100 1 102 70-130 12/26/2018 2150 Acceptance Surrogate Q % Rec Limit 1,2-Dichloroethane-d4 89 70-130 Bromofluorobenzene 100 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 23 of 40 Volatile Organic Compounds by GC/MS - MB Sample ID: TQ93619-001 Matrix: Aqueous Batch: 93619 Prep Method: 5030E Analytical Method: 8260B Parameter Result Q Dil LOQ Units Analysis Date Acetone ND 1 20 ug/L 12/28/2018 2210 Benzene ND 1 1.0 ug/L 12/28/2018 2210 Bromodichloromethane ND 1 1.0 ug/L 12/28/2018 2210 Bromoform ND 1 1.0 ug/L 12/28/2018 2210 Bromomethane (Methyl bromide) ND 1 2.0 ug/L 12/28/2018 2210 2-Butanone (MEK) ND 1 10 ug/L 12/28/2018 2210 Carbon disulfide ND 1 1.0 ug/L 12/28/2018 2210 Carbon tetrachloride ND 1 1.0 ug/L 12/28/2018 2210 Chlorobenzene ND 1 1.0 ug/L 12/28/2018 2210 Chloroethane ND 1 2.0 ug/L 12/28/2018 2210 Chloroform ND 1 1.0 ug/L 12/28/2018 2210 Chloromethane (Methyl chloride) ND 1 1.0 ug/L 12/28/2018 2210 Cyclohexane ND 1 1.0 ug/L 12/28/2018 2210 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 ug/L 12/28/2018 2210 Dibromochloromethane ND 1 1.0 ug/L 12/28/2018 2210 1,2-Dibromoethane (EDB) ND 1 1.0 ug/L 12/28/2018 2210 1,2-Dichlorobenzene ND 1 1.0 ug/L 12/28/2018 2210 1,3-Dichlorobenzene ND 1 1.0 ug/L 12/28/2018 2210 1,4-Dichlorobenzene ND 1 1.0 ug/L 12/28/2018 2210 Dichlorodifluoromethane ND 1 2.0 ug/L 12/28/2018 2210 1,1-Dichloroethane ND 1 1.0 ug/L 12/28/2018 2210 1,2-Dichloroethane ND 1 1.0 ug/L 12/28/2018 2210 1,1-Dichloroethene ND 1 1.0 ug/L 12/28/2018 2210 cis- 1,2-Dichloroethene ND 1 1.0 ug/L 12/28/2018 2210 trans- 1,2-Dichloroethene ND 1 1.0 ug/L 12/28/2018 2210 1,2-Dichloropropane ND 1 1.0 ug/L 12/28/2018 2210 cis- 1,3-Dichloropropene ND 1 1.0 ug/L 12/28/2018 2210 trans- 1,3-Dichloropropene ND 1 1.0 ug/L 12/28/2018 2210 Ethylbenzene ND 1 1.0 ug/L 12/28/2018 2210 2-Hexanone ND 1 10 ug/L 12/28/2018 2210 Isopropylbenzene ND 1 1.0 ug/L 12/28/2018 2210 Methyl acetate ND 1 1.0 ug/L 12/28/2018 2210 Methyl tertiary butyl ether (MTBE) ND 1 1.0 ug/L 12/28/2018 2210 4-Methyl-2-pentanone ND 1 10 ug/L 12/28/2018 2210 Methylcyclohexane ND 1 5.0 ug/L 12/28/2018 2210 Methylene chloride ND 1 1.0 ug/L 12/28/2018 2210 Styrene ND 1 1.0 ug/L 12/28/2018 2210 1,1,2,2-Tetrachloroethane ND 1 1.0 ug/L 12/28/2018 2210 Tetrachloroethene ND 1 1.0 ug/L 12/28/2018 2210 Toluene ND 1 1.0 ug/L 12/28/2018 2210 1,1,2-Trichloro-1,2,2-Trifluoroethane ND 1 1.0 ug/L 12/28/2018 2210 1,2,4-Trichlorobenzene ND 1 1.0 ug/L 12/28/2018 2210 1,1,1-Trichloroethane ND 1 1.0 ug/L 12/28/2018 2210 1,1,2-Trichloroethane ND 1 1.0 ug/L 12/28/2018 2210 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 24 of 40 Volatile Organic Compounds by GC/MS - MB Sample ID: TQ93619-001 Matrix: Aqueous Batch: 93619 Prep Method: 5030E Analytical Method: 8260B Parameter Result Q Dil LOQ Units Analysis Date Trichloroethene ND 1 1.0 ug/L 12/28/2018 2210 Trichlorofluoromethane ND 1 1.0 ug/L 12/28/2018 2210 Vinyl chloride ND 1 1.0 ug/L 12/28/2018 2210 Xylenes (total) ND 1 1.0 ug/L 12/28/2018 2210 Acceptance Surrogate Q % Rec Limit 1,2-Dichloroethane-d4 90 70-130 Bromofluorobenzene 103 70-130 Toluene-d8 99 70-130 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 25 of 40 Volatile Organic Compounds by GC/MS - LCS Sample ID: TQ93619-002 Matrix: Aqueous Batch: 93619 Prep Method: 5030E Analytical Method: 8260B Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 40 36 1 91 60-140 12/28/2018 2124 Benzene 20 19 1 95 70-130 12/28/2018 2124 Bromodichloromethane 20 18 1 90 70-130 12/28/2018 2124 Bromoform 20 17 1 86 70-130 12/28/2018 2124 Bromomethane (Methyl bromide) 20 21 1 105 70-130 12/28/2018 2124 2-Butanone (MEK) 40 37 1 94 70-130 12/28/2018 2124 Carbon disulfide 20 19 1 95 70-130 12/28/2018 2124 Carbon tetrachloride 20 18 1 89 70-130 12/28/2018 2124 Chlorobenzene 20 19 1 94 70-130 12/28/2018 2124 Chloroethane 20 21 1 105 70-130 12/28/2018 2124 Chloroform 20 18 1 91 70-130 12/28/2018 2124 Chloromethane (Methyl chloride) 20 20 1 99 60-140 12/28/2018 2124 Cyclohexane 20 18 1 92 70-130 12/28/2018 2124 1,2-Dibromo-3-chloropropane (DBCP) 20 17 1 87 70-130 12/28/2018 2124 Dibromochloromethane 20 18 1 92 70-130 12/28/2018 2124 1,2-Dibromoethane (EDB) 20 19 1 97 70-130 12/28/2018 2124 1,2-Dichlorobenzene 20 19 1 94 70-130 12/28/2018 2124 1,3-Dichlorobenzene 20 19 1 97 70-130 12/28/2018 2124 1,4-Dichlorobenzene 20 19 1 93 70-130 12/28/2018 2124 Dichlorodifluoromethane 20 20 1 101 60-140 12/28/2018 2124 1,1-Dichloroethane 20 19 1 94 70-130 12/28/2018 2124 1,2-Dichloroethane 20 19 1 93 70-130 12/28/2018 2124 1,1-Dichloroethene 20 19 1 94 70-130 12/28/2018 2124 cis- 1,2-Dichloroethene 20 19 1 95 70-130 12/28/2018 2124 trans- 1,2-Dichloroethene 20 19 1 96 70-130 12/28/2018 2124 1,2-Dichloropropane 20 17 1 85 70-130 12/28/2018 2124 cis- 1,3-Dichloropropene 20 17 1 83 70-130 12/28/2018 2124 trans- 1,3-Dichloropropene 20 17 1 83 70-130 12/28/2018 2124 Ethylbenzene 20 19 1 97 70-130 12/28/2018 2124 2-Hexanone 40 40 1 99 70-130 12/28/2018 2124 Isopropylbenzene 20 19 1 96 70-130 12/28/2018 2124 Methyl acetate 20 18 1 92 70-130 12/28/2018 2124 Methyl tertiary butyl ether (MTBE) 20 19 1 96 70-130 12/28/2018 2124 4-Methyl-2-pentanone 40 39 1 97 70-130 12/28/2018 2124 Methylcyclohexane 20 19 1 97 70-130 12/28/2018 2124 Methylene chloride 20 18 1 92 70-130 12/28/2018 2124 Styrene 20 19 1 97 70-130 12/28/2018 2124 1,1,2,2-Tetrachloroethane 20 19 1 96 70-130 12/28/2018 2124 Tetrachloroethene 20 20 1 99 70-130 12/28/2018 2124 Toluene 20 20 1 100 70-130 12/28/2018 2124 1,1,2-Trichloro-1,2,2-Trifluoroethane 20 18 1 92 70-130 12/28/2018 2124 1,2,4-Trichlorobenzene 20 21 1 103 70-130 12/28/2018 2124 1,1,1-Trichloroethane 20 18 1 89 70-130 12/28/2018 2124 1,1,2-Trichloroethane 20 20 1 98 70-130 12/28/2018 2124 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 26 of 40 Volatile Organic Compounds by GC/MS - LCS Sample ID: TQ93619-002 Matrix: Aqueous Batch: 93619 Prep Method: 5030E Analytical Method: 8260B Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Trichloroethene 20 19 1 96 70-130 12/28/2018 2124 Trichlorofluoromethane 20 19 1 95 70-130 12/28/2018 2124 Vinyl chloride 20 21 1 105 70-130 12/28/2018 2124 Xylenes (total) 40 39 1 98 70-130 12/28/2018 2124 Acceptance Surrogate Q % Rec Limit 1,2-Dichloroethane-d4 89 70-130 Bromofluorobenzene 97 70-130 Toluene-d8 98 70-130 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 27 of 40 Volatile Organic Compounds by GC/MS - MS Sample ID: TL18048-003MS Matrix: Aqueous Batch: 93619 Prep Method: 5030E Analytical Method: 8260B Sample Spike Amount Amount Result % Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone ND 1000 870 10 87 60-140 12/29/2018 0102 Benzene 61 500 520 10 92 70-130 12/29/2018 0102 Bromodichloromethane ND 500 450 10 89 70-130 12/29/2018 0102 Bromoform ND 500 420 10 83 70-130 12/29/2018 0102 Bromomethane (Methyl bromide) ND 500 460 10 93 70-130 12/29/2018 0102 2-Butanone (MEK) ND 1000 900 10 90 70-130 12/29/2018 0102 Carbon disulfide ND 500 470 10 94 70-130 12/29/2018 0102 Carbon tetrachloride ND 500 460 10 92 70-130 12/29/2018 0102 Chlorobenzene ND 500 460 10 92 70-130 12/29/2018 0102 Chloroethane ND 500 470 10 93 70-130 12/29/2018 0102 Chloroform ND 500 450 10 90 70-130 12/29/2018 0102 Chloromethane (Methyl chloride) ND 500 440 10 88 60-140 12/29/2018 0102 Cyclohexane 430 500 880 10 90 70-130 12/29/2018 0102 1,2-Dibromo-3-chloropropane (DBCP) ND 500 410 10 83 70-130 12/29/2018 0102 Dibromochloromethane ND 500 460 10 92 70-130 12/29/2018 0102 1,2-Dibromoethane (EDB) ND 500 460 10 93 70-130 12/29/2018 0102 1,2-Dichlorobenzene ND 500 450 10 90 70-130 12/29/2018 0102 1,3-Dichlorobenzene ND 500 460 10 92 70-130 12/29/2018 0102 1,4-Dichlorobenzene ND 500 450 10 89 70-130 12/29/2018 0102 Dichlorodifluoromethane ND 500 460 10 92 60-140 12/29/2018 0102 1,1-Dichloroethane ND 500 470 10 93 70-130 12/29/2018 0102 1,2-Dichloroethane ND 500 450 10 90 70-130 12/29/2018 0102 1,1-Dichloroethene ND 500 490 10 98 70-130 12/29/2018 0102 cis- 1,2-Dichloroethene ND 500 470 10 93 70-130 12/29/2018 0102 trans- 1,2-Dichloroethene ND 500 480 10 96 70-130 12/29/2018 0102 1,2-Dichloropropane ND 500 420 10 83 70-130 12/29/2018 0102 cis- 1,3-Dichloropropene ND 500 410 10 81 70-130 12/29/2018 0102 trans- 1,3-Dichloropropene ND 500 400 10 79 70-130 12/29/2018 0102 Ethylbenzene 360 500 820 10 93 70-130 12/29/2018 0102 2-Hexanone ND 1000 920 10 92 70-130 12/29/2018 0102 Isopropylbenzene 120 500 600 10 97 70-130 12/29/2018 0102 Methyl acetate ND 500 340 N 10 67 70-130 12/29/2018 0102 Methyl tertiary butyl ether (MTBE) ND 500 450 10 91 70-130 12/29/2018 0102 4-Methyl-2-pentanone ND 1000 920 10 92 70-130 12/29/2018 0102 Methylcyclohexane 500 500 980 10 95 70-130 12/29/2018 0102 Methylene chloride 13 500 460 10 89 70-130 12/29/2018 0102 Styrene ND 500 480 10 96 70-130 12/29/2018 0102 1,1,2,2-Tetrachloroethane ND 500 460 10 91 70-130 12/29/2018 0102 Tetrachloroethene ND 500 490 10 99 70-130 12/29/2018 0102 Toluene 21 500 510 10 97 70-130 12/29/2018 0102 1,1,2-Trichloro-1,2,2-Trifluoroethane ND 500 480 10 95 70-130 12/29/2018 0102 1,2,4-Trichlorobenzene ND 500 470 10 94 70-130 12/29/2018 0102 1,1,1-Trichloroethane ND 500 450 10 90 70-130 12/29/2018 0102 1,1,2-Trichloroethane ND 500 470 10 93 70-130 12/29/2018 0102 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 28 of 40 Volatile Organic Compounds by GC/MS - MS Sample ID: TL18048-003MS Matrix: Aqueous Batch: 93619 Prep Method: 5030E Analytical Method: 8260B Sample Spike Amount Amount Result % Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Trichloroethene ND 500 470 10 95 70-130 12/29/2018 0102 Trichlorofluoromethane ND 500 430 10 85 70-130 12/29/2018 0102 Vinyl chloride ND 500 470 10 94 70-130 12/29/2018 0102 Xylenes (total) 430 1000 1400 10 95 70-130 12/29/2018 0102 Acceptance Surrogate Q % Rec Limit 1,2-Dichloroethane-d4 87 70-130 Bromofluorobenzene 93 70-130 Toluene-d8 98 70-130 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 29 of 40 Volatile Organic Compounds by GC/MS - MSD Sample ID: TL18048-003MD Matrix: Aqueous Batch: 93619 Prep Method: 5030E Analytical Method: 8260B Sample Spike Amount Amount Result % Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Acetone ND 1000 800 10 80 8.5 60-140 20 12/29/2018 0125 Benzene 61 500 540 10 95 2.6 70-130 20 12/29/2018 0125 Bromodichloromethane ND 500 460 10 93 3.5 70-130 20 12/29/2018 0125 Bromoform ND 500 430 10 85 2.6 70-130 20 12/29/2018 0125 Bromomethane (Methyl bromide) ND 500 540 10 108 16 70-130 20 12/29/2018 0125 2-Butanone (MEK) ND 1000 910 10 91 1.7 70-130 20 12/29/2018 0125 Carbon disulfide ND 500 490 10 98 4.1 70-130 20 12/29/2018 0125 Carbon tetrachloride ND 500 470 10 94 1.7 70-130 20 12/29/2018 0125 Chlorobenzene ND 500 470 10 95 3.2 70-130 20 12/29/2018 0125 Chloroethane ND 500 550 10 109 16 70-130 20 12/29/2018 0125 Chloroform ND 500 450 10 91 1.1 70-130 20 12/29/2018 0125 Chloromethane (Methyl chloride) ND 500 520 10 103 16 60-140 20 12/29/2018 0125 Cyclohexane 430 500 910 10 97 3.8 70-130 20 12/29/2018 0125 1,2-Dibromo-3-chloropropane (DBCP) ND 500 450 10 89 7.4 70-130 20 12/29/2018 0125 Dibromochloromethane ND 500 470 10 94 2.7 70-130 20 12/29/2018 0125 1,2-Dibromoethane (EDB) ND 500 470 10 95 2.3 70-130 20 12/29/2018 0125 1,2-Dichlorobenzene ND 500 490 10 98 8.0 70-130 20 12/29/2018 0125 1,3-Dichlorobenzene ND 500 500 10 99 7.7 70-130 20 12/29/2018 0125 1,4-Dichlorobenzene ND 500 480 10 97 8.1 70-130 20 12/29/2018 0125 Dichlorodifluoromethane ND 500 550 10 110 17 60-140 20 12/29/2018 0125 1,1-Dichloroethane ND 500 470 10 95 1.8 70-130 20 12/29/2018 0125 1,2-Dichloroethane ND 500 460 10 91 1.3 70-130 20 12/29/2018 0125 1,1-Dichloroethene ND 500 500 10 99 1.4 70-130 20 12/29/2018 0125 cis- 1,2-Dichloroethene ND 500 480 10 96 2.8 70-130 20 12/29/2018 0125 trans- 1,2-Dichloroethene ND 500 490 10 98 1.2 70-130 20 12/29/2018 0125 1,2-Dichloropropane ND 500 420 10 85 1.7 70-130 20 12/29/2018 0125 cis- 1,3-Dichloropropene ND 500 420 10 84 4.0 70-130 20 12/29/2018 0125 trans- 1,3-Dichloropropene ND 500 410 10 82 3.4 70-130 20 12/29/2018 0125 Ethylbenzene 360 500 860 10 99 3.7 70-130 20 12/29/2018 0125 2-Hexanone ND 1000 940 10 94 2.2 70-130 20 12/29/2018 0125 Isopropylbenzene 120 500 610 10 98 0.94 70-130 20 12/29/2018 0125 Methyl acetate ND 500 420 + 10 84 22 70-130 20 12/29/2018 0125 Methyl tertiary butyl ether (MTBE) ND 500 470 10 93 2.5 70-130 20 12/29/2018 0125 4-Methyl-2-pentanone ND 1000 950 10 95 2.5 70-130 20 12/29/2018 0125 Methylcyclohexane 500 500 1000 10 103 4.2 70-130 20 12/29/2018 0125 Methylene chloride 13 500 470 10 90 1.4 70-130 20 12/29/2018 0125 Styrene ND 500 490 10 98 2.5 70-130 20 12/29/2018 0125 1,1,2,2-Tetrachloroethane ND 500 490 10 99 7.8 70-130 20 12/29/2018 0125 Tetrachloroethene ND 500 500 10 100 1.4 70-130 20 12/29/2018 0125 Toluene 21 500 520 10 100 3.1 70-130 20 12/29/2018 0125 1,1,2-Trichloro-1,2,2-Trifluoroethane ND 500 490 10 97 2.0 70-130 20 12/29/2018 0125 1,2,4-Trichlorobenzene ND 500 510 10 103 8.3 70-130 20 12/29/2018 0125 1,1,1-Trichloroethane ND 500 460 10 93 3.5 70-130 20 12/29/2018 0125 1,1,2-Trichloroethane ND 500 470 10 95 1.3 70-130 20 12/29/2018 0125 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 30 of 40 Volatile Organic Compounds by GC/MS - MSD Sample ID: TL18048-003MD Matrix: Aqueous Batch: 93619 Prep Method: 5030E Analytical Method: 8260B Sample Spike Amount Amount Result % Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Trichloroethene ND 500 490 10 97 2.8 70-130 20 12/29/2018 0125 Trichlorofluoromethane ND 500 500 10 101 17 70-130 20 12/29/2018 0125 Vinyl chloride ND 500 560 10 112 18 70-130 20 12/29/2018 0125 Xylenes (total) 430 1000 1400 10 99 2.9 70-130 20 12/29/2018 0125 Acceptance Surrogate Q % Rec Limit 1,2-Dichloroethane-d4 90 70-130 Bromofluorobenzene 105 70-130 Toluene-d8 102 70-130 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 31 of 40 Semivolatile Organic Compounds by GC/MS - MB Sample ID: TQ93115-001 Matrix: Aqueous Batch: 93115 Prep Method: 3520C Analytical Method: 8270D Prep Date: 12/21/2018 1643 Parameter Result Q Dil LOQ Units Analysis Date Acenaphthene ND 1 0.80 ug/L 12/23/2018 1117 Acenaphthylene ND 1 0.80 ug/L 12/23/2018 1117 Anthracene ND 1 0.80 ug/L 12/23/2018 1117 Benzo(a)anthracene ND 1 0.80 ug/L 12/23/2018 1117 Benzo(a)pyrene ND 1 0.80 ug/L 12/23/2018 1117 Benzo(b)fluoranthene ND 1 0.80 ug/L 12/23/2018 1117 Benzo(g,h,i)perylene ND 1 0.80 ug/L 12/23/2018 1117 Benzo(k)fluoranthene ND 1 0.80 ug/L 12/23/2018 1117 Chrysene ND 1 0.80 ug/L 12/23/2018 1117 Dibenzo(a,h)anthracene ND 1 0.80 ug/L 12/23/2018 1117 Fluoranthene ND 1 0.80 ug/L 12/23/2018 1117 Fluorene ND 1 0.80 ug/L 12/23/2018 1117 Indeno(1,2,3-c,d)pyrene ND 1 0.80 ug/L 12/23/2018 1117 1-Methyl naphthalene ND 1 0.80 ug/L 12/23/2018 1117 2-Methyl naphthalene ND 1 0.80 ug/L 12/23/2018 1117 Naphthalene ND 1 0.80 ug/L 12/23/2018 1117 Phenanthrene ND 1 0.80 ug/L 12/23/2018 1117 Pyrene ND 1 0.80 ug/L 12/23/2018 1117 Surrogate Q % Rec Acceptance Limit Nitrobenzene-d5 69 38-127 2-Fluorobiphenyl 52 37-129 Terphenyl-d 14 104 10-148 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 32 of 40 Semivolatile Organic Compounds by GC/MS - LCS Sample ID: TQ93115-002 Matrix: Aqueous Batch: 93115 Prep Method: 3520C Analytical Method: 8270D Prep Date: 12/21/2018 1643 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acenaphthene 40 28 1 71 30-122 12/23/2018 1141 Acenaphthylene 40 25 1 62 30-130 12/23/2018 1141 Anthracene 40 31 1 78 30-123 12/23/2018 1141 Benzo(a)anthracene 40 38 1 94 40-125 12/23/2018 1141 Benzo(a)pyrene 40 33 1 83 40-128 12/23/2018 1141 Benzo(b)fluoranthene 40 36 1 90 30-130 12/23/2018 1141 Benzo(g,h,i)perylene 40 41 1 101 30-130 12/23/2018 1141 Benzo(k)fluoranthene 40 38 1 95 30-130 12/23/2018 1141 Chrysene 40 38 1 96 30-130 12/23/2018 1141 Dibenzo(a,h)anthracene 40 38 1 94 30-130 12/23/2018 1141 Fluoranthene 40 37 1 93 40-128 12/23/2018 1141 Fluorene 40 27 1 68 30-124 12/23/2018 1141 Indeno(1,2,3-c,d)pyrene 40 38 1 95 30-130 12/23/2018 1141 1-Methyl naphthalene 40 30 1 75 42-126 12/23/2018 1141 2-Methyl naphthalene 40 29 1 73 40-132 12/23/2018 1141 Naphthalene 40 30 1 76 30-130 12/23/2018 1141 Phenanthrene 40 31 1 78 40-123 12/23/2018 1141 Pyrene 40 40 1 100 40-126 12/23/2018 1141 Surrogate Q % Rec Acceptance Limit Nitrobenzene-d5 98 38-127 2-Fluorobiphenyl 65 37-129 Terphenyl-d 14 107 10-148 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 33 of 40 Semivolatile Organic Compounds by GC/MS - MB Sample ID: TQ93116-001 Matrix: Aqueous Batch: 93116 Prep Method: 3520C Analytical Method: 8270D Prep Date: 12/21/2018 1643 Parameter Result Q Dil LOQ Units Analysis Date 1,1'-Biphenyl ND 1 4.0 ug/L 12/23/2018 1117 2,4,5-Trichlorophenol ND 1 4.0 ug/L 12/23/2018 1117 2,4,6-Trichlorophenol ND 1 4.0 ug/L 12/23/2018 1117 2,4-Dichlorophenol ND 1 8.0 ug/L 12/23/2018 1117 2,4-Dimethylphenol ND 1 4.0 ug/L 12/23/2018 1117 2,4-Dinitrophenol ND 1 20 ug/L 12/23/2018 1117 2,4-Dinitrotoluene ND 1 8.0 ug/L 12/23/2018 1117 2,6-Dinitrotoluene ND 1 8.0 ug/L 12/23/2018 1117 2-Chloronaphthalene ND 1 4.0 ug/L 12/23/2018 1117 2-Chlorophenol ND 1 4.0 ug/L 12/23/2018 1117 2-Methyl naphthalene ND 1 0.80 ug/L 12/23/2018 1117 2-Methylphenol ND 1 4.0 ug/L 12/23/2018 1117 2-Nitroaniline ND 1 8.0 ug/L 12/23/2018 1117 2-Nitrophenol ND 1 4.0 ug/L 12/23/2018 1117 3,3'-Dichlorobenzidine ND 1 4.0 ug/L 12/23/2018 1117 3+4-Methylphenol ND 1 4.0 ug/L 12/23/2018 1117 3-Nitroaniline ND 1 8.0 ug/L 12/23/2018 1117 4,6-Dinitro-2-methyl phenol ND 1 20 ug/L 12/23/2018 1117 4-Bromophenyl phenyl ether ND 1 4.0 ug/L 12/23/2018 1117 4-Chloro-3-methyl phenol ND 1 4.0 ug/L 12/23/2018 1117 4-Chloroaniline ND 1 8.0 ug/L 12/23/2018 1117 4-Chlorophenyl phenyl ether ND 1 4.0 ug/L 12/23/2018 1117 4-Nitroaniline ND 1 8.0 ug/L 12/23/2018 1117 4-Nitrophenol ND 1 20 ug/L 12/23/2018 1117 Acenaphthene ND 1 0.80 ug/L 12/23/2018 1117 Acenaphthylene ND 1 0.80 ug/L 12/23/2018 1117 Acetophenone ND 1 4.0 ug/L 12/23/2018 1117 Anthracene ND 1 0.80 ug/L 12/23/2018 1117 Atrazine ND 1 4.0 ug/L 12/23/2018 1117 Benzaldehyde ND 1 8.0 ug/L 12/23/2018 1117 Benzo(a)anthracene ND 1 0.80 ug/L 12/23/2018 1117 Benzo(a)pyrene ND 1 0.80 ug/L 12/23/2018 1117 Benzo(b)fluoranthene ND 1 0.80 ug/L 12/23/2018 1117 Benzo(g,h,i)perylene ND 1 0.80 ug/L 12/23/2018 1117 Benzo(k)fluoranthene ND 1 0.80 ug/L 12/23/2018 1117 bis (2-Chloro-1-methylethyl) ether ND 1 4.0 ug/L 12/23/2018 1117 bis(2-Chloroethoxy)methane ND 1 4.0 ug/L 12/23/2018 1117 bis(2-Chloroethyl)ether ND 1 4.0 ug/L 12/23/2018 1117 bis(2-Ethylhexyl)phthalate ND 1 4.0 ug/L 12/23/2018 1117 Butyl benzyl phthalate ND 1 4.0 ug/L 12/23/2018 1117 Caprolactam ND 1 8.0 ug/L 12/23/2018 1117 Carbazole ND 1 4.0 ug/L 12/23/2018 1117 Chrysene ND 1 0.80 ug/L 12/23/2018 1117 Dibenzo(a,h)anthracene ND 1 0.80 ug/L 12/23/2018 1117 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 34 of 40 Semivolatile Organic Compounds by GC/MS - MB Sample ID: TQ93116-001 Matrix: Aqueous Batch: 93116 Prep Method: 3520C Analytical Method: 8270D Prep Date: 12/21/2018 1643 Parameter Result Q Dil LOQ Units Analysis Date Dibenzofuran ND 1 4.0 ug/L 12/23/2018 1117 Diethylphthalate ND 1 4.0 ug/L 12/23/2018 1117 Dimethyl phthalate ND 1 4.0 ug/L 12/23/2018 1117 Di-n-butyl phthalate ND 1 4.0 ug/L 12/23/2018 1117 Di-n-octylphthalate ND 1 4.0 ug/L 12/23/2018 1117 Fluoranthene ND 1 0.80 ug/L 12/23/2018 1117 Fluorene ND 1 0.80 ug/L 12/23/2018 1117 Hexachlorobenzene ND 1 4.0 ug/L 12/23/2018 1117 Hexachlorobutadiene ND 1 4.0 ug/L 12/23/2018 1117 Hexachlorocyclopentadiene ND 1 20 ug/L 12/23/2018 1117 Hexachloroethane ND 1 4.0 ug/L 12/23/2018 1117 Indeno(1,2,3-c,d)pyrene ND 1 0.80 ug/L 12/23/2018 1117 Isophorone ND 1 4.0 ug/L 12/23/2018 1117 Naphthalene ND 1 0.80 ug/L 12/23/2018 1117 Nitrobenzene ND 1 4.0 ug/L 12/23/2018 1117 N-Nitrosodi-n-propylamine ND 1 4.0 ug/L 12/23/2018 1117 N-Nitrosodiphenylamine (Diphenylamine) ND 1 4.0 ug/L 12/23/2018 1117 Pentachlorophenol ND 1 20 ug/L 12/23/2018 1117 Phenanthrene ND 1 0.80 ug/L 12/23/2018 1117 Phenol ND 1 4.0 ug/L 12/23/2018 1117 Pyrene ND 1 0.80 ug/L 12/23/2018 1117 Surrogate Q % Rec Acceptance Limit 2-Fluorobiphenyl 52 37-129 2-Fluorophenol 33 24-127 Nitrobenzene-d5 69 38-127 Phenol-d5 43 28-128 Terphenyl-d 14 104 10-148 2,4,6-Tribromophenol 49 35-144 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 35 of 40 Semivolatile Organic Compounds by GC/MS - LCS Sample ID: TQ93116-002 Matrix: Aqueous Batch: 93116 Prep Method: 3520C Analytical Method: 8270D Prep Date: 12/21/2018 1643 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,1'-Biphenyl 40 28 1 69 30-130 12/23/2018 1141 2,4,5-Trichlorophenol 40 24 1 59 30-123 12/23/2018 1141 2,4,6-Trichlorophenol 40 25 1 62 30-130 12/23/2018 1141 2,4-Dichlorophenol 40 28 1 70 30-121 12/23/2018 1141 2,4-Dimethylphenol 40 26 1 66 20-125 12/23/2018 1141 2,4-Dinitrophenol 80 78 1 97 11-126 12/23/2018 1141 2,4-Dinitrotoluene 40 36 1 90 30-130 12/23/2018 1141 2,6-Dinitrotoluene 40 32 1 80 30-130 12/23/2018 1141 2-Chloronaphthalene 40 26 1 65 30-130 12/23/2018 1141 2-Chlorophenol 40 30 1 74 30-130 12/23/2018 1141 2-Methyl naphthalene 40 29 1 73 40-132 12/23/2018 1141 2-Methylphenol 40 36 1 90 30-130 12/23/2018 1141 2-Nitroaniline 40 33 1 82 30-130 12/23/2018 1141 2-Nitrophenol 40 33 1 83 30-130 12/23/2018 1141 3,3'-Dichlorobenzidine 40 25 1 63 10-126 12/23/2018 1141 3+4-Methylphenol 40 33 1 81 30-130 12/23/2018 1141 3-Nitroaniline 40 29 1 73 30-130 12/23/2018 1141 4,6-Dinitro-2-methyl phenol 40 50 1 125 30-130 12/23/2018 1141 4-Bromophenyl phenyl ether 40 29 1 73 30-124 12/23/2018 1141 4-Chloro-3-methyl phenol 40 33 1 83 30-123 12/23/2018 1141 4-Chloroaniline 40 19 1 49 12-157 12/23/2018 1141 4-Chlorophenyl phenyl ether 40 27 1 67 30-121 12/23/2018 1141 4-Nitroaniline 40 37 1 92 30-135 12/23/2018 1141 4-Nitrophenol 80 66 1 83 30-130 12/23/2018 1141 Acenaphthene 40 28 1 71 30-122 12/23/2018 1141 Acenaphthylene 40 25 1 62 30-130 12/23/2018 1141 Acetophenone 40 35 1 87 30-130 12/23/2018 1141 Anthracene 40 31 1 78 30-123 12/23/2018 1141 Atrazine 40 42 1 104 30-130 12/23/2018 1141 Benzaldehyde 40 31 1 78 20-115 12/23/2018 1141 Benzo(a)anthracene 40 38 1 94 40-125 12/23/2018 1141 Benzo(a)pyrene 40 33 1 83 40-128 12/23/2018 1141 Benzo(b)fluoranthene 40 36 1 90 30-130 12/23/2018 1141 Benzo(g,h,i)perylene 40 41 1 101 30-130 12/23/2018 1141 Benzo(k)fluoranthene 40 38 1 95 30-130 12/23/2018 1141 bis (2-Chloro-1-methylethyl) ether 40 35 1 87 30-130 12/23/2018 1141 bis(2-Chloroethoxy)methane 40 29 1 72 30-130 12/23/2018 1141 bis(2-Chloroethyl)ether 40 36 1 89 30-130 12/23/2018 1141 bis(2-Ethylhexyl)phthalate 40 36 1 90 30-130 12/23/2018 1141 Butyl benzyl phthalate 40 41 1 103 30-130 12/23/2018 1141 Caprolactam 40 40 1 99 30-130 12/23/2018 1141 Carbazole 40 34 1 85 30-130 12/23/2018 1141 Chrysene 40 38 1 96 30-130 12/23/2018 1141 Dibenzo(a,h)anthracene 40 38 1 94 30-130 12/23/2018 1141 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 36 of 40 Semivolatile Organic Compounds by GC/MS - LCS Sample ID: TQ93116-002 Matrix: Aqueous Batch: 93116 Prep Method: 3520C Analytical Method: 8270D Prep Date: 12/21/2018 1643 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Dibenzofuran 40 27 1 67 30-118 12/23/2018 1141 Diethylphthalate 40 33 1 82 40-125 12/23/2018 1141 Dimethyl phthalate 40 29 1 72 40-127 12/23/2018 1141 Di-n-butyl phthalate 40 39 1 98 40-127 12/23/2018 1141 Di-n-octylphthalate 40 31 1 78 30-130 12/23/2018 1141 Fluoranthene 40 37 1 93 40-128 12/23/2018 1141 Fluorene 40 27 1 68 30-124 12/23/2018 1141 Hexachlorobenzene 40 29 1 73 30-125 12/23/2018 1141 Hexachlorobutadiene 40 30 1 75 24-110 12/23/2018 1141 Hexachlorocyclopentadiene 200 100 1 51 22-122 12/23/2018 1141 Hexachloroethane 40 31 1 78 30-130 12/23/2018 1141 Indeno(1,2,3-c,d)pyrene 40 38 1 95 30-130 12/23/2018 1141 Isophorone 40 32 1 80 30-130 12/23/2018 1141 Naphthalene 40 30 1 76 30-130 12/23/2018 1141 Nitrobenzene 40 39 1 98 30-130 12/23/2018 1141 N-Nitrosodi-n-propylamine 40 39 1 98 30-130 12/23/2018 1141 N-Nitrosodiphenylamine (Diphenylamine) 40 34 1 85 30-123 12/23/2018 1141 Pentachlorophenol 80 65 1 82 30-130 12/23/2018 1141 Phenanthrene 40 31 1 78 40-123 12/23/2018 1141 Phenol 40 31 1 78 30-130 12/23/2018 1141 Pyrene 40 40 1 100 40-126 12/23/2018 1141 Acceptance Surrogate Q % Rec Limit 2-Fluorobiphenyl 65 37-129 2-Fluorophenol 72 24-127 Nitrobenzene-d5 98 38-127 Phenol-d5 78 28-128 Terphenyl-d 14 107 10-148 2,4,6-Tribromophenol 76 35-144 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the LOQ Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 37 of 40 Chain of Custody and Miscellaneous Documents Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 38 of 40 SHEALY ENVIRONMENTAL SERVICES, INC. p— co z �I A �r � s ib i r ., 3 ' ro C. CE 4 } rl 4 cU4 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 39 of 40 SHEALY ENVIRONMENTAL SERVICES, INC. 'nc. Page ] qd`I 1.1nimem. 1v_xher: %.'.:.::-j I..::-,= k.ret:-�e.-Viw. 3')P0 L8 a i np lc Receipt Checklist (rS Q q C1ieL'.'_' �r " I � (' I �r�t-�-I ' ��`�:}ICt It'L-�ncx;t�d '�[�.t�; t� ��7 � �.. I ' t tut #_ � � •� f� N-143ans of reMipt: ESl ❑ Client Q UPS n FedEx n 01lier — LJ Y es oj j 1. W= uusto y souls prmimt en the collykO I Yes ❑ No }1. 1# cusl[n stale were reralt, were imtsr an;l rmbr,}ken? pH Strip ID: Chlorine Strip ID: 'Tested by' Cirig'natt tePrrtpanture upon receipt Derived (Corrocted) prap=%m upon r'ecefpr; %.SolW 8n5p-C:1jp IA. Il�ltthody nper$# Ixlc ❑Agri s- . otfles a Ukin iD. Ll {il1R { oi7ect[rny 1 aCtOI 4f "t lwktftod of owl � er :ce L I I Tacks ❑ D lee ❑ 7Qgne tYrx � Ej Wn . If lVMPc'r4A= of any cooler cxc,,cdcd 6.0 'C, war, 'Mica Man ager Notified? L� NPM was Nutifiod by: phone i email r fake-m-face (circle one). ❑ Yes o 4. is tm tiro commercial Ctrw-ier's, pocking, slip UI.Licbrd ur ibis f*rm? ens ❑ Nu S_ 'Wera lrr�rer eustadv J+oc;ertlures (relinyuisE.rcUr c civrd) fuHDwed? ❑ Na 'uu sump lic 1 li9tcd ors w C'CJC'. es ❑ No 7_ Wme sample IN listed on all sample containers? tSI ❑ No 8. Was colleetion date & time listed on the CDC`, ❑ N. 9_ War calibmiem dW.,,- & tbnc listed on all samples containers?1. 1 cs ❑ No 10. Did all container label infbernallon (ID, date, timej apreo wlth the COC.? e: No 11. Were tests w he performM liekxl on tho Coo? LJ Na 2, Died all mniplm arrive in the proper aonminers for -each t~L-qt andiar in good rcmdition 1("vnbrokem, lids olri. cam)? PIyp ❑ No 13. lgsudeuatcrunplc volumt a'ailabJe'f -es ❑ No 14. Were all samples received within Va dir haklintg tirnt or 49 hom.-whieheuej' comes firs Yo 15. Were any samples ccwtninen missingAm s (carck one) samples Mat listed on OOC? ❑ Yes ' ,r n NA 16. For VOA and XSK-1?S .gantples, were Ixlktbles pmwit>"P"-si ' ('14"or binm in diant ) ir. arWorthe YC}dvisls'2 ❑ Yws L. I 151a 11 Winie all DR"eials nutri ent sarn plcu rc=ivcd ai it pfl of < 27 ❑ Yes ❑ No 18- W= all cyanide son les iceived at a pH::- 12 and sullida satnplc9 rcccivcd at a jT1-I .- zz— ❑ yes❑ No��AiollilorirLL; 19] t7brc=r+: applicable Nli,1TKNiryan i4eiphmoV625 (< 0.5mg1L) sampies free of residyte] ^ ' QYes ❑ No -- NA 0. WeM cli ant rem;2rk81xo[lu gists (i_e, requested dilutions, WAND d�i�,utioaas, etc, , , ) correctly tram?,mibe>d from tho COC ilito the cartsoserrt Median in J Yes Q w 1. Wus lht eluote number I isted on the container label? If yes, QLmte t ~— Fample Preservatlon (Must b-�complei)5dfor any snrnplu(4) incorrecly proserv4A or with headspace.) Nalnist [s} wcrc rxv &L� d incorrectly presened and wea't sndjustad a gIv : rL s mrl a res r.i.ring .With _mL of circle au&- 142SO 4, HNO3, FJ U, NaUk using SR ft ime of presentation 1f rncw'o than om. pnfeserwrd' ve :s needed, please t,otic itt the comments below. e�e7 to rl) wcrc received with bubl*6'.6-mm in diamezt�L ampLe�(s} were rweived with 1RC : 0_5 trL&L (lf.414 is mo ) and wi-.rc adjusted aecordinSly in sample recengngvwith sodiam thiosulfate CNa,S20,) wiLh Shealy ID: - -- ItsR bnrrr.rle labols iTplicd b}- _ t" IV D ! i-• j 11' 11 a II Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 40 of 40