3902_Granville_Butner_MSWLF_GW_FID1261331_201808

LENR USE ONLY El Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No) Doc/Event #:
NC DENR Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
Joyce Engineering, Inc.
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: G. Van Ness Burbach, Ph.D., P.G. Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
State Road 1004 August 13-15, 2018
Butner Landfill Butner, NC L39-02 .1600 November 02, 2018
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ❑ Detection Monitoring ❑X Assessment Monitoring ❑X Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑X
Leachate monitoring data
Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify) MNA Data
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
G. VanNess Burbach, Ph.D., PG Technical Consultant [phone]
2211 W. Meadowview Rd., Ste. 101 Greensboro, NC 27407
Facility Representative Address
C-0782
NC PE Firm License Number (if applicable effective May 1, 2009)
(Area Code) Telephone Number
„ Affix NC_jif,�g/_Professional Geologist Seal
CARo
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1349
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Revised 6/2009

PREPARED FOR:
GRANVILLE COUNTY
SOLID WASTE DEPARTMENT
P.O. Box 906
OXFORD, NORTH CAROLINA 27565
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BUTNER LANDFILL
PERMIT No. 39-02
AUGUST 2018 SEMIANNUAL
WATER QUALITY MONITORING REPORT
DECEMBER 2018
PREPARED BY:
&`i I EEE
E"4--J 1EEF711VG
2211 WEST MEADOWVIEW ROAD, SUITE 101
GREENSBORO, NORTH CAROLINA 27407
NC LICENSE NUMBER C-0782
PHONE: [phone]
FAx: [phone]
JOYCE PROJECT No. 2182022.01.07

August 2018 Semiannual Water Quality Monitoring Report
Butner Landfill, Permit No. 39-02
Granville County, North Carolina
TABLE OF CONTENTS
4.0
INTRODUCTION..............................................................................................................I
1.1
Site Information...................................................................................................................1
1.2
Site Geology.........................................................................................................................1
1.3
Groundwater Monitoring History........................................................................................1
1.4
Regulatory Status.................................................................................................................2
2.0
FACILITY MONITORING PROGRAM.......................................................................2
2.1
Groundwater Monitoring Program......................................................................................2
2.2
Surface Water Monitoring Program.....................................................................................3
3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2018............................................4
3.1 Field Work...........................................................................................................................4
3.1.1 Resampling Field Work............................................................................................ 4
3.2 Laboratory Analyses and Quality Control...........................................................................4
3.2.1 Analyses for Resampling Event................................................................................ 5
4.0
ANALYTICAL RESULTS AND STATISTICAL ANALYSES....................................5
4.1
Analytical Results for Groundwater and Comparisons to Standards...................................5
4.1.1 Inorganic Analyses....................................................................................................
5
4.1.2 Organic Analyses......................................................................................................
6
4.2
Statistical Analyses..............................................................................................................6
4.2.1 Statistical Methods....................................................................................................
6
4.2.2 Results of Statistical Analyses..................................................................................
7
4.3
Analytical Results for Surface Water and Comparisons to Standards.................................7
5.0
HYDROGEOLOGICAL CONDITIONS........................................................................7
6.0
CORRECTIVE ACTION EVALUATION.....................................................................8
6.1
Monitored Natural Attenuation Parameters.........................................................................8
6.2
Phytoremediation.................................................................................................................8
6.3
Evaluation of Plume Stability and Trends...........................................................................9
7.0
CONCLUSIONS................................................................................................................9
8.0
REFERENCES.................................................................................................................10
9.0
ACRONYMS....................................................................................................................10
Granville County - Butner Landfill, Permit No. 39-02 Joyce Engineering
August 2018 Semiannual Water Quality Monitoring Report December 2018
i

August 2018 Semiannual Water Quality Monitoring Report
Butner Landfill, Permit No. 39-02
Granville County, North Carolina
TABLE OF CONTENTS (CONTINUED)
Tables
Table 1
Monitoring Well Construction Data
Table 2
August 2018 Groundwater Elevations
Table 3
August 2018 Field Parameters
Table 4
Detected Constituents in Groundwater and Surface Water
Table 5
Exceedances of Groundwater Standards
Table 6
Hydraulic Gradients and Groundwater Flow Velocities
Table 7
Monitored Natural Attenuation Parameters
Charts
Chart 1
Benzene Concentrations vs. Time
Chart 2
Cobalt Concentrations vs. Time
Figure
Figure 1
Site Location Map
Drawings
Drawing 1 Groundwater Potentiometric Surface Map
Drawing 2 2018 Tree Survey
Appendices
Appendix A Field Data Logs
Appendix B Laboratory Analytical Reports and Chains of Custody
Appendix C Historical Groundwater Elevations
Appendix D Historical Constituents in Groundwater
Appendix E Historical Constituents in Surface Water
Granville County - Butner Landfill, Permit No. 39-02 Joyce Engineering
August 2018 Semiannual Water Quality Monitoring Report December 2018
ii

1.0 INTRODUCTION
1.1 Site Information
The Butner Landfill is a closed municipal solid waste (MSW) landfill, located off State Route
1004 near the town of Butner, in Granville County, North Carolina (Figure 1). The Butner
facility started receiving solid waste prior to May 1973. Permit Number 39-02, was issued by
the State of North Carolina on March 3, 1982. The facility stopped receiving solid waste in
August 1998. At the present, a small recycling center and transfer station are operated by the
County of Granville at the entrance of the closed landfill.
In accordance with North Carolina Solid Waste Management Regulations (NCSWMR), the
Butner Landfill entered an Assessment Monitoring Program in December of 1997 as a result of
detections of volatile organic compounds and pesticides above 15A-NCAC-2L (NC2L)
Groundwater Standards. An Assessment of Corrective Measures (ACM) was initiated in 2003,
and then suspended by North Carolina Department of Environment and Natural Resources
(NCDENR) [now the Department of Environmental Quality (NCDEQ)] since there had been no
more NC2L exceedances. The Nature and Extent Study (NES) and ACM recommenced in 2007
when apparent volatile organic compound (VOC) exceedances of the NC2L Standards began to
appear; however, they were again suspended when it was determined that the apparent
exceedances were not statistically significant increases (SSIs) above background. An ACM was
reinitiated after an exceedance of benzene in MW-2R in December 2012, and was submitted to
NCDENR in May 2013. Approval of the ACM was granted in a letter from NCDENR dated
June 27, 2013. A Corrective Action Plan (CAP) for monitored natural attenuation (MNA) plus
phytoremediation was submitted to NCDENR on May 23, 2014, and was approved by NCDENR
on June 18, 2014.
1.2 Site Geology
The Butner Landfill lies within the Piedmont physiographic province. The topography of the
area consists of rolling hills that support farmland and forest. The majority of the landfill area is
underlain by Carolina Slate Belt felsic volcanic rocks, which have been metamorphosed into
greenish grey foliated tuffs. The southeastern portion of the site is underlain by Triassic Sanford
Formation (conglomerate, sandstone, and mudstone), which unconformably overlies the Carolina
Slate Belt felsic volcanic rocks. There is no exposure of the Sanford Formation at the site;
however, float material consisting of grey, coarse -grained sandstone with quartz pebbles was
observed. Diabase dikes have also been observed in the vicinity of the site. Geologic
descriptions were taken from GAI Consultants' Groundwater and Surface Water Monitoring
System report (GAI, 1994).
1.3 Groundwater Monitoring History
• April 1994 — Current Monitoring Well Network installed.
• Dec. 1997 - The facility entered Assessment Monitoring.
• June 2003 — NC2L exceedances for heptachlor in MW-2R and MW-3R initiated an
ACM.
August 2018 Semiannual Water Quality Monitoring Report Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 November 2018
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• Dec. 2004 & June 2005 — There were no NC2L exceedances, so DENR agreed to put the
ACM on hold pending future monitoring results. At first, DENR said the facility needed
deed restrictions on adjoining property owned by the County, but this was apparently
based on incorrect information (the County did not own the property) so the requirement
for deed restrictions was dropped.
• Dec. 2006 — Benzene in MW-2R and 1,4-dichlorobenzene in MW-2R and MW-3R
detected above NC2L standards.
• June 14, 2007 - Granville County and JOYCE met with DENR to discuss a strategy for
performing a Nature and Extent Study (NES) and an ACM.
• Nov. 2007 — Nature & Extent well NES-1 was installed downgradient of MW-2R &
MW-3R.
• Dec. 2007 — NES & MNA sampling event on selected wells.
• Dec. 2008 — Organic results above the NC2L standards were determined to not represent
statistically significant exceedances, so corrective action and ACM were suspended with
the concurrence of the DENR and in accordance with the NCSWMR.
• Dec. 2012 — Benzene detections above the NC2L in MW-2R initiated the ACM.
• May 17, 2013 — ACM addressing the benzene detections above the NC2L in MW-2R
submitted to DENR.
• June 27, 2013 — ACM approved by DENR.
• September 3, 2013 — Public meeting and selection of remedy MNA plus
phytoremediation
• May 23, 2014 — CAP submitted to DENR.
• June 18, 2014 — CAP approved by DENR.
• December 2015 — Ist Corrective Action Evaluation Report (CARE) submitted
• February 2, 2016- Corrective Action Evaluation Report (CARE) reviewed and approved
by NCDEQ. NCDEQ denied the request to remove selected MNA parameters but
allowed a modified monitoring frequency beginning February 2018.
1.4 Regulatory Status
Groundwater and surface water monitoring at the Butner Landfill is completed in accordance
with NCSWMR §.1634-.1637. The site is currently in Assessment Monitoring and a Corrective
Action Monitoring Program. Groundwater samples are collected semiannually and analyzed in
accordance with the approved Corrective Action Plan. Surface water samples are collected and
sampled for Appendix I of 40 CFR Part 258, from here on known as North Carolina (NC)
Appendix I list of constituents during each sampling event.
2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
Seven active groundwater monitoring wells comprise the monitoring network at the Butner
Landfill: MW-IR (facility background well), MW-2R, MW-3R, MW-4, MW-5, MW-6, and
NES-1 (which was installed as part of a Nature and Extent Study on November 14, 2007). The
following table summarizes the monitoring network and required analytical parameters. A
summary of well construction details is provided in Table 1.
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Groundwater Moni
oring Network
Monitoring
Date
Monitoring
Lithology of
1a' SA Event
2"d SA Event
Well
Installed
Classification
Program
TD (ft)
Screened
Analyses
Analyses
Interval
MW-IR
4/21/94
Background
Assessment/
45.1
Saprolite
App.I1,MNA*
App. I + Det. plus
CAMP
1,4-Dioxane
Compliance/
Assessment/
App. I + Det. plus
MW-2R
4/12/94
Performance
CAMP
19.0
Saprolite
App. II, MNA
1,4-Dioxane,
MNA
Compliance/
Assessment/
App. I + Det. plus
MW-3R
4/14/94
Performance
CAMP
37.2
Bedrock
App. II, MNA
1,4-Dioxane,
MNA
MW-4
4/18/94
Compliance
Detection
31.5
Bedrock
App. I
App. I plus 1,4-
Dioxane
MW-S
4/18/94
Compliance
Detection
23.4
Saprolite
App. I
App. I plus 1,4-
Dioxane
MW-6
4/19/94
Compliance
Detection
31.7
Saprolite/
App I
App. I plus 1,4-
Bedrock
Dioxane
NES-1
11/14/07
Nature &
Sentinel
33.0
Saprolite/
COCs, MNA*
COCs
Extent
Bedrock
App. I = NCSWMR Appendix I list of constituents plus 1,4-Dioxane.
App. 11= NCSWMR Appendix II list of constituents plus 1,4-Dioxane.
App. I + Det. = App. I list plus detected App. II constituents. COCs = Constituents of Concern.
MNA = Monitored Natural Attenuation parameters. CAMP = Corrective Action Monitoring Plan.
Current Appendix II detected constituents: Tin.
Current COC: Benzene.
MNA Field Parameters: Temperature, pH, specific conductance, oxidation reduction
potential, turbidity, dissolved oxygen, and ferrous iron. Dissolved carbon dioxide will be
tested during both events every third year (next in 2019).
MNA Laboratory Parameters: Dissolved methane, alkalinity, sulfate, nitrate, chloride,
biological oxygen demand (BOD), chemical oxygen demand (COD), and total organic
carbon (TOC). Dissolved hydrogen, volatile fatty acids, sulfide, ethane and ethene are
analyzed during both events every third year (next in 2019).
*Note: MNA parameters are only required annually for MW-1R & NES-1.
2.2 Surface Water Monitoring Program
Two surface water samples have been collected semiannually since September 1994, at the
Butner Landfill. The surface water sample points SW-1 and SW-2 are located respectively
upstream and downstream of the facility, along an unnamed tributary of Picture Creek. The
surface water samples are analyzed for the NC Appendix I list of constituents plus 1,4-Dioxane
during both semiannual events.
August 2018 Semiannual Water Quality Monitoring Report Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 November 2018
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3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2018
3.1 Field Work
On August 13-15, 2018, Joyce Engineering (JOYCE) personnel visited the Butner Landfill to
purge and sample monitoring wells MW-1R, MW-2R, MW-3R, MW-4, MW-5, MW-6, and
NES-1. All monitoring wells were purged and sampled using new, disposable bailers. An
electronic water level meter was used to take the depth to water to 0.01 foot. Calculated
groundwater elevations can be found in Table 2. Measurements of temperature, pH, turbidity,
and conductivity were recorded in a field log. Additional field parameters (dissolved oxygen,
oxidation reduction potential and Ferrous Iron) were measured for MW-2R and MW-3R for this
sampling event and recorded in the field log. Prior to sampling, laboratory -supplied containers
were prepared with the following information:
• Monitoring well number (completed by laboratory/field personnel),
• Date and time of sample collection (completed by laboratory/field personnel),
• Initials of sampling personnel (completed by laboratory/field personnel),
• Project name and number (completed by the laboratory/field personnel),
• Chemical preservative (completed by the laboratory/field personnel); and
• Requested chemical analysis (completed by the laboratory/field personnel).
Groundwater samples from each monitoring well were collected directly from the bailers into the
provided laboratory containers, within 24 hours of the final purge volume. Immediately after
collection, the samples were placed in a laboratory provided cooler and preserved on ice. Field
Logs are provided in Appendix A and field parameters are summarized in Table 3.
Surface water points SW-1 and SW-2 were also sampled during the August 13-15, 2018, event.
Field Logs are included in Appendix A and field parameters are summarized in Table 3.
3.1.1 Resampling Field Work
On November 02, 2018, Joyce Engineering (JOYCE) personnel visited the Butner Landfill to
resample MW-2R. The monitoring well was purged and sampled with a peristaltic pump from
Pine Environmental. An electronic water level was used to take the depth to water to 0.01 foot.
Measurements of temperature, pH, turbidity, conductivity, Dissolved Oxygen and ORP were
recorded in the field log.
3.2 Laboratory Analyses and Quality Control
Pace Analytical Services, Inc. of Huntersville, North Carolina, analyzed the August 2018,
groundwater and surface water samples under chain -of -custody control. The groundwater
samples from MW-1R, MW-2R, and MW-3R were analyzed for the NC Appendix I list of
constituents and NC Appendix II detects plus 1,4-Dioxane. Additionally, samples from MW-2R
and MW-3R were analyzed for MNA parameters. The groundwater samples from MW-4, MW-
5, and MW-6 were analyzed for the NC Appendix I list of constituents plus 1,4-Dioxane. The
sample from sentinel well NES-1 was analyzed for the constituent of concern (benzene) only.
The surface water samples from SW-1 and SW-2 were analyzed for NC Appendix I constituents
plus 1,4- Dioxane. The samples were received by the laboratory on August 14, 2018 and August
August 2018 Semiannual Water Quality Monitoring Report
Granville County - Butner Landfill, Permit No. 39-02
Joyce Engineering
November 2018
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16, 2018 in good condition, properly preserved, at proper temperatures, and within analysis hold
times.
In addition to samples collected for compliance monitoring at the Butner Landfill, JOYCE
personnel collected a Field Blank for the August 2018 sampling event as part of the Quality
Control/Quality Assurance program. The Field Blank was analyzed for the NC Appendix I
constituents and NC Appendix II constituents plus 1,4-Dioxane. Also, a Trip Blank that was
prepared by the laboratory accompanied the volatile sampling containers to and from the
laboratory. The Trip Blank was analyzed for the Appendix I volatile organic compounds. The
complete laboratory analytical reports are included in Appendix B.
Upon receipt of the laboratory data package, JOYCE personnel reviewed the following data for:
• General typographical errors;
• Correct analyses performed and within method specified hold times;
• Biased data results based on Matrix Spike, Matrix Spike Duplicate, and Laboratory
Control Samples;
• Blank qualified data (B-flags);
• Detections above Groundwater Protection Standards (GPS) as defined in NCSWMR §
.1634(g), which are generally either the 15A NCAC 2L.0202 (NC2L) Groundwater
Standards or the NCDEQ Solid Waste Section (SWS) Groundwater Water Protection
Standards (GWPS);
• Detections above NC Surface Water Standards established in 15A NCAC 2B (NC2B);
and
• Detections that are above historical levels.
The complete laboratory analytical reports and the chains of custody from the August 2018 event
are included in Appendix B. The historical groundwater elevation data are presented in Appendix
C. Respectively, historical analytical results for groundwater and surface water are presented in
Appendices D and E.
3.2.1 Analyses for Resampling Event
The November 02, 2018, resample of MW-2R was submitted to Pace Analytical Services, Inc.
under chain -of custody control and was analyzed for total cobalt and dissolved cobalt. The same
analytical, quality -control, and data review protocols were followed for the resample. The
complete laboratory analytical report and the chain of custody from the November 2018 event
are included in Appendix B.
4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSES
4.1 Analytical Results for Groundwater and Comparisons to Standards
4.1.1 Inorganic Analyses
The following inorganic constituents were detected at quantified concentrations above the
method reporting limit (MRL) or practical quantitation limit (PQL) in one or more wells during
August 2018 Semiannual Water Quality Monitoring Report Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 November 2018
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the August 2018, sampling event: barium, cobalt, copper, and nickel. Table 4 summarizes all of
the detections from the August 2018 event.
Cobalt was the only inorganic constituent detected in exceedance of the GWPS in MW-2R and
MW-5. The result for cobalt in MW-5 is consistent with historical data; however, a resampling
event was conducted on November 02, 2018 to verify the exceedance for cobalt in MW-2R. The
results of the resampling event confirmed the exceedance. Exceedances of groundwater
standards from the August 2018 event are summarized in Table 5. A notification of detections
above the GPS was submitted to NCDEQ under separate cover.
No other inorganic constituents were detected above their GPS during the August 2018 sampling
event. The laboratory analytical reports and the chains of custody are included in Appendix B.
Complete historical analytical results for inorganic constituents are included in Appendix D.
4.1.2 Organic Anal
Benzene, chlorobenzene, 1,4-dioxane, and 1,4-dichlorobenzene were detected in one or more
monitoring wells at quantified concentrations above the MRL or PQL. Benzene and 1,4-dioxane
were detected above their respective NC2L standards. Table 4 summarizes all of the quantified
detections from the August 2018 event. These results (except for 1,4-dioxane) are consistent
with historical data as shown in Appendix D.
1,4-dioxane was detected in exceedance of the NC2L standard in MW, 2R, MW-3R, and MW-4.
Benzene was detected above the NC2L Standard in MW-2R. The benzene in MW-2R is
consistent with historical data and has been addressed in the ACM, approved in June 2013, and
the CAP, approved in June 2014. Exceedances of groundwater standards from the August 2018
event are summarized in Table 5. A notification of detections above the GPS was submitted to
NCDEQ under separate cover.
No other organic constituents were detected above their GPS during the August 2018 sampling
event. The laboratory analytical reports and the chains of custody are included in Appendix B.
Historical analytical results for organic constituents are presented in Appendix D.
4.2 Statistical Analyses
4.2.1 Statistical Methods
Monitoring well MW-1R is designated as the up -gradient background well for the facility. Data
from MW-1R between September 1994 and February 2018 have been used to determine
interwell statistical background concentrations for constituents detected at the facility.
Alternatively, intrawell statistical backgrounds for a downgradient well may be calculated using
data from a down -gradient well, excluding the 6-8 most recent sampling events.
The background data may be evaluated using the Shapiro -Wilk Test, Parametric Prediction
Limits, Parametric Tolerance Intervals, Aitchison's Adjustment, Non -Parametric Prediction
Limits, and Poisson Prediction Limits, as appropriate. Background data, tests for normality,
outliers, Aitchison's adjustment, tolerance interval, or prediction limits are used, as appropriate
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Granville County - Butner Landfill, Permit No. 39-02 November 2018
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based on the background data. The statistical test by which downgradient data are compared to
facility background data is based upon the nature of the data and the number of data values that
are less than the laboratory limit of detection. All statistical tests are evaluated at the 0.05 level
of significance, 95% confidence level, and are conducted as one -tailed tests. The data set was
evaluated to determine the appropriate procedure for calculation of the background value for
each parameter.
4.2.2 Results of Statistical Anal
Cobalt in MW-5 was the only inorganic constituents detected in exceedance of the GPS during
the August 2018 sampling event. No statistical analyses were performed for this sampling event.
4.3 Analytical Results for Surface Water and Comparisons to Standards
Surface water points SW-1 and SW-2 were sampled during the August 2018 sampling event. No
Appendix I organic or inorganic constituents were detected above the MRL or PQL during the
August 2018 sampling event; however, 1,4-dioxane was detected at a quantified concentration in
SW-2. There is no NC-213 surface water standard for 1,4-dioxane. Historical surface water data
are presented in Appendix E.
5.0 HYDROGEOLOGICAL CONDITIONS
Groundwater in the saprolite feeds the fractures in the bedrock and discharges into creeks
northeast of the landfill. Groundwater flow direction at deeper levels within the fractured
bedrock is controlled by fracture orientation.
Depth to groundwater was measured in the compliance monitoring wells at the site prior to
purging. The groundwater elevations were calculated relative to the surveyed measuring point
(top of casing) for each monitoring well. A groundwater surface contour map, developed with
static water level data obtained on August 13-15, 2018, is presented as Drawing 1. The static
water elevations depict groundwater flow to the southeast. The historical groundwater elevations
are summarized in Table 2.
Horizontal groundwater gradients along a representative flow path was estimated from the
August 2018 groundwater contours shown on Drawing I and are summarized in Table 6. The
average horizontal hydraulic gradient across the site was approximately 0.0479.
Linear groundwater flow velocities were computed using the modified Darcy equation:
Where:
V = Kiln,
V = average linear velocity (feet/year),
K = hydraulic conductivity (feet/day),
i = horizontal hydraulic gradient, and
ne = effective porosity.
August 2018 Semiannual Water Quality Monitoring Report Joyce Engineering
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The average of hydraulic conductivities (K = 2.18x10"05 cm/sec = 6.18x10-02 feet/day) from
single well aquifer test commonly known as slug -tests conducted in 1994 (GAI, 1994) was used
in these calculations. The average effective porosity (ne = 18%) based on 90% of reported total
porosity for soils (GAI, 1994), and ne = 10% for fractured bedrock were also used. Although the
regolith and bedrock are hydraulically connected, the effective porosity generally decreases with
depth into the underlying fractured bedrock. Groundwater flow direction beneath the landfill is
predominantly to the south and southeast. The calculated flow velocity was 6.01 ft/yr.
Because of our conservative estimate of effective porosity, actual groundwater velocities may be
significantly less than the calculated values. Also, the modified Darcy equation makes the
simplifying assumptions of a homogeneous and isotropic aquifer, which may not be accurate for
this site.
6.0 CORRECTIVE ACTION EVALUATION
6.1 Monitored Natural Attenuation Parameters
Wells MW-2R and MW-3R were analyzed for the following MNA parameters during the August
2018 sampling event:
MNA Field Parameters: Temperature, pH, conductivity, oxidation reduction potential,
turbidity, dissolved oxygen, and ferrous iron.
MNA Laboratory Parameters: Alkalinity, sulfide, sulfate, nitrate, chloride, biological
oxygen demand (BOD), chemical oxygen demand (COD), and total organic carbon
(TOC).
The current and historical MNA parameter data are presented in Table 7, and the laboratory
analytical report for MNA parameters for the August 2018 sampling event is included in
Appendix B. Based on response from NCSWMR to the first Corrective Action Evaluation
Report (CAER) submitted in December 2016, changes to the CAP were implemented starting
with the February 2017 event and the following parameters are now monitored during both
sampling events every third year: Dissolved carbon dioxide, dissolved hydrogen, sulfide,
volatile fatty acids, dissolved methane, ethene, and ethane. The next time these parameters will
be monitored will be in February 2019.
6.2 Phytoremediation
The sixth phytoremediation tree survey for the Butner Landfill was conducted on July 26, 2018
and the results are presented in Drawing 2. The results indicate that the flora in the remediation
zone remain healthy and are adequate to significantly remediate organic compounds in the
shallow groundwater. The CAP requires annual tree surveys and the next survey is scheduled for
summer 2019.
August 2018 Semiannual Water Quality Monitoring Report Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 November 2018
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6.3 Evaluation of Plume Stability and Trends
Chart 1 presents a plot of the benzene concentrations versus time in all monitoring wells where it
has been detected (MW-2R, MW-3R, and MW-4). There were no benzene detections prior to
December 2006; however, from December 2006 to present, benzene in MW-2R has fluctuated
between 1 µg/l and 2 µg/l and shows a slight downward trend and a possible seasonal fluctuation.
From December 2007 to present, benzene in MW-3R has fluctuated between 0.3 µg/l and 0.7
µg/l. Benzene in MW-4 has fluctuated between non -detect and 0.4 µg/l.
The benzene concentrations from the August 2018 are within the range of historical fluctuations.
Since there have been no detections of benzene in either the surface water or sentinel well
NES-1, there is no indication that the plume in migrating toward the property boundary. The
plume appears to be stable or decreasing.
Chart 2 presents a plot of the cobalt concentrations versus time in the monitoring wells where it
has been detected in exceedance of the GPS (MW-2R and MW-5). Cobalt in MW-2R has
ranged between no -detection and 38.0 µg/l, but has been consistently between 8.3 and 10.7 µg/1
since August 2014. Cobalt in MW-5 has fluctuated between no -detection and 251 µg/l, with
large fluctuations that appear to have a seasonal component (lower in winter and higher in
summer); however, there are inconsistencies (the highest historical concentration was in June
2002). There is no apparent increasing or decreasing trend for cobalt in either well.
7.0 CONCLUSIONS
The groundwater flow regime is consistent with previous events and the groundwater monitoring
network remains adequate to monitor the site.
Cobalt was detected in MW-2R and MW-5 above its corresponding GWPS. This exceedance is
consistent with historical detections. We recommend that cobalt be added to the constituents of
concern for this facility, and that we begin to sample the sentinel well, NES-1, for cobalt with the
next semiannual event.
Benzene was detected above the NC2L in MW-2R during the August 2018 sampling event.
Review of MNA parameter data, plume stability, and benzene trends indicate that the selected
remedies of natural attenuation and phytoremediation are adequately controlling the plume.
Samples from the facility compliance monitoring wells and surface water points were analyzed
for 1,4-dioxane for the first time during the August sampling event in response to the NCDEQ
memo dated May 2017, which mandated sampling for 1,4-dioxane at all landfills beginning July
1, 2018. 1,4-dioxane was detected above the NC2L standard in MW-2R, MW-3R, and MW-4.
It was also detected at an estimated concentration below the NC2L standard in MW-5.
1,4-dioxane was detected at a quantified concentration in SW-2; however, there is no NC-213
surface water standard for 1,4-dioxane.
1,4-dioxane is not a constituent required by the NCSWMR, so it is unclear what the appropriate
regulatory response to these detections should be. We recommend continuing to monitor
August 2018 Semiannual Water Quality Monitoring Report Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 November 2018
9

1,4-dioxane in the groundwater and surface water semiannually, and that we begin to sample the
sentinel well, NES-1, for 1,4-dioxane with the next semiannual event.
The next semiannual sampling event is tentatively scheduled for February 2019.
8.0 REFERENCES
GAI Consultants — NC, Inc. (GAI), 1994. Ground and Surface Water Monitoring System,
Granville County, Butner Landfill, NC Permit No. 39-02. June, 1994.
Joyce Engineering (JOYCE), 2013. Assessment of Corrective Action, Butner Landfill, Granville
County, Permit No. 39-02. May 2013.
Joyce Engineering (JOYCE), 2014. Corrective Action Plan, Butner Landfill, Granville Coun
Permit No. 39-02. May 2014.
Newell, Charles J., Ph.D., P.E., R. Kevin McLeod, and James R. Gonzales, 1996. BIOSCREEN
Natural Attenuation Decision Support System User's Manual, Version 1.3. United States
Environmental Protection Agency, Office of Research and Development, Washington
DC. EPA/600/R-96/087. August 1996.
Newell, Charles J., Ph.D., P.E., R. Kevin McLeod, and James R. Gonzales, 1997. BIOSCREEN
Natural Attenuation Decision Support System, Version 1.4 Revisions. United States
Environmental Protection Agency, Office of Research and Development, Washington
DC. July 1997.
North Carolina Department of Environment and Natural Resources (NC-DENR), 2011. North
Carolina Solid Waste Management Rules. 15 NCAC 13B. Amended April 2011.
NC-DENR, 2007. North Carolina Solid Waste Section Guidelines for Corrective Action at
Solid Waste Management Facilities. March 2007.
9.0 ACRONYMS
ACM Assessment of Corrective Measures (Report)
AOC Area of Concern
C&D Construction and Demolition Waste
CAP Corrective Action Plan (Report)
CAER Corrective Action Evaluation Report (Report)
COC Constituent of Concern
DENR See NCDENR
DL Detection Limit (for laboratory data)
DO Dissolved Oxygen
EPA United States Environmental Protection Agency
GPS Site -specific Groundwater Protection Standards per NCSWMR § 1634.g-h
GWPS Groundwater Protection Standards (established by DENR-SWS)
August 2018 Semiannual Water Quality Monitoring Report Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 November 2018
10

JOYCE Joyce Engineering
LFG Landfill Gas
MNA Monitored Natural Attenuation
MSW Municipal Solid Waste
NC2B North Carolina Surface Water Standards found in 15A NCAC 2B
NC2L North Carolina Groundwater Standards found in 15A NCAC 2L
NCAC North Carolina Administrative Code
NCDENR North Carolina Department of Environment and Natural Resources (now NCDEQ)
NCDEQ North Carolina Department of Environmental Quality (formerly NCDENR)
NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600)
ND Not Detected (for laboratory data)
NES Nature and Extent Study (Report)
O&M
Operations and Maintenance
QL
Quantitation Limit (for laboratory data)
QRA
Quantitative Risk Assessment (Report)
RL
Reporting Limit (for laboratory data)
SWQS
Surface Water Quality Standards
SWS
Solid Waste Section (of NCDENR/NCDEQ)
SWSL
North Carolina Solid Waste Section Reporting Limits
VOC
Volatile Organic Compound
WQMP
Water Quality Monitoring Plan (Report)
WQMR
Water Quality Monitoring Report (Report)
August 2018 Semiannual Water Quality Monitoring Report
Granville County - Butner Landfill, Permit No. 39-02
Joyce Engineering
November 2018
11

TABLES
Table 1 Monitoring Well Construction Data
Table 2 August 2018 Groundwater Elevations
Table 3 August 2018 Field Parameters
Table 4 Detected Constituents in Groundwater and Surface Water
Table 5 Exceedances of Groundwater Standards
Table 6 Hydraulic Gradients and Groundwater Flow Velocities
Table 7 Monitored Natural Attenuation Parameters

TABLE 1: Well Construction Details
WELL ID
5LOCATION
DEPTH in FEET from top of casing
Other Information
Permit #
Well #
Lat.
Long.
Surface
Top of
Top of
Bottom of
Total
'Water
Depth to
2Geologic
3Construction
Driller's
Comments
Elevation
Casing
Screen
Screen
Depth
Level
Bedrock
Unit
Date
Reg. #
Fractured
background well
39-02
MW-1 R
N36009' 55.49"
W78045' 37.80"
461.01
0.00
-41.00
-56.00
-56.00
-41.0
-30
4/21/1994
446
Bedrock
replacement
Weathered
compliance well
39-02
MW-2 R
N36009' 38.57"
W78045' 34.97"
326.60
+2.34
-3.85
-18.85
-18.85
-2.6
-13
4/12/1994
446
Bedrock
replacement
Fractured
compliance well
39-02
MW-3 R
N36009' 38.58"
W78045' 34.85"
328.77
+2.18
-25.83
-35.83
-35.83
-3.0
-13
4/14/1994
446
Bedrock
replacement
Fractured
39-02
MW-4
N36009' 38.93"
W78045' 30.15"
338.97
+1.95
-16.43
-31.43
-31.43
-9.8
-13
4/18/1994
446
compliance well
Bedrock
Fractured
39-02
MW-5
N36009' 39.35"
W78045' 23.77"
341.88
+2.12
-8.52
-23.52
-23.52
-12.8
-17
4/18/1994
446
compliance well
Bedrock
Fractured
39-02
MW-6
N360 09' 47.00"
W780 45' 25.47"
360.80
+2.00
-17.63
-32.63
-32.63
-11.7
_21.2
4/19/1994
446
compliance well
Bedrock
Fractured
nature & extent
39-02
NES-1
N360 09' 35.65"
W780 45131.5911
326.22
+2.5
-15
-30.0
-30.0
-22
_26
11/14/2007
2675
I
I
1
I
1
1
Bedrock
study well
Notes:
Water Level from TOC, approx. 24 hours after drilling.
Geology where well bore ends, documented as fractured metavolcanic bedrock of Carolina slate belt.
Typical Montoring Well Construction, materials are 2 inch SCH40 PVC casing and screen with 0.010 inch slot, sand pack, bentonite seal, grout pad, & steel outer casing.
Montoring Well Summary data is from well construction records, GAI Consultants June 1994, & Joyce Engineering November 2007 and field observations.
Locations and elevations from March 2013 survey.
Butner Landfill, Granville County Joyce Engineering
Permit # 39-02 December 2018

TABLE 2: August 2018 Groundwater Elevations
Location
�LIL
TOC Elevation
(Ft AMSL)
Depth to
Groundwater
(Ft BTOC)
Lithology
Well Depth
(Ft BTOC)
Groundwater
Elevation
(Ft AMSL)
MW-1R
8/13/2018
460.51
44.65
Bedrock
56
415.86
Alluvial/
MW-2R
8/13/2018
331.60
2.64
18.85
328.96
Residual
MW-3R
8/13/2018
330.96
3.00
Saprolite
35.83
327.96
MW-4
8/13/2018
340.80
8.83
Bedrock
31.43
331.97
MW-5
8/13/2018
343.88
14.20
Saprolite
23.52
329.68
MW-6
8/14/2018
362.53
12.41
Bedrock
32.63
350.12
NES-1
8/14/2018
328.40
15.89
Bedrock
32.8
312.51
Notes:
Butner Landfill, Granville County
Permit # 39-2
TOC = Top of casing
Ft = feet
BTOC = Below TOC AMSL = Above mean sea level
BGS = Below ground surface
Joyce Engineering
December 2018

TABLE 3: August 2018 Field Parameters
WELL ID
PARAMETER
RESULT
UNITS
SAMPLE DATE
3902-MW 1R
pH
6.30
S.U.
8/13/2018
3902-MWIR
Temperature
17.4
°C
8/13/2018
3902-MWIR
Conductivity
101.2
µS/cm
8/13/2018
3902-MWIR
Turbidity
13.43
NTU
8/13/2018
3902-MWIR
Dissolved Oxygen
6.31
mg/l
8/13/2018
3902-MWIR
Ferrous Iron
0.0
mg/l
8/13/2018
3902-MWIR
Oxidation Reduction Potential
117.9
my
8/13/2018
3902-MWIR
Static Water Level
44.65
ft
8/13/2018
3902-MWIR
Well Depth
56.00
ft
8/13/2018
3902-MW2R
pH
6.45
S.U.
8/13/2018
3902-MW2R
Temperature
21.1
°C
8/13/2018
3902-MW2R
Conductivity
2,013
µS/cm
8/13/2018
3902-MW2R
Turbidity
4.22
NTU
8/13/2018
3902-MW2R
Dissolved Oxygen
3.20
mg/l
8/13/2018
3902-MW2R
Ferrous Iron
5.5
mg/l
8/13/2018
3902-MW2R
Oxidation Reduction Potential
-60.5
mV
8/13/2018
3902-MW2R
Static Water Level
2.64
ft
8/13/2018
3902-MW2R
Well Depth
18.85
ft
8/13/2018
3902-MW2R*
pH
6.33
S.U.
11/2/2018
3902-MW2R*
Temperature
18.5
°C
11/2/2018
3902-MW2R*
Conductivity
1,808
µS/cm
11/2/2018
3902-MW2R*
Turbidity
2.75
NTU
11/2/2018
3902-MW2R*
Dissolved Oxygen
1.16
mg/1
11/2/2018
3902-MW2R*
Oxidation Reduction Potential
-180.1
mV
11/2/2018
3902-MW2R*
Static Water Level
2.35
ft
11/2/2018
3902-MW2R*
Well Depth
18.85
ft
11/2/2018
3902-MW3R
pH
6.64
S.U.
8/13/2018
3902-MW3R
Temperature
18.2
°C
8/13/2018
3902-MW3R
Conductivity
1,608
µS/cm
8/13/2018
3902-MW3R
Turbidity
0.00
NTU
8/13/2018
3902-MW3R
Dissolved Oxygen
2.35
mg/l
8/13/2018
3902-MW3R
Ferrous Iron
0.2
mg/1
8/13/2018
3902-MW3R
Oxidation Reduction Potential
-49.3
mV
8/13/2018
3902-MW3R
Static Water Level
3.00
ft
8/13/2018
3902-MW3R
Well Depth
35.83
ft
8/13/2018
3902-MW4
pH
6.38
S.U.
8/13/2018
3902-MW4
Temperature
19.3
°C
8/13/2018
3902-MW4
Conductivity
1,569
µS/cm
8/13/2018
3902-MW4
Turbidity
4.14
NTU
8/13/2018
3902-MW4
Static Water Level
8.83
ft
8/13/2018
3902-MW4
Well Depth
31.43
ft
8/13/2018
Butner Landfill, Granville Co.
Permit No. 39-02
1 of 2
Joyce Engineering
December 2018

TABLE 3: August 2018 Field Parameters
WELL ID
PARAMETER
RESULT
UNITS
SAMPLE DATE
3902-MW5
pH
7.15
S.U.
8/13/2018
3902-MW5
Temperature
20.6
°C
8/13/2018
3902-MW5
Conductivity
870.0
µS/cm
8/13/2018
3902-MW5
Turbidity
103
NTU
8/13/2018
3902-MW5
Dissolved Oxygen
NM
mg/l
8/13/2018
3902-MW5
Ferrous Iron
NM
mg/l
8/13/2018
3902-MW5
Oxidation Reduction Potential
NM
my
8/13/2018
3902-MW5
Static Water Level
14.20
ft
8/13/2018
3902-MW5
Well Depth
23.52
ft
8/13/2018
3902-MW6
pH
7.03
S.U.
8/14/2018
3902-MW6
Temperature
18.4
°C
8/14/2018
3902-MW6
Conductivity
620
µS/cm
8/14/2018
3902-MW6
Turbidity
0.64
NTU
8/14/2018
3902-MW6
Static Water Level
12.41
ft
8/14/2018
3902-MW6
Well Depth
32.63
ft
8/14/2018
3902-NES 1
pH
5.54
S.U.
8/14/2018
3902-NES 1
Temperature
16.6
°C
8/14/2018
3902-NES1
Conductivity
131.2
µS/cm
8/14/2018
3902-NES1
Turbidity
30.20
NTU
8/14/2018
3902-NES1
Dissolved Oxygen
3.91
mg/1
8/14/2018
3902-NES1
Ferrous Iron
NM
mg/1
8/14/2018
3902-NES1
Oxidation Reduction Potential
28.4
my
8/14/2018
3902-NES1
Static Water Level
15.89
ft
8/14/2018
3902-NES1
Well Depth
36.10
ft
8/14/2018
3902-SW 1
pH
6.60
S.U.
8/13/2018
3902-SW 1
Temperature
23.8
°C
8/13/2018
3902-SW1
Conductivity
269
µS/cm
8/13/2018
3902-SW1
Turbidity
5.65
NTU
8/13/2018
3902-SW2
pH
7.53
S.U.
8/14/2018
3902-SW2
Temperature
23.1
°C
8/14/2018
3902-SW2
Conductivity
849
µS/cm
8/14/2018
3902-SW2
Turbidity
7.25
NTU
8/14/2018
Units: °C = degrees Centigrade
S.U. =
Standard Units
µS/cm
= micro-Seimens per centimeter
NTU =
Nephelometric Turbidity Units
my = milivolts
mg/l =
miligrams per liter
*RESAMPLE 11/2/2018
Butner Landfill, Granville Co.
Permit No. 39-02
2 of 2
Joyce Engineering
December 2018

TABLE 4: Detected Constituents in Groundwater and Surface Water
SAMPLE
GPS:
SAMPLE
PARAMETER
RESULT
UNITS
MDL
MRL
ID
NC2L/*GWPS/NC2B
DATE
3902-MW1R
Barium
3.8 J
µg/l
2.5
100
700
8/13/2018
3902-MW2R
1,2-Dichlorobenzene
1.2 J
µg/l
0.30
5.0
20
8/13/2018
3902-MW2R
1,4-Dichlorobenzene
1.9
µg/l
0.33
1.0
6
8/13/2018
3902-MW2R
1,4-Dioxane (p-Dioxane)
88.0
µg/1
1.9
2.0
3
8/13/2018
3902-MW2R
Arsenic
5.4 J
µg/l
5.0
10.0
10
8/13/2018
3902-MW2R
Barium
116
µg/l
2.5
100
700
8/13/2018
3902-MW2R
Benzene
1.3
µg/1
0.25
1.0
1
8/13/2018
3902-MW2R
Chlorobenzene
14.5
µg/l
0.23
3.0
50
8/13/2018
3902-MW2R
Chloroethane
1.2 J
µg/1
0.54
10.0
3000
8/13/2018
3902-MW2R
Cobalt
10.7
µg/l
2.5
10.0
1*
8/13/2018
3902-MW2R+
Cobalt
10.0
µg/l
2.5
10.0
1*
11/2/2018
3902-MW2R
Copper
5.5 J
µg/l
2.5
10.0
1000
8/13/2018
3902-MW2R
Nickel
88.9
µg/l
2.5
50.0
100
8/13/2018
3902-MW2R
Tin
22.2 J
µg/l
2.5
100
2000*
8/13/2018
3902-MW2R
Vanadium
5.3 J
µg/l
2.5
25.0
0.3*
8/13/2018
3902-MW3R
1,2-Dichlorobenzene
1.6 J
µg/l
0.30
5.0
20
8/13/2018
3902-MW3R
1,4-Dichlorobenzene
1.1
µg/l
0.33
1.0
6
8/13/2018
3902-MW3R
1,4-Dioxane (p-Dioxane)
53.1
µg/1
1.9
2.0
3
8/13/2018
3902-MW3R
Barium
67.6 J
µg/l
2.5
100
700
8/13/2018
3902-MW3R
Benzene
0.61 J
µg/l
0.25
1.0
1 *
8/13/2018
3902-MW3R
Chlorobenzene
22.2
µg/l
0.23
3.0
50
8/13/2018
3902-MW3R
Chloroethane
2.4 J
µg/l
0.54
10.0
3000
8/13/2018
3902-MW3R
Copper
12.2
µg/l
2.5
10.00
1000
8/13/2018
3902-MW3R
Nickel
29.0 J
µg/l
2.5
50.00
100
8/13/2018
3902-MW3R
Tin
7.4 J
µg/l
2.5
100
2000*
8/13/2018
3902-MW3R
Vinyl chloride
0.72 J
µg/l
0.62
1.0
0.03
8/13/2018
3902-MW4
1, 1 -Dichloroethane
0.37 J
µg/l
0.32
5.0
6
8/13/2018
3902-MW4
1,4-Dioxane (p-Dioxane)
40.7
µg/1
1.9
2.0
3
8/13/2018
3902-MW4
Benzene
0.29 J
µg/l
0.25
1.0
1
8/13/2018
3902-MW4
Chlorobenzene
3.4
µg/l
0.23
3.0
50
8/13/2018
3902-MW4
Chloroethane
1.4 J
µg/l
0.54
10.0
3000
8/13/2018
3902-MW4
Copper
3.7 J
µg/l
2.5
10.0
1000
8/13/2018
3902-MW4
Nickel
12.3 J
µg/l
2.5
50.0
100
8/13/2018
3902-MW4
Vanadium
20.4 J
µg/1
2.5
25.0
0.3*
8/13/2018
Butner Landfill, Granville Co. Joyce Engineering
Permit No. 39-02 1 Of 2 December 2018

TABLE 4: Detected Constituents in Groundwater and Surface Water
SAMPLE
GPS:
SAMPLE
PARAMETER
RESULT
UNITS
MDL
MRL
ID
Mj I
NC2L/*GWPS/NC2B
DATE
3902-MW5
1,4-Dioxane (p-Dioxane)
2.0 J
µg/1
1.9
2.0
3
8/13/2018
3902-MW5
Barium
103
µg/1
2.5
100
700
8/13/2018
3902-MW5
Cobalt
97.7
µg/1
2.5
10.0
1*
8/13/2018
3902-MW5
Copper
48.8
µg/l
2.5
10.0
1000
8/13/2018
3902-MW5
Lead
4.6 J
µg/l
2.5
10.0
15
8/13/2018
3902-MW5
Nickel
21.9 J
µg/1
2.5
50.0
100
8/13/2018
3902-MW5
Thallium
0.037 J
µg/l
0.02
5.5
0.28*
8/13/2018
3902-MW5
Toluene
0.44 J
µg/l
0.26
1.0
600
8/13/2018
3902-MW5
Vanadium
2.9 J
µg/l
2.5
25.00
0.3*
8/13/2018
3902-MW5
Zinc
8.1 J
µg/l
5.0
10.0
1000
8/13/2018
3902-SW1
Barium
70.0 J
µg/l
2.5
100
NS
8/13/2018
3902-SW1
Chromium
5.9 J
µg/l
2.5
10.0
23.81
8/13/2018
3902-SW1
Cobalt
6.0 J
µg/l
2.5
10.0
NS
8/13/2018
3902-SW1
Copper
4.1 J
µg/l
2.5
10.0
2.74
8/13/2018
3902-SW1
Nickel
7.3 J
µg/l
2.5
50.0
144.92
8/13/2018
3902-SW1
Vanadium
8.3 J
µg/l
2.5
25.0
NS
8/13/2018
3902-SW1
Zinc
6.0 J
µg/l
5.0
10.0
36.2
8/13/2018
3902-SW2
1,4-Dioxane (p-Dioxane)
14.1
µg/l
1.9
2.0
NS
8/13/2018
3902-SW2
Barium
86.6 J
µg/l
2.5
100
NS
8/13/2018
3902-SW2
Nickel
12.4 J
µg/l
2.5
50.0
144.92
8/13/2018
3902-SW2
Vanadium
3.1 J
µg/l
2.5
25.0
NS
8/13/2018
NOTES: All Results in micorgrams per liter (µg/l).
GPS = Groundwater Protection Standards (either NC2L or GWPS):
NC2L = NC Groundwater Standard from 15A NCAC 2L.0202.
*GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L).
NC2B = NC Surface Water Standard from 15A NCAC 2B (lowest of the Aquatic Life or Fish Consumption Standards).
For most metals, the NC2B is dependant on hardness. A hardness of 25 mg/l is assumed in the absense of hardness data.
NS = No standard established.
MDL = Method Detection Level.
MRL = Method Reporting Limit.
NA= Not applicable.
J = Estimated concentration below the MRL.
Bold = GPS Exceedance.
+RESAMPLE 11/2/2018.
Butner Landfill, Granville Co. Joyce Engineering
Permit No. 39-02 2 of 2 December 2018

TABLE 5: Exceedances of Groundwater Standards
WELL
GPS:
SAMPLE
PARAMETER
RESULT
UNITS
MDL
MRL
ID
NC2L/*GWPS
DATE
3902-MW2R
1,4-Dioxane (p-Dioxane)
88.0
µg/l
1.9
2.0
3
8/13/2018
3902-MW2R
Benzene
1.3
µg/l
0.25
1.0
1
8/13/2018
3902-MW2R
Cobalt
10.7
µg/l
2.5
10.0
1*
8/13/2018
3902-MW2R+
Cobalt
10.0
µg/l
2.5
10.0
1 *
11/2/2018
3902-MW3R
1,4-Dioxane (p-Dioxane)
53.1
µg/l
1.9
2.0
3
8/13/2018
3902-MW4
1,4-Dioxane (p-Dioxane)
40.7
µg/l
1.9
2.0
3
8/13/2018
3902-MW5
Cobalt
97.7
µg/l
2.5
10.0
1*
8/13/2018
NOTES: All Results in micorgrams per liter (µg/l).
GPS = Groundwater Protection Standards (either NC2L or GWPS):
NC2L = NC Groundwater Standard from 15A NCAC 2L.0202.
*GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L).
MDL = Method Detection Limit.
MRL = Method Reporting Limit.
Bold = GPS Exceedance.
+RESAMPLE 11/2/2018.
Joyce Engineering
Butner Landfill, Granville Co. December 2018
Permit No. 39-02

TABLE 6: Estimated Hydraulic Gradients and Groundwater Flow Velocities
Based on Water Level Data obtained on: August 13, 2018
GROUND-
HORIZ.
HYDRAULIC
EFFECTIVE
LINEAR
GRADIENT
FLOW LINE
FLOW
WATER
GRADIENT
CONDUCTIVITY
POROSITY
VELOCITY
CALCULATION
LENGTH
DIRECTION
ELEVATION
i
K
n e
V
SEGMENT
(feet)
(feet)
(ft/day)
(ft/year)
0
41410
l 1
1878
SE
0.0479
6.18E-02
0.18
6.01
32
Notes:
Hydraulic conductivity (K) value is the average of results from slug -tests conducted in 1994 (GAI, 1994).
Effective Porosity (n e) based on average of 90% of reported Total Porosity (GAI, 1995) for site soils.
Linear flow velocity: V = Kiln e (modified Darcy equation).
See Drawing 1 for Flow Segments.
Granville County Joyce Engineering
Butner Landfill, Permit No. 39-02 December 2018

TABLE 7: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Temperature
12/30/03
°C
- -
15.4
11.1 11.2 12.5 13.6 14.2
-
(FP)
12/19/07
°C
- -
12.3
12.5 13.1 14.4 14.9 14.4
13.3
05/01/13
°C
- -
15.7
13.7 15.1 14.4 14.2 14.2
12.5
08/14/14
°C
- -
17.8
18.0 19.2 19.4 16.8 17.2
16.0
03/10/15
°C
- -
17.3
16.0 15.9 13.8 13.3 13.7
16.1
08/18/15
°C
- -
16.43
17.78 17.79 17.25 16.47 16.64
16.05
02/16/16
°C
- -
14.6
13.8 14.4 14.0 12.0 13.4
13.1
08/09/16
°C
- -
16.4
17.3 19.4 18.2 17.1 16.8
17.9
02/13/17
°C
- -
14.8
14.4 14.9 15.7 14.1 15.3
15.2
08/22/17
°C
- -
17.4
17.9 17.9 17.5 17.4 16.6
17.8
02/05/18
°C
- -
13.06
11.66 13.05 14.46 13.83 14.53
12.25
08/13/18
°C
- -
17.4
21.1 18.2 19.3 20.6 18.4
16.6
pH
12/30/03
SU
- -
7.31
6.54 6.81 6.90 7.24 7.29
-
(FP)
12/19/07
SU
- -
6.89
6.90 7.07 6.87 7.39 6.67
7.64
05/01/13
SU
- -
7.32
6.37 6.61 6.42 6.92 7.13
6.10
08/14/14
SU
- -
5.84
6.36 6.96 6.79 7.00 6.48
5.59
03/10/15
SU
- -
6.11
6.37 6.56 6.30 6.25 6.55
5.68
08/18/15
SU
- -
5.12
6.68 6.48 6.76 7.03 6.78
4.94
02/16/16
SU
- -
6.15
6.15 6.61 6.69 7.14 6.10
6.52
08/09/16
SU
- -
4.79
5.05 5.30 5.06 4.41 5.75
6.46
02/13/17
SU
- -
6.10
6.55 6.76 6.78 6.24 7.37
6.23
08/22/17
SU
- -
6.58
6.46 6.45 6.98 7.53 7.16
7.16
02/05/18
SU
- -
7.11
6.80 7.01 7.33 7.22 7.54
5.53
08/13/18
SU
- -
6.30
6.45 6.64 6.38 7.15 7.03
5.54
Conductivity
12/19/07
µS/cm
- -
96
1,964 1,591 1,245 - -
510
(FP)
05/01/13
µS/cm
- -
111
1,587 1,357 1,150 195 594
69.6
08/14/14
µS/cm
- -
231
1,897 1,534 1,413 522 565
172.6
03/10/15
µS/cm
- -
90
996 1,277 1,186 106 504
114
08/18/15
µS/cm
- -
134
1,630 1,680 1,244 617 534
83
02/16/16
µS/cm
- -
72.4
1,611 1,369 1,234 164 474
78.2
08/09/16
µ6/cm
- -
100.7
1,924 1,535 1,475 660 600
95.6
02/13/17
µS/cm
- -
68.0
1,535 1,314 1,155 272 508
89.6
08/22/17
µ6/cm
- -
77.1
1,752 1,350 1,446 755 560
175
02/05/18
µS/cm
- -
80.0
1,460 1,247 1,230 676 633
50.0
08/13/18
µ6/cm
- -
101.2
2,013 1,608 1,569 870 620
131.2
Redox Potential
12/30/03
my
- -
257.2
76.2 207.6 212.7 187.3 123.6
-
ORP
12/19/07
my
- -
146
45.0 142 134 - -
138
(FP)
05/01/13
my
- -
111.7
-26.7 55.2 120.5 - -
227.1
08/14/14
my
- -
115.8
-37.2 86.9 - - -
-
03/10/15
my
- -
87.0
0.8 56.3 - - -
96.7
08/18/15
my
- -
134.7
-96.3 -68.8 -33.9 -49.9 -
182.8
02/16/16
my
- -
111.7
-47.3 16.9 NS NS -
173.4
08/09/16
my
- -
56.0
-43.1 -6.9 NS NS NS
NS
02/13/17
my
- -
87.4
0.8 -16.5 NS NS NS
NS
08/22/17
my
- -
102.9
-37.1 87.0 NS NS NS
116.7
02/05/18
my
- -
57.1
29.5 49.4 NS NS NS
109.2
08/13/18
my
- -
117.9
-60.5 -49.3 NS NS 64.4
28.4
Dissolved Oxygen
12/30/03
mg/L
- -
9.49
4.84 26.19 24.19 15.31 20.17
-
DO
12/19/07
mg/L
- -
-
1.88 1.44 3.21 - -
0.70
(FP)
05/01/13
mg/L
- -
4.40
1.37 1.79 4.65 - -
2.90
08/14/14
mg/L
- -
4.44
3.26 2.48 - - -
2.80
03/10/15
mg/L
- -
3.84
1.47 1.80 - - -
1.85
08/18/15
mg/L
- -
4.95
5.75 1.30 - 3.79 -
1.77
02/16/16
mg/L
- -
4.45
3.66 2.51 - - -
3.72
08/09/16
mg/L
- -
3.17
2.87 2.29 NS NS NS
NS
02/13/17
mg/L
- -
5.37
3.16 2.14 NS NS NS
NS
08/22/17
mg/L
- -
5.43
2.24 4.02 NS NS NS
5.86
02/05/18
mg/L
- -
8.08
6.61 9.16 NS NS NS
8.36
08/13/18
mg/L
- -
6.31
3.20 2.35 NS NS 4.80
3.91
Butner Landfill, Granville Co.
Permit No. 39-02
Page 1 of 5
Joyce Engineering
December 2018

TABLE 7: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Dissolved CO2
12/19/07
mg/L
-
-
25
365
175
295
-
-
60
(FP)
05/01/13
mg/L
-
-
30.0
245
125
225
-
-
45
08/14/14
mg/L
-
-
60.0
390
185
-
-
-
75
03/10/15
mg/L
-
-
50.0
110
75
-
-
-
50
08/18/15
mg/L
-
-
30.0
275
125
-
-
-
60
02/16/16
mg/L
-
-
30.0
210
230
-
-
-
20
08/09/16
mg/L
-
-
NS
185
210
NS
NS
NS
NS
02/13/17
mg/L
-
-
NS
NS
NS
NS
NS
NS
NS
08/22/17
mg/L
-
-
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
-
-
NS
NS
NS
NS
NS
NS
NS
08/13/18
mg/L
-
-
NS
NS
NS
NS
NS
NS
NS
Fe, Ferrous (+2)
12/30/03
mg/L
-
-
ND
1.5
ND
ND
0.22
ND
-
(FP)
12/ 19/07
mg/L
-
-
ND
7.2
ND
ND
-
-
0.2
05/01/13
mg/L
-
-
0.0
1.0
0.0
0.0
-
-
0.0
08/14/14
mg/L
-
-
0.0
2.5
0.0
-
-
-
0.0
03/10/15
mg/L
-
-
0.0
5.3
0.0
-
-
-
0.0
08/18/15
mg/L
-
-
0.0
4.5
1.0
-
-
-
0.0
02/16/16
mg/L
-
-
0.0
4.0
1.3
-
-
-
0.0
08/09/16
mg/L
-
-
NS
3.1
1.0
NS
NS
NS
NS
02/13/17
mg/L
-
-
0.0
3.0
1.5
NS
NS
NS
NS
08/22/17
mg/L
-
-
0.0
3.5
1.5
NS
NS
NS
0.0
02/05/18
mg/L
-
-
0.0
4.0
0.5
NS
NS
NS
0.0
08/13/18
mg/L
-
-
0.0
5.5
0.2
NS
NS
NS
NS
Alkalinity (as CaCO3)
12/30/03
mg/L
9.00
10.0
37.0
800
690
640
68.0
350
-
12/19/07
mg/L
-
5.00
39.0
763
726
619
-
-
190
05/01/13
mg/L
1.00
5.00
43.4
757
660
645
-
-
10.4
08/14/14
mg/L
1.00
5.00
41.1
784
661
-
-
-
14.5
03/10/15
mg/L
1.00
5.00
38.0
744
653
-
-
-
8.8
08/18/15
mg/L
1.00
5.00
37.8
772
664
-
-
-
10.3
02/16/16
mg/L
1.00
5.00
41.2
792
741
-
-
-
8.73
08/09/16
mg/L
1.00
5.00
-
783
629
-
-
-
-
02/13/17
mg/L
1.00
5.00
37.9
753
654
NS
NS
NS
8.79
08/22/17
mg/L
1.00
5.00
42.4
766
678
NS
NS
NS
10.20
02/05/18
mg/L
1.00
5.00
44.4
821
752
NS
NS
NS
7.52
08/13/18
mg/L
1.00
5.00
NS
768
722
NS
NS
NS
NS
Chloride
12/30/03
mg/L
0.200
1.00
3.50
280
170
82.0
13.0
44.0
-
12/19/07
mg/L
-
5.00
ND
13.1
297
89.1
-
-
7.90
NC 2L = 250,000 µg/L
05/01/13
mg/L
0.50
1.00
3.54
258
180
123
-
-
2.85
(250 mg/L)
08/14/14
mg/L
0.50
1.00
5.53
264
144
-
-
-
5.00
03/10/15
mg/L
0.50
1.00
3.80
266
194
-
-
-
4.09
08/18/15
mg/L
0.50
1.00
4.69
267
178
-
-
-
3.90
02/16/16
mg/L
0.50
1.00
3.92
274
186
-
-
-
3.24
08/09/16
mg/L
0.50
1.00
-
269
191
-
-
-
-
02/13/17
mg/L
0.50
1.00
3.45
309
215
NS
NS
NS
5.09
08/22/17
mg/L
0.50
1.00
3.73
318
214
NS
NS
NS
5.86
02/05/18
mg/L
0.50
1.00
3.92
280
205
NS
NS
NS
2.52
08/13/18
mg/L
0.50
1.00
NS
221
165
NS
NS
NS
NS
Dissolved Hydrogen
05/01/13
nM
0.074
0.60
0.400
0.630
0.610
0.500
-
-
0.470
08/14/14
nM
0.13
0.60
1.4
1.6
5.4
-
-
-
1.4
03/10/15
nM
0.13
0.60
1.2
1.4
1.4
1.0
-
-
1.4
08/18/15
nM
0.13
0.60
1.7
2.2
1.7
-
-
-
1.5
02/16/16
nM
0.13
0.60
2.0
1.7
1.9
-
-
-
1.5
08/09/16
nM
0.13
0.60
-
1.5
1.6
-
-
-
-
02/13/17
nM
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/22/17
nM
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
nM
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/13/18
nM
NS
NS
NS
NS
NS
NS
NS
NS
NS
Butner Landfill, Granville Co.
Permit No. 39-02
Page 2 of 5
Joyce Engineering
December 2018

TABLE 7: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL
RL i
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Nitrate-N
12/30/03
mg/L
0.0200
0.0500
0.120
ND
ND
ND
ND
0.13
-
12/19/07
mg/L
-
0.100
ND
ND
ND
ND
-
-
13.0
05/01/13
mg/L
0.001
10.0
0.163
ND
ND
ND
-
-
3.58
08/14/14
mg/L
0.001
10.0
0.115 J
ND
ND
-
-
-
2.02 J
03/10/15
mg/L
0.001
10.0
0.252 J
ND
ND
-
-
-
2.56 J
08/18/15
mg/L
0.001
10.0
0.124 J
ND
ND
-
-
-
3.27 J
02/16/16
mg/L
0.001
10.0
0.36 J
ND
ND
-
-
-
2.54 J
08/09/16
mg/L
0.001
10.0
-
ND
ND
-
-
-
-
02/13/17
mg/L
0.001
10.0
0.248 J
0.189 J
ND
NS
NS
NS
2.63 J
08/22/17
mg/L
0.001
10.0
0.118 J
0.0186 J
0.0451 J
NS
NS
NS
4.06 J
02/05/18
mg/L
0.010
10.0
0.310 J
ND
0.0120 J
NS
NS
NS
1.15 J
08/13/18
mg/L
0.050
0.1
NS
ND
ND
NS
NS
NS
NS
Sulfate
12/30/03
mg/L
0.0600
2.00
ND
ND
ND
2.60
9.60
9.00
-
12/19/07
mg/L
-
5.00
ND
ND
ND
ND
-
-
36.8
NC 2L = 250,000 µg/L
05/01/13
mg/L
1.00
250
ND
ND
ND
4.69
-
-
10.7
(250 mg/L)
08/14/14
mg/L
1.00
250
1.08 J
1.2 J
ND
-
-
-
5.84 J
03/10/15
mg/L
1.00
250
1.52 J
1.13 J
1.52 J
-
-
-
7.04 J
08/18/15
mg/L
1.00
250
1.56 J
1.31 J
2.49 J
-
-
-
524 J
02/16/16
mg/L
1.0
250
1.5 J
1.7 J
1.8 J
-
-
-
10.0 J
08/09/16
mg/L
1.00
250
-
1.22 J
1.75 J
-
-
-
-
02/13/17
mg/L
1.00
250
1.53 J
1.59 J
1.78 J
NS
NS
NS
11.9 J
08/22/17
mg/L
1.00
250
ND
ND
0.626 J
NS
NS
NS
11.2 J
02/05/18
mg/L
0.500
250
ND
ND
0.627 J
NS
NS
NS
7.48 J
08/13/18
mg/L
0.500
250
ND
ND
0.630 J
NS
NS
NS
NS
Sulfide
08/14/14
mg/L
0.05
1.00
ND
ND
ND
-
-
-
ND
03/10/15
mg/L
0.05
1.00
ND
ND
ND
-
-
-
ND
08/18/15
mg/L
0.05
1.00
ND
ND
ND
-
-
-
1.0
02/16/16
mg/L
0.05
1.00
ND
ND
ND
-
-
-
ND
08/09/16
mg/L
0.05
1.00
-
ND
ND
-
-
-
-
02/13/17
mg/L
0.05
1.00
ND
ND
ND
NS
NS
NS
NS
08/22/17
mg/L
0.05
1.00
ND
ND
ND
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
Total Organic Carbon
12/19/07
mg/L
-
1.0 *
2.9
54.3
23.2
17.2
-
-
7.20
05/01/13
mg/L
0.50
1.00
2.24
29.5
30.0
19.4
-
-
5.74
08/14/14
mg/L
0.50
1.00
ND
229.00
25.5
-
-
-
8.39
03/10/15
mg/L
0.50
1.00
0.781J
34.8
9.5
-
-
-
1.88
08/18/15
mg/L
0.50
1.00
0.917J
32.9
9.86
-
-
-
27.80
02/16/16
mg/L
0.50
1.00
1.500
27.6
8.46
-
-
-
40.90
08/09/16
mg/L
0.50
1.00
-
29.4
9.53
-
-
-
-
02/13/17
mg/L
0.50
1.00
ND
28.5
9.72
NS
NS
NS
1.36
08/22/17
mg/L
0.50
1.00
ND
29.1
9.92
NS
NS
NS
1.71
02/05/18
mg/L
0.50
1.00
ND
25.9
11.4
NS
NS
NS
4.24
08/13/18
mg/L
0.50
1.00
ND
25.8
10.2
NS
NS
NS
NS
Biochemical Oxygen Demand
08/14/14
mg/L
2.00
2.00
ND
83.4
2.49
-
-
-
-
BOD
03/10/15
mg/L
2.00
2.00
2.55
10.6
ND
-
-
-
ND
08/18/15
mg/L
2.00
2.00
2.22
11.8
2.0
-
-
-
2.00
02/16/16
mg/L
2.00
2.00
ND
60.0
6.6
-
-
-
ND
08/09/16
mg/L
2.00
2.00
-
11.6
ND
-
-
-
-
02/13/17
mg/L
2.00
2.00
ND
9.50 J
ND
NS
NS
NS
ND
08/22/17
mg/L
2.00
2.00
ND
ND
ND
NS
NS
NS
ND
02/05/18
mg/L
2.00
2.00
ND
5.6
ND
NS
NS
NS
ND
08/13/18
mg/L
2.00
2.00
ND
71.8
3.56
NS
NS
NS
ND
Chemical Oxygen Demand
08/14/14
mg/L
12.5
25.0
ND
132.0
ND
-
-
-
50.00
COD
03/10/15
mg/L
12.5
25.0
15.OJ
235.0
96.0
-
-
-
ND
08/18/15
mg/L
12.5
25.0
25.0
110.0
756.0
-
-
-
25.00
02/16/16
mg/L
12.5
25.0
ND
295.0
50.0
-
-
-
ND
08/09/16
mg/L
12.5
25.0
-
131.0
50.0
-
-
-
-
02/13/17
mg/L
12.5
25.0
17.0 J
119.0
43.0
NS
NS
NS
22.0 J
08/22/17
mg/L
12.5
25.0
ND
121.0
74.0
NS
NS
NS
16.0 J
02/05/18
mg/L
12.5
25.0
ND
113.0
51.0
NS
NS
NS
46.0
08/13/18
mg/L
12.5
25.0
ND
112.0
73.9
NS
NS
NS
NS
Butner Landfill, Granville Co.
Permit No. 39-02
Page 3 of 5
Joyce Engineering
December 2018

TABLE 7: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Dissolved Ethane
12/30/03
mg/L
0.0002
0.0010
ND
ND
ND
ND
ND
ND
12/19/07
mg/L
-
20.0
ND
ND
ND
ND
-
-
ND
05/01/13
mg/L
0.0031
0.0062
ND
ND
ND
ND
-
-
ND
08/14/14
mg/L
0.0031
0.0062
ND
ND
0.0036 J
-
-
-
ND
03/10/15
mg/L
0.0031
0.0062
ND
ND
ND
-
-
-
ND
08/18/15
mg/L
0.0031
0.0062
0.01
0.01
0.01
-
-
-
0.01
02/16/16
mg/L
0.0031
0.0062
ND
ND
ND
-
-
-
ND
08/09/16
mg/L
0.0031
0.0062
-
1.6 J
2.6 J
-
-
-
-
02/13/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/22/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
Dissolved Ethene
12/01/03
mg/L
0.0003
0.0010
ND
ND
ND
ND
ND
ND
12/19/07
mg/L
-
20.0
ND
ND
ND
ND
-
-
ND
05/01/13
mg/L
0.0031
0.0062
ND
ND
0.0017
ND
-
-
ND
08/14/14
mg/L
0.0031
0.0062
ND
ND
ND
-
-
-
ND
03/10/15
mg/L
0.0031
0.0062
ND
ND
ND
-
-
-
ND
08/18/15
mg/L
0.0031
0.0062
0.01
0.01
0.01
-
-
-
0.01
02/16/16
mg/L
0.0031
0.0062
ND
ND
ND
-
-
-
ND
08/09/16
mg/L
0.0031
0.0062
-
ND
ND
-
-
-
-
02/13/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/22/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
Dissolved Methane
12/30/03
mg/L
0.0002
0.0010
ND
0.660
0.130
0.0099
0.0010
ND
-
12/19/07
mg/L
-
10.0
ND
0.116
0.186
ND
-
-
ND
05/01/13
mg/L
0.0033
0.0066
ND
0.0379
0.100
0.0337
-
-
ND
08/14/14
mg/L
0.0033
0.0066
ND
1.2900
0.284
-
-
-
ND
03/10/15
mg/L
0.0033
0.0066
0.0072
0.9960
0.158
-
-
-
ND
08/18/15
mg/L
0.0033
0.0066
0.0027
2.16
0.316
-
-
-
0.0013
02/16/16
mg/L
0.0033
0.0066
0.007 J
0.87
0.098
-
-
-
0.0016 J
08/09/16
mg/L
0.0033
0.0066
-
1.85
0.206
-
-
-
-
02/13/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/22/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
Pyruvic Acid
12/19/07
mg/L
2.50
ND
1.50
2.00
-
-
1.20
05/01/13
mg/L
2
10
ND
ND
ND
ND
-
-
ND
08/14/14
mg/L
0.77
10
ND
ND
ND
-
-
-
ND
03/10/15
mg/L
0.77
10
0.41J
0.41J
0.41J
-
-
-
0.41J
08/18/15
mg/L
0.77
10
ND
ND
ND
-
-
-
ND
02/16/16
mg/L
0.77
10
ND
ND
ND
-
-
-
ND
08/09/16
mg/L
0.77
10
-
ND
ND
-
-
-
-
02/13/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/22/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
Lactic Acid
12/19/07
mg/L
ND
5.40
11.9
3.10
-
-
ND
05/01/13
mg/L
2.3
25
ND
ND
ND
ND
-
-
ND
08/14/14
mg/L
2.5
25
4.2 J
ND
ND
-
-
-
ND
03/10/15
mg/L
2.5
25
ND
ND
ND
-
-
-
ND
08/18/15
mg/L
2.5
25
ND
ND
ND
-
-
-
ND
02/16/16
mg/L
2.5
25
ND
ND
ND
-
-
-
ND
08/09/16
mg/L
2.5
25
-
ND
ND
-
-
-
-
02/13/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/22/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
Butner Landfill, Granville Co.
Permit No. 39-02
Page 4 of 5
Joyce Engineering
December 2018

TABLE 7: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Acetic Acid
12/19/07
mg/L
ND
ND
ND
ND
-
-
ND
05/01/13
mg/L
1.8
5
ND
ND
ND
ND
-
-
ND
08/14/14
mg/L
0.81
5.0
ND
ND
ND
-
-
-
ND
03/10/15
mg/L
0.81
5.0
ND
ND
ND
-
-
-
ND
08/18/15
mg/L
0.81
5.0
ND
ND
0.97 J
-
-
-
ND
02/16/16
mg/L
0.81
5.0
ND
ND
ND
-
-
-
ND
08/09/16
mg/L
0.81
5.0
-
ND
ND
-
-
-
-
02/13/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/22/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
Propionic Acid
12/19/07
mg/L
ND
63.7
38.3
12.8
-
-
ND
05/01/13
mg/L
1
5
ND
ND
ND
ND
-
-
ND
08/14/14
mg/L
0.66
5.0
ND
ND
ND
-
-
-
ND
03/10/15
mg/L
0.66
5.0
ND
ND
ND
-
-
-
ND
08/18/15
mg/L
0.66
5.0
ND
ND
ND
-
-
-
ND
02/16/16
mg/L
0.66
5.0
ND
ND
ND
-
-
-
ND
08/09/16
mg/L
0.66
5.0
-
ND
ND
-
-
-
-
08/22/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/13/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/13/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
Butyric Acid
12/19/07
mg/L
ND
ND
ND
ND
-
-
ND
05/01/13
mg/L
0.87
5
ND
ND
ND
ND
-
-
ND
08/14/14
mg/L
0.70
5.0
ND
ND
ND
-
-
-
ND
03/10/15
mg/L
0.70
5.0
ND
ND
ND
-
-
-
ND
08/18/15
mg/L
0.70
5.0
ND
ND
ND
-
-
-
ND
02/16/16
mg/L
0.70
5.0
ND
ND
ND
-
-
-
ND
08/09/16
mg/L
0.70
5.0
-
ND
ND
-
-
-
02/13/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/22/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
Total Volatile Fatty Acids
12/19/07
mg/L
2.50
69.10
51.70
17.90
-
-
1.20
(sum of above 5 acids)
05/01/13
mg/L
ND
ND
ND
-
-
-
ND
08/14/14
mg/L
4.2 J
ND
ND
-
-
-
ND
03/10/15
mg/L
ND
ND
ND
-
-
-
ND
08/18/15
mg/L
ND
ND
0.97 J
-
-
-
ND
02/16/16
mg/L
ND
ND
ND
-
-
-
ND
08/09/16
mg/L
-
ND
ND
-
-
-
-
02/13/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/22/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
NOTES:
DL = laboratory detection limit. mg/L = milligrams per liter °C = degress Celcius
RL = laboratory reporting limit. my = millivolt µS/cm = micro-Siemen per centimeter
ND = not detected above detection limit. SU = standard unit ntu = nephelometric turbidity units
J = estimated concentration between the DL and the RL. nM = nano -Molar
- = not analyzed.
DL and RL for Alkalinity for Dec. 03 event was 1 and 2 respectively for wells MW-2R, -3R, and -4 due to different methods used by the labrotory.
* Alkalinity RL for: MW-1R = 1.0, MW-2R = 5.0, MW-3R = 5.0, MW-4 = 2.0, NES-1 = 5.0 mg/l.
Methane in December 2007 was out of hold time for MW-2R, MW-3R, MW-4, and NES-1.
Butner Landfill, Granville Co.
Permit No. 39-02
Page 5 of 5
Joyce Engineering
December 2018

CHARTS
Chart 1 Benzene Concentrations vs. Time
Chart 2 Cobalt Concentrations vs. Time

CHART 1: Benzene Concentrations vs. Time
2.
tMW-2R fMW-3R
1.
1.
1
m
" 1
0
MW-4R-NC 2L=1.Oµg/I
0.2 1 / \\ p ��Z IVAN
0.0j. 11 r. . .
10 0 n n c0 0o m rn o o v a in �n �o io n n m co
0 0 0 0 0 0 0 .+
m -D m LD m tD m tD m tD m 6 m ID m tD m ID m ID m t9
> > > > > > > > > > > > >
LL a LL a LL a LL a LL a LL a LL a LL a LL a LL a LL a LL a LL a
Butner Landfill, Granville County
Permit # 39-02 Joyce Engineering

CHART 2: Cobalt Concentrations vs. Time
180.0
160.0
140.0
120.0
m
c
100.0
c
v
u
O
O
u 80.0
O
V
60.0
40.0
20.0
0.0
e � n n co 0o m rn o o v e � io n n oo co
0 0 0 0 0 0 0 0
> > > > > > > > > > > > >
LL a LL a LL a LL a LL a LL a LL a LL a LL a LL a LL a LL a LL a
Butner Landfill, Granville County
Permit # 39-02 Joyce Engineering

FIGURE
Figure 1 Site Location Map

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DRAWING
Drawing 1 Groundwater Potentiometric Surface Map
Drawing 2 2018 Tree Survey

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APPROXIMATE LIMITS OF WASTE
GROUNDWATER SURFACE CONTOUR
(FEET ABOVE MEAN SEA LEVEL)
GROUNDWATER FLOW DIRECTION WITH
GRADIENT CALCULATION SEGMENT
EXISTING ROAD
CENTERLINE OF STREAM
- MW-1R GROUNDWATER MONITORING WELL
415.86 LOCATION AND IDENTIFICATION
O SEGMENT USED FOR GRADIENT
CALCULATIONS
GAS PROBE LOCATION AND
GP-1 IDENTIFICATION
GV GAS VENT
0 SW-1 SURFACE WATER MONITORING POINT
(NM) NOT MEASURED
FLOW PATH LENGTH
iD = 1,878 LF
NOTES
1. TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET
2. GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET
3. STATIC WATER LEVELS MEASURED ON 08/13/18.
4. GROUNDWATER CONTOURS BASED ON KNOWN DATA,
TOPOGRAPHIC CONTOURS, LINEAR INTERPOLATION AND
EXTRAPOLATION FROM KNOWN FIELD CONDITIONS.
5. ELEVATION RELATIVE TO MEAN SEA LEVEL.
6. GROUNDWATER ELEVATION IS BASED ON A WELL SURVEY
PERFORMED IN APRIL 2008
7. TOPOGRAPHIC CONTOURS SHOWN IN THIS MAP ARE BASED ON
2007 DATA OBTAINED FROM NCDOT WEBSITE.
8. BOUNDARY SURVEY PROVIDED BY BATEMAN CIVIL SURVEY
COMPANY DATED MARCH 15, 2013.
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APPENDICES
Appendix A Field Data Logs
Appendix B Laboratory Analytical Reports
Appendix C Historical Groundwater Elevations
Appendix D Historical Constituents in Groundwater
Appendix E Historical Constituents in Surface Water

Appendix A
Field Data Logs

DATE: 8/13/2018
ENC�lIVEEF?II"VG GROUND WATER SAMPLING LOG
Project Name: BUTNER, Granville Co. Project No./Phase No.: 2180175.04
Well ID: 3902-MW-1R Sampler(s): R. Mesubed / J. Kent
Well Location: North of the entrance at the tree line under the tower
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
WCT X 0.163
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with: disposable bailer
Sampled with: disposable bailer
2
inches
44.65
feet
56.00
feet
11.35
feet [DTB-DTW]
= 1.8 gallons
_ Lyallons
= 5.5 gallons
3.5 gallons
Depth to Water before Sampling: - feet
Gallons
Time
Temp.
°C
DO
Mg/L
Cond.
(US/cm)
pH
S.U.
ORP
mV
Turb.
ntu
Initials
0
0725
16.8
4.05
179.1
5.91
52.5
4.77
JK
1.8
0731
16.6
5.21
101.8
6.10
72.4
36.14
JK
Dry @ 3.5 gal
Before
Sampling
0805
17.4
6.31
101.2
6.30
117.9
13.43
RM
Comments (weather conditions, odor, color
8/13/201
etc.): The weather was cloudy with
Signature: Date: 11/6/4
QA/QC Sign Off. Date: 111a0/1$

DATE: 8/ 13/2018
GROUND WATER SAMPLING LOG
Project Name: BUTNER, Granville Co. Project No./Phase No.: 2180175.04
Well ID: 3902-MW-2R Sampler(s): R. Mesubed/ J. Kent
Well Location: South side of fill, inside tree line and next to MW-3R
Well Diameter:
2
inches
Initial Depth to Water (DTW):
2.64
feet
Depth to Bottom (DTB):
18.85
feet
Water Column Thickness (WCT):
16.21
feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 =
2.6
gallons
For 4" Well: WCT X 0.653 = gallons
For THREE Well Volumes: WV X 3 = 7.9 gallons
Actual Amount Purged/Bailed: 7.9 gallons
Purged with: disposable bailer
Sampled with: disposable bailer
Depth to Water before Sampling: -- feet
Gallons
Time
Temp.
°C
DO.
Mg/L
Cond.
(uS/cm)
pH
S.U.
ORP
MV
Turb.
ntu
Initials
0
1024
20.7
1.19
1968
6.33
48.1
18.79
RM
2.6
1030
19.8
1.86
1960
6.38
-2.82
128.0
RM
5.2
1035
17.7
1.60
1901
6.41
-34.2
59.13
RM
7.9
1040
17.3
1.30
1880
6.38
-51.4
23.84
RM
Before
Sampling
1103
21.1
3.20
2013
6.45
-60.5
4.22
RM
Comments (weather conditions, odor, color, silt, etc.): The weather was cloudy with
in the
Signature:
QA/QC Sign Off:
Fe2+: 5.5
Date: Z
Date: IQt9la,

DATE: 8/13/2018
AJLJ l L=
Et*4C31tVEEF?1NG GROUND WATER SAMPLING LOG
Project Name: BUTNER, Granville Co. Project No./Phase No.: 2180175.04
Well ID: 3902-MW-3R
Sampler(s): R. Mesubed/ J. Kent
Well Location: Next to MW-2R, inside tree line
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT)
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with: disposable bailer
Sampled with: disposable bailer
2
inches
3.00
feet
35.83
feet
32.83
feet [DTB-DTW]
5.3 gallons
= gallons
16.0 gallons
5.9 gallons
Depth to Water before Sampling: 15.81 feet
Gallons
Time
Temp.
°C
DO
mg/L
Cond.
(US/CM)
pH
S.U.
ORP
mV
Turb.
ntu
Initials
0
1051
20.9
1.15
1532
6.76
-13.1
0.0
JK
5.3
1057
16.4
2.67
1534
6.73
10.8
0.73
JK
DRY @ 5.9
Before
Sampling
1124
18.2
2.35
1608
6.64
-49.3
0.0
RM
Comments (weather conditions, odor, color, silt, etc.): The weather was cloudy with
tem eratures in the 70s on 8/13/2018• Fe2+: 0.2 m /L• 14 bottles sampled
Signature: Date: _ 6T/IA
QA/QC Sign Off:.—j2jY!±4!t-9Date: Plaohg

El,+l�1NE'E'R/NC3
DATE: 8/13/2018
GROUND WATER SAMPLING LOG
Project Name: BUTNER, Granville Co. Project No./Phase No.: 2180175.04
Well ID: 3902-MW-4 Sampler(s): J. Kent / R. Mesubed
Well Location: south of fill, just inside tree line
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT)
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
WCT X 0.163
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with: disposable bailer
Sampled with: disposable bailer
2
inches
8.83
feet
31.43
feet
22.60
feet [DTB-DTW]
= 3.7
gallons
_
gallons
= 11.1
gallons
4.3
gallons
Depth to Water before Sampling: 25.8
Gallons
Time
Temp.
°C
pH
S.U.
Cond.
(US/CM)
Turb.
ntu
Initials
0
1245
22.6
4.58
1687
0.00
RM
3.7
1253
19.4
6.37
1614
1.00
RM
DRY @ 4.3
Before
Sampling
1304
19.3
6.38
1069
4.14
RM
Comments (weather conditions, odor, color, silt, etc.): The weather was cloudy with
temperatures in the 70s on 8/13/2018; 7 bottles sampled
Signature: Date:
QA/QC Sign Off: Date: // wl/g

DATE: 8/ 13/2018
&JLJ19 &i=
F"CI IJFF 4/M-3 GROUND WATER SAMPLING LOG
Project Name: BUTNER, Granville Co. Project No./Phase No.: 2180175.04
Well ID: 3902-MW-5 Sampler(s):
J. Kent / R. Mesubed
Well Location: South side of old SED. pond, Basin in the woods
Well Diameter:
2 inches
Initial Depth to Water (DTW):
14.20 feet
Depth to Bottom (DTB):
23.52 feet
Water Column Thickness (WCT):
9.32 feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 =
1.5 gallons
For 4" Well: WCT X 0.653 =
gallons
For THREE Well Volumes: WV X 3 =
4.5 gallons
Actual Amount Purged/Bailed:
3.0 gallons
Purged with: disposable Bailer
Sampled with: disposable Bailer
Depth to Water before Sampling: 19.5
feet
Gallons
Time
Temp.
°C
pH
Cond.
(uS/cm)
Turb.
ntu
Initials
0
1333
20.4
7.24
929
57.42
JK
1.5
1340
17.9
7.51
939
1100
JK
DRY @ 3.0
Before
Sampling
1401
20.6
7.15
870
103
JK
Comments (weather conditions, odor, color, silt, etc.): The weather was cloudy with
temperatures in the 70s on 8/13/2018; 7 bottles sampled
Signature: �— Date: g,_
QA/QC Sign Off: _ " km�Date: 11 /aoZj& _�

&JLJJr &
lcJ�,J�lh/EERIN�
DATE: 8/14/2018
GROUND WATER SAMPLING LOG
Project Name: BUTNER, Granville Co. Project No./Phase No.: 2180175.04
Well ID: 3902-MW-6 Sampler(s): S. Slebodnik / R. Mesubed
Well Location: other side of large mulch pile
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
WCT X 0.163
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with: disposable Bailer
Sampled with: disposable Bailer
2
inches
12.41
feet
32.63
feet
20.22
feet [DTB-DTW]
3.3 gallons
gallons
9.9 gallons
8.4 gallons
Depth to Water before Sampling: 19.08 feet
Gallons
Time
Temp.
°C
pH
S.U.
Cond.
(US/CM)
DO
mg/L
ORP
mV
Turb.
ntu
Initials
0
1033
176
7.05
652
2.50
14.4
4.58
RM
3.3
1038
16.2
j 7.04
609
3.09
26.3
5.74
RM
6.6
1047
16.3
6.94
606
2.73
36.2
68.84
RM
DRY @ 8.4
Before
Sampling
1210
18.4
7.03
620
4.80
64.4
0.64
SS
Comments (weather conditions, odor, color, silt, etc.): The weather was cloudy with
temperatures in the 70s on 8/14/2018.
Signature: ` Date: ��
QA/QC Sign Off: M-AZ-41 hwuw Date: ��ZjE-

DATE: 8/14-15/2018
ENG11�.1EL�RthtG GROUND WATER SAMPLING LOG
Project Name: BUTNER, Granville Co. Project No./Phase No.: 2180175
Well ID: 3902-NES-1 Sampler(s): S. Slebodnik / R. Mesubed
Well Location: South of landfill, access through Wildlife Area hunt camp
Well Diameter: 2 inches
Initial Depth to Water (DTW): 15.89 feet
Depth to Bottom (DTB): 36.10 feet
Water Column Thickness (WCT): 20.21 feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 = 3.3 gallons
For 4" Well: WCT X 0.653 = gallons
For THREE Well Volumes: WV X 3 = 9.9 gallons
Actual Amount Purged/Bailed: 9.9 gallons
Purged with: disposable bailer
Sampled with: disposable bailer
Depth to Water before Sampling: 16.41 feet
Gallons
Time
Temp.
°C
pH
S.U.
Cond.
(US/cm)
DO
mg/L
ORP
mV
Turb.
ntu
Initials
0
1255
17.8
5.57
124.0
2.91
71.1
3.72
SS
3.3
1300
16.8
5.23
100.6
2.61
90.4
134.0
SS
6.6
1305
16.4
5.29
94.5
3.57
94.8
705.4
SS
9.9
1311
16.0
5.17
90.4
5.44
102.9
> 1000
SS
8/15/18
Before
Sampling
0619
16.6
5.54
131.2
3.91
28.4
30.20
SS
Comments (weather conditions, odor, color, silt, etc.): The weather was sunny with
temperatures in the 70s on 8/14-15/2018; FB @ 0631 with 18 bottles sampled
Signature: Date: /yzG C
QA/QC Sign Off: ?Y Date: 11 /20114 _

DATE: 8/ 13/2018
SJLJ r ��
l�h►�INEEl4/1'�!�
SURFACE WATER MONITORING LOG
Project Name: BUTNER, Granville Co. Project/Phase No.: 2180175.04
Surface Point ID: 3902-SW-1 Sampler(s):S. Slebodnik/R. Mesubed
Location: Near Sed. pond, Basin
Field Parameters:
Time of Sampling:
pH:
Temperature:
Conductivity:
Turbidity:
1346
6.60
23.8 (°C)
(US/cm)
5.65 (ntu)
Comments/Sample Description (weather conditions, odor, color, silt, etc.): The
weather was cloudy with temperatures in the 70s on 8/13/2018.
Sketch of Sample Location (include flow direction, drainage pathways, etc.):
0 MW-5
Signature: /� Date: �%�i� �
QA/QC Sign Off:'A.CL P? Cet`' Date:_ %I Z40-da

DATE: 8/ 14/2018
E1�JGIh1EER11tilG SURFACE WATER MONITORING LOG
Project Name: BUTNER, Granville Co. Project/Phase No.:2180175.04
Surface Point ID: 3902-SW-2 Sampler(s):S. Slebodnik / R. Mesubed
Location: Down from MW-2R & NM-3R
Field Parameters:
Time of Sampling: 1316
pH: 7.53
Temperature: 23.1 (° C)
Conductivity: 849 (US/CM)
Turbidity: 7.25 (ntu)
Comments/Sample Description (weather conditions, odor, color, silt, etc.): The
weather was cloudy with temperatures in the 70 on 8/14/2018. 7 bottles sampled
Sketch of Sample Location (include flow direction, drainage pathways, etc.):
10 if
MW ZR MW--3TZ
� � r
c
S'7RfrAM ,
Signature: I Date: �%slip
QA/QC Sign Off: U Date: // 42PZ(9

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Appendix B
Laboratory Analytical Reports

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
August 24, 2018
Mr. Van Burbach
Joyce Engineering -NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Butner Landfill Compliance
Pace Project No.: 92395744
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 14, 2018. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
��i Flo _ _.1I , .�:
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Mr. Daniel Girdner, LaBella Associates, D.P.C.
Miguel Vazquez, Joyce Engineering
Rochelle mesubed, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 34

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Butner Landfill Compliance
Pace Project No.: 92395744
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 34

aceAnalytical
—pacelabsxom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Butner Landfill Compliance
Pace Project No.: 92395744
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92395744001
3902-MW1R
Water
08/13/18 08:05
08/14/18 10:41
92395744002
3902-MW2R
Water
08/13/1811:03
08/14/18 10:41
92395744003
3902-MW3R
Water
08/13/1811:24
08/14/18 10:41
92395744004
3902-MW4
Water
08/13/1813:04
08/14/18 10:41
92395744005
3902-MW5
Water
08/13/1814:01
08/14/18 10:41
92395744006
3902-SW1
Water
08/13/1813:46
08/14/18 10:41
92395744007
3902-Trip Blank
Water
08/13/18 05:30
08/14/18 10:41
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 34

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Butner Landfill Compliance
92395744
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92395744001
3902-MW1R
EPA 6010D
KQ
15
PASI-A
EPA6020B
JMW1
1
PASI-A
EPA 8260E
CAH
50
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
92395744002
3902-MW2R
EPA 6010D
KQ
15
PASI-A
EPA6020B
JMW1
1
PASI-A
EPA 8260E
CAH
50
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
92395744003
3902-MW3R
EPA 6010D
KQ
15
PASI-A
EPA6020B
JMW1
1
PASI-A
EPA 8260E
CAH
50
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
92395744004
3902-MW4
EPA 6010D
KQ
14
PASI-A
EPA6020B
JMW1
1
PASI-A
EPA 8260E
CAH
50
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
92395744005
3902-MW5
EPA 6010D
KQ
14
PASI-A
EPA6020B
JMW1
1
PASI-A
EPA 8260E
CAH
50
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
92395744006
3902-SW1
EPA 6010D
KQ
14
PASI-A
EPA6020B
JMW1
1
PASI-A
EPA 8260E
CAH
50
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
92395744007
3902-Trip Blank
EPA 8260E
CAH
50
PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 34

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
Butner Landfill Compliance
92395744
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92395744001
3902-MW1 R
EPA 6010D
Barium
3.8J
ug/L
100
08/19/18 21:27
92395744002
3902-MW2R
EPA 6010D
Arsenic
5AJ
ug/L
10.0
08/19/18 21:39
EPA 6010D
Barium
116
ug/L
100
08/19/18 21:39
EPA 6010D
Cobalt
10.7
ug/L
10.0
08/19/18 21:39
EPA 6010D
Copper
5.5J
ug/L
10.0
08/19/18 21:39
EPA 6010D
Nickel
88.9
ug/L
50.0
08/19/18 21:39
EPA 6010D
Tin
22.2J
ug/L
100
08/19/18 21:39
EPA 6010D
Vanadium
5.3J
ug/L
25.0
08/19/18 21:39
EPA 8260B
Benzene
1.3
ug/L
1.0
08/19/18 13:05
EPA 8260B
Chlorobenzene
14.5
ug/L
3.0
08/19/18 13:05
EPA 8260B
Chloroethane
1.2J
ug/L
10.0
08/19/18 13:05
EPA 8260B
1,2-Dichlorobenzene
1.2J
ug/L
5.0
08/19/18 13:05
EPA 8260B
1,4-Dichlorobenzene
1.9
ug/L
1.0
08/19/18 13:05
EPA 8260B Mod.
1,4-Dioxane (p-Dioxane)
88.0
ug/L
2.0
08/21/18 18:33
92395744003
3902-MW3R
EPA 6010D
Barium
67.6J
ug/L
100
08/19/18 21:42
EPA 6010D
Copper
12.2
ug/L
10.0
08/19/18 21:42
EPA 6010D
Nickel
29.OJ
ug/L
50.0
08/19/18 21:42
EPA 6010D
Tin
7AJ
ug/L
100
08/19/18 21:42
EPA 8260B
Benzene
0.61 J
ug/L
1.0
08/19/18 13:22
EPA 8260B
Chlorobenzene
22.2
ug/L
3.0
08/19/18 13:22
EPA 8260B
Chloroethane
2AJ
ug/L
10.0
08/19/18 13:22
EPA 8260B
1,2-Dichlorobenzene
1.6J
ug/L
5.0
08/19/18 13:22
EPA 8260B
1,4-Dichlorobenzene
1.1
ug/L
1.0
08/19/18 13:22
EPA 8260B
Vinyl chloride
0.72J
ug/L
1.0
08/19/18 13:22
EPA 8260B Mod.
1,4-Dioxane (p-Dioxane)
53.1
ug/L
2.0
08/21/18 20:31
92395744004
3902-MW4
EPA 6010D
Copper
3.7J
ug/L
10.0
08/19/18 21:46
EPA 6010D
Nickel
12.3J
ug/L
50.0
08/19/18 21:46
EPA 6010D
Vanadium
20AJ
ug/L
25.0
08/19/18 21:46
EPA 8260B
Benzene
0.29J
ug/L
1.0
08/19/18 13:38
EPA 8260B
Chlorobenzene
3.4
ug/L
3.0
08/19/18 13:38
EPA 8260B
Chloroethane
1 AJ
ug/L
10.0
08/19/18 13:38
EPA 8260B
1,1-Dichloroethane
0.37J
ug/L
5.0
08/19/18 13:38
EPA 8260B Mod.
1,4-Dioxane (p-Dioxane)
40.7
ug/L
2.0
08/21/18 20:50
92395744005
3902-MW5
EPA 6010D
Barium
103
ug/L
100
08/19/18 21:49
EPA 6010D
Cobalt
97.7
ug/L
10.0
08/19/18 21:49
EPA 6010D
Copper
48.8
ug/L
10.0
08/19/18 21:49
EPA 6010D
Lead
4.6J
ug/L
10.0
08/19/18 21:49
EPA 6010D
Nickel
21.9J
ug/L
50.0
08/19/18 21:49
EPA 6010D
Vanadium
2.9J
ug/L
25.0
08/19/18 21:49
EPA 6010D
Zinc
8.1 J
ug/L
10.0
08/19/18 21:49
EPA 6020B
Thallium
0.037J
ug/L
5.5
08/23/18 21:43
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 5 of 34

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SUMMARY OF DETECTION
Project:
Pace Project No.:
Butner Landfill Compliance
92395744
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92395744005
3902-MW5
EPA 8260B
Toluene
0.44J
ug/L
1.0
08/19/18 13:54
EPA 8260B Mod.
1,4-Dioxane (p-Dioxane)
2.OJ
ug/L
2.0
08/21/18 21:10
92395744006
3902-SW1
EPA 6010D
Barium
70.OJ
ug/L
100
08/19/18 21:52
EPA 6010D
Chromium
5.9J
ug/L
10.0
08/19/18 21:52
EPA 6010D
Cobalt
6.OJ
ug/L
10.0
08/19/18 21:52
EPA 6010D
Copper
4.1 J
ug/L
10.0
08/19/18 21:52
EPA 6010D
Nickel
7.3J
ug/L
50.0
08/19/18 21:52
EPA 6010D
Vanadium
8.3J
ug/L
25.0
08/19/18 21:52
EPA 6010D
Zinc
6.OJ
ug/L
10.0
08/19/18 21:52
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 6 of 34

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ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92395744
Sample: 3902-MW1R Lab ID: 92395744001 Collected: 08/13/18 08:05 Received: 08/14/18 10:41 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Tin
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260 MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Date: 08/24/2018 02:30 PM
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
ND
ug/L
6.0
3.9
1
08/15/18 08:30
08/19/18 21:27
7440-36-0
ND
ug/L
10.0
5.0
1
08/15/18 08:30
08/19/18 21:27
7440-38-2
3.8J
ug/L
100
2.5
1
08/15/18 08:30
08/19/18 21:27
7440-39-3
ND
ug/L
1.0
0.50
1
08/15/18 08:30
08/19/18 21:27
7440-41-7
ND
ug/L
1.0
0.50
1
08/15/18 08:30
08/19/18 21:27
7440-43-9
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:27
7440-47-3
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:27
7440-48-4
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:27
7440-50-8
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:27
7439-92-1
ND
ug/L
50.0
2.5
1
08/15/18 08:30
08/19/18 21:27
7440-02-0
ND
ug/L
10.0
5.0
1
08/15/18 08:30
08/19/18 21:27
7782-49-2
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:27
7440-22-4
ND
ug/L
100
2.5
1
08/15/18 08:30
08/19/18 21:27
7440-31-5
ND
ug/L
25.0
2.5
1
08/15/18 08:30
08/19/18 21:27
7440-62-2
ND
ug/L
10.0
5.0
1
08/15/18 08:30
08/19/18 21:27
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 5.5 0.020 1 08/15/18 03:45 08/23/18 21:16 7440-28-0
Analytical Method: EPA 8260E
ND
ug/L
100
10.0
1
08/19/1812:33
67-64-1
ND
ug/L
200
1.9
1
08/19/1812:33
107-13-1
ND
ug/L
1.0
0.25
1
08/19/1812:33
71-43-2
ND
ug/L
3.0
0.17
1
08/19/1812:33
74-97-5
ND
ug/L
1.0
0.18
1
08/19/1812:33
75-27-4
ND
ug/L
3.0
0.26
1
08/19/1812:33
75-25-2
ND
ug/L
10.0
0.29
1
08/19/1812:33
74-83-9
ND
ug/L
100
0.96
1
08/19/1812:33
78-93-3
ND
ug/L
100
1.2
1
08/19/1812:33
75-15-0
ND
ug/L
1.0
0.25
1
08/19/1812:33
56-23-5
ND
ug/L
3.0
0.23
1
08/19/1812:33
108-90-7
ND
ug/L
10.0
0.54
1
08/19/1812:33
75-00-3
ND
ug/L
5.0
0.14
1
08/19/1812:33
67-66-3
ND
ug/L
1.0
0.11
1
08/19/1812:33
74-87-3
ND
ug/L
13.0
2.0
1
08/19/1812:33
96-12-8
ND
ug/L
3.0
0.21
1
08/19/1812:33
124-48-1
ND
ug/L
1.0
0.27
1
08/19/1812:33
106-93-4
ND
ug/L
10.0
0.21
1
08/19/1812:33
74-95-3
ND
ug/L
5.0
0.30
1
08/19/1812:33
95-50-1
ND
ug/L
1.0
0.33
1
08/19/1812:33
106-46-7
ND
ug/L
100
1.0
1
08/19/1812:33
110-57-6
ND
ug/L
5.0
0.32
1
08/19/1812:33
75-34-3
ND
ug/L
1.0
0.24
1
08/19/1812:33
107-06-2
ND
ug/L
5.0
0.56
1
08/19/1812:33
75-35-4
ND
ug/L
5.0
0.19
1
08/19/1812:33
156-59-2
ND
ug/L
5.0
0.49
1
08/19/1812:33
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 34

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[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92395744
Sample: 3902-MW1R Lab ID: 92395744001 Collected: 08/13/18 08:05 Received: 08/14/18 10:41 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260 MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 08/24/2018 02:30 PM
Analytical Method: EPA 8260E
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
50.0
ND
ug/L
10.0
ND
ug/L
1.0
ND
ug/L
100
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
3.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
50.0
ND
ug/L
1.0
ND
ug/L
5.0
97
%
70-130
98
%
70-130
98
%
70-130
Analytical Method: EPA 8260E Mod.
ND
ug/L
2.0
99
%
50-150
115
%
50-150
0.27
1
08/19/18 12:33
78-87-5
0.13
1
08/19/18 12:33
10061-01-5
0.26
1
08/19/18 12:33
10061-02-6
0.30
1
08/19/18 12:33
100-41-4
0.46
1
08/19/18 12:33
591-78-6
0.32
1
08/19/18 12:33
74-88-4
0.97
1
08/19/18 12:33
75-09-2
0.33
1
08/19/18 12:33
108-10-1
0.26
1
08/19/18 12:33
100-42-5
0.33
1
08/19/18 12:33
630-20-6
0.40
1
08/19/18 12:33
79-34-5
0.46
1
08/19/18 12:33
127-18-4
0.26
1
08/19/18 12:33
108-88-3
0.48
1
08/19/18 12:33
71-55-6
0.29
1
08/19/18 12:33
79-00-5
0.47
1
08/19/18 12:33
79-01-6
0.20
1
08/19/18 12:33
75-69-4
0.41
1
08/19/18 12:33
96-18-4
0.35
1
08/19/18 12:33
108-05-4
0.62
1
08/19/18 12:33
75-01-4
0.66
1
08/19/18 12:33
1330-20-7
1
08/19/18 12:33
460-00-4
1
08/19/18 12:33
17060-07-0
1
08/19/18 12:33
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
08/21/18 20:11 123-91-1
08/21 /18 20:11 17060-07-0
08/21 /18 20:11 2037-26-5
Page 8 of 34

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92395744
Sample: 3902-MW2R Lab ID: 92395744002 Collected: 08/13/18 11:03 Received: 08/14/18 10:41 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Tin
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260 MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Date: 08/24/2018 02:30 PM
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
ND
ug/L
6.0
3.9
1
08/15/18 08:30
08/19/18 21:39
7440-36-0
5.4J
ug/L
10.0
5.0
1
08/15/18 08:30
08/19/18 21:39
7440-38-2
116
ug/L
100
2.5
1
08/15/18 08:30
08/19/18 21:39
7440-39-3
ND
ug/L
1.0
0.50
1
08/15/18 08:30
08/19/18 21:39
7440-41-7
ND
ug/L
1.0
0.50
1
08/15/18 08:30
08/19/18 21:39
7440-43-9
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:39
7440-47-3
10.7
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:39
7440-48-4
5.5J
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:39
7440-50-8
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:39
7439-92-1
88.9
ug/L
50.0
2.5
1
08/15/18 08:30
08/19/18 21:39
7440-02-0
ND
ug/L
10.0
5.0
1
08/15/18 08:30
08/19/18 21:39
7782-49-2
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:39
7440-22-4
22.2J
ug/L
100
2.5
1
08/15/18 08:30
08/19/18 21:39
7440-31-5
5.3J
ug/L
25.0
2.5
1
08/15/18 08:30
08/19/18 21:39
7440-62-2
ND
ug/L
10.0
5.0
1
08/15/18 08:30
08/19/18 21:39
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 5.5 0.020 1 08/15/18 03:45 08/23/18 21:27 7440-28-0
Analytical Method: EPA 8260E
ND
ug/L
100
10.0
1
08/19/1813:05
67-64-1 M1
ND
ug/L
200
1.9
1
08/19/1813:05
107-13-1
1.3
ug/L
1.0
0.25
1
08/19/1813:05
71-43-2
ND
ug/L
3.0
0.17
1
08/19/1813:05
74-97-5
ND
ug/L
1.0
0.18
1
08/19/1813:05
75-27-4
ND
ug/L
3.0
0.26
1
08/19/1813:05
75-25-2
ND
ug/L
10.0
0.29
1
08/19/1813:05
74-83-9 M1
ND
ug/L
100
0.96
1
08/19/1813:05
78-93-3
ND
ug/L
100
1.2
1
08/19/1813:05
75-15-0
ND
ug/L
1.0
0.25
1
08/19/1813:05
56-23-5
14.5
ug/L
3.0
0.23
1
08/19/1813:05
108-90-7
1.2J
ug/L
10.0
0.54
1
08/19/1813:05
75-00-3
ND
ug/L
5.0
0.14
1
08/19/1813:05
67-66-3
ND
ug/L
1.0
0.11
1
08/19/1813:05
74-87-3
ND
ug/L
13.0
2.0
1
08/19/1813:05
96-12-8
ND
ug/L
3.0
0.21
1
08/19/1813:05
124-48-1
ND
ug/L
1.0
0.27
1
08/19/1813:05
106-93-4
ND
ug/L
10.0
0.21
1
08/19/1813:05
74-95-3
1.2J
ug/L
5.0
0.30
1
08/19/1813:05
95-50-1
1.9
ug/L
1.0
0.33
1
08/19/1813:05
106-46-7
ND
ug/L
100
1.0
1
08/19/1813:05
110-57-6
ND
ug/L
5.0
0.32
1
08/19/1813:05
75-34-3
ND
ug/L
1.0
0.24
1
08/19/1813:05
107-06-2
ND
ug/L
5.0
0.56
1
08/19/1813:05
75-35-4
ND
ug/L
5.0
0.19
1
08/19/1813:05
156-59-2
ND
ug/L
5.0
0.49
1
08/19/1813:05
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 34

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92395744
Sample: 3902-MW2R Lab ID: 92395744002 Collected: 08/13/18 11:03 Received: 08/14/18 10:41 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260 MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 08/24/2018 02:30 PM
Analytical Method: EPA 8260E
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
50.0
ND
ug/L
10.0
ND
ug/L
1.0
ND
ug/L
100
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
3.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
50.0
ND
ug/L
1.0
ND
ug/L
5.0
96
%
70-130
99
%
70-130
96
%
70-130
Analytical Method: EPA 8260E Mod.
88.0
ug/L
2.0
100
%
50-150
114
%
50-150
0.27
1
08/19/18 13:05
78-87-5
0.13
1
08/19/18 13:05
10061-01-5
0.26
1
08/19/18 13:05
10061-02-6
0.30
1
08/19/18 13:05
100-41-4
0.46
1
08/19/18 13:05
591-78-6
0.32
1
08/19/18 13:05
74-88-4
0.97
1
08/19/18 13:05
75-09-2
0.33
1
08/19/18 13:05
108-10-1
0.26
1
08/19/18 13:05
100-42-5
0.33
1
08/19/18 13:05
630-20-6
0.40
1
08/19/18 13:05
79-34-5
0.46
1
08/19/18 13:05
127-18-4
0.26
1
08/19/18 13:05
108-88-3
0.48
1
08/19/18 13:05
71-55-6
0.29
1
08/19/18 13:05
79-00-5
0.47
1
08/19/18 13:05
79-01-6
0.20
1
08/19/18 13:05
75-69-4
0.41
1
08/19/18 13:05
96-18-4
0.35
1
08/19/18 13:05
108-05-4
0.62
1
08/19/18 13:05
75-01-4
0.66
1
08/19/18 13:05
1330-20-7
1
08/19/18 13:05
460-00-4
1
08/19/18 13:05
17060-07-0
1
08/19/18 13:05
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
08/21 /18 18:33 123-91-1
08/21 /18 18:33 17060-07-0
08/21 /18 18:33 2037-26-5
Page 10 of 34

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92395744
Sample: 3902-MW3R Lab ID: 92395744003 Collected: 08/13/18 11:24 Received: 08/14/18 10:41 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Tin
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260 MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Date: 08/24/2018 02:30 PM
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
ND
ug/L
6.0
3.9
1
08/15/18 08:30
08/19/18 21:42
7440-36-0
ND
ug/L
10.0
5.0
1
08/15/18 08:30
08/19/18 21:42
7440-38-2
67.6J
ug/L
100
2.5
1
08/15/18 08:30
08/19/18 21:42
7440-39-3
ND
ug/L
1.0
0.50
1
08/15/18 08:30
08/19/18 21:42
7440-41-7
ND
ug/L
1.0
0.50
1
08/15/18 08:30
08/19/18 21:42
7440-43-9
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:42
7440-47-3
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:42
7440-48-4
12.2
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:42
7440-50-8
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:42
7439-92-1
29.OJ
ug/L
50.0
2.5
1
08/15/18 08:30
08/19/18 21:42
7440-02-0
ND
ug/L
10.0
5.0
1
08/15/18 08:30
08/19/18 21:42
7782-49-2
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:42
7440-22-4
7.4J
ug/L
100
2.5
1
08/15/18 08:30
08/19/18 21:42
7440-31-5
ND
ug/L
25.0
2.5
1
08/15/18 08:30
08/19/18 21:42
7440-62-2
ND
ug/L
10.0
5.0
1
08/15/18 08:30
08/19/18 21:42
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 5.5 0.020 1 08/15/18 03:45 08/23/18 21:38 7440-28-0
Analytical Method: EPA 8260E
ND
ug/L
100
10.0
1
08/19/1813:22
67-64-1
ND
ug/L
200
1.9
1
08/19/1813:22
107-13-1
0.61J
ug/L
1.0
0.25
1
08/19/1813:22
71-43-2
ND
ug/L
3.0
0.17
1
08/19/1813:22
74-97-5
ND
ug/L
1.0
0.18
1
08/19/1813:22
75-27-4
ND
ug/L
3.0
0.26
1
08/19/1813:22
75-25-2
ND
ug/L
10.0
0.29
1
08/19/1813:22
74-83-9
ND
ug/L
100
0.96
1
08/19/1813:22
78-93-3
ND
ug/L
100
1.2
1
08/19/1813:22
75-15-0
ND
ug/L
1.0
0.25
1
08/19/1813:22
56-23-5
22.2
ug/L
3.0
0.23
1
08/19/1813:22
108-90-7
2.4J
ug/L
10.0
0.54
1
08/19/1813:22
75-00-3
ND
ug/L
5.0
0.14
1
08/19/1813:22
67-66-3
ND
ug/L
1.0
0.11
1
08/19/1813:22
74-87-3
ND
ug/L
13.0
2.0
1
08/19/1813:22
96-12-8
ND
ug/L
3.0
0.21
1
08/19/1813:22
124-48-1
ND
ug/L
1.0
0.27
1
08/19/1813:22
106-93-4
ND
ug/L
10.0
0.21
1
08/19/1813:22
74-95-3
1.6J
ug/L
5.0
0.30
1
08/19/1813:22
95-50-1
1.1
ug/L
1.0
0.33
1
08/19/1813:22
106-46-7
ND
ug/L
100
1.0
1
08/19/1813:22
110-57-6
ND
ug/L
5.0
0.32
1
08/19/1813:22
75-34-3
ND
ug/L
1.0
0.24
1
08/19/1813:22
107-06-2
ND
ug/L
5.0
0.56
1
08/19/1813:22
75-35-4
ND
ug/L
5.0
0.19
1
08/19/1813:22
156-59-2
ND
ug/L
5.0
0.49
1
08/19/1813:22
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 34

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92395744
Sample: 3902-MW3R Lab ID: 92395744003 Collected: 08/13/18 11:24 Received: 08/14/18 10:41 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260 MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 08/24/2018 02:30 PM
Analytical Method: EPA 8260E
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
50.0
ND
ug/L
10.0
ND
ug/L
1.0
ND
ug/L
100
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
3.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
50.0
0.72J
ug/L
1.0
ND
ug/L
5.0
99
%
70-130
98
%
70-130
98
%
70-130
Analytical Method: EPA 8260E Mod.
53.1
ug/L
2.0
99
%
50-150
111
%
50-150
0.27
1
08/19/18 13:22
78-87-5
0.13
1
08/19/18 13:22
10061-01-5
0.26
1
08/19/18 13:22
10061-02-6
0.30
1
08/19/18 13:22
100-41-4
0.46
1
08/19/18 13:22
591-78-6
0.32
1
08/19/18 13:22
74-88-4
0.97
1
08/19/18 13:22
75-09-2
0.33
1
08/19/18 13:22
108-10-1
0.26
1
08/19/18 13:22
100-42-5
0.33
1
08/19/18 13:22
630-20-6
0.40
1
08/19/18 13:22
79-34-5
0.46
1
08/19/18 13:22
127-18-4
0.26
1
08/19/18 13:22
108-88-3
0.48
1
08/19/18 13:22
71-55-6
0.29
1
08/19/18 13:22
79-00-5
0.47
1
08/19/18 13:22
79-01-6
0.20
1
08/19/18 13:22
75-69-4
0.41
1
08/19/18 13:22
96-18-4
0.35
1
08/19/18 13:22
108-05-4
0.62
1
08/19/18 13:22
75-01-4
0.66
1
08/19/18 13:22
1330-20-7
1
08/19/18 13:22
460-00-4
1
08/19/18 13:22
17060-07-0
1
08/19/18 13:22
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
08/21/18 20:31 123-91-1
08/21 /18 20:31 17060-07-0
08/21 /18 20:31 2037-26-5
Page 12 of 34

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92395744
Sample: 3902-MW4 Lab ID: 92395744004 Collected: 08/13/18 13:04 Received: 08/14/18 10:41 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Antimony
ND
ug/L
6.0
3.9
1
08/15/18 08:30
08/19/18 21:46
7440-36-0
Arsenic
ND
ug/L
10.0
5.0
1
08/15/18 08:30
08/19/18 21:46
7440-38-2
Barium
ND
ug/L
100
2.5
1
08/15/18 08:30
08/19/18 21:46
7440-39-3
Beryllium
ND
ug/L
1.0
0.50
1
08/15/18 08:30
08/19/18 21:46
7440-41-7
Cadmium
ND
ug/L
1.0
0.50
1
08/15/18 08:30
08/19/18 21:46
7440-43-9
Chromium
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:46
7440-47-3
Cobalt
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:46
7440-48-4
Copper
3.7J
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:46
7440-50-8
Lead
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:46
7439-92-1
Nickel
12.3J
ug/L
50.0
2.5
1
08/15/18 08:30
08/19/18 21:46
7440-02-0
Selenium
ND
ug/L
10.0
5.0
1
08/15/18 08:30
08/19/18 21:46
7782-49-2
Silver
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:46
7440-22-4
Vanadium
20.4J
ug/L
25.0
2.5
1
08/15/18 08:30
08/19/18 21:46
7440-62-2
Zinc
ND
ug/L
10.0
5.0
1
08/15/18 08:30
08/19/18 21:46
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method:
EPA
3010A
Thallium
ND
ug/L
5.5
0.020
1
08/15/18 03:45
08/23/18 21:40
7440-28-0
8260 MSV Low Level Landfill
Analytical Method: EPA 8260E
Acetone
ND
ug/L
100
10.0
1
08/19/18 13:38
67-64-1
Acrylonitrile
ND
ug/L
200
1.9
1
08/19/18 13:38
107-13-1
Benzene
0.29J
ug/L
1.0
0.25
1
08/19/18 13:38
71-43-2
Bromochloromethane
ND
ug/L
3.0
0.17
1
08/19/18 13:38
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.18
1
08/19/18 13:38
75-27-4
Bromoform
ND
ug/L
3.0
0.26
1
08/19/18 13:38
75-25-2
Bromomethane
ND
ug/L
10.0
0.29
1
08/19/18 13:38
74-83-9
2-Butanone (MEK)
ND
ug/L
100
0.96
1
08/19/18 13:38
78-93-3
Carbon disulfide
ND
ug/L
100
1.2
1
08/19/18 13:38
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.25
1
08/19/18 13:38
56-23-5
Chlorobenzene
3.4
ug/L
3.0
0.23
1
08/19/18 13:38
108-90-7
Chloroethane
1.4J
ug/L
10.0
0.54
1
08/19/18 13:38
75-00-3
Chloroform
ND
ug/L
5.0
0.14
1
08/19/18 13:38
67-66-3
Chloromethane
ND
ug/L
1.0
0.11
1
08/19/18 13:38
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
13.0
2.0
1
08/19/18 13:38
96-12-8
Dibromochloromethane
ND
ug/L
3.0
0.21
1
08/19/18 13:38
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
08/19/18 13:38
106-93-4
Dibromomethane
ND
ug/L
10.0
0.21
1
08/19/18 13:38
74-95-3
1,2-Dichlorobenzene
ND
ug/L
5.0
0.30
1
08/19/18 13:38
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
08/19/18 13:38
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
100
1.0
1
08/19/18 13:38
110-57-6
1,1-Dichloroethane
0.37J
ug/L
5.0
0.32
1
08/19/18 13:38
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.24
1
08/19/18 13:38
107-06-2
1,1-Dichloroethene
ND
ug/L
5.0
0.56
1
08/19/18 13:38
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
5.0
0.19
1
08/19/18 13:38
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
5.0
0.49
1
08/19/18 13:38
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.27
1
08/19/18 13:38
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:30 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 34

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92395744
Sample: 3902-MW4 Lab ID: 92395744004 Collected: 08/13/18 13:04 Received: 08/14/18 10:41 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260 MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 08/24/2018 02:30 PM
Analytical Method: EPA 8260E
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
50.0
ND
ug/L
10.0
ND
ug/L
1.0
ND
ug/L
100
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
3.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
50.0
ND
ug/L
1.0
ND
ug/L
5.0
96
%
70-130
102
%
70-130
99
%
70-130
Analytical Method: EPA 8260E Mod.
40.7
ug/L
2.0
101
%
50-150
112
%
50-150
0.13
1
08/19/18 13:38
10061-01-5
0.26
1
08/19/18 13:38
10061-02-6
0.30
1
08/19/18 13:38
100-41-4
0.46
1
08/19/18 13:38
591-78-6
0.32
1
08/19/18 13:38
74-88-4
0.97
1
08/19/18 13:38
75-09-2
0.33
1
08/19/18 13:38
108-10-1
0.26
1
08/19/18 13:38
100-42-5
0.33
1
08/19/18 13:38
630-20-6
0.40
1
08/19/18 13:38
79-34-5
0.46
1
08/19/18 13:38
127-18-4
0.26
1
08/19/18 13:38
108-88-3
0.48
1
08/19/18 13:38
71-55-6
0.29
1
08/19/18 13:38
79-00-5
0.47
1
08/19/18 13:38
79-01-6
0.20
1
08/19/18 13:38
75-69-4
0.41
1
08/19/18 13:38
96-18-4
0.35
1
08/19/18 13:38
108-05-4
0.62
1
08/19/18 13:38
75-01-4
0.66
1
08/19/18 13:38
1330-20-7
1
08/19/18 13:38
460-00-4
1
08/19/18 13:38
17060-07-0
1
08/19/18 13:38
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
08/21/18 20:50 123-91-1
08/21 /18 20:50 17060-07-0
08/21 /18 20:50 2037-26-5
Page 14 of 34

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92395744
Sample: 3902-MW5 Lab ID: 92395744005 Collected: 08/13/18 14:01 Received: 08/14/18 10:41 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260 MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
Date: 08/24/2018 02:30 PM
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
ND
ug/L
6.0
3.9
1
08/15/18 08:30
08/19/18 21:49
7440-36-0
ND
ug/L
10.0
5.0
1
08/15/18 08:30
08/19/18 21:49
7440-38-2
103
ug/L
100
2.5
1
08/15/18 08:30
08/19/18 21:49
7440-39-3
ND
ug/L
1.0
0.50
1
08/15/18 08:30
08/19/18 21:49
7440-41-7
ND
ug/L
1.0
0.50
1
08/15/18 08:30
08/19/18 21:49
7440-43-9
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:49
7440-47-3
97.7
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:49
7440-48-4
48.8
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:49
7440-50-8
4.6J
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:49
7439-92-1
21.9J
ug/L
50.0
2.5
1
08/15/18 08:30
08/19/18 21:49
7440-02-0
ND
ug/L
10.0
5.0
1
08/15/18 08:30
08/19/18 21:49
7782-49-2
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:49
7440-22-4
2.9J
ug/L
25.0
2.5
1
08/15/18 08:30
08/19/18 21:49
7440-62-2
8.1J
ug/L
10.0
5.0
1
08/15/18 08:30
08/19/18 21:49
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
0.037J ug/L 5.5 0.020 1 08/15/18 03:45 08/23/18 21:43 7440-28-0
Analytical Method: EPA 8260E
ND
ug/L
100
10.0
1
08/19/1813:54
67-64-1
ND
ug/L
200
1.9
1
08/19/1813:54
107-13-1
ND
ug/L
1.0
0.25
1
08/19/1813:54
71-43-2
ND
ug/L
3.0
0.17
1
08/19/1813:54
74-97-5
ND
ug/L
1.0
0.18
1
08/19/1813:54
75-27-4
ND
ug/L
3.0
0.26
1
08/19/1813:54
75-25-2
ND
ug/L
10.0
0.29
1
08/19/1813:54
74-83-9
ND
ug/L
100
0.96
1
08/19/1813:54
78-93-3
ND
ug/L
100
1.2
1
08/19/1813:54
75-15-0
ND
ug/L
1.0
0.25
1
08/19/1813:54
56-23-5
ND
ug/L
3.0
0.23
1
08/19/1813:54
108-90-7
ND
ug/L
10.0
0.54
1
08/19/1813:54
75-00-3
ND
ug/L
5.0
0.14
1
08/19/1813:54
67-66-3
ND
ug/L
1.0
0.11
1
08/19/1813:54
74-87-3
ND
ug/L
13.0
2.0
1
08/19/1813:54
96-12-8
ND
ug/L
3.0
0.21
1
08/19/1813:54
124-48-1
ND
ug/L
1.0
0.27
1
08/19/1813:54
106-93-4
ND
ug/L
10.0
0.21
1
08/19/1813:54
74-95-3
ND
ug/L
5.0
0.30
1
08/19/1813:54
95-50-1
ND
ug/L
1.0
0.33
1
08/19/1813:54
106-46-7
ND
ug/L
100
1.0
1
08/19/1813:54
110-57-6
ND
ug/L
5.0
0.32
1
08/19/1813:54
75-34-3
ND
ug/L
1.0
0.24
1
08/19/1813:54
107-06-2
ND
ug/L
5.0
0.56
1
08/19/1813:54
75-35-4
ND
ug/L
5.0
0.19
1
08/19/1813:54
156-59-2
ND
ug/L
5.0
0.49
1
08/19/1813:54
156-60-5
ND
ug/L
1.0
0.27
1
08/19/1813:54
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 34

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92395744
Sample: 3902-MW5 Lab ID: 92395744005 Collected: 08/13/18 14:01 Received: 08/14/18 10:41 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260 MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 08/24/2018 02:30 PM
Analytical Method: EPA 8260E
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
50.0
ND
ug/L
10.0
ND
ug/L
1.0
ND
ug/L
100
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
3.0
ND
ug/L
1.0
0.44J
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
50.0
ND
ug/L
1.0
ND
ug/L
5.0
94
%
70-130
102
%
70-130
101
%
70-130
Analytical Method: EPA 8260E Mod.
2.OJ
ug/L
2.0
100
%
50-150
112
%
50-150
0.13
1
08/19/18 13:54
10061-01-5
0.26
1
08/19/18 13:54
10061-02-6
0.30
1
08/19/18 13:54
100-41-4
0.46
1
08/19/18 13:54
591-78-6
0.32
1
08/19/18 13:54
74-88-4
0.97
1
08/19/18 13:54
75-09-2
0.33
1
08/19/18 13:54
108-10-1
0.26
1
08/19/18 13:54
100-42-5
0.33
1
08/19/18 13:54
630-20-6
0.40
1
08/19/18 13:54
79-34-5
0.46
1
08/19/18 13:54
127-18-4
0.26
1
08/19/18 13:54
108-88-3
0.48
1
08/19/18 13:54
71-55-6
0.29
1
08/19/18 13:54
79-00-5
0.47
1
08/19/18 13:54
79-01-6
0.20
1
08/19/18 13:54
75-69-4
0.41
1
08/19/18 13:54
96-18-4
0.35
1
08/19/18 13:54
108-05-4
0.62
1
08/19/18 13:54
75-01-4
0.66
1
08/19/18 13:54
1330-20-7
1
08/19/18 13:54
460-00-4
1
08/19/18 13:54
17060-07-0
1
08/19/18 13:54
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
08/21/18 21:10 123-91-1
08/21 /18 21:10 17060-07-0
08/21 /18 21:10 2037-26-5
Page 16 of 34

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92395744
Sample: 3902-SW1 Lab ID: 92395744006 Collected: 08/13/18 13:46 Received: 08/14/18 10:41 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Antimony
ND
ug/L
6.0
3.9
1
08/15/18 08:30
08/19/18 21:52
7440-36-0
Arsenic
ND
ug/L
10.0
5.0
1
08/15/18 08:30
08/19/18 21:52
7440-38-2
Barium
70.OJ
ug/L
100
2.5
1
08/15/18 08:30
08/19/18 21:52
7440-39-3
Beryllium
ND
ug/L
1.0
0.50
1
08/15/18 08:30
08/19/18 21:52
7440-41-7
Cadmium
ND
ug/L
1.0
0.50
1
08/15/18 08:30
08/19/18 21:52
7440-43-9
Chromium
5.9J
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:52
7440-47-3
Cobalt
6.OJ
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:52
7440-48-4
Copper
4.1J
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:52
7440-50-8
Lead
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:52
7439-92-1
Nickel
7.3J
ug/L
50.0
2.5
1
08/15/18 08:30
08/19/18 21:52
7440-02-0
Selenium
ND
ug/L
10.0
5.0
1
08/15/18 08:30
08/19/18 21:52
7782-49-2
Silver
ND
ug/L
10.0
2.5
1
08/15/18 08:30
08/19/18 21:52
7440-22-4
Vanadium
8.3J
ug/L
25.0
2.5
1
08/15/18 08:30
08/19/18 21:52
7440-62-2
Zinc
6.OJ
ug/L
10.0
5.0
1
08/15/18 08:30
08/19/18 21:52
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method:
EPA
3010A
Thallium
ND
ug/L
5.5
0.020
1
08/15/18 03:45
08/23/18 21:46
7440-28-0
8260 MSV Low Level Landfill
Analytical Method: EPA 8260E
Acetone
ND
ug/L
100
10.0
1
08/19/18 14:10
67-64-1
Acrylonitrile
ND
ug/L
200
1.9
1
08/19/18 14:10
107-13-1
Benzene
ND
ug/L
1.0
0.25
1
08/19/18 14:10
71-43-2
Bromochloromethane
ND
ug/L
3.0
0.17
1
08/19/18 14:10
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.18
1
08/19/18 14:10
75-27-4
Bromoform
ND
ug/L
3.0
0.26
1
08/19/18 14:10
75-25-2
Bromomethane
ND
ug/L
10.0
0.29
1
08/19/18 14:10
74-83-9
2-Butanone (MEK)
ND
ug/L
100
0.96
1
08/19/18 14:10
78-93-3
Carbon disulfide
ND
ug/L
100
1.2
1
08/19/18 14:10
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.25
1
08/19/18 14:10
56-23-5
Chlorobenzene
ND
ug/L
3.0
0.23
1
08/19/18 14:10
108-90-7
Chloroethane
ND
ug/L
10.0
0.54
1
08/19/18 14:10
75-00-3
Chloroform
ND
ug/L
5.0
0.14
1
08/19/18 14:10
67-66-3
Chloromethane
ND
ug/L
1.0
0.11
1
08/19/18 14:10
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
13.0
2.0
1
08/19/18 14:10
96-12-8
Dibromochloromethane
ND
ug/L
3.0
0.21
1
08/19/18 14:10
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
08/19/18 14:10
106-93-4
Dibromomethane
ND
ug/L
10.0
0.21
1
08/19/18 14:10
74-95-3
1,2-Dichlorobenzene
ND
ug/L
5.0
0.30
1
08/19/18 14:10
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
08/19/18 14:10
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
100
1.0
1
08/19/18 14:10
110-57-6
1,1-Dichloroethane
ND
ug/L
5.0
0.32
1
08/19/18 14:10
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.24
1
08/19/18 14:10
107-06-2
1,1-Dichloroethene
ND
ug/L
5.0
0.56
1
08/19/18 14:10
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
5.0
0.19
1
08/19/18 14:10
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
5.0
0.49
1
08/19/18 14:10
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.27
1
08/19/18 14:10
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:30 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 34

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92395744
Sample: 3902-SW1 Lab ID: 92395744006 Collected: 08/13/18 13:46 Received: 08/14/18 10:41 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260 MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 08/24/2018 02:30 PM
Analytical Method: EPA 8260E
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
50.0
ND
ug/L
10.0
ND
ug/L
1.0
ND
ug/L
100
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
3.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
50.0
ND
ug/L
1.0
ND
ug/L
5.0
94
%
70-130
100
%
70-130
100
%
70-130
Analytical Method: EPA 8260E Mod.
ND
ug/L
2.0
101
%
50-150
112
%
50-150
0.13
1
08/19/18 14:10
10061-01-5
0.26
1
08/19/18 14:10
10061-02-6
0.30
1
08/19/18 14:10
100-41-4
0.46
1
08/19/18 14:10
591-78-6
0.32
1
08/19/18 14:10
74-88-4
0.97
1
08/19/18 14:10
75-09-2
0.33
1
08/19/18 14:10
108-10-1
0.26
1
08/19/18 14:10
100-42-5
0.33
1
08/19/18 14:10
630-20-6
0.40
1
08/19/18 14:10
79-34-5
0.46
1
08/19/18 14:10
127-18-4
0.26
1
08/19/18 14:10
108-88-3
0.48
1
08/19/18 14:10
71-55-6
0.29
1
08/19/18 14:10
79-00-5
0.47
1
08/19/18 14:10
79-01-6
0.20
1
08/19/18 14:10
75-69-4
0.41
1
08/19/18 14:10
96-18-4
0.35
1
08/19/18 14:10
108-05-4
0.62
1
08/19/18 14:10
75-01-4
0.66
1
08/19/18 14:10
1330-20-7
1
08/19/18 14:10
460-00-4
1
08/19/18 14:10
17060-07-0
1
08/19/18 14:10
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
08/21/18 21:29 123-91-1
08/21 /18 21:29 17060-07-0
08/21 /18 21:29 2037-26-5
Page 18 of 34

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92395744
Sample: 3902-Trip Blank Lab ID: 92395744007 Collected: 08/13/18 05:30 Received: 08/14/18 10:41 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill Analytical Method: EPA 8260E
Acetone
ND
ug/L
100
10.0
1
08/19/18 14:26
67-64-1
Acrylonitrile
ND
ug/L
200
1.9
1
08/19/18 14:26
107-13-1
Benzene
ND
ug/L
1.0
0.25
1
08/19/18 14:26
71-43-2
Bromochloromethane
ND
ug/L
3.0
0.17
1
08/19/18 14:26
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.18
1
08/19/18 14:26
75-27-4
Bromoform
ND
ug/L
3.0
0.26
1
08/19/18 14:26
75-25-2
Bromomethane
ND
ug/L
10.0
0.29
1
08/19/18 14:26
74-83-9
2-Butanone (MEK)
ND
ug/L
100
0.96
1
08/19/18 14:26
78-93-3
Carbon disulfide
ND
ug/L
100
1.2
1
08/19/18 14:26
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.25
1
08/19/18 14:26
56-23-5
Chlorobenzene
ND
ug/L
3.0
0.23
1
08/19/18 14:26
108-90-7
Chloroethane
ND
ug/L
10.0
0.54
1
08/19/18 14:26
75-00-3
Chloroform
ND
ug/L
5.0
0.14
1
08/19/18 14:26
67-66-3
Chloromethane
ND
ug/L
1.0
0.11
1
08/19/18 14:26
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
13.0
2.0
1
08/19/18 14:26
96-12-8
Dibromochloromethane
ND
ug/L
3.0
0.21
1
08/19/18 14:26
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
08/19/18 14:26
106-93-4
Dibromomethane
ND
ug/L
10.0
0.21
1
08/19/18 14:26
74-95-3
1,2-Dichlorobenzene
ND
ug/L
5.0
0.30
1
08/19/18 14:26
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
08/19/18 14:26
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
100
1.0
1
08/19/18 14:26
110-57-6
1,1-Dichloroethane
ND
ug/L
5.0
0.32
1
08/19/18 14:26
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.24
1
08/19/18 14:26
107-06-2
1,1-Dichloroethene
ND
ug/L
5.0
0.56
1
08/19/18 14:26
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
5.0
0.19
1
08/19/18 14:26
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
5.0
0.49
1
08/19/18 14:26
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.27
1
08/19/18 14:26
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.13
1
08/19/18 14:26
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.26
1
08/19/18 14:26
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.30
1
08/19/18 14:26
100-41-4
2-Hexanone
ND
ug/L
50.0
0.46
1
08/19/18 14:26
591-78-6
lodomethane
ND
ug/L
10.0
0.32
1
08/19/18 14:26
74-88-4
Methylene Chloride
ND
ug/L
1.0
0.97
1
08/19/18 14:26
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
100
0.33
1
08/19/18 14:26
108-10-1
Styrene
ND
ug/L
1.0
0.26
1
08/19/18 14:26
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
5.0
0.33
1
08/19/18 14:26
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
3.0
0.40
1
08/19/18 14:26
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.46
1
08/19/18 14:26
127-18-4
Toluene
ND
ug/L
1.0
0.26
1
08/19/18 14:26
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.48
1
08/19/18 14:26
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.29
1
08/19/18 14:26
79-00-5
Trichloroethene
ND
ug/L
1.0
0.47
1
08/19/18 14:26
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.20
1
08/19/18 14:26
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.41
1
08/19/18 14:26
96-18-4
Vinyl acetate
ND
ug/L
50.0
0.35
1
08/19/18 14:26
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.62
1
08/19/18 14:26
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:30 PM without the written consent of Pace Analytical Services, LLC.
Page 19 of 34

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ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92395744
Sample: 3902-Trip Blank
Lab ID:
92395744007
Collected:
08/13/18 05:30
Received: 08/14/18 10:41 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL DF
Prepared Analyzed
CAS No. Qual
8260 MSV Low Level Landfill
Analytical
Method: EPA 8260E
Xylene (Total)
ND
ug/L
5.0
0.66 1
08/19/18 14:26
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
95
%
70-130
1
08/19/18 14:26
460-00-4
1,2-Dichloroethane-d4 (S)
99
%
70-130
1
08/19/18 14:26
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
08/19/18 14:26
2037-26-5
Date: 08/24/2018 02:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 20 of 34

aceAnalytical
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92395744
QC Batch: 424982 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Associated Lab Samples: 92395744001, 92395744002, 92395744003, 92395744004, 92395744005, 92395744006
METHOD BLANK: 2350347 Matrix: Water
Associated Lab Samples: 92395744001, 92395744002, 92395744003, 92395744004, 92395744005, 92395744006
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Antimony
ug/L
ND
6.0
3.9
08/16/1816:44
Arsenic
ug/L
ND
10.0
5.0
08/16/1816:44
Barium
ug/L
ND
100
2.5
08/16/1816:44
Beryllium
ug/L
ND
1.0
0.50
08/16/1816:44
Cadmium
ug/L
ND
1.0
0.50
08/16/1816:44
Chromium
ug/L
ND
10.0
2.5
08/16/1816:44
Cobalt
ug/L
ND
10.0
2.5
08/16/1816:44
Copper
ug/L
ND
10.0
2.5
08/16/1816:44
Lead
ug/L
ND
10.0
2.5
08/16/1816:44
Nickel
ug/L
ND
50.0
2.5
08/16/1816:44
Selenium
ug/L
ND
10.0
5.0
08/16/1816:44
Silver
ug/L
ND
10.0
2.5
08/16/1816:44
Tin
ug/L
ND
100
2.5
08/16/1816:44
Vanadium
ug/L
ND
25.0
2.5
08/16/1816:44
Zinc
ug/L
ND
10.0
5.0
08/16/1816:44
LABORATORY CONTROL SAMPLE:
2350348
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Antimony
ug/L
500
490
98
80-120
Arsenic
ug/L
500
482
96
80-120
Barium
ug/L
500
501
100
80-120
Beryllium
ug/L
500
496
99
80-120
Cadmium
ug/L
500
489
98
80-120
Chromium
ug/L
500
499
100
80-120
Cobalt
ug/L
500
494
99
80-120
Copper
ug/L
500
506
101
80-120
Lead
ug/L
500
481
96
80-120
Nickel
ug/L
500
489
98
80-120
Selenium
ug/L
500
455
91
80-120
Silver
ug/L
250
253
101
80-120
Tin
ug/L
500
498
100
80-120
Vanadium
ug/L
500
499
100
80-120
Zinc
ug/L
500
481
96
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:30 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 34

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Butner Landfill Compliance
92395744
MATRIX SPIKE &
MATRIX SPIKE DUPLICATE:
2350349
2350350
MS
MSD
92395744001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
500
500
506
509
101
102
75-125
1
20
Arsenic
ug/L
ND
500
500
497
504
99
100
75-125
1
20
Barium
ug/L
3.8J
500
500
517
519
103
103
75-125
0
20
Beryllium
ug/L
ND
500
500
521
523
104
105
75-125
0
20
Cadmium
ug/L
ND
500
500
506
508
101
102
75-125
0
20
Chromium
ug/L
ND
500
500
510
512
102
102
75-125
0
20
Cobalt
ug/L
ND
500
500
497
500
99
100
75-125
1
20
Copper
ug/L
ND
500
500
518
521
103
104
75-125
1
20
Lead
ug/L
ND
500
500
492
495
98
99
75-125
1
20
Nickel
ug/L
ND
500
500
497
500
99
100
75-125
1
20
Selenium
ug/L
ND
500
500
500
501
100
100
75-125
0
20
Silver
ug/L
ND
250
250
256
259
103
104
75-125
1
20
Tin
ug/L
ND
500
500
508
512
101
102
75-125
1
20
Vanadium
ug/L
ND
500
500
509
514
101
102
75-125
1
20
Zinc
ug/L
ND
500
500
500
504
99
100
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:30 PM without the written consent of Pace Analytical Services, LLC.
Page 22 of 34

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92395744
QC Batch: 424971 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Associated Lab Samples: 92395744001, 92395744002, 92395744003, 92395744004, 92395744005, 92395744006
METHOD BLANK: 2350297 Matrix: Water
Associated Lab Samples: 92395744001, 92395744002, 92395744003, 92395744004, 92395744005, 92395744006
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Thallium ug/L ND 5.5 0.020 08/23/18 21:11
LABORATORY CONTROL SAMPLE: 2350298
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Thallium ug/L 10 9.9 99 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2350299 2350300
MS MSD
92395744001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Thallium ug/L ND 10 10 10.0 9.9 100 99 75-125 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:30 PM without the written consent of Pace Analytical Services, LLC.
Page 23 of 34

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92395744
QC Batch: 425801 Analysis Method: EPA 8260B
QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill
Associated Lab Samples: 92395744001, 92395744002, 92395744003, 92395744004, 92395744005, 92395744006, 92395744007
METHOD BLANK: 2354038 Matrix: Water
Associated Lab Samples: 92395744001, 92395744002, 92395744003, 92395744004, 92395744005, 92395744006, 92395744007
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
5.0
0.33
08/19/18 12:01
1,1,1-Trichloroethane
ug/L
ND
1.0
0.48
08/19/18 12:01
1,1,2,2-Tetrachloroethane
ug/L
ND
3.0
0.40
08/19/18 12:01
1,1,2-Trichloroethane
ug/L
ND
1.0
0.29
08/19/18 12:01
1,1-Dichloroethane
ug/L
ND
5.0
0.32
08/19/18 12:01
1,1-Dichloroethene
ug/L
ND
5.0
0.56
08/19/18 12:01
1,2,3-Trichloropropane
ug/L
ND
1.0
0.41
08/19/18 12:01
1,2-Dibromo-3-chloropropane
ug/L
ND
13.0
2.0
08/19/18 12:01
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
08/19/18 12:01
1,2-Dichlorobenzene
ug/L
ND
5.0
0.30
08/19/18 12:01
1,2-Dichloroethane
ug/L
ND
1.0
0.24
08/19/18 12:01
1,2-Dichloropropane
ug/L
ND
1.0
0.27
08/19/18 12:01
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
08/19/18 12:01
2-Butanone (MEK)
ug/L
ND
100
0.96
08/19/18 12:01
2-Hexanone
ug/L
ND
50.0
0.46
08/19/18 12:01
4-Methyl-2-pentanone (MIBK)
ug/L
ND
100
0.33
08/19/18 12:01
Acetone
ug/L
ND
100
10.0
08/19/18 12:01
Acrylonitrile
ug/L
ND
200
1.9
08/19/18 12:01
Benzene
ug/L
ND
1.0
0.25
08/19/18 12:01
Bromochloromethane
ug/L
ND
3.0
0.17
08/19/18 12:01
Bromodichloromethane
ug/L
ND
1.0
0.18
08/19/18 12:01
Bromoform
ug/L
ND
3.0
0.26
08/19/18 12:01
Bromomethane
ug/L
ND
10.0
0.29
08/19/18 12:01
Carbon disulfide
ug/L
ND
100
1.2
08/19/18 12:01
Carbon tetrachloride
ug/L
ND
1.0
0.25
08/19/18 12:01
Chlorobenzene
ug/L
ND
3.0
0.23
08/19/18 12:01
Chloroethane
ug/L
ND
10.0
0.54
08/19/18 12:01
Chloroform
ug/L
ND
5.0
0.14
08/19/18 12:01
Chloromethane
ug/L
ND
1.0
0.11
08/19/18 12:01
cis-1,2-Dichloroethene
ug/L
ND
5.0
0.19
08/19/18 12:01
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.13
08/19/18 12:01
Dibromochloromethane
ug/L
ND
3.0
0.21
08/19/18 12:01
Dibromomethane
ug/L
ND
10.0
0.21
08/19/18 12:01
Ethylbenzene
ug/L
ND
1.0
0.30
08/19/18 12:01
lodomethane
ug/L
ND
10.0
0.32
08/19/18 12:01
Methylene Chloride
ug/L
ND
1.0
0.97
08/19/18 12:01
Styrene
ug/L
ND
1.0
0.26
08/19/18 12:01
Tetrachloroethene
ug/L
ND
1.0
0.46
08/19/18 12:01
Toluene
ug/L
ND
1.0
0.26
08/19/18 12:01
trans-1,2-Dichloroethene
ug/L
ND
5.0
0.49
08/19/18 12:01
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.26
08/19/18 12:01
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:30 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 34

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92395744
METHOD BLANK: 2354038 Matrix: Water
Associated Lab Samples: 92395744001, 92395744002, 92395744003, 92395744004, 92395744005, 92395744006, 92395744007
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
trans-1,4-Dichloro-2-butene
ug/L
ND
100
1.0
08/19/18 12:01
Trichloroethene
ug/L
ND
1.0
0.47
08/19/18 12:01
Trichlorofluoromethane
ug/L
ND
1.0
0.20
08/19/18 12:01
Vinyl acetate
ug/L
ND
50.0
0.35
08/19/18 12:01
Vinyl chloride
ug/L
ND
1.0
0.62
08/19/18 12:01
Xylene (Total)
ug/L
ND
5.0
0.66
08/19/18 12:01
1,2-Dichloroethane-d4 (S)
%
98
70-130
08/19/18 12:01
4-Bromofluorobenzene (S)
%
96
70-130
08/19/18 12:01
Toluene-d8 (S)
%
100
70-130
08/19/18 12:01
LABORATORY CONTROL SAMPLE:
Parameter
2354039
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
50
51.6
103
80-125
1,1,1-Trichloroethane
ug/L
50
51.1
102
71-129
1,1,2,2-Tetrachloroethane
ug/L
50
49.3
99
79-124
1,1,2-Trichloroethane
ug/L
50
50.4
101
85-125
1,1-Dichloroethane
ug/L
50
46.8
94
73-126
1,1-Dichloroethene
ug/L
50
52.2
104
66-135
1,2,3-Trichloropropane
ug/L
50
48.5
97
75-130
1,2-Dibromo-3-chloropropane
ug/L
50
51.2
102
71-133
1,2-Dibromoethane (EDB)
ug/L
50
53.0
106
83-124
1,2-Dichlorobenzene
ug/L
50
49.2
98
80-133
1,2-Dichloroethane
ug/L
50
50.1
100
67-128
1,2-Dichloropropane
ug/L
50
50.1
100
75-132
1,4-Dichlorobenzene
ug/L
50
47.7
95
78-130
2-Butanone (MEK)
ug/L
100
96.2J
96
61-144
2-Hexanone
ug/L
100
100
100
68-143
4-Methyl-2-pentanone (MIBK)
ug/L
100
98AJ
98
72-135
Acetone
ug/L
100
112
112
48-146
Acrylonitrile
ug/L
250
248
99
40-160
Benzene
ug/L
50
49.1
98
80-125
Bromochloromethane
ug/L
50
52.0
104
71-125
Bromodichloromethane
ug/L
50
53.3
107
78-124
Bromoform
ug/L
50
51.1
102
71-128
Bromomethane
ug/L
50
37.9
76
40-160
Carbon disulfide
ug/L
50
51.3J
103
50-160
Carbon tetrachloride
ug/L
50
52.9
106
69-131
Chlorobenzene
ug/L
50
49.4
99
81-122
Chloroethane
ug/L
50
43.1
86
39-148
Chloroform
ug/L
50
51.7
103
73-127
Chloromethane
ug/L
50
44.4
89
44-146
cis-1,2-Dichloroethene
ug/L
50
49.2
98
74-124
cis-1,3-Dichloropropene
ug/L
50
50.2
100
72-132
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:30 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 34

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92395744
LABORATORY CONTROL SAMPLE:
2354039
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Dibromochloromethane
ug/L
50
51.3
103
78-125
Dibromomethane
ug/L
50
54.0
108
82-120
Ethylbenzene
ug/L
50
48.9
98
79-121
lodomethane
ug/L
100
98.6
99
39-154
Methylene Chloride
ug/L
50
51.6
103
64-133
Styrene
ug/L
50
49.4
99
84-126
Tetrachloroethene
ug/L
50
48.4
97
78-122
Toluene
ug/L
50
47.9
96
80-121
trans-1,2-Dichloroethene
ug/L
50
50.8
102
71-127
trans- 1,3-Dichloropropene
ug/L
50
50.8
102
69-141
trans-1,4-Dichloro-2-butene
ug/L
50
52.6J
105
40-160
Trichloroethene
ug/L
50
52.8
106
78-122
Trichlorofluoromethane
ug/L
50
51.2
102
53-137
Vinyl acetate
ug/L
100
98.1
98
40-160
Vinyl chloride
ug/L
50
51.5
103
58-137
Xylene (Total)
ug/L
150
149
99
81-126
1,2-Dichloroethane-d4 (S)
%
100
70-130
4-Bromofluorobenzene (S)
%
97
70-130
Toluene-d8 (S)
%
97
70-130
MATRIX SPIKE SAMPLE:
2354041
92395744002
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
19.3
96
70-130
1,1,1-Trichloroethane
ug/L
ND
20
20.7
103
70-130
1,1,2,2-Tetrachloroethane
ug/L
ND
20
18.9
94
70-130
1,1,2-Trichloroethane
ug/L
ND
20
19.4
97
70-130
1,1-Dichloroethane
ug/L
ND
20
19.3
97
70-130
1,1-Dichloroethene
ug/L
ND
20
21.8
109
70-166
1,2,3-Trichloropropane
ug/L
ND
20
18.8
94
70-130
1,2-Dibromo-3-chloropropane
ug/L
ND
20
18.0
90
70-130
1,2-Dibromoethane (EDB)
ug/L
ND
20
20.0
100
70-130
1,2-Dichlorobenzene
ug/L
1.2J
20
20.7
97
70-130
1,2-Dichloroethane
ug/L
ND
20
19.9
99
70-130
1,2-Dichloropropane
ug/L
ND
20
19.5
98
70-130
1,4-Dichlorobenzene
ug/L
1.9
20
20.2
92
70-130
2-Butanone (MEK)
ug/L
ND
40
39.OJ
97
70-130
2-Hexanone
ug/L
ND
40
37.2J
93
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
37.9J
95
70-130
Acetone
ug/L
ND
40
53.5J
134
70-130 M1
Acrylonitrile
ug/L
ND
100
97.3J
97
70-130
Benzene
ug/L
1.3
20
21.2
100
70-148
Bromochloromethane
ug/L
ND
20
20.5
103
70-130
Bromodichloromethane
ug/L
ND
20
20.1
101
70-130
Bromoform
ug/L
ND
20
18.1
90
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:30 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 34

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92395744
MATRIX SPIKE SAMPLE:
Parameter
2354041
Units
92395744002
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Bromomethane
ug/L
ND
20
9.6J
48
70-130 M1
Carbon disulfide
ug/L
ND
20
20.OJ
100
70-130
Carbon tetrachloride
ug/L
ND
20
20.6
103
70-130
Chlorobenzene
ug/L
14.5
20
33.9
97
70-146
Chloroethane
ug/L
1.2J
20
19.4
91
70-130
Chloroform
ug/L
ND
20
20.0
100
70-130
Chloromethane
ug/L
ND
20
17.7
89
70-130
cis-1,2-Dichloroethene
ug/L
ND
20
19.9
100
70-130
cis-1,3-Dichloropropene
ug/L
ND
20
18.6
93
70-130
Dibromochloromethane
ug/L
ND
20
19.0
95
70-130
Dibromomethane
ug/L
ND
20
21.3
107
70-130
Ethylbenzene
ug/L
ND
20
19.3
97
70-130
lodomethane
ug/L
ND
40
36.3
91
70-130
Methylene Chloride
ug/L
ND
20
19.9
100
70-130
Styrene
ug/L
ND
20
18.8
94
70-130
Tetrachloroethene
ug/L
ND
20
19.5
97
70-130
Toluene
ug/L
ND
20
19.2
96
70-155
trans-1,2-Dichloroethene
ug/L
ND
20
20.7
103
70-130
trans- 1,3-Dichloropropene
ug/L
ND
20
18.9
94
70-130
trans-1,4-Dichloro-2-butene
ug/L
ND
20
15.OJ
75
70-130
Trichloroethene
ug/L
ND
20
21.0
105
69-151
Trichlorofluoromethane
ug/L
ND
20
22.4
112
70-130
Vinyl acetate
ug/L
ND
40
35.9J
90
70-130
Vinyl chloride
ug/L
ND
20
21.2
106
70-130
Xylene (Total)
ug/L
ND
60
58.3
97
70-130
1,2-Dichloroethane-d4 (S)
%
100
70-130
4-Bromofluorobenzene (S)
%
97
70-130
Toluene-d8 (S)
%
96
70-130
SAMPLE DUPLICATE: 2354040
Parameter
Units
92395744001
Result
Dup
Result RPD
Max
RPD Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
ND
ND
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
1,2-Dichlorobenzene
ug/L
ND
ND
30
1,2-Dichloroethane
ug/L
ND
ND
30
1,2-Dichloropropane
ug/L
ND
ND
30
1,4-Dichlorobenzene
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:30 PM without the written consent of Pace Analytical Services, LLC.
Page 27 of 34

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92395744
SAMPLE DUPLICATE: 2354040
Parameter
Units
92395744001
Result
2-Butanone (MEK)
ug/L
ND
2-Hexanone
ug/L
ND
4-Methyl-2-pentanone (MIBK)
ug/L
ND
Acetone
ug/L
ND
Acrylonitrile
ug/L
ND
Benzene
ug/L
ND
Bromochloromethane
ug/L
ND
Bromodichloromethane
ug/L
ND
Bromoform
ug/L
ND
Bromomethane
ug/L
ND
Carbon disulfide
ug/L
ND
Carbon tetrachloride
ug/L
ND
Chlorobenzene
ug/L
ND
Chloroethane
ug/L
ND
Chloroform
ug/L
ND
Chloromethane
ug/L
ND
cis-1,2-Dichloroethene
ug/L
ND
cis-1,3-Dichloropropene
ug/L
ND
Dibromochloromethane
ug/L
ND
Dibromomethane
ug/L
ND
Ethylbenzene
ug/L
ND
lodomethane
ug/L
ND
Methylene Chloride
ug/L
ND
Styrene
ug/L
ND
Tetrachloroethene
ug/L
ND
Toluene
ug/L
ND
trans-1,2-Dichloroethene
ug/L
ND
trans- 1,3-Dichloropropene
ug/L
ND
trans-1,4-Dichloro-2-butene
ug/L
ND
Trichloroethene
ug/L
ND
Trichlorofluoromethane
ug/L
ND
Vinyl acetate
ug/L
ND
Vinyl chloride
ug/L
ND
Xylene (Total)
ug/L
ND
1,2-Dichloroethane-d4 (S)
%
98
4-Bromofluorobenzene (S)
%
97
Toluene-d8 (S)
%
98
Dup
Result RPD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
102
95
99
3
2
0
Max
RPD Qualifiers
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:30 PM without the written consent of Pace Analytical Services, LLC.
Page 28 of 34

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92395744
QC Batch: 426080 Analysis Method: EPA 8260B Mod.
QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM
Associated Lab Samples: 92395744001, 92395744002, 92395744003, 92395744004, 92395744005, 92395744006
METHOD BLANK: 2355220
Matrix:
Water
Associated Lab Samples:
92395744001, 92395744002, 92395744003, 92395744004, 92395744005, 92395744006
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
1.9 08/21/18 15:18
1,2-Dichloroethane-d4 (S)
%
97
50-150
08/21/18 15:18
Toluene-d8 (S)
%
107
50-150
08/21/18 15:18
LABORATORY CONTROL SAMPLE: 2355221
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 17.7 88 71-125
1,2-Dichloroethane-d4 (S) % 97 50-150
Toluene-d8(S) % 107 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2355222
2355223
MS
MSD
92395199068 Spike
Spike MS
MSD MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 18.5
17.9 91
88
50-150
3 30
1,2-Dichloroethane-d4 (S)
%
105
104
50-150
30
Toluene-d8 (S)
%
114
113
50-150
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:30 PM without the written consent of Pace Analytical Services, LLC.
Page 29 of 34

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Butner Landfill Compliance
Pace Project No.: 92395744
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:30 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 34

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Butner Landfill Compliance
92395744
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92395744001
3902-MW1 R
EPA 3010A
424982
EPA 6010D
425053
92395744002
3902-MW2R
EPA 3010A
424982
EPA 6010D
425053
92395744003
3902-MW3R
EPA 3010A
424982
EPA 6010D
425053
92395744004
3902-MW4
EPA 3010A
424982
EPA 6010D
425053
92395744005
3902-MW5
EPA 3010A
424982
EPA 6010D
425053
92395744006
3902-SW1
EPA 3010A
424982
EPA 6010D
425053
92395744001
3902-MW1 R
EPA 3010A
424971
EPA 6020B
425054
92395744002
3902-MW2R
EPA 3010A
424971
EPA 6020B
425054
92395744003
3902-MW3R
EPA 3010A
424971
EPA 6020B
425054
92395744004
3902-MW4
EPA 3010A
424971
EPA 6020B
425054
92395744005
3902-MW5
EPA 3010A
424971
EPA 6020B
425054
92395744006
3902-SW1
EPA 3010A
424971
EPA 6020B
425054
92395744001
3902-MW1 R
EPA 8260B
425801
92395744002
3902-MW2R
EPA 8260B
425801
92395744003
3902-MW3R
EPA 8260B
425801
92395744004
3902-MW4
EPA 8260B
425801
92395744005
3902-MW5
EPA 8260B
425801
92395744006
3902-SW1
EPA 8260B
425801
92395744007
3902-Trip Blank
EPA 8260B
425801
92395744001
3902-MW1R
EPA 8260B Mod.
426080
92395744002
3902-MW2R
EPA 8260B Mod.
426080
92395744003
3902-MW3R
EPA 8260B Mod.
426080
92395744004
3902-MW4
EPA 8260B Mod.
426080
92395744005
3902-MW5
EPA 8260B Mod.
426080
92395744006
3902-SW1
EPA 8260B Mod.
426080
Date: 08/24/2018 02:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 31 of 34

Document Name:
Document Revised: February 7, 2018
aceAnaly jcal9
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
F•CAR-CS-033-Rev.06
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville� Raleigh[] Mechanicsville❑
Sample Condition Client Name: WO# : 92395744
Project #:
Courier: ❑Fed Ex ❑UPS ❑USPS []Client
❑ Commercial QPace ❑Other: s 923g 144
£tsstedy�eaFPresent? ❑Yea la seals Intact? ❑Yes QIVa =
Date/Initials Person Examining Contents: '
Packing Material: ❑Bubble Wrap
❑None ❑ Other
Thermome^teV Type of Ice: Aret ❑Blue
t'j� Gun lD: 92TO43
Cooler Temp VQ: 3 • Correction Factor: Add/Subtract (°C) _0 2
Cooler Temp Corrected (°C):
USDA Regulated Soil ( NIA, water sample)
Did samples origipate in a quarantine zone within the United States: CA, NY, or SC (check maps)?
n a I
EiTu—bble Bags
Biological Tissue Fro 0❑Yes ❑No nN/A
❑None
Temp should be above freezing to VC
❑samples out of temp criteria. Samples on ice, cooling process
has begun
Did samples originate from a foreign source (interna
includine Hawaii and Puerto Rico)? MYes o
Comments/Discrepancy:
Chain of Custody Present?
ffyes
❑No
❑N/A
1.
Samples Arrived within Hold Time?
2(es
[]No
❑N/A
2•
Short Hold Time Analysis (02 hr.)?
❑Yes
!o
❑N/A
3.
Rush Turn Around Time Requested?
a
❑N/A
4.
Sufficient Valli me?
,❑Yes
O res
❑No
❑N/A
5.
Correct Containers Used?
-Pace Containers Used?
[2Yes
❑No
❑No
[I N/A
❑N/A
6.
Containers Intact?
,�s
.y3Yes
❑No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
o
[_—]NIA
8.
Sample Labels Match COC?
-Includes Date/Time/ID/Analysis Matrix:
4 n V` Yes
V
[I No
❑N/A
9.
Headspace in VOA Vials (>S-6mm)?
]Yes
No
❑N/A
10,
Trip Blank Present?
Trip Blank Custody Seals Present?
es
es
[]No
[]No
[]N/A
❑N/A
11.
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review: 62�
Date/Time:
Field Data Required? ❑Yes ❑No
Lot ID of split containers:
Date:
Date: 4i, V
Page 32 of 34

Document Name:
Document Revised: February 7, 2018
2aceAnalyttal-
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
"Bottom half of box is to list number of bottle
Projec WO# ; 923g5744
PM: NMG Due Date: 08/28/18
CLIENT: 92-Joyce Eng
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Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 33 of 34

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Page 34 of 34

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
August 24, 2018
Mr. Van Burbach
Joyce Engineering -NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Butner Landfill Compliance
Pace Project No.: 92396141
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 16, 2018. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
��i Flo _ _.1I , .�:
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Mr. Daniel Girdner, LaBella Associates, D.P.C.
Miguel Vazquez, Joyce Engineering
Rochelle mesubed, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 27

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Butner Landfill Compliance
Pace Project No.: 92396141
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 27

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Butner Landfill Compliance
Pace Project No.: 92396141
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92396141001
3902-MW6
Water
08/14/1812:10
08/16/18 10:00
92396141002
3902-SW-2
Water
08/14/1813:16
08/16/18 10:00
92396141003
3902-NES-1
Water
08/15/18 06:19
08/16/18 10:00
92396141004
3902-Field Blank
Water
08/15/18 06:31
08/16/18 10:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 27

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Butner Landfill Compliance
92396141
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92396141001
3902-MW6
EPA 6010D
IDS
15
PASI-A
EPA6020B
JMW1
1
PASI-A
EPA 8260E
CAH
50
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
92396141002
3902-SW-2
EPA 6010D
DS
14
PASI-A
EPA6020B
JMW1
1
PASI-A
EPA 8260E
CAH
50
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
92396141003
3902-NES-1
EPA 8260E
CAH
4
PASI-C
92396141004
3902-Field Blank
EPA 6010D
IDS
15
PASI-A
EPA6020B
JMW1
1
PASI-A
EPA 8260E
CAH
50
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 27

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
Butner Landfill Compliance
92396141
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92396141002
3902-SW-2
EPA 601 OD
Barium
86.6J
ug/L
100
08/21/18 22:34
EPA 601 OD
Nickel
12AJ
ug/L
50.0
08/21/18 22:34
EPA 601 OD
Vanadium
3.1 J
ug/L
25.0
08/21/18 22:34
EPA 8260B Mod.
1,4-Dioxane (p-Dioxane)
14.1
ug/L
2.0
08/21/18 22:08
92396141004
3902-Field Blank
EPA 8260B
Methylene Chloride
6.6
ug/L
1.0
08/19/18 16:04
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 27

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92396141
Sample: 3902-MW6 Lab ID: 92396141001 Collected: 08/14/18 12:10 Received: 08/16/18 10:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Tin
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260 MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Date: 08/24/2018 02:32 PM
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
ND
ug/L
6.0
3.9
1
08/17/18 07:28
08/21/18 22:11
7440-36-0
ND
ug/L
10.0
5.0
1
08/17/18 07:28
08/21/18 22:11
7440-38-2
ND
ug/L
100
2.5
1
08/17/18 07:28
08/21/18 22:11
7440-39-3
ND
ug/L
1.0
0.50
1
08/17/18 07:28
08/21/18 22:11
7440-41-7
ND
ug/L
1.0
0.50
1
08/17/18 07:28
08/21/18 22:11
7440-43-9
ND
ug/L
10.0
2.5
1
08/17/18 07:28
08/21/18 22:11
7440-47-3
ND
ug/L
10.0
2.5
1
08/17/18 07:28
08/21/18 22:11
7440-48-4
ND
ug/L
10.0
2.5
1
08/17/18 07:28
08/21/18 22:11
7440-50-8
ND
ug/L
10.0
2.5
1
08/17/18 07:28
08/21/18 22:11
7439-92-1
ND
ug/L
50.0
2.5
1
08/17/18 07:28
08/21/18 22:11
7440-02-0
ND
ug/L
10.0
5.0
1
08/17/18 07:28
08/21/18 22:11
7782-49-2
ND
ug/L
10.0
2.5
1
08/17/18 07:28
08/21/18 22:11
7440-22-4
ND
ug/L
100
2.5
1
08/17/18 07:28
08/21/18 22:11
7440-31-5
ND
ug/L
25.0
2.5
1
08/17/18 07:28
08/21/18 22:11
7440-62-2
ND
ug/L
10.0
5.0
1
08/17/18 07:28
08/21/18 22:11
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 5.5 0.020 1 08/17/18 07:17 08/23/18 22:15 7440-28-0
Analytical Method: EPA 8260E
ND
ug/L
100
10.0
1
08/19/1815:15
67-64-1
ND
ug/L
200
1.9
1
08/19/1815:15
107-13-1
ND
ug/L
1.0
0.25
1
08/19/1815:15
71-43-2
ND
ug/L
3.0
0.17
1
08/19/1815:15
74-97-5
ND
ug/L
1.0
0.18
1
08/19/1815:15
75-27-4
ND
ug/L
3.0
0.26
1
08/19/1815:15
75-25-2
ND
ug/L
10.0
0.29
1
08/19/1815:15
74-83-9
ND
ug/L
100
0.96
1
08/19/1815:15
78-93-3
ND
ug/L
100
1.2
1
08/19/1815:15
75-15-0
ND
ug/L
1.0
0.25
1
08/19/1815:15
56-23-5
ND
ug/L
3.0
0.23
1
08/19/1815:15
108-90-7
ND
ug/L
10.0
0.54
1
08/19/1815:15
75-00-3
ND
ug/L
5.0
0.14
1
08/19/1815:15
67-66-3
ND
ug/L
1.0
0.11
1
08/19/1815:15
74-87-3
ND
ug/L
13.0
2.0
1
08/19/1815:15
96-12-8
ND
ug/L
3.0
0.21
1
08/19/1815:15
124-48-1
ND
ug/L
1.0
0.27
1
08/19/1815:15
106-93-4
ND
ug/L
10.0
0.21
1
08/19/1815:15
74-95-3
ND
ug/L
5.0
0.30
1
08/19/1815:15
95-50-1
ND
ug/L
1.0
0.33
1
08/19/1815:15
106-46-7
ND
ug/L
100
1.0
1
08/19/1815:15
110-57-6
ND
ug/L
5.0
0.32
1
08/19/1815:15
75-34-3
ND
ug/L
1.0
0.24
1
08/19/1815:15
107-06-2
ND
ug/L
5.0
0.56
1
08/19/1815:15
75-35-4
ND
ug/L
5.0
0.19
1
08/19/1815:15
156-59-2
ND
ug/L
5.0
0.49
1
08/19/1815:15
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 27

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92396141
Sample: 3902-MW6 Lab ID: 92396141001 Collected: 08/14/18 12:10 Received: 08/16/18 10:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260 MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 08/24/2018 02:32 PM
Analytical Method: EPA 8260E
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
50.0
ND
ug/L
10.0
ND
ug/L
1.0
ND
ug/L
100
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
3.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
50.0
ND
ug/L
1.0
ND
ug/L
5.0
96
%
70-130
101
%
70-130
99
%
70-130
Analytical Method: EPA 8260E Mod.
ND
ug/L
2.0
99
%
50-150
111
%
50-150
0.27
1
08/19/18 15:15
78-87-5
0.13
1
08/19/18 15:15
10061-01-5
0.26
1
08/19/18 15:15
10061-02-6
0.30
1
08/19/18 15:15
100-41-4
0.46
1
08/19/18 15:15
591-78-6
0.32
1
08/19/18 15:15
74-88-4
0.97
1
08/19/18 15:15
75-09-2
0.33
1
08/19/18 15:15
108-10-1
0.26
1
08/19/18 15:15
100-42-5
0.33
1
08/19/18 15:15
630-20-6
0.40
1
08/19/18 15:15
79-34-5
0.46
1
08/19/18 15:15
127-18-4
0.26
1
08/19/18 15:15
108-88-3
0.48
1
08/19/18 15:15
71-55-6
0.29
1
08/19/18 15:15
79-00-5
0.47
1
08/19/18 15:15
79-01-6
0.20
1
08/19/18 15:15
75-69-4
0.41
1
08/19/18 15:15
96-18-4
0.35
1
08/19/18 15:15
108-05-4
0.62
1
08/19/18 15:15
75-01-4
0.66
1
08/19/18 15:15
1330-20-7
1
08/19/18 15:15
460-00-4
1
08/19/18 15:15
17060-07-0
1
08/19/18 15:15
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
08/21/18 21:49 123-91-1
08/21 /18 21:49 17060-07-0
08/21 /18 21:49 2037-26-5
Page 7 of 27

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92396141
Sample: 3902-SW-2 Lab ID: 92396141002 Collected: 08/14/18 13:16 Received: 08/16/18 10:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260 MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
Date: 08/24/2018 02:32 PM
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
ND
ug/L
6.0
3.9
1
08/17/18 07:28
08/21/18 22:34
7440-36-0
ND
ug/L
10.0
5.0
1
08/17/18 07:28
08/21/18 22:34
7440-38-2
86.6J
ug/L
100
2.5
1
08/17/18 07:28
08/21/18 22:34
7440-39-3
ND
ug/L
1.0
0.50
1
08/17/18 07:28
08/21/18 22:34
7440-41-7
ND
ug/L
1.0
0.50
1
08/17/18 07:28
08/21/18 22:34
7440-43-9
ND
ug/L
10.0
2.5
1
08/17/18 07:28
08/21/18 22:34
7440-47-3
ND
ug/L
10.0
2.5
1
08/17/18 07:28
08/21/18 22:34
7440-48-4
ND
ug/L
10.0
2.5
1
08/17/18 07:28
08/21/18 22:34
7440-50-8
ND
ug/L
10.0
2.5
1
08/17/18 07:28
08/21/18 22:34
7439-92-1
12.4J
ug/L
50.0
2.5
1
08/17/18 07:28
08/21/18 22:34
7440-02-0
ND
ug/L
10.0
5.0
1
08/17/18 07:28
08/21/18 22:34
7782-49-2
ND
ug/L
10.0
2.5
1
08/17/18 07:28
08/21/18 22:34
7440-22-4
3.1J
ug/L
25.0
2.5
1
08/17/18 07:28
08/21/18 22:34
7440-62-2
ND
ug/L
10.0
5.0
1
08/17/18 07:28
08/21/18 22:34
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 5.5 0.020 1 08/21/18 01:25 08/23/18 20:38 7440-28-0
Analytical Method: EPA 8260E
ND
ug/L
100
10.0
1
08/19/1815:31
67-64-1
ND
ug/L
200
1.9
1
08/19/1815:31
107-13-1
ND
ug/L
1.0
0.25
1
08/19/1815:31
71-43-2
ND
ug/L
3.0
0.17
1
08/19/1815:31
74-97-5
ND
ug/L
1.0
0.18
1
08/19/1815:31
75-27-4
ND
ug/L
3.0
0.26
1
08/19/1815:31
75-25-2
ND
ug/L
10.0
0.29
1
08/19/1815:31
74-83-9
ND
ug/L
100
0.96
1
08/19/1815:31
78-93-3
ND
ug/L
100
1.2
1
08/19/1815:31
75-15-0
ND
ug/L
1.0
0.25
1
08/19/1815:31
56-23-5
ND
ug/L
3.0
0.23
1
08/19/1815:31
108-90-7
ND
ug/L
10.0
0.54
1
08/19/1815:31
75-00-3
ND
ug/L
5.0
0.14
1
08/19/1815:31
67-66-3
ND
ug/L
1.0
0.11
1
08/19/1815:31
74-87-3
ND
ug/L
13.0
2.0
1
08/19/1815:31
96-12-8
ND
ug/L
3.0
0.21
1
08/19/1815:31
124-48-1
ND
ug/L
1.0
0.27
1
08/19/1815:31
106-93-4
ND
ug/L
10.0
0.21
1
08/19/1815:31
74-95-3
ND
ug/L
5.0
0.30
1
08/19/1815:31
95-50-1
ND
ug/L
1.0
0.33
1
08/19/1815:31
106-46-7
ND
ug/L
100
1.0
1
08/19/1815:31
110-57-6
ND
ug/L
5.0
0.32
1
08/19/1815:31
75-34-3
ND
ug/L
1.0
0.24
1
08/19/1815:31
107-06-2
ND
ug/L
5.0
0.56
1
08/19/1815:31
75-35-4
ND
ug/L
5.0
0.19
1
08/19/1815:31
156-59-2
ND
ug/L
5.0
0.49
1
08/19/1815:31
156-60-5
ND
ug/L
1.0
0.27
1
08/19/1815:31
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 27

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ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92396141
Sample: 3902-SW-2 Lab ID: 92396141002 Collected: 08/14/18 13:16 Received: 08/16/18 10:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260 MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 08/24/2018 02:32 PM
Analytical Method: EPA 8260E
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
50.0
ND
ug/L
10.0
ND
ug/L
1.0
ND
ug/L
100
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
3.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
50.0
ND
ug/L
1.0
ND
ug/L
5.0
96
%
70-130
100
%
70-130
100
%
70-130
Analytical Method: EPA 8260E Mod.
14.1
ug/L
2.0
95
%
50-150
108
%
50-150
0.13
1
08/19/18 15:31
10061-01-5
0.26
1
08/19/18 15:31
10061-02-6
0.30
1
08/19/18 15:31
100-41-4
0.46
1
08/19/18 15:31
591-78-6
0.32
1
08/19/18 15:31
74-88-4
0.97
1
08/19/18 15:31
75-09-2
0.33
1
08/19/18 15:31
108-10-1
0.26
1
08/19/18 15:31
100-42-5
0.33
1
08/19/18 15:31
630-20-6
0.40
1
08/19/18 15:31
79-34-5
0.46
1
08/19/18 15:31
127-18-4
0.26
1
08/19/18 15:31
108-88-3
0.48
1
08/19/18 15:31
71-55-6
0.29
1
08/19/18 15:31
79-00-5
0.47
1
08/19/18 15:31
79-01-6
0.20
1
08/19/18 15:31
75-69-4
0.41
1
08/19/18 15:31
96-18-4
0.35
1
08/19/18 15:31
108-05-4
0.62
1
08/19/18 15:31
75-01-4
0.66
1
08/19/18 15:31
1330-20-7
1
08/19/18 15:31
460-00-4
1
08/19/18 15:31
17060-07-0
1
08/19/18 15:31
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
08/21/18 22:08 123-91-1
08/21 /18 22:08 17060-07-0
08/21 /18 22:08 2037-26-5
Page 9 of 27

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Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92396141
Sample: 3902-NES-1
Lab ID:
92396141003
Collected:
08/15/18 06:19
Received: 08/16/18 10:00 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL DF
Prepared Analyzed
CAS No. Qual
8260 MSV Low Level Landfill
Analytical
Method: EPA 8260E
Benzene
ND
ug/L
1.0
0.25 1
08/19/18 15:47
71-43-2
Surrogates
4-Bromofluorobenzene (S)
93
%
70-130
1
08/19/18 15:47
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
08/19/18 15:47
17060-07-0
Toluene-d8 (S)
98
%
70-130
1
08/19/18 15:47
2037-26-5
Date: 08/24/2018 02:32 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 27

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92396141
Sample: 3902-Field Blank Lab ID: 92396141004 Collected: 08/15/18 06:31 Received: 08/16/18 10:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Tin
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260 MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Date: 08/24/2018 02:32 PM
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
ND
ug/L
6.0
3.9
1
08/17/18 07:28
08/21/18 22:43
7440-36-0
ND
ug/L
10.0
5.0
1
08/17/18 07:28
08/21/18 22:43
7440-38-2
ND
ug/L
100
2.5
1
08/17/18 07:28
08/21/18 22:43
7440-39-3
ND
ug/L
1.0
0.50
1
08/17/18 07:28
08/21/18 22:43
7440-41-7
ND
ug/L
1.0
0.50
1
08/17/18 07:28
08/21/18 22:43
7440-43-9
ND
ug/L
10.0
2.5
1
08/17/18 07:28
08/21/18 22:43
7440-47-3
ND
ug/L
10.0
2.5
1
08/17/18 07:28
08/21/18 22:43
7440-48-4
ND
ug/L
10.0
2.5
1
08/17/18 07:28
08/21/18 22:43
7440-50-8
ND
ug/L
10.0
2.5
1
08/17/18 07:28
08/21/18 22:43
7439-92-1
ND
ug/L
50.0
2.5
1
08/17/18 07:28
08/21/18 22:43
7440-02-0
ND
ug/L
10.0
5.0
1
08/17/18 07:28
08/21/18 22:43
7782-49-2
ND
ug/L
10.0
2.5
1
08/17/18 07:28
08/21/18 22:43
7440-22-4
ND
ug/L
100
2.5
1
08/17/18 07:28
08/21/18 22:43
7440-31-5
ND
ug/L
25.0
2.5
1
08/17/18 07:28
08/21/18 22:43
7440-62-2
ND
ug/L
10.0
5.0
1
08/17/18 07:28
08/21/18 22:43
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 5.5 0.020 1 08/17/18 07:17 08/23/18 22:39 7440-28-0
Analytical Method: EPA 8260E
ND
ug/L
100
10.0
1
08/19/1816:04
67-64-1
ND
ug/L
200
1.9
1
08/19/1816:04
107-13-1
ND
ug/L
1.0
0.25
1
08/19/1816:04
71-43-2
ND
ug/L
3.0
0.17
1
08/19/1816:04
74-97-5
ND
ug/L
1.0
0.18
1
08/19/1816:04
75-27-4
ND
ug/L
3.0
0.26
1
08/19/1816:04
75-25-2
ND
ug/L
10.0
0.29
1
08/19/1816:04
74-83-9
ND
ug/L
100
0.96
1
08/19/1816:04
78-93-3
ND
ug/L
100
1.2
1
08/19/1816:04
75-15-0
ND
ug/L
1.0
0.25
1
08/19/1816:04
56-23-5
ND
ug/L
3.0
0.23
1
08/19/1816:04
108-90-7
ND
ug/L
10.0
0.54
1
08/19/1816:04
75-00-3
ND
ug/L
5.0
0.14
1
08/19/1816:04
67-66-3
ND
ug/L
1.0
0.11
1
08/19/1816:04
74-87-3
ND
ug/L
13.0
2.0
1
08/19/1816:04
96-12-8
ND
ug/L
3.0
0.21
1
08/19/1816:04
124-48-1
ND
ug/L
1.0
0.27
1
08/19/1816:04
106-93-4
ND
ug/L
10.0
0.21
1
08/19/1816:04
74-95-3
ND
ug/L
5.0
0.30
1
08/19/1816:04
95-50-1
ND
ug/L
1.0
0.33
1
08/19/1816:04
106-46-7
ND
ug/L
100
1.0
1
08/19/1816:04
110-57-6
ND
ug/L
5.0
0.32
1
08/19/1816:04
75-34-3
ND
ug/L
1.0
0.24
1
08/19/1816:04
107-06-2
ND
ug/L
5.0
0.56
1
08/19/1816:04
75-35-4
ND
ug/L
5.0
0.19
1
08/19/1816:04
156-59-2
ND
ug/L
5.0
0.49
1
08/19/1816:04
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 27

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92396141
Sample: 3902-Field Blank Lab ID: 92396141004 Collected: 08/15/18 06:31 Received: 08/16/18 10:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260 MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 08/24/2018 02:32 PM
Analytical Method: EPA 8260E
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
50.0
ND
ug/L
10.0
6.6
ug/L
1.0
ND
ug/L
100
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
3.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
50.0
ND
ug/L
1.0
ND
ug/L
5.0
96
%
70-130
97
%
70-130
100
%
70-130
Analytical Method: EPA 8260E Mod.
ND
ug/L
2.0
96
%
50-150
110
%
50-150
0.27
1
08/19/18 16:04
78-87-5
0.13
1
08/19/18 16:04
10061-01-5
0.26
1
08/19/18 16:04
10061-02-6
0.30
1
08/19/18 16:04
100-41-4
0.46
1
08/19/18 16:04
591-78-6
0.32
1
08/19/18 16:04
74-88-4
0.97
1
08/19/18 16:04
75-09-2
0.33
1
08/19/18 16:04
108-10-1
0.26
1
08/19/18 16:04
100-42-5
0.33
1
08/19/18 16:04
630-20-6
0.40
1
08/19/18 16:04
79-34-5
0.46
1
08/19/18 16:04
127-18-4
0.26
1
08/19/18 16:04
108-88-3
0.48
1
08/19/18 16:04
71-55-6
0.29
1
08/19/18 16:04
79-00-5
0.47
1
08/19/18 16:04
79-01-6
0.20
1
08/19/18 16:04
75-69-4
0.41
1
08/19/18 16:04
96-18-4
0.35
1
08/19/18 16:04
108-05-4
0.62
1
08/19/18 16:04
75-01-4
0.66
1
08/19/18 16:04
1330-20-7
1
08/19/18 16:04
460-00-4
1
08/19/18 16:04
17060-07-0
1
08/19/18 16:04
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
08/21/18 22:28 123-91-1
08/21 /18 22:28 17060-07-0
08/21 /18 22:28 2037-26-5
Page 12 of 27

aceAnalytical
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Huntersville, NC 28078
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QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92396141
QC Batch: 425491 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Associated Lab Samples: 92396141001, 92396141002, 92396141004
METHOD BLANK: 2352643
Matrix:
Water
Associated Lab Samples: 92396141001, 92396141002, 92396141004
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
Antimony
ug/L
ND
6.0
3.9
08/21/18 22:05
Arsenic
ug/L
ND
10.0
5.0
08/21/18 22:05
Barium
ug/L
ND
100
2.5
08/21/18 22:05
Beryllium
ug/L
ND
1.0
0.50
08/21/18 22:05
Cadmium
ug/L
ND
1.0
0.50
08/21/18 22:05
Chromium
ug/L
ND
10.0
2.5
08/21/18 22:05
Cobalt
ug/L
ND
10.0
2.5
08/21/18 22:05
Copper
ug/L
ND
10.0
2.5
08/21/18 22:05
Lead
ug/L
ND
10.0
2.5
08/21/18 22:05
Nickel
ug/L
ND
50.0
2.5
08/21/18 22:05
Selenium
ug/L
ND
10.0
5.0
08/21/18 22:05
Silver
ug/L
ND
10.0
2.5
08/21/18 22:05
Tin
ug/L
ND
100
2.5
08/21/18 22:05
Vanadium
ug/L
ND
25.0
2.5
08/21/18 22:05
Zinc
ug/L
ND
10.0
5.0
08/21/18 22:05
LABORATORY CONTROL SAMPLE:
2352644
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Antimony
ug/L
500
487
97
80-120
Arsenic
ug/L
500
464
93
80-120
Barium
ug/L
500
483
97
80-120
Beryllium
ug/L
500
479
96
80-120
Cadmium
ug/L
500
458
92
80-120
Chromium
ug/L
500
476
95
80-120
Cobalt
ug/L
500
466
93
80-120
Copper
ug/L
500
496
99
80-120
Lead
ug/L
500
464
93
80-120
Nickel
ug/L
500
480
96
80-120
Selenium
ug/L
500
455
91
80-120
Silver
ug/L
250
246
99
80-120
Tin
ug/L
500
475
95
80-120
Vanadium
ug/L
500
482
96
80-120
Zinc
ug/L
500
452
90
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:32 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 27

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Butner Landfill Compliance
92396141
MATRIX SPIKE &
MATRIX SPIKE DUPLICATE:
2352645
2352646
MS
MSD
92396141001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
500
500
504
496
101
99
75-125
2
20
Arsenic
ug/L
ND
500
500
487
478
97
96
75-125
2
20
Barium
ug/L
ND
500
500
475
472
95
94
75-125
1
20
Beryllium
ug/L
ND
500
500
500
495
100
99
75-125
1
20
Cadmium
ug/L
ND
500
500
456
449
91
90
75-125
2
20
Chromium
ug/L
ND
500
500
472
465
94
93
75-125
1
20
Cobalt
ug/L
ND
500
500
453
447
91
89
75-125
1
20
Copper
ug/L
ND
500
500
502
492
100
98
75-125
2
20
Lead
ug/L
ND
500
500
457
450
91
90
75-125
2
20
Nickel
ug/L
ND
500
500
464
456
93
91
75-125
2
20
Selenium
ug/L
ND
500
500
503
493
100
98
75-125
2
20
Silver
ug/L
ND
250
250
251
246
100
99
75-125
2
20
Tin
ug/L
ND
500
500
474
464
95
93
75-125
2
20
Vanadium
ug/L
ND
500
500
494
487
98
97
75-125
1
20
Zinc
ug/L
ND
500
500
454
444
90
88
75-125
2
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:32 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 27

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92396141
QC Batch: 425510
Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A
Analysis Description: 6020 MET
Associated Lab Samples: 92396141001, 92396141004
METHOD BLANK: 2352702
Matrix: Water
Associated Lab Samples: 92396141001, 92396141004
Blank Reporting
Parameter Units
Result Limit MDL
Analyzed
Qualifiers
Thallium ug/L
ND 5.5 0.020
08/23/18 22:09
LABORATORY CONTROL SAMPLE: 2352703
Spike LCS LCS
% Rec
Parameter Units
Conc. Result % Rec
Limits Qualifiers
Thallium ug/L
10 10.1 101
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2352704 2352705
MS MSD
92396141001
Spike Spike MS MSD
MS MSD
% Rec Max
Parameter Units Result
Conc. Conc. Result Result
% Rec % Rec
Limits RPD RPD Qual
Thallium ug/L ND
10 10 10.3 10.3
103 103
75-125 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:32 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 27

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92396141
QC Batch: 425992
Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A
Analysis Description: 6020 MET
Associated Lab Samples: 92396141002
METHOD BLANK: 2354898
Matrix: Water
Associated Lab Samples: 92396141002
Blank Reporting
Parameter Units
Result Limit MDL
Analyzed
Qualifiers
Thallium ug/L
ND 5.5 0.020
08/23/1819:50
LABORATORY CONTROL SAMPLE: 2354899
Spike LCS LCS
% Rec
Parameter Units
Conc. Result % Rec
Limits Qualifiers
Thallium ug/L
10 9.7 97
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2354900 2354901
MS MSD
92396260002
Spike Spike MS MSD
MS MSD
% Rec Max
Parameter Units Result
Conc. Conc. Result Result
% Rec % Rec
Limits RPD RPD Qual
Thallium ug/L ND
10 10 9.9 9.9
99 99
75-125 0 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 27

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92396141
QC Batch: 425801 Analysis Method: EPA 8260B
QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill
Associated Lab Samples: 92396141001, 92396141002, 92396141003, 92396141004
METHOD BLANK: 2354038 Matrix: Water
Associated Lab Samples: 92396141001, 92396141002, 92396141003, 92396141004
Blank Reporting
Parameter Units Result Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
5.0
0.33
08/19/18 12:01
1,1,1-Trichloroethane
ug/L
ND
1.0
0.48
08/19/18 12:01
1,1,2,2-Tetrachloroethane
ug/L
ND
3.0
0.40
08/19/18 12:01
1,1,2-Trichloroethane
ug/L
ND
1.0
0.29
08/19/18 12:01
1,1-Dichloroethane
ug/L
ND
5.0
0.32
08/19/18 12:01
1,1-Dichloroethene
ug/L
ND
5.0
0.56
08/19/18 12:01
1,2,3-Trichloropropane
ug/L
ND
1.0
0.41
08/19/18 12:01
1,2-Dibromo-3-chloropropane
ug/L
ND
13.0
2.0
08/19/18 12:01
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
08/19/18 12:01
1,2-Dichlorobenzene
ug/L
ND
5.0
0.30
08/19/18 12:01
1,2-Dichloroethane
ug/L
ND
1.0
0.24
08/19/18 12:01
1,2-Dichloropropane
ug/L
ND
1.0
0.27
08/19/18 12:01
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
08/19/18 12:01
2-Butanone (MEK)
ug/L
ND
100
0.96
08/19/18 12:01
2-Hexanone
ug/L
ND
50.0
0.46
08/19/18 12:01
4-Methyl-2-pentanone (MIBK)
ug/L
ND
100
0.33
08/19/18 12:01
Acetone
ug/L
ND
100
10.0
08/19/18 12:01
Acrylonitrile
ug/L
ND
200
1.9
08/19/18 12:01
Benzene
ug/L
ND
1.0
0.25
08/19/18 12:01
Bromochloromethane
ug/L
ND
3.0
0.17
08/19/18 12:01
Bromodichloromethane
ug/L
ND
1.0
0.18
08/19/18 12:01
Bromoform
ug/L
ND
3.0
0.26
08/19/18 12:01
Bromomethane
ug/L
ND
10.0
0.29
08/19/18 12:01
Carbon disulfide
ug/L
ND
100
1.2
08/19/18 12:01
Carbon tetrachloride
ug/L
ND
1.0
0.25
08/19/18 12:01
Chlorobenzene
ug/L
ND
3.0
0.23
08/19/18 12:01
Chloroethane
ug/L
ND
10.0
0.54
08/19/18 12:01
Chloroform
ug/L
ND
5.0
0.14
08/19/18 12:01
Chloromethane
ug/L
ND
1.0
0.11
08/19/18 12:01
cis-1,2-Dichloroethene
ug/L
ND
5.0
0.19
08/19/18 12:01
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.13
08/19/18 12:01
Dibromochloromethane
ug/L
ND
3.0
0.21
08/19/18 12:01
Dibromomethane
ug/L
ND
10.0
0.21
08/19/18 12:01
Ethylbenzene
ug/L
ND
1.0
0.30
08/19/18 12:01
lodomethane
ug/L
ND
10.0
0.32
08/19/18 12:01
Methylene Chloride
ug/L
ND
1.0
0.97
08/19/18 12:01
Styrene
ug/L
ND
1.0
0.26
08/19/18 12:01
Tetrachloroethene
ug/L
ND
1.0
0.46
08/19/18 12:01
Toluene
ug/L
ND
1.0
0.26
08/19/18 12:01
trans-1,2-Dichloroethene
ug/L
ND
5.0
0.49
08/19/18 12:01
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.26
08/19/18 12:01
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 27

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92396141
METHOD BLANK: 2354038
Matrix:
Water
Associated Lab Samples:
92396141001, 92396141002, 92396141003, 92396141004
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed
trans-1,4-Dichloro-2-butene
ug/L
ND
100
1.0
08/19/18 12:01
Trichloroethene
ug/L
ND
1.0
0.47
08/19/18 12:01
Trichlorofluoromethane
ug/L
ND
1.0
0.20
08/19/18 12:01
Vinyl acetate
ug/L
ND
50.0
0.35
08/19/18 12:01
Vinyl chloride
ug/L
ND
1.0
0.62
08/19/18 12:01
Xylene (Total)
ug/L
ND
5.0
0.66
08/19/18 12:01
1,2-Dichloroethane-d4 (S)
%
98
70-130
08/19/18 12:01
4-Bromofluorobenzene (S)
%
96
70-130
08/19/18 12:01
Toluene-d8 (S)
%
100
70-130
08/19/18 12:01
LABORATORY CONTROL SAMPLE:
Parameter
2354039
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
50
51.6
103
80-125
1,1,1-Trichloroethane
ug/L
50
51.1
102
71-129
1,1,2,2-Tetrachloroethane
ug/L
50
49.3
99
79-124
1,1,2-Trichloroethane
ug/L
50
50.4
101
85-125
1,1-Dichloroethane
ug/L
50
46.8
94
73-126
1,1-Dichloroethene
ug/L
50
52.2
104
66-135
1,2,3-Trichloropropane
ug/L
50
48.5
97
75-130
1,2-Dibromo-3-chloropropane
ug/L
50
51.2
102
71-133
1,2-Dibromoethane (EDB)
ug/L
50
53.0
106
83-124
1,2-Dichlorobenzene
ug/L
50
49.2
98
80-133
1,2-Dichloroethane
ug/L
50
50.1
100
67-128
1,2-Dichloropropane
ug/L
50
50.1
100
75-132
1,4-Dichlorobenzene
ug/L
50
47.7
95
78-130
2-Butanone (MEK)
ug/L
100
96.2J
96
61-144
2-Hexanone
ug/L
100
100
100
68-143
4-Methyl-2-pentanone (MIBK)
ug/L
100
98AJ
98
72-135
Acetone
ug/L
100
112
112
48-146
Acrylonitrile
ug/L
250
248
99
40-160
Benzene
ug/L
50
49.1
98
80-125
Bromochloromethane
ug/L
50
52.0
104
71-125
Bromodichloromethane
ug/L
50
53.3
107
78-124
Bromoform
ug/L
50
51.1
102
71-128
Bromomethane
ug/L
50
37.9
76
40-160
Carbon disulfide
ug/L
50
51.3J
103
50-160
Carbon tetrachloride
ug/L
50
52.9
106
69-131
Chlorobenzene
ug/L
50
49.4
99
81-122
Chloroethane
ug/L
50
43.1
86
39-148
Chloroform
ug/L
50
51.7
103
73-127
Chloromethane
ug/L
50
44.4
89
44-146
cis-1,2-Dichloroethene
ug/L
50
49.2
98
74-124
cis-1,3-Dichloropropene
ug/L
50
50.2
100
72-132
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 27

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92396141
LABORATORY CONTROL SAMPLE:
2354039
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Dibromochloromethane
ug/L
50
51.3
103
78-125
Dibromomethane
ug/L
50
54.0
108
82-120
Ethylbenzene
ug/L
50
48.9
98
79-121
lodomethane
ug/L
100
98.6
99
39-154
Methylene Chloride
ug/L
50
51.6
103
64-133
Styrene
ug/L
50
49.4
99
84-126
Tetrachloroethene
ug/L
50
48.4
97
78-122
Toluene
ug/L
50
47.9
96
80-121
trans-1,2-Dichloroethene
ug/L
50
50.8
102
71-127
trans- 1,3-Dichloropropene
ug/L
50
50.8
102
69-141
trans-1,4-Dichloro-2-butene
ug/L
50
52.6J
105
40-160
Trichloroethene
ug/L
50
52.8
106
78-122
Trichlorofluoromethane
ug/L
50
51.2
102
53-137
Vinyl acetate
ug/L
100
98.1
98
40-160
Vinyl chloride
ug/L
50
51.5
103
58-137
Xylene (Total)
ug/L
150
149
99
81-126
1,2-Dichloroethane-d4 (S)
%
100
70-130
4-Bromofluorobenzene (S)
%
97
70-130
Toluene-d8 (S)
%
97
70-130
MATRIX SPIKE SAMPLE:
2354041
92395744002
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
19.3
96
70-130
1,1,1-Trichloroethane
ug/L
ND
20
20.7
103
70-130
1,1,2,2-Tetrachloroethane
ug/L
ND
20
18.9
94
70-130
1,1,2-Trichloroethane
ug/L
ND
20
19.4
97
70-130
1,1-Dichloroethane
ug/L
ND
20
19.3
97
70-130
1,1-Dichloroethene
ug/L
ND
20
21.8
109
70-166
1,2,3-Trichloropropane
ug/L
ND
20
18.8
94
70-130
1,2-Dibromo-3-chloropropane
ug/L
ND
20
18.0
90
70-130
1,2-Dibromoethane (EDB)
ug/L
ND
20
20.0
100
70-130
1,2-Dichlorobenzene
ug/L
1.2J
20
20.7
97
70-130
1,2-Dichloroethane
ug/L
ND
20
19.9
99
70-130
1,2-Dichloropropane
ug/L
ND
20
19.5
98
70-130
1,4-Dichlorobenzene
ug/L
1.9
20
20.2
92
70-130
2-Butanone (MEK)
ug/L
ND
40
39.OJ
97
70-130
2-Hexanone
ug/L
ND
40
37.2J
93
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
37.9J
95
70-130
Acetone
ug/L
ND
40
53.5J
134
70-130 M1
Acrylonitrile
ug/L
ND
100
97.3J
97
70-130
Benzene
ug/L
1.3
20
21.2
100
70-148
Bromochloromethane
ug/L
ND
20
20.5
103
70-130
Bromodichloromethane
ug/L
ND
20
20.1
101
70-130
Bromoform
ug/L
ND
20
18.1
90
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 27

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92396141
MATRIX SPIKE SAMPLE:
Parameter
2354041
Units
92395744002
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Bromomethane
ug/L
ND
20
9.6J
48
70-130 M1
Carbon disulfide
ug/L
ND
20
20.OJ
100
70-130
Carbon tetrachloride
ug/L
ND
20
20.6
103
70-130
Chlorobenzene
ug/L
14.5
20
33.9
97
70-146
Chloroethane
ug/L
1.2J
20
19.4
91
70-130
Chloroform
ug/L
ND
20
20.0
100
70-130
Chloromethane
ug/L
ND
20
17.7
89
70-130
cis-1,2-Dichloroethene
ug/L
ND
20
19.9
100
70-130
cis-1,3-Dichloropropene
ug/L
ND
20
18.6
93
70-130
Dibromochloromethane
ug/L
ND
20
19.0
95
70-130
Dibromomethane
ug/L
ND
20
21.3
107
70-130
Ethylbenzene
ug/L
ND
20
19.3
97
70-130
lodomethane
ug/L
ND
40
36.3
91
70-130
Methylene Chloride
ug/L
ND
20
19.9
100
70-130
Styrene
ug/L
ND
20
18.8
94
70-130
Tetrachloroethene
ug/L
ND
20
19.5
97
70-130
Toluene
ug/L
ND
20
19.2
96
70-155
trans-1,2-Dichloroethene
ug/L
ND
20
20.7
103
70-130
trans- 1,3-Dichloropropene
ug/L
ND
20
18.9
94
70-130
trans-1,4-Dichloro-2-butene
ug/L
ND
20
15.OJ
75
70-130
Trichloroethene
ug/L
ND
20
21.0
105
69-151
Trichlorofluoromethane
ug/L
ND
20
22.4
112
70-130
Vinyl acetate
ug/L
ND
40
35.9J
90
70-130
Vinyl chloride
ug/L
ND
20
21.2
106
70-130
Xylene (Total)
ug/L
ND
60
58.3
97
70-130
1,2-Dichloroethane-d4 (S)
%
100
70-130
4-Bromofluorobenzene (S)
%
97
70-130
Toluene-d8 (S)
%
96
70-130
SAMPLE DUPLICATE: 2354040
Parameter
Units
92395744001
Result
Dup
Result RPD
Max
RPD Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
ND
ND
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
1,2-Dichlorobenzene
ug/L
ND
ND
30
1,2-Dichloroethane
ug/L
ND
ND
30
1,2-Dichloropropane
ug/L
ND
ND
30
1,4-Dichlorobenzene
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:32 PM without the written consent of Pace Analytical Services, LLC.
Page 20 of 27

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92396141
SAMPLE DUPLICATE: 2354040
Parameter
Units
92395744001
Result
2-Butanone (MEK)
ug/L
ND
2-Hexanone
ug/L
ND
4-Methyl-2-pentanone (MIBK)
ug/L
ND
Acetone
ug/L
ND
Acrylonitrile
ug/L
ND
Benzene
ug/L
ND
Bromochloromethane
ug/L
ND
Bromodichloromethane
ug/L
ND
Bromoform
ug/L
ND
Bromomethane
ug/L
ND
Carbon disulfide
ug/L
ND
Carbon tetrachloride
ug/L
ND
Chlorobenzene
ug/L
ND
Chloroethane
ug/L
ND
Chloroform
ug/L
ND
Chloromethane
ug/L
ND
cis-1,2-Dichloroethene
ug/L
ND
cis-1,3-Dichloropropene
ug/L
ND
Dibromochloromethane
ug/L
ND
Dibromomethane
ug/L
ND
Ethylbenzene
ug/L
ND
lodomethane
ug/L
ND
Methylene Chloride
ug/L
ND
Styrene
ug/L
ND
Tetrachloroethene
ug/L
ND
Toluene
ug/L
ND
trans-1,2-Dichloroethene
ug/L
ND
trans- 1,3-Dichloropropene
ug/L
ND
trans-1,4-Dichloro-2-butene
ug/L
ND
Trichloroethene
ug/L
ND
Trichlorofluoromethane
ug/L
ND
Vinyl acetate
ug/L
ND
Vinyl chloride
ug/L
ND
Xylene (Total)
ug/L
ND
1,2-Dichloroethane-d4 (S)
%
98
4-Bromofluorobenzene (S)
%
97
Toluene-d8 (S)
%
98
Dup
Result RPD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
102
95
99
3
2
0
Max
RPD Qualifiers
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:32 PM without the written consent of Pace Analytical Services, LLC.
Page 21 of 27

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92396141
QC Batch: 426080 Analysis Method: EPA 8260B Mod.
QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM
Associated Lab Samples: 92396141001, 92396141002, 92396141004
METHOD BLANK: 2355220
Matrix:
Water
Associated Lab Samples:
92396141001, 92396141002, 92396141004
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
1.9 08/21/18 15:18
1,2-Dichloroethane-d4 (S)
%
97
50-150
08/21/18 15:18
Toluene-d8 (S)
%
107
50-150
08/21/18 15:18
LABORATORY CONTROL SAMPLE: 2355221
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 17.7 88 71-125
1,2-Dichloroethane-d4 (S) % 97 50-150
Toluene-d8(S) % 107 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2355222
2355223
MS
MSD
92395199068 Spike
Spike MS
MSD MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 18.5
17.9 91
88
50-150
3 30
1,2-Dichloroethane-d4 (S)
%
105
104
50-150
30
Toluene-d8 (S)
%
114
113
50-150
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:32 PM without the written consent of Pace Analytical Services, LLC.
Page 22 of 27

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Butner Landfill Compliance
Pace Project No.: 92396141
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2018 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 27

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Butner Landfill Compliance
92396141
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92396141001
3902-MW6
EPA 3010A
425491
EPA 6010D
425539
92396141002
3902-SW-2
EPA 3010A
425491
EPA 6010D
425539
92396141004
3902-Field Blank
EPA 3010A
425491
EPA 6010D
425539
92396141001
3902-MW6
EPA 3010A
425510
EPA 6020B
425544
92396141002
3902-SW-2
EPA 3010A
425992
EPA 6020B
426008
92396141004
3902-Field Blank
EPA 3010A
425510
EPA 6020B
425544
92396141001
3902-MW6
EPA 8260B
425801
92396141002
3902-SW-2
EPA 8260B
425801
92396141003
3902-NES-1
EPA 8260B
425801
92396141004
3902-Field Blank
EPA 8260B
425801
92396141001
3902-MW6
EPA 8260B Mod.
426080
92396141002
3902-SW-2
EPA 8260B Mod.
426080
92396141004
3902-Field Blank
EPA 8260B Mod.
426080
Date: 08/24/2018 02:32 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 24 of 27

Document Name;
Document Revised: February 7, 2018
g
Sample Condition Upon Receipt(SOUR)
Page 1 of 2
Document No.:
Issuing Authority:
aceAnalyical
F•CAR-CS-033-Rev.06
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood
Huntersville Raleigh[]
SampleCondition Client Name:
Upon Receipt Project M
Courier: ❑Fed Ex I ❑UPS ❑USPS J ❑Client
❑ Commercial [Pece' ❑0ther;
Custody Seal Present? Des MVO Seals Intact? []Yes
Mechanicsville[:]
WO#:92396141
92396141
IIIIIIIIIII IIIIIIIIIII
Date)lnitials Person Examining Contents:,
Packing Material: ❑Bubble Wrap ubble Bags ❑Bone ❑ Other Biological Tissue Fro. n?
Thermomete []Yes❑No - /A
iR Gun lD: 92TO43 Type of Ice: []Blue ❑None
Cooler Temp (°C): .5 .3 Correction Factor: Add/Subtract (T) -O 2
[ r-� Temp should be above freezing to 6°C
Cooler Temp Corrected ('C):---`-� '-F7 []samples cut of temp criteria. Samples on ice, cooling process
hasbegun
USDA Regulated Sail (['j%A, water sample)
Did samples origi in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source [interns eally,
nYes ;nrludire Hawaii and Puerto Rlcol? nYes No
Comments/Discrepancy:
Yes
LJ rqo
Samples Arrived within Hold Time?
des
❑]No
❑N/A
2.
Short Hold Time Analysis (<72 hr.)?
❑Yes
[No
❑N/A
3.
Rush Turn Around Time Requested?
❑Yes
to
[]N/A
4.
Sufficient Volume?
Yes
[]No
❑N/A
5.
Correct Containers Used?
-Pace Containers Used?
Ldfe
es
[]NO
ON.
❑N/A
❑N/A
6.
Containers Intact?
es
[]No
❑N/A
7,
Dissolved analysis: Samples Field Filtered?
❑Yes
❑No
/A
8,
Sample Labels MatchCOC?
-Includes Date/Time/ID/Analysis Matrix:
2<
T�
No
❑N/A
n
9. CUC S{{�! I��� IS�CuLk-
but
Headspace in VOA Vials (>5-6mm)?
[]Yes
No
❑N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
Des
26a
❑1do
❑N/A
❑N/A
11.
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
Lot ID of split containers:
Date/Time:Ay
_
Field Data Required? ❑Yes ❑No
Date: — -
Date:
Page 25 of 27

Document Name:
Document Revised: February 7, 2018
a
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
- aloArlaV Cal
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is Project #
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Caliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottle
W_0#92396141
RN: NMG Due Date: 08/30/18
CLIENT: 92--Joyce Eng
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot 9
Note: wnenever tnere is a mscrepancy arrecung norm Laroiina cu¢rlpnanLe 5dlnljle�, d ,�Nr
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 26 of 27

t,
t\
C
CHAIN
-OF -CUSTODY / Analytical Request Document
The
Chain-of-Cuslody is a LEGAL DOCUMENT. All relevant fields must be Completed accurately. c
a
Section A
Section B
Section C
Required Client Information:
Required Project Information:
Invoice Information: Page • I Of 1
Attertion: Jason Fails
Company Name: Granville County, Solid Waste
Company Joyce Ln ineerin
Report To: Van Burbach
Address: 2211 West Meadowview Rd
I copy To: Miguel Vazquez
Greensboro, NC 27407
Address: P.O. Box 906, Oxford NC 27565
Regulatory Agency
Email To: vburbach i-jo ceenl ineerin .Cd3ll I
I Purchase Order No -
Phone: [phone] Fax: I Client Project ID: Butner Landfill Complia
ice
State! Location
Requested Due Date/TAT: 10 Day (Default) Container Order Number:
' �.
North Carolina
Requested
Analysis
Filtered
(YIN)
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COLLECTE11
Preservatives
>-
MAt R1x CODE
Drinking Wafer eW
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aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
August 27, 2018
Mr. Van Burbach
Joyce Engineering -NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Butner Landfill MNA
Pace Project No.: 92395737
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 14, 2018. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
��i Flo _ _.1I , .�:
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Mr. Daniel Girdner, LaBella Associates, D.P.C.
Miguel Vazquez, Joyce Engineering
Rochelle mesubed, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 17

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Butner Landfill MNA
Pace Project No.: 92395737
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 17

aceAnalytical
—pacelabsxom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Butner Landfill MNA
Pace Project No.: 92395737
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92395737001
92395737002
3902-MW2R
3902-MW3R
Water
Water
08/13/1811:03
08/13/1811:24
08/14/1810:41
08/14/1810:41
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 17

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Butner Landfill MNA
92395737
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92395737001
3902-MW2R
SM 2320B-2011
ECH
1
PASI-A
SM 5210B-2011
SMK
1
PASI-A
EPA 300.0 Rev 2.1 1993
KDF1
3
PASI-A
SM 5220D-2011
GC
1
PASI-A
SM 5310B-2011
KDF1
1
PASI-A
92395737002
3902-MW3R
SM 2320B-2011
ECH
1
PASI-A
SM 5210B-2011
SMK
1
PASI-A
EPA 300.0 Rev 2.1 1993
KDF1
3
PASI-A
SM 5220D-2011
GC
1
PASI-A
SM 5310B-2011
KDF1
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 17

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project: Butner Landfill MNA
Pace Project No.: 92395737
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
92395737001
3902-MW2R
SM 2320B-2011
Alkalinity, Total as CaCO3
768000
ug/L
5000
08/23/18 13:52
SM 521 OB-2011
BOD, 5 day
71800
ug/L
2000
08/20/18 09:24
B3
EPA 300.0 Rev 2.1 1993
Chloride
221000
ug/L
4000
08/15/18 05:22
M1
SM 5220D-2011
Chemical Oxygen Demand
112000
ug/L
25000
08/16/18 17:41
SM 531OB-2011
Total Organic Carbon
25800
ug/L
5000
08/25/18 01:10
92395737002
3902-MW3R
SM 2320B-2011
Alkalinity, Total as CaCO3
722000
ug/L
5000
08/23/18 14:04
M1
SM 521 OB-2011
BOD, 5 day
3560
ug/L
2000
08/20/18 09:27
B3
EPA 300.0 Rev 2.1 1993
Chloride
165000
ug/L
3000
08/15/18 06:15
EPA 300.0 Rev 2.1 1993
Sulfate
0.63J
mg/L
250
08/15/18 05:04
SM 5220D-2011
Chemical Oxygen Demand
73900
ug/L
25000
08/16/18 17:42
SM 531OB-2011
Total Organic Carbon
10200
ug/L
1000
08/25/18 01:21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 17

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[phone]
ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92395737
Sample: 3902-MW2R
Lab ID: 92395737001 Collected: 08/13/18 11:03
Received: 08/14/18 10:41 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
2320B Alkalinity
Analytical Method: SM 2320B-2011
Alkalinity, Total as CaCO3
768000 ug/L 5000
1000
1
08/23/18 13:52
5210B BOD, 5 day
Analytical Method: SM 521 OB-2011
BOD, 5 day
71800 ug/L 2000
2000
1
08/15/18 07:27 08/20/18 09:24
B3
300.0 IC anions 48hr
Analytical Method: EPA 300.0 Rev 2.1 1993
Chloride
221000 ug/L 4000
2000
4
08/15/18 05:22
16887-00-6 M1
Nitrate as N
ND ug/L 100
50.0
1
08/15/18 04:10
14797-55-8
Sulfate
ND mg/L 250
0.50
1
08/15/18 04:10
14808-79-8
5220D COD
Analytical Method: SM 5220D-2011
Preparation
Method: SM 5220D-2011
Chemical Oxygen Demand
112000 ug/L 25000
12500
1
08/15/18 17:30 08/16/18 17:41
5310B TOC
Analytical Method: SM 531 OB-2011
Total Organic Carbon
25800 ug/L 5000
2500
5
08/25/18 01:10
7440-44-0
Date: 08/27/2018 10:43 AM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92395737
Sample: 3902-MW3R
Lab ID: 92395737002 Collected: 08/13/18 11:24
Received: 08/14/18 10:41 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
2320B Alkalinity
Analytical Method: SM 2320B-2011
Alkalinity, Total as CaCO3
722000 ug/L 5000
1000
1
08/23/18 14:04
M1
5210B BOD, 5 day
Analytical Method: SM 521 OB-2011
BOD, 5 day
3560 ug/L 2000
2000
1
08/15/18 07:27 08/20/18 09:27
B3
300.0 IC anions 48hr
Analytical Method: EPA 300.0 Rev 2.1 1993
Chloride
165000 ug/L 3000
1500
3
08/15/18 06:15
16887-00-6
Nitrate as N
ND ug/L 100
50.0
1
08/15/18 05:04
14797-55-8
Sulfate
0.63J mg/L 250
0.50
1
08/15/18 05:04
14808-79-8
5220D COD
Analytical Method: SM 5220D-2011
Preparation
Method: SM 5220D-2011
Chemical Oxygen Demand
73900 ug/L 25000
12500
1
08/15/18 17:30 08/16/18 17:42
5310B TOC
Analytical Method: SM 531 OB-2011
Total Organic Carbon
10200 ug/L 1000
500
1
08/25/18 01:21
7440-44-0
Date: 08/27/2018 10:43 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 17

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Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92395737
QC Batch: 426307
Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011
Analysis Description: 2320E Alkalinity
Associated Lab Samples: 92395737001, 92395737002
METHOD BLANK: 2356285
Matrix: Water
Associated Lab Samples: 92395737001, 92395737002
Blank Reporting
Parameter Units
Result Limit MDL Analyzed
Qualifiers
Alkalinity, Total as CaCO3 ug/L
ND 5000 1000 08/22/18 17:22
LABORATORY CONTROL SAMPLE: 2356286
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 ug/L
50000 50800 102 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2356287 2356288
MS MSD
92396420001
Spike Spike MS MSD MS MSD
% Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec
Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L 90.0 mg/L
50000 50000 137000 138000 94 96
80-120 1 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2356289 2356290
MS MSD
92395737002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L 722000 50000 50000 760000 728000 76 13 80-120 4 25 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/27/2018 10:43 AM without the written consent of Pace Analytical Services, LLC.
Page 8 of 17

aceAnalytical
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Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92395737
QC Batch: 424972
Analysis Method: SM 521 OB-2011
QC Batch Method: SM 521OB-2011
Analysis Description: 5210E BOD, 5 day
Associated Lab Samples: 92395737001,
92395737002
METHOD BLANK: 2350301
Matrix: Water
Associated Lab Samples: 92395737001,
92395737002
Blank Reporting
Parameter
Units
Result Limit MDL Analyzed Qualifiers
BOD, 5 day
ug/L
ND 2000 2000 08/20/18 09:13 B3
LABORATORY CONTROL SAMPLE: 2350302
Spike LCS LCS % Rec
Parameter
Units
Conc. Result % Rec Limits Qualifiers
BOD, 5 day
ug/L
198000 185000 93 84.6-115 B3
SAMPLE DUPLICATE: 2350304
92395639001 Dup Max
Parameter
Units
Result Result RPD RPD Qualifiers
BOD, 5 day
ug/L
11.5 mg/L 11600 1 10 B3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 08/27/2018 10:43 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 17

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92395737
QC Batch: 424964 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92395737001, 92395737002
METHOD BLANK: 2350267
Matrix:
Water
Associated Lab Samples:
92395737001, 92395737002
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
Chloride
ug/L
ND
1000
500 08/15/18 03:35
Nitrate as N
ug/L
ND
100
50.0 08/15/18 03:35
Sulfate
mg/L
ND
250
0.50 08/15/18 03:35
LABORATORY CONTROL SAMPLE:
2350268
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Chloride
ug/L
50000
50800 102
90-110
Nitrate as N
ug/L
2500
2460 98
90-110
Sulfate
mg/L
50
52.1J 104
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2350269
2350270
MS
MSD
92395737001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
Chloride ug/L
221000
50000
50000
265000
268000
88
94
90-110
1 10 M1
Nitrate as N ug/L
ND
2500
2500
2470
2430
99
97
90-110
2 10
Sulfate mg/L
ND
50
50
52.3J
51.7J
104
103
90-110
1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/27/2018 10:43 AM without the written consent of Pace Analytical Services, LLC.
Page 10 of 17

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92395737
QC Batch: 425207
Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011
Analysis Description: 5220D COD
Associated Lab Samples: 92395737001, 92395737002
METHOD BLANK: 2351450
Matrix: Water
Associated Lab Samples: 92395737001, 92395737002
Blank Reporting
Parameter Units
Result Limit
MDL Analyzed
Qualifiers
Chemical Oxygen Demand ug/L
ND 25000
12500 08/16/18 17:37
LABORATORY CONTROL SAMPLE: 2351451
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chemical Oxygen Demand ug/L
750000 752000
100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2351452 2351453
MS MSD
92395691040
Spike Spike MS
MSD MS MSD
% Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits RPD RPD Qual
Chemical Oxygen Demand ug/L 1390 mg/L
100000 100000 1480000
1470000 90 81
90-110 1 3 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2351454 2351455
MS MSD
92395671002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand ug/L 78.7 mg/L 100000 100000 188000 197000 109 119 90-110 5 3 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/27/2018 10:43 AM without the written consent of Pace Analytical Services, LLC.
Page 11 of 17

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92395737
QC Batch: 427055
Analysis Method: SM 531 OB-2011
QC Batch Method: SM 531 OB-2011
Analysis Description: 5310E TOC
Associated Lab Samples: 92395737001, 92395737002
METHOD BLANK: 2359827
Matrix: Water
Associated Lab Samples: 92395737001, 92395737002
Blank Reporting
Parameter Units
Result Limit
MDL
Analyzed Qualifiers
Total Organic Carbon ug/L
ND 1000
500 08/24/18 19:48
LABORATORY CONTROL SAMPLE: 2359828
Spike LCS
LCS
% Rec
Parameter Units
Conc. Result
% Rec
Limits Qualifiers
Total Organic Carbon ug/L
25000 23800
95
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2359829 2359830
MS MSD
92396309001
Spike Spike MS
MSD
MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result
% Rec % Rec Limits RPD RPD Qual
Total Organic Carbon ug/L 2.2 mg/L
25000 25000 24800
24800
91 91 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2359831 2359832
MS MSD
92396309011 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon ug/L 3.2 mg/L 25000 25000 26200 26400 92 93 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/27/2018 10:43 AM without the written consent of Pace Analytical Services, LLC.
Page 12 of 17

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Butner Landfill MNA
Pace Project No.: 92395737
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
ANALYTE QUALIFIERS
B3 The dissolved oxygen depletion of the dilution water blank exceeded 0.2 mg/L.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
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Date: 08/27/2018 10:43 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 17

aceAnalytical
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Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Butner Landfill MNA
92395737
Analytical
Lab ID
Sample ID
QC
Batch Method
QC Batch
Analytical Method
Batch
92395737001
3902-MW2R
SM
2320B-2011
426307
92395737002
3902-MW3R
SM
2320B-2011
426307
92395737001
3902-MW2R
SM
5210B-2011
424972
SM
5210B-2011
424997
92395737002
3902-MW3R
SM
5210B-2011
424972
SM
5210B-2011
424997
92395737001
3902-MW2R
EPA 300.0 Rev 2.1 1993
424964
92395737002
3902-MW3R
EPA 300.0 Rev 2.1 1993
424964
92395737001
3902-MW2R
SM
5220D-2011
425207
SM
5220D-2011
425443
92395737002
3902-MW3R
SM
5220D-2011
425207
SM
5220D-2011
425443
92395737001
3902-MW2R
SM
5310B-2011
427055
92395737002
3902-MW3R
SM
5310B-2011
427055
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/27/2018 10:43 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 17

Document Name:
Sample Condition Upon Receipt(SCUR)
Document Revised: February 7, 2018
Page 1 of 2
Document No.:
F-CAR-CS-033-Rev.06
issuing Authority:
Pace Carolinas Quality Office
_ i aeeAnalytica!'
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville Raleigh[] Mechanicsville❑
SampleCondition Client Name:
Upon Receipt - Project #:
'� O CL _ ��'-r ( f4
Courier: ❑Fed Ex ❑UPS ,_ LJUSPS J ❑Client
❑ Commercial Place ❑Other: /
usto y ea resen nJes_ _ `�' o= 5eaisintact? Dyes [�t�O
Packing Material: ❑Bubble Wrap Dad ble Bags ❑None �❑ Other
Thermomete Type of Ice: ®Diet ❑slue
IR Gun IDr 92TO43
Cooler Temp (•C): ___ Correction Factor: Add/subtract (°C) _0.2
Cooler Temp Corrected (Ty J �
USDA Regulated Sail (�A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)?
WOfI : 92395737
92393737
II I VI II I III I II I II I III
Date/Initials Person Examining Contents:. l
Biological Tissue Frozen?
[-]Yes❑No 2fi/A
❑None
Temp should be above freezing to 6°C
❑Samples out of temp criteria. Samples en ice, cooling process
has begun
Did samples originate from a foreign source (interns "finally,
❑Yes j:No
ir)ctuoingnawan ana rueecv r%ILV)r Urea tfj—
Comments/Discrepancy:
Chain of Custody Present?
es
❑Na
❑N/A
1.
Samples Arrived within Hold Time?
LJY
, I)oN/A
2,
short Hold Time Analysis (02 hr.)?
Yes
t
Wl
❑N/A
3.
Rush Turn Around Time Requested?
[]Yes
o
[-]N/A
4.
Sufficient Volume?
L3"es
❑Na
❑NIA
S.
Correct Containers Used?
[Yes
❑No
❑N/A
6.
-Pace Containers Used?
a
[-]NO
❑N/A
Containers Intact?
[]fps
❑3No�
❑N/A
7,
Dissolved analysis: Samples Field Filtered?
❑Ye
BNo
❑NIA
&
Sample Labels Match COC?
Yes
❑No
❑N/A
9.
-Includes Date)Time/iD/Analysis Matrix: yJ
Headspace in VOA Vials (>S-6mm)?
[-]Yes
No
❑N/A
10.
Trip Blank Present?
❑Yes
o
❑N/A
11.
Trip Blank Custody Seals Present?
❑yes
DO-.
❑N/A
COMMENTS/SAMPLE DISCREPANCY
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time:
Field Data Required? Des ❑No
Project Manager SCURF Review: Date:
Project Manager SRF Review: Date: ail rsJ' `,
Page 15 of 17

Document Name:
Sample Condition Upon Receil
aceAnalAcal n Document No.:
F-CAR-CS-033-Rev.06
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oi[ and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottle
Document Revised: February 7, 2018
Page 1 of 2
Issuing Authority:
Pace Carolinas Quality Office
Project # Ufflt : c-)2395737
t
PM: NMG Due Date: 08/28/18
CLIENT: 92-Joyce Eng
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pH Adjustment Log for Preserved Samples
Sample ID Type of Preservative PH upon receipt Date preservation adjusted Time preservation Amount of preservative Lot d
adjusted I added
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will besentto the North Carolina DEHNR Certification Office (i.e.
Out of ho€d, incorrect preservative, out of temp, incorrect containers.
Page 16 of 17

Section A
Required Client Information:
Company: Joyce En inee
Address: 2211 West Me
Greensboro, NC 27407
Email To: vburbach i0
Phone: [phone]M
Requested Due DateffATc 10
Lu
w
F
1
2
3
4
5
fi
7
8
11
12
7
SAMPLE ID
One Character per box.
(A-Z, 0-9 1, -j
Sample Ids must be unique
CHAIN -OF -CUSTODY 1 Analytical Request Docurnef
The Chain -of -Custody is a LEGAL DOCUIV ENT. All relevant fields must be completed a curately.
Section B Section C
Required Project information: lnVGlce Information:
Report To: Van Burbach
Attention.
Jason Fails
Rd
Copy TO: Miguel Vazquez
Company Name:
Granvill
County, Solid Waste
Address:
P.O. Box 9
6, Oxford NC 27565
fin .com
Purchase Order No.
Client Project ID: Butner Landfill MNA
Pace PM: NicDle Gasiorow;
ult
Container Order Number:
Profile: 3566-2
Re
uested
Analysis
Fi
� a
�
o COLLECTED
Preservati
s
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aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
November 11, 2018
Mr. Van Burbach
Joyce Engineering -NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Oxford Comp Unit 1 & Butner LF
Pace Project No.: 92405939
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on November 05, 2018.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
��i Flo _ _.1I , .�:
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Mr. Daniel Girdner, LaBella Associates, D.P.C.
Miguel Vazquez, Joyce Engineering
Rochelle mesubed, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 11

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Oxford Comp Unit 1 & Butner LF
Pace Project No.: 92405939
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 11

aceAnalytical
—pacelabsxom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Oxford Comp Unit 1 & Butner LF
Pace Project No.: 92405939
Lab ID Sample ID Matrix Date Collected Date Received
92405939001 Equipment Blank Water 11/02/18 16:35 11/05/18 10:16
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 11

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: Oxford Comp Unit 1 & Butner LF
Pace Project No.: 92405939
Lab ID Sample ID Method
92405939001 Equipment Blank EPA 601 OD
REPORT OF LABORATORY ANALYSIS
Analytes
Analysts Reported
SH1
Laboratory
PAS I -A
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 11

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Oxford Comp Unit 1 & Butner LF
Pace Project No.: 92405939
Sample: Equipment Blank
Lab ID:
92405939001
Collected:
11/02/18 16:35
Received: 11/05/18 10:16 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL DF
Prepared
Analyzed
CAS No. Qual
6010 MET ICP
Analytical
Method: EPA 6010D
Preparation Method: EPA 3010A
Chromium
ND
ug/L
10.0
2.5 1
11/06/18 06:30
11/09/18 03:06
7440-47-3
Cobalt
ND
ug/L
10.0
2.5 1
11/06/18 06:30
11/09/18 03:06
7440-48-4
Vanadium
ND
ug/L
25.0
2.5 1
11/06/18 06:30
11/09/18 03:06
7440-62-2
Date: 11 /11 /2018 10:06 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 11

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Oxford Comp Unit 1 & Butner LF
Pace Project No.: 92405939
QC Batch: 440466 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Associated Lab Samples: 92405939001
METHOD BLANK: 2419390
Matrix:
Water
Associated Lab Samples: 92405939001
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
Chromium
ug/L
ND
10.0
2.5 11/09/18 02:28
Cobalt
ug/L
ND
10.0
2.5 11/09/18 02:28
Vanadium
ug/L
ND
25.0
2.5 11/09/18 02:28
LABORATORY CONTROL SAMPLE:
2419391
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Chromium
ug/L
500
490
98
80-120
Cobalt
ug/L
500
487
97
80-120
Vanadium
ug/L
500
495
99
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2419392
2419393
MS
MSD
92405943001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
Chromium ug/L
ND
500
500
494
487
99
97
75-125
2 20
Cobalt ug/L
10.0
500
500
481
475
94
93
75-125
1 20
Vanadium ug/L
4.1J
500
500
511
503
101
100
75-125
1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /11 /2018 10:06 AM without the written consent of Pace Analytical Services, LLC.
Page 6 of 11

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Oxford Comp Unit 1 & Butner LF
Pace Project No.: 92405939
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /11 /2018 10:06 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 11

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Oxford Comp Unit 1 & Butner LF
Pace Project No.: 92405939
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92405939001 Equipment Blank EPA 3010A 440466 EPA 6010D 440500
Date: 11 /11 /2018 10:06 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 8 of 11

Document Name;
Document Revised: February 7, 2018
aeeAnalAicai
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
F-GAR-CS-033•Rev,06
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑
Client Name:
Courier:
❑ Commercial
Greenwood ❑ Huntersville Er Raleigh❑ Mechanicsville❑
Project!: W0# : 92405939
-cN �irnmt�� t eft 6P5 ❑U5P5 ❑Client
❑other: 924OS939
Custody Seal Present? ❑Yes ❑No seals intact? ❑Yes ErNo
natahnitieis Person Examinlniz Contents: 0
Packing Material: ❑Bubble Wrap []Bubble Bags None ❑ Other Biological Tissue Fro en?
Thermometer []Yes [:]NOFIR Gun 10: 92T045 Type of Ice: [3Wet []Yes
❑None
Cooler Temp (°C): 31 r/ Correction Factor: Add/Subtract (°C] _{) j
�*-, Temp should be above freezing to b°C
Cooler Temp Corrected rcl: r lam' ❑samples out of temp criteria. Samples an ice, cooling process
hashegun
USDA Regulated Soil (E]---N//A, water sample)
Did samples origin a in a quarantine zone within the United States: CA, NY, or 5C (check maps►? Did samples originate from a foreign source linterna onally,
1-1— inrhirlinp Hawaii and Puerto Rical? FlYes 0
Comments/Discrepancy:
/
Chain of Custody Present?
2,Y-
❑No
❑N/A
1,
Samples Arrived within Hold Time?
❑Ves
❑N/a
N/A
2.
Short Hold Time Analysis (02 hr.)?
❑Yes
01v//o
❑N/A
3.
Rush Turn Around Time Requested?
❑Yes
ONo
❑N/A
4.
Sufficient Volume?
[DYes
ONO
❑N/A
S.
Correct Containers Used?
L7Yes
❑No
❑NIA
6.
-Pace Containers Used?
[ [YCs
❑No
❑N/A
Containers Intact?
['Yes
ONO
❑N/A
7.
Dissolved analysis; Samples Field Filtered?
❑Yes
❑No
0N/A
B.
Sample Labels Match COC?
(3�es
❑No
❑NIA
9.
-includes Date/Time/ID/Analysis Matrix:
CAJ
Headspace in VOA Vials (>5-6mm)?
Dyes
❑No
��
C❑N/A
10.
Trip Blank Present?
❑yes
❑No
CgZ;/AA
11.
Trip Blank Custody seals Present?
❑Yes
[]No
Ml /A
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Date/Time:
Lot ID of split containers;
Project Manager SCURF Review:
Project Manager SRF Review:
Field Data Required? ❑Yes []NO
Date:
Date: L;
Page 9 of 11

_, ace Analytical'
Document Name:
Sample Condition upon Recell
Document No.:
F-CAR-CS-033-Rev.06
*Check mark top half of box if pH and/or dechlorination Is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, coliform, TOC, Oil and Grease, DRO/8015 {water} DOC, LLHg
**Bottom half of box is to list number of bottle
Document Revised: February 7, 2018
Page 1 of 2
Issuing Authority:
Pace Carolinas Quality Office -
Project WO# : 92405939
RM: NMf Due Date: 11/19/18
CLIENT: 92-Joyce Eng
ayEr
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Note: Whenever there is a discrepancy affecting North Carolina compuance samples, a copy ui « +�, ++ �,,, �_•_ • •� ^ - -- -
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 10 of 11

CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. i
Section A
Section B Section C
Required Client Information:
Required Project Information: Invoice Information: Page: 1 Of 1
Report To: Van Burbach Attention: Jason Falls
Rd Copy To: Rochelle Mesubed company Name: Granville County, Solid Waste
Company: Joyce Engineering
Address: 2211 West Meadowvie1N
Greensboro, INC 27407
Address: P.O. Box 906, Oxford NC 27565
Regulatory Agency
Email To� vUi11! r!c:l r: yc:.'vc:�:I Ir111
CMI .Colic
Purchase Order No.
Phone: [phone] Fax
Client project ID: Oxford Compliance Unit 1 & Butner LF
State/ Location
Requested Due Date/TAT: 10 Da DdfauIt
Container Order Number:
North Carolina
_
Requested
An
lysis
Filtered
Y1N
o
COLLECTED
Preservatives
MnTFlx cooE
o
Drinking Wamr Dw
Water WT
o
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=
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was<a Warnr WW
Product P
SAMPLE ID 01=hd oL
—
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START
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'—'
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One Character per box. w,Pn wP
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6
7
8
9
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11
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ADDITIONAL COMMENTS
RELINQUISHED BY 1 AFFILIATION
DATE
TIME
ACCEPTED BY! AFFILIATION
DATE
TIME
SAMPLE CONDITIONS
MIS
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SAMPLER NAME AND SIGNATURE
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PRINT Name of SAMPLER: n--
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SIGNATURE of SAMPLER:
DATE Signed:
:'l ri
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UU
U)}

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
November 11, 2018
Mr. Van Burbach
Joyce Engineering -NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Butner Landfill
Pace Project No.: 92405943
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on November 05, 2018.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
��i Flo _ _.1I , .�:
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Mr. Daniel Girdner, LaBella Associates, D.P.C.
Miguel Vazquez, Joyce Engineering
Rochelle mesubed, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 14

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Butner Landfill
Pace Project No.: 92405943
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 14

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Butner Landfill
Pace Project No.: 92405943
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92405943001
92405943002
3902-MW2R
3902-MW2R (Filtered)
Water
Water
11/02/1815:00
11/02/18 15:00
11/05/1810:16
11/05/18 10:16
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 14

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: Butner Landfill
Pace Project No.: 92405943
Analytes
Lab lD Sample ID Method Analysts Reported Laboratory
92405943001 3902-MW2R EPA 6010D SH1 1 PASI-A
92405943002 3902-MW2R(Filtered) EPA 6010D SH1 1 PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 14

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
Butner Landfill
92405943
Lab Sample ID
Client Sample ID
Method
Parameters Result Units Report Limit Analyzed Qualifiers
92405943001
3902-MW2R
EPA 6010D
Cobalt 10.0 ug/L 10.0 11/09/18 02:41
92405943002
3902-MW2R (Filtered)
EPA 6010D
Cobalt, Dissolved 9.3 ug/L 5.0 11/08/18 22:56
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 14

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill
Pace Project No.: 92405943
Sample: 3902-MW2R Lab ID: 92405943001 Collected: 11/02/18 15:00 Received: 11/05/18 10:16 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Cobalt 10.0 ug/L 10.0 2.5 1 11/06/18 06:30 11/09/18 02:41 7440-48-4
Date: 11 /11 /2018 10:25 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 14

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill
Pace Project No.: 92405943
Sample: 3902-MW2R (Filtered) Lab ID: 92405943002 Collected: 11/02/18 15:00 Received: 11/05/18 10:16 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP, Dissolved Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Cobalt, Dissolved 9.3 ug/L 5.0 2.5 1 11/06/18 14:50 11/08/18 22:56 7440-48-4
Date: 11 /11 /2018 10:25 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 14

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill
Pace Project No.: 92405943
QC Batch: 440466
Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A
Analysis Description: 6010 MET
Associated Lab Samples: 92405943001
METHOD BLANK: 2419390
Matrix: Water
Associated Lab Samples: 92405943001
Blank Reporting
Parameter Units
Result Limit MDL
Analyzed
Qualifiers
Cobalt ug/L
ND 10.0
2.5 11/09/18 02:28
LABORATORY CONTROL SAMPLE: 2419391
Spike LCS LCS
% Rec
Parameter Units
Conc. Result % Rec
Limits Qualifiers
Cobalt ug/L
500 487 97
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2419392 2419393
MS MSD
92405943001
Spike Spike MS MSD
MS MSD
% Rec Max
Parameter Units Result
Conc. Conc. Result Result
% Rec % Rec
Limits RPD RPD Qual
Cobalt ug/L 10.0
500 500 481 475
94 93
75-125 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /11 /2018 10:25 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 14

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill
Pace Project No.: 92405943
QC Batch: 440518
Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A
Analysis Description: 6010 MET Filtered Diss.
Associated Lab Samples: 92405943002
METHOD BLANK: 2419525
Matrix: Water
Associated Lab Samples: 92405943002
Blank Reporting
Parameter Units
Result Limit MDL
Analyzed
Qualifiers
Cobalt, Dissolved ug/L
ND 5.0
2.5 11/08/18 22:50
LABORATORY CONTROL SAMPLE: 2419526
Spike LCS LCS
% Rec
Parameter Units
Conc. Result % Rec
Limits Qualifiers
Cobalt, Dissolved ug/L
500 487 97
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2419527 2419528
MS MSD
92405943002
Spike Spike MS MSD
MS MSD
% Rec Max
Parameter Units Result
Conc. Conc. Result Result
% Rec % Rec
Limits RPD RPD Qual
Cobalt, Dissolved ug/L 9.3
500 500 434 435
85 85
75-125 0 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /11 /2018 10:25 AM without the written consent of Pace Analytical Services, LLC.
Page 9 of 14

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Butner Landfill
Pace Project No.: 92405943
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /11 /2018 10:25 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 14

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Butner Landfill
Pace Project No.: 92405943
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92405943001 3902-MW2R EPA 3010A 440466 EPA 6010D 440500
92405943002 3902-MW2R (Filtered) EPA 3010A 440518 EPA 6010D 440673
Date: 11 /11 /2018 10:25 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 14

Laboratory receiving samples:
Asheville ❑ Eden[]
Client (Name:
Document Name:
Condition Upon Rec
Document No.:
F-CAR-CS-033-Rev.[
Greenwood ❑
�Oee-
Courier. e x ❑UPS ❑USPs
❑ Commercial [� ace ❑Other:
Custody Seal Present? ❑Yes 'U- 1a Sealslntact? Des
Document Revised: February 7, 2018
Page 1 of 2
Issuing Authority:
Pace Carolinas Qualitv Office
Huntersville 9-1, Raleigh[] Mechanicsville❑
Project W®# : 92445943
]Client IIIH�I MIMI
92405943
°'c
Bate/Initials Person Examining Contents:
Packing Material: —]Bubble Wrap ❑Bubb]e Bags None El Other Biological Tissue Fr en?
Thermomete ❑Yes ❑Np /A
IR G,n ID: 92TO45 Type of Ice: [94eet ❑Blue ❑None
Cooler Temp (°Cj: 3- % Correction Factor: Add/Subtract ('Q _0 1
iJ "^ Temp should be above freezing to 6°C
Cooler Temp Corrected I'Cj: 05amples out of temp criteria. Samples on ice, cooling process
has begun
USDA Regulated $all Q N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or 5C (check maps)? Did samples originate from a foreign source (intern Clonally,
❑Yes [No
including Hawaii and Puerto Rico)? []Yes Qfo
Cam ments/Dlscre as new:
Chain of Custody Present?
Samples Arrived within Hold Time?
Short Hold Time Analysis 1<72 hr,j?
Rush Turn Around Time Requested?
Sufficient Volume?
Correct Containers Used?
-Pace Containers Used?
Containers Intact?
Dissolved analysis: Samples Field Filtered?
Sample Labels Match COC?
-Includes Date/7ime/ID/Analysis Mat
Headspace in VOA Vials {>5-6mm)?
Trip Blank Present?
Trip Blank Custody Seals Present?
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
NYes
l JNo
L]N/A
1,
045
❑NO
❑N/A
2.
Dyes
©No
❑N/A
3.
❑Yes
[}40
❑N/A
4.
lyes
❑No
❑N/A
5.
[�es
❑No
❑N/A
6.
Lt[. Yes UND L,N//A 7.
Des []NO©4/A g.
911es []No []N/A 9,
tj l_l
❑Yes_ ❑ND ©N/A 110.
Des LINO QN/A 11.
Date/Time:
Project Manager SCURF Review: V 6IIA111 6
Project Manager SRF Revlew:
Field Data Required? Des ❑NO
ID of split containers:
Date: �J
Date:
Page 12 of 14

Document Name:
Document Revised: February 7, 2018
aceAnalytrcala
Sample Conciltlon Upon RecelptlSCUR)
Page 1 of 2
Document No.:
Issuing Authority:
F•CAR•CS-033-Rev,06
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Colifo►m, TOC, Oil and Grease, DRO/9015 (water) HOC, LLHg
* * Rottom-balf_of_boxas-to-list-numbet•-o# bottle
Project IWO# : 92405943
hM: NMG Due Date: 11/12/18
CLIENT: 92—Joyce Eng
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pH Adjustment Log for preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount Of Preservative
added
Lot #1
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 13 of 14

Section A
Required Client Information:
company: Jo ce En it
4ddress: 2211 West I
3reensboro, NC 27407
-mail To: vburbacti-,�
hone: 336 323-01
4equested Due DatefrAT,
1
2
10
v
0
v
CHAIN -OF -CUSTODY / Analytical Request Document co
0)
The Chain -Of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section B
Section C
Required Project Information:
Invoice Information:
Report To: Veit 8Ur1]ach [Page Of t
Auernion: Jason Falls alopy To: Rochelle M8subed company Name: Granville Count , Solid Waste
Address: p.0. 8ox 90fi, Oxford NC 27565
urchase Order No. Ra ulato A enclient Project l-, Butner Landfill
North Carolina
Reguested Anal sis Filtered YIN
MATRIX
U-k,r,9woie,
cone
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,
COLLECTED
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Preservatives
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WM"
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SAMPLE ID
aely Wa�ar
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orh°`
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DATE TIME DATE TIME
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ADDITIONAL COMMENT RELINQUISHED BY I AFFILIATION
q
SIC
DATE TIME
eDBY/AFFILIATION DATE TIME
SAMPLE CONDITIONS
NAME AND SIGNATURE
75
Name of SgMPLER;
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TURE of SAMPLER: 2CL
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! DATE Signed:
E z
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Appendix C
Historical Groundwater Elevations

APPENDIX C: Historical Groundwater Elevations
Background
Downgradient
Well ID.
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Well TOC Elev.:
460.51
331.60
330.96
340.80
343.88
362.53
328.40
Well Depth:
56.00
18.85
35.83
31.43
23.52
32.63
32.80
21-Aug-99
418.68
329.13
328.06
330.50
330.83
352.10
NI
16-Nov-99
419.75
325.38
324.51
331.53
334.33
352.97
NI
10-May-00
424.53
329.60
328.83
334.15
334.49
355.72
NI
26-Oct-00
419.21
329.26
328.15
331.33
330.94
352.78
NI
18-Apr-01
418.76
329.42
328.63
333.57
334.36
354.22
NI
26-Oct-01
412.53
329.04
327.94
330.57
330.23
350.92
NI
13-Jun-02
413.70
328.38
327.41
330.21
330.29
351.04
NI
19-Nov-02
413.40
329.25
328.35
331.57
337.17
350.94
NI
27-Jun-03
423.61
329.57
328.93
334.24
333.99
355.21
NI
29-Dec-03
420.23
329.70
329.11
334.49
334.78
354.92
NI
30-Jun-04
418.81
329.38
328.48
332.26
331.39
353.10
NI
28-Dec-04
418.02
329.50
328.91
333.45
334.14
355.14
NI
29-Jun-05
418.81
329.10
329.26
331.62
330.90
352.76
NI
29-Dec-05
413.38
329.29
328.71
332.78
334.27
351.52
NI
27-Jun-06
414.75
329.17
328.40
332.18
333.56
353.43
NI
28-Dec-06
415.54
329.40
328.86
333.57
335.24
354.02
NI
12-Jul-07
438.64
328.69
327.97
331.31
330.52
352.30
NI
18-Dec-07
412.59
328.94
328.08
330.32
327.92
347.90
306.54
8-Jul-08
414.52
329.20
326.00
331.46
330.85
351.03
NM
17-Dec-08
412.79
329.39
328.84
333.15
335.03
350.82
NM
9-Jul-09
417.16
329.17
329.48
332.30
331.36
352.17
310.12
16-Dec-09
418.11
329.55
329.09
334.57
336.94
352.87
NM
24-Jun-10
422.42
329.41
328.77
333.65
333.15
353.62
NM
13-Dec-10
415.96
329.49
328.85
332.81
330.34
350.08
NM
20-Jun-11
416.00
328.95
328.18
336.77
331.38
351.83
NM
5-Dec-11
412.94
329.31
328.65
332.32
329.51
349.87
NM
11-Jun-12
414.56
329.10
328.35
332.52
331.33
351.75
312.50
12-Dec-12
412.83
329.19
328.36
331.67
330.35
349.48
NM
1-May-13
415.69
329.65
329.13
334.49
335.15
353.63
317.11
5-Aug-13
417.97
329.02
328.41
333.32
332.83
353.01
NM
24-Feb-14
415.81
329.68
329.17
334.48
331.63
351.78
316.15
11-Aug-14
416.23
329.38
328.48
332.04
329.08
350.08
310.93
10-Mar-15
417.09
329.87
329.45
335.07
336.42
353.13
317.55
17-Aug-15
417.71
328.65
327.81
331.05
327.73
347.63
308.80
17-Feb-16
418.51
330.10
329.71
335.05
337.53
353.44
317.87
9-Aug-16
418.59
329.50
328.61
332.95
330.95
352.03
312.65
13-Feb-17
415.21
329.45
328.96
333.10
333.03
350.83
313.45
22-Aug-17
414.68
328.55
327.61
331.60
329.78
350.38
310.55
5-Feb-18
412.31
329.41
328.21
332.07
328.87
348.18
317.10
14-Aug-18
415.86
328.96
327.96
331.97
329.68
350.12
312.51
Notes: TOC = Top of casing.
Elevations in feet above mean sea level.
Granville County -Butner Landfill
Permit No. 39-02
NM = Water level not measured.
NI = Well not yet installed.
Joyce Engineering
December 2018

Appendix D
Historical Constituents in Groundwater

APPENDIX D: Historical Constituents in Groundwater
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
INORGANICS
Antimony
8-Sep-94
---
30
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
30
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
30
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
30
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
30
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
30
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
30
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
30
ND
ND
ND
ND
ND
ND
---
---
1-Dec-97
---
30
ND
ND
ND
ND
ND
ND
---
---
20-May-98
---
30
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
30
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
30
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
30
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
30
ND
80.0
38.0
32.0
33.0
31.0
---
---
26-Oct-00
---
30
30.0
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
30
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
30
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
30
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
30
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
30
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
30
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
30
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
30
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
30
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
30
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
30
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
6
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
6
ND
ND
ND
ND
ND
ND
---
ND
GWPS = 1.4 µg/L (10/23/07)
19-Dec-07
---
6
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
---
6
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
2.6
6.0
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
2.6
6.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
2.6
6.0
ND
ND
ND
ND
ND
ND
---
ND
NC 2B = NE (03/24/10)
24-Jun-10
2.6
6.0
ND
ND
ND
2.9 J
ND
ND
---
ND
GWPS = 1 µg/L (8/1/10)
13-Dec-10
2.6
6.0
ND
ND
3.0 J
ND
2.8 J
ND
---
ND
20-Jun-11
5.0
6.0
ND
ND
ND
ND
6.0
ND
---
ND
5-Dec-11
5.0
6.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.0
6.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
6.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
5.0
6.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
6.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
5.0
6.0
8.8
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
EPA 6010
5.0
6.0
ND
10.5
8.0
ND
ND
ND
---
ND
10-Mar-15
EPA 6010
3.8
6.0
ND
7.1
6.5
3.9 J
ND
ND
---
ND
18-Aug-15
EPA 6010
3.8
6.0
ND
6.2
4.8 J
4.1 J
ND
ND
---
ND
16-Feb-16
EPA 6010
3.8
6.0
ND
9.9
6.5
4.3 J
ND
ND
---
ND
9-Aug-16
EPA 6010
3.8
6.0
ND
7.7
ND
ND
ND
ND
---
ND
13-Feb-17
EPA 6010
3.9
6.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
EPA 6010
3.9
6.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 6010
3.9
6.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
EPA 601OD
3.9
6.0
ND
ND
ND
ND
ND
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 1 of 42

APPENDIX D: Historical Constituents in Groundwater
r
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Arsenic
8-Sep-94
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
10
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
10
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
10
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
10
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
10
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
10
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
10
6.0 J
15.0
ND
ND
ND
ND
---
---
1-Dec-97
---
10
ND
5.0 J
ND
ND
ND
ND
---
---
20-May-98
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
10
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
10
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
10
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
10
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
10
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
10
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
10
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
10
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
2.0 J
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 50 µg/L (10/23/07)
19-Dec-07
---
10
ND
4.1 J
ND
ND
ND
ND
ND
ND
8-Jul-08
---
10
ND
4.9 J
ND
ND
ND
ND
---
ND
17-Dec-08
2.7
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
2.7
10.0
ND
13.5
10.9
5.6 J
ND
4.0 J
ND
ND
16-Dec-09
2.7
10.0
ND
10.6
6.4 J
5.0 J
ND
3.6 J
---
ND
NC 2L = 10 µg/L (02/05/10)
24-Jun-10
2.7
10.0
ND
11.8
8.1 J
8.2 J
3.3 J
3.1 J
---
ND
Resample >
12-Aug-10
2.7
10.0
---
---
7.2 J
---
---
---
---
ND
Resample >
31-Aug-10
2.7
10.0
---
15.4
---
---
---
---
---
ND
13-Dec-10
2.7
10.0
ND
4.9 J
2.7 J
5.4 J
ND
ND
---
ND
Arsenic
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.0
10.0
ND
5.4 J
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
5.6 J
ND
ND
ND
---
ND
24-Feb-14
5.0
10.0
ND
6.4 J
ND
ND
ND
ND
ND
ND
12-Aug-14
EPA 6010
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
EPA 6010
2.5
10.0
4.1 J
5.4 J
ND
ND
3.1 J
3.2 J
---
3.0 J
18-Aug-15
EPA 6011
2.5
10.0
ND
5.1 J
ND
ND
ND
ND
---
ND
16-Feb-16
EPA 6010
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
EPA 6010
2.5
10.0
ND
ND
ND
ND
ND
ND
---
5.1 J
13-Feb-17
EPA 6010
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
EPA 6010
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 6010
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
EPA 6010D
5.0
10.0
ND
5.4 J
ND
ND
ND
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 2 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Barium
8-Sep-94
---
500
ND
270
ND
ND
830
860
---
---
1-Dec-94
---
500
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
500
ND
ND
ND
ND
510
ND
---
---
2-Mar-95
---
500
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
500
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
500
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
500
ND
82.0
30.0
ND
15.0
ND
---
---
17-Jun-97
---
500
200
320
37.0
17.0
210
31.0
---
---
1-Dec-97
---
500
61.0
180
43.0
46.0
220
33.0
---
---
20-May-98
---
500
30.0
150
45.0
13.0
180
22.0
---
---
19-Nov-98
---
500
48.0
120
42.0
ND
380
12.0
---
---
21-Jul-99
---
500
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
500
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
500
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
500
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
500
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
500
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
500
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
500
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
500
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
500
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
500
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
500
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
500
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
500
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
500
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
500
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
100
5.2 J
120
64.9
1.5 J
64.1
1.8 J
---
0.20 J
12-Jul-07
---
100
2.5 1
129
65.7 J
1.1 1
77.0 1
1.3 1
---
ND
NC 2L = 2,000 µg/L (10/23/07)
19-Dec-07
---
100
2.8 B
99.2
50.0 B
1.4 B
49.6 B
1.7 B
87.8
11.7
8-Jul-08
---
100
5.8 J
102
58.4 J
1.1 B
57.9 J
1.2 B
---
0.29 J
17-Dec-08
0.20
100
2.7 B
92.9 J
53.1 B
1.2 B
55.5 J
1.1 B
---
10.7 J
9-Jul-09
0.20
100
4.6 B
121
63.4 B
0.37 B
81.4 B
0.94 B
72.4 B
17.6 1
16-Dec-09
0.20
100
2.9 B
108
62.8 B
0.61 B
56.8 B
0.87 B
---
17.1 J
NC 2L = 700 µg/L (02/05/10)
24-Jun-10
0.20
100
2.5 B
115 B
61.1 B
1.6 B
93.5 B
1.4 B
---
27.3 J
13-Dec-10
0.20
100
4.3 B
122
67.9 J
1.3 B
90.6 1
1.5 B
---
12.1 J
20-Jun-11
5.0
100
ND
108
70.7 J
ND
84.7 1
ND
---
ND
5-Dec-11
5.0
100
ND
118
73.0 J
ND
90.6 J
ND
---
ND
II-Jun-12
5.0
100
ND
138
65.2 J
ND
76.4 J
ND
61.3 J
ND
12-Dec-12
5.0
100
ND
113
64.7 1
ND
73.6 1
ND
---
ND
1-May-13
5.0
100
ND
118
69.1 J
ND
84.2 J
ND
81.2 J
ND
5-Aug-13
5.0
100
ND
111
65.1 J
ND
95.6 J
ND
---
ND
24-Feb-14
5.0
100
ND
93.8 J
44.8 J
ND
139
ND
ND
ND
12-Aug-14
EPA 6010
5.0
100
ND
125
66.4 1
ND
121
ND
---
ND
10-Mar-15
EPA 6010
2.5
100
3.0 J
109
61.8 J
ND
116
ND
---
ND
18-Aug-15
EPA 6010
2.5
100
4.4 J
119
63.1 J
ND
81.3 J
ND
---
ND
16-Feb-16
EPA 6010
2.5
100
5.2 J
123
72.7 J
3.0 J
126
ND
---
ND
9-Aug-16
EPA 6010
2.5
100
4.5 1
123
73.3 1
ND
109
ND
---
ND
13-Feb-17
EPA 6010
2.5
100
7.8 J
112
68.3 J
ND
151
5.6 J
---
ND
22-Aug-17
EPA 6010
2.5
100
ND
102
64.5 J
ND
99.9 J
ND
---
ND
5-Feb-18
EPA 6010
2.5
100
8.0 J
117
73.5 1
ND
161
ND
---
ND
13-Aug-18
EPA 6010D
2.5
100
3.8 J
116
67.6 1
ND
103
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 3 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
mvd=
MW-6
NES-1
Blanks
Beryllium
8-Sep-94
---
2
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
2
ND
ND
ND
ND
4.0
ND
---
---
9-Feb-95
---
2
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
2
ND
ND
ND
ND
2.0
ND
---
---
15-Nov-95
---
2
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
2
ND
ND
ND
ND
6.0
ND
---
---
22-Nov-96
---
2
ND
ND
ND
ND
3.0
ND
---
---
17-Jun-97
---
2
2.0
3.0
ND
ND
1.0
ND
---
---
1-Dec-97
---
2
ND
ND
ND
ND
ND
ND
---
---
20-May-98
---
2
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
2
ND
ND
ND
ND
2.0
ND
---
---
21-Jul-99
---
2
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
2
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
2
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
2
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
2
ND
12.0
ND
ND
ND
ND
---
---
27-Oct-01
---
2
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
2
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
2
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
2
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
2
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
2
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
1
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
1
ND
ND
ND
ND
ND
ND
---
ND
GWPS = 4 µg/L (10/23/07)
19-Dec-07
---
1
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
---
1
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
0.10
1.0
ND
ND
ND
ND
0.14 J
ND
---
ND
9-Jul-09
0.10
1.0
ND
0.18 J
0.22 J
0.17 J
ND
ND
0.23 J
ND
16-Dec-09
0.10
1.0
ND
0.15 J
0.17 J
0.15 J
0.25 J
ND
---
ND
NC 2B = 6.5 µg/L (02/05/10)
24-Jun-10
0.10
1.0
ND
ND
0.27 J
0.16 J
ND
ND
---
ND
13-Dec-10
0.10
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
EPA 6010
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
EPA 6010
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
EPA 6010
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
EPA 6010
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
EPA 6010
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
EPA 6010
0.50
1.0
ND
ND
ND
ND
0.57 J
ND
---
ND
22-Aug-17
EPA 6010
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 6010
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
EPA 6010D
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 4 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyt
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Cadmium
8-Sep-94
---
1
ND
ND
ND
ND
ND
4.0
---
---
1-Dec-94
---
1
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
1
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
1
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
1
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
1
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
1
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
1
ND
3.0
1.0
ND
ND
ND
---
---
1-Dec-97
---
1
ND
2.0
ND
ND
ND
ND
---
---
20-May-98
---
1
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
l
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
1
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
1
ND
3.0
3.0
ND
2.0
ND
---
---
10-May-00
---
1
5.0
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
1
ND
2.0
ND
ND
ND
ND
---
---
18-Apr-01
---
1
ND
11.0
ND
ND
ND
ND
---
---
27-Oct-01
---
1
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
1
ND
2.0
ND
ND
ND
ND
---
---
19-Nov-02
---
1
2.0
2.0
ND
ND
2.0
ND
---
---
27-Jun-03
---
1
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
1
ND
1.0
ND
ND
ND
ND
---
ND
30-Jun-04
---
l
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
1
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
1
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
1
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
l
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
1
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
1
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 1.75 µg/L (10/23/07)
19-Dec-07
---
1
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
---
1
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
0.50
1.0
ND
1.4
ND
ND
ND
ND
ND
ND
16-Dec-09
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 2 µg/L (02/05/10)
24-Jun-10
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
EPA 6010
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
EPA 6010
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
EPA 6010
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
EPA 6010
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
EPA 6010
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
EPA 6010
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
EPA 6010
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 6010
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
EPA 6010D
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 5 of 42

APPENDIX D: Historical Constituents in Groundwater
r
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Chromium
8-Sep-94
---
10
8.0
44.0
ND
6.0
48.0
80.0
---
---
1-Dec-94
---
10
14.0
ND
ND
ND
18.0
ND
---
---
9-Feb-95
---
10
14.0
ND
ND
10.0
ND
ND
---
---
2-Mar-95
---
10
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
10
13.0
13.0
ND
ND
ND
ND
---
---
28-May-96
---
10
33.0
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
10
3.0
ND
ND
ND
ND
3.0
---
---
17-Jun-97
---
10
57.0
43.0
ND
3.0
2.0
6.0
---
---
1-Dec-97
---
10
29.0
ND
ND
ND
ND
ND
---
---
20-May-98
---
10
10.0
3.0
ND
ND
12.0
ND
---
---
19-Nov-98
---
10
17.0
3.0
ND
ND
5.0
ND
---
---
21-Jul-99
---
10
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
10
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
10
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
10
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
10
ND
12.0
ND
ND
ND
ND
---
---
27-Oct-01
---
10
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
10
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 50 µg/L (10/23/07)
19-Dec-07
---
10
ND
2.0 B
ND
ND
ND
ND
1.1 B
1.4 J
8-Jul-08
---
10
ND
0.54 J
0.58 J
ND
ND
ND
---
ND
17-Dec-08
0.40
10.0
0.73 J
1.8 J
0.96 J
ND
0.96 J
0.70 J
---
ND
9-Jul-09
0.40
10.0
1.2 J
2.4 J
1.1 J
1.6 J
0.68 J
0.53 J
4.8 J
ND
16-Dec-09
0.40
10.0
1.3 J
ND
ND
ND
0.95 J
ND
---
ND
NC 2L = 10 µg/L (02/05/10)
24-Jun-10
0.40
10.0
1.1 B
3.5 B
2.8 B
2.4 B
1.2 B
1.4 B
---
0.71 J
13-Dec-10
0.40
10.0
2.5 J
1.3 J
1.8 J
0.69 J
0.57 J
1.2 J
---
ND
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.0
10.0
ND
8.6 J
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
10.0
ND
5.2 J
ND
ND
ND
ND
---
ND
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
EPA 6010
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
EPA 6010
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
EPA 6010
2.5
10.0
ND
2.7 J
ND
ND
ND
6.7 J
---
ND
16-Feb-16
EPA 6010
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
EPA 6010
2.5
10.0
2.8 B
2.8 B
ND
ND
ND
ND
---
2.9 J
13-Feb-17
EPA 6010
2.5
10.0
ND
2.6 J
ND
ND
ND
ND
---
ND
22-Aug-17
EPA 6010
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 6010
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
EPA 6010D
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 6 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Cobalt
8-Sep-94
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
10
11.0
ND
13.0
16.0
22.0
ND
---
---
9-Feb-95
---
10
20.0
14.0
ND
48.0
39.0
ND
---
---
2-Mar-95
---
10
16.0
21.0
ND
29.0
121.0
ND
---
---
15-Nov-95
---
10
20.0
21.0
ND
ND
27.0
ND
---
---
28-May-96
---
10
30.0
16.0
ND
ND
122
ND
---
---
22-Nov-96
---
10
6.0
13.0
ND
4.7
93.0
ND
---
---
17-Jun-97
---
10
130
38.0
ND
6.0
45.0
3.0
---
---
1-Dec-97
---
10
32.0
21.0
ND
12.0
36.0
4.0
---
---
20-May-98
---
10
15.0
16.0
2.0
9.0
100
3.0
---
---
19-Nov-98
---
10
21.0
16.0
2.0
7.0
180
3.0
---
---
21-Jul-99
---
10
ND
16.0
ND
ND
100
ND
---
---
16-Nov-99
---
10
ND
15.0
ND
ND
38.0
ND
---
---
10-May-00
---
10
ND
17.0
ND
ND
61.0
ND
---
---
26-Oct-00
---
10
ND
15.0
ND
ND
ND
ND
---
---
18-Apr-01
---
10
ND
27.0
ND
ND
74.0
ND
---
---
27-Oct-01
---
10
ND
12.0
ND
ND
47.0
ND
---
---
13-Jun-02
---
10
ND
14.0
ND
ND
251
ND
---
---
19-Nov-02
---
10
ND
10.0
ND
ND
57.0
ND
---
---
27-Jun-03
---
10
ND
15.0
ND
ND
75.0
ND
---
---
30-Dec-03
---
10
ND
17.0
ND
ND
52.0
ND
---
ND
30-Jun-04
---
10
ND
16.0
ND
ND
31.0
ND
---
ND
29-Dec-04
---
10
ND
11.0
ND
ND
46.0
ND
---
ND
29-Jun-05
---
10
ND
11.0
ND
ND
43.0
ND
---
ND
29-Dec-05
---
10
ND
12.0
ND
ND
30.0
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
72.5
ND
---
ND
29-Dec-06
---
10
ND
11.4
ND
ND
37.5
ND
---
ND
12-Jul-07
---
10
ND
11.8
ND
2.7
58.4
ND
---
ND
GWPS = 70 µg/L (10/23/07)
19-Dec-07
---
10
2.5 B
ND
ND
2.0 B
103
2.6 B
8.0 B
1.8 J
8-Jul-08
---
10
10.3 B
12.1 B
2.0 B
9.0 B
130
4.8 B
---
6.2 1
17-Dec-08
0.60
10.0
2.1 B
11.8 B
2.3 B
3.6 B
43.7
1.6 B
---
2.5 J
9-Jul-09
0.60
10.0
ND
6.2 J
ND
ND
100
ND
2.2 J
ND
16-Dec-09
0.60
10.0
ND
4.7 J
ND
ND
6.6 J
ND
---
ND
24-Jun-10
0.60
10.0
ND
16.3
ND
ND
25.0
ND
---
ND
GWPS = 1 µg/L (2/05/10)
13-Dec-10
0.60
10.0
2.5 B
15.5
ND
ND
11291
1ND1
---
1.6 11.0 J1 J
20-Jun-11
5.0
10.0
ND
14.2
ND
ND
81.8
ND
---
ND
5-Dec-11
5.0
10.0
ND
12.7
ND
ND
146
ND
---
ND
Resample >
25-Jan-12
5.0
10.0
---
---
---
---
47.5
---
---
ND
Cobalt
11-Jun-12
5.0
10.0
ND
14.2
ND
ND
101
ND
ND
ND
12-Dec-12
5.0
10.0
ND
11.3
ND
ND
113
ND
---
ND
1-May-13
5.0
10.0
ND
24.3
ND
ND
34.0
ND
ND
ND
5-Aug-13
5.0
10.0
ND
24.7
ND
ND
50.9
ND
---
ND
24-Feb-14
5.0
10.0
ND
18.4
ND
ND
9.6 J
ND
ND
ND
12-Aug-14
EPA 6010
5.0
10.0
ND
9.4 J
ND
ND
46.3
ND
---
ND
10-Mar-15
EPA 6010
2.5
10.0
ND
8.7 J
ND
ND
39.2
ND
---
ND
18-Aug-15
EPA 6010
2.5
10.0
ND
9.3 J
ND
ND
116
ND
---
ND
16-Feb-16
EPA 6010
2.5
10.0
ND
10.0
ND
ND
13.1
ND
---
ND
9-Aug-16
EPA 6010
2.5
10.0
ND
10.0 J
ND
ND
144
ND
---
ND
13-Feb-17
EPA 6010
2.5
10.0
ND
8.3 J
ND
ND
78.7
ND
---
ND
22-Aug-17
EPA 6010
2.5
10.0
ND
7.4 J
ND
ND
51.1
ND
---
ND
5-Feb-18
EPA 6010
2.5
10.0
ND
8.3 J
ND
ND
172
ND
---
ND
13-Aug-18
EPA 6010D
2.5
10.0
ND
10.7
ND
ND
97.7
ND
---
ND
Resamp e >
-Nov-
EPA1 OD
2.5
1
---
10.0
---
---
---
---
---
---
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 7 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Copper
8-Sep-94
---
200
ND
ND
ND
ND
ND
660
---
---
1-Dec-94
---
200
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
200
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
200
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
200
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
200
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
200
ND
ND
32.0
13.0
100
ND
---
---
17-Jun-97
---
200
34.0
350
13.0
37.0
28.0
77.0
---
---
1-Dec-97
---
200
19.0
72.0
14.0
88.0
15.0
34.0
---
---
20-May-98
---
200
12.0
48.0
380
41.0
53.0
28.0
---
---
19-Nov-98
---
200
10.0
ND
410
28.0
53.0
14.0
---
---
21-Jul-99
---
200
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
200
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
200
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
200
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
200
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
200
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
200
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
200
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
200
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
200
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
200
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
200
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
200
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
200
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
200
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
ND
ND
11.3
5.50 J
10.4
1.90 B
---
0.60 J
12-Jul-07
---
10
ND
ND
13.4
7.90
2.6 J
ND
---
ND
NC 2L = 1,000 µg/L (10/23/07)
19-Dec-07
---
10
2.0 B
ND
8.6 B
3.8 B
7.0 B
0.73 B
5.8 B
9.8
8-Jul-08
---
10
0.64 J
ND
12.1
3.7 J
8.5 J
ND
---
ND
17-Dec-08
0.30
10.0
0.80 J
13.6
10.2
3.9 J
11.9
0.37 J
---
ND
9-Jul-09
0.30
10.0
ND
ND
6.3 J
ND
5.7 J
ND
8.8 J
ND
16-Dec-09
0.30
10.0
ND
ND
9.2 J
1.6 J
5.7 J
ND
---
ND
24-Jun-10
0.3 0
10.0
ND
ND
10
1.2 J
5.1 J
ND
---
ND
13-Dec-10
0.30
10.0
1.1 B
ND
13.6
5.8 J
5.6 J
0.59 B
---
0.49 J
20-Jun-11
5.0
10.0
ND
ND
15.3
8.1 J
8.7 J
ND
---
ND
5-Dec-11
5.0
10.0
ND
ND
16.9
10.0 J
7.6 J
ND
---
ND
11-Jun-12
5.0
10.0
ND
10.7
12.2
6.3 J
7.4 J
ND
ND
ND
12-Dec-12
5.0
10.0
ND
ND
11.6
8.5 J
10.4
ND
---
ND
1-May-13
5.0
10.0
ND
ND
13.6
5.8 J
9.6 J
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
14.3
ND
10.2
ND
---
ND
24-Feb-14
5.0
10.0
ND
ND
12.2
ND
5.1 J
ND
ND
ND
12-Aug-14
EPA 6010
5.0
10.0
ND
ND
10.5
ND
ND
ND
---
ND
10-Mar-15
EPA 6010
2.5
10.0
ND
ND
8.7 J
ND
15.5
ND
---
ND
18-Aug-15
EPA 6010
2.5
10.0
ND
ND
6.7 J
5.6 J
10.1
ND
---
ND
NC 2L = 50 µg/L (06/01/2016)
16-Feb-16
EPA 6010
2.5
10.0
ND
ND
7.8 J
ND
5.1 J
ND
---
ND
9-Aug-16
EPA 6010
2.5
10.0
ND
ND
5.4 J
ND
7.8 J
ND
---
ND
13-Feb-17
EPA 6010
2.5
10.0
ND
ND
6.8 J
4.3 J
14.5
9.4 J
---
ND
22-Aug-17
EPA 6010
2.5
10.0
ND
ND
6.5 J
ND
5.7 J
4.4 J
---
ND
5-Feb-18
EPA 6010
2.5
10.0
ND
6.5 J
9.0 J
5.5 J
12.4
2.6 J
---
ND
13-Aug-18
EPA 6010D
2.5
10.0
ND
5.5 J
12.2
3.7 J
48.8
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 8 of 42

APPENDIX D: Historical Constituents in Groundwater
r
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Lead
8-Sep-94
---
10
ND
13.0
ND
ND
30.0
36.0
---
---
1-Dec-94
---
10
11.0
ND
ND
ND
36.0
ND
---
---
9-Feb-95
---
10
ND
ND
ND
10.0
37.0
ND
---
---
2-Mar-95
---
10
ND
ND
ND
ND
44.0
ND
---
---
15-Nov-95
---
10
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
10
ND
ND
ND
ND
42.0
ND
---
---
22-Nov-96
---
10
ND
ND
ND
ND
13.0
ND
---
---
17-Jun-97
---
10
20.0
29.0
ND
ND
13.0
ND
---
---
1-Dec-97
---
10
8.0
14.0
ND
5.0
14.0
ND
---
---
20-May-98
---
10
ND
6.0
ND
6.0
21.0
ND
---
---
19-Nov-98
---
10
5.0
ND
ND
ND
58.0
ND
---
---
21-Jul-99
---
10
ND
12.0
14.0
ND
ND
ND
---
---
16-Nov-99
---
10
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
10
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
10
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
10
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
10
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
10
11.0
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
10
ND
ND
ND
ND
12.0
ND
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
ND
ND
ND
ND
ND
2.1 J
---
ND
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 15 µg/L (10/23/07)
19-Dec-07
---
10
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
---
10
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
4.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
4.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
4.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
4.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
4.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
EPA 6010
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
EPA 6010
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
EPA 6010
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
EPA 6010
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
EPA 6010
2.5
10.0
ND
5.1 J
ND
ND
ND
ND
---
ND
13-Feb-17
EPA 6010
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
EPA 6010
2.5
10.0
ND
2.8 J
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 6010
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
EPA 6010D
2.5
10.0
ND
ND
ND
ND
4.6 J
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 9 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Mercury
1-Dec-97
---
0.5
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
0.5
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
0.5
ND
0.59
0.65
0.65
0.76
ND
---
---
10-May-00
---
0.5
---
ND
ND
ND
ND
---
---
---
26-Oct-00
---
0.5
---
ND
ND
ND
ND
---
---
---
18-Apr-01
---
0.5
---
ND
ND
ND
ND
---
---
---
13-Jun-02
---
0.5
---
ND
ND
ND
ND
---
---
---
27-Jun-03
---
0.5
---
ND
ND
ND
ND
---
---
---
30-Dec-03
---
0.5
---
---
---
---
---
---
---
---
30-Jun-04
---
0.5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
---
---
---
---
---
---
29-Jun-05
---
0.5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
---
---
---
---
---
---
28-Jun-06
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
---
---
---
---
---
---
---
---
---
12-Jul-07
---
0.2
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 1.05 µg/L (10/23/07)
19-Dec-07
---
---
---
---
---
---
---
---
ND
---
8-Jul-08
---
0.2
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
---
---
---
---
---
---
---
9-Jul-09
0.070
0.2
ND
ND
ND
ND
ND
ND
---
ND
16-Dec-09
---
---
---
---
---
---
---
NC 2L = 1 µg/L (02/05/10)
24-Jun-10
0.070
0.20
ND
ND
ND
ND
ND
0.098 J
---
ND
13-Dec-10
---
---
---
---
---
---
---
---
20-Jun-11
0.10
0.20
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
0.10
0.20
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
---
---
---
---
---
---
---
---
---
---
1-May-13
0.10
0.20
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
0.10
0.20
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
---
---
---
---
---
---
---
10-Mar-15
EPA 7470
0.10
0.20
ND
ND
ND
---
---
---
---
ND
16-Feb-16
EPA 7470
0.10
0.20
ND
ND
ND
---
---
---
---
ND
13-Feb-17
EPA 7470
0.10
0.20
ND
ND
ND
---
---
---
---
ND
22-Aug-17
EPA 7470
0.10
0.20
ND
ND
ND
---
---
---
---
ND
5-Feb-18
EPA 7470
0.10
0.20
ND
ND
ND
---
---
---
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 10 of 42

APPENDIX D: Historical Constituents in Groundwater
r
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Nickel
8-Sep-94
---
50
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
50
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
50
ND
72
ND
ND
ND
ND
---
---
2-Mar-95
---
50
ND
100
ND
ND
ND
ND
---
---
15-Nov-95
---
50
ND
61.0
ND
ND
ND
ND
---
---
28-May-96
---
50
ND
85.0
ND
ND
ND
ND
---
---
22-Nov-96
---
50
ND
72.0
ND
ND
ND
ND
---
---
17-Jun-97
---
50
75
98.0
ND
ND
ND
ND
---
---
1-Dec-97
---
50
ND
89.0
ND
ND
ND
ND
---
---
20-May-98
---
50
ND
91.0
ND
ND
ND
ND
---
---
19-Nov-98
---
50
ND
83.0
ND
ND
ND
ND
---
---
21-Jul-99
---
50
ND
109
ND
ND
ND
ND
---
---
16-Nov-99
---
50
ND
122
ND
ND
ND
ND
---
---
10-May-00
---
50
ND
104
ND
ND
ND
ND
---
---
26-Oct-00
---
50
ND
93.0
ND
ND
ND
ND
---
---
18-Apr-01
---
50
ND
107
ND
ND
ND
ND
---
---
27-Oct-01
---
50
ND
92.0
ND
ND
ND
ND
---
---
13-Jun-02
---
50
ND
98.0
ND
ND
ND
ND
---
---
19-Nov-02
---
50
ND
74.0
ND
ND
ND
ND
---
---
27-Jun-03
---
50
ND
85.0
ND
ND
ND
ND
---
---
30-Dec-03
---
50
ND
100
ND
ND
ND
ND
---
ND
30-Jun-04
---
50
ND
120 (81.0)
ND
ND
ND
ND
---
ND
29-Dec-04
---
50
ND
100
ND
ND
ND
ND
---
ND
29-Jun-05
---
50
ND
150 (92.0)
ND
ND
ND
ND
---
ND
29-Dec-05
---
50
ND
96.0
ND
ND
ND
ND
---
ND
28-Jun-06
---
50
ND
88.7
ND
ND
ND
ND
---
ND
29-Dec-06
---
50
ND
94.7
30.1
14.2
8.9 J
ND
---
ND
12-Jul-07
---
50
ND
99.0
30.6 J
13.9 J
13.7 J
ND
---
ND
NC 2L = 100 µg/L (10/23/07)
19-Dec-07
---
50
ND
83.4
23.7
11.0
18.3
ND
11.4
ND
8-Jul-08
---
50
ND
76.0
28.1 J
11.5 J
27.0 J
ND
---
ND
17-Dec-08
1.7
50.0
ND
75.5
27.8 J
12.2 J
11.0 B
ND
---
2.4 J
9-Jul-09
1.7
50.0
2.2 J
93.5
29.4 J
11.7 J
23.2 J
ND
13.1 J
ND
16-Dec-09
1.7
50.0
ND
81.2
28.2 J
11.8 B
2.6 B
ND
---
3.0 J
24-Jun-10
1.7
50.0
ND
76.3
19.7 J
9.0 J
7.0 J
4.5 J
---
ND
13-Dec-10
1.7
50.0
ND
83.0
23.5 J
6.8 B
20.7 J
ND
---
2.7 J
20-Jun-11
5.0
50.0
ND
78.8
30.1 J
11.2 J
15.3 J
ND
---
ND
5-Dec-11
5.0
50.0
ND
89.1
32.8 J
11.7 J
24.3 J
ND
---
ND
11-Jun-12
5.0
50.0
ND
91.8
28.9 J
10.0 J
17.3 J
ND
ND
ND
12-Dec-12
5.0
50.0
ND
91.8
29.2 J
9.3 J
21.1 J
ND
---
ND
1-May-13
5.0
50.0
ND
89.6
31.9 J
10.4 J
5.7 J
ND
ND
ND
5-Aug-13
5.0
50.0
ND
87.9
28.1 J
9.0 J
8.4 J
ND
---
ND
24-Feb-14
5.0
50.0
ND
83.1
16.7 J
10.4 J
ND
ND
ND
ND
12-Aug-14
EPA 6010
5.0
50.0
ND
97.9
29 J
12.9 J
13.2 J
ND
---
ND
10-Mar-15
EPA 6010
2.5
50.0
ND
91.9
32.9 J
12.3 J
8.2 J
ND
---
ND
18-Aug-15
EPA 6010
2.5
50.0
ND
98.0
28.0 J
11.9 J
26.2 J
5.4 J
---
ND
16-Feb-16
EPA 6010
2.5
50.0
ND
92.0
35.4 J
12.7 J
3.7 J
ND
---
ND
9-Aug-16
EPA 6010
2.5
50.0
3.3 J
88.9
29.0 J
12.2 J
30.7 J
ND
---
ND
13-Feb-17
EPA 6010
2.5
50.0
ND
89.6
30.4 J
13.5 J
16.2 J
ND
---
ND
22-Aug-17
EPA 6010
2.5
50.0
ND
84.2
28.2 J
12.3 J
13.5 J
ND
---
ND
5-Feb-18
EPA 6010
2.5
50.0
ND
87.6
29.8 J
11.7 J
28.5 J
ND
---
ND
13-Aug-18
EPA 6010D
2.5
50.0
ND
88.9
29.0 J
12.3 J
21.9 J
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 11 of 42

APPENDIX D: Historical Constituents in Groundwater
r
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Selenium
8-Sep-94
---
20
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
20
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
20
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
20
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
20
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
20
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
20
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
20
ND
ND
ND
ND
ND
ND
---
---
1-Dec-97
---
20
ND
ND
ND
ND
ND
ND
---
---
20-May-98
---
20
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
20
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
20
ND
ND
ND
ND
36.0
ND
---
---
16-Nov-99
---
20
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
20
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
20
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
20
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
20
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
20
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
20
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
20
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
20
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
20
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
20
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
20
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
20
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
20
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 50 µg/L (10/23/07)
19-Dec-07
---
10
ND
11.5
ND
ND
ND
ND
ND
ND
8-Jul-08
---
10
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
3.8
10
4.8 B
5.1 B
4.8 B
ND
ND
ND
---
4.9 J
9-Jul-09
3.8
10
ND
ND
4.2 J
ND
ND
ND
ND
ND
16-Dec-09
3.8
10
ND
ND
ND
5.1 J
ND
ND
---
ND
NC 2L = 20 µg/L (02/05/10)
24-Jun-10
3.8
10
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
3.8
10
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
10.0
10
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
10.0
10
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
10.0
10
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
10.0
10
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
10.0
10
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
10.0
10
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
10.0
10
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
EPA 6010
10.0
10
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
EPA 6010
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
EPA 6010
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
EPA 6010
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
EPA 6010
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
EPA 6010
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
EPA 6010
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 6010
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
EPA 6010D
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 12 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Silver
8-Sep-94
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
10
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
10
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
10
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
10
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
10
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
10
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-97
---
10
ND
8.0
ND
ND
ND
3
---
---
20-May-98
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
10
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
10
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
10
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
10
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
10
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
10
ND
15.0
ND
ND
ND
ND
---
---
27-Oct-01
---
10
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
10
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 17.5 µg/L (10/23/07)
19-Dec-07
---
10
ND
0.57 J
0.60 J
0.55 J
ND
0.33 J
ND
ND
8-Jul-08
---
10
ND
2.7 J
2.3 J
1.1 J
0.22 J
0.69 J
---
0.12 J
17-Dec-08
0.10
10.0
0.13 J
1.8 J
1.4 J
0.85 J
0.12 J
0.51 J
---
ND
9-Jul-09
0.10
10.0
ND
0.84 J
0.63 J
0.45 J
ND
0.11 J
ND
ND
16-Dec-09
0.10
10.0
0.12 J
2.0 J
1.6 J
1.0 J
0.12 J
0.52 J
---
ND
NC 2L = 20 µg/L (02/05/10)
24-Jun-10
0.10
10.0
ND
0.38 J
0.33 J
0.35 J
ND
ND
---
ND
13-Dec-10
0.10
10.0
0.15 B
1.3 J
0.99 J
0.45 B
{ND}
{ND}
---
0.21 10.19 T J
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
EPA 6010
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
EPA 6010
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
EPA 6010
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
EPA 6010
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
EPA 6010
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
EPA 6010
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
EPA 6010
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 6010
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
EPA 6010D
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 13 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Thallium
8-Sep-94
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
10
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
10
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
10
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
10
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
10
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
10
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
10
ND
3.0
ND
ND
ND
ND
---
---
1-Dec-97
---
10
ND
ND
ND
ND
ND
ND
---
---
20-May-98
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
10
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
10
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
10
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
10
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
10
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
10
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
10
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
10
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
10 J (ND)
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
22.0 (30.0)
13.0 (24.0)
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
23.0
20.0
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
25.7
12.6
ND
ND
ND
---
ND
29-Dec-06
---
6
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
5.5
ND
ND
ND
ND
ND
ND
---
ND
GWPS = 0.28 µg/L (10/23/07)
19-Dec-07
---
5.5
ND
4.0 J
ND
ND
ND
ND
ND
ND
8-Jul-08
---
5.5
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
3.0
5.5
ND
3.2 J
3.2 J
ND
ND
ND
---
ND
9-Jul-09
3.0
5.5
ND
ND
ND
4.1 J
ND
ND
ND
ND
16-Dec-09
3.0
5.5
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
3.0
5.5
ND
ND
5.2 J
3.1 J
ND
ND
---
ND
GWPS = 0.2 µg/L (10/1/10)
13-Dec-10
3.0
5.5
ND
ND
7.7
ND
ND
ND
---
ND
20-Jun-11
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
EPA 6010
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
EPA 6010
5.0
5.5
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
EPA 6010
5.0
5.5
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
EPA 6010
5.0
5.5
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
EPA 6010
5.0
5.5
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
EPA 6020B
0.02
5.5
0.023 J
0.040 J
ND
ND
0.035 J
ND
---
ND
22-Aug-17
EPA 6020B
0.02
5.5
ND
ND
ND
ND
0.033 J
ND
---
ND
5-Feb-18
EPA 6020
0.03
0.1
ND
ND
ND
ND
0.047 J
ND
---
ND
13-Aug-18
EPA 6020B
0.02
5.5
ND
ND
ND
ND
0.037 J
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 14 of 42

APPENDIX D: Historical Constituents in Groundwater
nalyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Tin
1-Dec-97
---
100
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
100
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
100
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
100
---
ND
ND
ND
ND
---
---
---
18-Apr-01
---
100
---
ND
ND
ND
ND
---
---
---
27-Oct-01
---
100
---
---
---
---
---
---
---
---
13-Jun-02
---
100
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
100
---
---
---
---
---
---
---
---
27-Jun-03
---
100
ND
149
127
ND
ND
ND
---
---
30-Dec-03
---
100
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
100
ND
41.1
14.4
3.2 J
ND
ND
---
ND
12-Jul-07
---
100
ND
35.2 J
13.9 J
5.2 J
ND
ND
---
ND
NC 2L = NE µg/L (10/23/07)
19-Dec-07
---
100
ND
33.6
7.4
ND
ND
ND
ND
ND
8-Jul-08
---
100
4.4 J
28.6 J
15.1 J
5.4 J
3.0 J
3.6 J
---
ND
17-Dec-08
1.8
100
ND
22.5 J
9.2 J
ND
ND
ND
---
ND
9-Jul-09
1.8
100
ND
21.4 J
8.6 J
ND
ND
ND
---
ND
16-Dec-09
1.8
100
ND
26.3 J
10.7 J
ND
ND
ND
---
ND
GWPS = 2100 µg/L (02/05/10)
24-Jun-10
1.8
100
ND
23.4 J
10.7 J
3.2 J
2.2 J
1.9 J
---
ND
13-Dec-10
1.8
100
ND
30.3 J
12.1 J
5.8 J
ND
ND
---
ND
20-Jun-11
5.0
100
ND
26.8 J
13.8 J
ND
ND
ND
---
ND
5-Dec-11
5.0
100
ND
25.8 J
13.9 J
ND
ND
ND
---
ND
11-Jun-12
5.0
100
ND
22.2 1
9.0 J
ND
ND
ND
ND
ND
12-Dec-12
5.0
100
ND
30.0 J
13.2 J
ND
ND
ND
---
ND
1-May-13
5.0
100
ND
25.8 J
12.2 J
ND
ND
ND
---
ND
5-Aug-13
5.0
100
ND
22.7 J
12.5 J
ND
ND
ND
---
ND
24-Feb-14
5.0
100
ND
26.7 J
11.7 J
9.8 J
ND
ND
ND
ND
12-Aug-14
EPA 6010
5.0
100
ND
30.7 J
8.2 J
ND
ND
ND
---
ND
10-Mar-15
EPA 6010
2.5
100
ND
28.7 J
11.1 J
ND
ND
ND
---
ND
18-Aug-15
EPA 6010
2.5
100
ND
27.7 J
7.5 J
ND
ND
ND
---
ND
16-Feb-16
EPA 6010
2.5
100
ND
28.6 J
10.4 J
---
---
---
---
ND
9-Aug-16
EPA 6010
2.5
100
ND
20.9 J
5.4 J
---
---
---
---
ND
13-Feb-17
EPA 6010
2.5
100
ND
25.5 B
7.8 B
---
---
---
---
3.6 J,
22-Aug-17
EPA 6010
2.5
100
ND
17.2 J
5.3 J
---
---
---
---
ND
5-Feb-18
EPA 6010
2.5
100
ND
20.3 J
9.5 J
---
---
---
---
ND
13-Aug-18
EPA 6010D
2.5
100
ND
22.2 J
7.4 J
---
---
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 15 of 42

APPENDIX D: Historical Constituents in Groundwater
r
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Vanadium
8-Sep-94
---
40
ND
ND
ND
ND
ND
130
---
---
1-Dec-94
---
40
63.0
ND
ND
45.0
ND
ND
---
---
9-Feb-95
---
40
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
40
41.0
ND
ND
45.0
ND
ND
---
---
15-Nov-95
---
40
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
40
83.0
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
40
7.0
17
ND
21.0
ND
ND
---
---
17-Jun-97
---
40
450
560
ND
19.0
ND
ND
---
---
1-Dec-97
---
40
62.0
88.0
ND
41.0
ND
10.0
---
---
20-May-98
---
40
25.0
15.0
ND
10.0
5.0
ND
---
---
19-Nov-98
---
40
33.0
29.0
5.0
16.0
9.0
5.0
---
---
21-Jul-99
---
40
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
40
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
40
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
40
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
40
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
40
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
40
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
40
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
40
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
40
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
40
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
40
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
40
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
40
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
40
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
25
2.7 J
ND
ND
14.5
ND
1.0 J
---
ND
12-Jul-07
---
25
ND
ND
ND
19.4 J
ND
ND
---
ND
GWPS = 3.5 µg/L (10/23/07)
19-Dec-07
---
25
2.2 B
2.2 B
ND
15.7 J
3.0 B
1.2 B
4.0 J
0.62 J
8-Jul-08
---
25
2.6 J
2.4 J
ND
14.6 J
1.4 J
1.2 J
---
0.20 J
17-Dec-08
0.20
25.0
1.9 B
2.3 B
ND
13.9 J
2.5 B
1.2 B
---
0.76 J
9-Jul-09
0.20
25.0
3.9 B
9.7 J
2.5 B
18.4 J
2.9 B
2.2 B
8.5 J
1.30 J
16-Dec-09
0.20
25.0
2.0 B
4.4 J
1.3 B
14.0 J
2.2 B
1.5 B
---
0.53 J
24-Jun-10
0.20
25.0
1.8 J
4.4 J
1.5 J
13.3 J
2.2 J
1.3 J
---
ND
GWPS = 0.3 µg/L (10/1/10)
13-Dec-10
0.20
25.0
3.2 J
3.6 J
0.35 B
16.6 J
1.8 B
1.0 B
---
0.36 J
20-Jun-11
5.0
25.0
ND
ND
ND
14.5 J
ND
ND
---
ND
5-Dec-11
5.0
25.0
ND
ND
ND
13.5 J
ND
ND
---
ND
11-Jun-12
5.0
25.0
ND
18.0 J
ND
12.3 J
ND
ND
ND
ND
12-Dec-12
5.0
25.0
ND
ND
ND
13.6 J
ND
ND
---
ND
1-May-13
5.0
25.0
ND
ND
ND
6.3 J
ND
ND
ND
ND
5-Aug-13
5.0
25.0
ND
ND
ND
10.2 J
ND
ND
---
ND
24-Feb-14
5.0
25.0
ND
ND
ND
12.9 J
ND
ND
ND
ND
12-Aug-14
EPA 6010
5.0
25.0
ND
ND
ND
18.6 J
ND
ND
---
ND
10-Mar-15
EPA 6010
2.5
25.0
3.1 J
11.6 J
6.2 J
13.4 J
ND
ND
---
ND
18-Aug-15
EPA 6010
2.5
25.0
3.4 J
6.8 J
3.6 J
19.6 J
2.8 J
ND
---
ND
16-Feb-16
EPA 6010
2.5
25.0
2.7 J
3.3 J
ND
14.4 J
ND
ND
---
ND
9-Aug-16
EPA 6010
2.5
25.0
2.5 J
3.5 J
ND
21.2 J
ND
ND
---
ND
13-Feb-17
EPA 6010
2.5
25.0
4.4 J
4.1 J
ND
18.4 J
3.0 1
2.9 J
---
ND
22-Aug-17
EPA 6010
2.5
25.0
ND
6.6 J
ND
20.6 J
2.6 J
ND
---
ND
5-Feb-18
EPA 6010
2.5
25.0
3.6 J
4.4 J
ND
17.6 J
ND
2.5 J
---
ND
13-Aug-18
EPA 6010D
2.5
25.0
ND
5.3 J
ND
20.4 J
2.9 J
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 16 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Zinc
8-Sep-94
---
50
110
160
ND
ND
320
430
---
---
1-Dec-94
---
50
132
ND
ND
70
164
ND
---
---
9-Feb-95
---
50
144
89
ND
91
79
74
---
---
2-Mar-95
---
50
67
ND
ND
ND
ill
ND
---
---
15-Nov-95
---
50
ND
50
ND
ND
ND
ND
---
---
28-May-96
---
50
136
ND
ND
ND
122
ND
---
---
22-Nov-96
---
50
79.0
48.0
28.0
ND
38.0
ND
---
---
17-Jun-97
---
50
370
410
33.0
39.0
36.0
69.0
---
---
1-Dec-97
---
50
140
110
11.0
45.0
34.0
30.0
---
---
20-May-98
---
50
70.0
63.0
23.0
31.0
47.0
34.0
---
---
19-Nov-98
---
50
61.0
33.0
21.0
17.0
53.0
10.0
---
---
21-Jul-99
---
50
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
50
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
50
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
50
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
50
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
50
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
50
ND
ND
ND
ND
382
ND
---
---
19-Nov-02
---
50
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
50
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
50
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
50
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
50
ND
ND
ND
66.0
ND
ND
---
ND
29-Jun-05
---
50
ND
54.0
56.0
ND
ND
ND
---
ND
29-Dec-05
---
50
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
50
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
50
8.0 J
ND
ND
4.1 J
4.3 J
4.1 1
---
ND
12-Jul-07
---
10
9.6 J
ND
ND
ND
ND
ND
---
ND
NC 2L = 1,050 µg/L (10/23/07)
19-Dec-07
---
10
4.3 B
14.3 B
6.3 B
ND
ND
ND
2.4 B
102
8-Jul-08
---
10
5.9 B
ND
ND
ND
4.1 B
ND
---
1.2 J
17-Dec-08
0.40
10.0
2.4 B
6.3 J
ND
ND
4.6 J
0.60 B
---
0.49 J
9-Jul-09
0.40
10.0
3.4 B
ND
ND
ND
ND
ND
6.1 B
1.6 J
16-Dec-09
0.40
10.0
4.6 B
ND
ND
ND
7.4 B
ND
---
7.7 J
NC 2L = 1,000 µg/L (02/05/10)
24-Jun-10
0.40
10.0
0.58 J
ND
ND
ND
ND
1.3 J
---
ND
13-Dec-10
0.40
10.0
4.5 B
ND
ND
ND
ND
ND
---
6.7 J
20-Jun-11
10.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
10.0
10.0
ND
ND
ND
ND
ND
ND
---
12.4
11-Jun-12
10.0
10.0
ND
20.9
ND
ND
ND
ND
N D
ND
12-Dec-12
10.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
10.0
10.0
ND
ND
ND
ND
11.8
ND
10.0
ND
5-Aug-13
10.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
10.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
EPA 6010
10.0
10.0
ND
ND
ND
ND
16.9
ND
---
ND
18-Aug-15
EPA 6010
5.0
10.0
7.4 J
ND
ND
ND
5.2 J
ND
---
ND
16-Feb-16
EPA 6010
5.0
10.0
14.5
16.7
17.8
46.1
5.9 J
ND
---
ND
9-Aug-16
EPA 6010
5.0
10.0
12.0
7.7 J
ND
ND
ND
ND
---
ND
13-Feb-17
EPA 6010
5.0
10.0
12.3
ND
ND
ND
9.8 J
6.0 J
---
ND
22-Aug-17
EPA 6010
5.0
10.0
ND
6.3 J
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 6010
5.0
10.0
6.7 J
17.9
ND
ND
ND
ND
---
ND
13-Aug-18
EPA 6010D
5.0
10.0
ND
ND
ND
ND
8.1 J
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 17 of 42

APPENDIX D: Historical Constituents in Groundwater
r
Analyte MmLhL--
Sample Date
M�m
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Cyanide
9-Jul-09
5.0
10
ND
ND
ND
ND
46.9
ND
ND
ND
Resample >
28-Sep-09
5.0
10
---
---
---
---
ND
---
---
ND
NC 2L = 70 µg/L (10/23/07)
16-Dec-09
---
---
---
---
---
---
---
---
---
24-Jun-10
5.0
10.0
ND
ND
ND
ND
ND
ND
---
N D
13-Dec-10
---
---
---
---
---
---
---
Resample >
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
5.0
10.0
ND
6.4 J
ND
ND
8.7 J
ND
---
ND
12-Dec-12
---
---
---
---
---
---
---
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
24-Feb-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
5.5 J
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
EPA 6010
5.0
10.0
9.5 B
7.5 B
8.5 B
8.8 B
11.8 B
6.6 B
---
5.6 J
16-Feb-16
SM 4500-CN-E
4.0
10.0
ND
ND
ND
---
---
---
---
ND
13-Feb-17
SM 4500-CN-E
4.0
10.0
ND
ND
ND
---
---
---
---
ND
22-Aug-17
SM 4500-CN-E
4.0
10.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
SM 4500-CN-E
4.0
10.0
ND
ND
ND
---
---
---
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 18 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
ORGANICS
Acetone
27-Oct-01
---
100
244 B
109 B
ND
130 B
128 B
476 B
---
479
13-Jun-02
---
100
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
100
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
100
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
100
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
100
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
100
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 700 µg/L (10/23/07)
19-Dec-07
---
100
ND
ND
ND
ND
ND
ND
ND
4.5 J
8-Jul-08
---
100
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
20.0
100
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
20.0
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
2.2
100
ND
ND
ND
ND
ND
ND
---
2.8 J
NC 2L = 6,000 µg/L (02/05/10)
24-Jun-10
2.2
100
ND
18.5 B
6.5 B
ND
2.2 B
ND
---
7.7 J
13-Dec-10
2.2
100
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
2.2
100
ND
ND
ND
ND
ND
2.4 B
---
3.9 J
5-Dec-11
2.2
100
ND
2.3 B
ND
ND
ND
ND
---
8.8 1
11-Jun-12
2.2
100
ND
3.5 B
ND
ND
ND
ND
ND
4.7 J
12-Dec-12
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
10.0
100
ND
ND
ND
ND
ND
ND
ND
14.6 J
5-Aug-13
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
10.0
100
ND
ND
ND
ND
ND
ND
ND
25.7 J
12-Aug-14
EPA 8260
10.0
100
ND
ND
ND
ND
ND
ND
ND
22.0 J
Acetone
10-Mar-15
EPA 8260
10.0
100
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
EPA 8260
10.0
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Feb-16
EPA 8260
10.0
100
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
EPA 8260
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
EPA 8260
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
EPA 8260
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 8260
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
EPA 8260B
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 19 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Benzene
8-Sep-94
---
5
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
5
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
5
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
5
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
5
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
5
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
5
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
5
ND
ND
ND
ND
ND
ND
---
---
1-Dec-97
---
5
ND
ND
ND
ND
ND
ND
---
---
20-May-98
---
5
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
5
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
5
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
5
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
5
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
5
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
5
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
5
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
5
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
5
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
5
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
3
ND
1.5
ND
ND
ND
ND
---
ND
Resample >
23-Feb-07
---
3
---
1.2
---
---
---
---
---
ND
12-Jul-07
---
1
ND
1.9
ND
ND
ND
ND
---
ND
NC 2L = 1 µg/L (10/23/07)
19-Dec-07
---
1
ND
1.8
0.48 J
0.26 J
ND
ND
ND
ND
8-Jul-08
---
1
ND
1.4
0.51 J
0.32 J
ND
ND
---
ND
17-Dec-08
0.25
1.0
ND
1.7
0.54 J
ND
ND
ND
---
ND
9-Jul-09
0.25
1.0
ND
1.7
0.34 J
ND
ND
ND
ND
ND
16-Dec-09
0.25
1.0
ND
1.7
0.60 J
0.29 J
ND
ND
---
ND
24-Jun-10
0.25
1.0
ND
0.77 J
0.49 J
0.33 J
ND
ND
---
ND
13-Dec-10
0.25
1.0
ND
1.8
0.59 J
0.37 J
ND
ND
---
ND
Resample >
8-Feb-11
0.25
1.0
---
1.4
---
---
---
---
---
ND
20-Jun-11
0.25
1.0
ND
1.7
0.60 J
0.39 J
ND
ND
---
ND
5-Dec-11
0.25
1.0
ND
1.4
0.69 J
0.40 J
ND
ND
---
ND
11-Jun-12
0.25
1.0
ND
ND
0.51 J
ND
ND
ND
ND
ND
12-Dec-12
0.25
1.0
ND
1.6
0.73 J
0.32 J
ND
ND
---
ND
Resample >
10-Jan-13
0.25
1.0
ND
1.4
---
---
---
---
ND
ND
1-May-13
0.25
1.0
ND
1.3
0.56 J
0.27 J
ND
ND
ND
ND
5-Aug-13
0.25
1.0
ND
1.6
0.64 J
0.44 J
ND
ND
---
ND
24-Feb-14
0.25
1.0
ND
1.4
ND
ND
ND
ND
ND
ND
12-Aug-14
EPA 8260
0.25
1.0
ND
1.7
0.61 J
0.25 J
ND
ND
ND
ND
10-Mar-15
EPA 8260
0.25
1.0
ND
1.3
0.54 J
ND
ND
ND
ND
ND
18-Aug-15
EPA 8260
0.25
1.0
ND
1.5
0.66 J
0.32 J
ND
ND
---
ND
16-Feb-16
EPA 8260
0.25
1.0
ND
1.3
0.56 J
ND
ND
ND
ND
ND
9-Aug-16
EPA 8260
0.25
1.0
ND
1.4
0.53 J
0.29 J
ND
ND
ND
ND
13-Feb-17
EPA 8260
0.25
1.0
ND
1.2
0.61 J
ND
ND
ND
ND
ND
22-Aug-17
EPA 8260
0.25
1.0
ND
1.3
0.54 J
ND
ND
ND
ND
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 20 of 42

APPENDIX D: Historical Constituents in Groundwater
AnalA E
Sample Date
Method
DL
RL
SOMMEMIL-
MW-1R
MW-2R
MW-3R
MW-4
0
MW-5
MW-6
NES-1
Blanks
Benzene
5-Feb-18
EPA 8260
--�
0.25
1.0
ND
1.2
0.67 J
-M
ND
ND
ND
ND
ND
13-Aug-18
EPA 8260B
0.25
1.0
ND
1.3
0.61 J
0.29 J
ND
ND
ND
ND
Bromomethane
17-Dec-08
0.29
10.0
ND
ND
0.58 J
ND
ND
ND
---
ND
NC 2L = NE µg/L (10/23/07)
9-Jul-09
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
GAPS = 10 µg/L (8/1/10)
13-Dec-10
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
EPA 8260
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
EPA 8260
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
EPA 8260
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
EPA 8260
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
EPA 8260
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
EPA 8260
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
EPA 8260
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 8260
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
EPA 8260B
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
2-Butanone (MEK)
17-Dec-08
0.96
100
ND
ND
ND
ND
1.2 J
ND
---
ND
NC 2L = 4,200 µg/L (10/23/07)
9-Jul-09
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 4,000 µg/L (02/05/10)
24-Jun-10
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
8-May-13
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
EPA 8260
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
EPA 8260
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
EPA 8260
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
EPA 8260
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
EPA 8260
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
EPA 8260
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 8260
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
EPA 8260B
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 21 of 42

APPENDIX D: Historical Constituents in Groundwater
FAnalylt
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Carbon Disulfide
17-Jun-97
---
100
ND
64.0
ND
ND
ND
ND
---
---
1-Dec-97
---
100
ND
5.0
8.0
ND
ND
ND
---
---
20-May-98
---
100
ND
7.5
6.2
ND
ND
ND
---
---
19-Nov-98
---
100
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
100
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
100
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
100
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
100
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
100
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
100
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
100
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
100
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
100
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
100
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 700 µg/L (10/23/07)
19-Dec-07
---
100
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
---
100
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
EPA 8260
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
EPA 8260
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
EPA 8260
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
EPA 8260
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
EPA 8260
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
EPA 8260
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
EPA 8260
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 8260
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
EPA 8260B
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 22 of 42

APPENDIX D: Historical Constituents in Groundwater
r
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Chlorobenzene
8-Sep-94
---
5
ND
10.0
7.0
ND
ND
ND
---
---
1-Dec-94
---
5
ND
ND
7.0
ND
ND
ND
---
---
9-Feb-95
---
5
ND
13.0
8.0
6.0
ND
ND
---
---
2-Mar-95
---
5
ND
12.0
9.0
ND
ND
ND
---
---
15-Nov-95
---
5
ND
14.0
8.0
9.0
ND
ND
---
---
28-May-96
---
5
ND
15.0
9.0
10.0
ND
ND
---
---
22-Nov-96
---
5
ND
15.0
ND
11.0
ND
ND
---
---
17-Jun-97
---
5
ND
19.0
11.0
14.0
ND
ND
---
---
1-Dec-97
---
5
ND
17.0
9.0
14.0
ND
ND
---
---
20-May-98
---
5
ND
20.0
8.6
12.0
ND
ND
---
---
19-Nov-98
---
5
ND
17.2
9.2
10.0
ND
ND
---
---
21-Jul-99
---
5
ND
14.0
10.0
11.0
ND
ND
---
---
16-Nov-99
---
5
ND
16.0
10.0
8.0
ND
ND
---
---
10-May-00
---
5
ND
17.0
11.0
10.0
ND
ND
---
---
26-Oct-00
---
5
ND
16.0
12.0
9.0
ND
ND
---
---
18-Apr-01
---
5
ND
16.0
13.0
6.0
ND
ND
---
---
27-Oct-01
---
0.5
ND
17.0
12.0
9.0
ND
ND
---
---
13-Jun-02
---
0.5
ND
16.0
11.0
8.0
ND
ND
---
---
19-Nov-02
---
0.5
ND
18.0
15.0
9.0
ND
ND
---
---
27-Jun-03
---
0.5
ND
17.7
13.3
7.4
ND
ND
---
ND
30-Dec-03
---
5
ND
20.0
15.0
6.1
ND
ND
---
ND
30-Jun-04
---
5
ND
18.0
15.0
9.9
ND
ND
---
ND
29-Dec-04
---
5
ND
19.0
16.0
9.4
ND
ND
---
ND
29-Jun-05
---
5
ND
15.0
13.0
8.0
ND
ND
---
ND
29-Dec-05
---
5
ND
18.0
16.0
5.0
ND
ND
---
ND
28-Jun-06
---
5
ND
16.5
10.8
7.8
ND
ND
---
ND
29-Dec-06
---
3
ND
17.0
17.0
4.2
ND
ND
---
ND
12-Jul-07
---
3
ND
17.0
16.0
ND
ND
ND
---
ND
NC 2L = 50 µg/L (10/23/07)
19-Dec-07
---
3
ND
17.3
16.9
4.7
ND
ND
ND
ND
8-Jul-08
---
3
ND
17.2
17.4
6.5
ND
ND
---
ND
17-Dec-08
0.23
3.0
ND
15.9
15.6
2.6 J
ND
ND
---
ND
9-Jul-09
0.23
3.0
ND
16.1
17.2
6.1
ND
ND
ND
ND
16-Dec-09
0.23
3.0
ND
15.5
17.7
4.8
ND
ND
---
ND
24-Jun-10
0.23
3.0
ND
8.3
15.7
6.3
ND
ND
---
ND
13-Dec-10
0.23
3.0
ND
17.7
18.2
6.4
ND
ND
---
0.28 J
20-Jun-11
0.23
3.0
ND
16.3
17.2
6.7
ND
ND
---
ND
5-Dec-11
0.23
3.0
ND
14.2
17.0
5.8
ND
ND
---
ND
11-Jun-12
0.23
3.0
ND
12
14.8
4.4
ND
ND
ND
ND
12-Dec-12
0.23
3.0
ND
15.8
17.9
4.5
ND
ND
---
ND
1-May-13
0.23
3.0
ND
14.0
16.6
3.0 J
ND
ND
ND
ND
5-Aug-13
0.23
3.0
ND
14.4
15.9
4.6
ND
ND
---
ND
24-Feb-14
0.23
3.0
ND
16.3
2.5 J
1.4 J
ND
ND
ND
ND
12-Aug-14
EPA 8260
0.23
3.0
ND
15.6
18.3
3.6
ND
ND
ND
ND
10-Mar-15
EPA 8260
0.23
3.0
ND
16.0
17.0
2.1 J
ND
ND
ND
ND
18-Aug-15
EPA 8260
0.23
3.0
ND
12.8
17.6
4.3
ND
ND
---
ND
16-Feb-16
EPA 8260
0.23
3.0
ND
13.5
16.4
1.5 J
ND
ND
ND
ND
9-Aug-16
EPA 8260
0.23
3.0
ND
13.5
16.9
4.2
ND
ND
---
ND
13-Feb-17
EPA 8260
0.23
3.0
ND
13.6
18.0
1.3 J
ND
ND
---
ND
22-Aug-17
EPA 8260
0.23
3.0
ND
14.2
19.9
4.2
ND
ND
---
ND
5-Feb-18
EPA 8260
0.23
3.0
ND
13.5
17.3
0.54 J
ND
ND
---
ND
13-Aug-18
EPA 8260B
0.23
3.0
ND
14.5
22.2
3.40
ND
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 23 of 42

APPENDIX D: Historical Constituents in Groundwater
r
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Chloroethane
1-Dec-97
---
10
ND
5.0
2.0
2.0
ND
ND
---
---
20-May-98
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
10
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
10
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
10
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
10
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
10
ND
ND
ND
ND
ND
ND
---
---
18-Apr-Ol
---
10
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
10
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
10
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
ND
2.2
1.9
ND
ND
ND
---
ND
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L 2,800 µg/L (10/23/07)
19-Dec-07
---
10
ND
1.9
1.9
1.5
ND
ND
ND
ND
8-Jul-08
---
10
ND
2.2 J
2.5 J
1.8 J
ND
ND
---
ND
17-Dec-08
0.54
10.0
ND
1.6 J
ND
ND
ND
ND
---
ND
9-Jul-09
0.54
10.0
ND
ND
ND
3.8 J
ND
ND
ND
ND
16-Dec-09
0.54
10.0
ND
ND
2.2 J
2.0 J
ND
ND
---
ND
NC 2L = 3,000 µg/L (02/05/10)
24-Jun-10
0.54
10.0
ND
ND
2.1 J
2.0 1
ND
ND
---
ND
13-Dec-10
0.54
10.0
ND
1.8 J
2.0 1
1.7 1
ND
ND
---
ND
20-Jun-11
0.54
10.0
ND
1.2 J
2.2 J
2.0 J
ND
ND
---
ND
5-Dec-11
0.54
10.0
ND
1.3 J
2.0 J
1.7 J
ND
ND
---
ND
11-Jun-12
0.54
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.54
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.54
10.0
ND
ND
1.9 J
2.7 J
ND
ND
ND
ND
5-Aug-13
0.54
10.0
ND
ND
2.0 J
2.2 J
ND
ND
---
ND
24-Feb-14
0.54
10.0
ND
1.1 J
0.82 J
ND
ND
ND
ND
ND
12-Aug-14
EPA 8260
0.54
10.0
ND
1.1 J
1.50 J
1.1 J
ND
ND
ND
ND
10-Mar-15
EPA 8260
0.54
10.0
ND
1.0 J
1.80 J
0.81 J
ND
ND
ND
ND
18-Aug-15
EPA 8260
0.54
10.0
ND
1.2 J
2.0 J
3.7 1
ND
ND
---
ND
16-Feb-16
EPA 8260
0.54
10.0
ND
1.1 J
1.8 1
0.79 1
ND
ND
ND
ND
9-Aug-16
EPA 8260
0.54
10.0
ND
0.68 J
2.4 J
1.5 J
ND
ND
---
ND
13-Feb-17
EPA 8260
0.54
10.0
ND
0.76 J
1.6 J
1.1 J
ND
ND
---
ND
22-Aug-17
EPA 8260
0.54
10.0
ND
1.3 J
2.0 1
1.6 1
ND
ND
---
ND
5-Feb-18
EPA 8260
0.54
10.0
ND
1.7 J
1.7 J
0.68 J
ND
ND
---
ND
13-Aug-18
EPA 8260B
0.54
10.0
ND
1.2 J
2.4 J
1.40 J
ND
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 24 of 42

APPENDIX D: Historical Constituents in Groundwater
r
Analyte
Sample Date
Method
D
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Chloromethane
9-Jul-09
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
NC 2L = 2.6 µg/L (10/23/07)
16-Dec-09
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
0.11
1.0
ND
ND
ND
ND
ND
0.11 J
---
ND
NC 2L = 3 µg/L (02/05/10)
13-Dec-10
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
0.25 J
12-Aug-14
EPA 8260
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
EPA 8260
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
EPA 8260
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
EPA 8260
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
EPA 8260
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
EPA 8260
0.11
1.0
0.20 B
ND
0.22 B
0.23 B
0.19 B
0.32 B
---
0.18 J
22-Aug-17
EPA 8260
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 8260
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
EPA 8260B
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 25 of 42

APPENDIX D: Historical Constituents in Groundwater
r
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
1,2-Dichlorobenzene
1-Dec-97
---
5
ND
3.0
2.0
1.0
ND
ND
---
---
20-May-98
---
5
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
5
ND
2.4
2.3
ND
ND
ND
---
---
21-Jul-99
---
5
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
5
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
5
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
5
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
5
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
5
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
5
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
5
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
5
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
5
ND
1.5
2.3
ND
ND
ND
---
ND
12-Jul-07
---
5
ND
1.4 J
1.7 J
0.31 J
ND
ND
---
ND
NC 2L = 24 µg/L (10/23/07)
19-Dec-07
---
5
ND
1.6
2.0
0.37 J
ND
ND
ND
ND
8-Jul-08
---
5
ND
1.6 J
2.0 J
0.39 J
ND
ND
---
ND
17-Dec-08
0.30
5.0
ND
1.4 1
1.9 1
ND
ND
ND
---
ND
9-Jul-09
0.30
5.0
ND
1.6 J
2.0 J
0.36 J
ND
ND
ND
ND
16-Dec-09
0.30
5.0
ND
1.6 J
2.0 J
0.33 J
ND
ND
---
ND
NC 2L = 20 µg/L (02/05/10)
24-Jun-10
0.30
5.0
ND
0.96 1
1.7 J
0.31 1
ND
ND
---
ND
13-Dec-10
0.30
5.0
ND
1.9 1
1.9 1
0.43 1
ND
ND
---
ND
20-Jun-11
0.30
5.0
ND
1.5 J
1.7 J
0.37 J
ND
ND
---
ND
5-Dec-11
0.30
5.0
ND
1.3 J
1.6 J
ND
ND
ND
---
ND
11-Jun-12
0.30
5.0
ND
1.0 1
1.5 1
ND
ND
ND
ND
ND
12-Dec-12
0.30
5.0
ND
1.3 J
1.7 J
ND
ND
ND
---
ND
1-May-13
0.30
5.0
ND
1.2 J
1.6 J
ND
ND
ND
ND
ND
5-Aug-13
0.30
5.0
ND
1.2 J
1.6 J
0.30 J
ND
ND
---
ND
24-Feb-14
0.30
5.0
ND
1.4 1
0.64 1
ND
ND
ND
ND
ND
12-Aug-14
EPA 8260
0.30
5.0
ND
1.2 J
1.5 J
ND
ND
ND
ND
ND
10-Mar-15
EPA 8260
0.30
5.0
ND
1.1 J
1.1 J
ND
ND
ND
ND
ND
18-Aug-15
EPA 8260
0.30
5.0
ND
0.88 J
1.3 1
ND
ND
ND
---
ND
16-Feb-16
EPA 8260
0.30
5.0
ND
1.1 1
1.4 1
ND
ND
ND
ND
ND
9-Aug-16
EPA 8260
0.30
5.0
ND
1.2 J
1.4 J
ND
ND
ND
---
ND
13-Feb-17
EPA 8260
0.30
5.0
ND
1.2 J
1.4 J
ND
ND
ND
---
ND
22-Aug-17
EPA 8260
0.30
5.0
ND
1.2 1
1.5 1
ND
ND
ND
---
ND
5-Feb-18
EPA 8260
0.30
5.0
ND
1.0 J
1.4 J
ND
ND
ND
---
ND
13-Aug-18
EPA 8260B
0.30
5.0
ND
1.2 J
1.6 J
ND
ND
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 26 of 42

APPENDIX D: Historical Constituents in Groundwater
r
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
1,4-Dichlorobenzene
8-Sep-94
---
5
ND
ND
5.0
ND
ND
ND
---
---
1-Dec-94
---
5
ND
ND
5.0
ND
ND
ND
---
---
9-Feb-95
---
5
ND
8.0
6.0
ND
ND
ND
---
---
2-Mar-95
---
5
ND
7.0
6.0
ND
ND
ND
---
---
15-Nov-95
---
5
ND
7.0
6.0
ND
ND
ND
---
---
28-May-96
---
5
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
5
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
5
ND
7.6
6.2
ND
ND
ND
---
---
1-Dec-97
---
5
ND
6.0
5.0
4.0
ND
ND
---
---
20-May-98
---
5
ND
7.6
ND
ND
ND
ND
---
---
19-Nov-98
---
5
ND
3.7
2.8
ND
ND
ND
---
---
21-Jul-99
---
5
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
5
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
5
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
5
ND
5.0
6.0
ND
ND
ND
---
---
18-Apr-01
---
5
ND
ND
5.0
6.0
ND
ND
---
---
27-Oct-01
---
5
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
5
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
5
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
5
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
3
ND
3.0
3.3
ND
ND
ND
---
ND
Resample >
23-Feb-07
---
3
---
3.2
3.3
---
---
---
---
ND
12-Jul-07
---
1
ND
3.3
2.9
0.31 J
ND
ND
---
ND
NC 2L = 1.4 µg/L (10/23/07)
19-Dec-07
---
1
ND
3.0
2.7
ND
ND
ND
ND
ND
8-Jul-08
---
1
ND
3.0
2.4
ND
ND
ND
---
ND
17-Dec-08
0.33
1.0
ND
2.9
2.5
ND
ND
ND
---
ND
9-Jul-09
0.33
1.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
0.33
1.0
ND
2.8
2.2
ND
ND
ND
---
ND
NC 2L = 6 µg/L (02/05/10)
24-Jun-10
0.33
1.0
ND
1.6
ND
ND
ND
ND
---
ND
13-Dec-10
0.33
1.0
ND
3.1
1.9
ND
ND
ND
---
ND
20-Jun-11
0.33
1.0
ND
2.7
1.6
ND
ND
ND
---
ND
5-Dec-11
0.33
1.0
ND
2.2
1.4
ND
ND
ND
---
ND
11-Jun-12
0.33
1.0
ND
1.8
1.4
ND
ND
ND
ND
ND
12-Dec-12
0.33
1.0
ND
2.4
1.3
ND
ND
ND
---
ND
1-May-13
0.33
1.0
ND
2.1
1.2
ND
ND
ND
ND
ND
5-Aug-13
0.33
1.0
ND
2.0
1.3
ND
ND
ND
---
ND
24-Feb-14
0.33
1.0
ND
2.2
1.8
ND
ND
ND
ND
ND
12-Aug-14
EPA 8260
0.33
1.0
ND
2.4
1.3
ND
ND
ND
ND
ND
10-Mar-15
EPA 8260
0.33
1.0
ND
2.2
1.1
ND
ND
ND
ND
ND
18-Aug-15
EPA 8260
0.33
1.0
ND
1.5
1.1
ND
ND
ND
---
ND
16-Feb-16
EPA 8260
0.33
1.0
ND
2.0
1.0
ND
ND
ND
ND
ND
9-Aug-16
EPA 8260
0.33
1.0
ND
1.9
1.0
ND
ND
ND
---
ND
13-Feb-17
EPA 8260
0.33
1.0
ND
1.9
0.90 J
ND
ND
ND
---
ND
22-Aug-17
EPA 8260
0.33
1.0
ND
1.9
0.96 J
ND
ND
ND
---
ND
5-Feb-18
EPA 8260
0.33
1.0
ND
1.6
1.1
ND
ND
ND
---
ND
13-Aug-18
EPA 8260B
0.33
1.0
ND
1.9
1.1
ND
ND
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 27 of 42

APPENDIX D: Historical Constituents in Groundwater
r
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Trans-1,4-Dichloro-2-Butene
20-May-98
---
100
ND
ND
5.1
ND
ND
ND
---
---
19-Nov-98
---
100
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
100
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
100
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
100
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
100
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
100
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
100
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
100
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
100
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
100
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
100
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = NE µg/L (10/23/07)
19-Dec-07
---
100
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
---
100
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
EPA 8260
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
EPA 8260
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
EPA 8260
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
EPA 8260
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
EPA 8260
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
EPA 8260
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
EPA 8260
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 8260
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
EPA 8260B
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 28 of 42

APPENDIX D: Historical Constituents in Groundwater
r
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
1, 1 -Dichloroethane
1-Dec-97
---
5
ND
ND
1.0
ND
ND
ND
---
---
20-May-98
---
5
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
5
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
5
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
5
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
5
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
5
ND
ND
ND
ND
ND
ND
---
---
18-Apr-Ol
---
5
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
5
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
5
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
5
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
5
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
5
ND
ND
0.36 J
0.52 J
ND
ND
---
ND
NC 2L 70 µg/L (10/23/07)
19-Dec-07
---
5
ND
ND
ND
0.57 J
ND
ND
ND
ND
8-Jul-08
---
5
ND
ND
ND
0.60 J
ND
ND
---
ND
17-Dec-08
0.32
5.0
ND
ND
ND
0.51 1
ND
ND
---
ND
9-Jul-09
0.32
5.0
ND
ND
ND
0.84 J
ND
ND
ND
ND
16-Dec-09
0.32
5.0
ND
ND
ND
0.73 J
ND
ND
---
ND
NC 2L = 6 µg/L (02/05/10)
24-Jun-10
0.32
5.0
ND
ND
ND
0.53 1
ND
ND
---
ND
13-Dec-10
0.32
5.0
ND
ND
ND
0.60 1
ND
ND
---
ND
20-Jun-11
0.32
5.0
ND
ND
ND
0.63 J
ND
ND
---
ND
5-Dec-11
0.32
5.0
ND
ND
ND
0.67 J
ND
ND
---
ND
11-Jun-12
0.32
5.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.32
5.0
ND
ND
ND
0.61 J
ND
ND
---
ND
1-May-13
0.32
5.0
ND
ND
ND
0.62 J
ND
ND
ND
ND
8-May-13
0.32
5.0
ND
ND
ND
0.53 J
ND
ND
---
ND
24-Feb-14
0.32
5.0
ND
ND
ND
0.50 1
ND
ND
ND
ND
12-Aug-14
EPA 8260
0.32
5.0
ND
ND
ND
0.47 J
ND
ND
ND
ND
10-Mar-15
EPA 8260
0.32
5.0
ND
ND
ND
0.50 J
ND
ND
ND
ND
18-Aug-15
EPA 8260
0.32
5.0
ND
ND
ND
0.49 1
ND
ND
---
ND
16-Feb-16
EPA 8260
0.32
5.0
ND
ND
ND
0.45 1
ND
ND
ND
ND
9-Aug-16
EPA 8260
0.32
5.0
ND
ND
ND
0.34 J
ND
ND
---
ND
13-Feb-17
EPA 8260
0.32
5.0
ND
ND
ND
0.33 J
ND
ND
---
ND
22-Aug-17
EPA 8260
0.32
5.0
ND
ND
ND
0.37 1
ND
ND
---
ND
5-Feb-18
EPA 8260
0.32
5.0
ND
ND
ND
0.38 J
ND
ND
---
ND
13-Aug-18
EPA 8260B
0.32
5.0
ND
ND
ND
0.37 J
ND
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 29 of 42

APPENDIX D: Historical Constituents in Groundwater
r
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
1,2-Dichloroethane
17-Dec-08
0.12
1.0
ND
ND
0.15 J
ND
ND
ND
---
ND
NC 2L = 0.38 µg/L (10/23/07)
9-Jul-09
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
0.19 J
16-Dec-09
0.12
1.0
ND
ND
0.14 J
ND
ND
ND
---
ND
NC 2L = 0.4 µg/L (02/05/10)
24-Jun-10
0.12
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
0.12
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.12
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.12
1.0
ND
ND
ND
ND
0.18 J
ND
---
ND
11-Jun-12
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.12
1.0
ND
ND
ND
ND
-0.20 J
ND
---
0.20 (ND) J
1-May-13
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.12
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
EPA 8260
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
EPA 8260
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
EPA 8260
0.24
1.0
ND
ND
0.33 J
0.29 J
0.36 J
ND
---
---
16-Feb-16
EPA 8260
0.24
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
EPA 8260
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
EPA 8260
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
EPA 8260
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 8260
0.24
1.0
0.25 J
ND
0.37 J
ND
0.43 J
ND
---
ND
13-Aug-18
EPA 8260B
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
Ethylbenzene
17-Dec-08
0.30
1.0
ND
0.31 J
ND
ND
ND
ND
---
ND
NC 2L = 550 µg/L (10/23/07)
9-Jul-09
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 600 µg/L (02/05/10)
24-Jun-10
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
EPA 8260
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
EPA 8260
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
EPA 8260
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
EPA 8260
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
EPA 8260
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
EPA 8260
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
EPA 8260
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 8260
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
EPA 8260B
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 30 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyte
Sample Date
Method
D
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Isobutanol
24-Jun-10
35.0
100
ND
59.0 J
ND
ND
ND
ND
---
ND
NC 2L = NE µg/L (02/05/10)
13-Dec-10
---
---
---
---
---
---
---
---
---
---
20-Jun-11
35.0
100
ND
39.5 J
ND
ND
ND
ND
---
ND
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
35.0
100.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
---
---
---
---
---
---
---
1-May-13
35.0
100
ND
ND
ND
ND
ND
ND
---
ND
5-Aug- 13
---
---
---
---
---
---
---
---
24-Feb-14
35.0
100
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
35.0
100
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
EPA 8260
35.0
100
ND
ND
ND
---
---
---
---
ND
16-Feb-16
EPA 8260
35.0
100
ND
42.5 J
ND
---
---
---
---
ND
13-Feb-17
EPA 8260
35.0
100
ND
ND
ND
---
---
---
---
ND
22-Aug-17
EPA 8260
35.0
100
ND
ND
ND
---
---
---
---
ND
5-Feb-18
EPA 8260
35.0
100
ND
ND
ND
---
---
---
---
ND
Methylene Chloride
9-Jul-09
0.97
2.0
ND
ND
ND
ND
ND
ND
ND
9.6
NC 2L = 4.3 µg/L (10/23/07)
16-Dec-09
0.97
2.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
0.97
1.0
ND
19.0
ND
ND
ND
ND
---
ND
NC 2L = 5 µg/L (02/05/10) Resamp
12-Aug-10
0.97
1.0
---
ND
---
---
---
---
---
ND
13-Dec-10
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.97
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
EPA 8260
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
EPA 8260
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
EPA 8260
0.97
1.0
1.3
1.1
1.6
ND
ND
ND
ND
ND
16-Feb-16
EPA 8260
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
EPA 8260
0.97
1.0
ND
ND
1.0 B
ND
ND
ND
---
2.2 B
13-Feb-17
EPA 8260
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
EPA 8260
0.97
1.0
ND
ND
ND
ND
ND
ND
---
1.4 C
5-Feb-18
EPA 8260
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
EPA 8260B
0.97
1.0
ND
ND
ND
ND
ND
ND
---
6.6
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 31 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyte A
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Naphthalene
8-Jul-08
---
10
ND
3.8 J
ND
ND
ND
ND
---
ND
NC 2L = 21 µg/L 00/23/07)
17-Dec-08
---
---
---
---
---
---
---
---
---
---
9-Jul-09
0.24
10.0
ND
2.4 J
ND
ND
ND
ND
---
ND
16-Dec-09
---
---
---
---
---
---
NC 2L = 6 µg/L (02/05/10)
24-Jun-10
0.24
10.0
ND
7.4 J
ND
ND
ND
ND
---
ND
13-Dec-10
---
---
---
---
---
---
---
20-Jun-11
0.24
10.0
ND
4.6 J
ND
ND
ND
ND
---
0.39 J
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
0.2
10.0
ND
4.6 J
ND
ND
ND
ND
ND
ND
12-Dec-12
---
---
---
---
---
---
---
1-May-13
0.24
10.0
ND
5.1 J
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
0.24
10.0
ND
5.8 J
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
---
---
---
---
10-Mar-15
EPA 8260
0.2
10
ND
5.4 J
ND
---
---
---
---
ND
16-Feb-16
EPA 8260
0.2
10
ND
5.7 J
ND
---
---
---
---
ND
13-Feb-17
EPA 8260
0.2
10
ND
6.1 J
ND
---
---
---
---
ND
22-Aug-17
EPA 8260
0.2
10
ND
7.0 J
0.45 J
---
---
---
---
ND
5-Feb-18
EPA 8260
0.2
10
ND
5.7 J
ND
---
---
---
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 32 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Toluene
20-May-98
---
5
ND
ND
8.1
ND
ND
ND
---
---
19-Nov-98
---
5
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
5
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
5
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
5
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
5
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
5
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
5
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
5
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
5
ND
ND
ND
ND
ND
ND
---
-
30-Dec-03
---
5
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
1
ND
0.49 B
ND
ND
ND
ND
---
0.34 J
NC 2L = 1,000 µg/L (10/23/07)
19-Dec-07
---
1
ND
0.51 J
ND
ND
ND
ND
ND
ND
8-Jul-08
---
1
ND
0.39 J
ND
ND
1.3
ND
---
ND
17-Dec-08
0.26
1.0
1.4
1.6
ND
ND
11.7
ND
---
ND
9-Jul-09
0.26
1.0
ND
0.46 J
ND
ND
ND
ND
N D
ND
16-Dec-09
0.26
1.0
ND
0.42 J
ND
ND
ND
ND
---
ND
NC 2L = 600 µg/L (02/05/10)
24-Jun-10
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
0.26
1.0
ND
0.54 J
ND
ND
ND
ND
---
ND
20-Jun-11
0.26
1.0
ND
0.34 J
ND
ND
ND
ND
---
ND
5-Dec-11
0.26
1.0
ND
0.28 J
ND
ND
0.30 J
ND
---
ND
11-Jun-12
0.26
1.0
ND
0.28 J
ND
ND
ND
ND
ND
ND
12-Dec-12
0.26
1.0
ND
0.29 J
ND
ND
0.36 J
ND
---
ND
1-May-13
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.26
1.0
ND
0.29 J
ND
ND
ND
ND
---
ND
24-Feb-14
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
EPA 8260
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
EPA 8260
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
EPA 8260
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
EPA 8260
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
EPA 8260
0.26
1.0
ND
0.33 J
ND
ND
ND
ND
---
ND
13-Feb-17
EPA 8260
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
EPA 8260
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 8260
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
EPA 8260B
0.26
1.0
ND
ND
ND
ND
0.44 J
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 33 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Vinyl Chloride
8-Sep-94
---
10
ND
ND
12.0
ND
ND
ND
---
---
1-Dec-94
---
10
ND
ND
13.0
ND
ND
ND
---
---
9-Feb-95
---
10
ND
ND
15.0
ND
ND
ND
---
---
2-Mar-95
---
10
ND
ND
14.0
ND
ND
ND
---
---
15-Nov-95
---
10
ND
ND
11.0
ND
ND
ND
---
---
28-May-96
---
10
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
10
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-97
---
10
ND
ND
7.0
4.0
ND
ND
---
---
20-May-98
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
10
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
10
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
10
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
10
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
10
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
10
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
10
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
10
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
5.5
ND
ND
0.98 J
ND
ND
ND
---
ND
Resample >
23-Feb-07
---
5.5
---
---
1.0
---
---
---
---
ND
12-Jul-07
---
1
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 0.015 µg/L (10/23/07)
19-Dec-07
---
1
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
---
1
ND
ND
0.76 J
ND
ND
ND
---
ND
17-Dec-08
0.62
1.0
ND
ND
0.76 J
ND
ND
ND
---
ND
9-Jul-09
0.62
1.0
ND
ND
0.99 J
ND
ND
ND
ND
ND
16-Dec-09
0.62
1.0
ND
ND
0.81 J
ND
ND
ND
---
ND
NC 2L = 0.03 µg/L (02/05/10)
24-Jun-10
0.62
1.0
ND
ND
0.77 J
ND
ND
ND
---
ND
13-Dec-10
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
EPA 8260
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
EPA 8260
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
EPA 8260
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
EPA 8260
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
EPA 8260
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
EPA 8260
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
EPA 8260
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 8260
0.62
1.0
ND
ND
0.63 J
ND
ND
ND
---
ND
13-Aug-18
EPA 8260B
0.62
1.0
ND
ND
0.72 J
ND
ND
ND
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 34 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Xylene (Total)
29-Dec-06
---
5
ND
1.4
ND
ND
ND
ND
---
ND
12-Jul-07
---
4
ND
1.2 J
ND
ND
ND
ND
---
ND
NC 2L = 530 µg/L (10/23/07)
19-Dec-07
---
4
ND
2.0
ND
ND
ND
ND
ND
ND
8-Jul-08
---
4
ND
1.1 J
ND
ND
ND
ND
---
ND
17-Dec-08
0.66
2.0
1.4 J
2.7
ND
ND
ND
ND
---
ND
9-Jul-09
0.66
2.0
ND
1.5 J
ND
ND
ND
ND
ND
ND
16-Dec-09
0.66
2.0
ND
2.2
ND
ND
ND
ND
---
ND
NC 2L = 500 µg/L (02/05/10)
24-Jun-10
0.66
2.0
ND
0.73 1
ND
ND
ND
ND
---
ND
13-Dec-10
0.66
2.0
ND
2.0
ND
ND
ND
ND
---
ND
20-Jun-11
0.66
2.0
ND
1.4 J
ND
ND
ND
ND
---
ND
5-Dec-11
0.66
2.0
ND
1.1 1
ND
ND
ND
ND
---
ND
11-Jun-12
0.66
2.0
ND
0.91 1
ND
ND
ND
ND
ND
ND
12-Dec-12
0.66
5.0
ND
0.97 J
ND
ND
ND
ND
---
ND
1-May-13
0.66
5.0
ND
0.68 J
ND
ND
ND
ND
ND
ND
5-Aug-13
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
EPA 8260
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
EPA 8260
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
EPA 8260
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
EPA 8260
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
EPA 8260
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
EPA 8260
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
EPA 8260
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
EPA 8260B
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
Bis(2-Ethylhexyl)phthalate
24-Feb-14
0.79
15.0
2.6 J
ND
ND
ND
ND
ND
ND
ND
NC 2L = 3 µg/L (2/5/10)
15-Apr-14
0.79
15.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
---
---
---
---
---
---
10-Mar-15
EPA 8270
0.5
15
ND
ND
ND
---
---
---
---
ND
16-Feb-16
EPA 8270
0.9
15
ND
ND
ND
---
---
---
---
ND
13-Feb-17
EPA 8270
0.9
15
ND
ND
ND
---
---
---
---
ND
22-Aug-17
EPA 8270
2.3
15
ND
ND
ND
---
---
---
---
ND
5-Feb-18
EPA 8270
2.4
16
ND
ND
ND
---
---
---
---
ND
N-Nitroso-di-n-butylamine
24-Feb-14
7.5
10.0
ND
ND
ND
8.6 J
ND
ND
ND
ND
12-Aug-14
---
---
---
---
---
---
---
10-Mar-15
EPA 8270
1.3
10
ND
ND
ND
---
---
---
---
ND
16-Feb-16
EPA 8270
2.2
10
ND
ND
ND
---
---
---
---
ND
13-Feb-17
EPA 8270
2.2
10
ND
ND
ND
---
---
---
---
ND
22-Aug-17
EPA 8270
1.6
10
ND
ND
ND
---
---
---
---
ND
5-Feb-18
EPA 8270
1.6
10
ND
ND
ND
---
---
---
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 35 of 42

APPENDIX D: Historical Constituents in Groundwater
FAnalylt
Sample Date
Method
D
RL
MEN=-
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Benzo(g,h,i)perylene
20-Jun-11
0.4
10.0
ND
ND
ND
ND
ND
1.4 1
---
ND
NC 2L = 200 µg/L (2/5/10)
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
0.3 8
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
---
---
---
---
---
---
---
1-May-13
0.3 8
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
24-Feb-14
0.3 8
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
---
---
10-Mar-15
EPA 8270
0.5
10.0
ND
ND
ND
---
---
---
---
ND
16-Feb-16
EPA 8270
0.4
10.0
ND
ND
ND
---
---
---
---
ND
13-Feb-17
EPA 8270
0.4
10.0
ND
ND
ND
---
---
---
---
ND
22-Aug-17
EPA 8270
2.1
10.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
EPA 8270
2.2
10.4
ND
ND
ND
---
---
---
---
ND
Dibenz(a,h)anthracene
20-Jun-11
0.55
10.0
ND
ND
ND
ND
ND
1.5 J
---
ND
NC 2L = 0.005 µg/L (2/5/10)
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
0.55
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
---
---
---
---
---
---
---
1-May-13
0.55
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
24-Feb-14
0.55
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
---
10-Mar-15
EPA 8270
0.5
10.0
ND
ND
ND
---
---
---
---
ND
16-Feb-16
EPA 8270
0.6
10.0
ND
ND
ND
---
---
---
---
ND
13-Feb-17
EPA 8270
0.6
10.0
ND
ND
ND
---
---
---
---
ND
22-Aug-17
EPA 8270
2.0
10.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
EPA 8270
2.1
10.4
ND
ND
ND
---
---
---
---
ND
Fluorene
24-Jun-10
3.8
12.2
ND
4.3 J
ND
ND
ND
ND
---
ND
Resample >
12-Aug-10
3.1
10.0
---
ND
---
---
---
---
---
ND
NC 2L = 300 µg/L (2/5/10)
13-Dec-10
---
---
---
---
---
---
---
---
---
---
20-Jun-11
0.2
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
0.21
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
---
---
---
---
---
---
---
1-May-13
0.21
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
24-Feb-14
0.21
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
---
10-Mar-15
EPA 8270
1.0
10.0
ND
ND
ND
---
---
---
---
ND
16-Feb-16
EPA 8270
0.2
10.0
ND
ND
ND
---
---
---
---
ND
13-Feb-17
EPA 8270
0.2
10.0
ND
ND
ND
---
---
---
---
ND
22-Aug-17
EPA 8270
1.6
10.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
EPA 8270
1.6
10.4
ND
ND
ND
---
---
---
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 36 of 42

APPENDIX D: Historical Constituents in Groundwater
mmr
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5 ML
MW-6
NES-1
Blanks
Indeno(1,2,3-cd)pyrene
20-Jun-11
0.29
10.0
ND
ND
ND
ND
ND
1.3 1
---
ND
NC 2L = 0.05 µg/L (2/5/10)
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
---
---
---
---
---
---
1-May-13
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
24-Feb-14
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
10-Mar-15
EPA 8270
0.5
10.0
ND
ND
ND
---
---
---
---
ND
16-Feb-16
EPA 8270
0.3
10.0
ND
ND
ND
---
---
---
---
ND
13-Feb-17
EPA 8270
0.3
10.0
ND
ND
ND
---
---
---
---
ND
22-Aug-17
EPA 8270
2.0
10.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
EPA 8270
2.1
10.4
ND
ND
ND
---
---
---
---
ND
2-Methylnaphthalene
24-Jun-10
5.1
12.2
ND
38.9
ND
ND
ND
ND
---
ND
Resample>
12-Aug-10
4.2
10
---
ND
---
---
---
---
---
ND
NC 2L = 30 µg/L (02/05/10)
13-Dec-10
---
---
---
---
---
---
---
---
---
---
20-Jun-11
0.3
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
0.28
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
---
---
---
---
---
---
---
1-May-13
0.28
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
24-Feb-14
0.28
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
---
10-Mar-15
EPA 8270
1.0
10.0
ND
ND
ND
---
---
---
---
ND
16-Feb-16
EPA 8270
0.3
10.0
ND
ND
ND
---
---
---
---
ND
13-Feb-17
EPA 8270
0.3
10.0
ND
ND
ND
---
---
---
---
ND
22-Aug-17
EPA 8270
1.4
10.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
EPA 8270
1.5
10.4
ND
ND
ND
---
---
---
---
ND
Phorate
18-Apr-01
---
10
---
3.2
ND
ND
ND
---
---
---
27-Oct-01
---
5
ND
8.1
ND
ND
ND
ND
---
---
27-Oct-01
---
0.5
---
8.1
1.3
ND
ND
---
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
0.5
---
ND
ND
ND
ND
---
---
---
19-Nov-02
---
5
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
5
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
---
---
---
---
---
---
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
---
---
---
---
---
---
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 1.4 µg/L (10/23/07)
19-Dec-07
---
---
---
---
---
---
---
---
ND
---
8-Jul-08
---
10
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
---
---
---
---
---
---
---
9-Jul-09
6.6
22.2
ND
ND
ND
ND
ND
ND
---
ND
16-Dec-09
---
---
---
---
---
---
---
NC 2L = 1 µg/L (02/05/10)
24-Jun-10
6.5
24.1
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
---
---
---
---
---
---
---
---
---
---
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 37 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyte
Sample Date
Method
D
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Phorate
20-Jun-11
5.4
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
---
---
---
---
---
---
11-Jun-12
5.4
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
---
---
---
---
---
---
---
1-May-13
5.4
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
24-Feb-14
5.4
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
---
10-Mar-15
EPA 8270
0.8
10.0
ND
ND
ND
---
---
---
---
ND
16-Feb-16
EPA 8270
1.1
10.0
ND
ND
ND
---
---
---
---
ND
13-Feb-17
EPA 8270
1.1
10.0
ND
ND
ND
---
---
---
---
ND
22-Aug-17
EPA 8270
1.7
10.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
EPA 8270
1.8
10.4
ND
ND
ND
---
---
---
---
ND
Beta-BHC
11-Jun-12
0.050
0.050
ND
ND
0.16
ND
ND
ND
---
ND
Resample >
19-Jul-12
0.050
0.050
---
---
ND
---
---
---
---
---
NC 2L = 0.019 µg/L (10/23/07)
12-Dec-12
---
---
---
---
---
---
---
---
---
---
1-May-13
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
0.050
0.050
ND
0.052
ND
ND
ND
ND
---
ND
Resample >
15-Apr-14
0.050
0.050
---
ND
---
---
---
---
---
ND
12-Aug-14
---
---
---
---
---
---
---
---
10-Mar-15
EPA 8081
0.1
0.1
ND
ND
ND
---
---
---
---
ND
16-Feb-16
EPA 8081
0.1
0.1
ND
ND
ND
---
---
---
---
ND
13-Feb-17
EPA 8081
0.1
0.1
ND
ND
ND
---
---
---
---
ND
5-Feb-18
EPA 8081
0.1
0.1
ND
ND
ND
---
---
---
---
ND
Delta-BHC
11-Jun-12
0.050
0.050
ND
ND
0.090
ND
ND
ND
---
ND
Resample >
19-Jul-12
0.050
0.050
---
---
ND
---
---
---
---
---
NC 2L = 0.019 µg/L (10/23/07)
12-Dec-12
---
---
---
---
---
---
---
---
---
---
1-May-13
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
24-Feb-14
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
---
10-Mar-15
EPA 8081
0.050
0.050
ND
ND
ND
---
---
---
---
ND
16-Feb-16
EPA 8081
0.050
0.050
ND
ND
ND
---
---
---
---
ND
13-Feb-17
EPA 8081
0.050
0.050
ND
ND
ND
---
---
---
---
ND
5-Feb-18
EPA 8081
0.052
0.052
ND
ND
ND
---
---
---
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 38 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
gamma-BHC (Lindane)
27-Jun-03
---
1.05
ND
0.085
ND
ND
ND
ND
---
ND
30-Dec-03
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 0.2 µg/L (10/23/07)
19-Dec-07
---
0.05
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
---
0.50
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
16-Dec-09
0.01
0.1
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 0.03 µg/L (02/05/10)
24-Jun-10
0.00021
0.010
ND
ND
0.052
ND
ND
ND
---
ND
Resample >
12-Aug-10
0.00020
0.010
---
---
ND
---
---
---
---
ND
13-Dec-10
0.00020
0.050
ND
ND
0.013 J
ND
ND
ND
---
ND
20-Jun-11
0.00020
0.050
ND
ND
0.066
ND
ND
ND
---
ND
Resample >
28-Jul-11
0.00020
0.010
---
---
ND
---
---
---
---
ND
5-Dec-11
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
0.050
0.050
ND
ND
ND
---
---
---
---
ND
10-Mar-15
EPA 8081
0.050
0.050
ND
ND
ND
---
---
---
---
ND
18-Aug-15
EPA 8081
0.050
0.050
ND
ND
ND
---
---
---
---
ND
16-Feb-16
EPA 8081
0.050
0.050
ND
ND
ND
---
---
---
---
ND
9-Aug-16
EPA 8081
0.050
0.050
ND
ND
ND
---
---
---
---
ND
13-Feb-17
EPA 8081
0.050
0.050
ND
ND
ND
---
---
---
---
ND
5-Feb-18
EPA 8081
0.052
0.052
ND
ND
ND
---
---
---
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 39 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Heptachlor
27-Jun-03
---
1.05
ND
0.03
0.17
ND
ND
ND
---
ND
30-Dec-03
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 0.0078 µg/L (10/23/07)
19-Dec-07
---
0.05
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
16-Dec-09
0.02
0.1
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 0.008 µg/L (02/05/10)
24-Jun-10
0.0015
0.010
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
0.0500
0.0015
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.050
0.0015
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.050
0.056
ND
0.062
ND
ND
ND
ND
---
ND
Resample >
25-Jan-12
0.050
0.0500
---
ND
---
---
---
---
---
ND
11-Jun-12
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
0.050
0.050
ND
ND
ND
---
---
---
---
ND
10-Mar-15
EPA 8081
0.050
0.050
ND
ND
ND
---
---
---
---
ND
18-Aug-15
EPA 8081
0.050
0.050
ND
ND
ND
---
---
---
---
ND
16-Feb-16
EPA 8081
0.050
0.050
ND
ND
ND
---
---
---
---
ND
9-Aug-16
EPA 8081
0.050
0.050
ND
ND
ND
---
---
---
---
ND
13-Feb-17
EPA 8081
0.050
0.050
ND
ND
ND
---
---
---
---
ND
5-Feb-18
EPA 8081
0.052
0.052
ND
ND
ND
---
---
---
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 40 of 42

APPENDIX D: Historical Constituents in Groundwater
r
Analyte
Sample Date
Method
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
M
MW-6
NES-1
Blanks
2,4-D
27-Jun-03
---
3
---
5.9
ND
ND
ND
---
---
---
30-Dec-03
---
2
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
2
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
2
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
2
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 70 µg/L (10/23/07)
19-Dec-07
---
2
ND
ND
ND
ND
ND
ND
ND
ND
8-Apr-08
---
2
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
---
2.0
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
---
2.0
ND
ND
ND
ND
ND
ND
---
ND
16-Dec-09
0.11
5.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
0.23
2.1
ND
ND
ND
ND
ND
ND
---
ND
10-Dec-10
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
EPA 8151
0.22
2.0
ND
ND
ND
---
---
---
---
ND
10-Mar-15
EPA 8151
0.24
2.1
ND
ND
ND
---
---
---
---
ND
18-Aug-15
EPA 8151
0.24
2.1
ND
ND
ND
---
---
---
---
ND
16-Feb-16
EPA 8151
0.23
1.0
ND
ND
ND
---
---
---
---
ND
9-Aug-16
EPA 8151
0.24
1.0
ND
ND
ND
---
---
---
---
ND
13-Feb-17
EPA 8151
0.22
0.9
ND
ND
ND
---
---
---
---
ND
22-Aug-17
EPA 8151
0.24
1.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
EPA 8151
0.24
1.0
ND
ND
ND
---
---
---
---
ND
4,4'-DDD
11-Jun-12
0.05
0.05
ND
ND
0.13
ND
ND
ND
---
ND
Resample>
19-Jul-12
0.05
0.10
---
---
ND
---
---
---
---
---
NC 2L = 0.1 µg/L (2/5/10)
12-Dec-12
---
---
---
---
---
---
---
---
---
---
1-May-13
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
---
10-Mar-15
EPA 8081
0.050
0.10
ND
ND
ND
---
---
---
---
ND
16-Feb-16
EPA 8081
0.050
0.10
ND
ND
ND
---
---
---
---
ND
13-Feb-17
EPA 8081
0.050
0.10
ND
ND
ND
---
---
---
---
ND
5-Feb-18
EPA 8081
0.052
0.10
ND
ND
ND
---
---
---
---
ND
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 41 of 42

APPENDIX D: Historical Constituents in Groundwater
Analyte
Sample Date
Method
RL
NOEL-
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
4,4'-DDT
11-Jun-12
0.05
0.05
ND
ND
0.10
ND
ND
N D
---
ND
Resample>
19-Jul-12
0.05
0.10
---
---
0.063 J
---
---
---
---
---
NC 2L = 0.1 µg/L (2/5/10)
12-Dec-12
---
---
---
---
---
---
---
---
---
---
1-May-13
0.050
0.10
ND
ND
ND
ND
N D
ND
---
ND
5-Aug-13
---
---
---
---
---
---
24-Feb-14
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
10-Mar-15
EPA 8081
0.050
0.10
ND
ND
ND
---
---
---
---
ND
16-Feb-16
EPA 8081
0.050
0.10
ND
ND
ND
---
---
---
---
ND
13-Feb-17
EPA 8081
0.050
0.10
ND
ND
ND
---
---
---
---
ND
5-Feb-18
EPA 8081
0.052
0.10
ND
ND
ND
---
---
---
---
ND
Dinoseb
10-Mar-15
EPA 8151
0.061
1.1
ND
ND
0.11 J
---
---
---
---
ND
16-Feb-16
EPA 8151
0.058
0.19
ND
ND
ND
---
---
---
---
ND
13-Feb-17
EPA 8151
0.057
0.19
ND
ND
ND
---
---
---
---
ND
22-Aug-17
EPA 8151
0.062
0.20
ND
ND
ND
---
---
---
---
ND
5-Feb-18
EPA 8151
0.061
0.20
ND
ND
ND
---
---
---
---
ND
Endrin aldehyde
11-Jun-12
0.050
0.050
ND
ND
0.14
ND
ND
ND
---
---
NC 2L= 2 (2/5/10)
12-Dec-12
0.050
0.10
ND
ND
ND
ND
ND
ND
---
---
1-May-13
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
EPA 8081
0.050
0.10
ND
ND
ND
---
---
---
---
ND
10-Mar-15
EPA 8081
0.050
0.10
ND
ND
ND
---
---
---
---
ND
18-Aug-15
EPA 8081
0.050
0.10
ND
ND
ND
---
---
---
---
ND
16-Feb-16
EPA 8081
0.050
0.10
ND
ND
ND
---
---
---
---
ND
9-Aug-16
EPA 8081
0.050
0.10
ND
ND
ND
---
---
---
---
ND
13-Feb-17
EPA 8081
0.050
0.10
ND
ND
ND
---
---
---
---
ND
5-Feb-18
EPA 8081
0.052
0.10
ND
ND
ND
---
---
---
---
ND
Dichlorodifluoromethane
5-Feb-18
EPA 8260
0.21
5.0
ND
0.36 J
ND
---
---
---
---
ND
1,4-Dioxane (p-Dioxane)
8/13/2018
EPA 8260B Mod.
1.9
2
ND
88
53.1
40.7
2 J
ND
---
ND
NC 2L = 3 µg/L
Notes:
All concentrations are in micrograms per liter (µg/L).
RL = Reporting Limit (MRL or PQL prior to December 2006; SWSL for December 2006 - February 2017; MRL or PQL for August 2018).
DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank -qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory detectiong limit.
NC 2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202.
GWPS = Groundwater Protection Standards established by the NCDEQ Solid Waste Section (SWS).
When the NC 2L has not been established, the GWPS will be used.
Bold values for groundwater are above the NC 2L Standards or GWPS.
--- = Well was not monitored and/or data was not reported.
Joyce Engineering
Granville County December 2018
Butner Landfill, Permit No. 39-02 Page 42 of 42

Appendix E
Historical Constituents in Surface Water

APPENDIX E: Historical Constituents in Surface Water
Analytes
Sample Date
Method
DL
RL
SW-1
SW-2
Blanks
INORGANICS
Arsenic
06/24/10
2.7
10.00
4.30 J
2.90 J
ND
NC 2B = 10 µg/L (03/28/08)
12/13/10
2.7
10.0
ND
ND
ND
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
ND
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/ 14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
---
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
3.0 J
08/18/15
---
---
Dry
Dry
---
02/ 16/ 16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
3.10 B
ND
5.1 J
02/13/17
EPA 6010
5.0
10.0
ND
ND
ND
08/22/17
EPA 6010
5.0
10.0
ND
ND
ND
02/05/18
EPA 6010
5.0
10.0
ND
ND
ND
08/13/18
EPA 6010D
5.0
10.0
ND
ND
ND
Granville County Joyce Engineering
Butner Landfill, Permit No. 39-02 Page 1 of 13 December 2018

APPENDIX E: Historical Constituents in Surface Water
Analytes
Sample Date
Method
DL
SW-1
SW-2
Blanks
Barium
11/22/96
---
500
37.0
37.0
---
06/17/97
---
500
37.0
62.0
---
12/01/97
---
500
53.0
45.0
---
05/20/98
---
500
24.0
69.0
---
11/19/98
---
500
ND
100.0
---
07/21/99
---
500
ND
ND
---
11/16/99
---
500
ND
ND
---
05/10/00
---
500
ND
ND
---
10/26/00
---
500
ND
ND
---
04/18/01
---
500
ND
ND
---
10/27/01
---
500
ND
ND
---
06/13/02
---
500
---
---
---
11/19/02
---
500
ND
ND
---
06/27/03
---
500
ND
ND
---
12/30/03
---
500
ND
ND
ND
06/30/04
---
500
ND
ND
ND
12/29/04
---
500
ND
ND
ND
12/29/04
---
500
ND
ND
ND
06/29/05
---
500
ND
ND
ND
12/29/05
---
500
ND
ND
ND
06/28/06
---
500
ND
ND
ND
12/29/06
---
100
37.5
40.6
0.20 J
07/12/07
---
100
33.3 J
---
ND
12/19/07
---
100
52.6 B
149.0
11.7
NC 2B = 1,000 µg/L (03/28/08)
07/08/08
---
100
33.8 J
161.0
0.3 J
12/17/08
0.2
100
30.2 B
33.5 B
10.7 J
07/09/09
0.2
100
36.8 B
78.4 B
17.6 J
12/16/09
0.2
100
31.2 B
36.2 B
17.1 J
06/24/10
0.2
100
34.5 B
71.3 B
27.3 J
12/13/10
0.2
100
36.1 B
91.0 1
12.1 J
06/20/11
5.0
100
40.3 1
93.0 1
ND
12/05/11
5.0
100
32.9 1
59.0 1
ND
06/11/12
5.0
100
40.0 J
95.6 J
ND
12/12/12
5.0
100
45.0 J
97.8 J
ND
05/01/13
5.0
100
32.7 J
43.1 J
ND
08/05/13
5.0
100
49.9 1
79.8 1
ND
02/24/14
5.0
100
29.0 1
30.4 1
ND
08/12/14
EPA 6010
5.0
100
---
121
ND
03/10/15
EPA 6010
2.5
100
29.0 J
32.1 J
ND
08/18/15
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
100
33.1 1
33.5 J
ND
08/09/16
EPA 6010
2.5
100
43.3 J
105
ND
02/13/17
EPA 6010
2.5
100
45.3 J
60.4 J
ND
08/22/17
EPA 6010
2.5
100
39.7 J
88.7 J
ND
02/05/18
EPA 6010
2.5
100
32.5 J
29.1 J
ND
08/13/18
EPA 6010D
2.5
100
70.0 1
86.6 1
ND
Granville County Joyce Engineering
Butner Landfill, Permit No. 39-02 Page 2 of 13 December 2018

APPENDIX E: Historical Constituents in Surface Water
Analytes
Sample Date
Method
DL
RL
SW-1
SW-2
Blanks
Beryllium
07/08/08
---
1.0
0.32 J
ND
ND
12/17/08
0.1
1.0
ND
ND
ND
07/09/09
0.1
1.0
ND
ND
ND
12/16/09
0.1
1.0
0.12 J
ND
ND
NC 2B = 6.5 µg/L (02/05/10)
06/24/10
0.1
1.0
ND
ND
ND
12/13/10
0.1
1.0
ND
ND
ND
06/20/11
1.0
1.0
ND
ND
ND
12/05/11
1.0
1.0
ND
ND
ND
06/11/12
1.0
1.0
ND
ND
ND
12/12/12
1.0
1.0
ND
ND
ND
05/01/13
1.0
1.0
ND
ND
ND
08/05/13
1.0
1.0
ND
ND
ND
02/24/14
1.0
1.0
ND
ND
ND
08/12/14
EPA 6010
1.0
1.0
---
ND
ND
03/10/15
EPA 6010
0.50
1.0
ND
ND
ND
08/18/15
---
Dry
Dry
---
02/16/16
EPA 6010
0.50
1.0
ND
ND
ND
08/09/16
EPA 6010
0.50
1.0
ND
ND
ND
02/13/17
EPA 6010
0.50
1.0
ND
ND
ND
08/22/17
EPA 6010
0.50
1.0
ND
ND
ND
02/05/18
EPA 6010
0.50
1.0
ND
ND
ND
08/13/18
EPA 6010D
0.50
1.0
ND
ND
ND
Granville County Joyce Engineering
Butner Landfill, Permit No. 39-02 Page 3 of 13 December 2018

APPENDIX E: Historical Constituents in Surface Water
Analytes
Sample Date
Method
DL
1
SW-2
Blanks
Chromium
06/17/97
---
10.0
ND
3.00
---
12/01/97
---
10.0
ND
ND
---
05/20/98
---
10.0
ND
ND
---
11/19/98
---
10.0
ND
ND
---
07/21/99
---
10.0
ND
ND
---
11/16/99
---
10.0
ND
ND
---
05/10/00
---
10.0
ND
ND
---
10/26/00
---
10.0
ND
ND
---
04/18/01
---
10.0
ND
ND
---
10/27/01
---
10.0
ND
ND
---
06/13/02
---
10.0
---
---
---
11/19/02
---
10.0
ND
ND
---
06/27/03
---
10.0
ND
ND
---
12/30/03
---
10.0
ND
ND
ND
06/30/04
---
10.0
ND
ND
ND
12/29/04
---
10.0
ND
ND
ND
06/29/05
---
10.0
ND
ND
ND
12/29/05
---
10.0
ND
ND
ND
06/28/06
---
10.0
ND
ND
ND
12/29/06
---
10.0
ND
ND
ND
07/12/07
---
10.0
ND
---
ND
12/19/07
---
10.0
2.20 B
2.60 B
1.40 J
NC 2B 50 µg/L (03/28/08)
07/08/08
---
10.0
2.50 J
2.20 J
ND
12/17/08
0.4
10.0
1.40 1
2.60 J
ND
07/09/09
0.4
10.0
2.6 1
1.2 1
ND
12/16/09
0.4
10.0
4.1 1
3.4 1
ND
06/24/10
0.4
10.0
3.3 B
7.3 J
0.71 J
12/13/10
0.4
10.0
1.4 J
1.5 J
ND
06/20/ 11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
7.2 J
ND
12/12/12
5.0
10.0
ND
8.2 J
ND
05/01/13
5.0
10.0
5.7 J
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/ 14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
---
ND
ND
03/10/15
EPA 6010
2.5
10.0
4.4 J
3.6 J
ND
08/18/15
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
10.0
4.6 J
6.8 J
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
2.90 J
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
02/05/18
EPA 6010
2.5
10.0
6.9 J
7.9 J
ND
08/13/18
EPA 601OD
2.5
10.0
5.9 J
ND
ND
Granville County Joyce Engineering
Butner Landfill, Permit No. 39-02 Page 4 of 13 December 2018

APPENDIX E: Historical Constituents in Surface Water
Analytes
Sample Date
Method
DL
RL
Rwi
SW-2
Blanks
Cobalt
05/20/98
---
10
2.0
2.0
---
11/19/98
---
10
ND
3.0
---
07/21/99
---
10
ND
ND
---
11/16/99
---
10
ND
ND
---
05/10/00
---
10
ND
ND
---
10/26/00
---
10
ND
ND
---
04/18/01
---
10
ND
ND
---
10/27/01
---
10.0
ND
22.0
---
06/13/02
---
10.0
---
---
---
11/19/02
---
10.0
ND
ND
---
06/27/03
---
10.0
ND
10.0
---
12/30/03
---
10.0
ND
ND
ND
06/30/04
---
10.0
ND
ND
ND
12/29/04
---
10.0
ND
ND
ND
06/29/05
---
10.0
ND
ND
ND
12/29/05
---
10.0
ND
ND
ND
06/28/06
---
10.0
ND
ND
ND
12/29/06
---
10.0
ND
ND
ND
07/12/07
---
10.0
ND
---
ND
12/19/07
---
10.0
4.2 B
1.20 B
1.8 J
07/08/08
---
10.0
4.80 B
10.5 B
6.20 J
12/17/08
0.6
10.0
1.70 B
1.1 B
2.50 J
07/09/09
0.6
10.0
ND
ND
ND
12/16/09
0.6
10.0
ND
1.0 J
ND
NC 2B = NE µg/L (03/24/10)
06/24/10
0.6
10.0
ND
ND
ND
12/13/10
0.6
10.0
{4.4} B
{ND{
1.6 {1.0 J{ J
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
Resample >
01/25/12
5.0
10.0
---
---
ND
06/11/12
5.0
10.0
ND
5.10 J
ND
12/ 12/ 12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
---
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
02/05/18
EPA 6010
2.5
10.0
ND
ND
ND
08/13/18
EPA 601OD
2.5
10.0
6.0 J
ND
ND
Granville County Joyce Engineering
Butner Landfill, Permit No. 39-02 Page 5 of 13 December 2018

APPENDIX E: Historical Constituents in Surface Water
Analytes
Sample Date
Method
DL
SW-1
SW-2
Blanks
Copper
12/29/06
---
10.0
1.3 B
1.10 B
0.60 J
07/12/07
---
10.0
ND
---
ND
12/19/07
---
10.0
5.3 B
ND
9.8
NC 2B = 7 µg/L (03/28/08)
07/08/08
---
10.0
1.7 J
4.20 J
ND
12/17/08
0.3
10.0
1.40 J
1.50 J
ND
07/09/09
0.3
10.0
ND
ND
ND
12/16/09
0.3
10.0
1.90 J
2.00 J
ND
06/24/10
0.3
10.0
ND
3.10 J
ND
12/13/10
0.3
10.0
0.31 B
ND
0.49 1
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
5.50 J
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
---
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
10.0
2.90 J
3.40 J
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
02/05/18
EPA 6010
2.5
10.0
3.8 J
3.8 J
ND
08/13/18
EPA 6010D
2.5
10.0
4.1 J
ND
ND
Granville County Joyce Engineering
Butner Landfill, Permit No. 39-02 Page 6 of 13 December 2018

APPENDIX E: Historical Constituents in Surface Water
Analytes
Sample Date
Method
DL
SW-1
SW-2
Blanks
Lead
05/20/98
---
10.0
ND
8.00
---
11/19/98
---
10.0
ND
ND
---
07/21/99
---
10.0
ND
10.0
---
11/16/99
---
10.0
ND
ND
---
05/10/00
---
10.0
ND
ND
---
10/26/00
---
10.0
ND
ND
---
04/18/01
---
10.0
ND
ND
---
10/27/01
---
10.0
ND
ND
---
06/13/02
---
10.0
---
---
---
11/19/02
---
10.0
ND
ND
---
06/27/03
---
10.0
ND
ND
---
12/30/03
---
10.0
ND
ND
ND
06/30/04
---
10.0
ND
ND
ND
12/29/04
---
10.0
ND
ND
ND
06/29/05
---
10.0
ND
ND
ND
12/29/05
---
10.0
ND
ND
ND
06/28/06
---
10.0
ND
ND
ND
12/29/06
---
10.0
ND
ND
ND
07/12/07
---
10.0
ND
---
ND
12/19/07
---
10.0
ND
ND
ND
NC 2B = 25 µg/L (03/28/08)
07/08/08
---
10.0
ND
ND
ND
12/17/08
4.0
10.0
ND
ND
ND
07/09/09
4.0
10.0
ND
ND
ND
12/ 16/09
4.0
10.0
ND
ND
ND
06/24/10
4.0
10.0
ND
ND
ND
12/13/10
4.0
10.0
ND
ND
ND
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
ND
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
---
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
02/05/18
EPA 6010
2.5
10.0
ND
ND
ND
08/13/18
EPA 6010D
2.5
10.0
ND
ND
ND
Granville County Joyce Engineering
Butner Landfill, Permit No. 39-02 Page 7 of 13 December 2018

APPENDIX E: Historical Constituents in Surface Water
Analytes
Sample Date
Method
DL
RL
SW-1
SW-2
Blanks
Nickel
12/29/04
---
50.0
ND
50.0 (ND)
ND
06/29/05
---
50.0
ND
ND
ND
12/29/05
---
50.0
ND
ND
ND
06/28/06
---
50.0
ND
ND
ND
12/29/06
---
50.0
ND
2.9 J
ND
07/12/07
---
50.0
3.8 J
---
ND
12/19/07
---
50.0
6.0
31.5
ND
NC 2B = 25 µg/L (03/28/08)
07/08/08
---
50.0
3.2 J
29.8 J
ND
12/17/08
1.7
50.0
2.4 B
4.0 B
2.4 J
07/09/09
1.7
50.0
4.1 J
12.3 J
ND
12/16/09
1.7
50.0
3.8 B
4.4 B
3.0 J
06/24/10
1.7
50.0
ND
2.0 J
ND
12/13/10
1.7
50.0
ND
14.2 J
2.7 J
06/20/11
5.0
50.0
ND
7.8 J
ND
12/05/11
5.0
50.0
ND
5.3 J
ND
06/11/12
5.0
50.0
ND
11.0 J
ND
12/12/12
5.0
50.0
ND
13.8 J
ND
05/01/13
5.0
50.0
ND
ND
ND
08/05/13
5.0
50.0
ND
5.6 J
ND
02/24/14
5.0
50.0
ND
ND
ND
08/12/14
EPA 6010
5.0
50.0
---
20.3 J
ND
03/10/15
EPA 6010
2.5
50.0
3.0 J
3.8 J
ND
08/18/15
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
50.0
2.9 J
4.7 J
ND
08/09/16
EPA 6010
2.5
50.0
3.3 J
15.2 J
ND
02/13/17
EPA 6010
2.5
50.0
ND
7.3 J
ND
08/22/17
EPA 6010
2.5
50.0
ND
16.3 J
ND
02/05/18
EPA 6010
2.5
50.0
5.3 J
4.4 J
ND
08/13/18
EPA 601OD
2.5
50.0
7.3 J
12.4 J
ND
Silver
07/12/07
---
10.0
2.20 J
---
ND
12/19/07
---
10.0
ND
0.34 J
ND
C 2B = 0.06 µg/L (03/28/08)
07/08/08
---
10.0
0.35 B
1.00 J
0.12 J
12/17/08
0.1
10.0
ND
ND
ND
07/09/09
0.1
10.0
ND
0.10 J
ND
12/ 16/09
0.1
10.0
ND
0.16 J
ND
06/24/10
0.1
10.0
ND
0.26 J
ND
12/13/10
0.1
10.0
{ND}
{0.28{ B
0.21 {0.19 J} J
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
ND
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/ 14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
---
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
02/05/18
EPA 6010
2.5
10.0
ND
ND
ND
08/13/18
EPA 6010D
2.5
10.0
ND
ND
ND
Granville County Joyce Engineering
Butner Landfill, Permit No. 39-02 Page 8 of 13 December 2018

APPENDIX E: Historical Constituents in Surface Water
Analytes
Sample Date
Method
DL
RL
SW-1
SW-2
Blanks
Thallium
12/29/04
---
10.0
ND
10.0 (ND)
ND
06/29/05
---
10.0
ND
ND
ND
12/29/05
---
10.0
ND
ND
ND
06/28/06
---
10.0
ND
ND
ND
12/29/06
---
6.00
ND
ND
ND
07/12/07
---
5.5
ND
---
ND
12/19/07
---
5.5
3.60 J
ND
ND
07/08/08
---
5.5
3.40 J
ND
ND
12/17/08
3.0
5.5
ND
ND
ND
07/09/09
3.0
5.5
ND
ND
ND
12/16/09
3.0
5.5
ND
ND
ND
NC 2B = NE (03/24/10)
06/24/10
3.0
5.5
ND
ND
ND
12/13/10
3.0
5.5
3.80 J
ND
ND
06/20/11
5.4
5.5
ND
ND
ND
12/05/11
5.4
5.5
ND
ND
ND
06/11/12
5.4
5.5
ND
ND
ND
12/12/12
5.4
5.5
ND
ND
ND
05/01/13
5.4
5.5
ND
ND
ND
08/05/13
5.4
5.5
ND
ND
ND
02/24/14
5.4
5.5
ND
ND
ND
08/12/14
EPA 6010
5.4
5.5
---
ND
ND
03/10/15
EPA 6010
5.0
5.5
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
5.0
5.5
ND
ND
ND
08/09/16
EPA 6010
5.0
5.5
ND
ND
ND
02/13/17
EPA 6020B
0.020
5.5
ND
ND
ND
08/22/17
EPA 6020B
0.020
5.5
ND
ND
ND
02/05/18
EPA 6020B
0.028
0.10
ND
ND
ND
08/13/18
EPA 6020B
0.020
5.50
ND
ND
ND
Vanadium
12/29/06
---
25.0
1.60 1
2.00 J
ND
07/12/07
---
25.0
4.60 J
---
ND
12/19/07
---
25.0
3.30 J
1.40 B
0.62 J
NC 2B = NE µg/L (03/28/08)
07/08/08
---
25.0
5.20 1
2.30 J
0.20 J
12/17/08
0.2
25.0
1.80 B
2.70 B
0.76 J
07/09/09
0.2
25.0
5.00 B
3.40 B
1.30 1
12/16/09
0.2
25.0
3.60 J
3.50 J
0.53 J
06/24/10
0.2
25.0
5.80 J
2.60 J
ND
12/13/10
0.2
25.0
1.60 B
0.67 B
0.36 J
06/20/11
5.0
25.0
ND
ND
ND
12/05/11
5.0
25.0
ND
ND
ND
06/11/12
5.0
25.0
ND
11.50 J
ND
12/12/12
5.0
25.0
ND
ND
ND
05/01/13
5.0
25.0
ND
ND
ND
08/05/13
5.0
25.0
ND
ND
ND
02/24/14
5.0
25.0
ND
ND
ND
08/12/14
EPA 6010
5.0
25.0
---
ND
ND
03/10/15
EPA 6010
2.5
25.0
3.9 J
4.7 J
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
25.0
4.1 J
5.8 J
ND
08/09/16
EPA 6010
2.5
25.0
2.9 1
2.8 1
ND
02/13/17
EPA 6010
2.5
25.0
ND
ND
ND
08/22/17
EPA 6010
2.5
25.0
2.8 J
ND
ND
02/05/18
EPA 6010
2.5
25.0
6.6 J
5.9 J
ND
08/13/18
EPA 6010D
2.5
25.0
8.3 J
3.1 J
ND
Granville County Joyce Engineering
Butner Landfill, Permit No. 39-02 Page 9 of 13 December 2018

APPENDIX E: Historical Constituents in Surface Water
Analytes
Sample Date
Method
DL
SW-1
SW-2
Blanks
Zinc
11/22/96
---
50.0
11.0
ND
---
06/17/97
---
50.0
ND
ND
---
12/01/97
---
50.0
20.0
ND
---
05/20/98
---
50.0
20.0
28.0
---
11/19/98
---
50.0
ND
ND
---
07/21/99
---
50.0
ND
ND
---
11/16/99
---
50.0
ND
ND
---
05/10/00
---
50.0
ND
ND
---
10/26/00
---
50.0
ND
ND
---
04/18/01
---
50.0
ND
ND
---
10/27/01
---
50.0
ND
ND
---
06/13/02
---
50.0
---
---
---
11 / 19/02
---
50.0
ND
ND
---
06/27/03
---
50.0
ND
ND
---
12/30/03
---
50.0
ND
ND
ND
06/30/04
---
50.0
ND
ND
ND
12/29/04
---
50.0
ND
ND
ND
06/29/05
---
50.0
ND
ND
ND
12/29/05
---
50.0
ND
ND
ND
06/28/06
---
50.0
ND
ND
ND
12/29/06
---
50.0
ND
ND
ND
07/12/07
---
10.0
ND
---
ND
12/19/07
---
10.0
24.6 B
ND
102
NC 2B = 50 µg/L (03/28/08)
07/08/08
---
10.0
ND
ND
1.20 J
12/17/08
0.4
10.0
ND
0.89 B
0.49 J
07/09/09
0.4
10.0
ND
4.90 B
1.60 J
12/16/09
0.4
10.0
2.60 B
2.60 B
7.70 J
06/24/10
0.4
10.0
ND
14.9
ND
12/13/10
0.4
10.0
ND
9.80 B
6.70 J
06/20/ 11
10.0
10.0
ND
ND
ND
12/05/11
10.0
10.0
ND
ND
12.4
06/11/12
10.0
10.0
ND
ND
ND
12/12/12
10.0
10.0
ND
ND
ND
05/01/13
10.0
10.0
ND
16.80
ND
08/05/13
10.0
10.0
ND
ND
ND
02/24/14
10.0
10.0
ND
ND
ND
08/12/14
EPA 6010
10.0
10.0
---
ND
ND
03/10/15
EPA 6010
5.0
10.0
7.7 B
7.8 B
5.6 J
08/18/15
---
Dry
Dry
---
02/16/16
EPA 6010
5.0
10.0
7.0 1
ND
ND
08/09/16
EPA 6010
5.0
10.0
ND
ND
ND
02/13/17
EPA 6010
5.0
10.0
ND
5.2 J
ND
08/22/17
EPA 6010
5.0
10.0
ND
ND
ND
02/05/18
EPA 6010
5.0
10.0
ND
ND
ND
08/13/18
EPA 601OD
5.0
10.0
6.0 J
ND
ND
Granville County Joyce Engineering
Butner Landfill, Permit No. 39-02 Page 10 of 13 December 2018

APPENDIX E: Historical Constituents in Surface Water
Analytes
Sample Date
Method
DL
RL
SW-1
SW-2
Blanks
ORGANICS
Acetone
10/27/01
---
100
168.0 B
337.0 B
479.0
06/13/02
---
100
---
---
---
06/13/02
---
100
---
---
---
11/19/02
---
100
ND
ND
---
06/27/03
---
100
ND
ND
---
12/30/03
---
100
ND
ND
ND
06/30/04
---
100
ND
ND
ND
12/29/04
---
100
ND
ND
ND
06/29/05
---
100
ND
ND
ND
12/29/05
---
100
ND
ND
ND
06/28/06
---
100
ND
ND
ND
12/29/06
---
100
ND
ND
ND
07/12/07
---
100
ND
---
ND
12/19/07
---
100
12.70 B
ND
4.50 J
NC 2B = 2,000 µg/L (03/28/08)
07/08/08
---
100
ND
ND
ND
12/17/08
20
100
ND
ND
ND
07/09/09
20
100
ND
ND
ND
NC 2B = NE (03/24/10)
12/16/09
2.2
100
ND
ND
2.80 J
06/24/10
2.2
100
2.80 B
ND
7.70 J
12/13/10
2.2
100
ND
3.00 J
ND
06/20/11
2.2
100
ND
3.80 B
3.90 J
12/05/11
2.2
100
ND
7.20 B
8.80 J
06/11/12
2.2
100
ND
5.50 B
4.70 J
12/12/12
10.0
100
ND
ND
ND
05/01/13
10.0
100
ND
ND
14.6 J
08/05/13
10.0
100
ND
ND
ND
02/24/14
10.0
100
ND
ND
25.7 J
08/12/14
EPA 8260
10.0
100
---
ND
22.0 J
03/10/15
EPA 8260
10.0
100
ND
ND
ND
08/18/15
---
Dry
Dry
---
02/16/16
EPA 8260
10.0
100
ND
ND
ND
08/09/16
EPA 8260
10.0
100
ND
ND
ND
02/13/17
EPA 8260
10.0
100
ND
ND
ND
08/22/17
EPA 8260
10.0
100
ND
ND
ND
02/05/18
EPA 8260
10.0
100
ND
ND
ND
08/13/18
EPA 8260B
10.0
100
ND
ND
ND
Granville County Joyce Engineering
Butner Landfill, Permit No. 39-02 Page 11 of 13 December 2018

APPENDIX E: Historical Constituents in Surface Water
Analytes
Sample Date
Method
DL
RL
1
SW-2
Blanks
Chlorobenzene
06/27/03
---
5.0
ND
7.20
ND
12/30/03
---
5.0
ND
ND
ND
06/30/04
---
5.0
ND
ND
ND
12/29/04
---
5.0
ND
ND
ND
06/29/05
---
5.0
ND
ND
ND
12/29/05
---
5.0
ND
ND
ND
06/28/06
---
5.0
ND
ND
ND
12/29/06
---
3.0
ND
ND
ND
07/12/07
---
3.0
ND
---
ND
12/19/07
---
3.0
ND
ND
ND
NC 2B = 130 µg/L (03/28/08)
07/08/08
---
3.0
ND
ND
ND
12/17/08
0.23
3.0
ND
ND
ND
07/09/09
0.23
3.0
ND
ND
ND
12/16/09
0.23
3.0
ND
ND
ND
06/24/10
0.23
3.0
ND
ND
ND
12/13/10
0.23
3.0
ND
ND
0.28 J
06/20/11
0.23
3.0
ND
ND
ND
12/05/11
0.23
3.0
ND
ND
ND
06/11/12
0.23
3.0
ND
ND
ND
12/12/12
0.23
3.0
ND
ND
ND
05/01/13
0.23
3.0
ND
ND
ND
08/05/13
0.23
3.0
ND
ND
ND
02/24/14
0.23
3.0
ND
ND
ND
08/12/14
EPA 8260
0.23
3.0
---
ND
ND
03/10/15
EPA 8260
0.23
3.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 8260
0.23
3.0
ND
ND
ND
08/09/16
EPA 8260
0.23
3.0
ND
ND
ND
02/13/17
EPA 8260
0.23
3.0
ND
ND
ND
08/22/17
EPA 8260
0.23
3.0
ND
ND
ND
02/05/18
EPA 8260
0.23
3.0
ND
ND
ND
08/13/18
EPA 8260B
0.23
3.0
ND
ND
ND
Chloromethane
07/09/09
0.11
1.0
ND
0.19 J
ND
12/16/09
0.11
1.0
ND
ND
ND
C 2B = NE (03/24/10)
06/24/10
0.11
1.0
ND
ND
ND
12/13/10
0.11
1.0
ND
ND
ND
06/20/11
0.11
1.0
ND
ND
ND
12/05/11
0.11
1.0
ND
ND
ND
06/11/12
0.11
1.0
ND
ND
ND
12/12/12
0.11
1.0
ND
ND
ND
05/01/13
0.11
1.0
ND
ND
ND
08/05/13
0.11
1.0
ND
ND
ND
02/24/14
0.11
1.0
ND
ND
0.25 J
08/12/14
EPA 8260
0.11
1.0
---
ND
ND
03/10/15
EPA 8260
0.11
1.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 8260
0.11
1.0
ND
ND
ND
08/09/16
EPA 8260
0.11
1.0
ND
ND
ND
02/13/17
EPA 8260
0.11
1.0
0.17 J
0.19 J
0.18 J
08/22/17
EPA 8260
0.11
1.0
ND
ND
ND
02/05/18
EPA 8260
0.11
1.0
ND
ND
ND
08/13/18
EPA 8260B
0.11
1.0
ND
ND
ND
Methylene Chloride
08/09/16
EPA 8260
0.97
1.0
ND
ND
2.20 J
02/13/17
EPA 8260
0.97
1.0
ND
ND
ND
NC 2L = 5 µg/L (2/5/10)
08/22/17
EPA 8260
0.97
1.0
ND
ND
1.4 C9
02/05/18
EPA 8260
0.97
1.0
ND
ND
ND
08/13/18
EPA 8260B
0.97
1.0
ND
ND
6.6
Granville County Joyce Engineering
Butner Landfill, Permit No. 39-02 Page 12 of 13 December 2018

APPENDIX E: Historical Constituents in Surface Water
Analytes
Sample Date
Method
DL
RL
SW-1
SW-2
Blanks
1,4-Dioxane (p-Dioxane)
08/13/18
EPA 8260B Mod.
1.9
2.0
ND
14.1
ND
Notes:
All concentrations are in micrograms per liter (µg/L).
RL = Reporting Limit (SWSL for December 2006 - present).
DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank -qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory reporting limit.
NS = Not sampled.
NR = Not Reported.
Dry =Surface water point considered to be dry.
NC 2B = North Carolina Surface Water Standards from 15A NCAC 2B.0101
NE = Not established.
Shaded values for surface water are above the NC 2B.
Granville County Joyce Engineering
Butner Landfill, Permit No. 39-02 Page 13 of 13 December 2018