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3901_Granville_Oxford_Unit2_MSWLF_GW_FID1261329_20180810
E—NR USE ONLY []Paper Report []Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR I I Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Joyce Engineering, Inc. Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: G. Van Ness Burbach, Ph.D., P.G. Phone: (336) 323-0092 E-mail: vburbach@joyceengineering.com NC Landfill Rule: Facility name: Facility Address: Facility Permit # (.0500 or .1600) Oxford Landfill Unit 2 6584 Landfill Rd. 3901- .1600 Oxford, NC 27565 MSWLF-2012 Actual sampling dates (e.g., October 20-24, 2006) August 15-16, 2018 October 3, 2018 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑X Detection Monitoring ❑ Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells Leachate monitoring data ❑ Surface water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? BX No. No groundwater or surface water standards were exceeded. Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. G. Van Ness Burbach, Ph.D., PG Technical Consultant (336) 323-0092 Title (Area Code) Telephone Number 1104, / 9 h 1 /'s y. Affix NC Licensed/ Professional Geologist Seal 2211 W. Meadowview Rd., Ste. 101 Greensboro, NC 27407 Facility Representative Address C-0782 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 CAV/v��s � J�o SEAL 1349 = ;Gq �FOLOG�`� �?,c %:V VESS � .•�`'. PREPARED FOR: GRANVILLE COUNTY SOLID WASTE DEPARTMENT P.O. Box 906 OXFORD, NORTH CAROLINA 27565 �lu F N CAlau OXFORD UNIT 2 LANDFILL PERMIT No. 39-01 MSWLF 2012 AUGUST 2018 SEMIANNUAL WATER QUALITY MONITORING REPORT NOVEMBER 2018 PREPARED BY: &.# I MILEE �rv�rnr�El�rrv� 2211 WEST MEADOWVIEW ROAD, SUITE 101 GREENSBORO, NORTH CAROLINA 27407 NC LICENSE NUMBER C-0782 PHONE: (336) 323-0092 FAx: (336) 323-0093 PROJECT No. 2182022, PHASE 06 August 2018 Semiannual Water Quality Monitoring Report Oxford Unit 2 Landfill Granville County, North Carolina TABLE OF CONTENTS 1.0 INTRODUCTION............................................................................................................. I 1.1 Site Information........................................................................................................ 1 1.2 Site Conceptual Model............................................................................................. 1 1.2.1 Site Geology...............................................................................................................................1 1.2.2 Site Hydrogeology.....................................................................................................................2 1.3 Regulatory Status......................................................................................................2 2.0 FACILITY MONITORING PROGRAM.......................................................................2 2.1 Groundwater Monitoring Program........................................................................... 2 2.2 Surface Water Monitoring Program......................................................................... 3 3.0 AUGUST 2018 SEMIANNUAL SAMPLING EVENT..................................................3 3.1 Field Work................................................................................................................ 3 3.2 Laboratory Analysis and Quality Control................................................................ 4 4.0 HYDROGEOLOGY......................................................................................................... 5 5.0 DATA ANALYSIS AND STATISTICAL RESULTS....................................................6 5.1 Analytical Results and Comparisons to Standards .................................................... 6 5.1.1 Groundwater...............................................................................................................................6 5.1.2 Surface water..............................................................................................................................7 5.2 Statistical Methods.................................................................................................... 7 6.0 CONCLUSION..................................................................................................................7 7.0 REFERENCES..................................................................................................................7 August 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 December 2018 i August 2018 Semiannual Water Quality Monitoring Report Oxford Unit 2 Landfill Granville County, North Carolina TABLE OF CONTENTS CONTINUED Tables Table 1 August 2018 Groundwater Elevations Table 2 August 2018 Estimated Hydraulic Gradients and Velocities Table 3 August 2018 Detections Table 4 August 2018 Exceedances Table 5 August 2018 Field Parameters Figure Figure 1 Site Location Map (USGS Topographic Map) Drawing Drawing 1 Groundwater Potentiometric Surface Map Appendices Appendix 1 Well Construction Details Appendix 2 Laboratory Analytical Reports and Field Data Logs Appendix 3 Historical Data Table A3-1 Historical Groundwater Elevations Table A3-2 Historical Groundwater Constituents Table A3-3 Historical Surface Water Constituents Table A3-4 Historical Groundwater Field Parameters Table A3-5 Historical Surface Water Field Parameters August 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 December 2018 ii 1.0 INTRODUCTION On behalf of Granville County, Joyce Engineering, (JOYCE) has prepared this Water Quality Monitoring Report for the Oxford Unit 2 Municipal Solid Waste Landfill, Solid Waste Permit Number 3901-MSWLF-2012 (facility), in accordance with the North Carolina Solid Waste Management Rules (NCSWMR) 15A NCAC 13B.1632. 1.1 Site Information The Oxford Landfill is located at 6584 Landfill Road, Oxford, Granville County, North Carolina, near the town of Kinton Fork (Figure 1). The facility is owned and operated by Granville County under Permit Number 3901-MSWLF-2012, issued by the North Carolina Department of Environmental Quality (NCDEQ) Solid Waste Section (SWS). The Oxford Landfill consists of two separate waste disposal units. Unit 1 is a former unlined municipal solid waste (MSW) landfill originally permitted for disposal of domestic, institutional, industrial, agricultural, and demolition wastes, with a C&D landfill on top. Unit 2 is a Subtitle-D MSW landfill. Granville County received the Unit 2 Permit to Operate from the NCDEQ on February 19, 2013. The County began placing waste in Unit 2 on May 1, 2013. 1.2 Site Conceptual Model 1.2.1 Site Geology The Oxford Landfill is located in the Carolina Slate Belt of the Piedmont Physiographic Province of North Carolina. The geologic province is characterized by rolling topography with a thick mantle of saprolite overlying late -Proterozoic and Paleozoic igneous and metamorphic bedrock. The Carolina Slate Belt is comprised of 550 to 650 million year old, metamorphosed sedimentary and volcanic rocks, intruded by granitic rocks. The Oxford Landfill is underlain by the Flat River Complex, a shallow intrusive complex of granitic composition, which comprises a large portion of the northern Carolina Slate Belt (Butler, 1991). The landfill is approximately 18 miles east of the Virgilina Synclinorium, approximately 10 miles west of the Nutbush Creek Fault Zone, and approximately 4 miles northwest of the Durham Basin (Butler, 1991). Previous investigations discovered limited exposures of competent, massive, gray to greenish gray meta -volcanic rock that is moderately fractured. Prominent fractures with near vertical dips and strike approximately N-20°- E (JOYCE, 2009b). Boring logs indicate that the depth to bedrock at Oxford Landfill ranges from 3 to 35 feet below ground surface. The overlying saprolite consists of brownish sandy to clayey silt (JOYCE, 2009b). August 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 December 2018 1 1.2.2 Site Hydro _geology Groundwater in the Piedmont can occur in substantial volumes where the soil is thick, but groundwater is typically found in minimal volumes in bedrock, primarily restricted to fractures. Based on groundwater depth measurement, the water table under the area landfill was encountered in the unconfined aquifer that is mostly in the transition zone that consists of saprolite and highly fractured bedrock. This unconfined aquifer is pervasive across the site. The saturated portion of the uppermost aquifer beneath the landfill is vertically continuous to bedrock, and no confining layers have been encountered during permitting. There is a high degree of connectivity between the saprolite and underlying fractured bedrock such that they behave as a single continuous aquifer. Groundwater elevations in Table 1 show that the depth to water ranged from 3 to 25 feet below grade in wells MW-7, MW-8, MW-9, MW-10, MW-11, and NES-2S. In general, the water table is near the saprolite/bedrock interface. Drawing 1 presents a groundwater potentiometric surface map based on static water level data obtained from both Unit 1 and Unit 2 monitoring wells on August 14-16, 2018. As depicted in Drawing 1, the groundwater flow generally to the north beneath Unit 2. 1.3 Regulatory Status The Granville County Oxford Unit 2 Landfill groundwater monitoring is completed in accordance with North Carolina Administrative Code Title 15A — Environmental Quality Chapter 13 SubChapter B — Solid Waste Management Rule (NCSWMR) § 1633 (Detection Monitoring Program). Statistical analyses of the laboratory data when required is prepared in accordance with the required compliance demonstration of the NCSWS Rule .1632(g), (h), and (i). 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program Six groundwater monitoring wells comprise the compliance monitoring network at the Oxford Unit 2 Landfill. The compliance network includes monitoring wells MW-7 (the current facility background well), MW-8 (which monitors the leachate tank area), MW-9, MW-10, MW-11, and NES-2S. The locations of these wells are shown on Drawing 1. All monitoring wells are sampled for Appendix I of 40 CFR Part 258, from here on known as North Carolina Appendix I list of constituents, during both semiannual sampling events in accordance with the January 2018 Water Quality Monitoring Plan for the facility. MW-7 also serves as the background well for the Unit 1 landfill and NES-2S also serves as a performance well under the Unit 1 Corrective Action Plan (CAP) for the facility. The monitoring well usages within the monitoring network and well construction details are presented in Appendix 1. August 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 December 2018 2 2.2 Surface Water Monitoring Program There are two surface water sampling points associated with Unit 2: SW-3, and SW-4. Sampling point SW-3 is located upstream of Unit 2, Phase 1 on the perennial creek that runs along the east side of the new phase. SW-4 is located on the same perennial creek downstream of the new phase, but before the confluence of the perennial creek and the drainage channel from the west side of Unit 2. The surface water samples are analyzed for the NCSWMR Appendix I list of constituents during both semiannual events. 3.0 AUGUST 2018 SEMIANNUAL SAMPLING EVENT 3.1 Field Work On August 15-16, 2018, JOYCE personnel visited Oxford Landfill to purge and sample monitoring wells MW-7, MW-8, MW-9, MW-10, and NES-2S and to collect samples from surface points SW-3 and SW-4. MW-I I could not be located in the brush and was not sampled. A resampling event took place on October 3, 2018, where JOYCE personnel revisited Oxford Landfill to locate, purge and sample MW-11. Monitoring wells were purged and sampled using either a 12-volt submersible pump or disposable bailers. Field measurements of temperature, pH, specific conductivity, and turbidity were recorded in a field log for all monitoring wells. Prior to sampling, laboratory -supplied containers were prepared with the following information: • Monitoring well ID (completed by laboratory or field personnel); • Date and time of sample collection (completed by field personnel); • Initials of sampling personnel (completed by field personnel); • Project name and number (completed by the laboratory or field personnel); • Chemical preservative (completed by the laboratory or field personnel); and • Requested chemical analysis (completed by the laboratory or field personnel). Groundwater samples from each monitoring well were collected within 24 hours of the final purge volume and were dispensed directly from the pump flow or bailer into the laboratory - provided containers. Immediately after collection, the samples were placed in a laboratory - provided cooler and preserved on ice. Field sampling logs are provided in Appendix 2. Surface water samples from SW-3 and SW-4 were collected directly from stream by lowering a clean, unpreserved sample container into the stream flow and dispensing the water into laboratory -prepared sample containers. Care was taken to avoid sample -induced turbidity. At the time of sampling, surface water was also measured for temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction potential, and turbidity. After sample collection, the samples were placed in a laboratory provided cooler and chilled on ice. Field sampling logs are provided in Appendix 2. August 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 December 2018 3 3.2 Laboratory Analysis and Quality Control The groundwater and surface water samples collected during the August 2018 sampling event were delivered to Pace Analytical Services Inc. of Huntersville, North Carolina under chain -of - custody protocol. Groundwater samples from the compliance wells and surface points were analyzed for NC Appendix I constituents. According to the laboratory records, the water samples were received by the laboratory on August 17, 2018, in good condition, properly preserved, at proper temperatures, and within analysis hold times. In addition to samples collected for compliance monitoring at the Oxford Landfill, JOYCE personnel collected a Field Blank as part of the August 2018 sampling event quality control and quality assurance (QA/QC) procedure. The Field Blank was analyzed for NC Appendix in both Oxford Unit 1 and Unit 2 list of constituents. Also, as part of the QA/QC procedure, a Trip Blank that was prepared by the laboratory accompanied the volatile sampling containers to and from the laboratory. The Trip Blank was analyzed for both Oxford Unit 1 and Unit 2 NC Appendix I list of constituents list of volatile organic compounds (VOCs). Upon receipt of the laboratory data package, JOYCE personnel reviewed the following data: • General typographical errors; • Correct analyses performed and within method specified hold times; • Biased data results based on Matrix Spike, Matrix Spike Duplicate, and Laboratory Control Samples; • Blank qualified data (B-flags); • Detections above the 15A NCAC 2L.0202 (NC2L) Groundwater Standards or the SWS Groundwater Water Protection Standards (GWPS), or 15A NCAC 2B (NC 2B) Surface Water Standards; and • Detections above historical levels. The complete laboratory analytical reports are included in Appendix 1. 4.0 HYDROGEOLOGY Depth to groundwater is measured in all compliance monitoring wells at the site prior to each sampling event. The groundwater elevations calculated relative to the surveyed measuring point (top of casing) for each monitoring well are summarized in Table 1. The groundwater elevation contours shown in Drawing 1 are based on data from the August 2018 sampling event. Groundwater flow beneath the Unit 1 Landfill is primarily to the north. Horizontal groundwater gradients were estimated from the August 2018 groundwater levels and are summarized in Table 2. Horizontal gradients (i) across the site ranged from 0.0225 to 0.0261 with an average of 0.0243. These values are consistent with previous estimates. Linear groundwater flow velocities for wells screened in saprolite were computed using the following modified Darcy equation: August 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 December 2018 4 where: V=Ki/ne, V = average linear velocity (feet/year), K = hydraulic conductivity (feet/day), i = horizontal hydraulic gradient, and ne = effective porosity. Under Unit 1, the water table is mostly above top of bedrock so flow is primarily in saprolite; therefore, the hydraulic conductivity (K = .0731 ft/day) was based on the geometric mean of values from slug tests conducted on saprolite wells at the facility in 2009 and the effective porosity (ne) value was estimated at 85% of the laboratory -determined porosity for soil samples from the facility. Under Unit 2, the water table is mostly below top of bedrock so flow is primarily in fractured bedrock; therefore, the hydraulic conductivity (K = 4.43 ft/day) was based on the geometric mean of values from slug tests conducted on bedrock wells at the facility in 2009 and the effective porosity (ne) value for fractured bedrock was estimated at 15%. Calculations for both Units are presented in Table 2. The average estimated linear groundwater flow velocity under Unit 2 is calculated to be approximately 281 feet per year. The modified Darcy equation for linear flow velocity makes the simplifying assumptions of a homogeneous and isotropic aquifer. 5.0 DATA ANALYSIS AND STATISTICAL RESULTS The final results from the August 2018 groundwater and surface water sampling event were received on August 30, 2018 from Pace Analytical. The final results from the October 3, 2018 resample of MW-11 were received on October 18, 2018 from Pace Analytical. All laboratory analytical reports can be found in Appendix 2. 5.1 Analytical Results and Comparisons to Standards 5.1.1 Groundwater Two inorganic constituents were detected in the August 2018 groundwater samples at a quantified concentration above the method reporting limit (MRL). Copper was detected above the MRL in MW-8 and iron was detected above the MRL in MW-7. No organic constituents were detected at quantified concentrations above the MRL. The only constituent in exceedance of its NC2L standard during this sampling event was Iron in well MW-8; however, this is consistent with previous detections and an alternate source demonstration (ASD) for iron was approved for the Oxford Landfill in 2011. No other constituents were detected above the NC2L or GWPS in any groundwater sample. Table 3 summarizes the quantified detections of constituents for the August 2018 sampling event. The laboratory analytical reports, the laboratory quality assurance/quality control information, and the chains -of -custody, are included in Appendix 2. Historical groundwater analytical results are presented in Appendix 3 (Table A3-2). Historical groundwater field parameters are summarized in Appendix 3 (Table A34). August 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 December 2018 5 MW-7 is the current upgradient background well for both Unit 1 and Unit 2. Data from MW-7 from June 2011 to present may be used to determine statistical background concentrations for inorganic constituents detected at the facility. In addition to data from MW-7, pre -waste background sampling data from MW-8, MW-9, MW-10, MW-11, and MW-12 collected between June and October 2012 may also be included as background data for statistical analyses. 5.1.2 Surface Water There were no constituents detected at quantified levels above the MRL in surface water samples SW-3 or SW-4. Surface water analytical results from the site were compared to the 15A-NCAC- 2B (NC-2B) surface water standards for Class C waters (aquatic life and secondary recreation). No constituents were detected above the NC 2B standard for Class C waters. The laboratory analytical reports, the laboratory quality assurance/quality control information, and the chains -of - custody for SW-3 and SW-4 are included in Appendix 2. Historical surface water analytical results are presented in Appendix 3 (Table A3-3). Historical surface water field parameters are presented in Appendix 3 (Table A3-5). 5.2 Statistical Methods The background data for inorganic constituents are evaluated in accordance with the procedures outlined in 15A NCAC 13B.1632 (g) and (h) to determine if the reported concentration exceeded the facility background concentrations using the Shapiro -Wilk Test, Parametric Prediction Limits, Parametric Tolerance Intervals, Aitchison's Adjustment, Non -Parametric Prediction Limits, and Poisson Prediction Limits as appropriate. Background data, tests for normality, outliers, Aitchison's adjustment, tolerance interval, or prediction limits are used, as appropriate based on the background data. The statistical test by which downgradient data are compared to facility background data is based upon the nature of the data and the number of data values that are less than the laboratory limit of detection. All statistical tests are evaluated at the 0.05 level of significance, 95% confidence level, and are conducted as one -tailed tests. No statistical analyses were conducted as part of this report. 6.0 CONCLUSION Based on analytical results from the August 2018 monitoring event, the Granville County, Oxford Unit 2 Landfill will remain in the Detection Monitoring program as outlined in Title 15A NCAC 13B.1633. The next semiannual sampling event is tentatively scheduled for February 2019. 7.0 REFERENCES The references cited herein were used to prepare this document and may or may not be cited in the text of this report. August 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 December 2018 6 Butler, J. Robert, and Secor, Jr., Donald T., 1991, The Central Piedmont, in Horton, J. W., Jr., and Zullo, V. A., eds., The Geology of the Carolinas: The University of Tennessee Press, p. 59-78. JOYCE, 2009a. Corrective Action Plan, Granville County Oxford Landfill. March 2009. JOYCE, 2009b. Hydrogeologic Reports, Granville County Oxford Landfill. October 2009. JOYCE, 2010a. Request for Background Well Replacement, Granville County Oxford Landfill, Permit # 39-01. October 25, 2010. JOYCE, 2010b. Corrective Action Evaluation Report and Alternate Source Demonstrations, Granville County Oxford C&D Over MSW Landfill, Permit # 39-01. November 29, 2010. JOYCE, 2013. Groundwater Background Monitoring Report Unit 2, Phase 1 MSWLF Expansion. January 4, 2013 North Carolina Department of Environment, Health, and Natural Resources, 1997. North Carolina Solid Waste Management Rules. 15 NCAC 13B.1600. January 1, 1997, with updates through April 2011. North Carolina Geological Survey, 1985, Geologic map of North Carolina: North Carolina Department of Natural Resources and Community Development, scale 1:500000. USEAP, 1992. Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance. July 1992. Woodward -Clyde Consultants, 1994. Transition Plan, Oxford Landfill Granville County, North Carolina. April 1994. 8.0 ACRONYMS ACM Assessment of Corrective Measures (report) AOC Area of Concern ASD Alternate Source Demonstration (report) C&D Construction and Demolition Waste CAP Corrective Action Plan (report) CAER Corrective Action Evaluation Report (report) CPVC Chlorinated Poly Vinyl Chloride COz Carbon Dioxide COC Contaminant of Concern August 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 December 2018 7 DCA Dichloroethane DCE Dichloroethylene DENR See NCDEQ DEQ See NCDENR DH Dissolved Hydrogen DL Detection Limit (for laboratory data) DO Dissolved Oxygen EPA United States Environmental Protection Agency Fee+ Ferrous Iron GEU Gas Extraction Unit GPS Groundwater Protection Standards per NCSWMR rule .1634.g.5. GWPS Groundwater Protection Standards set by the NCDEQ-SWS for constituents with no NC2L standard. HASP Site -specific Health and Safety Plan HDPE High -density Polyethylene JE Joyce Engineering JOYCE Joyce Engineering LFG Landfill Gas LEL Lower Explosive Limit MNA Monitored Natural Attenuation MSW Municipal Solid Waste MW Monitoring Well NC 2B North Carolina Surface Water Standards found in 15A NCAC 2B.0101 NC 2L North Carolina Groundwater Standards found in 15A NCAC 2L.0202 NCAC North Carolina Administrative Code NCDENR North Carolina Department of Environment and Natural Resources (now NCDEQ) NCDEQ North Carolina Department of Environmental Quality (formerly NCDENR) NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600) ND Not Detected (for laboratory data) NES Nature and Extent Study (report) O&M Operations and Maintenance ORP Oxidation -Reduction Potential OSHA Occupational Health and Safety Association PCE Perchloroethylene (aka — tetrachloroethylene) PVC Poly Vinyl Chloride QL Quantitation Limit (for laboratory data) QRA Quantitative Risk Assessment (report) RL Reporting Limit (for laboratory data) SC Specific Conductance SSI Statistically Significant Increase (over background concentration) SWQS Surface Water Quality Standards SWS NCDEQ (or NCDENR) Division of Waste Management, Solid Waste Section August 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 December 2018 SWSL North Carolina Solid Waste Section Reporting Limits (for laboratory data) TCE Trichloroethylene TDS Total Dissolved Solids TOC Total Organic Carbon TSS Total Suspended Solids VC Vinyl Chloride VFA Volatile Fatty Acid VOC Volatile Organic Compound WQMP Water Quality Monitoring Plan (report) August 2018 Semiannual Water Quality Monitoring Report Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 Joyce Engineering December 2018 I TABLES Table 1 August 2018 Groundwater Elevations Table 2 August 2018 Estimated Hydraulic Gradients and Velocities Table 3 August 2018 Detections Table 4 August 2018 Exceedances Table 5 August 2018 Field Parameters TABLE 1: August 2018 Groundwater Elevations LOCATION TOC ELEVATION (ftmsl) DEPTH TO GROUNDWATER 00 WELL DEPTH 00 GROUNDWATER ELEVATION (ftmsl) MW-7 534.24 24.02 37.32 510.22 MW-8 503.31 3.36 28.00 499.95 MW-9 487.51 9.29 43.00 478.22 MW-10 484.92 9.61 32.90 475.31 MW-11* 478.72 5.15 22.90 473.57 NES-2S 477.20 6.39 24.20 470.81 Notes ftmsl = feet mean sea level *= well unable to be located on 8/16/18, resampled on 10/3/18 Granville County - Oxford Landfill, Unit 2 Joyce Engineering Permit No. 3901 MSWLF-2012 December 2018 TABLE 2: August 2018 Estimated Hydraulic Gradients and Velocities Date of Water Table Measurements: August 14, 2018 SEGMENT HORIZ. HYDRAULIC EFFECTIVE LINEAR FLOW LINE SEGMENT FLOW BEGIN & END GRADIENT CONDUCTIVITY POROSITY VELOCITY LENGTH SEGMENT DIRECTION GW ELEVATION i K n e V (feet) (feet-AMSL) (ft/day) (ft/year) 50470 11 1110 NE 0.0225 4.36E+00 0.31 116 505 l 2 1341 N 0.0261 4.36E+00 0.31 134 470 Average 0.0243 Average 125 Notes: Linear flow velocity: V = Kiln e (modified Darcy equation). Hydraulic conductivity (K) is based on the arithmetic mean of values from slug tests conducted at the facility. Effective porosity (n e) value is estimated at 85% of the laboratory -determined porosity for soil samples from the facility. Refer to Drawing 1 for flow line segments. Granville County - Oxford Landfill, Unit 2 Joyce Engineering Permit No. 3901 MSWLF-2012 December 2018 TABLE 3: August 2018 Detections SAMPLE ID PARAMETER RESULT UNITS MDL MRL NC2L / NC2B DATE 3901-MW7 Barium 3.8 J ug/L 2.5 100 700 8/16/2018 3901-MW7 Manganese 6.7 J ug/L 2.5 50 50 8/16/2018 3901-MW7 Iron 340 ug/L 25 300 300 8/16/2018 3901-MW8 Barium 40.3 J ug/L 2.5 100 700 8/16/2018 3901-MW8 Copper 24.7 ug/L 2.5 10 1000 8/16/2018 3901-MW9 Barium 68.9 J ug/L 2.5 100 700 8/16/2018 3901-MW10 Barium 47.5 J ug/L 2.5 100 700 8/16/2018 3901-MW10 Copper 3.6 J ug/L 2.5 10 1000 8/16/2018 3901-MW10 Vanadium 2.9 J ug/L 2.5 25 0.3 8/16/2018 3901-NES2S Barium 25.8 J ug/L 2.5 100 700 8/16/2018 3901-NES2S Vanadium 2.5 J ug/L 2.5 25 0.3 8/16/2018 3901-SW3 Barium 24.2 J ug/L 2.5 100 NE 8/16/2018 3901-SW3 Vanadium 3.7 J ug/L 2.5 25 NE 8/16/2018 3901-SW4 Barium 38.2 J ug/L 2.5 100 NE 8/16/2018 3901-Field Blank Iron 27.8 J ug/L 25 300 300 8/16/2018 Notes: µg/l = micorgrams per liter MDL = Method detection limit MRL = Method reporting limit NC2L = Groundwater Standard from 15A NCAC 2L.0202 NC2B = Surface Water Standard from 15A NCAC 2B NE= Not Established NC DEQ SW classification: Class C (aquatic life, secondary recreation, fresh water) Granville County - Oxford Landfill, Unit 2 Joyce Engineering Permit No. 3901 MSWLF-2012 December 2018 TABLE 4: August 2018 Exceedances WELL ID PARAMETER RESULT UNITS MDL MRL NC2L/**NC2B DATE 3901-MW7 Iron 340 ug/L 25 300 300.00 8/16/201811 NOTES: µg/l = micorgrams per liter MDL = Method detection limit MRL = Method reporting limit NC 2L = NC Groundwater Standard from 15A NCAC 2L.0202 GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC 2L) GPS = Groundwater Protection Standard as defined by 15A NCAC 13B.1634(g) B= Blank Qualified Granville County- Oxford Unit 2 Landfill Joyce Engineering Permit No. 3901 MSWLF-2012 December 2018 TABLE 5: August 2018 Field Parameters WELL ID PARAMETER RESULT UNITS COLLECT DATE 3901-MW7 pH 6.61 S.0 8/15/2018 3901-MW7 Temperature 17.9 °C 8/15/2018 3901-MW7 Conductivity 364.1 µS/cm 8/15/2018 3901-MW7 Turbidity 4.64 NTU 8/15/2018 3901-MW7 Static Water Level 24.02 ft 8/15/2018 3901-MW7 Well Depth 37.32 ft 8/15/2018 3901-MW8 pH 7.79 S.0 8/16/2018 3901-MW8 Temperature 20.6 °C 8/16/2018 3901-MW8 Conductivity 242.4 µS/cm 8/16/2018 3901-MW8 Turbidity 15.08 ntu 8/16/2018 3901-MW8 Static Water Level 3.36 ft 8/16/2018 3901-MW8 Well Depth 28.00 ft 8/16/2018 3901-MW9 pH 7.18 S.0 8/16/2018 3901-MW9 Temperature 20.4 °C 8/16/2018 3901-MW9 Conductivity 337.5 µS/cm 8/16/2018 3901-MW9 Turbidity 2.10 NTU 8/16/2018 3901-MW9 Static Water Level 9.29 ft 8/16/2018 3901-MW9 Well Depth 43.00 ft 8/16/2018 3901-MW10 pH 5.98 S.0 8/16/2018 3901-MW10 Temperature 22.1 °C 8/16/2018 3901-MW10 Conductivity 151.1 µS/cm 8/16/2018 3901-MW10 Turbidity 23.96 NTU 8/16/2018 3901-MW10 Static Water Level 9.61 ft 8/16/2018 3901-MW10 Well Depth 31.50 ft 8/16/2018 3901-MW11* pH 6.03 S.0 10/3/2018 3901-MW 11 * Temperature 22.0 °C 10/3/2018 3901-MW11* Conductivity 153.0 µS/cm 10/3/2018 3901-MW 11 * Turbidity 13.84 NTU 10/3/2018 3901-MW 11 * Static Water Level 5.15 ft 10/3/2018 3901-MW 11 * Well Depth 22.90 ft 10/3/2018 3901-NES2S pH 6.02 S.0 8/15/2018 3901-NES2S Temperature 28.1 °C 8/15/2018 3901-NES2S Conductivity 246.8 µS/cm 8/15/2018 3901-NES2S Turbidity 17.35 NTU 8/15/2018 3901-NES2S Static Water Level 6.39 ft 8/15/2018 3901-NES2S Well Depth 24.20 ft 8/15/2018 3901-SW3 pH 8.00 S.0 8/16/2018 3901-SW3 Temperature 24.0 °C 8/16/2018 3901-SW3 Conductivity 76.4 µS/cm 8/16/2018 3901-SW3 Turbidity 22.90 NTU 8/16/2018 3901-SW4 pH 6.58 S.0 8/16/2018 3901-SW4 Temperature 22.0 °C 8/16/2018 3901-SW4 Conductivity 126.7 µS/cm 8/16/2018 3901-SW4 Turbidity 15.00 NTU 8/16/2018 Notes: mg/l = milligrams per liter. °C= degrees Centigrade. S.U.= Standard Units. µg/l = micrograms per liter. µS/cm = microSemens per centimeter. NTU = Nephelometric Turbidity Units. ft = feet. *= well unable to be located on 8/16/18- resampled on 10/3/18 Granville County- Oxford Unit 2 Landfill Permit No. 3901 MSWLF-2012 Joyce Engineering December 2018 FIGURE Figure 1 Site Location Map (USGS Topographic Map) • _..N6y9Yg0k. P a T2 9 NUADRANGLES TEU.S. .S. 5 MI T TOPO RAPHIC ti'� �`��FOR SATTERWHITE, STOVALL,�a �BEREA AND OXFORD, NORTH CAROLINA. ; S� OXFORD LANDFILL Vr� DESIGNED RWH PROJECT NO. GRANVILLE COUNTY, NORTH CAROLINA AJLI i `L DRACHECKED ce SCALE 660 EM31"EERIIV1:3 APPROVED GVB SITE LOCATION MAP DATE 10/15/15 1" = 2000' DRAWING NO. 2211 W. MEADOWVIEW ROAD GREENSBORO, NC 27407 0 2018 Joyce Engineering, Inc. 1 PHONE: (336) 323-0092 All dgh. reserved. NC CORP LIC: C-0782 L\GranAI.\dwg\0zfa d\, 2014 site Location Mw.dwg DRA WING Drawing ] Groundwater Potentiometric Surface Map 9 4"— SW-4 — ( I I NES-1D (ABANDONED) \ \ // �? I I I I I I / \�\ �\ `\'� \ l \ 1 NM4:8( I l �� AREA SURVEYED WITHIN 1S /NS THIS BOUNDARY CONSISTS \ 475.31 \ 1 1 I \ \ \ J I I NES-2;S OF GROUND SURVEY DATED MARCH 2013470,81 \ i -2D — 480— 480 480J �\ / 500 \ \'IF < \ ) I I \ 1 1 R �\ cs ACCESS ROAD �498.36 Lo c9 _ \ MW-5R — — — _ -- — _ -------_ ---� I 467.487 — �_� MW 5 kr I APPROXIMATE MSW LANDFILL V A G �-4 _ �� I S -2 I � LIMITS OF WASTE \ \ Y MW-9 �510���478.22 53� _ \ ),, 1�1 W 11 /NS MW-6R '498.60 vv �/ / o \ \ o -6 j j � 1� � � I I I I . , i i UNIT 2 PHASE 1 ol APPROXIMATE MSW LANDFILL I I \ 1 1 l \ LIMITS OF WASTE O � I I I � / `I so0 ��� I III II IIII liilII l I►I I cn GP-3 C O UNIT 1 N �o ACCES L0 \,\ / — r CTI, l i I _ I 600 f7 G -2 LEGEND /i \ / EXISTING 10 TOPOGRAPHIC CONTOUR l / / MW-12 / NS \ P-21 EXISTING 2 TOPOGRAPHIC CONTOUR / 484.15 \ EXISTING ROAD '/490 GROUNDWATER SURFACE CONTOUR -� FEET ABOVE MEAN SEA LEVEL AMSL MW- I I (ABANDONED) Mvv-2 �� \ \ �� / GROUNDWATER FLOW DIRECTION Oy \\ 504.44 GROUNDWATER MONITORING WELL LOCATION - I - AND IDENTIFICATION ON 1 SURFACE MONITORING POINT LOCATION AND 1 O �530—_ ` I / IDENTIFICATION y / AREA SURVEYED WITHIN -g / ; i� SEGMENT USED FOR GRADIENT CALCULATION \ �, THIS BOUNDARY CONSISTS 2 OF GROUND SURVEY DATED JUNE 2013 / �— -0 F= 12 FLOW PATH LENGTH 510 I E 506.3 I 7y 1,110 L F WON ` GP-1-0 I Z� � � o\ Oki50 I 51p \ II I �� °� l i / O 1,341 LF o y\ 0 SW-1 O _ v AOy —� SEDIMENT I \ NOTES BASIN SB-1 y I V 1. TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET 0 \ / a0� O 2. GROUNDWATER CONTOUR INTERVAL = 10 FEET y ,� I co \ 3 GROUNDWATER CONTOURS BASED ON LINEAR \ �10 i �500 co w A. \ �y MW-8"' Q \ 499.95 � hph I r \ I I \ INTERPOLATION BETWEEN AND EXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, I AND KNOWN FIELD CONDITIONS. THEREFORE, - MW-7 GROUNDWATER CONTOURS MAY NOT REFLECT 510.22 a 1 ACTUAL GROUNDWATER CONDITIONS. Oy 4. STATIC WATER LEVELS MEASURED ON 08/14/18. 1 \ \ \ \ \ GRAPHIC SCALE \ 0 ny 59-- 100 200 (FEET) ('y w Z) co co LL O 0 of O U w 0 z Q cn z O cn w of w Q 0 00 Li cn = m Y > > S U C� o wN Lu 0 0 w w > U � 0� z z cn¢w� Y O U 0� W co.� oQ D D U Q D OR V� Q OR� z O J� >� W > (" or z WO N U M Q��U W O c''� � ` ���n W u z w O Z �w 0U W N U' w z a w U LL Q z_ � J CU O 0� O� 00 Q O U Lu 2N O Z z z LU 1-- o L.L Q O 0� LL Lu x O a 3: 0 z Z) O PROJECT NO 2180175 SCALE AS SHOWN DRAWING NO. 1 0 co J 0 co J 00 co d Q 0 CL co w 2 0 x O M 0 J APPENDICES Appendix 1 Well Construction Details Appendix 2 Laboratory Analytical Reports and Field Data Logs Appendix 3 Historical Data Tables Appendix I Well Construction Details TABLE Al-01: Well Construction Details AR TD TD TOC Top Top Bottom Bottom Date GS Elev. TOC Elev. Screened DTW Well ID Northing Easting (Bedrock) (Boring) (Well) Stick-up Screen Screen Screen Screen Comments Installed (Ft-AMSL) (Ft-AMSL) (Ft-BGS) (Ft-BGS) (Ft-BTOC) (Ft-AGS) (Ft-BGS) (Ft-BTOC) (Ft-BGS) (Ft-BTOC) Lithology (Ft-BTOC) MW-7 07/28/08 953292.1160 2112043.4480 531.24 534.24 34.50 34.50 37.50 3.00 19.50 22.50 34.50 37.50 Saprolite 23.91 Background Well Units 1 & 2 (former P-2) 05/05/12 MW-8 953360.2000 2111527.6910 500.57 503.31 1.00 25.00 20.00 2.74 10.00 12.74 20.00 22.74 Bedrock Artesian Unit 2 Compliance 07/18/12 485.05 20.00 22.46 MW-9 10/06/08 954799.7410 2112842.3890 487.51 1.50 40.00 43.00 2.46 40.00 42.46 Bedrock 8.30 Unit 2 Compliance (former P-9) 2112571.1750 MW-10 10/02/08 955136.0000 481.81 484.92 6.00 30.00 32.90 3.11 15.00 18.11 30.00 33.11 Bedrock 8.15 Unit 2 Compliance (former P-10) MW-11 10/05/08 954795.8510 2111957.0410 476.43 478.72 6.00 20.00 22.90 2.30 5.00 7.30 20.00 22.30 Bedrock 6.80 Unit 2 Compliance (former P-13) MW-12 08/01/08 954077.4350 2112567.4920 519.29 521.30 31.00 50.00 52.30 2.00 40.00 42.00 50.00 52.00 Bedrock 30.75 Unit 2 Background, not sampled (former P-21) NES-2S 05/01/04 955091.2902 2111945.3411 474.53 477.20 9.00 21.50 24.17 2.67 11.00 13.67 21.00 23.67 Saprolite 9.14 Unit 2 Compliance and 69.21 Unit 1 Perfomance NES-21) 05/01/04 955081.7805 2111946.7398 474.72 477.43 21.50 66.50 2.71 51.00 53.71 66.00 68.71 Bedrock 5.00 Unit 1 Sentinel, not sampled for Unit 2 NOTES: AR = Auger Refusal (Estimate of depth to bedrock). TD = Total Depth (of boring or well/piezometer). TOC = Top of Casing. GS = Ground Surface. DTW = Depth to Water (as measured on 11/20/08). Ft-BGS = Feet below ground surface. Ft-AGS = Feet above ground surface. Ft-BTOC = Feet below TOC. Ft-AMSL = Feet above mean sea level. Granville Co., Oxford Landfill, Unit 2 Permit # 3901-MSWLF-2012 Joyce Engineering Appendix 2 Laboratory Analytical Reports and Field Data Logs aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 August 30, 2018 Mr. Van Burbach Joyce Engineering -NC 2211 West Meadowview Rd Boone Bldg, Suite 101 Greensboro, NC 27407 RE: Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on August 17, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ��i Flo _ _.1I , .�: Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Mr. Daniel Girdner, LaBella Associates, D.P.C. Miguel Vazquez, Joyce Engineering Rochelle mesubed, Joyce Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 29 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 29 aceAnalytical —pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 Lab ID Sample ID Matrix Date Collected Date Received 92396257001 3901-MW8 Water 08/16/18 12:04 08/17/18 09:37 92396257002 3901-MW9 Water 08/16/18 15:57 08/17/18 09:37 92396257003 3901-MW10 Water 08/16/18 15:46 08/17/18 09:37 92396257004 3901-SW3 Water 08/16/18 12:12 08/17/18 09:37 92396257005 3901-SW4 Water 08/16/18 10:40 08/17/18 09:37 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 29 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Oxford Compliance Unit 2 92396257 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92396257001 3901-MW8 EPA 601 OD IDS 14 PASI-A EPA6020B JMW1 1 PASI-A EPA 8260E CAH 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92396257002 3901-MW9 EPA 601 OD DS 14 PASI-A EPA6020B JMW1 1 PASI-A EPA 8260E CAH 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92396257003 3901-MW10 EPA 601 OD IDS 14 PASI-A EPA6020B JMW1 1 PASI-A EPA 8260E CAH 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92396257004 3901-SW3 EPA 601 OD IDS 14 PASI-A EPA6020B JMW1 1 PASI-A EPA 8260E CAH 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92396257005 3901-SW4 EPA 601 OD IDS 14 PASI-A EPA6020B JMW1 1 PASI-A EPA 8260E CAH 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 29 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Oxford Compliance Unit 2 92396257 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92396257001 3901-MW8 EPA 601 OD Barium 40.3J ug/L 100 08/25/18 21:50 EPA 601 OD Copper 24.7 ug/L 10.0 08/25/18 21:50 92396257002 3901-MW9 EPA 601 OD Barium 68.9J ug/L 100 08/25/18 22:03 92396257003 3901-MW10 EPA 601 OD Barium 47.5J ug/L 100 08/25/18 22:12 EPA 601 OD Copper 3.6J ug/L 10.0 08/25/18 22:12 EPA 601 OD Vanadium 2.9J ug/L 25.0 08/25/18 22:12 92396257004 3901-SW3 EPA 601 OD Barium 24.2J ug/L 100 08/25/18 22:15 EPA 601 OD Vanadium 3.7J ug/L 25.0 08/25/18 22:15 92396257005 3901-SW4 EPA 601 OD Barium 38.2J ug/L 100 08/25/18 22:18 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 29 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 Sample: 3901-MW8 Lab ID: 92396257001 Collected: 08/16/18 12:04 Received: 08/17/18 09:37 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 08/30/2018 12:03 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 6.0 3.9 1 08/25/18 07:40 08/25/18 21:50 7440-36-0 ND ug/L 10.0 5.0 1 08/25/18 07:40 08/25/18 21:50 7440-38-2 40.3J ug/L 100 2.5 1 08/25/18 07:40 08/25/18 21:50 7440-39-3 ND ug/L 1.0 0.50 1 08/25/18 07:40 08/25/18 21:50 7440-41-7 ND ug/L 1.0 0.50 1 08/25/18 07:40 08/25/18 21:50 7440-43-9 ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 21:50 7440-47-3 ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 21:50 7440-48-4 24.7 ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 21:50 7440-50-8 ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 21:50 7439-92-1 ND ug/L 50.0 2.5 1 08/25/18 07:40 08/25/18 21:50 7440-02-0 ND ug/L 10.0 5.0 1 08/25/18 07:40 08/25/18 21:50 7782-49-2 ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 21:50 7440-22-4 ND ug/L 25.0 2.5 1 08/25/18 07:40 08/25/18 21:50 7440-62-2 ND ug/L 10.0 5.0 1 08/25/18 07:40 08/25/18 21:50 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 5.5 0.020 1 08/18/18 06:19 08/29/18 16:47 7440-28-0 Analytical Method: EPA 8260E ND ug/L 100 10.0 1 08/28/1817:17 67-64-1 ND ug/L 200 1.9 1 08/28/1817:17 107-13-1 ND ug/L 1.0 0.25 1 08/28/1817:17 71-43-2 ND ug/L 3.0 0.17 1 08/28/1817:17 74-97-5 ND ug/L 1.0 0.18 1 08/28/1817:17 75-27-4 ND ug/L 3.0 0.26 1 08/28/1817:17 75-25-2 ND ug/L 10.0 0.29 1 08/28/1817:17 74-83-9 ND ug/L 100 0.96 1 08/28/1817:17 78-93-3 ND ug/L 100 1.2 1 08/28/1817:17 75-15-0 ND ug/L 1.0 0.25 1 08/28/1817:17 56-23-5 ND ug/L 3.0 0.23 1 08/28/1817:17 108-90-7 ND ug/L 10.0 0.54 1 08/28/1817:17 75-00-3 ND ug/L 5.0 0.14 1 08/28/1817:17 67-66-3 ND ug/L 1.0 0.11 1 08/28/1817:17 74-87-3 ND ug/L 13.0 2.0 1 08/28/1817:17 96-12-8 ND ug/L 3.0 0.21 1 08/28/1817:17 124-48-1 ND ug/L 1.0 0.27 1 08/28/1817:17 106-93-4 ND ug/L 10.0 0.21 1 08/28/1817:17 74-95-3 ND ug/L 5.0 0.30 1 08/28/1817:17 95-50-1 ND ug/L 1.0 0.33 1 08/28/1817:17 106-46-7 ND ug/L 100 1.0 1 08/28/1817:17 110-57-6 ND ug/L 5.0 0.32 1 08/28/1817:17 75-34-3 ND ug/L 1.0 0.24 1 08/28/1817:17 107-06-2 ND ug/L 5.0 0.56 1 08/28/1817:17 75-35-4 ND ug/L 5.0 0.19 1 08/28/1817:17 156-59-2 ND ug/L 5.0 0.49 1 08/28/1817:17 156-60-5 ND ug/L 1.0 0.27 1 08/28/1817:17 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 29 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 Sample: 3901-MW8 Lab ID: 92396257001 Collected: 08/16/18 12:04 Received: 08/17/18 09:37 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/30/2018 12:03 PM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 100 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 3.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 1.0 ND ug/L 5.0 96 % 70-130 100 % 70-130 99 % 70-130 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 99 % 50-150 115 % 50-150 0.13 1 08/28/18 17:17 10061-01-5 0.26 1 08/28/18 17:17 10061-02-6 0.30 1 08/28/18 17:17 100-41-4 0.46 1 08/28/18 17:17 591-78-6 0.32 1 08/28/18 17:17 74-88-4 0.97 1 08/28/18 17:17 75-09-2 0.33 1 08/28/18 17:17 108-10-1 0.26 1 08/28/18 17:17 100-42-5 0.33 1 08/28/18 17:17 630-20-6 0.40 1 08/28/18 17:17 79-34-5 0.46 1 08/28/18 17:17 127-18-4 0.26 1 08/28/18 17:17 108-88-3 0.48 1 08/28/18 17:17 71-55-6 0.29 1 08/28/18 17:17 79-00-5 0.47 1 08/28/18 17:17 79-01-6 0.20 1 08/28/18 17:17 75-69-4 0.41 1 08/28/18 17:17 96-18-4 0.35 1 08/28/18 17:17 108-05-4 0.62 1 08/28/18 17:17 75-01-4 0.66 1 08/28/18 17:17 1330-20-7 1 08/28/18 17:17 460-00-4 1 08/28/18 17:17 17060-07-0 1 08/28/18 17:17 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 08/23/18 19:02 123-91-1 08/23/18 19:02 17060-07-0 08/23/18 19:02 2037-26-5 Page 7 of 29 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 Sample: 3901-MW9 Lab ID: 92396257002 Collected: 08/16/18 15:57 Received: 08/17/18 09:37 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 08/30/2018 12:03 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 6.0 3.9 1 08/25/18 07:40 08/25/18 22:03 7440-36-0 ND ug/L 10.0 5.0 1 08/25/18 07:40 08/25/18 22:03 7440-38-2 68.9J ug/L 100 2.5 1 08/25/18 07:40 08/25/18 22:03 7440-39-3 ND ug/L 1.0 0.50 1 08/25/18 07:40 08/25/18 22:03 7440-41-7 ND ug/L 1.0 0.50 1 08/25/18 07:40 08/25/18 22:03 7440-43-9 ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:03 7440-47-3 ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:03 7440-48-4 ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:03 7440-50-8 ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:03 7439-92-1 ND ug/L 50.0 2.5 1 08/25/18 07:40 08/25/18 22:03 7440-02-0 ND ug/L 10.0 5.0 1 08/25/18 07:40 08/25/18 22:03 7782-49-2 ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:03 7440-22-4 ND ug/L 25.0 2.5 1 08/25/18 07:40 08/25/18 22:03 7440-62-2 ND ug/L 10.0 5.0 1 08/25/18 07:40 08/25/18 22:03 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 5.5 0.020 1 08/18/18 06:19 08/29/18 16:57 7440-28-0 Analytical Method: EPA 8260E ND ug/L 100 10.0 1 08/28/1817:33 67-64-1 ND ug/L 200 1.9 1 08/28/1817:33 107-13-1 ND ug/L 1.0 0.25 1 08/28/1817:33 71-43-2 ND ug/L 3.0 0.17 1 08/28/1817:33 74-97-5 ND ug/L 1.0 0.18 1 08/28/1817:33 75-27-4 ND ug/L 3.0 0.26 1 08/28/1817:33 75-25-2 ND ug/L 10.0 0.29 1 08/28/1817:33 74-83-9 ND ug/L 100 0.96 1 08/28/1817:33 78-93-3 ND ug/L 100 1.2 1 08/28/1817:33 75-15-0 ND ug/L 1.0 0.25 1 08/28/1817:33 56-23-5 ND ug/L 3.0 0.23 1 08/28/1817:33 108-90-7 ND ug/L 10.0 0.54 1 08/28/1817:33 75-00-3 ND ug/L 5.0 0.14 1 08/28/1817:33 67-66-3 ND ug/L 1.0 0.11 1 08/28/1817:33 74-87-3 ND ug/L 13.0 2.0 1 08/28/1817:33 96-12-8 ND ug/L 3.0 0.21 1 08/28/1817:33 124-48-1 ND ug/L 1.0 0.27 1 08/28/1817:33 106-93-4 ND ug/L 10.0 0.21 1 08/28/1817:33 74-95-3 ND ug/L 5.0 0.30 1 08/28/1817:33 95-50-1 ND ug/L 1.0 0.33 1 08/28/1817:33 106-46-7 ND ug/L 100 1.0 1 08/28/1817:33 110-57-6 ND ug/L 5.0 0.32 1 08/28/1817:33 75-34-3 ND ug/L 1.0 0.24 1 08/28/1817:33 107-06-2 ND ug/L 5.0 0.56 1 08/28/1817:33 75-35-4 ND ug/L 5.0 0.19 1 08/28/1817:33 156-59-2 ND ug/L 5.0 0.49 1 08/28/1817:33 156-60-5 ND ug/L 1.0 0.27 1 08/28/1817:33 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 29 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 Sample: 3901-MW9 Lab ID: 92396257002 Collected: 08/16/18 15:57 Received: 08/17/18 09:37 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/30/2018 12:03 PM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 100 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 3.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 1.0 ND ug/L 5.0 96 % 70-130 102 % 70-130 97 % 70-130 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 96 % 50-150 113 % 50-150 0.13 1 08/28/18 17:33 10061-01-5 0.26 1 08/28/18 17:33 10061-02-6 0.30 1 08/28/18 17:33 100-41-4 0.46 1 08/28/18 17:33 591-78-6 0.32 1 08/28/18 17:33 74-88-4 0.97 1 08/28/18 17:33 75-09-2 0.33 1 08/28/18 17:33 108-10-1 0.26 1 08/28/18 17:33 100-42-5 0.33 1 08/28/18 17:33 630-20-6 0.40 1 08/28/18 17:33 79-34-5 0.46 1 08/28/18 17:33 127-18-4 0.26 1 08/28/18 17:33 108-88-3 0.48 1 08/28/18 17:33 71-55-6 0.29 1 08/28/18 17:33 79-00-5 0.47 1 08/28/18 17:33 79-01-6 0.20 1 08/28/18 17:33 75-69-4 0.41 1 08/28/18 17:33 96-18-4 0.35 1 08/28/18 17:33 108-05-4 0.62 1 08/28/18 17:33 75-01-4 0.66 1 08/28/18 17:33 1330-20-7 1 08/28/18 17:33 460-00-4 1 08/28/18 17:33 17060-07-0 1 08/28/18 17:33 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 08/23/18 19:22 123-91-1 08/23/18 19:22 17060-07-0 08/23/18 19:22 2037-26-5 Page 9 of 29 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 Sample: 3901-MW10 Lab ID: 92396257003 Collected: 08/16/18 15:46 Received: 08/17/18 09:37 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 08/30/2018 12:03 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 6.0 3.9 1 08/25/18 07:40 08/25/18 22:12 7440-36-0 ND ug/L 10.0 5.0 1 08/25/18 07:40 08/25/18 22:12 7440-38-2 47.5J ug/L 100 2.5 1 08/25/18 07:40 08/25/18 22:12 7440-39-3 ND ug/L 1.0 0.50 1 08/25/18 07:40 08/25/18 22:12 7440-41-7 ND ug/L 1.0 0.50 1 08/25/18 07:40 08/25/18 22:12 7440-43-9 ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:12 7440-47-3 ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:12 7440-48-4 3.6J ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:12 7440-50-8 ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:12 7439-92-1 ND ug/L 50.0 2.5 1 08/25/18 07:40 08/25/18 22:12 7440-02-0 ND ug/L 10.0 5.0 1 08/25/18 07:40 08/25/18 22:12 7782-49-2 ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:12 7440-22-4 2.9J ug/L 25.0 2.5 1 08/25/18 07:40 08/25/18 22:12 7440-62-2 ND ug/L 10.0 5.0 1 08/25/18 07:40 08/25/18 22:12 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 5.5 0.020 1 08/18/18 06:19 08/29/18 17:00 7440-28-0 Analytical Method: EPA 8260E ND ug/L 100 10.0 1 08/28/1817:50 67-64-1 ND ug/L 200 1.9 1 08/28/1817:50 107-13-1 ND ug/L 1.0 0.25 1 08/28/1817:50 71-43-2 ND ug/L 3.0 0.17 1 08/28/1817:50 74-97-5 ND ug/L 1.0 0.18 1 08/28/1817:50 75-27-4 ND ug/L 3.0 0.26 1 08/28/1817:50 75-25-2 ND ug/L 10.0 0.29 1 08/28/1817:50 74-83-9 ND ug/L 100 0.96 1 08/28/1817:50 78-93-3 ND ug/L 100 1.2 1 08/28/1817:50 75-15-0 ND ug/L 1.0 0.25 1 08/28/1817:50 56-23-5 ND ug/L 3.0 0.23 1 08/28/1817:50 108-90-7 ND ug/L 10.0 0.54 1 08/28/1817:50 75-00-3 ND ug/L 5.0 0.14 1 08/28/1817:50 67-66-3 ND ug/L 1.0 0.11 1 08/28/1817:50 74-87-3 ND ug/L 13.0 2.0 1 08/28/1817:50 96-12-8 ND ug/L 3.0 0.21 1 08/28/1817:50 124-48-1 ND ug/L 1.0 0.27 1 08/28/1817:50 106-93-4 ND ug/L 10.0 0.21 1 08/28/1817:50 74-95-3 ND ug/L 5.0 0.30 1 08/28/1817:50 95-50-1 ND ug/L 1.0 0.33 1 08/28/1817:50 106-46-7 ND ug/L 100 1.0 1 08/28/1817:50 110-57-6 ND ug/L 5.0 0.32 1 08/28/1817:50 75-34-3 ND ug/L 1.0 0.24 1 08/28/1817:50 107-06-2 ND ug/L 5.0 0.56 1 08/28/1817:50 75-35-4 ND ug/L 5.0 0.19 1 08/28/1817:50 156-59-2 ND ug/L 5.0 0.49 1 08/28/1817:50 156-60-5 ND ug/L 1.0 0.27 1 08/28/1817:50 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. M1 Page 10 of 29 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 Sample: 3901-MW10 Lab ID: 92396257003 Collected: 08/16/18 15:46 Received: 08/17/18 09:37 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/30/2018 12:03 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.13 1 08/28/1817:50 10061-01-5 ND ug/L 1.0 0.26 1 08/28/1817:50 10061-02-6 ND ug/L 1.0 0.30 1 08/28/1817:50 100-41-4 ND ug/L 50.0 0.46 1 08/28/1817:50 591-78-6 ND ug/L 10.0 0.32 1 08/28/1817:50 74-88-4 ND ug/L 1.0 0.97 1 08/28/1817:50 75-09-2 ND ug/L 100 0.33 1 08/28/1817:50 108-10-1 ND ug/L 1.0 0.26 1 08/28/1817:50 100-42-5 ND ug/L 5.0 0.33 1 08/28/1817:50 630-20-6 ND ug/L 3.0 0.40 1 08/28/1817:50 79-34-5 ND ug/L 1.0 0.46 1 08/28/1817:50 127-18-4 ND ug/L 1.0 0.26 1 08/28/1817:50 108-88-3 ND ug/L 1.0 0.48 1 08/28/1817:50 71-55-6 ND ug/L 1.0 0.29 1 08/28/1817:50 79-00-5 ND ug/L 1.0 0.47 1 08/28/1817:50 79-01-6 ND ug/L 1.0 0.20 1 08/28/1817:50 75-69-4 ND ug/L 1.0 0.41 1 08/28/1817:50 96-18-4 ND ug/L 50.0 0.35 1 08/28/1817:50 108-05-4 ND ug/L 1.0 0.62 1 08/28/1817:50 75-01-4 ND ug/L 5.0 0.66 1 08/28/1817:50 1330-20-7 94 % 70-130 1 08/28/1817:50 460-00-4 100 % 70-130 1 08/28/1817:50 17060-07-0 98 % 70-130 1 08/28/1817:50 2037-26-5 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 1.9 1 08/23/1819:41 123-91-1 98 % 50-150 1 08/23/1819:41 17060-07-0 114 % 50-150 1 08/23/1819:41 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. M1 M1 Page 11 of 29 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 Sample: 3901-SW3 Lab ID: 92396257004 Collected: 08/16/18 12:12 Received: 08/17/18 09:37 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 6.0 3.9 1 08/25/18 07:40 08/25/18 22:15 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 08/25/18 07:40 08/25/18 22:15 7440-38-2 Barium 24.2J ug/L 100 2.5 1 08/25/18 07:40 08/25/18 22:15 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 08/25/18 07:40 08/25/18 22:15 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 08/25/18 07:40 08/25/18 22:15 7440-43-9 Chromium ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:15 7440-47-3 Cobalt ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:15 7440-48-4 Copper ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:15 7440-50-8 Lead ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:15 7439-92-1 Nickel ND ug/L 50.0 2.5 1 08/25/18 07:40 08/25/18 22:15 7440-02-0 Selenium ND ug/L 10.0 5.0 1 08/25/18 07:40 08/25/18 22:15 7782-49-2 Silver ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:15 7440-22-4 Vanadium 3.7J ug/L 25.0 2.5 1 08/25/18 07:40 08/25/18 22:15 7440-62-2 Zinc ND ug/L 10.0 5.0 1 08/25/18 07:40 08/25/18 22:15 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 5.5 0.020 1 08/18/18 06:19 08/29/18 17:02 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 100 10.0 1 08/28/18 18:06 67-64-1 Acrylonitrile ND ug/L 200 1.9 1 08/28/18 18:06 107-13-1 Benzene ND ug/L 1.0 0.25 1 08/28/18 18:06 71-43-2 Bromochloromethane ND ug/L 3.0 0.17 1 08/28/18 18:06 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 08/28/18 18:06 75-27-4 Bromoform ND ug/L 3.0 0.26 1 08/28/18 18:06 75-25-2 Bromomethane ND ug/L 10.0 0.29 1 08/28/18 18:06 74-83-9 2-Butanone (MEK) ND ug/L 100 0.96 1 08/28/18 18:06 78-93-3 Carbon disulfide ND ug/L 100 1.2 1 08/28/18 18:06 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 08/28/18 18:06 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 08/28/18 18:06 108-90-7 Chloroethane ND ug/L 10.0 0.54 1 08/28/18 18:06 75-00-3 Chloroform ND ug/L 5.0 0.14 1 08/28/18 18:06 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 08/28/18 18:06 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 13.0 2.0 1 08/28/18 18:06 96-12-8 Dibromochloromethane ND ug/L 3.0 0.21 1 08/28/18 18:06 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 08/28/18 18:06 106-93-4 Dibromomethane ND ug/L 10.0 0.21 1 08/28/18 18:06 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.30 1 08/28/18 18:06 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 08/28/18 18:06 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 100 1.0 1 08/28/18 18:06 110-57-6 1,1-Dichloroethane ND ug/L 5.0 0.32 1 08/28/18 18:06 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 08/28/18 18:06 107-06-2 1,1-Dichloroethene ND ug/L 5.0 0.56 1 08/28/18 18:06 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 0.19 1 08/28/18 18:06 156-59-2 trans-1,2-Dichloroethene ND ug/L 5.0 0.49 1 08/28/18 18:06 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 08/28/18 18:06 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/30/2018 12:03 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 29 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 Sample: 3901-SW3 Lab ID: 92396257004 Collected: 08/16/18 12:12 Received: 08/17/18 09:37 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/30/2018 12:03 PM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 100 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 3.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 1.0 ND ug/L 5.0 95 % 70-130 103 % 70-130 99 % 70-130 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 98 % 50-150 114 % 50-150 0.13 1 08/28/18 18:06 10061-01-5 0.26 1 08/28/18 18:06 10061-02-6 0.30 1 08/28/18 18:06 100-41-4 0.46 1 08/28/18 18:06 591-78-6 0.32 1 08/28/18 18:06 74-88-4 0.97 1 08/28/18 18:06 75-09-2 0.33 1 08/28/18 18:06 108-10-1 0.26 1 08/28/18 18:06 100-42-5 0.33 1 08/28/18 18:06 630-20-6 0.40 1 08/28/18 18:06 79-34-5 0.46 1 08/28/18 18:06 127-18-4 0.26 1 08/28/18 18:06 108-88-3 0.48 1 08/28/18 18:06 71-55-6 0.29 1 08/28/18 18:06 79-00-5 0.47 1 08/28/18 18:06 79-01-6 0.20 1 08/28/18 18:06 75-69-4 0.41 1 08/28/18 18:06 96-18-4 0.35 1 08/28/18 18:06 108-05-4 0.62 1 08/28/18 18:06 75-01-4 0.66 1 08/28/18 18:06 1330-20-7 1 08/28/18 18:06 460-00-4 1 08/28/18 18:06 17060-07-0 1 08/28/18 18:06 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 08/23/18 20:01 123-91-1 08/23/18 20:01 17060-07-0 08/23/18 20:01 2037-26-5 Page 13 of 29 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 Sample: 3901-SW4 Lab ID: 92396257005 Collected: 08/16/18 10:40 Received: 08/17/18 09:37 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 6.0 3.9 1 08/25/18 07:40 08/25/18 22:18 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 08/25/18 07:40 08/25/18 22:18 7440-38-2 Barium 38.2J ug/L 100 2.5 1 08/25/18 07:40 08/25/18 22:18 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 08/25/18 07:40 08/25/18 22:18 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 08/25/18 07:40 08/25/18 22:18 7440-43-9 Chromium ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:18 7440-47-3 Cobalt ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:18 7440-48-4 Copper ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:18 7440-50-8 Lead ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:18 7439-92-1 Nickel ND ug/L 50.0 2.5 1 08/25/18 07:40 08/25/18 22:18 7440-02-0 Selenium ND ug/L 10.0 5.0 1 08/25/18 07:40 08/25/18 22:18 7782-49-2 Silver ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:18 7440-22-4 Vanadium ND ug/L 25.0 2.5 1 08/25/18 07:40 08/25/18 22:18 7440-62-2 Zinc ND ug/L 10.0 5.0 1 08/25/18 07:40 08/25/18 22:18 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 5.5 0.020 1 08/18/18 06:19 08/29/18 17:04 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 100 10.0 1 08/28/18 18:22 67-64-1 Acrylonitrile ND ug/L 200 1.9 1 08/28/18 18:22 107-13-1 Benzene ND ug/L 1.0 0.25 1 08/28/18 18:22 71-43-2 Bromochloromethane ND ug/L 3.0 0.17 1 08/28/18 18:22 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 08/28/18 18:22 75-27-4 Bromoform ND ug/L 3.0 0.26 1 08/28/18 18:22 75-25-2 Bromomethane ND ug/L 10.0 0.29 1 08/28/18 18:22 74-83-9 2-Butanone (MEK) ND ug/L 100 0.96 1 08/28/18 18:22 78-93-3 Carbon disulfide ND ug/L 100 1.2 1 08/28/18 18:22 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 08/28/18 18:22 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 08/28/18 18:22 108-90-7 Chloroethane ND ug/L 10.0 0.54 1 08/28/18 18:22 75-00-3 Chloroform ND ug/L 5.0 0.14 1 08/28/18 18:22 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 08/28/18 18:22 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 13.0 2.0 1 08/28/18 18:22 96-12-8 Dibromochloromethane ND ug/L 3.0 0.21 1 08/28/18 18:22 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 08/28/18 18:22 106-93-4 Dibromomethane ND ug/L 10.0 0.21 1 08/28/18 18:22 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.30 1 08/28/18 18:22 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 08/28/18 18:22 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 100 1.0 1 08/28/18 18:22 110-57-6 1,1-Dichloroethane ND ug/L 5.0 0.32 1 08/28/18 18:22 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 08/28/18 18:22 107-06-2 1,1-Dichloroethene ND ug/L 5.0 0.56 1 08/28/18 18:22 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 0.19 1 08/28/18 18:22 156-59-2 trans-1,2-Dichloroethene ND ug/L 5.0 0.49 1 08/28/18 18:22 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 08/28/18 18:22 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/30/2018 12:03 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 29 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 Sample: 3901-SW4 Lab ID: 92396257005 Collected: 08/16/18 10:40 Received: 08/17/18 09:37 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/30/2018 12:03 PM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 100 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 3.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 1.0 ND ug/L 5.0 97 % 70-130 101 % 70-130 99 % 70-130 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 95 % 50-150 112 % 50-150 0.13 1 08/28/18 18:22 10061-01-5 0.26 1 08/28/18 18:22 10061-02-6 0.30 1 08/28/18 18:22 100-41-4 0.46 1 08/28/18 18:22 591-78-6 0.32 1 08/28/18 18:22 74-88-4 0.97 1 08/28/18 18:22 75-09-2 0.33 1 08/28/18 18:22 108-10-1 0.26 1 08/28/18 18:22 100-42-5 0.33 1 08/28/18 18:22 630-20-6 0.40 1 08/28/18 18:22 79-34-5 0.46 1 08/28/18 18:22 127-18-4 0.26 1 08/28/18 18:22 108-88-3 0.48 1 08/28/18 18:22 71-55-6 0.29 1 08/28/18 18:22 79-00-5 0.47 1 08/28/18 18:22 79-01-6 0.20 1 08/28/18 18:22 75-69-4 0.41 1 08/28/18 18:22 96-18-4 0.35 1 08/28/18 18:22 108-05-4 0.62 1 08/28/18 18:22 75-01-4 0.66 1 08/28/18 18:22 1330-20-7 1 08/28/18 18:22 460-00-4 1 08/28/18 18:22 17060-07-0 1 08/28/18 18:22 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 08/23/18 20:20 123-91-1 08/23/18 20:20 17060-07-0 08/23/18 20:20 2037-26-5 Page 15 of 29 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 QC Batch: 427103 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92396257001, 92396257002, 92396257003, 92396257004, 92396257005 METHOD BLANK: 2359969 Matrix: Water Associated Lab Samples: 92396257001, 92396257002, 92396257003, 92396257004, 92396257005 Blank Reporting Parameter Units Result Limit MDL Analyzed Antimony ug/L ND 6.0 3.9 08/25/18 21:44 Arsenic ug/L ND 10.0 5.0 08/25/18 21:44 Barium ug/L ND 100 2.5 08/25/18 21:44 Beryllium ug/L ND 1.0 0.50 08/25/18 21:44 Cadmium ug/L ND 1.0 0.50 08/25/18 21:44 Chromium ug/L ND 10.0 2.5 08/25/18 21:44 Cobalt ug/L ND 10.0 2.5 08/25/18 21:44 Copper ug/L ND 10.0 2.5 08/25/18 21:44 Lead ug/L ND 10.0 2.5 08/25/18 21:44 Nickel ug/L ND 50.0 2.5 08/25/18 21:44 Selenium ug/L ND 10.0 5.0 08/25/18 21:44 Silver ug/L ND 10.0 2.5 08/25/18 21:44 Vanadium ug/L ND 25.0 2.5 08/25/18 21:44 Zinc ug/L ND 10.0 5.0 08/25/18 21:44 LABORATORY CONTROL SAMPLE: Parameter 2359970 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 453 91 80-120 Arsenic ug/L 500 438 88 80-120 Barium ug/L 500 473 95 80-120 Beryllium ug/L 500 464 93 80-120 Cadmium ug/L 500 452 90 80-120 Chromium ug/L 500 462 92 80-120 Cobalt ug/L 500 449 90 80-120 Copper ug/L 500 469 94 80-120 Lead ug/L 500 444 89 80-120 Nickel ug/L 500 450 90 80-120 Selenium ug/L 500 435 87 80-120 Silver ug/L 250 232 93 80-120 Vanadium ug/L 500 458 92 80-120 Zinc ug/L 500 439 88 80-120 Qualifiers Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2359971 2359972 MS MSD 92396257001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 467 460 93 92 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/30/2018 12:03 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 29 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Oxford Compliance Unit 2 92396257 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2359971 2359972 MS MSD 92396257001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 462 455 92 91 75-125 1 20 Barium ug/L 40.3J 500 500 526 517 97 95 75-125 2 20 Beryllium ug/L ND 500 500 479 474 96 95 75-125 1 20 Cadmium ug/L ND 500 500 471 466 94 93 75-125 1 20 Chromium ug/L ND 500 500 476 470 95 94 75-125 1 20 Cobalt ug/L ND 500 500 456 451 91 90 75-125 1 20 Copper ug/L 24.7 500 500 508 500 97 95 75-125 2 20 Lead ug/L ND 500 500 453 448 91 89 75-125 1 20 Nickel ug/L ND 500 500 458 454 92 91 75-125 1 20 Selenium ug/L ND 500 500 461 458 92 92 75-125 1 20 Silver ug/L ND 250 250 242 238 97 95 75-125 2 20 Vanadium ug/L ND 500 500 475 470 95 94 75-125 1 20 Zinc ug/L ND 500 500 457 454 91 90 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/30/2018 12:03 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 29 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 QC Batch: 425734 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92396257001, 92396257002, 92396257003, 92396257004, 92396257005 METHOD BLANK: 2353880 Matrix: Water Associated Lab Samples: 92396257001, 92396257002, 92396257003, 92396257004, 92396257005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 5.5 0.020 08/29/1816:42 LABORATORY CONTROL SAMPLE: 2353881 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 9.9 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2353882 2353883 MS MSD 92396257001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.9 10 109 100 75-125 9 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/30/2018 12:03 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 29 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 QC Batch: 427539 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill Associated Lab Samples: 92396257001, 92396257002, 92396257003, 92396257004, 92396257005 METHOD BLANK: 2361841 Matrix: Water Associated Lab Samples: 92396257001, 92396257002, 92396257003, 92396257004, 92396257005 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.33 08/28/18 15:24 1,1,1-Trichloroethane ug/L ND 1.0 0.48 08/28/18 15:24 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.40 08/28/18 15:24 1,1,2-Trichloroethane ug/L ND 1.0 0.29 08/28/18 15:24 1,1-Dichloroethane ug/L ND 5.0 0.32 08/28/18 15:24 1,1-Dichloroethene ug/L ND 5.0 0.56 08/28/18 15:24 1,2,3-Trichloropropane ug/L ND 1.0 0.41 08/28/18 15:24 1,2-Dibromo-3-chloropropane ug/L ND 13.0 2.0 08/28/18 15:24 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 08/28/18 15:24 1,2-Dichlorobenzene ug/L ND 5.0 0.30 08/28/18 15:24 1,2-Dichloroethane ug/L ND 1.0 0.24 08/28/18 15:24 1,2-Dichloropropane ug/L ND 1.0 0.27 08/28/18 15:24 1,4-Dichlorobenzene ug/L ND 1.0 0.33 08/28/18 15:24 2-Butanone (MEK) ug/L ND 100 0.96 08/28/18 15:24 2-Hexanone ug/L ND 50.0 0.46 08/28/18 15:24 4-Methyl-2-pentanone (MIBK) ug/L ND 100 0.33 08/28/18 15:24 Acetone ug/L ND 100 10.0 08/28/18 15:24 Acrylonitrile ug/L ND 200 1.9 08/28/18 15:24 Benzene ug/L ND 1.0 0.25 08/28/18 15:24 Bromochloromethane ug/L ND 3.0 0.17 08/28/18 15:24 Bromodichloromethane ug/L ND 1.0 0.18 08/28/18 15:24 Bromoform ug/L ND 3.0 0.26 08/28/18 15:24 Bromomethane ug/L ND 10.0 0.29 08/28/18 15:24 Carbon disulfide ug/L ND 100 1.2 08/28/18 15:24 Carbon tetrachloride ug/L ND 1.0 0.25 08/28/18 15:24 Chlorobenzene ug/L ND 3.0 0.23 08/28/18 15:24 Chloroethane ug/L ND 10.0 0.54 08/28/18 15:24 Chloroform ug/L ND 5.0 0.14 08/28/18 15:24 Chloromethane ug/L ND 1.0 0.11 08/28/18 15:24 cis-1,2-Dichloroethene ug/L ND 5.0 0.19 08/28/18 15:24 cis-1,3-Dichloropropene ug/L ND 1.0 0.13 08/28/18 15:24 Dibromochloromethane ug/L ND 3.0 0.21 08/28/18 15:24 Dibromomethane ug/L ND 10.0 0.21 08/28/18 15:24 Ethylbenzene ug/L ND 1.0 0.30 08/28/18 15:24 lodomethane ug/L ND 10.0 0.32 08/28/18 15:24 Methylene Chloride ug/L ND 1.0 0.97 08/28/18 15:24 Styrene ug/L ND 1.0 0.26 08/28/18 15:24 Tetrachloroethene ug/L ND 1.0 0.46 08/28/18 15:24 Toluene ug/L ND 1.0 0.26 08/28/18 15:24 trans-1,2-Dichloroethene ug/L ND 5.0 0.49 08/28/18 15:24 trans- 1,3-Dichloropropene ug/L ND 1.0 0.26 08/28/18 15:24 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/30/2018 12:03 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 29 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 METHOD BLANK: 2361841 Matrix: Water Associated Lab Samples: 92396257001, 92396257002, 92396257003, 92396257004, 92396257005 Blank Reporting Parameter Units Result Limit MDL Analyzed trans-1,4-Dichloro-2-butene ug/L ND 100 1.0 08/28/18 15:24 Trichloroethene ug/L ND 1.0 0.47 08/28/18 15:24 Trichlorofluoromethane ug/L ND 1.0 0.20 08/28/18 15:24 Vinyl acetate ug/L ND 50.0 0.35 08/28/18 15:24 Vinyl chloride ug/L ND 1.0 0.62 08/28/18 15:24 Xylene (Total) ug/L ND 5.0 0.66 08/28/18 15:24 1,2-Dichloroethane-d4 (S) % 98 70-130 08/28/18 15:24 4-Bromofluorobenzene (S) % 96 70-130 08/28/18 15:24 Toluene-d8 (S) % 99 70-130 08/28/18 15:24 LABORATORY CONTROL SAMPLE: Parameter 2361842 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 53.1 106 80-125 1,1,1-Trichloroethane ug/L 50 51.1 102 71-129 1,1,2,2-Tetrachloroethane ug/L 50 49.6 99 79-124 1,1,2-Trichloroethane ug/L 50 51.4 103 85-125 1,1-Dichloroethane ug/L 50 46.9 94 73-126 1,1-Dichloroethene ug/L 50 53.0 106 66-135 1,2,3-Trichloropropane ug/L 50 50.1 100 75-130 1,2-Dibromo-3-chloropropane ug/L 50 52.7 105 71-133 1,2-Dibromoethane (EDB) ug/L 50 54.5 109 83-124 1,2-Dichlorobenzene ug/L 50 50.4 101 80-133 1,2-Dichloroethane ug/L 50 49.6 99 67-128 1,2-Dichloropropane ug/L 50 48.8 98 75-132 1,4-Dichlorobenzene ug/L 50 48.1 96 78-130 2-Butanone (MEK) ug/L 100 90.5J 90 61-144 2-Hexanone ug/L 100 100 100 68-143 4-Methyl-2-pentanone (MIBK) ug/L 100 98.2J 98 72-135 Acetone ug/L 100 103 103 48-146 Acrylonitrile ug/L 250 240 96 40-160 Benzene ug/L 50 50.2 100 80-125 Bromochloromethane ug/L 50 52.3 105 71-125 Bromodichloromethane ug/L 50 55.1 110 78-124 Bromoform ug/L 50 53.9 108 71-128 Bromomethane ug/L 50 42.6 85 40-160 Carbon disulfide ug/L 50 52AJ 105 50-160 Carbon tetrachloride ug/L 50 54.9 110 69-131 Chlorobenzene ug/L 50 50.8 102 81-122 Chloroethane ug/L 50 45.8 92 39-148 Chloroform ug/L 50 51.5 103 73-127 Chloromethane ug/L 50 45.9 92 44-146 cis-1,2-Dichloroethene ug/L 50 48.6 97 74-124 cis-1,3-Dichloropropene ug/L 50 51.5 103 72-132 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/30/2018 12:03 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 29 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 LABORATORY CONTROL SAMPLE: 2361842 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Dibromochloromethane ug/L 50 54.5 109 78-125 Dibromomethane ug/L 50 57.3 115 82-120 Ethylbenzene ug/L 50 49.9 100 79-121 lodomethane ug/L 100 124 124 39-154 Methylene Chloride ug/L 50 53.4 107 64-133 Styrene ug/L 50 50.8 102 84-126 Tetrachloroethene ug/L 50 51.0 102 78-122 Toluene ug/L 50 49.1 98 80-121 trans-1,2-Dichloroethene ug/L 50 49.9 100 71-127 trans- 1,3-Dichloropropene ug/L 50 52.2 104 69-141 trans-1,4-Dichloro-2-butene ug/L 50 48.8J 98 40-160 Trichloroethene ug/L 50 54.1 108 78-122 Trichlorofluoromethane ug/L 50 54.5 109 53-137 Vinyl acetate ug/L 100 99.2 99 40-160 Vinyl chloride ug/L 50 56.7 113 58-137 Xylene (Total) ug/L 150 153 102 81-126 1,2-Dichloroethane-d4 (S) % 99 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 96 70-130 MATRIX SPIKE SAMPLE: 2361843 92396257003 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 21.4 107 70-130 1,1,1-Trichloroethane ug/L ND 20 21.9 110 70-130 1,1,2,2-Tetrachloroethane ug/L ND 20 19.5 97 70-130 1,1,2-Trichloroethane ug/L ND 20 20.4 102 70-130 1,1-Dichloroethane ug/L ND 20 20.1 100 70-130 1,1-Dichloroethene ug/L ND 20 23.6 118 70-166 1,2,3-Trichloropropane ug/L ND 20 19.9 99 70-130 1,2-Dibromo-3-chloropropane ug/L ND 20 19.0 95 70-130 1,2-Dibromoethane (EDB) ug/L ND 20 20.8 104 70-130 1,2-Dichlorobenzene ug/L ND 20 19.4 97 70-130 1,2-Dichloroethane ug/L ND 20 21.2 106 70-130 1,2-Dichloropropane ug/L ND 20 20.2 101 70-130 1,4-Dichlorobenzene ug/L ND 20 19.1 96 70-130 2-Butanone (MEK) ug/L ND 40 37.5J 94 70-130 2-Hexanone ug/L ND 40 39.7J 99 70-130 4-Methyl-2-pentanone (MIBK) ug/L ND 40 39.6J 99 70-130 Acetone ug/L ND 40 42.5J 106 70-130 Acrylonitrile ug/L ND 100 97.OJ 97 70-130 Benzene ug/L ND 20 20.3 102 70-148 Bromochloromethane ug/L ND 20 20.9 105 70-130 Bromodichloromethane ug/L ND 20 22.1 110 70-130 Bromoform ug/L ND 20 19.5 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/30/2018 12:03 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 29 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 MATRIX SPIKE SAMPLE: Parameter 2361843 Units 92396257003 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Bromomethane ug/L ND 20 13.8 69 70-130 M1 Carbon disulfide ug/L ND 20 22.1J 111 70-130 Carbon tetrachloride ug/L ND 20 23.3 116 70-130 Chlorobenzene ug/L ND 20 20.5 102 70-146 Chloroethane ug/L ND 20 19.4 97 70-130 Chloroform ug/L ND 20 21.0 105 70-130 Chloromethane ug/L ND 20 21.0 105 70-130 cis-1,2-Dichloroethene ug/L ND 20 20.2 101 70-130 cis-1,3-Dichloropropene ug/L ND 20 19.3 97 70-130 Dibromochloromethane ug/L ND 20 20.8 104 70-130 Dibromomethane ug/L ND 20 22.8 114 70-130 Ethylbenzene ug/L ND 20 20.3 101 70-130 lodomethane ug/L ND 40 55.4 139 70-130 M1 Methylene Chloride ug/L ND 20 21.7 109 70-130 Styrene ug/L ND 20 19.8 99 70-130 Tetrachloroethene ug/L ND 20 20.6 103 70-130 Toluene ug/L ND 20 19.9 99 70-155 trans-1,2-Dichloroethene ug/L ND 20 21.7 108 70-130 trans- 1,3-Dichloropropene ug/L ND 20 19.7 99 70-130 trans-1,4-Dichloro-2-butene ug/L ND 20 14.6J 73 70-130 Trichloroethene ug/L ND 20 21.8 109 69-151 Trichlorofluoromethane ug/L ND 20 25.4 127 70-130 Vinyl acetate ug/L ND 40 27.3J 68 70-130 M1 Vinyl chloride ug/L ND 20 24.4 122 70-130 Xylene (Total) ug/L ND 60 61.6 103 70-130 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % 97 70-130 Toluene-d8 (S) % 97 70-130 SAMPLE DUPLICATE: 2361844 Parameter Units 92396257004 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/30/2018 12:03 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 29 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 SAMPLE DUPLICATE: 2361844 Parameter Units 92396257004 Result 2-Butanone (MEK) ug/L ND 2-Hexanone ug/L ND 4-Methyl-2-pentanone (MIBK) ug/L ND Acetone ug/L ND Acrylonitrile ug/L ND Benzene ug/L ND Bromochloromethane ug/L ND Bromodichloromethane ug/L ND Bromoform ug/L ND Bromomethane ug/L ND Carbon disulfide ug/L ND Carbon tetrachloride ug/L ND Chlorobenzene ug/L ND Chloroethane ug/L ND Chloroform ug/L ND Chloromethane ug/L ND cis-1,2-Dichloroethene ug/L ND cis-1,3-Dichloropropene ug/L ND Dibromochloromethane ug/L ND Dibromomethane ug/L ND Ethylbenzene ug/L ND lodomethane ug/L ND Methylene Chloride ug/L ND Styrene ug/L ND Tetrachloroethene ug/L ND Toluene ug/L ND trans-1,2-Dichloroethene ug/L ND trans- 1,3-Dichloropropene ug/L ND trans-1,4-Dichloro-2-butene ug/L ND Trichloroethene ug/L ND Trichlorofluoromethane ug/L ND Vinyl acetate ug/L ND Vinyl chloride ug/L ND Xylene (Total) ug/L ND 1,2-Dichloroethane-d4 (S) % 103 4-Bromofluorobenzene (S) % 95 Toluene-d8 (S) % 99 Dup Result RPD ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 102 93 99 0 2 0 Max RPD Qualifiers 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/30/2018 12:03 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 29 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 QC Batch: 426318 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 92396257001, 92396257002, 92396257003, 92396257004, 92396257005 METHOD BLANK: 2356318 Matrix: Water Associated Lab Samples: 92396257001, 92396257002, 92396257003, 92396257004, 92396257005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.9 08/23/18 14:49 1,2-Dichloroethane-d4 (S) % 95 50-150 08/23/18 14:49 Toluene-d8 (S) % 114 50-150 08/23/18 14:49 LABORATORY CONTROL SAMPLE: 2356319 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 16.6 83 71-125 1,2-Dichloroethane-d4 (S) % 95 50-150 Toluene-d8(S) % 113 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2356320 2356321 MS MSD 92396277008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 16.4 16.4 79 79 50-150 0 30 1,2-Dichloroethane-d4 (S) % 99 98 50-150 30 Toluene-d8 (S) % 114 115 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/30/2018 12:03 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 29 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Oxford Compliance Unit 2 Pace Project No.: 92396257 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/30/2018 12:03 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 29 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Oxford Compliance Unit 2 92396257 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92396257001 3901-MW8 EPA 3010A 427103 EPA 6010D 427125 92396257002 3901-MW9 EPA 3010A 427103 EPA 6010D 427125 92396257003 3901-MW10 EPA 3010A 427103 EPA6010D 427125 92396257004 3901-SW3 EPA 3010A 427103 EPA 6010D 427125 92396257005 3901-SW4 EPA 3010A 427103 EPA 6010D 427125 92396257001 3901-MW8 EPA 3010A 425734 EPA 6020B 425756 92396257002 3901-MW9 EPA 3010A 425734 EPA 6020B 425756 92396257003 3901-MW10 EPA 3010A 425734 EPA 6020B 425756 92396257004 3901-SW3 EPA 3010A 425734 EPA 6020B 425756 92396257005 3901-SW4 EPA 3010A 425734 EPA 6020B 425756 92396257001 3901-MW8 EPA 8260B 427539 92396257002 3901-MW9 EPA 8260B 427539 92396257003 3901-MW10 EPA 8260B 427539 92396257004 3901-SW3 EPA 8260B 427539 92396257005 3901-SW4 EPA 8260B 427539 92396257001 3901-MW8 EPA 8260B Mod. 426318 92396257002 3901-MW9 EPA 8260B Mod. 426318 92396257003 3901-MW10 EPA 8260B Mod. 426318 92396257004 3901-SW3 EPA 8260B Mod. 426318 92396257005 3901-SW4 EPA 8260B Mod. 426318 Date: 08/30/2018 12:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 26 of 29 Document Name: Document Revised: February 7, 2019 Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: aC�A>RB�yfICc�,?A F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office _.-LAbo.ra dry receiving samples:-- -- Asheville ❑ Eden[] Greenwood ❑ Huntersvil Raleigh[] Mechanicsville❑ SampleCondition Client Name: WO# ; 92396257 Upon Receipt(�� j l� Project 4 Courier: ❑Fed Ex ❑UPS �j❑CUSPS ❑Client ❑ Commercial r❑)r' ❑Other: 92396257 1! Custody Seal Present? Oyes � Seals Intact? ❑Yes a 41 l+ Datej€niEialsPerson Exarnining nt rts:JJ�`� Packing Material: ❑Bubble Wrap i&ble Bags ❑None ❑ Other Thermomre�t r�`: � Gun ID: 92TO43 Type of Ice: W t ❑Blue Cooler Temp (°C): `_correction Factor: Add/Subtract (°C) _� 2 Cooler Temp Corrected (°C): USDA Regulated Soil,/A, water sample) Did samples ri@ giplgte in a quarantine zone within the United States: CA, NY, or SC (check maps)? nYesi Bi logic I Issue Frozen? ❑Yes ' o []N/A ❑Nc�e I emp:hould be above freezing to VC ❑Samples out of temp criteria. Samples on ice, cooling process hasbegun Did samples originate from a foreign sourc�jinnt ptionally, inrhvi7na Hawaii and Pnwrtn Airnl) MYPc \ n Cam ments/Discrepancy: Chain of Custody Present? s ON- ❑N/A 1. Samples Arrived within Hold Time? ONO ❑N/A 2. Short Hold Time Analysis (<72 hr.)? Oyes ❑N/A 3. Rush Turn Around Time Requested? Oyes o ❑NIA 4. SufficientVolume? LY6i ❑No ❑N/A 5. Correct Containers Used? -Pace Containers Used? s n�gs ON. ❑No ❑N/A ❑N/A 6. Containers Intact? �es [-]No ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes [:]No /A a. Sample Labels match COC? -includes Date/Time/ID/Analysis Matrix: ��Yes [:]No ❑N/A 9. Headspace in VOA Via(s (>5-6tnm)? ❑Yes 60 ❑N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes ❑Yes a OL ❑N/A ❑N/A 11. COMMENTS/SAMPLE DISCREPANCY CLIENT NOTMCATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Lot ID of split containers: Oatenme: Field Data Required? ❑Yes ❑No kPi 16 77 Date: NJ N� Date: Page 27 of 29 Document Name: Document Revised: February 7, 2018 a Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: aeeAnalytical F-CAR-Cs-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is Project # WO# , 92396257 verified and within the acceptance range for preservation — — - - samples. PM: NMG Due date: 08/31//31/18 Exceptions: VOA, Cali€orm, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg CLIENT: 92—Joyce Bng **Bottom half of box is to list number of bottle E r m c U "v £ e in m a m c U a E 3 m a m q v a 5 U o E 7 ry 2 m ? ° v C N FLn `t I ri a m N o. a O [V u m E ar a A. op C d n'1 O S U E o 2 M a in 2' m N t�J Q Z V m a.a E ti a a m nl n C _Q z O Z ro E H U a a m C ° fy6 a N o E v LL � Z � 41 o, C a ¢ v. N l9 < v Q U S 4 0 M S •+ l7 Q V it a = E E o r&v ' rn (7 G N T a 7 0 N = a C `m N y N .9 l7 Q N v a LA£ E Q E M rn (7 4 V Z a Q 1 o rr? m O 4 m l7 Q _ Q Z U ¢ d E S U l7 O Z M O VfVI ¢ > o£ v 1= m > � _ Q Z C G 0 £ 7 m V 7 4 _y ? a 0 rn 4 O E q In to l7 O Q Vj o y,� +' m a ° Y Q O 7 Z u m \ a y t1 m y i7 > � N I Z U 'n �p 0. v E ,n n F u r3. �n ! Q 2 V y `m J E o ni M r[ a y Rl p Vi N 2 Z U ro a E 0 ry 4 M a m } y v c V E a of 0 7 a l? Q Q .Z_.. M j c O c E o ry v� V) 7 7 Z N q1 a C E Q E a c 7 m U' a 1 } 1 2 \J 4 1 ) 5 IK" 6 7 9 -\\\N 10 11 12 pH Adjustment Log for preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot 9 Note: whenever there fs a discrepancy affecting North Carolina Compliance samples, a copy oT tn's Form wni ce sent to the worm t-aroima ucnrvn �.eRmcau❑n UM x kl— Out of hoid, incorrect preservative, out of temp, incorrect Containers. Page 28 of 29 N O CHAIN -OF -CUSTODY / Analytical Request Document N The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. m Section A Section B Section C Required Client Information: Required Proiecl information: Invoice Information: Page : i Of 1 Company: Joyce Engineering RepoilTo: Van Burbach Attention: Jason Falls Address: 2211 West Meadowview Rd copy To: Miguel Vazquez Company Name: Granville County, Solid Waste Greensboro, NO 27407 Address: P.O. Box 906, Oxford NC 27565 Regulatory Agency Email To: vburbach to teen Ineefin .com Purchase Order No. Phone: 336 323-0092 Fax Client Project ID: Oxford Compliance Unit 2 Pace PM: Nicole Gasiorow: State I Location Requested Due Date1TAT: 10 Da Default Container Order Number: Profile: 3566-3 North Carolina Request Anat sis Filtered YIN y MATRIX CODE _ O COLLECTED Z Preservatives r o,l°x,°yw°m, Dw 4 water wT waste wolc. NIv4 _ m ~ En w 2 PI°Gw P y O N 0 } SAMPLE ID 5°; �nlid SL ❑A CL (7 START END F ¢ °' 1, d, N ° c One Character per box. w.Pe wP .. ¢ a w N p to-Z, 0-9 1. -1 An oT {~ � 7. Q CL c� Sample Ids must be unique T.— Ts cc Q ¢ ¢ a a U n O O 20 N = C a ci U 4 ~ s DATE TIME DATE TIME N� _= z z i O Z Z a 1 If 2 3901-MW8 wr G 3 3901-MW9 wr G X X X X X !/ 4 3901-fdlW10 wr G 15fi X X X X X Y a1- a 6 7 3901-SW3 -T G I $' ll4 1.2.2 X X X X X L'L 8 3901-SW4 wr G ! & (D X X X X X ,�: 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY! AFFILIATION DATE TIME CCEPTED BY 1 AFFILIATION DATE TIME SAMPLE CONDITIONS ku DCO3 ' Ir/'� {� Mw-7 & NES-2S are duplicates of samples from Oxford Unit 1. �� /�/ f i If possible, only run analayses once, but report for both. i SAMPLER NAME AND SIGNATURE—d, c ❑ Z = PRINT Name of SAMPLER: -- dz > V ❑ = Z SIGNA U� REAf S'LER: DATE Signed: aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 September 13, 2018 Mr. Van Burbach Joyce Engineering -NC 2211 West Meadowview Rd Boone Bldg, Suite 101 Greensboro, NC 27407 RE: Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory between August 16, 2018 and August 17, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. This revision was issued on 9/13/18 to include the chloride data for sample 3901-MW-7. This data did not show up on the original report due to an IT issue. If you have any questions concerning this report, please feel free to contact me. Sincerely, Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Mr. Daniel Girdner, LaBella Associates, D.P.C. Miguel Vazquez, Joyce Engineering Rochelle mesubed, Joyce Engineering �pQ ACrfFO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 9e0 without the written consent of Pace Analytical Services, LLC. Page 1 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 41 aceAnalytical —pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 Lab ID Sample ID Matrix Date Collected Date Received 92396142001 3901-MW-7 Water 08/15/1810:51 08/16/1810:00 92396142003 3901-NES-2S Water 08/15/1814:16 08/16/1810:00 92396142005 3901- Trip Blank Water 08/14/18 05:30 08/17/18 09:37 92396142006 3901- Field Blank Water 08/16/18 16:30 08/17/18 09:37 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: OXFORD UNITS 1&2 BLANKS JOINT 92396142 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92396142001 3901-MW-7 EPA 601 OD DS 16 PASI-A EPA6020B JMW1 1 PASI-A EPA7470A JMW1 1 PASI-A EPA 8260E CAH 51 PASI-C EPA 8260B Mod. DLK 3 PASI-C SM 2320B-2011 ECH 1 PASI-A SM 2540C-2011 CRV 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A 92396142003 3901-NES-2S EPA 601 OD DS 14 PASI-A EPA6020B JMW1 1 PASI-A EPA 8260E CAH 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92396142005 3901- Trip Blank EPA 8260E CAH 51 PASI-C 92396142006 3901- Field Blank EPA 601 OD DS 16 PASI-A EPA6020B JMW1 1 PASI-A EPA7470A JMW1 1 PASI-A EPA 8260E CAH 51 PASI-C EPA 8260B Mod. DLK 3 PASI-C SM 2320B-2011 ECH 1 PASI-A SM 2540C-2011 NAL 1 PASI-A EPA 300.0 Rev 2.1 1993 KDF1 2 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92396142001 3901-MW-7 EPA 601 OD Barium 3.8J ug/L 100 08/21/18 22:37 EPA 601 OD Iron 340 ug/L 300 08/21/18 22:37 EPA 601 OD Manganese 6.7J ug/L 50.0 08/21/18 22:37 SM 2320B-2011 Alkalinity, Total as CaCO3 124000 ug/L 5000 08/24/18 20:54 SM 2540C-2011 Total Dissolved Solids 249000 ug/L 25000 08/17/18 16:50 EPA 300.0 Rev 2.1 1993 Chloride 9720 ug/L 1000 08/24/18 09:14 EPA 300.0 Rev 2.1 1993 Sulfate 51400J ug/L 250000 08/24/18 09:14 92396142003 3901-NES-2S EPA 601 OD Barium 25.8J ug/L 100 08/21/18 22:46 EPA 601 OD Vanadium 2.5J ug/L 25.0 08/21/18 22:46 92396142006 3901-Field Blank EPA 601 OD Iron 27.8J ug/L 300 08/25/18 22:56 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 41 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 Sample: 3901-MW-7 Lab ID: 92396142001 Collected: 08/15/18 10:51 Received: 08/16/18 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Iron Lead Manganese Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 7470 Mercury Mercury 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane Date: 09/13/2018 12:26 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 6.0 3.9 1 08/17/18 07:28 08/21/18 22:37 7440-36-0 ND ug/L 10.0 5.0 1 08/17/18 07:28 08/21/18 22:37 7440-38-2 3.8J ug/L 100 2.5 1 08/17/18 07:28 08/21/18 22:37 7440-39-3 ND ug/L 1.0 0.50 1 08/17/18 07:28 08/21/18 22:37 7440-41-7 ND ug/L 1.0 0.50 1 08/17/18 07:28 08/21/18 22:37 7440-43-9 ND ug/L 10.0 2.5 1 08/17/18 07:28 08/21/18 22:37 7440-47-3 ND ug/L 10.0 2.5 1 08/17/18 07:28 08/21/18 22:37 7440-48-4 ND ug/L 10.0 2.5 1 08/17/18 07:28 08/21/18 22:37 7440-50-8 340 ug/L 300 25.0 1 08/17/18 07:28 08/21/18 22:37 7439-89-6 ND ug/L 10.0 2.5 1 08/17/18 07:28 08/21/18 22:37 7439-92-1 6.7J ug/L 50.0 2.5 1 08/17/18 07:28 08/21/18 22:37 7439-96-5 ND ug/L 50.0 2.5 1 08/17/18 07:28 08/21/18 22:37 7440-02-0 ND ug/L 10.0 5.0 1 08/17/18 07:28 08/21/18 22:37 7782-49-2 ND ug/L 10.0 2.5 1 08/17/18 07:28 08/21/18 22:37 7440-22-4 ND ug/L 25.0 2.5 1 08/17/18 07:28 08/21/18 22:37 7440-62-2 ND ug/L 10.0 5.0 1 08/17/18 07:28 08/21/18 22:37 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 5.5 0.020 1 08/17/18 07:17 08/23/18 22:33 7440-28-0 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.10 1 08/20/1819:25 08/21/1813:23 7439-97-6 Analytical Method: EPA 8260E ND ug/L 100 ND ug/L 200 ND ug/L 1.0 ND ug/L 3.0 ND ug/L 1.0 ND ug/L 3.0 ND ug/L 10.0 ND ug/L 100 ND ug/L 100 ND ug/L 1.0 ND ug/L 3.0 ND ug/L 10.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 13.0 ND ug/L 3.0 ND ug/L 1.0 ND ug/L 10.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 100 ND ug/L 5.0 10.0 1 08/19/18 16:20 67-64-1 1.9 1 08/19/18 16:20 107-13-1 0.25 1 08/19/18 16:20 71-43-2 0.17 1 08/19/18 16:20 74-97-5 0.18 1 08/19/18 16:20 75-27-4 0.26 1 08/19/18 16:20 75-25-2 0.29 1 08/19/18 16:20 74-83-9 0.96 1 08/19/18 16:20 78-93-3 1.2 1 08/19/18 16:20 75-15-0 0.25 1 08/19/18 16:20 56-23-5 0.23 1 08/19/18 16:20 108-90-7 0.54 1 08/19/18 16:20 75-00-3 0.14 1 08/19/18 16:20 67-66-3 0.11 1 08/19/18 16:20 74-87-3 2.0 1 08/19/18 16:20 96-12-8 0.21 1 08/19/18 16:20 124-48-1 0.27 1 08/19/18 16:20 106-93-4 0.21 1 08/19/18 16:20 74-95-3 0.30 1 08/19/18 16:20 95-50-1 0.33 1 08/19/18 16:20 106-46-7 1.0 1 08/19/18 16:20 110-57-6 0.32 1 08/19/18 16:20 75-34-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 41 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 Sample: 3901-MW-7 Lab ID: 92396142001 Collected: 08/15/18 10:51 Received: 08/16/18 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E 1,2-Dichloroethane ND ug/L 1.0 0.24 1 08/19/18 16:20 107-06-2 1,1-Dichloroethene ND ug/L 5.0 0.56 1 08/19/18 16:20 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 0.19 1 08/19/18 16:20 156-59-2 trans-1,2-Dichloroethene ND ug/L 5.0 0.49 1 08/19/18 16:20 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 08/19/18 16:20 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 08/19/18 16:20 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 08/19/18 16:20 10061-02-6 Ethylbenzene ND ug/L 1.0 0.30 1 08/19/18 16:20 100-41-4 2-Hexanone ND ug/L 50.0 0.46 1 08/19/18 16:20 591-78-6 lodomethane ND ug/L 10.0 0.32 1 08/19/18 16:20 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 08/19/18 16:20 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 100 0.33 1 08/19/18 16:20 108-10-1 Styrene ND ug/L 1.0 0.26 1 08/19/18 16:20 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 5.0 0.33 1 08/19/18 16:20 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 3.0 0.40 1 08/19/18 16:20 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 08/19/18 16:20 127-18-4 Tetrahydrofuran ND ug/L 10.0 3.1 1 08/19/18 16:20 109-99-9 Toluene ND ug/L 1.0 0.26 1 08/19/18 16:20 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 08/19/18 16:20 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 08/19/18 16:20 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 08/19/18 16:20 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 08/19/18 16:20 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 08/19/18 16:20 96-18-4 Vinyl acetate ND ug/L 50.0 0.35 1 08/19/18 16:20 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 08/19/18 16:20 75-01-4 Xylene (Total) ND ug/L 5.0 0.66 1 08/19/18 16:20 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 94 % 70-130 1 08/19/18 16:20 460-00-4 1,2-Dichloroethane-d4 (S) 101 % 70-130 1 08/19/18 16:20 17060-07-0 Toluene-d8 (S) 99 % 70-130 1 08/19/18 16:20 2037-26-5 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 08/23/18 18:04 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 99 % 50-150 1 08/23/18 18:04 17060-07-0 Toluene-d8 (S) 118 % 50-150 1 08/23/18 18:04 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B-2011 Alkalinity, Total as CaCO3 124000 ug/L 5000 1000 1 08/24/18 20:54 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011 Total Dissolved Solids 249000 ug/L 25000 25000 1 08/17/18 16:50 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Chloride 9720 ug/L 1000 500 1 08/24/18 09:14 16887-00-6 Sulfate 51400J ug/L 250000 500 1 08/24/18 09:14 14808-79-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 41 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 Sample: 3901-NES-2S Lab ID: 92396142003 Collected: 08/15/18 14:16 Received: 08/16/18 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 09/13/2018 12:26 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 6.0 3.9 1 08/17/18 07:28 08/21/18 22:46 7440-36-0 ND ug/L 10.0 5.0 1 08/17/18 07:28 08/21/18 22:46 7440-38-2 25.8J ug/L 100 2.5 1 08/17/18 07:28 08/21/18 22:46 7440-39-3 ND ug/L 1.0 0.50 1 08/17/18 07:28 08/21/18 22:46 7440-41-7 ND ug/L 1.0 0.50 1 08/17/18 07:28 08/21/18 22:46 7440-43-9 ND ug/L 10.0 2.5 1 08/17/18 07:28 08/21/18 22:46 7440-47-3 ND ug/L 10.0 2.5 1 08/17/18 07:28 08/21/18 22:46 7440-48-4 ND ug/L 10.0 2.5 1 08/17/18 07:28 08/21/18 22:46 7440-50-8 ND ug/L 10.0 2.5 1 08/17/18 07:28 08/21/18 22:46 7439-92-1 ND ug/L 50.0 2.5 1 08/17/18 07:28 08/21/18 22:46 7440-02-0 ND ug/L 10.0 5.0 1 08/17/18 07:28 08/21/18 22:46 7782-49-2 ND ug/L 10.0 2.5 1 08/17/18 07:28 08/21/18 22:46 7440-22-4 2.5J ug/L 25.0 2.5 1 08/17/18 07:28 08/21/18 22:46 7440-62-2 ND ug/L 10.0 5.0 1 08/17/18 07:28 08/21/18 22:46 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 5.5 0.020 1 08/17/18 07:17 08/23/18 22:41 7440-28-0 Analytical Method: EPA 8260E ND ug/L 100 10.0 1 08/19/1816:36 67-64-1 ND ug/L 200 1.9 1 08/19/1816:36 107-13-1 ND ug/L 1.0 0.25 1 08/19/1816:36 71-43-2 ND ug/L 3.0 0.17 1 08/19/1816:36 74-97-5 ND ug/L 1.0 0.18 1 08/19/1816:36 75-27-4 ND ug/L 3.0 0.26 1 08/19/1816:36 75-25-2 ND ug/L 10.0 0.29 1 08/19/1816:36 74-83-9 ND ug/L 100 0.96 1 08/19/1816:36 78-93-3 ND ug/L 100 1.2 1 08/19/1816:36 75-15-0 ND ug/L 1.0 0.25 1 08/19/1816:36 56-23-5 ND ug/L 3.0 0.23 1 08/19/1816:36 108-90-7 ND ug/L 10.0 0.54 1 08/19/1816:36 75-00-3 ND ug/L 5.0 0.14 1 08/19/1816:36 67-66-3 ND ug/L 1.0 0.11 1 08/19/1816:36 74-87-3 ND ug/L 13.0 2.0 1 08/19/1816:36 96-12-8 ND ug/L 3.0 0.21 1 08/19/1816:36 124-48-1 ND ug/L 1.0 0.27 1 08/19/1816:36 106-93-4 ND ug/L 10.0 0.21 1 08/19/1816:36 74-95-3 ND ug/L 5.0 0.30 1 08/19/1816:36 95-50-1 ND ug/L 1.0 0.33 1 08/19/1816:36 106-46-7 ND ug/L 100 1.0 1 08/19/1816:36 110-57-6 ND ug/L 5.0 0.32 1 08/19/1816:36 75-34-3 ND ug/L 1.0 0.24 1 08/19/1816:36 107-06-2 ND ug/L 5.0 0.56 1 08/19/1816:36 75-35-4 ND ug/L 5.0 0.19 1 08/19/1816:36 156-59-2 ND ug/L 5.0 0.49 1 08/19/1816:36 156-60-5 ND ug/L 1.0 0.27 1 08/19/1816:36 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 41 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 Sample: 3901-NES-2S Lab ID: 92396142003 Collected: 08/15/18 14:16 Received: 08/16/18 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/13/2018 12:26 PM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 100 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 3.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 1.0 ND ug/L 5.0 95 % 70-130 100 % 70-130 98 % 70-130 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 98 % 50-150 113 % 50-150 0.13 1 08/19/18 16:36 10061-01-5 0.26 1 08/19/18 16:36 10061-02-6 0.30 1 08/19/18 16:36 100-41-4 0.46 1 08/19/18 16:36 591-78-6 0.32 1 08/19/18 16:36 74-88-4 0.97 1 08/19/18 16:36 75-09-2 0.33 1 08/19/18 16:36 108-10-1 0.26 1 08/19/18 16:36 100-42-5 0.33 1 08/19/18 16:36 630-20-6 0.40 1 08/19/18 16:36 79-34-5 0.46 1 08/19/18 16:36 127-18-4 0.26 1 08/19/18 16:36 108-88-3 0.48 1 08/19/18 16:36 71-55-6 0.29 1 08/19/18 16:36 79-00-5 0.47 1 08/19/18 16:36 79-01-6 0.20 1 08/19/18 16:36 75-69-4 0.41 1 08/19/18 16:36 96-18-4 0.35 1 08/19/18 16:36 108-05-4 0.62 1 08/19/18 16:36 75-01-4 0.66 1 08/19/18 16:36 1330-20-7 1 08/19/18 16:36 460-00-4 1 08/19/18 16:36 17060-07-0 1 08/19/18 16:36 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 08/21 /18 18:53 123-91-1 08/21 /18 18:53 17060-07-0 08/21 /18 18:53 2037-26-5 Page 9 of 41 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 Sample: 3901- Trip Blank Lab ID: 92396142005 Collected: 08/14/18 05:30 Received: 08/17/18 09:37 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 100 10.0 1 08/19/18 16:52 67-64-1 Acrylonitrile ND ug/L 200 1.9 1 08/19/18 16:52 107-13-1 Benzene ND ug/L 1.0 0.25 1 08/19/18 16:52 71-43-2 Bromochloromethane ND ug/L 3.0 0.17 1 08/19/18 16:52 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 08/19/18 16:52 75-27-4 Bromoform ND ug/L 3.0 0.26 1 08/19/18 16:52 75-25-2 Bromomethane ND ug/L 10.0 0.29 1 08/19/18 16:52 74-83-9 2-Butanone (MEK) ND ug/L 100 0.96 1 08/19/18 16:52 78-93-3 Carbon disulfide ND ug/L 100 1.2 1 08/19/18 16:52 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 08/19/18 16:52 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 08/19/18 16:52 108-90-7 Chloroethane ND ug/L 10.0 0.54 1 08/19/18 16:52 75-00-3 Chloroform ND ug/L 5.0 0.14 1 08/19/18 16:52 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 08/19/18 16:52 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 13.0 2.0 1 08/19/18 16:52 96-12-8 Dibromochloromethane ND ug/L 3.0 0.21 1 08/19/18 16:52 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 08/19/18 16:52 106-93-4 Dibromomethane ND ug/L 10.0 0.21 1 08/19/18 16:52 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.30 1 08/19/18 16:52 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 08/19/18 16:52 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 100 1.0 1 08/19/18 16:52 110-57-6 1,1-Dichloroethane ND ug/L 5.0 0.32 1 08/19/18 16:52 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 08/19/18 16:52 107-06-2 1,1-Dichloroethene ND ug/L 5.0 0.56 1 08/19/18 16:52 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 0.19 1 08/19/18 16:52 156-59-2 trans-1,2-Dichloroethene ND ug/L 5.0 0.49 1 08/19/18 16:52 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 08/19/18 16:52 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 08/19/18 16:52 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 08/19/18 16:52 10061-02-6 Ethylbenzene ND ug/L 1.0 0.30 1 08/19/18 16:52 100-41-4 2-Hexanone ND ug/L 50.0 0.46 1 08/19/18 16:52 591-78-6 lodomethane ND ug/L 10.0 0.32 1 08/19/18 16:52 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 08/19/18 16:52 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 100 0.33 1 08/19/18 16:52 108-10-1 Styrene ND ug/L 1.0 0.26 1 08/19/18 16:52 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 5.0 0.33 1 08/19/18 16:52 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 3.0 0.40 1 08/19/18 16:52 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 08/19/18 16:52 127-18-4 Tetrahydrofuran ND ug/L 10.0 3.1 1 08/19/18 16:52 109-99-9 Toluene ND ug/L 1.0 0.26 1 08/19/18 16:52 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 08/19/18 16:52 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 08/19/18 16:52 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 08/19/18 16:52 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 08/19/18 16:52 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 08/19/18 16:52 96-18-4 Vinyl acetate ND ug/L 50.0 0.35 1 08/19/18 16:52 108-05-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 Sample: 3901- Trip Blank Lab ID: 92396142005 Collected: 08/14/18 05:30 Received: 08/17/18 09:37 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Vinyl chloride ND ug/L 1.0 0.62 1 08/19/18 16:52 75-01-4 Xylene (Total) ND ug/L 5.0 0.66 1 08/19/18 16:52 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 93 % 70-130 1 08/19/18 16:52 460-00-4 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 08/19/18 16:52 17060-07-0 Toluene-d8 (S) 101 % 70-130 1 08/19/18 16:52 2037-26-5 Date: 09/13/2018 12:26 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 41 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 Sample: 3901- Field Blank Lab ID: 92396142006 Collected: 08/16/18 16:30 Received: 08/17/18 09:37 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Iron Lead Manganese Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 7470 Mercury Mercury 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane Date: 09/13/2018 12:26 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 6.0 3.9 1 08/25/18 07:40 08/25/18 22:56 7440-36-0 ND ug/L 10.0 5.0 1 08/25/18 07:40 08/25/18 22:56 7440-38-2 ND ug/L 100 2.5 1 08/25/18 07:40 08/25/18 22:56 7440-39-3 ND ug/L 1.0 0.50 1 08/25/18 07:40 08/25/18 22:56 7440-41-7 ND ug/L 1.0 0.50 1 08/25/18 07:40 08/25/18 22:56 7440-43-9 ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:56 7440-47-3 ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:56 7440-48-4 ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:56 7440-50-8 27.8J ug/L 300 25.0 1 08/25/18 07:40 08/25/18 22:56 7439-89-6 ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:56 7439-92-1 ND ug/L 50.0 2.5 1 08/25/18 07:40 08/25/18 22:56 7439-96-5 ND ug/L 50.0 2.5 1 08/25/18 07:40 08/25/18 22:56 7440-02-0 ND ug/L 10.0 5.0 1 08/25/18 07:40 08/25/18 22:56 7782-49-2 ND ug/L 10.0 2.5 1 08/25/18 07:40 08/25/18 22:56 7440-22-4 ND ug/L 25.0 2.5 1 08/25/18 07:40 08/25/18 22:56 7440-62-2 ND ug/L 10.0 5.0 1 08/25/18 07:40 08/25/18 22:56 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 5.5 0.020 1 08/18/18 06:19 08/29/18 17:30 7440-28-0 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.10 1 08/20/1819:25 08/21/1813:28 7439-97-6 Analytical Method: EPA 8260E ND ug/L 100 ND ug/L 200 ND ug/L 1.0 ND ug/L 3.0 ND ug/L 1.0 ND ug/L 3.0 ND ug/L 10.0 ND ug/L 100 ND ug/L 100 ND ug/L 1.0 ND ug/L 3.0 ND ug/L 10.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 13.0 ND ug/L 3.0 ND ug/L 1.0 ND ug/L 10.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 100 ND ug/L 5.0 10.0 1 08/19/18 17:08 67-64-1 1.9 1 08/19/18 17:08 107-13-1 0.25 1 08/19/18 17:08 71-43-2 0.17 1 08/19/18 17:08 74-97-5 0.18 1 08/19/18 17:08 75-27-4 0.26 1 08/19/18 17:08 75-25-2 0.29 1 08/19/18 17:08 74-83-9 0.96 1 08/19/18 17:08 78-93-3 1.2 1 08/19/18 17:08 75-15-0 0.25 1 08/19/18 17:08 56-23-5 0.23 1 08/19/18 17:08 108-90-7 0.54 1 08/19/18 17:08 75-00-3 0.14 1 08/19/18 17:08 67-66-3 0.11 1 08/19/18 17:08 74-87-3 2.0 1 08/19/18 17:08 96-12-8 0.21 1 08/19/18 17:08 124-48-1 0.27 1 08/19/18 17:08 106-93-4 0.21 1 08/19/18 17:08 74-95-3 0.30 1 08/19/18 17:08 95-50-1 0.33 1 08/19/18 17:08 106-46-7 1.0 1 08/19/18 17:08 110-57-6 0.32 1 08/19/18 17:08 75-34-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 41 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 Sample: 3901- Field Blank Lab ID: 92396142006 Collected: 08/16/18 16:30 Received: 08/17/18 09:37 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E 1,2-Dichloroethane ND ug/L 1.0 0.24 1 08/19/18 17:08 107-06-2 1,1-Dichloroethene ND ug/L 5.0 0.56 1 08/19/18 17:08 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 0.19 1 08/19/18 17:08 156-59-2 trans-1,2-Dichloroethene ND ug/L 5.0 0.49 1 08/19/18 17:08 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 08/19/18 17:08 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 08/19/18 17:08 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 08/19/18 17:08 10061-02-6 Ethylbenzene ND ug/L 1.0 0.30 1 08/19/18 17:08 100-41-4 2-Hexanone ND ug/L 50.0 0.46 1 08/19/18 17:08 591-78-6 lodomethane ND ug/L 10.0 0.32 1 08/19/18 17:08 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 08/19/18 17:08 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 100 0.33 1 08/19/18 17:08 108-10-1 Styrene ND ug/L 1.0 0.26 1 08/19/18 17:08 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 5.0 0.33 1 08/19/18 17:08 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 3.0 0.40 1 08/19/18 17:08 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 08/19/18 17:08 127-18-4 Tetrahydrofuran ND ug/L 10.0 3.1 1 08/19/18 17:08 109-99-9 Toluene ND ug/L 1.0 0.26 1 08/19/18 17:08 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 08/19/18 17:08 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 08/19/18 17:08 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 08/19/18 17:08 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 08/19/18 17:08 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 08/19/18 17:08 96-18-4 Vinyl acetate ND ug/L 50.0 0.35 1 08/19/18 17:08 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 08/19/18 17:08 75-01-4 Xylene (Total) ND ug/L 5.0 0.66 1 08/19/18 17:08 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 94 % 70-130 1 08/19/18 17:08 460-00-4 1,2-Dichloroethane-d4 (S) 97 % 70-130 1 08/19/18 17:08 17060-07-0 Toluene-d8 (S) 101 % 70-130 1 08/19/18 17:08 2037-26-5 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 08/21/18 18:14 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 102 % 50-150 1 08/21/18 18:14 17060-07-0 Toluene-d8 (S) 114 % 50-150 1 08/21/18 18:14 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B-2011 Alkalinity, Total as CaCO3 ND ug/L 5000 1000 1 08/28/18 00:17 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011 Total Dissolved Solids ND ug/L 25000 25000 1 08/19/18 12:21 300.0 IC anions 48hr Analytical Method: EPA 300.0 Rev 2.1 1993 Chloride ND ug/L 1000 500 1 08/18/18 00:15 16887-00-6 Sulfate ND mg/L 250 0.50 1 08/18/18 00:15 14808-79-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 QC Batch: 425829 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Associated Lab Samples: 92396142001, 92396142006 METHOD BLANK: 2354113 Matrix: Water Associated Lab Samples: 92396142001, 92396142006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.10 08/21/1811:38 LABORATORY CONTROL SAMPLE: 2354114 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.4 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2354115 2354116 MS MSD 92395555001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.4 2.4 96 96 75-125 1 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 QC Batch: 425491 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92396142001, 92396142003 METHOD BLANK: 2352643 Associated Lab Samples: 92396142001, 92396142003 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 6.0 3.9 08/21/18 22:05 Arsenic ug/L ND 10.0 5.0 08/21/18 22:05 Barium ug/L ND 100 2.5 08/21/18 22:05 Beryllium ug/L ND 1.0 0.50 08/21/18 22:05 Cadmium ug/L ND 1.0 0.50 08/21/18 22:05 Chromium ug/L ND 10.0 2.5 08/21/18 22:05 Cobalt ug/L ND 10.0 2.5 08/21/18 22:05 Copper ug/L ND 10.0 2.5 08/21/18 22:05 Iron ug/L ND 300 25.0 08/21/18 22:05 Lead ug/L ND 10.0 2.5 08/21/18 22:05 Manganese ug/L ND 50.0 2.5 08/21/18 22:05 Nickel ug/L ND 50.0 2.5 08/21/18 22:05 Selenium ug/L ND 10.0 5.0 08/21/18 22:05 Silver ug/L ND 10.0 2.5 08/21/18 22:05 Vanadium ug/L ND 25.0 2.5 08/21/18 22:05 Zinc ug/L ND 10.0 5.0 08/21/18 22:05 LABORATORY CONTROL SAMPLE: 2352644 Parameter Units Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Cadmium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Manganese ug/L Nickel ug/L Selenium ug/L Silver ug/L Vanadium ug/L Zinc ug/L Spike Conc. LCS Result LCS % Rec % Rec Limits 500 487 97 80-120 500 464 93 80-120 500 483 97 80-120 500 479 96 80-120 500 458 92 80-120 500 476 95 80-120 500 466 93 80-120 500 496 99 80-120 5000 4880 98 80-120 500 464 93 80-120 500 474 95 80-120 500 480 96 80-120 500 455 91 80-120 250 246 99 80-120 500 482 96 80-120 500 452 90 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: OXFORD UNITS 1&2 92396142 BLANKS JOINT MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2352645 2352646 MS MSD 92396141001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 504 496 101 99 75-125 2 20 Arsenic ug/L ND 500 500 487 478 97 96 75-125 2 20 Barium ug/L ND 500 500 475 472 95 94 75-125 1 20 Beryllium ug/L ND 500 500 500 495 100 99 75-125 1 20 Cadmium ug/L ND 500 500 456 449 91 90 75-125 2 20 Chromium ug/L ND 500 500 472 465 94 93 75-125 1 20 Cobalt ug/L ND 500 500 453 447 91 89 75-125 1 20 Copper ug/L ND 500 500 502 492 100 98 75-125 2 20 Iron ug/L 83.9J 5000 5000 4940 4900 97 96 75-125 1 20 Lead ug/L ND 500 500 457 450 91 90 75-125 2 20 Manganese ug/L 9.81 500 500 482 474 94 93 75-125 2 20 Nickel ug/L ND 500 500 464 456 93 91 75-125 2 20 Selenium ug/L ND 500 500 503 493 100 98 75-125 2 20 Silver ug/L ND 250 250 251 246 100 99 75-125 2 20 Vanadium ug/L ND 500 500 494 487 98 97 75-125 1 20 Zinc ug/L ND 500 500 454 444 90 88 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 QC Batch: 427103 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92396142006 METHOD BLANK: 2359969 Associated Lab Samples: 92396142006 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 6.0 3.9 08/25/18 21:44 Arsenic ug/L ND 10.0 5.0 08/25/18 21:44 Barium ug/L ND 100 2.5 08/25/18 21:44 Beryllium ug/L ND 1.0 0.50 08/25/18 21:44 Cadmium ug/L ND 1.0 0.50 08/25/18 21:44 Chromium ug/L ND 10.0 2.5 08/25/18 21:44 Cobalt ug/L ND 10.0 2.5 08/25/18 21:44 Copper ug/L ND 10.0 2.5 08/25/18 21:44 Iron ug/L ND 300 25.0 08/25/18 21:44 Lead ug/L ND 10.0 2.5 08/25/18 21:44 Manganese ug/L ND 50.0 2.5 08/25/18 21:44 Nickel ug/L ND 50.0 2.5 08/25/18 21:44 Selenium ug/L ND 10.0 5.0 08/25/18 21:44 Silver ug/L ND 10.0 2.5 08/25/18 21:44 Vanadium ug/L ND 25.0 2.5 08/25/18 21:44 Zinc ug/L ND 10.0 5.0 08/25/18 21:44 LABORATORY CONTROL SAMPLE: 2359970 Parameter Units Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Cadmium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Manganese ug/L Nickel ug/L Selenium ug/L Silver ug/L Vanadium ug/L Zinc ug/L Spike Conc. LCS Result LCS % Rec % Rec Limits 500 453 91 80-120 500 438 88 80-120 500 473 95 80-120 500 464 93 80-120 500 452 90 80-120 500 462 92 80-120 500 449 90 80-120 500 469 94 80-120 5000 4630 93 80-120 500 444 89 80-120 500 449 90 80-120 500 450 90 80-120 500 435 87 80-120 250 232 93 80-120 500 458 92 80-120 500 439 88 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: OXFORD UNITS 1&2 92396142 BLANKS JOINT MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2359971 2359972 MS MSD 92396257001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 467 460 93 92 75-125 1 20 Arsenic ug/L ND 500 500 462 455 92 91 75-125 1 20 Barium ug/L 40.3J 500 500 526 517 97 95 75-125 2 20 Beryllium ug/L ND 500 500 479 474 96 95 75-125 1 20 Cadmium ug/L ND 500 500 471 466 94 93 75-125 1 20 Chromium ug/L ND 500 500 476 470 95 94 75-125 1 20 Cobalt ug/L ND 500 500 456 451 91 90 75-125 1 20 Copper ug/L 24.7 500 500 508 500 97 95 75-125 2 20 Iron ug/L 410 5000 5000 5320 5230 98 96 75-125 2 20 Lead ug/L ND 500 500 453 448 91 89 75-125 1 20 Manganese ug/L 270 500 500 746 734 95 93 75-125 2 20 Nickel ug/L ND 500 500 458 454 92 91 75-125 1 20 Selenium ug/L ND 500 500 461 458 92 92 75-125 1 20 Silver ug/L ND 250 250 242 238 97 95 75-125 2 20 Vanadium ug/L ND 500 500 475 470 95 94 75-125 1 20 Zinc ug/L ND 500 500 457 454 91 90 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 QC Batch: 425510 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92396142001, 92396142003 METHOD BLANK: 2352702 Matrix: Water Associated Lab Samples: 92396142001, 92396142003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 5.5 0.020 08/23/18 22:09 LABORATORY CONTROL SAMPLE: 2352703 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.1 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2352704 2352705 MS MSD 92396141001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.3 10.3 103 103 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 QC Batch: 425734 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92396142006 METHOD BLANK: 2353880 Matrix: Water Associated Lab Samples: 92396142006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 5.5 0.020 08/29/1816:42 LABORATORY CONTROL SAMPLE: 2353881 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 9.9 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2353882 2353883 MS MSD 92396257001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.9 10 109 100 75-125 9 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 41 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 QC Batch: 425801 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill Associated Lab Samples: 92396142001, 92396142003, 92396142005, 92396142006 METHOD BLANK: 2354038 Matrix: Water Associated Lab Samples: 92396142001, 92396142003, 92396142005, 92396142006 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.33 08/19/18 12:01 1,1,1-Trichloroethane ug/L ND 1.0 0.48 08/19/18 12:01 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.40 08/19/18 12:01 1,1,2-Trichloroethane ug/L ND 1.0 0.29 08/19/18 12:01 1,1-Dichloroethane ug/L ND 5.0 0.32 08/19/18 12:01 1,1-Dichloroethene ug/L ND 5.0 0.56 08/19/18 12:01 1,2,3-Trichloropropane ug/L ND 1.0 0.41 08/19/18 12:01 1,2-Dibromo-3-chloropropane ug/L ND 13.0 2.0 08/19/18 12:01 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 08/19/18 12:01 1,2-Dichlorobenzene ug/L ND 5.0 0.30 08/19/18 12:01 1,2-Dichloroethane ug/L ND 1.0 0.24 08/19/18 12:01 1,2-Dichloropropane ug/L ND 1.0 0.27 08/19/18 12:01 1,4-Dichlorobenzene ug/L ND 1.0 0.33 08/19/18 12:01 2-Butanone (MEK) ug/L ND 100 0.96 08/19/18 12:01 2-Hexanone ug/L ND 50.0 0.46 08/19/18 12:01 4-Methyl-2-pentanone (MIBK) ug/L ND 100 0.33 08/19/18 12:01 Acetone ug/L ND 100 10.0 08/19/18 12:01 Acrylonitrile ug/L ND 200 1.9 08/19/18 12:01 Benzene ug/L ND 1.0 0.25 08/19/18 12:01 Bromochloromethane ug/L ND 3.0 0.17 08/19/18 12:01 Bromodichloromethane ug/L ND 1.0 0.18 08/19/18 12:01 Bromoform ug/L ND 3.0 0.26 08/19/18 12:01 Bromomethane ug/L ND 10.0 0.29 08/19/18 12:01 Carbon disulfide ug/L ND 100 1.2 08/19/18 12:01 Carbon tetrachloride ug/L ND 1.0 0.25 08/19/18 12:01 Chlorobenzene ug/L ND 3.0 0.23 08/19/18 12:01 Chloroethane ug/L ND 10.0 0.54 08/19/18 12:01 Chloroform ug/L ND 5.0 0.14 08/19/18 12:01 Chloromethane ug/L ND 1.0 0.11 08/19/18 12:01 cis-1,2-Dichloroethene ug/L ND 5.0 0.19 08/19/18 12:01 cis-1,3-Dichloropropene ug/L ND 1.0 0.13 08/19/18 12:01 Dibromochloromethane ug/L ND 3.0 0.21 08/19/18 12:01 Dibromomethane ug/L ND 10.0 0.21 08/19/18 12:01 Ethylbenzene ug/L ND 1.0 0.30 08/19/18 12:01 lodomethane ug/L ND 10.0 0.32 08/19/18 12:01 Methylene Chloride ug/L ND 1.0 0.97 08/19/18 12:01 Styrene ug/L ND 1.0 0.26 08/19/18 12:01 Tetrachloroethene ug/L ND 1.0 0.46 08/19/18 12:01 Tetrahydrofuran ug/L ND 10.0 3.1 08/19/18 12:01 Toluene ug/L ND 1.0 0.26 08/19/18 12:01 trans-1,2-Dichloroethene ug/L ND 5.0 0.49 08/19/18 12:01 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 41 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 METHOD BLANK: 2354038 Matrix: Water Associated Lab Samples: 92396142001, 92396142003, 92396142005, 92396142006 Blank Reporting Parameter Units Result Limit MDL Analyzed trans- 1,3-Dichloropropene ug/L ND 1.0 0.26 08/19/18 12:01 trans-1,4-Dichloro-2-butene ug/L ND 100 1.0 08/19/18 12:01 Trichloroethene ug/L ND 1.0 0.47 08/19/18 12:01 Trichlorofluoromethane ug/L ND 1.0 0.20 08/19/18 12:01 Vinyl acetate ug/L ND 50.0 0.35 08/19/18 12:01 Vinyl chloride ug/L ND 1.0 0.62 08/19/18 12:01 Xylene (Total) ug/L ND 5.0 0.66 08/19/18 12:01 1,2-Dichloroethane-d4 (S) % 98 70-130 08/19/18 12:01 4-Bromofluorobenzene (S) % 96 70-130 08/19/18 12:01 Toluene-d8 (S) % 100 70-130 08/19/18 12:01 LABORATORY CONTROL SAMPLE: Parameter 2354039 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 51.6 103 80-125 1,1,1-Trichloroethane ug/L 50 51.1 102 71-129 1,1,2,2-Tetrachloroethane ug/L 50 49.3 99 79-124 1,1,2-Trichloroethane ug/L 50 50.4 101 85-125 1,1-Dichloroethane ug/L 50 46.8 94 73-126 1,1-Dichloroethene ug/L 50 52.2 104 66-135 1,2,3-Trichloropropane ug/L 50 48.5 97 75-130 1,2-Dibromo-3-chloropropane ug/L 50 51.2 102 71-133 1,2-Dibromoethane (EDB) ug/L 50 53.0 106 83-124 1,2-Dichlorobenzene ug/L 50 49.2 98 80-133 1,2-Dichloroethane ug/L 50 50.1 100 67-128 1,2-Dichloropropane ug/L 50 50.1 100 75-132 1,4-Dichlorobenzene ug/L 50 47.7 95 78-130 2-Butanone (MEK) ug/L 100 96.2J 96 61-144 2-Hexanone ug/L 100 100 100 68-143 4-Methyl-2-pentanone (MIBK) ug/L 100 98AJ 98 72-135 Acetone ug/L 100 112 112 48-146 Acrylonitrile ug/L 250 248 99 40-160 Benzene ug/L 50 49.1 98 80-125 Bromochloromethane ug/L 50 52.0 104 71-125 Bromodichloromethane ug/L 50 53.3 107 78-124 Bromoform ug/L 50 51.1 102 71-128 Bromomethane ug/L 50 37.9 76 40-160 Carbon disulfide ug/L 50 51.3J 103 50-160 Carbon tetrachloride ug/L 50 52.9 106 69-131 Chlorobenzene ug/L 50 49.4 99 81-122 Chloroethane ug/L 50 43.1 86 39-148 Chloroform ug/L 50 51.7 103 73-127 Chloromethane ug/L 50 44.4 89 44-146 cis-1,2-Dichloroethene ug/L 50 49.2 98 74-124 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 41 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 LABORATORY CONTROL SAMPLE: 2354039 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 50.2 100 72-132 Dibromochloromethane ug/L 50 51.3 103 78-125 Dibromomethane ug/L 50 54.0 108 82-120 Ethylbenzene ug/L 50 48.9 98 79-121 lodomethane ug/L 100 98.6 99 39-154 Methylene Chloride ug/L 50 51.6 103 64-133 Styrene ug/L 50 49.4 99 84-126 Tetrachloroethene ug/L 50 48.4 97 78-122 Tetrahydrofuran ug/L 500 477 95 69-148 Toluene ug/L 50 47.9 96 80-121 trans-1,2-Dichloroethene ug/L 50 50.8 102 71-127 trans- 1,3-Dichloropropene ug/L 50 50.8 102 69-141 trans-1,4-Dichloro-2-butene ug/L 50 52.6J 105 40-160 Trichloroethene ug/L 50 52.8 106 78-122 Trichlorofluoromethane ug/L 50 51.2 102 53-137 Vinyl acetate ug/L 100 98.1 98 40-160 Vinyl chloride ug/L 50 51.5 103 58-137 Xylene (Total) ug/L 150 149 99 81-126 1,2-Dichloroethane-d4 (S) % 100 70-130 4-Bromofluorobenzene (S) % 97 70-130 Toluene-d8 (S) % 97 70-130 MATRIX SPIKE SAMPLE: 2354041 92395744002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 19.3 96 70-130 1,1,1-Trichloroethane ug/L ND 20 20.7 103 70-130 1,1,2,2-Tetrachloroethane ug/L ND 20 18.9 94 70-130 1,1,2-Trichloroethane ug/L ND 20 19.4 97 70-130 1,1-Dichloroethane ug/L ND 20 19.3 97 70-130 1,1-Dichloroethene ug/L ND 20 21.8 109 70-166 1,2,3-Trichloropropane ug/L ND 20 18.8 94 70-130 1,2-Dibromo-3-chloropropane ug/L ND 20 18.0 90 70-130 1,2-Dibromoethane (EDB) ug/L ND 20 20.0 100 70-130 1,2-Dichlorobenzene ug/L 1.2J 20 20.7 97 70-130 1,2-Dichloroethane ug/L ND 20 19.9 99 70-130 1,2-Dichloropropane ug/L ND 20 19.5 98 70-130 1,4-Dichlorobenzene ug/L 1.9 20 20.2 92 70-130 2-Butanone (MEK) ug/L ND 40 39.OJ 97 70-130 2-Hexanone ug/L ND 40 37.2J 93 70-130 4-Methyl-2-pentanone (MIBK) ug/L ND 40 37.9J 95 70-130 Acetone ug/L ND 40 53.5J 134 70-130 M1 Acrylonitrile ug/L ND 100 97.3J 97 70-130 Benzene ug/L 1.3 20 21.2 100 70-148 Bromochloromethane ug/L ND 20 20.5 103 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 MATRIX SPIKE SAMPLE: 2354041 92395744002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Bromodichloromethane ug/L ND 20 20.1 101 70-130 Bromoform ug/L ND 20 18.1 90 70-130 Bromomethane ug/L ND 20 9.6J 48 70-130 M1 Carbon disulfide ug/L ND 20 20.OJ 100 70-130 Carbon tetrachloride ug/L ND 20 20.6 103 70-130 Chlorobenzene ug/L 14.5 20 33.9 97 70-146 Chloroethane ug/L 1.2J 20 19.4 91 70-130 Chloroform ug/L ND 20 20.0 100 70-130 Chloromethane ug/L ND 20 17.7 89 70-130 cis-1,2-Dichloroethene ug/L ND 20 19.9 100 70-130 cis-1,3-Dichloropropene ug/L ND 20 18.6 93 70-130 Dibromochloromethane ug/L ND 20 19.0 95 70-130 Dibromomethane ug/L ND 20 21.3 107 70-130 Ethylbenzene ug/L ND 20 19.3 97 70-130 lodomethane ug/L ND 40 36.3 91 70-130 Methylene Chloride ug/L ND 20 19.9 100 70-130 Styrene ug/L ND 20 18.8 94 70-130 Tetrachloroethene ug/L ND 20 19.5 97 70-130 Tetrahydrofuran ug/L 12.1 200 198 93 70-130 Toluene ug/L ND 20 19.2 96 70-155 trans-1,2-Dichloroethene ug/L ND 20 20.7 103 70-130 trans- 1,3-Dichloropropene ug/L ND 20 18.9 94 70-130 trans-1,4-Dichloro-2-butene ug/L ND 20 15.OJ 75 70-130 Trichloroethene ug/L ND 20 21.0 105 69-151 Trichlorofluoromethane ug/L ND 20 22.4 112 70-130 Vinyl acetate ug/L ND 40 35.9J 90 70-130 Vinyl chloride ug/L ND 20 21.2 106 70-130 Xylene (Total) ug/L ND 60 58.3 97 70-130 1,2-Dichloroethane-d4 (S) % 100 70-130 4-Bromofluorobenzene (S) % 97 70-130 Toluene-d8 (S) % 96 70-130 SAMPLE DUPLICATE: 2354040 Parameter Units 92395744001 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 SAMPLE DUPLICATE: 2354040 Parameter Units 92395744001 Result Dup Result 1,2-Dichloroethane ug/L ND ND 1,2-Dichloropropane ug/L ND ND 1,4-Dichlorobenzene ug/L ND ND 2-Butanone (MEK) ug/L ND ND 2-Hexanone ug/L ND ND 4-Methyl-2-pentanone (MIBK) ug/L ND ND Acetone ug/L ND ND Acrylonitrile ug/L ND ND Benzene ug/L ND ND Bromochloromethane ug/L ND ND Bromodichloromethane ug/L ND ND Bromoform ug/L ND ND Bromomethane ug/L ND ND Carbon disulfide ug/L ND ND Carbon tetrachloride ug/L ND ND Chlorobenzene ug/L ND ND Chloroethane ug/L ND ND Chloroform ug/L ND ND Chloromethane ug/L ND ND cis-1,2-Dichloroethene ug/L ND ND cis-1,3-Dichloropropene ug/L ND ND Dibromochloromethane ug/L ND ND Dibromomethane ug/L ND ND Ethylbenzene ug/L ND ND lodomethane ug/L ND ND Methylene Chloride ug/L ND ND Styrene ug/L ND ND Tetrachloroethene ug/L ND ND Tetrahydrofuran ug/L ND ND Toluene ug/L ND ND trans-1,2-Dichloroethene ug/L ND ND trans- 1,3-Dichloropropene ug/L ND ND trans-1,4-Dichloro-2-butene ug/L ND ND Trichloroethene ug/L ND ND Trichlorofluoromethane ug/L ND ND Vinyl acetate ug/L ND ND Vinyl chloride ug/L ND ND Xylene (Total) ug/L ND ND 1,2-Dichloroethane-d4 (S) % 98 102 4-Bromofluorobenzene (S) % 97 95 Toluene-d8 (S) % 98 99 Max RPD RPD Qualifiers 3 2 0 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 41 Pace Analytical Services, LLC ceAnalX cal ® 9800 Kiney Ave. Suite 100 Huntersville, NC 28078078 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 QC Batch: 426080 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 92396142003, 92396142006 METHOD BLANK: 2355220 Matrix: Water Associated Lab Samples: 92396142003, 92396142006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.9 08/21/18 15:18 1,2-Dichloroethane-d4 (S) % 97 50-150 08/21/18 15:18 Toluene-d8 (S) % 107 50-150 08/21/18 15:18 LABORATORY CONTROL SAMPLE: 2355221 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 17.7 88 71-125 1,2-Dichloroethane-d4 (S) % 97 50-150 Toluene-d8(S) % 107 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2355222 2355223 MS MSD 92395199068 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 18.5 17.9 91 88 50-150 3 30 1,2-Dichloroethane-d4 (S) % 105 104 50-150 30 Toluene-d8 (S) % 114 113 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 QC Batch: 426318 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 92396142001 METHOD BLANK: 2356318 Associated Lab Samples: 92396142001 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L 1,2-Dichloroethane-d4 (S) % Toluene-d8 (S) % Matrix: Water Blank Reporting Result Limit ND 2.0 95 50-150 114 50-150 MDL Analyzed 1.9 08/23/18 14:49 08/23/18 14:49 08/23/18 14:49 Qualifiers LABORATORY CONTROL SAMPLE: 2356319 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 16.6 83 71-125 1,2-Dichloroethane-d4 (S) % 95 50-150 Toluene-d8(S) % 113 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2356320 2356321 MS MSD 92396277008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 16.4 16.4 79 79 50-150 0 30 1,2-Dichloroethane-d4 (S) % 99 98 50-150 30 Toluene-d8 (S) % 114 115 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 QC Batch: 426910 Analysis Method: SM 2320B-2011 QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity Associated Lab Samples: 92396142001 METHOD BLANK: 2358896 Matrix: Water Associated Lab Samples: 92396142001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Alkalinity, Total as CaCO3 ug/L ND 5000 1000 08/24/18 19:05 LABORATORY CONTROL SAMPLE: 2358897 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ug/L 50000 50000 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2358898 2358899 MS MSD 92396797013 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 88.0 mg/L 50000 50000 136000 136000 96 96 80-120 0 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2358900 2358901 MS MSD 92396834004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 12.7 mg/L 50000 50000 61800 64600 98 104 80-120 4 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 QC Batch: 427280 Analysis Method: SM 2320B-2011 QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity Associated Lab Samples: 92396142006 METHOD BLANK: 2360642 Matrix: Water Associated Lab Samples: 92396142006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Alkalinity, Total as CaCO3 ug/L ND 5000 1000 08/27/18 22:09 LABORATORY CONTROL SAMPLE: 2360643 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ug/L 50000 50200 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2360644 2360645 MS MSD 92397010023 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 29.9 mg/L 50000 50000 78800 78900 98 98 80-120 0 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2360659 2360660 MS MSD 92396725004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 46.0 mg/L 50000 50000 96500 95400 101 99 80-120 1 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 QC Batch: 425684 Analysis Method: SM 2540C-2011 QC Batch Method: SM 2540C-2011 Analysis Description: 2540C Total Dissolved Solids Associated Lab Samples: 92396142001 METHOD BLANK: 2353674 Matrix: Water Associated Lab Samples: 92396142001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Dissolved Solids ug/L ND 25000 25000 08/17/18 16:50 LABORATORY CONTROL SAMPLE: 2353675 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Dissolved Solids ug/L 251000 250000 100 90-110 SAMPLE DUPLICATE: 2353676 92395975002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Dissolved Solids ug/L 890 mg/L 892000 0 5 SAMPLE DUPLICATE: 2353677 92395975012 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Dissolved Solids ug/L 162 mg/L 168000 4 5 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 QC Batch: 425804 Analysis Method: SM 2540C-2011 QC Batch Method: SM 2540C-2011 Analysis Description: 2540C Total Dissolved Solids Associated Lab Samples: 92396142006 METHOD BLANK: 2354053 Matrix: Water Associated Lab Samples: 92396142006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Dissolved Solids ug/L ND 25000 25000 08/19/18 12:18 LABORATORY CONTROL SAMPLE: 2354054 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Dissolved Solids ug/L 250000 262000 105 90-110 SAMPLE DUPLICATE: 2354055 92396221001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Dissolved Solids ug/L ND ND 5 SAMPLE DUPLICATE: 2354056 92396251003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Dissolved Solids ug/L 504 mg/L 504000 0 5 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 QC Batch: 426573 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92396142001 METHOD BLANK: 2357505 Matrix: Water Associated Lab Samples: 92396142001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chloride ug/L ND 1000 500 08/24/18 01:34 Sulfate ug/L ND 250000 500 08/24/18 01:34 LABORATORY CONTROL SAMPLE: 2357506 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 50000 51800 104 90-110 Sulfate ug/L 50000 49000J 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2357507 2357508 MS MSD 92396726011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 4.5 mg/L 50000 50000 61100 60100 113 111 90-110 2 10 M1 Sulfate ug/L 2.9 mg/L 50000 50000 56700J 55800J 108 106 90-110 2 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2357509 2357510 MS MSD 92396726021 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 4.9 mg/L 50000 50000 59300 60200 109 110 90-110 1 10 Sulfate ug/L 3.4 mg/L 50000 50000 54700J 56000J 103 105 90-110 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 QC Batch: 425712 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92396142006 METHOD BLANK: 2353804 Matrix: Water Associated Lab Samples: 92396142006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chloride ug/L ND 1000 500 08/17/18 22:44 Sulfate mg/L ND 250 0.50 08/17/18 22:44 LABORATORY CONTROL SAMPLE: 2353805 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 50000 50200 100 90-110 Sulfate mg/L 50 51.6J 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2353806 2353807 MS MSD 92396275001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 50600 50000 50000 96200 94200 91 87 90-110 2 10 M1 Sulfate mg/L 4AJ 50 50 56.3J 56.1J 104 104 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: OXFORD UNITS 1&2 BLANKS JOINT Pace Project No.: 92396142 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/13/2018 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 41 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: OXFORD UNITS 1&2 BLANKS JOINT 92396142 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92396142001 3901-MW-7 EPA 3010A 425491 EPA 6010D 425539 92396142003 3901-NES-2S EPA 3010A 425491 EPA6010D 425539 92396142006 3901- Field Blank EPA 3010A 427103 EPA 6010D 427125 92396142001 3901-MW-7 EPA 3010A 425510 EPA 6020B 425544 92396142003 3901-NES-2S EPA 3010A 425510 EPA 6020B 425544 92396142006 3901- Field Blank EPA 3010A 425734 EPA 6020B 425756 92396142001 3901-MW-7 EPA 7470A 425829 EPA 7470A 426024 92396142006 3901- Field Blank EPA 7470A 425829 EPA 7470A 426024 92396142001 3901-MW-7 EPA 8260B 425801 92396142003 3901-NES-2S EPA 8260B 425801 92396142005 3901- Trip Blank EPA 8260B 425801 92396142006 3901- Field Blank EPA 8260B 425801 92396142001 3901-MW-7 EPA 8260B Mod. 426318 92396142003 3901-NES-2S EPA 8260B Mod. 426080 92396142006 3901- Field Blank EPA 8260B Mod. 426080 92396142001 3901-MW-7 SM 2320B-2011 426910 92396142006 3901-Field Blank SM 2320B-2011 427280 92396142001 3901-MW-7 SM 2540C-2011 425684 92396142006 3901- Field Blank SM 2540C-2011 425804 92396142001 3901-MW-7 EPA 300.0 Rev 2.1 1993 426573 92396142006 3901- Field Blank EPA 300.0 Rev 2.1 1993 425712 Date: 09/13/2018 12:26 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 35 of 41 Document Name: Document Revised: February 7, 2018 9 Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issu€ng Authority: aC2A,�alyfiCal F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: / Asheville ❑ Eden❑ Greenwood ❑ Huntersville K] " Raleigh[] Mechanicsville❑ ' ; Client Name: L Project #; Courier: ❑Fed Ex t []UPS OUSPS ❑Client ❑ Commercial ce ❑Other: Custody Seal Present? ❑Yes ETNK, Seals Intact? Oyes 31O WOit : 92396142 1111111111111111111111 1142 Date/initials Person Examining Contents.. Packing Material: ❑Bubble Wrap Hfulble Bags ❑None ❑ Other Biological Tissue Fr en? Thermomete Dyes ❑No /A ER Gun Ib; 92TO43 Type of Ice: Ovet ❑Blue ❑None Cooler Temp ('C): —S ` Correction Factor: Add/Subtract (°C) _0.2 Temp should be above freezing to 6'C Cooler Temp Corrected (°C): ❑<amples out of temp criteria. Samples on ice, cooling process has begun USDA Regulated Soil ( /MIA, water sample) - Did samples originate in a quarantine zone within the United States: CA, NY, or 5C (check maps)? Did samples originate from a foreign source (internat ally, Dyes o in,i uiinv Hawaii and P,,Prrn Ritn17 I—lYat FZ11Cn Comments/Discrepancy: Chain of Custody Present? Yes ❑ryo ❑N/A 1. Samples Arrived within Hold Time? Yes ❑, ❑N/A 2. Short Hold Time Analysis (<72 hr.)? ❑Yes [No L3 Na/ ❑N/A 3, Rush Turn Around Time Requested? ❑yes 090-- ❑N/A 4. Sufficient Volume? �es ❑No ❑N/A 5. Correct Containers Used? -Pace Containers Used? es OKI' [--]No []No ❑N/A ❑N/A 6. Containers Intact? 4f Yes [-]No ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑No N/A a. Sample Labels Match COC? -Includes Date/TimeAD/Analysis Matrix: 3<s I� ❑No ❑N/A 9. Headspace in VOA Vials (>5-6mm)? ❑Yes ONo ❑N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? afes 2 es ❑No []No []NIA ❑N/A 11. COMMENTS/SAMPLE DISCREPANCY Field Data Required? ❑Yes ❑No Lu n Gl i'7I�UA' i .�i ,11(C002 an� fi/ (VI ►c � - / T7 RI�i}� �i�i�� t' ��i� co-J. 11 �(01^C Lb �t►l� illF'} ., `JU ,d,C-4)IV) Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: d tC. Datenme: Project Manager SCURF Review: , Date: OR1,6} / Project Manager SRF Review: _ Date: !� V Page 36 of 41 Document Name: Document Revised: February 7, 2018 a Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: acmnalytical F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples, Exceptions: VOA, Cotiform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottle Project It WO# » 2396142 li'i'I: NMG Due Date: 08/30/18 CLIENT: 92•-Joyce Eng V o v s Zi a Q3 v Y N a N Ci ? N V R ry T N _ z G] N h V G = d u 2 Z a 2 _ a = Z {= y m Q \ Z• Q C 41 ? y L N L a c J N a c Cl ca c 2 N m Q C O 0 S rL p Z = U G N = O Z ro V '� a C V a V v a c = a O ry Q O ,`^y = -0 E a m VI 0 _ .X m lil CJ' y z `—° '� 4 N ry Z y a 7 h N •� N u u m O u 4 u m cl u 4 a, y Y o E a E a n E Q v E 4 2 y a E � � E ¢ 1 ne Ln _ V ¢ O } N ,n Q O c ¢ O m ¢ O > = v a .=. .. Y S v m N y �n u a i.- y E a m c 'u Ln E 4 E N E E p m E N E L E N E N ° 3 `m `v _�_ J E ¢ — J E . 6 M :.i E r Q E E ) N A v @ 0 } J E Ln J E O Ll J E J ff J E p J E O Q aMEi .-I G� N a l!1 a ri 7 Q. v-I V7 a N Z a. r•1 N a. ri U op. ri 14 l7 r! 11 U N m l9 ,y H 0 M U M a CO} Oi 0 O�1 0 p0 Q5 l7 ai 0 a O (7 .N -1 V~i 0. N N a N naf a r•i O 0 N (�� Vr a0i i7 m m m m m m m m 3 a a a a a a o > > o > > �, v, ra a > z \kk 3 -1 4 5 —NN\\ N N 7 9 Y' 10 \1 g f( 11 zz N \M pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot if Note: whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 37 of 41 Section A Reouired Client Information: Section B Reouired Prnier_t Infnrmatinnr CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section C In—i.e Inf—lion Dann • 1 of Company: Joyce Engineering Report TO: Van Burbach Altention Jason Falls Address: 2211 West Meadowview Rd Copy To: Miguel Vazquez Company Name: Granville County, Solid Waste Greensboro, NC 27407 Address: P.O. Box 906, Oxford NC 27565 Reigulatopf.Agerney Email To: vburbach .O ceen ineerin .com Purchase Order No. Phoney 336 323-0092 Irax Client Project ID: Oxford Units 1&2 Blanks & Joint Pace PM: Nicole Gasiorowe State I Location Requested Due Date/TAT: 10 Da Default Container Order Number Profile: 3566-4 North Carolina Requested Analysis Filtered YIN ft h MATRIX CODE Dunking ware, Dw W't" WT waste Water P,od— P '40d SAMPLE 1D SoSL o, oL One Character per box. ww� wa (A-Z. 0-9 1. _) Ai, AR Sample Ids must be unique Tta Ts o w o x G 3 U ,� s7 w a "' Q ,n COLLECTED = O u p F a w LL` Q m z o O ar Preservatives r START END °' N � v O _ 2 _ U � z N z CC L � r O m I°i N 0 C Q a N t� Q U Z U O ti- Q U Z N E D_ O °� U Z ay t6 X Q �' U Q a) 2t d V � v � � � Z �% f �Z DATE TIME DATE TIME 1 3901-MW-7 vT G : r ii'` C1 11 >(Ix Ix I I I X X Ix Ix Ix I I I Il 3901-NES-2S 4!ir :r x IV X X X 9 3901-Field Blank wr G X X X X X�Z 10 3901-TripBlank JWT C X 11 12 ADDITIONAL COMMENTS RELINQUISHED BY ! AFFILIATION DATE TIME ACCEPTED BY I AFFILIATION DATE TIME SAMPLE CONDITIONS C&D Parameters = Iron, Manganese, Mercury, Alkalinity, Chloride, Sulfate, TDS, and /ate �' �j C/1 ��. �► 11r-�.� _ j �-� 5 [, Tetrah drofuran SAMPLER NAME AND SIGNATURE W C o U m m z o _ m E z PRINT Name of SAMPLER: N, SIGNATURE of SAMPLER: / 1) DATE Signed: L 1 f r w W 00 co d aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 October 18, 2018 Mr. Van Burbach Joyce Engineering -NC 2211 West Meadowview Rd Boone Bldg, Suite 101 Greensboro, NC 27407 RE: Project: Oxford Unit 2 Resample Pace Project No.: 92402129 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on October 04, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ��i Flo _ _.1I , .�: Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Mr. Daniel Girdner, LaBella Associates, D.P.C. Miguel Vazquez, Joyce Engineering Rochelle mesubed, Joyce Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 23 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Oxford Unit 2 Resample Pace Project No.: 92402129 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 23 aceAnalytical —pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Oxford Unit 2 Resample Pace Project No.: 92402129 Lab ID Sample ID Matrix Date Collected Date Received 92402129001 92402129002 3901-MW11 Field Blank Water Water 10/03/1814:30 10/03/18 14:50 10/04/1810:30 10/04/18 10:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 23 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Oxford Unit 2 Resample 92402129 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92402129001 3901-MW11 EPA 601OD SH1 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92402129002 Field Blank EPA 601OD SH1 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 23 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Oxford Unit 2 Resample 92402129 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92402129001 3901-MW11 EPA 6010D Barium 33.6J ug/L 100 10/05/18 18:05 EPA 6010D Nickel 4.OJ ug/L 50.0 10/05/18 18:05 EPA 6010D Vanadium 4.8J ug/L 25.0 10/05/18 18:05 EPA 6010D Zinc 7.7J ug/L 10.0 10/05/18 18:05 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 23 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Unit 2 Resample Pace Project No.: 92402129 Sample: 3901-MW11 Lab ID: 92402129001 Collected: 10/03/18 14:30 Received: 10/04/18 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 6.0 3.9 1 10/05/18 02:59 10/05/18 18:05 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 10/05/18 02:59 10/05/18 18:05 7440-38-2 Barium 33.6J ug/L 100 2.5 1 10/05/18 02:59 10/05/18 18:05 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 10/05/18 02:59 10/05/18 18:05 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 10/05/18 02:59 10/05/18 18:05 7440-43-9 Chromium ND ug/L 10.0 2.5 1 10/05/18 02:59 10/05/18 18:05 7440-47-3 Cobalt ND ug/L 10.0 2.5 1 10/05/18 02:59 10/05/18 18:05 7440-48-4 Copper ND ug/L 10.0 2.5 1 10/05/18 02:59 10/05/18 18:05 7440-50-8 Lead ND ug/L 10.0 2.5 1 10/05/18 02:59 10/05/18 18:05 7439-92-1 Nickel 4.OJ ug/L 50.0 2.5 1 10/05/18 02:59 10/05/18 18:05 7440-02-0 Selenium ND ug/L 10.0 5.0 1 10/05/18 02:59 10/05/18 18:05 7782-49-2 Silver ND ug/L 10.0 2.5 1 10/05/18 02:59 10/05/18 18:05 7440-22-4 Vanadium 4.8J ug/L 25.0 2.5 1 10/05/18 02:59 10/05/18 18:05 7440-62-2 Zinc 7.7J ug/L 10.0 5.0 1 10/05/18 02:59 10/05/18 18:05 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 5.5 0.020 1 10/05/18 02:59 10/05/18 15:17 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 100 10.0 1 10/05/18 07:45 67-64-1 Acrylonitrile ND ug/L 200 1.9 1 10/05/18 07:45 107-13-1 Benzene ND ug/L 1.0 0.25 1 10/05/18 07:45 71-43-2 Bromochloromethane ND ug/L 3.0 0.17 1 10/05/18 07:45 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 10/05/18 07:45 75-27-4 Bromoform ND ug/L 3.0 0.26 1 10/05/18 07:45 75-25-2 Bromomethane ND ug/L 10.0 0.29 1 10/05/18 07:45 74-83-9 M1 2-Butanone (MEK) ND ug/L 100 0.96 1 10/05/18 07:45 78-93-3 Carbon disulfide ND ug/L 100 1.2 1 10/05/18 07:45 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 10/05/18 07:45 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 10/05/18 07:45 108-90-7 Chloroethane ND ug/L 10.0 0.54 1 10/05/18 07:45 75-00-3 Chloroform ND ug/L 5.0 0.14 1 10/05/18 07:45 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 10/05/18 07:45 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 13.0 2.0 1 10/05/18 07:45 96-12-8 Dibromochloromethane ND ug/L 3.0 0.21 1 10/05/18 07:45 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/05/18 07:45 106-93-4 Dibromomethane ND ug/L 10.0 0.21 1 10/05/18 07:45 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.30 1 10/05/18 07:45 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 10/05/18 07:45 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 100 1.0 1 10/05/18 07:45 110-57-6 M1 1,1-Dichloroethane ND ug/L 5.0 0.32 1 10/05/18 07:45 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 10/05/18 07:45 107-06-2 1,1-Dichloroethene ND ug/L 5.0 0.56 1 10/05/18 07:45 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 0.19 1 10/05/18 07:45 156-59-2 trans-1,2-Dichloroethene ND ug/L 5.0 0.49 1 10/05/18 07:45 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 10/05/18 07:45 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/18/2018 04:45 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 23 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Unit 2 Resample Pace Project No.: 92402129 Sample: 3901-MW11 Lab ID: 92402129001 Collected: 10/03/18 14:30 Received: 10/04/18 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 10/18/2018 04:45 PM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 100 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 3.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 1.0 ND ug/L 5.0 108 % 70-130 95 % 70-130 110 % 70-130 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 105 % 50-150 125 % 50-150 0.13 1 10/05/18 07:45 10061-01-5 0.26 1 10/05/18 07:45 10061-02-6 0.30 1 10/05/18 07:45 100-41-4 0.46 1 10/05/18 07:45 591-78-6 0.32 1 10/05/18 07:45 74-88-4 M1 0.97 1 10/05/18 07:45 75-09-2 0.33 1 10/05/18 07:45 108-10-1 0.26 1 10/05/18 07:45 100-42-5 0.33 1 10/05/18 07:45 630-20-6 0.40 1 10/05/18 07:45 79-34-5 0.46 1 10/05/18 07:45 127-18-4 0.26 1 10/05/18 07:45 108-88-3 0.48 1 10/05/18 07:45 71-55-6 0.29 1 10/05/18 07:45 79-00-5 0.47 1 10/05/18 07:45 79-01-6 0.20 1 10/05/18 07:45 75-69-4 0.41 1 10/05/18 07:45 96-18-4 0.35 1 10/05/18 07:45 108-05-4 0.62 1 10/05/18 07:45 75-01-4 0.66 1 10/05/18 07:45 1330-20-7 1 10/05/18 07:45 460-00-4 1 10/05/18 07:45 17060-07-0 1 10/05/18 07:45 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 10/17/18 14:47 123-91-1 10/ 17/ 18 14:47 17060-07-0 10/17/1814:47 2037-26-5 Page 7 of 23 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Unit 2 Resample Pace Project No.: 92402129 Sample: Field Blank Lab ID: 92402129002 Collected: 10/03/18 14:50 Received: 10/04/18 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 10/18/2018 04:45 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 6.0 3.9 1 10/05/18 02:59 10/05/18 18:08 7440-36-0 ND ug/L 10.0 5.0 1 10/05/18 02:59 10/05/18 18:08 7440-38-2 ND ug/L 100 2.5 1 10/05/18 02:59 10/05/18 18:08 7440-39-3 ND ug/L 1.0 0.50 1 10/05/18 02:59 10/05/18 18:08 7440-41-7 ND ug/L 1.0 0.50 1 10/05/18 02:59 10/05/18 18:08 7440-43-9 ND ug/L 10.0 2.5 1 10/05/18 02:59 10/05/18 18:08 7440-47-3 ND ug/L 10.0 2.5 1 10/05/18 02:59 10/05/18 18:08 7440-48-4 ND ug/L 10.0 2.5 1 10/05/18 02:59 10/05/18 18:08 7440-50-8 ND ug/L 10.0 2.5 1 10/05/18 02:59 10/05/18 18:08 7439-92-1 ND ug/L 50.0 2.5 1 10/05/18 02:59 10/05/18 18:08 7440-02-0 ND ug/L 10.0 5.0 1 10/05/18 02:59 10/05/18 18:08 7782-49-2 ND ug/L 10.0 2.5 1 10/05/18 02:59 10/05/18 18:08 7440-22-4 ND ug/L 25.0 2.5 1 10/05/18 02:59 10/05/18 18:08 7440-62-2 ND ug/L 10.0 5.0 1 10/05/18 02:59 10/05/18 18:08 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 5.5 0.020 1 10/05/18 02:59 10/05/18 15:08 7440-28-0 Analytical Method: EPA 8260E ND ug/L 100 10.0 1 10/05/18 05:48 67-64-1 ND ug/L 200 1.9 1 10/05/18 05:48 107-13-1 ND ug/L 1.0 0.25 1 10/05/18 05:48 71-43-2 ND ug/L 3.0 0.17 1 10/05/18 05:48 74-97-5 ND ug/L 1.0 0.18 1 10/05/18 05:48 75-27-4 ND ug/L 3.0 0.26 1 10/05/18 05:48 75-25-2 ND ug/L 10.0 0.29 1 10/05/18 05:48 74-83-9 ND ug/L 100 0.96 1 10/05/18 05:48 78-93-3 ND ug/L 100 1.2 1 10/05/18 05:48 75-15-0 ND ug/L 1.0 0.25 1 10/05/18 05:48 56-23-5 ND ug/L 3.0 0.23 1 10/05/18 05:48 108-90-7 ND ug/L 10.0 0.54 1 10/05/18 05:48 75-00-3 ND ug/L 5.0 0.14 1 10/05/18 05:48 67-66-3 ND ug/L 1.0 0.11 1 10/05/18 05:48 74-87-3 ND ug/L 13.0 2.0 1 10/05/18 05:48 96-12-8 ND ug/L 3.0 0.21 1 10/05/18 05:48 124-48-1 ND ug/L 1.0 0.27 1 10/05/18 05:48 106-93-4 ND ug/L 10.0 0.21 1 10/05/18 05:48 74-95-3 ND ug/L 5.0 0.30 1 10/05/18 05:48 95-50-1 ND ug/L 1.0 0.33 1 10/05/18 05:48 106-46-7 ND ug/L 100 1.0 1 10/05/18 05:48 110-57-6 ND ug/L 5.0 0.32 1 10/05/18 05:48 75-34-3 ND ug/L 1.0 0.24 1 10/05/18 05:48 107-06-2 ND ug/L 5.0 0.56 1 10/05/18 05:48 75-35-4 ND ug/L 5.0 0.19 1 10/05/18 05:48 156-59-2 ND ug/L 5.0 0.49 1 10/05/18 05:48 156-60-5 ND ug/L 1.0 0.27 1 10/05/18 05:48 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 23 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Unit 2 Resample Pace Project No.: 92402129 Sample: Field Blank Lab ID: 92402129002 Collected: 10/03/18 14:50 Received: 10/04/18 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 10/18/2018 04:45 PM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 100 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 3.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 1.0 ND ug/L 5.0 103 % 70-130 91 % 70-130 107 % 70-130 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 105 % 50-150 110 % 50-150 0.13 1 10/05/18 05:48 10061-01-5 0.26 1 10/05/18 05:48 10061-02-6 0.30 1 10/05/18 05:48 100-41-4 0.46 1 10/05/18 05:48 591-78-6 0.32 1 10/05/18 05:48 74-88-4 0.97 1 10/05/18 05:48 75-09-2 0.33 1 10/05/18 05:48 108-10-1 0.26 1 10/05/18 05:48 100-42-5 0.33 1 10/05/18 05:48 630-20-6 0.40 1 10/05/18 05:48 79-34-5 0.46 1 10/05/18 05:48 127-18-4 0.26 1 10/05/18 05:48 108-88-3 0.48 1 10/05/18 05:48 71-55-6 0.29 1 10/05/18 05:48 79-00-5 0.47 1 10/05/18 05:48 79-01-6 0.20 1 10/05/18 05:48 75-69-4 0.41 1 10/05/18 05:48 96-18-4 0.35 1 10/05/18 05:48 108-05-4 0.62 1 10/05/18 05:48 75-01-4 0.66 1 10/05/18 05:48 1330-20-7 1 10/05/18 05:48 460-00-4 1 10/05/18 05:48 17060-07-0 1 10/05/18 05:48 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 10/17/18 12:11 123-91-1 10/ 17/ 18 12:11 17060-07-0 10/ 17/ 18 12:11 2037-26-5 Page 9 of 23 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 2 Resample Pace Project No.: 92402129 QC Batch: 434565 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92402129001, 92402129002 METHOD BLANK: 2393050 Associated Lab Samples: 92402129001, 92402129002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 6.0 3.9 10/05/1817:12 Arsenic ug/L ND 10.0 5.0 10/05/1817:12 Barium ug/L ND 100 2.5 10/05/1817:12 Beryllium ug/L ND 1.0 0.50 10/05/1817:12 Cadmium ug/L ND 1.0 0.50 10/05/1817:12 Chromium ug/L ND 10.0 2.5 10/05/1817:12 Cobalt ug/L ND 10.0 2.5 10/05/1817:12 Copper ug/L ND 10.0 2.5 10/05/1817:12 Lead ug/L ND 10.0 2.5 10/05/1817:12 Nickel ug/L ND 50.0 2.5 10/05/1817:12 Selenium ug/L ND 10.0 5.0 10/05/1817:12 Silver ug/L ND 10.0 2.5 10/05/1817:12 Vanadium ug/L ND 25.0 2.5 10/05/1817:12 Zinc ug/L ND 10.0 5.0 10/05/1817:12 LABORATORY CONTROL SAMPLE: Parameter 2393051 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 488 98 80-120 Arsenic ug/L 500 476 95 80-120 Barium ug/L 500 504 101 80-120 Beryllium ug/L 500 509 102 80-120 Cadmium ug/L 500 486 97 80-120 Chromium ug/L 500 490 98 80-120 Cobalt ug/L 500 485 97 80-120 Copper ug/L 500 504 101 80-120 Lead ug/L 500 478 96 80-120 Nickel ug/L 500 484 97 80-120 Selenium ug/L 500 466 93 80-120 Silver ug/L 250 247 99 80-120 Vanadium ug/L 500 490 98 80-120 Zinc ug/L 500 476 95 80-120 Qualifiers Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2393052 2393053 MS MSD 92402028001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 507 507 101 101 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/18/2018 04:45 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 23 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 2 Pace Project No.: 92402129 Resample MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2393052 2393053 MS MSD 92402028001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 506 506 99 99 75-125 0 20 Barium ug/L 184 500 500 708 712 105 105 75-125 0 20 Beryllium ug/L ND 500 500 533 536 107 107 75-125 0 20 Cadmium ug/L ND 500 500 509 509 102 102 75-125 0 20 Chromium ug/L 82.8 500 500 592 595 102 102 75-125 1 20 Cobalt ug/L 35.1 500 500 522 523 97 98 75-125 0 20 Copper ug/L 44.4 500 500 565 571 104 105 75-125 1 20 Lead ug/L ND 500 500 488 487 97 97 75-125 0 20 Nickel ug/L 58.1 500 500 541 542 96 97 75-125 0 20 Selenium ug/L ND 500 500 500 498 100 100 75-125 1 20 Silver ug/L ND 250 250 262 263 105 105 75-125 0 20 Vanadium ug/L 50.8 500 500 572 577 104 105 75-125 1 20 Zinc ug/L 33.8 500 500 518 520 97 97 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/18/2018 04:45 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 23 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 2 Resample Pace Project No.: 92402129 QC Batch: 434568 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92402129001, 92402129002 METHOD BLANK: 2393062 Matrix: Water Associated Lab Samples: 92402129001, 92402129002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 5.5 0.020 10/05/1814:49 LABORATORY CONTROL SAMPLE: 2393063 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 9.7 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2393064 2393065 MS MSD 92402129001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.3 10.1 103 101 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/18/2018 04:45 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 23 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 2 Resample Pace Project No.: 92402129 QC Batch: 434528 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill Associated Lab Samples: 92402129001, 92402129002 METHOD BLANK: 2392994 Associated Lab Samples: 92402129001, 92402129002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.33 10/04/18 22:48 1,1,1-Trichloroethane ug/L ND 1.0 0.48 10/04/18 22:48 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.40 10/04/18 22:48 1,1,2-Trichloroethane ug/L ND 1.0 0.29 10/04/18 22:48 1,1-Dichloroethane ug/L ND 5.0 0.32 10/04/18 22:48 1,1-Dichloroethene ug/L ND 5.0 0.56 10/04/18 22:48 1,2,3-Trichloropropane ug/L ND 1.0 0.41 10/04/18 22:48 1,2-Dibromo-3-chloropropane ug/L ND 13.0 2.0 10/04/18 22:48 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 10/04/18 22:48 1,2-Dichlorobenzene ug/L ND 5.0 0.30 10/04/18 22:48 1,2-Dichloroethane ug/L ND 1.0 0.24 10/04/18 22:48 1,2-Dichloropropane ug/L ND 1.0 0.27 10/04/18 22:48 1,4-Dichlorobenzene ug/L ND 1.0 0.33 10/04/18 22:48 2-Butanone (MEK) ug/L ND 100 0.96 10/04/18 22:48 2-Hexanone ug/L ND 50.0 0.46 10/04/18 22:48 4-Methyl-2-pentanone (MIBK) ug/L ND 100 0.33 10/04/18 22:48 Acetone ug/L ND 100 10.0 10/04/18 22:48 Acrylonitrile ug/L ND 200 1.9 10/04/18 22:48 Benzene ug/L ND 1.0 0.25 10/04/18 22:48 Bromochloromethane ug/L ND 3.0 0.17 10/04/18 22:48 Bromodichloromethane ug/L ND 1.0 0.18 10/04/18 22:48 Bromoform ug/L ND 3.0 0.26 10/04/18 22:48 Bromomethane ug/L ND 10.0 0.29 10/04/18 22:48 Carbon disulfide ug/L ND 100 1.2 10/04/18 22:48 Carbon tetrachloride ug/L ND 1.0 0.25 10/04/18 22:48 Chlorobenzene ug/L ND 3.0 0.23 10/04/18 22:48 Chloroethane ug/L ND 10.0 0.54 10/04/18 22:48 Chloroform ug/L ND 5.0 0.14 10/04/18 22:48 Chloromethane ug/L ND 1.0 0.11 10/04/18 22:48 cis-1,2-Dichloroethene ug/L ND 5.0 0.19 10/04/18 22:48 cis-1,3-Dichloropropene ug/L ND 1.0 0.13 10/04/18 22:48 Dibromochloromethane ug/L ND 3.0 0.21 10/04/18 22:48 Dibromomethane ug/L ND 10.0 0.21 10/04/18 22:48 Ethylbenzene ug/L ND 1.0 0.30 10/04/18 22:48 lodomethane ug/L 0.53J 10.0 0.32 10/04/18 22:48 Methylene Chloride ug/L ND 1.0 0.97 10/04/18 22:48 Styrene ug/L ND 1.0 0.26 10/04/18 22:48 Tetrachloroethene ug/L ND 1.0 0.46 10/04/18 22:48 Toluene ug/L ND 1.0 0.26 10/04/18 22:48 trans-1,2-Dichloroethene ug/L ND 5.0 0.49 10/04/18 22:48 trans- 1,3-Dichloropropene ug/L ND 1.0 0.26 10/04/18 22:48 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/18/2018 04:45 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 23 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 2 Resample Pace Project No.: 92402129 METHOD BLANK: 2392994 Matrix: Water Associated Lab Samples: 92402129001, 92402129002 Blank Reporting Parameter Units Result Limit MDL trans-1,4-Dichloro-2-butene ug/L ND 100 Trichloroethene ug/L ND 1.0 Trichlorofluoromethane ug/L ND 1.0 Vinyl acetate ug/L ND 50.0 Vinyl chloride ug/L ND 1.0 Xylene (Total) ug/L ND 5.0 1,2-Dichloroethane-d4 (S) % 93 70-130 4-Bromofluorobenzene (S) % 103 70-130 Toluene-d8 (S) % 106 70-130 Analyzed 1.0 10/04/18 22:48 0.47 10/04/18 22:48 0.20 10/04/18 22:48 0.35 10/04/18 22:48 0.62 10/04/18 22:48 0.66 10/04/18 22:48 10/04/18 22:48 10/04/18 22:48 10/04/18 22:48 LABORATORY CONTROL SAMPLE: Parameter 2392995 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 48.7 97 80-125 1,1,1-Trichloroethane ug/L 50 49.9 100 71-129 1,1,2,2-Tetrachloroethane ug/L 50 44.2 88 79-124 1,1,2-Trichloroethane ug/L 50 50.4 101 85-125 1,1-Dichloroethane ug/L 50 45.0 90 73-126 1,1-Dichloroethene ug/L 50 47.8 96 66-135 1,2,3-Trichloropropane ug/L 50 45.7 91 75-130 1,2-Dibromo-3-chloropropane ug/L 50 42.8 86 71-133 1,2-Dibromoethane (EDB) ug/L 50 50.7 101 83-124 1,2-Dichlorobenzene ug/L 50 46.5 93 80-133 1,2-Dichloroethane ug/L 50 47.7 95 67-128 1,2-Dichloropropane ug/L 50 52.0 104 75-132 1,4-Dichlorobenzene ug/L 50 47.4 95 78-130 2-Butanone (MEK) ug/L 100 91.7J 92 61-144 2-Hexanone ug/L 100 82.0 82 68-143 4-Methyl-2-pentanone (MIBK) ug/L 100 83.6J 84 72-135 Acetone ug/L 100 85.2J 85 48-146 Acrylonitrile ug/L 250 237 95 40-160 Benzene ug/L 50 50.0 100 80-125 Bromochloromethane ug/L 50 46.5 93 71-125 Bromodichloromethane ug/L 50 46.8 94 78-124 Bromoform ug/L 50 38.6 77 71-128 Bromomethane ug/L 50 34.4 69 40-160 Carbon disulfide ug/L 50 47.3J 95 50-160 Carbon tetrachloride ug/L 50 48.0 96 69-131 Chlorobenzene ug/L 50 47.4 95 81-122 Chloroethane ug/L 50 39.0 78 39-148 Chloroform ug/L 50 51.6 103 73-127 Chloromethane ug/L 50 38.5 77 44-146 cis-1,2-Dichloroethene ug/L 50 47.3 95 74-124 cis-1,3-Dichloropropene ug/L 50 53.3 107 72-132 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/18/2018 04:45 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 23 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 2 Resample Pace Project No.: 92402129 LABORATORY CONTROL SAMPLE: 2392995 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Dibromochloromethane ug/L 50 49.0 98 78-125 Dibromomethane ug/L 50 46.7 93 82-120 Ethylbenzene ug/L 50 45.9 92 79-121 lodomethane ug/L 100 79.4 79 39-154 Methylene Chloride ug/L 50 46.8 94 64-133 Styrene ug/L 50 45.8 92 84-126 Tetrachloroethene ug/L 50 49.0 98 78-122 Toluene ug/L 50 45.0 90 80-121 trans-1,2-Dichloroethene ug/L 50 47.7 95 71-127 trans- 1,3-Dichloropropene ug/L 50 49.9 100 69-141 trans-1,4-Dichloro-2-butene ug/L 50 32.9J 66 40-160 Trichloroethene ug/L 50 54.7 109 78-122 Trichlorofluoromethane ug/L 50 46.6 93 53-137 Vinyl acetate ug/L 100 101 101 40-160 Vinyl chloride ug/L 50 53.2 106 58-137 Xylene (Total) ug/L 150 139 93 81-126 1,2-Dichloroethane-d4 (S) % 91 70-130 4-Bromofluorobenzene (S) % 97 70-130 Toluene-d8 (S) % 97 70-130 MATRIX SPIKE SAMPLE: 2392997 92402129001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 20.1 100 70-130 1,1,1-Trichloroethane ug/L ND 20 22.2 111 70-130 1,1,2,2-Tetrachloroethane ug/L ND 20 18.7 93 70-130 1,1,2-Trichloroethane ug/L ND 20 20.4 102 70-130 1,1-Dichloroethane ug/L ND 20 20.6 103 70-130 1,1-Dichloroethene ug/L ND 20 22.9 114 70-166 1,2,3-Trichloropropane ug/L ND 20 19.2 96 70-130 1,2-Dibromo-3-chloropropane ug/L ND 20 16.4 82 70-130 1,2-Dibromoethane (EDB) ug/L ND 20 19.6 98 70-130 1,2-Dichlorobenzene ug/L ND 20 19.3 97 70-130 1,2-Dichloroethane ug/L ND 20 20.3 101 70-130 1,2-Dichloropropane ug/L ND 20 21.1 105 70-130 1,4-Dichlorobenzene ug/L ND 20 19.9 99 70-130 2-Butanone (MEK) ug/L ND 40 34.9J 87 70-130 2-Hexanone ug/L ND 40 35.3J 88 70-130 4-Methyl-2-pentanone (MIBK) ug/L ND 40 36.6J 91 70-130 Acetone ug/L ND 40 36.8J 92 70-130 Acrylonitrile ug/L ND 100 1001 100 70-130 Benzene ug/L ND 20 21.8 109 70-148 Bromochloromethane ug/L ND 20 21.5 107 70-130 Bromodichloromethane ug/L ND 20 19.9 100 70-130 Bromoform ug/L ND 20 15.0 75 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/18/2018 04:45 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 23 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 2 Resample Pace Project No.: 92402129 MATRIX SPIKE SAMPLE: Parameter 2392997 Units 92402129001 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Bromomethane ug/L ND 20 13.8 69 70-130 M1 Carbon disulfide ug/L ND 20 20.9J 105 70-130 Carbon tetrachloride ug/L ND 20 21.8 109 70-130 Chlorobenzene ug/L ND 20 21.0 105 70-146 Chloroethane ug/L ND 20 23.8 119 70-130 Chloroform ug/L ND 20 18.8 94 70-130 Chloromethane ug/L ND 20 17.9 90 70-130 cis-1,2-Dichloroethene ug/L ND 20 21.2 106 70-130 cis-1,3-Dichloropropene ug/L ND 20 20.1 100 70-130 Dibromochloromethane ug/L ND 20 18.3 91 70-130 Dibromomethane ug/L ND 20 20.4 102 70-130 Ethylbenzene ug/L ND 20 21.1 106 70-130 lodomethane ug/L ND 40 20.6 52 70-130 M1 Methylene Chloride ug/L ND 20 17.7 88 70-130 Styrene ug/L ND 20 20.9 105 70-130 Tetrachloroethene ug/L ND 20 20.5 103 70-130 Toluene ug/L ND 20 21.4 107 70-155 trans-1,2-Dichloroethene ug/L ND 20 21.4 107 70-130 trans- 1,3-Dichloropropene ug/L ND 20 19.5 98 70-130 trans-1,4-Dichloro-2-butene ug/L ND 20 13.3J 66 70-130 M1 Trichloroethene ug/L ND 20 22.5 113 69-151 Trichlorofluoromethane ug/L ND 20 23.1 116 70-130 Vinyl acetate ug/L ND 40 32.3J 81 70-130 Vinyl chloride ug/L ND 20 24.8 124 70-130 Xylene (Total) ug/L ND 60 63.6 106 70-130 1,2-Dichloroethane-d4 (S) % 91 70-130 4-Bromofluorobenzene (S) % 103 70-130 Toluene-d8 (S) % 100 70-130 SAMPLE DUPLICATE: 2392996 Parameter Units 92402005001 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/18/2018 04:45 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 23 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 2 Resample Pace Project No.: 92402129 SAMPLE DUPLICATE: 2392996 Parameter Units 92402005001 Result 2-Butanone (MEK) ug/L ND 2-Hexanone ug/L ND 4-Methyl-2-pentanone (MIBK) ug/L ND Acetone ug/L ND Acrylonitrile ug/L ND Benzene ug/L ND Bromochloromethane ug/L ND Bromodichloromethane ug/L ND Bromoform ug/L ND Bromomethane ug/L ND Carbon disulfide ug/L ND Carbon tetrachloride ug/L ND Chlorobenzene ug/L ND Chloroethane ug/L ND Chloroform ug/L ND Chloromethane ug/L ND cis-1,2-Dichloroethene ug/L ND cis-1,3-Dichloropropene ug/L ND Dibromochloromethane ug/L ND Dibromomethane ug/L ND Ethylbenzene ug/L ND lodomethane ug/L ND Methylene Chloride ug/L ND Styrene ug/L ND Tetrachloroethene ug/L ND Toluene ug/L ND trans-1,2-Dichloroethene ug/L ND trans- 1,3-Dichloropropene ug/L ND trans-1,4-Dichloro-2-butene ug/L ND Trichloroethene ug/L ND Trichlorofluoromethane ug/L ND Vinyl acetate ug/L ND Vinyl chloride ug/L ND Xylene (Total) ug/L ND 1,2-Dichloroethane-d4 (S) % 94 4-Bromofluorobenzene (S) % 103 Toluene-d8 (S) % 105 Dup Result RPD ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 93 106 106 1 3 2 Max RPD Qualifiers 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/18/2018 04:45 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 23 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 2 Resample Pace Project No.: 92402129 QC Batch: 436645 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 92402129001, 92402129002 METHOD BLANK: 2402221 Matrix: Water Associated Lab Samples: 92402129001, 92402129002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.9 10/17/18 11:52 1,2-Dichloroethane-d4 (S) % 105 50-150 10/17/18 11:52 Toluene-d8 (S) % 115 50-150 10/17/18 11:52 LABORATORY CONTROL SAMPLE: 2402222 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 19.1 95 71-125 1,2-Dichloroethane-d4 (S) % 102 50-150 Toluene-d8(S) % 109 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2402223 2402224 MS MSD 2610107037 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 17.9 19.2 90 96 50-150 7 30 1,2-Dichloroethane-d4 (S) % 105 105 50-150 30 Toluene-d8 (S) % 114 122 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/18/2018 04:45 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 23 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Oxford Unit 2 Resample Pace Project No.: 92402129 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/18/2018 04:45 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 23 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Oxford Unit 2 Resample Pace Project No.: 92402129 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92402129001 3901-MW11 EPA 3010A 434565 EPA6010D 434578 92402129002 Field Blank EPA 3010A 434565 EPA6010D 434578 92402129001 3901-MW11 EPA 3010A 434568 EPA6020B 434581 92402129002 Field Blank EPA 3010A 434568 EPA6020B 434581 92402129001 3901-MW11 EPA 8260B 434528 92402129002 Field Blank EPA 8260B 434528 92402129001 3901-MW11 EPA 8260B Mod. 436645 92402129002 Field Blank EPA 8260B Mod. 436645 Date: 10/18/2018 04:45 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 23 Document Name: Document Revised: February 7, 2018 ace AnalXicaI Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality office Laboratory receiving samples., Asheville ❑ Eden❑ Greenwood ❑ Huntersville © Raleigh❑ Mechanicsville❑ Sample Condition Clien7Ne* upon Receipt Project#: O d240129 Courier: []Fed Ex [-]UPS ❑LISPS ❑ClientI� ❑ Commercial Pace ❑Other: 92402129 Cu9tady-5ta1Pmm"t7❑Yes 0Ncy---SeatsIntact? ❑Yes ❑iVo Date/rnitlals Person Examining Contents: r Packing Material: ❑Bubble Wrap Elliubble Bags ❑None ❑ Other Biological Tissue Frozen? ❑Yes ❑No ❑N/A Thermometer: Type of Ice: ]Wet ❑Blue ❑None ❑IR Gun ID: 92T045 Cooler Temp ('C): 2 r D Correction Factor: Add/Subtract (°C) _0.1 rr /. Temp should be above freezing to 6°C Cooler Temp Corrected (VCI: ❑Samples out of temp criteria. samples on ice, cooling process hasbegun USDA Regulated Soll (p N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, I —IV.. 1—Imn includlne Hawaii and Puerto Rtcol? FlYes nNo Comments/Discrepancy: Chain of Custody Present? E(Yes ❑No []N/A 1. Samples Arrived within Hold Time? f 4es El No ❑N/A 2. Short Hold Time Analysis (e72 hr.)? ❑Yes ❑No ❑N/A 3. Rush Turn Around Time Requested? Dyes 0 No ❑N/A 4. Sufficient Volume? i ies []No ❑N/A S. Correct Containers Used? -Pace Containers Used? Oves vYes []No ❑No ❑NIA ❑N/A 6. Containers Intact? a4s []No ❑]N/A 7. Dissolved analysis: Samples Field Filtered? [:]Yes ❑No i`.IN/A S. Sample Labels Match CDC? -Includes Oate/Tirne/ID/Analysis Matrix: 'Ores []NO ❑N/A 9. Headspace in VOA Vials (>S-Gmm)? []Yes i No []N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? []Yes ❑Yes ❑No []No ']NJA ; N/A 11. COMMENTS/SAMPLE DISCREPANCY Lot If} of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review. Project Manager SRF Review- f� �Y4/L.t3I Date/Time: Field Data Required? Dyes ❑No Date: pQ Date: D C/ Page 21 of 23 Document Name: Oacument Revised: February 7, 2018 . aceAnalytical � Sample Condition Upon Recelpt(SCUR) Page 1 of 2 Document No.: Issuing Authority: F•CAR•CS-033-Rev,05 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottle Project # W®# 92402129 PM: NMG Due Date: 10/18/18 CLIENT: 92-Joyce Eng d a a V aJ E a m a a t' c c U aJ E LA 3 a m Z a Q c n V aJ E M J a m .zr v a c LY w 7 a m w v N v S D ,A S V a E V1 N lil a m _ A v S n m z = u aJ E 2 a m 0 ro Z a7S r a . 4 Z U a E ,fy N /N a m U N n = Q O Z u E U a m 7 m M w °E n 3 u. 3 Z v Z G v CL C d «_ r-i 7 r+ l7 a _ N v q _ U a L E a : .-I S r+ t7 a z 4i c�u N W a = .fl ¢ E vQi N rrl L7 a _ N = a v N Q a = 1%� rr L7 a V A a S JE E ,JN� et la a ? v 2 z Q a E T �7 _ a M t7 a a � 2 O E 0 S a� t9 o z N z > E v h C1 +7 > P. 7 O E 0 7 C5 l'! 7 ? � 2 O E 0 a. Cl Lei 0 2 �i m w N A X Q O > a Z ° U� y Y A Y l7 > �O z «-. i� °1 E N rr v1 a v, D o a J E N �+ri a v N N 2 _ V -M J E Q~ �1 a in 4 C. = 9 E c G g 'V O a ro G = c E o N l7 m u v a9 E 14 Of a 1 2 � J IV 3 4 5 6 7 9 I N 10 11 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amaunt of Preservative added tot # Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form wdl be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 22 of 23 M N O CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.to D- section A Section B Section C Required Client Information: Required Project Information: Invoice Information: Page ' 1 Of 1 Report To: Van Burbach Attention: Jason Falls Copy To: Miguel Vazquez Company Name: Granville County, Solid Waste Company: Joyce Engineering Address: 2211 West Meadowview Rd Greensboro, NC 27407 Address: P.O. Box 906. Oxford NC 27565 Re ulator A enc Email To: .!;1 Purchase Order No. Phone: 336 323-0092 Fax: Client Prciect ID: Oxford Unit 2 resam le State! Location Requested Due Cale1TAT: 10 Da Default Container Order Number: North Carolina Requested Anal sits Filtered YM _ a Taix CODE - o COLLECTED Preservatives D inking Waler DW V n U z O P SAMPLE ID s war WT a to Water W W otivct P &S.W aL b m a w C OL V c� START END F �, Fm- a, o W o One Character per box. Ica wP a w re > > C a her OOr w a } c m oil CL X t Sample Ids must be unique T sun Ts �' ~ z `� a ?` a .� v a a m p" 5 C Q Q 5 ~ a z O alg L a U w DATE TIME DATE TIME v4i = 2 p Z z 1 3901-MW11 wT G iJ14 i5 ly 7 1 IX X X X X Q� 2 Field Blank WT 't1;,�31,. � 7 1 IX X X X X 3 4 5 6 7 8 9 10 11 12 IIL I I I I I I I 1 71 ADDITIONAL COMMENTS - RELINQUISHED BY! AFFILIATION DATE TIME ACCEPTED BY! AFFILIATION DATE TIME SAMPLE CONDITIONS SAMPLER NAME AND SIGNATURE m— o c o � Z c S PRINT Name of SAMPLER: •, ✓ w in a SIGNATURE of SAMPLEflr- DATE Signed: ` _ DATE: 08/ 14-15/ 18 axi YCE EJVGI"=/!#1"C� GROUND WATER SAMPLING LOG Project Name: OXFORD, Granville Co. Project No. /Task No.: 2180175/02 Well ID: MW-7 Sampler(s): R. Mesubed/S. Slebodnik Well Location: Unit 2 area, near power lines Well Diameter: 2 inches Initial Depth to Water (DTW): 24.02 feet Depth to Bottom (DTB): 37.32 feet Water Column Thickness (WCT): 13.30 feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 = 2.16 gallons For 4" Well: WCT X 0.653 = gallons For THREE Well Volumes: WV X 3 = 6.5 gallons Actual Amount Purged/Bailed: 6.5 gallons Purged with: Disposable Bailer Sampled with: Disposable Bailer Depth to Water before Sampling: 24.13 feet Gallons Time Temp. °C DO mg/L Cond. (PS/cm) pH ORP Turb. NTU Initials 0 1419 19.8 5.63 413.8 6.50 49.8 7.57 RM 2.16 1424 19.9 4.49 388.8 6.32 41.9 134.0 RM 4.32 1428 16.7 5.19 366.4 6.34 37.0 437.8 RM 6.5 1433 16.9 5.99 362.5 6.32 33.8 818.2 RM 08/15/18 Before Sampling 1051 17.9 5.40 364.1 6.61 50.9 4.64 RM Comments (weather conditions, odor, color, silt, etc.): The weather was sunny with temperatures in the 60's on 08/14/18 and 08/15/18. The well was purged on 08/14/18 and sampled on 08/15/18. 1 bottle of dis. H+ was sampled with a bladder pump; 5 sec discharge time and 5 sec fill time Signature: cG Date: OSI is/l 8 QA/QC Sign Off: Date: Z- DATE: 8/16/2018 t + &LJ �A= E"C31 V'EEFUrVC3 GROUND WATER SAMPLING LOG Project Name: OXFORD, Granville Co. Project No. /Task No.: 2180175.02 Well ID: MW-8 Sampler(s): S. Slebodnik / R. Mesubed Well Location: _ First right after the scale house, well is on the left Well Diameter: 2 inches Initial Depth to Water (DTW): 3.36 feet Depth to Bottom (DTB): 28.00 feet Water Column Thickness (WCT): 24.64 feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 = 4.01 gallons For 4" Well: WCT X 0.653 = gallons For THREE Well Volumes: WV X 3 = 12.04 gallons Actual Amount Purged/Bailed: 12.04 gallons Purged with: Disposable Bailer Sampled with: Disposable Bailer Depth to Water before Sampling: - feet Gallons Time Temp. (°C) pH Cond. (µS/cm) Turb. (NTU) Initials 0 1528 23.6 7.32 269.3 2.48 RM 4.01 1529 19.9 7.71 239.2 13.65 RM 8.02 1533 20.3 7.82 242.2 56.65 RM 12.04 1538 20.6 7.79 242.4 15.08 RM Before Sampling 1538 20.6 7.79 242.4 15.08 RM Comments (weather conditions, odor, color, silt, etc.): The weather was sunny with temperatures in the 80s on 8/16/2018. 7 bottles sampled immediately after purging. Field blank taken @ 1630 on 08/16/2018. Signature:AdV,&Date: _ C291 t & /19 QA/QC Sign Off: Date: 12-/11,1.1,,,, _ DATE: 8/16/2018 JLJ FEE E"C31"EEF?1"C3 GROUND WATER SAMPLING LOG Project Name: OXFORD, Granville Co. Project No. /Task No.: 2180175.02 Well ID: MW-9 Sampler(s): S. Slebodnik/ R. Mesubed Well Location: East side of unit 2 off the access road Well Diameter: 2 inches Initial Depth to Water (DTW): 9.29 feet Depth to Bottom (DTB): 43.00 feet Water Column Thickness (WCT): 33.71 feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 = 5.49 gallons For 4" Well: WCT X 0.653 = gallons For THREE Well Volumes: WV X 3 = 16.48 gallons Actual Amount Purged/Bailed: 16.48 gallons Purged with: Disposable Bailer Sampled with: Disposable Bailer Depth to Water before Sampling: -- feet Gallons Time Temp. (°C) pH Cond. (µS/cm) Turb. (NTU) Initials 0 1122 20.1 7.35 1 353.1 0.00 RM 5.49 1129 16.6 7.38 323.2 3.28 RM 10.98 1140 16.0 7.47 313.4 24.93 RM 16.48 1157 16.1 7.22 317.5 62.44 RM Before Sampling 1557 20.4 7.18 337.5 2.18 RM Comments (weather conditions, odor, color, silt, etc.): The weather was sunny with temperatures in the 80s on 8/16/2018. Signature: Date: 193? QA/QC Sign Off: Date: IZA46 DATE: 8/16/2018 EJl1GINEER1f1AG GROUND WATER SAMPLING LOG Project Name: OXFORD, Granville Co. Project No. /Task No.: 2180175.02 Well ID: MW-10 Sampler(s): S. Slebodnik / R. Mesubed Well Location: Off NE corner of sed. pond on far side of unit 2 Well Diameter: 2 inches Initial Depth to Water (DTW): 9.61 feet Depth to Bottom (DTB): 31.50 feet Water Column Thickness (WCT): 21.89 feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 = 3.56 gallons For 4" Well: WCT X 0.653 = gallons For THREE Well Volumes: WV X 3 = 10.70 gallons Actual Amount Purged/Bailed: 10.70 gallons Purged with: Disposable Bailer Sampled with: Disposable Bailer Depth to Water before Sampling: 9.66 feet Gallons Time Temp. (°C) pH Cond. (µS/cm) Turb. (NTU) Initials 0 1020 20.4 6.91 151.4 0.82 RM 3.56 1025 18.5 6.02 144.2 8.44 RM 7.12 1029 17.6 6.06 135.9 21.77 RM 10.70 1033 17.6 6.04 130.8 38.94 RM Before Sampling 1546 22.1 5.98 151.1 32.7 RM Comments (weather conditions, odor, color, silt, etc.): The weather was sunny with temperatures in the 80s on 8/16/18. 7 bottles sampled Signature: Date: QA/QC Sign Off: Date: DATE: 08/14-15/18 �hJl� JIIJEEJI JJC-a GROUND WATER SAMPLING LOG Project Name: OXFORD, Granville Co. Project No./Task No.: 2180175.02 Well ID: NES-2S Sampler(s): S. Slebodnik / R. Mesubed Well Location: Near MW-4R Well Diameter: 2 inches Initial Depth to Water (DTW): 6.39 feet Depth to Bottom (DTB): 24.20 feet Water Column Thickness (WCT): 17.81 feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 = 2.90 gallons For 4" Well: WCT X 0.653 = gallons For THREE Well Volumes: WV X 3 = 8.70 gallons Actual Amount Purged/Bailed: 8.70 gallons Purged with: Disposable Bailer Sampled with: Disposable Bailer Depth to Water before Sampling: 6.44 feet Gallons Time Temp. (°C) pH S.U. Cond. Oas/cm) DO (mg/L) ORP (mV) Turb. (NTU) Initials 0 1508 22.6 6.39 135.7 4.43 54.8 143.7 SS 2.90 1514 17.8 6.13 135.4 6.01 60.7 63.35 SS 5.80 1519 17.1 6.16 141.9 6.05 61.7 135.1 SS 8.70 1527 17.4 6.31 144.4 5.51 63.7 64.78 SS 08/15/18 Before Sampling 1416 28.1 6.02 246.8 1.09 49.5 17.35 SS Comments (weather conditions, odor, color, silt, etc.): .): The weather was sunny with temperatures in the 60's on 08/14/18 and 08/15/18. The well was purged on 08/14/18 and sampled on 08/15/18. 1 bottle of dis. H+ was sampled with a bladder pump; 5 sec discharge and 5 sec fill time. Turbidity was 13.86 NTU on the 2°d bailer Signature: A6AS& Date: OS / Is/(I QA/QC Sign Off: , �il�- Date: _ (2,11141 -_ DATE: 8/ 16/2018 ENIMMEEF71r 3 SURFACE WATER MONITORING LOG Project Name: OXFORD, Granville Co. Project/Task No.: 2180175.02 Surface Point ID: SW-3 Sampler(s): S. Slebodnik / R. Mesubed Location: upstream from MW-9 behind Unit 2. Field Parameters: Time of Sampling: 1212 pH: 8.00 Temperature: 24.0 (°C) Conductivity: 76.4 (µS/cm) Turbidity: 22.9 (NTU) Comments/Sample Description (weather conditions, odor, color, silt, etc.): The weather was sunny with temperatures in the 80s on 8/16/18. Signature: Date: OY116 /IS QA/QC Sign Off• Date: % 2- 01 DATE: 8/16/2018 ElvC�llvEE141Pvr� SURFACE WATER MONITORING LOG Project Name: OXFORD, Granville Co. Project/Task No.: 2180175.02 Surface Point ID: SW-4 Sampler(s): S. Slebodnik/ R. Mesubed Location: near where the stream intersects the path behind MW-10 Field Parameters: Time of Sampling: 1040 pH: Temperature: 6.58 22.0 (° C) Conductivity: 126.7 (IS/cm) Turbidity: 15.00 (NTU) Comments/Sample Description (weather conditions, odor, color, silt, etc.): The weather was sunny with temperatures in the 80s on 8/16/18. . h 6 I Appendix 3 Historical Data Tables Table A3-1 Historical Groundwater Elevations Table A3-2 Historical Groundwater Constituents Table A3-3 Historical Surface Water Constituents Table A3-4 Historical Groundwater Field Parameters Table A3-5 Historical Surface Water Field Parameters TABLE A3-1: Historical Groundwater Elevations Background Downgradient Well ID: MW-7 MW-8 MW-9 MW-10 MW-11 NES-2S ell TOC Elev.: 534.24 503.31 487.51 484.92 478.72 477.20 ell Total Depth: 37.32 28.00 43.00 32.90 22.90 24.20 13Jun- 12 513.48 503.31 479.7 477.42 473.20 468.81 22-Aug-12 509.73 500.82 477.97 475.31 471.50 469.36 25-Sep-12 508.45 499.85 478.1 475.06 471.86 469.30 17-Oct-12 507.95 499.90 478 474.23 471.04 467.98 06-Aug-13 514.33 499.92 478.81 475.32 472.80 469.29 25-Feb-14 511.75 499.91 480.34 476.26 473.47 470.28 12-Aug-14 511.98 500.16 479.91 476.54 473.42 470.29 12-Mar-15 516.39 499.99 479.73 476.47 473.66 470.63 18-Aug-15 512.39 499.86 478.41 474.92 472.17 469.25 16-Feb-16 515.79 499.90 481.44 476.37 474.12 471.15 10-Aug-16 514.29 499.82 478.86 475.51 472.91 470.40 14-Feb-17 510.89 496.36 479.36 475.97 472.77 468.85 23-Aug-17 508.84 499.61 477.86 474.74 472.02 469.80 07-Feb-18 505.74 499.86 479.88 476.25 473.54 471.40 14-Aug-18 510.22 499.95 478.22 475.31 473.57* 470.81 Notes: TOC = top of casing. Water levels are measured from TOC. All elevations are in feet above mean sea level. *=resampling event Granville Co. - Oxford Landfill, Unit 2 Joyce Engineering Permit 3901-MSWLF-2012 December 2018 TABLE A3-2: Historical Groundwater Constituents Sample Collection Analyte Date EPA Method DL RL MW-7 MW-8 MW-9 MW-10 MW-11 NES-2S Blanks Inorganics Arsenic 12-Mar-15 EPA 6010 2.5 10.0 4.2 J ND ND ND ND ND ND NC 2L = 10 µg/L 18-Aug-15 10.0 ND ND ND ND ND ND ND 18-Feb-16 EPA 6010 2.5 10.0 ND ND 2.7 J ND 3.9 J ND ND 11-Aug-16 EPA 6010 2.5 10.0 ND ND ND 3.1 J 3.2 J ND ND 14-Feb-17 EPA 6010 5 10.0 ND ND ND ND ND ND ND 23-Aug-17 EPA 6010 5 10.0 ND ND ND ND ND ND ND 6-Feb-18 10.0 ND ND ND ND ND ND ND 16-Aug-18 EPA 601OD 5 10.0 ND ND ND ND NM ND ND Barium 13-Jun-12 100 9.2 J 36.8 J 59.2 J 48.2 J 30.6 J 31.4 J ND 22-Aug-12 100 ND 37.3 J 60.9 J 58.9 J 85 J 28.2 J ND 25-Sep-12 100 10.3 J 40.8 J 64.2 J 72.7 J 43.8 J 30.5 J ND NC 2L = 700 µg/L 17-Oct-12 100 24.2 J 57.3 J 65.1 J 48.7 J 110 28 J ND 6-Aug-13 100 ND 37.1 J 66.5 J 36.8 J 28.5 J 24.8 J ND 25-Feb-14 100 ND 43.6 J 65 J 41.1 J 20.3 J 58.6 J ND 13-Aug-14 EPA 6010 5.0 100 6.2 J 52.7 J 72.7 J 40.7 J 19.7 J 21.7 J ND 12-Mar-15 EPA 6010 2.5 100 9.8 J 47.9 J 76.3 J 49.1 J 19.1 J 35.5 J ND 18-Aug-15 100 11.0 J 45.6 J 72.1 J 43.5 J 20.5 J 31.3 J ND 18-Feb-16 EPA 6010 2.5 100 14.8 J 59.5 J 76.1 J 54.2 J 31.8 J 28.6 J ND 11-Aug-16 EPA 6010 2.5 100 6.2 J 42.9 J 81 J 61.2 J 49.9 J 31.1 J ND 14-Feb-17 EPA 6010 2.5 100 11.8 J 41.9 J 89.0 J 46.2 J 40.8 J 27.6 J ND 23-Aug-17 EPA 6010 2.5 100 25.2 J 42.6 J 126.0 40.8 J 51.4 J 33.8 J ND 6-Feb-18 100 19.3 J 62.6 J 90.7 J 47.1 J 33.9 J 25.4 J ND 16-Aug-18 EPA 601OD 2.5 100 3.8 J 40.3 J 68.9 J 47.5 J NM 25.8 J ND Cadmium 23-Aug-17 EPA 6010 0.5 1.0 ND ND ND 0.56 J ND ND ND NC 2L = 2 µg/L 6-Feb-18 1.0 ND ND ND ND 0.59 J ND ND 16-Aug-18 EPA 601OD 0.5 1.0 ND ND ND ND NM ND ND Granville Co. - Oxford Landfill, Unit 2 Joyce Engineering Permit No. 3901-MSWLF-2012 December 2018 TABLE A3-2: Historical Groundwater Constituents Analyte Sample Collection Date EPA Method DL RL MW-7 MW-8 MW-9 MW-10 MW-11 NES-2S Blanks Chromium 13-Jun-12 10.0 ND ND ND 10.9 ND ND ND 22-Aug-12 10.0 ND ND ND 10.4 18.3 ND ND 25-Sep-12 10.0 ND ND ND 10.3 ND ND ND NC 2L = 10 µg/L 17-Oct-12 10.0 ND ND ND 15.8 20.9 ND ND 6-Aug-13 10.0 ND ND ND ND ND ND ND 25-Feb-14 10.0 ND ND ND ND ND ND ND 13-Aug-14 10.0 ND ND ND 5.1 J ND ND ND 12-Mar-15 EPA 6010 2.5 10.0 ND 3.0 J ND ND ND ND ND 18-Aug-15 10.0 ND ND ND ND ND ND ND 18-Feb-16 EPA 6010 2.5 10.0 ND ND ND ND ND 3.00 J ND 11-Aug-16 EPA 6010 2.5 10.0 2.8 J ND ND 4.3 J 6.3 J ND ND 14-Feb-17 EPA 6010 2.5 10.0 ND ND ND ND 4.4 J ND ND 23-Aug-17 EPA 6010 2.5 10.0 ND ND ND ND 4.5 J ND ND 6-Feb-18 10.0 4.4 J ND ND ND ND ND ND 16-Aug-18 EPA 601OD 2.5 10.0 ND ND ND ND NM ND ND Cobalt 13-Jun-12 10.0 ND ND ND ND ND ND ND 22-Aug-12 10.0 ND ND ND ND ND ND ND 25-Sep-12 10.0 ND ND ND ND ND ND ND GWPS = 1 µg/L 17-Oct-12 10.0 10.3 ND ND ND 12.4 ND ND 6-Aug-13 10.0 ND ND ND ND ND ND ND 25-Feb-14 10.0 ND ND ND ND ND ND ND 13-Aug-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND 12-Mar-15 EPA 6010 2.5 10.0 ND ND ND ND ND 3.6 J ND 18-Aug-15 10.0 ND ND ND ND ND ND ND 18-Feb-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND 11-Aug-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND 14-Feb-17 EPA 6010 2.5 10.0 ND ND ND ND ND 3.2 J ND 23-Aug-17 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND 6-Feb-18 10.0 3.4 J ND ND ND ND ND ND 16-Aug-18 EPA 601OD 2.5 10.0 ND ND ND ND NM ND ND Granville Co. - Oxford Landfill, Unit 2 Joyce Engineering Permit No. 3901-MSWLF-2012 December 2018 TABLE A3-2: Historical Groundwater Constituents Sample Collection Analyte Date EPA Method DL RL MW-7 MW-8 MW-9 MW-10 MW-11 NES-2S Blanks Copper 13-Jun-12 10.0 ND ND ND 46 ND ND ND 22-Aug-12 10.0 ND ND ND 56.2 19.8 ND ND 25-Sep-12 10.0 7.4 J ND ND 63.6 5.7 J ND ND NC 2L = 1,000 µg/L 17-00-12 10.0 19.9 7.6 J ND 35.5 23.1 ND ND 6-Aug-13 10.0 ND ND ND ND ND ND ND 25-Feb-14 10.0 ND ND ND 7.9 J ND ND ND 13-Aug-14 EPA 6010 5.0 10.0 ND 11.6 ND 13.4 ND ND ND 12-Mar-15 EPA 6010 2.5 10.0 ND 47.0 ND 6.0 J ND 3.3 J ND 18-Aug-15 10.0 2.8 J 26.6 ND 12.3 ND 4.3 1 ND 18-Feb-16 EPA 6010 2.5 10.0 ND 7.8 J ND ND ND ND ND I I-Aug-16 EPA 6010 2.5 10.0 ND 30.7 ND 14.6 4.5 J 2.7 J ND 14-Feb-17 EPA 6010 2.5 10.0 ND 16.6 3.2 J 9.9 J 4.9 J 3.9 J ND 23-Aug-17 EPA 6010 2.5 10.0 8.8 J 6.4 J ND 6.4 J 4.5 J ND ND 6-Feb-18 10.0 18.6 133 3.7 J 5.4 J ND ND ND 16-Aug-18 EPA 601 OD 2.5 10.0 ND 24.7 ND 3.6 J NM ND ND Iron 6-Feb-18 300 9990 1500 1190 1670 1630 353 ND 16-Aug-18 EPA 6010D 25.0 300 340 --- --- --- NM --- 27.8 J NC 2L = 300 µg/L (2/5/10) Lead 14-Feb-17 EPA 6010 2.5 10.0 ND ND ND ND 2.9 J ND ND NC 2L= 15 µg/L 23-Aug-17 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND 6-Feb-18 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND 16-Aug-18 EPA 6010 2.5 10.0 ND ND ND ND NM ND ND Manganese 6-Feb-18 50.0 241 394 53.0 25.8 J 410 411 ND 16-Aug-18 EPA 6010D 2.5 50.0 6.7 J --- --- --- NM --- ND NC 2L = 50 µg/L (2/5/10) Nickel 13-Jun-12 50.0 ND ND ND ND ND ND ND 22-Aug-12 50.0 ND ND ND ND 6.1 J ND ND 25-Sep-12 50.0 ND ND ND ND ND ND ND NC 2L = 100 µg/L 17-Oct-12 50.0 ND ND ND 6.9 J 8.9 J ND ND 6-Aug-13 50.0 ND ND ND ND ND ND ND 25-Feb-14 50.0 ND ND ND ND ND ND ND 13-Aug-14 EPA 6010 5.0 50.0 ND ND ND ND ND ND ND 12-Mar-15 EPA 6010 2.5 50.0 ND ND ND ND ND ND ND 18-Aug-15 50.0 ND ND ND ND 2.7 J ND ND 18-Feb-16 EPA 6010 2.5 50.0 ND ND ND ND 2.9 J ND ND 11-Aug-16 EPA 6010 2.5 50.0 ND ND ND ND 6.2 J ND ND 14-Feb-17 EPA 6010 2.5 50.0 ND ND ND ND 5.2 J ND ND 23-Aug-17 EPA 6010 2.5 50.0 5.2 J ND ND 2.8 J 5.8 J ND ND 6-Feb-18 50.0 5.9 J ND ND ND 3.4 J ND ND 16-Aug-18 EPA 6010D 2.5 50.0 ND ND ND ND NM ND ND Granville Co. - Oxford Landfill, Unit 2 Joyce Engineering Permit No. 3901-MSWLF-2012 December 2018 TABLE A3-2: Historical Groundwater Constituents Sample Collection Analyte Date EPA Method DL RL MW-7 MW-8 MW-9 MW-10 MW-11 NES-2S Blanks Thallium 13-Jun-12 5.5 ND ND ND ND ND ND ND 22-Aug-12 5.5 ND 6.8 6.8 ND ND ND ND 25-Sep-12 5.5 ND ND ND ND ND ND ND GWPS = 0.28 µg/L 17-Oct-12 5.5 ND ND ND ND ND ND ND 6-Aug-13 5.5 ND ND ND ND ND ND ND 25-Feb-14 5.5 ND ND ND ND ND ND ND 13-Aug-14 EPA 6010 5.4 5.5 ND ND ND ND ND ND ND 12-Mar-15 EPA 6010 5.0 5.5 ND ND ND ND ND ND ND 18-Aug-15 5.5 ND ND ND ND ND ND ND 18-Feb-16 EPA 6010 5.0 5.5 ND ND ND ND ND ND ND 11-Aug-16 EPA 6010 5.0 5.5 ND ND ND ND ND ND ND 14-Feb-17 EPA 6020B 0.0 5.5 0.039 J 0.059 J ND ND ND ND ND 23-Aug-17 EPA 6020B 0.0 5.5 0.04 J 0.044 J ND ND 0.021 J ND ND 6-Feb-18 0.10 ND 0.034 J ND ND ND ND ND 16-Aug-18 EPA 6020B 0.02 5.50 ND ND ND ND NM ND ND Vanadium 13-Jun-12 25.0 5.2 J ND ND 27.8 17.3 J 11 J ND 22-Aug-12 25.0 ND ND ND 30.2 69.5 9 J ND 25-Sep-12 25.0 8.3 J ND ND 33.4 16.5 J 8.2 J ND GWPS = 0.3 µg/L 17-Oct-12 25.0 29.7 ND ND 19.5 J 63.8 6.2 J ND 6-Aug-13 25.0 ND ND ND ND 9.2 J ND ND 25-Feb-14 25.0 ND ND ND 10.2 J ND ND ND 13-Aug-14 EPA 6010 5.00 25.0 ND ND ND 11.8 J ND ND ND 12-Mar-15 EPA 6010 2.50 25.0 ND 4.4 J 7.3 J 5.0 J ND 6.7 J ND 18-Aug-15 25.0 6.1 J ND ND 6.5 J 3.6 J 9.1 J ND 18-Feb-16 EPA 6010 2.50 25.0 ND 2.9 J ND ND ND ND ND 11-Aug-16 EPA 6010 2.50 25.0 ND ND 5.8 J 10.0 J 14.3 J 6.6 J ND 14-Feb-17 EPA 6010 2.50 25.0 ND ND 5.2 J 4.0 J 9.1 J 5.4 J ND 23-Aug-17 EPA 6010 2.50 25.0 18.6 J ND 2.6 J 4.6 J 11.9 J 6.4 J ND 6-Feb-18 25.0 23.5 J 3.4 J 4.4 J 4.7 J 3.3 J ND ND 16-Aug-18 EPA 601OD 2.5 25.0 ND ND ND 2.9 J NM 2.5 J ND Granville Co. - Oxford Landfill, Unit 2 Joyce Engineering Permit No. 3901-MSWLF-2012 December 2018 TABLE A3-2: Historical Groundwater Constituents Sample Collection Analyte Date EPA Method DL RL MW-7 MW-8 MW-9 MW-10 MW-11 NES-2S Blanks Zinc 13-Jun-12 10.0 ND ND ND 10.5 ND ND ND 22-Aug-12 10.0 ND ND 32 31 21.9 10.6 ND 25-Sep-12 10.0 11.7 ND ND 14.8 ND ND ND NC 2L = 1,000 µg/L 17-00-12 10.0 32.5 ND ND 10.5 29 ND ND 6-Aug-13 10.0 ND ND ND ND ND ND ND 25-Feb-14 10.0 ND ND ND ND ND ND ND 13-Aug-14 EPA 6010 10-Jan-00 10.0 ND ND ND ND ND ND ND 12-Mar-15 EPA 6010 5-Jan-00 10.0 9.8 B 10.9 B 10.7 B 8.7 B 7.8 B 9.9 B 6.1 J 18-Aug-15 10.0 8.9 B ND ND ND ND 5.2 B 11.5 J 18-Feb-16 EPA 6010 5-Jan-00 10.0 ND 13.1 ND ND ND 8.6 J ND 11-Aug-16 EPA 6010 5-Jan-00 10.0 7.2 J 5.4 J ND 19.5 11.7 8.7 J ND 14-Feb-17 EPA 6010 5-Jan-00 10.0 7.0 J 6.0 J 5.4 J 5.3 J 8.3 J 6.0 J ND 23-Aug-17 EPA 6010 5-Jan-00 10.0 18.0 ND 6.3 J 5.1 J 15.5 6.9 J ND 6-Feb-18 10.0 ND ND ND ND ND ND ND 16-Aug-18 EPA 601 OD 5 10.0 ND ND ND ND NM ND ND ORGANICS cis-1,2-Dichloroethene NC 2L = 70 µg/L 18-Aug-15 5.0 0.71 J 0.36 J ND ND ND ND ND 18-Feb-16 18-Feb-16 5.0 5.0 ND ND ND ND ND ND ND 11-Aug-16 11-Aug-16 5.0 5.0 ND ND ND ND ND ND ND 14-Feb-17 EPA 8260 0.2 5.0 ND ND ND ND ND ND ND 23-Aug-17 EPA 8260 0.2 5.0 ND ND ND ND ND ND ND 6-Feb-18 5.0 ND ND ND ND ND ND ND 16-Aug-18 EPA 8260B 0.19 5.0 ND ND ND ND NM ND ND Methylene Chloride 14-Feb-17 EPA 8260 1.0 1.0 ND ND ND ND ND ND 1.0 23-Aug-17 EPA 8260 1.0 1.0 ND ND ND ND ND ND 2.7 NC 2L- 3.0 µg/L 6-Feb-18 1.0 ND ND ND ND ND ND ND 16-Aug-18 EPA 8260B 0.97 1.0 ND ND ND ND NM ND ND Granville Co. - Oxford Landfill, Unit 2 Joyce Engineering Permit No. 3901-MSWLF-2012 December 2018 TABLE A3-2: Historical Groundwater Constituents Analyte Sample Collection Date EPA Method DL RL 1"W-7 MW-8 MW-9 MW-10 MW-11 NES-2S Blanks Trichlorofluoromethane 13-Jun-12 1.0 ND ND ND ND 0.8 B 0.85 B 0.74 J 22-Aug-12 1.0 ND ND ND ND ND ND ND NC 2L = 2,000 µg/L 25-Sep-12 1.0 ND ND ND ND ND ND ND 17-00-12 1.0 ND ND ND ND ND ND ND 6-Aug-13 1.0 ND ND ND ND ND ND ND 25-Feb-14 1.0 ND ND ND ND ND ND ND 13-Aug-14 2.0 ND ND ND ND ND ND ND 12-Mar-15 EPA 8260 0.2 1.0 ND ND ND ND ND ND ND 18-Aug-15 1.0 ND ND ND ND ND ND ND 18-Feb-16 EPA 8260 0.2 1.0 ND ND ND ND ND ND ND 11-Aug-16 EPA 8260 0.2 1.0 ND ND ND ND ND ND ND 14-Feb-17 EPA 8260 0.2 1.0 ND ND ND ND ND ND ND 23-Aug-17 EPA 8260 0.2 1.0 ND ND ND ND ND ND ND 6-Feb-18 1.0 ND ND ND ND ND ND ND 16-Aug-18 EPA 8260B 0.2 1.0 ND ND ND ND NM ND ND 1,4-Dioxane (p-Dioxane) 16-Aug-18 PA 8260B Mod 1.9 2.0 ND ND ND ND NM ND ND NC2L = 3 µg/L I r - - - - - - - - - Notes: All concentrations are in micrograms per liter (µg/L). RL = Reporting Limit (SWSL for December 2006 - present). DL = Laboratory detection limit. J = Estimated value between the DL and the RL. B = Blank -qualified data; result is expected to be biased high based on concentrations in the blanks. ND = Not detected above laboratory reporting limit. NC 2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202. GWPS = Groundwater Protection Standards established by the DENR Solid Waste Section (SWS). When the NC 2L has not been established, the GWPS will be used. Bold values for groundwater are above the NC 2L Standards or GWPS. --- = Well was not monitored and/or not reported. * Detections of c-1,2-DCE in MW-7 and MW-8 in August 2015 are suspect. The sample collected from MW-7 at the same time for Unit 1 showed no detected c-1,2-DCE. Granville Co. - Oxford Landfill, Unit 2 Joyce Engineering Permit No. 3901-MSWLF-2012 December 2018 TABLE A3-3: Historical Surface Water Constituents Sample L Collection Analyte Date EPA Method SW-1 SW-2 SW-3 SW-4 Blanks Inorganics Arsenic 12-Mar-15 EPA 6010 2.5 10.0 4.9 J 2.7 J ND ND ND NC 2B = 50 (05/01/07) 19-Aug-15 2.5 10.0 ND Dry ND ND ND 18-Feb-16 EPA 6010 2.5 10.0 ND ND ND ND ND 11-Aug-16 EPA 6010 2.5 10.0 6.8 J 7.3 J ND ND ND 14-Feb-17 EPA 6010 5.0 10.0 ND ND ND ND ND 23-Aug-17 EPA 6010 5.0 10.0 ND Dry ND ND ND 6-Feb-18 5.0 10.0 ND ND ND ND ND 16-Aug-18 EPA 601OD 5.0 10.0 ND ND ND ND ND Barium 13-Aug-14 EPA 6010 5.0 100 47.4 J 43.9 J 22.1 J 33.9 J ND 12-Mar-15 EPA 6010 2.5 100 28.5 J 42 J 22.5 J 24.6 J ND NC 2B = NE (05/01/07) 19-Aug-15 2.5 100 37 J Dry 23.9 J 32.7 J ND 18-Feb-16 EPA 6010 2.5 100 58.2 J 55.0 J 22.0 J 26.3 J ND 11-Aug-16 EPA 6010 2.5 100 175 152 23.4 J 26.5 J ND 14-Feb-17 EPA 6010 2.5 100 285 38.2 J 18.6 J 21.4 J ND 23-Aug-17 EPA 6010 2.5 100 31.6 J Dry 32.3 J 33.3 J ND 6-Feb-18 2.5 100 22.4 J 33.5 J 23.7 J 32.3 J ND 16-Aug-18 EPA 6010D 2.5 100 19.1 J 28.3 J 24.2 J 38.2 J ND Beryllium 11-Aug-16 EPA 6010 0.50 1.0 1.9 1.7 ND ND ND 14-Feb-17 EPA 6010 0.50 1.0 ND ND ND ND ND NC 2B 6.5 µg/L 23-Aug-17 EPA 6010 0.50 1.0 ND Dry ND ND ND 6-Feb-18 0.50 1.0 ND ND ND ND ND 16-Aug-18 EPA 601OD 0.50 1.0 ND ND ND ND ND Chromium 13-Aug-14 EPA 6010 5.0 10.0 10.8 10 J ND ND ND 12-Mar-15 EPA 6010 2.5 10.0 4.0 J 3.1 J ND 2.6 J ND NC 2B = 50 µg/L (05/01/07) 2.5 10.0 ND ND ND ND 19-Aug -15 Dr Y 18-Feb-16 EPA 6010 2.5 10.0 ND ND ND ND ND NC 2B = 24 µg/L (3/01/16) 2.5 10.0 63.0 5.2 J ND ND 11-Aug-16 EPA 6010 55.1 13-Sep-16 2.5 10.0 13.8 (ND) DRY NS NS ND 14-Feb-17 EPA 6010 2.5 10.0 6.1 J 7.2 J 3.0 J ND ND 23-Aug-17 EPA 6010 2.5 10.0 7.0 J Dry ND ND ND 6-Feb-18 2.5 10.0 2.8 J 5.4 J ND 2.7 J ND 16-Aug-18 EPA 6010D 2.5 10.0 ND 3.2 J ND ND ND Granville Co. - Oxford Landfill, Unit 2 Joyce Engineering Permit No. 390 1 -MSWLF-2012 December 2018 TABLE A3-3: Historical Surface Water Constituents Sample Collection Analyte Date EPA Method DL RL SW-1 SW-2 SW-3 SW-4 Blanks Cobalt II-Aug-16 EPA 6010 2.5 10.0 16.7 12.7 ND ND ND 14-Feb-17 EPA 6010 2.5 10.0 4.0 J ND ND ND ND 23-Aug-17 EPA 6010 2.5 10.0 ND Dry ND ND ND 6-Feb-18 2.5 10.0 ND ND ND ND ND 16-Aug-18 EPA 6010D 2.5 10.0 ND ND ND ND ND Copper 13-Aug-14 EPA 6010 5.0 10.0 9.6 J 7.7 J ND ND ND 12-Mar-15 EPA 6010 2.5 10.0 3.1 J 2.6 J ND ND ND NC 2B = 7 µg/L (05/01/07) 2.5 10.0 ND ND ND ND 19-Aug-15 Dry 18-Feb-16 EPA 6010 2.5 10.0 6.3 J 5.7 J ND ND ND NC 213 = 2.7 µg/L (3/01/16) 2.5 10.0 39.9 ND ND ND II-Aug-16 EPA 6010 34.5 Resample > 13-Sep-16 2.5 10.0 9.3 (2.5 B) B DRY NS NS 3.5 B 14-Feb-17 EPA 6010 2.5 10.0 5.8 J 5.2 J ND ND ND 23-Aug-17 EPA 6010 2.5 10.0 4.5 J Dry ND ND ND 6-Feb-18 2.5 10.0 6.8 J 8.0 J 2.7 J 3.6 J ND 16-Aug-18 EPA 601OD 2.5 10.0 3.9 J 3.0 J ND ND ND Iron 6-Feb-18 25.0 300 NS NS 1520 2920 ND 16-Aug-18 EPA 6010D 25.0 300 3320 2750 --- --- 27.8 J NC 2L 300 µg/L (2/5/10) Lead 18-Feb-16 EPA 6010 2.5 10.0 4.0 B 2.6 B ND ND 2.7 J NC 213 = 25 (05/01/07) 11-Aug-16 EPA 6010 2.5 10.0 16.6 13.6 ND ND ND Resample > 13-Sep-16 2.5 10.0 4.1 (2.6 J) J DRY NS NS ND 14-Feb-17 EPA 6010 2.5 10.0 2.5 J 2.5 J ND ND ND 23-Aug-17 EPA 6010 2.5 10.0 2.5 J Dry ND ND ND 6-Feb-18 2.5 10.0 ND ND ND ND ND 16-Aug-18 EPA 601OD 2.5 10.0 ND ND ND ND ND Manganese 6-Feb-18 2.5 50.0 NS NS 11.6 J 25.8 J ND 16-Aug-18 EPA 601OD 2.5 50.0 176 45.2 J --- --- ND NC 2L = 50 µg/L (2/5/10) Granville Co. - Oxford Landfill, Unit 2 Joyce Engineering Permit No. 390 1 -MSWLF-2012 December 2018 TABLE A3-3: Historical Surface Water Constituents Sample Collection Analyte Date EPA Method DL RL SW-1 SW-2 SW-3 SW-4 Blanks Nickel 13-Aug-14 EPA 6010 5.0 50.0 7.5 J 5.4 J ND ND ND 12-Mar-15 EPA 6010 2.5 50.0 3 J 2.8 J ND ND ND NC 2B = 88 µg/L (05/01/07) 19-Aug-15 2.5 50.0 ND Dry ND ND ND 18-Feb-16 EPA 6010 2.5 50.0 3.3 J 3.0 J ND ND ND 11-Aug-16 EPA 6010 2.5 50.0 22.8 J 19.4 J 2.8 J ND ND 14-Feb-17 EPA 6010 2.5 50.0 4.2 J 4.1 J ND ND ND 23-Aug-17 EPA 6010 2.5 50.0 3.7 J Dry ND ND ND 6-Feb-18 2.5 50.0 ND 3.2 J ND ND ND 16-Aug-18 EPA 6010D 2.5 50.0 ND ND ND ND ND Selenium 11-Aug-16 EPA 6010 5.0 10.0 ND 6.0 J ND ND ND 14-Feb-17 EPA 6010 5.0 10.0 ND ND ND ND ND 23-Aug-17 EPA 6010 5.0 10.0 ND Dry ND ND ND 6-Feb-18 5.0 10.0 ND ND ND ND ND 16-Aug-18 EPA 6010D 5.0 10.0 ND ND ND ND ND Vanadium 13-Aug-14 EPA 6010 5.0 25.0 18.0 J 18.2 J ND 9.3 J ND 12-Mar-15 EPA 6010 2.5 25.0 7.8 J 8.3 J 3.1 J 6.3 J ND NC 2B = NE (05/01/07) 19-Aug-15 2.5 25.0 2.8 J Dry 2.7 J 4.3 J ND 18-Feb-16 EPA 6010 2.5 25.0 6.4 J 6.1 J ND ND ND 11-Aug-16 EPA 6010 2.5 25.0 160 144 ND 2.7 J ND 14-Feb-17 EPA 6010 2.5 25.0 18.2 J 20.8 J ND ND ND 23-Aug-17 EPA 6010 2.5 25.0 20.5 J Dry 4.6 J ND ND 6-Feb-18 2.5 25.0 6.9 J 14.4 J 4.3 J 8.2 J ND 16-Aug-18 EPA 601OD 2.5 25.0 7.6 J 5.8 J 3.7 J ND ND Zinc 13-Aug-14 EPA 6010 5.0 10.0 14.3 ND ND ND ND 12-Mar-15 EPA 6010 5.0 10.0 62.3 11.6 B 8.5 B 10.8 B 6.1 J NC 2B = 50 µg/L (05/01/07) 5.0 10.0 ND ND ND 11.5 J 19-Aug-15 Dry 18-Feb-16 EPA 6010 5.0 10.0 13.0 11.0 ND ND ND NC 2B = 36 µg/L (03/01/16) 5.0 10.0 66.4 13.0 5.6 J ND 11-Aug-16 EPA 6010 54.1 Resample > 13-Sep-16 5.0 10.0 14.5 (5.9 J; B DRY NS NS ND 14-Feb-17 EPA 6010 5.0 10.0 11.0 9.6 J 7.0 J ND ND 23-Aug-17 EPA 6010 5.0 10.0 7.6 J Dry ND ND ND 6-Feb-18 5.0 10.0 9.4 J 6.8 J ND ND ND 16-Aug-18 EPA 6010D 5.0 10.0 6.2 J ND ND ND ND Granville Co. - Oxford Landfill, Unit 2 Joyce Engineering Permit No. 390 1 -MSWLF-2012 December 2018 TABLE A3-3: Historical Surface Water Constituents Analyte Sample Collection Date EPA Method DL RL SW-2 SW-3 SW-4 Blanks 2-Hexanone 11-Aug-16 EPA 8260 0.46 50.0 —&- 1.2 J ND ND ND ND 14-Feb-17 EPA 8260 0.46 50.0 ND ND ND ND ND 23-Aug-17 EPA 8260 0.46 50.0 ND Dry ND ND ND 6-Feb-18 0.46 50.0 ND ND ND ND ND 16-Aug-18 EPA 8260B 0.46 50.0 ND ND ND ND ND 1,4-Dioxane (p-Dioxane) 16-Aug-18 EPA 8260B Mod. 1.90 2.0 ND 4.5 ND ND ND Notes: All concentrations are in micrograms per liter (µg/L). RL = Reporting Limit (SWSL for December 2006 - present). DL = Laboratory detection limit. J = Estimated value between the DL and the RL. B = Blank -qualified data; result is expected to be biased high based on concentrations in the blanks. ND = Not detected above laboratory reporting limit. NS = Not sampled. NR = Not Reported. Dry =Surface water point considered to be dry. NC 2B = North Carolina Surface Water Standards from 15A NCAC 2B. NE = Not established. Bold values for surface water are above the NC 2B. Surface waters are classified as fresh -water aquatic life. 9/13/16 RESAMPLE= Parenthesis indicate Dissolved concentrations. Granville Co. - Oxford Landfill, Unit 2 Joyce Engineering Permit No. 390 1 -MSWLF-2012 December 2018 TABLE A3-4: Historical Groundwater Field Parameters SAMPLE PARAMETER COLLECTION DATE MW-7 MW-8 MW-9 MW-10 MW-11 NES-2S PH 3/12/2015 6.53 7.45 6.96 6.73 6.8 6.5 (S.U.) 8/18/2015 6.27 7.77 6.98 6.01 6.02 5.88 2/18/2016 6.89 7.45 7.11 6.93 6.46 6.13 8/10/2016 4.55 5.51 5.01 5.34 5.31 6.13 2/15/2017 6.52 7.90 7.43 6.04 6.14 6.42 8/23/2017 6.63 7.36 7.47 6.55 6.04 6.65 2/7/2018 6.51 7.68 7.53 6.31 7.00 5.86 8/16/2018 6.61 7.79 7.18 5.98 6.03* 6.02 Temperature 3/12/2015 13.9 14.7 15.6 12.1 12.3 15.9 (°C) 8/18/2015 17.26 19.6 21.62 21.09 19.56 19.09 2/18/2016 12.8 15.6 14.7 12.6 12.1 11.3 8/10/2016 16.70 18.70 15.80 18.40 17.40 18.30 2/15/2017 12.00 14.80 14.70 14.60 13.40 11.60 8/23/2017 16.8 21.0 15.9 17.5 18.2 18.4 2/7/2018 14.9 14.55 15.1 12.8 12.7 11.3 8/16/2018 17.9 20.6 20.4 22.1 22.0* 28.1 Conductivity 3/12/2015 123.4 193.8 285.7 141.2 84.8 114.2 (µS/cm) 8/18/2015 284 282 268 108 89 112 2/18/2016 250 195.8 290.3 166.7 122.9 95.7 8/10/2016 287.10 215.00 249.40 132.10 131.00 123.70 2/15/2017 239.00 182.70 268.40 83.40 108.30 112.40 8/23/2017 297.2 222.2 284.3 89.3 116.4 133.3 2/7/2018 285 187 277 43.0 95.0 107 8/16/2018 364.1 242.4 337.5 151.1 153.0* 246.8 Turbidity 3/12/2015 5.33 15.2 25.1 9.2 9.57 8.75 (NTU) 8/18/2015 22.7 12.84 10.2 10.9 10.0 11.85 2/18/2016 8.25 10.25 11.2 11.25 25.4 8.55 8/10/2016 7.95 11.17 10.25 11.92 15.25 16.41 2/15/2017 4.54 4.44 10.78 9.10 12.45 5.25 8/23/2017 12.7 5.41 5.98 10.8 20.25 9.38 2/7/2018 15.4 16.69 17.05 30.0 27.18 18.06 11 8/16/2018 4.64 15.08 2.10 23.96 13.84* 17.35 Notes: µS/cm = microSemens per centimeter. °C= degrees Centigrade. S.U: Standard Units. NTU = Nephelometric Turbidity Units. *= well unable to be located on 8/16/18- resampled on 10/3/18 Granville Co. - Oxford Landfill, Unit 2 Joyce Engineering Permit No. 3 90 1 -MSWLF-2012 December 2018 TABLE A2-5: Historical Surface Water Field Parameters SAMPLE PARAMETER COLLECTION DATE SW-3 SW-4 pH 3/12/2015 7.25 6.94 (S.U) 8/18/2015 7.55 6.39 2/18/2016 7.35 6.88 8/10/2016 5.63 5.39 2/15/2017 7.01 6.35 8/23/2017 6.96 6.42 2/7/2018 6.75 6.25 8/16/2018 8.00 6.58 Temperature 3/12/2015 13.3 14.4 (°C) 8/18/2015 25.20 23.44 2/18/2016 10.8 10.2 8/10/2016 24.30 23.40 2/15/2017 10.90 6.90 8/23/2017 23.70 23.40 2/7/2018 8.95 8.25 8/16/2018 24.0 22.0 Conductivity 3/12/2015 39.3 46.3 (µS/cm) 8/18/2015 72 88 2/18/2016 33.7 36.4 8/10/2016 53.70 84.90 2/15/2017 51.00 45.70 8/23/2017 72.80 111.10 2/7/2018 40.0 47.0 8/16/2018 76.4 126.7 Turbidity 3/12/2015 17 37.7 (NTU) 8/18/2015 7.87 32.9 2/18/2016 13.1 43.5 8/10/2016 10.05 7.87 2/15/2017 11.70 5.80 8/23/2017 25.71 17.51 2/7/2018 22.45 44.03 11 8/16/2018 22.90 15.00 11 Notes: µS/cm = microSemens per centimeter. °C= degrees Centigrade. S.0 = Standard Units. NTU = Nephelometric Turbidity Units. *= well unable to be located on 8/16/18- resampled on 10/3/18 Granville Co. - Oxford Landfill, Unit 2 Joyce Engineering Permit No. 3 90 1 -MSWLF-2012 December 2018