13005_Tyner St_ Assessment Rpt 2012.08

ADDITIONAL ASSESSMENT REPORT

FORMER AMPLATE, INC. FACILITY
7810, 7820 AND 7842 TYNER STREET
CHARLOTTE, NORTH CAROLINA

Prepared for:
Tyner Street Investments, LLC
601 Minuet Lane
Charlotte, North Carolina 28217

Prepared by:
AWARE Environmental® Inc.
8514 McAlpine Park Dr.
Suite 100
Charlotte, North Carolina 28211

AEI Project No. N510-06
AEI Document No. 51006L001

August 2012
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Prior to conducting the above described work, a Work Plan was prepared and submitted to the
NCDENR – Brownfield Program on May 10, 2012 and approved by the Brownfield Program in
a letter dated May 15, 2012. The additional site assessment work was conducted in accordance
with the approved Work Plan. Soil and groundwater samples were sent to Davis and Floyd, Inc.
located in Greenwood, South Carolina, North Carolina Certification Number 25. Soil gas
samples were sent to Enthalpy Analytical located in Durham North Carolina. Samples were
shipped to the contracted laboratories by overnight courier. Laboratory results for metals in soil
and groundwater were estimated if concentrations were detected between the laboratory method
limits and reporting limits. Laboratory analytical data reports are provided in Attachment A.
Results of this investigation are summarized below. Photographs related to the site project are
provided in Attachment B.

SOIL SAMPLING RESULTS
On June 27, 2012, AEI personnel collected five (5) shallow soil samples (B-1 through B-5) at
locations shown on Figure 2. The soil samples were collected using a stainless steel hand auger
at approximately 1.0 feet below grade. At locations beneath the asphalt parking area (B-4 and B-
5), 4-inch diameter holes were cut through the asphalt using a hammer drill and soils collected
below the asphalt using a hand auger bucket. Soil samples collected were generally red clay.
Samples were placed in laboratory supplied containers and placed in an insulated cooler with ice.
Soil samples were analyzed for total chromium and hexavalent chromium. A summary of the
soil analytical results as well as historical soil sampling results are provided in Table 1 and
Figure 3.

Total chromium was detected in all five samples (B-1 through B-5) ranging between 20.7 mg/kg
and 145 mg/kg, well below industrial preliminary soil remediation goal (PSRGs) of 100,000
mg/kg for chromium III. Hexavalent chromium was detected in one sample, B-1 at 0.142 mg/kg
(estimated). This concentration is below hexavalent chromium’s industrial PSRG of 5.6 mg/kg.

SUMMARY OF JUNE 27, 2012 GROUNDWATER SAMPLING ACTIVITIES
Evaluation of Groundwater Flow
On June 27, 2012, static water levels were measured in on-site wells MW-1, MW-2, MW-3, and
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MW-4 (Table 2). Water table elevations were calculated from this data and a shallow
groundwater potentiometric map was constructed and presented in Figure 4. The potentiometric
map indicates that the shallow groundwater flow is to the north with a horizontal gradient of
approximately 0.014 feet per foot.

Monitoring Well Purge
Based on water levels in each well, well depths and inside casing diameter of 1.0 inches, the
volume of standing water in the monitoring wells were calculated. Using slow pumping rates, all
wells were purged dry using the peristaltic pump. Purge volumes per well were less than 15
ounces each. Because of the low volume produced during purging activities, purge water was
spread on an impermeable surface and allowed to evaporate. Once well purging was completed
and prior to sampling groundwater, field quality measurements were collected from each well
using a Horiba U-22. Field parameters included pH, temperature, conductivity, turbidity,
dissolved oxygen, total dissolved solids (TDS) and oxidation reduction potential (ORP). The
measured field parameters are summarized in Table 3.

Monitoring Well Sampling
Once the wells were purged, groundwater samples were collected using a peristaltic pump for
semi-VOCs and priority metal samples. VOC and hexavalent chromium samples were collected
using a dedicated polyethylene bailer. The samples were transferred to laboratory-supplied
sample containers, and then placed in an insulated cooler with ice.

Groundwater Analytical Results – Metals
Groundwater samples collected from the four (4) monitoring wells (MW-1, MW-2, MW-3, and
MW-4) were analyzed for total and dissolved priority metals (antimony, arsenic, beryllium,
cadmium, chromium, lead, mercury, nickel, selenium, silver, thallium and zinc) via EPA Method
6010C, mercury by EPA Method 7470A and hexavalent chromium by SW846 Method 7196A.
Groundwater samples for dissolved metal analyses were collected in unpreserved plastic
containers and filtered by the contract laboratory prior to analyses.

A summary of groundwater metal analytical data collected by AEI in June 2012 is provided in
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Table 4 and Figure 5. Also included in Figure 5 are results from temporary wells installed and
sampled by CDM Environmental Services, Inc. (CDM) in November 2005 (TW-1 through TW-
7) (Table 5).

The concentrations of the total and dissolved metals detected during the June 2012 sampling
event were significantly lower than those detected during the June 2008 sampling event. The
only metal detected above its 2L Groundwater Standard or Interim Standards during the June
2012 sampling event was thallium. Thallium was detected in well sample MW-1 (considered a
background well) at 3.2 µg/l, above its Interim 2L Standard of 0.2 µg/l. Thallium was also
detected above its Interim 2L Standard in well sample MW-3 at 1.7 µg/l. Hexavalent chromium
was detected in one groundwater sample, MW-3 at 6 µg/l. No 2L Standard has been established
for hexavalent chromium.

Groundwater Analytical Results – Volatile Organic Compounds (VOCs)
Collected groundwater samples were analyzed for VOCs via EPA Method 8260 for each of the
four (4) permanent groundwater monitoring wells located on-site (MW-1, MW-2, MW-3, and
MW-4). A summary of VOC groundwater results are provided in Table 4 and Figure 6. Also
included in Figure 6 are results from temporary wells installed and sampled by CDM
Environmental Services, Inc. (CDM) in November 2005 (TW-1 through TW-7) (Table 5).

Laboratory analytical results for monitoring well MW-1 (upgradient) and MW-3 (downgradient)
did not detect any VOCs above laboratory reportable limits. Historical groundwater results
between 2002 and 2008 also did not identify any VOCs above laboratory reportable limits in
these wells.

The 2012 analytical results from monitoring well MW-2 detected acetone and trichloroethene
(TCE) at concentrations above laboratory reportable limits. Acetone was detected at 4.47 µg/l,
well below its 2L Standard of 6,000 µg/l. TCE was detected at 5.55 µg/l, above its 2L Standard
of 2.8 µg/l. Historically tetrachloroethene (PCE) has also been detected in well MW-2 with
recent concentrations in 2005 and 2008 at 1.2 µg/l and 2.2 µg/l, respectively. PCE was not
detected during the 2012 sampling event above the laboratory reporting limit of 2.0 µg/l. Both
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PCE and TCE concentrations appear to be decreasing with time in well MW-2.

The 2012 analytical results from monitoring well MW-4 identified only PCE above its laboratory
reportable limit. PCE was detected at 5.96 µg/l, above its 2L Standard of 0.7 µg/l. TCE, which
has been historically detected in well MW-4, was not detected above laboratory reporting limit of
2.0 µg/l. PCE concentrations detected in well MW-4 between 1999 and April 2008 ranged
between 16.7 µg/l and 380 µg/l. TCE concentrations during that same time period ranged
between 1.6 µg/l and 340 µg/l. Both PCE and TCE concentrations appear to be decreasing with
time in well MW-4.

Groundwater Analytical Results – Semi-Volatile Organic Compounds (SVOCs)
Collected groundwater samples were analyzed for SVOCs via EPA Method 8270 for each of the
four (4) permanent groundwater monitoring wells located on-site (MW-1, MW-2, MW-3, and
MW-4). A summary of SVOCs groundwater results are provided in Table 4.

The 2012 groundwater sampling results did not detect any target SVOCs above laboratory
reporting limits.

SUB-SLAB SOIL GAS TESTING
The vapor intrusion evaluation work was conducted in accordance with the approved Work Plan.

Temporary Sub Slab Sample Point Installation
To evaluate the potential for vapor intrusion into the Tyner Street facility, four (4) temporary sub
slab vapor points were installed within the facility on June 27, 2012 (Figure 2). Vapor point
locations were placed in areas throughout the building, with two (2) of the locations in areas over
the identified shallow groundwater plume at the former Amplate portion of the building (V-3 and
V-4). The former Amplate portion of the building is currently unoccupied. Sample locations V-1
and V-2 were in portions of the building currently occupied. Vapor point V-1 is located in a
portion of the building used as a church. Reportedly the church uses this building a couple of
times per week. Vapor point V-2 is located in a building used as a remote warehouse; no
warehouse personnel are typically present at the site. No floor drains or sumps were observed in
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the areas of the sub slab vapor point locations. The temporary vapor sampling points were
installed by Troxler Geologic Services, Inc. (Troxler) out of Raleigh, North Carolina. Troxler
used a portable hammer drill to cut 4-inch diameter cores through the concrete at selected
locations (Photograph A). Concrete thicknesses ranged from 4 to 6 inches. Thin gravel layer
and fine sand was encountered beneath the concrete at all four (4) of the core locations (V-1
through V-4). Gravel and sand layer thickness ranged from 1 to 2 inches. At each core hole, a
temporary sample point with a three (3) inch long stainless steel screen (Photograph B) and ¼
inch diameter Teflon tubing was inserted into the gravel/soil beneath the slab and filled with sand
and topped with concrete to approximately 2-inches from the top of the concrete slab
(Photograph C). The wells were initially purged after construction using a MiniRAE 2000
photoionization detector (PID) with flow rate approximately 500 cubic centimeters per minute
(cc/min) (Photograph D). Approximately 5 to 8 liters of air were purged from each well upon
completion.

Sub-Slab Soil Gas Sampling
The installed vapor wells were allowed to cure overnight before conducting sampling activities.
Vapor samples were collected on June 28, 2012. Weather during the sampling event was sunny
with a slight breeze, and temperatures ranged between 81° F to 90° F. The inside air temperature
was approximately 80°F. The most recent precipitation event was on June 24, 2012,
approximately 0.08 inches of rain.

Enthalpy Analytical, Inc. (Enthalpy) in Durham, North Carolina was contracted to perform the
sample analyses. Laboratory analytical reports and chain-of-custody records are provided in
Attachment A. Five (5) 1.4 liter batch certified Summa canisters were provided by the
contracted laboratory to collect the sub slab soil gas samples. Each canister was equipped with a
pressure gauge and flow controller. Prior to conducting sampling, the vapor wells and tubing
were first purged using a photoionization detector (PID) (Photograph D). PID purging typically
lasted 3 to 4 minutes at a rate of 500 milliliters per minute (ml/min).

Once purging was completed the well was evaluated for possible short circuiting from the
surface or leakage from the tubing by placing a plastic cover over each well (Photograph E).
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Helium was placed beneath the plastic cover at concentrations ranging between 20 and 25
percent. Using a Dielectric Model MGD-2002 helium detector with a detection range between
25 ppm to 100 percent, air was drawn from the well at a rate of approximately 500 cc/min for
approximately 5 minutes and monitored for helium. No helium was detected during air purging
operations for vapor wells V-1 though V-4, suggesting these wells were properly sealed. Once a
well was seal tested and purged, a 1.4 liter Summa canister was connected to the well tubing and
the valve opened to collect the air sample (Photograph F). Initial vacuum pressure in each
canister ranged between 27 and 29 inches of mercury. Canister flow control was set at
approximately 130 milliliter per minute. Once the vacuum pressure gauge decreased to
approximately 1 inch of mercury, the canister was disconnected from the well. Time to collect
the sub slab soil gas sample at each well was approximately 13 minutes.

Once sub slab soil gas sampling was completed and the chain-of-custody prepared, the canisters
were delivered to the contract laboratory by courier for analyses.

Sub-Slab Soil Gas Results
A summary of contaminants of concern and analytical results are provided in Table 6 and Figure
7. Analyses of soil gas collected on June 28, 2012 detected twenty-four (24) compounds in the
sub slab vapor samples. Concentrations that were between the method detection limits and
laboratory reporting limits were estimated. Concentrations were compared to the NCDENR
Inactive Hazardous Sites Branch (IHSB) Vapor Intrusion Screening Levels (Acceptable Soil-Gas
Concentrations, February 2012) for residential and industrial/commercial sites. Two (2)
compounds were detected at concentrations that exceeded their respective acceptable Soil-Gas
concentrations for both Residential and Industrial/Commercial sites. Acrolein was detected at a
concentration (estimated) in vapor sample V-3 at 2.5 µg/m3, above its Residential screening level
of 0.042 µg/m3 and Industrial/Commercial screening level of 0.176 µg/m3. Trichloroethene was
detected in vapor samples V-3 and V-4 at 424.31 µg/m3 and 304.0 µg/m3, respectively. Both
concentrations are above its Residential screening level of 4.2 µg/m3 and its
Industrial/Commercial screening level of 17.6 µg/m3.

Two (2) compounds were detected above their respective residential Soil-Gas screening levels.
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Chloroform was detected at 14.93 µg/m3 in sample V-3, above its Residential screening level of
11 µg/m3. Tetrachloroethene was detected at 144.38 µg/m3 in vapor sample V-1, above its
Residential screening level of 83.4 µg/m3.

Summary
Soil Chromium
The recent soil chromium analyses did not detect chromium or hexavalent chromium at
concentrations above their respective PSRGs and does not appear to be a concern at the site.

Groundwater Volatile Organic Compounds
Chlorinated solvents (PCE and TCE) have historically been detected on-site in concentrations
exceeding 15A NCAC 2L Groundwater Quality Standards (2L Standards). PCE and TCE
concentrations in permanent groundwater monitoring wells MW-2 and MW-4 have shown a
decreasing trend since 1999 suggesting that the compounds are naturally attenuating.

Groundwater Metals
The 2012 analytical results for samples collected from groundwater monitoring wells MW-1,
MW-2, MW-3 and MW-4 only detected one metal above its Interim 2L Standard. Thallium was
detected in wells MW-1 and MW-3 at 3.2 µg/l and 1.7 µg/l, respectively. These concentrations
are above thallium’s Interim 2L Standard of 0.2 µg/l. MW-1 with a thallium concentration of 3.7
µg/l is considered a background well and the thallium detected is likely naturally occurring
levels in the groundwater. Dissolved thallium concentrations were below laboratory detection
limits, suggesting the detected thallium may have been in sediment in the sample. Metal
concentrations in groundwater decreased significantly between the 2008 and 2012 sampling
events. The concentration difference was likely due to the purging and sampling method during
each event. The 2008 sampling was conducted with a dedicated bailer and the 2012 event with a
peristaltic pump. Purging and sampling using a peristaltic typically reduces suspended sediment
in the sample.

Sub Slab Soil Gas
Sub slab soil gas results detected two (2) compounds (acrolein and trichloroethene) above their

FIGURES

TABLES
Table 1Summary of Soil Analytical Results7820 Tyner StreetCharlotte, North CarolinaAEI Job No. 510-06Sample ID B-1B-2B-3B-4B-5SB-1 (SS-1) (CE-1)SB-2 (SS-1) (CE-2)Date 6/27/126/27/126/27/126/27/126/27/122/23/992/23/99Depth (feet) 1111144ParametersProtection of Groundwater PSRGsResidential PSRGsIndustrial PSRGsVOCs (µg/kg)Tetrachloroethene517,00082,000NANANANANA<6.9<6Trichloroethene188804,000NANANANANA<6.9<61,1-Dichloroethene4548,000220,000NANANANANA61<6Methylene Chloride12311,00053,000NANANANANA59241,1,1-Trichloroethane1,200640,000640,000NANANANANA9.6<6Metals (mg/kg)Arsenic5.80.391.6NANANANANANANABarium5803,00038,000NANANANANANANACadmium314160NANANANANANANAChromium (III)360,00024,000100,00076.269.714535.220.7NANAHexavalent Chromium (VI) 3.80.295.60.142 J<0.124<0.124<0.133<0.131NANALead270400800NANANANANANANAMercury123.1NANANANANANANANickelNot Specified740,000A8,800,000ANANANANANANANASelenium2.1781,000NANANANANANANASilver3.4781,000NANANANANANANAZinc1,2004,60062,000NANANANANANANANotesSoil samples collected on 2/23/99 by Cooper Environmental personnel.Soil samples collected on 4/5/99 and 4/6/99 by Turner Hart & Hickman, P.C.Soil samples collected on 11/10/05 by CBM Environmental Services, Inc.Soil samples collected on 6/27/12 by AWARE Environmental Inc.- Concentration above IHSB Industrial PSRGs- Concentration above IHSB protection of groundwater PSRGsBold fonts are concentrations detected above laboratory method detection limits.J - Concentration estimatedVOCs - Volatile organic compounds analyzed by EPA method 8260 or 601.NA - Not analyzed.A - PSRGs for nickel refinery dust.1 - Methylene chloride was considered a possible laboratory contaminant by the contract laboratoryPSRG - Inactive Hazardous Site Branch - Preliminary Soil Remediation Goals (February 2012)Page: 1 of 9P:\N510\N510-04\GW Summary June-2012
Table 1Summary of Soil Analytical Results7820 Tyner StreetCharlotte, North CarolinaAEI Job No. 510-06Sample ID Date Depth (feet) ParametersProtection of Groundwater PSRGsResidential PSRGsIndustrial PSRGsVOCs (µg/kg)Tetrachloroethene517,00082,000Trichloroethene188804,0001,1-Dichloroethene4548,000220,000Methylene Chloride12311,00053,0001,1,1-Trichloroethane1,200640,000640,000Metals (mg/kg)Arsenic5.80.391.6Barium5803,00038,000Cadmium314160Chromium (III)360,00024,000100,000Hexavalent Chromium (VI) 3.80.295.6Lead270400800Mercury123.1NickelNot Specified740,000A8,800,000ASelenium2.1781,000Silver3.4781,000Zinc1,2004,60062,000NotesSoil samples collected on 2/23/99 by Cooper Environmental personnel.Soil samples collected on 4/5/99 and 4/6/99 by Turner Hart & Hickman, P.C.Soil samples collected on 11/10/05 by CBM Environmental Services, Inc.Soil samples collected on 6/27/12 by AWARE Environmental Inc.- Concentration above IHSB Industrial PSRGs- Concentration above IHSB protection of groundwater PSRGsBold fonts are concentrations detected above laboratory method detection limits.J - Concentration estimatedVOCs - Volatile organic compounds analyzed by EPA method 8260 or 601.NA - Not analyzed.A - PSRGs for nickel refinery dust.1 - Methylene chloride was considered a possible laboratory contaminant by the contract laboratoryPSRG - Inactive Hazardous Site Branch - Preliminary Soil Remediation Goals (February 2012)SB-2 (SS-2) (CE-2)SB-3 (SS-1) (CE-3)SB-3 (SS-2) (CE-3)SB-4 (SS-1) (CE-4)SB-4 SB-8 SB-92/23/99 2/23/99 2/23/99 2/23/99 4/5/99 4/5/99 4/5/996 - 8 4 841 - 20 - 10 - 1<6.4<6.2<6.2<6.2<1.4<1.3<1.2<6.4<6.2<6.220<1.4<1.3<1.2<6.4<6.2<6.2<6.2<1.4<1.3<1.21805318026<7.2<6.5<6.2<6.4<6.2<6.2<6.2<1.4<1.3<1.2NANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANAPage: 2 of 9P:\N510\N510-04\GW Summary June-2012
Table 1Summary of Soil Analytical Results7820 Tyner StreetCharlotte, North CarolinaAEI Job No. 510-06Sample ID Date Depth (feet) ParametersProtection of Groundwater PSRGsResidential PSRGsIndustrial PSRGsVOCs (µg/kg)Tetrachloroethene517,00082,000Trichloroethene188804,0001,1-Dichloroethene4548,000220,000Methylene Chloride12311,00053,0001,1,1-Trichloroethane1,200640,000640,000Metals (mg/kg)Arsenic5.80.391.6Barium5803,00038,000Cadmium314160Chromium (III)360,00024,000100,000Hexavalent Chromium (VI) 3.80.295.6Lead270400800Mercury123.1NickelNot Specified740,000A8,800,000ASelenium2.1781,000Silver3.4781,000Zinc1,2004,60062,000NotesSoil samples collected on 2/23/99 by Cooper Environmental personnel.Soil samples collected on 4/5/99 and 4/6/99 by Turner Hart & Hickman, P.C.Soil samples collected on 11/10/05 by CBM Environmental Services, Inc.Soil samples collected on 6/27/12 by AWARE Environmental Inc.- Concentration above IHSB Industrial PSRGs- Concentration above IHSB protection of groundwater PSRGsBold fonts are concentrations detected above laboratory method detection limits.J - Concentration estimatedVOCs - Volatile organic compounds analyzed by EPA method 8260 or 601.NA - Not analyzed.A - PSRGs for nickel refinery dust.1 - Methylene chloride was considered a possible laboratory contaminant by the contract laboratoryPSRG - Inactive Hazardous Site Branch - Preliminary Soil Remediation Goals (February 2012)SB-BG1 (MW-1)SB-BG2 BSB-1 BSB-2 BSB-3 BSB-4 BSB-54/6/99 4/6/99 11/10/05 11/10/05 11/10/05 11/10/05 11/10/051 - 2 2 - 312345Considered Background LocationConsidered Background LocationConsidered Background LocationConsidered Background LocationConsidered Background LocationConsidered Background LocationConsidered Background LocationNANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANA<0.972.171.201.901.100.751.209.956.72817163652<0.97<0.981.00.810.740.360.853.09 45.92638382154NANANANANANANANANA7.96.27.49.48.2<0.10<0.100.074 0.041 0.022J 0.027J 0.043NANA9.87.28.02.113NANA1515158.814NANA<1.8<1.8<1.7<0.33<1.8NANA4041382241Page: 3 of 9P:\N510\N510-04\GW Summary June-2012
Table 1Summary of Soil Analytical Results7820 Tyner StreetCharlotte, North CarolinaAEI Job No. 510-06Sample ID Date Depth (feet) ParametersProtection of Groundwater PSRGsResidential PSRGsIndustrial PSRGsVOCs (µg/kg)Tetrachloroethene517,00082,000Trichloroethene188804,0001,1-Dichloroethene4548,000220,000Methylene Chloride12311,00053,0001,1,1-Trichloroethane1,200640,000640,000Metals (mg/kg)Arsenic5.80.391.6Barium5803,00038,000Cadmium314160Chromium (III)360,00024,000100,000Hexavalent Chromium (VI) 3.80.295.6Lead270400800Mercury123.1NickelNot Specified740,000A8,800,000ASelenium2.1781,000Silver3.4781,000Zinc1,2004,60062,000NotesSoil samples collected on 2/23/99 by Cooper Environmental personnel.Soil samples collected on 4/5/99 and 4/6/99 by Turner Hart & Hickman, P.C.Soil samples collected on 11/10/05 by CBM Environmental Services, Inc.Soil samples collected on 6/27/12 by AWARE Environmental Inc.- Concentration above IHSB Industrial PSRGs- Concentration above IHSB protection of groundwater PSRGsBold fonts are concentrations detected above laboratory method detection limits.J - Concentration estimatedVOCs - Volatile organic compounds analyzed by EPA method 8260 or 601.NA - Not analyzed.A - PSRGs for nickel refinery dust.1 - Methylene chloride was considered a possible laboratory contaminant by the contract laboratoryPSRG - Inactive Hazardous Site Branch - Preliminary Soil Remediation Goals (February 2012)SB-1 SB-1 SB-2 SB-2 SB-3 SB-3 SB-411/10/05 11/10/05 11/10/05 11/10/05 11/10/05 11/10/05 11/10/051414141NANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANA0.721.403.701.302.702.401.00274219143418831.8011638.80.571.64536741901307581120NANANANANANANA6.39.711.07.29.38.59.10.041 0.020 0.044 0.048 0.052 0.019J 0.0329.4491302814273507.78.71623141511<0.32<0.32<1.6<1.7<1.5<1.5<1.5216315046384177Page: 4 of 9P:\N510\N510-04\GW Summary June-2012
Table 1Summary of Soil Analytical Results7820 Tyner StreetCharlotte, North CarolinaAEI Job No. 510-06Sample ID Date Depth (feet) ParametersProtection of Groundwater PSRGsResidential PSRGsIndustrial PSRGsVOCs (µg/kg)Tetrachloroethene517,00082,000Trichloroethene188804,0001,1-Dichloroethene4548,000220,000Methylene Chloride12311,00053,0001,1,1-Trichloroethane1,200640,000640,000Metals (mg/kg)Arsenic5.80.391.6Barium5803,00038,000Cadmium314160Chromium (III)360,00024,000100,000Hexavalent Chromium (VI) 3.80.295.6Lead270400800Mercury123.1NickelNot Specified740,000A8,800,000ASelenium2.1781,000Silver3.4781,000Zinc1,2004,60062,000NotesSoil samples collected on 2/23/99 by Cooper Environmental personnel.Soil samples collected on 4/5/99 and 4/6/99 by Turner Hart & Hickman, P.C.Soil samples collected on 11/10/05 by CBM Environmental Services, Inc.Soil samples collected on 6/27/12 by AWARE Environmental Inc.- Concentration above IHSB Industrial PSRGs- Concentration above IHSB protection of groundwater PSRGsBold fonts are concentrations detected above laboratory method detection limits.J - Concentration estimatedVOCs - Volatile organic compounds analyzed by EPA method 8260 or 601.NA - Not analyzed.A - PSRGs for nickel refinery dust.1 - Methylene chloride was considered a possible laboratory contaminant by the contract laboratoryPSRG - Inactive Hazardous Site Branch - Preliminary Soil Remediation Goals (February 2012)SB-4 SB-5 SB-5 SB-6 SB-6 SB-7 SB-711/10/05 11/10/05 11/10/05 11/10/05 11/10/05 11/10/05 11/10/054141414NANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANA1.101.602.002.30 0.30J 1.10 0.52J56324423185527294.92.11.4 0.073J 1.60.621509712070606763NANANANANANANA12.07.78.09.58.98.57.50.100 0.170 0.071 0.082 0.062 0.050 0.0613208120175.52814151615145.85.36.1<1.6<1.6<1.6<1.5<0.30<0.28<0.3175494540283834Page: 5 of 9P:\N510\N510-04\GW Summary June-2012
Table 1Summary of Soil Analytical Results7820 Tyner StreetCharlotte, North CarolinaAEI Job No. 510-06Sample ID Date Depth (feet) ParametersProtection of Groundwater PSRGsResidential PSRGsIndustrial PSRGsVOCs (µg/kg)Tetrachloroethene517,00082,000Trichloroethene188804,0001,1-Dichloroethene4548,000220,000Methylene Chloride12311,00053,0001,1,1-Trichloroethane1,200640,000640,000Metals (mg/kg)Arsenic5.80.391.6Barium5803,00038,000Cadmium314160Chromium (III)360,00024,000100,000Hexavalent Chromium (VI) 3.80.295.6Lead270400800Mercury123.1NickelNot Specified740,000A8,800,000ASelenium2.1781,000Silver3.4781,000Zinc1,2004,60062,000NotesSoil samples collected on 2/23/99 by Cooper Environmental personnel.Soil samples collected on 4/5/99 and 4/6/99 by Turner Hart & Hickman, P.C.Soil samples collected on 11/10/05 by CBM Environmental Services, Inc.Soil samples collected on 6/27/12 by AWARE Environmental Inc.- Concentration above IHSB Industrial PSRGs- Concentration above IHSB protection of groundwater PSRGsBold fonts are concentrations detected above laboratory method detection limits.J - Concentration estimatedVOCs - Volatile organic compounds analyzed by EPA method 8260 or 601.NA - Not analyzed.A - PSRGs for nickel refinery dust.1 - Methylene chloride was considered a possible laboratory contaminant by the contract laboratoryPSRG - Inactive Hazardous Site Branch - Preliminary Soil Remediation Goals (February 2012)SB-8 SB-8 SB-9 SB-9 SB-10 SB-10 SB-1111/10/05 11/10/05 11/10/05 11/10/05 11/10/05 11/10/05 11/10/051414141NANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANA0.13J 0.930.82<0.590.82<0.691.0091 24 87 1002523270.025J 3.0<0.29<0.29478.63.860110732109313067NANANANANANANA5.88.58.63.510.011.012.00.024 0.110 0.046 0.010J 0.047 0.035 0.0602531275712033344.66.25.63.47.9116.5<0.2812<0.29<0.29<0.31<1.7<0.3053354559505156Page: 6 of 9P:\N510\N510-04\GW Summary June-2012
Table 1Summary of Soil Analytical Results7820 Tyner StreetCharlotte, North CarolinaAEI Job No. 510-06Sample ID Date Depth (feet) ParametersProtection of Groundwater PSRGsResidential PSRGsIndustrial PSRGsVOCs (µg/kg)Tetrachloroethene517,00082,000Trichloroethene188804,0001,1-Dichloroethene4548,000220,000Methylene Chloride12311,00053,0001,1,1-Trichloroethane1,200640,000640,000Metals (mg/kg)Arsenic5.80.391.6Barium5803,00038,000Cadmium314160Chromium (III)360,00024,000100,000Hexavalent Chromium (VI) 3.80.295.6Lead270400800Mercury123.1NickelNot Specified740,000A8,800,000ASelenium2.1781,000Silver3.4781,000Zinc1,2004,60062,000NotesSoil samples collected on 2/23/99 by Cooper Environmental personnel.Soil samples collected on 4/5/99 and 4/6/99 by Turner Hart & Hickman, P.C.Soil samples collected on 11/10/05 by CBM Environmental Services, Inc.Soil samples collected on 6/27/12 by AWARE Environmental Inc.- Concentration above IHSB Industrial PSRGs- Concentration above IHSB protection of groundwater PSRGsBold fonts are concentrations detected above laboratory method detection limits.J - Concentration estimatedVOCs - Volatile organic compounds analyzed by EPA method 8260 or 601.NA - Not analyzed.A - PSRGs for nickel refinery dust.1 - Methylene chloride was considered a possible laboratory contaminant by the contract laboratoryPSRG - Inactive Hazardous Site Branch - Preliminary Soil Remediation Goals (February 2012)SB-11 SB-12 SB-12 SB-13 SB-13 SB-14 SB-1411/10/05 11/10/05 11/10/05 11/10/05 11/10/05 11/10/05 11/10/054141414NANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANA0.41J 0.084J<0.59<0.552.00 0.28J 2.1017861108457701102.1<0.28<0.29<0.280.042J 0.059J<0.3088452357488742NANANANANANANA7.03.86.06.09.26.612.00.053 0.014J 0.038 0.024 0.032 0.025 0.0279.8183208.4308.18.03.74.05.07.65.56.0<0.31<0.28<0.29<0.28<0.31<0.28<0.3036424747344028Page: 7 of 9P:\N510\N510-04\GW Summary June-2012
Table 1Summary of Soil Analytical Results7820 Tyner StreetCharlotte, North CarolinaAEI Job No. 510-06Sample ID Date Depth (feet) ParametersProtection of Groundwater PSRGsResidential PSRGsIndustrial PSRGsVOCs (µg/kg)Tetrachloroethene517,00082,000Trichloroethene188804,0001,1-Dichloroethene4548,000220,000Methylene Chloride12311,00053,0001,1,1-Trichloroethane1,200640,000640,000Metals (mg/kg)Arsenic5.80.391.6Barium5803,00038,000Cadmium314160Chromium (III)360,00024,000100,000Hexavalent Chromium (VI) 3.80.295.6Lead270400800Mercury123.1NickelNot Specified740,000A8,800,000ASelenium2.1781,000Silver3.4781,000Zinc1,2004,60062,000NotesSoil samples collected on 2/23/99 by Cooper Environmental personnel.Soil samples collected on 4/5/99 and 4/6/99 by Turner Hart & Hickman, P.C.Soil samples collected on 11/10/05 by CBM Environmental Services, Inc.Soil samples collected on 6/27/12 by AWARE Environmental Inc.- Concentration above IHSB Industrial PSRGs- Concentration above IHSB protection of groundwater PSRGsBold fonts are concentrations detected above laboratory method detection limits.J - Concentration estimatedVOCs - Volatile organic compounds analyzed by EPA method 8260 or 601.NA - Not analyzed.A - PSRGs for nickel refinery dust.1 - Methylene chloride was considered a possible laboratory contaminant by the contract laboratoryPSRG - Inactive Hazardous Site Branch - Preliminary Soil Remediation Goals (February 2012)SB-15 SB-15 SB-16 SB-16 SB-17 SB-17 SB-1811/10/05 11/10/05 11/10/05 11/10/05 11/10/05 11/10/05 11/10/051414141NANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANA0.821.502.601.503.004.401.5086834223823668<0.29<0.291.200.520.821.00.5563427351677074NANANANANANANA7.313.011.06.112.011.06.70.011J 0.021J 0.046 0.052 0.024 0.090 0.015J1113148.7164.9288.05.8127.77.2157.2<0.29<0.29<0.30<0.30<0.29<0.33<0.2948273120292631Page: 8 of 9P:\N510\N510-04\GW Summary June-2012
Table 1Summary of Soil Analytical Results7820 Tyner StreetCharlotte, North CarolinaAEI Job No. 510-06Sample ID Date Depth (feet) ParametersProtection of Groundwater PSRGsResidential PSRGsIndustrial PSRGsVOCs (µg/kg)Tetrachloroethene517,00082,000Trichloroethene188804,0001,1-Dichloroethene4548,000220,000Methylene Chloride12311,00053,0001,1,1-Trichloroethane1,200640,000640,000Metals (mg/kg)Arsenic5.80.391.6Barium5803,00038,000Cadmium314160Chromium (III)360,00024,000100,000Hexavalent Chromium (VI) 3.80.295.6Lead270400800Mercury123.1NickelNot Specified740,000A8,800,000ASelenium2.1781,000Silver3.4781,000Zinc1,2004,60062,000NotesSoil samples collected on 2/23/99 by Cooper Environmental personnel.Soil samples collected on 4/5/99 and 4/6/99 by Turner Hart & Hickman, P.C.Soil samples collected on 11/10/05 by CBM Environmental Services, Inc.Soil samples collected on 6/27/12 by AWARE Environmental Inc.- Concentration above IHSB Industrial PSRGs- Concentration above IHSB protection of groundwater PSRGsBold fonts are concentrations detected above laboratory method detection limits.J - Concentration estimatedVOCs - Volatile organic compounds analyzed by EPA method 8260 or 601.NA - Not analyzed.A - PSRGs for nickel refinery dust.1 - Methylene chloride was considered a possible laboratory contaminant by the contract laboratoryPSRG - Inactive Hazardous Site Branch - Preliminary Soil Remediation Goals (February 2012)SB-18 SB-19 SB-19 SB-20 SB-20 SB-21 SB-2111/10/05 11/10/05 11/10/05 11/10/05 11/10/05 11/10/05 11/10/054141414NANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANA2.70 0.35J 2.601.501.102.400.58221009040702501100.420.31 0.24J 0.39 0.24J 0.400.3253644685458095NANANANANANANA7.23.510.07.94.314.03.20.074 0.0086J 0.022J 0.045 0.014J 0.045 0.0253.6298.42218205710.05.86.68.45.27.65.6<0.30<0.29<0.30<0.30<0.31<0.29<0.2820492432343655Page: 9 of 9P:\N510\N510-04\GW Summary June-2012
Well ID
TOC
Elevation
(ft.)
Well Depth
(ft.)
Water Level to
TOC
(ft.)
Groundwater
Elevation
(ft.)
Water Level to
TOC
(ft.)
Groundwater
Elevation
(ft.)
MW-1 762.85 22 18.76 744.09 19.95 742.9
MW-2 752.75 15 10.46 742.29 11.14 741.61
MW-3 750.94 15 9.95 740.99 10.17 740.77
MW-4 753.68 15 10.82 742.86 11.17 742.51
Notes
Water levels collected by AWARE personnel on dates indicated.
Monitoring wells are 1-inch in diameter.
Elevations relative to a temporary on-site benchmark of 746.71 feet based on
National Geodetic Vertical Datum (NGVD).
Well elevation and depths from Table 4 of CBM Environmental Services, Inc. report
dated January 19, 2006.
6/13/20086/27/2012
AEI JOB No. N510-06
TABLE 2
MONITORING WELL INFORMATION
7820 TYNER STREET
CHARLOTTE, NORTH CAROLINA
P:\N510\N510-04\GW Summary June-2012
Well ID pH
Temperature
(°C)
Conductivity
(S/cm)
Turbidity
(NRU)
Dissolved
Oxygen (mg/l)
Total
Dissolved
Solids (TDS)
( g/l )
OPR
(mv)
MW-1 6.44 32.24 0.219 280 11.9 0.18 230
MW-2 4.67 22.68 0.103 134 NA 0.07 352
MW-3 7.04 27.2 98.8 104.1 13.9 52 27
MW-4 6.96 21.91 0.367
Very Silty -
No Reading 16.9 0.24 249
Notes
Measurements collected on June 27, 2012.
Parameters collected using a Horiba U-22.
ORP - Oxidation-reduction potential.
NA - No valid reading obtained.
AEI JOB No. N510-06
TABLE 3
FIELD PARAMETERS
7820 TYNER STREET
CHARLOTTE, NORTH CAROLINA
P:\N510\N510-04\GW Summary June-2012
Table 4Summary of Monitoring Well Analytical Data7820 Tyner StreetCharlotte, North CarolinaAEI Job No. 510-066/27&28/20126/13/08 11/15/05 4/30/02 4/26/01 4/27/00 4/6/996/27&28/20126/13/08 11/15/05 4/30/02 4/26/01 4/27/00 4/6/99Total Arsenic10 <3.426.24.2 J1NA NA NA NA<3.4 <5.05.1 JNA NA NA NADissolved Arsenic10<3.414.7<10.0NA NA NA NA<3.4 <5.0 <10.0NA NA NA NATotal Barium700NA1,870 680NA NA NA NANA325340NA NA NA NADissolved Barium700NA1,920 23NA NA NA NANA40556NA NA NA NATotal Beryllium4<0.8NA NA NA NA NA NA0.8 JNA NA NA NA NA NADissolved Beryllium4<0.8NA NA NA NA NA NA<0.8NA NA NA NA NA NATotal Cadmium2<143.6 34.0NA NA NA3.0<111.2 38NA NA NA NADissolved Cadmium2<118.3 1 J 1.0<1.02.0<1.0 <18.2 13 9 27 17NATotal Chromium10<2250 4NA NA NA NA3.5 J 115 6.0NA NA NA NADissolved Chromium10<216.9<5.0NA NA NA NA<2 <5.0 <5.0NA NA NA NATotal Hexavalent ChromiumNot Specified<5NA NA NA NA NA NA<5NA NA NA NA NA NADissolved Hexavalent ChromiumNot Specified<5NA NA NA NA NA NA<5NA NA NA NA NA NATotal Copper1,0004 JNA NA NA NA NA NA9.0 JNA NA NA NA NA NADissolved Copper1,0002 JNA NA NA NA NA NA6.0 JNA NA NA NA NA NATotal Lead15<2.876.3 5.8NA NA NA NA<2.810.2 5.0NA NA NA NADissolved Lead15<2.834.7<5.0NA NA NA NA<2.8 <5.0 <5.0NA NA NA NATotal Mercury1<0.051.1<0.2NA NA NA NA<0.050.37<0.2NA NA NA NADissolved Mercury1<0.05 <0.20 <0.2NA NA NA NA0.005 J<0.20 <0.2NA NA NA NATotal Nickel100<4361 8.9NA NA NA NA15 J 99.7 18.0NA NA NA NADissolved Nickel100<470.7<10.0NA NA NA NA14 J 16.97.7 JNA NA NA NATotal Thallium0.23.2 JNA NA NA NA NA NA<1.7NA NA NA NA NA NADissolved Thallium0.2 <1.7NA NA NA NA NA NA<1.7NA NA NA NA NA NATotal Zinc1,00015.6 J 2,470 170NA NA NA NA32.6 344 390NA NA NA NADissolved Zinc1,00011.3 J 639 22 JNA NA NA NA25.5 93.2 5.7NA NA NA NAVOCsAcetone6,000 <10 <25BDL NA NA NA NA4.47 J<25BDL NA NA NA NATetrachloroethene0.7 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.02.2 1.2 12.0 13.3 29 12.7Trichloroethene2.8 <5.0 <1.0 <2.0 <1.0 <1.0 <1.0 <1.05.55 20.3 3.8 38.6 54.2 87 33.71,2-Dichloroethane0.38 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0cis-1,2-Dichloroethene70 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0Dichlorodifluoromethane1,000 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0Vinyl Chloride0.015 <10.0 <1.0 <2.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <2.0 <1.0 <1.0 <1.0 <1.0SVOCsBDL NA NA NA NA NA NA BDL NA NA NA NA NA NANotesGroundwater samples collected on 6/13/08 and 6/27-28/12 by AWARE Environmental® Inc. personnel.Groundwater samples collected on 11/15/05 by CBM Environmental Services, Inc.Groundwater samples collected on 4/30/02 and 4/26/01by Hart & Hickman. Groundwater samples collected on 4/27/00 and 4/6/99 by Turner, Hart and Hickman, PC.- Concentration above NCAC 2L Groundwater Standards or Interim Standards, January 1, 2010.Bold fonts are concentrations detected above laboratory method detection limits.VOCs - Volatile organic compounds analyzed by EPA method 8260 or 601.SVOCs - Semi-VOCs analyzed by EPA Method 8270.J - Concentration estimatedBDL - Target compounds below laboratory reporting limits.NA - Not analyzed.Identified Compound(µg/L)NCAC 2L Standard (µg/L)MW-1MW-2P:\N510\N510-04\GW Summary June-2012
Table 4Summary of Monitoring Well Analytical Data7820 Tyner StreetCharlotte, North CarolinaAEI Job No. 510-06Total Arsenic10Dissolved Arsenic10Total Barium700Dissolved Barium700Total Beryllium4Dissolved Beryllium4Total Cadmium2Dissolved Cadmium2Total Chromium10Dissolved Chromium10Total Hexavalent ChromiumNot SpecifiedDissolved Hexavalent ChromiumNot SpecifiedTotal Copper1,000Dissolved Copper1,000Total Lead15Dissolved Lead15Total Mercury1Dissolved Mercury1Total Nickel100Dissolved Nickel100Total Thallium0.2Dissolved Thallium0.2Total Zinc1,000Dissolved Zinc1,000VOCsAcetone6,000Tetrachloroethene0.7Trichloroethene2.81,2-Dichloroethane0.38cis-1,2-Dichloroethene70Dichlorodifluoromethane1,000Vinyl Chloride0.015SVOCsIdentified Compound(µg/L)NCAC 2L Standard (µg/L)6/27&28/20126/13/08 11/15/05 4/30/02 4/26/01 4/27/00 4/6/996/27&28/20126/13/08 11/15/05 4/30/02 4/26/01 4/27/00 4/6/99<3.4 <5.010.0NA NA NA NA<3.417.6 27NA NA NA NA<3.49.5<10.0NA NA NA NA<3.4 <5.011NA NA NA NANA922720NA NA NA NANA448970NA NA NA NANA79159NA NA NA NANA3653.2 JNA NA NA NA<0.8NA NA NA NA NA NA<0.8NA NA NA NA NA NA<0.8NA NA NA NA NA NA<0.8NA NA NA NA NA NA<188.1 9.8NA NA NA NA1.1 J 28.1 24NA NA NA NA<131.0<5.01.0<1.0 <1.0NA<122.3 52 3.0 1.0<1.0NA<24548.6NA NA NA NA169 897 220NA NA NA NA<241.0<5.0NA NA NA NA25.9 280 110NA NA NA NA6 JNA NA NA NA NA NA<5NA NA NA NA NA NA<5NA NA NA NA NA NA<5NA NA NA NA NA NA2 JNA NA NA NA NA NA50NA NA NA NA NA NA<10NA NA NA NA NA NA3.0 JNA NA NA NA NA NA<2.865.5 28.0NA NA NA NA23.4 811 200NA NA NA NA<2.828.8<5.0NA NA NA NA<2.8767<5.0NA NA NA NA<0.050.56<0.2NA NA NA NA<0.050.21<0.2NA NA NA NA<0.05 <0.20 <0.2NA NA NA NA<0.05 <0.20 <0.2NA NA NA NA<411326NA NA NA NA39 213 48.0NA NA NA NA<423.1 2.4 JNA NA NA NA<438.3 23.0NA NA NA NA1.7 JNA NA NA NA NA NA<1.7NA NA NA NA NA NA<1.7NA NA NA NA NA NA<1.7NA NA NA NA NA NA31.4 931 140NA NA NA NA112 1,020 170.0NA NA NA NA20 326 61NA NA NA NA14 452 11.0 JNA NA NA NA<10 <25BDL NA NA NA NA<10 <25BDL NA NA NA NA<5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.05.96 16.7 22.0 190.0 90.3 380.0 80.7<5.0 <1.0 <2.0 <1.0 <1.0 <1.0 <1.0 <5.01.6 4.5 82.1 250.0 340.0 105<5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0<5.0 <1.0 <1.0 <1.01.1 1.0 1.3<5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0<5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.01.5<5.0 <1.0 <2.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <2.0 <1.0 <1.0 <1.0 <1.0BDL NA NA NA NA NA NA BDL NA NA NA NA NA NANotesGroundwater samples collected on 6/13/08 and 6/27-28/12 by AWARE Environmental® Inc. personnel.Groundwater samples collected on 11/15/05 by CBM Environmental Services, Inc.Groundwater samples collected on 4/30/02 and 4/26/01by Hart & Hickman. Groundwater samples collected on 4/27/00 and 4/6/99 by Turner, Hart and Hickman, PC.- Concentration above NCAC 2L Groundwater Standards or Interim Standards, January 1, 2010.Bold fonts are concentrations detected above laboratory method detection limits.VOCs - Volatile organic compounds analyzed by EPA method 8260 or 601.SVOCs - Semi-VOCs analyzed by EPA Method 8270.J - Concentration estimatedBDL - Target compounds below laboratory reporting limits.NA - Not analyzed.MW-3MW-4P:\N510\N510-04\GW Summary June-2012
Table 5Temporary Well Analytical Data7820 Tyner StreetCharlotte, North CarolinaAEI Job No. 510-06TW-1 TW-2 TW-1 TW-2 TW-3 TW-4 TW-5 TW-6 TW-702/23/99 02/23/99 11/15/05 11/15/05 11/15/05 11/15/05 11/15/05 11/15/05 11/15/05Total Arsenic10 <5.0 <5.019<105.9J<108.4J<108.7JDissolved Arsenic10 <5.0 <5.0 <10 <10 <10 <10 <10 <1011Total Barium700490 1,600 910 280 830 1,400 460 260 360Dissolved Barium700190 1,500 83 66 17 29 6.7J 6.8J 150Total Cadmium21,100<100 <10 <1.02.5 0.6J 0.2J 72 28,000Dissolved Cadmium21,300<10 <5.0 <5.0 <5.0 <5.0 <5.05.0 49,000Total Chromium101,100 630 48 14 9.8 4.7J 11 9.8 19Dissolved Chromium1021 50<5.0 <5.0 <5.0 <5.0 <5.0 <5.015Total Lead1515 230 80 8.4 33 19 21 19 17Dissolved Lead1513 8.7<5.0 <5.0 <5.0 <5.0 <5.0 <5.06.6Total Mercury10.46 5<0.2 <0.2 <0.2 <0.2 <0.2 <0.20.43Dissolved Mercury1 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.20.24Total Nickel100NANA48 35 40 25 13 350 8,800Dissolved Nickel100NANA8.7J 18 2.7J 5.8J<1029 17,000Total Zinc1,000NANA150 72 210 200 120 280 2,500Dissolved Zinc1,000NANA46 44 38 41 18J 56 3,600VOCsTetrachloroethene0.718.0 99.0<1.00.65J<1.0 <1.0 <1.0 <1.02.3Trichloroethene2.875.0 330.0<2.058<2.0 <2.0 <2.0 <2.04.81,2-Dichloroethane0.38 <5.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.03.5cis-1,2-Dichloroethene70 <5.0 <5.0 <1.011<1.0 <1.00.70 J<1.0 <1.0Dichlorofluoromethane1,400 <10 <10 -------Vinyl Chloride0.015 <10 <10 <2.01.7 J<2.0 <2.0 <2.0 <2.0 <2.0NotesGroundwater samples collected on 2/23/99 by Cooper Environmental, Inc. personnel.Groundwater samples collected on 11/15/05 by CBM Environmental Services, Inc.- Concentration above NCAC 2L Groundwater Standards, January 1, 2010.Bold fonts are concentrations detected above laboratory method detection limits.J - Concentration estimatedVOCs - Volatile organic compounds analyzed by EPA method 8260 or 601.ND - Not detectedNA - Not analyzed." - " - Not knownIdentified Compound(µg/L)NCAC 2L Standard (µg/L)P:\N510\N510-04\GW Summary June-2012
Vapor Screening Values Vapor Screening ValuesAcceptable Soil-Gas Acceptable Soil-GasConcentrationsConcentrationsCONTAMINANTS OFResidentialIndustrial/CommercialV-1V-2V-3V-4CONCERN(µg/m3)(µg/m3)6/28/12 6/28/12 6/28/12 6/28/12 6/28/12EPA Method TO-15 (µg/m3)Acetone64,000280,00046.332.064.528.140.6Acetonitrile1265200.828 J 1.26 J 0.853 J<0.5880.626 JAcrolein0.0420.176<0.815<0.8092.51 J<0.803<0.8392-Butanone (MEK)10,40044,0008.735.157.396.437.65Carbon Disulfide1,4606,2001.50 J 1.14 J<1.09<1.091.47 JChloroform11 533.42 J 4.12 J 14.90 5.58 J 6.04 J1,4-Dichlorobenzene 22 1005.42 J<2.12<2.11<2.11<2.2Dichlorodifluoromethane (Freon 12)2008801.84 J 1.80 J<1.74<1.73<1.811,2-Dichloroethane9.447<1.447.20<1.42<1.42<1.48EthanolNot SpecifiedNot Specified16.20 11.60 7.514.207.52Ethyl AcetateNot SpecifiedNot Specified9.68 3.10 J 10.20 10.30 11.70Hexane1,4606,200<1.25<1.241.29 J<1.23<1.292-Hexanone (MBK)Not SpecifiedNot Specified3.86 J<1.451.55 J 2.37 J 2.96 JIsopropyl AlcoholNot SpecifiedNot Specified6.54 16.30 6.76 2.99 J 16.90Methylene Chloride5202,6002.59 J 3.15 J 2.61 J 1.97 J 3.26 JMethyl Isobutyl Ketone6,20026,000<1.46<1.452.06 J 2.34 J 2.63 JNaphthalene6.2 26<1.864.25 J<1.84<1.84<1.92Styrene2,0008,8001.84 J 1.88 J<1.5<1.49<1.56Tetrachloroethene83.435014516.70 46.90 28.90 31.04Toluene10,40044,0004.00 J 4.45 J 5.03 3.06 J 2.90 JTrichloroethene4.217.6<1.91<1.94252953041,2,4-Trimethylbenzene14.6623.44 J 2.07 J 2.47 J 2.55 J 2.72 Jm-/p-Xylene2008803.67 J 2.85 J 2.55 J 2.36 J 2.37 Jo-Xylene200880 <1.53<1.53<1.52<1.59Notes: Soil gas samples collected by AWARE Environmental® Inc. personnel on dates indicated.Only compounds detected above laboratory reporting limits are presented in the table. - Concentration above Inactive Hazardous Sites Branch Acceptable Soil Gas Concentration for Industrial/Commerical Sites, February 2012. - Concentration above Inactive Hazardous Sites Branch Acceptable Soil Gas Concentration for Residential Sites, February 2012.Bold fonts are concentrations detected above laboratory method reporting limits.Duplicate sample (Labeled as V-Dup in lab report) was collected on June 28, 2012 was from vapor well V-4.J - Value is estimated, concentration between laboratory detection limit and laboratory reporting limit. AEI JOB No. N510-06V-Dup Duplicate of V-4Sample ID and Date SampledTABLE 6SUB SLAB SOIL GAS ANALYTICAL RESULTS7820 TYNER STREETCHARLOTTE, NORTH CAROLINAAEI Project No. N510-06P:\N510\N510-04\GW Summary June-2012

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AWARE Environmental, Inc.
8514 McAlpine Park Dr. Suite 100
Charlotte, NC 28211

Tyner St.
Client Project # N508-05

Analytical Report
(0612-142R)

EPA Method TO-15
TO-15 Target Compound List

Enthalpy Analytical, Inc.
Phone: (919) 850 - 4392 / Fax: (919) 850 - 9012 / www.enthalpy.com
800-1 Capitola Drive Durham, NC 27713-4385

I certify that to the best of my knowledge all analytical data presented in this report:
Have been checked for completeness
Are accurate, error-free, and legible
Have been conducted in accordance with approved protocol, and that all deviations and
analytical problems are summarized in the appropriate narrative(s)
This analytical report was prepared in Portable Document Format (.PDF) and contains ??? pages.

Report Issued: xx/xx/xxxx

Results
Sample ID:DF: 1.00
Data File: L1201442.D Tank DF: 1.776
Tank/Misc ID:ConCal 1
Quant
Ret.
Time
(min)
Area
Conc. as
Analyzed
(ppbv)
Sample
Conc.
(ppbv)
Flags
Sample
Conc.
(ug/m3)
41 NA 0 0.200 0.355 ND 0.611
85 4.78 32,538 0.209 0.372 J 1.84
85 NA 0 0.200 0.355 ND 2.48
50 NA 0 0.200 0.355 ND 0.734
62 NA 0 0.200 0.355 ND 0.908
39 NA 0 0.200 0.355 ND 0.786
94 NA 0 0.200 0.355 ND 1.38
64 NA 0 0.200 0.355 ND 0.937
106 NA 0 0.200 0.355 ND 1.55
101 NA 0 0.200 0.355 ND 2.00
45 7.85 92,538 4.84 8.60 16.2
56 NA 0 0.200 0.355 ND 0.815
151 NA 0 0.200 0.355 ND 2.72
61 NA 0 0.200 0.355 ND 1.41
43 8.75 1,217,781 11.0 19.5 46.3
76 9.15 41,687 0.271 0.482 J 1.50
45 9.09 170,372 1.50 2.66 6.54
76 NA 0 0.200 0.355 ND 1.11
41 9.35 15,629 0.278 0.493 J 0.828
49 9.77 35,662 0.420 0.746 J 2.59
61 NA 0 0.200 0.355 ND 1.41
73 NA 0 0.200 0.355 ND 1.28
53 NA 0 0.200 0.355 ND 0.771
57 NA 0 0.200 0.355 ND 1.25
63 NA 0 0.200 0.355 ND 1.44
43 NA 0 0.200 0.355 ND 1.25
61 NA 0 0.200 0.355 ND 1.41
72 12.55 42,108 1.67 2.96 8.73
45 12.64 33,530 1.51 2.69 9.68
83 13.23 45,826 0.394 0.700 J 3.42
72 NA 0 0.200 0.355 ND 1.05
97 NA 0 0.200 0.355 ND 1.94
56 NA 0 0.200 0.355 ND 1.22
117 NA 0 0.200 0.355 ND 2.24
78 NA 0 0.200 0.355 ND 1.14
57 NA 0 0.200 0.355 ND 1.66
62 NA 0 0.200 0.355 ND 1.44
57 NA 0 0.200 0.355 ND 1.46
130 NA 0 0.200 0.355 ND 1.91
63 NA 0 0.200 0.355 ND 1.64
69 NA 0 0.200 0.355 ND 1.45
88 NA 0 0.200 0.355 ND 1.28
83 NA 0 0.200 0.355 ND 2.38
75 NA 0 0.200 0.355 ND 1.61
43 NA 0 0.200 0.355 ND 1.46
91 17.40 108,367 0.598 1.06 J 4.00
75 NA 0 0.200 0.355 ND 1.61
Methyl isobutyl ketone
Toluene
trans-1,3-Dichloropropene
2,2,4-trimethylpentane
1,2-Dichloroethane
Heptane
cis-1,3-Dichloropropene
Bromodichloromethane
Trichloroethene
1,2-Dichloropropane
Methyl methacrylate
1,4-Dioxane
Benzene
cis-1,2-Dichloroethylene
Methyl ethyl ketone (2-Butanone)
Ethyl acetate
Chloroform
Tetrahydrofuran
1,1,1-Trichloroethane
Cyclohexane
Carbon tetrachloride
Acrylonitrile
Hexane
1,1-Dichloroethane
Vinyl acetate
Acetonitrile
Methylene chloride
trans-1,2-Dichloroethene
Methyl tert-butyl ether
Acetone
Carbon disulfide
Isopropyl alcohol
Allyl chloride (3-chloropropene)
Ethanol
Acrolein
Freon 113 (C2Cl3F3)
1,1-Dichloroethene
Bromomethane
Chloroethane
Bromoethene (Vinyl bromide)
Freon 11 (CCl3F)
Compound
TO15-Tyner St.-V-1-Can #00206
0612-142, 500mL load
Propylene
Freon 12 (CCl2F2)
Freon 114 (C2Cl2F4)
Chloromethane
Chloroethene (Vinyl chloride)
1,3-Butadiene
Company
Analyst
Parameters
AWARE Environmental, Inc.
DB
EPA Method TO-15 TCL
Client #
Job #
# Samples
N508-05
0612-142
5 (1.4L) Canisters
0612-142R results 8/11/2012
Sample ID:DF: 1.00
Data File: L1201442.D Tank DF: 1.776
Tank/Misc ID:ConCal 1
Quant
Ret.
Time
(min)
Area
Conc. as
Analyzed
(ppbv)
Sample
Conc.
(ppbv)
Flags
Sample
Conc.
(ug/m3)
Compound
TO15-Tyner St.-V-1-Can #00206
0612-142, 500mL load
Company
Analyst
Parameters
AWARE Environmental, Inc.
DB
EPA Method TO-15 TCL
Client #
Job #
# Samples
N508-05
0612-142
5 (1.4L) Canisters
97 NA 0 0.200 0.355 ND 1.94
166 18.09 1,116,779 12.0 21.3 145
43 18.18 86,179 0.530 0.942 J 3.86
129 NA 0 0.200 0.355 ND 3.03
107 NA 0 0.200 0.355 ND 2.73
112 NA 0 0.200 0.355 ND 1.64
91 NA 0 0.200 0.355 ND 1.54
131 NA 0 0.200 0.355 ND 2.44
91 19.30 83,422 0.476 0.845 J 3.67
91 19.68 37,233 0.208 0.369 J 1.60
104 19.70 35,816 0.243 0.431 J 1.84
173 NA 0 0.200 0.355 ND 3.67
83 NA 0 0.200 0.355 ND 2.44
105 NA 0 0.200 0.355 ND 1.75
91 NA 0 0.200 0.355 ND 1.84
105 NA 0 0.200 0.355 ND 1.75
105 20.83 77,144 0.394 0.699 J 3.44
146 NA 0 0.200 0.355 ND 2.14
146 21.18 70,646 0.507 0.901 J 5.42
91 NA 0 0.200 0.355 ND 1.84
146 NA 0 0.200 0.355 ND 2.14
180 NA 0 0.200 0.355 ND 2.64
225 NA 0 0.200 0.355 ND 3.79
128 NA 0 0.200 0.355 ND 1.86
Rec. (%) Flags
130 13.05 480,464 11.03 N/A
114 14.85 1,849,588 10.52 N/A
117 19.07 1,788,038 11.20 N/A
Internal Standard Acceptance Criteria (Area +/- 40%, RT +/- 20 sec.)
Concal Sample Ave. ICal Flag
RT RT IS Area
13.04 13.05 539,287 Pass
14.85 14.85 2,012,245 Pass
19.07 19.07 1,964,160 Pass
1,4-Difluorobenzene (IS)1,849,588
Chlorobenzene-d5 (IS)1,788,038
Sample
Name IS Area
Bromochloromethane (IS)480,464
Hexachlorobutadiene
Naphthalene
Internal Standard
1,4-Difluorobenzene (IS)
1,4-Dichlorobenzene
Benzyl chloride
1,2-Dichlorobenzene
1,2,4-Trichlorobenzene
2-Chlorotoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3-Dichlorobenzene
Styrene
Bromoform
1,1,2,2-Tetrachloroethane
4-Ethyltoluene
Ethylbenzene
1,1,1,2-Tetrachloroethane
m-/p-Xylenes
o-Xylene
Chlorobenzene-d5 (IS)
1,1,2-Trichloroethane
Tetrachloroethene
2-Hexanone (Methyl butyl ketone)
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
Bromochloromethane (IS)
0612-142R results 8/11/2012
Sample ID:DF: 1.00
Data File: L1201443.D Tank DF: 1.765
Tank/Misc ID:ConCal 1
Quant
Ret.
Time
(min)
Area
Conc. as
Analyzed
(ppbv)
Sample
Conc.
(ppbv)
Flags
Sample
Conc.
(ug/m3)
41 NA 0 0.200 0.353 ND 0.607
85 4.79 36,096 0.206 0.364 J 1.80
85 NA 0 0.200 0.353 ND 2.47
50 NA 0 0.200 0.353 ND 0.729
62 NA 0 0.200 0.353 ND 0.902
39 NA 0 0.200 0.353 ND 0.781
94 NA 0 0.200 0.353 ND 1.37
64 NA 0 0.200 0.353 ND 0.931
106 NA 0 0.200 0.353 ND 1.54
101 NA 0 0.200 0.353 ND 1.98
45 7.85 75,169 3.49 6.16 11.6
56 NA 0 0.200 0.353 ND 0.809
151 NA 0 0.200 0.353 ND 2.70
61 NA 0 0.200 0.353 ND 1.40
43 8.75 930,497 7.45 13.1 31.2
76 9.15 35,939 0.208 0.366 J 1.14
45 9.10 481,812 3.76 6.63 16.3
76 NA 0 0.200 0.353 ND 1.10
41 9.36 26,994 0.426 0.751 J 1.26
49 9.78 49,088 0.513 0.906 J 3.15
61 NA 0 0.200 0.353 ND 1.40
73 NA 0 0.200 0.353 ND 1.27
53 NA 0 0.200 0.353 ND 0.766
57 NA 0 0.200 0.353 ND 1.24
63 NA 0 0.200 0.353 ND 1.43
43 NA 0 0.200 0.353 ND 1.24
61 NA 0 0.200 0.353 ND 1.40
72 12.55 28,154 0.989 1.74 5.15
45 12.65 12,166 0.487 0.859 J 3.10
83 13.24 62,682 0.479 0.845 J 4.12
72 NA 0 0.200 0.353 ND 1.04
97 NA 0 0.200 0.353 ND 1.93
56 NA 0 0.200 0.353 ND 1.21
117 NA 0 0.200 0.353 ND 2.22
78 NA 0 0.200 0.353 ND 1.13
57 NA 0 0.200 0.353 ND 1.65
62 14.27 88,531 1.01 1.78 7.20
57 NA 0 0.200 0.353 ND 1.45
130 NA 0 0.200 0.353 ND 1.90
63 NA 0 0.200 0.353 ND 1.63
69 NA 0 0.200 0.353 ND 1.45
88 NA 0 0.200 0.353 ND 1.27
83 NA 0 0.200 0.353 ND 2.37
75 NA 0 0.200 0.353 ND 1.60
43 NA 0 0.200 0.353 ND 1.45
91 17.39 130,349 0.669 1.18 J 4.45
75 NA 0 0.200 0.353 ND 1.60
Methyl isobutyl ketone
Toluene
trans-1,3-Dichloropropene
2,2,4-trimethylpentane
1,2-Dichloroethane
Heptane
cis-1,3-Dichloropropene
Bromodichloromethane
Trichloroethene
1,2-Dichloropropane
Methyl methacrylate
1,4-Dioxane
Benzene
cis-1,2-Dichloroethylene
Methyl ethyl ketone (2-Butanone)
Ethyl acetate
Chloroform
Tetrahydrofuran
1,1,1-Trichloroethane
Cyclohexane
Carbon tetrachloride
Acrylonitrile
Hexane
1,1-Dichloroethane
Vinyl acetate
Acetonitrile
Methylene chloride
trans-1,2-Dichloroethene
Methyl tert-butyl ether
Acetone
Carbon disulfide
Isopropyl alcohol
Allyl chloride (3-chloropropene)
Ethanol
Acrolein
Freon 113 (C2Cl3F3)
1,1-Dichloroethene
Bromomethane
Chloroethane
Bromoethene (Vinyl bromide)
Freon 11 (CCl3F)
Compound
TO15-Tyner St.-V-2-Can #00208
0612-142, 500mL load
Propylene
Freon 12 (CCl2F2)
Freon 114 (C2Cl2F4)
Chloromethane
Chloroethene (Vinyl chloride)
1,3-Butadiene
Company
Analyst
Parameters
AWARE Environmental, Inc.
DB
EPA Method TO-15 TCL
Client #
Job #
# Samples
N508-05
0612-142
5 (1.4L) Canisters
0612-142R results 8/11/2012
Sample ID:DF: 1.00
Data File: L1201443.D Tank DF: 1.765
Tank/Misc ID:ConCal 1
Quant
Ret.
Time
(min)
Area
Conc. as
Analyzed
(ppbv)
Sample
Conc.
(ppbv)
Flags
Sample
Conc.
(ug/m3)
Compound
TO15-Tyner St.-V-2-Can #00208
0612-142, 500mL load
Company
Analyst
Parameters
AWARE Environmental, Inc.
DB
EPA Method TO-15 TCL
Client #
Job #
# Samples
N508-05
0612-142
5 (1.4L) Canisters
97 NA 0 0.200 0.353 ND 1.93
166 18.09 139,817 1.40 2.46 16.7
43 NA 0 0.200 0.353 ND 1.45
129 NA 0 0.200 0.353 ND 3.01
107 NA 0 0.200 0.353 ND 2.71
112 NA 0 0.200 0.353 ND 1.62
91 NA 0 0.200 0.353 ND 1.53
131 NA 0 0.200 0.353 ND 2.42
91 19.30 70,247 0.373 0.657 J 2.85
91 NA 0 0.200 0.353 ND 1.53
104 19.70 39,662 0.250 0.441 J 1.88
173 NA 0 0.200 0.353 ND 3.65
83 NA 0 0.200 0.353 ND 2.42
105 NA 0 0.200 0.353 ND 1.74
91 NA 0 0.200 0.353 ND 1.83
105 NA 0 0.200 0.353 ND 1.74
105 20.82 50,394 0.239 0.422 J 2.07
146 NA 0 0.200 0.353 ND 2.12
146 NA 0 0.200 0.353 ND 2.12
91 NA 0 0.200 0.353 ND 1.83
146 NA 0 0.200 0.353 ND 2.12
180 NA 0 0.200 0.353 ND 2.62
225 NA 0 0.200 0.353 ND 3.76
128 23.13 119,472 0.460 0.811 J 4.25
Rec. (%) Flags
130 13.06 541,335 11.03 N/A
114 14.86 2,075,679 10.52 N/A
117 19.06 1,923,477 11.20 N/A
Internal Standard Acceptance Criteria (Area +/- 40%, RT +/- 20 sec.)
Concal Sample Ave. ICal Flag
RT RT IS Area
13.04 13.06 539,287 Pass
14.85 14.86 2,012,245 Pass
19.07 19.06 1,964,160 Pass
1,4-Difluorobenzene (IS)2,075,679
Chlorobenzene-d5 (IS)1,923,477
Sample
Name IS Area
Bromochloromethane (IS)541,335
Hexachlorobutadiene
Naphthalene
Internal Standard
1,4-Difluorobenzene (IS)
1,4-Dichlorobenzene
Benzyl chloride
1,2-Dichlorobenzene
1,2,4-Trichlorobenzene
2-Chlorotoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3-Dichlorobenzene
Styrene
Bromoform
1,1,2,2-Tetrachloroethane
4-Ethyltoluene
Ethylbenzene
1,1,1,2-Tetrachloroethane
m-/p-Xylenes
o-Xylene
Chlorobenzene-d5 (IS)
1,1,2-Trichloroethane
Tetrachloroethene
2-Hexanone (Methyl butyl ketone)
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
Bromochloromethane (IS)
0612-142R results 8/11/2012
Sample ID:DF: 1.00
Data File: L1201444.D Tank DF: 1.757
Tank/Misc ID:ConCal 1
Quant
Ret.
Time
(min)
Area
Conc. as
Analyzed
(ppbv)
Sample
Conc.
(ppbv)
Flags
Sample
Conc.
(ug/m3)
41 NA 0 0.200 0.351 ND 0.605
85 NA 0 0.200 0.351 ND 1.74
85 NA 0 0.200 0.351 ND 2.46
50 NA 0 0.200 0.351 ND 0.726
62 NA 0 0.200 0.351 ND 0.898
39 NA 0 0.200 0.351 ND 0.777
94 NA 0 0.200 0.351 ND 1.36
64 NA 0 0.200 0.351 ND 0.927
106 NA 0 0.200 0.351 ND 1.54
101 NA 0 0.200 0.351 ND 1.97
45 7.86 50,262 2.27 3.99 7.51
56 8.42 14,824 0.622 1.09 J 2.51
151 NA 0 0.200 0.351 ND 2.69
61 NA 0 0.200 0.351 ND 1.39
43 8.75 1,984,829 15.4 27.1 64.5
76 NA 0 0.200 0.351 ND 1.09
45 9.10 206,264 1.56 2.75 6.76
76 NA 0 0.200 0.351 ND 1.10
41 9.37 18,868 0.289 0.508 J 0.853
49 9.79 42,007 0.427 0.750 J 2.61
61 NA 0 0.200 0.351 ND 1.39
73 NA 0 0.200 0.351 ND 1.27
53 NA 0 0.200 0.351 ND 0.763
57 11.03 19,218 0.209 0.367 J 1.29
63 NA 0 0.200 0.351 ND 1.42
43 NA 0 0.200 0.351 ND 1.24
61 NA 0 0.200 0.351 ND 1.39
72 12.56 41,752 1.43 2.51 7.39
45 12.64 41,462 1.61 2.84 10.2
83 13.24 234,569 1.74 3.06 14.9
72 NA 0 0.200 0.351 ND 1.04
97 NA 0 0.200 0.351 ND 1.92
56 NA 0 0.200 0.351 ND 1.21
117 NA 0 0.200 0.351 ND 2.21
78 NA 0 0.200 0.351 ND 1.12
57 NA 0 0.200 0.351 ND 1.64
62 NA 0 0.200 0.351 ND 1.42
57 NA 0 0.200 0.351 ND 1.44
130 15.24 4,127,162 45.0 79.0 425
63 NA 0 0.200 0.351 ND 1.62
69 NA 0 0.200 0.351 ND 1.44
88 NA 0 0.200 0.351 ND 1.27
83 NA 0 0.200 0.351 ND 2.35
75 NA 0 0.200 0.351 ND 1.59
43 17.02 57,566 0.286 0.503 J 2.06
91 17.39 151,572 0.760 1.34 5.03
75 NA 0 0.200 0.351 ND 1.59
Methyl isobutyl ketone
Toluene
trans-1,3-Dichloropropene
2,2,4-trimethylpentane
1,2-Dichloroethane
Heptane
cis-1,3-Dichloropropene
Bromodichloromethane
Trichloroethene
1,2-Dichloropropane
Methyl methacrylate
1,4-Dioxane
Benzene
cis-1,2-Dichloroethylene
Methyl ethyl ketone (2-Butanone)
Ethyl acetate
Chloroform
Tetrahydrofuran
1,1,1-Trichloroethane
Cyclohexane
Carbon tetrachloride
Acrylonitrile
Hexane
1,1-Dichloroethane
Vinyl acetate
Acetonitrile
Methylene chloride
trans-1,2-Dichloroethene
Methyl tert-butyl ether
Acetone
Carbon disulfide
Isopropyl alcohol
Allyl chloride (3-chloropropene)
Ethanol
Acrolein
Freon 113 (C2Cl3F3)
1,1-Dichloroethene
Bromomethane
Chloroethane
Bromoethene (Vinyl bromide)
Freon 11 (CCl3F)
Compound
TO15-Tyner St.-V-3-Can #00147
0612-142, 500mL load
Propylene
Freon 12 (CCl2F2)
Freon 114 (C2Cl2F4)
Chloromethane
Chloroethene (Vinyl chloride)
1,3-Butadiene
Company
Analyst
Parameters
AWARE Environmental, Inc.
DB
EPA Method TO-15 TCL
Client #
Job #
# Samples
N508-05
0612-142
5 (1.4L) Canisters
0612-142R results 8/11/2012
Sample ID:DF: 1.00
Data File: L1201444.D Tank DF: 1.757
Tank/Misc ID:ConCal 1
Quant
Ret.
Time
(min)
Area
Conc. as
Analyzed
(ppbv)
Sample
Conc.
(ppbv)
Flags
Sample
Conc.
(ug/m3)
Compound
TO15-Tyner St.-V-3-Can #00147
0612-142, 500mL load
Company
Analyst
Parameters
AWARE Environmental, Inc.
DB
EPA Method TO-15 TCL
Client #
Job #
# Samples
N508-05
0612-142
5 (1.4L) Canisters
97 NA 0 0.200 0.351 ND 1.92
166 18.09 403,359 3.94 6.92 46.9
43 18.18 38,547 0.216 0.379 J 1.55
129 NA 0 0.200 0.351 ND 2.99
107 NA 0 0.200 0.351 ND 2.70
112 NA 0 0.200 0.351 ND 1.62
91 NA 0 0.200 0.351 ND 1.53
131 NA 0 0.200 0.351 ND 2.41
91 19.30 64,443 0.334 0.587 J 2.55
91 NA 0 0.200 0.351 ND 1.53
104 NA 0 0.200 0.351 ND 1.50
173 NA 0 0.200 0.351 ND 3.63
83 NA 0 0.200 0.351 ND 2.41
105 NA 0 0.200 0.351 ND 1.73
91 NA 0 0.200 0.351 ND 1.82
105 NA 0 0.200 0.351 ND 1.73
105 20.83 61,625 0.286 0.502 J 2.47
146 NA 0 0.200 0.351 ND 2.11
146 NA 0 0.200 0.351 ND 2.11
91 NA 0 0.200 0.351 ND 1.82
146 NA 0 0.200 0.351 ND 2.11
180 NA 0 0.200 0.351 ND 2.61
225 NA 0 0.200 0.351 ND 3.75
128 NA 0 0.200 0.351 ND 1.84
Rec. (%) Flags
130 13.06 556,584 11.03 N/A
114 14.86 2,147,362 10.52 N/A
117 19.06 1,967,738 11.20 N/A
Internal Standard Acceptance Criteria (Area +/- 40%, RT +/- 20 sec.)
Concal Sample Ave. ICal Flag
RT RT IS Area
13.04 13.06 539,287 Pass
14.85 14.86 2,012,245 Pass
19.07 19.06 1,964,160 Pass
1,4-Difluorobenzene (IS)2,147,362
Chlorobenzene-d5 (IS)1,967,738
Sample
Name IS Area
Bromochloromethane (IS)556,584
Hexachlorobutadiene
Naphthalene
Internal Standard
1,4-Difluorobenzene (IS)
1,4-Dichlorobenzene
Benzyl chloride
1,2-Dichlorobenzene
1,2,4-Trichlorobenzene
2-Chlorotoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3-Dichlorobenzene
Styrene
Bromoform
1,1,2,2-Tetrachloroethane
4-Ethyltoluene
Ethylbenzene
1,1,1,2-Tetrachloroethane
m-/p-Xylenes
o-Xylene
Chlorobenzene-d5 (IS)
1,1,2-Trichloroethane
Tetrachloroethene
2-Hexanone (Methyl butyl ketone)
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
Bromochloromethane (IS)
0612-142R results 8/11/2012
Sample ID:DF: 1.00
Data File: L1201445.D Tank DF: 1.751
Tank/Misc ID:ConCal 1
Quant
Ret.
Time
(min)
Area
Conc. as
Analyzed
(ppbv)
Sample
Conc.
(ppbv)
Flags
Sample
Conc.
(ug/m3)
41 NA 0 0.200 0.350 ND 0.603
85 NA 0 0.200 0.350 ND 1.73
85 NA 0 0.200 0.350 ND 2.45
50 NA 0 0.200 0.350 ND 0.723
62 NA 0 0.200 0.350 ND 0.895
39 NA 0 0.200 0.350 ND 0.775
94 NA 0 0.200 0.350 ND 1.36
64 NA 0 0.200 0.350 ND 0.924
106 NA 0 0.200 0.350 ND 1.53
101 NA 0 0.200 0.350 ND 1.97
45 7.86 28,217 1.27 2.23 4.20
56 NA 0 0.200 0.350 ND 0.803
151 NA 0 0.200 0.350 ND 2.68
61 NA 0 0.200 0.350 ND 1.39
43 8.75 868,444 6.75 11.8 28.1
76 NA 0 0.200 0.350 ND 1.09
45 9.11 91,635 0.695 1.22 J 2.99
76 NA 0 0.200 0.350 ND 1.10
41 NA 0 0.200 0.350 ND 0.588
49 9.79 31,870 0.324 0.567 J 1.97
61 NA 0 0.200 0.350 ND 1.39
73 NA 0 0.200 0.350 ND 1.26
53 NA 0 0.200 0.350 ND 0.760
57 NA 0 0.200 0.350 ND 1.23
63 NA 0 0.200 0.350 ND 1.42
43 NA 0 0.200 0.350 ND 1.23
61 NA 0 0.200 0.350 ND 1.39
72 12.55 36,494 1.25 2.18 6.43
45 12.65 42,101 1.64 2.87 10.3
83 13.24 87,903 0.652 1.14 J 5.58
72 NA 0 0.200 0.350 ND 1.03
97 NA 0 0.200 0.350 ND 1.91
56 NA 0 0.200 0.350 ND 1.21
117 NA 0 0.200 0.350 ND 2.20
78 NA 0 0.200 0.350 ND 1.12
57 NA 0 0.200 0.350 ND 1.64
62 NA 0 0.200 0.350 ND 1.42
57 NA 0 0.200 0.350 ND 1.44
130 15.24 2,877,772 31.4 54.9 295
63 NA 0 0.200 0.350 ND 1.62
69 NA 0 0.200 0.350 ND 1.43
88 NA 0 0.200 0.350 ND 1.26
83 NA 0 0.200 0.350 ND 2.35
75 NA 0 0.200 0.350 ND 1.59
43 17.02 65,726 0.327 0.572 J 2.34
91 17.39 92,041 0.464 0.812 J 3.06
75 NA 0 0.200 0.350 ND 1.59
Methyl isobutyl ketone
Toluene
trans-1,3-Dichloropropene
2,2,4-trimethylpentane
1,2-Dichloroethane
Heptane
cis-1,3-Dichloropropene
Bromodichloromethane
Trichloroethene
1,2-Dichloropropane
Methyl methacrylate
1,4-Dioxane
Benzene
cis-1,2-Dichloroethylene
Methyl ethyl ketone (2-Butanone)
Ethyl acetate
Chloroform
Tetrahydrofuran
1,1,1-Trichloroethane
Cyclohexane
Carbon tetrachloride
Acrylonitrile
Hexane
1,1-Dichloroethane
Vinyl acetate
Acetonitrile
Methylene chloride
trans-1,2-Dichloroethene
Methyl tert-butyl ether
Acetone
Carbon disulfide
Isopropyl alcohol
Allyl chloride (3-chloropropene)
Ethanol
Acrolein
Freon 113 (C2Cl3F3)
1,1-Dichloroethene
Bromomethane
Chloroethane
Bromoethene (Vinyl bromide)
Freon 11 (CCl3F)
Compound
TO15-Tyner St.-V-4-Can #00192
0612-142, 500mL load
Propylene
Freon 12 (CCl2F2)
Freon 114 (C2Cl2F4)
Chloromethane
Chloroethene (Vinyl chloride)
1,3-Butadiene
Company
Analyst
Parameters
AWARE Environmental, Inc.
DB
EPA Method TO-15 TCL
Client #
Job #
# Samples
N508-05
0612-142
5 (1.4L) Canisters
0612-142R results
Sample ID:DF: 1.00
Data File: L1201445.D Tank DF: 1.751
Tank/Misc ID:ConCal 1
Quant
Ret.
Time
(min)
Area
Conc. as
Analyzed
(ppbv)
Sample
Conc.
(ppbv)
Flags
Sample
Conc.
(ug/m3)
Compound
TO15-Tyner St.-V-4-Can #00192
0612-142, 500mL load
Company
Analyst
Parameters
AWARE Environmental, Inc.
DB
EPA Method TO-15 TCL
Client #
Job #
# Samples
N508-05
0612-142
5 (1.4L) Canisters
97 NA 0 0.200 0.350 ND 1.91
166 18.09 248,552 2.44 4.27 28.9
43 18.18 58,767 0.330 0.578 J 2.37
129 NA 0 0.200 0.350 ND 2.98
107 NA 0 0.200 0.350 ND 2.69
112 NA 0 0.200 0.350 ND 1.61
91 NA 0 0.200 0.350 ND 1.52
131 NA 0 0.200 0.350 ND 2.40
91 19.30 59,559 0.310 0.543 J 2.36
91 NA 0 0.200 0.350 ND 1.52
104 NA 0 0.200 0.350 ND 1.49
173 NA 0 0.200 0.350 ND 3.62
83 NA 0 0.200 0.350 ND 2.40
105 NA 0 0.200 0.350 ND 1.72
91 NA 0 0.200 0.350 ND 1.81
105 NA 0 0.200 0.350 ND 1.72
105 20.83 63,636 0.297 0.519 J 2.55
146 NA 0 0.200 0.350 ND 2.11
146 NA 0 0.200 0.350 ND 2.11
91 NA 0 0.200 0.350 ND 1.81
146 NA 0 0.200 0.350 ND 2.11
180 NA 0 0.200 0.350 ND 2.60
225 NA 0 0.200 0.350 ND 3.73
128 NA 0 0.200 0.350 ND 1.84
Rec. (%) Flags
130 13.06 556,970 11.03 N/A
114 14.86 2,147,949 10.52 N/A
117 19.07 1,958,199 11.20 N/A
Internal Standard Acceptance Criteria (Area +/- 40%, RT +/- 20 sec.)
Concal Sample Ave. ICal Flag
RT RT IS Area
13.04 13.06 539,287 Pass
14.85 14.86 2,012,245 Pass
19.07 19.07 1,964,160 Pass
1,4-Difluorobenzene (IS)2,147,949
Chlorobenzene-d5 (IS)1,958,199
Sample
Name IS Area
Bromochloromethane (IS)556,970
Hexachlorobutadiene
Naphthalene
Internal Standard
1,4-Difluorobenzene (IS)
1,4-Dichlorobenzene
Benzyl chloride
1,2-Dichlorobenzene
1,2,4-Trichlorobenzene
2-Chlorotoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3-Dichlorobenzene
Styrene
Bromoform
1,1,2,2-Tetrachloroethane
4-Ethyltoluene
Ethylbenzene
1,1,1,2-Tetrachloroethane
m-/p-Xylenes
o-Xylene
Chlorobenzene-d5 (IS)
1,1,2-Trichloroethane
Tetrachloroethene
2-Hexanone (Methyl butyl ketone)
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
Bromochloromethane (IS)
0612-142R results
Sample ID:DF: 1.00
Data File: L1201446.D Tank DF: 1.830
Tank/Misc ID:ConCal 1
Quant
Ret.
Time
(min)
Area
Conc. as
Analyzed
(ppbv)
Sample
Conc.
(ppbv)
Flags
Sample
Conc.
(ug/m3)
41 NA 0 0.200 0.366 ND 0.630
85 NA 0 0.200 0.366 ND 1.81
85 NA 0 0.200 0.366 ND 2.56
50 NA 0 0.200 0.366 ND 0.756
62 NA 0 0.200 0.366 ND 0.936
39 NA 0 0.200 0.366 ND 0.810
94 NA 0 0.200 0.366 ND 1.42
64 NA 0 0.200 0.366 ND 0.966
106 NA 0 0.200 0.366 ND 1.60
101 NA 0 0.200 0.366 ND 2.06
45 7.86 48,479 2.18 3.99 7.52
56 NA 0 0.200 0.366 ND 0.839
151 NA 0 0.200 0.366 ND 2.81
61 NA 0 0.200 0.366 ND 1.45
43 8.75 1,202,276 9.33 17.1 40.6
76 9.15 45,983 0.258 0.471 J 1.47
45 9.10 496,848 3.76 6.88 16.9
76 NA 0 0.200 0.366 ND 1.15
41 9.37 13,335 0.204 0.373 J 0.626
49 9.79 50,598 0.513 0.939 J 3.26
61 NA 0 0.200 0.366 ND 1.45
73 NA 0 0.200 0.366 ND 1.32
53 NA 0 0.200 0.366 ND 0.794
57 NA 0 0.200 0.366 ND 1.29
63 NA 0 0.200 0.366 ND 1.48
43 NA 0 0.200 0.366 ND 1.29
61 NA 0 0.200 0.366 ND 1.45
72 12.56 41,613 1.42 2.59 7.65
45 12.65 45,770 1.78 3.25 11.7
83 13.24 91,255 0.676 1.24 J 6.04
72 NA 0 0.200 0.366 ND 1.08
97 NA 0 0.200 0.366 ND 2.00
56 NA 0 0.200 0.366 ND 1.26
117 NA 0 0.200 0.366 ND 2.30
78 NA 0 0.200 0.366 ND 1.17
57 NA 0 0.200 0.366 ND 1.71
62 NA 0 0.200 0.366 ND 1.48
57 NA 0 0.200 0.366 ND 1.50
130 15.24 2,850,243 30.9 56.6 304
63 NA 0 0.200 0.366 ND 1.69
69 NA 0 0.200 0.366 ND 1.50
88 NA 0 0.200 0.366 ND 1.32
83 NA 0 0.200 0.366 ND 2.45
75 NA 0 0.200 0.366 ND 1.66
43 17.02 70,953 0.351 0.643 J 2.63
91 17.39 84,844 0.421 0.771 J 2.90
75 NA 0 0.200 0.366 ND 1.66
TO15-Tyner St.-V-DUP-Can #00229
cis-1,3-Dichloropropene
Methyl isobutyl ketone
Toluene
trans-1,3-Dichloropropene
Methyl methacrylate
1,4-Dioxane
Benzene
2,2,4-trimethylpentane
1,2-Dichloroethane
Heptane
Methyl ethyl ketone (2-Butanone)
Ethyl acetate
Chloroform
Bromodichloromethane
Tetrahydrofuran
1,1,1-Trichloroethane
Cyclohexane
Carbon tetrachloride
Trichloroethene
1,2-Dichloropropane
Hexane
1,1-Dichloroethane
Vinyl acetate
cis-1,2-Dichloroethylene
Methylene chloride
trans-1,2-Dichloroethene
Methyl tert-butyl ether
Acrylonitrile
Allyl chloride (3-chloropropene)
Acetonitrile
Acrolein
Freon 113 (C2Cl3F3)
1,1-Dichloroethene
Acetone
Freon 11 (CCl3F)
Ethanol
Compound
0612-142, 500mL load
Carbon disulfide
Isopropyl alcohol
Propylene
Freon 12 (CCl2F2)
Freon 114 (C2Cl2F4)
Chloromethane
Chloroethene (Vinyl chloride)
1,3-Butadiene
Bromomethane
Chloroethane
Bromoethene (Vinyl bromide)
Company
Analyst
Parameters
AWARE Environmental, Inc.
DB
EPA Method TO-15 TCL
Client #
Job #
# Samples
N508-05
0612-142
5 (1.4L) Canisters
0612-142R results 8/11/2012
Sample ID:DF: 1.00
Data File: L1201446.D Tank DF: 1.830
Tank/Misc ID:ConCal 1
Quant
Ret.
Time
(min)
Area
Conc. as
Analyzed
(ppbv)
Sample
Conc.
(ppbv)
Flags
Sample
Conc.
(ug/m3)
TO15-Tyner St.-V-DUP-Can #00229
Compound
0612-142, 500mL load
Company
Analyst
Parameters
AWARE Environmental, Inc.
DB
EPA Method TO-15 TCL
Client #
Job #
# Samples
N508-05
0612-142
5 (1.4L) Canisters
97 NA 0 0.200 0.366 ND 2.00
166 18.10 258,964 2.50 4.58 31.0
43 18.19 71,466 0.395 0.724 J 2.96
129 NA 0 0.200 0.366 ND 3.12
107 NA 0 0.200 0.366 ND 2.81
112 NA 0 0.200 0.366 ND 1.69
91 NA 0 0.200 0.366 ND 1.59
131 NA 0 0.200 0.366 ND 2.51
91 19.30 58,135 0.298 0.545 J 2.37
91 NA 0 0.200 0.366 ND 1.59
104 NA 0 0.200 0.366 ND 1.56
173 NA 0 0.200 0.366 ND 3.78
83 NA 0 0.200 0.366 ND 2.51
105 NA 0 0.200 0.366 ND 1.80
91 NA 0 0.200 0.366 ND 1.90
105 NA 0 0.200 0.366 ND 1.80
105 20.83 67,101 0.308 0.563 J 2.77
146 NA 0 0.200 0.366 ND 2.20
146 NA 0 0.200 0.366 ND 2.20
91 NA 0 0.200 0.366 ND 1.90
146 NA 0 0.200 0.366 ND 2.20
180 NA 0 0.200 0.366 ND 2.72
225 NA 0 0.200 0.366 ND 3.90
128 NA 0 0.200 0.366 ND 1.92
Rec. (%) Flags
130 13.06 558,253 11.03 N/A
114 14.86 2,157,876 10.52 N/A
117 19.07 1,989,214 11.20 N/A
Internal Standard Acceptance Criteria (Area +/- 40%, RT +/- 20 sec.)
Concal Sample Ave. ICal Flag
RT RT IS Area
13.04 13.06 539,287 Pass
14.85 14.86 2,012,245 Pass
19.07 19.07 1,964,160 Pass
1,4-Difluorobenzene (IS)2,157,876
Chlorobenzene-d5 (IS)1,989,214
Sample
Name IS Area
Bromochloromethane (IS)558,253
1,2,4-Trichlorobenzene
Hexachlorobutadiene
Naphthalene
Internal Standard
1,4-Difluorobenzene (IS)
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl chloride
1,2-Dichlorobenzene
Chlorobenzene-d5 (IS)
4-Ethyltoluene
2-Chlorotoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
o-Xylene
Styrene
Bromoform
1,1,2,2-Tetrachloroethane
Chlorobenzene
Ethylbenzene
1,1,1,2-Tetrachloroethane
m-/p-Xylenes
1,1,2-Trichloroethane
Tetrachloroethene
2-Hexanone (Methyl butyl ketone)
Dibromochloromethane
1,2-Dibromoethane
Bromochloromethane (IS)
0612-142R results 8/11/2012
Sample ID:DF: 1.00
Data File: L1201447.D Tank DF: 1.776
Tank/Misc ID:ConCal 1
Quant
Ret.
Time
(min)
Area
Conc. as
Analyzed
(ppbv)
Sample
Conc.
(ppbv)
Flags % Difference
Sample
Conc.
(ug/m3)
41 NA 0 0.200 0.355 ND 0.0 0.611
85 NA 0 0.200 0.355 ND 4.5 1.76
85 NA 0 0.200 0.355 ND 0.0 2.48
50 NA 0 0.200 0.355 ND 0.0 0.734
62 NA 0 0.200 0.355 ND 0.0 0.908
39 NA 0 0.200 0.355 ND 0.0 0.786
94 NA 0 0.200 0.355 ND 0.0 1.38
64 NA 0 0.200 0.355 ND 0.0 0.937
106 NA 0 0.200 0.355 ND 0.0 1.55
101 NA 0 0.200 0.355 ND 0.0 2.00
45 7.86 109,163 5.14 9.13 6.0 17.2
56 NA 0 0.200 0.355 ND 0.0 0.815
151 NA 0 0.200 0.355 ND 0.0 2.72
61 NA 0 0.200 0.355 ND 0.0 1.41
43 8.75 1,444,026 11.7 20.8 6.5 49.5
76 9.16 49,043 0.287 0.510 J 5.8 1.59
45 9.10 208,958 1.65 2.94 9.9 7.22
76 NA 0 0.200 0.355 ND 0.0 1.11
41 9.36 17,482 0.280 0.497 J 0.7 0.834
49 9.79 44,561 0.473 0.839 J 11.8 2.92
61 NA 0 0.200 0.355 ND 0.0 1.41
73 NA 0 0.200 0.355 ND 0.0 1.28
53 NA 0 0.200 0.355 ND 0.0 0.771
57 11.04 22,823 0.258 0.459 J 25.5 1.62
63 NA 0 0.200 0.355 ND 0.0 1.44
43 NA 0 0.200 0.355 ND 0.0 1.25
61 NA 0 0.200 0.355 ND 0.0 1.41
72 12.56 48,654 1.73 3.08 3.9 9.08
45 12.65 39,961 1.62 2.88 7.0 10.4
83 13.24 53,069 0.411 0.730 J 4.2 3.57
72 NA 0 0.200 0.355 ND 0.0 1.05
97 NA 0 0.200 0.355 ND 0.0 1.94
56 NA 0 0.200 0.355 ND 0.0 1.22
117 NA 0 0.200 0.355 ND 0.0 2.24
78 NA 0 0.200 0.355 ND 0.0 1.14
57 NA 0 0.200 0.355 ND 0.0 1.66
62 NA 0 0.200 0.355 ND 0.0 1.44
57 NA 0 0.200 0.355 ND 0.0 1.46
130 NA 0 0.200 0.355 ND 0.0 1.91
63 NA 0 0.200 0.355 ND 0.0 1.64
69 NA 0 0.200 0.355 ND 0.0 1.45
88 NA 0 0.200 0.355 ND 0.0 1.28
83 NA 0 0.200 0.355 ND 0.0 2.38
75 NA 0 0.200 0.355 ND 0.0 1.61
43 NA 0 0.200 0.355 ND 0.0 1.46
91 17.40 133,048 0.705 1.25 J 16.4 4.72
75 NA 0 0.200 0.355 ND 0.0 1.61
TO15-Tyner St.-V-1-Can #00206 LD
cis-1,3-Dichloropropene
Methyl isobutyl ketone
Toluene
trans-1,3-Dichloropropene
Methyl methacrylate
1,4-Dioxane
Benzene
2,2,4-trimethylpentane
1,2-Dichloroethane
Heptane
Methyl ethyl ketone (2-Butanone)
Ethyl acetate
Chloroform
Bromodichloromethane
Tetrahydrofuran
1,1,1-Trichloroethane
Cyclohexane
Carbon tetrachloride
Trichloroethene
1,2-Dichloropropane
Hexane
1,1-Dichloroethane
Vinyl acetate
cis-1,2-Dichloroethylene
Methylene chloride
trans-1,2-Dichloroethene
Methyl tert-butyl ether
Acrylonitrile
Allyl chloride (3-chloropropene)
Acetonitrile
Acrolein
Freon 113 (C2Cl3F3)
1,1-Dichloroethene
Acetone
Freon 11 (CCl3F)
Ethanol
Compound
0612-142, 500mL load
Carbon disulfide
Isopropyl alcohol
Propylene
Freon 12 (CCl2F2)
Freon 114 (C2Cl2F4)
Chloromethane
Chloroethene (Vinyl chloride)
1,3-Butadiene
Bromomethane
Chloroethane
Bromoethene (Vinyl bromide)
Company
Analyst
Parameters
AWARE Environmental, Inc.
DB
EPA Method TO-15 TCL
Client #
Job #
# Samples
N508-05
0612-142
5 (1.4L) Canisters
0612-142R results 8/11/2012
Sample ID:DF: 1.00
Data File: L1201447.D Tank DF: 1.776
Tank/Misc ID:ConCal 1
Quant
Ret.
Time
(min)
Area
Conc. as
Analyzed
(ppbv)
Sample
Conc.
(ppbv)
Flags % Difference
Sample
Conc.
(ug/m3)
TO15-Tyner St.-V-1-Can #00206 LD
Compound
0612-142, 500mL load
Company
Analyst
Parameters
AWARE Environmental, Inc.
DB
EPA Method TO-15 TCL
Client #
Job #
# Samples
N508-05
0612-142
5 (1.4L) Canisters
97 NA 0 0.200 0.355 ND 0.0 1.94
166 18.10 1,232,794 12.7 22.6 5.8 153
43 18.19 107,079 0.633 1.12 J 17.6 4.61
129 NA 0 0.200 0.355 ND 0.0 3.03
107 NA 0 0.200 0.355 ND 0.0 2.73
112 NA 0 0.200 0.355 ND 0.0 1.64
91 NA 0 0.200 0.355 ND 0.0 1.54
131 NA 0 0.200 0.355 ND 0.0 2.44
91 19.30 95,704 0.524 0.931 J 9.7 4.04
91 19.69 43,316 0.232 0.412 J 11.1 1.79
104 19.71 41,101 0.267 0.475 J 9.7 2.02
173 NA 0 0.200 0.355 ND 0.0 3.67
83 NA 0 0.200 0.355 ND 0.0 2.44
105 NA 0 0.200 0.355 ND 0.0 1.75
91 NA 0 0.200 0.355 ND 0.0 1.84
105 NA 0 0.200 0.355 ND 0.0 1.75
105 20.83 84,249 0.413 0.733 J 4.8 3.60
146 NA 0 0.200 0.355 ND 0.0 2.14
146 21.18 74,324 0.513 0.910 J 1.0 5.47
91 NA 0 0.200 0.355 ND 0.0 1.84
146 NA 0 0.200 0.355 ND 0.0 2.14
180 NA 0 0.200 0.355 ND 0.0 2.64
225 NA 0 0.200 0.355 ND 0.0 3.79
128 NA 0 0.200 0.355 ND 0.0 1.86
Rec. (%) Flags
130 13.06 533,672 11.03 N/A
114 14.86 2,044,908 10.52 N/A
117 19.07 1,862,098 11.20 N/A
Internal Standard Acceptance Criteria (Area +/- 40%, RT +/- 20 sec.)
Concal Sample Ave. ICal Flag
RT RT IS Area
13.04 13.06 539,287 Pass
14.85 14.86 2,012,245 Pass
19.07 19.07 1,964,160 Pass
1,4-Difluorobenzene (IS)2,044,908
Chlorobenzene-d5 (IS)1,862,098
Sample
Name IS Area
Bromochloromethane (IS)533,672
1,2,4-Trichlorobenzene
Hexachlorobutadiene
Naphthalene
Internal Standard
1,4-Difluorobenzene (IS)
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl chloride
1,2-Dichlorobenzene
Chlorobenzene-d5 (IS)
4-Ethyltoluene
2-Chlorotoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
o-Xylene
Styrene
Bromoform
1,1,2,2-Tetrachloroethane
Chlorobenzene
Ethylbenzene
1,1,1,2-Tetrachloroethane
m-/p-Xylenes
1,1,2-Trichloroethane
Tetrachloroethene
2-Hexanone (Methyl butyl ketone)
Dibromochloromethane
1,2-Dibromoethane
Bromochloromethane (IS)
0612-142R results 8/11/2012
Sample ID:DF: 1.00
Data File: L1201440.D Tank DF: 1.00
Tank/Misc ID:ConCal 1
Quant
Ret.
Time
(min)
Area
Conc. as
Analyzed
(ppbv)
Sample
Conc.
(ppbv)
Flags
Sample
Conc.
(ug/m3)
41 NA 0 0.200 0.200 ND 0.344
85 NA 0 0.200 0.200 ND 0.989
85 NA 0 0.200 0.200 ND 1.40
50 NA 0 0.200 0.200 ND 0.413
62 NA 0 0.200 0.200 ND 0.511
39 NA 0 0.200 0.200 ND 0.442
94 NA 0 0.200 0.200 ND 0.777
64 NA 0 0.200 0.200 ND 0.528
106 NA 0 0.200 0.200 ND 0.875
101 NA 0 0.200 0.200 ND 1.12
45 7.84 7,253 0.368 0.368 J 0.693
56 NA 0 0.200 0.200 ND 0.459
151 NA 0 0.200 0.200 ND 1.53
61 NA 0 0.200 0.200 ND 0.793
43 8.76 27,653 0.242 0.242 J 0.574
76 NA 0 0.200 0.200 ND 0.623
45 NA 0 0.200 0.200 ND 0.492
76 NA 0 0.200 0.200 ND 0.626
41 NA 0 0.200 0.200 ND 0.336
49 9.77 30,514 0.349 0.349 J 1.21
61 NA 0 0.200 0.200 ND 0.793
73 NA 0 0.200 0.200 ND 0.721
53 NA 0 0.200 0.200 ND 0.434
57 NA 0 0.200 0.200 ND 0.705
63 NA 0 0.200 0.200 ND 0.809
43 NA 0 0.200 0.200 ND 0.704
61 NA 0 0.200 0.200 ND 0.793
72 NA 0 0.200 0.200 ND 0.590
45 NA 0 0.200 0.200 ND 0.721
83 NA 0 0.200 0.200 ND 0.976
72 NA 0 0.200 0.200 ND 0.590
97 NA 0 0.200 0.200 ND 1.09
56 NA 0 0.200 0.200 ND 0.688
117 NA 0 0.200 0.200 ND 1.26
78 NA 0 0.200 0.200 ND 0.639
57 NA 0 0.200 0.200 ND 0.934
62 NA 0 0.200 0.200 ND 0.809
57 NA 0 0.200 0.200 ND 0.820
130 NA 0 0.200 0.200 ND 1.07
63 NA 0 0.200 0.200 ND 0.924
69 NA 0 0.200 0.200 ND 0.819
88 NA 0 0.200 0.200 ND 0.721
83 NA 0 0.200 0.200 ND 1.34
75 NA 0 0.200 0.200 ND 0.908
43 NA 0 0.200 0.200 ND 0.819
91 NA 0 0.200 0.200 ND 0.754
75 NA 0 0.200 0.200 ND 0.908
Methyl isobutyl ketone
Toluene
trans-1,3-Dichloropropene
2,2,4-trimethylpentane
1,2-Dichloroethane
Heptane
cis-1,3-Dichloropropene
Bromodichloromethane
Trichloroethene
1,2-Dichloropropane
Methyl methacrylate
1,4-Dioxane
Benzene
cis-1,2-Dichloroethylene
Methyl ethyl ketone (2-Butanone)
Ethyl acetate
Chloroform
Tetrahydrofuran
1,1,1-Trichloroethane
Cyclohexane
Carbon tetrachloride
Acrylonitrile
Hexane
1,1-Dichloroethane
Vinyl acetate
Acetonitrile
Methylene chloride
trans-1,2-Dichloroethene
Methyl tert-butyl ether
Acetone
Carbon disulfide
Isopropyl alcohol
Allyl chloride (3-chloropropene)
Ethanol
Acrolein
Freon 113 (C2Cl3F3)
1,1-Dichloroethene
Bromomethane
Chloroethane
Bromoethene (Vinyl bromide)
Freon 11 (CCl3F)
Compound
humid blank
500mL load, can #10893
Propylene
Freon 12 (CCl2F2)
Freon 114 (C2Cl2F4)
Chloromethane
Chloroethene (Vinyl chloride)
1,3-Butadiene
Company
Analyst
Parameters
AWARE Environmental, Inc.
DB
EPA Method TO-15 TCL
Client #
Job #
# Samples
N508-05
0612-142
5 (1.4L) Canisters
0612-142R results 8/11/2012
Sample ID:DF: 1.00
Data File: L1201440.D Tank DF: 1.00
Tank/Misc ID:ConCal 1
Quant
Ret.
Time
(min)
Area
Conc. as
Analyzed
(ppbv)
Sample
Conc.
(ppbv)
Flags
Sample
Conc.
(ug/m3)
Compound
humid blank
500mL load, can #10893
Company
Analyst
Parameters
AWARE Environmental, Inc.
DB
EPA Method TO-15 TCL
Client #
Job #
# Samples
N508-05
0612-142
5 (1.4L) Canisters
97 NA 0 0.200 0.200 ND 1.09
166 NA 0 0.200 0.200 ND 1.36
43 NA 0 0.200 0.200 ND 0.819
129 NA 0 0.200 0.200 ND 1.70
107 NA 0 0.200 0.200 ND 1.54
112 NA 0 0.200 0.200 ND 0.921
91 NA 0 0.200 0.200 ND 0.868
131 NA 0 0.200 0.200 ND 1.37
91 NA 0 0.200 0.200 ND 0.868
91 NA 0 0.200 0.200 ND 0.868
104 NA 0 0.200 0.200 ND 0.852
173 NA 0 0.200 0.200 ND 2.07
83 NA 0 0.200 0.200 ND 1.37
105 NA 0 0.200 0.200 ND 0.983
91 NA 0 0.200 0.200 ND 1.04
105 NA 0 0.200 0.200 ND 0.983
105 NA 0 0.200 0.200 ND 0.983
146 NA 0 0.200 0.200 ND 1.20
146 NA 0 0.200 0.200 ND 1.20
91 NA 0 0.200 0.200 ND 1.04
146 NA 0 0.200 0.200 ND 1.20
180 NA 0 0.200 0.200 ND 1.48
225 NA 0 0.200 0.200 ND 2.13
128 NA 0 0.200 0.200 ND 1.05
Rec. (%) Flags
130 13.05 495,375 11.03 N/A
114 14.85 1,927,918 10.52 N/A
117 19.07 1,837,448 11.20 N/A
Internal Standard Acceptance Criteria (Area +/- 40%, RT +/- 20 sec.)
Concal Sample Ave. ICal Flag
RT RT IS Area
13.04 13.05 539,287 Pass
14.85 14.85 2,012,245 Pass
19.07 19.07 1,964,160 Pass
1,4-Difluorobenzene (IS)1,927,918
Chlorobenzene-d5 (IS)1,837,448
Sample
Name IS Area
Bromochloromethane (IS)495,375
Hexachlorobutadiene
Naphthalene
Internal Standard
1,4-Difluorobenzene (IS)
1,4-Dichlorobenzene
Benzyl chloride
1,2-Dichlorobenzene
1,2,4-Trichlorobenzene
2-Chlorotoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3-Dichlorobenzene
Styrene
Bromoform
1,1,2,2-Tetrachloroethane
4-Ethyltoluene
Ethylbenzene
1,1,1,2-Tetrachloroethane
m-/p-Xylenes
o-Xylene
Chlorobenzene-d5 (IS)
1,1,2-Trichloroethane
Tetrachloroethene
2-Hexanone (Methyl butyl ketone)
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
Bromochloromethane (IS)
0612-142R results 8/11/2012
Sample ID:DF: 1.00
Data File: L1201439.D Tank DF: 1.00
Tank/Misc ID: ConCal 1
Quant
Ret.
Time
(min)
Area
Conc. as
Analyzed
(ppbv)
Sample
Conc.
(ppbv)
Flags Tag Value
% Diff.
From Tag Pass/Fail
41 4.68 510,680 9.33 9.33 9.08 2.8 PASS
85 4.78 1,253,461 8.22 8.22 8.17 0.7 PASS
85 5.15 1,400,512 8.49 8.49 8.33 1.9 PASS
50 5.27 524,538 8.77 8.77 8.42 4.3 PASS
62 5.60 493,049 8.82 8.82 8.42 4.8 PASS
39 5.72 473,255 9.27 9.27 8.75 6.0 PASS
94 6.47 522,505 8.33 8.33 8.42 1.0 PASS
64 6.76 258,353 8.46 8.46 8.33 1.5 PASS
106 7.23 452,817 7.88 7.88 8.25 4.5 PASS
101 7.41 1,073,328 8.39 8.39 8.66 3.1 PASS
45 7.84 159,496 8.51 8.51 8.42 1.1 PASS
56 8.41 164,871 8.17 8.17 8.99 9.1 PASS
151 8.67 524,587 7.50 7.50 8.09 7.3 PASS
61 8.63 649,129 7.50 7.50 8.17 8.2 PASS
43 8.73 843,497 7.76 7.76 8.66 10.5 PASS
76 9.14 1,183,442 7.85 7.85 8.17 3.8 PASS
45 9.09 942,091 8.44 8.44 8.99 6.1 PASS
76 9.49 187,209 7.84 7.84 8.50 7.7 PASS
41 9.35 396,518 7.18 7.18 7.59 5.4 PASS
49 9.77 615,059 7.39 7.39 8.33 11.3 PASS
61 10.39 619,258 7.83 7.83 8.25 5.1 PASS
73 10.39 1,111,669 8.16 8.16 8.66 5.7 PASS
53 10.28 335,816 7.69 7.69 8.25 6.8 PASS
57 11.02 627,509 8.05 8.05 8.58 6.2 PASS
63 11.36 771,155 8.05 8.05 8.42 4.3 PASS
43 11.36 1,619,125 8.55 8.55 8.83 3.1 PASS
61 12.58 750,744 8.13 8.13 8.58 5.2 PASS
72 12.55 211,668 8.54 8.54 8.83 3.2 PASS
45 12.64 181,971 8.37 8.37 8.50 1.5 PASS
83 13.23 913,303 8.01 8.01 8.50 5.7 PASS
72 13.09 203,083 8.35 8.35 8.83 5.5 PASS
97 13.56 888,178 7.86 7.86 8.50 7.5 PASS
56 13.70 670,311 8.17 8.17 8.58 4.8 PASS
117 13.84 892,404 7.78 7.78 8.33 6.7 PASS
78 14.18 1,209,655 7.88 7.88 8.58 8.1 PASS
57 14.37 2,042,453 7.87 7.87 8.42 6.5 PASS
62 14.26 607,177 7.90 7.90 8.66 8.8 PASS
57 14.64 417,493 8.23 8.23 8.75 5.9 PASS
130 15.23 606,196 7.81 7.81 8.66 9.9 PASS
63 15.64 492,332 8.43 8.43 8.75 3.6 PASS
69 15.68 481,716 8.31 8.31 8.75 5.0 PASS
88 15.74 296,599 8.34 8.34 8.66 3.7 PASS
83 16.06 1,078,686 8.12 8.12 8.66 6.2 PASS
75 16.79 835,951 8.39 8.39 8.99 6.7 PASS
43 17.01 1,484,678 8.72 8.72 8.92 2.2 PASS
91 17.39 1,466,015 7.91 7.91 8.83 10.4 PASS
75 17.69 747,026 7.57 7.57 8.25 8.3 PASS
97 17.95 598,888 7.98 7.98 8.83 9.6 PASS
166 18.09 753,145 7.90 7.90 8.66 8.8 PASS
43 18.18 1,475,899 8.88 8.88 8.99 1.3 PASS
129 18.42 1,127,022 8.17 8.17 8.99 9.1 PASS
Compound
5.0ppbv TO-15 LCS std
125mL load, can #1414
Propylene
Freon 12 (CCl2F2)
Freon 114 (C2Cl2F4)
Chloromethane
Chloroethene (Vinyl chloride)
1,3-Butadiene
Ethanol
Acrolein
Freon 113 (C2Cl3F3)
1,1-Dichloroethene
Bromomethane
Chloroethane
Bromoethene (Vinyl bromide)
Freon 11 (CCl3F)
Acetonitrile
Methylene chloride
trans-1,2-Dichloroethene
Methyl tert-butyl ether
Acetone
Carbon disulfide
Isopropyl alcohol
Allyl chloride (3-chloropropene)
Cyclohexane
Carbon tetrachloride
Acrylonitrile
Hexane
1,1-Dichloroethane
Vinyl acetate
1,2-Dichloropropane
Methyl methacrylate
1,4-Dioxane
Benzene
cis-1,2-Dichloroethylene
Methyl ethyl ketone (2-Butanone)
Ethyl acetate
Chloroform
Tetrahydrofuran
1,1,1-Trichloroethane
2-Hexanone (Methyl butyl ketone)
Dibromochloromethane
2,2,4-trimethylpentane
1,2-Dichloroethane
Heptane
cis-1,3-Dichloropropene
Bromodichloromethane
Trichloroethene
Methyl isobutyl ketone
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethene
Company
Analyst
Parameters
AWARE Environmental, Inc.
DB
EPA Method TO-15 TCL
Client #
Job #
# Samples
N508-05
0612-142
5 (1.4L) Canisters
0612-142 results 7/18/2012
Sample ID:DF: 1.00
Data File: L1201439.D Tank DF: 1.00
Tank/Misc ID: ConCal 1
Quant
Ret.
Time
(min)
Area
Conc. as
Analyzed
(ppbv)
Sample
Conc.
(ppbv)
Flags Tag Value
% Diff.
From Tag Pass/FailCompound
5.0ppbv TO-15 LCS std
125mL load, can #1414
Company
Analyst
Parameters
AWARE Environmental, Inc.
DB
EPA Method TO-15 TCL
Client #
Job #
# Samples
N508-05
0612-142
5 (1.4L) Canisters
107 18.58 1,010,844 7.90 7.90 8.75 9.7 PASS
112 19.09 1,288,863 8.21 8.21 8.99 8.7 PASS
91 19.17 2,069,454 8.94 8.94 8.91 0.3 PASS
131 19.17 684,191 7.77 7.77 8.25 5.8 PASS
91 19.30 3,078,792 17.2 17.2 17.5 1.9 PASS
91 19.68 1,636,087 8.91 8.91 9.08 1.8 PASS
104 19.70 1,315,482 8.71 8.71 8.99 3.2 PASS
173 19.89 1,031,071 8.28 8.28 8.75 5.3 PASS
83 20.26 1,422,845 9.08 9.08 9.08 0.1 PASS
105 20.46 2,351,680 9.19 9.19 8.75 5.1 PASS
91 20.46 1,990,858 8.74 8.74 8.33 4.8 PASS
105 20.50 1,678,520 8.75 8.75 8.91 1.8 PASS
105 20.82 1,786,710 8.91 8.91 8.91 0.0 PASS
146 21.10 1,254,957 8.98 8.98 9.08 1.1 PASS
146 21.18 1,253,878 8.80 8.80 8.83 0.3 PASS
91 21.26 1,802,937 8.85 8.85 9.08 2.5 PASS
146 21.48 1,150,468 8.75 8.75 8.91 1.8 PASS
180 22.84 703,181 7.83 7.83 8.75 10.4 PASS
225 22.94 526,553 8.62 8.62 8.75 1.4 PASS
128 23.12 1,831,947 7.41 7.41 8.09 8.4 PASS
Rec. (%) Flags
130 13.05 471,063 11.03 N/A
114 14.85 1,817,409 10.52 N/A
117 19.06 1,830,096 11.20 N/A
Internal Standard Acceptance Criteria (Area +/- 40%, RT +/- 20 sec.)
Concal Sample Ave. ICal Flag
RT RT IS Area
13.04 13.05 539,287 Pass
14.85 14.85 2,012,245 Pass
19.07 19.06 1,964,160 Pass
Bromochloromethane (IS)
1,2-Dibromoethane
Chlorobenzene
Ethylbenzene
1,1,1,2-Tetrachloroethane
m-/p-Xylenes
o-Xylene
Chlorobenzene-d5 (IS)
2-Chlorotoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3-Dichlorobenzene
Styrene
Bromoform
1,1,2,2-Tetrachloroethane
4-Ethyltoluene
Hexachlorobutadiene
Naphthalene
Internal Standard
1,4-Difluorobenzene (IS)
1,4-Dichlorobenzene
Benzyl chloride
1,2-Dichlorobenzene
1,2,4-Trichlorobenzene
1,4-Difluorobenzene (IS)1,817,409
Chlorobenzene-d5 (IS)1,830,096
Sample
Name IS Area
Bromochloromethane (IS)471,063
0612-142 results 7/18/2012
SampleIDTankIDTankDilutionCanister Size (L)Sample Vol (L)at STPTempField(F)PbarField(mmHg)GaugeField(mmHg)TempLab/Field(F)PbarLab/Field(mmHg)GaugeLab/Field(mmHg)TempLab(F)PbarLab(mmHg)GaugeLab(mmHg)TO15-Tyner St.-V-1 00206 1.776 1.29 1.22 64.5 757 -757 65.5 749 -33 65.5 749 523TO15-Tyner St.-V-2 00208 1.765 1.29 1.20 64.5 757 -757 65.5 749 -43 65.5 749 497TO15-Tyner St.-V-3 00147 1.757 1.29 1.21 64.5 757 -757 65.5 749 -41 65.5 749 495TO15-Tyner St.-V-4 00192 1.751 1.29 1.21 64.5 757 -757 65.5 749 -42 65.5 749 489TO15-Tyner St.-V-Dup 00229 1.830 1.29 1.20 64.5 757 -757 65.5 749 -47 65.5 749 536Pre-samplePost-sampleFinalThe tank dilution factors are calculated using the following formula:460460///460TempFieldPbarFieldGaugeFieldFieldTempLabFieldPbarLabFieldGaugeLabTempLabPbarLabGaugeLabCompanyAnalystParametersAWARE Environmental, Inc.DBTank DilutionsClient #Job ## SamplesN508-050612-1425 (1.4L) Canisters0612-142 results7/18/2012

Narrative Summary

Enthalpy Analytical Narrative Summary

Company AWARE Environmental Client #N508-05
Analyst DB Job #0612-142
Parameters EPA Method TO-15 # Samples 5 (1.4L) Canisters

Custody Lindsey Chatterton received the samples on 6/29/12 after being
relinquished by AWARE Environmental, Inc. The samples were
received at ambient temperature and in good condition. Prior to, during,
and after analysis, the samples were kept under lock with access only to
authorized personnel by Enthalpy Analytical, Inc.
Analysis The samples were analyzed for TO-15 Target Compound List using the
analytical procedures in EPA Method TO-15, Determination of Volatile
Organic Compounds (VOCs) In Air Collected In Specially-Prepared
Canisters And Analyzed by Gas Chromatography/Mass Spectrometry
(GC/MS). The samples were analyzed following the procedures in
Section 10.0, Sample Analysis.
The samples were received at near ambient pressure and were
pressurized with zero air prior to sample analysis. The canister dilution
factor values were determined and presented on the Tank Dilution page
in the Results section of this report.
The Hewlett Packard Model 5890, Gas Chromatograph ("Lurch" S/N
2750A15233) was equipped with a 5971A Mass Selective Detector and
a Restek Rxi-624 Sil MS, 60 m x 0.32 mm x 1.8 µm (S/N 1035491)
capillary column for these analyses. All samples and standards were
introduced directly to the analyzer using an Entech 7100A
Preconcentrator.
Calibration A copy of the calibration curve is included in the Calibration Curve
Chromatograms section of this report.
Chromatographic
Conditions
The acquisition method MM624-L.M is included in the Curve/QA
Chromatograms section of this report.
QC Notes All target compounds met the 30% initial calibration RSD and the 30%
continuing calibration %D.
The ICV and LCS met %D acceptance criteria.
All internal standard area responses and retention time criteria were met.

Enthalpy Analytical Narrative Summary
(continued)

QC Notes
(continued)
The duplicate analyses associated with this set of data met QC criteria
of less than 25% D for all non-J flagged analytes.
The method blanks associated with the analyzed samples contained no
target analytes at concentrations greater than the method acceptable
criteria of 3x the MDL (0.6 ppbv for this project).
The samples were analyzed within the 30-day holding time required by
the method.
Reporting Notes The instrument was calibrated from approximately 0.66 ppbv to 50
ppbv.
These analyses met the requirements of the NELAC Standard. Any
deviations from the requirements of the reference method and/or the
NELAC Standard have been previously noted in this narrative.
The results presented in this report are representative of the samples as
provided to the laboratory.

General Reporting Notes

The following are general reporting notes that are applicable to all Enthalpy Analytical, Inc. data
reports, unless specifically noted otherwise.

The acronym MDL represents the Minimum Detection Limit. Below this value the laboratory cannot
determine the presence of the analyte of interest reliably.
The acronym LOQ represents the Limit of Quantification. Below this value the laboratory cannot
quantitate the analyte of interest within the criteria of the method.
The acronym ND following a value indicates a non-detect or analytical result below the MDL.
The letter J following a value indicates an analytical result between the MDL and the LOQ. A J flag
indicates that the laboratory can positively identify the analyte of interest as present, but the value
should be considered an estimate.
The letter E following a value indicates an analytical result exceeding 100% of the highest calibration
point. The associated value should be considered as an estimate.
The acronym DF represents Dilution Factor. This number represents dilution of the sample during the
preparation and/or analysis process. The analytical result taken from a laboratory instrument is
multiplied by the DF to determine the final undiluted sample results.
The addition of MS to the Sample ID represents a Matrix Spike. An aliquot of an actual sample is
spiked with a known amount of analyte so that a percent recovery value can be determined. This shows
what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample
matrix interferes with the analysis of the analyte(s).
The addition of MSD to the Sample ID represents a Matrix Spike Duplicate. Prepared in the same
manner as an MS, the use of duplicate matrix spikes allows further confirmation of laboratory quality
by showing the consistency of results gained by performing the same steps multiple times.
The addition of LD to the Sample ID represents a Laboratory Duplicate. The analyst prepares an
additional aliquot of sample for testing and the results of the duplicate analysis are compared to the
initial result. The result should have a difference value of within 10% of the initial result (if the results
of the original analysis are greater than the LOQ).
The addition of AD to the Sample ID represents an Alternate Dilution. The analyst prepares an
additional aliquot at a different dilution factor (usually double the initial factor). This analysis helps
confirm that no additional compound is present and coeluting or sharing absorbance with the analyte of
interest, as they would have a different response/absorbance than the analyte of interest.
The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample
matrix, prepared and analyzed by the laboratory using the same reagents, spiking standards and
procedures used for the client samples. The LCS is used to assess the control of the laboratory’s
analytical system. Whenever spikes are prepared for our client projects, two extra spikes are prepared.
The extras (randomly chosen) are labeled with the associated project number and kept in-house at the
appropriate temperature conditions. When the project samples are received for analysis, the LCSs are
analyzed to confirm that the analyte could be recovered from the media, separate from the samples
which were used on the project and which may have been affected by source matrix, sample collection
and/or sample transport.

General Reporting Notes
(continued)

Significant Figures: Where the reported value is much greater than unity (1.00) in the units expressed,
the number is rounded to a whole number of units, rather than to 3 significant figures. For example, a
value of 10,456.45 ug catch is rounded to 10,456 ug. There are five significant digits displayed, but no
confidence should be placed on more than two significant digits.
Manual Integration: The data systems used for processing will flag manually integrated peaks with
an “M”. There are several reasons a peak may be manually integrated. These reasons will be identified
by the following two letter designations. The peak was not integrated by the software “NI”, the peak
was integrated incorrectly by the software “II” or the wrong peak was integrated by the software
“WP”. These codes will accompany the analyst’s manual integration stamp placed next to the
compound name.

Sample Custody

Sample
Chromatograms
Quantitation Report
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201442.D Vial: 2
Acq On : 3 Jul 2012 1:46 pm Operator: DB
Sample : TO15-Tyner St.-V-1-Can #00206 Inst : Lurch
Misc : 0612-142, 500mL load Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 11:54 2012 Quant Results File: L062912C.RES
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00
0
1000000
2000000
3000000
4000000
5000000
6000000
7000000
8000000
9000000
1e+07
1.1e+07
1.2e+07
1.3e+07
1.4e+07
1.5e+07
1.6e+07
Time-->
Abundance TIC: L1201442.D
1,4-Dichlorobenzene1,2,4-TrimethylbenzeneStyreneo-Xylenem-/p-XylenesChlorobenzene-d5 (IS),I2-Hexanone (Methyl butyl ketone)TetrachloroetheneToluene1,4-Difluorobenzene (IS),IChloroformBromochloromethane (IS),IEthyl acetateMethyl ethyl ketone (2-Butanone)Methylene chlorideAcetonitrileCarbon disulfideIsopropyl alcoholAcetoneEthanolFreon 12 (CCl2F2)L1201442.D L062912C.M Wed Jul 11 12:01:50 2012 Page 3
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201442.D Vial: 2
Acq On : 3 Jul 2012 1:46 pm Operator: DB
Sample : TO15-Tyner St.-V-1-Can #00206 Inst : Lurch
Misc : 0612-142, 500mL load Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 11:54 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) Bromochloromethane (IS) 13.05 130 480464 11.03 PPBV -0.03
36) 1,4-Difluorobenzene (IS) 14.85 114 1849588 10.52 PPBV -0.03
48) Chlorobenzene-d5 (IS) 19.07 117 1788038 11.20 PPBV -0.02
Target Compounds Qvalue
2) Propylene 0.00 41 0 N.D. d
3) Freon 12 (CCl2F2) 4.78 85 32538 0.21 PPBV # 97
4) Freon 114 (C2Cl2F4) 0.00 85 0 N.D. d
5) Chloromethane 0.00 50 0 N.D. d
6) Chloroethene (Vinyl chlori 0.00 62 0 N.D.
7) 1,3-Butadiene 0.00 39 0 N.D. d
8) Bromomethane 0.00 94 0 N.D.
9) Chloroethane 0.00 64 0 N.D.
10) Bromoethene (Vinyl bromide 0.00 106 0 N.D.
11) Freon 11 (CCl3F) 0.00 101 0 N.D. d
12) Ethanol 7.85 45 92538 4.84 PPBV # 85
13) Acrolein 0.00 56 0 N.D. d
14) Freon 113 (C2Cl3F3) 0.00 151 0 N.D. d
15) 1,1-Dichloroethene 0.00 61 0 N.D.
16) Acetone 8.75 43 1217781 10.98 PPBV # 81
17) Carbon disulfide 9.15 76 41687 0.27 PPBV # 63
18) Isopropyl alcohol 9.09 45 170372 1.50 PPBV # 85
19) Allyl chloride (3-chloropr 0.00 76 0 N.D.
20) Acetonitrile 9.35 41 15629 0.28 PPBV # 88
21) Methylene chloride 9.77 49 35662 0.42 PPBV # 77
22) trans-1,2-Dichloroethene 0.00 61 0 N.D.
23) Methyl tert-butyl ether 0.00 73 0 N.D. d
24) Acrylonitrile 0.00 53 0 N.D. d
25) Hexane 11.02 57 14432 N.D.
26) 1,1-Dichloroethane 0.00 63 0 N.D.
27) Vinyl acetate 0.00 43 0 N.D. d
28) cis-1,2-Dichloroethylene 0.00 61 0 N.D. d
29) Methyl ethyl ketone (2-But 12.55 72 42108 1.67 PPBV 77
30) Ethyl acetate 12.64 45 33530 1.51 PPBV # 80
31) Chloroform 13.23 83 45826 0.39 PPBV 99
32) Tetrahydrofuran 0.00 72 0 N.D. d
33) 1,1,1-Trichloroethane 0.00 97 0 N.D.
34) Cyclohexane 0.00 56 0 N.D. d
35) Carbon tetrachloride 0.00 117 0 N.D. d
37) Benzene 0.00 78 0 N.D. d
38) 2,2,4-trimethylpentane 0.00 57 0 N.D. d
39) 1,2-Dichloroethane 0.00 62 0 N.D.
40) Heptane 0.00 57 0 N.D. d
41) Trichloroethene 0.00 130 0 N.D.
42) 1,2-Dichloropropane 0.00 63 0 N.D.
43) Methyl methacrylate 0.00 69 0 N.D. d
44) 1,4-Dioxane 0.00 88 0 N.D.
45) Bromodichloromethane 0.00 83 0 N.D. d
46) cis-1,3-Dichloropropene 0.00 75 0 N.D.
47) Methyl isobutyl ketone 0.00 43 0 N.D. d
49) Toluene 17.40 91 108367 0.60 PPBV 93
50) trans-1,3-Dichloropropene 0.00 75 0 N.D. d
51) 1,1,2-Trichloroethane 0.00 97 0 N.D.
52) Tetrachloroethene 18.09 166 1116779 11.99 PPBV 95
53) 2-Hexanone (Methyl butyl k 18.18 43 86179 0.53 PPBV # 93
54) Dibromochloromethane 0.00 129 0 N.D. d
55) 1,2-Dibromoethane 0.00 107 0 N.D.
56) Chlorobenzene 0.00 112 0 N.D. d
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201442.D L062912C.M Wed Jul 11 12:01:50 2012 Page 1
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201442.D Vial: 2
Acq On : 3 Jul 2012 1:46 pm Operator: DB
Sample : TO15-Tyner St.-V-1-Can #00206 Inst : Lurch
Misc : 0612-142, 500mL load Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 11:54 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Compound R.T. QIon Response Conc Unit Qvalue
-------------------------------------------------------------------------
57) Ethylbenzene 0.00 91 0 N.D. d
58) 1,1,1,2-Tetrachloroethane 0.00 131 0 N.D.
59) m-/p-Xylenes 19.30 91 83422 0.48 PPBV 97
60) o-Xylene 19.68 91 37233 0.21 PPBV 95
61) Styrene 19.70 104 35816 0.24 PPBV 91
62) Bromoform 0.00 173 0 N.D.
63) 1,1,2,2-Tetrachloroethane 0.00 83 0 N.D. d
64) 4-Ethyltoluene 0.00 105 0 N.D. d
65) 2-Chlorotoluene 0.00 91 0 N.D. d
66) 1,3,5-Trimethylbenzene 0.00 105 0 N.D. d
67) 1,2,4-Trimethylbenzene 20.83 105 77144 0.39 PPBV # 78
68) 1,3-Dichlorobenzene 0.00 146 0 N.D. d
69) 1,4-Dichlorobenzene 21.18 146 70646m 0.51 PPBV
70) Benzyl chloride 0.00 91 0 N.D. d
71) 1,2-Dichlorobenzene 0.00 146 0 N.D. d
72) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. d
73) Hexachlorobutadiene 0.00 225 0 N.D.
74) Naphthalene 0.00 128 0 N.D. d
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201442.D L062912C.M Wed Jul 11 12:01:50 2012 Page 2
#3
Freon 12 (CCl2F2)
Concen: 0.21 PPBV
RT: 4.78 min Scan# 157
Delta R.T. -0.03 min
Lab File: L1201442.D
Acq: 3 Jul 2012 1:46 pm
Tgt Ion: 85 Resp: 32538
Ion Ratio Lower Upper
85 100
87 32.1 26.7 40.1
101 7.7 8.2 12.2#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 185 (4.896 min): L1103939.D (-)
85
50 10331 220 241125 274 298145163 184
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 157 (4.784 min): L1201442.D
32
85
50 103 272290122207 244
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 157 (4.784 min): L1201442.D (-)
85
5031 103 276251 293122209
4.70 4.80 4.90
0
5000
10000
15000
Time-->
AbundanceIon 85.00 (84.70 to 85.70): L12
4.78
Ion 87.00 (86.70 to 87.70): L12
Ion 100.95 (100.65 to 101.65):
#12
Ethanol
Concen: 4.84 PPBV
RT: 7.85 min Scan# 462
Delta R.T. -0.03 min
Lab File: L1201442.D
Acq: 3 Jul 2012 1:46 pm
Tgt Ion: 45 Resp: 92538
Ion Ratio Lower Upper
45 100
43 26.5 31.3 46.9#
31 236.0 209.9 314.9
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 512 (8.184 min): L1103939.D (-)
31
7854 200106 220 247133 278 299153172
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 462 (7.851 min): L1201442.D
31
94 15874 18349 250 282208112 133
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 462 (7.851 min): L1201442.D (-)
31
77 108 250 28254127208147 168187
7.70 7.80 7.90 8.00
0
20000
40000
60000
80000
100000
Time-->
AbundanceIon 44.95 (44.65 to 45.65): L12
7.85
Ion 42.95 (42.65 to 43.65): L12Ion 30.95 (30.65 to 31.65): L12
L1201442.D L062912C.M Wed Jul 11 12:02:06 2012 Page 3
#16
Acetone
Concen: 10.98 PPBV
RT: 8.75 min Scan# 551
Delta R.T. -0.03 min
Lab File: L1201442.D
Acq: 3 Jul 2012 1:46 pm
Tgt Ion: 43 Resp: 1217781
Ion Ratio Lower Upper
43 100
58 23.4 12.2 18.4#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 572 (8.797 min): L1200822.D (-)
43
168128 2947622119397147254
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 551 (8.746 min): L1201442.D
43
277107 136 171 256 29919262214
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 551 (8.746 min): L1201442.D (-)
43
299151 171 19666 217 242 26496
8.60 8.70 8.80 8.90
0
100000
200000
300000
400000
Time-->
AbundanceIon 43.00 (42.70 to 43.70): L12
8.75
Ion 58.00 (57.70 to 58.70): L12
#17
Carbon disulfide
Concen: 0.27 PPBV
RT: 9.15 min Scan# 591
Delta R.T. -0.03 min
Lab File: L1201442.D
Acq: 3 Jul 2012 1:46 pm
Tgt Ion: 76 Resp: 41687
Ion Ratio Lower Upper
76 100
78 10.3 8.0 12.0
44 0.0 21.0 31.4#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 641 (9.481 min): L1103939.D (-)
76
45
196 239 26628621596 116 152171
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 591 (9.149 min): L1201442.D
76
32
94 20758115 138 277
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 591 (9.149 min): L1201442.D (-)
76
44
94 115 138 273208
9.00 9.10 9.20
0
5000
10000
15000
Time-->
AbundanceIon 76.00 (75.70 to 76.70): L12
9.15
Ion 78.00 (77.70 to 78.70): L12Ion 44.10 (43.80 to 44.80): L12
L1201442.D L062912C.M Wed Jul 11 12:02:07 2012 Page 4
#18
Isopropyl alcohol
Concen: 1.50 PPBV
RT: 9.09 min Scan# 585
Delta R.T. -0.04 min
Lab File: L1201442.D
Acq: 3 Jul 2012 1:46 pm
Tgt Ion: 45 Resp: 170372
Ion Ratio Lower Upper
45 100
43 18.4 21.4 32.2#
59 3.4 2.5 3.7
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 641 (9.481 min): L1103939.D (-)
45
77 266116286152171 19221197 243
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 585 (9.088 min): L1201442.D
45
76 20794 157 239 271289
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 585 (9.088 min): L1201442.D (-)
45
76 94 157 239 271207289
8.90 9.00 9.10 9.20 9.30
0
20000
40000
60000
Time-->
AbundanceIon 45.00 (44.70 to 45.70): L12
9.09
Ion 43.10 (42.80 to 43.80): L12
Ion 59.00 (58.70 to 59.70): L12
#20
Acetonitrile
Concen: 0.28 PPBV
RT: 9.35 min Scan# 611
Delta R.T. -0.04 min
Lab File: L1201442.D
Acq: 3 Jul 2012 1:46 pm
Tgt Ion: 41 Resp: 15629
Ion Ratio Lower Upper
41 100
40 58.5 51.7 77.5
39 22.4 25.2 37.8#
38 17.1 21.7 32.5#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 668 (9.752 min): L1103939.D (-)
41
97 17112869 195214 245 281147
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 611 (9.350 min): L1201442.D
32
58 20794152 235 287
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 611 (9.350 min): L1201442.D (-)
41
66 105 298152235207
9.20 9.30 9.40 9.50
0
2000
4000
6000
Time-->
AbundanceIon 40.95 (40.65 to 41.65): L12
9.35
Ion 40.00 (39.70 to 40.70): L12Ion 38.90 (38.60 to 39.60): L12Ion 37.90 (37.60 to 38.60): L12
L1201442.D L062912C.M Wed Jul 11 12:02:07 2012 Page 5
#21
Methylene chloride
Concen: 0.42 PPBV
RT: 9.77 min Scan# 653
Delta R.T. -0.04 min
Lab File: L1201442.D
Acq: 3 Jul 2012 1:46 pm
Tgt Ion: 49 Resp: 35662
Ion Ratio Lower Upper
49 100
84 62.6 66.8 100.2#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 675 (9.833 min): L1200822.D (-)
49 84
109 142 207 248 27822829
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 653 (9.772 min): L1201442.D
49
84
207119 14731 186 242 288
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 653 (9.772 min): L1201442.D (-)
49
84
115 147 214 242 288172190
9.70 9.80 9.90
0
5000
10000
Time-->
AbundanceIon 49.05 (48.75 to 49.75): L12
9.77
Ion 84.00 (83.70 to 84.70): L12
#29
Methyl ethyl ketone (2-Butanone)
Concen: 1.67 PPBV
RT: 12.55 min Scan# 929
Delta R.T. -0.03 min
Lab File: L1201442.D
Acq: 3 Jul 2012 1:46 pm
Tgt Ion: 72 Resp: 42108
Ion Ratio Lower Upper
72 100
43 593.5 420.9 631.3
57 33.9 32.6 48.8
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 984 (12.929 min): L1103939.D
43
72
96 123 143162 182201 226 254273
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 929 (12.548 min): L1201442.D
43
72
29791 112 194131 219 240 261
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 929 (12.548 min): L1201442.D (-)
43
72
223241 26191 286112131 194
12.40 12.50 12.60 12.70
0
50000
100000
Time-->
AbundanceIon 72.00 (71.70 to 72.70): L12
12.55
Ion 43.00 (42.70 to 43.70): L12Ion 57.00 (56.70 to 57.70): L12
L1201442.D L062912C.M Wed Jul 11 12:02:08 2012 Page 6
#30
Ethyl acetate
Concen: 1.51 PPBV
RT: 12.64 min Scan# 938
Delta R.T. -0.03 min
Lab File: L1201442.D
Acq: 3 Jul 2012 1:46 pm
Tgt Ion: 45 Resp: 33530
Ion Ratio Lower Upper
45 100
61 74.9 0.0 0.0#
88 27.2 27.6 41.4#
70 55.8 60.6 90.8#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 994 (13.030 min): L1103939.D (-)
43
70 88 202 238116 261 288139159
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 938 (12.639 min): L1201442.D
43
61 88 268 299106 130 151 190 225244
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 938 (12.639 min): L1201442.D (-)
43
61 88 299110 134 155 180 207225 247265
12.60 12.70
0
5000
10000
15000
Time-->
AbundanceIon 45.00 (44.70 to 45.70): L12
12.64
Ion 61.00 (60.70 to 61.70): L12
Ion 88.00 (87.70 to 88.70): L12
Ion 70.00 (69.70 to 70.70): L12
#31
Chloroform
Concen: 0.39 PPBV
RT: 13.23 min Scan# 997
Delta R.T. -0.03 min
Lab File: L1201442.D
Acq: 3 Jul 2012 1:46 pm
Tgt Ion: 83 Resp: 45826
Ion Ratio Lower Upper
83 100
85 65.9 52.3 78.5
Ref
Raw
Sub
40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1052 (13.613 min): L1103939.D (-)
83
47
120 200 224 252 275294141 161180102
40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 997 (13.232 min): L1201442.D
83
32
50 118 276 297254138156 202 226
40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 997 (13.232 min): L1201442.D (-)
83
276119 29757254138156 202 226
13.10 13.20 13.30
0
5000
10000
15000
Time-->
AbundanceIon 83.00 (82.70 to 83.70): L12
13.23
Ion 85.00 (84.70 to 85.70): L12
L1201442.D L062912C.M Wed Jul 11 12:02:08 2012 Page 7
#49
Toluene
Concen: 0.60 PPBV
RT: 17.40 min Scan# 1411
Delta R.T. -0.02 min
Lab File: L1201442.D
Acq: 3 Jul 2012 1:46 pm
Tgt Ion: 91 Resp: 108367
Ion Ratio Lower Upper
91 100
92 65.6 48.2 72.4
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1459 (17.705 min): L1103939.D (-)
91
39 65 135 162180 205 244 280110
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1411 (17.396 min): L1201442.D
91
43 65 112 200 239 267
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1411 (17.396 min): L1201442.D (-)
91
39 65 112 200 239 267
17.30 17.40 17.50
0
10000
20000
30000
40000
50000
Time-->
AbundanceIon 91.10 (90.80 to 91.80): L12
17.40
Ion 92.10 (91.80 to 92.80): L12
#52
Tetrachloroethene
Concen: 11.99 PPBV
RT: 18.09 min Scan# 1480
Delta R.T. -0.02 min
Lab File: L1201442.D
Acq: 3 Jul 2012 1:46 pm
Tgt Ion:166 Resp: 1116779
Ion Ratio Lower Upper
166 100
164 77.8 63.0 94.6
131 66.5 59.0 88.4
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1526 (18.379 min): L1103939.D (-)
166
131
94
47
18820765 232 252 275295
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1480 (18.090 min): L1201442.D
166
129
9447
68 207 232 281
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1480 (18.090 min): L1201442.D (-)
166
129
9447
207 228 24865
18.00 18.20
0
200000
400000
600000
800000
Time-->
AbundanceIon 165.90 (165.60 to 166.60):
18.09
Ion 163.90 (163.60 to 164.60): Ion 130.90 (130.60 to 131.60):
L1201442.D L062912C.M Wed Jul 11 12:02:09 2012 Page 8
#53
2-Hexanone (Methyl butyl ketone)
Concen: 0.53 PPBV
RT: 18.18 min Scan# 1489
Delta R.T. -0.02 min
Lab File: L1201442.D
Acq: 3 Jul 2012 1:46 pm
Tgt Ion: 43 Resp: 86179
Ion Ratio Lower Upper
43 100
58 46.8 33.7 50.5
57 15.9 15.2 22.8
100 9.8 10.4 15.6#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1535 (18.469 min): L1103939.D (-)
43
10071 176 212 235 255 282118 157137
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1489 (18.181 min): L1201442.D
43
10071 281207133164 251
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1489 (18.181 min): L1201442.D (-)
43
10071 281164133193 251
18.10 18.20
0
20000
40000
60000
Time-->
AbundanceIon 43.00 (42.70 to 43.70): L12
18.18
Ion 58.00 (57.70 to 58.70): L12
Ion 57.10 (56.80 to 57.80): L12
Ion 100.00 (99.70 to 100.70): L
#59
m-/p-Xylenes
Concen: 0.48 PPBV
RT: 19.30 min Scan# 1600
Delta R.T. -0.03 min
Lab File: L1201442.D
Acq: 3 Jul 2012 1:46 pm
Tgt Ion: 91 Resp: 83422
Ion Ratio Lower Upper
91 100
106 51.3 39.3 58.9
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1647 (19.595 min): L1103939.D (-)
91
39 65 109128 148 176 203 235 262281
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1600 (19.297 min): L1201442.D
43 91
70
128 207109187 230 281
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1600 (19.297 min): L1201442.D (-)
9143
70
128109 187207 230 298
19.20 19.30 19.40
0
10000
20000
30000
40000
Time-->
AbundanceIon 91.10 (90.80 to 91.80): L12
19.30
Ion 106.05 (105.75 to 106.75):
L1201442.D L062912C.M Wed Jul 11 12:02:09 2012 Page 9
#60
o-Xylene
Concen: 0.21 PPBV
RT: 19.68 min Scan# 1638
Delta R.T. -0.02 min
Lab File: L1201442.D
Acq: 3 Jul 2012 1:46 pm
Tgt Ion: 91 Resp: 37233
Ion Ratio Lower Upper
91 100
106 49.0 36.8 55.2
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1686 (19.988 min): L1103939.D (-)
91
39 65 245 276108127 147 166 186205 226
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1638 (19.679 min): L1201442.D
91
32 51
69 207111 140 177 232 260 283
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1638 (19.679 min): L1201442.D (-)
91
51
69 111 140 177 20434 232 283
19.60 19.65 19.70 19.75
0
5000
10000
15000
20000
25000
Time-->
AbundanceIon 91.10 (90.80 to 91.80): L12
19.68
Ion 106.10 (105.80 to 106.80):
#61
Styrene
Concen: 0.24 PPBV
RT: 19.70 min Scan# 1640
Delta R.T. -0.02 min
Lab File: L1201442.D
Acq: 3 Jul 2012 1:46 pm
Tgt Ion:104 Resp: 35816
Ion Ratio Lower Upper
104 100
78 47.8 46.2 69.2
103 51.3 44.0 66.0
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1688 (20.008 min): L1103939.D (-)
104
78
51
131 166 202221 241260 280
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1640 (19.699 min): L1201442.D
104
783251
207126144 172 232 281
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1640 (19.699 min): L1201442.D (-)
104
7851
32 126144 172 207 232 282
19.60 19.70 19.80
0
10000
20000
30000
Time-->
AbundanceIon 104.10 (103.80 to 104.80):
19.70
Ion 78.10 (77.80 to 78.80): L12Ion 103.10 (102.80 to 103.80):
L1201442.D L062912C.M Wed Jul 11 12:02:10 2012 Page 10
#67
1,2,4-Trimethylbenzene
Concen: 0.39 PPBV
RT: 20.83 min Scan# 1752
Delta R.T. -0.02 min
Lab File: L1201442.D
Acq: 3 Jul 2012 1:46 pm
Tgt Ion:105 Resp: 77144
Ion Ratio Lower Upper
105 100
120 32.6 37.8 56.6#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1803 (21.164 min): L1103939.D (-)
105
773958 299126 146165 189209 233252271
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1752 (20.826 min): L1201442.D
105
43 69
139 20787 260 281163 230
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1752 (20.826 min): L1201442.D (-)
105
7751 13933 207 230 281179
20.80 20.90
0
10000
20000
30000
40000
Time-->
AbundanceIon 105.10 (104.80 to 105.80):
20.83
Ion 120.15 (119.85 to 120.85):
#69
1,4-Dichlorobenzene
Concen: 0.51 PPBV m
RT: 21.18 min Scan# 1787
Delta R.T. -0.02 min
Lab File: L1201442.D
Acq: 3 Jul 2012 1:46 pm
Tgt Ion:146 Resp: 70646
Ion Ratio Lower Upper
146 100
148 65.4 51.8 77.8
111 61.9 27.9 41.9#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1840 (21.536 min): L1103939.D (-)
146
1117550
27931165 185 205 224 244
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1787 (21.178 min): L1201442.D
57
1132985 148 232 267209170 191
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1787 (21.178 min): L1201442.D (-)
57
1132985 146 168 192 228 267
21.15 21.20
0
20000
40000
60000
Time-->
AbundanceIon 146.00 (145.70 to 146.70):
21.18
Ion 148.00 (147.70 to 148.70): Ion 111.10 (110.80 to 111.80):
L1201442.D L062912C.M Wed Jul 11 12:02:10 2012 Page 11
Quantitation Report
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201443.D Vial: 3
Acq On : 3 Jul 2012 2:34 pm Operator: DB
Sample : TO15-Tyner St.-V-2-Can #00208 Inst : Lurch
Misc : 0612-142, 500mL load Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 11:34 2012 Quant Results File: L062912C.RES
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00
0
500000
1000000
1500000
2000000
2500000
3000000
3500000
4000000
4500000
5000000
5500000
6000000
6500000
7000000
7500000
8000000
8500000
9000000
9500000
1e+07
1.05e+07
1.1e+07
1.15e+07
1.2e+07
1.25e+07
1.3e+07
1.35e+07
1.4e+07
Time-->
Abundance TIC: L1201443.D
Naphthalene1,2,4-TrimethylbenzeneStyrenem-/p-XylenesChlorobenzene-d5 (IS),ITetrachloroetheneToluene1,4-Difluorobenzene (IS),I1,2-DichloroethaneChloroformBromochloromethane (IS),IEthyl acetateMethyl ethyl ketone (2-Butanone)Methylene chlorideAcetonitrileCarbon disulfideIsopropyl alcoholAcetoneEthanolFreon 12 (CCl2F2)L1201443.D L062912C.M Wed Jul 11 11:35:49 2012 Page 3
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201443.D Vial: 3
Acq On : 3 Jul 2012 2:34 pm Operator: DB
Sample : TO15-Tyner St.-V-2-Can #00208 Inst : Lurch
Misc : 0612-142, 500mL load Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 11:34 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) Bromochloromethane (IS) 13.06 130 541335 11.03 PPBV -0.02
36) 1,4-Difluorobenzene (IS) 14.86 114 2075679 10.52 PPBV -0.02
48) Chlorobenzene-d5 (IS) 19.06 117 1923477 11.20 PPBV -0.02
Target Compounds Qvalue
2) Propylene 0.00 41 0 N.D. d
3) Freon 12 (CCl2F2) 4.79 85 36096 0.21 PPBV 97
4) Freon 114 (C2Cl2F4) 0.00 85 0 N.D. d
5) Chloromethane 0.00 50 0 N.D. d
6) Chloroethene (Vinyl chlori 0.00 62 0 N.D.
7) 1,3-Butadiene 0.00 39 0 N.D.
8) Bromomethane 0.00 94 0 N.D.
9) Chloroethane 0.00 64 0 N.D. d
10) Bromoethene (Vinyl bromide 0.00 106 0 N.D.
11) Freon 11 (CCl3F) 0.00 101 0 N.D. d
12) Ethanol 7.85 45 75169 3.49 PPBV # 79
13) Acrolein 0.00 56 0 N.D. d
14) Freon 113 (C2Cl3F3) 0.00 151 0 N.D. d
15) 1,1-Dichloroethene 0.00 61 0 N.D.
16) Acetone 8.75 43 930497 7.45 PPBV # 80
17) Carbon disulfide 9.15 76 35939 0.21 PPBV # 62
18) Isopropyl alcohol 9.10 45 481812 3.76 PPBV # 85
19) Allyl chloride (3-chloropr 0.00 76 0 N.D.
20) Acetonitrile 9.36 41 26994 0.43 PPBV # 94
21) Methylene chloride 9.78 49 49088 0.51 PPBV # 77
22) trans-1,2-Dichloroethene 0.00 61 0 N.D.
23) Methyl tert-butyl ether 0.00 73 0 N.D. d
24) Acrylonitrile 0.00 53 0 N.D.
25) Hexane 0.00 57 0 N.D. d
26) 1,1-Dichloroethane 0.00 63 0 N.D.
27) Vinyl acetate 0.00 43 0 N.D. d
28) cis-1,2-Dichloroethylene 0.00 61 0 N.D. d
29) Methyl ethyl ketone (2-But 12.55 72 28154 0.99 PPBV 69
30) Ethyl acetate 12.65 45 12166 0.49 PPBV # 83
31) Chloroform 13.24 83 62682 0.48 PPBV 99
32) Tetrahydrofuran 0.00 72 0 N.D. d
33) 1,1,1-Trichloroethane 0.00 97 0 N.D. d
34) Cyclohexane 0.00 56 0 N.D. d
35) Carbon tetrachloride 0.00 117 0 N.D. d
37) Benzene 0.00 78 0 N.D. d
38) 2,2,4-trimethylpentane 0.00 57 0 N.D. d
39) 1,2-Dichloroethane 14.26 62 88531 1.01 PPBV 98
40) Heptane 0.00 57 0 N.D. d
41) Trichloroethene 0.00 130 0 N.D. d
42) 1,2-Dichloropropane 0.00 63 0 N.D.
43) Methyl methacrylate 0.00 69 0 N.D.
44) 1,4-Dioxane 0.00 88 0 N.D.
45) Bromodichloromethane 0.00 83 0 N.D. d
46) cis-1,3-Dichloropropene 0.00 75 0 N.D.
47) Methyl isobutyl ketone 0.00 43 0 N.D. d
49) Toluene 17.39 91 130349 0.67 PPBV 95
50) trans-1,3-Dichloropropene 0.00 75 0 N.D. d
51) 1,1,2-Trichloroethane 0.00 97 0 N.D. d
52) Tetrachloroethene 18.09 166 139817 1.40 PPBV 95
53) 2-Hexanone (Methyl butyl k 0.00 43 0 N.D. d
54) Dibromochloromethane 0.00 129 0 N.D. d
55) 1,2-Dibromoethane 0.00 107 0 N.D.
56) Chlorobenzene 0.00 112 0 N.D. d
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201443.D L062912C.M Wed Jul 11 11:35:48 2012 Page 1
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201443.D Vial: 3
Acq On : 3 Jul 2012 2:34 pm Operator: DB
Sample : TO15-Tyner St.-V-2-Can #00208 Inst : Lurch
Misc : 0612-142, 500mL load Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 11:34 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Compound R.T. QIon Response Conc Unit Qvalue
-------------------------------------------------------------------------
57) Ethylbenzene 0.00 91 0 N.D. d
58) 1,1,1,2-Tetrachloroethane 0.00 131 0 N.D.
59) m-/p-Xylenes 19.30 91 70247 0.37 PPBV 96
60) o-Xylene 0.00 91 0 N.D. d
61) Styrene 19.70 104 39662 0.25 PPBV 88
62) Bromoform 0.00 173 0 N.D.
63) 1,1,2,2-Tetrachloroethane 0.00 83 0 N.D. d
64) 4-Ethyltoluene 0.00 105 0 N.D. d
65) 2-Chlorotoluene 0.00 91 0 N.D. d
66) 1,3,5-Trimethylbenzene 0.00 105 0 N.D. d
67) 1,2,4-Trimethylbenzene 20.82 105 50394m 0.24 PPBV
68) 1,3-Dichlorobenzene 0.00 146 0 N.D. d
69) 1,4-Dichlorobenzene 0.00 146 0 N.D. d
70) Benzyl chloride 0.00 91 0 N.D. d
71) 1,2-Dichlorobenzene 0.00 146 0 N.D. d
72) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. d
73) Hexachlorobutadiene 0.00 225 0 N.D.
74) Naphthalene 23.13 128 119472 0.46 PPBV # 84
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201443.D L062912C.M Wed Jul 11 11:35:48 2012 Page 2
#3
Freon 12 (CCl2F2)
Concen: 0.21 PPBV
RT: 4.79 min Scan# 158
Delta R.T. -0.02 min
Lab File: L1201443.D
Acq: 3 Jul 2012 2:34 pm
Tgt Ion: 85 Resp: 36096
Ion Ratio Lower Upper
85 100
87 32.0 26.7 40.1
101 9.0 8.2 12.2
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 185 (4.896 min): L1103939.D (-)
85
50 10331 220 241125 274 298145163 184
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 158 (4.791 min): L1201443.D
32
85
50 103121 207 227 262 286139 160 187
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 158 (4.791 min): L1201443.D (-)
85
5030 103 293121 143 167 188 223 262
4.70 4.80 4.90
0
5000
10000
15000
Time-->
AbundanceIon 85.00 (84.70 to 85.70): L12
4.79
Ion 87.00 (86.70 to 87.70): L12
Ion 100.95 (100.65 to 101.65):
#12
Ethanol
Concen: 3.49 PPBV
RT: 7.85 min Scan# 462
Delta R.T. -0.03 min
Lab File: L1201443.D
Acq: 3 Jul 2012 2:34 pm
Tgt Ion: 45 Resp: 75169
Ion Ratio Lower Upper
45 100
43 24.4 31.3 46.9#
31 224.7 209.9 314.9
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 512 (8.184 min): L1103939.D (-)
31
7854 200106 220 247133 278 299153172
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 462 (7.848 min): L1201443.D
31
9455 174 209 25614673234 281115
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 462 (7.848 min): L1201443.D (-)
31
94 29162 122 146 174 267207 227
7.70 7.80 7.90 8.00
0
20000
40000
60000
80000
Time-->
AbundanceIon 44.95 (44.65 to 45.65): L12
7.85
Ion 42.95 (42.65 to 43.65): L12Ion 30.95 (30.65 to 31.65): L12
L1201443.D L062912C.M Wed Jul 11 11:36:02 2012 Page 3
#16
Acetone
Concen: 7.45 PPBV
RT: 8.75 min Scan# 552
Delta R.T. -0.02 min
Lab File: L1201443.D
Acq: 3 Jul 2012 2:34 pm
Tgt Ion: 43 Resp: 930497
Ion Ratio Lower Upper
43 100
58 23.7 12.2 18.4#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 572 (8.797 min): L1200822.D (-)
43
168128 2947622119397147 254
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 552 (8.753 min): L1201443.D
43
26097 28111920814062161 186
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 552 (8.753 min): L1201443.D (-)
43
263101 28412214062164 186 20883
8.60 8.80 9.00
0
100000
200000
300000
Time-->
AbundanceIon 43.00 (42.70 to 43.70): L12
8.75
Ion 58.00 (57.70 to 58.70): L12
#17
Carbon disulfide
Concen: 0.21 PPBV
RT: 9.15 min Scan# 591
Delta R.T. -0.03 min
Lab File: L1201443.D
Acq: 3 Jul 2012 2:34 pm
Tgt Ion: 76 Resp: 35939
Ion Ratio Lower Upper
76 100
78 9.4 8.0 12.0
44 0.0 21.0 31.4#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 641 (9.481 min): L1103939.D (-)
76
45
196 239 26628621596 116 152171
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 591 (9.146 min): L1201443.D
76
32
173 20858106 130148 237255
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 591 (9.146 min): L1201443.D (-)
76
45
173 205110 134 233251
9.00 9.10 9.20 9.30
0
5000
10000
15000
Time-->
AbundanceIon 76.00 (75.70 to 76.70): L12
9.15
Ion 78.00 (77.70 to 78.70): L12Ion 44.10 (43.80 to 44.80): L12
L1201443.D L062912C.M Wed Jul 11 11:36:02 2012 Page 4
#18
Isopropyl alcohol
Concen: 3.76 PPBV
RT: 9.10 min Scan# 586
Delta R.T. -0.03 min
Lab File: L1201443.D
Acq: 3 Jul 2012 2:34 pm
Tgt Ion: 45 Resp: 481812
Ion Ratio Lower Upper
45 100
43 18.0 21.4 32.2#
59 3.4 2.5 3.7
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 641 (9.481 min): L1103939.D (-)
45
77 266116286152171 19221197 243
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 586 (9.095 min): L1201443.D
45
83 134154 174 20765
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 586 (9.095 min): L1201443.D (-)
45
87 122 146 170 21666
8.90 9.00 9.10 9.20 9.30
0
50000
100000
150000
200000
Time-->
AbundanceIon 45.00 (44.70 to 45.70): L12
9.10
Ion 43.10 (42.80 to 43.80): L12
Ion 59.00 (58.70 to 59.70): L12
#20
Acetonitrile
Concen: 0.43 PPBV
RT: 9.36 min Scan# 612
Delta R.T. -0.03 min
Lab File: L1201443.D
Acq: 3 Jul 2012 2:34 pm
Tgt Ion: 41 Resp: 26994
Ion Ratio Lower Upper
41 100
40 65.1 51.7 77.5
39 26.9 25.2 37.8
38 17.6 21.7 32.5#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 668 (9.752 min): L1103939.D (-)
41
97 17112869 195214 245 281147
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 612 (9.357 min): L1201443.D
41
20771175109 133 251 275 298154
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 612 (9.357 min): L1201443.D (-)
41
71 175 211109 275 298154254133
9.30 9.40 9.50
0
5000
10000
Time-->
AbundanceIon 40.95 (40.65 to 41.65): L12
9.36
Ion 40.00 (39.70 to 40.70): L12Ion 38.90 (38.60 to 39.60): L12Ion 37.90 (37.60 to 38.60): L12
L1201443.D L062912C.M Wed Jul 11 11:36:03 2012 Page 5
#21
Methylene chloride
Concen: 0.51 PPBV
RT: 9.78 min Scan# 654
Delta R.T. -0.03 min
Lab File: L1201443.D
Acq: 3 Jul 2012 2:34 pm
Tgt Ion: 49 Resp: 49088
Ion Ratio Lower Upper
49 100
84 62.9 66.8 100.2#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 675 (9.833 min): L1200822.D (-)
49 84
109 142 207 248 27822429
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 654 (9.779 min): L1201443.D
49
84
32
174 202 241 268103121 153
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 654 (9.779 min): L1201443.D (-)
49
84
29 209 241 268107124142 170
9.60 9.70 9.80 9.90
0
5000
10000
15000
Time-->
AbundanceIon 49.05 (48.75 to 49.75): L12
9.78
Ion 84.00 (83.70 to 84.70): L12
#29
Methyl ethyl ketone (2-Butanone)
Concen: 0.99 PPBV
RT: 12.55 min Scan# 929
Delta R.T. -0.03 min
Lab File: L1201443.D
Acq: 3 Jul 2012 2:34 pm
Tgt Ion: 72 Resp: 28154
Ion Ratio Lower Upper
72 100
43 619.3 420.9 631.3
57 36.5 32.6 48.8
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 984 (12.929 min): L1103939.D
43
72
96 123 143 162 182 201 226 254 273
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 929 (12.545 min): L1201443.D
43
72
96 150 182 207225 250268
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 929 (12.545 min): L1201443.D (-)
43
72
179 214 236254158 275100
12.50 12.60
0
20000
40000
60000
80000
Time-->
AbundanceIon 72.00 (71.70 to 72.70): L12
12.55
Ion 43.00 (42.70 to 43.70): L12Ion 57.00 (56.70 to 57.70): L12
L1201443.D L062912C.M Wed Jul 11 11:36:03 2012 Page 6
#30
Ethyl acetate
Concen: 0.49 PPBV
RT: 12.65 min Scan# 939
Delta R.T. -0.02 min
Lab File: L1201443.D
Acq: 3 Jul 2012 2:34 pm
Tgt Ion: 45 Resp: 12166
Ion Ratio Lower Upper
45 100
61 70.4 0.0 0.0#
88 29.5 27.6 41.4
70 57.9 60.6 90.8#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 994 (13.030 min): L1103939.D (-)
43
70 88 202 238116 261 288139159
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 939 (12.646 min): L1201443.D
43
61 88 106 131 173 201152 281
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 939 (12.646 min): L1201443.D (-)
43
61 88 131 173 198106152
12.60 12.70
0
2000
4000
6000
Time-->
AbundanceIon 45.00 (44.70 to 45.70): L12
12.65
Ion 61.00 (60.70 to 61.70): L12
Ion 88.00 (87.70 to 88.70): L12
Ion 70.00 (69.70 to 70.70): L12
#31
Chloroform
Concen: 0.48 PPBV
RT: 13.24 min Scan# 998
Delta R.T. -0.02 min
Lab File: L1201443.D
Acq: 3 Jul 2012 2:34 pm
Tgt Ion: 83 Resp: 62682
Ion Ratio Lower Upper
83 100
85 66.3 52.3 78.5
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1052 (13.613 min): L1103939.D (-)
83
47
120 200 224 252 275294141 161180102
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 998 (13.239 min): L1201443.D
83
32
50 117 144 207 292234
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 998 (13.239 min): L1201443.D (-)
83
11757 29215539234
13.10 13.20 13.30
0
5000
10000
15000
20000
25000
Time-->
AbundanceIon 83.00 (82.70 to 83.70): L12
13.24
Ion 85.00 (84.70 to 85.70): L12
L1201443.D L062912C.M Wed Jul 11 11:36:03 2012 Page 7
#39
1,2-Dichloroethane
Concen: 1.01 PPBV
RT: 14.26 min Scan# 1100
Delta R.T. -0.02 min
Lab File: L1201443.D
Acq: 3 Jul 2012 2:34 pm
Tgt Ion: 62 Resp: 88531
Ion Ratio Lower Upper
62 100
64 33.1 25.5 38.3
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1151 (14.609 min): L1103939.D (-)
62
9835 230 261 28920681 115 139 162
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1100 (14.265 min): L1201443.D
62
32 98 130 207 232
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1100 (14.265 min): L1201443.D (-)
62
9835 130 232
14.20 14.30
0
10000
20000
30000
40000
Time-->
AbundanceIon 62.10 (61.80 to 62.80): L12
14.26
Ion 64.10 (63.80 to 64.80): L12
#49
Toluene
Concen: 0.67 PPBV
RT: 17.39 min Scan# 1411
Delta R.T. -0.02 min
Lab File: L1201443.D
Acq: 3 Jul 2012 2:34 pm
Tgt Ion: 91 Resp: 130349
Ion Ratio Lower Upper
91 100
92 63.9 48.2 72.4
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1459 (17.705 min): L1103939.D (-)
91
39 65 135 162180 205 244 280110
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1411 (17.393 min): L1201443.D
91
39 65 112 136 207 234 273 294
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1411 (17.393 min): L1201443.D (-)
91
39 65 112 237 273 294132207
17.30 17.40 17.50
0
20000
40000
60000
Time-->
AbundanceIon 91.10 (90.80 to 91.80): L12
17.39
Ion 92.10 (91.80 to 92.80): L12
L1201443.D L062912C.M Wed Jul 11 11:36:04 2012 Page 8
#52
Tetrachloroethene
Concen: 1.40 PPBV
RT: 18.09 min Scan# 1480
Delta R.T. -0.02 min
Lab File: L1201443.D
Acq: 3 Jul 2012 2:34 pm
Tgt Ion:166 Resp: 139817
Ion Ratio Lower Upper
166 100
164 78.0 63.0 94.6
131 66.4 59.0 88.4
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1526 (18.379 min): L1103939.D (-)
166131
94
47
18820765 232 252 275295
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1480 (18.087 min): L1201443.D
166
129
9447
72 193 260 281299
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1480 (18.087 min): L1201443.D (-)
166
129
9447
65 207 260 282
18.00 18.10 18.20
0
20000
40000
60000
80000
Time-->
AbundanceIon 165.90 (165.60 to 166.60):
18.09
Ion 163.90 (163.60 to 164.60):
Ion 130.90 (130.60 to 131.60):
#59
m-/p-Xylenes
Concen: 0.37 PPBV
RT: 19.30 min Scan# 1601
Delta R.T. -0.02 min
Lab File: L1201443.D
Acq: 3 Jul 2012 2:34 pm
Tgt Ion: 91 Resp: 70247
Ion Ratio Lower Upper
91 100
106 52.1 39.3 58.9
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1647 (19.595 min): L1103939.D (-)
91
39 65 109 128145 176 203 235 262281
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1601 (19.304 min): L1201443.D
43 91
70
128 207111 232 260278
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1601 (19.304 min): L1201443.D (-)
9143
70
128108 193 232 260278
19.20 19.30 19.40
0
10000
20000
30000
40000
Time-->
AbundanceIon 91.10 (90.80 to 91.80): L12
19.30
Ion 106.05 (105.75 to 106.75):
L1201443.D L062912C.M Wed Jul 11 11:36:04 2012 Page 9
#61
Styrene
Concen: 0.25 PPBV
RT: 19.70 min Scan# 1640
Delta R.T. -0.02 min
Lab File: L1201443.D
Acq: 3 Jul 2012 2:34 pm
Tgt Ion:104 Resp: 39662
Ion Ratio Lower Upper
104 100
78 46.4 46.2 69.2
103 48.4 44.0 66.0
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1688 (20.008 min): L1103939.D (-)
104
78
51
131 166 202221 241260 280
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1640 (19.696 min): L1201443.D
104
785132
207126147 179 232 253 277
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1640 (19.696 min): L1201443.D (-)
104
7851
29 126 207147 179 253 277
19.60 19.70 19.80
0
10000
20000
30000
Time-->
AbundanceIon 104.10 (103.80 to 104.80):
19.70
Ion 78.10 (77.80 to 78.80): L12
Ion 103.10 (102.80 to 103.80):
#67
1,2,4-Trimethylbenzene
Concen: 0.24 PPBV m
RT: 20.82 min Scan# 1752
Delta R.T. -0.02 min
Lab File: L1201443.D
Acq: 3 Jul 2012 2:34 pm
Tgt Ion:105 Resp: 50394
Ion Ratio Lower Upper
105 100
120 39.6 37.8 56.6
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1803 (21.164 min): L1103939.D (-)
105
773958 299126 146165 189209 233252271
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1752 (20.823 min): L1201443.D
105
41 69
139 207 267163 232 298
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1752 (20.823 min): L1201443.D (-)
105
7751 139 26722333 298163 191
20.80 20.85
0
10000
20000
30000
Time-->
AbundanceIon 105.10 (104.80 to 105.80):
20.82
Ion 120.15 (119.85 to 120.85):
L1201443.D L062912C.M Wed Jul 11 11:36:05 2012 Page 10
#74
Naphthalene
Concen: 0.46 PPBV
RT: 23.13 min Scan# 1981
Delta R.T. -0.02 min
Lab File: L1201443.D
Acq: 3 Jul 2012 2:34 pm
Tgt Ion:128 Resp: 119472
Ion Ratio Lower Upper
128 100
127 16.6 13.4 20.0
129 11.8 20.0 30.0#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 2050 (23.647 min): L1103939.D (-)
128
1025175 225178 249 27629520514731
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1981 (23.126 min): L1201443.D
128
43
71 102 207175147 260 281232
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1981 (23.126 min): L1201443.D (-)
128
51 10274 175146 193212232 261 28331
23.10 23.20
0
20000
40000
60000
80000
Time-->
AbundanceIon 127.95 (127.65 to 128.65):
23.13
Ion 126.95 (126.65 to 127.65):
Ion 128.95 (128.65 to 129.65):
L1201443.D L062912C.M Wed Jul 11 11:36:05 2012 Page 11
Quantitation Report
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201444.D Vial: 4
Acq On : 3 Jul 2012 3:23 pm Operator: DB
Sample : TO15-Tyner St.-V-3-Can #00147 Inst : Lurch
Misc : 0612-142, 500mL load Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 11:39 2012 Quant Results File: L062912C.RES
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00
0
500000
1000000
1500000
2000000
2500000
3000000
3500000
4000000
4500000
5000000
5500000
6000000
6500000
7000000
7500000
8000000
8500000
9000000
9500000
1e+07
1.05e+07
1.1e+07
1.15e+07
1.2e+07
1.25e+07
1.3e+07
Time-->
Abundance TIC: L1201444.D
1,2,4-Trimethylbenzenem-/p-XylenesChlorobenzene-d5 (IS),I2-Hexanone (Methyl butyl ketone)TetrachloroetheneTolueneMethyl isobutyl ketoneTrichloroethene1,4-Difluorobenzene (IS),IChloroformBromochloromethane (IS),IEthyl acetateMethyl ethyl ketone (2-Butanone)HexaneMethylene chlorideAcetonitrileIsopropyl alcoholAcetoneAcroleinEthanolL1201444.D L062912C.M Wed Jul 11 11:39:57 2012 Page 3
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201444.D Vial: 4
Acq On : 3 Jul 2012 3:23 pm Operator: DB
Sample : TO15-Tyner St.-V-3-Can #00147 Inst : Lurch
Misc : 0612-142, 500mL load Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 11:39 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) Bromochloromethane (IS) 13.06 130 556584 11.03 PPBV -0.02
36) 1,4-Difluorobenzene (IS) 14.86 114 2147362 10.52 PPBV -0.02
48) Chlorobenzene-d5 (IS) 19.06 117 1967738 11.20 PPBV -0.02
Target Compounds Qvalue
2) Propylene 0.00 41 0 N.D. d
3) Freon 12 (CCl2F2) 0.00 85 0 N.D. d
4) Freon 114 (C2Cl2F4) 0.00 85 0 N.D. d
5) Chloromethane 0.00 50 0 N.D. d
6) Chloroethene (Vinyl chlori 0.00 62 0 N.D.
7) 1,3-Butadiene 0.00 39 0 N.D. d
8) Bromomethane 0.00 94 0 N.D.
9) Chloroethane 0.00 64 0 N.D. d
10) Bromoethene (Vinyl bromide 0.00 106 0 N.D.
11) Freon 11 (CCl3F) 0.00 101 0 N.D. d
12) Ethanol 7.86 45 50262 2.27 PPBV # 83
13) Acrolein 8.42 56 14824 0.62 PPBV # 12
14) Freon 113 (C2Cl3F3) 0.00 151 0 N.D. d
15) 1,1-Dichloroethene 0.00 61 0 N.D.
16) Acetone 8.75 43 1984829 15.45 PPBV # 83
17) Carbon disulfide 0.00 76 0 N.D. d
18) Isopropyl alcohol 9.10 45 206264 1.56 PPBV # 87
19) Allyl chloride (3-chloropr 0.00 76 0 N.D.
20) Acetonitrile 9.37 41 18868 0.29 PPBV # 91
21) Methylene chloride 9.79 49 42007 0.43 PPBV # 79
22) trans-1,2-Dichloroethene 0.00 61 0 N.D.
23) Methyl tert-butyl ether 0.00 73 0 N.D. d
24) Acrylonitrile 0.00 53 0 N.D.
25) Hexane 11.03 57 19218 0.21 PPBV # 67
26) 1,1-Dichloroethane 0.00 63 0 N.D. d
27) Vinyl acetate 0.00 43 0 N.D. d
28) cis-1,2-Dichloroethylene 0.00 61 0 N.D. d
29) Methyl ethyl ketone (2-But 12.56 72 41752 1.43 PPBV 74
30) Ethyl acetate 12.64 45 41462 1.61 PPBV # 81
31) Chloroform 13.24 83 234569 1.74 PPBV 100
32) Tetrahydrofuran 0.00 72 0 N.D. d
33) 1,1,1-Trichloroethane 0.00 97 0 N.D. d
34) Cyclohexane 0.00 56 0 N.D. d
35) Carbon tetrachloride 0.00 117 0 N.D. d
37) Benzene 0.00 78 0 N.D. d
38) 2,2,4-trimethylpentane 0.00 57 0 N.D. d
39) 1,2-Dichloroethane 0.00 62 0 N.D. d
40) Heptane 0.00 57 0 N.D. d
41) Trichloroethene 15.24 130 4127162 44.99 PPBV # 88
42) 1,2-Dichloropropane 0.00 63 0 N.D.
43) Methyl methacrylate 0.00 69 0 N.D. d
44) 1,4-Dioxane 0.00 88 0 N.D. d
45) Bromodichloromethane 0.00 83 0 N.D. d
46) cis-1,3-Dichloropropene 0.00 75 0 N.D.
47) Methyl isobutyl ketone 17.02 43 57566 0.29 PPBV # 95
49) Toluene 17.39 91 151572 0.76 PPBV 95
50) trans-1,3-Dichloropropene 0.00 75 0 N.D.
51) 1,1,2-Trichloroethane 0.00 97 0 N.D. d
52) Tetrachloroethene 18.09 166 403359 3.94 PPBV 96
53) 2-Hexanone (Methyl butyl k 18.18 43 38547m 0.22 PPBV
54) Dibromochloromethane 0.00 129 0 N.D. d
55) 1,2-Dibromoethane 0.00 107 0 N.D.
56) Chlorobenzene 0.00 112 0 N.D. d
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201444.D L062912C.M Wed Jul 11 11:39:56 2012 Page 1
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201444.D Vial: 4
Acq On : 3 Jul 2012 3:23 pm Operator: DB
Sample : TO15-Tyner St.-V-3-Can #00147 Inst : Lurch
Misc : 0612-142, 500mL load Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 11:39 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Compound R.T. QIon Response Conc Unit Qvalue
-------------------------------------------------------------------------
57) Ethylbenzene 0.00 91 0 N.D. d
58) 1,1,1,2-Tetrachloroethane 0.00 131 0 N.D.
59) m-/p-Xylenes 19.30 91 64443 0.33 PPBV 96
60) o-Xylene 0.00 91 0 N.D. d
61) Styrene 0.00 104 0 N.D. d
62) Bromoform 0.00 173 0 N.D.
63) 1,1,2,2-Tetrachloroethane 0.00 83 0 N.D. d
64) 4-Ethyltoluene 0.00 105 0 N.D. d
65) 2-Chlorotoluene 0.00 91 0 N.D. d
66) 1,3,5-Trimethylbenzene 0.00 105 0 N.D. d
67) 1,2,4-Trimethylbenzene 20.83 105 61625m 0.29 PPBV
68) 1,3-Dichlorobenzene 0.00 146 0 N.D. d
69) 1,4-Dichlorobenzene 0.00 146 0 N.D. d
70) Benzyl chloride 0.00 91 0 N.D. d
71) 1,2-Dichlorobenzene 0.00 146 0 N.D.
72) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. d
73) Hexachlorobutadiene 0.00 225 0 N.D.
74) Naphthalene 0.00 128 0 N.D. d
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201444.D L062912C.M Wed Jul 11 11:39:56 2012 Page 2
#12
Ethanol
Concen: 2.27 PPBV
RT: 7.86 min Scan# 463
Delta R.T. -0.02 min
Lab File: L1201444.D
Acq: 3 Jul 2012 3:23 pm
Tgt Ion: 45 Resp: 50262
Ion Ratio Lower Upper
45 100
43 25.1 31.3 46.9#
31 234.2 209.9 314.9
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 512 (8.184 min): L1103939.D (-)
31
7854 200106 220 247133 278 299153172
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 463 (7.859 min): L1201444.D
31
2077956 97 171189 234 262281129 153
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 463 (7.859 min): L1201444.D (-)
31
78 196 298157270129 17510858 218 238
7.80 7.90 8.00
0
10000
20000
30000
40000
50000
Time-->
AbundanceIon 44.95 (44.65 to 45.65): L12
7.86
Ion 42.95 (42.65 to 43.65): L12
Ion 30.95 (30.65 to 31.65): L12
#13
Acrolein
Concen: 0.62 PPBV
RT: 8.42 min Scan# 519
Delta R.T. -0.03 min
Lab File: L1201444.D
Acq: 3 Jul 2012 3:23 pm
Tgt Ion: 56 Resp: 14824
Ion Ratio Lower Upper
56 100
55 0.0 60.4 90.6#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 569 (8.757 min): L1103939.D (-)
56
37
19076 95 115 155 249218 280135
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 519 (8.422 min): L1201444.D
44
9670 117 207141 173 249 269
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 519 (8.422 min): L1201444.D (-)
56
37 96 120 26974145173 207 249
8.30 8.40 8.50
0
1000
2000
3000
4000
5000
Time-->
AbundanceIon 55.95 (55.65 to 56.65): L12
8.42
Ion 54.90 (54.60 to 55.60): L12
L1201444.D L062912C.M Wed Jul 11 11:40:17 2012 Page 3
#16
Acetone
Concen: 15.45 PPBV
RT: 8.75 min Scan# 552
Delta R.T. -0.02 min
Lab File: L1201444.D
Acq: 3 Jul 2012 3:23 pm
Tgt Ion: 43 Resp: 1984829
Ion Ratio Lower Upper
43 100
58 22.6 12.2 18.4#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 572 (8.797 min): L1200822.D (-)
43
168128 2947622119397147254
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 552 (8.754 min): L1201444.D
43
71 89 151 207 241 269 293
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 552 (8.754 min): L1201444.D (-)
43
71 94 151 237 269 293
8.60 8.80 9.00
0
200000
400000
600000
Time-->
AbundanceIon 43.00 (42.70 to 43.70): L12
8.75
Ion 58.00 (57.70 to 58.70): L12
#18
Isopropyl alcohol
Concen: 1.56 PPBV
RT: 9.10 min Scan# 586
Delta R.T. -0.03 min
Lab File: L1201444.D
Acq: 3 Jul 2012 3:23 pm
Tgt Ion: 45 Resp: 206264
Ion Ratio Lower Upper
45 100
43 19.1 21.4 32.2#
59 3.3 2.5 3.7
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 641 (9.481 min): L1103939.D (-)
45
77 266116286152171 19221197 243
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 586 (9.096 min): L1201444.D
45
94 113 156 19166
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 586 (9.096 min): L1201444.D (-)
45
160 19173 94 113 139
8.90 9.00 9.10 9.20
0
20000
40000
60000
80000
Time-->
AbundanceIon 45.00 (44.70 to 45.70): L12
9.10
Ion 43.10 (42.80 to 43.80): L12Ion 59.00 (58.70 to 59.70): L12
L1201444.D L062912C.M Wed Jul 11 11:40:17 2012 Page 4
#20
Acetonitrile
Concen: 0.29 PPBV
RT: 9.37 min Scan# 613
Delta R.T. -0.02 min
Lab File: L1201444.D
Acq: 3 Jul 2012 3:23 pm
Tgt Ion: 41 Resp: 18868
Ion Ratio Lower Upper
41 100
40 68.1 51.7 77.5
39 27.8 25.2 37.8
38 15.6 21.7 32.5#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 668 (9.752 min): L1103939.D (-)
41
97 17112869 195214 245 281147
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 613 (9.367 min): L1201444.D
44
207 23578 27896164116
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 613 (9.367 min): L1201444.D (-)
41
207 235 27878 96 116 157
9.30 9.40
0
2000
4000
6000
8000
10000
Time-->
AbundanceIon 40.95 (40.65 to 41.65): L12
9.37
Ion 40.00 (39.70 to 40.70): L12
Ion 38.90 (38.60 to 39.60): L12
Ion 37.90 (37.60 to 38.60): L12
#21
Methylene chloride
Concen: 0.43 PPBV
RT: 9.79 min Scan# 655
Delta R.T. -0.02 min
Lab File: L1201444.D
Acq: 3 Jul 2012 3:23 pm
Tgt Ion: 49 Resp: 42007
Ion Ratio Lower Upper
49 100
84 64.5 66.8 100.2#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 675 (9.833 min): L1200822.D (-)
49 84
109 142 207 248 27822829
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 655 (9.790 min): L1201444.D
43
84
170188207 240 262 283103 13161
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 655 (9.790 min): L1201444.D (-)
42
84
209 248 269 290103 13161 152 173
9.70 9.80 9.90
0
5000
10000
15000
Time-->
AbundanceIon 49.05 (48.75 to 49.75): L12
9.79
Ion 84.00 (83.70 to 84.70): L12
L1201444.D L062912C.M Wed Jul 11 11:40:17 2012 Page 5
#25
Hexane
Concen: 0.21 PPBV
RT: 11.03 min Scan# 778
Delta R.T. -0.03 min
Lab File: L1201444.D
Acq: 3 Jul 2012 3:23 pm
Tgt Ion: 57 Resp: 19218
Ion Ratio Lower Upper
57 100
41 91.4 95.8 143.8#
43 101.5 52.1 78.1#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 833 (11.411 min): L1103939.D (-)
41
86
65 173 196 216 248267 287110 153129
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 778 (11.027 min): L1201444.D
32
57
86 207107226 246 282136 186 300
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 778 (11.027 min): L1201444.D (-)
57
29
86
226 254140 186 275293104207
10.90 11.00 11.10
0
2000
4000
6000
8000
Time-->
AbundanceIon 57.10 (56.80 to 57.80): L12
11.03
Ion 41.10 (40.80 to 41.80): L12
Ion 43.10 (42.80 to 43.80): L12
#29
Methyl ethyl ketone (2-Butanone)
Concen: 1.43 PPBV
RT: 12.56 min Scan# 930
Delta R.T. -0.02 min
Lab File: L1201444.D
Acq: 3 Jul 2012 3:23 pm
Tgt Ion: 72 Resp: 41752
Ion Ratio Lower Upper
72 100
43 603.3 420.9 631.3
57 37.1 32.6 48.8
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 984 (12.929 min): L1103939.D
43
72
96 123 143162 182201 226 254273
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 930 (12.556 min): L1201444.D
43
72
94 140 162 207 285
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 930 (12.556 min): L1201444.D (-)
43
72
28994 140159 194
12.40 12.50 12.60 12.70
0
50000
100000
150000
Time-->
AbundanceIon 72.00 (71.70 to 72.70): L12
12.56
Ion 43.00 (42.70 to 43.70): L12Ion 57.00 (56.70 to 57.70): L12
L1201444.D L062912C.M Wed Jul 11 11:40:18 2012 Page 6
#30
Ethyl acetate
Concen: 1.61 PPBV
RT: 12.64 min Scan# 938
Delta R.T. -0.03 min
Lab File: L1201444.D
Acq: 3 Jul 2012 3:23 pm
Tgt Ion: 45 Resp: 41462
Ion Ratio Lower Upper
45 100
61 81.2 0.0 0.0#
88 27.0 27.6 41.4#
70 56.5 60.6 90.8#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 994 (13.030 min): L1103939.D (-)
43
70 88 202 238116 261 288139159
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 938 (12.636 min): L1201444.D
43
61 88 141 207 279298
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 938 (12.636 min): L1201444.D (-)
43
61 88 279141298
12.60 12.70
0
5000
10000
15000
20000
Time-->
AbundanceIon 45.00 (44.70 to 45.70): L12
12.64
Ion 61.00 (60.70 to 61.70): L12
Ion 88.00 (87.70 to 88.70): L12
Ion 70.00 (69.70 to 70.70): L12
#31
Chloroform
Concen: 1.74 PPBV
RT: 13.24 min Scan# 998
Delta R.T. -0.02 min
Lab File: L1201444.D
Acq: 3 Jul 2012 3:23 pm
Tgt Ion: 83 Resp: 234569
Ion Ratio Lower Upper
83 100
85 65.6 52.3 78.5
Ref
Raw
Sub
40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1052 (13.613 min): L1103939.D (-)
83
47
120 200 224 252 275294141 161180102
40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 998 (13.240 min): L1201444.D
83
47
118 198 22665152170
40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 998 (13.240 min): L1201444.D (-)
83
11932 201 22661152 177
13.20 13.40
0
20000
40000
60000
80000
100000
Time-->
AbundanceIon 83.00 (82.70 to 83.70): L12
13.24
Ion 85.00 (84.70 to 85.70): L12
L1201444.D L062912C.M Wed Jul 11 11:40:18 2012 Page 7
#41
Trichloroethene
Concen: 44.99 PPBV
RT: 15.24 min Scan# 1197
Delta R.T. -0.02 min
Lab File: L1201444.D
Acq: 3 Jul 2012 3:23 pm
Tgt Ion:130 Resp: 4127162
Ion Ratio Lower Upper
130 100
132 97.6 79.5 119.3
95 98.2 61.1 91.7#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1247 (15.574 min): L1103939.D (-)
13095
60
35
151171 198 218 246264 284
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1197 (15.241 min): L1201444.D
13095
60
35
172 197 228 271 299
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1197 (15.241 min): L1201444.D (-)
13095
60
35
168 193 228 271 299
15.20 15.40
0
500000
1000000
1500000
2000000
Time-->
AbundanceIon 130.00 (129.70 to 130.70):
15.24
Ion 132.00 (131.70 to 132.70):
Ion 95.00 (94.70 to 95.70): L12
#47
Methyl isobutyl ketone
Concen: 0.29 PPBV
RT: 17.02 min Scan# 1374
Delta R.T. -0.03 min
Lab File: L1201444.D
Acq: 3 Jul 2012 3:23 pm
Tgt Ion: 43 Resp: 57566
Ion Ratio Lower Upper
43 100
58 34.5 26.3 39.5
85 14.2 14.8 22.2#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1427 (17.384 min): L1103939.D (-)
43
85
67 108 135 155 191 223242 262281
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1374 (17.021 min): L1201444.D
43
8567 188207 296267
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1374 (17.021 min): L1201444.D (-)
43
100
81 26763 296184
16.90 17.00 17.10
0
10000
20000
30000
Time-->
AbundanceIon 43.00 (42.70 to 43.70): L12
17.02
Ion 58.00 (57.70 to 58.70): L12Ion 85.00 (84.70 to 85.70): L12
L1201444.D L062912C.M Wed Jul 11 11:40:19 2012 Page 8
#49
Toluene
Concen: 0.76 PPBV
RT: 17.39 min Scan# 1411
Delta R.T. -0.02 min
Lab File: L1201444.D
Acq: 3 Jul 2012 3:23 pm
Tgt Ion: 91 Resp: 151572
Ion Ratio Lower Upper
91 100
92 63.9 48.2 72.4
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1459 (17.705 min): L1103939.D (-)
91
39 65 135 162180 205 244 280110
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1411 (17.394 min): L1201444.D
91
39 65 112 147 170 237 269 297207
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1411 (17.394 min): L1201444.D (-)
91
39 65 112 237 269 297178
17.30 17.40 17.50
0
20000
40000
60000
80000
Time-->
AbundanceIon 91.10 (90.80 to 91.80): L12
17.39
Ion 92.10 (91.80 to 92.80): L12
#52
Tetrachloroethene
Concen: 3.94 PPBV
RT: 18.09 min Scan# 1480
Delta R.T. -0.02 min
Lab File: L1201444.D
Acq: 3 Jul 2012 3:23 pm
Tgt Ion:166 Resp: 403359
Ion Ratio Lower Upper
166 100
164 79.1 63.0 94.6
131 67.7 59.0 88.4
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1526 (18.379 min): L1103939.D (-)
166
131
94
47
18820765 232 252 275295
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1480 (18.088 min): L1201444.D
166
129
9447
70 207226 246 282
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1480 (18.088 min): L1201444.D (-)
166
129
9447
74 218 246 279296191
18.00 18.10 18.20
0
50000
100000
150000
200000
250000
Time-->
AbundanceIon 165.90 (165.60 to 166.60):
18.09
Ion 163.90 (163.60 to 164.60): Ion 130.90 (130.60 to 131.60):
L1201444.D L062912C.M Wed Jul 11 11:40:19 2012 Page 9
#53
2-Hexanone (Methyl butyl ketone)
Concen: 0.22 PPBV m
RT: 18.18 min Scan# 1489
Delta R.T. -0.02 min
Lab File: L1201444.D
Acq: 3 Jul 2012 3:23 pm
Tgt Ion: 43 Resp: 38547
Ion Ratio Lower Upper
43 100
58 55.9 33.7 50.5#
57 21.8 15.2 22.8
100 11.6 10.4 15.6
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1535 (18.469 min): L1103939.D (-)
43
10071 176 212 235 255 282118 157137
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1489 (18.178 min): L1201444.D
43
97 28171126207163251 300
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1489 (18.178 min): L1201444.D (-)
9755 281
126
193 24975166 30036
18.15 18.20
0
10000
20000
30000
Time-->
AbundanceIon 43.00 (42.70 to 43.70): L12
18.18
Ion 58.00 (57.70 to 58.70): L12
Ion 57.10 (56.80 to 57.80): L12
Ion 100.00 (99.70 to 100.70): L
#59
m-/p-Xylenes
Concen: 0.33 PPBV
RT: 19.30 min Scan# 1601
Delta R.T. -0.02 min
Lab File: L1201444.D
Acq: 3 Jul 2012 3:23 pm
Tgt Ion: 91 Resp: 64443
Ion Ratio Lower Upper
91 100
106 51.8 39.3 58.9
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1647 (19.595 min): L1103939.D (-)
91
39 65 109 128145 176 203 235 262281
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1601 (19.305 min): L1201444.D
43 91
70
128 207111147 171 227 255
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1601 (19.305 min): L1201444.D (-)
91
43
70 128 191111147 171 208 255227
19.20 19.30 19.40
0
10000
20000
30000
Time-->
AbundanceIon 91.10 (90.80 to 91.80): L12
19.30
Ion 106.05 (105.75 to 106.75):
L1201444.D L062912C.M Wed Jul 11 11:40:19 2012 Page 10
#67
1,2,4-Trimethylbenzene
Concen: 0.29 PPBV m
RT: 20.83 min Scan# 1753
Delta R.T. -0.01 min
Lab File: L1201444.D
Acq: 3 Jul 2012 3:23 pm
Tgt Ion:105 Resp: 61625
Ion Ratio Lower Upper
105 100
120 44.5 37.8 56.6
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1803 (21.164 min): L1103939.D (-)
105
773958 299126 146165 189209 233252271
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1753 (20.833 min): L1201444.D
105
43 69
20713917687 267226 246
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1753 (20.833 min): L1201444.D (-)
105
7751 139 26732191226 246163
20.80 20.85
0
10000
20000
30000
40000
Time-->
AbundanceIon 105.10 (104.80 to 105.80):
20.83
Ion 120.15 (119.85 to 120.85):
L1201444.D L062912C.M Wed Jul 11 11:40:20 2012 Page 11
Quantitation Report
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201445.D Vial: 5
Acq On : 3 Jul 2012 4:11 pm Operator: DB
Sample : TO15-Tyner St.-V-4-Can #00192 Inst : Lurch
Misc : 0612-142, 500mL load Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 11:43 2012 Quant Results File: L062912C.RES
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00
0
500000
1000000
1500000
2000000
2500000
3000000
3500000
4000000
4500000
5000000
5500000
6000000
6500000
7000000
7500000
8000000
8500000
9000000
Time-->
Abundance TIC: L1201445.D
1,2,4-Trimethylbenzenem-/p-XylenesChlorobenzene-d5 (IS),I2-Hexanone (Methyl butyl ketone)TetrachloroetheneTolueneMethyl isobutyl ketoneTrichloroethene1,4-Difluorobenzene (IS),IChloroformBromochloromethane (IS),IEthyl acetateMethyl ethyl ketone (2-Butanone)Methylene chlorideIsopropyl alcoholAcetoneEthanolL1201445.D L062912C.M Wed Jul 11 11:43:49 2012 Page 3
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201445.D Vial: 5
Acq On : 3 Jul 2012 4:11 pm Operator: DB
Sample : TO15-Tyner St.-V-4-Can #00192 Inst : Lurch
Misc : 0612-142, 500mL load Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 11:43 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) Bromochloromethane (IS) 13.06 130 556970 11.03 PPBV -0.02
36) 1,4-Difluorobenzene (IS) 14.86 114 2147949 10.52 PPBV -0.02
48) Chlorobenzene-d5 (IS) 19.07 117 1958199 11.20 PPBV 0.00
Target Compounds Qvalue
2) Propylene 0.00 41 0 N.D. d
3) Freon 12 (CCl2F2) 0.00 85 0 N.D. d
4) Freon 114 (C2Cl2F4) 0.00 85 0 N.D. d
5) Chloromethane 0.00 50 0 N.D. d
6) Chloroethene (Vinyl chlori 0.00 62 0 N.D.
7) 1,3-Butadiene 0.00 39 0 N.D. d
8) Bromomethane 0.00 94 0 N.D.
9) Chloroethane 0.00 64 0 N.D. d
10) Bromoethene (Vinyl bromide 0.00 106 0 N.D.
11) Freon 11 (CCl3F) 0.00 101 0 N.D. d
12) Ethanol 7.86 45 28217 1.27 PPBV # 78
13) Acrolein 0.00 56 0 N.D. d
14) Freon 113 (C2Cl3F3) 0.00 151 0 N.D. d
15) 1,1-Dichloroethene 0.00 61 0 N.D.
16) Acetone 8.75 43 868444 6.75 PPBV # 79
17) Carbon disulfide 0.00 76 0 N.D. d
18) Isopropyl alcohol 9.10 45 91635 0.69 PPBV # 87
19) Allyl chloride (3-chloropr 0.00 76 0 N.D.
20) Acetonitrile 0.00 41 0 N.D. d
21) Methylene chloride 9.79 49 31870 0.32 PPBV # 80
22) trans-1,2-Dichloroethene 0.00 61 0 N.D.
23) Methyl tert-butyl ether 0.00 73 0 N.D. d
24) Acrylonitrile 0.00 53 0 N.D.
25) Hexane 0.00 57 0 N.D. d
26) 1,1-Dichloroethane 0.00 63 0 N.D.
27) Vinyl acetate 0.00 43 0 N.D. d
28) cis-1,2-Dichloroethylene 0.00 61 0 N.D. d
29) Methyl ethyl ketone (2-But 12.55 72 36494 1.25 PPBV 83
30) Ethyl acetate 12.65 45 42101 1.64 PPBV # 81
31) Chloroform 13.24 83 87903 0.65 PPBV 96
32) Tetrahydrofuran 0.00 72 0 N.D. d
33) 1,1,1-Trichloroethane 0.00 97 0 N.D. d
34) Cyclohexane 0.00 56 0 N.D. d
35) Carbon tetrachloride 0.00 117 0 N.D. d
37) Benzene 0.00 78 0 N.D. d
38) 2,2,4-trimethylpentane 0.00 57 0 N.D. d
39) 1,2-Dichloroethane 0.00 62 0 N.D. d
40) Heptane 0.00 57 0 N.D. d
41) Trichloroethene 15.24 130 2877772 31.36 PPBV # 88
42) 1,2-Dichloropropane 0.00 63 0 N.D.
43) Methyl methacrylate 0.00 69 0 N.D.
44) 1,4-Dioxane 0.00 88 0 N.D.
45) Bromodichloromethane 0.00 83 0 N.D. d
46) cis-1,3-Dichloropropene 0.00 75 0 N.D.
47) Methyl isobutyl ketone 17.02 43 65726 0.33 PPBV # 97
49) Toluene 17.39 91 92041 0.46 PPBV 96
50) trans-1,3-Dichloropropene 0.00 75 0 N.D.
51) 1,1,2-Trichloroethane 0.00 97 0 N.D.
52) Tetrachloroethene 18.09 166 248552 2.44 PPBV 96
53) 2-Hexanone (Methyl butyl k 18.18 43 58767 0.33 PPBV # 95
54) Dibromochloromethane 0.00 129 0 N.D. d
55) 1,2-Dibromoethane 0.00 107 0 N.D.
56) Chlorobenzene 0.00 112 0 N.D.
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201445.D L062912C.M Wed Jul 11 11:43:49 2012 Page 1
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201445.D Vial: 5
Acq On : 3 Jul 2012 4:11 pm Operator: DB
Sample : TO15-Tyner St.-V-4-Can #00192 Inst : Lurch
Misc : 0612-142, 500mL load Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 11:43 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Compound R.T. QIon Response Conc Unit Qvalue
-------------------------------------------------------------------------
57) Ethylbenzene 0.00 91 0 N.D. d
58) 1,1,1,2-Tetrachloroethane 0.00 131 0 N.D.
59) m-/p-Xylenes 19.30 91 59559 0.31 PPBV 97
60) o-Xylene 0.00 91 0 N.D. d
61) Styrene 0.00 104 0 N.D. d
62) Bromoform 0.00 173 0 N.D.
63) 1,1,2,2-Tetrachloroethane 0.00 83 0 N.D. d
64) 4-Ethyltoluene 0.00 105 0 N.D. d
65) 2-Chlorotoluene 0.00 91 0 N.D. d
66) 1,3,5-Trimethylbenzene 0.00 105 0 N.D. d
67) 1,2,4-Trimethylbenzene 20.83 105 63636 0.30 PPBV # 76
68) 1,3-Dichlorobenzene 0.00 146 0 N.D. d
69) 1,4-Dichlorobenzene 0.00 146 0 N.D. d
70) Benzyl chloride 0.00 91 0 N.D. d
71) 1,2-Dichlorobenzene 0.00 146 0 N.D.
72) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. d
73) Hexachlorobutadiene 0.00 225 0 N.D.
74) Naphthalene 0.00 128 0 N.D. d
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201445.D L062912C.M Wed Jul 11 11:43:49 2012 Page 2
#12
Ethanol
Concen: 1.27 PPBV
RT: 7.86 min Scan# 463
Delta R.T. -0.02 min
Lab File: L1201445.D
Acq: 3 Jul 2012 4:11 pm
Tgt Ion: 45 Resp: 28217
Ion Ratio Lower Upper
45 100
43 23.2 31.3 46.9#
31 223.4 209.9 314.9
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 512 (8.184 min): L1103939.D (-)
31
7854 200106 220 247133 278 299153172
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 463 (7.858 min): L1201445.D
31
94 20755 26973163136
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 463 (7.858 min): L1201445.D (-)
31
10761 148 210177 26282128
7.70 7.80 7.90 8.00
0
10000
20000
Time-->
AbundanceIon 44.95 (44.65 to 45.65): L12
7.86
Ion 42.95 (42.65 to 43.65): L12
Ion 30.95 (30.65 to 31.65): L12
#16
Acetone
Concen: 6.75 PPBV
RT: 8.75 min Scan# 552
Delta R.T. -0.02 min
Lab File: L1201445.D
Acq: 3 Jul 2012 4:11 pm
Tgt Ion: 43 Resp: 868444
Ion Ratio Lower Upper
43 100
58 24.0 12.2 18.4#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 572 (8.797 min): L1200822.D (-)
43
168128 2947622119397147254
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 552 (8.753 min): L1201445.D
43
85 151 187206 27710366
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 552 (8.753 min): L1201445.D (-)
43
194 2776615185 103
8.60 8.70 8.80 8.90
0
100000
200000
300000
Time-->
AbundanceIon 43.00 (42.70 to 43.70): L12
8.75
Ion 58.00 (57.70 to 58.70): L12
L1201445.D L062912C.M Wed Jul 11 11:44:02 2012 Page 3
#18
Isopropyl alcohol
Concen: 0.69 PPBV
RT: 9.10 min Scan# 587
Delta R.T. -0.02 min
Lab File: L1201445.D
Acq: 3 Jul 2012 4:11 pm
Tgt Ion: 45 Resp: 91635
Ion Ratio Lower Upper
45 100
43 19.2 21.4 32.2#
59 3.4 2.5 3.7
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 641 (9.481 min): L1103939.D (-)
45
77 266116286152171 19221197 243
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 587 (9.105 min): L1201445.D
45
76 207 26213394 291
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 587 (9.105 min): L1201445.D (-)
45
76 26294212 294133
8.90 9.00 9.10 9.20
0
10000
20000
30000
40000
Time-->
AbundanceIon 45.00 (44.70 to 45.70): L12
9.10
Ion 43.10 (42.80 to 43.80): L12
Ion 59.00 (58.70 to 59.70): L12
#21
Methylene chloride
Concen: 0.32 PPBV
RT: 9.79 min Scan# 655
Delta R.T. -0.02 min
Lab File: L1201445.D
Acq: 3 Jul 2012 4:11 pm
Tgt Ion: 49 Resp: 31870
Ion Ratio Lower Upper
49 100
84 65.2 66.8 100.2#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 675 (9.833 min): L1200822.D (-)
49 84
109 142 207 248 27822429
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 655 (9.789 min): L1201445.D
49
8432
177 206124 273145223241103
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 655 (9.789 min): L1201445.D (-)
49
84
29 191167 213121 145 273230103248
9.70 9.80 9.90
0
5000
10000
Time-->
AbundanceIon 49.05 (48.75 to 49.75): L12
9.79
Ion 84.00 (83.70 to 84.70): L12
L1201445.D L062912C.M Wed Jul 11 11:44:03 2012 Page 4
#29
Methyl ethyl ketone (2-Butanone)
Concen: 1.25 PPBV
RT: 12.55 min Scan# 930
Delta R.T. -0.02 min
Lab File: L1201445.D
Acq: 3 Jul 2012 4:11 pm
Tgt Ion: 72 Resp: 36494
Ion Ratio Lower Upper
72 100
43 574.7 420.9 631.3
57 33.3 32.6 48.8
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 984 (12.929 min): L1103939.D
43
72
96 123 143 162 182 201 226 254 273
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 930 (12.555 min): L1201445.D
43
72
26592207110127 152170187
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 930 (12.555 min): L1201445.D (-)
43
72
120138 159 184 20592 265
12.40 12.50 12.60 12.70
0
50000
100000
150000
Time-->
AbundanceIon 72.00 (71.70 to 72.70): L12
12.55
Ion 43.00 (42.70 to 43.70): L12
Ion 57.00 (56.70 to 57.70): L12
#30
Ethyl acetate
Concen: 1.64 PPBV
RT: 12.65 min Scan# 939
Delta R.T. -0.02 min
Lab File: L1201445.D
Acq: 3 Jul 2012 4:11 pm
Tgt Ion: 45 Resp: 42101
Ion Ratio Lower Upper
45 100
61 76.1 0.0 0.0#
88 27.8 27.6 41.4
70 57.0 60.6 90.8#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 994 (13.030 min): L1103939.D (-)
43
70 88 202 238116 261 288139159
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 939 (12.645 min): L1201445.D
43
61 88 119 198216 268
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 939 (12.645 min): L1201445.D (-)
43
61 88 119 198216 268
12.60 12.70
0
5000
10000
15000
20000
Time-->
AbundanceIon 45.00 (44.70 to 45.70): L12
12.65
Ion 61.00 (60.70 to 61.70): L12Ion 88.00 (87.70 to 88.70): L12Ion 70.00 (69.70 to 70.70): L12
L1201445.D L062912C.M Wed Jul 11 11:44:03 2012 Page 5
#31
Chloroform
Concen: 0.65 PPBV
RT: 13.24 min Scan# 998
Delta R.T. -0.02 min
Lab File: L1201445.D
Acq: 3 Jul 2012 4:11 pm
Tgt Ion: 83 Resp: 87903
Ion Ratio Lower Upper
83 100
85 68.3 52.3 78.5
Ref
Raw
Sub
40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1052 (13.613 min): L1103939.D (-)
83
47
120 200 224 252 275294141 161180102
40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 998 (13.239 min): L1201445.D
83
47
117 153 299181 207 231248 270135
40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 998 (13.239 min): L1201445.D (-)
83
117 18142145 299207 227 248267
13.10 13.20 13.30 13.40
0
10000
20000
30000
Time-->
AbundanceIon 83.00 (82.70 to 83.70): L12
13.24
Ion 85.00 (84.70 to 85.70): L12
#41
Trichloroethene
Concen: 31.36 PPBV
RT: 15.24 min Scan# 1197
Delta R.T. -0.02 min
Lab File: L1201445.D
Acq: 3 Jul 2012 4:11 pm
Tgt Ion:130 Resp: 2877772
Ion Ratio Lower Upper
130 100
132 97.9 79.5 119.3
95 98.9 61.1 91.7#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1247 (15.574 min): L1103939.D (-)
13095
60
35
151 171 198 218 246264 284
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1197 (15.240 min): L1201445.D
13095
60
35
171189 210 245 269151
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1197 (15.240 min): L1201445.D (-)
13095
60
35
151 171 207 242 269
15.10 15.20 15.30 15.40
0
500000
1000000
1500000
Time-->
AbundanceIon 130.00 (129.70 to 130.70):
15.24
Ion 132.00 (131.70 to 132.70): Ion 95.00 (94.70 to 95.70): L12
L1201445.D L062912C.M Wed Jul 11 11:44:03 2012 Page 6
#47
Methyl isobutyl ketone
Concen: 0.33 PPBV
RT: 17.02 min Scan# 1374
Delta R.T. -0.03 min
Lab File: L1201445.D
Acq: 3 Jul 2012 4:11 pm
Tgt Ion: 43 Resp: 65726
Ion Ratio Lower Upper
43 100
58 32.7 26.3 39.5
85 14.5 14.8 22.2#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1427 (17.384 min): L1103939.D (-)
43
85
67 108 135 155 191 223242 262281
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1374 (17.020 min): L1201445.D
43
85 110 220 29025266199270
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1374 (17.020 min): L1201445.D (-)
43
100
81 22762 252 286199
16.90 17.00 17.10
0
10000
20000
30000
Time-->
AbundanceIon 43.00 (42.70 to 43.70): L12
17.02
Ion 58.00 (57.70 to 58.70): L12
Ion 85.00 (84.70 to 85.70): L12
#49
Toluene
Concen: 0.46 PPBV
RT: 17.39 min Scan# 1411
Delta R.T. -0.02 min
Lab File: L1201445.D
Acq: 3 Jul 2012 4:11 pm
Tgt Ion: 91 Resp: 92041
Ion Ratio Lower Upper
91 100
92 63.3 48.2 72.4
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1459 (17.705 min): L1103939.D (-)
91
39 65 135 162180 205 244 280110
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1411 (17.393 min): L1201445.D
91
39 65 112 133 207 234 262280
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1411 (17.393 min): L1201445.D (-)
91
39 65 112 262280238133207
17.30 17.40 17.50
0
10000
20000
30000
40000
Time-->
AbundanceIon 91.10 (90.80 to 91.80): L12
17.39
Ion 92.10 (91.80 to 92.80): L12
L1201445.D L062912C.M Wed Jul 11 11:44:04 2012 Page 7
#52
Tetrachloroethene
Concen: 2.44 PPBV
RT: 18.09 min Scan# 1480
Delta R.T. -0.02 min
Lab File: L1201445.D
Acq: 3 Jul 2012 4:11 pm
Tgt Ion:166 Resp: 248552
Ion Ratio Lower Upper
166 100
164 78.3 63.0 94.6
131 67.5 59.0 88.4
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1526 (18.379 min): L1103939.D (-)
166131
94
47
18820765 232 252 275295
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1480 (18.087 min): L1201445.D
166
129
9447
65 190 221 254 282
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1480 (18.087 min): L1201445.D (-)
166
129
9447
65 193 225 257 281
18.00 18.10 18.20
0
50000
100000
150000
Time-->
AbundanceIon 165.90 (165.60 to 166.60):
18.09
Ion 163.90 (163.60 to 164.60):
Ion 130.90 (130.60 to 131.60):
#53
2-Hexanone (Methyl butyl ketone)
Concen: 0.33 PPBV
RT: 18.18 min Scan# 1489
Delta R.T. -0.02 min
Lab File: L1201445.D
Acq: 3 Jul 2012 4:11 pm
Tgt Ion: 43 Resp: 58767
Ion Ratio Lower Upper
43 100
58 40.9 33.7 50.5
57 15.0 15.2 22.8#
100 8.6 10.4 15.6#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1535 (18.469 min): L1103939.D (-)
43
10071 176 212 235 255 282118 157137
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1489 (18.177 min): L1201445.D
43
10071 283118207188247143 164
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1489 (18.177 min): L1201445.D (-)
43
10073118 188 209 247 283143 164
18.10 18.20 18.30
0
10000
20000
30000
40000
Time-->
AbundanceIon 43.00 (42.70 to 43.70): L12
18.18
Ion 58.00 (57.70 to 58.70): L12Ion 57.10 (56.80 to 57.80): L12Ion 100.00 (99.70 to 100.70): L
L1201445.D L062912C.M Wed Jul 11 11:44:04 2012 Page 8
#59
m-/p-Xylenes
Concen: 0.31 PPBV
RT: 19.30 min Scan# 1601
Delta R.T. -0.02 min
Lab File: L1201445.D
Acq: 3 Jul 2012 4:11 pm
Tgt Ion: 91 Resp: 59559
Ion Ratio Lower Upper
91 100
106 50.9 39.3 58.9
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1647 (19.595 min): L1103939.D (-)
91
39 65 109 128145 176 203 235 262281
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1601 (19.304 min): L1201445.D
43 91
70
128111 207148 234 260
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1601 (19.304 min): L1201445.D (-)
9143
70
128111 207148 234 260
19.20 19.30 19.40
0
10000
20000
30000
Time-->
AbundanceIon 91.10 (90.80 to 91.80): L12
19.30
Ion 106.05 (105.75 to 106.75):
#67
1,2,4-Trimethylbenzene
Concen: 0.30 PPBV
RT: 20.83 min Scan# 1753
Delta R.T. -0.01 min
Lab File: L1201445.D
Acq: 3 Jul 2012 4:11 pm
Tgt Ion:105 Resp: 63636
Ion Ratio Lower Upper
105 100
120 31.0 37.8 56.6#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1803 (21.164 min): L1103939.D (-)
105
773958 299126 146165 189209 233252271
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1753 (20.832 min): L1201445.D
105
41 69
207139 28116387260230
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1753 (20.832 min): L1201445.D (-)
105
7751 139 209 267163 191 23024933
20.70 20.80 20.90
0
10000
20000
30000
Time-->
AbundanceIon 105.10 (104.80 to 105.80):
20.83
Ion 120.15 (119.85 to 120.85):
L1201445.D L062912C.M Wed Jul 11 11:44:05 2012 Page 9
Quantitation Report
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201446.D Vial: 6
Acq On : 3 Jul 2012 5:00 pm Operator: DB
Sample : TO15-Tyner St.-V-DUP-Can #00229 Inst : Lurch
Misc : 0612-142, 500mL load Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 11:48 2012 Quant Results File: L062912C.RES
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00
0
500000
1000000
1500000
2000000
2500000
3000000
3500000
4000000
4500000
5000000
5500000
6000000
6500000
7000000
7500000
8000000
8500000
9000000
9500000
Time-->
Abundance TIC: L1201446.D
1,2,4-Trimethylbenzenem-/p-XylenesChlorobenzene-d5 (IS),I2-Hexanone (Methyl butyl ketone)TetrachloroetheneTolueneMethyl isobutyl ketoneTrichloroethene1,4-Difluorobenzene (IS),IChloroformBromochloromethane (IS),IEthyl acetateMethyl ethyl ketone (2-Butanone)Methylene chlorideAcetonitrileCarbon disulfideIsopropyl alcoholAcetoneEthanolL1201446.D L062912C.M Wed Jul 11 11:48:21 2012 Page 3
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201446.D Vial: 6
Acq On : 3 Jul 2012 5:00 pm Operator: DB
Sample : TO15-Tyner St.-V-DUP-Can #00229 Inst : Lurch
Misc : 0612-142, 500mL load Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 11:48 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) Bromochloromethane (IS) 13.06 130 558253 11.03 PPBV -0.02
36) 1,4-Difluorobenzene (IS) 14.86 114 2157876 10.52 PPBV -0.02
48) Chlorobenzene-d5 (IS) 19.07 117 1989214 11.20 PPBV 0.00
Target Compounds Qvalue
2) Propylene 0.00 41 0 N.D. d
3) Freon 12 (CCl2F2) 0.00 85 0 N.D. d
4) Freon 114 (C2Cl2F4) 0.00 85 0 N.D. d
5) Chloromethane 0.00 50 0 N.D. d
6) Chloroethene (Vinyl chlori 0.00 62 0 N.D.
7) 1,3-Butadiene 0.00 39 0 N.D.
8) Bromomethane 0.00 94 0 N.D.
9) Chloroethane 0.00 64 0 N.D. d
10) Bromoethene (Vinyl bromide 0.00 106 0 N.D.
11) Freon 11 (CCl3F) 0.00 101 0 N.D. d
12) Ethanol 7.86 45 48479 2.18 PPBV # 72
13) Acrolein 0.00 56 0 N.D. d
14) Freon 113 (C2Cl3F3) 0.00 151 0 N.D. d
15) 1,1-Dichloroethene 0.00 61 0 N.D.
16) Acetone 8.75 43 1202276 9.33 PPBV # 79
17) Carbon disulfide 9.15 76 45983 0.26 PPBV # 63
18) Isopropyl alcohol 9.10 45 496848 3.76 PPBV # 84
19) Allyl chloride (3-chloropr 0.00 76 0 N.D.
20) Acetonitrile 9.37 41 13335 0.20 PPBV 94
21) Methylene chloride 9.79 49 50598 0.51 PPBV # 77
22) trans-1,2-Dichloroethene 0.00 61 0 N.D.
23) Methyl tert-butyl ether 0.00 73 0 N.D. d
24) Acrylonitrile 0.00 53 0 N.D.
25) Hexane 0.00 57 0 N.D. d
26) 1,1-Dichloroethane 0.00 63 0 N.D.
27) Vinyl acetate 0.00 43 0 N.D. d
28) cis-1,2-Dichloroethylene 0.00 61 0 N.D. d
29) Methyl ethyl ketone (2-But 12.56 72 41613 1.42 PPBV 77
30) Ethyl acetate 12.65 45 45770 1.78 PPBV # 80
31) Chloroform 13.24 83 91255 0.68 PPBV 98
32) Tetrahydrofuran 0.00 72 0 N.D. d
33) 1,1,1-Trichloroethane 0.00 97 0 N.D. d
34) Cyclohexane 0.00 56 0 N.D. d
35) Carbon tetrachloride 0.00 117 0 N.D. d
37) Benzene 0.00 78 0 N.D. d
38) 2,2,4-trimethylpentane 0.00 57 0 N.D. d
39) 1,2-Dichloroethane 0.00 62 0 N.D. d
40) Heptane 0.00 57 0 N.D. d
41) Trichloroethene 15.24 130 2850243 30.92 PPBV # 87
42) 1,2-Dichloropropane 0.00 63 0 N.D.
43) Methyl methacrylate 0.00 69 0 N.D. d
44) 1,4-Dioxane 0.00 88 0 N.D.
45) Bromodichloromethane 0.00 83 0 N.D. d
46) cis-1,3-Dichloropropene 0.00 75 0 N.D.
47) Methyl isobutyl ketone 17.02 43 70953 0.35 PPBV # 95
49) Toluene 17.39 91 84844 0.42 PPBV 97
50) trans-1,3-Dichloropropene 0.00 75 0 N.D. d
51) 1,1,2-Trichloroethane 0.00 97 0 N.D.
52) Tetrachloroethene 18.10 166 258964 2.50 PPBV 96
53) 2-Hexanone (Methyl butyl k 18.19 43 71466 0.40 PPBV # 95
54) Dibromochloromethane 0.00 129 0 N.D. d
55) 1,2-Dibromoethane 0.00 107 0 N.D.
56) Chlorobenzene 0.00 112 0 N.D. d
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201446.D L062912C.M Wed Jul 11 11:48:20 2012 Page 1
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201446.D Vial: 6
Acq On : 3 Jul 2012 5:00 pm Operator: DB
Sample : TO15-Tyner St.-V-DUP-Can #00229 Inst : Lurch
Misc : 0612-142, 500mL load Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 11:48 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Compound R.T. QIon Response Conc Unit Qvalue
-------------------------------------------------------------------------
57) Ethylbenzene 0.00 91 0 N.D. d
58) 1,1,1,2-Tetrachloroethane 0.00 131 0 N.D.
59) m-/p-Xylenes 19.30 91 58135 0.30 PPBV 93
60) o-Xylene 0.00 91 0 N.D. d
61) Styrene 0.00 104 0 N.D. d
62) Bromoform 0.00 173 0 N.D.
63) 1,1,2,2-Tetrachloroethane 0.00 83 0 N.D. d
64) 4-Ethyltoluene 0.00 105 0 N.D. d
65) 2-Chlorotoluene 0.00 91 0 N.D. d
66) 1,3,5-Trimethylbenzene 0.00 105 0 N.D. d
67) 1,2,4-Trimethylbenzene 20.83 105 67101 0.31 PPBV # 78
68) 1,3-Dichlorobenzene 0.00 146 0 N.D. d
69) 1,4-Dichlorobenzene 0.00 146 0 N.D. d
70) Benzyl chloride 0.00 91 0 N.D. d
71) 1,2-Dichlorobenzene 0.00 146 0 N.D.
72) 1,2,4-Trichlorobenzene 0.00 180 0 N.D.
73) Hexachlorobutadiene 0.00 225 0 N.D.
74) Naphthalene 0.00 128 0 N.D. d
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201446.D L062912C.M Wed Jul 11 11:48:21 2012 Page 2
#12
Ethanol
Concen: 2.18 PPBV
RT: 7.86 min Scan# 462
Delta R.T. -0.02 min
Lab File: L1201446.D
Acq: 3 Jul 2012 5:00 pm
Tgt Ion: 45 Resp: 48479
Ion Ratio Lower Upper
45 100
43 24.9 31.3 46.9#
31 210.8 209.9 314.9
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 512 (8.184 min): L1103939.D (-)
31
7854 200106 220 247133 278 299153172
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 462 (7.859 min): L1201446.D
31
75 143 16750 20793 111 185 227 249 269
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 462 (7.859 min): L1201446.D (-)
31
75 93 136 168 21311151186 234 262
7.70 7.80 7.90 8.00
0
10000
20000
30000
40000
Time-->
AbundanceIon 44.95 (44.65 to 45.65): L12
7.86
Ion 42.95 (42.65 to 43.65): L12
Ion 30.95 (30.65 to 31.65): L12
#16
Acetone
Concen: 9.33 PPBV
RT: 8.75 min Scan# 551
Delta R.T. -0.02 min
Lab File: L1201446.D
Acq: 3 Jul 2012 5:00 pm
Tgt Ion: 43 Resp: 1202276
Ion Ratio Lower Upper
43 100
58 24.0 12.2 18.4#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 572 (8.797 min): L1200822.D (-)
43
168128 2947622119397147254
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 551 (8.754 min): L1201446.D
43
26097 139 16469182 207 238
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 551 (8.754 min): L1201446.D (-)
43
97 143 16869 264189 210 242
8.60 8.70 8.80 8.90
0
100000
200000
300000
400000
Time-->
AbundanceIon 43.00 (42.70 to 43.70): L12
8.75
Ion 58.00 (57.70 to 58.70): L12
L1201446.D L062912C.M Wed Jul 11 11:48:42 2012 Page 3
#17
Carbon disulfide
Concen: 0.26 PPBV
RT: 9.15 min Scan# 590
Delta R.T. -0.03 min
Lab File: L1201446.D
Acq: 3 Jul 2012 5:00 pm
Tgt Ion: 76 Resp: 45983
Ion Ratio Lower Upper
76 100
78 10.0 8.0 12.0
44 0.0 21.0 31.4#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 641 (9.481 min): L1103939.D (-)
76
45
196 239 26628621596 116 152171
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 590 (9.146 min): L1201446.D
7645
207100183 225 247 278296
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 590 (9.146 min): L1201446.D (-)
7645
229 29226194179 207
9.00 9.10 9.20
0
5000
10000
15000
20000
Time-->
AbundanceIon 76.00 (75.70 to 76.70): L12
9.15
Ion 78.00 (77.70 to 78.70): L12
Ion 44.10 (43.80 to 44.80): L12
#18
Isopropyl alcohol
Concen: 3.76 PPBV
RT: 9.10 min Scan# 585
Delta R.T. -0.03 min
Lab File: L1201446.D
Acq: 3 Jul 2012 5:00 pm
Tgt Ion: 45 Resp: 496848
Ion Ratio Lower Upper
45 100
43 17.5 21.4 32.2#
59 3.1 2.5 3.7
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 641 (9.481 min): L1103939.D (-)
45
77 266116286152171 19221197 243
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 585 (9.096 min): L1201446.D
45
29789 107 128 15064168 202 272234
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 585 (9.096 min): L1201446.D (-)
45
29793 111 132 15364171 202 234 262
9.00 9.20
0
50000
100000
150000
200000
Time-->
AbundanceIon 45.00 (44.70 to 45.70): L12
9.10
Ion 43.10 (42.80 to 43.80): L12Ion 59.00 (58.70 to 59.70): L12
L1201446.D L062912C.M Wed Jul 11 11:48:43 2012 Page 4
#20
Acetonitrile
Concen: 0.20 PPBV
RT: 9.37 min Scan# 612
Delta R.T. -0.02 min
Lab File: L1201446.D
Acq: 3 Jul 2012 5:00 pm
Tgt Ion: 41 Resp: 13335
Ion Ratio Lower Upper
41 100
40 57.8 51.7 77.5
39 32.9 25.2 37.8
38 24.3 21.7 32.5
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 668 (9.752 min): L1103939.D (-)
41
97 17112869 195214 245 281147
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 612 (9.368 min): L1201446.D
44
20768 125 242 266100 143 178
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 612 (9.368 min): L1201446.D (-)
41
65 24513589 270178 210117153
9.20 9.30 9.40
0
2000
4000
6000
Time-->
AbundanceIon 40.95 (40.65 to 41.65): L12
9.37
Ion 40.00 (39.70 to 40.70): L12
Ion 38.90 (38.60 to 39.60): L12
Ion 37.90 (37.60 to 38.60): L12
#21
Methylene chloride
Concen: 0.51 PPBV
RT: 9.79 min Scan# 654
Delta R.T. -0.02 min
Lab File: L1201446.D
Acq: 3 Jul 2012 5:00 pm
Tgt Ion: 49 Resp: 50598
Ion Ratio Lower Upper
49 100
84 62.7 66.8 100.2#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 675 (9.833 min): L1200822.D (-)
49 84
109 142 207 248 27822829
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 654 (9.790 min): L1201446.D
49
84
207 259277112 14331 168186 238
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 654 (9.790 min): L1201446.D (-)
49
84
143 172 292112192210 238256
9.70 9.80 9.90
0
5000
10000
15000
20000
Time-->
AbundanceIon 49.05 (48.75 to 49.75): L12
9.79
Ion 84.00 (83.70 to 84.70): L12
L1201446.D L062912C.M Wed Jul 11 11:48:43 2012 Page 5
#29
Methyl ethyl ketone (2-Butanone)
Concen: 1.42 PPBV
RT: 12.56 min Scan# 929
Delta R.T. -0.02 min
Lab File: L1201446.D
Acq: 3 Jul 2012 5:00 pm
Tgt Ion: 72 Resp: 41613
Ion Ratio Lower Upper
72 100
43 593.6 420.9 631.3
57 35.4 32.6 48.8
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 984 (12.929 min): L1103939.D
43
72
96 123 143 162 182 201 226 254 273
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 929 (12.556 min): L1201446.D
43
72
90 111 139 207 238
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 929 (12.556 min): L1201446.D (-)
43
72
97 118 139 207 238
12.50 12.60
0
50000
100000
150000
Time-->
AbundanceIon 72.00 (71.70 to 72.70): L12
12.56
Ion 43.00 (42.70 to 43.70): L12
Ion 57.00 (56.70 to 57.70): L12
#30
Ethyl acetate
Concen: 1.78 PPBV
RT: 12.65 min Scan# 938
Delta R.T. -0.02 min
Lab File: L1201446.D
Acq: 3 Jul 2012 5:00 pm
Tgt Ion: 45 Resp: 45770
Ion Ratio Lower Upper
45 100
61 75.8 0.0 0.0#
88 27.0 27.6 41.4#
70 56.2 60.6 90.8#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 994 (13.030 min): L1103939.D (-)
43
70 88 202 238116 261 288139159
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 938 (12.646 min): L1201446.D
43
61 88 125 177 297196 216 245 273
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 938 (12.646 min): L1201446.D (-)
43
61 88 125 184 209 245 280
12.60 12.70 12.80
0
5000
10000
15000
20000
25000
Time-->
AbundanceIon 45.00 (44.70 to 45.70): L12
12.65
Ion 61.00 (60.70 to 61.70): L12Ion 88.00 (87.70 to 88.70): L12Ion 70.00 (69.70 to 70.70): L12
L1201446.D L062912C.M Wed Jul 11 11:48:43 2012 Page 6
#31
Chloroform
Concen: 0.68 PPBV
RT: 13.24 min Scan# 997
Delta R.T. -0.02 min
Lab File: L1201446.D
Acq: 3 Jul 2012 5:00 pm
Tgt Ion: 83 Resp: 91255
Ion Ratio Lower Upper
83 100
85 67.2 52.3 78.5
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1052 (13.613 min): L1103939.D (-)
83
47
120 200 224 252 275294141161180102
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 997 (13.240 min): L1201446.D
83
47
29 120 207 293257
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 997 (13.240 min): L1201446.D (-)
83
29 57 120 293257
13.10 13.20 13.30 13.40
0
10000
20000
30000
Time-->
AbundanceIon 83.00 (82.70 to 83.70): L12
13.24
Ion 85.00 (84.70 to 85.70): L12
#41
Trichloroethene
Concen: 30.92 PPBV
RT: 15.24 min Scan# 1196
Delta R.T. -0.02 min
Lab File: L1201446.D
Acq: 3 Jul 2012 5:00 pm
Tgt Ion:130 Resp: 2850243
Ion Ratio Lower Upper
130 100
132 97.7 79.5 119.3
95 99.3 61.1 91.7#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1247 (15.574 min): L1103939.D (-)
13095
60
35
151171 198 218 246264 284
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1196 (15.241 min): L1201446.D
13095
60
35
191 257 281
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1196 (15.241 min): L1201446.D (-)
13095
60
35
191 253 297
15.20 15.40
0
500000
1000000
1500000
Time-->
AbundanceIon 130.00 (129.70 to 130.70):
15.24
Ion 132.00 (131.70 to 132.70): Ion 95.00 (94.70 to 95.70): L12
L1201446.D L062912C.M Wed Jul 11 11:48:44 2012 Page 7
#47
Methyl isobutyl ketone
Concen: 0.35 PPBV
RT: 17.02 min Scan# 1373
Delta R.T. -0.03 min
Lab File: L1201446.D
Acq: 3 Jul 2012 5:00 pm
Tgt Ion: 43 Resp: 70953
Ion Ratio Lower Upper
43 100
58 34.4 26.3 39.5
85 14.3 14.8 22.2#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1427 (17.384 min): L1103939.D (-)
43
85
67 108 135 155 191 223242 262281
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1373 (17.022 min): L1201446.D
43
10067 216 251 290141 170187
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1373 (17.022 min): L1201446.D (-)
43
100
67 298141 170 191 212231 255
16.90 17.00 17.10
0
10000
20000
30000
Time-->
AbundanceIon 43.00 (42.70 to 43.70): L12
17.02
Ion 58.00 (57.70 to 58.70): L12
Ion 85.00 (84.70 to 85.70): L12
#49
Toluene
Concen: 0.42 PPBV
RT: 17.39 min Scan# 1410
Delta R.T. -0.02 min
Lab File: L1201446.D
Acq: 3 Jul 2012 5:00 pm
Tgt Ion: 91 Resp: 84844
Ion Ratio Lower Upper
91 100
92 62.7 48.2 72.4
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1459 (17.705 min): L1103939.D (-)
91
39 65 135 162180 205 244 280110
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1410 (17.394 min): L1201446.D
91
43 65 112 133 192 281164
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1410 (17.394 min): L1201446.D (-)
91
43 65 112 136 164 192 281
17.30 17.40 17.50
0
10000
20000
30000
40000
Time-->
AbundanceIon 91.10 (90.80 to 91.80): L12
17.39
Ion 92.10 (91.80 to 92.80): L12
L1201446.D L062912C.M Wed Jul 11 11:48:44 2012 Page 8
#52
Tetrachloroethene
Concen: 2.50 PPBV
RT: 18.10 min Scan# 1480
Delta R.T. -0.01 min
Lab File: L1201446.D
Acq: 3 Jul 2012 5:00 pm
Tgt Ion:166 Resp: 258964
Ion Ratio Lower Upper
166 100
164 78.1 63.0 94.6
131 67.1 59.0 88.4
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1526 (18.379 min): L1103939.D (-)
166131
94
47
18820765 232 252 275295
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1480 (18.098 min): L1201446.D
166
129
9447
72 198216 237255 276 297
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1480 (18.098 min): L1201446.D (-)
166
129
9447
198216 237 26264280
18.00 18.10 18.20
0
50000
100000
150000
Time-->
AbundanceIon 165.90 (165.60 to 166.60):
18.10
Ion 163.90 (163.60 to 164.60):
Ion 130.90 (130.60 to 131.60):
#53
2-Hexanone (Methyl butyl ketone)
Concen: 0.40 PPBV
RT: 18.19 min Scan# 1489
Delta R.T. -0.01 min
Lab File: L1201446.D
Acq: 3 Jul 2012 5:00 pm
Tgt Ion: 43 Resp: 71466
Ion Ratio Lower Upper
43 100
58 41.2 33.7 50.5
57 14.5 15.2 22.8#
100 8.5 10.4 15.6#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1535 (18.469 min): L1103939.D (-)
43
10071 176 212 235 255 282118 157137
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1489 (18.188 min): L1201446.D
43
10071 133 207 281164260
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1489 (18.188 min): L1201446.D (-)
43
10071 133 207 281164260
18.10 18.20 18.30
0
10000
20000
30000
40000
50000
Time-->
AbundanceIon 43.00 (42.70 to 43.70): L12
18.19
Ion 58.00 (57.70 to 58.70): L12Ion 57.10 (56.80 to 57.80): L12Ion 100.00 (99.70 to 100.70): L
L1201446.D L062912C.M Wed Jul 11 11:48:44 2012 Page 9
#59
m-/p-Xylenes
Concen: 0.30 PPBV
RT: 19.30 min Scan# 1600
Delta R.T. -0.02 min
Lab File: L1201446.D
Acq: 3 Jul 2012 5:00 pm
Tgt Ion: 91 Resp: 58135
Ion Ratio Lower Upper
91 100
106 53.8 39.3 58.9
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1647 (19.595 min): L1103939.D (-)
91
39 65 109 128145 176 203 235 262281
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1600 (19.305 min): L1201446.D
43 91
70 128 207111177 260 281
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1600 (19.305 min): L1201446.D (-)
9143
70
128111 209177 260 281
19.20 19.30 19.40
0
10000
20000
30000
Time-->
AbundanceIon 91.10 (90.80 to 91.80): L12
19.30
Ion 106.05 (105.75 to 106.75):
#67
1,2,4-Trimethylbenzene
Concen: 0.31 PPBV
RT: 20.83 min Scan# 1752
Delta R.T. -0.01 min
Lab File: L1201446.D
Acq: 3 Jul 2012 5:00 pm
Tgt Ion:105 Resp: 67101
Ion Ratio Lower Upper
105 100
120 32.2 37.8 56.6#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1803 (21.164 min): L1103939.D (-)
105
773958 299126 146165 189209 233252271
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1752 (20.834 min): L1201446.D
105
41 69
207139 26717987158232
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1752 (20.834 min): L1201446.D (-)
105
7751 154 267136 17933 208
20.80 20.90
0
10000
20000
30000
Time-->
AbundanceIon 105.10 (104.80 to 105.80):
20.83
Ion 120.15 (119.85 to 120.85):
L1201446.D L062912C.M Wed Jul 11 11:48:45 2012 Page 10
Quantitation Report
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201447.D Vial: 2
Acq On : 3 Jul 2012 5:49 pm Operator: DB
Sample : TO15-Tyner St.-V-1-Can #00206 LD Inst : Lurch
Misc : 0612-142, 500mL load Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 11:56 2012 Quant Results File: L062912C.RES
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00
0
1000000
2000000
3000000
4000000
5000000
6000000
7000000
8000000
9000000
1e+07
1.1e+07
1.2e+07
1.3e+07
1.4e+07
1.5e+07
1.6e+07
1.7e+07
Time-->
Abundance TIC: L1201447.D
1,4-Dichlorobenzene1,2,4-TrimethylbenzeneStyreneo-Xylenem-/p-XylenesChlorobenzene-d5 (IS),I2-Hexanone (Methyl butyl ketone)TetrachloroetheneToluene1,4-Difluorobenzene (IS),IChloroformBromochloromethane (IS),IEthyl acetateMethyl ethyl ketone (2-Butanone)HexaneMethylene chlorideAcetonitrileCarbon disulfideIsopropyl alcoholAcetoneEthanolL1201447.D L062912C.M Wed Jul 11 12:01:07 2012 Page 3
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201447.D Vial: 2
Acq On : 3 Jul 2012 5:49 pm Operator: DB
Sample : TO15-Tyner St.-V-1-Can #00206 LD Inst : Lurch
Misc : 0612-142, 500mL load Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 11:56 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) Bromochloromethane (IS) 13.06 130 533672 11.03 PPBV -0.02
36) 1,4-Difluorobenzene (IS) 14.86 114 2044908 10.52 PPBV -0.02
48) Chlorobenzene-d5 (IS) 19.07 117 1862098 11.20 PPBV 0.00
Target Compounds Qvalue
2) Propylene 0.00 41 0 N.D. d
3) Freon 12 (CCl2F2) 4.79 85 33733 N.D.
4) Freon 114 (C2Cl2F4) 0.00 85 0 N.D. d
5) Chloromethane 0.00 50 0 N.D. d
6) Chloroethene (Vinyl chlori 0.00 62 0 N.D.
7) 1,3-Butadiene 0.00 39 0 N.D. d
8) Bromomethane 0.00 94 0 N.D.
9) Chloroethane 0.00 64 0 N.D.
10) Bromoethene (Vinyl bromide 0.00 106 0 N.D.
11) Freon 11 (CCl3F) 0.00 101 0 N.D. d
12) Ethanol 7.86 45 109163 5.14 PPBV # 75
13) Acrolein 0.00 56 0 N.D. d
14) Freon 113 (C2Cl3F3) 0.00 151 0 N.D. d
15) 1,1-Dichloroethene 0.00 61 0 N.D.
16) Acetone 8.75 43 1444026 11.72 PPBV # 79
17) Carbon disulfide 9.16 76 49043 0.29 PPBV # 63
18) Isopropyl alcohol 9.10 45 208958 1.65 PPBV # 85
19) Allyl chloride (3-chloropr 0.00 76 0 N.D.
20) Acetonitrile 9.36 41 17482 0.28 PPBV # 81
21) Methylene chloride 9.79 49 44561 0.47 PPBV # 77
22) trans-1,2-Dichloroethene 0.00 61 0 N.D.
23) Methyl tert-butyl ether 0.00 73 0 N.D. d
24) Acrylonitrile 0.00 53 0 N.D. d
25) Hexane 11.04 57 22823 0.26 PPBV # 81
26) 1,1-Dichloroethane 0.00 63 0 N.D.
27) Vinyl acetate 0.00 43 0 N.D. d
28) cis-1,2-Dichloroethylene 0.00 61 0 N.D. d
29) Methyl ethyl ketone (2-But 12.56 72 48654 1.73 PPBV 73
30) Ethyl acetate 12.65 45 39961 1.62 PPBV # 82
31) Chloroform 13.24 83 53069 0.41 PPBV 96
32) Tetrahydrofuran 0.00 72 0 N.D. d
33) 1,1,1-Trichloroethane 0.00 97 0 N.D.
34) Cyclohexane 0.00 56 0 N.D. d
35) Carbon tetrachloride 0.00 117 0 N.D. d
37) Benzene 0.00 78 0 N.D. d
38) 2,2,4-trimethylpentane 0.00 57 0 N.D. d
39) 1,2-Dichloroethane 0.00 62 0 N.D.
40) Heptane 0.00 57 0 N.D. d
41) Trichloroethene 0.00 130 0 N.D. d
42) 1,2-Dichloropropane 0.00 63 0 N.D.
43) Methyl methacrylate 0.00 69 0 N.D. d
44) 1,4-Dioxane 0.00 88 0 N.D.
45) Bromodichloromethane 0.00 83 0 N.D. d
46) cis-1,3-Dichloropropene 0.00 75 0 N.D.
47) Methyl isobutyl ketone 0.00 43 0 N.D. d
49) Toluene 17.40 91 133048 0.71 PPBV 97
50) trans-1,3-Dichloropropene 0.00 75 0 N.D. d
51) 1,1,2-Trichloroethane 0.00 97 0 N.D. d
52) Tetrachloroethene 18.10 166 1232794 12.71 PPBV 96
53) 2-Hexanone (Methyl butyl k 18.19 43 107079 0.63 PPBV # 92
54) Dibromochloromethane 0.00 129 0 N.D. d
55) 1,2-Dibromoethane 0.00 107 0 N.D.
56) Chlorobenzene 0.00 112 0 N.D. d
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201447.D L062912C.M Wed Jul 11 12:01:07 2012 Page 1
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201447.D Vial: 2
Acq On : 3 Jul 2012 5:49 pm Operator: DB
Sample : TO15-Tyner St.-V-1-Can #00206 LD Inst : Lurch
Misc : 0612-142, 500mL load Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 11:56 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Compound R.T. QIon Response Conc Unit Qvalue
-------------------------------------------------------------------------
57) Ethylbenzene 0.00 91 0 N.D. d
58) 1,1,1,2-Tetrachloroethane 0.00 131 0 N.D.
59) m-/p-Xylenes 19.30 91 95704 0.52 PPBV 96
60) o-Xylene 19.69 91 43316 0.23 PPBV 94
61) Styrene 19.71 104 41101 0.27 PPBV 90
62) Bromoform 0.00 173 0 N.D.
63) 1,1,2,2-Tetrachloroethane 0.00 83 0 N.D. d
64) 4-Ethyltoluene 0.00 105 0 N.D. d
65) 2-Chlorotoluene 0.00 91 0 N.D. d
66) 1,3,5-Trimethylbenzene 0.00 105 0 N.D. d
67) 1,2,4-Trimethylbenzene 20.83 105 84249 0.41 PPBV # 80
68) 1,3-Dichlorobenzene 0.00 146 0 N.D. d
69) 1,4-Dichlorobenzene 21.18 146 74324m 0.51 PPBV
70) Benzyl chloride 0.00 91 0 N.D. d
71) 1,2-Dichlorobenzene 0.00 146 0 N.D.
72) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. d
73) Hexachlorobutadiene 0.00 225 0 N.D.
74) Naphthalene 0.00 128 0 N.D. d
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201447.D L062912C.M Wed Jul 11 12:01:07 2012 Page 2
#12
Ethanol
Concen: 5.14 PPBV
RT: 7.86 min Scan# 479
Delta R.T. -0.02 min
Lab File: L1201447.D
Acq: 3 Jul 2012 5:49 pm
Tgt Ion: 45 Resp: 109163
Ion Ratio Lower Upper
45 100
43 21.5 31.3 46.9#
31 219.0 209.9 314.9
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 512 (8.184 min): L1103939.D (-)
31
7854 200106 220 247133 278 299153172
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 479 (7.858 min): L1201447.D
31
55 20794133 16173 185 260 281299112
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 479 (7.858 min): L1201447.D (-)
31
263112 2962146013379154 175
7.70 7.80 7.90 8.00
0
20000
40000
60000
80000
100000
Time-->
AbundanceIon 44.95 (44.65 to 45.65): L12
7.86
Ion 42.95 (42.65 to 43.65): L12
Ion 30.95 (30.65 to 31.65): L12
#16
Acetone
Concen: 11.72 PPBV
RT: 8.75 min Scan# 568
Delta R.T. -0.02 min
Lab File: L1201447.D
Acq: 3 Jul 2012 5:49 pm
Tgt Ion: 43 Resp: 1444026
Ion Ratio Lower Upper
43 100
58 24.1 12.2 18.4#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 572 (8.797 min): L1200822.D (-)
43
168128 2947622119397147254
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 568 (8.753 min): L1201447.D
43
88 112 134 155 26964183 207226
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 568 (8.753 min): L1201447.D (-)
43
91 112 134 155 17967 208 233 265
8.60 8.70 8.80 8.90 9.00
0
100000
200000
300000
400000
500000
Time-->
AbundanceIon 43.00 (42.70 to 43.70): L12
8.75
Ion 58.00 (57.70 to 58.70): L12
L1201447.D L062912C.M Wed Jul 11 12:01:27 2012 Page 3
#17
Carbon disulfide
Concen: 0.29 PPBV
RT: 9.16 min Scan# 608
Delta R.T. -0.02 min
Lab File: L1201447.D
Acq: 3 Jul 2012 5:49 pm
Tgt Ion: 76 Resp: 49043
Ion Ratio Lower Upper
76 100
78 9.5 8.0 12.0
44 0.0 21.0 31.4#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 641 (9.481 min): L1103939.D (-)
76
45
196 239 26628621596 116 152171
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 608 (9.156 min): L1201447.D
76
32
58 94 207118 267285
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 608 (9.156 min): L1201447.D (-)
76
44
118 26728597208
9.00 9.10 9.20
0
5000
10000
15000
20000
Time-->
AbundanceIon 76.00 (75.70 to 76.70): L12
9.16
Ion 78.00 (77.70 to 78.70): L12
Ion 44.10 (43.80 to 44.80): L12
#18
Isopropyl alcohol
Concen: 1.65 PPBV
RT: 9.10 min Scan# 602
Delta R.T. -0.03 min
Lab File: L1201447.D
Acq: 3 Jul 2012 5:49 pm
Tgt Ion: 45 Resp: 208958
Ion Ratio Lower Upper
45 100
43 18.3 21.4 32.2#
59 3.6 2.5 3.7
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 641 (9.481 min): L1103939.D (-)
45
77 266116286152171 19221197 243
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 602 (9.095 min): L1201447.D
45
20773 94 127
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 602 (9.095 min): L1201447.D (-)
45
73 94 207
9.00 9.10 9.20 9.30
0
20000
40000
60000
80000
Time-->
AbundanceIon 45.00 (44.70 to 45.70): L12
9.10
Ion 43.10 (42.80 to 43.80): L12Ion 59.00 (58.70 to 59.70): L12
L1201447.D L062912C.M Wed Jul 11 12:01:27 2012 Page 4
#20
Acetonitrile
Concen: 0.28 PPBV
RT: 9.36 min Scan# 628
Delta R.T. -0.03 min
Lab File: L1201447.D
Acq: 3 Jul 2012 5:49 pm
Tgt Ion: 41 Resp: 17482
Ion Ratio Lower Upper
41 100
40 53.9 51.7 77.5
39 29.9 25.2 37.8
38 0.0 21.7 32.5#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 668 (9.752 min): L1103939.D (-)
41
97 17112869 195214 245 281147
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 628 (9.357 min): L1201447.D
32
58 207143 174111 28476
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 628 (9.357 min): L1201447.D (-)
41
69 185107 210 283143
9.20 9.30 9.40 9.50
0
2000
4000
6000
8000
Time-->
AbundanceIon 40.95 (40.65 to 41.65): L12
9.36
Ion 40.00 (39.70 to 40.70): L12
Ion 38.90 (38.60 to 39.60): L12
Ion 37.90 (37.60 to 38.60): L12
#21
Methylene chloride
Concen: 0.47 PPBV
RT: 9.79 min Scan# 671
Delta R.T. -0.02 min
Lab File: L1201447.D
Acq: 3 Jul 2012 5:49 pm
Tgt Ion: 49 Resp: 44561
Ion Ratio Lower Upper
49 100
84 62.7 66.8 100.2#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 675 (9.833 min): L1200822.D (-)
49 84
109 142 207 248 27822429
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 671 (9.789 min): L1201447.D
49
84
32
207131 228
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 671 (9.789 min): L1201447.D (-)
49
84
29 131 228207
9.70 9.80 9.90
0
5000
10000
15000
Time-->
AbundanceIon 49.05 (48.75 to 49.75): L12
9.79
Ion 84.00 (83.70 to 84.70): L12
L1201447.D L062912C.M Wed Jul 11 12:01:27 2012 Page 5
#25
Hexane
Concen: 0.26 PPBV
RT: 11.04 min Scan# 795
Delta R.T. -0.02 min
Lab File: L1201447.D
Acq: 3 Jul 2012 5:49 pm
Tgt Ion: 57 Resp: 22823
Ion Ratio Lower Upper
57 100
41 99.6 95.8 143.8
43 80.9 52.1 78.1#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 833 (11.411 min): L1103939.D (-)
41
86
65 173 196 216 248267 287110 153129
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 795 (11.036 min): L1201447.D
32 57
86
207 248111 288139 167185
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 795 (11.036 min): L1201447.D (-)
57
29
86
213 281117 139 248163181
10.90 11.00 11.10
0
2000
4000
6000
8000
Time-->
AbundanceIon 57.10 (56.80 to 57.80): L12
11.04
Ion 41.10 (40.80 to 41.80): L12
Ion 43.10 (42.80 to 43.80): L12
#29
Methyl ethyl ketone (2-Butanone)
Concen: 1.73 PPBV
RT: 12.56 min Scan# 946
Delta R.T. -0.02 min
Lab File: L1201447.D
Acq: 3 Jul 2012 5:49 pm
Tgt Ion: 72 Resp: 48654
Ion Ratio Lower Upper
72 100
43 606.7 420.9 631.3
57 36.1 32.6 48.8
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 984 (12.929 min): L1103939.D
43
72
96 123 143 162 182 201 226 254 273
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 946 (12.555 min): L1201447.D
43
72
106123 148 173 207 226 251 279
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 946 (12.555 min): L1201447.D (-)
43
72
117 148 176 207 226 28396251
12.40 12.50 12.60 12.70
0
50000
100000
Time-->
AbundanceIon 72.00 (71.70 to 72.70): L12
12.56
Ion 43.00 (42.70 to 43.70): L12Ion 57.00 (56.70 to 57.70): L12
L1201447.D L062912C.M Wed Jul 11 12:01:28 2012 Page 6
#30
Ethyl acetate
Concen: 1.62 PPBV
RT: 12.65 min Scan# 955
Delta R.T. -0.02 min
Lab File: L1201447.D
Acq: 3 Jul 2012 5:49 pm
Tgt Ion: 45 Resp: 39961
Ion Ratio Lower Upper
45 100
61 75.0 0.0 0.0#
88 28.2 27.6 41.4
70 57.6 60.6 90.8#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 994 (13.030 min): L1103939.D (-)
43
70 88 202 238116 261 288139159
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 955 (12.646 min): L1201447.D
43
61 88 177 207 298241 262
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 955 (12.646 min): L1201447.D (-)
43
61 88 181 209 241 262 283
12.60 12.70
0
5000
10000
15000
20000
Time-->
AbundanceIon 45.00 (44.70 to 45.70): L12
12.65
Ion 61.00 (60.70 to 61.70): L12
Ion 88.00 (87.70 to 88.70): L12
Ion 70.00 (69.70 to 70.70): L12
#31
Chloroform
Concen: 0.41 PPBV
RT: 13.24 min Scan# 1014
Delta R.T. -0.02 min
Lab File: L1201447.D
Acq: 3 Jul 2012 5:49 pm
Tgt Ion: 83 Resp: 53069
Ion Ratio Lower Upper
83 100
85 68.3 52.3 78.5
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1052 (13.613 min): L1103939.D (-)
83
47
120 200 224 252 275294141 161180102
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1014 (13.239 min): L1201447.D
83
32
50 118 278146 167 188207 239
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1014 (13.239 min): L1201447.D (-)
83
121 146 167 188 2822395731207
13.10 13.20 13.30
0
5000
10000
15000
20000
Time-->
AbundanceIon 83.00 (82.70 to 83.70): L12
13.24
Ion 85.00 (84.70 to 85.70): L12
L1201447.D L062912C.M Wed Jul 11 12:01:28 2012 Page 7
#49
Toluene
Concen: 0.71 PPBV
RT: 17.40 min Scan# 1428
Delta R.T. -0.01 min
Lab File: L1201447.D
Acq: 3 Jul 2012 5:49 pm
Tgt Ion: 91 Resp: 133048
Ion Ratio Lower Upper
91 100
92 62.8 48.2 72.4
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1459 (17.705 min): L1103939.D (-)
91
39 65 135 162180 205 244 280110
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1428 (17.403 min): L1201447.D
91
43 65 112 226 258276207 297143
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1428 (17.403 min): L1201447.D (-)
91
39 65 112 230 258276 297143 191
17.30 17.40 17.50
0
20000
40000
60000
Time-->
AbundanceIon 91.10 (90.80 to 91.80): L12
17.40
Ion 92.10 (91.80 to 92.80): L12
#52
Tetrachloroethene
Concen: 12.71 PPBV
RT: 18.10 min Scan# 1497
Delta R.T. -0.01 min
Lab File: L1201447.D
Acq: 3 Jul 2012 5:49 pm
Tgt Ion:166 Resp: 1232794
Ion Ratio Lower Upper
166 100
164 78.6 63.0 94.6
131 66.7 59.0 88.4
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1526 (18.379 min): L1103939.D (-)
166
131
94
47
18820765 232 252 275295
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1497 (18.097 min): L1201447.D
166
129
9447
68 184 207 296261
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1497 (18.097 min): L1201447.D (-)
166
129
9447
184 207 261 29665
18.00 18.20
0
200000
400000
600000
800000
Time-->
AbundanceIon 165.90 (165.60 to 166.60):
18.10
Ion 163.90 (163.60 to 164.60): Ion 130.90 (130.60 to 131.60):
L1201447.D L062912C.M Wed Jul 11 12:01:29 2012 Page 8
#53
2-Hexanone (Methyl butyl ketone)
Concen: 0.63 PPBV
RT: 18.19 min Scan# 1506
Delta R.T. -0.01 min
Lab File: L1201447.D
Acq: 3 Jul 2012 5:49 pm
Tgt Ion: 43 Resp: 107079
Ion Ratio Lower Upper
43 100
58 46.8 33.7 50.5
57 15.9 15.2 22.8
100 9.1 10.4 15.6#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1535 (18.469 min): L1103939.D (-)
43
10071 176 212 235 255 282118 157137
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1506 (18.188 min): L1201447.D
43
10071 281207133 166 245
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1506 (18.188 min): L1201447.D (-)
43
10071 281133 166 218193 249
18.10 18.20 18.30
0
50000
100000
Time-->
AbundanceIon 43.00 (42.70 to 43.70): L12
18.19
Ion 58.00 (57.70 to 58.70): L12
Ion 57.10 (56.80 to 57.80): L12
Ion 100.00 (99.70 to 100.70): L
#59
m-/p-Xylenes
Concen: 0.52 PPBV
RT: 19.30 min Scan# 1617
Delta R.T. -0.02 min
Lab File: L1201447.D
Acq: 3 Jul 2012 5:49 pm
Tgt Ion: 91 Resp: 95704
Ion Ratio Lower Upper
91 100
106 51.8 39.3 58.9
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1647 (19.595 min): L1103939.D (-)
91
39 65 109 128145 176 203 235 262281
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1617 (19.304 min): L1201447.D
43 91
70
128111 207163 190 233 257
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1617 (19.304 min): L1201447.D (-)
9143
70
128111 190208 233 257163
19.20 19.30 19.40
0
20000
40000
Time-->
AbundanceIon 91.10 (90.80 to 91.80): L12
19.30
Ion 106.05 (105.75 to 106.75):
L1201447.D L062912C.M Wed Jul 11 12:01:29 2012 Page 9
#60
o-Xylene
Concen: 0.23 PPBV
RT: 19.69 min Scan# 1655
Delta R.T. -0.01 min
Lab File: L1201447.D
Acq: 3 Jul 2012 5:49 pm
Tgt Ion: 91 Resp: 43316
Ion Ratio Lower Upper
91 100
106 49.8 36.8 55.2
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1686 (19.988 min): L1103939.D (-)
91
39 65 245 276115 147 166 186205 226
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1655 (19.686 min): L1201447.D
91
32 51
69 207111133 232 260163 281
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1655 (19.686 min): L1201447.D (-)
91
51
29 69 111 140 232209163 191 260 281
19.60 19.70
0
10000
20000
30000
Time-->
AbundanceIon 91.10 (90.80 to 91.80): L12
19.69
Ion 106.10 (105.80 to 106.80):
#61
Styrene
Concen: 0.27 PPBV
RT: 19.71 min Scan# 1657
Delta R.T. -0.01 min
Lab File: L1201447.D
Acq: 3 Jul 2012 5:49 pm
Tgt Ion:104 Resp: 41101
Ion Ratio Lower Upper
104 100
78 48.5 46.2 69.2
103 49.9 44.0 66.0
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1688 (20.008 min): L1103939.D (-)
104
78
51
131 166 202221 241260 280
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1657 (19.706 min): L1201447.D
104
785132
207126165 232 260 281
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1657 (19.706 min): L1201447.D (-)
104
7851
126 165 193 232 28130
19.60 19.70 19.80
0
10000
20000
30000
Time-->
AbundanceIon 104.10 (103.80 to 104.80):
19.71
Ion 78.10 (77.80 to 78.80): L12Ion 103.10 (102.80 to 103.80):
L1201447.D L062912C.M Wed Jul 11 12:01:29 2012 Page 10
#67
1,2,4-Trimethylbenzene
Concen: 0.41 PPBV
RT: 20.83 min Scan# 1769
Delta R.T. -0.01 min
Lab File: L1201447.D
Acq: 3 Jul 2012 5:49 pm
Tgt Ion:105 Resp: 84249
Ion Ratio Lower Upper
105 100
120 34.1 37.8 56.6#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1803 (21.164 min): L1103939.D (-)
105
773958 299126 146165 189209 233252271
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1769 (20.833 min): L1201447.D
105
43 69
139 20787 260 281163 232
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 1769 (20.833 min): L1201447.D (-)
105
7751 139 207 267163 23232
20.70 20.80 20.90
0
10000
20000
30000
40000
Time-->
AbundanceIon 105.10 (104.80 to 105.80):
20.83
Ion 120.15 (119.85 to 120.85):
#69
1,4-Dichlorobenzene
Concen: 0.51 PPBV m
RT: 21.18 min Scan# 1804
Delta R.T. -0.01 min
Lab File: L1201447.D
Acq: 3 Jul 2012 5:49 pm
Tgt Ion:146 Resp: 74324
Ion Ratio Lower Upper
146 100
148 64.0 51.8 77.8
111 63.6 27.9 41.9#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1840 (21.536 min): L1103939.D (-)
146
1117550
27931165 185 205 224 244
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1804 (21.185 min): L1201447.D
57
29 11385 148 232 281209 260168 191
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 1804 (21.185 min): L1201447.D (-)
57
113
29 14683 168 208 233 260 289
21.15 21.20 21.25
0
20000
40000
60000
Time-->
AbundanceIon 146.00 (145.70 to 146.70):
21.18
Ion 148.00 (147.70 to 148.70): Ion 111.10 (110.80 to 111.80):
L1201447.D L062912C.M Wed Jul 11 12:01:30 2012 Page 11
Quantitation Report
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201440.D Vial: 1
Acq On : 3 Jul 2012 12:17 pm Operator: DB
Sample : humid blank Inst : Lurch
Misc : 500mL load, can #10893 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 10:52 2012 Quant Results File: L062912C.RES
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00
0
500000
1000000
1500000
2000000
2500000
3000000
3500000
4000000
4500000
5000000
5500000
6000000
6500000
7000000
Time-->
Abundance TIC: L1201440.D
Chlorobenzene-d5 (IS),I1,4-Difluorobenzene (IS),IBromochloromethane (IS),IMethylene chlorideAcetoneEthanolL1201440.D L062912C.M Wed Jul 11 10:53:07 2012 Page 3
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201440.D Vial: 1
Acq On : 3 Jul 2012 12:17 pm Operator: DB
Sample : humid blank Inst : Lurch
Misc : 500mL load, can #10893 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 10:52 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) Bromochloromethane (IS) 13.05 130 495375 11.03 PPBV -0.02
36) 1,4-Difluorobenzene (IS) 14.85 114 1927918 10.52 PPBV -0.02
48) Chlorobenzene-d5 (IS) 19.07 117 1837448 11.20 PPBV -0.01
Target Compounds Qvalue
2) Propylene 0.00 41 0 N.D. d
3) Freon 12 (CCl2F2) 0.00 85 0 N.D. d
4) Freon 114 (C2Cl2F4) 0.00 85 0 N.D. d
5) Chloromethane 0.00 50 0 N.D. d
6) Chloroethene (Vinyl chlori 0.00 62 0 N.D. d
7) 1,3-Butadiene 0.00 39 0 N.D. d
8) Bromomethane 0.00 94 0 N.D. d
9) Chloroethane 0.00 64 0 N.D. d
10) Bromoethene (Vinyl bromide 0.00 106 0 N.D. d
11) Freon 11 (CCl3F) 0.00 101 0 N.D. d
12) Ethanol 7.84 45 7253 0.37 PPBV # 84
13) Acrolein 0.00 56 0 N.D. d
14) Freon 113 (C2Cl3F3) 0.00 151 0 N.D. d
15) 1,1-Dichloroethene 0.00 61 0 N.D. d
16) Acetone 8.76 43 27653 0.24 PPBV # 61
17) Carbon disulfide 0.00 76 0 N.D. d
18) Isopropyl alcohol 0.00 45 0 N.D. d
19) Allyl chloride (3-chloropr 0.00 76 0 N.D. d
20) Acetonitrile 0.00 41 0 N.D. d
21) Methylene chloride 9.77 49 30514 0.35 PPBV # 74
22) trans-1,2-Dichloroethene 0.00 61 0 N.D. d
23) Methyl tert-butyl ether 0.00 73 0 N.D. d
24) Acrylonitrile 0.00 53 0 N.D. d
25) Hexane 0.00 57 0 N.D. d
26) 1,1-Dichloroethane 0.00 63 0 N.D. d
27) Vinyl acetate 0.00 43 0 N.D. d
28) cis-1,2-Dichloroethylene 0.00 61 0 N.D. d
29) Methyl ethyl ketone (2-But 0.00 72 0 N.D. d
30) Ethyl acetate 0.00 45 0 N.D. d
31) Chloroform 0.00 83 0 N.D. d
32) Tetrahydrofuran 0.00 72 0 N.D. d
33) 1,1,1-Trichloroethane 0.00 97 0 N.D. d
34) Cyclohexane 0.00 56 0 N.D. d
35) Carbon tetrachloride 0.00 117 0 N.D. d
37) Benzene 0.00 78 0 N.D. d
38) 2,2,4-trimethylpentane 0.00 57 0 N.D. d
39) 1,2-Dichloroethane 0.00 62 0 N.D. d
40) Heptane 0.00 57 0 N.D. d
41) Trichloroethene 0.00 130 0 N.D. d
42) 1,2-Dichloropropane 0.00 63 0 N.D. d
43) Methyl methacrylate 0.00 69 0 N.D. d
44) 1,4-Dioxane 0.00 88 0 N.D. d
45) Bromodichloromethane 0.00 83 0 N.D. d
46) cis-1,3-Dichloropropene 0.00 75 0 N.D. d
47) Methyl isobutyl ketone 0.00 43 0 N.D. d
49) Toluene 0.00 91 0 N.D. d
50) trans-1,3-Dichloropropene 0.00 75 0 N.D. d
51) 1,1,2-Trichloroethane 0.00 97 0 N.D. d
52) Tetrachloroethene 0.00 166 0 N.D. d
53) 2-Hexanone (Methyl butyl k 0.00 43 0 N.D. d
54) Dibromochloromethane 0.00 129 0 N.D. d
55) 1,2-Dibromoethane 0.00 107 0 N.D. d
56) Chlorobenzene 0.00 112 0 N.D. d
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201440.D L062912C.M Wed Jul 11 10:53:07 2012 Page 1
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201440.D Vial: 1
Acq On : 3 Jul 2012 12:17 pm Operator: DB
Sample : humid blank Inst : Lurch
Misc : 500mL load, can #10893 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 10:52 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Compound R.T. QIon Response Conc Unit Qvalue
-------------------------------------------------------------------------
57) Ethylbenzene 0.00 91 0 N.D. d
58) 1,1,1,2-Tetrachloroethane 0.00 131 0 N.D. d
59) m-/p-Xylenes 0.00 91 0 N.D. d
60) o-Xylene 0.00 91 0 N.D. d
61) Styrene 0.00 104 0 N.D. d
62) Bromoform 0.00 173 0 N.D. d
63) 1,1,2,2-Tetrachloroethane 0.00 83 0 N.D. d
64) 4-Ethyltoluene 0.00 105 0 N.D. d
65) 2-Chlorotoluene 0.00 91 0 N.D. d
66) 1,3,5-Trimethylbenzene 0.00 105 0 N.D. d
67) 1,2,4-Trimethylbenzene 0.00 105 0 N.D. d
68) 1,3-Dichlorobenzene 0.00 146 0 N.D. d
69) 1,4-Dichlorobenzene 0.00 146 0 N.D. d
70) Benzyl chloride 0.00 91 0 N.D. d
71) 1,2-Dichlorobenzene 0.00 146 0 N.D. d
72) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. d
73) Hexachlorobutadiene 0.00 225 0 N.D. d
74) Naphthalene 0.00 128 0 N.D. d
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201440.D L062912C.M Wed Jul 11 10:53:07 2012 Page 2
#12
Ethanol
Concen: 0.37 PPBV
RT: 7.84 min Scan# 477
Delta R.T. -0.03 min
Lab File: L1201440.D
Acq: 3 Jul 2012 12:17 pm
Tgt Ion: 45 Resp: 7253
Ion Ratio Lower Upper
45 100
43 55.8 31.3 46.9#
31 235.8 209.9 314.9
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 512 (8.184 min): L1103939.D (-)
31
7854 200106 220 247133 278 299153172
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 477 (7.843 min): L1201440.D
32
55 94 171 20714273 121 237257 290
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 477 (7.843 min): L1201440.D (-)
31
139 17155 11180 199 237 261 290
7.75 7.80 7.85 7.90 7.95
0
2000
4000
6000
8000
Time-->
AbundanceIon 44.95 (44.65 to 45.65): L12
7.84
Ion 42.95 (42.65 to 43.65): L12
Ion 30.95 (30.65 to 31.65): L12
#16
Acetone
Concen: 0.24 PPBV
RT: 8.76 min Scan# 568
Delta R.T. -0.01 min
Lab File: L1201440.D
Acq: 3 Jul 2012 12:17 pm
Tgt Ion: 43 Resp: 27653
Ion Ratio Lower Upper
43 100
58 31.8 12.2 18.4#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 572 (8.797 min): L1200822.D (-)
43
168128 2947622119397147254
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 568 (8.759 min): L1201440.D
43
20794 256114 135 170
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
0
50
m/z-->
Abundance Scan 568 (8.759 min): L1201440.D (-)
43
107 135 207170 25679
8.60 8.70 8.80
0
5000
10000
Time-->
AbundanceIon 43.00 (42.70 to 43.70): L12
8.76
Ion 58.00 (57.70 to 58.70): L12
L1201440.D L062912C.M Wed Jul 11 10:53:24 2012 Page 3
#21
Methylene chloride
Concen: 0.35 PPBV
RT: 9.77 min Scan# 669
Delta R.T. -0.03 min
Lab File: L1201440.D
Acq: 3 Jul 2012 12:17 pm
Tgt Ion: 49 Resp: 30514
Ion Ratio Lower Upper
49 100
84 60.2 66.8 100.2#
Ref
Raw
Sub
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 675 (9.833 min): L1200822.D (-)
49 84
109 142 207 248 27822829
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 669 (9.774 min): L1201440.D
49
84
114 185 209142 248 26928716031
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
50
m/z-->
Abundance Scan 669 (9.774 min): L1201440.D (-)
49
84
114 241135 185 205 259 283153
9.60 9.70 9.80 9.90
0
5000
10000
Time-->
AbundanceIon 49.05 (48.75 to 49.75): L12
9.77
Ion 84.00 (83.70 to 84.70): L12
L1201440.D L062912C.M Wed Jul 11 10:53:24 2012 Page 4
Quantitation Report
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201439.D Vial: 1
Acq On : 3 Jul 2012 11:28 am Operator: DB
Sample : 8.25ppbv TO-15 LCS std Inst : Lurch
Misc : 125mL load, can #1414 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 10:50 2012 Quant Results File: L062912C.RES
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00
0
500000
1000000
1500000
2000000
2500000
3000000
3500000
4000000
4500000
5000000
5500000
6000000
6500000
7000000
7500000
8000000
Time-->
Abundance TIC: L1201439.D
NaphthaleneHexachlorobutadiene1,2,4-Trichlorobenzene1,2-DichlorobenzeneBenzyl chloride1,4-Dichlorobenzene1,3-Dichlorobenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene2-Chlorotoluene4-Ethyltoluene1,1,2,2-TetrachloroethaneBromoformStyreneo-Xylenem-/p-Xylenes1,1,1,2-TetrachloroethaneEthylbenzeneChlorobenzeneChlorobenzene-d5 (IS),I1,2-DibromoethaneDibromochloromethane2-Hexanone (Methyl butyl ketone)Tetrachloroethene1,1,2-Trichloroethanetrans-1,3-DichloropropeneTolueneMethyl isobutyl ketonecis-1,3-DichloropropeneBromodichloromethane1,4-DioxaneMethyl methacrylate1,2-DichloropropaneTrichloroethene1,4-Difluorobenzene (IS),IHeptane2,2,4-trimethylpentane1,2-DichloroethaneBenzeneCarbon tetrachlorideCyclohexane1,1,1-TrichloroethaneChloroformTetrahydrofuranBromochloromethane (IS),IEthyl acetatecis-1,2-DichloroethyleneMethyl ethyl ketone (2-Butanone)1,1-DichloroethaneVinyl acetateHexanetrans-1,2-DichloroetheneMethyl tert-butyl etherAcrylonitrileMethylene chlorideAllyl chloride (3-chloropropene)AcetonitrileCarbon disulfideIsopropyl alcoholAcetoneFreon 113 (C2Cl3F3)1,1-DichloroetheneAcroleinEthanolFreon 11 (CCl3F)Bromoethene (Vinyl bromide)ChloroethaneBromomethane1,3-ButadieneChloroethene (Vinyl chloride)ChloromethaneFreon 114 (C2Cl2F4)Freon 12 (CCl2F2)PropyleneL1201439.D L062912C.M Wed Jul 11 10:50:51 2012 Page 3
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201439.D Vial: 1
Acq On : 3 Jul 2012 11:28 am Operator: DB
Sample : 8.25ppbv TO-15 LCS std Inst : Lurch
Misc : 125mL load, can #1414 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 10:50 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) Bromochloromethane (IS) 13.05 130 471063 11.03 PPBV -0.03
36) 1,4-Difluorobenzene (IS) 14.85 114 1817409 10.52 PPBV -0.03
48) Chlorobenzene-d5 (IS) 19.06 117 1830096 11.20 PPBV -0.02
Target Compounds Qvalue
2) Propylene 4.68 41 510680 9.33 PPBV # 71
3) Freon 12 (CCl2F2) 4.78 85 1253461 8.22 PPBV 97
4) Freon 114 (C2Cl2F4) 5.15 85 1400512 8.49 PPBV # 93
5) Chloromethane 5.27 50 524538 8.77 PPBV 98
6) Chloroethene (Vinyl chlori 5.60 62 493049 8.82 PPBV 100
7) 1,3-Butadiene 5.72 39 473255 9.27 PPBV 89
8) Bromomethane 6.47 94 522505 8.33 PPBV 99
9) Chloroethane 6.76 64 258353 8.46 PPBV 99
10) Bromoethene (Vinyl bromide 7.23 106 452817 7.87 PPBV # 96
11) Freon 11 (CCl3F) 7.41 101 1073328 8.39 PPBV 99
12) Ethanol 7.84 45 159496 8.51 PPBV # 84
13) Acrolein 8.41 56 164871 8.17 PPBV 94
14) Freon 113 (C2Cl3F3) 8.67 151 524587 7.50 PPBV 98
15) 1,1-Dichloroethene 8.63 61 649129 7.50 PPBV 90
16) Acetone 8.73 43 843497 7.76 PPBV # 83
17) Carbon disulfide 9.14 76 1183442 7.85 PPBV 92
18) Isopropyl alcohol 9.09 45 942091 8.44 PPBV # 86
19) Allyl chloride (3-chloropr 9.49 76 187209 7.84 PPBV # 48
20) Acetonitrile 9.35 41 396518 7.18 PPBV # 83
21) Methylene chloride 9.77 49 615059 7.39 PPBV # 78
22) trans-1,2-Dichloroethene 10.39 61 619258 7.83 PPBV 98
23) Methyl tert-butyl ether 10.39 73 1111669 8.16 PPBV # 86
24) Acrylonitrile 10.28 53 335816 7.69 PPBV # 89
25) Hexane 11.02 57 627509 8.05 PPBV # 78
26) 1,1-Dichloroethane 11.36 63 771155 8.05 PPBV 99
27) Vinyl acetate 11.36 43 1619125 8.55 PPBV 96
28) cis-1,2-Dichloroethylene 12.58 61 750744 8.13 PPBV 94
29) Methyl ethyl ketone (2-But 12.55 72 211668 8.54 PPBV 79
30) Ethyl acetate 12.64 45 181971 8.37 PPBV # 82
31) Chloroform 13.23 83 913303 8.01 PPBV 98
32) Tetrahydrofuran 13.09 72 203083 8.35 PPBV # 57
33) 1,1,1-Trichloroethane 13.56 97 888178 7.86 PPBV 95
34) Cyclohexane 13.70 56 670311 8.17 PPBV # 79
35) Carbon tetrachloride 13.84 117 892404 7.78 PPBV 97
37) Benzene 14.18 78 1209655 7.88 PPBV # 94
38) 2,2,4-trimethylpentane 14.37 57 2042453 7.87 PPBV # 80
39) 1,2-Dichloroethane 14.26 62 607177 7.90 PPBV 98
40) Heptane 14.64 57 417493 8.23 PPBV # 89
41) Trichloroethene 15.23 130 606196 7.81 PPBV # 89
42) 1,2-Dichloropropane 15.64 63 492332 8.43 PPBV 94
43) Methyl methacrylate 15.68 69 481716 8.31 PPBV # 89
44) 1,4-Dioxane 15.74 88 296599 8.34 PPBV # 79
45) Bromodichloromethane 16.06 83 1078686 8.12 PPBV # 97
46) cis-1,3-Dichloropropene 16.79 75 835951 8.39 PPBV 98
47) Methyl isobutyl ketone 17.01 43 1484678 8.72 PPBV # 94
49) Toluene 17.39 91 1466015 7.91 PPBV 95
50) trans-1,3-Dichloropropene 17.69 75 747026 7.57 PPBV 98
51) 1,1,2-Trichloroethane 17.95 97 598888 7.98 PPBV 87
52) Tetrachloroethene 18.09 166 753145 7.90 PPBV 95
53) 2-Hexanone (Methyl butyl k 18.18 43 1475899 8.88 PPBV # 91
54) Dibromochloromethane 18.42 129 1127022 8.17 PPBV 99
55) 1,2-Dibromoethane 18.58 107 1010844 7.90 PPBV 97
56) Chlorobenzene 19.09 112 1288863 8.21 PPBV # 90
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201439.D L062912C.M Wed Jul 11 10:50:50 2012 Page 1
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201439.D Vial: 1
Acq On : 3 Jul 2012 11:28 am Operator: DB
Sample : 8.25ppbv TO-15 LCS std Inst : Lurch
Misc : 125mL load, can #1414 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 10:50 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Compound R.T. QIon Response Conc Unit Qvalue
-------------------------------------------------------------------------
57) Ethylbenzene 19.17 91 2069454 8.94 PPBV 100
58) 1,1,1,2-Tetrachloroethane 19.17 131 684191 7.77 PPBV 92
59) m-/p-Xylenes 19.30 91 3078792 17.16 PPBV 94
60) o-Xylene 19.68 91 1636087 8.91 PPBV 93
61) Styrene 19.70 104 1315482 8.71 PPBV 90
62) Bromoform 19.89 173 1031071 8.28 PPBV 98
63) 1,1,2,2-Tetrachloroethane 20.26 83 1422845 9.08 PPBV 98
64) 4-Ethyltoluene 20.46 105 2351680 9.19 PPBV 98
65) 2-Chlorotoluene 20.46 91 1990858 8.74 PPBV 97
66) 1,3,5-Trimethylbenzene 20.50 105 1678520 8.75 PPBV 96
67) 1,2,4-Trimethylbenzene 20.82 105 1786710 8.91 PPBV 97
68) 1,3-Dichlorobenzene 21.10 146 1254957 8.98 PPBV 97
69) 1,4-Dichlorobenzene 21.18 146 1253878 8.80 PPBV 98
70) Benzyl chloride 21.26 91 1802937 8.85 PPBV 94
71) 1,2-Dichlorobenzene 21.48 146 1150468 8.75 PPBV 98
72) 1,2,4-Trichlorobenzene 22.84 180 703181 7.83 PPBV 99
73) Hexachlorobutadiene 22.94 225 526553 8.62 PPBV 98
74) Naphthalene 23.12 128 1831947 7.41 PPBV # 79
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201439.D L062912C.M Wed Jul 11 10:50:51 2012 Page 2

Calibration
Curve Chromatograms

Sample ID LID FileName
0.4ppbv TO-15 std 0.66 L1201400.D
1.0ppbv TO-15 std 1.65 L1201401.D Inst: Lurch
2.0ppbv TO-15 std 3.3 L1201409.D
5ppbv TO-15 std 8.25 L1201404.D Curve: L062912C.M
10ppbv TO-15 std 16.5 L1201405.D
20ppbv TO-15 std 33 L1201406.D
30ppbv TO-15 std 49.5 L1201407.D
#Name
0.4ppbv TO-
15 std
1.0ppbv TO-
15 std
2.0ppbv TO-
15 std
5ppbv TO-
15 std
10ppbv TO-
15 std
20ppbv TO-
15 std
30ppbv TO-
15 std Average RF %RSD
2)Propylene 1.60 1.38 1.31 1.15 1.24 1.18 1.11 1.28 13.2%
3)Freon 12 (CCl2F2)4.13 3.74 3.76 3.31 3.58 3.35 3.12 3.57 9.58%
4)Freon 114 (C2Cl2F4)4.45 4.04 4.12 3.57 3.87 3.63 3.36 3.86 9.64%
5)Chloromethane 1.61 1.48 1.47 1.28 1.40 1.31 1.25 1.40 9.30%
6) Chloroethene (Vinyl chloride) 1.48 1.32 1.39 1.22 1.32 1.26 1.18 1.31 7.86%
7)1,3-Butadiene 1.34 1.27 1.26 1.11 1.20 1.12 1.06 1.19 8.59%
8)Bromomethane 1.67 1.52 1.55 1.37 1.46 1.40 1.32 1.47 8.15%
9)Chloroethane 0.821 0.731 0.747 0.669 0.706 0.679 0.654 0.715 8.03%
10) Bromoethene (Vinyl bromide) 1.55 1.40 1.43 1.24 1.33 1.27 1.21 1.35 8.97%
11)Freon 11 (CCl3F)3.48 3.25 3.16 2.77 2.96 2.77 2.56 3.00 10.7%
12)Ethanol 0.514 0.464 0.461 0.399 0.426 0.412 0.396 0.439 9.78%
13)Acrolein 0.470 0.445 0.467 0.459 0.500 0.488 0.477 0.472 3.87%
14)Freon 113 (C2Cl3F3)1.87 1.67 1.72 1.50 1.63 1.57 1.51 1.64 8.05%
15)1,1-Dichloroethene 2.28 1.98 2.16 1.90 2.04 1.95 1.87 2.03 7.30%
16)Acetone 3.54 2.44 2.59 2.29 2.42 2.32 2.23 2.55 17.8%
17)Carbon disulfide 3.98 3.60 3.77 3.24 3.51 3.37 3.23 3.53 7.89%
18)Isopropyl alcohol 3.06 2.68 2.76 2.44 2.62 2.42 2.31 2.61 9.77%
19) Allyl chloride (3-chloropropene) 0.620 0.570 0.586 0.515 0.557 0.541 0.523 0.559 6.61%
20)Acetonitrile 1.48 1.32 1.34 1.18 1.27 1.24 1.21 1.29 7.85%
21)Methylene chloride 2.84 2.10 1.99 1.66 1.77 1.67 1.60 1.95 22.3%
22) trans-1,2-Dichloroethene 2.07 1.92 1.99 1.70 1.85 1.77 1.68 1.85 7.88%
23)Methyl tert-butyl ether 3.53 3.29 3.38 2.93 3.19 3.08 2.93 3.19 7.13%
24)Acrylonitrile 1.13 1.02 1.09 0.938 1.02 1.00 0.967 1.02 6.49%
25)Hexane 2.12 1.89 1.92 1.67 1.80 1.73 1.65 1.83 9.04%
26)1,1-Dichloroethane 2.55 2.31 2.38 2.06 2.22 2.14 2.04 2.24 8.20%
27)Vinyl acetate 4.92 4.60 4.83 4.14 4.45 4.19 3.89 4.43 8.53%
28) cis-1,2-Dichloroethylene 2.44 2.22 2.28 1.98 2.15 2.07 1.98 2.16 7.78%
29) Methyl ethyl ketone (2-Butanone) 0.633 0.580 0.610 0.535 0.587 0.569 0.547 0.580 5.87%
30)Ethyl acetate 0.543 0.523 0.555 0.473 0.512 0.492 0.466 0.509 6.68%
31)Chloroform 2.98 2.75 2.82 2.45 2.67 2.57 2.45 2.67 7.38%
32)Tetrahydrofuran 0.607 0.573 0.608 0.523 0.576 0.558 0.544 0.570 5.47%
33)1,1,1-Trichloroethane 3.01 2.74 2.79 2.42 2.64 2.53 2.40 2.64 8.24%
34)Cyclohexane 2.15 1.98 2.05 1.77 1.92 1.85 1.74 1.92 7.78%
35)Carbon tetrachloride 3.02 2.82 2.82 2.47 2.68 2.57 2.42 2.69 8.10%
37)Benzene 0.961 0.914 0.953 0.817 0.898 0.866 0.808 0.888 6.85%
38)2,2,4-trimethylpentane 1.66 1.58 1.63 1.40 1.51 1.43 1.31 1.50 8.54%
39)1,2-Dichloroethane 0.493 0.459 0.462 0.415 0.443 0.434 0.408 0.445 6.55%
40)Heptane 0.317 0.304 0.316 0.275 0.297 0.285 0.264 0.294 6.91%
41)Trichloroethene 0.479 0.457 0.473 0.413 0.458 0.448 0.419 0.449 5.62%
42)1,2-Dichloropropane 0.364 0.349 0.365 0.313 0.344 0.328 0.305 0.338 7.06%
43)Methyl methacrylate 0.353 0.343 0.359 0.311 0.343 0.333 0.307 0.336 5.91%
44)1,4-Dioxane 0.228 0.212 0.214 0.184 0.205 0.204 0.198 0.206 6.64%
45)Bromodichloromethane 0.826 0.794 0.819 0.713 0.779 0.753 0.697 0.769 6.51%
46) cis-1,3-Dichloropropene 0.600 0.586 0.616 0.535 0.588 0.575 0.536 0.577 5.33%
47)Methyl isobutyl ketone 1.03 1.01 1.07 0.934 1.01 0.955 0.877 0.985 6.72%
49)Toluene 1.14 1.12 1.27 1.05 1.17 1.13 1.07 1.13 6.43%
50) trans-1,3-Dichloropropene 0.583 0.587 0.672 0.561 0.625 0.615 0.584 0.604 6.10%
51)1,1,2-Trichloroethane 0.453 0.445 0.515 0.430 0.472 0.462 0.437 0.459 6.18%
52)Tetrachloroethene 0.564 0.577 0.665 0.554 0.614 0.585 0.525 0.583 7.77%
53) 2-Hexanone (Methyl butyl ketone) 0.991 1.02 1.18 0.973 1.06 0.994 0.909 1.02 8.21%
54)Dibromochloromethane 0.829 0.838 0.958 0.799 0.876 0.842 0.767 0.844 7.21%
55)1,2-Dibromoethane 0.753 0.761 0.888 0.736 0.815 0.792 0.737 0.783 6.96%
56)Chlorobenzene 0.895 0.922 1.09 0.914 1.01 0.979 0.906 0.960 7.59%
57)Ethylbenzene 1.38 1.47 1.75 1.44 1.54 1.30 1.04 1.42 15.4%
58) 1,1,1,2-Tetrachloroethane 0.526 0.543 0.640 0.528 0.577 0.517 0.441 0.539 11.2%
59)m-/p-Xylenes 1.04 1.11 1.33 1.10 1.19 1.06 0.858 1.10 13.2%
60)o-Xylene 1.01 1.10 1.36 1.13 1.22 1.12 0.933 1.12 12.3%
61)Styrene 0.808 0.891 1.11 0.920 1.01 0.939 0.793 0.925 12.0%
62)Bromoform 0.667 0.737 0.900 0.753 0.835 0.771 0.670 0.762 11.1%
63) 1,1,2,2-Tetrachloroethane 0.790 0.897 1.16 0.960 1.05 0.988 0.869 0.959 12.8%
06/29/12 18:53
PASS
06/29/12 20:10
06/29/12 16:35
06/29/12 17:17
06/29/12 18:03
Response Factor Report
Acq. Date
06/29/12 12:52
06/29/12 13:43
Sample ID LID FileName
0.4ppbv TO-15 std 0.66 L1201400.D
1.0ppbv TO-15 std 1.65 L1201401.D Inst: Lurch
2.0ppbv TO-15 std 3.3 L1201409.D
5ppbv TO-15 std 8.25 L1201404.D Curve: L062912C.M
10ppbv TO-15 std 16.5 L1201405.D
20ppbv TO-15 std 33 L1201406.D
30ppbv TO-15 std 49.5 L1201407.D
#Name
0.4ppbv TO-
15 std
1.0ppbv TO-
15 std
2.0ppbv TO-
15 std
5ppbv TO-
15 std
10ppbv TO-
15 std
20ppbv TO-
15 std
30ppbv TO-
15 std Average RF %RSD
06/29/12 18:53
PASS
06/29/12 20:10
06/29/12 16:35
06/29/12 17:17
06/29/12 18:03
Response Factor Report
Acq. Date
06/29/12 12:52
06/29/12 13:43
64)4-Ethyltoluene 1.27 1.45 1.97 1.67 1.91 1.52 1.17 1.57 19.4%
65)2-Chlorotoluene 1.16 1.35 1.79 1.49 1.59 1.33 1.06 1.39 17.9%
66)1,3,5-Trimethylbenzene 0.906 1.05 1.49 1.23 1.22 1.22 1.09 1.17 15.7%
67)1,2,4-Trimethylbenzene 0.912 1.02 1.52 1.27 1.40 1.31 1.15 1.23 17.4%
68)1,3-Dichlorobenzene 0.607 0.688 1.05 0.890 0.990 0.933 0.827 0.856 18.8%
69)1,4-Dichlorobenzene 0.617 0.691 1.08 0.911 1.01 0.951 0.845 0.872 19.3%
70)Benzyl chloride 0.901 1.03 1.53 1.28 1.42 1.36 1.20 1.25 17.9%
71)1,2-Dichlorobenzene 0.561 0.613 1.00 0.833 0.933 0.896 0.796 0.805 20.3%
72)1,2,4-Trichlorobenzene 0.639 0.276 0.635 0.480 0.606 0.627 0.582 0.549 24.1%
73)Hexachlorobutadiene 0.503 0.200 0.437 0.339 0.407 0.389 0.339 0.373 25.6%
74)Naphthalene 1.84 0.786 1.76 1.32 1.63 1.68 1.57 1.51 23.9%
= %RSD >30 and <40, two allowed
= %RSD >40, zero allowed
Sample ID LID FileName
0.4ppbv TO-15 std 0.66 L1201400.D
1.0ppbv TO-15 std 1.65 L1201401.D Inst: Lurch
2.0ppbv TO-15 std 3.3 L1201409.D
5ppbv TO-15 std 8.25 L1201404.D Curve: L062912C.M
10ppbv TO-15 std 16.5 L1201405.D
20ppbv TO-15 std 33 L1201406.D
30ppbv TO-15 std 49.5 L1201407.D
#Name
0.4ppbv TO-
15 std
1.0ppbv TO-
15 std
2.0ppbv TO-
15 std
5ppbv TO-
15 std
10ppbv TO-
15 std
20ppbv TO-
15 std
30ppbv TO-
15 std
Average
RRT
2)Propylene 0.36 0.36 0.36 0.36 0.36 0.36 0.36 0.36
3)Freon 12 (CCl2F2)0.37 0.37 0.37 0.37 0.37 0.37 0.37 0.37
4)Freon 114 (C2Cl2F4)0.40 0.40 0.40 0.40 0.40 0.40 0.40 0.40
5)Chloromethane 0.41 0.40 0.41 0.41 0.41 0.41 0.41 0.41
6) Chloroethene (Vinyl chloride) 0.43 0.43 0.43 0.43 0.43 0.43 0.43 0.43
7)1,3-Butadiene 0.44 0.44 0.44 0.44 0.44 0.44 0.44 0.44
8)Bromomethane 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50
9)Chloroethane 0.52 0.52 0.52 0.52 0.52 0.52 0.52 0.52
10) Bromoethene (Vinyl bromide) 0.55 0.55 0.56 0.56 0.56 0.56 0.56 0.56
11)Freon 11 (CCl3F)0.57 0.57 0.57 0.57 0.57 0.57 0.57 0.57
12)Ethanol 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60
13)Acrolein 0.65 0.65 0.65 0.65 0.65 0.65 0.65 0.65
14)Freon 113 (C2Cl3F3)0.67 0.67 0.67 0.67 0.67 0.67 0.67 0.67
15)1,1-Dichloroethene 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66
16)Acetone 0.67 0.67 0.67 0.67 0.67 0.67 0.67 0.67
17)Carbon disulfide 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70
18)Isopropyl alcohol 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70
19) Allyl chloride (3-chloropropene) 0.73 0.73 0.73 0.73 0.73 0.73 0.73 0.73
20)Acetonitrile 0.72 0.72 0.72 0.72 0.72 0.72 0.72 0.72
21)Methylene chloride 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75
22) trans-1,2-Dichloroethene 0.80 0.80 0.80 0.80 0.80 0.80 0.80 0.80
23)Methyl tert-butyl ether 0.80 0.80 0.80 0.80 0.80 0.80 0.80 0.80
24)Acrylonitrile 0.79 0.79 0.79 0.79 0.79 0.79 0.79 0.79
25)Hexane 0.85 0.84 0.85 0.85 0.85 0.85 0.85 0.85
26)1,1-Dichloroethane 0.87 0.87 0.87 0.87 0.87 0.87 0.87 0.87
27)Vinyl acetate 0.87 0.87 0.87 0.87 0.87 0.87 0.87 0.87
28) cis-1,2-Dichloroethylene 0.96 0.96 0.96 0.96 0.96 0.96 0.96 0.96
29) Methyl ethyl ketone (2-Butanone) 0.96 0.96 0.96 0.96 0.96 0.96 0.96 0.96
30)Ethyl acetate 0.97 0.97 0.97 0.97 0.97 0.97 0.97 0.97
31)Chloroform 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01
32)Tetrahydrofuran 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00
33)1,1,1-Trichloroethane 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04
34)Cyclohexane 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05
35)Carbon tetrachloride 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.06
37)Benzene 0.96 0.95 0.95 0.96 0.96 0.95 0.95 0.95
38)2,2,4-trimethylpentane 0.97 0.97 0.97 0.97 0.97 0.97 0.97 0.97
39)1,2-Dichloroethane 0.96 0.96 0.96 0.96 0.96 0.96 0.96 0.96
40)Heptane 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99
41)Trichloroethene 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03
42)1,2-Dichloropropane 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05
43)Methyl methacrylate 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.06
44)1,4-Dioxane 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.06
45)Bromodichloromethane 1.08 1.08 1.08 1.08 1.08 1.08 1.08 1.08
46) cis-1,3-Dichloropropene 1.13 1.13 1.13 1.13 1.13 1.13 1.13 1.13
47)Methyl isobutyl ketone 1.15 1.15 1.15 1.15 1.15 1.15 1.15 1.15
49)Toluene 0.91 0.91 0.91 0.91 0.91 0.91 0.91 0.91
50) trans-1,3-Dichloropropene 0.93 0.93 0.93 0.93 0.93 0.93 0.93 0.93
51)1,1,2-Trichloroethane 0.94 0.94 0.94 0.94 0.94 0.94 0.94 0.94
52)Tetrachloroethene 0.95 0.95 0.95 0.95 0.95 0.95 0.95 0.95
53) 2-Hexanone (Methyl butyl ketone) 0.95 0.95 0.95 0.95 0.95 0.95 0.95 0.95
54)Dibromochloromethane 0.97 0.97 0.97 0.97 0.97 0.97 0.97 0.97
55)1,2-Dibromoethane 0.97 0.97 0.97 0.97 0.97 0.97 0.97 0.97
56)Chlorobenzene 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00
57)Ethylbenzene 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01
58) 1,1,1,2-Tetrachloroethane 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01
59)m-/p-Xylenes 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01
60)o-Xylene 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03
61)Styrene 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03
62)Bromoform 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04
63) 1,1,2,2-Tetrachloroethane 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.06
64)4-Ethyltoluene 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07
06/29/12 18:53
06/29/12 20:10
06/29/12 16:35
06/29/12 17:17
06/29/12 18:03
Relative Retention Time Report
Acq. Date
06/29/12 12:52
06/29/12 13:43
Sample ID LID FileName
0.4ppbv TO-15 std 0.66 L1201400.D
1.0ppbv TO-15 std 1.65 L1201401.D Inst: Lurch
2.0ppbv TO-15 std 3.3 L1201409.D
5ppbv TO-15 std 8.25 L1201404.D Curve: L062912C.M
10ppbv TO-15 std 16.5 L1201405.D
20ppbv TO-15 std 33 L1201406.D
30ppbv TO-15 std 49.5 L1201407.D
#Name
0.4ppbv TO-
15 std
1.0ppbv TO-
15 std
2.0ppbv TO-
15 std
5ppbv TO-
15 std
10ppbv TO-
15 std
20ppbv TO-
15 std
30ppbv TO-
15 std
Average
RRT
06/29/12 18:53
06/29/12 20:10
06/29/12 16:35
06/29/12 17:17
06/29/12 18:03
Relative Retention Time Report
Acq. Date
06/29/12 12:52
06/29/12 13:43
65)2-Chlorotoluene 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07
66)1,3,5-Trimethylbenzene 1.08 1.08 1.07 1.08 1.08 1.08 1.08 1.08
67)1,2,4-Trimethylbenzene 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09
68)1,3-Dichlorobenzene 1.11 1.11 1.11 1.11 1.11 1.11 1.11 1.11
69)1,4-Dichlorobenzene 1.11 1.11 1.11 1.11 1.11 1.11 1.11 1.11
70)Benzyl chloride 1.11 1.11 1.11 1.11 1.11 1.11 1.11 1.11
71)1,2-Dichlorobenzene 1.13 1.13 1.13 1.13 1.13 1.13 1.13 1.13
72)1,2,4-Trichlorobenzene 1.20 1.20 1.20 1.20 1.20 1.20 1.20 1.20
73)Hexachlorobutadiene 1.20 1.20 1.20 1.20 1.20 1.20 1.20 1.20
74)Naphthalene 1.21 1.21 1.21 1.21 1.21 1.21 1.21 1.21
= RRT outside 0.06 unit RRT window
Sample ID LID FileName
0.4ppbv TO-15 std 0.66 L1201400.D
1.0ppbv TO-15 std 1.65 L1201401.D Inst: Lurch
2.0ppbv TO-15 std 3.3 L1201409.D
5ppbv TO-15 std 8.25 L1201404.D Curve: L062912C.M
10ppbv TO-15 std 16.5 L1201405.D
20ppbv TO-15 std 33 L1201406.D
30ppbv TO-15 std 49.5 L1201407.D
#Name
0.4ppbv TO-
15 std
1.0ppbv TO-
15 std
2.0ppbv TO-
15 std
5ppbv TO-
15 std
10ppbv TO-
15 std
20ppbv TO-
15 std
30ppbv TO-
15 std Average
1) Bromochloromethane (IS) 13.07 13.07 13.08 13.08 13.08 13.08 13.08 13.08
36) 1,4-Difluorobenzene (IS) 14.87 14.87 14.88 14.87 14.87 14.88 14.88 14.87
48)Chlorobenzene-d5 (IS)19.07 19.07 19.09 19.07 19.09 19.08 19.08 19.08
= ISTD retention time outside of 20 sec (0.33 min) window
06/29/12 18:53
06/29/12 20:10
06/29/12 16:35
06/29/12 17:17
06/29/12 18:03
Internal Standards Retention Time Report
Acq. Date
06/29/12 12:52
06/29/12 13:43
Sample ID LID FileName
0.4ppbv TO-15 std 0.66 L1201400.D
1.0ppbv TO-15 std 1.65 L1201401.D Inst: Lurch
2.0ppbv TO-15 std 3.3 L1201409.D
5ppbv TO-15 std 8.25 L1201404.D Curve: L062912C.M
10ppbv TO-15 std 16.5 L1201405.D
20ppbv TO-15 std 33 L1201406.D
30ppbv TO-15 std 49.5 L1201407.D
#Name
0.4ppbv TO-
15 std
1.0ppbv TO-
15 std
2.0ppbv TO-
15 std
5ppbv TO-
15 std
10ppbv TO-
15 std
20ppbv TO-
15 std
30ppbv TO-
15 std Average
1) Bromochloromethane (IS) 555,770 537,994 525,089 565,097 511,785 528,136 551,135 539,287
36) 1,4-Difluorobenzene (IS) 2,110,446 2,011,663 1,959,096 2,107,927 1,899,253 1,943,308 2,054,023 2,012,245
48)Chlorobenzene-d5 (IS) 2,167,566 2,045,766 1,833,148 2,065,230 1,845,581 1,862,242 1,929,586 1,964,160
= ISTD response outside of 40% window
06/29/12 18:53
06/29/12 20:10
06/29/12 16:35
06/29/12 17:17
06/29/12 18:03
Internal Standards Area Report
Acq. Date
06/29/12 12:52
06/29/12 13:43
#Compound Name 49.5ppbv 33ppbv 16.5ppbv 8.25ppbv 3.3ppbv 1.65ppbv 0.66ppbv
2)Propylene 54.5 36.3 18.2 9.08 3.63 1.82 0.726
3)Freon 12 (CCl2F2)49.0 32.7 16.3 8.17 3.27 1.63 0.653
4)Freon 114 (C2Cl2F4)50.0 33.3 16.7 8.33 3.33 1.67 0.667
5)Chloromethane 50.5 33.7 16.8 8.42 3.37 1.68 0.673
6) Chloroethene (Vinyl chloride) 50.5 33.7 16.8 8.42 3.37 1.68 0.673
7)1,3-Butadiene 52.5 35.0 17.5 8.75 3.50 1.75 0.700
8)Bromomethane 50.5 33.7 16.8 8.42 3.37 1.68 0.673
9)Chloroethane 50.0 33.3 16.7 8.33 3.33 1.67 0.667
10) Bromoethene (Vinyl bromide) 49.5 33.0 16.5 8.25 3.30 1.65 0.660
11)Freon 11 (CCl3F)52.0 34.7 17.3 8.66 3.47 1.73 0.693
12)Ethanol 50.5 33.7 16.8 8.42 3.37 1.68 0.673
13)Acrolein 54.0 36.0 18.0 8.99 3.60 1.80 0.719
14) Freon 113 (C2Cl3F3)48.5 32.3 16.2 8.09 3.23 1.62 0.647
15)1,1-Dichloroethene 49.0 32.7 16.3 8.17 3.27 1.63 0.653
16)Acetone 52.0 34.7 17.3 8.66 3.47 1.73 0.693
17)Carbon disulfide 49.0 32.7 16.3 8.17 3.27 1.63 0.653
18)Isopropyl alcohol 54.0 36.0 18.0 8.99 3.60 1.80 0.719
19) Allyl chloride (3-chloropropene) 51.0 34.0 17.0 8.50 3.40 1.70 0.680
20)Acetonitrile 45.5 30.4 15.2 7.59 3.04 1.52 0.607
21)Methylene chloride 50.0 33.3 16.7 8.33 3.33 1.67 0.667
22) trans-1,2-Dichloroethene 49.5 33.0 16.5 8.25 3.30 1.65 0.660
23) Methyl tert-butyl ether 52.0 34.7 17.3 8.66 3.47 1.73 0.693
24)Acrylonitrile 49.5 33.0 16.5 8.25 3.30 1.65 0.660
25)Hexane 51.5 34.3 17.2 8.58 3.43 1.72 0.686
26)1,1-Dichloroethane 50.5 33.7 16.8 8.42 3.37 1.68 0.673
27)Vinyl acetate 53.0 35.3 17.7 8.83 3.53 1.77 0.706
28) cis-1,2-Dichloroethylene 51.5 34.3 17.2 8.58 3.43 1.72 0.686
29) Methyl ethyl ketone (2-Butanone) 53.0 35.3 17.7 8.83 3.53 1.77 0.706
30)Ethyl acetate 51.0 34.0 17.0 8.50 3.40 1.70 0.680
31)Chloroform 51.0 34.0 17.0 8.50 3.40 1.70 0.680
32)Tetrahydrofuran 53.0 35.3 17.7 8.83 3.53 1.77 0.706
33) 1,1,1-Trichloroethane 51.0 34.0 17.0 8.50 3.40 1.70 0.680
34)Cyclohexane 51.5 34.3 17.2 8.58 3.43 1.72 0.686
35)Carbon tetrachloride 50.0 33.3 16.7 8.33 3.33 1.67 0.667
37)Benzene 51.5 34.3 17.2 8.58 3.43 1.72 0.686
38) 2,2,4-trimethylpentane 50.5 33.7 16.8 8.42 3.37 1.68 0.673
39)1,2-Dichloroethane 52.0 34.7 17.3 8.66 3.47 1.73 0.693
40)Heptane 52.5 35.0 17.5 8.75 3.50 1.75 0.700
41)Trichloroethene 52.0 34.7 17.3 8.66 3.47 1.73 0.693
42)1,2-Dichloropropane 52.5 35.0 17.5 8.75 3.50 1.75 0.700
43)Methyl methacrylate 52.5 35.0 17.5 8.75 3.50 1.75 0.700
44)1,4-Dioxane 52.0 34.7 17.3 8.66 3.47 1.73 0.693
45) Bromodichloromethane 52.0 34.7 17.3 8.66 3.47 1.73 0.693
46) cis-1,3-Dichloropropene 54.0 36.0 18.0 8.99 3.60 1.80 0.719
47) Methyl isobutyl ketone 53.5 35.7 17.8 8.92 3.57 1.78 0.713
49)Toluene 53.0 35.3 17.7 8.83 3.53 1.77 0.706
50) trans-1,3-Dichloropropene 49.5 33.0 16.5 8.25 3.30 1.65 0.660
51) 1,1,2-Trichloroethane 53.0 35.3 17.7 8.83 3.53 1.77 0.706
52)Tetrachloroethene 52.0 34.7 17.3 8.66 3.47 1.73 0.693
53) 2-Hexanone (Methyl butyl ketone) 54.0 36.0 18.0 8.99 3.60 1.80 0.719
54) Dibromochloromethane 54.0 36.0 18.0 8.99 3.60 1.80 0.719
55)1,2-Dibromoethane 52.5 35.0 17.5 8.75 3.50 1.75 0.700
56)Chlorobenzene 54.0 36.0 18.0 8.99 3.60 1.80 0.719
57)Ethylbenzene 53.5 35.6 17.8 8.91 3.56 1.78 0.713
58) 1,1,1,2-Tetrachloroethane 49.5 33.0 16.5 8.25 3.30 1.65 0.660
59)m-/p-Xylenes 105 70.0 35.0 17.5 7.00 3.50 1.40
60)o-Xylene 54.5 36.3 18.2 9.08 3.63 1.82 0.726
61)Styrene 54.0 36.0 18.0 8.99 3.60 1.80 0.719
62)Bromoform 52.5 35.0 17.5 8.75 3.50 1.75 0.700
63) 1,1,2,2-Tetrachloroethane 54.5 36.3 18.2 9.08 3.63 1.82 0.726
64)4-Ethyltoluene 52.5 35.0 17.5 8.75 3.50 1.75 0.700
65)2-Chlorotoluene 50.0 33.3 16.7 8.33 3.33 1.67 0.667
Tag Values
#Compound Name 49.5ppbv 33ppbv 16.5ppbv 8.25ppbv 3.3ppbv 1.65ppbv 0.66ppbv
Tag Values
66) 1,3,5-Trimethylbenzene 53.5 35.6 17.8 8.91 3.56 1.78 0.713
67) 1,2,4-Trimethylbenzene 53.5 35.6 17.8 8.91 3.56 1.78 0.713
68)1,3-Dichlorobenzene 54.5 36.3 18.2 9.08 3.63 1.82 0.726
69)1,4-Dichlorobenzene 53.0 35.3 17.7 8.83 3.53 1.77 0.706
70)Benzyl chloride 54.5 36.3 18.2 9.08 3.63 1.82 0.726
71)1,2-Dichlorobenzene 53.5 35.6 17.8 8.91 3.56 1.78 0.713
72) 1,2,4-Trichlorobenzene 52.5 35.0 17.5 8.75 3.50 1.75 0.700
73) Hexachlorobutadiene 52.5 35.0 17.5 8.75 3.50 1.75 0.700
74)Naphthalene 48.5 32.3 16.2 8.09 3.23 1.62 0.647
Response Factor Report Lurch
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
Calibration Files
0.66 =L1201400.D 1.65 =L1201401.D 3.3 =L1201409.D
8.25 =L1201404.D 16.5 =L1201405.D 33 =L1201406.D
Compound 0.66 1.65 3.3 8.25 16.5 33 Avg %RSD
-------------------------------------------------------------------------
1) I Bromochloromethane (I ----------------ISTD----------------------
2) Propylene 1.600 1.381 1.313 1.149 1.245 1.179 1.282 13.21
3) Freon 12 (CCl2F2) 4.131 3.743 3.759 3.313 3.575 3.345 3.569 9.59
4) Freon 114 (C2Cl2F4) 4.448 4.042 4.115 3.574 3.865 3.625 3.861 9.65
5) Chloromethane 1.614 1.476 1.469 1.276 1.403 1.313 1.400 9.32
6) Chloroethene (Vinyl 1.476 1.322 1.394 1.216 1.320 1.260 1.309 7.87
7) 1,3-Butadiene 1.344 1.273 1.259 1.111 1.198 1.121 1.195 8.61
8) Bromomethane 1.669 1.518 1.550 1.370 1.460 1.396 1.469 8.18
9) Chloroethane 0.822 0.731 0.747 0.669 0.706 0.679 0.715 8.04
10) Bromoethene (Vinyl 1.549 1.402 1.428 1.236 1.330 1.268 1.346 8.98
11) Freon 11 (CCl3F) 3.485 3.246 3.163 2.772 2.964 2.771 2.995 10.72
12) Ethanol 0.514 0.464 0.461 0.399 0.426 0.412 0.439 9.79
13) Acrolein 0.470 0.445 0.467 0.459 0.500 0.488 0.472 3.87
14) Freon 113 (C2Cl3F3) 1.875 1.672 1.716 1.496 1.629 1.567 1.638 8.06
15) 1,1-Dichloroethene 2.283 1.983 2.158 1.902 2.041 1.950 2.026 7.32
16) Acetone 3.540 2.437 2.590 2.289 2.420 2.317 2.546 17.83
17) Carbon disulfide 3.984 3.599 3.765 3.243 3.506 3.372 3.528 7.90
18) Isopropyl alcohol 3.064 2.675 2.762 2.439 2.619 2.417 2.612 9.78
19) Allyl chloride (3-c 0.620 0.570 0.586 0.515 0.557 0.541 0.559 6.62
20) Acetonitrile 1.482 1.323 1.343 1.183 1.268 1.239 1.293 7.86
21) Methylene chloride 2.845 2.103 1.988 1.663 1.768 1.674 1.949 22.33
22) trans-1,2-Dichloroe 2.069 1.915 1.987 1.704 1.846 1.768 1.853 7.89
23) Methyl tert-butyl e 3.529 3.294 3.375 2.928 3.187 3.076 3.188 7.13
24) Acrylonitrile 1.129 1.022 1.087 0.938 1.019 0.996 1.023 6.50
25) Hexane 2.118 1.889 1.922 1.667 1.796 1.734 1.825 9.05
26) 1,1-Dichloroethane 2.546 2.307 2.383 2.057 2.222 2.139 2.242 8.20
27) Vinyl acetate 4.925 4.596 4.826 4.144 4.447 4.193 4.432 8.54
28) cis-1,2-Dichloroeth 2.442 2.224 2.283 1.984 2.152 2.069 2.162 7.79
29) Methyl ethyl ketone 0.633 0.579 0.610 0.535 0.587 0.569 0.580 5.87
30) Ethyl acetate 0.543 0.523 0.555 0.473 0.512 0.492 0.509 6.69
31) Chloroform 2.978 2.750 2.821 2.449 2.665 2.570 2.668 7.39
32) Tetrahydrofuran 0.607 0.572 0.608 0.523 0.576 0.558 0.570 5.48
33) 1,1,1-Trichloroetha 3.007 2.736 2.787 2.415 2.635 2.533 2.644 8.25
34) Cyclohexane 2.150 1.981 2.046 1.766 1.921 1.850 1.922 7.79
35) Carbon tetrachlorid 3.025 2.820 2.823 2.471 2.681 2.569 2.687 8.10
36) I 1,4-Difluorobenzene ( ----------------ISTD----------------------
37) Benzene 0.961 0.914 0.953 0.817 0.898 0.866 0.888 6.85
38) 2,2,4-trimethylpent 1.659 1.580 1.628 1.397 1.510 1.429 1.502 8.54
39) 1,2-Dichloroethane 0.493 0.459 0.462 0.415 0.443 0.434 0.445 6.56
40) Heptane 0.317 0.304 0.316 0.275 0.297 0.285 0.294 6.91
41) Trichloroethene 0.479 0.457 0.473 0.413 0.458 0.448 0.449 5.62
42) 1,2-Dichloropropane 0.364 0.349 0.365 0.313 0.344 0.328 0.338 7.06
43) Methyl methacrylate 0.353 0.343 0.359 0.311 0.343 0.333 0.336 5.91
44) 1,4-Dioxane 0.226 0.208 0.214 0.187 0.205 0.204 0.206 6.06
45) Bromodichloromethan 0.826 0.793 0.819 0.713 0.779 0.753 0.768 6.51
46) cis-1,3-Dichloropro 0.600 0.586 0.616 0.535 0.587 0.575 0.577 5.33
47) Methyl isobutyl ket 1.033 1.011 1.071 0.934 1.014 0.956 0.985 6.72
48) I Chlorobenzene-d5 (IS) ----------------ISTD----------------------
49) Toluene 1.136 1.118 1.273 1.050 1.169 1.127 1.135 6.43
50) trans-1,3-Dichlorop 0.583 0.587 0.672 0.561 0.625 0.615 0.604 6.10
51) 1,1,2-Trichloroetha 0.453 0.445 0.515 0.430 0.472 0.462 0.459 6.18
52) Tetrachloroethene 0.564 0.577 0.665 0.554 0.614 0.585 0.583 7.78
53) 2-Hexanone (Methyl 0.991 1.019 1.176 0.973 1.062 0.994 1.018 8.21
54) Dibromochloromethan 0.829 0.838 0.958 0.799 0.876 0.842 0.844 7.21
55) 1,2-Dibromoethane 0.753 0.761 0.888 0.736 0.815 0.792 0.783 6.96
56) Chlorobenzene 0.895 0.922 1.094 0.914 1.012 0.979 0.960 7.59
57) Ethylbenzene 1.380 1.466 1.750 1.438 1.540 1.304 1.416 15.40
L062912C.M Tue Jul 10 18:57:28 2012 Page 1
(#) = Out of Range ### Number of calibration levels exceeded format ###
Response Factor Report Lurch
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
Calibration Files
0.66 =L1201400.D 1.65 =L1201401.D 3.3 =L1201409.D
8.25 =L1201404.D 16.5 =L1201405.D 33 =L1201406.D
Compound 0.66 1.65 3.3 8.25 16.5 33 Avg %RSD
-------------------------------------------------------------------------
58) 1,1,1,2-Tetrachloro 0.526 0.543 0.640 0.528 0.577 0.517 0.539 11.23
59) m-/p-Xylenes 1.036 1.108 1.334 1.099 1.188 1.064 1.098 13.20
60) o-Xylene 1.006 1.102 1.357 1.126 1.222 1.119 1.124 12.31
61) Styrene 0.808 0.891 1.110 0.920 1.009 0.939 0.924 12.01
62) Bromoform 0.667 0.737 0.900 0.753 0.835 0.771 0.762 11.08
63) 1,1,2,2-Tetrachloro 0.790 0.897 1.163 0.960 1.046 0.988 0.959 12.82
64) 4-Ethyltoluene 1.272 1.446 1.973 1.666 1.909 1.518 1.565 19.38
65) 2-Chlorotoluene 1.160 1.348 1.790 1.490 1.586 1.328 1.395 17.94
66) 1,3,5-Trimethylbenz 0.908 1.051 1.495 1.235 1.215 1.221 1.174 15.67
67) 1,2,4-Trimethylbenz 0.912 1.025 1.521 1.272 1.403 1.312 1.228 17.37
68) 1,3-Dichlorobenzene 0.607 0.688 1.054 0.890 0.990 0.933 0.856 18.79
69) 1,4-Dichlorobenzene 0.617 0.691 1.084 0.910 1.007 0.951 0.872 19.25
70) Benzyl chloride 0.901 1.027 1.534 1.282 1.425 1.359 1.247 17.87
71) 1,2-Dichlorobenzene 0.561 0.613 1.002 0.833 0.933 0.896 0.805 20.32
72) 1,2,4-Trichlorobenz 0.639 0.276 0.635 0.480 0.606 0.627 0.549 24.08
73) Hexachlorobutadiene 0.503 0.200 0.440 0.339 0.407 0.389 0.374 25.64
74) Naphthalene 1.840 0.786 1.763 1.319 1.632 1.682 1.514 23.86
L062912C.M Tue Jul 10 18:57:29 2012 Page 2
(#) = Out of Range ### Number of calibration levels exceeded format ###
Quantitation Report
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201400.D Vial: 1
Acq On : 29 Jun 2012 12:52 pm Operator: DB
Sample : 0.66ppbv TO-15 std Inst : Lurch
Misc : 10mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:34 2012 Quant Results File: L062912C.RES
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:34:39 2012
Response via : Initial Calibration
4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00
0
200000
400000
600000
800000
1000000
1200000
1400000
1600000
1800000
2000000
2200000
2400000
2600000
2800000
3000000
3200000
3400000
3600000
3800000
4000000
4200000
4400000
4600000
4800000
5000000
5200000
5400000
5600000
5800000
6000000
Time-->
Abundance TIC: L1201400.D
NaphthaleneHexachlorobutadiene1,2,4-Trichlorobenzene1,2-DichlorobenzeneBenzyl chloride1,4-Dichlorobenzene1,3-Dichlorobenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene2-Chlorotoluene4-Ethyltoluene1,1,2,2-TetrachloroethaneBromoformStyreneo-Xylenem-/p-Xylenes1,1,1,2-TetrachloroethaneEthylbenzeneChlorobenzeneChlorobenzene-d5 (IS),I1,2-DibromoethaneDibromochloromethane2-Hexanone (Methyl butyl ketone)Tetrachloroethene1,1,2-Trichloroethanetrans-1,3-DichloropropeneTolueneMethyl isobutyl ketonecis-1,3-DichloropropeneBromodichloromethane1,4-DioxaneMethyl methacrylate1,2-DichloropropaneTrichloroethene1,4-Difluorobenzene (IS),IHeptane2,2,4-trimethylpentane1,2-DichloroethaneBenzeneCarbon tetrachlorideCyclohexane1,1,1-TrichloroethaneChloroformTetrahydrofuranBromochloromethane (IS),IEthyl acetatecis-1,2-DichloroethyleneMethyl ethyl ketone (2-Butanone)1,1-DichloroethaneVinyl acetateHexaneMethyl tert-butyl ethertrans-1,2-DichloroetheneAcrylonitrileMethylene chlorideAllyl chloride (3-chloropropene)AcetonitrileCarbon disulfideIsopropyl alcoholAcetoneFreon 113 (C2Cl3F3)1,1-DichloroetheneAcroleinEthanolFreon 11 (CCl3F)Bromoethene (Vinyl bromide)ChloroethaneBromomethane1,3-ButadieneChloroethene (Vinyl chloride)ChloromethaneFreon 114 (C2Cl2F4)Freon 12 (CCl2F2)PropyleneL1201400.D L062912C.M Tue Jul 10 18:35:25 2012 Page 3
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201400.D Vial: 1
Acq On : 29 Jun 2012 12:52 pm Operator: DB
Sample : 0.66ppbv TO-15 std Inst : Lurch
Misc : 10mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:34 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:05:57 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) Bromochloromethane (IS) 13.07 130 555635 11.03 PPBV 0.00
36) 1,4-Difluorobenzene (IS) 14.87 114 2110446 10.52 PPBV 0.00
48) Chlorobenzene-d5 (IS) 19.07 117 2167566 11.20 PPBV 0.00
Target Compounds Qvalue
2) Propylene 4.69 41 58532 0.91 PPBV # 76
3) Freon 12 (CCl2F2) 4.79 85 135961 0.76 PPBV 97
4) Freon 114 (C2Cl2F4) 5.17 85 149371 0.77 PPBV # 94
5) Chloromethane 5.29 50 54736 0.78 PPBV 99
6) Chloroethene (Vinyl chlori 5.61 62 50071 0.76 PPBV 100
7) 1,3-Butadiene 5.73 39 47362 0.79 PPBV 90
8) Bromomethane 6.49 94 56597 0.76 PPBV 97
9) Chloroethane 6.79 64 27587 0.77 PPBV 91
10) Bromoethene (Vinyl bromide 7.24 106 51508 0.76 PPBV # 94
11) Freon 11 (CCl3F) 7.42 101 121675 0.81 PPBV 99
12) Ethanol 7.87 45 17442 0.79 PPBV # 78
13) Acrolein 8.43 56 17049 0.72 PPBV 100
14) Freon 113 (C2Cl3F3) 8.69 151 61094 0.74 PPBV 97
15) 1,1-Dichloroethene 8.65 61 75150 0.74 PPBV 93
16) Acetone 8.76 43 123576 0.96 PPBV # 81
17) Carbon disulfide 9.15 76 131142 0.74 PPBV 96
18) Isopropyl alcohol 9.11 45 111053 0.84 PPBV # 89
19) Allyl chloride (3-chloropr 9.51 76 21245 0.75 PPBV # 50
20) Acetonitrile 9.38 41 45338 0.70 PPBV # 86
21) Methylene chloride 9.80 49 95520 0.97 PPBV # 81
22) trans-1,2-Dichloroethene 10.42 61 68803 0.74 PPBV 99
23) Methyl tert-butyl ether 10.43 73 123211 0.77 PPBV # 86
24) Acrylonitrile 10.30 53 37531 0.73 PPBV # 90
25) Hexane 11.05 57 73229 0.80 PPBV # 76
26) 1,1-Dichloroethane 11.39 63 86329 0.76 PPBV 98
27) Vinyl acetate 11.39 43 175219 0.78 PPBV 97
28) cis-1,2-Dichloroethylene 12.59 61 84426 0.78 PPBV 95
29) Methyl ethyl ketone (2-But 12.57 72 22527 0.77 PPBV 83
30) Ethyl acetate 12.65 45 18607 0.73 PPBV # 88
31) Chloroform 13.25 83 101973 0.76 PPBV 98
32) Tetrahydrofuran 13.12 72 21607 0.75 PPBV # 63
33) 1,1,1-Trichloroethane 13.58 97 102978 0.77 PPBV 95
34) Cyclohexane 13.72 56 74356 0.77 PPBV # 80
35) Carbon tetrachloride 13.86 117 101595 0.75 PPBV 97
37) Benzene 14.20 78 132333 0.74 PPBV # 94
38) 2,2,4-trimethylpentane 14.38 57 224075 0.74 PPBV # 80
39) 1,2-Dichloroethane 14.27 62 68472 0.77 PPBV 100
40) Heptane 14.67 57 44490 0.75 PPBV 91
41) Trichloroethene 15.25 130 66608 0.74 PPBV # 88
42) 1,2-Dichloropropane 15.66 63 51041 0.75 PPBV 91
43) Methyl methacrylate 15.70 69 49520 0.74 PPBV # 90
44) 1,4-Dioxane 15.76 88 31460 0.76 PPBV 99
45) Bromodichloromethane 16.07 83 114829 0.74 PPBV # 98
46) cis-1,3-Dichloropropene 16.82 75 86650 0.75 PPBV 98
47) Methyl isobutyl ketone 17.04 43 147814 0.75 PPBV # 94
49) Toluene 17.41 91 155282 0.71 PPBV 96
50) trans-1,3-Dichloropropene 17.69 75 74528 0.64 PPBV 99
51) 1,1,2-Trichloroethane 17.97 97 61965 0.70 PPBV 89
52) Tetrachloroethene 18.11 166 75583 0.67 PPBV 96
53) 2-Hexanone (Methyl butyl k 18.20 43 138038 0.70 PPBV # 92
54) Dibromochloromethane 18.44 129 115399 0.71 PPBV 99
55) 1,2-Dibromoethane 18.59 107 101955 0.67 PPBV 97
56) Chlorobenzene 19.10 112 124548 0.67 PPBV # 81
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201400.D L062912C.M Tue Jul 10 18:35:24 2012 Page 1
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201400.D Vial: 1
Acq On : 29 Jun 2012 12:52 pm Operator: DB
Sample : 0.66ppbv TO-15 std Inst : Lurch
Misc : 10mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:34 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:05:57 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Compound R.T. QIon Response Conc Unit Qvalue
-------------------------------------------------------------------------
57) Ethylbenzene 19.19 91 190326 0.69 PPBV 99
58) 1,1,1,2-Tetrachloroethane 19.19 131 67172 0.64 PPBV # 91
59) m-/p-Xylenes 19.31 91 280674 1.32 PPBV 94
60) o-Xylene 19.69 91 141295 0.65 PPBV 93
61) Styrene 19.71 104 112500 0.63 PPBV 91
62) Bromoform 19.90 173 90302 0.61 PPBV 98
63) 1,1,2,2-Tetrachloroethane 20.27 83 110945 0.60 PPBV 97
64) 4-Ethyltoluene 20.47 105 172256 0.57 PPBV 97
65) 2-Chlorotoluene 20.47 91 149643 0.55 PPBV 98
66) 1,3,5-Trimethylbenzene 20.51 105 125291 0.55 PPBV 97
67) 1,2,4-Trimethylbenzene 20.83 105 125821 0.53 PPBV 99
68) 1,3-Dichlorobenzene 21.10 146 85300 0.52 PPBV 97
69) 1,4-Dichlorobenzene 21.18 146 84331 0.50 PPBV 96
70) Benzyl chloride 21.26 91 126563 0.52 PPBV 94
71) 1,2-Dichlorobenzene 21.49 146 77386 0.50 PPBV 97
72) 1,2,4-Trichlorobenzene 22.85 180 86453 0.81 PPBV 98
73) Hexachlorobutadiene 22.94 225 68154 0.94 PPBV 98
74) Naphthalene 23.14 128 230386 0.79 PPBV # 79
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201400.D L062912C.M Tue Jul 10 18:35:24 2012 Page 2
Quantitation Report
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201401.D Vial: 1
Acq On : 29 Jun 2012 1:43 pm Operator: DB
Sample : 1.65ppbv TO-15 std Inst : Lurch
Misc : 25mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:34 2012 Quant Results File: L062912C.RES
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:34:39 2012
Response via : Initial Calibration
4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00
0
200000
400000
600000
800000
1000000
1200000
1400000
1600000
1800000
2000000
2200000
2400000
2600000
2800000
3000000
3200000
3400000
3600000
3800000
4000000
4200000
4400000
4600000
4800000
5000000
5200000
5400000
Time-->
Abundance TIC: L1201401.D
NaphthaleneHexachlorobutadiene1,2,4-Trichlorobenzene1,2-DichlorobenzeneBenzyl chloride1,4-Dichlorobenzene1,3-Dichlorobenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene2-Chlorotoluene4-Ethyltoluene1,1,2,2-TetrachloroethaneBromoformStyreneo-Xylenem-/p-Xylenes1,1,1,2-TetrachloroethaneEthylbenzeneChlorobenzeneChlorobenzene-d5 (IS),I1,2-DibromoethaneDibromochloromethane2-Hexanone (Methyl butyl ketone)Tetrachloroethene1,1,2-Trichloroethanetrans-1,3-DichloropropeneTolueneMethyl isobutyl ketonecis-1,3-DichloropropeneBromodichloromethane1,4-DioxaneMethyl methacrylate1,2-DichloropropaneTrichloroethene1,4-Difluorobenzene (IS),IHeptane2,2,4-trimethylpentane1,2-DichloroethaneBenzeneCarbon tetrachlorideCyclohexane1,1,1-TrichloroethaneChloroformTetrahydrofuranBromochloromethane (IS),IEthyl acetatecis-1,2-DichloroethyleneMethyl ethyl ketone (2-Butanone)1,1-DichloroethaneVinyl acetateHexanetrans-1,2-DichloroetheneMethyl tert-butyl etherAcrylonitrileMethylene chlorideAllyl chloride (3-chloropropene)AcetonitrileCarbon disulfideIsopropyl alcoholAcetoneFreon 113 (C2Cl3F3)1,1-DichloroetheneAcroleinEthanolFreon 11 (CCl3F)Bromoethene (Vinyl bromide)ChloroethaneBromomethane1,3-ButadieneChloroethene (Vinyl chloride)ChloromethaneFreon 114 (C2Cl2F4)Freon 12 (CCl2F2)PropyleneL1201401.D L062912C.M Tue Jul 10 18:36:38 2012 Page 3
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201401.D Vial: 1
Acq On : 29 Jun 2012 1:43 pm Operator: DB
Sample : 1.65ppbv TO-15 std Inst : Lurch
Misc : 25mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:34 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:34:20 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) Bromochloromethane (IS) 13.07 130 537994 11.03 PPBV 0.00
36) 1,4-Difluorobenzene (IS) 14.87 114 2011663 10.52 PPBV 0.00
48) Chlorobenzene-d5 (IS) 19.07 117 2045766 11.20 PPBV 0.00
Target Compounds Qvalue
2) Propylene 4.68 41 122234 1.95 PPBV # 71
3) Freon 12 (CCl2F2) 4.79 85 298306 1.71 PPBV 97
4) Freon 114 (C2Cl2F4) 5.17 85 328643 1.75 PPBV # 93
5) Chloromethane 5.28 50 121185 1.77 PPBV 98
6) Chloroethene (Vinyl chlori 5.61 62 108512 1.70 PPBV 100
7) 1,3-Butadiene 5.73 39 108616 1.86 PPBV 89
8) Bromomethane 6.49 94 124641 1.74 PPBV 99
9) Chloroethane 6.78 64 59455 1.70 PPBV 95
10) Bromoethene (Vinyl bromide 7.25 106 112838 1.72 PPBV # 97
11) Freon 11 (CCl3F) 7.43 101 274355 1.88 PPBV 98
12) Ethanol 7.86 45 38062 1.78 PPBV 77
13) Acrolein 8.43 56 39060 1.70 PPBV 94
14) Freon 113 (C2Cl3F3) 8.69 151 131868 1.65 PPBV 99
15) 1,1-Dichloroethene 8.65 61 158074 1.60 PPBV 89
16) Acetone 8.76 43 206012 1.66 PPBV # 83
17) Carbon disulfide 9.16 76 286870 1.67 PPBV 94
18) Isopropyl alcohol 9.12 45 234758 1.84 PPBV # 89
19) Allyl chloride (3-chloropr 9.51 76 47251 1.73 PPBV # 52
20) Acetonitrile 9.37 41 97955 1.55 PPBV # 84
21) Methylene chloride 9.79 49 170999 1.80 PPBV # 78
22) trans-1,2-Dichloroethene 10.42 61 154135 1.71 PPBV 99
23) Methyl tert-butyl ether 10.42 73 278412 1.79 PPBV # 87
24) Acrylonitrile 10.30 53 82227 1.65 PPBV # 90
25) Hexane 11.04 57 158110 1.78 PPBV # 79
26) 1,1-Dichloroethane 11.39 63 189402 1.73 PPBV 98
27) Vinyl acetate 11.39 43 395880 1.83 PPBV 97
28) cis-1,2-Dichloroethylene 12.60 61 186155 1.77 PPBV 95
29) Methyl ethyl ketone (2-But 12.58 72 49913 1.76 PPBV 78
30) Ethyl acetate 12.67 45 43333 1.74 PPBV # 87
31) Chloroform 13.25 83 228020 1.75 PPBV 98
32) Tetrahydrofuran 13.12 72 49310 1.77 PPBV # 59
33) 1,1,1-Trichloroethane 13.58 97 226877 1.76 PPBV 95
34) Cyclohexane 13.72 56 165770 1.77 PPBV # 80
35) Carbon tetrachloride 13.86 117 229285 1.75 PPBV 97
37) Benzene 14.20 78 300050 1.77 PPBV # 94
38) 2,2,4-trimethylpentane 14.39 57 508485 1.77 PPBV # 80
39) 1,2-Dichloroethane 14.28 62 152084 1.79 PPBV 99
40) Heptane 14.67 57 101643 1.81 PPBV 88
41) Trichloroethene 15.25 130 151313 1.76 PPBV # 89
42) 1,2-Dichloropropane 15.66 63 116777 1.81 PPBV 93
43) Methyl methacrylate 15.70 69 114625 1.79 PPBV # 89
44) 1,4-Dioxane 15.76 88 68904 1.75 PPBV # 79
45) Bromodichloromethane 16.08 83 262935 1.79 PPBV # 96
46) cis-1,3-Dichloropropene 16.82 75 201640 1.83 PPBV 96
47) Methyl isobutyl ketone 17.04 43 344813 1.83 PPBV # 93
49) Toluene 17.41 91 360766 1.74 PPBV 96
50) trans-1,3-Dichloropropene 17.70 75 176988 1.60 PPBV 98
51) 1,1,2-Trichloroethane 17.97 97 143469 1.71 PPBV 88
52) Tetrachloroethene 18.10 166 182522 1.71 PPBV 96
53) 2-Hexanone (Methyl butyl k 18.19 43 334788 1.80 PPBV # 91
54) Dibromochloromethane 18.44 129 275311 1.79 PPBV 100
55) 1,2-Dibromoethane 18.59 107 243223 1.70 PPBV 97
56) Chlorobenzene 19.11 112 303018 1.73 PPBV # 87
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201401.D L062912C.M Tue Jul 10 18:36:37 2012 Page 1
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201401.D Vial: 1
Acq On : 29 Jun 2012 1:43 pm Operator: DB
Sample : 1.65ppbv TO-15 std Inst : Lurch
Misc : 25mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:34 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:34:20 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Compound R.T. QIon Response Conc Unit Qvalue
-------------------------------------------------------------------------
57) Ethylbenzene 19.19 91 477131 1.84 PPBV 100
58) 1,1,1,2-Tetrachloroethane 19.19 131 163637 1.66 PPBV # 93
59) m-/p-Xylenes 19.32 91 707887 3.53 PPBV 94
60) o-Xylene 19.69 91 365434 1.78 PPBV 93
61) Styrene 19.71 104 292742 1.73 PPBV 90
62) Bromoform 19.90 173 235459 1.69 PPBV 98
63) 1,1,2,2-Tetrachloroethane 20.27 83 297378 1.70 PPBV 98
64) 4-Ethyltoluene 20.47 105 461897 1.62 PPBV 96
65) 2-Chlorotoluene 20.47 91 410495 1.61 PPBV 98
66) 1,3,5-Trimethylbenzene 20.51 105 341953 1.59 PPBV 96
67) 1,2,4-Trimethylbenzene 20.83 105 333526 1.49 PPBV 97
68) 1,3-Dichlorobenzene 21.11 146 228223 1.46 PPBV 97
69) 1,4-Dichlorobenzene 21.19 146 222876 1.40 PPBV 97
70) Benzyl chloride 21.27 91 340625 1.50 PPBV 94
71) 1,2-Dichlorobenzene 21.49 146 199635 1.36 PPBV 96
72) 1,2,4-Trichlorobenzene 22.86 180 88285 0.88 PPBV 99
73) Hexachlorobutadiene 22.96 225 63894 0.94 PPBV 98
74) Naphthalene 23.14 128 232085 0.84 PPBV # 79
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201401.D L062912C.M Tue Jul 10 18:36:37 2012 Page 2
Quantitation Report
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201409.D Vial: 1
Acq On : 29 Jun 2012 8:10 pm Operator: DB
Sample : 3.3ppbv TO-15 std Inst : Lurch
Misc : 50mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:37 2012 Quant Results File: L062912C.RES
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:37:47 2012
Response via : Initial Calibration
4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00
0
500000
1000000
1500000
2000000
2500000
3000000
3500000
4000000
4500000
5000000
5500000
6000000
6500000
7000000
Time-->
Abundance TIC: L1201409.D
NaphthaleneHexachlorobutadiene1,2,4-Trichlorobenzene1,2-DichlorobenzeneBenzyl chloride1,4-Dichlorobenzene1,3-Dichlorobenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene2-Chlorotoluene4-Ethyltoluene1,1,2,2-TetrachloroethaneBromoformStyreneo-Xylenem-/p-Xylenes1,1,1,2-TetrachloroethaneEthylbenzeneChlorobenzeneChlorobenzene-d5 (IS),I1,2-DibromoethaneDibromochloromethane2-Hexanone (Methyl butyl ketone)Tetrachloroethene1,1,2-Trichloroethanetrans-1,3-DichloropropeneTolueneMethyl isobutyl ketonecis-1,3-DichloropropeneBromodichloromethane1,4-DioxaneMethyl methacrylate1,2-DichloropropaneTrichloroethene1,4-Difluorobenzene (IS),IHeptane2,2,4-trimethylpentane1,2-DichloroethaneBenzeneCarbon tetrachlorideCyclohexane1,1,1-TrichloroethaneChloroformTetrahydrofuranBromochloromethane (IS),IEthyl acetatecis-1,2-DichloroethyleneMethyl ethyl ketone (2-Butanone)1,1-DichloroethaneVinyl acetateHexanetrans-1,2-DichloroetheneMethyl tert-butyl etherAcrylonitrileMethylene chlorideAllyl chloride (3-chloropropene)AcetonitrileCarbon disulfideIsopropyl alcoholAcetoneFreon 113 (C2Cl3F3)1,1-DichloroetheneAcroleinEthanolFreon 11 (CCl3F)Bromoethene (Vinyl bromide)ChloroethaneBromomethane1,3-ButadieneChloroethene (Vinyl chloride)ChloromethaneFreon 114 (C2Cl2F4)Freon 12 (CCl2F2)PropyleneL1201409.D L062912C.M Tue Jul 10 18:38:10 2012 Page 3
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201409.D Vial: 1
Acq On : 29 Jun 2012 8:10 pm Operator: DB
Sample : 3.3ppbv TO-15 std Inst : Lurch
Misc : 50mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:37 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:34:39 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) Bromochloromethane (IS) 13.08 130 525089 11.03 PPBV 0.01
36) 1,4-Difluorobenzene (IS) 14.88 114 1959096 10.52 PPBV 0.01
48) Chlorobenzene-d5 (IS) 19.09 117 1833148 11.20 PPBV 0.01
Target Compounds Qvalue
2) Propylene 4.70 41 226926 3.72 PPBV # 72
3) Freon 12 (CCl2F2) 4.81 85 584635 3.44 PPBV 98
4) Freon 114 (C2Cl2F4) 5.19 85 652971 3.55 PPBV # 93
5) Chloromethane 5.31 50 235385 3.53 PPBV 98
6) Chloroethene (Vinyl chlori 5.63 62 223310 3.58 PPBV 99
7) 1,3-Butadiene 5.75 39 209620 3.68 PPBV # 87
8) Bromomethane 6.50 94 248387 3.55 PPBV 99
9) Chloroethane 6.80 64 118492 3.48 PPBV 99
10) Bromoethene (Vinyl bromide 7.27 106 224277 3.50 PPBV # 95
11) Freon 11 (CCl3F) 7.44 101 521799 3.66 PPBV 98
12) Ethanol 7.88 45 73936 3.54 PPBV # 79
13) Acrolein 8.45 56 79980 3.56 PPBV 93
14) Freon 113 (C2Cl3F3) 8.72 151 264251 3.39 PPBV 99
15) 1,1-Dichloroethene 8.67 61 335653 3.48 PPBV 93
16) Acetone 8.78 43 427202 3.52 PPBV # 81
17) Carbon disulfide 9.17 76 585581 3.49 PPBV # 92
18) Isopropyl alcohol 9.13 45 472957 3.80 PPBV # 85
19) Allyl chloride (3-chloropr 9.52 76 94833 3.56 PPBV # 50
20) Acetonitrile 9.39 41 194154 3.16 PPBV # 84
21) Methylene chloride 9.81 49 315411 3.40 PPBV # 80
22) trans-1,2-Dichloroethene 10.44 61 312195 3.54 PPBV 99
23) Methyl tert-butyl ether 10.44 73 556638 3.67 PPBV # 87
24) Acrylonitrile 10.32 53 170779 3.51 PPBV # 89
25) Hexane 11.06 57 314029 3.61 PPBV # 78
26) 1,1-Dichloroethane 11.40 63 381825 3.58 PPBV 99
27) Vinyl acetate 11.40 43 811230 3.85 PPBV 97
28) cis-1,2-Dichloroethylene 12.61 61 373036 3.62 PPBV 96
29) Methyl ethyl ketone (2-But 12.58 72 102494 3.71 PPBV 77
30) Ethyl acetate 12.67 45 89850 3.71 PPBV # 84
31) Chloroform 13.26 83 456429 3.59 PPBV 97
32) Tetrahydrofuran 13.12 72 102158 3.77 PPBV # 60
33) 1,1,1-Trichloroethane 13.59 97 450889 3.58 PPBV 95
34) Cyclohexane 13.74 56 334326 3.65 PPBV # 80
35) Carbon tetrachloride 13.88 117 448001 3.50 PPBV 97
37) Benzene 14.21 78 608814 3.68 PPBV # 93
38) 2,2,4-trimethylpentane 14.40 57 1020754 3.65 PPBV # 80
39) 1,2-Dichloroethane 14.29 62 298096 3.60 PPBV 98
40) Heptane 14.67 57 205759 3.76 PPBV 89
41) Trichloroethene 15.26 130 305000 3.64 PPBV # 89
42) 1,2-Dichloropropane 15.68 63 237963 3.78 PPBV 93
43) Methyl methacrylate 15.71 69 234036 3.74 PPBV # 89
44) 1,4-Dioxane 15.78 88 137983 3.61 PPBV # 82
45) Bromodichloromethane 16.08 83 528361 3.69 PPBV # 97
46) cis-1,3-Dichloropropene 16.82 75 412505 3.84 PPBV 98
47) Methyl isobutyl ketone 17.04 43 711716 3.88 PPBV # 94
49) Toluene 17.42 91 735501 3.96 PPBV 96
50) trans-1,3-Dichloropropene 17.71 75 363049 3.67 PPBV 98
51) 1,1,2-Trichloroethane 17.97 97 297529 3.96 PPBV 88
52) Tetrachloroethene 18.11 166 377200 3.95 PPBV 95
53) 2-Hexanone (Methyl butyl k 18.20 43 692092 4.15 PPBV # 91
54) Dibromochloromethane 18.44 129 563912 4.08 PPBV 99
55) 1,2-Dibromoethane 18.60 107 508341 3.97 PPBV 97
56) Chlorobenzene 19.12 112 644202 4.10 PPBV # 91
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201409.D L062912C.M Tue Jul 10 18:38:09 2012 Page 1
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201409.D Vial: 1
Acq On : 29 Jun 2012 8:10 pm Operator: DB
Sample : 3.3ppbv TO-15 std Inst : Lurch
Misc : 50mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:37 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:34:39 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Compound R.T. QIon Response Conc Unit Qvalue
-------------------------------------------------------------------------
57) Ethylbenzene 19.20 91 1020621 4.40 PPBV 100
58) 1,1,1,2-Tetrachloroethane 19.20 131 345522 3.92 PPBV 92
59) m-/p-Xylenes 19.32 91 1527259 8.50 PPBV 94
60) o-Xylene 19.70 91 806018 4.38 PPBV 93
61) Styrene 19.71 104 653780 4.32 PPBV 89
62) Bromoform 19.91 173 515547 4.13 PPBV 98
63) 1,1,2,2-Tetrachloroethane 20.27 83 691079 4.40 PPBV 98
64) 4-Ethyltoluene 20.47 105 1129703 4.41 PPBV 97
65) 2-Chlorotoluene 20.47 91 976740 4.28 PPBV 98
66) 1,3,5-Trimethylbenzene 20.51 105 872074 4.54 PPBV 97
67) 1,2,4-Trimethylbenzene 20.84 105 886969 4.41 PPBV 97
68) 1,3-Dichlorobenzene 21.11 146 626345 4.47 PPBV 97
69) 1,4-Dichlorobenzene 21.19 146 626318 4.39 PPBV 97
70) Benzyl chloride 21.27 91 911670 4.47 PPBV 94
71) 1,2-Dichlorobenzene 21.49 146 584283 4.44 PPBV 97
72) 1,2,4-Trichlorobenzene 22.86 180 363771 4.05 PPBV 98
73) Hexachlorobutadiene 22.96 225 251828 4.12 PPBV 98
74) Naphthalene 23.14 128 933238 3.77 PPBV # 79
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201409.D L062912C.M Tue Jul 10 18:38:10 2012 Page 2
Quantitation Report
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201404.D Vial: 1
Acq On : 29 Jun 2012 4:35 pm Operator: DB
Sample : 8.25ppbv TO-15 std Inst : Lurch
Misc : 125mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:38 2012 Quant Results File: L062912C.RES
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:37:47 2012
Response via : Initial Calibration
4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00
0
500000
1000000
1500000
2000000
2500000
3000000
3500000
4000000
4500000
5000000
5500000
6000000
6500000
7000000
7500000
8000000
8500000
9000000
Time-->
Abundance TIC: L1201404.D
NaphthaleneHexachlorobutadiene1,2,4-Trichlorobenzene1,2-DichlorobenzeneBenzyl chloride1,4-Dichlorobenzene1,3-Dichlorobenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene2-Chlorotoluene4-Ethyltoluene1,1,2,2-TetrachloroethaneBromoformStyreneo-Xylenem-/p-Xylenes1,1,1,2-TetrachloroethaneEthylbenzeneChlorobenzeneChlorobenzene-d5 (IS),I1,2-DibromoethaneDibromochloromethane2-Hexanone (Methyl butyl ketone)Tetrachloroethene1,1,2-Trichloroethanetrans-1,3-DichloropropeneTolueneMethyl isobutyl ketonecis-1,3-DichloropropeneBromodichloromethane1,4-DioxaneMethyl methacrylate1,2-DichloropropaneTrichloroethene1,4-Difluorobenzene (IS),IHeptane2,2,4-trimethylpentane1,2-DichloroethaneBenzeneCarbon tetrachlorideCyclohexane1,1,1-TrichloroethaneChloroformTetrahydrofuranBromochloromethane (IS),IEthyl acetatecis-1,2-DichloroethyleneMethyl ethyl ketone (2-Butanone)1,1-DichloroethaneVinyl acetateHexanetrans-1,2-DichloroetheneMethyl tert-butyl etherAcrylonitrileMethylene chlorideAllyl chloride (3-chloropropene)AcetonitrileCarbon disulfideIsopropyl alcoholAcetoneFreon 113 (C2Cl3F3)1,1-DichloroetheneAcroleinEthanolFreon 11 (CCl3F)Bromoethene (Vinyl bromide)ChloroethaneBromomethane1,3-ButadieneChloroethene (Vinyl chloride)ChloromethaneFreon 114 (C2Cl2F4)Freon 12 (CCl2F2)PropyleneL1201404.D L062912C.M Tue Jul 10 18:38:43 2012 Page 3
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201404.D Vial: 1
Acq On : 29 Jun 2012 4:35 pm Operator: DB
Sample : 8.25ppbv TO-15 std Inst : Lurch
Misc : 125mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:38 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:37:47 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) Bromochloromethane (IS) 13.08 130 565097 11.03 PPBV 0.00
36) 1,4-Difluorobenzene (IS) 14.87 114 2107927 10.52 PPBV -0.01
48) Chlorobenzene-d5 (IS) 19.07 117 2065230 11.20 PPBV -0.01
Target Compounds Qvalue
2) Propylene 4.71 41 533996 8.13 PPBV # 71
3) Freon 12 (CCl2F2) 4.81 85 1386386 7.58 PPBV 97
4) Freon 114 (C2Cl2F4) 5.19 85 1525617 7.71 PPBV # 93
5) Chloromethane 5.30 50 550215 7.67 PPBV 98
6) Chloroethene (Vinyl chlori 5.63 62 524082 7.81 PPBV 99
7) 1,3-Butadiene 5.75 39 497919 8.13 PPBV 88
8) Bromomethane 6.50 94 590840 7.85 PPBV 99
9) Chloroethane 6.79 64 285701 7.80 PPBV 100
10) Bromoethene (Vinyl bromide 7.27 106 522538 7.58 PPBV # 96
11) Freon 11 (CCl3F) 7.44 101 1230381 8.02 PPBV 99
12) Ethanol 7.87 45 172042 7.65 PPBV # 79
13) Acrolein 8.44 56 211248 8.73 PPBV 91
14) Freon 113 (C2Cl3F3) 8.70 151 619836 7.39 PPBV 98
15) 1,1-Dichloroethene 8.66 61 795795 7.66 PPBV 94
16) Acetone 8.77 43 1016053 7.79 PPBV # 81
17) Carbon disulfide 9.17 76 1357019 7.51 PPBV # 92
18) Isopropyl alcohol 9.12 45 1123921 8.40 PPBV # 86
19) Allyl chloride (3-chloropr 9.52 76 224114 7.83 PPBV # 50
20) Acetonitrile 9.38 41 459827 6.94 PPBV # 83
21) Methylene chloride 9.80 49 710123 7.11 PPBV # 79
22) trans-1,2-Dichloroethene 10.43 61 720274 7.59 PPBV 99
23) Methyl tert-butyl ether 10.43 73 1299569 7.96 PPBV # 88
24) Acrylonitrile 10.30 53 396375 7.57 PPBV # 90
25) Hexane 11.06 57 732865 7.84 PPBV # 78
26) 1,1-Dichloroethane 11.39 63 886609 7.72 PPBV 99
27) Vinyl acetate 11.39 43 1874218 8.25 PPBV 97
28) cis-1,2-Dichloroethylene 12.61 61 872287 7.87 PPBV 96
29) Methyl ethyl ketone (2-But 12.57 72 242069 8.14 PPBV 79
30) Ethyl acetate 12.66 45 205892 7.89 PPBV # 86
31) Chloroform 13.26 83 1066408 7.80 PPBV 98
32) Tetrahydrofuran 13.11 72 236752 8.11 PPBV # 60
33) 1,1,1-Trichloroethane 13.58 97 1051387 7.76 PPBV 95
34) Cyclohexane 13.72 56 776131 7.88 PPBV # 80
35) Carbon tetrachloride 13.86 117 1054929 7.66 PPBV 97
37) Benzene 14.21 78 1405360 7.90 PPBV # 94
38) 2,2,4-trimethylpentane 14.40 57 2356167 7.83 PPBV # 80
39) 1,2-Dichloroethane 14.28 62 720380 8.08 PPBV 100
40) Heptane 14.67 57 481500 8.18 PPBV 90
41) Trichloroethene 15.25 130 716796 7.96 PPBV # 89
42) 1,2-Dichloropropane 15.66 63 548043 8.09 PPBV 93
43) Methyl methacrylate 15.70 69 545213 8.11 PPBV # 89
44) 1,4-Dioxane 15.76 88 323757 7.86 PPBV # 82
45) Bromodichloromethane 16.08 83 1237891 8.04 PPBV # 96
46) cis-1,3-Dichloropropene 16.82 75 964626 8.35 PPBV 98
47) Methyl isobutyl ketone 17.04 43 1669002 8.46 PPBV # 94
49) Toluene 17.41 91 1709474 8.17 PPBV 95
50) trans-1,3-Dichloropropene 17.70 75 854158 7.67 PPBV 98
51) 1,1,2-Trichloroethane 17.97 97 700670 8.27 PPBV 88
52) Tetrachloroethene 18.11 166 884494 8.22 PPBV 96
53) 2-Hexanone (Methyl butyl k 18.19 43 1613195 8.60 PPBV # 91
54) Dibromochloromethane 18.44 129 1324425 8.51 PPBV 99
55) 1,2-Dibromoethane 18.59 107 1186413 8.22 PPBV 97
56) Chlorobenzene 19.11 112 1515611 8.56 PPBV 91
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201404.D L062912C.M Tue Jul 10 18:38:42 2012 Page 1
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201404.D Vial: 1
Acq On : 29 Jun 2012 4:35 pm Operator: DB
Sample : 8.25ppbv TO-15 std Inst : Lurch
Misc : 125mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:38 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:37:47 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Compound R.T. QIon Response Conc Unit Qvalue
-------------------------------------------------------------------------
57) Ethylbenzene 19.19 91 2362353 9.04 PPBV 99
58) 1,1,1,2-Tetrachloroethane 19.19 131 803883 8.09 PPBV 93
59) m-/p-Xylenes 19.31 91 3544366 17.50 PPBV 93
60) o-Xylene 19.70 91 1884755 9.10 PPBV 93
61) Styrene 19.71 104 1524974 8.95 PPBV 90
62) Bromoform 19.90 173 1214982 8.65 PPBV 99
63) 1,1,2,2-Tetrachloroethane 20.27 83 1605618 9.08 PPBV 98
64) 4-Ethyltoluene 20.47 105 2686357 9.31 PPBV 97
65) 2-Chlorotoluene 20.47 91 2289486 8.90 PPBV 99
66) 1,3,5-Trimethylbenzene 20.51 105 2028766 9.37 PPBV 96
67) 1,2,4-Trimethylbenzene 20.83 105 2090498 9.24 PPBV 97
68) 1,3-Dichlorobenzene 21.10 146 1490067 9.44 PPBV 97
69) 1,4-Dichlorobenzene 21.19 146 1482128 9.22 PPBV 97
70) Benzyl chloride 21.27 91 2145361 9.33 PPBV 94
71) 1,2-Dichlorobenzene 21.49 146 1367821 9.22 PPBV 97
72) 1,2,4-Trichlorobenzene 22.85 180 774232 7.64 PPBV 99
73) Hexachlorobutadiene 22.95 225 546773 7.93 PPBV 99
74) Naphthalene 23.14 128 1966866 7.05 PPBV # 79
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201404.D L062912C.M Tue Jul 10 18:38:42 2012 Page 2
Quantitation Report
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201405.D Vial: 1
Acq On : 29 Jun 2012 5:17 pm Operator: DB
Sample : 16.5ppbv TO-15 std Inst : Lurch
Misc : 250mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:39 2012 Quant Results File: L062912C.RES
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:39:51 2012
Response via : Initial Calibration
4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00
0
500000
1000000
1500000
2000000
2500000
3000000
3500000
4000000
4500000
5000000
5500000
6000000
6500000
7000000
7500000
8000000
8500000
9000000
9500000
1e+07
1.05e+07
1.1e+07
1.15e+07
1.2e+07
1.25e+07
1.3e+07
1.35e+07
1.4e+07
1.45e+07
1.5e+07
Time-->
Abundance TIC: L1201405.D
NaphthaleneHexachlorobutadiene1,2,4-Trichlorobenzene1,2-DichlorobenzeneBenzyl chloride1,4-Dichlorobenzene1,3-Dichlorobenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene4-Ethyltoluene2-Chlorotoluene1,1,2,2-TetrachloroethaneBromoformStyreneo-Xylenem-/p-Xylenes1,1,1,2-TetrachloroethaneEthylbenzeneChlorobenzeneChlorobenzene-d5 (IS),I1,2-DibromoethaneDibromochloromethane2-Hexanone (Methyl butyl ketone)Tetrachloroethene1,1,2-Trichloroethanetrans-1,3-DichloropropeneTolueneMethyl isobutyl ketonecis-1,3-DichloropropeneBromodichloromethane1,4-DioxaneMethyl methacrylate1,2-DichloropropaneTrichloroethene1,4-Difluorobenzene (IS),IHeptane2,2,4-trimethylpentane1,2-DichloroethaneBenzeneCarbon tetrachlorideCyclohexane1,1,1-TrichloroethaneChloroformTetrahydrofuranBromochloromethane (IS),IEthyl acetatecis-1,2-DichloroethyleneMethyl ethyl ketone (2-Butanone)1,1-DichloroethaneVinyl acetateHexanetrans-1,2-DichloroetheneMethyl tert-butyl etherAcrylonitrileMethylene chlorideAllyl chloride (3-chloropropene)AcetonitrileCarbon disulfideIsopropyl alcoholAcetoneFreon 113 (C2Cl3F3)1,1-DichloroetheneAcroleinEthanolFreon 11 (CCl3F)Bromoethene (Vinyl bromide)ChloroethaneBromomethane1,3-ButadieneChloroethene (Vinyl chloride)ChloromethaneFreon 114 (C2Cl2F4)Freon 12 (CCl2F2)PropyleneL1201405.D L062912C.M Tue Jul 10 18:39:57 2012 Page 3
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201405.D Vial: 1
Acq On : 29 Jun 2012 5:17 pm Operator: DB
Sample : 16.5ppbv TO-15 std Inst : Lurch
Misc : 250mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:39 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:39:32 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) Bromochloromethane (IS) 13.08 130 511785 11.03 PPBV 0.00
36) 1,4-Difluorobenzene (IS) 14.87 114 1899253 10.52 PPBV 0.00
48) Chlorobenzene-d5 (IS) 19.09 117 1845581 11.20 PPBV 0.01
Target Compounds Qvalue
2) Propylene 4.71 41 1048206 17.62 PPBV # 71
3) Freon 12 (CCl2F2) 4.81 85 2710421 16.37 PPBV 98
4) Freon 114 (C2Cl2F4) 5.20 85 2989111 16.68 PPBV # 94
5) Chloromethane 5.31 50 1095365 16.86 PPBV 98
6) Chloroethene (Vinyl chlori 5.63 62 1030764 16.97 PPBV 99
7) 1,3-Butadiene 5.75 39 972354 17.54 PPBV # 87
8) Bromomethane 6.50 94 1139816 16.72 PPBV 100
9) Chloroethane 6.80 64 546026 16.45 PPBV 100
10) Bromoethene (Vinyl bromide 7.27 106 1018302 16.30 PPBV # 96
11) Freon 11 (CCl3F) 7.44 101 2383120 17.15 PPBV 99
12) Ethanol 7.87 45 332454 16.32 PPBV # 77
13) Acrolein 8.44 56 417488 19.05 PPBV 90
14) Freon 113 (C2Cl3F3) 8.72 151 1222107 16.08 PPBV 98
15) 1,1-Dichloroethene 8.68 61 1547647 16.46 PPBV 93
16) Acetone 8.77 43 1945726 16.47 PPBV # 80
17) Carbon disulfide 9.18 76 2658184 16.24 PPBV # 92
18) Isopropyl alcohol 9.11 45 2186123 18.04 PPBV # 85
19) Allyl chloride (3-chloropr 9.53 76 439427 16.95 PPBV # 52
20) Acetonitrile 9.38 41 892855 14.89 PPBV # 83
21) Methylene chloride 9.81 49 1367281 15.12 PPBV # 80
22) trans-1,2-Dichloroethene 10.44 61 1413464 16.44 PPBV 99
23) Methyl tert-butyl ether 10.43 73 2562286 17.32 PPBV # 88
24) Acrylonitrile 10.31 53 780310 16.45 PPBV # 90
25) Hexane 11.06 57 1430368 16.89 PPBV # 78
26) 1,1-Dichloroethane 11.40 63 1735457 16.68 PPBV 98
27) Vinyl acetate 11.39 43 3643999 17.72 PPBV 98
28) cis-1,2-Dichloroethylene 12.61 61 1713710 17.08 PPBV 97
29) Methyl ethyl ketone (2-But 12.57 72 481251 17.88 PPBV 82
30) Ethyl acetate 12.66 45 403837 17.09 PPBV # 86
31) Chloroform 13.26 83 2101872 16.98 PPBV 98
32) Tetrahydrofuran 13.11 72 471610 17.84 PPBV # 62
33) 1,1,1-Trichloroethane 13.58 97 2078368 16.94 PPBV 96
34) Cyclohexane 13.73 56 1529900 17.16 PPBV # 80
35) Carbon tetrachloride 13.88 117 2073649 16.63 PPBV 97
37) Benzene 14.21 78 2781866 17.35 PPBV # 94
38) 2,2,4-trimethylpentane 14.40 57 4586675 16.91 PPBV # 80
39) 1,2-Dichloroethane 14.29 62 1386900 17.27 PPBV 99
40) Heptane 14.67 57 936258 17.65 PPBV 91
41) Trichloroethene 15.25 130 1432643 17.66 PPBV # 89
42) 1,2-Dichloropropane 15.68 63 1084740 17.77 PPBV 93
43) Methyl methacrylate 15.71 69 1083367 17.88 PPBV # 87
44) 1,4-Dioxane 15.77 88 640830 17.25 PPBV # 82
45) Bromodichloromethane 16.08 83 2436809 17.56 PPBV # 96
46) cis-1,3-Dichloropropene 16.82 75 1907822 18.33 PPBV 97
47) Methyl isobutyl ketone 17.04 43 3264899 18.36 PPBV # 94
49) Toluene 17.42 91 3403214 18.20 PPBV 95
50) trans-1,3-Dichloropropene 17.70 75 1699629 17.07 PPBV 98
51) 1,1,2-Trichloroethane 17.97 97 1373629 18.15 PPBV 88
52) Tetrachloroethene 18.11 166 1752926 18.24 PPBV 96
53) 2-Hexanone (Methyl butyl k 18.19 43 3147624 18.77 PPBV # 91
54) Dibromochloromethane 18.44 129 2597057 18.67 PPBV 99
55) 1,2-Dibromoethane 18.60 107 2348157 18.20 PPBV 97
56) Chlorobenzene 19.12 112 3000018 18.96 PPBV 93
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201405.D L062912C.M Tue Jul 10 18:39:57 2012 Page 1
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201405.D Vial: 1
Acq On : 29 Jun 2012 5:17 pm Operator: DB
Sample : 16.5ppbv TO-15 std Inst : Lurch
Misc : 250mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:39 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:39:32 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Compound R.T. QIon Response Conc Unit Qvalue
-------------------------------------------------------------------------
57) Ethylbenzene 19.20 91 4520884 19.37 PPBV 98
58) 1,1,1,2-Tetrachloroethane 19.20 131 1567810 17.66 PPBV 93
59) m-/p-Xylenes 19.33 91 6847120 37.84 PPBV 92
60) o-Xylene 19.70 91 3655566 19.74 PPBV 92
61) Styrene 19.71 104 2992602 19.65 PPBV 90
62) Bromoform 19.91 173 2407528 19.17 PPBV 99
63) 1,1,2,2-Tetrachloroethane 20.27 83 3127549 19.79 PPBV 97
64) 4-Ethyltoluene 20.48 105 5503138 21.34 PPBV 92
65) 2-Chlorotoluene 20.47 91 4355782 18.95 PPBV 99
66) 1,3,5-Trimethylbenzene 20.52 105 3569038 18.45 PPBV # 84
67) 1,2,4-Trimethylbenzene 20.84 105 4118810 20.36 PPBV 96
68) 1,3-Dichlorobenzene 21.11 146 2959459 20.99 PPBV 97
69) 1,4-Dichlorobenzene 21.19 146 2929218 20.38 PPBV 97
70) Benzyl chloride 21.27 91 4261076 20.73 PPBV 96
71) 1,2-Dichlorobenzene 21.50 146 2740624 20.67 PPBV 97
72) 1,2,4-Trichlorobenzene 22.86 180 1747050 19.30 PPBV 99
73) Hexachlorobutadiene 22.96 225 1172016 19.03 PPBV 98
74) Naphthalene 23.14 128 4347767 17.43 PPBV # 80
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201405.D L062912C.M Tue Jul 10 18:39:57 2012 Page 2
Quantitation Report
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201406.D Vial: 1
Acq On : 29 Jun 2012 6:03 pm Operator: DB
Sample : 33ppbv TO-15 std Inst : Lurch
Misc : 500mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:40 2012 Quant Results File: L062912C.RES
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:40:20 2012
Response via : Initial Calibration
4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00
0
1000000
2000000
3000000
4000000
5000000
6000000
7000000
8000000
9000000
1e+07
1.1e+07
1.2e+07
1.3e+07
1.4e+07
1.5e+07
1.6e+07
1.7e+07
1.8e+07
1.9e+07
2e+07
2.1e+07
2.2e+07
2.3e+07
2.4e+07
Time-->
Abundance TIC: L1201406.D
NaphthaleneHexachlorobutadiene1,2,4-Trichlorobenzene1,2-DichlorobenzeneBenzyl chloride1,4-Dichlorobenzene1,3-Dichlorobenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene2-Chlorotoluene4-Ethyltoluene1,1,2,2-TetrachloroethaneBromoformStyreneo-Xylenem-/p-XylenesEthylbenzene1,1,1,2-TetrachloroethaneChlorobenzeneChlorobenzene-d5 (IS),I1,2-DibromoethaneDibromochloromethane2-Hexanone (Methyl butyl ketone)Tetrachloroethene1,1,2-Trichloroethanetrans-1,3-DichloropropeneTolueneMethyl isobutyl ketonecis-1,3-DichloropropeneBromodichloromethane1,4-DioxaneMethyl methacrylate1,2-DichloropropaneTrichloroethene1,4-Difluorobenzene (IS),IHeptane2,2,4-trimethylpentane1,2-DichloroethaneBenzeneCarbon tetrachlorideCyclohexane1,1,1-TrichloroethaneChloroformTetrahydrofuranBromochloromethane (IS),IEthyl acetatecis-1,2-DichloroethyleneMethyl ethyl ketone (2-Butanone)1,1-DichloroethaneVinyl acetateHexanetrans-1,2-DichloroetheneMethyl tert-butyl etherAcrylonitrileMethylene chlorideAllyl chloride (3-chloropropene)AcetonitrileCarbon disulfideIsopropyl alcoholAcetoneFreon 113 (C2Cl3F3)1,1-DichloroetheneAcroleinEthanolFreon 11 (CCl3F)Bromoethene (Vinyl bromide)ChloroethaneBromomethane1,3-ButadieneChloroethene (Vinyl chloride)ChloromethaneFreon 114 (C2Cl2F4)Freon 12 (CCl2F2)PropyleneL1201406.D L062912C.M Tue Jul 10 18:40:28 2012 Page 3
Quantitation Report (Not Reviewed)
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201406.D Vial: 1
Acq On : 29 Jun 2012 6:03 pm Operator: DB
Sample : 33ppbv TO-15 std Inst : Lurch
Misc : 500mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:40 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:39:51 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) Bromochloromethane (IS) 13.08 130 528136 11.03 PPBV 0.00
36) 1,4-Difluorobenzene (IS) 14.88 114 1943308 10.52 PPBV 0.00
48) Chlorobenzene-d5 (IS) 19.08 117 1862242 11.20 PPBV 0.00
Target Compounds Qvalue
2) Propylene 4.71 41 2049504 33.39 PPBV # 71
3) Freon 12 (CCl2F2) 4.81 85 5232600 30.62 PPBV 98
4) Freon 114 (C2Cl2F4) 5.19 85 5785251 31.29 PPBV # 94
5) Chloromethane 5.30 50 2116264 31.57 PPBV 98
6) Chloroethene (Vinyl chlori 5.63 62 2031117 32.40 PPBV 100
7) 1,3-Butadiene 5.75 39 1878146 32.82 PPBV # 86
8) Bromomethane 6.50 94 2249964 31.99 PPBV 99
9) Chloroethane 6.80 64 1084210 31.65 PPBV 100
10) Bromoethene (Vinyl bromide 7.26 106 2004093 31.09 PPBV # 96
11) Freon 11 (CCl3F) 7.44 101 4596987 32.06 PPBV 99
12) Ethanol 7.87 45 664813 31.63 PPBV # 77
13) Acrolein 8.44 56 840345 37.16 PPBV 91
14) Freon 113 (C2Cl3F3) 8.71 151 2427220 30.94 PPBV 99
15) 1,1-Dichloroethene 8.67 61 3049811 31.43 PPBV 92
16) Acetone 8.77 43 3844812 31.54 PPBV # 80
17) Carbon disulfide 9.18 76 5274579 31.22 PPBV # 92
18) Isopropyl alcohol 9.12 45 4161992 33.28 PPBV # 86
19) Allyl chloride (3-chloropr 9.53 76 880710 32.91 PPBV # 52
20) Acetonitrile 9.38 41 1801670 29.11 PPBV # 83
21) Methylene chloride 9.81 49 2670846 28.62 PPBV # 81
22) trans-1,2-Dichloroethene 10.43 61 2794180 31.49 PPBV 98
23) Methyl tert-butyl ether 10.43 73 5102963 33.43 PPBV # 89
24) Acrylonitrile 10.31 53 1573732 32.14 PPBV # 90
25) Hexane 11.06 57 2848964 32.60 PPBV # 78
26) 1,1-Dichloroethane 11.40 63 3447522 32.12 PPBV 98
27) Vinyl acetate 11.40 43 7089597 33.41 PPBV 99
28) cis-1,2-Dichloroethylene 12.61 61 3399712 32.84 PPBV 97
29) Methyl ethyl ketone (2-But 12.58 72 962316 34.64 PPBV 87
30) Ethyl acetate 12.67 45 800399 32.83 PPBV # 87
31) Chloroform 13.26 83 4182525 32.74 PPBV 97
32) Tetrahydrofuran 13.12 72 942611 34.55 PPBV # 64
33) 1,1,1-Trichloroethane 13.59 97 4123153 32.56 PPBV 96
34) Cyclohexane 13.73 56 3039707 33.03 PPBV # 81
35) Carbon tetrachloride 13.87 117 4100420 31.87 PPBV 97
37) Benzene 14.20 78 5490414 33.47 PPBV # 94
38) 2,2,4-trimethylpentane 14.40 57 8886727 32.02 PPBV # 80
39) 1,2-Dichloroethane 14.28 62 2778288 33.81 PPBV 98
40) Heptane 14.68 57 1839094 33.89 PPBV 92
41) Trichloroethene 15.26 130 2870236 34.57 PPBV # 89
42) 1,2-Dichloropropane 15.67 63 2117748 33.91 PPBV 93
43) Methyl methacrylate 15.71 69 2149674 34.68 PPBV # 85
44) 1,4-Dioxane 15.76 88 1304187 34.30 PPBV # 83
45) Bromodichloromethane 16.09 83 4816920 33.93 PPBV # 96
46) cis-1,3-Dichloropropene 16.82 75 3817352 35.84 PPBV 97
47) Methyl isobutyl ketone 17.04 43 6296019 34.60 PPBV # 93
49) Toluene 17.41 91 6616636 35.07 PPBV 94
50) trans-1,3-Dichloropropene 17.70 75 3376819 33.62 PPBV 99
51) 1,1,2-Trichloroethane 17.97 97 2714810 35.55 PPBV 87
52) Tetrachloroethene 18.11 166 3371954 34.77 PPBV 96
53) 2-Hexanone (Methyl butyl k 18.20 43 5945478 35.14 PPBV 91
54) Dibromochloromethane 18.45 129 5038035 35.90 PPBV 98
55) 1,2-Dibromoethane 18.60 107 4603957 35.36 PPBV 97
56) Chlorobenzene 19.11 112 5857369 36.68 PPBV 93
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201406.D L062912C.M Tue Jul 10 18:40:28 2012 Page 1
Quantitation Report (Not Reviewed)
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201406.D Vial: 1
Acq On : 29 Jun 2012 6:03 pm Operator: DB
Sample : 33ppbv TO-15 std Inst : Lurch
Misc : 500mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:40 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:39:51 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Compound R.T. QIon Response Conc Unit Qvalue
-------------------------------------------------------------------------
57) Ethylbenzene 19.20 91 7724903 32.80 PPBV 96
58) 1,1,1,2-Tetrachloroethane 19.19 131 2836930 31.67 PPBV 93
59) m-/p-Xylenes 19.32 91 12377413 67.78 PPBV 89
60) o-Xylene 19.70 91 6755526 36.16 PPBV 90
61) Styrene 19.72 104 5616483 36.54 PPBV # 89
62) Bromoform 19.91 173 4484743 35.39 PPBV 99
63) 1,1,2,2-Tetrachloroethane 20.27 83 5964619 37.41 PPBV 96
64) 4-Ethyltoluene 20.48 105 8831152 33.93 PPBV 99
65) 2-Chlorotoluene 20.48 91 7361140 31.74 PPBV 100
66) 1,3,5-Trimethylbenzene 20.52 105 7232750 37.05 PPBV 93
67) 1,2,4-Trimethylbenzene 20.84 105 7776711 38.10 PPBV 95
68) 1,3-Dichlorobenzene 21.11 146 5630909 39.58 PPBV 97
69) 1,4-Dichlorobenzene 21.19 146 5584798 38.51 PPBV 97
70) Benzyl chloride 21.28 91 8203559 39.56 PPBV 97
71) 1,2-Dichlorobenzene 21.50 146 5306742 39.66 PPBV 97
72) 1,2,4-Trichlorobenzene 22.86 180 3646984 39.93 PPBV 99
73) Hexachlorobutadiene 22.95 225 2260394 36.37 PPBV 98
74) Naphthalene 23.15 128 9044262 35.93 PPBV # 80
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201406.D L062912C.M Tue Jul 10 18:40:28 2012 Page 2
Quantitation Report
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201407.D Vial: 1
Acq On : 29 Jun 2012 6:53 pm Operator: DB
Sample : 49.5ppbv TO-15 std Inst : Lurch
Misc : 750mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:40 2012 Quant Results File: L062912C.RES
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00
0
1000000
2000000
3000000
4000000
5000000
6000000
7000000
8000000
9000000
1e+07
1.1e+07
1.2e+07
1.3e+07
1.4e+07
1.5e+07
1.6e+07
1.7e+07
1.8e+07
1.9e+07
2e+07
2.1e+07
2.2e+07
2.3e+07
2.4e+07
2.5e+07
2.6e+07
Time-->
Abundance TIC: L1201407.D
NaphthaleneHexachlorobutadiene1,2,4-Trichlorobenzene1,2-DichlorobenzeneBenzyl chloride1,4-Dichlorobenzene1,3-Dichlorobenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene2-Chlorotoluene4-Ethyltoluene1,1,2,2-TetrachloroethaneBromoformStyreneo-Xylenem-/p-XylenesEthylbenzene1,1,1,2-TetrachloroethaneChlorobenzeneChlorobenzene-d5 (IS),I1,2-DibromoethaneDibromochloromethane2-Hexanone (Methyl butyl ketone)Tetrachloroethene1,1,2-Trichloroethanetrans-1,3-DichloropropeneTolueneMethyl isobutyl ketonecis-1,3-DichloropropeneBromodichloromethane1,4-DioxaneMethyl methacrylate1,2-DichloropropaneTrichloroethene1,4-Difluorobenzene (IS),IHeptane2,2,4-trimethylpentane1,2-DichloroethaneBenzeneCarbon tetrachlorideCyclohexane1,1,1-TrichloroethaneChloroformTetrahydrofuranBromochloromethane (IS),IEthyl acetatecis-1,2-DichloroethyleneMethyl ethyl ketone (2-Butanone)1,1-DichloroethaneVinyl acetateHexanetrans-1,2-DichloroetheneMethyl tert-butyl etherAcrylonitrileMethylene chlorideAllyl chloride (3-chloropropene)AcetonitrileCarbon disulfideIsopropyl alcoholAcetoneFreon 113 (C2Cl3F3)1,1-DichloroetheneAcroleinEthanolFreon 11 (CCl3F)Bromoethene (Vinyl bromide)ChloroethaneBromomethane1,3-ButadieneChloroethene (Vinyl chloride)ChloromethaneFreon 114 (C2Cl2F4)Freon 12 (CCl2F2)PropyleneL1201407.D L062912C.M Tue Jul 10 18:41:06 2012 Page 3
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201407.D Vial: 1
Acq On : 29 Jun 2012 6:53 pm Operator: DB
Sample : 49.5ppbv TO-15 std Inst : Lurch
Misc : 750mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:40 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:40:20 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) Bromochloromethane (IS) 13.08 130 551135 11.03 PPBV 0.00
36) 1,4-Difluorobenzene (IS) 14.88 114 2054023 10.52 PPBV 0.00
48) Chlorobenzene-d5 (IS) 19.08 117 1929586 11.20 PPBV 0.00
Target Compounds Qvalue
2) Propylene 4.71 41 3014596 47.06 PPBV # 71
3) Freon 12 (CCl2F2) 4.81 85 7631751 42.80 PPBV 99
4) Freon 114 (C2Cl2F4) 5.19 85 8392425 43.50 PPBV # 95
5) Chloromethane 5.31 50 3150344 45.03 PPBV 98
6) Chloroethene (Vinyl chlori 5.63 62 2972703 45.43 PPBV 100
7) 1,3-Butadiene 5.76 39 2774617 46.47 PPBV # 86
8) Bromomethane 6.51 94 3327129 45.33 PPBV 100
9) Chloroethane 6.80 64 1633094 45.69 PPBV 100
10) Bromoethene (Vinyl bromide 7.26 106 2995425 44.53 PPBV # 96
11) Freon 11 (CCl3F) 7.44 101 6660123 44.50 PPBV 100
12) Ethanol 7.88 45 999728 45.58 PPBV # 77
13) Acrolein 8.45 56 1286056 54.49 PPBV 90
14) Freon 113 (C2Cl3F3) 8.71 151 3663176 44.75 PPBV 99
15) 1,1-Dichloroethene 8.67 61 4574493 45.18 PPBV 90
16) Acetone 8.77 43 5790162 45.51 PPBV # 80
17) Carbon disulfide 9.18 76 7905053 44.84 PPBV # 92
18) Isopropyl alcohol 9.12 45 6224536 47.69 PPBV # 86
19) Allyl chloride (3-chloropr 9.53 76 1331969 47.70 PPBV # 55
20) Acetonitrile 9.39 41 2752398 42.62 PPBV # 83
21) Methylene chloride 9.81 49 4007278 41.15 PPBV # 81
22) trans-1,2-Dichloroethene 10.43 61 4153875 44.87 PPBV 97
23) Methyl tert-butyl ether 10.43 73 7607520 47.76 PPBV # 89
24) Acrylonitrile 10.31 53 2391453 46.81 PPBV # 90
25) Hexane 11.06 57 4246809 46.56 PPBV # 79
26) 1,1-Dichloroethane 11.40 63 5144649 45.93 PPBV 98
27) Vinyl acetate 11.40 43 10295320 46.49 PPBV 100
28) cis-1,2-Dichloroethylene 12.60 61 5093665 47.15 PPBV 98
29) Methyl ethyl ketone (2-But 12.57 72 1448309 49.96 PPBV 92
30) Ethyl acetate 12.67 45 1187453 46.68 PPBV # 88
31) Chloroform 13.26 83 6229706 46.73 PPBV 97
32) Tetrahydrofuran 13.12 72 1440045 50.58 PPBV # 66
33) 1,1,1-Trichloroethane 13.59 97 6110910 46.25 PPBV 96
34) Cyclohexane 13.73 56 4471773 46.57 PPBV # 82
35) Carbon tetrachloride 13.87 117 6038251 44.98 PPBV 97
37) Benzene 14.20 78 8117642 46.81 PPBV # 94
38) 2,2,4-trimethylpentane 14.40 57 12944538 44.13 PPBV # 80
39) 1,2-Dichloroethane 14.28 62 4144568 47.71 PPBV 98
40) Heptane 14.68 57 2704036 47.14 PPBV 93
41) Trichloroethene 15.26 130 4247318 48.40 PPBV # 89
42) 1,2-Dichloropropane 15.67 63 3120675 47.27 PPBV 93
43) Methyl methacrylate 15.71 69 3149658 48.07 PPBV # 84
44) 1,4-Dioxane 15.76 88 2005673 49.91 PPBV # 83
45) Bromodichloromethane 16.08 83 7071200 47.13 PPBV # 96
46) cis-1,3-Dichloropropene 16.82 75 5647333 50.17 PPBV 97
47) Methyl isobutyl ketone 17.05 43 9166225 47.66 PPBV # 93
49) Toluene 17.41 91 9762631 49.93 PPBV 93
50) trans-1,3-Dichloropropene 17.70 75 4978159 47.83 PPBV 98
51) 1,1,2-Trichloroethane 17.98 97 3986083 50.38 PPBV 87
52) Tetrachloroethene 18.11 166 4701277 46.78 PPBV 97
53) 2-Hexanone (Methyl butyl k 18.20 43 8453901 48.22 PPBV # 90
54) Dibromochloromethane 18.45 129 7130737 49.03 PPBV 97
55) 1,2-Dibromoethane 18.60 107 6660135 49.37 PPBV 97
56) Chlorobenzene 19.11 112 8422020 50.90 PPBV 94
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201407.D L062912C.M Tue Jul 10 18:41:05 2012 Page 1
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201407.D Vial: 1
Acq On : 29 Jun 2012 6:53 pm Operator: DB
Sample : 49.5ppbv TO-15 std Inst : Lurch
Misc : 750mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:40 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:40:20 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Compound R.T. QIon Response Conc Unit Qvalue
-------------------------------------------------------------------------
57) Ethylbenzene 19.20 91 9570551 39.22 PPBV 94
58) 1,1,1,2-Tetrachloroethane 19.19 131 3759675 40.50 PPBV 94
59) m-/p-Xylenes 19.32 91 15518944 82.02 PPBV 86
60) o-Xylene 19.70 91 8749755 45.20 PPBV 88
61) Styrene 19.72 104 7375041 46.31 PPBV # 90
62) Bromoform 19.91 173 6058978 46.15 PPBV 100
63) 1,1,2,2-Tetrachloroethane 20.28 83 8151087 49.34 PPBV 96
64) 4-Ethyltoluene 20.48 105 10590794 39.27 PPBV 98
65) 2-Chlorotoluene 20.48 91 9136229 38.02 PPBV 98
66) 1,3,5-Trimethylbenzene 20.52 105 10068990 49.78 PPBV 92
67) 1,2,4-Trimethylbenzene 20.84 105 10575165 50.00 PPBV 93
68) 1,3-Dichlorobenzene 21.11 146 7753839 52.60 PPBV 97
69) 1,4-Dichlorobenzene 21.19 146 7714217 51.34 PPBV 97
70) Benzyl chloride 21.27 91 11274262 52.47 PPBV 100
71) 1,2-Dichlorobenzene 21.50 146 7330026 52.87 PPBV 96
72) 1,2,4-Trichlorobenzene 22.86 180 5259093 55.57 PPBV 99
73) Hexachlorobutadiene 22.96 225 3061459 47.54 PPBV 98
74) Naphthalene 23.15 128 13162334 50.47 PPBV # 82
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201407.D L062912C.M Tue Jul 10 18:41:05 2012 Page 2
Quantitation Report
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201410.D Vial: 1
Acq On : 29 Jun 2012 8:50 pm Operator: DB
Sample : 8.25ppbv TO-15 ICV std Inst : Lurch
Misc : 125mL load, can #1414 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:52 2012 Quant Results File: L062912C.RES
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00
0
500000
1000000
1500000
2000000
2500000
3000000
3500000
4000000
4500000
5000000
5500000
6000000
6500000
7000000
7500000
Time-->
Abundance TIC: L1201410.D
NaphthaleneHexachlorobutadiene1,2,4-Trichlorobenzene1,2-DichlorobenzeneBenzyl chloride1,4-Dichlorobenzene1,3-Dichlorobenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene4-Ethyltoluene2-Chlorotoluene1,1,2,2-TetrachloroethaneBromoformStyreneo-Xylenem-/p-Xylenes1,1,1,2-TetrachloroethaneEthylbenzeneChlorobenzeneChlorobenzene-d5 (IS),I1,2-DibromoethaneDibromochloromethane2-Hexanone (Methyl butyl ketone)Tetrachloroethene1,1,2-Trichloroethanetrans-1,3-DichloropropeneTolueneMethyl isobutyl ketonecis-1,3-DichloropropeneBromodichloromethane1,4-DioxaneMethyl methacrylate1,2-DichloropropaneTrichloroethene1,4-Difluorobenzene (IS),IHeptane2,2,4-trimethylpentane1,2-DichloroethaneBenzeneCarbon tetrachlorideCyclohexane1,1,1-TrichloroethaneChloroformTetrahydrofuranBromochloromethane (IS),IEthyl acetatecis-1,2-DichloroethyleneMethyl ethyl ketone (2-Butanone)Vinyl acetate1,1-DichloroethaneHexanetrans-1,2-DichloroetheneMethyl tert-butyl etherAcrylonitrileMethylene chlorideAllyl chloride (3-chloropropene)AcetonitrileCarbon disulfideIsopropyl alcoholAcetoneFreon 113 (C2Cl3F3)1,1-DichloroetheneAcroleinEthanolFreon 11 (CCl3F)Bromoethene (Vinyl bromide)ChloroethaneBromomethane1,3-ButadieneChloroethene (Vinyl chloride)ChloromethaneFreon 114 (C2Cl2F4)Freon 12 (CCl2F2)PropyleneL1201410.D L062912C.M Tue Jul 10 18:52:38 2012 Page 3
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201410.D Vial: 1
Acq On : 29 Jun 2012 8:50 pm Operator: DB
Sample : 8.25ppbv TO-15 ICV std Inst : Lurch
Misc : 125mL load, can #1414 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:52 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) Bromochloromethane (IS) 13.08 130 537310 11.03 PPBV 0.00
36) 1,4-Difluorobenzene (IS) 14.88 114 2013301 10.52 PPBV 0.00
48) Chlorobenzene-d5 (IS) 19.08 117 1900220 11.20 PPBV 0.00
Target Compounds Qvalue
2) Propylene 4.70 41 498900 7.99 PPBV # 71
3) Freon 12 (CCl2F2) 4.80 85 1288859 7.41 PPBV 98
4) Freon 114 (C2Cl2F4) 5.18 85 1427781 7.59 PPBV # 93
5) Chloromethane 5.30 50 519733 7.62 PPBV 99
6) Chloroethene (Vinyl chlori 5.62 62 494985 7.76 PPBV 99
7) 1,3-Butadiene 5.74 39 468306 8.04 PPBV # 88
8) Bromomethane 6.50 94 541011 7.56 PPBV 98
9) Chloroethane 6.79 64 260464 7.47 PPBV 99
10) Bromoethene (Vinyl bromide 7.26 106 484101 7.38 PPBV # 96
11) Freon 11 (CCl3F) 7.44 101 1147535 7.87 PPBV 99
12) Ethanol 7.87 45 130716 6.11 PPBV # 78
13) Acrolein 8.44 56 178518 7.76 PPBV 90
14) Freon 113 (C2Cl3F3) 8.70 151 584589 7.33 PPBV 98
15) 1,1-Dichloroethene 8.66 61 702124 7.11 PPBV 89
16) Acetone 8.76 43 947874 7.64 PPBV # 80
17) Carbon disulfide 9.17 76 1270709 7.39 PPBV # 92
18) Isopropyl alcohol 9.12 45 914131 7.18 PPBV # 86
19) Allyl chloride (3-chloropr 9.52 76 205656 7.55 PPBV # 50
20) Acetonitrile 9.38 41 411882 6.54 PPBV # 83
21) Methylene chloride 9.80 49 660259 6.95 PPBV # 79
22) trans-1,2-Dichloroethene 10.43 61 674328 7.47 PPBV 99
23) Methyl tert-butyl ether 10.43 73 1214626 7.82 PPBV # 87
24) Acrylonitrile 10.31 53 361740 7.26 PPBV # 90
25) Hexane 11.05 57 683473 7.69 PPBV # 78
26) 1,1-Dichloroethane 11.39 63 832791 7.63 PPBV 99
27) Vinyl acetate 11.40 43 1747230 8.09 PPBV 97
28) cis-1,2-Dichloroethylene 12.61 61 816237 7.75 PPBV 96
29) Methyl ethyl ketone (2-But 12.58 72 226013 8.00 PPBV 83
30) Ethyl acetate 12.67 45 190204 7.67 PPBV # 85
31) Chloroform 13.26 83 1005351 7.73 PPBV 99
32) Tetrahydrofuran 13.12 72 217917 7.85 PPBV # 59
33) 1,1,1-Trichloroethane 13.58 97 983180 7.63 PPBV 96
34) Cyclohexane 13.73 56 731759 7.82 PPBV # 79
35) Carbon tetrachloride 13.87 117 978771 7.48 PPBV 97
37) Benzene 14.21 78 1319255 7.76 PPBV # 93
38) 2,2,4-trimethylpentane 14.40 57 2190326 7.62 PPBV # 80
39) 1,2-Dichloroethane 14.29 62 655806 7.70 PPBV 99
40) Heptane 14.67 57 444883 7.91 PPBV 90
41) Trichloroethene 15.25 130 675006 7.85 PPBV # 89
42) 1,2-Dichloropropane 15.67 63 521112 8.05 PPBV 94
43) Methyl methacrylate 15.70 69 513761 8.00 PPBV # 87
44) 1,4-Dioxane 15.76 88 259518 6.59 PPBV # 81
45) Bromodichloromethane 16.08 83 1162162 7.90 PPBV # 96
46) cis-1,3-Dichloropropene 16.82 75 898114 8.14 PPBV 97
47) Methyl isobutyl ketone 17.04 43 1548814 8.22 PPBV # 94
49) Toluene 17.41 91 1593716 8.28 PPBV 95
50) trans-1,3-Dichloropropene 17.71 75 796094 7.77 PPBV 98
51) 1,1,2-Trichloroethane 17.97 97 654838 8.40 PPBV 88
52) Tetrachloroethene 18.11 166 823373 8.32 PPBV 96
53) 2-Hexanone (Methyl butyl k 18.20 43 1529155 8.86 PPBV # 91
54) Dibromochloromethane 18.44 129 1230540 8.59 PPBV 99
55) 1,2-Dibromoethane 18.60 107 1102509 8.30 PPBV 97
56) Chlorobenzene 19.11 112 1401829 8.60 PPBV 91
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201410.D L062912C.M Tue Jul 10 18:52:37 2012 Page 1
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201410.D Vial: 1
Acq On : 29 Jun 2012 8:50 pm Operator: DB
Sample : 8.25ppbv TO-15 ICV std Inst : Lurch
Misc : 125mL load, can #1414 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 10 18:52 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Compound R.T. QIon Response Conc Unit Qvalue
-------------------------------------------------------------------------
57) Ethylbenzene 19.19 91 2189132 9.11 PPBV 99
58) 1,1,1,2-Tetrachloroethane 19.19 131 736232 8.05 PPBV 92
59) m-/p-Xylenes 19.33 91 3262536 17.51 PPBV 94
60) o-Xylene 19.70 91 1727473 9.06 PPBV 93
61) Styrene 19.71 104 1403297 8.95 PPBV 90
62) Bromoform 19.91 173 1117318 8.64 PPBV 98
63) 1,1,2,2-Tetrachloroethane 20.27 83 1460898 8.98 PPBV 97
64) 4-Ethyltoluene 20.48 105 2597671 9.78 PPBV 92
65) 2-Chlorotoluene 20.47 91 2079625 8.79 PPBV 98
66) 1,3,5-Trimethylbenzene 20.52 105 1670846 8.39 PPBV 86
67) 1,2,4-Trimethylbenzene 20.83 105 1904610 9.14 PPBV 97
68) 1,3-Dichlorobenzene 21.11 146 1331108 9.17 PPBV 97
69) 1,4-Dichlorobenzene 21.19 146 1314567 8.88 PPBV 97
70) Benzyl chloride 21.27 91 1901370 8.99 PPBV 94
71) 1,2-Dichlorobenzene 21.50 146 1220676 8.94 PPBV 97
72) 1,2,4-Trichlorobenzene 22.86 180 710233 7.62 PPBV 99
73) Hexachlorobutadiene 22.96 225 516625 8.15 PPBV 98
74) Naphthalene 23.14 128 1802834 7.02 PPBV # 79
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201410.D L062912C.M Tue Jul 10 18:52:37 2012 Page 2
Sample ID:DF: 1.00
Data File: L1201410.D Tank DF: 1.00
Tank/Misc ID:ConCal 1
Quant
Ret.
Time
(min)
Area
Conc. as
Analyzed
(ppbv)
Sample
Conc.
(ppbv)
Flags Tag Value
% Diff.
From Tag Pass/Fail
41 4.70 498,900 7.99 7.99 9.08 12.0 PASS
85 4.80 1,288,859 7.41 7.41 8.17 9.2 PASS
85 5.18 1,427,781 7.59 7.59 8.33 8.9 PASS
50 5.30 519,733 7.62 7.62 8.42 9.4 PASS
62 5.62 494,985 7.76 7.76 8.42 7.8 PASS
39 5.74 468,306 8.04 8.04 8.75 8.0 PASS
94 6.50 541,011 7.56 7.56 8.42 10.2 PASS
64 6.79 260,464 7.47 7.47 8.33 10.3 PASS
106 7.26 484,101 7.38 7.38 8.25 10.5 PASS
101 7.44 1,147,535 7.87 7.87 8.66 9.2 PASS
45 7.87 130,716 6.11 6.11 8.42 27.4 PASS
56 8.44 178,518 7.76 7.76 8.99 13.7 PASS
151 8.70 584,589 7.33 7.33 8.09 9.4 PASS
61 8.66 702,124 7.11 7.11 8.17 12.9 PASS
43 8.76 947,874 7.64 7.64 8.66 11.8 PASS
76 9.17 1,270,709 7.39 7.39 8.17 9.5 PASS
45 9.12 914,131 7.18 7.18 8.99 20.1 PASS
76 9.52 205,656 7.55 7.55 8.50 11.1 PASS
41 9.38 411,882 6.54 6.54 7.59 13.8 PASS
49 9.80 660,259 6.95 6.95 8.33 16.5 PASS
61 10.43 674,328 7.47 7.47 8.25 9.4 PASS
73 10.43 1,214,626 7.82 7.82 8.66 9.7 PASS
53 10.31 361,740 7.26 7.26 8.25 12.0 PASS
57 11.05 683,473 7.69 7.69 8.58 10.4 PASS
63 11.39 832,791 7.63 7.63 8.42 9.4 PASS
43 11.40 1,747,230 8.09 8.09 8.83 8.3 PASS
61 12.61 816,237 7.75 7.75 8.58 9.7 PASS
72 12.58 226,013 8.00 8.00 8.83 9.4 PASS
45 12.67 190,204 7.67 7.67 8.50 9.8 PASS
83 13.26 1,005,351 7.73 7.73 8.50 9.0 PASS
72 13.12 217,917 7.85 7.85 8.83 11.1 PASS
97 13.58 983,180 7.63 7.63 8.50 10.2 PASS
56 13.73 731,759 7.82 7.82 8.58 8.9 PASS
117 13.87 978,771 7.48 7.48 8.33 10.3 PASS
78 14.21 1,319,255 7.76 7.76 8.58 9.5 PASS
57 14.40 2,190,326 7.62 7.62 8.42 9.5 PASS
62 14.29 655,806 7.70 7.70 8.66 11.1 PASS
57 14.67 444,883 7.91 7.91 8.75 9.5 PASS
130 15.25 675,006 7.85 7.85 8.66 9.4 PASS
63 15.67 521,112 8.05 8.05 8.75 7.9 PASS
69 15.70 513,761 8.00 8.00 8.75 8.5 PASS
88 15.76 259,518 6.59 6.59 8.66 23.9 PASS
83 16.08 1,162,162 7.90 7.90 8.66 8.8 PASS
75 16.82 898,114 8.14 8.14 8.99 9.5 PASS
43 17.04 1,548,814 8.22 8.22 8.92 7.9 PASS
91 17.41 1,593,716 8.28 8.28 8.83 6.2 PASS
75 17.71 796,094 7.77 7.77 8.25 5.8 PASS
97 17.97 654,838 8.40 8.40 8.83 4.8 PASS
cis-1,3-Dichloropropene
Methyl isobutyl ketone
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Benzene
2,2,4-trimethylpentane
1,2-Dichloroethane
Heptane
Trichloroethene
1,2-Dichloropropane
Methyl methacrylate
1,4-Dioxane
Bromodichloromethane
Tetrahydrofuran
1,1,1-Trichloroethane
Cyclohexane
Carbon tetrachloride
cis-1,2-Dichloroethylene
Methyl ethyl ketone (2-Butanone)
Ethyl acetate
Chloroform
Acrylonitrile
Hexane
1,1-Dichloroethane
Vinyl acetate
Acetonitrile
Methylene chloride
trans-1,2-Dichloroethene
Methyl tert-butyl ether
Acetone
Carbon disulfide
Isopropyl alcohol
Allyl chloride (3-chloropropene)
Ethanol
Acrolein
Freon 113 (C2Cl3F3)
1,1-Dichloroethene
Bromomethane
Chloroethane
Bromoethene (Vinyl bromide)
Freon 11 (CCl3F)
Compound
5.0ppbv TO-15 ICV std
125mL load, can #1414
Propylene
Freon 12 (CCl2F2)
Freon 114 (C2Cl2F4)
Chloromethane
Chloroethene (Vinyl chloride)
1,3-Butadiene
Company
Analyst
Parameters
In House
DB
EPA Method TO-15 TCL
Client #
Job #
# Samples
TO-15 ICV
NA
NA
0612-20 RWsummaries REDO.xls 7/10/2012
Sample ID:DF: 1.00
Data File: L1201410.D Tank DF: 1.00
Tank/Misc ID:ConCal 1
Quant
Ret.
Time
(min)
Area
Conc. as
Analyzed
(ppbv)
Sample
Conc.
(ppbv)
Flags Tag Value
% Diff.
From Tag Pass/FailCompound
5.0ppbv TO-15 ICV std
125mL load, can #1414
Company
Analyst
Parameters
In House
DB
EPA Method TO-15 TCL
Client #
Job #
# Samples
TO-15 ICV
NA
NA
166 18.11 823,373 8.32 8.32 8.66 4.0 PASS
43 18.20 1,529,155 8.86 8.86 8.99 1.5 PASS
129 18.44 1,230,540 8.59 8.59 8.99 4.4 PASS
107 18.60 1,102,509 8.30 8.30 8.75 5.1 PASS
112 19.11 1,401,829 8.60 8.60 8.99 4.3 PASS
91 19.19 2,189,132 9.11 9.11 8.91 2.2 PASS
131 19.19 736,232 8.05 8.05 8.25 2.4 PASS
91 19.33 3,262,536 17.5 17.5 17.5 0.1 PASS
91 19.70 1,727,473 9.06 9.06 9.08 0.1 PASS
104 19.71 1,403,297 8.95 8.95 8.99 0.5 PASS
173 19.91 1,117,318 8.64 8.64 8.75 1.2 PASS
83 20.27 1,460,898 8.98 8.98 9.08 1.0 PASS
105 20.48 2,597,671 9.78 9.78 8.75 11.9 PASS
91 20.47 2,079,625 8.79 8.79 8.33 5.5 PASS
105 20.52 1,670,846 8.39 8.39 8.91 5.9 PASS
105 20.83 1,904,610 9.15 9.15 8.91 2.6 PASS
146 21.11 1,331,108 9.17 9.17 9.08 1.0 PASS
146 21.19 1,314,567 8.88 8.88 8.83 0.6 PASS
91 21.27 1,901,370 8.99 8.99 9.08 1.0 PASS
146 21.50 1,220,676 8.94 8.94 8.91 0.3 PASS
180 22.86 710,233 7.62 7.62 8.75 12.9 PASS
225 22.96 516,625 8.15 8.15 8.75 6.8 PASS
128 23.14 1,802,834 7.02 7.02 8.09 13.2 PASS
Rec. (%) Flags
130 13.08 537,310 11.03 N/A
114 14.88 2,013,301 10.52 N/A
117 19.08 1,900,220 11.20 N/A
Internal Standard Acceptance Criteria (Area +/- 40%, RT +/- 20 sec.)
Concal Sample Ave. ICal Flag
RT RT IS Area
13.05 13.08 539,287 Pass
14.85 14.88 2,012,245 Pass
19.06 19.08 1,964,160 Pass
1,4-Difluorobenzene (IS)2,013,301
Chlorobenzene-d5 (IS)1,900,220
Sample
Name IS Area
Bromochloromethane (IS)537,310
1,2,4-Trichlorobenzene
Hexachlorobutadiene
Naphthalene
Internal Standard
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl chloride
1,2-Dichlorobenzene
4-Ethyltoluene
2-Chlorotoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
o-Xylene
Styrene
Bromoform
1,1,2,2-Tetrachloroethane
Chlorobenzene
Ethylbenzene
1,1,1,2-Tetrachloroethane
m-/p-Xylenes
Chlorobenzene-d5 (IS)
Tetrachloroethene
2-Hexanone (Methyl butyl ketone)
Dibromochloromethane
1,2-Dibromoethane
1,4-Difluorobenzene (IS)
Bromochloromethane (IS)
0612-20 RWsummaries REDO.xls 7/10/2012
Evaluate Continuing Calibration Report
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201438.D Vial: 1
Acq On : 3 Jul 2012 10:46 am Operator: DB
Sample : 8.25ppbv TO-15 CCV std Inst : Lurch
Misc : 125mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Multiple Level Calibration
Min. RRF : 0.000 Min. Rel. Area : 40% Max. R.T. Dev 0.50min
Max. RRF Dev : 30% Max. Rel. Area : 200%
Compound AvgRF CCRF %Dev Area% Dev(min)
--------------------------------------------------------------------------
1 I Bromochloromethane (IS) 1.000 1.000 0.0 87 -0.03
2 Propylene 1.282 1.269 1.0 96 -0.03
3 Freon 12 (CCl2F2) 3.569 3.513 1.6 92 -0.03
4 Freon 114 (C2Cl2F4) 3.861 3.801 1.6 92 -0.03
5 Chloromethane 1.400 1.420 -1.4 97 -0.03
6 Chloroethene (Vinyl chlorid 1.309 1.320 -0.8 94 -0.04
7 1,3-Butadiene 1.195 1.247 -4.4 97 -0.04
8 Bromomethane 1.469 1.407 4.2 89 -0.03
9 Chloroethane 0.715 0.706 1.3 92 -0.03
10 Bromoethene (Vinyl bromide) 1.346 1.244 7.6 87 -0.03
11 Freon 11 (CCl3F) 2.995 2.898 3.2 91 -0.03
12 Ethanol 0.439 0.460 -4.8 100 -0.03
13 Acrolein 0.472 0.435 7.8 82 -0.04
14 Freon 113 (C2Cl3F3) 1.638 1.487 9.2 86 -0.04
15 1,1-Dichloroethene 2.026 1.851 8.6 84 -0.04
16 Acetone 2.546 2.231 12.4 85 -0.03
17 Carbon disulfide 3.528 3.288 6.8 88 -0.04
18 Isopropyl alcohol 2.612 2.518 3.6 90 -0.03
19 Allyl chloride (3-chloropro 0.559 0.516 7.7 87 -0.04
20 Acetonitrile 1.293 1.244 3.8 91 -0.04
21 Methylene chloride 1.949 1.729 11.3 90 -0.03
22 trans-1,2-Dichloroethene 1.853 1.755 5.3 89 -0.03
23 Methyl tert-butyl ether 3.188 2.989 6.2 89 -0.03
24 Acrylonitrile 1.023 0.963 5.9 89 -0.03
25 Hexane 1.825 1.708 6.4 89 -0.03
26 1,1-Dichloroethane 2.242 2.124 5.3 90 -0.03
27 Vinyl acetate 4.432 4.314 2.7 90 -0.03
28 cis-1,2-Dichloroethylene 2.162 2.046 5.4 89 -0.03
29 Methyl ethyl ketone (2-Buta 0.580 0.560 3.4 91 -0.03
30 Ethyl acetate 0.509 0.495 2.8 91 -0.03
31 Chloroform 2.668 2.492 6.6 88 -0.03
32 Tetrahydrofuran 0.570 0.536 6.0 89 -0.03
33 1,1,1-Trichloroethane 2.644 2.437 7.8 88 -0.03
34 Cyclohexane 1.922 1.820 5.3 89 -0.03
35 Carbon tetrachloride 2.687 2.498 7.0 88 -0.03
36 I 1,4-Difluorobenzene (IS) 1.000 1.000 0.0 92 -0.02
37 Benzene 0.888 0.791 10.9 89 -0.02
38 2,2,4-trimethylpentane 1.502 1.376 8.4 91 -0.02
39 1,2-Dichloroethane 0.445 0.395 11.2 88 -0.02
40 Heptane 0.294 0.267 9.2 90 -0.03
41 Trichloroethene 0.449 0.395 12.0 88 -0.03
42 1,2-Dichloropropane 0.338 0.314 7.1 93 -0.02
43 Methyl methacrylate 0.336 0.308 8.3 91 -0.03
44 1,4-Dioxane 0.206 0.196 4.9 97 -0.02
45 Bromodichloromethane 0.768 0.700 8.9 91 -0.03
46 cis-1,3-Dichloropropene 0.577 0.524 9.2 90 -0.02
47 Methyl isobutyl ketone 0.985 0.939 4.7 93 -0.03
48 I Chlorobenzene-d5 (IS) 1.000 1.000 0.0 97 -0.01
49 Toluene 1.135 0.973 14.3 90 -0.02
50 trans-1,3-Dichloropropene 0.604 0.524 13.2 90 -0.02
51 1,1,2-Trichloroethane 0.459 0.398 13.3 89 -0.02
52 Tetrachloroethene 0.583 0.505 13.4 88 -0.01
53 2-Hexanone (Methyl butyl ke 1.018 0.952 6.5 95 -0.02
54 Dibromochloromethane 0.844 0.730 13.5 88 -0.02
55 1,2-Dibromoethane 0.783 0.678 13.4 89 -0.02
--------------------------------------------------------------------------
(#) = Out of Range
L1201438.D L062912C.M Wed Jul 11 10:50:10 2012 Page 1
Evaluate Continuing Calibration Report
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201438.D Vial: 1
Acq On : 3 Jul 2012 10:46 am Operator: DB
Sample : 8.25ppbv TO-15 CCV std Inst : Lurch
Misc : 125mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Multiple Level Calibration
Min. RRF : 0.000 Min. Rel. Area : 40% Max. R.T. Dev 0.50min
Max. RRF Dev : 30% Max. Rel. Area : 200%
Compound AvgRF CCRF %Dev Area% Dev(min)
--------------------------------------------------------------------------
56 Chlorobenzene 0.960 0.831 13.4 88 -0.01
57 Ethylbenzene 1.416 1.347 4.9 91 -0.02
58 1,1,1,2-Tetrachloroethane 0.539 0.484 10.2 89 -0.01
59 m-/p-Xylenes 1.098 1.022 6.9 90 -0.01
60 o-Xylene 1.124 1.043 7.2 90 -0.01
61 Styrene 0.924 0.852 7.8 90 -0.02
62 Bromoform 0.762 0.690 9.4 89 -0.01
63 1,1,2,2-Tetrachloroethane 0.959 0.925 3.5 93 -0.02
64 4-Ethyltoluene 1.565 1.620 -3.5 94 -0.01
65 2-Chlorotoluene 1.395 1.392 0.2 90 -0.01
66 1,3,5-Trimethylbenzene 1.174 1.026 12.6 80 -0.01
67 1,2,4-Trimethylbenzene 1.228 1.160 5.5 88 -0.01
68 1,3-Dichlorobenzene 0.856 0.802 6.3 87 -0.02
69 1,4-Dichlorobenzene 0.872 0.821 5.8 87 -0.01
70 Benzyl chloride 1.247 1.169 6.3 88 -0.02
71 1,2-Dichlorobenzene 0.805 0.751 6.7 87 -0.01
72 1,2,4-Trichlorobenzene 0.549 0.467 14.9 94 -0.02
73 Hexachlorobutadiene 0.374 0.330 11.8 94 -0.02
74 Naphthalene 1.514 1.323 12.6 97 -0.02
--------------------------------------------------------------------------
(#) = Out of Range SPCC's out = 0 CCC's out = 0
L1201438.D L062912C.M Wed Jul 11 10:50:10 2012 Page 2
Quantitation Report
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201438.D Vial: 1
Acq On : 3 Jul 2012 10:46 am Operator: DB
Sample : 8.25ppbv TO-15 CCV std Inst : Lurch
Misc : 125mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 10:49 2012 Quant Results File: L062912C.RES
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00
0
500000
1000000
1500000
2000000
2500000
3000000
3500000
4000000
4500000
5000000
5500000
6000000
6500000
7000000
7500000
Time-->
Abundance TIC: L1201438.D
NaphthaleneHexachlorobutadiene1,2,4-Trichlorobenzene1,2-DichlorobenzeneBenzyl chloride1,4-Dichlorobenzene1,3-Dichlorobenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene2-Chlorotoluene4-Ethyltoluene1,1,2,2-TetrachloroethaneBromoformStyreneo-Xylenem-/p-Xylenes1,1,1,2-TetrachloroethaneEthylbenzeneChlorobenzeneChlorobenzene-d5 (IS),I1,2-DibromoethaneDibromochloromethane2-Hexanone (Methyl butyl ketone)Tetrachloroethene1,1,2-Trichloroethanetrans-1,3-DichloropropeneTolueneMethyl isobutyl ketonecis-1,3-DichloropropeneBromodichloromethane1,4-DioxaneMethyl methacrylate1,2-DichloropropaneTrichloroethene1,4-Difluorobenzene (IS),IHeptane2,2,4-trimethylpentane1,2-DichloroethaneBenzeneCarbon tetrachlorideCyclohexane1,1,1-TrichloroethaneChloroformTetrahydrofuranBromochloromethane (IS),IEthyl acetatecis-1,2-DichloroethyleneMethyl ethyl ketone (2-Butanone)1,1-DichloroethaneVinyl acetateHexanetrans-1,2-DichloroetheneMethyl tert-butyl etherAcrylonitrileMethylene chlorideAllyl chloride (3-chloropropene)AcetonitrileCarbon disulfideIsopropyl alcoholAcetoneFreon 113 (C2Cl3F3)1,1-DichloroetheneAcroleinEthanolFreon 11 (CCl3F)Bromoethene (Vinyl bromide)ChloroethaneBromomethane1,3-ButadieneChloroethene (Vinyl chloride)ChloromethaneFreon 114 (C2Cl2F4)Freon 12 (CCl2F2)PropyleneL1201438.D L062912C.M Wed Jul 11 10:49:51 2012 Page 3
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201438.D Vial: 1
Acq On : 3 Jul 2012 10:46 am Operator: DB
Sample : 8.25ppbv TO-15 CCV std Inst : Lurch
Misc : 125mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 10:49 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) Bromochloromethane (IS) 13.04 130 490430 11.03 PPBV -0.03
36) 1,4-Difluorobenzene (IS) 14.85 114 1944470 10.52 PPBV -0.02
48) Chlorobenzene-d5 (IS) 19.07 117 1998806 11.20 PPBV -0.01
Target Compounds Qvalue
2) Propylene 4.67 41 511846 8.98 PPBV # 71
3) Freon 12 (CCl2F2) 4.78 85 1275755 8.04 PPBV 97
4) Freon 114 (C2Cl2F4) 5.16 85 1408423 8.20 PPBV # 93
5) Chloromethane 5.28 50 531478 8.54 PPBV 97
6) Chloroethene (Vinyl chlori 5.59 62 493826 8.48 PPBV 99
7) 1,3-Butadiene 5.71 39 485006 9.13 PPBV 90
8) Bromomethane 6.47 94 526594 8.06 PPBV 99
9) Chloroethane 6.77 64 261530 8.22 PPBV 99
10) Bromoethene (Vinyl bromide 7.23 106 456269 7.62 PPBV # 97
11) Freon 11 (CCl3F) 7.40 101 1116235 8.38 PPBV 99
12) Ethanol 7.84 45 172059 8.81 PPBV # 84
13) Acrolein 8.41 56 173932 8.28 PPBV 93
14) Freon 113 (C2Cl3F3) 8.67 151 534602 7.34 PPBV 98
15) 1,1-Dichloroethene 8.63 61 672312 7.46 PPBV 91
16) Acetone 8.74 43 859475 7.59 PPBV # 82
17) Carbon disulfide 9.13 76 1194081 7.61 PPBV 94
18) Isopropyl alcohol 9.09 45 1006863 8.67 PPBV # 86
19) Allyl chloride (3-chloropr 9.48 76 194848 7.84 PPBV # 47
20) Acetonitrile 9.34 41 419720 7.30 PPBV # 83
21) Methylene chloride 9.77 49 640590 7.39 PPBV # 77
22) trans-1,2-Dichloroethene 10.40 61 643653 7.81 PPBV 98
23) Methyl tert-butyl ether 10.40 73 1151462 8.12 PPBV # 85
24) Acrylonitrile 10.28 53 353372 7.77 PPBV # 90
25) Hexane 11.02 57 651508 8.03 PPBV # 78
26) 1,1-Dichloroethane 11.36 63 794660 7.97 PPBV 99
27) Vinyl acetate 11.36 43 1693209 8.59 PPBV 97
28) cis-1,2-Dichloroethylene 12.57 61 780554 8.12 PPBV 93
29) Methyl ethyl ketone (2-But 12.54 72 219647 8.51 PPBV 77
30) Ethyl acetate 12.63 45 187091 8.26 PPBV # 84
31) Chloroform 13.22 83 941422 7.94 PPBV 98
32) Tetrahydrofuran 13.08 72 210550 8.31 PPBV # 56
33) 1,1,1-Trichloroethane 13.56 97 920711 7.83 PPBV 94
34) Cyclohexane 13.70 56 694281 8.13 PPBV # 79
35) Carbon tetrachloride 13.84 117 925635 7.75 PPBV 97
37) Benzene 14.18 78 1255005 7.64 PPBV # 94
38) 2,2,4-trimethylpentane 14.37 57 2140066 7.71 PPBV # 80
39) 1,2-Dichloroethane 14.26 62 632822 7.70 PPBV 99
40) Heptane 14.64 57 431065 7.94 PPBV # 89
41) Trichloroethene 15.23 130 631693 7.60 PPBV # 88
42) 1,2-Dichloropropane 15.65 63 507296 8.12 PPBV 93
43) Methyl methacrylate 15.68 69 497376 8.02 PPBV # 89
44) 1,4-Dioxane 15.74 88 313229 8.23 PPBV # 80
45) Bromodichloromethane 16.05 83 1120604 7.89 PPBV # 97
46) cis-1,3-Dichloropropene 16.79 75 870854 8.17 PPBV 98
47) Methyl isobutyl ketone 17.02 43 1547729 8.50 PPBV # 94
49) Toluene 17.39 91 1533731 7.57 PPBV 96
50) trans-1,3-Dichloropropene 17.68 75 771196 7.15 PPBV 97
51) 1,1,2-Trichloroethane 17.95 97 626698 7.65 PPBV 87
52) Tetrachloroethene 18.09 166 780745 7.50 PPBV 95
53) 2-Hexanone (Methyl butyl k 18.17 43 1528216 8.41 PPBV # 91
54) Dibromochloromethane 18.42 129 1171617 7.78 PPBV 99
55) 1,2-Dibromoethane 18.57 107 1058857 7.58 PPBV 96
56) Chlorobenzene 19.10 112 1334466 7.79 PPBV # 90
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201438.D L062912C.M Wed Jul 11 10:49:50 2012 Page 1
Quantitation Report (QT Reviewed)
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201438.D Vial: 1
Acq On : 3 Jul 2012 10:46 am Operator: DB
Sample : 8.25ppbv TO-15 CCV std Inst : Lurch
Misc : 125mL load, can #10897 Multiplr: 1.00
MS Integration Params: rteint.p
Quant Time: Jul 11 10:49 2012 Quant Results File: L062912C.RES
Quant Method : M:\MS2012\M...\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
Last Update : Tue Jul 10 18:41:00 2012
Response via : Initial Calibration
DataAcq Meth : MM624-L
Compound R.T. QIon Response Conc Unit Qvalue
-------------------------------------------------------------------------
57) Ethylbenzene 19.18 91 2141278 8.47 PPBV 100
58) 1,1,1,2-Tetrachloroethane 19.18 131 711926 7.40 PPBV # 92
59) m-/p-Xylenes 19.31 91 3189935 16.28 PPBV 94
60) o-Xylene 19.68 91 1689436 8.43 PPBV 93
61) Styrene 19.69 104 1366648 8.28 PPBV 90
62) Bromoform 19.89 173 1077198 7.92 PPBV 98
63) 1,1,2,2-Tetrachloroethane 20.25 83 1497997 8.75 PPBV 98
64) 4-Ethyltoluene 20.47 105 2528244 9.05 PPBV 99
65) 2-Chlorotoluene 20.47 91 2070460 8.32 PPBV 98
66) 1,3,5-Trimethylbenzene 20.51 105 1632222 7.79 PPBV 96
67) 1,2,4-Trimethylbenzene 20.83 105 1844261 8.42 PPBV 97
68) 1,3-Dichlorobenzene 21.09 146 1299000 8.51 PPBV 97
69) 1,4-Dichlorobenzene 21.18 146 1293219 8.31 PPBV 97
70) Benzyl chloride 21.25 91 1893336 8.51 PPBV 93
71) 1,2-Dichlorobenzene 21.48 146 1193979 8.31 PPBV 98
72) 1,2,4-Trichlorobenzene 22.84 180 728154 7.43 PPBV 99
73) Hexachlorobutadiene 22.94 225 514813 7.72 PPBV 99
74) Naphthalene 23.12 128 1908673 7.06 PPBV # 79
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
L1201438.D L062912C.M Wed Jul 11 10:49:50 2012 Page 2
BFB
Data File : M:\MS2012Q2\LURCH\DATA\JUN12\L062912A\L1201397.D Vial: 1
Acq On : 29 Jun 2012 10:31 am Operator: DB
Sample : BFB Inst : Lurch
Misc : 50mL load Multiplr: 1.00
MS Integration Params: rteint.p
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
18.20 18.40 18.60 18.80 19.00 19.20 19.40 19.60 19.80 20.00 20.20 20.40 20.60 20.80 21.00 21.20 21.40 21.60 21.80 22.00
0
500000
1000000
1500000
2000000
2500000
3000000
3500000
4000000
4500000
5000000
Time-->
Abundance TIC: L1201397.D
30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 240 250 260 270 280 290 300
0
100000
200000
300000
400000
500000
600000
700000
800000
m/z-->
Abundance Average of 20.168 to 20.188 min.: L1201397.D (-)
95
174
75
50
37 8761 143117104130 155163 209 261 281191 296233268219 247
AutoFind: Scans 1703, 1704, 1705; Background Corrected with Scan 1697
| Target | Rel. to | Lower | Upper | Rel. | Raw | Result |
| Mass | Mass | Limit% | Limit% | Abn% | Abn | Pass/Fail |
----------------------------------------------------------------------
| 50 | 95 | 8 | 40 | 21.9 | 178226 | PASS |
| 75 | 95 | 30 | 66 | 44.2 | 359589 | PASS |
| 95 | 95 | 100 | 100 | 100.0 | 814080 | PASS |
| 96 | 95 | 5 | 9 | 6.8 | 55220 | PASS |
| 173 | 174 | 0.00 | 2 | 0.0 | 0 | PASS |
| 174 | 95 | 50 | 120 | 76.9 | 626197 | PASS |
| 175 | 174 | 4 | 9 | 7.4 | 46249 | PASS |
| 176 | 174 | 93 | 101 | 95.8 | 599765 | PASS |
| 177 | 176 | 5 | 9 | 6.6 | 39812 | PASS |
----------------------------------------------------------------------
L1201397.D L062912C.M Tue Jul 10 18:35:56 2012
Average of 20.168 to 20.188 min.: L1201397.D
BFB
Modified:subtracted
m/z abund. m/z abund. m/z abund. m/z abund.
30.95 33113 43.95 4072 55.95 11958 67.95 79971
31.95 336 44.95 8414 56.95 21035 68.90 78008
33.00 4101 46.00 378 57.90 792 69.90 5348
33.95 60 46.95 12645 59.90 7799 70.95 7
35.95 10864 47.95 6120 60.95 35120 71.95 4112
37.00 53819 49.00 38016 61.95 33255 72.95 30928
38.00 43997 50.00 178226 63.00 24107 74.00 114867
39.00 16479 51.00 52847 63.95 2081 74.95 359589
39.95 421 51.90 2184 64.95 433 75.90 31256
40.95 129 52.95 118 65.85 3 76.90 4857
42.95 398 54.90 2152 66.95 1383 77.95 3578
Average of 20.168 to 20.188 min.: L1201397.D
BFB
Modified:subtracted
m/z abund. m/z abund. m/z abund. m/z abund.
78.85 21006 91.95 20093 104.85 1313 115.85 2429
79.95 6189 92.95 31190 105.80 3107 116.80 4223
80.85 22508 93.90 86315 106.80 821 117.80 2622
81.80 4153 95.00 814080 107.90 78 118.80 3275
82.85 113 95.95 55220 108.50 49 119.90 34
84.00 57 96.95 1556 108.80 49 121.85 35
85.95 573 99.90 96 109.95 199 122.65 67
86.90 42157 100.55 78 110.75 319 122.85 91
87.85 40429 101.35 53 111.80 411 123.85 471
89.45 79 102.90 351 112.80 510 124.80 317
90.85 2912 103.85 3141 114.80 696 125.80 145
Average of 20.168 to 20.188 min.: L1201397.D
BFB
Modified:subtracted
m/z abund. m/z abund. m/z abund. m/z abund.
126.80 212 137.95 66 148.85 405 158.85 697
127.85 2671 138.90 390 149.75 546 159.85 38
128.80 1096 139.80 463 150.75 63 160.80 529
129.80 2697 140.80 5731 151.80 295 162.05 40
130.80 1051 141.85 956 152.80 520 162.85 128
131.80 176 142.80 5731 153.75 268 163.70 58
133.80 184 143.90 129 154.85 1639 165.00 46
134.75 1108 144.85 405 155.75 108 166.70 36
135.70 149 145.85 1084 156.10 40 167.50 58
135.95 106 146.80 473 156.90 1033 168.10 46
136.80 1035 147.85 1527 157.85 71 169.00 36
Average of 20.168 to 20.188 min.: L1201397.D
BFB
Modified:subtracted
m/z abund. m/z abund. m/z abund. m/z abund.
169.90 8 190.00 36 249.80 34 288.45 34
170.85 63 190.85 77 260.80 83 292.65 39
171.05 63 191.80 62 261.00 62 296.50 50
171.45 57 196.05 37 264.85 37
171.85 128 208.85 117 266.85 46
173.85 626197 210.05 38 268.55 36
174.85 46249 218.95 35 275.65 33
175.80 599765 232.05 41 276.85 36
176.85 39812 233.05 45 280.85 78
177.80 1071 237.00 35 282.70 36
178.80 126 246.80 35 284.70 35
BFB
Data File : M:\MS2012Q3\LURCH\DATA\JUL12\L070312A\L1201436.D Vial: 1
Acq On : 3 Jul 2012 8:04 am Operator: DB
Sample : BFB Inst : Lurch
Misc : 50mL load Multiplr: 1.00
MS Integration Params: rteint.p
Method : M:\MS2012\METHODS\LURCH\L062912C.M (RTE Integrator)
Title : TO15 - 72 TCL - Primary "A" w/IS cyl - CC117359
18.20 18.40 18.60 18.80 19.00 19.20 19.40 19.60 19.80 20.00 20.20 20.40 20.60 20.80 21.00 21.20 21.40 21.60 21.80 22.00
0
500000
1000000
1500000
2000000
2500000
3000000
3500000
4000000
4500000
5000000
Time-->
Abundance TIC: L1201436.D
30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 240 250 260 270 280
0
100000
200000
300000
400000
500000
600000
700000
800000
m/z-->
Abundance Average of 20.168 to 20.188 min.: L1201436.D (-)
95
174
75
50
37 8761 143117106130 155 207 281162 260190 268
AutoFind: Scans 1703, 1704, 1705; Background Corrected with Scan 1697
| Target | Rel. to | Lower | Upper | Rel. | Raw | Result |
| Mass | Mass | Limit% | Limit% | Abn% | Abn | Pass/Fail |
----------------------------------------------------------------------
| 50 | 95 | 8 | 40 | 22.6 | 187383 | PASS |
| 75 | 95 | 30 | 66 | 45.8 | 379435 | PASS |
| 95 | 95 | 100 | 100 | 100.0 | 828757 | PASS |
| 96 | 95 | 5 | 9 | 6.7 | 55517 | PASS |
| 173 | 174 | 0.00 | 2 | 0.0 | 0 | PASS |
| 174 | 95 | 50 | 120 | 81.4 | 675008 | PASS |
| 175 | 174 | 4 | 9 | 7.2 | 48304 | PASS |
| 176 | 174 | 93 | 101 | 95.2 | 642283 | PASS |
| 177 | 176 | 5 | 9 | 6.6 | 42203 | PASS |
----------------------------------------------------------------------
L1201436.D L062912C.M Wed Jul 11 10:48:50 2012
Average of 20.168 to 20.188 min.: L1201436.D
BFB
Modified:subtracted
m/z abund. m/z abund. m/z abund. m/z abund.
30.95 36850 42.95 229 52.95 92 64.95 210
31.95 363 43.95 5028 54.90 2019 67.00 1757
33.05 4697 45.00 9066 55.95 12878 67.95 84507
34.00 141 45.95 498 56.95 22885 68.95 80549
34.90 57 47.00 14051 57.90 954 69.95 5693
36.00 11728 48.00 5881 58.90 190 70.90 138
37.00 58243 49.00 40341 59.90 7996 72.00 4282
38.00 48452 49.95 187383 61.00 37117 73.00 32075
38.95 18258 50.95 55794 62.00 35416 74.00 121968
39.90 466 51.95 2392 63.00 25531 75.00 379435
40.95 97 52.75 35 63.95 2246 75.95 32333
Average of 20.168 to 20.188 min.: L1201436.D
BFB
Modified:subtracted
m/z abund. m/z abund. m/z abund. m/z abund.
76.90 5087 87.85 42677 102.85 427 113.85 40
77.90 4004 89.85 53 103.85 3292 114.85 885
78.85 24563 90.85 3265 104.85 1066 115.85 2664
79.95 6412 91.95 21160 105.80 3439 116.80 4731
80.85 25283 92.95 31973 106.80 825 117.80 2671
81.80 4658 93.90 89255 108.00 34 118.80 3565
82.95 323 95.00 828757 108.70 41 119.80 60
83.90 59 95.95 55517 109.80 482 121.85 209
84.60 54 96.95 1567 110.75 601 122.80 269
85.90 688 98.50 43 111.80 384 123.80 503
86.90 45405 102.05 51 112.80 619 124.85 250
Average of 20.168 to 20.188 min.: L1201436.D
BFB
Modified:subtracted
m/z abund. m/z abund. m/z abund. m/z abund.
125.85 328 137.85 168 148.80 463 160.80 559
126.75 322 138.85 361 149.80 724 161.75 39
127.85 2623 139.85 232 150.85 33 162.15 37
128.80 1369 140.80 6490 151.85 346 169.20 40
129.80 2771 141.90 1051 152.80 526 169.95 142
130.80 1133 142.80 6543 153.85 440 170.55 59
131.80 70 143.85 445 154.85 1839 171.45 86
133.85 283 144.85 599 155.90 279 171.75 173
134.80 1179 145.80 1127 156.85 1018 173.85 675008
135.65 104 146.80 509 157.85 222 174.85 48304
136.80 1124 147.85 1765 158.80 781 175.80 642283
Average of 20.168 to 20.188 min.: L1201436.D
BFB
Modified:subtracted
m/z abund. m/z abund. m/z abund. m/z abund.
176.80 42203 268.25 35
177.85 1161 280.90 86
178.80 40
180.90 52
190.00 35
201.30 38
206.85 130
208.85 97
259.90 36
260.70 36
264.35 36
TOPLEVEL PARAMETERS
-------------------
Method Information For: M:\MS2012\METHODS\LURCH\MM624-L.M
Method Sections To Run:
( ) Save Copy of Method With Data
(X) Pre-Run Cmd/Macro = MPVGotoVialDDE
(X) Data Acquisition
( ) Data Analysis
( ) Post-Run Cmd/Macro = MACRO "POSTMSD" ,GO
Method Comments:
This is the acquisition method for Method TO-14 with Toluene-d8 as the
internal standard being used to quantitate analytes.
END OF TOPLEVEL PARAMETERS
--------------------------
INSTRUMENT CONTROL PARAMETERS
-----------------------------
Sample Inlet: GC
Injection Source: External Device
Injection Location: Rear
Mass Spectrometer: Enabled
HP5890 Temperature Parameters
Zone Temperatures: State Setpoint
Inlet A: On 250 C
Inlet B: Off 50 C
Detector A: Off 50 C
Detector B: On 280 C
Auxiliary: Off 50 C
Oven Parameters:
Oven Equib Time: 0.20 minutes
Oven Max: 325 C
Oven State: On
Cryo State: On
Cryo Blast: On
Ambient: 25 C
Oven Program:
Initial Temperature: 30 C
Initial Time: 3.00 minutes
Rate Final Final
Level (C/minute) Temperature (C) Time (minutes)
1 5.0 75 0.00
2(A) 15.0 120 2.00
3(B) 70.0 240 8.00
Next Run Time: 26.71 minutes
HP5890 Inlet Temperature Programs
Inlet A:
Oven Tracking: Off
Inlet Zone: On
Initial Temperature: 250 C
Initial Time: 480.00 minutes
Rate Final Final
Level (C/minute) Temperature (C) Time (minutes)
Method: MM624-L.M Fri Apr 20 11:50:02 2012 Page: 1
1 0 50 0.00
2(A) 0 50 0.00
3(B) 0 50 0.00
Total Program Time: 480.00 minutes
Inlet B:
Oven Tracking: Off
Inlet Zone: Off
Initial Temperature: 50 C
Initial Time: 650.00 minutes
Rate Final Final
Level (C/minute) Temperature (C) Time (minutes)
1 0 50 0.00
2(A) 0 50 0.00
3(B) 0 50 0.00
Total Program Time: 650.00 minutes
HP5890 Inlet Pressure Programs
GC Pressure Units: psi
Inlet A:
Constant Flow: On
Constant Flow Pressure: 8.7 psi
Constant Flow Temperature: 35 C
Initial Pressure: 0.0 psi
Initial Time: 650.00 minutes
Rate Final Final
Level (psi/minute) Pressure (psi) Time (minutes)
1 0.00 0.0 0.00
2(A) 0.00 0.0 0.00
3(B) 0.00 0.0 0.00
Total Program Time: 650.00 minutes
Column Length: 60.00 m
Column Diameter: 0.320 mm
Gas: He
Vacuum Compensation: On
Inlet B:
Constant Flow: Off
Constant Flow Pressure: 0.0 psi
Constant Flow Temperature: 50 C
Initial Pressure: 0.0 psi
Initial Time: 650.00 minutes
Rate Final Final
Level (psi/minute) Pressure (psi) Time (minutes)
1 0.00 0.0 0.00
2(A) 0.00 0.0 0.00
3(B) 0.00 0.0 0.00
Total Program Time: 650.00 minutes
Column Length: 30.00 m
Column Diameter: 0.530 mm
Gas: He
Vacuum Compensation: Off
HP5890 Packed Column Flow Control
Inlet A not used to control packed column flow.
Inlet B not used to control packed column flow.
HP5890 Purge Valve Settings
Inlet Purge Init Value On Time Off Time Splitless Injection
A Off 0.00 0.00 Yes
Method: MM624-L.M Fri Apr 20 11:50:02 2012 Page: 2
B Off 0.00 0.00 Yes
HP5890 Valve and Relay Information
Initial Setpoints:
5890 Valves:
Valve 1: Off Valve 2: Off Valve 3: Off Valve 4: Off
19405 Valves:
Valve 5: Off Valve 6: Off Valve 7: Off Valve 8: Off
19405 Relays:
Relay 1: Off Relay 2: Off Relay 3: Off Relay 4: Off
HP5890 Detector Information
Detector Type State
A --- Off
B --- Off
HP5890 Signal Information
Not saving signal data.
Signal Source Peak Width Data Rate Start Data Stop Data
1 Testplot 0.053 5.000 0.00 1.00
2 Testplot 0.053 5.000 0.00 1.00
MS ACQUISITION PARAMETERS
General Information
------- -----------
Tune File : bfb.u
Acquistion Mode : Scan
MS Information
-- -----------
Solvent Delay : 3.00 min
EM Absolute : False
EM Offset : 0
Resulting EM Voltage : 2447.1
[Scan Parameters]
Low Mass : 29
High Mass : 300
Threshold : 100
Sample # : 3 A/D Samples 8
END OF MS ACQUISITION PARAMETERS
END OF INSTRUMENT CONTROL PARAMETERS
------------------------------------

DATA ANALYSIS PARAMETERS
------------------------

Method: MM624-L.M Fri Apr 20 11:50:02 2012 Page: 3

This Is The Last Page
Of This Report.

ATTACHMENT B

PHOTOGRAPHS

Photograph A: Coring concrete with hammer drill.

Photograph B: Sub-slab stainless steel screen.

Photograph C: Concrete sealed sub-slab vapor sampling point.

Photograph D: Purging sub-slab vapor well with photoionization detector.

Photograph E: Testing for seal break through using helium and helium detector.

Photograph F: Collecting sub-slab soil gas sample using 1.4 liter Summa canister.