RA-7781_39876_CA_MRP_20170828

GROUNDWATER MONITORING REPORT

FRIENDLY MART
3055 STANTONSBURG ROAD, WILSON, WILSON COUNTY, NC 27893
GROUNDWATER INCIDENT #: 39876
FACILITY ID #: 0-024589

AUGUST 28, 2017

UST OWNER:
ROSE OIL COMPANY, INC.
613 US 158 BYPASS, HENDERSON, NC 27536-0706
PHONE NUMBER: [phone]

PROPERTY OWNER:
SMW, INC., 613 US 158 BYPASS, HENDERSON, NC 27536-0706

CONSULTANT:
HENRY NEMARGUT ENGINEERING SERVICES
2211 CHESTNUT STREET, WILMINGTON, NC 28405
PHONE NUMBER: [phone]

RELEASE INFORMATION:
DATE DISCOVERED: 12/17/15
ESTIMATED QUANTITY OF RELEASE: UNKNOWN
CAUSE OF RELEASE: UNKNOWN
SOURCE OF RELEASE: UST SYSTEM
SIZE AND CONTENTS: (1) 4,000 GALLON DIESEL;
(2) 6,000 GALLON GASOLINE & (1) 4,000 GALLON GASOLINE USTS
LATITUDE: N 35.69099167o; LONGITUDE: W 77.88775o

The Monitoring Report for this site has been prepared by Henry Nemargut Engineering Services. All
engineering work performed on this project was conducted under my direct supervision:

Henry Nemargut, P.E.
Henry Nemargut Engineering Services
North Carolina License #17669

August 28, 2017

Raymond Bartholomew
Rose Oil Company, Inc.
613 US 158 Bypass
Henderson, NC 27536-0706

Reference: Groundwater Monitoring Report
Friendly Mart
3055 Stantonsburg Road
Wilson, Wilson County, North Carolina 27893
Facility ID#: 0-024589; Incident #39876

Dear Mr. Bartholomew:

Please find enclosed a report summarizing groundwater monitoring activities conducted at the
above referenced facility. Previous assessment activities at this site revealed a release of
petroleum in groundwater in the vicinity of the former location of a gasoline UST and dispenser
island. Ten new and existing on-site and off-site monitor wells and one nearby water supply
well were sampled in June, 2017 to evaluate the site for the presence of dissolved gasoline
constituents. The findings of this investigation are summarized herein.

Mr. Bartholomew, if you have questions regarding this report please contact my office..
Sincerely,

Henry Nemargut, P.E.
Henry Nemargut Engineering Services

TABLE OF CONTENTS

Section Page

1.0 Introduction and Background
1.1 Introduction 1
1.2 Scope of Services 1

2.0 Field Activities 2
2.1 Monitor Well Installation 2
2.2 Groundwater Flow Direction and Gradient 2
2.3 Monitor Well Sampling and Analysis 2
2.4 Supply Well Sampling and Analysis 3
2.5 Plume Development 3

3.0 Conclusions and Recommendations
3.1 General Summary 4
3.2 Recommendations 4
3.3 Limitations 5

LIST OF FIGURES

Figure 1: Project Location
Figure 2: Site Layout and Monitor Well Locations
Figure 3: Potentiometric Surface Map (6/27/17)
Figure 4: Benzene Iso-Concentration Map
Figure 5: Naphthalene Iso-Concentration Map
Figure 6: MTBE Iso-Concentration Map

LIST OF TABLES

Table 1: Monitoring Well Information and Groundwater Elevations
Table 2: Summary of Groundwater Laboratory Analytical Results
Table 3: Benzene vs. Time

APPENDICES

Appendix A: Well Construction Records
Appendix B: Groundwater Laboratory Analytical Results

Page - 1
GROUNDWATER MONITORING REPORT
FRIENDLY MART
3055 STANTONSBURG ROAD
WILSON, NORTH CAROLINA 27893

1.0 Introduction and Background

1.1 Introduction

Rose Oil Company, Inc. owns USTs which are operated at the Friendly Mart facility located at 3055
Stantonsburg Road in Wilson, North Carolina. Figure 1 illustrates the location of this facility on the
Wilson Quadrangle U.S.G.S. Topo Map. This facility contains one permanent structure which is used as
a gasoline convenience store. The site formerly contained (2) 6,000 gallon gasoline, (1) 4,000 gallon
gasoline, & (1) 4,000 gallon diesel USTs. All of the gasoline USTs are still in use at this facility. The
4,000 gallon diesel UST, which was last used at this facility in November, 2015, was removed on
December 17, 2015. Figure 2 illustrates the overall layout of this site and the UST locations.

A release from the UST system was suspected on 12/17/15 based on elevated PID readings observed in
soil samples collected from around the UST and the presence of a floating layer of diesel in the UST
excavation. Groundwater was observed at a depth of approximately 4’ to 5’ below surface in the UST
pit during soil abatement activities. The site and adjacent properties are used for commercial, residential
and industrial purposes. Municipal water supplies are available to properties within 1,500’; however,
adjacent properties are served by a local water supply well.

The NCDEQ recently approved an ePATA to conduct the following tasks be conducted at this site prior
to proceeding with development of a Corrective Action Plan for this facility:

• Sample existing monitoring wells
• Sample (1) nearby water supply well

1.2 Scope of Services

This Groundwater monitoring report contains documentation concerning the following activities which
have been conducted at this facility:

o A monitoring well sampling event consisting of sampling 2 new and 8 existing wells at the site

o Supply well sampling for (1) nearby private supply well

o Laboratory analyses of groundwater samples conducted by Pace Analytical, Inc. of Charlotte,
NC.

o Estimation of the approximate groundwater flow direction and hydraulic gradient at the site.

Page - 2
o Isoconcentration maps illustrating the current contaminant levels in the monitoring wells at the
facility.

2.0 Field Activities

2.1 Monitoring Well Installation

A total of (2) North Carolina Type II groundwater monitoring wells were installed off-site to complete
horizontal delineation of the contaminant plume. Figure 2 illustrates the locations of the new monitor
wells, denoted as MW-10 and MW-1 which were installed on property owned by Thomas Jones. The
monitoring wells installed at the site were constructed of 2-inch Schedule 40 PVC pipe with 7.5’ feet of
casing and 10’ of 0.010 inch slotted screen. Based on the assumption that the contaminants being
addressed were primarily hydrocarbon constituents with specific gravities of less than 1.0, the Type II
monitoring wells were installed so that the screened interval intersected the shallow groundwater table
at the time of installation. Well construction records for the new monitor wells constructed at this site
are included in Appendix A.

2.2 Ground Water Flow Direction and Gradient

In order to estimate the groundwater flow direction in the vicinity of the petroleum release, elevations of
the monitor well casings were measured using surveying equipment. Static water levels were obtained
from each of the wells and the data was used to compute a potentiometric surface map which is included
as Figure 3.

Groundwater data and monitoring well information, which are summarized in Table 1, were also used to
estimate the hydraulic gradient at the project site. Using the horizontal distance between the monitor
wells and the static water levels, the groundwater was estimated to be flowing in the east/northeast
direction with a horizontal hydraulic gradient of approximately 0.015 ft/ft.

2.3 Monitor Well Sampling and Analyses

On June 27, 2017, 10 monitoring wells were sampled for analyses utilizing Standard Method 6200B.
Before sampling, the monitor wells were purged by removing a minimum of three well volumes to
ensure that the samples were representative of the actual groundwater conditions. The monitor wells
were developed using disposable plastic balers suspended with unused nylon string. Following
development of the groundwater monitoring wells, samples were obtained from the disposable balers.

All samples were placed in laboratory supplied glassware, labeled with sample location, analysis to be
performed, time, date and sampler's name. The sample jars were then immediately placed in a cooler,
chilled with ice to approximately 4oC in preparation of transportation to an analytical laboratory
utilizing EPA approved chain-of-custody procedures.

Page - 3
Laboratory analytical results indicate the presence of 9 compounds above the current listed 2L Standards
in the monitor well network at this site. Total BTEX was detected at a maximum level of 88,670 ug/l in
MW-9 installed down-gradient of the gasoline UST source area. Benzene was detected at a maximum
concentration of 13,500 ug/l in MW-9, above its 2L standard of 1 ug/l and also above its GCL of 5,000
ug/l. Naphthalene was detected at a maximum concentration of 414 ug/l in MW-4, above its 2L
standard of 6 ug/l. MTBE was detected at a maximum concentration of 7,810 ug/l in MW-9, above its
2L Standard of 20 ug/l. Table 2 summarizes the laboratory analytical results, and Appendix B contains
a copy of the laboratory analytical report and chain of custody records. Figure 4 contains a benzene iso-
concentration map, Figure 5 illustrates the estimated Naphthatlene concentration map, and Figure 6
illustrates the MTBE isoconcentration for the site.

2.4 Supply Well Sampling and Analyses

On June 27, 2017, the Thomas Jones supply well at an adjacent property (SW-1) was sampled for
analyses utilizing Standard Method 6200B. Before sampling, the supply wells were purged by pumping
from the wells for approximately 10 minutes to ensure that the samples were representative of the actual
groundwater conditions. After pumping, the flowrate was reduced for collection of samples. The
sample from SW-1 was obtained from the bathroom sink at Ready Contractors.

All samples were placed in laboratory supplied glassware, labeled with sample location, analysis to be
performed, time, date and sampler's name. The sample jars were then immediately placed in a cooler,
chilled with ice to approximately 4oC in preparation of transportation to an analytical laboratory
utilizing EPA approved chain-of-custody procedures.

Laboratory analytical results indicate the presence of MTBE above 2L Standards in the supply well SW-
1 which serves Ready Contractors and a Private Residence. The MTBE level was noted in SW-1 at a
concentration of 23.7 ug/l, above its 2L Standard of 20 ug/l. No other compounds were noted in this
supply well. Table 2 summarizes the laboratory analytical results, and Appendix A contains a copy of
the laboratory analytical report and chain of custody records.

2.5 Plume Development

In prior sampling events conducted at the site, contaminants have been reported above 2L Standards in
on-site monitoring wells and above GCLs for benzene. Benzene was observed at a maximum level at
the site of 14,000 ug/l in the initial sampling event for MW-9 conducted in December, 2016, with a
0.01’ floating layer of gasoline noted in this well on December 15, 2016. In the latest monitoring event
on June 27, 2017, benzene was observed at a level of 13,500 ug/l; however, free product was not
observed. Benzene and MTBE levels have generally decreased in other monitoring wells over the brief
history of the site except for MW-5 which is believed to be influenced by drawdown effects from SW-1.
MW-5 showed an increase in Benzene during the June 27, 2017 sampling event, and SW-1 showed a
significant increase in MTBE concentration during the June 27, 2017 sampling event to a level above 2L
Standards. Sufficient data has not been collected to establish consistent trends for the site caused by
seasonal fluctuations. Table 3 contains historical benzene concentrations at the site for source area
monitoring wells.
Page - 4

3.0 Conclusions and Recommendations

3.1 General Summary

A groundwater monitoring sampling event has been conducted at the Friendly Mart facility located at
3055 Stantonsburg Road in Wilson, NC. From a review of all information gathered during this
remediation project, Henry Nemargut Engineering Services makes the following conclusions:

o 9 petroleum compounds were detected in on site monitoring wells above 2L Standards. Benzene
was detected at a maximum concentration of 13,500 ug/l in MW-9, above its 2L standard of 1
ug/l and also above its GCL of 5,000 ug/l. MTBE was detected at a maximum concentration of
7,810 ug/l in MW-9, above its 2L Standard of 20 ug/l.

o Free product was not observed at the site during the June 27, 2017 monitoring event.

o The benzene level appears to have remained relatively constant in source area well MW-9 since
the December, 2016 sampling event. Benzene and MTBE levels have generally decreased in
other monitoring wells over the brief history of the site except for MW-5 which is believed to be
influenced by drawdown effects from SW-1. MW-5 showed an increase in Benzene during the
June 27, 2017 sampling event, and SW-1 showed a significant increase in MTBE concentration
during the June 27, 2017 sampling event to a level above 2L Standards.

o Due to the observed 2L violation in off-site supply well SW-1, Rose Oil Company, Inc. has a
verbal agreement to connect all the SW-1 users to municipal water supply to reduce the risk of
this site. Competitive bids are being obtained at the time of this report.

3.2 Recommendations

Based on information obtained during this sampling event, Henry Nemargut Engineering Services
makes the following recommendations for this site:

o The SW-1 users should be connected to municipal water supplies once competitive bids are
obtained.

o MW-9 should be subjected to an AFVR event in November, 2017 to remove residual free
product previously observed in this well with a semi-annual monitoring event conducted in
December, 2017 to document benzene levels.

A copy of this monitoring report has been forwarded to:

Sean Patrick
NCDEQ-RRO UST Section
3800 Barrett Drive
Raleigh, NC 27609
Page - 5

3.3 Limitations

This report has been prepared for the exclusive use of Rose Oil Company, Inc. for the specific
application to the referenced site located in Wilson County, North Carolina. The assessment was
conducted based on the scope of work and level of effort desired by the client. Our findings have been
developed in accordance with generally accepted standards in the practice of Groundwater Monitoring
in the State of North Carolina, available information and our professional judgment. No other warranty
is expressed or implied.

The data presented in this report are indicative of conditions that existed at the precise locations sampled
and at the time the samples were collected. Additionally, the data obtained from the samples would be
interpreted as meaningful with respect to the parameters indicated in the laboratory reports. No
additional information can be logically inferred from this data.

FIGURES

TABLES
TABLE 1Monitoring Well Information and Groundwater ElevationsFriendly Mart, 3055 Stantonsburg, NC 27893Well Number Top of Casing Elevation Top of Screen Elevation Bottom of Screen Elevation Depth to Water Groundwater ElevationMW-1 99.79 95.79 85.79 3.49 96.30MW-2 100.00 96.00 86.00 not measured #VALUE!MW-3 99.19 95.19 85.19 4.03 95.16MW-4 99.88 95.88 85.88 4.73 95.15MW-5 99.42 94.42 84.42 6.84 92.58MW-6 99.78 94.78 84.78 8.95 90.83MW-7 100.06 95.06 85.06 8.59 91.47MW-8 100.52 95.52 85.52 6.60 93.92MW-9 100.01 95.01 85.01 5.95 94.06MW-10 98.50 81.00 71.00 8.01 90.49MW-11 98.00 91.00 81.00 7.84 90.16VEW-1 100.16 25.16 20.16 not measured #VALUE!All measurements taken in feet and based on an arbitrary benchmark of 100 ft. established at MW-1Groundwater levels measured on 6/27/2017Friendly Mart
TABLE 2
SUMMARY OF GROUNDWATER ANALYTICAL RESULTS
FRIENDLY MART
3055 STANTONSBURG RD, WILSON, NC
Constituent MW-1 MW-3 MW-4 MW-5 GCL 2L Standard

Date 6/27/2017 6/27/2017 6/27/2017 6/27/2017
Method 6200B (ug/L)
Benzene 1.1 0.54 484 21.2 5,000 1
Toluene 4.1 BDL 630 BDL 260,000 600
Ethylbenzene BDL BDL 1240 BDL 84,500 600
Xylenes (total) 1.54 BDL 3089 BDL 85,500 500
BTEX (total) 6.74 0.54 5443 21.2 NSE NSE
p-Isopropyltoluene BDL BDL BDL BDL NSE NSE
Isopropylbenzene 2.2 BDL 83.2 BDL 25,000 70
Diisopropyl Ether (DIPE) BDL BDL 112 BDL 70,000 70
Naphthalene BDL BDL 414 19.7 6,000 6
sec-Butylbenzene BDL BDL BDL BDL 8,500 70
n-propylbenzene BDL BDL BDL BDL 30,000 70
Bromodichloromethene BDL BDL BDL BDL NSE NSE
Chloromethane 6.7 BDL BDL BDL 3,000 3.0
n-butylbenzene BDL BDL BDL BDL 6,900 70
Styrene BDL BDL BDL BDL 70,000 70
Methyl-tert-butyl-ether (MTBE) BDL 1.1 208 517 20,000 20
1,2,4-Trimethylbenzene BDL BDL 1390 BDL 28,500 400
1,3,5-Trimethylbenzene BDL BDL 367 BDL 25,000 400
1,2-Dibromoethane (EDB) BDL BDL BDL BDL 50 0.02
Lead (3010) N/A N/A N/A N/A 15,000 15
Method 625 (ug/L)
Acenaphthene N/A N/A N/A N/A 2,120 80
Phenol N/A N/A N/A N/A 30,000 30
Naphthalene N/A N/A N/A N/A 6,000 6
Total TICs N/A N/A N/A N/A NSE NSE
Aliphatic Fraction Classes (ug/L)
C5-C8 Volatile Aliphatics N/A N/A N/A N/A NSE 400
C9-C12 Volatile Aliphatics N/A N/A N/A N/A NSE NSE
C9-C18 Extractable Aliphatics N/A N/A N/A N/A NSE 700
C9-C18 Aliphatics (total) N/A N/A N/A N/A NSE 700
C19-C36 Extractable Aliphatics N/A N/A N/A N/A NSE 10,000
Aromatic Fraction Classes (ug/L)
C9-C10 Volatile Aromatics N/A N/A N/A N/A NSE NSE
C11-C22 Extractable Aromatics N/A N/A N/A N/A NSE NSE
C9-C22 Aromatics (total)N/A N/A N/A N/A NSE 200
N/A = Not Analyzed
BDL = Below Detection Limits
NSE = No Standard Established
TABLE 2 (continued)
SUMMARY OF GROUNDWATER ANALYTICAL RESULTS
FRIENDLY MART
3055 STANTONSBURG RD, WILSON, NC
Constituent MW-6 MW-7 MW-8 MW-9 GCL 2L Standard

Date 6/27/2017 6/27/2017 6/27/2017 6/27/2017
Method 6200B (ug/L)
Benzene BDL BDL BDL 13500 5,000 1
Toluene BDL BDL BDL 49600 260,000 600
Ethylbenzene BDL 0.68 BDL 4380 84,500 600
Xylenes (total) BDL BDL BDL 21190 85,500 500
BTEX (total) 0 0.68 0 88670 NSE NSE
p-Isopropyltoluene BDL BDL BDL BDL NSE NSE
Isopropylbenzene BDL BDL BDL BDL 25,000 70
Diisopropyl Ether (DIPE) 21.6 56.1 1.7 629 70,000 70
Naphthalene BDL BDL BDL BDL 6,000 6
sec-Butylbenzene BDL BDL BDL BDL 8,500 70
n-propylbenzene BDL BDL BDL BDL 30,000 70
Chloroform BDL BDL BDL BDL 70,000 70.0
n-butylbenzene BDL BDL BDL BDL 6,900 70
1,2-Dichloroethane BDL BDL BDL BDL 400 0.4
Methyl-tert-butyl-ether (MTBE)405 73 3.3 7810 20,000 20
1,2,4-Trimethylbenzene BDL BDL BDL 2400 28,500 400
1,3,5-Trimethylbenzene BDL BDL BDL BDL 25,000 400
1,2-Dibromoethane (EDB) BDL BDL BDL BDL 50 0.02
Methylene Chloride BDL BDL BDL BDL 5,000 5
Lead (3010) N/A N/A N/A N/A 15,000 15
Method 625 (ug/L)
Acenaphthene N/A N/A N/A N/A 2,120 80
Phenol N/A N/A N/A N/A 30,000 30
Naphthalene N/A N/A N/A N/A 6,000 6
Total TICs N/A N/A N/A N/A NSE NSE
Aliphatic Fraction Classes (ug/L)
C5-C8 Volatile Aliphatics N/A N/A N/A N/A NSE 400
C9-C12 Volatile Aliphatics N/A N/A N/A N/A NSE NSE
C9-C18 Extractable Aliphatics N/A N/A N/A N/A NSE 700
C9-C18 Aliphatics (total) N/A N/A N/A N/A NSE 700
C19-C36 Extractable Aliphatics N/A N/A N/A N/A NSE 10,000
Aromatic Fraction Classes (ug/L)
C9-C10 Volatile Aromatics N/A N/A N/A N/A NSE NSE
C11-C22 Extractable Aromatics N/A N/A N/A N/A NSE NSE
C9-C22 Aromatics (total)N/A N/A N/A N/A NSE 200
N/A = Not Analyzed
BDL = Below Detection Limits
NSE = No Standard Established
TABLE 2 (continued)
SUMMARY OF GROUNDWATER ANALYTICAL RESULTS
FRIENDLY MART
3055 STANTONSBURG RD, WILSON, NC
Constituent MW-10 MW-11 SW-1 GCL 2L Standard

Date 6/27/2017 6/27/2017 6/27/2017
Method 6200B (ug/L)
Benzene BDL BDL BDL 5,000 1
Toluene BDL BDL BDL 260,000 600
Ethylbenzene BDL BDL BDL 84,500 600
Xylenes (total) BDL BDL BDL 85,500 500
BTEX (total) 0 0 0 NSE NSE
p-Isopropyltoluene BDL BDL BDL NSE NSE
Isopropylbenzene BDL BDL BDL 25,000 70
Diisopropyl Ether (DIPE) BDL BDL BDL 70,000 70
Naphthalene BDL BDL BDL 6,000 6
sec-Butylbenzene BDL BDL BDL 8,500 70
n-propylbenzene BDL BDL BDL 30,000 70
Chloroform BDL BDL BDL 70,000 70.0
n-butylbenzene BDL BDL BDL 6,900 70
1,2-Dichloroethane BDL BDL BDL 400 0.4
Methyl-tert-butyl-ether (MTBE) BDL BDL 23.7 20,000 20
1,2,4-Trimethylbenzene BDL BDL BDL 28,500 400
1,3,5-Trimethylbenzene BDL BDL BDL 25,000 400
1,2-Dibromoethane (EDB) BDL BDL BDL 50 0.02
Lead (3010) N/A N/A N/A 15,000 15
Method 625 (ug/L)
Acenaphthene N/A N/A N/A 2,120 80
Phenol N/A N/A N/A 30,000 30
Naphthalene N/A N/A N/A 6,000 6
Total TICs N/A N/A N/A NSE NSE
Aliphatic Fraction Classes (ug/L)
C5-C8 Volatile Aliphatics N/A N/A N/A NSE 400
C9-C12 Volatile Aliphatics N/A N/A N/A NSE NSE
C9-C18 Extractable Aliphatics N/A N/A N/A NSE 700
C9-C18 Aliphatics (total) N/A N/A N/A NSE 700
C19-C36 Extractable Aliphatics N/A N/A N/A NSE 10,000
Aromatic Fraction Classes (ug/L)
C9-C10 Volatile Aromatics N/A N/A N/A NSE NSE
C11-C22 Extractable Aromatics N/A N/A N/A NSE NSE
C9-C22 Aromatics (total)N/A N/A N/A NSE 200
N/A = Not Analyzed
BDL = Below Detection Limits
NSE = No Standard Established
TABLE 3TABLE 3Time Based Analytical Data BenzeneTime Based Analytical Data - BenzeneFi dl M tFriendly Marty3055 Stantonsburg Road Wilson NC3055 Stantonsburg Road, Wilson, NCDate of SamplingMW 1MW 2MW 3MW 4MW 5MW 7MW 8MW 9Date of SamplingMW-1MW-2MW-3MW-4MW-5MW-7MW-8MW-94/20/2016381020238304/20/20163810202383012/8/201600417154071114 00012/8/201600417154071114,0006/27/201711484210013 5006/27/201711484210013,500Results in ug/lResults in ug/l

APPENDIX A

WELL CONSTRUCTION RECORDS
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6/28/2017
1. WELL CONTRACTOR:
Henry Nemargut
Well Contractor (Individual) Name
Henry Nemargut Engineering Services
Well Contractor Company Name
STREET ADDRESS 2211 Chestnut Street
Wilmington NC
City or Town State
~, 762,5475
Area code- Phone number
2. WELL INFORMATION:
SITE WELL ID #(if applicable),_M_W_'_10
STATE WELL PERMIT#(if applicable),
DWQ or OTHER PERMIT #(if applicable)
WELL USE (Check Applicable Box) Monitoring tKl
Industrial/CommercialD AgriculturalO Recovery 0 Injection 0
IrrigationD Other 0 (list use) _
DATE DRILLED,_6/_2_6/_2_01_7 _
TIME COMPLETED_1_:0_0 AM 0 PM ~
3. WELL LOCATION:
CITY: Wilson COUNTy_W_ils_o_n _
3055 Stantonsburg Rd, Wilson, NC 27893
(Street Name. Numbers. Community, Subdivision. Lot No., Parcel, Zip Code)
TOPOGRAPHIC / LAND SETTING:
DSlope DValley []Flat DRidge DOther _
(check appropriate box)
LATITUDE -L _ 35.69099167 May be in degrees,
minutes. seconds or
LONGITUDE 7788775 in a decnna I format
Latitude/longitude source: J0GPS DTopographic map
(/ocation of well must be shown on a USGS topo map and
attached to this form if not using GPS)
4. FACIL1TY-is the name of the business where the well is located,
FACILITY ID #(if applicable)_0:..,.:.:02:..4:.,:5:.:8.:.:9 _
NAME OF FACILlTy_F_r....:ie_n.:...dl"'-Y_M-'a_rt _
STREET ADDRESS 3055 Stantonsburg Road

Wilson NC 27893

City or Town State Zip Code
CONTACT PERSON Raymond Bartholomew
MAILING ADDRESS,...:P...,:.:.:O.:,.. .:.:Bo:.:x:..7:..,:0:.:6 _
Henderson NC 27536­
City or Town State

(252 ),_4_3_8-_7_14_1 _

Area code· Phone number

5. WELL DETAILS:
a. TOTAL DEPTH:_1_7_.5_' _
b. DOES WELL REPLACE EXISTING WELL?
c. WATER LEVEL Below Top of Casing: 8.01'
(Use "+" if Above Top of Casing)
NONRESIDENTIAL WELL CONSTRUCTION RECORD , ...
North Carolina Department ofEnvironment and Natural Resources-Division of Water Quality
WELL CONTRACTOR CERTIFICATION # ...:;:3;..:.42::..;6'----_
Zip Code
YES 0 NO IZJ
FT.
28405
Zip Code
_
_
_
Municipal/Public 0
d. TOP OF CASING IS 0' FT. Above Land Surface'
'Top of casing terminated aVor below land surface may require
a variance in accordance with 15A NCAC 2C .0118.
e. YIELD (gpm): METHOD OF TEST
f. DISINFECTION: Type
g. WATER ZONES (depth):
From--­To--­
From--­To___
From--­To___
6. CASING:
Depth !?iameter WeightSch 40 From_O_'__ To~Fl._2_'__

From To Ft. _

From To Ft. _

7. GROUT: Depth Material Method
From_O_'__ To~Fl. Portland
From To Ft.
From To Ft.
8. SCREEN: Depth Diameter
2From~ To~ Ft.___in.
From Ft.--in.To___
From---Ft in.To___
9. SAND/GRAVEL PACK:
Depth Size
From 6.5' To_1_8'__ Ft. #2
From To___ Ft.
From To Ft.
10. DRILLING LOG
From To
0' 3'
3' 8'
8' 16'
16' 18'
11. REMARKS:
I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED tN ACCORDANCE WITH
15A NCAC 2C. WELL CONSTRUCTION STANDARDS. AND THAT A COPY OF THIS
RECORD HAS BEEN P VIDEO TO THE WELL OWNE8.
DATE
Formation Description
gray-brawn-tan. Silt w/gravel & some clay
orange-tan. Silt w/clay
orange-tan, Clay w/silt
gray-tan, Clay w/silt
Amount
To___
From---To___
From To___
From--­
Thickness/
Pour
_
_
Slot Size Material
001 in. PVC
in.
in.
Material
Filter Sand
Submit the original to the Division of Water Quality within 30 days. Attn: Information Mgt., Form GW,1b1617 Mail Service Center -Raleigh, NC 27699-1617 Phone No. (919) 733·7015 ext 568. Rev. 7/05
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--
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-------- --
---
--
,.:...>­
1. WELL CONTRACTOR:
Henry Nemargut
Well Contractor (Individual) Name
Henry Nemargut Engineering Services

Well Contractor Company Name

2211 Chestnut StreetSTREET ADDRESS
Wilmington NC 28405

City or Town State Zip Code

~_ 762-5475

Area code-Phone number

2. WELL INFORMATION:
SITE WELL 10 #(if applicable) MW-11

STATE WELL PERMIT#(if applicable)

DWQ or OTHER PERMIT #(if applicable)
WELL USE (Check Applicable Box) Monitoring IZJ MunicipallPublic 0
IndustriallCommercialD Agricultural 0 Recovery 0 Injection 0
Irrigationo Other 0 (list use)
DATE DRILLED 6/26/2017
TIME COMPLETED 5:00 AMo PM~
3. WELL LOCATION:
CITY: Wilson COUNTY Wilson
3055 Stantonsburg Rd, Wilson, NC 27893
(Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code)
TOPOGRAPHIC I LAND SETTING: .
o Slope 0 Valley KJ Flat o Ridge 0 Other
(check appropriate box)
Mal' be in degrees,-L_ 35.69099167LATITUDE mintltes. seconds or
LONGITUDE 77.88775 in a decimal fonmat
Latitude/longitude source: ;0GPS o Topographic map

(location of well must be shown on a USGS tapa map and

attached to this form if not using GPS)

4. FACILITY-is the name of the business where the well is located.
FACILITY ID #(if applicable) 0-024589
NAME OF FACILITY Friendly Mart
STREET ADDRESS 3055 Stantonsburg Road
Wilson NC 27893
City or Town State Zip Code
CONTACT PERSON Raymond Bartholomew
MAILING ADDRESS PO Box 706
Henderson NC
City or Town State
( 252 )-438-7141
Area code· Phone number
5. WELL DETAILS:
17.5'a. TOTAL DEPTH:
b. DOES WELL REPLACE EXISTING WELL?
c. WATER LEVEL Below Top of Casing: 7.84'
(Use "+" if Above Top of Casing)
NON RESIDENTIAL WELL CONSTRUCTION RECORD
North Carolina Department of Environment and Natural Resources-Division of Water Quality
WELL CONTRACTOR CERTIFICATION # --.::3~4.=.:26::....-
2753&
Zip Code
YESO NO~
FT.
_
d. TOP OF CASING IS 0' FT. Above Land Surface*
*Top of casing terminated at/or below land surface may require
a variance in accordance with 15A NCAC 2C .0118.
e. YIELD (gpm): METHOD OF TEST
f. DISINFECTION: Type
g. WATER ZONES (depth)
From--­To--­
From To--­--­
From To--­--­
6. CASING:
Depth Qiameter
From_O_'__ To~ Ft. 2'
From To___ Ft.
From Ft.To___
7. GROUT: Depth Material Method
From 0' To-=-Ft.--­
Portland Pour
From To___ Ft.--­
From To___ Ft.--­
8. SCREEN: Depth Diameter Slot Size Material
2 001 PVC
From To Ft. in. in.
From To Ft in. in.
From~To~Ft.___in. in.
9. SANDIGRAVEL PACK:
Depth Size Material
From 65' To_1_8'__ Ft. #2 Filter Sand
From To Ft.
From To___ Ft.
10. DRILLING LOG
From To
0' 3'
3' 7'
7' 10'
10' 16'
16' 18'
11. REMARKS:
I DO HEREBY CERnFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH
15A NCAC 2C, WELL CONSTRUCTION STANDARDS, AND THAT ACOPY OF THIS R~:AS BEEN ~DED TO"7OWNER.
F ""). _ ........ -y 6/28/2017
SIGNATURE'OF CERTI~I~WELLCONTRACTOR DATE
J-I-.eY) (1."1 NeA~ ('<."'-~
PRINTED NAMt= OF PERSON CONe1RUCTING THE WELL
Formation Description
gray, Silt wlsome clay & sand
tan·brown, Silt w/clay
tan-orange, Clay wlsand & silt
orange-tan, Clay wlsilt
gray, Soft Clay
Amount
From--­To___
To___From
To___From
Thicknessl
~eigh6 ~~eialcH 4
Submit the original to the Division of Water Quality within 30 days. Attn: Information Mgt., Form GW-1b1617 Mail Service Center-Raleigh, NC 27699-1617 Phone No. [phone] ext 568. Rev. 7/05

APPENDIX B

LABORATORY ANALYTICAL RESULTS
#=CL#
July 07, 2017
LIMS USE: FR - HENRY NEMARGUT
LIMS OBJECT ID: 92346051
92346051
Project:
Pace Project No.:
RE:
Henry Nemargut
Henry Nemargut Engineering
2211 Chestnut Street
Wilmington, NC 28405
FRIENDLY MART
Dear Henry Nemargut:
Enclosed are the analytical results for sample(s) received by the laboratory on June 29, 2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
1(704)875-9092
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 56
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 56
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92346051
FRIENDLY MART
Lab ID Sample ID Matrix Date Collected Date Received
92346051001 MW 1 Water 06/27/17 07:40 06/29/17 09:28
92346051002 MW 3 Water 06/27/17 08:10 06/29/17 09:28
92346051003 MW 4 Water 06/27/17 08:35 06/29/17 09:28
92346051004 MW 5 Water 06/27/17 09:00 06/29/17 09:28
92346051005 MW 6 Water 06/27/17 09:25 06/29/17 09:28
92346051006 MW 7 Water 06/27/17 09:50 06/29/17 09:28
92346051007 MW 8 Water 06/27/17 10:20 06/29/17 09:28
92346051008 MW 9 Water 06/27/17 10:50 06/29/17 09:28
92346051009 MW 10 Water 06/27/17 11:20 06/29/17 09:28
92346051010 MW 11 Water 06/27/17 11:50 06/29/17 09:28
92346051011 SW 1 Water 06/27/17 12:15 06/29/17 09:28
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 56
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92346051
FRIENDLY MART
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92346051001 MW 1 SM 6200B 63 PASI-CCAH
92346051002 MW 3 SM 6200B 63 PASI-CCAH
92346051003 MW 4 SM 6200B 63 PASI-CCAH
92346051004 MW 5 SM 6200B 63 PASI-CCAH
92346051005 MW 6 SM 6200B 63 PASI-CCAH
92346051006 MW 7 SM 6200B 63 PASI-CGAW
92346051007 MW 8 SM 6200B 63 PASI-CGAW
92346051008 MW 9 SM 6200B 63 PASI-CCAH
92346051009 MW 10 SM 6200B 63 PASI-CGAW
92346051010 MW 11 SM 6200B 63 PASI-CGAW
92346051011 SW 1 SM 6200B 63 PASI-CZDO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 56
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92346051
FRIENDLY MART
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92346051001 MW 1
Benzene 1.1 ug/L 07/03/17 15:370.50SM 6200B
Chloromethane 6.7 ug/L 07/03/17 15:371.0SM 6200B
Isopropylbenzene (Cumene) 2.2 ug/L 07/03/17 15:370.50SM 6200B
Toluene 4.1 ug/L 07/03/17 15:370.50SM 6200B
m&p-Xylene 1.0 ug/L 07/03/17 15:371.0SM 6200B
o-Xylene 0.54 ug/L 07/03/17 15:370.50SM 6200B
92346051002 MW 3
Benzene 0.54 ug/L 07/03/17 15:540.50SM 6200B
Methyl-tert-butyl ether 1.1 ug/L 07/03/17 15:540.50SM 6200B
92346051003 MW 4
Benzene 484 ug/L 07/03/17 16:286.2SM 6200B
Diisopropyl ether 112 ug/L 07/03/17 16:286.2SM 6200B
Ethylbenzene 1240 ug/L 07/03/17 16:286.2SM 6200B
Isopropylbenzene (Cumene) 83.2 ug/L 07/03/17 16:286.2SM 6200B
Methyl-tert-butyl ether 208 ug/L 07/03/17 16:286.2SM 6200B
Naphthalene 414 ug/L 07/03/17 16:2825.0SM 6200B
Toluene 630 ug/L 07/03/17 16:286.2SM 6200B
1,2,4-Trimethylbenzene 1390 ug/L 07/03/17 16:286.2SM 6200B
1,3,5-Trimethylbenzene 367 ug/L 07/03/17 16:286.2SM 6200B
m&p-Xylene 2540 ug/L 07/03/17 16:2812.5SM 6200B
o-Xylene 549 ug/L 07/03/17 16:286.2SM 6200B
92346051004 MW 5
Benzene 21.2 ug/L 07/03/17 16:452.0SM 6200B
Methyl-tert-butyl ether 517 ug/L 07/03/17 16:452.0SM 6200B
Naphthalene 19.7 ug/L 07/03/17 16:458.0SM 6200B
92346051005 MW 6
Diisopropyl ether 21.6 ug/L 07/07/17 11:532.0SM 6200B
Methyl-tert-butyl ether 405 ug/L 07/07/17 11:532.0SM 6200B
92346051006 MW 7
Diisopropyl ether 56.1 ug/L 06/30/17 06:130.50SM 6200B
Ethylbenzene 0.68 ug/L 06/30/17 06:130.50SM 6200B
Methyl-tert-butyl ether 73.0 ug/L 06/30/17 06:130.50SM 6200B
92346051007 MW 8
Diisopropyl ether 1.7 ug/L 06/30/17 06:300.50SM 6200B
Methyl-tert-butyl ether 3.3 ug/L 06/30/17 06:300.50SM 6200B
92346051008 MW 9
Benzene 13500 ug/L 07/06/17 17:54200SM 6200B
Diisopropyl ether 629 ug/L 07/06/17 17:54200SM 6200B
Ethylbenzene 4380 ug/L 07/06/17 17:54200SM 6200B
Methyl-tert-butyl ether 7810 ug/L 07/06/17 17:54200SM 6200B
Toluene 49600 ug/L 07/06/17 17:54200SM 6200B
1,2,4-Trimethylbenzene 2400 ug/L 07/06/17 17:54200SM 6200B
m&p-Xylene 14300 ug/L 07/06/17 17:54400SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 56
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92346051
FRIENDLY MART
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92346051008 MW 9
o-Xylene 6890 ug/L 07/06/17 17:54200SM 6200B
92346051011 SW 1
Methyl-tert-butyl ether 23.7 ug/L 06/30/17 02:130.50SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 1 Lab ID: 92346051001 Collected: 06/27/17 07:40 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene 1.1 ug/L 07/03/17 15:37 71-43-20.50 1
Bromobenzene ND ug/L 07/03/17 15:37 108-86-10.50 1
Bromochloromethane ND ug/L 07/03/17 15:37 74-97-50.50 1
Bromodichloromethane ND ug/L 07/03/17 15:37 75-27-40.50 1
Bromoform ND ug/L 07/03/17 15:37 75-25-20.50 1
Bromomethane ND ug/L 07/03/17 15:37 74-83-95.0 1
n-Butylbenzene ND ug/L 07/03/17 15:37 104-51-80.50 1
sec-Butylbenzene ND ug/L 07/03/17 15:37 135-98-80.50 1
tert-Butylbenzene ND ug/L 07/03/17 15:37 98-06-60.50 1
Carbon tetrachloride ND ug/L 07/03/17 15:37 56-23-50.50 1
Chlorobenzene ND ug/L 07/03/17 15:37 108-90-70.50 1
Chloroethane ND ug/L 07/03/17 15:37 75-00-31.0 1
Chloroform ND ug/L 07/03/17 15:37 67-66-30.50 1
Chloromethane 6.7 ug/L 07/03/17 15:37 74-87-31.0 1
2-Chlorotoluene ND ug/L 07/03/17 15:37 95-49-80.50 1
4-Chlorotoluene ND ug/L 07/03/17 15:37 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 07/03/17 15:37 96-12-81.0 1
Dibromochloromethane ND ug/L 07/03/17 15:37 124-48-10.50 1
1,2-Dibromoethane (EDB) ND ug/L 07/03/17 15:37 106-93-40.50 1
Dibromomethane ND ug/L 07/03/17 15:37 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 07/03/17 15:37 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 07/03/17 15:37 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 07/03/17 15:37 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 07/03/17 15:37 75-71-80.50 1
1,1-Dichloroethane ND ug/L 07/03/17 15:37 75-34-30.50 1
1,2-Dichloroethane ND ug/L 07/03/17 15:37 107-06-20.50 1
1,1-Dichloroethene ND ug/L 07/03/17 15:37 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 07/03/17 15:37 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 07/03/17 15:37 156-60-50.50 1
1,2-Dichloropropane ND ug/L 07/03/17 15:37 78-87-50.50 1
1,3-Dichloropropane ND ug/L 07/03/17 15:37 142-28-90.50 1
2,2-Dichloropropane ND ug/L 07/03/17 15:37 594-20-70.50 1
1,1-Dichloropropene ND ug/L 07/03/17 15:37 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 07/03/17 15:37 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 07/03/17 15:37 10061-02-60.50 1
Diisopropyl ether ND ug/L 07/03/17 15:37 108-20-30.50 1
Ethylbenzene ND ug/L 07/03/17 15:37 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 07/03/17 15:37 87-68-32.0 1
Isopropylbenzene (Cumene)2.2 ug/L 07/03/17 15:37 98-82-80.50 1
Methylene Chloride ND ug/L 07/03/17 15:37 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 07/03/17 15:37 1634-04-40.50 1
Naphthalene ND ug/L 07/03/17 15:37 91-20-32.0 1
n-Propylbenzene ND ug/L 07/03/17 15:37 103-65-10.50 1
Styrene ND ug/L 07/03/17 15:37 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 07/03/17 15:37 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 07/03/17 15:37 79-34-50.50 1
Tetrachloroethene ND ug/L 07/03/17 15:37 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 1 Lab ID: 92346051001 Collected: 06/27/17 07:40 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene 4.1 ug/L 07/03/17 15:37 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 07/03/17 15:37 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 07/03/17 15:37 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 07/03/17 15:37 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 07/03/17 15:37 79-00-50.50 1
Trichloroethene ND ug/L 07/03/17 15:37 79-01-60.50 1
Trichlorofluoromethane ND ug/L 07/03/17 15:37 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 07/03/17 15:37 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 07/03/17 15:37 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 07/03/17 15:37 108-67-80.50 1
Vinyl chloride ND ug/L 07/03/17 15:37 75-01-41.0 1
m&p-Xylene 1.0 ug/L 07/03/17 15:37 179601-23-11.0 1
o-Xylene 0.54 ug/L 07/03/17 15:37 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S) 106 % 07/03/17 15:37 17060-07-070-130 1
4-Bromofluorobenzene (S) 99 % 07/03/17 15:37 460-00-470-130 1
Toluene-d8 (S) 103 % 07/03/17 15:37 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 3 Lab ID: 92346051002 Collected: 06/27/17 08:10 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene 0.54 ug/L 07/03/17 15:54 71-43-20.50 1
Bromobenzene ND ug/L 07/03/17 15:54 108-86-10.50 1
Bromochloromethane ND ug/L 07/03/17 15:54 74-97-50.50 1
Bromodichloromethane ND ug/L 07/03/17 15:54 75-27-40.50 1
Bromoform ND ug/L 07/03/17 15:54 75-25-20.50 1
Bromomethane ND ug/L 07/03/17 15:54 74-83-95.0 1
n-Butylbenzene ND ug/L 07/03/17 15:54 104-51-80.50 1
sec-Butylbenzene ND ug/L 07/03/17 15:54 135-98-80.50 1
tert-Butylbenzene ND ug/L 07/03/17 15:54 98-06-60.50 1
Carbon tetrachloride ND ug/L 07/03/17 15:54 56-23-50.50 1
Chlorobenzene ND ug/L 07/03/17 15:54 108-90-70.50 1
Chloroethane ND ug/L 07/03/17 15:54 75-00-31.0 1
Chloroform ND ug/L 07/03/17 15:54 67-66-30.50 1
Chloromethane ND ug/L 07/03/17 15:54 74-87-31.0 1
2-Chlorotoluene ND ug/L 07/03/17 15:54 95-49-80.50 1
4-Chlorotoluene ND ug/L 07/03/17 15:54 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 07/03/17 15:54 96-12-81.0 1
Dibromochloromethane ND ug/L 07/03/17 15:54 124-48-10.50 1
1,2-Dibromoethane (EDB) ND ug/L 07/03/17 15:54 106-93-40.50 1
Dibromomethane ND ug/L 07/03/17 15:54 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 07/03/17 15:54 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 07/03/17 15:54 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 07/03/17 15:54 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 07/03/17 15:54 75-71-80.50 1
1,1-Dichloroethane ND ug/L 07/03/17 15:54 75-34-30.50 1
1,2-Dichloroethane ND ug/L 07/03/17 15:54 107-06-20.50 1
1,1-Dichloroethene ND ug/L 07/03/17 15:54 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 07/03/17 15:54 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 07/03/17 15:54 156-60-50.50 1
1,2-Dichloropropane ND ug/L 07/03/17 15:54 78-87-50.50 1
1,3-Dichloropropane ND ug/L 07/03/17 15:54 142-28-90.50 1
2,2-Dichloropropane ND ug/L 07/03/17 15:54 594-20-70.50 1
1,1-Dichloropropene ND ug/L 07/03/17 15:54 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 07/03/17 15:54 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 07/03/17 15:54 10061-02-60.50 1
Diisopropyl ether ND ug/L 07/03/17 15:54 108-20-30.50 1
Ethylbenzene ND ug/L 07/03/17 15:54 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 07/03/17 15:54 87-68-32.0 1
Isopropylbenzene (Cumene) ND ug/L 07/03/17 15:54 98-82-80.50 1
Methylene Chloride ND ug/L 07/03/17 15:54 75-09-22.0 1
Methyl-tert-butyl ether 1.1 ug/L 07/03/17 15:54 1634-04-40.50 1
Naphthalene ND ug/L 07/03/17 15:54 91-20-32.0 1
n-Propylbenzene ND ug/L 07/03/17 15:54 103-65-10.50 1
Styrene ND ug/L 07/03/17 15:54 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 07/03/17 15:54 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 07/03/17 15:54 79-34-50.50 1
Tetrachloroethene ND ug/L 07/03/17 15:54 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 3 Lab ID: 92346051002 Collected: 06/27/17 08:10 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene ND ug/L 07/03/17 15:54 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 07/03/17 15:54 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 07/03/17 15:54 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 07/03/17 15:54 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 07/03/17 15:54 79-00-50.50 1
Trichloroethene ND ug/L 07/03/17 15:54 79-01-60.50 1
Trichlorofluoromethane ND ug/L 07/03/17 15:54 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 07/03/17 15:54 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 07/03/17 15:54 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 07/03/17 15:54 108-67-80.50 1
Vinyl chloride ND ug/L 07/03/17 15:54 75-01-41.0 1
m&p-Xylene ND ug/L 07/03/17 15:54 179601-23-11.0 1
o-Xylene ND ug/L 07/03/17 15:54 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S) 103 % 07/03/17 15:54 17060-07-070-130 1
4-Bromofluorobenzene (S) 101 % 07/03/17 15:54 460-00-470-130 1
Toluene-d8 (S) 105 % 07/03/17 15:54 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 4 Lab ID: 92346051003 Collected: 06/27/17 08:35 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene 484 ug/L 07/03/17 16:28 71-43-26.2 12.5
Bromobenzene ND ug/L 07/03/17 16:28 108-86-16.2 12.5
Bromochloromethane ND ug/L 07/03/17 16:28 74-97-56.2 12.5
Bromodichloromethane ND ug/L 07/03/17 16:28 75-27-46.2 12.5
Bromoform ND ug/L 07/03/17 16:28 75-25-26.2 12.5
Bromomethane ND ug/L 07/03/17 16:28 74-83-962.5 12.5
n-Butylbenzene ND ug/L 07/03/17 16:28 104-51-86.2 12.5
sec-Butylbenzene ND ug/L 07/03/17 16:28 135-98-86.2 12.5
tert-Butylbenzene ND ug/L 07/03/17 16:28 98-06-66.2 12.5
Carbon tetrachloride ND ug/L 07/03/17 16:28 56-23-56.2 12.5
Chlorobenzene ND ug/L 07/03/17 16:28 108-90-76.2 12.5
Chloroethane ND ug/L 07/03/17 16:28 75-00-312.5 12.5
Chloroform ND ug/L 07/03/17 16:28 67-66-36.2 12.5
Chloromethane ND ug/L 07/03/17 16:28 74-87-312.5 12.5
2-Chlorotoluene ND ug/L 07/03/17 16:28 95-49-86.2 12.5
4-Chlorotoluene ND ug/L 07/03/17 16:28 106-43-46.2 12.5
1,2-Dibromo-3-chloropropane ND ug/L 07/03/17 16:28 96-12-812.5 12.5
Dibromochloromethane ND ug/L 07/03/17 16:28 124-48-16.2 12.5
1,2-Dibromoethane (EDB) ND ug/L 07/03/17 16:28 106-93-46.2 12.5
Dibromomethane ND ug/L 07/03/17 16:28 74-95-36.2 12.5
1,2-Dichlorobenzene ND ug/L 07/03/17 16:28 95-50-16.2 12.5
1,3-Dichlorobenzene ND ug/L 07/03/17 16:28 541-73-16.2 12.5
1,4-Dichlorobenzene ND ug/L 07/03/17 16:28 106-46-76.2 12.5
Dichlorodifluoromethane ND ug/L 07/03/17 16:28 75-71-86.2 12.5
1,1-Dichloroethane ND ug/L 07/03/17 16:28 75-34-36.2 12.5
1,2-Dichloroethane ND ug/L 07/03/17 16:28 107-06-26.2 12.5
1,1-Dichloroethene ND ug/L 07/03/17 16:28 75-35-46.2 12.5
cis-1,2-Dichloroethene ND ug/L 07/03/17 16:28 156-59-26.2 12.5
trans-1,2-Dichloroethene ND ug/L 07/03/17 16:28 156-60-56.2 12.5
1,2-Dichloropropane ND ug/L 07/03/17 16:28 78-87-56.2 12.5
1,3-Dichloropropane ND ug/L 07/03/17 16:28 142-28-96.2 12.5
2,2-Dichloropropane ND ug/L 07/03/17 16:28 594-20-76.2 12.5
1,1-Dichloropropene ND ug/L 07/03/17 16:28 563-58-66.2 12.5
cis-1,3-Dichloropropene ND ug/L 07/03/17 16:28 10061-01-56.2 12.5
trans-1,3-Dichloropropene ND ug/L 07/03/17 16:28 10061-02-66.2 12.5
Diisopropyl ether 112 ug/L 07/03/17 16:28 108-20-36.2 12.5
Ethylbenzene 1240 ug/L 07/03/17 16:28 100-41-46.2 12.5
Hexachloro-1,3-butadiene ND ug/L 07/03/17 16:28 87-68-325.0 12.5
Isopropylbenzene (Cumene)83.2 ug/L 07/03/17 16:28 98-82-86.2 12.5
Methylene Chloride ND ug/L 07/03/17 16:28 75-09-225.0 12.5
Methyl-tert-butyl ether 208 ug/L 07/03/17 16:28 1634-04-46.2 12.5
Naphthalene 414 ug/L 07/03/17 16:28 91-20-325.0 12.5
n-Propylbenzene ND ug/L 07/03/17 16:28 103-65-16.2 12.5
Styrene ND ug/L 07/03/17 16:28 100-42-56.2 12.5
1,1,1,2-Tetrachloroethane ND ug/L 07/03/17 16:28 630-20-66.2 12.5
1,1,2,2-Tetrachloroethane ND ug/L 07/03/17 16:28 79-34-56.2 12.5
Tetrachloroethene ND ug/L 07/03/17 16:28 127-18-46.2 12.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 4 Lab ID: 92346051003 Collected: 06/27/17 08:35 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene 630 ug/L 07/03/17 16:28 108-88-36.2 12.5
1,2,3-Trichlorobenzene ND ug/L 07/03/17 16:28 87-61-625.0 12.5
1,2,4-Trichlorobenzene ND ug/L 07/03/17 16:28 120-82-125.0 12.5
1,1,1-Trichloroethane ND ug/L 07/03/17 16:28 71-55-66.2 12.5
1,1,2-Trichloroethane ND ug/L 07/03/17 16:28 79-00-56.2 12.5
Trichloroethene ND ug/L 07/03/17 16:28 79-01-66.2 12.5
Trichlorofluoromethane ND ug/L 07/03/17 16:28 75-69-412.5 12.5
1,2,3-Trichloropropane ND ug/L 07/03/17 16:28 96-18-46.2 12.5
1,2,4-Trimethylbenzene 1390 ug/L 07/03/17 16:28 95-63-66.2 12.5
1,3,5-Trimethylbenzene 367 ug/L 07/03/17 16:28 108-67-86.2 12.5
Vinyl chloride ND ug/L 07/03/17 16:28 75-01-412.5 12.5
m&p-Xylene 2540 ug/L 07/03/17 16:28 179601-23-112.5 12.5
o-Xylene 549 ug/L 07/03/17 16:28 95-47-66.2 12.5
Surrogates
1,2-Dichloroethane-d4 (S) 107 % 07/03/17 16:28 17060-07-070-130 12.5
4-Bromofluorobenzene (S) 102 % 07/03/17 16:28 460-00-470-130 12.5
Toluene-d8 (S) 101 % 07/03/17 16:28 2037-26-570-130 12.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 5 Lab ID: 92346051004 Collected: 06/27/17 09:00 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene 21.2 ug/L 07/03/17 16:45 71-43-22.0 4
Bromobenzene ND ug/L 07/03/17 16:45 108-86-12.0 4
Bromochloromethane ND ug/L 07/03/17 16:45 74-97-52.0 4
Bromodichloromethane ND ug/L 07/03/17 16:45 75-27-42.0 4
Bromoform ND ug/L 07/03/17 16:45 75-25-22.0 4
Bromomethane ND ug/L 07/03/17 16:45 74-83-920.0 4
n-Butylbenzene ND ug/L 07/03/17 16:45 104-51-82.0 4
sec-Butylbenzene ND ug/L 07/03/17 16:45 135-98-82.0 4
tert-Butylbenzene ND ug/L 07/03/17 16:45 98-06-62.0 4
Carbon tetrachloride ND ug/L 07/03/17 16:45 56-23-52.0 4
Chlorobenzene ND ug/L 07/03/17 16:45 108-90-72.0 4
Chloroethane ND ug/L 07/03/17 16:45 75-00-34.0 4
Chloroform ND ug/L 07/03/17 16:45 67-66-32.0 4
Chloromethane ND ug/L 07/03/17 16:45 74-87-34.0 4
2-Chlorotoluene ND ug/L 07/03/17 16:45 95-49-82.0 4
4-Chlorotoluene ND ug/L 07/03/17 16:45 106-43-42.0 4
1,2-Dibromo-3-chloropropane ND ug/L 07/03/17 16:45 96-12-84.0 4
Dibromochloromethane ND ug/L 07/03/17 16:45 124-48-12.0 4
1,2-Dibromoethane (EDB) ND ug/L 07/03/17 16:45 106-93-42.0 4
Dibromomethane ND ug/L 07/03/17 16:45 74-95-32.0 4
1,2-Dichlorobenzene ND ug/L 07/03/17 16:45 95-50-12.0 4
1,3-Dichlorobenzene ND ug/L 07/03/17 16:45 541-73-12.0 4
1,4-Dichlorobenzene ND ug/L 07/03/17 16:45 106-46-72.0 4
Dichlorodifluoromethane ND ug/L 07/03/17 16:45 75-71-82.0 4
1,1-Dichloroethane ND ug/L 07/03/17 16:45 75-34-32.0 4
1,2-Dichloroethane ND ug/L 07/03/17 16:45 107-06-22.0 4
1,1-Dichloroethene ND ug/L 07/03/17 16:45 75-35-42.0 4
cis-1,2-Dichloroethene ND ug/L 07/03/17 16:45 156-59-22.0 4
trans-1,2-Dichloroethene ND ug/L 07/03/17 16:45 156-60-52.0 4
1,2-Dichloropropane ND ug/L 07/03/17 16:45 78-87-52.0 4
1,3-Dichloropropane ND ug/L 07/03/17 16:45 142-28-92.0 4
2,2-Dichloropropane ND ug/L 07/03/17 16:45 594-20-72.0 4
1,1-Dichloropropene ND ug/L 07/03/17 16:45 563-58-62.0 4
cis-1,3-Dichloropropene ND ug/L 07/03/17 16:45 10061-01-52.0 4
trans-1,3-Dichloropropene ND ug/L 07/03/17 16:45 10061-02-62.0 4
Diisopropyl ether ND ug/L 07/03/17 16:45 108-20-32.0 4
Ethylbenzene ND ug/L 07/03/17 16:45 100-41-42.0 4
Hexachloro-1,3-butadiene ND ug/L 07/03/17 16:45 87-68-38.0 4
Isopropylbenzene (Cumene) ND ug/L 07/03/17 16:45 98-82-82.0 4
Methylene Chloride ND ug/L 07/03/17 16:45 75-09-28.0 4
Methyl-tert-butyl ether 517 ug/L 07/03/17 16:45 1634-04-42.0 4
Naphthalene 19.7 ug/L 07/03/17 16:45 91-20-38.0 4
n-Propylbenzene ND ug/L 07/03/17 16:45 103-65-12.0 4
Styrene ND ug/L 07/03/17 16:45 100-42-52.0 4
1,1,1,2-Tetrachloroethane ND ug/L 07/03/17 16:45 630-20-62.0 4
1,1,2,2-Tetrachloroethane ND ug/L 07/03/17 16:45 79-34-52.0 4
Tetrachloroethene ND ug/L 07/03/17 16:45 127-18-42.0 4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 5 Lab ID: 92346051004 Collected: 06/27/17 09:00 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene ND ug/L 07/03/17 16:45 108-88-32.0 4
1,2,3-Trichlorobenzene ND ug/L 07/03/17 16:45 87-61-68.0 4
1,2,4-Trichlorobenzene ND ug/L 07/03/17 16:45 120-82-18.0 4
1,1,1-Trichloroethane ND ug/L 07/03/17 16:45 71-55-62.0 4
1,1,2-Trichloroethane ND ug/L 07/03/17 16:45 79-00-52.0 4
Trichloroethene ND ug/L 07/03/17 16:45 79-01-62.0 4
Trichlorofluoromethane ND ug/L 07/03/17 16:45 75-69-44.0 4
1,2,3-Trichloropropane ND ug/L 07/03/17 16:45 96-18-42.0 4
1,2,4-Trimethylbenzene ND ug/L 07/03/17 16:45 95-63-62.0 4
1,3,5-Trimethylbenzene ND ug/L 07/03/17 16:45 108-67-82.0 4
Vinyl chloride ND ug/L 07/03/17 16:45 75-01-44.0 4
m&p-Xylene ND ug/L 07/03/17 16:45 179601-23-14.0 4
o-Xylene ND ug/L 07/03/17 16:45 95-47-62.0 4
Surrogates
1,2-Dichloroethane-d4 (S) 105 % 07/03/17 16:45 17060-07-070-130 4
4-Bromofluorobenzene (S) 100 % 07/03/17 16:45 460-00-470-130 4
Toluene-d8 (S) 102 % 07/03/17 16:45 2037-26-570-130 4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 6 Lab ID: 92346051005 Collected: 06/27/17 09:25 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 07/07/17 11:53 71-43-22.0 4
Bromobenzene ND ug/L 07/07/17 11:53 108-86-12.0 4
Bromochloromethane ND ug/L 07/07/17 11:53 74-97-52.0 4
Bromodichloromethane ND ug/L 07/07/17 11:53 75-27-42.0 4
Bromoform ND ug/L 07/07/17 11:53 75-25-22.0 4
Bromomethane ND ug/L 07/07/17 11:53 74-83-920.0 4
n-Butylbenzene ND ug/L 07/07/17 11:53 104-51-82.0 4
sec-Butylbenzene ND ug/L 07/07/17 11:53 135-98-82.0 4
tert-Butylbenzene ND ug/L 07/07/17 11:53 98-06-62.0 4
Carbon tetrachloride ND ug/L 07/07/17 11:53 56-23-52.0 4
Chlorobenzene ND ug/L 07/07/17 11:53 108-90-72.0 4
Chloroethane ND ug/L 07/07/17 11:53 75-00-34.0 4
Chloroform ND ug/L 07/07/17 11:53 67-66-32.0 4
Chloromethane ND ug/L 07/07/17 11:53 74-87-34.0 4
2-Chlorotoluene ND ug/L 07/07/17 11:53 95-49-82.0 4
4-Chlorotoluene ND ug/L 07/07/17 11:53 106-43-42.0 4
1,2-Dibromo-3-chloropropane ND ug/L 07/07/17 11:53 96-12-84.0 4
Dibromochloromethane ND ug/L 07/07/17 11:53 124-48-12.0 4
1,2-Dibromoethane (EDB) ND ug/L 07/07/17 11:53 106-93-42.0 4
Dibromomethane ND ug/L 07/07/17 11:53 74-95-32.0 4
1,2-Dichlorobenzene ND ug/L 07/07/17 11:53 95-50-12.0 4
1,3-Dichlorobenzene ND ug/L 07/07/17 11:53 541-73-12.0 4
1,4-Dichlorobenzene ND ug/L 07/07/17 11:53 106-46-72.0 4
Dichlorodifluoromethane ND ug/L 07/07/17 11:53 75-71-82.0 4
1,1-Dichloroethane ND ug/L 07/07/17 11:53 75-34-32.0 4
1,2-Dichloroethane ND ug/L 07/07/17 11:53 107-06-22.0 4
1,1-Dichloroethene ND ug/L 07/07/17 11:53 75-35-42.0 4
cis-1,2-Dichloroethene ND ug/L 07/07/17 11:53 156-59-22.0 4
trans-1,2-Dichloroethene ND ug/L 07/07/17 11:53 156-60-52.0 4
1,2-Dichloropropane ND ug/L 07/07/17 11:53 78-87-52.0 4
1,3-Dichloropropane ND ug/L 07/07/17 11:53 142-28-92.0 4
2,2-Dichloropropane ND ug/L 07/07/17 11:53 594-20-72.0 4
1,1-Dichloropropene ND ug/L 07/07/17 11:53 563-58-62.0 4
cis-1,3-Dichloropropene ND ug/L 07/07/17 11:53 10061-01-52.0 4
trans-1,3-Dichloropropene ND ug/L 07/07/17 11:53 10061-02-62.0 4
Diisopropyl ether 21.6 ug/L 07/07/17 11:53 108-20-32.0 4
Ethylbenzene ND ug/L 07/07/17 11:53 100-41-42.0 4
Hexachloro-1,3-butadiene ND ug/L 07/07/17 11:53 87-68-38.0 4
Isopropylbenzene (Cumene) ND ug/L 07/07/17 11:53 98-82-82.0 4
Methylene Chloride ND ug/L 07/07/17 11:53 75-09-28.0 4
Methyl-tert-butyl ether 405 ug/L 07/07/17 11:53 1634-04-42.0 4
Naphthalene ND ug/L 07/07/17 11:53 91-20-38.0 4
n-Propylbenzene ND ug/L 07/07/17 11:53 103-65-12.0 4
Styrene ND ug/L 07/07/17 11:53 100-42-52.0 4
1,1,1,2-Tetrachloroethane ND ug/L 07/07/17 11:53 630-20-62.0 4
1,1,2,2-Tetrachloroethane ND ug/L 07/07/17 11:53 79-34-52.0 4
Tetrachloroethene ND ug/L 07/07/17 11:53 127-18-42.0 4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 6 Lab ID: 92346051005 Collected: 06/27/17 09:25 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene ND ug/L 07/07/17 11:53 108-88-32.0 4
1,2,3-Trichlorobenzene ND ug/L 07/07/17 11:53 87-61-68.0 4
1,2,4-Trichlorobenzene ND ug/L 07/07/17 11:53 120-82-18.0 4
1,1,1-Trichloroethane ND ug/L 07/07/17 11:53 71-55-62.0 4
1,1,2-Trichloroethane ND ug/L 07/07/17 11:53 79-00-52.0 4
Trichloroethene ND ug/L 07/07/17 11:53 79-01-62.0 4
Trichlorofluoromethane ND ug/L 07/07/17 11:53 75-69-44.0 4
1,2,3-Trichloropropane ND ug/L 07/07/17 11:53 96-18-42.0 4
1,2,4-Trimethylbenzene ND ug/L 07/07/17 11:53 95-63-62.0 4
1,3,5-Trimethylbenzene ND ug/L 07/07/17 11:53 108-67-82.0 4
Vinyl chloride ND ug/L 07/07/17 11:53 75-01-44.0 4
m&p-Xylene ND ug/L 07/07/17 11:53 179601-23-14.0 4
o-Xylene ND ug/L 07/07/17 11:53 95-47-62.0 4
Surrogates
1,2-Dichloroethane-d4 (S) 106 % 07/07/17 11:53 17060-07-070-130 4
4-Bromofluorobenzene (S) 98 % 07/07/17 11:53 460-00-470-130 4
Toluene-d8 (S) 104 % 07/07/17 11:53 2037-26-570-130 4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 7 Lab ID: 92346051006 Collected: 06/27/17 09:50 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 06/30/17 06:13 71-43-20.50 1
Bromobenzene ND ug/L 06/30/17 06:13 108-86-10.50 1
Bromochloromethane ND ug/L 06/30/17 06:13 74-97-50.50 1
Bromodichloromethane ND ug/L 06/30/17 06:13 75-27-40.50 1
Bromoform ND ug/L 06/30/17 06:13 75-25-20.50 1
Bromomethane ND ug/L 06/30/17 06:13 74-83-95.0 1
n-Butylbenzene ND ug/L 06/30/17 06:13 104-51-80.50 1
sec-Butylbenzene ND ug/L 06/30/17 06:13 135-98-80.50 1
tert-Butylbenzene ND ug/L 06/30/17 06:13 98-06-60.50 1
Carbon tetrachloride ND ug/L 06/30/17 06:13 56-23-50.50 1
Chlorobenzene ND ug/L 06/30/17 06:13 108-90-70.50 1
Chloroethane ND ug/L 06/30/17 06:13 75-00-31.0 1
Chloroform ND ug/L 06/30/17 06:13 67-66-30.50 1
Chloromethane ND ug/L 06/30/17 06:13 74-87-31.0 1
2-Chlorotoluene ND ug/L 06/30/17 06:13 95-49-80.50 1
4-Chlorotoluene ND ug/L 06/30/17 06:13 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 06/30/17 06:13 96-12-81.0 1
Dibromochloromethane ND ug/L 06/30/17 06:13 124-48-10.50 1
1,2-Dibromoethane (EDB) ND ug/L 06/30/17 06:13 106-93-40.50 1
Dibromomethane ND ug/L 06/30/17 06:13 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 06/30/17 06:13 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 06/30/17 06:13 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 06/30/17 06:13 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 06/30/17 06:13 75-71-80.50 1
1,1-Dichloroethane ND ug/L 06/30/17 06:13 75-34-30.50 1
1,2-Dichloroethane ND ug/L 06/30/17 06:13 107-06-20.50 1
1,1-Dichloroethene ND ug/L 06/30/17 06:13 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 06/30/17 06:13 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 06/30/17 06:13 156-60-50.50 1
1,2-Dichloropropane ND ug/L 06/30/17 06:13 78-87-50.50 1
1,3-Dichloropropane ND ug/L 06/30/17 06:13 142-28-90.50 1
2,2-Dichloropropane ND ug/L 06/30/17 06:13 594-20-70.50 1
1,1-Dichloropropene ND ug/L 06/30/17 06:13 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 06/30/17 06:13 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 06/30/17 06:13 10061-02-60.50 1
Diisopropyl ether 56.1 ug/L 06/30/17 06:13 108-20-30.50 1
Ethylbenzene 0.68 ug/L 06/30/17 06:13 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 06/30/17 06:13 87-68-32.0 1
Isopropylbenzene (Cumene) ND ug/L 06/30/17 06:13 98-82-80.50 1
Methylene Chloride ND ug/L 06/30/17 06:13 75-09-22.0 1
Methyl-tert-butyl ether 73.0 ug/L 06/30/17 06:13 1634-04-40.50 1
Naphthalene ND ug/L 06/30/17 06:13 91-20-32.0 1
n-Propylbenzene ND ug/L 06/30/17 06:13 103-65-10.50 1
Styrene ND ug/L 06/30/17 06:13 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 06/30/17 06:13 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 06/30/17 06:13 79-34-50.50 1
Tetrachloroethene ND ug/L 06/30/17 06:13 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 7 Lab ID: 92346051006 Collected: 06/27/17 09:50 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene ND ug/L 06/30/17 06:13 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 06/30/17 06:13 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 06/30/17 06:13 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 06/30/17 06:13 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 06/30/17 06:13 79-00-50.50 1
Trichloroethene ND ug/L 06/30/17 06:13 79-01-60.50 1
Trichlorofluoromethane ND ug/L 06/30/17 06:13 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 06/30/17 06:13 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 06/30/17 06:13 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 06/30/17 06:13 108-67-80.50 1
Vinyl chloride ND ug/L 06/30/17 06:13 75-01-41.0 1
m&p-Xylene ND ug/L 06/30/17 06:13 179601-23-11.0 1
o-Xylene ND ug/L 06/30/17 06:13 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S) 100 % 06/30/17 06:13 17060-07-070-130 1
4-Bromofluorobenzene (S) 99 % 06/30/17 06:13 460-00-470-130 1
Toluene-d8 (S) 100 % 06/30/17 06:13 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 8 Lab ID: 92346051007 Collected: 06/27/17 10:20 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 06/30/17 06:30 71-43-20.50 1
Bromobenzene ND ug/L 06/30/17 06:30 108-86-10.50 1
Bromochloromethane ND ug/L 06/30/17 06:30 74-97-50.50 1
Bromodichloromethane ND ug/L 06/30/17 06:30 75-27-40.50 1
Bromoform ND ug/L 06/30/17 06:30 75-25-20.50 1
Bromomethane ND ug/L 06/30/17 06:30 74-83-95.0 1
n-Butylbenzene ND ug/L 06/30/17 06:30 104-51-80.50 1
sec-Butylbenzene ND ug/L 06/30/17 06:30 135-98-80.50 1
tert-Butylbenzene ND ug/L 06/30/17 06:30 98-06-60.50 1
Carbon tetrachloride ND ug/L 06/30/17 06:30 56-23-50.50 1
Chlorobenzene ND ug/L 06/30/17 06:30 108-90-70.50 1
Chloroethane ND ug/L 06/30/17 06:30 75-00-31.0 1
Chloroform ND ug/L 06/30/17 06:30 67-66-30.50 1
Chloromethane ND ug/L 06/30/17 06:30 74-87-31.0 1
2-Chlorotoluene ND ug/L 06/30/17 06:30 95-49-80.50 1
4-Chlorotoluene ND ug/L 06/30/17 06:30 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 06/30/17 06:30 96-12-81.0 1
Dibromochloromethane ND ug/L 06/30/17 06:30 124-48-10.50 1
1,2-Dibromoethane (EDB) ND ug/L 06/30/17 06:30 106-93-40.50 1
Dibromomethane ND ug/L 06/30/17 06:30 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 06/30/17 06:30 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 06/30/17 06:30 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 06/30/17 06:30 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 06/30/17 06:30 75-71-80.50 1
1,1-Dichloroethane ND ug/L 06/30/17 06:30 75-34-30.50 1
1,2-Dichloroethane ND ug/L 06/30/17 06:30 107-06-20.50 1
1,1-Dichloroethene ND ug/L 06/30/17 06:30 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 06/30/17 06:30 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 06/30/17 06:30 156-60-50.50 1
1,2-Dichloropropane ND ug/L 06/30/17 06:30 78-87-50.50 1
1,3-Dichloropropane ND ug/L 06/30/17 06:30 142-28-90.50 1
2,2-Dichloropropane ND ug/L 06/30/17 06:30 594-20-70.50 1
1,1-Dichloropropene ND ug/L 06/30/17 06:30 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 06/30/17 06:30 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 06/30/17 06:30 10061-02-60.50 1
Diisopropyl ether 1.7 ug/L 06/30/17 06:30 108-20-30.50 1
Ethylbenzene ND ug/L 06/30/17 06:30 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 06/30/17 06:30 87-68-32.0 1
Isopropylbenzene (Cumene) ND ug/L 06/30/17 06:30 98-82-80.50 1
Methylene Chloride ND ug/L 06/30/17 06:30 75-09-22.0 1
Methyl-tert-butyl ether 3.3 ug/L 06/30/17 06:30 1634-04-40.50 1
Naphthalene ND ug/L 06/30/17 06:30 91-20-32.0 1
n-Propylbenzene ND ug/L 06/30/17 06:30 103-65-10.50 1
Styrene ND ug/L 06/30/17 06:30 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 06/30/17 06:30 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 06/30/17 06:30 79-34-50.50 1
Tetrachloroethene ND ug/L 06/30/17 06:30 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 8 Lab ID: 92346051007 Collected: 06/27/17 10:20 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene ND ug/L 06/30/17 06:30 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 06/30/17 06:30 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 06/30/17 06:30 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 06/30/17 06:30 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 06/30/17 06:30 79-00-50.50 1
Trichloroethene ND ug/L 06/30/17 06:30 79-01-60.50 1
Trichlorofluoromethane ND ug/L 06/30/17 06:30 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 06/30/17 06:30 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 06/30/17 06:30 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 06/30/17 06:30 108-67-80.50 1
Vinyl chloride ND ug/L 06/30/17 06:30 75-01-41.0 1
m&p-Xylene ND ug/L 06/30/17 06:30 179601-23-11.0 1
o-Xylene ND ug/L 06/30/17 06:30 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S) 101 % 06/30/17 06:30 17060-07-070-130 1
4-Bromofluorobenzene (S) 99 % 06/30/17 06:30 460-00-470-130 1
Toluene-d8 (S) 102 % 06/30/17 06:30 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 9 Lab ID: 92346051008 Collected: 06/27/17 10:50 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene 13500 ug/L 07/06/17 17:54 71-43-2200 400
Bromobenzene ND ug/L 07/06/17 17:54 108-86-1200 400
Bromochloromethane ND ug/L 07/06/17 17:54 74-97-5200 400
Bromodichloromethane ND ug/L 07/06/17 17:54 75-27-4200 400
Bromoform ND ug/L 07/06/17 17:54 75-25-2200 400
Bromomethane ND ug/L 07/06/17 17:54 74-83-92000 400
n-Butylbenzene ND ug/L 07/06/17 17:54 104-51-8200 400
sec-Butylbenzene ND ug/L 07/06/17 17:54 135-98-8200 400
tert-Butylbenzene ND ug/L 07/06/17 17:54 98-06-6200 400
Carbon tetrachloride ND ug/L 07/06/17 17:54 56-23-5200 400
Chlorobenzene ND ug/L 07/06/17 17:54 108-90-7200 400
Chloroethane ND ug/L 07/06/17 17:54 75-00-3400 400
Chloroform ND ug/L 07/06/17 17:54 67-66-3200 400
Chloromethane ND ug/L 07/06/17 17:54 74-87-3400 400
2-Chlorotoluene ND ug/L 07/06/17 17:54 95-49-8200 400
4-Chlorotoluene ND ug/L 07/06/17 17:54 106-43-4200 400
1,2-Dibromo-3-chloropropane ND ug/L 07/06/17 17:54 96-12-8400 400
Dibromochloromethane ND ug/L 07/06/17 17:54 124-48-1200 400
1,2-Dibromoethane (EDB) ND ug/L 07/06/17 17:54 106-93-4200 400
Dibromomethane ND ug/L 07/06/17 17:54 74-95-3200 400
1,2-Dichlorobenzene ND ug/L 07/06/17 17:54 95-50-1200 400
1,3-Dichlorobenzene ND ug/L 07/06/17 17:54 541-73-1200 400
1,4-Dichlorobenzene ND ug/L 07/06/17 17:54 106-46-7200 400
Dichlorodifluoromethane ND ug/L 07/06/17 17:54 75-71-8200 400
1,1-Dichloroethane ND ug/L 07/06/17 17:54 75-34-3200 400
1,2-Dichloroethane ND ug/L 07/06/17 17:54 107-06-2200 400
1,1-Dichloroethene ND ug/L 07/06/17 17:54 75-35-4200 400
cis-1,2-Dichloroethene ND ug/L 07/06/17 17:54 156-59-2200 400
trans-1,2-Dichloroethene ND ug/L 07/06/17 17:54 156-60-5200 400
1,2-Dichloropropane ND ug/L 07/06/17 17:54 78-87-5200 400
1,3-Dichloropropane ND ug/L 07/06/17 17:54 142-28-9200 400
2,2-Dichloropropane ND ug/L 07/06/17 17:54 594-20-7200 400
1,1-Dichloropropene ND ug/L 07/06/17 17:54 563-58-6200 400
cis-1,3-Dichloropropene ND ug/L 07/06/17 17:54 10061-01-5200 400
trans-1,3-Dichloropropene ND ug/L 07/06/17 17:54 10061-02-6200 400
Diisopropyl ether 629 ug/L 07/06/17 17:54 108-20-3200 400
Ethylbenzene 4380 ug/L 07/06/17 17:54 100-41-4200 400
Hexachloro-1,3-butadiene ND ug/L 07/06/17 17:54 87-68-3800 400
Isopropylbenzene (Cumene) ND ug/L 07/06/17 17:54 98-82-8200 400
Methylene Chloride ND ug/L 07/06/17 17:54 75-09-2800 400
Methyl-tert-butyl ether 7810 ug/L 07/06/17 17:54 1634-04-4200 400
Naphthalene ND ug/L 07/06/17 17:54 91-20-3800 400
n-Propylbenzene ND ug/L 07/06/17 17:54 103-65-1200 400
Styrene ND ug/L 07/06/17 17:54 100-42-5200 400
1,1,1,2-Tetrachloroethane ND ug/L 07/06/17 17:54 630-20-6200 400
1,1,2,2-Tetrachloroethane ND ug/L 07/06/17 17:54 79-34-5200 400
Tetrachloroethene ND ug/L 07/06/17 17:54 127-18-4200 400
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 9 Lab ID: 92346051008 Collected: 06/27/17 10:50 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene 49600 ug/L 07/06/17 17:54 108-88-3200 400
1,2,3-Trichlorobenzene ND ug/L 07/06/17 17:54 87-61-6800 400
1,2,4-Trichlorobenzene ND ug/L 07/06/17 17:54 120-82-1800 400
1,1,1-Trichloroethane ND ug/L 07/06/17 17:54 71-55-6200 400
1,1,2-Trichloroethane ND ug/L 07/06/17 17:54 79-00-5200 400
Trichloroethene ND ug/L 07/06/17 17:54 79-01-6200 400
Trichlorofluoromethane ND ug/L 07/06/17 17:54 75-69-4400 400
1,2,3-Trichloropropane ND ug/L 07/06/17 17:54 96-18-4200 400
1,2,4-Trimethylbenzene 2400 ug/L 07/06/17 17:54 95-63-6200 400
1,3,5-Trimethylbenzene ND ug/L 07/06/17 17:54 108-67-8200 400
Vinyl chloride ND ug/L 07/06/17 17:54 75-01-4400 400
m&p-Xylene 14300 ug/L 07/06/17 17:54 179601-23-1400 400
o-Xylene 6890 ug/L 07/06/17 17:54 95-47-6200 400
Surrogates
1,2-Dichloroethane-d4 (S) 105 % 07/06/17 17:54 17060-07-070-130 400
4-Bromofluorobenzene (S) 99 % 07/06/17 17:54 460-00-470-130 400
Toluene-d8 (S) 103 % 07/06/17 17:54 2037-26-570-130 400
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 10 Lab ID: 92346051009 Collected: 06/27/17 11:20 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 06/30/17 06:47 71-43-20.50 1
Bromobenzene ND ug/L 06/30/17 06:47 108-86-10.50 1
Bromochloromethane ND ug/L 06/30/17 06:47 74-97-50.50 1
Bromodichloromethane ND ug/L 06/30/17 06:47 75-27-40.50 1
Bromoform ND ug/L 06/30/17 06:47 75-25-20.50 1
Bromomethane ND ug/L 06/30/17 06:47 74-83-95.0 1
n-Butylbenzene ND ug/L 06/30/17 06:47 104-51-80.50 1
sec-Butylbenzene ND ug/L 06/30/17 06:47 135-98-80.50 1
tert-Butylbenzene ND ug/L 06/30/17 06:47 98-06-60.50 1
Carbon tetrachloride ND ug/L 06/30/17 06:47 56-23-50.50 1
Chlorobenzene ND ug/L 06/30/17 06:47 108-90-70.50 1
Chloroethane ND ug/L 06/30/17 06:47 75-00-31.0 1
Chloroform ND ug/L 06/30/17 06:47 67-66-30.50 1
Chloromethane ND ug/L 06/30/17 06:47 74-87-31.0 1
2-Chlorotoluene ND ug/L 06/30/17 06:47 95-49-80.50 1
4-Chlorotoluene ND ug/L 06/30/17 06:47 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 06/30/17 06:47 96-12-81.0 1
Dibromochloromethane ND ug/L 06/30/17 06:47 124-48-10.50 1
1,2-Dibromoethane (EDB) ND ug/L 06/30/17 06:47 106-93-40.50 1
Dibromomethane ND ug/L 06/30/17 06:47 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 06/30/17 06:47 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 06/30/17 06:47 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 06/30/17 06:47 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 06/30/17 06:47 75-71-80.50 1
1,1-Dichloroethane ND ug/L 06/30/17 06:47 75-34-30.50 1
1,2-Dichloroethane ND ug/L 06/30/17 06:47 107-06-20.50 1
1,1-Dichloroethene ND ug/L 06/30/17 06:47 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 06/30/17 06:47 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 06/30/17 06:47 156-60-50.50 1
1,2-Dichloropropane ND ug/L 06/30/17 06:47 78-87-50.50 1
1,3-Dichloropropane ND ug/L 06/30/17 06:47 142-28-90.50 1
2,2-Dichloropropane ND ug/L 06/30/17 06:47 594-20-70.50 1
1,1-Dichloropropene ND ug/L 06/30/17 06:47 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 06/30/17 06:47 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 06/30/17 06:47 10061-02-60.50 1
Diisopropyl ether ND ug/L 06/30/17 06:47 108-20-30.50 1
Ethylbenzene ND ug/L 06/30/17 06:47 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 06/30/17 06:47 87-68-32.0 1
Isopropylbenzene (Cumene) ND ug/L 06/30/17 06:47 98-82-80.50 1
Methylene Chloride ND ug/L 06/30/17 06:47 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 06/30/17 06:47 1634-04-40.50 1
Naphthalene ND ug/L 06/30/17 06:47 91-20-32.0 1
n-Propylbenzene ND ug/L 06/30/17 06:47 103-65-10.50 1
Styrene ND ug/L 06/30/17 06:47 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 06/30/17 06:47 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 06/30/17 06:47 79-34-50.50 1
Tetrachloroethene ND ug/L 06/30/17 06:47 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 10 Lab ID: 92346051009 Collected: 06/27/17 11:20 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene ND ug/L 06/30/17 06:47 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 06/30/17 06:47 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 06/30/17 06:47 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 06/30/17 06:47 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 06/30/17 06:47 79-00-50.50 1
Trichloroethene ND ug/L 06/30/17 06:47 79-01-60.50 1
Trichlorofluoromethane ND ug/L 06/30/17 06:47 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 06/30/17 06:47 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 06/30/17 06:47 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 06/30/17 06:47 108-67-80.50 1
Vinyl chloride ND ug/L 06/30/17 06:47 75-01-41.0 1
m&p-Xylene ND ug/L 06/30/17 06:47 179601-23-11.0 1
o-Xylene ND ug/L 06/30/17 06:47 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S) 99 % 06/30/17 06:47 17060-07-070-130 1
4-Bromofluorobenzene (S) 99 % 06/30/17 06:47 460-00-470-130 1
Toluene-d8 (S) 102 % 06/30/17 06:47 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 11 Lab ID: 92346051010 Collected: 06/27/17 11:50 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 06/30/17 07:05 71-43-20.50 1
Bromobenzene ND ug/L 06/30/17 07:05 108-86-10.50 1
Bromochloromethane ND ug/L 06/30/17 07:05 74-97-50.50 1
Bromodichloromethane ND ug/L 06/30/17 07:05 75-27-40.50 1
Bromoform ND ug/L 06/30/17 07:05 75-25-20.50 1
Bromomethane ND ug/L 06/30/17 07:05 74-83-95.0 1
n-Butylbenzene ND ug/L 06/30/17 07:05 104-51-80.50 1
sec-Butylbenzene ND ug/L 06/30/17 07:05 135-98-80.50 1
tert-Butylbenzene ND ug/L 06/30/17 07:05 98-06-60.50 1
Carbon tetrachloride ND ug/L 06/30/17 07:05 56-23-50.50 1
Chlorobenzene ND ug/L 06/30/17 07:05 108-90-70.50 1
Chloroethane ND ug/L 06/30/17 07:05 75-00-31.0 1
Chloroform ND ug/L 06/30/17 07:05 67-66-30.50 1
Chloromethane ND ug/L 06/30/17 07:05 74-87-31.0 1
2-Chlorotoluene ND ug/L 06/30/17 07:05 95-49-80.50 1
4-Chlorotoluene ND ug/L 06/30/17 07:05 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 06/30/17 07:05 96-12-81.0 1
Dibromochloromethane ND ug/L 06/30/17 07:05 124-48-10.50 1
1,2-Dibromoethane (EDB) ND ug/L 06/30/17 07:05 106-93-40.50 1
Dibromomethane ND ug/L 06/30/17 07:05 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 06/30/17 07:05 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 06/30/17 07:05 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 06/30/17 07:05 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 06/30/17 07:05 75-71-80.50 1
1,1-Dichloroethane ND ug/L 06/30/17 07:05 75-34-30.50 1
1,2-Dichloroethane ND ug/L 06/30/17 07:05 107-06-20.50 1
1,1-Dichloroethene ND ug/L 06/30/17 07:05 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 06/30/17 07:05 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 06/30/17 07:05 156-60-50.50 1
1,2-Dichloropropane ND ug/L 06/30/17 07:05 78-87-50.50 1
1,3-Dichloropropane ND ug/L 06/30/17 07:05 142-28-90.50 1
2,2-Dichloropropane ND ug/L 06/30/17 07:05 594-20-70.50 1
1,1-Dichloropropene ND ug/L 06/30/17 07:05 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 06/30/17 07:05 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 06/30/17 07:05 10061-02-60.50 1
Diisopropyl ether ND ug/L 06/30/17 07:05 108-20-30.50 1
Ethylbenzene ND ug/L 06/30/17 07:05 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 06/30/17 07:05 87-68-32.0 1
Isopropylbenzene (Cumene) ND ug/L 06/30/17 07:05 98-82-80.50 1
Methylene Chloride ND ug/L 06/30/17 07:05 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 06/30/17 07:05 1634-04-40.50 1
Naphthalene ND ug/L 06/30/17 07:05 91-20-32.0 1
n-Propylbenzene ND ug/L 06/30/17 07:05 103-65-10.50 1
Styrene ND ug/L 06/30/17 07:05 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 06/30/17 07:05 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 06/30/17 07:05 79-34-50.50 1
Tetrachloroethene ND ug/L 06/30/17 07:05 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: MW 11 Lab ID: 92346051010 Collected: 06/27/17 11:50 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene ND ug/L 06/30/17 07:05 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 06/30/17 07:05 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 06/30/17 07:05 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 06/30/17 07:05 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 06/30/17 07:05 79-00-50.50 1
Trichloroethene ND ug/L 06/30/17 07:05 79-01-60.50 1
Trichlorofluoromethane ND ug/L 06/30/17 07:05 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 06/30/17 07:05 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 06/30/17 07:05 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 06/30/17 07:05 108-67-80.50 1
Vinyl chloride ND ug/L 06/30/17 07:05 75-01-41.0 1
m&p-Xylene ND ug/L 06/30/17 07:05 179601-23-11.0 1
o-Xylene ND ug/L 06/30/17 07:05 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S) 100 % 06/30/17 07:05 17060-07-070-130 1
4-Bromofluorobenzene (S) 99 % 06/30/17 07:05 460-00-470-130 1
Toluene-d8 (S) 103 % 06/30/17 07:05 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: SW 1 Lab ID: 92346051011 Collected: 06/27/17 12:15 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 06/30/17 02:13 71-43-20.50 1
Bromobenzene ND ug/L 06/30/17 02:13 108-86-10.50 1
Bromochloromethane ND ug/L 06/30/17 02:13 74-97-50.50 1
Bromodichloromethane ND ug/L 06/30/17 02:13 75-27-40.50 1
Bromoform ND ug/L 06/30/17 02:13 75-25-20.50 1
Bromomethane ND ug/L 06/30/17 02:13 74-83-95.0 1
n-Butylbenzene ND ug/L 06/30/17 02:13 104-51-80.50 1
sec-Butylbenzene ND ug/L 06/30/17 02:13 135-98-80.50 1
tert-Butylbenzene ND ug/L 06/30/17 02:13 98-06-60.50 1
Carbon tetrachloride ND ug/L 06/30/17 02:13 56-23-50.50 1
Chlorobenzene ND ug/L 06/30/17 02:13 108-90-70.50 1
Chloroethane ND ug/L 06/30/17 02:13 75-00-31.0 1
Chloroform ND ug/L 06/30/17 02:13 67-66-30.50 1
Chloromethane ND ug/L 06/30/17 02:13 74-87-31.0 1
2-Chlorotoluene ND ug/L 06/30/17 02:13 95-49-80.50 1
4-Chlorotoluene ND ug/L 06/30/17 02:13 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 06/30/17 02:13 96-12-81.0 1
Dibromochloromethane ND ug/L 06/30/17 02:13 124-48-10.50 1
1,2-Dibromoethane (EDB) ND ug/L 06/30/17 02:13 106-93-40.50 1
Dibromomethane ND ug/L 06/30/17 02:13 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 06/30/17 02:13 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 06/30/17 02:13 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 06/30/17 02:13 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 06/30/17 02:13 75-71-80.50 1
1,1-Dichloroethane ND ug/L 06/30/17 02:13 75-34-30.50 1
1,2-Dichloroethane ND ug/L 06/30/17 02:13 107-06-20.50 1
1,1-Dichloroethene ND ug/L 06/30/17 02:13 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 06/30/17 02:13 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 06/30/17 02:13 156-60-50.50 1
1,2-Dichloropropane ND ug/L 06/30/17 02:13 78-87-50.50 1
1,3-Dichloropropane ND ug/L 06/30/17 02:13 142-28-90.50 1
2,2-Dichloropropane ND ug/L 06/30/17 02:13 594-20-70.50 1
1,1-Dichloropropene ND ug/L 06/30/17 02:13 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 06/30/17 02:13 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 06/30/17 02:13 10061-02-60.50 1
Diisopropyl ether ND ug/L 06/30/17 02:13 108-20-30.50 1
Ethylbenzene ND ug/L 06/30/17 02:13 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 06/30/17 02:13 87-68-32.0 1
Isopropylbenzene (Cumene) ND ug/L 06/30/17 02:13 98-82-80.50 1
Methylene Chloride ND ug/L 06/30/17 02:13 75-09-22.0 1
Methyl-tert-butyl ether 23.7 ug/L 06/30/17 02:13 1634-04-40.50 1
Naphthalene ND ug/L 06/30/17 02:13 91-20-32.0 1
n-Propylbenzene ND ug/L 06/30/17 02:13 103-65-10.50 1
Styrene ND ug/L 06/30/17 02:13 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 06/30/17 02:13 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 06/30/17 02:13 79-34-50.50 1
Tetrachloroethene ND ug/L 06/30/17 02:13 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346051
FRIENDLY MART
Sample: SW 1 Lab ID: 92346051011 Collected: 06/27/17 12:15 Received: 06/29/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene ND ug/L 06/30/17 02:13 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 06/30/17 02:13 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 06/30/17 02:13 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 06/30/17 02:13 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 06/30/17 02:13 79-00-50.50 1
Trichloroethene ND ug/L 06/30/17 02:13 79-01-60.50 1
Trichlorofluoromethane ND ug/L 06/30/17 02:13 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 06/30/17 02:13 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 06/30/17 02:13 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 06/30/17 02:13 108-67-80.50 1
Vinyl chloride ND ug/L 06/30/17 02:13 75-01-41.0 1
m&p-Xylene ND ug/L 06/30/17 02:13 179601-23-11.0 1
o-Xylene ND ug/L 06/30/17 02:13 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S) 102 % 06/30/17 02:13 17060-07-070-130 1
4-Bromofluorobenzene (S) 98 % 06/30/17 02:13 460-00-470-130 1
Toluene-d8 (S) 102 % 06/30/17 02:13 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367180
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples: 92346051011
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2035490
Associated Lab Samples:92346051011
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 06/29/17 22:12
1,1,1-Trichloroethane ug/L ND 0.50 06/29/17 22:12
1,1,2,2-Tetrachloroethane ug/L ND 0.50 06/29/17 22:12
1,1,2-Trichloroethane ug/L ND 0.50 06/29/17 22:12
1,1-Dichloroethane ug/L ND 0.50 06/29/17 22:12
1,1-Dichloroethene ug/L ND 0.50 06/29/17 22:12
1,1-Dichloropropene ug/L ND 0.50 06/29/17 22:12
1,2,3-Trichlorobenzene ug/L ND 2.0 06/29/17 22:12
1,2,3-Trichloropropane ug/L ND 0.50 06/29/17 22:12
1,2,4-Trichlorobenzene ug/L ND 2.0 06/29/17 22:12
1,2,4-Trimethylbenzene ug/L ND 0.50 06/29/17 22:12
1,2-Dibromo-3-chloropropane ug/L ND 1.0 06/29/17 22:12
1,2-Dibromoethane (EDB) ug/L ND 0.50 06/29/17 22:12
1,2-Dichlorobenzene ug/L ND 0.50 06/29/17 22:12
1,2-Dichloroethane ug/L ND 0.50 06/29/17 22:12
1,2-Dichloropropane ug/L ND 0.50 06/29/17 22:12
1,3,5-Trimethylbenzene ug/L ND 0.50 06/29/17 22:12
1,3-Dichlorobenzene ug/L ND 0.50 06/29/17 22:12
1,3-Dichloropropane ug/L ND 0.50 06/29/17 22:12
1,4-Dichlorobenzene ug/L ND 0.50 06/29/17 22:12
2,2-Dichloropropane ug/L ND 0.50 06/29/17 22:12
2-Chlorotoluene ug/L ND 0.50 06/29/17 22:12
4-Chlorotoluene ug/L ND 0.50 06/29/17 22:12
Benzene ug/L ND 0.50 06/29/17 22:12
Bromobenzene ug/L ND 0.50 06/29/17 22:12
Bromochloromethane ug/L ND 0.50 06/29/17 22:12
Bromodichloromethane ug/L ND 0.50 06/29/17 22:12
Bromoform ug/L ND 0.50 06/29/17 22:12
Bromomethane ug/L ND 5.0 06/29/17 22:12
Carbon tetrachloride ug/L ND 0.50 06/29/17 22:12
Chlorobenzene ug/L ND 0.50 06/29/17 22:12
Chloroethane ug/L ND 1.0 06/29/17 22:12
Chloroform ug/L ND 0.50 06/29/17 22:12
Chloromethane ug/L ND 1.0 06/29/17 22:12
cis-1,2-Dichloroethene ug/L ND 0.50 06/29/17 22:12
cis-1,3-Dichloropropene ug/L ND 0.50 06/29/17 22:12
Dibromochloromethane ug/L ND 0.50 06/29/17 22:12
Dibromomethane ug/L ND 0.50 06/29/17 22:12
Dichlorodifluoromethane ug/L ND 0.50 06/29/17 22:12
Diisopropyl ether ug/L ND 0.50 06/29/17 22:12
Ethylbenzene ug/L ND 0.50 06/29/17 22:12
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2035490
Associated Lab Samples:92346051011
Matrix: Water
Analyzed
Hexachloro-1,3-butadiene ug/L ND 2.0 06/29/17 22:12
Isopropylbenzene (Cumene) ug/L ND 0.50 06/29/17 22:12
m&p-Xylene ug/L ND 1.0 06/29/17 22:12
Methyl-tert-butyl ether ug/L ND 0.50 06/29/17 22:12
Methylene Chloride ug/L ND 2.0 06/29/17 22:12
n-Butylbenzene ug/L ND 0.50 06/29/17 22:12
n-Propylbenzene ug/L ND 0.50 06/29/17 22:12
Naphthalene ug/L ND 2.0 06/29/17 22:12
o-Xylene ug/L ND 0.50 06/29/17 22:12
sec-Butylbenzene ug/L ND 0.50 06/29/17 22:12
Styrene ug/L ND 0.50 06/29/17 22:12
tert-Butylbenzene ug/L ND 0.50 06/29/17 22:12
Tetrachloroethene ug/L ND 0.50 06/29/17 22:12
Toluene ug/L ND 0.50 06/29/17 22:12
trans-1,2-Dichloroethene ug/L ND 0.50 06/29/17 22:12
trans-1,3-Dichloropropene ug/L ND 0.50 06/29/17 22:12
Trichloroethene ug/L ND 0.50 06/29/17 22:12
Trichlorofluoromethane ug/L ND 1.0 06/29/17 22:12
Vinyl chloride ug/L ND 1.0 06/29/17 22:12
1,2-Dichloroethane-d4 (S) % 98 70-130 06/29/17 22:12
4-Bromofluorobenzene (S) % 95 70-130 06/29/17 22:12
Toluene-d8 (S) % 101 70-130 06/29/17 22:12
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2035491LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.050 100 60-140
1,1,1-Trichloroethane ug/L 51.150 102 60-140
1,1,2,2-Tetrachloroethane ug/L 49.650 99 60-140
1,1,2-Trichloroethane ug/L 48.150 96 60-140
1,1-Dichloroethane ug/L 50.350 101 60-140
1,1-Dichloroethene ug/L 50.250 100 60-140
1,1-Dichloropropene ug/L 51.150 102 60-140
1,2,3-Trichlorobenzene ug/L 50.450 101 60-140
1,2,3-Trichloropropane ug/L 48.250 96 60-140
1,2,4-Trichlorobenzene ug/L 49.450 99 60-140
1,2,4-Trimethylbenzene ug/L 50.750 101 60-140
1,2-Dibromo-3-chloropropane ug/L 51.250 102 60-140
1,2-Dibromoethane (EDB) ug/L 50.650 101 60-140
1,2-Dichlorobenzene ug/L 49.050 98 60-140
1,2-Dichloroethane ug/L 45.350 91 60-140
1,2-Dichloropropane ug/L 50.150 100 60-140
1,3,5-Trimethylbenzene ug/L 49.050 98 60-140
1,3-Dichlorobenzene ug/L 48.250 96 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2035491LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 51.750 103 60-140
1,4-Dichlorobenzene ug/L 48.450 97 60-140
2,2-Dichloropropane ug/L 49.450 99 60-140
2-Chlorotoluene ug/L 50.750 101 60-140
4-Chlorotoluene ug/L 49.350 99 60-140
Benzene ug/L 50.750 101 60-140
Bromobenzene ug/L 48.650 97 60-140
Bromochloromethane ug/L 49.950 100 60-140
Bromodichloromethane ug/L 49.750 99 60-140
Bromoform ug/L 46.150 92 60-140
Bromomethane ug/L 46.850 94 60-140
Carbon tetrachloride ug/L 49.450 99 60-140
Chlorobenzene ug/L 48.150 96 60-140
Chloroethane ug/L 44.850 90 60-140
Chloroform ug/L 49.550 99 60-140
Chloromethane ug/L 43.750 87 60-140
cis-1,2-Dichloroethene ug/L 49.450 99 60-140
cis-1,3-Dichloropropene ug/L 53.150 106 60-140
Dibromochloromethane ug/L 51.750 103 60-140
Dibromomethane ug/L 48.450 97 60-140
Dichlorodifluoromethane ug/L 48.050 96 60-140
Diisopropyl ether ug/L 51.850 104 60-140
Ethylbenzene ug/L 50.450 101 60-140
Hexachloro-1,3-butadiene ug/L 51.150 102 60-140
Isopropylbenzene (Cumene) ug/L 49.950 100 60-140
m&p-Xylene ug/L 100100 100 60-140
Methyl-tert-butyl ether ug/L 52.550 105 60-140
Methylene Chloride ug/L 50.950 102 60-140
n-Butylbenzene ug/L 49.750 99 60-140
n-Propylbenzene ug/L 49.450 99 60-140
Naphthalene ug/L 51.350 103 60-140
o-Xylene ug/L 49.150 98 60-140
sec-Butylbenzene ug/L 49.750 99 60-140
Styrene ug/L 50.550 101 60-140
tert-Butylbenzene ug/L 42.150 84 60-140
Tetrachloroethene ug/L 45.950 92 60-140
Toluene ug/L 50.050 100 60-140
trans-1,2-Dichloroethene ug/L 50.050 100 60-140
trans-1,3-Dichloropropene ug/L 52.050 104 60-140
Trichloroethene ug/L 49.650 99 60-140
Trichlorofluoromethane ug/L 48.650 97 60-140
Vinyl chloride ug/L 47.650 95 60-140
1,2-Dichloroethane-d4 (S) % 101 70-130
4-Bromofluorobenzene (S) % 101 70-130
Toluene-d8 (S) % 100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037625MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346043003
2037626
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 103 60-140103 0 3020ND 20.6 20.5
1,1,1-Trichloroethane ug/L 20 117 60-140113 4 3020ND 23.3 22.5
1,1,2,2-Tetrachloroethane ug/L 20 105 60-140102 3 3020ND 21.0 20.5
1,1,2-Trichloroethane ug/L 20 103 60-140100 2 3020ND 20.5 20.0
1,1-Dichloroethane ug/L 20 114 60-140109 4 3020ND 22.8 21.8
1,1-Dichloroethene ug/L 20 119 60-140112 6 3020ND 23.8 22.5
1,1-Dichloropropene ug/L 20 120 60-140116 3 3020ND 23.9 23.1
1,2,3-Trichlorobenzene ug/L 20 115 60-140115 0 3020ND 23.0 23.0
1,2,3-Trichloropropane ug/L 20 103 60-14099 4 3020ND 20.5 19.7
1,2,4-Trichlorobenzene ug/L 20 109 60-140111 2 3020ND 21.8 22.2
1,2,4-Trimethylbenzene ug/L 20 112 60-140114 2 3020ND 22.4 22.7
1,2-Dibromo-3-
chloropropane
ug/L 20 104 60-140104 1 3020ND 20.9 20.8
1,2-Dibromoethane (EDB) ug/L 20 103 60-140103 0 3020ND 20.6 20.6
1,2-Dichlorobenzene ug/L 20 106 60-140106 0 3020ND 21.2 21.2
1,2-Dichloroethane ug/L 20 101 60-14098 3 3020ND 20.1 19.5
1,2-Dichloropropane ug/L 20 108 60-140104 4 3020ND 21.7 20.8
1,3,5-Trimethylbenzene ug/L 20 109 60-140110 1 3020ND 21.8 22.0
1,3-Dichlorobenzene ug/L 20 104 60-140108 4 3020ND 20.8 21.5
1,3-Dichloropropane ug/L 20 111 60-140110 1 3020ND 22.2 22.0
1,4-Dichlorobenzene ug/L 20 105 60-140106 1 3020ND 21.0 21.2
2,2-Dichloropropane ug/L 20 115 60-140116 1 3020ND 22.9 23.1
2-Chlorotoluene ug/L 20 113 60-140113 0 3020ND 22.5 22.5
4-Chlorotoluene ug/L 20 110 60-140111 1 3020ND 21.9 22.2
Benzene ug/L 20 109 60-140106 2 3020ND 21.8 21.3
Bromobenzene ug/L 20 106 60-140107 0 3020ND 21.3 21.4
Bromochloromethane ug/L 20 111 60-140107 3 3020ND 22.1 21.5
Bromodichloromethane ug/L 20 107 60-140105 2 3020ND 21.5 21.0
Bromoform ug/L 20 96 60-14095 2 3020ND 19.3 18.9
Bromomethane ug/L 20 89 60-14091 2 3020ND 17.9 18.2
Carbon tetrachloride ug/L 20 110 60-140108 2 3020ND 22.0 21.5
Chlorobenzene ug/L 20 107 60-140104 2 3020ND 21.3 20.8
Chloroethane ug/L 20 105 60-140107 1 3020ND 21.1 21.4
Chloroform ug/L 20 112 60-140108 3 3020ND 22.4 21.7
Chloromethane ug/L 20 112 60-14097 14 3020ND 22.4 19.4
cis-1,2-Dichloroethene ug/L 20 112 60-140112 0 3020ND 22.3 22.3
cis-1,3-Dichloropropene ug/L 20 108 60-140106 1 3020ND 21.5 21.2
Dibromochloromethane ug/L 20 107 60-140107 0 3020ND 21.4 21.4
Dibromomethane ug/L 20 101 60-14098 3 3020ND 20.3 19.6
Dichlorodifluoromethane ug/L 20 107 60-140105 2 3020ND 21.5 21.0
Diisopropyl ether ug/L 20 114 60-140113 1 3020ND 22.8 22.5
Ethylbenzene ug/L 20 112 60-140110 2 3020ND 22.3 21.9
Hexachloro-1,3-butadiene ug/L 20 113 60-140118 4 3020ND 22.6 23.6
Isopropylbenzene (Cumene) ug/L 20 110 60-140107 3 3020ND 21.9 21.3
m&p-Xylene ug/L 40 110 60-140107 2 3040ND 43.8 42.8
Methyl-tert-butyl ether ug/L 20 114 60-140112 2 3020ND 22.8 22.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037625MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346043003
2037626
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methylene Chloride ug/L 20 96 60-140102 7 3020ND 19.2 20.5
n-Butylbenzene ug/L 20 115 60-140116 1 3020ND 23.1 23.2
n-Propylbenzene ug/L 20 111 60-140112 0 3020ND 22.3 22.4
Naphthalene ug/L 20 117 60-140114 3 3020ND 23.5 22.9
o-Xylene ug/L 20 104 60-140103 1 3020ND 20.9 20.6
sec-Butylbenzene ug/L 20 110 60-140112 2 3020ND 22.1 22.5
Styrene ug/L 20 108 60-140104 4 3020ND 21.6 20.7
tert-Butylbenzene ug/L 20 93 60-14093 0 3020ND 18.5 18.6
Tetrachloroethene ug/L 20 101 60-140101 0 3020ND 20.2 20.2
Toluene ug/L 20 106 60-140106 0 3020ND 21.2 21.2
trans-1,2-Dichloroethene ug/L 20 113 60-140112 1 3020ND 22.7 22.5
trans-1,3-Dichloropropene ug/L 20 107 60-140104 3 3020ND 21.4 20.7
Trichloroethene ug/L 20 105 60-140105 0 3020ND 21.0 21.1
Trichlorofluoromethane ug/L 20 115 60-140111 4 3020ND 23.1 22.2
Vinyl chloride ug/L 20 109 60-140105 4 3020ND 21.8 21.0
1,2-Dichloroethane-d4 (S) % 109 70-130106
4-Bromofluorobenzene (S) % 103 70-130102
Toluene-d8 (S) % 101 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367181
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples: 92346051006, 92346051007, 92346051009, 92346051010
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2035494
Associated Lab Samples:92346051006, 92346051007, 92346051009, 92346051010
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 06/30/17 05:56
1,1,1-Trichloroethane ug/L ND 0.50 06/30/17 05:56
1,1,2,2-Tetrachloroethane ug/L ND 0.50 06/30/17 05:56
1,1,2-Trichloroethane ug/L ND 0.50 06/30/17 05:56
1,1-Dichloroethane ug/L ND 0.50 06/30/17 05:56
1,1-Dichloroethene ug/L ND 0.50 06/30/17 05:56
1,1-Dichloropropene ug/L ND 0.50 06/30/17 05:56
1,2,3-Trichlorobenzene ug/L ND 2.0 06/30/17 05:56
1,2,3-Trichloropropane ug/L ND 0.50 06/30/17 05:56
1,2,4-Trichlorobenzene ug/L ND 2.0 06/30/17 05:56
1,2,4-Trimethylbenzene ug/L ND 0.50 06/30/17 05:56
1,2-Dibromo-3-chloropropane ug/L ND 1.0 06/30/17 05:56
1,2-Dibromoethane (EDB) ug/L ND 0.50 06/30/17 05:56
1,2-Dichlorobenzene ug/L ND 0.50 06/30/17 05:56
1,2-Dichloroethane ug/L ND 0.50 06/30/17 05:56
1,2-Dichloropropane ug/L ND 0.50 06/30/17 05:56
1,3,5-Trimethylbenzene ug/L ND 0.50 06/30/17 05:56
1,3-Dichlorobenzene ug/L ND 0.50 06/30/17 05:56
1,3-Dichloropropane ug/L ND 0.50 06/30/17 05:56
1,4-Dichlorobenzene ug/L ND 0.50 06/30/17 05:56
2,2-Dichloropropane ug/L ND 0.50 06/30/17 05:56
2-Chlorotoluene ug/L ND 0.50 06/30/17 05:56
4-Chlorotoluene ug/L ND 0.50 06/30/17 05:56
Benzene ug/L ND 0.50 06/30/17 05:56
Bromobenzene ug/L ND 0.50 06/30/17 05:56
Bromochloromethane ug/L ND 0.50 06/30/17 05:56
Bromodichloromethane ug/L ND 0.50 06/30/17 05:56
Bromoform ug/L ND 0.50 06/30/17 05:56
Bromomethane ug/L ND 5.0 06/30/17 05:56
Carbon tetrachloride ug/L ND 0.50 06/30/17 05:56
Chlorobenzene ug/L ND 0.50 06/30/17 05:56
Chloroethane ug/L ND 1.0 06/30/17 05:56
Chloroform ug/L ND 0.50 06/30/17 05:56
Chloromethane ug/L ND 1.0 06/30/17 05:56
cis-1,2-Dichloroethene ug/L ND 0.50 06/30/17 05:56
cis-1,3-Dichloropropene ug/L ND 0.50 06/30/17 05:56
Dibromochloromethane ug/L ND 0.50 06/30/17 05:56
Dibromomethane ug/L ND 0.50 06/30/17 05:56
Dichlorodifluoromethane ug/L ND 0.50 06/30/17 05:56
Diisopropyl ether ug/L ND 0.50 06/30/17 05:56
Ethylbenzene ug/L ND 0.50 06/30/17 05:56
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2035494
Associated Lab Samples:92346051006, 92346051007, 92346051009, 92346051010
Matrix: Water
Analyzed
Hexachloro-1,3-butadiene ug/L ND 2.0 06/30/17 05:56
Isopropylbenzene (Cumene) ug/L ND 0.50 06/30/17 05:56
m&p-Xylene ug/L ND 1.0 06/30/17 05:56
Methyl-tert-butyl ether ug/L ND 0.50 06/30/17 05:56
Methylene Chloride ug/L ND 2.0 06/30/17 05:56
n-Butylbenzene ug/L ND 0.50 06/30/17 05:56
n-Propylbenzene ug/L ND 0.50 06/30/17 05:56
Naphthalene ug/L ND 2.0 06/30/17 05:56
o-Xylene ug/L ND 0.50 06/30/17 05:56
sec-Butylbenzene ug/L ND 0.50 06/30/17 05:56
Styrene ug/L ND 0.50 06/30/17 05:56
tert-Butylbenzene ug/L ND 0.50 06/30/17 05:56
Tetrachloroethene ug/L ND 0.50 06/30/17 05:56
Toluene ug/L ND 0.50 06/30/17 05:56
trans-1,2-Dichloroethene ug/L ND 0.50 06/30/17 05:56
trans-1,3-Dichloropropene ug/L ND 0.50 06/30/17 05:56
Trichloroethene ug/L ND 0.50 06/30/17 05:56
Trichlorofluoromethane ug/L ND 1.0 06/30/17 05:56
Vinyl chloride ug/L ND 1.0 06/30/17 05:56
1,2-Dichloroethane-d4 (S) % 99 70-130 06/30/17 05:56
4-Bromofluorobenzene (S) % 100 70-130 06/30/17 05:56
Toluene-d8 (S) % 102 70-130 06/30/17 05:56
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2035495LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.950 102 60-140
1,1,1-Trichloroethane ug/L 52.150 104 60-140
1,1,2,2-Tetrachloroethane ug/L 50.850 102 60-140
1,1,2-Trichloroethane ug/L 50.650 101 60-140
1,1-Dichloroethane ug/L 51.050 102 60-140
1,1-Dichloroethene ug/L 50.850 102 60-140
1,1-Dichloropropene ug/L 52.650 105 60-140
1,2,3-Trichlorobenzene ug/L 52.450 105 60-140
1,2,3-Trichloropropane ug/L 50.650 101 60-140
1,2,4-Trichlorobenzene ug/L 50.350 101 60-140
1,2,4-Trimethylbenzene ug/L 51.650 103 60-140
1,2-Dibromo-3-chloropropane ug/L 52.650 105 60-140
1,2-Dibromoethane (EDB) ug/L 51.550 103 60-140
1,2-Dichlorobenzene ug/L 49.850 100 60-140
1,2-Dichloroethane ug/L 46.850 94 60-140
1,2-Dichloropropane ug/L 51.750 103 60-140
1,3,5-Trimethylbenzene ug/L 49.950 100 60-140
1,3-Dichlorobenzene ug/L 49.350 99 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2035495LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 53.250 106 60-140
1,4-Dichlorobenzene ug/L 49.550 99 60-140
2,2-Dichloropropane ug/L 49.950 100 60-140
2-Chlorotoluene ug/L 51.650 103 60-140
4-Chlorotoluene ug/L 49.850 100 60-140
Benzene ug/L 51.750 103 60-140
Bromobenzene ug/L 49.750 99 60-140
Bromochloromethane ug/L 50.150 100 60-140
Bromodichloromethane ug/L 52.150 104 60-140
Bromoform ug/L 47.850 96 60-140
Bromomethane ug/L 38.350 77 60-140
Carbon tetrachloride ug/L 50.150 100 60-140
Chlorobenzene ug/L 49.350 99 60-140
Chloroethane ug/L 49.350 99 60-140
Chloroform ug/L 51.250 102 60-140
Chloromethane ug/L 43.550 87 60-140
cis-1,2-Dichloroethene ug/L 50.650 101 60-140
cis-1,3-Dichloropropene ug/L 53.150 106 60-140
Dibromochloromethane ug/L 54.150 108 60-140
Dibromomethane ug/L 50.750 101 60-140
Dichlorodifluoromethane ug/L 46.950 94 60-140
Diisopropyl ether ug/L 53.450 107 60-140
Ethylbenzene ug/L 51.650 103 60-140
Hexachloro-1,3-butadiene ug/L 53.150 106 60-140
Isopropylbenzene (Cumene) ug/L 50.650 101 60-140
m&p-Xylene ug/L 102100 102 60-140
Methyl-tert-butyl ether ug/L 54.050 108 60-140
Methylene Chloride ug/L 49.050 98 60-140
n-Butylbenzene ug/L 51.150 102 60-140
n-Propylbenzene ug/L 50.350 101 60-140
Naphthalene ug/L 52.650 105 60-140
o-Xylene ug/L 49.850 100 60-140
sec-Butylbenzene ug/L 50.750 101 60-140
Styrene ug/L 51.550 103 60-140
tert-Butylbenzene ug/L 42.850 86 60-140
Tetrachloroethene ug/L 46.450 93 60-140
Toluene ug/L 49.850 100 60-140
trans-1,2-Dichloroethene ug/L 50.650 101 60-140
trans-1,3-Dichloropropene ug/L 52.650 105 60-140
Trichloroethene ug/L 50.550 101 60-140
Trichlorofluoromethane ug/L 48.050 96 60-140
Vinyl chloride ug/L 47.750 95 60-140
1,2-Dichloroethane-d4 (S) % 102 70-130
4-Bromofluorobenzene (S) % 102 70-130
Toluene-d8 (S) % 99 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2035496MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346048001
2035497
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 2500 110 60-140108 2 302500ND 2750 2690
1,1,1-Trichloroethane ug/L 2500 119 60-140115 3 302500ND 2970 2890
1,1,2,2-Tetrachloroethane ug/L 2500 107 60-140109 2 302500ND 2670 2720
1,1,2-Trichloroethane ug/L 2500 109 60-140105 3 302500ND 2710 2630
1,1-Dichloroethane ug/L 2500 120 60-140116 3 302500ND 2990 2900
1,1-Dichloroethene ug/L 2500 121 60-140117 4 302500ND 3040 2930
1,1-Dichloropropene ug/L 2500 125 60-140117 6 302500ND 3110 2930
1,2,3-Trichlorobenzene ug/L 2500 114 60-140112 2 302500ND 2850 2800
1,2,3-Trichloropropane ug/L 2500 110 60-140106 4 302500ND 2740 2640
1,2,4-Trichlorobenzene ug/L 2500 111 60-140107 3 302500ND 2770 2680
1,2,4-Trimethylbenzene ug/L 2500 114 60-140110 2 3025001800 4650 4540
1,2-Dibromo-3-
chloropropane
ug/L 2500 105 60-140106 1 302500ND 2630 2660
1,2-Dibromoethane (EDB) ug/L 2500 111 60-140112 1 302500519 3290 3310
1,2-Dichlorobenzene ug/L 2500 109 60-140107 3 302500ND 2740 2660
1,2-Dichloroethane ug/L 2500 104 60-140102 1 3025001260 3860 3810
1,2-Dichloropropane ug/L 2500 118 60-140116 1 302500ND 2940 2910
1,3,5-Trimethylbenzene ug/L 2500 115 60-140111 3 302500514 3380 3280
1,3-Dichlorobenzene ug/L 2500 109 60-140107 2 302500ND 2720 2670
1,3-Dichloropropane ug/L 2500 117 60-140112 4 302500ND 2920 2800
1,4-Dichlorobenzene ug/L 2500 111 60-140107 4 302500ND 2770 2660
2,2-Dichloropropane ug/L 2500 101 60-14097 3 302500ND 2520 2430
2-Chlorotoluene ug/L 2500 112 60-140115 3 302500ND 2800 2890
4-Chlorotoluene ug/L 2500 113 60-140109 4 302500ND 2830 2730
Benzene ug/L M12500 143 60-140124 3 30250013900 17500 17000
Bromobenzene ug/L 2500 111 60-140109 2 302500ND 2780 2720
Bromochloromethane ug/L 2500 115 60-140111 3 302500ND 2880 2780
Bromodichloromethane ug/L 2500 114 60-140112 2 302500ND 2860 2810
Bromoform ug/L 2500 94 60-14093 1 302500ND 2340 2320
Bromomethane ug/L 2500 94 60-14089 6 302500ND 2350 2210
Carbon tetrachloride ug/L 2500 115 60-140111 4 302500ND 2880 2770
Chlorobenzene ug/L 2500 110 60-140108 2 302500ND 2750 2700
Chloroethane ug/L 2500 108 60-140106 2 302500ND 2690 2640
Chloroform ug/L 2500 116 60-140116 0 302500ND 2900 2900
Chloromethane ug/L 2500 119 60-140130 9 302500ND 2960 3250
cis-1,2-Dichloroethene ug/L 2500 118 60-140113 4 302500ND 2950 2830
cis-1,3-Dichloropropene ug/L 2500 111 60-140111 0 302500ND 2780 2770
Dibromochloromethane ug/L 2500 112 60-140109 3 302500ND 2800 2720
Dibromomethane ug/L 2500 108 60-140109 1 302500ND 2700 2720
Dichlorodifluoromethane ug/L 2500 105 60-140100 5 302500ND 2620 2500
Diisopropyl ether ug/L 2500 125 60-140120 3 3025001970 5100 4960
Ethylbenzene ug/L 2500 116 60-140110 4 3025001620 4530 4370
Hexachloro-1,3-butadiene ug/L 2500 115 60-140115 0 302500ND 2890 2890
Isopropylbenzene (Cumene) ug/L 2500 114 60-140109 4 30250069.4 2910 2800
m&p-Xylene ug/L 5000 114 60-140107 3 3050007080 12800 12400
Methyl-tert-butyl ether ug/L 2500 119 60-140117 1 302500ND 2960 2920
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2035496MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346048001
2035497
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methylene Chloride ug/L 2500 108 60-140108 0 302500ND 2690 2700
n-Butylbenzene ug/L 2500 114 60-140111 3 302500ND 2850 2780
n-Propylbenzene ug/L 2500 121 60-140116 4 302500ND 3030 2910
Naphthalene ug/L 2500 111 60-140110 1 302500961 3740 3700
o-Xylene ug/L 2500 113 60-140108 2 3025003280 6100 5980
sec-Butylbenzene ug/L 2500 116 60-140111 4 302500ND 2900 2790
Styrene ug/L 2500 113 60-140111 2 302500ND 2830 2770
tert-Butylbenzene ug/L 2500 97 60-14095 2 302500ND 2430 2380
Tetrachloroethene ug/L 2500 104 60-14097 7 302500ND 2600 2430
Toluene ug/L 2500 118 60-140113 1 30250016700 19600 19500
trans-1,2-Dichloroethene ug/L 2500 120 60-140114 5 302500ND 2990 2860
trans-1,3-Dichloropropene ug/L 2500 109 60-140112 2 302500ND 2740 2790
Trichloroethene ug/L 2500 116 60-140108 7 302500ND 2910 2700
Trichlorofluoromethane ug/L 2500 116 60-140111 5 302500ND 2900 2760
Vinyl chloride ug/L 2500 113 60-140109 4 302500ND 2820 2710
1,2-Dichloroethane-d4 (S) % 102 70-130104
4-Bromofluorobenzene (S) % 100 70-130102
Toluene-d8 (S) % 97 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367597
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples: 92346051001, 92346051002, 92346051003, 92346051004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037609
Associated Lab Samples:92346051001, 92346051002, 92346051003, 92346051004
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 07/03/17 15:20
1,1,1-Trichloroethane ug/L ND 0.50 07/03/17 15:20
1,1,2,2-Tetrachloroethane ug/L ND 0.50 07/03/17 15:20
1,1,2-Trichloroethane ug/L ND 0.50 07/03/17 15:20
1,1-Dichloroethane ug/L ND 0.50 07/03/17 15:20
1,1-Dichloroethene ug/L ND 0.50 07/03/17 15:20
1,1-Dichloropropene ug/L ND 0.50 07/03/17 15:20
1,2,3-Trichlorobenzene ug/L ND 2.0 07/03/17 15:20
1,2,3-Trichloropropane ug/L ND 0.50 07/03/17 15:20
1,2,4-Trichlorobenzene ug/L ND 2.0 07/03/17 15:20
1,2,4-Trimethylbenzene ug/L ND 0.50 07/03/17 15:20
1,2-Dibromo-3-chloropropane ug/L ND 1.0 07/03/17 15:20
1,2-Dibromoethane (EDB) ug/L ND 0.50 07/03/17 15:20
1,2-Dichlorobenzene ug/L ND 0.50 07/03/17 15:20
1,2-Dichloroethane ug/L ND 0.50 07/03/17 15:20
1,2-Dichloropropane ug/L ND 0.50 07/03/17 15:20
1,3,5-Trimethylbenzene ug/L ND 0.50 07/03/17 15:20
1,3-Dichlorobenzene ug/L ND 0.50 07/03/17 15:20
1,3-Dichloropropane ug/L ND 0.50 07/03/17 15:20
1,4-Dichlorobenzene ug/L ND 0.50 07/03/17 15:20
2,2-Dichloropropane ug/L ND 0.50 07/03/17 15:20
2-Chlorotoluene ug/L ND 0.50 07/03/17 15:20
4-Chlorotoluene ug/L ND 0.50 07/03/17 15:20
Benzene ug/L ND 0.50 07/03/17 15:20
Bromobenzene ug/L ND 0.50 07/03/17 15:20
Bromochloromethane ug/L ND 0.50 07/03/17 15:20
Bromodichloromethane ug/L ND 0.50 07/03/17 15:20
Bromoform ug/L ND 0.50 07/03/17 15:20
Bromomethane ug/L ND 5.0 07/03/17 15:20
Carbon tetrachloride ug/L ND 0.50 07/03/17 15:20
Chlorobenzene ug/L ND 0.50 07/03/17 15:20
Chloroethane ug/L ND 1.0 07/03/17 15:20
Chloroform ug/L ND 0.50 07/03/17 15:20
Chloromethane ug/L ND 1.0 07/03/17 15:20
cis-1,2-Dichloroethene ug/L ND 0.50 07/03/17 15:20
cis-1,3-Dichloropropene ug/L ND 0.50 07/03/17 15:20
Dibromochloromethane ug/L ND 0.50 07/03/17 15:20
Dibromomethane ug/L ND 0.50 07/03/17 15:20
Dichlorodifluoromethane ug/L ND 0.50 07/03/17 15:20
Diisopropyl ether ug/L ND 0.50 07/03/17 15:20
Ethylbenzene ug/L ND 0.50 07/03/17 15:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037609
Associated Lab Samples:92346051001, 92346051002, 92346051003, 92346051004
Matrix: Water
Analyzed
Hexachloro-1,3-butadiene ug/L ND 2.0 07/03/17 15:20
Isopropylbenzene (Cumene) ug/L ND 0.50 07/03/17 15:20
m&p-Xylene ug/L ND 1.0 07/03/17 15:20
Methyl-tert-butyl ether ug/L ND 0.50 07/03/17 15:20
Methylene Chloride ug/L ND 2.0 07/03/17 15:20
n-Butylbenzene ug/L ND 0.50 07/03/17 15:20
n-Propylbenzene ug/L ND 0.50 07/03/17 15:20
Naphthalene ug/L ND 2.0 07/03/17 15:20
o-Xylene ug/L ND 0.50 07/03/17 15:20
sec-Butylbenzene ug/L ND 0.50 07/03/17 15:20
Styrene ug/L ND 0.50 07/03/17 15:20
tert-Butylbenzene ug/L ND 0.50 07/03/17 15:20
Tetrachloroethene ug/L ND 0.50 07/03/17 15:20
Toluene ug/L ND 0.50 07/03/17 15:20
trans-1,2-Dichloroethene ug/L ND 0.50 07/03/17 15:20
trans-1,3-Dichloropropene ug/L ND 0.50 07/03/17 15:20
Trichloroethene ug/L ND 0.50 07/03/17 15:20
Trichlorofluoromethane ug/L ND 1.0 07/03/17 15:20
Vinyl chloride ug/L ND 1.0 07/03/17 15:20
1,2-Dichloroethane-d4 (S) % 103 70-130 07/03/17 15:20
4-Bromofluorobenzene (S) % 99 70-130 07/03/17 15:20
Toluene-d8 (S) % 101 70-130 07/03/17 15:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037610LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.650 101 60-140
1,1,1-Trichloroethane ug/L 51.750 103 60-140
1,1,2,2-Tetrachloroethane ug/L 51.350 103 60-140
1,1,2-Trichloroethane ug/L 48.250 96 60-140
1,1-Dichloroethane ug/L 50.750 101 60-140
1,1-Dichloroethene ug/L 50.250 100 60-140
1,1-Dichloropropene ug/L 52.450 105 60-140
1,2,3-Trichlorobenzene ug/L 53.450 107 60-140
1,2,3-Trichloropropane ug/L 50.950 102 60-140
1,2,4-Trichlorobenzene ug/L 52.350 105 60-140
1,2,4-Trimethylbenzene ug/L 52.750 105 60-140
1,2-Dibromo-3-chloropropane ug/L 53.450 107 60-140
1,2-Dibromoethane (EDB) ug/L 51.050 102 60-140
1,2-Dichlorobenzene ug/L 50.950 102 60-140
1,2-Dichloroethane ug/L 46.150 92 60-140
1,2-Dichloropropane ug/L 48.750 97 60-140
1,3,5-Trimethylbenzene ug/L 51.750 103 60-140
1,3-Dichlorobenzene ug/L 49.650 99 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037610LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 53.250 106 60-140
1,4-Dichlorobenzene ug/L 50.750 101 60-140
2,2-Dichloropropane ug/L 52.850 106 60-140
2-Chlorotoluene ug/L 51.850 104 60-140
4-Chlorotoluene ug/L 51.650 103 60-140
Benzene ug/L 49.250 98 60-140
Bromobenzene ug/L 49.950 100 60-140
Bromochloromethane ug/L 49.650 99 60-140
Bromodichloromethane ug/L 48.650 97 60-140
Bromoform ug/L 48.650 97 60-140
Bromomethane ug/L 44.150 88 60-140
Carbon tetrachloride ug/L 48.250 96 60-140
Chlorobenzene ug/L 49.250 98 60-140
Chloroethane ug/L 44.850 90 60-140
Chloroform ug/L 49.650 99 60-140
Chloromethane ug/L 37.150 74 60-140
cis-1,2-Dichloroethene ug/L 50.550 101 60-140
cis-1,3-Dichloropropene ug/L 51.250 102 60-140
Dibromochloromethane ug/L 52.550 105 60-140
Dibromomethane ug/L 47.450 95 60-140
Dichlorodifluoromethane ug/L 45.550 91 60-140
Diisopropyl ether ug/L 52.550 105 60-140
Ethylbenzene ug/L 51.250 102 60-140
Hexachloro-1,3-butadiene ug/L 54.450 109 60-140
Isopropylbenzene (Cumene) ug/L 50.550 101 60-140
m&p-Xylene ug/L 102100 102 60-140
Methyl-tert-butyl ether ug/L 54.150 108 60-140
Methylene Chloride ug/L 50.750 101 60-140
n-Butylbenzene ug/L 52.550 105 60-140
n-Propylbenzene ug/L 51.450 103 60-140
Naphthalene ug/L 54.250 108 60-140
o-Xylene ug/L 49.650 99 60-140
sec-Butylbenzene ug/L 51.450 103 60-140
Styrene ug/L 50.950 102 60-140
tert-Butylbenzene ug/L 43.550 87 60-140
Tetrachloroethene ug/L 46.150 92 60-140
Toluene ug/L 47.550 95 60-140
trans-1,2-Dichloroethene ug/L 49.750 99 60-140
trans-1,3-Dichloropropene ug/L 51.450 103 60-140
Trichloroethene ug/L 47.750 95 60-140
Trichlorofluoromethane ug/L 47.850 96 60-140
Vinyl chloride ug/L 46.850 94 60-140
1,2-Dichloroethane-d4 (S) % 106 70-130
4-Bromofluorobenzene (S) % 105 70-130
Toluene-d8 (S) % 99 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037611MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346051001
2037612
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 107 60-140109 1 3020ND 21.5 21.8
1,1,1-Trichloroethane ug/L 20 121 60-140120 1 3020ND 24.2 24.0
1,1,2,2-Tetrachloroethane ug/L 20 106 60-140105 0 3020ND 21.1 21.1
1,1,2-Trichloroethane ug/L 20 107 60-140106 1 3020ND 21.4 21.2
1,1-Dichloroethane ug/L 20 120 60-140121 1 3020ND 24.0 24.2
1,1-Dichloroethene ug/L 20 122 60-140122 0 3020ND 24.3 24.4
1,1-Dichloropropene ug/L 20 124 60-140123 0 3020ND 24.7 24.6
1,2,3-Trichlorobenzene ug/L 20 117 60-140116 1 3020ND 23.5 23.2
1,2,3-Trichloropropane ug/L 20 103 60-140105 2 3020ND 20.6 21.0
1,2,4-Trichlorobenzene ug/L 20 113 60-140111 1 3020ND 22.6 22.3
1,2,4-Trimethylbenzene ug/L 20 116 60-140118 1 3020ND 23.5 23.8
1,2-Dibromo-3-
chloropropane
ug/L 20 111 60-140105 5 3020ND 22.2 21.1
1,2-Dibromoethane (EDB) ug/L 20 109 60-140109 0 3020ND 21.7 21.7
1,2-Dichlorobenzene ug/L 20 109 60-140109 0 3020ND 21.7 21.8
1,2-Dichloroethane ug/L 20 106 60-140105 1 3020ND 21.3 21.0
1,2-Dichloropropane ug/L 20 111 60-140115 3 3020ND 22.2 22.9
1,3,5-Trimethylbenzene ug/L 20 114 60-140116 2 3020ND 22.8 23.1
1,3-Dichlorobenzene ug/L 20 108 60-140110 2 3020ND 21.6 22.0
1,3-Dichloropropane ug/L 20 113 60-140113 1 3020ND 22.6 22.7
1,4-Dichlorobenzene ug/L 20 109 60-140111 3 3020ND 21.7 22.3
2,2-Dichloropropane ug/L 20 123 60-140124 0 3020ND 24.7 24.8
2-Chlorotoluene ug/L 20 116 60-140117 2 3020ND 23.1 23.5
4-Chlorotoluene ug/L 20 112 60-140115 3 3020ND 22.3 23.1
Benzene ug/L 20 113 60-140117 3 30201.1 23.7 24.4
Bromobenzene ug/L 20 108 60-140111 3 3020ND 21.6 22.3
Bromochloromethane ug/L 20 116 60-140115 1 3020ND 23.3 22.9
Bromodichloromethane ug/L 20 114 60-140111 2 3020ND 22.7 22.3
Bromoform ug/L 20 99 60-14096 3 3020ND 19.7 19.2
Bromomethane ug/L 20 75 60-14083 10 3020ND 15.0 16.6
Carbon tetrachloride ug/L 20 114 60-140117 3 3020ND 22.8 23.4
Chlorobenzene ug/L 20 109 60-140111 1 3020ND 21.9 22.1
Chloroethane ug/L 20 109 60-140112 3 3020ND 21.9 22.4
Chloroform ug/L 20 117 60-140119 2 3020ND 23.4 23.8
Chloromethane ug/L 20 106 60-140131 17 30206.7 27.9 33.0
cis-1,2-Dichloroethene ug/L 20 118 60-140119 1 3020ND 23.5 23.7
cis-1,3-Dichloropropene ug/L 20 110 60-140111 1 3020ND 22.0 22.1
Dibromochloromethane ug/L 20 111 60-140114 2 3020ND 22.2 22.7
Dibromomethane ug/L 20 103 60-140104 1 3020ND 20.6 20.9
Dichlorodifluoromethane ug/L 20 109 60-140112 3 3020ND 21.7 22.3
Diisopropyl ether ug/L 20 120 60-140120 0 3020ND 24.0 24.1
Ethylbenzene ug/L 20 115 60-140118 3 3020ND 22.9 23.6
Hexachloro-1,3-butadiene ug/L 20 130 60-140123 5 3020ND 26.1 24.7
Isopropylbenzene (Cumene) ug/L 20 109 60-140116 6 30202.2 24.0 25.4
m&p-Xylene ug/L 40 113 60-140114 0 30401.0 46.3 46.4
Methyl-tert-butyl ether ug/L 20 118 60-140120 2 3020ND 23.6 23.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037611MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346051001
2037612
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methylene Chloride ug/L 20 117 60-140114 2 3020ND 23.3 22.9
n-Butylbenzene ug/L 20 120 60-140120 1 3020ND 24.1 23.9
n-Propylbenzene ug/L 20 115 60-140116 1 3020ND 23.3 23.6
Naphthalene ug/L 20 120 60-140117 2 3020ND 24.0 23.4
o-Xylene ug/L 20 107 60-140111 3 30200.54 21.9 22.7
sec-Butylbenzene ug/L 20 118 60-140117 1 3020ND 23.6 23.5
Styrene ug/L 20 110 60-140112 1 3020ND 22.0 22.3
tert-Butylbenzene ug/L 20 97 60-14097 0 3020ND 19.4 19.4
Tetrachloroethene ug/L 20 103 60-140104 1 3020ND 20.6 20.8
Toluene ug/L 20 110 60-140111 1 30204.1 26.0 26.2
trans-1,2-Dichloroethene ug/L 20 121 60-140121 0 3020ND 24.3 24.2
trans-1,3-Dichloropropene ug/L 20 109 60-140110 1 3020ND 21.8 22.0
Trichloroethene ug/L 20 112 60-140113 1 3020ND 22.4 22.6
Trichlorofluoromethane ug/L 20 115 60-140118 2 3020ND 23.0 23.5
Vinyl chloride ug/L 20 115 60-140114 0 3020ND 22.9 22.8
1,2-Dichloroethane-d4 (S) % 108 70-130109
4-Bromofluorobenzene (S) % 102 70-130102
Toluene-d8 (S) % 101 70-130101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367941
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples: 92346051008
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2039131
Associated Lab Samples:92346051008
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 07/06/17 16:28
1,1,1-Trichloroethane ug/L ND 0.50 07/06/17 16:28
1,1,2,2-Tetrachloroethane ug/L ND 0.50 07/06/17 16:28
1,1,2-Trichloroethane ug/L ND 0.50 07/06/17 16:28
1,1-Dichloroethane ug/L ND 0.50 07/06/17 16:28
1,1-Dichloroethene ug/L ND 0.50 07/06/17 16:28
1,1-Dichloropropene ug/L ND 0.50 07/06/17 16:28
1,2,3-Trichlorobenzene ug/L ND 2.0 07/06/17 16:28
1,2,3-Trichloropropane ug/L ND 0.50 07/06/17 16:28
1,2,4-Trichlorobenzene ug/L ND 2.0 07/06/17 16:28
1,2,4-Trimethylbenzene ug/L ND 0.50 07/06/17 16:28
1,2-Dibromo-3-chloropropane ug/L ND 1.0 07/06/17 16:28
1,2-Dibromoethane (EDB) ug/L ND 0.50 07/06/17 16:28
1,2-Dichlorobenzene ug/L ND 0.50 07/06/17 16:28
1,2-Dichloroethane ug/L ND 0.50 07/06/17 16:28
1,2-Dichloropropane ug/L ND 0.50 07/06/17 16:28
1,3,5-Trimethylbenzene ug/L ND 0.50 07/06/17 16:28
1,3-Dichlorobenzene ug/L ND 0.50 07/06/17 16:28
1,3-Dichloropropane ug/L ND 0.50 07/06/17 16:28
1,4-Dichlorobenzene ug/L ND 0.50 07/06/17 16:28
2,2-Dichloropropane ug/L ND 0.50 07/06/17 16:28
2-Chlorotoluene ug/L ND 0.50 07/06/17 16:28
4-Chlorotoluene ug/L ND 0.50 07/06/17 16:28
Benzene ug/L ND 0.50 07/06/17 16:28
Bromobenzene ug/L ND 0.50 07/06/17 16:28
Bromochloromethane ug/L ND 0.50 07/06/17 16:28
Bromodichloromethane ug/L ND 0.50 07/06/17 16:28
Bromoform ug/L ND 0.50 07/06/17 16:28
Bromomethane ug/L ND 5.0 07/06/17 16:28
Carbon tetrachloride ug/L ND 0.50 07/06/17 16:28
Chlorobenzene ug/L ND 0.50 07/06/17 16:28
Chloroethane ug/L ND 1.0 07/06/17 16:28
Chloroform ug/L ND 0.50 07/06/17 16:28
Chloromethane ug/L ND 1.0 07/06/17 16:28
cis-1,2-Dichloroethene ug/L ND 0.50 07/06/17 16:28
cis-1,3-Dichloropropene ug/L ND 0.50 07/06/17 16:28
Dibromochloromethane ug/L ND 0.50 07/06/17 16:28
Dibromomethane ug/L ND 0.50 07/06/17 16:28
Dichlorodifluoromethane ug/L ND 0.50 07/06/17 16:28
Diisopropyl ether ug/L ND 0.50 07/06/17 16:28
Ethylbenzene ug/L ND 0.50 07/06/17 16:28
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2039131
Associated Lab Samples:92346051008
Matrix: Water
Analyzed
Hexachloro-1,3-butadiene ug/L ND 2.0 07/06/17 16:28
Isopropylbenzene (Cumene) ug/L ND 0.50 07/06/17 16:28
m&p-Xylene ug/L ND 1.0 07/06/17 16:28
Methyl-tert-butyl ether ug/L ND 0.50 07/06/17 16:28
Methylene Chloride ug/L ND 2.0 07/06/17 16:28
n-Butylbenzene ug/L ND 0.50 07/06/17 16:28
n-Propylbenzene ug/L ND 0.50 07/06/17 16:28
Naphthalene ug/L ND 2.0 07/06/17 16:28
o-Xylene ug/L ND 0.50 07/06/17 16:28
sec-Butylbenzene ug/L ND 0.50 07/06/17 16:28
Styrene ug/L ND 0.50 07/06/17 16:28
tert-Butylbenzene ug/L ND 0.50 07/06/17 16:28
Tetrachloroethene ug/L ND 0.50 07/06/17 16:28
Toluene ug/L ND 0.50 07/06/17 16:28
trans-1,2-Dichloroethene ug/L ND 0.50 07/06/17 16:28
trans-1,3-Dichloropropene ug/L ND 0.50 07/06/17 16:28
Trichloroethene ug/L ND 0.50 07/06/17 16:28
Trichlorofluoromethane ug/L ND 1.0 07/06/17 16:28
Vinyl chloride ug/L ND 1.0 07/06/17 16:28
1,2-Dichloroethane-d4 (S) % 104 70-130 07/06/17 16:28
4-Bromofluorobenzene (S) % 98 70-130 07/06/17 16:28
Toluene-d8 (S) % 103 70-130 07/06/17 16:28
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2039132LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 49.850 100 60-140
1,1,1-Trichloroethane ug/L 52.350 105 60-140
1,1,2,2-Tetrachloroethane ug/L 48.250 96 60-140
1,1,2-Trichloroethane ug/L 47.650 95 60-140
1,1-Dichloroethane ug/L 51.550 103 60-140
1,1-Dichloroethene ug/L 51.350 103 60-140
1,1-Dichloropropene ug/L 52.450 105 60-140
1,2,3-Trichlorobenzene ug/L 52.850 106 60-140
1,2,3-Trichloropropane ug/L 47.850 96 60-140
1,2,4-Trichlorobenzene ug/L 50.950 102 60-140
1,2,4-Trimethylbenzene ug/L 51.350 103 60-140
1,2-Dibromo-3-chloropropane ug/L 50.150 100 60-140
1,2-Dibromoethane (EDB) ug/L 49.650 99 60-140
1,2-Dichlorobenzene ug/L 49.550 99 60-140
1,2-Dichloroethane ug/L 47.050 94 60-140
1,2-Dichloropropane ug/L 49.450 99 60-140
1,3,5-Trimethylbenzene ug/L 50.450 101 60-140
1,3-Dichlorobenzene ug/L 48.950 98 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
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[phone]
Page 45 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2039132LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 51.950 104 60-140
1,4-Dichlorobenzene ug/L 49.550 99 60-140
2,2-Dichloropropane ug/L 52.650 105 60-140
2-Chlorotoluene ug/L 52.050 104 60-140
4-Chlorotoluene ug/L 50.750 101 60-140
Benzene ug/L 49.550 99 60-140
Bromobenzene ug/L 49.250 98 60-140
Bromochloromethane ug/L 51.250 102 60-140
Bromodichloromethane ug/L 49.850 100 60-140
Bromoform ug/L 46.350 93 60-140
Bromomethane ug/L 45.750 91 60-140
Carbon tetrachloride ug/L 48.850 98 60-140
Chlorobenzene ug/L 48.450 97 60-140
Chloroethane ug/L 45.850 92 60-140
Chloroform ug/L 51.050 102 60-140
Chloromethane ug/L 42.550 85 60-140
cis-1,2-Dichloroethene ug/L 51.350 103 60-140
cis-1,3-Dichloropropene ug/L 51.950 104 60-140
Dibromochloromethane ug/L 51.950 104 60-140
Dibromomethane ug/L 47.550 95 60-140
Dichlorodifluoromethane ug/L 45.450 91 60-140
Diisopropyl ether ug/L 54.050 108 60-140
Ethylbenzene ug/L 49.850 100 60-140
Hexachloro-1,3-butadiene ug/L 52.850 106 60-140
Isopropylbenzene (Cumene) ug/L 49.150 98 60-140
m&p-Xylene ug/L 98.3100 98 60-140
Methyl-tert-butyl ether ug/L 52.850 106 60-140
Methylene Chloride ug/L 53.550 107 60-140
n-Butylbenzene ug/L 51.450 103 60-140
n-Propylbenzene ug/L 51.050 102 60-140
Naphthalene ug/L 52.450 105 60-140
o-Xylene ug/L 48.250 96 60-140
sec-Butylbenzene ug/L 50.850 102 60-140
Styrene ug/L 49.650 99 60-140
tert-Butylbenzene ug/L 42.250 84 60-140
Tetrachloroethene ug/L 45.150 90 60-140
Toluene ug/L 47.350 95 60-140
trans-1,2-Dichloroethene ug/L 50.850 102 60-140
trans-1,3-Dichloropropene ug/L 51.950 104 60-140
Trichloroethene ug/L 48.050 96 60-140
Trichlorofluoromethane ug/L 48.450 97 60-140
Vinyl chloride ug/L 47.250 94 60-140
1,2-Dichloroethane-d4 (S) % 108 70-130
4-Bromofluorobenzene (S) % 103 70-130
Toluene-d8 (S) % 101 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
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[phone]
Page 46 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2039133MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346356001
2039134
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 100 60-140101 2 3020ND 19.9 20.2
1,1,1-Trichloroethane ug/L 20 111 60-140114 2 3020ND 22.3 22.8
1,1,2,2-Tetrachloroethane ug/L 20 100 60-140101 1 3020ND 20.0 20.3
1,1,2-Trichloroethane ug/L 20 102 60-140103 1 3020ND 20.5 20.6
1,1-Dichloroethane ug/L 20 112 60-140112 0 3020ND 22.4 22.4
1,1-Dichloroethene ug/L 20 110 60-140113 3 3020ND 22.0 22.7
1,1-Dichloropropene ug/L 20 116 60-140115 1 3020ND 23.2 23.0
1,2,3-Trichlorobenzene ug/L 20 102 60-140117 14 3020ND 20.4 23.4
1,2,3-Trichloropropane ug/L 20 98 60-140101 2 3020ND 19.7 20.1
1,2,4-Trichlorobenzene ug/L 20 105 60-140110 4 3020ND 21.1 22.0
1,2,4-Trimethylbenzene ug/L 20 108 60-140111 3 3020ND 21.5 22.3
1,2-Dibromo-3-
chloropropane
ug/L 20 100 60-140109 9 3020ND 20.0 21.7
1,2-Dibromoethane (EDB) ug/L 20 102 60-140102 0 3020ND 20.4 20.4
1,2-Dichlorobenzene ug/L 20 103 60-140107 4 3020ND 20.5 21.4
1,2-Dichloroethane ug/L 20 98 60-140100 2 3020ND 19.6 19.9
1,2-Dichloropropane ug/L 20 105 60-140110 4 3020ND 21.0 21.9
1,3,5-Trimethylbenzene ug/L 20 105 60-140110 5 3020ND 21.0 22.0
1,3-Dichlorobenzene ug/L 20 100 60-140103 3 3020ND 19.9 20.6
1,3-Dichloropropane ug/L 20 108 60-140111 3 3020ND 21.5 22.1
1,4-Dichlorobenzene ug/L 20 100 60-140105 5 3020ND 19.9 21.0
2,2-Dichloropropane ug/L 20 101 60-14099 1 3020ND 20.1 19.9
2-Chlorotoluene ug/L 20 108 60-140112 4 3020ND 21.6 22.4
4-Chlorotoluene ug/L 20 104 60-140109 5 3020ND 20.7 21.8
Benzene ug/L 20 108 60-140110 2 3020ND 21.5 22.0
Bromobenzene ug/L 20 102 60-140106 4 3020ND 20.4 21.1
Bromochloromethane ug/L 20 107 60-140107 0 3020ND 21.5 21.4
Bromodichloromethane ug/L 20 104 60-140106 1 3020ND 20.9 21.2
Bromoform ug/L 20 86 60-14091 6 3020ND 17.2 18.2
Bromomethane ug/L 20 100 60-140102 2 3020ND 20.0 20.3
Carbon tetrachloride ug/L 20 105 60-140109 4 3020ND 21.1 21.9
Chlorobenzene ug/L 20 102 60-140105 3 3020ND 20.5 21.0
Chloroethane ug/L 20 103 60-14099 4 3020ND 20.6 19.8
Chloroform ug/L 20 110 60-140108 2 3020ND 22.0 21.7
Chloromethane ug/L 20 94 60-14088 6 3020ND 18.7 17.6
cis-1,2-Dichloroethene ug/L 20 112 60-140112 0 3020ND 22.4 22.4
cis-1,3-Dichloropropene ug/L 20 102 60-140106 4 3020ND 20.4 21.2
Dibromochloromethane ug/L 20 102 60-140107 5 3020ND 20.4 21.3
Dibromomethane ug/L 20 95 60-140101 5 3020ND 19.1 20.1
Dichlorodifluoromethane ug/L 20 100 60-140101 0 3020ND 20.1 20.1
Diisopropyl ether ug/L 20 110 60-140111 1 3020ND 22.0 22.2
Ethylbenzene ug/L 20 106 60-140110 3 3020ND 21.3 22.0
Hexachloro-1,3-butadiene ug/L 20 105 60-140117 11 3020ND 21.0 23.4
Isopropylbenzene (Cumene) ug/L 20 100 60-140107 7 3020ND 20.0 21.4
m&p-Xylene ug/L 40 103 60-140107 4 3040ND 41.4 42.9
Methyl-tert-butyl ether ug/L 20 108 60-140110 2 3020ND 21.6 22.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 47 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2039133MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346356001
2039134
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methylene Chloride ug/L 20 104 60-140104 0 3020ND 20.9 20.8
n-Butylbenzene ug/L 20 110 60-140114 3 3020ND 22.0 22.7
n-Propylbenzene ug/L 20 106 60-140111 5 3020ND 21.1 22.1
Naphthalene ug/L M1,R120 171 60-140122 33 3020ND 34.1 24.5
o-Xylene ug/L 20 101 60-140103 2 3020ND 20.2 20.7
sec-Butylbenzene ug/L 20 105 60-140109 4 3020ND 21.0 21.8
Styrene ug/L 20 100 60-140104 4 3020ND 20.0 20.8
tert-Butylbenzene ug/L 20 88 60-14094 6 3020ND 17.6 18.7
Tetrachloroethene ug/L 20 94 60-14098 4 3020ND 18.9 19.6
Toluene ug/L 20 105 60-140109 4 3020ND 20.9 21.7
trans-1,2-Dichloroethene ug/L 20 112 60-140113 1 3020ND 22.4 22.6
trans-1,3-Dichloropropene ug/L 20 99 60-140104 5 3020ND 19.9 20.9
Trichloroethene ug/L 20 104 60-140106 1 3020ND 20.9 21.2
Trichlorofluoromethane ug/L 20 107 60-140106 2 3020ND 21.5 21.1
Vinyl chloride ug/L 20 100 60-140108 8 3020ND 20.0 21.6
1,2-Dichloroethane-d4 (S) % 108 70-130106
4-Bromofluorobenzene (S) % 102 70-130101
Toluene-d8 (S) % 102 70-130104
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
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Huntersville, NC 28078
[phone]
Page 48 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
368113
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples: 92346051005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2040011
Associated Lab Samples:92346051005
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 07/07/17 01:50
1,1,1-Trichloroethane ug/L ND 0.50 07/07/17 01:50
1,1,2,2-Tetrachloroethane ug/L ND 0.50 07/07/17 01:50
1,1,2-Trichloroethane ug/L ND 0.50 07/07/17 01:50
1,1-Dichloroethane ug/L ND 0.50 07/07/17 01:50
1,1-Dichloroethene ug/L ND 0.50 07/07/17 01:50
1,1-Dichloropropene ug/L ND 0.50 07/07/17 01:50
1,2,3-Trichlorobenzene ug/L ND 2.0 07/07/17 01:50
1,2,3-Trichloropropane ug/L ND 0.50 07/07/17 01:50
1,2,4-Trichlorobenzene ug/L ND 2.0 07/07/17 01:50
1,2,4-Trimethylbenzene ug/L ND 0.50 07/07/17 01:50
1,2-Dibromo-3-chloropropane ug/L ND 1.0 07/07/17 01:50
1,2-Dibromoethane (EDB) ug/L ND 0.50 07/07/17 01:50
1,2-Dichlorobenzene ug/L ND 0.50 07/07/17 01:50
1,2-Dichloroethane ug/L ND 0.50 07/07/17 01:50
1,2-Dichloropropane ug/L ND 0.50 07/07/17 01:50
1,3,5-Trimethylbenzene ug/L ND 0.50 07/07/17 01:50
1,3-Dichlorobenzene ug/L ND 0.50 07/07/17 01:50
1,3-Dichloropropane ug/L ND 0.50 07/07/17 01:50
1,4-Dichlorobenzene ug/L ND 0.50 07/07/17 01:50
2,2-Dichloropropane ug/L ND 0.50 07/07/17 01:50
2-Chlorotoluene ug/L ND 0.50 07/07/17 01:50
4-Chlorotoluene ug/L ND 0.50 07/07/17 01:50
Benzene ug/L ND 0.50 07/07/17 01:50
Bromobenzene ug/L ND 0.50 07/07/17 01:50
Bromochloromethane ug/L ND 0.50 07/07/17 01:50
Bromodichloromethane ug/L ND 0.50 07/07/17 01:50
Bromoform ug/L ND 0.50 07/07/17 01:50
Bromomethane ug/L ND 5.0 07/07/17 01:50
Carbon tetrachloride ug/L ND 0.50 07/07/17 01:50
Chlorobenzene ug/L ND 0.50 07/07/17 01:50
Chloroethane ug/L ND 1.0 07/07/17 01:50
Chloroform ug/L ND 0.50 07/07/17 01:50
Chloromethane ug/L ND 1.0 07/07/17 01:50
cis-1,2-Dichloroethene ug/L ND 0.50 07/07/17 01:50
cis-1,3-Dichloropropene ug/L ND 0.50 07/07/17 01:50
Dibromochloromethane ug/L ND 0.50 07/07/17 01:50
Dibromomethane ug/L ND 0.50 07/07/17 01:50
Dichlorodifluoromethane ug/L ND 0.50 07/07/17 01:50
Diisopropyl ether ug/L ND 0.50 07/07/17 01:50
Ethylbenzene ug/L ND 0.50 07/07/17 01:50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 49 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2040011
Associated Lab Samples:92346051005
Matrix: Water
Analyzed
Hexachloro-1,3-butadiene ug/L ND 2.0 07/07/17 01:50
Isopropylbenzene (Cumene) ug/L ND 0.50 07/07/17 01:50
m&p-Xylene ug/L ND 1.0 07/07/17 01:50
Methyl-tert-butyl ether ug/L ND 0.50 07/07/17 01:50
Methylene Chloride ug/L ND 2.0 07/07/17 01:50
n-Butylbenzene ug/L ND 0.50 07/07/17 01:50
n-Propylbenzene ug/L ND 0.50 07/07/17 01:50
Naphthalene ug/L ND 2.0 07/07/17 01:50
o-Xylene ug/L ND 0.50 07/07/17 01:50
sec-Butylbenzene ug/L ND 0.50 07/07/17 01:50
Styrene ug/L ND 0.50 07/07/17 01:50
tert-Butylbenzene ug/L ND 0.50 07/07/17 01:50
Tetrachloroethene ug/L ND 0.50 07/07/17 01:50
Toluene ug/L ND 0.50 07/07/17 01:50
trans-1,2-Dichloroethene ug/L ND 0.50 07/07/17 01:50
trans-1,3-Dichloropropene ug/L ND 0.50 07/07/17 01:50
Trichloroethene ug/L ND 0.50 07/07/17 01:50
Trichlorofluoromethane ug/L ND 1.0 07/07/17 01:50
Vinyl chloride ug/L ND 1.0 07/07/17 01:50
1,2-Dichloroethane-d4 (S) % 106 70-130 07/07/17 01:50
4-Bromofluorobenzene (S) % 98 70-130 07/07/17 01:50
Toluene-d8 (S) % 104 70-130 07/07/17 01:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2040012LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 46.950 94 60-140
1,1,1-Trichloroethane ug/L 48.150 96 60-140
1,1,2,2-Tetrachloroethane ug/L 46.050 92 60-140
1,1,2-Trichloroethane ug/L 45.150 90 60-140
1,1-Dichloroethane ug/L 48.050 96 60-140
1,1-Dichloroethene ug/L 45.450 91 60-140
1,1-Dichloropropene ug/L 48.750 97 60-140
1,2,3-Trichlorobenzene ug/L 49.250 98 60-140
1,2,3-Trichloropropane ug/L 45.950 92 60-140
1,2,4-Trichlorobenzene ug/L 48.750 97 60-140
1,2,4-Trimethylbenzene ug/L 48.150 96 60-140
1,2-Dibromo-3-chloropropane ug/L 49.750 99 60-140
1,2-Dibromoethane (EDB) ug/L 47.450 95 60-140
1,2-Dichlorobenzene ug/L 47.150 94 60-140
1,2-Dichloroethane ug/L 44.350 89 60-140
1,2-Dichloropropane ug/L 46.550 93 60-140
1,3,5-Trimethylbenzene ug/L 46.150 92 60-140
1,3-Dichlorobenzene ug/L 45.250 90 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 50 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346051
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2040012LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 50.050 100 60-140
1,4-Dichlorobenzene ug/L 46.250 92 60-140
2,2-Dichloropropane ug/L 43.150 86 60-140
2-Chlorotoluene ug/L 47.450 95 60-140
4-Chlorotoluene ug/L 46.650 93 60-140
Benzene ug/L 46.250 92 60-140
Bromobenzene ug/L 45.750 91 60-140
Bromochloromethane ug/L 48.350 97 60-140
Bromodichloromethane ug/L 46.950 94 60-140
Bromoform ug/L 43.050 86 60-140
Bromomethane ug/L 42.850 86 60-140
Carbon tetrachloride ug/L 44.450 89 60-140
Chlorobenzene ug/L 45.950 92 60-140
Chloroethane ug/L 43.050 86 60-140
Chloroform ug/L 47.750 95 60-140
Chloromethane ug/L 40.550 81 60-140
cis-1,2-Dichloroethene ug/L 47.250 94 60-140
cis-1,3-Dichloropropene ug/L 48.250 96 60-140
Dibromochloromethane ug/L 50.250 100 60-140
Dibromomethane ug/L 43.750 87 60-140
Dichlorodifluoromethane ug/L 40.650 81 60-140
Diisopropyl ether ug/L 49.850 100 60-140
Ethylbenzene ug/L 46.950 94 60-140
Hexachloro-1,3-butadiene ug/L 47.650 95 60-140
Isopropylbenzene (Cumene) ug/L 44.850 90 60-140
m&p-Xylene ug/L 91.4100 91 60-140
Methyl-tert-butyl ether ug/L 49.950 100 60-140
Methylene Chloride ug/L 49.350 99 60-140
n-Butylbenzene ug/L 47.250 94 60-140
n-Propylbenzene ug/L 46.250 92 60-140
Naphthalene ug/L 52.350 105 60-140
o-Xylene ug/L 45.450 91 60-140
sec-Butylbenzene ug/L 45.950 92 60-140
Styrene ug/L 46.550 93 60-140
tert-Butylbenzene ug/L 39.150 78 60-140
Tetrachloroethene ug/L 41.450 83 60-140
Toluene ug/L 44.850 90 60-140
trans-1,2-Dichloroethene ug/L 46.250 92 60-140
trans-1,3-Dichloropropene ug/L 47.850 96 60-140
Trichloroethene ug/L 44.050 88 60-140
Trichlorofluoromethane ug/L 42.350 85 60-140
Vinyl chloride ug/L 43.550 87 60-140
1,2-Dichloroethane-d4 (S) % 105 70-130
4-Bromofluorobenzene (S) % 102 70-130
Toluene-d8 (S) % 100 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 51 of 56
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92346051
FRIENDLY MART
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 52 of 56
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92346051
FRIENDLY MART
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92346051001 367597MW 1 SM 6200B
92346051002 367597MW 3 SM 6200B
92346051003 367597MW 4 SM 6200B
92346051004 367597MW 5 SM 6200B
92346051005 368113MW 6 SM 6200B
92346051006 367181MW 7 SM 6200B
92346051007 367181MW 8 SM 6200B
92346051008 367941MW 9 SM 6200B
92346051009 367181MW 10 SM 6200B
92346051010 367181MW 11 SM 6200B
92346051011 367180SW 1 SM 6200B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/07/2017 03:42 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 53 of 56
Page 54 of 56
Page 55 of 56
Page 56 of 56