4104_CityHighPointKerseyValleyMSWLF_Sep2017GWMR_20171201

December 1, 2017

Ms. Jaclynne Drummond, Compliance Hydrogeologist
Division of Waste Management, Solid Waste Section
Asheville Regional Office
2090 US Highway 70
Swannanoa, North Carolina 28778

Re: Alternate Source Demonstration Addendum
Kersey Valley MSWLF Permit No. 4104-MSWLF-1991
High Point, Guilford County, North Carolina

Dear Jackie,

This Alternative Source Demonstration Addendum (ASDA) is provided to address the
approved June 26, 2017 Scope of Work and July 28, 2017 Additional Work Activities which
were approved by NCDEQ on August 15, 2017. Babb & Associates, P.A. is providing this
ASDA pursuant to 15A NCAC 13B .1633(c)(3) on behalf of the City of High Point to
address the historic concentration of cadmium in monitoring well 4104-MW4, an existing
compliance well in the water quality monitoring network.

The approved ASDA Scope of Work provided for the replacement of monitoring well 4104-
MW4 and the collection of soil and groundwater samples to determine the naturally
occurring concentration of inorganic compounds in the groundwater hydraulically upgradient
of the MSWLF. A description of the field activities, soil and groundwater laboratory
analytical results, and ASDA conclusions is provided below.

Background Information

The Kersey Valley Landfill is located approximately five miles east of downtown High Point
and one-half mile east of the intersection of US 70/US 29/I-85 Business on Kivett Drive.
The surrounding area is mixed residential and commercial land uses.

The Kersey Valley Landfill is located in the central Piedmont Physiographic Province, in the
northern portion of the Carolina Slate Belt. Granite is the predominant rock type in the area
and outcrops are observed along the creeks and within the site. Groundwater in the
uppermost aquifer generally flows through unconsolidated sediments and secondary fractures
in the underlying bedrock. Recharge occurs primarily in the northern portion of the site and
is limited on slopes. Groundwater flows generally south where it discharges into two
unnamed tributaries of Richland Creek.

The groundwater potentiometric map (Figure 1) shows that monitoring well 4104-MW4 and
the location of the new replacement well are hydraulically upgradient of the landfill
operations and hydraulically downgradient of several commercial and residential properties
along Kivett Drive. As noted in the approved Water Quality Monitoring Plan for the Kersey
Valley Landfill, monitoring well 4104-MW4 is identified as “Upgradient of Phase 3”.
Phases 1 through 3 were part of the original Area 1 landfill as shown on Figure 1.

Historically, monitoring well 4104-MW4 has shown minor concentrations of cadmium over
the past four years, ranging from a low of Below Quantitation Limits (BQL) in May 2014 to
a high of 20.3 ug/l in April 2015. No other inorganic compounds have been reported above
the NC 2L Groundwater Standards in monitoring well 4104-MW4. No other wells in the
groundwater monitoring network have reported inorganic constituents in concentrations
exceeding the NC 2L Groundwater Standards during recent water quality monitoring events.

Monitoring Well Installation and Soil Sampling

A new monitoring well was installed on September 5, 2017 to replace the existing 4104-
MW4. The new well (4104-MW4A) is located approximately 75 feet to the east as shown on
Figure 2.

The new well was installed to a depth of 30 feet below land surface and constructed in
accordance with the NC Well Construction Standards. The well was completed with a
lockable steel above-grade protector and a 2’x2’ concrete pad. The Well Construction
Record (GW-1) and the Well Construction Schematic are provided in Appendix A.

During drilling of the new well, three soil samples were collected for laboratory analyses of
total Appendix I metals. The soil samples were collected at depths of 8’, 18’, and 25’ to
evaluate naturally occurring metals concentrations in the clay and silty sand soil encountered
during the soil boring. A soil boring log for 4104-MW4A is provided in Appendix A.

After installation, the well was developed to remove as much sediment as possible. An
attempt was made to conduct a bail test on the new monitoring well to determine the
estimated hydraulic conductivity of the shallow aquifer. It was determined that the recharge
rate of the shallow aquifer did not allow for lowering the water table more that 2-3 inches
using either a bailer or peristaltic pump. It is likely the high yield of the well is due to the
relic open fractures observed at a depth of 16’ below land surface. If additional information
is needed regarding aquifer properties, a higher capacity pump will be necessary.

Groundwater Sample Collection

Three groundwater samples were collected from the new well following well installation and
development. Two groundwater samples were collected using a new disposable bailer. One
sample was collected with a nitric acid preservative and a duplicate sample was collected
unpreserved. The unpreserved sample was filtered in the laboratory using a 0.45 micron
filter prior to adding the preservative.

A third groundwater sample was collected from the new well using low-flow sampling
methodology. This sample was collected using a peristaltic pump to slowly remove water
within the screened section of the casing while continuously monitoring indicator parameters
(pH, conductivity, temperature, dissolved oxygen, and ORP) using a flow cell. The turbidity
of the sample was also be monitored during the low-flow sampling process. The sample was
collected in a laboratory container with nitric acid preservative after the indicator parameters
had stabilized and the turbidity was below 10 NTU (Table 1).

The three groundwater samples were submitted to the laboratory for analysis of total
Appendix I metals. A temperature blank was provided to assure proper transport of the
samples. The samples were hand delivered to the analytical laboratory under chain of
custody control.

Laboratory Analysis

The soil and groundwater samples from monitoring well 4104-MW4A were received by the
analytical laboratory (Environmental Conservation Laboratories, Inc. of Cary, NC) on
September 7, 2017. The analytical report was issued by ENCO laboratory on September 27,
2017 (Appendix B). A summary of the laboratory analytical results is provided with this
report for groundwater (Table 2) and soil (Table 3).

Soil Analytical Results

The laboratory analysis of the three soil samples (SS-1, SS-2, and SS-3) reported
concentrations above the laboratory reporting limit for several inorganic compounds,
including: barium, cobalt, copper, vanadium, and zinc. Soil sample SS-1 was
collected above the water table at a depth of 8’ below land surface. Soil samples SS-
2 and SS-3 were collected below the water table at depths of 18’ and 25’,
respectfully. The higher concentration of inorganic compounds in SS-2 and SS-3 may
be attributed to the relatively low pH of the groundwater (~4.5 pH).

Groundwater Analytical Results

The three groundwater samples collected from 4104-MW4A did not report any
inorganic compounds above the laboratory reporting limits. Several inorganic
compounds were detected above the method detection limit but below the method
reporting limit (J flagged), including: barium, chromium, copper, thallium,
vanadium, and zinc. These detected compounds generally correspond to the results of
the soil sample analysis.

A comparison of the three sample collection methodologies (bailer, bailer with
filtering, and low-flow) did not indicate an appreciable difference in the reported
concentrations of inorganic compounds.
Conclusions and Recommendations

Based on current and historic groundwater elevations at the site, new monitoring well 4104-
MW4A is hydraulically upgradient of the landfill operations and downgradient of several
commercial/residential properties along Kivett Drive.

The laboratory analysis of the three soil samples collected during the installation of 4104-
MW4A reported concentrations of barium, cobalt, copper, vanadium, and zinc above the
laboratory reporting limit.

The laboratory analysis of the three groundwater samples, collected with a bailer, bailer with
filter, and low-flow, did not report any Appendix I inorganic compounds above the
laboratory reporting limits. The method of sample collection did not appear to affect the
outcome of the inorganic laboratory analysis.

Based on the results of the Appendix I inorganic sampling and analysis of new monitoring
well 4104-MW4A, groundwater quality at this location has not been impacted by landfill
operations or any other activities. Based on the results of this ASDA and the hydraulic
position of monitoring well 4104-MW4A with respect to the Kersey Valley Landfill
operations, Babb & Associates, P.A. recommends continuation of detection monitoring at the
facility.

We appreciate your consideration of this ASDA and look forward to your response to this
submittal. If there are any questions concerning this information, please contact the
undersigned at [phone].

Respectfully,

Babb & Associates, P.A.

Gary D. Babb, P.G.
President

Cc: Mr. Mike Spencer, City of High Point
Mr. Robby Stone, City of High Point

FIGURES
TOC=784.62DTW=13.49GWE=771.13MW-7DTOC=783.97DTW=21.22GWE=762.75MW-8ATOC=760.69DTW=7.12GWE=753.57MW-8BTOC=760.91DTW=7.64GWE=753.27MW-15TOC=775.93DTW=15.10GWE=760.83MW-9TOC=786.48DTW=21.66GWE=764.82MW-10TOC=814.84DTW=20.77GWE=794.07MW-1TOC=833.37DTW=28.41GWE=804.96MW-4TOC=830.32DTW=15.77GWE=814.55MW-6ATOC=784.62MW-11TOC=813.06DTW=9.58GWE=803.48MW-12TOC=782.18DTW=9.10GWE=773.08MW-13STOC=819.19DTW=23.69GWE=795.50MW-13DTOC=818.78DTW=23.51GWE=795.27MW-14TOC=805.21DTW=16.41GWE=788.80MW-9TOC=786.48DTW=21.66GWE=764.82MW-10TOC=814.84DTW=20.77GWE=794.07MW-1TOC=833.37DTW=28.41GWE=804.96MW-4TOC=830.32DTW=15.77GWE=814.55MW-6ATOC=784.62MW-11TOC=813.06DTW=9.58GWE=803.48MW-12TOC=782.18DTW=9.10GWE=773.08MW-13STOC=819.19DTW=23.69GWE=795.50MW-13DTOC=818.78DTW=23.51GWE=795.27MW-14TOC=805.21DTW=16.41GWE=788.80PROJECT TITLE:DRAWING TITLE:REV. DATEDESCRIPTIONDESIGNED:DRAWN:APPROVED:PROJECT NO:SCALE:FILENAME:PREPARED BY:PREPARED FOR:SHEET NUMBER:DRAWING NUMBER:DATE:G:\CAD\High Point\Hpoint 14-1\sheets\HP-D0511.dwg - 5/11/2016 10:32 AM
SEALSEALSMITHGARDNERENGINEERS+14 N. Boylan Avenue, Raleigh NC 27603NC LIC. NO. C-0828 (ENGINEERING)919.828.0577Electronic files are instruments of service provided by SmithGardner, Inc. for the convenience of the intended recipient(s), andno warranty is either expressed or implied.  Any reuse orredistribution of this document in whole or part without thewritten authorization of Smith Gardner, Inc., will be at the solerisk of the recipient.  If there is a discrepancy between theelectronic files and the signed and sealed hard copies, the hardcopies shall govern.  Use of  any electronic files generated orprovided by Smith Gardner, Inc., constitutes an acceptance ofthese terms and conditions.© 2014 Smith Gardner, Inc.CITY OF HIGH POINTDEPARTMENT OFPUBLIC SERVICESHIGH POINT, NCKERSEY VALLEY MSW LANDFILLPHASES 5A & 5BGROUNDWATERPOTENTIOMETRICSURFACE MAPAPRIL 2016 M.M.G.C.T.J.HPOINT 16-1AS SHOWNMay 2016HP-D0511FIG.1MW-1TOC=DTW=GWE=

TABLES
TABLE 1Monitoring Well 4104-MW4A Low-Flow Field MeasurementsKersey Valley MSWLFHigh Point, North CarolinaPermit #41-04Time Temperature Dissolved Oxygen Conductivity pH ORP Turbidity915 19.1 5.60 67.2 6.45 152 NM920 18.5 5.30 64.8 5.78 180 735.0924 18.4 6.60 64.0 5.49 198 NM928 18.3 6.70 63.2 5.48 198 386.0932 18.3 6.60 62.9 5.35 200 NM935 18.3 6.30 62.8 5.08 207 168.0939 18.3 6.15 62.5 4.94 206 101.0945 18.8 5.64 62.1 4.84 204 37.0949 18.9 5.40 61.9 4.80 204 28.0953 18.9 5.30 62.1 4.70 202 25.01000 18.8 5.16 62.0 4.60 208 14.01005 19.0 5.07 61.9 4.38 199 16.01010 19.0 5.02 61.8 4.56 196 11.01015 19.0 5.32 61.8 4.50 194 8.5Notes:Field parameters measured using a YSI 556 Multi-Probe Meter with Flow Cell and Hanna HI 98703 Turbidity MeterNM - No Measurement
TABLE 2Monitoring Well 4104-MW4AGroundwater Analytical ResultsKersey Valley MSWLFHigh Point, North CarolinaPermit #41-04Parameter Bailer Bailer Filtered Low-Flow 2L Groundwater StandardAntimony BQL BQL BQL NEArsenic BQL BQL BQL 10Barium 38.2 J 30.1 J 37.7 J 700Beryllium BQL BQL BQL NECadmium BQL BQL BQL 2Chromium 1.83 J 1.70 J 1.62 J 10Cobalt BQL BQL BQL NECopper 3.22 J BQL BQL 1000Lead BQL BQL BQL 15Nickel BQL BQL BQL 100Selenium BQL BQL BQL 20Silver BQL BQL BQL 20Thallium 0.305 J 0.304 J 0.220 J NEVanadium 2.05 J BQL 1.83 J NEZinc 7.82 J 4.95 J 6.54 J 1000Notes:All laboratory results and 2L Standards in ug/lNE - Not EstablishedBQL - Below Quantitation LimitJ - Estimated concentration, below method reporting limitSamples collected on September 7, 2017
TABLE 3Monitoring Well 4104-MW4ASoil Analytical ResultsKersey Valley MSWLFHigh Point, North CarolinaPermit #41-04Parameter SS-1 SS-2 SS-3Antimony BQL BQL BQLArsenic 0.507 J 2.62 J BQLBarium 83.8 J211 435Beryllium BQL BQL BQLCadmium BQL BQL BQLChromium 3.65 J 3.88 J 3.71 JCobalt 1.99 J12.7 29.8Copper15.0 53.2 59.1Lead 4.55 J 4.84 J 5.85 JNickel 2.41 J 4.34 J 11.0 JSelenium BQL BQL BQLSilver 0.209 J 0.363 J 0.366 JThallium BQL BQL 0.0719 JVanadium39.7 66.9 52.1Zinc12.0 42.3 45.9Notes:All laboratory results in mg/kg dryBold Concentrations Above Quantitation LimitBQL - Below Quantitation LimitJ - Estimated concentration, below method reporting limitSamples collected on September 7, 2017

APPENDIX A
BABB AND ASSOCIATES, P.A.
Raleigh, North Carolina
SOIL BORING LOG
PROJECT:Kersey Valley Landfill
PROJECT #:4104-MSWLF-1991
BORING ID:MW-4 Replacement Page:1 of 1
Date:9/5/17 Total Depth:30.0 feet
Method:Hollow-Stem Auger Boring Dia:6.25"
Contractor:Piedmont Industrial Field Rep:G. Babb
Sample
Number
Depth
Interval
Description Soil Sample Notes
A 0' - 2.5' Fill Material
B 2.5' - 5.0' Red fine sandy silty CLAY
C 5.0' - 9.0' Red fine sandy silty CLAY SS-1 @ 8'

D 9.0' - 16.0' Orange chlyey silty med. SAND PWR
Wet at 16'
E 16.0' - 25.0' Yellow clayey silty med. SAND SS-2 @ 18' PWR
F 25.0' - 27.0' Brown fine sandy silty CLAY SS-3 @ 25' PWR

G 27.0' - 30.0' Weathered granitic PWR with quartz PWR

Comments: PVC stickup 3.0'. Time of boring water level - 21.15' below top of casing.

APPENDIX B
102-A Woodwinds Industrial Court
Cary NC, 27511
919.467.3090 919.467.3515Phone:FAX:www.encolabs.com
Environmental Conservation Laboratories, Inc.
ENCO Workorder(s): CA13915
Raleigh, NC 27606
Unless otherwise noted in an attached project narrative, all samples were received in
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are in compliance with NELAC standards, except
as noted in the project narrative. This report shall not be reproduced except in full, without
the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
Enclosure(s)
Project Number: [none], Project Name/Desc: Kersey Valley Landfill- Well Inst,
Attn: Gary Babb
Babb & Associates (BA024)
3605 Country Cove Lane
Bill Scott
Project Manager
Wednesday, September 27, 2017
RE: Laboratory Results for
Dear Gary Babb,
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Thursday, September 7, 2017.
The total number of pages in this report, including this page is 25.
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SAMPLE SUMMARY/LABORATORY CHRONICLE
SS-1 CA13915-01 Sampled:09/05/17 09:30 Received:09/07/17 15:46Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 6010D 03/04/18 09/13/17 10:40 9/14/2017 15:30
EPA 6020B 03/04/18 09/20/17 14:02 9/22/2017 16:19
EPA 6020B 03/04/18 09/20/17 14:02 9/25/2017 13:40
SS-1 CA13915-01RE1 Sampled:09/05/17 09:30 Received:09/07/17 15:46Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 6020B 03/04/18 09/20/17 14:02 9/22/2017 17:14
SS-2 CA13915-02 Sampled:09/05/17 09:45 Received:09/07/17 15:46Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 6010D 03/04/18 09/13/17 10:40 9/14/2017 15:32
EPA 6020B 03/04/18 09/20/17 14:02 9/22/2017 16:25
EPA 6020B 03/04/18 09/20/17 14:02 9/25/2017 13:42
SS-2 CA13915-02RE1 Sampled:09/05/17 09:45 Received:09/07/17 15:46Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 6020B 03/04/18 09/20/17 14:02 9/22/2017 17:22
SS-3 CA13915-03 Sampled:09/05/17 10:00 Received:09/07/17 15:46Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 6010D 03/04/18 09/13/17 10:40 9/14/2017 15:35
EPA 6020B 03/04/18 09/20/17 14:02 9/22/2017 16:30
EPA 6020B 03/04/18 09/20/17 14:02 9/25/2017 13:45
SS-3 CA13915-03RE1 Sampled:09/05/17 10:00 Received:09/07/17 15:46Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 6020B 03/04/18 09/20/17 14:02 9/22/2017 17:27
4104-MW4Nbailer CA13915-04 Sampled:09/07/17 09:00 Received:09/07/17 15:46Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 6010D 03/06/18 09/11/17 13:22 9/12/2017 14:39
EPA 6020B 03/06/18 09/12/17 12:39 9/15/2017 12:34
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4104-MW4Nbailer(dissolved)CA13915-05 Sampled:09/07/17 09:00 Received:09/07/17 15:46Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 6010D 03/06/18 09/11/17 13:22 9/12/2017 15:11
EPA 6020B 03/06/18 09/12/17 12:39 9/15/2017 12:38
4104-MW4Npump CA13915-06 Sampled:09/07/17 10:15 Received:09/07/17 15:46Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 6010D 03/06/18 09/11/17 13:22 9/12/2017 15:13
EPA 6020B 03/06/18 09/12/17 12:39 9/15/2017 10:37
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NORTH CAROLINA SWS SAMPLE DETECTION SUMMARY
Analyte MethodUnitsResults
Lab ID:Client ID:SS-1 CA13915-01
Flag NotesMDLNC SWSLMRLDF
0.507 mg/kg dry EPA 6010DJ 100.6430.4121Arsenic - Total
83.8 mg/kg dry EPA 6010DJ 1000.6430.1291Barium - Total
3.65 mg/kg dry EPA 6010DJ 100.6430.1291Chromium - Total
1.99 mg/kg dry EPA 6010DJ 100.6430.1291Cobalt - Total
15.0 mg/kg dry EPA 6010D 100.6430.2441Copper - Total
4.55 mg/kg dry EPA 6010DJ 100.6430.1541Lead - Total
2.41 mg/kg dry EPA 6010DJ 503.220.4631Nickel - Total
0.209 mg/kg dry EPA 6010DJ 100.6430.1291Silver - Total
39.7 mg/kg dry EPA 6010D 250.6430.1291Vanadium - Total
12.0 mg/kg dry EPA 6010D 103.221.421Zinc - Total
Analyte MethodUnitsResults
Lab ID:Client ID:SS-2 CA13915-02
Flag NotesMDLNC SWSLMRLDF
2.62 mg/kg dry EPA 6010DJ 100.7290.4671Arsenic - Total
211 mg/kg dry EPA 6010D 1000.7290.1461Barium - Total
3.88 mg/kg dry EPA 6010DJ 100.7290.1461Chromium - Total
12.7 mg/kg dry EPA 6010D 100.7290.1461Cobalt - Total
53.2 mg/kg dry EPA 6010D 100.7290.2771Copper - Total
4.84 mg/kg dry EPA 6010DJ 100.7290.1751Lead - Total
4.34 mg/kg dry EPA 6010DJ 503.650.5251Nickel - Total
0.363 mg/kg dry EPA 6010DJ 100.7290.1461Silver - Total
66.9 mg/kg dry EPA 6010D 250.7290.1461Vanadium - Total
42.3 mg/kg dry EPA 6010D 103.651.601Zinc - Total
Analyte MethodUnitsResults
Lab ID:Client ID:SS-3 CA13915-03
Flag NotesMDLNC SWSLMRLDF
435 mg/kg dry EPA 6010D 1000.7130.1431Barium - Total
3.71 mg/kg dry EPA 6010DJ 100.7130.1431Chromium - Total
29.8 mg/kg dry EPA 6010D 100.7130.1431Cobalt - Total
59.1 mg/kg dry EPA 6010D 100.7130.2711Copper - Total
5.85 mg/kg dry EPA 6010DJ 100.7130.1711Lead - Total
11.0 mg/kg dry EPA 6010DJ 503.570.5141Nickel - Total
0.366 mg/kg dry EPA 6010DJ 100.7130.1431Silver - Total
0.0719 mg/kg dry EPA 6020BJ R-015.51.490.05521Thallium - Total
52.1 mg/kg dry EPA 6010D 250.7130.1431Vanadium - Total
45.9 mg/kg dry EPA 6010D 103.571.571Zinc - Total
Analyte MethodUnitsResults
Lab ID:Client ID:4104-MW4Nbailer CA13915-04
Flag NotesMDLNC SWSLMRLDF
38.2 ug/L EPA 6010DJ 10010.01.001Barium - Total
1.83 ug/L EPA 6010DJ 1010.01.401Chromium - Total
3.22 ug/L EPA 6010DJ 1010.01.601Copper - Total
0.305 ug/L EPA 6020BJ 5.51.000.1101Thallium - Total
2.05 ug/L EPA 6010DJ 2510.01.401Vanadium - Total
7.82 ug/L EPA 6010DJ 1010.04.401Zinc - Total
Analyte MethodUnitsResults
Lab ID:Client ID:4104-MW4Nbailer(dissolved)CA13915-05
Flag NotesMDLNC SWSLMRLDF
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Analyte MethodUnitsResults
Lab ID:Client ID:4104-MW4Nbailer(dissolved)CA13915-05
Flag NotesMDLNC SWSLMRLDF
30.1 ug/L EPA 6010DJ 10010.01.001Barium - Dissolved
1.70 ug/L EPA 6010DJ 1010.01.001Chromium - Dissolved
0.304 ug/L EPA 6020BJ 5.51.000.1101Thallium - Dissolved
4.95 ug/L EPA 6010DJ 1010.04.401Zinc - Dissolved
Analyte MethodUnitsResults
Lab ID:Client ID:4104-MW4Npump CA13915-06
Flag NotesMDLNC SWSLMRLDF
37.7 ug/L EPA 6010DJ 10010.01.001Barium - Total
1.62 ug/L EPA 6010DJ 1010.01.401Chromium - Total
0.220 ug/L EPA 6020BJ 5.51.000.1101Thallium - Total
1.83 ug/L EPA 6010DJ 2510.01.401Vanadium - Total
6.54 ug/L EPA 6010DJ 1010.04.401Zinc - Total
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ANALYTICAL RESULTS
SS-1Description:Lab Sample ID:CA13915-01 09/07/17 15:46Received:
Matrix:Soil Sampled:09/05/17 09:30 Work Order:CA13915
Kersey Valley Landfill- Well Inst,Project:Sampled By:Gary Babb % Solids: 77.7
Metals by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
mg/kg dry EPA 6010D 09/14/17 15:30Arsenic [7440-38-2] ^0.412 JMV0.6430.507 J 101
mg/kg dry EPA 6010D 09/14/17 15:30Barium [7440-39-3] ^0.129 JMV0.64383.8 J 1001
mg/kg dry EPA 6010D 09/14/17 15:30Beryllium [7440-41-7] ^0.0154 JMV0.06430.0154 U 11
mg/kg dry EPA 6010D 09/14/17 15:30Cadmium [7440-43-9] ^0.0124 JMV0.06430.0124 U 11
mg/kg dry EPA 6010D 09/14/17 15:30Chromium [7440-47-3] ^0.129 JMV0.6433.65 J 101
mg/kg dry EPA 6010D 09/14/17 15:30Cobalt [7440-48-4] ^0.129 JMV0.6431.99 J 101
mg/kg dry EPA 6010D 09/14/17 15:30Copper [7440-50-8] ^0.244 JMV0.64315.0 101
mg/kg dry EPA 6010D 09/14/17 15:30Lead [7439-92-1] ^0.154 JMV0.6434.55 J 101
mg/kg dry EPA 6010D 09/14/17 15:30Nickel [7440-02-0] ^0.463 JMV3.222.41 J 501
mg/kg dry EPA 6010D 09/14/17 15:30Silver [7440-22-4] ^0.129 JMV0.6430.209 J 101
mg/kg dry EPA 6010D 09/14/17 15:30Vanadium [7440-62-2] ^0.129 JMV0.64339.7 251
mg/kg dry EPA 6010D 09/14/17 15:30Zinc [7440-66-6] ^1.42 JMV3.2212.0 101
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SS-1Description:Lab Sample ID:CA13915-01 09/07/17 15:46Received:
Matrix:Soil Sampled:09/05/17 09:30 Work Order:CA13915
Kersey Valley Landfill- Well Inst,Project:Sampled By:Gary Babb % Solids: 77.7
Metals by EPA 6000/7000 Series Methods
^ - ENCO Orlando certified analyte [NC 424]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
mg/kg dry EPA 6020B 09/22/17 17:14Antimony [7440-36-0] ^0.373 JMA0.7460.373 U R-0161
mg/kg dry EPA 6020B 09/22/17 16:19Selenium [7782-49-2] ^1.36 JMA1.491.36 U R-01101
mg/kg dry EPA 6020B 09/25/17 13:40Thallium [7440-28-0] ^0.0552 JMA1.490.0552 U R-015.51
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
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SS-2Description:Lab Sample ID:CA13915-02 09/07/17 15:46Received:
Matrix:Soil Sampled:09/05/17 09:45 Work Order:CA13915
Kersey Valley Landfill- Well Inst,Project:Sampled By:Gary Babb % Solids: 68.5
Metals by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
mg/kg dry EPA 6010D 09/14/17 15:32Arsenic [7440-38-2] ^0.467 JMV0.7292.62 J 101
mg/kg dry EPA 6010D 09/14/17 15:32Barium [7440-39-3] ^0.146 JMV0.729211 1001
mg/kg dry EPA 6010D 09/14/17 15:32Beryllium [7440-41-7] ^0.0175 JMV0.07290.0175 U 11
mg/kg dry EPA 6010D 09/14/17 15:32Cadmium [7440-43-9] ^0.0140 JMV0.07290.0140 U 11
mg/kg dry EPA 6010D 09/14/17 15:32Chromium [7440-47-3] ^0.146 JMV0.7293.88 J 101
mg/kg dry EPA 6010D 09/14/17 15:32Cobalt [7440-48-4] ^0.146 JMV0.72912.7 101
mg/kg dry EPA 6010D 09/14/17 15:32Copper [7440-50-8] ^0.277 JMV0.72953.2 101
mg/kg dry EPA 6010D 09/14/17 15:32Lead [7439-92-1] ^0.175 JMV0.7294.84 J 101
mg/kg dry EPA 6010D 09/14/17 15:32Nickel [7440-02-0] ^0.525 JMV3.654.34 J 501
mg/kg dry EPA 6010D 09/14/17 15:32Silver [7440-22-4] ^0.146 JMV0.7290.363 J 101
mg/kg dry EPA 6010D 09/14/17 15:32Vanadium [7440-62-2] ^0.146 JMV0.72966.9 251
mg/kg dry EPA 6010D 09/14/17 15:32Zinc [7440-66-6] ^1.60 JMV3.6542.3 101
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SS-2Description:Lab Sample ID:CA13915-02 09/07/17 15:46Received:
Matrix:Soil Sampled:09/05/17 09:45 Work Order:CA13915
Kersey Valley Landfill- Well Inst,Project:Sampled By:Gary Babb % Solids: 68.5
Metals by EPA 6000/7000 Series Methods
^ - ENCO Orlando certified analyte [NC 424]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
mg/kg dry EPA 6020B 09/22/17 17:22Antimony [7440-36-0] ^0.477 JMA0.9540.477 U R-0161
mg/kg dry EPA 6020B 09/22/17 16:25Selenium [7782-49-2] ^1.74 JMA1.911.74 U R-01101
mg/kg dry EPA 6020B 09/25/17 13:42Thallium [7440-28-0] ^0.0706 JMA1.910.0706 U R-015.51
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
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SS-3Description:Lab Sample ID:CA13915-03 09/07/17 15:46Received:
Matrix:Soil Sampled:09/05/17 10:00 Work Order:CA13915
Kersey Valley Landfill- Well Inst,Project:Sampled By:Gary Babb % Solids: 70.1
Metals by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
mg/kg dry EPA 6010D 09/14/17 15:35Arsenic [7440-38-2] ^0.457 JMV0.7130.457 U 101
mg/kg dry EPA 6010D 09/14/17 15:35Barium [7440-39-3] ^0.143 JMV0.713435 1001
mg/kg dry EPA 6010D 09/14/17 15:35Beryllium [7440-41-7] ^0.0171 JMV0.07130.0171 U 11
mg/kg dry EPA 6010D 09/14/17 15:35Cadmium [7440-43-9] ^0.0137 JMV0.07130.0137 U 11
mg/kg dry EPA 6010D 09/14/17 15:35Chromium [7440-47-3] ^0.143 JMV0.7133.71 J 101
mg/kg dry EPA 6010D 09/14/17 15:35Cobalt [7440-48-4] ^0.143 JMV0.71329.8 101
mg/kg dry EPA 6010D 09/14/17 15:35Copper [7440-50-8] ^0.271 JMV0.71359.1 101
mg/kg dry EPA 6010D 09/14/17 15:35Lead [7439-92-1] ^0.171 JMV0.7135.85 J 101
mg/kg dry EPA 6010D 09/14/17 15:35Nickel [7440-02-0] ^0.514 JMV3.5711.0 J 501
mg/kg dry EPA 6010D 09/14/17 15:35Silver [7440-22-4] ^0.143 JMV0.7130.366 J 101
mg/kg dry EPA 6010D 09/14/17 15:35Vanadium [7440-62-2] ^0.143 JMV0.71352.1 251
mg/kg dry EPA 6010D 09/14/17 15:35Zinc [7440-66-6] ^1.57 JMV3.5745.9 101
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SS-3Description:Lab Sample ID:CA13915-03 09/07/17 15:46Received:
Matrix:Soil Sampled:09/05/17 10:00 Work Order:CA13915
Kersey Valley Landfill- Well Inst,Project:Sampled By:Gary Babb % Solids: 70.1
Metals by EPA 6000/7000 Series Methods
^ - ENCO Orlando certified analyte [NC 424]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
mg/kg dry EPA 6020B 09/22/17 17:27Antimony [7440-36-0] ^0.373 JMA0.7450.373 U R-0161
mg/kg dry EPA 6020B 09/22/17 16:30Selenium [7782-49-2] ^1.36 JMA1.491.36 U R-01101
mg/kg dry EPA 6020B 09/25/17 13:45Thallium [7440-28-0] ^0.0552 JMA1.490.0719 J R-015.51
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
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4104-MW4NbailerDescription:Lab Sample ID:CA13915-04 09/07/17 15:46Received:
Matrix:Water Sampled:09/07/17 09:00 Work Order:CA13915
Kersey Valley Landfill- Well Inst,Project:Sampled By:Gary Babb
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
ug/L EPA 6020B 09/15/17 12:34Antimony [7440-36-0] ^0.370 JDH2.000.370 U 61
ug/L EPA 6010D 09/12/17 14:39Arsenic [7440-38-2] ^6.80 JMV10.06.80 U 101
ug/L EPA 6010D 09/12/17 14:39Barium [7440-39-3] ^1.00 JMV10.038.2 J 1001
ug/L EPA 6010D 09/12/17 14:39Beryllium [7440-41-7] ^0.130 JMV1.000.130 U 11
ug/L EPA 6010D 09/12/17 14:39Cadmium [7440-43-9] ^0.360 JMV1.000.360 U 11
ug/L EPA 6010D 09/12/17 14:39Chromium [7440-47-3] ^1.40 JMV10.01.83 J 101
ug/L EPA 6010D 09/12/17 14:39Cobalt [7440-48-4] ^1.10 JMV10.01.10 U 101
ug/L EPA 6010D 09/12/17 14:39Copper [7440-50-8] ^1.60 JMV10.03.22 J 101
ug/L EPA 6010D 09/12/17 14:39Lead [7439-92-1] ^3.10 JMV10.03.10 U 101
ug/L EPA 6010D 09/12/17 14:39Nickel [7440-02-0] ^2.20 JMV10.02.20 U 501
ug/L EPA 6020B 09/15/17 12:34Selenium [7782-49-2] ^0.910 JDH3.000.910 U 101
ug/L EPA 6010D 09/12/17 14:39Silver [7440-22-4] ^1.90 JMV10.01.90 U 101
ug/L EPA 6020B 09/15/17 12:34Thallium [7440-28-0] ^0.110 JDH1.000.305 J 5.51
ug/L EPA 6010D 09/12/17 14:39Vanadium [7440-62-2] ^1.40 JMV10.02.05 J 251
ug/L EPA 6010D 09/12/17 14:39Zinc [7440-66-6] ^4.40 JMV10.07.82 J 101
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
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4104-MW4Nbailer(dissolved)Description:Lab Sample ID:CA13915-05 09/07/17 15:46Received:
Matrix:Water Sampled:09/07/17 09:00 Work Order:CA13915
Kersey Valley Landfill- Well Inst,Project:Sampled By:Gary Babb
Metals (Dissolved) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
ug/L EPA 6020B 09/15/17 12:38Antimony [7440-36-0] ^0.370 JDH2.000.370 U 61
ug/L EPA 6010D 09/12/17 15:11Arsenic [7440-38-2] ^6.80 JMV10.06.80 U 101
ug/L EPA 6010D 09/12/17 15:11Barium [7440-39-3] ^1.00 JMV10.030.1 J 1001
ug/L EPA 6010D 09/12/17 15:11Beryllium [7440-41-7] ^0.130 JMV1.000.130 U 11
ug/L EPA 6010D 09/12/17 15:11Cadmium [7440-43-9] ^0.360 JMV1.000.360 U 11
ug/L EPA 6010D 09/12/17 15:11Chromium [7440-47-3] ^1.00 JMV10.01.70 J 101
ug/L EPA 6010D 09/12/17 15:11Cobalt [7440-48-4] ^1.10 JMV10.01.10 U 101
ug/L EPA 6010D 09/12/17 15:11Copper [7440-50-8] ^1.60 JMV10.01.60 U 101
ug/L EPA 6010D 09/12/17 15:11Lead [7439-92-1] ^3.10 JMV10.03.10 U 101
ug/L EPA 6010D 09/12/17 15:11Nickel [7440-02-0] ^2.20 JMV10.02.20 U 501
ug/L EPA 6020B 09/15/17 12:38Selenium [7782-49-2] ^0.910 JDH3.000.910 U 101
ug/L EPA 6010D 09/12/17 15:11Silver [7440-22-4] ^5.00 JMV10.05.00 U 101
ug/L EPA 6020B 09/15/17 12:38Thallium [7440-28-0] ^0.110 JDH1.000.304 J 5.51
ug/L EPA 6010D 09/12/17 15:11Vanadium [7440-62-2] ^1.40 JMV10.01.40 U 251
ug/L EPA 6010D 09/12/17 15:11Zinc [7440-66-6] ^4.40 JMV10.04.95 J 101
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
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4104-MW4NpumpDescription:Lab Sample ID:CA13915-06 09/07/17 15:46Received:
Matrix:Water Sampled:09/07/17 10:15 Work Order:CA13915
Kersey Valley Landfill- Well Inst,Project:Sampled By:Gary Babb
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
ug/L EPA 6020B 09/15/17 10:37Antimony [7440-36-0] ^0.370 JDH2.000.370 U 61
ug/L EPA 6010D 09/12/17 15:13Arsenic [7440-38-2] ^6.80 JMV10.06.80 U 101
ug/L EPA 6010D 09/12/17 15:13Barium [7440-39-3] ^1.00 JMV10.037.7 J 1001
ug/L EPA 6010D 09/12/17 15:13Beryllium [7440-41-7] ^0.130 JMV1.000.130 U 11
ug/L EPA 6010D 09/12/17 15:13Cadmium [7440-43-9] ^0.360 JMV1.000.360 U 11
ug/L EPA 6010D 09/12/17 15:13Chromium [7440-47-3] ^1.40 JMV10.01.62 J 101
ug/L EPA 6010D 09/12/17 15:13Cobalt [7440-48-4] ^1.10 JMV10.01.10 U 101
ug/L EPA 6010D 09/12/17 15:13Copper [7440-50-8] ^1.60 JMV10.01.60 U 101
ug/L EPA 6010D 09/12/17 15:13Lead [7439-92-1] ^3.10 JMV10.03.10 U 101
ug/L EPA 6010D 09/12/17 15:13Nickel [7440-02-0] ^2.20 JMV10.02.20 U 501
ug/L EPA 6020B 09/15/17 10:37Selenium [7782-49-2] ^0.910 JDH3.000.910 U 101
ug/L EPA 6010D 09/12/17 15:13Silver [7440-22-4] ^1.90 JMV10.01.90 U 101
ug/L EPA 6020B 09/15/17 10:37Thallium [7440-28-0] ^0.110 JDH1.000.220 J 5.51
ug/L EPA 6010D 09/12/17 15:13Vanadium [7440-62-2] ^1.40 JMV10.01.83 J 251
ug/L EPA 6010D 09/12/17 15:13Zinc [7440-66-6] ^4.40 JMV10.06.54 J 101
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
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QUALITY CONTROL
Metals by EPA 6000/7000 Series Methods - Quality Control
Batch 7I13018 - EPA 3050B
Prepared: 09/13/2017 10:40 Analyzed: 09/14/2017 14:36Blank (7I13018-BLK1)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/kg wet0.5000.320 U Arsenic
mg/kg wet0.5000.100 U Barium
mg/kg wet0.05000.0120 U Beryllium
mg/kg wet0.05000.00960 U Cadmium
mg/kg wet0.5000.100 U Chromium
mg/kg wet0.5000.100 U Cobalt
mg/kg wet0.5000.190 U Copper
mg/kg wet0.5000.120 U Lead
mg/kg wet2.500.360 U Nickel
mg/kg wet0.5000.100 U Silver
mg/kg wet0.5000.100 U Vanadium
mg/kg wet2.501.10 U Zinc
Prepared: 09/13/2017 10:40 Analyzed: 09/14/2017 15:16LCS (7I13018-BS1)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/kg wet0.500 10.0 80-120959.51 Arsenic
mg/kg wet0.500 10.0 80-120949.42 Barium
mg/kg wet0.0500 1.00 80-120910.912 Beryllium
mg/kg wet0.0500 1.00 80-120930.930 Cadmium
mg/kg wet0.500 10.0 80-120969.57 Chromium
mg/kg wet0.500 10.0 80-120969.59 Cobalt
mg/kg wet0.500 10.0 80-120959.48 Copper
mg/kg wet0.500 10.0 80-120959.45 Lead
mg/kg wet2.50 10.0 80-120949.44 Nickel
mg/kg wet0.500 10.0 80-1201009.99 Silver
mg/kg wet0.500 10.0 80-1201009.96 Vanadium
mg/kg wet2.50 10.0 80-120919.15 Zinc
Prepared: 09/13/2017 10:40 Analyzed: 09/14/2017 14:44Matrix Spike (7I13018-MS1)
Source: CA12996-01
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/kg dry0.502 9.94 75-125820.8809.05 Arsenic
mg/kg dry0.502 9.94 75-125890.5219.37 Barium
mg/kg dry0.0502 0.994 75-125800.0120 U0.795 Beryllium
mg/kg dry0.0502 0.994 75-125760.00964 U0.753 Cadmium
mg/kg dry0.502 9.94 75-125988.5918.3 Chromium
mg/kg dry0.502 9.94 75-125850.100 U8.46 Cobalt
mg/kg dry0.502 9.94 75-125850.191 U8.46 Copper
mg/kg dry0.502 9.94 75-125921.9411.1 Lead
mg/kg dry2.51 9.94 75-125850.361 U8.48 Nickel
mg/kg dry0.502 9.94 75-125880.1978.91 Silver
mg/kg dry0.502 9.94 75-12511117.628.7 Vanadium
mg/kg dry2.51 9.94 75-125841.10 U8.35 Zinc
Prepared: 09/13/2017 10:40 Analyzed: 09/14/2017 14:47Matrix Spike Dup (7I13018-MSD1)
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QUALITY CONTROL
Metals by EPA 6000/7000 Series Methods - Quality Control
Batch 7I13018 - EPA 3050B
Prepared: 09/13/2017 10:40 Analyzed: 09/14/2017 14:47Matrix Spike Dup (7I13018-MSD1) Continued
Source: CA12996-01
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/kg dry0.502 10.0 2075-12585 40.8809.40 Arsenic
mg/kg dry0.502 10.0 2075-12594 60.5219.93 Barium
mg/kg dry0.0502 1.00 2075-12584 60.0120 U0.845 Beryllium
mg/kg dry0.0502 1.00 2075-12581 80.00964 U0.815 Cadmium
mg/kg dry0.502 10.0 2075-125101 28.5918.8 Chromium
mg/kg dry0.502 10.0 2075-12590 70.100 U9.05 Cobalt
mg/kg dry0.502 10.0 2075-12592 80.191 U9.19 Copper
mg/kg dry0.502 10.0 2075-12596 51.9411.6 Lead
mg/kg dry2.51 10.0 2075-12591 70.361 U9.14 Nickel
mg/kg dry0.502 10.0 2075-12593 60.1979.51 Silver
mg/kg dry0.502 10.0 2075-125106 217.628.2 Vanadium
mg/kg dry2.51 10.0 2075-12589 71.10 U8.93 Zinc
Prepared: 09/13/2017 10:40 Analyzed: 09/14/2017 14:50Post Spike (7I13018-PS1)
Source: CA12996-01
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/L0.0100 0.200 80-1201020.01750.222 Arsenic
mg/L0.0100 0.200 80-120990.01040.208 Barium
mg/L0.00100 0.0200 80-12093-0.0006020.0185 Beryllium
mg/L0.00100 0.0200 80-12092-0.001200.0184 Cadmium
mg/L0.0100 0.200 80-1201020.1710.374 Chromium
mg/L0.0100 0.200 80-1201010.0008950.203 Cobalt
mg/L0.0100 0.200 80-120990.003670.203 Copper
mg/L0.0100 0.200 80-1201000.03870.238 Lead
mg/L0.0500 0.200 80-1201000.001120.202 Nickel
mg/L0.0100 0.200 80-120970.003930.198 Silver
mg/L0.0100 0.200 80-1201080.3500.567 Vanadium
mg/L0.0500 0.200 80-120960.001240.194 Zinc
Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control
Batch 7I11030 - EPA 3005A
Prepared: 09/11/2017 13:22 Analyzed: 09/12/2017 14:30Blank (7I11030-BLK1)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L10.06.80 U Arsenic
ug/L10.01.00 U Barium
ug/L1.000.130 U Beryllium
ug/L1.000.360 U Cadmium
ug/L10.01.40 U Chromium
ug/L10.01.10 U Cobalt
ug/L10.01.60 U Copper
ug/L10.03.10 U Lead
ug/L10.02.20 U Nickel
ug/L10.01.90 U Silver
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QUALITY CONTROL
Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control
Batch 7I11030 - EPA 3005A
Prepared: 09/11/2017 13:22 Analyzed: 09/12/2017 14:30Blank (7I11030-BLK1) Continued
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L10.01.40 U Vanadium
ug/L10.04.40 U Zinc
Prepared: 09/11/2017 13:22 Analyzed: 09/12/2017 14:33Blank (7I11030-BLK2)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L10.06.80 U Arsenic
ug/L10.01.00 U Barium
ug/L1.000.130 U Beryllium
ug/L1.000.360 U Cadmium
ug/L10.01.40 U Chromium
ug/L10.01.10 U Cobalt
ug/L10.01.60 U Copper
ug/L10.03.10 U Lead
ug/L10.02.20 U Nickel
ug/L10.01.90 U Silver
ug/L10.01.40 U Vanadium
ug/L10.04.40 U Zinc
Prepared: 09/11/2017 13:22 Analyzed: 09/12/2017 14:36LCS (7I11030-BS1)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L10.0 200 80-120107215 Arsenic
ug/L10.0 200 80-120105211 Barium
ug/L1.00 20.0 80-12010220.4 Beryllium
ug/L1.00 20.0 80-12010320.7 Cadmium
ug/L10.0 200 80-120107214 Chromium
ug/L10.0 200 80-120105210 Cobalt
ug/L10.0 200 80-120105211 Copper
ug/L10.0 200 80-120106212 Lead
ug/L10.0 200 80-120105209 Nickel
ug/L10.0 200 80-120111223 Silver
ug/L10.0 200 80-120110220 Vanadium
ug/L10.0 200 80-120104208 Zinc
Prepared: 09/11/2017 13:22 Analyzed: 09/12/2017 14:42Matrix Spike (7I11030-MS1)
Source: CA13915-04
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L10.0 200 75-1251036.80 U205 Arsenic
ug/L10.0 200 75-12510138.2239 Barium
ug/L1.00 20.0 75-1251010.130 U20.1 Beryllium
ug/L1.00 20.0 75-125980.360 U19.7 Cadmium
ug/L10.0 200 75-1251031.83207 Chromium
ug/L10.0 200 75-1251031.10 U206 Cobalt
ug/L10.0 200 75-1251023.22206 Copper
ug/L10.0 200 75-1251053.10 U210 Lead
ug/L10.0 200 75-1251002.20 U201 Nickel
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QUALITY CONTROL
Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control
Batch 7I11030 - EPA 3005A
Prepared: 09/11/2017 13:22 Analyzed: 09/12/2017 14:42Matrix Spike (7I11030-MS1) Continued
Source: CA13915-04
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L10.0 200 75-1251071.90 U214 Silver
ug/L10.0 200 75-1251062.05214 Vanadium
ug/L10.0 200 75-125997.82206 Zinc
Prepared: 09/11/2017 13:22 Analyzed: 09/12/2017 14:44Matrix Spike Dup (7I11030-MSD1)
Source: CA13915-04
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L10.0 200 2075-125106 46.80 U213 Arsenic
ug/L10.0 200 2075-125103 238.2244 Barium
ug/L1.00 20.0 2075-125102 10.130 U20.3 Beryllium
ug/L1.00 20.0 2075-125101 20.360 U20.1 Cadmium
ug/L10.0 200 2075-125105 21.83211 Chromium
ug/L10.0 200 2075-125104 11.10 U208 Cobalt
ug/L10.0 200 2075-125103 13.22209 Copper
ug/L10.0 200 2075-125106 0.93.10 U212 Lead
ug/L10.0 200 2075-125104 42.20 U209 Nickel
ug/L10.0 200 2075-125109 21.90 U217 Silver
ug/L10.0 200 2075-125108 22.05219 Vanadium
ug/L10.0 200 2075-125101 27.82210 Zinc
Prepared: 09/11/2017 13:22 Analyzed: 09/12/2017 14:47Post Spike (7I11030-PS1)
Source: CA13915-04
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/L0.0100 0.200 80-120105-0.001940.209 Arsenic
mg/L0.0100 0.200 80-1201020.03820.242 Barium
mg/L0.00100 0.0200 80-120101-0.0002560.0202 Beryllium
mg/L0.00100 0.0200 80-120100-4.52E-50.0199 Cadmium
mg/L0.0100 0.200 80-1201040.001830.211 Chromium
mg/L0.0100 0.200 80-1201030.0003480.206 Cobalt
mg/L0.0100 0.200 80-1201020.003220.207 Copper
mg/L0.0100 0.200 80-120105-9.94E-50.210 Lead
mg/L0.0100 0.200 80-1201019.82E-50.202 Nickel
mg/L0.0100 0.200 80-1201010.0003950.202 Silver
mg/L0.0100 0.200 80-1201080.002050.218 Vanadium
mg/L0.0100 0.200 80-1201000.007820.208 Zinc
Batch 7I12020 - EPA 3005A
Prepared: 09/12/2017 12:39 Analyzed: 09/15/2017 10:29Blank (7I12020-BLK1)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L2.000.370 U Antimony
ug/L3.000.910 U Selenium
ug/L1.000.110 U Thallium
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QUALITY CONTROL
Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control
Batch 7I12020 - EPA 3005A
Prepared: 09/12/2017 12:39 Analyzed: 09/15/2017 10:41LCS (7I12020-BS1)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L2.00 200 80-120105210 Antimony
ug/L3.00 200 80-120103207 Selenium
ug/L1.00 200 80-120100200 Thallium
Prepared: 09/12/2017 12:39 Analyzed: 09/15/2017 10:45Matrix Spike (7I12020-MS1)
Source: CA13915-06
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L2.00 200 75-125990.370 U197 Antimony
ug/L3.00 200 75-1251030.910 U206 Selenium
ug/L1.00 200 75-125960.220191 Thallium
Prepared: 09/12/2017 12:39 Analyzed: 09/15/2017 10:49Matrix Spike Dup (7I12020-MSD1)
Source: CA13915-06
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L2.00 200 2075-125103 40.370 U205 Antimony
ug/L3.00 200 2075-125103 0.40.910 U205 Selenium
ug/L1.00 200 2075-12598 20.220195 Thallium
Prepared: 09/12/2017 12:39 Analyzed: 09/15/2017 10:53Post Spike (7I12020-PS1)
Source: CA13915-06
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L2.00 200 80-1201020.0143204 Antimony
ug/L3.00 200 80-1201030.0842205 Selenium
ug/L1.00 200 75-125990.220198 Thallium
Metals (Dissolved) by EPA 6000/7000 Series Methods - Quality Control
Batch 7I11030 - EPA 3005A
Prepared: 09/11/2017 13:22 Analyzed: 09/12/2017 14:30Blank (7I11030-BLK1)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L10.06.80 U Arsenic
ug/L10.01.00 U Barium
ug/L1.000.130 U Beryllium
ug/L1.000.360 U Cadmium
ug/L10.01.00 U Chromium
ug/L10.01.10 U Cobalt
ug/L10.01.60 U Copper
ug/L10.03.10 U Lead
ug/L10.02.20 U Nickel
ug/L10.05.00 U Silver
ug/L10.01.40 U Vanadium
ug/L10.04.40 U Zinc
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QUALITY CONTROL
Metals (Dissolved) by EPA 6000/7000 Series Methods - Quality Control
Batch 7I11030 - EPA 3005A
Prepared: 09/11/2017 13:22 Analyzed: 09/12/2017 14:33Blank (7I11030-BLK2)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L10.06.80 U Arsenic
ug/L10.01.00 U Barium
ug/L1.000.130 U Beryllium
ug/L1.000.360 U Cadmium
ug/L10.01.00 U Chromium
ug/L10.01.10 U Cobalt
ug/L10.01.60 U Copper
ug/L10.03.10 U Lead
ug/L10.02.20 U Nickel
ug/L10.05.00 U Silver
ug/L10.01.40 U Vanadium
ug/L10.04.40 U Zinc
Prepared: 09/11/2017 13:22 Analyzed: 09/12/2017 14:36LCS (7I11030-BS1)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L10.0 200 80-120107215 Arsenic
ug/L10.0 200 80-120105211 Barium
ug/L1.00 20.0 80-12010220.4 Beryllium
ug/L1.00 20.0 80-12010320.7 Cadmium
ug/L10.0 200 80-120107214 Chromium
ug/L10.0 200 80-120105210 Cobalt
ug/L10.0 200 80-120105211 Copper
ug/L10.0 200 80-120106212 Lead
ug/L10.0 200 80-120105209 Nickel
ug/L10.0 200 80-120111223 Silver
ug/L10.0 200 80-120110220 Vanadium
ug/L10.0 200 80-120104208 Zinc
Prepared: 09/11/2017 13:22 Analyzed: 09/12/2017 14:42Matrix Spike (7I11030-MS1)
Source: CA13915-04
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L10.0 200 75-1251036.80 U205 Arsenic
ug/L10.0 200 75-12510138.2239 Barium
ug/L1.00 20.0 75-1251010.130 U20.1 Beryllium
ug/L1.00 20.0 75-125980.360 U19.7 Cadmium
ug/L10.0 200 75-1251031.83207 Chromium
ug/L10.0 200 75-1251031.10 U206 Cobalt
ug/L10.0 200 75-1251023.22206 Copper
ug/L10.0 200 75-1251053.10 U210 Lead
ug/L10.0 200 75-1251002.20 U201 Nickel
ug/L10.0 200 75-1251075.00 U214 Silver
ug/L10.0 200 75-1251062.05214 Vanadium
ug/L10.0 200 75-125997.82206 Zinc
Prepared: 09/11/2017 13:22 Analyzed: 09/12/2017 14:44Matrix Spike Dup (7I11030-MSD1)
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QUALITY CONTROL
Metals (Dissolved) by EPA 6000/7000 Series Methods - Quality Control
Batch 7I11030 - EPA 3005A
Prepared: 09/11/2017 13:22 Analyzed: 09/12/2017 14:44Matrix Spike Dup (7I11030-MSD1) Continued
Source: CA13915-04
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L10.0 200 2075-125106 46.80 U213 Arsenic
ug/L10.0 200 2075-125103 238.2244 Barium
ug/L1.00 20.0 2075-125102 10.130 U20.3 Beryllium
ug/L1.00 20.0 2075-125101 20.360 U20.1 Cadmium
ug/L10.0 200 2075-125105 21.83211 Chromium
ug/L10.0 200 2075-125104 11.10 U208 Cobalt
ug/L10.0 200 2075-125103 13.22209 Copper
ug/L10.0 200 2075-125106 0.93.10 U212 Lead
ug/L10.0 200 2075-125104 42.20 U209 Nickel
ug/L10.0 200 2075-125109 25.00 U217 Silver
ug/L10.0 200 2075-125108 22.05219 Vanadium
ug/L10.0 200 2075-125101 27.82210 Zinc
Prepared: 09/11/2017 13:22 Analyzed: 09/12/2017 14:47Post Spike (7I11030-PS1)
Source: CA13915-04
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/L0.0100 0.200 80-120105-0.001940.209 Arsenic
mg/L0.0100 0.200 80-1201020.03820.242 Barium
mg/L0.00100 0.0200 80-120101-0.0002560.0202 Beryllium
mg/L0.00100 0.0200 80-120100-4.52E-50.0199 Cadmium
mg/L0.0100 0.200 80-1201040.001830.211 Chromium
mg/L0.0100 0.200 80-1201030.0003480.206 Cobalt
mg/L0.0100 0.200 80-1201020.003220.207 Copper
mg/L0.0100 0.200 80-120105-9.94E-50.210 Lead
mg/L0.0100 0.200 80-1201019.82E-50.202 Nickel
mg/L0.0100 0.200 80-1201010.0003950.202 Silver
mg/L0.0100 0.200 80-1201080.002050.218 Vanadium
mg/L0.0100 0.200 80-1201000.007820.208 Zinc
Batch 7I12020 - EPA 3005A
Prepared: 09/12/2017 12:39 Analyzed: 09/15/2017 10:33Blank (7I12020-BLK2)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L2.000.370 U Antimony
ug/L3.000.910 U Selenium
ug/L1.000.110 U Thallium
Prepared: 09/12/2017 12:39 Analyzed: 09/15/2017 10:41LCS (7I12020-BS1)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L2.00 200 80-120105210 Antimony
ug/L3.00 200 80-120103207 Selenium
ug/L1.00 200 80-120100200 Thallium
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QUALITY CONTROL
Metals (Dissolved) by EPA 6000/7000 Series Methods - Quality Control
Batch 7I12020 - EPA 3005A
Prepared: 09/12/2017 12:39 Analyzed: 09/15/2017 10:45Matrix Spike (7I12020-MS1)
Source: CA13915-06
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L2.00 200 75-125990.370 U197 Antimony
ug/L3.00 200 75-1251030.910 U206 Selenium
ug/L1.00 200 75-125960.220191 Thallium
Prepared: 09/12/2017 12:39 Analyzed: 09/15/2017 10:49Matrix Spike Dup (7I12020-MSD1)
Source: CA13915-06
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L2.00 200 2075-125103 40.370 U205 Antimony
ug/L3.00 200 2075-125103 0.40.910 U205 Selenium
ug/L1.00 200 2075-12598 20.220195 Thallium
Prepared: 09/12/2017 12:39 Analyzed: 09/15/2017 10:53Post Spike (7I12020-PS1)
Source: CA13915-06
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L2.00 200 80-1201020.0143204 Antimony
ug/L3.00 200 80-1201030.0842205 Selenium
ug/L1.00 200 80-120990.220198 Thallium
QUALITY CONTROL
Metals by EPA 6000/7000 Series Methods - Quality Control
Batch 7I19035 - EPA 3050B
Prepared: 09/20/2017 14:02 Analyzed: 09/22/2017 14:00Blank (7I19035-BLK2)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/kg wet0.5000.250 U Antimony
mg/kg wet1.000.910 U Selenium
Prepared: 09/20/2017 14:02 Analyzed: 09/25/2017 12:44Blank (7I19035-BLK3)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/kg wet1.000.0370 U Thallium
Prepared: 09/20/2017 14:02 Analyzed: 09/22/2017 14:03LCS (7I19035-BS2)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/kg wet0.500 5.00 80-1201004.99 Antimony
mg/kg wet1.00 50.0 80-1209848.9 Selenium
Prepared: 09/20/2017 14:02 Analyzed: 09/25/2017 12:46LCS (7I19035-BS3)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/kg wet1.00 5.00 80-1201045.22 Thallium
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QUALITY CONTROL
Metals by EPA 6000/7000 Series Methods - Quality Control
Batch 7I19035 - EPA 3050B
Prepared: 09/20/2017 14:02 Analyzed: 09/22/2017 14:09Matrix Spike (7I19035-MS2)
Source: AA06605-02
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/kg dry6.37 6.30 75-1253.18 U3.18 UD QM-07Antimony
mg/kg dry12.7 63.0 75-1256011.6 U37.7 D QM-07Selenium
Prepared: 09/20/2017 14:02 Analyzed: 09/25/2017 12:48Matrix Spike (7I19035-MS3)
Source: AA06605-02
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/kg dry12.7 6.30 75-125990.471 U6.23 JD Thallium
Prepared: 09/20/2017 14:02 Analyzed: 09/22/2017 14:12Matrix Spike Dup (7I19035-MSD2)
Source: AA06605-02
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/kg dry6.37 6.37 2075-1253.18 U3.18 UD QM-07Antimony
mg/kg dry12.7 63.7 2075-12571 1811.6 U45.1 D QM-07Selenium
Prepared: 09/20/2017 14:02 Analyzed: 09/25/2017 12:49Matrix Spike Dup (7I19035-MSD3)
Source: AA06605-02
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/kg dry12.7 6.37 2075-125104 70.471 U6.65 JD Thallium
Prepared: 09/22/2017 08:00 Analyzed: 09/22/2017 14:17Post Spike (7I19035-PS2)
Source: AA06605-02
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L0.500 4.90 75-12594-0.02874.60 Antimony
ug/L1.00 49.0 75-125101-0.16949.3 Selenium
Prepared: 09/25/2017 10:00 Analyzed: 09/25/2017 12:52Post Spike (7I19035-PS3)
Source: AA06605-02
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L1.00 4.90 75-1251040.01925.13 Thallium
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FLAGS/NOTES AND DEFINITIONS
The sample was analyzed at dilution.
The analyte was detected in the associated method blank.
The reported value is between the laboratory method detection limit (MDL) and the laboratory method
reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable.
The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
The concentration indicated for this analyte is an estimated value above the calibration range of the
instrument. This value is considered an estimate.
Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution
factor, and, in the case of soil samples, moisture content.
MRL
E
U
J
D
B
PQL: Practical Quantitation Limit.PQL
The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was
accepted based on acceptable LCS recovery.
QM-07
The Reporting Limit for this analyte has been raised to account for matrix interference.R-01
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