0803_EastCarolina_20170509_GWMonReport_DINxxxxx

PREPARED FOR:
REPUBLIC SERVICES OF NORTH CAROLINA, LLC
D.B.A. EAST CAROLINA ENVIRONMENTAL
1922 REPUBLICAN ROAD
AULANDER, NORTH CAROLINA 27805

EAST CAROLINA REGIONAL LANDFILL
PERMIT NO. 08-03

FIRST SEMIANNUAL WATER QUALITY
MONITORING REPORT OF 2017

MAY 2017

PREPARED BY:

2211 WEST MEADOWVIEW ROAD, SUITE 101
GREENSBORO, NORTH CAROLINA 27407
NC LICENSE NUMBER C-0782
PHONE: [phone]
FAX: [phone]
JOYCE ENGINEERING PROJECT NO. 00894.1701.12

_______________________________________________________________________
First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
East Carolina Regional Landfill, Permit No. 08-03 May 2017

i

EXECUTIVE SUMMARY

This report presents the results of the first semiannual 2017 water quality monitoring event
conducted at the East Carolina Regional Landfill on January 25, 2017. Samples were collected
by representatives of Joyce Engineering from groundwater monitoring wells, surface water
monitoring points, and the leachate collection system on January 25, 2017. The complete
analytical results from the first semiannual 2017 monitoring event, and April 5, 2017, resampling
event, have been reported by Pace Analytical Services, LLC, of Norcross, Georgia laboratory
certification number 381.

Eight inorganic constituents (barium, beryllium, chromium, cobalt, copper, lead, silver and zinc)
were detected in samples from one or more groundwater or surface water monitoring points at
concentrations above their respective Solid Waste Section (SWS) Reporting Limits (SWSLs)
 Barium was detected above the SWSL in GW-2, GW-8, GW-9, GW-10, GW-13, GW-15,
GW-17, and GW-18.
 Chromium was detected above the SWSL in GW-17;
 Beryllium was detected above the SWSL in GW-2 and GW-7.
 Cobalt and silver were detected in GW-7 above the SWSL.
 Zinc was detected above the SWSL in GW-2, GW-7, GW-9, GW-13, GW-17, and GW-
18.
 Barium and Copper were detected above the SWSL in SW-2.

No other inorganic or organic constituents were detected above their respective SWSLs in
monitoring wells or surface water monitoring points during the January 2017 sampling event.

Three inorganic constituent (chromium, cobalt, and silver) were detected at a concentration
above their respective 15A NCAC 2L.0202 Groundwater Protection Standards (NC2L) or SWS
Groundwater Protection Standard (GWPS).

 Cobalt was detected above its GWPS in GW-7 at 29.8 µg/L, and
 Silver was detected above its NC2L in GW-7 at 52.9 µg/L. The resample result was
estimated at 0.81 µg/L, below the NC2L (see below).

Chromium was also initially reported at 11.1 µg/L in GW-17, which exceeded its NC2L. Upon
review of the initial reported inorganic concentrations, the laboratory was requested to confirm
the results for cobalt and silver in GW-7 and chromium in GW-17 and to run dissolved metal
samples collected during sampling in order to confirm each exceedance of the NC2L or GWPS.
Chromium was re-run and reported at 10.0 µg/L in GW-17, which did not confirm the initial
exceedance of the NC2L. Cobalt and Silver re-run analysis confirmed the exceedances in GW-7.
The Cobalt detections in GW-7 are historically consistent; however the silver detection above the
NC2L was not historically consistent. Therefore, a verification sample for silver was collected

_______________________________________________________________________
First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
East Carolina Regional Landfill, Permit No. 08-03 May 2017

ii

from GW-7 on April 5, 2017, and included in this report. The verification results did not confirm
the initial NC2L exceedance for silver in GW-7.

Cobalt was detected above the GWPS in GW-7; however, this is consistent with historical data
for GW-7. The cobalt detection was not a statistically significant increase (SSI) above
background; therefore, we request that the background 50.0 µg/L be considered the Groundwater
Protection Standard (GPS) for cobalt in GW-7 in accordance with 15A NCAC 13B.1634.(g).(5).

There were no other inorganic or organic detections above SWSLs or in exceedance of NC2L,
GWPS, or NC2B standards in groundwater or surface water monitoring points for the first
semiannual event of 2017 for the facility.

Based on the results summarized herein, we recommend that Republic Services of NC, LLC,
continue monitoring the uppermost aquifer beneath the East Carolina Regional Landfill in
accordance with the requirements for Detection Monitoring Program as outlined in Title 15A
NCAC 13B .1633.

_______________________________________________________________________
First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
East Carolina Regional Landfill, Permit No. 08-03 May 2017

iii

First Semiannual Water Quality Monitoring Report of 2017
East Carolina Regional Landfill, Permit No. 08-03
Bertie County, North Carolina

TABLE OF CONTENTS

EXECUTIVE SUMMARY ........................................................................................................... i 
1.0 INTRODUCTION..............................................................................................................1 
1.1  Site Description and Background ................................................................................ 1 
1.2 Compliance Monitoring History .................................................................................. 1 
1.3 Hydrogeologic Setting ................................................................................................... 2 
2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION ......................3 
2.1 Visual Inspection Program........................................................................................... 3 
2.2 Well Network and Groundwater Elevation Measurements...................................... 4 
2.3 January 2017 Monitoring Event .................................................................................. 4 
2.4 Laboratory Analysis Program ..................................................................................... 5 
2.5 January 2017 Sampling Results ................................................................................... 5 
3.0 LABORATORY AND FIELD QA/QC ............................................................................6 
4.0 DATA EVALUATION ......................................................................................................7 
4.1 Comparisons to Groundwater and Surface Water Standards ................................. 7 
4.2 Statistical Evaluations .................................................................................................. 7 
5.0 CONCLUSIONS ................................................................................................................8 
6.0 REFERENCES ...................................................................................................................8 

_______________________________________________________________________
First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
East Carolina Regional Landfill, Permit No. 08-03 May 2017

iv

TABLE OF CONTENTS
(CONTINUED)

Tables

Table 1 Historical Groundwater Elevations for the Yorktown Formation
Table 2 Historical Groundwater Elevations for the Black Creek Formation
Table 3 Estimated Hydraulic Gradients and Linear Groundwater Velocities
Table 4 Well Construction Information
Table 5 Quantified Detections by Monitoring Locations
Table 6 Exceedances of Groundwater Standards
Table 7 Field Parameters by Location

Drawing

Drawing 1 Potentiometric Surface Map, January 25, 2017

Appendices

Appendix A Historical Tables
Table 8 Historical Constituents/Analytes in Groundwater
Table 9 Historical Constituents/Analytes in Surface Water
Table 10 Historical Constituents/Analytes in Leachate
Appendix B Groundwater and Surface Water Field Data Logs
Appendix C Laboratory Analytical Reports
Appendix D Statistical Analyses Worksheets and Summary Table

______________________________________________________________________________
First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
East Carolina Regional Landfill, Permit No. 08-03 May 2017

1

1.0 INTRODUCTION
This report summarizes the monitoring results from the January 25, 2017, water quality
monitoring event at the East Carolina Regional Landfill in Bertie County, North Carolina, in
accordance with Title 15A of the North Carolina Administrative Code (NCAC) Subchapter 13B
.1632. The East Carolina Regional Landfill, which is an active municipal solid waste landfill, is
owned and operated by Republic Services of North Carolina, LLC (Republic) under Permit No.
08-03, issued by the North Carolina Department of Environmental and Quality (NCDEQ).

1.1 Site Description and Background
The East Carolina Regional Landfill is an active Subtitle D municipal solid waste landfill that
began operating in 1993. The location of the facility is shown on the inlay on Drawing 1. The
East Carolina Regional Landfill is located approximately 7.5 miles northwest of Windsor, NC at
the intersection of State Routes 1221 and 1225. The facility is bounded to the north and east by
undeveloped property and the Connaritsa Swamp, to the west by State Route 1225 and
undeveloped and agricultural property, and to the south by State Route 1221, wooded property,
and undeveloped bottomlands associated with the easterly flowing Cashie River.

Topographic elevations at the facility range from approximately 30 to 70 feet above mean sea
level. Along the northern and eastern portions of the facility, surface drainage from the facility
and surrounding areas is routed by drainage channels and stormwater control structures to
tributaries of the southerly-flowing Connaritsa Swamp, a tributary system of the Cashie River.
Along the western and southern portions of the facility, surface drainage from the facility and
surrounding areas is routed by drainage channels and stormwater control structures to tributaries
of the southeasterly flowing Cashie River. The Cashie River discharges to the Roanoke River
south of the Town of Windsor.

1.2 Compliance Monitoring History
Groundwater monitoring at the facility was initiated in January 1995 under the Detection
Monitoring Program for municipal solid waste landfills. The facility’s monitoring network
historically consisted of 14 monitoring wells (GW-1 through GW-14), which monitored the
uppermost Yorktown Formation (GW-2, GW-3, GW-5, GW-7 through GW-11, GW-13, and
GW-14) and the lower Black Creek Formation (GW-1, GW-4, GW-6, and GW-12). Monitoring
wells GW-1 and GW-2 were considered upgradient background wells and the remaining wells
were considered to be downgradient or side-gradient compliance wells. Well GW-16 was
decommissioned following the January 2007 sampling event during the construction of Cell 12.
Bunnell Lammons Engineering, Inc. (BLE) installed monitoring well GW-16R as a replacement
well prior to the January 2008 monitoring event. BLE installed GW-17 following the January
2008 sampling event as an additional monitoring well during the construction of Cell 12.
Monitoring well GW-14 was decommissioned and GW-18 was installed March 22, 2009, in
order to construct Cell 13. Piezometer PZ-110 was installed May 17, 2005, to monitoring well

______________________________________________________________________________
First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
East Carolina Regional Landfill, Permit No. 08-03 May 2017

2

specifications. On June 3, 2009, PZ-110 was converted into a monitoring well and was renamed
GW-21. A background sampling event for GW-18 and GW-21 was performed during the
January 2009 monitoring event. Cell 13 began receiving waste in the first quarter of 2014 and
wells GW-18 and GW-21 became part of the compliance network with the July 2014 sampling
event. Due to damage, GW-11 was abandoned and replaced with GW-11R on July 21, 2014.

In accordance with the facility’s permit, the current compliance monitoring network monitors the
Yorktown formation and is composed of GW-2 (background), GW-7, GW-8, GW-9, GW-10,
GW-11R, GW-13, GW-15, GW-16R, GW-17, GW-18, and GW-21, with the remaining
monitoring wells used for static water level observation. Per the June 2005 revision to the Water
Monitoring Procedures (BLE, 2005), the groundwater wells screened in the Black Creek
Formation are no longer sampled.

In addition to the routine groundwater monitoring points, the facility’s monitoring network
includes one upstream surface water monitoring point (SW-1) and three downstream surface
water sampling points (SW-2, SW-3, and SW-4), which are sampled in conjunction with the
groundwater monitoring wells. The leachate is sampled semiannually per the Solid Waste
Section requirements.

1.3 Hydrogeologic Setting
Geologically, the facility is located within the Carolina Coastal Plain Physiographic Province
(NCGS, 1985). The Coastal Plain Province is composed of easterly-dipping sedimentary strata
that thicken towards the east. Based on hydrogeologic characteristics, these strata are generally
classified as aquifer systems separated by aquitard units. The strata underlying the facility
include the Tertiary Yorktown Formation and the Cretaceous Black Creek Formation, both of
which are classified as aquifers. The Yorktown Formation is unconfined at this location, and the
lower Black Creek Formation, which is separated from the overlying Yorktown Formation by a
low permeability unit, is confined.

The uppermost groundwater beneath the facility is present in the shallow, unconfined Yorktown
Aquifer. Depending on topographic elevation, the depth to water in the Yorktown Formation
ranges from approximately 5 feet below grade along the southwestern perimeter of the facility to
approximately 25 feet below grade near the central and northeastern portion of the facility. In the
lower Black Creek Formation, the depth to water ranges from 10 to 20 feet below grade in the
monitoring wells screened in this unit. Historical static water level data are presented in Tables 1
and 2.

As presented in Table 1, the water level in the uppermost Yorktown aquifer beneath the facility
is fairly consistent, with temporal variation from the long-term average limited to approximately
four-five feet in the upgradient wells and three-four feet in the downgradient wells. Similarly, as
presented in Table 2, the fluctuation in the Black Creek aquifer is limited to approximately three
feet from the average. As expected, the range in fluctuation appears to be greater in the

______________________________________________________________________________
First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
East Carolina Regional Landfill, Permit No. 08-03 May 2017

3

upgradient wells, as these wells are more centrally located to the regional groundwater recharge
area. The range in fluctuation in the downgradient compliance wells, which are generally located
near groundwater discharge areas, is less likely due to the stabilizing effect of hydraulic
discharge boundaries.

Static water level measurements obtained during the January 25, 2017, sampling event were used
to prepare the groundwater surface contours presented on Drawing 1. In the upper Yorktown
Formation, groundwater flow across most of the site is toward the south-southwest. This is
consistent with previously submitted interpretations for this facility. Previous maps of the Black
Creek Formation show an apparent flow direction towards the southeast.

Based on the January 25, 2017, potentiometric surface map, the hydraulic gradient in the
uppermost aquifer underlying the site, as measured along the conceptual flow paths shown on the
contour map, was calculated to be approximately 0.0023 to 0.0072 ft/ft (Table 3). The estimated
rate of groundwater flow for the uppermost aquifer beneath the facility was calculated using the
following modified Darcy equation:

Vgw = Ki/ne

Where Vgw = average linear velocity (feet per day), K = hydraulic conductivity (feet per day),
i = horizontal hydraulic gradient, and ne = effective porosity.

The estimated linear groundwater flow velocity under the waste management unit is
approximately 2.87 to 9.06 ft/year, generally to the southwest (Table 3). The linear velocity
equation and resultant rates are based on the simplifying assumptions of a homogeneous and
isotropic aquifer, and may not be accurate when applied to heterogeneous and/or anisotropic
conditions.

2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION
2.1 Visual Inspection Program
In order to help detect potential releases of leachate and/or landfill gas migration in a timely
manner, a visual inspection program has been implemented at the East Carolina Regional
Landfill. This inspection program involves field personnel making the following observations in
the vicinity of the monitoring wells and surface water monitoring points:

 Observation of stress induced on the biological community (i.e., dead or dying vegetation);
 Indications of leachate impact (i.e., seeps, impacted surface water);
 Observations of erosion; and
 Negative changes around the waste facility.

______________________________________________________________________________
First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
East Carolina Regional Landfill, Permit No. 08-03 May 2017

4

During the January 2017 monitoring event, no physical indications of impacts were observed in
the vicinity of the monitoring wells and surface points.

2.2 Well Network and Groundwater Elevation Measurements
Monitoring well GW-2 is the facility’s background well and monitoring wells GW-7, GW-8,
GW-9, GW-10, GW-11R, GW-13, GW-15, GW-16R, GW-17, GW-18, and GW-21 are the
facility’s compliance wells. These wells are all screened within the upper Yorktown Formation.
The remaining monitoring wells are screened in the deeper Black Creek Formation and are used
as observation wells to monitor the depth to groundwater. Monitoring well construction
information is summarized in Table 4 and the well locations are shown on Drawing 1. The
network of monitoring wells was constructed to intercept the flow path for groundwater in the
uppermost aquifer underlying the waste disposal areas.

Depth-to-water measurements were recorded to the nearest 0.01 foot prior to initiating
groundwater purging and sampling activities. The groundwater elevations for this event, as well
as historical groundwater elevations for the Yorktown Formation wells and Black Creek
Formation wells are presented in Tables 1 and 2, respectively.

2.3 January 2017 Monitoring Event
Personnel from Joyce Engineering visited the facility on January 25, 2017, to purge and sample
monitoring wells GW-2, GW-7, GW-8, GW-9, GW-10, GW-11R, GW-13, GW-15, GW-16R,
GW-17, GW-18, and GW-21. In addition to the groundwater samples from the monitoring wells,
a leachate sample was collected from the facility’s holding tanks. Additional depth-to-water
measurements were obtained from GW-1, GW-4, GW-5, GW-6 and GW-12. Surface water
samples were collected from three downstream monitoring points, SW-1, SW-2 and SW-3. SW-
4 was dry and was not sampled during the January 2017 monitoring event.

Monitoring wells GW-2, GW-7, GW-8, GW-9, GW-10, GW-11R, GW-13, GW-15, GW-16R,
GW-17, GW-18, and GW-21 were purged with dedicated bladder pumps using micropurge
procedures pursuant to the facility’s approved monitoring plan. Measurements of pH, specific
conductance, dissolved oxygen, oxidation-reduction potential, temperature, and turbidity were
recorded after each system volume collected during the purge with field-calibrated instruments to
monitor for stabilization of water quality. Field parameters from the January 2017 event are
presented in Table 7.

Prior to sampling, the laboratory-supplied sample containers were prepared. Each sample
container was labeled with the sample identification number, sampling personnel, date and time
of sample collection, project name and number, and requested chemical analyses.

The required groundwater samples were collected directly from the dedicated bladder pump
discharge lines in the labeled, laboratory-supplied, pre-preserved sample containers after purging
was completed based on stabilization of all field parameters.

______________________________________________________________________________
First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
East Carolina Regional Landfill, Permit No. 08-03 May 2017

5

The surface water sample was collected directly from the stream flow, by lowering the sample
containers into the stream flow, taking care to prevent the overflow of the sample containers and
to minimize sample induced turbidity. Measurements of temperature, pH, specific conductivity,
and turbidity were recorded during the collection of the surface water samples.

The leachate sample was collected directly from the leachate piping manifold that serves the
leachate holding tanks. Measurements of temperature, pH, specific conductivity, and turbidity
were recorded during the collection of the leachate sample.

After collection, the samples were placed in a cooler on ice, under chain-of-custody control.
Copies of the sampling logs are presented in Appendix B. Included in each log is a description
of the sampling location, sampling equipment, sampling method, field observations, and field
parameters.

Due to the elevated silver concentration in GW-7, a verification resampling event was performed
on April 5, 2017. A sampling log for the resampling event is included in Appendix B.

2.4 Laboratory Analysis Program
The January 25, 2017 groundwater, surface water, and leachate samples were submitted to Pace
Analytical Services, LLC, of Norcross, Georgia under chain-of-custody control for analysis. The
groundwater samples, surface water samples, and the field blank, were analyzed for North
Carolina Appendix I constituents. The leachate sample was analyzed for NC Appendix I
constituents, mercury, biochemical oxygen demand, chemical oxygen demand, cyanide, nitrate
as N, nitrate/nitrite as N, nitrite as N, phosphorous, sulfate, total kjeldahl nitrogen, total
suspended solids, phenolics, and oil & grease. The trip blank was analyzed for North Carolina
Appendix I organic constituents only. Joyce Engineering requested a Level II data report for the
final laboratory report. The samples were kept on ice and received by the laboratory on January
26, 2017 in good condition, properly preserved, and within analysis hold times.

2.5 January 2017 Sampling Results
Constituents detected at quantified concentrations above the SWSL for the January 25, 2017
samples are summarized in Table 5, and exceedances of groundwater standards for the event are
summarized in Table 6. Historical analytical data for groundwater, surface water, and leachate
are summarized in Appendix A. The laboratory’s certificates-of-analysis and chains-of-custody
for this monitoring event and the resampling event are included in Appendix C.

Eight inorganic constituents (barium, beryllium, chromium, cobalt, copper, lead, silver and zinc)
were detected in samples from one or more groundwater or surface water monitoring points at
concentrations above their respective SWSL. Chromium in GW-17 and cobalt and silver in
GW-7 were the only constituents exceeding their respective 15A NCAC 2L.0202 Groundwater
Protection Standards (NC2L) or GWPS. The laboratory was contacted to confirm the initial

______________________________________________________________________________
First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
East Carolina Regional Landfill, Permit No. 08-03 May 2017

6

chromium, cobalt, and silver detections above their respective NC2L or GWPS, as well as run
dissolved metal analysis on the samples collected on January 25, 2017. The results of the
laboratory confirmation re-run analyses were as follows: Chromium in GW-17 was reported at
10 µg/L and was therefore not confirmed in excess of the NC2L. Dissolved Chromium in GW-17
was not detected and was therefore not confirmed in excess of the NC2L. Cobalt in GW-7 was
confirmed in excess of the GWPS, and silver in GW-7 was a confirmed detection above the
NC2L. Dissolved metals analyses from GW-7 were non-detect for cobalt and silver. Due to the
elevated silver concentrations in GW-7, a verification resampling event for silver was conducted
on April 5, 2017. The results of the resampling event did not confirm silver in excess of the
NC2L in GW-7.

Barium and Copper were reported at quantified concentrations in surface water monitoring point
SW-2 above the SWSLs, but below NC2B standards, during the January 2017 sampling event.
The constituent concentrations reported for the leachate samples collected during the January
2017 monitoring event are generally consistent with historical data.

No other inorganic or organic constituents were detected above their respective SWSLs in
monitoring wells or surface water monitoring points during the January 2017 monitoring event.

3.0 LABORATORY AND FIELD QA/QC
A field blank was collected by Joyce Engineering as part of the January 25, 2017 monitoring
event. In addition to the field blank, laboratory-prepared a trip blank accompanied the volatile
sample containers for the sampling event to and from the laboratory. The field blank was
analyzed for NC Appendix I constituents and the trip blank for NC Appendix I VOCs. In
addition to the field and trip blank, at least one method blank was analyzed by the laboratory for
each method used.

Upon receipt of the laboratory data package, the data was reviewed by Joyce Engineering for the
following:

 General typographical errors;
 Correct analyses performed and within method specified hold times;
 Correct reporting limits;
 Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate,
and Laboratory Control Samples;
 Blank qualified data (B-flags);
 Detections above the groundwater and surface water standards; and
 Detections that are above historical levels.

______________________________________________________________________________
First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
East Carolina Regional Landfill, Permit No. 08-03 May 2017

7

4.0 DATA EVALUATION
4.1 Comparisons to Groundwater and Surface Water Standards
Cobalt was detected above its GWPS in monitoring well GW-7 at 29.8 µg/L . Note that the
GWPS for cobalt is 1 µg/L but the SWSL for cobalt is 10 µg/L. Since the SWSL is higher than
the GWPS, and since only quantified detections above the SWSL are considered by the NCDEQ,
the SWSL is the effective standard for comparison. The cobalt detection in GW-7 was
statistically evaluated in accordance with the procedures outlined in 15A NCAC 13B.1632 (g)
and (h) to determine whether the reported concentrations exceeded the facility background
concentration (see Section 4.2). The cobalt detection in GW-7 was not identified as a
statistically significant increase (SSI) above background according to intrawell statistical
analyses for the monitoring location; therefore, we request that the SWS approve using the
background as the Groundwater Protection Standard (GPS) in accordance with 15A NCAC
13B.1634.(g).(5).

There were no other confirmed exceedances of NC2L or GWPS in groundwater monitoring
points during the first semiannual monitoring event of 2017

Current NC2B Standards allow for the calculation of the standard for some metals based on
water hardness. The SW-2 sample was analyzed for water hardness, with a result of 237 mg/L,
providing a calculated NC2B Standard of 18.72 µg/L for copper. Total copper from SW-2 was
reported at 16.4 µg/L; therefore, there were no exceedances of NC2B standards in Surface Water
monitoring points during the first semiannual monitoring event of 2017.
4.2 Statistical Evaluations

If comparison to a groundwater standard indicates an apparent exceedance of the standard for a
constituent, it was statistically evaluated in accordance with the procedures outlined in 15A
NCAC 13B.1632 (g) and (h) to determine if the reported concentrations exceeded the facility
background concentrations. The facility background data were evaluated through the use of the
Shapiro-Wilkes Test, Parametric Prediction Limits, Parametric Tolerance Intervals, Aitchison’s
Adjustment, Non-parametric Prediction Limits, and Poisson Prediction Limits, as appropriate.
Background data, tests for normality, outliers, Aitchison’s adjustment, tolerance interval, or
prediction limits are used, as appropriate based on the background data.

The statistical test by which downgradient data are compared to facility background data is based
upon the nature of the data and the number of data values that are less than the laboratory limit of
detection. All statistical tests are evaluated at the 0.05 level of significance, 95% confidence
level, and are conducted as one-tailed tests.

The data from the facility background well, GW-2, from October 1998 through January 2017
were used for interwell statistical analyses. For intrawell statistical analyses, the data from the
well in question, excluding the most recent eight sampling events, were used in the evaluation.

______________________________________________________________________________
First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
East Carolina Regional Landfill, Permit No. 08-03 May 2017

8

Cobalt was detected above its SWSL and GWPS in the sample from the downgradient
monitoring well GW-7 during the January 2017 sampling event. Cobalt has often been detected
in the facility’s upgradient background well, GW-2, at concentrations above the SWSL; although
the GW-2 result from the January 2017 event was estimated below the SWSL.

The cobalt detection in GW-7 was statistically evaluated in accordance with the procedures
outlined in 15A NCAC 13B.1632 (g) and (h) to determine if the reported concentrations
exceeded the facility background concentrations. The interwell statistical background calculated
based on historical cobalt concentrations from GW-2 between October 1998 and January 2017 is
17.3 µg/L. In the case of GW-7, cobalt has historically and consistently been detected at
concentrations above 17.3 µg/L, suggesting a different geochemistry for the monitoring area of
GW-7 and the need to perform intrawell statistical evaluation based on the specific background
history of GW-7 itself. For the intrawell statistics, the background data consisted of the
historical cobalt concentrations from MW-7 from October 1998 through January 2013 (i.e.,
excluding the last eight sampling events). The intrawell statistical background for GW-7 was
50.0 µg/L. Based on the statistical evaluations, the detections of cobalt are not identified as SSIs
above background and are representative of historical background concentrations. A summary
table and statistical worksheets are presented in Appendix D.

5.0 CONCLUSIONS
Based on the results summarized herein, we recommend that Republic Services of NC, LLC
continue monitoring the uppermost aquifer beneath the East Carolina Regional Landfill in
accordance with the requirements for Detection Monitoring Program as outlined in Title 15A
NCAC 13B .1633. The next compliance monitoring event for this facility is tentatively
scheduled for July 2017.

6.0 REFERENCES
BLE (Bunnell-Lammons Engineering, Inc.), December 2004. Report of Ground Water Quality
Results & Statistical Analysis, Second Semi-Annual Sampling Event of 2004 (N27) East Carolina
Regional MSW Landfill, Bertie County, North Carolina. 5 pp.

BLE (Bunnell-Lammons Engineering, Inc.), 2005. Water Monitoring Procedures, June 2005
Revision.

Law Engineering, August 1996. Design Hydrogeologic Report Phase II (Cells 7 and 8). 15 pp.

Golder Associates NC, Inc., August, 2011. Second Semi-Annual 2011 Sampling Event.
Prepared for Republic Services of North Carolina, LLC.

______________________________________________________________________________
First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
East Carolina Regional Landfill, Permit No. 08-03 May 2017

9

North Carolina Dept. Environment, Health, and Natural Resources (NCDEHNR), 1995, N.C.
Water Quality Monitoring Guidance Document for Solid Waste Facilities.

North Carolina Geologic Survey, 1985, Geologic Map of North Carolina; North Carolina
Department of Natural Resources and Community Development, Geological Survey Section;
scale 1:500,000.

Tables

TABLE 1:Historical Groundwater Elevations for the Yorktown FormationBackgroundGW-2 GW-3 GW-5 GW-7 GW-8 GW-9 GW-10 GW-11 GW-11R GW-13 GW-14 GW-15 GW-16 GW-16R GW-17 GW-18 GW-21TOC Elevation:66.36 66.23 62.60 58.79 60.04 51.94 53.22 72.42 70.90 74.76 78.74 78.23 63.02 66.12 85.68 62.00 62.07Jan-95 51.79 54.53 48.45 47.12 46.43 47.89 - - - - - - - - - - -Jul-95 55.85 51.80 50.42 53.84 48.12 48.13 - - - - - - - - - - -Jan-96 58.36 53.73 51.42 49.89 49.09 49.43 - - - - - - - - - - -Oct-96 59.92 55.53 53.05 49.87 49.14 50.32 50.32 - - - - - - - - - -Apr-97 57.00 51.96 50.85 47.77 47.50 49.15 49.67 50.20 - - - - - - - - -Oct-97 50.20 48.05 46.74 44.79 44.41 45.61 45.41 43.67 - - - - - - - - -Apr-98 55.12 51.65 50.52 47.78 47.26 48.01 47.00 44.22 - - - - - - - - -Oct-98 51.35 49.25 48.24 46.30 45.58 47.82 45.43 DRY - - - - - - - - -07-Apr-99 53.54 51.25 50.01 48.15 47.50 47.45 45.85 DRY - - - - - - - - -20-Oct-99 57.26 52.67 51.25 48.79 52.38 49.12 47.80 45.82 - - - - - - - - -26-Apr-00 54.03 50.93 49.56 48.02 47.52 47.46 45.75 DRY - - - - - - - - -18-Oct-00 52.71 49.70 48.56 46.80 46.23 45.57 43.40 DRY - - - - - - - - -18-Apr-01 53.54 50.36 48.94 47.37 46.85 46.32 43.93 DRY - 48.31 - - - - - - -24-Oct-01 50.78 47.97 47.00 45.50 44.75 44.84 44.48 43.99 - 47.95 - - - - - - -22-Apr-02 51.64 49.10 47.94 46.92 46.38 45.67 46.46 46.07 - 49.30 - - - - - - -21-Oct-02 50.06 47.73 46.41 45.70 45.30 46.22 47.07 46.61 - 48.82 - - - - - - -01-Apr-03 56.58 51.55 50.37 48.69 48.07 48.30 49.81 48.94 - 53.08 - - - - - - -27-Oct-03 54.61 50.14 48.86 46.99 46.42 47.81 48.57 48.63 - 51.91 53.64 - - - - - -26-Apr-04 55.24 50.59 49.25 47.69 47.10 48.45 48.82 48.74 - 52.02 54.55 - - - - - -26-Oct-04 53.01 48.53 47.38 45.91 45.49 46.99 48.20 48.27 - 50.79 52.11 - - - - - -15-Mar-05 54.56 49.40 47.93 46.88 46.57 47.72 48.48 48.42 - 51.96 54.34 - - - - - -12-Jul-05 53.25 48.88 47.74 46.35 45.86 47.22 47.98 48.34 - 51.00 52.71 - - - - - -19-Jan-06 55.12 49.82 48.23 46.81 46.60 48.28 48.74 48.40 - 51.66 53.92 53.10 - - - - -11-Jul-06 54.89 49.63 48.44 47.28 46.79 47.78 48.06 48.25 - 51.46 53.16 52.90 51.00 - - - -17-Jan-07 56.09 51.21 47.81 48.67 48.00 49.68 48.67 48.28 - 52.23 54.74 53.59 53.11 - - - -09-Jul-07 52.58 48.30 47.41 45.21 44.69 46.44 46.82 46.11 - 50.50 50.84 51.42 49.53 - - - -14-Jan-08 50.15 46.67 45.64 44.76 44.95 46.45 <32.68 47.54 - 49.43 49.93 49.75 - 47.23 - - 30-Apr-08 --------------52.99 - -14-Jul-08 51.58 47.34 46.60 46.22 46.11 46.67 <32.68 47.91 - 50.00 50.19 50.60 - 47.40 49.54 - -02-Oct-08 --------------48.44 - -19-Jan-09 50.24 46.83 45.93 46.51 47.00 47.80 48.69 48.28 - 49.63 49.29 49.88 - 46.92 48.96 - -20-Jul-09 51.00 47.38 46.39 46.22 46.00 46.29 47.49 47.70 - 49.64 - 50.16 - 48.33 49.60 46.67 48.6925-Jan-10 53.27 48.91 47.84 49.17 49.39 49.15 50.01 48.70 - 51.24 - 51.83 - 54.40 56.38 49.24 53.8206-Jul-10 52.53 48.86 47.87 47.67 47.09 47.01 47.06 47.86 - 50.61 - 51.38 - 50.97 51.49 49.85 50.6804-Jan-11 51.80 48.72 47.50 48.04 47.81 48.06 48.58 48.17 - 50.60 - 51.08 - 53.27 53.50 52.30 50.3205-Jul-11 51.86 48.14 47.21 46.61 46.00 46.15 46.67 47.47 - 49.77 - 50.69 - 50.32 51.07 49.50 50.1109-Jan-12 51.53 48.64 47.41 47.15 46.84 47.47 48.34 47.95 - 49.68 - 50.49 - 51.53 52.48 50.55 49.7509-Jul-12 51.12 48.79 47.62 46.79 46.19 46.66 47.24 47.68 - 48.33 - 49.39 - 50.88 51.47 49.98 50.0828-Jan-13 49.73 47.62 46.65 47.01 47.00 47.36 48.34 48.00 - 48.64 - 49.12 - 51.09 51.44 49.88 48.6917-Jul-13 50.85 48.91 47.53 47.61 47.54 47.13 48.08 47.98 - 49.01 - 49.62 - 53.41 54.58 52.68 49.3728-Jan-14 49.73 47.64 46.63 47.30 47.56 47.24 48.31 47.92 - 48.56 - 49.02 - 51.06 54.58 49.85 48.7224-Jul-14 49.28 49.07 47.87 47.88 46.44 46.26 44.79 - 42.39 45.23 - 46.96 - 53.02 53.54 53.25 49.6628-Jan-15 49.11 50.83 47.50 47.04 47.12 46.60 44.78 - 40.99 44.82 - 46.53 - 54.81 55.58 54.00 49.6230-Jul-15 - - 46.66 44.69 44.13 44.44 42.77 - - 43.54 - 45.29 - 49.80 50.13 49.09 49.4727-Jan-16 46.81 48.99 47.36 46.84 47.14 46.49 44.67 - - 43.26 - 42.23 - 54.77 55.66 54.25 49.8227-Jul-16 46.96 48.33 47.29 45.84 45.44 45.45 43.47 - 40.20 43.46 - 45.18 - 51.08 51.08 50.25 49.9725-Jan-17 48.31 47.53 47.57 46.99 47.04 46.32 44.47 - 40.49 44.11 - 44.63 - 54.27 54.58 53.65 50.52MEAN52.61 49.62 48.17 47.23 46.82 47.26 47.01 47.54 41.02 49.11 52.45 49.34 51.21 51.29 52.35 50.94 49.96MAXIMUM59.92 55.53 53.05 53.84 52.38 50.32 50.32 50.20 42.39 53.08 54.74 53.59 53.11 54.81 56.38 54.25 53.82MINIMUM46.81 46.67 45.64 44.69 44.13 44.44 42.77 43.67 40.20 43.26 49.29 42.23 49.53 46.92 48.44 46.67 48.69Notes: Elevations in Ft-AMSL = Feet above mean sea level. *MW-16 was decommissioned after the installation of MW-16R.TOC = Top of casing. MW-11 was abandonded and MW-11R was installed on July 21, 2014. '- = not measured All data prior to 2012 taken from previous report by Golder Associates NC, Inc. Location:DowngradientEast Carolina Regional LandfillPermit No. 08-03Joyce Engineering
TABLE 2:
Historical Groundwater Elevations for the Black Creek Formation
Background
GW-1 GW-4 GW-6 GW-12
TOC Elevation 65.87 62.53 58.95 66.13
Jan-95 48.13 47.31 47.78 51.62
Jul-95 51.12 49.35 49.95 49.51
Jan-96 51.98 49.68 50.10 49.89
Oct-96 53.44 51.38 51.85 51.70
Apr-97 53.46 51.00 51.60 51.38
Oct-97 47.00 46.10 46.44 46.24
Apr-98 52.44 50.03 50.33 50.29
Oct-98 48.24 48.23 48.00 47.70
07-Apr-99 51.94 49.27 49.64 49.50
20-Oct-99 52.13 49.56 49.45 49.83
26-Apr-00 52.15 49.13 49.60 49.37
18-Oct-00 51.04 48.09 48.49 48.36
18-Apr-01 52.14 48.40 48.81 48.64
24-Oct-01 48.58 46.29 46.73 48.20
22-Apr-02 50.40 47.41 47.85 49.45
21-Oct-02 48.08 45.93 46.37 45.93
01-Apr-03 53.40 49.65 50.18 49.75
27-Oct-03 52.07 48.91 49.32 49.03
26-Apr-04 52.83 49.05 49.66 49.16
26-Oct-04 50.57 47.45 48.00 47.54
15-Mar-05 53.10 48.31 48.96 48.47
12-Jul-05 50.96 47.51 48.29 47.82
19-Jan-06 52.27 48.24 48.85 48.40
11-Jul-06 50.95 47.82 48.30 47.92
17-Jan-07 52.62 48.11 49.95 49.14
09-Jul-07 49.96 46.83 47.34 46.80
14-Jan-08 47.41 45.14 45.64 45.02
14-Jul-08 48.65 45.92 46.46 45.90
19-Jan-09 48.13 45.31 45.92 45.35
20-Jul-09 48.79 45.78 46.27 45.78
25-Jan-10 51.98 47.45 48.15 47.56
06-Jul-10 50.61 47.22 47.77 47.37
04-Jan-11 50.35 46.98 47.53 47.16
05-Jul-11 49.88 46.64 46.47 46.79
09-Jan-12 50.39 47.10 47.71 47.25
09-Jul-12 50.09 47.13 47.64 47.31
28-Jan-13 49.00 45.94 46.54 45.99
17-Jul-13 50.47 46.88 47.40 46.98
28-Jan-14 49.08 45.92 46.55 46.02
24-Jul-14 50.50 47.03 46.99 47.27
28-Jan-15 51.27 47.13 47.59 NM
30-Jul-15 47.27 47.21 47.46 NM
27-Jan-16 51.22 47.11 47.16 47.38
27-Jul-16 49.57 46.68 47.10 46.93
25-Jan-17 51.02 46.13 47.60 47.28
MEAN 50.59 47.64 48.13 48.02
MAXIMUM 53.46 51.38 51.85 51.70
MINIMUM 47.00 45.14 45.64 45.02
Notes:
Elevations in Ft-AMSL = Feet above mean sea level.
TOC = Top of casing.
All data prior to 2012 taken from previous report by Golder Associates NC. Inc.
Location Downgradient
East Carolina Regional Landfill
Permit No. 08-03
Joyce Engineering
TABLE 3: Hydraulic Gradients and Linear Groundwater VelocitiesDate of Water Table Measurements: SEGMENT HORIZ. HYDRAULIC EFFECTIVE LINEARFLOW BEGIN & END GRADIENT CONDUCTIVITY POROSITY VELOCITYDIRECTION GW ELEVATIONiKneV(feet) (feet-AMSL) (ft/ft) (ft/day) (ft/year)544050404844Average 0.0047 Average 6.00Notes:Linear flow velocity: V = Ki/ne (modified Darcy equation). Hydraulic conductivity (K) is based on the arithmetic mean of values from slug tests conducted at the facility.Effective porosity (ne) value is estimated at 85% of the laboratory-determined porosity for soil samples from the facility.Refer to Drawing 1 for flow line segments.January 25, 20172.87i31763SW0.0023 9.35E-010.279.35E-010.279.06i22082SW0.0048 9.35E-010.276.07FLOW LINE SEGMENTi11954SW0.0072SEGMENT LENGTHEast Carolina Regional LandfillPermit No. 08-03Joyce Engineering Inc.
TABLE 4: Well Construction InformationWell IdentificationConstruction DateGround Surface ElevationTOC ElevationWell DepthWell DiameterScreened IntervalScreened Geologic Formation(Ft-AMSL) (Ft-AMSL) (Feet) (Inches) (Ft-AMSL)GW-11993 63.72 65.87 622 11.72 to 1.72 Black Creek FormationGW-21993 64.02 66.36 262 48.02 to 38.02 Yorktown FormationGW-31993 63.72 66.23 262 47.72 to 37.72 Yorktown FormationGW-41993 60.68 62.53 592 11.68 to 1.68 Black Creek FormationGW-51993 60.94 62.60 242 46.94 to 36.94 Yorktown FormationGW-61993 57.53 58.95 632 4.53 to -5.47 Black Creek FormationGW-71993 57.44 58.79 182 49.44 to 39.44 Yorktown FormationGW-81993 58.60 60.04 182 50.60 to 40.60 Yorktown FormationGW-91993 50.14 51.94 132 47.14 to 37.14 Yorktown FormationGW-101996 50.47 53.22 222 40.47 to 30.47 Yorktown FormationGW-111997 68.60 72.42 282 49.60 to 39.60 Yorktown FormationGW-11R2014 48.00 51.00 402 20.00 to 40.00 Yorktown FormationGW-121993 63.70 66.13 542 19.70 to 9.70 Black Creek FormationGW-132001 72.16 74.76 41.302 45.86 to 30.86 Yorktown FormationGW-14200376.7 78.74 47.82 38.9 to 28.9 Yorktown FormationGW-152005 75.25 78.23 39.222 51.03 to 36.03 Yorktown FormationGW-162006 60.99 63.02 232 13.0 to 23 Yorktown FormationGW-16R2007 63.02 66.12 24.242 53.78 to 38.78 Yorktown FormationGW-172008 82.92 85.68 41.332 51.59 to 41.59 Yorktown FormationGW-182009 59.20 62.07 26.712 47.49 to 32.49 Yorktown FormationGW-212006 60.86 62.98 28.002 47.86 to 32.86 Yorktown FormationNotes:Ft-AMSL = Feet above mean sea level. GW-1, -3, -4, -5, -6, -12, -18, and -21 are used for collection of water level data only.TOC - Top of casing (measureing point). All data prior to 2012 taken from report by Golder Associates NC, Inc.Shaded wells have been decommissioned or abandoned.East Carolina Regional LandfillPermit No. 08-03Joyce Engineering
Table 5: Quantified Detections by Monitoring Locations
WELL ID PARAMETER RESULT UNITS SWSL DATE
0803-GW2 Total Barium 462 µg/L 100 1/25/2017
0803-GW2 Total Beryllium 1.03 µg/L 1 1/25/2017
0803-GW2 Total Zinc 13.3 µg/L 10 1/25/2017
0803-GW7 Total Beryllium 1.60 µg/L 1 1/25/2017
0803-GW7 Total Cobalt (re-run)33.0 µg/L 10 1/25/2017
0803-GW7 Total Cobalt 29.8 µg/L 10 1/25/2017
0803-GW7 Dissolved Cobalt ND µg/L 10 1/25/2017
0803-GW7 Total Silver (re-run)40.9 µg/L 10 1/25/2017
0803-GW7 Total Silver 52.9 µg/L 10 1/25/2017
0803-GW7 Dissolved Silver ND µg/L 10 1/25/2017
0803-GW7 Total Silver (resample) 0.81 J µg/L 10 4/5/2017
0803-GW7 Total Zinc 11.4 µg/L 10 1/25/2017
0803-GW8 Total Barium 113 µg/L 100 1/25/2017
0803-GW9 Total Barium 163 µg/L 100 1/25/2017
0803-GW9 Total Zinc 12.8 µg/L 10 1/25/2017
0803-GW10 Total Barium 111 µg/L 100 1/25/2017
0803-GW13 Total Barium 380 µg/L 100 1/25/2017
0803-GW13 Total Zinc 10.4 µg/L 10 1/25/2017
0803-GW15 Total Barium 166 µg/L 100 1/25/2017
Republic - East Carolina Landfill
Permit No. 08-03
Joyce Engineering
Table 5: Quantified Detections by Monitoring Locations
WELL ID PARAMETER RESULT UNITS SWSL DATE
0803-GW17 Total Barium 176 µg/L 100 1/25/2017
0803-GW17 Total Chromium (re-run) 10.0 µg/L 10 1/25/2017
0803-GW17 Total Chromium 11.1 µg/L 10 1/25/2017
0803-GW17 Dissolved Chromium ND µg/L 10 1/25/2017
0803-GW17 Total Zinc 11.8 µg/L 10 1/25/2017
0803-GW18 Total Barium 190 µg/L 100 1/25/2017
0803-GW18 Total Zinc 11.2 µg/L 10 1/25/2017
0803-SW2 Total Barium 106 µg/L 100 1/25/2017
0803-SW2 Total Copper 16.4 µg/L 10 1/25/2017
0803-SW2 Total Hardness 237 mg/L --- 1/25/2017
0803-PW1 Total Copper 186 µg/L 10 1/25/2017
0803-PW1 Total Lead 13.2 µg/L 10 1/25/2017
0803-PW1 Total Zinc 316 µg/L 10 1/25/2017
Notes: µg/L = micorgrams per liter.
mg/L = milligrams per liter.
SWSL = NC Soild Waste Section Reporting Limit.
Laboratory Reporting Limit used when SWSL has not been established.
>>Dissolved samples processed 2/22/2017
(re-run) laboratory re-analysis for confirmation, performed February 28, 2017.
GW-7 resample for silver on 4/5/2017
Republic - East Carolina Landfill
Permit No. 08-03
Joyce Engineering
Table 6: Exceedances of Groundwater StandardsWELL IDPARAMETER RESULT UNITS SWSLNC2L/*GWPS /**2BBACKGROUNDDATE0803-GW7 Total Cobalt29.8µg/L 10 1* 50.0 1/25/20170803-GW7 Total Silver 52.9 µg/L 10 20 --- 1/25/20170803-GW7 Total Silver (resample) 0.81 J µg/L 10 20 --- 4/5/20170803-GW17 Total Chromium 11.1 µg/L 10 10 10.4 1/25/20170803-GW17 Total Chromium (re-run) 10.0 µg/L 10 10 10.4 1/25/2017NOTES: µg/L = micorgrams per liter.SWSL = NC Soild Waste Section Reporting Limit.Laboratory Reporting Limit used when SWSL has not been established.NC 2L = NC Groundwater Standard from 15A NCAC 2L.0202.*GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC 2L).**2B = NC 15A NCAC 02B Surface Water Quality StandardsGPS = Groundwater Protection Standard as defined by 15A NCAC 13B.1634(g).Bold indicates confirmed GPS exceedance.Republic- East Carolina landfillPermit No. 08-03Joyce Engineering
Table 7: Field Parameters by Location
WELL ID PARAMETER RESULT UNITS DATE
0803-GW2 Temperature 17.2 C° 1/25/2017
0803-GW2 Dissolved oxygen 5.69 mg/L 1/25/2017
0803-GW2 Conductivity 189.8 µS/cm 1/25/2017
0803-GW2 pH 6.32 S.U. 1/25/2017
0803-GW2 Oxidation Reduction Potential 185.9 mV 1/25/2017
0803-GW2 Turbidity 7.23 ntu 1/25/2017
0803-GW2 Static Water Level 18.05 ft 1/25/2017
0803-GW2 Well Depth 30.00 ft 1/25/2017
0803-GW7 Temperature 18.7 C° 1/25/2017
0803-GW7 Dissolved oxygen 6.28 mg/L 1/25/2017
0803-GW7 Conductivity 172.8 µS/cm 1/25/2017
0803-GW7 pH 4.3 S.U. 1/25/2017
0803-GW7 Oxidation Reduction Potential 286.8 mV 1/25/2017
0803-GW7 Turbidity 1.34 ntu 1/25/2017
0803-GW7 Static Water Level 11.8 ft 1/25/2017
0803-GW7 Well Depth 18.00 ft 1/25/2017
0803-GW7** Temperature 17.9 C° 4/5/2017
0803-GW7** Dissolved oxygen 6.53 mg/L 4/5/2017
0803-GW7** Conductivity 166.3 µS/cm 4/5/2017
0803-GW7**pH 4.52 S.U. 4/5/2017
0803-GW7** Oxidation Reduction Potential 164.8 mV 4/5/2017
0803-GW7**Turbidity 5.15 ntu 4/5/2017
0803-GW7** Static Water Level 11.48 ft 4/5/2017
0803-GW7** Well Depth 18.00 ft 4/5/2017
0803-GW8 Temperature 15.8 C° 1/25/2017
0803-GW8 Dissolved oxygen 6.36 mg/L 1/25/2017
0803-GW8 Conductivity 119.7 µS/cm 1/25/2017
0803-GW8 pH 5.41 S.U. 1/25/2017
0803-GW8 Oxidation Reduction Potential 221.2 mV 1/25/2017
0803-GW8 Turbidity 2.63 ntu 1/25/2017
0803-GW8 Static Water Level 13.00 ft 1/25/2017
0803-GW8 Well Depth 18.00 ft 1/25/2017
0803-GW9 Temperature 13.2 C° 1/25/2017
0803-GW9 Dissolved oxygen 7.16 mg/L 1/25/2017
0803-GW9 Conductivity 136.2 µS/cm 1/25/2017
0803-GW9 pH 5.50 S.U. 1/25/2017
0803-GW9 Oxidation Reduction Potential 239.2 mV 1/25/2017
0803-GW9 Turbidity 2.50 ntu 1/25/2017
0803-GW9 Static Water Level 5.62 ft 1/25/2017
0803-GW9 Well Depth 17.00 ft 1/25/2017
Republic- East Carolina Landfill
Permit No. 08-03 Page 1 of 4
Joyce Engineering
Table 7: Field Parameters by Location
WELL ID PARAMETER RESULT UNITS DATE
0803-GW10 Temperature 16.3 C° 1/25/2017
0803-GW10 Dissolved oxygen 0.51 mg/L 1/25/2017
0803-GW10 Conductivity 125.9 µS/cm 1/25/2017
0803-GW10 pH 5.86 S.U. 1/25/2017
0803-GW10 Oxidation Reduction Potential 122.9 mV 1/25/2017
0803-GW10 Turbidity 2.56 ntu 1/25/2017
0803-GW10 Static Water Level 8.75 ft 1/25/2017
0803-GW10 Well Depth 20.00 ft 1/25/2017
0803-GW11R Temperature 14.0 C° 1/25/2017
0803-GW11R Dissolved oxygen 4.19 mg/L 1/25/2017
0803-GW11R Conductivity 42.9 µS/cm 1/25/2017
0803-GW11R pH 5.27 S.U. 1/25/2017
0803-GW11R Oxidation Reduction Potential 205.3 mV 1/25/2017
0803-GW11R Turbidity 1.68 ntu 1/25/2017
0803-GW11R Static Water Level 30.41 ft 1/25/2017
0803-GW11R Well Depth 42.24 ft 1/25/2017
0803-GW13 Temperature 17.5 C° 1/25/2017
0803-GW13 Dissolved oxygen 3.23 mg/L 1/25/2017
0803-GW13 Conductivity 93.2 µS/cm 1/25/2017
0803-GW13 pH 4.84 S.U. 1/25/2017
0803-GW13 Oxidation Reduction Potential 215.8 mV 1/25/2017
0803-GW13 Turbidity 2.11 ntu 1/25/2017
0803-GW13 Static Water Level 30.65 ft 1/25/2017
0803-GW13 Well Depth 41.60 ft 1/25/2017
0803-GW15 Temperature 17.5 C° 1/25/2017
0803-GW15 Dissolved oxygen 5.82 mg/L 1/25/2017
0803-GW15 Conductivity 95.8 µS/cm 1/25/2017
0803-GW15 pH 5.34 S.U. 1/25/2017
0803-GW15 Oxidation Reduction Potential 195.7 mV 1/25/2017
0803-GW15 Turbidity 18.76 ntu 1/25/2017
0803-GW15 Static Water Level 33.60 ft 1/25/2017
0803-GW15 Well Depth 39.05 ft 1/25/2017
0803-GW16R Temperature 17.1 C° 1/25/2017
0803-GW16R Dissolved oxygen 3.85 mg/L 1/25/2017
0803-GW16R Conductivity 52.9 µS/cm 1/25/2017
0803-GW16R pH 4.65 S.U. 1/25/2017
0803-GW16R Oxidation Reduction Potential 367.5 mV 1/25/2017
0803-GW16R Turbidity 3.7 ntu 1/25/2017
0803-GW16R Static Water Level 11.85 ft 1/25/2017
0803-GW16R Well Depth 27.20 ft 1/25/2017
Republic- East Carolina Landfill
Permit No. 08-03 Page 2 of 4
Joyce Engineering
Table 7: Field Parameters by Location
WELL ID PARAMETER RESULT UNITS DATE
0803-GW17 Temperature 16.9 C° 1/25/2017
0803-GW17 Dissolved oxygen 4.49 mg/L 1/25/2017
0803-GW17 Conductivity 57.8 µS/cm 1/25/2017
0803-GW17 pH 5.1 S.U. 1/25/2017
0803-GW17 Oxidation Reduction Potential 199.7 mV 1/25/2017
0803-GW17 Turbidity 15.13 ntu 1/25/2017
0803-GW17 Static Water Level 31.10 ft 1/25/2017
0803-GW17 Well Depth 44.30 ft 1/25/2017
0803-GW18 Temperature 16.8 C° 1/25/2017
0803-GW18 Dissolved oxygen 6.90 mg/L 1/25/2017
0803-GW18 Conductivity 141.4 µS/cm 1/25/2017
0803-GW18 pH 4.38 S.U. 1/25/2017
0803-GW18 Oxidation Reduction Potential 288.9 mV 1/25/2017
0803-GW18 Turbidity 4.52 ntu 1/25/2017
0803-GW18 Static Water Level 8.35 ft 1/25/2017
0803-GW18 Well Depth 29.60 ft 1/25/2017
0803-GW21 Temperature 18.0 C° 1/25/2017
0803-GW21 Dissolved oxygen 2.71 mg/L 1/25/2017
0803-GW21 Conductivity 34.1 µS/cm 1/25/2017
0803-GW21 pH 4.85 S.U. 1/25/2017
0803-GW21 Oxidation Reduction Potential 217.2 mV 1/25/2017
0803-GW21 Turbidity 2.86 ntu 1/25/2017
0803-GW21 Static Water Level 11.55 ft 1/25/2017
0803-GW21 Well Depth 29.95 ft 1/25/2017
Republic- East Carolina Landfill
Permit No. 08-03 Page 3 of 4
Joyce Engineering
Table 7: Field Parameters by Location
WELL ID PARAMETER RESULT UNITS DATE
0803-PW1 Temperature 17.3 C° 1/25/2017
0803-PW1 Dissolved oxygen 3.24 mg/L 1/25/2017
0803-PW1 Conductivity 415.3 µS/cm 1/25/2017
0803-PW1 pH 7.94 S.U. 1/25/2017
0803-PW1 Oxidation Reduction Potential 212.5 mV 1/25/2017
0803-PW1 Turbidity 4.79 ntu 1/25/2017
0803-SW1 Temperature 13.5 C° 1/25/2017
0803-SW1 Dissolved oxygen 10.86 mg/L 1/25/2017
0803-SW1 Conductivity 287 µS/cm 1/25/2017
0803-SW1 pH 5.30 S.U. 1/25/2017
0803-SW1 Oxidation Reduction Potential 246.3 mV 1/25/2017
0803-SW1 Turbidity 16.15 ntu 1/25/2017
0803-SW2 Temperature 14 C° 1/25/2017
0803-SW2 Dissolved oxygen 5.36 mg/L 1/25/2017
0803-SW2 Conductivity 970 µS/cm 1/25/2017
0803-SW2 pH 7.50 S.U. 1/25/2017
0803-SW2 Oxidation Reduction Potential 185.1 mV 1/25/2017
0803-SW2 Turbidity 16.15 ntu 1/25/2017
0803-SW3 Temperature 11.5 C° 1/25/2017
0803-SW3 Dissolved oxygen 8.8 mg/L 1/25/2017
0803-SW3 Conductivity 200.8 µS/cm 1/25/2017
0803-SW3 pH 7.31 S.U. 1/25/2017
0803-SW3 Oxidation Reduction Potential 175 mV 1/25/2017
0803-SW3 Turbidity 18.1 ntu 1/25/2017
Notes: ºC= degrees Centigrade
S.U..= Standard Units
µS/cm = micro-Siemens per centimeter
ntu = Nephelometric Turbidity Units
mg/L = milligrams per liter
mV = millivolts.
** GW-7 resample for silver on 4/5/2017
Republic- East Carolina Landfill
Permit No. 08-03 Page 4 of 4
Joyce Engineering

Drawing

W.E.48.8GW-11R
40.49GW-15
44.63
GW-2
48.31
GW-17
54.58
GW-16R
54.27
GW-18
53.65
GW-21
50.52
GW-3
47.53
GW-5
47.57
GW-7
46.99
SW-2
GW-8
47.04
GW-9
46.32
GW-10
44.47
SW-1
EXISTING
CELL
NO. 12 EXISTING
CELL
NO. 11
EXISTING
CELL
NO. 10
EXISTING
CELL
NO. 9
EXISTING
CELL
NO. 8
EXISTING
CELL
NO. 7
EXISTING
CELL
NO. 6
EXISTING
CELL
NO. 5
EXISTING
CELL
NO. 3
APPROXIMATE LIMITS OF WASTE
LEACHATE TANK
4452 46
48GW-13
44.11
EXISTING
CELL
NO. 4
50
50506060
50506050506070
90
110
130
150 70606060505060606060
5050 605050
5070
80
100
120
140
160
180
200
5060
502207090110130150160170 180200606060506060150806060 40405050504040
50 406060505060606060606060606060504060604050606070709060100
120
140
160
180
200
22016070806070
80
90
60 606060606050
EXISTING
CELL
NO. 13
i 1
i 2
48
4
0
404446i 3
GW-1
GW-12
GW-4
GW-6
424
25454505250SITE
710
GW-X
SW-X
PROPERTY LINE
EXISTING 10' TOPOGRAPHIC CONTOUR
EXISTING 2' TOPOGRAPHIC CONTOUR
EXISTING ROAD
APPROXIMATE LIMITS OF WASTE
GROUNDWATER SURFACE CONTOUR
[FEET ABOVE MEAN SEA LEVEL (AMSL)]
GROUNDWATER FLOW DIRECTION
GROUNDWATER MONITORING WELL
SCREENED IN THE BLACK ROCK FORMATION
GROUNDWATER MONITORING WELL
LOCATION AND IDENTIFICATION WITH STATIC
WATER LEVEL ELEVATION (FEET AMSL)
SURFACE MONITORING POINT LOCATION AND
IDENTIFICATION
PERSONAL WELL
SEGMENT USED FOR GRADIENT CALCULATION
1.TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET
2.GROUNDWATER CONTOUR INTERVAL = 2 FEET
3.STATIC WATER LEVELS WERE MEASURED ON 01/25/17.
4.GROUNDWATER CONTOURS BASED ON LINEAR
INTERPOLATION BETWEEN AND EXTRAPOLATION FROM
KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWN
FIELD CONDITIONS. THEREFORE, GROUNDWATER
CONTOURS MAY NOT REFLECT ACTUAL GROUNDWATER
CONDITIONS.
5.TOPOGRAPHIC SURVEY COMPLETED BY COOPER AERIAL
SURVEY CO. PHILADELPHIA, PA., DATED FEBRUARY 4, 2015.
6.GW-1, GW-4, GW-6, AND GW-12 WELLS ARE SCREENED IN
THE BLACK CREEK FORMATION.
i
LEGEND
2660
NOTES
W PW-X
GW-X
FLOW PATH LENGTH
i
i
= 1,954 LF
= 2,082 LF
= 1,763 LFi
PROJECT NO.APPROVEDCHECKEDDRAWNDESIGNEDDATEDATEREVISIONS AND RECORD OF ISSUEBYNO APPCK
SCALE All rights reserved.Ó Joyce Engineering, Inc.DRAWING NO.L:\Republic NC\East Carolina\JANUARY 2017 East Carolina GW Map.dwg Layout=Layout12211 W. MEADOWVIEW ROADGREENSBORO, NC 27407PHONE: [phone]NC CORP LIC: C-0782894EAST CAROLINA REGIONAL LANDFILL BERTIE COUNTY, NORTH CAROLINA20171
AS SHOWNPOTENTIOMETRIC SURFACE CONTOUR MAPYORKTOWN FORMATIONJANUARY 25, 2017PERMIT NO. 08-03GERHVBVB02/21/170
(FEET)
GRAPHIC SCALE
400200100
VICINITY MAP
SOURCE: U.S.G.S. 7.5 MINUTE TOPOS FOR AULANDER AND REPUBLICAN, NC
SW-3 AND SW-4 LOCATED
APPROXIMATELY 1000' SE

Appendix A

Historical Tables

TABLE 8
Historical Groundwater Constituents/Analytes
Sample
Analyte
Collection
Date DL SWSL GW-2 GW-7 GW-8 GW-9 GW-10 GW-11/11R GW-13 GW-15 GW-16R GW-17 GW-18 GW-21 Blanks
Inorganic Compounds
Total Antimony 01/09/12 --- 6.00 ND ND ND ND ND ND 0.18 J ND ND ND --- --- NDGWPS = 1 µg/L 07/09/12 --- 6.00 0.70 J 0.24 J ND ND ND ND ND ND ND ND ------ND
01/28/13 --- 6.00 1.47 J 0.40 J ND ND ND ND ND ND ND ND ------ND
07/17/13 --- 6.00 2.85 B 0.97 B 0.55 B 0.34 B ND 0.58 B 0.28 B ND ND ND ------0.39 J01/28/14 --- 6.00 2.12 J 0.50 J ND ND ND ---ND ND ND ND ------ND
05/31/14 --- 6.00 ------------------------------ND ND ND
06/24/14 --- 6.00 ------------------------------ND ND ND07/24/14 1.05 6.00 ND ND ND ND ND ND ND ND ND ND ND ND ND01/28/15 1.05 6.00 ND ND ND ND ND ND ND ND ND ND ND ND ND
07/30/15 0.25 6.00 ---1.77 J ND ND ND ---ND ND 0.37 J ND ND ND ND
09/16/15 0.25 6.00 ND ---------------------------------ND01/27/16 0.25 6.00 ND 1.17 J ND ND ND ---ND ND 0.35 J ND ND ND ND07/27/16 0.25 6.00 2.02 J 0.69 J 0.36 J ND ND 0.33 J ND ND ND ND ND ND ND
01/25/17 0.25 6.00 1.03 J 0.45 J ND ND ND ND ND ND ND ND ND ND ND
Total Arsenic 07/12/05 --- 10.0 ND ND ND ND ND ND ND ---------------ND
NC 2L = 10 µg/L 01/19/06 --- 10.0 ND ND ND ND ND ND ND ---------------ND
07/11/06 --- 10.0 ND ND ND ND ND ND ND ND ------------ND10/31/06 --- 10.0 ---------------------ND ------------ND01/17/07 --- 10.0 2.10 B ND 2.10 B ND ND 2.10 B ND ND ------------3.40 J
07/09/07 --- 10.0 ND ND 2.10 J ND ND ND ND ND ------------ND
01/14/08 --- 10.0 ND ND 2.10 J 2.70 J ND 2.30 J ND ND ND ---------ND04/30/08 --- 10.0 ---------------------------ND ------2.20 J
07/14/08 --- 10.0 ND ND ND ND ND ND ND 2.9 J ND 3.50 J ------ND
10/03/08 --- 10.0 ---------------------------ND ------ND01/19/09 --- 10.0 3.80 B ND 2.80 B 5.20 B 3.70 B 3.90 B 4.40 B 4.5 B 4.10 B ND ------3.60 J07/20/09 --- 10.0 ND ND ND ND ND ND ND ND ND ND 4.02 J ND ND
01/25/10 --- 10.0 ND 4.61 J 3.57 J 5.19 J ND ND 4.10 J 4.24 J ND ND ------ND
07/06/10 --- 10.0 ND ND ND ND ND ND ND ND ND ND ------ND01/04/11 --- 10.0 3.06 J 5.85 J ND 6.00 J ND ND ND 8.04 J ND ND ------ND
07/05/11 --- 10.0 ND ND ND ND ND ND ND ND ND ND ------ND
01/09/12 --- 10.0 ND ND ND ND ND ND ND ND ND ND ------ND07/09/12 --- 10.0 ND 1.35 J 1.74 J 2.11 J 1.45 J 1.77 J ND ND ND ND ------ND01/28/13 --- 10.0 ND ND ND 3.49 J ND ND ND ND ND ND ------ND
07/17/13 --- 10.0 ND ND ND 3.68 J ND ND ND ND ND 0.93 J ------ND
01/28/14 --- 10.0 ND ND ND 0.85 J 1.06 J ---ND 1.23 J 0.94 J 1.80 J ------ND05/31/14 --- 10.0 ------------------------------ND ND ND06/24/14 --- 10.0 ------------------------------ND ND ND
07/24/14 1.13 10.0 ND ND ND ND ND ND ND ND ND ND ND ND ND
01/28/15 1.13 10.0 ND 1.65 J ND 1.43 J ND ND ND ND ND 2.98 J ND ND ND07/30/15 0.75 10.0 ---1.72 J ND ND ND ---ND 1.12 J ND 1.82 J 1.88 J ND ND
09/16/15 0.75 10.0 ND ---------------------------------ND
01/27/16 0.75 10.0 ND 0.75 J ND ND ND ---ND 3.17 J ND ND 0.85 J ND ND07/27/16 0.75 10.0 ND 1.4 J ND ND ND ND ND ND ND ND 0.85 J ND ND01/25/17 0.75 10.0 ND 0.92 J ND ND ND ND ND ND ND 1.07 J 1.10 J ND ND
Total Barium 10/28/98 --- 500 ND ND ND ND ND Dry ------------------NDNC 2L = 700 µg/L 04/07/99 --- 500 ND ND ND ND ND Dry ------------------ND
12/08/99 --- 500 ND ND ND ND ND ND ------------------ND
04/27/00 --- 500 ND ND ND ND ND Dry ------------------ND10/18/00 --- 500 ND ND ND ND ND Dry ND ---------------ND11/28/00 --- 500 ------------------ND ------------------
01/03/01 --- 500 ------------------ND ------------------
02/08/01 --- 500 ------------------ND ------------------04/19/01 --- 500 ND ND ND ---ND Dry ND ---------------ND12/24/01 --- 500 ND ND ND ND ND ND ND ---------------ND
04/23/02 --- 500 ND ND ND ND ND ND ND ---------------ND10/23/02 --- 500 ND ND ND ND ND ND ND ---------------ND04/01/03 --- 500 ND ND ND ND ND ND ND ---------------ND
10/28/03 --- 500 ND ND ND ND ND ND ND ---------------ND
04/27/04 --- 500 500 ND ND ND ND ND ND ---------------ND10/26/04 --- 500 ND ND ND ND ND ND ND ---------------ND03/15/05 --- 500 500 ND ND ND ND ND ND ---------------ND
07/12/05 --- 500 ND ND ND ND ND ND ND ---------------ND
01/12/06 --- 30 ---------------------ND ------------ND01/19/06 --- 500 523 ND ND ND ND ND ND ---------------ND
07/11/06 --- 500 517 ND ND ND ND ND ND ND ------------ND
10/31/06 --- 500 ---------------------ND ------------ND01/17/07 --- 100 516 122 137 82.1 95.7 17.8 273 98.3 ------------0.30 J07/09/07 --- 100 448 162 121 93.5 J 89.3 J 20.8 J 259 114 ------------0.80 J
01/14/08 --- 100 405 129 127 59.0 J 94.6 J 18.5 J 291 117 38 J ---------0.30 J
04/30/08 --- 100 ---------------------------106 ------0.50 J07/14/08 --- 100 500 130 123 76.0 J 103 18.7 J 317 94.7 J 32.2 J 127 ------ND
10/03/08 --- 100 ---------------------------116 ------ND
01/19/09 --- 100 534 135 148 62.9 J 88.4 J 20.1 J 357 116 41.2 J 138 ------ND07/20/09 --- 100 534 96.4 J 145 89.2 J 88.6 J 20.0 J 332 112 39.3 J 168 445 37.2 J ND01/25/10 --- 100 545 116 0.68 B 67.6 J 91.3 J 22.0 J 312 117 32.9 J 143 ------0.43 J
07/06/10 --- 100 419 49.1 J 103 89.2 J 73.5 J 18.1 J 245 92.7 J 32.5 J 117 ------ND
01/04/11 --- 100 409 100 120 207 92.8 J 21.8 J 261 105 37.8 J 156 ------1.11 J07/05/11 --- 100 455 53.8 J 119 167 101 27.5 J 317 115 41.5 J 149 ------ND01/09/12 --- 100 427 21.8 J 105 212 93.8 J 19.2 J 343 120 38.8 J 156 ------0.24 J
07/09/12 --- 100 414 45.1 J 108 196 114 21.1 J 369 124 46.9 J 135 ------0.75 J
01/28/13 --- 100 387 72.0 J 91.9 J 257 107 19.2 J 331 125 46.3 J 140 ------ND07/17/13 --- 100 426 72.0 86.9 J 186 91.2 J 21.2 J 318 154 55.3 J 150 ------0.37 J
01/28/14 --- 100 382 63.7 J 78.4 J 251 117 ---320 141 69.1 J 214 ------ND
05/31/14 --- 100 ------------------------------261 29.8 J ND06/24/14 --- 100 ------------------------------285 27.3 J ND07/24/14 0.10 100 390 42.7 J 91.1 J 222 107 48.2 J 233 123 64.6 J 146 209 23.9 J 0.32 J
01/28/15 0.10 100 370 71.3 J 83.0 J 241 124 30.7 J 332 127 59.8 J 340 237 28.6 J 0.12 J
07/30/15 0.30 100 ---53.2 J 110 171 106 ---308 144 84.4 J 179 237 26.7 J 0.45 J09/16/15 0.30 100 543 ---------------------------------0.47 J
01/27/16 0.30 100 377 46.9 J 118 180 109 ---344 547 51.2 J 159 220 30.0 J 0.42 J
07/27/16 0.30 100 357 40.1 J 122 151 109 30.4 J 307 159 104 144 192 28.2 J 0.31 J01/25/17 0.30 100 462 48.4 J 113 163 111 30.3 J 380 166 80.4 J 176 190 37.5 J 0.30 J
East Carolina Regional Landfill
Permit No. 08-03 Page 1 of 11 Joyce Engineering
TABLE 8
Historical Groundwater Constituents/Analytes
Sample
Analyte
Collection
Date DL SWSL GW-2 GW-7 GW-8 GW-9 GW-10 GW-11/11R GW-13 GW-15 GW-16R GW-17 GW-18 GW-21 Blanks
Total Beryllium 10/28/98 --- 2.00 ND ND ND ND ND Dry ------------------ND
GWPS = 4 µg/L 04/07/99 --- 2.00 ND 2.00 ND ND ND Dry ------------------ND
12/08/99 --- 2.00 ND ND ND ND ND ND ------------------ND04/27/00 --- 2.00 ND ND ND ND ND Dry ------------------ND10/18/00 --- 2.00 ND ND ND ND ND Dry ND ---------------ND
11/28/00 --- 2.00 ------------------ND ------------------
01/03/01 --- 2.00 ------------------ND ------------------02/08/01 --- 2.00 ------------------4.00 ------------------
04/19/01 --- 2.00 ND ND ND ---ND Dry ND ---------------ND
12/24/01 --- 2.00 ND ND ND ND ND ND ND ---------------ND04/23/02 --- 2.00 ND ND ND ND ND ND ND ---------------ND10/23/02 --- 2.00 ND 3.00 ND ND ND ND ND ---------------ND
04/01/03 --- 2.00 ND ND ND ND ND ND ND ---------------ND
10/28/03 --- 2.00 ND 3.00 ND ND ND ND ND ---------------ND04/27/04 --- 2.00 ND 3.00 ND ND ND ND ND ---------------ND
10/26/04 --- 2.00 ND 3.00 ND ND ND ND ND ---------------ND
03/15/05 --- 2.00 ND ND ND ND ND ND ND ---------------ND07/12/05 --- 2.00 ND 2.20 ND ND ND ND ND ---------------ND01/12/06 --- 2.00 ---------------------ND ------------ND
01/19/06 --- 2.00 ND 2.00 ND ND ND ND ND ---------------ND
07/11/06 --- 2.00 ND ND ND ND ND ND ND ND ------------ND10/31/06 --- 2.00 ---------------------ND ------------ND
01/17/07 --- 1.00 1.0 1.90 ND ND ND ND ND ND ------------ND
07/09/07 --- 1.00 0.7 J 1.90 ND ND ND ND ND ND ------------ND01/14/08 --- 1.00 ND 1.50 ND ND ND ND ND ND ND ---------ND04/30/08 --- 1.00 ---------------------------ND ------ND
07/14/08 --- 1.00 0.80 J 1.60 ND ND ND ND 0.10 J ND ND 0.10 J ------ND
10/03/08 --- 1.00 ---------------------------0.20 J ------ND01/19/09 --- 1.00 0.90 J 1.30 ND ND ND ND 0.30 J ND ND 0.10 J ------ND07/20/09 --- 1.00 1.3 2.11 0.80 J 0.49 J 0.252 B 0.39 J 0.60 J 0.31 B 0.12 B 0.59 J 1.66 0.359 B 0.0779 J
01/25/10 --- 1.00 1.34 2.11 1.52 0.46 J 0.256 J 0.45 J 0.61 J 0.35 J 0.15 J 0.35 J ------ND
07/06/10 --- 1.00 0.87 J 1.98 0.47 J 0.45 J 0.164 J 0.25 J 0.37 J 0.23 J ND 0.21 J ------ND01/04/11 --- 1.00 1.08 2.38 0.80 J 0.57 J 0.296 J 0.43 J 0.51 J 0.28 J 0.15 J 0.42 J ------ND
07/05/11 --- 1.00 0.98 J 2.01 0.70 J 0.95 J 0.312 J 0.40 J 0.56 J 0.30 J ND 0.38 J ------ND
01/09/12 --- 1.00 0.99 J 0.80 J 0.60 J 0.49 J 0.16 J 0.29 J 0.58 J 0.44 J 0.07 J 0.50 J ------ND07/09/12 --- 1.00 1.03 1.94 0.62 J 1.11 0.52 J 0.28 J 0.61 J 0.27 J 0.10 J 0.31 J ------ND01/28/13 --- 1.00 0.85 J 2.01 0.46 J 1.38 0.22 J 0.23 J 0.52 J 0.27 J ND 0.35 J ------ND
07/17/13 --- 1.00 1.23 2.19 0.57 J 1.34 0.12 J 0.36 J 0.64 J 1.05 0.15 J 0.43 J ------ND
01/28/14 --- 1.00 0.95 J 1.91 0.57 J 1.10 0.68 J ---0.61 J 0.50 J 0.25 J 0.83 J ------ND05/31/14 --- 1.00 ------------------------------1.27 0.09 J ND
06/24/14 --- 1.00 ------------------------------1.18 ND ND
07/24/14 0.05 1.00 1.02 1.68 0.55 J 1.05 0.34 J 0.69 J 0.39 J 0.29 J 0.15 J 0.29 J 0.91 J 0.09 J ND01/28/15 0.05 1.00 0.63 J 2.03 0.53 J 0.89 J 0.51 J 0.12 J 0.60 J 0.35 J 0.17 J 1.78 0.97 J 0.07 J ND07/30/15 0.09 1.00 ---1.65 0.60 J 0.97 J 0.24 J ---0.54 J 0.39 J 0.20 J 0.60 J 1.01 ND ND
09/16/15 0.09 1.00 0.94 J ---------------------------------ND
01/27/16 0.09 1.00 0.95 J 1.94 0.71 J 0.87 J 0.39 J ---0.62 J 32.0 0.11 J 0.45 J 0.94 J ND NDResample >>03/09/16 0.09 1.00 ---------------------0.90 J ------------ND07/27/16 0.09 1.00 0.85 J 1.65 0.70 J 0.87 J 0.29 J 0.14 J 0.56 J 0.43 J 0.21 J 0.29 J 0.83 J ND ND
01/25/17 0.09 1.00 1.03 1.60 0.64 J 0.95 J 0.23 J 0.12 J 0.64 J 0.48 J 0.17 J 0.55 J 0.77 J ND ND
Total Cadmium 10/28/98 --- 1.00 ND ND ND ND ND Dry ------------------ND
NC 2L = 2 µg/L 04/07/99 --- 1.00 ND ND ND ND ND Dry ------------------ND
12/08/99 --- 1.00 ND ND ND ND ND ND ------------------ND04/27/00 --- 1.00 ND ND ND ND ND Dry ------------------ND10/18/00 --- 1.00 ND ND ND ND ND Dry ND ---------------ND
11/28/00 --- 1.00 ------------------ND ------------------
01/03/01 --- 1.00 ------------------5.00 ------------------02/08/01 --- 1.00 ------------------ND ------------------
04/19/01 --- 1.00 ND ND ND ---ND Dry ND ---------------ND
12/24/01 --- 1.00 ND ND ND ND ND ND ND ---------------ND04/23/02 --- 1.00 ND ND ND ND ND ND ND ---------------ND10/23/02 --- 1.00 ND ND ND ND ND ND ND ---------------ND
04/01/03 --- 1.00 ND ND ND ND ND ND ND ---------------ND
10/28/03 --- 1.00 ND ND ND ND ND ND ND ---------------ND04/27/04 --- 1.00 ND ND ND ND ND ND ND ---------------ND
10/26/04 --- 1.00 ND ND ND ND ND ND ND ---------------ND
03/15/05 --- 1.00 ND ND ND ND ND ND ND ---------------ND07/12/05 --- 1.00 ND ND ND ND ND ND ND ---------------ND01/12/06 --- 1.00 ---------------------ND ------------ND
01/19/06 --- 1.00 ND ND ND ND ND ND ND ---------------ND
07/11/06 --- 1.00 ND ND ND ND ND ND ND ND ------------ND10/31/06 --- 1.00 ---------------------ND ------------ND01/17/07 --- 1.00 ND ND ND ND ND ND ND ND ------------ND
07/09/07 --- 1.00 ND ND ND ND ND ND ND ND ------------ND
01/14/08 --- 1.00 ND ND ND ND ND ND ND ND ND ---------ND04/30/08 --- 1.00 ---------------------------ND ------ND
07/14/08 --- 1.00 ND ND ND ND ND ND ND ND ND ND ------ND
10/03/08 --- 1.00 ---------------------------ND ------ND01/19/09 --- 1.00 ND ND ND ND ND ND ND ND ND ND ------ND07/20/09 --- 1.00 0.14 B 0.26 B 0.11 B ND 0.159 B 0.10 B ND ND 0.18 B 0.09 B 0.252 B 0.328 B 0.11 J
01/25/10 --- 1.00 0.39 B 0.35 B 1.59 0.88 B 0.357 B 0.26 B 0.33 B 0.391 B 0.36 B 0.43 B ------0.28 J
07/06/10 --- 1.00 ND ND ND ND ND ND ND ND ND ND ------ND01/04/11 --- 1.00 0.43 J ND ND ND ND ND ND ND ND ND ------ND
07/05/11 --- 1.00 ND ND ND ND ND ND ND ND ND ND ------ND
01/09/12 --- 1.00 ND ND ND ND ND ND ND ND ND ND ------ND07/09/12 --- 1.00 0.07 J ND ND ND ND ND ND 0.06 J 0.28 J ND ------ND01/28/13 --- 1.00 ND ND ND ND ND ND ND ND ND ND ------ND
07/17/13 --- 1.00 ND ND ND ND ND 0.19 J 0.14 J ND 0.19 J ND ------ND
01/28/14 --- 1.00 0.20 J 0.09 J ND ND 0.16 J ---ND 0.21 J 0.07 J ND ------ND05/31/14 --- 1.00 ------------------------------0.05 J ND ND
06/24/14 --- 1.00 ------------------------------ND ND ND
07/24/14 0.05 1.00 0.05 J ND ND ND ND 0.05 J ND ND ND ND 0.05 J ND ND01/28/15 0.05 1.00 ND 0.06 J 0.08 J ND 0.06 J ND 0.05 J ND ND 0.05 J ND ND ND07/30/15 0.1 1.00 ---0.93 J ND 0.24 J ND ---ND ND ND ND ND ND ND
09/16/15 0.1 1.00 0.15 J ---------------------------------ND
01/27/16 0.1 1.00 ND 0.10 J ND ND ND ---0.12 J 0.19 J ND ND ND ND ND07/27/16 0.1 1.00 ND ND ND ND ND ND ND ND ND ND ND ND ND01/25/17 0.1 1.00 ND 0.17 J ND 0.15 J ND ND ND ND ND ND ND ND ND
East Carolina Regional Landfill
Permit No. 08-03 Page 2 of 11 Joyce Engineering
TABLE 8
Historical Groundwater Constituents/Analytes
Sample
Analyte
Collection
Date DL SWSL GW-2 GW-7 GW-8 GW-9 GW-10 GW-11/11R GW-13 GW-15 GW-16R GW-17 GW-18 GW-21 Blanks
Total Chromium 10/28/98 --- 10.0 ND ND ND ND ND Dry ------------------ND
NC 2L = 10 µg/L 04/07/99 --- 10.0 ND ND ND ND ND Dry ------------------ND
12/08/99 --- 10.0 ND ND ND ND ND ND ------------------ND04/27/00 --- 10.0 ND ND ND ND ND Dry ------------------ND10/18/00 --- 10.0 ND ND ND ND ND Dry ND ---------------ND
11/28/00 --- 10.0 ------------------ND ------------------
01/03/01 --- 10.0 ------------------ND ------------------02/08/01 --- 10.0 ------------------ND ------------------
04/19/01 --- 10.0 ND ND ND ---ND Dry ND ---------------ND
12/24/01 --- 10.0 ND ND ND ND ND ND ND ---------------ND04/23/02 --- 10.0 ND ND 10.0 ND ND ND ND ---------------ND
10/23/02 --- 10.0 ND ND ND ND ND ND ND ---------------ND
04/01/03 --- 10.0 ND ND 10.0 ND ND ND ND ---------------ND10/28/03 --- 10.0 ND ND ND ND ND ND ND ---------------ND
04/27/04 --- 10.0 ND ND ND ND ND ND ND ---------------ND
10/26/04 --- 10.0 ND ND 10.0 ND ND ND ND ---------------ND03/15/05 --- 10.0 ND ND ND ND ND ND ND ---------------ND07/12/05 --- 10.0 ND ND ND ND ND ND ND ---------------ND
01/12/06 --- 10.0 ---------------------ND ------------ND
01/19/06 --- 10.0 ND ND ND ND ND ND ND ---------------ND07/11/06 --- 10.0 ND ND ND ND ND ND ND ND ------------ND10/31/06 --- 10.0 ---------------------ND ------------ND
01/17/07 --- 10.0 ND ND ND ND ND 4.30 J ND ND ------------ND
07/09/07 --- 10.0 ND ND ND ND ND 2.50 J ND ND ------------ND01/14/08 --- 10.0 2.60 J ND ND ND ND 5.90 J 3.80 J ND ND ---------ND
04/30/08 --- 10.0 ---------------------------8.80 J ------ND
07/14/08 --- 10.0 ND ND ND ND ND 2.80 J ND ND 1.40 J 2.0 J ------ND10/03/08 --- 10.0 ---------------------------1.60 J ------ND01/19/09 --- 10.0 3.70 J ND ND 1.20 J ND 4.60 J ND ND 3.0 J 1.6 J ------ND
07/20/09 --- 10.0 0.94 J 0.78 J 0.80 J ND ND 4.17 J ND 1.56 J 1.0 J 7.4 J 2.55 J 4.63 J ND
01/25/10 --- 10.0 ND ND ND ND ND 5.97 J ND ND ND ND ------ND07/06/10 --- 10.0 10.4 2.17 J 1.15 J ND ND 3.08 J ND ND ND 1.58 J ------ND
01/04/11 --- 10.0 1.46 J 4.26 J 1.42 J 4.41 J ND 4.82 J ND 1.23 J ND 5.21 J ------ND
07/05/11 --- 10.0 1.44 J 1.40 J ND 3.65 J 1.9 J 9.73 J ND 1.67 J ND 2.96 J ------ND01/09/12 --- 10.0 ND ND 0.60 J ND ND 4.20 J ND 2.62 J ND 4.00 J ------ND07/09/12 --- 10.0 1.88 J 2.28 J ND ND ND 3.82 J ND ND ND ND ------ND
01/28/13 --- 10.0 2.40 B 2.06 B 1.82 B 3.18 B 1.27 B 5.98 B 0.75 B 2.24 B 0.78 B 3.08 B ------1.38 J
07/17/13 --- 10.0 3.22 J 2.53 J 1.96 J 2.55 J ND 4.64 J ND 9.5 J ND 2.20 J ------ND01/28/14 --- 10.0 1.85 3.38 2.35 2.79 3.96 ---ND 2.85 4.98 11.1 ------2.84 J05/31/14 --- 10.0 ------------------------------2.18 B 2.93 B 3.93 J
06/24/14 --- 10.0 ------------------------------9.44 B 7.42 B 8.19 J07/24/14 0.73 10.0 0.83 J 1.32 J ND ND ND 6.64 J ND ND ND ND ND ND ND01/28/15 0.73 10.0 1.86 J 2.84 J 1.00 J ND 2.27 J 1.78 J ND 1.98 J 1.45 J 32.4 1.34 J ND ND
Resample >>03/05/15 --- 10.0 ---------------------------9.28 J ------ND
07/30/15 0.43 10.0 ---2.02 J ND ND ND ---ND 0.89 J ND 9.48 J 0.91 J ND ND09/16/15 0.43 10.0 1.82 J ---------------------------------ND01/27/16 0.43 10.0 2.86 J 1.90 J 0.98 J 1.31 J 0.49 J ---1.25 J 90.0 0.47 J 9.39 J 1.25 J 0.48 J ND
Resample >>03/09/16 0.09 1.00 ---------------------13.0 ------------0.49 J
07/27/16 0.43 10.00 1.55 J 1.20 J 1.04 J 0.57 J ND 4.28 J 0.54 J 3.11 J ND 2.95 J 0.84 J ND ND01/25/17 0.43 10.00 5.98 J 3.31 J 2.92 J 1.45 J 0.56 J 3.98 J 0.97 J 4.32 J 0.49 J 11.1(10.0) 1.24 J ND ND
Total Cobalt 10/28/98 --- 10.0 ND 30 ND ND ND Dry ------------------NDGWPS = 1 µg/L 04/07/99 --- 10.0 ND 20 ND ND ND Dry ------------------ND12/08/99 --- 10.0 10 20 ND ND ND ND ------------------ND
04/27/00 --- 10.0 ND 30 ND ND ND Dry ------------------ND
10/18/00 --- 10.0 ND 30 ND ND ND Dry 30.00 ---------------ND11/28/00 --- 10.0 ------------------10.00 ------------------
01/03/01 --- 10.0 ------------------ND ------------------
02/08/01 --- 10.0 ------------------ND ------------------04/19/01 --- 10.0 ND 30 ND ---ND Dry ND ---------------ND12/24/01 --- 10.0 ND 30 ND ND ND ND ND ---------------ND
04/23/02 --- 10.0 ND 30 ND ND ND ND ND ---------------ND
10/23/02 --- 10.0 ND 50 ND ND ND ND ND ---------------ND04/01/03 --- 10.0 10 40 ND ND ND ND ND ---------------ND10/28/03 --- 10.0 ND 50 ND ND ND ND ND ---------------ND
04/27/04 --- 10.0 ND 30 ND ND ND ND ND ---------------ND10/26/04 --- 10.0 ND 40 ND ND ND ND ND ---------------ND03/15/05 --- 10.0 10 36 ND ND ND ND ND ---------------ND
07/12/05 --- 10.0 ND 40 ND ND ND ND ND ---------------ND
01/12/06 --- 10.0 ---------------------ND ------------ND01/19/06 --- 10.0 11.9 30 ND ND ND ND ND ---------------ND07/11/06 --- 10.0 12.5 31.6 ND ND ND ND ND ND ------------ND
10/31/06 --- 10.0 ---------------------ND ------------ND
01/17/07 --- 10.0 10.30 34.9 3.9 J ND ND ND 3.0 J 2.90 J ------------ND07/09/07 --- 10.0 10.00 37.5 2.9 J ND ND ND ND 2.60 J ------------ND
01/14/08 --- 10.0 11.30 35.1 4.2 J 3.20 J 3.8 J 2.0 J 3.30 J 3.40 J 2.60 J ---------ND
04/30/08 --- 10.0 --------------------------- 20.50 ------ND07/14/08 --- 10.0 10.10 37.3 2.6 J ND ND ND 2.70 J 2.10 J 1.20 J 4.50 J ------ND10/03/08 --- 10.0 ---------------------------6.30 J ------ND
01/19/09 --- 10.0 12.0 23.7 3.7 J 3.00 J 4.6 J ND 1.80 J 1.70 J 1.80 J 5.20 J ------ND
07/20/09 --- 10.0 11.40 35.4 3.93 J 1.47 J 2.91 J 0.59 J 2.00 J 2.67 J 0.77 J 3.93 J 7.69 J 0.895 J ND01/25/10 --- 10.0 12.6 21.5 2.0 B 2.46 J 0.858 B 1.6 B 2.71 J 3.62 J 1.57 B 3.02 B ------0.49 J
07/06/10 --- 10.0 8.59 J 26.6 2.62 J 1.15 J ND ND 1.66 J 2.07 J 1.89 J 2.14 J ------ND
01/04/11 --- 10.0 9.65 J 29.8 3.63 J 3.19 J ND 1.19 J 2.24 J 2.6 J 1.77 J 5.07 J ------ND07/05/11 --- 10.0 10.40 39.0 3.19 J 2.17 J 2.03 J 1.40 J 2.34 J 2.8 J 2.18 J 3.65 J ------ND
01/09/12 --- 10.0 9.51 J 13.8 2.92 J 2.44 J 1.63 J 0.73 J 2.73 J 3.29 J 1.84 J 3.93 J ------ND
07/09/12 --- 10.0 9.76 J 26.1 3.39 J 2.19 J 2.52 J 0.78 J 3.44 J 2.94 J 3.29 J 3.13 J ------ND01/28/13 --- 10.0 9.53 J 33.3 2.98 J 2.84 J 3.22 J 0.82 J 3.28 J 3.13 J 1.83 J 3.49 J ------ND07/17/13 --- 10.0 10.80 28.0 2.50 J 2.67 J 1.14 J 0.95 J 2.89 J 6.64 J 3.91 J 3.79 J ------ND
01/28/14 --- 10.0 9.72 J 28.2 2.24 J 2.88 J 7.80 J ---2.83 J 4.06 J 4.70 J 5.35 J ------ND
05/31/14 --- 10.0 ------------------------------5.78 J 0.42 J ND06/24/14 --- 10.0 ------------------------------5.64 J ND ND
07/24/14 0.26 10.0 9.08 J 23.0 2.53 J 2.50 J 5.34 J 9.10 J 2.02 J 2.92 J 2.93 J 2.56 J 4.06 J 0.33 J ND
01/28/15 0.26 10.0 6.52 J 34.3 2.35 J 2.82 J 8.05 J 2.81 J 3.29 J 3.25 J 7.03 J 11.9 4.83 J 0.33 J ND07/30/15 0.29 10.0 ---38.0 3.13 J 2.02 J 4.38 J ---3.06 J 3.50 J 5.08 J 3.93 J 4.88 J ND ND09/16/15 0.29 10.0 10.2 ---------------------------------ND
01/27/16 0.29 10.0 8.44 J 34.0 3.83 J 2.25 J 7.67 J ---2.37 J 34.1 4.78 J 3.11 J 4.47 J ND ND
Resample >>03/09/16 0.09 1.00 ---------------------6.5 J ------------ND07/27/16 0.29 10.00 8.68 J 37.40 4.21 J 2.05 J 6.98 J 2.26 J 4.28 J 4.61 J 3.88 J 2.35 J 4.19 J ND ND
01/25/17 0.29 10.00 8.57 J 29.8 (33.0)3.96 J 2.23 J 4.3 J 1.81 J 4.94 J 4.16 J 3.82 J 3.32 J 4.15 J 0.30 J ND
East Carolina Regional Landfill
Permit No. 08-03 Page 3 of 11 Joyce Engineering
TABLE 8
Historical Groundwater Constituents/Analytes
Sample
Analyte
Collection
Date DL SWSL GW-2 GW-7 GW-8 GW-9 GW-10 GW-11/11R GW-13 GW-15 GW-16R GW-17 GW-18 GW-21 Blanks
Total Copper 07/12/05 --- 200 ND ND ND ND ND ND ND ---------------ND
NC 2L = 1000 µg/L 01/19/06 --- 200 ND ND ND ND ND ND ND ---------------ND
07/11/06 --- 200 ND ND ND ND ND ND ND ND ------------ND10/31/06 --- 200 ---------------------ND ------------ND01/17/07 --- 10.0 ND 0.80 J ND ND ND ND ND ND ------------ND
07/09/07 --- 10.0 ND 5.40 J ND ND 1 J ND ND ND ------------ND
01/14/08 --- 10.0 4.70 J 1.60 B 1.30 B 1.30 B ND 1.00 B 0.80 B 0.8 B 1.10 B ---------0.70 J04/30/08 --- 10.0 ---------------------------2.60 B ------1.40 J
07/14/08 --- 10.0 ND ND ND ND ND ND ND ND ND ND ------ND
10/03/08 --- 10.0 ---------------------------ND ------ND01/19/09 --- 10.0 ND ND 1.70 J ND ND ND ND ND 2.00 J ND ------ND07/20/09 --- 10.0 ND ND 0.868 B ND ND ND ND ND ND 2.19 B ND 1.09 B 1.25 J
01/25/10 --- 10.0 ND ND ND ND ND ND ND ND ND ND ------ND07/06/10 --- 10.0 ND ND ND 2.56 J ND ND ND ND ND ND ------ND
01/04/11 --- 10.0 2.3 J 2.16 J ND 3.09 J 1.8 J 4.68 J ND ND ND 3.49 J ------ND
07/05/11 --- 10.0 8.78 J 1.60 J ND 2.66 J ND ND ND ND ND ND ------ND01/09/12 --- 10.0 1.57 B 1.54 B 1.06 B 0.62 B 0.62 B 0.68 B 0.59 B 1.87 B 0.32 B 2.32 B ------0.66 J07/09/12 --- 10.0 1.24 J 0.88 J 0.31 J ND 0.64 J 0.24 J ND ND 0.65 J 0.45 J ------ND
01/28/13 --- 10.0 1.12 B 1.13 B 1.23 B 1.39 B 1.45 B 1.15 B 0.84 B 1.19 B 0.46 B 1.74 B ------0.26 J
07/17/13 --- 10.0 1.67 J 1.18 J 1.05 J 1.15 J 0.63 J 1.03 J 0.39 J 3.59 J 0.91 J 1.73 J ------ND01/28/14 --- 10.0 2.05 J 1.48 J 1.51 J 0.68 J 1.65 J ---ND 1.96 J 4.48 J 5.79 J ------ND05/31/14 --- 10.0 ------------------------------0.98 J 0.81 J ND
06/24/14 --- 10.0 ------------------------------0.79 B 0.42 B 0.23 J
07/24/14 0.22 10.0 1.39 J 3.05 J 1.09 J 0.50 J 0.45 J 3.19 J 0.25 J 0.54 J 0.32 J 0.93 J 0.39 J 0.46 J ND01/28/15 0.22 10.0 1.38 J 1.68 J 2.16 J 0.72 J 7.30 J 4.40 J 0.56 J 0.73 J 1.26 J 13.6 0.64 J 0.49 J ND
07/30/15 0.41 10.0 ---8.18 J 1.38 B 1.27 B 7.65 J ---0.42 B 0.89 B 0.56 B 4.4 B 0.51 B ND 1.31 J
09/16/15 0.41 10.0 2.32 J ---------------------------------ND01/27/16 0.41 10.0 1.28 B 1.24 B 0.41 B ND 0.61 B ---1.43 B 25.0 0.54 B 2.89 B 0.61 B ND 2.44 J07/27/16 0.41 10.0 0.76 B 1.13 B ND ND 2.49 B 0.66 B ND 0.98 B 1.19 B 1.21 B 0.55 B ND 8.47 J
01/25/17 0.41 10.0 3.61 B 2.55 B ND ND 0.92 B 0.68 B 6.15 J 1.00 B 0.42 B 4.83 B 0.65 B ND 0.59 J
Total Lead 10/28/98 --- 10.0 ND ND ND ND ND Dry ------------------ND
NC 2L = 15 µg/L 04/07/99 --- 10.0 ND ND ND ND ND Dry ------------------ND
12/08/99 --- 10.0 ND ND ND ND ND ND ------------------ND04/27/00 --- 10.0 ND ND ND ND ND Dry ------------------ND10/18/00 --- 10.0 ND ND ND ND ND Dry ND ---------------ND
11/28/00 --- 10.0 ------------------ND ------------------
01/03/01 --- 10.0 ------------------ND ------------------02/08/01 --- 10.0 ------------------ND ------------------04/19/01 --- 10.0 ND ND ND ---ND Dry ND ---------------ND
12/24/01 --- 10.0 ND ND ND ND ND ND ND ---------------ND04/23/02 --- 10.0 ND ND ND ND ND ND ND ---------------ND10/23/02 --- 10.0 ND ND ND ND ND ND ND ---------------ND
04/01/03 --- 10.0 ND ND ND ND ND ND ND ---------------ND
10/28/03 --- 10.0 ND ND ND ND ND ND ND ---------------ND04/27/04 --- 10.0 ND ND ND ND ND ND ND ---------------ND10/26/04 --- 10.0 ND ND ND ND ND ND ND ---------------ND
03/15/05 --- 10.0 ND ND ND ND ND ND ND ---------------ND
07/12/05 --- 10.0 ND ND ND ND ND ND ND ---------------ND01/12/06 --- 10.0 ---------------------ND ------------ND
01/19/06 --- 10.0 ND ND ND ND ND ND ND ---------------ND
07/11/06 --- 10.0 ND ND ND ND ND ND ND ND ------------ND10/31/06 --- 10.0 ---------------------ND ------------ND01/17/07 --- 10.0 ND 2.30 J ND ND ND ND ND ND ------------ND
07/09/07 --- 10.0 2.30 J 2.90 J 2.90 J ND ND 2.00 J ND 2.2 J ------------ND
01/14/08 --- 10.0 ND ND ND ND ND ND ND ND ND ---------ND04/30/08 --- 10.0 ---------------------------4.30 J ------ND
07/14/08 --- 10.0 ND ND ND ND ND ND ND ND ND 2.10 J ------ND
10/03/08 --- 10.0 ---------------------------2.20 J ------ND01/19/09 --- 10.0 ND ND ND ND ND ND ND ND ND ND ------ND07/20/09 --- 10.0 2.82 B 2.21 B ND 1.71 B 2.73 B ND ND ND 2.68 B 6.81 B 6.11 B 5.83 B 2.16 J
01/25/10 --- 10.0 ND 1.70 J 7.56 J 1.55 J ND ND ND ND ND 2.06 J ------ND
07/06/10 --- 10.0 ND 2.40 J ND ND ND ND ND ND ND ND ------ND01/04/11 --- 10.0 ND 3.03 J ND ND ND ND ND ND ND ND ------ND07/05/11 --- 10.0 ND 3.52 J ND 2.16 J ND ND ND ND ND ND ------ND
01/09/12 --- 10.0 0.77 B 1.21 B 0.47 B 0.75 B 0.45 B 0.20 B 2.43 B 2.33 B 0.43 B 3.19 B ------0.94 J07/09/12 --- 10.0 0.84 J 2.69 J 0.22 J 0.29 J 0.37 J ND 0.21 J 0.11 J 0.21 J 1.34 J ------ND01/28/13 --- 10.0 0.25 J 1.14 J 0.22 J 1.77 J 0.52 J ND 0.24 J 0.11 J 0.36 J 2.73 J ------ND
07/17/13 --- 10.0 0.68 J 1.55 J 0.42 J 0.76 J 0.11 J 0.15 J 0.18 J 3.59 J 0.57 J 2.43 J ------ND
01/28/14 --- 10.0 0.34 J 1.25 J 0.56 J 0.26 J 1.57 J ---0.23 J 0.98 J 7.74 J 11.7 ------ND05/31/14 --- 10.0 ------------------------------2.40 J 2.59 J ND06/24/14 --- 10.0 ------------------------------3.26 J 0.70 J ND
07/24/14 0.05 10.0 0.27 J 1.62 J 0.23 J 0.11 J 0.66 J 2.07 J 0.13 J 0.05 J 0.48 J 0.96 J 2.78 J 1.62 J ND
01/28/15 0.05 10.0 0.18 B 1.94 J 0.21 B 0.06 B 1.55 B 0.10 B 0.38 B ND 1.95 J 18.3 2.35 J 1.35 B 0.34 JResample >>03/05/15 0.05 10.0 ---------------------------3.39 J ------ND
07/30/15 0.08 10.0 ---1.63 J 0.18 J 0.26 J 0.66 J ---0.20 J 0.30 J 0.78 J 4.06 J 2.63 J 0.74 J ND
09/16/15 0.08 10.0 0.43 J ---------------------------------ND01/27/16 0.08 10.0 0.27 J 0.78 J 0.16 J 0.21 J 0.14 J ---0.29 J 34.4 0.93 J 2.77 J 2.46 J 0.91 J NDResample>>03/09/16 0.09 1.00 ---------------------2.6 J ------------ND
07/27/16 0.08 10.00 0.10 J 0.73 J 0.16 J ND 0.4 J 0.30 J 0.21 J 0.53 J 1.12 J 0.87 J 2.26 J 0.86 J ND
01/25/17 0.08 10.00 2.02 J 1.44 J 0.26 J 0.40 J 0.17 J 0.25 J 0.49 J 0.80 J 1.30 J 5.16 J 2.99 J 1.03 J ND
East Carolina Regional Landfill
Permit No. 08-03 Page 4 of 11 Joyce Engineering
TABLE 8
Historical Groundwater Constituents/Analytes
Sample
Analyte
Collection
Date DL SWSL GW-2 GW-7 GW-8 GW-9 GW-10 GW-11/11R GW-13 GW-15 GW-16R GW-17 GW-18 GW-21 Blanks
Total Nickel 10/28/98 --- 50.0 ND ND ND ND ND Dry ------------------ND
NC 2L = 100 µg/L 04/07/99 --- 50.0 ND ND ND ND ND Dry ------------------ND
12/08/99 --- 50.0 ND ND ND ND ND ND ------------------ND04/27/00 --- 50.0 ND ND ND ND ND Dry ------------------ND10/18/00 --- 50.0 ND ND ND ND ND Dry ND ---------------ND
11/28/00 --- 50.0 ------------------ND ------------------
01/03/01 --- 50.0 ------------------ND ------------------02/08/01 --- 50.0 ------------------ND ------------------
04/19/01 --- 50.0 ND ND ND ---ND Dry ND ---------------ND
12/24/01 --- 50.0 ND ND ND ND ND ND ND ---------------ND04/23/02 --- 50.0 ND ND ND ND ND ND ND ---------------ND10/23/02 --- 50.0 ND ND ND ND ND ND ND ---------------ND
04/01/03 --- 50.0 ND ND 20.00 ND ND ND ND ---------------ND
10/28/03 --- 50.0 ND ND ND ND ND ND ND ---------------ND
04/27/04 --- 50.0 ND ND ND ND ND ND ND ---------------ND
10/26/04 --- 50.0 ND ND ND ND ND ND ND ---------------ND03/15/05 --- 50.0 ND ND ND ND ND ND ND ---------------ND07/12/05 --- 50.0 ND ND ND ND ND ND ND ---------------ND
01/12/06 --- 50.0 ---------------------ND ------------ND
01/19/06 --- 50.0 ND ND ND ND ND ND ND ---------------ND07/11/06 --- 50.0 ND ND ND ND ND ND ND ND ------------ND10/31/06 --- 50.0 ---------------------ND ------------ND
01/17/07 --- 50.0 7.40 J 10.40 3.70 J 4.10 J ND ND 3.00 J 3.6 J ------------ND
07/09/07 --- 50.0 6.00 J 9.10 J 3.80 J 2.00 J ND ND 2.30 J 2.5 J ------------ND01/14/08 --- 50.0 11.00 J 8.00 J 5.80 J 3.70 J 2.0 J 3.20 J 4.70 J 3.8 J ND ---------ND
04/30/08 --- 50.0 ---------------------------4.10 J ------ND
07/14/08 --- 50.0 3.90 J 7.10 J 2.40 J 2.00 J ND ND 2.50 J ND ND ND ------ND
10/03/08 --- 50.0 ---------------------------2.40 J ------ND
01/19/09 --- 50.0 7.80 B 7.10 B 3.40 B 4.10 B 3.1 B 2.40 B 4.40 B 5.2 B ND ND ------2.20 J07/20/09 --- 50.0 6.08 J 9.00 J 3.27 J 3.03 J 1.07 J 0.72 J 2.48 J 2.59 J ND 2.56 J 9.37 J 1.49 J ND01/25/10 --- 50.0 4.55 J 6.31 J ND ND ND ND ND 1.75 J ND ND ------ND
07/06/10 --- 50.0 5.31 J 10.00 J ND ND ND ND ND ND ND ND ------ND
01/04/11 --- 50.0 6.42 J 9.32 J 2.17 J 4.60 J ND ND 2.50 J 2.92 J ND 2.54 J ------ND07/05/11 --- 50.0 6.82 J 10.60 J 2.64 J 6.35 J ND ND 2.94 J 3.22 J ND ND ------ND
01/09/12 --- 50.0 6.14 J 6.14 J 3.28 J 6.42 J 1.37 J 1.14 J 3.10 J 3.66 J 0.67 J 1.76 J ------ND
07/09/12 --- 50.0 7.09 J 10.80 J 2.78 J 6.67 J 1.68 J 1.45 J 3.75 J 3.52 J 0.70 J 1.16 J ------ND01/28/13 --- 50.0 7.35 J 9.57 J 2.6 J 8.82 J 5.06 J 2.37 J 3.48 J 3.57 J 0.74 J 1.70 J ------ND07/17/13 --- 50.0 7.88 J 9.55 J 2.48 J 6.23 J 1.52 J 1.43 J 2.75 J 5.84 J 1.31 J 2.04 J ------ND
01/28/14 --- 50.0 7.86 J 13.60 J 3.19 J 8.60 J 3.67 J ---3.25 J 5.79 J 2.88 J 3.37 J ------ND
05/31/14 --- 50.0 ------------------------------6.80 J 0.59 J ND06/24/14 --- 50.0 ------------------------------6.61 J ND ND
07/24/14 0.22 50.0 7.21 J 8.60 J 2.36 J 7.56 J 2.59 J 5.87 J 1.86 J 3.2 J 1.07 J 1.29 J 4.58 J 0.38 J ND
01/28/15 0.22 50.0 6.07 J 10.6 J 2.55 J 9.41 J 5.19 J 1.76 J 3.13 J 3.68 J 1.41 J 5.89 J 5.64 J 0.41 J ND07/30/15 0.48 50.0 ---15.4 J 2.84 J 6.23 J 2.67 J ---2.81 J 3.54 J 1.24 J 2.43 J 5.45 J ND ND09/16/15 0.48 50.0 8.68 J ---------------------------------ND
01/27/16 0.48 50.0 8.04 J 9.75 J 3.21 J 6.79 J 3.38 J ---11.3 J 25.8 J 0.82 J 2.82 J 4.66 J ND ND
07/27/16 0.48 50.0 7.78 J 8.86 J 3.68 J 5.87 J 4.23 J 1.98 J 3.76 J 4.42 J 1.54 J 1.55 J 4.54 J ND ND01/25/17 0.48 50.0 7.01 J 20.2 J 6.3 J 10.5 J 2.96 J 2.1 J 6.4 J 4.59 J 1.28 J 2.2 J 4.41 J ND ND
Total Selenium 07/12/05 --- 20.0 ND ND ND ND ND ND ND ---------------NDNC 2L = 20 µg/L 01/19/06 --- 20.0 ND ND ND ND ND ND ND ---------------ND07/11/06 --- 20.0 ND ND ND ND ND ND ND ND ------------ND
10/31/06 --- 20.0 ---------------------ND ------------ND
01/17/07 --- 10.0 ND ND ND ND ND ND ND ND ------------ND07/09/07 --- 10.0 ND ND ND ND 2.0 J ND ND ND ------------ND01/14/08 --- 10.0 2.30 J ND 2.00 J ND ND ND ND 2.3 J ND ---------ND
04/30/08 --- 10.0 ---------------------------ND ------ND
07/14/08 --- 10.0 ND 3.30 J ND ND ND ND 2.90 J ND 2.70 J ND ------ND10/03/08 --- 10.0 ---------------------------ND ------ND
01/19/09 --- 10.0 5.60 J ND 4.40 J 2.90 J ND ND ND ND ND ND ------ND
07/20/09 --- 10.0 ND 4.33 B 3.90 B ND 5.08 B ND ND ND ND 4.21 B 7.32 B 8.27 B 3.58 J01/25/10 --- 10.0 ND 1.62 J 1.08 J 1.86 J 1.32 J ND ND 0.918 J 0.88 J 0.86 J ------ND07/06/10 --- 10.0 ND ND ND ND ND ND ND ND ND ND ------ND
01/04/11 --- 10.0 ND ND ND 1.89 J ND ND ND ND ND ND ------ND
07/05/11 --- 10.0 ND ND ND ND ND ND ND ND ND ND ------ND01/09/12 --- 10.0 ND ND ND 0.80 J ND ND ND ND ND ND ------ND
07/09/12 --- 10.0 ND 1.43 ND ND ND ND ND ND ND ND ------ND
01/28/13 --- 10.0 ND 1.10 J ND 1.49 J ND ND ND ND ND ND ------ND07/17/13 --- 10.0 ND 1.44 J ND 1.09 J ND ND ND ND ND ND ------ND01/28/14 --- 10.0 ND 0.83 J ND 1.02 J ND ---ND ND ND ND ------ND
05/31/14 --- 10.0 ------------------------------ND ND ND
06/24/14 --- 10.0 ------------------------------1.28 J ND ND07/24/14 1.01 10.0 ND 1.20 J ND ND ND ND ND ND ND ND ND ND ND01/28/15 1.01 10.0 ND ND ND ND ND ND ND ND ND ND ND ND ND
07/30/15 0.85 10.0 ---6.23 J 0.91 J ND ND ---ND ND ND 2.55 J 5.11 J ND ND09/16/15 0.85 10.0 ND ---------------------------------ND01/27/16 0.85 10.0 ND 3.63 J ND ND ND ---ND 7.07 J ND 1.10 J 3.58 J ND ND
07/27/16 0.85 10.0 ND 5.56 J ND ND ND ND ND ND ND ND 3.49 J ND ND
01/25/17 0.85 10.0 1.3 J 4.54 J ND ND ND ND ND ND ND 2.19 J 3.77 J ND ND
Total Silver 07/12/05 --- 10.0 ND ND ND ND ND ND ND ---------------ND
NC 2L = 20 µg/L 01/19/06 --- 10.0 ND ND ND ND ND ND ND ---------------ND07/11/06 --- 10.0 ND ND ND ND ND ND ND ND ------------ND
10/31/06 --- 10.0 ---------------------ND ------------ND
01/17/07 --- 10.0 ND ND ND ND ND ND ND ND ------------ND07/09/07 --- 10.0 ND ND ND ND ND ND ND ND ------------ND01/14/08 --- 10.0 2.10 J ND ND 3.10 J ND ND ND 2.1 J ND ---------ND
04/30/08 --- 10.0 ---------------------------ND ------ND
07/14/08 --- 10.0 ND ND ND ND ND ND ND ND ND ND ------ND10/03/08 --- 10.0 ---------------------------ND ------ND01/19/09 --- 10.0 ND ND ND ND ND ND ND ND 3.60 J ND ------ND
07/20/09 --- 10.0 ND ND ND ND ND ND ND ND ND 2.05 J ND 2.61 J ND
01/25/10 --- 10.0 1.59 B 1.20 B 6.82 J 1.68 B 1.76 B 1.55 B 1.79 B 1.74 B 2.07 B 2.55 B ------1.25 J07/06/10 --- 10.0 ND ND ND ND ND ND ND ND ND ND ------ND
01/04/11 --- 10.0 ND ND ND ND ND ND ND ND ND ND ------ND
07/05/11 --- 10.0 ND ND ND ND ND ND ND ND ND ND ------ND01/09/12 --- 10.0 ND 1.58 J ND ND ND ND 0.43 J 0.27 J ND 0.83 J ------ND07/09/12 --- 10.0 ND 0.25 J ND 0.50 J 0.43 J 0.68 J 1.00 J 0.83 J ND 1.25 J ------ND
01/28/13 --- 10.0 ND 0.34 J ND 0.90 J 1.17 J 0.86 J 1.09 J 0.17 J ND 2.13 J ------ND
07/17/13 --- 10.0 ND ND ND 0.27 J ND ND ND 1.64 J ND 5.64 J ------ND01/28/14 --- 10.0 ND 0.57 J ND ND 1.02 J ---ND 16.0 1.91 J 3.70 J ------ND
05/31/14 --- 10.0 ------------------------------ND ND ND
06/24/14 --- 10.0 ------------------------------ND ND ND07/24/14 0.17 10.0 ND 0.23 J ND ND 0.80 J ND 0.32 J 4.32 J ND 6.50 J ND ND ND01/28/15 0.17 10.0 ND 3.68 J 0.44 J 0.32 J 2.94 J ND 1.01 J 0.18 J 0.49 J 5.38 J ND ND ND
07/30/15 0.22 10.0 ---16.9 ND 0.29 J 0.58 J ---0.57 J ND ND 4.62 J ND ND ND
09/16/15 0.22 10.0 4.27 B ---------------------------------4.12 J01/27/16 0.22 10.0 ND 1.27 J ND ND ND ---18.1 1.02 J ND 5.21 J ND ND ND07/27/16 0.22 10.0 ND 0.93 J ND ND 0.94 J ND ND 0.78 J ND 6.45 J ND ND ND
01/25/17 0.22 10.0 ND 52.9(40.9)ND 4.98 J 1.01 J ND 5.4 J ND 0.38 J 4.84 J ND ND NDResample >>04/05/17 0.22 10.0 ---0.81 J ------------------------------ND
East Carolina Regional Landfill
Permit No. 08-03 Page 5 of 11 Joyce Engineering
TABLE 8
Historical Groundwater Constituents/Analytes
Sample
Analyte
Collection
Date DL SWSL GW-2 GW-7 GW-8 GW-9 GW-10 GW-11/11R GW-13 GW-15 GW-16R GW-17 GW-18 GW-21 Blanks
Total Thallium 07/12/05 --- 10.0 ND ND ND ND ND ND ND ---------------ND
GWPS = 0.2 µg/L 01/19/06 --- 10.0 ND ND ND ND ND ND ND ---------------ND
07/11/06 --- 10.0 ND ND ND ND ND ND ND ND ------------ND10/31/06 --- 10.0 ---------------------ND ------------ND01/17/07 --- 5.50 0.07 J 0.05 J ND ND ND ND 0.05 J ND ------------ND
07/09/07 --- 5.50 0.07 J 0.05 J 0.06 J 0.05 J ND ND 0.06 J ND ------------ND
01/14/08 --- 5.50 0.08 J 0.07 J ND ND ND ND 0.06 J ND ND ---------ND04/30/08 --- 5.50 ---------------------------0.14 J ------ND
07/14/08 --- 5.50 ND ND ND ND ND ND ND ND ND ND ------ND
10/03/08 --- 5.50 ---------------------------0.16 J ------ND01/19/09 --- 5.50 ND ND ND ND ND ND ND ND ND ND ------ND07/20/09 --- 5.50 0.04 J 0.05 J ND ND ND ND ND ND ND ND ND ND ND
01/25/10 --- 5.50 0.12 J 0.15 J ND ND ND ND ND ND ND ND ------ND
07/06/10 --- 5.50 ND ND ND ND ND ND ND ND ND ND ------ND01/04/11 --- 5.50 ND 0.12 J ND ND ND ND ND ND ND ND ------ND
07/05/11 --- 5.50 ND ND ND ND ND ND ND ND ND ND ------ND
01/09/12 --- 5.50 ND ND ND ND ND ND ND ND ND ND ------ND07/09/12 --- 5.50 ND ND ND ND ND ND ND ND ND ND ------ND01/28/13 --- 5.50 ND ND ND ND ND ND ND ND ND ND ------ND
07/17/13 --- 5.50 0.15 J 0.10 J ND ND ND ND ND ND ND ND ------ND
01/28/14 --- 5.50 0.13 J 0.09 J ND ND ND ---ND ND ND 0.08 J ------ND05/31/14 --- 5.50 ------------------------------ND ND ND
06/24/14 --- 5.50 ------------------------------ND ND ND
07/24/14 0.09 5.50 ND ND ND ND ND ND ND ND ND ND ND ND ND01/28/15 0.09 5.50 ND ND ND ND ND ND ND ND ND ND ND ND ND07/30/15 0.06 5.50 ---1.10 J ND ND ND ---ND ND 0.09 J ND ND ND ND
09/16/15 0.06 5.50 0.06 J ---------------------------------ND
01/27/16 0.06 5.50 ND 0.17 J ND ND ND ---ND 0.33 J ND 0.07 J ND ND ND07/27/16 0.06 5.50 0.16 J 0.09 J ND ND ND ND ND ND ND ND ND ND ND01/25/17 0.06 5.50 0.14 J 0.08 J ND ND ND ND 0.06 J ND ND 0.09 J ND ND ND
Total Vanadium 07/12/05 --- 40.0 ND ND ND ND ND ND ND ---------------NDGWPS = 0.3 µg/L 01/19/06 --- 40.0 ND ND ND ND ND ND ND ---------------ND
07/11/06 --- 40.0 ND ND ND ND ND ND ND ND ------------ND
10/31/06 --- 40.0 ---------------------ND ------------ND01/17/07 --- 25.0 ND ND ND ND ND ND 1.00 J 1.1 J ------------ND07/09/07 --- 25.0 ND ND ND 1.50 B ND ND ND ND ------------1.00 J
01/14/08 --- 25.0 1.60 B ND 1.10 B 2.70 B ND 2.00 B ND 1 B ND ---------1.00 J
04/30/08 --- 25.0 --------------------------- 13.70 J ------1.30 J07/14/08 --- 25.0 ND ND ND ND ND ND ND ND ND 2.00 J ------ND
10/03/08 --- 25.0 ---------------------------ND ------ND
01/19/09 --- 25.0 ND ND ND ND ND ND ND ND 1.40 J ND ------ND07/20/09 --- 25.0 1.55 B 0.78 B ND 1.63 B ND ND 0.75 B 0.856 B 0.89 B 10.40 J 4.71 J 9.74 J 0.803 J01/25/10 --- 25.0 ND ND 3.64 J ND ND 1.83 J ND ND ND 0.51 J ------ND
07/06/10 --- 25.0 ND ND ND ND ND ND ND ND ND ND ------ND
01/04/11 --- 25.0 ND 6.03 J ND 10.50 J ND ND ND ND ND 8.25 J ------ND07/05/11 --- 25.0 ND 1.84 J ND 7.12 J 1.42 J 2.51 J ND ND ND 3.39 J ------ND01/09/12 --- 25.0 ND ND ND ND ND ND ND ND ND 8.37 J ------ND
07/09/12 --- 25.0 2.41 J 1.85 J ND ND ND ND ND ND ND 1.71 J ------ND01/28/13 --- 25.0 2.24 B ND ND 15.30 B ND ND ND ND ND 6.45 B ------2.68 J07/17/13 --- 25.0 3.64 J ND ND 11.80 J ND ND 2.29 J 15.3 J ND 5.57 J ------ND
01/28/14 --- 25.0 ND ND ND 2.50 B ND ---ND 2.65 B 13.9 B 34.3 B ------8.09 J
05/31/14 --- 25.0 ------------------------------ND 4.36 J ND06/24/14 --- 25.0 ------------------------------ND ND ND07/24/14 0.93 25.0 1.24 B ND ND 1.44 B ND 10.8 J 1.47 B ND 0.97 B 2.30 B 1.20 B 4.69 B 1.41 J
01/28/15 0.93 25.0 1.11 J 2.35 J ND ND 1.38 J ND ND ND 2.37 J 60.7 ND 1.07 J ND
Resample >>03/05/15 --- 25.0 ---------------------------15.3 J ------1.40 J07/30/15 1.57 25.0 ---2.09 J ND ND ND ---ND ND 1.79 J 16.4 J ND 2.23 J ND
09/16/15 1.57 25.0 1.81 J ---------------------------------ND
01/27/16 1.57 25.0 ND ND ND ND ND ---ND 159 ND 13.0 J 1.61 J ND NDResample>>03/09/16 0.09 1.00 ---------------------17.7 J ------------ND07/27/16 1.57 25.00 ND 1.63 J ND ND ND 1.90 J ND 2.64 J ND 3.21 J ND ND ND
01/25/17 1.57 25.00 6.69 J ND ND ND ND ND ND 3.56 J ND 15.40 J ND ND ND
Total Zinc 10/28/98 --- 50 ND ND ND ND ND Dry ------------------ND
NC 2L = 1000 µg/L 04/07/99 --- 50 50.0 40.0 30.0 ND ND Dry ------------------30.0
12/08/99 --- 50 ND 40.0 80.0 ND 60 30.0 ------------------ND04/27/00 --- 50 90.0 70.0 ND 150 ND Dry ------------------ND10/18/00 --- 50 ND ND ND ND ND Dry ND ---------------ND
11/28/00 --- 50 ------------------60.0 ------------------
01/03/01 --- 50 ------------------ND ------------------02/08/01 --- 50 ------------------ND ------------------04/19/01 --- 50 ND ND ND ---ND Dry ND ---------------ND
12/24/01 --- 50 ND ND ND ND ND ND ND ---------------ND
04/23/02 --- 50 ND ND ND ND ND ND ND ---------------ND10/23/02 --- 50 ND ND ND 90.0 ND ND ND ---------------ND
04/01/03 --- 50 110.0 120.0 50.0 90.0 50.0 70.0 40.0 ---------------30.0
10/28/03 --- 50 ND ND ND ND ND ND ND ---------------ND04/27/04 --- 50 ND ND ND ND ND ND ND ---------------ND10/26/04 --- 50 ND ND ND ND ND ND ND ---------------ND
03/15/05 --- 50 ND ND ND ND ND ND ND ---------------ND
07/12/05 --- 50 ND ND ND ND ND ND ND ---------------ND01/12/06 --- 50 ---------------------ND ------------ND
01/19/06 --- 50 ND ND ND ND ND ND ND ---------------ND
07/11/06 --- 50 ND ND ND ND ND ND ND ND ------------ND10/31/06 --- 50 ---------------------ND ------------ND01/17/07 --- 10.0 18.80 B 23.30 B 12.20 B 12.70 B 5.9 B 10.40 B 15.60 B 7.7 B ------------5.50 J
07/09/07 --- 10.0 8.30 J 21.50 3.90 J 4.80 J 4.4 J ND 3.90 J 5.2 J ------------ND
01/14/08 --- 10.0 13.30 5.70 B 4.10 B 6.00 B 2.9 B 5.20 B 4.80 B 3.7 B 13.60 ---------1.30 J04/30/08 --- 10.0 --------------------------- 18.80 ------ND
07/14/08 --- 10.0 10.20 B 7.40 B 4.90 B 6.10 B ND ND 4.40 B 5.9 B ND 6.70 B ------5.00 J
10/03/08 --- 10.0 ---------------------------8.70 J ------ND01/19/09 --- 10.0 10.90 4.10 J 4.10 J 10.60 ND ND 4.30 J ND ND ND ------ND07/20/09 --- 10.0 10.30 28.00 9.27 J 12.20 ND ND 7.25 J 5.4 J 8.07 J 17.60 21.7 ND ND
01/25/10 --- 10.0 13.00 6.56 J ND 15.30 6.86 J 2.89 J 6.92 J 4.45 J 6.07 J 4.26 J ------ND
07/06/10 --- 10.0 12.00 5.01 J ND 9.64 J ND 4.54 J 5.00 J ND 6.07 J ND ------ND01/04/11 --- 10.0 9.70 J 7.51 J ND 14.00 ND ND ND ND ND 8.51 J ------ND07/05/11 --- 10.0 20.60 8.55 J 6.18 J 19.60 4.28 J 7.45 J 7.77 J 5.46 J ND 6.28 J ------ND
01/09/12 --- 10.0 12.40 B 3.07 B 3.85 B 13.80 B 2.31 B 3.53 B 7.41 B 73.8 B 3.38 B 7.26 B ------ 15.90
07/09/12 --- 10.0 10.40 J 4.69 J 2.52 B 14.10 3.42 J 2.21 B 5.46 J 5.74 J 6.37 J 3.83 J ------0.30 J01/28/13 --- 10.0 8.93 J 4.76 B 2.66 B 9.37 J 3.84 B 1.55 B 5.26 B 3.96 B 2.93 B 5.01 B ------0.57 J
07/17/13 --- 10.0 11.50 5.40 J 3.49 J 11.20 1.66 J 3.98 J 9.59 J 13.0 5.46 J 7.94 J ------ND
01/28/14 --- 10.0 10.10 6.11 J 2.11 J 13.10 5.09 J ---4.09 J 6.70 J 9.31 J 15.2 ------ND05/31/14 --- 10.0 ------------------------------15.2 2.42 B 1.03 J06/24/14 --- 10.0 ------------------------------19.0 3.04 B 1.70 J
07/24/14 0.64 10.0 11.7 4.34 J 1.85 B 13.0 3.06 B 14.10 3.01 B 5.24 J 4.29 J 4.31 J 7.39 J 1.29 B 0.71 J
01/28/15 0.64 10.0 9.68 7.77 5.38 B 14.8 24.8 4.73 B 5.83 B 4.43 B 5.89 B 34.9 11.1 3.41 B 1.38 J07/30/15 1.3 10.0 ---21.5 2.71 J 11.2 13.9 ---9.39 J 5.70 J 5.44 J 15.1 9.79 J 1.97 J ND
09/16/15 1.3 10.0 16.10 ---------------------------------1.41 J
01/27/16 1.3 10.0 9.58 J 6.70 J 3.17 J 12.6 5.79 J ---7.93 J 85.6 3.42 J 8.98 J 10.0 ND ND07/27/16 1.3 10.0 9.68 J 5.37 B 3.02 B 10.0 J 10.1 J 5.83 B 5.94 B 6.56 B 6.28 B 6.33 B 9.75 B 1.70 B 1.51 J01/25/17 1.3 10.0 13.30 11.40 4.56 B 12.8 6.1 B 5.49 B 10.40 7.88 B 4.97 B 11.80 11.20 2.66 B 2.13 J
East Carolina Regional Landfill
Permit No. 08-03 Page 6 of 11 Joyce Engineering
TABLE 8
Historical Groundwater Constituents/Analytes
Sample
Analyte
Collection
Date DL SWSL GW-2 GW-7 GW-8 GW-9 GW-10 GW-11/11R GW-13 GW-15 GW-16R GW-17 GW-18 GW-21 Blanks
Organic Compounds
Benzene 01/28/13 --- 1.0 0.70 J ND ND ND ND ND ND ND ND ND ------ND
NC 2L= 1 µg/L 07/17/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND01/28/14 --- 1.0 ND ND ND ND ND ---ND ND ND ND ------ND05/31/14 --- 1.0 ------------------------------ND ND ND
06/24/14 --- 1.0 ------------------------------ND ND ND
07/24/14 0.2 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND01/28/15 0.2 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND
07/30/15 0.2 1.0 ---ND ND ND ND ---ND ND ND ND ND ND ND
09/16/15 0.2 1.0 ND ---------------------------------ND01/27/16 0.2 1.0 ND ND ND ND ND ---ND ND ND ND ND ND ND07/27/16 0.2 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND
01/25/17 0.2 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND
Carbon Disulfide 07/24/14 0.8 100 ND ND ND ND ND 0.80 J ND ND ND ND ND ND ND
NC 2L = 700 µg/L 01/28/15 0.8 100 ND ND ND ND ND ND ND ND ND ND ND ND ND
07/30/15 0.3 100 ---ND ND ND ND ---ND ND ND ND ND ND ND09/16/15 0.5 100 ND ---------------------------------ND01/27/16 0.9 100 ND ND ND ND ND ---ND ND ND ND ND ND ND
07/27/16 0.6 100 ND ND ND ND ND ND ND ND ND ND ND ND ND
01/25/17 0.8 100 ND ND ND ND ND ND ND ND ND ND ND ND ND
Chloroform 01/17/07 --- 5.0 ND ND ND ND ND 0.63 J ND ND ------------ND
NC 2L = 70 µg/L 07/09/07 --- 5.0 ND ND ND ND ND 0.37 J ND ND ------------ND01/14/08 --- 5.0 ND ND ND ND ND 0.62 J ND ND 0.54 J ---------ND04/30/08 --- 5.0 ---------------------------1.0 J ------ND
07/14/08 --- 5.0 ND ND ND ND ND 0.66 J ND ND 1.10 J 2.0 J ------ND
10/03/08 --- 5.0 ---------------------------2.7 J ------ND01/19/09 --- 5.0 ND ND ND ND ND 0.58 J ND ND 0.52 J 2.6 J ------ND07/20/09 --- 5.0 ND ND ND ND ND 0.52 J ND ND 0.65 J 1.5 J ND 1.30 J ND
01/25/10 --- 5.0 ND ND ND ND ND 0.68 J ND ND 1.10 J 3.2 J ------ND
07/06/10 --- 5.0 ND ND ND ND ND 0.55 J ND ND ND 1.3 J ------ND01/04/11 --- 5.0 ND ND ND ND ND 0.44 J ND ND ND 2.3 J ------ND
07/05/11 --- 5.0 ND ND ND ND ND ND ND ND ND 1.2 J ------ND
01/09/12 --- 5.0 ND ND ND ND ND ND ND ND ND 1.2 J ------ND07/09/12 --- 5.0 ND ND ND ND ND 0.50 J ND ND ND 1.1 J ------ND01/28/13 --- 5.0 ND ND ND ND ND 0.50 J ND ND ND 1.2 J ------ND
07/17/13 --- 5.0 ND ND ND ND ND 0.50 J ND ND ND 1.8 J ------ND
01/28/14 --- 5.0 ND ND ND ND ND ---ND ND ND 1.0 J ------ND05/31/14 --- 5.0 ------------------------------ND 3.2 J ND
06/24/14 --- 5.0 ------------------------------ND 4.2 J ND
07/24/14 0.2 5.0 ND ND ND ND ND ND ND ND ND 0.5 J ND 3.8 J ND01/28/15 0.2 5.0 ND ND ND ND ND 0.2 J ND ND ND 0.6 J ND 4.7 J ND07/30/15 0.2 5.0 ---ND ND ND ND ---ND ND ND 0.4 J ND 4.4 J ND
09/16/15 0.4 5.0 ND ---------------------------------ND
01/27/16 0.3 5.0 ND ND ND ND 0.50 J ---ND ND ND 0.60 J ND 2.0 J ND07/27/16 0.3 5.0 ND ND ND ND 3.1 J 0.40 J ND ND ND 0.60 J ND 0.90 J ND01/25/17 0.6 5.0 ND ND ND ND 4.5 J ND ND ND ND 1.60 J ND ND ND
Chloromethane 07/06/10 --- 1.0 ND ND ND ND ND ND ND ND 0.43 J ND ------NDNC 2L = 3 µg/L 01/04/11 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND
07/05/11 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND
01/09/12 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND07/09/12 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND01/28/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND
07/17/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND
01/28/14 --- 1.0 ND ND ND ND ND ---ND ND ND ND ------ND05/31/14 --- 1.0 ------------------------------ND ND ND
06/24/14 --- 1.0 ------------------------------ND ND ND
07/24/14 0.2 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND01/28/15 0.2 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND07/30/15 0.4 1.0 ---ND ND ND ND ---ND ND ND ND ND ND ND
09/16/15 0.6 1.0 ND ---------------------------------ND
01/27/16 0.4 1.0 ND ND ND ND ND ---ND ND ND ND ND ND ND07/27/16 0.4 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND
01/25/17 0.4 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND
1,4- Dichlorobenzene 07/09/12 --- 1.0 0.40 J ND ND ND ND ND ND ND ND ND ------NDNC 2L = 6 µg/L 01/28/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND
07/17/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND
01/28/14 --- 1.0 ND ND ND ND ND ---ND ND ND ND ------ND05/31/14 --- 1.0 ------------------------------ND ND ND06/24/14 --- 1.0 ------------------------------ND ND ND
07/24/14 0.2 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND
01/28/15 0.3 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND01/27/16 0.3 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND
Methylene Chloride 01/28/13 --- 1.0 0.50 J ND ND ND ND ND ND ND ND ND ------NDNC 2L = 5 µg/L 07/17/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND01/28/14 --- 1.0 ND ND ND ND ND ---ND ND ND ND ------ND
05/31/14 --- 1.0 ------------------------------ND ND ND
06/24/14 --- 1.0 ------------------------------ND ND ND07/24/14 0.6 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND
01/28/15 0.6 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND
07/30/15 0.3 1.0 ---ND ND ND ND ---ND ND ND ND ND ND ND09/16/15 0.6 1.0 ND ---------------------------------ND01/27/16 0.5 1.0 ND ND ND ND ND ---ND ND ND ND ND ND ND
07/27/16 0.5 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND
01/25/17 0.5 1.0 ND ND ND ND ND ND ND ND ND ND ND ND 2.10
East Carolina Regional Landfill
Permit No. 08-03 Page 7 of 11 Joyce Engineering
TABLE 8
Historical Groundwater Constituents/Analytes
Sample
Analyte
Collection
Date DL SWSL GW-2 GW-7 GW-8 GW-9 GW-10 GW-11/11R GW-13 GW-15 GW-16R GW-17 GW-18 GW-21 Blanks
Toluene 01/28/13 --- 1.0 1.50 B 0.20 B ND ND ND ND ND ND ND ND ------0.20 J
NC 2L = 200 µg/L 07/17/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND
01/28/14 --- 1.0 ND ND ND ND ND ---ND ND ND ND ------ND05/31/14 --- 1.0 ------------------------------ND ND 0.30 J06/24/14 --- 1.0 ------------------------------ND ND 0.20 J
07/24/14 0.2 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND
01/28/15 0.2 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND07/30/15 0.2 1.0 ---ND ND ND ND ---ND ND ND ND ND ND ND
09/16/15 0.2 1.0 ND ---------------------------------0.50 J
01/27/16 0.3 1.0 ND ND ND ND ND ---ND ND ND ND ND ND ND07/27/16 0.3 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND01/25/17 0.3 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND
Trichloroethene 07/12/05 --- 5.0 ND ND ND ND ND ND ND ---------------NDNC 2L = 3 µg/L 01/19/06 --- 5.0 ND ND ND ND ND ND ND ---------------ND
07/11/06 --- 5.0 ND ND ND ND ND ND ND ND ------------ND
10/31/06 --- 5.0 ---------------------ND ------------ND01/17/07 --- 3.0 ND ND ND ND ND ND ND ND ------------ND07/09/07 --- 1.0 0.47 J ND 0.35 J ND ND ND ND ND ------------ND
01/14/08 --- 1.0 ND ND ND ND ND ND ND ND ND ---------ND
04/30/08 --- 1.0 ---------------------------ND ------ND07/14/08 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND
10/03/08 --- 1.0 ---------------------------ND ------ND
01/19/09 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND07/20/09 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND01/25/10 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND
07/06/10 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND
01/04/11 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND07/05/11 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND01/09/12 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND
07/09/12 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND
01/28/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND07/17/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ------ND
01/28/14 --- 1.0 ND ND ND ND ND ---ND ND ND ND ------ND
05/31/14 1.0 ------------------------------ND ND ND06/24/14 1.0 ------------------------------ND ND ND07/24/14 0.4 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND
01/28/15 0.4 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND
07/30/15 0.4 1.0 ---ND ND ND ND ---ND ND ND ND ND ND ND09/16/15 0.4 1.0 ND ------------------------------------
01/27/16 0.4 1.0 ND ND ND ND ND ---ND ND ND ND ND ND ND
07/27/16 0.4 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND01/25/17 0.3 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND
Field Parameters
pH 10/28/98 --- --- 5.38 4.61 5.58 5.76 6.63 Dry ---------------------(S.U.)04/07/99 --- --- 5.14 4.60 5.38 5.66 6.32 Dry ---------------------
12/08/99 --- --- 5.11 6.31 5.20 5.30 6.02 7.50 ---------------------
04/27/00 --- --- 5.06 4.50 5.28 5.64 5.84 Dry ---------------------10/18/00 --- --- 4.93 4.19 5.04 5.41 6.04 Dry 6.00 ------------------11/28/00 --- --- ------------------4.24 ------------------
01/03/01 --- --- ------------------5.83 ------------------
02/08/01 --- --- ------------------5.94 ------------------04/19/01 --- --- 4.98 4.26 5.07 ---6.27 Dry 5.76 ------------------
12/24/01 --- --- 5.13 4.27 5.03 5.57 6.41 5.46 5.19 ------------------
04/23/02 --- --- 4.97 4.24 4.91 5.40 6.5 5.05 4.89 ------------------10/23/02 --- --- 4.62 4.02 4.67 5.03 6.05 4.90 5.00 ------------------04/01/03 --- --- 4.92 4.26 4.99 5.46 6.25 5.41 5.28 ------------------
10/28/03 --- --- 4.74 4.13 5.01 5.31 6.29 5.13 4.97 ------------------
04/27/04 --- --- 4.70 4.19 4.70 5.08 6.03 5.16 4.59 ------------------10/26/04 --- --- 4.45 3.97 4.49 5.05 5.73 4.74 4.55 ------------------03/15/05 --- --- 4.70 4.21 5.04 5.32 6.03 5.26 4.78 ------------------
07/12/05 --- --- 4.15 4.17 4.88 4.73 5.6 4.85 4.33 ------------------01/19/06 --- --- 2.69 2.38 5.05 4.68 6.58 3.56 5.76 ------------------07/11/06 --- --- 4.64 4.23 4.94 5.17 5.67 5.17 4.81 5.13 ---------------10/31/06 --- --- ---------------------4.67 ---------------
01/17/07 --- --- 4.01 4.1 4.72 5.1 6.04 5.18 4.7 4.89 ---------------07/09/07 --- --- 4.31 4.18 5.00 5.20 6.08 4.98 4.65 4.84 ---------------
01/14/08 --- --- 4.34 4.25 4.88 5.42 5.77 5.27 4.99 5.18 5.08 ------------
04/30/08 --- --- ---------------------------4.51 ---------07/14/08 --- --- 4.47 4.13 4.82 5.22 5.7 5.10 4.72 4.99 5.02 4.68 ---------
10/03/08 --- --- ---------------------------4.33 ---------
01/19/09 --- --- 4.63 4.06 4.85 4.72 5.08 4.75 4.75 4.95 4.50 4.23 ---------07/20/09 --- --- 4.79 4.29 4.80 5.34 5.55 4.16 3.83 4.46 4.74 4.39 4.23 4.65 ---01/25/10 --- --- 4.30 4.01 4.63 4.94 5.51 5.02 4.62 4.89 4.51 4.36 ---------
07/06/10 --- --- 4.17 4.08 4.70 5.09 5.49 4.66 4.73 4.17 4.48 4.41 ---------
01/04/11 --- --- 4.55 4.07 4.71 5.73 5.73 5.00 4.72 4.86 4.46 4.48 ---------07/05/11 --- --- 3.71 3.69 4.29 4.98 4.47 4.43 3.89 4.71 3.68 3.50 ---------01/09/12 --- --- 4.76 4.42 4.60 5.47 5.81 5.07 4.64 5.38 4.50 4.6 ---------
07/09/12 --- --- 4.83 4.24 4.9 5.24 5.82 5.33 4.89 5.24 4.94 4.8 ---------
01/28/13 --- --- 4.96 4.33 4.98 5.90 5.79 5.21 5.04 5.22 4.79 4.93 ---------07/17/13 --- --- 4.19 4.00 4.7 5.10 5.29 4.29 4.24 5.01 4.03 4.70 ---------
01/28/14 --- --- 4.99 6.11 5.41 5.66 5.9 5.15 5.28 5.29 4.89 4.98 ---------
05/31/14 --- --- ------------------------------4.01 4.22 ---06/24/14 --- --- ------------------------------4.15 4.03 ---07/24/14 --- --- 4.49 4.18 4.51 4.87 5.14 5.15 4.87 5.36 4.35 4.65 4.22 4.01 ---
01/28/15 --- --- 5.46 3.85 4.62 4.88 4.83 5.42 4.29 5.08 4.43 4.51 4.39 4.33 ---
03/05/15 --- --- ---------------------------4.63 ---------07/30/15 --- --- ---4.38 4.92 5.15 5.68 ---4.89 5.17 4.64 4.98 4.39 4.81 ---
09/16/15 --- --- 4.58 ------------------------------------
01/27/16 --- --- 4.68 4.43 5.08 4.92 5.00 ---5.04 4.95 4.43 4.66 4.05 4.43 ---07/27/16 --- --- 4.78 4.83 5.34 5.02 4.77 5.03 4.85 4.88 5.09 5.02 5.11 4.60 ---01/25/17 --- --- 6.32 4.30 5.41 5.5 5.86 5.27 4.84 5.34 4.65 5.1 4.38 4.85 ---
East Carolina Regional Landfill
Permit No. 08-03 Page 8 of 11 Joyce Engineering
TABLE 8
Historical Groundwater Constituents/Analytes
Sample
Analyte
Collection
Date DL SWSL GW-2 GW-7 GW-8 GW-9 GW-10 GW-11/11R GW-13 GW-15 GW-16R GW-17 GW-18 GW-21 Blanks
Conductivity 10/28/98 --- --- 83 257.0 98 78.00 115 Dry ---------------------
(µS/cm)04/07/99 --- --- 69.41 173.0 75.21 52.07 67.89 Dry ---------------------
12/08/99 --- --- 61 306.0 52 89.00 48 41 ---------------------04/27/00 --- --- 78 210.0 87 57.00 57 Dry ---------------------10/18/00 --- --- 110 317.0 130 76.00 108 Dry ---------------------
11/28/00 --- --- ------------------191.0 ------------------
01/03/01 --- --- ------------------7.3 ------------------02/08/01 --- --- ------------------75.0 ------------------
04/19/01 --- --- 106.0 284.0 130.0 ---125 Dry 5.8 ------------------
12/24/01 --- --- 85.0 224.0 105.0 71.00 104 46.0 80.0 ------------------04/23/02 --- --- 112.0 282.0 136.0 84.00 131 62.0 156.0 ------------------10/23/02 --- --- 62.0 161.0 77.0 49.00 75 37.0 41.0 ------------------
04/01/03 --- --- 71.0 131.0 86.0 54.00 72 43.0 83.0 ------------------
10/28/03 --- --- 84.0 221.0 89.0 64.00 85 38.0 93.0 ------------------04/27/04 --- --- 99.0 227.0 108.0 82.00 102 53.0 118.0 ------------------
10/26/04 --- --- 110.0 259.0 115.0 95.00 122 51.0 97.0 ------------------
03/15/05 --- --- 108.0 223.0 94.0 79.00 97 47.0 91.0 ------------------07/12/05 --- --- 106.0 231.0 98.0 84.00 88 49.0 91.0 ------------------01/19/06 --- --- 103.0 214.0 100.0 66.00 98 47.0 89.0 ------------------
07/11/06 --- --- 147.0 307.0 146.0 121.00 129 70.0 126.0 106 ---------------
10/31/06 --- --- ---------------------90 ---------------01/17/07 --- --- 136.0 291.0 164.0 112.00 132 52.0 98.0 92 ---------------
07/09/07 --- --- 134.0 268.0 133.0 115.00 109 54.0 89.0 92 ---------------
01/14/08 --- --- 212.00 442.0 208.0 128.00 279 120.0 252.0 248 53.0 ------------04/30/08 --- --- ---------------------------77.0 ---------07/14/08 --- --- 146.00 301.0 155.00 113.00 127 69.0 118.0 107 39.0 82.0 ---------
10/03/08 --- --- ---------------------------79.0 ---------
01/19/09 --- --- 138.0 264.0 164.0 84.00 108 64.0 113.0 100 38.0 86.0 ---------07/20/09 --- --- 138.0 266.0 161.0 122.0 119 67.0 113.0 100 33.0 77.0 198 26 ---01/25/10 --- --- 139.0 260.0 149.0 90.0 127 61.0 108.0 100 33.0 76.0 ---------
07/06/10 --- --- 134.0 233.0 145.0 138.0 123 61.0 97.0 134 33.0 76.0 ---------
01/04/11 --- --- 140.0 269.0 148.0 342.0 135 62.0 101.0 100 32.0 82.0 ---------07/05/11 --- --- 143.0 251.0 145.0 205.0 135 71.0 111.0 100 33.0 78.0 ---------
01/09/12 --- --- 116.0 201.0 111.0 219.0 105 51.0 93.0 79 29.0 62.0 ---------
07/09/12 --- --- 123.9 220.2 136.3 220.9 133.2 63.6 127.4 91.5 36.5 75.7 ---------01/28/13 --- --- 117.6 190.1 105.1 4.2 108.9 45.9 96.5 79.8 27.5 61.4 ---------07/17/13 --- --- 104.8 208.1 121.3 220.1 98.7 49.7 92.0 83.9 34.3 69.9 ---------
01/28/14 --- --- 109.1 184.2 115.3 242.7 106.2 45.0 96.1 55.6 29.3 66.7 ---------
05/31/14 --- --- ------------------------------145 22.3 ---06/24/14 --- --- ------------------------------ 163.3 23.3 ---
07/24/14 --- --- 131.1 182.1 118.4 251.6 128.2 53.2 102.8 93.8 45.2 79.0 164.5 23.7 ---
01/28/15 --- --- 175.3 202.9 102.8 233.0 111.1 42.5 98.0 83.1 38.3 65.2 129.4 22.4 ---03/05/15 --- --- ---------------------------64.9 ---------07/30/15 --- --- ---213 114 187 123 ---98 89 49 72 143 24 ---
09/16/15 --- --- 129.10 ------------------------------------
01/27/16 --- --- 122.2 177.6 124.8 171.9 123.4 ---145.8 125.3 41.4 64.7 138.9 25.9 ---07/27/16 --- --- 128.9 179.4 135.8 178.0 131.6 54.2 105.2 107.0 56.5 76.4 151.8 29.6 ---01/25/17 --- --- 188.60 172.80 119.7 136.2 125.90 42.9 93.2 95.8 52.90 57.8 141.40 34.10 ---
Temperature 10/28/98 --- --- 15.30 19.00 19.70 18.60 15.9 Dry ---------------------(ºC)04/07/99 --- --- 16.70 17.30 17.30 15.60 17.6 Dry ---------------------
12/08/99 --- --- 15.10 17.00 25.00 17.10 16.7 17.00 ---------------------
04/27/00 --- --- 15.60 13.10 14.40 13.70 12.9 Dry ---------------------10/18/00 --- --- 16.70 19.10 19.30 20.40 16.6 Dry ---------------------11/28/00 --- --- ------------------15.60 ------------------
01/03/01 --- --- ------------------14.50 ------------------
02/08/01 --- --- ------------------16.90 ------------------04/19/01 --- --- 14.90 31.00 14.70 ---13.7 Dry 17.10 ------------------
12/24/01 --- --- 17.90 20.20 20.70 20.80 17.7 20.10 21.60 ------------------
04/23/02 --- --- 15.90 16.00 15.70 15.60 14.5 18.40 17.10 ------------------10/23/02 --- --- 15.80 19.10 19.40 20.30 17 17.80 15.70 ------------------04/01/03 --- --- 16.90 16.40 17.00 14.40 15.7 18.50 17.30 ------------------
10/28/03 --- --- 16.50 19.10 18.00 18.10 15.9 16.60 18.30 ------------------
04/27/04 --- --- 16.00 17.00 15.50 14.00 15 17.30 19.40 ------------------10/26/04 --- --- 16.80 18.80 19.10 19.70 17 18.00 15.90 ------------------
03/15/05 --- --- 16.18 15.79 15.80 12.86 14.6 17.44 16.39 ------------------
07/12/05 --- --- 16.32 16.80 16.56 18.09 15.97 17.78 17.92 ------------------01/19/06 --- --- 16.61 17.50 17.51 15.06 15.39 17.88 17.19 ------------------07/11/06 --- --- 16.10 16.80 17.00 18.20 15.7 17.70 17.30 19.9 ---------------
10/31/06 --- --- ---------------------17.6 ---------------
01/17/07 --- --- 15.60 15.60 15.80 14.50 15 16.60 16.00 14.9 ---------------07/09/07 --- --- 17.09 17.81 17.53 18.90 17 17.75 17.80 18.61 ---------------01/14/08 --- --- 16.26 17.88 15.93 15.44 14.32 16.65 17.53 16.65 16.6 ------------
04/30/08 --- --- --------------------------- 15.09 ---------
07/14/08 --- --- 17.17 19.03 18.84 20.55 18.13 19.59 18.67 18.44 18.38 16.22 ---------10/03/08 --- --- --------------------------- 16.30 ---------
01/19/09 --- --- 15.32 14.69 15.59 13.80 13.94 16.71 15.22 15.18 13.25 12.81 ---------
07/20/09 --- --- 17.08 19.47 18.99 19.25 16.87 19.62 18.99 19.18 17.43 18.09 18.25 17.64 ---01/25/10 --- --- 16.60 16.99 16.89 14.08 14.52 18.16 17.10 16.5 15.94 15.68 ---------07/06/10 --- --- 17.58 20.10 18.72 21.4 16.4 19.7 25.6 17.58 17.78 18.99 ---------
01/04/11 --- --- 16.52 17.09 16.38 14.2 14.7 17.5 16.5 15.5 15.51 15.44 ---------
07/05/11 --- --- 17.6 19.52 19.02 22.2 17.5 21.1 17.9 19.67 16.82 17.90 ---------01/09/12 --- --- 15.4 15.82 14.83 13.7 13.8 16.0 15.8 13.81 16.40 14.89 ---------
07/09/12 --- --- 17.0 18.30 18.80 19.3 16.2 18.3 19.0 19.3 16.60 18.30 ---------
01/28/13 --- --- 16.7 16.60 16.50 13.20 14.6 17.30 16.90 14.8 16.60 17.00 ---------07/17/13 --- --- 16.4 18.10 17.90 18.10 15.9 18.00 18.60 21.6 19.80 23.30 ---------01/28/14 --- --- 14.3 13.30 16.90 10.30 14.6 14.60 14.40 14.4 14.30 14.40 ---------
05/31/14 --- --- ------------------------------ 15.50 15.90 ---
06/24/14 --- --- ------------------------------ 16.20 16.60 ---07/24/14 --- --- 16.2 17.50 18.00 19.20 15.7 21.00 18.50 19.2 17.00 18.60 19.20 18.10 ---
01/28/15 --- --- 16.7 16.60 16.20 13.00 11.4 15.40 17.80 15.1 14.60 15.70 13.90 15.30 ---
03/05/15 --- --- --------------------------- 13.40 ---------07/30/15 --- --- --- 23.10 18.56 20.02 16.31 ---20 19.3 17.86 20.10 18.60 19.67 ---09/16/15 --- --- 17.00 ------------------------------------
01/27/16 --- --- 16.7 17.1 15.7 14.7 15.3 ---15.5 11.9 15.4 15.3 14.5 15.4 ---
07/27/16 --- --- 19.8 17.8 19.4 20.5 16.3 23.5 20.8 20.8 17.9 20.6 19.5 20.9 ---01/25/17 --- --- 17.2 18.7 15.8 13.2 15.6 14.0 17.5 17.5 17.1 16.9 16.8 18.0 ---
East Carolina Regional Landfill
Permit No. 08-03 Page 9 of 11 Joyce Engineering
TABLE 8
Historical Groundwater Constituents/Analytes
Sample
Analyte
Collection
Date DL SWSL GW-2 GW-7 GW-8 GW-9 GW-10 GW-11/11R GW-13 GW-15 GW-16R GW-17 GW-18 GW-21 Blanks
Turbidity 10/28/98 --- --- 80.0 65.00 19.00 13.00 17 Dry ---------------------
(NTU)04/07/99 --- --- 20.00 1.51 3.13 2.61 2.96 Dry ---------------------
12/08/99 --- --- 20.00 9.46 5.04 2.24 26 19.00 ---------------------04/27/00 --- --- 32.00 18.00 14.00 7.07 1.76 Dry ---------------------10/18/00 --- --- 20.40 38.10 9.20 6.39 1.6 Dry 15.90 ------------------
11/28/00 --- --- ------------------11.40 ------------------
01/03/01 --- --- ------------------11.00 ------------------02/08/01 --- --- ------------------18.00 ------------------
04/19/01 --- --- 169.00 31.00 11.00 ---11 Dry 16.00 ------------------
12/24/01 --- --- 28.00 60.00 5.31 33.00 2.45 61.00 29.00 ------------------04/23/02 --- --- 27.00 26.00 2.08 290.00 450 11.00 4.28 ------------------10/23/02 --- --- 6.54 5.77 1.84 3.97 1.35 71.00 6.58 ------------------
04/01/03 --- --- 44.00 23.00 2.63 15.00 91 44.00 10.00 ------------------
10/28/03 --- --- 34.00 25.00 1.80 25.00 7.99 20.00 13.00 ------------------04/27/04 --- --- 32.00 13.00 0.85 33.00 34 20.00 2.37 ------------------
10/26/04 --- --- 10.00 10.00 0.89 38.00 5.89 29.00 44.00 ------------------
03/15/05 --- --- 68.60 17.90 15.40 43.50 45.1 50.30 26.30 ------------------07/12/05 --- --- 78.00 29.70 30.30 37.30 30.3 45.20 36.30 ------------------01/19/06 --- --- 39.20 0.00 0.00 0.00 0 0.00 0.00 ------------------
07/11/06 --- --- 33.60 3.40 1.70 25.40 31 34.50 15.00 78.2 ---------------
10/31/06 --- --- ---------------------193 ---------------01/17/07 --- --- 13.00 0.00 9.50 23.70 97.2 6.90 8.80 8.3 ---------------
07/09/07 --- --- 0.00 0.00 0.00 0.00 65.8 0.00 0.00 0 ---------------
01/14/08 --- --- 7.31 5.39 1.19 37.50 24 1.29 0.68 9.48 4.1 ------------04/30/08 --- --- --------------------------- >1000 ---------07/14/08 --- --- 10.60 1.10 1.46 29.50 50.6 2.61 0.40 2.03 8.77 33.10 ---------
10/03/08 --- --- ---------------------------9.54 ---------
01/19/09 --- --- 13.80 1.81 0.41 20.90 5.82 2.99 0.39 1.76 3.04 2.45 ---------07/20/09 --- --- 8.53 1.50 21.00 36.20 7.84 2.22 1.45 1.67 6.42 45.90 92.0 85.2 ---01/25/10 --- --- 4.45 3.91 1.46 57.00 29 20.90 3.56 2.75 8.8 14.30 ---------
07/06/10 --- --- 7.74 2.34 0.87 34.90 40 3.37 1.26 7.74 11.3 1.73 ---------
01/04/11 --- --- 9.95 14.30 5.51 42.20 29.8 8.01 1.41 0.78 0.67 82.20 ---------07/05/11 --- --- 12.90 74.40 1.22 87.50 41.9 29.40 0.94 2.23 0.77 30.60 ---------
01/09/12 --- --- 10.93 9.11 7.20 5.69 10.96 6.21 6.10 28.2 6.07 49.10 ---------
07/09/12 --- --- 15.30 18.70 4.74 19.70 42 4.16 10.10 14.7 7.80 11.50 ---------01/28/13 --- --- 19.79 20.71 21.09 91.31 11.91 15.29 27.10 20.1 15.26 37.80 ---------07/17/13 --- --- 7.24 9.71 8.43 11.23 8.61 8.09 7.92 20.92 7.42 8.98 ---------
01/28/14 --- --- 10.28 4.34 3.86 15.80 10.31 14.02 5.94 8.16 9.20 17.02 ---------
05/31/14 --- --- ------------------------------7.26 29.9 ---06/24/14 --- --- ------------------------------5.60 7.48 ---
07/24/14 --- --- 5.10 6.50 2.77 3.31 3.9 8.70 3.81 3.76 3.78 18.70 4.12 ------01/28/15 ------3.30 8.50 1.25 2.28 9.7 5.29 1.99 1.97 14.30 45.00 2.02 18.20 ---03/05/15 ---------------------------------------------07/30/15 ---------4.1 6.5 4.1 8.1 ---4.8 13.5 12.50 21.00 4.20 ------09/16/15 ------16.30 ------------------------------------01/27/16 ------13.7 4.7 5.21 8.57 3.97 ---5.01 120 8.06 9.86 3.19 4.93 ---07/27/16 ------4.01 3.9 4.00 4.18 2.98 5.69 4.28 11.70 3.68 6.95 4.64 4.66 ---01/25/17 --- --- 7.23 1.34 2.63 2.50 2.56 1.68 2.11 18.76 3.70 15.13 4.52 2.86 ---
Oxidation Reduction Potential 03/15/05 --- --- 363.0 411.0 236.0 121.0 14.0 270.0 319.0 ------------------(mV)07/12/05 --- --- 407.0 412.0 234.0 173.0 5.0 279.0 375.0 ------------------01/19/06 --- --- 361.0 370.0 222.0 174.0 16.0 283.0 339.0 ------------------
07/11/06 --- --- 382.0 309.0 312.0 216.0 115.0 317.0 363.0 290.0 ---------------
10/31/06 --- --- --------------------- 343.0 ---------------01/17/07 --- --- 347.0 391.0 306.0 153.0 32.0 290.0 318.0 305.0 ---------------
07/09/07 --- --- 371.0 431.0 309.0 204.0 81.0 290.0 352.0 328.0 ---------------
01/14/08 --- --- 363.0 403.0 342.0 166.0 147.0 317.0 336.0 317.0 308.0 ------------07/14/08 --- --- 314.0 365.0 248.0 114.0 6.0 247.0 274.0 257.0 243.0 291.0 ---------10/03/08 --- --- --------------------------- 260.0 ---------
01/19/09 --- --- 203.8 260.9 254.4 152.1 193.3 159.2 238.9 213.8 216.4 179.8 ---------
07/20/09 --- --- 302.4 289.1 245.3 122.3 110.0 238.0 223.1 202.5 253.0 285.4 285.2 251.8 ---01/25/10 --- --- 255.6 310.6 243.0 185.9 144.4 245.0 264.1 244.5 285.2 300.7 ---------
07/06/10 --- --- 76.9 101.1 48.2 151.4 -26.2 57.2 93.5 76.9 224.2 94.6 ---------
01/04/11 --- --- 163.4 274.2 211.4 -5.9 85.4 138.1 160.0 151.7 219.2 243.4 ---------07/05/11 --- --- 224.2 273.0 245.9 131.1 151.5 207.3 261.7 231.9 260.7 271.0 ---------01/09/12 --- --- 121.5 95.1 104.1 33.7 -4.9 76.8 99.9 94.0 35.6 63.9 ---------
07/09/12 --- --- 105.2 177.0 135.5 42.6 -41.2 75.7 116.0 103.8 53.1 127.1 ---------
01/28/13 --- --- 289.9 385.8 220.1 19.8 150.1 249.1 288.4 269.7 261.4 287.6 ---------07/17/13 --- --- 253.1 263.7 100.6 77.3 58.6 214.6 267.1 187.4 196.1 155.3 ---------
01/28/14 --- --- 288.3 202.1 81.4 108.4 159.9 246.0 268.3 269.1 273.5 269.1 ---------
05/31/14 --- --- ------------------------------ 180.3 171.9 ---06/24/14 --- --- ------------------------------ 171.2 181.4 ---07/24/14 --- --- 137.5 166.1 146.0 93.8 109.2 84.0 126.4 98.0 145.3 122.9 153.2 171.5 ---
01/28/15 --- --- 145.9 132.1 150.7 88.7 160.4 177.0 180.8 162.6 190.8 184.3 200.7 170.5 ---
03/05/15 --- --- --------------------------- 134.87 ---------07/30/15 --- --- --- 261.7 239.1 111.3 65.6 ---197.6 182.1 417.1 202.8 275.6 241.3 ---09/16/15 --- --- 307.1 ------------------------------------
01/27/16 --- --- 258.9 273.3 339.9 103.3 150.1 ---221.6 227.9 244.1 268.2 342.3 371.0 ---
07/27/16 --- --- 104.5 115.7 96.1 88.6 94.1 85.4 108.2 95.1 118.1 96.4 107.0 100.3 ---01/25/17 --- --- 185.90 286.80 221.20 239.20 122.90 205.30 215.80 195.70 367.50 199.70 288.90 217.20 ---
East Carolina Regional Landfill
Permit No. 08-03 Page 10 of 11 Joyce Engineering
TABLE 8
Historical Groundwater Constituents/Analytes
Sample
Analyte
Collection
Date DL SWSL GW-2 GW-7 GW-8 GW-9 GW-10 GW-11/11R GW-13 GW-15 GW-16R GW-17 GW-18 GW-21 Blanks
Dissolved Oxygen 03/15/05 --- --- 4.65 2.69 1.61 1.23 1.39 2.10 5.55 ------------------
(mg/L)07/12/05 --- --- 6.22 3.06 0.53 1.83 1.12 2.48 6.90 ------------------
01/19/06 --- --- 3.34 0.00 0.00 0.00 0 0.21 3.71 ------------------07/11/06 --- --- 9.31 5.50 3.00 3.32 1.6 3.52 7.88 8.05 ---------------10/31/06 --- --- ---------------------6.3 ---------------
01/17/07 --- --- 8.80 3.90 1.70 2.70 2.1 4.60 7.80 7.9 ---------------
07/09/07 --- --- 6.30 3.20 0.90 1.60 2.3 2.70 6.80 7 ---------------01/14/08 --- --- 8.12 4.09 4.87 2.56 3.44 3.96 8.25 8.66 6.37 ------------
07/14/08 --- --- 7.46 3.42 1.49 2.37 0.86 2.29 6.24 6.53 4.27 4.21 ---------
10/03/08 --- --- ---------------------------5.07 ---------01/19/09 --- --- 8.53 3.27 1.79 1.62 1.26 3.01 6.69 7.15 7.2 6.07 ---------07/20/09 --- --- 7.63 4.89 3.50 2.99 0.99 2.63 6.76 6.81 3.9 4.76 4.97 6.19 ---
01/25/10 --- --- 7.95 4.55 3.54 4.67 1.29 4.89 7.10 7.27 4.4 3.95 ---------
07/06/10 --- --- 7.26 4.86 3.50 0.30 4.04 5.37 5.72 7.26 2.7 3.33 ---------01/04/11 --- --- 8.43 4.15 4.46 2.30 1.84 6.24 7.95 7.07 1.0 4.04 ---------
07/05/11 --- --- 6.37 3.11 1.25 3.58 0.64 1.84 7.27 7.08 2.4 5.20 ---------
01/09/12 --- --- 6.04 4.44 1.87 0.60 1.41 2.75 4.91 5.5 0.4 2.64 ---------07/09/12 --- --- 0.45 4.99 3.12 0.52 0.32 1.10 2.62 1.03 0.4 3.18 ---------01/28/13 --- --- 5.43 5.81 5.79 8.63 0.69 4.09 7.15 7.26 1.9 4.51 ---------
07/17/13 --- --- 5.27 1.64 2.31 0.40 0.18 1.79 5.91 4.95 1.06 3.49 ---------
01/28/14 --- --- 4.93 3.86 3.11 4.52 1.18 5.95 7.68 7.78 7.30 5.26 ---------05/31/14 --- --- ------------------------------6.57 5.48 ---
06/24/14 --- --- ------------------------------3.54 3.33 ---
07/24/14 --- --- 4.32 4.40 3.18 1.49 1.61 4.03 4.12 4.34 1.33 3.47 4.51 4.44 ---01/28/15 --- --- 7.07 3.51 4.96 1.39 5.07 2.98 5.44 6.05 3.77 4.34 7.66 6.95 ---03/05/15 --- --- ---------------------------------------
07/30/15 --- --- ---9.21 2.95 0.63 0.22 ---5.67 4.99 1.41 2.59 7.45 5.84 ---
09/16/15 --- --- 5.31 ------------------------------------01/27/16 --- --- 5.59 3.82 4.36 1.01 0.39 ---5.78 8.29 1.85 3.65 5.08 4.80 ---07/27/16 --- --- 6.17 4.42 1.78 0.42 0.49 2.92 2.72 5.33 0.80 2.72 6.67 2.38 ---
01/25/17 --- --- 5.69 6.28 6.36 7.16 0.51 4.19 3.23 5.82 3.85 4.49 6.90 2.71 ---
Notes:DL = Method Detection Limit.
RL = Reporting Limit = PQL prior to 2007 and SWSL starting January 2007.
PQL = Practical Quantitation Limit.SWSL = NC-DENR Solid Waste Section Limit.NC 2L = Groundwater Standard established in 15 A NCAC 2L.0202
GWPS = NC DENR Solid Waste Section Groundwater Protection Standard for constituents with no listed NC 2L.
ND = Not detected above the DL.J = Estimated concentration below the RL.
B = Blank qualified data.
dry = insufficient water to sample. --- = No data.All inorganic and organic compunds are reported in µg/L
µg/L = micrograms per liter
S.U. = Standard Units.NTU = Nephelometric Turbidity Units.
µS/cm= microsiemens per centimeter.
mV = Millivolts.Bold = Concentrations above the NC 2L or Groundwater Protection standards (GWPS) have been bolded.Blanks = field, trip and/or method blanks.
All data prior to 2012 taken from previous reports by Golder Associates NC, Inc.
GW-11 was abandonded and replaced with GW-11R on July 21, 2014.GW-2 became infested with ants, blocking bladder pump use. The blockage was removed and the system decontaminated before sampling on September 16, 2015.(10.0) Results in paranthesis are results from laboratory confirmation or re-run analysis.
East Carolina Regional Landfill
Permit No. 08-03 Page 11 of 11 Joyce Engineering
TABLE 9
Historical Surface Water Constituents/Analytes
Analyte
Sample Collection
Date DL RL SW-1 SW-2 SW-3 SW-4 Blanks
Inorganic Compounds
Total Antimony 07/12/05 --- 30.00 ND ND ND ND ND
No NC 2B Standard 01/19/06 --- 30.00 ND ND ND ND ND
07/12/06 --- 30.00 ND ND ND ND ND
01/17/07 --- 6.00 ND ND ND ND ND
01/15/08 --- 6.00 ND ND --- ND ND
07/14/08 --- 6.00 ND --- ND --- ND
01/19/09 --- 6.00 ND --- ND ND ND
07/20/09 --- 6.00 --- --- ND ND ND
01/26/10 --- 6.00 ND 0.44 J 0.08 J ND ND
07/06/10 --- 6.00 --- --- --- --- ND
01/04/11 --- 6.00 ND --- ND ND ND
07/05/11 --- 6.00 ND --- --- --- ND
01/10/12 --- 6.00 ND 1.19 J ND ND ND
07/09/12 --- 6.00 --- --- ND --- ND
01/28/13 --- 6.00 ND 1.60 J ND ND ND
07/17/13 --- 6.00 ND --- ND --- 0.39 J
01/28/14 --- 6.00 ND --- 0.24 J --- ND
07/24/14 1.05 6.00 ND --- ND --- ND
01/28/15 1.05 6.00 ND --- ND --- ND
07/30/15 0.25 6.00 --- --- ND --- ND
01/27/16 0.25 6.00 --- 1.52 J ND --- ND
07/27/16 0.25 6.00 --- 1.06 J 0.27 J --- ND
01/25/17 0.25 6.00 ND 1.89 J 0.35 J --- ND
Total Arsenic 07/12/05 --- 10.0 ND ND ND ND ND
NC 2B = 50 µg/L 01/19/06 --- 10.0 ND ND ND ND ND
07/12/06 --- 10.0 ND ND ND ND ND
01/17/07 --- 10.0 ND ND ND ND 3.40 J
01/15/08 --- 10.0 ND ND --- 2.60 J ND
07/14/08 --- 10.0 ND --- ND --- ND
01/19/09 --- 10.0 7.90 B --- ND ND 3.60 J
07/20/09 --- 10.0 --- --- ND 6.32 J ND
01/26/10 --- 10.0 ND 6.48 J ND 7.95 J ND
01/04/11 --- 10.0 5.15 J --- ND ND ND
07/05/11 --- 10.0 ND --- --- --- ND
01/10/12 --- 10.0 ND ND ND ND ND
07/09/12 --- 10.0 --- --- 1.31 J --- ND
01/28/13 --- 10.0 ND ND ND ND ND
07/17/13 --- 10.0 1.24 J --- 1.01 J --- ND
01/28/14 --- 10.0 ND --- ND --- ND
07/24/14 1.13 10.0 ND --- 2.28 J --- ND
01/28/15 1.13 10.0 ND --- ND --- ND
07/30/15 0.75 10.0 --- --- 1.12 J --- ND
01/27/16 0.75 10.0 --- 1.45 J ND --- ND
NC 2B = 10 µg/L 07/27/16 0.75 10.0 --- 5.13 J 1.26 J --- ND
01/25/17 0.75 10.0 ND 2.65 J 1.20 J --- ND
East Carolina Regional Landfill
Permit No. 08-03 Page 1 of 16
Joyce Engineering
TABLE 9
Historical Surface Water Constituents/Analytes
Analyte
Sample Collection
Date DL RL SW-1 SW-2 SW-3 SW-4 Blanks
Total Barium 09/16/93 --- --- 100 60.0 90.0 ------
No NC 2B Standard 09/20/93 --- --- 80.0 50.0 120 ------
09/22/93 --- --- 50.0 60.0 140 ------
09/24/93 --- --- 210 50.0 230 ------
10/04/93 --- --- 40.0 70.0 70.0 ------
01/20/94 --- --- 50.0 130 60.0 40.0 ---
07/28/94 --- --- 40.0 ---60.0 50.0 ---
01/26/95 --- --- 80.0 80.0 100 10.0 ---
07/26/95 --- --- ND ND ND ------
01/23/96 --- --- ND ND ND ------
10/10/96 --- --- ND ND ND ------
04/15/97 --- --- ND ND ND ------
10/23/97 --- --- ND ND ND ------
04/28/98 --- --- ND ND ND ND ---
03/15/05 --- 500 ND ND ND ND ---
07/12/05 --- 500 ND ND ND ND ND
01/19/06 --- 500 ND ND ND ND ND
07/12/06 --- 500 ND ND ND ND ND
01/17/07 --- 100 35.5 44.80 51.90 34.90 0.30 J
01/15/08 --- 100 81.3 J 92.10 J ---24.10 J 0.30 J
07/14/08 --- 100 60.5 J ---78.8 J ---ND
01/19/09 --- 100 82.3 J ---65.2 J 72.20 J ND
07/20/09 --- 100 ------112 159 ND
01/26/10 --- 100 63.1 J 79.7 J 58.8 J 63.4 J 0.43 J
01/04/11 --- 100 56.9 J ---59.60 J 87.60 J 1.11 J
07/05/11 --- 100 110 ---------ND
01/10/12 --- 100 47.4 J 82.1 J 65.0 J 112 0.24 J
07/09/12 --- 100 ------105 ---0.75 J
01/28/13 --- 100 124 49.60 J 72.6 J 92.70 J ND
07/17/13 --- 100 64.8 J ---69.1 J ---0.37 J
01/28/14 --- 100 74.5 J ---73.3 J ---ND
07/24/14 0.10 100 54.2 J ---101 ---0.32 J
01/28/15 0.10 100 46.5 J ---45.8 J ---0.12 J
07/30/15 0.30 100 ------16.5 J ---0.45 J
01/27/16 0.30 100 ---58.8 J 30.6 J ---0.42 J
NC 2B = 200,000 µg/L 07/27/16 0.30 100 ---53.1 J ------0.31 J
01/25/17 0.30 100 47.1 J 106 81.2 J ---0.30 J
Total Beryllium 07/12/05 --- 2.00 ND ND ND ND ND
NC 2B = 6.5 µg/L 01/19/06 --- 2.00 ND ND ND ND ND
07/12/06 --- 2.00 ND ND ND ND ND
01/17/07 --- 1.00 ND ND ND ND ND
01/15/08 --- 1.00 ND ND ---ND ND
07/14/08 --- 1.00 ND ---ND ---ND
01/19/09 --- 1.00 0.10 J ---ND ND ND
07/20/09 --- 1.00 ------ND 1.0 0.08 J
01/26/10 --- 1.00 0.26 J 0.3 J 0.21 J 0.4 J ND
01/04/11 --- 1.00 0.21 J ---0.18 J 0.2 J ND
07/05/11 --- 1.00 0.27 J ---------ND
01/10/12 --- 1.00 0.15 J ND 0.70 J 0.4 J ND
07/09/12 --- 1.00 ------ND ---ND
01/28/13 --- 1.00 0.25 J ND ND 0.2 J ND
07/17/13 --- 1.00 0.30 J ---0.32 J ---ND
01/28/14 --- 1.00 0.25 J ---ND ---ND
07/24/14 0.05 1.00 0.24 J ---0.21 J ---ND
01/28/15 0.05 1.00 0.18 J ---0.14 J ---ND
07/30/15 0.09 1.00 ------ND ---ND
01/27/16 0.09 1.00 ---ND 0.12 J ---ND
NC 2B = 6.5 µg/L (d)07/27/16 0.09 1.00 ---ND 0.10 J ---ND
01/25/17 0.09 1.00 0.17 J ND 0.14 J ---ND
East Carolina Regional Landfill
Permit No. 08-03 Page 2 of 16
Joyce Engineering
TABLE 9
Historical Surface Water Constituents/Analytes
Analyte
Sample Collection
Date DL RL SW-1 SW-2 SW-3 SW-4 Blanks
Total Cadmium 09/16/93 --- --- ND ND 1.0 ------
NC 2B = 2 µg/L 09/20/93 --- --- 1.0 ND ND ------
09/22/93 --- --- ND ND ND ------
09/24/93 --- --- ND ND ND ------
10/04/93 --- --- ND ND ND ------
01/20/94 --- --- ND ND ND ND ---
07/28/94 --- --- 5.00 ---ND ND ---
01/26/95 --- --- ND ---ND ND ---
07/26/95 --- --- ND ND ND ------
01/23/96 --- --- ND ND ND ------
10/10/96 --- --- ND ND ND ------
04/15/97 --- --- ND ND ND ------
10/23/97 --- --- ND ND ND ------
04/28/98 --- --- 1.30 ND ND ND ---
03/15/05 --- 1.00 ND ND ND ND ---
07/12/05 --- 1.00 ND ND ND ND ND
01/19/06 --- 1.00 ND ND ND ND ND
07/12/06 --- 1.00 ND ND ND ND ND
01/17/07 --- 1.00 ND ND ND ND ND
01/15/08 --- 1.00 ND ND ---ND ND
07/14/08 --- 1.00 ND ---ND ---ND
01/19/09 --- 1.00 0.40 J ---ND ND ND
07/20/09 --- 1.00 ------ND 0.27 B 0.11 J
01/26/10 --- 1.00 0.35 B 0.41 B 0.24 B 0.69 B 0.28 J
01/04/11 --- 1.00 ND ---ND ND ND
07/05/11 --- 1.00 ND ---------ND
01/10/12 --- 1.00 ND ND ND ND ND
07/09/12 --- 1.00 ------ND ---ND
01/28/13 --- 1.00 ND ND ND ND ND
07/17/13 --- 1.00 ND ---0.6 J ---ND
01/28/14 --- 1.00 0.06 J ---ND ---ND
07/24/14 0.05 1.00 ND ---ND ---ND
01/28/15 0.05 1.00 ND ---ND ---ND
07/30/15 0.05 1.00 ------ND ---ND
01/27/16 0.1 1.00 ---ND ND ---ND
NC 2B = 0.15 µg/L (d)(h)07/27/16 0.1 1.00 ---ND ND ---ND
01/25/17 0.1 1.00 ND ND ND ---ND
East Carolina Regional Landfill
Permit No. 08-03 Page 3 of 16
Joyce Engineering
TABLE 9
Historical Surface Water Constituents/Analytes
Analyte
Sample Collection
Date DL RL SW-1 SW-2 SW-3 SW-4 Blanks
Total Chromium 09/16/93 --- --- ND ND 10 ------
NC 2B = 50 µg/L 09/20/93 --- --- ND ND ND ------
09/22/93 --- --- ND ND 10.00 ------
09/24/93 --- --- 70.00 ND 70.00 ------
10/04/93 --- --- 1.00 ND ND ------
01/20/94 --- --- ND ND ND ND ---
07/28/94 --- --- ND ---ND ND ---
01/26/95 --- --- ND ND ND ND ---
07/26/95 --- --- ND ND ND ------
01/23/96 --- --- ND ND ND ------
10/10/96 --- --- ND ND ND ------
04/15/97 --- --- ND ND ND ------
10/23/97 --- --- ND ND ND ------
04/28/98 --- --- ND ND ND ND ---
10/28/98 --- 10.0 ND ND ---------
04/07/99 --- 10.0 ND ND ND ND ---
12/08/99 --- 10.0 ND ---ND ND ---
04/27/00 --- 10.0 ND ND ND ND ---
10/18/00 --- 10.0 ND ---ND ------
04/18/01 --- 10.0 ND ND ND ND ---
10/24/01 --- 10.0 ND ND ND ND ---
04/23/02 --- 10.0 ND ND ND ND ---
10/23/02 --- 10.0 ND ND ND ND ---
04/01/03 --- 10.0 ND ND ND ND ---
10/27/03 --- 10.0 ND 40.00 ND ------
04/27/04 --- 10.0 ND 40.00 ND ND ---
10/26/04 --- 10.0 ND ND ND ND ---
03/15/05 --- 10.0 ND ND ND ND ND
07/12/05 --- 10.0 ND ND ND ND ND
01/19/06 --- 10.0 ND ND ND ND ND
07/12/06 --- 10.0 ND ND ND ND ND
01/17/07 --- 10.0 ND 3.30 J ND ND ND
01/15/08 --- 10.0 ND ND ---ND ND
07/14/08 --- 10.0 1.6 J ---ND ---ND
01/19/09 --- 10.0 2.90 J ---ND 3.40 J ND
07/20/09 --- 10.0 ------ND 38.30 ND
01/26/10 --- 10.0 ND 12.10 2.12 J 13.10 ND
01/04/11 --- 10.0 1.10 J ---1.40 J 5.21 J ND
07/05/11 --- 10.0 5.03 J ---------ND
01/10/12 --- 10.0 2.60 J 1.63 J 0.63 J 8.60 J ND
07/09/12 --- 10.0 ------ND ---ND
01/28/13 --- 10.0 1.82 B 3.22 B 2.92 B 7.65 B 1.38 J
07/17/13 --- 10.0 2.99 J ---4.30 J ---ND
01/28/14 --- 10.0 6.12 J ---2.13 J ---2.84 J
07/24/14 0.73 10.0 1.00 J ---2.49 J ---ND
01/28/15 0.73 10.0 1.89 J ---1.55 J ---ND
07/30/15 0.43 10.0 ------ND ---ND
01/27/16 0.43 10.0 ---4.06 J 1.71 J ---ND
NC 2B = 24 µg/L (d)(h)07/27/16 0.43 10.0 ---3.05 J 1.53 J ---ND
01/25/17 0.43 10.0 1.92 J 9.27 J 2.71 J ---ND
East Carolina Regional Landfill
Permit No. 08-03 Page 4 of 16
Joyce Engineering
TABLE 9
Historical Surface Water Constituents/Analytes
Analyte
Sample Collection
Date DL RL SW-1 SW-2 SW-3 SW-4 Blanks
Total Cobalt 09/16/93 --- --- ND ND ND --- ---
No NC 2B Standard 09/20/93 --- --- ND ND ND --- ---
09/22/93 --- --- ND ND ND --- ---
09/24/93 --- --- ND ND ND ------
10/04/93 --- --- ND ND ND ------
01/20/94 --- --- ND ND ND ND ---
07/28/94 --- --- ND ---ND ND ---
01/26/95 --- --- ND 10.00 ND ND ---
07/26/95 --- --- ND ND ND ------
01/23/96 --- --- ND ND ND ------
10/10/96 --- --- ND ND ND ------
04/15/97 --- --- ND ND ND ------
10/23/97 --- --- ND ND ND ------
04/28/98 --- --- ND ND ND ND ---
10/28/98 --- 10.0 ND ND ---------
04/07/99 --- 10.0 ND ND ND ND ---
12/08/99 --- 10.0 ND ---ND ND ---
04/27/00 --- 10.0 ND ND ND ND ---
10/18/00 --- 10.0 ND ---ND ------
04/18/01 --- 10.0 ND ND ND ND ---
10/24/01 --- 10.0 ND ND ND ND ---
04/23/02 --- 10.0 ND ND ND ND ---
10/23/02 --- 10.0 ND ND ND ND ---
04/01/03 --- 10.0 ND ND ND ND ---
10/27/03 --- 10.0 ND 10.00 ND ------
04/27/04 --- 10.0 ND ND ND ND ---
10/26/04 --- 10.0 ND ND ND ND ---
03/15/05 --- 10.0 ND ND ND ND ND
07/12/05 --- 10.0 ND ND ND ND ND
01/19/06 --- 10.0 ND ND ND ND ND
07/12/06 --- 10.0 ND ND ND ND ND
01/17/07 --- 10.0 ND ND ND ND ND
01/15/08 --- 10.0 ND 2.90 J ---ND ND
07/14/08 --- 10.0 ND ---ND ---ND
01/19/09 --- 10.0 4.40 J ---ND 1.50 J ND
07/20/09 --- 10.0 ------0.97 J 5.81 J ND
01/26/10 --- 10.0 2.14 B 2.85 J 1.29 B 2.70 J 0.49 J
01/04/11 --- 10.0 1.51 J ---ND 3.01 J ND
07/05/11 --- 10.0 ND ---------ND
01/10/12 --- 10.0 1.50 J 0.69 J 0.86 J 5.03 J ND
07/09/12 --- 10.0 ------1.63 J ---ND
01/28/13 --- 10.0 2.30 J 1.03 J 1.32 J 3.34 J ND
07/17/13 --- 10.0 2.40 J ---1.73 J ---ND
01/28/14 --- 10.0 1.77 J ---0.77 J ---ND
07/24/14 0.26 10.0 1.64 J ---1.81 J ---ND
01/28/15 0.26 10.0 1.46 J ---0.85 J ---ND
07/30/15 0.29 10.0 ------0.36 J ---ND
01/27/16 0.29 10.0 ---1.54 J 0.63 J ---ND
07/27/16 0.29 10.0 ---1.32 J 2.94 J ---ND
01/25/17 0.29 10.0 1.18 J 3.22 J 4.26 J ---ND
East Carolina Regional Landfill
Permit No. 08-03 Page 5 of 16
Joyce Engineering
TABLE 9
Historical Surface Water Constituents/Analytes
Analyte
Sample Collection
Date DL RL SW-1 SW-2 SW-3 SW-4 Blanks
Total Copper 09/16/93 --- --- ND ND ND ------
NC 2B = 7 µg/L 09/20/93 --- --- ND ND 30.0 ------
09/22/93 --- --- ND ND 30.0 ------
09/24/93 --- --- 20.0 ND 30.0 ------
10/04/93 --- --- ND ND ND ------
01/20/94 --- --- ND ND ND ND ---
07/28/94 --- --- ND ---ND ND ---
01/26/95 --- --- ND ND ND ND ---
07/26/95 --- --- ND ND ND ------
01/23/96 --- --- ND ND ND ------
10/10/96 --- --- ND ND ND ------
04/15/97 --- --- ND ND ND ------
10/23/97 --- --- ND 50.0 ND ------
04/28/98 --- --- ND ND ND ND ---
03/15/05 --- 200 ND ND ND ND ND
07/12/05 --- 200 ND ND ND ND ND
01/19/06 --- 200 ND ND ND ND ND
07/12/06 --- 200 ND ND ND ND ND
01/17/07 --- 10.0 ND 4.50 J ND ND ND
01/15/08 --- 10.0 ND ND ---ND 0.70 J
07/14/08 --- 10.0 ND ---ND ---ND
01/19/09 --- 10.0 3.20 J ---ND ND ND
07/20/09 --- 10.0 ------ND 6.67 J 1.25 J
01/26/10 --- 10.0 ND 3.19 J ND 4.25 J ND
01/04/11 --- 10.0 ND ---1.67 J 2.02 J ND
07/05/11 --- 10.0 1.83 J ---------ND
01/10/12 --- 10.0 1.74 B 2.04 B 0.98 B 4.10 J 0.66 J
07/09/12 --- 10.0 ------ND ---ND
01/28/13 --- 10.0 1.27 B 6.90 J 1.30 B 3.79 J 0.26 J
07/17/13 --- 10.0 2.44 J ---3.70 J ---ND
01/28/14 --- 10.0 2.34 J ---17.6 ---ND
07/24/14 0.22 10.0 1.67 J ---2.54 J ---ND
01/28/15 0.22 10.0 0.86 J ---2.47 J ---ND
07/30/15 0.41 10.0 ------1.29 B ---1.31 J
01/27/16 0.41 10.0 ---12.8 1.79 J ---2.44 J
NC 2B = 2.7 µg/L (d)(h)07/27/16 0.41 10.0 ---2.94 J 0.65 J ---8.47 J
*2B Calc. for SW-2 = 18.72 µg/L 01/25/17 0.41 10.0 0.96 B 16.4 2.08 B ---0.59 J
East Carolina Regional Landfill
Permit No. 08-03 Page 6 of 16
Joyce Engineering
TABLE 9
Historical Surface Water Constituents/Analytes
Analyte
Sample Collection
Date DL RL SW-1 SW-2 SW-3 SW-4 Blanks
Total Lead 09/16/93 --- --- ND ND 31.0 ------
NC 2B = 25 µg/L 09/20/93 --- --- 16.0 9.0 19.0 ------
09/22/93 --- --- 7.0 ND 33.0 ------
09/24/93 --- --- 36.0 ND 44.0 ------
10/04/93 --- --- 9.0 ND ND ------
01/20/94 --- --- ND ND ND ND ---
07/28/94 --- --- ND ---ND ND ---
01/26/95 --- --- ND ND ND ND ---
07/26/95 --- --- ND ND ND ------
01/23/96 --- --- ND ND ND ------
10/10/96 --- --- ND ND ND ------
04/15/97 --- --- ND ND ND ------
10/23/97 --- --- ND ND ND ------
04/28/98 --- --- ND ND ND ND ---
10/28/98 --- 10.0 ND ND ---------
04/07/99 --- 10.0 ND ND ND ND ---
12/08/99 --- 10.0 ND ---ND ND ---
04/27/00 --- 10.0 ND ND ND ND ---
10/18/00 --- 10.0 ND ---ND ------
04/18/01 --- 10.0 ND ND ND ND ---
10/24/01 --- 10.0 ND ND ND ND ---
04/23/02 --- 10.0 ND ND ND ND ---
10/23/02 --- 10.0 ND ND ND ND ---
04/01/03 --- 10.0 ND ND ND ND ---
10/27/03 --- 10.0 ND 30.0 ND ------
04/27/04 --- 10.0 ND 20.0 ND ND ---
10/26/04 --- 10.0 ND ND ND ND ---
03/15/05 --- 10.0 ND ND ND ND ND
07/12/05 --- 10.0 ND ND ND ND ND
01/19/06 --- 10.0 ND ND ND ND ND
07/12/06 --- 10.0 ND ND ND ND ND
01/17/07 --- 10.0 ND ND 2.70 J ND ND
01/15/08 --- 10.0 ND ND ---ND ND
07/14/08 --- 10.0 2.40 J ---ND ---ND
01/19/09 --- 10.0 ND ---ND ND ND
07/20/09 --- 10.0 ------1.65 B 18.40 2.16 J
01/26/10 --- 10.0 ND 7.63 J 1.42 J 9.38 J ND
01/04/11 --- 10.0 ND ---ND ND ND
07/05/11 --- 10.0 10.3 ---------ND
01/10/12 --- 10.0 2.59 B 3.04 B 1.40 B 4.39 B 0.94 J
07/09/12 --- 10.0 ------0.41 J ---ND
01/28/13 --- 10.0 0.94 J 1.26 J 0.65 J 4.32 J ND
07/17/13 --- 10.0 3.02 J ---2.60 J ---ND
01/28/14 --- 10.0 1.77 J ---0.82 J ---ND
07/24/14 0.05 10.0 1.98 J ---1.93 J ---ND
01/28/15 0.05 10.0 0.69 B ---0.71 B ---0.34 J
07/30/15 0.08 10.0 ------ND ---ND
01/27/16 0.08 10.0 ---0.36 J 0.72 J ---ND
NC 2B = 14 µg/L acute; (d)(h)07/27/16 0.08 10.0 ---1.65 J 0.66 J ---ND
= 0.54 chronic; (d)(h)01/25/17 0.08 10.0 1.21 J 1.29 J 1.31 J ---ND
East Carolina Regional Landfill
Permit No. 08-03 Page 7 of 16
Joyce Engineering
TABLE 9
Historical Surface Water Constituents/Analytes
Analyte
Sample Collection
Date DL RL SW-1 SW-2 SW-3 SW-4 Blanks
Total Nickel 09/16/93 --- --- ND ND ND ------
NC 2B = 25 µg/L 09/20/93 --- --- ND ND ND ------
09/22/93 --- --- ND ND ND ------
09/24/93 --- --- ND ND ND ------
10/04/93 --- --- 30.0 ND ND ------
01/20/94 --- --- ND ND ND ND ---
07/28/94 --- --- ND ---ND ND ---
01/26/95 --- --- ND ND ND ND ---
07/26/95 --- --- ND ND ND ------
01/23/96 --- --- ND ND ND ------
10/10/96 --- --- ND ND ND ------
04/15/97 --- --- ND ND ND ------
10/23/97 --- --- ND ND ND ------
04/28/98 --- --- ND ND ND ND ---
10/28/98 --- 50.0 ND ND ---------
04/07/99 --- 50.0 ND ND ND ND ---
12/08/99 --- 50.0 50.0 ---ND ND ---
04/27/00 --- 50.0 ND ND ND ND ---
10/18/00 --- 50.0 ND ---ND ------
04/18/01 --- 50.0 ND ND ND ND ---
10/24/01 --- 50.0 ND ND ND ND ---
04/23/02 --- 50.0 ND ND ND ND ---
10/23/02 --- 50.0 ND ND ND ND ---
04/01/03 --- 50.0 ND ND ND ND ---
10/27/03 --- 50.0 ND ND ND ------
04/27/04 --- 50.0 ND ND ND ND ---
10/26/04 --- 50.0 ND ND ND ND ---
03/15/05 --- 50.0 ND ND ND ND ND
07/12/05 --- 50.0 ND ND ND ND ND
01/19/06 --- 50.0 ND ND ND ND ND
07/12/06 --- 50.0 ND ND ND ND ND
01/17/07 --- 50.0 ND 3.80 J 2.80 J 3.00 J ND
01/15/08 --- 50.0 ND 2.40 J ---ND ND
07/14/08 --- 50.0 ND ---ND ---ND
01/19/09 --- 50.0 ND ---2.10 B 4.00 B 2.20 J
07/20/09 --- 50.0 ------1.72 J 11.40 J ND
01/26/10 --- 50.0 ND 2.83 J ND 2.43 J ND
01/04/11 --- 50.0 ND ---ND 3.41 J ND
07/05/11 --- 50.0 2.76 J ---------ND
01/10/12 --- 50.0 2.09 J 3.92 J 1.67 J 7.58 J ND
07/09/12 --- 50.0 ------1.10 J ---ND
01/28/13 --- 50.0 2.08 J 5.04 J 1.90 J 4.94 J ND
07/17/13 --- 50.0 3.23 J ---3.40 J ---ND
01/28/14 --- 50.0 2.25 J ---3.88 J ---ND
07/24/14 0.22 50.0 2.27 J ---3.28 J ---ND
01/28/15 0.22 50.0 1.28 J ---2.09 J ---ND
07/30/15 0.48 50.0 ------0.78 J ---ND
01/27/16 0.48 50.0 ---8.69 J 1.52 J ---ND
NC 2B = 16 µg/L chronic; (d)(h)07/27/16 0.48 50.0 ---7.46 J 2.06 J ---ND
01/25/17 0.48 50.0 1.50 J 18.1 J 3.83 J ---ND
East Carolina Regional Landfill
Permit No. 08-03 Page 8 of 16
Joyce Engineering
TABLE 9
Historical Surface Water Constituents/Analytes
Analyte
Sample Collection
Date DL RL SW-1 SW-2 SW-3 SW-4 Blanks
Total Selenium 07/12/05 --- 20.00 ND ND ND ND ND
NC 2B = 5 µg/L 01/19/06 --- 20.0 ND ND ND ND ND
07/12/06 --- 20.0 ND ND ND ND ND
01/17/07 --- 10.0 ND ND 3.40 J ND ND
01/15/08 --- 10.0 ND ND ---ND ND
07/14/08 --- 10.0 ND ---ND ---ND
01/19/09 --- 10.0 ND ---ND ND ND
07/20/09 --- 10.0 ------ND 6.2 B 3.58 J
01/26/10 --- 10.0 ND 1.74 J 0.937 J ND ND
01/04/11 --- 10.0 ND ---ND ND ND
07/05/11 --- 10.0 ND ---------ND
01/10/12 --- 10.0 ND ND ND ND ND
07/09/12 --- 10.0 ------ND ---ND
01/28/13 --- 10.0 ND 0.99 J ND ND ND
07/17/13 --- 10.0 ND ---ND ---ND
01/28/14 --- 10.0 ND ---ND ---ND
07/24/14 1.01 10.0 ND ---ND ---ND
01/28/15 1.01 10.0 ND ---ND ---ND
07/30/15 0.85 10.0 ------ND ---ND
01/27/16 0.85 10.0 ---0.98 J ND ---ND
NC 2B = 5 µg/L 07/27/16 0.85 10.0 ---1.00 J ND ---ND
01/25/17 0.85 10.0 ND ND 0.98 J ---ND
Total Silver 09/16/93 --- --- ND ND ND ------
NC 2B = 0.06 µg/L 09/20/93 --- --- ND ND ND ------
09/22/93 --- --- ND 10.00 ND ------
09/24/93 --- --- ND ND ND ------
10/04/93 --- --- ND ND ND ------
01/20/94 --- --- ND ND ND ND ---
07/28/94 --- --- ND ---ND ND ---
01/26/95 --- --- ND ND ND ND ---
07/26/95 --- --- ND ND ND ------
01/23/96 --- --- ND ND ND ------
10/10/96 --- --- ND ND ND ------
03/15/05 --- 10.0 ND ND ND ND ND
07/12/05 --- 10.0 ND ND ND ND ND
01/19/06 --- 10.0 ND ND ND ND ND
07/12/06 --- 10.0 ND ND ND ND ND
01/17/07 --- 10.0 ND ND ND ND ND
01/15/08 --- 10.0 ND ND ---ND ND
07/14/08 --- 10.0 ND ---ND ---ND
01/19/09 --- 10.0 2.40 J ---ND ND ND
07/20/09 --- 10.0 ------ND ND ND
01/26/10 --- 10.0 1.93 B 2.43 B 1.68 B 2.19 B 1.25 J
01/04/11 --- 10.0 ND ---ND ND ND
07/05/11 --- 10.0 ND ---------ND
01/10/12 --- 10.0 ND ND ND ND ND
07/09/12 --- 10.0 ------ND ---ND
01/28/13 --- 10.0 ND ND ND ND ND
07/17/13 --- 10.0 ND ---ND ---ND
01/28/14 --- 10.0 ND ---ND ---ND
07/24/14 0.17 10.0 ND ---ND ---ND
01/28/15 0.17 10.0 ND ---ND ---ND
07/30/15 0.22 10.0 ------ND ---ND
01/27/16 0.22 10.0 ---ND ND ---ND
NC 2B = 0.06 µg/L, chronic (d)(h)07/27/16 0.22 10.0 ---ND ND ---ND
01/25/17 0.22 10.0 ND ND ND ---ND
Total Thallium 07/12/05 --- 10.0 ND ND ND ND ND
01/19/06 --- 10.0 ND ND ND ND ND
07/12/06 --- 10.0 ND ND ND ND ND
01/17/07 --- 5.5 ND ND ND ND ND
01/15/08 --- 5.5 0.04 J 0.06 J ---ND ND
07/14/08 --- 5.5 ND ---ND ---ND
01/19/09 --- 5.5 ND ---ND ND ND
07/20/09 --- 5.5 ------ND 0.05 J ND
01/26/10 --- 5.5 ND ND ND ND ND
01/04/11 --- 5.5 ND ---ND ND ND
07/05/11 --- 5.5 ND ---------ND
01/10/12 --- 5.5 ND ND ND 0.08 J ND
07/09/12 --- 5.5 ------ND ---ND
01/28/13 --- 5.5 ND ND ND ND ND
07/17/13 --- 5.5 ND ---ND ---ND
01/28/14 --- 5.5 ND ---ND ---ND
07/24/14 0.09 5.5 ND ---ND ---ND
01/28/15 0.09 5.5 ND ---ND ---ND
07/30/15 0.06 5.5 ------ND ---ND
01/27/16 0.06 5.5 ---ND ND ---ND
NC 2B=0.47 µg/L, HH* (3/2016)07/27/16 0.06 5.5 ---ND ND ---ND
01/25/17 0.06 5.5 ND ND ND ---ND
East Carolina Regional Landfill
Permit No. 08-03 Page 9 of 16
Joyce Engineering
TABLE 9
Historical Surface Water Constituents/Analytes
Analyte
Sample Collection
Date DL RL SW-1 SW-2 SW-3 SW-4 Blanks
Total Vanadium 09/16/93 --- --- ND ND 40.0 ------
No NC 2B Standard 09/20/93 --- --- ND ND 70.0 ------
09/22/93 --- --- 30.0 ND 100 ------
09/24/93 --- --- 280 ND 200 ------
10/04/93 --- --- ND ND ND ------
01/20/94 --- --- ND ND ND ND ---
07/28/94 --- --- ND ---ND ND ---
01/26/95 --- --- ND ND ND ND ---
07/26/95 --- --- ND ND ND ------
01/23/96 --- --- ND ND ND ------
10/10/96 --- --- ND ND ND ------
04/15/97 --- --- ND ND ND ------
10/23/97 --- --- ND ND ND ------
04/28/98 --- --- ND ND ND ND ---
10/28/98 --- 40.0 ND ND ---------
04/07/99 --- 40.0 ND ND ND ND ---
12/08/99 --- 40.0 ND ---ND ND ---
04/27/00 --- 40.0 ND ND ND ND ---
10/18/00 --- 40.0 ND ---ND ------
04/18/01 --- 40.0 ND ND ND ND ---
10/24/01 --- 40.0 ND ND ND ND ---
04/23/02 --- 40.0 ND ND ND ND ---
10/23/02 --- 40.0 ND ND ND ND ---
04/01/03 --- 40.0 ND ND ND ND ---
10/27/03 --- 40.0 ND 60.0 ND ------
04/27/04 --- 40.0 ND 60.0 ND ND ---
10/26/04 --- 40.0 ND ND ND ND ---
03/15/05 --- 40.0 ND ND ND ND ND
07/12/05 --- 40.0 ND ND ND ND ND
01/19/06 --- 40.0 ND ND ND ND ND
07/12/06 --- 40.0 ND ND ND ND ND
01/17/07 --- 25.0 2.20 J 2.80 J 2.30 J 2.20 J ND
01/15/08 --- 25.0 4.10 J ND ---1.00 B 1.00 J
07/14/08 --- 25.0 6.30 J ---ND ---ND
01/19/09 --- 25.0 2.30 J ---ND 5.70 J ND
07/20/09 --- 25.0 ------2.11 B 69.00 0.80 J
01/26/10 --- 25.0 1.01 J 23.80 J 4.21 J 23.80 J ND
01/04/11 --- 25.0 1.51 J ---2.02 J 10.00 J ND
07/05/11 --- 25.0 17.20 J ---------ND
01/10/12 --- 25.0 7.62 J 3.93 J ND 13.20 J ND
07/09/12 --- 25.0 ------ND ---ND
01/28/13 --- 25.0 3.62 B 9.56 B 3.68 B 10.60 B 2.7 J
07/17/13 --- 25.0 5.65 J ---8.30 J ---ND
01/28/14 --- 25.0 2.37 J ---3.11 J ---ND
07/24/14 0.93 25.0 4.77 B ---7.41 J ---1.41 J
01/28/15 0.93 25.0 1.03 J ---1.97 J ---ND
07/30/15 1.57 25.0 ------2.73 J ---ND
01/27/16 1.57 25.0 ---4.05 J 3.34 J ---ND
07/27/16 1.57 25.0 ---4.54 J 1.93 J ---ND
01/25/17 1.57 25.0 ND 6.42 J 3.52 J ---ND
East Carolina Regional Landfill
Permit No. 08-03 Page 10 of 16
Joyce Engineering
TABLE 9
Historical Surface Water Constituents/Analytes
Analyte
Sample Collection
Date DL RL SW-1 SW-2 SW-3 SW-4 Blanks
Total Zinc 09/16/93 --- --- 30.0 20.0 60.0 ------
NC 2B = 50 µg/L 09/20/93 --- --- 130 40.0 120 ------
09/22/93 --- --- 100 60.0 340 ------
09/24/93 --- --- 240 70.0 420 ------
10/04/93 --- --- 1000 190 70 ------
01/20/94 --- --- 60.0 200 70 70.0 ---
07/28/94 --- --- 120 ---ND 30.0 ---
01/26/95 --- --- ND 30 60 60.0 ---
07/26/95 --- --- ND ND ND ------
01/23/96 --- --- ND ND ND ------
10/10/96 --- --- ND ND ND ------
04/15/97 --- --- 80.0 60.0 60.0 ------
10/23/97 --- --- 100 60.0 30.0 ------
04/28/98 --- --- 50.0 ND ND ND ---
10/28/98 --- 50.0 ND ND ---------
04/07/99 --- 50.0 30.0 40.0 30.0 40.0 ---
12/08/99 --- 50.0 60.0 ---50.0 60.0 ---
04/27/00 --- 50.0 ND 70.0 60.0 ND ---
10/18/00 --- 50.0 50.0 ---70.0 ------
04/18/01 --- 50.0 ND ND ND ND ---
10/24/01 --- 50.0 ND ND ND ND ---
04/23/02 --- 50.0 ND 50.0 ND ND ---
10/23/02 --- 50.0 ND 60.0 ND ND ---
04/01/03 --- 50.0 60.0 30.0 50 70.0 ---
10/27/03 --- 50.0 ND 130 70 ------
04/27/04 --- 50.0 ND 60.0 ND ND ---
10/26/04 --- 50.0 ND ND ND ND ---
03/15/05 --- 50.0 ND ND ND ND ND
07/12/05 --- 50.0 100 ND ND ND ND
01/19/06 --- 50.0 ND ND 79.0 ND ND
07/12/06 --- 50.0 ND ND ND ND ND
01/17/07 --- 10.0 15.8 B 9.20 B 16.90 B 11.60 B 5.50 J
01/15/08 --- 10.0 8.7 J 13.60 ---5.70 B 1.30 J
07/14/08 --- 10.0 17.3 B ---7.80 B ---5.00 J
01/19/09 --- 10.0 17.0 ---14.00 33.20 ND
07/20/09 --- 10.0 ------6.05 J 55.60 ND
01/26/10 --- 10.0 8.1 J 17.40 9.78 J 35.20 ND
01/04/11 --- 10.0 5.8 J ---8.05 J 64.00 ND
07/05/11 --- 10.0 10.5 ---------ND
01/10/12 --- 10.0 10.2 B 57.30 B 5.39 B 132.00 15.90
07/09/12 --- 10.0 ------1.37 J ---0.30 J
01/28/13 --- 10.0 10.9 5.11 B 4.93 B 86.50 0.57 J
07/17/13 --- 10.0 17.8 ---11.80 ---ND
01/28/14 --- 10.0 15.7 ---4.51 J ---ND
07/24/14 0.64 10.0 6.84 J ---10.2 ---0.71 J
01/28/15 0.64 10.0 6.30 B ---6.99 J ---1.38 J
07/30/15 0.64 10.0 ------4.76 J ---ND
01/27/16 1.3 10.0 ---7.24 J 5.42 J ---ND
NC 2B = 36 µg/L, (d)(h)07/27/16 1.3 10.0 ---7.01 J 5.20 J ---1.51 J
01/25/17 1.3 10.0 6.59 B 16.10 8.33 B ---2.13 J
East Carolina Regional Landfill
Permit No. 08-03 Page 11 of 16
Joyce Engineering
TABLE 9
Historical Surface Water Constituents/Analytes
Analyte
Sample Collection
Date DL RL SW-1 SW-2 SW-3 SW-4 Blanks
Organic Compounds
Acetone 07/12/05 --- 100 ND ND ND ND ND
No NC 2B Standard 01/19/06 --- 100 ND ND ND ND ND
07/12/06 --- 100 ND ND ND ND ND
01/17/07 --- 100 ND ND ND ND ND
01/15/08 --- 100 ND ND --- ND ND
07/14/08 --- 100 ND --- 8.90 J --- ND
01/19/09 --- 100 ND --- ND ND ND
07/20/09 --- 100 --- --- 5.70 J ND ND
01/26/10 --- 100 ND ND ND ND ND
01/04/11 --- 100 ND --- ND ND ND
07/05/11 --- 100 7.40 J --- --- --- ND
01/10/12 --- 100 ND ND ND ND ND
07/09/12 --- 100 --- --- ND --- ND
01/28/13 --- 100 ND ND ND ND ND
07/17/13 --- 100 ND --- ND --- ND
01/28/14 --- 100 ND --- ND --- 5.80 J
07/24/14 5.7 100 ND --- 5.8 J --- ND
01/28/15 5.7 100 ND --- ND --- ND
07/30/15 3.1 100 --- --- ND --- ND
01/27/16 4.9 100 --- ND ND --- ND
07/27/16 4.9 100 --- ND ND --- ND
01/25/17 8.2 100 ND ND ND --- ND
Benzene 01/28/15 0.2 1.0 0.2 J --- ND --- ND
NC 2B = 51 µg/L 07/30/15 0.2 1.0 --- --- ND --- ND
01/27/16 0.2 1.0 --- ND ND --- ND
07/27/16 0.2 1.0 --- ND ND --- ND
01/25/17 0.2 1.0 ND ND ND --- ND
Chloroform 07/30/15 0.2 5.0 --- --- 1.0 J --- ND
01/27/16 0.3 5.0 --- ND ND --- ND
07/27/16 0.3 5.0 --- ND ND --- ND
01/25/17 0.6 5.0 ND ND ND --- ND
4-Methyl-2-pentanone (MIBK) 09/24/93 --- --- 150.00 ND ND --- ND
NC 2B = 26 µg/L 03/15/05 --- 100 ND ND ND ND ND
07/12/05 --- 100 ND ND ND ND ND
01/19/06 --- 10 ND ND ND ND ND
07/12/06 --- 100 ND ND ND ND ND
01/17/07 --- 100 ND ND ND ND ND
01/15/08 --- 100 ND ND --- ND ND
07/14/08 --- 100 ND --- ND --- ND
01/19/09 --- 100 ND --- ND ND ND
07/20/09 --- 100 --- --- ND ND ND
01/26/10 --- 100 ND ND ND ND ND
01/04/11 --- 100 ND --- ND ND ND
07/05/11 --- 100 ND --- --- --- ND
01/10/12 --- 100 ND ND ND ND ND
07/09/12 --- 100 --- --- ND --- ND
01/28/13 --- 100 ND ND ND ND ND
07/17/13 --- 100 ND --- ND --- ND
01/28/14 --- 100 ND --- ND --- ND
07/24/14 1.4 100 ND --- 6.0 J --- ND
01/28/15 1.4 100 ND --- ND --- ND
07/30/15 1 100 --- --- ND --- ND
01/27/16 1.7 100 --- ND ND --- ND
07/27/16 1.7 100 --- ND ND --- ND
01/25/17 0.9 100 ND ND ND --- ND
East Carolina Regional Landfill
Permit No. 08-03 Page 12 of 16
Joyce Engineering
TABLE 9
Historical Surface Water Constituents/Analytes
Analyte
Sample Collection
Date DL RL SW-1 SW-2 SW-3 SW-4 Blanks
Toluene 10/23/97 --- --- ND ND 20.0 ------
NC 2B = 11 µg/L 10/28/98 --- 5.0 ND ND ---------
04/07/99 --- 5.0 ND ND ND ND ---
12/08/99 --- 5.0 ND ---ND ND ---
04/27/00 --- 5.0 ND ND ND ND ---
10/18/00 --- 5.0 ND ---ND ------
04/18/01 --- 5.0 ND ND ND ND ---
10/24/01 --- 5.0 ND ND ND ND ---
04/23/02 --- 5.0 ND ND ND ND ---
10/23/02 --- 5.0 ND ND ND ND ---
04/01/03 --- 5.0 ND ND ND ND ---
10/27/03 --- 5.0 ND ND ND ------
04/27/04 --- 5.0 ND ND ND ND ---
10/26/04 --- 5.0 ND ND ND ND ---
3/15/2005 --- 5.0 ND ND ND ND ND
07/12/05 --- 5.0 ND ND ND ND ND
01/19/06 --- 5.0 ND ND ND ND ND
07/12/06 --- 5.0 ND ND ND ND ND
01/17/07 --- 5.0 ND ND ND ND ND
01/15/08 --- 1.0 ND ND ---ND ND
07/14/08 --- 1.0 ND ---ND ---ND
01/19/09 --- 1.0 ND ---ND ND ND
07/20/09 --- 1.0 ------ND ND 0.44 J
01/26/10 --- 1.0 ND ND ND ND ND
01/04/11 --- 1.0 ND ---ND ND ND
07/05/11 --- 1.0 ND ---------ND
01/10/12 --- 1.0 ND ND 0.50 J ND ND
07/09/12 --- 1.0 ------ND ---ND
01/28/13 --- 1.0 ND ND ND ND ND
07/17/13 --- 1.0 ND ---0.40 J ---ND
01/28/14 --- 1.0 ND ---ND ---ND
07/24/14 0.2 1.0 ND ---ND ---ND
01/28/15 0.2 1.0 ND ---ND ---ND
07/30/15 0.2 1.0 ------ND ---ND
01/27/16 0.3 1.0 ---ND ND ---ND
07/27/16 0.3 1.0 ---ND 0.30 J ---ND
01/25/17 0.3 1.0 ND ND ND ---ND
Xylenes, total 10/23/97 --- --- ND ND 10.00 ------
NC 2B = 670 µg/L 10/28/98 --- 5.0 ND ND ---------
04/07/99 --- 5.0 ND ND ND ND ---
12/08/99 --- 5.0 ND ---ND ND ---
04/27/00 --- 5.0 ND ND ND ND ---
10/18/00 --- 5.0 ND ---ND ------
04/18/01 --- 5.0 ND ND ND ND ---
10/24/01 --- 5.0 ND ND ND ND ---
04/23/02 --- 5.0 ND ND ND ND ---
10/23/02 --- 5.0 ND ND ND ND ---
04/01/03 --- 5.0 ND ND ND ND ---
10/27/03 --- 5.0 ND ND ND ------
04/27/04 --- 5.0 ND ND ND ND ---
10/26/04 --- 5.0 ND ND ND ND ---
03/15/05 --- 5.0 ND ND ND ND ND
07/12/05 --- 5.0 ND ND ND ND ND
01/19/06 --- 5.0 ND ND ND ND ND
07/12/06 --- 5.0 ND ND ND ND ND
01/17/07 --- 5.0 ND ND ND ND ND
07/14/08 --- 5.0 ND ---ND ---ND
01/19/09 --- 5.0 ND ---ND ND ND
07/20/09 --- 5.0 ------ND ND ND
01/26/10 --- 5.0 ND ND ND ND ND
01/04/11 --- 5.0 ND ---ND ND ND
01/10/12 --- 5.0 ND ND ND ND ND
07/09/12 --- 5.0 ------ND ---ND
01/28/13 --- 5.0 ND ND ND ND ND
07/17/13 --- 5.0 ND ---ND ---ND
01/28/14 --- 5.0 ND ---ND ---ND
07/24/14 0.5 5.0 ND ---ND ---ND
01/28/15 0.5 5.0 ND ---ND ---ND
07/30/15 0.2 5.0 ------ND ---ND
01/27/16 0.4 5.0 ---ND ND ---ND
07/27/16 0.4 5.0 ---ND ------ND
01/25/17 1.4 5.0 ND ND ND ---ND
East Carolina Regional Landfill
Permit No. 08-03 Page 13 of 16
Joyce Engineering
TABLE 9
Historical Surface Water Constituents/Analytes
Analyte
Sample Collection
Date DL RL SW-1 SW-2 SW-3 SW-4 Blanks
Field Parameters
pH 10/28/98 --- --- 7.05 5.47 --- --- ---
(S.U.) 04/07/99 --- --- 5.26 7.18 6.22 6.74 ---
12/08/99 --- --- 5.04 --- 5.56 5.24 ---
04/27/00 --- --- 5.15 6.47 6.02 5.80 ---
10/18/00 --- --- 8.28 --- 6.07 --- ---
04/18/01 --- --- 5.67 7.75 5.96 6.29 ---
10/24/01 --- --- 6.64 6.27 6.39 6.02 ---
04/23/02 --- --- 5.70 6.07 8.16 7.71 ---
10/23/02 --- --- 4.03 6.31 4.78 5.19 ---
04/01/03 --- --- 4.67 8.23 5.80 5.73 ---
10/27/03 --- --- 4.57 5.20 5.55 --- ---
04/27/04 --- --- 4.88 6.12 5.77 6.62 ---
10/26/04 --- --- 5.82 6.04 5.62 5.57 ---
03/15/05 --- --- 4.51 5.96 5.63 5.67 ---
07/13/05 --- --- 5.55 6.18 5.83 5.38 ---
01/19/06 --- --- 3.54 7.25 5.49 4.51 ---
07/12/06 --- --- 7.10 6.07 5.88 5.65 ---
01/17/07 --- --- 4.57 4.20 5.36 5.26 ---
01/15/08 --- --- 5.63 5.42 --- 5.56 ---
07/14/08 --- --- 6.17 --- 6.05 --- ---
01/19/09 --- --- 5.46 --- 4.38 4.42 ---
07/20/09 --- --- --- --- 5.92 5.31 ---
01/26/10 --- --- 3.67 6.56 6.49 7.01 ---
01/04/11 --- --- 4.24 --- 5.51 4.30 ---
07/05/11 --- --- 7.26 --- --- --- ---
01/10/12 --- --- 7.30 6.96 7.30 6.72 ---
07/09/12 --- --- --- --- 6.74 --- ---
01/28/13 --- --- 5.82 8.63 8.98 7.81 ---
07/17/13 --- --- 4.71 --- 5.68 --- ---
01/28/14 --- --- 9.39 --- 5.14 --- ---
07/24/14 --- --- 5.26 --- 6.00 --- ---
01/28/15 --- --- 5.76 --- 7.24 --- ---
07/30/15 --- --- --- --- 9.68 --- ---
01/27/16 --- --- --- 5.26 5.41 --- ---
07/27/16 --- --- --- 5.66 5.51 ---
01/25/17 --- --- 5.30 7.50 7.31 --- ---
Conductivity 10/28/98 --- --- 50.0 109.0 --- --- ---
(µS/cm) 04/07/99 --- --- 31.9 88.3 67.0 55.3 ---
12/08/99 --- --- 29.0 --- 32.0 24.0 ---
04/27/00 --- --- 26.0 143.0 48.0 31.0 ---
10/18/00 --- --- 72.0 --- 136.0 --- ---
04/18/01 --- --- 21.0 75.0 48.0 28.0 ---
10/24/01 --- --- 41.0 99.0 72.0 51.0 ---
04/23/02 --- --- 64.0 79.0 80.0 43.0 ---
10/23/02 --- --- 39.0 87.0 50.0 26.0 ---
04/01/03 --- --- 35.0 121.0 42.0 45.0 ---
10/27/03 --- --- 31.0 48.0 50.0 --- ---
04/27/04 --- --- 58.0 399.0 74.0 72.0 ---
10/26/04 --- --- 62.0 190.0 88.0 40.0 ---
03/15/05 --- --- 32.0 46.0 51.0 38.0 ---
07/13/05 --- --- 64.0 155.0 141.0 76.0 ---
01/19/06 --- --- 31.0 50.0 52.0 43.0 ---
07/12/06 --- --- 50.0 200.0 97.0 101.0 ---
01/17/07 --- --- 14.0 103.0 81.0 51.0 ---
01/15/08 --- --- 108.0 353.0 --- 65.0 ---
01/19/09 --- --- 49.0 --- 121.0 72.0 ---
07/20/09 --- --- --- --- 149.0 85.0 ---
01/26/10 --- --- 40.0 427.0 87.0 45.0 ---
01/04/11 --- --- 34.0 --- 126.0 87.0 ---
07/05/11 --- --- 140.0 --- --- --- ---
01/10/12 --- --- 80.7 510.0 153.0 97.8 ---
07/09/12 --- --- --- --- 245.3 --- ---
01/28/13 --- --- 136.3 567.4 191.5 85.8 ---
07/17/13 --- --- 57.6 --- 97.4 --- ---
01/28/14 --- --- 98.4 --- 154.2 --- ---
07/24/14 --- --- 37.8 --- 20.1 --- ---
01/28/15 --- --- 220.0 --- 73.5 --- ---
07/30/15 --- --- --- --- 136 --- ---
01/27/16 --- --- --- 457.1 47.8 --- ---
07/27/16 --- --- --- 840 229.8 --- ---
01/25/17 --- --- 287.0 970.0 200.8 --- ---
East Carolina Regional Landfill
Permit No. 08-03 Page 14 of 16
Joyce Engineering
TABLE 9
Historical Surface Water Constituents/Analytes
Analyte
Sample Collection
Date DL RL SW-1 SW-2 SW-3 SW-4 Blanks
Temperature 10/28/98 --- --- 13.00 20.30 ---------
(°C)04/07/99 --- --- 18.10 25.10 29.30 23.90 ---
12/08/99 --- --- 8.50 ---11.50 10.60 ---
04/27/00 --- --- 13.10 14.00 13.60 12.60 ---
10/18/00 --- --- 18.10 ---20.10 ------
04/18/01 --- --- 9.20 7.30 8.00 9.10 ---
10/24/01 --- --- 19.30 23.80 25.90 24.90 ---
04/23/02 --- --- 18.70 16.30 26.20 25.40 ---
10/23/02 --- --- 13.50 12.20 12.00 12.00 ---
04/01/03 --- --- 15.40 21.60 26.00 24.20 ---
10/27/03 --- --- 18.60 20.10 20.80 ------
04/27/04 --- --- 16.70 21.90 20.60 22.90 ---
10/26/04 --- --- 15.60 17.40 18.10 17.60 ---
03/15/05 --- --- 12.09 14.65 15.57 10.80 ---
07/13/05 --- --- 25.58 25.31 26.40 24.82 ---
01/19/06 --- --- 8.41 6.76 9.79 9.97 ---
07/12/06 --- --- 24.50 29.70 27.40 25.50 ---
01/17/07 --- --- 11.70 11.80 11.70 11.70 ---
07/17/08 --- --- 23.97 ---27.12 ------
01/19/09 --- --- 5.40 ---2.95 3.76 ---
07/20/09 --- --- ------24.00 21.65 ---
01/26/10 --- --- 8.51 8.97 11.07 8.78 ---
01/04/11 --- --- 4.82 ---6.06 6.16 ---
07/05/11 --- --- 24.60 ------------
01/10/12 --- --- 8.90 9.20 8.00 8.70 ---
07/09/12 --- --- ------29.10 ------
01/28/13 --- --- 5.40 5.00 2.00 4.70 ---
07/17/13 --- --- 24.70 ---27.70 ------
01/28/14 --- --- 2.80 ---5.00 ------
07/24/14 --- --- 23.20 ---26.10 ------
01/28/15 --- --- 4.30 ---4.40 ------
07/30/15 --- --- ------25.5 ------
01/27/16 --- --- ---6.90 5.30 ------
07/27/16 --- --- ---27.9 26.7 ------
01/25/17 --- --- 13.5 14.0 11.5 ------
Turbidity 10/28/98 --- --- 93.0 99.0 ---------
(NTU)04/07/99 --- --- 4.4 16.0 58.0 20.0 ---
12/08/99 --- --- 13.0 ---50.0 143.0 ---
04/27/00 --- --- 25.0 202.0 148.0 80.0 ---
10/18/00 --- --- 20.0 ---58.0 ------
04/18/01 --- --- 16.1 183.0 23.0 192.0 ---
10/24/01 --- --- 38.0 44.0 78.0 94.0 ---
04/23/02 --- --- 20.0 38.0 34.0 9.3 ---
10/23/02 --- --- 23.0 292.0 75.0 179.0 ---
04/01/03 --- --- 3.0 75.0 16.0 153.0 ---
10/27/03 --- --- 37.0 780.0 2.3 ------
04/27/04 --- --- 18.0 750.0 16.0 11.0 ---
10/26/04 --- --- 73.0 74.0 37.0 79.0 ---
03/15/05 --- --- 24.8 64.3 41.7 274.0 ---
07/13/05 --- --- 141.0 401.0 150.0 546.0 ---
01/19/06 --- --- 62.5 33.2 0.0 242.0 ---
07/12/06 --- --- 16.1 116.0 17.8 71.3 ---
01/17/07 --- --- 1.5 32.8 28.0 121.0 ---
01/15/08 --- --- 177.0 182.0 ---205.0 ---
07/17/08 --- --- 264.0 ---13.3 ------
01/19/09 --- --- 2.9 ---24.7 111.0 ---
07/20/09 --- --- ------25.4 465.0 ---
01/26/10 --- --- 7.1 297.0 65.1 308.0 ---
01/04/11 --- --- 1.5 ---12.9 40.4 ---
07/05/11 --- --- 185.0 ------------
01/10/12 --- --- 13.2 28.7 10.2 53.3 ---
07/09/12 --- --- ------8.1 ------
01/28/13 --- --- 27.9 32.4 21.2 116.0 ---
07/17/13 --- --- 42.6 ---47.6 ------
01/28/14 --- --- 12.8 ---48.1 ------
07/24/14 --- --- 137.0 ---142.0 ------
01/28/15 --- --- 16.8 ---5.2 ------
07/30/15 --- --- ------11.8 ------
01/27/16 --- --- ---9.88 18.6 ------
07/27/16 --- --- ---24.3 49.4 ------
01/25/17 --- --- 12.05 16.15 18.10 ------
East Carolina Regional Landfill
Permit No. 08-03 Page 15 of 16
Joyce Engineering
TABLE 9
Historical Surface Water Constituents/Analytes
Analyte
Sample Collection
Date DL RL SW-1 SW-2 SW-3 SW-4 Blanks
Oxidation Reduction Potential 03/15/05 --- --- 345.0 139.0 160.0 152.0 ---
(mV)07/13/05 --- --- 148.0 22.0 73.0 32.0 ---
01/19/06 --- --- 338.0 107.0 122.0 186.0 ---
07/12/06 --- --- 196.0 203.0 193.0 196.0 ---
01/15/08 --- --- 186.0 163.0 ---218.0 ---
07/17/08 --- --- 160.0 ---79.0 ------
01/19/09 --- --- 360.3 ---196.3 131.0 ---
07/20/09 --- --- ------129.9 234.3 ---
01/26/10 --- --- 322.8 203.4 203.6 205.7 ---
01/04/11 --- --- 211.1 ---288.5 281.2 ---
07/05/11 --- --- 63.8 ------------
01/10/12 --- --- ---------------
07/09/12 --- --- ------108.5 ------
01/28/13 --- --- 141.8 46.2 59.6 136.8 ---
07/17/13 --- --- 323.9 ---69.5 ------
01/28/14 --- --- 16.2 ---167.3 ------
07/24/14 --- --- 122.8 ---38.7 ------
01/28/15 --- --- 119.6 ---106.9 ------
07/30/15 --- --- ------74.2 ------
01/27/16 --- --- ---180.7 195.7 ------
07/27/16 --- --- ---33.9 44.2 ------
01/25/17 --- --- 246.3 185.1 175.0 ------
Dissolved Oxygen 03/15/05 --- --- 6.9 6.9 6.1 7.4 ---
(mg/L)07/13/05 --- --- 5.0 7.5 8.1 5.8 ---
01/19/06 --- --- 5.1 5.9 5.2 6.3 ---
01/17/07 --- --- 5.4 5.4 4.7 6.2 ---
01/15/08 --- --- 11.3 6.0 ---13.5 ---
07/17/08 --- --- 8.0 ---5.8 ------
01/19/09 --- --- 10.0 ---13.1 12.7 ---
07/20/09 --- --- ------6.4 7.1 ---
01/26/10 --- --- 8.74 10.77 9.52 10.49 ---
01/04/11 --- --- 8.08 ---10.95 10.59 ---
07/05/11 --- --- 3.16 ------------
01/10/12 --- --- ---------------
07/09/12 --- --- ------6.7 ------
01/28/13 --- --- 7.4 10.2 11.9 9.5 ---
07/17/13 --- --- 3.2 ---69.5 ------
01/28/14 --- --- 6.4 ---8.0 ------
07/24/14 --- --- 2.7 ---0.3 ------
01/28/15 --- --- 12.4 ---8.8 ------
07/30/15 --- --- ------7.04 ------
01/27/16 --- --- ---6.48 12.24 ------
07/27/16 --- --- ---3.49 1.81 ------
01/25/17 --- --- 10.86 5.36 8.75 ------
Notes:
DL = Method Detection Limit.
RL = Reporting Limit = PQL prior to 2007 and SWSL starting January 2007.
PQL = Practical Quantitation Limit.
SWSL = NC-DENR Solid Waste Section Limit.
NC 2B = Surface Water Standard established in 15A NCAC 2B, Revised June 2016*
ND = Not detected above the DL.
J = Estimated concentration below the RL.
B = Blank qualified data.
dry = Insufficient water flow for sampling.
--- = No data.
All inorganic and organic compunds are reported in µg/L
µg/L = micrograms per liter
S.U. = Standard Units.
NTU = Nephelometric Turbidity Units.
µS/cm= microsiemens per centimeter.
mV = Millivolts.
Bold = Concentrations above the NC 2B Standards.
Blanks = field, trip and/or method blanks.
All data prior to 2012 taken from previous reports by Golder Associates NC, Inc.
(d) dissolved metal standard
(h) hardness dependent dissolved metal standard. Assume < 25 mg/L in-stream hardness.
*2B Calc. = NC 2B Standard calculated based on Water Hardness data for adjacent date.
NC 2B Standard for SW-2 Copper results on January 25, 2017, calculated from a total water hardness value of 237 mg/L.
East Carolina Regional Landfill
Permit No. 08-03 Page 16 of 16
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Inorganic Compounds
Total Antimony 13-Jul-05 --- 30 ND ND
20-Jan-06 ---30 ND ND
12-Jul-06 ---30 ND ND
18-Jan-07 0.58 6.00 5.08 ND
10-Jul-07 0.68 6.00 3.07 J ND
15-Jan-08 0.68 6.00 9.02 ND
15-Jul-08 0.68 6.00 4.20 J ND
20-Jan-09 0.68 6.00 4.21 J ND
21-Jul-09 0.680 6.00 4.05 J ND
26-Jan-10 0.0730 6.00 5.00 J ND
07-Jul-10 2.20 6.00 12.4 J ND
05-Jan-11 2.20 6.00 20.0 ND
06-Jul-11 2.20 6.00 14.1 J ND
10-Jan-12 --- 6.00 16.0 ND
09-Jul-12 --- 6.00 12.0 ND
29-Jan-13 --- 6.00 31.1 ND
17-Jul-13 --- 6.00 29.7 B 0.39 J
29-Jan-14 0.22 6.00 26.2 ND
24-Jul-14 1.05 6.00 30.3 ND
28-Jan-15 5.26 6.00 24.6 ND
30-Jul-15 1.25 30.0 104 ND
27-Jan-16 1.25 30.0 40.5 ND
27-Jul-16 0.25 6.0 58.2 ND
25-Jan-17 1.25 30.0 60.4 ND
Total Arsenic 07-Apr-99 ---10.0 ND ---
08-Dec-99 ---10.0 10.0 ---
27-Apr-00 ---10.0 10.0 ---
15-Mar-05 ---10.0 21.0 ND
13-Jul-05 --- 10.0 34.0 ND
20-Jan-06 ---10.0 24.0 ND
12-Jul-06 ---10.0 18.4 ND
18-Jan-07 2 10.0 ND ND
10-Jul-07 2 10.0 ND ND
15-Jan-08 2 10.0 21.8 ND
15-Jul-08 2.8 10.0 26.2 ND
20-Jan-09 2.8 10.0 5.7 B 3.6 J
21-Jul-09 2.80 10.0 43.4 ND
26-Jan-10 3.90 10.0 38.6 ---
07-Jul-10 2.80 10.0 92.6 ND
05-Jan-11 2.80 10.0 72.7 ND
06-Jul-11 2.80 10.0 146 ND
10-Jan-12 --- 10.0 107 ND
09-Jul-12 --- 10.0 109 ND
29-Jan-13 --- 10.0 192 ND
17-Jul-13 --- 10.0 175 ND
29-Jan-14 0.78 10.0 126 ND
24-Jul-14 1.13 10.0 222 ND
28-Jan-15 5.66 10.0 132 ND
30-Jul-15 3.73 50.0 393 ND
27-Jan-16 3.73 50.0 218 ND
27-Jul-16 0.75 10.0 325 ND
25-Jan-17 3.73 50.0 238 ND
East Carolina Regional Landfill
Permit No. 08-03 Page 1 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Total Barium 07-Apr-99 ---500 ND ---
08-Dec-99 ---500 ND ---
27-Apr-00 ---500 ND ---
15-Mar-05 ---500 630 ND
13-Jul-05 --- 500 510 ND
20-Jan-06 ---500 883 ND
12-Jul-06 ---500 678 ND
18-Jan-07 0.2 100 624 ND
10-Jul-07 0.2 100 547 ND
15-Jan-08 0.2 100 645 0.3 J
15-Jul-08 1 100 303 ND
20-Jan-09 1 100 347 ND
21-Jul-09 4.20 100 100 ND
26-Jan-10 0.250 100 273 ND
07-Jul-10 1.00 100 392 ND
05-Jan-11 1.00 100 426 ND
06-Jul-11 1.00 100 496 ND
10-Jan-12 --- 100 374 0.24 J
09-Jul-12 --- 100 449 0.75 J
29-Jan-13 --- 100 394 ND
17-Jul-13 --- 100 391 ND
29-Jan-14 0.25 100 309 ND
24-Jul-14 0.10 100 571 0.32 J
28-Jan-15 0.48 100 328 ---
30-Jul-15 1.49 100 224 0.45 J
27-Jan-16 1.49 100 267 0.42 J
27-Jul-16 0.30 100 349 0.31 J
25-Jan-17 1.49 100 357 0.30 J
Total Beryllium 10-Jan-12 --- 1.00 0.10 J ND
09-Jul-12 --- 1.00 0.60 J ND
29-Jan-13 --- 1.00 ND ND
17-Jul-13 --- 1.00 ND ND
29-Jan-14 0.11 1.00 ND ND
24-Jul-14 0.05 1.00 0.20 J ND
28-Jan-15 0.24 1.00 ND ND
30-Jul-15 1.88 20.00 ND ND
27-Jan-16 0.47 1.00 ND ND
27-Jul-16 0.09 1.00 0.14 J ND
25-Jan-17 0.47 1.00 ND ND
East Carolina Regional Landfill
Permit No. 08-03 Page 2 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Total Cadmium 13-Jul-05 --- 1.00 ND ND
20-Jan-06 ---1.00 ND ND
12-Jul-06 ---1.00 ND ND
18-Jan-07 0.5 1.00 ND ND
10-Jul-07 0.5 1.00 ND ND
15-Jan-08 0.5 1.00 ND ND
15-Jul-08 0.36 1.00 ND ND
20-Jan-09 0.36 1.00 ND ND
21-Jul-09 0.0870 1.00 0.126 J ND
26-Jan-10 0.130 1.00 0.347 B 0.226 J
07-Jul-10 0.360 1.00 ND ND
05-Jan-11 0.360 1.00 ND ND
06-Jul-11 0.360 1.00 ND ND
10-Jan-12 --- 1.00 ND ND
09-Jul-12 --- 1.00 0.34 J ND
29-Jan-13 --- 1.00 0.17 J ND
17-Jul-13 --- 1.00 ND ND
29-Jan-14 0.060 1.00 0.15 J ND
24-Jul-14 0.050 1.00 0.23 J ND
28-Jan-15 0.23 1.00 0.25 J ND
30-Jul-15 0.48 1.00 ND ND
27-Jan-16 0.48 2.50 ND ND
27-Jul-16 0.10 1.00 ND ND
25-Jan-17 0.48 1.00 ND ND
Total Chromium 13-Jul-05 --- 10.0 ND ND
20-Jan-06 ---10.0 ND ND
12-Jul-06 ---10.0 ND ND
18-Jan-07 2 10.0 ND ND
10-Jul-07 2 10.0 ND ND
15-Jan-08 2 10.0 ND ND
15-Jul-08 1 10.0 ND ND
20-Jan-09 1 10.0 ND ND
21-Jul-09 0.710 10.0 57.7 ND
26-Jan-10 1.70 10.0 40.8 ND
07-Jul-10 1.00 10.0 70.5 ND
05-Jan-11 1.00 10.0 59.7 ND
06-Jul-11 1.00 10.0 108 ND
10-Jan-12 --- 10.0 92.7 ND
09-Jul-12 --- 10.0 168.0 ND
29-Jan-13 --- 10.0 121.0 1.38 J
17-Jul-13 --- 50.0 132 ND
29-Jan-14 0.58 10.0 70 ND
24-Jul-14 0.73 10.0 103 ND
28-Jan-15 3.64 10.0 97.8 ND
30-Jul-15 2.16 50.0 164 ND
27-Jan-16 2.16 50.0 205 ND
27-Jul-16 0.43 10.0 384 ND
25-Jan-17 2.16 50.0 337 ND
East Carolina Regional Landfill
Permit No. 08-03 Page 3 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Total Cobalt 07-Apr-99 ---10.0 10.0 ---
08-Dec-99 ---10.0 60.0 ---
27-Apr-00 ---10.0 10.0 ---
15-Mar-05 ---10.0 43.0 ND
13-Jul-05 --- 10.0 40.0 ND
20-Jan-06 ---10.0 60.0 ND
12-Jul-06 ---10.0 63.5 ND
18-Jan-07 2 10.0 16.1 ND
10-Jul-07 2 10.0 18.3 ND
15-Jan-08 2 10.0 23.0 ND
15-Jul-08 1.1 10.0 17.1 ND
20-Jan-09 1.1 10.0 13.3 1.1 J
21-Jul-09 0.580 10.0 19.9 ND
26-Jan-10 0.410 10.0 14.8 0.468 J
07-Jul-10 1.10 10.0 20.2 ND
05-Jan-11 1.10 10.0 19.8 ND
06-Jul-11 1.10 10.0 24.7 ND
10-Jan-12 --- 10.0 23.0 ND
09-Jul-12 --- 10.0 24.6 ND
29-Jan-13 --- 10.0 21.0 ND
17-Jul-13 --- 20.0 26.5 ND
29-Jan-14 --- 10.0 26.2 ND
24-Jul-14 --- 10.0 15.0 ND
28-Jan-15 1.29 10.0 15.5 ND
30-Jul-15 1.44 10.0 29.1 ND
27-Jan-16 1.44 10.0 26.6 ND
27-Jul-16 0.29 10.0 32.8 ND
25-Jan-17 1.44 10.0 35.3 ND
Total Copper 13-Jul-05 --- 200 ND ND
20-Jan-06 ---200 ND ND
12-Jul-06 ---200 ND ND
18-Jan-07 0.6 10.0 ND ND
10-Jul-07 0.6 10.0 ND ND
15-Jan-08 0.6 10.0 ND ND
15-Jul-08 1.6 10.0 8.20 J ND
20-Jan-09 1.6 10.0 ND ND
21-Jul-09 0.810 10.0 ND 1.25 J
26-Jan-10 1.90 10.0 ND ND
07-Jul-10 1.60 10.0 ND ND
05-Jan-11 1.60 10.0 2.57 J ND
06-Jul-11 1.60 10.0 ND ND
10-Jan-12 --- 10.0 11.6 0.66 J
09-Jul-12 --- 10.0 53.7 ND
29-Jan-13 --- 10.0 17.3 0.26 J
17-Jul-13 --- 10.0 16.4 ND
29-Jan-14 0.38 10.0 12.6 ND
24-Jul-14 0.22 10.0 18.0 ND
28-Jan-15 1.10 10.0 64.6 ND
30-Jul-15 2.04 10.0 17.3 1.31 J
27-Jan-16 2.04 50.0 63.8 2.44 J
27-Jul-16 0.41 10.0 4.2 J 8.47 J
25-Jan-17 2.04 10.0 9.21 J 0.59 J
East Carolina Regional Landfill
Permit No. 08-03 Page 4 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Total Lead 13-Jul-05 --- 10.0 ND ND
20-Jan-06 ---10.0 ND ND
15-Mar-06 ---10.0 ND ND
12-Jul-06 ---10.0 13.0 ND
26-Oct-06 ---10.0 ------
18-Jan-07 2 10.0 ND ND
10-Jul-07 2 10.0 ND ND
15-Jan-08 2 10.0 ND ND
15-Jul-08 1.9 10.0 2.3 J ND
20-Jan-09 1.9 10.0 ND 2.0 J
21-Jul-09 1.60 10.0 5.28 B 2.16 J
26-Jan-10 1.10 10.0 5.68 B 1.84 J
07-Jul-10 1.90 10.0 3.84 J ND
05-Jan-11 1.90 10.0 ND ND
06-Jul-11 1.90 10.0 ND ND
10-Jan-12 --- 10.0 2.75 B 0.94 J
09-Jul-12 --- 10.0 45.2 ND
29-Jan-13 --- 10.0 3.38 J ND
17-Jul-13 --- 10.0 0.51 J ND
29-Jan-14 0.050 10.0 3.66 J ND
24-Jul-14 0.050 10.0 5.53 J ND
28-Jan-15 0.24 10.0 4.15 J ND
30-Jul-15 0.42 10.0 1.7 J ND
27-Jan-16 0.42 10.0 3.00 J ND
27-Jul-16 0.08 10.0 3.20 J ND
25-Jan-17 0.42 10.0 8.09 J ND
Total Mercury 29-Jan-14 0.064 0.20 0.119 J ND
24-Jul-14 0.064 0.20 0.203 ND
28-Jan-15 0.064 0.200 0.084 J ND
30-Jul-15 0.070 0.200 0.122 J ND
27-Jan-16 0.070 0.200 ND ND
27-Jul-16 0.880 1.330 ND ---
25-Jan-17 0.132 0.200 ND ---
East Carolina Regional Landfill
Permit No. 08-03 Page 5 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Total Nickel 07-Apr-99 ---50.0 ND ---
08-Dec-99 ---50.0 30.0 ---
27-Apr-00 ---50.0 50.0 ---
15-Mar-05 ---50.0 85.0 ND
13-Jul-05 --- 50.0 86.0 ND
20-Jan-06 ---50.0 74.0 ND
12-Jul-06 ---50.0 ND ND
18-Jan-07 2 50.0 72.2 ND
10-Jul-07 2 50.0 75.8 ND
15-Jan-08 2 50.0 91.6 ND
15-Jul-08 1.8 50.0 55.6 ND
20-Jan-09 1.8 50.0 41.1 J ND
21-Jul-09 0.650 50.0 84.2 ND
26-Jan-10 1.60 50.0 61.1 ND
07-Jul-10 1.80 50.0 89.0 ND
05-Jan-11 1.80 50.0 86.3 ND
06-Jul-11 1.80 50.0 95.0 ND
10-Jan-12 --- 50.0 92.0 ND
09-Jul-12 --- 50.0 114.0 ND
29-Jan-13 --- 50.0 95.0 ND
17-Jul-13 --- 100 108 ND
29-Jan-14 0.41 50.0 59.0 ND
24-Jul-14 0.22 50.0 60.7 ND
28-Jan-15 1.08 50.0 81.0 ND
30-Jul-15 2.42 50.0 130 ND
27-Jan-16 2.42 50.0 123 ND
27-Jul-16 0.48 50.0 146 ND
25-Jan-17 2.42 50.0 153 ND
Total Selenium 13-Jul-05 --- 20.0 ND ND
20-Jan-06 ---20.0 ND ND
12-Jul-06 ---20.0 ND ND
18-Jan-07 2 10.0 ND ND
10-Jul-07 2 10.0 ND ND
15-Jan-08 2 10.0 3.2 J ND
15-Jul-08 2.7 10.0 ND ND
20-Jan-09 2.7 10.0 ND ND
21-Jul-09 3.40 10.0 5.82 B 3.58 J
26-Jan-10 4.40 10.0 ND ND
07-Jul-10 2.70 10.0 ND ND
05-Jan-11 2.70 10.0 ND ND
06-Jul-11 2.70 10.0 ND ND
10-Jan-12 --- 10.0 ND ND
09-Jul-12 --- 10.0 4.32 ND
29-Jan-13 --- 10.0 1.41 J ND
17-Jul-13 --- 10.0 2.74 ND
29-Jan-14 0.77 10.0 3.65 J ND
24-Jul-14 1.01 10.0 ND ND
28-Jan-15 5.06 10.0 ND ND
30-Jul-15 4.27 10.0 ND ND
27-Jan-16 4.27 10.0 5.74 J ND
27-Jul-16 0.85 10.0 ND ND
25-Jan-17 4.27 10.0 6.43 J ND
East Carolina Regional Landfill
Permit No. 08-03 Page 6 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Total Silver 13-Jul-05 --- 10.0 ND ND
20-Jan-06 ---10.0 ND ND
12-Jul-06 ---10.0 ND ND
18-Jan-07 2 10.0 ND ND
10-Jul-07 2 10.0 ND ND
15-Jan-08 2 10.0 ND ND
15-Jul-08 1.9 10.0 ND ND
20-Jan-09 1.9 10.0 ND ND
21-Jul-09 0.960 10.0 1.69 J ND
26-Jan-10 0.480 10.0 2.33 B 1.36 J
07-Jul-10 1.90 10.0 ND ND
05-Jan-11 --- 10.0 ND ND
05-Jan-11 1.90 10.0 ND ND
06-Jul-11 1.90 10.0 ND ND
10-Jan-12 --- 10.0 0.20 J ND
09-Jul-12 --- 10.0 0.47 ND
29-Jan-13 --- 10.0 0.29 J ND
17-Jul-13 --- 10.0 0.37 J ND
29-Jan-14 0.24 10.0 ND ND
24-Jul-14 0.17 10.0 0.29 J ND
28-Jan-15 0.84 10.0 ND ND
30-Jul-15 1.12 10.0 ND ND
27-Jan-16 1.12 10.0 ND ND
27-Jul-16 0.22 10.0 ND ND
25-Jan-17 1.12 10.0 ND ND
Total Thallium 13-Jul-05 --- 10.0 ND ND
20-Jan-06 ---10.0 16.0 ND
15-Mar-06 ---10.0 ND ND
12-Jul-06 ---10.0 22.0 ND
26-Oct-06 ---10.0 ------
18-Jan-07 0.044 5.5 0.046 J ND
10-Jul-07 0.036 5.5 ND ND
15-Jan-08 0.036 5.5 ND ND
15-Jul-08 0.036 5.5 ND ND
20-Jan-09 0.036 5.5 ND ND
21-Jul-09 0.0360 5.5 ND ND
26-Jan-10 0.110 5.5 ND ND
07-Jul-10 1.10 5.5 ND ND
05-Jan-11 --- 5.5 ND ND
05-Jan-11 1.10 5.5 ND ND
06-Jul-11 1.10 5.5 6.28 J ND
10-Jan-12 --- 5.5 ND ND
09-Jul-12 --- 5.5 ND ND
29-Jan-13 --- 5.5 ND ND
17-Jul-13 --- 5.5 ND ND
29-Jan-14 0.06 5.5 ND ND
24-Jul-14 0.09 5.5 ND ND
28-Jan-15 0.46 5.50 ND ND
30-Jul-15 0.28 5.50 ND ND
27-Jan-16 0.28 5.50 ND ND
27-Jul-16 0.06 5.50 ND ND
25-Jan-17 0.28 5.50 ND ND
East Carolina Regional Landfill
Permit No. 08-03 Page 7 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Total Vanadium 13-Jul-05 --- 40.0 ND ND
20-Jan-06 ---40.0 ND ND
12-Jul-06 ---40.0 ND ND
18-Jan-07 1 25.0 24.6 ND
10-Jul-07 1 25.0 39.7 ND
15-Jan-08 1 25.0 55.4 ND
15-Jul-08 1.4 25.0 23.7 J ND
20-Jan-09 1.4 25.0 ND ND
21-Jul-09 0.680 25.0 638 0.803 J
26-Jan-10 0.400 25.0 102 ND
07-Jul-10 1.40 25.0 189 ND
05-Jan-11 1.40 25.0 110 ND
06-Jul-11 1.40 25.0 87.5 ND
10-Jan-12 --- 25.0 127 ND
09-Jul-12 --- 25.0 199 ND
29-Jan-13 --- 125 130 2.68 J
17-Jul-13 --- 25.0 123 ND
29-Jan-14 1.97 25.0 79.8 ND
24-Jul-14 0.93 25.0 88.8 1.41 J
28-Jan-15 4.67 25.0 79.6 1.1 J
30-Jul-15 7.86 125.0 151 ND
27-Jan-16 7.86 125.0 162 ND
27-Jul-16 1.57 25.0 238 ND
25-Jan-17 7.86 125.0 180 ND
Total Zinc 07-Apr-99 ---50.0 50 ---
08-Dec-99 ---50.0 160 ---
27-Apr-00 ---50.0 30 ---
15-Mar-05 ---50.0 120 ND
13-Jul-05 --- 50.0 100 ND
20-Jan-06 ---50.0 63.0 ND
12-Jul-06 ---50.0 99.6 ND
18-Jan-07 1 10.0 22.1 4.8 J
10-Jul-07 1 10.0 37.5 ND
15-Jan-08 1 10.0 15.2 1.3 J
15-Jul-08 3.8 10.0 80.9 5.0 J
20-Jan-09 3.8 10.0 17.7 ND
21-Jul-09 3.40 10.0 21.0 ND
26-Jan-10 1.60 10.0 14.5 ND
07-Jul-10 3.80 10.0 64.2 ND
05-Jan-11 3.80 10.0 34.9 ND
06-Jul-11 3.80 10.0 41.6 ND
10-Jan-12 --- 10.0 62.4 B ND
09-Jul-12 --- 10.0 183.0 0.3 J
29-Jan-13 --- 10.0 39.9 0.57 J
17-Jul-13 --- 10.0 14.2 ND
29-Jan-14 0.87 10.0 40.1 ND
24-Jul-14 0.64 10.0 314 0.71 J
28-Jan-15 3.20 10.0 120 3.15 J
30-Jul-15 6.52 10.0 37.3 ND
27-Jan-16 6.52 50.0 54.9 ND
27-Jul-16 1.30 10.0 181 1.51 J
25-Jan-17 6.52 50.0 470 2.13 J
East Carolina Regional Landfill
Permit No. 08-03 Page 8 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Organic Compounds
Acetone 07-Apr-99 ---100 830 ---
08-Dec-99 ---100 4,300 ---
27-Apr-00 ---100 2,000 ---
15-Mar-05 ---100 28,000 ND
13-Jul-05 --- 100 2000 ND
20-Jan-06 ---11,000 11,200 ND
12-Jul-06 ---100 4,810 ND
18-Jan-07 0.9 100 13,000 ND
10-Jul-07 4.5 100 27 J ND
15-Jan-08 45 100 6,700 ND
15-Jul-08 6.2 100 980 ND
20-Jan-09 75 100 4,900 ND
21-Jul-09 15 100 580 ND
26-Jan-10 30 100 3,300 ND
07-Jul-10 30 100 2,800 ND
05-Jan-11 75 100 3,600 ND
06-Jul-11 120 100 12,000 ND
10-Jan-12 --- 10,000 16,000 D ND
09-Jul-12 --- 5,000 11,000 ND
29-Jan-13 --- 10,000 21,000 ND
17-Jul-13 --- 2,500 5,800 ND
29-Jan-14 6 100 10,000 5.8 J
24-Jul-14 6 100 13,000 ND
28-Jan-15 570 2,000 5,000 ND
30-Jul-15 150 1,000 1,800 ND
27-Jan-16 5 100 160 ND
27-Jul-16 5 100 9,400 ND
25-Jan-17 820 10,000 20,000 ND
Acrylonitrile 29-Jan-14 1 200 1.1 J ND
24-Jul-14 1 200 ND ND
28-Jan-15 0.6 200 ND ND
30-Jul-15 0.9 200 ND ND
27-Jan-16 1.8 200 ND ND
27-Jul-16 1.8 200 ND ND
25-Jan-17 2.5 200 ND ND
East Carolina Regional Landfill
Permit No. 08-03 Page 9 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Benzene 07-Apr-99 ---5.0 ND ---
08-Dec-99 ---5.0 5.0 ---
27-Apr-00 ---5.0 ND ---
15-Mar-05 ---500 ND ND
13-Jul-05 --- 5.0 ND ND
20-Jan-06 ---550 ND ND
12-Jul-06 ---5.0 ND ND
18-Jan-07 0.12 3.0 ND ND
10-Jul-07 0.6 1.0 2.0 J ND
15-Jan-08 6 1.0 ND ND
15-Jul-08 2 1.0 ND ND
20-Jan-09 10 1.0 ND ND
21-Jul-09 2.0 1.0 ND ND
26-Jan-10 1.0 1.0 ND ND
07-Jul-10 4.0 1.0 ND ND
05-Jan-11 10 1.0 ND ND
06-Jul-11 68 1.0 ND ND
10-Jan-12 --- 1.0 2.9 ND
09-Jul-12 --- 1.0 1.0 ND
29-Jan-13 --- 1.0 2.4 ND
17-Jul-13 --- 1.0 0.8 J ND
29-Jan-14 0 1.0 3.5 ND
24-Jul-14 0 1.0 1.9 ND
28-Jan-15 0.2 1.0 2.6 ND
30-Jul-15 0.2 1.0 0.7 J ND
27-Jan-16 0.2 1.0 1.0 J ND
27-Jul-16 0.2 1.0 2.0 ND
25-Jan-17 0.2 1.0 3.7 ND
Carbon Disulfide 17-Jul-13 --- 100 3.3 J ND
29-Jan-14 0.8 100 ND ND
24-Jul-14 0.8 100 ND ND
28-Jan-15 0.8 100 ND ND
30-Jul-15 0.3 100 0.5 J ND
27-Jan-16 0.9 100 5.0 J ND
27-Jul-16 0.6 100 1.2 J ND
25-Jan-17 0.8 100 12.0 J ND
Chlorobenzene 10-Jan-12 ---3.0 0.8 J ND
09-Jul-12 ---3.0 3.0 ND
29-Jan-13 ---3.0 0.8 J ND
17-Jul-13 ---3.0 ND 0.8 J
29-Jan-14 0.2 3.0 0.9 J ND
24-Jul-14 0.2 3.0 0.3 J ND
28-Jan-15 0.2 3.0 0.3 J ND
30-Jul-15 0.5 3.0 ND ND
27-Jan-16 0.4 3.0 ND ND
27-Jul-16 0.4 3.0 0.60 J ND
25-Jan-17 0.5 3.0 0.60 J ND
East Carolina Regional Landfill
Permit No. 08-03 Page 10 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Chloroform 27-Jul-16 0.3 5.0 0.3 J ND
25-Jan-17 0.6 5.0 ND ND
1,2-Dichlorobenzene 29-Jan-13 ---5.0 0.4 J ND
17-Jul-13 ---5.0 ND ND
29-Jan-14 0.3 5.0 0.4 J ND
24-Jul-14 0.3 5.0 ND ND
28-Jan-15 0.3 5.0 ND ND
30-Jul-15 0.2 5.0 ND ND
27-Jan-16 0.5 5.0 ND ND
27-Jul-16 0.5 5.0 ND ND
25-Jan-17 0.5 5.0 ND ND
1,4-Dichlorobenzene 07-Apr-99 ---5.0 ND ---
08-Dec-99 ---5.0 5.0 ---
27-Apr-00 ---5.0 7.0 ---
15-Mar-05 ---500 ND ND
13-Jul-05 --- 5.0 ND ND
20-Jan-06 ---550 ND ND
12-Jul-06 ---5.0 ND ND
18-Jan-07 0.15 3.0 ND ND
10-Jul-07 0.75 1.0 6.6 ND
15-Jan-08 7.5 1.0 ND ND
15-Jul-08 2 1.0 7.2 J ND
20-Jan-09 19 1.0 ND ND
21-Jul-09 3.8 1.0 ND ND
26-Jan-10 2.0 1.0 9.4 J ND
07-Jul-10 7.6 1.0 9.0 J ND
05-Jan-11 19 1.0 ND ND
06-Jul-11 79 1.0 ND ND
10-Jan-12 --- 1.0 11 ND
09-Jul-12 --- 1.0 1.8 ND
29-Jan-13 --- 1.0 9.6 ND
17-Jul-13 --- 1.0 4.4 ND
29-Jan-14 0.3 1.0 12 ND
24-Jul-14 0.3 1.0 5.0 ND
28-Jan-15 0.3 1.0 4.8 ND
30-Jul-15 0.3 1.0 2.7 ND
27-Jan-16 0.2 1.0 3.2 ND
27-Jul-16 0.3 1.0 7.0 ND
25-Jan-17 0.6 1.0 8.6 ND
trans-1,4-Dichloro-2-butene 24-Jul-14 2 100 9.4 J ND
28-Jan-15 2 100 ND ND
30-Jul-15 1 100 ND ND
27-Jan-16 2 100 ND ND
27-Jul-16 2 100 ND ND
25-Jan-17 2 100 ND ND
East Carolina Regional Landfill
Permit No. 08-03 Page 11 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
1,1-Dichloroethane 07-Apr-99 ---5.0 9.0 ---
08-Dec-99 ---5.0 9.0 ---
27-Apr-00 ---5.0 ND ---
15-Mar-05 ---500 ND ND
13-Jul-05 --- 5.0 ND ND
20-Jan-06 ---550 ND ND
12-Jul-06 ---5.0 ND ND
18-Jan-07 0.09 5.0 ND ND
10-Jul-07 0.45 5.0 ND ND
15-Jan-08 4.5 5.0 ND ND
15-Jul-08 3.3 5.0 ND ND
20-Jan-09 16 5.0 ND ND
21-Jul-09 3.3 5.0 ND ND
26-Jan-10 1.0 5.0 ND ND
07-Jul-10 6.6 5.0 ND ND
05-Jan-11 16 5.0 ND ND
06-Jul-11 8.0 5.0 ND ND
10-Jan-12 --- 5.0 ND ND
09-Jul-12 --- 5.0 ND ND
29-Jan-13 --- 5.0 ND ND
17-Jul-13 --- 5.0 ND ND
29-Jan-14 0.2 5.0 ND ND
24-Jul-14 0.2 5.0 ND ND
28-Jan-15 0.2 5.0 ND ND
30-Jul-15 0.2 5.0 ND ND
27-Jan-16 0.4 5.0 ND ND
27-Jul-16 0.4 5.0 ND ND
25-Jan-17 0.4 5.0 ND ND
1,2-Dichloroethane 10-Jan-12 ---1.0 1.3 ND
09-Jul-12 ---1.0 0.6 ND
29-Jan-13 ---1.0 1.7 ND
17-Jul-13 ---1.0 ND ND
29-Jan-14 0.4 1.0 0.9 J ND
24-Jul-14 0.4 1.0 11 ND
28-Jan-15 0.4 1.0 ND ND
30-Jul-15 0.2 1.0 ND ND
27-Jan-16 0.3 1.0 ND ND
27-Jul-16 0.3 1.0 0.3 J ND
25-Jan-17 0.7 1.0 ND ND
cis-1,2-Dichloroethene 10-Jan-12 ---5.0 1.3 J ND
09-Jul-12 ---5.0 0.3 ND
29-Jan-13 ---5.0 1.4 J ND
17-Jul-13 ---5.0 0.5 J ND
29-Jan-14 0.2 5.0 1.8 J ND
24-Jul-14 0.2 5.0 1.4 J ND
28-Jan-15 0.2 5.0 ND ND
30-Jul-15 0.3 5.0 ND ND
27-Jan-16 0.5 5.0 ND ND
27-Jul-16 0.5 5.0 ND ND
25-Jan-17 0.7 5.0 ND ND
East Carolina Regional Landfill
Permit No. 08-03 Page 12 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
1,2-Dichloropropane 29-Jan-14 0.2 1.0 0.8 J ND
24-Jul-14 0.2 1.0 ND ND
30-Jul-15 0.2 1.0 ND ND
27-Jan-16 0.5 1.0 ND ND
27-Jul-16 0.5 1.0 ND ND
25-Jan-17 0.6 1.0 ND ND
Ethylbenzene 07-Apr-99 ---5.0 26.0 ---
08-Dec-99 ---5.0 49.0 ---
27-Apr-00 ---5.0 35.0 ---
15-Mar-05 ---500 ND ND
13-Jul-05 --- 5.0 ND ND
20-Jan-06 ---550 ND ND
12-Jul-06 ---5.0 ND ND
18-Jan-07 0.17 5.0 35.0 J ND
10-Jul-07 0.85 1.0 15.0 ND
15-Jan-08 8.5 1.0 29.0 J ND
15-Jul-08 2 1.0 24.0 ND
20-Jan-09 10 1.0 71.0 ND
21-Jul-09 2.0 1.0 4.0 J ND
26-Jan-10 2.0 1.0 16.0 J ND
07-Jul-10 4.0 1.0 12.0 J ND
05-Jan-11 10 1.0 31.0 J ND
06-Jul-11 62 1.0 ND ND
10-Jan-12 --- 1.0 25.0 ND
09-Jul-12 --- 1.0 4.1 ND
29-Jan-13 --- 1.0 31 ND
17-Jul-13 --- 1.0 6.4 ND
29-Jan-14 0.2 1.0 38 ND
24-Jul-14 0.2 1.0 17 ND
28-Jan-15 0.2 1.0 17 ND
30-Jul-15 0.2 1.0 4.4 ND
27-Jan-16 0.3 1.0 8.00 ND
27-Jul-16 0.2 1.0 18.0 ND
25-Jan-17 0.4 1.0 19.0 ND
East Carolina Regional Landfill
Permit No. 08-03 Page 13 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Methyl Butyl Ketone (2-Hexanone)13-Jul-05 --- 50 ND ND
20-Jan-06 ---5500 ND ND
12-Jul-06 ---50 ND ND
18-Jan-07 0.24 50 17.0 J ND
10-Jul-07 1.2 50 ND ND
15-Jan-08 12 50 ND ND
15-Jul-08 6 50 ND ND
20-Jan-09 34 50 ND ND
21-Jul-09 6.9 50 ND ND
26-Jan-10 14 50 ND ND
07-Jul-10 14 50 ND ND
05-Jan-11 34 50 ND ND
06-Jul-11 88 50 ND ND
10-Jan-12 --- 50 27.0 J ND
09-Jul-12 --- 50 21.0 ND
29-Jan-13 --- 50 41 J ND
17-Jul-13 --- 50 8.5 J ND
29-Jan-14 0.6 50 41 J ND
24-Jul-14 0.6 50 15 J ND
28-Jan-15 0.6 50 13 J ND
30-Jul-15 0.4 50 6.6 J ND
27-Jan-16 0.9 50 12.0 J ND
27-Jul-16 0.9 50 16.0 J ND
25-Jan-17 0.9 50 68.0 ND
Methylene chloride 07-Apr-99 ---10 68.0 ---
08-Dec-99 ---10 21.0 ---
27-Apr-00 ---10 ND ---
15-Mar-05 ---1000 ND ND
13-Jul-05 --- 10 ND ND
20-Jan-06 ---1100 ND ND
12-Jul-06 ---10 ND ND
18-Jan-07 0.088 5.5 ND ND
10-Jul-07 0.44 1.0 ND ND
15-Jan-08 4.4 1.0 ND ND
15-Jul-08 2.4 1.0 ND ND
20-Jan-09 26 1.0 30.0 J ND
21-Jul-09 5.3 1.0 ND ND
26-Jan-10 1.4 1.0 ND ND
07-Jul-10 11 1.0 ND ND
05-Jan-11 26 1.0 ND ND
06-Jul-11 14 1.0 ND ND
10-Jan-12 --- 1.0 1.4 B 0.8 J
09-Jul-12 --- 1.0 0.2 ND
29-Jan-13 --- 1.0 0.2 J ND
17-Jul-13 --- 1.0 ND ND
29-Jan-14 0.2 1.0 ND ND
24-Jul-14 0.6 1.0 9.6 ND
28-Jan-15 0.6 1.0 ND ND
30-Jul-15 0.3 1.0 ND ND
27-Jan-16 0.5 1.0 ND ND
27-Jul-16 0.5 1.0 ND ND
25-Jan-17 0.5 1.0 ND 2.1
East Carolina Regional Landfill
Permit No. 08-03 Page 14 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Methyl Ethyl Ketone (2-Butanone)07-Apr-99 ---100 660 ---
08-Dec-99 ---100 12,000 ---
27-Apr-00 ---100 4,400 ---
15-Mar-05 ---100 34,000 ND
13-Jul-05 --- 100 1800 ND
20-Jan-06 ---11000 16,600 ND
12-Jul-06 ---100 7,870 ND
18-Jan-07 0.56 100 7,300 ND
10-Jul-07 2.8 100 ND ND
15-Jan-08 28 100 7,800 ND
15-Jul-08 4.4 100 960 ND
20-Jan-09 50 100 6,500 ND
21-Jul-09 10 100 660 ND
26-Jan-10 20 100 3,800 ND
07-Jul-10 20 100 3,800 ND
05-Jan-11 50 100 3,900 ND
06-Jul-11 130 100 12,000 ND
10-Jan-12 --- 20,000 26,000 ND
09-Jul-12 --- 5,000 8,100 ND
29-Jan-13 --- 20,000 47,000 ND
17-Jul-13 --- 100 3,800 ND
29-Jan-14 0.8 100 14,000 ND
24-Jul-14 0.8 100 15,000 ND
28-Jan-15 85 5,000 5,000 ND
30-Jul-15 45 5,000 1,200 J ND
27-Jan-16 1 100 160 ND
27-Jul-16 1 100 8,100 ND
25-Jan-17 320 10,000 16,000 ND
East Carolina Regional Landfill
Permit No. 08-03 Page 15 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
4-Methyl-2-pentanone (MIBK)07-Apr-99 ---100 ND ---
08-Dec-99 ---100 ND ---
27-Apr-00 ---100 110 ---
15-Mar-05 ---10000 ND ND
13-Jul-05 --- 100 ND ND
20-Jan-06 ---11000 ND ND
12-Jul-06 ---100 ND ND
18-Jan-07 0.36 100 95 J ND
10-Jul-07 1.8 100 7.4 J ND
15-Jan-08 18 100 ND ND
15-Jul-08 5.6 100 ND ND
20-Jan-09 55 100 110 J ND
21-Jul-09 11 100 27.0 J ND
26-Jan-10 22 100 180 ND
07-Jul-10 22 100 42.0 J ND
05-Jan-11 55 100 66.0 J ND
06-Jul-11 110 100 160 J ND
10-Jan-12 --- 100 220 ND
09-Jul-12 --- 100 140 ND
29-Jan-13 --- 500 680 ND
17-Jul-13 --- 100 98 ND
29-Jan-14 1.4 100 190 ND
24-Jul-14 1.4 100 85 J ND
28-Jan-15 1.4 100 95 J ND
30-Jul-15 1.0 100 31 J ND
27-Jan-16 1.7 100 140 ND
27-Jul-16 1.7 100 90 J ND
25-Jan-17 86.0 200 390 ND
Styrene 29-Jan-13 --- 1.0 2.4 ND
17-Jul-13 --- 1.0 ND ND
29-Jan-14 0.2 1.0 7.1 ND
24-Jul-14 0.2 1.0 2.4 ND
28-Jan-15 0.2 1.0 1.7 ND
30-Jul-15 0.2 1.0 2.6 ND
27-Jan-16 0.4 1.0 ND ND
27-Jul-16 0.4 1.0 3.1 ND
25-Jan-17 0.5 1.0 1.4 ND
East Carolina Regional Landfill
Permit No. 08-03 Page 16 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Toluene 07-Apr-99 ---5.0 100 ---
08-Dec-99 ---5.0 150 ---
27-Apr-00 ---5.0 120 ---
15-Mar-05 ---500 ND ND
13-Jul-05 --- 5.0 ND ND
20-Jan-06 ---550 ND ND
12-Jul-06 ---5.0 255 ND
18-Jan-07 0.15 5.0 36.0 J ND
10-Jul-07 0.75 1.0 9.0 ND
15-Jan-08 7.5 1.0 35.0 J ND
15-Jul-08 2 1.0 23.0 ND
20-Jan-09 14 1.0 120 ND
21-Jul-09 2.7 1.0 ND 0.44 J
26-Jan-10 1.1 1.0 24.0 ND
07-Jul-10 5.4 1.0 14.0 J ND
05-Jan-11 14 1.0 26.0 J ND
06-Jul-11 85 1.0 ND ND
10-Jan-12 --- 1.0 33.0 ND
09-Jul-12 --- 1.0 7.1 ND
29-Jan-13 --- 1.0 33 ND
17-Jul-13 --- 1.0 8.7 ND
29-Jan-14 0.2 1.0 45 ND
24-Jul-14 0.2 1.0 35 ND
28-Jan-15 0.2 1.0 100 ND
30-Jul-15 0.2 1.0 4.1 ND
27-Jan-16 0.3 1.0 12.0 ND
27-Jul-16 0.3 1.0 23.0 ND
25-Jan-17 0.3 1.0 24.0 ND
Trichloroethene 29-Jan-13 --- 1.0 0.2 J ND
17-Jul-13 --- 1.0 ND 0.4 J
29-Jan-14 0.4 1.0 ND ND
24-Jul-14 0.4 1.0 ND ND
28-Jan-15 0.4 1.0 ND ND
30-Jul-15 0.4 1.0 ND ND
27-Jan-16 0.4 1.0 ND ND
27-Jul-16 0.4 1.0 ND ND
25-Jan-17 0.3 1.0 ND ND
1,1,2-Trichloroethane 10-Jan-12 ---1.0 2.0 ND
09-Jul-12 ---1.0 ND ND
29-Jan-13 ---1.0 ND ND
17-Jul-13 ---1.0 ND ND
29-Jan-14 0.3 1.0 ND ND
24-Jul-14 0.3 1.0 ND ND
28-Jan-15 0.3 1.0 ND ND
30-Jul-15 0.4 1.0 ND ND
27-Jan-16 0.8 1.0 ND ND
27-Jul-16 0.8 1.0 ND ND
25-Jan-17 0.6 1.0 ND ND
East Carolina Regional Landfill
Permit No. 08-03 Page 17 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Vinyl Chloride 29-Jan-13 ---1.0 0.2 J ND
17-Jul-13 ---1.0 ND ND
29-Jan-14 0.3 1.0 ND ND
24-Jul-14 0.3 1.0 ND ND
28-Jan-15 0.3 1.0 ND ND
30-Jul-15 0.4 1.0 ND ND
27-Jan-16 0.7 1.0 ND ND
27-Jul-16 0.7 1.0 ND ND
25-Jan-17 0.6 1.0 ND ND
Xylenes, total 07-Apr-99 ---5.0 30.0 ---
08-Dec-99 ---5.0 62.0 ---
27-Apr-00 ---5.0 56.0 ---
15-Mar-05 ---500 ND ND
13-Jul-05 --- 5.0 ND ND
20-Jan-06 ---550 ND ND
12-Jul-06 ---5.0 ND ND
18-Jan-07 0.14 --- 60.0 J ND
10-Jul-07 1 4.0 22.0 ND
15-Jan-08 10 5.0 42.0 J ND
15-Jul-08 4 5.0 39.0 ND
20-Jan-09 20 5.0 100 ND
21-Jul-09 4.0 5.0 ND ND
26-Jan-10 4.4 5.0 31.0 ND
07-Jul-10 8.0 5.0 29.0 ND
05-Jan-11 20 5.0 39.0 J ND
06-Jul-11 210 5.0 ND ND
10-Jan-12 --- 5.0 51.0 ND
09-Jul-12 --- 5.0 10.0 ND
29-Jan-13 --- 5.0 57.0 ND
17-Jul-13 --- 5.0 16 ND
29-Jan-14 0.5 5.0 77 ND
24-Jul-14 0.5 5.0 25 ND
28-Jan-15 0.5 5.0 32 ND
30-Jul-15 0.2 5.0 15 ND
27-Jan-16 0.4 5.0 19.0 ND
27-Jul-16 0.4 5.0 34.0 ND
25-Jan-17 1.4 5.0 42.0 ND
East Carolina Regional Landfill
Permit No. 08-03 Page 18 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Other Parameters
Cyanide, Total 20-Jan-06 ---0.01 ND ND
12-Jul-06 ---0.05 ND ND
18-Jan-07 0.0058 10 ND ND
10-Jul-07 0.01 10 ND ND
15-Jan-08 0.004 10 ND ND
15-Jul-08 0.004 10 ND ND
20-Jan-09 0.004 10 0.0041 J ND
21-Jul-09 0.0047 10 ND ND
26-Jan-10 0.0047 10 0.0054 J ND
07-Jul-10 0.005 0.01 ND ND
05-Jan-11 0.005 0.01 0.0059 J ND
06-Jul-11 0.0039 0.01 ND ND
10-Jan-12 --- 20 ND ND
09-Jul-12 --- 10 ND ND
29-Jan-13 --- 10 14.0 ND
17-Jul-13 --- 10 ND ND
29-Jan-14 10.0 10 10.0 ND
24-Jul-14 10.0 10 ND ND
28-Jan-15 50.0 50.0 ND ND
30-Jul-15 50.0 50.0 ND ND
27-Jan-16 50.0 50.0 ND ND
27-Jul-16 100.0 100.0 ND ---
25-Jan-17 50.0 50.0 ND ---
Oil & Grease (HEM)20-Jan-06 ---25 ND
12-Jul-06 ---219 ND
18-Jan-07 2 --- 5 ND
10-Jul-07 3 --- ND ND
15-Jan-08 3 --- 9.15 ND
15-Jul-08 3 --- 3.00 J ND
20-Jan-09 3 --- 5.11 ND
21-Jul-09 3.00 --- 5.29 ND
26-Jan-10 3.00 --- ND ND
07-Jul-10 3.56 --- ND ND
05-Jan-11 3 --- 7.34 ND
06-Jul-11 3 --- 4.82 J ND
10-Jan-12 --- 5,200 10,000 ND
09-Jul-12 --- 5,700 13,000 ND
29-Jan-13 --- 5,400 6,600 ND
17-Jul-13 --- 5,300 9,800 ND
29-Jan-14 6,600 6,600 7,300 ND
24-Jul-14 5,800 5,800 17,000 ND
28-Jan-15 6,200 6,200 8,100 ND
30-Jul-15 5,800 5,800 14,000 ND
27-Jan-16 5,700 5,700 6,000 ND
27-Jul-16 6,000 6,000 14,000 ---
25-Jan-17 17,000 17,000 38,000 ---
East Carolina Regional Landfill
Permit No. 08-03 Page 19 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Total Phenols as Phenol 15-Mar-05 ---0.05 0.84 ND
20-Jan-06 ---0.2 1 ND
12-Jul-06 ---0.1 1 ND
18-Jan-07 0.01 --- 0.92 ND
10-Jul-07 0.02 --- 0.03 J ND
15-Jan-08 0.03 --- 1.1 ND
15-Jul-08 0.02 --- 0.20 ND
20-Jan-09 0.02 --- 0.53 ND
21-Jul-09 0.02 --- 0.23 ND
26-Jan-10 0.01 --- 0.43 ND
07-Jul-10 0.01 --- 0.56 ND
05-Jan-11 0.02 --- 0.95 ND
06-Jul-11 0.12 --- 2.60 ND
10-Jan-12 --- 1,000 5,380 ND
09-Jul-12 --- 50.0 1,480 ND
29-Jan-13 --- 100 3,260 ND
17-Jul-13 --- 50.0 448 ND
29-Jan-14 100 100 2,420 ND
24-Jul-14 250 250 4,340 ND
28-Jan-15 250 250 2,190 ND
30-Jul-15 50 50 1,040 ND
27-Jan-16 50 50 188 ND
27-Jul-16 250 250 2,860 ---
25-Jan-17 250 250 4,080 ---
Total Kjeldahl Nitrogen as N 15-Mar-05 ---0.05 480 ND
20-Jan-06 ---1 495 ND
12-Jul-06 ---0.05 396 ND
18-Jan-07 4 --- 440 ND
10-Jul-07 22 --- 570 ND
15-Jan-08 22 --- 560 0.088
15-Jul-08 2.2 --- 320 ND
20-Jan-09 3 --- 340 ND
21-Jul-09 9.0 --- 550 ND
26-Jan-10 9.0 --- 460 ND
07-Jul-10 9 --- 720 ND
05-Jan-11 14 --- 720 ND
06-Jul-11 16 --- 1,000 B 250 J
10-Jan-12 --- 40,000 593,000 ND
09-Jul-12 --- 40.0 519,000 ND
29-Jan-13 --- 80.0 840,000 ND
17-Jul-13 --- 50.0 884,000 ND
29-Jan-14 8 8000 466,000 ND
24-Jul-14 80,000 80,000 700,000 ND
28-Jan-15 80,000 80,000 714,000 ---
30-Jul-15 20,000 20,000 1,160,000 ---
27-Jan-16 80,000 80,000 1,160,000 ND
27-Jul-16 200,000 200,000 2,220,000 ---
25-Jan-17 40,000 40,000 1,870,000 ---
East Carolina Regional Landfill
Permit No. 08-03 Page 20 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Nitrate as N 13-Jul-05 --- 0.1 ND ND
05-Jan-11 0.025 10 0.072 J ND
06-Jul-11 0.025 10 ND ND
10-Jan-12 --- 50.0 280 ND
09-Jul-12 --- 50.0 ND ND
29-Jan-13 --- 500.0 ND ND
17-Jul-13 --- 100 120 ND
29-Jan-14 50 50 1500 ND
24-Jul-14 50 50 ND ND
28-Jan-15 100 100 ND ND
30-Jul-15 250 250 ND ND
27-Jan-16 50 50 ND ND
27-Jul-16 50 50 ND ---
25-Jan-17 50 50 ND ---
Nitrite as N 29-Jan-14 50 50 680 ND
24-Jul-14 50 50 340 ND
28-Jan-15 100 100 ND ND
30-Jul-15 250 250 ND ND
27-Jan-16 50 50 ND ND
27-Jul-16 50 50 ND ---
25-Jan-17 2500 2500 ND ---
Nitrate/Nitrite as N 29-Jan-14 50 50 2200 ND
24-Jul-14 50 50 350 ND
28-Jan-15 100 100 ND ND
30-Jul-15 250 250 ND ND
27-Jan-16 50 50 ND ND
27-Jul-16 50 50 ND ---
25-Jan-17 50 50 ND ---
Sulfate 13-Jul-05 --- 2 ND ND
20-Jan-06 --- 2 ND ND
12-Jul-06 --- 2 6.23 ND
18-Jan-07 0.6 --- 29.3 2.25 J
10-Jul-07 0.6 --- 34.0 1.1
15-Jan-08 0.06 250 5.6 J ND
15-Jul-08 0.05 250 3.8 J ND
20-Jan-09 0.05 250 2.5 J ND
21-Jul-09 0.078 250 3.1 J ND
26-Jan-10 0.18 250 1.6 B 1.1 J
07-Jul-10 0.12 250 5.4 J ND
05-Jan-11 0.12 250 10.0 J ND
06-Jul-11 0.02 250 4.00 B 1.90 J
10-Jan-12 --- 5,000 2,900 J ND
09-Jul-12 --- 5,000 ND ND
29-Jan-13 --- 10,000 ND ND
17-Jul-13 --- 10,000 ND ND
29-Jan-14 5,000 5,000 9100.0 ND
24-Jul-14 5,000 5,000 ND ND
28-Jan-15 1,000 1,000 ND ND
30-Jul-15 5,000 5,000 9200.0 ND
27-Jan-16 5,000 5,000 ND ND
27-Jul-16 5,000 5,000 ND ---
25-Jan-17 51 5,000 8200.0 ---
East Carolina Regional Landfill
Permit No. 08-03 Page 21 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Biochemical Oxygen Demand 15-Mar-05 ---2 1,300 ND
13-Jul-05 --- 2 220 J ND
20-Jan-06 ---2 1,910 ND
12-Jul-06 ---2 1,770 ND
18-Jan-07 2 --- 593 ND
10-Jul-07 2 --- 97.0 ND
15-Jan-08 2 --- 620 ND
15-Jul-08 2 --- 110 ND
20-Jan-09 2 --- 630 ND
21-Jul-09 2.0 --- 130 ND
26-Jan-10 2.0 --- 130 ND
07-Jul-10 2 --- 420 ND
05-Jan-11 2 --- 460 ND
06-Jul-11 2 --- 890 ND
10-Jan-12 --- 45,000 1,380,000 ND
09-Jul-12 --- 32.0 560 ND
29-Jan-13 --- 65.0 1,820 ND
17-Jul-13 --- 25,000 513,000 130
29-Jan-14 2.0 32,000 1,470,000 D ND
24-Jul-14 2.0 55,000 2,950,000 D ND
28-Jan-15 2.0 19,000 375,000 D 120 J
30-Jul-15 2.0 34,000 481,000 D ND
27-Jan-16 2.0 42,000 244,000 ND
27-Jul-16 2.0 213,000 1,890,000 D ---
25-Jan-17 2.0 68,000 1,220,000 D ---
Chemical Oxygen Demand 15-Mar-05 ---10 2,500.00 ND
13-Jul-05 --- 10 1,120.00 ND
27-Feb-06 --- 40 1,710.00 ND
12-Jul-06 ---10 2,990.00 ND
18-Jan-07 10 --- 1,810.00 ND
10-Jul-07 10 --- 980.00 ND
15-Jan-08 20 --- 1,600.00 ND
15-Jul-08 41 --- 950.00 ND
20-Jan-09 20 --- 1,300.00 ND
21-Jul-09 6.2 --- 990.00 ND
26-Jan-10 5.6 --- 920.00 ND
07-Jul-10 28 --- 1,700.00 ND
05-Jan-11 14 --- 1,700.00 ND
06-Jul-11 100 --- 2,500.00 ND
10-Jan-12 --- 200,000 4,050,000 ND
09-Jul-12 --- 200 3,050,000 ND
29-Jan-13 --- 200 4,770,000 5830
17-Jul-13 --- 200 2,590,000 ND
29-Jan-14 100 100 3,470,000 ND
24-Jul-14 200000 200,000 7,850,000 ND
28-Jan-15 100 10 2,270,000 ND
30-Jul-15 100000 100,000 2,400,000 ND
27-Jan-16 50 50 2,630,000 ND
27-Jul-16 100000 100,000 5,780,000 ---
25-Jan-17 200 200,000 9,020,000 ---
Chloroform 27-Jul-16 0.3 5 0.30 J ---
East Carolina Regional Landfill
Permit No. 08-03 Page 22 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Total Suspended Solids 15-Mar-05 ---2 140 ND
12-Jul-06 ---2 264 ND
18-Jan-07 1 --- 45.0 ND
10-Jul-07 1 --- 21.0 ND
15-Jan-08 1 --- 26.0 ND
15-Jul-08 1 --- 59.0 ND
20-Jan-09 1 --- 85.0 ND
21-Jul-09 1.0 --- 17.0 ND
26-Jan-10 1.0 --- 23.0 ND
07-Jul-10 1 --- 67.0 ND
05-Jan-11 1 --- 23.0 ND
06-Jul-11 1 --- 36.0 ND
10-Jan-12 --- 10,000 78,000 ND
09-Jul-12 --- 33 780,000 ND
29-Jan-13 --- 5 46,000 ND
17-Jul-13 --- 5,000 20,500 ND
29-Jan-14 5,000 5,000 49,000 ND
24-Jul-14 10,000 10,000 160,000 D ND
28-Jan-15 10,000 10,000 46,000 D ND
30-Jul-15 9,090 9,090 197,000 D ND
27-Jan-16 5,000 5,000 52,500 ND
27-Jul-16 10,000 10,000 117,000 D ---
25-Jan-17 20,000 20,000 230,000 D ---
Phosphorus-Total 15-Mar-05 ---0.03 1.8 ND
13-Jul-05 --- 0.03 2.2 ND
20-Jan-06 ---0.1 2.0 ND
12-Jul-06 ---0.03 1.0 ND
18-Jan-07 0.02 --- 1.7 ND
10-Jul-07 0.02 --- 2.8 ND
15-Jan-08 0.02 --- 2.6 ND
15-Jul-08 0.05 --- 1.2 ND
20-Jan-09 0.05 --- 0.82 ND
21-Jul-09 0.050 --- 0.69 ND
26-Jan-10 0.025 --- 1.7 ND
20-Jan-09 0.017 --- 0.084 J ND
21-Jul-09 0.021 --- ND ND
26-Jan-10 0.021 --- 0.059 B 0.021
07-Jul-10 0.025 --- 0.034 J ND
05-Jan-11 0.025 --- 0.097 J ND
06-Jul-11 0.025 --- 0.041 J ND
10-Jan-12 --- 50 280 ND
09-Jul-12 --- 50 ND ND
29-Jan-13 --- 500 ND ND
17-Jul-13 --- 100 120 ND
29-Jan-14 0.220 0.22 1240 D ND
24-Jul-14 222 222 1900 D ND
28-Jan-15 0.22 0.22 4030 D ND
30-Jul-15 0.22 0.22 3270 D ND
27-Jan-16 222.00 222 2940 D ND
27-Jul-16 0.22 222 6930 D ---
25-Jan-17 0.22 0.22 3820 D ---
East Carolina Regional Landfill
Permit No. 08-03 Page 23 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Field Parameters
pH 07-Apr-99 ------ 6.82 ---
(S.U.) 15-Mar-05 ------ 6.34 ---
13-Jul-05 ------ 7.36 ---
20-Jan-06 ------ 9.48 ---
12-Jul-06 ------ 7.22 ---
18-Jan-07 ------ 6.00 ---
10-Jul-07 ------ 8.31 ---
15-Jan-08 ------ 7.53 ---
15-Jul-08 ------ 7.39 ---
20-Jan-09 ------ 6.97 ---
21-Jul-09 ------ 7.93 ---
26-Jan-10 ------ 7.03 ---
06-Jul-10 ------ 7.36 ---
05-Jan-11 ------ 7.50 ---
06-Jul-11 --- --- 7.42 ---
10-Jan-12 --- --- 7.60 ---
09-Jul-12 --- --- 8.15 ---
29-Jan-13 --- --- 7.67 ---
17-Jul-13 --- --- 7.90 ---
29-Jan-14 ------ 7.84 ---
24-Jul-14 ------ 7.55 ---
28-Jan-15 FIELD FIELD --- ---
30-Jul-15 FIELD FIELD 7.82 ---
27-Jan-16 FIELD FIELD 8.27 ---
27-Jul-16 FIELD FIELD 5.40 ---
25-Jan-17 FIELD FIELD 7.55 ---
Conductivity 07-Apr-99 ------ 2,061 ---
(µS/cm) 15-Mar-05 ------ 6,310 ---
13-Jul-05 ------ 14,500 ---
20-Jan-06 ------ 4,940 ---
12-Jul-06 ------ 7,940 ---
18-Jan-07 ------ 3,400 ---
10-Jul-07 ------ 9,800 ---
15-Jan-08 ------ 13,100 ---
15-Jul-08 ------ 5,700 ---
20-Jan-09 ------ 4,816 ---
21-Jul-09 ------ 10,430 ---
26-Jan-10 ------ 8,672 ---
06-Jul-10 ------ 11,900 ---
05-Jan-11 ------ 11,370 ---
06-Jul-11 --- --- 12,810 ---
10-Jan-12 --- --- 12,470 ---
09-Jul-12 --- --- 13,336 ---
29-Jan-13 --- --- 11,016 ---
17-Jul-13 --- --- 14,908 ---
29-Jan-14 ------ 12,520 ---
24-Jul-14 ------ 11,310 ---
28-Jan-15 FIELD FIELD ------
30-Jul-15 FIELD FIELD 19027 ---
27-Jan-16 FIELD FIELD 55251 ---
27-Jul-16 FIELD FIELD 13384 ---
25-Jan-17 FIELD FIELD 18378 ---
East Carolina Regional Landfill
Permit No. 08-03 Page 24 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Temperature 15-Mar-05 ------ 12.8 ---
(°C)13-Jul-05 ------ 28.82 ---
20-Jan-06 ------ 16.07 ---
12-Jul-06 ------ 30.0 ---
18-Jan-07 ------ 7.0 ---
10-Jul-07 ------ 33.2 ---
15-Jan-08 ------ 9.95 ---
15-Jul-08 ------ 29.93 ---
20-Jan-09 ------ 6.96 ---
21-Jul-09 ------ 31.07 ---
26-Jan-10 ------ 13.84 ---
06-Jul-10 ------ 28.01 ---
05-Jan-11 ------ 13.21 ---
29-Jan-14 ------ 16.20 ---
24-Jul-14 ------ 32.70 ---
28-Jan-15 FIELD FIELD ------
30-Jul-15 FIELD FIELD 38.90 ---
27-Jan-16 FIELD FIELD 8.40 ---
27-Jul-16 FIELD FIELD 33 ---
25-Jan-17 FIELD FIELD 18.8 ---
Turbidity 18-Jan-07 ------ 71.7 ---
(NTU)10-Jul-07 ------ 33.2 ---
15-Jan-08 ------ 800.7 ---
15-Jan-08 ------ 9.95 ---
15-Jul-08 ------ 294 ---
15-Jul-08 ------ 294 ---
20-Jan-09 ------ 212 ---
21-Jul-09 ------ 189 ---
06-Jul-11 ------ 27.02 ---
10-Jan-12 --- --- 15.8 ---
09-Jul-12 --- --- 29.6 ---
29-Jan-13 --- --- 17.4 ---
17-Jul-13 --- --- 37.1 ---
29-Jan-14 --- --- 1000 ---
28-Jan-15 FIELD FIELD ------
30-Jul-15 FIELD FIELD >1000 ---
27-Jan-16 FIELD FIELD >1000 ---
27-Jun-16 FIELD FIELD >1000 ---
25-Jan-17 FIELD FIELD >1000 ---
East Carolina Regional Landfill
Permit No. 08-03 Page 25 of 26
Joyce Engineering
TABLE 10
Historical Leachate Constituents/Analytes
Analyte
Sample Collection
Date DL RL Leachate Blanks
Notes:
DL = Method Detection Limit.
RL = Reporting Limit = PQL prior to 2007 and SWSL starting January 2007.
SWSL = NC-DENR Solid Waste Section Limit.
ND = Not detected above the DL.
J = Estimated concentration below the RL.
B = Blank qualified data.
--- = No data.
Prior to 2012 all "Other Parameters" were reported in mg/L. beginning with the 1/10/12 event they are reported in µg/L
mg/L = milligrams per liter
µg/L = micrograms per liter
S.U. = Standard Units.
NTU = Nephelometric Turbidity Units.
µS/cm= microsiemens per centimeter.
mV = Millivolts.
Blanks = field, trip and/or method blanks.
All data prior to 2012 taken from previous reports by Golder Associates NC, Inc.
R = Anomalous data.
*8260B analysis diluted by a factor of 10x for the July 2011 event.
*6020A analysis for Antimony and Thallium diluted by a factor of 10x for the July 2011 event.
*Acetone & MEK DF 50x; C.O.D. DF 10x for the January 2012 event.
Phosphorous, total DF 1.11x for Jan. & July 2012 events.
East Carolina Regional Landfill
Permit No. 08-03 Page 26 of 26
Joyce Engineering

Appendix B

Groundwater and Surface Water Field Data Logs

DATE:-25LJOYCE_________rJGIr\issRIf\JGGROUNDWATERSAMPLINGLOGProjectName:Republic-EastCarolinaLFProjectNo./TaskNo.:894.1601.12.01WellID:GW-2Sampler(s):H.SeatonlG.EllerWellDiameter:2.00inchesInitialDepthtoWater:1p5feetDepthtoBottom:30.00feetWaterColumnThickness15feetWellLocation:NWcorneroflandfill,accessedfromRepublicanrd.orlandfillaccessroadEquipment:YSI-Pro,GeoControlProCompressor.WaterLevelMeter.OaktonturbidimeterFlowrate:250mi/mmSystemvolume:150mlTimeTemp.Dis.02Cond.p11ORPTurb.P1WCmg/L[Ls.ICmS.U.myntufeetIbLi-osit(IC113(‘-°LtLi-5;IO7LJ.Sc,55.tCS1311.lioa’1G?5tc.-)ç,O’k’?C,1-7.co?9Illtc11g)S9335—Comments(weatherconditions,odor,color,silt,typeofsample,etc.):‘ci5kiZ-JSignature:-Date:2QAIQCSignOff:__________________Date:—.2i-1—
st\IcIr’]sRII\JGProjectName:Republic-EastCarolinaLfWellID:GW-7WellDiameter:2.00inchesDepthtoBottom:18.00feetWellLocation:nexttoleachatetanksEquipment:YSI-pro,GeoControlProCompressor,flowrate:250mI/mmSystemvolume:150mlDATE:_______Signature:iJ4iZ4z4U%2/-ate:GROUNDWATERSAMPLINGLOGProjectNo.ITaskNo.:894.1601.12.01m.sI(s):H.Seaton!G.EllerInitialDepthtoWater:.C).OWaterColumnThickness\WaterLevelMeter.OaktonturhidimeterfeetFTimeTemp.Dis.02Cond.pHORPTurb.DTWCmg/LLs./cmS.U.myutufeetLc-zi-jUm-z3.iI(-5L[94.30(o.icflkL1130t1-tI]5t-c39isH.0t.zoH179r6c‘&(o.3o....ri..5‘-1.I28l1LILf.3(Comments(weatherconditions,odor,color,silt,typeofsample,etc.):Weather:S’3fln(6153r-I)L/j/3oDate:1QA/QCSignOff:-c_z‘-,2-4-21-i-i
DATE:________JOYCESPJGI1\JE8RII\JcGROUNDWATERSAMPLINGLOGProjectName:Republic-EastCarolinaLF-WellID:GW-8WellDiameter:2.00inchesDepthtoBottom:18.00feetWellLocation:nexttomaintenancebuildingEquipment:YSI-pro.GeoControlProCompressorFlowrate:300ml/minSystemvolume:150mlProjectNo.IlaskNo.:X941s01.12.01Sampler(s):H.Seaton!G.EllerInitiaLDepthtoWater:3-00WaterColumnThickness5-Comments(weatherconditions,odor,color,silt,typeofsample,etc.):Wti,er(\(c.J(p01fr\1—ZSt1(/O&35Signature:1C47.k’4Date:WaterLevelMeter.OaktonturbidimeterfeetfeetTimeTemp.Dis.02Cond.pHORPTurb.DTW°Cmg/Li.s./cms.u.myntufeetC)9?5Yj3ç.‘1.OEZ’1Lt5.SLlG.c)-i(),o819t5’i(4iS5C&-tc-I.cqcø3ft5c7&.U.’—{-loCjcc:tZop1g,151BO5i5-5-(ic3t3.—-QA/QCSignOff:%-----Date:
DATE:________LiU1Lr.GROUNDWATERSAMPLINGLOGProjectName:Republic-EastCarolinaLfProjectNo./TaskNo.:894.1601.12.01WellID:GW-9Sampler(s):H.Seaton/G.FilerWellDiameter:2.00inchesInitialDepthtoWater:feetDepthtoBottom:17.00feetWaterColumnThicknessIfeetWellLocation:nexttowetlandnearmaintenancebuildingEquipment:YSI-pro.GeoControlProCompressor.WaterLevelMeter, Oaktonturbidimeterflowrate:175mI/mmSystemvolume:150mlTimeTemp.Dis.02Cond.pHORPTurb.DTWCmg/L.t.s./cmS.U.myntufeetQf’H’7Ljc1L,q,z..5oz.;Ot7Zj3j..3.15510O6ot3t17J213(p,L1551-13-1.5ciIO’5Z3)--j5SIZ31-.c5:çpQ5LJJ1.13(L,13-5t-zq2-z-5OComments(weatherconditions,odor,color,silt,typeofsample,etc.):Weather:YLA15—(S/L4//IYSignature:-.Date:/75QA/QCSignOff:-..Date:
1JLJILJG!CJRI1’4GDATE:_______GROUNDWATERSAMPLINGLOGProjectName:Republic-EastCarolinaLfWellID:GW-l0WellDiameter:2.00inchesDepthtoBottom:20.00feetWellLocation:SWofLFbehindsedbasinEquipment:YSI-pro,GeoControlProflowrate:200mI/mmSystemvolume:150mlTimeTemp.Dis.02Cond.pHORPTurb.DTWCmg/Lji.s.IcmS.U.myntufeet135it,Li695fl-19I33.-15.5O.7OIZ61Z-57)t383Z..t3Yii55oi15t3L!,332J7t3-IZ15J,ô,sgiZ5I5cj.-/9It€.,Q$.8i13w83oI,‘?5i3i15i6o-siiciiu-g—Comments(weatherconditions,odor,color,silt,typeofsample,etc.):Weather:Su,ivi.6fSC1-Z.5-;‘kdDate:/—zc-1—iDate:ProjectNo./TaskNo.:894.1601.12.01Sampler(s):H.Seaton/G.EllerInitialDepthtoWater:WaterColumnThicknessI-Compressor,WaterLevelMeter,OaktonturbidimeterfeetfeetSignature:QAIQCSignOff:
DATE:1-73-ISIt’J8SRII\JGROUNDWATERSAMPLINGLOGProjectName:Republic-EastCarolinaLFProjectNo./TaskNo.:894.1601.12.01WellID:GW-l1RSampler(s):H.SeatonlG.EtlerWellDiameter:2.00inchesInitialDepthtoWater:.O-11feetDepthtoBottom:42.24feetWaterColumn ThicknessI..3feetWellLocation:WestoflandfillbetweenperimeterroadandconstructedwetlandsEquipment:YSI-pro,GeoControlProCompressor,WaterLevelMeter,OaktonturbidimeterFlowrate:mI/mmSystemvolume:150mlTimeTemp.Dis.02Cond.pHORPTurb.DTW°Cmg/L11.5./cmS.U.myntufeetojOZ5.-flL15,35jt/7-LI.I2-’1’5Oqo’))Lj.Iq31c43O.’15qo1Lj‘-iZo2CIoo13.’1L1.z,c)L13.z5..i7(171OQtIcI1cj-1.lqlOS3I.C’—Comments(weatherconditions,odor,color,silt,typeofsample,etc.):Weather:(QjGnZ51.GtA.t4k(iSignature:/c1_Date:/5—/7-QA/QCSignOff:..,.
.Date:
DATE:1Z-5/JLJIm6I\JGIrJ&.8RIrJEGROUNDWATERSAMPLINGLOGProjectName:Republic-EastCarolinaLFProjectNo./TaskNo.: 894.1601.12.01WellID:GW-13Sampler(s):H.Seaton/G.EllerWellDiameter:2.00inchesInitialDepthtoWater:7,feetDepthtoBottom:41.60feetWaterColumnThickness/d.QYfeetWellLocation:WofLFbetweenperimeterroadandconstructedwetlandsEquipment:YSI-pro,GeoControlProCompressor,WaterLevelMeter.OaktonturbidimeterFlowrate:200m1/minSystemvolume:150mlTimeTemp.Dis.02Cond.pHORPTurILDTW°CmgIL.I.t.s./cms.u.myntufeetpei9Ii-L/jcr37(./.3Zi7.’3O.c-5o’13117.3q.i3c)-/.El1./jib,?1IO4317.’-,3.L/bC735L,.L/-.J’c)30.13Q35/53q35q3.3L1.cyT_i5Z-153U.75Or3?17.5373j3.W.ø-1Z‘z‘1Comments(weatherconditions,odor,color,silt,typeofsample,etc.):Weather:6.>C)s-1.3—(4A/%r’,1,1’((37Signature:/Clt{ZL.L4.Date:QAIQCSignOff:___________________Date:
JOYCES1\JGIt’J8SRItIGDATE:GROUNDWATERSAMPLINGLOGProjectName:Republic-EastCarolinaLF-WellID:GW-15tVellDiameter:2.00inchesDepthtoBottom:39.05feetWellLocation:NWofLfbehindcontainerctnrwEquipment:YSI-pro.GeoControlProFlowrate:250mi/mmSystemvolume:150mlProjectNo./TaskNo.:894.1601.12.01Sampler(s):H.Seaton!G.EllerInitialDepthtoWater:33.WaterColumnThickness5.‘15TimeTemp.Dis.02Cond.pHORPTurb.GalCmg/I.JI.s./cms.u.myntuOd’-tV-Ia.S,7.ci;•flLotOU7Ss9c::cA9—s-09tC°ft(4,cyT’4go.3-.i3\LX2.t35ti_i..3s•9SHI95‘]k5cpltclComments(weatherconditions,odor,color,silt,typeofsample,etc.):Weather:6Jvw(O5)]352Vnh5fl5-cCY(kAVOAJflW5flCtn{ZtC.Jan4cfliW{Signature:/C1t(J%QA/QCSignOff:_________________Date:Date:CrcrWaterLevelMeter. Oakton_feetfeet
DATE:j-Z5-)-JOYcE_________8r\JGIr\JESRI[\JGGROUNDWATERSAMPLINGLOGProjectName:Republic-EastCarolinaLFProjectNo./TaskNo.: 894.1601.12.01WellID:GW-16RSampler(s):H.Seaton!G.EllerWellDiameter:2.00inchesInitialDepthtoWater:ifeetDepthtoBottom:27.20feetWaterColumnThicknessI5•.5feetWellLocation:NEcornerofLFaloneperimeterroadEquipment:YSI-pro,GeoControlProCompressor,WaterLevelMeter, OaktonturbidimeterFlowrate:250m1/minSystem volume:150mlTimeTemp.Dis.02Cond.pHORPTurb.P1WCmgJLJI.S./CmS.U.myntufeeti—I.31.5‘-i..,c’5i.i-L5fl.I,1O1SLI4LL•.-L5cc1.-i.i_liC)553.H5355CC)S•-9?3c1\nfl-3jL53s3’-t337Ljç5u1ciit15(3‘c55-.I-t5S.1b1Ot--Comments(weatherconditions,?dor,color,silt,typeofsample,etc.):Weather:‘.-‘‘-io()‘50’n‘1-Sc.y’t&‘‘/ffSignature:Date:QAIQCSignOff:________________________Date:&_,z.i---
JOYCE&fJGIt’JS8RIt\JGDATE:________GROUNDWATERSAMPLINGLOGProjectName:Republic-EastCarolinaLFWel
l
ID:GW-17_
__
__
__
_
_
_
_WellDiameter:2.00inchesDepthtoBottom:44.30feetWellLocation:NofLfalongperimeterroadEquipment:YSI-pro,GeoControlProCompressor,WaterLevelMeter,OaktonturbidimeterFlowrate:175ml/minSystemvolume:150m1TimeTemp.Dis.02Cond.p11ORPTurb.DTWCmg/I.$Ls./cmS.U.myntufeett15fl!)5.3(3U3(.cD.’I—i5tij(ifl35(tr-t1ict)-9t.so5.9\‘imo3\93iü5jIl_\.55S&3sS3i1L1LJc-i.Comments(weatherconditions,odor,color,silt,typeofsample,etc.):Weather:C)1—ZS—1ScASignature:Date:2IQAIQCSignOff:}-‘%-—Date:-77—-ProjectNo.!TaskNo.:894.1601.12.01‘“r(c:H.SeatonlG.Eller__
__
_
_
_
__
__
__
_
_
_InitialDepthtoWater:___________feetWaterColumnThickness‘3feet
DATE:H7-5-rEf”1cr’.JssRII’.JcGROUNDWATERSAMPLINGLOGProjectName:Republic-EastCarolinaLfProjectNo./TaskNo.:894.1601.12.01WellID:GW-18Sampler(s):H.Seaton!G.111crWellDiameter:2.00inchesInitialDepthtoWater:5feetDepthtoBottom:29.60feetWaterColumnThickness11.7.-5feetWellLocation:WofLFbetweenperimeterroadandconstructedwetlandsEquipment:YSI-pro,GeoControlProCompressor,WaterLevelMeter.OaktonturbidimeterFlowrate:200mlIminSystemvolume:150mlTimeTemp.Dis.02Cond.pHORPTurb.DTW°CmgILj.t.sJcms.u.myntufeet‘11isl15Io.9c15gel,?t3f)9.qoic9.C7Jf542-3gc)-59blc--zLI-ci3itL3U3C1.c——Comments(weatherconditions,odor,color,silt,typeofsample,etc.):Weather:6’C)Sc44,?i&61(i3Signature:idDate:I-QAJQCSignOff:Date:
DATE:JOYCE_________srqGIr\JssIp.JGGROUNDWATERSAMPLINGLOGProjectName:Republic-EastCarolinaLFProjectNo./TaskNo.:894.1601.12.01WellID:GW-21Sampler(s):H.Seaton!G.EllerWellDiameter:2.00inchesInitialDepthtoWater:—feetDepthtoBottom:29.95feetWaterColumnThicknessifeetWellLocation:Equipment:YSI-pro.OEDMP15.WaterLevelMeter.Oaktonturbidimeterflowrate:200ml/minSystemvolume:150mlTimeTemp.Dis.02Cond.p11ORPTurb.DTW°Cmg/Lj.t.s.IcmS.U.myntufeetVz-’6Lk13.o5.v2flc3It30Lglctd1fl32-\Ici-3’-Icj.Oi’i-j.5Vz.il’Z,3L01.O-k€51b.OComments(weatherconditions,odor,color,silt,typeofsample,etc.):Weather:C\?V15\Le23csSignature:LLL&.4Date:t-7.--5—AQAIQCSignOff:-Date:
7’s8RIr]c9ProjectName:Republic-FastCarolinaLFSurfacePointID:LeachateLocation:leachatetanklncateHnearmethaneflareFieldParameters:TimeofSampling:pH:Temperature:Conductivity:Turbidity:DO:(°C)(EISIcm)(ntu)(mg/L)(mV)—tw’(t,4accJSignature:QA/QCSignOff:S?-L’:1--MDate:jYl]LEACHATESAMPLINGLOGProjectlTaskNo.:_894.1601.1201m.lo..(s):H.Seaton/G.EllerH7-3‘7.5ifi,,)C3,37f%7OCOORP:________________Comments/SampleDescription(weatherconditions,odor,color,silt,etc.):Weather:/).JflY11.A(.‘)(1.onSeQ1L-&LL______Date:__
__
__
__Date:
DATE:/-Z5--lTrmrC7’YITLGROUNDWATERSAMPLINGLOGProjectName:Republic-EastCarolinaProjectNo./TaskNo.:894.1601.12.01WellID:PW-1Sampler(s):H.Seaton/G.EllerWellDiameter:-inchesInitialDepthtoWater:-feetDepthtoBottom:-feetWaterColumnThickness:-feetWellLocation:spigotinsidepumphousebackleftcornerEquipment:YSI-pro.OaktonturbidimeterFlowrate:mi/mmSystemvolume:mlTime Temp.Dis.02Cond.}pH]ORP°C1J..s.Icm_js.u.myntutO5153]cQL5’IComments(weatherconditions,odor,color,silt,typeofsample,etc.):Weather:Jvwjt.U)Ranpumpforfifteenminutesthensampledat:1.2-05FieldBlanktaken@Ii/Signature:LDate:IQAIQCSignOff:Date:22J7)‘
DATE:4/271-1-6-cL&rSURFACEWATERSAMPLINGLOGProjectName:Republic-EastCarolinaLFProject/TaskNo.:00894.1601.12.01SurfacePointID:SW-iSampler(s):H.SeatonlG.EllerLocation:streamalongRepublicanrd.nearLFentranceFieldParameters:TimeofSampling:_______________________pH:-Temperature:135(°C)Conductivity:________________________(pS/cm)Turbidity:7.-.o5(ntu)DO:________________(mg/L)ORP:_____________(mV)Comments/SampleDescription(weatherconditions,odor,color,silt,etc.):___________Weather:5JrwjfpL5On—z5-i’l_
_
__
_
_
_
__
_
_
_
__‘\FI0J/.2ISignature:tZit%..&4._j%‘JDate:z—iQAIQCSignOff:Date:
DATE:(Z5..-sIr\JsRIr\Jc9SURFACEWATERSAMPLINGLOGProjectName:Republic-EastCarolinaLfProject/TaskNo.:894.1601.12.01SurfacePointID:SW-2Sampler(s):H.Seaton/G.FlierLocation:behindleachatetanksandsed.pondintreesfieldParameters:TimeofSampling:1-i13pH:750Temperature:H,0(°C)Conductivity:C17(jiSlcm)Turbidity:I.i(ntu)DO:S?b(mg/L)ORP:I5(mV)Comments/SampleDescription(weatherconditions,odor,color,silt,etc.):__________Weather:toz.5-1—5--I/Signature:—%_4j_-J<Date:..t-5iQAIQCSignOff:_________________Date:
DATE:(.-?5-r7r’SURFACEWATERSAMPLINGLOGProjectName:Republic-EastCarolinaLFProject[faskNo.:894.1601.12.01SurfacePointID:SW-3Sampler(s):H.SeatoniG.EllerLocation:offaccessroadnearwetlandareaFieldParameters:Time ofSampling:_______________________pH:_____________________Temperature:___________________________(°C)Conductivity:zoo(J)Turbidity:i‘,t0(ntu)DO:75(mg/i)ORP:_______________(mV)Comments/SampleDescription(weatherconditions,odor,color,silt,etc.):___________Weather:5u’c-Li(QU.3OnSignature:/LCJ1-&jDate:____________QAIQCSignOff:___________________Date:___________
DATE:HZ-51?‘7)V\/7/E4J1LLWSURFACEWATERSAMPLINGLOGProjectName:Republic-EastCarolinaLFProject/TaskNo.:894.1601.12.01SurfacePointID:SW-4Sampler(s):H.Seaton!G.EllerLocation:returningtoLFfromSW-3,firstright,alongrightsideofroadintreesFieldParameters:TimeofSampling:__
__
_
__
_pH:__
__
_
__
_Temperature:Conductivity:__
__
_
__
_Turbidity:__
__
__
_
__DO:___
_
_ORP:___
__
__
__
__
__
__Comments/SampleDescription(weatherconditions,_
_
_______Weather:buI-cC9miAiu_______
____
____
____
__
.-.(°C)(iSIcm)fntu’)(mgfL)(mV)odor,color,silt,etc.):__________crc)c5re—,cc{sr-\CA\3LV’jCflL_6tL4-t’.*HiSignature:__________________________Date:1251QAIQCSignOff:__________________Date:21

Appendix C

Laboratory Analytical Reports

PACE ANALYTICAL SERVICES, LLC.Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]Republic Services of North Carolina, LLCProject: East Carolina Regional LandfillConover, NC 286131220 Commerce Street, SWMr. Matt EinsmannWe appreciate the opportunity to provide the analytical support for your project. The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Pace Analytical Services, LLC. certifies that the following analytical results meet all requirements of the National Environmental Laboratory Accreditation Conference(NELAC).All test results relate only to the samples analyzed.Laboratory ReportProject #:[none]Prepared For:Attention:March 01, 2017Report Number:AAA0860Approved:This report may not be reproduced, except in full, without written approval from Pace Analytical Services, LLC.Page 1 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017Sample IDLaboratory IDMatrixDate SampledANALYTICAL REPORT FOR SAMPLESDate Received0803-GW2AAA0860-0101/25/17 10:27 01/26/17 09:20Ground Water0803-GW7AAA0860-0201/25/17 13:0201/26/17 09:20Ground Water0803-GW8AAA0860-0301/25/17 08:3501/26/17 09:20Ground Water0803-GW9AAA0860-0401/25/17 08:5401/26/17 09:20Ground Water0803-GW10AAA0860-0501/25/17 13:4501/26/17 09:20Ground Water0803-GW11RAAA0860-0601/25/17 09:1001/26/17 09:20Ground Water0803-GW13AAA0860-0701/25/17 09:3701/26/17 09:20Ground Water0803-GW15AAA0860-0801/25/17 13:5201/26/17 09:20Ground Water0803-GW16RAAA0860-0901/25/17 11:1501/26/17 09:20Ground Water0803-GW17AAA0860-1001/25/17 10:5301/26/17 09:20Ground Water0803-GW18AAA0860-1101/25/17 11:3301/26/17 09:20Ground Water0803-GW21AAA0860-1201/25/17 12:3801/26/17 09:20Ground Water0803-PW1AAA0860-1301/25/17 12:0501/26/17 09:20Ground WaterPage 2 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017East Carolina Semi-Annual Report AAA0860 3/1/2017Report revised per consultant request to reanalyze for cobalt and silver on sample GW-7 and for chromium on GW-17.Case NarrativePage 3 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW2Ground WaterAAA0860-01AAA086001/25/17 10:27Project:East Carolina Regional Landfill01/26/17 09:20Metals, TotalEPA 6020B1.03ug/L1Antimony6.00J7020138EPA 3005A0.257440-36-002/10/17 04:1602/06/17 18:25NDEPA 6020Bug/L1Arsenic10.07020138EPA 3005A0.757440-38-202/10/17 04:1602/06/17 18:25EPA 6020B462ug/L1Barium1007020138EPA 3005A0.307440-39-302/10/17 04:1602/06/17 18:25EPA 6020B1.03ug/L1Beryllium1.007020138EPA 3005A0.097440-41-702/17/17 13:3202/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020138EPA 3005A0.107440-43-902/10/17 04:1602/06/17 18:25EPA 6020B5.98ug/L1Chromium10.0J7020138EPA 3005A0.437440-47-302/10/17 04:1602/06/17 18:25EPA 6020B8.57ug/L1Cobalt10.0J7020138EPA 3005A0.297440-48-402/10/17 04:1602/06/17 18:25EPA 6020B3.61ug/L1Copper10.0J7020138EPA 3005A0.417440-50-802/10/17 04:1602/06/17 18:25EPA 6020B2.02ug/L1Lead10.0J7020138EPA 3005A0.087439-92-102/10/17 04:1602/06/17 18:25EPA 6020B7.01ug/L1Nickel50.0J7020138EPA 3005A0.487440-02-002/10/17 04:1602/06/17 18:25EPA 6020B1.32ug/L1Selenium10.0J7020138EPA 3005A0.857782-49-202/10/17 04:1602/06/17 18:25NDEPA 6020Bug/L1Silver10.07020138EPA 3005A0.227440-22-402/10/17 04:1602/06/17 18:25EPA 6020B0.14ug/L1Thallium5.50J7020138EPA 3005A0.067440-28-002/10/17 04:1602/06/17 18:25EPA 6020B6.69ug/L1Vanadium25.0J7020138EPA 3005A1.577440-62-202/10/17 04:1602/06/17 18:25EPA 6020B13.3ug/L1Zinc10.0B-017020138EPA 3005A1.307440-66-602/10/17 04:1602/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010680EPA 5030B8.267-64-101/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Acrylonitrile2007010680EPA 5030B2.5107-13-101/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Benzene1.07010680EPA 5030B0.271-43-201/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Bromochloromethane3.07010680EPA 5030B0.574-97-501/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Bromodichloromethane1.07010680EPA 5030B0.475-27-401/26/17 15:3401/26/17 12:15Page 4 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW2Ground WaterAAA0860-01AAA086001/25/17 10:27Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromoform3.07010680EPA 5030B0.675-25-201/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Bromomethane107010680EPA 5030B1.074-83-901/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Carbon Disulfide1007010680EPA 5030B0.875-15-001/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Carbon Tetrachloride1.07010680EPA 5030B0.456-23-501/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Chlorobenzene3.07010680EPA 5030B0.5108-90-701/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Chloroethane107010680EPA 5030B0.575-00-301/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Chloroform5.07010680EPA 5030B0.667-66-301/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Chloromethane1.07010680EPA 5030B0.474-87-301/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Dibromochloromethane3.07010680EPA 5030B0.3124-48-101/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010680EPA 5030B0.696-12-801/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L11,2-Dibromoethane1.07010680EPA 5030B0.3106-93-401/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Dibromomethane107010680EPA 5030B0.674-95-301/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010680EPA 5030B0.595-50-101/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010680EPA 5030B0.6106-46-701/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010680EPA 5030B1.6110-57-601/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethane5.07010680EPA 5030B0.475-34-301/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L11,2-Dichloroethane1.07010680EPA 5030B0.7107-06-201/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethene5.07010680EPA 5030B0.775-35-401/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010680EPA 5030B0.7156-59-201/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010680EPA 5030B0.5156-60-501/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L11,2-Dichloropropane1.07010680EPA 5030B0.678-87-501/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010680EPA 5030B0.210061-01-501/26/17 15:3401/26/17 12:15Page 5 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW2Ground WaterAAA0860-01AAA086001/25/17 10:27Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010680EPA 5030B0.310061-02-601/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Ethylbenzene1.07010680EPA 5030B0.4100-41-401/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Iodomethane107010680EPA 5030B3.174-88-401/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010680EPA 5030B0.9591-78-601/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Methylene Chloride1.07010680EPA 5030B0.575-09-201/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010680EPA 5030B3.278-93-301/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010680EPA 5030B0.9108-10-101/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Styrene1.07010680EPA 5030B0.5100-42-501/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010680EPA 5030B0.3630-20-601/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010680EPA 5030B0.579-34-501/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Tetrachloroethene1.07010680EPA 5030B0.8127-18-401/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Toluene1.07010680EPA 5030B0.3108-88-301/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010680EPA 5030B0.471-55-601/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010680EPA 5030B0.679-00-501/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Trichloroethene1.07010680EPA 5030B0.379-01-601/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Trichlorofluoromethane1.07010680EPA 5030B0.575-69-401/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010680EPA 5030B0.596-18-401/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Vinyl Acetate507010680EPA 5030B0.4108-05-401/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Vinyl Chloride1.07010680EPA 5030B0.675-01-401/26/17 15:3401/26/17 12:15NDEPA 8260Bug/L1Xylenes, total5.07010680EPA 5030B1.41330-20-701/26/17 15:3401/26/17 12:15EPA 8260B92 %Surr: Dibromofluoromethane7010680EPA 5030B1868-53-701/26/17 15:3401/26/17 12:1580-120Page 6 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW2Ground WaterAAA0860-01AAA086001/25/17 10:27Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260EPA 8260B100 %Surr: 1,2-Dichloroethane-d47010680EPA 5030B17060-07-001/26/17 15:3401/26/17 12:1578-120EPA 8260B102 %Surr: Toluene-d87010680EPA 5030B2037-26-501/26/17 15:3401/26/17 12:1580-120EPA 8260B101 %Surr: 4-Bromofluorobenzene7010680EPA 5030B460-00-401/26/17 15:3401/26/17 12:1580-120Page 7 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW7Ground WaterAAA0860-02AAA086001/25/17 13:02Project:East Carolina Regional Landfill01/26/17 09:20Metals, TotalEPA 6020B0.45ug/L1Antimony6.00J7020138EPA 3005A0.257440-36-002/10/17 04:2202/06/17 18:25EPA 6020B0.92ug/L1Arsenic10.0J7020138EPA 3005A0.757440-38-202/10/17 04:2202/06/17 18:25EPA 6020B48.4ug/L1Barium100J7020138EPA 3005A0.307440-39-302/10/17 04:2202/06/17 18:25EPA 6020B1.60ug/L1Beryllium1.007020138EPA 3005A0.097440-41-702/17/17 13:3802/06/17 18:25EPA 6020B0.17ug/L1Cadmium1.00J7020138EPA 3005A0.107440-43-902/10/17 04:2202/06/17 18:25EPA 6020B3.31ug/L1Chromium10.0J7020138EPA 3005A0.437440-47-302/10/17 04:2202/06/17 18:25EPA 6020B33.0ug/L1Cobalt10.07020824EPA 3005A0.297440-48-402/28/17 23:0902/28/17 10:50EPA 6020B29.8ug/L1Cobalt10.07020138EPA 3005A0.297440-48-402/10/17 04:2202/06/17 18:25EPA 6020B2.55ug/L1Copper10.0J7020138EPA 3005A0.417440-50-802/10/17 04:2202/06/17 18:25EPA 6020B1.44ug/L1Lead10.0J7020138EPA 3005A0.087439-92-102/10/17 04:2202/06/17 18:25EPA 6020B20.2ug/L1Nickel50.0J7020138EPA 3005A0.487440-02-002/10/17 04:2202/06/17 18:25EPA 6020B4.54ug/L1Selenium10.0J7020138EPA 3005A0.857782-49-202/10/17 04:2202/06/17 18:25EPA 6020B40.9ug/L1Silver10.07020824EPA 3005A0.227440-22-402/28/17 23:0902/28/17 10:50EPA 6020B52.9ug/L1Silver10.07020138EPA 3005A0.227440-22-402/10/17 04:2202/06/17 18:25EPA 6020B0.08ug/L1Thallium5.50J7020138EPA 3005A0.067440-28-002/10/17 04:2202/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020138EPA 3005A1.577440-62-202/10/17 04:2202/06/17 18:25EPA 6020B11.4ug/L1Zinc10.0B-017020138EPA 3005A1.307440-66-602/10/17 04:2202/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010680EPA 5030B8.267-64-101/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Acrylonitrile2007010680EPA 5030B2.5107-13-101/26/17 15:5901/26/17 12:15Page 8 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW7Ground WaterAAA0860-02AAA086001/25/17 13:02Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Benzene1.07010680EPA 5030B0.271-43-201/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Bromochloromethane3.07010680EPA 5030B0.574-97-501/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Bromodichloromethane1.07010680EPA 5030B0.475-27-401/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Bromoform3.07010680EPA 5030B0.675-25-201/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Bromomethane107010680EPA 5030B1.074-83-901/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Carbon Disulfide1007010680EPA 5030B0.875-15-001/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Carbon Tetrachloride1.07010680EPA 5030B0.456-23-501/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Chlorobenzene3.07010680EPA 5030B0.5108-90-701/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Chloroethane107010680EPA 5030B0.575-00-301/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Chloroform5.07010680EPA 5030B0.667-66-301/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Chloromethane1.07010680EPA 5030B0.474-87-301/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Dibromochloromethane3.07010680EPA 5030B0.3124-48-101/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010680EPA 5030B0.696-12-801/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L11,2-Dibromoethane1.07010680EPA 5030B0.3106-93-401/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Dibromomethane107010680EPA 5030B0.674-95-301/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010680EPA 5030B0.595-50-101/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010680EPA 5030B0.6106-46-701/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010680EPA 5030B1.6110-57-601/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethane5.07010680EPA 5030B0.475-34-301/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L11,2-Dichloroethane1.07010680EPA 5030B0.7107-06-201/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethene5.07010680EPA 5030B0.775-35-401/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010680EPA 5030B0.7156-59-201/26/17 15:5901/26/17 12:15Page 9 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW7Ground WaterAAA0860-02AAA086001/25/17 13:02Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010680EPA 5030B0.5156-60-501/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L11,2-Dichloropropane1.07010680EPA 5030B0.678-87-501/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010680EPA 5030B0.210061-01-501/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010680EPA 5030B0.310061-02-601/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Ethylbenzene1.07010680EPA 5030B0.4100-41-401/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Iodomethane107010680EPA 5030B3.174-88-401/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010680EPA 5030B0.9591-78-601/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Methylene Chloride1.07010680EPA 5030B0.575-09-201/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010680EPA 5030B3.278-93-301/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010680EPA 5030B0.9108-10-101/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Styrene1.07010680EPA 5030B0.5100-42-501/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010680EPA 5030B0.3630-20-601/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010680EPA 5030B0.579-34-501/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Tetrachloroethene1.07010680EPA 5030B0.8127-18-401/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Toluene1.07010680EPA 5030B0.3108-88-301/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010680EPA 5030B0.471-55-601/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010680EPA 5030B0.679-00-501/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Trichloroethene1.07010680EPA 5030B0.379-01-601/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Trichlorofluoromethane1.07010680EPA 5030B0.575-69-401/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010680EPA 5030B0.596-18-401/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Vinyl Acetate507010680EPA 5030B0.4108-05-401/26/17 15:5901/26/17 12:15Page 10 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW7Ground WaterAAA0860-02AAA086001/25/17 13:02Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Vinyl Chloride1.07010680EPA 5030B0.675-01-401/26/17 15:5901/26/17 12:15NDEPA 8260Bug/L1Xylenes, total5.07010680EPA 5030B1.41330-20-701/26/17 15:5901/26/17 12:15EPA 8260B90 %Surr: Dibromofluoromethane7010680EPA 5030B1868-53-701/26/17 15:5901/26/17 12:1580-120EPA 8260B100 %Surr: 1,2-Dichloroethane-d47010680EPA 5030B17060-07-001/26/17 15:5901/26/17 12:1578-120EPA 8260B103 %Surr: Toluene-d87010680EPA 5030B2037-26-501/26/17 15:5901/26/17 12:1580-120EPA 8260B100 %Surr: 4-Bromofluorobenzene7010680EPA 5030B460-00-401/26/17 15:5901/26/17 12:1580-120Page 11 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW8Ground WaterAAA0860-03AAA086001/25/17 08:35Project:East Carolina Regional Landfill01/26/17 09:20Metals, TotalNDEPA 6020Bug/L1Antimony6.007020138EPA 3005A0.257440-36-002/10/17 04:2702/06/17 18:25NDEPA 6020Bug/L1Arsenic10.07020138EPA 3005A0.757440-38-202/10/17 04:2702/06/17 18:25EPA 6020B113ug/L1Barium1007020138EPA 3005A0.307440-39-302/10/17 04:2702/06/17 18:25EPA 6020B0.64ug/L1Beryllium1.00J7020138EPA 3005A0.097440-41-702/17/17 13:4402/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020138EPA 3005A0.107440-43-902/10/17 04:2702/06/17 18:25EPA 6020B2.92ug/L1Chromium10.0J7020138EPA 3005A0.437440-47-302/10/17 04:2702/06/17 18:25EPA 6020B3.96ug/L1Cobalt10.0J7020138EPA 3005A0.297440-48-402/10/17 04:2702/06/17 18:25NDEPA 6020Bug/L1Copper10.07020138EPA 3005A0.417440-50-802/10/17 04:2702/06/17 18:25EPA 6020B0.26ug/L1Lead10.0J7020138EPA 3005A0.087439-92-102/10/17 04:2702/06/17 18:25EPA 6020B6.30ug/L1Nickel50.0J7020138EPA 3005A0.487440-02-002/10/17 04:2702/06/17 18:25NDEPA 6020Bug/L1Selenium10.07020138EPA 3005A0.857782-49-202/10/17 04:2702/06/17 18:25NDEPA 6020Bug/L1Silver10.07020138EPA 3005A0.227440-22-402/10/17 04:2702/06/17 18:25NDEPA 6020Bug/L1Thallium5.507020138EPA 3005A0.067440-28-002/10/17 04:2702/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020138EPA 3005A1.577440-62-202/10/17 04:2702/06/17 18:25EPA 6020B4.56ug/L1Zinc10.0B-01, J7020138EPA 3005A1.307440-66-602/10/17 04:2702/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010680EPA 5030B8.267-64-101/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Acrylonitrile2007010680EPA 5030B2.5107-13-101/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Benzene1.07010680EPA 5030B0.271-43-201/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Bromochloromethane3.07010680EPA 5030B0.574-97-501/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Bromodichloromethane1.07010680EPA 5030B0.475-27-401/26/17 16:2501/26/17 12:15Page 12 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW8Ground WaterAAA0860-03AAA086001/25/17 08:35Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromoform3.07010680EPA 5030B0.675-25-201/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Bromomethane107010680EPA 5030B1.074-83-901/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Carbon Disulfide1007010680EPA 5030B0.875-15-001/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Carbon Tetrachloride1.07010680EPA 5030B0.456-23-501/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Chlorobenzene3.07010680EPA 5030B0.5108-90-701/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Chloroethane107010680EPA 5030B0.575-00-301/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Chloroform5.07010680EPA 5030B0.667-66-301/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Chloromethane1.07010680EPA 5030B0.474-87-301/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Dibromochloromethane3.07010680EPA 5030B0.3124-48-101/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010680EPA 5030B0.696-12-801/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L11,2-Dibromoethane1.07010680EPA 5030B0.3106-93-401/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Dibromomethane107010680EPA 5030B0.674-95-301/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010680EPA 5030B0.595-50-101/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010680EPA 5030B0.6106-46-701/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010680EPA 5030B1.6110-57-601/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethane5.07010680EPA 5030B0.475-34-301/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L11,2-Dichloroethane1.07010680EPA 5030B0.7107-06-201/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethene5.07010680EPA 5030B0.775-35-401/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010680EPA 5030B0.7156-59-201/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010680EPA 5030B0.5156-60-501/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L11,2-Dichloropropane1.07010680EPA 5030B0.678-87-501/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010680EPA 5030B0.210061-01-501/26/17 16:2501/26/17 12:15Page 13 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW8Ground WaterAAA0860-03AAA086001/25/17 08:35Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010680EPA 5030B0.310061-02-601/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Ethylbenzene1.07010680EPA 5030B0.4100-41-401/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Iodomethane107010680EPA 5030B3.174-88-401/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010680EPA 5030B0.9591-78-601/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Methylene Chloride1.07010680EPA 5030B0.575-09-201/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010680EPA 5030B3.278-93-301/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010680EPA 5030B0.9108-10-101/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Styrene1.07010680EPA 5030B0.5100-42-501/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010680EPA 5030B0.3630-20-601/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010680EPA 5030B0.579-34-501/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Tetrachloroethene1.07010680EPA 5030B0.8127-18-401/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Toluene1.07010680EPA 5030B0.3108-88-301/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010680EPA 5030B0.471-55-601/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010680EPA 5030B0.679-00-501/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Trichloroethene1.07010680EPA 5030B0.379-01-601/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Trichlorofluoromethane1.07010680EPA 5030B0.575-69-401/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010680EPA 5030B0.596-18-401/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Vinyl Acetate507010680EPA 5030B0.4108-05-401/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Vinyl Chloride1.07010680EPA 5030B0.675-01-401/26/17 16:2501/26/17 12:15NDEPA 8260Bug/L1Xylenes, total5.07010680EPA 5030B1.41330-20-701/26/17 16:2501/26/17 12:15EPA 8260B92 %Surr: Dibromofluoromethane7010680EPA 5030B1868-53-701/26/17 16:2501/26/17 12:1580-120Page 14 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW8Ground WaterAAA0860-03AAA086001/25/17 08:35Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260EPA 8260B102 %Surr: 1,2-Dichloroethane-d47010680EPA 5030B17060-07-001/26/17 16:2501/26/17 12:1578-120EPA 8260B100 %Surr: Toluene-d87010680EPA 5030B2037-26-501/26/17 16:2501/26/17 12:1580-120EPA 8260B100 %Surr: 4-Bromofluorobenzene7010680EPA 5030B460-00-401/26/17 16:2501/26/17 12:1580-120Page 15 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW9Ground WaterAAA0860-04AAA086001/25/17 08:54Project:East Carolina Regional Landfill01/26/17 09:20Metals, TotalNDEPA 6020Bug/L1Antimony6.007020138EPA 3005A0.257440-36-002/10/17 04:3302/06/17 18:25NDEPA 6020Bug/L1Arsenic10.07020138EPA 3005A0.757440-38-202/10/17 04:3302/06/17 18:25EPA 6020B163ug/L1Barium1007020138EPA 3005A0.307440-39-302/10/17 04:3302/06/17 18:25EPA 6020B0.95ug/L1Beryllium1.00J7020138EPA 3005A0.097440-41-702/17/17 13:5002/06/17 18:25EPA 6020B0.15ug/L1Cadmium1.00J7020138EPA 3005A0.107440-43-902/10/17 04:3302/06/17 18:25EPA 6020B1.45ug/L1Chromium10.0J7020138EPA 3005A0.437440-47-302/10/17 04:3302/06/17 18:25EPA 6020B2.23ug/L1Cobalt10.0J7020138EPA 3005A0.297440-48-402/10/17 04:3302/06/17 18:25NDEPA 6020Bug/L1Copper10.07020138EPA 3005A0.417440-50-802/10/17 04:3302/06/17 18:25EPA 6020B0.40ug/L1Lead10.0J7020138EPA 3005A0.087439-92-102/10/17 04:3302/06/17 18:25EPA 6020B10.5ug/L1Nickel50.0J7020138EPA 3005A0.487440-02-002/10/17 04:3302/06/17 18:25NDEPA 6020Bug/L1Selenium10.07020138EPA 3005A0.857782-49-202/10/17 04:3302/06/17 18:25EPA 6020B4.98ug/L1Silver10.0J7020138EPA 3005A0.227440-22-402/10/17 04:3302/06/17 18:25NDEPA 6020Bug/L1Thallium5.507020138EPA 3005A0.067440-28-002/10/17 04:3302/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020138EPA 3005A1.577440-62-202/10/17 04:3302/06/17 18:25EPA 6020B12.8ug/L1Zinc10.0B-017020138EPA 3005A1.307440-66-602/10/17 04:3302/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010680EPA 5030B8.267-64-101/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Acrylonitrile2007010680EPA 5030B2.5107-13-101/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Benzene1.07010680EPA 5030B0.271-43-201/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Bromochloromethane3.07010680EPA 5030B0.574-97-501/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Bromodichloromethane1.07010680EPA 5030B0.475-27-401/26/17 16:5001/26/17 12:15Page 16 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW9Ground WaterAAA0860-04AAA086001/25/17 08:54Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromoform3.07010680EPA 5030B0.675-25-201/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Bromomethane107010680EPA 5030B1.074-83-901/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Carbon Disulfide1007010680EPA 5030B0.875-15-001/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Carbon Tetrachloride1.07010680EPA 5030B0.456-23-501/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Chlorobenzene3.07010680EPA 5030B0.5108-90-701/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Chloroethane107010680EPA 5030B0.575-00-301/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Chloroform5.07010680EPA 5030B0.667-66-301/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Chloromethane1.07010680EPA 5030B0.474-87-301/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Dibromochloromethane3.07010680EPA 5030B0.3124-48-101/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010680EPA 5030B0.696-12-801/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L11,2-Dibromoethane1.07010680EPA 5030B0.3106-93-401/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Dibromomethane107010680EPA 5030B0.674-95-301/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010680EPA 5030B0.595-50-101/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010680EPA 5030B0.6106-46-701/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010680EPA 5030B1.6110-57-601/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethane5.07010680EPA 5030B0.475-34-301/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L11,2-Dichloroethane1.07010680EPA 5030B0.7107-06-201/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethene5.07010680EPA 5030B0.775-35-401/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010680EPA 5030B0.7156-59-201/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010680EPA 5030B0.5156-60-501/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L11,2-Dichloropropane1.07010680EPA 5030B0.678-87-501/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010680EPA 5030B0.210061-01-501/26/17 16:5001/26/17 12:15Page 17 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW9Ground WaterAAA0860-04AAA086001/25/17 08:54Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010680EPA 5030B0.310061-02-601/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Ethylbenzene1.07010680EPA 5030B0.4100-41-401/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Iodomethane107010680EPA 5030B3.174-88-401/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010680EPA 5030B0.9591-78-601/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Methylene Chloride1.07010680EPA 5030B0.575-09-201/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010680EPA 5030B3.278-93-301/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010680EPA 5030B0.9108-10-101/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Styrene1.07010680EPA 5030B0.5100-42-501/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010680EPA 5030B0.3630-20-601/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010680EPA 5030B0.579-34-501/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Tetrachloroethene1.07010680EPA 5030B0.8127-18-401/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Toluene1.07010680EPA 5030B0.3108-88-301/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010680EPA 5030B0.471-55-601/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010680EPA 5030B0.679-00-501/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Trichloroethene1.07010680EPA 5030B0.379-01-601/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Trichlorofluoromethane1.07010680EPA 5030B0.575-69-401/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010680EPA 5030B0.596-18-401/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Vinyl Acetate507010680EPA 5030B0.4108-05-401/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Vinyl Chloride1.07010680EPA 5030B0.675-01-401/26/17 16:5001/26/17 12:15NDEPA 8260Bug/L1Xylenes, total5.07010680EPA 5030B1.41330-20-701/26/17 16:5001/26/17 12:15EPA 8260B91 %Surr: Dibromofluoromethane7010680EPA 5030B1868-53-701/26/17 16:5001/26/17 12:1580-120Page 18 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW9Ground WaterAAA0860-04AAA086001/25/17 08:54Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260EPA 8260B100 %Surr: 1,2-Dichloroethane-d47010680EPA 5030B17060-07-001/26/17 16:5001/26/17 12:1578-120EPA 8260B102 %Surr: Toluene-d87010680EPA 5030B2037-26-501/26/17 16:5001/26/17 12:1580-120EPA 8260B104 %Surr: 4-Bromofluorobenzene7010680EPA 5030B460-00-401/26/17 16:5001/26/17 12:1580-120Page 19 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW10Ground WaterAAA0860-05AAA086001/25/17 13:45Project:East Carolina Regional Landfill01/26/17 09:20Metals, TotalNDEPA 6020Bug/L1Antimony6.007020138EPA 3005A0.257440-36-002/10/17 04:3902/06/17 18:25NDEPA 6020Bug/L1Arsenic10.07020138EPA 3005A0.757440-38-202/10/17 04:3902/06/17 18:25EPA 6020B111ug/L1Barium1007020138EPA 3005A0.307440-39-302/10/17 04:3902/06/17 18:25EPA 6020B0.23ug/L1Beryllium1.00J7020138EPA 3005A0.097440-41-702/17/17 13:5502/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020138EPA 3005A0.107440-43-902/10/17 04:3902/06/17 18:25EPA 6020B0.56ug/L1Chromium10.0J7020138EPA 3005A0.437440-47-302/10/17 04:3902/06/17 18:25EPA 6020B4.30ug/L1Cobalt10.0J7020138EPA 3005A0.297440-48-402/10/17 04:3902/06/17 18:25EPA 6020B0.92ug/L1Copper10.0J7020138EPA 3005A0.417440-50-802/10/17 04:3902/06/17 18:25EPA 6020B0.17ug/L1Lead10.0J7020138EPA 3005A0.087439-92-102/10/17 04:3902/06/17 18:25EPA 6020B2.96ug/L1Nickel50.0J7020138EPA 3005A0.487440-02-002/10/17 04:3902/06/17 18:25NDEPA 6020Bug/L1Selenium10.07020138EPA 3005A0.857782-49-202/10/17 04:3902/06/17 18:25EPA 6020B1.01ug/L1Silver10.0J7020138EPA 3005A0.227440-22-402/10/17 04:3902/06/17 18:25NDEPA 6020Bug/L1Thallium5.507020138EPA 3005A0.067440-28-002/10/17 04:3902/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020138EPA 3005A1.577440-62-202/10/17 04:3902/06/17 18:25EPA 6020B6.06ug/L1Zinc10.0B-01, J7020138EPA 3005A1.307440-66-602/10/17 04:3902/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010680EPA 5030B8.267-64-101/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Acrylonitrile2007010680EPA 5030B2.5107-13-101/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Benzene1.07010680EPA 5030B0.271-43-201/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Bromochloromethane3.07010680EPA 5030B0.574-97-501/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Bromodichloromethane1.07010680EPA 5030B0.475-27-401/26/17 17:1501/26/17 12:15Page 20 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW10Ground WaterAAA0860-05AAA086001/25/17 13:45Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromoform3.07010680EPA 5030B0.675-25-201/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Bromomethane107010680EPA 5030B1.074-83-901/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Carbon Disulfide1007010680EPA 5030B0.875-15-001/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Carbon Tetrachloride1.07010680EPA 5030B0.456-23-501/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Chlorobenzene3.07010680EPA 5030B0.5108-90-701/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Chloroethane107010680EPA 5030B0.575-00-301/26/17 17:1501/26/17 12:15EPA 8260B4.5ug/L1Chloroform5.0J7010680EPA 5030B0.667-66-301/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Chloromethane1.07010680EPA 5030B0.474-87-301/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Dibromochloromethane3.07010680EPA 5030B0.3124-48-101/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010680EPA 5030B0.696-12-801/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L11,2-Dibromoethane1.07010680EPA 5030B0.3106-93-401/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Dibromomethane107010680EPA 5030B0.674-95-301/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010680EPA 5030B0.595-50-101/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010680EPA 5030B0.6106-46-701/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010680EPA 5030B1.6110-57-601/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethane5.07010680EPA 5030B0.475-34-301/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L11,2-Dichloroethane1.07010680EPA 5030B0.7107-06-201/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethene5.07010680EPA 5030B0.775-35-401/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010680EPA 5030B0.7156-59-201/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010680EPA 5030B0.5156-60-501/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L11,2-Dichloropropane1.07010680EPA 5030B0.678-87-501/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010680EPA 5030B0.210061-01-501/26/17 17:1501/26/17 12:15Page 21 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW10Ground WaterAAA0860-05AAA086001/25/17 13:45Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010680EPA 5030B0.310061-02-601/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Ethylbenzene1.07010680EPA 5030B0.4100-41-401/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Iodomethane107010680EPA 5030B3.174-88-401/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010680EPA 5030B0.9591-78-601/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Methylene Chloride1.07010680EPA 5030B0.575-09-201/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010680EPA 5030B3.278-93-301/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010680EPA 5030B0.9108-10-101/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Styrene1.07010680EPA 5030B0.5100-42-501/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010680EPA 5030B0.3630-20-601/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010680EPA 5030B0.579-34-501/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Tetrachloroethene1.07010680EPA 5030B0.8127-18-401/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Toluene1.07010680EPA 5030B0.3108-88-301/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010680EPA 5030B0.471-55-601/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010680EPA 5030B0.679-00-501/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Trichloroethene1.07010680EPA 5030B0.379-01-601/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Trichlorofluoromethane1.07010680EPA 5030B0.575-69-401/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010680EPA 5030B0.596-18-401/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Vinyl Acetate507010680EPA 5030B0.4108-05-401/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Vinyl Chloride1.07010680EPA 5030B0.675-01-401/26/17 17:1501/26/17 12:15NDEPA 8260Bug/L1Xylenes, total5.07010680EPA 5030B1.41330-20-701/26/17 17:1501/26/17 12:15EPA 8260B92 %Surr: Dibromofluoromethane7010680EPA 5030B1868-53-701/26/17 17:1501/26/17 12:1580-120Page 22 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW10Ground WaterAAA0860-05AAA086001/25/17 13:45Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260EPA 8260B98 %Surr: 1,2-Dichloroethane-d47010680EPA 5030B17060-07-001/26/17 17:1501/26/17 12:1578-120EPA 8260B102 %Surr: Toluene-d87010680EPA 5030B2037-26-501/26/17 17:1501/26/17 12:1580-120EPA 8260B103 %Surr: 4-Bromofluorobenzene7010680EPA 5030B460-00-401/26/17 17:1501/26/17 12:1580-120Page 23 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW11RGround WaterAAA0860-06AAA086001/25/17 09:10Project:East Carolina Regional Landfill01/26/17 09:20Metals, TotalNDEPA 6020Bug/L1Antimony6.007020138EPA 3005A0.257440-36-002/10/17 04:5602/06/17 18:25NDEPA 6020Bug/L1Arsenic10.07020138EPA 3005A0.757440-38-202/10/17 04:5602/06/17 18:25EPA 6020B30.3ug/L1Barium100J7020138EPA 3005A0.307440-39-302/10/17 04:5602/06/17 18:25EPA 6020B0.12ug/L1Beryllium1.00J7020138EPA 3005A0.097440-41-702/10/17 04:5602/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020138EPA 3005A0.107440-43-902/10/17 04:5602/06/17 18:25EPA 6020B3.98ug/L1Chromium10.0J7020138EPA 3005A0.437440-47-302/10/17 04:5602/06/17 18:25EPA 6020B1.81ug/L1Cobalt10.0J7020138EPA 3005A0.297440-48-402/10/17 04:5602/06/17 18:25EPA 6020B0.68ug/L1Copper10.0J7020138EPA 3005A0.417440-50-802/10/17 04:5602/06/17 18:25EPA 6020B0.25ug/L1Lead10.0J7020138EPA 3005A0.087439-92-102/10/17 04:5602/06/17 18:25EPA 6020B2.10ug/L1Nickel50.0J7020138EPA 3005A0.487440-02-002/10/17 04:5602/06/17 18:25NDEPA 6020Bug/L1Selenium10.07020138EPA 3005A0.857782-49-202/10/17 04:5602/06/17 18:25NDEPA 6020Bug/L1Silver10.07020138EPA 3005A0.227440-22-402/10/17 04:5602/06/17 18:25NDEPA 6020Bug/L1Thallium5.507020138EPA 3005A0.067440-28-002/10/17 04:5602/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020138EPA 3005A1.577440-62-202/10/17 04:5602/06/17 18:25EPA 6020B5.49ug/L1Zinc10.0B-01, J7020138EPA 3005A1.307440-66-602/10/17 04:5602/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010680EPA 5030B8.267-64-101/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Acrylonitrile2007010680EPA 5030B2.5107-13-101/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Benzene1.07010680EPA 5030B0.271-43-201/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Bromochloromethane3.07010680EPA 5030B0.574-97-501/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Bromodichloromethane1.07010680EPA 5030B0.475-27-401/26/17 17:4001/26/17 12:15Page 24 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW11RGround WaterAAA0860-06AAA086001/25/17 09:10Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromoform3.07010680EPA 5030B0.675-25-201/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Bromomethane107010680EPA 5030B1.074-83-901/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Carbon Disulfide1007010680EPA 5030B0.875-15-001/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Carbon Tetrachloride1.07010680EPA 5030B0.456-23-501/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Chlorobenzene3.07010680EPA 5030B0.5108-90-701/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Chloroethane107010680EPA 5030B0.575-00-301/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Chloroform5.07010680EPA 5030B0.667-66-301/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Chloromethane1.07010680EPA 5030B0.474-87-301/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Dibromochloromethane3.07010680EPA 5030B0.3124-48-101/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010680EPA 5030B0.696-12-801/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L11,2-Dibromoethane1.07010680EPA 5030B0.3106-93-401/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Dibromomethane107010680EPA 5030B0.674-95-301/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010680EPA 5030B0.595-50-101/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010680EPA 5030B0.6106-46-701/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010680EPA 5030B1.6110-57-601/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethane5.07010680EPA 5030B0.475-34-301/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L11,2-Dichloroethane1.07010680EPA 5030B0.7107-06-201/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethene5.07010680EPA 5030B0.775-35-401/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010680EPA 5030B0.7156-59-201/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010680EPA 5030B0.5156-60-501/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L11,2-Dichloropropane1.07010680EPA 5030B0.678-87-501/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010680EPA 5030B0.210061-01-501/26/17 17:4001/26/17 12:15Page 25 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW11RGround WaterAAA0860-06AAA086001/25/17 09:10Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010680EPA 5030B0.310061-02-601/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Ethylbenzene1.07010680EPA 5030B0.4100-41-401/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Iodomethane107010680EPA 5030B3.174-88-401/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010680EPA 5030B0.9591-78-601/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Methylene Chloride1.07010680EPA 5030B0.575-09-201/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010680EPA 5030B3.278-93-301/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010680EPA 5030B0.9108-10-101/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Styrene1.07010680EPA 5030B0.5100-42-501/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010680EPA 5030B0.3630-20-601/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010680EPA 5030B0.579-34-501/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Tetrachloroethene1.07010680EPA 5030B0.8127-18-401/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Toluene1.07010680EPA 5030B0.3108-88-301/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010680EPA 5030B0.471-55-601/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010680EPA 5030B0.679-00-501/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Trichloroethene1.07010680EPA 5030B0.379-01-601/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Trichlorofluoromethane1.07010680EPA 5030B0.575-69-401/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010680EPA 5030B0.596-18-401/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Vinyl Acetate507010680EPA 5030B0.4108-05-401/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Vinyl Chloride1.07010680EPA 5030B0.675-01-401/26/17 17:4001/26/17 12:15NDEPA 8260Bug/L1Xylenes, total5.07010680EPA 5030B1.41330-20-701/26/17 17:4001/26/17 12:15EPA 8260B91 %Surr: Dibromofluoromethane7010680EPA 5030B1868-53-701/26/17 17:4001/26/17 12:1580-120Page 26 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW11RGround WaterAAA0860-06AAA086001/25/17 09:10Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260EPA 8260B99 %Surr: 1,2-Dichloroethane-d47010680EPA 5030B17060-07-001/26/17 17:4001/26/17 12:1578-120EPA 8260B101 %Surr: Toluene-d87010680EPA 5030B2037-26-501/26/17 17:4001/26/17 12:1580-120EPA 8260B103 %Surr: 4-Bromofluorobenzene7010680EPA 5030B460-00-401/26/17 17:4001/26/17 12:1580-120Page 27 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW13Ground WaterAAA0860-07AAA086001/25/17 09:37Project:East Carolina Regional Landfill01/26/17 09:20Metals, TotalNDEPA 6020Bug/L1Antimony6.007020138EPA 3005A0.257440-36-002/10/17 05:0202/06/17 18:25NDEPA 6020Bug/L1Arsenic10.07020138EPA 3005A0.757440-38-202/10/17 05:0202/06/17 18:25EPA 6020B380ug/L1Barium1007020138EPA 3005A0.307440-39-302/10/17 05:0202/06/17 18:25EPA 6020B0.64ug/L1Beryllium1.00J7020138EPA 3005A0.097440-41-702/10/17 05:0202/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020138EPA 3005A0.107440-43-902/10/17 05:0202/06/17 18:25EPA 6020B0.97ug/L1Chromium10.0J7020138EPA 3005A0.437440-47-302/10/17 05:0202/06/17 18:25EPA 6020B4.94ug/L1Cobalt10.0J7020138EPA 3005A0.297440-48-402/10/17 05:0202/06/17 18:25EPA 6020B6.15ug/L1Copper10.0J7020138EPA 3005A0.417440-50-802/10/17 05:0202/06/17 18:25EPA 6020B0.49ug/L1Lead10.0J7020138EPA 3005A0.087439-92-102/10/17 05:0202/06/17 18:25EPA 6020B6.40ug/L1Nickel50.0J7020138EPA 3005A0.487440-02-002/10/17 05:0202/06/17 18:25NDEPA 6020Bug/L1Selenium10.07020138EPA 3005A0.857782-49-202/10/17 05:0202/06/17 18:25EPA 6020B5.37ug/L1Silver10.0J7020138EPA 3005A0.227440-22-402/10/17 05:0202/06/17 18:25EPA 6020B0.06ug/L1Thallium5.50J7020138EPA 3005A0.067440-28-002/10/17 05:0202/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020138EPA 3005A1.577440-62-202/10/17 05:0202/06/17 18:25EPA 6020B10.4ug/L1Zinc10.0B-017020138EPA 3005A1.307440-66-602/10/17 05:0202/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010680EPA 5030B8.267-64-101/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Acrylonitrile2007010680EPA 5030B2.5107-13-101/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Benzene1.07010680EPA 5030B0.271-43-201/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Bromochloromethane3.07010680EPA 5030B0.574-97-501/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Bromodichloromethane1.07010680EPA 5030B0.475-27-401/26/17 18:0501/26/17 12:15Page 28 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW13Ground WaterAAA0860-07AAA086001/25/17 09:37Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromoform3.07010680EPA 5030B0.675-25-201/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Bromomethane107010680EPA 5030B1.074-83-901/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Carbon Disulfide1007010680EPA 5030B0.875-15-001/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Carbon Tetrachloride1.07010680EPA 5030B0.456-23-501/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Chlorobenzene3.07010680EPA 5030B0.5108-90-701/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Chloroethane107010680EPA 5030B0.575-00-301/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Chloroform5.07010680EPA 5030B0.667-66-301/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Chloromethane1.07010680EPA 5030B0.474-87-301/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Dibromochloromethane3.07010680EPA 5030B0.3124-48-101/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010680EPA 5030B0.696-12-801/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L11,2-Dibromoethane1.07010680EPA 5030B0.3106-93-401/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Dibromomethane107010680EPA 5030B0.674-95-301/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010680EPA 5030B0.595-50-101/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010680EPA 5030B0.6106-46-701/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010680EPA 5030B1.6110-57-601/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethane5.07010680EPA 5030B0.475-34-301/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L11,2-Dichloroethane1.07010680EPA 5030B0.7107-06-201/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethene5.07010680EPA 5030B0.775-35-401/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010680EPA 5030B0.7156-59-201/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010680EPA 5030B0.5156-60-501/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L11,2-Dichloropropane1.07010680EPA 5030B0.678-87-501/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010680EPA 5030B0.210061-01-501/26/17 18:0501/26/17 12:15Page 29 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW13Ground WaterAAA0860-07AAA086001/25/17 09:37Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010680EPA 5030B0.310061-02-601/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Ethylbenzene1.07010680EPA 5030B0.4100-41-401/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Iodomethane107010680EPA 5030B3.174-88-401/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010680EPA 5030B0.9591-78-601/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Methylene Chloride1.07010680EPA 5030B0.575-09-201/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010680EPA 5030B3.278-93-301/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010680EPA 5030B0.9108-10-101/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Styrene1.07010680EPA 5030B0.5100-42-501/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010680EPA 5030B0.3630-20-601/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010680EPA 5030B0.579-34-501/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Tetrachloroethene1.07010680EPA 5030B0.8127-18-401/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Toluene1.07010680EPA 5030B0.3108-88-301/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010680EPA 5030B0.471-55-601/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010680EPA 5030B0.679-00-501/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Trichloroethene1.07010680EPA 5030B0.379-01-601/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Trichlorofluoromethane1.07010680EPA 5030B0.575-69-401/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010680EPA 5030B0.596-18-401/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Vinyl Acetate507010680EPA 5030B0.4108-05-401/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Vinyl Chloride1.07010680EPA 5030B0.675-01-401/26/17 18:0501/26/17 12:15NDEPA 8260Bug/L1Xylenes, total5.07010680EPA 5030B1.41330-20-701/26/17 18:0501/26/17 12:15EPA 8260B92 %Surr: Dibromofluoromethane7010680EPA 5030B1868-53-701/26/17 18:0501/26/17 12:1580-120Page 30 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW13Ground WaterAAA0860-07AAA086001/25/17 09:37Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260EPA 8260B99 %Surr: 1,2-Dichloroethane-d47010680EPA 5030B17060-07-001/26/17 18:0501/26/17 12:1578-120EPA 8260B102 %Surr: Toluene-d87010680EPA 5030B2037-26-501/26/17 18:0501/26/17 12:1580-120EPA 8260B100 %Surr: 4-Bromofluorobenzene7010680EPA 5030B460-00-401/26/17 18:0501/26/17 12:1580-120Page 31 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW15Ground WaterAAA0860-08AAA086001/25/17 13:52Project:East Carolina Regional Landfill01/26/17 09:20Metals, TotalNDEPA 6020Bug/L1Antimony6.007020138EPA 3005A0.257440-36-002/10/17 05:0702/06/17 18:25NDEPA 6020Bug/L1Arsenic10.07020138EPA 3005A0.757440-38-202/10/17 05:0702/06/17 18:25EPA 6020B166ug/L1Barium1007020138EPA 3005A0.307440-39-302/10/17 05:0702/06/17 18:25EPA 6020B0.48ug/L1Beryllium1.00J7020138EPA 3005A0.097440-41-702/10/17 05:0702/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020138EPA 3005A0.107440-43-902/10/17 05:0702/06/17 18:25EPA 6020B4.32ug/L1Chromium10.0J7020138EPA 3005A0.437440-47-302/10/17 05:0702/06/17 18:25EPA 6020B4.16ug/L1Cobalt10.0J7020138EPA 3005A0.297440-48-402/10/17 05:0702/06/17 18:25EPA 6020B1.00ug/L1Copper10.0J7020138EPA 3005A0.417440-50-802/10/17 05:0702/06/17 18:25EPA 6020B0.80ug/L1Lead10.0J7020138EPA 3005A0.087439-92-102/10/17 05:0702/06/17 18:25EPA 6020B4.59ug/L1Nickel50.0J7020138EPA 3005A0.487440-02-002/10/17 05:0702/06/17 18:25NDEPA 6020Bug/L1Selenium10.07020138EPA 3005A0.857782-49-202/10/17 05:0702/06/17 18:25NDEPA 6020Bug/L1Silver10.07020138EPA 3005A0.227440-22-402/10/17 05:0702/06/17 18:25NDEPA 6020Bug/L1Thallium5.507020138EPA 3005A0.067440-28-002/10/17 05:0702/06/17 18:25EPA 6020B3.56ug/L1Vanadium25.0J7020138EPA 3005A1.577440-62-202/10/17 05:0702/06/17 18:25EPA 6020B7.88ug/L1Zinc10.0B-01, J7020138EPA 3005A1.307440-66-602/10/17 05:0702/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010680EPA 5030B8.267-64-101/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Acrylonitrile2007010680EPA 5030B2.5107-13-101/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Benzene1.07010680EPA 5030B0.271-43-201/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Bromochloromethane3.07010680EPA 5030B0.574-97-501/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Bromodichloromethane1.07010680EPA 5030B0.475-27-401/26/17 18:3001/26/17 12:15Page 32 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW15Ground WaterAAA0860-08AAA086001/25/17 13:52Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromoform3.07010680EPA 5030B0.675-25-201/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Bromomethane107010680EPA 5030B1.074-83-901/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Carbon Disulfide1007010680EPA 5030B0.875-15-001/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Carbon Tetrachloride1.07010680EPA 5030B0.456-23-501/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Chlorobenzene3.07010680EPA 5030B0.5108-90-701/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Chloroethane107010680EPA 5030B0.575-00-301/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Chloroform5.07010680EPA 5030B0.667-66-301/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Chloromethane1.07010680EPA 5030B0.474-87-301/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Dibromochloromethane3.07010680EPA 5030B0.3124-48-101/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010680EPA 5030B0.696-12-801/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L11,2-Dibromoethane1.07010680EPA 5030B0.3106-93-401/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Dibromomethane107010680EPA 5030B0.674-95-301/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010680EPA 5030B0.595-50-101/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010680EPA 5030B0.6106-46-701/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010680EPA 5030B1.6110-57-601/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethane5.07010680EPA 5030B0.475-34-301/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L11,2-Dichloroethane1.07010680EPA 5030B0.7107-06-201/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethene5.07010680EPA 5030B0.775-35-401/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010680EPA 5030B0.7156-59-201/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010680EPA 5030B0.5156-60-501/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L11,2-Dichloropropane1.07010680EPA 5030B0.678-87-501/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010680EPA 5030B0.210061-01-501/26/17 18:3001/26/17 12:15Page 33 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW15Ground WaterAAA0860-08AAA086001/25/17 13:52Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010680EPA 5030B0.310061-02-601/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Ethylbenzene1.07010680EPA 5030B0.4100-41-401/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Iodomethane107010680EPA 5030B3.174-88-401/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010680EPA 5030B0.9591-78-601/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Methylene Chloride1.07010680EPA 5030B0.575-09-201/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010680EPA 5030B3.278-93-301/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010680EPA 5030B0.9108-10-101/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Styrene1.07010680EPA 5030B0.5100-42-501/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010680EPA 5030B0.3630-20-601/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010680EPA 5030B0.579-34-501/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Tetrachloroethene1.07010680EPA 5030B0.8127-18-401/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Toluene1.07010680EPA 5030B0.3108-88-301/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010680EPA 5030B0.471-55-601/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010680EPA 5030B0.679-00-501/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Trichloroethene1.07010680EPA 5030B0.379-01-601/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Trichlorofluoromethane1.07010680EPA 5030B0.575-69-401/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010680EPA 5030B0.596-18-401/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Vinyl Acetate507010680EPA 5030B0.4108-05-401/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Vinyl Chloride1.07010680EPA 5030B0.675-01-401/26/17 18:3001/26/17 12:15NDEPA 8260Bug/L1Xylenes, total5.07010680EPA 5030B1.41330-20-701/26/17 18:3001/26/17 12:15EPA 8260B92 %Surr: Dibromofluoromethane7010680EPA 5030B1868-53-701/26/17 18:3001/26/17 12:1580-120Page 34 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW15Ground WaterAAA0860-08AAA086001/25/17 13:52Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260EPA 8260B100 %Surr: 1,2-Dichloroethane-d47010680EPA 5030B17060-07-001/26/17 18:3001/26/17 12:1578-120EPA 8260B101 %Surr: Toluene-d87010680EPA 5030B2037-26-501/26/17 18:3001/26/17 12:1580-120EPA 8260B102 %Surr: 4-Bromofluorobenzene7010680EPA 5030B460-00-401/26/17 18:3001/26/17 12:1580-120Page 35 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW16RGround WaterAAA0860-09AAA086001/25/17 11:15Project:East Carolina Regional Landfill01/26/17 09:20Metals, TotalNDEPA 6020Bug/L1Antimony6.007020138EPA 3005A0.257440-36-002/10/17 05:1302/06/17 18:25NDEPA 6020Bug/L1Arsenic10.07020138EPA 3005A0.757440-38-202/10/17 05:1302/06/17 18:25EPA 6020B80.4ug/L1Barium100J7020138EPA 3005A0.307440-39-302/10/17 05:1302/06/17 18:25EPA 6020B0.17ug/L1Beryllium1.00J7020138EPA 3005A0.097440-41-702/10/17 05:1302/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020138EPA 3005A0.107440-43-902/10/17 05:1302/06/17 18:25EPA 6020B0.49ug/L1Chromium10.0J7020138EPA 3005A0.437440-47-302/10/17 05:1302/06/17 18:25EPA 6020B3.82ug/L1Cobalt10.0J7020138EPA 3005A0.297440-48-402/10/17 05:1302/06/17 18:25EPA 6020B0.42ug/L1Copper10.0J7020138EPA 3005A0.417440-50-802/10/17 05:1302/06/17 18:25EPA 6020B1.30ug/L1Lead10.0J7020138EPA 3005A0.087439-92-102/10/17 05:1302/06/17 18:25EPA 6020B1.28ug/L1Nickel50.0J7020138EPA 3005A0.487440-02-002/10/17 05:1302/06/17 18:25NDEPA 6020Bug/L1Selenium10.07020138EPA 3005A0.857782-49-202/10/17 05:1302/06/17 18:25EPA 6020B0.38ug/L1Silver10.0J7020138EPA 3005A0.227440-22-402/10/17 05:1302/06/17 18:25NDEPA 6020Bug/L1Thallium5.507020138EPA 3005A0.067440-28-002/10/17 05:1302/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020138EPA 3005A1.577440-62-202/10/17 05:1302/06/17 18:25EPA 6020B4.97ug/L1Zinc10.0B-01, J7020138EPA 3005A1.307440-66-602/10/17 05:1302/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010680EPA 5030B8.267-64-101/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Acrylonitrile2007010680EPA 5030B2.5107-13-101/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Benzene1.07010680EPA 5030B0.271-43-201/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Bromochloromethane3.07010680EPA 5030B0.574-97-501/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Bromodichloromethane1.07010680EPA 5030B0.475-27-401/26/17 18:5601/26/17 12:15Page 36 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW16RGround WaterAAA0860-09AAA086001/25/17 11:15Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromoform3.07010680EPA 5030B0.675-25-201/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Bromomethane107010680EPA 5030B1.074-83-901/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Carbon Disulfide1007010680EPA 5030B0.875-15-001/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Carbon Tetrachloride1.07010680EPA 5030B0.456-23-501/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Chlorobenzene3.07010680EPA 5030B0.5108-90-701/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Chloroethane107010680EPA 5030B0.575-00-301/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Chloroform5.07010680EPA 5030B0.667-66-301/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Chloromethane1.07010680EPA 5030B0.474-87-301/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Dibromochloromethane3.07010680EPA 5030B0.3124-48-101/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010680EPA 5030B0.696-12-801/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L11,2-Dibromoethane1.07010680EPA 5030B0.3106-93-401/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Dibromomethane107010680EPA 5030B0.674-95-301/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010680EPA 5030B0.595-50-101/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010680EPA 5030B0.6106-46-701/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010680EPA 5030B1.6110-57-601/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethane5.07010680EPA 5030B0.475-34-301/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L11,2-Dichloroethane1.07010680EPA 5030B0.7107-06-201/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethene5.07010680EPA 5030B0.775-35-401/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010680EPA 5030B0.7156-59-201/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010680EPA 5030B0.5156-60-501/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L11,2-Dichloropropane1.07010680EPA 5030B0.678-87-501/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010680EPA 5030B0.210061-01-501/26/17 18:5601/26/17 12:15Page 37 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW16RGround WaterAAA0860-09AAA086001/25/17 11:15Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010680EPA 5030B0.310061-02-601/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Ethylbenzene1.07010680EPA 5030B0.4100-41-401/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Iodomethane107010680EPA 5030B3.174-88-401/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010680EPA 5030B0.9591-78-601/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Methylene Chloride1.07010680EPA 5030B0.575-09-201/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010680EPA 5030B3.278-93-301/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010680EPA 5030B0.9108-10-101/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Styrene1.07010680EPA 5030B0.5100-42-501/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010680EPA 5030B0.3630-20-601/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010680EPA 5030B0.579-34-501/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Tetrachloroethene1.07010680EPA 5030B0.8127-18-401/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Toluene1.07010680EPA 5030B0.3108-88-301/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010680EPA 5030B0.471-55-601/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010680EPA 5030B0.679-00-501/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Trichloroethene1.07010680EPA 5030B0.379-01-601/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Trichlorofluoromethane1.07010680EPA 5030B0.575-69-401/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010680EPA 5030B0.596-18-401/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Vinyl Acetate507010680EPA 5030B0.4108-05-401/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Vinyl Chloride1.07010680EPA 5030B0.675-01-401/26/17 18:5601/26/17 12:15NDEPA 8260Bug/L1Xylenes, total5.07010680EPA 5030B1.41330-20-701/26/17 18:5601/26/17 12:15EPA 8260B90 %Surr: Dibromofluoromethane7010680EPA 5030B1868-53-701/26/17 18:5601/26/17 12:1580-120Page 38 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW16RGround WaterAAA0860-09AAA086001/25/17 11:15Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260EPA 8260B98 %Surr: 1,2-Dichloroethane-d47010680EPA 5030B17060-07-001/26/17 18:5601/26/17 12:1578-120EPA 8260B103 %Surr: Toluene-d87010680EPA 5030B2037-26-501/26/17 18:5601/26/17 12:1580-120EPA 8260B102 %Surr: 4-Bromofluorobenzene7010680EPA 5030B460-00-401/26/17 18:5601/26/17 12:1580-120Page 39 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW17Ground WaterAAA0860-10AAA086001/25/17 10:53Project:East Carolina Regional Landfill01/26/17 09:20Metals, TotalNDEPA 6020Bug/L1Antimony6.007020138EPA 3005A0.257440-36-002/10/17 05:1902/06/17 18:25EPA 6020B1.07ug/L1Arsenic10.0J7020138EPA 3005A0.757440-38-202/10/17 05:1902/06/17 18:25EPA 6020B176ug/L1Barium1007020138EPA 3005A0.307440-39-302/10/17 05:1902/06/17 18:25EPA 6020B0.55ug/L1Beryllium1.00J7020138EPA 3005A0.097440-41-702/10/17 05:1902/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020138EPA 3005A0.107440-43-902/10/17 05:1902/06/17 18:25EPA 6020B10.0ug/L1Chromium10.07020824EPA 3005A0.437440-47-302/28/17 23:1402/28/17 10:50EPA 6020B11.1ug/L1Chromium10.07020138EPA 3005A0.437440-47-302/10/17 05:1902/06/17 18:25EPA 6020B3.32ug/L1Cobalt10.0J7020138EPA 3005A0.297440-48-402/10/17 05:1902/06/17 18:25EPA 6020B4.83ug/L1Copper10.0J7020138EPA 3005A0.417440-50-802/10/17 05:1902/06/17 18:25EPA 6020B5.16ug/L1Lead10.0J7020138EPA 3005A0.087439-92-102/10/17 05:1902/06/17 18:25EPA 6020B2.20ug/L1Nickel50.0J7020138EPA 3005A0.487440-02-002/10/17 05:1902/06/17 18:25EPA 6020B2.19ug/L1Selenium10.0J7020138EPA 3005A0.857782-49-202/10/17 05:1902/06/17 18:25EPA 6020B4.84ug/L1Silver10.0J7020138EPA 3005A0.227440-22-402/10/17 05:1902/06/17 18:25EPA 6020B0.09ug/L1Thallium5.50J7020138EPA 3005A0.067440-28-002/10/17 05:1902/06/17 18:25EPA 6020B15.4ug/L1Vanadium25.0J7020138EPA 3005A1.577440-62-202/10/17 05:1902/06/17 18:25EPA 6020B11.8ug/L1Zinc10.0B-017020138EPA 3005A1.307440-66-602/10/17 05:1902/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010680EPA 5030B8.267-64-101/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Acrylonitrile2007010680EPA 5030B2.5107-13-101/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Benzene1.07010680EPA 5030B0.271-43-201/26/17 19:2101/26/17 12:15Page 40 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW17Ground WaterAAA0860-10AAA086001/25/17 10:53Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromochloromethane3.07010680EPA 5030B0.574-97-501/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Bromodichloromethane1.07010680EPA 5030B0.475-27-401/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Bromoform3.07010680EPA 5030B0.675-25-201/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Bromomethane107010680EPA 5030B1.074-83-901/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Carbon Disulfide1007010680EPA 5030B0.875-15-001/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Carbon Tetrachloride1.07010680EPA 5030B0.456-23-501/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Chlorobenzene3.07010680EPA 5030B0.5108-90-701/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Chloroethane107010680EPA 5030B0.575-00-301/26/17 19:2101/26/17 12:15EPA 8260B1.6ug/L1Chloroform5.0J7010680EPA 5030B0.667-66-301/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Chloromethane1.07010680EPA 5030B0.474-87-301/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Dibromochloromethane3.07010680EPA 5030B0.3124-48-101/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010680EPA 5030B0.696-12-801/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L11,2-Dibromoethane1.07010680EPA 5030B0.3106-93-401/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Dibromomethane107010680EPA 5030B0.674-95-301/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010680EPA 5030B0.595-50-101/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010680EPA 5030B0.6106-46-701/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010680EPA 5030B1.6110-57-601/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethane5.07010680EPA 5030B0.475-34-301/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L11,2-Dichloroethane1.07010680EPA 5030B0.7107-06-201/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethene5.07010680EPA 5030B0.775-35-401/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010680EPA 5030B0.7156-59-201/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010680EPA 5030B0.5156-60-501/26/17 19:2101/26/17 12:15Page 41 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW17Ground WaterAAA0860-10AAA086001/25/17 10:53Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichloropropane1.07010680EPA 5030B0.678-87-501/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010680EPA 5030B0.210061-01-501/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010680EPA 5030B0.310061-02-601/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Ethylbenzene1.07010680EPA 5030B0.4100-41-401/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Iodomethane107010680EPA 5030B3.174-88-401/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010680EPA 5030B0.9591-78-601/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Methylene Chloride1.07010680EPA 5030B0.575-09-201/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010680EPA 5030B3.278-93-301/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010680EPA 5030B0.9108-10-101/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Styrene1.07010680EPA 5030B0.5100-42-501/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010680EPA 5030B0.3630-20-601/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010680EPA 5030B0.579-34-501/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Tetrachloroethene1.07010680EPA 5030B0.8127-18-401/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Toluene1.07010680EPA 5030B0.3108-88-301/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010680EPA 5030B0.471-55-601/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010680EPA 5030B0.679-00-501/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Trichloroethene1.07010680EPA 5030B0.379-01-601/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Trichlorofluoromethane1.07010680EPA 5030B0.575-69-401/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010680EPA 5030B0.596-18-401/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Vinyl Acetate507010680EPA 5030B0.4108-05-401/26/17 19:2101/26/17 12:15NDEPA 8260Bug/L1Vinyl Chloride1.07010680EPA 5030B0.675-01-401/26/17 19:2101/26/17 12:15Page 42 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW17Ground WaterAAA0860-10AAA086001/25/17 10:53Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Xylenes, total5.07010680EPA 5030B1.41330-20-701/26/17 19:2101/26/17 12:15EPA 8260B93 %Surr: Dibromofluoromethane7010680EPA 5030B1868-53-701/26/17 19:2101/26/17 12:1580-120EPA 8260B98 %Surr: 1,2-Dichloroethane-d47010680EPA 5030B17060-07-001/26/17 19:2101/26/17 12:1578-120EPA 8260B102 %Surr: Toluene-d87010680EPA 5030B2037-26-501/26/17 19:2101/26/17 12:1580-120EPA 8260B103 %Surr: 4-Bromofluorobenzene7010680EPA 5030B460-00-401/26/17 19:2101/26/17 12:1580-120Page 43 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW18Ground WaterAAA0860-11AAA086001/25/17 11:33Project:East Carolina Regional Landfill01/26/17 09:20Metals, TotalNDEPA 6020Bug/L1Antimony6.007020138EPA 3005A0.257440-36-002/10/17 05:2502/06/17 18:25EPA 6020B1.10ug/L1Arsenic10.0J7020138EPA 3005A0.757440-38-202/10/17 05:2502/06/17 18:25EPA 6020B190ug/L1Barium1007020138EPA 3005A0.307440-39-302/10/17 05:2502/06/17 18:25EPA 6020B0.77ug/L1Beryllium1.00J7020138EPA 3005A0.097440-41-702/10/17 05:2502/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020138EPA 3005A0.107440-43-902/10/17 05:2502/06/17 18:25EPA 6020B1.24ug/L1Chromium10.0J7020138EPA 3005A0.437440-47-302/10/17 05:2502/06/17 18:25EPA 6020B4.15ug/L1Cobalt10.0J7020138EPA 3005A0.297440-48-402/10/17 05:2502/06/17 18:25EPA 6020B0.65ug/L1Copper10.0J7020138EPA 3005A0.417440-50-802/10/17 05:2502/06/17 18:25EPA 6020B2.99ug/L1Lead10.0J7020138EPA 3005A0.087439-92-102/10/17 05:2502/06/17 18:25EPA 6020B4.41ug/L1Nickel50.0J7020138EPA 3005A0.487440-02-002/10/17 05:2502/06/17 18:25EPA 6020B3.77ug/L1Selenium10.0J7020138EPA 3005A0.857782-49-202/10/17 05:2502/06/17 18:25NDEPA 6020Bug/L1Silver10.07020138EPA 3005A0.227440-22-402/10/17 05:2502/06/17 18:25NDEPA 6020Bug/L1Thallium5.507020138EPA 3005A0.067440-28-002/10/17 05:2502/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020138EPA 3005A1.577440-62-202/10/17 05:2502/06/17 18:25EPA 6020B11.2ug/L1Zinc10.0B-017020138EPA 3005A1.307440-66-602/10/17 05:2502/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010680EPA 5030B8.267-64-101/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Acrylonitrile2007010680EPA 5030B2.5107-13-101/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Benzene1.07010680EPA 5030B0.271-43-201/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Bromochloromethane3.07010680EPA 5030B0.574-97-501/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Bromodichloromethane1.07010680EPA 5030B0.475-27-401/26/17 19:4601/26/17 12:15Page 44 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW18Ground WaterAAA0860-11AAA086001/25/17 11:33Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromoform3.07010680EPA 5030B0.675-25-201/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Bromomethane107010680EPA 5030B1.074-83-901/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Carbon Disulfide1007010680EPA 5030B0.875-15-001/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Carbon Tetrachloride1.07010680EPA 5030B0.456-23-501/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Chlorobenzene3.07010680EPA 5030B0.5108-90-701/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Chloroethane107010680EPA 5030B0.575-00-301/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Chloroform5.07010680EPA 5030B0.667-66-301/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Chloromethane1.07010680EPA 5030B0.474-87-301/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Dibromochloromethane3.07010680EPA 5030B0.3124-48-101/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010680EPA 5030B0.696-12-801/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L11,2-Dibromoethane1.07010680EPA 5030B0.3106-93-401/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Dibromomethane107010680EPA 5030B0.674-95-301/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010680EPA 5030B0.595-50-101/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010680EPA 5030B0.6106-46-701/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010680EPA 5030B1.6110-57-601/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethane5.07010680EPA 5030B0.475-34-301/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L11,2-Dichloroethane1.07010680EPA 5030B0.7107-06-201/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethene5.07010680EPA 5030B0.775-35-401/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010680EPA 5030B0.7156-59-201/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010680EPA 5030B0.5156-60-501/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L11,2-Dichloropropane1.07010680EPA 5030B0.678-87-501/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010680EPA 5030B0.210061-01-501/26/17 19:4601/26/17 12:15Page 45 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW18Ground WaterAAA0860-11AAA086001/25/17 11:33Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010680EPA 5030B0.310061-02-601/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Ethylbenzene1.07010680EPA 5030B0.4100-41-401/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Iodomethane107010680EPA 5030B3.174-88-401/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010680EPA 5030B0.9591-78-601/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Methylene Chloride1.07010680EPA 5030B0.575-09-201/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010680EPA 5030B3.278-93-301/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010680EPA 5030B0.9108-10-101/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Styrene1.07010680EPA 5030B0.5100-42-501/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010680EPA 5030B0.3630-20-601/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010680EPA 5030B0.579-34-501/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Tetrachloroethene1.07010680EPA 5030B0.8127-18-401/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Toluene1.07010680EPA 5030B0.3108-88-301/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010680EPA 5030B0.471-55-601/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010680EPA 5030B0.679-00-501/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Trichloroethene1.07010680EPA 5030B0.379-01-601/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Trichlorofluoromethane1.07010680EPA 5030B0.575-69-401/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010680EPA 5030B0.596-18-401/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Vinyl Acetate507010680EPA 5030B0.4108-05-401/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Vinyl Chloride1.07010680EPA 5030B0.675-01-401/26/17 19:4601/26/17 12:15NDEPA 8260Bug/L1Xylenes, total5.07010680EPA 5030B1.41330-20-701/26/17 19:4601/26/17 12:15EPA 8260B92 %Surr: Dibromofluoromethane7010680EPA 5030B1868-53-701/26/17 19:4601/26/17 12:1580-120Page 46 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW18Ground WaterAAA0860-11AAA086001/25/17 11:33Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260EPA 8260B101 %Surr: 1,2-Dichloroethane-d47010680EPA 5030B17060-07-001/26/17 19:4601/26/17 12:1578-120EPA 8260B102 %Surr: Toluene-d87010680EPA 5030B2037-26-501/26/17 19:4601/26/17 12:1580-120EPA 8260B104 %Surr: 4-Bromofluorobenzene7010680EPA 5030B460-00-401/26/17 19:4601/26/17 12:1580-120Page 47 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW21Ground WaterAAA0860-12AAA086001/25/17 12:38Project:East Carolina Regional Landfill01/26/17 09:20Metals, TotalNDEPA 6020Bug/L1Antimony6.007020138EPA 3005A0.257440-36-002/10/17 05:3002/06/17 18:25NDEPA 6020Bug/L1Arsenic10.07020138EPA 3005A0.757440-38-202/10/17 05:3002/06/17 18:25EPA 6020B37.5ug/L1Barium100J7020138EPA 3005A0.307440-39-302/10/17 05:3002/06/17 18:25NDEPA 6020Bug/L1Beryllium1.007020138EPA 3005A0.097440-41-702/10/17 05:3002/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020138EPA 3005A0.107440-43-902/10/17 05:3002/06/17 18:25NDEPA 6020Bug/L1Chromium10.07020138EPA 3005A0.437440-47-302/10/17 05:3002/06/17 18:25EPA 6020B0.30ug/L1Cobalt10.0J7020138EPA 3005A0.297440-48-402/10/17 05:3002/06/17 18:25NDEPA 6020Bug/L1Copper10.07020138EPA 3005A0.417440-50-802/10/17 05:3002/06/17 18:25EPA 6020B1.03ug/L1Lead10.0J7020138EPA 3005A0.087439-92-102/10/17 05:3002/06/17 18:25NDEPA 6020Bug/L1Nickel50.07020138EPA 3005A0.487440-02-002/10/17 05:3002/06/17 18:25NDEPA 6020Bug/L1Selenium10.07020138EPA 3005A0.857782-49-202/10/17 05:3002/06/17 18:25NDEPA 6020Bug/L1Silver10.07020138EPA 3005A0.227440-22-402/10/17 05:3002/06/17 18:25NDEPA 6020Bug/L1Thallium5.507020138EPA 3005A0.067440-28-002/10/17 05:3002/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020138EPA 3005A1.577440-62-202/10/17 05:3002/06/17 18:25EPA 6020B2.66ug/L1Zinc10.0B-01, J7020138EPA 3005A1.307440-66-602/10/17 05:3002/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010680EPA 5030B8.267-64-101/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Acrylonitrile2007010680EPA 5030B2.5107-13-101/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Benzene1.07010680EPA 5030B0.271-43-201/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Bromochloromethane3.07010680EPA 5030B0.574-97-501/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Bromodichloromethane1.07010680EPA 5030B0.475-27-401/26/17 20:1101/26/17 12:15Page 48 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW21Ground WaterAAA0860-12AAA086001/25/17 12:38Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromoform3.07010680EPA 5030B0.675-25-201/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Bromomethane107010680EPA 5030B1.074-83-901/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Carbon Disulfide1007010680EPA 5030B0.875-15-001/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Carbon Tetrachloride1.07010680EPA 5030B0.456-23-501/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Chlorobenzene3.07010680EPA 5030B0.5108-90-701/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Chloroethane107010680EPA 5030B0.575-00-301/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Chloroform5.07010680EPA 5030B0.667-66-301/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Chloromethane1.07010680EPA 5030B0.474-87-301/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Dibromochloromethane3.07010680EPA 5030B0.3124-48-101/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010680EPA 5030B0.696-12-801/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L11,2-Dibromoethane1.07010680EPA 5030B0.3106-93-401/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Dibromomethane107010680EPA 5030B0.674-95-301/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010680EPA 5030B0.595-50-101/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010680EPA 5030B0.6106-46-701/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010680EPA 5030B1.6110-57-601/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethane5.07010680EPA 5030B0.475-34-301/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L11,2-Dichloroethane1.07010680EPA 5030B0.7107-06-201/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethene5.07010680EPA 5030B0.775-35-401/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010680EPA 5030B0.7156-59-201/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010680EPA 5030B0.5156-60-501/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L11,2-Dichloropropane1.07010680EPA 5030B0.678-87-501/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010680EPA 5030B0.210061-01-501/26/17 20:1101/26/17 12:15Page 49 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW21Ground WaterAAA0860-12AAA086001/25/17 12:38Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010680EPA 5030B0.310061-02-601/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Ethylbenzene1.07010680EPA 5030B0.4100-41-401/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Iodomethane107010680EPA 5030B3.174-88-401/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010680EPA 5030B0.9591-78-601/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Methylene Chloride1.07010680EPA 5030B0.575-09-201/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010680EPA 5030B3.278-93-301/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010680EPA 5030B0.9108-10-101/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Styrene1.07010680EPA 5030B0.5100-42-501/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010680EPA 5030B0.3630-20-601/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010680EPA 5030B0.579-34-501/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Tetrachloroethene1.07010680EPA 5030B0.8127-18-401/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Toluene1.07010680EPA 5030B0.3108-88-301/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010680EPA 5030B0.471-55-601/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010680EPA 5030B0.679-00-501/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Trichloroethene1.07010680EPA 5030B0.379-01-601/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Trichlorofluoromethane1.07010680EPA 5030B0.575-69-401/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010680EPA 5030B0.596-18-401/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Vinyl Acetate507010680EPA 5030B0.4108-05-401/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Vinyl Chloride1.07010680EPA 5030B0.675-01-401/26/17 20:1101/26/17 12:15NDEPA 8260Bug/L1Xylenes, total5.07010680EPA 5030B1.41330-20-701/26/17 20:1101/26/17 12:15EPA 8260B92 %Surr: Dibromofluoromethane7010680EPA 5030B1868-53-701/26/17 20:1101/26/17 12:1580-120Page 50 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW21Ground WaterAAA0860-12AAA086001/25/17 12:38Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260EPA 8260B100 %Surr: 1,2-Dichloroethane-d47010680EPA 5030B17060-07-001/26/17 20:1101/26/17 12:1578-120EPA 8260B104 %Surr: Toluene-d87010680EPA 5030B2037-26-501/26/17 20:1101/26/17 12:1580-120EPA 8260B102 %Surr: 4-Bromofluorobenzene7010680EPA 5030B460-00-401/26/17 20:1101/26/17 12:1580-120Page 51 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-PW1Ground WaterAAA0860-13AAA086001/25/17 12:05Project:East Carolina Regional Landfill01/26/17 09:20Metals, TotalNDEPA 6020Bug/L1Antimony6.007020138EPA 3005A0.257440-36-002/10/17 05:3602/06/17 18:25NDEPA 6020Bug/L1Arsenic10.07020138EPA 3005A0.757440-38-202/10/17 05:3602/06/17 18:25EPA 6020B67.1ug/L1Barium100J7020138EPA 3005A0.307440-39-302/10/17 05:3602/06/17 18:25NDEPA 6020Bug/L1Beryllium1.007020138EPA 3005A0.097440-41-702/10/17 05:3602/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020138EPA 3005A0.107440-43-902/10/17 05:3602/06/17 18:25NDEPA 6020Bug/L1Chromium10.07020138EPA 3005A0.437440-47-302/10/17 05:3602/06/17 18:25NDEPA 6020Bug/L1Cobalt10.07020138EPA 3005A0.297440-48-402/10/17 05:3602/06/17 18:25EPA 6020B186ug/L1Copper10.07020138EPA 3005A0.417440-50-802/10/17 05:3602/06/17 18:25EPA 6020B13.2ug/L1Lead10.07020138EPA 3005A0.087439-92-102/10/17 05:3602/06/17 18:25EPA 6020B2.17ug/L1Nickel50.0J7020138EPA 3005A0.487440-02-002/10/17 05:3602/06/17 18:25NDEPA 6020Bug/L1Selenium10.07020138EPA 3005A0.857782-49-202/10/17 05:3602/06/17 18:25NDEPA 6020Bug/L1Silver10.07020138EPA 3005A0.227440-22-402/10/17 05:3602/06/17 18:25NDEPA 6020Bug/L1Thallium5.507020138EPA 3005A0.067440-28-002/10/17 05:3602/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020138EPA 3005A1.577440-62-202/10/17 05:3602/06/17 18:25EPA 6020B316ug/L1Zinc10.0B-017020138EPA 3005A1.307440-66-602/10/17 05:3602/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010680EPA 5030B8.267-64-101/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Acrylonitrile2007010680EPA 5030B2.5107-13-101/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Benzene1.07010680EPA 5030B0.271-43-201/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Bromochloromethane3.07010680EPA 5030B0.574-97-501/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Bromodichloromethane1.07010680EPA 5030B0.475-27-401/26/17 20:3701/26/17 12:15Page 52 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-PW1Ground WaterAAA0860-13AAA086001/25/17 12:05Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromoform3.07010680EPA 5030B0.675-25-201/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Bromomethane107010680EPA 5030B1.074-83-901/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Carbon Disulfide1007010680EPA 5030B0.875-15-001/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Carbon Tetrachloride1.07010680EPA 5030B0.456-23-501/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Chlorobenzene3.07010680EPA 5030B0.5108-90-701/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Chloroethane107010680EPA 5030B0.575-00-301/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Chloroform5.07010680EPA 5030B0.667-66-301/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Chloromethane1.07010680EPA 5030B0.474-87-301/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Dibromochloromethane3.07010680EPA 5030B0.3124-48-101/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010680EPA 5030B0.696-12-801/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L11,2-Dibromoethane1.07010680EPA 5030B0.3106-93-401/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Dibromomethane107010680EPA 5030B0.674-95-301/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010680EPA 5030B0.595-50-101/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010680EPA 5030B0.6106-46-701/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010680EPA 5030B1.6110-57-601/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethane5.07010680EPA 5030B0.475-34-301/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L11,2-Dichloroethane1.07010680EPA 5030B0.7107-06-201/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethene5.07010680EPA 5030B0.775-35-401/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010680EPA 5030B0.7156-59-201/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010680EPA 5030B0.5156-60-501/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L11,2-Dichloropropane1.07010680EPA 5030B0.678-87-501/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010680EPA 5030B0.210061-01-501/26/17 20:3701/26/17 12:15Page 53 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-PW1Ground WaterAAA0860-13AAA086001/25/17 12:05Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010680EPA 5030B0.310061-02-601/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Ethylbenzene1.07010680EPA 5030B0.4100-41-401/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Iodomethane107010680EPA 5030B3.174-88-401/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010680EPA 5030B0.9591-78-601/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Methylene Chloride1.07010680EPA 5030B0.575-09-201/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010680EPA 5030B3.278-93-301/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010680EPA 5030B0.9108-10-101/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Styrene1.07010680EPA 5030B0.5100-42-501/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010680EPA 5030B0.3630-20-601/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010680EPA 5030B0.579-34-501/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Tetrachloroethene1.07010680EPA 5030B0.8127-18-401/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Toluene1.07010680EPA 5030B0.3108-88-301/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010680EPA 5030B0.471-55-601/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010680EPA 5030B0.679-00-501/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Trichloroethene1.07010680EPA 5030B0.379-01-601/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Trichlorofluoromethane1.07010680EPA 5030B0.575-69-401/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010680EPA 5030B0.596-18-401/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Vinyl Acetate507010680EPA 5030B0.4108-05-401/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Vinyl Chloride1.07010680EPA 5030B0.675-01-401/26/17 20:3701/26/17 12:15NDEPA 8260Bug/L1Xylenes, total5.07010680EPA 5030B1.41330-20-701/26/17 20:3701/26/17 12:15EPA 8260B91 %Surr: Dibromofluoromethane7010680EPA 5030B1868-53-701/26/17 20:3701/26/17 12:1580-120Page 54 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-PW1Ground WaterAAA0860-13AAA086001/25/17 12:05Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260EPA 8260B100 %Surr: 1,2-Dichloroethane-d47010680EPA 5030B17060-07-001/26/17 20:3701/26/17 12:1578-120EPA 8260B101 %Surr: Toluene-d87010680EPA 5030B2037-26-501/26/17 20:3701/26/17 12:1580-120EPA 8260B104 %Surr: 4-Bromofluorobenzene7010680EPA 5030B460-00-401/26/17 20:3701/26/17 12:1580-120Page 55 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020138 - EPA 3005ABlank (7020138-BLK1)Prepared: 02/06/17 Analyzed: 02/10/17 Antimonyug/LND6.00Arsenicug/LND10.0Bariumug/LND100Berylliumug/LND1.00Cadmiumug/LND1.00Chromiumug/LND10.0Cobaltug/LND10.0Copperug/LND10.0Leadug/LND10.0Nickelug/LND50.0Seleniumug/LND10.0Silverug/LND10.0Thalliumug/LND5.50Vanadiumug/LND25.0Zincug/L1.7710.0JLCS (7020138-BS1)Prepared: 02/06/17 Analyzed: 02/10/17 Antimonyug/L1096.00100.0080-120109Arsenicug/L10210.0100.0080-120102Bariumug/L99.4100100.00J80-12099Berylliumug/L1011.00100.0080-120101Cadmiumug/L1081.00100.0080-120108Chromiumug/L10610.0100.0080-120106Cobaltug/L98.510.0100.0080-12098Copperug/L10110.0100.0080-120101Leadug/L10410.0100.0080-120104Nickelug/L99.650.0100.0080-120100Page 56 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020138 - EPA 3005ALCS (7020138-BS1)Prepared: 02/06/17 Analyzed: 02/10/17 Seleniumug/L10310.0100.0080-120103Silverug/L10210.0100.0080-120102Thalliumug/L1065.50100.0080-120106Vanadiumug/L10525.0100.0080-120105Zincug/L10710.0100.0080-120107Matrix Spike (7020138-MS1)Prepared: 02/06/17 Analyzed: 02/10/17 Source: AAA0880-01Antimonyug/L1086.00100.000.2575-125107Arsenicug/L10010.0100.00ND75-125100Bariumug/L136100100.0038.075-12598Berylliumug/L99.21.00100.00ND75-12599Cadmiumug/L1041.00100.00ND75-125104Chromiumug/L10510.0100.000.9175-125104Cobaltug/L99.210.0100.00ND75-12599Copperug/L10010.0100.00ND75-125100Leadug/L10510.0100.00ND75-125105Nickelug/L10550.0100.002.3475-125102Seleniumug/L10210.0100.00ND75-125102Silverug/L10110.0100.00ND75-125101Thalliumug/L1045.50100.00ND75-125104Vanadiumug/L10325.0100.00ND75-125103Zincug/L10310.0100.003.3675-125100Matrix Spike Dup (7020138-MSD1)Prepared: 02/06/17 Analyzed: 02/10/17 Source: AAA0880-01Antimonyug/L1116.00100.000.252075-1251113Arsenicug/L10410.0100.00ND2075-1251044Bariumug/L142100100.0038.02075-1251045Berylliumug/L1041.00100.00ND2075-1251044Page 57 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020138 - EPA 3005AMatrix Spike Dup (7020138-MSD1)Prepared: 02/06/17 Analyzed: 02/10/17 Source: AAA0880-01Cadmiumug/L1071.00100.00ND2075-1251072Chromiumug/L11310.0100.000.912075-1251127Cobaltug/L10410.0100.00ND2075-1251045Copperug/L10710.0100.00ND2075-1251076Leadug/L10510.0100.00ND2075-1251050.4Nickelug/L10750.0100.002.342075-1251052Seleniumug/L10310.0100.00ND2075-1251031Silverug/L10610.0100.00ND2075-1251064Thalliumug/L1075.50100.00ND2075-1251072Vanadiumug/L11025.0100.00ND2075-1251106Zincug/L11110.0100.003.362075-1251087Post Spike (7020138-PS1)Prepared: 02/06/17 Analyzed: 02/10/17 Source: AAA0880-01Antimonyug/L102100.000.2580-120101Arsenicug/L101100.00-0.3480-120101Bariumug/L143100.0038.080-120105Berylliumug/L104100.000.0680-120104Cadmiumug/L110100.000.0480-120110Chromiumug/L110100.000.9180-120109Cobaltug/L104100.000.0180-120104Copperug/L104100.00-0.0680-120104Leadug/L102100.000.0480-120102Nickelug/L105100.002.3480-120103Seleniumug/L101100.000.2580-120101Silverug/L103100.000.0280-120103Thalliumug/L104100.000.0580-120104Vanadiumug/L107100.00-0.6880-120107Zincug/L108100.003.3680-120104Page 58 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020138 - EPA 3005ABatch 7020824 - EPA 3005ABlank (7020824-BLK1)Prepared & Analyzed: 02/28/17 Chromiumug/LND10.0Cobaltug/LND10.0Silverug/LND10.0LCS (7020824-BS1)Prepared & Analyzed: 02/28/17 Chromiumug/L11210.0100.0080-120112Cobaltug/L10310.0100.0080-120103Silverug/L10310.0100.0080-120103Duplicate (7020824-DUP1)Prepared & Analyzed: 02/28/17 Source: AAA0860-02RE1Chromiumug/L3.9210.04.1720J6Cobaltug/L31.810.033.0204Silverug/L43.010.040.9205Duplicate (7020824-DUP2)Prepared & Analyzed: 02/28/17 Source: AAA0860-10RE1Chromiumug/L11.010.010.02010Cobaltug/L3.7510.03.5520J6Silverug/L4.2910.04.5320J6Matrix Spike (7020824-MS1)Prepared & Analyzed: 02/28/17 Source: AAA0860-10RE1Chromiumug/L12410.0100.0010.075-125114Cobaltug/L10910.0100.003.5575-125105Silverug/L10810.0100.004.5375-125104Page 59 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020824 - EPA 3005AMatrix Spike Dup (7020824-MSD1)Prepared & Analyzed: 02/28/17 Source: AAA0860-10RE1Chromiumug/L13110.0100.0010.02075-1251215Cobaltug/L11010.0100.003.552075-1251061Silverug/L11410.0100.004.532075-1251105Post Spike (7020824-PS1)Prepared & Analyzed: 02/28/17 Source: AAA0860-10RE1Chromiumug/L122100.0010.080-120112Cobaltug/L109100.003.5580-120106Silverug/L110100.004.5380-120106Page 60 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010680 - EPA 5030BBlank (7010680-BLK1)Prepared & Analyzed: 01/26/17 Acetoneug/LND100Acrylonitrileug/LND200Benzeneug/LND1.0Bromochloromethaneug/LND3.0Bromodichloromethaneug/LND1.0Bromoformug/LND3.0Bromomethaneug/LND10Carbon Disulfideug/LND100Carbon Tetrachlorideug/LND1.0Chlorobenzeneug/LND3.0Chloroethaneug/LND10Chloroformug/LND5.0Chloromethaneug/LND1.0Dibromochloromethaneug/LND3.01,2-Dibromo-3-chloropropaneug/LND131,2-Dibromoethaneug/LND1.0Dibromomethaneug/LND101,2-Dichlorobenzeneug/LND5.01,4-Dichlorobenzeneug/LND1.0trans-1,4-Dichloro-2-buteneug/LND1001,1-Dichloroethaneug/LND5.01,2-Dichloroethaneug/LND1.01,1-Dichloroetheneug/LND5.0cis-1,2-Dichloroetheneug/LND5.0trans-1,2-Dichloroetheneug/LND5.01,2-Dichloropropaneug/LND1.0cis-1,3-Dichloropropeneug/LND1.0Page 61 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010680 - EPA 5030BBlank (7010680-BLK1)Prepared & Analyzed: 01/26/17 trans-1,3-Dichloropropeneug/LND1.0Ethylbenzeneug/LND1.0Iodomethaneug/LND10Methyl Butyl Ketone (2-Hexanone)ug/LND50Methylene Chlorideug/LND1.0Methyl Ethyl Ketone (2-Butanone)ug/LND1004-Methyl-2-pentanone (MIBK)ug/LND100Styreneug/LND1.01,1,1,2-Tetrachloroethaneug/LND5.01,1,2,2-Tetrachloroethaneug/LND3.0Tetrachloroetheneug/LND1.0Tolueneug/LND1.01,1,1-Trichloroethaneug/LND1.01,1,2-Trichloroethaneug/LND1.0Trichloroetheneug/LND1.0Trichlorofluoromethaneug/LND1.01,2,3-Trichloropropaneug/LND1.0Vinyl Acetateug/LND50Vinyl Chlorideug/LND1.0Xylenes, totalug/LND5.0ug/L50.00080-120Surr: Dibromofluoromethane9346ug/L50.00078-120Surr: 1,2-Dichloroethane-d49648ug/L50.00080-120Surr: Toluene-d810352ug/L50.00080-120Surr: 4-Bromofluorobenzene10352LCS (7010680-BS1)Prepared & Analyzed: 01/26/17 Benzeneug/L4950.00067-13499Page 62 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010680 - EPA 5030BLCS (7010680-BS1)Prepared & Analyzed: 01/26/17 Chlorobenzeneug/L4950.00069-122981,1-Dichloroetheneug/L5450.00058-142108Tolueneug/L4550.00068-12791Trichloroetheneug/L4950.00072-13298ug/L50.00080-120Surr: Dibromofluoromethane9346ug/L50.00078-120Surr: 1,2-Dichloroethane-d49547ug/L50.00080-120Surr: Toluene-d810251ug/L50.00080-120Surr: 4-Bromofluorobenzene10251Matrix Spike (7010680-MS1)Prepared & Analyzed: 01/26/17 Source: AAA0860-02Benzeneug/L5850.0000.067-134116Chlorobenzeneug/L5550.0000.069-1221101,1-Dichloroetheneug/L6950.0000.058-142137Tolueneug/L5050.0000.068-127101Trichloroetheneug/L5650.0000.072-132113ug/L50.00080-120Surr: Dibromofluoromethane8844ug/L50.00078-120Surr: 1,2-Dichloroethane-d410151ug/L50.00080-120Surr: Toluene-d810150ug/L50.00080-120Surr: 4-Bromofluorobenzene10251Matrix Spike Dup (7010680-MSD1)Prepared & Analyzed: 01/26/17 Source: AAA0860-02Benzeneug/L5950.0000.0967-1341171Chlorobenzeneug/L5850.0000.01369-12211551,1-Dichloroetheneug/L6950.0000.0958-1421390.9Tolueneug/L5350.0000.0968-1271066Trichloroetheneug/L5850.0000.01172-1321163Page 63 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010680 - EPA 5030BMatrix Spike Dup (7010680-MSD1)Prepared & Analyzed: 01/26/17 Source: AAA0860-02ug/L50.00080-120Surr: Dibromofluoromethane9045ug/L50.00078-120Surr: 1,2-Dichloroethane-d410050ug/L50.00080-120Surr: Toluene-d810351ug/L50.00080-120Surr: 4-Bromofluorobenzene10352Page 64 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017Laboratory CertificationsCodeDescriptionNumberExpires812Georgia DW Inorganics Eff: 07/01/201606/30/2017GADW812Georgia DW Microbiology Eff: 07/01/201503/09/2017GADWM381North Carolina12/31/2017NCE87315FL DOH (Non-Pot. Water, Solids) Eff:: 07/01/201606/30/2017NELACE87315FL DOH NELAC (Drinking Water) Eff: 07/01/201606/30/2017NELDW98011001South Carolina06/30/2017SCT104704397-08-TXTexas03/31/2017TX1340Virginia12/14/2017VAPage 65 of 68
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 01, 2017LegendDefination of Laboratory Terms - Not Detected at levels greater than or equal to SWSL/RLNDSWSL/RLMDL - NC DENR Solid Waste Section LImit/Reporting Limit (Adjusted for DF/Prep Factor) - Method Detection LimitQualifiers - Dilution FactorDFJEstimated value less than Reporting Limit (RL) but greater than Method Detection Limit(MDL) (CLP J-Flag).B-01Analyte was detected in the associated method blank at an estimated level equal to or greater than the MDL. Sample values reported as greater than the MDL and less than 10x the method blank value are reported as estimated values.Note: Unless otherwise noted, all results are reported on an as received basis.Page 66 of 68
Page 67 of 68
LOG-IN CHECKLIST
Republic Services of North Carolina, LLC
East Carolina Regional LandfillProject:
Client:
Printed: 3/1/2017 2:31:12PM
Environmental Monitoring & Laboratory Analysis
[phone] FAX [phone]
110 Technology Parkway, Peachtree Corners, GA 30092
PACE ANALYTICAL SERVICES, LLC.
Date Received:01/26/17 09:20 Logged In By:Charles Hawks
Work Order:AAA0860
OBSERVATIONS
Attn: Mr. Matt Einsmann
#Samples: 13 #Containers: 56
2.0 2.0
YES
Minimum Temp(C):Maximum Temp(C):
CHECKLIST ITEMS
COC included with Samples
Sample Container(s) Intact
Chain of Custody Complete
Sample Container(s) Match COC
Custody seal Intact
Temperature in Compliance
Sufficient Sample Volume for Analysis
Zero Headspace Maintained for VOA Analyses
Samples labeled preserved (If Applicable)
Samples received within Allowable Hold Times
Samples Received on Ice
Preservation Confirmed
YES
YES
YES
N/A
YES
YES
YES
YES
YES
YES
YES
Custody Seal(s) Used:No
Per communication with consultant 2/22/2017, GW7 (AAA0860-02) was reanalyzed for cobalt and silver, GW17
(AAA0860-10) was reanalyzed for chromium. BMcD
Comments:
Page 1 of 1Page 68 of 68
PACE ANALYTICAL SERVICES, LLC.Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]Republic Services of North Carolina, LLCProject: East Carolina Regional LandfillConover, NC 286131220 Commerce Street, SWMr. Matt EinsmannWe appreciate the opportunity to provide the analytical support for your project. The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Pace Analytical Services, LLC. certifies that the following analytical results meet all requirements of the National Environmental Laboratory Accreditation Conference(NELAC).All test results relate only to the samples analyzed.Laboratory ReportProject #:[none]Prepared For:Attention:February 27, 2017Report Number:AAA0859Approved:This report may not be reproduced, except in full, without written approval from Pace Analytical Services, LLC.Page 1 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 27, 2017Sample IDLaboratory IDMatrixDate SampledANALYTICAL REPORT FOR SAMPLESDate Received0803-GW7AAA0859-0101/25/17 13:02 01/26/17 09:20Ground Water0803-GW17AAA0859-0301/25/17 10:5301/26/17 09:20Ground WaterPage 2 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 27, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW7Ground WaterAAA0859-01AAA085901/25/17 13:02Project:East Carolina Regional Landfill01/26/17 09:20Metals, DissolvedNDEPA 6020Bug/L1Cobalt10.07020670EPA 3005A0.527440-48-402/24/17 15:5302/24/17 09:55NDEPA 6020Bug/L1Silver10.07020670EPA 3005A0.487440-22-402/24/17 15:5302/24/17 09:55Page 3 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 27, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW17Ground WaterAAA0859-03AAA085901/25/17 10:53Project:East Carolina Regional Landfill01/26/17 09:20Metals, DissolvedNDEPA 6020Bug/L1Chromium10.07020670EPA 3005A0.947440-47-302/24/17 16:0002/24/17 09:55Page 4 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 27, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Dissolved - Quality ControlBatch 7020670 - EPA 3005ABlank (7020670-BLK1)Prepared & Analyzed: 02/24/17 Chromiumug/LND10.0Cobaltug/LND10.0Silverug/LND10.0Blank (7020670-BLK2)Prepared & Analyzed: 02/24/17 Chromiumug/LND10.0Cobaltug/LND10.0Silverug/LND10.0LCS (7020670-BS1)Prepared & Analyzed: 02/24/17 Chromiumug/L10510.0100.0080-120105Cobaltug/L10310.0100.0080-120103Silverug/L11210.0100.0080-120112LCS (7020670-BS2)Prepared & Analyzed: 02/24/17 Chromiumug/L10810.0100.0080-120108Cobaltug/L10610.0100.0080-120106Silverug/L10910.0100.0080-120109Matrix Spike (7020670-MS1)Prepared & Analyzed: 02/24/17 Source: AAA0880-18Chromiumug/L99.510.0100.00ND75-125100Cobaltug/L19410.0100.0092.875-125101Silverug/L10510.0100.00ND75-125105Matrix Spike Dup (7020670-MSD1)Prepared & Analyzed: 02/24/17 Source: AAA0880-18Chromiumug/L10610.0100.00ND2075-1251066Cobaltug/L19810.0100.0092.82075-1251052Silverug/L10710.0100.00ND2075-1251072Page 5 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 27, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Dissolved - Quality ControlBatch 7020670 - EPA 3005APost Spike (7020670-PS1)Prepared & Analyzed: 02/24/17 Source: AAA0880-18Chromiumug/L104100.00-7.3880-120104Cobaltug/L187100.0092.880-12094Silverug/L101100.000.0480-120101Page 6 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 27, 2017Laboratory CertificationsCodeDescriptionNumberExpires812Georgia DW Inorganics Eff: 07/01/201606/30/2017GADW812Georgia DW Microbiology Eff: 07/01/201503/09/2017GADWM381North Carolina12/31/2017NCE87315FL DOH (Non-Pot. Water, Solids) Eff:: 07/01/201606/30/2017NELACE87315FL DOH NELAC (Drinking Water) Eff: 07/01/201606/30/2017NELDW98011001South Carolina06/30/2017SCT104704397-08-TXTexas03/31/2017TX1340Virginia12/14/2017VAPage 7 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 27, 2017LegendDefination of Laboratory Terms - Not Detected at levels greater than or equal to SWSL/RLNDSWSL/RLMDL - NC DENR Solid Waste Section LImit/Reporting Limit (Adjusted for DF/Prep Factor) - Method Detection LimitQualifiers - Dilution FactorDFNote: Unless otherwise noted, all results are reported on an as received basis.Page 8 of 10
Page 9 of 10
LOG-IN CHECKLIST
Republic Services of North Carolina, LLC
East Carolina Regional LandfillProject:
Client:
Printed: 1/30/2017 12:11:35PM
Environmental Monitoring & Laboratory Analysis
[phone] FAX [phone]
110 Technology Parkway, Peachtree Corners, GA 30092
PACE ANALYTICAL SERVICES, LLC.
Date Received:01/26/17 09:20 Logged In By:Charles Hawks
Work Order:AAA0859
OBSERVATIONS
Attn: Mr. Matt Einsmann
#Samples: 3 #Containers: 3
2.0 2.0
YES
Minimum Temp(C):Maximum Temp(C):
CHECKLIST ITEMS
COC included with Samples
Sample Container(s) Intact
Chain of Custody Complete
Sample Container(s) Match COC
Custody seal Intact
Temperature in Compliance
Sufficient Sample Volume for Analysis
Zero Headspace Maintained for VOA Analyses
Samples labeled preserved (If Applicable)
Samples received within Allowable Hold Times
Samples Received on Ice
Preservation Confirmed
YES
YES
YES
N/A
YES
YES
YES
YES
YES
YES
YES
Custody Seal(s) Used:No
Comments:
Page 1 of 1Page 10 of 10
PACE ANALYTICAL SERVICES, LLC.Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]Republic Services of North Carolina, LLCProject: East Carolina Regional LandfillConover, NC 286131220 Commerce Street, SWMr. Matt EinsmannWe appreciate the opportunity to provide the analytical support for your project. The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Pace Analytical Services, LLC. certifies that the following analytical results meet all requirements of the National Environmental Laboratory Accreditation Conference(NELAC).All test results relate only to the samples analyzed.Laboratory ReportProject #:[none]Prepared For:Attention:May 09, 2017Report Number:AAA0864Approved:This report may not be reproduced, except in full, without written approval from Pace Analytical Services, LLC.Page 1 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017Sample IDLaboratory IDMatrixDate SampledANALYTICAL REPORT FOR SAMPLESDate Received0803-SW1AAA0864-0101/25/17 13:27 01/26/17 09:20Surface Water0803-SW2AAA0864-0201/25/17 14:1301/26/17 09:20Surface Water0803-SW3AAA0864-0301/25/17 12:1601/26/17 09:20Surface WaterPage 2 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017East Carolina Regional Landfill Report AAA0864 5/9/2017This revised report replaces the original report submitted on 2/20/2017.Per consultant request, hardness analysis was added to AAA0864-02 (0803-SW2). No other changes were made to this report.Case NarrativePage 3 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-SW1Surface WaterAAA0864-01AAA086401/25/17 13:27Project:East Carolina Regional Landfill01/26/17 09:20Metals, TotalNDEPA 6020Bug/L1Antimony6.007020138EPA 3005A0.257440-36-002/10/17 05:4702/06/17 18:25NDEPA 6020Bug/L1Arsenic10.07020138EPA 3005A0.757440-38-202/10/17 05:4702/06/17 18:25EPA 6020B47.1ug/L1Barium100J7020138EPA 3005A0.307440-39-302/10/17 05:4702/06/17 18:25EPA 6020B0.17ug/L1Beryllium1.00J7020138EPA 3005A0.097440-41-702/10/17 05:4702/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020138EPA 3005A0.107440-43-902/10/17 05:4702/06/17 18:25EPA 6020B1.92ug/L1Chromium10.0J7020138EPA 3005A0.437440-47-302/10/17 05:4702/06/17 18:25EPA 6020B1.18ug/L1Cobalt10.0J7020138EPA 3005A0.297440-48-402/10/17 05:4702/06/17 18:25EPA 6020B0.96ug/L1Copper10.0J7020138EPA 3005A0.417440-50-802/10/17 05:4702/06/17 18:25EPA 6020B1.21ug/L1Lead10.0J7020138EPA 3005A0.087439-92-102/10/17 05:4702/06/17 18:25EPA 6020B1.50ug/L1Nickel50.0J7020138EPA 3005A0.487440-02-002/10/17 05:4702/06/17 18:25NDEPA 6020Bug/L1Selenium10.07020138EPA 3005A0.857782-49-202/10/17 05:4702/06/17 18:25NDEPA 6020Bug/L1Silver10.07020138EPA 3005A0.227440-22-402/10/17 05:4702/06/17 18:25NDEPA 6020Bug/L1Thallium5.507020138EPA 3005A0.067440-28-002/10/17 05:4702/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020138EPA 3005A1.577440-62-202/10/17 05:4702/06/17 18:25EPA 6020B6.59ug/L1Zinc10.0B-01, J7020138EPA 3005A1.307440-66-602/10/17 05:4702/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010680EPA 5030B8.267-64-101/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Acrylonitrile2007010680EPA 5030B2.5107-13-101/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Benzene1.07010680EPA 5030B0.271-43-201/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Bromochloromethane3.07010680EPA 5030B0.574-97-501/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Bromodichloromethane1.07010680EPA 5030B0.475-27-401/26/17 14:1801/26/17 12:15Page 4 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-SW1Surface WaterAAA0864-01AAA086401/25/17 13:27Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromoform3.07010680EPA 5030B0.675-25-201/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Bromomethane107010680EPA 5030B1.074-83-901/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Carbon Disulfide1007010680EPA 5030B0.875-15-001/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Carbon Tetrachloride1.07010680EPA 5030B0.456-23-501/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Chlorobenzene3.07010680EPA 5030B0.5108-90-701/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Chloroethane107010680EPA 5030B0.575-00-301/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Chloroform5.07010680EPA 5030B0.667-66-301/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Chloromethane1.07010680EPA 5030B0.474-87-301/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Dibromochloromethane3.07010680EPA 5030B0.3124-48-101/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010680EPA 5030B0.696-12-801/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L11,2-Dibromoethane1.07010680EPA 5030B0.3106-93-401/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Dibromomethane107010680EPA 5030B0.674-95-301/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010680EPA 5030B0.595-50-101/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010680EPA 5030B0.6106-46-701/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010680EPA 5030B1.6110-57-601/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethane5.07010680EPA 5030B0.475-34-301/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L11,2-Dichloroethane1.07010680EPA 5030B0.7107-06-201/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethene5.07010680EPA 5030B0.775-35-401/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010680EPA 5030B0.7156-59-201/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010680EPA 5030B0.5156-60-501/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L11,2-Dichloropropane1.07010680EPA 5030B0.678-87-501/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010680EPA 5030B0.210061-01-501/26/17 14:1801/26/17 12:15Page 5 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-SW1Surface WaterAAA0864-01AAA086401/25/17 13:27Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010680EPA 5030B0.310061-02-601/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Ethylbenzene1.07010680EPA 5030B0.4100-41-401/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Iodomethane107010680EPA 5030B3.174-88-401/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010680EPA 5030B0.9591-78-601/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Methylene Chloride1.07010680EPA 5030B0.575-09-201/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010680EPA 5030B3.278-93-301/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010680EPA 5030B0.9108-10-101/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Styrene1.07010680EPA 5030B0.5100-42-501/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010680EPA 5030B0.3630-20-601/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010680EPA 5030B0.579-34-501/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Tetrachloroethene1.07010680EPA 5030B0.8127-18-401/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Toluene1.07010680EPA 5030B0.3108-88-301/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010680EPA 5030B0.471-55-601/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010680EPA 5030B0.679-00-501/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Trichloroethene1.07010680EPA 5030B0.379-01-601/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Trichlorofluoromethane1.07010680EPA 5030B0.575-69-401/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010680EPA 5030B0.596-18-401/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Vinyl Acetate507010680EPA 5030B0.4108-05-401/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Vinyl Chloride1.07010680EPA 5030B0.675-01-401/26/17 14:1801/26/17 12:15NDEPA 8260Bug/L1Xylenes, total5.07010680EPA 5030B1.41330-20-701/26/17 14:1801/26/17 12:15EPA 8260B93 %Surr: Dibromofluoromethane7010680EPA 5030B1868-53-701/26/17 14:1801/26/17 12:1580-120Page 6 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-SW1Surface WaterAAA0864-01AAA086401/25/17 13:27Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260EPA 8260B97 %Surr: 1,2-Dichloroethane-d47010680EPA 5030B17060-07-001/26/17 14:1801/26/17 12:1578-120EPA 8260B102 %Surr: Toluene-d87010680EPA 5030B2037-26-501/26/17 14:1801/26/17 12:1580-120EPA 8260B103 %Surr: 4-Bromofluorobenzene7010680EPA 5030B460-00-401/26/17 14:1801/26/17 12:1580-120Page 7 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-SW2Surface WaterAAA0864-02AAA086401/25/17 14:13Project:East Carolina Regional Landfill01/26/17 09:20Metals, TotalEPA 6020B1.89ug/L1Antimony6.00J7020138EPA 3005A0.257440-36-002/17/17 14:3902/06/17 18:25EPA 6020B2.65ug/L1Arsenic10.0J7020138EPA 3005A0.757440-38-202/17/17 14:3902/06/17 18:25EPA 6020B106ug/L1Barium1007020138EPA 3005A0.307440-39-302/17/17 14:3902/06/17 18:25NDEPA 6020Bug/L1Beryllium1.007020138EPA 3005A0.097440-41-702/17/17 14:3902/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020138EPA 3005A0.107440-43-902/17/17 14:3902/06/17 18:25EPA 6020B9.27ug/L1Chromium10.0J7020138EPA 3005A0.437440-47-302/17/17 14:3902/06/17 18:25EPA 6020B3.22ug/L1Cobalt10.0J7020138EPA 3005A0.297440-48-402/17/17 14:3902/06/17 18:25EPA 6020B16.4ug/L1Copper10.07020138EPA 3005A0.417440-50-802/17/17 14:3902/06/17 18:25EPA 6020B1.29ug/L1Lead10.0J7020138EPA 3005A0.087439-92-102/17/17 14:3902/06/17 18:25EPA 6020B18.1ug/L1Nickel50.0J7020138EPA 3005A0.487440-02-002/17/17 14:3902/06/17 18:25NDEPA 6020Bug/L1Selenium10.07020138EPA 3005A0.857782-49-202/17/17 14:3902/06/17 18:25NDEPA 6020Bug/L1Silver10.07020138EPA 3005A0.227440-22-402/17/17 14:3902/06/17 18:25NDEPA 6020Bug/L1Thallium5.507020138EPA 3005A0.067440-28-002/17/17 14:3902/06/17 18:25EPA 6020B6.42ug/L1Vanadium25.0J7020138EPA 3005A1.577440-62-202/17/17 14:3902/06/17 18:25EPA 6020B16.1ug/L1Zinc10.0B-017020138EPA 3005A1.307440-66-602/17/17 14:3902/06/17 18:25EPA 200.725.6mg/L1Calcium1.007050099EPA 200.70.0517440-70-205/04/17 17:1505/03/17 11:50EPA 200.742.0mg/L1Magnesium0.0507050099EPA 200.70.0067439-95-405/04/17 17:1505/03/17 11:50SM 2340 B237mg/L1Hardness2.70[CALC][CALC]0.15205/04/17 17:1505/03/17 11:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010680EPA 5030B8.267-64-101/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Acrylonitrile2007010680EPA 5030B2.5107-13-101/26/17 14:4301/26/17 12:15Page 8 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-SW2Surface WaterAAA0864-02AAA086401/25/17 14:13Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Benzene1.07010680EPA 5030B0.271-43-201/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Bromochloromethane3.07010680EPA 5030B0.574-97-501/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Bromodichloromethane1.07010680EPA 5030B0.475-27-401/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Bromoform3.07010680EPA 5030B0.675-25-201/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Bromomethane107010680EPA 5030B1.074-83-901/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Carbon Disulfide1007010680EPA 5030B0.875-15-001/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Carbon Tetrachloride1.07010680EPA 5030B0.456-23-501/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Chlorobenzene3.07010680EPA 5030B0.5108-90-701/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Chloroethane107010680EPA 5030B0.575-00-301/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Chloroform5.07010680EPA 5030B0.667-66-301/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Chloromethane1.07010680EPA 5030B0.474-87-301/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Dibromochloromethane3.07010680EPA 5030B0.3124-48-101/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010680EPA 5030B0.696-12-801/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L11,2-Dibromoethane1.07010680EPA 5030B0.3106-93-401/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Dibromomethane107010680EPA 5030B0.674-95-301/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010680EPA 5030B0.595-50-101/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010680EPA 5030B0.6106-46-701/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010680EPA 5030B1.6110-57-601/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethane5.07010680EPA 5030B0.475-34-301/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L11,2-Dichloroethane1.07010680EPA 5030B0.7107-06-201/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethene5.07010680EPA 5030B0.775-35-401/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010680EPA 5030B0.7156-59-201/26/17 14:4301/26/17 12:15Page 9 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-SW2Surface WaterAAA0864-02AAA086401/25/17 14:13Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010680EPA 5030B0.5156-60-501/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L11,2-Dichloropropane1.07010680EPA 5030B0.678-87-501/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010680EPA 5030B0.210061-01-501/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010680EPA 5030B0.310061-02-601/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Ethylbenzene1.07010680EPA 5030B0.4100-41-401/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Iodomethane107010680EPA 5030B3.174-88-401/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010680EPA 5030B0.9591-78-601/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Methylene Chloride1.07010680EPA 5030B0.575-09-201/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010680EPA 5030B3.278-93-301/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010680EPA 5030B0.9108-10-101/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Styrene1.07010680EPA 5030B0.5100-42-501/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010680EPA 5030B0.3630-20-601/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010680EPA 5030B0.579-34-501/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Tetrachloroethene1.07010680EPA 5030B0.8127-18-401/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Toluene1.07010680EPA 5030B0.3108-88-301/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010680EPA 5030B0.471-55-601/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010680EPA 5030B0.679-00-501/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Trichloroethene1.07010680EPA 5030B0.379-01-601/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Trichlorofluoromethane1.07010680EPA 5030B0.575-69-401/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010680EPA 5030B0.596-18-401/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Vinyl Acetate507010680EPA 5030B0.4108-05-401/26/17 14:4301/26/17 12:15Page 10 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-SW2Surface WaterAAA0864-02AAA086401/25/17 14:13Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Vinyl Chloride1.07010680EPA 5030B0.675-01-401/26/17 14:4301/26/17 12:15NDEPA 8260Bug/L1Xylenes, total5.07010680EPA 5030B1.41330-20-701/26/17 14:4301/26/17 12:15EPA 8260B89 %Surr: Dibromofluoromethane7010680EPA 5030B1868-53-701/26/17 14:4301/26/17 12:1580-120EPA 8260B98 %Surr: 1,2-Dichloroethane-d47010680EPA 5030B17060-07-001/26/17 14:4301/26/17 12:1578-120EPA 8260B103 %Surr: Toluene-d87010680EPA 5030B2037-26-501/26/17 14:4301/26/17 12:1580-120EPA 8260B101 %Surr: 4-Bromofluorobenzene7010680EPA 5030B460-00-401/26/17 14:4301/26/17 12:1580-120Page 11 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-SW3Surface WaterAAA0864-03AAA086401/25/17 12:16Project:East Carolina Regional Landfill01/26/17 09:20Metals, TotalEPA 6020B0.35ug/L1Antimony6.00J7020138EPA 3005A0.257440-36-002/17/17 14:4502/06/17 18:25EPA 6020B1.20ug/L1Arsenic10.0J7020138EPA 3005A0.757440-38-202/17/17 14:4502/06/17 18:25EPA 6020B81.2ug/L1Barium100J7020138EPA 3005A0.307440-39-302/17/17 14:4502/06/17 18:25EPA 6020B0.14ug/L1Beryllium1.00J7020138EPA 3005A0.097440-41-702/17/17 14:4502/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020138EPA 3005A0.107440-43-902/17/17 14:4502/06/17 18:25EPA 6020B2.71ug/L1Chromium10.0J7020138EPA 3005A0.437440-47-302/17/17 14:4502/06/17 18:25EPA 6020B4.26ug/L1Cobalt10.0J7020138EPA 3005A0.297440-48-402/17/17 14:4502/06/17 18:25EPA 6020B2.08ug/L1Copper10.0J7020138EPA 3005A0.417440-50-802/17/17 14:4502/06/17 18:25EPA 6020B1.31ug/L1Lead10.0J7020138EPA 3005A0.087439-92-102/17/17 14:4502/06/17 18:25EPA 6020B3.83ug/L1Nickel50.0J7020138EPA 3005A0.487440-02-002/17/17 14:4502/06/17 18:25EPA 6020B0.98ug/L1Selenium10.0J7020138EPA 3005A0.857782-49-202/17/17 14:4502/06/17 18:25NDEPA 6020Bug/L1Silver10.07020138EPA 3005A0.227440-22-402/17/17 14:4502/06/17 18:25NDEPA 6020Bug/L1Thallium5.507020138EPA 3005A0.067440-28-002/17/17 14:4502/06/17 18:25EPA 6020B3.52ug/L1Vanadium25.0J7020138EPA 3005A1.577440-62-202/17/17 14:4502/06/17 18:25EPA 6020B8.33ug/L1Zinc10.0B-01, J7020138EPA 3005A1.307440-66-602/17/17 14:4502/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010680EPA 5030B8.267-64-101/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Acrylonitrile2007010680EPA 5030B2.5107-13-101/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Benzene1.07010680EPA 5030B0.271-43-201/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Bromochloromethane3.07010680EPA 5030B0.574-97-501/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Bromodichloromethane1.07010680EPA 5030B0.475-27-401/26/17 15:0901/26/17 12:15Page 12 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-SW3Surface WaterAAA0864-03AAA086401/25/17 12:16Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromoform3.07010680EPA 5030B0.675-25-201/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Bromomethane107010680EPA 5030B1.074-83-901/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Carbon Disulfide1007010680EPA 5030B0.875-15-001/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Carbon Tetrachloride1.07010680EPA 5030B0.456-23-501/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Chlorobenzene3.07010680EPA 5030B0.5108-90-701/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Chloroethane107010680EPA 5030B0.575-00-301/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Chloroform5.07010680EPA 5030B0.667-66-301/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Chloromethane1.07010680EPA 5030B0.474-87-301/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Dibromochloromethane3.07010680EPA 5030B0.3124-48-101/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010680EPA 5030B0.696-12-801/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L11,2-Dibromoethane1.07010680EPA 5030B0.3106-93-401/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Dibromomethane107010680EPA 5030B0.674-95-301/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010680EPA 5030B0.595-50-101/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010680EPA 5030B0.6106-46-701/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010680EPA 5030B1.6110-57-601/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethane5.07010680EPA 5030B0.475-34-301/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L11,2-Dichloroethane1.07010680EPA 5030B0.7107-06-201/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethene5.07010680EPA 5030B0.775-35-401/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010680EPA 5030B0.7156-59-201/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010680EPA 5030B0.5156-60-501/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L11,2-Dichloropropane1.07010680EPA 5030B0.678-87-501/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010680EPA 5030B0.210061-01-501/26/17 15:0901/26/17 12:15Page 13 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-SW3Surface WaterAAA0864-03AAA086401/25/17 12:16Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010680EPA 5030B0.310061-02-601/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Ethylbenzene1.07010680EPA 5030B0.4100-41-401/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Iodomethane107010680EPA 5030B3.174-88-401/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010680EPA 5030B0.9591-78-601/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Methylene Chloride1.07010680EPA 5030B0.575-09-201/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010680EPA 5030B3.278-93-301/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010680EPA 5030B0.9108-10-101/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Styrene1.07010680EPA 5030B0.5100-42-501/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010680EPA 5030B0.3630-20-601/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010680EPA 5030B0.579-34-501/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Tetrachloroethene1.07010680EPA 5030B0.8127-18-401/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Toluene1.07010680EPA 5030B0.3108-88-301/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010680EPA 5030B0.471-55-601/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010680EPA 5030B0.679-00-501/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Trichloroethene1.07010680EPA 5030B0.379-01-601/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Trichlorofluoromethane1.07010680EPA 5030B0.575-69-401/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010680EPA 5030B0.596-18-401/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Vinyl Acetate507010680EPA 5030B0.4108-05-401/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Vinyl Chloride1.07010680EPA 5030B0.675-01-401/26/17 15:0901/26/17 12:15NDEPA 8260Bug/L1Xylenes, total5.07010680EPA 5030B1.41330-20-701/26/17 15:0901/26/17 12:15EPA 8260B91 %Surr: Dibromofluoromethane7010680EPA 5030B1868-53-701/26/17 15:0901/26/17 12:1580-120Page 14 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-SW3Surface WaterAAA0864-03AAA086401/25/17 12:16Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260EPA 8260B99 %Surr: 1,2-Dichloroethane-d47010680EPA 5030B17060-07-001/26/17 15:0901/26/17 12:1578-120EPA 8260B102 %Surr: Toluene-d87010680EPA 5030B2037-26-501/26/17 15:0901/26/17 12:1580-120EPA 8260B101 %Surr: 4-Bromofluorobenzene7010680EPA 5030B460-00-401/26/17 15:0901/26/17 12:1580-120Page 15 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020138 - EPA 3005ABlank (7020138-BLK1)Prepared: 02/06/17 Analyzed: 02/10/17 Antimonyug/LND6.00Arsenicug/LND10.0Bariumug/LND100Berylliumug/LND1.00Cadmiumug/LND1.00Chromiumug/LND10.0Cobaltug/LND10.0Copperug/LND10.0Leadug/LND10.0Nickelug/LND50.0Seleniumug/LND10.0Silverug/LND10.0Thalliumug/LND5.50Vanadiumug/LND25.0Zincug/L1.7710.0JLCS (7020138-BS1)Prepared: 02/06/17 Analyzed: 02/10/17 Antimonyug/L1096.00100.0080-120109Arsenicug/L10210.0100.0080-120102Bariumug/L99.4100100.00J80-12099Berylliumug/L1011.00100.0080-120101Cadmiumug/L1081.00100.0080-120108Chromiumug/L10610.0100.0080-120106Cobaltug/L98.510.0100.0080-12098Copperug/L10110.0100.0080-120101Leadug/L10410.0100.0080-120104Nickelug/L99.650.0100.0080-120100Page 16 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020138 - EPA 3005ALCS (7020138-BS1)Prepared: 02/06/17 Analyzed: 02/10/17 Seleniumug/L10310.0100.0080-120103Silverug/L10210.0100.0080-120102Thalliumug/L1065.50100.0080-120106Vanadiumug/L10525.0100.0080-120105Zincug/L10710.0100.0080-120107Matrix Spike (7020138-MS1)Prepared: 02/06/17 Analyzed: 02/10/17 Source: AAA0880-01Antimonyug/L1086.00100.000.2575-125107Arsenicug/L10010.0100.00ND75-125100Bariumug/L136100100.0038.075-12598Berylliumug/L99.21.00100.00ND75-12599Cadmiumug/L1041.00100.00ND75-125104Chromiumug/L10510.0100.000.9175-125104Cobaltug/L99.210.0100.00ND75-12599Copperug/L10010.0100.00ND75-125100Leadug/L10510.0100.00ND75-125105Nickelug/L10550.0100.002.3475-125102Seleniumug/L10210.0100.00ND75-125102Silverug/L10110.0100.00ND75-125101Thalliumug/L1045.50100.00ND75-125104Vanadiumug/L10325.0100.00ND75-125103Zincug/L10310.0100.003.3675-125100Matrix Spike Dup (7020138-MSD1)Prepared: 02/06/17 Analyzed: 02/10/17 Source: AAA0880-01Antimonyug/L1116.00100.000.252075-1251113Arsenicug/L10410.0100.00ND2075-1251044Bariumug/L142100100.0038.02075-1251045Berylliumug/L1041.00100.00ND2075-1251044Page 17 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020138 - EPA 3005AMatrix Spike Dup (7020138-MSD1)Prepared: 02/06/17 Analyzed: 02/10/17 Source: AAA0880-01Cadmiumug/L1071.00100.00ND2075-1251072Chromiumug/L11310.0100.000.912075-1251127Cobaltug/L10410.0100.00ND2075-1251045Copperug/L10710.0100.00ND2075-1251076Leadug/L10510.0100.00ND2075-1251050.4Nickelug/L10750.0100.002.342075-1251052Seleniumug/L10310.0100.00ND2075-1251031Silverug/L10610.0100.00ND2075-1251064Thalliumug/L1075.50100.00ND2075-1251072Vanadiumug/L11025.0100.00ND2075-1251106Zincug/L11110.0100.003.362075-1251087Post Spike (7020138-PS1)Prepared: 02/06/17 Analyzed: 02/10/17 Source: AAA0880-01Antimonyug/L102100.000.2580-120101Arsenicug/L101100.00-0.3480-120101Bariumug/L143100.0038.080-120105Berylliumug/L104100.000.0680-120104Cadmiumug/L110100.000.0480-120110Chromiumug/L110100.000.9180-120109Cobaltug/L104100.000.0180-120104Copperug/L104100.00-0.0680-120104Leadug/L102100.000.0480-120102Nickelug/L105100.002.3480-120103Seleniumug/L101100.000.2580-120101Silverug/L103100.000.0280-120103Thalliumug/L104100.000.0580-120104Vanadiumug/L107100.00-0.6880-120107Zincug/L108100.003.3680-120104Page 18 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020138 - EPA 3005ABatch 7050099 - EPA 200.7Blank (7050099-BLK1)Prepared: 05/03/17 Analyzed: 05/04/17 Calciummg/LND1.00Magnesiummg/LND0.050LCS (7050099-BS1)Prepared: 05/03/17 Analyzed: 05/04/17 Calciummg/L1.021.001.000085-115102Magnesiummg/L1.050.0501.000085-115105Duplicate (7050099-DUP1)Prepared: 05/03/17 Analyzed: 05/04/17 Source: AAD1002-01Calciummg/LND1.00ND20Magnesiummg/L0.0080.0500.01520QR-0167Matrix Spike (7050099-MS1)Prepared: 05/03/17 Analyzed: 05/04/17 Source: AAE0050-01Calciummg/L2.501.001.00001.4270-130107Magnesiummg/L1.590.0501.00000.52570-130106Matrix Spike (7050099-MS2)Prepared: 05/03/17 Analyzed: 05/04/17 Source: AAE0055-01Calciummg/L4.261.001.00003.0970-130117Magnesiummg/L1.710.0501.00000.62370-130109Post Spike (7050099-PS1)Prepared: 05/03/17 Analyzed: 05/04/17 Source: AAE0050-01Calciummg/L2.511.00001.4285-115109Magnesiummg/L1.601.00000.52585-115107Page 19 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010680 - EPA 5030BBlank (7010680-BLK1)Prepared & Analyzed: 01/26/17 Acetoneug/LND100Acrylonitrileug/LND200Benzeneug/LND1.0Bromochloromethaneug/LND3.0Bromodichloromethaneug/LND1.0Bromoformug/LND3.0Bromomethaneug/LND10Carbon Disulfideug/LND100Carbon Tetrachlorideug/LND1.0Chlorobenzeneug/LND3.0Chloroethaneug/LND10Chloroformug/LND5.0Chloromethaneug/LND1.0Dibromochloromethaneug/LND3.01,2-Dibromo-3-chloropropaneug/LND131,2-Dibromoethaneug/LND1.0Dibromomethaneug/LND101,2-Dichlorobenzeneug/LND5.01,4-Dichlorobenzeneug/LND1.0trans-1,4-Dichloro-2-buteneug/LND1001,1-Dichloroethaneug/LND5.01,2-Dichloroethaneug/LND1.01,1-Dichloroetheneug/LND5.0cis-1,2-Dichloroetheneug/LND5.0trans-1,2-Dichloroetheneug/LND5.01,2-Dichloropropaneug/LND1.0cis-1,3-Dichloropropeneug/LND1.0Page 20 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010680 - EPA 5030BBlank (7010680-BLK1)Prepared & Analyzed: 01/26/17 trans-1,3-Dichloropropeneug/LND1.0Ethylbenzeneug/LND1.0Iodomethaneug/LND10Methyl Butyl Ketone (2-Hexanone)ug/LND50Methylene Chlorideug/LND1.0Methyl Ethyl Ketone (2-Butanone)ug/LND1004-Methyl-2-pentanone (MIBK)ug/LND100Styreneug/LND1.01,1,1,2-Tetrachloroethaneug/LND5.01,1,2,2-Tetrachloroethaneug/LND3.0Tetrachloroetheneug/LND1.0Tolueneug/LND1.01,1,1-Trichloroethaneug/LND1.01,1,2-Trichloroethaneug/LND1.0Trichloroetheneug/LND1.0Trichlorofluoromethaneug/LND1.01,2,3-Trichloropropaneug/LND1.0Vinyl Acetateug/LND50Vinyl Chlorideug/LND1.0Xylenes, totalug/LND5.0ug/L50.00080-120Surr: Dibromofluoromethane9346ug/L50.00078-120Surr: 1,2-Dichloroethane-d49648ug/L50.00080-120Surr: Toluene-d810352ug/L50.00080-120Surr: 4-Bromofluorobenzene10352LCS (7010680-BS1)Prepared & Analyzed: 01/26/17 Benzeneug/L4950.00067-13499Page 21 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010680 - EPA 5030BLCS (7010680-BS1)Prepared & Analyzed: 01/26/17 Chlorobenzeneug/L4950.00069-122981,1-Dichloroetheneug/L5450.00058-142108Tolueneug/L4550.00068-12791Trichloroetheneug/L4950.00072-13298ug/L50.00080-120Surr: Dibromofluoromethane9346ug/L50.00078-120Surr: 1,2-Dichloroethane-d49547ug/L50.00080-120Surr: Toluene-d810251ug/L50.00080-120Surr: 4-Bromofluorobenzene10251Matrix Spike (7010680-MS1)Prepared & Analyzed: 01/26/17 Source: AAA0860-02Benzeneug/L5850.0000.067-134116Chlorobenzeneug/L5550.0000.069-1221101,1-Dichloroetheneug/L6950.0000.058-142137Tolueneug/L5050.0000.068-127101Trichloroetheneug/L5650.0000.072-132113ug/L50.00080-120Surr: Dibromofluoromethane8844ug/L50.00078-120Surr: 1,2-Dichloroethane-d410151ug/L50.00080-120Surr: Toluene-d810150ug/L50.00080-120Surr: 4-Bromofluorobenzene10251Matrix Spike Dup (7010680-MSD1)Prepared & Analyzed: 01/26/17 Source: AAA0860-02Benzeneug/L5950.0000.0967-1341171Chlorobenzeneug/L5850.0000.01369-12211551,1-Dichloroetheneug/L6950.0000.0958-1421390.9Tolueneug/L5350.0000.0968-1271066Trichloroetheneug/L5850.0000.01172-1321163Page 22 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010680 - EPA 5030BMatrix Spike Dup (7010680-MSD1)Prepared & Analyzed: 01/26/17 Source: AAA0860-02ug/L50.00080-120Surr: Dibromofluoromethane9045ug/L50.00078-120Surr: 1,2-Dichloroethane-d410050ug/L50.00080-120Surr: Toluene-d810351ug/L50.00080-120Surr: 4-Bromofluorobenzene10352Page 23 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017Laboratory CertificationsCodeDescriptionNumberExpires812Georgia DW Inorganics Eff: 07/01/201606/30/2017GADW812Georgia DW Microbiology Eff: 07/01/201512/09/2019GADWM381North Carolina12/31/2017NCE87315FL DOH (Non-Pot. Water, Solids) Eff:: 07/01/201606/30/2017NELACE87315FL DOH NELAC (Drinking Water) Eff: 07/01/201606/30/2017NELDW98011001South Carolina06/30/2017SCT104704397-08-TXTexas03/31/2018TX460204Virginia12/14/2017VAPage 24 of 27
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMay 09, 2017LegendDefination of Laboratory Terms - Not Detected at levels greater than or equal to SWSL/RLNDSWSL/RLMDL - NC DENR Solid Waste Section LImit/Reporting Limit (Adjusted for DF/Prep Factor) - Method Detection LimitQualifiers - Dilution FactorDFQR-01RPD was outside acceptance limits due to sample concentrations near or below the reporting limit.JEstimated value less than Reporting Limit (RL) but greater than Method Detection Limit(MDL) (CLP J-Flag).B-01Analyte was detected in the associated method blank at an estimated level equal to or greater than the MDL. Sample values reported as greater than the MDL and less than 10x the method blank value are reported as estimated values.Note: Unless otherwise noted, all results are reported on an as received basis.Page 25 of 27
Page 26 of 27
LOG-IN CHECKLIST
Republic Services of North Carolina, LLC
East Carolina Regional LandfillProject:
Client:
Printed: 1/30/2017 11:37:22AM
Environmental Monitoring & Laboratory Analysis
[phone] FAX [phone]
110 Technology Parkway, Peachtree Corners, GA 30092
PACE ANALYTICAL SERVICES, LLC.
Date Received:01/26/17 09:20 Logged In By:Charles Hawks
Work Order:AAA0864
OBSERVATIONS
Attn: Mr. Matt Einsmann
#Samples: 3 #Containers: 12
2.0 2.0
YES
Minimum Temp(C):Maximum Temp(C):
CHECKLIST ITEMS
COC included with Samples
Sample Container(s) Intact
Chain of Custody Complete
Sample Container(s) Match COC
Custody seal Intact
Temperature in Compliance
Sufficient Sample Volume for Analysis
Zero Headspace Maintained for VOA Analyses
Samples labeled preserved (If Applicable)
Samples received within Allowable Hold Times
Samples Received on Ice
Preservation Confirmed
YES
YES
YES
N/A
YES
YES
YES
YES
YES
YES
YES
Custody Seal(s) Used:No
Comments:
Page 1 of 1Page 27 of 27
PACE ANALYTICAL SERVICES, LLC.Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]Republic Services of North Carolina, LLCProject: East Carolina Regional Landfill LeachateConover, NC 286131220 Commerce Street, SWMr. Matt EinsmannWe appreciate the opportunity to provide the analytical support for your project. The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Pace Analytical Services, LLC. certifies that the following analytical results meet all requirements of the National Environmental Laboratory Accreditation Conference(NELAC).All test results relate only to the samples analyzed.Laboratory ReportProject #:[none]Prepared For:Attention:February 20, 2017Report Number:AAA0852Approved:This report may not be reproduced, except in full, without written approval from Pace Analytical Services, LLC.Page 1 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017Sample IDLaboratory IDMatrixDate SampledANALYTICAL REPORT FOR SAMPLESDate Received0803-LeachateAAA0852-0101/25/17 14:23 01/26/17 09:20WaterPage 2 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-LeachateWaterAAA0852-01AAA085201/25/17 14:23Project:East Carolina Regional Landfill Leachate01/26/17 09:20General ChemistrySM 5210 B1220000ug/L5Biochemical Oxygen Demand680007010693SM 5210 B2.0E-1010602/01/17 08:1501/27/17 08:00SM 5220 D9020000ug/L20Chemical Oxygen Demand2000007020047EPA 410.4200E-1011702/02/17 16:1502/02/17 13:20NDEPA 9010C/9014ug/L1Cyanide, Total50.0R-047010727EPA 901050.057-12-501/29/17 15:0001/29/17 12:30EPA 1664B38000ug/L1Oil & Grease (HEM)17000OG-01, P-047020186EPA 166417000C-00702/08/17 07:5502/08/17 07:55EPA 420.14080ug/L5Total Phenols as Phenol2507010770EPA 420.1250E-1025301/31/17 16:3901/31/17 12:39SM 4500-P B,E3820ug/L1.11Phosphorus-Total0.227020144SM 4500-P B0.227723-14-002/09/17 18:4802/08/17 10:55EPA 351.21870000ug/L100Total Kjeldahl Nitrogen as N400007010687EPA 351.240000E-1026401/27/17 13:4701/27/17 07:25SM 2540 D230000ug/L1Total Suspended Solids200007010739SM 2540 D20000E-1016201/30/17 13:3501/30/17 13:35Inorganic AnionsNDEPA 9056Aug/L1Nitrate/Nitrite as N507010724EPA 9056A50E-1012801/26/17 17:5501/26/17 15:00NDEPA 9056Aug/L1Nitrate as N507010724EPA 9056A5014797-55-801/26/17 17:5501/26/17 15:00NDEPA 9056Aug/L50Nitrite as N2500H-04, R-017010724EPA 9056A25001594-56-502/14/17 02:2601/26/17 15:00EPA 9056A8200ug/L1Sulfate50007010724EPA 9056A5114808-79-801/26/17 17:5501/26/17 15:00Metals, TotalEPA 6020B60.4ug/L5Antimony30.07020138EPA 3005A1.257440-36-002/17/17 15:5202/06/17 18:25EPA 6020B238ug/L5Arsenic50.07020138EPA 3005A3.737440-38-202/17/17 15:5202/06/17 18:25EPA 6020B357ug/L5Barium1007020138EPA 3005A1.497440-39-302/17/17 15:5202/06/17 18:25NDEPA 6020Bug/L5Beryllium1.007020138EPA 3005A0.477440-41-702/17/17 15:5202/06/17 18:25NDEPA 6020Bug/L5Cadmium1.007020138EPA 3005A0.487440-43-902/17/17 15:5202/06/17 18:25EPA 6020B337ug/L5Chromium50.07020138EPA 3005A2.167440-47-302/17/17 15:5202/06/17 18:25Page 3 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-LeachateWaterAAA0852-01AAA085201/25/17 14:23Project:East Carolina Regional Landfill Leachate01/26/17 09:20Metals, TotalEPA 6020B35.3ug/L5Cobalt10.07020138EPA 3005A1.447440-48-402/17/17 15:5202/06/17 18:25EPA 6020B9.21ug/L5Copper10.0J7020138EPA 3005A2.047440-50-802/17/17 15:5202/06/17 18:25EPA 6020B8.09ug/L5Lead10.0J7020138EPA 3005A0.427439-92-102/17/17 15:5202/06/17 18:25EPA 6020B153ug/L5Nickel50.07020138EPA 3005A2.427440-02-002/17/17 15:5202/06/17 18:25EPA 6020B6.43ug/L5Selenium10.0J7020138EPA 3005A4.277782-49-202/17/17 15:5202/06/17 18:25NDEPA 6020Bug/L5Silver10.07020138EPA 3005A1.127440-22-402/17/17 15:5202/06/17 18:25NDEPA 6020Bug/L5Thallium5.507020138EPA 3005A0.287440-28-002/17/17 15:5202/06/17 18:25EPA 6020B180ug/L5Vanadium1257020138EPA 3005A7.867440-62-202/17/17 15:5202/06/17 18:25EPA 6020B470ug/L5Zinc50.0B-017020138EPA 3005A6.527440-66-602/17/17 15:5202/06/17 18:25NDEPA 7470Aug/L1Mercury0.2007020211EPA 7470A0.1327439-97-602/09/17 15:1302/09/17 10:35Volatile Organic Compounds by EPA 8260EPA 8260B20000ug/L100Acetone100007010604EPA 5030B82067-64-101/26/17 17:3901/26/17 10:00NDEPA 8260Bug/L1Acrylonitrile2007010604EPA 5030B2.5107-13-101/28/17 00:0801/26/17 10:00EPA 8260B3.7ug/L1Benzene1.07010604EPA 5030B0.271-43-201/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1Bromochloromethane3.07010604EPA 5030B0.574-97-501/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1Bromodichloromethane1.07010604EPA 5030B0.475-27-401/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1Bromoform3.07010604EPA 5030B0.675-25-201/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1Bromomethane107010604EPA 5030B1.074-83-901/28/17 00:0801/26/17 10:00EPA 8260B12ug/L1Carbon Disulfide100J7010604EPA 5030B0.875-15-001/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1Carbon Tetrachloride1.07010604EPA 5030B0.456-23-501/28/17 00:0801/26/17 10:00EPA 8260B0.6ug/L1Chlorobenzene3.0J7010604EPA 5030B0.5108-90-701/28/17 00:0801/26/17 10:00Page 4 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-LeachateWaterAAA0852-01AAA085201/25/17 14:23Project:East Carolina Regional Landfill Leachate01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Chloroethane107010604EPA 5030B0.575-00-301/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1Chloroform5.07010604EPA 5030B0.667-66-301/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1Chloromethane1.07010604EPA 5030B0.474-87-301/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1Dibromochloromethane3.07010604EPA 5030B0.3124-48-101/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010604EPA 5030B0.696-12-801/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L11,2-Dibromoethane1.07010604EPA 5030B0.3106-93-401/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1Dibromomethane107010604EPA 5030B0.674-95-301/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010604EPA 5030B0.595-50-101/28/17 00:0801/26/17 10:00EPA 8260B8.6ug/L11,4-Dichlorobenzene1.07010604EPA 5030B0.6106-46-701/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010604EPA 5030B1.6110-57-601/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L11,1-Dichloroethane5.07010604EPA 5030B0.475-34-301/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L11,2-Dichloroethane1.07010604EPA 5030B0.7107-06-201/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L11,1-Dichloroethene5.07010604EPA 5030B0.775-35-401/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010604EPA 5030B0.7156-59-201/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010604EPA 5030B0.5156-60-501/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L11,2-Dichloropropane1.07010604EPA 5030B0.678-87-501/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010604EPA 5030B0.210061-01-501/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010604EPA 5030B0.310061-02-601/28/17 00:0801/26/17 10:00EPA 8260B19ug/L1Ethylbenzene1.07010604EPA 5030B0.4100-41-401/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1Iodomethane107010604EPA 5030B3.174-88-401/28/17 00:0801/26/17 10:00EPA 8260B68ug/L1Methyl Butyl Ketone (2-Hexanone)507010604EPA 5030B0.9591-78-601/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1Methylene Chloride1.07010604EPA 5030B0.575-09-201/28/17 00:0801/26/17 10:00Page 5 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-LeachateWaterAAA0852-01AAA085201/25/17 14:23Project:East Carolina Regional Landfill Leachate01/26/17 09:20Volatile Organic Compounds by EPA 8260EPA 8260B16000ug/L100Methyl Ethyl Ketone (2-Butanone)100007010604EPA 5030B32078-93-301/26/17 17:3901/26/17 10:00EPA 8260B390ug/L1004-Methyl-2-pentanone (MIBK)2007010604EPA 5030B86108-10-101/26/17 17:3901/26/17 10:00EPA 8260B1.4ug/L1Styrene1.07010604EPA 5030B0.5100-42-501/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010604EPA 5030B0.3630-20-601/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010604EPA 5030B0.579-34-501/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1Tetrachloroethene1.07010604EPA 5030B0.8127-18-401/28/17 00:0801/26/17 10:00EPA 8260B24ug/L1Toluene1.07010604EPA 5030B0.3108-88-301/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010604EPA 5030B0.471-55-601/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010604EPA 5030B0.679-00-501/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1Trichloroethene1.07010604EPA 5030B0.379-01-601/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1Trichlorofluoromethane1.07010604EPA 5030B0.575-69-401/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010604EPA 5030B0.596-18-401/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1Vinyl Acetate507010604EPA 5030B0.4108-05-401/28/17 00:0801/26/17 10:00NDEPA 8260Bug/L1Vinyl Chloride1.07010604EPA 5030B0.675-01-401/28/17 00:0801/26/17 10:00EPA 8260B42ug/L1Xylenes, total5.07010604EPA 5030B1.41330-20-701/28/17 00:0801/26/17 10:00EPA 8260B95 %Surr: Dibromofluoromethane7010604EPA 5030B1868-53-701/26/17 17:3901/26/17 10:0080-120EPA 8260B90 %Surr: Dibromofluoromethane7010604EPA 5030B1868-53-701/28/17 00:0801/26/17 10:0080-120EPA 8260B97 %Surr: 1,2-Dichloroethane-d47010604EPA 5030B17060-07-001/28/17 00:0801/26/17 10:0078-120EPA 8260B95 %Surr: 1,2-Dichloroethane-d47010604EPA 5030B17060-07-001/26/17 17:3901/26/17 10:0078-120EPA 8260B94 %Surr: Toluene-d87010604EPA 5030B2037-26-501/26/17 17:3901/26/17 10:0080-120EPA 8260B101 %Surr: Toluene-d87010604EPA 5030B2037-26-501/28/17 00:0801/26/17 10:0080-120Page 6 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-LeachateWaterAAA0852-01AAA085201/25/17 14:23Project:East Carolina Regional Landfill Leachate01/26/17 09:20Volatile Organic Compounds by EPA 8260EPA 8260B104 %Surr: 4-Bromofluorobenzene7010604EPA 5030B460-00-401/28/17 00:0801/26/17 10:0080-120EPA 8260B105 %Surr: 4-Bromofluorobenzene7010604EPA 5030B460-00-401/26/17 17:3901/26/17 10:0080-120Page 7 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteGeneral Chemistry - Quality ControlBatch 7010687 - EPA 351.2Blank (7010687-BLK1)Prepared & Analyzed: 01/27/17 Total Kjeldahl Nitrogen as Nug/LND400LCS (7010687-BS1)Prepared & Analyzed: 01/27/17 Total Kjeldahl Nitrogen as Nug/L105004001000090-110105Matrix Spike (7010687-MS1)Prepared & Analyzed: 01/27/17 Source: AAA0755-02Total Kjeldahl Nitrogen as Nug/L103004001000054090-11098Matrix Spike (7010687-MS2)Prepared & Analyzed: 01/27/17 Source: AAA0755-03Total Kjeldahl Nitrogen as Nug/L1070040010000ND90-110107Batch 7010693 - SM 5210 BBlank (7010693-BLK1)Prepared: 01/27/17 Analyzed: 02/01/17 Biochemical Oxygen Demandug/LND2000LCS (7010693-BS1)Prepared: 01/27/17 Analyzed: 02/01/17 Biochemical Oxygen Demandug/L183000200019800085-11592Duplicate (7010693-DUP1)Prepared: 01/27/17 Analyzed: 02/01/17 Source: AAA0842-01Biochemical Oxygen Demandug/L2020002000ND20BOD-2Batch 7010727 - EPA 9010Blank (7010727-BLK1)Prepared & Analyzed: 01/29/17 Cyanide, Totalug/LND10.0Page 8 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteGeneral Chemistry - Quality ControlBatch 7010727 - EPA 9010LCS (7010727-BS1)Prepared & Analyzed: 01/29/17 Cyanide, Totalug/L87.010.080.00085-115109Duplicate (7010727-DUP1)Prepared & Analyzed: 01/29/17 Source: AAA0718-05RE1Cyanide, Totalug/L18.010.019.0205Matrix Spike (7010727-MS1)Prepared & Analyzed: 01/29/17 Source: AAA0913-02Cyanide, Totalug/L84.010.080.00034.0QM-0585-11962Matrix Spike Dup (7010727-MSD1)Prepared & Analyzed: 01/29/17 Source: AAA0913-02Cyanide, Totalug/L82.010.080.00034.013QM-0585-119602Batch 7010739 - SM 2540 DBlank (7010739-BLK1)Prepared & Analyzed: 01/30/17 Total Suspended Solidsug/LND5000LCS (7010739-BS1)Prepared & Analyzed: 01/30/17 Total Suspended Solidsug/L95500500010000090-11096Duplicate (7010739-DUP1)Prepared & Analyzed: 01/30/17 Source: AAA0852-01Total Suspended Solidsug/L24600020000230000107Batch 7010770 - EPA 420.1Blank (7010770-BLK1)Prepared & Analyzed: 01/31/17 Total Phenols as Phenolug/LND50.0Page 9 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteGeneral Chemistry - Quality ControlBatch 7010770 - EPA 420.1LCS (7010770-BS1)Prepared & Analyzed: 01/31/17 Total Phenols as Phenolug/L49350.0500.0080-12099Matrix Spike (7010770-MS1)Prepared & Analyzed: 01/31/17 Source: AAA0757-01Total Phenols as Phenolug/L47050.0500.00ND80-12094Matrix Spike Dup (7010770-MSD1)Prepared & Analyzed: 01/31/17 Source: AAA0757-01Total Phenols as Phenolug/L46050.0500.00ND2080-120922Batch 7020047 - EPA 410.4Blank (7020047-BLK1)Prepared & Analyzed: 02/02/17 Chemical Oxygen Demandug/LND10000LCS (7020047-BS1)Prepared & Analyzed: 02/02/17 Chemical Oxygen Demandug/L2080001000020000090-110104Matrix Spike (7020047-MS1)Prepared & Analyzed: 02/02/17 Source: AAA0945-01Chemical Oxygen Demandug/L20400010000200000ND90-110102Matrix Spike (7020047-MS2)Prepared & Analyzed: 02/02/17 Source: AAA0979-01Chemical Oxygen Demandug/L46100010000200000460000QM-0590-1100.3Matrix Spike Dup (7020047-MSD1)Prepared & Analyzed: 02/02/17 Source: AAA0945-01Chemical Oxygen Demandug/L20000010000200000ND1090-1101002Batch 7020144 - SM 4500-P BBlank (7020144-BLK1)Prepared: 02/08/17 Analyzed: 02/09/17 Phosphorus-Totalug/LND20.0Page 10 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteGeneral Chemistry - Quality ControlBatch 7020144 - SM 4500-P BLCS (7020144-BS1)Prepared: 02/08/17 Analyzed: 02/09/17 Phosphorus-Totalug/L47020.0500.0088-11094Matrix Spike (7020144-MS1)Prepared: 02/08/17 Analyzed: 02/09/17 Source: AAB0043-26Phosphorus-Totalug/L58120.0500.0027.072-123111Matrix Spike Dup (7020144-MSD1)Prepared: 02/08/17 Analyzed: 02/09/17 Source: AAB0043-26Phosphorus-Totalug/L57720.0500.0027.01172-1231100.7Batch 7020186 - EPA 1664Blank (7020186-BLK1)Prepared & Analyzed: 02/08/17 Oil & Grease (HEM)ug/LND5000LCS (7020186-BS1)Prepared & Analyzed: 02/08/17 Oil & Grease (HEM)ug/L3800050004000078-11496Duplicate (7020186-DUP1)Prepared & Analyzed: 02/08/17 Source: AAB0063-01Oil & Grease (HEM)ug/L360005400460007523Matrix Spike (7020186-MS1)Prepared & Analyzed: 02/08/17 Source: AAB0096-02Oil & Grease (HEM)ug/L3000054004301115000QM-0578-11435Page 11 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteInorganic Anions - Quality ControlBatch 7010724 - EPA 9056ABlank (7010724-BLK1)Prepared & Analyzed: 01/26/17 Nitrate/Nitrite as Nug/LND50Nitrate as Nug/LND50Nitrite as Nug/LND50Sulfateug/LND5000LCS (7010724-BS1)Prepared & Analyzed: 01/26/17 Nitrate/Nitrite as Nug/L21100502000090-110106Nitrate as Nug/L10500501002090-110105Nitrite as Nug/L10700501000090-110107Sulfateug/L1070050001002090-110106Matrix Spike (7010724-MS1)Prepared & Analyzed: 01/26/17 Source: AAA0852-01Nitrate/Nitrite as Nug/L20600005020000NDQM-0590-1100Nitrate as Nug/L105005010020ND90-110105Nitrite as Nug/L205000050100002560000QM-0590-1100Sulfateug/L151005000100208190QM-0290-11069Matrix Spike Dup (7010724-MSD1)Prepared & Analyzed: 01/26/17 Source: AAA0852-01Nitrate/Nitrite as Nug/L20700005020000ND15QM-0590-11000.5Nitrate as Nug/L104005010020ND1590-1101031Nitrite as Nug/L20600005010000256000015QM-0590-11000.5Sulfateug/L15100500010020819015QM-0290-110690.1Page 12 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020138 - EPA 3005ABlank (7020138-BLK1)Prepared: 02/06/17 Analyzed: 02/10/17 Antimonyug/LND6.00Arsenicug/LND10.0Bariumug/LND100Berylliumug/LND1.00Cadmiumug/LND1.00Chromiumug/LND10.0Cobaltug/LND10.0Copperug/LND10.0Leadug/LND10.0Nickelug/LND50.0Seleniumug/LND10.0Silverug/LND10.0Thalliumug/LND5.50Vanadiumug/LND25.0Zincug/L1.7710.0JLCS (7020138-BS1)Prepared: 02/06/17 Analyzed: 02/10/17 Antimonyug/L1096.00100.0080-120109Arsenicug/L10210.0100.0080-120102Bariumug/L99.4100100.00J80-12099Berylliumug/L1011.00100.0080-120101Cadmiumug/L1081.00100.0080-120108Chromiumug/L10610.0100.0080-120106Cobaltug/L98.510.0100.0080-12098Copperug/L10110.0100.0080-120101Leadug/L10410.0100.0080-120104Nickelug/L99.650.0100.0080-120100Seleniumug/L10310.0100.0080-120103Page 13 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020138 - EPA 3005ALCS (7020138-BS1)Prepared: 02/06/17 Analyzed: 02/10/17 Silverug/L10210.0100.0080-120102Thalliumug/L1065.50100.0080-120106Vanadiumug/L10525.0100.0080-120105Zincug/L10710.0100.0080-120107Matrix Spike (7020138-MS1)Prepared: 02/06/17 Analyzed: 02/10/17 Source: AAA0880-01Antimonyug/L1086.00100.000.2575-125107Arsenicug/L10010.0100.00ND75-125100Bariumug/L136100100.0038.075-12598Berylliumug/L99.21.00100.00ND75-12599Cadmiumug/L1041.00100.00ND75-125104Chromiumug/L10510.0100.000.9175-125104Cobaltug/L99.210.0100.00ND75-12599Copperug/L10010.0100.00ND75-125100Leadug/L10510.0100.00ND75-125105Nickelug/L10550.0100.002.3475-125102Seleniumug/L10210.0100.00ND75-125102Silverug/L10110.0100.00ND75-125101Thalliumug/L1045.50100.00ND75-125104Vanadiumug/L10325.0100.00ND75-125103Zincug/L10310.0100.003.3675-125100Matrix Spike Dup (7020138-MSD1)Prepared: 02/06/17 Analyzed: 02/10/17 Source: AAA0880-01Antimonyug/L1116.00100.000.252075-1251113Arsenicug/L10410.0100.00ND2075-1251044Bariumug/L142100100.0038.02075-1251045Berylliumug/L1041.00100.00ND2075-1251044Cadmiumug/L1071.00100.00ND2075-1251072Page 14 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020138 - EPA 3005AMatrix Spike Dup (7020138-MSD1)Prepared: 02/06/17 Analyzed: 02/10/17 Source: AAA0880-01Chromiumug/L11310.0100.000.912075-1251127Cobaltug/L10410.0100.00ND2075-1251045Copperug/L10710.0100.00ND2075-1251076Leadug/L10510.0100.00ND2075-1251050.4Nickelug/L10750.0100.002.342075-1251052Seleniumug/L10310.0100.00ND2075-1251031Silverug/L10610.0100.00ND2075-1251064Thalliumug/L1075.50100.00ND2075-1251072Vanadiumug/L11025.0100.00ND2075-1251106Zincug/L11110.0100.003.362075-1251087Post Spike (7020138-PS1)Prepared: 02/06/17 Analyzed: 02/10/17 Source: AAA0880-01Antimonyug/L102100.000.2580-120101Arsenicug/L101100.00-0.3480-120101Bariumug/L143100.0038.080-120105Berylliumug/L104100.000.0680-120104Cadmiumug/L110100.000.0480-120110Chromiumug/L110100.000.9180-120109Cobaltug/L104100.000.0180-120104Copperug/L104100.00-0.0680-120104Leadug/L102100.000.0480-120102Nickelug/L105100.002.3480-120103Seleniumug/L101100.000.2580-120101Silverug/L103100.000.0280-120103Thalliumug/L104100.000.0580-120104Vanadiumug/L107100.00-0.6880-120107Zincug/L108100.003.3680-120104Page 15 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020211 - EPA 7470ABlank (7020211-BLK1)Prepared & Analyzed: 02/09/17 Mercuryug/LND0.200LCS (7020211-BS1)Prepared & Analyzed: 02/09/17 Mercuryug/L2.420.2002.500080-12097Matrix Spike (7020211-MS1)Prepared & Analyzed: 02/09/17 Source: AAB0083-13Mercuryug/L1.960.2002.5000ND75-12578Matrix Spike Dup (7020211-MSD1)Prepared & Analyzed: 02/09/17 Source: AAB0083-13Mercuryug/L1.920.2002.5000ND2075-125772Post Spike (7020211-PS1)Prepared & Analyzed: 02/09/17 Source: AAB0083-13Mercuryug/L1.321.66670.037QM-0580-12077Page 16 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010604 - EPA 5030BBlank (7010604-BLK1)Prepared & Analyzed: 01/26/17 Acetoneug/L14100JAcrylonitrileug/LND200Benzeneug/LND1.0Bromochloromethaneug/LND3.0Bromodichloromethaneug/LND1.0Bromoformug/LND3.0Bromomethaneug/LND10Carbon Disulfideug/LND100Carbon Tetrachlorideug/LND1.0Chlorobenzeneug/LND3.0Chloroethaneug/LND10Chloroformug/LND5.0Chloromethaneug/LND1.0Dibromochloromethaneug/LND3.01,2-Dibromo-3-chloropropaneug/LND131,2-Dibromoethaneug/LND1.0Dibromomethaneug/LND101,2-Dichlorobenzeneug/LND5.01,4-Dichlorobenzeneug/LND1.0trans-1,4-Dichloro-2-buteneug/LND1001,1-Dichloroethaneug/LND5.01,2-Dichloroethaneug/LND1.01,1-Dichloroetheneug/LND5.0cis-1,2-Dichloroetheneug/LND5.0trans-1,2-Dichloroetheneug/LND5.01,2-Dichloropropaneug/LND1.0cis-1,3-Dichloropropeneug/LND1.0Page 17 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010604 - EPA 5030BBlank (7010604-BLK1)Prepared & Analyzed: 01/26/17 trans-1,3-Dichloropropeneug/LND1.0Ethylbenzeneug/LND1.0Iodomethaneug/LND10Methyl Butyl Ketone (2-Hexanone)ug/LND50Methylene Chlorideug/LND1.0Methyl Ethyl Ketone (2-Butanone)ug/LND1004-Methyl-2-pentanone (MIBK)ug/LND100Styreneug/LND1.01,1,1,2-Tetrachloroethaneug/LND5.01,1,2,2-Tetrachloroethaneug/LND3.0Tetrachloroetheneug/LND1.0Tolueneug/LND1.01,1,1-Trichloroethaneug/LND1.01,1,2-Trichloroethaneug/LND1.0Trichloroetheneug/LND1.0Trichlorofluoromethaneug/LND1.01,2,3-Trichloropropaneug/LND1.0Vinyl Acetateug/LND50Vinyl Chlorideug/LND1.0Xylenes, totalug/LND5.0ug/L50.00080-120Surr: Dibromofluoromethane9246ug/L50.00078-120Surr: 1,2-Dichloroethane-d49547ug/L50.00080-120Surr: Toluene-d89447ug/L50.00080-120Surr: 4-Bromofluorobenzene10050LCS (7010604-BS1)Prepared & Analyzed: 01/26/17 Benzeneug/L561.050.00067-134112Page 18 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010604 - EPA 5030BLCS (7010604-BS1)Prepared & Analyzed: 01/26/17 Chlorobenzeneug/L473.050.00069-122951,1-Dichloroetheneug/L605.050.00058-142121Tolueneug/L541.050.00068-127108Trichloroetheneug/L511.050.00072-132102ug/L50.00080-120Surr: Dibromofluoromethane10251ug/L50.00078-120Surr: 1,2-Dichloroethane-d49648ug/L50.00080-120Surr: Toluene-d89547ug/L50.00080-120Surr: 4-Bromofluorobenzene10251Matrix Spike (7010604-MS1)Prepared & Analyzed: 01/26/17 Source: AAA0672-01Benzeneug/L551.050.000ND67-134110Chlorobenzeneug/L473.050.000ND69-122931,1-Dichloroetheneug/L605.050.000ND58-142119Tolueneug/L531.050.000ND68-127106Trichloroetheneug/L511.050.000ND72-132102ug/L50.00080-120Surr: Dibromofluoromethane10352ug/L50.00078-120Surr: 1,2-Dichloroethane-d49447ug/L50.00080-120Surr: Toluene-d89648ug/L50.00080-120Surr: 4-Bromofluorobenzene10151Matrix Spike Dup (7010604-MSD1)Prepared & Analyzed: 01/26/17 Source: AAA0672-01Benzeneug/L561.050.000ND967-1341122Chlorobenzeneug/L483.050.000ND1369-1229631,1-Dichloroetheneug/L605.050.000ND958-1421190.2Tolueneug/L551.050.000ND968-1271094Trichloroetheneug/L501.050.000ND1172-132992Page 19 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010604 - EPA 5030BMatrix Spike Dup (7010604-MSD1)Prepared & Analyzed: 01/26/17 Source: AAA0672-01ug/L50.00080-120Surr: Dibromofluoromethane10452ug/L50.00078-120Surr: 1,2-Dichloroethane-d49547ug/L50.00080-120Surr: Toluene-d89547ug/L50.00080-120Surr: 4-Bromofluorobenzene10050Page 20 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017Laboratory CertificationsCodeDescriptionNumberExpires812Georgia DW Inorganics Eff: 07/01/201606/30/2017GADW812Georgia DW Microbiology Eff: 07/01/201503/09/2017GADWM381North Carolina12/31/2017NCE87315FL DOH (Non-Pot. Water, Solids) Eff:: 07/01/201606/30/2017NELACE87315FL DOH NELAC (Drinking Water) Eff: 07/01/201606/30/2017NELDW98011001South Carolina06/30/2017SCT104704397-08-TXTexas03/31/2017TX1340Virginia12/14/2017VAPage 21 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017LegendDefination of Laboratory Terms - Not Detected at levels greater than or equal to SWSL/RLNDSWSL/RLMDL - NC DENR Solid Waste Section LImit/Reporting Limit (Adjusted for DF/Prep Factor) - Method Detection LimitQualifiers - Dilution FactorDFR-04Elevated reporting limit due to sample foaming.R-01Elevated reporting limit due to matrix interference.QM-05The spike recovery was outside acceptance limits for the MS and/or MSD and/or PDS due to suspected matrix interference. Sample results for the QC batch were accepted based on acceptable LCS recoveries.QM-02The spike recovery is outside acceptance limits due to insignificant spike amount as compared to sample concentration.P-04Sample was received preserved with proper preservative and pH within method specified limits but, due to sample matrix buffering during storage, required further adjustment prior to extraction and/or analysis.OG-01Due to matrix interference, analysis was performed on a subsample of the original container received.JEstimated value less than Reporting Limit (RL) but greater than Method Detection Limit(MDL) (CLP J-Flag).H-04Sample dilution was analyzed outside holding time. Sample was originally analyzed within holding time but required further dilution.BOD-2Dilutions selected for BOD analysis based on screening COD value failed to meet the criteria of a residual dissolved oxygen of at least 1 mg/L (overdepleted). Result is reported as an estimated value > or equal to the value reported.Page 22 of 25
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017LegendDefination of Laboratory Terms - Not Detected at levels greater than or equal to SWSL/RLNDSWSL/RLMDL - NC DENR Solid Waste Section LImit/Reporting Limit (Adjusted for DF/Prep Factor) - Method Detection LimitQualifiers - Dilution FactorDFB-01Analyte was detected in the associated method blank at an estimated level equal to or greater than the MDL. Sample values reported as greater than the MDL and less than 10x the method blank value are reported as estimated values.Note: Unless otherwise noted, all results are reported on an as received basis.Page 23 of 25
Page 24 of 25
LOG-IN CHECKLIST
Republic Services of North Carolina, LLC
East Carolina Regional Landfill LeachateProject:
Client:
Printed: 1/30/2017 9:39:52AM
Environmental Monitoring & Laboratory Analysis
[phone] FAX [phone]
110 Technology Parkway, Peachtree Corners, GA 30092
PACE ANALYTICAL SERVICES, LLC.
Date Received:01/26/17 09:20 Logged In By:Charles Hawks
Work Order:AAA0852
OBSERVATIONS
Attn: Mr. Matt Einsmann
#Samples: 1 #Containers: 12
2.0 2.0
YES
Minimum Temp(C):Maximum Temp(C):
CHECKLIST ITEMS
COC included with Samples
Sample Container(s) Intact
Chain of Custody Complete
Sample Container(s) Match COC
Custody seal Intact
Temperature in Compliance
Sufficient Sample Volume for Analysis
Zero Headspace Maintained for VOA Analyses
Samples labeled preserved (If Applicable)
Samples received within Allowable Hold Times
Samples Received on Ice
Preservation Confirmed
YES
YES
YES
N/A
YES
YES
YES
YES
YES
YES
YES
Custody Seal(s) Used:No
The Phenols/COD/NO3+NO2, Mets and O/G were pH adjusted from 7 to <2 with H2SO4, HNO3 and HCL respectively.
CFH
Comments:
Page 1 of 1Page 25 of 25
PACE ANALYTICAL SERVICES, LLC.Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]Republic Services of North Carolina, LLCProject: East Carolina Regional LandfillConover, NC 286131220 Commerce Street, SWMr. Matt EinsmannWe appreciate the opportunity to provide the analytical support for your project. The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Pace Analytical Services, LLC. certifies that the following analytical results meet all requirements of the National Environmental Laboratory Accreditation Conference(NELAC).All test results relate only to the samples analyzed.Laboratory ReportProject #:[none]Prepared For:Attention:February 20, 2017Report Number:AAA0863Approved:This report may not be reproduced, except in full, without written approval from Pace Analytical Services, LLC.Page 1 of 21
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017Sample IDLaboratory IDMatrixDate SampledANALYTICAL REPORT FOR SAMPLESDate Received0803-Field BlankAAA0863-0101/25/17 14:40 01/26/17 09:20Water0803-Trip BlankAAA0863-0201/24/17 15:30 01/26/17 09:20WaterPage 2 of 21
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-Field BlankWaterAAA0863-01AAA086301/25/17 14:40Project:East Carolina Regional Landfill01/26/17 09:20Metals, TotalNDEPA 6020Bug/L1Antimony6.007020138EPA 3005A0.257440-36-002/10/17 05:4202/06/17 18:25NDEPA 6020Bug/L1Arsenic10.07020138EPA 3005A0.757440-38-202/10/17 05:4202/06/17 18:25EPA 6020B0.30ug/L1Barium100J7020138EPA 3005A0.307440-39-302/10/17 05:4202/06/17 18:25NDEPA 6020Bug/L1Beryllium1.007020138EPA 3005A0.097440-41-702/10/17 05:4202/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020138EPA 3005A0.107440-43-902/10/17 05:4202/06/17 18:25NDEPA 6020Bug/L1Chromium10.07020138EPA 3005A0.437440-47-302/10/17 05:4202/06/17 18:25NDEPA 6020Bug/L1Cobalt10.07020138EPA 3005A0.297440-48-402/10/17 05:4202/06/17 18:25EPA 6020B0.59ug/L1Copper10.0J7020138EPA 3005A0.417440-50-802/10/17 05:4202/06/17 18:25NDEPA 6020Bug/L1Lead10.07020138EPA 3005A0.087439-92-102/10/17 05:4202/06/17 18:25NDEPA 6020Bug/L1Nickel50.07020138EPA 3005A0.487440-02-002/10/17 05:4202/06/17 18:25NDEPA 6020Bug/L1Selenium10.07020138EPA 3005A0.857782-49-202/10/17 05:4202/06/17 18:25NDEPA 6020Bug/L1Silver10.07020138EPA 3005A0.227440-22-402/10/17 05:4202/06/17 18:25NDEPA 6020Bug/L1Thallium5.507020138EPA 3005A0.067440-28-002/10/17 05:4202/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020138EPA 3005A1.577440-62-202/10/17 05:4202/06/17 18:25EPA 6020B2.13ug/L1Zinc10.0B-01, J7020138EPA 3005A1.307440-66-602/10/17 05:4202/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010680EPA 5030B8.267-64-101/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Acrylonitrile2007010680EPA 5030B2.5107-13-101/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Benzene1.07010680EPA 5030B0.271-43-201/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Bromochloromethane3.07010680EPA 5030B0.574-97-501/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Bromodichloromethane1.07010680EPA 5030B0.475-27-401/26/17 13:5301/26/17 12:15Page 3 of 21
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-Field BlankWaterAAA0863-01AAA086301/25/17 14:40Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromoform3.07010680EPA 5030B0.675-25-201/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Bromomethane107010680EPA 5030B1.074-83-901/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Carbon Disulfide1007010680EPA 5030B0.875-15-001/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Carbon Tetrachloride1.07010680EPA 5030B0.456-23-501/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Chlorobenzene3.07010680EPA 5030B0.5108-90-701/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Chloroethane107010680EPA 5030B0.575-00-301/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Chloroform5.07010680EPA 5030B0.667-66-301/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Chloromethane1.07010680EPA 5030B0.474-87-301/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Dibromochloromethane3.07010680EPA 5030B0.3124-48-101/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010680EPA 5030B0.696-12-801/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L11,2-Dibromoethane1.07010680EPA 5030B0.3106-93-401/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Dibromomethane107010680EPA 5030B0.674-95-301/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010680EPA 5030B0.595-50-101/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010680EPA 5030B0.6106-46-701/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010680EPA 5030B1.6110-57-601/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethane5.07010680EPA 5030B0.475-34-301/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L11,2-Dichloroethane1.07010680EPA 5030B0.7107-06-201/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethene5.07010680EPA 5030B0.775-35-401/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010680EPA 5030B0.7156-59-201/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010680EPA 5030B0.5156-60-501/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L11,2-Dichloropropane1.07010680EPA 5030B0.678-87-501/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010680EPA 5030B0.210061-01-501/26/17 13:5301/26/17 12:15Page 4 of 21
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-Field BlankWaterAAA0863-01AAA086301/25/17 14:40Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010680EPA 5030B0.310061-02-601/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Ethylbenzene1.07010680EPA 5030B0.4100-41-401/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Iodomethane107010680EPA 5030B3.174-88-401/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010680EPA 5030B0.9591-78-601/26/17 13:5301/26/17 12:15EPA 8260B2.1ug/L1Methylene Chloride1.07010680EPA 5030B0.575-09-201/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010680EPA 5030B3.278-93-301/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010680EPA 5030B0.9108-10-101/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Styrene1.07010680EPA 5030B0.5100-42-501/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010680EPA 5030B0.3630-20-601/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010680EPA 5030B0.579-34-501/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Tetrachloroethene1.07010680EPA 5030B0.8127-18-401/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Toluene1.07010680EPA 5030B0.3108-88-301/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010680EPA 5030B0.471-55-601/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010680EPA 5030B0.679-00-501/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Trichloroethene1.07010680EPA 5030B0.379-01-601/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Trichlorofluoromethane1.07010680EPA 5030B0.575-69-401/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010680EPA 5030B0.596-18-401/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Vinyl Acetate507010680EPA 5030B0.4108-05-401/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Vinyl Chloride1.07010680EPA 5030B0.675-01-401/26/17 13:5301/26/17 12:15NDEPA 8260Bug/L1Xylenes, total5.07010680EPA 5030B1.41330-20-701/26/17 13:5301/26/17 12:15EPA 8260B91 %Surr: Dibromofluoromethane7010680EPA 5030B1868-53-701/26/17 13:5301/26/17 12:1580-120Page 5 of 21
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-Field BlankWaterAAA0863-01AAA086301/25/17 14:40Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260EPA 8260B96 %Surr: 1,2-Dichloroethane-d47010680EPA 5030B17060-07-001/26/17 13:5301/26/17 12:1578-120EPA 8260B104 %Surr: Toluene-d87010680EPA 5030B2037-26-501/26/17 13:5301/26/17 12:1580-120EPA 8260B106 %Surr: 4-Bromofluorobenzene7010680EPA 5030B460-00-401/26/17 13:5301/26/17 12:1580-120Page 6 of 21
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-Trip BlankWaterAAA0863-02AAA086301/24/17 15:30Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010680EPA 5030B8.267-64-101/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Acrylonitrile2007010680EPA 5030B2.5107-13-101/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Benzene1.07010680EPA 5030B0.271-43-201/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Bromochloromethane3.07010680EPA 5030B0.574-97-501/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Bromodichloromethane1.07010680EPA 5030B0.475-27-401/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Bromoform3.07010680EPA 5030B0.675-25-201/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Bromomethane107010680EPA 5030B1.074-83-901/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Carbon Disulfide1007010680EPA 5030B0.875-15-001/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Carbon Tetrachloride1.07010680EPA 5030B0.456-23-501/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Chlorobenzene3.07010680EPA 5030B0.5108-90-701/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Chloroethane107010680EPA 5030B0.575-00-301/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Chloroform5.07010680EPA 5030B0.667-66-301/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Chloromethane1.07010680EPA 5030B0.474-87-301/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Dibromochloromethane3.07010680EPA 5030B0.3124-48-101/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010680EPA 5030B0.696-12-801/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L11,2-Dibromoethane1.07010680EPA 5030B0.3106-93-401/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Dibromomethane107010680EPA 5030B0.674-95-301/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010680EPA 5030B0.595-50-101/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010680EPA 5030B0.6106-46-701/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010680EPA 5030B1.6110-57-601/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L11,1-Dichloroethane5.07010680EPA 5030B0.475-34-301/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L11,2-Dichloroethane1.07010680EPA 5030B0.7107-06-201/26/17 13:2801/26/17 12:15Page 7 of 21
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-Trip BlankWaterAAA0863-02AAA086301/24/17 15:30Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,1-Dichloroethene5.07010680EPA 5030B0.775-35-401/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010680EPA 5030B0.7156-59-201/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010680EPA 5030B0.5156-60-501/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L11,2-Dichloropropane1.07010680EPA 5030B0.678-87-501/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010680EPA 5030B0.210061-01-501/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010680EPA 5030B0.310061-02-601/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Ethylbenzene1.07010680EPA 5030B0.4100-41-401/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Iodomethane107010680EPA 5030B3.174-88-401/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010680EPA 5030B0.9591-78-601/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Methylene Chloride1.07010680EPA 5030B0.575-09-201/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010680EPA 5030B3.278-93-301/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010680EPA 5030B0.9108-10-101/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Styrene1.07010680EPA 5030B0.5100-42-501/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010680EPA 5030B0.3630-20-601/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010680EPA 5030B0.579-34-501/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Tetrachloroethene1.07010680EPA 5030B0.8127-18-401/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Toluene1.07010680EPA 5030B0.3108-88-301/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010680EPA 5030B0.471-55-601/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010680EPA 5030B0.679-00-501/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Trichloroethene1.07010680EPA 5030B0.379-01-601/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Trichlorofluoromethane1.07010680EPA 5030B0.575-69-401/26/17 13:2801/26/17 12:15Page 8 of 21
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-Trip BlankWaterAAA0863-02AAA086301/24/17 15:30Project:East Carolina Regional Landfill01/26/17 09:20Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010680EPA 5030B0.596-18-401/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Vinyl Acetate507010680EPA 5030B0.4108-05-401/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Vinyl Chloride1.07010680EPA 5030B0.675-01-401/26/17 13:2801/26/17 12:15NDEPA 8260Bug/L1Xylenes, total5.07010680EPA 5030B1.41330-20-701/26/17 13:2801/26/17 12:15EPA 8260B89 %Surr: Dibromofluoromethane7010680EPA 5030B1868-53-701/26/17 13:2801/26/17 12:1580-120EPA 8260B94 %Surr: 1,2-Dichloroethane-d47010680EPA 5030B17060-07-001/26/17 13:2801/26/17 12:1578-120EPA 8260B103 %Surr: Toluene-d87010680EPA 5030B2037-26-501/26/17 13:2801/26/17 12:1580-120EPA 8260B103 %Surr: 4-Bromofluorobenzene7010680EPA 5030B460-00-401/26/17 13:2801/26/17 12:1580-120Page 9 of 21
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020138 - EPA 3005ABlank (7020138-BLK1)Prepared: 02/06/17 Analyzed: 02/10/17 Antimonyug/LND6.00Arsenicug/LND10.0Bariumug/LND100Berylliumug/LND1.00Cadmiumug/LND1.00Chromiumug/LND10.0Cobaltug/LND10.0Copperug/LND10.0Leadug/LND10.0Nickelug/LND50.0Seleniumug/LND10.0Silverug/LND10.0Thalliumug/LND5.50Vanadiumug/LND25.0Zincug/L1.7710.0JLCS (7020138-BS1)Prepared: 02/06/17 Analyzed: 02/10/17 Antimonyug/L1096.00100.0080-120109Arsenicug/L10210.0100.0080-120102Bariumug/L99.4100100.00J80-12099Berylliumug/L1011.00100.0080-120101Cadmiumug/L1081.00100.0080-120108Chromiumug/L10610.0100.0080-120106Cobaltug/L98.510.0100.0080-12098Copperug/L10110.0100.0080-120101Leadug/L10410.0100.0080-120104Nickelug/L99.650.0100.0080-120100Page 10 of 21
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020138 - EPA 3005ALCS (7020138-BS1)Prepared: 02/06/17 Analyzed: 02/10/17 Seleniumug/L10310.0100.0080-120103Silverug/L10210.0100.0080-120102Thalliumug/L1065.50100.0080-120106Vanadiumug/L10525.0100.0080-120105Zincug/L10710.0100.0080-120107Matrix Spike (7020138-MS1)Prepared: 02/06/17 Analyzed: 02/10/17 Source: AAA0880-01Antimonyug/L1086.00100.000.2575-125107Arsenicug/L10010.0100.00ND75-125100Bariumug/L136100100.0038.075-12598Berylliumug/L99.21.00100.00ND75-12599Cadmiumug/L1041.00100.00ND75-125104Chromiumug/L10510.0100.000.9175-125104Cobaltug/L99.210.0100.00ND75-12599Copperug/L10010.0100.00ND75-125100Leadug/L10510.0100.00ND75-125105Nickelug/L10550.0100.002.3475-125102Seleniumug/L10210.0100.00ND75-125102Silverug/L10110.0100.00ND75-125101Thalliumug/L1045.50100.00ND75-125104Vanadiumug/L10325.0100.00ND75-125103Zincug/L10310.0100.003.3675-125100Matrix Spike Dup (7020138-MSD1)Prepared: 02/06/17 Analyzed: 02/10/17 Source: AAA0880-01Antimonyug/L1116.00100.000.252075-1251113Arsenicug/L10410.0100.00ND2075-1251044Bariumug/L142100100.0038.02075-1251045Berylliumug/L1041.00100.00ND2075-1251044Page 11 of 21
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020138 - EPA 3005AMatrix Spike Dup (7020138-MSD1)Prepared: 02/06/17 Analyzed: 02/10/17 Source: AAA0880-01Cadmiumug/L1071.00100.00ND2075-1251072Chromiumug/L11310.0100.000.912075-1251127Cobaltug/L10410.0100.00ND2075-1251045Copperug/L10710.0100.00ND2075-1251076Leadug/L10510.0100.00ND2075-1251050.4Nickelug/L10750.0100.002.342075-1251052Seleniumug/L10310.0100.00ND2075-1251031Silverug/L10610.0100.00ND2075-1251064Thalliumug/L1075.50100.00ND2075-1251072Vanadiumug/L11025.0100.00ND2075-1251106Zincug/L11110.0100.003.362075-1251087Post Spike (7020138-PS1)Prepared: 02/06/17 Analyzed: 02/10/17 Source: AAA0880-01Antimonyug/L102100.000.2580-120101Arsenicug/L101100.00-0.3480-120101Bariumug/L143100.0038.080-120105Berylliumug/L104100.000.0680-120104Cadmiumug/L110100.000.0480-120110Chromiumug/L110100.000.9180-120109Cobaltug/L104100.000.0180-120104Copperug/L104100.00-0.0680-120104Leadug/L102100.000.0480-120102Nickelug/L105100.002.3480-120103Seleniumug/L101100.000.2580-120101Silverug/L103100.000.0280-120103Thalliumug/L104100.000.0580-120104Vanadiumug/L107100.00-0.6880-120107Zincug/L108100.003.3680-120104Page 12 of 21
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020138 - EPA 3005APage 13 of 21
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010680 - EPA 5030BBlank (7010680-BLK1)Prepared & Analyzed: 01/26/17 Acetoneug/LND100Acrylonitrileug/LND200Benzeneug/LND1.0Bromochloromethaneug/LND3.0Bromodichloromethaneug/LND1.0Bromoformug/LND3.0Bromomethaneug/LND10Carbon Disulfideug/LND100Carbon Tetrachlorideug/LND1.0Chlorobenzeneug/LND3.0Chloroethaneug/LND10Chloroformug/LND5.0Chloromethaneug/LND1.0Dibromochloromethaneug/LND3.01,2-Dibromo-3-chloropropaneug/LND131,2-Dibromoethaneug/LND1.0Dibromomethaneug/LND101,2-Dichlorobenzeneug/LND5.01,4-Dichlorobenzeneug/LND1.0trans-1,4-Dichloro-2-buteneug/LND1001,1-Dichloroethaneug/LND5.01,2-Dichloroethaneug/LND1.01,1-Dichloroetheneug/LND5.0cis-1,2-Dichloroetheneug/LND5.0trans-1,2-Dichloroetheneug/LND5.01,2-Dichloropropaneug/LND1.0cis-1,3-Dichloropropeneug/LND1.0Page 14 of 21
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010680 - EPA 5030BBlank (7010680-BLK1)Prepared & Analyzed: 01/26/17 trans-1,3-Dichloropropeneug/LND1.0Ethylbenzeneug/LND1.0Iodomethaneug/LND10Methyl Butyl Ketone (2-Hexanone)ug/LND50Methylene Chlorideug/LND1.0Methyl Ethyl Ketone (2-Butanone)ug/LND1004-Methyl-2-pentanone (MIBK)ug/LND100Styreneug/LND1.01,1,1,2-Tetrachloroethaneug/LND5.01,1,2,2-Tetrachloroethaneug/LND3.0Tetrachloroetheneug/LND1.0Tolueneug/LND1.01,1,1-Trichloroethaneug/LND1.01,1,2-Trichloroethaneug/LND1.0Trichloroetheneug/LND1.0Trichlorofluoromethaneug/LND1.01,2,3-Trichloropropaneug/LND1.0Vinyl Acetateug/LND50Vinyl Chlorideug/LND1.0Xylenes, totalug/LND5.0ug/L50.00080-120Surr: Dibromofluoromethane9346ug/L50.00078-120Surr: 1,2-Dichloroethane-d49648ug/L50.00080-120Surr: Toluene-d810352ug/L50.00080-120Surr: 4-Bromofluorobenzene10352LCS (7010680-BS1)Prepared & Analyzed: 01/26/17 Benzeneug/L4950.00067-13499Page 15 of 21
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010680 - EPA 5030BLCS (7010680-BS1)Prepared & Analyzed: 01/26/17 Chlorobenzeneug/L4950.00069-122981,1-Dichloroetheneug/L5450.00058-142108Tolueneug/L4550.00068-12791Trichloroetheneug/L4950.00072-13298ug/L50.00080-120Surr: Dibromofluoromethane9346ug/L50.00078-120Surr: 1,2-Dichloroethane-d49547ug/L50.00080-120Surr: Toluene-d810251ug/L50.00080-120Surr: 4-Bromofluorobenzene10251Matrix Spike (7010680-MS1)Prepared & Analyzed: 01/26/17 Source: AAA0860-02Benzeneug/L5850.0000.067-134116Chlorobenzeneug/L5550.0000.069-1221101,1-Dichloroetheneug/L6950.0000.058-142137Tolueneug/L5050.0000.068-127101Trichloroetheneug/L5650.0000.072-132113ug/L50.00080-120Surr: Dibromofluoromethane8844ug/L50.00078-120Surr: 1,2-Dichloroethane-d410151ug/L50.00080-120Surr: Toluene-d810150ug/L50.00080-120Surr: 4-Bromofluorobenzene10251Matrix Spike Dup (7010680-MSD1)Prepared & Analyzed: 01/26/17 Source: AAA0860-02Benzeneug/L5950.0000.0967-1341171Chlorobenzeneug/L5850.0000.01369-12211551,1-Dichloroetheneug/L6950.0000.0958-1421390.9Tolueneug/L5350.0000.0968-1271066Trichloroetheneug/L5850.0000.01172-1321163Page 16 of 21
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010680 - EPA 5030BMatrix Spike Dup (7010680-MSD1)Prepared & Analyzed: 01/26/17 Source: AAA0860-02ug/L50.00080-120Surr: Dibromofluoromethane9045ug/L50.00078-120Surr: 1,2-Dichloroethane-d410050ug/L50.00080-120Surr: Toluene-d810351ug/L50.00080-120Surr: 4-Bromofluorobenzene10352Page 17 of 21
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017Laboratory CertificationsCodeDescriptionNumberExpires812Georgia DW Inorganics Eff: 07/01/201606/30/2017GADW812Georgia DW Microbiology Eff: 07/01/201503/09/2017GADWM381North Carolina12/31/2017NCE87315FL DOH (Non-Pot. Water, Solids) Eff:: 07/01/201606/30/2017NELACE87315FL DOH NELAC (Drinking Water) Eff: 07/01/201606/30/2017NELDW98011001South Carolina06/30/2017SCT104704397-08-TXTexas03/31/2017TX1340Virginia12/14/2017VAPage 18 of 21
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 20, 2017LegendDefination of Laboratory Terms - Not Detected at levels greater than or equal to SWSL/RLNDSWSL/RLMDL - NC DENR Solid Waste Section LImit/Reporting Limit (Adjusted for DF/Prep Factor) - Method Detection LimitQualifiers - Dilution FactorDFJEstimated value less than Reporting Limit (RL) but greater than Method Detection Limit(MDL) (CLP J-Flag).B-01Analyte was detected in the associated method blank at an estimated level equal to or greater than the MDL. Sample values reported as greater than the MDL and less than 10x the method blank value are reported as estimated values.Note: Unless otherwise noted, all results are reported on an as received basis.Page 19 of 21
Page 20 of 21
LOG-IN CHECKLIST
Republic Services of North Carolina, LLC
East Carolina Regional LandfillProject:
Client:
Printed: 1/30/2017 10:27:59AM
Environmental Monitoring & Laboratory Analysis
[phone] FAX [phone]
110 Technology Parkway, Peachtree Corners, GA 30092
PACE ANALYTICAL SERVICES, LLC.
Date Received:01/26/17 09:20 Logged In By:Charles Hawks
Work Order:AAA0863
OBSERVATIONS
Attn: Mr. Matt Einsmann
#Samples: 2 #Containers: 7
2.0 2.0
YES
Minimum Temp(C):Maximum Temp(C):
CHECKLIST ITEMS
COC included with Samples
Sample Container(s) Intact
Chain of Custody Complete
Sample Container(s) Match COC
Custody seal Intact
Temperature in Compliance
Sufficient Sample Volume for Analysis
Zero Headspace Maintained for VOA Analyses
Samples labeled preserved (If Applicable)
Samples received within Allowable Hold Times
Samples Received on Ice
Preservation Confirmed
YES
YES
YES
N/A
YES
YES
YES
YES
YES
YES
YES
Custody Seal(s) Used:No
Comments:
Page 1 of 1Page 21 of 21
PACE ANALYTICAL SERVICES, LLC.Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]Republic Services of North Carolina, LLCProject: East Carolina Regional Landfill ResampleConover, NC 286131220 Commerce Street, SWMr. Matt EinsmannWe appreciate the opportunity to provide the analytical support for your project. The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Pace Analytical Services, LLC. certifies that the following analytical results meet all requirements of the National Environmental Laboratory Accreditation Conference(NELAC).All test results relate only to the samples analyzed.Laboratory ReportProject #:GW-7Prepared For:Attention:April 17, 2017Report Number:AAD0214Approved:This report may not be reproduced, except in full, without written approval from Pace Analytical Services, LLC.Page 1 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannApril 17, 2017Sample IDLaboratory IDMatrixDate SampledANALYTICAL REPORT FOR SAMPLESDate Received0803-GW7AAD0214-0104/05/17 11:5604/06/17 09:20Ground Water0803-Field BlankAAD0214-0204/05/17 12:0504/06/17 09:20WaterPage 2 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannApril 17, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-GW7Ground WaterAAD0214-01AAD021404/05/17 11:56Project:East Carolina Regional Landfill Resample04/06/17 09:20Metals, TotalEPA 6020B0.81ug/L1Silver10.0J7040185EPA 3005A0.327440-22-404/07/17 18:3004/07/17 11:30Metals, DissolvedEPA 6020B0.36ug/L1Silver10.0J7040224EPA 3005A0.327440-22-404/14/17 00:3904/10/17 09:40Page 3 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannApril 17, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:0803-Field BlankWaterAAD0214-02AAD021404/05/17 12:05Project:East Carolina Regional Landfill Resample04/06/17 09:20Metals, TotalNDEPA 6020Bug/L1Silver10.07040185EPA 3005A0.327440-22-404/07/17 18:3604/07/17 11:30Page 4 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannApril 17, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7040185 - EPA 3005ABlank (7040185-BLK1)Prepared & Analyzed: 04/07/17 Silverug/LND10.0LCS (7040185-BS1)Prepared & Analyzed: 04/07/17 Silverug/L10110.0100.0080-120101Matrix Spike (7040185-MS1)Prepared & Analyzed: 04/07/17 Source: AAD0056-01Silverug/L98.610.0100.00ND75-12599Matrix Spike Dup (7040185-MSD1)Prepared & Analyzed: 04/07/17 Source: AAD0056-01Silverug/L97.610.0100.00ND2075-125981Post Spike (7040185-PS1)Prepared & Analyzed: 04/07/17 Source: AAD0056-01Silverug/L98.1100.000.2280-12098Page 5 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannApril 17, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Dissolved - Quality ControlBatch 7040224 - EPA 3005ABlank (7040224-BLK1)Prepared: 04/10/17 Analyzed: 04/13/17 Silverug/LND10.0Blank (7040224-BLK2)Prepared: 04/10/17 Analyzed: 04/13/17 Silverug/LND10.0LCS (7040224-BS1)Prepared: 04/10/17 Analyzed: 04/13/17 Silverug/L96.610.0100.0080-12097LCS (7040224-BS2)Prepared: 04/10/17 Analyzed: 04/13/17 Silverug/L10510.0100.0080-120105Matrix Spike (7040224-MS1)Prepared: 04/10/17 Analyzed: 04/13/17 Source: AAD0274-01Silverug/L10110.0100.00ND75-125101Matrix Spike Dup (7040224-MSD1)Prepared: 04/10/17 Analyzed: 04/13/17 Source: AAD0274-01Silverug/L99.210.0100.00ND2075-125992Post Spike (7040224-PS1)Prepared: 04/10/17 Analyzed: 04/13/17 Source: AAD0274-01Silverug/L98.3100.000.00180-12098Page 6 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannApril 17, 2017Laboratory CertificationsCodeDescriptionNumberExpires812Georgia DW Inorganics Eff: 07/01/201606/30/2017GADW812Georgia DW Microbiology Eff: 07/01/201505/09/2017GADWM381North Carolina12/31/2017NCE87315FL DOH (Non-Pot. Water, Solids) Eff:: 07/01/201606/30/2017NELACE87315FL DOH NELAC (Drinking Water) Eff: 07/01/201606/30/2017NELDW98011001South Carolina06/30/2017SCT104704397-08-TXTexas03/31/2018TX460204Virginia12/14/2017VAPage 7 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannApril 17, 2017LegendDefination of Laboratory Terms - Not Detected at levels greater than or equal to SWSL/RLNDSWSL/RLMDL - NC DENR Solid Waste Section LImit/Reporting Limit (Adjusted for DF/Prep Factor) - Method Detection LimitQualifiers - Dilution FactorDFJEstimated value less than Reporting Limit (RL) but greater than Method Detection Limit(MDL) (CLP J-Flag).Note: Unless otherwise noted, all results are reported on an as received basis.Page 8 of 10
Page 9 of 10
LOG-IN CHECKLIST
Republic Services of North Carolina, LLC
East Carolina Regional Landfill ResampleProject:
Client:
Printed: 4/7/2017 1:46:27PM
Environmental Monitoring & Laboratory Analysis
[phone] FAX [phone]
110 Technology Parkway, Peachtree Corners, GA 30092
PACE ANALYTICAL SERVICES, LLC.
Date Received:04/06/17 09:20 Logged In By:Charles Hawks
Work Order:AAD0214
OBSERVATIONS
Attn: Mr. Matt Einsmann
#Samples: 2 #Containers: 3
1.0 1.0
YES
Minimum Temp(C):Maximum Temp(C):
CHECKLIST ITEMS
COC included with Samples
Sample Container(s) Intact
Chain of Custody Complete
Sample Container(s) Match COC
Custody seal Intact
Temperature in Compliance
Sufficient Sample Volume for Analysis
Zero Headspace Maintained for VOA Analyses
Samples labeled preserved (If Applicable)
Samples received within Allowable Hold Times
Samples Received on Ice
Preservation Confirmed
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
Custody Seal(s) Used:Yes
Comments:
Page 1 of 1Page 10 of 10

Appendix D

Statistical Analyses Worksheets and Summary Table

Joyce Project: East Carolina Regional Landfill
Project No: 894.1701.12
Task No: 02
Date: 1-Mar-17
Analyte:Cobalt
Concentration
Sample No. Sample Date Location (µg/L) QL
1 28-Oct-98 GW-7 30 13.8 50
2 07-Apr-99 GW-7 20 20 50
3 08-Dec-99 GW-7 20 20 40
4 27-Apr-00 GW-7 30 21.5 40
5 18-Oct-00 GW-7 30 23.7 40
6 19-Apr-01 GW-7 30 26.1 39.0
7 24-Dec-01 GW-7 30 26.6 37.5
8 23-Apr-02 GW-7 30 29.8 37.3
9 23-Oct-02 GW-7 50 30 36
10 01-Apr-03 GW-7 40 30 35.4
11 28-Oct-03 GW-7 50 30 35.1
12 27-Apr-04 GW-7 30 30 34.9
13 26-Oct-04 GW-7 40 30 33.3
14 15-Mar-05 GW-7 36 30 31.6
15 12-Jul-05 GW-7 40 30 30
16 19-Jan-06 GW-7 30.0 30.0 30
17 11-Jul-06 GW-7 31.6 31.6 30
18 17-Jan-07 GW-7 34.9 33.3 30
19 09-Jul-07 GW-7 37.5 34.9 30
20 14-Jan-08 GW-7 35.1 35.1 30
21 14-Jul-08 GW-7 37.3 35.4 30
22 19-Jan-09 GW-7 23.7 36 30.0
23 20-Jul-09 GW-7 35.4 37.3 29.8
24 25-Jan-10 GW-7 21.5 37.5 26.6
25 06-Jul-10 GW-7 26.6 39.0 26.1
26 04-Jan-11 GW-7 29.8 40 23.7
27 05-Jul-11 GW-7 39.0 40 21.5
28 09-Jan-12 GW-7 13.8 40 20
29 09-Jul-12 GW-7 26.1 50 20
30 28-Jan-13 GW-7 33.3 50 13.8
Number of Data: 30
Number of Truncated Data: 0
Percentage of Truncated Data: 0%
Upper Tolerance Limit: 50.0 µg/L
All concentrations in micrograms per liter (µg/L).
B = Blank qualified data not used in statistical calculations.
J = Estimated concentration below quantification limit.
ND = Not detected above the detection limit (truncated).
Sorted
Concentration (µg/L)
JEI Project: East Carolina Regional Landfill
Project No:894.1701.12
Task No:02
Date:1-Mar-17
Shapiro Wilk Test Statistic (W) for normality of total Cobalt
Complete the following table where
i = ordered value of sample, arranged from smallest to largest
X(i) = sample values arranged from smallest to largest
X(n-i+1) = sample values arranged from largest to smallest
A(n-i+1) = coefficient from table A-1, Statistical Analysis of Ground-Water
Data at RCRA Facilities
B(i) = summation of (X(n-i+1)-X(i))A(n-i+1)
i X(i) X(n-i+1) X(n-i+1) - X(i) A(n-i+1) B(i)
1 13.8 50 36.20 0.4254 15.3995
2 20 50 30.00 0.2944 8.8320
3 20 40 20.00 0.2487 4.9740
4 21.5 40 18.50 0.2148 3.9738
5 23.7 40 16.30 0.1870 3.0481
6 26.1 39.0 12.90 0.1630 2.1027
7 26.6 37.5 10.90 0.1415 1.5424
8 29.8 37.3 7.50 0.1219 0.9143
9 30 36 6.00 0.1036 0.6216
10 30 35.4 5.40 0.0862 0.4655
11 30 35.1 5.10 0.0697 0.3555
12 30 34.9 4.90 0.0537 0.2631
13 30 33.3 3.30 0.0381 0.1257
14 30 31.6 1.60 0.0227 0.0363
15 30 30 0.00 0.0076 0.0000
16 30.0 30 0.00
17 31.6 30 -1.60
18 33.3 30 -3.30
19 34.9 30 -4.90
20 35.1 30 -5.10
21 35.4 30 -5.40
22 36 30.0 -6.00
23 37.3 29.8 -7.50
24 37.5 26.6 -10.90
25 39.0 26.1 -12.90
26 40 23.7 -16.30
27 40 21.5 -18.50
28 40 20 -20.00
29 50 20 -30.00
30 50 13.8 -36.20
The test statistic W can be found using:
W = SQR[B/(SD x SQRT(n-1))]
where: B = summation of (X(n-i+1)-X(i))A(n-i+1) = 42.65
SD = standard deviation of the data group = 8.08
n = number of samples = 30
W = 0.961
Compare this value to the critical value in Table A-2 of Statistical Analysis of Ground-Water
Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance (Draft)
July, 1992, to determine if the data is normally distributed.
From Table A-2 with (n) samples and a 95% confidence level, the critical value is
W(crit) = 0.927
and the calculated W = 0.961
Therefore the data set is Normal
JOYCE Project: East Carolina Regional Landfill
Project No: 894.1701.12
Task No: 02
Date: 1-Mar-17
Probability Plots to determine the distribution of Cobalt
Complete the following table where
i = ordered value of sample, arranged from smallest to largest
X(i) = sample values arranged from smallest to largest
LN[X(i)] = Natural Log Value of sample concentrations arranged from
smallest to largest
[i/(n+1)] = Cumulative probability
n = number of samples = 30
X(i) LN[X(i)] i Rank [Rank/(n+1)] Quantiles
13.80 2.62 1 1 0.032 -1.85
20.00 3.00 2 2 0.065 -1.52
20.00 3.00 3 3 0.097 -1.30
21.50 3.07 4 4 0.129 -1.13
23.70 3.17 5 5 0.161 -0.99
26.10 3.26 6 6 0.194 -0.86
26.60 3.28 7 7 0.226 -0.75
29.80 3.39 8 8 0.258 -0.65
30.00 3.40 9 9 0.290 -0.55
30.00 3.40 10 10 0.323 -0.46
30.00 3.40 11 11 0.355 -0.37
30.00 3.40 12 12 0.387 -0.29
30.00 3.40 13 13 0.419 -0.20
30.00 3.40 14 14 0.452 -0.12
30.00 3.40 15 15 0.484 -0.04
30.00 3.40 16 16 0.516 0.04
31.60 3.45 17 17 0.548 0.12
33.30 3.51 18 18 0.581 0.20
34.90 3.55 19 19 0.613 0.29
35.10 3.56 20 20 0.645 0.37
35.40 3.57 21 21 0.677 0.46
36.00 3.58 22 22 0.710 0.55
37.30 3.62 23 23 0.742 0.65
37.50 3.62 24 24 0.774 0.75
39.00 3.66 25 25 0.806 0.86
40.00 3.69 26 26 0.839 0.99
40.00 3.69 27 27 0.871 1.13
40.00 3.69 28 28 0.903 1.30
50.00 3.91 29 29 0.935 1.52
50.00 3.91 30 30 0.968 1.85
Plot analysis indicates that the data more closely follow a normal distribution.
JEI Project: East Carolina Regional Landfill
Project No: 894.1701.12
Task No: 02
Date: 1-Mar-17
Probability Plots to determine the distribution of Cobalt
Upper Prediction Limit:
Lower Prediction Limit:
R² = 0.9445
-2.50
-2.00
-1.50
-1.00
-0.50
0.00
0.50
1.00
1.50
2.00
0.00 10.00 20.00 30.00 40.00 50.00 60.00Quantile
Concentration (ug/L)
Normal Probability Plot
Cobalt
R² = 0.9082
-2.00
-1.50
-1.00
-0.50
0.00
0.50
1.00
1.50
2.00
0.00 1.00 2.00 3.00 4.00 5.00Quantile
Ln [Concentration (ug/L)]
Log-Normal Probability Plot
Cobalt
JOYCE Project East Carolina Regional Landfill
Project No: 894.1701.12
Task No: 02
Date: 1-Mar-17
Determination of reported background value as an outlier
Analyte:Cobalt
Background Data
Concentration
Sample No. Sample Date Location (µg/L)
1 28-Oct-98 GW-7 30.00
2 07-Apr-99 GW-7 20.00
3 08-Dec-99 GW-7 20.00
4 27-Apr-00 GW-7 30.00
5 18-Oct-00 GW-7 30.00
6 19-Apr-01 GW-7 30.00
7 24-Dec-01 GW-7 30.00
8 23-Apr-02 GW-7 30.00
9 23-Oct-02 GW-7 50.00
10 01-Apr-03 GW-7 40.00
11 28-Oct-03 GW-7 50.00
12 27-Apr-04 GW-7 30.00
13 26-Oct-04 GW-7 40.00
14 15-Mar-05 GW-7 36.00
15 12-Jul-05 GW-7 40.00
16 19-Jan-06 GW-7 30.00
17 11-Jul-06 GW-7 31.60
18 17-Jan-07 GW-7 34.90
19 09-Jul-07 GW-7 37.50
20 14-Jan-08 GW-7 35.10
21 14-Jul-08 GW-7 37.30
22 19-Jan-09 GW-7 23.70
23 20-Jul-09 GW-7 35.40
24 25-Jan-10 GW-7 21.50
25 06-Jul-10 GW-7 26.60
26 04-Jan-11 GW-7 29.80
27 05-Jul-11 GW-7 39.00
28 09-Jan-12 GW-7 13.80
29 09-Jul-12 GW-7 26.10
30 28-Jan-13 GW-7 33.3
Mean = 32.053
STD = 8.081
Note: All concentrations are in µg/L.
Using the data listed above, form the statisitc Tn:
Tn = (Xn - mean) / STD
where: Xn = largest observed sample value
mean = mean of the background values
STD = standard deviation of the background values
For Xn = 50.000
mean = 32.053
STD = 8.081
Tn = 2.221
From Table 8 included in the Statistical Analysis of Groundwater Monitoring Data at
RCRA Facilities - Interim Final Guidance, the critical value for the given sample group is
Number of samples = 30
Tc = 2.745
Since Tc>Tn, the sample result is not considered to be an outlier
JEI Project: East Carolina Regional Landfill
Project No: 894.1701.12
Date: 01-Mar-17
Parametric Tolerance Interval for normally distributed data
Analyte:Cobalt
Background Data
Sample No. Sample Date Location Concentration
1 10/28/98 GW-7 30.00
2 04/07/99 GW-7 20.00
3 12/08/99 GW-7 20.00
4 04/27/00 GW-7 30.00
5 10/18/00 GW-7 30.00
6 04/19/01 GW-7 30.00
7 12/24/01 GW-7 30.00
8 04/23/02 GW-7 30.00
9 10/23/02 GW-7 50.00
10 04/01/03 GW-7 40.00
11 10/28/03 GW-7 50.00
12 04/27/04 GW-7 30.00
13 10/26/04 GW-7 40.00
14 03/15/05 GW-7 36.00
15 07/12/05 GW-7 40.00
16 01/19/06 GW-7 30.00
17 07/11/06 GW-7 31.60
18 01/17/07 GW-7 34.90
19 07/09/07 GW-7 37.50
20 01/14/08 GW-7 35.10
21 07/14/08 GW-7 37.30
22 01/19/09 GW-7 23.70
23 07/20/09 GW-7 35.40
24 01/25/10 GW-7 21.50
25 07/06/10 GW-7 26.60
26 01/04/11 GW-7 29.80
27 07/05/11 GW-7 39.00
28 01/09/12 GW-7 13.80
29 07/09/12 GW-7 26.10
30 01/28/13 GW-7 33.30
Using the background data, the upper Tolerance Limit can be determined using:
Upper Tolerance Limit = (Mean Concentration) + K x (Standard Deviation Samples)
where: Mean Conc = mean concentration background samples
K = factor for constructing one sided normal tolerance limit
taken from table 4-2, page 87, Statistical Methods for Groundwater
Monitoring, Gibbons, 1994
n = number of background samples
STDS = Standard Deviation Samples
For: n = 30
K = 2.220
Mean Conc = 32.05
STDS = 8.08
UTL = 49.99 µg/L
Joyce Project: East Carolina Regional Landfill
Project No: 894.1701.12
Task No: 02
Date: April 2017
Analyte:Chromium
Concentration
Sample No. Sample Date Location (µg/L)QL
1 28-Oct-98 GW-2 ND 10 0.83 10.40
2 07-Apr-99 GW-2 ND 10 0.94 5.98
3 08-Dec-99 GW-2 ND 10 1.44 3.70
4 27-Apr-00 GW-2 ND 10 1.46 3.22
5 18-Oct-00 GW-2 ND 10 1.55 2.86
6 19-Apr-01 GW-2 ND 10 1.82 2.60
7 24-Dec-01 GW-2 ND 10 1.85 1.88
8 23-Apr-02 GW-2 ND 10 1.86 1.86
9 23-Oct-02 GW-2 ND 10 1.88 1.85
10 01-Apr-03 GW-2 ND 10 2.60 1.82
11 28-Oct-03 GW-2 ND 10 2.86 1.55
12 27-Apr-04 GW-2 ND 10 3.22 1.46
13 26-Oct-04 GW-2 ND 10 3.70 1.44
14 15-Mar-05 GW-2 ND 10 5.98 0.94
15 12-Jul-05 GW-2 ND 10 10.40 0.83
16 19-Jan-06 GW-2 ND 10
17 11-Jul-06 GW-2 ND 10
18 17-Jan-07 GW-2 ND 10
19 09-Jul-07 GW-2 ND 10
20 14-Jan-08 GW-2 2.60 J 10
21 14-Jul-08 GW-2 ND 10
22 19-Jan-09 GW-2 3.70 J 10
23 20-Jul-09 GW-2 0.94 J 10
24 25-Jan-10 GW-2 ND 10
25 06-Jul-10 GW-2 10.40 10
26 04-Jan-11 GW-2 1.46 J 10
27 05-Jul-11 GW-2 1.44 J 10
28 09-Jan-12 GW-2 ND 10
29 09-Jul-12 GW-2 1.88 J 10
28-Jan-13 GW-2 2.40 B 10
30 17-Jul-13 GW-2 3.22 J 10
31 28-Jan-14 GW-2 1.85 10
32 24-Jul-14 GW-2 0.83 J 10
33 28-Jan-15 GW-2 1.86 J 10
34 16-Sep-15 GW-2 1.82 J 10
35 27-Jan-16 GW-2 2.86 J 10
36 27-Jul-16 GW-2 1.55 J 10
37 25-Jan-17 GW-2 5.98 J 10
Number of Data: 37
Number of Truncated Data: 22
Percentage of Truncated Data: 59%
Non-Parametric Prediction Interval 10.4 µg/L
All concentrations in micrograms per liter (µg/L).
B = Blank-qualified data not used in statistical calculations.
J = Estimated concentration below the quantitation limit (QL).
ND = Not detected above the detection limit (truncated).
Sorted
Concentration (µg/L)
Summary of Statistical Analyses (January 2017 Sampling Event)Constituent NC 2L GWPS Data DistributionStatistical Method used to Establish BackgroundCalculated Background Concentration (µg/L)Sample LocationSample Result (µg/L) SSICobaltN/E 10% Truncated NormalUpper Tolerance Limit - Intrawell MW-7 50.0 GW-7 33.0 NOChromium 10 N/E 59% Truncated Non-parametric Prediction Interval - Interwell10.4 GW-17 10.0 NONotes:Concentrations are in micrograms per liter (µg/L).GWPS = NC DENR Solid Waste Section Groundwater Protect Standard.SSI = Statistically significant increase over background.N/E = Not established.N/A = Not applicable.Republic - East Carolina LandfillPermit # 08-03Joyce Engineering