Loading...
HomeMy WebLinkAbout14007_Bloom Additional Indoor Air Report 20180823i S:\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Report\Additional Indoor Air Sampling Report.doc Additional Indoor Air Sampling and Well Abandonment Report Bloomsburg Mills Brownfields Site 3000 Stitt Street Monroe, North Carolina H&H Job No. IME-001 Table of Contents Section Page No. 1.0 Introduction and Background Information .........................................................................1 2.0 Indoor Air Sampling ...............................................................................................................8 2.1 Indoor Air Sampling Methodology ........................................................................................8 2.2 Indoor Air Sampling Results .................................................................................................9 2.3 Cumulative Risk Calculations .............................................................................................11 3.0 Well Abandonment ...............................................................................................................13 4.0 Summary and Conclusions....................................................................................................14 List of Tables Table 1 Summary of the Indoor Air Field Measurement Data Table 2 Summary of Indoor and Background Air Analytical Data List of Figures Figure 1 Site Location Map Figure 2 Detailed Site Map Figure 3 Soil Vapor, Indoor Air, and Background Sample Locations Map List of Appendices Appendix A DEQ Indoor Air Building Survey and Sampling Form Appendix B Laboratory Analytical Report Appendix C DEQ Risk Calculators Appendix D Well Abandonment Records 1 S:\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Report\Additional Indoor Air Sampling Report.doc Additional Indoor Air Sampling and Well Abandonment Report Bloomsburg Mills Brownfields Site 3000 Stitt Street Monroe, North Carolina H&H Job No. IME-001 1.0 Introduction and Background Information Hart & Hickman, PC (H&H) has prepared this report to document post-Brownfields agreement indoor air sampling conducted at the Bloomsburg Mills Brownfields Site located at 3000 Stitt Street in Monroe, Union County, North Carolina (Site). A Site Location Map is provided as Figure 1. In addition, this report provides documentation of the abandonment of monitoring and remediation wells at the Site which was conducted concurrently with the indoor air sampling. The Site consists of one parcel that is divided into two portions. The northern portion of the parcel is approximately 3.8 acres, is located on the north side of Stitt St. and is currently vacant land. The southern portion of the parcel is approximately 19.8 acres, is located on the south side of Stitt St. and is developed with an approximately 207,000 sq ft building, an out of use water tank, and parking and loading dock areas. A detailed Site map depicting the southern portion of the Site is included as Figure 2. The western and southeastern portions of the building are occupied by IMET Alloys (IMET) for the receipt, sorting, testing, cutting, cleaning, packaging, and shipping of nickel and titanium alloys for the aerospace industry. The northeastern portion of the building is occupied by Achem which performs cutting, limited printing, packaging, and distribution of tape products. The Site building was constructed in 1963 by Springs Industries, and Bloomsburg Mills acquired the property in 1978 and operated at the Site until 2009. An addition was constructed on the building prior to 1976. Springs and Bloomsburg used the Site building for textile dyeing and finishing. A wastewater lagoon was also located in the northern portion of the parcel from the late 1970s until it was closed in 2009. 2 S:\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Report\Additional Indoor Air Sampling Report.doc Bloom Industrial (unrelated to Bloomsburg Mills) purchased the Site from Bloomsburg Mills to redevelop and lease the building to various tenants for industrial purposes. At that time, Bloom Industrial began pursuit of a Brownfields agreement for the Site due to the presence of soil and groundwater impacts associated with previous use of the Site for textile dyeing and finishing. In August 2014, Bloom Industrial completed the Brownfields agreement with the North Carolina Department of Environmental Quality (DEQ). IMET originally leased a portion of the Site building from Bloom Industrial beginning in 2012 and, in April 2017, an affiliate of IMET (IMET Properties LLC) purchased the facility from Bloom Industrial. Previous assessment activities have been performed in conjunction with former petroleum underground storage tanks (USTs) and former textile operations. These are briefly discussed below. Former USTs • A 1,000-gallon gasoline UST was removed from the Site in 1989; however, the exact location of the UST was not reported. Post-excavation soil sampling did not contain detectable concentrations of gasoline range total petroleum hydrocarbons (TPH-GRO). In a letter dated June 12, 1990, the DEQ indicated that no further action was warranted for the UST. • One 30,000-gallon No. 6 fuel oil UST was removed from the western side of the Site building in 1993. The former location of the UST is depicted in Figure 2. Soil and groundwater impacts were identified after removal of the UST; however, excavated soils were placed back into the excavation due to reported concentrations of oil & grease which were below the calculated final cleanup levels for the Site. • Two 20,000-gallon No. 6 fuel oil USTs were removed from the northwestern side of the Site building in 1994. The former locations of the USTs are depicted in Figure 2. Soil and groundwater impacts were identified in association with the USTs after removal, and 3 S:\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Report\Additional Indoor Air Sampling Report.doc approximately 917.13 tons of impacted soil was excavated and transported to Stalite Environmental in Salisbury, North Carolina. • Additional soil and groundwater assessments were conducted from 1996 through 1998 associated with the release of fuel-oil from the former USTs. The results of the additional assessment activities revealed that the soil impacts did not exceed DEQ levels ant that groundwater impacts were still present above North Carolina groundwater standards but did not exceed the DEQ UST Section Gross Contamination Levels. The DEQ classified the release as low risk and subsequently issued a risk-based no further action (NFA) for the UT release incident, with a provision that groundwater was restricted for use as a water supply, on October 20, 1998. Former Textile Finishing Operations In 1991, Bloomsburg Mills conducted an assessment of stained soil on the west side of the building. The area was reportedly used to store drums during the time when the plant was operated by Springs. Subsequently, additional soil and groundwater assessment were performed on the west side of the building associated with the stained soil and former USTs (as noted above) which indicated the presence of chlorinated volatile organic compounds (CVOCs) (principally tetrachloroethene (PCE)) in groundwater. The groundwater assessment indicated the presence of two areas of CVOC groundwater impacts, one in the northwestern and one in the southwestern portions of the Site. The northwestern area is believed to be associated with a PCE above ground storage tank (AST) that was located outside the northwest corner of the building which was pumped to a process tank in the building. The southwestern area is believed to be associated with maintenance activities conducted in storage sheds and drum and equipment staging pad which were formerly located in that portion of the Site. Groundwater flow was reported to be toward the northeast in the northwestern portion of the Site and to the southeast in the southwestern portion of the Site. Bloomsburg Mills conducted interim corrective actions at the Site which consisted of pumping groundwater from two recovery wells to the wastewater lagoon located in the northern portion of 4 S:\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Report\Additional Indoor Air Sampling Report.doc the Site parcel. The recovery system was installed in 2002 and operated at least until 2008. According to the most recent groundwater sampling report, (Resolve Environmental Services, PLLC, December 2008) PCE was detecting in MW-19 at a concentration of 40,500 micrograms per liter (µg/L) which exceeded the North Carolina groundwater standard of 0.7 µg/L. MW-19 is located outside the building in the northwestern portion of the Site. PCE was detected up to 1,790 µg/L in the northern part of the Site (MW-20), and up to 3,040 µg/L in the southern portion of the Site (MW-22). PCE degradation products such as trichloroethene (TCE) were also detected above North Carolina groundwater standards. Vapor Intrusion Assessments Previous vapor intrusion assessments were conducted in the Site building from 2011 to 2015 by Resolve Environmental Services, PA (Resolve) and Harmon Environmental, PA (Harmon). As part of the sampling, the building was given certain “Area” designations as shown in Figure 2 and briefly described below: • Area 1 – IMET offices • Area 2 – Achem offices • Area 3 – IMET nickel and titanium solids handling and nickel washing • Area 4 – Achem operations • Area 5 – IMET vacant • Area 6 – IMET nickel and titanium torch and shot blast • Area 7 – IMET shipping In January 2011, Bloomsburg collected soil vapor samples from below the building to evaluate the potential for vapor intrusion concerns for the Site building associated with the soil and groundwater impacts. The approximate locations of soil vapor samples are indicated in Figure 2. The results of the soil vapor sampling indicated that only PCE was detected above current Non- Residential Soil Gas Screening Levels (SGSLs) in samples collected from the northern portion of the IMET solids handling space (Area 3; AS-1) and below the Achem space (Area 4; AS-7). The locations of the previous soil vapor samples are indicated in Figure 3. 5 S:\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Report\Additional Indoor Air Sampling Report.doc In September 2011, Bloom Industrial made improvements to the building which included filling in some equipment pits in Area 3 and sealing the large cracks and gaps in the floor of the building. In addition, Bloom Industrial applied two sealants on the concrete floor to minimize vapor intrusion. IMET has also more recently filled in a pit in Area 5. In October 2011, Harmon collected eight (8) indoor air samples on behalf of Bloom Industrial. The samples were analyzed for a full list of volatile organic compounds (VOCs) and the sample analytes were not limited based upon detection in soil vapor data. The results of the indoor air sampling indicated that no CVOCs were detected above DEQ Non-Residential Indoor Air Screening Levels (IASLs) with the exception of TCE which was detected at concentrations above the screening level of 1.8 micrograms per cubic meter (µg/m3). TCE was detected in samples AS-1 (6.2 µg/m3), AS-3 (2.4 µg/m3), and AS-4 (5.4 µg/m3), all of which are located in the far northern and western portions of the building (Area 3). Note that because the IASLs are conservative, the presence of a compound at a concentration above the IASL does not indicate that vapor mitigation is warranted, only that additional evaluation may be warranted. In addition, several petroleum-related volatile organic compounds (VOCs) were also detected above the Non- Residential IASLs (naphthalene, toluene, xylenes, and 1,2,4-trimethylbenzene); however, these compounds were thought to be associated with indoor air sources in the building and not vapor intrusion. Further, petroleum-related VOCs and some CVOCs (including PCE and TCE) were detected in the exterior background samples. In July 2012, Harmon conducted another round of indoor air sampling. The results of analysis of the indoor air samples indicated that PCE and/or TCE were detected above the Non-Residential IASLs in samples AS-1, AS-3, and AS-4, collected from the far northern and western portions of the building and AS-2 and AS-7, collected from the Achem space in the eastern portion of the building. One petroleum-related compound (toluene) was also detected above the Non- Residential IASL in sample AS-7. As noted previously, a Brownfields agreement was completed for the Site in July 2014. The Brownfields agreement included a provision that a work plan be submitted for DEQ approval for additional indoor air sampling as part of the post-Brownfields agreement activities. A plan for 6 S:\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Report\Additional Indoor Air Sampling Report.doc indoor air sampling was subsequently submitted to and approved by DEQ, and two additional rounds of sampling were completed in January 2015 and July 2015. During both rounds of sampling, soil vapor samples were collected concurrently with some of the indoor air sample locations. The results of analysis of the soil vapor samples collected in January and July 2015 indicated that PCE and/or TCE were detected above Non-Residential SGSLs in sample AS-3 collected from the far western portion of the building. No other compounds were detected above the Non- Residential SGSLs. The results of analysis of the indoor air samples collected in January and July 2015 indicated that no CVOCs were detected at concentrations above the Non-Residential IASL with the exception of 1,2-dichloroethane (1,2-DCA) and TCE. TCE and 1,2-DCA were detected above the Non- Residential IASL in the sample collected in the IMET office area (AS-1), and TCE was detected above the Non-Residential IASL in the sample collected from the far northwestern corner of the building (AS-3) and norther wall of the building (AS-5). It should be noted that the 2015 sample designations do not necessarily correspond to the same locations where samples with the same sample designations were collected in 2011 and/or 2012. Several other VOCs were detected in the samples above Non-Residential IASLs including toluene, benzyl chloride, and ethyl acetate in the Achem space, and benzyl chloride, chloromethane, and ethyl acetate in the IMET offices. Many of the non-chlorinated VOCs (including compounds detected above Non-Residential IASLs) were detected at concentrations greater than the soil vapor concentrations indicating that the presence of the non-chlorinated VOCs is primarily attributable to indoor air sources and not soil vapor intrusion. 2018 Indoor Air Sampling Work Plan Based upon discussions with DEQ Brownfields during due diligence for purchase of the Site by IMET Properties LLC, DEQ requested that an additional round of indoor samples be collected because of the time since completion of the 2015 samples and the possible influence of work place products on the previous indoor air sampling results. 7 S:\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Report\Additional Indoor Air Sampling Report.doc In November 2017, H&H and IMET personnel met at the Site to review Site conditions and the locations of proposed indoor air samples. In January 2018, H&H submitted a work plan for additional indoor sampling, and the work plan was revised in March 2018 based upon DEQ comments. As part of the work plan preparation, H&H conducted a review of compounds that are being used by IMET and Achem that appeared to have affected the previous indoor air sample data. IMET uses small quantities of various substances which generally include the alloy material, welding gases, sulfuric acid (used to neutralize the waste oil), oils and fuels, and cleaners. IMET uses multiple petroleum-related compounds in its operations including oils (honing, hydraulic, lubricating, cutting), xylenes, mineral spirits, adhesives, paints, and fuels. Achem uses small quantities of chemicals such as petroleum-based printing inks, printing cleaners, and lubricants. Furthermore, the facility cuts and prints on adhesive tape which contains products such as acetates. Achem uses petroleum related products (WD-40, toluene, release coats, and inks) and propanol and propyl acetate. Our review of the previous indoor air data, soil vapor data, and product inventory indicated that the products used by IMET and Achem contain compounds of concern which have been detected in indoor air at the facility including, but not limited to, aromatics (i.e., toluene, xylenes, etc.), naphthalenes, acetone, cyclohexane, heptane, and hexane. Many of these compounds have been detected in indoor air at concentrations greater than soil vapor confirming that they are from an indoor air source. Based upon our evaluation, it is very likely that most of the non-chlorinated VOCs previously detected in indoor air in the Site building are associated with use at the facility and not from vapor intrusion. As such, in the 2018 indoor air sampling work plan, H&H proposed and DEQ approved analysis of the indoor air samples for the CVOCs of concern at the Site (see Section 2.1 below). The methods and results of the additional indoor air sampling conducted in 2018 are discussed in Section 2.0 below. In addition, the methods and results of well abandonment activities conducted concurrently with the indoor air sampling are provided in Section 3.0. 8 S:\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Report\Additional Indoor Air Sampling Report.doc 2.0 Indoor Air Sampling On June 12, 2018, H&H collected five indoor air samples from within the Site building. The locations of the samples are depicted in Figure 3 and were located in the following areas: • HHIA-A was collected in the Achem space (Area 4) • HHIA-B was collected in the southern portion of the building (Area 6) • HHIA-C was collected in the IMET offices (Area 1) • HHIA-D was collected from the northwestern portion of the IMET solids processing area (Area 3) • HHIA-E was collected from the western portion of the IMET space which is currently vacant (Area 5) For quality assurance/quality control purposes one duplicate indoor air sample (DUP-1) was collected at the HHIA-D location. In addition, two background outdoor air samples were collected, one from near the main loading dock near the southeastern portion of the building (HHBA-A) and one from an upwind location outside the IMET and Achem offices (HHBA-B). The locations of the indoor air and background samples are indicated in Figure 3. 2.1 Indoor Air Sampling Methodology The indoor and background air samples were collected using laboratory-supplied, 6-liter stainless steel Summa canisters connected to in-line flow controllers with a built-in vacuum gauge. A 3-ft long laboratory-supplied sampling cane was also connected to the flow controller so that the sample intake point was positioned approximately 5 ft above grade (typical breathing zone height). The flow controller was set by the laboratory to allow for the samples to be collected over an approximate 8-hr period. The samples were collected during normal business hours and conditions, the HVAC was operational within the IMET and Achem offices, and mechanical ventilation fans operated in accordance with normal operating conditions. 9 S:\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Report\Additional Indoor Air Sampling Report.doc Following set-up of the Summa canisters, the airflow regulator sample valves were opened and the air samples were collected over an approximate 8-hour period. As part of the sampling event, H&H periodically measured exterior wind speed and direction, indoor and outdoor temperature, and indoor/outdoor air pressure differential. A tabular summary of the results of the field measurement data (including temperature, barometric pressure, wind direction and speed, and differential pressure) collected during the sampling is included in Table 1. As shown in Table 1, the outdoor pressure was measured to be higher relative to the indoor pressure during the sampling event. Differential pressure readings during sampling ranged from 0.002 inches of water to 0.005 inches of water. Higher outdoor pressure as compared to indoor pressure may increase the likelihood of vapor intrusion; as such, the samples were collected under an expected “worst case” condition. As also shown in Table 1, the indoor air temperature ranged from 72 degrees Fahrenheit (oF) to 76oF while the outdoor air temperature ranged from 68oF to 75oF. At the end of the 8-hour sample period, the sample canisters valves were closed and shipped under standard chain-of-custody protocol to Pace Analytical Laboratory (Pace) for analysis of select VOCs by EPA Method TO-15. In accordance with the approved work plan, the CVOCs selected for analysis were the compounds detected during the previous sub-slab vapor sampling conducted at the Site including tetrachloroethene (PCE), trichloroethene (TCE), carbon tetrachloride, 1,1-dichloroethane, 1,1-dichloroethene, 1,2-dichloroethane, cis-1,2-dichloroethene, trans-1,2-dichloroethene, vinyl chloride, and 1,1,2,2-tetrachloroethane. In general accordance with the DWM Vapor Intrusion Guidance, H&H also completed the DEQ Indoor Air Building Survey and Sampling Form during the sampling event which includes, among other items, an inventory of chemicals in the Site building. The completed DEQ Indoor Air Building Survey and Sampling Form is provided as Appendix A. 2.2 Indoor Air Sampling Results The indoor air analytical results were compared to the February 2018 DEQ Non-Residential Indoor Air Screening Levels (IASLs). A tabular summary of the indoor and background air 10 S:\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Report\Additional Indoor Air Sampling Report.doc sample laboratory analytical results is provided in Table 2, and the laboratory analytical data are provided in Appendix B. The laboratory analytical results indicate that concentrations of CVOCs were either not detected above the laboratory method detection limit (MDL) or were below the Non-Residential IASLs, with the exception of TCE. TCE was detected in one sample located within Area 3 (HHIA-D) as well as the duplicate air sample of HHIA-D (labeled DUP-1) at concentrations of 3.9 µg/m3 and 4.3 µg/m3, respectively, which are above the DEQ Non-Residential IASL of 1.8 µg/m3. HHIA-D was collected in the northwestern portion of the building where the highest concentrations of CVOCs have previously been detected. Other compounds detected in the June 2018 samples below Non-Residential IASLs were PCE, TCE, and/or cis-1,2-dichloroethene (cis-1,2-DCE) in samples HHIA-C and HHIA-D. CVOCs were not detected above the MDL in samples HHIA-A, HHIA-B, HHIA-E, or either of the two background samples. As indicated in Table 2, since modifications to the building were completed in 2011 to reduce vapor intrusion potential (i.e., filling in pits, filling floor gaps and sealing floor), concentrations of CVOCs have generally been stable to decreasing over time. As such, it is unlikely that indoor air concentrations will increase in the future. For quality assurance/quality control purposes, a field duplicate sample (DUP-1) was collected in accordance with the approved work plan to evaluate the precision of the field sampling procedures, sample matrix variability, and analytical reproducibility. The duplicate sample was collected using a sample “T” such that the indoor air sample (HHIA-D) and duplicate sample were collected simultaneously. The duplicate sample results were comparable to the results of HHIA-D which indicate good analytical repeatability. The results for DUP-1 are provided in Table 2. 11 S:\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Report\Additional Indoor Air Sampling Report.doc 2.3 Cumulative Risk Calculations The IASLs are conservative screening levels that are based upon a Lifetime Incremental Cancer Risk (LICR) of 1 x 10-6 for potential carcinogenic effects and a Hazard Index (HI) of 0.2 for potential non-carcinogenic effects. Vapor intrusion mitigation for occupied industrial/ commercial structures is not typically considered unless the LICR exceeds 1 x 10-4 and/or the HI exceeds 1. To further assess the detected indoor air concentrations, H&H used DEQ’s Vapor Intrusion Indoor Air Risk Calculator to calculate the cumulative risks using the CVOCs detected in indoor air sample HHIA-D and its duplicate DUP-1. A copy of the risk calculations is provided in Appendix C and the calculated LICRs and HI values are summarized below. Sample ID Date Sample Location Non-Residential LICR HI HHIA-D 6/12/18 Area 3 1.7 x 10-6 0.55 DUP-1 6/12/18 Area 3 1.9 x 10-6 0.60 As noted above, the calculated LICR for indoor air sample HHIA-D/DUP-1 ranged from 1.7 x 10-6 to 1.9 x 10-6 which are within the acceptable risk range of 1 x 10-4 to 1 x 10-6. The calculated non-carcinogenic HI values ranged from 0.55 to 0.60, which are below the acceptable threshold level of 1. For comparison purposes, H&H also calculated cumulative risks for the Site CVOCs detected in the 2015 to 2018 sampling events for samples collected in Areas 1 and 3 where the highest concentrations of compounds have been detected. A summary of those risk calculations is provided below: 12 S:\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Report\Additional Indoor Air Sampling Report.doc Sample ID Date Sample Location Non-Residential LICR HI AS-1 1/22/15 Area 1 1.5 x 10-6 0.47 AS-1 7/27/15 Area 1 1.6 x 10-6 0.52 HHIA-C 6/12/18 Area 1 7.2 x 10-8 0.019 AS-3 1/22/15 Area 3 9.1 x 10-7 0.29 AS-5 1/22/15 Area 3 1.3 x 10-6 0.42 AS-3 7/27/15 Area 3 4.5 x 10-7 0.14 AS-5 7/27/15 Area 3 1.4 x 10-6 0.45 HHIA-D 6/12/18 Area 3 1.7 x 10-6 0.55 DUP-1 6/12/18 Area 3 1.9 x 10-6 0.60 As indicated above, in the three sampling events conducted in January 2015, July 2015, and June 2018, cumulative LICRs calculated using detected CVOCs in the areas of highest compound concentrations were all within or below the acceptable LICR risk range of 1 x 10-4 to 1 x 10-6, and the calculated non-carcinogenic HI values were all been less than 1. 13 S:\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Report\Additional Indoor Air Sampling Report.doc 3.0 Well Abandonment On June 11, 2018, H&H oversaw the abandonment of monitoring wells and recovery wells at the Site by SAEDACCO, a licensed well contractor. In accordance with the Brownfields agreement for the Site, H&H submitted an e-mail request to DEQ Brownfields notifying DEQ of the well abandonment on January 31, 2018, and DEQ indicated that they had no objection to the well abandonment in an e-mail dated April 17, 2018. SAEDACCO abandoned the following 18 wells at the Site: MW-1, MW-2, MW4, MW-7, MW-9, MW-10, MW-10A, MW-11, MW-13, MW-14, MW-15, MW-17, MW-17A, MW-19, MW-20, MW22, RW-1, and RW-2. In addition, during the well abandonment activities, wells MW-8 and MW-12 were found to have been previously abandoned. As noted in the well abandonment request submitted to DEQ, H&H was unable to locate wells MW-3, MW- 5, MW-6, and MW-16, and these wells are presumed to have been lost or destroyed. The locations of the wells and the well abandonment records are provided in Appendix D. The wells were abandoned by removing and properly disposing of the surface completions of the wells and then tremie grouting the wells from the surface with cement grout. 14 S:\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Report\Additional Indoor Air Sampling Report.doc 4.0 Summary and Conclusions H&H conducted additional indoor air assessment and well abandonment activities at the Bloomsburg Mills Brownfields Site located at 3000 Stitt Street in Monroe, North Carolina. A summary of the recent and previous assessment results is provided below: • The results of the June 2018 indoor air sampling indicate that CVOCs were not detected in indoor air samples at concentrations above the MDL or the Non-Residential IASL, with the exception of TCE in one sample from the northwest portion of the building. TCE was detected in indoor air sample HHIA-D and its duplicate DUP-1 at concentrations of 3.9 µg/m3 and 4.3 µg/m3, respectively, which are above the conservative Non-Residential IASL of 1.8 µg/m3. • The results of cumulative risk calculations for HHIA-D/DUP-1 indicate that the cumulative LICR ranged from 1.7 x 10-6 to 1.9 x 10-6 which are within the acceptable risk range of 1 x 10-4 to 1 x 10-6. The calculated cumulative non-carcinogenic HI values ranged from 0.55 to 0.60, which are below the acceptable threshold level of 1. • Since modifications to the building were completed to 2011 to reduce vapor intrusion potential (i.e., filling in pits, filling floor gaps, and sealing floor), concentrations of CVOCs have generally been stable to decreasing over time. As such, it is unlikely that indoor air concentrations will increase in the future. In the three sampling events conducted in January 2015, July 2015, and June 2018, cumulative LICRs calculated using detected CVOCs in the areas of highest compound concentrations have all been within or below the acceptable LICR risk range of 1 x 10-4 to 1 x 10-6, and calculated non- carcinogenic HI values have all been less than 1. • The monitoring wells and recovery wells at the Site have been properly abandoned. 15 S:\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Report\Additional Indoor Air Sampling Report.doc Based on the results of the indoor assessment activities which indicate stable to decreasing indoor air concentrations with time and the acceptable risk levels during the last three sampling events, vapor intrusion does not appear to pose a significant risk to current or future Site workers. As such, H&H does not recommend further evaluation of the vapor intrusion pathway for the Site building. Table 1 Summary of Indoor Air Sampling Field Measurement Data Former Bloomsburg Mills 3000 Stitt Street Monroe, North Carolina H&H Job No. IME-001 S:\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Tables\IA Data Tables June 2018.xlsx 8/22/2018 Table 1 (Page 1 of 1) Hart & Hickman, PC Time Temperature oF Differential Pressure (in Water) Temperature oF Wind Direction Wind Speed (mph) Barometric Pressure (in Hg) Precipitation (inches) 8:20 NA NA 68 From N 5 29.60 0.0010:03 NA NA 68 From N 4 29.59 0.0011:58 NA NA 73 From NNE 3 29.60 0.00 13:57 NA NA 74 From NNE 3 29.97 0.00 15:57 NA NA 75 From NNE 4 29.96 0.00 8:20 75 0.005 10:03 72 0.00411:58 75 0.00413:57 74 0.00315:57 74 0.0038:24 76 0.003 10:14 72 0.003 12:04 75 0.004 14:04 73 0.003 16:24 72 0.003 Notes:Information from on-site weather station set up by H&H on June 12, 2018 during indoor air sampling event. Positive differential pressure measurement indicates that pressure in the building was lower than the outside pressure. Differential pressure and temperature readings taken from location at approximately 2-hour intervals during the 8-hour sample collection NA = Not Applicable; mph = miles per hour Sample Location Indoor Outdoor Outdoor HHIA-D IMET Facility HHIA-A ACHEM Facility Table 2 Summary of Indoor and Background Air Analytical Data Former Bloomsburg Mills 3000 Stitt Street Monroe, North Carolina H&H Job No. IME-001 \\HHFS01\MasterFiles\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Tables\IA Data Tables June 2018.xlsx 8/22/2018 Table 2 (Page 1 of 1) Hart & Hickman, PC Area Indoor Air Sample ID Sample Location Sample Date Analytical Method Carbon Tetrachloride 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,1,2,2-Tetrachloroethane Tetrachloroethene Trichloroethene Vinyl ChlorideAS2*AS-2 10/17/2011 TO-15 <1.1 <1.4 <0.71 <1.4 <1.4 <1.4 <1.2 6.4 1.6 <0.45 AS-2*AS-2 7/6/2012 TO-15 <3.8 <4.9 <2.4 <4.8 <4.8 <4.8 <4.2 38.8 7.1 <1.5 556-04-AS-1(1-22)**AS-1 1/22/2015 TO-17 <0.41 <0.82 <0.16 <0.16 2.0 <0.16 <0.41 21.0 3.1 <0.41 GSS-05AS-1**AS-1 7/27/2015 TO-15 <0.44 <0.83 0.69 <0.17 2.1 <0.17 <0.42 25.2 3.3 <0.42 HHIA-C HHIA-C 6/12/2018 TO-15 <0.51 <0.34 <0.32 <0.38 <0.55 <0.47 <0.47 3.4 <0.43 <0.20 AS1*AS-1 10/17/2011 TO-15 <1.1 <1.4 <0.71 <1.4 2.9 <1.4 <1.2 22.3 6.2 <0.45 AS-1*AS-1 7/6/2012 TO-15 <1.1 <1.4 <0.69 <1.4 5.1 <1.4 <1.2 43.0 7.1 <0.44 AS3*AS-3 10/17/2011 TO-15 <1.1 <1.4 <0.68 <1.3 1.9 <1.3 <1.2 14.1 2.4 <0.43 AS-3*AS-3 7/6/2012 TO-15 <1.1 <1.4 <0.69 <1.4 6.7 <1.4 <1.2 58.1 9.9 <0.44 AS4*AS-4 10/17/2011 TO-15 <1.1 <1.4 <0.68 <1.3 2.3 <1.3 <1.2 14.5 5.4 <0.43 AS-4*AS-4 7/6/2012 TO-15 <1.1 <1.4 <0.69 <1.4 3.7 <1.4 <1.2 31.8 3.3 <0.44 556-04-AS-3(1-22)**AS-3 1/22/2015 TO-17 <0.39 <0.79 <0.16 <0.16 1.4 <0.16 <0.39 11.4 2.0 <0.39 556-04-AS-5(1-22)**AS-5 1/22/2015 TO-17 <0.40 <0.79 <0.16 <0.16 1.8 <0.16 <0.40 15.8 2.9 <0.40 GSS-05AS-3**AS-3 7/27/2015 TO-15 <0.44 <0.83 <0.29 <0.17 0.63 <0.17 <0.42 6.7 0.91 <0.42 GSS-05AS-5**AS-5 7/27/2015 TO-15 <0.44 <0.83 <0.29 <0.17 2.0 <0.17 <0.42 24.6 2.7 <0.42 HHIA-D HHIA-D 6/12/2018 TO-15 <0.50 <0.33 <0.31 <0.37 2.3 <0.47 <0.46 18.8 3.9 <0.20 DUP-1 DUP-1 6/12/2018 TO-15 <0.51 <0.34 <0.32 <0.38 2.9 <0.47 <0.47 19.8 4.3 <0.20 AS7*AS-7 10/17/2011 TO-15 <1.1 <1.4 <0.71 <1.4 <1.4 <1.4 <1.2 4.5 <0.95 <0.45 AS-7*AS-7 7/6/2012 TO-15 <1.1 <1.4 <0.69 <1.4 <1.4 <1.4 <1.2 18.8 2.4 <0.44 556-04-AS-2(1-22)**AS-2 1/22/2015 TO-17 <0.41 <0.83 <0.17 <0.17 <0.17 <0.17 <0.41 <0.41 <0.41 <0.41 GSS-05AS-2**AS-2 7/27/2015 TO-15 <0.44 <0.83 <0.29 <0.17 <0.17 <0.17 <0.42 0.85 <0.42 <0.42 HHIA-A HHIA-A 6/12/2018 TO-15 <0.52 <0.35 <0.32 <0.39 <0.56 <0.48 <0.48 <0.47 <0.44 <0.21 AS8*AS-8 10/21/2011 TO-15 <1.2 <1.5 <0.74 <1.5 <1.5 <1.5 <1.3 1.9 <0.99 <0.47 AS-8*AS-8 7/6/2012 TO-15 <1.0 <1.3 <0.66 <1.3 <1.3 <1.3 <1.1 1.8 3.2 <0.42 HHIA-E HHIA-E 6/12/2018 TO-15 <0.58 <0.39 <0.36 <0.43 <0.62 <0.54 <0.53 <0.53 <0.49 <0.23 AS5*AS-5 10/17/2011 TO-15 <1.1 <1.4 <0.71 <1.4 <1.4 <1.4 <1.2 4.2 1.4 <0.45 AS-5*AS-5 7/6/2012 TO-15 <1.1 <1.4 <0.69 <1.4 <1.4 <1.4 <1.2 4.0 1.1 <0.44 556-04-AS-4(1-22)**AS-4 1/22/2015 TO-17 <0.40 <0.79 <0.16 <0.16 0.68 <0.16 <0.40 5.0 0.96 <0.40 GSS-05AS-4**AS-4 7/27/2015 TO-15 <0.44 <0.83 <0.29 <0.17 0.22 <0.17 <0.42 22.6 0.46 <0.42 HHIA-B HHIA-B 6/12/2018 TO-15 <0.50 <0.33 <0.31 <0.37 <0.54 <0.47 <0.46 <0.45 <0.42 <0.20 AS6*AS-6 10/21/2011 TO-15 <1.2 <1.5 <0.74 <1.5 <1.5 <1.5 <1.3 <1.2 <0.99 <0.47 AS-6*AS-6 7/6/2012 TO-15 <1.1 <1.4 <0.69 <1.4 <1.4 <1.4 <1.2 4.6 <0.92 <0.44 556-04-AS-6(1-22)**AS-6 1/22/2015 TO-17 <0.45 <0.90 <0.18 <0.18 0.80 <0.18 <0.45 7.1 1.3 <0.45 GSS-05AS-6**AS-6 7/27/2015 TO-15 0.63 <0.83 <0.29 <0.17 <0.17 <0.17 <0.41 2.4 <0.41 <0.41 HHBA-A HHBA-A 6/12/2018 TO-15 <0.92 <0.61 <0.57 <0.68 <0.98 <0.85 <0.84 <0.83 <0.77 <0.36 HHBA-B HHBA-B 6/12/2018 TO-15 <0.56 <0.37 <0.35 <0.41 <0.60 <0.52 <0.51 <0.50 <0.47 <0.22 2.0 7.7 0.47 180 NS NS 0.21 35 1.8 28 Notes: 1) North Carolina Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Non-Residential Indoor Air Screening Levels (IASLs) dated February 2018 (TCR = 1.0E-06 and THQ = 0.2) Bold indicates concentration exceeds DWM Non-Residential IASL (February 2018) * = collected by Resolve Environmental Services, PLLC and analyzed by Pace Analytical Services, Inc. ** = collected by Harmon Environmental, PA and analyzed by Pace Analytical Services, Inc. Concentrations are presented in micrograms per cubic meter (μg/m3) NS = Not Specified; BG = Background For 2018 samples, because the laboratory was requested to report J-flagged values, non-detects are reported less than the method detection limit. All other non-detects are reported to less than the sample reporting limit. 1 3 4 BG Non-Residential IASL(1) 5 6 7 0 2000 4000 APPROXIMATE SCALE IN FEETN U.S.G.S. QUADRANGLE MAP QUADRANGLE 7.5 MINUTE SERIES (TOPOGRAPHIC) Wingate, North Carolina 2002 TITLE PROJECT SITE LOCATION MAP FORMER BLOOMSBURG MILL3000 STITT STREET MONROE, NORTH CAROLINA DATE: JOB NO: REVISION NO: FIGURE: 06-29-2018 0 1IME-001 SITE REVISION NO. 0 JOB NO. IME-001 DATE: 4-20-17 FIGURE NO. 2 FORMER BLOOMSBURG MILL 3000 STITT STREET MONROE, NORTH CAROLINA DETAILED SITE MAP LEGEND SITE PROPERTY BOUNDARY PAD-MOUNTED TRANSFORMER 2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 Geology ACHEM STITT STRE E T OUT OF USE WATER TANK IMET OFFICES ACHEM OFFICES PARKING PARKING TAPE PRINTER NICKEL TORCH SHOT BLASTER MAINTENANCE TITANIUM TORCH NICKEL CRUSHING FORMER TEXTILES DYEING AREAS USED OIL AST SHIPPINGNICKEL WASHNICKEL SOLIDSTITANIUM SOLIDS(2) FORMER 20,000-GAL. USTs FORMER 30,000-GAL. UST S:\AAA-Master Projects\Imet Alloys\Figures\Detailed Site Map.dwg, FIG 3, 4/20/2017 1:36:23 PM, zbarlow REVISION NO. 0 JOB NO. IME-001 DATE: 6-27-18 FIGURE NO. 3 FORMER BLOOMSBURG MILL 3000 STITT STREET MONROE, NORTH CAROLINA PREVIOUS SOIL GAS & INDOOR AIR & 2018 INDOOR AIR SAMPLE LOCATIONS LEGEND SITE PROPERTY BOUNDARY PAD-MOUNTED TRANSFORMER 2011 INDOOR AIR SAMPLE LOCATION 2011 SOIL GAS & INDOOR AIR SAMPLE LOCATION 2012 INDOOR AIR SAMPLE LOCATION 2015 SOIL GAS & INDOOR AIR SAMPLE LOCATION 2018 INDOOR AIR AND BACKGROUND SAMPLE LOCATION 2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 Geology ACHEM STITT STRE E T OUT OF USE WATER TANK IMET OFFICES ACHEM OFFICES PARKING PARKING TAPE PRINTER NICKEL TORCH SHOT BLASTER MAINTENANCE TITANIUM TORCH NICKEL CRUSHING FORMER TEXTILES DYEING AREAS USED OIL AST SHIPPINGNICKEL WASHNICKEL SOLIDSTITANIUM SOLIDS(2) FORMER 20,000-GAL. USTs FORMER 30,000-GAL. UST "AREA 2" "AREA 1" LOADING DOCKS (2) "AREA 4" "AREA 3""AREA 5" "AREA 6" "AREA 7" LOADING DOCKS (2) LOADING DOCKS (6) AS-8 AS-5 AS-6 AS-7 AS-2AS-1 AS-3 AS-4 AS-5 AS-6 AS-7 AS-2 AS-1 AS-3 AS-8 AS-4 AS-6 AS-4/ SS-4 AS-3/ SS-4 AS-5 AS-1/ SS-1 AS-2/ SS-2 HHIA-B HHIA-A HHIA-G HHIA-D/DUP-1 HHIA-E HHBA-A HHBA-B S:\AAA-Master Projects\Imet Alloys\Figures\Sample Location Map.dwg, FIG 3, 6/27/2018 9:30:25 AM, erichardson Appendix A DEQ Indoor Air Building Survey and Sampling Form S:\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Report\Additional Indoor Air Sampling Report.doc IMET 3/8/2017 1 3M Industrial Adhesives 3M Super 77 Multipurpose Adhesive Aiken Chemical Company Purple Power Industrial Strength Cleaner/Degreaser Airgas Carbon Dioxide Airgas Oxygen-Liquid/Gas Airgas Propane-Gas AirGas Compressed Air AirGas Argon Airgas Propylene-Gas Akzo Nobel Paints Devflex 4212 HP Acrylic Eggshell Alex C. Fergusson, LLC. 10% Defoamer (AFCO 1260) Alex C. Fergusson, LLC. Super Defoamer (AFCO 1072) Alex C. Fergusson, LLC. Super Alk HD (AFCO 5237) Alex C. Fergusson, LLC. Chelated Caustic (AFCO 5239) Alex C. Fergusson, LLC. Refinish Plus HD TW (AFCO 5755) Allison Abrasives, Inc. Resin & Rubber Resin Bonded Abrasive Products Alpha Resources Glass Wool Alpha Resources Quartz Wool (Fine and Filtering) Alpha Resources Alpha Dri (Magnesium Perchlorate, Anhydrone) Alpha Resources Alpha Solve l/Alpha Solve ll (Sodium Hydroxide) Alpha Resources Titanium Standards (O,N,H, and C) Alpha Resources Quartz Glass Alpha Resources Hand Tools and Metal Parts (ss, steel, iron, brass) Alpha Resources Borosilicate Glass Alpha Resources Ceramic (Quartz) Refractory Shapes Alpha Resources Alphacel lll (Tungsten) Alpha Resources Steel/Iron/SS (pin/chip/ring standards, tubes) AquaPhoenix Scientific, Inc. Sulfuric Acid, 1.0N (Titration kit) AquaPhoenix Scientific, Inc. Phenolphalein Indicator Solution (Titration kit) AquaPhoenix Scientific, Inc. Sulfuric Acid, 0.5N (Titration kit) AquaPhoenix Scientific, Inc. Sodium Hydroxide, 0.5N (Titration kit) AquaPhoenix Scientific, Inc. Sodium Thiosulfate Solution, 1N (Titration kit) AquaPhoenix Scientific, Inc. Hydrochloric Acid, 2.5N (Titration kit) AquaPhoenix Scientific, Inc. Hydrochloric Acid, 7.7N (Titration kit) ARC Technology ARC Cool 1200 Series (ATI TSAF Tngs) Armstrong World Industries Shine Keeper Ashburn Mike-O-Drill TP-60 Ashburn Chemical Technologies Petroleum Oil (Honing Oil) ATI Allvac Nickel-Base Alloys Supplier Product Appendix A IMET Alloys SDS Master listing Sorted Alphabetically by Supplier 3/8/2017 2 ATI Allvac Titanium-Base Alloys ATI Allvac Iron-Base Alloys ATI Allvac Cobalt-Base Alloys ATI Allvac Titanium Sponge Bengal UltraDust2X Fireant Killer Blaster Chemical Co. PB Penetrating Catalyst BP Lubricants Castrol Dexron III Mercon Camel Grinding Wheels 6NX35 Grinding wheel 8" X1" X 1" Castrol Industrial Hysol MB50 CETCO Energy Services, an MTI Company ACCOFLOC 350 Citgo Petroleum Corp. EP-2 Lithium Grease Clorox Company Formula 409 Clorox Company Cleaner disinfectant (pine cleaner) Color Place(dist. Wal-Mart Stores, Inc.) Aerosol Enamel, All Colors Cross Oil Packaging Industrial Hydrolic Fluid Ervin Industries AMASTEEL SHOT Exxon Mobil Corp.Mobil DTE 13M Exxon Mobil Corp.Mobilegear 629 Exxon Mobil Corp. Mobil DTE Oil Heavy Medium Exxon Mobil Corporation Delvac EL 50/50 Prediluted Coolant/Antifreeze Floor Sweep, Inc.Oil Based Sweeping Compound Fuchs Lubricants Co.Ecocool 206 (Carpenter Tngs) Gobain Abrasives 12V887 Chop Saw Wheel 14" X 1/8" X 1" Gojo Industries, Inc.Gojo Botanical Foam Handwash Gojo Industries, Inc.Gojo Supro Max Hand Cleaner Grainger 3HUT9- Glass Cleaner Blue H2O GmbH CL 3-2 H2O GmbH LA 1-1 H2O GmbH DF 4-1 H2O GmbH DF 3-1 H2O GmbH DF 2-1 H2O GmbH Defoamer E2 (5I, 25I) Haynes International Corrosion-Resistant/High-Temp Alloys Henkel Corporation Loctite High Performance Spray Adhesive Hess Corporation Gasoline, All Grades Houghton Canada Inc.HOCUT 795-B Impact Absorbents, Inc.Xsorb Acid Neutralizing Super Absorbent C3456 Industrial Solutions, Inc.Indusol Cleaner 245 Industrial Solutions, Inc.Indusol D-911 Industrial Solutions, Inc.Defoamer 7 Industrial Solutions, Inc.Indusol 1369 JAM Distributing Company JAM ME 100 LabChem Inc.Buffer Solution pH 10.00 LabChem Inc.Potassium Hydroxide, 50% w/v LabChem Inc.Conductivity Standard, 500 umho/cm Master Chemical Corp Trim E206 nd- Frisa Turnings Master Chemical Corporation Trim TC 239 (ATI Richburg Tngs) 3/8/2017 3 N/A- Titanium Dust Collector Titanium Dioxide Powder (waste product) NPS Corporation Oil Only Sorbent Pad D5253 Nu-Calgon Liquid Scale Dissolver Oil-Dri Corporation of america Granular Absorbent- GA Oil-Dri Corporation of america Polyolefin Melt Blown Absorbent Omega Engineering Inc. Buffer Solution pH 7.00 Packaging Service Crown Low Odor Mineral Spirits Packaging Service Crown Acetone Para-Chem Fusion Series Fusion X Wall Base Adhesive PCC Airfoils, LLC Nickel Alloy Castings Permatex, Inc Rust Treatment 1 gal. Pinnacle Oil Holdings, LLC Black Gold Vacuum Pump Oil PPG Industries Advantage 900 S/G-Pastel Base PPG Industries, Inc. Pitt-Tech Inhibitive Acrylic Primer Precision Fluids, Inc EPF 3310 Procter & Gamble Professional Dawn Professional Dish Detergent Quikrete Companies Hardscapes Play Sand Radiator Specialty Co. Liquid Wrench Multi-Use Lubricating oil Radiator Specialty Co. KWO3-14B Rector Seal RectorSeal Tru-Blu RTI International Titanium Alloy with Iron RTI International Titanium Alpha Alloy RTI International Titanium Aluminides RTI International Titanium Beta Alloy RTI International Titanium CP Family Rust-Oleum Corp. Pro LSPR 6pk Safety Yellow Rust-Oleum Corp. Ptouch 2X+ SSPR 6pk Semi-Gloss Black Rust-Oleum Corp. Strust Qt 2 pk Gloss Sunburst Rust-Oleum Corp. Rust-Oleum Professional Inverted Marking Paint Saint-Gobain Abrasives Aluminum Oxide Coated Abrasive (Sanding Belt)3UP56 Saint-Gobain Abrasives Coated Abrasive (Sanding Belt)2D556 Schaeffer's 411 Maxkool SS Seal-Krete Seal-Krete Epoxy-Shell 1000 Seymour of Sycamore Stripe Yellow Traffic Marker Paint Shell Eastern Trading (PTE) Ltd Diesel (ULSD/Gasoil) Sherwin-Williams Co. Rust Tough Rust Preventative Enamel Southern States Chemical Sulfuric acid Special Metals Corp. Inconel Alloys Sperian Eye & Face Protection, Inc.Replacement Eye Wash Bottle, 32 oz. Steco Corporation Tap Magic EP-Xtra Sunnyside Corporation Xylene (Xylol) Sunshine Makers, Inc.Simple Green Industrial Cleaner & Degreaser The Clorox Company Original Pine-Sol Multi-Surface Cleaner The Valspar Corporation VAL LX ZN MRK (zone marking paint) Titanium Industries Generic Titanium Metal Titanium Industries Generic Nickel-Base Alloys Tough Guy Bleach 3/8/2017 4 TW Metals Compamy, Inc. Nickel Alloys WD-40 Company WD-40 Aerosol Wyman-Gordon Company Titanium Alloys Zep Inc. Zep Streak-Free Glass Cleaner S:\AAA-Master Projects\Imet Alloys\2018 IA Sampling\Report\Additional Indoor Air Sampling Report.doc Achem 1 Odorized Propane WD- 40 N Propl Alchohol (N Propanol) N Propl Acetate Toluene Mayzo Release Coat Accudyne Test Markers All Propalin Consolvent Inks White Black 185 Red 485 Red Reflex Blue Process Blue 3435 Dk Green Consolv Green Yellow Achem SDS Master Listing Sorted Alphabetically by Product Product Appendix B Laboratory Analytical Report #=CL# July 02, 2018 LIMS USE: FR - BRETT LAWRENCE LIMS OBJECT ID: 92388290 92388290 Project: Pace Project No.: RE: Brett Lawrence Hart & Hickman 2923 South Tryon St. Suite 100 Charlotte, NC 28203 Former Bloomsburg Mills Dear Brett Lawrence: Enclosed are the analytical results for sample(s) received by the laboratory on June 13, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Godwin kevin.godwin@pacelabs.com Project Manager 1(704)875-9092 Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 17 #=CP# CERTIFICATIONS Pace Project No.: Project: 92388290 Former Bloomsburg Mills Minnesota Certification IDs 1700 Elm Street SE, Suite 200, Minneapolis, MN 55414- 2485 A2LA Certification #: 2926.01 Alabama Certification #: 40770 Alaska Contaminated Sites Certification #: 17-009 Alaska DW Certification #: MN00064 Arizona Certification #: AZ0014 Arkansas Certification #: 88-0680 California Certification #: 2929 CNMI Saipan Certification #:MP0003 Colorado Certification #: MN00064 Connecticut Certification #: PH-0256 EPA Region 8+Wyoming DW Certification #: via MN 027- 053-137 Florida Certification #: E87605 Georgia Certification #: 959 Guam EPA Certification #: MN00064 Hawaii Certification #: MN00064 Idaho Certification #: MN00064 Illinois Certification #: 200011 Indiana Certification #: C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky DW Certification #: 90062 Kentucky WW Certification #: 90062 Louisiana DEQ Certification #: 03086 Louisiana DW Certification #: MN00064 Maine Certification #: MN00064 Maryland Certification #: 322 Massachusetts Certification #: M-MN064 Michigan Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: MN00064 Montana Certification #: CERT0092 Nebraska Certification #: NE-OS-18-06 Nevada Certification #: MN00064 New Hampshire Certification #: 2081 New Jersey Certification #: MN002 New York Certification #: 11647 North Carolina DW Certification #: 27700 North Carolina WW Certification #: 530 North Dakota Certification #: R-036 Ohio DW Certification #: 41244 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon NwTPH Certification #: MN300001 Oregon Secondary Certification #: MN200001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification #: MN00064 South Carolina Certification #:74003001 Tennessee Certification #: TN02818 Texas Certification #: T104704192 Utah Certification #: MN00064 Virginia Certification #: 460163 Washington Certification #: C486 West Virginia DW Certification #: 9952 C West Virginia DEP Certification #: 382 Wisconsin Certification #: 999407970 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 17 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92388290 Former Bloomsburg Mills Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92388290001 HHIA-A Can#1486 TO-15 10 PASI-MMJL 92388290002 HHIA-B Can#2810 TO-15 10 PASI-MMJL 92388290003 HHIA-C Can#1284 TO-15 10 PASI-MMJL 92388290004 HHIA-D Can#2367 TO-15 10 PASI-MMJL 92388290005 HHIA-E Can#2350 TO-15 10 PASI-MMJL 92388290006 HHBA-A Can#1582 TO-15 10 PASI-MMJL 92388290007 HHBA-B Can#0730 TO-15 10 PASI-MMJL 92388290008 DUP-1 Can#0940 TO-15 10 PASI-MMJL REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 17 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92388290 Former Bloomsburg Mills Sample: HHIA-A Can#1486 Lab ID: 92388290001 Collected: 06/12/18 16:22 Received: 06/13/18 13:22 Matrix: Air Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit Analytical Method: TO-15TO15 MSV AIR Carbon tetrachloride ND ug/m3 06/15/18 15:43 56-23-51.0 1.64 1,1-Dichloroethane ND ug/m3 06/15/18 15:43 75-34-31.3 1.64 1,2-Dichloroethane ND ug/m3 06/15/18 15:43 107-06-20.67 1.64 1,1-Dichloroethene ND ug/m3 06/15/18 15:43 75-35-41.3 1.64 cis-1,2-Dichloroethene ND ug/m3 06/15/18 15:43 156-59-21.3 1.64 trans-1,2-Dichloroethene ND ug/m3 06/15/18 15:43 156-60-51.3 1.64 1,1,2,2-Tetrachloroethane ND ug/m3 06/15/18 15:43 79-34-51.1 1.64 Tetrachloroethene ND ug/m3 06/15/18 15:43 127-18-42.3 1.64 Trichloroethene ND ug/m3 06/15/18 15:43 79-01-60.90 1.64 Vinyl chloride ND ug/m3 06/15/18 15:43 75-01-40.43 1.64 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/02/2018 12:29 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 17 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92388290 Former Bloomsburg Mills Sample: HHIA-B Can#2810 Lab ID: 92388290002 Collected: 06/12/18 16:10 Received: 06/13/18 13:22 Matrix: Air Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit Analytical Method: TO-15TO15 MSV AIR Carbon tetrachloride ND ug/m3 06/15/18 16:19 56-23-51.0 1.58 1,1-Dichloroethane ND ug/m3 06/15/18 16:19 75-34-31.3 1.58 1,2-Dichloroethane ND ug/m3 06/15/18 16:19 107-06-20.65 1.58 1,1-Dichloroethene ND ug/m3 06/15/18 16:19 75-35-41.3 1.58 cis-1,2-Dichloroethene ND ug/m3 06/15/18 16:19 156-59-21.3 1.58 trans-1,2-Dichloroethene ND ug/m3 06/15/18 16:19 156-60-51.3 1.58 1,1,2,2-Tetrachloroethane ND ug/m3 06/15/18 16:19 79-34-51.1 1.58 Tetrachloroethene ND ug/m3 06/15/18 16:19 127-18-42.2 1.58 Trichloroethene ND ug/m3 06/15/18 16:19 79-01-60.86 1.58 Vinyl chloride ND ug/m3 06/15/18 16:19 75-01-40.41 1.58 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/02/2018 12:29 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 17 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92388290 Former Bloomsburg Mills Sample: HHIA-C Can#1284 Lab ID: 92388290003 Collected: 06/12/18 15:47 Received: 06/13/18 13:22 Matrix: Air Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit Analytical Method: TO-15TO15 MSV AIR Carbon tetrachloride ND ug/m3 06/15/18 16:54 56-23-51.0 1.61 1,1-Dichloroethane ND ug/m3 06/15/18 16:54 75-34-31.3 1.61 1,2-Dichloroethane ND ug/m3 06/15/18 16:54 107-06-20.66 1.61 1,1-Dichloroethene ND ug/m3 06/15/18 16:54 75-35-41.3 1.61 cis-1,2-Dichloroethene ND ug/m3 06/15/18 16:54 156-59-21.3 1.61 trans-1,2-Dichloroethene ND ug/m3 06/15/18 16:54 156-60-51.3 1.61 1,1,2,2-Tetrachloroethane ND ug/m3 06/15/18 16:54 79-34-51.1 1.61 Tetrachloroethene 3.4 ug/m3 06/15/18 16:54 127-18-42.2 1.61 Trichloroethene ND ug/m3 06/15/18 16:54 79-01-60.88 1.61 Vinyl chloride ND ug/m3 06/15/18 16:54 75-01-40.42 1.61 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/02/2018 12:29 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 17 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92388290 Former Bloomsburg Mills Sample: HHIA-D Can#2367 Lab ID: 92388290004 Collected: 06/12/18 16:02 Received: 06/13/18 13:22 Matrix: Air Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit Analytical Method: TO-15TO15 MSV AIR Carbon tetrachloride ND ug/m3 06/15/18 18:06 56-23-51.0 1.58 1,1-Dichloroethane ND ug/m3 06/15/18 18:06 75-34-31.3 1.58 1,2-Dichloroethane ND ug/m3 06/15/18 18:06 107-06-20.65 1.58 1,1-Dichloroethene ND ug/m3 06/15/18 18:06 75-35-41.3 1.58 cis-1,2-Dichloroethene 2.3 ug/m3 06/15/18 18:06 156-59-21.3 1.58 trans-1,2-Dichloroethene ND ug/m3 06/15/18 18:06 156-60-51.3 1.58 1,1,2,2-Tetrachloroethane ND ug/m3 06/15/18 18:06 79-34-51.1 1.58 Tetrachloroethene 18.8 ug/m3 06/15/18 18:06 127-18-42.2 1.58 Trichloroethene 3.9 ug/m3 06/15/18 18:06 79-01-60.86 1.58 Vinyl chloride ND ug/m3 06/15/18 18:06 75-01-40.41 1.58 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/02/2018 12:29 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 17 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92388290 Former Bloomsburg Mills Sample: HHIA-E Can#2350 Lab ID: 92388290005 Collected: 06/12/18 17:22 Received: 06/13/18 13:22 Matrix: Air Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit Analytical Method: TO-15TO15 MSV AIR Carbon tetrachloride ND ug/m3 06/15/18 18:42 56-23-51.2 1.83 1,1-Dichloroethane ND ug/m3 06/15/18 18:42 75-34-31.5 1.83 1,2-Dichloroethane ND ug/m3 06/15/18 18:42 107-06-20.75 1.83 1,1-Dichloroethene ND ug/m3 06/15/18 18:42 75-35-41.5 1.83 cis-1,2-Dichloroethene ND ug/m3 06/15/18 18:42 156-59-21.5 1.83 trans-1,2-Dichloroethene ND ug/m3 06/15/18 18:42 156-60-51.5 1.83 1,1,2,2-Tetrachloroethane ND ug/m3 06/15/18 18:42 79-34-51.3 1.83 Tetrachloroethene ND ug/m3 06/15/18 18:42 127-18-42.5 1.83 Trichloroethene ND ug/m3 06/15/18 18:42 79-01-61.0 1.83 Vinyl chloride ND ug/m3 06/15/18 18:42 75-01-40.48 1.83 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/02/2018 12:29 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 17 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92388290 Former Bloomsburg Mills Sample: HHBA-A Can#1582 Lab ID: 92388290006 Collected: 06/12/18 17:27 Received: 06/13/18 13:22 Matrix: Air Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit Analytical Method: TO-15TO15 MSV AIR Carbon tetrachloride ND ug/m3 06/15/18 19:18 56-23-51.8 2.88 1,1-Dichloroethane ND ug/m3 06/15/18 19:18 75-34-32.4 2.88 1,2-Dichloroethane ND ug/m3 06/15/18 19:18 107-06-21.2 2.88 1,1-Dichloroethene ND ug/m3 06/15/18 19:18 75-35-42.3 2.88 cis-1,2-Dichloroethene ND ug/m3 06/15/18 19:18 156-59-22.3 2.88 trans-1,2-Dichloroethene ND ug/m3 06/15/18 19:18 156-60-52.3 2.88 1,1,2,2-Tetrachloroethane ND ug/m3 06/15/18 19:18 79-34-52.0 2.88 Tetrachloroethene ND ug/m3 06/15/18 19:18 127-18-44.0 2.88 Trichloroethene ND ug/m3 06/15/18 19:18 79-01-61.6 2.88 Vinyl chloride ND ug/m3 06/15/18 19:18 75-01-40.75 2.88 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/02/2018 12:29 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 17 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92388290 Former Bloomsburg Mills Sample: HHBA-B Can#0730 Lab ID: 92388290007 Collected: 06/12/18 15:30 Received: 06/13/18 13:22 Matrix: Air Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit Analytical Method: TO-15TO15 MSV AIR Vinyl chloride ND ug/m3 06/15/18 20:28 75-01-40.46 1.75 1,1-Dichloroethene ND ug/m3 06/15/18 20:28 75-35-41.4 1.75 1,1-Dichloroethane ND ug/m3 06/15/18 20:28 75-34-31.4 1.75 cis-1,2-Dichloroethene ND ug/m3 06/15/18 20:28 156-59-21.4 1.75 1,2-Dichloroethane ND ug/m3 06/15/18 20:28 107-06-20.72 1.75 Carbon tetrachloride ND ug/m3 06/15/18 20:28 56-23-51.1 1.75 Trichloroethene ND ug/m3 06/15/18 20:28 79-01-60.96 1.75 Tetrachloroethene ND ug/m3 06/15/18 20:28 127-18-42.4 1.75 1,1,2,2-Tetrachloroethane ND ug/m3 06/15/18 20:28 79-34-51.2 1.75 trans-1,2-Dichloroethene ND ug/m3 06/15/18 20:28 156-60-51.4 1.75 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/02/2018 12:29 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 17 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92388290 Former Bloomsburg Mills Sample: DUP-1 Can#0940 Lab ID: 92388290008 Collected: 06/12/18 00:00 Received: 06/13/18 13:22 Matrix: Air Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit Analytical Method: TO-15TO15 MSV AIR Carbon tetrachloride ND ug/m3 06/15/18 21:41 56-23-51.0 1.61 1,1-Dichloroethane ND ug/m3 06/15/18 21:41 75-34-31.3 1.61 1,2-Dichloroethane ND ug/m3 06/15/18 21:41 107-06-20.66 1.61 1,1-Dichloroethene ND ug/m3 06/15/18 21:41 75-35-41.3 1.61 cis-1,2-Dichloroethene 2.9 ug/m3 06/15/18 21:41 156-59-21.3 1.61 trans-1,2-Dichloroethene ND ug/m3 06/15/18 21:41 156-60-51.3 1.61 1,1,2,2-Tetrachloroethane ND ug/m3 06/15/18 21:41 79-34-51.1 1.61 Tetrachloroethene 19.8 ug/m3 06/15/18 21:41 127-18-42.2 1.61 Trichloroethene 4.3 ug/m3 06/15/18 21:41 79-01-60.88 1.61 Vinyl chloride ND ug/m3 06/15/18 21:41 75-01-40.42 1.61 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/02/2018 12:29 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 17 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92388290 Former Bloomsburg Mills Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 544972 TO-15 TO-15 TO15 MSV AIR Low Level Associated Lab Samples:92388290001, 92388290002, 92388290003, 92388290004, 92388290005, 92388290006, 92388290007, 92388290008 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK: 2963437 Associated Lab Samples: 92388290001, 92388290002, 92388290003, 92388290004, 92388290005, 92388290006, 92388290007, 92388290008 Matrix: Air Analyzed 1,1,2,2-Tetrachloroethane ug/m3 ND 0.70 06/15/18 11:08 1,1-Dichloroethane ug/m3 ND 0.82 06/15/18 11:08 1,1-Dichloroethene ug/m3 ND 0.81 06/15/18 11:08 1,2-Dichloroethane ug/m3 ND 0.41 06/15/18 11:08 Carbon tetrachloride ug/m3 ND 0.64 06/15/18 11:08 cis-1,2-Dichloroethene ug/m3 ND 0.81 06/15/18 11:08 Tetrachloroethene ug/m3 ND 1.4 MN06/15/18 11:08 trans-1,2-Dichloroethene ug/m3 ND 0.81 06/15/18 11:08 Trichloroethene ug/m3 ND 0.55 06/15/18 11:08 Vinyl chloride ug/m3 ND 0.26 06/15/18 11:08 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2963438LABORATORY CONTROL SAMPLE: LCSSpike 1,1,2,2-Tetrachloroethane ug/m3 63.969.8 92 70-146 1,1-Dichloroethane ug/m3 37.541.1 91 70-134 1,1-Dichloroethene ug/m3 34.440.3 85 70-137 1,2-Dichloroethane ug/m3 41.141.1 100 70-136 Carbon tetrachloride ug/m3 63.664 99 60-145 cis-1,2-Dichloroethene ug/m3 40.240.3 100 70-136 Tetrachloroethene ug/m3 66.568.9 96 70-133 trans-1,2-Dichloroethene ug/m3 38.740.3 96 70-132 Trichloroethene ug/m3 58.554.6 107 70-135 Vinyl chloride ug/m3 22.426 86 70-141 Parameter Units Dup Result QualifiersRPDResult 92388290003 2964127SAMPLE DUPLICATE: 1,1,2,2-Tetrachloroethane ug/m3 NDND 1,1-Dichloroethane ug/m3 NDND 1,1-Dichloroethene ug/m3 NDND 1,2-Dichloroethane ug/m3 NDND Carbon tetrachloride ug/m3 NDND cis-1,2-Dichloroethene ug/m3 NDND Tetrachloroethene ug/m3 3.5 33.4 trans-1,2-Dichloroethene ug/m3 NDND Trichloroethene ug/m3 NDND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/02/2018 12:29 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 17 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92388290 Former Bloomsburg Mills Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result QualifiersRPDResult 92388290003 2964127SAMPLE DUPLICATE: Vinyl chloride ug/m3 NDND Parameter Units Dup Result QualifiersRPDResult 92388290007 2964128SAMPLE DUPLICATE: 1,1,2,2-Tetrachloroethane ug/m3 NDND 1,1-Dichloroethane ug/m3 NDND 1,1-Dichloroethene ug/m3 NDND 1,2-Dichloroethane ug/m3 NDND Carbon tetrachloride ug/m3 NDND cis-1,2-Dichloroethene ug/m3 NDND Tetrachloroethene ug/m3 NDND trans-1,2-Dichloroethene ug/m3 NDND Trichloroethene ug/m3 NDND Vinyl chloride ug/m3 NDND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/02/2018 12:29 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 17 #=QL# QUALIFIERS Pace Project No.: Project: 92388290 Former Bloomsburg Mills DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - MinneapolisPASI-M ANALYTE QUALIFIERS The reporting limit has been raised in accordance with Minnesota Statutes 4740.2100 Subpart 8. C, D. Reporting Limit Evaluation Rule.MN REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/02/2018 12:29 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 17 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92388290 Former Bloomsburg Mills Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92388290001 544972HHIA-A Can#1486 TO-15 92388290002 544972HHIA-B Can#2810 TO-15 92388290003 544972HHIA-C Can#1284 TO-15 92388290004 544972HHIA-D Can#2367 TO-15 92388290005 544972HHIA-E Can#2350 TO-15 92388290006 544972HHBA-A Can#1582 TO-15 92388290007 544972HHBA-B Can#0730 TO-15 92388290008 544972DUP-1 Can#0940 TO-15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/02/2018 12:29 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 17 Page 16 of 17 6/14/18 Page 17 of 17 Appendix C DEQ Risk Calculators DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: October 2017 Basis: June 2017 EPA RSL Table Site ID: Former Bloomsburg Mills Exposure Unit ID: HHIA-D CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 156-59-2 Dichloroethylene, 1,2-cis-2.3 -- 127-18-4 Tetrachloroethylene 18.8 4.7E+01 3.5E+01 4.0E-07 1.1E-01 79-01-6 Trichloroethylene 3.9 3.0E+00 1.8E+00 1.3E-06 4.5E-01 Cumulative: 1.7E-06 5.5E-01 All concentrations are in ug/m3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: October 2017 Basis: June 2017 EPA RSL Table Site ID: Former Bloomsburg Mills Exposure Unit ID: DUP-1 CAS #Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 156-59-2 Dichloroethylene, 1,2-cis-2.9 -- 127-18-4 Tetrachloroethylene 19.8 4.7E+01 3.5E+01 4.2E-07 1.1E-01 79-01-6 Trichloroethylene 4.3 3.0E+00 1.8E+00 1.4E-06 4.9E-01 Cumulative:1.9E-06 6.0E-01 All concentrations are in ug/m3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. Appendix D Well Abandonment Records Stefan Smith 3576A SAEDACCO Inc , , X 6-11-2018 Former Bloomsburg Mill 3000 Stitt Street Monroe, NC 28110 Union 34.985232 80.493770 RW2 100 8 25.3 110' 1 249 X Neat Cem.:2256lb ,Wtr:168gal. Sand Cem.:lb ,Wtr:gal. Bentonite.:30lb ,Wtr:gal. Tremie grouted approximately 300 gallons of portland/bentonite grout. 6/20/2018 Stefan Smith 3576A SAEDACCO Inc , , X 6-11-2018 Former Bloomsburg Mill 3000 Stitt Street Monroe, NC 28110 Union 34.985384 80.493782 MW14 21 2 17 1 >1 gallon X Neat Cem.:94lb ,Wtr:8gal. Sand Cem.:lb ,Wtr:gal. Bentonite.:3lb ,Wtr:gal. Tremie grouted approximately 6 gallons of portland/bentonite grout. 6/20/2018 Stefan Smith 3576A SAEDACCO Inc , , X 6-11-2018 Former Bloomsburg Mill 3000 Stitt Street Monroe, NC 28110 Union 34.985159 80.493761 MW11 31 2 17 1 >1 gallon X Neat Cem.:94lb ,Wtr:8gal. Sand Cem.:lb ,Wtr:gal. Bentonite.:3lb ,Wtr:gal. Tremie grouted approximately 6 gallons of portland/bentonite grout. 6/20/2018 Stefan Smith 3576A SAEDACCO Inc , , X 6-11-2018 Former Bloomsburg Mill 3000 Stitt Street Monroe, NC 28110 Union 34.985204 80.493583 MW15 29 2 17 1 >1 gallon X Neat Cem.:94lb ,Wtr:8gal. Sand Cem.:lb ,Wtr:gal. Bentonite.:3lb ,Wtr:gal. Tremie grouted approximately 6 gallons of portland/bentonite grout. 6/20/2018 Stefan Smith 3576A SAEDACCO Inc , , X 6-11-2018 Former Bloomsburg Mill 3000 Stitt Street Monroe, NC 28110 Union 34.985272 80.493411 MW17A 81 6 32 69' 1 51 Calcium hypochlorite 1oz X Neat Cem.:752lb ,Wtr:64gal. Sand Cem.:lb ,Wtr:gal. Bentonite.:10lb ,Wtr:gal. Tremie grouted approximately 99 gallons of portland/bentonite grout. 6/20/2018 Stefan Smith 3576A SAEDACCO Inc , , X 6-11-2018 Former Bloomsburg Mill 3000 Stitt Street Monroe, NC 28110 Union 34.985272 80.493411 MW17 18 2 15 1 >1 gallon X Neat Cem.:94lb ,Wtr:8gal. Sand Cem.:lb ,Wtr:gal. Bentonite.:3lb ,Wtr:gal. Tremie grouted approximately 6 gallons of portland/bentonite grout. 6/20/2018 Stefan Smith 3576A SAEDACCO Inc , , X 6-11-2018 Former Bloomsburg Mill 3000 Stitt Street Monroe, NC 28110 Union 34.985261 80.492983 MW20 30 2 20 1 >1 gallon X Neat Cem.:94lb ,Wtr:8gal. Sand Cem.:lb ,Wtr:gal. Bentonite.:3lb ,Wtr:gal. Tremie grouted approximately 9 gallons of portland/bentonite grout. 6/20/2018 Stefan Smith 3576A SAEDACCO Inc , , X 6-11-2018 Former Bloomsburg Mill 3000 Stitt Street Monroe, NC 28110 Union 34.983678 80.493400 MW22 38 2 25 1 >1 gallon X Neat Cem.:94lb ,Wtr:8gal. Sand Cem.:lb ,Wtr:gal. Bentonite.:3lb ,Wtr:gal. Tremie grouted approximately 12 gallons of portland/bentonite grout. 6/20/2018 Stefan Smith 3576A SAEDACCO Inc , , X 6-11-2018 Former Bloomsburg Mill 3000 Stitt Street Monroe, NC 28110 Union 34.983834 80.493760 MW10 38 2 19 1 >1 gallon X Neat Cem.:94lb ,Wtr:8gal. Sand Cem.:lb ,Wtr:gal. Bentonite.:3lb ,Wtr:gal. Tremie grouted approximately 12 gallons of portland/bentonite grout. 6/20/2018 Stefan Smith 3576A SAEDACCO Inc , , X 6-11-2018 Former Bloomsburg Mill 3000 Stitt Street Monroe, NC 28110 Union 34.9852834 80.493760 MW10A 80 6 4 70' N/A 1 78 Calcium hypochlorite 1oz X Neat Cem.:752lb ,Wtr:64gal. Sand Cem.:lb ,Wtr:gal. Bentonite.:10lb ,Wtr:gal. Tremie grouted approximately 104 gallons of portland/bentonite grout. 6/20/2018 Stefan Smith 3576A SAEDACCO Inc , , X 6-11-2018 Former Bloomsburg Mill 3000 Stitt Street Monroe, NC 28110 Union 34.983801 80.493940 MW9 37 2 21 1 >1 gallon X Neat Cem.:94lb ,Wtr:8gal. Sand Cem.:lb ,Wtr:gal. Bentonite.:3lb ,Wtr:gal. Tremie grouted approximately 12 gallons of portland/bentonite grout. 6/20/2018 Stefan Smith 3576A SAEDACCO Inc , , X 6-11-2018 Former Bloomsburg Mill 3000 Stitt Street Monroe, NC 28110 Union 34.984632 80.494046 MW4 25 2 12 1 >1 gallon X Neat Cem.:94lb ,Wtr:8gal. Sand Cem.:lb ,Wtr:gal. Bentonite.:3lb ,Wtr:gal. Tremie grouted approximately 8 gallons of portland/bentonite grout. 6/20/2018 Stefan Smith 3576A SAEDACCO Inc , , X 6-11-2018 Former Bloomsburg Mill 3000 Stitt Street Monroe, NC 28110 Union 34.984632 80.494046 MW1 23 2 12 1 >1 gallon X Neat Cem.:94lb ,Wtr:8gal. Sand Cem.:lb ,Wtr:gal. Bentonite.:3lb ,Wtr:gal. Tremie grouted approximately 8 gallons of portland/bentonite grout. 6/20/2018 Stefan Smith 3576A SAEDACCO Inc , , X 6-11-2018 Former Bloomsburg Mill 3000 Stitt Street Monroe, NC 28110 Union 34.984695 80.494278 MW7 13 2 8.5 1 >1 gallon X Neat Cem.:94lb ,Wtr:8gal. Sand Cem.:lb ,Wtr:gal. Bentonite.:3lb ,Wtr:gal. Tremie grouted approximately 4 gallons of portland/bentonite grout. 6/20/2018 Stefan Smith 3576A SAEDACCO Inc , , X 6-11-2018 Former Bloomsburg Mill 3000 Stitt Street Monroe, NC 28110 Union 34.9846975 80.494048 MW2 18 2 Unknown 1 X Neat Cem.:94lb ,Wtr:8gal. Sand Cem.:lb ,Wtr:gal. Bentonite.:3lb ,Wtr:gal. Well was an above grade and apparently hit by a vehicle or piece of equipment and was unable to gauge, poured approximately 4 gallons of portland/bentonite grout. 6/20/2018 Stefan Smith 3576A SAEDACCO Inc , , X 6-11-2018 Former Bloomsburg Mill 3000 Stitt Street Monroe, NC 28110 Union 34.985146 80.493833 MW13 15.5 2 Unknown 1 >1 X Neat Cem.:94lb ,Wtr:8gal. Sand Cem.:lb ,Wtr:gal. Bentonite.:3lb ,Wtr:gal. Tremie grouted approximately 4 gallons of portland/bentonite grout. 6/20/2018 Stefan Smith 3576A SAEDACCO Inc , , X 6-11-2018 Former Bloomsburg Mill 3000 Stitt Street Monroe, NC 28110 Union 34.985146 80.493833 MW19 14 2 9.9 1 >1 X Neat Cem.:94lb ,Wtr:8gal. Sand Cem.:lb ,Wtr:gal. Bentonite.:3lb ,Wtr:gal. Tremie grouted approximately 7 gallons of portland/bentonite grout. 6/20/2018 Stefan Smith 3576A SAEDACCO Inc , , X 6-12-2018 Former Bloomsburg Mill 3000 Stitt Street Monroe, NC 28110 Union 34.983667 80.493324 RW1 100 8 27.7 Unknown 20 239 Chlorine 1.5 oz X Neat Cem.:2256lb ,Wtr:168gal. Sand Cem.:lb ,Wtr:gal. Bentonite.:30lb ,Wtr:gal. Tremie grouted approximately 300 gallons of portland/bentonite grout. 6/20/2018