1203_Burke_JohnsRiver_CDLF_MSWLF_WQMR_20171017

2211 West Meadowview Rd.
Greensboro, NC 27407

tel: [phone]
fax: [phone]
www.JoyceEngineering.com

October 24, 2017

Jaclynne Drummond
Compliance Hydrogeologist
NC Department of Environmental Quality
Division of Waste Management - Solid Waste Section
2090 US Highway 70, Swannanoa, NC 28778

RE: Burke County, Johns River Landfill
Permit Number 12-03
Phase 1A C&D Expansion
First Semiannual Water Quality Monitoring Report of 2017
JOYCE Project No. 277.1801.12, Task 03

Dear Ms. Drummond;

On behalf of Burke County, we are submitting the First Semiannual Water Quality
Monitoring Report of 2017 for the Phase 1A C&D Landfill Expansion at the Johns River Waste
Management Facility, Permit # 12-03. If you have any questions or if we can provide any
additional information please call me at [phone]. Thank you.

Sincerely,
JOYCE ENGINEERING

Van Burbach, Ph.D., P.G.
Sr. Technical Consultant

Attachments:
NCDEQ EMRF
First Semiannual Water Quality Monitoring Report of 2017

cc: Miles Champion, Burke County

PREPARED FOR:
BOARD OF COMMISSIONERS
COUNTY OF BURKE
P.O. BOX 1486
MORGANTON, NORTH CAROLINA 28680

JOHNS RIVER WASTE MANAGEMENT FACILITY
PERMIT NO. 12-03
C&D EXPANSION - PHASE 1A

FIRST SEMIANNUAL WATER QUALITY MONITORING
REPORT OF 2017

OCTOBER 2017

PREPARED BY:

2211 WEST MEADOWVIEW ROAD, SUITE 101
GREENSBORO, NORTH CAROLINA 27407
NC LICENSE NUMBER C-0782
PHONE: [phone]
FAX: [phone]
JOYCE PROJECT NO. 277.1801.12

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River Landfill, Phase 1A, Permit No. 12-03 October 2017
i

First Semiannual Water Quality Monitoring Report of 2017
Johns River Waste Management Facility – Permit No. 12-03
C&D Expansion - Phase 1A
Burke County, North Carolina

TABLE OF CONTENTS

1.0 INTRODUCTION..............................................................................................................1 
1.1 Site Information ........................................................................................................................1 
1.2 Site Geology .............................................................................................................................1 
1.3 Regulatory Status .....................................................................................................................2 
2.0 FACILITY MONITORING PROGRAM .......................................................................2 
2.1 Groundwater Monitoring Program ...........................................................................................2 
2.2 Surface Water Monitoring Program .........................................................................................3 
3.0 FIRST SEMIANNUAL SAMPLING EVENT OF 2017 ................................................3 
3.1 Field Work ................................................................................................................................3 
3.2 Laboratory Analysis and Quality Control ................................................................................4 
4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSIS .....................................5 
4.1 Analytical Results for Inorganic Constituents ..........................................................................5 
4.2 Analytical Results for Organic Constituents ............................................................................6 
4.4 Analytical Results for Surface Water .......................................................................................6 
4.3 Statistical Analyses ...................................................................................................................6 
4.3.1 Statistical Methods and Background .................................................................................. 6 
5.0 HYDROGEOLOGICAL CONDITIONS ........................................................................6 
6.0 CONCLUSION ..................................................................................................................7 
7.0 REFERENCES ...................................................................................................................8 
9.0 ACRONYMS ......................................................................................................................9 

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River Landfill, Phase 1A, Permit No. 12-03 October 2017
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First Semiannual Water Quality Monitoring Report of 2017
Johns River Waste Management Facility – Permit No. 12-03
C&D Expansion - Phase 1A
Burke County, North Carolina

TABLE OF CONTENTS (CONTINUED)

Tables:
Table 1 Historical Groundwater Elevation Data
Table 2 Field Parameters Table 3 Quantified Detections of Groundwater and Surface Water Constituents
Table 4 Exceedances of Groundwater and Surface Water Standards Table 5 Quantified Detections in Additional Wells/Piezometers (LFG Delineation
Study)
Table 6 Exceedances in Additional Monitoring Wells/Piezometers (LFG Delineation Study)
Table 7 Hydraulic Gradients and Groundwater Flow Velocities

Figure:
Figure 1 Site Location Map

Drawing:
Drawing 1 Groundwater Surface Map

Appendices:
Appendix A Field Data Logs
Appendix B Laboratory Analytical Reports
Appendix C Historical Detected Groundwater Constituents
Appendix D Historical Detected Constituents in Additional Wells/ Piezometers
Appendix E Historical Detected Surface Water Constituents

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River Landfill, Phase 1A, Permit No. 12-03 October 2017
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1.0 INTRODUCTION
1.1 Site Information
The Johns River Waste Management Facility (JRWMF) is located in the north-central portion of
Burke County, north of Morganton, North Carolina. The 318-acre landfill property is bounded
by Lower Creek to the north and east, and the Catawba River to the south. The Catawba River
forms Lake Rhodhiss along the southeastern property line (Figure 1). Lake Rhodhiss is a long,
narrow lake formed by the Rhodhiss Hydroelectric Dam located approximately 12 miles
downstream of the landfill. The John’s River flows into the Catawba River near the southwest
corner of the landfill property. A Municipal Solid Waste (MSW) transfer facility is located in
the eastern half of the property. A site plan showing all the pertinent features of the facility is
provided in Drawing 1.

The site has rolling topography with elevations ranging from 975 feet to 1,150 feet above mean
sea level (MSL). The central portion is generally gently sloping and contains the higher
elevations; relatively steep slopes and significant drainage features are located around the
perimeter. The 100-year flood boundary extends onto the landfill property. The adjacent
property to the west of the Johns River Waste Management Facility consists of undeveloped,
heavily wooded land. Properties within 2,000 feet of the landfill boundary are covered by
surface water or are heavily wooded.

Burke County (the County) has operated a permitted Construction and Demolition (C&D)
disposal area on top of the closed portions of the MSW landfill since 1998. The C&D-over-
MSW waste disposal unit consists of 28 acres in the southwest corner of the landfill property.
The MSW landfill began operation in April 1988, but was closed in 1997 to comply with Rule
.1627(c)(10)(A) of the North Carolina Solid Waste Management Regulations (NCSWMR),
which regulate the MSW Landfills units that were not designed with a base liner and leachate
collection system. The results of the second semiannual sampling event for the C&D-over-MSW
landfill will be presented in a separate report.

A Permit to Construct for Phase 1A was issued in March 2014 and the County completed
construction of Phase 1A of the C&D landfill expansion in July 2014. A Permit to Operate for
Phase 1A was issued to the County by the North Carolina Department of Environment and
Natural Resources, now the Department of Environmental Quality (NCDEQ), on August 14,
2014. In accordance with the facility approved Water Quality Monitoring Plan (WQMP) dated
August 2012 (the WQMP), there are four groundwater monitoring wells designated as
compliance wells for Phase 1A: MW-21 (background), MW-20, MW-22S, and MW-38.

1.2 Site Geology
The JRWMF is in close proximity to the Brevard Shear Zone, and is underlain by highly
metamorphosed rocks including gneiss and schist, as well as calc-silicate rocks, felsic rocks, and
metavolcanic rocks. The dominant rock type at the facility is biotite-muscovite schist, as seen in
outcrops, boulders, and rock cores located on site. The structures within limited outcrops
indicate that these rocks are complexly-folded, with attitudes that vary from vertical to
horizontal. The site regolith is typical of the inner piedmont and consists mostly of silty sand,

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clayey sand, and sandy silt. The regolith is up to 100 feet thick and varies in thickness with
topography.

An abundance of rounded gravel, cobble, and boulder-sized alluvial deposits are exposed along
the banks of the Catawba River, which borders the site. The greatest accumulation of these
deposits is along the southwestern site boundary. These river deposits are 40 feet or more above
the current river elevation and have been described as ancient river terrace deposits.

1.3 Regulatory Status
The following report of groundwater monitoring data from the JRWMF Phase 1A C&D
expansion has been prepared in accordance with the NCSWMR 15A NCAC 13B §.0544
(Monitoring Plans and Requirements for C&D Landfill Facilities). The Phase 1A expansion is
currently operating under the Detection Monitoring Program.

2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
Groundwater monitoring at the JRWMF Phase 1A is performed in accordance with NCSWMR
§.0544. Groundwater samples are collected semiannually and analyzed for constituents
according to the WQMP. Following is a summary of the compliance monitoring wells.

Well ID Date
Installed Classification Monitoring
Program
Total Depth
of Well (ft)
Lithology of
Screened
Interval
Constituent
List
MW-20 5-18-95 Compliance Detection 67.0 Saprolite Comp.
MW-21 5-18-95 Background Detection 45.0 Saprolite Comp.
MW-22s 6-1-96 Compliance Detection 25.0 Saprolite Comp.
MW-38 5-09-11 Compliance/
Performance* Detection 71.0 Bedrock Comp., LFG
Notes: Comp. = Compliance Parameters: 40 CFR Part 258, Appendix I, incorporated by reference into the
NCSWMR (NC Appendix I) and/or 40 CFR Part 258, Appendix II, incorporated by reference into the
NCSWMR (NC Appendix II) organics and inorganics plus C&D parameters, as required for routine
assessment or detection monitoring.
LFG = Landfill Gas Indicators: Dissolved CH4 and dissolved CO2.
*MW-38 is also a performance well for the C&D-over-MSW Landfill.

As previously stated, the compliance groundwater monitoring network at the facility consists of
one upgradient well (MW-21), and three downgradient wells (MW-20, MW-22S and MW-38).
However, in January 2014, in response to the County’s permit application for the C&D
expansion area, the NCDEQ requested that additional wells and/or piezometers in the vicinity of
Phases 1 and 2 of the expansion been sampled. The County agreed to sample PZ-31, PZ-30S,
PZ-34, MW-36(PZ-36), PZ-12, and MW-15S semiannually beginning with the spring 2014
sampling event. The County also agreed to sample the following wells/piezometers in the event
of Groundwater Protection Standard (GPS) exceedances in the referenced wells/piezometers, as
follows:

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 PZ-30D will be added in the event that there are GPS exceedances at PZ-30S;
 PZ-35 will be added in the event that there are GPS exceedances at PZ-34;
 MW-15D will be added in the event that there are GPS exceedances at MW-15S;
 PZ-16S will be added in the event that there are GPS exceedances at PZ-35 or PZ-12;
and
 PZ-16D will be added in the event that there are GPS exceedances at PZ-16S.
 PZ-34 was inadvertently destroyed during the spring of 2014; therefore, PZ-35 is now
sampled instead.

The additional piezometers/wells are to be sampled for the facility’s contaminants of concern
(COCs) (excluding alpha-BHC and beta-BHC). Sampling of the additional piezometers/wells
will be conducted for two years (four sampling events), after which the NCDEQ will reevaluate
the need for continued sampling of the additional piezometers/wells.

2.2 Surface Water Monitoring Program
The current surface water monitoring points are SMP-5, SMP-6, and SMP-7. Surface water
monitoring point SMP-5 (located at the southwestern property line) and SMP-6 (located at the
southeastern property line) are both located downstream from existing sediment basins. Surface
water monitoring point SMP-7 is located downstream from the Phase 1A expansion area. The
surface water monitoring program is designed to monitor for possible impacts from both the
C&D over MSW Landfill and the Phase 1A C&D Landfill; surface water samples are analyzed
for the NC Appendix I list of constituents plus detected NC Appendix II constituents during both
semiannual events.

Surface Point Classification Monitoring
Program Location
SMP-5 Compliance Surface Water Creek on west side of landfill,
downstream of sediment basin.
SMP-6 Compliance Surface Water Creek on east side of landfill,
downstream of sediment basin.
SMP-7 Compliance Surface Water
Creek southeast of Phase 1A and
east of sediment basin SB-2A.
Downstream of PZ-12.

3.0 FIRST SEMIANNUAL SAMPLING EVENT OF 2017
3.1 Field Work
In order to detect potential releases of leachate and/or landfill gas migration in a timely manner,
a visual inspection program has been implemented at the JRWMF. This inspection program
involves field personnel making the following observations:
 Indications of stress on the biological community (e.g., dead or dying vegetation);
 Indications of leachate impact (e.g., seeps, impacted surface water);
 Observations of erosion;
 Condition of monitoring wells; and
 Negative changes around the waste facility.

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River Landfill, Phase 1A, Permit No. 12-03 October 2017
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Between June 27 and June 28, 2017, personnel from JOYCE Engineering (Joyce) visited the
JRWMF to purge and collect groundwater samples from monitoring wells MW-20, MW-21,
MW-22S, MW-38, MW-15S, PZ-12, PZ-30S, PZ-31, PZ-35, and PZ-36. Further, surface
monitoring points SMP-5, SMP-6, and SMP-7 were also sampled during the June 2017’s
sampling event. The usual inspections indicated no unusual issues or concerns.

Prior collecting the groundwater sample depth-to-water measurements were obtained to the
nearest 0.01 foot using an electronic water level indicator. Table 1 presents current and
historical groundwater elevation data. After measuring the depth-to-water and calculating the
well water volume, the monitoring wells were purged and sampled using disposable bailers.
Measurements of temperature, pH, specific conductivity, and turbidity were recorded in the site
log book as well as on field data logs prior to purging, after purging a well volume, and during
sampling. Field data logs for the June 2017 event are provided in Appendix A, and the field
parameters are summarized in Table 2.

Laboratory-supplied containers were prepared and labeled (either by the laboratory or in the
field, as indicated) with the following information:
 Monitoring well number (completed by field personnel),
 Date and time of sample collection (completed by field personnel),
 Initials of sampling personnel (completed by field personnel),
 Project name and number (completed by the laboratory),
 Chemical preservative (completed by the laboratory); and
 Requested chemical analysis (completed by the laboratory).

Groundwater samples from each monitoring well were dispensed directly from the disposable
bailers into the provided laboratory containers within 24 hours of the final purge volume.
Immediately after collection, the samples were placed in a laboratory-provided cooler and chilled
with ice.

Surface water samples were collected directly from stream flow by lowering the prepared sample
containers into the stream flow. Care was taken not the overflow the sample containers (which
could lead to preservative loss) and avoid sample-induced turbidity. At the time of sampling,
surface water was also measured for temperature, pH, specific conductivity, and turbidity and
recorded in the site log book. After sample collection, the samples were placed in a laboratory
provided cooler and chilled on ice. Field data logs are provided in Appendix A, and the field
parameters are summarized in Table 2.

3.2 Laboratory Analysis and Quality Control
The First Semiannual (June 2017) groundwater and surface water samples were submitted to
Pace Analytical Services, Inc. of Huntersville, North Carolina under chain-of-custody control for
analysis. The groundwater samples were analyzed for the NC Appendix I list of constituents,
plus additional required C&D parameters. Surface water samples were analyzed for the NC
Appendix I list of constituents (plus detected NC Appendix II constituents from the old C&D-
over-MSW landfill) during previous semiannual events. As a quality control measure, JOYCE
requested a Level II data report for the final laboratory report. As stated in the laboratory

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reports, the samples were received by the laboratory in good condition, properly preserved, and
within required hold times.

In addition to samples collected for compliance monitoring at the JRWMF and as a quality
control measure, a Field Blank was collected by JOYCE personnel as part of the June 2017’s
sampling event. Also, a Trip Blank prepared by the laboratory accompanied the volatile
sampling containers from and to the laboratory. The Field Blank was analyzed for the NC
Appendix I, plus previously detected NC Appendix II list of constituents, plus iron, manganese
and tetrahydrofuran, and the Trip Blank was analyzed for NC Appendix I list of constituents plus
additional detected NC Appendix II volatile organic compounds and tetrahydrofuran.

Upon receipt of the laboratory data package, JOYCE personnel reviewed the data package for
quality assurance/quality control (QA/QC) purposes and for possible regulatory issues. If any
QA/QC or regulatory issues were found, the laboratory would be contacted to resolve the issue,
and a resampling event might be scheduled, if needed. The laboratory analytical packages can
be found in Appendix B of this report. The data package was reviewed for the following:
 General typographical errors;
 Correct analyses performed and within method specified hold times;
 Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate,
and Laboratory Control Samples;
 Blank-qualified data (B-flags);
 Detections exceeding the North Carolina 15A NCAC 2L .0202 Groundwater Standards
(NC2L), NCDEQ-SWS Groundwater Water Protection Standards (GWPS), and North
Carolina 15A NCAC 2B Surface Water Standards (NC2B); and
 Detections that are above historical levels.

4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSIS
The constituents with quantified detections above the SWSL in one or more compliance
monitoring wells are presented in Table 3 and the constituents with exceedances of the NC2L
Standards or GWPS in one or more compliance monitoring wells are presented in Table 4. The
constituents with quantified detections above the North Carolina Solid Waste Section Reporting
Limits (SWSL) in one or more of the additional wells/piezometers are presented in Table 5 and
the constituents with exceedances of the NC2L Standards or GWPS in one or more additional
wells/piezometers are presented in Table 6. The complete laboratory reports and chains of
custody are included in Appendix B. Historical data for detected groundwater constituents,
detected constituents in the additional wells/piezometers and detected surface water constituents
are presented in Appendices C, D, and E, respectively.

4.1 Analytical Results for Inorganic Constituents
Two inorganic constituents were detected above the NC2L/GWPS in one or more monitoring
wells during the June 2017 sampling event. The constituents were the C&D landfill parameters
iron and manganese. Iron was reported above the NC2L Standard in MW-20, MW-21, MW-22S
and MW-38; and manganese was reported above the NC2L Standard in MW-20, MW-21, and
MW-38; however, an Alternate Source Demonstration (ASD) was approved for iron and
manganese by DENR for the Johns River facility on April 12, 2012; therefore, those

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River Landfill, Phase 1A, Permit No. 12-03 October 2017
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concentrations are not consider exceedance. In general, the detections and concentrations are
consistent with historical data.

4.2 Analytical Results for Organic Constituents
Four organic constituents, benzene, 1,1-dichloroethane, 1,4-dichlorobenzene, and vinyl chloride
were detected above the NC2L Standards in compliance monitoring well MW-38 during the June
2017 sampling event. In addition, results from the additional wells/piezometers indicated NC2L
exceedance of benzene and 1,4-dichlorobenzene in MW-36. No other exceedances were
reported. In general, the detections and concentrations are consistent with historical data and
display trends of decreasing concentrations over time.

4.4 Analytical Results for Surface Water
There were two constituents with quantified detections in the collected surface water samples
during the June 2017 sampling event (Table 3), Trichloroethene and Zinc. Trichloroethene was
detected in surface water SMP6 and Zinc was detected in surface waters SMP6 and SMP7;
nonetheless, only Zinc concentration detected in surface water sample SMP7 exceeded the NC2L
standard (Table 4). Current and historical surface water data can be found in Appendix E.

4.3 Statistical Analyses
4.3.1 Statistical Methods and Background

No statistical analyses were conducted for the June 2017 sampling event because there were no
exceedances of NC2L or GWPS for inorganic constituents that were not covered by a
previously-approved ASD.
5.0 HYDROGEOLOGICAL CONDITIONS
Based on outcrop and drilling information, the water table appears to occur within regolith
everywhere across the site. This regolith consists of alluvium, residual soils, saprolite, and
variably fractured and weathered layered metamorphic rock. Inspection of drill cuttings and site
outcrops indicates that water in the regolith is transmitted largely through fractures. In this
regard, regolith behaves similar to unweathered bedrock, except that fractures are more
numerous and better connected in the regolith, and will tend to have more isotropic hydraulic
properties. Along the low-lying areas of the Catawba River and its tributaries, the water table
occurs within surficial alluvial deposits overlying the residual soils and weathered bedrock.

Based on site hydrogeological site conditions, it is expected that Groundwater will discharge into
the creeks located to the east and west of the landfill and into the Catawba River located to the
south of the landfill. A groundwater potentiometric surface map, developed from static water
level data obtained in June 2017, is presented as Drawing 1. The potentiometric surface map
depicts groundwater flow primarily to the south.

Static groundwater depth was measured in the compliance monitoring wells at the site prior to
sampling. The June 2017, and historical groundwater elevations are provided in Table 1. The
groundwater elevations were calculated relative to the surveyed measuring point (top of casing)

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Burke County – Johns River Landfill, Phase 1A, Permit No. 12-03 October 2017
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for each monitoring well. Horizontal groundwater gradients along representative flow paths
were estimated from the June 2017 groundwater contours shown on Drawing 1 and are
summarized in Table 7. Horizontal gradients across the site ranged from 0.0367 to 0.0521 ft/ft,
with an average of approximately 0.0450 ft/ft. This is consistent with previous estimates.

Linear groundwater flow velocities for wells screened in saprolite were computed using the
modified Darcy equation:

V = Ki/n, where;

V = average linear velocity,
K = hydraulic conductivity,
i = horizontal hydraulic gradient, and
n = effective porosity.

The average of hydraulic conductivities from slug-tests conducted at the facility (K = 3.28 ft/day)
was used in these calculations, along with an effective porosity of n = 0.40 (40%) based on
laboratory porosities for soil samples from the facility. The estimated linear groundwater flow
velocity under the facility ranged from 110 -156 feet/year, with an average flow velocity of
approximately 134 feet/year (Table 7). The modified Darcy equation makes the simplified
assumptions of a homogeneous and isotropic aquifer.

The groundwater flow direction and rate have shown no significant seasonal variations over
several years of monitoring. The groundwater flow regime on this site is well constrained and
predictable. Migration of groundwater contaminants are expected to follow the general
groundwater flow paths and there are no known preferred pathways or barriers to groundwater
flow that could significantly affect plume migration or the effectiveness of the groundwater
monitoring network to monitoring plume migration. The current groundwater monitoring
network remains sufficient for monitoring the groundwater at this facility.

6.0 CONCLUSION
Benzene, 1,1-dichloroehane, 1,4-dichlorobenzene, and vinyl chloride were detected above their
respective NC2L standards in MW-38; however, a verification groundwater sample for vinyl
chloride in MW-38 indicated the presence of vinyl chloride at concentration below its NC2L
standard. Results from the additional wells/piezometers indicated NC2L exceedance of benzene
and 1,4-dichlorobenzene in MW 36. The exceedances noted in wells MW-36 and MW-38 are
believed to be due to landfill gas migration from the C&D-over-MSW Landfill and are being
addressed in the Corrective Action Plan for that landfill. No other organic constituents were
detected above the GPS in any of the Phase 1A compliance monitoring wells. These results are
consistent with historical data from the site.

Detections of inorganic constituents were consistent with historical data from previous sampling
events. An ASD was approved for iron and manganese by NCDEQ (formerly DENR) on April
12, 2012. No other inorganic constituents were detected above NC2L standards or GWPS.

Zinc was detected above the NC2B Standard in surface water sample SMP-7. If zinc remains
elevated in SMP-7 during future sampling events, we recommend sampling SMP-7 for dissolved

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metals and total dissolved solids (TDS). There were no other organic or inorganic detections
above the NC2B Surface Water Standards for surface water samples from the June 2017
sampling event.

The groundwater flow regime is consistent with previous events and the groundwater monitoring
network remains adequate to monitor the site. Based on analytical results from the June 2017
sampling event, Phase 1A of the Johns River Landfill will remain in Detection Monitoring. The
next semiannual sampling event is scheduled December of 2017.

7.0 REFERENCES
Hinchee, R.E., A. Leeson, L. Semprini, and S.K. Ong. 1994. Bioremediation of Chlorinated and
Polycyclic Aromatic Hydrocarbon Compounds. Lewis Publishers, Boca Raton.

Interstate Technology and Regulatory Cooperation Work Group (ITRC). September 1999.
Natural Attenuation of Chlorinated Solvents in Groundwater: Principles and Practices.
Technical/Regulatory Guidelines.

Interstate Technical Regulatory Council (ITRC). 2003. Technical and Regulatory Guidance
Document for Constructed Treatment Wetlands.

Joyce Engineering (JOYCE), 1994. Transition Plan, Johns River Waste Management Facility.
April 1994.

JOYCE, 2000. Water Quality Assessment Report, Johns River Waste Management Facility.
January 2000.

JOYCE, 2004. Update on Groundwater Assessment Activities, Johns River Waste Management
Facility. October 2004.

JOYCE, 2005a. Assessment of Corrective Measures Report, Johns River Waste Management
Facility. February 2005.

JOYCE, 2005b. Quantitative Risk Assessment, Johns River Waste Management Facility.
February 2005.

JOYCE, 2008. Corrective Action Plan, Johns River Waste Management Facility. June 2008.

JOYCE, 2011. Corrective Action Evaluation Report, Johns River Waste Management Facility.
May 2011.

JOYCE, 2013. Addendum to the Corrective Action Plan, Johns River Waste Management
Facility. August 2013.

JOYCE, 2016. Corrective Action Evaluation Report, Johns River Waste Management Facility.
April 2016.

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
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National Research Council (NRC), 2000. Natural Attenuation for Groundwater Remediation.
National Academy Press, Washington, D.C. pp. 108-111.

North Carolina Department of Environment, Health, and Natural Resources (NC-DENR), 1997.
North Carolina Solid Waste Management Rules. 15 NCAC 13B. January 1, 1997.

NC-DENR, 2007. North Carolina Solid Waste Section Guidelines for Corrective Action at Solid
Waste Management Facilities. March 2007.

Sumsion, C.T., and Laney, R.L., 1967, Geology and Ground-water Resources of the Morganton
area North Carolina. N.C. Department of Water Resources, Ground Water Bulletin No.
12, 119 p.

U.S. Department of Energy (USDE). May 1999. Decision-Making Framework Guide for the
Evaluation and Selection of Monitored Natural Attenuation Remedies at Department of
Energy Sites.

U.S. Environmental Protection Agency (USEPA), 1992. Statistical Analysis of Groundwater
Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance. July 1992.

USEPA. October 1988. Interim Final Guidance for Conducting Remedial Investigations and
Feasibility Studies under CERCLA. Office of Solid Waste and Emergency Response
(OSWER) Directive 9355.3-01, EPA/540/G-89/004.

USEPA. February 1991. Conducting Remedial Investigations/Feasibility Studies for CERCLA
Municipal Landfill Sites. OSWER Directive 9355.3-11, EPA/540/P-91/001.

USEPA. May 1995. How to Evaluate Alternative Cleanup Technologies for Underground
Storage Tank Sites: A Guide for Corrective Action Plan Reviewers. Chapters 2 (Soil
Vapor Extraction) and 10 (In-Situ Groundwater Bioremediation).

USEPA. May 1996. Seminars on Bioremediation of Hazardous Waste Sites: Practical
Approaches to Implementation. ORD, EPA/625/K-96/001. Chapters 15 (Natural
Attenuation of Groundwater) and 17 (Natural Attenuation of Landfills).

USEPA and U.S. Air Force (USAF). July 1993. Remediation Technologies Screening Matrix
Reference Guide, Version I. Joint Project of OSWER and Environics Directorate, PB93-
2118212.

9.0 ACRONYMS
ACM Assessment of Corrective Measures (Report)
AMSL Above Mean Sea Level
AOC Area of Concern
BGS Below Ground Surface
C&D Construction and Demolition Waste
CAP Corrective Action Plan (Report)
CAER Corrective Action Evaluation Report (Report)

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CAMP Corrective Action Monitoring Plan (Report)
CAS Chemical Abstracts Service
CFR Code of Federal Regulations
CPVC Chlorinated Poly Vinyl Chloride
COC Contaminant of Concern (for corrective action)
COC Chain of Custody (for sampling and lab reports)
DENR North Carolina Department of Environment and Natural Resources
DL Detection Limit (for laboratory data)
DO Dissolved Oxygen
EPA United States Environmental Protection Agency (or USEPA)
GWPS Groundwater Protection Standards (Established by DENR-SWS)
JOYCE Joyce Engineering
LFG Landfill Gas
MNA Monitored Natural Attenuation
MSW Municipal Solid Waste
MW Monitoring Well
NC2B North Carolina Surface Water Standards found in 15A NCAC 2B
NC2L North Carolina Groundwater Standards found in 15A NCAC 2L
NCAC North Carolina Administrative Code
NCGS North Carolina Geological Survey
NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600)
ND Not Detected (for laboratory data)
NES Nature and Extent Study (Report)
O&M Operations and Maintenance
QL Quantitation Limit (for laboratory data)
QRA Quantitative Risk Assessment (Report)
RL Reporting Limit (for laboratory data)
RQD Rock Quality Designation
SPT Standard Penetration Test
SSI Statistically Significant Increase (above background concentrations)
SWQS Surface Water Quality Standards
SWS Solid Waste Section (of DENR-Division of Waste Management)
SWSL North Carolina Solid Waste Section Reporting Limits
TOC Top of Casing (Well)
USCS Unified Soil Classification System
USEPA United States Environmental Protection Agency (or EPA)
USGS United States Geological Survey
VOC Volatile Organic Compound
WQMP Water Quality Monitoring Plan (Report)

TABLES

Table 1 Historical Groundwater Elevation Data
Table 2 Field Parameters
Table 3 Quantified Detections of Groundwater and Surface Water Constituents
Table 4 Exceedances of Groundwater and Surface Water Standards
Table 5 Quantified Detections in Additional Wells/Piezometers
Table 6 Exceedances in Additional Monitoring Wells/Piezometers
Table 7 Hydraulic Gradients and Groundwater Flow Velocities

TABLE 1: HISTORICAL GROUNDWATER ELEVATIONSClassification: BackgroundWell No. (Former ID)MW-21 (PZ-1)MW-20 (PZ-4)MW-22S (PZ-22S)MW-38 (PZ-38)MW-36 (PZ-36)MW-15S PZ-12 PZ-30S PZ-31 PZ-35TOC Elevation1099.86 1115.04 1061.20 1087.76 1099.52 1069.04 1025.64 1088.92 1089.81 1063.39Well Depth41.00 67.00 26.40 73.13 45.00 56.16 15.09 55.25 43.13 37.7518-Jun-96 NM NM 1049.88 NI NI 1022.70 1017.92 NI NI NI4-Dec-96 NM NM 1046.75 NI NI 1021.30 1017.91 NI NI NI6-May-14 1066.06 1058.24 1048.70 1042.18 1069.17 1025.74 1018.14 1041.92 1064.14 1044.4721-Oct-14 1063.48 1056.42 1045.76 1045.18 1066.52 1024.64 1017.68 1048.92 1061.04 1042.1321-May-15 1062.18 1053.69 1043.65 1044.68 1066.03 1025.17 1017.60 1047.22 1060.17 1041.129-Dec-15 1061.71 1051.65 1042.60 1046.24 1066.72 1025.19 1017.69 1045.57 1058.70 fill in!4-May-16 1065.36 1056.81 1045.81 1044.91 1071.22 1026.24 1017.94 1047.47 1056.31 fill in!13-Dec-16 1061.11 1051.66 1042.52 1042.81 1065.99 1022.89 1017.19 1046.32 1057.01 1039.4428-Jun-17 1061.51 1050.54 1042.20 1044.86 1065.77 1024.79 1017.64 1045.22 1058.31 1040.69Notes: All elevations are in feet above mean sea level.NM = Groundwater level not measured.NI = well not yet installed.Phase 1A ComplianceAdditional Wells & PiezometersBurke County Johns River CDLF - Phase 1A Permit 12-03 Joyce Engineering
TABLE 2:
FIELD PARAMETERS
WELL ID PARAMETER RESULT UNITS COLLECT DATE
MW-20 Conductivity 19.7 µS/cm 6/27/2017
MW-20 Dissolved Oxygen 8.98 mg/l 6/27/2017
MW-20 Oxidation Reduction Potential 152.2 mV 6/27/2017
MW-20 pH 5.98 S.U.6/27/2017
MW-20 Static Water Level 64.5 ft 6/27/2017
MW-20 Temperature 16.4 ºC 6/27/2017
MW-20 Turbidity 15.2 NTU 6/27/2017
MW-20 Well Depth 67.00 ft 6/27/2017
MW-21 Conductivity 28.9 µS/cm 6/27/2017
MW-21 Dissolved Oxygen 7.06 mg/l 6/27/2017
MW-21 Ferrous Iron 1.0 mg/l 6/27/2017
MW-21 Oxygen Reduction Potential 184.2 mV 6/27/2017
MW-21 pH 6.45 S.U.6/27/2017
MW-21 Static Water Level 38.35 ft 6/27/2017
MW-21 Temperature 15 ºC 6/27/2017
MW-21 Turbidity 12.20 NTU 6/27/2017
MW-21 Well Depth 46.80 ft 6/27/2017
MW-22S Static Water Level 19.00 ft 6/27/2017
MW-22S pH 6.27 S.U.6/27/2017
MW-22S Conductivity 29.70 µS/cm 6/27/2017
MW-22S Temperature 18.1 ºC 6/27/2017
MW-22S Turbidity 15.05 NTU 6/27/2017
MW-22S Well Depth 26.40 ft 6/27/2017
MW-38 Static Water Level 44.95 ft 6/27/2017
MW-38 pH 6.70 S.U.6/27/2017
MW-38 Conductivity 577 µS/cm 6/27/2017
MW-38 Temperature 17.9 ºC 6/27/2017
MW-38 Turbidity 11.25 NTU 6/27/2017
MW-38 Well Depth 74.50 ft 6/27/2017
PZ-12 Static Water Level 8.00 ft 6/27/2017
PZ-12 pH 5.87 S.U.6/27/2017
PZ-12 Conductivity 24.6 µS/cm 6/27/2017
PZ-12 Temperature 15.2 ºC 6/27/2017
PZ-12 Turbidity 15.00 NTU 6/27/2017
PZ-12 Well Depth 14.90 ft 6/27/2017
MW-15S Static Water Level 44.25 ft 6/27/2017
MW-15S pH 5.31 S.U.6/27/2017
MW-15S Conductivity 45.6 µS/cm 6/27/2017
MW-15S Temperature 16.0 ºC 6/27/2017
MW-15S Turbidity 8.95 NTU 6/27/2017
MW-15S Well Depth 58.27 ft 6/27/2017
Burke County Johns River CDLF - Phase 1A
Permit No. 12-03 Page 1 of 2
Joyce Engineering
TABLE 2:
FIELD PARAMETERS
WELL ID PARAMETER RESULT UNITS COLLECT DATE
PZ-30S Static Water Level 43.70 ft 6/27/2017
PZ-30S pH 7.22 S.U.6/27/2017
PZ-30S Conductivity 43.4 µS/cm 6/27/2017
PZ-30S Temperature 16.30 ºC 6/27/2017
PZ-30S Turbidity 8.9 NTU 6/27/2017
PZ-30S Well Depth 55.30 ft 6/27/2017
PZ-31 Static Water Level 32.80 ft 6/27/2017
PZ-31 pH 6.78 S.U.6/27/2017
PZ-31 Conductivity 33.0 µS/cm 6/27/2017
PZ-31 Temperature 14.3 ºC 6/27/2017
PZ-31 Turbidity 9.20 NTU 6/27/2017
PZ-31 Well Depth 45.60 ft 6/27/2017
PZ-35 Static Water Level 23.95 ft 6/27/2017
PZ-35 pH 6.17 S.U.6/27/2017
PZ-35 Conductivity 25.7 µS/cm 6/27/2017
PZ-35 Temperature 20.1 ºC 6/27/2017
PZ-35 Turbidity 10.75 NTU 6/27/2017
PZ-35 Well Depth 39.05 ft 6/27/2017
MW-36 Static Water Level 33.75 ft 6/27/2017
MW-36 pH 6.22 S.U.6/27/2017
MW-36 Conductivity 268.3 µS/cm 6/27/2017
MW-36 Temperature 16.8 ºC 6/27/2017
MW-36 Turbidity 11.60 NTU 6/27/2017
MW-36 Well Depth 45.58 ft 6/27/2017
SMP-5 Conductivity 110.5 µS/cm 6/27/2017
SMP-5 pH 6.37 S.U.6/27/2017
SMP-5 Temperature 21.1 ºC 6/27/2017
SMP-5 Turbidity 15.21 NTU 6/27/2017
SMP-6 Conductivity 89.6 µS/cm 6/27/2017
SMP-6 pH 6.49 S.U.6/27/2017
SMP-6 Temperature 89.6 ºC 6/27/2017
SMP-6 Turbidity 12.65 NTU 6/27/2017
SMP-7 Conductivity 34.3 µS/cm 6/27/2017
SMP-7 pH 5.85 S.U.6/27/2017
SMP-7 Temperature 16.7 ºC 6/27/2017
SMP-7 Turbidity 25.4 NTU 6/27/2017
Notes:ºC= degrees Centigrade
S.U.= Standard Units
µS = microsemens
NTU = Nephelometric Turbidity Units
mg/l = milligrams per liter
ft = feet
Burke County Johns River CDLF - Phase 1A
Permit No. 12-03 Page 2 of 2
Joyce Engineering
TABLE 3:
QUANTIFIED DETECTIONS OF GROUNDWATER
and SURFACE WATER CONSTITUENTS
WELL ID PARAMETER RESULT UNITS SWSL COLLECT DATE
1203-MW20 Iron 3,140 µg/L 300 6/27/2017
1203-MW20 Manganese 65.5 µg/L 50 6/27/2017
1203-MW20 Zinc 11.4 µg/L 10 6/27/2017
1203-MW20 Alkalinity, Total as CaCO3 6,110 µg/L NE 6/27/2017
1203-MW20 Total Dissolved Solids (TDS) 34,000 µg/L NE 6/27/2017
1203-MW20 Chloride 1,380 µg/L NE 6/27/2017
1203-MW21 Iron 2,340 µg/l 300 6/27/2017
1203-MW21 Manganese 60.3 µg/L 50 6/27/2017
1203-MW22S Iron 1,300 µg/L 300 6/27/2017
1203-MW22S Zinc 11.9 µg/L 10 6/27/2017
1203-MW22S Alkalinity, Total as CaCO3 5,060 µg/L NE 6/27/2017
1203-MW22S Total Dissolved Solids (TDS) 28,000 µg/L NE 6/27/2017
1203-MW22S Chloride 1,070 µg/L NE 6/27/2017
1203-MW38 Iron 40,800 µg/L 300 6/27/2017
1203-MW38 Manganese 3,700 µg/L 50 6/27/2017
1203-MW38 1,1-Dichloroethane 6.2 µg/L 5 6/27/2017
1203-MW38 1,4-Dichlorobenzene 11.0 µg/L 1 6/27/2017
1203-MW38 Benzene 5.0 µg/L 1 6/27/2017
1203-MW38 Trichloroethene 2.1 µg/L 1 6/27/2017
1203-MW38 Vinyl Chloride 1.9 µg/L 1 6/27/2017
1203-MW38* Vinyl Chloride 0.87 J µg/L 1 8/8/2017
1203-MW38 Carbon Dioxide 260,000 µg/L NE 6/27/2017
1203-MW38 cis-1,2-Dichloroethene 10.9 µg/L 5 6/27/2017
1203-MW38 Alkalinity, Total as CaCO3 315,000 µg/L NE 6/27/2017
1203-MW38 Total Dissolved Solids (TDS) 374,000 µg/L NE 6/27/2017
1203-MW38 Chloride 4,670 µg/L NE 6/27/2017
1203-SMP6 Zinc 17.4 µg/l 10 6/28/2017
1203-SMP6 Trichloroethene 1.1 µg/l 1 6/29/2017
1203-SMP7 Zinc 39 µg/l 10 6/30/2017
Notes: µg/L = micorgrams per liter. J = Estiamted below SWSL.
SWSL = NC Soild Waste Section Reporting Limit.NE = Not Established.
Laboratory Reporting limit used when SWSL has not been established.
There were no quantified detections in surface water from the December 2016 sampling event.
MW-38 detections are impacts from the old C&D-over-MSWLF and not from new Phase 1A cell.
* = Verification sampling for vinyl chloride in MW‐38 sample collected on August 8, 2017.
Burke County Johns River CDLF - Phase 1A
Permit No. 12-03 Joyce Engineering
TABLE 4:EXCEEDANCES OF GROUNDWATER and SURFACE WATER STANDARDSWELL IDPARAMETERRESULT UNITS SWSLNC2L /*GWPS /**NC2BGPS COLLECT DATE1203-MW20 Iron3,140µg/l 300 300 ASD 6/27/20171203-MW20 Manganese65.5µg/l 5050 ASD 6/27/20171203-MW21 Iron2,340µg/l 300 300 ASD 6/27/20171203-MW21 Manganese60µg/l 5050 ASD 6/27/20171203-MW22S Iron1,300µg/l 300 300 ASD 6/27/20171203-MW38 Iron40,800µg/l 300 300 ASD 6/27/20171203-MW38 Manganese3,700µg/l 5050 ASD 6/27/20171203-MW38 1,1-Dichloroethane6.2µg/l 5666/27/20171203-MW38 1,4-Dichlorobenzene11.0µg/l 1666/27/20171203-MW38 Benzene5.0µg/l 1116/27/20171203-MW38 Vinyl Chloride1.9 µg/l 10.03 0.03 6/27/20171203-MW38* Vinyl Chloride0.87 J µg/l 10.03 0.03 8/8/20171203-SMP7 Zinc39.4µg/l 1036‐‐‐6/30/2017Notes: µg/l = micorgrams per liter.J = Estiamted below SWSL.SWSL = NC Soild Waste Section Reporting Limit.NE = Not Established.Laboratory Reporting limit used when SWSL has not been established.NC2L = NC Groundwater Standard from 15A NCAC 2L.0202 NC2B = NC Surface Water Standards & Protective Values from 15A NCAC 02B GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L)GPS = Groundwater Protection Standard as defined by 15A NCAC 13B.1634(g) GPS for chromium, cobalt, and vanadium are based on background calculations for the site.GPS Exceedances are bold.ASD = Alternate Source Demonstration. An ASD for Iron and Manganese was approved by DEQ in April 2012; therefore, they are not considered GPS exceedances.MW-38 detections are attributed to impacts from the old C&D-over-MSWLF, and not from the new Phase 1A cell.* = Verification sampling for vinyl chloride in MW-38 sample collected on August 8, 2017.Burke County Johns River CDLF - Phase 1APermit No. 12-03Joyce Engineering
TABLE 5:QUANTIFIED DETECTIONS IN ADDITIONAL MONITORING WELLS/PIEZOMETERS (LFG DELINEATION STUDY)WELL IDPARAMETERRESULT UNITS SWSL COLLECT DATE1203-PZ12 Carbon Dioxide 36,000µg/lNE 6/27/20171203-PZ30S Carbon Dioxide 23,000µg/lNE 6/27/20171203-PZ31 Carbon Dioxide 14,000µg/lNE 6/27/20171203-PZ35 Carbon Dioxide 22,000µg/lNE 6/27/20171203-MW15S Methane 25,900 µg/l NE 6/27/20171203-MW15S Carbon Dioxide 250,000µg/lNE 6/27/20171203-MW36 1,4-Dichlorobenzene20.1µg/l 1 6/27/20171203-MW36 Benzene5.3µg/l 1 6/27/20171203-MW36 Methane 45,400 µg/l NE 6/27/20171203-MW36 Carbon Dioxide 420,000µg/lNE 6/27/20171203-MW38 Carbon Dioxide 260,000µg/lNE 6/27/2017Notes: µg/l = micorgrams per liter.SWSL = NC Soild Waste Section Reporting Limit.NE = Not Established.Laboratory Reporting limit used when SWSL has not been established.Burke County Johns River CDLF - Phase 1APermit No. 12-03Joyce Engineering
TABLE 6:EXCEEDANCES IN ADDITIONAL MONITORING WELLS/PIEZOMETERS(LFG DELINEATION STUDY)WELL IDPARAMETERRESULT UNITS SWSL NC2L/*GWPS GPS COLLECT DATE1203-MW36 1,4-Dichlorobenzene20.1µg/l 1 6 6 6/27/20171203-MW36 Benzene5.3µg/l 1 1 1 6/27/2017Notes: µg/l = micorgrams per liter.SWSL = NC Soild Waste Section Reporting Limit.NE = Not Established.Laboratory Reporting limit used when SWSL has not been established.NC2L = NC Groundwater Standard from 15A NCAC 2L.0202 GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L)GPS = Groundwater Protection Standard as defined by 15A NCAC 13B.1634(g)GPS Exceedances are bold.Burke County Johns River CDLF - Phase 1APermit No. 12-03Joyce Engineering
TABLE 7: HYDRAULIC GRADIENTS AND GROUNDWATER FLOW VELOCITIESGRADIENT CALCULATION SEGMENTFLOW LINE LENGTH (feet)FLOW DIRECTIONGROUNDWATER ELEVATION (feet)HORIZONTAL GRADIENT i (ft/ft)HYDRAULIC CONDUCTIVITY K (ft/day)EFFECTIVE POROSITY neLINEAR VELOCITY V (ft/year)10601000106010001060101010501030AVERAGE: 0.0450AVERAGE: 134.7Notes:Hydraulic conductivity (K=3.28 ft/day) is based on the arithmetric means of K from individual slug tests in saprolite wells at the facility.Effective Porosity (ne = 0.40) is assummed to be slightly less than the average laboratory porosity for site soil samples (saprolite) = 44% (0.44).Gradient segments are based on the December 2016 groundwater potentiometric surface map (see Drawing 1).V = Ki/ne; assumes homogeneous isotropic porous aquifer.June 28, 2017i11,395SSW0.0430 3.28E+00 0.40 128.7144.4i3960SSE0.0521 3.28E+00 0.40 155.9i21,244S0.0482 3.28E+00 0.40109.8i4545SE0.0367 3.28E+00 0.40Burke County Johns River CDLF - Phase 1APermit 12-03Joyce Engineering

FIGURE

Figure 1: Site Location Map

APPROXIMATE LOCATION
OF EXISTING LANDFILL
APPROXIMATE LOCATION
OF PROPERTY LINE
SOURCE: U.S.G.S. TOPOGRAPHIC MAP
FOR MORGANTON NORTH, N.C.
0
(FEET)
GRAPHIC SCALE
400020001000
2211 W. MEADOWVIEW ROAD
GREENSBORO, NC 27407
PHONE: [phone]
PROJECT NO.
FIGURE NO.APPROVED
CHECKED
DRAWN
DESIGNED
DATE
All rights reserved.
Ó Joyce Engineering, Inc.
SCALE
NC CORP LIC: C-0782
JOHN'S RIVER LANDFILL
BURKE COUNTY, NORTH CAROLINA
SITE LOCATION MAP
277
1
AS SHOWN
2017
ACE
RH
ACE
ACE
2017

DRAWING

Drawing 1: Groundwater Potentiometric Surface Map

SMP-5SURFACE MONITORING POINT LOCATION AND IDENTIFICATIONNOT MEASUREDLEGENDPROPERTY LINEEXISTING ROADEXISTING 25' TOPOGRAPHIC CONTOUREXISTING 2' TOPOGRAPHIC CONTOURGROUNDWATER SURFACE CONTOUR [FEETABOVE MEAN SEA LEVEL (AMSL)]APPROXIMATE LIMITS OF WASTECENTERLINE OF STREAMGAS PROBE LOCATION AND IDENTIFICATIONPIEZOMETER LOCATION AND IDENTIFICATIONCOMPLIANCE WELL LOCATION AND IDENTIFICATION WITH STATICWATER LEVEL ELEVATION (FEET AMSL)(NM)GP10501020MW-131009.84PZ-9DGMP-3TOPOGRAPHIC CONTOUR INTERVAL = 2 AND 10 FEET.GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET.STATIC WATER LEVELS WERE MEASURED ON JUNE 28, 2017.GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN ANDEXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWNFIELD CONDITIONS.MW-16D GROUNDWATER ELEVATION WAS NOT USED IN CALCULATINGGROUNDWATER CONTOURS.NOTESEXISTING 5' TOPOGRAPHIC CONTOUREXISTING 10' TOPOGRAPHIC CONTOUR1080T1TEMPORARY WELLAPPROXIMATE LOCATION OF SPRING HEAD1.2.3.4.5.JE-0020CONTROL POINT LOCATION AND IDENTIFICATIONSENTINEL WELL LOCATION AND IDENTIFICATION WITH STATICWATER LEVEL ELEVATION (FEET AMSL)MW-18GROUNDWATER FLOW PATHWAY USED TOCALCULATE HYDRAULIC GRADIENTi1SEGMENT USED FOR GRADIENT CALCULATIONMW-9ABANDONED OR UNUSED MONITORING WELLiiiFLOW PATH LENGTH1,395 LF1,244 LF960 LF545 LFi1030102
01010102010101000100010101020103010401050 1060107010801090110011101120113011401150116011501140113011201110110010901080117010801070106010501040105010401030102010101000105010401030102010101000i1i2i3i41060(ABANDONED)PZ-2S(ABANDONED)PZ-2D(NM)PZ-23(NM)PZ-15(NM)MW-22D1042.20MW-22S(NM)PZ-16D(NM)PZ-16S1017.64PZ-12(NM)PZ-27(NM)PZ-14(NM)PZ-13(ND)PZ-9D(NM)PZ-9S1009.84MW-13SMP-6993.13MW-12992.87MW-11994.07MW-16D992.82MW-16S999.55MW-10SMP-5(ABANDONED)MW-9(NM)MW-141024.79MW-15S(NM)MW-15D1040.99MW-8(NM)MW-1(FORMERLY PZ-4)MW-20NMMW-17SHOOTINGRANGEMULCHINGAREALOWER CREEKJOHNS RIVERCATAWBA R
IVER PROTECTED AREAWETLANDEXISTING TRAILAPPROX. LIMIT OFEXISTING WASTETRANSFER FACILITYBOUNDARYEXISTINGSEDIMENTBASINEXISTING C&DDISPOSAL AREACURRENT BACKGROUND WELLFORMER MW-18MW-19NMNM1050.54OFFICEANDGARAGE1040 1050 1070 1080 1090 11001060MW-381044.86MW-361065.77PZ-30S1045.22PZ-30DPZ-311058.31PZ-351039.441061.51MW-21 (FORMERLY PZ-1)BACKGROUND WELLCURRENT PHASE 1A LIMITS1060SMP-7PROJECT NO.APPROVED
CHECKED
DRAWN
DESIGNED
DATE
DATE REVISIONS AND RECORD OF ISSUE BYNO APPCKSCALE All rights reserved.
Ó Joyce Engineering, Inc.DRAWING NO.N:\Dwgs\Drawings-Current\BURKE\GW EVENT MAPS\GW-EVENT 6-17.DWG Layout=SHT 01
2211 W. MEADOWVIEW ROAD
GREENSBORO, NC 27407
PHONE: [phone]JOHNS RIVER, WASTE MANAGEMENT FACILITY
BURKE COUNTY, NORTH CAROLINA
20171AS NOTEDGROUNDWATER POTENTIOMETRIC SURFACE MAP
JUNE 28, 2017
PERMIT NO. 12-03
GE
RWH
VB
VB
09/22/170(FEET)GRAPHIC SCALE400200100

APPENDICES

Appendix A: Field Data Logs
Appendix B: Laboratory Analytical Reports
Appendix C: Statistical Analyses Worksheets
Appendix D: Historical Detected Groundwater Constituents
Appendix E: Historical Detected Constituents in Additional Wells and Piezometers
Appendix F: Historical Detected Surface Water Constituents

Appendix A

Field Data Logs

Signature:Date:QA/QCSignOff:%%2Date:2inches44.25feet58.27feet14.02feet[DTB-DTW]=2.3gallons=____________gallons=6.9gallons6.9gallonsJOYCE8tJGI1\J8RirJcDATE:6/27/2017GROUNDWATERSAMPLING LOGProjectName:BurkeCounty-JohnsRiverProjectNo./TaskNo.: 00277.1701.12.02WellID:MW-15SSampler(s):H.Seaton/G.EllersouthwestofMW-3$,across fromGP-4WellLocation:WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumn Thickness(WCT):CalculationforOne Well Volume(WV):for2”Well:WCTX0.163for4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmount Purged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbefore Sampling:
-feetGallonsTimeTemp(°C)pH(s.u.)Cond.Turb.Initials(jiS/cm)(NTU)0083616.05.2744.76.70GE2.3083915.8 5.3145.58.25GE4.6084215.75.2946.08.91GE6.9084516.05.3145.68.95GEBefore084516.05.3145.68.95GESampleComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe70son6/28/2017.Revised12/30/05
DATE:6/27-28/2017JOYCE_________GROUNDWATERSAMPLINGLOGProjectName:BurkeCounty-JohnsRiverProjectNo.ITaskNo.:00277.1701.12.02WellID:MW-20Sampler(s):G.Eller/H.SeatonWellLocation:infieldonlefibetweenshoDandroadtoC&Dentrance2inches64.50feet67.00feet2.50feet=0.4gallons=_____________gallons=1.2gallons0.8gallonsWellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:[DTB-DTW]64.95feetGallonsTimeTemp(°C)DO(mgIL)Cond.p11ORP(mV)Iurb.Initials(iSIcm)(s.u.)(NTU)0150017.47.2938.16.13130.64.97GE0.4150116.69.6119.36.04139.1269GE0.8150216.58.765.905.90139.5>1000GEDry0.8galGE6/28/17BeforeSample091216.48.9819.75.98152.215.2GEComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe70son6/27/2017andon6/28/17.Thewellwaspurgedon6/27/17andsampledon6/28/17.Signature:tAJ1Date:QA!QCSignOff:jP714—Date:7—3frt7Revised12/30/05
JOYCE_______
______Er’.JGiP’.]8RICJG_______________________________ProjectName:John’sRiver,BurkeCoWellID:MW-21Sampler(s):________________________________________WellLocation:Offtheroadbythewesternpropertyboundary,upfromGP-1WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):for2”Well:WCTX0.163=For4”Well:WCTX0.653=ForTHREEWellVolumes:WVX3=ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:38.70feetFe2+:1.0m/L1.3gallons3.9gallons3.9gallonsSignature:t\1P4Date:QAIQCSignOff:_________________________G,1-t-DATE:6/27/2017DEVELOPMENTANDGROUNDWATERSAMPLINGLOGProjectNo./TaskNo.:277.1701.12.02G.Eller/ H.Seaton2inches38.35feet46.80feet8.45feetEDTB-DTW]GallonsTimeTemp(°C)DOCond.pHORP(mV)Turb.Initials(mg/L)(jiSlcm)(s.u.)(NTU)0082515.011.8756.88.6866.46.81GE1.3082614.98.8115.18.87122.3123GE2.6082814.88.0911.67.10143.6306 GE3.9082914.78.3011.46.35162.6529GEBeforeSampling104515.07.0628.96.45184.212.2HSComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe70son6/27/2017.7—t-/)
DATE:6/27-28/17JOYCE___________8I\JCIP’J8RII\JLDevelopmentandGROUNDWATERSAMPLINGLOGProjectName:John’sRiver,BurkeCoProjectNo./TaskNo.:277.1701.12.02WellID:MW-22SSampler(s):G.Flier/H.SeatonWellLocation:InthewoodsontheedgeofthenewC&DcellWellDiameter:2inchesInitialDepthtoWater(DTW):19.00feetDepthtoBottom(DTB):26.40feetWaterColumnThickness(WCT):7.40feet[DTB-DTW]CalculationforOneWellVolume(WV):For2”Well:WCTX0.1631.2gallonsFor4”Well:WCTX0.653____________gallonsForTHREEWellVolumes:WVX33.6gallonsActualAmountPurgedlBailed:3.6gallonsPurgedwith:DisposablebailerSampledwith:DisposablebailerDepthtoWaterbeforeSampling:19.50feetGallonsTimeTemp(°C)pHCond.Turb.Initials(s.u.)(S/cm)(NTU)0141817.35.75369.71GE1.2142017.06.0020.522.8GE2.4142116.35.7619.6165GE3.6142316.15.5919.5316GE6/28/17BeforeSampling110418.16.2729.715.05GEComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe70son6/27/2017.Signature:fw-_Date:27—iQA/QCSignOff:Date:Jf7
DATE:6/28/2017Signature:Date:QAJQCSignOff:1j47j-’——Date:2inches33.75feet45.58feet11.83feet[DTB-DTWJ=1.9gallons=_____________gallons5.7gallons5.7gallonsJOYCE____
_____8P’.J9It\J8RItJGGROUNDWATERSAMPLINGLOGProjectName:_Burke_County-JohnsRiverProjectNo.ITaskNo.:00277.1701.12.02WellID:MW-36Sampler(s):H.Seaton/G.EllerWellLocation:Pronosedexoansionarea.downhillfromGP-2WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged!Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:feetGallonsTimeTemp(°C)pH(s.u.)Cond.Turb.Initials(jiSlcm)(NTU)0101817.15.69201.14.73HS1.9101916.55.82240.29.21HS3.8102116.65.90256.310.8HS5.7102316.86.22268.311.6HSBeforeSampling102316.86.22268.311.6HSComments(weatherconditions,odor,color,silt,etc.):temneraturesinthe70son6/28/2017.Theweatherwassunnywith
DATE:6/28/20172inches42.90feet74.50feet31.60feet[DTB-DTW]=5.1gallons=_____________gallons=15.3gallons15.3gallonsSignature:Date:QAIQCSignOff:,AzDate:/.7tzLJOYCE&fJGIrJSS!r\JGGROUNDWATERSAMPLINGLOGProjectName:BurkeCounty-JohnsRiverProjectNo./TaskNo.:00277.1701.12.02WellID:MW-38Sampler(s):H.Seaton/G.EllerProposedExpansionArea.SouthofPZ-36WellLocation:WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):Calculation forOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:--feetGallonsTimeTemp(°C)p11(s.u.)Cond.Turb.InitialsQ.tS/cm)(NTU)0104519.46.3651611.25GE5.1104717.36.30405.515.13GE10.2105117.16.4250510.54GE15.3105317.96.5757711.25GEBeforeSampling105317.96.5757711.25GEConunents(weatherconditions,odor,color,silt, etc.):Theweatherwassunnywithtemneraturesinthe70son6/28/2017.
DATE:6/27/2017JOYCE_________81\JcIr’JESRII\JGGROUNDWATERSAMPLING LOGProjectName:BurkeCounty-JohnsRiverProjectNo./TaskNo.:00277.1701.12.02WellID:PZ-12Sampler(s):H.Seaton/ G.FlierWellLocation:Proposed expansionarea,WestofPZ-165&-16DWel
l
D
ia
m
e
ter:
___
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_
_
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_InitialDepthtoWater(DTW):___
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_DepthtoBottom(DTB):_
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_
_
_
_
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_Water ColumnThickness(WCT):_
_
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______CalculationforOneWellVolume(WV):For2”Well:WCTX0.163=___
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__For4”Well:WCTX0.653=___
_
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_____ForTHREEWellVolumes:WVX3=__
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_
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_ActualAmount Purged/Bailed:
___
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_Purgedwith:DisposablebailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:8.70feetGallonsTimeTemp(°C)p11(s.u.)Cond.Turb.Initials(itS/cm)(NTU)0093516.36.0521.69.31HS1.1093714.45.8423.110.05HSDry1.4BeforeSample094515.25.8724.615HSSignature:QA/QCSignOff:Date:2inches8.00feet14.90feet6.90feet[DTB-DTW]1.1gallons______________gallons3.3gallons1.4gallonsComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe70son6/27/2017.Iig-i7
DATE:6/27-28/2017Signature:Date:QA/QCSignOff:_________________________2inches43.70feet55.30feet11.60feet[DTB-DTW]1.8gallons________gallons5.4gallons5.4gallonsJOYCEIrJRIrJc9GROUNDWATERSAMPLINGLOGProjectName:Burke County-JohnsRiverProjectNo./TaskNo.:00277.1701.12.02WellID:PZ-30sSampler(s):H.Seaton/G.EllerWellLocation:Proposedexpansionarea.SouthofMW-36WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWell Volumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:43.72feetGallonsTimeTemp(°C)pH(s.u.)Cond.Thrb.Initials(jiS/cm)(NTU)0143317.45.9028.18.93HS1.8143516.86.0818.942.6HS3.6143716.65.8518.4186HS5.4143916.55.7821.4223HS6/28/17BeforeSample081516.37.2243.48.90HSComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe70son6/27/2017andon6/28/17.Thewellwaspurgedon6/27/17andsampledon6/28/17._7—?I-,7Revised12/30/05
DATE:6/27-28/2017Signature:QA/QCSignOff:_________________________2inches31.50feet45.60feet14.10feet[DTB-DTW]=2.3gallonsgallons=6.9gallons6.9gallonsJOYCE_________I1\fsEF?Ir\JcGROUNDWATERSAMPLINGLOGProjectName:BurkeCounty-JohnsRiverProjectNo./TaskNo.:00277.1701.12.01WellID:PZ-31Sampler(s):H.Seaton/G.EllerWellLocation:BorrownitareaWellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(‘WV):for2”Well:WCTX0.163for4”Well:WCTX0.653For THREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:31.54feetGallonslimelemp(°C)pHCond.Turb.Initials(s.u.)(jiS/cm)(NIU)0144617.75.9911.97.56GE2.3144816.85.9614.621.8GE4.6145016.95.9318.462.0GE6.9145216.85.9824.7129GE6/28/17BeforeSampling082416.76.2315.47.56HSComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe70son6/27/2017andon6/28/17.Thewellwaspurgedon6/27/17andsamuledon6/28/17.-_%;_3—f—,7
DATE:6/28/20172inches22.70feet39.05feet16.35feet______________al1ons______________gallons8.1gallons8.1a11onsSignature:?lüi’4yP2/’Date:QAIQCSignOff:___________________Date:t:;2YI’GROUNDWATERSAMPLING1LOGJOYCE__________8Ir\JRi!\JG________________________ProjectName:BurkeCounty-JohnsRiverProjectNo./TaskNo.:00277.1701.12.02WellID:PZ-35Sampler(s):H.Seaton/G.FilerWellLocation:Proposedexpansionarea,downhillfromPZ-34andsed.pondWellDiameter:_
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_WaterColumnThickness(WCT):_
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_CalculationforOneWellVolume(WV):For2”Well:WCTX0.1632.7For4”Well:WCTX0.653=____________ForTHREEWellVolumes:WVX3=___
_
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_ActualAmountPurged/Bailed:____________Purgedwith:DisposableBailerSampledwith:_______________________________________________________DepthtoWater___
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_[DTB-DTW]DisnosableBailerbeforeSampling:23.71feetGallonsTimeTemp(°C)pH(s.u.)Cond.Turb.Initials(jiSfcm)(NTU)0085616.26.0220.012.51HS2.7085916.15.9318.7>1000HS5.4090316.15.9018.2>1000HS8.1090516.25.8718.2>1000HSBeforeSampling111320.16.3925.710.75HSComments(weatherconditions,odor,color,silt,etc.):temoeraturesinthe70son6/28/2017.Theweatherwassunnywith
1—Z/-i7SketchofSampleLocation(includeflowdirection,drainagepathways,etc.):-.DATE:6/28/2017JOYCE__________IrJSRII\JCSURFACEWATERMONITORINGLOGProjectName:BurkeCounty-JohnsRiverProject/TaskNo.:00277.1701.12.02SurfacePointID:SMP-5Sampler(s):G.Eller/H.SeatonLocation:downroadtoriver,rightatforkinroadbesidebarnFieldParameters:TimeofSampling:1145pH:6.37Temperature:21.1(°C)Conductivity:110.5(tS/cm)Turbidity:15.21(NTU)Comments/SampleDescription(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithterrrneraturesinthe70son6/28/2017.VTh
DATE:6/28/2017JOYCE__________IPJERIr\JGSURFACEWATERMONITORINGLOGProjectName:BurkeCounty-JohnsRiverProject/TaskNo.:00277.1701.12.02SurfacePointID:$MP-6Sampler(s):G.EllenH.SeatonLocation:downhillfrombetweenMW-12&MW-13tostreamFieldParameters:TimeofSampling:1200pH:6.49Temperature:18.3(°C)Conductivity:89.6(p.S/cm)Turbidity:12.65(NTU)Comments/SampleDescription(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe70son6/28/2017.7-t-t7
DATE:6/28/2017JOYCE__________CJEIC’JGSURFACEWATERMONITORINGLOGProjectName:BurkeCounty-JohnsRiverProject/TaskNo.:00277.1701.12.02SurfacePointID: SMP-7Sampler(s):G.EllenH.SeatonLocation:UpstreamfromPZ-12FieldParameters:TimeofSampling:0940pH:5.85Temperature:16.7(°C)Conductivity:34.3(jiS/cm)Turbidity:25.4(NTU)Comments/SampleDescription(weatherconditions,odor,color,silt,etc.):__________Theweatherwassunnywithtemperaturesinthe70son6/28/2017.FIELDBLANK(ifl300)Signature:________________________Date:QAIQCSignOff:___________________Date:7Jt/7

Appendix B

Laboratory Analytical Reports

#=CL#
July 15, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92346154
92346154
Project:
Pace Project No.:
RE:
Mr. Van BurbachJoyce Engineering-Greensboro2211 West Meadowview RdBoone Bldg, Suite 101Greensboro, NC 27407
JOHNS R. -PHASE 1A GW
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on June 29, 2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager(704)875-9092
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 31
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 31
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Lab ID Sample ID Matrix Date Collected Date Received
92346154001 1203-MW-20 Water 06/27/17 09:12 06/29/17 11:14
92346154002 1203-MW-22S Water 06/27/17 11:04 06/29/17 11:14
92346154003 1203-MW-38 Water 06/27/17 10:53 06/29/17 11:14
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 31
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92346154001 1203-MW-20 EPA 6010 16 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AKAL
EPA 8260 53 PASI-CGAW
SM 2320B 1 PASI-AKDF1
SM 2540C 1 PASI-ASLB
EPA 300.0 1 PASI-ACDC
SM 4500-Cl-E 1 PASI-ABRJ
92346154002 1203-MW-22S EPA 6010 16 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AKAL
EPA 8260 53 PASI-CGAW
SM 2320B 1 PASI-AKDF1
SM 2540C 1 PASI-ASLB
EPA 300.0 1 PASI-ACDC
SM 4500-Cl-E 1 PASI-ABRJ
92346154003 1203-MW-38 EPA 6010 16 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AKAL
EPA 8260 53 PASI-CGAW
SM 2320B 1 PASI-AKDF1
SM 2540C 1 PASI-ASLB
EPA 300.0 1 PASI-ACDC
SM 4500-Cl-E 1 PASI-ABRJ
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 31
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92346154001 1203-MW-20
Barium 72.1J ug/L 07/12/17 21:34100EPA 6010
Chromium 3.5J ug/L 07/12/17 21:3410.0EPA 6010
Copper 3.3J ug/L 07/12/17 21:3410.0EPA 6010
Iron 3140 ug/L 07/12/17 21:34300EPA 6010
Manganese 65.5 ug/L 07/12/17 21:3450.0EPA 6010
Vanadium 5.1J ug/L 07/12/17 21:3425.0EPA 6010
Zinc 11.4 ug/L 07/12/17 21:3410.0EPA 6010
Thallium 0.077J ug/L 07/12/17 15:245.5EPA 6020B
Acetone 12.4J ug/L 07/04/17 17:37100EPA 8260
Alkalinity, Total as CaCO3 6110 ug/L 07/01/17 19:455000SM 2320B
Total Dissolved Solids 34000 ug/L 06/30/17 10:0825000SM 2540C
Sulfate 712J ug/L 07/04/17 03:07250000EPA 300.0
Chloride 1380 ug/L 07/08/17 01:481000SM 4500-Cl-E
92346154002 1203-MW-22S
Barium 74.3J ug/L 07/12/17 21:37100EPA 6010
Iron 1300 ug/L 07/12/17 21:37300EPA 6010
Manganese 24.9J ug/L 07/12/17 21:3750.0EPA 6010
Zinc 11.9 ug/L 07/12/17 21:3710.0EPA 6010
Thallium 0.057J ug/L 07/12/17 15:265.5EPA 6020B
Acetone 20.2J ug/L 07/04/17 17:55100EPA 8260
Trichlorofluoromethane 0.46J ug/L 07/04/17 17:551.0EPA 8260
Alkalinity, Total as CaCO3 5060 ug/L 07/01/17 20:205000SM 2320B
Total Dissolved Solids 28000 ug/L 06/30/17 10:08 D625000SM 2540C
Sulfate 761J ug/L 07/04/17 03:24250000EPA 300.0
Chloride 1070 ug/L 07/08/17 01:491000SM 4500-Cl-E
92346154003 1203-MW-38
Barium 77.1J ug/L 07/12/17 21:40100EPA 6010
Chromium 3.0J ug/L 07/12/17 21:4010.0EPA 6010
Iron 40800 ug/L 07/12/17 21:40300EPA 6010
Lead 3.4J ug/L 07/12/17 21:4010.0EPA 6010
Manganese 3700 ug/L 07/12/17 21:4050.0EPA 6010
Vanadium 2.8J ug/L 07/12/17 21:4025.0EPA 6010
Zinc 7.0J ug/L 07/12/17 21:4010.0EPA 6010
Acetone 12.2J ug/L 07/04/17 18:12100EPA 8260
Benzene 5.0 ug/L 07/04/17 18:121.0EPA 8260
1,4-Dichlorobenzene 11.0 ug/L 07/04/17 18:121.0EPA 8260
1,1-Dichloroethane 6.2 ug/L 07/04/17 18:125.0EPA 8260
1,2-Dichloroethane 0.67J ug/L 07/04/17 18:121.0EPA 8260
cis-1,2-Dichloroethene 10.9 ug/L 07/04/17 18:125.0EPA 8260
Tetrahydrofuran 3.1J ug/L 07/04/17 18:1210.0EPA 8260
Toluene 0.30J ug/L 07/04/17 18:121.0EPA 8260
Trichloroethene 2.1 ug/L 07/04/17 18:121.0EPA 8260
Vinyl chloride 1.9 ug/L 07/04/17 18:121.0EPA 8260
Alkalinity, Total as CaCO3 315000 ug/L 07/01/17 20:325000SM 2320B
Total Dissolved Solids 374000 ug/L 06/30/17 10:0925000SM 2540C
Sulfate 5400J ug/L 07/04/17 03:41250000EPA 300.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 31
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92346154003 1203-MW-38
Chloride 4670 ug/L 07/08/17 01:54 M11000SM 4500-Cl-E
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Sample: 1203-MW-20 Lab ID: 92346154001 Collected: 06/27/17 09:12 Received: 06/29/17 11:14 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 07/12/17 21:34 7440-36-007/05/17 15:356.0 3.9 1
Arsenic ND ug/L 07/12/17 21:34 7440-38-207/05/17 15:3510.0 5.0 1
Barium 72.1J ug/L 07/12/17 21:34 7440-39-307/05/17 15:35100 2.5 1
Beryllium ND ug/L 07/12/17 21:34 7440-41-707/05/17 15:351.0 0.50 1
Cadmium ND ug/L 07/12/17 21:34 7440-43-907/05/17 15:351.0 0.50 1
Chromium 3.5J ug/L 07/12/17 21:34 7440-47-307/05/17 15:3510.0 2.5 1
Cobalt ND ug/L 07/12/17 21:34 7440-48-407/05/17 15:3510.0 2.5 1
Copper 3.3J ug/L 07/12/17 21:34 7440-50-807/05/17 15:3510.0 2.5 1
Iron 3140 ug/L 07/12/17 21:34 7439-89-607/05/17 15:35300 25.0 1
Lead ND ug/L 07/12/17 21:34 7439-92-107/05/17 15:3510.0 2.5 1
Manganese 65.5 ug/L 07/12/17 21:34 7439-96-507/05/17 15:3550.0 2.5 1
Nickel ND ug/L 07/12/17 21:34 7440-02-007/05/17 15:3550.0 2.5 1
Selenium ND ug/L 07/12/17 21:34 7782-49-207/05/17 15:3510.0 5.0 1
Silver ND ug/L 07/12/17 21:34 7440-22-407/05/17 15:3510.0 2.5 1
Vanadium 5.1J ug/L 07/12/17 21:34 7440-62-207/05/17 15:3525.0 2.5 1
Zinc 11.4 ug/L 07/12/17 21:34 7440-66-607/05/17 15:3510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium 0.077J ug/L 07/12/17 15:24 7440-28-007/04/17 05:505.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 07/11/17 07:11 7439-97-607/07/17 12:290.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 12.4J ug/L 07/04/17 17:37 67-64-1100 10.0 1
Acrylonitrile ND ug/L 07/04/17 17:37 107-13-1200 1.9 1
Benzene ND ug/L 07/04/17 17:37 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/04/17 17:37 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/04/17 17:37 75-27-41.0 0.18 1
Bromoform ND ug/L 07/04/17 17:37 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/04/17 17:37 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/04/17 17:37 78-93-3100 0.96 1
Carbon disulfide ND ug/L 07/04/17 17:37 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 07/04/17 17:37 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/04/17 17:37 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/04/17 17:37 75-00-310.0 0.54 1
Chloroform ND ug/L 07/04/17 17:37 67-66-35.0 0.14 1
Chloromethane ND ug/L 07/04/17 17:37 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 07/04/17 17:37 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/04/17 17:37 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/04/17 17:37 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/04/17 17:37 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/04/17 17:37 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/04/17 17:37 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/04/17 17:37 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 07/04/17 17:37 75-71-85.0 0.21 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Sample: 1203-MW-20 Lab ID: 92346154001 Collected: 06/27/17 09:12 Received: 06/29/17 11:14 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,1-Dichloroethane ND ug/L 07/04/17 17:37 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/04/17 17:37 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/04/17 17:37 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/04/17 17:37 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/04/17 17:37 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/04/17 17:37 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/04/17 17:37 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/04/17 17:37 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 07/04/17 17:37 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/04/17 17:37 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/04/17 17:37 74-88-410.0 0.32 1
Isobutanol ND ug/L 07/04/17 17:37 78-83-1100 35.0 1
Methylene Chloride ND ug/L 07/04/17 17:37 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/04/17 17:37 108-10-1100 0.33 1
Styrene ND ug/L 07/04/17 17:37 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/04/17 17:37 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/04/17 17:37 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/04/17 17:37 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 07/04/17 17:37 109-99-910.0 3.1 1
Toluene ND ug/L 07/04/17 17:37 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/04/17 17:37 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/04/17 17:37 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/04/17 17:37 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/04/17 17:37 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/04/17 17:37 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/04/17 17:37 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/04/17 17:37 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/04/17 17:37 1330-20-75.0 0.66 1
Surrogates4-Bromofluorobenzene (S)98 %07/04/17 17:37 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %07/04/17 17:37 17060-07-070-130 1
Toluene-d8 (S)104 %07/04/17 17:37 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 6110 ug/L 07/01/17 19:455000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 34000 ug/L 06/30/17 10:0825000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 712J ug/L 07/04/17 03:07 14808-79-8250000 500 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 1380 ug/L 07/08/17 01:48 16887-00-61000 500 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Sample: 1203-MW-22S Lab ID: 92346154002 Collected: 06/27/17 11:04 Received: 06/29/17 11:14 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 07/12/17 21:37 7440-36-007/05/17 15:356.0 3.9 1
Arsenic ND ug/L 07/12/17 21:37 7440-38-207/05/17 15:3510.0 5.0 1
Barium 74.3J ug/L 07/12/17 21:37 7440-39-307/05/17 15:35100 2.5 1
Beryllium ND ug/L 07/12/17 21:37 7440-41-707/05/17 15:351.0 0.50 1
Cadmium ND ug/L 07/12/17 21:37 7440-43-907/05/17 15:351.0 0.50 1
Chromium ND ug/L 07/12/17 21:37 7440-47-307/05/17 15:3510.0 2.5 1
Cobalt ND ug/L 07/12/17 21:37 7440-48-407/05/17 15:3510.0 2.5 1
Copper ND ug/L 07/12/17 21:37 7440-50-807/05/17 15:3510.0 2.5 1
Iron 1300 ug/L 07/12/17 21:37 7439-89-607/05/17 15:35300 25.0 1
Lead ND ug/L 07/12/17 21:37 7439-92-107/05/17 15:3510.0 2.5 1
Manganese 24.9J ug/L 07/12/17 21:37 7439-96-507/05/17 15:3550.0 2.5 1
Nickel ND ug/L 07/12/17 21:37 7440-02-007/05/17 15:3550.0 2.5 1
Selenium ND ug/L 07/12/17 21:37 7782-49-207/05/17 15:3510.0 5.0 1
Silver ND ug/L 07/12/17 21:37 7440-22-407/05/17 15:3510.0 2.5 1
Vanadium ND ug/L 07/12/17 21:37 7440-62-207/05/17 15:3525.0 2.5 1
Zinc 11.9 ug/L 07/12/17 21:37 7440-66-607/05/17 15:3510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium 0.057J ug/L 07/12/17 15:26 7440-28-007/04/17 05:505.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 07/11/17 07:14 7439-97-607/07/17 12:290.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 20.2J ug/L 07/04/17 17:55 67-64-1100 10.0 1
Acrylonitrile ND ug/L 07/04/17 17:55 107-13-1200 1.9 1
Benzene ND ug/L 07/04/17 17:55 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/04/17 17:55 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/04/17 17:55 75-27-41.0 0.18 1
Bromoform ND ug/L 07/04/17 17:55 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/04/17 17:55 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/04/17 17:55 78-93-3100 0.96 1
Carbon disulfide ND ug/L 07/04/17 17:55 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 07/04/17 17:55 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/04/17 17:55 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/04/17 17:55 75-00-310.0 0.54 1
Chloroform ND ug/L 07/04/17 17:55 67-66-35.0 0.14 1
Chloromethane ND ug/L 07/04/17 17:55 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 07/04/17 17:55 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/04/17 17:55 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/04/17 17:55 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/04/17 17:55 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/04/17 17:55 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/04/17 17:55 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/04/17 17:55 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 07/04/17 17:55 75-71-85.0 0.21 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Sample: 1203-MW-22S Lab ID: 92346154002 Collected: 06/27/17 11:04 Received: 06/29/17 11:14 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,1-Dichloroethane ND ug/L 07/04/17 17:55 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/04/17 17:55 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/04/17 17:55 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/04/17 17:55 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/04/17 17:55 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/04/17 17:55 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/04/17 17:55 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/04/17 17:55 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 07/04/17 17:55 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/04/17 17:55 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/04/17 17:55 74-88-410.0 0.32 1
Isobutanol ND ug/L 07/04/17 17:55 78-83-1100 35.0 1
Methylene Chloride ND ug/L 07/04/17 17:55 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/04/17 17:55 108-10-1100 0.33 1
Styrene ND ug/L 07/04/17 17:55 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/04/17 17:55 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/04/17 17:55 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/04/17 17:55 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 07/04/17 17:55 109-99-910.0 3.1 1
Toluene ND ug/L 07/04/17 17:55 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/04/17 17:55 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/04/17 17:55 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/04/17 17:55 79-01-61.0 0.47 1
Trichlorofluoromethane 0.46J ug/L 07/04/17 17:55 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/04/17 17:55 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/04/17 17:55 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/04/17 17:55 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/04/17 17:55 1330-20-75.0 0.66 1
Surrogates4-Bromofluorobenzene (S)97 %07/04/17 17:55 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %07/04/17 17:55 17060-07-070-130 1
Toluene-d8 (S)103 %07/04/17 17:55 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 5060 ug/L 07/01/17 20:205000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 28000 ug/L 06/30/17 10:08 D625000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 761J ug/L 07/04/17 03:24 14808-79-8250000 500 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 1070 ug/L 07/08/17 01:49 16887-00-61000 500 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Sample: 1203-MW-38 Lab ID: 92346154003 Collected: 06/27/17 10:53 Received: 06/29/17 11:14 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 07/12/17 21:40 7440-36-007/05/17 15:356.0 3.9 1
Arsenic ND ug/L 07/12/17 21:40 7440-38-207/05/17 15:3510.0 5.0 1
Barium 77.1J ug/L 07/12/17 21:40 7440-39-307/05/17 15:35100 2.5 1
Beryllium ND ug/L 07/12/17 21:40 7440-41-707/05/17 15:351.0 0.50 1
Cadmium ND ug/L 07/12/17 21:40 7440-43-907/05/17 15:351.0 0.50 1
Chromium 3.0J ug/L 07/12/17 21:40 7440-47-307/05/17 15:3510.0 2.5 1
Cobalt ND ug/L 07/12/17 21:40 7440-48-407/05/17 15:3510.0 2.5 1
Copper ND ug/L 07/12/17 21:40 7440-50-807/05/17 15:3510.0 2.5 1
Iron 40800 ug/L 07/12/17 21:40 7439-89-607/05/17 15:35300 25.0 1
Lead 3.4J ug/L 07/12/17 21:40 7439-92-107/05/17 15:3510.0 2.5 1
Manganese 3700 ug/L 07/12/17 21:40 7439-96-507/05/17 15:3550.0 2.5 1
Nickel ND ug/L 07/12/17 21:40 7440-02-007/05/17 15:3550.0 2.5 1
Selenium ND ug/L 07/12/17 21:40 7782-49-207/05/17 15:3510.0 5.0 1
Silver ND ug/L 07/12/17 21:40 7440-22-407/05/17 15:3510.0 2.5 1
Vanadium 2.8J ug/L 07/12/17 21:40 7440-62-207/05/17 15:3525.0 2.5 1
Zinc 7.0J ug/L 07/12/17 21:40 7440-66-607/05/17 15:3510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 07/12/17 15:28 7440-28-007/04/17 05:505.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 07/11/17 07:21 7439-97-607/07/17 12:290.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 12.2J ug/L 07/04/17 18:12 67-64-1100 10.0 1
Acrylonitrile ND ug/L 07/04/17 18:12 107-13-1200 1.9 1
Benzene 5.0 ug/L 07/04/17 18:12 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/04/17 18:12 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/04/17 18:12 75-27-41.0 0.18 1
Bromoform ND ug/L 07/04/17 18:12 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/04/17 18:12 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/04/17 18:12 78-93-3100 0.96 1
Carbon disulfide ND ug/L 07/04/17 18:12 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 07/04/17 18:12 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/04/17 18:12 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/04/17 18:12 75-00-310.0 0.54 1
Chloroform ND ug/L 07/04/17 18:12 67-66-35.0 0.14 1
Chloromethane ND ug/L 07/04/17 18:12 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 07/04/17 18:12 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/04/17 18:12 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/04/17 18:12 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/04/17 18:12 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/04/17 18:12 95-50-15.0 0.30 1
1,4-Dichlorobenzene 11.0 ug/L 07/04/17 18:12 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/04/17 18:12 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 07/04/17 18:12 75-71-85.0 0.21 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Sample: 1203-MW-38 Lab ID: 92346154003 Collected: 06/27/17 10:53 Received: 06/29/17 11:14 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,1-Dichloroethane 6.2 ug/L 07/04/17 18:12 75-34-35.0 0.32 1
1,2-Dichloroethane 0.67J ug/L 07/04/17 18:12 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/04/17 18:12 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 10.9 ug/L 07/04/17 18:12 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/04/17 18:12 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/04/17 18:12 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/04/17 18:12 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/04/17 18:12 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 07/04/17 18:12 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/04/17 18:12 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/04/17 18:12 74-88-410.0 0.32 1
Isobutanol ND ug/L 07/04/17 18:12 78-83-1100 35.0 1
Methylene Chloride ND ug/L 07/04/17 18:12 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/04/17 18:12 108-10-1100 0.33 1
Styrene ND ug/L 07/04/17 18:12 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/04/17 18:12 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/04/17 18:12 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/04/17 18:12 127-18-41.0 0.46 1
Tetrahydrofuran 3.1J ug/L 07/04/17 18:12 109-99-910.0 3.1 1
Toluene 0.30J ug/L 07/04/17 18:12 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/04/17 18:12 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/04/17 18:12 79-00-51.0 0.29 1
Trichloroethene 2.1 ug/L 07/04/17 18:12 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/04/17 18:12 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/04/17 18:12 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/04/17 18:12 108-05-450.0 0.35 1
Vinyl chloride 1.9 ug/L 07/04/17 18:12 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/04/17 18:12 1330-20-75.0 0.66 1
Surrogates4-Bromofluorobenzene (S)97 %07/04/17 18:12 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %07/04/17 18:12 17060-07-070-130 1
Toluene-d8 (S)102 %07/04/17 18:12 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 315000 ug/L 07/01/17 20:325000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 374000 ug/L 06/30/17 10:0925000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 5400J ug/L 07/04/17 03:41 14808-79-8250000 500 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 4670 ug/L 07/08/17 01:54 16887-00-6 M11000 500 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367794
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92346154001, 92346154002, 92346154003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2038382
Associated Lab Samples:92346154001, 92346154002, 92346154003
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 07/11/17 06:520.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2038383LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2038384MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346179002
2038385
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 100 75-12599 1 252.5ND 2.5 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367657
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples: 92346154001, 92346154002, 92346154003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037842
Associated Lab Samples:92346154001, 92346154002, 92346154003
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 6.0 07/12/17 21:073.9
Arsenic ug/L ND 10.0 07/12/17 21:075.0
Barium ug/L ND 100 07/12/17 21:072.5
Beryllium ug/L ND 1.0 07/12/17 21:070.50
Cadmium ug/L ND 1.0 07/12/17 21:070.50
Chromium ug/L ND 10.0 07/12/17 21:072.5
Cobalt ug/L ND 10.0 07/12/17 21:072.5
Copper ug/L ND 10.0 07/12/17 21:072.5
Iron ug/L ND 300 07/12/17 21:0725.0
Lead ug/L ND 10.0 07/12/17 21:072.5
Manganese ug/L ND 50.0 07/12/17 21:072.5
Nickel ug/L ND 50.0 07/12/17 21:072.5
Selenium ug/L ND 10.0 07/12/17 21:075.0
Silver ug/L ND 10.0 07/12/17 21:072.5
Vanadium ug/L ND 25.0 07/12/17 21:072.5
Zinc ug/L ND 10.0 07/12/17 21:075.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037843LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 529500 106 80-120
Arsenic ug/L 520500 104 80-120
Barium ug/L 549500 110 80-120
Beryllium ug/L 532500 106 80-120
Cadmium ug/L 556500 111 80-120
Chromium ug/L 538500 108 80-120
Cobalt ug/L 546500 109 80-120
Copper ug/L 541500 108 80-120
Iron ug/L 51005000 102 80-120
Lead ug/L 537500 107 80-120
Manganese ug/L 536500 107 80-120
Nickel ug/L 517500 103 80-120
Selenium ug/L 557500 111 80-120
Silver ug/L 265250 106 80-120
Vanadium ug/L 526500 105 80-120
Zinc ug/L 555500 111 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037844MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346111005
2037845
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 102 75-125102 0 20500ND509 509
Arsenic ug/L 500 101 75-125101 1 20500ND505 507
Barium ug/L 500 109 75-125109 0 2050050.9J 597 595
Beryllium ug/L 500 104 75-125104 0 20500ND523 522
Cadmium ug/L 500 109 75-125109 0 20500ND544 545
Chromium ug/L 500 107 75-125107 0 205005.8J 540 539
Cobalt ug/L 500 107 75-125107 0 20500ND535 536
Copper ug/L 500 107 75-125107 0 205002.7J 536 539
Iron ug/L 5000 118 75-125122 2 20500026708560 8770
Lead ug/L 500 105 75-125105 0 20500ND526 527
Manganese ug/L 500 106 75-125107 1 2050029.6 558 562
Nickel ug/L 500 101 75-125102 1 205003.6J 510 513
Selenium ug/L 500 107 75-125108 1 20500ND537 540
Silver ug/L 250 103 75-125104 1 20250ND258 260
Vanadium ug/L 500 104 75-125104 0 205005.3J 523 525
Zinc ug/L 500 109 75-125108 1 2050012.1 557 550
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367648
EPA 3010A
EPA 6020B
6020 MET
Associated Lab Samples: 92346154001, 92346154002, 92346154003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037803
Associated Lab Samples:92346154001, 92346154002, 92346154003
Matrix: Water
AnalyzedMDL
Thallium ug/L ND 5.5 07/12/17 16:210.020
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037804LABORATORY CONTROL SAMPLE:
LCSSpike
Thallium ug/L 98.7100 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037805MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345862003
2037806
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Thallium ug/L 100 98 75-125101 3 20100ND98.2 101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367663
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92346154001, 92346154002, 92346154003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037868
Associated Lab Samples:92346154001, 92346154002, 92346154003
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 07/04/17 14:110.33
1,1,1-Trichloroethane ug/L ND 1.0 07/04/17 14:110.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 07/04/17 14:110.40
1,1,2-Trichloroethane ug/L ND 1.0 07/04/17 14:110.29
1,1-Dichloroethane ug/L ND 5.0 07/04/17 14:110.32
1,1-Dichloroethene ug/L ND 5.0 07/04/17 14:110.56
1,2,3-Trichloropropane ug/L ND 1.0 07/04/17 14:110.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 07/04/17 14:112.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 07/04/17 14:110.27
1,2-Dichlorobenzene ug/L ND 5.0 07/04/17 14:110.30
1,2-Dichloroethane ug/L ND 1.0 07/04/17 14:110.24
1,2-Dichloropropane ug/L ND 1.0 07/04/17 14:110.27
1,4-Dichlorobenzene ug/L ND 1.0 07/04/17 14:110.33
2-Butanone (MEK)ug/L ND 100 07/04/17 14:110.96
2-Hexanone ug/L ND 50.0 07/04/17 14:110.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 07/04/17 14:110.33
Acetone ug/L ND 100 07/04/17 14:1110.0
Acrylonitrile ug/L ND 200 07/04/17 14:111.9
Benzene ug/L ND 1.0 07/04/17 14:110.25
Bromochloromethane ug/L ND 3.0 07/04/17 14:110.17
Bromodichloromethane ug/L ND 1.0 07/04/17 14:110.18
Bromoform ug/L ND 3.0 07/04/17 14:110.26
Bromomethane ug/L ND 10.0 07/04/17 14:110.29
Carbon disulfide ug/L ND 100 07/04/17 14:111.2
Carbon tetrachloride ug/L ND 1.0 07/04/17 14:110.25
Chlorobenzene ug/L ND 3.0 07/04/17 14:110.23
Chloroethane ug/L ND 10.0 07/04/17 14:110.54
Chloroform ug/L ND 5.0 07/04/17 14:110.14
Chloromethane ug/L ND 1.0 07/04/17 14:110.11
cis-1,2-Dichloroethene ug/L ND 5.0 07/04/17 14:110.19
cis-1,3-Dichloropropene ug/L ND 1.0 07/04/17 14:110.13
Dibromochloromethane ug/L ND 3.0 07/04/17 14:110.21
Dibromomethane ug/L ND 10.0 07/04/17 14:110.21
Dichlorodifluoromethane ug/L ND 5.0 07/04/17 14:110.21
Ethylbenzene ug/L ND 1.0 07/04/17 14:110.30
Iodomethane ug/L ND 10.0 07/04/17 14:110.32
Isobutanol ug/L ND 100 07/04/17 14:1135.0
Methylene Chloride ug/L ND 1.0 07/04/17 14:110.97
Styrene ug/L ND 1.0 07/04/17 14:110.26
Tetrachloroethene ug/L ND 1.0 07/04/17 14:110.46
Tetrahydrofuran ug/L ND 10.0 07/04/17 14:113.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037868
Associated Lab Samples:92346154001, 92346154002, 92346154003
Matrix: Water
AnalyzedMDL
Toluene ug/L ND 1.0 07/04/17 14:110.26
trans-1,2-Dichloroethene ug/L ND 5.0 07/04/17 14:110.49
trans-1,3-Dichloropropene ug/L ND 1.0 07/04/17 14:110.26
trans-1,4-Dichloro-2-butene ug/L ND 100 07/04/17 14:111.0
Trichloroethene ug/L ND 1.0 07/04/17 14:110.47
Trichlorofluoromethane ug/L ND 1.0 07/04/17 14:110.20
Vinyl acetate ug/L ND 50.0 07/04/17 14:110.35
Vinyl chloride ug/L ND 1.0 07/04/17 14:110.62
Xylene (Total)ug/L ND 5.0 07/04/17 14:110.66
1,2-Dichloroethane-d4 (S)%103 70-130 07/04/17 14:11
4-Bromofluorobenzene (S)%99 70-130 07/04/17 14:11
Toluene-d8 (S)%104 70-130 07/04/17 14:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037869LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 48.850 98 80-125
1,1,1-Trichloroethane ug/L 49.450 99 71-129
1,1,2,2-Tetrachloroethane ug/L 47.550 95 79-124
1,1,2-Trichloroethane ug/L 47.050 94 85-125
1,1-Dichloroethane ug/L 49.550 99 73-126
1,1-Dichloroethene ug/L 48.350 97 66-135
1,2,3-Trichloropropane ug/L 45.650 91 75-130
1,2-Dibromo-3-chloropropane ug/L 52.750 105 71-133
1,2-Dibromoethane (EDB)ug/L 47.850 96 83-124
1,2-Dichlorobenzene ug/L 50.550 101 80-133
1,2-Dichloroethane ug/L 46.550 93 67-128
1,2-Dichloropropane ug/L 48.050 96 75-132
1,4-Dichlorobenzene ug/L 49.550 99 78-130
2-Butanone (MEK)ug/L 109100 109 61-144
2-Hexanone ug/L 101100 101 68-143
4-Methyl-2-pentanone (MIBK)ug/L 93.5J100 94 72-135
Acetone ug/L 135100 135 48-146
Acrylonitrile ug/L 257250 103 40-160
Benzene ug/L 47.750 95 80-125
Bromochloromethane ug/L 49.450 99 71-125
Bromodichloromethane ug/L 49.450 99 78-124
Bromoform ug/L 46.650 93 71-128
Bromomethane ug/L 47.150 94 40-160
Carbon disulfide ug/L 48.2J50 96 50-160
Carbon tetrachloride ug/L 47.250 94 69-131
Chlorobenzene ug/L 47.850 96 81-122
Chloroethane ug/L 46.650 93 39-148
Chloroform ug/L 49.450 99 73-127
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037869LABORATORY CONTROL SAMPLE:
LCSSpike
Chloromethane ug/L 56.650 113 44-146
cis-1,2-Dichloroethene ug/L 49.850 100 74-124
cis-1,3-Dichloropropene ug/L 50.950 102 72-132
Dibromochloromethane ug/L 50.750 101 78-125
Dibromomethane ug/L 45.150 90 82-120
Dichlorodifluoromethane ug/L 45.650 91 34-157
Ethylbenzene ug/L 49.650 99 79-121
Iodomethane ug/L 84.7100 85 39-154
Isobutanol ug/L 10601000 106 34-160
Methylene Chloride ug/L 51.350 103 64-133
Styrene ug/L 48.450 97 84-126
Tetrachloroethene ug/L 44.350 89 78-122
Tetrahydrofuran ug/L 499500 100 69-148
Toluene ug/L 47.450 95 80-121
trans-1,2-Dichloroethene ug/L 49.650 99 71-127
trans-1,3-Dichloropropene ug/L 49.850 100 69-141
trans-1,4-Dichloro-2-butene ug/L 78.3J50 157 40-160
Trichloroethene ug/L 46.550 93 78-122
Trichlorofluoromethane ug/L 45.850 92 53-137
Vinyl acetate ug/L 109100 109 40-160
Vinyl chloride ug/L 46.050 92 58-137
Xylene (Total)ug/L 146150 97 81-126
1,2-Dichloroethane-d4 (S)%105 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2037871MATRIX SPIKE SAMPLE:
MSSpike
Result
92346206008
1,1,1,2-Tetrachloroethane ug/L 20.420 102 70-130ND
1,1,1-Trichloroethane ug/L 21.220 106 70-130ND
1,1,2,2-Tetrachloroethane ug/L 20.520 102 70-130ND
1,1,2-Trichloroethane ug/L 20.220 101 70-130ND
1,1-Dichloroethane ug/L 21.020 105 70-130ND
1,1-Dichloroethene ug/L 21.520 107 70-166ND
1,2,3-Trichloropropane ug/L 20.520 103 70-130ND
1,2-Dibromo-3-chloropropane ug/L 21.420 107 70-130ND
1,2-Dibromoethane (EDB)ug/L 20.720 103 70-130ND
1,2-Dichlorobenzene ug/L 21.420 107 70-130ND
1,2-Dichloroethane ug/L 19.520 98 70-130ND
1,2-Dichloropropane ug/L 21.020 105 70-130ND
1,4-Dichlorobenzene ug/L 21.120 105 70-130ND
2-Butanone (MEK)ug/L 45.0J40 112 70-130ND
2-Hexanone ug/L 43.2J40 108 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 41.2J40 103 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2037871MATRIX SPIKE SAMPLE:
MSSpike
Result
92346206008
Acetone ug/L 67.8J40 129 70-13016.1J
Acrylonitrile ug/L 112J100 112 70-130ND
Benzene ug/L 20.920 104 70-148ND
Bromochloromethane ug/L 20.620 103 70-130ND
Bromodichloromethane ug/L 20.320 102 70-130ND
Bromoform ug/L 17.620 88 70-130ND
Bromomethane ug/L 20.220 101 70-130ND
Carbon disulfide ug/L 21.0J20 105 70-130ND
Carbon tetrachloride ug/L 21.420 107 70-130ND
Chlorobenzene ug/L 21.120 105 70-146ND
Chloroethane ug/L 20.320 102 70-130ND
Chloroform ug/L 22.020 107 70-1300.55J
Chloromethane ug/L 19.820 99 70-130ND
cis-1,2-Dichloroethene ug/L 21.320 107 70-130ND
cis-1,3-Dichloropropene ug/L 20.320 101 70-130ND
Dibromochloromethane ug/L 20.520 102 70-130ND
Dibromomethane ug/L 19.320 96 70-130ND
Dichlorodifluoromethane ug/L 16.620 83 70-130ND
Ethylbenzene ug/L 22.120 110 70-130ND
Iodomethane ug/L 36.240 91 70-130ND
Isobutanol ug/L 443400 111 70-130ND
Methylene Chloride ug/L 19.020 95 70-130ND
Styrene ug/L 20.820 104 70-130ND
Tetrachloroethene ug/L 24.220 101 70-1304.0
Tetrahydrofuran ug/L 217200 108 70-130ND
Toluene ug/L 21.320 107 70-155ND
trans-1,2-Dichloroethene ug/L 21.820 109 70-130ND
trans-1,3-Dichloropropene ug/L 20.120 101 70-130ND
trans-1,4-Dichloro-2-butene ug/L 17.4J20 87 70-130ND
Trichloroethene ug/L 20.220 101 69-151ND
Trichlorofluoromethane ug/L 21.020 105 70-130ND
Vinyl acetate ug/L 39.1J40 98 70-130ND
Vinyl chloride ug/L 21.120 105 70-130ND
1,2-Dichloroethane-d4 (S)%104 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%102 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92346206005
2037870SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92346206005
2037870SAMPLE DUPLICATE:
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L 0.28J 30ND
1,2-Dichloropropane ug/L 2.0 7 302.1
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L 25.4J 3019.0J
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L 1.8J 2 301.8
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Isobutanol ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L 7.1 1 307.0
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L 1.9 1 301.9
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%103 1104
4-Bromofluorobenzene (S)%98 197
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
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Page 21 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92346206005
2037870SAMPLE DUPLICATE:
Toluene-d8 (S)%103 0103
REPORT OF LABORATORY ANALYSIS
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Page 22 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367212
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples: 92346154001, 92346154002, 92346154003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2035586
Associated Lab Samples:92346154001, 92346154002, 92346154003
Matrix: Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 07/01/17 14:331000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2035587LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4990050000 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2035588MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345640002
2035589
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L M1500009380-120128 2 2550000732 mg/L 778000 796000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2035590MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345867005
2035591
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 90 80-12089 0 255000099100144000 143000
REPORT OF LABORATORY ANALYSIS
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Page 23 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367250
SM 2540C
SM 2540C
2540C Total Dissolved Solids
Associated Lab Samples: 92346154001, 92346154002, 92346154003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2035726
Associated Lab Samples:92346154001, 92346154002, 92346154003
Matrix: Water
AnalyzedMDL
Total Dissolved Solids ug/L ND 25000 06/30/17 10:0325000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2035727LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids ug/L 234000250000 94 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92345864001
2035728SAMPLE DUPLICATE:
Total Dissolved Solids ug/L ND 5ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92346154002
2035729SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 26000 D67528000
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
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[phone]
Page 24 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367513
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples: 92346154001, 92346154002, 92346154003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037182
Associated Lab Samples:92346154001, 92346154002, 92346154003
Matrix: Water
AnalyzedMDL
Sulfate ug/L ND 250000 07/04/17 00:32500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037183LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 50600J50000 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037184MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346111005
2037185
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 50000 105 90-110106 1 10500001010J53400J 54000J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037186MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346168027
2037187
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 50000 106 90-110107 1 10500005310J58200J 58800J
REPORT OF LABORATORY ANALYSIS
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Page 25 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
368013
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples: 92346154001, 92346154002, 92346154003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2039606
Associated Lab Samples:92346154001, 92346154002, 92346154003
Matrix: Water
AnalyzedMDL
Chloride ug/L ND 1000 07/08/17 02:14500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2039607LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 2190020000 109 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2039608MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346187005
2039609
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M11000011790-110117 0 10100002.9 mg/L 14500 14500
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2039610MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346154003
2039611
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M11000012090-110119 1 1010000467016700 16600
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
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Page 26 of 31
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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Page 27 of 31
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92346154
JOHNS R. -PHASE 1A GW
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92346154001 367657 3682421203-MW-20 EPA 3010A EPA 6010
92346154002 367657 3682421203-MW-22S EPA 3010A EPA 6010
92346154003 367657 3682421203-MW-38 EPA 3010A EPA 6010
92346154001 367648 3684581203-MW-20 EPA 3010A EPA 6020B
92346154002 367648 3684581203-MW-22S EPA 3010A EPA 6020B
92346154003 367648 3684581203-MW-38 EPA 3010A EPA 6020B
92346154001 367794 3683251203-MW-20 EPA 7470 EPA 7470
92346154002 367794 3683251203-MW-22S EPA 7470 EPA 7470
92346154003 367794 3683251203-MW-38 EPA 7470 EPA 7470
92346154001 3676631203-MW-20 EPA 8260
92346154002 3676631203-MW-22S EPA 8260
92346154003 3676631203-MW-38 EPA 8260
92346154001 3672121203-MW-20 SM 2320B
92346154002 3672121203-MW-22S SM 2320B
92346154003 3672121203-MW-38 SM 2320B
92346154001 3672501203-MW-20 SM 2540C
92346154002 3672501203-MW-22S SM 2540C
92346154003 3672501203-MW-38 SM 2540C
92346154001 3675131203-MW-20 EPA 300.0
92346154002 3675131203-MW-22S EPA 300.0
92346154003 3675131203-MW-38 EPA 300.0
92346154001 3680131203-MW-20 SM 4500-Cl-E
92346154002 3680131203-MW-22S SM 4500-Cl-E
92346154003 3680131203-MW-38 SM 4500-Cl-E
REPORT OF LABORATORY ANALYSIS
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Page 28 of 31
Page 29 of 31
Page 30 of 31
Page 31 of 31
#=CL#
July 12, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92345864
92345864
Project:
Pace Project No.:
RE:
Mr. Van BurbachJoyce Engineering-Greensboro2211 West Meadowview RdBoone Bldg, Suite 101Greensboro, NC 27407
JOHNS R. BACKGROUND
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on June 28, 2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager(704)875-9092
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 1 of 30
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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Page 2 of 30
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Lab ID Sample ID Matrix Date Collected Date Received
92345864001 1203-MW21 Water 06/27/17 10:45 06/28/17 09:28
REPORT OF LABORATORY ANALYSIS
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Page 3 of 30
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92345864001 1203-MW21 EPA 8081 4 PASI-CRES
EPA 6010 17 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AKAL
EPA 8260 53 PASI-CZDO
SM 2320B 1 PASI-AKDF1
SM 2540C 1 PASI-ASLB
SM 4500-S2D 1 PASI-AMVC
EPA 300.0 1 PASI-ACDC
SM 4500-Cl-E 1 PASI-ABRJ
SM 4500-CN-E 1 PASI-AAES2
REPORT OF LABORATORY ANALYSIS
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Page 4 of 30
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92345864001 1203-MW21
Barium 18.8J ug/L 07/12/17 06:20100EPA 6010
Copper 3.9J ug/L 07/09/17 00:2610.0EPA 6010
Iron 2340 ug/L 07/09/17 00:26300EPA 6010
Manganese 60.3 ug/L 07/09/17 00:2650.0EPA 6010
Vanadium 9.4J ug/L 07/09/17 00:2625.0EPA 6010
Zinc 8.2J ug/L 07/09/17 00:2610.0EPA 6010
Acetone 35.8J ug/L 06/30/17 00:44 L1100EPA 8260
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Sample: 1203-MW21 Lab ID: 92345864001 Collected: 06/27/17 10:45 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
alpha-BHC ND ug/L 07/07/17 15:40 319-84-606/29/17 13:000.050 0.050 1
beta-BHC ND ug/L 07/07/17 15:40 319-85-706/29/17 13:000.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)65 %07/07/17 15:40 877-09-806/29/17 13:0020-130 1
Decachlorobiphenyl (S)52 %07/07/17 15:40 2051-24-306/29/17 13:0020-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 07/09/17 00:26 7440-36-006/29/17 16:156.0 3.9 1
Arsenic ND ug/L 07/09/17 00:26 7440-38-206/29/17 16:1510.0 5.0 1
Barium 18.8J ug/L 07/12/17 06:20 7440-39-306/29/17 16:15100 2.5 1
Beryllium ND ug/L 07/09/17 00:26 7440-41-706/29/17 16:151.0 0.50 1
Cadmium ND ug/L 07/09/17 00:26 7440-43-906/29/17 16:151.0 0.50 1
Chromium ND ug/L 07/09/17 00:26 7440-47-306/29/17 16:1510.0 2.5 1
Cobalt ND ug/L 07/09/17 00:26 7440-48-406/29/17 16:1510.0 2.5 1
Copper 3.9J ug/L 07/09/17 00:26 7440-50-806/29/17 16:1510.0 2.5 1
Iron 2340 ug/L 07/09/17 00:26 7439-89-606/29/17 16:15300 25.0 1
Lead ND ug/L 07/09/17 00:26 7439-92-106/29/17 16:1510.0 2.5 1
Manganese 60.3 ug/L 07/09/17 00:26 7439-96-506/29/17 16:1550.0 2.5 1
Nickel ND ug/L 07/09/17 00:26 7440-02-006/29/17 16:1550.0 2.5 1
Selenium ND ug/L 07/09/17 00:26 7782-49-206/29/17 16:1510.0 5.0 1
Silver ND ug/L 07/09/17 00:26 7440-22-406/29/17 16:1510.0 2.5 1
Tin ND ug/L 07/09/17 00:26 7440-31-506/29/17 16:155.0 2.5 1
Vanadium 9.4J ug/L 07/09/17 00:26 7440-62-206/29/17 16:1525.0 2.5 1
Zinc 8.2J ug/L 07/09/17 00:26 7440-66-606/29/17 16:1510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 07/08/17 21:10 7440-28-007/01/17 07:255.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 07/07/17 04:01 7439-97-607/05/17 15:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 35.8J ug/L 06/30/17 00:44 67-64-1 L1100 10.0 1
Acrylonitrile ND ug/L 06/30/17 00:44 107-13-1200 1.9 1
Benzene ND ug/L 06/30/17 00:44 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 06/30/17 00:44 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 06/30/17 00:44 75-27-41.0 0.18 1
Bromoform ND ug/L 06/30/17 00:44 75-25-23.0 0.26 1
Bromomethane ND ug/L 06/30/17 00:44 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 06/30/17 00:44 78-93-3 L1100 0.96 1
Carbon disulfide ND ug/L 06/30/17 00:44 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 06/30/17 00:44 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 06/30/17 00:44 108-90-73.0 0.23 1
Chloroethane ND ug/L 06/30/17 00:44 75-00-310.0 0.54 1
Chloroform ND ug/L 06/30/17 00:44 67-66-35.0 0.14 1
REPORT OF LABORATORY ANALYSIS
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Page 6 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Sample: 1203-MW21 Lab ID: 92345864001 Collected: 06/27/17 10:45 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Chloromethane ND ug/L 06/30/17 00:44 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 06/30/17 00:44 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 06/30/17 00:44 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 06/30/17 00:44 106-93-41.0 0.27 1
Dibromomethane ND ug/L 06/30/17 00:44 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 06/30/17 00:44 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 06/30/17 00:44 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 06/30/17 00:44 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 06/30/17 00:44 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 06/30/17 00:44 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 06/30/17 00:44 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 06/30/17 00:44 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 06/30/17 00:44 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 06/30/17 00:44 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 06/30/17 00:44 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 06/30/17 00:44 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 06/30/17 00:44 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 06/30/17 00:44 100-41-41.0 0.30 1
2-Hexanone ND ug/L 06/30/17 00:44 591-78-650.0 0.46 1
Iodomethane ND ug/L 06/30/17 00:44 74-88-410.0 0.32 1
Isobutanol ND ug/L 06/30/17 00:44 78-83-1100 35.0 1
Methylene Chloride ND ug/L 06/30/17 00:44 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 06/30/17 00:44 108-10-1100 0.33 1
Styrene ND ug/L 06/30/17 00:44 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 06/30/17 00:44 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 06/30/17 00:44 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 06/30/17 00:44 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 06/30/17 00:44 109-99-910.0 3.1 1
Toluene ND ug/L 06/30/17 00:44 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 06/30/17 00:44 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 06/30/17 00:44 79-00-51.0 0.29 1
Trichloroethene ND ug/L 06/30/17 00:44 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 06/30/17 00:44 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 06/30/17 00:44 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 06/30/17 00:44 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 06/30/17 00:44 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 06/30/17 00:44 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)102 %06/30/17 00:44 460-00-470-130 1
1,2-Dichloroethane-d4 (S)114 %06/30/17 00:44 17060-07-070-130 1
Toluene-d8 (S)106 %06/30/17 00:44 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 ND ug/L 07/01/17 17:245000 1000 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
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Huntersville, NC 28078
[phone]
Page 7 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Sample: 1203-MW21 Lab ID: 92345864001 Collected: 06/27/17 10:45 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids ND ug/L 06/30/17 10:0425000 25000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 07/03/17 20:00 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate ND ug/L 07/04/17 00:12 14808-79-8250000 500 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride ND ug/L 07/08/17 01:14 16887-00-61000 500 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 07/07/17 14:06 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
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[phone]
Page 8 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367714
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037984
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 07/07/17 03:260.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037985LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.72.5 107 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037986MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346178003
2037987
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L M12.5 55 75-12560 8 252.5ND 1.6 1.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 9 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
366984
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2034185
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 6.0 07/08/17 23:373.9
Arsenic ug/L ND 10.0 07/08/17 23:375.0
Barium ug/L ND 100 07/12/17 05:212.5
Beryllium ug/L ND 1.0 07/08/17 23:370.50
Cadmium ug/L ND 1.0 07/08/17 23:370.50
Chromium ug/L ND 10.0 07/08/17 23:372.5
Cobalt ug/L ND 10.0 07/08/17 23:372.5
Copper ug/L ND 10.0 07/08/17 23:372.5
Iron ug/L ND 300 07/08/17 23:3725.0
Lead ug/L ND 10.0 07/08/17 23:372.5
Manganese ug/L ND 50.0 07/08/17 23:372.5
Nickel ug/L ND 50.0 07/08/17 23:372.5
Selenium ug/L ND 10.0 07/08/17 23:375.0
Silver ug/L ND 10.0 07/08/17 23:372.5
Tin ug/L ND 5.0 07/12/17 05:212.5
Vanadium ug/L ND 25.0 07/08/17 23:372.5
Zinc ug/L ND 10.0 07/12/17 05:215.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2034189LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 521500 104 80-120
Arsenic ug/L 504500 101 80-120
Barium ug/L 477500 95 80-120
Beryllium ug/L 481500 96 80-120
Cadmium ug/L 500500 100 80-120
Chromium ug/L 485500 97 80-120
Cobalt ug/L 508500 102 80-120
Copper ug/L 512500 102 80-120
Iron ug/L 50705000 101 80-120
Lead ug/L 500500 100 80-120
Manganese ug/L 497500 99 80-120
Nickel ug/L 488500 98 80-120
Selenium ug/L 526500 105 80-120
Silver ug/L 258250 103 80-120
Tin ug/L 497500 99 80-120
Vanadium ug/L 489500 98 80-120
Zinc ug/L 513500 103 80-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2034190MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345849003
2034191
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 105 75-125108 2 20500ND527 538
Arsenic ug/L 500 104 75-125106 2 20500ND518 528
Barium ug/L 500 95 75-12593 1 20500448922 912
Beryllium ug/L 500 99 75-12597 1 20500ND494 487
Cadmium ug/L 500 101 75-125102 1 205002.5 508 514
Chromium ug/L 500 98 75-12598 0 20500ND491 490
Cobalt ug/L 500 100 75-125101 1 2050056.6 554 562
Copper ug/L 500 103 75-125103 0 20500ND516 518
Iron ug/L 5000 100 75-12596 3 20500028207840 7610
Lead ug/L 500 98 75-12599 2 20500ND490 498
Manganese ug/L M15009575-12546 5 2050042504720 4480
Nickel ug/L 500 95 75-12596 1 2050044.9J 521 526
Selenium ug/L 500 104 75-125107 2 20500ND522 534
Silver ug/L 250 104 75-125104 0 20250ND260 260
Tin ug/L 500 103 75-125105 2 20500ND516 526
Vanadium ug/L 500 101 75-125101 0 205005.3J 508 509
Zinc ug/L 500 101 75-125103 2 2050011.0 516 525
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367201
EPA 3010A
EPA 6020B
6020 MET
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2035540
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Thallium ug/L ND 5.5 07/08/17 20:220.020
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2035541LABORATORY CONTROL SAMPLE:
LCSSpike
Thallium ug/L 103100 103 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2035542MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345640003
2035543
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Thallium ug/L 100 100 75-125101 1 20100ND100 101
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367160
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2035365
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 06/29/17 23:520.33
1,1,1-Trichloroethane ug/L ND 1.0 06/29/17 23:520.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 06/29/17 23:520.40
1,1,2-Trichloroethane ug/L ND 1.0 06/29/17 23:520.29
1,1-Dichloroethane ug/L ND 5.0 06/29/17 23:520.32
1,1-Dichloroethene ug/L ND 5.0 06/29/17 23:520.56
1,2,3-Trichloropropane ug/L ND 1.0 06/29/17 23:520.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 06/29/17 23:522.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 06/29/17 23:520.27
1,2-Dichlorobenzene ug/L ND 5.0 06/29/17 23:520.30
1,2-Dichloroethane ug/L ND 1.0 06/29/17 23:520.24
1,2-Dichloropropane ug/L ND 1.0 06/29/17 23:520.27
1,4-Dichlorobenzene ug/L ND 1.0 06/29/17 23:520.33
2-Butanone (MEK)ug/L ND 100 06/29/17 23:520.96
2-Hexanone ug/L ND 50.0 06/29/17 23:520.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 06/29/17 23:520.33
Acetone ug/L ND 100 06/29/17 23:5210.0
Acrylonitrile ug/L ND 200 06/29/17 23:521.9
Benzene ug/L ND 1.0 06/29/17 23:520.25
Bromochloromethane ug/L ND 3.0 06/29/17 23:520.17
Bromodichloromethane ug/L ND 1.0 06/29/17 23:520.18
Bromoform ug/L ND 3.0 06/29/17 23:520.26
Bromomethane ug/L ND 10.0 06/29/17 23:520.29
Carbon disulfide ug/L ND 100 06/29/17 23:521.2
Carbon tetrachloride ug/L ND 1.0 06/29/17 23:520.25
Chlorobenzene ug/L ND 3.0 06/29/17 23:520.23
Chloroethane ug/L ND 10.0 06/29/17 23:520.54
Chloroform ug/L ND 5.0 06/29/17 23:520.14
Chloromethane ug/L ND 1.0 06/29/17 23:520.11
cis-1,2-Dichloroethene ug/L ND 5.0 06/29/17 23:520.19
cis-1,3-Dichloropropene ug/L ND 1.0 06/29/17 23:520.13
Dibromochloromethane ug/L ND 3.0 06/29/17 23:520.21
Dibromomethane ug/L ND 10.0 06/29/17 23:520.21
Dichlorodifluoromethane ug/L ND 5.0 06/29/17 23:520.21
Ethylbenzene ug/L ND 1.0 06/29/17 23:520.30
Iodomethane ug/L ND 10.0 06/29/17 23:520.32
Isobutanol ug/L ND 100 06/29/17 23:5235.0
Methylene Chloride ug/L ND 1.0 06/29/17 23:520.97
Styrene ug/L ND 1.0 06/29/17 23:520.26
Tetrachloroethene ug/L ND 1.0 06/29/17 23:520.46
Tetrahydrofuran ug/L ND 10.0 06/29/17 23:523.1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2035365
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Toluene ug/L ND 1.0 06/29/17 23:520.26
trans-1,2-Dichloroethene ug/L ND 5.0 06/29/17 23:520.49
trans-1,3-Dichloropropene ug/L ND 1.0 06/29/17 23:520.26
trans-1,4-Dichloro-2-butene ug/L ND 100 06/29/17 23:521.0
Trichloroethene ug/L ND 1.0 06/29/17 23:520.47
Trichlorofluoromethane ug/L ND 1.0 06/29/17 23:520.20
Vinyl acetate ug/L ND 50.0 06/29/17 23:520.35
Vinyl chloride ug/L ND 1.0 06/29/17 23:520.62
Xylene (Total)ug/L ND 5.0 06/29/17 23:520.66
1,2-Dichloroethane-d4 (S)%112 70-130 06/29/17 23:52
4-Bromofluorobenzene (S)%103 70-130 06/29/17 23:52
Toluene-d8 (S)%105 70-130 06/29/17 23:52
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2035366LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 47.350 95 80-125
1,1,1-Trichloroethane ug/L 45.050 90 71-129
1,1,2,2-Tetrachloroethane ug/L 48.550 97 79-124
1,1,2-Trichloroethane ug/L 46.650 93 85-125
1,1-Dichloroethane ug/L 45.750 91 73-126
1,1-Dichloroethene ug/L 47.950 96 66-135
1,2,3-Trichloropropane ug/L 49.150 98 75-130
1,2-Dibromo-3-chloropropane ug/L 53.250 106 71-133
1,2-Dibromoethane (EDB)ug/L 47.850 96 83-124
1,2-Dichlorobenzene ug/L 42.050 84 80-133
1,2-Dichloroethane ug/L 46.150 92 67-128
1,2-Dichloropropane ug/L 46.050 92 75-132
1,4-Dichlorobenzene ug/L 40.650 81 78-130
2-Butanone (MEK)ug/L 148 L1100148 61-144
2-Hexanone ug/L 128100 128 68-143
4-Methyl-2-pentanone (MIBK)ug/L 113100 113 72-135
Acetone ug/L 160 L1100160 48-146
Acrylonitrile ug/L 336250 134 40-160
Benzene ug/L 45.850 92 80-125
Bromochloromethane ug/L 47.250 94 71-125
Bromodichloromethane ug/L 44.650 89 78-124
Bromoform ug/L 44.350 89 71-128
Bromomethane ug/L 32.850 66 40-160
Carbon disulfide ug/L 45.4J50 91 50-160
Carbon tetrachloride ug/L 41.850 84 69-131
Chlorobenzene ug/L 42.250 84 81-122
Chloroethane ug/L 41.750 83 39-148
Chloroform ug/L 45.950 92 73-127
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
Page 14 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2035366LABORATORY CONTROL SAMPLE:
LCSSpike
Chloromethane ug/L 45.650 91 44-146
cis-1,2-Dichloroethene ug/L 49.550 99 74-124
cis-1,3-Dichloropropene ug/L 46.650 93 72-132
Dibromochloromethane ug/L 49.850 100 78-125
Dibromomethane ug/L 45.550 91 82-120
Dichlorodifluoromethane ug/L 49.750 99 34-157
Ethylbenzene ug/L 41.850 84 79-121
Iodomethane ug/L 65.3100 65 39-154
Isobutanol ug/L 14301000 143 34-160
Methylene Chloride ug/L 53.250 106 64-133
Styrene ug/L 42.550 85 84-126
Tetrachloroethene ug/L 40.450 81 78-122
Tetrahydrofuran ug/L 718500 144 69-148
Toluene ug/L 43.150 86 80-121
trans-1,2-Dichloroethene ug/L 46.250 92 71-127
trans-1,3-Dichloropropene ug/L 43.950 88 69-141
trans-1,4-Dichloro-2-butene ug/L 62.3J50 125 40-160
Trichloroethene ug/L 44.550 89 78-122
Trichlorofluoromethane ug/L 44.450 89 53-137
Vinyl acetate ug/L 105100 105 40-160
Vinyl chloride ug/L 46.050 92 58-137
Xylene (Total)ug/L 126150 84 81-126
1,2-Dichloroethane-d4 (S)%101 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%96 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2035367MATRIX SPIKE SAMPLE:
MSSpike
Result
92345640018
1,1,1,2-Tetrachloroethane ug/L 17.820 89 70-130ND
1,1,1-Trichloroethane ug/L 19.920 99 70-130ND
1,1,2,2-Tetrachloroethane ug/L 18.520 93 70-130ND
1,1,2-Trichloroethane ug/L 19.720 98 70-130ND
1,1-Dichloroethane ug/L 19.820 96 70-1300.62J
1,1-Dichloroethene ug/L 20.420 102 70-166ND
1,2,3-Trichloropropane ug/L 19.920 99 70-130ND
1,2-Dibromo-3-chloropropane ug/L 22.120 111 70-130ND
1,2-Dibromoethane (EDB)ug/L 18.720 94 70-130ND
1,2-Dichlorobenzene ug/L 17.320 87 70-130ND
1,2-Dichloroethane ug/L 20.120 101 70-130ND
1,2-Dichloropropane ug/L 19.420 97 70-130ND
1,4-Dichlorobenzene ug/L 19.520 83 70-1303.0
2-Butanone (MEK)ug/L 56.5J M040141 70-130ND
2-Hexanone ug/L 48.8J40 122 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 48.8J40 122 70-130ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
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[phone]
Page 15 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2035367MATRIX SPIKE SAMPLE:
MSSpike
Result
92345640018
Acetone ug/L 75.9J M040133 70-13022.8J
Acrylonitrile ug/L 139J M1100139 70-130ND
Benzene ug/L 19.520 97 70-148ND
Bromochloromethane ug/L 19.420 97 70-130ND
Bromodichloromethane ug/L 18.220 91 70-130ND
Bromoform ug/L 16.020 80 70-130ND
Bromomethane ug/L 12.5 M12063 70-130ND
Carbon disulfide ug/L 20.3J20 101 70-130ND
Carbon tetrachloride ug/L 18.520 92 70-130ND
Chlorobenzene ug/L 23.020 83 70-1466.4
Chloroethane ug/L 20.320 102 70-130ND
Chloroform ug/L 18.420 92 70-130ND
Chloromethane ug/L 22.520 113 70-130ND
cis-1,2-Dichloroethene ug/L 23.820 102 70-1303.4
cis-1,3-Dichloropropene ug/L 17.520 88 70-130ND
Dibromochloromethane ug/L 18.820 94 70-130ND
Dibromomethane ug/L 19.920 100 70-130ND
Dichlorodifluoromethane ug/L 21.720 108 70-130ND
Ethylbenzene ug/L 16.620 83 70-130ND
Iodomethane ug/L 32.440 81 70-130ND
Isobutanol ug/L 581 M1400145 70-130ND
Methylene Chloride ug/L 22.520 112 70-130ND
Styrene ug/L 16.620 83 70-130ND
Tetrachloroethene ug/L 16.320 81 70-130ND
Tetrahydrofuran ug/L 298 M1200147 70-1304.8J
Toluene ug/L 19.120 96 70-155ND
trans-1,2-Dichloroethene ug/L 20.020 100 70-130ND
trans-1,3-Dichloropropene ug/L 18.220 91 70-130ND
trans-1,4-Dichloro-2-butene ug/L 17.9J20 90 70-130ND
Trichloroethene ug/L 19.320 96 69-151ND
Trichlorofluoromethane ug/L 20.420 102 70-130ND
Vinyl acetate ug/L 34.8J40 87 70-130ND
Vinyl chloride ug/L 21.820 109 70-130ND
1,2-Dichloroethane-d4 (S)%110 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92345640019
2035368SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 0.98J 300.88J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
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[phone]
Page 16 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92345640019
2035368SAMPLE DUPLICATE:
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 1.3 21 301.1
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L 14.9J 3011.8J
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 1.1J 8 301.0
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L 0.57J 300.55J
cis-1,2-Dichloroethene ug/L 10.7 3 3010.4
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Isobutanol ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L 0.80J 300.89J
Tetrahydrofuran ug/L 4.0J 304.2J
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L 2.7 2 302.8
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 300.78J
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%114 0114
4-Bromofluorobenzene (S)%102 1101
REPORT OF LABORATORY ANALYSIS
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Page 17 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92345640019
2035368SAMPLE DUPLICATE:
Toluene-d8 (S)%106 1105
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367064
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2034599
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
alpha-BHC ug/L ND 0.050 07/06/17 22:480.050
beta-BHC ug/L ND 0.050 07/06/17 22:480.050
Decachlorobiphenyl (S)%58 20-130 07/06/17 22:48
Tetrachloro-m-xylene (S)%77 20-130 07/06/17 22:48
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2034600LABORATORY CONTROL SAMPLE:
LCSSpike
alpha-BHC ug/L 0.20.25 82 20-150
beta-BHC ug/L 0.18.25 74 20-150
Decachlorobiphenyl (S)%88 20-130
Tetrachloro-m-xylene (S)%87 20-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2034601MATRIX SPIKE SAMPLE:
MSSpike
Result
92345640011
alpha-BHC ug/L 0.14.25 58 20-150ND
beta-BHC ug/L 0.12.25 49 20-150ND
Decachlorobiphenyl (S)%61 20-130
Tetrachloro-m-xylene (S)%63 20-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92345640012
2034602SAMPLE DUPLICATE:
alpha-BHC ug/L ND 30ND
beta-BHC ug/L ND 30ND
Decachlorobiphenyl (S)%62 867
Tetrachloro-m-xylene (S)%74 3353
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
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Page 19 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367212
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2035586
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 07/01/17 14:331000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2035587LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4990050000 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2035588MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345640002
2035589
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L M1500009380-120128 2 2550000732 mg/L 778000 796000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2035590MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345867005
2035591
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 90 80-12089 0 255000099100144000 143000
REPORT OF LABORATORY ANALYSIS
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Page 20 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367250
SM 2540C
SM 2540C
2540C Total Dissolved Solids
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2035726
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Total Dissolved Solids ug/L ND 25000 06/30/17 10:0325000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2035727LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids ug/L 234000250000 94 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92345864001
2035728SAMPLE DUPLICATE:
Total Dissolved Solids ug/L ND 5ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92346154002
2035729SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 26000 D67528000
REPORT OF LABORATORY ANALYSIS
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Page 21 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367596
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037603
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Sulfide ug/L ND 1000 07/03/17 20:00100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037604LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 497J500 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037605MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345769001
2037606
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 96 80-12098 2 10500ND503J 513J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037607MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345640015
2037608
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L M15006680-12067 2 10500ND336J 343J
REPORT OF LABORATORY ANALYSIS
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Page 22 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367506
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037142
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Sulfate ug/L ND 250000 07/03/17 13:29500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037143LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 52600J50000 105 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037144MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345945089
2037145
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 50000 101 90-110102 1 105000032.0 mg/L 82500J 83200J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037206MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345867001
2037207
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 50000 108 90-110109 1 10500005290J59500J 59900J
REPORT OF LABORATORY ANALYSIS
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Page 23 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
368012
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2039600
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Chloride ug/L ND 1000 07/08/17 01:00500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2039601LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 2160020000 108 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2039602MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346191001
2039603
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M11000011990-110118 1 10100001.6 mg/L 13500 13400
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2039604MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345867003
2039605
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 10000 109 90-110108 0 10100001040021300 21300
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
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Page 24 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367925
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2039007
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Cyanide ug/L ND 10.0 07/07/17 13:474.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2039008LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 99.9100 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2039009MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346296007
2039010
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L M1,R11003980-12054 19 101000.030mg/L 69.3 83.9
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2039011MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345640016
2039012
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 93 80-12091 2 10100ND94.0 91.7
REPORT OF LABORATORY ANALYSIS
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Page 25 of 30
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associatedsamples may be biased high.L1
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
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Page 26 of 30
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92345864001 367064 3672261203-MW21 EPA 3510 EPA 8081
92345864001 366984 3680021203-MW21 EPA 3010A EPA 6010
92345864001 367201 3677901203-MW21 EPA 3010A EPA 6020B
92345864001 367714 3680241203-MW21 EPA 7470 EPA 7470
92345864001 3671601203-MW21 EPA 8260
92345864001 3672121203-MW21 SM 2320B
92345864001 3672501203-MW21 SM 2540C
92345864001 3675961203-MW21 SM 4500-S2D
92345864001 3675061203-MW21 EPA 300.0
92345864001 3680121203-MW21 SM 4500-Cl-E
92345864001 3679251203-MW21 SM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
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[phone]
Page 27 of 30
Page 28 of 30
Page 29 of 30
Page 30 of 30
#=CL#
July 18, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92346145
92346145
Project:
Pace Project No.:
RE:
Mr. Van BurbachJoyce Engineering-Greensboro2211 West Meadowview RdBoone Bldg, Suite 101Greensboro, NC 27407
JOHNS R.-ADD MW LFG
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on June 28, 2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.
Some analyses have been subcontracted outside of the Pace Network. The subcontractedlaboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager(704)875-9092
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 1 of 37
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
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Page 2 of 37
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Lab ID Sample ID Matrix Date Collected Date Received
92346145001 1203-MW-15S Water 06/28/17 08:45 06/28/17 12:45
92346145002 1203-PZ-12 Water 06/28/17 09:45 06/28/17 12:45
92346145003 1203-PZ-30S Water 06/28/17 08:15 06/28/17 12:45
92346145004 1203-PZ-31 Water 06/28/17 08:24 06/28/17 12:45
92346145005 1203-PZ-35 Water 06/28/17 11:13 06/28/17 12:45
92346145006 1203-PZ-36 Water 06/28/17 10:23 06/28/17 12:45
92346145007 1203-MW-38 Water 06/28/17 10:53 06/28/17 12:45
REPORT OF LABORATORY ANALYSIS
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Page 3 of 37
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92346145001 1203-MW-15S RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CGAW
92346145002 1203-PZ-12 RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CGAW
92346145003 1203-PZ-30S RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CGAW
92346145004 1203-PZ-31 RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CGAW
92346145005 1203-PZ-35 RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CGAW
92346145006 1203-PZ-36 RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CGAW
92346145007 1203-MW-38 RSK 175 Modified 1 PASI-CWDV
REPORT OF LABORATORY ANALYSIS
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Page 4 of 37
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92346145001 1203-MW-15S
Methane 25900 ug/L 07/03/17 10:53100RSK 175 Modified
Benzene 0.43J ug/L 07/01/17 18:221.0EPA 8260
1,1-Dichloroethane 0.59J ug/L 07/01/17 18:225.0EPA 8260
Tetrachloroethene 0.80J ug/L 07/01/17 18:221.0EPA 8260
92346145006 1203-PZ-36
Methane 45400 ug/L 07/03/17 11:08100RSK 175 Modified
Benzene 5.3 ug/L 07/01/17 19:511.0EPA 8260
1,4-Dichlorobenzene 20.1 ug/L 07/01/17 19:511.0EPA 8260
1,1-Dichloroethane 4.3J ug/L 07/01/17 19:515.0EPA 8260
1,2-Dichloroethane 0.75J ug/L 07/01/17 19:511.0EPA 8260
Vinyl chloride 0.64J ug/L 07/01/17 19:511.0EPA 8260
92346145007 1203-MW-38
Methane 35400 ug/L 07/03/17 11:24100RSK 175 Modified
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Sample: 1203-MW-15S Lab ID: 92346145001 Collected: 06/28/17 08:45 Received: 06/28/17 12:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 25900 ug/L 07/03/17 10:53 74-82-8100 100 10
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene 0.43J ug/L 07/01/17 18:22 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 07/01/17 18:22 106-46-71.0 0.33 1
1,1-Dichloroethane 0.59J ug/L 07/01/17 18:22 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/01/17 18:22 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 07/01/17 18:22 75-09-21.0 0.97 1
Tetrachloroethene 0.80J ug/L 07/01/17 18:22 127-18-41.0 0.46 1
Trichloroethene ND ug/L 07/01/17 18:22 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 07/01/17 18:22 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)98 %07/01/17 18:22 460-00-470-130 1
1,2-Dichloroethane-d4 (S)94 %07/01/17 18:22 17060-07-070-130 1
Toluene-d8 (S)103 %07/01/17 18:22 2037-26-570-130 1
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Sample: 1203-PZ-12 Lab ID: 92346145002 Collected: 06/28/17 09:45 Received: 06/28/17 12:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/02/17 13:36 74-82-810.0 10.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 07/01/17 18:40 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 07/01/17 18:40 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 07/01/17 18:40 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/01/17 18:40 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 07/01/17 18:40 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 07/01/17 18:40 127-18-41.0 0.46 1
Trichloroethene ND ug/L 07/01/17 18:40 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 07/01/17 18:40 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)98 %07/01/17 18:40 460-00-470-130 1
1,2-Dichloroethane-d4 (S)93 %07/01/17 18:40 17060-07-070-130 1
Toluene-d8 (S)104 %07/01/17 18:40 2037-26-570-130 1
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Sample: 1203-PZ-30S Lab ID: 92346145003 Collected: 06/28/17 08:15 Received: 06/28/17 12:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/02/17 13:51 74-82-810.0 10.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 07/01/17 18:58 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 07/01/17 18:58 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 07/01/17 18:58 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/01/17 18:58 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 07/01/17 18:58 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 07/01/17 18:58 127-18-41.0 0.46 1
Trichloroethene ND ug/L 07/01/17 18:58 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 07/01/17 18:58 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)94 %07/01/17 18:58 460-00-470-130 1
1,2-Dichloroethane-d4 (S)91 %07/01/17 18:58 17060-07-070-130 1
Toluene-d8 (S)105 %07/01/17 18:58 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Sample: 1203-PZ-31 Lab ID: 92346145004 Collected: 06/28/17 08:24 Received: 06/28/17 12:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/02/17 14:06 74-82-810.0 10.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 07/01/17 19:15 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 07/01/17 19:15 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 07/01/17 19:15 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/01/17 19:15 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 07/01/17 19:15 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 07/01/17 19:15 127-18-41.0 0.46 1
Trichloroethene ND ug/L 07/01/17 19:15 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 07/01/17 19:15 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)101 %07/01/17 19:15 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %07/01/17 19:15 17060-07-070-130 1
Toluene-d8 (S)104 %07/01/17 19:15 2037-26-570-130 1
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Page 9 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Sample: 1203-PZ-35 Lab ID: 92346145005 Collected: 06/28/17 11:13 Received: 06/28/17 12:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/02/17 15:07 74-82-810.0 10.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 07/01/17 19:33 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 07/01/17 19:33 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 07/01/17 19:33 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/01/17 19:33 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 07/01/17 19:33 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 07/01/17 19:33 127-18-41.0 0.46 1
Trichloroethene ND ug/L 07/01/17 19:33 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 07/01/17 19:33 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)95 %07/01/17 19:33 460-00-470-130 1
1,2-Dichloroethane-d4 (S)92 %07/01/17 19:33 17060-07-070-130 1
Toluene-d8 (S)104 %07/01/17 19:33 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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Page 10 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Sample: 1203-PZ-36 Lab ID: 92346145006 Collected: 06/28/17 10:23 Received: 06/28/17 12:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 45400 ug/L 07/03/17 11:08 74-82-8100 100 10
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene 5.3 ug/L 07/01/17 19:51 71-43-21.0 0.25 1
1,4-Dichlorobenzene 20.1 ug/L 07/01/17 19:51 106-46-71.0 0.33 1
1,1-Dichloroethane 4.3J ug/L 07/01/17 19:51 75-34-35.0 0.32 1
1,2-Dichloroethane 0.75J ug/L 07/01/17 19:51 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 07/01/17 19:51 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 07/01/17 19:51 127-18-41.0 0.46 1
Trichloroethene ND ug/L 07/01/17 19:51 79-01-61.0 0.47 1
Vinyl chloride 0.64J ug/L 07/01/17 19:51 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)97 %07/01/17 19:51 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %07/01/17 19:51 17060-07-070-130 1
Toluene-d8 (S)107 %07/01/17 19:51 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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Page 11 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Sample: 1203-MW-38 Lab ID: 92346145007 Collected: 06/28/17 10:53 Received: 06/28/17 12:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 35400 ug/L 07/03/17 11:24 74-82-8100 100 10
REPORT OF LABORATORY ANALYSIS
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Page 12 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367434
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples: 92346145001, 92346145002, 92346145003, 92346145004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2036913
Associated Lab Samples:92346145001, 92346145002, 92346145003, 92346145004
Matrix: Water
AnalyzedMDL
Methane ug/L ND 10.0 07/02/17 08:1510.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2036914LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 367396 93 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2036915MATRIX SPIKE SAMPLE:
MSSpike
Result
92345828035
Methane ug/L 13900 M139615 70-13013800
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92345865004
2036916SAMPLE DUPLICATE:
Methane ug/L 11.3 D6532019.4
REPORT OF LABORATORY ANALYSIS
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Page 13 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367435
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples: 92346145005, 92346145006, 92346145007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2036917
Associated Lab Samples:92346145005, 92346145006, 92346145007
Matrix: Water
AnalyzedMDL
Methane ug/L ND 10.0 07/02/17 14:5210.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2036918LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 360396 91 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2036919MATRIX SPIKE SAMPLE:
MSSpike
Result
92346100001
Methane ug/L 603396 108 70-130177
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92346100002
2036920SAMPLE DUPLICATE:
Methane ug/L 61.9 10 2068.6
REPORT OF LABORATORY ANALYSIS
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Page 14 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367395
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92346145001, 92346145002, 92346145003, 92346145004, 92346145005, 92346145006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2036776
Associated Lab Samples:92346145001, 92346145002, 92346145003, 92346145004, 92346145005, 92346145006
Matrix: Water
AnalyzedMDL
1,1-Dichloroethane ug/L ND 5.0 07/01/17 13:040.32
1,2-Dichloroethane ug/L ND 1.0 07/01/17 13:040.24
1,4-Dichlorobenzene ug/L ND 1.0 07/01/17 13:040.33
Benzene ug/L ND 1.0 07/01/17 13:040.25
Methylene Chloride ug/L ND 1.0 07/01/17 13:040.97
Tetrachloroethene ug/L ND 1.0 07/01/17 13:040.46
Trichloroethene ug/L ND 1.0 07/01/17 13:040.47
Vinyl chloride ug/L ND 1.0 07/01/17 13:040.62
1,2-Dichloroethane-d4 (S)%94 70-130 07/01/17 13:04
4-Bromofluorobenzene (S)%96 70-130 07/01/17 13:04
Toluene-d8 (S)%104 70-130 07/01/17 13:04
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2036777LABORATORY CONTROL SAMPLE:
LCSSpike
1,1-Dichloroethane ug/L 43.550 87 73-126
1,2-Dichloroethane ug/L 45.250 90 67-128
1,4-Dichlorobenzene ug/L 49.550 99 78-130
Benzene ug/L 47.850 96 80-125
Methylene Chloride ug/L 47.050 94 64-133
Tetrachloroethene ug/L 46.950 94 78-122
Trichloroethene ug/L 47.450 95 78-122
Vinyl chloride ug/L 41.150 82 58-137
1,2-Dichloroethane-d4 (S)%93 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%95 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2036779MATRIX SPIKE SAMPLE:
MSSpike
Result
92346168021
1,1-Dichloroethane ug/L 19.120 95 70-130ND
1,2-Dichloroethane ug/L 19.120 95 70-130ND
1,4-Dichlorobenzene ug/L 20.720 103 70-130ND
Benzene ug/L 20.320 101 70-148ND
Methylene Chloride ug/L 17.720 88 70-130ND
Tetrachloroethene ug/L 19.020 95 70-130ND
Trichloroethene ug/L 20.420 102 69-151ND
Vinyl chloride ug/L 18.620 93 70-130ND
REPORT OF LABORATORY ANALYSIS
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Page 15 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2036779MATRIX SPIKE SAMPLE:
MSSpike
Result
92346168021
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92346168020
2036778SAMPLE DUPLICATE:
1,1-Dichloroethane ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
Benzene ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%94 094
4-Bromofluorobenzene (S)%99 297
Toluene-d8 (S)%110 3106
REPORT OF LABORATORY ANALYSIS
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Page 16 of 37
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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Page 17 of 37
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92346145001 3674341203-MW-15S RSK 175 Modified
92346145002 3674341203-PZ-12 RSK 175 Modified
92346145003 3674341203-PZ-30S RSK 175 Modified
92346145004 3674341203-PZ-31 RSK 175 Modified
92346145005 3674351203-PZ-35 RSK 175 Modified
92346145006 3674351203-PZ-36 RSK 175 Modified
92346145007 3674351203-MW-38 RSK 175 Modified
92346145001 3673951203-MW-15S EPA 8260
92346145002 3673951203-PZ-12 EPA 8260
92346145003 3673951203-PZ-30S EPA 8260
92346145004 3673951203-PZ-31 EPA 8260
92346145005 3673951203-PZ-35 EPA 8260
92346145006 3673951203-PZ-36 EPA 8260
REPORT OF LABORATORY ANALYSIS
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Page 18 of 37
Page 19 of 37
Page 20 of 37
Page 21 of 37
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23145 - 942704 Page 1 of 14
Trey Carter
Pace Analytical Charlotte9800 Kincey Ave
Suite 100Huntersville, NC 28078
July 11, 2017
RE:
Pace Workorder:
JOHNS R.-ADD MW LFG / 92346145
Dear Trey Carter:
23145
Enclosed are the analytical results for sample(s) received by the laboratory on Friday, June 30, 2017. Results
reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated inthe body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Enclosures
Ruth Welsh 07/11/[e-mail]
Total Number of Pages ____
As a valued client we would appreciate your comments on our service.
Please email [e-mail].
Customer Service Representative
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Phone: [phone]
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without the written consent of Pace Analytical Energy Services LLC.
16
Page 22 of 37
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23145 - 942704 Page 2 of 14
LABORATORY ACCREDITATIONS & CERTIFICATIONS
Pennsylvania Department of Environmental Protection, Bureau of Laboratories
02-00538
NELAP Non-Potable Water and Solid & Hazardous Waste
Accreditor:
Accreditation ID:
Scope:
West Virginia Department of Environmental Protection, Division of Water and Waste
Management
395
Non-Potable Water
Accreditor:
Accreditation ID:
Scope:
South Carolina Department of Health and Environmental Control, Office of EnvironmentalLaboratory Certification
89009003
Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA)
Accreditor:
Accreditation ID:
Scope:
NELAP: New Jersey, Department of Environmental Protection
PA026
Non-Potable Water; Solid and Chemical Materials
Accreditor:
Accreditation ID:
Scope:
NELAP: New York, Department of Health Wadsworth Center
11815
Non-Potable Water; Solid and Hazardous Waste
Accreditor:
Accreditation ID:
Scope:
State of Connecticut, Department of Public Health, Division of Environmental Health
PH-0263
Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA)
Accreditor:
Accreditation ID:
Scope:
NELAP: Texas, Commission on Environmental Quality
T104704453-09-TX
Non-Potable Water
Accreditor:
Accreditation ID:
Scope:
State of New Hampshire
299409
Non-potable water
Accreditor:
Accreditation ID:
Scope:
State of Georgia
Chapter 391-3-26
As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES isaccredited by the Pennsylvania Department of Environmental Protection Bureau of
Laboratories under the National Environmental Laboratory Approval Program (NELAC).
Accreditor:
Accreditation ID:
Scope:
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Page 23 of 37
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Report ID: 23145 - 942704 Page 3 of 14
SAMPLE SUMMARY
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
Lab ID Sample ID Matrix Date Collected Date Received
231450001 1203-MW-15S Water 6/28/2017 08:45 6/30/2017 11:30
231450002 1203-PZ-12 Water 6/28/2017 09:45 6/30/2017 11:30
231450003 1203-PZ-30S Water 6/28/2017 08:15 6/30/2017 11:30
231450004 1203-PZ-31 Water 6/28/2017 08:24 6/30/2017 11:30
231450005 1203-PZ-35 Water 6/28/2017 11:13 6/30/2017 11:30
231450006 1203-PZ-36 Water 6/28/2017 10:23 6/30/2017 11:30
231450007 1203-MW-38 Water 6/28/2017 10:53 6/30/2017 11:30
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Report ID: 23145 - 942704 Page 4 of 14
ANALYTICAL RESULTS
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
6/30/2017 11:30
1203-MW-15S
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
231450001
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
6/28/2017 08:45
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Carbon Dioxide 250 mg/l 5.0 1 7/6/2017 09:28 BW n0.45
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Page 25 of 37
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Report ID: 23145 - 942704 Page 5 of 14
ANALYTICAL RESULTS
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
6/30/2017 11:30
1203-PZ-12
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
231450002
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
6/28/2017 09:45
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Carbon Dioxide 36 mg/l 5.0 1 7/6/2017 09:37 BW n0.45
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ANALYTICAL RESULTS
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
6/30/2017 11:30
1203-PZ-30S
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
231450003
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
6/28/2017 08:15
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Carbon Dioxide 23 mg/l 5.0 1 7/6/2017 09:49 BW n0.45
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ANALYTICAL RESULTS
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
6/30/2017 11:30
1203-PZ-31
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
231450004
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
6/28/2017 08:24
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Carbon Dioxide 14 mg/l 5.0 1 7/6/2017 10:02 BW n0.45
220 William Pitt Way
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Page 28 of 37
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Report ID: 23145 - 942704 Page 8 of 14
ANALYTICAL RESULTS
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
6/30/2017 11:30
1203-PZ-35
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
231450005
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
6/28/2017 11:13
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Carbon Dioxide 22 mg/l 5.0 1 7/6/2017 10:12 BW n0.45
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ANALYTICAL RESULTS
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
6/30/2017 11:30
1203-PZ-36
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
231450006
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
6/28/2017 10:23
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Carbon Dioxide 420 mg/l 5.0 1 7/6/2017 10:29 BW n0.45
220 William Pitt Way
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Report ID: 23145 - 942704 Page 10 of 14
ANALYTICAL RESULTS
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
6/30/2017 11:30
1203-MW-38
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
231450007
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
6/28/2017 10:53
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Carbon Dioxide 260 mg/l 5.0 1 7/6/2017 10:39 BW n0.45
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ANALYTICAL RESULTS QUALIFIERS
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
DEFINITIONS/QUALIFIERS
U
J
Indicates the compound was analyzed for, but not detected at or above the noted concentration.
Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL).
MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection.
PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation.
ND Not detected at or above reporting limit.
DF Dilution Factor.
S Surrogate.
RPD Relative Percent Difference.
% Rec Percent Recovery.
The laboratory does not hold NELAP/TNI accreditation for this method or analyte.n
220 William Pitt Way
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QUALITY CONTROL DATA
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
QC Batch:
QC Batch Method:
DISG/6206
AM20GAX
Analysis Method: AM20GAX
Associated Lab Samples:231450001, 231450002, 231450003, 231450004, 231450005, 231450006, 231450007
METHOD BLANK: 49706
Parameter Units Result
Blank
Limit
Reporting
Qualifiers
RISK
Carbon Dioxide 0.45Umg/l 0.45 n
LABORATORY CONTROL SAMPLE & LCSD:
Parameter Units Conc.
Spike
Result
LCS
49708 49710
LCSD
Result % Rec
LCS LCSD
% Rec
% Rec
Limit RPD RPD
Max
Qualifiers
RISK
Carbon Dioxide mg/l 120 120 99 80-120 n110972 20
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QUALITY CONTROL DATA QUALIFIERS
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QUALITY CONTROL PARAMETER QUALIFIERS
The laboratory does not hold NELAP/TNI accreditation for this method or analyte.n
220 William Pitt Way
Pittsburgh, PA 15238
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
Lab ID Sample ID Prep Method Analysis MethodPrep Batch Batch
Analysis
231450001 1203-MW-15S DISG/6206AM20GAX
231450002 1203-PZ-12 DISG/6206AM20GAX
231450003 1203-PZ-30S DISG/6206AM20GAX
231450004 1203-PZ-31 DISG/6206AM20GAX
231450005 1203-PZ-35 DISG/6206AM20GAX
231450006 1203-PZ-36 DISG/6206AM20GAX
231450007 1203-MW-38 DISG/6206AM20GAX
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Page 35 of 37
Page 36 of 37
Page 37 of 37
#=CL#
July 13, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92346176
92346176
Project:
Pace Project No.:
RE:
Mr. Van BurbachJoyce Engineering-Greensboro2211 West Meadowview RdBoone Bldg, Suite 101Greensboro, NC 27407
JOHNS R-SURFACE WATER
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on June 29, 2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager(704)875-9092
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 29
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 29
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Lab ID Sample ID Matrix Date Collected Date Received
92346176001 1203-SMP5 Water 06/28/17 11:45 06/29/17 10:10
92346176002 1203-SMP6 Water 06/28/17 12:00 06/29/17 10:10
92346176003 1203-SMP7 Water 06/28/17 09:40 06/29/17 10:10
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 3 of 29
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92346176001 1203-SMP5 EPA 8081 4 PASI-CSWB
EPA 6010 16 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AKAL
EPA 8260 53 PASI-CZDO
SM 4500-CN-E 1 PASI-AAES2
92346176002 1203-SMP6 EPA 8081 4 PASI-CSWB
EPA 6010 16 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AKAL
EPA 8260 53 PASI-CZDO
SM 4500-CN-E 1 PASI-AAES2
92346176003 1203-SMP7 EPA 8081 4 PASI-CSWB
EPA 6010 16 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AKAL
EPA 8260 53 PASI-CZDO
SM 4500-CN-E 1 PASI-AAES2
REPORT OF LABORATORY ANALYSIS
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Page 4 of 29
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92346176001 1203-SMP5
Barium 46.3J ug/L 07/13/17 08:20100EPA 6010
Cobalt 6.4J ug/L 07/13/17 08:2010.0EPA 6010
Hardness, Total (SM 2340B)32900 ug/L 07/13/17 08:20662EPA 6010
Zinc 5.8J ug/L 07/13/17 08:2010.0EPA 6010
Acetone 14.7J ug/L 07/06/17 19:03100EPA 8260
Chloromethane 0.46J ug/L 07/06/17 19:031.0EPA 8260
92346176002 1203-SMP6
Arsenic 5.5J ug/L 07/13/17 08:2310.0EPA 6010
Barium 41.4J ug/L 07/13/17 08:23100EPA 6010
Cobalt 3.6J ug/L 07/13/17 08:2310.0EPA 6010
Hardness, Total (SM 2340B)20900 ug/L 07/13/17 08:23662EPA 6010
Zinc 17.4 ug/L 07/13/17 08:2310.0EPA 6010
Acetone 29.4J ug/L 07/06/17 19:21100EPA 8260
Benzene 0.59J ug/L 07/06/17 19:211.0EPA 8260
Chloromethane 0.65J ug/L 07/06/17 19:211.0EPA 8260
1,1-Dichloroethane 4.2J ug/L 07/06/17 19:215.0EPA 8260
cis-1,2-Dichloroethene 1.1J ug/L 07/06/17 19:215.0EPA 8260
Trichloroethene 1.1 ug/L 07/06/17 19:211.0EPA 8260
92346176003 1203-SMP7
Barium 31.5J ug/L 07/13/17 08:26100EPA 6010
Nickel 8.0J ug/L 07/13/17 08:2650.0EPA 6010
Hardness, Total (SM 2340B)10800 ug/L 07/13/17 08:26662EPA 6010
Vanadium 3.1J ug/L 07/13/17 08:2625.0EPA 6010
Zinc 39.4 ug/L 07/13/17 08:2610.0EPA 6010
Thallium 0.044J ug/L 07/12/17 16:085.5EPA 6020B
Acetone 18.0J ug/L 07/06/17 19:38100EPA 8260
Chloromethane 0.50J ug/L 07/06/17 19:381.0EPA 8260
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 5 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Sample: 1203-SMP5 Lab ID: 92346176001 Collected: 06/28/17 11:45 Received: 06/29/17 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
alpha-BHC ND ug/L 07/06/17 03:20 319-84-607/04/17 09:000.050 0.050 1
beta-BHC ND ug/L 07/06/17 03:20 319-85-707/04/17 09:000.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)77 %07/06/17 03:20 877-09-807/04/17 09:0020-130 1
Decachlorobiphenyl (S)67 %07/06/17 03:20 2051-24-307/04/17 09:0020-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 07/13/17 08:20 7440-36-007/06/17 16:256.0 3.9 1
Arsenic ND ug/L 07/13/17 08:20 7440-38-207/06/17 16:2510.0 5.0 1
Barium 46.3J ug/L 07/13/17 08:20 7440-39-307/06/17 16:25100 2.5 1
Beryllium ND ug/L 07/13/17 08:20 7440-41-707/06/17 16:251.0 0.50 1
Cadmium ND ug/L 07/13/17 08:20 7440-43-907/06/17 16:251.0 0.50 1
Chromium ND ug/L 07/13/17 08:20 7440-47-307/06/17 16:2510.0 2.5 1
Cobalt 6.4J ug/L 07/13/17 08:20 7440-48-407/06/17 16:2510.0 2.5 1
Copper ND ug/L 07/13/17 08:20 7440-50-807/06/17 16:2510.0 2.5 1
Lead ND ug/L 07/13/17 08:20 7439-92-107/06/17 16:2510.0 2.5 1
Nickel ND ug/L 07/13/17 08:20 7440-02-007/06/17 16:2550.0 2.5 1
Selenium ND ug/L 07/13/17 08:20 7782-49-207/06/17 16:2510.0 5.0 1
Silver ND ug/L 07/13/17 08:20 7440-22-407/06/17 16:2510.0 2.5 1
Tin ND ug/L 07/13/17 08:20 7440-31-507/06/17 16:255.0 2.5 1
Hardness, Total (SM 2340B)32900 ug/L 07/13/17 08:2007/06/17 16:25662 662 1
Vanadium ND ug/L 07/13/17 08:20 7440-62-207/06/17 16:2525.0 2.5 1
Zinc 5.8J ug/L 07/13/17 08:20 7440-66-607/06/17 16:2510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 07/12/17 15:59 7440-28-007/01/17 06:405.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 07/06/17 06:11 7439-97-607/05/17 17:040.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 14.7J ug/L 07/06/17 19:03 67-64-1100 10.0 1
Acrylonitrile ND ug/L 07/06/17 19:03 107-13-1200 1.9 1
Benzene ND ug/L 07/06/17 19:03 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/06/17 19:03 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/06/17 19:03 75-27-41.0 0.18 1
Bromoform ND ug/L 07/06/17 19:03 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/06/17 19:03 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/06/17 19:03 78-93-3100 0.96 1
Carbon disulfide ND ug/L 07/06/17 19:03 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 07/06/17 19:03 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/06/17 19:03 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/06/17 19:03 75-00-310.0 0.54 1
Chloroform ND ug/L 07/06/17 19:03 67-66-35.0 0.14 1
Chloromethane 0.46J ug/L 07/06/17 19:03 74-87-31.0 0.11 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/13/2017 07:31 PM
Pace Analytical Services, LLC
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Page 6 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Sample: 1203-SMP5 Lab ID: 92346176001 Collected: 06/28/17 11:45 Received: 06/29/17 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dibromo-3-chloropropane ND ug/L 07/06/17 19:03 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/06/17 19:03 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/06/17 19:03 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/06/17 19:03 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/06/17 19:03 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/06/17 19:03 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/06/17 19:03 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 07/06/17 19:03 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 07/06/17 19:03 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/06/17 19:03 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/06/17 19:03 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/06/17 19:03 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/06/17 19:03 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/06/17 19:03 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/06/17 19:03 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/06/17 19:03 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 07/06/17 19:03 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/06/17 19:03 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/06/17 19:03 74-88-410.0 0.32 1
Isobutanol ND ug/L 07/06/17 19:03 78-83-1100 35.0 1
Methylene Chloride ND ug/L 07/06/17 19:03 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/06/17 19:03 108-10-1100 0.33 1
Styrene ND ug/L 07/06/17 19:03 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/06/17 19:03 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/06/17 19:03 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/06/17 19:03 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 07/06/17 19:03 109-99-910.0 3.1 1
Toluene ND ug/L 07/06/17 19:03 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/06/17 19:03 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/06/17 19:03 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/06/17 19:03 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/06/17 19:03 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/06/17 19:03 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/06/17 19:03 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/06/17 19:03 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/06/17 19:03 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %07/06/17 19:03 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %07/06/17 19:03 17060-07-070-130 1
Toluene-d8 (S)103 %07/06/17 19:03 2037-26-570-130 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 07/07/17 14:34 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/13/2017 07:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Sample: 1203-SMP6 Lab ID: 92346176002 Collected: 06/28/17 12:00 Received: 06/29/17 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
alpha-BHC ND ug/L 07/06/17 03:38 319-84-607/04/17 09:000.050 0.050 1
beta-BHC ND ug/L 07/06/17 03:38 319-85-707/04/17 09:000.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)72 %07/06/17 03:38 877-09-807/04/17 09:0020-130 1
Decachlorobiphenyl (S)69 %07/06/17 03:38 2051-24-307/04/17 09:0020-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 07/13/17 08:23 7440-36-007/06/17 16:256.0 3.9 1
Arsenic 5.5J ug/L 07/13/17 08:23 7440-38-207/06/17 16:2510.0 5.0 1
Barium 41.4J ug/L 07/13/17 08:23 7440-39-307/06/17 16:25100 2.5 1
Beryllium ND ug/L 07/13/17 08:23 7440-41-707/06/17 16:251.0 0.50 1
Cadmium ND ug/L 07/13/17 08:23 7440-43-907/06/17 16:251.0 0.50 1
Chromium ND ug/L 07/13/17 08:23 7440-47-307/06/17 16:2510.0 2.5 1
Cobalt 3.6J ug/L 07/13/17 08:23 7440-48-407/06/17 16:2510.0 2.5 1
Copper ND ug/L 07/13/17 08:23 7440-50-807/06/17 16:2510.0 2.5 1
Lead ND ug/L 07/13/17 08:23 7439-92-107/06/17 16:2510.0 2.5 1
Nickel ND ug/L 07/13/17 08:23 7440-02-007/06/17 16:2550.0 2.5 1
Selenium ND ug/L 07/13/17 08:23 7782-49-207/06/17 16:2510.0 5.0 1
Silver ND ug/L 07/13/17 08:23 7440-22-407/06/17 16:2510.0 2.5 1
Tin ND ug/L 07/13/17 08:23 7440-31-507/06/17 16:255.0 2.5 1
Hardness, Total (SM 2340B)20900 ug/L 07/13/17 08:2307/06/17 16:25662 662 1
Vanadium ND ug/L 07/13/17 08:23 7440-62-207/06/17 16:2525.0 2.5 1
Zinc 17.4 ug/L 07/13/17 08:23 7440-66-607/06/17 16:2510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 07/12/17 16:01 7440-28-007/01/17 06:405.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 07/06/17 06:14 7439-97-607/05/17 17:040.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 29.4J ug/L 07/06/17 19:21 67-64-1100 10.0 1
Acrylonitrile ND ug/L 07/06/17 19:21 107-13-1200 1.9 1
Benzene 0.59J ug/L 07/06/17 19:21 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/06/17 19:21 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/06/17 19:21 75-27-41.0 0.18 1
Bromoform ND ug/L 07/06/17 19:21 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/06/17 19:21 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/06/17 19:21 78-93-3100 0.96 1
Carbon disulfide ND ug/L 07/06/17 19:21 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 07/06/17 19:21 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/06/17 19:21 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/06/17 19:21 75-00-310.0 0.54 1
Chloroform ND ug/L 07/06/17 19:21 67-66-35.0 0.14 1
Chloromethane 0.65J ug/L 07/06/17 19:21 74-87-31.0 0.11 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/13/2017 07:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Sample: 1203-SMP6 Lab ID: 92346176002 Collected: 06/28/17 12:00 Received: 06/29/17 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dibromo-3-chloropropane ND ug/L 07/06/17 19:21 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/06/17 19:21 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/06/17 19:21 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/06/17 19:21 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/06/17 19:21 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/06/17 19:21 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/06/17 19:21 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 07/06/17 19:21 75-71-85.0 0.21 1
1,1-Dichloroethane 4.2J ug/L 07/06/17 19:21 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/06/17 19:21 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/06/17 19:21 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 1.1J ug/L 07/06/17 19:21 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/06/17 19:21 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/06/17 19:21 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/06/17 19:21 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/06/17 19:21 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 07/06/17 19:21 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/06/17 19:21 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/06/17 19:21 74-88-410.0 0.32 1
Isobutanol ND ug/L 07/06/17 19:21 78-83-1100 35.0 1
Methylene Chloride ND ug/L 07/06/17 19:21 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/06/17 19:21 108-10-1100 0.33 1
Styrene ND ug/L 07/06/17 19:21 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/06/17 19:21 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/06/17 19:21 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/06/17 19:21 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 07/06/17 19:21 109-99-910.0 3.1 1
Toluene ND ug/L 07/06/17 19:21 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/06/17 19:21 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/06/17 19:21 79-00-51.0 0.29 1
Trichloroethene 1.1 ug/L 07/06/17 19:21 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/06/17 19:21 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/06/17 19:21 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/06/17 19:21 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/06/17 19:21 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/06/17 19:21 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %07/06/17 19:21 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %07/06/17 19:21 17060-07-070-130 1
Toluene-d8 (S)102 %07/06/17 19:21 2037-26-570-130 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 07/07/17 14:35 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/13/2017 07:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Sample: 1203-SMP7 Lab ID: 92346176003 Collected: 06/28/17 09:40 Received: 06/29/17 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
alpha-BHC ND ug/L 07/06/17 03:55 319-84-607/04/17 09:000.050 0.050 1
beta-BHC ND ug/L 07/06/17 03:55 319-85-707/04/17 09:000.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)45 %07/06/17 03:55 877-09-807/04/17 09:0020-130 1
Decachlorobiphenyl (S)38 %07/06/17 03:55 2051-24-307/04/17 09:0020-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 07/13/17 08:26 7440-36-007/06/17 16:256.0 3.9 1
Arsenic ND ug/L 07/13/17 08:26 7440-38-207/06/17 16:2510.0 5.0 1
Barium 31.5J ug/L 07/13/17 08:26 7440-39-307/06/17 16:25100 2.5 1
Beryllium ND ug/L 07/13/17 08:26 7440-41-707/06/17 16:251.0 0.50 1
Cadmium ND ug/L 07/13/17 08:26 7440-43-907/06/17 16:251.0 0.50 1
Chromium ND ug/L 07/13/17 08:26 7440-47-307/06/17 16:2510.0 2.5 1
Cobalt ND ug/L 07/13/17 08:26 7440-48-407/06/17 16:2510.0 2.5 1
Copper ND ug/L 07/13/17 08:26 7440-50-807/06/17 16:2510.0 2.5 1
Lead ND ug/L 07/13/17 08:26 7439-92-107/06/17 16:2510.0 2.5 1
Nickel 8.0J ug/L 07/13/17 08:26 7440-02-007/06/17 16:2550.0 2.5 1
Selenium ND ug/L 07/13/17 08:26 7782-49-207/06/17 16:2510.0 5.0 1
Silver ND ug/L 07/13/17 08:26 7440-22-407/06/17 16:2510.0 2.5 1
Tin ND ug/L 07/13/17 08:26 7440-31-507/06/17 16:255.0 2.5 1
Hardness, Total (SM 2340B)10800 ug/L 07/13/17 08:2607/06/17 16:25662 662 1
Vanadium 3.1J ug/L 07/13/17 08:26 7440-62-207/06/17 16:2525.0 2.5 1
Zinc 39.4 ug/L 07/13/17 08:26 7440-66-607/06/17 16:2510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium 0.044J ug/L 07/12/17 16:08 7440-28-007/01/17 06:405.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 07/11/17 07:23 7439-97-607/07/17 12:290.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 18.0J ug/L 07/06/17 19:38 67-64-1100 10.0 1
Acrylonitrile ND ug/L 07/06/17 19:38 107-13-1200 1.9 1
Benzene ND ug/L 07/06/17 19:38 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/06/17 19:38 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/06/17 19:38 75-27-41.0 0.18 1
Bromoform ND ug/L 07/06/17 19:38 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/06/17 19:38 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/06/17 19:38 78-93-3100 0.96 1
Carbon disulfide ND ug/L 07/06/17 19:38 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 07/06/17 19:38 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/06/17 19:38 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/06/17 19:38 75-00-310.0 0.54 1
Chloroform ND ug/L 07/06/17 19:38 67-66-35.0 0.14 1
Chloromethane 0.50J ug/L 07/06/17 19:38 74-87-31.0 0.11 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/13/2017 07:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Sample: 1203-SMP7 Lab ID: 92346176003 Collected: 06/28/17 09:40 Received: 06/29/17 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dibromo-3-chloropropane ND ug/L 07/06/17 19:38 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/06/17 19:38 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/06/17 19:38 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/06/17 19:38 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/06/17 19:38 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/06/17 19:38 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/06/17 19:38 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 07/06/17 19:38 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 07/06/17 19:38 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/06/17 19:38 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/06/17 19:38 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/06/17 19:38 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/06/17 19:38 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/06/17 19:38 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/06/17 19:38 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/06/17 19:38 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 07/06/17 19:38 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/06/17 19:38 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/06/17 19:38 74-88-410.0 0.32 1
Isobutanol ND ug/L 07/06/17 19:38 78-83-1100 35.0 1
Methylene Chloride ND ug/L 07/06/17 19:38 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/06/17 19:38 108-10-1100 0.33 1
Styrene ND ug/L 07/06/17 19:38 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/06/17 19:38 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/06/17 19:38 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/06/17 19:38 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 07/06/17 19:38 109-99-910.0 3.1 1
Toluene ND ug/L 07/06/17 19:38 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/06/17 19:38 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/06/17 19:38 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/06/17 19:38 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/06/17 19:38 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/06/17 19:38 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/06/17 19:38 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/06/17 19:38 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/06/17 19:38 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %07/06/17 19:38 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %07/06/17 19:38 17060-07-070-130 1
Toluene-d8 (S)104 %07/06/17 19:38 2037-26-570-130 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 07/07/17 14:36 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/13/2017 07:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367472
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92346176001, 92346176002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037042
Associated Lab Samples:92346176001, 92346176002
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 07/06/17 05:120.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037043LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.12.5 85 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037044MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346004021
2037045
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 94 75-125100 6 252.5ND 2.4 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/13/2017 07:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367794
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92346176003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2038382
Associated Lab Samples:92346176003
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 07/11/17 06:520.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2038383LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2038384MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346179002
2038385
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 100 75-12599 1 252.5ND 2.5 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/13/2017 07:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367844
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples: 92346176001, 92346176002, 92346176003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2038628
Associated Lab Samples:92346176001, 92346176002, 92346176003
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 6.0 07/13/17 07:123.9
Arsenic ug/L ND 10.0 07/13/17 07:125.0
Barium ug/L ND 100 07/13/17 07:122.5
Beryllium ug/L ND 1.0 07/13/17 07:120.50
Cadmium ug/L ND 1.0 07/13/17 07:120.50
Chromium ug/L ND 10.0 07/13/17 07:122.5
Cobalt ug/L ND 10.0 07/13/17 07:122.5
Copper ug/L ND 10.0 07/13/17 07:122.5
Hardness, Total (SM 2340B)ug/L ND 662 07/13/17 07:12662
Lead ug/L ND 10.0 07/13/17 07:122.5
Nickel ug/L ND 50.0 07/13/17 07:122.5
Selenium ug/L ND 10.0 07/13/17 07:125.0
Silver ug/L ND 10.0 07/13/17 07:122.5
Tin ug/L ND 5.0 07/13/17 07:122.5
Vanadium ug/L ND 25.0 07/13/17 07:122.5
Zinc ug/L ND 10.0 07/13/17 07:125.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2038629LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 537500 107 80-120
Arsenic ug/L 525500 105 80-120
Barium ug/L 567500 113 80-120
Beryllium ug/L 541500 108 80-120
Cadmium ug/L 569500 114 80-120
Chromium ug/L 549500 110 80-120
Cobalt ug/L 557500 111 80-120
Copper ug/L 548500 110 80-120
Hardness, Total (SM 2340B)ug/L 35400
Lead ug/L 550500 110 80-120
Nickel ug/L 523500 105 80-120
Selenium ug/L 560500 112 80-120
Silver ug/L 269250 108 80-120
Tin ug/L 542500 108 80-120
Vanadium ug/L 540500 108 80-120
Zinc ug/L 558500 112 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/13/2017 07:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2038630MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346168018
2038631
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 105 75-125103 2 20500ND527 516
Arsenic ug/L 500 103 75-125101 1 20500ND515 508
Barium ug/L 500 109 75-125109 0 2050017.1J 564 564
Beryllium ug/L 500 104 75-125104 0 20500ND522 521
Cadmium ug/L 500 111 75-125109 2 20500ND556 547
Chromium ug/L 500 108 75-125106 2 20500ND540 531
Cobalt ug/L 500 109 75-125107 1 20500ND546 538
Copper ug/L 500 108 75-125106 2 20500ND541 532
Hardness, Total (SM 2340B) ug/L 1630040400 40000
Lead ug/L 500 107 75-125105 2 20500ND535 527
Nickel ug/L 500 102 75-125100 2 205004.0J 514 506
Selenium ug/L 500 110 75-125107 3 20500ND548 533
Silver ug/L 250 105 75-125103 2 20250ND262 257
Tin ug/L 500 106 75-125105 1 20500ND531 523
Vanadium ug/L 500 106 75-125103 2 20500ND529 517
Zinc ug/L 500 108 75-125107 1 2050011.9 553 548
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/13/2017 07:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367204
EPA 3010A
EPA 6020B
6020 MET
Associated Lab Samples: 92346176001, 92346176002, 92346176003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2035552
Associated Lab Samples:92346176001, 92346176002, 92346176003
Matrix: Water
AnalyzedMDL
Thallium ug/L ND 5.5 07/12/17 13:460.020
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2035553LABORATORY CONTROL SAMPLE:
LCSSpike
Thallium ug/L 98.0100 98 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2035554MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346168021
2035555
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Thallium ug/L 100 94 75-12590 4 201000.046J 94.5 90.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/13/2017 07:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367961
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92346176001, 92346176002, 92346176003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2039240
Associated Lab Samples:92346176001, 92346176002, 92346176003
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 07/06/17 15:170.33
1,1,1-Trichloroethane ug/L ND 1.0 07/06/17 15:170.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 07/06/17 15:170.40
1,1,2-Trichloroethane ug/L ND 1.0 07/06/17 15:170.29
1,1-Dichloroethane ug/L ND 5.0 07/06/17 15:170.32
1,1-Dichloroethene ug/L ND 5.0 07/06/17 15:170.56
1,2,3-Trichloropropane ug/L ND 1.0 07/06/17 15:170.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 07/06/17 15:172.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 07/06/17 15:170.27
1,2-Dichlorobenzene ug/L ND 5.0 07/06/17 15:170.30
1,2-Dichloroethane ug/L ND 1.0 07/06/17 15:170.24
1,2-Dichloropropane ug/L ND 1.0 07/06/17 15:170.27
1,4-Dichlorobenzene ug/L ND 1.0 07/06/17 15:170.33
2-Butanone (MEK)ug/L ND 100 07/06/17 15:170.96
2-Hexanone ug/L ND 50.0 07/06/17 15:170.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 07/06/17 15:170.33
Acetone ug/L ND 100 07/06/17 15:1710.0
Acrylonitrile ug/L ND 200 07/06/17 15:171.9
Benzene ug/L ND 1.0 07/06/17 15:170.25
Bromochloromethane ug/L ND 3.0 07/06/17 15:170.17
Bromodichloromethane ug/L ND 1.0 07/06/17 15:170.18
Bromoform ug/L ND 3.0 07/06/17 15:170.26
Bromomethane ug/L ND 10.0 07/06/17 15:170.29
Carbon disulfide ug/L ND 100 07/06/17 15:171.2
Carbon tetrachloride ug/L ND 1.0 07/06/17 15:170.25
Chlorobenzene ug/L ND 3.0 07/06/17 15:170.23
Chloroethane ug/L ND 10.0 07/06/17 15:170.54
Chloroform ug/L ND 5.0 07/06/17 15:170.14
Chloromethane ug/L ND 1.0 07/06/17 15:170.11
cis-1,2-Dichloroethene ug/L ND 5.0 07/06/17 15:170.19
cis-1,3-Dichloropropene ug/L ND 1.0 07/06/17 15:170.13
Dibromochloromethane ug/L ND 3.0 07/06/17 15:170.21
Dibromomethane ug/L ND 10.0 07/06/17 15:170.21
Dichlorodifluoromethane ug/L ND 5.0 07/06/17 15:170.21
Ethylbenzene ug/L ND 1.0 07/06/17 15:170.30
Iodomethane ug/L ND 10.0 07/06/17 15:170.32
Isobutanol ug/L ND 100 07/06/17 15:1735.0
Methylene Chloride ug/L ND 1.0 07/06/17 15:170.97
Styrene ug/L ND 1.0 07/06/17 15:170.26
Tetrachloroethene ug/L ND 1.0 07/06/17 15:170.46
Tetrahydrofuran ug/L ND 10.0 07/06/17 15:173.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/13/2017 07:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2039240
Associated Lab Samples:92346176001, 92346176002, 92346176003
Matrix: Water
AnalyzedMDL
Toluene ug/L ND 1.0 07/06/17 15:170.26
trans-1,2-Dichloroethene ug/L ND 5.0 07/06/17 15:170.49
trans-1,3-Dichloropropene ug/L ND 1.0 07/06/17 15:170.26
trans-1,4-Dichloro-2-butene ug/L ND 100 07/06/17 15:171.0
Trichloroethene ug/L ND 1.0 07/06/17 15:170.47
Trichlorofluoromethane ug/L ND 1.0 07/06/17 15:170.20
Vinyl acetate ug/L ND 50.0 07/06/17 15:170.35
Vinyl chloride ug/L ND 1.0 07/06/17 15:170.62
Xylene (Total)ug/L ND 5.0 07/06/17 15:170.66
1,2-Dichloroethane-d4 (S)%93 70-130 07/06/17 15:17
4-Bromofluorobenzene (S)%98 70-130 07/06/17 15:17
Toluene-d8 (S)%102 70-130 07/06/17 15:17
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2039241LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 56.750 113 80-125
1,1,1-Trichloroethane ug/L 55.950 112 71-129
1,1,2,2-Tetrachloroethane ug/L 55.050 110 79-124
1,1,2-Trichloroethane ug/L 58.150 116 85-125
1,1-Dichloroethane ug/L 52.650 105 73-126
1,1-Dichloroethene ug/L 55.250 110 66-135
1,2,3-Trichloropropane ug/L 53.350 107 75-130
1,2-Dibromo-3-chloropropane ug/L 53.250 106 71-133
1,2-Dibromoethane (EDB)ug/L 59.550 119 83-124
1,2-Dichlorobenzene ug/L 56.850 114 80-133
1,2-Dichloroethane ug/L 50.150 100 67-128
1,2-Dichloropropane ug/L 58.450 117 75-132
1,4-Dichlorobenzene ug/L 56.750 113 78-130
2-Butanone (MEK)ug/L 121100 121 61-144
2-Hexanone ug/L 111100 111 68-143
4-Methyl-2-pentanone (MIBK)ug/L 109100 109 72-135
Acetone ug/L 128100 128 48-146
Acrylonitrile ug/L 271250 109 40-160
Benzene ug/L 59.750 119 80-125
Bromochloromethane ug/L 58.150 116 71-125
Bromodichloromethane ug/L 56.750 113 78-124
Bromoform ug/L 57.650 115 71-128
Bromomethane ug/L 43.750 87 40-160
Carbon disulfide ug/L 58.4J50 117 50-160
Carbon tetrachloride ug/L 55.650 111 69-131
Chlorobenzene ug/L 55.550 111 81-122
Chloroethane ug/L 42.550 85 39-148
Chloroform ug/L 55.150 110 73-127
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/13/2017 07:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2039241LABORATORY CONTROL SAMPLE:
LCSSpike
Chloromethane ug/L 51.450 103 44-146
cis-1,2-Dichloroethene ug/L 54.950 110 74-124
cis-1,3-Dichloropropene ug/L 59.550 119 72-132
Dibromochloromethane ug/L 60.450 121 78-125
Dibromomethane ug/L 56.250 112 82-120
Dichlorodifluoromethane ug/L 40.250 80 34-157
Ethylbenzene ug/L 55.650 111 79-121
Iodomethane ug/L 97.2100 97 39-154
Isobutanol ug/L 10901000 109 34-160
Methylene Chloride ug/L 57.150 114 64-133
Styrene ug/L 56.450 113 84-126
Tetrachloroethene ug/L 54.350 109 78-122
Tetrahydrofuran ug/L 566500 113 69-148
Toluene ug/L 55.650 111 80-121
trans-1,2-Dichloroethene ug/L 53.650 107 71-127
trans-1,3-Dichloropropene ug/L 61.050 122 69-141
trans-1,4-Dichloro-2-butene ug/L 75.3J50 151 40-160
Trichloroethene ug/L 54.150 108 78-122
Trichlorofluoromethane ug/L 48.950 98 53-137
Vinyl acetate ug/L 115100 115 40-160
Vinyl chloride ug/L 48.350 97 58-137
Xylene (Total)ug/L 164150 109 81-126
1,2-Dichloroethane-d4 (S)%90 70-130
4-Bromofluorobenzene (S)%96 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2039244MATRIX SPIKE SAMPLE:
MSSpike
Result
92346168001
1,1,1,2-Tetrachloroethane ug/L 18.220 91 70-130ND
1,1,1-Trichloroethane ug/L 19.420 97 70-130ND
1,1,2,2-Tetrachloroethane ug/L 19.320 97 70-130ND
1,1,2-Trichloroethane ug/L 20.320 101 70-130ND
1,1-Dichloroethane ug/L 18.620 93 70-130ND
1,1-Dichloroethene ug/L 19.820 99 70-166ND
1,2,3-Trichloropropane ug/L 19.120 96 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.520 98 70-130ND
1,2-Dibromoethane (EDB)ug/L 19.720 99 70-130ND
1,2-Dichlorobenzene ug/L 18.720 94 70-130ND
1,2-Dichloroethane ug/L 16.720 83 70-130ND
1,2-Dichloropropane ug/L 19.520 98 70-130ND
1,4-Dichlorobenzene ug/L 21.820 93 70-1303.2
2-Butanone (MEK)ug/L 38.7J40 97 70-130ND
2-Hexanone ug/L 36.3J40 91 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 36.3J40 91 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/13/2017 07:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2039244MATRIX SPIKE SAMPLE:
MSSpike
Result
92346168001
Acetone ug/L 70.1J40 115 70-13024.0J
Acrylonitrile ug/L 98.0J100 98 70-130ND
Benzene ug/L 21.420 103 70-1480.92J
Bromochloromethane ug/L 20.620 103 70-130ND
Bromodichloromethane ug/L 19.820 99 70-130ND
Bromoform ug/L 18.320 91 70-130ND
Bromomethane ug/L 15.520 78 70-130ND
Carbon disulfide ug/L 21.4J20 107 70-130ND
Carbon tetrachloride ug/L 20.120 101 70-130ND
Chlorobenzene ug/L 20.120 100 70-146ND
Chloroethane ug/L 16.620 83 70-130ND
Chloroform ug/L 19.820 99 70-130ND
Chloromethane ug/L 18.220 87 70-1300.94J
cis-1,2-Dichloroethene ug/L 20.320 95 70-1301.2J
cis-1,3-Dichloropropene ug/L 18.420 92 70-130ND
Dibromochloromethane ug/L 18.920 95 70-130ND
Dibromomethane ug/L 21.520 107 70-130ND
Dichlorodifluoromethane ug/L 15.620 78 70-130ND
Ethylbenzene ug/L 20.420 102 70-130ND
Iodomethane ug/L 31.840 80 70-130ND
Isobutanol ug/L 350400 88 70-130ND
Methylene Chloride ug/L 18.220 91 70-130ND
Styrene ug/L 20.020 100 70-130ND
Tetrachloroethene ug/L 20.620 103 70-130ND
Tetrahydrofuran ug/L 198200 99 70-130ND
Toluene ug/L 20.220 101 70-155ND
trans-1,2-Dichloroethene ug/L 20.620 103 70-130ND
trans-1,3-Dichloropropene ug/L 18.220 91 70-130ND
trans-1,4-Dichloro-2-butene ug/L 17.9J20 90 70-130ND
Trichloroethene ug/L 19.620 98 69-151ND
Trichlorofluoromethane ug/L 18.920 95 70-130ND
Vinyl acetate ug/L 29.6J40 74 70-130ND
Vinyl chloride ug/L 18.520 93 70-130ND
1,2-Dichloroethane-d4 (S)%89 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92346206002
2039243SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/13/2017 07:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92346206002
2039243SAMPLE DUPLICATE:
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L 2.8J 302.1J
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L 1.3J 301.3J
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Isobutanol ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L 779 1 30774
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%97 494
4-Bromofluorobenzene (S)%97 097
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/13/2017 07:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92346206002
2039243SAMPLE DUPLICATE:
Toluene-d8 (S)%101 1102
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/13/2017 07:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367699
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples: 92346176001, 92346176002, 92346176003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037927
Associated Lab Samples:92346176001, 92346176002, 92346176003
Matrix: Water
AnalyzedMDL
alpha-BHC ug/L ND 0.050 07/06/17 05:070.050
beta-BHC ug/L ND 0.050 07/06/17 05:070.050
Decachlorobiphenyl (S)%62 20-130 07/06/17 05:07
Tetrachloro-m-xylene (S)%77 20-130 07/06/17 05:07
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037928LABORATORY CONTROL SAMPLE:
LCSSpike
alpha-BHC ug/L 0.21.25 85 20-150
beta-BHC ug/L 0.19.25 77 20-150
Decachlorobiphenyl (S)%84 20-130
Tetrachloro-m-xylene (S)%79 20-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92346139002
2037930SAMPLE DUPLICATE:
alpha-BHC ug/L ND 30ND
beta-BHC ug/L ND 30ND
Decachlorobiphenyl (S)%47 2436
Tetrachloro-m-xylene (S)%69 3250
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Page 23 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367927
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples: 92346176001, 92346176002, 92346176003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2039017
Associated Lab Samples:92346176001, 92346176002, 92346176003
Matrix: Water
AnalyzedMDL
Cyanide ug/L ND 10.0 07/07/17 14:154.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2039018LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 105100 105 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2039019MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346394001
2039020
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L M11003880-12038 0 101000.026mg/L 64.2 64.0
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2039021MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346139002
2039022
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 91 80-12090 1 10100ND93.8 92.6
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
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Page 25 of 29
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92346176
JOHNS R-SURFACE WATER
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92346176001 367699 3677621203-SMP5 EPA 3510 EPA 8081
92346176002 367699 3677621203-SMP6 EPA 3510 EPA 8081
92346176003 367699 3677621203-SMP7 EPA 3510 EPA 8081
92346176001 367844 3684931203-SMP5 EPA 3010A EPA 6010
92346176002 367844 3684931203-SMP6 EPA 3010A EPA 6010
92346176003 367844 3684931203-SMP7 EPA 3010A EPA 6010
92346176001 367204 3677841203-SMP5 EPA 3010A EPA 6020B
92346176002 367204 3677841203-SMP6 EPA 3010A EPA 6020B
92346176003 367204 3677841203-SMP7 EPA 3010A EPA 6020B
92346176001 367472 3678541203-SMP5 EPA 7470 EPA 7470
92346176002 367472 3678541203-SMP6 EPA 7470 EPA 7470
92346176003 367794 3683251203-SMP7 EPA 7470 EPA 7470
92346176001 3679611203-SMP5 EPA 8260
92346176002 3679611203-SMP6 EPA 8260
92346176003 3679611203-SMP7 EPA 8260
92346176001 3679271203-SMP5 SM 4500-CN-E
92346176002 3679271203-SMP6 SM 4500-CN-E
92346176003 3679271203-SMP7 SM 4500-CN-E
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Page 27 of 29
Page 28 of 29
Page 29 of 29
#=CL#
August 22, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92350924
92350924
Project:
Pace Project No.:
RE:
Mr. Van BurbachJoyce Engineering-Greensboro2211 West Meadowview RdBoone Bldg, Suite 101Greensboro, NC 27407
BURKE CO JOHNS RIVER RESAMPLE
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 09, 2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager(704)875-9092
Enclosures
cc: Gretta Eller, Joyce Engineering
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Page 1 of 15
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Lab ID Sample ID Matrix Date Collected Date Received
92350924001 TRIP BLANK Water 08/08/17 08:00 08/09/17 10:17
92350924002 MW-38 Water 08/08/17 12:02 08/09/17 10:17
92350924003 FIELD BLANK Water 08/08/17 12:15 08/09/17 10:17
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92350924001 TRIP BLANK EPA 8260 4 PASI-CZDO
92350924002 MW-38 EPA 8260 4 PASI-CZDO
92350924003 FIELD BLANK EPA 8260 4 PASI-CZDO
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#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92350924002 MW-38
Vinyl chloride 0.87J ug/L 08/12/17 15:531.0EPA 8260
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Sample: TRIP BLANK Lab ID: 92350924001 Collected: 08/08/17 08:00 Received: 08/09/17 10:17 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Vinyl chloride ND ug/L 08/12/17 15:35 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)104 %08/12/17 15:35 460-00-470-130 1
1,2-Dichloroethane-d4 (S)115 %08/12/17 15:35 17060-07-070-130 1
Toluene-d8 (S)109 %08/12/17 15:35 2037-26-570-130 1
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Sample: MW-38 Lab ID: 92350924002 Collected: 08/08/17 12:02 Received: 08/09/17 10:17 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Vinyl chloride 0.87J ug/L 08/12/17 15:53 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)103 %08/12/17 15:53 460-00-470-130 1
1,2-Dichloroethane-d4 (S)122 %08/12/17 15:53 17060-07-070-130 1
Toluene-d8 (S)110 %08/12/17 15:53 2037-26-570-130 1
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Sample: FIELD BLANK Lab ID: 92350924003 Collected: 08/08/17 12:15 Received: 08/09/17 10:17 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Vinyl chloride ND ug/L 08/22/17 02:59 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)98 %08/22/17 02:59 460-00-470-130 1
1,2-Dichloroethane-d4 (S)106 %08/22/17 02:59 17060-07-070-130 1
Toluene-d8 (S)107 %08/22/17 02:59 2037-26-570-130 1
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Page 8 of 15
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
373046
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92350924001, 92350924002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2067164
Associated Lab Samples:92350924001, 92350924002
Matrix: Water
AnalyzedMDL
Vinyl chloride ug/L ND 1.0 08/12/17 11:150.62
1,2-Dichloroethane-d4 (S)%117 70-130 08/12/17 11:15
4-Bromofluorobenzene (S)%105 70-130 08/12/17 11:15
Toluene-d8 (S)%112 70-130 08/12/17 11:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2067165LABORATORY CONTROL SAMPLE:
LCSSpike
Vinyl chloride ug/L 52.150 104 58-137
1,2-Dichloroethane-d4 (S)%110 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2068023MATRIX SPIKE SAMPLE:
MSSpike
Result
92350896003
Vinyl chloride ug/L 23.020 115 70-130ND
1,2-Dichloroethane-d4 (S)%105 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92350896002
2067345SAMPLE DUPLICATE:
Vinyl chloride ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%116 2118
4-Bromofluorobenzene (S)%103 3101
Toluene-d8 (S)%109 2110
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Page 9 of 15
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
374353
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92350924003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2074072
Associated Lab Samples:92350924003
Matrix: Water
AnalyzedMDL
Vinyl chloride ug/L ND 1.0 08/22/17 01:500.62
1,2-Dichloroethane-d4 (S)%105 70-130 08/22/17 01:50
4-Bromofluorobenzene (S)%96 70-130 08/22/17 01:50
Toluene-d8 (S)%106 70-130 08/22/17 01:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2074073LABORATORY CONTROL SAMPLE:
LCSSpike
Vinyl chloride ug/L 40.350 81 58-137
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2074074MATRIX SPIKE SAMPLE:
MSSpike
Result
92351475001
Vinyl chloride ug/L 22.620 109 70-1300.83J
1,2-Dichloroethane-d4 (S)%104 70-130
4-Bromofluorobenzene (S)%96 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92351475002
2074075SAMPLE DUPLICATE:
Vinyl chloride ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%106 4102
4-Bromofluorobenzene (S)%100 199
Toluene-d8 (S)%110 1109
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Page 10 of 15
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
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Page 11 of 15
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92350924001 373046TRIP BLANK EPA 8260
92350924002 373046MW-38 EPA 8260
92350924003 374353FIELD BLANK EPA 8260
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Page 12 of 15
Page 13 of 15
Page 14 of 15
Page 15 of 15

Appendix C

Historical Detected Groundwater Constituents

APPENDIX C:
HISTORICAL DETECTED GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL QL MW-21 MW-20 MW-22S MW-38 Blanks
INORGANICS
Alkalinity, Total as CaCO3 10-Apr-14 1,000 5,000 1,560 J --- 5,510 208,000 ND
NC 2L = NE (01/01/10) 6-May-14 1,000 5,000 1,170 J --- 4,060 J 209,000 ND
20-Jun-14 1,000 5,000 2,020 J --- 4,060 J 262,000 ND
17-Jul-14 1,000 5,000 1,990 J --- 3,960 J 197,000 ND
23-Oct-14 1,000 5,000 1,360 J 7,980 4,340 J 232,000 ND
21-May-15 1,000 5,000 ND 6,540 3,630 J 206,000 ---
8-Dec-15 1,000 5,000 1,030 J 8,280 6,670 234,000 ---
4-May-16 1,000 5,000 1,250 J 5,640 4,190 J 239,000 ---
13-Dec-16 1,000 5,000 1,190 J 6,190 4,100 J 294,000 ---
27-Jun-17 1,000 5,000 ND 6,110 5,060 315,000 ---
Arsenic 8-Dec-15 2.5 10 ND ND 12.7 4.9 J ND
NC 2L = 10 µg/l (01/01/10)4-Feb-16 2.5 10 ------5.8 J ---ND
4-May-16 2.5 10 ND ND ND ND ND
13-Dec-16 2.5 10 ND ND ND 3.2 JND
27-Jun-17 5.0 10 ND ND ND ND ND
Barium 10-Apr-14 5 100 14.4 J ---86.9 J 127 ND
NC 2L = 700 µg/l (01/01/10)6-May-14 5 100 11.7 J ---75.7 J 110 ND
20-Jun-14 5 100 14.2 J ---52.2 J 85.2 J ND
17-Jul-14 5 100 14.4 J ---52.4 J 58.1 J ND
23-Oct-14 5 100 20.3 J 70.0 J 20.8 J 97.8 J ND
21-May-15 5 100 17.9 J 116.0 28.3 J 91 J ND
8-Dec-15 2.5 100 17.6 J 67.3 J 1110 83.5 J ND
Verification Sample >4-Feb-16 2.5 100 ------264 ---ND
4-May-16 2.5 100 26.6 J 118.0 38.4 J 111 ND
13-Dec-16 2.5 100 13.4 J 123 56.6 J 92.8 J ND
27-Jun-17 2.5 100 18.8 J 72.1 J 74.3 J 77.1 J ND
Beryllium 8-Dec-15 0.5 1 ND ND 3.4 ND ND
Verification Sample >4-Feb-16 0.5 1 ------0.83 J ---ND
GWPS = 4 µg/l (01/01/10). 4-May-16 0.5 1 ND ND ND ND ND
13-Dec-16 0.5 1 ND ND ND ND ND
27-Jun-17 0.5 1 ND ND ND ND ND
Chloride 10-Apr-14 1,000 1,000 ND ---ND 4,980 ND
NC 2L = 250,000 µg/l (01/01/10)6-May-14 1,000 1,000 ND ---1,140 4,930 ND
20-Jun-14 1,000 1,000 ND ---1,320 4,410 ND
17-Jul-14 500 1,000 570 J ---1,090 4,310 ND
23-Oct-14 500 1,000 ND 1,050 727 J 4,650 ND
21-May-15 500 1,000 750 J 1,550 1,380 4,980 ---
8-Dec-15 500 1,000 859 J 1,840 4,200 4,390 ---
4-May-16 500 1,000 558 J 4,500 2,440 5,980 ---
13-Dec-16 500 1,000 1,470 1,460 1,240 4,760 ---
27-Jun-17 500 1,000 ND 1,380 1,070 4,670 ---
Chromium 10-Apr-14 5 10 ND ---ND ND ND
NC 2L = 10 µg/l (01/01/10)6-May-14 5 10 ND ---ND ND ND
20-Jun-14 5 10 ND ---ND ND ND
17-Jul-14 5 10 ND ---ND ND ND
23-Oct-14 5 10 ND 7.0 J ND ND ND
21-May-15 5 10 ND 7.4 J ND ND ND
8-Dec-15 2.5 10 ND 4.7 J 16.8 ND ND
Verification Sample >4-Feb-16 2.5 10 ------6.6 J ---ND
4-May-16 2.5 10 4.2 J 10.4 ND ND ND
13-Dec-16 2.5 10 ND 9.8 JND 4.0 JND
27-Jun-17 2.5 10 ND 3.5 JND 3.0 JND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 1 of 6
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL QL MW-21 MW-20 MW-22S MW-38 Blanks
Cobalt 10-Apr-14 5 10 ND ---ND 80.8 ND
GWPS = 1 µg/l (10/1/10)6-May-14 5 10 ND ---ND 58.0 ND
20-Jun-14 5 10 ND ---ND 12.5 ND
17-Jul-14 5 10 ND ---ND 18.9 ND
23-Oct-14 5 10 ND ND ND 21.5 ND
21-May-15 5 10 ND 2.9 J ND 10.5 ND
8-Dec-15 2.5 10 ND ND 11.2 4.1 J ND
Verification Sample >4-Feb-16 2.5 10 ------3.2 J ---ND
4-May-16 2.5 10 4.0 J 3.1 JND 10.0 ND
13-Dec-16 2.5 10 ND 3.6 JND ND ND
27-Jun-17 2.5 10 ND ND ND ND ND
Copper 8-Dec-15 2.5 10 ND J 30.0 3.3 J ND
NC 2L = 1,000 µg/l (01/01/10). Verifi. Sample > 4-Feb-16 2.5 10 ------10.4 ---ND
4-May-16 2.5 10 8.7 J 9.8 JND 2.8 JND
13-Dec-16 2.5 10 4.1 J 11.9 2.8 J 9.1 JND
27-Jun-17 2.5 10 3.9 J 3.3 JND ND ND
Iron 10-Apr-14 50 300 ND ---559 22,800 ND
NC 2L = 300 µg/l (01/01/10) 6-May-14 50 300 177 J ---3,930 16,300 ND
20-Jun-14 50 300 200 J ---402 14,400 ND
17-Jul-14 50 300 381 ---2,280 4,390 ND
23-Oct-14 50 300 2,340 3,990 719 16,700 ND
21-May-15 50 300 350 6,660 295 J 16,100 ND
8-Dec-15 25 300 1,380 3,590 29,700 27,800 ND
Verification Sample >4-Feb-16 25 300 ------9,840 ---ND
4-May-16 25 300 7,630 8,590 929 30,500 27.3 J
13-Dec-16 25 300 2,020 9,700 2,440 37,400 ND
27-Jun-17 25 300 2,340 3,140 1,300 40,800 ND
Lead 8-Dec-15 2.5 10 ND 3.0 J 39.4 3.2 J ND
NC 2L = 15 µg/l (01/01/10)4-Feb-16 2.5 10 ------10.5 ---ND
4-May-16 2.5 10 ND 4.4 JND ND ND
13-Dec-16 2.5 10 ND 5.1 JND 6.2 JND
27-Jun-17 2.5 10 ND ND ND 3.4 JND
Manganese 10-Apr-14 5 50 20.8 J ---132 5,450 ND
NC 2L = 50 µg/l (01/01/10)6-May-14 5 50 22.5 J ---77.5 4,830 ND
20-Jun-14 5 50 24.7 J ---52.2 3,790 ND
17-Jul-14 5 50 27.9 J ---39.8 J 3,380 ND
23-Oct-14 5 50 73.6 77.5 16.6 J 3,930 ND
21-May-15 5 50 27.4 J 146 11.7 J 3,060 ND
8-Dec-15 2.5 50 50.0 J 68.5 462 3,220 ND
Verification Sample >4-Feb-16 2.5 50 ------124 ---ND
4-May-16 2.5 50 142 148 14.3 J 4,170 ND
13-Dec-16 2.5 50 48.1 J 169 33.0 J 3,380 ND
27-Jun-17 2.5 50 60.3 65.5 24.9 J 3,700 ND
Nickel 10-Apr-14 5 50 ND ---ND ND ND
NC 2L = 100 µg/l (10/23/07)6-May-14 5 50 ND ---ND 10.6 J ND
20-Jun-14 5 50 ND ---ND ND ND
17-Jul-14 5 50 ND ---ND 5 J ND
23-Oct-14 5 50 ND ND ND 5.1 J ND
21-May-15 5 50 ND 4.3 ND 4.3 J ND
8-Dec-15 2.5 50 ND 2.5 J 18.7 J 3.0 J ND
Verification Sample >4-Feb-16 2.5 50 ------5.7 J ---ND
4-May-16 2.5 50 ND 5.9 JND 2.7 JND
13-Dec-16 2.5 50 ND 6.8 JND 3.4 JND
27-Jun-17 2.5 50 ND ND ND ND ND
Thallium 8-Dec-15 5 5.5 ND ND ND ND J ND
GWPS = 0.28 µg/l 4-Feb-16 2.5 50 ------9.1 ---ND
4-May-16 5 5.5 ND ND ND ND ND
13-Dec-16 5 5.5 ND ND ND ND ND
27-Jun-17 0.02 5.5 ND 0.077 J 0.057 J ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 2 of 6
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL QL MW-21 MW-20 MW-22S MW-38 Blanks
Sulfate 10-Apr-14 2,000 250,000 ND ---2,110 J 3,430 J ND
NC 2L = 250,000 µg/l (01/01/10)6-May-14 2,000 250,000 ND ---8,740 J ND ND
20-Jun-14 2,000 250,000 ND ---ND 10,100 J ND
17-Jul-14 1,000 250,000 1,340 J ---1,560 J 8,720 J ND
23-Oct-14 1,000 250,000 ND 1,300 J 1,320 J 3,320 J ND
21-May-15 1,000 250,000 ND ND ND 2,650 J ND
8-Dec-15 1,000 250,000 ND ND ND 4,640 J ND
4-May-16 1,000 250,000 ND 1,270 J 1,290 J 2,770 J ND
13-Dec-16 1,000 250,000 1,340 J 1,530 J 1,460 J 6,820 J ---
27-Jun-17 500 250,000 ND 712 J 761 J 5,400 J ---
Total Dissolved Solids, Dissolved 10-Apr-14 25,000 25,000 37,000 ---68,000 302,000 ND
NC 2L = 500,000 µg/l (01/01/10)6-May-14 25,000 25,000 ND ---30,000 257,000 ND
20-Jun-14 25,000 25,000 ND ---ND 301,000 ND
17-Jul-14 25,000 25,000 ND ---ND 245,000 ND
23-Oct-14 25,000 25,000 ND 25,000 ND 265,000 ND
21-May-15 25,000 25,000 ND 36,000 29,000 268,000 ---
8-Dec-15 25,000 25,000 ND 31,000 96,000 311,000 ---
4-May-16 25,000 25,000 ND 30,000 30,000 299,000 ---
13-Dec-16 25,000 25,000 ND 33,000 ND 366,000 ---
27-Jun-17 25,000 25,000 ND 34,000 28,000 374,000 ---
Vanadium 10-Apr-14 5 25 ND ---ND ND ND
GWPS = 0.3 µg/l (10/1/10)6-May-14 5 25 ND ---7.3 J ND ND
20-Jun-14 5 25 ND ---ND ND ND
17-Jul-14 5 25 ND ---ND ND ND
23-Oct-14 5 25 9.6 J 6.5 J ND ND ND
21-May-15 5 25 ND 11.6 ND 4 J ND
8-Dec-15 2.5 25 ND J 6.9 J 44.8 8.5 J ND
Verification Sample >4-Feb-16 2.5 50 ------16.0 J ---ND
4-May-16 2.5 25 29.7 14.5 JND ND ND
13-Dec-16 2.5 25 6.8 J 13.9 J 3.30 J ND ND
27-Jun-17 2.5 25 9.4 J 5.1 JND 2.8 JND
Zinc 10-Apr-14 10 10 ND ---19.6 ND ND
NC 2L = 1,000 µg/l (01/01/10)6-May-14 10 10 ND ---15.5 15.8 ND
20-Jun-14 10 10 ND ---ND ND 10.9
17-Jul-14 10 10 ND ---ND 12.5 B 10.5
23-Oct-14 10 10 ND 12.8 ND ND ND
21-May-15 10 10 26.4 19.7 ND ND ND
8-Dec-15 5 10 ND 10.3 127 8.7 J ND
Verification Sample >4-Feb-16 5 10 ------36.5 ND ND
4-May-16 5 10 10.5 22.4 5.5 J 6.4 J ND
13-Dec-16 5 10 ND 23.8 9.3 J 9.5 J ND
27-Jun-17 5 10 8.2 J 11.4 11.9 7.0 J ND
ORGANICS
Acetone 10-Apr-14 10 100 ND ---ND 10.2 J ND
NC 2L = 6,000 µg/l 6-May-14 10 100 ND ---ND ND ND
20-Jun-14 10 100 ND ---ND ND ND
17-Jul-14 10 100 ND ---ND ND ND
23-Oct-14 10 100 ND ND ND ND ND
21-May-15 10 100 ND ND ND ND ND
8-Dec-15 10 100 ND ND ND ND ND
4-May-16 10 100 ND ND ND ND ND
13-Dec-16 10 100 ND ND ND ND ---
27-Jun-17 10 100 35.8 B 12.4 B 20.2 B 12.2 B 35.3 J
Benzene 10-Apr-14 0.25 1 ND ---ND 6.6 ND
NC 2L = 1 µg/l (10/23/07)6-May-14 0.25 1 ND ---ND 6.5 ND
20-Jun-14 0.25 1 ND ---ND 5.5 ND
17-Jul-14 0.25 1 ND ---ND 4.6 ND
23-Oct-14 0.25 1 ND ND ND 5.9 ND
21-May-15 0.25 1 ND ND ND 4.9 ND
8-Dec-15 0.25 1 ND ND ND 4.4 ND
4-May-16 0.25 1 ND ND ND 5.4 ND
13-Dec-16 0.25 1 ND ND ND 3.0 ND
27-Jun-17 0.25 1 ND ND ND 5.0 ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 3 of 6
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL QL MW-21 MW-20 MW-22S MW-38 Blanks
Chlorobenzene 10-Apr-14 0.23 3 ND --- ND 0.71 J ND
NC 2L = 50 µg/l (10/23/07) 6-May-14 0.23 3 ND --- ND 0.6 J ND
20-Jun-14 0.23 3 ND --- ND 0.5 J ND
17-Jul-14 0.23 3 ND --- ND 0.61 J ND
23-Oct-14 0.23 3 ND ND ND 0.61 J ND
21-May-15 0.23 3 ND ND ND 0.51 J ND
8-Dec-15 0.23 3 ND ND ND 0.49 J ND
4-May-16 0.23 3 ND ND ND 0.56 J ND
13-Dec-16 0.23 3 ND ND ND 0.41 J ND
27-Jun-17 0.23 3 ND ND ND ND ND
1,2-Dichlorobenzene 10-Apr-14 0.3 5 ND --- ND 0.3 J ND
NC 2L = 20 µg/l (01/01/10) 6-May-14 0.3 5 ND --- ND 0.36 J ND
20-Jun-14 0.3 5 ND --- ND ND ND
17-Jul-14 0.3 5 ND --- ND ND ND
23-Oct-14 0.3 5 ND ND ND 0.31 J ND
21-May-15 0.3 5 ND ND ND ND ND
8-Dec-15 0.3 5 ND ND ND ND ND
4-May-16 0.3 5 ND ND ND 0.30 J ND
13-Dec-16 0.3 5 ND ND ND ND ND
27-Jun-17 0.3 5 ND ND ND ND ND
1,4-Dichlorobenzene 10-Apr-14 0.33 1 ND --- ND 13.9 ND
NC 2L = 6 µg/l (01/01/10) 6-May-14 0.33 1 ND --- ND 13.5 ND
20-Jun-14 0.33 1 ND --- ND 9.9 ND
17-Jul-14 0.33 1 ND --- ND 13.0 ND
23-Oct-14 0.33 1 ND ND ND 12.9 ND
21-May-15 0.33 1 ND ND ND 12.3 ND
8-Dec-15 0.33 1 ND ND ND 12.2 ND
4-May-16 0.33 1 ND ND ND 13.3 ND
13-Dec-16 0.33 1 ND ND ND 8.3 ND
27-Jun-17 0.33 1 ND ND ND 11.0 ND
1,1-Dichloroethane 10-Apr-14 0.32 5 ND --- ND 8.6 ND
NC 2L = 6 µg/l (01/01/10) 6-May-14 0.32 5 ND --- ND 8.1 ND
20-Jun-14 0.32 5 ND --- ND 8.0 ND
17-Jul-14 0.32 5 ND --- ND 5.7 ND
23-Oct-14 0.32 5 ND ND ND 6.9 ND
21-May-15 0.32 5 ND ND ND 5.5 ND
8-Dec-15 0.32 5 ND ND ND 7.2 ND
4-May-16 0.32 5 ND ND ND 6.5 ND
13-Dec-16 0.32 5 ND ND ND 6.0 ND
27-Jun-17 0.32 5 ND ND ND 6.2 ND
1,2-Dichloroethane 10-Apr-14 0.12 1 ND --- ND 0.77 J ND
NC 2L = 0.4 µg/l (01/01/10)6-May-14 0.12 1 ND --- ND ND ND
20-Jun-14 0.12 1 ND --- ND 0.63 J ND
17-Jul-14 0.12 1 ND --- ND 0.79 J ND
23-Oct-14 0.12 1 ND ND ND 0.63 J ND
21-May-15 0.12 1 ND ND ND ND ND
8-Dec-15 0.24 1 ND ND ND 0.70 J ND
4-May-16 0.24 1 ND ND ND 0.74 J ND
13-Dec-16 0.24 1 ND ND ND 0.63 J ND
27-Jun-17 0.24 1 ND ND ND 0.67 J ND
cis-1,2-Dichloroethene 10-Apr-14 0.19 5 ND ---ND 19.6 ND
NC 2L = 70 µg/l (10/23/07)6-May-14 0.19 5 ND ---ND 17.1 ND
20-Jun-14 0.19 5 ND ---ND 16 ND
17-Jul-14 0.19 5 ND ---ND 14.1 ND
23-Oct-14 0.19 5 ND ND ND 16.3 ND
21-May-15 0.19 5 ND ND ND 12.1 ND
8-Dec-15 0.19 5 ND ND ND 14.7 ND
4-May-16 0.19 5 ND ND ND 13.2 ND
13-Dec-16 0.19 5 ND ND ND 12.7 ND
27-Jun-17 0.19 5 ND ND ND 10.9 ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 4 of 6
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL QL MW-21 MW-20 MW-22S MW-38 Blanks
Ethylbenzene 10-Apr-14 0.3 1 ND ---ND 1.2 ND
NC 2L = 600 µg/l (01/01/10)6-May-14 0.3 1 ND ---ND 1.3 ND
20-Jun-14 0.3 1 ND ---ND 0.77 J ND
17-Jul-14 0.3 1 ND ---ND 0.64 J ND
23-Oct-14 0.3 1 ND ND ND 1.3 ND
21-May-15 0.3 1 ND ND ND 1.1 ND
8-Dec-15 0.3 1 ND ND ND ND ND
4-May-16 0.3 1 ND ND ND 0.72 J ND
13-Dec-16 0.3 1 ND ND ND ND ND
27-Jun-17 0.3 1 ND ND ND ND ND
2-Hexanone (MBK)10-Apr-14 0.46 50 ND ---0.55 J ND ND
GWPS = 280 µg/l (01/01/10)6-May-14 0.46 50 ND ---ND ND ND
20-Jun-14 0.46 50 ND ---ND ND ND
17-Jul-14 0.46 50 ND ---ND ND ND
23-Oct-14 0.46 50 ND ND ND ND ND
GWPS = 280 µg/l (02/01/15)21-May-15 0.46 50 ND ND ND ND ND
8-Dec-15 0.46 50 ND ND ND ND ND
4-Methyl-2-pentanone (MIBK)10-Apr-14 0.33 100 ND ---ND 3.7 J ND
GWPS = 560 µg/l (12/7/10)6-May-14 0.33 100 ND ---ND 8.2 J ND
20-Jun-14 0.33 100 ND ---ND ND ND
17-Jul-14 0.33 100 ND ---ND ND ND
23-Oct-14 0.33 100 ND ND ND 1.5 J ND
21-May-15 0.33 100 ND ND ND ND
8-Dec-15 0.33 100 ND ND ND ND ND
4-May-16 0.33 100 ND ND ND 0.89 J ND
13-Dec-16 0.33 100 ND ND ND ND ND
27-Jun-17 0.33 100 ND ND ND ND ND
Methane 10-Apr-14 3.3 6.6 ---------------
6-May-14 3.3 6.6 ---------4,150 ---
20-Jun-14 3.3 6.6 ---------------
17-Jul-14 3.3 6.6 ---------------
23-Oct-14 3.3 6.6 ---------6,820 ---
21-May-15 3.3 6.6 ---------4,900 ---
8-Dec-15 3.3 6.6 ---------3,112 2.0 J
13-Dec-16 100 100 ---------15,300 J ---
Methylene Chloride 8-Dec-15 0.97 1 ND ND ND ND 2.0
4-May-16 0.97 1 ND ND ND ND ND
13-Dec-16 0.97 1 ND ND ND ND ---
27-Jun-17 0.97 1 ND ND ND ND ND
NC 2L = 5 (02/01/15)
Tetrahydrofuran 10-Apr-14 3.1 10 ND ---ND 923 ND
NC 2L = NE (01/01/10)6-May-14 3.1 10 ND ---ND 848 ND
20-Jun-14 3.1 10 ND ---ND 758 ND
17-Jul-14 3.1 10 ND ---ND 841 ND
23-Oct-14 3.1 10 ND ND ND 744 ND
21-May-15 3.1 10 ND ND ND 407 ND
8-Dec-15 3.1 10 ND ND ND 39.1 ND
4-May-16 3.1 10 ND ND ND 313 ND
13-Dec-16 3.1 10 ND ND ND ND ---
27-Jun-17 3.1 10 ND ND ND 3.1 J ND
Toluene 10-Apr-14 0.26 1 ND ---ND 0.62 J ND
NC 2L = 600 µg/l (01/01/10)6-May-14 0.26 1 ND ---ND 0.68 J ND
20-Jun-14 0.26 1 ND ---ND 0.32 J ND
17-Jul-14 0.26 1 ND ---ND 0.28 J ND
23-Oct-14 0.26 1 ND ND ND 0.66 J ND
21-May-15 0.26 1 ND ND ND 0.48 J ND
8-Dec-15 0.26 1 ND ND ND ND ND
4-May-16 0.26 1 ND ND ND 0.49 J ND
13-Dec-16 0.26 1 ND ND ND ND ---
27-Jun-17 0.26 1 ND ND ND 0.30 J ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 5 of 6
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL QL MW-21 MW-20 MW-22S MW-38 Blanks
Trichlorofluoromethane 27-Jun-17 0.2 1 ND ND 0.46 J ND ND
Trichloroethene 10-Apr-14 0.47 1 ND ---ND 2.7 ND
NC 2L = 3 µg/l (01/01/10)6-May-14 0.47 1 ND ---ND 2.1 ND
20-Jun-14 0.47 1 ND ---ND 2.2 ND
17-Jul-14 0.47 1 ND ---ND 2.5 ND
23-Oct-14 0.47 1 ND ND ND 1.8 ND
21-May-15 0.47 1 ND ND ND 0.92 J ND
8-Dec-15 0.47 1 ND ND ND 2.1 ND
4-May-16 0.47 1 ND ND ND 1.7 ND
13-Dec-16 0.47 1 ND ND ND 1.8 ---
27-Jun-17 0.47 1 ND ND ND 2.1 ND
Vinyl chloride 4-May-16 0.62 1 ND ND ND 1.8 ND
Verification Sample >9-Jun-16 0.62 1 ---------ND ND
NC 2L = 0.03 µg/l (02/01/15)13-Dec-16 0.62 1 ND ND ND ND ---
27-Jun-17 0.62 1 ND ND ND 1.9 ND
Verification Sample >8-Aug-17 0.62 1 ---------ND ND
Xylene (Total)10-Apr-14 0.66 5 ND ---ND 16.9 ND
NC 2L = 500 µg/l (01/01/10)6-May-14 0.66 5 ND ---ND 19.3 ND
20-Jun-14 0.66 5 ND ---ND 2.5 J ND
17-Jul-14 0.66 5 ND ---ND 8.8 ND
23-Oct-14 0.66 5 ND ND ND 18.7 ND
21-May-15 0.66 5 ND ND ND 17.1 ND
8-Dec-15 0.66 5 ND ND ND 1.6 J ND
4-May-16 0.66 5 ND ND ND 11.5 ND
13-Dec-16 0.66 5 ND ND ND ND ---
27-Jun-17 0.66 5 ND ND ND ND ND
Notes:
All concentrations in micrograms per liter (µg/l) = parts per billion.
RL = Reporting Limit (SWSL).
DL = Laboratory Detection Limit.
--- = Not sampled for this parameter or Not reported.
ND = Not Detected at or above the DL.
J = Estimated value - concentration is less than the RL but greater than the DL.
B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination based on similar concentrations detected in field, trip, or method blanks).
NC 2L = Groundwater Standard from 15A NCAC 2L.0202.
GWPS = Groundwater Protection Standard set by NC-DENR-SWS for constituents with no listed NC 2L standard.
NE = No NC 2L or GWPS established.
Values above the NC 2L Standard or GWPS are bold.
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 6 of 6
Joyce Engineering

Appendix D

Historical Detected Constituents in Additional Wells and Piezometers

APPENDIX D:
DETECTED CONSTITUENTS IN ADDITIONAL WELLS/PIEZOMETERS
Sample
Analyte Collection Date DL RL MW-36 MW-15S PZ-12 PZ-30S PZ-31 PZ-35 Blanks
Organic Compounds
Acetone 18-Feb-13 10.0 100 19.8 J ------ND ---ND ND
18-Jul-13 10.0 100 ------------ND ---15.80 J
NC 2L = 6,000 µg/l (01/01/10)6-May-14 10.0 100 ------------------ND
22-Oct-14 10.0 100 ------------------ND
21-May-15 10.0 100 ------------------ND
9-Dec-15 10.0 100 ------------------ND
Benzene 18-Feb-13 0.25 1.0 8.0 --- --- ND --- ND ND
18-Jul-13 0.25 1.0 --- --- --- ---7.6 --- ND
NC 2L = 1 µg/l (10/23/07)6-May-14 0.25 1.0 8.7 4.6 --- ND ND ND ND
22-Oct-14 0.25 1.0 8.3 3.3 ND ND ND ND ND
21-May-15 0.25 1.0 5.8 2.0 ND ND ND ND ND
9-Dec-15 0.25 1.0 5.8 1.2 ND ND ND ND ND
4-May-16 0.25 1.0 6.7 1.3 ND ND ND ND ND
14-Dec-16 0.25 1.0 5.5 0.85 J ND ND ND ND ND
28-Jun-17 0.25 1.0 5.3 0.43 J ND ND ND ND ND
Chlorobenzene 18-Feb-13 0.23 3.0 0.760 J ------ND ---ND ND
18-Jul-13 0.23 3.0 ------------0.480 J ---ND
NC 2L = 50 µg/l (10/23/07)6-May-14 0.23 3.0 ------------------ND
22-Oct-14 0.23 3.0 ------------------ND
21-May-15 0.23 3.0 ------------------ND
9-Dec-15 0.23 3.0 ------------------ND
Chloroethane 18-Feb-13 0.54 10.0 1.10 J ------ND ---ND ND
18-Jul-13 0.54 10.0 ------------ND ---ND
NC 2L = 3,000 µg/l (01/01/10)6-May-14 0.54 10.0 ------------------ND
22-Oct-14 0.54 10.0 ------------------ND
21-May-15 0.54 10.0 ------------------ND
9-Dec-15 0.54 10.0 ------------------ND
1,2-Dichlorobenzene 18-Feb-13 0.30 5.0 0.44 J ------ND ---ND ND
18-Jul-13 0.30 5.0 ------------0.61 J ---ND
NC 2L = 20 µg/l (01/01/10)6-May-14 0.30 5.0 ------------------ND
22-Oct-14 0.30 5.0 ------------------ND
21-May-15 0.30 5.0 ------------------ND
9-Dec-15 0.30 5.0 ------------------ND
1,4-Dichlorobenzene 18-Feb-13 0.33 1.0 18.0 --- --- ND --- ND ND
18-Jul-13 0.33 1.0 ------------6.5 ---ND
NC 2L = 6 µg/l (01/01/10)6-May-14 0.33 1.0 10.0 2.3 --- ND ND ND ND
22-Oct-14 0.33 1.0 15.2 1.6 ND ND ND ND ND
21-May-15 0.33 1.0 18.7 1.4 ND ND ND ND ND
9-Dec-15 0.33 1.0 19.6 1.0 ND ND ND ND ND
4-May-16 0.33 1.0 16.5 0.9JNDNDNDND---
14-Dec-16 0.33 1.0 15.8 0.7JNDNDNDNDND
28-Jun-17 0.33 1.0 20.1 ND ND ND ND ND ND
1,1-Dichloroethane 18-Feb-13 0.32 5.0 7.9 --- --- ND --- ND ND
18-Jul-13 0.32 5.0 ------------11.3 ---ND
NC 2L = 6 µg/l (01/01/10)6-May-14 0.32 5.0 11.6 7.1 --- ND ND ND ND
22-Oct-14 0.32 5.0 9.0 4.9JNDNDNDNDND
21-May-15 0.32 5.0 4.8 J 2.4JNDNDNDNDND
9-Dec-15 0.32 5.0 5.9 2.2 J ND ND ND ND ND
4-May-16 0.32 5.0 5.9 1.5 J ND ND ND ND ---
14-Dec-16 0.32 5.0 4.4 J 0.85 J ND ND ND ND ND
28-Jun-17 0.32 5.0 4.3 J 0.59 J ND ND ND ND ND
1,2-Dichloroethane 18-Feb-13 0.12 1.0 1.0 --- --- ND --- ND ND
18-Jul-13 0.12 1.0 ------------0.54 J ---ND
NC 2L = 0.4 µg/l (01/01/10)6-May-14 0.12 1.0 0.78 J ND ---ND ND ND ND
22-Oct-14 0.12 1.0 0.92 J ND ND ND ND ND ND
21-May-15 0.12 1.0 ND ND ND ND ND ND ND
9-Dec-15 0.24 1.0 0.66 J ND ND ND ND ND ND
4-May-16 0.24 1.0 0.92 J ND ND ND ND ND ---
14-Dec-16 0.24 1.0 0.77 J ND ND ND ND ND ND
28-Jun-17 0.24 1.0 0.75 J ND ND ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 1 of 3
Joyce Engineering
APPENDIX D:
DETECTED CONSTITUENTS IN ADDITIONAL WELLS/PIEZOMETERS
Sample
Analyte Collection Date DL RL MW-36 MW-15S PZ-12 PZ-30S PZ-31 PZ-35 Blanks
cis-1,2-Dichloroethylene 18-Feb-13 0.19 5.0 21.0 ------ND ---ND ND
18-Jul-13 0.19 5.0 ------------19.3 ---ND
NC 2L = 70 µg/l (10/23/07)6-May-14 0.19 5.0 ------------------ND
22-Oct-14 0.19 5.0 ------------------ND
21-May-15 0.19 5.0 ------------------ND
9-Dec-15 0.19 5.0 ------------------ND
Ethylbenzene 18-Feb-13 0.30 1.0 23.2 ------ND ---ND ND
18-Jul-13 0.30 1.0 ------------0.94 J ---ND
NC 2L = 600 µg/l (01/01/10)6-May-14 0.30 1.0 ------------------ND
22-Oct-14 0.30 1.0 ------------------ND
21-May-15 0.30 1.0 ------------------ND
9-Dec-15 0.30 1.0 ------------------ND
Methylene Chloride 18-Feb-13 0.97 1.0 17.9 --- --- ND --- ND ND
18-Jul-13 0.97 1.0 NS --- --- ---16.4 --- ND
NC 2L = 5 µg/l (01/01/10)6-May-14 0.97 1.0 24.1 16.7 --- ND ND ND 2.20
22-Oct-14 0.97 1.0 15.7 1.6 ND ND ND ND ND
21-May-15 0.97 1.0 9.5 B 4.4 B ND ND ND ND 1.70
9-Dec-15 0.97 1.0 11.2 B 2.6 B ND ND ND ND 2.0
4-May-16 0.97 1.0 3.1 2.0 ND ND ND ND ---
14-Dec-16 0.97 1.0 ND ND ND ND ND ND ND
28-Jun-17 0.97 1.0 ND ND ND ND ND ND ND
Tetrachloroethene 18-Feb-13 0.46 1.0 5.5 --- --- ND --- ND ND
18-Jul-13 0.46 1.0 NS ---------7.8 ---ND
NC 2L = 0.7 µg/l (10/23/07)6-May-14 0.46 1.0 7.9 6.9 --- ND ND ND ND
22-Oct-14 0.46 1.0 7.3 5.2 ND ND ND ND ND
21-May-15 0.46 1.0 6.0 3.3 ND ND ND ND ND
9-Dec-15 0.46 1.0 5.0 2.1 ND ND ND ND ND
4-May-16 0.46 1.0 4.5 2.0 ND ND ND ND ---
14-Dec-16 0.46 1.0 ND 1.4 ND ND ND ND ND
28-Jun-17 0.46 1.0 ND 0.80 J ND ND ND ND ND
Toluene 18-Feb-13 0.26 1.0 44.10 ------ND ---ND ND
18-Jul-13 0.26 1.0 ------------1.50 ---ND
NC 2L = 600 µg/l (01/01/10)6-May-14 0.26 1.0 ------------------ND
22-Oct-14 0.26 1.0 ------------------ND
21-May-15 0.26 1.0 ------------------ND
9-Dec-15 0.26 1.0 ------------------ND
Trichloroethene 18-Feb-13 0.47 1.0 3.6 --- --- ND --- ND ND
18-Jul-13 0.47 1.0 ------------5.8 ---ND
NC 2L = 3 µg/l (01/01/10)6-May-14 0.47 1.0 6.0 4.3 --- ND ND ND ND
22-Oct-14 0.47 1.0 5.1 3.4 ND ND ND ND ND
21-May-15 0.47 1.0 3.5 2.1 ND ND ND ND ND
9-Dec-15 0.47 1.0 2.9 1.1 ND ND ND ND ND
4-May-16 0.47 1.0 3.1 --- ND ND ND ND ---
14-Dec-16 0.47 1.0 ND 0.81 J ND ND ND ND ND
28-Jun-17 0.47 1.0 ND ND ND ND ND ND ND
Trichlorofluoromethane 18-Feb-13 0.20 1.0 0.650 J ------ND ---ND ND
18-Jul-13 0.20 1.0 ------------0.890 J ---ND
NC 2L = 2,000 µg/l (01/01/10)6-May-14 0.20 1.0 ------------------ND
22-Oct-14 0.20 1.0 ------------------ND
21-May-15 0.20 1.0 ------------------ND
9-Dec-15 0.20 1.0 ------------------ND
Vinyl chloride 18-Feb-13 0.62 1.0 1.2 --- --- ND --- ND ND
18-Jul-13 0.62 1.0 ------------ND ---ND
NC 2L = 0.03 µg/l (01/01/10)6-May-14 0.62 1.0 1.1 ND --- ND ND ND ND
22-Oct-14 0.62 1.0 0.87 J ND ND ND ND ND ND
21-May-15 0.62 1.0 ND ND ND ND ND ND ND
9-Dec-15 0.62 1.0 0.80 J ND ND ND ND ND ND
4-May-16 0.62 1.0 0.80 J ND ND ND ND ND ---
14-Dec-16 0.62 1.0 ND ND ND ND ND ND ND
28-Jun-17 0.62 1.0 0.64 J ND ND ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 2 of 3
Joyce Engineering
APPENDIX D:
DETECTED CONSTITUENTS IN ADDITIONAL WELLS/PIEZOMETERS
Sample
Analyte Collection Date DL RL MW-36 MW-15S PZ-12 PZ-30S PZ-31 PZ-35 Blanks
Xylene (Total)18-Feb-13 0.66 2.0 295 ------ND ---ND ND
18-Jul-13 0.66 2.0 ------------92.5 ---ND
NC 2L = 500 µg/l (01/01/10)6-May-14 0.66 2.0 ------------------ND
22-Oct-14 0.66 2.0 ------------------ND
21-May-15 0.66 2.0 ---ND ND ND ND ---ND
9-Dec-15 0.66 2.0 ---ND ND ND ND ---ND
Carbon Dioxide 14-Dec-16 450 5000 510000 350000 35000 22000 14000 29000 ---
(Dissolved Carbon Dioxide)28-Jun-17 450.0 5000 420000 250000 36000 23000 14000 22000 ---
Methane 18-Feb-13 0.66 2.0 ---------------------
(Dissolved Methane)18-Jul-13 0.66 2.0 ---------------------
6-May-14 0.66 2.0 348 9940 ---ND ND ND ---
22-Oct-14 3.30 6.6 8450 13000 ND ND ND ND ND
21-May-15 0.63 10.0 173 4680 2.0 J 1.5 J 1.7 J 2.0 J ---
9-Dec-15 0.63 10.0 3780 8550 3.0 J 2.5 J 4.8 J 2.7 J ---
4-May-16 0.49 10.0 8920 7860 1.6 J 1.6 J 1.8 J 2.3 J ---
14-Dec-16 200 200 32200 16700 ND ND 27.0 J ND ---
28-Jun-17 10 10 45400 25900 ND ND ND ND ---
Notes:
All concentrations in micrograms per liter (µg/l) = parts per billion.ND = Not Detected above the DL.
DL = Laboratory Detection Limit.J = Estimated value - Concentration is less than the SWSL but greater than the DL.
RL = SWSL = Solid Waste Section Reporting Limit.B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination).
NC 2L = Groundwater Standard from 15A NCAC 2L.0202.Values above the NC 2L Standard are bold
Italics = Constituent of Concern (COC).
nle = No longer exists (MW-34 was accidentaly destroyed during construciton activties).
--- = Not reported or Not monitored
MW-36 was converted from PZ-36.
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 3 of 3
Joyce Engineering

Appendix E

Historical Detected Surface Water Constituents
APPENDIX E:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Inorganic Compounds
Antimony 6-Nov-08 2.6 6.0 ND 8.4 ---ND
3-Jun-09 2.6 6.0 ND ND --- ND
18-Nov-09 2.6 6.0 ND ND --- ND
NC 2B = NE (05/01/07) 15-Jun-10 2.6 6.0 ND ND --- ND
1-Dec-10 2.6 6.0 ND ND --- ND
1-Jun-11 2.6 6.0 ND ND --- ND
20-Dec-11 5.0 6.0 ND ND --- ND
30-May-12 5.0 6.0 ND ND --- ND
5-Dec-12 5.0 6.0 ND ND --- ND
12-Jun-13 5.0 6.0 ND ND --- ND
28-Oct-13 5.0 6.0 ND ND --- ND
6-May-14 5.0 6.0 ND ND --- ND
22-Oct-14 5.0 6.0 --- ND ND ND
21-May-15 3.8 6.0 ND ND ND ND
9-Dec-15 3.8 6.0 ND ND ND ND
NC 2B = 5.6 µg/l (03/01/16) 4-May-16 3.8 6.0 ND ND ND ND
14-Dec-16 3.8 6.0 ND ND ND ND
28-Jun-17 3.9 6.0 ND ND ND ---
Arsenic 6-Nov-08 2.7 10.0 2.9 B 4.5 B ---4.1 J
3-Jun-09 2.7 10.0 ND 4.5 J ---ND
18-Nov-09 2.7 10.0 ND ND ---ND
NC 2B = 10 µg/l (05/01/07)15-Jun-10 2.7 10.0 ND ND ---ND
1-Dec-10 2.7 10.0 ND ND ---ND
1-Jun-11 2.7 10.0 ND ND ---ND
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 ND ND ---ND
12-Jun-13 5.0 10.0 ND ND ---ND
28-Oct-13 5.0 10.0 ND ND ---ND
6-May-14 5.0 10.0 ND ND ---ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 10 µg/l (03/01/16)4-May-16 2.5 10.0 3.0 J ND 3.3 J ND
14-Dec-16 2.5 10.0 ND ND ND ND
28-Jun-17 5.0 10.0 ND 5.5 J ND ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 1 of 9
Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Barium 30-May-07 --- 100 81.3 J 23.8 J ---0.2 J
29-Nov-07 --- 100 116 27.5 J --- 0.50 J
29-May-08 0.2 100 71.9 J 19.6 J --- ND
6-Nov-08 0.20 100 82.5 J 40.2 B --- 9.6 J
3-Jun-09 0.20 100 104 36.2 B --- 15.9 J
18-Nov-09 0.20 100 49.9 B 15.7 B --- 20.1 J
NC 2B = 1,000 µg/l (05/01/07) 15-Jun-10 0.20 100 47.6 J 20.7 J --- 0.77 J
1-Dec-10 0.20 100 39.8 J 46.8 J --- ND
1-Jun-11 0.20 100 51.6 J 19.9 J --- ND
20-Dec-11 5.0 100 63.7 J 13.9 J --- ND
30-May-12 5.0 100 16.9 J 22.0 J --- ND
5-Dec-12 5.0 100 69.9 J 24.8 J --- ND
12-Jun-13 5.0 100 54.9 B 40.0 B ---13.6 J
28-Oct-13 5.0 100 35.4 J 20.8 J --- ND
6-May-14 5.0 100 37.0 J 17.8 J --- ND
22-Oct-14 5.0 100 --- 25.5 J 19.8 J ND
21-May-15 2.5 100 53.0 J 14.6 J 21.6 J ND
9-Dec-15 2.5 100 26.1 J 23.4 J 27.8 J ND
NC 2B = 1,000 µg/l (03/01/16) 4-May-16 2.5 100 41.4 J 37.3 J 51.0 J ND
14-Dec-16 2.5 100 44.7 J 21.2 J 17.5 J ND
28-Jun-17 2.5 100 46.3 J 41.4 J 31.5 J ---
Beryllium 14-Nov-02 --- 2 2.0 B 2.2 B ---2.1
14-May-03 --- 2 ND ND ---ND
20-Nov-03 --- 2 ND ND ---ND
6-May-04 --- 2 ND ND ---ND
10-Nov-04 --- 2 ND ND ---ND
5-May-05 --- 2 ND ND ---ND
3-Nov-05 --- 2 ND ND ---ND
25-May-06 --- 2 ND ND ---ND
2-Nov-06 --- 2 ND ND ---ND
30-May-07 --- 1 ND ND ---ND
29-Nov-07 --- 1 ND ND ---ND
29-May-08 0.10 1.0 ND ND ---ND
6-Nov-08 0.10 1.0 0.24 B 0.37 B ---0.29 J
3-Jun-09 0.10 1.0 0.64 J 0.21 J --- ND
18-Nov-09 0.10 1.0 ND ND --- ND
NC 2B = 6.5 µg/l (05/01/07) 15-Jun-10 0.10 1.0 ND ND ---ND
1-Dec-10 0.10 1.0 ND ND --- ND
1-Jun-11 0.10 1.0 ND ND --- ND
20-Dec-11 1.0 1.0 ND ND --- ND
30-May-12 1.0 1.0 ND ND --- ND
5-Dec-12 1.0 1.0 ND ND --- ND
12-Jun-13 1.0 1.0 ND ND --- ND
28-Oct-13 1.0 1.0 ND ND --- ND
6-May-14 1.0 1.0 ND ND --- ND
22-Oct-14 1.0 1.0 --- ND ND ND
21-May-15 0.5 1.0 ND ND ND ND
9-Dec-15 0.5 1.0 ND ND ND ND
NC 2B = 6.5 µg/l Chronic (03/01/16)* 4-May-16 0.5 1.0 ND ND ND ND
14-Dec-16 0.5 1.0 ND ND ND ND
28-Jun-17 0.5 1.0 ND ND ND ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 2 of 9
Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Cadmium 7-Nov-01 --- 1 ND 1.0 --- ND
22-May-02 --- 1 ND 1.7 B ---1.3
14-Nov-02 --- 1 ND ND ---ND
14-May-03 --- 1 ND ND ---ND
20-Nov-03 --- 1 ND ND ---ND
6-May-04 --- 1 ND ND ---ND
10-Nov-04 --- 1 ND ND ---ND
5-May-05 --- 1 ND ND ---ND
3-Nov-05 --- 1 ND ND ---ND
25-May-06 --- 1 ND ND ---ND
2-Nov-06 --- 1 ND ND ---ND
30-May-07 --- 1 ND ND ---ND
29-Nov-07 --- 1 ND ND ---ND
29-May-08 0.5 1.0 ND ND ---ND
6-Nov-08 0.50 1.0 ND ND ---ND
3-Jun-09 0.50 1.0 ND ND ---ND
18-Nov-09 0.50 1.0 ND ND ---ND
NC 2B = 2 µg/l (05/01/07)15-Jun-10 0.50 1.0 ND ND ---ND
1-Dec-10 0.50 1.0 ND ND ---ND
1-Jun-11 0.50 1.0 ND ND ---ND
20-Dec-11 1.0 1.0 ND ND ---ND
30-May-12 1.0 1.0 ND ND ---ND
5-Dec-12 1.0 1.0 ND ND ---ND
12-Jun-13 1.0 1.0 ND ND ---ND
28-Oct-13 1.0 1.0 ND ND ---ND
6-May-14 1.0 1.0 ND ND ---ND
22-Oct-14 1.0 1.0 --- ND ND ND
21-May-15 0.5 1.0 ND ND ND ND
9-Dec-15 0.5 1.0 ND ND ND ND
NC 2B = 0.15 µg/l Chronic (03/01/16)*4-May-16 0.5 1.0 ND ND ND ND
14-Dec-16 0.5 1.0 ND ND ND ND
28-Jun-17 0.5 1.0 ND ND ND ---
Chromium, total 6-Nov-08 0.40 10.0 ND 0.47 J --- ND
3-Jun-09 0.40 10.0 7.5 J 3.2 J --- ND
18-Nov-09 0.40 10.0 ND ND ---ND
NC 2B = 50 µg/l (05/01/07)15-Jun-10 0.40 10.0 1.2 B 0.48 B --- 0.74 J
1-Dec-10 0.40 10.0 0.68 B 5.1 J --- 0.51 J
1-Jun-11 0.40 10.0 0.59 B 0.59 B --- 0.73 J
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 ND ND ---ND
12-Jun-13 5.0 10.0 ND ND ---ND
28-Oct-13 5.0 10.0 ND ND --- ND
6-May-14 5.0 10.0 ND ND ---ND
22-Oct-14 5.0 10.0 --- ND 9.7 J ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 11 µg/l Chronic (03/01/16)*4-May-16 2.5 10.0 4.7 J 4.6 J 8.8 J ND
14-Oct-16 2.5 10.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 3 of 9
Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Cobalt 22-May-02 --- 10 14.0 17.0 --- 11.0
14-Nov-02 --- 10 ND ND ---ND
14-May-03 --- 10 ND 10.0 ---ND
20-Nov-03 --- 10 14.0 ND ---ND
6-May-04 --- 10 ND ND ---ND
10-Nov-04 --- 10 10.0 ND ---ND
5-May-05 --- 10 10.0 ND ---ND
3-Nov-05 --- 10 16.0 ND ---ND
25-May-06 --- 10 12 ND ---ND
2-Nov-06 --- 10 13.6 ND ---ND
30-May-07 --- 10 12.3 8.8 J ---ND
29-Nov-07 --- 10 19.0 2.1 J ---ND
29-May-08 0.60 10.0 13.7 ND ---ND
6-Nov-08 0.60 10.0 12.6 ND --- 0.65 J
3-Jun-09 0.60 10.0 11.9 B 6.6 B ---7.6 J
18-Nov-09 0.60 10.0 3.6 J 4.6 J --- ND
NC 2B = NE (05/01/07)15-Jun-10 0.60 10.0 6.4 J 22.3 --- ND
1-Dec-10 0.60 10.0 0.76 J 4.1 J ---ND
1-Jun-11 0.60 10.0 2.0 J 1.7 J --- ND
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 29.0 7.7 J ---ND
12-Jun-13 5.0 10.0 ND 9.1 J --- ND
28-Oct-13 5.0 10.0 11.5 12.4 ---ND
6-May-14 5.0 10.0 ND ND ---ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 6.3 J ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 3 µg/l (03/01/16)4-May-16 2.5 10.0 4.0 J 5.6 J 3.3 J ND
14-Dec-16 2.5 10.0 5.9 J ND ND ND
28-Jun-17 2.5 10.0 6.4 J 3.6 J ND ---
Copper 29-May-08 0.30 10.0 ND 1.3 B --- 0.37 J
6-Nov-08 4.0 10.0 0.45 B 3.4 J --- 0.65 J
3-Jun-09 0.30 10.0 6.6 J 2.1 J --- ND
18-Nov-09 0.30 10.0 ND ND --- ND
NC 2B = 7 µg/l (05/01/07)15-Jun-10 0.30 10.0 0.56 B ND --- 0.77 J
1-Dec-10 0.30 10.0 3.6 J 5.9 J --- ND
1-Jun-11 0.30 10.0 1.8 J 0.35 J --- ND
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 ND ND --- ND
12-Jun-13 5.0 10.0 5.2 B ND ---9.8 J
28-Oct-13 5.0 10.0 ND ND --- ND
6-May-14 5.0 10.0 ND ND --- ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 2.7 µg/l Chronic (3/1/16)*4-May-16 2.5 10.0 4.6 J 5.5 J 11 ND
resample 17-May-16 2.5 10.0 --- --- ND ND
14-Dec-16 2.5 10.0 ND ND ND ND
28-Jun-17 2.5 10.0 ND ND ND ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 4 of 9
Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Lead 3-Jun-09 4.0 10.0 7.3 J ND ---ND
18-Nov-09 4.0 10.0 ND ND ---ND
NC 2B = 25 µg/l (05/01/07)15-Jun-10 4.0 10.0 ND ND ---ND
1-Dec-10 4.0 10.0 ND 4.6 J --- ND
1-Jun-11 4.0 10.0 ND ND ---ND
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND --- ND
5-Dec-12 5.0 10.0 ND ND ---ND
12-Jun-13 5.0 10.0 ND ND ---ND
28-Oct-13 5.0 10.0 ND ND --- ND
6-May-14 5.0 10.0 ND ND ---ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 14 µg/l Acute, 0.54 µg/l Chronic * 4-May-16 2.5 10.0 ND 4.9 J 7.2 J ND
14-Dec-16 2.5 10.0 ND ND ND ND
28-Jun-17 2.5 10.0 ND ND ND ---
Nickel 3-Jun-09 1.7 50.0 5.5 B ND ---1.7 J
18-Nov-09 1.7 50.0 ND ND ---ND
NC 2B = 25 µg/l (05/01/07)15-Jun-10 1.7 50.0 ND ND ---ND
1-Dec-10 1.7 50.0 2.8 J 2.8 J --- ND
1-Jun-11 1.7 50.0 ND ND ---2.3 J
20-Dec-11 5.0 50.0 ND ND ---ND
30-May-12 5.0 50.0 ND ND --- ND
5-Dec-12 5.0 50.0 ND ND ---ND
12-Jun-13 5.0 50.0 ND ND ---ND
28-Oct-13 5.0 50.0 ND ND --- ND
6-May-14 5.0 50.0 ND ND ---ND
22-Oct-14 5.0 50.0 --- ND ND ND
21-May-15 2.5 50.0 ND ND ND ND
9-Dec-15 2.5 50.0 ND ND ND ND
NC 2B = 16 µg/l Chronic (03/01/16)*4-May-16 2.5 50.0 3.8 J 3.9 J 6.7 J ND
14-Dec-16 2.5 50.0 ND ND ND ND
28-Jun-17 2.5 50.0 ND ND 8.0 J ---
Selenium 6-Nov-08 3.8 10 ND 10.9 ---ND
3-Jun-09 3.8 10.0 ND ND ---ND
18-Nov-09 3.8 10.0 ND ND ---ND
NC 2B = 5 µg/l (05/01/07)15-Jun-10 3.8 10.0 ND ND --- ND
1-Dec-10 3.8 10.0 ND ND ---ND
1-Jun-11 3.8 10.0 ND ND ---ND
20-Dec-11 10.0 10.0 ND ND --- ND
30-May-12 10.0 10.0 ND ND ---ND
5-Dec-12 10.0 10.0 ND ND ---ND
12-Jun-13 10.0 10.0 ND ND --- ND
28-Oct-13 10.0 10.0 ND ND ---ND
6-May-14 10.0 10.0 ND ND --- ND
22-Oct-14 10.0 10.0 --- ND ND ND
21-May-15 5.0 10.0 ND ND ND ND
9-Dec-15 5.0 10.0 ND ND ND ND
NC 2B = 5 µg/l (03/01/16)4-May-16 5.0 10.0 ND ND ND ND
14-Dec-16 5.0 10.0 ND ND ND ND
28-Jun-17 5.0 10.0 ND ND ND ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 5 of 9
Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Silver 22-May-02 --- 10 16.0 B 15.0 B --- 15.0
14-Nov-02 --- 10 ND ND ---ND
14-May-03 --- 10 ND ND ---ND
20-Nov-03 --- 10 ND ND ---ND
6-May-04 --- 10 ND ND ---ND
10-Nov-04 --- 10 ND ND ---ND
5-May-05 --- 10 ND ND --- ND
3-Nov-05 --- 10 ND ND ---ND
25-May-06 --- 10 ND ND ---ND
2-Nov-06 --- 10 ND ND --- ND
30-May-07 --- 10 ND ND ---ND
29-Nov-07 --- 10 ND ND --- ND
29-May-08 0.10 10.0 0.29 J 0.13 J --- ND
6-Nov-08 0.10 10.0 0.72 B 0.38 B --- 0.23 J
3-Jun-09 0.10 10.0 0.18 B ND --- 0.31 J
18-Nov-09 0.10 10.0 0.27 B 0.23 B --- 0.23 J
NC 2B = 0.06 µg/l (05/01/07)15-Jun-10 0.10 10.0 ND ND ---ND
1-Dec-10 0.10 10.0 ND ND ---ND
1-Jun-11 0.10 10.0 ND 0.22 J --- ND
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 ND ND --- ND
12-Jun-13 5.0 10.0 ND ND ---ND
28-Oct-13 5.0 10.0 ND ND --- ND
6-May-14 5.0 10.0 ND ND --- ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 0.06 µg/l Chronic (03/01/16)*4-May-16 2.5 10.0 ND ND ND ND
14-Dec-16 2.5 10.0 ND ND ND ND
28-Jun-17 2.5 10.0 ND ND ND ---
Thallium 5-May-05 --- 10 22.0 11.0 --- ND
3-Nov-05 --- 10 20.0 ND ---ND
25-May-06 --- 10 ND ND ---ND
2-Nov-06 --- 10 ND ND --- ND
30-May-07 --- 5.5 0.053 J ND ---ND
29-Nov-07 --- 5.5 0.055 J ND ---ND
29-May-08 3.0 5.5 ND ND ---ND
6-Nov-08 3.0 5.5 ND ND ---ND
3-Jun-09 3.0 5.5 ND ND ---ND
18-Nov-09 3.0 5.5 ND ND ---4.2 J
NC 2B = NE (05/01/07)15-Jun-10 3.0 5.5 3.2 J ND ---ND
1-Dec-10 3.0 5.5 ND ND ---4.0 J
1-Jun-11 3.0 5.5 ND ND ---ND
20-Dec-11 5.4 5.5 ND ND ---ND
30-May-12 5.4 5.5 ND ND ---ND
5-Dec-12 5.4 5.5 ND ND ---ND
12-Jun-13 5.4 5.5 ND ND ---ND
28-Oct-13 5.4 5.5 ND ND ---ND
6-May-14 5.4 5.5 ND ND ---ND
22-Oct-14 5.4 5.5 --- ND ND ND
21-May-15 5.0 5.5 ND ND ND ND
9-Dec-15 5.0 5.5 ND ND ND ND
NC 2B = 0.24 (03/01/16)4-May-16 5.0 5.5 ND ND ND ND
14-Dec-16 5.0 5.5 ND ND ND ND
28-Jun-17 0.0 5.5 ND ND 0.044 J ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 6 of 9
Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Vanadium 6-Nov-08 0.20 25.0 0.90 B 8.9 B ---2.1 J
3-Jun-09 0.20 25.0 17.4 J 7.5 J ---1.0 J
18-Nov-09 0.20 25.0 0.26 B 0.30 B --- 0.56 J
NC 2B = NE (05/01/07)15-Jun-10 0.20 25.0 1.5 B 1.0 B --- 0.98 J
1-Dec-10 0.20 25.0 1.1 J 13.7 J --- ND
1-Jun-11 0.20 25.0 1.1 J 0.74 J --- ND
20-Dec-11 5.0 25.0 ND ND ---ND
30-May-12 5.0 25.0 ND ND ---ND
5-Dec-12 5.0 25.0 ND ND ---ND
12-Jun-13 5.0 25.0 7.6 J ND ---ND
28-Oct-13 5.0 25.0 ND ND --- ND
6-May-14 5.0 25.0 ND ND ---ND
22-Oct-14 5.0 25.0 --- ND ND ND
21-May-15 2.5 25.0 7.5 J ND 4.1 J ND
9-Dec-15 2.5 25.0 ND ND 3.9 J ND
4-May-16 2.5 25.0 10.9 J 11.4 J 23.9 J ND
14-Dec-16 2.5 25.0 ND ND ND ND
28-Jun-17 2.5 25.0 ND ND 3.1 J ---
Zinc 30-May-07 --- 10 1.8 B ND ---1.6 J
29-Nov-07 --- 10 9.6 B ND ---3.1 J
29-May-08 0.40 10.0 6.0 B ND ---3.0 J
6-Nov-08 0.40 10.0 0.82 B 1.4 B ---2.7 J
3-Jun-09 0.40 10.0 33.7 B 9.6 B --- 82.0
18-Nov-09 0.40 10.0 2.2 B 2.5 B ---3.1 J
NC 2B = 50 µg/l (05/01/07)15-Jun-10 0.40 10.0 ND ND ---ND
1-Dec-10 0.40 10.0 8.8 J 6.6 J --- 0.62 J
1-Jun-11 0.40 10.0 15.1 B 21.5 B --- 13.7
20-Dec-11 10.0 10.0 ND ND ---ND
30-May-12 10.0 10.0 ND ND ---ND
5-Dec-12 10.0 10.0 ND ND ---ND
12-Jun-13 10.0 10.0 ND ND --- 76.5
28-Oct-13 10.0 10.0 ND ND ---ND
6-May-14 10.0 10.0 ND ND ---ND
22-Oct-14 10.0 10.0 --- ND ND ND
21-May-15 5.0 10.0 ND 5.8 J ND ND
9-Dec-15 5.0 10.0 ND ND ND ND
NC 2B = 36 µg/l Acute, Chronic (03/01/16)* 4-May-16 5.0 10.0 8.7 J 7.7 J 15.2 ND
14-Dec-16 5.0 10.0 ND ND 6.9 J ND
28-Jun-17 5.0 10.0 5.8 J 17.4 39.4 ---
Hardness, Total (SM 2340B)28-Jun-17 662.00 662.0 32900 20900 10800 ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 7 of 9
Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Organic Compounds
Acetone 29-Nov-07 --- 100 3.6 B ND --- 5.1 J
29-May-08 20 100 ND ND --- ND
6-Nov-08 20 100 ND ND --- ND
3-Jun-09 2.2 100 5.7 J ND --- ND
18-Nov-09 2.2 100 ND ND --- ND
NC 2B = NE (05/01/07) 15-Jun-10 2.2 100 2.2 B 2.3 B --- 7.2 J
1-Dec-10 2.2 100 ND ND --- 3.7 J
1-Jun-11 2.2 100 5.4 B 2.9 B --- 3.9 J
20-Dec-11 2.2 100 ND ND --- ND
30-May-12 2.2 100 ND ND --- ND
5-Dec-12 10.0 100 ND ND --- ND
12-Jun-13 10.0 100 ND ND --- ND
28-Oct-13 10.0 100 ND ND --- ND
6-May-14 10.0 100 ND ND --- ND
22-Oct-14 10.0 100 --- ND ND ND
21-May-15 10.0 100 ND ND ND ND
9-Dec-15 10.0 100 ND ND ND ND
NC 2B = 1,100 mg/l (03/01/16) 4-May-16 10.0 100 ND ND ND ND
14-Dec-16 10.0 100 ND ND ND ND
28-Jun-17 10.0 100 14.7 J 29.4 J 18 J 35.3 J
Benzene 28-Jun-17 0.25 1.0 ND 0.59 J ND ---
Chloromethane 15-Jun-10 0.11 1.0 ND 0.11 J ---ND
NC 2B = NE (05/01/07)1-Dec-10 0.11 1.0 ND ND ---ND
1-Jun-11 0.11 1.0 ND ND ---ND
20-Dec-11 0.11 1.0 ND ND --- ND
30-May-12 0.11 1.0 ND ND --- ND
5-Dec-12 0.11 1.0 ND ND --- ND
12-Jun-13 0.11 1.0 ND ND --- ND
28-Oct-13 0.11 1.0 ND ND --- ND
6-May-14 0.11 1.0 ND ND --- ND
22-Oct-14 0.11 1.0 --- ND ND ND
21-May-15 0.11 1.0 ND ND ND ND
9-Dec-15 0.11 1.0 ND ND ND ND
NC 2B = NE (03/01/16)4-May-16 0.11 1.0 ND ND ND ND
14-Dec-16 0.11 1.0 ND ND ND 0.17 J
28-Jun-17 0.11 1.0 0.46 J 0.65 J 0.5 J ---
Trichloroethene 14-Dec-16 0.47 1.0 ND 0.52 J ND ND
28-Jun-17 0.47 1.0 ND 1.1 ND ---
NC 2B = 30 µg/l (03/01/16)
1,1-Dichloroethane 1-Jun-11 0.32 5.0 ND 0.41 J ---ND
NC 2B = NE (05/01/07)20-Dec-11 0.32 5.0 ND ND ---ND
30-May-12 0.32 5.0 ND ND ---ND
5-Dec-12 0.32 5.0 ND 1.6 J ---ND
12-Jun-13 0.32 5.0 ND ND ---ND
28-Oct-13 0.32 5.0 ND 0.96 J ---ND
6-May-14 0.32 5.0 ND ND ---ND
22-Oct-14 0.32 5.0 --- 1.5 J ND ND
21-May-15 0.32 5.0 ND ND ND ND
9-Dec-15 0.32 5.0 ND ND ND ND
NC 2B = 0.38 µg/l (03/01/16)4-May-16 0.32 5.0 ND ND ND ND
14-Dec-16 0.32 5.0 ND 2.6 J ND ND
28-Jun-17 0.32 5.0 ND 4.2 J ND ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 8 of 9
Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
cis-1,2-Dichloroethene 22-Oct-14 0.2 5.0 --- 0.20 J ND ND
NC 2B = NE (05/15/13)21-May-15 0.2 5.0 ND ND ND ND
9-Dec-15 0.2 5.0 ND ND ND ND
NC 2B = 60 µg/l (03/01/16)4-May-16 0.2 5.0 ND ND ND ND
14-Dec-16 0.2 5.0 ND 0.43 J ND ND
28-Jun-17 0.2 5.0 ND 1.10 J ND ---
Notes:
All concentrations in micrograms per liter (µg/l) = parts per billion.
RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006;
and SWSL for December 2006 - present).
DL = Laboratory Detection Limit.
NI = Monitoring well not yet installed.
AB = Monitoring well abandoned.
--- = Not sampled for this parameter or Not reported
ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006).
J = Estimated value - concentration is less than the RL but greater than the DL.
B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination based on
similar concentrations detected in field, trip, or method blanks).
D = Sample was diluted when analyzed.
NC 2B = Groundwater Standard from 15A NCAC 2B.
NE = No NC 2B established.
Values above the NC 2B Standard are bold.
Surface waters classified as WS-IV (water supply IV, highly developed), B (primary recreation, fresh water), and CA (critical area).
based on dissolved metal and in-stream water hardness results. Site specific values may be calculated based on water hardness at time of sampling.
*NC 2B Groundwater Standards and Protective Values updated March 2016 to include acute and chronic exposure levels for designated metals
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 9 of 9
Joyce Engineering