1203_Burke_ JohnsRiver_CDLF_MSWLF_WQMR_20171017

2211 West Meadowview Rd.
Greensboro, NC 27407

tel: [phone]
fax: [phone]
www.JoyceEngineering.com

October 24 2017

Jaclynne Drummond
Compliance Hydrogeologist
NC Department of Environmental Quality
Division of Waste Management - Solid Waste Section
2090 US Highway 70, Swannanoa, NC 28778

RE: Burke County, Johns River Landfill
Permit Number 12-03
Closed C&D-over-MSW Landfill
First Semiannual Water Quality Monitoring Report of 2017
JOYCE Project No. 277.1801.12, Task 03

Dear Ms. Drummond;

On behalf of Burke County, we are submitting the First Semiannual Water Quality
Monitoring Report of 2017 for the Closed C&D-over-MSW Landfill at the Johns River Waste
Management Facility, Permit # 12-03. If you have any questions or if we can provide any
additional information please call me at [phone]. Thank you.

Sincerely,
JOYCE ENGINEERING

Van Burbach, Ph.D., P.G.
Sr. Technical Consultant

Attachments:
NCDEQ EMRF
First Semiannual Water Quality Monitoring Report of 2017

cc: Miles Champion, Burke County

PREPARED FOR:
BOARD OF COMMISSIONERS
COUNTY OF BURKE
P.O. BOX 1486
MORGANTON, NORTH CAROLINA 28680

BURKE COUNTY
JOHNS RIVER WASTE MANAGEMENT FACILITY
C&D-OVER-MSW LANDFILL
PERMIT NO. 12-03

FIRST SEMIANNUAL WATER QUALITY
MONITORING REPORT OF 2017

OCTOBER 2017

PREPARED BY:

2211 WEST MEADOWVIEW ROAD, SUITE 101
GREENSBORO, NORTH CAROLINA 27407
NC LICENSE NUMBER C-0782
PHONE: [phone]
FAX: [phone]
JOYCE PROJECT NO. 277.1701.12

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River C&D Over MSW Landfill, Permit No. 12-03 October 2017
i
First Semiannual Water Quality Monitoring Report of 2017
Johns River Waste Management Facility – Permit No. 12-03
C&D-over-MSW Landfill
Burke County, North Carolina

TABLE OF CONTENTS

1.0 INTRODUCTION..............................................................................................................1 
1.1 Site Information ........................................................................................................................1 
1.2 Site Geology .............................................................................................................................1 
1.3 Regulatory Status .....................................................................................................................2 
1.4 Groundwater Monitoring History .............................................................................................2 
2.0 FACILITY MONITORING PROGRAM .......................................................................3 
2.1 Groundwater Monitoring Program ...........................................................................................3 
2.2 Surface Water Monitoring Program .........................................................................................6 
3.0 FIRST SEMIANNUAL SAMPLING EVENT OF 2017 ................................................6 
3.1 Field Work ................................................................................................................................6 
3.2 Laboratory Analysis and Quality Control ................................................................................7 
4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSIS .....................................8 
4.1 Analytical Results for Inorganic Constituents ..........................................................................8 
4.2 Analytical Results for Organic Constituents ............................................................................8 
4.3 Statistical Analyses ...................................................................................................................9 
4.3.1 Statistical Methods and Background ...................................................................... 9 
4.3.2 Statistical Analyses of Inorganic Constituents ....................................................... 9 
4.4 Analytical Results for Surface Water .....................................................................................10 
5.0 EVALUATION OF MONITORED NATURAL ATTENUATION (MNA) ..............10 
5.1 MNA Parameters and Biodegradation Screening Matrix .......................................................10 
5.2 Biochlor Modeling and Mass-Balance Assessment ...............................................................11 
5.3 Trend Analysis and Plume Stability .......................................................................................11 
6.0 HYDROGEOLOGICAL CONDITIONS ......................................................................12 
7.0 CONCLUSIONS ..............................................................................................................13 
8.0 REFERENCES .................................................................................................................13 
9.0 ACRONYMS ....................................................................................................................15 

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River C&D Over MSW Landfill, Permit No. 12-03 October 2017
ii

TABLE OF CONTENTS (CONTINUED)

Tables:
Table 1 Historical Groundwater Elevation Data
Table 2 Field Parameters Table 3 Quantified Detections in Groundwater and Surface Water
Table 4 Exceedances of Groundwater and Surface Water Standards Table 5 Statistical Background Analyses
Table 6 MNA Parameters
Table 7 Biodegradation Screening Matrix Table 8 Hydraulic Gradients and Groundwater Flow Velocities

Charts:
Chart 1 Benzene Concentrations vs. Time
Chart 2 1,4-Dichlorobenzene Concentrations vs. Time
Chart 3 1,1-Dichloroethane Concentrations vs. Time
Chart 4 1,2-Dichloroethane Concentrations vs. Time
Chart 5 Tetrachloroethylene (PCE) Concentrations vs. Time
Chart 6 Trichloroethylene (TCE) Concentrations vs. Time
Chart 7 Vinyl Chloride Concentrations vs. Time
Chart 8 Methylene Chloride Concentrations vs. Time
Chart 9 alpha-BHC Concentrations vs. Time
Chart 10 beta-BHC Concentrations vs. Time
Figure:
Figure 1 Site Location Map

Drawing:
Drawing 1 Groundwater Potentiometric Surface Map

Appendices:
Appendix A Field Data Logs
Appendix B Laboratory Analytical Reports
Appendix C Statistical Analyses Worksheets
Appendix D Historical Detected Inorganic Groundwater Constituents
Appendix E Historical Detected Organic Groundwater Constituents
Appendix F Historical Detected Constituents in Performance & Sentinel Wells
Appendix G Historical Detected Surface Water Constituents
Appendix H Historical MNA Parameters

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River C&D Over MSW Landfill, Permit No. 12-03 October 2017
1
1.0 INTRODUCTION
1.1 Site Information
The Johns River Waste Management Facility (JRWMF) is located in the north-central portion of
Burke County, north of Morganton, North Carolina. The 318-acre landfill property is bounded
by Lower Creek to the north and east, and the Catawba River to the south. The Catawba River
forms Lake Rhodhiss along the southeastern property line (Figure 1). Lake Rhodhiss is a long,
narrow lake formed by the Rhodhiss Hydroelectric Dam located approximately 12 miles
downstream of the landfill. The Johns River flows into the Catawba River near the southwest
corner of the landfill property.

The site has rolling topography with elevations ranging from 975 feet to 1,150 feet above mean
sea level (MSL). The central portion is generally gently sloping and contains the higher
elevations; relatively steep slopes and significant drainage features are located around the
perimeter. The 100-year flood boundary extends onto the landfill property. The adjacent
property to the west of the Johns River Waste Management Facility consists of undeveloped,
heavily wooded land. Properties within 2,000 feet of the landfill boundary are covered by
surface water or are heavily wooded.

The unlined waste disposal unit consists of 28 acres in the southwest corner of the landfill
property. The municipal solid waste (MSW) landfill began operation in April 1988, but was
closed to comply with Rule .1627(c)(10)(A) of the NCSWMR, a regulation governing MSW
Landfills units that were not designed with a base liner and leachate collection system. Burke
County has operated a permitted Construction and Demolition (C&D) disposal area on top of the
closed portions of the MSW landfill since 1998. A MSW transfer facility is located in the
eastern half of the property. In 2014, Phase 1A of the C&D expansion was constructed
northeast of the C&D over MSW landfill. Results of groundwater monitoring for Phase 1A will
be presented in a separate report. A site plan showing all the pertinent features of the facility is
provided in Drawing 1.

1.2 Site Geology
The Johns River Waste Management Facility is in close proximity to the Brevard Shear Zone,
and is underlain by highly metamorphosed rocks including gneiss, schist, as well as calc-silicate
rocks, felsic rocks, and metavolcanic rocks. The dominant rock type at the facility is biotite-
muscovite schist, as seen in outcrops, boulders, and rock cores located on site. The structures
within limited outcrops indicate that these rocks are complexly-folded, with attitudes that vary
from vertical to horizontal in most outcrops. The site regolith is typical of the inner piedmont
and consists mostly of silty sand, clayey sand, and sandy silt. The regolith is up to 100 feet thick
and varies in thickness with topography.

An abundance of rounded gravel, cobble, and boulder-sized alluvial deposits are exposed along
the banks of the Catawba River, which borders the site. The greatest accumulation of these
deposits is along the southwestern site boundary. These river deposits are 40 feet or more above
the current river elevation and have been described as ancient river terrace deposits.

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River C&D Over MSW Landfill, Permit No. 12-03 October 2017
2

1.3 Regulatory Status
The following report of groundwater monitoring data from the JRWMF has been prepared in
accordance with the North Carolina Solid Waste Management Rules (NCSWMR) 15A NCAC
13B §.1632 (Groundwater Sampling & Analysis Requirements) §.1633 (Detection Monitoring
Program), and §.1634 (Assessment Monitoring Program). The facility has operated under these
programs under the auspices the North Carolina Department of Environment and Natural
Resources (NCDENR), which is now the Department of Environmental Quality (NCDEQ). To
avoid confusion, NCDEQ will be used in reference to this department throughout this report
even in reference to past events or documents when it was the NCDENR.

The C&D over MSW landfill has been in the Assessment Monitoring Program since August
1995. In January 2000, Burke County submitted a Water Quality Assessment Report (WQAR),
for the landfill to the NCDEQ. The WQAR determined that the constituents-of-concern (COCs)
at the landfill were several volatile organic compounds (VOCs), specifically: benzene; 1,4-
dichlorobenzene; methylene chloride; tetrachloroethylene; and trichloroethylene.

The JRWMF entered the Corrective Action Program following the correspondence received
from the NCDEQ Solid Waste Section (SWS) dated August 18, 2003. An Assessment of
Corrective Measures (ACM) was submitted to NCDEQ in February 2005. A public meeting was
held on May 16, 2006 in order to receive public comments regarding the ACM as required by
NCSWMR §.1635 (d). A Corrective Action Plan (CAP) was submitted to NCDEQ in June 2008
and revised in November 2008. The CAP was approved by NCDEQ in a letter dated January 29,
2009. An addendum to the facility’s CAP was submitted to the NCDEQ in August 2013, adding
control of landfill gas as a remedy for groundwater impacts on the northeastern side of the
landfill between the old landfill and the new C&D expansion area.

1.4 Groundwater Monitoring History
 April 1988: Facility began operations as an MSW landfill.
 August 1995: Assessment Monitoring began.
 January 1998: Facility closed as an MSW landfill, but began operating a C&D landfill
on top of the former MSW landfill.
 January 2000: Water Quality Assessment Report (JOYCE, 2000).
 October 2004: Update on Water Quality Assessment Report (JOYCE, 2004).
 February 2005: Assessment of Corrective Measures (ACM) (JOYCE, 2005a) and
Quantitative Risk Assessment (JOYCE, 2005b).
 May 2006: Public Meeting for ACM.
 June 2008: Corrective Action Plan (CAP) submitted to NCDEQ-SWS.
 November 2008: CAP Revised per comments from NCDEQ-SWS & resubmitted.
 January 2009: CAP Approved by NCDEQ-SWS.
 June 2009: First Monitored Natural Attenuation (MNA) baseline sampling event.
 May 2011: First Corrective Action Evaluation Report (CAER).

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River C&D Over MSW Landfill, Permit No. 12-03 October 2017
3
 April 2012: Alternate Source Demonstration (ASD) for iron and manganese approved
by NCDEQ.
 August 2013: Addendum to the CAP to add control of landfill gas as a remedy.
 April 2016: Second Corrective Action Evaluation Report (CAER).

2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
Groundwater monitoring at the C&D over MSW landfill is performed in accordance with
NCSWMR §.1634, the site’s Transition Plan (JOYCE, April 1994), and the sites Corrective
Action Monitoring Plan (CAMP) (JOYCE, 2008, 2013) Groundwater samples are collected
semiannually and analyzed for constituents according to the sampling plan submitted to the SWS
on October 29, 1999 and subsequent documents. Following is a summary of the compliance
monitoring wells and other wells in the immediate vicinity of the landfill.

Well ID Date
Installed Classification Monitoring
Program
Total Depth
of Well (ft)
Lithology of
Screened
Interval
Constituent
List
MW-8 9-15-87 not used - 39.5 Saprolite -
MW-9 8-31-94 Abandoned/
Former Bkgnd. - - - -
MW-10 9-02-94 Compliance Assessment 23.0 Saprolite Comp.
MW-11 9-02-94 Compliance/
Performance
Assessment/
Cor. Act. 43.0 Saprolite Comp., MNA*
MW-12 9-01-94 Compliance/
Performance
Assessment/
Cor. Act. 51.5 Bedrock Comp., MNA*
MW-13 8-31-94 Compliance Assessment 58.0 Bedrock Comp.
MW-14 6-07-96 not used - 21.5 Saprolite -
MW-15S 6-04-96 not used - 54.0 Saprolite -
MW-15D 6-04-96 not used -118.5 Bedrock -
MW-16S 3-08-99 Compliance/
Performance
Assessment/
Cor. Act. 20.0 Saprolite Comp., MNA*
MW-16D 3-10-99 Compliance Detection 120.0 Bedrock Comp.
MW-17 3-08-99 Not used/
Former Bkgnd. - 52.0 Bedrock -
MW-18 4-07-09 Sentinel** Corrective
Action 12.0 Alluvial Soil COCs, MNA*
MW-19 4-07-09 Sentinel** Corrective
Action 13.0 Alluvial Soil COCs, MNA*
MW-20 5-18-95
Former Bkgnd./
Phase 1A
Compliance
Assessment 67.0 Saprolite Comp.
MW-21 5-18-95 Background Assessment/
Cor. Act. 45.0 Saprolite Comp., MNA*
MW-36 5-08-11 Performance*** Corrective
Action 43.0 Bedrock COCs, LFG
MW-38 5-09-11
Phase 1A
Compliance/
Performance***
Corrective
Action 71.0 Bedrock COCs, LFG

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River C&D Over MSW Landfill, Permit No. 12-03 October 2017
4
Notes: Comp. = Compliance Parameters: NCSWMR Appendix I and/or Appendix II organics and inorganics
plus C&D parameters, as required for routine assessment or detection monitoring.
COCs = Constituents of Concern.
MNA = Monitored Natural Attenuation Parameters: Temperature, pH, specific conductance, oxidation
reduction potential, dissolved oxygen, nitrate, sulfate, chloride, dissolved hydrogen, sulfide, alkalinity,
TOC, methane, ethane, ethene, volatile fatty acids, carbon dioxide, ferrous iron, and turbidity.
LFG = Landfill Gas Indicators: Dissolved CH4 and dissolved CO2.
* After the baseline period, the NCDEQ approved alternate frequencies for carbon dioxide, sulfide,
volatile fatty acids, ethane, and ethylene. These parameters will be monitored during both semiannual
events every third year.
** After the baseline period, sampling frequency for sentinel wells was changed to annual.
*** Performance wells (MW-36& MW-38) for the control of landfill gas remedy were added in the
August 2013 CAP Addendum. MW-38 is also a compliance well for Phase 1A.

The current compliance groundwater monitoring network at the facility consists of one
upgradient well (MW-21), and six downgradient wells (MW-10, MW-11, MW-12 MW-13,
MW-16S, and MW-16D). In March 1999, monitoring wells MW-16S and MW-16D were
installed as downgradient monitoring wells and well MW-17 was installed as a replacement for
upgradient background well MW-9. These wells were incorporated into the compliance
monitoring network during the second semiannual groundwater monitoring event of 2005 after
receiving approval from the SWS in a letter dated August 1, 2005. The letter also gave approval
to drop MW-9 from the compliance monitoring network. MW-9 was abandoned in July 2006.
There are several other monitoring wells at the facility (including MW-8, MW-14, MW-15S, and
MW-15D) and several piezometers that have been used in the past to collect groundwater data to
supplement the data from the compliance monitoring wells. Sentinel wells MW-18 and MW-19
were installed on April 7, 2009 in accordance with the facility’s Corrective Action Plan.

Due to organic detections in MW-17, a request was submitted in August 2010 to replace MW-17
with MW-20 as the facility background well. MW-20 (originally named PZ-4) was installed as a
piezometer in 1995 for site characterization. The NCDEQ-SWS requested that we sample both
MW-17 and MW-20 for the next 2 sampling events (November 2010 and June 2011), and then
submit a revised Water Quality Monitoring Plan to incorporate MW-20 into the compliance
network as the new background well. MW-20 served as the background well until August 2014
when the new Permit to Operate for Phase 1A C&D Landfill expansion was issued by the North
Carolina Department of Environment and Natural Resources. MW-20 was replaced by MW-21,
(formerly PZ-1). MW-21 will serve as the new background monitoring well for both Phase 1A
and the old C&D over MSW landfills. The former background well for the old C&D over MSW
landfill, MW-20, which is located side-gradient of and to the northeast of Phase 1A, will
continue to be sampled as a compliance well for Phase 1A.

The wells in assessment monitoring (MW-10, MW-11, MW-12, MW-13, MW-16S, and MW-20)
are analyzed for the NCSWMR Appendix I list of constituents plus additional detected Appendix
II constituents and additional required C&D parameters during the first semiannual event, and
for all constituents listed in NCSWMR Appendix II plus additional required C&D parameters
during the second semiannual monitoring event. Monitoring well MW-16D is analyzed for the

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River C&D Over MSW Landfill, Permit No. 12-03 October 2017
5
NCSWMR Appendix I plus additional required C&D parameters list during both events.
Monitoring wells MW-11, MW-12, MW-16S, and MW-21 are also sampled for MNA
parameters during each sampling event.

In accordance with the CAP for the facility, MNA baseline sampling was initiated with the June
2009 sampling event and continued through the November 2010 sampling event. The baseline
data were evaluated in a CAER dated May 2011. After reviewing the CAER, in a letter dated
July 12, 2011, the NCDEQ agreed to a reduced frequency for monitoring carbon dioxide, sulfide,
volatile fatty acids, ethane, and ethylene. These parameters will be sampled during both
semiannual sampling events every third year. The first and second semiannual events of 2016
are third year events sampling for the full MNA list.

A second CAER report for the facility dated April 2016 was submitted to DEQ concluding that
conditions at the landfill were relatively stable and corrective actions and monitoring were
adequate and would continue as they had been approved in The Corrective Action Monitoring
Plan (CAMP) for the facility. DEQ reviewed and approved the CAER as described in a letter
dated April 19, 2016.

The CAMP requires samples from sentinel wells MW-18 and MW-19 to be analyzed for the
facility’s Constituents of Concern (COC’s). The current COC list includes the following
constituents:
 Benzene;
 1,4-Dichlorobenzene;
 Methylene chloride;
 Tetrachloroethylene (PCE);
 Trichloroethylene (TCE);
 1,1-Dichloroethane;
 1,2-Dichloroethane;
 Vinyl chloride.
 alpha-BHC
 beta-BHC

After the 2011 CAER, the NCDEQ agreed that sentinel wells MW-18 and MW-19 need only be
sampled annually. MW-18 and MW-19 were last sampled during the May 2016 event. During
future events, MW-18 and MW-19 will be monitored for the above COC list plus required MNA
parameters annually.

An addendum to the facility’s CAP was submitted to the NCDEQ in August 2013, adding
control of landfill gas as a remedy for groundwater impacts on the northeastern side of the
landfill between the old landfill and the new C&D expansion area. In accordance with the CAP
addendum, piezometers PZ-36 and PZ-38 were converted to permanent monitoring wells
MW-36 and MW-38 to act as performance wells for the control of LFG remedy. MW-36 and
MW-38 are to be sampled semiannually for the current VOC COC list, plus dissolved methane
and dissolved carbon dioxide. MW-38 is also a compliance well for the Phase 1A C&D landfill.

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River C&D Over MSW Landfill, Permit No. 12-03 October 2017
6
2.2 Surface Water Monitoring Program
The current surface water monitoring points are SMP-5, SMP-6, and SMP-7. Surface water
monitoring point SMP-5 (located at the southwestern property line) and SMP-6 (located at the
southeastern property line) are both located downstream from existing sediment basins. Surface
water monitoring point SMP-7 is located downstream from the new Phase 1A expansion.
Surface water samples are analyzed for the NCSWMR Appendix I list of constituents plus
detected Appendix II constituents during both semiannual events.

Surface Point Classification Monitoring
Program Location
SMP-5 Compliance Surface Water Creek on west side of landfill,
downstream of sediment basin.
SMP-6 Compliance Surface Water Creek on east side of landfill,
downstream of sediment basin.
SMP-7 Compliance Surface Water
Creek southeast of Phase 1A
and east of sediment basin
SB-2A. Downstream of PZ-12.

3.0 FIRST SEMIANNUAL SAMPLING EVENT OF 2017
3.1 Field Work
In order to detect potential releases of leachate and/or landfill gas migration in a timely manner,
a visual inspection program has been implemented at the Johns River Waste Management
Facility. This inspection program involves field personnel making the following observations:
 Indications of stress on the biological community (e.g., dead or dying vegetation);
 Indications of leachate impact (e.g., seeps, impacted surface water);
 Observations of erosion;
 Condition of monitoring wells; and
 Negative changes around the waste facility.

On June 27-28, 2017, personnel from JOYCE visited Johns River Waste Management Facility to
purge and sample monitoring wells MW-10, MW-11, MW-12, MW-13, MW-16S, MW-16D,
MW-21, MW-36, and MW-38. Sentinel wells MW-18 and MW-19 were not sampled during the
June 2017 because we need to shift the annual sampling of these well to the 4th quarter event, to
correspond to the full Appendix II event, as originally intended. Surface monitoring points
SMP-5, SMP-6, and SMP-7 were also sampled during the June 2017 event.

Depth-to-water measurements were obtained to the nearest 0.01 foot using an electronic water
level indicator for all monitoring wells in the compliance network prior to purging. Current and
historical groundwater elevation data are presented in Table 1. Monitoring wells were purged
and sampled using disposable bailers. Measurements of temperature, pH, specific conductivity,
and turbidity were recorded in the site log book as well as on field data logs prior to purging,
after each purge volume, and during sampling. Field data logs for the June 2017 event are
provided in Appendix A. Field parameter data are presented in Table 2.

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River C&D Over MSW Landfill, Permit No. 12-03 October 2017
7

Laboratory-supplied containers were prepared and labeled (either by the laboratory or in the
field, as indicated) with the following information:
 Monitoring well number (completed by field personnel),
 Date and time of sample collection (completed by field personnel),
 Initials of sampling personnel (completed by field personnel),
 Project name and number (completed by the laboratory),
 Chemical preservative (completed by the laboratory); and
 Requested chemical analysis (completed by the laboratory).

Groundwater samples from each monitoring well were dispensed directly from the disposable
bailers into the provided laboratory containers either immediately after purging or within 24
hours of the final purge volume. Immediately after collection, the samples were placed in a
laboratory-provided cooler and chilled with ice.

Surface water samples were collected directly from stream flow by lowering the prepared sample
containers into the stream flow. Care was taken not the overflow the sample containers (which
could lead to preservative loss) and avoid sample-induced turbidity. At the time of sampling,
surface water was also measured for temperature, pH, specific conductivity, and turbidity and
recorded in the site log book. Immediately after sample collection, the samples were placed in a
laboratory-provided cooler and chilled on ice. Field data logs are provided in Appendix A.

Due a detection of vinyl chloride in MW-38 that was inconsistent with historical results, a
verification (resampling) event was conducted for MW-38 on August 8, 2017.

3.2 Laboratory Analysis and Quality Control
The June 2017 groundwater and surface water samples were submitted to Pace Analytical
Services, Inc. of Huntersville, North Carolina under chain-of-custody control for analysis. The
groundwater samples from the wells in assessment monitoring were analyzed for the NC
Appendix I list of constituents plus previously detected Appendix II constituents plus required
C&D parameters. Groundwater from MW-16D was analyzed for the NC Appendix I list of
constituents plus required C&D parameters. In addition, samples from corrective action wells
were analyzed for the COC list plus MNA or LFG parameters as described in Section 2.1.
Surface water samples were analyzed for the NC Appendix I list of constituents plus previously
detected Appendix II constituents. JOYCE requested a Level II data report for the final
laboratory report. The samples were received by the laboratory in good condition, properly
preserved, and within required hold times.

In addition to samples collected for compliance monitoring at the Johns River Waste
Management Facility, a Field Blank was collected by JOYCE personnel as part of the June 2017
sampling event. Also, a Trip Blank prepared by the laboratory accompanied the volatile
sampling containers from and to the laboratory. The Field Blank was analyzed for the same
parameters as the compliance wells in Assessment Monitoring and the Trip Blank was analyzed

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River C&D Over MSW Landfill, Permit No. 12-03 October 2017
8
for Appendix I list of constituents plus additional detected Appendix II volatile organic
compounds and tetrahydrofuran.

Upon receipt of the laboratory data package, JOYCE personnel reviewed the data package for
quality assurance/quality control (QA/QC) purposes and for possible regulatory issues. If any
QA/QC or regulatory issues were found, the laboratory would be contacted to resolve the issue,
and a resampling event might be scheduled, if needed. The laboratory analytical packages can
be found in Appendix B of this report. The data package was reviewed for the following:

 General typographical errors;
 Correct analyses performed and within method-specified hold times;
 Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate,
and Laboratory Control Samples;
 Blank-qualified data (B-flags);
 Detections exceeding the North Carolina 15A NCAC 2L .0202 Groundwater Standards
(NC2L), NCDEQ-SWS Groundwater Water Protection Standards (GWPS), and North
Carolina 15A NCAC 2B Surface Water Standards (NC2B); and
 Detections that are above historical levels.

4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSIS
4.1 Analytical Results for Inorganic Constituents
Five inorganic constitutes (barium, cobalt, iron, manganese, and zinc) were detected above the
SWSL in one or more monitoring wells during the June 2017 sampling event. Cobalt was
detected above the GWPS in all wells except MW-21. The cobalt detections were not above the
calculated background concentrations (see Section 4.3.2). Iron and manganese were in
exceedance of the NC2L Standards in all compliance wells with the exception of iron in
monitoring well MW-16D. An ASD was approved for iron and manganese by NCDEQ on April
12, 2012; therefore, these are not considered exceedances.

Table 3 presents the constituents with quantified detections during the June 2017 sampling event,
and Table 4 presents a summary of the exceedances of groundwater standards. Both tables
include the results from data qualification and laboratory confirmation re-analysis. In general, the
inorganic detections and concentrations are consistent with historical data. Historical data for
inorganic constituents are summarized in Appendix D.

4.2 Analytical Results for Organic Constituents
Thirteen organic constituents were detected above the SWSL in one or more monitoring wells
during the June 2017 sampling event. Nine of these detections were above an NC2L Standard or
GWPS, including benzene, 1,4-dichlorobenzene, 1,1-dichloroethane; 1,2-dichloroethane;
methylene chloride; trichloroethene; tetrachloroethene; vinyl chloride, and alpha-BHC; however,
the results of the August 2017 resampling event for MW-38 refuted the NC2L exceedance for
vinyl chloride. Table 3 presents the constituents with quantified detections during the June 2017

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River C&D Over MSW Landfill, Permit No. 12-03 October 2017
9
sampling event, and Table 4 presents a summary of the exceedances of groundwater standards.
In general, the detections and concentrations are consistent with historical data. Historical data
for organic constituents in compliance wells are summarized in Appendix E, and historical data
for organic constituents in performance and sentinel wells are summarized in Appendix F.

4.3 Statistical Analyses
4.3.1 Statistical Methods and Background
MW-9 was the facility background well from 1994 until May 2005, when it was abandoned.
MW-17 was the facility background well from May 1999 until June 2011. Both MW-9 and
MW-17 were sampled between May 1998 and May 2005. Due to gas related impacts to MW-17,
MW-20 became the facility background well in December 2010. Both MW-17 and MW-20
were sampled between December 2010 and June 2011. With the opening of Phase 1A of the
C&D expansion in August 2014, MW-21 (formerly PZ-1) became the facility background well
and MW-20 became a compliance well for Phase 1A.

Facility background data used to evaluate the December 2015 groundwater monitoring data
include all data collected for wells MW-9, MW-17, and MW-20 from September 1994 through
the May 2014 event plus the October 2014 through December 2015 data from MW-21.
Alternatively, intrawell statistics may be used to evaluate the statistical background for a specific
well. Data used for intrawell statistics will use all available data for that well, excluding the last
eight sampling events.

The background data for inorganic constituents were evaluated using the Shapiro-Wilk Test,
Parametric Prediction Limits, Parametric Tolerance Intervals, Aitchison’s Adjustment, Non-
Parametric Prediction Limits, and/or Poisson Prediction Limits as appropriate. Background data,
tests for normality, outliers, Aitchison’s adjustment, tolerance interval, or prediction limits are
used, as appropriate based on the background data. The statistical test by which downgradient
data are compared to facility background data is based upon the nature of the data and the
number of data values that are below the laboratory limit of detection. All statistical tests are
evaluated at the 0.05 level of significance, 95% confidence level, and are conducted as one-tailed
tests.

4.3.2 Statistical Analyses of Inorganic Constituents
The inorganic constituents detected at quantifiable concentrations (excluding blank-qualified
data) above the North Carolina SWSL in downgradient monitoring wells in the June 2017
sampling event were barium, cobalt, iron, manganese, mercury and zinc. Since barium, mercury
and zinc were not detected in exceedance of NC2L/GWPS, there is no need to calculate
statistical background for these constituents. Iron and manganese were addressed in an ASD
approved by NCDEQ in April 2012; therefore, we do not consider them to be exceedances.

Interwell statistics were used to a determine background value of 88.2 µg/l for cobalt. Using
intrawell statistics for MW-10, excluding the eight most recent sampling events, yields a

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River C&D Over MSW Landfill, Permit No. 12-03 October 2017
10
background for MW-10 of 271 µg/l. A summary of the statistical analyses is presented in Table
5, and the detailed statistical analyses worksheets are included in Appendix C.

Since the background concentrations of cobalt are greater than their respective GWPS, we
request that the background values be considered the applicable GPS for these constituents per
rule .1634(g)(5) of the NCSWMR. If this request is not approved by NCDEQ, cobalt may need
to be added to the facility’s COC list.

4.4 Analytical Results for Surface Water
Surface monitoring points SMP-5, SMP-6, and SMP-7 were sampled during the June 2017 event.
Zinc was detected above the SWSL in surface water samples SMP-6 and SMP-7. The
concentration of zinc in SMP-7 (39.4 µg/l) was above the NC2B Standard (36 µg/l).
Trichloroethene was detected above the SWSL in SMP-6; however, it was not in exceedance of
the NC2B Standard. There were no other quantified detections above SWSL in any of the
surface water samples. Current and historical surface water data can be found in Appendix G.

5.0 EVALUATION OF MONITORED NATURAL ATTENUATION (MNA)
5.1 MNA Parameters and Biodegradation Screening Matrix
In accordance with the CAP for the facility, MNA baseline sampling was initiated with the June
2009 sampling event and continued through the November 2010 sampling event. The baseline
data were evaluated in a CAER dated May 2011. MNA parameter data were obtained for the
following wells: the site background well (MW-21); and downgradient compliance/performance
wells MW-11, MW-12, and MW-16S. MNA field parameters included temperature, pH, specific
conductance, oxidation-reduction potential (ORP), turbidity, dissolved oxygen, dissolved carbon
dioxide and ferrous iron. MNA laboratory parameters included dissolved hydrogen, alkalinity,
TOC, dissolved methane, nitrate, sulfate, and chloride. Table 6 summarizes the MNA data for
the June 2017 event, and historical MNA data are presented in Appendix H. Field data logs and
laboratory reports are included in Appendices A and B, respectively.

The MNA parameter data were evaluated in general accordance with the United States
Environmental Protection Agency’s (EPA’s) Technical Protocol Manual (EPA, 1998) to
determine whether the conditions are conducive to, or whether there is evidence for anaerobic
degradation of the chlorinated hydrocarbons. Specifically, the results were evaluated according
to the weighted system presented in Table 2.3 of the Technical Protocol Manual, referred to
hereafter as the Biodegradation Screening Matrix. According to this manual, a score less than 5
indicates that there is inadequate evidence for anaerobic natural attenuation, a score of 6 to 14
indicates that there is limited evidence for anaerobic natural attenuation, a score of 15 to 20
indicates that there is adequate evidence for anaerobic natural attenuation, and a score greater
than 20 indicates that there is strong evidence that anaerobic natural attenuation is occurring.

MNA evaluation was performed based on the results from the June 2017 sampling event for
downgradient wells within the contaminant plume, compared where appropriate to the

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River C&D Over MSW Landfill, Permit No. 12-03 October 2017
11
background well (MW-21). The Biodegradation Screening Matrix is presented in Table 7 of this
report.

One difficulty in evaluation of the Screening Matrix is that the matrix assumes some compounds
(such as, but not limited to methane and vinyl chloride) are daughter products of biodegradation
within the plume; however, at a landfill we cannot eliminate the possibility that they may be
contaminants released directly from the landfill. If we include the scores for these potential
daughter products, our total score could be artificially high; on the other hand, if we exclude
them, the score might be artificially low. Table 7 presents scoring results both with and without
the questionable daughter product scores.

The following table summarizes the scoring results from Table 7 for both options for interpreting
the data. The scores ranged from 14 (limited evidence of natural attenuation) to 30 (strong
evidence of natural attenuation). In reality, the best score is probably in the middle of this range,
indicating good evidence of natural attenuation.

DP = Points for possible daughter products.

5.2 Biochlor Modeling and Mass-Balance Assessment
Biochlor modeling is performed annually for this facility. The next Biochlor modeling will be
conducted with the 4th Quarter 2017 event, which will include the full Appendix II monitoring
results as well as results for sentinel wells MW-18 and MW-19.

5.3 Trend Analysis and Plume Stability
Charts 1-10 show the concentrations of key constituents versus time for the wells MW-10,
MW-11, MW-12, MW-13, and MW-16S from the earliest recorded detections through June
2017. In general, most constituents in most wells show decreasing or stable trends, especially
over the last 3-5 years. One of the clearest long-term increasing trends is for benzene in MW-13;
however, the benzene trend appears to have stabilized in the last few years. 1,4-dichlorobenzene
also shows a clear upward trend in MW-13. MW-13 is located farther north (upgradient) than
the other downgradient wells and is representative of the central part of the plume, whereas
MW-11, MW-12, and MW-16S are located nearer the southern leading edge of the plume and
MW-10 is located near the western edge of the plume. The fact that the concentrations in the
central part of the plume appear to be stable or increasing while the concentrations near the
leading edge seem to be stable or decreasing supports the contention that natural attenuation is
adequately controlling the plume.

Alpha-BHC has had sporadic detections in MW-13 over the last few sampling events. There
appears to be a seasonal component to the data trend, with detections occurring in the fall or
winter. There also appears to be a seasonal component to the pattern of detection of beta-BHC in
Points Awarded
including DP
Points Awarded
excluding DP
Points Awarded
excluding HD 30 14

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River C&D Over MSW Landfill, Permit No. 12-03 October 2017
12
MW-11, which was not detected during the June 2017 event. There may be slight downward
trends for both alpha-BHC and beta-BHC; however, the data are too sporadic to be certain.

6.0 HYDROGEOLOGICAL CONDITIONS
Based on outcrop and drilling information, the water table appears to occur within regolith
everywhere across the site. This regolith consists of alluvium, residual soils, saprolite, and
variably fractured and weathered layered metamorphic rock. Inspection of drill cuttings and site
outcrops indicates that water in the regolith is transmitted largely through fractures. In this
regard, regolith behaves similar to unweathered bedrock, except that fractures are more
numerous and better connected in the regolith, and will tend to have more isotropic hydraulic
properties. Along the low-lying areas of the Catawba River and its tributaries, the water table
occurs within surficial alluvial deposits overlying the residual soils and weathered bedrock.

Groundwater discharges into creeks to the east and west of the landfill and to the Catawba River
to the south. A groundwater potentiometric surface map, developed from static water level data
obtained in June 2017, is presented as Drawing 1. The potentiometric surface map depicts
groundwater flow primarily to the south.

Depth to groundwater was measured in the compliance monitoring wells at the site prior to
sampling. The June 2017 and historical groundwater elevations are provided in Table 1. The
groundwater elevations were calculated relative to the surveyed measuring point (top of casing)
for each monitoring well. Horizontal groundwater gradients along representative flow paths
were estimated from the June 2017 groundwater contours shown on Drawing 1 and calculated
gradients and flow velocities are summarized in Table 8. Horizontal gradients across the site
ranged from 0.0367 to 0.0521 ft/ft, with an average of approximately 0.0450 ft/ft. This is
consistent with previous estimates.

Linear groundwater flow velocities for wells screened in saprolite were computed using the
modified Darcy equation: V = Ki/ne, where V = average linear velocity, K = hydraulic
conductivity, i = horizontal hydraulic gradient, and ne = effective porosity. The mean of
hydraulic conductivities from slug-tests conducted in 1995 and 2015 (K = 3.28 ft/day) was used
in these calculations, along with an estimated effective porosity of ne = 0.40 (40%) for saprolite
based on laboratory porosities for soil samples from the site.

The estimated linear groundwater flow velocity under the facility ranged from 110-156 feet/year,
with an average flow velocity of approximately 135 feet/year for the site (Table 8), or 137
feet/year under the C&D-over-MSWLF cells based on flow lines i1 and i2 only. The modified
Darcy equation makes the simplifying assumptions of a homogeneous and isotropic aquifer,
which may yield inaccurate results when applied to heterogeneous and/or anisotropic conditions
such as are believed to exist at this site.

The groundwater flow direction and rate have shown no significant seasonal variations over
several years of monitoring. The groundwater flow regime on this site is well constrained and
predictable. Migration of groundwater contaminants are expected to follow the general

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River C&D Over MSW Landfill, Permit No. 12-03 October 2017
13
groundwater flow paths and there are no known preferred pathways or barriers to groundwater
flow that could significantly affect plume migration or the effectiveness of the groundwater
monitoring network to monitoring plume migration. The current groundwater monitoring
network remains sufficient for monitoring the groundwater at this facility.

7.0 CONCLUSIONS
There were several organic constituents detected above the NC2L Groundwater Standards at the
Johns River Landfill during the June 2017 sampling event. These results are generally consistent
with previous sampling events and are being addressed by the Corrective Action Plan for the
facility.

Evaluation of MNA data and trends of key constituents all indicate that natural attenuation is
actively occurring on the site and that it is adequately controlling the constituent plume.

Cobalt was detected above the GWPS; however it was not detected above the calculated
background concentrations; therefore, we request that the background be considered ground
water protection standards for cobalt per rule .1635 (g) of the NCSWMR. If this request is not
approved by NCDEQ, cobalt may need to be added to the facility’s COC list.

An ASD was approved for iron and manganese by NCDEQ on April 12, 2012. The inorganic
results from the June 2017 monitoring event are consistent with historical data.

Zinc was detected above the NC2B Standard in surface water sample SMP-7. If zinc remains
elevated in SMP-7 during future sampling events, we recommend sampling SMP-7 for dissolved
metals and total dissolved solids (TDS). There were no other organic or inorganic detections
above the NC2B Surface Water Standards for surface water samples from the June 2017
sampling event.

The groundwater flow regime is consistent with previous events and the groundwater monitoring
network remains adequate to monitor the site. Based on approval of the 2016 CAER by DEQ
and the analytical results from the June 2017 sampling event, The Johns River Solid Waste
Management Facility will remain in Assessment Monitoring and Corrective Action. The next
semiannual sampling event is scheduled for December of 2017.

8.0 REFERENCES
Hinchee, R.E., A. Leeson, L. Semprini, and S.K. Ong. 1994. Bioremediation of Chlorinated and
Polycyclic Aromatic Hydrocarbon Compounds. Lewis Publishers, Boca Raton.

Interstate Technology and Regulatory Cooperation Work Group (ITRC). September 1999.
Natural Attenuation of Chlorinated Solvents in Groundwater: Principles and Practices.
Technical/Regulatory Guidelines.

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River C&D Over MSW Landfill, Permit No. 12-03 October 2017
14
Interstate Technical Regulatory Council (ITRC). 2003. Technical and Regulatory Guidance
Document for Constucted Treatment Wetlands.

Joyce Engineering (JOYCE), 1994. Transition Plan, Johns River Waste Management Facility.
April 1994.

JOYCE, 2000. Water Quality Assessment Report, Johns River Waste Management Facility.
January 2000.

JOYCE, 2004. Update on Groundwater Assessment Activities, Johns River Waste Management
Facility. October 2004.

JOYCE, 2005a. Assessment of Corrective Measures Report, Johns River Waste Management
Facility. February 2005.

JOYCE, 2005b. Quantitative Risk Assessment, Johns River Waste Management Facility.
February 2005.

JOYCE, 2008. Corrective Action Plan, Johns River Waste Management Facility. June 2008.

JOYCE, 2011. Corrective Action Evaluation Report, Johns River Waste Management Facility.
May 2011.

JOYCE, 2013. Addendum to the Corrective Action Plan, Johns River Waste Management
Facility. August 2013.

National Research Council (NRC), 2000. Natural Attenuation for Groundwater Remediation.
National Academy Press, Washington, D.C. pp. 108-111.

North Carolina Department of Environmental Quality (NCDEQ), 1997. North Carolina Solid
Waste Management Rules. 15 NCAC 13B. January 1, 1997.

NCDEQ, 2007. North Carolina Solid Waste Section Guidelines for Corrective Action at Solid
Waste Management Facilities. March 2007.

Sumsion, C.T., and Laney, R.L., 1967, Geology and Ground-water Resources of the Morganton
area North Carolina. N.C. Department of Water Resources, Ground Water Bulletin No.
12, 119 p.

U.S. Department of Energy (USDE). May 1999. Decision-Making Framework Guide for the
Evaluation and Selection of Monitored Natural Attenuation Remedies at Department of
Energy Sites.

U.S. Environmental Protection Agency (USEPA), 1992. Statistical Analysis of Groundwater
Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance. July 1992.

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River C&D Over MSW Landfill, Permit No. 12-03 October 2017
15

USEPA. October 1988. Interim Final Guidance for Conducting Remedial Investigations and
Feasibility Studies under CERCLA. Office of Solid Waste and Emergency Response
(OSWER) Directive 9355.3-01, EPA/540/G-89/004.

USEPA. February 1991. Conducting Remedial Investigations/Feasibility Studies for CERCLA
Municipal Landfill Sites. OSWER Directive 9355.3-11, EPA/540/P-91/001.

USEPA. May 1995. How to Evaluate Alternative Cleanup Technologies for Underground
Storage Tank Sites: A Guide for Corrective Action Plan Reviewers. Chapters 2 (Soil
Vapor Extraction) and 10 (In-Situ Groundwater Bioremediation).

USEPA. May 1996. Seminars on Bioremediation of Hazardous Waste Sites: Practical
Approaches to Implementation. ORD,EPA/625/K-96/001. Chapters 15 (Natural
Attenuation of Groundwater) and 17 (Natural Attenuation of Landfills).

USEPA and U.S. Air Force (USAF). July 1993. Remediation Technologies Screening Matrix
Reference Guide, Version I. Joint Project of OSWER and Environics Directorate, PB93-
2118212.

9.0 ACRONYMS
ACM Assessment of Corrective Measures (Report)
AMSL Above Mean Sea Level
AOC Area of Concern
BGS Below Ground Surface
C&D Construction and Demolition Waste
CAP Corrective Action Plan (Report)
CAER Corrective Action Evaluation Report (Report)
CAMP Corrective Action Monitoring Plan (Report)
CAS Chemical Abstracts Service
CFR Code of Federal Regulations
CPVC Chlorinated Poly Vinyl Chloride
COC Contaminant of Concern (for corrective action)
COC Chain of Custody (for sampling and lab reports)
DL Detection Limit (for laboratory data)
DO Dissolved Oxygen
EPA United States Environmental Protection Agency (or USEPA)
GWPS Groundwater Protection Standards (Established by NCDEQ-SWS)
JOYCE Joyce Engineering
LFG Landfill Gas
MNA Monitored Natural Attenuation
MSW Municipal Solid Waste
MW Monitoring Well
NC2B North Carolina Surface Water Standards found in 15A NCAC 2B

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Burke County – Johns River C&D Over MSW Landfill, Permit No. 12-03 October 2017
16
NC2L North Carolina Groundwater Standards found in 15A NCAC 2L
NCAC North Carolina Administrative Code
NCDENR North Carolina Dept. of Environment and Natural Resources (now the NCDEQ)
NCDEQ North Carolina Dept. of Environmental Quality (formerly the NCDENR)
NCGS North Carolina Geological Survey
NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600)
ND Not Detected (for laboratory data)
NES Nature and Extent Study (Report)
O&M Operations and Maintenance
QL Quantitation Limit (for laboratory data)
QRA Quantitative Risk Assessment (Report)
RL Reporting Limit (for laboratory data)
RQD Rock Quality Designation
SPT Standard Penetration Test
SSI Statistically Significant Increase (above background concentrations)
SWQS Surface Water Quality Standards
SWS Solid Waste Section (of NCDEQ-Division of Waste Management)
SWSL North Carolina Solid Waste Section Reporting Limits
TOC Top of Casing (Well)
USCS Unified Soil Classification System
USEPA United States Environmental Protection Agency (or EPA)
USGS United States Geological Survey
VOC Volatile Organic Compound
WQMP Water Quality Monitoring Plan (Report)

TABLES

Table 1 Historical Groundwater Elevation Data
Table 2 Field Parameters (June 2017)
Table 3 Quantified Detections of Groundwater Constituents (June 2017)
Table 4 Exceedances of Groundwater Standards (June 2017)
Table 5 Statistical Background Analyses Table 6 MNA Parameters (June 2017)
Table 7 Biodegradation Screening Matrix
Table 8 Hydraulic Gradients and Groundwater Flow Velocities

TABLE 1: HISTORICAL GROUNDWATER ELEVATIONSMW-9 MW-17 MW-20 MW-21 MW-8 MW-10 MW-11 MW-12 MW-13 MW-14 MW-15S MW-15D MW-16S MW-16D MW-18 MW-19 MW-36 MW-38TOC Elevation1145.97 1121.77 1115.04 1099.86 1072.55 1012.23 1028.58 1034.22 1059.40 1017.96 1069.04 1069.06 1007.67 1007.87 998.49 999.95 1099.52 1087.76Well Depth67.63 43.35 67.00 41.00 39.35 24.16 44.20 53.00 59.00 23.20 56.16 121.39 21.45 90.50 12.00 15.00 45.00 73.13Jul-951089.48 NI NM NM 1040.88 998.40 994.13 993.65 1009.67 NI NI NI NI NI NI NI NI NISep-951090.60 NI NM NM 1040.80 997.73 993.10 993.54 1008.88 NI NI NI NI NI NI NI NI NIOct-951090.32 NI NM NM 1041.16 998.75 994.38 994.32 1009.46 NI NI NI NI NI NI NI NI NIApr-961090.66 NI NM NM 1041.08 998.78 993.30 993.84 1010.40 NI NI NI NI NI NI NI NI NIJun-961089.40 NI NM NM 1040.78 998.41 992.80 994.50 1010.03 1007.01 1022.70 1023.38 NI NI NI NI NI NIDec-961087.28 NI NM NM NM NM NM 994.66 1009.17 1007.14 1021.30 1021.80 NI NI NI NI NI NIMay-971087.07 NI NM NM NM 998.66 993.04 993.54 1009.52 NM NM NM NI NI NI NI NI NINov-971091.49 NI NM NM NM 999.00 993.58 993.98 1010.40 NM NM NM NI NI NI NI NI NIMay-981090.97 NI NM NM NM 999.08 993.58 994.52 1011.57 NM NM NM NI NI NI NI NI NINov-981086.65 NI NM NM NM 998.66 992.83 993.42 1010.01 NM NM NM NI NI NI NI NI NIApr-991086.35 NM NM NM 1039.87 998.19 992.73 993.121009.40 NM 1023.26 1023.40 NM NM NI NI NI NIMay-991087.70 NM NM NM NM 998.98 1003.35 993.78 1010.54 NM NM NM NM NM NI NI NI NIOct-991085.87 1079.43 NM NM NM 998.84 992.86 993.43 1009.65 NM NM NM 992.15 993.94 NI NI NI NIMay-001085.09 1076.55 NM NM NM 999.38 993.71 994.01 1009.75 NM NM NM 992.59 994.09 NI NI NI NINov-001085.22 1076.60 NM NM NM 998.60 992.21 992.46 1008.89 NM NM NM 991.07 992.62 NI NI NI NIMay-011085.76 1077.06 NM NM NM 997.85 992.75 993.41 1009.62 NM NM NM 992.07 993.59 NI NI NI NINov-011085.84 1079.07 NM NM NM 998.43 992.22 992.90 1008.79 NM NM NM 991.36 992.84 NI NI NI NIMay-021086.29 1080.36 NM NM NM 998.58 992.83 993.48 1009.50 NM 1021.94 1022.30 992.02 993.47 NI NI NI NINov-021085.19 1079.71 NM NM NM 999.04 993.63 993.93 1009.24 NM 1021.25 1021.59 992.66 993.60 NI NI NI NIMay-031094.25 1092.35 NM NM NM 999.53 994.16 994.96 1012.95 NM NM NM 993.03 994.22 NI NI NI NINov-031089.49 1087.02 NM NM 1041.05 999.43 993.78 994.67 1011.60 1008.06 1027.08 1028.29 992.84 994.19 NI NI NI NIMay-041086.81 1082.54 NM NM 1040.28 999.22 993.25 993.85 1011.40 1007.96 1025.71 1026.59 992.18 993.87 NI NI NI NINov-041085.92 1080.38 NM NM NM 999.26 993.58 993.72 1010.78 NM NM NM 992.57 993.67 NI NI NI NIMay-051087.82 1083.35 NM NM NM 999.01 993.17 993.87 1011.26 NM NM NM 992.30 993.72 NI NI NI NINov-05AB 1082.66 NM NM NM 998.91 992.76 993.50 1010.59 NM NM NM 991.92 993.19 NI NI NI NI25-May-06AB 1081.13 NM NM NM 998.79 992.89 993.52 1010.48 NM NM NM 991.97 993.42 NI NI NI NI01-Nov-06AB 1081.19 NM NM NM 999.35 993.42 994.02 1010.58 1008.46 1023.28 NM 992.59 993.73 NI NI NI NI30-May-07AB 1083.42 NM NM NM 998.89 992.65 993.42 1010.80 NM NM NM 991.84 993.47 NI NI NI NI02-Aug-07AB NM NM NM NM NM NM NM NM NM NM NM NM 993.28 NI NI NI NI28-Nov-07AB 1077.85 NM NM NM 998.02 989.46 990.52 1009.01 NM NM NM 988.84 990.30 NI NI NI NI29-May-08AB 1078.52 NM NM NM 998.64 992.50 993.22 1010.02 NM NM NM 991.74 993.13 NI NI NI NI06-Nov-08AB 1078.77 NM NM NM 998.83 993.36 993.78 1009.10 NM NM NM 992.42 993.67 NI NI NI NI02-Jun-09AB 1083.33 NM NM NM 1000.63 994.17 994.86 1011.20 NM NM NM 993.89 994.70 993.48 994.75 NI NI16-Nov-09AB 1082.29 NM NM NM 999.60 994.43 994.98 1010.43 NM NM NM 993.53 1004.56 994.28 993.69 NI NI15-Jun-10AB 1084.81 NM NM NM 999.09 992.90 993.71 1011.32 NMNM NM 992.10 993.56 992.67 992.60 NI NI30-Nov-10AB 1079.76 1056.10 NM NM 999.24 993.14 993.56 1010.25 NM NM NM 992.25 992.90 992.14 992.13 NI NI01-Jun-11AB 1080.66 1053.93 NM NM 999.22 993.36 993.92 1010.62 NM NM NM 992.48 993.74 992.98 992.81 NM NM20-Dec-11AB 1077.47 1052.27 NM NM 999.27 993.66 994.00 1009.56 NM NM NM 992.67 993.88 NM NM NM NM30-May-12AB NM 1052.63 NM NM 1000.32 993.37 993.93 1009.52 NM NM NM 992.46 993.76 993.09 993.15 NM NM11-Dec-12AB NM 1053.51 NM NM 999.04 992.94 993.46 1009.52 NM NM NM 992.05 993.43 NM NM NM NM11-Jun-13AB NM 1055.80 NM NM 1001.25 996.39 996.60 1011.00 NM NM NM 995.47 996.51 NM NM NM NM28-Oct-13AB NM 1060.44 NM NM 999.42 993.13 993.80 1010.68 NM NM NM 992.55 993.72 993.63 992.95 NM NM06-May-14AB NM 1058.24 NM NM 999.71 990.63 994.22 1010.84 NM NM NM 992.73 994.02 993.31 993.17 1069.17 1042.1821-Oct-14AB NM 1056.42 1063.48 NM 999.49 993.93 994.27 1009.98NM 1024.64 NM 992.97 994.40 NM NM 1066.52 1045.1821-May-15AB NM 1053.69 1062.18 NM 999.22 993.03 993.62 1010.18 NM1025.17 NM 992.11 993.36 992.54 992.60 1066.03 1044.6808-Dec-15AB NM 1051.65 1061.71 NM 999.49 992.25 993.42 1009.64NM 1025.19 NM 994.47 995.17 NM NM 1066.72 1046.2404-May-16AB NM 1056.81 1065.36 1041.51 998.98 993.73 993.22 1009.66 NM 1026.24 NM 992.97994.42 992.74 993.45 1071.22 1044.9113-Dec-16AB NM 1051.66 1061.11 1041.18 998.88 992.90 993.47 1007.90 NM 1022.89 NM 992.08 993.42 NM NM 1065.99 1042.8128-Jun-17AB NM 1050.54 1061.51 1040.99 999.55 992.87 993.13 1009.84 NM 1024.79992.82 994.07 NM NM 1065.77 1044.86 Notes:All elevations are in feet above mean sea level. NI = Monitoring well not yet installed. NM = Groundwater level not measured. AB = Monitoring well abandoned.LocationDowngradientBackgroundPerformanceSentinelBurke Co. - Johns River C+D-over-MSWLFPermit 12-03Joyce Engineering
TABLE 2: FIELD PARAMETERS
WELL ID PARAMETER RESULT UNITS COLLECT DATE
MW-10 pH 5.93 S.U. 6/27/2017
MW-10 Temperature 17.8 ºC 6/27/2017
MW-10 Turbidity 9.65 NTU 6/27/2017
MW-10 Conductivity 254.7 µS 6/27/2017
MW-10 Static Water Level 12.68 ft 6/27/2017
MW-10 Well Depth 24.16 ft 6/27/2017
MW-11 pH 6.06 S.U. 6/27/2017
MW-11 Temperature 16.8 ºC 6/27/2017
MW-11 Turbidity 7.29 NTU 6/27/2017
MW-11 ORP 5.3 mV 6/27/2017
MW-11 DO 2.40 mg/l 6/27/2017
MW-11 Ferrous Iron 4 mg/l 6/27/2017
MW-11 Conductivity 450.1 µS 6/27/2017
MW-11 Static Water Level 35.71 ft 6/27/2017
MW-11 Well Depth 44.20 ft 6/27/2017
MW-12 pH 5.99 S.U. 6/27/2017
MW-12 Temperature 17 ºC 6/27/2017
MW-12 Conductivity 234.6 µS 6/27/2017
MW-12 ORP 10.7 mV 6/27/2017
MW-12 DO 4.75 mg/l 6/27/2017
MW-12 Ferrous Iron 0.5 mg/l 6/27/2017
MW-12 Turbidity 9.78 NTU 6/27/2017
MW-12 Static Water Level 41.09 ft 6/27/2017
MW-12 Well Depth 53.00 ft 6/27/2017
MW-13 pH 4.94 S.U. 6/27/2017
MW-13 Temperature 16.1 ºC 6/27/2017
MW-13 Conductivity 33.8 µS 6/27/2017
MW-13 Turbidity 9.58 NTU 6/27/2017
MW-13 Static Water Level 49.56 ft 6/27/2017
MW-13 Well Depth 59.00 ft 6/27/2017
MW-16S pH 5.95 S.U. 6/27/2017
MW-16S Temperature 16.8 ºC 6/27/2017
MW-16S Conductivity 226.1 µS 6/27/2017
MW-16S Turbidity 11.6 NTU 6/27/2017
MW-16S ORP 20.5 mV 6/27/2017
MW-16S Ferrous Iron 1.5 mg/l 6/27/2017
MW-16S DO 2.16 mg/l 6/27/2017
MW-16S Static Water Level 14.85 ft 6/27/2017
MW-16S Well Depth 21.45 ft 6/27/2017
Burke Co. - Johns River C+D-over-MSWLF
Permit No. 12-03
1 of 3
Joyce Engineering
TABLE 2: FIELD PARAMETERS
WELL ID PARAMETER RESULT UNITS COLLECT DATE
MW-16D pH 8.88 S.U. 6/27/2017
MW-16D Temperature 16.4 ºC 6/27/2017
MW-16D Turbidity 6.19 NTU 6/27/2017
MW-16D Conductivity 95.7 µS 6/27/2017
MW-16D Static Water Level 13.80 ft 6/27/2017
MW-16D Well Depth 90.50 ft 6/27/2017
MW-15S pH 5.31 S.U. 6/27/2017
MW-15S Temperature 16 ºC 6/27/2017
MW-15S Turbidity 8.95 NTU 6/27/2017
MW-15S Conductivity 45.6 µS 6/27/2017
MW-15S Static Water Level 44.25 ft 6/27/2017
MW-15S Well Depth 58.27 ft 6/27/2017
MW-21 pH 6.45 S.U. 6/27/2017
MW-21 Temperature 15.0 ºC 6/27/2017
MW-21 Turbidity 15 NTU 6/27/2017
MW-21 Conductivity 20.9 µS 6/27/2017
MW-21 Dissolved Oxygen 7.06 mg/l 6/27/2017
MW-21 Oxygen Reduction Potential 184.2 mV 6/27/2017
MW-21 Ferrous Iron 1.0 mg/l 6/27/2017
MW-21 Static Water Level 38.35 ft 6/27/2017
MW-21 Well Depth 46.80 ft 6/27/2017
MW-36 pH 6.22 S.U. 6/27/2017
MW-36 Temperature 16.8 ºC 6/27/2017
MW-36 Turbidity 11.6 NTU 6/27/2017
MW-36 Conductivity 268.3 µS 6/27/2017
MW-36 Static Water Level 33.75 ft 6/27/2017
MW-36 Well Depth 45.58 ft 6/27/2017
MW-38 pH 6.36 S.U. 6/27/2017
MW-38 Temperature 17.9 ºC 6/27/2017
MW-38 Turbidity 11.25 NTU 6/27/2017
MW-38 Conductivity 577 µS 6/27/2017
MW-38 Static Water Level 42.90 ft 6/27/2017
MW-38 Well Depth 74.50 ft 6/27/2017
MW-38*pH 5.98 S.U. 8/8/2017
MW-38*Temperature 18.8 ºC 8/8/2017
MW-38*Turbidity 7.11 NTU 8/8/2017
MW-38*Conductivity 440 µS 8/8/2017
MW-38*Static Water Level 43.06 ft 8/8/2017
MW-38*Well Depth 74.50 ft 8/8/2017
Burke Co. - Johns River C+D-over-MSWLF
Permit No. 12-03
2 of 3
Joyce Engineering
TABLE 2: FIELD PARAMETERS
WELL ID PARAMETER RESULT UNITS COLLECT DATE
PZ-35 pH 6.39 S.U. 6/27/2017
PZ-35 Temperature 20.1 ºC 6/27/2017
PZ-35 Turbidity 10.75 NTU 6/27/2017
PZ-35 Conductivity 25.7 µS 6/27/2017
PZ-35 Static Water Level 22.70 ft 6/27/2017
PZ-35 Well Depth 39.05 ft 6/27/2017
SMP-5 pH 6.37 S.U. 6/28/2017
SMP-5 Temperature 21.1 ºC 6/28/2017
SMP-5 Conductivity 110.5 µS 6/28/2017
SMP-5 Turbidity 15.21 NTU 6/28/2017
SMP-6 pH 6.49 S.U. 6/28/2017
SMP-6 Temperature 18.3 ºC 6/28/2017
SMP-6 Conductivity 89.6 µS 6/28/2017
SMP-6 Turbidity 12.65 NTU 6/28/2017
SMP-7 pH 5.85 S.U. 6/28/2017
SMP-7 Temperature 16.7 ºC 6/28/2017
SMP-7 Conductivity 34.3 µS 6/28/2017
SMP-7 Turbidity 25.4 NTU 6/28/2017
Notes:ºC= degrees Centigrade
S.U.= Standard Units
µS = microsemens
NTU = Nephelometric Turbidity Units
mg/l = milligrams per liter
mV = millivolts
ft = feet
*= MW-38 verification (resample) event performed 8/8/2017.
Burke Co. - Johns River C+D-over-MSWLF
Permit No. 12-03
3 of 3
Joyce Engineering
TABLE 3:
QUANTIFIED DETECTIONS IN GROUNDWATER AND SURFACE WATER
SAMPLE
ID PARAMETER RESULT UNITS SWSL
SAMPLE
DATE
1203-MW10 Cobalt 121 µg/l 10 6/28/2017
1203-MW10 Iron 58,100 µg/l 300 6/28/2017
1203-MW10 Manganese 8,910 µg/l 50 6/28/2017
1203-MW10 Benzene 1.6 µg/l 1 6/28/2017
1203-MW10 Alkalinity, Total as CaCO3 102,000 µg/l 5,000 6/28/2017
1203-MW10 Total Dissolved Solids 151,000 µg/l 25,000 6/28/2017
1203-MW10 Chloride 11,500 µg/l 1,000 6/28/2017
1203-MW11 Barium 127 µg/l 100 6/28/2017
1203-MW11 Cobalt 60.5 µg/l 10 6/28/2017
1203-MW11 Iron 67,400 µg/l 300 6/28/2017
1203-MW11 Manganese 19,900 µg/l 500 6/28/2017
1203-MW11 Zinc 19.6 µg/l 10 6/28/2017
1203-MW11 1,4-Dichlorobenzene 10.6 µg/l 1 6/28/2017
1203-MW11 Benzene 2.1 µg/l 1 6/28/2017
1203-MW11 cis-1,2-Dichloroethene 5.8 µg/l 5 6/28/2017
1203-MW11 Alkalinity, Total as CaCO3 165,000 µg/l 5,000 6/28/2017
1203-MW11 Total Dissolved Solids 237,000 µg/l 25,000 6/28/2017
1203-MW11 Chloride 29,700 µg/l 1,000 6/28/2017
1203-MW12 Cobalt 74 µg/l 10 6/28/2017
1203-MW12 Iron 51,800 µg/l 300 6/28/2017
1203-MW12 Manganese 10,200 µg/l 500 6/28/2017
1203-MW12 Zinc 11.7 µg/l 10 6/28/2017
1203-MW12 1,1-Dichloroethane 26.8 µg/l 5 6/28/2017
1203-MW12 Benzene 2.6 µg/l 1 6/28/2017
1203-MW12 Trichloroethene 1.4 µg/l 1 6/28/2017
1203-MW12 cis-1,2-Dichloroethene 9 µg/l 5 6/28/2017
1203-MW12 Alkalinity, Total as CaCO3 98,700 µg/l 5,000 6/28/2017
1203-MW12 Total Dissolved Solids 153,000 µg/l 25,000 6/28/2017
1203-MW12 Chloride 10,400 µg/l 1,000 6/28/2017
1203-MW13 Cobalt 75.5 µg/l 10 6/28/2017
1203-MW13 Iron 1,230 µg/l 300 6/28/2017
1203-MW13 Manganese 1,750 µg/l 50 6/28/2017
1203-MW13 Zinc 22 µg/l 10 6/28/2017
1203-MW13 alpha-BHC 0.11 µg/l 0.05 6/28/2017
1203-MW13 1,1-Dichloroethane 24.2 µg/l 5 6/28/2017
1203-MW13 1,2-Dichloroethane 1.3 µg/l 1 6/28/2017
1203-MW13 1,4-Dichlorobenzene 16 µg/l 1 6/28/2017
1203-MW13 Benzene 14.8 µg/l 1 6/28/2017
1203-MW13 Ethylbenzene 1.5 µg/l 1 6/28/2017
1203-MW13 Methylene Chloride 17.3 µg/l 1 6/28/2017
1203-MW13 Tetrachloroethene 6.5 µg/l 1 6/28/2017
1203-MW13 Toluene 2.1 µg/l 1 6/28/2017
1203-MW13 Trichloroethene 10 µg/l 1 6/28/2017
1203-MW13 Xylene (Total) 63.8 µg/l 5 6/28/2017
1203-MW13 cis-1,2-Dichloroethene 23.3 µg/l 5 6/28/2017
1203-MW13 Alkalinity, Total as CaCO3 11,300 µg/l 5,000 6/28/2017
1203-MW13 Chloride 1,550 µg/l 1,000 6/28/2017
Burke Co. - Johns River C+D-over-MSWLF
Permit No. 12-03 1 of 2
Joyce Engineering
TABLE 3:
QUANTIFIED DETECTIONS IN GROUNDWATER AND SURFACE WATER
SAMPLE
ID PARAMETER RESULT UNITS SWSL
SAMPLE
DATE
1203-MW16D Manganese 131 µg/l 50 6/28/2017
1203-MW16D Alkalinity, Total as CaCO3 51,200 µg/l 5,000 6/28/2017
1203-MW16S Cobalt 35.4 µg/l 10 6/28/2017
1203-MW16S Iron 29,100 µg/l 300 6/28/2017
1203-MW16S Manganese 11,000 µg/l 500 6/28/2017
1203-MW16S Zinc 35.8 µg/l 10 6/28/2017
1203-MW16S 1,1-Dichloroethane 17.8 µg/l 5 6/28/2017
1203-MW16S Benzene 1.2 µg/l 1 6/28/2017
1203-MW16S cis-1,2-Dichloroethene 5.4 µg/l 5 6/28/2017
1203-MW16S Alkalinity, Total as CaCO3 99,100 µg/l 5,000 6/28/2017
1203-MW16S Total Dissolved Solids 105,000 µg/l 25,000 6/28/2017
1203-MW16S Chloride 7,000 µg/l 1,000 6/28/2017
1203-MW36 Benzene 20.1 µg/l 1 6/27/2017
1203-MW38 1,1-Dichloroethane 6.2 µg/l 5 6/27/2017
1203-MW38 cis-1,2-Dichloroethene 10.9 µg/l 5 6/27/2017
1203-MW38 Vinyl Chloride 1.9 µg/l 1 6/27/2017
1203-MW38 Vinyl Chloride - Resample 0.87 J µg/l 1 8/8/2017
1203-SMP6 Zinc 17.4 µg/l 10 6/28/2017
1203-SMP6 Trichloroethene 1.1 µg/l 1 6/29/2017
1203-SMP7 Zinc 39.4 µg/l 10 6/30/2017
Notes: µg/l = Micrograms per liter (parts per billion).
ND = Not detected.
J = Estimated concentration below the SWSL.
B = Blank-qualified detection (detected in a field, trip, or method blank at a similar concentration).
SWSL = NC Solid Waste Section Reporting Limit.
NE = SWSL not established (Laboratory reporting limit used).
Burke Co. - Johns River C+D-over-MSWLF
Permit No. 12-03 2 of 2
Joyce Engineering
TABLE 4:
EXCEEDANCES OF GROUNDWATER OR SURFACE WATER STANDARDS
WELL
ID PARAMETER RESULT UNITS SWSL
NC2L /
*GWPS /
**NC2B
GPS SAMPLE
DATE
1203-MW10 Cobalt 121 µg/l 10 1* 253 6/28/2017
1203-MW10 Iron 58,100 µg/l 300 300 ASD 6/28/2017
1203-MW10 Manganese 8,910 µg/l 50 50 ASD 6/28/2017
1203-MW10 Benzene 1.6 µg/l 1 1 1 6/28/2017
1203-MW11 Cobalt 60.5 µg/l 10 1* 90.7 Bkg. 6/28/2017
1203-MW11 Iron 67,400 µg/l 300 300 ASD 6/28/2017
1203-MW11 Manganese 19,900 µg/l 50 50 ASD 6/28/2017
1203-MW11 1,4-Dichlorobenzene 10.6 µg/l 1 6 6 6/28/2017
1203-MW11 Benzene 2.1 µg/l 1 1 1 6/28/2017
1203-MW12 Cobalt 74.0 µg/l 10 1* 90.7 Bkg. 6/28/2017
1203-MW12 Iron 51,800 µg/l 300 300 ASD 6/28/2017
1203-MW12 Manganese 10,200 µg/l 50 50 ASD 6/28/2017
1203-MW12 1,1-Dichloroethane 26.8 µg/l 5 6 6 6/28/2017
1203-MW12 1,2-Dichloroethane 1.1 µg/l 1 0.4 1 6/28/2017
1203-MW12 Benzene 2.6 µg/l 1 1 1 6/28/2017
1203-MW13 Cobalt 75.5 µg/l 10 1* 90.7 Bkg. 6/28/2017
1203-MW13 Iron 1230 µg/l 300 300 ASD 6/28/2017
1203-MW13 Manganese 1,750 µg/l 50 50 ASD 6/28/2017
1203-MW13 alpha-BHC 0.11 µg/l 0.05 0.006 0.050 6/28/2017
1203-MW13 1,1-Dichloroethane 24.2 µg/l 5 6 6 6/28/2017
1203-MW13 1,2-Dichloroethane 1.3 µg/l 1 0.4 1 6/28/2017
1203-MW13 1,4-Dichlorobenzene 16 µg/l 1 6 6 6/28/2017
1203-MW13 Benzene 14.8 µg/l 1 1 1 6/28/2017
1203-MW13 Methylene Chloride 17.3 µg/l 1 5 5 6/28/2017
1203-MW13 Tetrachloroethene 6.5 µg/l 1 0.7 1 6/28/2017
1203-MW13 Trichloroethene 10 µg/l 1 3 3 6/28/2017
1203-MW16D Manganese 131 µg/l 50 50 ASD 6/28/2017
1203-MW16S Cobalt 35.4 µg/l 10 1* 90.7 Bkg. 6/28/2017
1203-MW16S Iron 29,100 µg/l 300 300 ASD 6/28/2017
1203-MW16S Manganese 11,000 µg/l 50 50 ASD 6/28/2017
1203-MW16S 1,1-Dichloroethane 17.8 µg/l 5 6 6 6/28/2017
1203-MW36 Benzene 20.1 µg/l 1 1 1 6/27/2017
1203-MW38 1,1-Dichloroethane 6.2 µg/l 5 6 6 6/27/2017
1203-MW38 Vinyl Chloride 1.9 µg/l 1 0.03 1 6/27/2017
1203-MW38 Vinyl Chloride - Resample 0.87 J µg/l 1 0.03 1 8/8/2017
1203-SMP7 Zinc 39.4 µg/l 10 36 ‐‐‐6/30/2017
Notes: µg/l = Micrograms per liter (parts per billion).
ND = Not detected.
SWSL = NC Solid Waste Section Reporting Limit.
NE = SWSL not established (Laboratory reporting limit used).
NC2B = Surface Water Protection Standard from 15A NCAC 2B.
NC2L = Groundwater Protection Standard from 15A NCAC 2L.0202.
GWPS = NC SWS Groundwater Protection Standard for constituents with no lisated NC2L.
GPS = Groundwater Protection Standard as defind by 15 A NCAC 13B.1634.(g).
Bkg. = Indicates a Proposed GPS based on background (See Section 4.3 & Table 5).
GPS = SWSL if SWSL > listed NC2L or GWPS.
ASD = This constituent coverd by an approved ASD; therefore, it is not considered a GPS exceedance
Bold Results are considered confirmed exceedances of the GPS.
Burke Co. - Johns River C+D-over-MSWLF
Permit No. 12-03
Joyce Engineering
TABLE 5: STATISTICAL BACKGROUND ANALYSESAnalyte Data Distribution Statistical Method used to Establish BackgroundBackground (µg/L)SWSL (µg/L)NC2L or *GWPS (µg/L)Proposed GPS (µg/L)Sampling Result (Max.) (µg/L)ExceedancesCobalt148% ND, Log-NormalUpper Tolerance Limit: Interwell88.2 10 1* 88.2 75.5 NoneCobalt20% ND, Log-NormalUpper Tolerance Limit: Intrawell (MW-10)271 10 1* 271 121.0 NoneNotes: SWSL = NC Solid Waste Section LimitsNC 2L = NC Groundwater Standards (15A NCAC 2L.0202)GWPS = Solid Waste Section Groundwater Protection Standards for Constituents with no NC 2L (indicated by *%ND = percentage of data that were non-detect (i.e., truncated).Only constituents with quantified detections above the SWSL in down-gradient wells are included in statistical analyses.GPS = Groundwater Protection Standard per 15A NCAC .1634(g) 1 Cobalt for all wells except MW-102 Cobalt for MW-10Sample Dates: June 27-28, 2017Burke Co. - Johns River C+D-over-MSWLFPermit No. 12-03Joyce Engineering
TABLE 6: MNA Parameters BackgroundAnalyte/Parameter Date Units MW-21 MW-11 MW-12 MW-16S MW-18 MW-19Temperature (FP)6/27/2017oC15.0 16.8 17.0 16.8NSNSpH (FP)6/27/2017 S.U. 6.45 6.06 5.99 5.95NSNSSpecific Conductance (FP)6/27/2017 µS/cm28.9 450.1 234.6 226.1NSNSORP (FP)6/27/2017 mV184.2 5.3 10.7 20.5NSNSTurbidity (FP)6/27/2017 ntu12.20 7.29 9.78 11.60NSNSDissolved Oxygen (FP)6/27/2017 mg/l7.06 2.40 4.75 2.16NSNSCarbon Dioxide (FP)6/27/2017 mg/lNSNSNSNSNSNSIron II (ferrous iron) (FP)6/27/2017 mg/l1.04.0 0.5 1.5NSNSNitrate 6/27/2017 mg/l .201 J ND ND ND NS NSAlkalinity 6/27/2017 mg/l ND 165.000 98.700 99.100 NS NSChloride 6/27/2017 mg/l ND 11.500 29.700 10.400 NS NSSulfate 6/27/2017 mg/l ND 2.20 J 3.20 J ND NS NSSulfide 6/27/2017 mg/l NS NS NS NS NS NSMethane 6/27/2017 mg/l 0.0194 3.150 16.600 12.500 NS NSEthane 6/27/2017 mg/l NS NS NS NS NS NSEthylene (Ethene) 6/27/2017 mg/l NS NS NS NS NS NSDissolved Hydrogen 6/27/2017 nM 2.0 1.7 2.0 2.0 NS NSVolatile Fatty Acids 6/27/2017 mg/l NS NS NS NS NS NSTOC 6/27/2017 mg/l ND 2.98 2.17 2.74 NS NSTetrachloroethene (PCE) 6/27/2017 µg/l ND ND ND ND NS NSTrichloroethene (TCE) 6/27/2017 µg/l ND ND 1.4 0.56 J NS NS1,2-Dichloroethene (DCE) 6/27/2017 µg/l ND 5.8 9.0 5.4 NS NSVinyl Chloride (VC) 6/27/2017 µg/l ND 0.63 J 0.80 J 0.95 J NS NS1,1,1-Trichloroethane 6/27/2017 µg/l ND ND ND ND NS NS1,1-Dichloroethane 6/27/2017 µg/l ND 3.3 J 26.8 17.8 NS NSChloroethane 6/27/2017 µg/l ND ND 2.6 J 1.6 J NS NSChloroform 6/27/2017 µg/l ND ND ND ND NS NSMethylene Chloride 6/27/2017 µg/lNDNDNDNDNSNSNotes: (FP) = Field Parameter mV = millivoltsND = Not Detected S.U. = standard unitsJ = Estimated concentrationoC = degrees CelciusORP = Oxidation-Reduction PotentialmS/cm = microsiemens per centimeterTOC = Total Organic Carbonmg/l = milligrams per liter (parts per million)BTEX = Total Benzene, Toluene, Ethylbenzene, Xylenesµg/l = micrograms per liter (parts per billion)DowngradientSentinelBurke Co. - Johns River C+D-over-MSWLFPermit 12-03Joyce Engineering
TABLE 7:
BIODEGRADATION SCREENING MATRIX
Parameter Concentration Interpretation Possible Points Awarded Points Awarded
in Plume Points with DP points without DP points
Oxygen < 0.5 mg/L Tolerated, suppresses the reductive pathway at higher 3 0 0
concentrations
> 5 mg/L Not tolerated; however, vinyl chloride may be oxidized -3 0 0
aerobically
Nitrate < 1 mg/L At higher concentrations may compete with reductive 2 2 2
pathway
Iron II (Ferrous Iron)> 1 mg/L Reductive pathway possible; vinyl chloride may be 3 3 3
oxidized under Fe (III) - reducing conditions
Sulfate < 20 mg/L At higher concentrations may compete with reductive 2 2 2
pathway
Sulfide *> 1 mg/L Reductive pathway possible 3 0 0
Methane < 0.5 mg/L Vinyl chloride oxidizes 0
> 0.5 mg/L Ultimate reductive daughter product, vinyl chloride 3 3 0
accumulates
Oxidation Reduction < 50 mV Reductive pathway possible 1 1 1
Potential < -100 mV Reductive pathway likely 2
pH 5 < pH < 9 Optimal range for reductive pathway 0 0 0
5 > pH > 9 Outside optimal range for reductive pathway -2 0 0
TOC > 20 mg/L Carbon and energy source; drives dechlorination; can 2 0 0
be natural or anthropogenic
Temperature >20o C At T > 20
oC biochemical process is accelerated 10 0
Carbon Dioxide * > 2x background Ultimate oxidative daughter product 1 1 0
Alkalinity > 2x background Results from interaction between CO2 and 1 1 1
aquifer minerals
Chloride > 2x background Daughter product of organic chlorine 2 2 2
Hydrogen > 1 nM Reductive pathway possible 3 3 3
< 1 nM Vinyl chloride oxidizes 0
Volatile Fatty Acids * > 0.1 mg/L Intermediates resulting from biodegradation of more 2 0 0
complex compounds; carbon and energy source
BTEX > 0.1 mg/L Carbon and energy source; drives dechlorination 2 0 0
Tetrachloroethene (PCE) --- Material released 0 0 0
Trichloroethene (TCE) --- Material released 0 0
--- Daughter product of PCE 2 2
Dichloroethenes (DCE) --- Material released 0 0
Daughter product of TCE 2 2
Dichloroethene, cis-1,2, --- Material released 0 0
--- Daughter product of trichlorethene 2 2
Vinyl Chloride (VC) --- Material released 0 0
--- Daughter product of DCE 2 2
1,1,1-Trichloroethane (TCA) --- Material released 0 0 0
1,1-Dichloroethane (DCA) --- Material released 0 0
Daughter product of TCA 2 2
Chloroethane --- Daughter product of dichloroethane or vinyl chloride
under reducing conditions 2 2 0
Ethene/Ethane * > 0.01 mg/L Daughter products of vinyl chloride/ethene 2 0 0
> 0.1 mg/L 3 0 0
Chloroform --- Material released 0 0 0
--- Daughter product of carbon tetrachloride 2 0 0
Dichloromethane (MC) --- Material released 0 0 0
(Methylene Chloride) --- Daughter product of chloroform 2
Based on samples collected on June 27-28, 2017. Total Points Awarded : 30 14
* These parameters are required on a reduced schedule, so were not collected for this event.
mg/L = miligrams per liter Scores for these parameters are based on historical results.
mV = millivolts NOTE: Chloroethane, Methane, TCE, DCE, cis-1,2-DCE, MC, VC, DCA, and CO2 are all present in the plume; however,
nM = nanomolar it is uncertain whether these are primary leachate constituents or daughter products (DPs); therefore, we
C = Celcius have two calculation columns. The first column assumes all of these are daughter products, and the
NA = Not Analyzed second column assumes none of them are. The true score is probably between the two.
BTEX = Sum of Benzene, Toluene, Ethylbenzene, and Total Xylenes (Score based on MW-13 data).
NS (0) = Not sampled for this parameter, value in parenthsis is a score based on historical data.SCORE: Evid. of Nat. Atten.
< 5 inadequate
This screening matrix is prepared in general accordance with the United Stated Environmental Protection Agency's 6-14 limited
(EPA's) Table 2.3 Analytical Parameters and Weighted for Preliminary Screening for Anaerobic Biodegradation 15-19 adequate
Process presented in the EPA's Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents > 20 strong
in Groundwater, September 1988.
Burke Co. - Johns River C+D-over-MSWLF
Permit 12-03
1 of 1
Joyce Engineering

CHARTS

Chart 1: Benzene Concentrations vs. Time
Chart 2: 1,4-Dichlorobenzene Concentrations vs. Time
Chart 3: 1,1-Dichloroethane Concentrations vs. Time
Chart 4: 1,2-Dichloroethane Concentrations vs. Time
Chart 5: Tetrachloroethylene (PCE) Concentrations vs. Time
Chart 6: Trichloroethylene (TCE) Concentrations vs. Time
Chart 7: Vinyl Chloride Concentrations vs. Time
Chart 8: Methylene Chloride Concentrations vs. Time
Chart 9 alpha-BHC Concentrations vs. Time
Chart 10: beta-BHC Concentrations vs. Time

Johns River Landfill, Burke Co.Permit 12‐03Joyce Engineering024681012141618May‐96Nov‐96May‐97Nov‐97May‐98Nov‐98May‐99Nov‐99May‐00Nov‐00May‐01Nov‐01May‐02Nov‐02May‐03Nov‐03May‐04Nov‐04May‐05Nov‐05May‐06Nov‐06May‐07Nov‐07May‐08Nov‐08May‐09Nov‐09May‐10Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16May‐17Concentration  (µg/l)Chart 1:  Benzene Concentration vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS
Johns River Landfill, Burke Co.Permit 12‐03Joyce Engineeirng0510152025May‐94Nov‐94May‐95Nov‐95May‐96Nov‐96May‐97Nov‐97May‐98Nov‐98May‐99Nov‐99May‐00Nov‐00May‐01Nov‐01May‐02Nov‐02May‐03Nov‐03May‐04Nov‐04May‐05Nov‐05May‐06Nov‐06May‐07Nov‐07May‐08Nov‐08May‐09Nov‐09May‐10Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16May‐17Concentration  (µg/l)Chart 2:  1,4‐Dichlorobenzene Concentration vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS
Johns River Landfill, Burke Co.Permit 12‐03Joyce Engineering050100150200250300May‐94Nov‐94May‐95Nov‐95May‐96Nov‐96May‐97Nov‐97May‐98Nov‐98May‐99Nov‐99May‐00Nov‐00May‐01Nov‐01May‐02Nov‐02May‐03Nov‐03May‐04Nov‐04May‐05Nov‐05May‐06Nov‐06May‐07Nov‐07May‐08Nov‐08May‐09Nov‐09May‐10Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16May‐17Concentration  (µg/l)Chart 3:  1,1‐Dichloroethane vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS
Johns River Landfill, Burke Co.Permit 12‐03Joyce Engineering02468101214Nov‐05May‐06Nov‐06May‐07Nov‐07May‐08Nov‐08May‐09Nov‐09May‐10Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16May‐17Concentration  (µg/l)Chart 4:  1,2‐Dichloroethane vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS
Johns River Landfill, Burke Co.Permit 12‐03Joyce Engineering02468101214May‐97Nov‐97May‐98Nov‐98May‐99Nov‐99May‐00Nov‐00May‐01Nov‐01May‐02Nov‐02May‐03Nov‐03May‐04Nov‐04May‐05Nov‐05May‐06Nov‐06May‐07Nov‐07May‐08Nov‐08May‐09Nov‐09May‐10Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16May‐17Concentration  (µg/l)Chart 5:  Tetrachloroethene vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS
Johns River Landfill, Burke Co.Permit 12‐03Joyce Engineering02468101214161820May‐94Nov‐94May‐95Nov‐95May‐96Nov‐96May‐97Nov‐97May‐98Nov‐98May‐99Nov‐99May‐00Nov‐00May‐01Nov‐01May‐02Nov‐02May‐03Nov‐03May‐04Nov‐04May‐05Nov‐05May‐06Nov‐06May‐07Nov‐07May‐08Nov‐08May‐09Nov‐09May‐10Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16May‐17Concentration  (µg/l)Chart 6:  Trichloroethene vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS
Johns River Landfill, Burke Co.Permit 12‐03Joyce Engineering00.511.522.533.54May‐07Nov‐07May‐08Nov‐08May‐09Nov‐09May‐10Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16May‐17Concentration  (µg/l)Chart 7:  Vinyl Chloride vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS
Johns River Landfill, Burke Co.Permit 12‐03Joyce Engineering0100200300400500600700800900May‐94Nov‐94May‐95Nov‐95May‐96Nov‐96May‐97Nov‐97May‐98Nov‐98May‐99Nov‐99May‐00Nov‐00May‐01Nov‐01May‐02Nov‐02May‐03Nov‐03May‐04Nov‐04May‐05Nov‐05May‐06Nov‐06May‐07Nov‐07May‐08Nov‐08May‐09Nov‐09May‐10Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16May‐17Concentration  (µg/l)Chart 8:  Methylene Chloride vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS
Johns River Landfill, Burke Co.Permit 12‐03 Joyce Engineering00.020.040.060.080.10.120.140.160.180.2May‐96Nov‐96May‐97Nov‐97May‐98Nov‐98May‐99Nov‐99May‐00Nov‐00May‐01Nov‐01May‐02Nov‐02May‐03Nov‐03May‐04Nov‐04May‐05Nov‐05May‐06Nov‐06May‐07Nov‐07May‐08Nov‐08May‐09Nov‐09May‐10Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16May‐17Concentration  (µg/l)Chart 9:  alpha‐BHC vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS
Johns River Landfill, Burke Co.Permit 12‐03Joyce Engineering00.050.10.150.20.250.30.35Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16May‐17Concentration  (µg/l)Chart 10:  beta‐BHC vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS

FIGURE

Figure 1: Site Location Map

APPROXIMATE LOCATION
OF EXISTING LANDFILL
APPROXIMATE LOCATION
OF PROPERTY LINE
SOURCE: U.S.G.S. TOPOGRAPHIC MAP
FOR MORGANTON NORTH, N.C.
0
(FEET)
GRAPHIC SCALE
400020001000
2211 W. MEADOWVIEW ROAD
GREENSBORO, NC 27407
PHONE: [phone]
PROJECT NO.
FIGURE NO.APPROVED
CHECKED
DRAWN
DESIGNED
DATE
All rights reserved.
Ó Joyce Engineering, Inc.
SCALE
NC CORP LIC: C-0782
JOHN'S RIVER LANDFILL
BURKE COUNTY, NORTH CAROLINA
SITE LOCATION MAP
277
1
AS SHOWN
2017
ACE
RH
ACE
ACE
2017

DRAWING

Drawing 1: Groundwater Potentiometric Surface Map

SMP-5SURFACE MONITORING POINT LOCATION AND IDENTIFICATIONNOT MEASUREDLEGENDPROPERTY LINEEXISTING ROADEXISTING 25' TOPOGRAPHIC CONTOUREXISTING 2' TOPOGRAPHIC CONTOURGROUNDWATER SURFACE CONTOUR [FEETABOVE MEAN SEA LEVEL (AMSL)]APPROXIMATE LIMITS OF WASTECENTERLINE OF STREAMGAS PROBE LOCATION AND IDENTIFICATIONPIEZOMETER LOCATION AND IDENTIFICATIONCOMPLIANCE WELL LOCATION AND IDENTIFICATION WITH STATICWATER LEVEL ELEVATION (FEET AMSL)(NM)GP10501020MW-131009.84PZ-9DGMP-3TOPOGRAPHIC CONTOUR INTERVAL = 2 AND 10 FEET.GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET.STATIC WATER LEVELS WERE MEASURED ON JUNE 28, 2017.GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN ANDEXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWNFIELD CONDITIONS.MW-16D GROUNDWATER ELEVATION WAS NOT USED IN CALCULATINGGROUNDWATER CONTOURS.NOTESEXISTING 5' TOPOGRAPHIC CONTOUREXISTING 10' TOPOGRAPHIC CONTOUR1080T1TEMPORARY WELLAPPROXIMATE LOCATION OF SPRING HEAD1.2.3.4.5.JE-0020CONTROL POINT LOCATION AND IDENTIFICATIONSENTINEL WELL LOCATION AND IDENTIFICATION WITH STATICWATER LEVEL ELEVATION (FEET AMSL)MW-18GROUNDWATER FLOW PATHWAY USED TOCALCULATE HYDRAULIC GRADIENTi1SEGMENT USED FOR GRADIENT CALCULATIONMW-9ABANDONED OR UNUSED MONITORING WELLiiiFLOW PATH LENGTH1,395 LF1,244 LF960 LF545 LFi1030102
01010102010101000100010101020103010401050 1060107010801090110011101120113011401150116011501140113011201110110010901080117010801070106010501040105010401030102010101000105010401030102010101000i1i2i3i41060(ABANDONED)PZ-2S(ABANDONED)PZ-2D(NM)PZ-23(NM)PZ-15(NM)MW-22D1042.20MW-22S(NM)PZ-16D(NM)PZ-16S1017.64PZ-12(NM)PZ-27(NM)PZ-14(NM)PZ-13(ND)PZ-9D(NM)PZ-9S1009.84MW-13SMP-6993.13MW-12992.87MW-11994.07MW-16D992.82MW-16S999.55MW-10SMP-5(ABANDONED)MW-9(NM)MW-141024.79MW-15S(NM)MW-15D1040.99MW-8(NM)MW-1(FORMERLY PZ-4)MW-20NMMW-17SHOOTINGRANGEMULCHINGAREALOWER CREEKJOHNS RIVERCATAWBA R
IVER PROTECTED AREAWETLANDEXISTING TRAILAPPROX. LIMIT OFEXISTING WASTETRANSFER FACILITYBOUNDARYEXISTINGSEDIMENTBASINEXISTING C&DDISPOSAL AREACURRENT BACKGROUND WELLFORMER MW-18MW-19NMNM1050.54OFFICEANDGARAGE1040 1050 1070 1080 1090 11001060MW-381044.86MW-361065.77PZ-30S1045.22PZ-30DPZ-311058.31PZ-351039.441061.51MW-21 (FORMERLY PZ-1)BACKGROUND WELLCURRENT PHASE 1A LIMITS1060SMP-7PROJECT NO.APPROVED
CHECKED
DRAWN
DESIGNED
DATE
DATE REVISIONS AND RECORD OF ISSUE BYNO APPCKSCALE All rights reserved.
Ó Joyce Engineering, Inc.DRAWING NO.N:\Dwgs\Drawings-Current\BURKE\GW EVENT MAPS\GW-EVENT 6-17.DWG Layout=SHT 01
2211 W. MEADOWVIEW ROAD
GREENSBORO, NC 27407
PHONE: [phone]JOHNS RIVER, WASTE MANAGEMENT FACILITY
BURKE COUNTY, NORTH CAROLINA
20171AS NOTEDGROUNDWATER POTENTIOMETRIC SURFACE MAP
JUNE 28, 2017
PERMIT NO. 12-03
GE
RWH
VB
VB
09/22/170(FEET)GRAPHIC SCALE400200100

APPENDICES

Appendix A Field Data Logs
Appendix B Laboratory Analytical Reports
Appendix C Statistical Analyses Worksheets
Appendix D Historical Detected Inorganic Groundwater Constituents
Appendix E Historical Detected Organic Groundwater Constituents
Appendix F Historical Detected Constituents in Performance & Sentinel Wells
Appendix G Historical Detected Surface Water Constituents
Appendix H Historical MNA Parameters

Appendix A

Field Data Logs

Appendix B

Laboratory Analytical Reports

#=CL#
July 15, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92345867
92345867
Project:
Pace Project No.:
RE:
Mr. Van BurbachJoyce Engineering-Greensboro2211 West Meadowview RdBoone Bldg, Suite 101Greensboro, NC 27407
JOHNS R. C&D/MSWLF GW
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on June 28, 2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager(704)875-9092
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 49
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 49
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Lab ID Sample ID Matrix Date Collected Date Received
92345867001 1203-MW10 Water 06/27/17 11:12 06/28/17 09:28
92345867002 1203-MW11 Water 06/27/17 11:17 06/28/17 09:28
92345867003 1203-MW12 Water 06/27/17 12:00 06/28/17 09:28
92345867004 1203-MW13 Water 06/27/17 13:10 06/28/17 09:28
92345867005 1203-MW16S Water 06/27/17 12:30 06/28/17 09:28
92345867006 1203-MW16D Water 06/27/17 10:18 06/28/17 09:28
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 49
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92345867001 1203-MW10 EPA 8081 4 PASI-CRES
EPA 6010 17 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AKAL
EPA 8260 53 PASI-CGAW
SM 2320B 1 PASI-AKDF1
SM 2540C 1 PASI-ASLB
EPA 300.0 1 PASI-ACDC
SM 4500-Cl-E 1 PASI-ABRJ
SM 4500-CN-E 1 PASI-AAES2
92345867002 1203-MW11 EPA 8081 4 PASI-CRES
EPA 6010 17 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AKAL
EPA 8260 53 PASI-CGAW
SM 2320B 1 PASI-AKDF1
SM 2540C 1 PASI-ASLB
EPA 300.0 1 PASI-ACDC
SM 4500-Cl-E 1 PASI-ABRJ
SM 4500-CN-E 1 PASI-AAES2
92345867003 1203-MW12 EPA 8081 4 PASI-CRES
EPA 6010 17 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AKAL
EPA 8260 53 PASI-CGAW
SM 2320B 1 PASI-AKDF1
SM 2540C 1 PASI-ASLB
EPA 300.0 1 PASI-ACDC
SM 4500-Cl-E 1 PASI-ABRJ
SM 4500-CN-E 1 PASI-AAES2
92345867004 1203-MW13 EPA 8081 4 PASI-CRES
EPA 6010 17 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AKAL
EPA 8260 53 PASI-CGAW
SM 2320B 1 PASI-AKDF1
SM 2540C 1 PASI-ASLB
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 49
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
EPA 300.0 1 PASI-ACDC
SM 4500-Cl-E 1 PASI-ABRJ
SM 4500-CN-E 1 PASI-AAES2
92345867005 1203-MW16S EPA 8081 4 PASI-CRES
EPA 6010 17 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AKAL
EPA 8260 53 PASI-CGAW
SM 2320B 1 PASI-AKDF1
SM 2540C 1 PASI-ASLB
EPA 300.0 1 PASI-ACDC
SM 4500-Cl-E 1 PASI-ABRJ
SM 4500-CN-E 1 PASI-AAES2
92345867006 1203-MW16D EPA 6010 16 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AKAL
EPA 8260 52 PASI-CGAW
SM 2320B 1 PASI-AKDF1
EPA 300.0 1 PASI-ACDC
SM 4500-Cl-E 1 PASI-ABRJ
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 49
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92345867001 1203-MW10
Barium 47.4J ug/L 07/12/17 06:23100EPA 6010
Cobalt 121 ug/L 07/09/17 00:3010.0EPA 6010
Iron 58100 ug/L 07/09/17 00:30300EPA 6010
Lead 3.0J ug/L 07/09/17 00:3010.0EPA 6010
Manganese 8910 ug/L 07/09/17 00:3050.0EPA 6010
Nickel 4.7J ug/L 07/09/17 00:3050.0EPA 6010
Vanadium 10.6J ug/L 07/09/17 00:3025.0EPA 6010
Zinc 10J ug/L 07/09/17 00:3010.0EPA 6010
Thallium 0.24J ug/L 07/12/17 14:595.5EPA 6020B
Mercury 0.17J ug/L 07/07/17 04:150.20EPA 7470
Acetone 10.4J ug/L 06/29/17 05:32100EPA 8260
Benzene 1.6 ug/L 06/29/17 05:321.0EPA 8260
Chlorobenzene 1.3J ug/L 06/29/17 05:323.0EPA 8260
Chloroethane 0.58J ug/L 06/29/17 05:3210.0EPA 8260
Chloromethane 0.31J ug/L 06/29/17 05:321.0EPA 8260
1,1-Dichloroethane 0.78J ug/L 06/29/17 05:325.0EPA 8260
cis-1,2-Dichloroethene 3.5J ug/L 06/29/17 05:325.0EPA 8260
Alkalinity, Total as CaCO3 102000 ug/L 07/01/17 17:585000SM 2320B
Total Dissolved Solids 151000 ug/L 06/30/17 10:0525000SM 2540C
Sulfate 5290J ug/L 07/04/17 00:28250000EPA 300.0
Chloride 11500 ug/L 07/08/17 01:151000SM 4500-Cl-E
92345867002 1203-MW11
Barium 127 ug/L 07/12/17 06:26100EPA 6010
Chromium 3.9J ug/L 07/09/17 00:3310.0EPA 6010
Cobalt 60.5 ug/L 07/09/17 00:3310.0EPA 6010
Iron 67400 ug/L 07/09/17 00:33300EPA 6010
Lead 3.9J ug/L 07/09/17 00:3310.0EPA 6010
Manganese 19900 ug/L 07/12/17 06:42500EPA 6010
Nickel 4.1J ug/L 07/09/17 00:3350.0EPA 6010
Vanadium 20.6J ug/L 07/09/17 00:3325.0EPA 6010
Zinc 19.6 ug/L 07/09/17 00:3310.0EPA 6010
Thallium 0.36J ug/L 07/12/17 15:015.5EPA 6020B
Acetone 32.4J ug/L 06/29/17 05:49100EPA 8260
Benzene 2.1 ug/L 06/29/17 05:491.0EPA 8260
Chlorobenzene 0.53J ug/L 06/29/17 05:493.0EPA 8260
Chloromethane 0.20J ug/L 06/29/17 05:491.0EPA 8260
1,2-Dichlorobenzene 0.31J ug/L 06/29/17 05:495.0EPA 8260
1,4-Dichlorobenzene 10.6 ug/L 06/29/17 05:491.0EPA 8260
1,1-Dichloroethane 3.3J ug/L 06/29/17 05:495.0EPA 8260
1,2-Dichloroethane 0.26J ug/L 06/29/17 05:491.0EPA 8260
cis-1,2-Dichloroethene 5.8 ug/L 06/29/17 05:495.0EPA 8260
Vinyl chloride 0.63J ug/L 06/29/17 05:491.0EPA 8260
Alkalinity, Total as CaCO3 165000 ug/L 07/01/17 18:095000SM 2320B
Total Dissolved Solids 237000 ug/L 06/30/17 10:0525000SM 2540C
Sulfate 2120J ug/L 07/04/17 01:18250000EPA 300.0
Chloride 29700 ug/L 07/08/17 01:161000SM 4500-Cl-E
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 49
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92345867003 1203-MW12
Barium 81.1J ug/L 07/12/17 06:29100EPA 6010
Chromium 5.8J ug/L 07/09/17 00:3610.0EPA 6010
Cobalt 74.0 ug/L 07/09/17 00:3610.0EPA 6010
Iron 51800 ug/L 07/09/17 00:36300EPA 6010
Lead 5.0J ug/L 07/09/17 00:3610.0EPA 6010
Manganese 10200 ug/L 07/12/17 06:45500EPA 6010
Nickel 29.0J ug/L 07/09/17 00:3650.0EPA 6010
Vanadium 15.8J ug/L 07/09/17 00:3625.0EPA 6010
Zinc 11.7 ug/L 07/09/17 00:3610.0EPA 6010
Thallium 0.094J ug/L 07/12/17 15:035.5EPA 6020B
Acetone 22.8J ug/L 06/29/17 06:07100EPA 8260
Benzene 2.6 ug/L 06/29/17 06:071.0EPA 8260
Chlorobenzene 0.73J ug/L 06/29/17 06:073.0EPA 8260
Chloroethane 2.6J ug/L 06/29/17 06:0710.0EPA 8260
Chloromethane 0.27J ug/L 06/29/17 06:071.0EPA 8260
1,1-Dichloroethane 26.8 ug/L 06/29/17 06:075.0EPA 8260
1,2-Dichloroethane 0.88J ug/L 06/29/17 06:071.0EPA 8260
cis-1,2-Dichloroethene 9.0 ug/L 06/29/17 06:075.0EPA 8260
Trichloroethene 1.4 ug/L 06/29/17 06:071.0EPA 8260
Vinyl chloride 0.80J ug/L 06/29/17 06:071.0EPA 8260
Alkalinity, Total as CaCO3 98700 ug/L 07/01/17 18:235000SM 2320B
Total Dissolved Solids 153000 ug/L 06/30/17 10:0525000SM 2540C
Sulfate 3200J ug/L 07/04/17 01:34250000EPA 300.0
Chloride 10400 ug/L 07/08/17 01:171000SM 4500-Cl-E
92345867004 1203-MW13
alpha-BHC 0.11 ug/L 07/07/17 16:520.050EPA 8081
Barium 76.2J ug/L 07/12/17 06:32100EPA 6010
Cobalt 75.5 ug/L 07/09/17 00:3910.0EPA 6010
Iron 1230 ug/L 07/09/17 00:39300EPA 6010
Manganese 1750 ug/L 07/09/17 00:3950.0EPA 6010
Nickel 4.5J ug/L 07/09/17 00:3950.0EPA 6010
Zinc 21.9 ug/L 07/09/17 00:3910.0EPA 6010
Thallium 0.097J ug/L 07/12/17 15:045.5EPA 6020B
Acetone 15.9J ug/L 06/29/17 06:25100EPA 8260
Benzene 14.8 ug/L 06/29/17 06:251.0EPA 8260
Chlorobenzene 1.1J ug/L 06/29/17 06:253.0EPA 8260
Chloroethane 0.78J ug/L 06/29/17 06:2510.0EPA 8260
Chloromethane 0.36J ug/L 06/29/17 06:251.0EPA 8260
1,2-Dichlorobenzene 0.80J ug/L 06/29/17 06:255.0EPA 8260
1,4-Dichlorobenzene 16.0 ug/L 06/29/17 06:251.0EPA 8260
Dichlorodifluoromethane 0.64J ug/L 06/29/17 06:255.0EPA 8260
1,1-Dichloroethane 24.2 ug/L 06/29/17 06:255.0EPA 8260
1,2-Dichloroethane 1.3 ug/L 06/29/17 06:251.0EPA 8260
cis-1,2-Dichloroethene 23.3 ug/L 06/29/17 06:255.0EPA 8260
1,2-Dichloropropane 0.28J ug/L 06/29/17 06:251.0EPA 8260
Ethylbenzene 1.5 ug/L 06/29/17 06:251.0EPA 8260
Methylene Chloride 17.3 ug/L 06/29/17 06:251.0EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 49
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92345867004 1203-MW13
Tetrachloroethene 6.5 ug/L 06/29/17 06:251.0EPA 8260
Tetrahydrofuran 7.5J ug/L 06/29/17 06:2510.0EPA 8260
Toluene 2.1 ug/L 06/29/17 06:251.0EPA 8260
Trichloroethene 10 ug/L 06/29/17 06:251.0EPA 8260
Trichlorofluoromethane 0.26J ug/L 06/29/17 06:251.0EPA 8260
Xylene (Total)63.8 ug/L 06/29/17 06:255.0EPA 8260
Alkalinity, Total as CaCO3 11300 ug/L 07/01/17 18:355000SM 2320B
Chloride 1550 ug/L 07/08/17 01:201000SM 4500-Cl-E
92345867005 1203-MW16S
Barium 50.7J ug/L 07/12/17 06:36100EPA 6010
Cobalt 35.4 ug/L 07/09/17 00:4310.0EPA 6010
Iron 29100 ug/L 07/09/17 00:43300EPA 6010
Manganese 11000 ug/L 07/12/17 06:58500EPA 6010
Vanadium 12.5J ug/L 07/09/17 00:4325.0EPA 6010
Zinc 35.8 ug/L 07/09/17 00:4310.0EPA 6010
Acetone 33.0J ug/L 06/29/17 06:42100EPA 8260
Benzene 1.2 ug/L 06/29/17 06:421.0EPA 8260
Chlorobenzene 0.57J ug/L 06/29/17 06:423.0EPA 8260
Chloroethane 1.6J ug/L 06/29/17 06:4210.0EPA 8260
Chloromethane 0.28J ug/L 06/29/17 06:421.0EPA 8260
1,1-Dichloroethane 17.8 ug/L 06/29/17 06:425.0EPA 8260
1,2-Dichloroethane 0.96J ug/L 06/29/17 06:421.0EPA 8260
cis-1,2-Dichloroethene 5.4 ug/L 06/29/17 06:425.0EPA 8260
Toluene 0.47J ug/L 06/29/17 06:421.0EPA 8260
Trichloroethene 0.56J ug/L 06/29/17 06:421.0EPA 8260
Vinyl chloride 0.95J ug/L 06/29/17 06:421.0EPA 8260
Alkalinity, Total as CaCO3 99100 ug/L 07/01/17 18:455000SM 2320B
Total Dissolved Solids 105000 ug/L 06/30/17 10:0625000SM 2540C
Chloride 7000 ug/L 07/08/17 01:211000SM 4500-Cl-E
Cyanide 4.3J ug/L 07/07/17 14:1210.0SM 4500-CN-E
92345867006 1203-MW16D
Barium 9.9J ug/L 07/12/17 06:39100EPA 6010
Iron 213J ug/L 07/09/17 00:46300EPA 6010
Manganese 131 ug/L 07/09/17 00:4650.0EPA 6010
Zinc 9.8J ug/L 07/09/17 00:4610.0EPA 6010
Acetone 13.4J ug/L 06/29/17 07:00100EPA 8260
Chloromethane 0.30J ug/L 06/29/17 07:001.0EPA 8260
Alkalinity, Total as CaCO3 51200 ug/L 07/01/17 19:245000SM 2320B
Sulfate 9920J ug/L 07/04/17 04:19250000EPA 300.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Sample: 1203-MW10 Lab ID: 92345867001 Collected: 06/27/17 11:12 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
alpha-BHC ND ug/L 07/07/17 15:58 319-84-606/29/17 13:000.050 0.050 1
beta-BHC ND ug/L 07/07/17 15:58 319-85-706/29/17 13:000.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)80 %07/07/17 15:58 877-09-806/29/17 13:0020-130 1
Decachlorobiphenyl (S)66 %07/07/17 15:58 2051-24-306/29/17 13:0020-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 07/09/17 00:30 7440-36-006/29/17 16:156.0 3.9 1
Arsenic ND ug/L 07/09/17 00:30 7440-38-206/29/17 16:1510.0 5.0 1
Barium 47.4J ug/L 07/12/17 06:23 7440-39-306/29/17 16:15100 2.5 1
Beryllium ND ug/L 07/09/17 00:30 7440-41-706/29/17 16:151.0 0.50 1
Cadmium ND ug/L 07/09/17 00:30 7440-43-906/29/17 16:151.0 0.50 1
Chromium ND ug/L 07/09/17 00:30 7440-47-306/29/17 16:1510.0 2.5 1
Cobalt 121 ug/L 07/09/17 00:30 7440-48-406/29/17 16:1510.0 2.5 1
Copper ND ug/L 07/09/17 00:30 7440-50-806/29/17 16:1510.0 2.5 1
Iron 58100 ug/L 07/09/17 00:30 7439-89-606/29/17 16:15300 25.0 1
Lead 3.0J ug/L 07/09/17 00:30 7439-92-106/29/17 16:1510.0 2.5 1
Manganese 8910 ug/L 07/09/17 00:30 7439-96-506/29/17 16:1550.0 2.5 1
Nickel 4.7J ug/L 07/09/17 00:30 7440-02-006/29/17 16:1550.0 2.5 1
Selenium ND ug/L 07/09/17 00:30 7782-49-206/29/17 16:1510.0 5.0 1
Silver ND ug/L 07/09/17 00:30 7440-22-406/29/17 16:1510.0 2.5 1
Tin ND ug/L 07/09/17 00:30 7440-31-506/29/17 16:155.0 2.5 1
Vanadium 10.6J ug/L 07/09/17 00:30 7440-62-206/29/17 16:1525.0 2.5 1
Zinc 10J ug/L 07/09/17 00:30 7440-66-606/29/17 16:1510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium 0.24J ug/L 07/12/17 14:59 7440-28-007/04/17 05:505.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury 0.17J ug/L 07/07/17 04:15 7439-97-607/05/17 15:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 10.4J ug/L 06/29/17 05:32 67-64-1100 10.0 1
Acrylonitrile ND ug/L 06/29/17 05:32 107-13-1200 1.9 1
Benzene 1.6 ug/L 06/29/17 05:32 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 06/29/17 05:32 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 06/29/17 05:32 75-27-41.0 0.18 1
Bromoform ND ug/L 06/29/17 05:32 75-25-23.0 0.26 1
Bromomethane ND ug/L 06/29/17 05:32 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 06/29/17 05:32 78-93-3100 0.96 1
Carbon disulfide ND ug/L 06/29/17 05:32 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 06/29/17 05:32 56-23-51.0 0.25 1
Chlorobenzene 1.3J ug/L 06/29/17 05:32 108-90-73.0 0.23 1
Chloroethane 0.58J ug/L 06/29/17 05:32 75-00-310.0 0.54 1
Chloroform ND ug/L 06/29/17 05:32 67-66-35.0 0.14 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Sample: 1203-MW10 Lab ID: 92345867001 Collected: 06/27/17 11:12 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Chloromethane 0.31J ug/L 06/29/17 05:32 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 06/29/17 05:32 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 06/29/17 05:32 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 06/29/17 05:32 106-93-41.0 0.27 1
Dibromomethane ND ug/L 06/29/17 05:32 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 06/29/17 05:32 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 06/29/17 05:32 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 06/29/17 05:32 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 06/29/17 05:32 75-71-85.0 0.21 1
1,1-Dichloroethane 0.78J ug/L 06/29/17 05:32 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 06/29/17 05:32 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 06/29/17 05:32 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 3.5J ug/L 06/29/17 05:32 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 06/29/17 05:32 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 06/29/17 05:32 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 06/29/17 05:32 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 06/29/17 05:32 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 06/29/17 05:32 100-41-41.0 0.30 1
2-Hexanone ND ug/L 06/29/17 05:32 591-78-650.0 0.46 1
Iodomethane ND ug/L 06/29/17 05:32 74-88-410.0 0.32 1
Isobutanol ND ug/L 06/29/17 05:32 78-83-1100 35.0 1
Methylene Chloride ND ug/L 06/29/17 05:32 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 06/29/17 05:32 108-10-1100 0.33 1
Styrene ND ug/L 06/29/17 05:32 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 06/29/17 05:32 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 06/29/17 05:32 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 06/29/17 05:32 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 06/29/17 05:32 109-99-910.0 3.1 1
Toluene ND ug/L 06/29/17 05:32 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 06/29/17 05:32 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 06/29/17 05:32 79-00-51.0 0.29 1
Trichloroethene ND ug/L 06/29/17 05:32 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 06/29/17 05:32 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 06/29/17 05:32 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 06/29/17 05:32 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 06/29/17 05:32 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 06/29/17 05:32 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %06/29/17 05:32 460-00-470-130 1
1,2-Dichloroethane-d4 (S)91 %06/29/17 05:32 17060-07-070-130 1
Toluene-d8 (S)111 %06/29/17 05:32 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 102000 ug/L 07/01/17 17:585000 1000 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Sample: 1203-MW10 Lab ID: 92345867001 Collected: 06/27/17 11:12 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 151000 ug/L 06/30/17 10:0525000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 5290J ug/L 07/04/17 00:28 14808-79-8250000 500 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 11500 ug/L 07/08/17 01:15 16887-00-61000 500 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 07/07/17 14:07 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Sample: 1203-MW11 Lab ID: 92345867002 Collected: 06/27/17 11:17 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
alpha-BHC ND ug/L 07/07/17 16:16 319-84-606/29/17 13:000.050 0.050 1
beta-BHC ND ug/L 07/07/17 16:16 319-85-706/29/17 13:000.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)63 %07/07/17 16:16 877-09-806/29/17 13:0020-130 1
Decachlorobiphenyl (S)54 %07/07/17 16:16 2051-24-306/29/17 13:0020-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 07/09/17 00:33 7440-36-006/29/17 16:156.0 3.9 1
Arsenic ND ug/L 07/09/17 00:33 7440-38-206/29/17 16:1510.0 5.0 1
Barium 127 ug/L 07/12/17 06:26 7440-39-306/29/17 16:15100 2.5 1
Beryllium ND ug/L 07/09/17 00:33 7440-41-706/29/17 16:151.0 0.50 1
Cadmium ND ug/L 07/09/17 00:33 7440-43-906/29/17 16:151.0 0.50 1
Chromium 3.9J ug/L 07/09/17 00:33 7440-47-306/29/17 16:1510.0 2.5 1
Cobalt 60.5 ug/L 07/09/17 00:33 7440-48-406/29/17 16:1510.0 2.5 1
Copper ND ug/L 07/09/17 00:33 7440-50-806/29/17 16:1510.0 2.5 1
Iron 67400 ug/L 07/09/17 00:33 7439-89-606/29/17 16:15300 25.0 1
Lead 3.9J ug/L 07/09/17 00:33 7439-92-106/29/17 16:1510.0 2.5 1
Manganese 19900 ug/L 07/12/17 06:42 7439-96-506/29/17 16:15500 25.0 10
Nickel 4.1J ug/L 07/09/17 00:33 7440-02-006/29/17 16:1550.0 2.5 1
Selenium ND ug/L 07/09/17 00:33 7782-49-206/29/17 16:1510.0 5.0 1
Silver ND ug/L 07/09/17 00:33 7440-22-406/29/17 16:1510.0 2.5 1
Tin ND ug/L 07/09/17 00:33 7440-31-506/29/17 16:155.0 2.5 1
Vanadium 20.6J ug/L 07/09/17 00:33 7440-62-206/29/17 16:1525.0 2.5 1
Zinc 19.6 ug/L 07/09/17 00:33 7440-66-606/29/17 16:1510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium 0.36J ug/L 07/12/17 15:01 7440-28-007/04/17 05:505.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 07/07/17 04:22 7439-97-607/05/17 15:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 32.4J ug/L 06/29/17 05:49 67-64-1100 10.0 1
Acrylonitrile ND ug/L 06/29/17 05:49 107-13-1200 1.9 1
Benzene 2.1 ug/L 06/29/17 05:49 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 06/29/17 05:49 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 06/29/17 05:49 75-27-41.0 0.18 1
Bromoform ND ug/L 06/29/17 05:49 75-25-23.0 0.26 1
Bromomethane ND ug/L 06/29/17 05:49 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 06/29/17 05:49 78-93-3100 0.96 1
Carbon disulfide ND ug/L 06/29/17 05:49 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 06/29/17 05:49 56-23-51.0 0.25 1
Chlorobenzene 0.53J ug/L 06/29/17 05:49 108-90-73.0 0.23 1
Chloroethane ND ug/L 06/29/17 05:49 75-00-310.0 0.54 1
Chloroform ND ug/L 06/29/17 05:49 67-66-35.0 0.14 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Sample: 1203-MW11 Lab ID: 92345867002 Collected: 06/27/17 11:17 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Chloromethane 0.20J ug/L 06/29/17 05:49 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 06/29/17 05:49 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 06/29/17 05:49 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 06/29/17 05:49 106-93-41.0 0.27 1
Dibromomethane ND ug/L 06/29/17 05:49 74-95-310.0 0.21 1
1,2-Dichlorobenzene 0.31J ug/L 06/29/17 05:49 95-50-15.0 0.30 1
1,4-Dichlorobenzene 10.6 ug/L 06/29/17 05:49 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 06/29/17 05:49 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 06/29/17 05:49 75-71-85.0 0.21 1
1,1-Dichloroethane 3.3J ug/L 06/29/17 05:49 75-34-35.0 0.32 1
1,2-Dichloroethane 0.26J ug/L 06/29/17 05:49 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 06/29/17 05:49 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 5.8 ug/L 06/29/17 05:49 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 06/29/17 05:49 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 06/29/17 05:49 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 06/29/17 05:49 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 06/29/17 05:49 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 06/29/17 05:49 100-41-41.0 0.30 1
2-Hexanone ND ug/L 06/29/17 05:49 591-78-650.0 0.46 1
Iodomethane ND ug/L 06/29/17 05:49 74-88-410.0 0.32 1
Isobutanol ND ug/L 06/29/17 05:49 78-83-1100 35.0 1
Methylene Chloride ND ug/L 06/29/17 05:49 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 06/29/17 05:49 108-10-1100 0.33 1
Styrene ND ug/L 06/29/17 05:49 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 06/29/17 05:49 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 06/29/17 05:49 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 06/29/17 05:49 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 06/29/17 05:49 109-99-910.0 3.1 1
Toluene ND ug/L 06/29/17 05:49 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 06/29/17 05:49 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 06/29/17 05:49 79-00-51.0 0.29 1
Trichloroethene ND ug/L 06/29/17 05:49 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 06/29/17 05:49 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 06/29/17 05:49 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 06/29/17 05:49 108-05-450.0 0.35 1
Vinyl chloride 0.63J ug/L 06/29/17 05:49 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 06/29/17 05:49 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)103 %06/29/17 05:49 460-00-470-130 1
1,2-Dichloroethane-d4 (S)94 %06/29/17 05:49 17060-07-070-130 1
Toluene-d8 (S)107 %06/29/17 05:49 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 165000 ug/L 07/01/17 18:095000 1000 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Sample: 1203-MW11 Lab ID: 92345867002 Collected: 06/27/17 11:17 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 237000 ug/L 06/30/17 10:0525000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 2120J ug/L 07/04/17 01:18 14808-79-8250000 500 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 29700 ug/L 07/08/17 01:16 16887-00-61000 500 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 07/07/17 14:07 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Sample: 1203-MW12 Lab ID: 92345867003 Collected: 06/27/17 12:00 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
alpha-BHC ND ug/L 07/07/17 16:34 319-84-606/29/17 13:000.050 0.050 1
beta-BHC ND ug/L 07/07/17 16:34 319-85-706/29/17 13:000.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)64 %07/07/17 16:34 877-09-806/29/17 13:0020-130 1
Decachlorobiphenyl (S)23 %07/07/17 16:34 2051-24-306/29/17 13:0020-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 07/09/17 00:36 7440-36-006/29/17 16:156.0 3.9 1
Arsenic ND ug/L 07/09/17 00:36 7440-38-206/29/17 16:1510.0 5.0 1
Barium 81.1J ug/L 07/12/17 06:29 7440-39-306/29/17 16:15100 2.5 1
Beryllium ND ug/L 07/09/17 00:36 7440-41-706/29/17 16:151.0 0.50 1
Cadmium ND ug/L 07/09/17 00:36 7440-43-906/29/17 16:151.0 0.50 1
Chromium 5.8J ug/L 07/09/17 00:36 7440-47-306/29/17 16:1510.0 2.5 1
Cobalt 74.0 ug/L 07/09/17 00:36 7440-48-406/29/17 16:1510.0 2.5 1
Copper ND ug/L 07/09/17 00:36 7440-50-806/29/17 16:1510.0 2.5 1
Iron 51800 ug/L 07/09/17 00:36 7439-89-606/29/17 16:15300 25.0 1
Lead 5.0J ug/L 07/09/17 00:36 7439-92-106/29/17 16:1510.0 2.5 1
Manganese 10200 ug/L 07/12/17 06:45 7439-96-506/29/17 16:15500 25.0 10
Nickel 29.0J ug/L 07/09/17 00:36 7440-02-006/29/17 16:1550.0 2.5 1
Selenium ND ug/L 07/09/17 00:36 7782-49-206/29/17 16:1510.0 5.0 1
Silver ND ug/L 07/09/17 00:36 7440-22-406/29/17 16:1510.0 2.5 1
Tin ND ug/L 07/09/17 00:36 7440-31-506/29/17 16:155.0 2.5 1
Vanadium 15.8J ug/L 07/09/17 00:36 7440-62-206/29/17 16:1525.0 2.5 1
Zinc 11.7 ug/L 07/09/17 00:36 7440-66-606/29/17 16:1510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium 0.094J ug/L 07/12/17 15:03 7440-28-007/04/17 05:505.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 07/07/17 04:25 7439-97-607/05/17 15:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 22.8J ug/L 06/29/17 06:07 67-64-1100 10.0 1
Acrylonitrile ND ug/L 06/29/17 06:07 107-13-1200 1.9 1
Benzene 2.6 ug/L 06/29/17 06:07 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 06/29/17 06:07 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 06/29/17 06:07 75-27-41.0 0.18 1
Bromoform ND ug/L 06/29/17 06:07 75-25-23.0 0.26 1
Bromomethane ND ug/L 06/29/17 06:07 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 06/29/17 06:07 78-93-3100 0.96 1
Carbon disulfide ND ug/L 06/29/17 06:07 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 06/29/17 06:07 56-23-51.0 0.25 1
Chlorobenzene 0.73J ug/L 06/29/17 06:07 108-90-73.0 0.23 1
Chloroethane 2.6J ug/L 06/29/17 06:07 75-00-310.0 0.54 1
Chloroform ND ug/L 06/29/17 06:07 67-66-35.0 0.14 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Sample: 1203-MW12 Lab ID: 92345867003 Collected: 06/27/17 12:00 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Chloromethane 0.27J ug/L 06/29/17 06:07 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 06/29/17 06:07 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 06/29/17 06:07 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 06/29/17 06:07 106-93-41.0 0.27 1
Dibromomethane ND ug/L 06/29/17 06:07 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 06/29/17 06:07 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 06/29/17 06:07 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 06/29/17 06:07 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 06/29/17 06:07 75-71-85.0 0.21 1
1,1-Dichloroethane 26.8 ug/L 06/29/17 06:07 75-34-35.0 0.32 1
1,2-Dichloroethane 0.88J ug/L 06/29/17 06:07 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 06/29/17 06:07 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 9.0 ug/L 06/29/17 06:07 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 06/29/17 06:07 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 06/29/17 06:07 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 06/29/17 06:07 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 06/29/17 06:07 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 06/29/17 06:07 100-41-41.0 0.30 1
2-Hexanone ND ug/L 06/29/17 06:07 591-78-650.0 0.46 1
Iodomethane ND ug/L 06/29/17 06:07 74-88-410.0 0.32 1
Isobutanol ND ug/L 06/29/17 06:07 78-83-1100 35.0 1
Methylene Chloride ND ug/L 06/29/17 06:07 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 06/29/17 06:07 108-10-1100 0.33 1
Styrene ND ug/L 06/29/17 06:07 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 06/29/17 06:07 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 06/29/17 06:07 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 06/29/17 06:07 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 06/29/17 06:07 109-99-910.0 3.1 1
Toluene ND ug/L 06/29/17 06:07 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 06/29/17 06:07 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 06/29/17 06:07 79-00-51.0 0.29 1
Trichloroethene 1.4 ug/L 06/29/17 06:07 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 06/29/17 06:07 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 06/29/17 06:07 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 06/29/17 06:07 108-05-450.0 0.35 1
Vinyl chloride 0.80J ug/L 06/29/17 06:07 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 06/29/17 06:07 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %06/29/17 06:07 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %06/29/17 06:07 17060-07-070-130 1
Toluene-d8 (S)105 %06/29/17 06:07 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 98700 ug/L 07/01/17 18:235000 1000 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Sample: 1203-MW12 Lab ID: 92345867003 Collected: 06/27/17 12:00 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 153000 ug/L 06/30/17 10:0525000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 3200J ug/L 07/04/17 01:34 14808-79-8250000 500 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 10400 ug/L 07/08/17 01:17 16887-00-61000 500 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 07/07/17 14:08 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Sample: 1203-MW13 Lab ID: 92345867004 Collected: 06/27/17 13:10 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
alpha-BHC 0.11 ug/L 07/07/17 16:52 319-84-606/29/17 13:000.050 0.050 1
beta-BHC ND ug/L 07/07/17 16:52 319-85-706/29/17 13:000.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)80 %07/07/17 16:52 877-09-806/29/17 13:0020-130 1
Decachlorobiphenyl (S)51 %07/07/17 16:52 2051-24-306/29/17 13:0020-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 07/09/17 00:39 7440-36-006/29/17 16:156.0 3.9 1
Arsenic ND ug/L 07/09/17 00:39 7440-38-206/29/17 16:1510.0 5.0 1
Barium 76.2J ug/L 07/12/17 06:32 7440-39-306/29/17 16:15100 2.5 1
Beryllium ND ug/L 07/09/17 00:39 7440-41-706/29/17 16:151.0 0.50 1
Cadmium ND ug/L 07/09/17 00:39 7440-43-906/29/17 16:151.0 0.50 1
Chromium ND ug/L 07/09/17 00:39 7440-47-306/29/17 16:1510.0 2.5 1
Cobalt 75.5 ug/L 07/09/17 00:39 7440-48-406/29/17 16:1510.0 2.5 1
Copper ND ug/L 07/09/17 00:39 7440-50-806/29/17 16:1510.0 2.5 1
Iron 1230 ug/L 07/09/17 00:39 7439-89-606/29/17 16:15300 25.0 1
Lead ND ug/L 07/09/17 00:39 7439-92-106/29/17 16:1510.0 2.5 1
Manganese 1750 ug/L 07/09/17 00:39 7439-96-506/29/17 16:1550.0 2.5 1
Nickel 4.5J ug/L 07/09/17 00:39 7440-02-006/29/17 16:1550.0 2.5 1
Selenium ND ug/L 07/09/17 00:39 7782-49-206/29/17 16:1510.0 5.0 1
Silver ND ug/L 07/09/17 00:39 7440-22-406/29/17 16:1510.0 2.5 1
Tin ND ug/L 07/09/17 00:39 7440-31-506/29/17 16:155.0 2.5 1
Vanadium ND ug/L 07/09/17 00:39 7440-62-206/29/17 16:1525.0 2.5 1
Zinc 21.9 ug/L 07/09/17 00:39 7440-66-606/29/17 16:1510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium 0.097J ug/L 07/12/17 15:04 7440-28-007/04/17 05:505.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 07/07/17 04:27 7439-97-607/05/17 15:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 15.9J ug/L 06/29/17 06:25 67-64-1100 10.0 1
Acrylonitrile ND ug/L 06/29/17 06:25 107-13-1200 1.9 1
Benzene 14.8 ug/L 06/29/17 06:25 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 06/29/17 06:25 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 06/29/17 06:25 75-27-41.0 0.18 1
Bromoform ND ug/L 06/29/17 06:25 75-25-23.0 0.26 1
Bromomethane ND ug/L 06/29/17 06:25 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 06/29/17 06:25 78-93-3100 0.96 1
Carbon disulfide ND ug/L 06/29/17 06:25 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 06/29/17 06:25 56-23-51.0 0.25 1
Chlorobenzene 1.1J ug/L 06/29/17 06:25 108-90-73.0 0.23 1
Chloroethane 0.78J ug/L 06/29/17 06:25 75-00-310.0 0.54 1
Chloroform ND ug/L 06/29/17 06:25 67-66-35.0 0.14 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Sample: 1203-MW13 Lab ID: 92345867004 Collected: 06/27/17 13:10 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Chloromethane 0.36J ug/L 06/29/17 06:25 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 06/29/17 06:25 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 06/29/17 06:25 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 06/29/17 06:25 106-93-41.0 0.27 1
Dibromomethane ND ug/L 06/29/17 06:25 74-95-310.0 0.21 1
1,2-Dichlorobenzene 0.80J ug/L 06/29/17 06:25 95-50-15.0 0.30 1
1,4-Dichlorobenzene 16.0 ug/L 06/29/17 06:25 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 06/29/17 06:25 110-57-6100 1.0 1
Dichlorodifluoromethane 0.64J ug/L 06/29/17 06:25 75-71-85.0 0.21 1
1,1-Dichloroethane 24.2 ug/L 06/29/17 06:25 75-34-35.0 0.32 1
1,2-Dichloroethane 1.3 ug/L 06/29/17 06:25 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 06/29/17 06:25 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 23.3 ug/L 06/29/17 06:25 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 06/29/17 06:25 156-60-55.0 0.49 1
1,2-Dichloropropane 0.28J ug/L 06/29/17 06:25 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 06/29/17 06:25 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 06/29/17 06:25 10061-02-61.0 0.26 1
Ethylbenzene 1.5 ug/L 06/29/17 06:25 100-41-41.0 0.30 1
2-Hexanone ND ug/L 06/29/17 06:25 591-78-650.0 0.46 1
Iodomethane ND ug/L 06/29/17 06:25 74-88-410.0 0.32 1
Isobutanol ND ug/L 06/29/17 06:25 78-83-1100 35.0 1
Methylene Chloride 17.3 ug/L 06/29/17 06:25 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 06/29/17 06:25 108-10-1100 0.33 1
Styrene ND ug/L 06/29/17 06:25 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 06/29/17 06:25 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 06/29/17 06:25 79-34-53.0 0.40 1
Tetrachloroethene 6.5 ug/L 06/29/17 06:25 127-18-41.0 0.46 1
Tetrahydrofuran 7.5J ug/L 06/29/17 06:25 109-99-910.0 3.1 1
Toluene 2.1 ug/L 06/29/17 06:25 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 06/29/17 06:25 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 06/29/17 06:25 79-00-51.0 0.29 1
Trichloroethene 10 ug/L 06/29/17 06:25 79-01-61.0 0.47 1
Trichlorofluoromethane 0.26J ug/L 06/29/17 06:25 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 06/29/17 06:25 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 06/29/17 06:25 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 06/29/17 06:25 75-01-41.0 0.62 1
Xylene (Total)63.8 ug/L 06/29/17 06:25 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %06/29/17 06:25 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %06/29/17 06:25 17060-07-070-130 1
Toluene-d8 (S)104 %06/29/17 06:25 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 11300 ug/L 07/01/17 18:355000 1000 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Sample: 1203-MW13 Lab ID: 92345867004 Collected: 06/27/17 13:10 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids ND ug/L 06/30/17 10:0625000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate ND ug/L 07/04/17 01:51 14808-79-8250000 500 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 1550 ug/L 07/08/17 01:20 16887-00-61000 500 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 07/07/17 14:09 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Sample: 1203-MW16S Lab ID: 92345867005 Collected: 06/27/17 12:30 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
alpha-BHC ND ug/L 07/07/17 17:09 319-84-606/29/17 13:000.050 0.050 1
beta-BHC ND ug/L 07/07/17 17:09 319-85-706/29/17 13:000.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)57 %07/07/17 17:09 877-09-806/29/17 13:0020-130 1
Decachlorobiphenyl (S)60 %07/07/17 17:09 2051-24-306/29/17 13:0020-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 07/09/17 00:43 7440-36-006/29/17 16:156.0 3.9 1
Arsenic ND ug/L 07/09/17 00:43 7440-38-206/29/17 16:1510.0 5.0 1
Barium 50.7J ug/L 07/12/17 06:36 7440-39-306/29/17 16:15100 2.5 1
Beryllium ND ug/L 07/09/17 00:43 7440-41-706/29/17 16:151.0 0.50 1
Cadmium ND ug/L 07/09/17 00:43 7440-43-906/29/17 16:151.0 0.50 1
Chromium ND ug/L 07/09/17 00:43 7440-47-306/29/17 16:1510.0 2.5 1
Cobalt 35.4 ug/L 07/09/17 00:43 7440-48-406/29/17 16:1510.0 2.5 1
Copper ND ug/L 07/09/17 00:43 7440-50-806/29/17 16:1510.0 2.5 1
Iron 29100 ug/L 07/09/17 00:43 7439-89-606/29/17 16:15300 25.0 1
Lead ND ug/L 07/09/17 00:43 7439-92-106/29/17 16:1510.0 2.5 1
Manganese 11000 ug/L 07/12/17 06:58 7439-96-506/29/17 16:15500 25.0 10
Nickel ND ug/L 07/09/17 00:43 7440-02-006/29/17 16:1550.0 2.5 1
Selenium ND ug/L 07/09/17 00:43 7782-49-206/29/17 16:1510.0 5.0 1
Silver ND ug/L 07/09/17 00:43 7440-22-406/29/17 16:1510.0 2.5 1
Tin ND ug/L 07/09/17 00:43 7440-31-506/29/17 16:155.0 2.5 1
Vanadium 12.5J ug/L 07/09/17 00:43 7440-62-206/29/17 16:1525.0 2.5 1
Zinc 35.8 ug/L 07/09/17 00:43 7440-66-606/29/17 16:1510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 07/12/17 15:12 7440-28-007/04/17 05:505.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 07/07/17 04:29 7439-97-607/05/17 15:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 33.0J ug/L 06/29/17 06:42 67-64-1100 10.0 1
Acrylonitrile ND ug/L 06/29/17 06:42 107-13-1200 1.9 1
Benzene 1.2 ug/L 06/29/17 06:42 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 06/29/17 06:42 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 06/29/17 06:42 75-27-41.0 0.18 1
Bromoform ND ug/L 06/29/17 06:42 75-25-23.0 0.26 1
Bromomethane ND ug/L 06/29/17 06:42 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 06/29/17 06:42 78-93-3100 0.96 1
Carbon disulfide ND ug/L 06/29/17 06:42 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 06/29/17 06:42 56-23-51.0 0.25 1
Chlorobenzene 0.57J ug/L 06/29/17 06:42 108-90-73.0 0.23 1
Chloroethane 1.6J ug/L 06/29/17 06:42 75-00-310.0 0.54 1
Chloroform ND ug/L 06/29/17 06:42 67-66-35.0 0.14 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Sample: 1203-MW16S Lab ID: 92345867005 Collected: 06/27/17 12:30 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Chloromethane 0.28J ug/L 06/29/17 06:42 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 06/29/17 06:42 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 06/29/17 06:42 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 06/29/17 06:42 106-93-41.0 0.27 1
Dibromomethane ND ug/L 06/29/17 06:42 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 06/29/17 06:42 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 06/29/17 06:42 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 06/29/17 06:42 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 06/29/17 06:42 75-71-85.0 0.21 1
1,1-Dichloroethane 17.8 ug/L 06/29/17 06:42 75-34-35.0 0.32 1
1,2-Dichloroethane 0.96J ug/L 06/29/17 06:42 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 06/29/17 06:42 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 5.4 ug/L 06/29/17 06:42 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 06/29/17 06:42 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 06/29/17 06:42 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 06/29/17 06:42 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 06/29/17 06:42 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 06/29/17 06:42 100-41-41.0 0.30 1
2-Hexanone ND ug/L 06/29/17 06:42 591-78-650.0 0.46 1
Iodomethane ND ug/L 06/29/17 06:42 74-88-410.0 0.32 1
Isobutanol ND ug/L 06/29/17 06:42 78-83-1100 35.0 1
Methylene Chloride ND ug/L 06/29/17 06:42 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 06/29/17 06:42 108-10-1100 0.33 1
Styrene ND ug/L 06/29/17 06:42 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 06/29/17 06:42 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 06/29/17 06:42 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 06/29/17 06:42 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 06/29/17 06:42 109-99-910.0 3.1 1
Toluene 0.47J ug/L 06/29/17 06:42 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 06/29/17 06:42 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 06/29/17 06:42 79-00-51.0 0.29 1
Trichloroethene 0.56J ug/L 06/29/17 06:42 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 06/29/17 06:42 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 06/29/17 06:42 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 06/29/17 06:42 108-05-450.0 0.35 1
Vinyl chloride 0.95J ug/L 06/29/17 06:42 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 06/29/17 06:42 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)97 %06/29/17 06:42 460-00-470-130 1
1,2-Dichloroethane-d4 (S)93 %06/29/17 06:42 17060-07-070-130 1
Toluene-d8 (S)107 %06/29/17 06:42 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 99100 ug/L 07/01/17 18:455000 1000 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Sample: 1203-MW16S Lab ID: 92345867005 Collected: 06/27/17 12:30 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 105000 ug/L 06/30/17 10:0625000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate ND ug/L 07/04/17 02:40 14808-79-8250000 500 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 7000 ug/L 07/08/17 01:21 16887-00-61000 500 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide 4.3J ug/L 07/07/17 14:12 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Sample: 1203-MW16D Lab ID: 92345867006 Collected: 06/27/17 10:18 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 07/09/17 00:46 7440-36-006/29/17 16:156.0 3.9 1
Arsenic ND ug/L 07/09/17 00:46 7440-38-206/29/17 16:1510.0 5.0 1
Barium 9.9J ug/L 07/12/17 06:39 7440-39-306/29/17 16:15100 2.5 1
Beryllium ND ug/L 07/09/17 00:46 7440-41-706/29/17 16:151.0 0.50 1
Cadmium ND ug/L 07/09/17 00:46 7440-43-906/29/17 16:151.0 0.50 1
Chromium ND ug/L 07/09/17 00:46 7440-47-306/29/17 16:1510.0 2.5 1
Cobalt ND ug/L 07/09/17 00:46 7440-48-406/29/17 16:1510.0 2.5 1
Copper ND ug/L 07/09/17 00:46 7440-50-806/29/17 16:1510.0 2.5 1
Iron 213J ug/L 07/09/17 00:46 7439-89-606/29/17 16:15300 25.0 1
Lead ND ug/L 07/09/17 00:46 7439-92-106/29/17 16:1510.0 2.5 1
Manganese 131 ug/L 07/09/17 00:46 7439-96-506/29/17 16:1550.0 2.5 1
Nickel ND ug/L 07/09/17 00:46 7440-02-006/29/17 16:1550.0 2.5 1
Selenium ND ug/L 07/09/17 00:46 7782-49-206/29/17 16:1510.0 5.0 1
Silver ND ug/L 07/09/17 00:46 7440-22-406/29/17 16:1510.0 2.5 1
Vanadium ND ug/L 07/09/17 00:46 7440-62-206/29/17 16:1525.0 2.5 1
Zinc 9.8J ug/L 07/09/17 00:46 7440-66-606/29/17 16:1510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 07/12/17 15:13 7440-28-007/04/17 05:505.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 07/11/17 07:04 7439-97-607/07/17 12:290.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 13.4J ug/L 06/29/17 07:00 67-64-1100 10.0 1
Acrylonitrile ND ug/L 06/29/17 07:00 107-13-1200 1.9 1
Benzene ND ug/L 06/29/17 07:00 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 06/29/17 07:00 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 06/29/17 07:00 75-27-41.0 0.18 1
Bromoform ND ug/L 06/29/17 07:00 75-25-23.0 0.26 1
Bromomethane ND ug/L 06/29/17 07:00 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 06/29/17 07:00 78-93-3100 0.96 1
Carbon disulfide ND ug/L 06/29/17 07:00 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 06/29/17 07:00 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 06/29/17 07:00 108-90-73.0 0.23 1
Chloroethane ND ug/L 06/29/17 07:00 75-00-310.0 0.54 1
Chloroform ND ug/L 06/29/17 07:00 67-66-35.0 0.14 1
Chloromethane 0.30J ug/L 06/29/17 07:00 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 06/29/17 07:00 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 06/29/17 07:00 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 06/29/17 07:00 106-93-41.0 0.27 1
Dibromomethane ND ug/L 06/29/17 07:00 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 06/29/17 07:00 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 06/29/17 07:00 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 06/29/17 07:00 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 06/29/17 07:00 75-34-35.0 0.32 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Sample: 1203-MW16D Lab ID: 92345867006 Collected: 06/27/17 10:18 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloroethane ND ug/L 06/29/17 07:00 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 06/29/17 07:00 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 06/29/17 07:00 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 06/29/17 07:00 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 06/29/17 07:00 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 06/29/17 07:00 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 06/29/17 07:00 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 06/29/17 07:00 100-41-41.0 0.30 1
2-Hexanone ND ug/L 06/29/17 07:00 591-78-650.0 0.46 1
Iodomethane ND ug/L 06/29/17 07:00 74-88-410.0 0.32 1
Isobutanol ND ug/L 06/29/17 07:00 78-83-1100 35.0 1
Methylene Chloride ND ug/L 06/29/17 07:00 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 06/29/17 07:00 108-10-1100 0.33 1
Styrene ND ug/L 06/29/17 07:00 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 06/29/17 07:00 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 06/29/17 07:00 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 06/29/17 07:00 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 06/29/17 07:00 109-99-910.0 3.1 1
Toluene ND ug/L 06/29/17 07:00 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 06/29/17 07:00 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 06/29/17 07:00 79-00-51.0 0.29 1
Trichloroethene ND ug/L 06/29/17 07:00 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 06/29/17 07:00 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 06/29/17 07:00 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 06/29/17 07:00 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 06/29/17 07:00 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 06/29/17 07:00 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)93 %06/29/17 07:00 460-00-470-130 1
1,2-Dichloroethane-d4 (S)94 %06/29/17 07:00 17060-07-070-130 1
Toluene-d8 (S)103 %06/29/17 07:00 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 51200 ug/L 07/01/17 19:245000 1000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 9920J ug/L 07/04/17 04:19 14808-79-8250000 500 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride ND ug/L 07/08/17 01:22 16887-00-61000 500 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367714
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92345867001, 92345867002, 92345867003, 92345867004, 92345867005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037984
Associated Lab Samples:92345867001, 92345867002, 92345867003, 92345867004, 92345867005
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 07/07/17 03:260.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037985LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.72.5 107 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037986MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346178003
2037987
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L M12.5 55 75-12560 8 252.5ND 1.6 1.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367794
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92345867006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2038382
Associated Lab Samples:92345867006
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 07/11/17 06:520.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2038383LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2038384MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346179002
2038385
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 100 75-12599 1 252.5ND 2.5 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
366984
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples: 92345867001, 92345867002, 92345867003, 92345867004, 92345867005, 92345867006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2034185
Associated Lab Samples:92345867001, 92345867002, 92345867003, 92345867004, 92345867005, 92345867006
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 6.0 07/08/17 23:373.9
Arsenic ug/L ND 10.0 07/08/17 23:375.0
Barium ug/L ND 100 07/12/17 05:212.5
Beryllium ug/L ND 1.0 07/08/17 23:370.50
Cadmium ug/L ND 1.0 07/08/17 23:370.50
Chromium ug/L ND 10.0 07/08/17 23:372.5
Cobalt ug/L ND 10.0 07/08/17 23:372.5
Copper ug/L ND 10.0 07/08/17 23:372.5
Iron ug/L ND 300 07/08/17 23:3725.0
Lead ug/L ND 10.0 07/08/17 23:372.5
Manganese ug/L ND 50.0 07/08/17 23:372.5
Nickel ug/L ND 50.0 07/08/17 23:372.5
Selenium ug/L ND 10.0 07/08/17 23:375.0
Silver ug/L ND 10.0 07/08/17 23:372.5
Tin ug/L ND 5.0 07/12/17 05:212.5
Vanadium ug/L ND 25.0 07/08/17 23:372.5
Zinc ug/L ND 10.0 07/12/17 05:215.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2034189LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 521500 104 80-120
Arsenic ug/L 504500 101 80-120
Barium ug/L 477500 95 80-120
Beryllium ug/L 481500 96 80-120
Cadmium ug/L 500500 100 80-120
Chromium ug/L 485500 97 80-120
Cobalt ug/L 508500 102 80-120
Copper ug/L 512500 102 80-120
Iron ug/L 50705000 101 80-120
Lead ug/L 500500 100 80-120
Manganese ug/L 497500 99 80-120
Nickel ug/L 488500 98 80-120
Selenium ug/L 526500 105 80-120
Silver ug/L 258250 103 80-120
Tin ug/L 497500 99 80-120
Vanadium ug/L 489500 98 80-120
Zinc ug/L 513500 103 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2034190MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345849003
2034191
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 105 75-125108 2 20500ND527 538
Arsenic ug/L 500 104 75-125106 2 20500ND518 528
Barium ug/L 500 95 75-12593 1 20500448922 912
Beryllium ug/L 500 99 75-12597 1 20500ND494 487
Cadmium ug/L 500 101 75-125102 1 205002.5 508 514
Chromium ug/L 500 98 75-12598 0 20500ND491 490
Cobalt ug/L 500 100 75-125101 1 2050056.6 554 562
Copper ug/L 500 103 75-125103 0 20500ND516 518
Iron ug/L 5000 100 75-12596 3 20500028207840 7610
Lead ug/L 500 98 75-12599 2 20500ND490 498
Manganese ug/L M15009575-12546 5 2050042504720 4480
Nickel ug/L 500 95 75-12596 1 2050044.9J 521 526
Selenium ug/L 500 104 75-125107 2 20500ND522 534
Silver ug/L 250 104 75-125104 0 20250ND260 260
Tin ug/L 500 103 75-125105 2 20500ND516 526
Vanadium ug/L 500 101 75-125101 0 205005.3J 508 509
Zinc ug/L 500 101 75-125103 2 2050011.0 516 525
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367648
EPA 3010A
EPA 6020B
6020 MET
Associated Lab Samples: 92345867001, 92345867002, 92345867003, 92345867004, 92345867005, 92345867006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037803
Associated Lab Samples:92345867001, 92345867002, 92345867003, 92345867004, 92345867005, 92345867006
Matrix: Water
AnalyzedMDL
Thallium ug/L ND 5.5 07/12/17 16:210.020
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037804LABORATORY CONTROL SAMPLE:
LCSSpike
Thallium ug/L 98.7100 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037805MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345862003
2037806
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Thallium ug/L 100 98 75-125101 3 20100ND98.2 101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
366964
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92345867001, 92345867002, 92345867003, 92345867004, 92345867005, 92345867006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2034085
Associated Lab Samples:92345867001, 92345867002, 92345867003, 92345867004, 92345867005, 92345867006
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 06/29/17 00:130.33
1,1,1-Trichloroethane ug/L ND 1.0 06/29/17 00:130.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 06/29/17 00:130.40
1,1,2-Trichloroethane ug/L ND 1.0 06/29/17 00:130.29
1,1-Dichloroethane ug/L ND 5.0 06/29/17 00:130.32
1,1-Dichloroethene ug/L ND 5.0 06/29/17 00:130.56
1,2,3-Trichloropropane ug/L ND 1.0 06/29/17 00:130.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 06/29/17 00:132.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 06/29/17 00:130.27
1,2-Dichlorobenzene ug/L ND 5.0 06/29/17 00:130.30
1,2-Dichloroethane ug/L ND 1.0 06/29/17 00:130.24
1,2-Dichloropropane ug/L ND 1.0 06/29/17 00:130.27
1,4-Dichlorobenzene ug/L ND 1.0 06/29/17 00:130.33
2-Butanone (MEK)ug/L ND 100 06/29/17 00:130.96
2-Hexanone ug/L ND 50.0 06/29/17 00:130.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 06/29/17 00:130.33
Acetone ug/L ND 100 06/29/17 00:1310.0
Acrylonitrile ug/L ND 200 06/29/17 00:131.9
Benzene ug/L ND 1.0 06/29/17 00:130.25
Bromochloromethane ug/L ND 3.0 06/29/17 00:130.17
Bromodichloromethane ug/L ND 1.0 06/29/17 00:130.18
Bromoform ug/L ND 3.0 06/29/17 00:130.26
Bromomethane ug/L ND 10.0 06/29/17 00:130.29
Carbon disulfide ug/L ND 100 06/29/17 00:131.2
Carbon tetrachloride ug/L ND 1.0 06/29/17 00:130.25
Chlorobenzene ug/L ND 3.0 06/29/17 00:130.23
Chloroethane ug/L ND 10.0 06/29/17 00:130.54
Chloroform ug/L ND 5.0 06/29/17 00:130.14
Chloromethane ug/L ND 1.0 06/29/17 00:130.11
cis-1,2-Dichloroethene ug/L ND 5.0 06/29/17 00:130.19
cis-1,3-Dichloropropene ug/L ND 1.0 06/29/17 00:130.13
Dibromochloromethane ug/L ND 3.0 06/29/17 00:130.21
Dibromomethane ug/L ND 10.0 06/29/17 00:130.21
Dichlorodifluoromethane ug/L ND 5.0 06/29/17 00:130.21
Ethylbenzene ug/L ND 1.0 06/29/17 00:130.30
Iodomethane ug/L ND 10.0 06/29/17 00:130.32
Isobutanol ug/L ND 100 06/29/17 00:1335.0
Methylene Chloride ug/L ND 1.0 06/29/17 00:130.97
Styrene ug/L ND 1.0 06/29/17 00:130.26
Tetrachloroethene ug/L ND 1.0 06/29/17 00:130.46
Tetrahydrofuran ug/L ND 10.0 06/29/17 00:133.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2034085
Associated Lab Samples:92345867001, 92345867002, 92345867003, 92345867004, 92345867005, 92345867006
Matrix: Water
AnalyzedMDL
Toluene ug/L ND 1.0 06/29/17 00:130.26
trans-1,2-Dichloroethene ug/L ND 5.0 06/29/17 00:130.49
trans-1,3-Dichloropropene ug/L ND 1.0 06/29/17 00:130.26
trans-1,4-Dichloro-2-butene ug/L ND 100 06/29/17 00:131.0
Trichloroethene ug/L ND 1.0 06/29/17 00:130.47
Trichlorofluoromethane ug/L ND 1.0 06/29/17 00:130.20
Vinyl acetate ug/L ND 50.0 06/29/17 00:130.35
Vinyl chloride ug/L ND 1.0 06/29/17 00:130.62
Xylene (Total)ug/L ND 5.0 06/29/17 00:130.66
1,2-Dichloroethane-d4 (S)%90 70-130 06/29/17 00:13
4-Bromofluorobenzene (S)%98 70-130 06/29/17 00:13
Toluene-d8 (S)%106 70-130 06/29/17 00:13
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2034086LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.150 102 80-125
1,1,1-Trichloroethane ug/L 52.450 105 71-129
1,1,2,2-Tetrachloroethane ug/L 48.450 97 79-124
1,1,2-Trichloroethane ug/L 52.750 105 85-125
1,1-Dichloroethane ug/L 51.750 103 73-126
1,1-Dichloroethene ug/L 53.350 107 66-135
1,2,3-Trichloropropane ug/L 46.250 92 75-130
1,2-Dibromo-3-chloropropane ug/L 50.850 102 71-133
1,2-Dibromoethane (EDB)ug/L 54.050 108 83-124
1,2-Dichlorobenzene ug/L 48.450 97 80-133
1,2-Dichloroethane ug/L 49.050 98 67-128
1,2-Dichloropropane ug/L 55.150 110 75-132
1,4-Dichlorobenzene ug/L 49.050 98 78-130
2-Butanone (MEK)ug/L 102100 102 61-144
2-Hexanone ug/L 91.1100 91 68-143
4-Methyl-2-pentanone (MIBK)ug/L 91.0J100 91 72-135
Acetone ug/L 106100 106 48-146
Acrylonitrile ug/L 246250 98 40-160
Benzene ug/L 53.350 107 80-125
Bromochloromethane ug/L 51.450 103 71-125
Bromodichloromethane ug/L 53.650 107 78-124
Bromoform ug/L 41.450 83 71-128
Bromomethane ug/L 59.550 119 40-160
Carbon disulfide ug/L 51.2J50 102 50-160
Carbon tetrachloride ug/L 49.650 99 69-131
Chlorobenzene ug/L 49.150 98 81-122
Chloroethane ug/L 43.950 88 39-148
Chloroform ug/L 49.850 100 73-127
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2034086LABORATORY CONTROL SAMPLE:
LCSSpike
Chloromethane ug/L 51.550 103 44-146
cis-1,2-Dichloroethene ug/L 51.250 102 74-124
cis-1,3-Dichloropropene ug/L 55.050 110 72-132
Dibromochloromethane ug/L 56.250 112 78-125
Dibromomethane ug/L 49.950 100 82-120
Dichlorodifluoromethane ug/L 48.950 98 34-157
Ethylbenzene ug/L 48.350 97 79-121
Iodomethane ug/L 113100 113 39-154
Isobutanol ug/L 9261000 93 34-160
Methylene Chloride ug/L 55.050 110 64-133
Styrene ug/L 50.150 100 84-126
Tetrachloroethene ug/L 47.150 94 78-122
Tetrahydrofuran ug/L 526500 105 69-148
Toluene ug/L 48.950 98 80-121
trans-1,2-Dichloroethene ug/L 50.650 101 71-127
trans-1,3-Dichloropropene ug/L 53.450 107 69-141
trans-1,4-Dichloro-2-butene ug/L 63.4J50 127 40-160
Trichloroethene ug/L 55.450 111 78-122
Trichlorofluoromethane ug/L 48.950 98 53-137
Vinyl acetate ug/L 104100 104 40-160
Vinyl chloride ug/L 47.450 95 58-137
Xylene (Total)ug/L 146150 97 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%95 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2034088MATRIX SPIKE SAMPLE:
MSSpike
Result
92345867006
1,1,1,2-Tetrachloroethane ug/L 19.020 95 70-130ND
1,1,1-Trichloroethane ug/L 21.820 109 70-130ND
1,1,2,2-Tetrachloroethane ug/L 18.820 94 70-130ND
1,1,2-Trichloroethane ug/L 18.420 92 70-130ND
1,1-Dichloroethane ug/L 22.120 110 70-130ND
1,1-Dichloroethene ug/L 22.320 112 70-166ND
1,2,3-Trichloropropane ug/L 17.920 90 70-130ND
1,2-Dibromo-3-chloropropane ug/L 17.820 89 70-130ND
1,2-Dibromoethane (EDB)ug/L 19.720 99 70-130ND
1,2-Dichlorobenzene ug/L 20.120 100 70-130ND
1,2-Dichloroethane ug/L 20.420 102 70-130ND
1,2-Dichloropropane ug/L 21.120 106 70-130ND
1,4-Dichlorobenzene ug/L 19.820 99 70-130ND
2-Butanone (MEK)ug/L 35.6J40 89 70-130ND
2-Hexanone ug/L 36.3J40 91 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 37.2J40 93 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2034088MATRIX SPIKE SAMPLE:
MSSpike
Result
92345867006
Acetone ug/L 49.4J40 90 70-13013.4J
Acrylonitrile ug/L 94.2J100 94 70-130ND
Benzene ug/L 21.620 108 70-148ND
Bromochloromethane ug/L 21.720 109 70-130ND
Bromodichloromethane ug/L 21.020 105 70-130ND
Bromoform ug/L 14.920 75 70-130ND
Bromomethane ug/L 21.020 105 70-130ND
Carbon disulfide ug/L 21.5J20 108 70-130ND
Carbon tetrachloride ug/L 22.220 111 70-130ND
Chlorobenzene ug/L 20.320 102 70-146ND
Chloroethane ug/L 20.520 102 70-130ND
Chloroform ug/L 20.620 103 70-130ND
Chloromethane ug/L 22.120 109 70-1300.30J
cis-1,2-Dichloroethene ug/L 22.020 110 70-130ND
cis-1,3-Dichloropropene ug/L 20.320 102 70-130ND
Dibromochloromethane ug/L 19.320 97 70-130ND
Dibromomethane ug/L 20.420 102 70-130ND
Dichlorodifluoromethane ug/L 20.220 101 70-130ND
Ethylbenzene ug/L 20.720 104 70-130ND
Iodomethane ug/L 36.340 91 70-130ND
Isobutanol ug/L 363400 91 70-130ND
Methylene Chloride ug/L 20.820 104 70-130ND
Styrene ug/L 19.520 98 70-130ND
Tetrachloroethene ug/L 19.720 99 70-130ND
Tetrahydrofuran ug/L 194200 97 70-130ND
Toluene ug/L 21.420 107 70-155ND
trans-1,2-Dichloroethene ug/L 20.920 104 70-130ND
trans-1,3-Dichloropropene ug/L 20.220 101 70-130ND
trans-1,4-Dichloro-2-butene ug/L 16.4J20 82 70-130ND
Trichloroethene ug/L 21.120 105 69-151ND
Trichlorofluoromethane ug/L 20.620 103 70-130ND
Vinyl acetate ug/L 33.2J40 83 70-130ND
Vinyl chloride ug/L 19.820 99 70-130ND
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92345867005
2034087SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 17.5 2 3017.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92345867005
2034087SAMPLE DUPLICATE:
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L 0.95J 300.96J
1,2-Dichloropropane ug/L 0.33J 30ND
1,4-Dichlorobenzene ug/L 6.3 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L 12.3J 3033.0J
Acrylonitrile ug/L ND 30ND
Benzene ug/L 1.1 12 301.2
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 0.62J 300.57J
Chloroethane ug/L 1.6J 1 301.6J
Chloroform ug/L ND 30ND
Chloromethane ug/L 0.19J 300.28J
cis-1,2-Dichloroethene ug/L 5.1 5 305.4
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Isobutanol ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L 0.39J 300.47J
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 300.56J
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L 0.75J 300.95J
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%90 393
4-Bromofluorobenzene (S)%102 497
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92345867005
2034087SAMPLE DUPLICATE:
Toluene-d8 (S)%109 2107
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367064
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples: 92345867001, 92345867002, 92345867003, 92345867004, 92345867005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2034599
Associated Lab Samples:92345867001, 92345867002, 92345867003, 92345867004, 92345867005
Matrix: Water
AnalyzedMDL
alpha-BHC ug/L ND 0.050 07/06/17 22:480.050
beta-BHC ug/L ND 0.050 07/06/17 22:480.050
Decachlorobiphenyl (S)%58 20-130 07/06/17 22:48
Tetrachloro-m-xylene (S)%77 20-130 07/06/17 22:48
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2034600LABORATORY CONTROL SAMPLE:
LCSSpike
alpha-BHC ug/L 0.20.25 82 20-150
beta-BHC ug/L 0.18.25 74 20-150
Decachlorobiphenyl (S)%88 20-130
Tetrachloro-m-xylene (S)%87 20-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2034601MATRIX SPIKE SAMPLE:
MSSpike
Result
92345640011
alpha-BHC ug/L 0.14.25 58 20-150ND
beta-BHC ug/L 0.12.25 49 20-150ND
Decachlorobiphenyl (S)%61 20-130
Tetrachloro-m-xylene (S)%63 20-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92345640012
2034602SAMPLE DUPLICATE:
alpha-BHC ug/L ND 30ND
beta-BHC ug/L ND 30ND
Decachlorobiphenyl (S)%62 867
Tetrachloro-m-xylene (S)%74 3353
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367212
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples: 92345867001, 92345867002, 92345867003, 92345867004, 92345867005, 92345867006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2035586
Associated Lab Samples:92345867001, 92345867002, 92345867003, 92345867004, 92345867005, 92345867006
Matrix: Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 07/01/17 14:331000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2035587LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4990050000 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2035588MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345640002
2035589
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L M1500009380-120128 2 2550000732 mg/L 778000 796000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2035590MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345867005
2035591
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 90 80-12089 0 255000099100144000 143000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367250
SM 2540C
SM 2540C
2540C Total Dissolved Solids
Associated Lab Samples: 92345867001, 92345867002, 92345867003, 92345867004, 92345867005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2035726
Associated Lab Samples:92345867001, 92345867002, 92345867003, 92345867004, 92345867005
Matrix: Water
AnalyzedMDL
Total Dissolved Solids ug/L ND 25000 06/30/17 10:0325000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2035727LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids ug/L 234000250000 94 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92345864001
2035728SAMPLE DUPLICATE:
Total Dissolved Solids ug/L ND 5ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92346154002
2035729SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 26000 D67528000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367506
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples: 92345867001, 92345867002, 92345867003, 92345867004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037142
Associated Lab Samples:92345867001, 92345867002, 92345867003, 92345867004
Matrix: Water
AnalyzedMDL
Sulfate ug/L ND 250000 07/03/17 13:29500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037143LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 52600J50000 105 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037144MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345945089
2037145
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 50000 101 90-110102 1 105000032.0 mg/L 82500J 83200J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037206MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345867001
2037207
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 50000 108 90-110109 1 10500005290J59500J 59900J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367508
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples: 92345867005, 92345867006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037152
Associated Lab Samples:92345867005, 92345867006
Matrix: Water
AnalyzedMDL
Sulfate ug/L ND 250000 07/04/17 02:07500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037153LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 52600J50000 105 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037154MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345867005
2037155
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 50000 109 90-110110 1 1050000ND54900J 55600J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037156MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345640023
2037157
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 50000 107 90-110107 1 10500009.3 mg/L 62700J 63000J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
368012
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples: 92345867001, 92345867002, 92345867003, 92345867004, 92345867005, 92345867006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2039600
Associated Lab Samples:92345867001, 92345867002, 92345867003, 92345867004, 92345867005, 92345867006
Matrix: Water
AnalyzedMDL
Chloride ug/L ND 1000 07/08/17 01:00500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2039601LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 2160020000 108 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2039602MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346191001
2039603
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M11000011990-110118 1 10100001.6 mg/L 13500 13400
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2039604MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345867003
2039605
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 10000 109 90-110108 0 10100001040021300 21300
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367925
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples: 92345867001, 92345867002, 92345867003, 92345867004, 92345867005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2039007
Associated Lab Samples:92345867001, 92345867002, 92345867003, 92345867004, 92345867005
Matrix: Water
AnalyzedMDL
Cyanide ug/L ND 10.0 07/07/17 13:474.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2039008LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 99.9100 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2039009MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346296007
2039010
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L M1,R11003980-12054 19 101000.030mg/L 69.3 83.9
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2039011MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345640016
2039012
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 93 80-12091 2 10100ND94.0 91.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 49
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 49
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92345867001 367064 3672261203-MW10 EPA 3510 EPA 8081
92345867002 367064 3672261203-MW11 EPA 3510 EPA 8081
92345867003 367064 3672261203-MW12 EPA 3510 EPA 8081
92345867004 367064 3672261203-MW13 EPA 3510 EPA 8081
92345867005 367064 3672261203-MW16S EPA 3510 EPA 8081
92345867001 366984 3680021203-MW10 EPA 3010A EPA 6010
92345867002 366984 3680021203-MW11 EPA 3010A EPA 6010
92345867003 366984 3680021203-MW12 EPA 3010A EPA 6010
92345867004 366984 3680021203-MW13 EPA 3010A EPA 6010
92345867005 366984 3680021203-MW16S EPA 3010A EPA 6010
92345867006 366984 3680021203-MW16D EPA 3010A EPA 6010
92345867001 367648 3684581203-MW10 EPA 3010A EPA 6020B
92345867002 367648 3684581203-MW11 EPA 3010A EPA 6020B
92345867003 367648 3684581203-MW12 EPA 3010A EPA 6020B
92345867004 367648 3684581203-MW13 EPA 3010A EPA 6020B
92345867005 367648 3684581203-MW16S EPA 3010A EPA 6020B
92345867006 367648 3684581203-MW16D EPA 3010A EPA 6020B
92345867001 367714 3680241203-MW10 EPA 7470 EPA 7470
92345867002 367714 3680241203-MW11 EPA 7470 EPA 7470
92345867003 367714 3680241203-MW12 EPA 7470 EPA 7470
92345867004 367714 3680241203-MW13 EPA 7470 EPA 7470
92345867005 367714 3680241203-MW16S EPA 7470 EPA 7470
92345867006 367794 3683251203-MW16D EPA 7470 EPA 7470
92345867001 3669641203-MW10 EPA 8260
92345867002 3669641203-MW11 EPA 8260
92345867003 3669641203-MW12 EPA 8260
92345867004 3669641203-MW13 EPA 8260
92345867005 3669641203-MW16S EPA 8260
92345867006 3669641203-MW16D EPA 8260
92345867001 3672121203-MW10 SM 2320B
92345867002 3672121203-MW11 SM 2320B
92345867003 3672121203-MW12 SM 2320B
92345867004 3672121203-MW13 SM 2320B
92345867005 3672121203-MW16S SM 2320B
92345867006 3672121203-MW16D SM 2320B
92345867001 3672501203-MW10 SM 2540C
92345867002 3672501203-MW11 SM 2540C
92345867003 3672501203-MW12 SM 2540C
92345867004 3672501203-MW13 SM 2540C
92345867005 3672501203-MW16S SM 2540C
92345867001 3675061203-MW10 EPA 300.0
92345867002 3675061203-MW11 EPA 300.0
92345867003 3675061203-MW12 EPA 300.0
92345867004 3675061203-MW13 EPA 300.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 49
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92345867
JOHNS R. C&D/MSWLF GW
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92345867005 3675081203-MW16S EPA 300.0
92345867006 3675081203-MW16D EPA 300.0
92345867001 3680121203-MW10 SM 4500-Cl-E
92345867002 3680121203-MW11 SM 4500-Cl-E
92345867003 3680121203-MW12 SM 4500-Cl-E
92345867004 3680121203-MW13 SM 4500-Cl-E
92345867005 3680121203-MW16S SM 4500-Cl-E
92345867006 3680121203-MW16D SM 4500-Cl-E
92345867001 3679251203-MW10 SM 4500-CN-E
92345867002 3679251203-MW11 SM 4500-CN-E
92345867003 3679251203-MW12 SM 4500-CN-E
92345867004 3679251203-MW13 SM 4500-CN-E
92345867005 3679251203-MW16S SM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/15/2017 07:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 49
Page 47 of 49
Page 48 of 49
Page 49 of 49
#=CL#
July 12, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92345864
92345864
Project:
Pace Project No.:
RE:
Mr. Van BurbachJoyce Engineering-Greensboro2211 West Meadowview RdBoone Bldg, Suite 101Greensboro, NC 27407
JOHNS R. BACKGROUND
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on June 28, 2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager(704)875-9092
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 30
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 30
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Lab ID Sample ID Matrix Date Collected Date Received
92345864001 1203-MW21 Water 06/27/17 10:45 06/28/17 09:28
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 30
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92345864001 1203-MW21 EPA 8081 4 PASI-CRES
EPA 6010 17 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AKAL
EPA 8260 53 PASI-CZDO
SM 2320B 1 PASI-AKDF1
SM 2540C 1 PASI-ASLB
SM 4500-S2D 1 PASI-AMVC
EPA 300.0 1 PASI-ACDC
SM 4500-Cl-E 1 PASI-ABRJ
SM 4500-CN-E 1 PASI-AAES2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 30
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92345864001 1203-MW21
Barium 18.8J ug/L 07/12/17 06:20100EPA 6010
Copper 3.9J ug/L 07/09/17 00:2610.0EPA 6010
Iron 2340 ug/L 07/09/17 00:26300EPA 6010
Manganese 60.3 ug/L 07/09/17 00:2650.0EPA 6010
Vanadium 9.4J ug/L 07/09/17 00:2625.0EPA 6010
Zinc 8.2J ug/L 07/09/17 00:2610.0EPA 6010
Acetone 35.8J ug/L 06/30/17 00:44 L1100EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Sample: 1203-MW21 Lab ID: 92345864001 Collected: 06/27/17 10:45 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
alpha-BHC ND ug/L 07/07/17 15:40 319-84-606/29/17 13:000.050 0.050 1
beta-BHC ND ug/L 07/07/17 15:40 319-85-706/29/17 13:000.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)65 %07/07/17 15:40 877-09-806/29/17 13:0020-130 1
Decachlorobiphenyl (S)52 %07/07/17 15:40 2051-24-306/29/17 13:0020-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 07/09/17 00:26 7440-36-006/29/17 16:156.0 3.9 1
Arsenic ND ug/L 07/09/17 00:26 7440-38-206/29/17 16:1510.0 5.0 1
Barium 18.8J ug/L 07/12/17 06:20 7440-39-306/29/17 16:15100 2.5 1
Beryllium ND ug/L 07/09/17 00:26 7440-41-706/29/17 16:151.0 0.50 1
Cadmium ND ug/L 07/09/17 00:26 7440-43-906/29/17 16:151.0 0.50 1
Chromium ND ug/L 07/09/17 00:26 7440-47-306/29/17 16:1510.0 2.5 1
Cobalt ND ug/L 07/09/17 00:26 7440-48-406/29/17 16:1510.0 2.5 1
Copper 3.9J ug/L 07/09/17 00:26 7440-50-806/29/17 16:1510.0 2.5 1
Iron 2340 ug/L 07/09/17 00:26 7439-89-606/29/17 16:15300 25.0 1
Lead ND ug/L 07/09/17 00:26 7439-92-106/29/17 16:1510.0 2.5 1
Manganese 60.3 ug/L 07/09/17 00:26 7439-96-506/29/17 16:1550.0 2.5 1
Nickel ND ug/L 07/09/17 00:26 7440-02-006/29/17 16:1550.0 2.5 1
Selenium ND ug/L 07/09/17 00:26 7782-49-206/29/17 16:1510.0 5.0 1
Silver ND ug/L 07/09/17 00:26 7440-22-406/29/17 16:1510.0 2.5 1
Tin ND ug/L 07/09/17 00:26 7440-31-506/29/17 16:155.0 2.5 1
Vanadium 9.4J ug/L 07/09/17 00:26 7440-62-206/29/17 16:1525.0 2.5 1
Zinc 8.2J ug/L 07/09/17 00:26 7440-66-606/29/17 16:1510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 07/08/17 21:10 7440-28-007/01/17 07:255.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 07/07/17 04:01 7439-97-607/05/17 15:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 35.8J ug/L 06/30/17 00:44 67-64-1 L1100 10.0 1
Acrylonitrile ND ug/L 06/30/17 00:44 107-13-1200 1.9 1
Benzene ND ug/L 06/30/17 00:44 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 06/30/17 00:44 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 06/30/17 00:44 75-27-41.0 0.18 1
Bromoform ND ug/L 06/30/17 00:44 75-25-23.0 0.26 1
Bromomethane ND ug/L 06/30/17 00:44 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 06/30/17 00:44 78-93-3 L1100 0.96 1
Carbon disulfide ND ug/L 06/30/17 00:44 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 06/30/17 00:44 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 06/30/17 00:44 108-90-73.0 0.23 1
Chloroethane ND ug/L 06/30/17 00:44 75-00-310.0 0.54 1
Chloroform ND ug/L 06/30/17 00:44 67-66-35.0 0.14 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Sample: 1203-MW21 Lab ID: 92345864001 Collected: 06/27/17 10:45 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Chloromethane ND ug/L 06/30/17 00:44 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 06/30/17 00:44 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 06/30/17 00:44 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 06/30/17 00:44 106-93-41.0 0.27 1
Dibromomethane ND ug/L 06/30/17 00:44 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 06/30/17 00:44 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 06/30/17 00:44 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 06/30/17 00:44 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 06/30/17 00:44 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 06/30/17 00:44 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 06/30/17 00:44 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 06/30/17 00:44 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 06/30/17 00:44 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 06/30/17 00:44 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 06/30/17 00:44 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 06/30/17 00:44 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 06/30/17 00:44 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 06/30/17 00:44 100-41-41.0 0.30 1
2-Hexanone ND ug/L 06/30/17 00:44 591-78-650.0 0.46 1
Iodomethane ND ug/L 06/30/17 00:44 74-88-410.0 0.32 1
Isobutanol ND ug/L 06/30/17 00:44 78-83-1100 35.0 1
Methylene Chloride ND ug/L 06/30/17 00:44 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 06/30/17 00:44 108-10-1100 0.33 1
Styrene ND ug/L 06/30/17 00:44 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 06/30/17 00:44 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 06/30/17 00:44 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 06/30/17 00:44 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 06/30/17 00:44 109-99-910.0 3.1 1
Toluene ND ug/L 06/30/17 00:44 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 06/30/17 00:44 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 06/30/17 00:44 79-00-51.0 0.29 1
Trichloroethene ND ug/L 06/30/17 00:44 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 06/30/17 00:44 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 06/30/17 00:44 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 06/30/17 00:44 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 06/30/17 00:44 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 06/30/17 00:44 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)102 %06/30/17 00:44 460-00-470-130 1
1,2-Dichloroethane-d4 (S)114 %06/30/17 00:44 17060-07-070-130 1
Toluene-d8 (S)106 %06/30/17 00:44 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 ND ug/L 07/01/17 17:245000 1000 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Sample: 1203-MW21 Lab ID: 92345864001 Collected: 06/27/17 10:45 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids ND ug/L 06/30/17 10:0425000 25000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 07/03/17 20:00 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate ND ug/L 07/04/17 00:12 14808-79-8250000 500 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride ND ug/L 07/08/17 01:14 16887-00-61000 500 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 07/07/17 14:06 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367714
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037984
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 07/07/17 03:260.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037985LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.72.5 107 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037986MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346178003
2037987
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L M12.5 55 75-12560 8 252.5ND 1.6 1.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
366984
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2034185
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 6.0 07/08/17 23:373.9
Arsenic ug/L ND 10.0 07/08/17 23:375.0
Barium ug/L ND 100 07/12/17 05:212.5
Beryllium ug/L ND 1.0 07/08/17 23:370.50
Cadmium ug/L ND 1.0 07/08/17 23:370.50
Chromium ug/L ND 10.0 07/08/17 23:372.5
Cobalt ug/L ND 10.0 07/08/17 23:372.5
Copper ug/L ND 10.0 07/08/17 23:372.5
Iron ug/L ND 300 07/08/17 23:3725.0
Lead ug/L ND 10.0 07/08/17 23:372.5
Manganese ug/L ND 50.0 07/08/17 23:372.5
Nickel ug/L ND 50.0 07/08/17 23:372.5
Selenium ug/L ND 10.0 07/08/17 23:375.0
Silver ug/L ND 10.0 07/08/17 23:372.5
Tin ug/L ND 5.0 07/12/17 05:212.5
Vanadium ug/L ND 25.0 07/08/17 23:372.5
Zinc ug/L ND 10.0 07/12/17 05:215.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2034189LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 521500 104 80-120
Arsenic ug/L 504500 101 80-120
Barium ug/L 477500 95 80-120
Beryllium ug/L 481500 96 80-120
Cadmium ug/L 500500 100 80-120
Chromium ug/L 485500 97 80-120
Cobalt ug/L 508500 102 80-120
Copper ug/L 512500 102 80-120
Iron ug/L 50705000 101 80-120
Lead ug/L 500500 100 80-120
Manganese ug/L 497500 99 80-120
Nickel ug/L 488500 98 80-120
Selenium ug/L 526500 105 80-120
Silver ug/L 258250 103 80-120
Tin ug/L 497500 99 80-120
Vanadium ug/L 489500 98 80-120
Zinc ug/L 513500 103 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2034190MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345849003
2034191
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 105 75-125108 2 20500ND527 538
Arsenic ug/L 500 104 75-125106 2 20500ND518 528
Barium ug/L 500 95 75-12593 1 20500448922 912
Beryllium ug/L 500 99 75-12597 1 20500ND494 487
Cadmium ug/L 500 101 75-125102 1 205002.5 508 514
Chromium ug/L 500 98 75-12598 0 20500ND491 490
Cobalt ug/L 500 100 75-125101 1 2050056.6 554 562
Copper ug/L 500 103 75-125103 0 20500ND516 518
Iron ug/L 5000 100 75-12596 3 20500028207840 7610
Lead ug/L 500 98 75-12599 2 20500ND490 498
Manganese ug/L M15009575-12546 5 2050042504720 4480
Nickel ug/L 500 95 75-12596 1 2050044.9J 521 526
Selenium ug/L 500 104 75-125107 2 20500ND522 534
Silver ug/L 250 104 75-125104 0 20250ND260 260
Tin ug/L 500 103 75-125105 2 20500ND516 526
Vanadium ug/L 500 101 75-125101 0 205005.3J 508 509
Zinc ug/L 500 101 75-125103 2 2050011.0 516 525
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367201
EPA 3010A
EPA 6020B
6020 MET
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2035540
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Thallium ug/L ND 5.5 07/08/17 20:220.020
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2035541LABORATORY CONTROL SAMPLE:
LCSSpike
Thallium ug/L 103100 103 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2035542MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345640003
2035543
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Thallium ug/L 100 100 75-125101 1 20100ND100 101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367160
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2035365
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 06/29/17 23:520.33
1,1,1-Trichloroethane ug/L ND 1.0 06/29/17 23:520.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 06/29/17 23:520.40
1,1,2-Trichloroethane ug/L ND 1.0 06/29/17 23:520.29
1,1-Dichloroethane ug/L ND 5.0 06/29/17 23:520.32
1,1-Dichloroethene ug/L ND 5.0 06/29/17 23:520.56
1,2,3-Trichloropropane ug/L ND 1.0 06/29/17 23:520.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 06/29/17 23:522.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 06/29/17 23:520.27
1,2-Dichlorobenzene ug/L ND 5.0 06/29/17 23:520.30
1,2-Dichloroethane ug/L ND 1.0 06/29/17 23:520.24
1,2-Dichloropropane ug/L ND 1.0 06/29/17 23:520.27
1,4-Dichlorobenzene ug/L ND 1.0 06/29/17 23:520.33
2-Butanone (MEK)ug/L ND 100 06/29/17 23:520.96
2-Hexanone ug/L ND 50.0 06/29/17 23:520.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 06/29/17 23:520.33
Acetone ug/L ND 100 06/29/17 23:5210.0
Acrylonitrile ug/L ND 200 06/29/17 23:521.9
Benzene ug/L ND 1.0 06/29/17 23:520.25
Bromochloromethane ug/L ND 3.0 06/29/17 23:520.17
Bromodichloromethane ug/L ND 1.0 06/29/17 23:520.18
Bromoform ug/L ND 3.0 06/29/17 23:520.26
Bromomethane ug/L ND 10.0 06/29/17 23:520.29
Carbon disulfide ug/L ND 100 06/29/17 23:521.2
Carbon tetrachloride ug/L ND 1.0 06/29/17 23:520.25
Chlorobenzene ug/L ND 3.0 06/29/17 23:520.23
Chloroethane ug/L ND 10.0 06/29/17 23:520.54
Chloroform ug/L ND 5.0 06/29/17 23:520.14
Chloromethane ug/L ND 1.0 06/29/17 23:520.11
cis-1,2-Dichloroethene ug/L ND 5.0 06/29/17 23:520.19
cis-1,3-Dichloropropene ug/L ND 1.0 06/29/17 23:520.13
Dibromochloromethane ug/L ND 3.0 06/29/17 23:520.21
Dibromomethane ug/L ND 10.0 06/29/17 23:520.21
Dichlorodifluoromethane ug/L ND 5.0 06/29/17 23:520.21
Ethylbenzene ug/L ND 1.0 06/29/17 23:520.30
Iodomethane ug/L ND 10.0 06/29/17 23:520.32
Isobutanol ug/L ND 100 06/29/17 23:5235.0
Methylene Chloride ug/L ND 1.0 06/29/17 23:520.97
Styrene ug/L ND 1.0 06/29/17 23:520.26
Tetrachloroethene ug/L ND 1.0 06/29/17 23:520.46
Tetrahydrofuran ug/L ND 10.0 06/29/17 23:523.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2035365
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Toluene ug/L ND 1.0 06/29/17 23:520.26
trans-1,2-Dichloroethene ug/L ND 5.0 06/29/17 23:520.49
trans-1,3-Dichloropropene ug/L ND 1.0 06/29/17 23:520.26
trans-1,4-Dichloro-2-butene ug/L ND 100 06/29/17 23:521.0
Trichloroethene ug/L ND 1.0 06/29/17 23:520.47
Trichlorofluoromethane ug/L ND 1.0 06/29/17 23:520.20
Vinyl acetate ug/L ND 50.0 06/29/17 23:520.35
Vinyl chloride ug/L ND 1.0 06/29/17 23:520.62
Xylene (Total)ug/L ND 5.0 06/29/17 23:520.66
1,2-Dichloroethane-d4 (S)%112 70-130 06/29/17 23:52
4-Bromofluorobenzene (S)%103 70-130 06/29/17 23:52
Toluene-d8 (S)%105 70-130 06/29/17 23:52
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2035366LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 47.350 95 80-125
1,1,1-Trichloroethane ug/L 45.050 90 71-129
1,1,2,2-Tetrachloroethane ug/L 48.550 97 79-124
1,1,2-Trichloroethane ug/L 46.650 93 85-125
1,1-Dichloroethane ug/L 45.750 91 73-126
1,1-Dichloroethene ug/L 47.950 96 66-135
1,2,3-Trichloropropane ug/L 49.150 98 75-130
1,2-Dibromo-3-chloropropane ug/L 53.250 106 71-133
1,2-Dibromoethane (EDB)ug/L 47.850 96 83-124
1,2-Dichlorobenzene ug/L 42.050 84 80-133
1,2-Dichloroethane ug/L 46.150 92 67-128
1,2-Dichloropropane ug/L 46.050 92 75-132
1,4-Dichlorobenzene ug/L 40.650 81 78-130
2-Butanone (MEK)ug/L 148 L1100148 61-144
2-Hexanone ug/L 128100 128 68-143
4-Methyl-2-pentanone (MIBK)ug/L 113100 113 72-135
Acetone ug/L 160 L1100160 48-146
Acrylonitrile ug/L 336250 134 40-160
Benzene ug/L 45.850 92 80-125
Bromochloromethane ug/L 47.250 94 71-125
Bromodichloromethane ug/L 44.650 89 78-124
Bromoform ug/L 44.350 89 71-128
Bromomethane ug/L 32.850 66 40-160
Carbon disulfide ug/L 45.4J50 91 50-160
Carbon tetrachloride ug/L 41.850 84 69-131
Chlorobenzene ug/L 42.250 84 81-122
Chloroethane ug/L 41.750 83 39-148
Chloroform ug/L 45.950 92 73-127
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2035366LABORATORY CONTROL SAMPLE:
LCSSpike
Chloromethane ug/L 45.650 91 44-146
cis-1,2-Dichloroethene ug/L 49.550 99 74-124
cis-1,3-Dichloropropene ug/L 46.650 93 72-132
Dibromochloromethane ug/L 49.850 100 78-125
Dibromomethane ug/L 45.550 91 82-120
Dichlorodifluoromethane ug/L 49.750 99 34-157
Ethylbenzene ug/L 41.850 84 79-121
Iodomethane ug/L 65.3100 65 39-154
Isobutanol ug/L 14301000 143 34-160
Methylene Chloride ug/L 53.250 106 64-133
Styrene ug/L 42.550 85 84-126
Tetrachloroethene ug/L 40.450 81 78-122
Tetrahydrofuran ug/L 718500 144 69-148
Toluene ug/L 43.150 86 80-121
trans-1,2-Dichloroethene ug/L 46.250 92 71-127
trans-1,3-Dichloropropene ug/L 43.950 88 69-141
trans-1,4-Dichloro-2-butene ug/L 62.3J50 125 40-160
Trichloroethene ug/L 44.550 89 78-122
Trichlorofluoromethane ug/L 44.450 89 53-137
Vinyl acetate ug/L 105100 105 40-160
Vinyl chloride ug/L 46.050 92 58-137
Xylene (Total)ug/L 126150 84 81-126
1,2-Dichloroethane-d4 (S)%101 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%96 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2035367MATRIX SPIKE SAMPLE:
MSSpike
Result
92345640018
1,1,1,2-Tetrachloroethane ug/L 17.820 89 70-130ND
1,1,1-Trichloroethane ug/L 19.920 99 70-130ND
1,1,2,2-Tetrachloroethane ug/L 18.520 93 70-130ND
1,1,2-Trichloroethane ug/L 19.720 98 70-130ND
1,1-Dichloroethane ug/L 19.820 96 70-1300.62J
1,1-Dichloroethene ug/L 20.420 102 70-166ND
1,2,3-Trichloropropane ug/L 19.920 99 70-130ND
1,2-Dibromo-3-chloropropane ug/L 22.120 111 70-130ND
1,2-Dibromoethane (EDB)ug/L 18.720 94 70-130ND
1,2-Dichlorobenzene ug/L 17.320 87 70-130ND
1,2-Dichloroethane ug/L 20.120 101 70-130ND
1,2-Dichloropropane ug/L 19.420 97 70-130ND
1,4-Dichlorobenzene ug/L 19.520 83 70-1303.0
2-Butanone (MEK)ug/L 56.5J M040141 70-130ND
2-Hexanone ug/L 48.8J40 122 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 48.8J40 122 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2035367MATRIX SPIKE SAMPLE:
MSSpike
Result
92345640018
Acetone ug/L 75.9J M040133 70-13022.8J
Acrylonitrile ug/L 139J M1100139 70-130ND
Benzene ug/L 19.520 97 70-148ND
Bromochloromethane ug/L 19.420 97 70-130ND
Bromodichloromethane ug/L 18.220 91 70-130ND
Bromoform ug/L 16.020 80 70-130ND
Bromomethane ug/L 12.5 M12063 70-130ND
Carbon disulfide ug/L 20.3J20 101 70-130ND
Carbon tetrachloride ug/L 18.520 92 70-130ND
Chlorobenzene ug/L 23.020 83 70-1466.4
Chloroethane ug/L 20.320 102 70-130ND
Chloroform ug/L 18.420 92 70-130ND
Chloromethane ug/L 22.520 113 70-130ND
cis-1,2-Dichloroethene ug/L 23.820 102 70-1303.4
cis-1,3-Dichloropropene ug/L 17.520 88 70-130ND
Dibromochloromethane ug/L 18.820 94 70-130ND
Dibromomethane ug/L 19.920 100 70-130ND
Dichlorodifluoromethane ug/L 21.720 108 70-130ND
Ethylbenzene ug/L 16.620 83 70-130ND
Iodomethane ug/L 32.440 81 70-130ND
Isobutanol ug/L 581 M1400145 70-130ND
Methylene Chloride ug/L 22.520 112 70-130ND
Styrene ug/L 16.620 83 70-130ND
Tetrachloroethene ug/L 16.320 81 70-130ND
Tetrahydrofuran ug/L 298 M1200147 70-1304.8J
Toluene ug/L 19.120 96 70-155ND
trans-1,2-Dichloroethene ug/L 20.020 100 70-130ND
trans-1,3-Dichloropropene ug/L 18.220 91 70-130ND
trans-1,4-Dichloro-2-butene ug/L 17.9J20 90 70-130ND
Trichloroethene ug/L 19.320 96 69-151ND
Trichlorofluoromethane ug/L 20.420 102 70-130ND
Vinyl acetate ug/L 34.8J40 87 70-130ND
Vinyl chloride ug/L 21.820 109 70-130ND
1,2-Dichloroethane-d4 (S)%110 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92345640019
2035368SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 0.98J 300.88J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92345640019
2035368SAMPLE DUPLICATE:
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 1.3 21 301.1
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L 14.9J 3011.8J
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 1.1J 8 301.0
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L 0.57J 300.55J
cis-1,2-Dichloroethene ug/L 10.7 3 3010.4
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Isobutanol ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L 0.80J 300.89J
Tetrahydrofuran ug/L 4.0J 304.2J
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L 2.7 2 302.8
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 300.78J
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%114 0114
4-Bromofluorobenzene (S)%102 1101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92345640019
2035368SAMPLE DUPLICATE:
Toluene-d8 (S)%106 1105
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367064
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2034599
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
alpha-BHC ug/L ND 0.050 07/06/17 22:480.050
beta-BHC ug/L ND 0.050 07/06/17 22:480.050
Decachlorobiphenyl (S)%58 20-130 07/06/17 22:48
Tetrachloro-m-xylene (S)%77 20-130 07/06/17 22:48
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2034600LABORATORY CONTROL SAMPLE:
LCSSpike
alpha-BHC ug/L 0.20.25 82 20-150
beta-BHC ug/L 0.18.25 74 20-150
Decachlorobiphenyl (S)%88 20-130
Tetrachloro-m-xylene (S)%87 20-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2034601MATRIX SPIKE SAMPLE:
MSSpike
Result
92345640011
alpha-BHC ug/L 0.14.25 58 20-150ND
beta-BHC ug/L 0.12.25 49 20-150ND
Decachlorobiphenyl (S)%61 20-130
Tetrachloro-m-xylene (S)%63 20-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92345640012
2034602SAMPLE DUPLICATE:
alpha-BHC ug/L ND 30ND
beta-BHC ug/L ND 30ND
Decachlorobiphenyl (S)%62 867
Tetrachloro-m-xylene (S)%74 3353
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367212
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2035586
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 07/01/17 14:331000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2035587LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4990050000 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2035588MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345640002
2035589
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L M1500009380-120128 2 2550000732 mg/L 778000 796000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2035590MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345867005
2035591
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 90 80-12089 0 255000099100144000 143000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367250
SM 2540C
SM 2540C
2540C Total Dissolved Solids
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2035726
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Total Dissolved Solids ug/L ND 25000 06/30/17 10:0325000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2035727LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids ug/L 234000250000 94 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92345864001
2035728SAMPLE DUPLICATE:
Total Dissolved Solids ug/L ND 5ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92346154002
2035729SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 26000 D67528000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367596
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037603
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Sulfide ug/L ND 1000 07/03/17 20:00100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037604LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 497J500 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037605MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345769001
2037606
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 96 80-12098 2 10500ND503J 513J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037607MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345640015
2037608
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L M15006680-12067 2 10500ND336J 343J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367506
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037142
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Sulfate ug/L ND 250000 07/03/17 13:29500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037143LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 52600J50000 105 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037144MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345945089
2037145
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 50000 101 90-110102 1 105000032.0 mg/L 82500J 83200J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037206MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345867001
2037207
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 50000 108 90-110109 1 10500005290J59500J 59900J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
368012
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2039600
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Chloride ug/L ND 1000 07/08/17 01:00500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2039601LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 2160020000 108 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2039602MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346191001
2039603
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M11000011990-110118 1 10100001.6 mg/L 13500 13400
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2039604MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345867003
2039605
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 10000 109 90-110108 0 10100001040021300 21300
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367925
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples: 92345864001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2039007
Associated Lab Samples:92345864001
Matrix: Water
AnalyzedMDL
Cyanide ug/L ND 10.0 07/07/17 13:474.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2039008LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 99.9100 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2039009MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346296007
2039010
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L M1,R11003980-12054 19 101000.030mg/L 69.3 83.9
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2039011MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345640016
2039012
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 93 80-12091 2 10100ND94.0 91.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 30
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associatedsamples may be biased high.L1
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 30
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92345864
JOHNS R. BACKGROUND
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92345864001 367064 3672261203-MW21 EPA 3510 EPA 8081
92345864001 366984 3680021203-MW21 EPA 3010A EPA 6010
92345864001 367201 3677901203-MW21 EPA 3010A EPA 6020B
92345864001 367714 3680241203-MW21 EPA 7470 EPA 7470
92345864001 3671601203-MW21 EPA 8260
92345864001 3672121203-MW21 SM 2320B
92345864001 3672501203-MW21 SM 2540C
92345864001 3675961203-MW21 SM 4500-S2D
92345864001 3675061203-MW21 EPA 300.0
92345864001 3680121203-MW21 SM 4500-Cl-E
92345864001 3679251203-MW21 SM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2017 04:25 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 30
Page 28 of 30
Page 29 of 30
Page 30 of 30
#=CL#
July 17, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92345865
92345865
Project:
Pace Project No.:
RE:
Mr. Van BurbachJoyce Engineering-Greensboro2211 West Meadowview RdBoone Bldg, Suite 101Greensboro, NC 27407
BURKE CO. JOHNS RIVER MNA
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on June 28, 2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.
Some analyses have been subcontracted outside of the Pace Network. The subcontractedlaboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager(704)875-9092
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 29
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92345865
BURKE CO. JOHNS RIVER MNA
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 29
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92345865
BURKE CO. JOHNS RIVER MNA
Lab ID Sample ID Matrix Date Collected Date Received
92345865001 1203-MW-11 Water 06/27/17 11:17 06/28/17 09:28
92345865002 1203-MW-12 Water 06/27/17 12:00 06/28/17 09:28
92345865003 1203-MW-16S Water 06/27/17 12:30 06/28/17 09:28
92345865004 1203-MW-21 Water 06/27/17 10:45 06/28/17 09:28
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 29
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92345865
BURKE CO. JOHNS RIVER MNA
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92345865001 1203-MW-11 RSK 175 Modified 3 PASI-CWDV
EPA 353.2 1 PASI-ADMN
SM 5310B 1 PASI-AKDF1
92345865002 1203-MW-12 RSK 175 Modified 3 PASI-CWDV
EPA 353.2 1 PASI-ADMN
SM 5310B 1 PASI-AKDF1
92345865003 1203-MW-16S RSK 175 Modified 3 PASI-CWDV
EPA 353.2 1 PASI-ADMN
SM 5310B 1 PASI-AKDF1
92345865004 1203-MW-21 RSK 175 Modified 3 PASI-CWDV
EPA 353.2 1 PASI-ADMN
SM 5310B 1 PASI-AKDF1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 29
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92345865
BURKE CO. JOHNS RIVER MNA
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92345865001 1203-MW-11
Methane 3150 ug/L 07/02/17 11:4910.0RSK 175 Modified
Total Organic Carbon 2980 ug/L 07/05/17 18:371000SM 5310B
92345865002 1203-MW-12
Methane 16600 ug/L 07/02/17 12:0410.0RSK 175 Modified
Total Organic Carbon 2170 ug/L 07/05/17 18:571000SM 5310B
92345865003 1203-MW-16S
Methane 12500 ug/L 07/02/17 12:1910.0RSK 175 Modified
Total Organic Carbon 2740 ug/L 07/05/17 19:071000SM 5310B
92345865004 1203-MW-21
Methane 19.4 ug/L 07/02/17 13:05 D610.0RSK 175 Modified
Nitrogen, Nitrate 201J ug/L 06/28/17 22:1210000EPA 353.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345865
BURKE CO. JOHNS RIVER MNA
Sample: 1203-MW-11 Lab ID: 92345865001 Collected: 06/27/17 11:17 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Ethane ND ug/L 07/02/17 11:49 74-84-010.0 10.0 1
Ethene ND ug/L 07/02/17 11:49 74-85-110.0 10.0 1
Methane 3150 ug/L 07/02/17 11:49 74-82-810.0 10.0 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate ND ug/L 06/28/17 22:1910000 10.0 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 2980 ug/L 07/05/17 18:37 7440-44-01000 500 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/17/2017 07:52 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345865
BURKE CO. JOHNS RIVER MNA
Sample: 1203-MW-12 Lab ID: 92345865002 Collected: 06/27/17 12:00 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Ethane ND ug/L 07/02/17 12:04 74-84-010.0 10.0 1
Ethene ND ug/L 07/02/17 12:04 74-85-110.0 10.0 1
Methane 16600 ug/L 07/02/17 12:04 74-82-810.0 10.0 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate ND ug/L 06/28/17 22:2010000 10.0 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 2170 ug/L 07/05/17 18:57 7440-44-01000 500 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/17/2017 07:52 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345865
BURKE CO. JOHNS RIVER MNA
Sample: 1203-MW-16S Lab ID: 92345865003 Collected: 06/27/17 12:30 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Ethane ND ug/L 07/02/17 12:19 74-84-010.0 10.0 1
Ethene ND ug/L 07/02/17 12:19 74-85-110.0 10.0 1
Methane 12500 ug/L 07/02/17 12:19 74-82-810.0 10.0 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate ND ug/L 06/28/17 22:2410000 10.0 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 2740 ug/L 07/05/17 19:07 7440-44-01000 500 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/17/2017 07:52 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92345865
BURKE CO. JOHNS RIVER MNA
Sample: 1203-MW-21 Lab ID: 92345865004 Collected: 06/27/17 10:45 Received: 06/28/17 09:28 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Ethane ND ug/L 07/02/17 13:05 74-84-010.0 10.0 1
Ethene ND ug/L 07/02/17 13:05 74-85-110.0 10.0 1
Methane 19.4 ug/L 07/02/17 13:05 74-82-8 D610.0 10.0 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 201J ug/L 06/28/17 22:1210000 10.0 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon ND ug/L 07/05/17 19:18 7440-44-01000 500 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/17/2017 07:52 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345865
BURKE CO. JOHNS RIVER MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367434
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples: 92345865001, 92345865002, 92345865003, 92345865004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2036913
Associated Lab Samples:92345865001, 92345865002, 92345865003, 92345865004
Matrix: Water
AnalyzedMDL
Ethane ug/L ND 10.0 07/02/17 08:1510.0
Ethene ug/L ND 10.0 07/02/17 08:1510.0
Methane ug/L ND 10.0 07/02/17 08:1510.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2036914LABORATORY CONTROL SAMPLE:
LCSSpike
Ethane ug/L 639658 97 70-130
Ethene ug/L 11001120 98 70-130
Methane ug/L 367396 93 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2036915MATRIX SPIKE SAMPLE:
MSSpike
Result
92345828035
Ethane ug/L 772658 117 70-130ND
Ethene ug/L 14101120 126 70-130ND
Methane ug/L 13900 M139615 70-13013800
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92345865004
2036916SAMPLE DUPLICATE:
Ethane ug/L ND 20ND
Ethene ug/L ND 20ND
Methane ug/L 11.3 D6532019.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/17/2017 07:52 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345865
BURKE CO. JOHNS RIVER MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
366975
EPA 353.2
EPA 353.2
353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92345865001, 92345865002, 92345865003, 92345865004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2034148
Associated Lab Samples:92345865001, 92345865002, 92345865003, 92345865004
Matrix: Water
AnalyzedMDL
Nitrogen, Nitrate ug/L ND 10000 06/28/17 22:0810.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2034149LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate ug/L 2460J2500 98 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2034150MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345865004
2034151
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate ug/L 2500 103 90-110103 0 102500201J2780J 2770J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/17/2017 07:52 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92345865
BURKE CO. JOHNS RIVER MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367702
SM 5310B
SM 5310B
5310B TOC
Associated Lab Samples: 92345865001, 92345865002, 92345865003, 92345865004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2037937
Associated Lab Samples:92345865001, 92345865002, 92345865003, 92345865004
Matrix: Water
AnalyzedMDL
Total Organic Carbon ug/L ND 1000 07/05/17 13:29500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2037938LABORATORY CONTROL SAMPLE:
LCSSpike
Total Organic Carbon ug/L 2330025000 93 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037939MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92345706003
2037940
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Total Organic Carbon ug/L 25000 94 90-11094 0 1025000ND23800 23800
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2037941MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92346396011
2037942
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Total Organic Carbon ug/L 25000 93 90-11093 0 10250000.79Jmg/L 24000 24000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/17/2017 07:52 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 29
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92345865
BURKE CO. JOHNS RIVER MNA
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/17/2017 07:52 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 29
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92345865
BURKE CO. JOHNS RIVER MNA
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92345865001 3674341203-MW-11 RSK 175 Modified
92345865002 3674341203-MW-12 RSK 175 Modified
92345865003 3674341203-MW-16S RSK 175 Modified
92345865004 3674341203-MW-21 RSK 175 Modified
92345865001 3669751203-MW-11 EPA 353.2
92345865002 3669751203-MW-12 EPA 353.2
92345865003 3669751203-MW-16S EPA 353.2
92345865004 3669751203-MW-21 EPA 353.2
92345865001 3677021203-MW-11 SM 5310B
92345865002 3677021203-MW-12 SM 5310B
92345865003 3677021203-MW-16S SM 5310B
92345865004 3677021203-MW-21 SM 5310B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/17/2017 07:52 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 29
Page 15 of 29
Page 16 of 29
Page 17 of 29
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23138 - 942822 Page 1 of 11
Trey Carter
Pace Analytical Charlotte9800 Kincey Ave
Suite 100Huntersville, NC 28078
July 10, 2017
RE:
Pace Workorder:
BURKE CO JOHNS RIVER/92345865
Dear Trey Carter:
23138
Enclosed are the analytical results for sample(s) received by the laboratory on Thursday, June 29, 2017.
Results reported herein conform to the most current NELAC standards, where applicable, unless otherwisenarrated in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Enclosures
Ruth Welsh 07/10/[e-mail]
Total Number of Pages ____
As a valued client we would appreciate your comments on our service.
Please email [e-mail].
Customer Service Representative
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
12
Page 18 of 29
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23138 - 942822 Page 2 of 11
LABORATORY ACCREDITATIONS & CERTIFICATIONS
Pennsylvania Department of Environmental Protection, Bureau of Laboratories
02-00538
NELAP Non-Potable Water and Solid & Hazardous Waste
Accreditor:
Accreditation ID:
Scope:
West Virginia Department of Environmental Protection, Division of Water and Waste
Management
395
Non-Potable Water
Accreditor:
Accreditation ID:
Scope:
South Carolina Department of Health and Environmental Control, Office of EnvironmentalLaboratory Certification
89009003
Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA)
Accreditor:
Accreditation ID:
Scope:
NELAP: New Jersey, Department of Environmental Protection
PA026
Non-Potable Water; Solid and Chemical Materials
Accreditor:
Accreditation ID:
Scope:
NELAP: New York, Department of Health Wadsworth Center
11815
Non-Potable Water; Solid and Hazardous Waste
Accreditor:
Accreditation ID:
Scope:
State of Connecticut, Department of Public Health, Division of Environmental Health
PH-0263
Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA)
Accreditor:
Accreditation ID:
Scope:
NELAP: Texas, Commission on Environmental Quality
T104704453-09-TX
Non-Potable Water
Accreditor:
Accreditation ID:
Scope:
State of New Hampshire
299409
Non-potable water
Accreditor:
Accreditation ID:
Scope:
State of Georgia
Chapter 391-3-26
As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES isaccredited by the Pennsylvania Department of Environmental Protection Bureau of
Laboratories under the National Environmental Laboratory Approval Program (NELAC).
Accreditor:
Accreditation ID:
Scope:
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 19 of 29
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23138 - 942822 Page 3 of 11
SAMPLE SUMMARY
Workorder: 23138 BURKE CO JOHNS RIVER/92345865
Lab ID Sample ID Matrix Date Collected Date Received
231380001 1203-MW-11 Bubble Strip 6/27/2017 11:17 6/29/2017 11:45
231380002 1203-MW-12 Bubble Strip 6/27/2017 12:00 6/29/2017 11:45
231380003 1203-MW-16S Bubble Strip 6/27/2017 12:30 6/29/2017 11:45
231380004 1203-MW-21 Bubble Strip 6/27/2017 10:45 6/29/2017 11:45
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 20 of 29
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23138 - 942822 Page 4 of 11
ANALYTICAL RESULTS
Workorder: 23138 BURKE CO JOHNS RIVER/92345865
6/29/2017 11:45
1203-MW-11
Matrix: Bubble Strip
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
231380001
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
6/27/2017 11:17
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 1.7 nM 0.60 1 7/8/2017 09:57 TD n0.075
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 21 of 29
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23138 - 942822 Page 5 of 11
ANALYTICAL RESULTS
Workorder: 23138 BURKE CO JOHNS RIVER/92345865
6/29/2017 11:45
1203-MW-12
Matrix: Bubble Strip
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
231380002
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
6/27/2017 12:00
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 2.0 nM 0.60 1 7/8/2017 10:09 TD n0.075
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 22 of 29
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23138 - 942822 Page 6 of 11
ANALYTICAL RESULTS
Workorder: 23138 BURKE CO JOHNS RIVER/92345865
6/29/2017 11:45
1203-MW-16S
Matrix: Bubble Strip
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
231380003
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
6/27/2017 12:30
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 2.0 nM 0.60 1 7/8/2017 10:30 TD n0.075
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 23 of 29
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23138 - 942822 Page 7 of 11
ANALYTICAL RESULTS
Workorder: 23138 BURKE CO JOHNS RIVER/92345865
6/29/2017 11:45
1203-MW-21
Matrix: Bubble Strip
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
231380004
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
6/27/2017 10:45
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 2.0 nM 0.60 1 7/8/2017 10:43 TD n0.075
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 24 of 29
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23138 - 942822 Page 8 of 11
ANALYTICAL RESULTS QUALIFIERS
Workorder: 23138 BURKE CO JOHNS RIVER/92345865
DEFINITIONS/QUALIFIERS
U
J
Indicates the compound was analyzed for, but not detected at or above the noted concentration.
Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL).
MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection.
PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation.
ND Not detected at or above reporting limit.
DF Dilution Factor.
S Surrogate.
RPD Relative Percent Difference.
% Rec Percent Recovery.
The laboratory does not hold NELAP/TNI accreditation for this method or analyte.n
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 25 of 29
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23138 - 942822 Page 9 of 11
QUALITY CONTROL DATA
Workorder: 23138 BURKE CO JOHNS RIVER/92345865
QC Batch:
QC Batch Method:
DISG/6211
AM20GAX
Analysis Method: AM20GAX
Associated Lab Samples:231380001, 231380002, 231380003, 231380004
METHOD BLANK: 49747
Parameter Units Result
Blank
Limit
Reporting
Qualifiers
RISK
Hydrogen 0.075UnM 0.075 n
LABORATORY CONTROL SAMPLE & LCSD:
Parameter Units Conc.
Spike
Result
LCS
49748 49749
LCSD
Result % Rec
LCS LCSD
% Rec
% Rec
Limit RPD RPD
Max
Qualifiers
RISK
Hydrogen nM 24 23 94 80-120 n23951.1 20
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 26 of 29
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23138 - 942822 Page 10 of 11
QUALITY CONTROL DATA QUALIFIERS
Workorder: 23138 BURKE CO JOHNS RIVER/92345865
QUALITY CONTROL PARAMETER QUALIFIERS
The laboratory does not hold NELAP/TNI accreditation for this method or analyte.n
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 27 of 29
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23138 - 942822 Page 11 of 11
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Workorder: 23138 BURKE CO JOHNS RIVER/92345865
Lab ID Sample ID Prep Method Analysis MethodPrep Batch Batch
Analysis
231380001 1203-MW-11 DISG/6211AM20GAX
231380002 1203-MW-12 DISG/6211AM20GAX
231380003 1203-MW-16S DISG/6211AM20GAX
231380004 1203-MW-21 DISG/6211AM20GAX
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 28 of 29
Page 29 of 29
#=CL#
July 18, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92346145
92346145
Project:
Pace Project No.:
RE:
Mr. Van BurbachJoyce Engineering-Greensboro2211 West Meadowview RdBoone Bldg, Suite 101Greensboro, NC 27407
JOHNS R.-ADD MW LFG
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on June 28, 2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.
Some analyses have been subcontracted outside of the Pace Network. The subcontractedlaboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager(704)875-9092
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 37
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 37
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Lab ID Sample ID Matrix Date Collected Date Received
92346145001 1203-MW-15S Water 06/28/17 08:45 06/28/17 12:45
92346145002 1203-PZ-12 Water 06/28/17 09:45 06/28/17 12:45
92346145003 1203-PZ-30S Water 06/28/17 08:15 06/28/17 12:45
92346145004 1203-PZ-31 Water 06/28/17 08:24 06/28/17 12:45
92346145005 1203-PZ-35 Water 06/28/17 11:13 06/28/17 12:45
92346145006 1203-PZ-36 Water 06/28/17 10:23 06/28/17 12:45
92346145007 1203-MW-38 Water 06/28/17 10:53 06/28/17 12:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 37
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92346145001 1203-MW-15S RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CGAW
92346145002 1203-PZ-12 RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CGAW
92346145003 1203-PZ-30S RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CGAW
92346145004 1203-PZ-31 RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CGAW
92346145005 1203-PZ-35 RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CGAW
92346145006 1203-PZ-36 RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CGAW
92346145007 1203-MW-38 RSK 175 Modified 1 PASI-CWDV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 37
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92346145001 1203-MW-15S
Methane 25900 ug/L 07/03/17 10:53100RSK 175 Modified
Benzene 0.43J ug/L 07/01/17 18:221.0EPA 8260
1,1-Dichloroethane 0.59J ug/L 07/01/17 18:225.0EPA 8260
Tetrachloroethene 0.80J ug/L 07/01/17 18:221.0EPA 8260
92346145006 1203-PZ-36
Methane 45400 ug/L 07/03/17 11:08100RSK 175 Modified
Benzene 5.3 ug/L 07/01/17 19:511.0EPA 8260
1,4-Dichlorobenzene 20.1 ug/L 07/01/17 19:511.0EPA 8260
1,1-Dichloroethane 4.3J ug/L 07/01/17 19:515.0EPA 8260
1,2-Dichloroethane 0.75J ug/L 07/01/17 19:511.0EPA 8260
Vinyl chloride 0.64J ug/L 07/01/17 19:511.0EPA 8260
92346145007 1203-MW-38
Methane 35400 ug/L 07/03/17 11:24100RSK 175 Modified
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Sample: 1203-MW-15S Lab ID: 92346145001 Collected: 06/28/17 08:45 Received: 06/28/17 12:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 25900 ug/L 07/03/17 10:53 74-82-8100 100 10
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene 0.43J ug/L 07/01/17 18:22 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 07/01/17 18:22 106-46-71.0 0.33 1
1,1-Dichloroethane 0.59J ug/L 07/01/17 18:22 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/01/17 18:22 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 07/01/17 18:22 75-09-21.0 0.97 1
Tetrachloroethene 0.80J ug/L 07/01/17 18:22 127-18-41.0 0.46 1
Trichloroethene ND ug/L 07/01/17 18:22 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 07/01/17 18:22 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)98 %07/01/17 18:22 460-00-470-130 1
1,2-Dichloroethane-d4 (S)94 %07/01/17 18:22 17060-07-070-130 1
Toluene-d8 (S)103 %07/01/17 18:22 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/18/2017 09:57 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Sample: 1203-PZ-12 Lab ID: 92346145002 Collected: 06/28/17 09:45 Received: 06/28/17 12:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/02/17 13:36 74-82-810.0 10.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 07/01/17 18:40 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 07/01/17 18:40 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 07/01/17 18:40 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/01/17 18:40 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 07/01/17 18:40 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 07/01/17 18:40 127-18-41.0 0.46 1
Trichloroethene ND ug/L 07/01/17 18:40 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 07/01/17 18:40 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)98 %07/01/17 18:40 460-00-470-130 1
1,2-Dichloroethane-d4 (S)93 %07/01/17 18:40 17060-07-070-130 1
Toluene-d8 (S)104 %07/01/17 18:40 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/18/2017 09:57 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Sample: 1203-PZ-30S Lab ID: 92346145003 Collected: 06/28/17 08:15 Received: 06/28/17 12:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/02/17 13:51 74-82-810.0 10.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 07/01/17 18:58 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 07/01/17 18:58 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 07/01/17 18:58 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/01/17 18:58 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 07/01/17 18:58 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 07/01/17 18:58 127-18-41.0 0.46 1
Trichloroethene ND ug/L 07/01/17 18:58 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 07/01/17 18:58 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)94 %07/01/17 18:58 460-00-470-130 1
1,2-Dichloroethane-d4 (S)91 %07/01/17 18:58 17060-07-070-130 1
Toluene-d8 (S)105 %07/01/17 18:58 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/18/2017 09:57 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Sample: 1203-PZ-31 Lab ID: 92346145004 Collected: 06/28/17 08:24 Received: 06/28/17 12:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/02/17 14:06 74-82-810.0 10.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 07/01/17 19:15 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 07/01/17 19:15 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 07/01/17 19:15 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/01/17 19:15 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 07/01/17 19:15 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 07/01/17 19:15 127-18-41.0 0.46 1
Trichloroethene ND ug/L 07/01/17 19:15 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 07/01/17 19:15 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)101 %07/01/17 19:15 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %07/01/17 19:15 17060-07-070-130 1
Toluene-d8 (S)104 %07/01/17 19:15 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/18/2017 09:57 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Sample: 1203-PZ-35 Lab ID: 92346145005 Collected: 06/28/17 11:13 Received: 06/28/17 12:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/02/17 15:07 74-82-810.0 10.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 07/01/17 19:33 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 07/01/17 19:33 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 07/01/17 19:33 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/01/17 19:33 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 07/01/17 19:33 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 07/01/17 19:33 127-18-41.0 0.46 1
Trichloroethene ND ug/L 07/01/17 19:33 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 07/01/17 19:33 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)95 %07/01/17 19:33 460-00-470-130 1
1,2-Dichloroethane-d4 (S)92 %07/01/17 19:33 17060-07-070-130 1
Toluene-d8 (S)104 %07/01/17 19:33 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/18/2017 09:57 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Sample: 1203-PZ-36 Lab ID: 92346145006 Collected: 06/28/17 10:23 Received: 06/28/17 12:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 45400 ug/L 07/03/17 11:08 74-82-8100 100 10
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene 5.3 ug/L 07/01/17 19:51 71-43-21.0 0.25 1
1,4-Dichlorobenzene 20.1 ug/L 07/01/17 19:51 106-46-71.0 0.33 1
1,1-Dichloroethane 4.3J ug/L 07/01/17 19:51 75-34-35.0 0.32 1
1,2-Dichloroethane 0.75J ug/L 07/01/17 19:51 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 07/01/17 19:51 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 07/01/17 19:51 127-18-41.0 0.46 1
Trichloroethene ND ug/L 07/01/17 19:51 79-01-61.0 0.47 1
Vinyl chloride 0.64J ug/L 07/01/17 19:51 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)97 %07/01/17 19:51 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %07/01/17 19:51 17060-07-070-130 1
Toluene-d8 (S)107 %07/01/17 19:51 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/18/2017 09:57 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Sample: 1203-MW-38 Lab ID: 92346145007 Collected: 06/28/17 10:53 Received: 06/28/17 12:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 35400 ug/L 07/03/17 11:24 74-82-8100 100 10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/18/2017 09:57 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367434
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples: 92346145001, 92346145002, 92346145003, 92346145004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2036913
Associated Lab Samples:92346145001, 92346145002, 92346145003, 92346145004
Matrix: Water
AnalyzedMDL
Methane ug/L ND 10.0 07/02/17 08:1510.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2036914LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 367396 93 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2036915MATRIX SPIKE SAMPLE:
MSSpike
Result
92345828035
Methane ug/L 13900 M139615 70-13013800
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92345865004
2036916SAMPLE DUPLICATE:
Methane ug/L 11.3 D6532019.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/18/2017 09:57 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367435
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples: 92346145005, 92346145006, 92346145007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2036917
Associated Lab Samples:92346145005, 92346145006, 92346145007
Matrix: Water
AnalyzedMDL
Methane ug/L ND 10.0 07/02/17 14:5210.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2036918LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 360396 91 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2036919MATRIX SPIKE SAMPLE:
MSSpike
Result
92346100001
Methane ug/L 603396 108 70-130177
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92346100002
2036920SAMPLE DUPLICATE:
Methane ug/L 61.9 10 2068.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/18/2017 09:57 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
367395
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92346145001, 92346145002, 92346145003, 92346145004, 92346145005, 92346145006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2036776
Associated Lab Samples:92346145001, 92346145002, 92346145003, 92346145004, 92346145005, 92346145006
Matrix: Water
AnalyzedMDL
1,1-Dichloroethane ug/L ND 5.0 07/01/17 13:040.32
1,2-Dichloroethane ug/L ND 1.0 07/01/17 13:040.24
1,4-Dichlorobenzene ug/L ND 1.0 07/01/17 13:040.33
Benzene ug/L ND 1.0 07/01/17 13:040.25
Methylene Chloride ug/L ND 1.0 07/01/17 13:040.97
Tetrachloroethene ug/L ND 1.0 07/01/17 13:040.46
Trichloroethene ug/L ND 1.0 07/01/17 13:040.47
Vinyl chloride ug/L ND 1.0 07/01/17 13:040.62
1,2-Dichloroethane-d4 (S)%94 70-130 07/01/17 13:04
4-Bromofluorobenzene (S)%96 70-130 07/01/17 13:04
Toluene-d8 (S)%104 70-130 07/01/17 13:04
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2036777LABORATORY CONTROL SAMPLE:
LCSSpike
1,1-Dichloroethane ug/L 43.550 87 73-126
1,2-Dichloroethane ug/L 45.250 90 67-128
1,4-Dichlorobenzene ug/L 49.550 99 78-130
Benzene ug/L 47.850 96 80-125
Methylene Chloride ug/L 47.050 94 64-133
Tetrachloroethene ug/L 46.950 94 78-122
Trichloroethene ug/L 47.450 95 78-122
Vinyl chloride ug/L 41.150 82 58-137
1,2-Dichloroethane-d4 (S)%93 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%95 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2036779MATRIX SPIKE SAMPLE:
MSSpike
Result
92346168021
1,1-Dichloroethane ug/L 19.120 95 70-130ND
1,2-Dichloroethane ug/L 19.120 95 70-130ND
1,4-Dichlorobenzene ug/L 20.720 103 70-130ND
Benzene ug/L 20.320 101 70-148ND
Methylene Chloride ug/L 17.720 88 70-130ND
Tetrachloroethene ug/L 19.020 95 70-130ND
Trichloroethene ug/L 20.420 102 69-151ND
Vinyl chloride ug/L 18.620 93 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/18/2017 09:57 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2036779MATRIX SPIKE SAMPLE:
MSSpike
Result
92346168021
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92346168020
2036778SAMPLE DUPLICATE:
1,1-Dichloroethane ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
Benzene ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%94 094
4-Bromofluorobenzene (S)%99 297
Toluene-d8 (S)%110 3106
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/18/2017 09:57 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 37
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/18/2017 09:57 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 37
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92346145
JOHNS R.-ADD MW LFG
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92346145001 3674341203-MW-15S RSK 175 Modified
92346145002 3674341203-PZ-12 RSK 175 Modified
92346145003 3674341203-PZ-30S RSK 175 Modified
92346145004 3674341203-PZ-31 RSK 175 Modified
92346145005 3674351203-PZ-35 RSK 175 Modified
92346145006 3674351203-PZ-36 RSK 175 Modified
92346145007 3674351203-MW-38 RSK 175 Modified
92346145001 3673951203-MW-15S EPA 8260
92346145002 3673951203-PZ-12 EPA 8260
92346145003 3673951203-PZ-30S EPA 8260
92346145004 3673951203-PZ-31 EPA 8260
92346145005 3673951203-PZ-35 EPA 8260
92346145006 3673951203-PZ-36 EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/18/2017 09:57 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 37
Page 19 of 37
Page 20 of 37
Page 21 of 37
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23145 - 942704 Page 1 of 14
Trey Carter
Pace Analytical Charlotte9800 Kincey Ave
Suite 100Huntersville, NC 28078
July 11, 2017
RE:
Pace Workorder:
JOHNS R.-ADD MW LFG / 92346145
Dear Trey Carter:
23145
Enclosed are the analytical results for sample(s) received by the laboratory on Friday, June 30, 2017. Results
reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated inthe body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Enclosures
Ruth Welsh 07/11/[e-mail]
Total Number of Pages ____
As a valued client we would appreciate your comments on our service.
Please email [e-mail].
Customer Service Representative
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
16
Page 22 of 37
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23145 - 942704 Page 2 of 14
LABORATORY ACCREDITATIONS & CERTIFICATIONS
Pennsylvania Department of Environmental Protection, Bureau of Laboratories
02-00538
NELAP Non-Potable Water and Solid & Hazardous Waste
Accreditor:
Accreditation ID:
Scope:
West Virginia Department of Environmental Protection, Division of Water and Waste
Management
395
Non-Potable Water
Accreditor:
Accreditation ID:
Scope:
South Carolina Department of Health and Environmental Control, Office of EnvironmentalLaboratory Certification
89009003
Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA)
Accreditor:
Accreditation ID:
Scope:
NELAP: New Jersey, Department of Environmental Protection
PA026
Non-Potable Water; Solid and Chemical Materials
Accreditor:
Accreditation ID:
Scope:
NELAP: New York, Department of Health Wadsworth Center
11815
Non-Potable Water; Solid and Hazardous Waste
Accreditor:
Accreditation ID:
Scope:
State of Connecticut, Department of Public Health, Division of Environmental Health
PH-0263
Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA)
Accreditor:
Accreditation ID:
Scope:
NELAP: Texas, Commission on Environmental Quality
T104704453-09-TX
Non-Potable Water
Accreditor:
Accreditation ID:
Scope:
State of New Hampshire
299409
Non-potable water
Accreditor:
Accreditation ID:
Scope:
State of Georgia
Chapter 391-3-26
As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES isaccredited by the Pennsylvania Department of Environmental Protection Bureau of
Laboratories under the National Environmental Laboratory Approval Program (NELAC).
Accreditor:
Accreditation ID:
Scope:
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 23 of 37
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23145 - 942704 Page 3 of 14
SAMPLE SUMMARY
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
Lab ID Sample ID Matrix Date Collected Date Received
231450001 1203-MW-15S Water 6/28/2017 08:45 6/30/2017 11:30
231450002 1203-PZ-12 Water 6/28/2017 09:45 6/30/2017 11:30
231450003 1203-PZ-30S Water 6/28/2017 08:15 6/30/2017 11:30
231450004 1203-PZ-31 Water 6/28/2017 08:24 6/30/2017 11:30
231450005 1203-PZ-35 Water 6/28/2017 11:13 6/30/2017 11:30
231450006 1203-PZ-36 Water 6/28/2017 10:23 6/30/2017 11:30
231450007 1203-MW-38 Water 6/28/2017 10:53 6/30/2017 11:30
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 24 of 37
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23145 - 942704 Page 4 of 14
ANALYTICAL RESULTS
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
6/30/2017 11:30
1203-MW-15S
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
231450001
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
6/28/2017 08:45
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Carbon Dioxide 250 mg/l 5.0 1 7/6/2017 09:28 BW n0.45
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 25 of 37
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23145 - 942704 Page 5 of 14
ANALYTICAL RESULTS
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
6/30/2017 11:30
1203-PZ-12
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
231450002
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
6/28/2017 09:45
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Carbon Dioxide 36 mg/l 5.0 1 7/6/2017 09:37 BW n0.45
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 26 of 37
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23145 - 942704 Page 6 of 14
ANALYTICAL RESULTS
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
6/30/2017 11:30
1203-PZ-30S
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
231450003
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
6/28/2017 08:15
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Carbon Dioxide 23 mg/l 5.0 1 7/6/2017 09:49 BW n0.45
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 27 of 37
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23145 - 942704 Page 7 of 14
ANALYTICAL RESULTS
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
6/30/2017 11:30
1203-PZ-31
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
231450004
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
6/28/2017 08:24
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Carbon Dioxide 14 mg/l 5.0 1 7/6/2017 10:02 BW n0.45
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 28 of 37
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23145 - 942704 Page 8 of 14
ANALYTICAL RESULTS
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
6/30/2017 11:30
1203-PZ-35
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
231450005
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
6/28/2017 11:13
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Carbon Dioxide 22 mg/l 5.0 1 7/6/2017 10:12 BW n0.45
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 29 of 37
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23145 - 942704 Page 9 of 14
ANALYTICAL RESULTS
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
6/30/2017 11:30
1203-PZ-36
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
231450006
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
6/28/2017 10:23
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Carbon Dioxide 420 mg/l 5.0 1 7/6/2017 10:29 BW n0.45
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 30 of 37
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23145 - 942704 Page 10 of 14
ANALYTICAL RESULTS
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
6/30/2017 11:30
1203-MW-38
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
231450007
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
6/28/2017 10:53
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Carbon Dioxide 260 mg/l 5.0 1 7/6/2017 10:39 BW n0.45
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 31 of 37
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23145 - 942704 Page 11 of 14
ANALYTICAL RESULTS QUALIFIERS
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
DEFINITIONS/QUALIFIERS
U
J
Indicates the compound was analyzed for, but not detected at or above the noted concentration.
Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL).
MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection.
PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation.
ND Not detected at or above reporting limit.
DF Dilution Factor.
S Surrogate.
RPD Relative Percent Difference.
% Rec Percent Recovery.
The laboratory does not hold NELAP/TNI accreditation for this method or analyte.n
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 32 of 37
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23145 - 942704 Page 12 of 14
QUALITY CONTROL DATA
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
QC Batch:
QC Batch Method:
DISG/6206
AM20GAX
Analysis Method: AM20GAX
Associated Lab Samples:231450001, 231450002, 231450003, 231450004, 231450005, 231450006, 231450007
METHOD BLANK: 49706
Parameter Units Result
Blank
Limit
Reporting
Qualifiers
RISK
Carbon Dioxide 0.45Umg/l 0.45 n
LABORATORY CONTROL SAMPLE & LCSD:
Parameter Units Conc.
Spike
Result
LCS
49708 49710
LCSD
Result % Rec
LCS LCSD
% Rec
% Rec
Limit RPD RPD
Max
Qualifiers
RISK
Carbon Dioxide mg/l 120 120 99 80-120 n110972 20
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 33 of 37
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23145 - 942704 Page 13 of 14
QUALITY CONTROL DATA QUALIFIERS
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
QUALITY CONTROL PARAMETER QUALIFIERS
The laboratory does not hold NELAP/TNI accreditation for this method or analyte.n
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 34 of 37
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 23145 - 942704 Page 14 of 14
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Workorder: 23145 JOHNS R.-ADD MW LFG / 92346145
Lab ID Sample ID Prep Method Analysis MethodPrep Batch Batch
Analysis
231450001 1203-MW-15S DISG/6206AM20GAX
231450002 1203-PZ-12 DISG/6206AM20GAX
231450003 1203-PZ-30S DISG/6206AM20GAX
231450004 1203-PZ-31 DISG/6206AM20GAX
231450005 1203-PZ-35 DISG/6206AM20GAX
231450006 1203-PZ-36 DISG/6206AM20GAX
231450007 1203-MW-38 DISG/6206AM20GAX
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 35 of 37
Page 36 of 37
Page 37 of 37
#=CL#
August 22, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92350924
92350924
Project:
Pace Project No.:
RE:
Mr. Van BurbachJoyce Engineering-Greensboro2211 West Meadowview RdBoone Bldg, Suite 101Greensboro, NC 27407
BURKE CO JOHNS RIVER RESAMPLE
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 09, 2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager(704)875-9092
Enclosures
cc: Gretta Eller, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 15
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 15
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Lab ID Sample ID Matrix Date Collected Date Received
92350924001 TRIP BLANK Water 08/08/17 08:00 08/09/17 10:17
92350924002 MW-38 Water 08/08/17 12:02 08/09/17 10:17
92350924003 FIELD BLANK Water 08/08/17 12:15 08/09/17 10:17
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 15
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92350924001 TRIP BLANK EPA 8260 4 PASI-CZDO
92350924002 MW-38 EPA 8260 4 PASI-CZDO
92350924003 FIELD BLANK EPA 8260 4 PASI-CZDO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 15
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92350924002 MW-38
Vinyl chloride 0.87J ug/L 08/12/17 15:531.0EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 15
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Sample: TRIP BLANK Lab ID: 92350924001 Collected: 08/08/17 08:00 Received: 08/09/17 10:17 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Vinyl chloride ND ug/L 08/12/17 15:35 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)104 %08/12/17 15:35 460-00-470-130 1
1,2-Dichloroethane-d4 (S)115 %08/12/17 15:35 17060-07-070-130 1
Toluene-d8 (S)109 %08/12/17 15:35 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/22/2017 01:13 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 15
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Sample: MW-38 Lab ID: 92350924002 Collected: 08/08/17 12:02 Received: 08/09/17 10:17 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Vinyl chloride 0.87J ug/L 08/12/17 15:53 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)103 %08/12/17 15:53 460-00-470-130 1
1,2-Dichloroethane-d4 (S)122 %08/12/17 15:53 17060-07-070-130 1
Toluene-d8 (S)110 %08/12/17 15:53 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/22/2017 01:13 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 15
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Sample: FIELD BLANK Lab ID: 92350924003 Collected: 08/08/17 12:15 Received: 08/09/17 10:17 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Vinyl chloride ND ug/L 08/22/17 02:59 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)98 %08/22/17 02:59 460-00-470-130 1
1,2-Dichloroethane-d4 (S)106 %08/22/17 02:59 17060-07-070-130 1
Toluene-d8 (S)107 %08/22/17 02:59 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/22/2017 01:13 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 15
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
373046
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92350924001, 92350924002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2067164
Associated Lab Samples:92350924001, 92350924002
Matrix: Water
AnalyzedMDL
Vinyl chloride ug/L ND 1.0 08/12/17 11:150.62
1,2-Dichloroethane-d4 (S)%117 70-130 08/12/17 11:15
4-Bromofluorobenzene (S)%105 70-130 08/12/17 11:15
Toluene-d8 (S)%112 70-130 08/12/17 11:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2067165LABORATORY CONTROL SAMPLE:
LCSSpike
Vinyl chloride ug/L 52.150 104 58-137
1,2-Dichloroethane-d4 (S)%110 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2068023MATRIX SPIKE SAMPLE:
MSSpike
Result
92350896003
Vinyl chloride ug/L 23.020 115 70-130ND
1,2-Dichloroethane-d4 (S)%105 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92350896002
2067345SAMPLE DUPLICATE:
Vinyl chloride ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%116 2118
4-Bromofluorobenzene (S)%103 3101
Toluene-d8 (S)%109 2110
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/22/2017 01:13 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 15
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
374353
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92350924003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2074072
Associated Lab Samples:92350924003
Matrix: Water
AnalyzedMDL
Vinyl chloride ug/L ND 1.0 08/22/17 01:500.62
1,2-Dichloroethane-d4 (S)%105 70-130 08/22/17 01:50
4-Bromofluorobenzene (S)%96 70-130 08/22/17 01:50
Toluene-d8 (S)%106 70-130 08/22/17 01:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2074073LABORATORY CONTROL SAMPLE:
LCSSpike
Vinyl chloride ug/L 40.350 81 58-137
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2074074MATRIX SPIKE SAMPLE:
MSSpike
Result
92351475001
Vinyl chloride ug/L 22.620 109 70-1300.83J
1,2-Dichloroethane-d4 (S)%104 70-130
4-Bromofluorobenzene (S)%96 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92351475002
2074075SAMPLE DUPLICATE:
Vinyl chloride ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%106 4102
4-Bromofluorobenzene (S)%100 199
Toluene-d8 (S)%110 1109
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/22/2017 01:13 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 15
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/22/2017 01:13 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 15
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92350924
BURKE CO JOHNS RIVER RESAMPLE
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92350924001 373046TRIP BLANK EPA 8260
92350924002 373046MW-38 EPA 8260
92350924003 374353FIELD BLANK EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/22/2017 01:13 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 15
Page 13 of 15
Page 14 of 15
Page 15 of 15

Appendix C

Statistical Analyses Worksheets

JOYCE Project:Burke County - Johns River Landfill
Project No: 277.1801.12
Date: June 2017
Analyte:Cobalt
Sample No. Sample Date Location Concentration RL
1 Sep-94 MW-9 52 2.6 120
2 Jan-95 MW-9 35 10 4.0 52
3 Feb-95 MW-9 16 10 4.1 37
4 Mar-95 MW-9 28 10 5.4 37
5 Aug-95 MW-9 ND 10 7.3 35
6 Jan-96 MW-9 17 10 7.8 33
7 Feb-96 MW-9 37 10 9.2 29
8 May-96 MW-9 11 10 9.8 28
9 Oct-96 MW-9 16 10 10 28
10 May-97 MW-9 33 6 10 26
11 Nov-97 MW-9 29 5 10 26
12 May-98 MW-9 28 1 11 22.1
13 Nov-98 MW-9 10 1 12 20
14 May-99 MW-9 20 5 14.9 20
15 Oct-99 MW-9 120 10 16 19.1
16 May-00 MW-9 ND 10 16 19
17 Nov-00 MW-9 ND 10 17 17
18 May-01 MW-9 ND 10 19 16
19 Nov-01 MW-9 ND 10 19.1 16
20 Nov-02 MW-9 ND 10 20 14.9
21 May-03 MW-9 19 10 20 12
22 Nov-03 MW-9 26 10 22.1 11
23 May-04 MW-9 ND 10 26 10
24 Nov-04 MW-9 10 10 26 10
25 May-05 MW-9 12 10 28 10
26 May-99 MW-17 26 10 28 9.8
27 Oct-99 MW-17 37 10 29 9.2
28 May-00 MW-17 ND 10 33 7.8
29 Nov-00 MW-17 20 10 35 7.3
30 May-01 MW-17 ND 10 37 5.4
31 Nov-01 MW-17 ND 10 37 4.1
32 Nov-02 MW-17 ND 10 52 4.0
33 May-03 MW-17 ND 10 120 2.6
34 Nov-03 MW-17 10 J 10
35 May-04 MW-17 ND 10
36 Nov-04 MW-17 ND 10
37 May-05 MW-17 ND 10
38 Nov-05 MW-17 ND 10
39 25-May-06 MW-17 ND 10
40 02-Nov-06 MW-17 ND 10
41 31-May-07 MW-17 4.1 J 10
42 29-Nov-07 MW-17 7.3 J 10
43 29-May-08 MW-17 5.4 J 10
44 06-Nov-08 MW-17 9.2 J 10
45 18-Nov-09 MW-17 14.9 10
46 16-Jun-10 MW-17 19.1 10
47 01-Dec-10 MW-17 9.8 J 10.0
48 01-Dec-10 MW-20 22.1 10.0
49 13-Jan-11 MW-20 ND 10.0
50 01-Jun-11 MW-17 7.8 J 10.0
51 01-Jun-11 MW-20 2.6 J 10.0
52 20-Dec-11 MW-20 ND 10.0
53 30-May-12 MW-20 ND 10.0
54 05-Dec-12 MW-20 ND 10.0
55 12-Jun-13 MW-20 ND 10.0
56 28-Oct-13 MW-20 ND 10.0
57 06-May-14 MW-20 ND 10.0
58 23-Oct-14 MW-21 ND 10.0
59 21-May-15 MW-21 ND 10.0
60 08-Dec-15 MW-21 ND 10.0
61 03-May-16 MW-21 4.0 J 10.0
62 13-Dec-16 MW-21 ND 10.0
63 27-Jun-17 MW-21 ND 11.0
Number of Data: 63
Number of Truncated Data: 30
Percentage of Truncated Data: 48%
Upper Tolerance Limit: 88.2 µg/L
Notes: All concentrations in micrograms per liter (µg/L).
J = Estimated Data (used in statistical analyses)
ND = Not detected (truncated).
Sorted
Concentration
Joyce Project:Burke County - Johns River Landfill
Project No: 277.1801.12
Date: June 2017
Shapiro Wilk Test Statistic (W) for normality of total Cobalt
Complete the following table where
i = ordered value of sample, arranged from smallest to largest
X(i) = sample values arranged from smallest to largest
X(n-i+1) = sample values arranged from largest to smallest
A(n-i+1) = coefficient from table A-1, Statistical Analysis of Ground-Water
Data at RCRA Facilities
B(i) = summation of (X(n-i+1)-X(i))A(n-i+1)
i X(i) X(n-i+1) X(n-i+1) - X(i) A(n-i+1) B(i)
1 2.6 120 117.40 0.4156 48.7914
2 4.0 52 48.00 0.2876 13.8048
3 4.1 37 32.90 0.2451 8.0638
4 5.4 37 31.60 0.2137 6.7529
5 7.3 35 27.70 0.1880 5.2076
6 7.8 33 25.20 0.1660 4.1832
7 9.2 29 19.80 0.1463 2.8967
8 9.8 28 18.20 0.1284 2.3369
9 10.0 28 18.00 0.1118 2.0124
10 10.0 26 16.00 0.0961 1.5376
11 10.0 26 16.00 0.0812 1.2992
12 11.0 22 11.10 0.0669 0.7426
13 12.0 20 8.00 0.0530 0.4240
14 14.9 20 5.10 0.0395 0.2015
15 16.0 19 3.10 0.0262 0.08
16 16.0 19 3.00 0.0131 0.04
17 17.0 17 0.00 0.0000 0.00
18 19.0 16 -3.00
19 19.1 16 -3.10
20 20.0 15 -5.10
21 20.0 12 -8.00
22 22.1 11 -11.10
23 26.0 10 -16.00
24 26.0 10 -16.00
25 28.0 10 -18.00
26 28.0 10 -18.20
27 29.0 9 -19.80
28 33.0 8 -25.20
29 35.0 7 -27.70
30 37.0 5 -31.60
31 37.0 4 -32.90
32 52.0 4 -48.00
33 120.0 3 -117.40
The test statistic W can be found using:
W = SQR[B/(SD x SQRT(n-1))]
where:B = summation of (X(n-i+1)-X(i))A(n-i+1)= 98.38
SD = standard deviation of the data group = 21.10
n = number of samples = 33
W = 0.679
Compare this value to the critical value in Table A-2 of Statistical Analysisof Ground-Water
Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance (Draft)
July, 1992, to determine if the data is normally distributed.
From Table A-2 with (n) samples and a 95% confidence level, the critical value is
W(crit) = 0.931
and the calculated W = 0.679
Therefore the data is Non-Normal.
Joyce Project:Burke County - Johns River Landfill
Project No: 277.1801.12
Date: June 2017
Shapiro Wilk Test Statistic (W) for log normality of Cobalt
Complete the following table where
i = ordered value of sample, arranged from smallest to largest
X(i) = sample values arranged from smallest to largest
X(n-i+1) = sample values arranged from largest to smallest
A(n-i+1) = coefficient from table A-1, Statistical Analysis of Ground-Water
Data at RCRA Facilities
B(i) = summation of (X(n-i+1)-X(i))A(n-i+1)
i X(i) X(n-i+1) X(n-i+1) - X(i) A(n-i+1) B(i)
1 0.96 4.79 3.8320 0.4156 1.5926
2 1.39 3.95 2.5649 0.2876 0.7377
3 1.41 3.61 2.1999 0.2451 0.5392
4 1.69 3.61 1.9245 0.2137 0.4113
5 1.99 3.56 1.5675 0.1880 0.2947
6 2.05 3.50 1.4424 0.1660 0.2394
7 2.22 3.37 1.1481 0.1463 0.1680
8 2.28 3.33 1.0498 0.1284 0.1348
9 2.30 3.33 1.0296 0.1118 0.1151
10 2.30 3.26 0.9555 0.0961 0.0918
11 2.30 3.26 0.9555 0.0812 0.0776
12 2.40 3.10 0.6977 0.0669 0.0467
13 2.48 3.00 0.5108 0.0530 0.0271
14 2.70 3.00 0.2944 0.0395 0.0116
15 2.77 2.95 0.1771 0.0262 0.0046
16 2.77 2.94 0.1719 0.0131 0.0023
17 2.83 2.83 0.0000 0.0000 0.0000
18 2.94 2.77 -0.1719
19 2.95 2.77 -0.1771
20 3.00 2.70 -0.2944
21 3.00 2.48 -0.5108
22 3.10 2.40 -0.6977
23 3.26 2.30 -0.9555
24 3.26 2.30 -0.9555
25 3.33 2.30 -1.0296
26 3.33 2.28 -1.0498
27 3.37 2.22 -1.1481
28 3.50 2.05 -1.4424
29 3.56 1.99 -1.5675
30 3.61 1.69 -1.9245
31 3.61 1.41 -2.1999
32 3.95 1.39 -2.5649
33 4.79 0.96 -3.8320
The test statistic W can be found using:
W = SQR((B/SD x SQRT(n-1))
where:B = summation of (X(n-i+1)-X(i))A(n-i+1) = 4.4944
SD = standard deviation of the data group = 0.8011
n = number of samples = 33
W = 0.9835
Compare this value to the critical value in Table A-2 of Statistical Analysisof Ground-Water
Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance (Draft)
July, 1992, to determine if the data is normally distributed.
From Table A-2 with (n) samples and a 95% confidence level, the critical value is
W(crit) = 0.931
and the calculated W = 0.984
Therefore the data set is Log-Normal.
Joyce Project:Burke County - Johns River Landfill
Project No: 277.1801.12
Date: June 2017
Probability Plots to determine the distribution of Cobalt
Complete the following table where
i = ordered value of sample, arranged from smallest to largest
X(i) = sample values arranged from smallest to largest
LN[X(i)] = Natural Log Value of sample concentrations arranged from
smallest to largest
[i/(n+1)] = Cumulative probability
n = number of samples = 33
X(i)LN[X(i)] i Rank [Rank/(n+1)] Quantiles
2.6 0.96 1 1 0.029 -1.89
4 1.39 2 2 0.059 -1.56
4.1 1.41 3 3 0.088 -1.35
5.4 1.69 4 4 0.118 -1.19
7.3 1.99 5 5 0.147 -1.05
7.8 2.05 6 6 0.176 -0.93
9.2 2.22 7 7 0.206 -0.82
9.8 2.28 8 8 0.235 -0.72
10 2.30 9 9 0.265 -0.63
10 2.30 10 10 0.294 -0.54
10 2.30 11 11 0.324 -0.46
11 2.40 12 12 0.353 -0.38
12 2.48 13 13 0.382 -0.30
14.9 2.70 14 14 0.412 -0.22
16 2.77 15 15 0.441 -0.15
16 2.77 16 16 0.471 -0.07
17 2.83 17 17 0.500 0.00
19 2.94 18 18 0.529 0.07
19.1 2.95 19 19 0.559 0.15
20 3.00 20 20 0.588 0.22
20 3.00 21 21 0.618 0.30
22.1 3.10 22 22 0.647 0.38
26 3.26 23 23 0.676 0.46
26 3.26 24 24 0.706 0.54
28 3.33 25 25 0.735 0.63
28 3.33 26 26 0.765 0.72
29 3.37 27 27 0.794 0.82
33 3.50 28 28 0.824 0.93
35 3.56 29 29 0.853 1.05
37 3.61 30 30 0.882 1.19
37 3.61 31 31 0.912 1.35
52 3.95 32 32 0.941 1.56
120 4.79 33 33 0.971 1.89
Plot analysis indicates that the data more closely follow a normal distribution in the
log-transformed format.
Joyce Project:Burke County - Johns River Landfill
Project No: 277.1801.12
Date: June 2017
Probability Plots to determine the distribution of Cobalt
R² = 0.6351
-2.50
-2.00
-1.50
-1.00
-0.50
0.00
0.50
1.00
1.50
2.00
050100150Quantile
Concentration (micrograms per liter)
Normal Probability Plot
Cobalt Concentrations
R² = 0.972
-2.00
-1.50
-1.00
-0.50
0.00
0.50
1.00
1.50
2.00
2.50
3.00
0.00 1.00 2.00 3.00 4.00 5.00 6.00Quantile
Ln [Concentration (micrograms per liter)]
Log Normal Probability Plot
Cobalt Concentrations
Joyce Project:Burke County - Johns River Landfill
Project No: 277.1801.12
Date: June 2017
Determination of reported background value as an outlier
Analyte:Cobalt
Background Data
Sample No. Sample Date Location ln(Concentration)
1 Sep-94 MW-9 3.951
2 Jan-95 MW-9 3.555
3 Feb-95 MW-9 2.773
4 Mar-95 MW-9 3.332
5 Aug-95 MW-9 ND
6 Jan-96 MW-9 2.833
7 Feb-96 MW-9 3.611
8 May-96 MW-9 2.398
9 Oct-96 MW-9 2.773
10 May-97 MW-9 3.49711 Nov-97 MW-9 3.367
12 May-98 MW-9 3.332
13 Nov-98 MW-9 2.303
14 May-99 MW-9 2.996
15 Oct-99 MW-9 4.787
16 May-00 MW-9 ND
17 Nov-00 MW-9 ND
18 May-01 MW-9 ND
19 Nov-01 MW-9 ND20 Nov-02 MW-9 ND
21 May-03 MW-9 2.944
22 Nov-03 MW-9 3.258
23 May-04 MW-9 ND
24 Nov-04 MW-9 2.303
25 May-05 MW-9 2.485
26 May-99 MW-17 3.258
27 Oct-99 MW-17 3.611
28 May-00 MW-17 ND
29 Nov-00 MW-17 2.996
30 May-01 MW-17 ND
31 Nov-01 MW-17 ND
32 Nov-02 MW-17 ND
33 May-03 MW-17 ND
34 Nov-03 MW-17 2.303
35 May-04 MW-17 ND
36 Nov-04 MW-17 ND
37 May-05 MW-17 ND
38 Nov-05 MW-17 ND
39 May-06 MW-17 ND
40 Nov-06 MW-17 ND
41 May-07 MW-17 1.411
42 Nov-07 MW-17 1.988
43 May-08 MW-17 1.686
44 Nov-08 MW-17 2.21945 Nov-09 MW-17 2.701
46 Jun-10 MW-17 2.950
47 Dec-10 MW-17 2.282
48 Dec-10 MW-20 3.096
49 Jan-11 MW-20 ND
50 Jun-11 MW-17 2.054
51 Jun-11 MW-20 0.956
52 Dec-11 MW-20 ND
53 May-12 MW-20 ND
54 Dec-12 MW-20 ND
55 Jun-13 MW-20 ND
56 Oct-13 MW-20 ND
57 May-14 MW-20 ND
58 Oct-14 MW-21 ND
59 May-15 MW-21 ND
60 Dec-15 MW-21 ND
61 May-16 MW-21 1.386
62 Dec-16 MW-21 ND
mean = 2.770
STD = 0.801
Note: All concentrations are micrograms per liter (µg/L)
Using the data listed above, form the statisitc Tn:
Tn = (Xn - mean) / STD
where: Xn = largest observed sample value
mean = mean of the background values
STD = standard deviation of the background values
For Xn = 4.787
mean = 2.770
STD = 0.801
Tn = 2.519
From Table 8 included in the Staistical Analysis of Groundwater Monitoring Data at
RCRA Facilities - Interim Final Guidance, the critical value for the given sample group is
Number of samples = 33
Tc = 2.736
Since Tc>Tn, the sample result is not considered to be an outlier
Joyce Project:Burke County - Johns River Landfill
Project No: 277.1801.12
Date: June 2017
Aitchison's Adjustment for Cobalt
Background Values (positive detects only)
Concentration ln(conc)
Sample No. Sample Date Location (µg/l)
1 Sep-94 MW-9 52 3.951
2 Jan-95 MW-9 35 3.5553Feb-95 MW-9 16 2.773
4 Mar-95 MW-9 28 3.332
5 Aug-95 MW-9 ND -
6 Jan-96 MW-9 17 2.833
7 Feb-96 MW-9 37 3.611
8 May-96 MW-9 11 2.398
9 Oct-96 MW-9 16 2.773
10 May-97 MW-9 33 3.497
11 Nov-97 MW-9 29 3.367
12 May-98 MW-9 28 3.332
13 Nov-98 MW-9 10 2.303
14 May-99 MW-9 20 2.996
15 Oct-99 MW-9 120 4.787
16 May-00 MW-9 ND -
17 Nov-00 MW-9 ND -
18 May-01 MW-9 ND -
19 Nov-01 MW-9 ND -
20 Nov-02 MW-9 ND -
21 May-03 MW-9 19 2.944
22 Nov-03 MW-9 26 3.258
23 May-04 MW-9 ND -
24 Nov-04 MW-9 10 2.303
25 May-05 MW-9 12 2.485
26 May-99 MW-17 26 3.258
27 Oct-99 MW-17 37 3.611
28 May-00 MW-17 ND -
29 Nov-00 MW-17 20 2.996
30 May-01 MW-17 ND -
31 Nov-01 MW-17 ND -
32 Nov-02 MW-17 ND -
33 May-03 MW-17 ND -
34 Nov-03 MW-17 10 2.303
35 May-04 MW-17 ND -
36 Nov-04 MW-17 ND -37 May-05 MW-17 ND -
38 Nov-05 MW-17 ND -
39 May-06 MW-17 ND -
40 Nov-06 MW-17 ND -
41 May-07 MW-17 4.1 1.411
42 Nov-07 MW-17 7.3 1.988
43 May-08 MW-17 5.4 1.686
44 Nov-08 MW-17 9.2 2.219
45 Nov-09 MW-17 14.9 2.701
46 Jun-10 MW-17 19.1 2.950
47 Dec-10 MW-17 9.8 2.282
48 Dec-10 MW-20 22.1 3.096
49 Jan-11 MW-20 ND -
50 Jun-11 MW-17 7.8 2.054
51 Jun-11 MW-20 2.6 0.956
52 Dec-11 MW-20 ND -
53 May-12 MW-20 ND -
54 Dec-12 MW-20 ND -
55 Jun-13 MW-20 ND -
56 Oct-13 MW-20 ND -
57 May-14 MW-20 ND -
58 Oct-14 MW-21 ND -
59 May-15 MW-21 ND -
60 Dec-15 MW-21 ND -
61 May-16 MW-21 4 1.386
62 Dec-16 MW-21 ND -63 Jun-17 MW-21 ND -
Mean of detected values = 2.77
Standard Deviation of detected values = 0.80
The adjusted mean can be found using
M(a) = (1-d/n) x M
where:d = number non- detected values = 30
n = total number samples = 63
M = mean detected values = 2.77
M(a) = 1.45
The adjusted standard deviation squared may be found using
STD(a) = [(n-(d+1))/(n-1)] S + d/n((n-d)/(n-1))MM
where:n = total number samples = 62
d = number non-detected values = 29
S = std deviation of detected values squared = 0.64
MM = mean of detected values squared = 7.67
STD(a) = 2.28
and the adjusted standard deviation is then
S(a) = SQRT(STD(a)) = 1.51
Joyce Project:Burke County - Johns River Landfill
Project No: 277.1801.12
Date: June 2017
Parametric Tolerance Interval for Aitchison's adjusted data
Analyte:Cobalt
Background Data
Sample No. Sample Date Location Concentration ln(Concentration)
1 Sep-94 MW-9 52 3.951
2 Jan-95 MW-9 35 3.555
3 Feb-95 MW-9 16 2.773
4 Mar-95 MW-9 28 3.332
5 Aug-95 MW-9 ND -
6 Jan-96 MW-9 17 2.833
7 Feb-96 MW-9 37 3.611
8 May-96 MW-9 11 2.398
9 Oct-96 MW-9 16 2.773
10 May-97 MW-9 33 3.497
11 Nov-97 MW-9 29 3.367
12 May-98 MW-9 28 3.332
13 Nov-98 MW-9 10 2.303
14 May-99 MW-9 20 2.996
15 Oct-99 MW-9 120 4.787
16 May-00 MW-9 ND -
17 Nov-00 MW-9 ND -
18 May-01 MW-9 ND -
19 Nov-01 MW-9 ND -
20 Nov-02 MW-9 ND -
21 May-03 MW-9 19 2.944
22 Nov-03 MW-9 26 3.258
23 May-04 MW-9 ND -
24 Nov-04 MW-9 10 2.303
25 May-05 MW-9 12 2.485
26 May-99 MW-17 26 3.258
27 Oct-99 MW-17 37 3.611
28 May-00 MW-17 ND -
29 Nov-00 MW-17 20 2.996
30 May-01 MW-17 ND -
31 Nov-01 MW-17 ND -
32 Nov-02 MW-17 ND -
33 May-03 MW-17 ND -
34 Nov-03 MW-17 10 2.303
35 May-04 MW-17 ND -
36 Nov-04 MW-17 ND -
37 May-05 MW-17 ND -
38 Nov-05 MW-17 ND -
39 May-06 MW-17 ND -
40 Nov-06 MW-17 ND -
41 May-07 MW-17 4 1.411
42 Nov-07 MW-17 7 1.988
43 May-08 MW-17 5 1.686
44 Nov-08 MW-17 9 2.219
45 Nov-09 MW-17 15 2.701
46 Jun-10 MW-17 19 2.950
47 Dec-10 MW-17 10 2.282
48 Dec-10 MW-20 22 3.096
49 Jan-11 MW-20 ND -
50 Jun-11 MW-17 8 2.054
51 Jun-11 MW-20 3 0.956
52 Dec-11 MW-20 ND -
53 May-12 MW-20 ND -
54 Dec-12 MW-20 ND -
55 Jun-13 MW-20 ND -
56 Oct-13 MW-20 ND -
57 May-14 MW-20 ND -
58 Oct-14 MW-21 ND -
59 May-15 MW-21 ND -
60 Dec-15 MW-21 ND -
61 May-16 MW-21 4 1.386
62 Dec-16 MW-21 ND -
Note: All sample concentrations are micrograms per liter (µg/L)
The background mean and standard deviation were modified using Aitchison's Adjustment.
The adjusted mean and standard deviation are as follows:
The ln(adjusted mean) and ln(standard deviation) are
ln(adjusted mean) = 1.45
ln(adjusted standard deviation) = 1.51
Using the background data, the upper Tolerance Limit can be determined using
Upper Tolerance Limit = (Mean Concentration) + K x (Standard Deviation Samples)
where: K = factor for constructing one sided normal tolerance limit
taken from table 4-2, page 87, Statistical Methods for Groundwater
Monitoring, Gibbons, 1994
n = number of background samples
For: K = 2.007
n = 63
UTL = 88.2 µg/L
JOYCE Project:Burke County - Johns River Landfill
Project No: 277.1801.12
Task No: 03
Date: June 2017
Analyte:Cobalt (Intrawell MW-10)
Sample No. Sample Date Location Concentration RL
1 18-Jan-95 MW-10 35.0 10 26.0 340
2 6-Feb-95 MW-10 43.0 10 29.0 280
3 Mar-95 MW-10 57.0 10 35.0 243
4 Aug-95 MW-10 58.0 10 37.0 170
5 Jan-96 MW-10 37.0 10 40.0 140
6 Feb-96 MW-10 41.0 10 41.0 140
7 May-96 MW-10 26.0 10 43.0 139
8 Oct-96 MW-10 52.0 10 46.6 131
9 May-97 MW-10 120 6 48.0 130
10 Nov-97 MW-10 99.0 5 52.0 126
11 May-98 MW-10 120 1 53.0 120
12 Nov-98 MW-10 140 1 54.0 120
13 11-May-99 MW-10 48.0 5 57.0 99.0
14 18-Oct-99 MW-10 85.0 10 58.0 96
15 3-May-00 MW-10 54.0 10 60.0 92.8
16 7-Nov-00 MW-10 40.0 10 66.0 90.2
17 31-May-01 MW-10 53.0 10 67.2 90.0
18 7-Nov-01 MW-10 29.0 10.0 68.0 87.2
19 22-May-02 MW-10 68.0 10 71.9 85.0
20 14-Nov-02 MW-10 90.0 10 71.9 80.3
21 14-May-03 MW-10 280 10 72.7 76.4
22 20-Nov-03 MW-10 340 10 76.4 72.7
23 6-May-04 MW-10 140 10 80.3 71.9
24 10-Nov-04 MW-10 170 10 85.0 71.9
25 5-May-05 MW-10 130 10 87.2 68.0
26 3-Nov-05 MW-10 66.0 10 90.0 67.2
27 25-May-06 MW-10 80.3 10 90.2 66.0
28 2-Nov-06 MW-10 131 10 92.8 60.0
29 30-May-07 MW-10 87.2 10 96 58.0
30 29-Nov-07 MW-10 67.2 10 99.0 57.0
31 29-May-08 MW-10 71.9 10 120 54.0
32 6-Nov-08 MW-10 71.9 10.0 120 53.0
33 3-Jun-09 MW-10 139 10.0 126 52.0
34 27-Aug-09 MW-10 60.0 10.0 130 48.0
35 18-Nov-09 MW-10 126 10.0 131 46.6
36 16-Jun-10 MW-10 96 10.0 139 43.0
37 1-Dec-10 MW-10 72.7 10.0 140 41.0
38 1-Jun-11 MW-10 76.4 10.0 140 40.0
39 20-Dec-11 MW-10 92.8 10.0 170 37.0
40 30-May-12 MW-10 90.2 10.0 243 35.0
41 5-Dec-12 MW-10 46.6 10.0 280 29.0
42 12-Jun-13 MW-10 243.0 10.0 340 26.0
Number of Data: 42
Number of Truncated Data: 0
Percentage of Truncated Data: 0%
Upper Tolerance Limit: 271 µg/L
Notes: All concentrations in micrograms per liter (µg/L).
Data excludes the most recent eight sampling events.
Sorted
Concentration
JEI Project:Burke County - Johns River Landfill
Project No: 277.1801.12
Date: June 2017
Shapiro Wilk Test Statistic (W) for normality of total Cobalt (Intrawell MW-10)
Complete the following table where
i = ordered value of sample, arranged from smallest to largest
X(i) = sample values arranged from smallest to largest
X(n-i+1) = sample values arranged from largest to smallest
A(n-i+1) = coefficient from table A-1, Statistical Analysis of Ground-Water
Data at RCRA Facilities
B(i) = summation of (X(n-i+1)-X(i))A(n-i+1)
i X(i) X(n-i+1) X(n-i+1) - X(i) A(n-i+1) B(i)
1 26.0 340 314.00 0.3917 122.9938
2 29.0 280 251.00 0.2710 68.0210
3 35.0 243 208.00 0.2345 48.7760
4 37.0 170 133.00 0.2085 27.7305
5 40.0 140 100.00 0.1874 18.7400
6 41.0 140 99.00 0.1694 16.7706
7 43.0 139 96.00 0.1535 14.7360
8 46.6 131 84.40 0.1392 11.7485
9 48.0 130 82.00 0.1259 10.3238
10 52.0 126 74.00 0.1136 8.4064
11 53.0 120 67.00 0.1020 6.8340
12 54.0 120 66.00 0.0909 5.9994
13 57.0 99 42.00 0.0804 3.3768
14 58.0 96 38.10 0.0701 2.6708
15 60.0 93 32.80 0.0602 1.9746
16 66.0 90 24.20 0.0506 1.2245
17 67.2 90 22.80 0.0411 0.9371
18 68.0 87 19.20 0.0318 0.6106
19 71.9 85 13.10 0.0227 0.2974
20 71.9 80 8.40 0.0136 0.1142
21 72.7 76 3.70 0.0045 0.0167
22 76.4 73 -3.70
23 80.3 72 -8.40
24 85.0 72 -13.10
25 87.2 68 -19.20
26 90.0 67 -22.80
27 90.2 66 -24.20
28 92.8 60 -32.80
29 96.1 58 -38.10
30 99.0 57 -42.00
31 120.0 54 -66.00
32 120.0 53 -67.00
33 126.0 52 -74.00
34 130.0 48 -82.00
35 131.0 47 -84.40
36 139.0 43 -96.00
37 140.0 41 -99.00
38 140.0 40 -100.00
39 170.0 37 -133.00
40 243.0 35 -208.00
41 280.0 29 -251.00
42 340.0 26 -314.00
The test statistic W can be found using:
W = SQR[B/(SD x SQRT(n-1))]
where: B = summation of (X(n-i+1)-X(i))A(n-i+1) = 372.30
SD = standard deviation of the data group = 65.48
n = number of samples = 42
W = 0.788
Compare this value to the critical value in Table A-2 of Statistical Analysisof Ground-Water
Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance (Draft)
July, 1992, to determine if the data is normally distributed.
From Table A-2 with (n) samples and a 95% confidence level, the critical value is
W(crit) = 0.922
and the calculated W = 0.788
Therefore the data is Non-Normal
JOYCE Project:Burke County - Johns River Landfill
Project No: 277.1801.12
Task No: 03
Date:June 2017
Shapiro Wilk Test Statistic (W) for log normality of Cobalt (Intrawell MW-10)
Complete the following table where
i = ordered value of sample, arranged from smallest to largest
X(i) = sample values arranged from smallest to largest
X(n-i+1) = sample values arranged from largest to smallest
A(n-i+1) = coefficient from table A-1, Statistical Analysis of Ground-Water
Data at RCRA Facilities
B(i) = summation of (X(n-i+1)-X(i))A(n-i+1)
i X(i) X(n-i+1) X(n-i+1) - X(i) A(n-i+1) B(i)
1 3.26 5.83 2.5708 0.3917 1.0070
2 3.37 5.63 2.2675 0.2710 0.6145
3 3.56 5.49 1.9377 0.2345 0.4544
4 3.61 5.14 1.5249 0.2085 0.3179
5 3.69 4.94 1.2528 0.1874 0.2348
6 3.71 4.94 1.2281 0.1694 0.2080
7 3.76 4.93 1.1733 0.1535 0.1801
8 3.84 4.88 1.0336 0.1392 0.1439
9 3.87 4.87 0.9963 0.1259 0.1254
10 3.95 4.84 0.8850 0.1136 0.1005
11 3.97 4.79 0.8172 0.1020 0.0834
12 3.99 4.79 0.7985 0.0909 0.0726
13 4.04 4.60 0.5521 0.0804 0.0444
14 4.06 4.57 0.5049 0.0701 0.0354
15 4.09 4.53 0.4361 0.0602 0.0263
16 4.19 4.50 0.3124 0.0506 0.0158
17 4.21 4.50 0.2921 0.0411 0.0120
18 4.22 4.47 0.2487 0.0318 0.0079
19 4.28 4.44 0.1674 0.0227 0.0038
20 4.28 4.39 0.1105 0.0136 0.0015
21 4.29 4.34 0.0496 0.0045 0.0002
22 4.34 4.29 -0.0496
23 4.39 4.28 -0.1105
24 4.44 4.28 -0.1674
25 4.47 4.22 -0.2487
26 4.50 4.21 -0.2921
27 4.50 4.19 -0.3124
28 4.53 4.09 -0.4361
29 4.57 4.06 -0.5049
30 4.60 4.04 -0.5521
31 4.79 3.99 -0.7985
32 4.79 3.97 -0.8172
33 4.84 3.95 -0.8850
34 4.87 3.87 -0.9963
35 4.88 3.84 -1.0336
36 4.93 3.76 -1.1733
37 4.94 3.71 -1.2281
38 4.94 3.69 -1.2528
39 5.14 3.61 -1.5249
40 5.49 3.56 -1.9377
41 5.63 3.37 -2.2675
42 5.83 3.26 -2.5708
The test statistic W can be found using:
W = SQR((B/SD x SQRT(n-1))
where:B = summation of (X(n-i+1)-X(i))A(n-i+1) = 3.6898
SD = standard deviation of the data group = 0.5827
n = number of samples =42
W = 0.9779
Compare this value to the critical value in Table A-2 of Statistical Analysisof Ground-Water
Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance (Draft)
July, 1992, to determine if the data is normally distributed.
From Table A-2 with (n) samples and a 95% confidence level, the critical value is
W(crit) = 0.922
and the calculated W = 0.978
Therefore the data set is Log-Normal.
JOYCE Project:Burke County - Johns River Landfill
Project No: 277.1801.12
Task No: 03
Date: June 2017
Probability Plots to determine the distribution of Cobalt (Intrawell MW-10)
Complete the following table where
i = ordered value of sample, arranged from smallest to largest
X(i) = sample values arranged from smallest to largest
LN[X(i)] = Natural Log Value of sample concentrations arranged from
smallest to largest
[i/(n+1)] = Cumulative probability
n = number of samples = 42
X(i)LN[X(i)] i Rank [Rank/(n+1)] Quantiles
26 3.26 1 1 0.023 -1.99
29 3.37 2 2 0.047 -1.68
35 3.56 3 3 0.070 -1.48
37 3.61 4 4 0.093 -1.32
40 3.69 5 5 0.116 -1.19
41 3.71 6 6 0.140 -1.08
43 3.76 7 7 0.163 -0.98
46.6 3.84 8 8 0.186 -0.89
48 3.87 9 9 0.209 -0.81
52 3.95 10 10 0.233 -0.73
53 3.97 11 11 0.256 -0.66
54 3.99 12 12 0.279 -0.59
57 4.04 13 13 0.302 -0.52
58 4.06 14 14 0.326 -0.45
60 4.09 15 15 0.349 -0.39
66 4.19 16 16 0.372 -0.33
67.2 4.21 17 17 0.395 -0.27
68 4.22 18 18 0.419 -0.21
71.9 4.28 19 19 0.442 -0.15
71.9 4.28 20 20 0.465 -0.09
72.7 4.29 21 21 0.488 -0.03
76.4 4.34 22 22 0.512 0.03
80.3 4.39 23 23 0.535 0.09
85 4.44 24 24 0.558 0.15
87.2 4.47 25 25 0.581 0.21
90 4.50 26 26 0.605 0.27
90.2 4.50 27 27 0.628 0.33
92.8 4.53 28 28 0.651 0.39
96.1 4.57 29 29 0.674 0.45
99 4.60 30 30 0.698 0.52
120 4.79 31 31 0.721 0.59
120 4.79 32 32 0.744 0.66
126 4.84 33 33 0.767 0.73
130 4.87 34 34 0.791 0.81
131 4.88 35 35 0.814 0.89
139 4.93 36 36 0.837 0.98
140 4.94 37 37 0.860 1.08
140 4.94 38 38 0.884 1.19
170 5.14 39 39 0.907 1.32
280 5.49 40 40 0.930 1.48
340 5.63 41 41 0.953 1.68
341 5.83 42 42 0.977 1.99
Plot analysis indicates that the data more closely follow a normal distribution in the
log-transformed format.
JOYCE Project:Burke County - Johns River Landfill
Project No: 277.1801.12
Task No: 03
Date: June 2017
Probability Plots to determine the distribution of Cobalt (Intrawell MW-10)
R² = 0.7251
-2.50
-2.00
-1.50
-1.00
-0.50
0.00
0.50
1.00
1.50
2.00
0 100 200 300 400Quantile
Concentration (micrograms per liter)
Normal Probability Plot
Cobalt Concentrations
R² = 0.9805
-2.00
-1.50
-1.00
-0.50
0.00
0.50
1.00
1.50
2.00
2.50
3.00
0.00 2.00 4.00 6.00 8.00Quantile
Ln [Concentration (micrograms per liter)]
Log Normal Probability Plot
Cobalt Concentrations
JOYCE Project:Burke County - Johns River Landfill
Project No: 277.1801.12
Task No: 03
Date:June 2017
Determination of reported background value as an outlier
Analyte:Cobalt (Intrawell MW-10)
Background Data
Sample No. Sample Date Location ln(Concentration)
1 Jan-95 MW-10 3.555
2 Feb-95 MW-10 3.761
3 Mar-95 MW-10 4.043
4 Aug-95 MW-10 4.060
5 Jan-96 MW-10 3.611
6 Feb-96 MW-10 3.714
7 May-96 MW-10 3.258
8 Oct-96 MW-10 3.951
9 May-97 MW-10 4.787
10 Nov-97 MW-10 4.595
11 May-98 MW-10 4.787
12 Nov-98 MW-10 4.942
13 May-99 MW-10 3.871
14 Oct-99 MW-10 4.443
15 May-00 MW-10 3.989
16 Nov-00 MW-10 3.689
17 May-01 MW-10 3.970
18 Nov-01 MW-10 3.367
19 May-02 MW-10 4.220
20 Nov-02 MW-10 4.500
21 May-03 MW-10 5.635
22 Nov-03 MW-10 5.829
23 May-04 MW-10 4.942
24 Nov-04 MW-10 5.136
25 May-05 MW-10 4.868
26 Nov-05 MW-10 4.190
27 May-06 MW-10 4.386
28 Nov-06 MW-10 4.875
29 May-07 MW-10 4.468
30 Nov-07 MW-10 4.208
31 May-08 MW-10 4.275
32 Nov-08 MW-10 4.275
33 Jun-09 MW-10 4.934
34 Aug-09 MW-10 4.094
35 Nov-09 MW-10 4.836
36 Jun-10 MW-10 4.565
37 Dec-10 MW-10 4.286
38 Jun-11 MW-10 4.336
39 Dec-11 MW-10 4.530
40 May-12 MW-10 4.502
41 Dec-12 MW-10 3.842
42 Jun-13 MW-10 5.493
mean = 4.372
STD = 0.583
Note: All concentrations are micrograms per liter (µg/L)
Using the data listed above, form the statisitc Tn:
Tn = (Xn - mean) / STD
where:Xn = largest observed sample value
mean = mean of the background values
STD = standard deviation of the background values
For Xn = 5.829
mean = 4.372
STD = 0.583
Tn = 2.500
From Table 8 included in the Staistical Analysis of Groundwater Monitoring Data at
RCRA Facilities - Interim Final Guidance, the critical value for the given sample group is
Number of samples =42
Tc = 2.887
Since Tc>Tn, the sample result is not considered to be an outlier
JOYCE Project:Burke County - Johns River Landfill
Project No: 277.1801.12
Task No: 03
Date: June 2017
Parametric Tolerance Interval for log normally distributed data
Analyte:Cobalt (Intrawell MW-10)
Background Data: Note use of log(concentration)
Background Data Quantitation
Concentration Limit Natural Log
Sample No. Sample Date Location (µg/L) Notes (µg/L) Concentration
1 18-Jan-95 MW-10 35 10 3.555
2 06-Feb-95 MW-10 43 10 3.761
3 01-Mar-95 MW-10 57 10 4.043
4 01-Aug-95 MW-10 58 10 4.060
5 01-Jan-96 MW-10 37 10 3.611
6 01-Feb-96 MW-10 41 10 3.714
7 01-May-96 MW-10 26 10 3.258
8 01-Oct-96 MW-10 52 10 3.951
9 01-May-97 MW-10 120 6 4.787
10 01-Nov-97 MW-10 99 5 4.595
11 01-May-98 MW-10 120 1 4.787
12 01-Nov-98 MW-10 140 1 4.942
13 11-May-99 MW-10 48 5 3.871
14 18-Oct-99 MW-10 85 10 4.443
15 03-May-00 MW-10 54 10 3.989
16 07-Nov-00 MW-10 40 10 3.689
17 31-May-01 MW-10 53 10 3.970
18 07-Nov-01 MW-10 29 10 3.367
19 22-May-02 MW-10 68 10 4.220
20 14-Nov-02 MW-10 90 10 4.500
21 14-May-03 MW-10 280 10 5.635
22 20-Nov-03 MW-10 340 10 5.829
23 06-May-04 MW-10 140 10 4.942
24 10-Nov-04 MW-10 170 10 5.136
25 05-May-05 MW-10 130 10 4.868
26 03-Nov-05 MW-10 66 10 4.190
27 25-May-06 MW-10 80 10 4.386
28 02-Nov-06 MW-10 131 10 4.875
29 30-May-07 MW-10 87 10 4.468
30 29-Nov-07 MW-10 67 10 4.208
31 29-May-08 MW-10 72 10 4.275
32 06-Nov-08 MW-10 72 10 4.275
33 03-Jun-09 MW-10 139 10 4.934
34 27-Aug-09 MW-10 60 10 4.094
35 18-Nov-09 MW-10 126 10 4.836
36 16-Jun-10 MW-10 96 10 4.565
37 01-Dec-10 MW-10 72.7 10 4.286
38 01-Jun-11 MW-10 76.4 10 4.336
39 20-Dec-11 MW-10 92.8 10 4.530
40 30-May-12 MW-10 90.2 10 4.502
41 05-Dec-12 MW-10 46.6 10 3.842
42 12-Jun-13 MW-10 243.0 10 5.493
Note: All sample concentrations are micrograms per liter
Using the background data, the upper Tolerance Limit can be determined using:
Upper Tolerance Limit = antilog((Mean Concentration)+K x (Standard Deviation Samples))
where: Mean Conc = mean concentration background samples
K = factor for constructing one sided normal tolerance limit
taken from table 4-2, page 87, Statistical Methods for Groundwate
Monitoring, Gibbons, 1994
STDS = Standard Deviation Samples
n = number of background samples
For: n = 42
K = 2.114
Mean Conc = 4.372
STDS = 0.583
UTL = 271 µg/L

Appendix D

Historical Detected Inorganic Groundwater Constituents

APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Inorganic Compounds
Antimony 30-May-07 --- 6 --- ND --- --- ND ND 1.09 J ND ND ND ND
GWPS = 1.4 µg/L (10/23/07) 29-Nov-07 --- 6 --- ND --- --- ND ND 1.94 J ND ND ND ND
29-May-08 2.6 6.0 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 2.6 6.0 --- ND --- --- ND ND 2.7 J ND 5.9 J ND ND
3-Jun-09 2.6 6.0 --- ND --- --- ND ND ND ND ND 3.2 J ND
18-Nov-09 2.6 6.0 --- ND --- --- ND ND ND ND ND ND ND
16-Jun-10 2.6 6.0 --- ND --- --- ND ND 2.8 J ND ND ND ND
GWPS = 1 µg/L (8/1/10) 1-Dec-10 2.6 6.0 --- ND ND --- ND 3.5 J 2.9 J ND ND ND ND
1-Jun-11 2.6 6.0 --- ND ND --- ND ND ND ND ND 2.9 J ND
20-Dec-11 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.0 6.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 3.8 6.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 3.8 6.0 --- --- --- ND ND ND 6.3 ND ND ND ND
Lab Re-run Analyses> 8-Dec-15 3.8 6.0 --- --- --- --- --- ---6.2 --- ------ ---
Resample> 4-Feb-16 3.8 6.0 --- --- --- --- --- --- ND --- ------ ND
3-May-16 3.8 6.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 3.8 6.0 --- --- --- ND ND ND ND ND ND ND ND
27-Jun-17 3.9 6.0 --- --- --- ND ND ND ND ND ND ND ---
Arsenic 30-May-07 --- 10 --- ND --- --- ND 2.2 B ND 3.6 B ND 2.1 B 2.6 J
NC 2L = 50 µg/L (10/23/07) 29-Nov-07 --- 10 --- 2.5 J --- --- ND ND ND ND 2.1 J ND ND
29-May-08 2.7 10.0 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 2.7 10.0 --- ND --- --- ND 3.1 B ND 3.2 B 3 B ND 4.1 J
3-Jun-09 2.7 10.0 --- ND --- --- ND ND ND ND ND 3.2 J ND
18-Nov-09 2.7 10.0 --- ND --- --- 3.0 J ND ND ND ND ND ND
NC 2L = 10 µg/L (01/01/10) 16-Jun-10 2.7 10.0 --- ND --- --- ND 4.6 J ND ND 3.0 J ND ND
1-Dec-10 2.7 10.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 2.7 10.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 2.5 10.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 2.5 10.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 2.5 10.0 --- --- --- ND ND 3.7 J ND ND ND ND ND
13-Dec-16 2.5 10.0 --- --- --- ND 3.2 J ND ND ND ND 3.5 J ND
27-Jun-17 5.0 10.0 --- --- --- ND ND ND ND ND ND ND ---
Barium 15-Sep-94 --- 100 1320 NI NI NI 194 5580 ND 584 NI NI ND
1-Oct-94 --- 100 --- NI NI NI --- 1030 --- --- NI NI ND
18-Jan-95 --- 100 981 NI NI NI 122 1490 ND 355 NI NI ND
6-Feb-95 --- 100 435 NI NI NI 124 350 ND 311 NI NI ND
1-Mar-95 --- 100 556 NI NI NI 260 732 196 528 NI NI ND
1-Aug-95 --- 100 199 NI --- --- 250 688 ND 408 NI NI ND
1-Jan-96 --- 100 455 NI --- --- 228 734 196 ND NI NI ND
1-Feb-96 --- 100 306 NI --- --- 211 321 288 ND NI NI ND
1-May-96 --- 100 170 NI --- --- ND 453 319 ND NI NI ND
1-Oct-96 --- 100 302 NI --- --- 234 447 102 ND NI NI ND
1-May-97 --- 100 330 NI --- --- 170 360 400 ND NI NI ND
1-Nov-97 --- 100 800 NI --- --- 200 600 800 100 NI NI ND
1-May-98 --- 100 400 NI --- --- 200 400 1200 200 NI NI ND
1-Nov-98 --- 100 140 NI --- --- 270 310 880 ND NI NI ND
11-May-99 --- 5 240 200 --- --- 70 130 200 60 220 16 ND
18-Oct-99 --- 500 1900 ND --- --- ND ND 1400 ND ND ND ND
3-May-00 --- 500 ND ND --- --- ND ND ND ND 730 ND ND
7-Nov-00 --- 500 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 500 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 500 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 500 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 500 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 500 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 500 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 500 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 500 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 500 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 500 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 500 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 500 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 100 --- 52.0 J --- --- 48.1 J 132 88.4 J 66.9 J 50.9 J 8.0 J 0.20 J
NC 2L = 2,000 µg/L (10/23/07) 29-Nov-07 --- 100 --- 214 --- --- 54.8 J 232 97.0 J 75.3 J 57.9 J 8.6 J 0.50 J
29-May-08 0.20 100 --- 67.9 J --- --- 41.5 J 148 71.0 J 77.0 J 43.7 J 7.9 J ND
6-Nov-08 0.20 100 --- 82.3 J --- --- 45.5 B 118 81.2 J 90.6 J 66.7 J 7.1 B 9.6 J
3-Jun-09 0.20 100 --- 34.2 B --- --- 26.9 B 119 67.6 B 66.9 B 49.5 B 9.8 B 15.9 J
18-Nov-09 0.20 100 --- 78.9 B --- --- 36.3 B 116 88.6 B 81.0 B 46.6 B 7.8 B 20.1 J
NC 2L = 700 µg/L (01/01/10)16-Jun-10 0.20 100 --- 58.1 J --- --- 50.5 J 296 103 73.4 J 47.0 J 8.6 J 0.77 J
1-Dec-10 0.20 100 --- 60.1 J 376 --- 59.6 J 134 94.1 J 78.7 J 37.5 J 16.3 J ND
1-Jun-11 0.20 100 --- 55.6 J 164 --- 43.3 J 154 74.3 J 74.4 J 44.7 J 12.3 J ND
20-Dec-11 5.0 100 --- --- 119 --- 50.9 J 138 76.6 J 78.3 J 46.7 J 10.5 J ND
30-May-12 5.0 100 --- --- 96.7 J --- 40.6 J 137 77.7 J 74.5 J 67.8 J 9.1 J ND
5-Dec-12 5.0 100 --- --- 63.0 J --- 53.3 J 148 89.8 J 81.4 J 43.6 J 10.5 J ND
12-Jun-13 5.0 100 --- --- 59.6 B --- 28.3 B 167 82.3 J 83.6 J 48.1 B 13.2 B 13.6 J
28-Oct-13 5.0 100 --- --- 47.9 J --- 47.4 J 194 93.8 J 70.7 J 49.4 J 9.6 J ND
6-May-14 5.0 100 --- --- 73.6 J --- 37.3 J 129 89.9 J 73.9 J 45.5 J 8.2 J ND
23-Oct-14 5.0 100 --- --- * 20.3 J 53.4 J 127 74.6 J 76.0 J 46.3 J 13.3 J ND
20-May-15 2.5 100 --- --- --- 17.9 47.5 J 145 75.5 J 76.9 J 44.6 J 8.4 J ND
8-Dec-15 2.5 100 --- --- --- 17.6 J 45.6 J 140 132 82.6 J 50.6 J 8.0 J ND
3-May-16 2.5 100 --- --- --- 26.6 J 43.6 J 156 82.4 J 87.3 J 51.2 J 9.5 J ND
13-Dec-16 2.5 100 --- --- --- 13.4 J 66.0 J 128 83.2 J 80.9 J 48.1 J 10.0 J ND
27-Jun-17 2.5 100 --- --- --- 18.8 J 47.4 J 127 81.1 J 76.2 J 50.7 J 9.9 J ---
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 1 of 10 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Beryllium 1-May-97 --- 1 ND NI --- --- ND ND 1.0 ND NI NI ND
1-Nov-97 --- 1 1.0 NI --- --- ND 3.0 ND ND NI NI ND
1-May-98 --- 1 ND NI --- --- ND ND 3.0 ND NI NI ND
1-Nov-98 --- 1 ND NI --- --- ND ND 1 ND NI NI ND
11-May-99 --- 2 ND ND --- --- ND ND ND ND 4.3 ND ND
18-Oct-99 --- 2 8.0 3.0 J --- --- 2.0 J 2.0 J 13.0 ND ND ND ND
3-May-00 --- 2 ND ND --- --- ND ND ND ND 8.0 ND ND
7-Nov-00 --- 2 ND 2.0 --- --- ND ND ND ND ND ND ND
31-May-01 --- 2 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 2 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 2 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 2 ND ND --- --- ND ND ND ND ND ND 2.1
14-May-03 --- 2 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 2 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 2 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 2 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 2 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 2 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 2 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 2 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 1 --- ND --- --- ND ND ND ND ND ND ND
GWPS = 4 µg/L (10/23/07)29-Nov-07 --- 1 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.10 1.0 --- ND --- --- 0.18 J ND ND ND ND ND ND
6-Nov-08 0.10 1.0 --- 0.49 B --- --- 0.65 B 0.32 B 0.42 B 0.61 B 0.53 B 0.27 B 0.29 J
3-Jun-09 0.10 1.0 --- ND --- --- ND ND ND 0.25 J 0.23 J 2.2 ND
18-Nov-09 0.10 1.0 --- ND --- --- ND ND ND 0.25 J ND ND ND
16-Jun-10 0.10 1.0 --- ND --- --- 0.24 J 0.94 J ND 0.11 J ND ND ND
1-Dec-10 0.10 1.0 --- ND 1.7 --- 0.14 J ND ND ND ND ND ND
1-Jun-11 0.10 1.0 --- ND 0.44 J --- J ND ND ND ND ND ND ND
20-Dec-11 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 1.0 1.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND
27-Jun-17 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ---
Cadmium 1-May-97 --- 1 ND NI --- --- ND ND 1.0 ND NI NI ND
1-Nov-97 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-May-98 --- 1 ND NI --- --- ND ND 1.0 ND NI NI ND
1-Nov-98 --- 1 ND NI --- --- ND ND 2.0 ND NI NI ND
11-May-99 --- 1 ND ND --- --- ND ND ND ND ND ND ND
18-Oct-99 --- 1 24.0 6.0 --- --- 6.0 3.0 J 30.0 2.0 J 2.0 J ND ND
3-May-00 --- 1 ND ND --- --- ND 1.0 J 1.0 J ND 5.0 ND ND
7-Nov-00 --- 1 2.0 5.0 --- --- ND ND 1.0 ND 1.0 ND ND
31-May-01 --- 1 ND ND --- --- ND ND 1.0 J ND 1.0 J ND ND
7-Nov-01 --- 1 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 1 ND ND --- --- ND ND ND 2.0 B ND ND 1.3
14-Nov-02 --- 1 ND ND --- --- ND ND 1.2 ND 3.7 ND ND
14-May-03 --- 1 ND ND --- --- 1.1 ND ND ND 2.5 ND ND
20-Nov-03 --- 1 2.0 1.3 --- --- ND ND 1.2 ND ND ND ND
6-May-04 --- 1 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 1 ND ND --- --- 1.5 ND ND ND 2.2 ND ND
5-May-05 --- 1 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 1 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 1 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 1 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 1 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 1.75 µg/L (10/23/07)29-Nov-07 --- 1 --- ND --- --- ND ND 0.60 J ND ND ND ND
29-May-08 0.50 1.0 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 0.50 1.0 --- ND --- --- ND ND ND ND 0.94 J ND ND
3-Jun-09 0.50 1.0 --- ND --- --- ND ND ND ND ND 1.9 ND
18-Nov-09 0.50 1.0 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 2 µg/L (01/01/10)16-Jun-10 0.50 1.0 --- ND --- --- ND 6.0 ND ND ND ND ND
Resample> 5-Aug-10 0.50 1.0 --- --- --- --- --- 1.2 --- --- ------ ND
1-Dec-10 0.50 1.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 0.50 1.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 1.0 1.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 0.5 1.0 --- --- --- ND ND 0.85 J ND ND ND ND ND
8-Dec-15 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND
27-Jun-17 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ---
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 2 of 10 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Chromium 1-Mar-95 --- 5 ND NI NI NI ND ND 11.0 ND NI NI ND
1-Aug-95 --- 5 ND NI --- --- ND ND ND ND NI NI ND
1-Jan-96 --- 5 ND NI --- --- ND ND 7.0 ND NI NI ND
1-Feb-96 --- 5 ND NI --- --- ND ND 6.0 ND NI NI ND
1-May-96 --- 5 ND NI --- --- ND ND 16.0 ND NI NI ND
1-Oct-96 --- 5 ND NI --- --- ND ND 6.0 ND NI NI ND
1-May-97 --- 1 4.0 NI --- --- 2.0 3.0 18.0 3.0 NI NI ND
1-Nov-97 --- 1 6.0 NI --- --- 1.0 1.0 108 2.0 NI NI ND
1-May-98 --- 1 8.0 NI --- --- 4.0 6.0 66.0 6.0 NI NI ND
1-Nov-98 --- 1 3.0 NI --- --- 1.0 3.0 180 3.0 NI NI ND
11-May-99 --- 5 26.0 24.0 --- --- 8.4 6.5 44.0 11.0 46.0 ND ND
18-Oct-99 --- 10 290 58.0 --- --- 44.0 36.0 410 21.0 ND ND ND
3-May-00 --- 10 ND ND --- --- ND ND 12.0 ND 92.0 ND ND
7-Nov-00 --- 10 11.0 30.0 --- --- ND ND ND ND ND ND ND
31-May-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 10 ND ND --- --- ND ND ND ND 10.0 ND ND
14-Nov-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 10 12.0 ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 10 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 10 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 50 µg/L (10/23/07)29-Nov-07 --- 10 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.40 10.0 --- ND --- --- ND 1.9 B 1 B 1.4 B ND ND 0.85 J
6-Nov-08 0.40 10.0 --- 0.59 J --- --- 1 J 0.83 J 2.8 J 3.4 J 2.5 J ND ND
3-Jun-09 0.40 10.0 --- ND --- --- ND 2.1 J ND 1.1 J 0.66 J 2.1 J ND
18-Nov-09 0.40 10.0 --- ND --- --- ND ND 2.2 J 2.2 J ND ND ND
NC 2L = 10 µg/L (01/01/10)16-Jun-10 0.40 10.0 --- 0.43 B --- --- 1.0 B 13.9 4.7 J 1.0 B ND ND 0.74 J
Resample> 5-Aug-10 0.40 10.0 --- --- --- --- --- 0.88 B --- --- ------ 0.51 J
1-Dec-10 0.40 10.0 --- 0.60 B 39.6 --- 1.8 B 1.3 B 5.5 J 1.2 B ND ND 0.51 J
Resample> 13-Jan-11 0.40 10.0 --- --- ND --- --- --- --- --- ------ ND
1-Jun-11 0.40 10.0 --- ND 11.2 --- ND 1.2 B 0.72 B ND ND ND 0.73 J
Resample> 7-Jul-11 0.40 10.0 --- --- 7.8 J --- --- --- --- --- ------ ND
20-Dec-11 5.0 10.0 --- --- 8.2 J --- ND ND ND ND ND ND ND
30-May-12 5.0 10.0 --- --- 5.3 J --- ND ND ND ND 5.4 J ND ND
5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 5.0 10.0 --- --- 6.1 J --- ND ND ND ND ND ND ND
23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 2.5 10.0 --- --- --- ND ND 3.9 J ND ND ND 4.7 J ND
8-Dec-15 2.5 10.0 --- --- --- ND ND ND 13.8 ND ND ND ND
Lab Re-run Analyses> 8-Dec-15 2.5 10.0 --- --- --- --- --- ---14.7 --- ------ ---
Resample> 4-Feb-16 2.5 10.0 --- --- --- --- --- --- ND --- ------ ND
3-May-16 2.5 10.0 --- --- --- 4.2 J ND 3.1 J 4.1 J 4.5 J ND ND ND
13-Dec-16 2.5 10.0 --- --- --- ND ND 3.7 J 4.4 J ND ND ND ND
27-Jun-17 2.5 10.0 --- --- --- ND ND 3.9 J 5.8 J ND ND ND ---
Cobalt 18-Jan-95 --- 10 35.0 NI NI NI 35.0 14.0 52.0 14.0 NI NI ND
6-Feb-95 --- 10 16.0 NI NI NI 43.0 ND 66.0 ND NI NI ND
Mar-95 --- 10 28.0 NI NI NI 57.0 ND 78.0 20.0 NI NI ND
Aug-95 --- 10 ND NI --- --- 58.0 ND 30.0 32.0 NI NI ND
Jan-96 --- 10 17.0 NI --- --- 37.0 ND 23.0 ND NI NI ND
Feb-96 --- 10 37.0 NI --- --- 41.0 ND 24.0 ND NI NI ND
May-96 --- 10 11.0 NI --- --- 26.0 ND 24.0 ND NI NI ND
Oct-96 --- 10 16.0 NI --- --- 52.0 ND 16.0 ND NI NI ND
May-97 --- 6 33.0 NI --- --- 120 5.0 J 32.0 6.0 NI NI ND
Nov-97 --- 5 29.0 NI --- --- 99.0 11.0 48.0 14.0 NI NI ND
May-98 --- 1 28.0 NI --- --- 120 8.0 76.0 32.0 NI NI ND
Nov-98 --- 1 10.0 NI --- --- 140 6.0 47.0 1.0 NI NI ND
11-May-99 --- 5 20.0 26.0 --- --- 48.0 13.0 34.0 17.0 59.0 ND ND
18-Oct-99 --- 10 120 37.0 --- --- 85.0 20.0 220 16.0 40.0 ND ND
3-May-00 --- 10 ND ND --- --- 54.0 ND 31.0 13.0 89.0 ND ND
7-Nov-00 --- 10 ND 20.0 --- --- 40.0 ND 18.0 ND 32.0 ND ND
31-May-01 --- 10 ND ND --- --- 53.0 ND 30.0 11.0 32.0 ND ND
7-Nov-01 --- 10 ND ND --- --- 29.0 ND 23.0 ND 26.0 ND ND
22-May-02 --- 10 14.0 B 14.0 B --- --- 68.0 16.0 B 51.0 B 17.0 B 39.0 B 12.0 B 11.0
14-Nov-02 --- 10 ND ND --- --- 90.0 ND 41.0 11.0 34.0 ND ND
14-May-03 --- 10 19.0 ND --- --- 280 ND 46.0 53.0 24.0 ND ND
20-Nov-03 --- 10 26.0 10.0 J --- --- 340 18.0 56.0 58.0 30.0 ND ND
6-May-04 --- 10 ND ND --- --- 140 ND 46.0 47.0 29.0 ND ND
10-Nov-04 --- 10 10.0 ND --- --- 170 21.0 50.0 46.0 29.0 ND ND
5-May-05 --- 10 12.0 ND --- --- 130 16.0 46.0 60.0 26.0 ND ND
3-Nov-05 --- 10 --- ND --- --- 66.0 15.0 42.0 45.0 25.0 ND ND
25-May-06 --- 10 --- ND --- --- 80.3 21.7 42.7 43.2 24.9 ND ND
2-Nov-06 --- 10 --- ND --- --- 131 30.8 37.0 28.3 26.6 ND ND
30-May-07 --- 10 --- 4.1 J --- --- 87.2 20.7 44.0 36.9 26.6 ND ND
GWPS = 70 µg/L (10/23/07)29-Nov-07 --- 10 --- 7.3 J --- ---67.2 55.5 47.9 J 23.4 30.7 ND ND
29-May-08 0.60 10.0 --- 5.4 J --- ---71.9 54.6 34.8 35.3 ND ND ND
6-Nov-08 0.60 10.0 --- 9.2 J --- ---71.9 60.0 47.9 44.1 24.3 2.2 B 1.6 J
3-Jun-09 0.60 10.0 --- 22.8 B --- ---139 78.6 53.5 49.3 54.7 7.6 B 7.6 J
Resample> 27-Aug-09 0.60 10.0 --- --- --- --- 60.0 --- --- --- ------ ---
18-Nov-09 0.60 10.0 --- 14.9 --- ---126 84.5 50.3 44.1 31.8 ND ND
16-Jun-10 0.60 10.0 --- 19.1 --- ---96.1 103 70.9 38.0 48.6 ND ND
Resample> 5-Aug-10 0.60 10.0 --- --- --- --- ---85.5 --- --- ------ ND
GWPS = 1 µg/L (10/1/10)1-Dec-10 0.60 10.0 --- 9.8 J 22.1 ---72.7 151 111 43.1 33.3 ND ND
Resample> 13-Jan-11 0.60 10.0 --- --- ND --- ---84.2 --- --- ------ ND
1-Jun-11 0.60 10.0 --- 7.8 J 2.6 J --- J 76.4 99.3 72.9 41.7 38.6 ND ND
20-Dec-11 5.0 10.0 --- --- ND ---92.8 75.6 62.7 36.5 25.5 ND ND
30-May-12 5.0 10.0 --- --- ND ---90.2 108 78.8 42.3 46.2 ND ND
5-Dec-12 5.0 10.0 --- --- ND ---46.6 27.9 101 45.8 51.4 ND ND
12-Jun-13 5.0 10.0 --- --- ND ---243 150 118 92.2 66.0 ND ND
28-Oct-13 5.0 10.0 --- --- ND ---200 128 124 117 75.7 ND ND
Resample> 10-Dec-13 5.0 10.0 --- --- --- --- --- --- ---40.4 ------ ND
6-May-14 5.0 10.0 --- --- ND ---138 33.4 68.9 65.9 26.6 ND ND
22-Oct-14 5.0 10.0 --- --- * ND 126 37.1 82.0 74.9 32.1 ND ND
20-May-15 2.5 10.0 --- --- --- ND 116 34.8 77.8 90.0 34.0 ND ND
8-Dec-15 2.5 10.0 --- --- --- ND 175 61.0 84.8 49.7 32.8 ND ND
3-May-16 2.5 10.0 --- --- --- 4.0 J 132 52.6 69.7 85.0 27.6 ND ND
13-Dec-16 2.5 10.0 --- --- --- ND 93.2 52.4 70.6 58.8 28.1 ND ND
27-Jun-17 2.5 10.0 --- --- --- ND 121 60.5 74.0 75.5 35.4 ND ---
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 3 of 10 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Copper 18-Jan-95 --- 10 16.0 NI NI NI ND ND ND 14.0 NI NI ND
6-Feb-95 --- 10 ND NI NI NI ND ND ND ND NI NI ND
1-Mar-95 --- 10 ND NI NI NI ND ND ND 20.0 NI NI ND
1-Aug-95 --- 10 ND NI --- --- ND ND ND 18.0 NI NI ND
1-Jan-96 --- 10 ND NI --- --- ND ND ND ND NI NI ND
1-Feb-96 --- 10 21.0 NI --- --- ND ND ND ND NI NI ND
1-May-96 --- 10 14.0 NI --- --- 13.0 11.0 ND 11.0 NI NI ND
1-Oct-96 --- 10 ND NI --- --- ND ND ND ND NI NI ND
1-May-97 --- 10 ND NI --- --- 30.0 ND ND ND NI NI ND
1-Nov-97 --- 10 ND NI --- --- ND ND ND ND NI NI ND
1-May-98 --- 10 20.0 NI --- --- ND 10.0 70.0 20.0 NI NI ND
1-Nov-98 --- 10 ND NI --- --- 13.0 ND 28.0 ND NI NI ND
11-May-99 --- 5 28.0 49.0 --- --- 14.0 ND 9.3 28.0 37.0 ND ND
18-Oct-99 --- 200 380 ND --- --- ND ND 240 ND ND ND ND
3-May-00 --- 200 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 200 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 200 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 200 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 200 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 200 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 200 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 200 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 200 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 200 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 200 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 200 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 200 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 200 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 10 --- 0.7 B --- --- ND ND ND 3.2 B ND ND 1.3 J
NC 2L = 1,000 µg/L (10/23/07) 29-Nov-07 --- 10 --- 8.30 J --- --- ND ND ND 6.10 J ND ND ND
29-May-08 0.30 10.0 --- 0.42 B --- --- 0.99 B 1.5 B 1.0 B 14.9 0.89 B ND 0.37 J
6-Nov-08 0.30 10.0 --- 2.0 B --- --- 1.8 B 0.7 B 2.4 B 16.6 4.2 J 0.46 B 0.65 J
3-Jun-09 0.30 10.0 --- 0.83 J --- --- ND 1 J ND 6.7 J 0.61 J 3.5 J ND
18-Nov-09 0.30 10.0 --- 0.34 J --- --- ND ND 1.2 J 10.7 0.38 J ND ND
16-Jun-10 0.30 10.0 --- 0.37 B --- --- 2.6 B 9.0 J 3.2 B 3.4 B ND ND 0.77 J
1-Dec-10 0.30 10.0 --- 1.3 J 36.1 --- 3.8 J 1.2 J 1.8 J 3.9 J 2.1 J ND ND
1-Jun-11 0.30 10.0 --- 0.54 J 12.9 --- 0.94 J 2.3 J 0.79 J 4.8 J 0.66 J ND ND
20-Dec-11 5.0 10.0 --- --- 9.0 J --- ND ND ND ND ND ND ND
30-May-12 5.0 10.0 --- --- 7.0 J --- ND ND ND ND 5.6 J ND ND
5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND 5.6 J ND ND ND
12-Jun-13 5.0 10.0 --- --- 34.0 B --- ND ND ND 11.1 B ND ND 9.8 J
28-Oct-13 5.0 10.0 --- --- ND --- ND 6.1 J ND ND ND ND ND
6-May-14 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 2.5 10.0 --- --- --- ND ND ND ND 4.6 J ND ND ND
8-Dec-15 2.5 10.0 --- --- --- ND 8.1 J 6.4 J 9.7 J ND 5.9 J ND ND
3-May-16 2.5 10.0 --- --- --- 8.7 J ND ND ND 9.6 J ND 8.6 J ND
13-Dec-16 2.5 10.0 --- --- --- 4.1 J ND ND ND ND ND ND ND
27-Jun-17 2.5 10.0 --- --- --- 3.9 J ND ND ND ND ND ND ---
Cyanide 1-Nov-98 --- 2 6.0 NI --- --- 2.0 ND 7.0 ND NI NI ND
11-May-99 --- 2 ND ND --- --- ND ND ND ND ND ND ND
18-Oct-99 --- 50 ND ND --- --- --- ND ND ND ND ND ND
7-Nov-00 --- 50 ND --- --- --- ND ND ND ND ND --- ND
31-May-01 --- 50 ND --- --- --- ND ND ND ND ND --- ND
7-Nov-01 --- 50 ND --- --- --- ND ND ND ND ND --- ND
14-Nov-02 --- 50 ND --- --- --- ND ND ND ND ND --- ND
20-Nov-03 --- 50 ND --- --- --- ND ND ND ND ND --- ND
10-Nov-04 --- 10 ND --- --- --- ND ND ND ND ND --- ND
3-Nov-05 --- --- --- ND --- --- ND ND ND ND ND --- ND
2-Nov-06 --- 50 --- ND --- --- ND ND ND ND ND --- ND
NC 2L = 70 µg/L (10/23/07)29-Nov-07 --- 10 --- ND --- --- ND ND ND ND ND --- ND
6-Nov-08 5.0 10.0 --- ND --- --- ND ND ND ND ND --- ND
18-Nov-09 5.0 10.0 --- ND --- --- ND ND ND ND ND --- ND
1-Dec-10 5.0 10.0 --- ND 5.9 J --- ND ND 5.2 J 5.8 J 6.5 J --- ND
Resample> 13-Jan-11 5.0 10.0 --- --- ND --- --- --- 5.0 J ND 5.8 J --- ND
5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND 7.0 J --- ND
28-Oct-13 5.0 10.0 --- --- ND --- 12.4 5.6 J 10.0 ND 6.5 J ND ND
Resample> 10-Dec-13 5.0 10.0 --- --- --- --- 10.8 --- 9.0 J --- ------ ND
6-May-14 0.0 0.0 --- --- ND --- ND ND ND ND ND --- ND
23-Oct-14 2.5 10.0 --- --- * ND 3.6 J 4.7 J 4.2 J ND 5.2 J --- ND
20-May-15 0.0 10.0 --- --- --- ND ND ND ND ND ND --- ND
8-Dec-15 4.0 10.0 --- --- --- ND ND ND ND ND ND --- ND
3-May-16 4.0 10.0 --- --- --- ND ND ND 5.3 J ND ND --- ND
13-Dec-16 4.0 10.0 --- --- --- ND ND ND ND ND ND --- ND
27-Jun-17 4.0 10.0 --- --- --- ND ND ND ND ND 4.3 J --- ---
Iron 1-Jun-11 14.0 300 ---308 11,000 ---20,500 29,200 16,300 886 22,200 413 ND
NC 2L = 300 µg/L (01/01/10) Resample>7-Jul-11 50.0 300 --- ---7,150 --- --- --- --- --- --- --- ND
20-Dec-11 50.0 300 --- ---8,010 ---26,300 36,700 22,900 1,160 22,200 93.5 J ND
30-May-12 50.0 300 --- ---5,940 ---24,500 45,700 21,700 1,300 24,500 ND ND
5-Dec-12 50.0 300 --- ---2,970 ---7,010 8,730 28,200 393 21,700 159 J ND
12-Jun-13 50.0 300 --- ---2,460 ---55,300 55,300 34,800 4,650 26,700 522 81.2 J
28-Oct-13 50.0 300 --- ---883 ---28,700 49,700 29,800 1,730 24,300 ND ND
6-May-14 50.0 300 --- ---4,240 ---47,300 46,800 29,700 1,200 24,600 ND ND
23-Oct-14 50.0 300 --- --- *2,340 33,600 29,200 31,200 528 27,700 171 J ND
20-May-15 25.0 300 --- --- ---350 22,400 22,600 33,800 672 25,800 63.5 J ND
8-Dec-15 25.0 300 --- --- ---1,380 102,000 74,200 50,200 1,460 27,400 43.7 J ND
3-May-16 25.0 300 --- --- ---7,630 39,300 67,900 42,400 3,870 24,000 168 J 27.3 J
13-Dec-16 25.0 300 --- --- ---2,020 17,600 67,800 45,300 969 24,000 217 J ND
27-Jun-17 25.0 300 --- --- ---2,340 58,100 67,400 51,800 1,230 29,100 213 J ---
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 4 of 10 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Lead 15-Sep-94 --- 5 41.0 NI NI NI 12.0 49.0 7.0 43.0 NI NI ND
1-Oct-94 --- 5 --- NI NI NI --- 9.0 --- --- NI NI ND
18-Jan-95 --- 5 35.0 NI NI NI 9.0 17.0 10.0 30.0 NI NI ND
6-Feb-95 --- 5 15.0 NI NI NI 7.0 ND ND 26.0 NI NI ND
1-Mar-95 --- 5 26.0 NI NI NI 16.0 12.0 9.0 43.0 NI NI ND
1-Aug-95 --- 5 11.0 NI --- --- 25.0 16.0 6.0 48.0 NI NI ND
1-Jan-96 --- 5 22.0 NI --- --- 18.0 12.0 10.0 7.0 NI NI ND
1-Feb-96 --- 5 16.0 NI --- --- 15.0 6.0 9.0 10.0 NI NI ND
1-May-96 --- 5 7.0 NI --- --- 8.0 9.0 15.0 ND NI NI ND
1-Oct-96 --- 5 15.0 NI --- --- 24.0 10.0 7.0 6.0 NI NI ND
1-May-97 --- 5 16.0 NI --- --- 23.0 10.0 22.0 16.0 NI NI ND
1-Nov-97 --- 5 40.0 NI --- --- 27.0 14.0 30.0 24.0 NI NI ND
1-May-98 --- 5 18.0 NI --- --- 9.0 ND 10.0 6.0 NI NI ND
1-Nov-98 --- 5 7.0 NI --- --- 39.0 9.0 47.0 14.0 NI NI ND
11-May-99 --- 10 14.0 18.0 --- --- ND ND ND ND ND ND ND
18-Oct-99 --- 10 160 54.0 --- --- 56.0 27.0 140 23.0 ND ND ND
3-May-00 --- 10 ND ND --- --- ND ND ND ND 11.0 J ND ND
7-Nov-00 --- 10 ND 20.0 --- --- ND ND ND ND ND ND ND
31-May-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 10 ND 19.0 --- --- ND ND ND 20.0 ND ND ND
6-May-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 10 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 10 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 10 --- 2.5 J --- --- ND ND ND 2.3 J ND ND ND
NC 2L = 15 µg/L (10/23/07)29-Nov-07 --- 10 --- 7.5 J --- --- ND 6.1 J ND 5.1 J ND ND ND
29-May-08 4.0 10.0 --- ND --- --- ND ND ND 6.8 ND ND ND
6-Nov-08 4.0 10.0 --- ND --- --- ND ND ND 8.8 J ND ND ND
3-Jun-09 4.0 10.0 --- ND --- --- ND ND ND ND ND ND ND
18-Nov-09 4.0 10.0 --- ND --- --- ND ND ND 5.5 J ND ND ND
16-Jun-10 4.0 10.0 --- ND --- --- 4.4 J 13.9 ND ND ND ND ND
1-Dec-10 4.0 10.0 --- ND 16.8 --- ND ND ND ND ND ND ND
Resample> 13-Jan-11 4.0 10.0 --- ND ND --- --- --- --- --- ------ ND
1-Jun-11 4.0 10.0 --- ND 5.9 J --- ND ND ND ND ND ND ND
20-Dec-11 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 5.0 10.0 --- --- ND --- ND 5.5 J ND 5.6 J ND ND ND
28-Oct-13 5.0 10.0 --- --- ND --- ND 5.2 J ND ND ND ND ND
6-May-14 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 2.5 10.0 --- --- --- ND 4.9 J 4.3 J ND ND 2.7 J ND ND
8-Dec-15 2.5 10.0 --- --- --- ND 7.8 J 6.3 J 9.8 J ND ND ND ND
3-May-16 2.5 10.0 --- --- --- ND ND 6.8 J 5.3 J 3.3 J 3.8 J ND ND
13-Dec-16 2.5 10.0 --- --- --- ND ND 3.5 J 2.6 J ND ND ND ND
27-Jun-17 2.5 10.0 --- --- --- ND 3.0 J 3.9 J 5.0 J ND ND ND ---
Manganese 1-Jun-11 0.30 50.0 ---385 209 ---5,770 14,500 9,330 1,160 8,460 123 0.36 J
NC 2L = 50 µg/L (01/01/10) Resample>7-Jul-11 5.0 50.0 --- --- 143 --- --- --- --- --- ------ ND
20-Dec-11 5.0 50.0 --- ---136 ---6,670 15,500 D 9,480 1,030 8,540 119 ND
30-May-12 5.0 50.0 --- ---104 ---6,700 14,300 9,370 1,170 8,790 119 ND
5-Dec-12 5.0 50.0 --- ---54.5 ---2,650 8,930 9,150 1,230 9,180 122 ND
12-Jun-13 5.0 50.0 --- --- 49.3 J ---16,800 15,400 11,700 2,060 8,150 130 ND
28-Oct-13 5.0 50.0 --- ---80.0 ---8,420 15,000 9,910 2,500 9,680 124 ND
6-May-14 50.0 500.0 --- ---83.5 ---12,300 18,300 9,950 1,600 9,720 119 ND
23-Oct-14 50.0 500.0 --- --- *73.6 9,400 23,200 11,000 1,740 11,500 115 ND
20-May-15 2.5 50.0 --- --- --- 27.4 9,070 29,800 10,800 2,010 12,400 121 ND
8-Dec-15 12.5 50.0 --- --- --- 50.0 J 15,000 18,100 10,800 1,500 8,440 124 ND
3-May-16 2.5 50.0 --- --- ---142 7,850 17,500 9,140 1,810 6,600 119 ND
13-Dec-16 2.5 50.0 --- --- --- 48.1 J 5,100 17,900 8,850 1,560 10,900 122 ND
27-Jun-17 2.5 50.0 --- --- --- 60.3 8,910 19,900 10,200 1,750 11,000 131 ---
Mercury 16-Aug-95 --- 0.2 0.30 B NI --- --- 0.30 B 0.30 B 0.20 B 0.30 B NI NI 0.2
25-Jan-96 --- 0.2 1.6 NI --- --- 0.40 0.70 ND 1.3 NI NI ND
28-Feb-96 --- 0.2 ND NI --- --- 2.4 ND ND 0.20 NI NI ND
1-May-96 --- 0.2 1.4 NI --- --- 1.7 1.5 2.1 2.3 NI NI ND
1-Oct-96 --- 0.5 ND NI --- --- ND ND ND ND NI NI ND
1-May-97 --- --- --- NI --- --- NS NS NS NS NI NI NS
1-Nov-97 --- 0.2 ND NI --- --- 0.80 ND ND ND NI NI ND
1-May-98 --- 0.2 ND NI --- --- 0.80 ND ND 0.40 NI NI ND
1-Nov-98 --- 0.2 ND NI --- --- 1.3 ND ND 0.49 NI NI ND
11-May-99 --- 0.2 --- ND --- --- --- --- --- --- ND ND ---
18-Oct-99 --- 0.5 ND ND --- --- --- ND ND 0.55 ND ND ND
3-May-00 --- 0.5 --- --- --- --- --- --- --- --- ------ ---
7-Nov-00 --- 0.5 ND --- --- --- ND ND ND ND ND --- ND
31-May-01 --- 0.5 ND --- --- --- 0.70 ND ND 0.90 ND --- ND
7-Nov-01 --- 0.5 ND --- --- --- ND ND ND 1.0 ND --- ND
22-May-02 --- 0.5 ND --- --- --- 0.62 ND ND ND ND --- ND
14-Nov-02 --- 0.5 ND --- --- --- ND ND ND ND ND --- ND
14-May-03 --- 0.5 ND --- --- --- ND ND ND ND ND --- ND
20-Nov-03 --- 0.5 ND --- --- --- 0.80 ND ND 0.73 ND --- ND
6-May-04 --- 0.5 ND --- --- --- 0.71 ND ND 0.52 ND --- ND
10-Nov-04 --- 0.5 ND --- --- --- ND ND ND 0.74 ND --- ND
5-May-05 --- 0.5 ND --- --- --- ND ND ND ND ND --- ND
3-Nov-05 --- 0.5 --- ND --- --- 1.0 ND ND ND ND --- ND
25-May-06 --- 2 --- --- --- --- ND ND ND ND ND --- ND
2-Nov-06 --- 0.5 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 0.2 --- --- --- --- 0.12 J ND ND 0.13 J ND --- ---
NC 2L = 1.05 µg/L (10/23/07)29-Nov-07 --- 0.2 --- ND --- --- 0.88 ND ND 0.50 ND ND ND
29-May-08 0.090 0.20 --- --- --- --- 0.12 B ND 0.13 B 0.66 0.12 B --- 0.1 J
6-Nov-08 0.090 0.20 --- ND --- --- ND ND ND 0.41 ND ND ND
3-Jun-09 0.070 0.20 --- ND --- --- ND ND ND 0.14 J ND --- ND
18-Nov-09 0.070 0.20 --- ND --- --- ND ND ND 0.43 ND ND ND
NC 2L = 1 µg/L (01/01/10)16-Jun-10 0.070 0.20 --- ND --- --- 0.17 J ND ND 0.077 J ------ ND
1-Dec-10 0.070 0.20 --- 0.089 J ND --- 0.62 ND ND 0.21 ND ND ND
1-Jun-11 0.10 0.20 --- ND ND --- 0.19 J ND ND 0.19 J ND --- ND
20-Dec-11 0.10 0.20 --- --- ND --- 0.14 J ND ND 0.15 J ND ND ND
30-May-12 0.10 0.10 --- --- ND --- 0.13 J ND ND 0.10 J ND ND ND
5-Dec-12 0.10 0.20 --- --- ND --- 0.11 J ND ND 0.27 ND --- ND
12-Jun-13 0.10 0.20 --- --- ND --- ND ND ND 0.56 ND ND ND
28-Oct-13 0.10 0.20 --- --- ND --- 0.15 J ND ND 0.11 J ND ND ND
6-May-14 0.10 0.20 --- --- ND --- 0.15 J ND ND ND ND ND ND
23-Oct-14 0.10 0.20 --- --- * ND ND ND ND 0.38 ND ND ND
20-May-15 0.10 0.20 --- --- --- ND 0.13 J ND ND 0.45 ND ND ND
8-Dec-15 0.10 0.20 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.10 0.20 --- --- --- ND 0.33 ND ND 0.40 ND ND ND
13-Dec-16 0.10 0.20 --- --- --- ND 0.25 ND ND 0.15 J ND ND ND
27-Jun-17 0.10 0.20 --- --- --- ND 0.17 J ND ND ND ND ND ---
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 5 of 10 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Nickel 15-Sep-94 --- 50 ND NI NI NI ND ND 100 ND NI NI ND
1-Oct-94 --- 50 --- NI NI NI --- ND --- --- NI NI ND
18-Jan-95 --- 50 ND NI NI NI ND ND ND ND NI NI ND
6-Feb-95 --- 50 ND NI NI NI ND ND 71.0 ND NI NI ND
1-Mar-95 --- 50 ND NI NI NI ND ND ND ND NI NI ND
1-Aug-95 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-Jan-96 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-Feb-96 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-May-96 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-Oct-96 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-May-97 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-Nov-97 --- 50 ND NI --- --- ND ND 80.0 ND NI NI ND
1-May-98 --- 50 ND NI --- --- ND ND 90.0 ND NI NI ND
1-Nov-98 --- 50 ND NI --- --- ND ND 74.0 ND NI NI ND
11-May-99 --- 5 21.0 33.0 --- --- 16.0 11.0 63.0 14.0 53.0 ND ND
18-Oct-99 --- 50 180 67.0 --- --- 55.0 ND 570 ND ND ND ND
3-May-00 --- 50 ND ND --- --- ND ND ND ND 71.0 ND ND
7-Nov-00 --- 50 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 50 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 50 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 50 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 50 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 50 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 50 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 50 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 50 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 50 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 50 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 50 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 50 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 50 --- 2.2 J --- --- 2.1 J 2.2 J 3.7 J 4.1 J ND ND ND
NC 2L = 100 µg/L (10/23/07)29-Nov-07 --- 50 --- 3.9 J --- --- ND 7.3 J 8.0 J 2.2 J ND ND ND
29-May-08 1.7 50.0 --- 3.6 J --- --- 3.1 J 5.6 J 3.0 J 4.3 J 2.5 J ND ND
6-Nov-08 1.7 50.0 --- 2.2 J --- --- 2.9 J 5.6 J 6.8 J 5.1 J 5.6 J ND ND
3-Jun-09 1.7 50.0 --- 3.1 B --- --- 2.6 B 8.5 B ND 4.1 B 2.8 B 2.2 B 1.7 J
18-Nov-09 1.7 50.0 --- 2.4 J --- --- 3.2 J 5.9 J 4.9 J 4.9 J 1.8 J ND ND
16-Jun-10 1.7 50.0 --- 1.7 J --- --- 4.5 J 13.1 J 8.2 J 3.4 J 1.7 J ND ND
1-Dec-10 1.7 50.0 --- ND 19.0 J --- 3.1 J 4.1 J 7.8 J 3.7 J ND ND ND
1-Jun-11 1.7 50.0 --- ND 4.7 B --- 2.2 B 3.5 B 2.2 B 3.0 B ND ND 2.3 J
20-Dec-11 5.0 50.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.0 50.0 --- --- ND --- ND ND ND ND 5.2 J ND ND
5-Dec-12 5.0 50.0 --- --- ND --- ND ND 6.7 J ND ND ND ND
12-Jun-13 5.0 50.0 --- --- ND --- ND ND 5.2 J 5.4 J ND ND ND
28-Oct-13 5.0 50.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 5.0 50.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.0 50.0 --- --- * ND 6.0 J ND ND ND ND ND ND
20-May-15 2.5 50.0 --- --- --- ND 5.3 J 4.6 J 3.1 J 4.4 J ND ND ND
8-Dec-15 2.5 50.0 --- --- --- ND 5.5 J 3.4 J 17.7 J 4.2 J ND ND ND
3-May-16 2.5 50.0 --- --- --- ND 4.5 J 5.0 J 21.6 J 5.6 J ND ND ND
13-Dec-16 2.5 50.0 --- --- --- ND 3.9 J 3.8 J 29.7 J 3.8 J ND ND ND
27-Jun-17 2.5 50.0 --- --- --- ND 4.7 J 4.1 J 29.0 J 4.5 J ND ND ---
Selenium 29-May-08 3.8 10.0 --- ND --- --- ND 6.1 J ND ND 5.8 J ND ND
6-Nov-08 3.8 10.0 --- ND --- --- 13.2 6.4 J 6.7 J ND 5.8 J ND ND
3-Jun-09 3.8 10.0 --- ND --- --- ND 5.4 J ND ND ND ND ND
18-Nov-09 3.8 10.0 --- ND --- --- ND 4.3 J 4.7 J 4.4 J 5.0 J ND ND
NC 2L = 20 µg/L (01/01/10) 16-Jun-10 3.8 10.0 --- ND --- --- 3.8 J ND 6.9 J ND ND ND ND
1-Dec-10 3.8 10.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 3.8 10.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 10.0 10.0 --- --- ND --- 11.7 11.3 ND ND ND ND ND
5-Dec-12 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 10.0 10.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 5.0 10.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 5.0 10.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 5.0 10.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 5.0 10.0 --- --- --- ND ND ND ND ND ND ND ND
27-Jun-17 5.0 10.0 --- --- --- ND ND ND ND ND ND ND ---
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 6 of 10 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Silver 6-Feb-95 --- 10 ND NI NI NI 11.0 ND 11.0 ND NI NI ND
1-Mar-95 --- 10 ND NI NI NI ND ND ND ND NI NI ND
1-Aug-95 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-Jan-96 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-Feb-96 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-May-96 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-Oct-96 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-May-97 --- 5 ND NI --- --- 6.0 ND ND ND NI NI ND
1-Nov-97 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-May-98 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-Nov-98 --- 1 ND NI --- --- ND ND ND ND NI NI ND
11-May-99 --- 2 ND ND --- --- ND ND ND ND ND ND ND
18-Oct-99 --- 10 ND ND --- --- ND ND ND ND ND ND ND
3-May-00 --- 10 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 10 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 10 15.0 B 15.0 B --- --- 14.0 B 15.0 B 14.0 B 12.0 B 16.0 B 16.0 B 15.0
14-Nov-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 10 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 10 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 10 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 17.5 µg/L (10/23/07)29-Nov-07 --- 10 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.10 10.0 --- 0.14 J --- --- 0.59 J 1.1 J 0.45 J ND 0.57 J ND ND
6-Nov-08 0.10 10.0 --- 0.25 B --- --- 1.1 B 2.1 J 1.3 J 0.26 B 1.1 B 0.22 B 0.23 J
3-Jun-09 0.10 10.0 --- 0.68 B --- --- 1.0 B 1.4 B 0.73 B 0.13 B 0.76 B 1.0 B 0.31 J
18-Nov-09 0.10 10.0 --- 0.28 B --- --- 0.72 B 1.0 B 0.61 B 0.19 B 0.57 B 0.19 B 0.23 J
NC 2L = 20 µg/L (01/01/10)16-Jun-10 0.10 10.0 --- ND --- --- ND ND ND ND ND ND ND
1-Dec-10 0.10 10.0 --- ND ND --- ND 0.24 J ND ND ND ND ND
1-Jun-11 0.10 10.0 --- 0.39 B 0.16 B --- 0.22 B 0.60 B 0.32 B 0.29 B 0.22 B 0.23 B 0.17 J
20-Dec-11 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 2.5 10.0 --- --- --- ND ND 3.6 J ND ND ND ND ND
8-Dec-15 2.5 10.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 2.5 10.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 2.5 10.0 --- --- --- ND ND ND ND ND ND ND ND
27-Jun-17 2.5 10.0 --- --- --- ND ND ND ND ND ND ND ---
Sulfide 1-Aug-95 --- 100 900 NI --- --- ND 600 ND 100 NI NI ND
1-Jan-96 --- 100 ND NI --- --- ND 300 ND ND NI NI ND
1-Feb-96 --- 100 ND NI --- --- ND 100 ND ND NI NI ND
1-May-96 --- 100 200 NI --- --- ND 900 700 300 NI NI ND
1-Oct-96 --- 100 2800 NI --- --- ND 200 3000 7500 NI NI ND
1-May-97 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-Nov-97 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-May-98 --- 50 50 NI --- --- ND ND ND ND NI NI ND
1-Nov-98 --- 50 ND NI --- --- 130 ND 80.0 110 NI NI ND
11-May-99 --- 50 ND ND --- --- ND ND ND ND --- ND ND
18-Oct-99 --- 1000 ND ND --- --- --- ND ND ND ND ND ND
7-Nov-00 --- 1000 ND --- --- --- ND ND ND ND ND --- ND
31-May-01 --- 1000 ND --- --- --- ND ND ND ND ND --- ND
7-Nov-01 --- 1000 ND --- --- --- ND ND ND ND ND --- ND
14-Nov-02 --- 1000 ND --- --- --- ND ND ND ND ND --- ND
20-Nov-03 --- 1000 ND --- --- --- ND ND ND ND ND --- ND
10-Nov-04 --- 1000 ND --- --- --- ND ND ND ND ND ---6
3-Nov-05 --- --- --- ND --- --- ND ND 1800 ND ND --- ND
2-Nov-06 --- 1000 --- ND --- --- ND ND ND ND ND --- ND
NC 2L = NE (10/23/07)29-Nov-07 --- 1000 --- ND --- --- ND ND ND ND ND --- ND
6-Nov-08 100 1000 --- ND --- --- ND ND ND ND ND --- ND
3-Jun-09 100 1000 --- ND --- --- --- ND ND --- ND --- ND
18-Nov-09 100 1000 --- ND --- --- ND ND ND ND ND --- ND
16-Jun-10 100 1000 --- ND --- --- --- ND ND --- ND --- ND
1-Dec-10 100 1000 --- ND ND --- ND ND ND ND ND --- ND
5-Dec-12 100 1000 --- --- ND --- ND ND ND ND ND --- ND
12-Jun-13 100 1000 --- --- ND --- ND ND ND ND ND --- ND
28-Oct-13 100 1000 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 100 1000 --- --- * ND --- --- --- --- ------ ND
8-Dec-15 100 1000 --- --- --- ND ND ND ND ND ND --- ND
3-May-16 100 1000 --- --- --- ND --- --- --- --- ------ ND
13-Dec-16 100 1000 --- --- --- ND ND ND ND ND ND --- ND
27-Jun-17 100 1000 --- --- --- ND --- --- --- --- ------ ---
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 7 of 10 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Thallium 1-Nov-97 --- 1 2.0 B NI --- --- 2.0 B 2.0 B 3.0 B 1.0 B NI NI 2.0
1-May-98 --- 1 ND NI --- --- ND ND ND 1.0 NI NI ND
1-Nov-98 --- 1 ND NI --- --- ND ND ND 1.0 NI NI ND
11-May-99 --- 2 2.0 3.0 --- --- 4.0 3.0 4.0 ND 3 2.0 ND
18-Oct-99 --- 10 ND ND --- --- ND ND ND ND ND ND ND
3-May-00 --- 10 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 10 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 10 16.0 ND --- --- 41.0 23.0 25.0 14.0 26.0 ND ND
3-Nov-05 --- 10 --- ND --- --- 19.0 17.0 15.0 ND 13.0 ND ND
25-May-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 5.5 --- ND --- --- 0.169 J 0.29 J 0.221 J 0.131 J 0.078 J ND ND
GWPS = 0.28 µg/L (10/23/07)29-Nov-07 --- 5.5 --- 0.042 J --- --- 0.118 J 0.321 J 0.199 J 0.150 J 0.065 J ND ND
29-May-08 3.0 5.5 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 3.0 5.5 --- ND --- ---8.9 ND ND ND ND ND ND
3-Jun-09 3.0 5.5 --- ND --- --- ND ND ND ND ND 14.8 ND
18-Nov-09 3.0 5.5 --- ND --- --- ND ND ND ND ND ND 4.2 J
16-Jun-10 3.0 5.5 --- ND --- --- 5.3 J 7.7 4.1 J ND 4.0 J ND ND
Resample> 5-Aug-10 3.0 5.5 --- --- --- --- ---20.4 --- --- ------ 3.2 J
GWPS = 0.2 µg/L (10/1/1)1-Dec-10 3.0 5.5 --- 3.3 B ND --- 3.3 B 9.1 B 5.1 B ND 7.8 B ND 3.1 J
1-Jun-11 3.0 5.5 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 5.4 5.5 --- --- ND --- ND ND ND ND ND ND 6.8
12-Jun-13 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.4 5.5 --- --- * ND ND ND ND ND ND ND ND
20-May-15 5.0 5.5 --- --- --- ND ND 6.4 ND ND ND ND ND
8-Dec-15 5.0 5.5 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 5.0 5.5 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 5.0 5.5 --- --- --- ND 5.3 J 5.1 J ND ND ND ND ND
27-Jun-17 0.0 5.5 --- --- --- ND 0.24 J 0.36 J 0.094 J 0.097 J ND ND ---
Tin 6-Nov-08 1.8 100 --- ND --- --- 2.3 J 3.8 J 2.1 J ND 2.9 J --- ND
GWPS = 0.28 µg/L (10/23/07) 3-Jun-09 --- --- --- --- --- --- --- --- --- --- --- --- ---
18-Nov-09 1.8 100 --- ND --- --- ND ND ND ND ND ND ND
GWPS =2,100 µg/L (01/01/10) 16-Jun-10 1.8 100 --- ND --- --- ND ND ND ND --- --- ND
GWPS =2,000 µg/L (10/1/10) 1-Dec-10 1.8 100 --- ND ND --- ND ND ND ND ND --- ND
1-Jun-11 1.8 100 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 5.0 100 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.0 100 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 5.0 100 --- --- ND --- ND ND ND ND ND --- ND
12-Jun-13 5.0 100 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 5.0 100 --- --- ND --- ND 5.1 J ND ND ND --- ND
6-May-14 5.0 100 --- --- ND --- ND ND ND ND ND --- ND
23-Oct-14 5.0 100 --- --- * ND ND ND ND ND ND --- ND
20-May-15 2.5 100 --- --- --- ND ND ND ND ND ND --- ND
8-Dec-15 2.5 100 --- --- --- ND ND ND ND ND ND --- ND
3-May-16 2.5 100 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16 2.5 100 --- --- --- ND ND ND ND ND ND --- ND
27-Jun-17 2.5 5 --- --- --- ND ND ND ND ND ND --- ---
Vanadium 1-May-97 --- 5 12.0 NI --- --- 5.0 ND 66.0 9.0 NI NI ND
1-Nov-97 --- 40 ND NI --- --- ND ND 180 ND NI NI ND
1-May-98 --- 5 14.0 NI --- --- 6.0 7.0 159 22.0 NI NI ND
1-Nov-98 --- 5 15.0 NI --- --- 12.0 8.0 110 14.0 NI NI ND
11-May-99 --- 5 55.0 58.0 --- --- 25.0 16.0 72.0 31.0 71.0 100 ND
18-Oct-99 --- 40 630 150 --- --- 150 79.0 690 62.0 ND ND ND
3-May-00 --- 40 ND ND --- --- ND ND ND ND 140 ND ND
7-Nov-00 --- 40 ND 66.0 --- --- ND ND ND ND ND ND ND
31-May-01 --- 40 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 40 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 40 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 40 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 40 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 40 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 40 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 40 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 40 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 40 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 40 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 40 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 25 --- ND --- --- ND ND ND ND ND ND 1.3 J
GWPS = 3.5 µg/L (10/23/07)29-Nov-07 --- 25 --- 7.3 J --- --- ND ND ND ND ND ND ND
29-May-08 0.2 25.0 --- 0.43 J --- --- ND 2.4 J 1.3 J 3.7 J ND ND ND
6-Nov-08 0.2 25.0 --- 3.0 B --- --- 2.2 B 0.53 B 5.5 B 11.1 J 6.2 B 1.4 B 2.1 J
3-Jun-09 0.2 25.0 --- 0.94 B --- --- 0.47 B 0.91 B 0.66 B 5.2 J 1.8 B 2.7 B 1.0 J
18-Nov-09 0.20 25.0 --- 0.82 B --- --- 0.43 B 0.66 B 4.1 J 5.4 J 1.3 B 0.29 B 0.56 J
16-Jun-10 0.20 25.0 --- 1.1 B --- --- 4.5 B 28.5 8.3 J 2.0 B 1.3 B 0.66 B 0.98 J
Resample> 5-Aug-10 0.20 25.0 --- --- --- --- --- 1.5 B --- --- ------ 0.62 J
GWPS = 0.3 µg/L (10/1/10)1-Dec-10 0.20 25.0 --- 0.48 J 55.2 --- 3.2 J 0.63 J 5.7 J 0.33 J 2.9 J 2.4 J ND
Resample> 13-Jan-11 0.20 25.0 --- --- 0.55 B --- --- --- --- --- ------ 0.33 J
1-Jun-11 0.20 25.0 --- 0.69 J 17.2 J --- 0.34 J 1.5 J 0.32 J 0.37 J ND 5.5 J ND
20-Dec-11 5.0 25.0 --- --- 10.7 J --- ND ND ND ND ND ND ND
30-May-12 5.0 25.0 --- --- 9.2 J --- ND ND ND ND 7.9 J ND ND
5-Dec-12 5.0 25.0 --- --- ND --- ND ND 6.1 J ND ND ND ND
12-Jun-13 5.0 25.0 --- --- ND --- ND ND ND 5.6 J ND ND ND
28-Oct-13 5.0 25.0 --- --- ND --- ND 8.3 J ND ND ND ND ND
6-May-14 5.0 25.0 --- --- 6.7 J --- ND ND ND ND ND ND ND
22-Oct-14 5.0 25.0 --- --- * 9.6 J ND ND ND ND ND ND ND
20-May-15 2.5 25.0 --- --- --- ND 9.1 J 20.1 J 10.7 J 2.6 J 11.3 J ND ND
8-Dec-15 2.5 25.0 --- --- --- 6.6 J 20.4 J 23.5 J 36.9 3.0 J 11.5 J ND ND
Lab Re-run analyses> 8-Dec-15 2.5 25.0 --- --- --- --- --- --- 19.8 J --- ------ ---
3-May-16 2.5 25.0 --- --- ---29.7 ND ND ND 5.7 J ND ND ND
13-Dec-16 2.5 25.0 --- --- --- 6.8 J ND ND ND ND ND ND ND
27-Jun-17 2.5 25.0 --- --- --- 9.4 J 10.6 J 20.6 J 15.8 J ND 12.5 J ND ---
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 8 of 10 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Zinc 15-Sep-94 --- 10 36.0 NI NI NI ND 27.0 ND ND NI NI ND
1-Oct-94 --- 10 --- NI NI NI --- 52.0 --- --- NI NI ND
18-Jan-95 --- 10 21.0 NI NI NI ND 27.0 21.0 ND NI NI ND
6-Feb-95 --- 10 21.0 NI NI NI ND 18.0 37.0 14.0 NI NI ND
1-Mar-95 --- 10 27.0 NI NI NI 14.0 24.0 29.0 29.0 NI NI ND
1-Aug-95 --- 10 ND NI --- --- ND 29.0 23.0 27.0 NI NI ND
1-Jan-96 --- 10 28.0 NI --- --- 22.0 37.0 49.0 21.0 NI NI ND
1-Feb-96 --- 10 48.0 NI --- --- 27.0 24.0 31.0 26.0 NI NI ND
1-May-96 --- 10 46.0 NI --- --- 46.0 48.0 56.0 55.0 NI NI ND
1-Oct-96 --- 10 23.0 NI --- --- 16.0 30.0 20.0 16.0 NI NI ND
1-May-97 --- 10 50.0 NI --- --- 50.0 50.0 80.0 50.0 NI NI ND
1-Nov-97 --- 10 60.0 NI --- --- 20.0 30.0 80.0 ND NI NI ND
1-May-98 --- 10 40.0 NI --- --- 30.0 40.0 110 30.0 NI NI ND
1-Nov-98 --- 10 29.0 NI --- --- 24.0 23.0 150 ND NI NI ND
11-May-99 --- 20 64.0 43.0 --- --- 150 28.0 68.0 61.0 69.0 210 ND
18-Oct-99 --- 50 570 89.0 --- --- 160 140 700 75.0 J ND 99.0 ND
3-May-00 --- 50 ND ND --- --- ND ND ND 62.0 J 160 63.0 J ND
7-Nov-00 --- 50 130 150 --- --- ND 110 60.0 70.0 ND ND ND
31-May-01 --- 50 ND ND --- --- ND ND 79.0 ND ND ND ND
7-Nov-01 --- 50 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 50 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 50 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 50 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 50 ND 100 --- --- 50.0 ND ND ND ND ND ND
6-May-04 --- 50 ND ND --- --- 78.0 ND ND ND ND ND ND
10-Nov-04 --- 50 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 50 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 50 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 50 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 50 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 10 --- 5.9 B --- --- 7.6 B 11.4 19.3 14.0 46.5 1.3 1.6 J
NC 2L = 1,050 µg/L (10/23/07) 29-Nov-07 --- 10 --- 20.4 --- --- 10.9 B 62.0 30.2 16.4 44.5 35.6 3.1 J
29-May-08 0.40 10.0 --- 2.9 B --- --- 20.4 44.3 27.9 25.7 35.2 25.0 3.0 J
6-Nov-08 0.40 10.0 --- 12.1 B --- --- 10.2 B 16.6 18.6 27.1 76.7 30.9 2.7 J
3-Jun-09 0.40 10.0 --- 3.9 B --- --- 4.6 B 40.5 B 7.0 B 20.0 B 19.2 B 6.6 B 82.0
18-Nov-09 0.40 10.0 --- 4.2 B --- --- 7.2 B 21.4 18.6 22.1 13.6 B 2.5 B 3.1 J
NC 2L = 1,000 µg/L (01/01/10) 16-Jun-10 0.40 10.0 --- ND --- --- 6.0 J 56.2 20.5 10.1 24.0 ND ND
1-Dec-10 0.40 10.0 --- 6.5 J 76.5 --- 14.1 33.4 25.6 16.2 119 5.4 J 0.62 J
1-Jun-11 0.40 10.0 --- 8.3 B 31.6 B --- 14.3 B 40.8 B 27.2 B 20.1 B 24.9 B 44.7 B 13.7
20-Dec-11 10.0 10.0 --- --- 19.6 --- 13.3 40.8 20.2 17.6 30.5 15.8 ND
30-May-12 10.0 10.0 --- --- 11.5 --- ND 39.2 16.6 13.3 48.8 ND ND
5-Dec-12 10.0 10.0 --- --- ND --- 12.1 17.8 24.4 17.8 ND 11.2 ND
12-Jun-13 10.0 10.0 --- --- 31.4 --- ND 38.9 B ND 23.7 B ND 32.2 B 76.5
28-Oct-13 10.0 10.0 --- --- 15.9 --- ND 68.9 14.3 22.0 18.2 ND ND
6-May-14 10.0 10.0 --- --- 13.7 --- ND 23.4 12.2 17.2 11.7 ND ND
23-Oct-14 10.0 10.0 --- --- * ND ND 17.8 11.2 18.5 32.2 13.9 ND
20-May-15 5.0 10.0 --- --- --- 26.4 9.6 J 24.2 15.6 19.8 20.4 ND ND
8-Dec-15 5.0 10.0 --- --- --- ND 9.0 J 20.0 65.1 19.0 47.3 8.2 J ND
3-May-16 5.0 10.0 --- --- --- 10.5 B 7.5 B 35.3 B 8.4 B 23.2 B 20.7 B 9.3 B 7.4 J
13-Dec-16 5.0 10.0 --- --- --- ND 12.8 17.6 9.7 J 15.7 51 6.8 J ND
27-Jun-17 5.0 10.0 --- --- --- 8.2 J 10.0 J 19.6 11.7 21.9 35.8 9.8 J ---
Alkalinity, Total as CaCO3 1-Jun-11 5,000 5,000 --- 45,100 --- --- --- 177,000 70,700 --- 109,000 --- ND
NC 2L = NE (01/01/10) 20-Dec-11 5,000 5,000 --- --- 8,580 --- 53,600 189,000 70,800 ND 77,200 47,200 ND
30-May-12 1,000 1,000 --- --- 8,140 --- 64,700 200,000 76,700 8,360 104,000 44,400 ND
5-Dec-12 1,000 5,000 --- --- 7,690 --- 22,600 178,000 76,600 ND 106,000 46,500 ND
12-Jun-13 1,000 5,000 --- --- 7,950 --- 138,000 202,000 111,000 7,020 99,700 51,700 ND
28-Oct-13 1,000 5,000 --- --- 8,140 --- 69,900 197,000 91,300 9,520 116,000 45,000 ND
6-May-14 1,000 5,000 --- --- 8,060 --- 85,900 208,000 90,600 5,520 119,000 45,700 ND
23-Oct-14 1,000 5,000 --- --- * 1,360 J 88,100 215,000 96,100 7,500 122,000 52,000 ---
20-May-15 1,000 5,000 --- --- --- ND 67,300 153,000 67,500 8,780 92,100 41,600 ---
8-Dec-15 1,000 NE --- --- --- 1,030 J 98,400 202,000 88,800 9,130 95,900 46,200 ---
3-May-16 1,000 NE --- --- --- 1,250 J 57,400 146,000 56,800 9,300 79,200 49,600 ND
13-Dec-16 1,000 5,000 --- --- --- 1,190 J 35,700 97,700 54,100 9,380 72,100 49,400 ---
27-Jun-17 1,000 5,000 --- --- --- ND 102,000 165,000 98,700 11,300 99,100 51,200 ---
Chloride 1-Jun-11 5,000 5,000 --- ND --- --- --- 17,000 6,330 --- 7,870 --- ND
NC 2L = 250,000 µg/L (01/01/10) 20-Dec-11 5,000 5,000 --- --- ND --- 6,320 20,200 6,400 ND 6,530 ND ND
30-May-12 1,000 1,000 --- --- 1,480 --- 6,190 20,000 ND 2,100 5,840 ND ND
5-Dec-12 1,000 1,000 --- --- 2,130 --- 5,970 19,500 7,290 2,060 7,430 1,130 ND
12-Jun-13 1,000 1,000 --- --- 1,380 --- 13,300 19,500 7,500 2,260 5,100 ND ND
28-Oct-13 1,000 1,000 --- --- 1,120 --- 11,400 18,100 7,750 2,210 8,490 ND ND
6-May-14 1,000 1,000 --- --- ND --- 17,300 18,200 8,140 1,890 8,920 ND ND
23-Oct-14 500 1,000 --- --- * ND 19,200 20,800 9,050 1,570 8,120 642 J ND
20-May-15 500 1,000 --- --- --- --- 14,000 25,300 9,680 1,720 10,400 572 J ---
8-Dec-15 500 NE --- --- --- 859 J 26,500 30,800 9,400 1,910 4,190 945 J ---
3-May-16 500 NE --- --- --- 558 J 13,500 33,200 11,300 3,170 7,810 1,120 ---
13-Dec-16 500 1,000 --- --- --- 1,470 9,040 35,000 7,650 1,810 9,280 965 J ---
27-Jun-17 500 1,000 --- --- --- ND 11,500 29,700 10,400 1,550 7,000 ND ---
Sulfate 1-Jun-11 5,000 5,000 --- ND --- --- --- ND ND --- ND --- ND
NC 2L = 250,000 µg/L (01/01/10) 20-Dec-11 5,000 5,000 --- --- ND --- 5,150 ND ND ND ND 8,630 ND
30-May-12 2,000 250,000 --- --- ND --- 5,380 J ND ND ND ND 8,860 J ND
5-Dec-12 2,000 250,000 --- --- ND --- 2,880 J 2,920 J 4,400 J ND 2,320 J 8,910 J ND
12-Jun-13 2,000 250,000 --- --- ND --- 11,200 J 3,080 J 2,910 J 6,940 J ND 9,310 J ND
28-Oct-13 2,000 250,000 --- --- ND --- 4,420 J ND 2,940 J ND ND 8,150 J ND
6-May-14 2,000 250,000 --- --- ND --- 10,500 J 2,300 J 3,720 J ND 2,070 J 8,780 J ND
23-Oct-14 1,000 250,000 --- --- * ND 7,270 J 2,280 J 3,740 J 1,240 J 1,940 J 9,710 J ND
20-May-15 1,000 250,000 --- --- --- ND 5,620 J 2,310 J 3,440 J ND 2,150 J 8,780 J ---
8-Dec-15 1,000 250,000 --- --- --- ND 10,200 J 1,530 J 2,020 J ND ND 9,260 J ---
3-May-16 2,000 250,000 --- --- --- ND 5,300 J 5,490 J 3,440 J ND ND 8,720 J ---
13-Dec-16 1,000 250,000 --- --- --- 1,340 J 3,220 J 3,500 J 4,050 J 1,340 J 1,930 J 9,850 J ---
27-Jun-17 500 250,000 --- --- --- ND 5,290 J 2,120 J 3,200 J ND ND 9,920 J ---
Total Dissolved Solids, Dissolved 1-Jun-11 25,000 25,000 --- 62,000 --- --- --- 200,000 93,000 --- 127,000 --- ND
NC 2L = 500,000 µg/L (01/01/10) 20-Dec-11 25,000 25,000 --- --- ND --- 59,000 196,000 82,000 ND 103,000 78,000 ND
30-May-12 25,000 25,000 --- --- 37,000 --- 85,000 12,500 J 109,000 ND 136,000 90,000 ND
5-Dec-12 25,000 25,000 --- --- 35,000 --- 50,000 219,000 109,000 28,000 134,000 97,000 ND
12-Jun-13 25,000 25,000 --- --- 34,000 --- 177,000 225,000 136,000 ND 111,000 107,000 ND
28-Oct-13 25,000 25,000 --- --- 49,000 --- 109,000 227,000 134,000 ND 138,000 112,000 ND
6-May-14 25,000 25,000 --- --- 34,000 --- 136,000 234,000 115,000 32,000 126,000 102,000 ND
23-Oct-14 25,000 25,000 --- --- * ND 126,000 238,000 119,000 ND 129,000 98,000 ND
20-May-15 25,000 25,000 --- --- --- ND 112,000 252,000 122,000 30,000 135,000 88,000 ---
8-Dec-15 25,000 NE --- --- --- ND 182,000 280,000 117,000 ND 106,000 93,000 ---
3-May-16 25,000 NE --- --- --- ND 110,000 245,000 129,000 ND 89,000 89,000 ---
13-Dec-16 25,000 25,000 --- --- --- ND 73,000 241,000 133,000 ND 131,000 90,000 ---
27-Jun-17 25,000 25,000 --- --- --- ND 151,000 237,000 153,000 ND 105,000 --- ---
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 9 of 10 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Notes:
(Abbreviations and Referrences)
All concentrations in micrograms per liter (µg/L) = parts per billion.
--- = Not sampled for this parameter or not reported.
AB = Monitoring well abandoned.
B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination based on similar concentrations detected in field, trip, or method blanks).
D = Sample was diluted when analyzed.
DL = Laboratory Detection Limit.
GWPS = Groundwater Protection Standard set by NC-DENR-SWS for constituents with no listed NC 2L standard.
When the NC 2L Groundwater Standard has not been established, the GWPS will be used.
J = Estimated value - concentration is less than the RL but greater than the DL.
NC 2L = Groundwater Standard from 15A NCAC 2L.
ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006).
NE = No NC 2L or GWPS established.
NI = Not Installed; monitoring was not yet installed.
RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present).
Values above the NC2L Standard or GWPS are bold.
Notes: (Event Narratives)
Volatile organics (8260) for MW-9 for November 10, 2004 sampling event were unable to be analyzed and were resampled on December 1, 2004.
There was a resamplinging event on August 2, 2007 for MW-16D because the prevoius samples from the May 2007 were analyzed out of hold time. There were no detects in the resample.
* MW-21 replaced MW-20 as the background well starting with the Fall 2014 sampling event; however MW-20 continues to be sampled as a compliance well for the C&D Expansion (Phase 1A).
See the Water Quality Monitrong Report for the C&D Expansion Area for current results for MW-20.
The dates on the table above reflect the last samples were collected during the semiannual monitoring event. Individual collection dates are preserved in the Lab Reports (Appendix B).
Pace Analytical Re-ran the analysis for Antimony, Chromium, and Vanadium in MW-12 on January 19, 2016 from the samples collected in December 2016, and the results are included in the table.
A Verification Sampling Event was performed for beta-BHC in MW-11 and Antimony and Chromium in MW-12 on February 4, 2016, for the December 2015 event and results are included.
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 10 of 10 Joyce Engineering

Appendix E

Historical Detected Organic Groundwater Constituents

APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Organic Compounds
Acetone 30-May-07 --- 100.0 --- 2.7 B --- --- ND ND ND ND ND ND 2.1 J
NC 2L = 700 µg/L (10/23/07) 29-Nov-07 --- 100.0 --- 8.1 B --- --- 3 B ND 2.8 B 8.1 B 13 B 2.6 B 5.1 J
29-May-08 20.0 100.0 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 20.0 100.0 --- 26.8 J --- --- ND ND ND ND ND ND ND
3-Jun-09 2.2 100.0 --- 48.3 J --- --- 6.5 J ND ND ND 18.5 J ND ND
18-Nov-09 2.2 100.0 --- ND ND --- ND ND ND ND ND ND ND
NC 2L = 6,000 µg/L (01/01/10) 16-Jun-10 2.2 100.0 --- 5.3 B --- --- ND 3.1 B ND ND ND ND 7.2 J
1-Dec-10 2.2 100.0 --- ND ND --- 8.4 B ND ND ND 56.6 J ND 3.7 J
1-Jun-11 2.2 100.0 --- 3.5 B ND --- 3.4 B 8.1 B 7.7 B ND 80 J ND 3.9 J
20-Dec-11 2.2 100.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 2.2 100.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 10.0 100.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 10.0 100.0 --- --- ND --- 33 J ND ND ND 20.5 J ND ND
28-Oct-13 10.0 100.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 10.0 100.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 10.0 100.0 --- --- * ND ND ND 10.4 J ND ND ND ND
21-May-15 10.0 100.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 10.0 100.0 --- --- --- ND ND ND ND ND 16.5 J ND ND
3-May-16 10.0 100.0 --- --- --- ND ND ND ND 41.5 J ND ND ND
13-Dec-16 10.0 100.0 --- --- --- ND ND ND ND ND ND ND ND
27-Jun-17 10.0 100.0 --- --- --- 35.8 J 10.4 J 32.4 J 22.8 J 15.9 J 33 J 13.4 J ---
Acrolein 8-Dec-15 1.6 53.0 --- --- --- 1.6 B ND ND ND ND ND ---2.8 J
# NC 2L = 6,000 µg/L (01/01/10) 13-Dec-16 1.6 53.0 --- --- --- ND ND ND ND ND ND ---ND
Benzene 1-Oct-96 --- 5.0 --- NI --- --- ND 6 ND ND NI NI ---
1-May-97 --- 5.0 ND NI --- --- ND 6.8 2.7 J ND NI NI ---
1-Nov-97 --- 1.0 ND NI --- --- ND 9 ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- --- ND 10 9.4 ND NI NI ---
24-Nov-98 --- 2.0 ND NI --- --- ND 11.6 ND ND NI NI ---
10-May-99 --- 5.0 ND ND --- --- ND 13 ND ND 5.3 ND ND
18-Oct-99 --- 5.0 ND ND --- --- ND 12 ND ND 5.4 ND ND
3-May-00 --- 5.0 ND ND --- --- ND 10 ND ND 6.3 ND ND
7-Nov-00 --- 5.0 ND ND --- --- ND 9.2 ND ND ND ND ND
31-May-01 --- 5.0 ND ND --- --- ND 7.7 ND ND 5.8 ND ND
7-Nov-01 --- 5.0 ND ND --- --- ND 8.1 5.2 ND 6.7 ND ND
22-May-02 --- 5.0 ND ND --- --- ND 8.2 8.1 ND 8.0 ND ND
14-Nov-02 --- 5.0 ND ND --- --- ND 5.1 7.7 ND 9.4 ND ND
14-May-03 --- 5.0 ND ND --- --- ND 8 5.4 7 13 ND ND
20-Nov-03 --- 5.0 ND ND --- --- ND 7.3 5.7 7.5 9.2 ND ND
6-May-04 --- 5.0 ND ND --- --- ND 7.3 7.2 9.3 9.6 ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND 7.5 6 8.5 10 ND ND
27-May-05 --- 5.0 ND ND --- --- ND 8 9 11 9 ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND ND 58 6ND ND
25-May-06 --- 5.0 --- ND --- --- ND ND 6.1 8.5 5.3 ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND 5.3 5.3 11 7.6 ND ND
30-May-07 --- 1.0 --- 0.22 J --- --- 0.87 J 7.3 7.4 13 6.6 ND ND
NC 2L = 1 µg/L (10/23/07)29-Nov-07 --- 1.0 --- 0.6 J --- --- 0.79 J 3.6 2.8 12 3.3 ND ND
29-May-08 0.25 1.0 --- 0.49 J --- --- 0.88 J 4.6 4.6 13.5 4.1 ND ND
6-Nov-08 0.25 1.0 --- 0.53 J --- --- 0.81 J 4.3 4.4 12 3.1 ND ND
3-Jun-09 0.25 1.0 --- 0.67 J --- ---1.2 4.5 5.4 15.3 4.1 ND ND
18-Nov-09 0.25 1.0 --- 1.3 --- --- 0.81 J 4 5.6 14.9 3.3 ND ND
16-Jun-10 0.25 1.0 --- 0.59 J --- --- 0.81 J 5.9 5 14.3 2.4 ND ND
1-Dec-10 0.25 1.0 --- ND ND --- 0.96 J 5 3 11.5 4 ND ND
1-Jun-11 0.25 1.0 --- 0.99 J ND --- 1 5.4 3.9 16.1 1.2 ND ND
20-Dec-11 0.25 1.0 --- --- ND --- 1 J 4.2 3.1 12.9 D 2 ND ND
30-May-12 0.25 1.0 --- --- ND --- ND 4.4 2.8 14.7 2 ND ND
5-Dec-12 0.25 1.0 --- --- ND --- 0.83 J 4.1 2.8 14.9 1.6 ND ND
12-Jun-13 0.25 1.0 --- --- ND ---1.5 3.5 4.2 15.9 2.9 ND ND
28-Oct-13 0.25 1.0 --- --- ND --- 1 4.1 4.1 15.6 2 ND ND
6-May-14 0.25 1.0 --- --- ND ---1.6 3.9 3.8 17.2 2.1 ND ND
22-Oct-14 0.25 1.0 --- --- * ND 1.8 2.8 3.0 14.9 1.8 ND ND
21-May-15 0.25 1.0 --- --- ND ND 1.3 2.8 2.8 12.3 1.2 ND ND
8-Dec-15 0.25 1.0 --- --- * ND 1.6 2.2 2.3 13.8 1.7 ND ND
3-May-16 0.25 1.0 --- --- --- ND 1.8 2.8 2.9 14.1 1.5 ND ND
13-Dec-16 0.25 1.0 --- --- --- ND 1.7 2.3 2.8 14.5 1.4 ND ND
27-Jun-17 0.25 1.0 --- --- --- ND 1.6 2.1 2.6 14.8 1.2 ND ---
Bromodichloromethane 30-May-07 --- 1.0 --- ND --- --- 0.54 J ND 0.63 J ND ND ND ND
NC 2L = 0.56 µg/L (10/23/07)29-Nov-07 --- 1.0 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.18 1.0 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 0.18 1.0 --- ND --- --- ND ND ND ND ND ND ND
3-Jun-09 0.18 1.0 --- ND --- --- ND ND ND ND ND ND ND
18-Nov-09 0.18 1.0 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 0.6 µg/L (01/01/10)16-Jun-10 0.18 1.0 --- ND --- --- ND ND ND ND ND ND ND
1-Dec-10 0.18 1.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 0.18 1.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 0.18 1.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 0.18 1.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.18 1.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 0.18 1.0 --- --- ND --- ND ND ND ND ND ND 18.60
28-Oct-13 0.18 1.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 0.18 1.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 0.18 1.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.18 1.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.18 1.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.18 1.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.18 1.0 --- --- --- ND ND ND ND ND ND ND ND
27-Jun-17 0.18 1.0 --- --- --- ND ND ND ND ND ND ND ---
Bromomethane 12-Jun-13 0.29 10.0 --- --- ND --- 1.4 J ND ND ND ND ND ND
NC 2L = NE (10/23/07)28-Oct-13 0.29 10.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 0.29 10.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 0.29 10.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.29 10.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.29 10.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.29 10.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.29 10.0 --- --- --- ND ND ND ND ND ND ND ND
27-Jun-17 0.29 10.0 --- --- --- ND ND ND ND ND ND ND ---
2-Butanone (MEK)20-Dec-11 0.96 100.0 --- --- ND --- ND ND ND 5.6
J
D ND ND ND
NC 2L = 4000 µg/L (10/23/07)30-May-12 0.96 100.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.96 100.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 0.96 100.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 0.96 100.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 0.96 100.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 0.96 100.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.96 100.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.96 100.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.96 100.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.96 100.0 --- --- --- ND ND ND ND ND ND ND ND
27-Jun-17 0.96 100.0 --- --- --- ND ND ND ND ND ND ND ---
Burke County Johns River C D over MSWLF
Permit 12-03 Page 1 of 12 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Carbon Disulfide 1-Nov-97 --- 1.0 8 NI --- --- ND ND ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---
24-Nov-98 --- 2.0 6.2 NI --- --- ND ND 8.9 ND NI NI ---
10-May-99 --- 5.0 ND ND --- --- ND ND 6.7 9 ND 100 ND
18-Oct-99 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
3-May-00 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
27-May-05 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 100.0 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 100.0 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 100.0 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 100.0 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 700 µg/L (10/23/07)29-Nov-07 --- 100.0 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 1.2 100.0 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 1.2 100.0 --- ND --- --- ND ND ND ND ND ND ND
3-Jun-09 1.2 100.0 --- ND --- --- ND ND ND ND ND ND ND
18-Nov-09 1.2 100.0 --- ND --- --- ND ND ND ND ND ND ND
16-Jun-10 1.2 100.0 --- ND --- --- ND ND ND ND ND ND ND
1-Dec-10 1.2 100.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 1.2 100.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 1.2 100.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 1.2 100.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 1.2 100.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 1.2 100.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 1.2 100.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 1.2 100.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 1.2 100.0 --- --- * ND ND ND ND ND ND ND 1.4 J
21-May-15 1.2 100.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 1.2 100.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 1.2 100.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 1.2 100.0 --- --- --- ND ND ND ND ND ND ND ND
27-Jun-17 1.2 100.0 --- --- --- ND ND ND ND ND ND ND ---
Chlorobenzene 30-May-07 --- 3.0 --- ND --- --- ND 0.63 J 1.1 J 0.3 J 0.61 J ND ND
NC 2L = 50 µg/L (10/23/07)29-Nov-07 --- 3.0 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.23 3.0 --- ND --- --- ND 0.48 J 0.7 J 0.32 J 0.59 J ND ND
6-Nov-08 0.23 3.0 --- ND --- --- ND 0.53 J 0.8 J 0.3 J 0.59 J ND ND
3-Jun-09 0.23 3.0 --- ND --- --- 0.26 J 0.47 J 0.73 J 0.39 J 0.76 J ND ND
18-Nov-09 0.23 3.0 --- ND --- --- ND 0.51 J 1.0 J 0.39 J 0.71 J ND ND
16-Jun-10 0.23 3.0 --- ND --- --- ND 0.9 J 1.2 J 0.41 J 0.79 J ND ND
1-Dec-10 0.23 3.0 --- ND ND --- ND 0.74 J 0.63 J ND 0.72 J ND ND
1-Jun-11 0.23 3.0 --- ND ND --- ND 0.8 J 1.0 J 0.5 J 0.4 J ND ND
20-Dec-11 0.23 3.0 --- --- ND --- ND 0.7 J 0.7 J ND 0.7 J ND ND
30-May-12 0.23 3.0 --- --- ND --- 0.24 J 0.73 J 0.7 J 0.47 J 0.7 J ND ND
5-Dec-12 0.23 3.0 --- --- ND --- ND 0.7 J 0.6 J 0.54 J 0.7 J ND ND
12-Jun-13 0.23 3.0 --- --- ND --- 0.88 J 0.57 J 0.86 J 0.57 J 0.65 J ND ND
28-Oct-13 0.23 3.0 --- --- ND --- 0.35 J 0.93 J 0.94 J 0.6 J 0.91 J ND ND
6-May-14 0.23 3.0 --- --- ND --- 0.7 J 0.93 J 0.9 J 0.79 J 0.91 J ND ND
22-Oct-14 0.23 3.0 --- --- * ND 0.84 J 0.77 J 0.79 J 0.80 J 0.78 J ND ND
21-May-15 0.23 3.0 --- --- --- ND 0.67 J 0.84 J 0.74 J 0.72 J 0.58 J ND ND
8-Dec-15 0.23 3.0 --- --- --- ND 1.5 J 0.61 J 0.73 J 0.86 J 0.82 J ND ND
3-May-16 0.23 3.0 --- --- --- ND 1.0 J 0.58 J 0.94 J 0.81 J 0.63 J ND ND
13-Dec-16 0.23 3.0 --- --- --- ND 0.85 J 0.48 J 0.63 J 0.96 J 0.69 J ND ND
27-Jun-17 0.23 3.0 --- --- --- ND 1.3 J 0.53 J 0.73 J 1.10 J 0.57 J ND ---
Chloroethane 1-Sep-94 --- 10.0 ND NI NI NI ND 29 ND ND NI NI ---
1-Jan-95 --- 10.0 --- NI NI NI ND 16 ND ND NI NI ---
1-Feb-95 --- 10.0 --- NI NI NI ND 32 ND ND NI NI ---
1-Mar-95 --- 10.0 ND NI NI NI ND 34 11 ND NI NI ---
1-Aug-95 --- 10.0 ND NI --- --- ND 47 ND ND NI NI ---
1-Jan-96 --- 10.0 --- NI --- --- ND ND ND ND NI NI ---
1-Feb-96 --- 10.0 --- NI --- --- ND 28 ND ND NI NI ---
1-May-96 --- 10.0 --- NI --- --- ND 34 11 ND NI NI ---
1-Oct-96 --- 10.0 --- NI --- --- ND 23 11.00 ND NI NI ---
1-May-97 --- 5.0 3.8 J NI --- --- 15 33 11 ND NI NI ---
1-Nov-97 --- 1.0 3 NI --- --- 10 ND 7 ND NI NI ---
1-May-98 --- 10.0 ND NI --- --- ND 30 28 10 NI NI ---
24-Nov-98 --- 2.0 ND NI --- --- ND ND ND ND NI NI ---
10-May-99 --- 10.0 ND ND --- --- ND 10.0 ND ND 17 ND ND
18-Oct-99 --- 10.0 ND ND --- --- ND 12 ND ND 21 ND ND
3-May-00 --- 10.0 ND ND --- --- ND ND 6.1 6.7 19 ND ND
7-Nov-00 --- 10.0 ND ND --- --- ND ND ND ND 13 ND ND
31-May-01 --- 10.0 ND ND --- --- ND ND ND ND 12 ND ND
7-Nov-01 --- 10.0 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 10.0 12 ND --- --- ND ND ND ND 12 ND ND
14-Nov-02 --- 10.0 10 ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 10.0 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 10.0 ND ND --- --- ND ND 10 ND ND ND ND
6-May-04 --- 10.0 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 10.0 ND ND --- --- ND ND 10 ND ND ND ND
27-May-05 --- 10.0 ND ND --- --- ND ND 10.0 ND ND ND ND
3-Nov-05 --- 10.0 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 10.0 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 10.0 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 10.0 --- ND --- --- ND ND 9.8 J 8.9 J ND ND ND
NC 2L = 2,800 µg/L (10/23/07)29-Nov-07 --- 10.0 --- 1.4 J --- --- ND ND 4.3 J 5.7 JD 4.3 J ND ND
29-May-08 0.54 10.0 --- 1.2 J --- --- 1.1 J ND 1.5 J 6.0 J 2.6 J ND ND
6-Nov-08 0.54 10.0 --- 2 J --- --- ND 0.9 J 3.5 J 5.6 J 4.3 J ND ND
3-Jun-09 0.54 10.0 --- 1.1 J --- --- ND ND ND 4.0 J 4.4 J ND ND
18-Nov-09 0.54 10.0 --- 3.1 J --- --- 0.8 J 0.6 J 5.5 J 5.1 J 3.5 J ND ND
NC 2L = 3,000 µg/L (01/01/10)16-Jun-10 0.54 10.0 --- 1.7 J --- --- 0.72 J 0.88 J 3.1 J 4.5 J 2.2 J ND ND
1-Dec-10 0.54 10.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 0.54 10.0 --- 1.5 J ND --- 0.71 J ND 2.7 J 3.8 J ND ND ND
20-Dec-11 0.54 10.0 --- --- ND --- 0.64 J ND 2.1 J ND 2.9 J ND ND
30-May-12 0.54 10.0 --- --- ND --- ND ND 1.5 J 2.4 J ND ND ND
5-Dec-12 0.54 10.0 --- --- ND --- ND ND 1.8 J 2.7 J 1.9 J ND ND
12-Jun-13 0.54 10.0 --- --- ND --- ND ND 0.63 J 0.84 J 1.5 J ND ND
28-Oct-13 0.54 10.0 --- --- ND --- ND ND 1.9 J 2.3 J ND ND ND
6-May-14 0.54 10.0 --- --- ND --- ND ND 1.6 J 1.7 J 1.3 J ND ND
22-Oct-14 0.54 10.0 --- --- * ND 0.75 J ND ND 2.1 J 1.6 J ND ND
21-May-15 0.54 10.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.54 10.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.54 10.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.54 10.0 --- --- --- ND ND ND 3.0 J 1.2 J 1.7 J ND ND
27-Jun-17 0.54 10.0 --- --- --- ND 0.58 J ND 2.6 J 0.78 J 1.6 J ND ---
Burke County Johns River C D over MSWLF
Permit 12-03 Page 2 of 12 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Chloromethane 18-Nov-09 0.11 1.0 --- ND --- --- ND ND ND 0.45 J ND ND ND
NC 2L = 3 µg/L (01/01/10)16-Jun-10 0.11 1.0 --- ND --- --- 0.14 J ND ND 0.48 J ND ND ND
1-Dec-10 0.11 1.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 0.11 1.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 0.11 1.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 0.11 1.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.11 1.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 0.11 1.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 0.11 1.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 0.11 1.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 0.11 1.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.11 1.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.11 1.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.11 1.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.11 1.0 --- --- --- ND ND ND ND ND 0.16 B ND 0.17 J
27-Jun-17 0.11 1.0 --- --- --- ND 0.31 J 0.20 J 0.27 J 0.36 J 0.28 J 0.30 J ---
Chloroform 30-May-07 --- 5.0 --- ND --- --- 0.92 B 1.2 B 0.99 B 1.4 B 1 B ND 0.98 J
NC 2L = 70 µg/L (10/23/07)29-Nov-07 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.14 5.0 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 0.14 5.0 --- ND --- --- ND ND ND ND ND ND ND
3-Jun-09 0.14 5.0 --- ND --- --- ND ND ND ND ND ND ND
18-Nov-09 0.14 5.0 --- ND --- --- ND ND ND ND ND ND ND
16-Jun-10 0.14 5.0 --- ND --- --- ND ND ND 0.2 B ND ND 0.29 J
1-Dec-10 0.14 5.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 0.14 5.0 --- ND ND --- ND ND ND 0.36 B ND ND 0.63 J
20-Dec-11 0.14 5.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 0.14 5.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.14 5.0 --- --- ND --- ND ND ND 0.14 J ND ND ND
12-Jun-13 0.14 5.0 --- --- ND --- ND ND ND ND ND ND 46
28-Oct-13 0.14 5.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 0.14 5.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 0.14 5.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.14 5.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.14 5.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.14 5.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.14 5.0 --- --- --- ND ND ND ND ND ND ND ND
27-Jun-17 0.14 5.0 --- --- --- ND ND ND ND ND ND ND ---
Dibromochloromethane 30-May-07 --- 1.0 --- ND --- --- 1.7 ND ND ND 1.7 ND ND
GWPS = 0.41 µg/L (10/23/07)Nov-07 --- 3.0 --- ND --- --- ND ND ND ND ND ND ND
May-08 0.21 3.0 --- ND --- --- ND ND ND ND ND ND ND
Nov-08 0.21 3.0 --- ND --- --- ND ND ND ND ND ND ND
Jun-09 0.21 3.0 --- ND --- --- ND ND ND ND ND ND ND
Nov-09 0.21 3.0 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 0.4 µg/L (01/01/10)Jun-10 0.21 3.0 --- ND --- --- ND ND ND ND ND ND ND
Dec-10 0.21 3.0 --- ND ND --- ND ND ND ND ND ND ND
Jun-11 0.21 3.0 --- ND ND --- ND ND ND ND ND ND ND
Dec-11 0.21 3.0 --- --- ND --- ND ND ND ND ND ND ND
May-12 0.21 3.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.21 3.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 0.21 3.0 --- --- ND --- ND ND ND ND ND ND 9.2
28-Oct-13 0.21 3.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 0.21 3.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 0.21 3.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.21 3.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.21 3.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.21 3.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.21 3.0 --- --- --- ND ND ND ND ND ND ND ND
27-Jun-17 0.21 3.0 --- --- --- ND ND ND ND ND ND ND ---
1,2-Dichlorobenzene 3-Jun-09 0.3 5.0 --- ND --- --- ND ND ND 0.4 J ND ND ND
NC 2L = 24 µg/L (10/23/07)18-Nov-09 0.3 5.0 --- ND --- --- ND ND ND 0.4 J ND ND ND
NC 2L = 20 µg/L (01/01/10)16-Jun-10 0.3 5.0 --- ND --- --- ND 0.39 J ND 0.4 J ND ND ND
1-Dec-10 0.3 5.0 --- ND ND --- ND 0.49 J ND 0.5 J ND ND ND
1-Jun-11 0.3 5.0 --- ND ND --- ND 0.5 J ND 0.5 J ND ND ND
20-Dec-11 0.3 5.0 --- --- ND --- ND 0.4 J ND ND ND ND ND
30-May-12 0.3 5.0 --- --- ND --- ND 0.4 J ND 0.6 J ND ND ND
5-Dec-12 0.3 5.0 --- --- ND --- ND 0.4 J ND 0.6 J ND ND ND
12-Jun-13 0.3 5.0 --- --- ND --- ND 0.4 J ND 0.6 J ND ND ND
28-Oct-13 0.3 5.0 --- --- ND --- ND 0.39 J ND 0.54 J ND ND ND
6-May-14 0.3 5.0 --- --- ND --- ND 0.46 J ND 0.55 J ND ND ND
22-Oct-14 0.3 5.0 --- --- * ND ND 0.45 J ND ND ND ND ND
21-May-15 0.3 5.0 --- --- --- ND ND 0.45 J ND 0.58 J ND ND ND
8-Dec-15 0.3 5.0 --- --- --- ND ND 0.39 J ND 0.45 J ND ND ND
3-May-16 0.3 5.0 --- --- --- ND ND 0.42 J ND 0.54 J ND ND ND
13-Dec-16 0.3 5.0 --- --- --- ND ND 0.32 J ND 0.67 J ND ND ND
27-Jun-17 0.3 5.0 --- --- --- ND ND 0.31 J ND 0.80 J ND ND ---
Burke County Johns River C D over MSWLF
Permit 12-03 Page 3 of 12 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
1,4-Dichlorobenzene 1-Sep-94 --- 5.0 ND NI NI NI ND 6.5 ND ND NI NI ---
1-Oct-94 --- 5.0 --- NI NI NI ---8 --- --- NI NI ---
1-Jan-95 --- 5.0 --- NI NI NI ND ND ND ND NI NI ---
1-Feb-95 --- 5.0 --- NI NI NI ND 9.8 ND ND NI NI ---
1-Mar-95 --- 5.0 ND NI NI NI ND 12.0 ND ND NI NI ---
1-Aug-95 --- 5.0 ND NI --- --- ND 14.0 ND ND NI NI ---
1-Jan-96 --- 5.0 --- NI --- --- ND 20 ND ND NI NI ---
1-Feb-96 --- 5.0 --- NI --- --- ND 19.0 ND ND NI NI ---
1-May-96 --- 5.0 --- NI --- --- ND 18 ND ND NI NI ---
1-Oct-96 --- 5.0 --- NI --- --- ND 16.0 ND ND NI NI ---
1-May-97 --- 5.0 ND NI --- --- ND 14.0 ND ND NI NI ---
1-Nov-97 --- 1.0 ND NI --- --- ND ND ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---
24-Nov-98 --- 2.0 ND NI --- --- ND 4 ND ND NI NI ---
10-May-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
18-Oct-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
3-May-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 5.0 ND ND --- --- ND 7.2 ND ND 6.5 ND ND
20-Nov-03 --- 5.0 ND ND --- --- ND 12 ND ND 5.7 ND ND
6-May-04 --- 5.0 ND ND --- --- ND 14 ND ND 5.2 ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND 17 ND ND 6.7 ND ND
27-May-05 --- 5.0 ND ND --- --- ND 20.0 ND ND 6.0 ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND 21 ND ND 6.0 ND ND
25-May-06 --- 5.0 --- ND --- --- ND 16.5 ND ND 5.4 ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND 16 ND ND 7.2 ND ND
30-May-07 --- 1.0 --- ND --- --- ND 23.0 5.2 4.4 7.2 ND ND
NC 2L = 1.4 µg/L (10/23/07)29-Nov-07 --- 1.0 --- ND --- --- ND 11 2.3 4.5 5.2 ND ND
29-May-08 0.33 1.0 --- ND --- --- ND 13.5 3.1 5.2 6.0 ND ND
6-Nov-08 0.33 1.0 --- ND --- --- ND 9.7 Q 3.7 4.3 5.5 ND ND
3-Jun-09 0.33 1.0 --- ND --- --- ND 14.3 4.2 7.3 8.0 ND ND
18-Nov-09 0.33 1.0 --- ND --- --- ND 12.2 4.5 6.4 6.8 ND 0.55 J
NC 2L = 6 µg/L (01/01/10)16-Jun-10 0.33 1.0 --- ND --- --- ND 19.8 4.7 6.8 5.7 ND ND
1-Dec-10 0.33 1.0 --- ND ND --- 0.43 J 18.5 3.5 7.5 7.5 ND ND
1-Jun-11 0.33 1.0 --- ND ND --- ND 19.2 4.5 8.4 3.4 ND ND
20-Dec-11 0.33 1.0 --- --- ND --- 0.37 J 13.9 4 7.8 D 6.5 ND ND
30-May-12 0.33 1.0 --- --- ND --- ND 16.4 4.2 9.9 7.0 ND ND
5-Dec-12 0.33 1.0 --- --- ND --- ND 15 4.4 9.7 6.0 ND ND
12-Jun-13 0.33 1.0 --- --- ND --- 0.48 J 12.4 4.9 9.7 7.5 ND ND
28-Oct-13 0.33 1.0 --- --- 0.63 J --- 0.45 J 16.7 5 10.1 8.3 ND ND
6-May-14 0.33 1.0 --- --- ND --- 0.63 J 18 5.2 12.3 8.9 ND ND
22-Oct-14 0.33 1.0 --- --- * ND 0.73 J 16.1 4.8 11.9 7.5 ND ND
21-May-15 0.33 1.0 --- --- --- ND 0.7 J 17.1 5.0 12.0 7.1 ND ND
8-Dec-15 0.33 1.0 --- --- --- ND 0.98 J 12.6 4.8 13.2 9.1 ND ND
3-May-16 0.33 1.0 --- --- --- ND 0.93 J 14.2 6.0 15.0 6.6 ND ND
13-Dec-16 0.33 1.0 --- --- --- ND 0.89 J 10.5 4.7 13.9 7.2 ND ND
27-Jun-17 0.33 1.0 --- --- --- ND ND 10.6 ND 16.0 ND ND ---
Dichlorodifluoromethane 1-Aug-95 --- 5.0 ND NI --- --- ND 26 ND 22 NI NI ---
#1-Jan-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---
1-Feb-96 --- 10.0 --- NI --- --- ND ND ND ND NI NI ---
1-May-96 --- 10.0 --- NI --- --- ND 35 25 ND NI NI ---
1-Oct-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---
1-May-97 --- 5.0 6.4 NI --- --- ND 16 20.0 42.0 NI NI ---
1-Nov-97 --- 5.0 14 NI --- --- ND ND 31.0 90.0 NI NI ---
24-Nov-98 --- 2.0 ND NI --- --- ND ND ND ND NI NI ---
10-May-99 --- 10.0 ND ND --- --- ND ND 19.0 27.0 ND ND ND
18-Oct-99 --- 5.0 ND ND --- --- --- 14.0 50.0 130.0 25 ND ND
3-May-00 --- 5.0 --- --- --- --- --- ND 16.00 36.0 8.9 --- ND
7-Nov-00 --- 5.0 ND --- --- --- ND ND 9.40 30.0 7.9 --- ND
31-May-01 --- 5.0 ND --- --- --- ND ND 13 25 6.2 --- ND
7-Nov-01 --- 5.0 ND --- --- --- ND 5.5 ND 34 12 --- ND
22-May-02 --- 5.0 ND --- --- --- ND 5 15 24 11 --- ND
14-Nov-02 --- 5.0 ND --- --- --- ND ND ND 20 ND --- ND
14-May-03 --- 5.0 ND --- --- --- ND ND 8.7 12 ND --- ND
20-Nov-03 --- 5.0 ND ND --- --- ND ND 6.3 10 ND ND ND
6-May-04 --- 5.0 ND --- --- --- ND ND ND 9.2 ND --- ND
10-Nov-04 --- 5.0 ND --- --- --- ND ND 7.6 10 ND ND ND
27-May-05 --- 5.0 ND --- --- --- ND ND 14 22 ND --- ND
3-Nov-05 --- 5.0 --- ND --- --- ND ND 9 12 ND ND ND
25-May-06 --- 5.0 --- --- --- --- ND ND ND 5.4 ND --- ND
2-Nov-06 --- 5.0 --- ND --- --- ND ND 8.2 6.6 ND ND ND
30-May-07 ---5.0 --- --- --- --- ND ND 7.1 7.6 ND --- ---
NC 2L = 1,400 µg/L (10/23/07)29-Nov-07 --- 5.0 --- ND --- --- ND ND 1.1 J 1.8 JD ND ND ND
29-May-08 0.21 1.0 --- --- --- --- ND 0.35 J 2.9 3.6 ND --- ND
6-Nov-08 0.21 5.0 --- 0.62 J --- --- ND 0.33 J 1.9 J 2.2 J 0.69 J ND ND
3-Jun-09 0.21 5.0 --- 0.45 J --- --- 0.96 J ND 2.5 J 1.9 J 0.72 J ND ND
18-Nov-09 0.21 5.0 --- ND --- --- ND ND 1.2 J 1.9 J 0.47 J ND ND
NC 2L = 1,000 µg/L (01/01/10)16-Jun-10 0.21 5.0 --- ND --- --- ND ND 0.81 J 1.4 J ND ND ND
1-Dec-10 0.21 5.0 --- 0.26 J ND --- ND ND 0.69 J 1.1 J 0.55 J ND ND
1-Jun-11 0.21 5.0 --- 0.42 J ND --- ND ND ND 1.2 J ND ND ND
20-Dec-11 0.21 5.0 --- --- ND --- ND ND ND 0.76
J
D ND ND ND
30-May-12 0.21 5.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.21 5.0 --- --- ND --- ND ND ND ND ND --- ND
12-Jun-13 0.21 5.0 --- --- ND --- 0.34 J ND ND ND ND ND ND
28-Oct-13 0.21 5.0 --- --- ND --- ND ND ND 1.1 J ND ND ND
6-May-14 0.21 5.0 --- --- ND --- ND ND ND ND ND --- ND
22-Oct-14 0.21 5.0 --- --- * ND ND ND ND ND ND --- ND
21-May-15 0.21 5.0 --- --- --- ND ND ND ND ND ND --- ND
8-Dec-15 0.21 5.0 --- --- --- ND ND ND ND ND ND --- ND
3-May-16 0.21 5.0 --- --- --- ND ND ND ND 0.54 J 0.26 J --- ND
13-Dec-16 0.21 5.0 --- --- --- ND ND ND ND 0.57 J ND --- ND
27-Jun-17 0.21 5.0 --- --- --- ND ND ND ND 0.64 J ND --- ---
Burke County Johns River C D over MSWLF
Permit 12-03 Page 4 of 12 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
1,1-Dichloroethane 1-Sep-94 --- 5.0 ND NI NI NI ND 50 7.5 ND NI NI ---
1-Jan-95 --- 5.0 ---NI NI NI ND 35 33 ND NI NI ---
1-Feb-95 --- 5.0 --- NI NI NI ND 66 34 ND NI NI ---
1-Mar-95 --- 5.0 ND NI NI NI ND 72 34 ND NI NI ---
1-Aug-95 --- 5.0 ND NI --- --- ND 96 ND ND NI NI ---
1-Jan-96 --- 5.0 --- NI --- --- 13 120 54 ND NI NI ---
1-Feb-96 --- 5.0 --- NI --- --- 11 ND ND ND NI NI ---
1-May-96 --- 5.0 --- NI --- --- 12 110 68 ND NI NI ---
1-Oct-96 --- 5.0 --- NI --- --- 17 140 86 ND NI NI ---
1-May-97 --- 5.0 ND NI --- --- 39 170 100 4 J NI NI ---
1-Nov-97 --- 1.0 2 NI --- --- 22 200 69.0 8 NI NI ---
1-May-98 --- 5.0 5.5 NI --- --- 22.0 250.0 250.0 45.0 NI NI ---
24-Nov-98 --- 2.0 3.8 NI --- --- 14 150.0 57 19.9 NI NI ---
10-May-99 --- 5.0 7.7 ND --- --- 9.7 180.0 64.0 30.0 120 ND ND
18-Oct-99 --- 5.0 11.0 J ND --- --- 9.3 J 200 59 30.0 120 ND ND
3-May-00 --- 5.0 9.3 J ND --- --- 6.2 J 120.0 61.0 38.0 120 ND ND
7-Nov-00 --- 5.0 9.5 ND --- --- 5.0 110.0 60.0 44.0 92 ND ND
31-May-01 --- 5.0 7.9 6 --- --- ND 80.0 75.0 45.0 79 ND ND
7-Nov-01 --- 5.0 14.0 5.3 --- --- ND 84.0 100.0 42.0 95 ND ND
22-May-02 --- 5.0 19.0 ND --- --- ND 75.0 110.0 57 100 ND ND
14-Nov-02 --- 5.0 21.0 ND --- --- ND 41.0 90.0 50.0 82 ND ND
14-May-03 --- 5.0 27.0 ND --- --- ND 48.0 60.0 69.0 82 ND ND
20-Nov-03 --- 5.0 25.0 ND --- --- ND 34.0 48.0 62.0 59 ND ND
6-May-04 --- 5.0 33.0 ND --- --- ND 33 58.0 72.0 58 ND ND
10-Nov-04 --- 5.0 38.0 ND --- --- ND 22.0 37.0 50.0 42 ND ND
27-May-05 --- 5.0 68.0 ND --- --- ND 25 48 66 44.0 ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND 18.0 34 54.0 38 ND ND
25-May-06 --- 5.0 --- ND --- --- ND 10.9 27 37.6 25.3 ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND 12 34 47 33 ND ND
30-May-07 --- 5.0 --- 5.3 --- --- 3.3 J 16 48 59 41 ND ND
NC 2L = 70 µg/L (10/23/07)29-Nov-07 --- 5.0 --- 6.1 --- --- 2.2 J 7.7 39 44 34 ND ND
29-May-08 0.32 5.0 --- 1.7 J --- --- 1.7 J 8.7 38.8 ND 29.7 ND ND
6-Nov-08 0.32 5.0 --- 5.7 --- --- 1.9 J 8.1 34.6 52.3 26.2 ND ND
3-Jun-09 0.32 5.0 --- 6.3 --- --- 1.3 J 8.2 47.8 53.1 32 ND ND
18-Nov-09 0.32 5.0 --- 10.8 --- --- 1.2 J 6.7 41.9 52.0 29.4 ND ND
NC 2L = 6 µg/L (01/01/10)16-Jun-10 0.32 5.0 --- 3.9 J --- --- 1.2 J 5.7 35.7 43.1 32.1 ND ND
1-Dec-10 0.32 5.0 ---6.8 ND --- 1.7 J 5.4 41.3 37.9 16.9 ND ND
1-Jun-11 0.32 5.0 ---9.3 ND --- 2 J 6.8 45.5 53.3 19.1 ND ND
20-Dec-11 0.32 5.0 --- --- ND --- 1.9 J 5.1 39.7 39.7 D 26.2 ND ND
30-May-12 0.32 5.0 --- --- ND --- 1.5 J 5.9 38.2 45.8 24.1 ND ND
5-Dec-12 0.32 5.0 --- --- ND --- 1.7 J 4.6 J 39.3 39.3 26.5 ND ND
12-Jun-13 0.32 5.0 --- --- ND --- 0.73 J 5.3 37.1 41.6 21.4 ND ND
28-Oct-13 0.32 5.0 --- --- ND --- 1 J 4.9 J 43.2 41.8 26.2 ND ND
6-May-14 0.32 5.0 --- --- ND --- 1 J 4 J 43.4 39.5 21.5 ND ND
22-Oct-14 0.32 5.0 --- --- * ND 1.3 J 3.6 J 34.4 33.2 25.3 ND ND
21-May-15 0.32 5.0 --- --- --- ND 0.75 J 2.8 J 26.7 23.1 17.3 ND ND
8-Dec-15 0.32 5.0 --- --- --- ND 0.95 J 3.2 J 31.7 33.7 10.3 ND ND
3-May-16 0.32 5.0 --- --- --- ND 1.3 J 3.4 J 23.4 28.4 14.8 ND ND
13-Dec-16 0.32 5.0 --- --- --- ND 1.4 J 3.0 J 27.4 26.4 22.1 ND ND
27-Jun-17 0.32 5.0 --- --- --- ND 0.78 J 3.3 J 26.8 24.2 17.8 ND ---
1,2-Dichloroethane 3-Nov-05 --- 5.0 --- ND --- --- ND 13 ND ND ND ND ND
25-May-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 1.0 --- ND --- --- ND 2.4 ND 1.6 ND ND ND
NC 2L = 0.38 µg/L (10/23/07) 29-Nov-07 --- 1.0 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.12 1.0 --- ND --- --- ND 1.2 0.64 J 1.5 1.1 ND ND
6-Nov-08 0.12 1.0 --- ND --- --- ND 0.65 B 0.27 B 1.8 B 0.46 B ND 1 J
3-Jun-09 0.12 1.0 --- ND --- --- ND 0.78 J 0.8 J 1.9 0.98 J ND ND
18-Nov-09 0.12 1.0 --- ND --- --- ND 0.98 J 1.0 1.8 0.97 J ND ND
NC 2L = 0.4 µg/L (01/01/10)16-Jun-10 0.12 1.0 --- ND --- --- ND 1.2 1.1 1.8 1.0 ND ND
1-Dec-10 0.12 1.0 --- ND ND --- ND 0.94 J 0.58 J 1.5 0.18 J ND ND
1-Jun-11 0.12 1.0 --- ND ND --- ND ND 1.1 2.1 1.0 ND ND
20-Dec-11 0.12 1.0 --- --- ND --- ND 0.8 J 0.92 J 1.8 J 1.0 ND ND
30-May-12 0.12 1.0 --- --- ND --- ND 0.75 J 0.97 J 2 1 ND ND
5-Dec-12 0.12 1.0 ------ND --- ND 0.7 J 0.8 J 1.7 1.3 ND ND
12-Jun-13 0.12 1.0 --- --- ND --- ND 0.6 J 1.3 1.7 1.0 ND ND
28-Oct-13 0.12 1.0 --- --- ND --- ND 0.9 J 1.4 1.7 1.4 ND ND
6-May-14 0.12 1.0 --- --- ND --- ND 0.8 J 1.2 1.6 1.2 ND ND
22-Oct-14 0.12 1.0 --- --- * ND ND 0.51 J 0.85 J 1.5 1.2 ND ND
21-May-15 0.12 1.0 --- --- --- ND ND ND 0.71 J ND ND ND ND
8-Dec-15 0.24 1.0 --- --- --- ND ND 0.65 J ND 1.3 1.3 ND ND
3-May-16 0.24 1.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.24 1.0 --- --- --- ND ND 0.48 J 1.1 1.3 1.2 ND ND
27-Jun-17 0.24 1.0 --- --- --- ND ND 0.26 J 0.88 J 1.3 1.0 J ND ---
1,1-Dichloroethene 1-May-97 --- 5.0 ND NI --- ---ND 3 J ND 4 J NI NI ---
1-Nov-97 --- 1.0 ND NI --- --- ND ND ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---
24-Nov-98 --- 2.0 ND NI --- --- ND ND ND ND NI NI ---
10-May-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
18-Oct-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
3-May-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
27-May-05 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 5.0 --- ND --- --- ND ND 0.93 J 1.8 J 0.42 J ND ND
NC 2L = 7 µg/L (10/23/07) 29-Nov-07 --- 5.0 --- ND --- --- ND ND 0.8 J 1.2 JD 0.59 J ND ND
29-May-08 0.6 1.0 --- ND --- --- ND ND 0.75 J 1.3 ND ND ND
6-Nov-08 0.6 5.0 --- ND --- --- ND ND 0.64 J 1.1 J ND ND ND
3-Jun-09 0.6 5.0 --- ND --- --- ND ND 0.95 J 1.1 J ND ND ND
18-Nov-09 0.6 5.0 --- ND --- --- ND ND 0.78 J 1.1 J ND ND ND
16-Jun-10 0.6 5.0 --- ND --- --- 0.98 J ND 0.68 J 1.2 J ND ND ND
1-Dec-10 0.6 5.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 0.6 5.0 --- ND ND --- ND ND 0.68 J 0.82 J ND ND ND
20-Dec-11 0.6 5.0 --- --- ND --- ND ND 0.59 J ND ND ND ND
30-May-12 0.6 5.0 --- --- ND --- ND ND 0.62 J 0.58 J ND ND ND
5-Dec-12 0.6 5.0 --- --- ND --- ND ND 0.66 J 0.58 J ND ND ND
NC 2L = 350 µg/L (04/01/2013) 12-Jun-13 0.6 5.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 0.6 5.0 --- --- ND --- ND ND 0.6 J ND ND ND ND
6-May-14 0.6 5.0 --- --- ND --- ND ND 0.59 J ND ND ND ND
22-Oct-14 0.6 5.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.6 5.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.6 5.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.6 5.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.6 5.0 --- --- --- ND ND ND ND ND ND ND ND
27-Jun-17 0.6 5.0 --- --- --- ND ND ND ND ND ND ND ---
Burke County Johns River C D over MSWLF
Permit 12-03 Page 5 of 12 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
cis-1,2-Dichloroethene 1-Feb-96 --- 5.0 --- NI --- --- 11 89 35 ND NI NI ---
1-May-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---
1-Oct-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---
1-May-97 --- 5.0 ND NI --- --- ND 2.1 J ND ND NI NI ---
1-Nov-97 --- 1.0 ND NI --- --- ND ND ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---
24-Nov-98 --- 2.0 ND NI --- --- ND 2.8 ND ND NI NI ---
10-May-99 --- 5.0 ND ND --- --- ND ND ND ND 7 ND ND
18-Oct-99 --- 5.0 ND ND --- --- ND 6.3 ND ND 14 ND ND
3-May-00 --- 5.0 ND ND --- --- ND ND ND ND 13 ND ND
7-Nov-00 --- 5.0 ND ND --- --- ND ND ND ND 13 ND ND
31-May-01 --- 5.0 ND ND --- --- ND ND ND ND 14 ND ND
7-Nov-01 --- 5.0 ND ND --- --- ND 5.9 6.5 ND 18 ND ND
22-May-02 --- 5.0 ND ND --- --- ND 8 11 ND 24 ND ND
14-Nov-02 --- 5.0 ND ND --- --- 5 7 13.0 ND 28 ND ND
14-May-03 --- 5.0 ND ND --- --- 7 11 8 5 36 ND ND
20-Nov-03 --- 5.0 ND ND --- --- 5 14 13 6 27 ND ND
6-May-04 --- 5.0 ND ND --- --- ND 16 17 7.2 32 ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND 14 13 5.8 29 ND ND
27-May-05 --- 5.0 ND ND --- --- ND 16 23 8 23 ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND 5 6 ND 9 ND ND
25-May-06 --- 5.0 --- ND --- --- ND 8.2 9.3 5.2 7.7 ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND 16 12.0 12 17 ND ND
30-May-07 --- 5.0 --- ND --- --- 4.9 J 20 21.0 17 15 ND ND
NC 2L = 70 µg/L (10/23/07)29-Nov-07 --- 5.0 --- ND --- --- 2.9 J 8.6 7.2 13 9.1 ND ND
29-May-08 0.19 5.0 --- ND --- --- 2.8 J 13.4 10.9 18.4 10.4 ND ND
6-Nov-08 0.19 5.0 --- 0.5 J --- --- 2.8 J 12.7 10 20.4 7.6 ND ND
3-Jun-09 0.19 5.0 --- 0.71 J --- --- 2.5 J 13.1 11.9 25.3 10.4 ND ND
18-Nov-09 0.19 5.0 --- 2.8 B --- --- 2.5 B 12.2 B 20 25.9 10.8 B ND 2.6 J
16-Jun-10 0.19 5.0 --- 1.7 J --- --- 2.3 J 14.8 15.6 22.2 9.7 ND ND
1-Dec-10 0.19 5.0 --- 0.66 J ND --- 3.1 J 11.3 9.2 19.7 7.1 ND ND
1-Jun-11 0.19 5.0 --- 0.89 J ND --- 3.7 J 14.5 13.8 28.8 5.7 ND ND
20-Dec-11 0.19 5.0 --- --- ND --- 3.7 J 9.5 9.7 21.4 D 6.5 ND ND
30-May-12 0.19 5.0 --- --- ND --- 3.1 J 11.8 11.2 26.5 6.8 ND ND
5-Dec-12 0.19 5.0 --- --- ND --- 3.3 J 9.1 9.4 25.4 6.6 ND ND
12-Jun-13 0.19 5.0 --- --- ND --- 2.5 J 9 12.8 26.2 6.2 ND ND
28-Oct-13 0.19 5.0 --- --- ND --- 3 J 11.2 14 29.1 7.7 ND ND
6-May-14 0.19 5.0 --- --- ND --- 3.4 J 9.5 13 27.1 7.7 ND ND
22-Oct-14 0.19 5.0 --- --- * ND 4.3 J 8.0 10.1 25 7.1 ND ND
21-May-15 0.19 5.0 --- --- --- ND 2.8 J 6.7 7.6 17.0 4.2 J ND ND
8-Dec-15 0.19 5.0 --- --- --- ND 3.9 J 6.9 9.9 25.8 4.4 J ND ND
3-May-16 0.19 5.0 --- --- --- ND 4.3 J 5.9 9.6 23.9 4.6 J ND ND
13-Dec-16 0.19 5.0 --- --- --- ND 5.1 5.7 9.8 25.7 6.1 ND ND
27-Jun-17 0.19 5.0 --- --- --- ND 3.5 J 5.8 9.0 23.3 5.4 ND ---
trans-1,2-Dichloroethene 5-Dec-13 0.49 5.0 --- --- ND --- ND ND 0.67 J 0.59 J ND ND ND
NC 2L = 100 µg/L (10/23/07)12-Jun-13 0.49 5.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 0.49 5.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 0.49 5.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 0.49 5.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.49 5.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.49 5.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.49 5.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.49 5.0 --- --- --- ND ND ND ND ND ND ND ND
27-Jun-17 0.49 5.0 --- --- --- ND ND ND ND ND ND ND ---

1,2-Dichloropropane 30-May-07 --- 1.0 --- ND --- --- ND ND ND 2.2 2.5 ND ND
NC 2L = 0.51 µg/L (10/23/07)29-Nov-07 --- 1.0 --- ND --- --- ND ND ND ND 0.7 J ND ND
29-May-08 0.27 1.0 --- ND --- --- ND ND 0.4 J 0.72 J 0.85 J ND ND
6-Nov-08 0.27 1.0 --- ND --- --- ND 0.32 J 0.5 J 0.68 J 0.67 J ND ND
3-Jun-09 0.27 1.0 --- ND --- --- ND ND ND 0.88 J 0.9 J ND ND
18-Nov-09 0.27 1.0 --- ND --- --- ND ND 0.5 J 0.7 J 0.84 J ND ND
NC 2L = 0.6 µg/L (01/01/10)16-Jun-10 0.27 1.0 --- ND --- --- ND ND 0.5 J 0.7 J 0.67 J ND ND
1-Dec-10 0.27 1.0 --- ND ND --- ND 0.33 J 0.29 J 0.55 J 0.72 J ND ND
1-Jun-11 0.27 1.0 --- ND ND --- ND ND ND 0.88 J ND ND ND
20-Dec-11 0.27 1.0 --- --- ND --- ND ND 0.35 J 0.57 JD 0.48 J ND ND
30-May-12 0.27 1.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.27 1.0 --- --- ND --- ND ND 0.37 J 0.65 J 0.59 J ND ND
12-Jun-13 0.27 1.0 --- --- ND --- ND ND 0.35 J 0.6 J 0.59 J ND ND
28-Oct-13 0.27 1.0 --- --- ND --- ND ND ND ND 0.47 J ND ND
6-May-14 0.27 1.0 --- --- ND --- ND ND 0.33 J 0.54 J 0.58 J ND ND
22-Oct-14 0.27 1.0 --- --- * ND ND ND ND ND 0.49 J ND ND
21-May-15 0.27 1.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.27 1.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.27 1.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.27 1.0 --- --- --- ND ND ND ND ND ND ND ND
27-Jun-17 0.27 1.0 --- --- --- ND ND ND ND 0.28 J ND ND ---
Ethylbenzene 1-May-98 --- 5.0 ND NI --- --- ND ND 6.4 ND NI NI ---
24-Nov-98 --- 2.0 ND NI --- --- ND ND ND ND NI NI ---
10-May-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
18-Oct-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
3-May-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 5.0 ND ND --- --- ND ND 6.4 ND ND ND ND
7-Nov-01 --- 5.0 ND ND --- --- ND ND 5 ND ND ND ND
22-May-02 --- 5.0 ND ND --- --- ND ND 14 ND ND ND ND
14-Nov-02 --- 5.0 ND ND --- --- ND ND 14 ND ND ND ND
14-May-03 --- 5.0 ND ND --- --- ND ND 11 8.8 ND ND ND
20-Nov-03 --- 5.0 ND ND --- --- ND ND 15 8.3 ND ND ND
6-May-04 --- 5.0 ND ND --- --- ND ND 21 7.6 ND ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND ND 11.0 ND ND ND ND
27-May-05 --- 5.0 ND ND --- --- ND ND 23 8 ND ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND ND 14 9 ND ND ND
25-May-06 --- 5.0 --- ND --- --- ND ND 17 5.8 ND ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND ND 8.4 ND ND ND ND
30-May-07 --- 1.0 --- ND --- --- ND ND 18 4.1 ND ND ND
NC 2L = 550 µg/L (10/23/07)29-Nov-07 --- 1.0 --- ND --- --- ND ND 0.54 J 2 ND ND ND
29-May-08 0.3 1.0 --- ND --- --- ND ND 2.6 2.6 ND ND ND
6-Nov-08 0.3 1.0 --- ND --- --- ND ND 2 3.5 ND ND ND
3-Jun-09 0.3 1.0 --- ND --- --- ND ND 6 8 ND ND ND
18-Nov-09 0.3 1.0 --- ND --- --- ND ND 3.3 4.1 ND ND ND
NC 2L = 600 µg/L (01/01/10)16-Jun-10 0.3 1.0 --- ND --- --- ND ND 6.5 5 ND ND ND
1-Dec-10 0.3 1.0 --- ND ND --- ND ND 2.9 3 ND ND ND
1-Jun-11 0.3 1.0 --- ND ND --- ND ND 1.3 3 ND ND ND
20-Dec-11 0.3 1.0 --- --- ND --- ND ND 0.59 J 1.2 JD ND ND ND
30-May-12 0.3 1.0 --- --- ND --- ND 0.38 J 0.77 J 7 ND ND ND
5-Dec-12 0.3 1.0 --- --- ND --- ND 0.32 J 1.1 2.1 ND ND ND
12-Jun-13 0.3 1.0 --- --- ND --- ND 0.4 J 2.3 5.1 ND ND ND
28-Oct-13 0.3 1.0 --- --- ND --- ND 0.35 J 1 5.9 ND ND ND
6-May-14 0.3 1.0 --- --- ND --- ND ND ND 1.6 ND ND ND
22-Oct-14 0.3 1.0 --- --- * ND ND ND 0.32 J 1.5 ND ND ND
21-May-15 0.3 1.0 --- --- --- ND ND ND 0.86 J 1.3 ND ND ND
8-Dec-15 0.3 1.0 --- --- --- ND ND ND 1.2 2.7 ND ND ND
3-May-16 0.3 1.0 --- --- --- ND ND ND 1.4 4.6 ND ND ND
13-Dec-16 0.3 1.0 --- --- --- ND ND ND ND 3.0 ND ND ND
27-Jun-17 0.3 1.0 --- --- --- ND ND ND ND 1.5 ND ND ---
Burke County Johns River C D over MSWLF
Permit 12-03 Page 6 of 12 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Methylene Chloride 1-Sep-94 --- 5.0 ND NI NI NI ND 360 ND ND NI NI ---
1-Oct-94 --- 5.0 --- NI NI NI ---430 --- --- NI NI ---
1-Jan-95 --- 5.0 --- NI NI NI ND 290 ND ND NI NI ---
1-Feb-95 --- 5.0 --- NI NI NI ND 560 ND ND NI NI ---
1-Mar-95 --- 5.0 ND NI NI NI ND 610 ND ND NI NI ---
1-Aug-95 --- 5.0 ND NI --- --- ND 810 ND ND NI NI ---
1-Jan-96 --- 5.0 --- NI --- --- ND 380 ND ND NI NI ---
1-Feb-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---
1-May-96 --- 5.0 --- NI --- --- ND 330 5.3 ND NI NI ---
1-Oct-96 --- 5.0 --- NI --- --- ---68 19 ND NI NI ---
1-May-97 --- 5.0 ND NI --- --- 2.4 J 280 11 ND NI NI ---
1-Nov-97 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- --- ND 420 450 61 NI NI ---
24-Nov-98 --- 10.0 ND NI --- --- ND 92.5 B ND ND NI NI ---
10-May-99 --- 5.0 ND ND --- --- ND 120.00 ND 37 ND ND ND
18-Oct-99 --- 10.0 ND ND --- --- ND 78.00 B ND 34 B ND ND 21
3-May-00 --- 10.0 ND ND --- --- ND 98 ND 68 ND ND ND
7-Nov-00 --- 10.0 ND ND --- --- ND ND ND 56 ND ND ND
31-May-01 --- 10.0 ND ND --- --- ND 18 ND 96 ND ND ND
7-Nov-01 --- 10.0 ND ND --- --- ND ND ND 88 ND ND ND
22-May-02 --- 10.0 ND ND --- --- ND ND 11 130 ND ND ND
14-Nov-02 --- 10.0 ND ND --- --- ND ND 20 130 ND ND ND
14-May-03 --- 10.0 ND ND --- --- ND 18 ND 320 ND ND ND
20-Nov-03 --- 10.0 ND ND --- --- ND ND ND 570 ND ND ND
6-May-04 --- 10.0 12 ND --- --- ND ND 10 420 ND ND ND
10-Nov-04 --- 10.0 12 ND --- --- ND ND ND 360 ND ND ND
27-May-05 --- 10.0 40 ND --- --- ND ND ND 480 ND ND ND
3-Nov-05 --- 10.0 --- ND --- --- ND ND ND 510 ND ND ND
25-May-06 --- 10.0 --- ND --- --- ND ND ND 375 ND ND ND
2-Nov-06 --- 10.0 --- ND --- --- ND ND ND 210 ND ND ND
30-May-07 --- 1.0 --- 2.3 B --- --- ND ND ND 310 ND ND 3.2
NC 2L = 4.6 µg/L (10/23/07)29-Nov-07 --- 1.0 ---4.8 ------0.89 J ND ND 220 ND ND ND
29-May-08 0.97 2.0 --- 2.2 B --- --- ND ND ND 285 ND ND 1.5 J
6-Nov-08 0.97 2.0 --- 2.6 B --- --- 1.1 B ND ND 831 ND ND 3.2 J
3-Jun-09 0.97 2.0 --- ND --- --- ND ND ND 278 ND ND 19.1
18-Nov-09 0.97 2.0 ---11.1 --- --- ND ND ND 241 ND ND ND
NC 2L = 5 µg/L (01/01/10) 16-Jun-10 0.97 2.0 --- ND --- --- ND ND ND 234 ND ND ND
1-Dec-10 0.97 1.0 --- 2.2 ND --- ND ND ND 174 ND ND ND
1-Jun-11 0.97 1.0 --- 2.3 ND --- ND ND ND 232 ND ND ND
20-Dec-11 0.97 1.0 --- --- ND --- ND ND ND 196 D ND ND 1.9
30-May-12 0.97 1.0 --- --- ND --- ND ND ND 185 ND ND ND
5-Dec-12 0.97 1.0 --- --- ND --- ND ND ND 174 ND ND ND
12-Jun-13 0.97 1.0 --- --- ND --- ND ND ND 77.9 ND ND ND
28-Oct-13 0.97 1.0 --- --- ND --- ND ND ND 128 ND ND ND
6-May-14 0.97 1.0 --- --- ND --- ND ND ND 154 ND ND 2.2
22-Oct-14 0.97 1.0 --- --- * ND ND ND ND 130 ND ND ND
21-May-15 0.97 1.0 --- --- --- ND ND ND ND 82.8 ND ND 1.7
8-Dec-15 0.97 1.0 --- --- --- ND ND ND ND 113 ND ND 2.0
3-May-16 0.97 1.0 --- --- --- ND ND ND ND 30.5 ND ND ND
13-Dec-16 0.97 1.0 --- --- --- ND ND ND ND 41.8 ND ND ND
27-Jun-17 0.97 1.0 --- --- --- ND ND ND ND 17.3 ND ND ---
Iodomethane 29-May-08 0 10.0 --- 0.35 J --- --- ND ND ND ND ND ND ND
NC 2L = NE (10/23/07) 6-Nov-08 0 10.0 --- ND --- --- ND ND ND ND ND ND ND
3-Jun-09 0 10.0 --- ND --- --- ND ND ND ND ND ND ND
18-Nov-09 0 10.0 --- ND --- --- ND ND ND ND ND ND ND
16-Jun-10 0 10.0 --- ND --- --- ND ND ND ND ND ND ND
1-Dec-10 0 10.0 --- ND ND --- 5 J ND ND ND ND ND ND
1-Jun-11 0.32 10.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 0.32 10.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 0.32 10.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.32 10.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 0.32 10.0 --- --- ND --- 8.6 J ND ND ND ND ND ND
28-Oct-13 0.32 10.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 0.32 10.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 0.32 10.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.32 10.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.32 10.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.32 10.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.32 10.0 --- --- --- ND ND ND ND ND ND ND ND
27-Jun-17 0.32 10.0 --- --- --- ND ND ND ND ND ND ND ---
Styrene 3-Jun-09 0.26 1.0 --- ND --- --- ND 2 ND ND ND ND ND
NC 2L = 100 µg/L (10/23/07) 18-Nov-09 0.26 1.0 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 70 µg/L (01/01/10) 16-Jun-10 0.26 1.0 --- ND --- --- ND ND ND ND ND ND ND
1-Dec-10 0.26 1.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 0.26 1.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 0.26 1.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 0.26 1.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.26 1.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 0.26 1.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 0.26 1.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 0.26 1.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 0.26 1.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.26 1.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.26 1.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.26 1.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.26 1.0 --- --- --- ND ND ND ND ND ND ND ND
27-Jun-17 0.26 1.0 --- --- --- ND ND ND ND ND ND ND ---
Burke County Johns River C D over MSWLF
Permit 12-03 Page 7 of 12 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Tetrachloroethene 1-May-97 --- 5.0 5.6 NI --- --- ND 6.3 3.6 J ND NI NI ---
1-Nov-97 --- 1.0 2 NI --- --- ND ND ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---
24-Nov-98 --- 2.0 6.7 NI --- --- ND 7.8 3.2 ND NI NI ---
10-May-99 --- 5.0 8.5 ND --- --- ND 9.3 ND ND ND ND ND
18-Oct-99 --- 5.0 5.3 ND --- --- ND 7.3 ND ND ND ND ND
3-May-00 --- 5.0 7 ND --- --- ND 6.4 ND ND ND ND ND
7-Nov-00 --- 5.0 6.6 ND --- --- ND 5.3 ND ND ND ND ND
31-May-01 --- 5.0 9.6 ND --- --- ND 7.1 ND ND ND ND ND
7-Nov-01 --- 5.0 9.5 ND --- --- ND 5.6 5 ND ND ND ND
22-May-02 --- 5.0 10 ND --- --- ND 5.7 5.5 ND ND ND ND
14-Nov-02 --- 5.0 8 ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 5.0 10 ND --- --- ND 5.5 ND ND ND ND ND
20-Nov-03 --- 5.0 8.8 ND --- --- ND 6.6 ND ND ND ND ND
6-May-04 --- 5.0 8.9 ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 5.0 12 ND --- --- ND ND ND 5.1 ND ND ND
27-May-05 --- 5.0 10 ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND ND ND 12 ND ND ND
25-May-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND ND ND 5.8 ND ND ND
30-May-07 --- 1.0 ---1.6 --- --- ND 0.44 J 1.6 5.9 ND ND ND
NC 2L = 0.7 µg/L (10/23/07)29-Nov-07 --- 1.0 ---1.7 --- --- ND ND 1.1 4.9 ND ND ND
29-May-08 0.46 1.0 ---2.2 --- --- ND ND 1.1 6.6 ND ND ND
6-Nov-08 0.46 1.0 ---2.7 --- --- ND ND 1.3 6.2 ND ND ND
3-Jun-09 0.46 1.0 ---2.1 --- --- ND ND 0.7 J 7.5 ND ND ND
18-Nov-09 0.46 1.0 ---2.6 --- --- ND ND 0.49 J 6.3 ND ND ND
16-Jun-10 0.46 1.0 ---1.2 --- --- ND ND 0.46 J 6.7 ND ND ND
1-Dec-10 0.46 1.0 ---3 ND --- ND ND ND 5.8 ND ND ND
1-Jun-11 0.46 1.0 ---3.6 ND --- ND ND ND 7.7 ND ND ND
20-Dec-11 0.46 1.0 --- --- ND --- ND 0.59 B 0.7 B 5.7 D ND ND 1 J
30-May-12 0.46 1.0 --- --- ND --- ND ND ND 7.7 ND ND ND
5-Dec-12 0.46 1.0 --- --- ND --- ND ND ND 7.3 ND ND ND
12-Jun-13 0.46 1.0 --- --- ND --- ND ND ND 6.4 ND ND ND
28-Oct-13 0.46 1.0 --- --- ND --- ND ND ND 5.7 ND ND ND
6-May-14 0.46 1.0 --- --- ND --- ND ND ND 7.3 ND ND ND
22-Oct-14 0.46 1.0 --- --- * ND ND ND ND 7.0 ND ND ND
21-May-15 0.46 1.0 --- --- --- ND ND ND ND 6.4 ND ND ND
8-Dec-15 0.46 1.0 --- --- --- ND ND ND ND 5.6 ND ND ND
3-May-16 0.46 1.0 --- --- --- ND ND ND ND 7.6 ND ND ND
13-Dec-16 0.46 1.0 --- --- --- ND ND ND ND 5.9 ND ND ND
27-Jun-17 0.46 1.0 --- --- --- ND ND ND ND 6.5 ND ND ---
Tetrahydrofuran 1-Dec-10 3.1 10.0 --- ND ND --- ND ND ND 10.1 ND ND ND
NC 2L = NE (01/01/10)1-Jun-11 3.1 10.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 3.1 10.0 --- --- ND --- ND ND ND 9.3 JD ND ND ND
30-May-12 3.1 10.0 --- --- ND --- ND ND ND 8.9 J ND ND ND
5-Dec-12 3.1 10.0 --- --- ND --- ND ND ND 6.9 J ND ND ND
12-Jun-13 3.1 10.0 --- --- ND --- ND ND ND 6.3 J ND ND ND
28-Oct-13 3.1 10.0 --- --- ND --- ND ND ND 8.6 J ND ND ND
6-May-14 3.1 10.0 --- --- ND --- ND ND ND 10.2 ND ND ND
22-Oct-14 3.1 10.0 --- --- * ND ND ND ND 7.4 J ND ND ND
21-May-15 3.1 NE --- --- --- ND ND ND ND 6.3 J ND ND ND
8-Dec-15 3.1 NE --- --- --- ND ND ND ND 9.7 J ND ND ND
3-May-16 3.1 NE --- --- --- ND ND ND ND 7.9 J ND ND ND
13-Dec-16 3.1 NE --- --- --- ND ND ND ND 9.2 J ND ND ND
27-Jun-17 3.1 10.0 --- --- --- ND ND ND ND 7.5 J ND ND ---
Toluene 1-Jan-95 --- 5.0 --- NI NI NI ND ND 19 ND NI NI ---
1-Feb-95 --- 5.0 --- NI NI NI ND ND ND ND NI NI ---
1-Mar-95 --- 5.0 ND NI NI NI ND ND ND ND NI NI ---
1-Aug-95 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---
1-Jan-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---
1-Feb-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---
1-May-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---
1-Oct-96 --- 5.0 --- NI --- --- ND ND 5 ND NI NI ---
1-May-97 --- 5.0 ND NI --- --- ND ND 2 J 3.4 J NI NI ---
1-Nov-97 --- 1.0 ND NI --- --- ND ND ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---
24-Nov-98 --- 2.0 ND NI --- --- ND ND ND ND NI NI ---
10-May-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
18-Oct-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
3-May-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 5.0 ND ND --- --- ND ND 22 15.00 ND ND ND
7-Nov-01 --- 5.0 ND ND --- --- ND ND 11 7.20 ND ND ND
22-May-02 --- 5.0 ND ND --- --- ND ND 11 17.00 ND ND ND
14-Nov-02 --- 5.0 ND ND --- --- ND ND 21 ND ND ND ND
14-May-03 --- 5.0 ND ND --- --- ND ND 8.4 86 ND ND ND
20-Nov-03 --- 5.0 ND ND --- --- ND ND 14 77 ND ND ND
6-May-04 --- 5.0 ND ND --- --- ND ND 22 54 ND ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND ND ND 35 ND ND ND
27-May-05 --- 5.0 ND ND --- --- ND ND ND 100 ND ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND ND 20 80 ND ND ND
25-May-06 ---5.0 --- ND --- --- ND ND 30.4 35.6 ND ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND ND ND 22 ND ND ND
30-May-07 --- 1.0 --- ND --- --- 0.22 B 0.3 B 27.0 30 0.58 B ND 0.44 J
NC 2L = 1,000 µg/L (10/23/07)29-Nov-07 --- 1.0 --- ND --- --- ND ND 1.5 12.0 ND ND ND
29-May-08 0.26 1.0 --- ND --- --- ND ND 3.1 12.8 5.9 ND ND
6-Nov-08 0.26 1.0 --- ND --- --- ND ND 0.7 J 23.5 0.76 J ND ND
3-Jun-09 0.26 1.0 --- ND --- --- ND ND 0.4 J 52.6 0.85 J ND ND
18-Nov-09 0.26 1.0 --- ND --- --- ND ND ND 27.2 0.55 J ND ND
NC 2L = 600 µg/L (01/01/10)16-Jun-10 0.26 1.0 --- ND --- --- ND ND 2.5 34.8 0.38 J ND ND
1-Dec-10 0.26 1.0 --- ND ND --- ND ND 4.1 17.5 ND ND ND
1-Jun-11 0.26 1.0 --- ND ND --- ND ND ND 24.7 1.1 ND ND
20-Dec-11 0.26 1.0 --- --- ND --- ND ND ND 4.9 D 0.53 J ND ND
30-May-12 0.26 1.0 --- --- ND --- ND ND ND 46.8 0.67 J ND ND
5-Dec-12 0.26 1.0 --- --- ND --- ND ND 0.33 J 10.7 0.45 J ND ND
12-Jun-13 0.26 1.0 --- --- ND --- ND ND ND 27.6 0.7 J ND ND
28-Oct-13 0.26 1.0 --- --- ND --- ND ND ND 14.6 0.5 J ND ND
6-May-14 0.26 1.0 --- --- ND --- ND ND ND 3.9 0.48 J ND ND
22-Oct-14 0.26 1.0 --- --- * ND ND ND ND 4.3 0.28 J ND ND
21-May-15 0.26 1.0 --- --- --- ND ND ND ND 4.1 ND ND ND
8-Dec-15 0.26 1.0 --- --- --- ND ND ND ND 6.0 0.31 J ND ND
3-May-16 0.26 1.0 --- --- --- ND ND ND ND 38.2 0.53 J ND ND
13-Dec-16 0.26 1.0 --- --- --- ND ND ND ND 6.8 0.28 J ND ND
27-Jun-17 0.26 1.0 --- --- --- ND ND ND ND 2.1 0.47 J ND ---
Burke County Johns River C D over MSWLF
Permit 12-03 Page 8 of 12 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
1,1,1-Trichloroethane 1-Sep-94 --- 5.0 ND NI NI NI ND 26 ND ND NI NI ---
1-Oct-94 --- 5.0 --- NI NI NI --- ND --- --- NI NI ---
1-Jan-95 --- 5.0 --- NI NI NI ND 23 ND ND NI NI ---
1-Feb-95 --- 5.0 --- NI NI NI ND 27 ND ND NI NI ---
1-Mar-95 --- 5.0 ND NI NI NI ND 28 6.5 ND NI NI ---
1-Aug-95 --- 5.0 ND NI --- --- ND 42 ND 5 NI NI ---
1-Jan-96 --- 5.0 --- NI --- --- ND 44 6 9 NI NI ---
1-Feb-96 --- 5.0 --- NI --- --- ND 31 6.7 ND NI NI ---
1-May-96 --- 5.0 --- NI --- --- ND 30 6.7 9.2 NI NI ---
1-Oct-96 --- 5.0 --- NI --- --- ND 22 5 9 NI NI ---
1-May-97 --- 5.0 16 NI --- --- 2.4 J 19 5.3 17 NI NI ---
1-Nov-97 --- 1.0 14 NI --- --- ND ND ND 14 NI NI ---
1-May-98 --- 5.0 15 NI --- --- ND 9.3 9.3 22.0 NI NI ---
24-Nov-98 --- 2.0 10.1 NI --- --- ND 4.9 3 9.3 NI NI ---
10-May-99 --- 5.0 15 ND --- --- ND ND ND 8.7 ND ND ND
18-Oct-99 --- 5.0 11 ND --- --- ND ND ND 9.2 ND ND ND
3-May-00 --- 5.0 12 ND --- --- ND ND ND 8.5 ND ND ND
7-Nov-00 --- 5.0 10 ND --- --- ND ND ND 7.3 ND ND ND
31-May-01 --- 5.0 9.8 ND --- --- ND ND ND 6.0 ND ND ND
7-Nov-01 --- 5.0 14 ND --- --- ND ND ND 7.9 ND ND ND
22-May-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
27-May-05 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND ND ND 5.0 ND ND ND
25-May-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 1.0 --- ND --- --- ND ND ND 3 ND ND ND
NC 2L = 200 µg/L (10/23/07)29-Nov-07 --- 1.0 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.48 1.0 --- ND --- --- ND ND ND 1 J ND ND ND
6-Nov-08 0.48 1.0 --- ND --- --- ND ND ND 1 J ND ND ND
3-Jun-09 0.48 1.0 --- ND --- --- ND ND ND 1 J ND ND ND
18-Nov-09 0.48 1.0 --- ND --- --- ND ND ND ND ND ND ND
16-Jun-10 0.48 1.0 --- ND --- --- ND ND ND ND ND ND ND
1-Dec-10 0.48 1.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 0.48 1.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 0.48 1.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 0.48 1.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.48 1.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 0.48 1.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 0.48 1.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 0.48 1.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 0.48 1.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.48 1.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.48 1.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.48 1.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.48 1.0 --- --- --- ND ND ND ND ND ND ND ND
27-Jun-17 0.48 1.0 --- --- --- ND ND ND ND ND ND ND ---
Trichloroethene 1-Sep-94 --- 5.0 ND NI NI NI ND 9 ND ND NI NI ---
1-Oct-94 --- 5.0 --- NI NI NI ---11 --- --- NI NI ---
1-Jan-95 --- 5.0 --- NI NI NI ND 6 ND ND NI NI ---
1-Feb-95 --- 5.0 --- NI NI NI ND 10 ND ND NI NI ---
1-Mar-95 --- 5.0 ND NI NI NI ND 12 ND ND NI NI ---
1-Aug-95 --- 5.0 ND NI --- --- ND 13 ND ND NI NI ---
1-Jan-96 --- 5.0 --- NI --- --- ND 13 ND ND NI NI ---
1-Feb-96 --- 5.0 --- NI --- --- ND 14 ND ND NI NI ---
1-May-96 --- 5.0 --- NI --- --- ND 14 ND ND NI NI ---
1-Oct-96 --- 5.0 --- NI --- --- ND 14 ND ND NI NI ---
1-May-97 --- 5.0 2 J NI --- --- ND 13 5 J ND NI NI ---
1-Nov-97 --- 1.0 2 NI --- --- ND 16 J ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- --- ND 14 13 ND NI NI ---
24-Nov-98 --- 2.0 4 NI --- --- ND 16 4 ND NI NI ---
10-May-99 --- 5.0 6 ND --- --- ND 19 5 ND ND ND ND
18-Oct-99 --- 5.0 ND ND --- --- ND 15 ND ND 5 ND ND
3-May-00 --- 5.0 5.4 ND --- --- ND 14 6 ND 6 ND ND
7-Nov-00 --- 5.0 ND ND --- --- ND 12 ND ND ND ND ND
31-May-01 --- 5.0 ND ND --- --- ND 12 7 6 5 ND ND
7-Nov-01 --- 5.0 ND ND --- --- ND 12 8 7 5 ND ND
22-May-02 --- 5.0 ND ND --- --- ND 10 9 8 ND ND ND
14-Nov-02 --- 5.0 ND ND --- ---ND 5.5 7.6 6.5 ND ND ND
14-May-03 --- 5.0 ND ND --- ---ND 11 7 12 6.8 ND ND
20-Nov-03 --- 5.0 ND ND --- ---ND 9.5 6.6 12 ND ND ND
6-May-04 --- 5.0 ND ND --- ---ND 9.1 5.8 12 ND ND ND
10-Nov-04 --- 5.0 ND ND --- ---ND 8.6 ND 11 ND ND ND
27-May-05 --- 5.0 5 ND --- ---ND 11 ND 12 ND ND ND
3-Nov-05 --- 5.0 --- ND --- ---ND 9 ND 14 ND ND ND
25-May-06 --- 5.0 --- ND --- ---ND 8.6 ND 10 ND ND ND
2-Nov-06 --- 5.0 --- ND --- ---ND 7 ND 12 ND ND ND
30-May-07 --- 1.0 --- 2 --- ---1.9 8.5 4.6 12 2.8 ND ND
NC 2L = 2.8 µg/L (10/23/07)29-Nov-07 --- 1.0 --- 1 --- ---0.45 J 3.5 2.5 9.7 1.6 ND ND
29-May-08 0.47 1.0 --- ND --- ---ND 3.5 2.9 11.9 1.4 ND ND
6-Nov-08 0.47 1.0 --- 1.3 --- ---0.53 J 3.7 3.3 11.6 1.3 ND ND
3-Jun-09 0.47 1.0 --- 1.8 --- ---ND 3.6 4.3 12.1 1.4 ND ND
18-Nov-09 0.47 1.0 --- 1.9 --- ---0.58 J 3.3 3.3 11.2 1.2 ND ND
NC 2L = 3 µg/L (01/01/10)16-Jun-10 0.47 1.0 --- 0.6 J --- ---ND 5.1 3.3 11.2 1.4 ND ND
1-Dec-10 0.47 1.0 --- 1.9 ND ---0.76 J 3.7 3.3 9.3 ND ND ND
1-Jun-11 0.47 1.0 --- 2 ND ---0.51 J 2.8 3.2 11.4 ND ND ND
20-Dec-11 0.47 1.0 --- ---ND ---0.6 J 2.5 3.5 10 D 1.1 ND ND
30-May-12 0.47 1.0 --- ---ND ---ND 2.5 2.6 11.1 0.55 J ND ND
5-Dec-12 0.47 1.0 --- ---ND ---0.53 J 2.3 3.3 11.2 0.67 J ND ND
12-Jun-13 0.47 1.0 --- ---ND ---0.66 J 2.1 1.8 11.5 0.76 J ND ND
28-Oct-13 0.47 1.0 --- ---ND ---ND 3.1 2.5 10.7 0.76 J ND ND
6-May-14 0.47 1.0 --- ---ND ---ND 2 2.6 11.9 0.6 J ND ND
22-Oct-14 0.47 1.0 --- --- * ND 0.61 J 1.3 2.2 11.4 0.86 J ND ND
21-May-15 0.47 1.0 --- --- --- ND ND 0.9 J 2.3 10.1 ND ND ND
8-Dec-15 0.47 1.0 --- --- --- ND ND 0.71 J 1.4 9.7 ND ND ND
3-May-16 0.47 1.0 --- --- --- ND 0.53 J 0.63 J 1.8 10.1 ND ND ND
13-Dec-16 0.47 1.0 --- --- --- ND 0.52 J 0.56 J 2.1 9.9 0.64 J ND ND
27-Jun-17 0.47 1.0 --- --- --- ND ND ND 1.4 10.0 0.56 J ND ---
Burke County Johns River C D over MSWLF
Permit 12-03 Page 9 of 12 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Trichlorofluoromethane 1-Oct-94 --- 5.0 --- NI NI NI --- 60 --- --- NI NI ---
1-Jan-95 --- 5.0 --- NI NI NI ND 37 ND ND NI NI ---
1-Feb-95 --- 5.0 --- NI NI NI ND 40 ND ND NI NI ---
1-Mar-95 --- 5.0 ND NI NI NI ND 48 ND ND NI NI ---
1-Aug-95 --- 5.0 ND NI --- ---ND 51 ND 9 NI NI ---
1-Jan-96 --- 5.0 --- NI --- ---ND 20 5 11 NI NI ---
1-Feb-96 --- 5.0 --- NI --- ---ND 11 6.2 7.9 NI NI ---
1-May-96 --- 5.0 --- NI --- ---ND 8.8 ND 9.1 NI NI ---
1-Oct-96 --- 5.0 --- NI --- ---ND ND ND 9 NI NI ---
1-May-97 --- 5.0 4.2 J NI --- ---ND 2.1 J 3.4 J 11 NI NI ---
1-Nov-97 --- 1.0 4 NI --- ---ND ND ND 11 NI NI ---
1-May-98 --- 5.0 ND NI --- ---ND ND ND 5 NI NI ---
24-Nov-98 --- 2.0 ND NI --- ---ND ND ND 7.6 NI NI ---
10-May-99 --- 10.0 ND ND --- ---ND ND ND ND ND ND ND
18-Oct-99 --- 5.0 ND ND --- ---ND ND ND 12 ND ND ND
3-May-00 --- 5.0 ND ND --- ---ND ND ND 9.4 ND ND ND
7-Nov-00 --- 5.0 ND ND --- ---ND ND ND 10 ND ND ND
31-May-01 --- 5.0 ND ND --- ---ND ND ND 6.5 ND ND ND
7-Nov-01 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
22-May-02 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
14-Nov-02 --- 5.0 ND ND --- ---ND ND ND 6.5 ND ND ND
14-May-03 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
20-Nov-03 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
6-May-04 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
10-Nov-04 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
27-May-05 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
3-Nov-05 --- 5.0 --- ND --- ---ND ND ND ND ND ND ND
25-May-06 --- 5.0 --- ND --- ---ND ND ND ND ND ND ND
2-Nov-06 --- 5.0 --- ND --- ---ND ND ND ND ND ND ND
30-May-07 --- 1.0 --- ND --- ---ND ND ND 4.2 ND ND ND
NC 2L = 2,100 µg/L (10/23/07) 29-Nov-07 --- 1.0 --- 0.74 J --- ---ND ND ND ND ND ND ND
29-May-08 0.2 1.0 --- 0.42 J --- ---ND ND ND ND ND ND ND
6-Nov-08 0.2 1.0 --- 0.71 J --- ---ND ND 0.24 J 1.1 ND ND ND
3-Jun-09 0.2 1.0 --- 0.38 J --- ---ND ND ND ND ND ND ND
18-Nov-09 0.2 1.0 --- 1.9 --- ---ND ND 1.6 2.1 ND ND ND
NC 2L = 2,000 µg/L (01/01/10)16-Jun-10 0.2 1.0 --- ND --- ---ND ND ND ND ND ND ND
1-Dec-10 0.2 1.0 --- 0.34 J ND ---ND ND ND 0.58 J ND ND ND
1-Jun-11 0.2 1.0 --- 0.5 J ND ---ND ND ND 0.79 J ND ND ND
20-Dec-11 0.2 1.0 --- ---ND ---ND ND ND ND ND ND ND
30-May-12 0.2 1.0 --- ---ND ---ND ND ND ND ND ND ND
5-Dec-12 0.2 1.0 --- ---ND ---ND ND ND 0.65 J ND ND ND
12-Jun-13 0.2 1.0 --- ---ND ---ND ND ND ND ND ND ND
28-Oct-13 0.2 1.0 --- ---ND ---ND ND ND ND ND ND ND
6-May-14 0.2 1.0 --- ---ND ---ND ND ND 0.3 J ND ND ND
22-Oct-14 0.2 1.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.2 1.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.2 1.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.2 1.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.2 1.0 --- --- --- ND ND ND ND ND ND ND ND
27-Jun-17 0.2 1.0 --- --- --- ND ND ND ND 0.26 J ND ND ---
Vinyl Chloride 30-May-07 0.62 1.0 --- ND --- ---ND 0.46 J 1.6 ND 3.1 ND ND
NC 2L = 0.015 µg/L (10/23/07)29-Nov-07 0.62 1.0 --- 0.42 J --- ---ND ND 1.4 ND 1.9 ND ND
29-May-08 0.62 1.0 --- ND --- ---ND ND 1.2 ND 2.2 ND ND
6-Nov-08 0.62 1.0 --- 0.63 J --- ---ND 0.68 J 1.1 ND 1.8 ND ND
3-Jun-09 0.62 1.0 --- ND --- ---ND ND 0.95 J ND 2 ND ND
18-Nov-09 0.62 1.0 --- 0.69 J --- ---ND 0.66 J 1.6 ND 2.5 ND ND
NC 2L = 0.03 µg/L (01/01/10)16-Jun-10 0.62 1.0 --- ND --- ---ND ND 1.1 ND 2.1 ND ND
1-Dec-10 0.62 1.0 --- ND ND ---ND 0.65 J 0.93 J ND 3.5 ND ND
1-Jun-11 0.62 1.0 --- ND ND ---ND 0.87 J 1.1 ND 1.8 ND ND
20-Dec-11 0.62 1.0 --- ---ND ---ND 0.63 J ND ND 1.4 ND ND
30-May-12 0.62 1.0 --- ---ND ---ND ND ND ND 1.6 ND ND
5-Dec-12 0.62 1.0 --- ---ND ---ND ND ND ND ND ND ND
12-Jun-13 0.62 1.0 --- ---ND ---ND ND 0.96 J ND 2.1 ND ND
28-Oct-13 0.62 1.0 --- ---ND ---ND ND 0.74 J ND 1.3 ND ND
6-May-14 0.62 1.0 --- ---ND ---ND ND 0.77 J ND 1.8 ND ND
22-Oct-14 0.62 1.0 --- --- * ND ND ND ND ND 1.3 ND ND
21-May-15 0.62 1.0 --- --- --- ND ND ND ND ND 1.1 ND ND
8-Dec-15 0.62 1.0 --- --- --- ND ND 0.72 J ND ND 1.4 ND ND
3-May-16 0.62 1.0 --- --- --- ND ND ND 0.74 J ND 1.2 ND ND
13-Dec-16 0.62 1.0 --- --- --- ND ND ND ND ND 0.90 J ND ND
27-Jun-17 0.62 1.0 --- --- --- ND ND 0.63 J 0.80 J ND 0.95 J ND ---
Xylene (Total)1-Sep-94 --- 5.0 ND NI NI NI ND 12 ND ND NI NI ---
1-Oct-94 --- 5.0 --- NI NI NI --- 22 --- --- NI NI ---
1-Jan-95 --- 5.0 --- NI NI NI ND 7.6 ND ND NI NI ---
1-Feb-95 --- 5.0 --- NI NI NI ND 20 ND ND NI NI ---
1-Mar-95 --- 5.0 ND NI NI NI ND 24 ND ND NI NI ---
1-Aug-95 --- 5.0 ND NI NI NI ND 5 ND ND NI NI ---
1-Jan-96 --- 5.0 --- NI --- ---ND ND ND ND NI NI ---
1-Feb-96 --- 5.0 --- NI --- ---ND ND ND ND NI NI ---
1-May-96 --- 5.0 --- NI --- ---ND ND ND ND NI NI ---
1-Oct-96 --- 5.0 --- NI --- ---ND 6 ND ND NI NI ---
1-May-97 --- 5.0 ND NI --- ---ND 9.2 4.3 J ND NI NI ---
1-Nov-97 --- 2.0 ND NI --- ---ND ND ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- ---ND 5.6 ND ND NI NI ---
24-Nov-98 --- 2.0 ND NI --- ---ND 14.8 ND ND NI NI ---
10-May-99 --- 5.0 ND ND --- ---ND 13 ND ND ND ND ND
18-Oct-99 --- 5.0 ND ND --- ---ND 14 ND ND ND ND ND
3-May-00 --- 5.0 ND ND --- ---ND 17.5 ND ND ND ND ND
7-Nov-00 --- 5.0 ND ND --- ---ND 11 ND ND ND ND ND
31-May-01 --- 5.0 ND ND --- ---ND 10 9 10 ND ND ND
7-Nov-01 --- 5.0 ND ND --- ---ND 7.9 5.3 7.6 ND ND ND
22-May-02 --- 5.0 ND ND --- ---ND 5.3 8.5 14 ND ND ND
14-Nov-02 --- 5.0 ND ND --- ---ND ND 21.3 12 ND ND ND
14-May-03 --- 5.0 ND ND --- ---ND 5.4 6.6 48 ND ND ND
20-Nov-03 --- 5.0 ND ND --- ---ND ND 7.4 50 ND ND ND
6-May-04 --- 5.0 ND ND --- ---ND ND 18.9 58 ND ND ND
10-Nov-04 --- 5.0 ND ND --- ---ND ND ND 54 ND ND ND
27-May-05 --- 5.0 11 ND --- ---ND ND 7 58 ND ND ND
3-Nov-05 --- 5.0 --- ND --- ---ND ND 26 119 ND ND ND
25-May-06 --- 5.0 --- ND --- ---ND ND 17.4 38.7 ND ND ND
2-Nov-06 --- 10.0 --- ND --- ---ND ND ND 31 ND ND ND
30-May-07 --- 4.0 --- 1.1 J --- ---ND 2 J 24 34 1.2 J ND ND
NC 2L = 530 µg/L (10/23/07)29-Nov-07 --- 5.0 --- 2.7 J --- ---ND ND 3.9 J 24 ND ND ND
29-May-08 0.89 10.0 --- 1.7 J --- ---ND 0.92 J 6.2 J 29.6 ND ND ND
6-Nov-08 0.66 2.0 --- 2.3 --- ---ND 0.78 J 2.8 28.7 ND ND ND
3-Jun-09 0.66 2.0 --- 1.6 J --- ---ND ND 4.7 46.5 ND ND ND
18-Nov-09 0.66 2.0 --- 5.7 --- ---ND ND 3.1 40.3 ND ND ND
NC 2L = 500 µg/L (01/01/10)16-Jun-10 0.66 2.0 --- 1.8 J --- ---ND 1 J 5.2 40.3 ND ND ND
1-Dec-10 0.66 2.0 --- 2.3 ND ---ND ND 5.6 42.9 ND ND ND
1-Jun-11 0.66 2.0 --- 3.6 ND ---ND ND 0.88 J 44.1 ND ND ND
20-Dec-11 0.66 2.0 --- ---ND ---ND ND 0.94 J 26.8 D ND ND ND
30-May-12 0.66 2.0 --- ---ND ---ND ND 0.7 J 53.5 ND ND ND
5-Dec-12 0.66 5.0 --- ---ND ---ND ND 2.4 J 43.6 ND ND ND
12-Jun-13 0.66 5.0 --- ---ND ---ND ND ND 48.3 ND ND ND
28-Oct-13 0.66 5.0 --- ---ND ---ND ND ND 49.3 ND ND ND
6-May-14 0.66 5.0 --- ---ND ---ND ND ND 40.7 ND ND ND
22-Oct-14 0.66 5.0 --- --- * ND ND ND ND 46.6 ND ND ND
21-May-15 0.66 5.0 --- --- --- ND ND ND ND 43.6 ND ND ND
8-Dec-15 0.66 5.0 --- --- --- ND ND ND ND 45.4 ND ND ND
3-May-16 0.66 5.0 --- --- --- ND ND ND ND 72.4 ND ND ND
13-Dec-16 0.66 5.0 --- --- --- ND ND ND ND 63.8 ND ND ND
27-Jun-17 0.66 5.0 --- --- --- ND ND ND ND 63.8 ND ND ---
Burke County Johns River C D over MSWLF
Permit 12-03 Page 10 of 12 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Diethyl phthalate 29-Nov-07 --- 10.0 --- ND --- ---1.7 J 2.3 J 2 J ND 1.3 J --- ND
#6-Nov-08 2.5 10.0 --- ND --- ---ND ND ND ND ND ND ND
NC 2L = 5,000 µg/L (10/23/07)18-Nov-09 4 10.0 --- ND --- ---ND ND ND ND ND --- ND
1-Dec-10 2.7 10.0 --- ND ND ---ND ND ND ND ND --- ND
20-Dec-11 0.58 10.0 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 0.58 6000 --- ---ND ---ND ND ND ND ND --- ND
28-Oct-13 0.58 6000 --- ---ND ---ND ND ND ND ND --- ND
22-Oct-14 0.91 6000 --- ---*NDND ND ND ND ND --- ND
8-Dec-15 1.3 6000 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16
Naphthalene 29-Nov-07 --- 10.0 --- ND --- ---ND ND ND 1.3 JD ND --- ND
#6-Nov-08 0.24 10.0 --- ND --- ---ND ND ND ND ND --- 0.67 J
NC 2L = 21 µg/L (10/23/07)18-Nov-09 0.24 10.0 --- ND --- ---ND ND ND 0.77 JD ND --- ND
1-Dec-10 4 10.0 --- ND ND ---ND ND ND 0.96 J ND --- ND
20-Dec-11 0.34 10.0 --- ---ND ---ND ND ND 0.84 JD ND --- ND
5-Dec-12 0.34 10.0 --- ---ND ---ND ND ND 1.5 B ND --- 0.46 J
28-Oct-13 0.24 10.0 --- ---ND ---ND ND ND 1.6 J ND --- ND
22-Oct-14 0.24 10.0 --- --- * ND ND ND ND 1.9 J ND --- ND
8-Dec-15 0.24 10.0 --- --- --- ND ND ND ND 2.2 J ND --- ND
13-Dec-16 0.24 10.0 --- --- --- ND ND ND ND 2.6 J ND --- 0.26 J
Pentachlorophenol 29-Nov-07 --- 25.0 --- ND --- ---ND ND ND 0.42 JD ND --- ND
#6-Nov-08 1.7 25.0 --- ND --- ---ND ND ND ND ND --- ND
NC 2L = 0.29 µg/L (10/23/07)18-Nov-09 5 50.0 --- ND --- ---ND ND ND ND ND --- ND
1-Dec-10 18 25.0 --- ND ND ---ND ND ND ND ND --- ND
20-Dec-11 4.6 25.0 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 4.6 25.0 --- ---ND ---ND ND ND ND ND --- ND
28-Oct-13 4.6 25.0 --- ---ND ---ND ND ND ND ND --- ND
22-Oct-14 1.2 25.0 --- --- * ND ND ND ND ND ND --- ND
8-Dec-15 2.3 25.0 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16 2.3 25.0 --- --- --- ND ND ND ND ND ND --- ND
alpha-BHC 1-Oct-96 --- 0.050 --- NI --- ---ND 0.07 ND ND NI NI ---
#1-May-97 --- 0.050 ND NI --- ---ND ND ND ND NI NI ---
1-Nov-97 --- 0.100 ND NI --- ---ND ND ND ND NI NI ---
1-May-98 --- 0.050 ND NI --- ---ND ND ND ND NI NI ---
24-Nov-98 --- 0.050 ND NI --- ---ND ND ND ND NI NI ---
10-May-99 --- 0.050 ND ND --- ---0.061 ND ND ND ND ND ND
18-Oct-99 --- 0.050 ND ND --- ------ ND ND ND ND ND ND
3-May-00 --- 0.050 ND ------ ---ND ND --- --- ------ ND
7-Nov-00 --- 0.050 ND ---------ND ND ND ND ND --- ND
7-Nov-01 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
14-Nov-02 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
20-Nov-03 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
10-Nov-04 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
3-Nov-05 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
2-Nov-06 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
GWPS = 0.006 µg/L (10/23/07) 29-Nov-07 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
6-Nov-08 0.05 0.050 --- ND --- ---ND ND ND ND ND --- ND
18-Nov-09 0.00031 0.010 --- ND --- ---ND ND ND ND ND --- ND
1-Dec-10 0.0003 0.050 --- ND ND ---ND ND ND ND ND --- ND
20-Dec-11 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
28-Oct-13 0.05 0.050 --- ---ND ---ND ND ND 0.19 ND --- ND
Resample >10-Dec-13 0.05 0.050 --- ------ ------ --- ---0.085 --- --- ND
6-May-14 0.05 0.050 --- ---ND ---ND ND ND 0.07 ND --- ---
22-Oct-14 0.05 0.050 --- --- * ND ND ND ND ND ND --- ND
21-May-15 0.05 0.050 --- --- --- ND ND ND ND 0.12 ND --- ND
8-Dec-15 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND
3-May-16 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16 0.05 0.050 --- --- --- ND ND ND ND 0.063 ND --- ND
27-Jun-17 0.05 0.050 --- --- --- ND ND ND ND 0.11 ND --- ---
beta-BHC 1-Dec-10 0.0005 0.050 --- ND ND ---ND ND 0.019 J ND ND --- ND
# Resample >13-Jan-11 0.0005 0.050 --- ------ ------ --- ND --- ------ ND
GWPS = 0.019 µg/L (10/23/07)20-Dec-11 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
28-Oct-13 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
22-Oct-14 0.05 0.050 --- --- * ND ND ND ND ND ND --- ND
8-Dec-15 0.05 0.050 --- --- --- ND ND 0.16 ND ND ND --- ND
Resample >4-Feb-16 0.05 0.050 --- --- --- --- ---0.33 --- --- ------ ND
3-May-16 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16 0.05 0.050 --- --- --- ND ND 0.120 ND ND ND --- ND
27-Jun-17 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ---
Delta-BHC 18-Oct-99 --- 0.050 ND ND --- ------ 0.06 J ND ND ND ND ND
#3-May-00 --- 0.050 ND ------ ---ND ND --- --- ------ ND
7-Nov-00 ---0.050 ND ------ ---ND ND ND ND ND --- ND
7-Nov-01 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
14-Nov-02 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
20-Nov-03 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
10-Nov-04 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
3-Nov-05 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
2-Nov-06 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
GWPS = 0.019 µg/L (10/23/07) 29-Nov-07 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
6-Nov-08 0.05 0.050 --- ND --- ---ND ND ND ND ND --- ND
18-Nov-09 0.00041 0.010 --- ND --- ---ND ND ND ND ND --- ND
1-Dec-10 0.0004 0.050 --- ND ND ---ND ND ND ND ND --- ND
20-Dec-11 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
28-Oct-13 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
22-Oct-14 0.05 0.050 --- --- * ND ND ND ND ND ND --- ND
8-Dec-15 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND
Gamma-BHC 18-Oct-99 --- 0.050 ND ND --- ------ 0.08 J ND ND ND ND ND
(Lindane) 3-May-00 --- 0.050 ND ------ ---ND ND --- --- --- --- ND
# 7-Nov-00 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
7-Nov-01 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
14-Nov-02 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
20-Nov-03 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
10-Nov-04 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
3-Nov-05 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
2-Nov-06 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
NC 2L = 0.2 µg/L (10/23/07) 29-Nov-07 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
6-Nov-08 0.05 0.050 --- ND --- ---ND ND ND ND ND --- ND
18-Nov-09 0.00021 0.010 --- 0.032 --- ---ND ND ND ND ND --- ND
Resample >19-Jan-10 0.00021 0.010 --- ND --- ------ --- --- --- ------ ND
1-Dec-10 0.0002 0.050 --- ND ND ---ND ND 0.034 J ND ND --- ND
Resample >13-Jan-11 0.0002 0.050 --- ------ ------ --- 0.048 J --- ------ ND
20-Dec-11 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
28-Oct-13 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
22-Oct-14 0.05 0.050 --- ---*NDND ND ND ND ND --- ND
8-Dec-15 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND
Burke County Johns River C D over MSWLF
Permit 12-03 Page 11 of 12 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Heptachlor 18-Oct-99 --- 0.050 ND ND --- ------ 0.11 J ND ND ND ND ND
# 3-May-00 --- 0.050 ND ------ ---ND ND --- --- --- --- ND
7-Nov-01 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
14-Nov-02 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
20-Nov-03 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
10-Nov-04 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
3-Nov-05 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
2-Nov-06 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
NC 2L = 0.0078 µg/L (10/23/07) 29-Nov-07 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
6-Nov-08 0.05 0.050 --- ND --- ---ND ND ND ND ND --- ND
18-Nov-09 0.0015 0.010 --- ND --- ---ND ND ND ND ND --- ND
1-Dec-10 0.0015 0.050 --- ND ND ---ND ND ND ND ND --- ND
20-Dec-11 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
28-Oct-13 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
22-Oct-14 0.05 0.050 --- --- * ND ND ND ND ND ND --- ND
8-Dec-15 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND
N-Nitroso-di-n-butylamine 22-Oct-14 1.3 10.0 --- --- --- --- 4.0 J ND ND 11.2 ND --- ND
# Resample >22-Dec-14 1.3 10.0 --- --- --- --- --- --- --- ND ------ ---
NC 2L = NE (01/01/10)8-Dec-15 2.2 10.0 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16 2.2 10.0 --- --- --- ND ND ND ND ND ND --- ND
PCB-1232 18-Oct-99 --- 2.0 4.7 ND --- ------ ND ND ND ND ND ND
#3-May-00 --- 2.0 ND ------ ---ND ND --- --- ------ ND
7-Nov-00 --- 2.0 ND ------ ---ND ND ND ND ND --- ND
7-Nov-00 --- 2.0 ND ------ ---ND ND ND ND ND --- ND
31-May-01 --- 2.0 ND ------ ------ --- --- --- ------ ND
7-Nov-01 --- 2.0 ND ------ ---ND ND ND ND ND --- ND
14-Nov-02 --- 2.0 ND ------ ---ND ND ND ND ND --- ND
20-Nov-03 --- 2.0 ND ------ ---ND ND ND ND ND --- ND
10-Nov-04 --- 1.0 ND ------ ---ND ND ND ND ND --- ND
6-May-05 --- 1.0 --- ------ ------ --- --- --- ------ ---
3-Nov-05 --- 1.0 --- ND --- ---ND ND ND ND ND --- ND
2-Nov-06 --- 1.0 --- ND --- ---ND ND ND ND ND --- ND
GWPS = 0.5 µg/L (10/23/07)29-Nov-07 --- 2.0 --- ND --- ---ND ND ND ND ND --- ND
6-Nov-08 1 NE --- ND --- ---ND ND ND ND ND --- ND
18-Nov-09 0.12 0.5 --- ND --- ---ND ND ND ND ND --- ND
GWPS = 0.09 µg/L (10/01/10)1-Dec-10 0.5 0.5 --- ND ND ---ND ND ND ND ND --- ND
20-Dec-11 0.5 0.5 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 0.5 0.5 --- ---ND ---ND ND ND ND ND --- ND
28-Oct-13 0.5 0.5 --- ---ND ---ND ND ND ND ND --- ND
22-Oct-14 0.5 0.5 --- ---*NDND ND ND ND ND --- ND
8-Dec-15 0.5 0.5 --- --- --- ND ND ND ND ND ND --- ND
2,4-D 1-Aug-95 --- 0.3 ND NI --- ---ND 0.478 ND ND NI NI ---
#1-Jan-96 --- 2.0 --- NI --- ---ND ND ND ND NI NI ---
1-Feb-96 --- 2.0 --- NI --- ---ND ND ND ND NI NI ---
1-May-96 --- 2.0 --- NI --- ---ND ND ND ND NI NI ---
1-Oct-96 --- 0.5 --- NI --- ---ND ND ND ND NI NI ---
1-Nov-97 --- 0.4 ND NI --- ---ND ND ND ND NI NI ---
24-Nov-98 --- 2.0 ND NI --- ---ND ND ND ND NI NI ---
18-Oct-99 --- 2.0 ND ND --- ------ ND ND ND ND ND ND
7-Nov-01 --- 2.0 ND ------ ---ND ND ND ND ND --- ND
14-Nov-02 --- 2.0 ND ------ ---ND ND ND ND ND --- ND
20-Nov-03 --- 2.0 ND ------ ---ND ND ND ND ND --- ND
10-Nov-04 --- 2.0 ND ------ ---ND ND ND ND ND --- ND
3-Nov-05 --- 2.0 --- ND --- ---ND ND ND ND ND --- ND
2-Nov-06 --- 2.0 --- ND --- ---ND ND ND ND ND --- ND
NC 2L = 70 µg/L (10/23/07)29-Nov-07 --- 2.0 --- ND --- ---ND 1.4 J ND ND ND --- ND
6-Nov-08 1 2.0 --- ND --- ---ND ND ND ND ND --- ND
18-Nov-09 0.22 2.0 --- ND --- ---ND ND ND ND ND --- ND
Resample >19-Jan-10 0.23 1.0 --- ND --- ------ --- --- ND ------ ND
1-Dec-10 0.22 2.0 --- ND ND ---ND ND ND ND ND --- ND
20-Dec-11 0.22 2.0 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 0.22 2.0 --- ---ND ---ND ND ND ND ND --- ND
28-Oct-13 0.22 2.0 --- ---ND ---ND ND ND ND ND --- ND
22-Oct-14 0.23 0.96 --- --- * ND ND ND ND ND ND --- ---
8-Dec-15 0.22 2.00 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16 0.22 2.00 --- --- --- ND ND ND ND ND ND --- ND
2,4,5-TP (Silvex) 13-Dec-16 0.049 2.00 --- --- --- ND ND 0.14 J ND ND ND --- ND
NC 2L = 50 µg/L (01/01/10)
4,4'-DDD 1-Dec-10 0.0019 0.10 --- ND ND ---ND 0.019 J ND ND ND --- ND
# Resample >13-Jan-11 0.0019 0.10 --- ------ ------ ND --- --- ------ ND
NC 2L = 0.1 µg/L (01/01/10)20-Dec-11 0.05 0.05 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 0.05 0.10 --- ---ND ---ND ND ND ND ND --- ND
28-Oct-13 0.05 0.10 --- ---ND ---ND ND ND ND ND --- ND
22-Oct-14 0.05 0.10 --- --- * ND ND ND ND ND ND --- ---
8-Dec-15 0.05 0.10 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16 0.05 0.10 --- --- --- ND ND ND ND ND ND --- ND
4,4'-DDE 1-Dec-10 0.0009 0.10 --- ND ND ---ND ND ND 0.019 J ND --- ND
# Resample >13-Jan-11 0.0009 0.10 --- ------ ------ --- --- 0.027 J ------ ND
NC 2L = NE (01/01/10)20-Dec-11 0.05 0.05 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 0.05 0.10 --- ---ND ---ND ND ND ND ND --- ND
28-Oct-13 0.05 0.10 --- ---ND ---ND ND ND ND ND --- ND
22-Oct-14 0.05 0.10 --- --- * ND ND ND ND ND ND --- ---
8-Dec-15 0.05 0.10 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16 0.05 0.10 --- --- --- ND ND ND ND ND ND --- ND
Notes: (Abbreviations and Referrences)
All concentrations in micrograms per liter (µg/L) = parts per billion.
# = Constituent is included on the NC Appendix II list but not on the NC Appendix I list.
--- = Not sampled for this parameter or Not reported
AB = Monitoring well abandoned.
B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination based on similar concentrations detected in field, trip, or method blanks).
D = Sample was diluted when analyzed.
DL = Laboratory Detection Limit.
GWPS = Groundwater Protection Standard set by NC-DENR-SWS for constituents with no listed NC 2L standard.
When the NC 2L Groundwater Standard has not been established, the GWPS will be used.
J = Estimated value - concentration is less than the RL but greater than the DL.
NC 2L = Groundwater Standard from 15A NCAC 2L.0202.
ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006).
NE = No NC 2L or GWPS established.
NI = Not Installed. Monitoring well not yet installed.
RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present).
Values above the NC2L Standard or GWPS are bold.
Notes: (Event Narratives)
Volatile organics (8260) for MW-9 for November 10, 2004 sampling event were unable to be analyzed and were resampled on December 1, 2004.
There was a resamplinging event on August 2, 2007 for MW-16D because the prevoius samples from the May 2007 were analyzed out of hold time. There were no detects in the resample.
* MW-21 replaced MW-20 as the background well starting with the Fall 2014 sampling event; however MW-20 continues to be sampled as a compliance well for the C&D Expansion (Phase 1A).
See the Water Quality Monitrong Report for the C&D Expansion Area for current results for MW-20.
Sample Collection Date Column displays the last day of the Respective Semiannaul Monitoring Event that samples were collected. Each individual sampling point date is preserved in the Lab Reports (Appendix A).
Burke County Johns River C D over MSWLF
Permit 12-03 Page 12 of 12 Joyce Engineering

Appendix F

Historical Detected Constituents in Performance & Sentinel Wells

APPENDIX F:
CONSTITUENTS OF CONCERN DETECTIONS
IN PERFORMANCE AND SENTINEL WELLS
Sample EPA
Analyte Collection Date Method DL RL MW-18 MW-19 MW-36 MW-38 Blanks
Organic Compounds
Benzene 18-Feb-13 0.25 1.0 ------8.0 3.8 ND
NC 2L = 6 µg/l (01/01/10)18-Jul-13 0.25 1.0 ------------ND
28-Oct-13 0.25 1.0 ND ND ------ND
6-May-14 0.25 1.0 ND ND 8.7 6.5 ND
22-Oct-14 EPA 8260 0.25 1.0 ND ND 8.3 5.9 ND
21-May-15 EPA 8260 0.25 1.0 ND ND 5.8 4.9 ND
18-Jul-13 0.33 1.0 ------------ND
28-Oct-13 0.33 1.0 ND ND ------ND
6-May-14 0.33 1.0 ND ND 10.0 13.5 ND
22-Oct-14 EPA 8260 0.33 1.0 ND ND 15.2 12.9 ND
NC 2L = 1 µg/l (02/1/15)21-May-15 EPA 8260 0.33 1.0 ND ND 18.7 12.3 ND
8-Dec-15 0.33 1.0 ------5.8 4.4 ND
3-May-16 0.33 1.0 ND ND 6.7 5.4 ND
14-Dec-16 0.33 1.0 ------5.5 3.0 ND
27-Jun-17 EPA 8260 0.33 1.0 ------20.1 12.2 J ND
cis-1,2-Dichloroethene 27-Jun-17 EPA 8260 0.2 5.0 ---------10.90 ND
1,1-Dichloroethane 3-Jun-09 0.3 5.0 3.9 J 2.8 J ------ND
18-Nov-09 0.3 5.0 6.7 3.7 J ------ND
16-Jun-10 0.3 5.0 4.4 J 2.3 J ------ND
1-Dec-10 0.3 5.0 ------------ND
1-Jun-11 0.3 5.0 2.8 J 2.6 J ------ND
20-Dec-11 0.3 5.0 ------------ND
30-May-12 0.3 5.0 1.6 J 2.7 J ------ND
5-Dec-12 0.3 5.0 ------------ND
18-Feb-13 0.32 5.0 ------7.9 9.1 ND
12-Jun-13 0.3 5.0 ------------ND
18-Jul-13 0.32 5.0 ------------ND
28-Oct-13 0.3 5.0 0.93 J 3.0 J ------ND
NC 2L = 6 µg/l (01/01/10)6-May-14 0.32 5.0 1.2 J 2.9 J 11.6 8.1 ND
22-Oct-14 EPA 8260 0.32 5.0 ------9.0 6.9 ND
21-May-15 EPA 8260 0.32 5.0 ND 1.7 J 4.8 J 5.5 ND
8-Dec-15 0.32 5.0 ------5.9 7.2 ND
3-May-16 0.32 5.0 0.4 J 2.5 J 5.9 6.5 ND
14-Dec-16 0.32 5.0 ------4.4 J 6.0 ND
27-Jun-17 EPA 8260 0.32 5.0 ------4.3 J 6.2 ND
1,2-Dichloroethane 3-Jun-09 0.1 1.0 0.33 J ND ------ND
18-Nov-09 0.1 1.0 0.56 J ND ------ND
16-Jun-10 0.1 1.0 0.37 J ND ------ND
1-Dec-10 0.1 1.0 ------------ND
1-Jun-11 0.1 1.0 0.34 J ND ------ND
20-Dec-11 0.1 1.0 ------------ND
30-May-12 0.1 1.0 ND ND ------ND
5-Dec-12 0.1 1.0 ------------ND
18-Feb-13 0.12 1.0 ------1.0 0.59 J ND
12-Jun-13 0.1 1.0 ------------ND
18-Jul-13 0.12 1.0 ------------ND
28-Oct-13 0.1 1.0 ND ND ------ND
NC 2L = 0.4 µg/l (01/01/10)6-May-14 0.12 1.0 ND ND 0.78 J ND ND
22-Oct-14 EPA 8260 0.12 1.0 ------0.92 J 0.63 J ND
21-May-15 EPA 8260 0.12 1.0 ND ND ND ND ND
8-Dec-15 0.12 1.0 ------0.66 J 0.70 J ND
3-May-16 0.12 1.0 ND ND 0.92 J 0.74 J ND
14-Dec-16 0.12 1.0 ------ND ND ND
27-Jun-17 EPA 8260 0.24 1.0 ------0.75 J 0.67 J ND
Methylene Chloride 18-Feb-13 0.97 1.0 ------17.9 ND ND
18-Jul-13 0.97 1.0 ------------ND
28-Oct-13 0.97 1.0 ND ND ------ND
NC 2L = 5 µg/l (01/01/10)6-May-14 0.97 1.0 ------24.1 1.7 2.20
22-Oct-14 EPA 8260 0.97 1.0 ------15.7 ND ND
21-May-15 EPA 8260 0.97 1.0 ND ND 9.5 B ND 1.7
8-Dec-15 0.97 1.0 ------11.2 B ND 2.0
3-May-16 0.97 1.0 ND ND 3.1 ND ND
14-Dec-16 0.97 1.0 ------ND ND ND
27-Jun-17 EPA 8260 0.97 1.0 ------ND ND ND
Sentinel Performance
Burke Co. - Johns River C+D-over-MSWLF
Permit No. 12-03
Page 1 of 2
Joyce Engineering
APPENDIX F:
CONSTITUENTS OF CONCERN DETECTIONS
IN PERFORMANCE AND SENTINEL WELLS
Sample EPA
Analyte Collection Date Method DL RL MW-18 MW-19 MW-36 MW-38 Blanks
Sentinel Performance
Tetrachloroethene 18-Feb-13 0.46 1.0 --- ---5.5 ND ND
18-Jul-13 0.46 1.0 --- --- --- --- ND
28-Oct-13 0.46 1.0 ND ND --- --- ND
NC 2L = 0.7 µg/l (10/23/07) 6-May-14 0.46 1.0 --- ---7.9 ND ND
22-Oct-14 EPA 8260 0.46 1.0 --- ---7.3 ND ND
21-May-15 EPA 8260 0.46 1.0 ND ND 6.0 ND ND
8-Dec-15 0.46 1.0 --- ---5.0 ND ND
3-May-16 0.46 1.0 ND ND 4.5 ND ND
14-Dec-16 0.46 1.0 --- --- ND ND ND
27-Jun-17 EPA 8260 0.46 1.0 --- --- ND ND ND
Tetrahydrofuran 27-Jun-17 EPA 8260 3.1 10.0 --- ------3.1 J ---
Trichloroethene 18-Feb-13 0.47 1.0 --- ---3.6 2.7 ND
18-Jul-13 0.47 1.0 --- --- --- --- ND
28-Oct-13 0.47 1.0 ND ND --- --- ND
NC 2L = 3 µg/l (01/01/10) 6-May-14 0.47 1.0 --- ---6.0 2.1 ND
22-Oct-14 EPA 8260 0.47 1.0 --- ---5.1 1.8 ND
21-May-15 EPA 8260 0.47 1.0 ND ND 3.5 0.9 J ND
8-Dec-15 0.47 1.0 --- --- 2.9 2.1 ND
3-May-16 0.47 1.0 ND ND 3.1 1.7 ND
14-Dec-16 0.47 1.0 --- --- ND 1.8 ND
27-Jun-17 EPA 8260 0.47 1.0 --- --- ND 0.30 J ND
Vinyl chloride 18-Feb-13 0.62 1.0 --- ---1.2 ND ND
18-Jul-13 0.62 1.0 --- --- --- --- ND
28-Oct-13 0.62 1.0 ND ND --- --- ND
NC 2L = 0.03 µg/l (01/01/10) 6-May-14 0.62 1.0 --- ---1.1 ND ND
22-Oct-14 EPA 8260 0.62 1.0 --- --- 0.9 J ND ND
21-May-15 EPA 8260 0.62 1.0 ND ND ND ND ND
8-Dec-15 0.62 1.0 --- --- 0.80 J ND ND
3-May-16 0.62 1.0 ND ND 0.80 J 1.8 ND
Resample >9-Jun-16 0.62 1.0 --- --- --- ND ND
14-Dec-16 0.62 1.0 --- --- --- ND ND
27-Jun-17 EPA 8260 0.62 1.0 --- --- 0.6 J 1.9 ND
Resample >8-Aug-17 EPA 8260 0.62 1.0 --- --- --- 0.87 J ---
Notes:
All concentrations in micrograms per liter (µg/l) = parts per billion.
DL = Laboratory Detection Limit.
RL = SWSL = Solid Waste Section Reporting Limit.
NC 2L = Groundwater Standard from 15A NCAC 2L.0202.
GWPS = Groundwater Protection Standard set by NC-DENR-SWS for constituents with no listed NC 2L.
nle = No longer exists (MW-34 was accidentaly destroyed during construciton activties).
--- = Not reported or not monitored.
Italics = Constituent of Concern (COC).
Resample > indicates results of a verification sample event.
For MW-36 and MW-38, only COC's are reported in this Appendix. Additional constituents required for the Phase 1A area are included in the Semiannual Groundwater Monitoring
Report for Phase 1A.
Burke Co. - Johns River C+D-over-MSWLF
Permit No. 12-03
Page 2 of 2
Joyce Engineering

Appendix G

Historical Detected Surface Water Constituents

APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Inorganic Compounds
Antimony 6-Nov-08 2.6 6.0 ND 8.4 ---ND
3-Jun-09 2.6 6.0 ND ND --- ND
18-Nov-09 2.6 6.0 ND ND --- ND
NC 2B = NE (05/01/07) 15-Jun-10 2.6 6.0 ND ND --- ND
1-Dec-10 2.6 6.0 ND ND --- ND
1-Jun-11 2.6 6.0 ND ND --- ND
20-Dec-11 5.0 6.0 ND ND --- ND
30-May-12 5.0 6.0 ND ND --- ND
5-Dec-12 5.0 6.0 ND ND --- ND
12-Jun-13 5.0 6.0 ND ND --- ND
28-Oct-13 5.0 6.0 ND ND --- ND
6-May-14 5.0 6.0 ND ND --- ND
22-Oct-14 5.0 6.0 --- ND ND ND
21-May-15 3.8 6.0 ND ND ND ND
9-Dec-15 3.8 6.0 ND ND ND ND
NC 2B = 5.6 µg/l (03/01/16) 4-May-16 3.8 6.0 ND ND ND ND
14-Dec-16 3.8 6.0 ND ND ND ND
28-Jun-17 3.9 6.0 ND ND ND ---
Arsenic 6-Nov-08 2.7 10.0 2.9 B 4.5 B ---4.1 J
3-Jun-09 2.7 10.0 ND 4.5 J --- ND
18-Nov-09 2.7 10.0 ND ND --- ND
NC 2B = 10 µg/l (05/01/07) 15-Jun-10 2.7 10.0 ND ND --- ND
1-Dec-10 2.7 10.0 ND ND --- ND
1-Jun-11 2.7 10.0 ND ND --- ND
20-Dec-11 5.0 10.0 ND ND --- ND
30-May-12 5.0 10.0 ND ND --- ND
5-Dec-12 5.0 10.0 ND ND --- ND
12-Jun-13 5.0 10.0 ND ND --- ND
28-Oct-13 5.0 10.0 ND ND --- ND
6-May-14 5.0 10.0 ND ND --- ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 10 µg/l (03/01/16) 4-May-16 2.5 10.0 3.0 J ND 3.3 J ND
14-Dec-16 2.5 10.0 ND ND ND ND
28-Jun-17 5.0 10.0 ND 5.5 J ND ---
Barium 30-May-07 --- 100 81.3 J 23.8 J ---0.2 J
29-Nov-07 --- 100 116 27.5 J --- 0.50 J
29-May-08 0.2 100 71.9 J 19.6 J --- ND
6-Nov-08 0.20 100 82.5 J 40.2 B --- 9.6 J
3-Jun-09 0.20 100 104 36.2 B --- 15.9 J
18-Nov-09 0.20 100 49.9 B 15.7 B --- 20.1 J
NC 2B = 1,000 µg/l (05/01/07) 15-Jun-10 0.20 100 47.6 J 20.7 J --- 0.77 J
1-Dec-10 0.20 100 39.8 J 46.8 J --- ND
1-Jun-11 0.20 100 51.6 J 19.9 J --- ND
20-Dec-11 5.0 100 63.7 J 13.9 J --- ND
30-May-12 5.0 100 16.9 J 22.0 J --- ND
5-Dec-12 5.0 100 69.9 J 24.8 J --- ND
12-Jun-13 5.0 100 54.9 B 40.0 B ---13.6 J
28-Oct-13 5.0 100 35.4 J 20.8 J --- ND
6-May-14 5.0 100 37.0 J 17.8 J --- ND
22-Oct-14 5.0 100 --- 25.5 J 19.8 J ND
21-May-15 2.5 100 53.0 J 14.6 J 21.6 J ND
9-Dec-15 2.5 100 26.1 J 23.4 J 27.8 J ND
NC 2B = 1,000 µg/l (03/01/16) 4-May-16 2.5 100 41.4 J 37.3 J 51.0 J ND
14-Dec-16 2.5 100 44.7 J 21.2 J 17.5 J ND
28-Jun-17 2.5 100 46.3 J 41.4 J 31.5 J ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 1 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Beryllium 14-Nov-02 --- 2 2.0 B 2.2 B ---2.1
14-May-03 --- 2 ND ND ---ND
20-Nov-03 --- 2 ND ND ---ND
6-May-04 --- 2 ND ND ---ND
10-Nov-04 --- 2 ND ND ---ND
5-May-05 --- 2 ND ND ---ND
3-Nov-05 --- 2 ND ND ---ND
25-May-06 --- 2 ND ND ---ND
2-Nov-06 --- 2 ND ND ---ND
30-May-07 --- 1 ND ND ---ND
29-Nov-07 --- 1 ND ND ---ND
29-May-08 0.10 1.0 ND ND ---ND
6-Nov-08 0.10 1.0 0.24 B 0.37 B ---0.29 J
3-Jun-09 0.10 1.0 0.64 J 0.21 J ---ND
18-Nov-09 0.10 1.0 ND ND ---ND
NC 2B = 6.5 µg/l (05/01/07)15-Jun-10 0.10 1.0 ND ND ---ND
1-Dec-10 0.10 1.0 ND ND ---ND
1-Jun-11 0.10 1.0 ND ND ---ND
20-Dec-11 1.0 1.0 ND ND ---ND
30-May-12 1.0 1.0 ND ND ---ND
5-Dec-12 1.0 1.0 ND ND ---ND
12-Jun-13 1.0 1.0 ND ND ---ND
28-Oct-13 1.0 1.0 ND ND ---ND
6-May-14 1.0 1.0 ND ND ---ND
22-Oct-14 1.0 1.0 --- ND ND ND
21-May-15 0.5 1.0 ND ND ND ND
9-Dec-15 0.5 1.0 ND ND ND ND
NC 2B = 6.5 µg/l Chronic (03/01/16)*4-May-16 0.5 1.0 ND ND ND ND
14-Dec-16 0.5 1.0 ND ND ND ND
28-Jun-17 0.5 1.0 ND ND ND ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 2 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Cadmium 7-Nov-01 --- 1 ND 1.0 ---ND
22-May-02 --- 1 ND 1.7 B ---1.3
14-Nov-02 --- 1 ND ND ---ND
14-May-03 --- 1 ND ND ---ND
20-Nov-03 --- 1 ND ND ---ND
6-May-04 --- 1 ND ND ---ND
10-Nov-04 --- 1 ND ND ---ND
5-May-05 --- 1 ND ND ---ND
3-Nov-05 --- 1 ND ND ---ND
25-May-06 --- 1 ND ND ---ND
2-Nov-06 --- 1 ND ND ---ND
30-May-07 --- 1 ND ND ---ND
29-Nov-07 --- 1 ND ND ---ND
29-May-08 0.5 1.0 ND ND ---ND
6-Nov-08 0.50 1.0 ND ND ---ND
3-Jun-09 0.50 1.0 ND ND ---ND
18-Nov-09 0.50 1.0 ND ND ---ND
NC 2B = 2 µg/l (05/01/07)15-Jun-10 0.50 1.0 ND ND ---ND
1-Dec-10 0.50 1.0 ND ND ---ND
1-Jun-11 0.50 1.0 ND ND ---ND
20-Dec-11 1.0 1.0 ND ND ---ND
30-May-12 1.0 1.0 ND ND ---ND
5-Dec-12 1.0 1.0 ND ND ---ND
12-Jun-13 1.0 1.0 ND ND ---ND
28-Oct-13 1.0 1.0 ND ND ---ND
6-May-14 1.0 1.0 ND ND ---ND
22-Oct-14 1.0 1.0 --- ND ND ND
21-May-15 0.5 1.0 ND ND ND ND
9-Dec-15 0.5 1.0 ND ND ND ND
NC 2B = 0.15 µg/l Chronic (03/01/16)*4-May-16 0.5 1.0 ND ND ND ND
14-Dec-16 0.5 1.0 ND ND ND ND
28-Jun-17 0.5 1.0 ND ND ND ---
Chromium, total 6-Nov-08 0.40 10.0 ND 0.47 J ---ND
3-Jun-09 0.40 10.0 7.5 J 3.2 J ---ND
18-Nov-09 0.40 10.0 ND ND ---ND
NC 2B = 50 µg/l (05/01/07)15-Jun-10 0.40 10.0 1.2 B 0.48 B ---0.74 J
1-Dec-10 0.40 10.0 0.68 B 5.1 J --- 0.51 J
1-Jun-11 0.40 10.0 0.59 B 0.59 B ---0.73 J
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 ND ND ---ND
12-Jun-13 5.0 10.0 ND ND ---ND
28-Oct-13 5.0 10.0 ND ND ---ND
6-May-14 5.0 10.0 ND ND ---ND
22-Oct-14 5.0 10.0 --- ND 9.7 J ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 11 µg/l Chronic (03/01/16)*4-May-16 2.5 10.0 4.7 J 4.6 J 8.8 J ND
14-Oct-16 2.5 10.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 3 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Cobalt 22-May-02 --- 10 14.0 17.0 ---11.0
14-Nov-02 --- 10 ND ND ---ND
14-May-03 --- 10 ND 10.0 ---ND
20-Nov-03 --- 10 14.0 ND ---ND
6-May-04 --- 10 ND ND ---ND
10-Nov-04 --- 10 10.0 ND ---ND
5-May-05 --- 10 10.0 ND ---ND
3-Nov-05 --- 10 16.0 ND ---ND
25-May-06 --- 10 12 ND ---ND
2-Nov-06 --- 10 13.6 ND ---ND
30-May-07 --- 10 12.3 8.8 J ---ND
29-Nov-07 --- 10 19.0 2.1 J ---ND
29-May-08 0.60 10.0 13.7 ND ---ND
6-Nov-08 0.60 10.0 12.6 ND ---0.65 J
3-Jun-09 0.60 10.0 11.9 B 6.6 B ---7.6 J
18-Nov-09 0.60 10.0 3.6 J 4.6 J ---ND
NC 2B = NE (05/01/07)15-Jun-10 0.60 10.0 6.4 J 22.3 ---ND
1-Dec-10 0.60 10.0 0.76 J 4.1 J ---ND
1-Jun-11 0.60 10.0 2.0 J 1.7 J ---ND
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 29.0 7.7 J ---ND
12-Jun-13 5.0 10.0 ND 9.1 J ---ND
28-Oct-13 5.0 10.0 11.5 12.4 ---ND
6-May-14 5.0 10.0 ND ND ---ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 6.3 J ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 3 µg/l (03/01/16)4-May-16 2.5 10.0 4.0 J 5.6 J 3.3 J ND
14-Dec-16 2.5 10.0 5.9 J ND ND ND
28-Jun-17 2.5 10.0 6.4 J 3.6 J ND ---
Copper 29-May-08 0.30 10.0 ND 1.3 B --- 0.37 J
6-Nov-08 4.0 10.0 0.45 B 3.4 J --- 0.65 J
3-Jun-09 0.30 10.0 6.6 J 2.1 J ---ND
18-Nov-09 0.30 10.0 ND ND ---ND
NC 2B = 7 µg/l (05/01/07)15-Jun-10 0.30 10.0 0.56 B ND ---0.77 J
1-Dec-10 0.30 10.0 3.6 J 5.9 J ---ND
1-Jun-11 0.30 10.0 1.8 J 0.35 J ---ND
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 ND ND ---ND
12-Jun-13 5.0 10.0 5.2 B ND ---9.8 J
28-Oct-13 5.0 10.0 ND ND ---ND
6-May-14 5.0 10.0 ND ND ---ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 2.7 µg/l Chronic (3/1/16)*4-May-16 2.5 10.0 4.6 J 5.5 J 11 ND
resample 17-May-16 2.5 10.0 ------ ND ND
14-Dec-16 2.5 10.0 ND ND ND ND
28-Jun-17 2.5 10.0 ND ND ND ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 4 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Lead 3-Jun-09 4.0 10.0 7.3 J ND ---ND
18-Nov-09 4.0 10.0 ND ND ---ND
NC 2B = 25 µg/l (05/01/07)15-Jun-10 4.0 10.0 ND ND ---ND
1-Dec-10 4.0 10.0 ND 4.6 J ---ND
1-Jun-11 4.0 10.0 ND ND ---ND
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 ND ND ---ND
12-Jun-13 5.0 10.0 ND ND ---ND
28-Oct-13 5.0 10.0 ND ND ---ND
6-May-14 5.0 10.0 ND ND ---ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 14 µg/l Acute, 0.54 µg/l Chronic *4-May-16 2.5 10.0 ND 4.9 J 7.2 J ND
14-Dec-16 2.5 10.0 ND ND ND ND
28-Jun-17 2.5 10.0 ND ND ND ---
Nickel 3-Jun-09 1.7 50.0 5.5 B ND ---1.7 J
18-Nov-09 1.7 50.0 ND ND ---ND
NC 2B = 25 µg/l (05/01/07)15-Jun-10 1.7 50.0 ND ND ---ND
1-Dec-10 1.7 50.0 2.8 J 2.8 J ---ND
1-Jun-11 1.7 50.0 ND ND ---2.3 J
20-Dec-11 5.0 50.0 ND ND ---ND
30-May-12 5.0 50.0 ND ND ---ND
5-Dec-12 5.0 50.0 ND ND ---ND
12-Jun-13 5.0 50.0 ND ND ---ND
28-Oct-13 5.0 50.0 ND ND ---ND
6-May-14 5.0 50.0 ND ND ---ND
22-Oct-14 5.0 50.0 --- ND ND ND
21-May-15 2.5 50.0 ND ND ND ND
9-Dec-15 2.5 50.0 ND ND ND ND
NC 2B = 16 µg/l Chronic (03/01/16)*4-May-16 2.5 50.0 3.8 J 3.9 J 6.7 J ND
14-Dec-16 2.5 50.0 ND ND ND ND
28-Jun-17 2.5 50.0 ND ND 8.0 J ---
Selenium 6-Nov-08 3.8 10 ND 10.9 ---ND
3-Jun-09 3.8 10.0 ND ND ---ND
18-Nov-09 3.8 10.0 ND ND ---ND
NC 2B = 5 µg/l (05/01/07)15-Jun-10 3.8 10.0 ND ND ---ND
1-Dec-10 3.8 10.0 ND ND ---ND
1-Jun-11 3.8 10.0 ND ND ---ND
20-Dec-11 10.0 10.0 ND ND ---ND
30-May-12 10.0 10.0 ND ND ---ND
5-Dec-12 10.0 10.0 ND ND ---ND
12-Jun-13 10.0 10.0 ND ND ---ND
28-Oct-13 10.0 10.0 ND ND ---ND
6-May-14 10.0 10.0 ND ND ---ND
22-Oct-14 10.0 10.0 --- ND ND ND
21-May-15 5.0 10.0 ND ND ND ND
9-Dec-15 5.0 10.0 ND ND ND ND
NC 2B = 5 µg/l (03/01/16)4-May-16 5.0 10.0 ND ND ND ND
14-Dec-16 5.0 10.0 ND ND ND ND
28-Jun-17 5.0 10.0 ND ND ND ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 5 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Silver 22-May-02 --- 10 16.0 B 15.0 B ---15.0
14-Nov-02 --- 10 ND ND ---ND
14-May-03 --- 10 ND ND ---ND
20-Nov-03 --- 10 ND ND ---ND
6-May-04 --- 10 ND ND ---ND
10-Nov-04 --- 10 ND ND ---ND
5-May-05 --- 10 ND ND ---ND
3-Nov-05 --- 10 ND ND ---ND
25-May-06 --- 10 ND ND ---ND
2-Nov-06 --- 10 ND ND ---ND
30-May-07 --- 10 ND ND ---ND
29-Nov-07 --- 10 ND ND ---ND
29-May-08 0.10 10.0 0.29 J 0.13 J ---ND
6-Nov-08 0.10 10.0 0.72 B 0.38 B ---0.23 J
3-Jun-09 0.10 10.0 0.18 B ND ---0.31 J
18-Nov-09 0.10 10.0 0.27 B 0.23 B --- 0.23 J
NC 2B = 0.06 µg/l (05/01/07)15-Jun-10 0.10 10.0 ND ND ---ND
1-Dec-10 0.10 10.0 ND ND ---ND
1-Jun-11 0.10 10.0 ND 0.22 J ---ND
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 ND ND ---ND
12-Jun-13 5.0 10.0 ND ND ---ND
28-Oct-13 5.0 10.0 ND ND ---ND
6-May-14 5.0 10.0 ND ND ---ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 0.06 µg/l Chronic (03/01/16)*4-May-16 2.5 10.0 ND ND ND ND
14-Dec-16 2.5 10.0 ND ND ND ND
28-Jun-17 2.5 10.0 ND ND ND ---
Thallium 5-May-05 --- 10 22.0 11.0 ---ND
3-Nov-05 --- 10 20.0 ND ---ND
25-May-06 --- 10 ND ND ---ND
2-Nov-06 --- 10 ND ND ---ND
30-May-07 --- 5.5 0.053 J ND ---ND
29-Nov-07 --- 5.5 0.055 J ND ---ND
29-May-08 3.0 5.5 ND ND ---ND
6-Nov-08 3.0 5.5 ND ND ---ND
3-Jun-09 3.0 5.5 ND ND ---ND
18-Nov-09 3.0 5.5 ND ND ---4.2 J
NC 2B = NE (05/01/07)15-Jun-10 3.0 5.5 3.2 J ND ---ND
1-Dec-10 3.0 5.5 ND ND ---4.0 J
1-Jun-11 3.0 5.5 ND ND ---ND
20-Dec-11 5.4 5.5 ND ND ---ND
30-May-12 5.4 5.5 ND ND ---ND
5-Dec-12 5.4 5.5 ND ND ---ND
12-Jun-13 5.4 5.5 ND ND ---ND
28-Oct-13 5.4 5.5 ND ND ---ND
6-May-14 5.4 5.5 ND ND ---ND
22-Oct-14 5.4 5.5 --- ND ND ND
21-May-15 5.0 5.5 ND ND ND ND
9-Dec-15 5.0 5.5 ND ND ND ND
NC 2B = 0.24 (03/01/16)4-May-16 5.0 5.5 ND ND ND ND
14-Dec-16 5.0 5.5 ND ND ND ND
28-Jun-17 0.0 5.5 ND ND 0.044 J ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 6 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Vanadium 6-Nov-08 0.20 25.0 0.90 B 8.9 B ---2.1 J
3-Jun-09 0.20 25.0 17.4 J 7.5 J ---1.0 J
18-Nov-09 0.20 25.0 0.26 B 0.30 B ---0.56 J
NC 2B = NE (05/01/07)15-Jun-10 0.20 25.0 1.5 B 1.0 B ---0.98 J
1-Dec-10 0.20 25.0 1.1 J 13.7 J ---ND
1-Jun-11 0.20 25.0 1.1 J 0.74 J ---ND
20-Dec-11 5.0 25.0 ND ND ---ND
30-May-12 5.0 25.0 ND ND ---ND
5-Dec-12 5.0 25.0 ND ND ---ND
12-Jun-13 5.0 25.0 7.6 J ND ---ND
28-Oct-13 5.0 25.0 ND ND ---ND
6-May-14 5.0 25.0 ND ND ---ND
22-Oct-14 5.0 25.0 --- ND ND ND
21-May-15 2.5 25.0 7.5 J ND 4.1 J ND
9-Dec-15 2.5 25.0 ND ND 3.9 J ND
4-May-16 2.5 25.0 10.9 J 11.4 J 23.9 J ND
14-Dec-16 2.5 25.0 ND ND ND ND
28-Jun-17 2.5 25.0 ND ND 3.1 J ---
Zinc 30-May-07 --- 10 1.8 B ND ---1.6 J
29-Nov-07 --- 10 9.6 B ND ---3.1 J
29-May-08 0.40 10.0 6.0 B ND ---3.0 J
6-Nov-08 0.40 10.0 0.82 B 1.4 B ---2.7 J
3-Jun-09 0.40 10.0 33.7 B 9.6 B ---82.0
18-Nov-09 0.40 10.0 2.2 B 2.5 B ---3.1 J
NC 2B = 50 µg/l (05/01/07)15-Jun-10 0.40 10.0 ND ND ---ND
1-Dec-10 0.40 10.0 8.8 J 6.6 J ---0.62 J
1-Jun-11 0.40 10.0 15.1 B 21.5 B ---13.7
20-Dec-11 10.0 10.0 ND ND ---ND
30-May-12 10.0 10.0 ND ND ---ND
5-Dec-12 10.0 10.0 ND ND ---ND
12-Jun-13 10.0 10.0 ND ND ---76.5
28-Oct-13 10.0 10.0 ND ND ---ND
6-May-14 10.0 10.0 ND ND ---ND
22-Oct-14 10.0 10.0 --- ND ND ND
21-May-15 5.0 10.0 ND 5.8 J ND ND
9-Dec-15 5.0 10.0 ND ND ND ND
NC 2B = 36 mg/l (03/01/16)4-May-16 5.0 10.0 8.7 J 7.7 J 15.2 ND
14-Dec-16 5.0 10.0 ND ND 6.9 J ND
28-Jun-17 5.0 10.0 5.8 J 17.4 39.4 ---
Hardness, Total (SM 2340B)28-Jun-17 662.00 662.0 32,900 20,900 10,800 ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 7 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Organic Compounds
Acetone 29-Nov-07 --- 100 3.6 B ND --- 5.1 J
29-May-08 20 100 ND ND --- ND
6-Nov-08 20 100 ND ND --- ND
3-Jun-09 2.2 100 5.7 J ND --- ND
18-Nov-09 2.2 100 ND ND --- ND
NC 2B = NE (05/01/07) 15-Jun-10 2.2 100 2.2 B 2.3 B --- 7.2 J
1-Dec-10 2.2 100 ND ND --- 3.7 J
1-Jun-11 2.2 100 5.4 B 2.9 B --- 3.9 J
20-Dec-11 2.2 100 ND ND --- ND
30-May-12 2.2 100 ND ND --- ND
5-Dec-12 10.0 100 ND ND --- ND
12-Jun-13 10.0 100 ND ND --- ND
28-Oct-13 10.0 100 ND ND --- ND
6-May-14 10.0 100 ND ND --- ND
22-Oct-14 10.0 100 --- ND ND ND
21-May-15 10.0 100 ND ND ND ND
9-Dec-15 10.0 100 ND ND ND ND
NC 2B = 1,100 mg/l (03/01/16) 4-May-16 10.0 100 ND ND ND ND
14-Dec-16 10.0 100 ND ND ND ---
28-Jun-17 10.0 100 14.7 B 29.4 B 18.0 B 35.5 J
Benzene 28-Jun-17 0.25 1.0 ND 0.59 J ND ND
Chloromethane 15-Jun-10 0.11 1.0 ND 0.11 J --- ND
NC 2B = NE (05/01/07) 1-Dec-10 0.11 1.0 ND ND --- ND
1-Jun-11 0.11 1.0 ND ND --- ND
20-Dec-11 0.11 1.0 ND ND --- ND
30-May-12 0.11 1.0 ND ND --- ND
5-Dec-12 0.11 1.0 ND ND --- ND
12-Jun-13 0.11 1.0 ND ND --- ND
28-Oct-13 0.11 1.0 ND ND --- ND
6-May-14 0.11 1.0 ND ND --- ND
22-Oct-14 0.11 1.0 --- ND ND ND
21-May-15 0.11 1.0 ND ND ND ND
9-Dec-15 0.11 1.0 ND ND ND ND
NC 2B = NE (03/01/16) 4-May-16 0.11 1.0 ND ND ND ND
14-Dec-16 0.11 1.0 ND ND ND ---
28-Jun-17 0.11 1.0 0.46 J 0.65 J 0.50 J ---
Trichloroethene 14-Dec-16 0.47 1.0 ND 0.52 J ND ---
NC 2B = 30 µg/l (03/01/16) 28-Jun-17 0.47 1.0 ND 1.1 ND ---
1,1-Dichloroethane 1-Jun-11 0.32 5.0 ND 0.41 J --- ND
NC 2B = NE (05/01/07) 20-Dec-11 0.32 5.0 ND ND --- ND
30-May-12 0.32 5.0 ND ND --- ND
5-Dec-12 0.32 5.0 ND 1.6 J --- ND
12-Jun-13 0.32 5.0 ND ND --- ND
28-Oct-13 0.32 5.0 ND 0.96 J --- ND
6-May-14 0.32 5.0 ND ND --- ND
22-Oct-14 0.32 5.0 --- 1.5 J ND ND
21-May-15 0.32 5.0 ND ND ND ND
9-Dec-15 0.32 5.0 ND ND ND ND
NC 2B = 0.38 µg/l (03/01/16) 4-May-16 0.32 5.0 ND ND ND ND
14-Dec-16 0.32 5.0 ND 2.6 J ND ---
28-Jun-17 0.32 5.0 ND 4.2 J ND ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 8 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
cis-1,2-Dichloroethene 22-Oct-14 0.2 5.0 --- 0.20 J ND ND
NC 2B = NE (05/15/13)21-May-15 0.2 5.0 ND ND ND ND
9-Dec-15 0.2 5.0 ND ND ND ND
NC 2B = 60 µg/l (03/01/16)4-May-16 0.2 5.0 ND ND ND ND
14-Dec-16 0.2 5.0 ND 0.43 J ND ---
28-Jun-17 0.2 5.0 ND 1.10 J ND ---
Notes:
All concentrations in micrograms per liter (µg/l) = parts per billion.
RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006;
and SWSL for December 2006 - present).
DL = Laboratory Detection Limit.
NI = Monitoring well not yet installed.
AB = Monitoring well abandoned.
--- = Not sampled for this parameter or Not reported
ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006).
J = Estimated value - concentration is less than the RL but greater than the DL.
B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination based on
similar concentrations detected in field, trip, or method blanks).
D = Sample was diluted when analyzed.
NC 2B = Groundwater Standard from 15A NCAC 2B.
NE = No NC 2B established.
Values above the NC 2B Standard are bold.
Surface waters classified as WS-IV (water supply IV, highly developed), B (primary recreation, fresh water), and CA (critical area).
based on dissolved metal and in-stream water hardness results. Site specific values may be calculated based on water hardness at time of sampling.
*NC 2B Groundwater Standards and Protective Values updated March 2016 to include acute and chronic exposure levels for designated metals
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 9 of 9
Joyce Engineering

Appendix H

Historical MNA Parameters

APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
Temperature (FP)11/3/2006 oC 14.90 NS NS 15.25 16.97 16.52 NI NI
6/3/2009 oC 15.90 NS NS 19.10 19.40 14.50 16.20 16.30
11/17/2009 oC 12.0 NS NS 13.9 15.9 13.7 13.8 12.0
6/16/2010 oC 16.06 NS NS 17.65 17.8 17.69 18.83 16.3
12/1/2010 oC 13.43 NU NS 11.17 12.27 14.1 14.4 14.6
6/1/2011 oC 17.21 NU NS 18.39 17.59 21.68 15.04 16.57
12/20/2011 oC NS 14.30 NS 14.52 14.30 14.69 NS NS
5/30/2012 oC NS 18.18 NS 21.70 20.80 16.90 16.99 17.26
12/5/2012 oC NS 15.40 NS 15.00 15.50 16.90 NS NS
6/12/2013 oC NS 18.10 NS 18.70 18.20 16.30 NS NS
10/28/2013 oC NS 17.70 NS 18.40 18.20 17.50 17.40 17.10
5/6/2014 oC NS 16.90 NS 22.40 21.00 18.00 14.90 14.50
10/23/2014 oC NS * 17.20 13.00 11.50 9.80 NS NS
5/21/2015 oC NS 17.80 19.80 18.70 22.20 18.60 18.10 25.50
12/8/2015 oC NS 16.20 15.20 15.40 16.10 16.90 NS NS
5/3/2016 oC NS 17.5 17.9 17.0 18.4 17.2 13.7 15.8
12/13/2016 oC NS 14.1 14.4 14.9 14.9 14.8 NS NS
5/23/2017 oC NS 16.4 15.0 16.8 17.0 16.8 NS NS
pH (FP)11/3/2006 S.U. 5.34 NS NS 5.32 5.40 5.68 NI NI
6/3/2009 S.U. 5.79 NS NS 5.74 5.62 5.96 6.20 6.28
11/17/2009 S.U. 6.03 NS NS 5.92 5.49 6.08 5.84 6.24
6/16/2010 S.U. 6.23 NS NS 6.37 6.28 5.64 6.28 6.05
12/1/2010 S.U. 5.40 NU NS 6.10 6.10 6.05 6.52 6.36
6/1/2011 S.U. 5.83 NU NS 6.01 5.96 5.87 6.25 6.24
12/20/2011 S.U. NS 6.12 NS 5.98 5.90 6.01 NS NS
5/30/2012 S.U. NS 6.61 NS 5.74 5.57 5.61 5.84 5.76
12/5/2012 S.U. NS 5.41 NS 6.12 5.93 5.75 NS NS
6/12/2013 S.U. NS 5.92 NS 6.00 5.32 5.57 NS NS
10/28/2013 S.U. NS 6.89 NS 5.85 5.88 5.76 6.12 6.22
5/6/2014 S.U. NS 5.37 NS 5.46 5.69 5.74 5.41 5.74
10/23/2014 S.U. NS * 5.52 5.80 5.64 5.41 NS NS
5/21/2015 S.U. NS 6.18 5.29 6.03 6.25 5.88 6.09 6.19
12/8/2015 S.U. NS 6.09 5.13 6.06 5.81 5.66 NS NS
5/3/2016 S.U. NS 19.70 4.83 5.54 5.34 5.06 5.30 5.29
12/13/2016 S.U. NS 6.45 5.17 6.05 6.22 5.77 NS NS
6/27/2017 S.U. NS 5.98 6.45 6.06 5.99 5.95 NS NS
Specific Conductance (FP)11/3/2006 µS/cm 59 NS NS 133 95 207 NI NI
6/3/2009 µS/cm 139.5 NS NS 258 146.2 286 220 329
11/17/2009 µS/cm 182.7 NS NS 279 146.9 245 218 330
6/16/2010 µS/cm 124 NS NS 310 214 213 216 309
12/1/2010 µS/cm 143 NU NS 235 133 160 292 310
6/1/2011 µS/cm 69 NU NS 384 175 293 241 392
12/20/2011 µS/cm NS 26 NS 314 152 229 NS NS
5/30/2012 µS/cm NS 26.0 NS 392.0 177.0 229.0 227.0 256.0
12/5/2012 µS/cm NS 19.5 NS 370.1 148.8 197.4 NS NS
6/12/2013 µS/cm NS 29.8 NS 345.2 201.7 201.7 NS NS
10/28/2013 µS/cm NS 24.5 NS 430.0 189.5 229.9 215.6 295.2
5/6/2014 µS/cm NS 30.1 NS 460.7 208.5 230.4 179.0 276.9
10/23/2014 µS/cm NS * 68.1 311.0 170.2 103.8 NS NS
5/21/2015 µS/cm NS 19.8 27.2 435.4 221.5 231.2 262.0 412.2
12/8/2015 µS/cm NS 24.1 15.5 400.6 203.4 208.5 NS NS
5/3/2016 µS/cm NS 19.7 16.0 473.5 247.0 221.0 292.0 256.9
12/13/2016 µS/cm NS 66.0 180.4 458 198 215 NS NS
6/27/2017 µS/cm NS 19.7 28.9 450.1 234.6 226.1 NS NS
Background Downgradient Sentinel
Burke Co.- Johns River C and D-over-MSWLF
Permit No. 12-03 Page 1 of 10
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
ORP (FP)11/3/2006 mV 93.8 NS NS 143.9 90.5 43.2 NI NI
6/3/2009 mV 195.0 NS NS 150.0 130.0 138.0 132.0 113.0
11/17/2009 mV 167.0 NS NS 133.0 162.0 132.0 158.0 128.0
6/16/2010 mV 13.8 NS NS -12.5 -58.6 -73.4 -36.8 -63.5
12/1/2010 mV 31.6 NU NS -49.1 -74.7 -105.9 NS NS
6/1/2011 mV 73.2 NU NS 28.6 -7.2 40.1 10.3 -2.6
12/20/2011 mV NS 56.8 NS 18.7 30.3 3.9 NS NS
5/30/2012 mV NS 7.1 NS -14.8 38.9 21.7 26.70 20.10
12/5/2012 mV NS 227.2 NS -6.9 46.0 23.4 NS NS
6/12/2013 mV NS 104.7 NS -38.0 29.6 86.4 NS NS
10/28/2013 mV NS 21.7 NS -10.5 53.2 47.3 -7.20 5.40
5/6/2014 mV NS 116.5 NS 21.0 29.7 228.0 94.20 33.90
10/23/2014 mV NS * 104.6 -2.3 -3.8 36.6 NS NS
5/21/2015 mV NS 61.80 136.8 21.9 66.0 46.9 66.00 12.50
12/8/2015 mV NS 148.80 269.9 -21.4 -6.2 25.7 NS NS
5/3/2016 mV NS 81.70 80.4 14.1 29.3 57.3 29.9 45.7
12/13/2016 mV NS 217.40 180.4 29.0 18.1 70.9 NS NS
6/27/2017 mV NS 152.20 184.2 5.3 10.7 20.5 NS NS
Turbidity (FP)11/3/2006 ntu 10.4 NS NS 7.97 64.0 16.3 NI NI
6/3/2009 ntu 154 NS NS 20.6 7.54 39.1 390 125
11/17/2009 ntu 318 NS NS 19.65 7.89 23.0 <100 22.2
6/16/2010 ntu 44.8 NS NS 165 95.9 43.2 14.9 9.29
12/1/2010 ntu 20.2 NU NS 31 46.4 43.1 >1000 463
6/1/2011 ntu 7.58 NU NS 19.06 13.14 5.74 33.4 59.6
12/20/2011 ntu NS 80.4 NS 46.30 36.70 24.80 NS NS
5/30/2012 ntu NS 14.0 NS 19.80 33.50 15.90 20.60 27.30
12/5/2012 ntu NS 631 NS 19.50 23.50 7.14 NS NS
6/12/2013 ntu NS 21.3 NS 10.82 15.80 8.11 NS NS
10/28/2013 ntu NS 7.39 NS 8.30 6.41 4.31 4.62 14.30
5/6/2014 ntu NS 37.1 NS 12.95 6.05 4.29 37.00 9.20
10/23/2014 ntu NS * 8.15 21.7 10.04 7.55 NS NS
5/21/2015 ntu NS 27.10 8.15 12.6 17.50 7.72 9.10 11.13
12/8/2015 ntu NS 55.60 25.5 16.7 35.40 30.50 NS NS
5/3/2016 ntu NS 29.20 17.55 19.75 16.88 18.30 21.30 28.10
12/13/2016 ntu NS 17.55 12.63 9.48 10.20 9.70 NS NS
6/27/2017 ntu NS 15.20 12.20 7.29 9.78 11.60 NS NS
Dissolved Oxygen (FP)11/3/2006 mg/l 4.01 NS NS 0.95 1.21 1.10 NI NI
6/3/2009 mg/l 1.21 NS NS 0.84 0.57 0.99 1.38 0.60
11/17/2009 mg/l NS NS NS 2.35 4.12 3.50 2.23 3.20
6/16/2010 mg/l 4.61 NS NS 2.49 2.86 2.10 3.59 4.16
12/1/2010 mg/l 7.94 NU NS 1.29 1.29 5.15 NS NS
6/1/2011 mg/l 4.76 NU NS 2.46 1.77 1.64 3.80 3.27
12/20/2011 mg/l NS 8.18 NS 1.87 2.17 2.17 NS NS
5/30/2012 mg/l NS 6.24 NS 3.67 6.33 1.98 8.47 8.11
12/5/2012 mg/l NS 7.29 NS 2.09 3.57 0.99 NS NS
6/12/2013 mg/l NS 8.68 NS 1.53 1.25 1.75 NS NS
10/28/2013 mg/l NS 7.14 NS 3.42 2.47 2.82 3.62 3.21
5/6/2014 mg/l NS 7.83 NS 1.89 1.47 1.33 2.25 1.86
10/23/2014 mg/l NS * 5.74 2.78 1.36 2.75 NS NS
5/21/2015 mg/l NS 0.10 5.66 1.01 1.79 0.01 1.01 0.10
12/8/2015 mg/l NS 7.53 7.59 4.62 2.47 1.49 NS NS
5/3/2016 mg/l NS 9.55 7.26 1.60 2.23 3.35 4.19 2.20
12/13/2016 mg/l NS 7.69 5.41 5.11 3.23 2.07 NS NS
6/27/2017 mg/l NS 8.98 7.06 2.40 4.75 2.16 NS NS
Burke Co.- Johns River C and D-over-MSWLF
Permit No. 12-03 Page 2 of 10
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
Carbon Dioxide (FP)11/3/2006 mg/l NS NS NS NS NS NS NI NI
6/3/2009 mg/l 170 NS NS 295 255 325 185 315.00
11/17/2009 mg/l 220 NS NS 355 335 385 NS 280
6/16/2010 mg/l 220 NS NS 510 395 430 185 280
12/1/2010 mg/l 25 NU NS 440 285 230 NS NS
6/1/2011 mg/l NS NU NS NS NS NS NS NS
12/20/2011 mg/l NS NS NS NS NS NS NS NS
5/30/2012 mg/l NS NS NS NS NS NS NS NS
12/5/2012 mg/l NS NS NS NS NS NS NS NS
6/12/2013 mg/l NS 25.0 NS 80 95 90 NS NS
10/28/2013 mg/l NS 25.0 NS 335 240 130 160 130
5/6/2014 mg/l NS NS NS NS NS NS NS NS
10/23/2014 mg/l NS * NS NS NS NS NS NS
5/21/2015 mg/l NS NS NS NS NS NS NS NS
12/8/2015 mg/l NS NS NS NS NS NS NS NS
5/3/2016 mg/l NS NS 30 95 85 155 220 150
12/13/2016 mg/l NS NS NS NS NS NS NS NS
6/27/2017 mg/l NS NS NS NS NS NS NS NS
Iron II (ferrous iron) (FP)11/3/2006 mg/l NS NS NS 0.5 6.4 7.5 NI NI
6/3/2009 mg/l 0.0 NS NS 5.9 9.5 9.4 7.2 9.4
11/17/2009 mg/l 0.0 NS NS 5.0 6.8 4.0 4.0 6.0
6/16/2010 mg/l 6.5 NS NS 8.0 6.5 4.0 5.0 8.8
12/1/2010 mg/l 0.0 NU NS 6.2 4.6 10.0 NS NS
6/1/2011 mg/l NS NU NS NS NS NS NS NS
12/20/2011 mg/l NS 0.0 NS 6.1 4.5 5.6 NS NS
5/30/2012 mg/l NS 0.0 NS 5.6 3.8 5.2 3.20 3.30
12/5/2012 mg/l NS 0.0 NS 5.2 4.0 6.3 NS NS
6/12/2013 mg/l NS 0.0 NS 6.0 4.2 3.0 NS NS
10/28/2013 mg/l NS 0.0 NS 5.5 9.0 4.8 6.5 6.0
5/6/2014 mg/l NS 0.0 NS 7.3 4.3 5.8 5.0 5.8
10/23/2014 mg/l NS * 0.0 4.5 7.0 3.75 NS NS
5/21/2015 mg/l NS NS 0.0 5.8 7.0 7.0 4.7 5.8
12/8/2015 mg/l NS NS 0.0 3.5 2.0 3.2 NS NS
5/3/2016 mg/l NS NS 0.8 4.5 5.0 3.5 3.4 4.0
12/13/2016 mg/l NS NS 0.5 5.2 3.0 2.2 NS NS
6/27/2017 mg/l NS NS 1.0 4.0 0.5 1.5 NS NS
Nitrate 11/3/2006 mg/l NS NS NS <0.5 <0.5 <0.5 NI NI
6/3/2009 mg/l <0.1 NS NS <0.1 <0.1 <0.1 <0.1 0.26
11/17/2009 mg/l <0.1 NS NS <0.1 <0.1 <0.1 <0.1 <0.1
6/16/2010 mg/l <0.1 NS NS <0.1 <0.1 <0.1 <0.1 <0.1
12/1/2010 mg/l <0.1 NU NS <0.1 <0.1 <0.1 NS NS
6/1/2011 mg/l <0.1 NU NS <0.1 <0.1 <0.1 <0.1 <0.1
12/20/2011 mg/l NS <0.1 NS <0.1 <0.1 <0.1 NS NS
5/30/2012 mg/l NS .207 J NS <0.1 <0.1 <0.1 <0.1 <0.1
12/5/2012 mg/l NS .294 J NS <0.1 <0.1 <0.1 NS NS
6/12/2013 mg/l NS .384 J NS <0.1 <0.1 <0.1 NS NS
10/28/2013 mg/l NS .333 J NS <0.1 <0.1 <0.1 <0.1 <0.1
5/6/2014 mg/l NS .282 J NS <0.1 <0.1 <0.1 <0.1 <0.1
10/23/2014 mg/l NS * <0.1 <0.1 <0.1 <0.1 NS NS
5/21/2015 mg/l NS <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
12/8/2016 mg/l NS NS .256 J <0.1 <0.1 <0.1 NS NS
5/3/2016 mg/l NS NS 0.120 J ND ND ND <0.1 <0.1
12/13/2016 mg/l NS NS 0.210 J ND ND ND NS NS
6/27/2017 mg/l NS NS .201 J ND ND ND NS NS
Burke Co.- Johns River C and D-over-MSWLF
Permit No. 12-03 Page 3 of 10
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
Alkalinity 11/3/2006 mg/l NS NS NS 47 36 106 NI NI
6/3/2009 mg/l 163 NS NS 112 62.5 76.6 80.8 128
11/17/2009 mg/l 70.8 NS NS 121 50.0 83.3 81.2 115
6/16/2010 mg/l 61.2 NS NS 154 59.1 111 74.7 185
12/1/2010 mg/l 35.2 NU NS 156 86.9 64.4 NS NS
6/1/2011 mg/l 45.1 NU NS 177 70.7 109 84.6 132
12/20/2011 mg/l NS 8.58 NS 189 70.8 77.2 NS NS
5/30/2012 mg/l NS 8.14 NS 200 76.7 104 107.0 150.0
12/5/2012 mg/l NS 7.69 NS 178 76.6 106 NS NS
6/12/2013 mg/l NS 7.95 NS 202 111 99.7 NS NS
10/28/2013 mg/l NS 8.14 NS 197 91.3 116 NS NS
5/6/2014 mg/l NS 8.06 NS 208 90.6 119 68.90 113.0
10/23/2014 mg/l NS * 1.36 J 215 96.1 122 NS NS
5/21/2015 mg/l NS 6.54 ND 153.000 67.500 92.100 51.300 154.000
12/8/2015 mg/l NS 8.280 1.030 J 202.000 88.800 95.900 NS NS
5/3/2016 mg/l NS NS 1.370 J 122.000 49.000 76.800 62.500 100.000
12/13/2016 mg/l NS 6.190 1.190 J 106.000 45.600 77.600 NS NS
6/27/2017 mg/l NS ND ND 165.000 98.700 99.100 NS NS
Chloride 11/3/2006 mg/l NS NS NS 9.30 1.69 2.49 NI NI
6/3/2009 mg/l <5.0 NS NS 16.1 <5.0 6.7 5.9 <5.0
11/17/2009 mg/l <5.0 NS NS 16.8 <5.0 <5.0 6.8 <5.0
6/16/2010 mg/l <5.0 NS NS 5.45 6.29 8.55 8.23 <5.0
12/1/2010 mg/l <5.0 NU NS 15.1 6.84 <5.0 NS NS
6/1/2011 mg/l <5.0 NU NS 17.0 6.33 7.87 9.45 <5.0
12/20/2011 mg/l NS <5.0 NS 20.2 6.40 6.53 NS NS
5/30/2012 mg/l NS 1.48 NS 20.0 6.32 5.84 133.0 2.79
12/5/2012 mg/l NS 2.13 NS 19.5 7.29 7.43 NS NS
6/12/2013 mg/l NS 1.38 NS 19.5 7.50 5.1 NS NS
10/28/2013 mg/l NS 1.12 NS 18.1 7.75 8.49 NS NS
5/6/2014 mg/l NS ND NS 18.2 8.14 8.92 13.50 2.41
10/23/2014 mg/l NS * ND 20.8 9.05 8.12 NS NS
5/21/2015 mg/l NS 1.550 ND 25.300 9.680 10.400 12.400 2.500
12/8/2015 mg/l NS 1.840 0.859 J 30.800 9.400 4.190 NS NS
5/3/2016 mg/l NS NS 6.07 33.700 14.000 7.980 13.600 7.150
12/13/2016 mg/l NS 1.460 1.330 30.300 10.700 8.240 NS NS
6/27/2017 mg/l NS NS ND 11.500 29.700 10.400 NS NS
Sulfate 11/3/2006 mg/l NS NS NS 3.72 <2 <2 NI NI
6/3/2009 mg/l <5.1 NS NS <5.0 <5.0 <5.0 5.8 ND
11/17/2009 mg/l <5.0 NS NS <5.0 <5.0 <5.0 <5.0 <5.0
6/16/2010 mg/l <5.0 NS NS <5.0 <5.0 <5.0 <5.0 <5.0
12/1/2010 mg/l <2.5 NU NS <12.5 <12.5 <12.5 NS NS
6/1/2011 mg/l <5.0 NU NS <5.0 <5.0 <5.0 <5.0 <5.0
12/20/2011 mg/l NS <5.0 NS <5.0 <5.0 <5.0 NS NS
5/30/2012 mg/l NS <5.0 NS <5.0 <5.0 <5.0 <5.0 <5.0
12/5/2012 mg/l NS ND NS ND 4.4 J ND NS NS
6/12/2013 mg/l NS ND NS 3.08 J 2.91 J ND NS NS
10/28/2013 mg/l NS ND NS ND 2.94 J ND NS NS
5/6/2014 mg/l NS ND NS 2.30 J 3.72 J 2.07 J ND 2.49 J
10/23/2014 mg/l NS * ND 2.28 J 3.74 J 1.94 J NS NS
5/21/2015 mg/l NS ND ND 2.310 J 3.440 J 2.750 J 1.700 J 1.980 J
12/8/2015 mg/l NS ND ND 1.530 J 2.020 J 9.260 J NS NS
5/3/2016 mg/l NS 1.270 J 1.090 J 5.490 J 3.440 J 8.720 J 2.900 J 3.020 J
12/13/2016 mg/l NS 1.530 J ND ND 4.020 J 10.700 J NS NS
6/27/2017 mg/l NS ND ND 2.20 J 3.20 J ND NS NS
Burke Co.- Johns River C and D-over-MSWLF
Permit No. 12-03 Page 4 of 10
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
Sulfide 11/3/2006 mg/l NS NS NS 3.72 <2 <2 NI NI
6/3/2009 mg/l <0.10 NS NS <0.10 <0.10 <0.10 <0.10 ND
11/17/2009 mg/l <0.10 NS NS <0.10 <0.10 <0.10 NS NS
6/16/2010 mg/l <0.10 NS NS <0.10 <0.10 <0.10 <0.10 <0.10
12/1/2010 mg/l <0.10 NU NS <0.10 <0.10 <0.10 NS NS
6/1/2011 mg/l NS NU NS NS NS NS NS NS
12/20/2011 mg/l NS NS NS NS NS NS NS NS
5/30/2012 mg/l NS NS NS NS NS NS NS NS
12/5/2012 mg/l NS ND NS ND ND ND NS NS
6/12/2013 mg/l NS ND NS ND ND ND NS NS
10/28/2013 mg/l NS ND NS ND ND ND ND ND
5/6/2014 mg/l NS NS NS NS NS NS NS NS
10/23/2014 mg/l NS * ND ND ND ND NS NS
5/21/2015 mg/l NS NS NS NS NS NS NS NS
12/8/2015 mg/l NS NS ND ND ND ND NS NS
5/3/2016 mg/l NS NS ND ND ND ND ND ND
12/13/2016 mg/l NS NS ND ND ND ND NS NS
6/27/2017 mg/l NS NS ND ND ND ND NS NS
Methane 11/3/2006 mg/l NS NS NS 2.23 2.50 2.92 NI NI
6/3/2009 mg/l 0.340 NS NS 0.111 8.61 8.26 0.494 0.814
11/17/2009 mg/l 2.580 NS NS 4.310 0.147 10.300 1.200 0.271
Resample 1/19/2010 mg/l NS NS NS NS 2.120 NS NS NS
6/16/2010 mg/l 0.750 NS NS 4.600 6.000 6.200 1.000 1.100
12/1/2010 mg/l 1.35 NU NS 3.04 6.0 6.65 NS NS
6/1/2011 mg/l 2.1 NU NS 0.157 0.0128 <0.010 0.899 2.64
12/20/2011 mg/l NS <0.005 NS 1.460 6.300 5.650 NS NS
5/30/2012 mg/l NS 0.0061 NS 0.883 6.130 3.760 0.46 0.718
12/5/2012 mg/l NS ND NS 2.070 2.050 4.910 NS NS
6/12/2013 mg/l NS 0.0063 NS 0.964 8.900 11.400 NS NS
10/28/2013 mg/l NS ND NS .0033 J 2.610 0.173 0.0581 0.0085
5/6/2014 mg/l NS ND NS 2.040 6.190 4.360 0.3850 1.5900
10/23/2014 mg/l NS * 5.93 2.21 ND 5.61 NS NS
5/21/2015 mg/l NS 0.0018 J 0.0012 J 2.270 6.700 4.940 0.136 3.060
12/8/2015 mg/l NS NS 0.0020 J 0.959 0.796 7.510 NS NS
5/3/2016 mg/l NS NS 0.0014 J 1.880 5.350 5.160 0.457 0.514
12/13/2016 mg/l NS NS NS 3.050 8.940 17.300 NS NS
6/27/2017 mg/l NS NS .00194 D6 3.150 16.600 12.500 NS NS
Ethane 11/3/2006 mg/l NS NS NS <0.002 <0.002 <0.002 NI NI
6/3/2009 mg/l <0.005 NS NS <0.005 <0.005 <0.005 <0.005 <0.005
11/17/2009 mg/l <0.005 NS NS <0.005 <0.005 <0.005 <0.005 <0.005
Resample 1/19/2010 mg/l NS NS NS NS <0.005 NS NS NS
6/16/2010 mg/l <0.013 NS NS <0.013 <0.011 <0.011 <0.013 <0.013
12/1/2010 mg/l <0.0022 NU NS <0.0022 <0.0022 <0.0022 NS NS
6/1/2011 mg/l NS NU NS NS NS NS NS NS
12/20/2011 mg/l NS NS NS NS NS NS NS NS
5/30/2012 mg/l NS NS NS NS NS NS NS NS
12/5/2012 mg/l NS NS NS NS NS NS NS NS
6/12/2013 mg/l NS ND NS ND ND ND NS NS
10/28/2013 mg/l NS ND NS .0016 J ND ND ND ND
5/6/2014 mg/l NS NS NS NS NS NS NS NS
10/23/2014 mg/l NS * NS NS NS NS NS NS
5/21/2015 mg/l NS NS NS NS NS NS NS NS
12/8/2016 mg/l NS NS NS NS NS NS NS NS
5/3/2016 mg/l NS NS ND ND ND ND ND ND
12/13/2016 mg/l NS NS ND ND ND ND NS NS
6/27/2017 mg/l NS NS ND ND ND ND NS NS
Burke Co.- Johns River C and D-over-MSWLF
Permit No. 12-03 Page 5 of 10
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
Ethylene (Ethene)11/3/2006 mg/l NS NS NS <0.002 <0.002 <0.002 NI NI
6/3/2009 mg/l <0.005 NS NS <0.005 <0.005 <0.005 <0.005 <0.005
11/17/2009 mg/l <0.005 NS NS <0.005 <0.005 <0.005 <0.005 <0.005
Resample 1/19/2010 mg/l NS NS NS NS <0.005 NS NS NS
6/16/2010 mg/l <0.013 NS NS <0.013 <0.011 <0.011 <0.013 <0.013
12/1/2010 mg/l <0.0018 NU NS <0.0018 <0.0018 <0.0018 NS NS
6/1/2011 mg/l NS NU NS NS NS NS NS NS
12/20/2011 mg/l NS NS NS NS NS NS NS NS
5/30/2012 mg/l NS NS NS NS NS NS NS NS
12/5/2012 mg/l NS NS NS NS NS NS NS NS
6/12/2013 mg/l NS ND NS ND ND ND NS NS
10/28/2013 mg/l NS ND NS .0017 J ND ND ND ND
5/6/2014 mg/l NS NS NS NS NS NS NS NS
10/23/2014 mg/l NS * NS NS NS NS NS NS
5/21/2015 mg/l NS NS NS NS NS NS NS NS
12/8/2015 mg/l NS NS NS NS NS NS NS NS
5/3/2016 mg/l NS NS ND ND ND ND ND ND
12/13/2016 mg/l NS NS ND ND ND ND NS NS
6/27/2017 mg/l NS NS ND ND ND ND NS NS
Dissolved Hydrogen 11/3/2006 nM NS NS NS NS NS NS NI NI
6/3/2009 nM 0.480 J NS NS 0.720 <0.600 0.350 J 0.580 J 0.790
11/17/2009 nM 0.780 NS NS 0.850 0.690 1.000 1.200 0.630
6/16/2010 nM 4.800 NS NS 3.400 2.800 2.200 2.800 3.300
12/1/2010 nM 1.500 NU NS 0.850 0.740 0.950 NS NS
6/1/2011 nM 2.300 NU NS 2.400 1.900 2.200 2.100 2.000
12/20/2011 nM NS 21 NS 19 6.3 7.0 NS NS
5/30/2012 nM NS 0.74 NS 2.0 1.1 0.84 0.79 0.76
12/5/2012 nM NS 1.7 NS 0.5 J 0.35 J 0.57 J NS NS
6/12/2013 nM NS 1.1 NS 1.1 0.83 1.60 NS NS
10/28/2013 nM NS 0.61 NS 0.61 0.55 J 0.52 J 0.56 J 0.68
5/6/2014 nM NS 0.61 NS 0.82 1.1 J 1.1 J 0.61 3.50
10/23/2014 nM NS * 0.75 0.86 0.85 1.2 NS NS
5/21/2015 nM NS NS 1.7 1.3 1.1 1.6 1.6 1.2
12/8/2016 nM NS NS 2.0 1.6 2.3 1.9 NS NS
5/3/2016 nM NS NS 0.97 0.86 0.82 0.77 0.80 0.80
12/13/2016 nM NS NS 1.9 2.0 1.5 1.3 NS NS
6/27/2017 nM NS NS 2.0 1.7 2.0 2.0 NS NS
Volatile Fatty Acids 11/3/2006 mg/l NS NS NS NS NS NS NI NI
6/3/2009 mg/l 10.9 NS NS 0.5 J ND ND ND ND
11/17/2009 mg/l 0.9 J NS NS ND 0.6 J ND 0.9 J ND
6/16/2010 mg/l ND NS NS 32.0 ND 1.3 0.8 J 5.2
12/1/2010 mg/l ND NU NS ND ND 6.4 J NS NS
6/1/2011 mg/l NS NU NS NS NS NS NS NS
12/20/2011 mg/l NS NS NS NS NS NS NS NS
5/30/2012 mg/l NS NS NS NS NS NS NS NS
12/5/2012 mg/l NS NS NS NS NS NS NS NS
6/12/2013 mg/l NS ND NS ND ND ND NS NS
10/28/2013 mg/l NS ND NS ND ND ND ND ND
5/6/2014 mg/l NS NS NS NS NS NS NS NS
10/23/2014 mg/l NS * NS NS NS NS NS NS
5/21/2015 mg/l NS NS NS NS NS NS NS NS
12/8/2015 mg/l NS NS NS NS NS NS NS NS
5/3/2016 mg/l NS NS ND ND ND ND ND ND
12/13/2016 mg/l NS NS ND ND ND ND NS NS
6/27/2017 mg/l NS NS ND ND ND ND NS NS
Burke Co.- Johns River C and D-over-MSWLF
Permit No. 12-03 Page 6 of 10
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
TOC 11/3/2006 mg/l NS NS NS NS NS NS NI NI
6/3/2009 mg/l 9.4 NS NS 11.1 10.1 17.8 8.6 14.2
11/17/2009 mg/l 2.1 NS NS 13.1 12.6 14.6 3.9 11.4
6/16/2010 mg/l 24.9 NS NS 12.9 8.66 11.1 6.4 16.8
12/1/2010 mg/l 17.6 NU NS 29.3 23.4 43.8 NS NS
6/1/2011 mg/l NS NU NS NS NS NS NS NS
12/20/2011 mg/l NS 6.53 NS 13.6 12.2 16.1 NS NS
5/30/2012 mg/l NS 6.49 NS 12.5 12.1 14.5 6.55 10.90
12/5/2012 mg/l NS ND NS 13.1 13.1 16.0 NS NS
6/12/2013 mg/l NS ND NS 13.3 12.9 18.3 NS NS
10/28/2013 mg/l NS ND NS 15.3 12.9 15.2 7.5 14.7
5/6/2014 mg/l NS ND NS 17.6 12.0 19.9 9.54 11.3
10/23/2014 mg/l NS * 27.0 35.7 66.4 33.2 NS NS
5/21/2015 mg/l NS ND ND 4.410 4.580 3.880 2.530 8.580
12/8/2016 mg/l NS ND ND 5.320 -- 6.070 NS NS
5/3/2016 mg/l NS NS 0.528 J 4.330 2.380 6.080 2.010 3.520
12/13/2016 mg/l NS NS 0.70 J 4.0 3.7 3.6 NS NS
6/27/2017 mg/l NS NS ND 2.98 2.17 2.74 NS NS
Tetrachloroethene (PCE) 11/3/2006 µg/l ND NS NS ND ND ND NI NI
6/3/2009 µg/l 2.1 NS NS ND 0.70 J ND ND ND
11/17/2009 µg/l 2.6 NS NS ND 0.49 J ND ND ND
6/16/2010 µg/l 1.2 NS NS ND 0.46 J ND ND ND
12/1/2010 µg/l 3.0 NU NS ND ND ND NS NS
6/1/2011 µg/l 3.6 NU NS ND ND ND ND ND
12/20/2011 µg/l NS ND NS 0.59 J 0.70 J ND NS NS
5/30/2012 µg/l NS ND NS ND ND ND ND ND
12/5/2012 µg/l NS ND NS ND ND ND NS NS
6/12/2013 µg/l NS ND NS ND ND ND NS NS
10/28/2013 µg/l NS ND NS ND ND ND ND ND
5/6/2014 µg/l NS ND NS ND ND ND ND ND
10/23/2014 µg/l NS * ND ND ND ND NS NS
5/21/2015 µg/l NS ND ND ND ND ND ND ND
12/8/2016 µg/l NS ND ND ND ND ND NS NS
5/3/2016 µg/l NS NS ND ND ND ND ND ND
12/13/2016 µg/l NS NS ND ND ND ND NS NS
6/27/2017 µg/l NS NS ND ND ND ND NS NS
Trichloroethene (TCE) 11/3/2006 µg/l ND NS NS ND ND ND NI NI
6/3/2009 µg/l 1.8 NS NS 3.6 4.3 1.4 ND ND
11/17/2009 µg/l 1.9 NS NS 3.3 3.3 1.2 ND ND
6/16/2010 µg/l 0.61 J NS NS 5.1 3.3 1.4 ND ND
12/1/2010 µg/l 1.9 NU NS 3.7 3.3 ND NS NS
6/1/2011 µg/l 2.0 NU NS 2.8 3.2 ND ND ND
12/20/2011 µg/l NS ND NS 2.5 3.5 1.1 NS NS
5/30/2012 µg/l NS ND NS 2.5 2.6 0.55 J ND ND
12/5/2012 µg/l NS ND NS 2.3 3.3 0.67 J NS NS
6/12/2013 µg/l NS ND NS 2.1 1.8 0.76 J NS NS
10/28/2013 µg/l NS ND NS 3.1 2.5 0.76 J ND ND
5/6/2014 µg/l NS ND NS 2.0 2.6 0.60 J ND ND
10/23/2014 µg/l NS * ND 1.3 2.2 0.86 J NS NS
5/21/2015 µg/l NS ND ND 0.9 J 2.3 ND ND ND
12/8/2016 µg/l NS ND ND 0.71 J 1.4 ND NS NS
5/3/2016 µg/l NS NS ND 0.63 J 1.8 ND ND ND
12/13/2016 µg/l NS NS ND 0.56 J 2.1 0.64 J NS NS
6/27/2017 µg/l NS NS ND ND 1.4 0.56 J NS NS
Burke Co.- Johns River C and D-over-MSWLF
Permit No. 12-03 Page 7 of 10
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
1,2-Dichloroethene (DCE) 11/3/2006 µg/l ND NS NS 16 12 17 NI NI
(Total including all isomers) 6/3/2009 µg/l 0.71 J NS NS 13.3 12.1 10.6 3.9 J ND
11/17/2009 µg/l 2.8 J NS NS 12.5 20.3 11.1 NS NS
6/16/2010 µg/l 1.7 J NS NS 14.9 15.6 9.9 4.5 J ND
12/1/2010 µg/l 0.66 J NU NS 11.5 9.3 7.4 NS NS
6/1/2011 µg/l 0.66 J NU NS 14.6 13.9 5.7 4.6 J ND
12/20/2011 µg/l NS ND NS 9.7 9.8 6.6 NS NS
5/30/2012 µg/l NS ND NS 11.8 11.2 6.8 ND ND
12/5/2012 µg/l NS ND NS 9.1 10.07 6.6 NS NS
6/12/2013 µg/l NS ND NS 9.0 12.8 6.2 NS NS
10/28/2013 µg/l NS ND NS 11.2 14.0 7.7 NS NS
5/6/2014 µg/l NS ND NS 9.5 13.0 7.7 NS NS
10/23/2014 µg/l NS * ND 8.0 10.1 7.1 NS NS
5/21/2015 µg/l NS ND ND 6.7 7.6 4.2 NS NS
12/8/2015 µg/l NS ND ND 0.65 J ND 1.3 NS NS
5/3/2016 µg/l NS NS ND 5.9 9.6 4.6 1.5 J ND
12/13/2016 µg/l NS NS ND 5.7 9.8 6.1 NS NS
6/27/2017 µg/l NS NS ND 5.8 9.0 5.4 NS NS
Vinyl Chloride (VC) 11/3/2006 µg/l ND NS NS ND ND ND NI NI
6/3/2009 µg/l ND NS NS ND 0.95 J 2.0 ND ND
11/17/2009 µg/l 0.69 J NS NS 0.66 J 1.6 2.5 ND ND
6/16/2010 µg/l ND NS NS ND 1.1 2.1 ND ND
12/1/2010 µg/l ND NU NS 0.65 J 0.93 J 3.5 NS NS
6/1/2011 µg/l ND NU NS 0.87 J 1.1 1.8 ND ND
12/20/2011 µg/l NS ND NS 0.63 J ND 1.4 NS NS
5/30/2012 µg/l NS ND NS ND ND 1.6 ND ND
12/5/2012 µg/l NS ND NS ND ND ND NS NS
6/12/2013 µg/l NS ND NS ND 0.96 J 2.10 NS NS
10/28/2013 µg/l NS ND NS ND 0.74 J 1.3 ND ND
5/6/2014 µg/l NS ND NS ND 0.77 J 1.8 ND ND
10/23/2014 µg/l NS * ND ND ND 1.3 NS NS
5/21/2015 µg/l NS ND ND ND ND 1.1 ND ND
12/8/2015 µg/l NS 0.72 J ND ND ND 1.4 NS NS
5/3/2016 µg/l NS NS ND ND 0.74 J 1.2 ND ND
12/13/2016 µg/l NS NS ND ND ND 0.9 J NS NS
6/27/2017 µg/l NS NS ND 0.63 J 0.80 J 0.95 J NS NS
1,1,1-Trichloroethane 11/3/2006 µg/l ND NS NS ND ND ND NI NI
(TCA) 6/3/2009 µg/l ND NS NS ND ND ND ND ND
11/17/2009 µg/l ND NS NS ND ND ND ND ND
6/16/2010 µg/l ND NS NS ND ND ND ND ND
12/1/2010 µg/l ND NU NS ND ND ND NS NS
6/1/2011 µg/l ND NU NS ND ND ND ND ND
12/20/2011 µg/l NS ND NS ND ND ND NS NS
5/30/2012 µg/l NS ND NS ND ND ND ND ND
12/5/2012 µg/l NS ND NS ND ND ND NS NS
6/12/2013 µg/l NS ND NS ND ND ND NS NS
10/28/2013 µg/l NS ND NS ND ND ND NS NS
5/6/2014 µg/l NS ND NS ND ND ND NS NS
10/23/2014 µg/l NS * ND ND ND ND NS NS
5/21/2015 µg/l NS ND ND ND ND ND NS NS
12/8/2015 µg/l NS ND ND ND ND ND NS NS
5/3/2016 µg/l NS NS ND ND ND ND ND ND
12/13/2016 µg/l NS NS ND ND ND ND NS NS
6/27/2017 µg/l NS NS ND ND ND ND NS NS
Burke Co.- Johns River C and D-over-MSWLF
Permit No. 12-03 Page 8 of 10
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
1,1-Dichloroethane 11/3/2006 µg/l ND NS NS 12 34 33 NI NI
(DCA)6/3/2009 µg/l 6.3 NS NS 8.2 47.8 32.0 3.9 J 2.8 J
11/17/2009 µg/l 10.8 NS NS 6.7 41.9 29.4 6.7 3.7 J
6/16/2010 µg/l 3.9 J NS NS 5.7 35.7 32.1 4.4 J 2.3 J
12/1/2010 µg/l 6.8 NU NS 5.4 41.3 16.9 NS NS
6/1/2011 µg/l 9.3 NU NS 6.8 45.5 19.1 2.8 J 2.6 J
12/20/2011 µg/l NS ND NS 5.1 39.7 26.2 NS NS
5/30/2012 µg/l NS ND NS 5.9 38.2 24.1 1.6 J 2.7 J
12/5/2012 µg/l NS ND NS 4.6 J 39.3 26.5 NS NS
6/12/2013 µg/l NS ND NS 5.3 37.1 21.4 NS NS
10/28/2013 µg/l NS ND NS 4.6 J 43.2 26.2 0.93 J 3.0 J
5/6/2014 µg/l NS ND NS 4.0 J 43.4 21.5 1.2 J 2.9 J
10/23/2014 µg/l NS * ND 3.6 J 34.4 25.3 NS NS
5/21/2015 µg/l NS ND ND 2.8 J 26.7 17.3 ND 1.7 J
12/8/2015 µg/l NS ND ND 3.2 J 31.7 10.3 NS NS
5/3/2016 µg/l NS NS ND ND ND ND 0.44 J 2.5 J
12/13/2016 µg/l NS NS ND 3.0 J 27.4 22.1 NS NS
6/27/2017 µg/l NS NS ND 3.3 J 26.8 17.8 NS NS
Chloroethane 11/3/2006 µg/l ND NS NS ND ND ND NI NI
(CA)6/3/2009 µg/l 1.1 J NS NS ND ND 4.4 J 4.3 J ND
11/17/2009 µg/l 3.1 J NS NS 0.63 J 5.5 J 3.5 J 2.9 J 0.90 J
6/16/2010 µg/l 1.7 J NS NS 0.88 J 3.1 J 2.2 J 2.6 J 0.80 J
12/1/2010 µg/l ND NU NS ND ND ND NS NS
6/1/2011 µg/l 1.5 J NU NS ND 2.7 J ND 3.6 J 0.85 J
12/20/2011 µg/l NS ND NS ND 2.1 J 2.9 J NS NS
5/30/2012 µg/l NS ND NS ND 1.5 J ND ND ND
12/5/2012 µg/l NS ND NS ND 1.8 J 1.9 J NS NS
6/12/2013 µg/l NS ND NS ND 0.63 J 1.5 J NS NS
10/28/2013 µg/l NS ND NS ND 1.9 J ND NS NS
5/6/2014 µg/l NS ND NS ND 1.6 J 1.3 J NS NS
10/23/2014 µg/l NS * ND ND ND 1.6 J NS NS
5/21/2015 µg/l NS ND ND ND ND 1.6 J NS NS
12/8/2015 µg/l NS ND ND ND ND ND NS NS
5/3/2016 µg/l NS NS ND ND ND ND ND ND
12/13/2016 µg/l NS NS ND ND 3.0 J 1.7 J NS NS
6/27/2017 µg/l NS NS ND ND 2.6 J 1.6 J NS NS
Chloroform 11/3/2006 µg/l ND NS NS ND ND ND NI NI
6/3/2009 µg/l ND NS NS ND ND ND ND ND
11/17/2009 µg/l ND NS NS ND ND ND ND ND
6/16/2010 µg/l ND NS NS ND ND ND ND ND
12/1/2010 µg/l ND NU NS ND ND ND NS NS
6/1/2011 µg/l ND NU NS ND ND ND ND ND
12/20/2011 µg/l NS ND NS ND ND ND NS NS
5/30/2012 µg/l NS ND NS ND ND ND ND ND
12/5/2012 µg/l NS ND NS ND ND ND NS NS
6/12/2013 µg/l NS ND NS ND ND ND NS NS
10/28/2013 µg/l NS ND NS ND ND ND NS NS
5/6/2014 µg/l NS ND NS ND ND ND NS NS
10/23/2014 µg/l NS * ND ND ND ND NS NS
5/21/2015 µg/l NS ND ND ND ND ND NS NS
12/8/2015 µg/l NS ND ND ND ND ND NS NS
5/3/2016 µg/l NS NS ND ND ND ND ND ND
12/13/2016 µg/l NS NS ND ND ND ND NS NS
6/27/2017 µg/l NS NS ND ND ND ND NS NS
Burke Co.- Johns River C and D-over-MSWLF
Permit No. 12-03 Page 9 of 10
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
Methylene Chloride 11/3/2006 µg/l ND NS NS ND ND ND NI NI
6/3/2009 µg/l ND NS NS ND ND ND ND ND
11/17/2009 µg/l 11.1 NS NS ND ND ND ND ND
6/16/2010 µg/l ND NS NS ND ND ND ND ND
12/1/2010 µg/l 2.2 NU NS ND ND ND NS NS
6/1/2011 µg/l 2.3 NU NS ND ND ND ND ND
12/20/2011 µg/l NS ND NS ND ND ND NS NS
5/30/2012 µg/l NS ND NS ND ND ND ND ND
12/5/2012 µg/l NS ND NS ND ND ND NS NS
6/12/2013 µg/l NS ND NS ND ND ND NS NS
10/28/2013 µg/l NS ND NS ND ND ND ND ND
5/6/2014 µg/l NS ND NS ND ND ND ND ND
10/23/2014 µg/l NS * ND ND ND ND NS NS
5/21/2015 µg/l NS ND ND ND ND ND ND ND
12/8/2015 µg/l NS ND ND ND ND ND NS NS
5/3/2016 µg/l NS NS ND ND ND ND ND ND
12/13/2016 µg/l NS NS ND ND ND ND NS NS
6/27/2017 µg/l NS NS ND ND ND ND NS NS
Notes:
(FP) = Field Parameter
ND = Not Detected
NS = Not Sampled
mV = millivolts
S.U. = standard units
oC = degrees Celcius
mS/cm = microsiemens per centimeter
mg/l = milligrams per liter (parts per million)
µg/l = micrograms per liter (parts per billion)
NU = Not Used as background data until approved
* MW-21 replaced MW-20 as the background well starting with the Fall 2014 sampling event; however MW-20 continues to be sampled as a compliance well
for the C&D Expansion (Phase 1A).
May 20, 2015: Shaded dissolved oxygen results are suspect. The DO Sensor began reading very low, re-calibration attempts did not appear to correct the issue.
A short in the DO probe was diagnosed after the field event.
-- MW-12 TOC sample for 12/08/15 was broken in transit to the laboratory and could not be analyzed.
Burke Co.- Johns River C and D-over-MSWLF
Permit No. 12-03 Page 10 of 10
Joyce Engineering