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HomeMy WebLinkAbout5503_LincolnCountyMSWLF_GWMR_20180214October 2017 Semi-Annual Monitoring Report Lincoln County Landfill – Permit #55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 PREPARED FOR: Lincoln County 5291 Crouse Road Crouse, North Carolina 28033 PREPARED BY: S&ME, Inc. 9751 Southern Pine Boulevard Charlotte, NC 28273 February 14, 2018 S&ME, Inc. | 9751 Southern Pine Boulevard | Charlotte, NC 28273 | p 704.523.4726 | www.smeinc.com February 14, 2018 Lincoln County 5291 Crouse Road Crouse, North Carolina 28033 Attention: Mr. Mark Bivins Reference: October 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit #55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 Dear Mr. Bivins: S&ME Inc. (S&ME) has completed the October 2017 Semi-Annual Monitoring and Reporting for the Lincoln County Landfill. This report presents the results of the second monitoring event of the year for the facility. S&ME appreciates the continued opportunity to provide services to you and Lincoln County. If you have any questions or need additional information regarding this report, please contact us at (704) 523-4726. Sincerely, S&ME, Inc. Jasmine Tayouga Julie P. Robertson, P.G. Staff Professional Project Manager/Senior Geologist Registration No. 1995 Cc: Jaclynne Drummond, NCDEQ – Solid Waste Section October 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit #55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 February 14, 2018 ii Table of Contents 1.0 Introduction ....................................................................................................................... 1 2.0 Groundwater Levels and Flow ....................................................................................... 1 3.0 Analytical Data .................................................................................................................. 1 3.1 Groundwater Monitoring and Sampling .................................................................................... 1 3.1.1 MSW Area “E” and Phase 1 ............................................................................................................. 1 3.1.1.1 Volatile Organic Compounds (VOCs) ......................................................................................... 2 3.1.1.2 Inorganic Constituents (Metals) ................................................................................................... 3 3.1.2 MSW Phase 2 .................................................................................................................................... 4 3.1.2.1 Volatile Organic Compounds (VOCs) ......................................................................................... 4 3.1.2.2 Inorganic Constituents (Metals) ................................................................................................... 4 3.1.3 MSW Phase 3 .................................................................................................................................... 5 3.1.3.1 Volatile Organic Compounds (VOCs) ......................................................................................... 5 3.1.3.2 Inorganic Constituents (Metals) ................................................................................................... 5 3.1.4 C&D Landfill Phase 1 and 2 ............................................................................................................. 5 3.1.4.1 Volatile Organic Compounds (VOCs) ......................................................................................... 6 3.1.4.2 Inorganic Constituents (Metals) ................................................................................................... 6 3.1.4.3 Classical Chemistry Compounds ................................................................................................. 6 3.2 Surface Water Sampling ................................................................................................................ 6 3.2.1 Surface Water Locations SW-1 through SW-5 ................................................................................. 7 3.2.2 Surface Water Location SW-6 ........................................................................................................... 7 3.3 Leachate Sampling ......................................................................................................................... 7 4.0 Statistical Analysis ............................................................................................................ 7 4.1 Volatile Organic Compounds (VOCs) ......................................................................................... 8 4.2 Total Metals ..................................................................................................................................... 8 5.0 Methane Readings ............................................................................................................ 9 October 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit #55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 February 14, 2018 iii Appendices Appendix I – Drawings Appendix II – Tables Appendix III – Well Sampling Logs and Laboratory Reports Appendix IV – Statistical Analysis Procedures Appendix V – Graphs Depicting Concentrations over Time for Wells with a Statistically Significant Increase Appendix VI – Monthly Methane Data (April 2017 – October 2017) October 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit #55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 February 14, 2018 1 1.0 Introduction S&ME, Inc. (S&ME) was contracted by Lincoln County to provide groundwater, surface water, and leachate monitoring services at the Lincoln County Landfill located at 5291 Crouse Road in Crouse, North Carolina. This semi-annual monitoring event was conducted on October 9th – 11th, 2017. This report presents the results of the second semi-annual sampling event for the year 2017 at the facility. The facility’s monitoring network includes one background well (MW-1A), twenty-eight compliance wells, six (6) surface water sample locations, and one leachate sample. The next sampling event is scheduled for April 2018 and will include wells associated with the newly constructed Phase 4. 2.0 Groundwater Levels and Flow The water table elevations and our interpretation of the groundwater surface expressed as a potentiometric map along with groundwater flow direction are shown on Drawing 1 of 1 in Appendix I. Based upon the groundwater elevations in the vicinity of the landfill, groundwater in this area is projected to flow primarily to the south, with secondary flow toward the southwest and southeast toward tributaries located east and west of the landfills. Groundwater levels for the monitoring wells are presented in Table 1 in Appendix II. The hydraulic gradient (i) in the vicinity of each well was estimated by calculating the vertical difference between the groundwater elevation at each well and one or more nearby contour lines from Drawing 1 of 1. This value was then divided by the horizontal distance measured from the well to the selected groundwater elevation contour line. Groundwater velocity was calculated by multiplying the gradient (i) by the hydraulic conductivity (k) and dividing by the estimated effective porosity (ne) of the aquifer. Table 2 in Appendix II summarizes the groundwater flow rates for the monitoring wells. 3.0 Analytical Data Analytical results for the landfill monitoring wells, surface water samples, and leachate sample are summarized in Tables 4 through 10 in Appendix II. Detections above the NCAC 2L .0202 Groundwater Quality Standards (2L Standards), NCAC 2B surface water standards (2B Standards), and/or SW GWP Standard are highlighted in gray. Field measurements of pH, conductivity, and temperature are summarized in Table 3 in Appendix II. Well sampling logs containing this information are included in Appendix III. 3.1 Groundwater Monitoring and Sampling 3.1.1 MSW Area “E” and Phase 1 MSW Area “E” and Phase 1 groundwater monitoring well locations were sampled for Appendix I volatile organic compounds (VOCs) and Appendix I metals. In addition to Appendix I VOCs and metals, the groundwater analysis for background monitoring well MW-1A also included inorganic constituents iron and manganese. A summary of October 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit #55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 February 14, 2018 2 the detected analytes associated with this Phase of the landfill is included as Table 4 in Appendix II. The groundwater monitoring wells associated with these areas include background well MW-1A, compliance wells MW-8, MW-9, and MW-10R that monitor the abandoned leachate pond, and compliance wells MW-12 through MW-20 that monitor down gradient and side gradient of the unlined MSW landfill Area “E” and the lined MSW landfill identified as Phase 1. During the previous sampling event it was discovered that MW-15 was damaged and could not be sampled. Lincoln County was notified of the damage and the well will be replaced. Based on the laboratory analytical reports included in Appendix III, thirteen VOCs and sixteen metals were detected in MSW Area “E” and Phase 1 groundwater monitoring wells during the October 2017 monitoring event. During the October 2017 sampling event MW-8 was dry and could not be sampled. MW-10R went dry while purging and did not recharge enough to collect a laboratory sample. 3.1.1.1 Volatile Organic Compounds (VOCs) Background monitoring well MW-1A had a detection of Chloroform at a concentration of 12 micrograms per liter (µg/L), which is below the 2L Standard of 70 µg/L. Both Bromoform and Chloroform have historically been detected in monitoring well MW-1A which are commonly associated with chlorinated municipal water. Due to MW-1A’s close proximity to Crouse Road, it is likely that the detection of Chloroform in the well is from a leaking nearby municipal water or sewer line. No VOCs were detected in groundwater monitoring wells MW-9, MW-12, and MW-18 during the October 2017 monitoring event. Monitoring wells MW-13, MW-14, MW-16R, MW-17R, MW-19, and MW-20 contained two or more of the fifteen VOCs detected. Of the VOCs detected, five compounds were detected above their respective 2L Standard: 1,1- Dichloroethane, Benzene, Methylene Chloride, Tetrachloroethene, and Vinyl Chloride. Please note that groundwater monitoring well MW-14 had no VOC detections above its respective 2L Standards. The analytical results for groundwater monitoring well MW-13 indicated that 1,1-Dichloroethane, Benzene, Tetrachloroethene, and Vinyl Chloride were detected above their respective 2L Standards. The results of which are as follows: •1,1-Dichloroethane detected at 11 µg/L. 2L Standard is 6 µg/L. •Benzene detected at 4 µg/L. 2L Standard is 1 µg/L. •Tetrachloroethene detected at 2.5 µg/L. 2L Standard is 0.7 µg/L. •Vinyl Chloride detected at 0.68 µg/L. 2L Standard is 0.03 µg/L. The results for groundwater monitoring well MW-16R indicated that Benzene and Vinyl Chloride were detected above their respective 2L Standard. The results of which are as follows: •Benzene detected at 5.3 µg/L. 2L Standard is 1 µg/L. •Vinyl chloride detected at 2.8 µg/L. 2L Standard is 0.03 µg/L. The results for groundwater monitoring well MW-17R indicated that 1,1-Dichloroethane, Benzene, and Methylene Chloride were detected above their respective 2L Standard. The results of which are as follows: October 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit #55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 February 14, 2018 3 •1,1-Dichloroethane detected at 6.2 µg/L. 2L Standard is 6 µg/L. •Benzene detected at 4.2 µg/L. 2L Standard is 1 µg/L. •Methylene Chloride detected at 39 µg/L. 2L Standard is 5 µg/L. The results for groundwater monitoring well MW-19 indicated that 1,1-Dichloroethane, Benzene, and Tetrachloroethene were detected above their respective 2L Standard. The results are as follows: •1,1-Dichloroethane detected at 12 µg/L. 2L Standard is 6 µg/L. •Benzene detected at 1.4 µg/L. 2L Standard is 1 µg/L. •Tetrachloroethene detected at 2.0 µg/L. 2L Standard is 0.7 µg/L. The results for groundwater monitoring well MW-20 indicated that 1,1-Dichloroethane, Benzene, Tetrachloroethene, and Vinyl Chloride were detected above their respective 2L Standard. The results are as follows: •1,1-Dichloroethane detected at 7.2 µg/L. 2L Standard is 6 µg/L. •Benzene detected at 1.9 µg/L. 2L Standard is 1 µg/L. •Tetrachloroethene detected at 0.82 J µg/L. 2L Standard is 0.7 µg/L. •Vinyl Chloride detected at 0.87 J µg/L. 2L Standard is 0.03 µg/L. Groundwater monitoring wells MW-13, MW-14, MW-16R, MW-17R, MW-19 and MW-20 monitor down gradient and side gradient of the of the unlined Area “E” landfill, and the volatile organic constituents detected in these wells are associated with the unlined landfill section. 3.1.1.2 Inorganic Constituents (Metals) The groundwater monitoring wells associated with the MSW Area “E” and Phase 1 landfills had three or more Appendix I metals detected. Eight constituents were detected above their respective 2L Standard or SW GWP Standard: Antimony, Arsenic, Chromium, Cobalt, Iron, Manganese, Thallium, and Vanadium. •Antimony was detected above its SW GWP Standard of 1 µg/L in background groundwater monitoring well MW-1A, compliance monitoring wells MW-9, MW-14, and MW-19 at concentrations ranging from 1.30 J µg/L to 4.76 J µg/L. •Arsenic was detected above its 2L Standard of 10 µg/L in compliance monitoring well MW-16R at a concentration of 18.0 µg/L. •Chromium was detected above its 2L Standard of 10 µg/L in background monitoring well MW-1A at a concentration of 53.10 µg/L. •Cobalt was detected above its SW GWP Standard of 1 µg/L in background monitoring well MW-1A, compliance monitoring wells MW-12, MW-13, MW-14, MW-16R, MW-17R, MW-18, and MW-20 at concentrations ranging from 1.17 J µg/L to 242 µg/L. •Iron was detected above its 2L Standard of 300 µg/L in background monitoring well MW-1A at a concentration of 16,300 µg/L. •Manganese was detected above its 2L Standard of 50 µg/L in background monitoring well MW-1A at a concentration of 301 µg/L. October 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit #55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 February 14, 2018 4 •Thallium was detected above its SW GWP Standard of 0.28 µg/L in background monitoring well MW-1A, compliance monitoring wells MW-13, MW-16R, and MW-17R at concentrations ranging from 0.370 J to 24.2 JD µg/L. •Vanadium was detected above its SW GWP Standard of 0.3 µg/L in background monitoring well MW-1A, compliance monitoring wells MW-9, MW-12, MW-13, MW-17R, and MW-18 at concentrations ranging from 1.65 J to 34.5 µg/L. Total metal concentrations in groundwater sampled from wells are often dependent on the turbidity or suspended particulates (from the aquifer formation) retrieved with the groundwater sample. The turbidity is a function of the sampling method, well construction, how the well was developed, and the grain size/consolidation of the lithologic unit sampled. Since the unfiltered samples are acidified in the field at the time of collection, metals contained within the particulates are dissolved into the sample. Thus, the presence of turbidity in groundwater samples often results in elevated (false positive) analytical results for total metal concentrations. Therefore, the presence of elevated total metal concentrations does not necessarily correlate with groundwater impact. Based on historical water quality data, the background well and each of the compliance groundwater monitoring wells have contained at least one total metal at concentrations above the 2L Standards. Metal concentrations in several wells have fluctuated below and above detection limits. In background well MW-1A, beryllium, cadmium, chromium, cobalt, iron, lead, silver, and vanadium have been detected at concentrations above the 2L Standards. Based on this data, it appears that the majority of the metals detected within the monitoring wells are either naturally occurring or a product of turbidity during sampling. 3.1.2 MSW Phase 2 MSW Phase 2 groundwater monitoring well locations were sampled for Appendix I VOCs and Appendix I metals. A summary of the detected analytes associated with this Phase of the landfill is included as Table 5 in Appendix II. The groundwater monitoring wells associated with this Phase are compliance wells MW-21 and MW-24 that monitor side gradient of the landfill and MW-25 and MW-25A that monitor the Phase 2 sump. During the October 2017 monitoring event MW-25 was dry and could not be sampled. 3.1.2.1 Volatile Organic Compounds (VOCs) No VOCs were detected above their respective 2L Standard or SW GWP Standard in the MSW Phase 2 monitoring wells during the October 2017 monitoring event. 1,1-Dichloroethane was detected in MW-25A at a concentration of 0.55 J µg/L which is below its 2L Standard of 6 µg/L. Acetone was detected in MW-21 at a concentration of 36 J µg/L which is below its 2L Standard of 6,000 µg/L. 3.1.2.2 Inorganic Constituents (Metals) The groundwater monitoring wells associated with the Phase 2 landfill had four or more Appendix I metals detections, three of which were detected above their respective SW GWP Standards. Cobalt was detected above the SW GWP Standard of 1 µg/L in groundwater monitoring well MW-25A at a concentration of 6.86 J µg/L. Thallium was detected above the SW GWP Standard of 0.28 µg/L in groundwater monitoring well MW-24 at a concentration of 0.336 J µg/L. Vanadium was detected above the SW GWP Standard of 0.3 µg/L in groundwater monitoring well MW-25A at a concentration of 2.02 J µg/L. October 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit #55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 February 14, 2018 5 As previously discussed above, it appears that the majority of the metals detected within the groundwater monitoring wells are either naturally occurring or a product of turbidity during sampling. 3.1.3 MSW Phase 3 MSW Phase 3 groundwater monitoring well locations were sampled for Appendix I VOCs and Appendix I metals. A summary of the detected analytes associated with this phase of the landfill is included in Table 6 in Appendix II. The groundwater monitoring wells associated with this area include compliance well MW-32R that monitors down gradient and side gradient of the landfill and MW-33/33A and MW-35/35A that monitor the Phase 3 sump locations. Monitoring well MW-34 that previously monitored downgradient of Phase 3 was abandoned during Phase 4 construction activities. During the October 2017 monitoring event MW-35 went dry during purging and a laboratory sample could not be collected. 3.1.3.1 Volatile Organic Compounds (VOCs) No VOCs were detected in the MSW Phase 3 monitoring wells during the October 2017 monitoring event. 3.1.3.2 Inorganic Constituents (Metals) The groundwater monitoring wells associated with the Phase 3 landfill had three or more Appendix I metals detected, three of which were detected above their respective 2L Standard or SW GWP Standard. The detections above standards are as follows: •Antimony was detected above the SW GWP Standard of 1 µg/L in groundwater monitoring wells MW-33A and MW-35A at concentrations of 4.36 J µg/L and 4.78 J µg/L, respectively. •Cobalt was detected above the SW GWP Standard of 1 µg/L in groundwater monitoring well MW-33A at a concentration of 1.53 J µg/L. •Vanadium was detected above the SW GWP Standard of 0.3 µg/L in groundwater monitoring well MW- 35A at a concentration of 3.19 J µg/L. As previously discussed above, it appears that the majority of the metals detected within the groundwater monitoring wells are either naturally occurring or a product of turbidity during sampling. 3.1.4 C&D Landfill Phase 1 and 2 C&D Landfill Phase 1 and Phase 2 groundwater monitoring well locations were sampled for Appendix I VOCs; Appendix I metals plus mercury, manganese, and iron; and four classical chemistry compounds: Chloride, Total Dissolved Solids, Sulfate, and Alkalinity. A summary of the detected analytes associated with the C&D Landfills is included as Table 7 and 8 in Appendix II. The groundwater monitoring wells associated with the C&D landfill include compliance wells MW-26, MW-27, and MW-28 that monitor Phase 1 and MW-29, MW-30, MW-31, and MW-36 that monitor Phase 2. Groundwater monitoring well MW-36 was installed near the C&D compliance boundary as part of the 2013 C&D Assessment. October 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit #55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 February 14, 2018 6 3.1.4.1 Volatile Organic Compounds (VOCs) C&D Landfill groundwater monitoring wells had five VOCs detected during the October 2017 monitoring event, two (2) of which were detected above their respective 2L Standard. •Tetrachloroethene was detected in groundwater monitoring well MW-28 at a concentration of 8.9 µg/L, which is above its 2L Standard of 0.7 µg/L. •Vinyl Chloride was detected in groundwater monitoring well MW-28 at a concentration of 0.84 J µg/L, which is above its 2L Standard of 0.03 µg/L. 3.1.4.2 Inorganic Constituents (Metals) The groundwater monitoring wells associated with the C&D landfill had six or more metals detections, and four (4) constituents were detected above their respective 2L Standard and/or SW GWP Standard. The detections above standards are as follows: •Cobalt was detected in groundwater monitoring wells MW-26, MW-27, and MW-28 at a concentrations ranging from 1.11 J to 12.0 µg/L which are above the SW GWP Standard of 1 µg/L. •Iron was detected in groundwater monitoring wells MW-26, MW-27, MW-29, MW-30, MW-31, and MW- 36 at concentrations ranging from 347 to 52,400 µg/L, which are above the 2L Standard of 300 µg/L. •Manganese was detected in groundwater monitoring wells MW-27, MW-29 and MW-30 at concentrations of 203 µg/L and 1620 µg/L, respectively, which are above the 2L Standard of 50 µg/L. •Vanadium was detected in groundwater monitoring wells MW-26, MW-27, MW-29, and MW-36 at concentrations ranging from 1.86 J to 4.24 J µg/L, which are above the SW GWP Standard of 0.3 µg/L. As previously discussed above, it appears that the majority of the metals detected within the groundwater monitoring wells are either naturally occurring or a product of turbidity during sampling. Since October 2007, Iron and Manganese have been included in the analysis for the C&D wells, and since April 2008, Iron and Manganese were included in the analysis for the background well MW-1A. Iron and Manganese have been detected in MW- 1A in each monitoring event that has included their analysis. 3.1.4.3 Classical Chemistry Compounds Total Dissolved Solids, Chloride, Sulfate, and Alkalinity were analyzed for in the C&D landfill groundwater monitoring wells. The results of the analyses are summarized in Tables 7 and 8 in Appendix II. Please note that none of the classical chemistry compounds analyzed for exceeded any of the established 2L Standards and/or SW GWP Standards. 3.2 Surface Water Sampling Lincoln County Landfill has five surface water sampling locations positioned in the tributaries located to the east, south, and west of the landfill as indicated on the attached Drawing 1 of 1 in Appendix I. The original five surface water samples are analyzed for Appendix I VOCs and Appendix I metals plus Mercury, Iron and Manganese. Beginning with the April 2010 sampling event, a sixth surface water sample location was added to the semi-annual monitoring plan, SW-6. The addition of SW-6 to the monitoring plan was in response to the October 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit #55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 February 14, 2018 7 January 2009 leachate release at the facility. SW-6 is located at the discharge of the lowland area downgradient from the leachate holding tanks as indicated on Drawing 1 of 1. A summary of the detected analytes associated with the surface water samples collected is included as Table 9 in Appendix II. 3.2.1 Surface Water Locations SW-1 through SW-5 No VOCs were detected in surface water sampling locations during the October 2017 sampling event. Ten (10) or more metals were detected in surface water sampling locations SW-1, SW-2, SW-3, SW-4, and SW-5, none of which were detected at concentrations above their respective 2B Standard. 3.2.2 Surface Water Location SW-6 No VOCs were detected in surface water sampling location SW-6 during the October 2017 sampling event. Seven (7) metals were detected in SW-6, none of which were detected at concentrations above their respective 2B Standard. Of the classical chemistry compounds analyzed for, none were detected above their respective 2B Standard. 3.3 Leachate Sampling A sample of the leachate from the leachate collection system for the landfill was collected from the lift station prior to leachate entering the on-site leachate holding tanks. The leachate sample was analyzed for Appendix I VOCs, Appendix I metals, BOD, COD, Nitrate/Nitrite, Sulfate, TSS, and Phosphorous. A summary of the detected analytes for the leachate is included as Table 10 in Appendix II. 4.0 Statistical Analysis S&ME compared the water quality data with the 2L Standards and the SW GWP standards and performed a statistical evaluation of the data. S&ME utilized three (3) statistical methods to evaluate statistically significant increases between the compliance monitoring wells and the background monitoring well (MW-1A). The first method utilized was a one-way parametric Analysis of Variance (Parametric ANOVA). The parametric ANOVA analysis is recommended by the 1992 guidance document for parameters with fewer than 15% non- detects in a specific well. The second method used was the Kruskal-Wallis non-parametric rank method. The Kruskal-Wallis method is recommended by the 1992 guidance document for parameters that have 15% to 90% non-detects in a specific well. The third method used was an inter-well non-parametric prediction limit. The prediction limit was used for parameters with greater than 90% non-detects in a specific well. The 1992 guidance document recommends this method when a significant portion of the samples are non-detect. Tables 11 through 13 in Appendix II summarize the results of the statistical analysis. Copies of the analytical procedures used to perform the analysis used by the ChemStat software are included in Appendix IV. October 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit #55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 February 14, 2018 8 4.1 Volatile Organic Compounds (VOCs) One (1) or more volatile organic compounds were found to have a statistical increase over background concentrations in groundwater monitoring wells MW-13, MW-14, MW-16(16R), MW-17(17R), MW-19, and MW-20 that are located downgradient from the unlined closed landfill Area “E”. The statistical increases are as follows: •1,1-Dichloroethane in groundwater monitoring wells MW-13, MW-14, MW-16(16R), MW-19 and MW-20. It should be noted that concentrations of 1,1-Dichloroethene in MW-13 and MW-16 have decreased over time. •1,4-Dichlorobenzene in groundwater monitoring wells MW-13 and MW-16(16R). •Acetone in groundwater monitoring well MW-13, which has ranged from non-detect to detect over time. •Benzene in groundwater monitoring wells MW-13, MW-16(16R), and MW-19. Reported concentrations over time have been generally stable. •cis-1,2-Dichloroethene in groundwater monitoring wells MW-13, MW-16(16R), MW-19 and MW-20. Concentrations at these wells have been relatively stable, although a rising trend over time is noted at MW-16. •Chlorobenzene in groundwater monitoring well MW-16(16R). •Chloroethane in groundwater monitoring wells MW-13 and MW-16(16R). It should be noted that concentrations of Chloroethane in well MW-13 have decreased over time and both MW-13 and MW- 16(16R) have concentrations that vary from non-detect to detect. •Methylene Chloride in groundwater monitoring wells MW-13, MW-16(16R), MW-19 and MW-20. It should be noted that concentrations of Methylene Chloride in wells MW-19 and MW-20 have decreased over time. •Tetrachloroethene in groundwater monitoring wells MW-13, MW-17 (17R), and MW-19. Reported concentrations over time have been generally stable. October 2017 was the first statistically significant increase for MW-17(17R). •Toluene in groundwater monitoring well MW-13. •Trichloroethene in groundwater monitoring wells MW-13, MW-19, and MW-20. Reported concentrations over time have been generally stable. October 2017 was the first statistically significant increase for MW- 17(17R). •Trichlorofluoromethane in MW-19. Over time concentrations have varied from non-detect to detect. •Vinyl Chloride in groundwater monitoring wells MW-13 and MW-16(16R). Reported concentrations over time have been generally stable. •Total Xylenes in groundwater monitoring wells MW-13, MW-16(16R) and MW-19. Reported concentrations over time have been generally stable in MW-13; MW-16 concentrations vary from non- detect to detect. October 2017 was the first statistically significant increase in MW-19. There were no volatile organic compounds with statistically significant increases over background for the Phase 2 and Phase 3 MSW wells. Graphs depicting concentrations over time for constituents with a statistical increase are provided in Appendix V. 4.2 Total Metals Total metal concentrations in groundwater sampled from wells are often dependent on the turbidity or suspended particulates (from the aquifer formation) retrieved with the groundwater sample. The turbidity is a function of the October 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit #55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 February 14, 2018 9 sampling method, well construction, how the well was developed, and the grain size/consolidation of the lithologic unit sampled. Since the unfiltered samples are acidified in the field at the time of sample collection, metals contained within the particulates are dissolved into the water sample. Thus, the presence of turbidity in groundwater samples often results in elevated (false positive) analytical results for total metal concentrations. Therefore, the presence of elevated total metal concentrations does not necessarily correlate with groundwater impact. Based on the historical water quality data, the background well and each of the compliance groundwater monitoring wells (excluding MW-22) have contained at least one (1) total metal at concentrations above the 2L Standards. The statistical evaluation indicates that twelve (12) of the compliance groundwater monitoring wells (MW-8, 10, 12, 13, 15, 16(16R), 17(17R), 24, 25, 25A, 33, and MW-33A) contained at least one (1) metal at a statistically significant level higher than the background well. Metal concentrations in several wells have fluctuated between non-detect and detect. In the background well, MW-1A, antimony, beryllium, cadmium, chromium, cobalt, iron, lead, manganese, silver, thallium, and vanadium have historically been detected at concentrations above the 2L Standards. Graphs depicting concentrations over time for constituents with a statistical increase are provided in Appendix V. 5.0 Methane Readings Methane Readings are collected from eleven (11) locations on site, including eight (8) methane monitoring wells (MMW-1 through MMW-8) and the scale house, landfill shop, and lift station on site. Methane readings are measured monthly by Lincoln County personnel using a GEM 2000 gas meter. April 2017 through October 2017 methane readings and a figure showing their locations are located in Appendix VI. Please note that September 2017 methane readings were not recorded due to equipment failure. A new meter was purchased and readings resumed in October 2017. Appendices Appendix I – Drawings kjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkj!.!.!.!.!.!.kjC&D PHASE II C&D PHASE I EXISTING AREA "E"CLOSED LANDFILLEXISTING AREA "D"PHASE IPHASE II PHASE III805 810855860830845870875880825815PHASE IV FUTURE PHASE V 820835840850865MW-8DRY MW-9803.15 MW-12812.78MW-24813.02 MW-25/25A806.14 MW-21815.19 MW-18840.76 MW-19832.13 MW-13839.30 MW-14839.54 MW-20843.39 MW-28869.43MW-29836.45 MW-36824.60 MW-30830.90 MW-31847.24 MW-26856.09 MW-27861.62 MW-1A884.95 MW-17R855.32 MW-10R804.45 MW-32R807.43 MW-16R858.50 MW-35/MW-35A803.77 MW-33/MW-33A801.74 SW-4 SW-5 SW-1 SW-2 SW-3 SW-6 SHOAL RD CROUSE RDYO D E R R D SHIRLEY R E Y N O L D S L N GROUNDWATER SURFACE MAPOctober 9-10, 2017LINCOLN COUNTY LANDFILLCROUSE, NORTH CAROLINA1 1356-07-004SJT2-14-2018FIGURE NO.SCALE:PROJECT NO.DATE:DRAWN BY:³1 " = 400 'Q:\1356\LINCOLN COUNTY\07-004\GIS\OCT 2017 GW Map 11x17_arcmap104.mxd plotted by JTayouga 02-14-20180 500 1,000 (IN FEET) MW-15NS Legend kj Groundwater Wells !.Surface Water Sample Locations Roads MSW Boundary Property Line C&D Landfill Boundary Streams on Landfill Property Groundwater Flow Direction 4' Contours 10/2017 Groundwater Surface Appendix II – Tables Latitude Longitude Ground TOC DTW - TOC GW ELEV. (MM/DD/YY)(ft)(ft-MSL) MW-1A Background - - - 35.4305188° -081.3550147° - - -929.27 - - - to - - -- - - to - - -- - - to - - -- - - to - - -- - - to - - -- - -44.32 884.95 MW-8 Leachate Lagoon - - -35.4204767°-081.3543964°- - -840.03 - - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -DRY N/A MW-9 Leachate Lagoon - - -35.4205014°-081.3544769°- - -840.20 - - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -37.05 803.15 MW-10R Leachate Lagoon - - -35.4209399°-081.3538215°- - -834.97 - - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -30.52 804.45 MW-12 Area "E" and Phase 1 - - -35.4229138°-081.3543339°- - -827.57 - - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -14.79 812.78 MW-13 Area "E" and Phase 1 - - -35.4252197°-081.3569120°- - -872.78 - - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -33.48 839.30 MW-14 Area "E" and Phase 1 - - -35.4252431°-081.3570085°- - -871.44 - - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -31.90 839.54 MW-15 Area "E" and Phase 1 - - -35.4232655°-081.3580245°- - -847.86 - - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -Note 1 N/A MW-16R Area "E" and Phase 1 - - -35.4270857°-081.3570696°- - -876.39 - - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -17.89 858.50 MW-17R Area "E" and Phase 1 07/20/93 35.4262555°-081.3548668°898.14 899.64 0.0 to 20.0 20.0 to 35.0 0.0 to 16.0 16.0 to 18.0 18.0 to 45.5 - - -44.32 855.32 MW-18 Area "E" and Phase 1 - - -35.4246249°-081.3576782°859.20 861.41 - - -to - - -- - -to - - -- - -to - - -- - -to - - -15.2 to 30.2 - - -20.65 840.76 MW-19 Area "E" and Phase 1 - - -35.4247561°-081.3576590°859.95 859.73 - - -to - - -- - -to - - -- - -to - - -- - -to - - -63.0 to 68.0 - - -27.60 832.13 MW-20 Area "E" and Phase 1 - - -35.4256922°-081.3575990°- - -860.00 - - -to - - -- - -to - - -- - -to - - -- - -to - - -10.1 to 25.1 - - -16.61 843.39 MW-21 Phase 2 09/03/99 35.4221305°-081.3579143°853.80 855.91 0.0 to 27.0 27.0 to 42.0 0.0 to 23.0 23.0 to 25.0 25.0 to 42.0 SAP 40.72 815.19 MW-24 Phase 2 09/02/99 35.4219922°-081.3540276°838.95 841.13 0.0 to 14.0 14.0 to 29.0 0.0 to 10.0 10.0 to 12.0 12.0 to 29.0 SAP 28.11 813.02 MW-25 Phase 2 08/31/99 35.4213534°-081.3546541°836.75 838.73 0.0 to 15.0 15.0 to 30.0 0.0 to 11.0 11.0 to 13.0 13.0 to 30.0 SAP DRY N/A MW-25A Phase 2 09/01/99 35.4212848°-081.3547068°836.75 838.84 0.0 to 50.0 50.0 to 60.0 0.0 to 46.0 46.0 to 48.0 48.0 to 60.0 SAP 32.70 806.14 MW-26 C&D Phase 1 09/08/99 35.4273089°-081.3527074°869.11 871.19 0.0 to 6.0 6.0 to 21.0 0.0 to 4.0 4.0 to 5.0 5.0 to 21.0 SAP 15.10 856.09 MW-27 C&D Phase 1 09/07/99 35.4278831°-081.3533157°879.03 880.90 0.0 to 10.0 10.0 to 25.0 0.0 to 6.0 6.0 to 8.0 8.0 to 25.0 SAP 19.28 861.62 MW-28 C&D Phase 1 04/01/99 35.4276977°-081.3542728°912.72 915.68 0.0 to 36.0 36.0 to 51.0 0.0 to 32.0 32.0 to 34.0 34.0 to 51.0 SAP 46.25 869.43 MW-29 C&D Phase 2 04/30/02 35.4252895°-081.3534741°877.45 879.97 0.0 to 30.0 30.0 to 45.0 0.0 to 26.0 26.0 to 28.0 28.0 to 45.0 PWR 43.52 836.45 MW-30 C&D Phase 2 05/02/02 35.4259842°-081.3520549°883.72 886.35 0.0 to 45.0 45.0 to 60.0 0.0 to 41.0 41.0 to 43.0 43.0 to 60.0 SAP 55.45 830.90 MW-31 C&D Phase 2 06/19/03 35.4266563°-081.3521999°877.40 879.88 0.0 to 25.0 25.0 to 40.0 0.0 to 21.0 21.0 to 23.0 23.0 to 40.0 PWR 32.64 847.24 MW-32R Phase 3 12/20/04 35.4214589°-081.3583317°825.89 827.25 0.0 to 10.0 10.0 to 25.0 0.0 to 6.0 6.0 to 8.0 8.0 to 25.0 SAP 19.82 807.43 MW-33 Phase 3 12/30/04 35.4208632°-081.3585631°816.33 819.38 0.0 to 7.0 7.0 to 22.0 0.0 to 3.0 3.0 to 5.0 5.0 to 22.0 SAP 17.64 801.74 MW-33A Phase 3 12/30/04 35.4208632°-081.3585631°815.94 818.67 0.0 to 56.5 56.5 to 61.5 0.0 to 52.5 52.5 to 54.5 54.5 to 61.5 ROCK 17.41 801.26 MW-35 Phase 3 12/28/04 35.4200537°-081.3551088°836.85 839.64 0.0 to 19.0 19.0 to 34.0 0.0 to 15.0 15.0 to 17.0 17.0 to 34.0 SAP 35.87 803.77 MW-35A Phase 3 12/28/04 35.4200537°-081.3551088°836.77 839.83 0.0 to 60.0 60.0 to 65.0 0.0 to 56.0 56.0 to 58.0 58.0 to 65.0 SAP 37.52 802.31 MW-36 C&D Phase 2 06/26/13 35.4252949° -081.3518019° 852.00 854.83 0.0 to 19.5 19.5 to 34.5 0.0 to 9.5 9.5 to 17.7 17.7 to 35.0 SAP 30.23 824.60 Notes: (ft-MSL)Feet Mean Sea Level DTW Depth to Water Sch. 40 Schedule 40 Pipe PWR Partially Weathered Rock (ft-bls)Feet Below Land Surface GW ELEV.Groundwater Elevation 0.010 Slot 0.010-Inch Machine-Slotted Pipe ROCK Bedrock TOC Top of Casing #2 Filter Sand Medium to Fine Grained Silica Sand Neat Cement Cement Mixture without Bentonite - - -Not Available Ground Ground Surface Bentonite Bentonite Pellets SAP Saprolite DRY No water in well at time of sampling Note 1 Well was destroyed during clearing operations. Scheduled to be replaced. NS Well was not sampled N/A Not Applicable 2-inch, SCH. 40, PVC 2-inch, 0.010 Slot, PVC Neat Cement Bentonite Interval (decimal degrees)(ft-MSL)(ft-bls)(ft-bls)(ft-bls) Screen Interval Grout Interval Seal Interval Filter Pack Geology in Screen Interval October 2017 (ft-bls)(ft-bls) Table 1 Well Construction Summary and Water Level Data Lincoln County Landfill S&ME Project No: 1356-07-004 Well ID Area Monitored Install Date GPS Coordinates Survey Elevations Casing Interval K n I v Well Hydraulic Cond. Eff. Porosity Gradient Flow Velocity ID (ft/day)(ne)(ft/ft)(ft/yr) MW-1A - - -- - -- - -- - - MW-8 - - -- - -- - -- - - MW-10R - - -- - -- - -- - - MW-12 - - -- - -- - -- - - MW-13 - - -- - -- - -- - - MW-15 - - -- - -- - -- - - MW-16R - - -- - -- - -- - - MW-17R 1.4E+00 17%0.01 36 MW-18 - - -- - -- - -- - - MW-20 - - -- - -- - -- - - MW-21 4.5E-01 23%0.02 17 MW-24 - - -- - -- - -- - - MW-25 - - -- - -- - -- - - MW-26 - - -- - -- - -- - - MW-27 - - -- - -- - -- - - MW-28 - - -- - -- - -- - - MW-29 8.6E-01 3%0.04 366 MW-30 5.0E+00 24%0.05 402 MW-31 - - -- - -- - -- - - MW-32R 2.6E-01 20%0.03 14 MW-33 3.0E+00 27%0.02 85 MW-34 - - -- - -- - -- - - MW-35 4.9E-01 16%0.004 4 MW-36 3.5E+00 20%0.004 26 Notes: (4) Seepage velocity v = (K*i)/ne - - -Not Available (1) Hydraulic Conductivity was calculated from slug tests performed after well construction. October 2017 (3) Hydraulic gradient calculated by measuring linear feet between selected contour intervals. Table 2 Groundwater Flow Data Lincoln County Landfill S&ME Project No: 1356-07-004 (2) Effective porosity was estimated from soils collected within the saturated portion of screen interval during well construction. Well ID DTW TOC (ft-bls)pH Temp (°C)Conductance (μS) MW-1A 44.32 5.86 18.0 15 MW-8 MW-9 37.05 5.57 16.8 40 MW-10R 30.52 6.13 17.9 155 MW-12 14.79 5.82 18.1 199 MW-13 33.48 18.10 18.1 282 MW-14 31.90 6.00 17.5 113 MW-16R 17.89 6.39 17.6 730 MW-17R 44.32 NA 17.9 57 MW-18 20.65 6.14 17.3 142 MW-19 27.60 6.22 16.0 133 MW-20 16.61 5.69 17.3 123 MW-21 40.72 6.06 17.0 105 MW-24 28.11 5.20 18.5 252 MW-25 MW-25A 32.70 5.92 18.4 152 MW-26 15.10 5.58 18.2 94 MW-27 19.28 5.18 17.1 372 MW-28 46.25 4.70 18.9 39 MW-29 43.52 5.57 18.3 311 MW-30 55.45 5.62 17.0 71 MW-31 32.64 5.60 16.8 52 MW-32R 19.82 5.75 17.0 44 MW-33 17.64 6.01 18.7 91 MW-33A 17.41 6.85 16.4 253 MW-35 35.87 3.05 18.1 101 MW-35A 37.52 6.61 16.9 49 MW-36 30.23 5.40 15.6 22 Notes: °C degrees Celsius μS micro siemems NTU nephelometric turbidity unit Table 3 October 2017 - Field Parameters in Monitoring Wells Lincoln County Landfill S&ME Project No. 1356-07-004 DRY Dry Notes: (1) ug/L = micrograms per liter (parts per billion) (2) mg/L = milligrams per liter (parts per million) (3) μS = microSiemens (4) 15A NCAC 2L = North Carolina Groundwater Quality Standards (5) 15A NCAC 2B = North Carolina Surface Water Quality Standards (6) GWP ST = Solid Waste Groundwater Protection Standard (7) NE = No established standard (8) Bold indicates above 15A NCAC 2L, 15A NCAC 2B, or SWS GWP standard (9) Compounds not shown were not detected. (10) SWSL = North Carolina Department of Environmtental Quality, Solid Waste Section Limit established in 2007 (11) NA = Not Analyzed (12) J = Analyte detected is between the Method Detection Limit (MDL) and the SWSL (13) B = Analyte was detected in the associated method blank (14) D = The sample was analyzed at dilution (15) Dry = Surface water sample location dry or no flow, location not sampled (16) NS - Not Sampled Notes for Tables 4 through 10 S&ME Project No. 1356-07-004 EPA Appendix I Volatile Organic Compounds Method 8260 (µg/L) NCDEQ SWSL 15A NCAC 2L Soild Waste GWP ST MW-1A MW-8 MW-9 MW-10R MW-12 MW-13 MW-14 MW-15 MW-16R MW-17R MW-18 MW-19 MW-20 1,1-Dichloroethane 5 6 NE 11 2.7 J 0.79 J 6.2 12 7.2 1,4 - Dichlorobenzene 1 6 NE 2.4 4.3 2.2 1.9 cis-1,2,-Dichloroethene 5 70 NE 2.8 J 9.1 3.5 J 1.3 J 4.9 J Acetone 100 6000 NE 12 J Benzene 1 1 NE 4 5.3 4.2 1.4 1.9 Chlorobenzene 3 50 NE 5.0 Chloroform 5 70 NE 12 Ethyl Chloride (Chloroethane)10 3000 NE 0.98 J 0.86 J 1.1 J Methylene Chloride 1 5 NE 39 0.66 J Tetrachloroethene 1 0.7 NE 2.5 0.65 J 2.0 0.82 J Trichloroethane 1 3 NE 1.7 0.45 J 1.1 1.5 0.58 J Vinyl chloride 1 0.03 NE 0.68 J 2.8 0.87 J Xylenes (total)5 500 NE 1.3 12 1.6 J 2.5 J EPA Appendix I Metals Method 6010B/6020 (µg/L) Antimony 6 NE 1 3.74 J 1.30 J 4.76 J 1.55 J Arsenic 10 10 NE 9.14 J 18.0 Barium 100 700 NE 218 28.5 J 153 97.8 J 28.3 J 689 122 52.4 J 32.8 J 102 Beryllium 1 NE 4 0.276 J 0.155 J 0.139 J 0.323 J Chromium 10 10 NE 53.10 2.42 J 2.21 J 3.85 J 1.41 J Cobalt 10 NE 1 13.5 22.8 242 3.59 J 56.7 17.7 1.17 J 7.64 J Copper 10 1000 NE 16.9 4.04 J 3.60 J 7.37 J Iron 300 300 NE 16,300 NA NA NA NA NA NA NA NA NA Lead 10 15 NE 12.7 4.73 J 4.40 J Manganese 50 50 NE 301 NA NA NA NA NA NA NA NA NA Nickel 50 100 NE 28.3 J 8.00 J 14.0 J 3.23 J 76.1 10.4 J 4.97 J 3.93 J Selenium 10 20 NE 1.50 J 1.10 J Silver 10 20 NE 3.65 J Thallium 5.5 NE 0.28 0.663 J 0.177 J 1.04 J 24.2 JD 0.370 J 0.221 J 0.252 J Vanadium 25 NE 0.3 34.5 1.65 J 2.22 J 3.64 J 4.66 J 3.83 J Zinc 10 1000 NE 69.2 4.89 J 22.1 36.1 15.5 8.56 J 8.26 J Table 4 October 2017 - Detected Analytes in Monitoring Wells for MSW Area “E” and Phase 1 Lincoln County Landfill S&ME Project No. 1356-07-004 DRY DRY NS NS DRY DRY EPA Appendix I Volatile Organic Compounds Method 8260 (µg/L) NCDEQ SWSL 15A NCAC 2L Soild Waste GWP ST MW-21 MW-24 MW-25 MW-25A 1,1-Dichloroethane 5 6 NE DRY 0.55 J Acetone 100 6000 NE 36 J EPA Appendix I Metals Method 6010B/6020 (µg/L) Antimony 6 NE 1 0.889 J Barium 100 700 NE 62.4 J 224 166 Beryllium 1 NE 4 0.322 J 1.26 Cobalt 10 NE 1 6.86 J Copper 10 1000 NE 5.95 J Nickel 50 100 NE 2.88 J Thallium 5.5 NE 0.28 0.171 J 0.336 J Vanadium 25 NE 0.3 2.02 J Zinc 10 1000 NE 11.3 30.5 12.6 Table 5 October 2017 - Detected Analytes in Monitoring Wells for MSW Phase 2 Lincoln County Landfill S&ME Project No. 1356-07-004 DRY EPA Appendix I Volatile Organic Compounds Method 8260 (µg/L) NCDEQ SWSL 15A NCAC 2L Soild Waste GWP ST MW-32R MW-33 MW-33A MW-35 MW-35A EPA Appendix I Metals Method 6010B/6020 (µg/L) Antimony 6 NE 1 4.36 J 4.78 J Barium 100 700 NE 9.10 J 43.6 J 7.68 J 36.2 J Beryllium 1 NE 4 0.161 J Chromium 10 10 NE 2.69 J Cobalt 10 NE 1 1.53 J Copper 10 1000 NE 3.04 J Thallium 5.5 NE 0.28 0.111 J 0.120 J Vanadium 25 NE 0.3 3.19 J Zinc 10 1000 NE 4.75 J 28.0 7.83 J No Volatile Organic Compounds Detected in Phase 3 in October 2017 Table 6 October 2017 - Detected Analytes in Monitoring Wells for MSW Phase 3 Lincoln County Landfill S&ME Project No. 1356-07-004 DRY EPA Appendix I Volatile Organic Compounds Method 8260 (µg/L) NCDEQ SWSL 15A NCAC 2L Soild Waste GWP ST MW-26 MW-27 MW-28 1,1-Dichloroethane 5 6 NE 0.70 J Tetrachloroethene 1 0.7 NE 0.50 J 8.9 Tetrahydrofuran NE NE NE 3.1 Trichloroethene 1 3 NE 0.55 J Vinyl Chloride 1 0.03 NE 0.84 J EPA Appendix I Metals Method 6010B/6020 (µg/L) Barium 100 700 NE 117 121 114 Beryllium 1 NE 4 0.439 J Cadmium 1 2 NE 1.11 Chromium 10 10 NE 3.83 J 1.50 J Cobalt 10 NE 1 1.11 J 12.0 2.48 J Copper 10 1000 NE 4.48 J 1.79 J Iron 300 300 NE 576 430 25.8 J Manganese 50 50 NE 13.0 J 1,620 26.1 J Nickel 50 100 NE 18.8 J 4.94 J Thallium 5.5 NE 0.28 0.268 J 0.148 J Vanadium 25 NE 0.3 1.86 J 3.17 J Zinc 10 1000 NE 5.92 J 20.6 9.72 J Classical Chemistry Compounds (mg/L) Chloride NE 250 NE 3.6 J 17 Sulfate as SO4 250 250 NE 3.5 J 84 J Total Dissolved Solids NE 500 NE 220 Total Alkalinity NE NE NE 35 64 15 S&ME Project No. 1356-07-004 Lincoln County Landfill October 2017 - Detected Analytes in Monitoring Wells for C&D Phase 1 Table 7 EPA Appendix I Volatile Organic Compounds Method 8260 (µg/L) NCDEQ SWSL 15A NCAC 2L Soild Waste GWP ST MW-29 MW-30 MW-31 MW-36 EPA Appendix I Metals Method 6010B/6020 (µg/L) Barium 100 700 NE 20.5 J 80.8 J 5.71 J 67.7 J Beryllium 1 NE 4 0.433 J Chromium 10 10 NE 8.84 J 3.61 J Cobalt 10 NE 70 2.04 J Copper 10 1000 NE 6.93 J 2.20 J Iron 300 300 NE 52,400 347 10,000 1,410 Lead 10 15 NE 4.51 J Manganese 50 50 NE 203 55.1 38.5 J 18.2 J Nickel 50 100 NE 13.2 J 2.90 J 3.35 J Thallium 5.5 NE 0.28 0.145 J Vanadium 25 NE 0.3 4.24 J 2.09 J Zinc 10 1000 NE 14.2 19.2 4.47 J 8.34 J Classical Chemistry Compounds (mg/L) Chloride NE 250 NE 6 Sulfate as SO4 250 250 NE 5.6 J 8.7 J Total Dissolved Solids NE 500 NE 190 Total Alkalinity NE NE NE 150 25 S&ME Project No. 1356-07-004 Lincoln County Landfill October 2017 - Detected Analytes in Monitoring Wells for C&D Phase 2 Table 8 No Volatile Organic Compounds Detected in C&D Phase 2 in October 2017 EPA Appendix I Volatile Organic Compounds Method 8260 (µg/L) 15A NCAC 2B SW-1 SW-2 SW-3 SW-4 SW-5 SW-6 EPA Appendix I Metals Method 6010B/6020 (µg/L) Antimony 640 35.7 J 35.8 J Arsenic 50 7.32 J Barium 1,000 58.3 J 33.8 J 44.6 J 32.9 J Chromium 74 3.06 J 2.11 J 3.40 J 2.97 J Cobalt 270 1.27 J 4.48 J Copper 7 2.58 J 3.67 J 4.67 J Iron NE 2,760 1,270 3,160 612 1,020 Lead 25 3.87 J 3.93 J Manganese NE 171 74.6 315 66.7 49.7 J Nickel 88 3.15 J 3.34 J Thallium 0.47 0.260 J 0.180 J 0.137 J 0.137 J 0.126 J Vanadium NE 5.11 J 3.10 J 6.90 J 2.02 J 7.54 J Zinc 36 15.3 12.6 20.4 Classical Chemistry Compounds (mg/L) BOD NE NA NA NA NA NA 2.1 COD NE NA NA NA NA NA 26 Sulfate as SO4 NE NA NA NA NA NA 7.5 Phosphorous NE NA NA NA NA NA 0.085 J Nitrate as N NE NA NA NA NA NA 0.090 J Nitrate/Nitrite as N NE NA NA NA NA NA 0.090 J Total Suspended Solids NE NA NA NA NA NA 18 Total Alkalinity NE NA NA NA NA NA 15 Table 9 October 2017 - Detected Analytes in Surface Water Samples Lincoln County Landfill S&ME Project No. 1356-07-004 No Volatile Organic Compounds Detected in October 2017 EPA Appendix I Volatile Organic Compounds Method 8260 (µg/L) NCDEQ SWSL Lift Station EPA Appendix I Metals Method 6010B/6020 (µg/L) Arsenic 10 16.8 Barium 100 284 Chromium 10 3.70 J Cobalt 10 9.16 J Copper 10 Lead 10 3.41 J Nickel 50 16.1 J Thallium 5.5 4.66 JD Vanadium 25 2.35 J Zinc 10 6.93 J Classical Chemistry Compounds (mg/L) BOD NE 13 COD NE 180 Sulfate as SO4 250 7.0 J Phosphorous NE 0.150 Nitrate as N 10 0.180 J Nitrite as N 1000 0.150 J Nitrate/Nitrite as N NE 0.330 Total Alkalinity NE 550 D Total Suspended Solids NE 26 Table 10 October 2017 - Detected Analytes in Leachate Lincoln County Landfill S&ME Project No. 1356-07-004 No Volatile Organic Compounds Detected in October 2017 Notes: (1) SSI = Statistically Significant Increase (2) PA = One Way Parametric Analysis of Variance (Parametric ANOVA) The parametric ANOVA analysis is recommended by the 1992 guidance document for parameters with fewer than 15% non-detects in a specific well. (3) KW = Kruskal Wallis Non-Parametric Rank Analysis The Kruskal-Wallis method is recommended by the 1992 guidance document for parameters that have 15% to 90% non-detects in a specific well. (4) PL = Non-Parametric Inter-Well Prediction Limit Analysis The prediction limit was used for parameters with greater than 90% non-detects in a specific well. The 1992 guidance document recommends this method when a significant portion of the samples are non-detect. Notes for Tables 11 through 13 S&ME Project No. 1356-07-004 Statistical Percent Analysis Parameter Well ID Non-Detect Method SSI Comments 1,1,1-Trichloroethane MW-13 90%KW FALSE 1,1-Dichloroethane MW-13 2%P PA TRUE Concentrations have decreased over time MW-14 49%KW TRUE MW-16 25%KW TRUE Concentrations have decreased over time MW-17 78%KW FALSE MW-19 31%KW TRUE MW-20 36%KW TRUE 1,1-Dichloroethene MW-16 96%PL FALSE MW-19 98%PL FALSE 1,2-Dichloroethane MW-13 94%PL FALSE 1,4-Dichlorobenzene MW-13 53%KW TRUE MW-16 54%KW TRUE MW-17 87%KW FALSE MW-19 90%PL FALSE MW-20 83%KW FALSE 2-Butanone MW-13 98%PL FALSE Acetone MW-12 98%PL FALSE MW-13 51%KW TRUE Concentrations vary from non-detect to detect MW-14 96%PL FALSE MW-16 90%KW FALSE MW-17 73%KW FALSE MW-15 98%PL FALSE MW-9 98%PL FALSE MW-18 97%PL FALSE MW-19 95%PL FALSE MW-20 98%PL FALSE Antimony MW-12 96%PL FALSE MW-13 90%KW FALSE MW-14 53%KW FALSE MW-16 94%PL FALSE MW-10 91%PL FALSE MW-8 93%PL FASLSE MW-9 74%KW FALSE MW-18 90%PL FALSE MW-19 55%KW FALSE MW-20 93%PL FALSE Arsenic MW-12 84%KW FALSE MW-13 47%KW TRUE Concentrations vary from non-detect to detect MW-14 94%PL FALSE MW-16 56%KW TRUE MW-17 96%PL FALSE MW-10 91%PL FALSE MW-15 91%PL FALSE MW-8 89%KW FALSE MW-9 94%PL FALSE MW-18 90%PL FALSE MW-19 90%PL FALSE MW-20 83%KW FALSE Table 11 October 2017 Statistical Analysis for Phase 1 and Area "E" Lincoln County Landfill S&ME Project No. 1356-07-004 Page 1 of 6 Statistical Percent Analysis Parameter Well ID Non-Detect Method SSI Comments Table 11 October 2017 Statistical Analysis for Phase 1 and Area "E" Lincoln County Landfill S&ME Project No. 1356-07-004 Barium MW-12 37%KW TRUE MW-13 33%KW TRUE MW-14 43%KW FALSE MW-16 33%KW TRUE MW-17 33%KW TRUE MW-10 23%KW TRUE MW-15 22%KW TRUE MW-8 39%KW FALSE MW-9 33%KW FALSE MW-18 31%KW FALSE MW-19 48%KW FALSE MW-20 31%KW FALSE Benzene MW-13 33%KW TRUE MW-16 50%KW TRUE MW-17 84%KW FALSE MW-19 62%KW TRUE MW-20 69%KW FALSE Beryllium MW-12 61%KW FALSE MW-13 69%KW FALSE MW-14 98%PL FALSE MW-16 79%KW FALSE MW-17 56%KW FALSE MW-10 59%KW FALSE MW-15 39%KW TRUE Concentrations have decreased over time MW-8 56%KW TRUE MW-9 90%KW FALSE MW-18 86%KW FALSE MW-19 95%PL FALSE MW-20 79%KW FALSE cis-1,2-Dichloroethene MW-13 45%KW TRUE MW-16 48%KW TRUE MW-17 87%KW FALSE MW-19 55%KW TRUE MW-20 62%KW TRUE cis-1,3-Dichloropropene MW-12 98%PL FALSE Cadmium MW-12 71%KW FALSE MW-13 76%KW FALSE MW-14 75%KW FALSE MW-16 75%KW FALSE MW-17 78%KW FALSE MW-10 77%KW FALSE MW-15 76%KW FALSE MW-8 75%KW FALSE MW-9 90%KW FALSE MW-18 90%PL FALSE MW-19 98%KW FALSE MW-20 88%KW FALSE Chlorobenzene MW-13 88%KW FALSE MW-16 58%KW TRUE Chloroethane MW-13 35%KW TRUE Concentrations vary from non-detect to detect MW-16 60%KW TRUE Concentrations vary from non-detect to detect MW-19 95%PL FALSE MW-20 81%KW FALSE Chloromethane MW-10 97%PL FALSE MW-12 98%PL FALSE MW-13 98%PL FALSE MW-16 98%PL FALSE MW-9 98%PL FALSE MW-20 98%PL FALSE Page 2 of 6 Statistical Percent Analysis Parameter Well ID Non-Detect Method SSI Comments Table 11 October 2017 Statistical Analysis for Phase 1 and Area "E" Lincoln County Landfill S&ME Project No. 1356-07-004 Chromium MW-12 80%KW FALSE MW-13 45%KW FALSE MW-14 82%KW FALSE MW-16 52%KW FALSE MW-17 49%KW FALSE MW-10 MW-15 MW-8 MW-9 33%KW FALSE MW-18 76%KW FALSE MW-20 83%KW FALSE Cobalt MW-12 29%KW TRUE MW-13 0%ANOVA TRUE MW-14 73%KW FALSE MW-16 8%ANOVA FALSE MW-17 38%KW TRUE MW-10 32%KW FALSE MW-15 76%KW FALSE MW-8 32%KW TRUE MW-9 90%KW FALSE MW-18 60%KW FALSE MW-19 95%PL FALSE MW-20 62%KW FALSE Copper MW-12 71%KW FALSE MW-13 65%KW FALSE MW-14 41%KW FALSE MW-16 92%PL FALSE MW-17 60%KW FALSE MW-10 59%KW FALSE MW-15 78%KW FALSE MW-8 57%KW FALSE MW-9 67%KW FALSE MW-18 52%KW FALSE MW-19 76%KW FALSE MW-20 86%KW FALSE Ethylbenzene MW-13 80%KW FALSE MW-16 96%PL FALSE Page 3 of 6 Statistical Percent Analysis Parameter Well ID Non-Detect Method SSI Comments Table 11 October 2017 Statistical Analysis for Phase 1 and Area "E" Lincoln County Landfill S&ME Project No. 1356-07-004 Lead MW-12 88%KW FALSE MW-13 69%KW FALSE MW-14 94%PL FALSE MW-16 46%KW TRUE Non-Detect in April 2017 MW-17 82%KW FALSE MW-10 68%KW FALSE MW-15 74%KW FALSE MW-8 57%KW FALSE MW-9 88%KW FALSE MW-18 90%PL FALSE MW-19 95%PL FALSE MW-20 86%KW FALSE Methylene Chloride MW-12 98%PL FALSE MW-13 49%KW TRUE Concentrations have decreased over time MW-14 92%PL FALSE MW-16 60%KW TRUE Concentrations have been non-detect since Oct 2011 MW-17 87%KW FALSE MW-19 48%KW TRUE Concentrations have decreased over time MW-20 48%KW TRUE Concentrations have decreased over time Nickel MW-12 55%KW FALSE MW-13 45%KW FALSE MW-14 63%KW FALSE MW-16 52%KW FALSE MW-17 44%KW FALSE MW-10 68%KW FALSE MW-15 96%PL FALSE MW-8 61%KW FALSE MW-9 98%PL FALSE MW-18 62%KW FALSE MW-19 98%PL FALSE MW-20 83%KW FALSE Selenium MW-13 98%PL FALSE MW-16 88%KW FALSE MW-17 98%PL FALSE MW-10 95%PL FALSE MW-15 98%PL FALSE MW-8 96%PL FALSE MW-18 93%PL FALSE MW-19 98%PL FALSE MW-20 95%PL FALSE Page 4 of 6 Statistical Percent Analysis Parameter Well ID Non-Detect Method SSI Comments Table 11 October 2017 Statistical Analysis for Phase 1 and Area "E" Lincoln County Landfill S&ME Project No. 1356-07-004 Silver MW-12 96%PL FALSE MW-13 86%KW FALSE MW-14 96%PL FALSE MW-16 69%KW TRUE FIRST SSI OCTOBER 2017 MW-17 96%PL FALSE MW-10 93%PL FALSE MW-15 98%PL FALSE MW-8 96%PL FALSE MW-9 96%PL FALSE MW-19 95%PL FALSE t-1,2-Dichloroehthene MW-16 98%PL FALSE t-1,4-Dichlor-2-Butene MW-14 98%PL FALSE MW-19 98%PL FALSE Tetrachloroethene MW-13 47%KW TRUE MW-14 84%KW FALSE MW-17 69%KW TRUE FIRST SSI OCTOBER 2017 MW-19 48%KW TRUE MW-20 71%KW FALSE Thallium MW-12 63%KW FALSE MW-13 43%KW TRUE MW-14 90%KW FALSE MW-16 50%KW FALSE MW-17 84%KW FALSE MW-10 89%KW FALSE MW-15 89%KW FALSE MW-8 75%KW FALSE MW-18 60%KW FALSE MW-19 95%PL FALSE MW-20 95%PL FALSE Toluene MW-12 98%PL FALSE MW-13 69%KW TRUE Concentrations vary from non-detect to detect Trichloroethene MW-13 47%KW TRUE MW-14 86%KW FALSE MW-16 88%KW FALSE MW-17 80%KW FALSE MW-19 50%KW TRUE MW-20 71%KW TRUE FIRST SSI OCTOBER 2017 Trichlorofluoromethane MW-16 92%PL FALSE MW-17 93%PL FALSE MW-19 67%KW TRUE Concentrations vary from non-detect to detect Vanadium MW-12 84%KW FALSE MW-13 67%KW FALSE MW-14 84%KW FALSE MW-16 90%KW FALSE MW-17 69%KW FALSE MW-10 30%KW TRUE MW-15 65%KW FALSE MW-8 32%KW FALSE MW-9 60%KW FALSE MW-18 60%KW FALSE MW-19 81%KW FALSE MW-20 90%PL FALSE Page 5 of 6 Statistical Percent Analysis Parameter Well ID Non-Detect Method SSI Comments Table 11 October 2017 Statistical Analysis for Phase 1 and Area "E" Lincoln County Landfill S&ME Project No. 1356-07-004 Vinyl Chloride MW-12 98%PL FALSE MW-13 59%KW TRUE Non-Detect in April 2015 MW-16 27%KW TRUE Concentrations have decreased over time MW-20 83%KW FALSE Xylenes (Total)MW-13 40%KW TRUE MW-16 56%KW TRUE Concentrations vary from non-detect to detect MW-17 87%KW FALSE FIRST FALSE OCTOBER 2017 MW-19 67%KW TRUE FIRST SSI OCTOBER 2017 MW-20 74%KW FALSE Zinc MW-12 2%ANOVA TRUE Concentrations have decreased over time MW-13 37%KW FALSE MW-14 45%KW FALSE MW-16 35%KW FALSE MW-17 36%KW FALSE MW-10 27%KW FALSE MW-15 59%KW FALSE MW-8 36%KW FALSE MW-9 56%KW FALSE MW-18 52%KW FALSE MW-19 64%KW FALSE MW-20 62%KW FALSE Page 6 of 6 Statistical Percent Analysis Parameter Well ID Non-Detect Method SSI Comments Dichloroethane MW-25A 95%PL FALSE Butanone MW-25A 95%PL FALSE Acetone MW-21 85%KW FALSE MW-24 97%PL FALSE MW-25 97%PL FALSE MW-25A 87%KW FALSE Antimony MW-21 95%PL FALSE MW-24 97%PL FALSE MW-25 95%PL FALSE MW-25A 44%KW FALSE Arsenic MW-21 95%PL FALSE MW-24 87%KW FALSE MW-25 89%KW FALSE MW-25A 85%KW FALSE Barium MW-21 31%KW FALSE MW-24 36%KW FALSE MW-25 38%KW TRUE MW-25A 31%KW FALSE Beryllium MW-21 51%KW FALSE MW-24 49%KW TRUE MW-25 54%KW FALSE MW-25A 87%KW FALSE Cadmium MW-21 90%KW FALSE MW-24 92%PL FALSE MW-25 84%KW FALSE MW-25A 87%KW FALSE Chloromethane MW-21 97%PL FALSE MW-25 97%PL FALSE MW-25A 97%PL FALSE Chromium MW-21 82%KW FALSE MW-24 79%KW FALSE MW-25 49%KW FALSE MW-25A 33%KW FALSE Cobalt MW-21 82%KW FALSE MW-24 87%KW FALSE MW-25 97%PL FALSE MW-25A 49%KW TRUE Copper MW-21 72%KW FALSE MW-24 74%KW FALSE MW-25 76%KW FALSE MW-25A 67%KW FALSE Lead MW-21 92%PL FALSE MW-24 97%PL FALSE MW-25A 95%PL FALSE Nickel MW-21 92%PL FALSE MW-24 74%KW FALSE MW-25 65%KW FALSE MW-25A 97%PL FALSE Selenium MW-21 97%PL FALSE MW-25 97%PL FALSE Table 12 October 2017 Statistical Analysis for Phase 2 Lincoln County Landfill S&ME Project No. 1356-07-004 Page 1 of 2 Statistical Percent Analysis Parameter Well ID Non-Detect Method SSI Comments Table 12 October 2017 Statistical Analysis for Phase 2 Lincoln County Landfill S&ME Project No. 1356-07-004 Silver MW-24 95%PL FALSE MW-25 97%PL FALSE MW-25A 97%PL FALSE Thallium MW-21 92%PL FALSE MW-24 69%KW FALSE MW-25 84%KW FALSE MW-25A 97%PL FALSE Vanadium MW-21 78%KW FALSE MW-24 90%KW FALSE MW-25 89%KW FALSE MW-25A 44%KW FALSE Zinc MW-21 59%KW FALSE MW-24 41%KW FALSE MW-25 43%KW FALSE MW-25A 46%KW FALSE Page 2 of 2 Statistical Percent Analysis Parameter Well ID Non-Detect Method SSI Comments Acetone MW-32 96%PL FALSE MW-33 96%PL FALSE MW-33A 93%PL FALSE MW-35 96%PL FALSE MW-35A 93%PL FALSE Antimony MW-32 93%PL FALSE MW-33 93%PL FALSE MW-33A 29%KW TRUE MW-35 85%KW FALSE MW-35A 46%KW FALSE Arsenic MW-32 89%KW FALSE MW-33 89%KW FALSE MW-33A 96%PL FALSE MW-35 92%PL FALSE MW-35A 86%KW FALSE Barium MW-32 7%PA FALSE MW-33 7%PA FALSE MW-33A 21%KW FALSE MW-35 8%PA FALSE MW-35A 7%PA FALSE Beryllium MW-32 48%KW FALSE MW-33 43%KW TRUE FIRST SSI OCTOBER 2017 MW-33A 96%PL FALSE MW-35 46%KW FALSE MW-35A 79%KW FALSE Cadmium MW-33A 86%KW FALSE MW-35A 96%PL FALSE Chloroform MW-33A 86%KW FALSE MW-35A 96%PL FALSE Chloromethane MW-32 96%PL FALSE MW-33 96%PL FALSE MW-35 96%PL FALSE MW-35A 96%PL FALSE Chromium MW-32 70%KW FALSE MW-33 93%PL FALSE MW-35 65%KW FALSE MW-35A 25%KW FALSE Cobalt MW-32 89%KW FALSE MW-33A 93%PL FALSE MW-35 54%KW FALSE MW-35A 93%PL FALSE Table 13 October 2017 Statistical Analysis for Phase 3 Lincoln County Landfill S&ME Project No. 1356-07-004 Page 1 of 2 Statistical Percent Analysis Parameter Well ID Non-Detect Method SSI Comments Table 13 October 2017 Statistical Analysis for Phase 3 Lincoln County Landfill S&ME Project No. 1356-07-004 Copper MW-32 63%KW FALSE MW-33 86%KW FALSE MW-33A 32%KW FALSE MW-35 73%KW FALSE MW-35A 68%KW FALSE Lead MW-32 52%KW FALSE MW-33 96%PL FALSE MW-33A 96%PL FALSE MW-35 92%PL FALSE Nickel MW-32 81%KW FALSE MW-33 96%PL FALSE MW-35 77%KW FALSE MW-35A 93%PL FALSE Selenium MW-32 93%PL FALSE MW-33 93%PL FALSE MW-35A 96%PL FALSE Silver MW-32 93%PL FALSE MW-33 96%PL FALSE MW-33A 96%PL FALSE Thallium MW-32 81%KW FALSE MW-33 89%KW FALSE MW-33A 96%PL FALSE MW-35 77%KW FALSE Vanadium MW-32 37%KW FALSE MW-33 93%PL FALSE MW-33A 79%KW FALSE MW-35 50%KW FALSE MW-35A 21%KW FALSE Zinc MW-32 30%KW FALSE MW-33 39%KW FALSE MW-33A 21%KW FALSE MW-35 19%KW FALSE MW-35A 35%KW FALSE Page 2 of 2 Appendix III – Well Sampling Logs and Laboratory Reports Surface Water and Leachate Samples Lincoln County Landfill S&ME Project 1356-07-004 Location Date Time Sampled Sample Observations SW-1 10/10/2017 14:25 NA SW-2 10/10/2017 15:45 NA SW-3 10/10/2017 15:55 Stagnant, slightly turbid SW-4 10/11/2017 9:25 NA SW-5 10/11/2017 9:15 NA Lift Station 10/11/2017 11:50 NA SW- 6 10/11/2017 11:35 Grass, freshly mowed, low water level Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-1A Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/9/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 0816 7.21 19.4 2.1 0819 6.82 17.9 4.2 0822 5.92 17.5 Final 6.3 0825 5.86 18.0 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Comments Lab 36 22 15 10/10/2017 12.68 2.1 25 Electric Water Level Probe Field-Cleaned Typhoon Pump Rainy 57.00 TOC 44.32 ENCO HCL 0900 disposable teflon bailer slightly turbid Appendix I Metals + Hg, Mn, Fe HNO3(1) 500 mL plastic bottle Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-8 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 Final Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab 31.00 Disposable Teflon Bailer Electric Water Level Probe TOC ENCO HCL HNO3 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-9 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/9/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 1143 5.78 19 5.5 1148 5.65 17.1 11.0 1153 5.61 17.00 Final 16.5 1158 5.57 16.8 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab TOC 37.05 70.50 Rainy 39 38 42 33.45 5.5 Electric Water Level Probe Field Cleaned Typhoon Pump ENCO NA HCL HNO3 40 10/10/2017 11:30 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-10R Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/9/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 1220 6.13 17.9 Final *Checked on 10/10/17 and still no recharge. Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab disposable teflon bailer ENCO HCL HNO3 155 0.98 Disposable Teflon Bailer Went dry - was only able to get approximately 1/4th of a bailer purged. Rainy 0.2 Electric Water Level Probe TOC 30.52 31.50 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-12 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/9/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 1305 5.91 19.1 0.6 1306 5.85 18.5 1.2 1307 5.81 18.3 Final 1.8 1308 5.82 18.1 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab TOC 14.79 18.50 Rainy 261 260 197 3.71 0.6 Electric Water Level Probe Disposable Teflon Bailer ENCO NA HCL HNO3 199 10/10/2017 1220 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-13 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/9/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 1350 19.2 19.2 1.2 1352 18.8 18.8 2.4 1354 18.7 18.7 Final 3.6 1357 18.1 18.1 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab 10/10/2017 0935 disposable teflon bailer ENCO NA HCL HNO3 279 280 281 7.02 Disposable Teflon Bailer 282 Rainy 1.2 Electric Water Level Probe TOC 33.48 40.50 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-14 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 1353 6.40 18.8 7.2 1359 5.95 17.5 14.4 1406 5.93 17.5 Final 21.6 1413 6.00 17.5 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab TOC 31.90 76.00 Rainy 130 125 112 44.10 7.2 Electric Water Level Probe Field Cleaned Typhoon Pump ENCO NA HCL HNO3 113 10/11/2017 0950 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-15 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 Final Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab disposable teflon bailer ENCO HCL HNO3 Disposable Teflon Bailer Electric Water Level Probe TOC 30.50 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-16R Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/9/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 0842 6.18 17.9 0.6 0844 6.30 17.9 1.2 0846 6.34 17.7 Final 1.8 0848 6.39 17.6 *Note - turbid and slight odor Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab TOC 17.89 21.60 Rainy 784 735 725 3.71 0.61 Electric Water Level Probe Disposable Teflon Bailer ENCO NA HCL HNO3 730 10/10/2017 0915 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-17R Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/9/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 1038 4.96*18.3 0.5 1040 4.65*18.0 1.0 1041 4.62*17.9 Final 1.5 1043 3.29*17.9 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab 10/10/2017 1230 disposable teflon bailer * = pH meter malfunction, replaced for next well ENCO NA HCL HNO3 93 61 60 3.18 Disposable Teflon Bailer 57 Rainy 0.5 Electric Water Level Probe TOC 44.32 47.50 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-18 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/9/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 0925 6.36 17.5 1.9 0930 6.14 17.3 3.8 Final 5.7 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab TOC 20.65 32.00 Rainy 11.35 1.9 Electric Water Level Probe Disposable Teflon Bailer 140 Dry at approximately 2.2 gallons. 142 ENCO NA HCL HNO3 10/10/2017 1010 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-19 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/9/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 0920 6.34 18.1 7.3 0926 6.30 16.1 14.6 0931 6.21 15.9 Final 21.9 0938 6.22 16.0 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab 10/10/2017 1015 disposable teflon bailer ENCO NA HCL HNO3 123 127 125 44.40 Field Cleaned Typhoon Pump 133 Rainy 7.3 Electric Water Level Probe TOC 27.60 72.00 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-20 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/9/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 0857 6.24 17.3 1.7 0902 5.91 17.2 3.4 0905 5.68 17.4 Final 5.1 0908 5.69 17.3 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab TOC 16.61 27.00 Rainy 173 156 139 10.39 1.7 Electric Water Level Probe Disposable Teflon Bailer ENCO NA HCL HNO3 123 0920 10/10/2017 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-21 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/9/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 1013 6.09 17.3 0.6 1014 6.05 17.1 1.2 1016 6.03 16.9 Final 1.8 1018 6.06 17.0 * Dead insects in water, odor Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab 10/10/2017 1025 disposable teflon bailer ENCO some organics present HCL HNO3 122 109 103 3.39 Disposable Teflon Bailer 105 Rainy Well cap off - broken protective cover 0.6 Electric Water Level Probe TOC 40.72 44.11 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-24 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/9/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 1237 5.29 19.9 0.6 1239 5.30 18.7 1.2 1241 5.21 18.5 Final 1.8 1243 5.20 18.5 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab TOC 28.11 31.60 Rainy 262 261 260 3.49 0.6 Electric Water Level Probe Disposable Teflon Bailer ENCO NA HCL HNO3 252 10/10/2017 1210 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-25 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/9/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 Final Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab disposable teflon bailer ENCO HCL HNO3 Disposable Teflon Bailer Rainy Electric Water Level Probe TOC 31.50 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-25A Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 1145 5.99 20.4 4.5 1150 5.90 18.7 9.0 1155 5.93 18.4 Final 13.5 1200 5.92 18.4 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab TOC 32.70 60.00 Rainy 135 160 153 27.30 4.5 Electric Water Level Probe Field Cleaned Typhoon Pump ENCO NA HCL HNO3 152 10/11/2017 1015 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-26 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 1518 5.71 19.2 1.3 1520 5.57 18.4 2.6 1523 5.62 18.3 Final 3.9 1526 5.58 18.2 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs & THF (3) 40 mL glass vials Appendix I Metals + Hg, Mn, Fe(1) 250 mL plastic bottle Comments Lab 1100 disposable teflon bailer ENCO NA HCL HNO3 95 Alkalinity/TDS/ Chloride/Sulfate (1) 250 mL plastic bottle Rainy 1.3 None 10/11/2017 Disposable Teflon Bailer 94 Electric Water Level Probe TOC 15.10 23.00 7.90 107 103 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-27 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 1445 5.12 18.6 1.3 1448 5.11 17.9 2.6 1451 5.11 17.5 Final 3.9 1454 5.18 17.1 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs & THF (3) 40 mL glass vials Appendix I Metals + Hg, Mn, Fe(1) 250 mL plastic bottle Comments Lab 372 Cloudy Alkalinity/TDS/ Chloride/Sulfate (1) 250 mL plastic bottle None 7.72 1.3 382 337 370 Disposable Teflon Bailer TOC 19.28 27.00 Electric Water Level Probe ENCO NA HCL HNO3 10/11/2017 1110 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-28 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/9/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 1315 4.78 19.3 1.4 1318 4.79 19.1 2.8 1320 4.71 18.9 Final 4.2 1322 4.70 18.9 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs & THF (3) 40 mL glass vials Appendix I Metals + Hg, Mn, Fe(1) 250 mL plastic bottle Comments Lab 1245 disposable teflon bailer ENCO NA HCL HNO3 43 Alkalinity/TDS/ Chloride/Sulfate (1) 250 mL plastic bottle Rainy 1.4 None 10/10/2017 Disposable Teflon Bailer 39 Electric Water Level Probe TOC 46.25 54.50 8.25 48 45 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-29 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/9/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 1505 5.57 18.7 0.2 1506 5.61 18.5 0.4 1507 5.63 18.5 Final 0.6 1508 5.57 18.3 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs & THF (3) 40 mL glass vials Appendix I Metals + Hg, Mn, Fe(1) 250 mL plastic bottle Comments Lab 1305 disposable teflon bailer ENCO NA HCL HNO3 305 Alkalinity/TDS/ Chloride/Sulfate (1) 250 mL plastic bottle Rainy 0.2 None 10/10/2017 Disposable Teflon Bailer 311 Electric Water Level Probe TOC 43.52 45.00 1.48 319 300 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-30 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 1339 5.54 16.9 1.4 1344 5.54 17.1 2.8 1347 5.59 16.7 Final 4.2 1351 5.62 17.0 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs & THF (3) 40 mL glass vials Appendix I Metals + Hg, Mn, Fe(1) 250 mL plastic bottle Comments Lab 1040 disposable teflon bailer ENCO NA HCL HNO3 35 Alkalinity/TDS/ Chloride/Sulfate (1) 250 mL plastic bottle Cloudy 1.4 None 10/11/2017 Disposable Teflon Bailer 71 Electric Water Level Probe TOC 55.45 64.00 8.55 47 55 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-31 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 1408 5.67 17.4 1.2 1411 5.51 17.3 2.4 1415 5.57 17.1 Final 3.6 1418 5.60 16.8 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs & THF (3) 40 mL glass vials Appendix I Metals + Hg, Mn, Fe(1) 250 mL plastic bottle Comments Lab 1055 disposable teflon bailer ENCO NA HCL HNO3 54 Alkalinity/TDS/ Chloride/Sulfate (1) 250 mL plastic bottle Cloudy 1.2 None 10/11/2017 Disposable Teflon Bailer 52 Electric Water Level Probe TOC 32.64 40.00 7.36 72 54 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-32R Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/9/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 0957 6.22 17.1 1.3 0959 5.82 17.3 2.6 1002 5.80 17.2 Final 3.9 1004 5.75 17.0 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottles Comments Lab TOC 19.82 28.05 Rainy 43 43 38 8.23 Disposable Teflon Bailer 1.3 Electric Water Level Probe ENCO NA HCL HNO3 44 10/10/2017 1035 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-33 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/9/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1430 5.36 19.3 1.3 1432 6.01 18.7 Final Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottles Comments Lab 10/10/2017 1040 disposable teflon bailer ENCO NA HCL HNO3 91 7.66 Disposable Teflon Bailer Dry after approximately 1.3 gallons. Rainy 1.3 Electric Water Level Probe TOC 17.64 25.30 87 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-33A Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 1035 6.49 18.3 7.3 1040 6.75 16.7 14.6 1046 6.90 16.5 Final 21.9 1052 6.85 16.4 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottles Comments Lab TOC 17.41 64.55 Rainy 227 256 261 47.14 Field Cleaned Typhoon Pump 7.7 Electric Water Level Probe ENCO NA HCL HNO3 253 10/11/2017 1000 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-35 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/9/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 1105 3.05 18.1 0.2 DRY after a quarter of a bailer - pH was off and tried to 0.4 measure with new instrument but no water left in well. Final 0.6 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottles Comments Lab Rainy 101 1.38 Disposable Teflon Bailer 0.2 Electric Water Level Probe TOC 35.87 37.25 ENCO HCL HNO3 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-35A Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/9/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 1103 6.62 17.4 5.3 1106 6.67 17.1 10.6 1111 6.63 17.1 Final 15.9 1120 6.61 16.9 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottles Comments Lab 10/10/2017 120 disposable teflon bailer ENCO NA HCL HNO3 51 50 49 32.17 Field Cleaned Typhoon Pump 49 Rainy 5.3 Electric Water Level Probe TOC 37.52 69.69 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-36 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0.0 1320 5.55 18.2 1.1 1322 5.30 16.3 2.2 1325 5.34 16.2 Final 3.3 1327 5.40 15.6 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs & THF (3) 40 mL glass vials Appendix I Metals + Hg, Mn, Fe(1) 250 mL plastic bottle Comments Lab Slightly turbid at end of sampling ENCO HCL HNO3 Alkalinity/TDS/ Chloride/Sulfate (1) 250 mL plastic bottle None 22 22 22 10/11/2017 1030 disposable teflon bailer 30.23 36.68 6.45 Electric Water Level Probe Disposable Teflon Bailer 29 Cloudy TOC 1.1 Appendix IV – Statistical Analysis Procedures Appendix V – Graphs Depicting Concentrations over Time for Wells with a Statistically Significant Increase 0 10 20 30 40 50 60 70 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date 1,1 - Dichloroethane Phase 1 and Area "E" Wells With SSI MW-13 MW-14 MW-16 MW-19 MW-20 Note: Non-DetectValues are Set at Method Detection Limits 0 1 2 3 4 5 6 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date 1,4 - Dichlorobenzene Phase 1 and Area "E" Wells With SSI MW-13 MW-16 Note: Non-DetectValues are Set at Method Detection Limits 0 100 200 300 400 500 600 700 800 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Acetone Phase 1 and Area "E" Wells With SSI MW-13 Note: Non-DetectValues are Set at Method Detection Limits 0 10 20 30 40 50 60 70 80 90 100 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Arsenic Phase 1 and Area "E" Wells With SSI MW-13 MW-16 Note: Non-DetectValues are Set at Method Detection Limits 0 2000 4000 6000 8000 10000 12000 14000 16000 18000 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Barium Phase 1 and Area "E" Wells With SSI MW-15 MW-16 MW-10 MW-12 MW-13 MW-17 Note: Non-DetectValues are Set at Method Detection Limits 0 2 4 6 8 10 12 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Benzene Phase 1 and Area "E" Wells With SSI MW-13 MW-16 MW-19 Note: Non-DetectValues are Set at Method Detection Limits 0 5 10 15 20 25 30 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Beryllium Phase 1 and Area "E" Wells With SSI MW-15 MW-8 Note: Non-DetectValues are Set at Method Detection Limits 0 2 4 6 8 10 12 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date cis-1,2-Dichloroethane Phase 1 and Area "E" Wells With SSI MW-13 MW-16 MW-19 MW-20 Note: Non-DetectValues are Set at Method Detection Limits 0 1 2 3 4 5 6 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Chlorobenzene Phase 1 and Area "E" Wells With SSI MW-16 Note: Non-DetectValues are Set at Method Detection Limits 0 5 10 15 20 25 30 35 40 45 50 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Chloroethane Phase 1 and Area "E" Wells With SSI MW-13 MW-16 Note: Non-DetectValues are Set at Method Detection Limits 0 100 200 300 400 500 600 700 800 900 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Cobalt Phase 1 and Area "E" Wells With SSI MW-12 MW-13 MW-17 MW-8 Note: Non-DetectValues are Set at Method Detection Limits 0 10 20 30 40 50 60 70 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Lead Phase 1 and Area "E" Wells With SSI MW-16 Note: Non-DetectValues are Set at Method Detection Limits 0 10 20 30 40 50 60 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Methylene Chloride Phase 1 and Area "E" Wells With SSI MW-13 MW-16 MW-19 MW-20 Note: Non-DetectValues are Set at Method Detection Limits 0 10 20 30 40 50 60 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Silver Phase 1 and Area "E" Wells With SSI MW-16 Note: Non-DetectValues are Set at Method Detection Limits 0 1 2 3 4 5 6 7 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Tetrachloroethene Phase 1 and Area "E" Wells With SSI MW-13 MW-19 MW-17 Note: Non-DetectValues are Set at Method Detection Limits 0 5 10 15 20 25 30 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Thallium Phase 1 and Area "E" Wells With SSI MW-13 Note: Non-DetectValues are Set at Method Detection Limits 0 2 4 6 8 10 12 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Toluene Phase 1 and Area "E" Wells With SSI MW-13 Note: Non-DetectValues are Set at Method Detection Limits 0 1 2 3 4 5 6 7 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Trichloroethene Phase 1 and Area "E" Wells With SSI MW-13 MW-19 MW-20 Note: Non-DetectValues are Set at Method Detection Limits 0 1 2 3 4 5 6 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Trichlorofluoromethane Phase 1 and Area "E" Wells With SSI MW-19 Note: Non-DetectValues are Set at Method Detection Limits 0 100 200 300 400 500 600 700 800 900 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Vanadium Phase 1 and Area "E" Wells With SSI MW-10 Note: Non-DetectValues are Set at Method Detection Limits 0 5 10 15 20 25 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Vinyl Chloride Phase 1 and Area "E" Wells With SSI MW-13 MW-16 Note: Non-DetectValues are Set at Method Detection Limits 0 5 10 15 20 25 30 35 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Total Xylenes Phase 1 and Area "E" Wells With SSI MW-13 MW-16 MW-17 MW-19 Note: Non-DetectValues are Set at Method Detection Limits 0 1000 2000 3000 4000 5000 6000 7000 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Zinc Phase 1 and Area "E" Wells With SSI MW-12 Note: Non-DetectValues are Set at Method Detection Limits 0 100 200 300 400 500 600 1/1/1999 9/27/2001 6/23/2004 3/20/2007 12/14/2009 9/9/2012 6/6/2015 3/2/2018 11/26/2020Concentration (ug/L)Date Barium Phase 2 Wells With SSI MW-25 Note: Non-DetectValues are Set at Method Detection Limits 0 0.5 1 1.5 2 2.5 1/1/1999 9/27/2001 6/23/2004 3/20/2007 12/14/2009 9/9/2012 6/6/2015 3/2/2018 11/26/2020Concentration (ug/L)Date Beryllium Phase 2 Wells With SSI MW-24 Note: Non-DetectValues are Set at Method Detection Limits 0 5 10 15 20 25 30 35 1/1/1999 9/27/2001 6/23/2004 3/20/2007 12/14/2009 9/9/2012 6/6/2015 3/2/2018 11/26/2020Concentration (ug/L)Date Cobalt Phase 2 Wells With SSI MW-25A Note: Non-DetectValues are Set at Method Detection Limits 0 5 10 15 20 25 30 35 1/14/2004 10/10/2006 7/6/2009 4/1/2012 12/27/2014 9/22/2017 6/18/2020Concentration (ug/L)Date Antimony Phase 3 Wells With SSI MW-33A Note: Non-DetectValues are Set at Method Detection Limits 0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 1/14/2004 10/10/2006 7/6/2009 4/1/2012 12/27/2014 9/22/2017 6/18/2020Concentration (ug/L)Date Antimony Phase 3 Wells With SSI MW-33 Note: Non-DetectValues are Set at Method Detection Limits Appendix VI – Monthly Methane Data (April 2017 – October 2017) LEGENDWWW.SMEINC.COM1METHANE MONTORING LOCATIONS LINCOLN COUNTY LANDFILL CROUSE, NORTH CAROLINA LIFTSTATIONSCALEHOUSESHOPAREA