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HomeMy WebLinkAbout5503_LincolnCountyMSWLF_GWMR_20170803 April 2017 Semi-Annual Monitoring Report Lincoln County Landfill - Permit # 55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 Prepared for: Lincoln County 5291 Crouse Road Crouse, North Carolina 28033 Prepared by: S&ME, Inc. 9751 Southern Pine Boulevard Charlotte, NC 28273 August 3, 2017 S&ME, Inc. | 9751 Southern Pine Boulevard | Charlotte, NC 28273 | p 704.523.4726 | f 704.525.3953 | www.smeinc.com August 3, 2017 Lincoln County 5291 Crouse Road Crouse, North Carolina 28033 Attention: Mr. Mark Bivins Reference: April 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit # 55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 Dear Mr. Bivins: S&ME Inc. (S&ME) has completed the April 2017 Semi-Annual Monitoring and Reporting for the Lincoln County Landfill. This report presents the results of the second monitoring event of the year for the facility. S&ME appreciates the continued opportunity to provide services to you and Lincoln County. If you have any questions or need additional information regarding this report, please contact us at (704) 523-4726. Sincerely, S&ME, Inc. Jasmine Tayouga, E.I. Julie P. Robertson, P.G. Staff Professional Project Manager/Senior Geologist NC Registration No. 1995 Cc: Jaclynne Drummond, NCDENR – Solid Waste Section April 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit # 55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 August 3, 2017 ii Table of Contents 1.0 Introduction ............................................................................................................ 1 2.0 Groundwater Levels and Flow............................................................................ 1 3.0 Analytical Data ...................................................................................................... 1 3.1 Groundwater Monitoring and Sampling ...................................................................... 1 3.1.1 MSW Area “E” and Phase 1 ............................................................................................... 1 3.1.1.1 Volatile Organic Compounds (VOCs) ........................................................................... 2 3.1.1.2 Inorganic Constituents (Metals) ..................................................................................... 3 3.1.2 MSW Phase 2 ...................................................................................................................... 4 3.1.2.1 Volatile Organic Compounds (VOCs) ........................................................................... 4 3.1.2.2 Inorganic Constituents (Metals) ..................................................................................... 4 3.1.3 MSW Phase 3 ...................................................................................................................... 4 3.1.3.1 Volatile Organic Compounds (VOCs) ........................................................................... 4 3.1.3.2 Inorganic Constituents (Metals) ..................................................................................... 4 3.1.4 C&D Landfill Phase 1 and 2 ............................................................................................... 5 3.1.4.1 Inorganic Constituents (Metals) ..................................................................................... 5 3.1.4.2 Classical Chemistry Compounds ................................................................................... 6 3.2 Surface Water Sampling .................................................................................................. 6 3.2.1 Surface Water Locations SW-1 through SW-5 ................................................................... 6 3.2.2 Surface Water Location SW-6 ............................................................................................. 6 3.3 Leachate Sampling............................................................................................................ 6 4.0 Statistical Analysis ................................................................................................ 7 4.1 Volatile Organic Compounds (VOCs) ........................................................................... 7 4.2 Total Metals ....................................................................................................................... 8 5.0 Methane Readings ................................................................................................. 8 April 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit # 55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 August 3, 2017 iii Appendices Appendix I – Drawings Appendix II –Tables Appendix III – Well Sampling Logs and Laboratory Reports Appendix IV – Statistical Analysis Procedures Appendix V – Graphs Depicting Concentrations over Time for Wells with a Statistically Significant Increase Appendix VI – Monthly Methane Data (October 2016 – April 2017) April 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit # 55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 August 3, 2017 1 1.0 Introduction S&ME, Inc. (S&ME) was contracted by Lincoln County to provide groundwater, surface water, and leachate monitoring services at the Lincoln County Landfill located at 5291 Crouse Road in Crouse, North Carolina. This semi-annual monitoring event was conducted on April 10th through 12th, 2017. This report presents the results of the first semi-annual sampling event for the year 2017 at the facility. The facility’s monitoring network includes one background well (MW-1A), twenty-eight compliance wells, six (6) surface water sample locations, and one leachate sample. The next sampling event is scheduled for October 2017 and will include wells associated with the newly constructed Phase 4. 2.0 Groundwater Levels and Flow The water table elevations and our interpretation of the groundwater surface expressed as a potentiometric map along with groundwater flow direction are shown on Drawing 1 of 1 in Appendix I. Based upon the groundwater elevations in the vicinity of the landfill, groundwater in this area is projected to flow primarily to the south, with secondary flow toward the southwest and southeast toward tributaries located east and west of the landfills. Groundwater levels for the monitoring wells are presented in Table 1 in Appendix II. The hydraulic gradient (i) in the vicinity of each well was estimated by calculating the vertical difference between the groundwater elevation at each well and one or more nearby contour lines from Drawing 1 of 1. This value was then divided by the horizontal distance measured from the well to the selected groundwater elevation contour line. Groundwater velocity was calculated by multiplying the gradient (i) by the hydraulic conductivity (k) and dividing by the estimated effective porosity (ne) of the aquifer. Table 2 in Appendix II summarizes the groundwater flow rates for the monitoring wells. 3.0 Analytical Data Analytical results for the landfill monitoring wells, surface water samples, and leachate sample are summarized in Tables 4 through 10 in Appendix II. Detections above the NCAC 2L .0202 Groundwater Quality Standards (2L Standards), NCAC 2B surface water standards (2B Standards), and/or SW GWP Standard are highlighted in gray. Field measurements of pH, conductivity, and temperature are summarized in Table 3 in Appendix II. Well sampling logs containing this information are included in Appendix III. 3.1 Groundwater Monitoring and Sampling 3.1.1 MSW Area “E” and Phase 1 MSW Area “E” and Phase 1 groundwater monitoring well locations were sampled for Appendix I volatile organic compounds (VOCs) and Appendix I metals. In addition to Appendix I VOCs and metals, the groundwater analysis for background monitoring well MW-1A also included inorganic constituents iron and manganese. A summary of the detected analytes associated with this Phase of the landfill is included as Table 4 in Appendix II. The groundwater monitoring wells associated with these areas include April 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit # 55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 August 3, 2017 2 background well MW-1A, compliance wells MW-8, MW-9, and MW-10R that monitor the abandoned leachate pond, and compliance wells MW-12 through MW-20 that monitor down gradient and side gradient of the unlined MSW landfill Area “E” and the lined MSW landfill identified as Phase 1. During the April 2017 sampling event it was discovered that MW-15 was damaged and could not be sampled. Lincoln County was notified of the damage and the well will be replaced. Based on the laboratory analytical reports included in Appendix III, fifteen VOCs and fifteen metals were detected in MSW Area “E” and Phase 1 groundwater monitoring wells during the April 2017 monitoring event. During the April 2017 monitoring even MW-8 was dry, and therefore not sampled. 3.1.1.1 Volatile Organic Compounds (VOCs) Background monitoring well MW-1A had a detection of Chloroform at a concentration of 16 micrograms per liter (µg/L), which is below the 2L Standard of 70 µg/L. Both Bromoform and Chloroform have historically been detected in monitoring well MW-1A which are commonly associated with chlorinated municipal water. Due to MW-1A’s close proximity to Crouse Road, it is likely that the detection of Chloroform in the well is from a leaking nearby municipal water or sewer line. No VOCs were detected in groundwater monitoring wells MW-9, MW-10R, MW-12, MW-18, and MW-20 during the April 2017 monitoring event. Monitoring wells MW-13, MW-14, MW-16R, MW-17R, and MW-19 contained two or more of the fifteen VOCs detected. Of the VOCs detected, five compounds were detected above their respective 2L Standard: 1,1-Dichloroethane, Benzene, Methylene Chloride, Tetrachloroethene, and Vinyl Chloride. Please note that groundwater monitoring well MW-14 had no VOC detections above its respective 2L Standards. The analytical results for groundwater monitoring well MW-13 indicated that 1,1-Dichloroethane, Benzene, Tetrachloroethene, and Vinyl Chloride were detected above their respective 2L Standards. The results of which are as follows:  1,1-Dichloroethane detected at 17 µg/L. 2L Standard is 6 µg/L.  Benzene detected at 5.5 µg/L. 2L Standard is 1 µg/L.  Tetrachloroethene detected at 2.6 µg/L. 2L Standard is 0.7 µg/L.  Vinyl Chloride detected at 1.5 µg/L. 2L Standard is 0.3 µg/L. The results for groundwater monitoring well MW-16R indicated that Benzene and Vinyl Chloride were detected above their respective 2L Standard. The results of which are as follows:  Benzene detected at 6.7 µg/L. 2L Standard is 1 µg/L.  Vinyl chloride detected at 4.6 µg/L. 2L Standard is 0.03 µg/L. The results for groundwater monitoring well MW-17R indicated that 1,1-Dichloroethane, Benzene, and Methylene Chloride were detected above their respective 2L Standard. The results of which are as follows:  1,1-Dichloroethane detected at 8.2 µg/L. 2L Standard is 6 µg/L.  Benzene detected at 5.3 µg/L. 2L Standard is 1 µg/L.  Methylene Chloride at 55 µg/L. 2L Standard is 5 µg/L. The results for groundwater monitoring well MW-19 indicated that 1,1-Dichloroethane, Benzene, Methylene Chloride, and Tetrachloroethene were detected above their respective 2L Standard. The results are as follows: April 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit # 55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 August 3, 2017 3  1,1-Dichloroethane detected at 19 µg/L. 2L Standard is 6 µg/L.  Benzene detected at 2.4 µg/L. 2L Standard is 1 µg/L.  Methylene Chloride detected at 5.3 µg/L. 2L Standard is 5 µg/L.  Tetrachloroethene detected at 2.6 µg/L. 2L Standard is 0.7 µg/L. Groundwater monitoring wells MW-13, MW-14, MW-16R, MW-17R, MW-19 and MW-20 monitor down gradient and side gradient of the of the unlined Area “E” landfill, and the volatile organic constituents detected in these wells are associated with the unlined landfill section. 3.1.1.2 Inorganic Constituents (Metals) The groundwater monitoring wells associated with the MSW Area “E” and Phase 1 landfills had three or more Appendix I metals detected. Five constituents were detected above their respective 2L Standard or SW GWP Standard: Antimony, Arsenic, Cobalt, Iron, and Thallium.  Antimony was detected above its SW GWP Standard of 1 µg/L in background groundwater monitoring well MW-1A at a concentration of 1.03 J µg/L, and in compliance monitoring well MW-14 at a concentration of 5.75 µg/L.  Arsenic was detected above its 2L Standard of 10 µg/L in compliance monitoring well MW-13 at a concentration of 12.5 µg/L, and in compliance monitoring well MW-16R at a concentration of 17.9 µg/L.  Cobalt was detected above its SW GWP Standard of 70 µg/L in compliance monitoring wells MW- 12, MW-13, MW-14, MW-16R, MW-17R, MW-18, and MW-19 at concentrations ranging from 1.73 J µg/L to 276 µg/L.  Iron was detected above its 2L Standard of 300 µg/L in background monitoring well MW-1A at a concentration of 2,380 µg/L.  Thallium was detected above its SW GWP Standard of 0.28 µg/L in compliance monitoring wells MW-12, MW-13, MW-16R, MW-17R, and MW-18 at concentrations ranging from 0.333 J to 1.75 J µg/L.  Vanadium was detected above its SW GWP Standard of 0.3 µg/L in background monitoring well MW-1A, compliance monitoring wells MW-10R, MW-17R, and MW-18 at concentrations ranging from 2.36 J to 14.8 J µg/L. Total metal concentrations in groundwater sampled from wells are often dependent on the turbidity or suspended particulates (from the aquifer formation) retrieved with the groundwater sample. The turbidity is a function of the sampling method, well construction, how the well was developed, and the grain size/consolidation of the lithologic unit sampled. Since the unfiltered samples are acidified in the field at the time of collection, metals contained within the particulates are dissolved into the sample. Thus, the presence of turbidity in groundwater samples often results in elevated (false positive) analytical results for total metal concentrations. Therefore, the presence of elevated total metal concentrations does not necessarily correlate with groundwater impact. Based on historical water quality data, the background well and each of the compliance groundwater monitoring wells have contained at least one total metal at concentrations above the 2L Standards. Metal concentrations in several wells have fluctuated below and above detection limits. In background well MW- 1A, beryllium, cadmium, chromium, cobalt, iron, lead, silver, and vanadium have been detected at concentrations above the 2L Standards. Based on this data, it appears that the majority of the metals April 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit # 55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 August 3, 2017 4 detected within the monitoring wells are either naturally occurring or a product of turbidity during sampling. 3.1.2 MSW Phase 2 MSW Phase 2 groundwater monitoring well locations were sampled for Appendix I VOCs and Appendix I metals. A summary of the detected analytes associated with this Phase of the landfill is included as Table 5 in Appendix II. The groundwater monitoring wells associated with this Phase are compliance wells MW- 21 and MW-24 that monitor side gradient of the landfill and MW-25 and MW-25A that monitor the Phase 2 sump. 3.1.2.1 Volatile Organic Compounds (VOCs) No VOCs were detected above their respective 2L Standard or SW GWP Standard in the MSW Phase 2 monitoring wells during the April 2017 monitoring event. 2-Butanone and Acetone were both detected in MW-25A at respective concentrations of 0.42 J µg/L and 15 µg/L which are below their respective 2L and SW GWP Standards. 3.1.2.2 Inorganic Constituents (Metals) The groundwater monitoring wells associated with the Phase 2 landfill had five or more Appendix I metals detections, three of which were detected above its respective SW GWP Standard. Antimony was detected above the SW GWP Standard of 1 µg/L in groundwater monitoring well MW-25A at a concentration of 1.27 J µg/L. Cobalt was detected above the SW GWP Standard of 1 µg/L in groundwater monitoring wells MW-21 and MW-25A at concentrations of 2.15 J and 21.9 µg/L, respectively. Thallium was detected above the SW GWP Standard of 0.28 µg/L in groundwater monitoring wells MW-21, MW-24, MW-25, and MW-25A at concentrations ranging from 0.333 J to 0.654 J µg/L. As previously discussed above, it appears that the majority of the metals detected within the groundwater monitoring wells are either naturally occurring or a product of turbidity during sampling. 3.1.3 MSW Phase 3 MSW Phase 3 groundwater monitoring well locations were sampled for Appendix I VOCs and Appendix I metals. A summary of the detected analytes associated with this phase of the landfill is included in Table 6 in Appendix II. The groundwater monitoring wells associated with this area include compliance well MW-32R that monitors down gradient and side gradient of the landfill and MW-33/33A and MW-35/35A that monitor the Phase 3 sump locations. Monitoring well MW-34 that previously monitored downgradient of Phase 3 was abandoned during Phase 4 construction activities. 3.1.3.1 Volatile Organic Compounds (VOCs) No VOCs were detected in the MSW Phase 3 monitoring wells during the April 2017 monitoring event. 3.1.3.2 Inorganic Constituents (Metals) The groundwater monitoring wells associated with the Phase 3 landfill had four or more Appendix I metals detected, fourof which were detected above their respective 2L Standard or SW GWP Standard. The detections above standards are as follows: April 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit # 55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 August 3, 2017 5  Antimony was detected above the SW GWP Standard of 1 µg/L in groundwater monitoring well MW-33A at a concentration of 4.61 J µg/L.  Cobalt was detected above the SW GWP Standard of 1 µg/L in groundwater monitoring well MW- 35 at a concentration of 3.69 J µg/L.  Thallium was detected above the SW GWP Standard of 0.28 µg/L in groundwater monitoring well MW-33 at a concentrations of 0.491 J µg/L.  Vanadium was detected above the SW GWP Standard of 0.3 µg/L in groundwater monitoring wells MW-32R, MW-35, and MW-35A at concentrations ranging from 4.54 J to 15.7 J µg/L. As previously discussed above, it appears that the majority of the metals detected within the groundwater monitoring wells are either naturally occurring or a product of turbidity during sampling. 3.1.4 C&D Landfill Phase 1 and 2 C&D Landfill Phase 1 and Phase 2 groundwater monitoring well locations were sampled for Appendix I VOCs; Appendix I metals plus mercury, manganese, and iron; and four classical chemistry compounds: Chloride, Total Dissolved Solids, Sulfate, and Alkalinity. A summary of the detected analytes associated with the C&D Landfills is included as Table 7 and 8 in Appendix II. The groundwater monitoring wells associated with the C&D landfill include compliance wells MW-26, MW-27, and MW-28 that monitor Phase 1 and MW-29, MW-30, MW-31, and MW-36 that monitor Phase 2. Groundwater monitoring well MW-36 was installed near the C&D compliance boundary as part of the 2013 C&D Assessment. Volatile Organic Compounds (VOCs) C&D Landfill groundwater monitoring wells had five VOCs detected during the April 2017 monitoring event, two (2) of which were detected above their respective 2L Standard.  Tetrachloroethene was detected in groundwater monitoring well MW-28 at a concentration of 9.6 µg/L, which is above its 2L Standard of 0.7 µg/L.  Vinyl Chloride was detected in groundwater monitoring well MW-28 at a concentration of 1.2 µg/L, which is above its 2L Standard of 0.03 µg/L. 3.1.4.1 Inorganic Constituents (Metals) The groundwater monitoring wells associated with the C&D landfill had seven or more metals detections, and five (5) constituents were detected above their respective 2L Standard and/or SW GWP Standard. The detections above standards are as follows:  Cobalt was detected in groundwater monitoring wells MW-26, MW-27, and MW-28 at a concentrations ranging from 1.69 J to 10.6 µg/L which are above the SW GWP Standard of 1 µg/L.  Iron was detected in groundwater monitoring wells MW-26, MW-27, MW-29, MW-30, MW-31, and MW-36 at concentrations ranging from 516 to 40,200 µg/L, which are above the 2L Standard of 300 µg/L.  Manganese was detected in groundwater monitoring wells MW-26, MW-27 and MW-29 at concentrations ranging from 66.4 to 1,240 µg/L, which are above the 2L Standard of 50 µg/L.  Thallium was detected in groundwater monitoring wells MW-26 and MW-27 at concentrations of 0.371 J µg/L and 0.634 J µg/L, respectively, which are above the SW GWP Standard of 0.28 µg/L. April 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit # 55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 August 3, 2017 6  Vanadium was detected in groundwater monitoring wells MW-26, MW-27, and MW-29 at concentrations ranging from 1.50 J to 4.45 J µg/L, which are above the SW GWP Standard of 0.3 µg/L. As previously discussed above, it appears that the majority of the metals detected within the groundwater monitoring wells are either naturally occurring or a product of turbidity during sampling. Since October 2007, Iron and Manganese have been included in the analysis for the C&D wells, and since April 2008, Iron and Manganese were included in the analysis for the background well MW-1A. Iron and Manganese have been detected in MW-1A in each monitoring event that has included their analysis. 3.1.4.2 Classical Chemistry Compounds Total Dissolved Solids, Chloride, Sulfate, and Alkalinity were analyzed for in the C&D landfill groundwater monitoring wells. The results of the analyses are summarized in Tables 7 and 8 in Appendix II. Please note that none of the classical chemistry compounds analyzed for exceeded any of the established 2L Standards and/or SW GWP Standards. 3.2 Surface Water Sampling Lincoln County Landfill has five surface water sampling locations positioned in the tributaries located to the east, south, and west of the landfill as indicated on the attached Drawing 1 of 1 in Appendix I. The original five surface water samples are analyzed for Appendix I VOCs and Appendix I metals plus Mercury, Iron and Manganese. Beginning with the April 2010 sampling event, a sixth surface water sample location was added to the semi-annual monitoring plan, SW-6. The addition of SW-6 to the monitoring plan was in response to the January 2009 leachate release at the facility. SW-6 is located at the discharge of the lowland area downgradient from the leachate holding tanks as indicated on Drawing 1 of 1. A summary of the detected analytes associated with the surface water samples collected is included as Table 9 in Appendix II. 3.2.1 Surface Water Locations SW-1 through SW-5 No VOCs were detected in surface water sampling locations during the April 2017 sampling event. Five (5) or more metals were detected in surface water sampling locations SW-1, SW-2, SW-3, SW-4, and SW-5, one of which was detected at a concentration above its respective 2B Standard. Thallium was detected at SW-1 at a concentration of 0.501 J µg/L, which is above the 2B Standard of 0.47 µg/L. 3.2.2 Surface Water Location SW-6 No VOCs were detected in surface water sampling location SW-6 during the April 2017 sampling event. Eight (8) metals were detected in SW-6, none of which were detected at concentrations above their respective 2B Standard. 3.3 Leachate Sampling A sample of the leachate from the leachate collection system for the landfill was collected from the lift station prior to leachate entering the on-site leachate holding tanks. The leachate sample was analyzed for Appendix I VOCs, Appendix I metals, BOD, COD, Nitrate/Nitrite, Sulfate, TSS, and Phosphorous. A summary of the detected analytes for the leachate is included as Table 10 in Appendix II. April 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit # 55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 August 3, 2017 7 4.0 Statistical Analysis S&ME compared the water quality data with the 2L Standards and the SW GWP standards and performed a statistical evaluation of the data. S&ME utilized three (3) statistical methods to evaluate statistically significant increases between the compliance monitoring wells and the background monitoring well (MW- 1A). The first method utilized was a one-way parametric Analysis of Variance (Parametric ANOVA). The parametric ANOVA analysis is recommended by the 1992 guidance document for parameters with fewer than 15% non-detects in a specific well. The second method used was the Kruskal-Wallis non-parametric rank method. The Kruskal-Wallis method is recommended by the 1992 guidance document for parameters that have 15% to 90% non- detects in a specific well. The third method used was an inter-well non-parametric prediction limit. The prediction limit was used for parameters with greater than 90% non-detects in a specific well. The 1992 guidance document recommends this method when a significant portion of the samples are non-detect. Tables 11 through 13 in Appendix II summarize the results of the statistical analysis. Copies of the analytical procedures used to perform the analysis used by the ChemStat software are included in Appendix IV. 4.1 Volatile Organic Compounds (VOCs) One (1) or more volatile organic compounds were found to have a statistical increase over background concentrations in groundwater monitoring wells MW-13, MW-14, MW-16(16R), MW-17(17R), MW-19, and MW-20 that are located downgradient from the unlined closed landfill Area “E”. The statistical increases are as follows:  1,1-Dichloroethane in groundwater monitoring wells MW-13, MW-14, MW-16(16R), MW-19 and MW-20. It should be noted that concentrations of 1,1-Dichloroethene in MW-13 and MW-16 have decreased over time, and MW-20 had no detection of 1,1-Dichloroethane in April 2017.  1,4-Dichlorobenzene in groundwater monitoring wells MW-13 and MW-16(16R).  Acetone in groundwater monitoring well MW-13, which has ranged from non-detect to detect over time.  Benzene in groundwater monitoring wells MW-13, MW-16(16R), and MW-19. Reported concentrations over time have been generally stable.  cis-1,2-Dichloroethene in groundwater monitoring wells MW-13, MW-16(16R), MW-19 and MW- 20. Concentrations at these wells have been relatively stable, although a rising trend over time is noted at MW-16.  Chlorobenzene in groundwater monitoring well MW-16(16R).  Chloroethane in groundwater monitoring well MW-13. It should be noted that concentrations of Chloroethane in well MW-13 have decreased over time.  Methylene Chloride in groundwater monitoring wells MW-13, MW-16(16R), MW-19 and MW-20. It should be noted that concentrations of Methylene Chloride in wells MW-19 and MW-20 have decreased over time.  Tetrachloroethene in groundwater monitoring wells MW-13 and MW-19. Reported concentrations over time have been generally stable. April 2017 Semi-Annual Monitoring Report Lincoln County Landfill Permit # 55-03 Crouse, North Carolina S&ME Project No. 1356-07-004 August 3, 2017 8  Toluene in groundwater monitoring well MW-13.  Trichloroethene in groundwater monitoring wells MW-13 and MW-19. Reported concentrations over time have been generally stable.  Vinyl Chloride in groundwater monitoring wells MW-13 and MW-16(16R). Reported concentrations over time have been generally stable.  Total Xylenes in groundwater monitoring wells MW-13, MW-16(16R) and MW-17(17R). Reported concentrations over time have been generally stable in MW-13 and MW-17(17R); MW-16 concentrations vary from non-detect to detect. There were no volatile organic compounds with statistically significant increases over background for the Phase 2 and Phase 3 MSW wells. Graphs depicting concentrations over time for constituents with a statistical increase are provided in Appendix V. 4.2 Total Metals Total metal concentrations in groundwater sampled from wells are often dependent on the turbidity or suspended particulates (from the aquifer formation) retrieved with the groundwater sample. The turbidity is a function of the sampling method, well construction, how the well was developed, and the grain size/consolidation of the lithologic unit sampled. Since the unfiltered samples are acidified in the field at the time of sample collection, metals contained within the particulates are dissolved into the water sample. Thus, the presence of turbidity in groundwater samples often results in elevated (false positive) analytical results for total metal concentrations. Therefore, the presence of elevated total metal concentrations does not necessarily correlate with groundwater impact. Based on the historical water quality data, the background well and each of the compliance groundwater monitoring wells (excluding MW-19, 22, 24 and 25) have contained at least one (1) total metal at concentrations above the 2L Standards. The statistical evaluation indicates that nine (9) of the compliance groundwater monitoring wells (MW-8, 10, 12, 13, 15, 16, 17, 25A, and MW-33A) contained at least one (1) metal at a statistically significant level higher than the background well. Metal concentrations in several wells have fluctuated between non-detect and detect. In the background well, MW-1A, antimony, beryllium, cadmium, chromium, cobalt, iron, lead, silver, and vanadium have been detected at concentrations above the 2L Standards. Graphs depicting concentrations over time for constituents with a statistical increase are provided in Appendix V. 5.0 Methane Readings Methane Readings are collected from eleven (11) locations on site, including eight (8) methane monitoring wells (MMW-1 through MMW-8) and the scale house, landfill shop, and lift station on site. Methane readings are measured monthly by Lincoln County personnel using a GEM 2000 gas meter. October 2016 through April 2017 methane readings and a figure showing their locations are located in Appendix VI. Appendices Appendix I – Drawings kjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkjkj!.!.!.!.!.!.kjC&D PHASE II C&D PHASE I EXISTING AREA "E" CLOSED LANDFILLEXISTING AREA "D" PHASE IPHASE II PHASE III805 810820850860885840830845865870875880825815PHASE IV FUTURE PHASE V MW-8 DRY MW-9 805.66 MW-12 823.61MW-24 816.13 MW-25/25A 808.10 MW-21 817.70 MW-18 838.71 MW-19 831.04 MW-13 839.90 MW-14 840.15 MW-20 845.06 MW-28 869.97 MW-29 837.97 MW-36 827.34 MW-30 833.50 MW-31 851.03 MW-26 857.50 MW-27 862.77 MW-1A 885.45 MW-17R 855.63 MW-10R 806.55 MW-32R 811.91 MW-16R 860.80 MW-35/MW-35A 804.39 MW-33/MW-33A 806.24 SW-4 SW-5 SW-1 SW-2 SW-3 SW-6 SHOAL R D CROUSE RDY O D E R R D SHIRL E Y R E Y N O L D S L N GROUNDWATER SURFACE MAPApril 10-11, 2017LINCOLN COUNTY LANDFILLCROUSE, NORTH CAROLINA1 1356-07-004SJT8-3-2017FIGURE NO.SCALE:PROJECT NO.DATE:DRAWN BY:³1 " = 400 'Q:\1356\LINCOLN COUNTY\07-004\GIS\APRIL 2017 GW Map 11x17.mxd plotted by JTayouga 08-03-20170 500 1,000 (IN FEET) Legend kj Groundwater Wells !.Surface Water Sample Locations Roads MSW Boundary Property Line C&D Landfill Boundary Streams on Landfill Property Groundwater Flow Direction 4' Contours 04/2017 Groundwater Surface MW-15 NS Appendix II –Tables Latitude Longitude Ground TOC DTW - TOC GW ELEV. (MM/DD/YY)(ft)(ft-MSL) MW-1A Background - - - 35.4305188° -081.3550147° - - - 929.27 - - - to - - - - - - to - - - - - - to - - - - - - to - - - - - - to - - - - - -43.82 885.45 MW-8 Leachate Lagoon - - -35.4204767°-081.3543964°- - -840.03 - - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -DRY N/A MW-9 Leachate Lagoon - - -35.4205014°-081.3544769°- - -840.20 - - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -34.54 805.66 MW-10R Leachate Lagoon - - -35.4209399°-081.3538215°- - -834.97 - - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -28.42 806.55 MW-12 Area "E" and Phase 1 - - -35.4229138°-081.3543339°- - -827.57 - - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -3.96 823.61 MW-13 Area "E" and Phase 1 - - -35.4252197°-081.3569120°- - -872.78 - - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -32.88 839.90 MW-14 Area "E" and Phase 1 - - -35.4252431°-081.3570085°- - -871.44 - - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -31.29 840.15 MW-15 Area "E" and Phase 1 - - -35.4232655°-081.3580245°- - -847.86 - - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -Note 1 N/A MW-16R Area "E" and Phase 1 - - -35.4270857°-081.3570696°- - -876.39 - - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -to - - -- - -15.59 860.80 MW-17R Area "E" and Phase 1 07/20/93 35.4262555°-081.3548668°898.14 899.64 0.0 to 20.0 20.0 to 35.0 0.0 to 16.0 16.0 to 18.0 18.0 to 45.5 - - -44.01 855.63 MW-18 Area "E" and Phase 1 - - -35.4246249°-081.3576782°859.20 861.41 - - -to - - -- - -to - - -- - -to - - -- - -to - - -15.2 to 30.2 - - -22.70 838.71 MW-19 Area "E" and Phase 1 - - -35.4247561°-081.3576590°859.95 859.73 - - -to - - -- - -to - - -- - -to - - -- - -to - - -63.0 to 68.0 - - -28.69 831.04 MW-20 Area "E" and Phase 1 - - -35.4256922°-081.3575990°- - -860.00 - - -to - - -- - -to - - -- - -to - - -- - -to - - -10.1 to 25.1 - - -14.94 845.06 MW-21 Phase 2 09/03/99 35.4221305°-081.3579143°853.80 855.91 0.0 to 27.0 27.0 to 42.0 0.0 to 23.0 23.0 to 25.0 25.0 to 42.0 SAP 38.21 817.70 MW-24 Phase 2 09/02/99 35.4219922°-081.3540276°838.95 841.13 0.0 to 14.0 14.0 to 29.0 0.0 to 10.0 10.0 to 12.0 12.0 to 29.0 SAP 25.00 816.13 MW-25 Phase 2 08/31/99 35.4213534°-081.3546541°836.75 838.73 0.0 to 15.0 15.0 to 30.0 0.0 to 11.0 11.0 to 13.0 13.0 to 30.0 SAP 30.63 808.10 MW-25A Phase 2 09/01/99 35.4212848°-081.3547068°836.75 838.84 0.0 to 50.0 50.0 to 60.0 0.0 to 46.0 46.0 to 48.0 48.0 to 60.0 SAP 30.86 807.98 MW-26 C&D Phase 1 09/08/99 35.4273089°-081.3527074°869.11 871.19 0.0 to 6.0 6.0 to 21.0 0.0 to 4.0 4.0 to 5.0 5.0 to 21.0 SAP 13.69 857.50 MW-27 C&D Phase 1 09/07/99 35.4278831°-081.3533157°879.03 880.90 0.0 to 10.0 10.0 to 25.0 0.0 to 6.0 6.0 to 8.0 8.0 to 25.0 SAP 18.13 862.77 MW-28 C&D Phase 1 04/01/99 35.4276977°-081.3542728°912.72 915.68 0.0 to 36.0 36.0 to 51.0 0.0 to 32.0 32.0 to 34.0 34.0 to 51.0 SAP 45.71 869.97 MW-29 C&D Phase 2 04/30/02 35.4252895°-081.3534741°877.45 879.97 0.0 to 30.0 30.0 to 45.0 0.0 to 26.0 26.0 to 28.0 28.0 to 45.0 PWR 42.00 837.97 MW-30 C&D Phase 2 05/02/02 35.4259842°-081.3520549°883.72 886.35 0.0 to 45.0 45.0 to 60.0 0.0 to 41.0 41.0 to 43.0 43.0 to 60.0 SAP 52.85 833.50 MW-31 C&D Phase 2 06/19/03 35.4266563°-081.3521999°877.40 879.88 0.0 to 25.0 25.0 to 40.0 0.0 to 21.0 21.0 to 23.0 23.0 to 40.0 PWR 28.85 851.03 MW-32R Phase 3 12/20/04 35.4214589°-081.3583317°825.89 827.25 0.0 to 10.0 10.0 to 25.0 0.0 to 6.0 6.0 to 8.0 8.0 to 25.0 SAP 15.34 811.91 MW-33 Phase 3 12/30/04 35.4208632°-081.3585631°816.33 819.38 0.0 to 7.0 7.0 to 22.0 0.0 to 3.0 3.0 to 5.0 5.0 to 22.0 SAP 13.14 806.24 MW-33A Phase 3 12/30/04 35.4208632°-081.3585631°815.94 818.67 0.0 to 56.5 56.5 to 61.5 0.0 to 52.5 52.5 to 54.5 54.5 to 61.5 ROCK 13.74 804.93 MW-35 Phase 3 12/28/04 35.4200537°-081.3551088°836.85 839.64 0.0 to 19.0 19.0 to 34.0 0.0 to 15.0 15.0 to 17.0 17.0 to 34.0 SAP 35.25 804.39 MW-35A Phase 3 12/28/04 35.4200537°-081.3551088°836.77 839.83 0.0 to 60.0 60.0 to 65.0 0.0 to 56.0 56.0 to 58.0 58.0 to 65.0 SAP 35.48 804.35 MW-36 C&D Phase 2 06/26/13 35.4252949° -081.3518019° 852.00 854.83 0.0 to 19.5 19.5 to 34.5 0.0 to 9.5 9.5 to 17.7 17.7 to 35.0 SAP 27.49 827.34 Notes: (ft-MSL)Feet Mean Sea Level DTW Depth to Water Sch. 40 Schedule 40 Pipe PWR Partially Weathered Rock (ft-bls)Feet Below Land Surface GW ELEV.Groundwater Elevation 0.010 Slot 0.010-Inch Machine-Slotted Pipe ROCK Bedrock TOC Top of Casing #2 Filter Sand Medium to Fine Grained Silica Sand Neat Cement Cement Mixture without Bentonite - - -Not Available Ground Ground Surface Bentonite Bentonite Pellets SAP Saprolite DRY No water in well at time of sampling Note 1 Well was destroyed during clearing operations. Scheduled to be replaced. NS Well was not sampled N/A Not Applicable 2-inch, SCH. 40, PVC 2-inch, 0.010 Slot, PVC Neat Cement Bentonite Interval (decimal degrees)(ft-MSL)(ft-bls)(ft-bls)(ft-bls) Screen Interval Grout Interval Seal Interval Filter Pack Geology in Screen Interval April 2017 (ft-bls)(ft-bls) Table 1 Well Construction Summary and Water Level Data Lincoln County Landfill S&ME Project No: 1356-07-004 Well ID Area Monitored Install Date GPS Coordinates Survey Elevations Casing Interval K n I v Well Hydraulic Cond. Eff. Porosity Gradient Flow Velocity ID (ft/day)(ne)(ft/ft) (ft/yr) MW-1A - - -- - -- - -- - - MW-8 - - -- - -- - -- - - MW-10R - - -- - -- - -- - - MW-12 - - -- - -- - -- - - MW-13 - - -- - -- - -- - - MW-15 - - -- - -- - -- - - MW-16R - - -- - -- - -- - - MW-17R 1.4E+00 17%0.01 39 MW-18 - - -- - -- - -- - - MW-20 - - -- - -- - -- - - MW-21 4.5E-01 23%0.01 9 MW-24 - - -- - -- - -- - - MW-25 1.0E-01 24%0.02 3 MW-26 - - -- - -- - -- - - MW-27 - - -- - -- - -- - - MW-28 3.2E-01 - - -- - -- - - MW-29 8.6E-01 3%0.01 120 MW-30 5.0E+00 24%0.01 59 MW-31 - - -- - -- - -- - - MW-32R 2.6E-01 20%0.02 9 MW-33 3.0E+00 27%0.03 111 MW-34 7.5E+00 21%- - -- - - MW-35 4.9E-01 16%0.01 10 MW-36 3.5E+00 20%0.03 171 Notes: (4) Seepage velocity v = (K*i)/ne - - -Not Available (1) Hydraulic Conductivity was calculated from slug tests performed after well construction. April 2017 (3) Hydraulic gradient calculated by measuring linear feet between selected contour intervals. Table 2 Groundwater Flow Data Lincoln County Landfill S&ME Project No: 1356-07-004 (2) Effective porosity was estimated from soils collected within the saturated portion of screen interval during well construction. Well ID DTW TOC (ft-bls)pH Temp (°C)Conductance (μS) MW-1A 43.82 6.05 16.7 23 MW-8 MW-9 34.54 6.71 16.1 39 MW-10R 28.42 6.80 16.9 182 MW-12 3.96 5.31 13.9 92 MW-13 32.88 6.20 17.3 293 MW-14 31.29 6.43 17.2 107 MW-16R 15.59 6.45 15.5 725 MW-17R 44.01 5.37 17.4 52 MW-18 22.70 6.61 15.0 169 MW-19 28.69 6.23 15.7 112 MW-20 14.94 5.89 15.2 51 MW-21 38.21 5.65 16.3 85 MW-24 25.00 5.66 16.5 252 MW-25 30.63 5.93 17.9 158 MW-25A 30.86 6.35 17.5 137 MW-26 13.69 5.83 14.6 116 MW-27 18.13 5.50 15.8 219 MW-28 45.71 5.26 17.1 41 MW-29 42.00 6.02 16.9 287 MW-30 52.85 5.97 15.6 50 MW-31 28.85 5.47 15.9 48 MW-32R 15.34 5.35 15.1 17 MW-33 13.14 5.89 14.7 82 MW-33A 13.74 6.72 15.8 215 MW-35 35.25 6.60 15.9 18 MW-35A 35.48 6.39 16.1 47 MW-36 27.49 5.63 15.2 15 Notes: °C degrees Celsius μS micro siemems NTU nephelometric turbidity unit Table 3 April 2017 - Field Parameters in Monitoring Wells Lincoln County Landfill S&ME Project No. 1356-07-004 DRY Notes: (1) ug/L = micrograms per liter (parts per billion) (2) mg/L = milligrams per liter (parts per million) (3) μS = microSiemens (4) 15A NCAC 2L = North Carolina Groundwater Quality Standards (5) 15A NCAC 2B = North Carolina Surface Water Quality Standards (6) GWP ST = Solid Waste Groundwater Protection Standard (7) NE = No established standard (8) Bold indicates above 15A NCAC 2L, 15A NCAC 2B, or SWS GWP standard (9) Compounds not shown were not detected. (10) SWSL = North Carolina Department of Environmtental Quality, Solid Waste Section Limit established in 2007 (11) NA = Not Analyzed (12) J = Analyte detected is between the Method Detection Limit (MDL) and the SWSL (13) B = Analyte was detected in the associated method blank (14) D = The sample was analyzed at dilution (15) Dry = Surface water sample location dry or no flow, location not sampled (16) NS - Not Sampled Notes for Tables 4 through 10 S&ME Project No. 1356-07-004 EPA Appendix I Volatile Organic Compounds Method 8260 (µg/L) NCDEQ SWSL 15A NCAC 2L Soild Waste GWP ST MW-1A MW-8 MW-9 MW-10R MW-12 MW-13 MW-14 MW-15 MW-16R MW-17R MW-18 MW-19 MW-20 1,1-Dichloroethane 5 6 NE 17 4.3 J 1.2 J 8.2 19 1,4 - Dichlorobenzene 1 6 NE 3.6 4.0 2.9 0.45 J cis-1,2,-Dichloroethene 5 70 NE 3.0 J 3.0 J 1.1 J Acetone 100 6000 NE 54 J Benzene 1 1 NE 5.5 6.7 5.3 2.4 Chlorobenzene 3 50 NE 0.43 J 4.4 Chloroform 5 70 NE 16 Ethyl Chloride (Chloroethane)10 3000 NE 2.7 J Methylene Chloride 1 5 NE 55 5.3 Tetrachloroethene 1 0.7 NE 2.6 0.65 J 2.6 Toluene 1 600 NE 0.93 J Trichloroethane 1 3 NE 2.2 0.60 J 1.3 1.9 Trichlorofluoromethane 1 2000 NE 0.49 J 0.49 J Vinyl chloride 1 0.03 NE 1.5 4.6 Xylenes (total)5 500 NE 1.8 J 11 1.6 JEPA Appendix I Metals Method 6010B/6020 (µg/L) Antimony 6 NE 1 1.03 J 0.653 J 5.75 J 3.39 J Arsenic 10 10 NE 12.5 17.9 Barium 100 700 NE 46.7 33.2 J 32.3 J 214 113 29.7 J 436 125 84.0 J 34.2 J 42.9 J Beryllium 1 NE 4 0.136 J Chromium 10 10 NE 8.29 J 2.54 J 7.20 J 1.94 J 2.44 J 7.45 J Cobalt 10 NE 1 1.73 J 9.70 J 276 3.33 J 30.8 17.1 5.31 J Copper 10 1000 NE 5.49 J 2.71 J 1.65 J 7.89 J 3.87 J 5.96 J 4.49 J 8.28 J 5.76 J 2.43 J Iron 300 300 NE 2,380 Lead 10 15 NE 3.10 J Manganese 50 50 NE 29.5 J Nickel 50 100 NE 6.38 J 2.54 J 3.51 J 18.0 J 2.69 J 9.07 J 8.92 J 6.16 J Silver 10 20 NE 2.46 J 5.58 J Thallium 5.5 NE 0.28 0.236 J 0.236 J 0.537 J 1.13 J 0.203 J 1.75 J 0.581 J 0.644 J 0.208 J 0.333 J Vanadium 25 NE 0.3 4.36 J 3.98 J 2.36 J 14.8 J Zinc 10 1000 NE 12.7 5.93 J 4.79 J 24.1 5.26 J 17.6 15.9 16.3 9.46 J Table 4 April 2017 - Detected Analytes in Monitoring Wells for MSW Area “E” and Phase 1 Lincoln County Landfill S&ME Project No. 1356-07-004 DRY DRY NS NS EPA Appendix I Volatile Organic Compounds Method 8260 (µg/L) NCDEQ SWSL 15A NCAC 2L Soild Waste GWP ST MW-21 MW-24 MW-25 MW-25A 2-Butanone 100 4000 NE 5.0 J Acetone 100 6000 NE 110 15 EPA Appendix I Metals Method 6010B/6020 (µg/L) Antimony 6 NE 1 1.27 J Barium 100 700 NE 58.0 J 227 284 142 Beryllium 1 NE 4 0.920 J Cadmium 1 2 NE 0.428 J Cobalt 10 NE 1 2.15 J 21.9 Copper 10 1000 NE 3.56 J 5.37 J 1.67 J 4.07 J Nickel 50 100 NE 7.38 J 2.74 J Thallium 5.5 NE 0.28 0.333 J 0.654 J 0.394 J 0.443 J Zinc 10 1000 NE 5.07 J 30.8 28.0 14.2 Table 5 April 2017 - Detected Analytes in Monitoring Wells for MSW Phase 2 Lincoln County Landfill S&ME Project No. 1356-07-004 EPA Appendix I Volatile Organic Compounds Method 8260 (µg/L) NCDEQ SWSL 15A NCAC 2L Soild Waste GWP ST MW-32R MW-33 MW-33A MW-35 MW-35A EPA Appendix I Metals Method 6010B/6020 (µg/L) Antimony 6 NE 1 4.61 J 3.02 J Barium 100 700 NE 25.8 J 43.9 J 6.52 J 67.7 J 37.2 J Chromium 10 10 NE 1.96 J 5.10 J 2.53 J Cobalt 10 NE 1 3.69 J Copper 10 1000 NE 3.28 J 2.65 J 7.01 J 5.22 J 3.45 J Nickel 50 100 NE 3.03 J Thallium 5.5 NE 0.28 0.220 J 0.491 J 0.266 J 0.202 J Vanadium 25 NE 0.3 4.54 J 15.7 J 2.19 J Zinc 10 1000 NE 5.01 J 15.5 13.8 6.31 J No Volatile Organic Compounds Detected in Phase 3 in April 2017 Table 6 April 2017 - Detected Analytes in Monitoring Wells for MSW Phase 3 Lincoln County Landfill S&ME Project No. 1356-07-004 EPA Appendix I Volatile Organic Compounds Method 8260 (µg/L) NCDEQ SWSL 15A NCAC 2L Soild Waste GWP ST MW-26 MW-27 MW-28 1,1-Dichloroethane 5 6 NE 0.76 J Acetone 100 6000 NE 10 J 19 J Tetrachloroethene 1 0.7 NE 9.6 Trichloroethene 1 3 NE 0.59 J Vinyl Chloride 1 0.03 NE 1.2 EPA Appendix I Metals Method 6010B/6020 (µg/L) Barium 100 700 NE 66.3 J 186 105 Beryllium 1 NE 4 0.390 J Cadmium 1 2 NE 1.24 Chromium 10 10 NE 2.61 J 1.56 J Cobalt 10 NE 1 1.69 J 10.6 2.76 J Copper 10 1000 NE 6.65 J 3.69 J 4.92 J Iron 300 300 NE 1120 516 66.4 J Manganese 50 50 NE 66.4 1,240 30.9 J Nickel 50 100 NE 3.84 J 17.2 J 4.88 J Silver 10 20 NE 2.63 J 3.04 J 2.81 J Thallium 5.5 NE 0.28 0.371 J 0.634 J 0.217 J Vanadium 25 NE 0.3 1.50 J 3.12 J Zinc 10 1000 NE 7.29 J 17.7 11.1 Classical Chemistry Compounds (mg/L) Chloride NE 250 NE 5.8 13 Sulfate as SO4 250 250 NE 17 J 60 J Total Dissolved Solids NE 500 NE 56 180 Total Alkalinity NE NE NE 23 46 17 S&ME Project No. 1356-07-004 Lincoln County Landfill April 2017 - Detected Analytes in Monitoring Wells for C&D Phase 1 Table 7 EPA Appendix I Volatile Organic Compounds Method 8260 (µg/L) NCDEQ SWSL 15A NCAC 2L Soild Waste GWP ST MW-29 MW-30 MW-31 MW-36 Methyl Chloride (Chloromethane)1 3 NE 2.8 EPA Appendix I Metals Method 6010B/6020 (µg/L) Barium 100 700 NE 17.7 J 75.9 J 9.72 J 103 Beryllium 1 NE 4 0.376 J 0.149 J Cadmium 1 2 NE 0.367 J 0.563 J 0.400 J 0.367 J Chromium 10 10 NE 4.16 J Cobalt 10 NE 70 8.41 J 1.31 J 2.83 J Copper 10 1000 NE 4.10 J 4.19 J 3.78 J 5.03 J Iron 300 300 NE 40,200 733 6,030 3,070 Manganese 50 50 NE 172 43.6 J 49.5 J 49.5 J Nickel 50 100 NE 13.9 J 3.23 J 3.15 J Silver 10 20 NE 2.65 J 2.62 J 2.49 J 2.93 J Thallium 5.5 NE 0.28 0.229 J 0.128 J 0.216 J Vanadium 25 NE 0.3 4.45 J Zinc 10 1000 NE 15.9 6.57 J 16.2 Classical Chemistry Compounds (mg/L) Chloride NE 250 NE 4.1 J 3.4 J Sulfate as SO4 250 250 NE 10 J 3.8 J 9.3 J Total Dissolved Solids NE 500 NE 170 60 Total Alkalinity NE NE NE 120 23 S&ME Project No. 1356-07-004 Lincoln County Landfill April 2017 - Detected Analytes in Monitoring Wells for C&D Phase 2 Table 8 EPA Appendix I Volatile Organic Compounds Method 8260 (µg/L) 15A NCAC 2B SW-1 SW-2 SW-3 SW-4 SW-5 SW-6 EPA Appendix I Metals Method 6010B/6020 (µg/L) Barium 1,000 39.0 J 25.5 J 93.7 J 22.5 J 41.1 J 59.8 J Chromium 74 1.74 J 9.68 J Cobalt 270 2.14 J 1.42 J 36.7 3.69 J 5.65 J Copper 7 4.00 J 3.40 J 3.59 J 2.55 J 3.11 J 6.51 J Iron NE 1,680 855 9,580 445 2,290 Manganese NE 300 140 3,490 28.3 383 Nickel 88 4.30 J Thallium 0.47 0.501 J 0.207 J 0.360 J 0.302 J 0.276 J Vanadium NE 1.55 J 2.65 J 13.9 J Zinc 36 15.9 17.4 21.0 Classical Chemistry Compounds (mg/L) COD NE 24 Sulfate as SO4 NE 5.5 J Phosphorous NE 0.056 J Nitrate as N NE 0.089 J Nitrate/Nitrite as N NE 0.089 J Total Suspended Solids NE 88 Total Alkalinity NE 15 Table 9 April 2017 - Detected Analytes in Surface Water Samples Lincoln County Landfill S&ME Project No. 1356-07-004 No Volatile Organic Compounds Detected in April 2017 EPA Appendix I Volatile Organic Compounds Method 8260 (µg/L) NCDEQ SWSL Lift Station EPA Appendix I Metals Method 6010B/6020 (µg/L) Arsenic 10 169 Barium 100 1,280 Chromium 10 10.1 Cobalt 10 9.03 J Copper 10 4.07 J Nickel 50 33.9 J Thallium 5.5 1.95 JD Vanadium 25 7.42 J Zinc 10 22.6 Classical Chemistry Compounds (mg/L) BOD NE 28 COD NE 380 Sulfate as SO4 250 4.7 J Phosphorous NE 1 D Nitrite as N 1000 0.160 J Nitrate/Nitrite as N NE 0.140 Total Alkalinity NE 1300 D Total Suspended Solids NE 220 Table 10 April 2017 - Detected Analytes in Leachate Lincoln County Landfill S&ME Project No. 1356-07-004 No Volatile Organic Compounds Detected in April 2017 Notes: (1) SSI = Statistically Significant Increase (2) PA = One Way Parametric Analysis of Variance (Parametric ANOVA) The parametric ANOVA analysis is recommended by the 1992 guidance document for parameters with fewer than 15% non-detects in a specific well. (3) KW = Kruskal Wallis Non-Parametric Rank Analysis The Kruskal-Wallis method is recommended by the 1992 guidance document for parameters that have 15% to 90% non-detects in a specific well. (4) PL = Non-Parametric Inter-Well Prediction Limit Analysis The prediction limit was used for parameters with greater than 90% non-detects in a specific well. The 1992 guidance document recommends this method when a significant portion of the samples are non-detect. Notes for Tables 11 through 13 S&ME Project No. 1356-07-004 Statistical Percent Analysis Parameter Well ID Non-Detect Method SSI Comments 1,1,1-Trichloroethane MW-13 90%KW FALSE 1,1-Dichloroethane MW-13 2%PA TRUE Concentrations have decreased over time MW-14 50%KW TRUE MW-16 26%KW TRUE Concentrations have decreased over time MW-17 80%KW FALSE MW-19 32%KW TRUE MW-20 37%KW TRUE Not detected during April 2017 sampling event 1,1-Dichloroethene MW-16 96%PL FALSE MW-19 98%PL FALSE 1,2-Dichloroethane MW-13 94%PL FALSE 1,4-Dichlorobenzene MW-13 54%KW TRUE MW-16 55%KW TRUE MW-17 89%KW FALSE MW-19 90%KW FALSE MW-20 85%KW FALSE 2-Butanone MW-13 98%PL FALSE Acetone MW-12 98%PL FALSE MW-13 52%KW TRUE Concentrations vary from non-detect to detect MW-14 96%PL FALSE MW-16 89%KW FALSE MW-17 73%KW FALSE MW-15 98%PL FALSE MW-9 98%PL FALSE MW-18 98%PL FALSE MW-19 95%PL FALSE MW-20 98%PL FALSE Antimony MW-12 96%PL FALSE MW-13 90%KW FALSE MW-14 54%KW FALSE MW-16 94%PL FALSE MW-10 91%PL FALSE MW-8 93%PL FALSE MW-9 76%KW FALSE MW-18 90%KW FALSE MW-19 56%KW FALSE MW-20 93%PL FALSE Arsenic MW-12 83%KW FALSE MW-13 46%KW TRUE Concentrations vary from non-detect to detect MW-14 94%PL FALSE MW-16 57%KW TRUE MW-17 95%PL FALSE MW-10 91%PL FALSE MW-15 91%PL FALSE MW-8 89%KW FALSE MW-9 94%PL FALSE MW-18 90%KW FALSE MW-19 90%KW FALSE MW-20 83%KW FALSE Barium MW-12 38%KW TRUE MW-13 33%KW TRUE MW-14 44%KW FALSE MW-16 34%KW TRUE MW-17 34%KW TRUE MW-10 23%KW TRUE MW-15 22%KW TRUE MW-8 39%KW FALSE MW-9 34%KW FALSE MW-18 32%KW FALSE MW-19 49%KW FALSE MW-20 32%KW FALSE Table 11 April 2017 Statistical Analysis for Phase 1 and Area "E" Lincoln County Landfill S&ME Project No. 1356-07-004 Page 1 of 5 Statistical Percent Analysis Parameter Well ID Non-Detect Method SSI Comments Table 11 April 2017 Statistical Analysis for Phase 1 and Area "E" Lincoln County Landfill S&ME Project No. 1356-07-004 Benzene MW-13 33%KW TRUE MW-16 51%KW TRUE MW-17 86%KW FALSE MW-19 63%KW TRUE MW-20 71%KW FALSE Beryllium MW-12 63%KW FALSE MW-13 71%KW FALSE MW-14 98%PL FALSE MW-16 81%KW FALSE MW-17 57%KW FALSE MW-10 59%KW FALSE MW-15 39%KW TRUE Concentrations have decreased over time MW-8 46%KW TRUE MW-9 89%KW FALSE MW-18 85%KW FALSE MW-19 95%PL FALSE MW-20 78%KW FALSE cis-1,2-Dichloroethene MW-13 46%KW TRUE MW-16 49%KW TRUE MW-17 89%KW FALSE MW-19 56%KW TRUE MW-20 63%KW TRUE cis-1,3-Dichloropropene MW-12 98%PL FALSE Cadmium MW-12 71%KW FALSE MW-13 75%KW FALSE MW-14 75%KW FALSE MW-16 74%KW FALSE MW-17 77%KW FALSE MW-10 77%KW FALSE MW-15 76%KW FALSE MW-8 75%KW FALSE MW-9 89%KW FALSE MW-18 90%KW FALSE MW-19 98%KW FALSE MW-20 88%KW FALSE Chlorobenzene MW-13 88%KW FALSE MW-16 60%KW TRUE Chloroethane MW-13 35%KW TRUE Concentrations vary from non-detect to detect MW-16 62%KW TRUE Concentrations vary from non-detect to detect MW-19 95%PL FALSE MW-20 83%KW FALSE Chloromethane MW-10 97%PL FALSE MW-12 98%PL FALSE MW-13 98%PL FALSE MW-16 98%PL FALSE MW-9 98%PL FALSE MW-20 98%PL FALSE Chromium MW-12 79%KW FALSE MW-13 44%KW FALSE MW-14 81%KW FALSE MW-16 53%KW FALSE MW-17 50%KW FALSE MW-10 32%KW FALSE MW-15 76%KW FALSE MW-8 32%KW FALSE MW-9 34%KW FALSE MW-18 78%KW FALSE MW-20 83%KW FALSE Page 2 of 5 Statistical Percent Analysis Parameter Well ID Non-Detect Method SSI Comments Table 11 April 2017 Statistical Analysis for Phase 1 and Area "E" Lincoln County Landfill S&ME Project No. 1356-07-004 Cobalt MW-12 29%KW TRUE MW-13 0%PA TRUE MW-14 75%KW FALSE MW-16 9%PA FALSE MW-17 39%KW TRUE MW-10 64%KW FALSE MW-15 76%KW FALSE MW-8 32%KW TRUE MW-9 89%KW FALSE MW-18 61%KW FALSE MW-19 95%PL FALSE MW-20 63%KW FALSE Copper MW-12 71%KW FALSE MW-13 65%KW FALSE MW-14 42%KW FALSE MW-16 91%PL FALSE MW-17 61%KW FALSE MW-10 59%KW FALSE MW-15 78%KW FALSE MW-8 57%KW FALSE MW-9 66%KW FALSE MW-18 54%KW FALSE MW-19 76%KW FALSE MW-20 85%KW FALSE Ethylbenzene MW-13 79%KW FALSE MW-16 96%PL FALSE Lead MW-12 88%KW FALSE MW-13 69%KW FALSE MW-14 94%PL FALSE MW-16 47%KW TRUE Non-Detect in April 2017 MW-17 84%KW FALSE MW-10 68%KW FALSE MW-15 74%KW FALSE MW-8 57%KW FALSE MW-9 87%KW FALSE MW-18 90%KW FALSE MW-19 95%PL FALSE MW-20 85%KW FALSE Methylene Chloride MW-12 98%PL FALSE MW-13 48%KW TRUE Concentrations have decreased over time MW-14 92%PL FALSE MW-16 60%KW TRUE Concentrations have been non-detect since Oct 2011 MW-17 89%KW FALSE MW-19 46%KW TRUE Concentrations have decreased over time MW-20 49%KW TRUE Concentrations have decreased over time Nickel MW-12 56%KW FALSE MW-13 46%KW FALSE MW-14 65%KW FALSE MW-16 53%KW FALSE MW-17 45%KW FALSE MW-10 68%KW FALSE MW-15 96%PL FALSE MW-8 61%KW FALSE MW-9 98%PL FALSE MW-18 63%KW FALSE MW-19 98%PL FALSE MW-20 85%KW FALSE Page 3 of 5 Statistical Percent Analysis Parameter Well ID Non-Detect Method SSI Comments Table 11 April 2017 Statistical Analysis for Phase 1 and Area "E" Lincoln County Landfill S&ME Project No. 1356-07-004 Selenium MW-13 98%PL FALSE MW-16 87%KW FALSE MW-17 98%PL FALSE MW-10 95%PL FALSE MW-15 98%PL FALSE MW-8 96%PL FALSE MW-18 95%PL FALSE MW-19 98%PL FALSE MW-20 95%PL FALSE Silver MW-12 96%PL FALSE MW-13 85%KW FALSE MW-14 96%PL FALSE MW-16 70%KW FALSE MW-17 95%PL FALSE MW-10 93%PL FALSE MW-15 98%PL FALSE MW-8 96%PL FALSE MW-9 96%PL FALSE MW-19 95%PL FALSE Tetrachloroethene MW-13 48%KW TRUE MW-14 83%KW FALSE MW-17 70%KW FALSE MW-19 49%KW TRUE MW-20 73%KW FALSE Thallium MW-12 65%KW FALSE MW-13 44%KW TRUE MW-14 90%KW FALSE MW-16 51%KW FALSE MW-17 86%KW FALSE MW-10 89%KW FALSE MW-15 89%KW FALSE MW-8 75%KW FALSE MW-18 61%KW FALSE MW-19 95%PL FALSE MW-20 98%PL FALSE Toluene MW-12 98%PL FALSE MW-13 69%KW TRUE Concentrations vary from non-detect to detect Trichloroethene MW-13 48%KW TRUE MW-14 88%KW FALSE MW-16 87%KW FALSE MW-17 82%KW FALSE MW-19 51%KW TRUE MW-20 73%KW FALSE Trichlorofluoromethane MW-16 91%PL FALSE MW-17 93%PL FALSE MW-19 66%KW TRUE Concentrations vary from non-detect to detect Vanadium MW-12 85%KW FALSE MW-13 69%KW FALSE MW-14 83%KW FALSE MW-16 89%KW FALSE MW-17 70%KW FALSE MW-10 30%KW TRUE MW-15 65%KW FALSE MW-8 32%KW FALSE MW-9 62%KW FALSE MW-18 61%KW FALSE MW-19 80%KW FALSE MW-20 90%KW FALSE Vinyl Chloride MW-12 98%PL FALSE MW-13 60%KW TRUE Non-Detect in April 2015 MW-16 28%KW TRUE Concentrations have decreased over time MW-20 85%KW FALSE Page 4 of 5 Statistical Percent Analysis Parameter Well ID Non-Detect Method SSI Comments Table 11 April 2017 Statistical Analysis for Phase 1 and Area "E" Lincoln County Landfill S&ME Project No. 1356-07-004 Xylenes (Total)MW-13 40%KW TRUE MW-16 55%KW TRUE Concentrations vary from non-detect to detect MW-17 89%KW TRUE MW-19 68%KW FALSE MW-20 76%KW FALSE Zinc MW-12 2%PA TRUE Concentrations have decreased over time MW-13 35%KW FALSE MW-14 46%KW FALSE MW-16 34%KW FALSE MW-17 36%KW FALSE MW-10 27%KW FALSE MW-15 59%KW FALSE MW-8 36%KW FALSE MW-9 55%KW FALSE MW-18 54%KW FALSE MW-19 66%KW FALSE MW-20 63%KW FALSE Page 5 of 5 Statistical Percent Analysis Parameter Well ID Non-Detect Method SSI Comments Acetone MW-21 87%KW FALSE MW-24 97%PL FALSE MW-25 97%PL FALSE MW-25A 87%KW FALSE Antimony MW-21 95%PL FALSE MW-24 97%PL FALSE MW-25 95%PL FALSE MW-25A 45%KW FALSE Arsenic MW-21 95%PL FALSE MW-24 87%KW FALSE MW-25 89%KW FALSE MW-25A 84%KW FALSE Barium MW-21 32%KW FALSE MW-24 37%KW FALSE MW-25 38%KW TRUE MW-25A 32%KW FALSE Beryllium MW-21 53%KW FALSE MW-24 50%KW TRUE MW-25 54%KW FALSE MW-25A 87%KW FALSE Cadmium MW-21 89%KW FALSE MW-24 92%PL FALSE MW-25 84%KW FALSE MW-25A 87%KW FALSE Chloromethane MW-21 97%PL FALSE MW-25 97%PL FALSE MW-25A 97%PL FALSE Chromium MW-21 82%KW FALSE MW-24 79%KW FALSE MW-25 49%KW FALSE MW-25A 32%KW FALSE Cobalt MW-21 82%KW FALSE MW-24 87%KW FALSE MW-25 97%PL FALSE MW-25A 50%KW TRUE Copper MW-21 71%KW FALSE MW-24 74%KW FALSE MW-25 76%KW FALSE MW-25A 68%KW FALSE Lead MW-21 92%PL FALSE MW-24 97%PL FALSE MW-25A 95%PL FALSE Nickel MW-21 92%PL FALSE MW-24 76%KW FALSE MW-25 65%KW FALSE MW-25A 97%PL FALSE Table 12 April 2017 Statistical Analysis for Phase 2 Lincoln County Landfill S&ME Project No. 1356-07-004 Page 1 of 2 Statistical Percent Analysis Parameter Well ID Non-Detect Method SSI Comments Table 12 April 2017 Statistical Analysis for Phase 2 Lincoln County Landfill S&ME Project No. 1356-07-004 Selenium MW-21 97%PL FALSE MW-25 97%PL FALSE Silver MW-24 95%PL FALSE MW-25 97%PL FALSE MW-25A 97%PL FALSE Thallium MW-21 95%PL FALSE MW-24 71%KW FALSE MW-25 84%KW FALSE MW-25A 97%PL FALSE Vanadium MW-21 71%KW FALSE MW-24 89%KW FALSE MW-25 89%KW FALSE MW-25A 45%KW FALSE Zinc MW-21 61%KW FALSE MW-24 42%KW FALSE MW-25 43%KW FALSE MW-25A 47%KW FALSE Page 2 of 2 Statistical Percent Analysis Parameter Well ID Non-Detect Method SSI Comments Acetone MW-32 96%PL FALSE MW-33 96%PL FALSE MW-33A 93%PL FALSE MW-35 96%PL FALSE MW-35A 93%PL FALSE Antimony MW-32 93%Pl FALSE MW-33 93%Pl FALSE MW-33A 30%KW TRUE MW-35 85%KW FALSE MW-35A 48%KW FALSE Arsenic MW-32 89%KW FALSE MW-33 89%KW FALSE MW-33A 96%PL FALSE MW-35 92%PL FALSE MW-35A 85%KW FALSE Barium MW-32 7%PA FALSE MW-33 7%PA FALSE MW-33A 22%KW FALSE MW-35 8%PA FALSE MW-35A 7%PA FALSE Beryllium MW-32 48%KW FALSE MW-33 44%KW FALSE MW-33A 96%PL FALSE MW-35 46%KW FALSE MW-35A 78%KW FALSE Cadmium MW-33A 85%KW FALSE MW-35A 96%PL FALSE Chloroform MW-33A 85%KW FALSE MW-35A 96%PL FALSE Chromium MW-32 70%KW FALSE MW-33 93%PL FALSE MW-35 65%KW FALSE MW-35A 26%KW FALSE Cobalt MW-32 89%KW FALSE MW-33A 96%PL FALSE MW-35 54%KW FALSE MW-35A 93%PL FALSE Copper MW-32 63%KW FALSE MW-33 85%KW FALSE MW-33A 33%KW FALSE MW-35 73%KW FALSE MW-35A 67%KW FALSE Lead MW-32 52%KW FALSE MW-33 96%PL FALSE MW-33A 96%PL FALSE MW-35 92%PL FALSE Nickel MW-32 81%KW FALSE MW-33 96%PL FALSE MW-35 77%KW FALSE MW-35A 93%PL FALSE Selenium MW-32 93%PL FALSE MW-33 93%PL FALSE MW-35A 96%PL FALSE Table 13 April 2017 Statistical Analysis for Phase 3 Lincoln County Landfill S&ME Project No. 1356-07-004 Page 1 of 2 Statistical Percent Analysis Parameter Well ID Non-Detect Method SSI Comments Table 13 April 2017 Statistical Analysis for Phase 3 Lincoln County Landfill S&ME Project No. 1356-07-004 Silver MW-32 93%PL FALSE MW-33 96%PL FALSE MW-33A 96%PL FALSE Thallium MW-32 81%KW FALSE MW-33 93%PL FALSE MW-33A 96%PL FALSE MW-35 77%KW FALSE Vanadium MW-32 37%KW FALSE MW-33 93%PL FALSE MW-33A 78%KW FALSE MW-35 50%KW FALSE MW-35A 22%KW FALSE Zinc MW-32 30%KW FALSE MW-33 37%KW FALSE MW-33A 22%KW FALSE MW-35 19%KW FALSE MW-35A 37%KW FALSE Page 2 of 2 Appendix III – Well Sampling Logs and Laboratory Reports Surface Water and Leachate Samples Lincoln County Landfill S&ME Project 1356-07-004 Location Date Time Sampled Sample Observations SW-1 4/12/2017 945 none/clear SW-2 4/12/2017 1030 orange tint, turbid, organics, stagnant water SW-3 4/12/2017 1045 none/clear SW-4 4/12/2017 1115 none/clear SW-5 4/12/2017 1145 turbid, mostly stagnant Lift Station 4/12/2017 1340 (Sampled from Pump #2 Lift Station) SW- 6 4/12/2017 1300 turbid, some debris Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-1A Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 917 9.31 16.0 2.2 921 7.05 16.7 4.4 924 6.25 16.8 Final 6.6 927 6.05 16.7 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Comments Lab 25 21 23 4/11/2017 13.18 2.2 57 Electric Water Level Probe Field-Cleaned Typhoon Pump Sunny 57.00 TOC 43.82 ENCO HCL 1215 disposable teflon bailer none/clear Appendix I Metals + Hg, Mn, Fe HNO3(1) 500 mL plastic bottle Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-8 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 Final Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab 31.00 0.00 Disposable Teflon Bailer Electric Water Level Probe TOC 31.00 Sunny ENCO HCL HNO3 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-9 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1340 6.68 17.5 5.9 1344 6.61 16.4 11.8 1348 6.67 16.4 Final 17.7 1353 6.71 16.1 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab TOC 34.54 70.50 35 39 38 35.96 5.9 Electric Water Level Probe Field Cleaned Typhoon Pump ENCO none/clear HCL HNO3 39 4/11/2017 1355 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-10R Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1407 6.78 17.2 0.5 1408 6.80 16.9 1.0 - Final 1.5 - Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab 4/11/2017 1420 disposable teflon bailer ENCO none/clear HCL HNO3 185 182 3.08 Disposable Teflon Bailer Sunny 0.5 Electric Water Level Probe TOC 28.42 31.50 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-12 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1520 5.63 16.3 2.4 1522 5.33 14.5 4.8 1523 5.36 14.1 Final 7.2 1524 5.31 13.9 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab TOC 3.96 18.50 Sunny 93 94 94 14.54 2.4 Electric Water Level Probe Field Cleaned Typhoon Pump ENCO none/clear HCL HNO3 92 4/11/2017 1445 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-13 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1102 6.15 17.4 1.2 1104 6.12 17.4 2.4 1107 6.16 17.4 Final 4.6 1111 6.20 17.3 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab 4/11/2017 1245 disposable teflon bailer ENCO none/clear HCL HNO3 261 266 287 7.62 Disposable Teflon Bailer 293 Sunny 1.2 Electric Water Level Probe TOC 32.88 40.50 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-14 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1058 6.63 18.7 7.3 1104 6.51 17.2 14.6 1110 6.41 17.1 Final 21.9 1116 6.43 17.2 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab TOC 31.29 76.00 Sunny 112 101 107 44.71 7.3 Electric Water Level Probe Field Cleaned Typhoon Pump ENCO none/clear HCL HNO3 107 4/11/2017 1240 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-15 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 Final Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab disposable teflon bailer ENCO HCL HNO3 Disposable Teflon Bailer Sunny Electric Water Level Probe TOC 30.50 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-16R Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 941 6.41 15.9 1.0 942 6.43 15.5 2.0 943 6.45 15.5 Final 3.0 945 6.45 15.5 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab TOC 15.59 21.60 Sunny 759 748 747 6.01 0.99 Electric Water Level Probe Disposable Teflon Bailer ENCO none/clear HCL HNO3 725 4/11/2017 1225 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-17R Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/11/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 948 5.45 17.5 0.6 950 5.38 17.4 1.2 952 5.37 17.4 Final 1.8 954 5.37 17.4 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab 4/12/2017 845 disposable teflon bailer ENCO none/clear HCL HNO3 58 52 56 3.49 Disposable Teflon Bailer 52 Sunny 0.6 Electric Water Level Probe TOC 44.01 47.50 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-18 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1030 6.56 15.2 1.5 1033 6.62 14.8 3.0 1036 6.61 15.0 Final 4.5 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab DRY @ 3.0 gallons TOC 22.70 32.00 Sunny 172 175 169 9.30 1.5 Electric Water Level Probe Disposable Teflon Bailer ENCO turbid HCL HNO3 4/11/2017 1255 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-19 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1022 6.32 17.2 7.1 1029 6.25 16.6 14.2 1034 6.25 15.7 Final 21.3 1038 6.23 15.7 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab 4/11/2017 1250 disposable teflon bailer ENCO none/clear HCL HNO3 116 111 114 43.31 Field Cleaned Typhoon Pump 112 Sunny 7.1 Electric Water Level Probe TOC 28.69 72.00 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-20 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 955 7.18 15.6 2.0 957 6.28 15.0 4.0 1000 6.00 15.1 Final 6.0 1005 5.89 15.2 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab TOC 14.94 27.00 Sunny 53 43 46 12.06 2.0 Electric Water Level Probe Disposable Teflon Bailer ENCO none/clear HCL HNO3 51 4/11/2017 1230 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-21 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1139 5.75 17.3 1.0 1142 5.69 16.5 2.0 1144 5.67 16.3 Final 3.0 1147 5.65 16.3 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab 4/11/2017 1305 disposable teflon bailer ENCO none/clear HCL HNO3 83 83 91 5.90 Disposable Teflon Bailer 85 Sunny 1.0 Electric Water Level Probe TOC 38.21 44.11 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-24 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1505 6.49 16.9 1.1 1507 5.93 16.6 2.2 1508 5.91 16.6 Final 3.3 1509 5.66 16.5 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab TOC 25.00 31.60 Sunny 253 256 255 6.60 1.1 Electric Water Level Probe Disposable Teflon Bailer ENCO none/clear HCL HNO3 252 4/11/2017 1430 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-25 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1431 5.87 17.8 0.1 1432 5.87 17.9 0.2 1433 5.93 17.9 Final 0.3 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab 4/11/2017 1415 disposable teflon bailer ENCO none/clear HCL HNO3 157 162 158 0.87 Disposable Teflon Bailer DRY before 0.3 gallons Sunny 0.1 Electric Water Level Probe TOC 30.63 31.50 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-25A Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1428 6.83 18.5 4.8 1437 6.25 17.6 9.6 1443 6.31 17.6 Final 14.4 1448 6.35 17.5 Note: During purging well went dry after 4 gal.; let recharge for 5 mins and continued without issue. Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottle Comments Lab TOC 30.86 60.00 Sunny 141 151 136 29.14 4.8 Electric Water Level Probe Field Cleaned Typhoon Pump ENCO none/clear HCL HNO3 137 4/11/2017 1405 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-26 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/11/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1118 5.62 15.0 1.5 1120 5.71 14.7 3.0 1123 5.77 14.6 Final 4.5 1125 5.83 14.6 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs & THF (3) 40 mL glass vials Appendix I Metals + Hg, Mn, Fe (1) 250 mL plastic bottle Comments Lab 955 disposable teflon bailer ENCO none/clear HCL HNO3 111 Alkalinity/TDS/ Chloride/Sulfate (1) 250 mL plastic bottle Sunny 1.5 None 4/12/2017 Disposable Teflon Bailer 116 Electric Water Level Probe TOC 13.69 23.00 9.31 126 118 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-27 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/11/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1133 5.53 16.1 1.5 1136 5.49 15.7 3.0 1138 5.47 15.8 Final 4.5 1140 5.50 15.8 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs & THF (3) 40 mL glass vials Appendix I Metals + Hg, Mn, Fe (1) 250 mL plastic bottle Comments Lab 219 Sunny Alkalinity/TDS/ Chloride/Sulfate (1) 250 mL plastic bottle None 8.87 1.5 222 177 214 Disposable Teflon Bailer TOC 18.13 27.00 Electric Water Level Probe ENCO none/clear HCL HNO3 4/12/2017 1010 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-28 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/11/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 931 5.45 17.4 1.4 935 5.25 17.3 2.8 937 5.26 17.1 Final 4.2 939 5.26 17.1 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs & THF (3) 40 mL glass vials Appendix I Metals + Hg, Mn, Fe (1) 250 mL plastic bottle Comments Lab 835 disposable teflon bailer ENCO none/clear HCL HNO3 43 Alkalinity/TDS/ Chloride/Sulfate (1) 250 mL plastic bottle Sunny 1.4 None 4/12/2017 Disposable Teflon Bailer 41 Electric Water Level Probe TOC 45.71 54.50 8.79 59 47 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-29 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/11/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1006 5.97 17.1 0.5 1007 5.99 17.0 1.0 1008 6.05 17.0 Final 1.5 1009 6.02 16.9 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs & THF (3) 40 mL glass vials Appendix I Metals + Hg, Mn, Fe (1) 250 mL plastic bottle Comments Lab 855 disposable teflon bailer ENCO none/clear HCL HNO3 295 Alkalinity/TDS/ Chloride/Sulfate (1) 250 mL plastic bottle Sunny 0.5 None 4/12/2017 Disposable Teflon Bailer 287 Electric Water Level Probe TOC 42.00 45.00 3.00 275 295 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-30 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/11/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1035 5.84 16.0 1.8 1039 6.00 15.7 3.6 1042 5.93 15.7 Final 5.4 1045 5.97 15.6 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs & THF (3) 40 mL glass vials Appendix I Metals + Hg, Mn, Fe (1) 250 mL plastic bottle Comments Lab 920 disposable teflon bailer ENCO none/clear HCL HNO3 46 Alkalinity/TDS/ Chloride/Sulfate (1) 250 mL plastic bottle Sunny 1.8 None 4/12/2017 Disposable Teflon Bailer 50 Electric Water Level Probe TOC 52.85 64.00 11.15 62 55 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-31 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/11/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1057 6.10 16.2 1.8 1059 5.65 16.0 3.6 1103 5.54 15.9 Final 5.4 1107 5.47 15.9 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs & THF (3) 40 mL glass vials Appendix I Metals + Hg, Mn, Fe (1) 250 mL plastic bottle Comments Lab 935 disposable teflon bailer ENCO none/clear HCL HNO3 46 Alkalinity/TDS/ Chloride/Sulfate (1) 250 mL plastic bottle Sunny 1.8 None 4/12/2017 Disposable Teflon Bailer 48 Electric Water Level Probe TOC 28.85 40.00 11.15 60 52 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-32R Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1153 6.09 15.4 2.1 1158 5.46 15.0 4.2 1202 5.40 15.1 Final 6.3 1204 5.35 15.1 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottles Comments Lab TOC 15.34 28.05 Sunny 15 17 18 12.71 Disposable Teflon Bailer 2.1 Electric Water Level Probe ENCO slightly turbid HCL HNO3 17 4/11/2017 1315 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-33 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1219 5.90 15.6 2.0 1223 5.87 15.6 4.0 1223 5.82 14.6 Final 6.0 1231 5.89 14.7 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottles Comments Lab 4/11/2017 1330 disposable teflon bailer ENCO HCL HNO3 78 82 80 12.16 Disposable Teflon Bailer 82 Sunny 2.0 Electric Water Level Probe TOC 13.14 25.30 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-33A Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1215 6.04 16.5 8.3 1222 6.66 15.8 16.6 1227 6.72 15.7 Final 24.9 1234 6.72 15.8 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottles Comments Lab TOC 13.74 64.55 Sunny 204 241 230 50.81 Field Cleaned Typhoon Pump 8.3 Electric Water Level Probe ENCO none/clear HCL HNO3 215 4/11/2017 1325 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-35 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1305 6.73 16.5 0.3 1307 5.81 16.2 0.6 1308 5.54 16.2 Final 0.9 1316 6.60 15.9 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottles Comments Lab TOC 35.25 37.25 Sunny 16 13 13 2.00 Disposable Teflon Bailer 0.3 Electric Water Level Probe ENCO slightly turbid HCL HNO3 18 4/11/2017 1340 disposable teflon bailer Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-35A Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/10/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1301 8.10 17.9 5.6 1305 6.53 16.9 11.2 1309 6.38 16.1 Final 16.8 1313 6.39 16.1 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs (3) 40 mL glass vials Appendix I Metals (1) 500 mL plastic bottles Comments Lab 4/11/2017 1345 disposable teflon bailer ENCO none/clear HCL HNO3 46 49 46 34.21 Field Cleaned Typhoon Pump 47 Sunny 5.6 Electric Water Level Probe TOC 35.48 69.69 Project Name: Lincoln County Landfill Project Location: Crouse, North Carolina Project Number: 1356-07-004 Well ID MW-36 Sampling Personnel (1) SJT (2) NGS Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.174) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/11/2017 Purging Equipment Total Volume (Gal)Time pH Temp (C)Conductance (µS) Initial 0 1019 5.83 15.9 1.5 1021 5.64 15.3 3.0 1024 5.62 15.2 Final 4.5 1026 5.63 15.2 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Appendix I VOCs & THF (3) 40 mL glass vials Appendix I Metals + Hg, Mn, Fe(1) 250 mL plastic bottle Comments Lab slightly turbid ENCO HCL HNO3 Alkalinity/TDS/ Chloride/Sulfate (1) 250 mL plastic bottle None 19 15 15 4/12/2017 910 disposable teflon bailer 27.49 36.68 9.19 Electric Water Level Probe Disposable Teflon Bailer 22 Sunny TOC 1.5 Appendix IV – Statistical Analysis Procedures Appendix V – Graphs Depicting Concentrations over Time for Wells with a Statistically Significant Increase 0 10 20 30 40 50 60 70 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date 1,1 - Dichloroethane Phase 1 and Area "E" Wells With SSI MW-13 MW-14 MW-16 MW-19 MW-20 Note: Non-DetectValues are Set at Method Detection Limits 0 1 2 3 4 5 6 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date 1,4 - Dichlorobenzene Phase 1 and Area "E" Wells With SSI MW-13 MW-16 Note: Non-DetectValues are Set at Method Detection Limits 0 100 200 300 400 500 600 700 800 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Acetone Phase 1 and Area "E" Wells With SSI MW-13 Note: Non-DetectValues are Set at Method Detection Limits 0 10 20 30 40 50 60 70 80 90 100 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Arsenic Phase 1 and Area "E" Wells With SSI MW-13 MW-16 Note: Non-DetectValues are Set at Method Detection Limits 0 2000 4000 6000 8000 10000 12000 14000 16000 18000 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Barium Phase 1 and Area "E" Wells With SSI MW-15 MW-16 MW-10 MW-12 MW-13 MW-17 Note: Non-DetectValues are Set at Method Detection Limits 0 2 4 6 8 10 12 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Benzene Phase 1 and Area "E" Wells With SSI MW-13 MW-16 MW-19 Note: Non-DetectValues are Set at Method Detection Limits 0 5 10 15 20 25 30 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Beryllium Phase 1 and Area "E" Wells With SSI MW-15 MW-8 Note: Non-DetectValues are Set at Method Detection Limits 0 2 4 6 8 10 12 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date cis-1,2-Dichloroethane Phase 1 and Area "E" Wells With SSI MW-13 MW-16 MW-19 MW-20 Note: Non-DetectValues are Set at Method Detection Limits 0 1 2 3 4 5 6 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Chlorobenzene Phase 1 and Area "E" Wells With SSI MW-16 Note: Non-DetectValues are Set at Method Detection Limits 0 5 10 15 20 25 30 35 40 45 50 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Chloroethane Phase 1 and Area "E" Wells With SSI MW-13 MW-16 Note: Non-DetectValues are Set at Method Detection Limits 0 100 200 300 400 500 600 700 800 900 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Cobalt Phase 1 and Area "E" Wells With SSI MW-12 MW-13 MW-17 MW-8 Note: Non-DetectValues are Set at Method Detection Limits 0 10 20 30 40 50 60 70 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Lead Phase 1 and Area "E" Wells With SSI MW-16 Note: Non-DetectValues are Set at Method Detection Limits 0 10 20 30 40 50 60 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Methylene Chloride Phase 1 and Area "E" Wells With SSI MW-13 MW-16 MW-19 MW-20 Note: Non-DetectValues are Set at Method Detection Limits 0 1 2 3 4 5 6 7 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Tetrachloroethene Phase 1 and Area "E" Wells With SSI MW-13 MW-19 Note: Non-DetectValues are Set at Method Detection Limits 0 5 10 15 20 25 30 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Thallium Phase 1 and Area "E" Wells With SSI MW-13 Note: Non-DetectValues are Set at Method Detection Limits 0 2 4 6 8 10 12 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Toluene Phase 1 and Area "E" Wells With SSI MW-13 Note: Non-DetectValues are Set at Method Detection Limits 0 1 2 3 4 5 6 7 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Trichloroethene Phase 1 and Area "E" Wells With SSI MW-13 MW-19 Note: Non-DetectValues are Set at Method Detection Limits 0 1 2 3 4 5 6 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Trichlorofluoromethane Phase 1 and Area "E" Wells With SSI MW-19 Note: Non-DetectValues are Set at Method Detection Limits 0 100 200 300 400 500 600 700 800 900 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Vanadium Phase 1 and Area "E" Wells With SSI MW-10 Note: Non-DetectValues are Set at Method Detection Limits 0 5 10 15 20 25 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Vinyl Chloride Phase 1 and Area "E" Wells With SSI MW-13 MW-16 Note: Non-DetectValues are Set at Method Detection Limits 0 5 10 15 20 25 30 35 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Total Xylenes Phase 1 and Area "E" Wells With SSI MW-13 MW-16 MW-17 Note: Non-DetectValues are Set at Method Detection Limits 0 1000 2000 3000 4000 5000 6000 7000 1/1/1992 9/27/1994 6/23/1997 3/19/2000 12/14/2002 9/9/2005 6/5/2008 3/2/2011 11/26/2013 8/22/2016 5/19/2019Concentration (ug/L)Date Zinc Phase 1 and Area "E" Wells With SSI MW-12 Note: Non-DetectValues are Set at Method Detection Limits 0 100 200 300 400 500 600 1/1/1999 9/27/2001 6/23/2004 3/20/2007 12/14/2009 9/9/2012 6/6/2015 3/2/2018 11/26/2020Concentration (ug/L)Date Barium Phase 2 Wells With SSI MW-25 Note: Non-DetectValues are Set at Method Detection Limits 0 0.5 1 1.5 2 2.5 1/1/1999 9/27/2001 6/23/2004 3/20/2007 12/14/2009 9/9/2012 6/6/2015 3/2/2018 11/26/2020Concentration (ug/L)Date Beryllium Phase 2 Wells With SSI MW-24 Note: Non-DetectValues are Set at Method Detection Limits 0 5 10 15 20 25 30 35 1/1/1999 9/27/2001 6/23/2004 3/20/2007 12/14/2009 9/9/2012 6/6/2015 3/2/2018 11/26/2020Concentration (ug/L)Date Cobalt Phase 2 Wells With SSI MW-25A Note: Non-DetectValues are Set at Method Detection Limits 0 5 10 15 20 25 30 35 1/14/2004 5/28/2005 10/10/2006 2/22/2008 7/6/2009 11/18/2010 4/1/2012 8/14/2013 12/27/2014 5/10/2016 9/22/2017 2/4/2019Concentration (ug/L)Date Antimony Phase 3 Wells With SSI MW-33A Note: Non-DetectValues are Set at Method Detection Limits Appendix VI– Monthly Methane Data (October 2016 – April 2017)