5803_MadisonCountyMSWLF_WQMR_20180213

DElectronic Data -Email CD data loaded: Yes / No Doc/Event#: Environmental Monitoring Division of Waste Management -Solid Waste Reportin Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 28 surface water standards. The notification
must include a preliminary analysis of the cause and significance ofeach value. (e.g. naturally occurring, off-site source, pre-existing condition; etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.--t:
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 138 .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic. Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste ·section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
AnchorQEA of North Carolina, PLLC
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Brian Gant Phone: [phone] --�----------------------
E -ma i I: [e-mail]
Facility name: Facility Address:
Madison County Operating Solid 271 Craig Rudisill Road Waste Facility Marshall, NC 28753
Environmental Status: (Check all that apply) D Initial/Background Monitoring � Detection Monitoring
T e of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells
X Leachate monitoring data X Surface water monitorin data
Notification attached?
NC Landfill Rule: Actual sampling dates (e.g., October 20-24, 2006) Facility Permit# (.0500 or .1600) EJ .0500 and .1600
D Assessment Monitoring
D Methane gas monitoring data D Corrective action data (specify) D Other(specify)
October 17-18, 2017
D Corrective Action
D . No. No groundwater or surface water standards were exceeded.
� Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 28 surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. D Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification To the best of my knowledge,. the information reported and statements made on this data submittal and attachments are �rue and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Alec Macbeth, PG Project Geologist
Facility Representative Name (Print) Title
�tJ� P. 'rVl4 �
Signature
231 Haywood Street Asheville, North Carolina 28801
Facility Representative Address
P�1649
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009
828-281-3350
(Area Code) Telephone Number
February 13, 2018 Affix NC Licensed/ Professional Geologist Seal
Date
'1

February 2018
Madison County Operating Solid Waste Facility, Permit No. 58-03
Fall 2017
Semiannual Water Quality Monitoring Report
Prepared for Madison County, North Carolina

Project Number: C71500-01.01 \\Asheville1\Asheville\Projects\Madison County\Reports\2017\Fall\5803-Operating\Final_DRAFT5803Oct2017 Semiannual Water Quality Report
February 2018
Madison County Operating Solid Waste Facility, Permit No. 58-03
Fall 2017
Semiannual Water Quality Monitoring Report
Prepared for
Madison County, North Carolina
P.O. Box 579
Marshall, North Carolina 28753
Prepared by
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
____________________________________________
Alec Macbeth, PG
Project Geologist
Fall 2017
Semiannual Water Quality Monitoring Report i February 2018
TABLE OF CONTENTS
1 Introduction ................................................................................................................................ 1
2 Semiannual Monitoring ........................................................................................................... 2
2.1 Monitoring Well Sampling Methods ........................................................................................................... 2
2.2 Surface Water Sampling Methods ................................................................................................................ 2
2.3 Leachate Sampling Methods .......................................................................................................................... 3
2.4 Sample Handling, Documentation, and Analysis .................................................................................... 3
3 Findings ........................................................................................................................................ 4
3.1 Analytical Results ................................................................................................................................................. 4
3.1.1 Groundwater ......................................................................................................................................... 5
3.1.2 Surface Water ........................................................................................................................................ 5
3.1.3 Leachate .................................................................................................................................................. 6
3.1.4 Groundwater Flow Direction ........................................................................................................... 7
4 Summary ...................................................................................................................................... 8
4.1 Future Activities ................................................................................................................................................... 8
5 References ................................................................................................................................... 9

Fall 2017
Semiannual Water Quality Monitoring Report ii February 2018
TABLES
Table 1 Well Construction Details and Corresponding Elevations
Table 2 Summary of Laboratory Analyses Performed on Samples
Table 3 Groundwater and Surface Water Summary of Analytical Results
Table 4 Leachate Summary of Analytical Results

FIGURES
Figure 1 Site Location Map
Figure 2 Sample Location Map
Figure 3 Generalized Groundwater Flow

APPENDICES
Appendix A Sampling Logs and Equipment Documentation and Instrument Calibration Data Sheets
Appendix B Report of Laboratory Analysis and Chain-of-Custody Documentation
Fall 2017
Semiannual Water Quality Monitoring Report iii February 2018
ABBREVIATIONS
µg/L micrograms per liter
µS/cm microsiemens per centimeter
2B standards North Carolina surface water quality standards, defined in 15A NCAC 2B
2L standards North Carolina groundwater quality standards, defined in
15A NCAC 2L .0202
C&D construction and demolition debris
DEQ North Carolina Department of Environmental Quality
DO dissolved oxygen
DWM Division of Waste Management
EPA U.S. Environmental Protection Agency
IMAC interim maximum allowable concentration
MDL method detection limit
mg/L milligrams per liter
MRL method reporting limit
MSW municipal solid waste
mV millivolt
NCAC North Carolina Administrative Code
NTU nephelometric turbidity unit
ORP oxidation reduction potential
SC specific conductivity
SU Standard Unit
SWS Solid Waste Section
SWSL Solid Waste Section Limit
VOC volatile organic compound

Fall 2017
Semiannual Water Quality Monitoring Report 1 February 2018
1 Introduction
The Madison County Solid Waste Department operates a solid waste facility (Operating Landfill)
located on Craig Rudisill Road, west of U.S. Highway 25/70, near Marshall, North Carolina. A site
location map is included as Figure 1. The Operating Landfill includes the following permitted
components (Figure 2):
• Operating construction and demolition debris (C&D) landfill cell (Permit No. 58-03)
• Operating transfer station (Permit No. 58-03T)
• Closed C&D landfill cell (Permit No. 58-03)
• Closed municipal solid waste (MSW) landfill cell (Permit No. 58-03)
The Operating Landfill also contains a leachate underground holding tank that was installed in
August 2011. Previously, the leachate was stored in a lined leachate basin that is no longer in use.
State landfill regulations are enforced by the North Carolina Department of Environmental Quality
(DEQ), Division of Waste Management (DWM). The Operating Landfill is permitted by the DEQ DWM
under Permit No. 58-03. The permit requires semiannual monitoring of groundwater, surface water,
and leachate quality.
This report, prepared by Anchor QEA of North Carolina, PLLC (Anchor QEA), documents the second
semiannual water quality monitoring event of 2017 at the Madison County Operating Landfill and
provides an evaluation of groundwater, surface water, and leachate quality for the Operating Landfill.
It is being submitted in accordance with requirements stipulated in the DEQ Solid Waste
Management Rules, Title 15A, North Carolina Administrative Code (NCAC), Subchapter 13B (15A
NCAC 13B).
The current water quality monitoring network for the Operating Landfill consists of nine compliance
monitoring wells (MW-01, MW-02, MW-03, MW-04, MW-05, MW-06R, MW-07R, MW-08, and
MW-09), two surface water sample locations (SW-01 [upstream] and SW-02R [downstream]) along a
tributary of Walnut Creek, and a leachate sample location (LT-01) collected from the fill port on the
underground holding tank. Monitoring well construction details are summarized in Table 1. These
monitoring wells are screened in the upper saturated zone (MW-03, MW-06R, and MW-09), in the
partially weathered rock/transition zone1 (MW-01, MW-02, MW-07R, and MW-08), and within the
bedrock (MW-04 and MW-05 [interpreted]). Monitoring well MW-06R is used to evaluate the
background groundwater quality at the Operating Landfill. This monitoring well was installed on
September 30, 2008, as a replacement for the pre-existing background monitoring well, MW-06,
which had historically been dry.

1 The partially weathered rock/transition zone is a depth interval that represents the transition from unconsolidated materials to competent bedrock. It can be highly variable in thickness.
Fall 2017
Semiannual Water Quality Monitoring Report 2 February 2018
2 Semiannual Monitoring
On October 17 and 18, 2017, Anchor QEA collected nine groundwater samples from the monitoring
wells (including background well MW-06R), two surface water samples from the established surface
water locations, and one aqueous sample from the leachate underground holding tank. Sampling
locations are shown in Figures 2 and 3.
2.1 Monitoring Well Sampling Methods
Prior to collection of groundwater samples from the monitoring wells, the static water level was
measured and recorded for each well. The monitoring wells were then purged and sampled with a
peristaltic pump or a bladder pump using low-flow techniques in accordance with the procedures
described in Low-Flow (Minimal Drawdown) Ground-Water Sampling Procedures (Puls and
Barcelona 1996). During the purging process, field parameters (pH, specific conductivity [SC],
dissolved oxygen [DO], oxidation reduction potential [ORP], turbidity, and temperature) were
measured and recorded approximately every 3 minutes. Well purging continued until these
parameters had stabilized for three consecutive readings. The required stabilization criteria are
established by the U.S. Environmental Protection Agency (EPA), Region 4 Science and Ecosystem
Support Division Operating Procedure: Groundwater Sampling (EPA 2017), as follows:
• pH values within ± 0.1 unit
• SC values within ± 3%
• Temperature, DO, and turbidity values within ± 10%
• ORP values within ± 10 millivolts (mV)
Following stabilization of these parameters, a groundwater sample was collected by a technician
wearing a new pair of non-reactive nitrile gloves. Each sample was placed directly into
laboratory-supplied sample containers. Low-flow sampling logs are included in Appendix A.
2.2 Surface Water Sampling Methods
Surface water samples SW-01 and SW-02R were collected at designated locations from an unnamed
tributary of Walnut Creek that flows in a northerly direction adjacent to the western border of the
Operating Landfill (Figure 2). Sample SW-01 is considered representative of surface water quality
upstream of the Operating Landfill, and sample SW-02R is considered representative of surface water
quality downstream from the facility. Surface water samples were collected in laboratory-supplied
sample containers by a technician wearing a new pair of non-reactive nitrile gloves. As with
groundwater sampling, field parameters (pH, SC, DO, ORP, turbidity, and temperature) were
measured and recorded at each surface water sampling location prior to sample collection. The field
parameters and observations pertaining to surface water quality are provided in sampling logs
included in Appendix A.
Fall 2017
Semiannual Water Quality Monitoring Report 3 February 2018
2.3 Leachate Sampling Methods
One aqueous sample, LT-01, was collected from the leachate underground holding tank. Historically,
leachate had been collected from a lined storage basin. On August 12, 2011, a leachate underground
holding tank was installed and connected to the leachate collection piping associated with the closed
MSW landfill cell. Shortly thereafter, the lined leachate basin was closed.
Leachate sample LT-01 was collected from one of the tank’s fill ports on October 17, 2017, using a
new disposable polyethylene bailer. One round of field parameters (as described in the preceding
sections) was measured and recorded for the sample (Appendix A). Leachate that collects in the
holding tank at the Operating Landfill is transported as needed by truck to the sewage treatment
facility in Marshall, North Carolina.
2.4 Sample Handling, Documentation, and Analysis
Field parameters for groundwater and surface water were measured, and the results are provided in
the sampling logs included in Appendix A. Following sample collection, each sample was
immediately placed on ice in a sample cooler for transport to TestAmerica Laboratories, Inc., a
North Carolina-certified laboratory located in Nashville, Tennessee. Anchor QEA submitted the
groundwater, surface water, and leachate samples for the required analyses summarized in Table 2.
Proper chain-of-custody documentation procedures were followed during collection and transport of
each sample. Three trip blanks provided by the laboratory, one for each of the three media collected
(i.e., groundwater, surface water, and leachate), were stored in separate sample coolers before being
analyzed for Appendix I volatile organic compounds (VOCs). The reports of laboratory analysis and
chain-of-custody documentation are provided in Appendix B.
Fall 2017
Semiannual Water Quality Monitoring Report 4 February 2018
3 Findings
3.1 Analytical Results
The field parameter data and laboratory analytical results for the groundwater and surface water
samples, the leachate sample, and the trip blanks are included in Appendices A and B. Results are
also submitted separately to the DEQ DWM Solid Waste Section (SWS) in the Electronic Data
Deliverable format (most recently updated on May 5, 2010).
All laboratory analytical results were reported and appropriately qualified as follows:
• Non-detections: Non-detections (non-detects) are values reported by the laboratory as
below method detection limits (MDLs). They are tabulated in Table 3 and flagged with a “U”
qualifier. The MDL is the minimum concentration of a substance that can be measured and
reported by a laboratory with 99% confidence that the constituent concentration is greater
than zero.
• Solid Waste Section Limits: All detections (values above the MDL) were compared to
constituent-specific Solid Waste Section Limits (SWSLs) established by the DEQ. The SWSL is
defined as the lowest concentration of a constituent in a sample that can be quantitatively
determined with suitable precision and accuracy. A non-italicized “J” qualifier is used by the
laboratory for parameters that are detected at estimated concentrations greater than the MDL
but less than the laboratory’s method reporting limit (MRL). The MRL is the minimum
concentration of a target analyte that can be accurately determined by the referenced
method.
• Estimated or “J”-Qualified: If the reported concentration is greater than the laboratory MDL
and MRL, but less than the SWSL, the analytical result is qualified as estimated and is flagged
with an italicized “J” qualifier by Anchor QEA, per SWS reporting requirements. In addition to
non-detects, detected concentrations of constituents below the applicable SWSLs are
included in Table 3.
• 2L Standard: Detected concentrations of constituents in groundwater samples were
compared to applicable North Carolina groundwater quality standards. For most constituents,
this is the 2L standard, defined in 15A NCAC 2L .0202. Detected concentrations of analytes in
groundwater with no established 2L standard were compared either to the interim maximum
allowable concentrations (IMACs) for Class GA and GSA groundwater (in accordance with
15A NCAC 02L .0202 [c]), or to the Groundwater Protection Standards pursuant to
15A NCAC 13B .1634.
• 2B Standard: Detections of analytes in surface water samples were compared to the surface
water quality standards described in 15A NCAC 2B (2B standards).
Fall 2017
Semiannual Water Quality Monitoring Report 5 February 2018
Table 3 presents a summary of detected constituents and outlines concentrations of analytes that
were above the applicable SWSLs, as well as detected analytes that exceeded their respective 2L
standard, IMAC, Groundwater Protection Standard, or 2B standard.
3.1.1 Groundwater
The following sections summarize the results of laboratory and field parameter analyses of
groundwater samples.
3.1.1.1 Field Parameters
Field parameters were recorded during the sampling activities on October 17 and 18, 2017.
Measured pH values for samples collected from the monitoring wells ranged from 5.58 to
6.31 Standard Units (SU), all below the 2L standard pH range of 6.5 to 8.5 SU (Table 3).
Turbidity values ranged from 3.44 Nephelometric Turbidity Units (NTUs) to 156 NTUs. DO values
ranged from 0.78 milligrams per liter (mg/L; MW-01 and MW-02) to 9.43 mg/L (MW-07R). SC
measurements ranged from 45 microsiemens per centimeter (µS/cm; MW-07R) to 261 µS/cm
(MW-03). ORP values ranged between -90.7 mV (MW-09) to 224.0 mV (MW-07R). These field
parameters do not have established groundwater standards. A summary of field parameters is
provided in Table 3.
3.1.1.2 Appendix I Metals
Eight metals were detected in the samples collected from one or more of the monitoring wells. Four
of the metals (i.e., barium, cobalt, lead, and zinc) were detected at concentrations above their SWSLs
in one or more of the groundwater samples (Table 3). Two of the metals, cobalt and vanadium, were
detected at concentrations above their groundwater standards. Cobalt was detected at a
concentration above the applicable IMAC in the samples collected from monitoring wells MW-01,
MW-02, MW-03, MW-05, and MW-07R (Table 3). Vanadium was detected at a concentration above
the applicable IMAC standard in samples collected from all the monitoring wells, with the exception
of MW-01 and MW-03 (Table 3).
3.1.1.3 Appendix I Volatile Organic Compounds
One VOC, benzene, was detected in the groundwater sample collected from MW-05 at a
concentration of 0.219 J micrograms per liter (µg/L), which is well below the compound’s SWSL and
2L standard.
3.1.2 Surface Water
The following sections summarize the results of laboratory and field parameter analyses of surface
water samples SW-01 and SW-02R.
Fall 2017
Semiannual Water Quality Monitoring Report 6 February 2018
3.1.2.1 Field Parameters
The pH values recorded for surface water samples SW-01 and SW-02R were measured at 6.61 SU
and 6.30 SU, respectively. Both pH results are within the 2B standard range of 6.0 to 9.0 SU.
The measured turbidity values for SW-01 and SW-02R were 4.62 NTUs and 7.60 NTUs, respectively.
Both readings are within the 2B standard for turbidity established at 25 NTUs (Table 3).
DO was recorded at 4.54 mg/L and 12.30 mg/L for surface water samples SW-01 and SW-02R,
respectively. The DO concentration for surface water sample SW-01 is outside of the 2B standard,
established as equal to or greater than 5.0 mg/L.
SC measurements were recorded at 118 µS/cm and 124 µS/cm for surface water samples SW-01 and
SW-02R, respectively. ORP values for these surface water samples were recorded at 117.1 mV and
126.1 mV, respectively. These parameters do not have established 2B surface water quality standards.
3.1.2.2 Appendix I Metals
Four metals (i.e., barium, cobalt, lead, and vanadium) were detected in one or both surface water
samples, all at concentrations below their respective SWSLs. The concentration of lead in the
downstream surface water sample (SW-02R) exceeded the established 2B standard of 0.54 µg/L. No
other metals were detected at concentrations above applicable 2B standards (Table 3).
3.1.2.3 Appendix I Volatile Organic Compounds
No VOCs were detected in either of the surface water samples collected from the Operating Landfill.
3.1.3 Leachate
Analytical results for the leachate sample (LT-01) collected from the leachate underground holding
tank are summarized in Table 4 and discussed in the following sections.
3.1.3.1 Field Parameters
Field parameters were measured and recorded for the leachate sample on October 17, 2017, and
summarized as follows:
• pH: 7.35 SU
• DO: 6.12 mg/L
• Turbidity: 19.0 NTUs
• SC: 3,742 µS/cm
• ORP: 150.1 mV
No standards exist for leachate.
Fall 2017
Semiannual Water Quality Monitoring Report 7 February 2018
3.1.3.2 Appendix I Metals
Eleven metals were detected in the aqueous sample collected from the leachate storage tank. Of the
detected metals, four (i.e., barium at 145.0 µg/L; cobalt at 38.5 µg/L; vanadium at 40.5 µg/L; and zinc
at 175.0 µg/L) were detected at concentrations above their respective SWSLs (Table 4).
3.1.3.3 Appendix I Volatile Organic Compounds
Methylene chloride was detected in the leachate sample at a concentration slightly above the SWSL.
This parameter was also detected in the laboratory method blank (flagged with a “B” qualifier in the
analytical report), as well as in the trip blank. No other VOCs were detected in the leachate sample.
3.1.3.4 Inorganics
LT-01 was also analyzed for biochemical oxygen demand, chemical oxygen demand, nitrate,
phosphorus, and sulfate. The analytical results for these parameters are summarized as follows:
• Biochemical oxygen demand: 2,770 µg/L
• Chemical oxygen demand: 111,000 µg/L
• Nitrate: 43,400 µg/L
• Total Phosphorous: 135 µg/L
• Sulfate: 159,000 J µg/L
Nitrate was detected at a concentration in excess of the SWSL (see Table 4). None of the other
parameters, with the exception of sulfate, have established SWSLs. Sulfate was detected well below
its SWSL.
3.1.4 Groundwater Flow Direction
Based on groundwater measurements from monitoring wells MW-03, MW-06R and MW-9, taken by
Anchor QEA on October 17 and 18, 2017, the predominant groundwater flow direction was
calculated within the saturated upper zone overlying the transition zone and bedrock. (The
remaining monitoring wells are interpreted to be screened in the transition zone or bedrock.). The
calculated groundwater flow direction appears to be west-northwest, toward the unnamed tributary
of Walnut Creek. Figure 3 depicts the generalized groundwater flow direction. Water level data and
well construction details are summarized in Table 1.
Fall 2017
Semiannual Water Quality Monitoring Report 8 February 2018
4 Summary
Anchor QEA completed the second semiannual water quality monitoring event of 2017 at the
Operating Landfill on October 17 and 18, 2017.
Two metals, cobalt and vanadium, were detected at concentrations above their groundwater
standards in one or more samples collected from the monitoring wells. No VOCs were detected at
concentrations above the groundwater standards in the samples collected from the monitoring wells.
The concentration of lead in the downstream surface water sample (SW-02R) exceeded the
established 2B standard of 0.54 µg/L. No VOCs were detected in either surface water sample.
The calculated groundwater flow direction appears to be west-northwest, toward the unnamed
tributary of Walnut Creek. Figure 3 depicts the generalized groundwater flow direction.
Detailed analytical results and field data used to interpret groundwater and surface water quality at
the Operating Landfill are provided in Tables 3 and 4, the sampling logs (Appendix A), and the
TestAmerica Reports of Laboratory Analysis (Appendix B).
4.1 Future Activities
Anchor QEA will continue to measure field parameters and collect water quality samples from
groundwater, surface water, and leachate monitoring points associated with the Operating Landfill.
Water quality samples will be submitted to a North Carolina-certified laboratory for analysis for
Appendix I metals and VOCs on a semiannual basis. The next sampling event is scheduled for
April 2018.
Fall 2017
Semiannual Water Quality Monitoring Report 9 February 2018
5 References
EPA (U.S. Environmental Protection Agency), 2017. Operating Procedure: Groundwater Sampling.
Region 4 Science and Ecosystem Support Division. Revised April 26, 2017.
Puls, R.W., and M.J. Barcelona, 1996. Low-Flow (Minimal Drawdown) Ground-Water Sampling
Procedures. Prepared for the U.S. Environmental Protection Agency, Office of Solid Waste and
Emergency Response. EPA/540/S-95/504. April 1996.

Tables

Table 1
Well Construction Details and Corresponding Elevations
MW-01 1,859.04 1,857.04 6.17 1,852.87 7 1,850.0 2 to 17 1,855.04 PWR/Transition
MW-02 1,898.94 1,895.94 4.70 1,894.24 6 1,889.9 1 to 16 1,892.94 PWR/Transition
MW-03 1,932.96 1,929.46 23.70 1,909.26 NA NA 15.5 to 25.5 1,913.96 Saturated Upper Zone
MW-04 1,935.64 1,932.04 28.15 1,907.49 35.2 1,896.8 70.7 to 80.7 1,861.34 Bedrock
MW-05 1,972.76 1,969.26 47.65 1,925.11 NA NA 46.5 to 61.5 1,922.76 Bedrock (interpreted)
MW-06 2,082.87 2,081.87 NA NA 28 2,053.9 80 to 100 2,001.87 Bedrock
MW-06R 1,942.19 1,942.19 9.25 1,932.94 NA NA 10 to 25 1,932.19 Saturated Upper Zone
MW-07R 1,919.34 1,916.64 28.69 1,890.65 NA NA 26 to 41 1,890.64 PWR/Transition
MW-08 1,899.92 1,896.92 20.05 1,879.87 NA NA 16 to 26 1,880.92 PWR/Transition
MW-09 1,949.43 1,946.43 7.08 1,942.35 NA NA 12.4 to 22.4 1,934.03 Saturated Upper Zone
Notes:
Depth to water measurements were obtained in the field on October 17 and 18, 2017.
PWR: partially weathered rock
Depth to bedrock and screened intervals are measured in feet below ground surface. Data were taken from boring logs completed on September 26 through 29, 1992, by Metro Drill, Inc., and
on April 12, 1995, by Engineering Tectonics.
For MW-01, MW-02, MW-05, and MW-06, TOC elevations are based on the Transition Plan Application report (Law Engineering, April 1994).
For MW-03 and MW-04, TOC elevations are based on the survey performed on December 14, 2006, by McGill Associates staff (J. Dallas Gordon, PLS).
For MW-07R and MW-08, TOC elevations were taken from survey data included in boring logs completed by Bunnell-Lammons Engineering, Inc., on July 28–30, 2003.
For MW-09, the TOC elevation was taken from survey data included in a boring log completed by Bunnell-Lammons Engineering, Inc., on October 13, 2006.
Ground
Elevation
Depth to
Water from
TOC
Screened
Interval
Top of Screen
Elevation
TOC
Elevation
Groundwater
Elevation
Facility
Permit Well ID
Ground elevations are calculated based on TOC elevations and field measurements.
Depth to
Bedrock
Top of Bedrock
Elevation
Geology of
Screened Interval
58-03
Elevations are in feet, based on the North American Vertical Datum of 1988.
MW-03 and MW-04 were installed during closure of the municipal solid waste cell.
Monitoring of background well MW-06 was terminated in fall 2008 because the well was dry. MW-06R was installed on September 27, 2008, to replace MW-06. Survey data for MW-06R are
based on a survey conducted on April 16, 2009, by Wes Cole Land Surveying, Pennsylvania. MW-06 was gauged and recorded if water was present, but not sampled.
Ground survey data were included in the Closure Plan drawing generated by McGill Associates on January 4, 2007. Adjusted depth to bedrock and screened interval elevations were calculated
using original data from the September 1992 boring logs and new data from the December 14, 2006 survey.
TOC: top of casing
NA: not applicable
Fall 2017 Semiannual Water Quality Monitoring Report
Madison County Operating Solid Waste Facility
Page 1 of 1
February 2018
Table 2
Summary of Laboratory Analyses Performed on Samples
Groundwater Samples Surface Water Samples
MW-01 10/17/2017 X X SW-01 10/17/2017 X X
MW-02 10/17/2017 X X SW-02R 10/17/2017 X X
MW-03 10/18/2017 X X
MW-04 10/18/2017 X X Quality Control Sample
MW-05 10/18/2017 X X
MW-06R 10/17/2017 X X
MW-07R 10/17/2017 X X TRIP BLANK (LT-01)10/17/2017 X
MW-08 10/17/2017 X X TRIP BLANK (MW)10/18/2017 X
MW-09 10/18/2017 X X TRIP BLANK (SW)10/17/2017 X
Leachate Sample
LT-01 10/17/2017 X X X X X X X
EPA: U.S. Environmental Protection Agency
SM: Standard Method
VOC: volatile organic compound
VOCs
EPA 8260B
BOD
SM 5210B
Nitrate as N
Nitrate by calc.
COD
SM 5220D
Total
Phosphorus
EPA 365.4
Notes:
Sample
Name
Sulfate
EPA 300.0
Metals and VOC analyses include Appendix I metals per the Code of Federal Regulations (40 CFR Part 258, Appendix I Constituents for Detection Monitoring.)
Metals analyses also include mercury.
Leachate sample LT-01 was collected from the leachate underground holding tank.
BOD: biochemical oxygen demand
COD: chemical oxygen demand
Sample
Name Collect Date Sample Name Collect Date
Sample Name Collect Date
Metals
EPA 6010D
EPA 6020B
EPA 7470A
VOCs
EPA 8260B
Metals
EPA 6010D
EPA 6020B
EPA 7470A
VOCs
EPA 8260B
VOCs
EPA 8260B
Collect Date
Metals
EPA 6010D
EPA 6020B
EPA 7470A
Fall 2017 Semiannual Water Quality Monitoring Report
Madison County Operating Solid Waste Facility
Page 1 of 1
February 2018
Table 3
Groundwater and Surface Water Summary of Analytical Results
VOCs
387
Laboratory Method EPA 8260B
Parameter Barium Beryllium Cadmium Chromium Cobalt Lead Vanadium Zinc Benzene Dissolved
Oxygen pH Turbidity Temperature Specific
Conductivity
Oxidation
Reduction
Potential
CAS Number 7440-39-3 7440-41-7 7440-43-9 7440-47-3 7440-48-4 7439-92-1 7440-62-2 7440-66-6 71-43-2 7782-44-7 SW320 SW330 SW325 SW323 SW336
SWS ID 15 23 34 51 53 131 209 213 16 356 320 330 325 323 336
Units µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/L SU NTU °C µS/cm mV
Sample Name Collect Date Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result
Monitoring Well Samples
MW-01 10/17/2017 85.6 J 0.100 U 0.500 U 3.00 U 1.69 J 2.50 J 0.700 U 5.20 U 0.200 U 0.78 5.78 7.78 14.21 75 116.0
MW-02 10/17/2017 187 0.100 U 0.500 U 3.00 U 26.9 4.00 J 6.77 J 12.0 J 0.200 U 0.78 5.86 25.3 17.17 149 85.9
MW-03 10/18/2017 157 0.100 U 0.500 U 3.00 U 57.9 12.3 0.700 U 5.20 U 0.200 U 0.95 5.96 60.7 17.28 261 0.4
MW-04 10/18/2017 147 0.100 U 0.500 U 3.00 U 0.505 J 4.30 J 7.96 J 5.20 U 0.200 U 2.59 6.25 38.1 16.58 175 130.7
MW-05 10/18/2017 121 0.100 U 0.500 U 3.00 U 1.06 J 2.30 J 5.15 J 7.35 J 0.219 J 4.39 5.82 26.9 11.58 190 214.4
MW-06R 10/17/2017 25.1 J 0.100 U 0.500 U 3.00 U 0.100 U 2.00 U 0.727 J 5.20 U 0.200 U 5.92 6.10 3.84 17.66 100 182.9
MW-07R 10/17/2017 138 0.412 J 0.500 J 6.60 J 2.00 J 5.80 J 9.16 J 22.8 J 0.200 U 9.43 5.58 156 16.02 45 224.0
MW-08 10/17/2017 27.8 J 0.100 U 0.500 U 3.00 U 0.300 J 4.00 J 3.09 J 5.20 U 0.200 U 7.77 6.17 3.44 14.49 213 180.2
MW-09 10/18/2017 162 0.100 U 0.500 U 3.00 U 0.914 J 4.10 J 1.75 J 5.20 U 0.200 U 0.62 6.31 17.1 15.16 151 -90.7
Surface Water Samples
SW-01 10/17/2017 68.9 J 0.100 U 0.500 U 3.00 U 1.49 J 2.00 U 0.700 U 5.20 U 0.200 U 4.54 6.61 4.62 14.45 118 117.1
SW-02R 10/17/2017 58.2 J 0.100 U 0.500 U 3.00 U 0.410 J 3.4 J 1.16 J 5.20 U 0.200 U 12.3 6.30 7.60 11.49 124 126.1
Quality Control Samples
TRIP BLANK (MW)10/18/2017 NA NA NA NA NA NA NA NA 0.200 U NA NA NA NA NA NA
TRIP BLANK (SW)10/17/2017 NA NA NA NA NA NA NA NA 0.200 U NA NA NA NA NA NA
MDL 5.00 0.100 0.500 3.00 0.100 2.00 0.700 5.20 0.200 NA NA NA NA NA NA
MRL 10.0 2.0 1.0 5.0 2.0 5.0 2.0 25.0 1.0 NA NA NA NA NA NA
SWSL 100 1 1 10 10 10 25 10 1 NE NE NE NE NE NE
2L 700 NE 2 10 NE 15 NE 1,000 1 NE 6.5-8.5 NE NE NE NE
IMAC NE 4 NE NE 1 NE 0.3 NE NE NE NE NE NE NE NE
GWPS NE 4 NE NE 1 NE 0.3 NE NE NE NE NE NE NE NE
2B 200,000 6.5 0.15 35 4 0.54 NE 36 51 > 5.0 6.0-9.0 25 NE NE NE
Laboratory Certification Metals
387
EPA 6010D, 6020B
Field Parameters
5445 (pH only)
Fall 2017 Semiannual Water Quality Monitoring Report
Madison County Operating Solid Waste Facility
Page 1 of 2
February 2018
Table 3
Groundwater and Surface Water Summary of Analytical Results
Notes:
Shaded cell
Bold entry
°C
µg/L
µS/cm
2B
2L
CAS Number
Collect Date
EPA U.S. Environmental Protection Agency (method)
GWPS
IMAC
J
J
Laboratory Method
MDL
mg/L milligrams per liter
MRL
mV millivolt
NA
NE
NTU nephelometric turbidity unit
Result
SWS ID
SWSL
U
VOC volatile organic compound
indicates a result in exceedance of the 2L or 2B standards or the IMAC, or greater than or equal to the GWPS (if no 2L/2B standard or IMAC exists)
surface water standard, per North Carolina Administrative Code, Title 15A: Department of Environment and Natural Resources, Subchapter 2B - Surface Water and Wetland Standards (last amended on May 1, 2007). For compounds with no 2B standard established, the EPA National
Criteria Table (current as of May 15, 2013) was consulted for the most stringent standards for fresh water and human health.
groundwater standards from North Carolina Administrative Code (NCAC), Title 15A: Department of Environmental Quality, Subchapter 2L - Groundwater Classifications and Standards (last amended April 1, 2013)
the analytical method used to analyze the constituents
method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero
a unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters
the date on which the sample was collected in the field
Groundwater Protection Standard, pursuant to 15A NCAC 13B .1634.
Current standards were obtained from http://deq.nc.gov/about/divisions/waste-management/waste-management-permit-guidance/solid-waste-section/environmental-monitoring/environmental-monitoring-list/.
Solid Waste Section Limit, which is the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy (as identified by the North Carolina Department of Environmental Quality)
a laboratory data qualifier used for parameters not detected at concentrations above the MDL
Only detected constituents are listed on this table. Please refer to the TestAmerica Laboratories, Inc. Report of Laboratory Analysis for further details.
indicates a result in exceedance of the SWSL
micrograms per liter
microsiemens per centimeter
degrees Celsius
method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method
not applicable
not established
analytical data reported by the laboratory, or field data collected by Anchor QEA
Solid Waste Section identification number
interim maximum allowable concentration. An IMAC is applied to a constituent if there is no 2L standard established. Standards are from NCAC 15A 02L .0202.
a laboratory data qualifier used for parameters detected at estimated concentrations above the MDL, but below the MRL and SWSL
a qualifier assigned by Anchor QEA to reflect a detected concentration that is above the MRL and MDL, but below the SWSL
Fall 2017 Semiannual Water Quality Monitoring Report
Madison County Operating Solid Waste Facility
Page 2 of 2
February 2018
Table 4
Leachate Summary of Analytical Results
VOCs
387
Laboratory Method EPA 8260B
Parameter Antimony Barium Beryllium Chromium Cobalt Copper Lead Nickel Selenium Vanadium Zinc
Methylene
Chloride
CAS Number 7440-36-0 7440-39-3 7440-41-7 7440-47-3 7440-48-4 7440-50-8 7439-92-1 7440-02-0 7782-49-2 7440-62-2 7440-66-6 75-09-2
SWS ID 13 15 23 51 53 54 131 152 183 209 213 140
Units µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L
Sample Name Collect Date Result Result Result Result Result Result Result Result Result Result Result Result
LT-01 10/17/2017 0.901 J 145 0.478 J 3.5 J 38.5 6.3 J 2.4 J 46.9 J 8.0 J 40.5 175 1.53 J, B
TRIP BLANK (LT-01)10/17/2017 NA NA NA NA NA NA NA NA NA NA NA 2.48 J
MDL 0.800 5.00 0.100 3.00 0.100 5.00 2.00 3.00 5.00 0.700 5.20 1.00
MRL 2.0 10.0 2.0 5.0 2.0 10.0 5.0 10.0 5.0 2.0 25 5.0
SWSL 6 100 1 10 10 10 10 50 10 25 10 1
Laboratory Method SM 5210B SM 5220D Nitrate by calc.EPA 365.4 EPA 300.0
Parameter BOD COD Nitrate as N
Total
Phosphorus Sulfate
Dissolved
Oxygen pH Turbidity Temperature
Specific
Conductivity
Oxidation
Reduction
Potential
CAS Number SW316 SW317 14797-55-8 7723-14-0 14808-79-8 7782-44-7 SW320 SW330 SW325 SW323 SW336
SWS ID 316 317 303 412 315 356 320 330 325 323 336
Units µg/L µg/L µg/L µg/L µg/L mg/L SU NTU °C µS/cm mV
Sample Name Collect Date Result Result Result Result Result Result Result Result Result Result Result
LT-01 10/17/2017 2,770 111,000 43,400 135 159,000 J 6.12 7.35 19.0 22.62 3,742 150.1
TRIP BLANK (LT-01)10/17/2017 NA NA NA NA NA NA NA NA NA NA NA
MDL 2,000 4,000 40.0 50.0 12,000 NA NA NA NA NA NA
MRL 2,000 20,000 100 100 20,000 NA NA NA NA NA NA
SWSL NE NE 10,000 NE 250,000 NE NE NE NE NE NE
387
Field Parameters
5445 (pH only)Laboratory Certification
Metals
387
EPA 6010D & 6020B
Laboratory Certification
General Chemistry
Fall 2017 Semiannual Water Quality Monitoring Report
Madison County Operating Solid Waste Facility
Page 1 of 2
February 2018
Table 4
Leachate Summary of Analytical Results
Notes:
Bold entry
°C
µg/L
µS/cm
B
BOD
CAS Number
COD
Collect Date
EPA U.S. Environmental Protection Agency (method)
J
J
Laboratory Method
MDL
mg/L milligrams per liter
MRL
mV millivolt
NA
NE
NTU nephelometric turbidity unit
Result
SM
SU Standard Unit
SWS ID
SWSL
U
VOC
Only detected constituents are listed on this table. Please refer to the TestAmerica Laboratories, Inc. Report of Laboratory Analysis for further details.
indicates a result in exceedance of the SWSL
a laboratory data qualifier used for parameters that were detected in both the laboratory blank and the sample.
biochemical oxygen demand
a unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters
chemical oxygen demand
micrograms per liter
not established
analytical data reported by the laboratory, or field data collected by Anchor QEA
microsiemens per centimeter
degrees Celsius
not applicable
the date on which the sample was collected in the field
a laboratory data qualifier used for parameters detected at estimated concentrations above the MDL, but below the MRL and SWSL
a qualifier assigned by Anchor QEA to reflect a detected concentration that is above the MRL and MDL, but below the SWSL
the analytical method used to analyze the constituents
method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero
method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method
Standard Method
Solid Waste Section identification number
Solid Waste Section Limit, which is the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy (as identified by the North Carolina Department of Environmental Quality)
a laboratory data qualifier used for parameters not detected at concentrations above the MDL
volatile organic compound
Fall 2017 Semiannual Water Quality Monitoring Report
Madison County Operating Solid Waste Facility
Page 2 of 2
February 2018

Figures
[0 2,0001,000
Feet
LEGEND:
Landfill Parcel Boundary
Publish Date: 2018/02/13, 8:05 AM | User: alesueurFilepath: \\Asheville1\Asheville\Projects\Madison County\Figures\GIS\GIS User\MXDs\2017\Fall\5803Oct Figure 1-Site Location Map Operating AQ.mxd
Figure 1Site Location Map
Fall 2017 Semiannual Water Quality Monitoring ReportMadison County Operating Solid Waste Facility, Permit No. 58-03, Marshall, North Carolina
SOURCES:Basemap: USGS 1:24,000 Scale Topo Maps,Marshall Quadrangle, 1990Parcels: Madison County GIS
Anchor QEA of North Carolina, PLLC
!(#I#I@A
@A
@A
@A
@A@A
@A
@A
@A
OperatingTransfer Station
Former Leachate Basin
POND
%Tributary Flow Direction
OperatingC&D Cell
ClosedMSW Cell
ClosedC&D Cell
LT-01
SW-01
SW-02R
MW-05
MW-07R
MW-02
MW-08
MW-03
MW-04
MW-09
MW-06R
MW-01
20251765211519451875 199517052235198520351715200520751725 19
6
5
210
5
19151745
2125175518
8
5 17351985
18952075
2135198519952095
1
9
2
5
1775
192517251785 1835
1795
1715
1895191518051825
181519751935
1815
1825
206
5
1805
1835202519051725 1795
184520652065
1945 19651785
222518551
9
1
5
17751735
1955
17
4
5
1875 195520551765
18651755
1965
2015
1735
19451
9
8
5
22
1
519751755
1805
2205
1985
1925 19951985188519951745
219519351975
20052045 218
5
19
6
5
2055
2175
201519552135212519
4
5
1
9
1
5
21
6
5187521152105
20452155
214
5209517451755
19
7
5
201520051995193520851975
20751965
20651
7
7
5
1765 1785
20351795
20251815 1825
1965
18951835
20552045
18
4
5
20351855186520251875201519
0
5
18951885
200519
4
5
1985199519
7
5
1
9
6
5
19
5
5
1
9
2
5
CRAIG

R
U
D
I
S
I
L
L

R
D
[0 500
Feet
LEGEND:
@A Monitoring Well Location
#ISurface Water Sample Location
Unnamed Tributary
Cell Boundary Locations
!(Leachate Holding Tank
Roads
Elevation Contours (10-Foot Interval)
Publish Date: 2018/02/13, 8:17 AM | User: alesueurFilepath: \\Asheville1\Asheville\Projects\Madison County\Figures\GIS\GIS User\MXDs\2017\Fall\5803OctFigure 2-Sample Location Map Operating AQ.mxd
Figure 2Sample Location Map
Fall 2017 Semiannual Water Quality Monitoring ReportMadison County Operating Solid Waste Facility, Permit No. 58-03, Marshall, North Carolina
SOURCES:Basemap: NC OneMap 2010Roads and Streams: MadisonCounty GIS 2006
Anchor QEA of North Carolina, PLLC
!(%#I#I@A
@A
@A
@A
@A@A
@A
@A
@A
OperatingTransfer Station
Former Leachate Basin
POND
%Tributary Flow Direction OperatingC&D Cell
ClosedMSW Cell
ClosedC&D Cell
Groundwater
FlowDirection
MW-05(1,925.11)
MW-07R(1,890.65)
MW-02(1,894.24)
MW-08
(1,879.87)
MW-03
(1,909.26
MW-04
(1,907.49)
MW-09
(1,942.35)
MW-06R
(1,932.94)
MW-01(1,852.87)
2105 19051875 19951765
2235198520352095
20752005178517951935 1745
1915
18
8
5
19851815
2075 1985199518251
9
2
5
1755
192518351845
189519151765
1
9
7
5
1
9
3
5
2
0
6
5
20
65
1735
1855
202519051745
2065 1965194
5
186
5
2
2
2
5
1
9
1
5
1955 19551875
2
2
1
520552015
196
5 19452205
1
9
8
5
19752195180520551925
19851995 19851
8
8
5
2185
19
9
5193519752045 2175
2005 196520151875204519452165
213519552125211519451915
21
5
5
214521051745
1965
1755
2095176519
7
5
2015200519951935
20851975
207520651775
19
65
17851795
20351815
20251825
1895
1
8
3
5
194
5
2055
20
4
5
1955
1845
185
5
2035
1865
20251875
20151895
1885
19
0
5
19
2
5
2
0
0
5
198519951975196
5
1915192519351955SW-01
SW-02R
[
0 500
Feet
NOTES:1. (1,909.26) = Groundwater Elevation2. Groundwater (GW) flow direction based on GWelevations in water table wells MW-02, MW-03, MW-05,MW-06R, MW-07R, and MW-08.3. GW elevations based on depth to water measurementscollected on October 17 and 18, 2017.
LEGEND:
@A Monitoring Well Location
Groundwater Flow Direction
!(Leachate Tank Location
Unnamed Tributary
Elevation Contours (10-Foot Interval)
Publish Date: 2018/02/13, 8:15 AM | User: alesueurFilepath: \\Asheville1\Asheville\Projects\Madison County\Figures\GIS\GIS User\MXDs\2017\Fall\5803Oct Figure 3-Groundwater Flow(2).mxd
Figure 3Generalized Groundwater Flow
Fall 2017 Semiannual Water Quality Monitoring ReportMadison County Operating Solid Waste Facility, Permit No. 58-03, Marshall, North Carolina
SOURCES:Basemap: NC OneMap 2010Streams: Madison County GIS 2006
Anchor QEA of North Carolina, PLLC

Appendix A
Sampling Logs and Equipment
Documentation and Instrument
Calibration Data Sheets

Appendix B
Report of Laboratory Analysis and
Chain-of-Custody Documentation
ANALYTICAL REPORT
TestAmerica Laboratories, Inc.
TestAmerica Nashville
2960 Foster Creighton Drive
Nashville, TN 37204
Tel: [phone]
TestAmerica Job ID: 490-138924-1
Client Project/Site: Madison Co Operating Landfill Leachate
For:
Anchor QEA of North Carolina PLLC
231 W Haywood Street
Asheville, North Carolina 28801
Attn: Brian Gant
Authorized for release by:
11/6/2017 2:01:53 PM
Ken Hayes, Project Manager II
[phone]
[e-mail]
The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited
parameters, exceptions are noted in this report. This report may not be reproduced except in full,
and with written approval from the laboratory. For questions please contact the Project Manager
at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
1
2
3
4
5
6
7
8
9
10
11
12
13
Table of Contents
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
TestAmerica Job ID: 490-138924-1
Page 2 of 35 TestAmerica Nashville11/6/2017
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .10
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .28
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .31
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .32
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .33
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .34
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .35
1
2
3
4
5
6
7
8
9
10
11
12
13
Sample Summary
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Lab Sample ID Client Sample ID ReceivedCollectedMatrix
490-138924-1 LT-01 Water 10/17/17 13:00 10/18/17 09:55
490-138924-2 Trip Blank Water 10/17/17 00:01 10/18/17 09:55
TestAmerica Nashville
Page 3 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Case Narrative
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-138924-1
Project/Site: Madison Co Operating Landfill Leachate
Job ID: 490-138924-1
Laboratory: TestAmerica Nashville
Narrative
Job Narrative
490-138924-1
Comments
No additional comments.
Receipt
The samples were received on 10/18/2017 9:55 AM; the samples arrived in good condition, properly preserved and, where required, on
ice. The temperature of the cooler at receipt was 0.3º C.
GC/MS VOA
Method 8260B: The RPD of the laboratory control sample (LCS) and laboratory control sample duplicate (LCSD) for analytical batch
490-469123 recovered outside control limits for the following analytes: Styrene.
Method 8260B: The method blank for analytical batch 490-469123 contained Methylene Chloride above the method detection limit. This
target analyte concentration was less than half the reporting limit (1/2RL); therefore, re-analysis of samples was not performed.
Method 8260B: The following volatile sample was analyzed with significant headspace in the sample Container: Trip Blank
(490-138924-2). Significant headspace is defined as a bubble greater than 6 mm in diameter.
Method 8260B: The method blank for analytical batch 490-469238 contained Methylene Chloride above the method detection limit. This
target analyte concentration was less than half the reporting limit (1/2RL); therefore, re-analysis of samples was not performed.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
HPLC/IC
Method 300.0: The following sample was diluted due to the nature of the sample matrix: LT-01 (490-138924-1). Elevated reporting limits
(RLs) are provided.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Metals
Method 6010D: The method blank for preparation batch 490-469156 and analytical batch 490-471125 contained Selenium above the
method detection limit. This target analyte concentration was less than the reporting limit (RL); therefore, re-extraction and/or re-analysis
of samples was not performed.
Method 6010D: The low level continuing calibration verification (CCVL) associated with batch 490-471125 recovered above the upper
control limit for Arsenic, Copper, Lead and Selenium. The samples associated with this CCV were non-detects for the affected analytes;
therefore, the data have been reported.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
General Chemistry
Method 353.2: The closing continuing calibration blank (CCB) for batch 490-469027 contained Nitrite as N above the reporting limit (RL).
The sample result, associated with this continuing calibration blank, is less than the report limit (RL) but greater than the MDL; therefore,
re-extraction and/or re-analysis of samples were not performed.
Method 353.2: The method blank, initial calibration blank, and continuing calibration blank for analytical batch 490-469027 contained
Nitrite as N above the method detection limit. This target analyte concentration was less than the reporting limit (RL); therefore,
re-extraction and/or re-analysis of samples was not performed.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
VOA Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
TestAmerica NashvillePage 4 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Definitions/Glossary
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Qualifiers
GC/MS VOA
Qualifier Description
B Compound was found in the blank and sample.
Qualifier
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
*RPD of the LCS and LCSD exceeds the control limits
Metals
Qualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Qualifier
^ICV,CCV,ICB,CCB, ISA, ISB, CRI, CRA, DLCK or MRL standard: Instrument related QC is outside acceptance limits.
B Compound was found in the blank and sample.
F1 MS and/or MSD Recovery is outside acceptance limits.
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TestAmerica Nashville
Page 5 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Lab Sample ID: 490-138924-1Client Sample ID: LT-01
Matrix: WaterDate Collected: 10/17/17 13:00
Date Received: 10/18/17 09:55
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/20/17 04:05 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
10.0 0.500 ug/L 10/20/17 04:05 1Acrylonitrile<0.500
1.00 0.200 ug/L 10/20/17 04:05 1Benzene<0.200
1.00 0.150 ug/L 10/20/17 04:05 1Bromochloromethane<0.150
1.00 0.170 ug/L 10/20/17 04:05 1Bromodichloromethane<0.170
1.00 0.290 ug/L 10/20/17 04:05 1Bromoform<0.290
1.00 0.350 ug/L 10/20/17 04:05 1Bromomethane<0.350
50.0 2.64 ug/L 10/20/17 04:05 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 10/20/17 04:05 1Carbon disulfide <0.220
1.00 0.180 ug/L 10/20/17 04:05 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 10/20/17 04:05 1Chlorobenzene<0.180
1.00 0.360 ug/L 10/20/17 04:05 1Chloroethane<0.360
1.00 0.230 ug/L 10/20/17 04:05 1Chloroform<0.230
1.00 0.360 ug/L 10/20/17 04:05 1Chloromethane<0.360
1.00 0.210 ug/L 10/20/17 04:05 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 10/20/17 04:05 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 10/20/17 04:05 1Dibromochloromethane<0.250
10.0 0.940 ug/L 10/20/17 04:05 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 10/20/17 04:05 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 10/20/17 04:05 1Dibromomethane<0.450
1.00 0.190 ug/L 10/20/17 04:05 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 10/20/17 04:05 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 10/20/17 04:05 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 10/20/17 04:05 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 10/20/17 04:05 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 10/20/17 04:05 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 10/20/17 04:05 1Ethylbenzene<0.190
10.0 1.28 ug/L 10/20/17 04:05 12-Hexanone <1.28
10.0 1.50 ug/L 10/20/17 04:05 1Iodomethane<1.50
5.00 1.00 ug/L 10/20/17 04:05 1Methylene Chloride 1.53 J B
10.0 0.810 ug/L 10/20/17 04:05 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 10/20/17 04:05 1Styrene<0.280
1.00 0.150 ug/L 10/20/17 04:05 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 10/20/17 04:05 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 10/20/17 04:05 1Tetrachloroethene<0.140
1.00 0.170 ug/L 10/20/17 04:05 1Toluene<0.170
5.00 0.460 ug/L 10/20/17 04:05 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 10/20/17 04:05 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 10/20/17 04:05 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 10/20/17 04:05 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 10/20/17 04:05 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 10/20/17 04:05 1Trichloroethene<0.200
1.00 0.210 ug/L 10/20/17 04:05 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 10/20/17 04:05 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 10/20/17 04:05 1Vinyl acetate <1.71
1.00 0.180 ug/L 10/20/17 04:05 1Vinyl chloride <0.180
3.00 0.580 ug/L 10/20/17 04:05 1Xylenes, Total <0.580
TestAmerica Nashville
Page 6 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Lab Sample ID: 490-138924-1Client Sample ID: LT-01
Matrix: WaterDate Collected: 10/17/17 13:00
Date Received: 10/18/17 09:55
4-Bromofluorobenzene (Surr)85 70-130 10/20/17 04:05 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Dibromofluoromethane (Surr)109 10/20/17 04:05 170-130
1,2-Dichloroethane-d4 (Surr)104 10/20/17 04:05 170-130
Toluene-d8 (Surr)100 10/20/17 04:05 170-130
Method: 300.0 - Anions, Ion Chromatography
RL MDL
Chloride 814 50.0 35.0 mg/L 10/26/17 07:05 50
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
50.0 30.0 mg/L 10/26/17 07:05 50Sulfate159
Method: 6010D - Metals (ICP)
RL MDL
Arsenic <0.00860 ^0.0100 0.00860 mg/L 10/19/17 13:43 10/25/17 16:40 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.0100 0.00500 mg/L 10/19/17 13:43 10/29/17 03:26 1Barium0.145
0.00100 0.000500 mg/L 10/19/17 13:43 10/29/17 03:26 1Cadmium<0.000500
0.00500 0.00300 mg/L 10/19/17 13:43 10/29/17 03:26 1Chromium0.00350 J
0.0100 0.00500 mg/L 10/19/17 13:43 10/25/17 16:40 1Copper0.00630 J ^
0.00500 0.00200 mg/L 10/19/17 13:43 10/25/17 16:40 1Lead0.00240 J ^
0.0100 0.00300 mg/L 10/19/17 13:43 10/29/17 03:26 1Nickel0.0469
0.0100 0.00500 mg/L 10/19/17 13:43 10/25/17 16:40 1Selenium0.00800 J B ^
0.00500 0.00300 mg/L 10/19/17 13:43 10/29/17 03:26 1Silver<0.00300
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony 0.901 J 2.00 0.800 ug/L 10/19/17 13:31 10/20/17 14:38 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2.00 0.100 ug/L 10/19/17 13:31 10/20/17 14:38 1Beryllium0.478 J
2.00 0.100 ug/L 10/19/17 13:31 10/20/17 14:38 1Cobalt38.5
2.00 0.800 ug/L 10/19/17 13:31 10/20/17 14:38 1Thallium<0.800
2.00 0.700 ug/L 10/19/17 13:31 10/20/17 14:38 1Vanadium40.5
25.0 5.20 ug/L 10/19/17 13:31 10/20/17 14:38 1Zinc175
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 10/23/17 22:14 10/24/17 16:44 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General Chemistry
RL MDL
Phosphorus, Total 0.135 0.100 0.0500 mg/L 10/19/17 09:36 10/21/17 06:32 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.100 0.0400 mg/L 10/19/17 09:54 1Nitrate as N 43.4
20.0 4.00 mg/L 10/19/17 15:05 1Chemical Oxygen Demand 111
RL RL
Biochemical Oxygen Demand 2.77 2.00 2.00 mg/L 10/18/17 16:11 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
TestAmerica Nashville
Page 7 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Lab Sample ID: 490-138924-2Client Sample ID: Trip Blank
Matrix: WaterDate Collected: 10/17/17 00:01
Date Received: 10/18/17 09:55
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/19/17 17:21 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
10.0 0.500 ug/L 10/19/17 17:21 1Acrylonitrile<0.500
1.00 0.200 ug/L 10/19/17 17:21 1Benzene<0.200
1.00 0.150 ug/L 10/19/17 17:21 1Bromochloromethane<0.150
1.00 0.170 ug/L 10/19/17 17:21 1Bromodichloromethane<0.170
1.00 0.290 ug/L 10/19/17 17:21 1Bromoform<0.290
1.00 0.350 ug/L 10/19/17 17:21 1Bromomethane<0.350
50.0 2.64 ug/L 10/19/17 17:21 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 10/19/17 17:21 1Carbon disulfide <0.220
1.00 0.180 ug/L 10/19/17 17:21 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 10/19/17 17:21 1Chlorobenzene<0.180
1.00 0.360 ug/L 10/19/17 17:21 1Chloroethane<0.360
1.00 0.230 ug/L 10/19/17 17:21 1Chloroform<0.230
1.00 0.360 ug/L 10/19/17 17:21 1Chloromethane<0.360
1.00 0.210 ug/L 10/19/17 17:21 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 10/19/17 17:21 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 10/19/17 17:21 1Dibromochloromethane<0.250
10.0 0.940 ug/L 10/19/17 17:21 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 10/19/17 17:21 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 10/19/17 17:21 1Dibromomethane<0.450
1.00 0.190 ug/L 10/19/17 17:21 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 10/19/17 17:21 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 10/19/17 17:21 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 10/19/17 17:21 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 10/19/17 17:21 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 10/19/17 17:21 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 10/19/17 17:21 1Ethylbenzene<0.190
10.0 1.28 ug/L 10/19/17 17:21 12-Hexanone <1.28
10.0 1.50 ug/L 10/19/17 17:21 1Iodomethane<1.50
5.00 1.00 ug/L 10/19/17 17:21 1Methylene Chloride 2.48 J B
10.0 0.810 ug/L 10/19/17 17:21 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 10/19/17 17:21 1Styrene<0.280 *
1.00 0.150 ug/L 10/19/17 17:21 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 10/19/17 17:21 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 10/19/17 17:21 1Tetrachloroethene<0.140
1.00 0.170 ug/L 10/19/17 17:21 1Toluene<0.170
5.00 0.460 ug/L 10/19/17 17:21 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 10/19/17 17:21 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 10/19/17 17:21 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 10/19/17 17:21 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 10/19/17 17:21 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 10/19/17 17:21 1Trichloroethene<0.200
1.00 0.210 ug/L 10/19/17 17:21 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 10/19/17 17:21 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 10/19/17 17:21 1Vinyl acetate <1.71
1.00 0.180 ug/L 10/19/17 17:21 1Vinyl chloride <0.180
3.00 0.580 ug/L 10/19/17 17:21 1Xylenes, Total <0.580
TestAmerica Nashville
Page 8 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Lab Sample ID: 490-138924-2Client Sample ID: Trip Blank
Matrix: WaterDate Collected: 10/17/17 00:01
Date Received: 10/18/17 09:55
4-Bromofluorobenzene (Surr)84 70-130 10/19/17 17:21 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Dibromofluoromethane (Surr)110 10/19/17 17:21 170-130
1,2-Dichloroethane-d4 (Surr)101 10/19/17 17:21 170-130
Toluene-d8 (Surr)99 10/19/17 17:21 170-130
TestAmerica Nashville
Page 9 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Method: 8260B - Volatile Organic Compounds (GC/MS)
Client Sample ID: Method BlankLab Sample ID: MB 490-469123/7
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469123
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/19/17 15:07 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
<0.500 0.50010.0 ug/L 10/19/17 15:07 1Acrylonitrile
<0.200 0.2001.00 ug/L 10/19/17 15:07 1Benzene
<0.150 0.1501.00 ug/L 10/19/17 15:07 1Bromochloromethane
<0.170 0.1701.00 ug/L 10/19/17 15:07 1Bromodichloromethane
<0.290 0.2901.00 ug/L 10/19/17 15:07 1Bromoform
<0.350 0.3501.00 ug/L 10/19/17 15:07 1Bromomethane
<2.64 2.6450.0 ug/L 10/19/17 15:07 12-Butanone (MEK)
<0.220 0.2201.00 ug/L 10/19/17 15:07 1Carbon disulfide
<0.180 0.1801.00 ug/L 10/19/17 15:07 1Carbon tetrachloride
<0.180 0.1801.00 ug/L 10/19/17 15:07 1Chlorobenzene
<0.360 0.3601.00 ug/L 10/19/17 15:07 1Chloroethane
<0.230 0.2301.00 ug/L 10/19/17 15:07 1Chloroform
<0.360 0.3601.00 ug/L 10/19/17 15:07 1Chloromethane
<0.210 0.2101.00 ug/L 10/19/17 15:07 1cis-1,2-Dichloroethene
<0.170 0.1701.00 ug/L 10/19/17 15:07 1cis-1,3-Dichloropropene
<0.250 0.2501.00 ug/L 10/19/17 15:07 1Dibromochloromethane
<0.940 0.94010.0 ug/L 10/19/17 15:07 11,2-Dibromo-3-Chloropropane
<0.210 0.2101.00 ug/L 10/19/17 15:07 11,2-Dibromoethane (EDB)
<0.450 0.4501.00 ug/L 10/19/17 15:07 1Dibromomethane
<0.190 0.1901.00 ug/L 10/19/17 15:07 11,2-Dichlorobenzene
<0.170 0.1701.00 ug/L 10/19/17 15:07 11,4-Dichlorobenzene
<0.240 0.2401.00 ug/L 10/19/17 15:07 11,1-Dichloroethane
<0.200 0.2001.00 ug/L 10/19/17 15:07 11,2-Dichloroethane
<0.250 0.2501.00 ug/L 10/19/17 15:07 11,1-Dichloroethene
<0.250 0.2501.00 ug/L 10/19/17 15:07 11,2-Dichloropropane
<0.190 0.1901.00 ug/L 10/19/17 15:07 1Ethylbenzene
<1.28 1.2810.0 ug/L 10/19/17 15:07 12-Hexanone
<1.50 1.5010.0 ug/L 10/19/17 15:07 1Iodomethane
1.500 J 1.005.00 ug/L 10/19/17 15:07 1Methylene Chloride
<0.810 0.81010.0 ug/L 10/19/17 15:07 14-Methyl-2-pentanone (MIBK)
<0.280 0.2801.00 ug/L 10/19/17 15:07 1Styrene
<0.150 0.1501.00 ug/L 10/19/17 15:07 11,1,1,2-Tetrachloroethane
<0.190 0.1901.00 ug/L 10/19/17 15:07 11,1,2,2-Tetrachloroethane
<0.140 0.1401.00 ug/L 10/19/17 15:07 1Tetrachloroethene
<0.170 0.1701.00 ug/L 10/19/17 15:07 1Toluene
<0.460 0.4605.00 ug/L 10/19/17 15:07 1trans-1,4-Dichloro-2-butene
<0.230 0.2301.00 ug/L 10/19/17 15:07 1trans-1,2-Dichloroethene
<0.170 0.1701.00 ug/L 10/19/17 15:07 1trans-1,3-Dichloropropene
<0.190 0.1901.00 ug/L 10/19/17 15:07 11,1,1-Trichloroethane
<0.190 0.1901.00 ug/L 10/19/17 15:07 11,1,2-Trichloroethane
<0.200 0.2001.00 ug/L 10/19/17 15:07 1Trichloroethene
<0.210 0.2101.00 ug/L 10/19/17 15:07 1Trichlorofluoromethane
<0.230 0.2301.00 ug/L 10/19/17 15:07 11,2,3-Trichloropropane
<1.71 1.7110.0 ug/L 10/19/17 15:07 1Vinyl acetate
<0.180 0.1801.00 ug/L 10/19/17 15:07 1Vinyl chloride
<0.580 0.5803.00 ug/L 10/19/17 15:07 1Xylenes, Total
TestAmerica Nashville
Page 10 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 490-469123/7
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469123
4-Bromofluorobenzene (Surr)83 70-130 10/19/17 15:07 1
MB MB
Surrogate Dil FacPrepared AnalyzedQualifier Limits%Recovery
109 10/19/17 15:07 1Dibromofluoromethane (Surr)70-130
101 10/19/17 15:07 11,2-Dichloroethane-d4 (Surr)70-130
99 10/19/17 15:07 1Toluene-d8 (Surr)70-130
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469123/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469123
Acetone 100 97.11 ug/L 97 39-150
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Acrylonitrile 200 186.8 ug/L 93 63-135
Benzene 20.0 19.04 ug/L 95 70-130
Bromochloromethane 20.0 20.82 ug/L 104 70-130
Bromodichloromethane 20.0 19.11 ug/L 96 70-130
Bromoform 20.0 22.05 ug/L 110 70-137
Bromomethane 20.0 18.92 ug/L 95 53-150
2-Butanone (MEK)100 99.10 ug/L 99 55-143
Carbon disulfide 20.0 19.76 ug/L 99 64-135
Carbon tetrachloride 20.0 21.22 ug/L 106 70-147
Chlorobenzene 20.0 19.67 ug/L 98 70-130
Chloroethane 20.0 21.77 ug/L 109 60-138
Chloroform 20.0 19.25 ug/L 96 70-130
Chloromethane 20.0 19.92 ug/L 100 33-150
cis-1,2-Dichloroethene 20.0 19.65 ug/L 98 70-130
cis-1,3-Dichloropropene 20.0 18.75 ug/L 94 70-133
Dibromochloromethane 20.0 19.89 ug/L 99 70-133
1,2-Dibromo-3-Chloropropane 20.0 15.85 ug/L 79 45-138
1,2-Dibromoethane (EDB)20.0 19.83 ug/L 99 70-130
Dibromomethane 20.0 18.95 ug/L 95 70-130
1,2-Dichlorobenzene 20.0 19.47 ug/L 97 70-130
1,4-Dichlorobenzene 20.0 18.62 ug/L 93 70-130
1,1-Dichloroethane 20.0 19.14 ug/L 96 70-130
1,2-Dichloroethane 20.0 18.90 ug/L 95 70-130
1,1-Dichloroethene 20.0 19.61 ug/L 98 70-132
1,2-Dichloropropane 20.0 18.86 ug/L 94 70-130
Ethylbenzene 20.0 18.88 ug/L 94 70-130
2-Hexanone 100 89.12 ug/L 89 54-142
Iodomethane 20.0 20.46 ug/L 102 40-150
Methylene Chloride 20.0 20.92 ug/L 105 70-130
4-Methyl-2-pentanone (MIBK)100 92.73 ug/L 93 60-137
Styrene 20.0 18.19 ug/L 91 70-130
1,1,1,2-Tetrachloroethane 20.0 20.54 ug/L 103 70-130
1,1,2,2-Tetrachloroethane 20.0 16.69 ug/L 83 69-131
Tetrachloroethene 20.0 21.93 ug/L 110 70-130
Toluene 20.0 17.93 ug/L 90 70-130
trans-1,4-Dichloro-2-butene 20.0 16.25 ug/L 81 41-150
trans-1,2-Dichloroethene 20.0 19.44 ug/L 97 70-130
TestAmerica Nashville
Page 11 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469123/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469123
trans-1,3-Dichloropropene 20.0 18.67 ug/L 93 63-142
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
1,1,1-Trichloroethane 20.0 19.78 ug/L 99 70-135
1,1,2-Trichloroethane 20.0 18.00 ug/L 90 70-130
Trichloroethene 20.0 20.00 ug/L 100 70-130
Trichlorofluoromethane 20.0 22.78 ug/L 114 59-150
1,2,3-Trichloropropane 20.0 16.10 ug/L 80 70-131
Vinyl acetate 40.0 43.35 ug/L 108 54-146
Vinyl chloride 20.0 20.76 ug/L 104 57-137
Xylenes, Total 40.0 37.75 ug/L 94 70-132
4-Bromofluorobenzene (Surr)70 -130
Surrogate
85
LCS LCS
Qualifier Limits%Recovery
108Dibromofluoromethane (Surr)70 -130
991,2-Dichloroethane-d4 (Surr)70 -130
97Toluene-d8 (Surr)70 -130
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-469123/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469123
Acetone 100 106.2 ug/L 106 39-150 9 23
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Acrylonitrile 200 198.2 ug/L 99 63-135 6 16
Benzene 20.0 20.78 ug/L 104 70-130 9 12
Bromochloromethane 20.0 23.38 ug/L 117 70-130 12 16
Bromodichloromethane 20.0 20.72 ug/L 104 70-130 8 14
Bromoform 20.0 23.33 ug/L 117 70-137 6 14
Bromomethane 20.0 17.92 ug/L 90 53-150 5 19
2-Butanone (MEK)100 101.3 ug/L 101 55-143 2 19
Carbon disulfide 20.0 21.98 ug/L 110 64-135 11 16
Carbon tetrachloride 20.0 23.06 ug/L 115 70-147 8 16
Chlorobenzene 20.0 22.06 ug/L 110 70-130 11 12
Chloroethane 20.0 19.14 ug/L 96 60-138 13 15
Chloroform 20.0 21.55 ug/L 108 70-130 11 14
Chloromethane 20.0 18.10 ug/L 91 33-150 10 20
cis-1,2-Dichloroethene 20.0 21.42 ug/L 107 70-130 9 15
cis-1,3-Dichloropropene 20.0 20.73 ug/L 104 70-133 10 15
Dibromochloromethane 20.0 21.40 ug/L 107 70-133 7 13
1,2-Dibromo-3-Chloropropane 20.0 16.65 ug/L 83 45-138 5 19
1,2-Dibromoethane (EDB)20.0 21.74 ug/L 109 70-130 9 13
Dibromomethane 20.0 19.94 ug/L 100 70-130 5 14
1,2-Dichlorobenzene 20.0 21.35 ug/L 107 70-130 9 12
1,4-Dichlorobenzene 20.0 20.64 ug/L 103 70-130 10 12
1,1-Dichloroethane 20.0 21.16 ug/L 106 70-130 10 17
1,2-Dichloroethane 20.0 20.04 ug/L 100 70-130 6 13
1,1-Dichloroethene 20.0 21.51 ug/L 108 70-132 9 20
1,2-Dichloropropane 20.0 20.68 ug/L 103 70-130 9 15
Ethylbenzene 20.0 21.11 ug/L 106 70-130 11 12
TestAmerica Nashville
Page 12 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-469123/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469123
2-Hexanone 100 94.44 ug/L 94 54-142 6 17
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Iodomethane 20.0 22.95 ug/L 115 40-150 11 20
Methylene Chloride 20.0 22.85 ug/L 114 70-130 9 15
4-Methyl-2-pentanone (MIBK)100 99.07 ug/L 99 60-137 7 21
Styrene 20.0 20.62 * ug/L 103 70-130 13 12
1,1,1,2-Tetrachloroethane 20.0 22.69 ug/L 113 70-130 10 13
1,1,2,2-Tetrachloroethane 20.0 18.20 ug/L 91 69-131 9 15
Tetrachloroethene 20.0 24.06 ug/L 120 70-130 9 17
Toluene 20.0 20.41 ug/L 102 70-130 13 13
trans-1,4-Dichloro-2-butene 20.0 17.88 ug/L 89 41-150 10 20
trans-1,2-Dichloroethene 20.0 21.76 ug/L 109 70-130 11 15
trans-1,3-Dichloropropene 20.0 20.47 ug/L 102 63-142 9 13
1,1,1-Trichloroethane 20.0 21.83 ug/L 109 70-135 10 15
1,1,2-Trichloroethane 20.0 19.62 ug/L 98 70-130 9 13
Trichloroethene 20.0 22.77 ug/L 114 70-130 13 14
Trichlorofluoromethane 20.0 20.03 ug/L 100 59-150 13 22
1,2,3-Trichloropropane 20.0 16.77 ug/L 84 70-131 4 14
Vinyl acetate 40.0 46.56 ug/L 116 54-146 7 20
Vinyl chloride 20.0 18.57 ug/L 93 57-137 11 15
Xylenes, Total 40.0 41.91 ug/L 105 70-132 10 11
4-Bromofluorobenzene (Surr)70 -130
Surrogate
85
LCSD LCSD
Qualifier Limits%Recovery
108Dibromofluoromethane (Surr)70 -130
971,2-Dichloroethane-d4 (Surr)70 -130
98Toluene-d8 (Surr)70 -130
Client Sample ID: Matrix SpikeLab Sample ID: 490-139026-B-2 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469123
Acetone <2.66 100 90.71 ug/L 91 39-150
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Acrylonitrile <0.500 200 192.2 ug/L 96 50-135
Benzene 16.5 20.0 34.77 ug/L 92 55-147
Bromochloromethane <0.150 20.0 20.02 ug/L 100 59-132
Bromodichloromethane <0.170 20.0 19.17 ug/L 96 70-140
Bromoform <0.290 20.0 20.71 ug/L 104 53-150
Bromomethane <0.350 20.0 10.57 ug/L 53 30-150
2-Butanone (MEK)2.96 J 100 100.1 ug/L 97 50-143
Carbon disulfide <0.220 20.0 18.61 ug/L 93 35-150
Carbon tetrachloride <0.180 20.0 20.52 ug/L 103 56-150
Chlorobenzene <0.180 20.0 18.96 ug/L 95 70-130
Chloroethane <0.360 20.0 19.21 ug/L 96 58-141
Chloroform 1.40 20.0 19.63 ug/L 91 66-138
Chloromethane <0.360 20.0 17.48 ug/L 87 10-150
cis-1,2-Dichloroethene 30.8 20.0 50.59 ug/L 99 68-131
cis-1,3-Dichloropropene <0.170 20.0 17.79 ug/L 89 70-133
TestAmerica Nashville
Page 13 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Matrix SpikeLab Sample ID: 490-139026-B-2 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469123
Dibromochloromethane <0.250 20.0 18.97 ug/L 95 66-140
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
1,2-Dibromo-3-Chloropropane <0.940 20.0 15.78 ug/L 79 38-138
1,2-Dibromoethane (EDB)<0.210 20.0 19.05 ug/L 95 65-137
Dibromomethane <0.450 20.0 18.29 ug/L 91 70-130
1,2-Dichlorobenzene <0.190 20.0 18.53 ug/L 93 70-130
1,4-Dichlorobenzene <0.170 20.0 17.90 ug/L 90 70-130
1,1-Dichloroethane <0.240 20.0 18.30 ug/L 91 61-139
1,2-Dichloroethane <0.200 20.0 18.82 ug/L 94 64-136
1,1-Dichloroethene <0.250 20.0 19.05 ug/L 95 54-150
1,2-Dichloropropane <0.250 20.0 18.60 ug/L 93 67-130
Ethylbenzene 3.36 20.0 22.28 ug/L 95 65-139
2-Hexanone <1.28 100 85.69 ug/L 86 44-150
Iodomethane <1.50 20.0 11.74 ug/L 59 34-150
Methylene Chloride <1.00 20.0 22.36 ug/L 112 64-130
4-Methyl-2-pentanone (MIBK)<0.810 100 91.72 ug/L 92 50-140
Styrene <0.280 *20.0 17.19 ug/L 86 70-130
1,1,1,2-Tetrachloroethane <0.150 20.0 19.21 ug/L 96 70-131
1,1,2,2-Tetrachloroethane <0.190 20.0 16.12 ug/L 81 56-145
Tetrachloroethene 4.13 20.0 25.40 ug/L 106 57-138
Toluene 0.306 J 20.0 18.28 ug/L 90 64-136
trans-1,4-Dichloro-2-butene <0.460 20.0 15.52 ug/L 78 39-150
trans-1,2-Dichloroethene <0.230 20.0 19.48 ug/L 97 59-143
trans-1,3-Dichloropropene <0.170 20.0 18.01 ug/L 90 63-142
1,1,1-Trichloroethane <0.190 20.0 19.29 ug/L 96 68-144
1,1,2-Trichloroethane <0.190 20.0 18.40 ug/L 92 70-130
Trichloroethene 2.75 20.0 22.87 ug/L 101 63-135
Trichlorofluoromethane <0.210 20.0 20.56 ug/L 103 44-150
1,2,3-Trichloropropane <0.230 20.0 15.30 ug/L 76 65-131
Vinyl acetate <1.71 40.0 41.35 ug/L 103 43-146
Vinyl chloride <0.180 20.0 20.20 ug/L 101 57-150
Xylenes, Total <0.580 40.0 36.27 ug/L 91 69-132
4-Bromofluorobenzene (Surr)70 -130
Surrogate
84
MS MS
Qualifier Limits%Recovery
109Dibromofluoromethane (Surr)70 -130
991,2-Dichloroethane-d4 (Surr)70 -130
100Toluene-d8 (Surr)70 -130
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-139026-C-2 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469123
Acetone <2.66 100 87.57 ug/L 88 39-150 4 28
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Acrylonitrile <0.500 200 193.5 ug/L 97 50-135 1 23
Benzene 16.5 20.0 34.56 ug/L 91 55-147 1 22
Bromochloromethane <0.150 20.0 19.76 ug/L 99 59-132 1 21
Bromodichloromethane <0.170 20.0 19.03 ug/L 95 70-140 1 196
TestAmerica Nashville
Page 14 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-139026-C-2 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469123
Bromoform <0.290 20.0 21.13 ug/L 106 53-150 2 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Bromomethane <0.350 20.0 14.76 ug/L 74 30-150 33 44
2-Butanone (MEK)2.96 J 100 102.0 ug/L 99 50-143 2 28
Carbon disulfide <0.220 20.0 18.98 ug/L 95 35-150 2 34
Carbon tetrachloride <0.180 20.0 21.01 ug/L 105 56-150 2 18
Chlorobenzene <0.180 20.0 19.06 ug/L 95 70-130 0 15
Chloroethane <0.360 20.0 19.81 ug/L 99 58-141 3 31
Chloroform 1.40 20.0 19.93 ug/L 93 66-138 1 21
Chloromethane <0.360 20.0 17.79 ug/L 89 10-150 2 43
cis-1,2-Dichloroethene 30.8 20.0 50.55 ug/L 99 68-131 0 21
cis-1,3-Dichloropropene <0.170 20.0 17.90 ug/L 89 70-133 1 19
Dibromochloromethane <0.250 20.0 18.77 ug/L 94 66-140 1 19
1,2-Dibromo-3-Chloropropane <0.940 20.0 17.04 ug/L 85 38-138 8 26
1,2-Dibromoethane (EDB)<0.210 20.0 18.93 ug/L 95 65-137 1 21
Dibromomethane <0.450 20.0 18.11 ug/L 91 70-130 1 19
1,2-Dichlorobenzene <0.190 20.0 18.58 ug/L 93 70-130 0 15
1,4-Dichlorobenzene <0.170 20.0 17.63 ug/L 88 70-130 2 14
1,1-Dichloroethane <0.240 20.0 18.87 ug/L 94 61-139 3 23
1,2-Dichloroethane <0.200 20.0 19.55 ug/L 98 64-136 4 22
1,1-Dichloroethene <0.250 20.0 20.12 ug/L 101 54-150 5 24
1,2-Dichloropropane <0.250 20.0 18.28 ug/L 91 67-130 2 19
Ethylbenzene 3.36 20.0 22.45 ug/L 95 65-139 1 18
2-Hexanone <1.28 100 85.42 ug/L 85 44-150 0 21
Iodomethane <1.50 20.0 13.79 ug/L 69 34-150 16 37
Methylene Chloride <1.00 20.0 22.82 ug/L 114 64-130 2 22
4-Methyl-2-pentanone (MIBK)<0.810 100 94.26 ug/L 94 50-140 3 24
Styrene <0.280 *20.0 17.74 ug/L 89 70-130 3 16
1,1,1,2-Tetrachloroethane <0.150 20.0 19.51 ug/L 98 70-131 2 16
1,1,2,2-Tetrachloroethane <0.190 20.0 16.29 ug/L 81 56-145 1 19
Tetrachloroethene 4.13 20.0 25.49 ug/L 107 57-138 0 17
Toluene 0.306 J 20.0 18.11 ug/L 89 64-136 1 18
trans-1,4-Dichloro-2-butene <0.460 20.0 15.59 ug/L 78 39-150 0 28
trans-1,2-Dichloroethene <0.230 20.0 19.91 ug/L 100 59-143 2 25
trans-1,3-Dichloropropene <0.170 20.0 17.55 ug/L 88 63-142 3 18
1,1,1-Trichloroethane <0.190 20.0 19.82 ug/L 99 68-144 3 17
1,1,2-Trichloroethane <0.190 20.0 17.73 ug/L 89 70-130 4 18
Trichloroethene 2.75 20.0 23.21 ug/L 102 63-135 1 17
Trichlorofluoromethane <0.210 20.0 20.69 ug/L 103 44-150 1 32
1,2,3-Trichloropropane <0.230 20.0 14.80 ug/L 74 65-131 3 19
Vinyl acetate <1.71 40.0 43.26 ug/L 108 43-146 5 20
Vinyl chloride <0.180 20.0 20.43 ug/L 102 57-150 1 37
Xylenes, Total <0.580 40.0 36.24 ug/L 91 69-132 0 17
4-Bromofluorobenzene (Surr)70 -130
Surrogate
84
MSD MSD
Qualifier Limits%Recovery
109Dibromofluoromethane (Surr)70 -130
1011,2-Dichloroethane-d4 (Surr)70 -130
98Toluene-d8 (Surr)70 -130
TestAmerica Nashville
Page 15 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Client Sample ID: Method BlankLab Sample ID: MB 490-469238/6
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469238
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/20/17 03:12 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
<0.500 0.50010.0 ug/L 10/20/17 03:12 1Acrylonitrile
<0.200 0.2001.00 ug/L 10/20/17 03:12 1Benzene
<0.150 0.1501.00 ug/L 10/20/17 03:12 1Bromochloromethane
<0.170 0.1701.00 ug/L 10/20/17 03:12 1Bromodichloromethane
<0.290 0.2901.00 ug/L 10/20/17 03:12 1Bromoform
<0.350 0.3501.00 ug/L 10/20/17 03:12 1Bromomethane
<2.64 2.6450.0 ug/L 10/20/17 03:12 12-Butanone (MEK)
<0.220 0.2201.00 ug/L 10/20/17 03:12 1Carbon disulfide
<0.180 0.1801.00 ug/L 10/20/17 03:12 1Carbon tetrachloride
<0.180 0.1801.00 ug/L 10/20/17 03:12 1Chlorobenzene
<0.360 0.3601.00 ug/L 10/20/17 03:12 1Chloroethane
<0.230 0.2301.00 ug/L 10/20/17 03:12 1Chloroform
<0.360 0.3601.00 ug/L 10/20/17 03:12 1Chloromethane
<0.210 0.2101.00 ug/L 10/20/17 03:12 1cis-1,2-Dichloroethene
<0.170 0.1701.00 ug/L 10/20/17 03:12 1cis-1,3-Dichloropropene
<0.250 0.2501.00 ug/L 10/20/17 03:12 1Dibromochloromethane
<0.940 0.94010.0 ug/L 10/20/17 03:12 11,2-Dibromo-3-Chloropropane
<0.210 0.2101.00 ug/L 10/20/17 03:12 11,2-Dibromoethane (EDB)
<0.450 0.4501.00 ug/L 10/20/17 03:12 1Dibromomethane
<0.190 0.1901.00 ug/L 10/20/17 03:12 11,2-Dichlorobenzene
<0.170 0.1701.00 ug/L 10/20/17 03:12 11,4-Dichlorobenzene
<0.240 0.2401.00 ug/L 10/20/17 03:12 11,1-Dichloroethane
<0.200 0.2001.00 ug/L 10/20/17 03:12 11,2-Dichloroethane
<0.250 0.2501.00 ug/L 10/20/17 03:12 11,1-Dichloroethene
<0.250 0.2501.00 ug/L 10/20/17 03:12 11,2-Dichloropropane
<0.190 0.1901.00 ug/L 10/20/17 03:12 1Ethylbenzene
<1.28 1.2810.0 ug/L 10/20/17 03:12 12-Hexanone
<1.50 1.5010.0 ug/L 10/20/17 03:12 1Iodomethane
1.796 J 1.005.00 ug/L 10/20/17 03:12 1Methylene Chloride
<0.810 0.81010.0 ug/L 10/20/17 03:12 14-Methyl-2-pentanone (MIBK)
<0.280 0.2801.00 ug/L 10/20/17 03:12 1Styrene
<0.150 0.1501.00 ug/L 10/20/17 03:12 11,1,1,2-Tetrachloroethane
<0.190 0.1901.00 ug/L 10/20/17 03:12 11,1,2,2-Tetrachloroethane
<0.140 0.1401.00 ug/L 10/20/17 03:12 1Tetrachloroethene
<0.170 0.1701.00 ug/L 10/20/17 03:12 1Toluene
<0.460 0.4605.00 ug/L 10/20/17 03:12 1trans-1,4-Dichloro-2-butene
<0.230 0.2301.00 ug/L 10/20/17 03:12 1trans-1,2-Dichloroethene
<0.170 0.1701.00 ug/L 10/20/17 03:12 1trans-1,3-Dichloropropene
<0.190 0.1901.00 ug/L 10/20/17 03:12 11,1,1-Trichloroethane
<0.190 0.1901.00 ug/L 10/20/17 03:12 11,1,2-Trichloroethane
<0.200 0.2001.00 ug/L 10/20/17 03:12 1Trichloroethene
<0.210 0.2101.00 ug/L 10/20/17 03:12 1Trichlorofluoromethane
<0.230 0.2301.00 ug/L 10/20/17 03:12 11,2,3-Trichloropropane
<1.71 1.7110.0 ug/L 10/20/17 03:12 1Vinyl acetate
<0.180 0.1801.00 ug/L 10/20/17 03:12 1Vinyl chloride
<0.580 0.5803.00 ug/L 10/20/17 03:12 1Xylenes, Total
4-Bromofluorobenzene (Surr)84 70-130 10/20/17 03:12 1
MB MB
Surrogate Dil FacPrepared AnalyzedQualifier Limits%Recovery
TestAmerica Nashville
Page 16 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 490-469238/6
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469238
Dibromofluoromethane (Surr)109 70-130 10/20/17 03:12 1
MB MB
Surrogate Dil FacPrepared AnalyzedQualifier Limits%Recovery
100 10/20/17 03:12 11,2-Dichloroethane-d4 (Surr)70-130
100 10/20/17 03:12 1Toluene-d8 (Surr)70-130
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469238/3
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469238
Acetone 100 108.6 ug/L 109 39-150
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Acrylonitrile 200 186.4 ug/L 93 63-135
Benzene 20.0 17.84 ug/L 89 70-130
Bromochloromethane 20.0 20.72 ug/L 104 70-130
Bromodichloromethane 20.0 18.79 ug/L 94 70-130
Bromoform 20.0 21.37 ug/L 107 70-137
Bromomethane 20.0 16.78 ug/L 84 53-150
2-Butanone (MEK)100 102.6 ug/L 103 55-143
Carbon disulfide 20.0 17.98 ug/L 90 64-135
Carbon tetrachloride 20.0 19.64 ug/L 98 70-147
Chlorobenzene 20.0 19.04 ug/L 95 70-130
Chloroethane 20.0 19.76 ug/L 99 60-138
Chloroform 20.0 18.47 ug/L 92 70-130
Chloromethane 20.0 18.03 ug/L 90 33-150
cis-1,2-Dichloroethene 20.0 18.67 ug/L 93 70-130
cis-1,3-Dichloropropene 20.0 18.57 ug/L 93 70-133
Dibromochloromethane 20.0 19.91 ug/L 100 70-133
1,2-Dibromo-3-Chloropropane 20.0 16.25 ug/L 81 45-138
1,2-Dibromoethane (EDB)20.0 19.33 ug/L 97 70-130
Dibromomethane 20.0 18.46 ug/L 92 70-130
1,2-Dichlorobenzene 20.0 19.28 ug/L 96 70-130
1,4-Dichlorobenzene 20.0 18.08 ug/L 90 70-130
1,1-Dichloroethane 20.0 18.14 ug/L 91 70-130
1,2-Dichloroethane 20.0 18.00 ug/L 90 70-130
1,1-Dichloroethene 20.0 18.10 ug/L 90 70-132
1,2-Dichloropropane 20.0 18.20 ug/L 91 70-130
Ethylbenzene 20.0 17.96 ug/L 90 70-130
2-Hexanone 100 92.00 ug/L 92 54-142
Iodomethane 20.0 14.46 ug/L 72 40-150
Methylene Chloride 20.0 20.27 ug/L 101 70-130
4-Methyl-2-pentanone (MIBK)100 97.72 ug/L 98 60-137
Styrene 20.0 17.69 ug/L 88 70-130
1,1,1,2-Tetrachloroethane 20.0 19.74 ug/L 99 70-130
1,1,2,2-Tetrachloroethane 20.0 17.12 ug/L 86 69-131
Tetrachloroethene 20.0 20.37 ug/L 102 70-130
Toluene 20.0 17.77 ug/L 89 70-130
trans-1,4-Dichloro-2-butene 20.0 15.90 ug/L 80 41-150
trans-1,2-Dichloroethene 20.0 18.46 ug/L 92 70-130
trans-1,3-Dichloropropene 20.0 18.43 ug/L 92 63-142
TestAmerica Nashville
Page 17 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469238/3
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469238
1,1,1-Trichloroethane 20.0 18.34 ug/L 92 70-135
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
1,1,2-Trichloroethane 20.0 18.33 ug/L 92 70-130
Trichloroethene 20.0 19.48 ug/L 97 70-130
Trichlorofluoromethane 20.0 20.62 ug/L 103 59-150
1,2,3-Trichloropropane 20.0 16.60 ug/L 83 70-131
Vinyl acetate 40.0 42.08 ug/L 105 54-146
Vinyl chloride 20.0 18.97 ug/L 95 57-137
Xylenes, Total 40.0 36.10 ug/L 90 70-132
4-Bromofluorobenzene (Surr)70 -130
Surrogate
85
LCS LCS
Qualifier Limits%Recovery
109Dibromofluoromethane (Surr)70 -130
991,2-Dichloroethane-d4 (Surr)70 -130
100Toluene-d8 (Surr)70 -130
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-469238/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469238
Acetone 100 122.8 ug/L 123 39-150 12 23
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Acrylonitrile 200 209.1 ug/L 105 63-135 11 16
Benzene 20.0 20.13 ug/L 101 70-130 12 12
Bromochloromethane 20.0 23.27 ug/L 116 70-130 12 16
Bromodichloromethane 20.0 20.86 ug/L 104 70-130 10 14
Bromoform 20.0 24.41 ug/L 122 70-137 13 14
Bromomethane 20.0 16.61 ug/L 83 53-150 1 19
2-Butanone (MEK)100 116.8 ug/L 117 55-143 13 19
Carbon disulfide 20.0 20.28 ug/L 101 64-135 12 16
Carbon tetrachloride 20.0 21.94 ug/L 110 70-147 11 16
Chlorobenzene 20.0 21.18 ug/L 106 70-130 11 12
Chloroethane 20.0 18.75 ug/L 94 60-138 5 15
Chloroform 20.0 20.65 ug/L 103 70-130 11 14
Chloromethane 20.0 16.64 ug/L 83 33-150 8 20
cis-1,2-Dichloroethene 20.0 21.02 ug/L 105 70-130 12 15
cis-1,3-Dichloropropene 20.0 20.27 ug/L 101 70-133 9 15
Dibromochloromethane 20.0 21.92 ug/L 110 70-133 10 13
1,2-Dibromo-3-Chloropropane 20.0 18.62 ug/L 93 45-138 14 19
1,2-Dibromoethane (EDB)20.0 21.93 ug/L 110 70-130 13 13
Dibromomethane 20.0 21.12 ug/L 106 70-130 13 14
1,2-Dichlorobenzene 20.0 21.11 ug/L 106 70-130 9 12
1,4-Dichlorobenzene 20.0 20.30 ug/L 102 70-130 12 12
1,1-Dichloroethane 20.0 20.52 ug/L 103 70-130 12 17
1,2-Dichloroethane 20.0 19.64 ug/L 98 70-130 9 13
1,1-Dichloroethene 20.0 20.53 ug/L 103 70-132 13 20
1,2-Dichloropropane 20.0 20.26 ug/L 101 70-130 11 15
Ethylbenzene 20.0 19.99 ug/L 100 70-130 11 12
2-Hexanone 100 103.8 ug/L 104 54-142 12 17
TestAmerica Nashville
Page 18 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-469238/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469238
Iodomethane 20.0 16.31 ug/L 82 40-150 12 20
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Methylene Chloride 20.0 22.67 ug/L 113 70-130 11 15
4-Methyl-2-pentanone (MIBK)100 110.6 ug/L 111 60-137 12 21
Styrene 20.0 20.01 ug/L 100 70-130 12 12
1,1,1,2-Tetrachloroethane 20.0 22.17 ug/L 111 70-130 12 13
1,1,2,2-Tetrachloroethane 20.0 18.74 ug/L 94 69-131 9 15
Tetrachloroethene 20.0 22.81 ug/L 114 70-130 11 17
Toluene 20.0 19.53 ug/L 98 70-130 9 13
trans-1,4-Dichloro-2-butene 20.0 17.45 ug/L 87 41-150 9 20
trans-1,2-Dichloroethene 20.0 20.11 ug/L 101 70-130 9 15
trans-1,3-Dichloropropene 20.0 20.32 ug/L 102 63-142 10 13
1,1,1-Trichloroethane 20.0 20.49 ug/L 102 70-135 11 15
1,1,2-Trichloroethane 20.0 19.68 ug/L 98 70-130 7 13
Trichloroethene 20.0 22.24 ug/L 111 70-130 13 14
Trichlorofluoromethane 20.0 18.94 ug/L 95 59-150 9 22
1,2,3-Trichloropropane 20.0 18.19 ug/L 91 70-131 9 14
Vinyl acetate 40.0 43.59 ug/L 109 54-146 4 20
Vinyl chloride 20.0 17.55 ug/L 88 57-137 8 15
Xylenes, Total 40.0 40.12 ug/L 100 70-132 11 11
4-Bromofluorobenzene (Surr)70 -130
Surrogate
85
LCSD LCSD
Qualifier Limits%Recovery
109Dibromofluoromethane (Surr)70 -130
1001,2-Dichloroethane-d4 (Surr)70 -130
99Toluene-d8 (Surr)70 -130
Client Sample ID: Matrix SpikeLab Sample ID: 490-139043-B-1 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469238
Acetone <2.66 100 87.19 ug/L 87 39-150
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Acrylonitrile <0.500 200 163.9 ug/L 82 50-135
Benzene <0.200 20.0 17.84 ug/L 89 55-147
Bromochloromethane <0.150 20.0 19.10 ug/L 96 59-132
Bromodichloromethane <0.170 20.0 17.62 ug/L 88 70-140
Bromoform <0.290 20.0 19.35 ug/L 97 53-150
Bromomethane <0.350 20.0 14.43 ug/L 72 30-150
2-Butanone (MEK)<2.64 100 89.77 ug/L 90 50-143
Carbon disulfide <0.220 20.0 18.64 ug/L 93 35-150
Carbon tetrachloride <0.180 20.0 20.24 ug/L 101 56-150
Chlorobenzene <0.180 20.0 18.96 ug/L 95 70-130
Chloroethane <0.360 20.0 18.75 ug/L 94 58-141
Chloroform <0.230 20.0 18.10 ug/L 90 66-138
Chloromethane <0.360 20.0 17.98 ug/L 90 10-150
cis-1,2-Dichloroethene <0.210 20.0 18.23 ug/L 91 68-131
cis-1,3-Dichloropropene <0.170 20.0 17.89 ug/L 89 70-133
Dibromochloromethane <0.250 20.0 17.40 ug/L 87 66-140
TestAmerica Nashville
Page 19 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Matrix SpikeLab Sample ID: 490-139043-B-1 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469238
1,2-Dibromo-3-Chloropropane <0.940 20.0 13.22 ug/L 66 38-138
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
1,2-Dibromoethane (EDB)<0.210 20.0 17.93 ug/L 90 65-137
Dibromomethane <0.450 20.0 17.49 ug/L 87 70-130
1,2-Dichlorobenzene <0.190 20.0 18.15 ug/L 91 70-130
1,4-Dichlorobenzene <0.170 20.0 17.63 ug/L 88 70-130
1,1-Dichloroethane <0.240 20.0 18.11 ug/L 91 61-139
1,2-Dichloroethane <0.200 20.0 17.00 ug/L 85 64-136
1,1-Dichloroethene <0.250 20.0 18.33 ug/L 92 54-150
1,2-Dichloropropane <0.250 20.0 17.90 ug/L 90 67-130
Ethylbenzene <0.190 20.0 18.21 ug/L 91 65-139
2-Hexanone <1.28 100 73.84 ug/L 74 44-150
Iodomethane <1.50 20.0 15.93 ug/L 80 34-150
Methylene Chloride 1.67 J B 20.0 19.43 ug/L 89 64-130
4-Methyl-2-pentanone (MIBK)<0.810 100 86.13 ug/L 86 50-140
Styrene <0.280 20.0 17.36 ug/L 87 70-130
1,1,1,2-Tetrachloroethane <0.150 20.0 18.83 ug/L 94 70-131
1,1,2,2-Tetrachloroethane <0.190 20.0 15.00 ug/L 75 56-145
Tetrachloroethene <0.140 20.0 21.45 ug/L 107 57-138
Toluene <0.170 20.0 17.85 ug/L 89 64-136
trans-1,4-Dichloro-2-butene <0.460 20.0 15.02 ug/L 75 39-150
trans-1,2-Dichloroethene <0.230 20.0 18.67 ug/L 93 59-143
trans-1,3-Dichloropropene <0.170 20.0 17.69 ug/L 88 63-142
1,1,1-Trichloroethane <0.190 20.0 18.74 ug/L 94 68-144
1,1,2-Trichloroethane <0.190 20.0 17.00 ug/L 85 70-130
Trichloroethene <0.200 20.0 20.07 ug/L 100 63-135
Trichlorofluoromethane <0.210 20.0 20.40 ug/L 102 44-150
1,2,3-Trichloropropane <0.230 20.0 14.29 ug/L 71 65-131
Vinyl acetate <1.71 40.0 40.12 ug/L 100 43-146
Vinyl chloride <0.180 20.0 19.23 ug/L 96 57-150
Xylenes, Total <0.580 40.0 35.89 ug/L 90 69-132
4-Bromofluorobenzene (Surr)70 -130
Surrogate
85
MS MS
Qualifier Limits%Recovery
107Dibromofluoromethane (Surr)70 -130
1021,2-Dichloroethane-d4 (Surr)70 -130
101Toluene-d8 (Surr)70 -130
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-139043-C-1 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469238
Acetone <2.66 100 86.70 ug/L 87 39-150 1 28
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Acrylonitrile <0.500 200 165.3 ug/L 83 50-135 1 23
Benzene <0.200 20.0 18.13 ug/L 91 55-147 2 22
Bromochloromethane <0.150 20.0 19.74 ug/L 99 59-132 3 21
Bromodichloromethane <0.170 20.0 17.98 ug/L 90 70-140 2 196
Bromoform <0.290 20.0 19.11 ug/L 96 53-150 1 20
TestAmerica Nashville
Page 20 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-139043-C-1 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469238
Bromomethane <0.350 20.0 16.59 ug/L 83 30-150 14 44
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
2-Butanone (MEK)<2.64 100 83.89 ug/L 84 50-143 7 28
Carbon disulfide <0.220 20.0 19.08 ug/L 95 35-150 2 34
Carbon tetrachloride <0.180 20.0 20.27 ug/L 101 56-150 0 18
Chlorobenzene <0.180 20.0 18.80 ug/L 94 70-130 1 15
Chloroethane <0.360 20.0 19.35 ug/L 97 58-141 3 31
Chloroform <0.230 20.0 18.60 ug/L 93 66-138 3 21
Chloromethane <0.360 20.0 18.12 ug/L 91 10-150 1 43
cis-1,2-Dichloroethene <0.210 20.0 18.62 ug/L 93 68-131 2 21
cis-1,3-Dichloropropene <0.170 20.0 18.15 ug/L 91 70-133 1 19
Dibromochloromethane <0.250 20.0 18.27 ug/L 91 66-140 5 19
1,2-Dibromo-3-Chloropropane <0.940 20.0 14.76 ug/L 74 38-138 11 26
1,2-Dibromoethane (EDB)<0.210 20.0 18.02 ug/L 90 65-137 1 21
Dibromomethane <0.450 20.0 16.98 ug/L 85 70-130 3 19
1,2-Dichlorobenzene <0.190 20.0 18.27 ug/L 91 70-130 1 15
1,4-Dichlorobenzene <0.170 20.0 18.00 ug/L 90 70-130 2 14
1,1-Dichloroethane <0.240 20.0 18.43 ug/L 92 61-139 2 23
1,2-Dichloroethane <0.200 20.0 17.60 ug/L 88 64-136 4 22
1,1-Dichloroethene <0.250 20.0 19.29 ug/L 96 54-150 5 24
1,2-Dichloropropane <0.250 20.0 18.05 ug/L 90 67-130 1 19
Ethylbenzene <0.190 20.0 18.13 ug/L 91 65-139 0 18
2-Hexanone <1.28 100 73.38 ug/L 73 44-150 1 21
Iodomethane <1.50 20.0 17.55 ug/L 88 34-150 10 37
Methylene Chloride 1.67 J B 20.0 19.73 ug/L 90 64-130 1 22
4-Methyl-2-pentanone (MIBK)<0.810 100 85.99 ug/L 86 50-140 0 24
Styrene <0.280 20.0 17.57 ug/L 88 70-130 1 16
1,1,1,2-Tetrachloroethane <0.150 20.0 19.01 ug/L 95 70-131 1 16
1,1,2,2-Tetrachloroethane <0.190 20.0 15.18 ug/L 76 56-145 1 19
Tetrachloroethene <0.140 20.0 21.81 ug/L 109 57-138 2 17
Toluene <0.170 20.0 17.82 ug/L 89 64-136 0 18
trans-1,4-Dichloro-2-butene <0.460 20.0 14.71 ug/L 74 39-150 2 28
trans-1,2-Dichloroethene <0.230 20.0 19.08 ug/L 95 59-143 2 25
trans-1,3-Dichloropropene <0.170 20.0 17.42 ug/L 87 63-142 2 18
1,1,1-Trichloroethane <0.190 20.0 19.22 ug/L 96 68-144 3 17
1,1,2-Trichloroethane <0.190 20.0 17.04 ug/L 85 70-130 0 18
Trichloroethene <0.200 20.0 19.53 ug/L 98 63-135 3 17
Trichlorofluoromethane <0.210 20.0 20.57 ug/L 103 44-150 1 32
1,2,3-Trichloropropane <0.230 20.0 13.92 ug/L 70 65-131 3 19
Vinyl acetate <1.71 40.0 38.72 ug/L 97 43-146 4 20
Vinyl chloride <0.180 20.0 19.67 ug/L 98 57-150 2 37
Xylenes, Total <0.580 40.0 36.20 ug/L 91 69-132 1 17
4-Bromofluorobenzene (Surr)70 -130
Surrogate
86
MSD MSD
Qualifier Limits%Recovery
109Dibromofluoromethane (Surr)70 -130
981,2-Dichloroethane-d4 (Surr)70 -130
99Toluene-d8 (Surr)70 -130
TestAmerica Nashville
Page 21 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Method: 300.0 - Anions, Ion Chromatography
Client Sample ID: Method BlankLab Sample ID: MB 490-470814/3
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470814
RL MDL
Chloride <0.700 1.00 0.700 mg/L 10/26/17 04:59 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
<0.600 0.6001.00 mg/L 10/26/17 04:59 1Sulfate
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-470814/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470814
Chloride 10.0 9.605 mg/L 96 90-110
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Sulfate 10.0 9.671 mg/L 97 90-110
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-470814/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470814
Chloride 10.0 9.196 mg/L 92 90-110 4 20
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Sulfate 10.0 9.459 mg/L 94 90-110 2 20
Method: 6010D - Metals (ICP)
Client Sample ID: Method BlankLab Sample ID: MB 490-469156/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 471125 Prep Batch: 469156
RL MDL
Arsenic <0.00860 ^0.0100 0.00860 mg/L 10/19/17 13:43 10/25/17 16:00 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
<0.00500 0.005000.0100 mg/L 10/19/17 13:43 10/25/17 16:00 1Copper
<0.00200 0.002000.00500 mg/L 10/19/17 13:43 10/25/17 16:00 1Lead
0.005600 J 0.005000.0100 mg/L 10/19/17 13:43 10/25/17 16:00 1Selenium
Client Sample ID: Method BlankLab Sample ID: MB 490-469156/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 471733 Prep Batch: 469156
RL MDL
Barium <0.00500 0.0100 0.00500 mg/L 10/19/17 13:43 10/29/17 02:21 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
<0.000500 0.0005000.00100 mg/L 10/19/17 13:43 10/29/17 02:21 1Cadmium
<0.00300 0.003000.00500 mg/L 10/19/17 13:43 10/29/17 02:21 1Chromium
<0.00300 0.003000.0100 mg/L 10/19/17 13:43 10/29/17 02:21 1Nickel
<0.00300 0.003000.00500 mg/L 10/19/17 13:43 10/29/17 02:21 1Silver
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469156/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 471125 Prep Batch: 469156
Arsenic 0.100 0.1025 ^ mg/L 103 80-120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Copper 0.100 0.09190 mg/L 92 80-120
TestAmerica Nashville
Page 22 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Method: 6010D - Metals (ICP) (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469156/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 471125 Prep Batch: 469156
Lead 0.100 0.1059 mg/L 106 80-120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Selenium 0.100 0.1001 mg/L 100 80-120
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469156/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 471733 Prep Batch: 469156
Barium 0.100 0.1018 mg/L 102 80-120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Cadmium 0.100 0.09890 mg/L 99 80-120
Chromium 0.100 0.1017 mg/L 102 80-120
Nickel 0.100 0.1010 mg/L 101 80-120
Silver 0.100 0.1012 mg/L 101 80-120
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-469156/18-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 471125 Prep Batch: 469156
Arsenic 0.100 0.09800 ^ mg/L 98 80-120 4 20
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Copper 0.100 0.09820 mg/L 98 80-120 7 20
Lead 0.100 0.1041 mg/L 104 80-120 2 20
Selenium 0.100 0.1046 mg/L 105 80-120 4 20
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-469156/18-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 471733 Prep Batch: 469156
Barium 0.100 0.1006 mg/L 101 80-120 1 20
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Cadmium 0.100 0.09820 mg/L 98 80-120 1 20
Chromium 0.100 0.1001 mg/L 100 80-120 2 20
Nickel 0.100 0.09930 mg/L 99 80-120 2 20
Silver 0.100 0.09990 mg/L 100 80-120 1 20
Client Sample ID: Matrix SpikeLab Sample ID: 490-138933-G-3-B MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 471125 Prep Batch: 469156
Arsenic 0.0153 ^0.100 0.1052 ^ mg/L 90 75-125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Copper 0.0281 0.100 0.1190 mg/L 91 75-125
Lead 0.00280 J 0.100 0.1035 mg/L 101 75-125
Selenium 0.00720 J B 0.100 0.1036 mg/L 96 75-125
TestAmerica Nashville
Page 23 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Method: 6010D - Metals (ICP) (Continued)
Client Sample ID: Matrix SpikeLab Sample ID: 490-138933-G-3-B MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 471733 Prep Batch: 469156
Barium <1.00 0.100 <1.00 mg/L NC 75-125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Cadmium <0.100 F1 0.100 0.1000 J mg/L 100 75-125
Chromium <0.600 0.100 <0.600 mg/L NC 75-125
Nickel <0.600 0.100 <0.600 mg/L NC 75-125
Silver <0.600 0.100 <0.600 mg/L NC 75-125
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-138933-G-3-C MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 471125 Prep Batch: 469156
Arsenic 0.0153 ^0.100 0.1038 ^ mg/L 89 75-125 1 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Copper 0.0281 0.100 0.1302 mg/L 102 75-125 9 20
Lead 0.00280 J 0.100 0.1031 mg/L 100 75-125 0 20
Selenium 0.00720 J B 0.100 0.1073 mg/L 100 75-125 4 20
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-138933-G-3-C MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 471733 Prep Batch: 469156
Barium <1.00 0.100 <1.00 mg/L NC 75-125 NC 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Cadmium <0.100 F1 0.100 0.1000 J F1 mg/L 0 75-125 NC 20
Chromium <0.600 0.100 <0.600 mg/L NC 75-125 NC 20
Nickel <0.600 0.100 <0.600 mg/L NC 75-125 NC 20
Silver <0.600 0.100 <0.600 mg/L NC 75-125 NC 20
Method: 6020B - Metals (ICP/MS)
Client Sample ID: Method BlankLab Sample ID: MB 490-469152/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469548 Prep Batch: 469152
RL MDL
Antimony <0.800 2.00 0.800 ug/L 10/19/17 13:31 10/20/17 13:56 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
<0.100 0.1002.00 ug/L 10/19/17 13:31 10/20/17 13:56 1Beryllium
<0.100 0.1002.00 ug/L 10/19/17 13:31 10/20/17 13:56 1Cobalt
<0.800 0.8002.00 ug/L 10/19/17 13:31 10/20/17 13:56 1Thallium
<0.700 0.7002.00 ug/L 10/19/17 13:31 10/20/17 13:56 1Vanadium
<5.20 5.2025.0 ug/L 10/19/17 13:31 10/20/17 13:56 1Zinc
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469152/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469548 Prep Batch: 469152
Antimony 100 101.0 ug/L 101 80-120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Beryllium 100 95.22 ug/L 95 80-120
Cobalt 100 99.82 ug/L 100 80-120
TestAmerica Nashville
Page 24 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Method: 6020B - Metals (ICP/MS) (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469152/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469548 Prep Batch: 469152
Thallium 100 98.41 ug/L 98 80-120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Vanadium 100 101.0 ug/L 101 80-120
Zinc 100 102.1 ug/L 102 80-120
Client Sample ID: Matrix SpikeLab Sample ID: 490-138985-D-1-B MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469548 Prep Batch: 469152
Antimony <0.800 100 101.4 ug/L 101 75-125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Beryllium <0.100 100 94.46 ug/L 94 75-125
Cobalt 1.49 J 100 102.2 ug/L 101 75-125
Thallium <0.800 100 100.8 ug/L 101 75-125
Vanadium <0.700 100 101.4 ug/L 101 75-125
Zinc <5.20 100 102.9 ug/L 103 75-125
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-138985-D-1-C MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469548 Prep Batch: 469152
Antimony <0.800 100 98.52 ug/L 99 75-125 3 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Beryllium <0.100 100 94.31 ug/L 94 75-125 0 20
Cobalt 1.49 J 100 100.6 ug/L 99 75-125 2 20
Thallium <0.800 100 99.58 ug/L 100 75-125 1 20
Vanadium <0.700 100 100.4 ug/L 100 75-125 1 20
Zinc <5.20 100 102.7 ug/L 103 75-125 0 20
Method: 7470A - Mercury (CVAA)
Client Sample ID: Method BlankLab Sample ID: MB 490-470121/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470713 Prep Batch: 470121
RL MDL
Mercury <0.100 0.200 0.100 ug/L 10/23/17 22:14 10/24/17 16:01 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-470121/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470713 Prep Batch: 470121
Mercury 1.00 1.146 ug/L 115 80-120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
TestAmerica Nashville
Page 25 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Method: 7470A - Mercury (CVAA) (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-470121/3-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470713 Prep Batch: 470121
Mercury 1.00 1.090 ug/L 109 80-120 5 20
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Client Sample ID: Matrix SpikeLab Sample ID: 490-139187-G-1-B MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470713 Prep Batch: 470121
Mercury <0.100 1.00 0.8628 ug/L 86 75-125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-139187-G-1-C MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470713 Prep Batch: 470121
Mercury <0.100 1.00 0.8608 ug/L 86 75-125 0 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Method: 365.4 - Phosphorus, Total
Client Sample ID: Method BlankLab Sample ID: MB 490-469022/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469686 Prep Batch: 469022
RL MDL
Phosphorus, Total <0.0500 0.100 0.0500 mg/L 10/19/17 09:36 10/21/17 05:15 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469022/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469686 Prep Batch: 469022
Phosphorus, Total 2.00 1.830 mg/L 92 90-110
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-469022/3-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469686 Prep Batch: 469022
Phosphorus, Total 2.00 1.970 mg/L 99 90-110 7 20
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Client Sample ID: Matrix SpikeLab Sample ID: 580-72134-B-2-E MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469686 Prep Batch: 469022
Phosphorus, Total 0.514 2.00 2.310 mg/L 90 73-119
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
TestAmerica Nashville
Page 26 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Method: 365.4 - Phosphorus, Total (Continued)
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 580-72134-B-2-F MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469686 Prep Batch: 469022
Phosphorus, Total 0.514 2.00 2.250 mg/L 87 73-119 3 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Method: SM5210B - BOD, 5 Day
Client Sample ID: Method BlankLab Sample ID: USB 490-470447/1
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470447
RL RL
Biochemical Oxygen Demand <2.00 2.00 2.00 mg/L 10/18/17 18:25 1
USB USB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-470447/2
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470447
Biochemical Oxygen Demand 3.96 4.295 mg/L 108 85-115
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: DuplicateLab Sample ID: 490-138938-A-3 DU
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470447
Biochemical Oxygen Demand <2.00 <2.00 mg/L NC 20
Analyte
DU DU
DUnitResult Qualifier
Sample
Result
Sample
Qualifier LimitRPD
RPD
TestAmerica Nashville
Page 27 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Association Summary
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
GC/MS VOA
Analysis Batch: 469123
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 8260B490-138924-2 Trip Blank Total/NA
Water 8260BMB 490-469123/7 Method Blank Total/NA
Water 8260BLCS 490-469123/4 Lab Control Sample Total/NA
Water 8260BLCSD 490-469123/5 Lab Control Sample Dup Total/NA
Water 8260B490-139026-B-2 MS Matrix Spike Total/NA
Water 8260B490-139026-C-2 MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 469238
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 8260B490-138924-1 LT-01 Total/NA
Water 8260BMB 490-469238/6 Method Blank Total/NA
Water 8260BLCS 490-469238/3 Lab Control Sample Total/NA
Water 8260BLCSD 490-469238/4 Lab Control Sample Dup Total/NA
Water 8260B490-139043-B-1 MS Matrix Spike Total/NA
Water 8260B490-139043-C-1 MSD Matrix Spike Duplicate Total/NA
HPLC/IC
Analysis Batch: 470814
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 300.0490-138924-1 LT-01 Total/NA
Water 300.0MB 490-470814/3 Method Blank Total/NA
Water 300.0LCS 490-470814/4 Lab Control Sample Total/NA
Water 300.0LCSD 490-470814/5 Lab Control Sample Dup Total/NA
Metals
Prep Batch: 469152
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3010A490-138924-1 LT-01 Total/NA
Water 3010AMB 490-469152/1-A Method Blank Total/NA
Water 3010ALCS 490-469152/2-A Lab Control Sample Total/NA
Water 3010A490-138985-D-1-B MS Matrix Spike Total/NA
Water 3010A490-138985-D-1-C MSD Matrix Spike Duplicate Total/NA
Prep Batch: 469156
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3010A490-138924-1 LT-01 Total/NA
Water 3010AMB 490-469156/1-A Method Blank Total/NA
Water 3010ALCS 490-469156/2-A Lab Control Sample Total/NA
Water 3010ALCSD 490-469156/18-A Lab Control Sample Dup Total/NA
Water 3010A490-138933-G-3-B MS Matrix Spike Total/NA
Water 3010A490-138933-G-3-C MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 469548
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020B 469152490-138924-1 LT-01 Total/NA
Water 6020B 469152MB 490-469152/1-A Method Blank Total/NA
Water 6020B 469152LCS 490-469152/2-A Lab Control Sample Total/NA
Water 6020B 469152490-138985-D-1-B MS Matrix Spike Total/NA
TestAmerica Nashville
Page 28 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Association Summary
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Metals (Continued)
Analysis Batch: 469548 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020B 469152490-138985-D-1-C MSD Matrix Spike Duplicate Total/NA
Prep Batch: 470121
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A490-138924-1 LT-01 Total/NA
Water 7470AMB 490-470121/1-A Method Blank Total/NA
Water 7470ALCS 490-470121/2-A Lab Control Sample Total/NA
Water 7470ALCSD 490-470121/3-A Lab Control Sample Dup Total/NA
Water 7470A490-139187-G-1-B MS Matrix Spike Total/NA
Water 7470A490-139187-G-1-C MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 470713
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A 470121490-138924-1 LT-01 Total/NA
Water 7470A 470121MB 490-470121/1-A Method Blank Total/NA
Water 7470A 470121LCS 490-470121/2-A Lab Control Sample Total/NA
Water 7470A 470121LCSD 490-470121/3-A Lab Control Sample Dup Total/NA
Water 7470A 470121490-139187-G-1-B MS Matrix Spike Total/NA
Water 7470A 470121490-139187-G-1-C MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 471125
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6010D 469156490-138924-1 LT-01 Total/NA
Water 6010D 469156MB 490-469156/1-A Method Blank Total/NA
Water 6010D 469156LCS 490-469156/2-A Lab Control Sample Total/NA
Water 6010D 469156LCSD 490-469156/18-A Lab Control Sample Dup Total/NA
Water 6010D 469156490-138933-G-3-B MS Matrix Spike Total/NA
Water 6010D 469156490-138933-G-3-C MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 471733
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6010D 469156490-138924-1 LT-01 Total/NA
Water 6010D 469156MB 490-469156/1-A Method Blank Total/NA
Water 6010D 469156LCS 490-469156/2-A Lab Control Sample Total/NA
Water 6010D 469156LCSD 490-469156/18-A Lab Control Sample Dup Total/NA
Water 6010D 469156490-138933-G-3-B MS Matrix Spike Total/NA
Water 6010D 469156490-138933-G-3-C MSD Matrix Spike Duplicate Total/NA
General Chemistry
Prep Batch: 469022
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 365.2/365.3/365490-138924-1 LT-01 Total/NA
Water 365.2/365.3/365MB 490-469022/1-A Method Blank Total/NA
Water 365.2/365.3/365LCS 490-469022/2-A Lab Control Sample Total/NA
Water 365.2/365.3/365LCSD 490-469022/3-A Lab Control Sample Dup Total/NA
Water 365.2/365.3/365580-72134-B-2-E MS Matrix Spike Total/NA
Water 365.2/365.3/365580-72134-B-2-F MSD Matrix Spike Duplicate Total/NA
TestAmerica Nashville
Page 29 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Association Summary
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
General Chemistry (Continued)
Analysis Batch: 469194
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water SM 5220D490-138924-1 LT-01 Total/NA
Analysis Batch: 469686
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 365.4 469022490-138924-1 LT-01 Total/NA
Water 365.4 469022MB 490-469022/1-A Method Blank Total/NA
Water 365.4 469022LCS 490-469022/2-A Lab Control Sample Total/NA
Water 365.4 469022LCSD 490-469022/3-A Lab Control Sample Dup Total/NA
Water 365.4 469022580-72134-B-2-E MS Matrix Spike Total/NA
Water 365.4 469022580-72134-B-2-F MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 470447
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water SM5210B490-138924-1 LT-01 Total/NA
Water SM5210BUSB 490-470447/1 Method Blank Total/NA
Water SM5210BLCS 490-470447/2 Lab Control Sample Total/NA
Water SM5210B490-138938-A-3 DU Duplicate Total/NA
Analysis Batch: 471942
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water Nitrate by calc490-138924-1 LT-01 Total/NA
TestAmerica Nashville
Page 30 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Lab Chronicle
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-138924-1
Project/Site: Madison Co Operating Landfill Leachate
Client Sample ID: LT-01 Lab Sample ID: 490-138924-1
Matrix: WaterDate Collected: 10/17/17 13:00
Date Received: 10/18/17 09:55
Analysis 8260B AK110/20/17 04:051 TAL NSH469238
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Analysis 300.0 50 470814 10/26/17 07:05 JHS TAL NSHTotal/NA
Prep 3010A 469156 10/19/17 13:43 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 471125 10/25/17 16:40 BLG TAL NSHTotal/NA
Prep 3010A 469156 10/19/17 13:43 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 471733 10/29/17 03:26 BLG TAL NSHTotal/NA
Prep 3010A 469152 10/19/17 13:31 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 469548 10/20/17 14:38 BLG TAL NSHTotal/NA
Prep 7470A 470121 10/23/17 22:14 RDF TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 470713 10/24/17 16:44 RDF TAL NSHTotal/NA
Prep 365.2/365.3/365 469022 10/19/17 09:36 LDT TAL NSHTotal/NA 20 mL 20 mL
Analysis 365.4 1 469686 10/21/17 06:32 SDL TAL NSHTotal/NA 20 mL 20 mL
Analysis Nitrate by calc 1 471942 10/19/17 09:54 BMC TAL NSHTotal/NA 50 mL 50 mL
Analysis SM 5220D 1 469194 10/19/17 15:05 MSJ TAL NSHTotal/NA 2 mL 2 mL
Analysis SM5210B 1 470447 NKK TAL NSHTotal/NA
10/18/17 16:11
10/23/17 14:30
(Start)
(End)
Client Sample ID: Trip Blank Lab Sample ID: 490-138924-2
Matrix: WaterDate Collected: 10/17/17 00:01
Date Received: 10/18/17 09:55
Analysis 8260B P1B10/19/17 17:211 TAL NSH469123
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Laboratory References:
TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL [phone]
TestAmerica Nashville
Page 31 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Method Summary
TestAmerica Job ID: 490-138924-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill Leachate
Method Method Description LaboratoryProtocol
SW8468260BVolatile Organic Compounds (GC/MS)TAL NSH
MCAWW300.0 Anions, Ion Chromatography TAL NSH
SW8466010DMetals (ICP)TAL NSH
SW8466020BMetals (ICP/MS)TAL NSH
SW8467470AMercury (CVAA)TAL NSH
EPA365.4 Phosphorus, Total TAL NSH
SMNitrate by calc Nitrogen, Nitrate-Nitrite TAL NSH
SMSM 5220D COD TAL NSH
SMSM5210B BOD, 5 Day TAL NSH
Protocol References:
EPA = US Environmental Protection Agency
MCAWW = "Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And Subsequent Revisions.
SM = "Standard Methods For The Examination Of Water And Wastewater",
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL [phone]
TestAmerica Nashville
Page 32 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Accreditation/Certification Summary
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-138924-1
Project/Site: Madison Co Operating Landfill Leachate
Laboratory: TestAmerica Nashville
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.
Authority Program EPA Region Identification Number Expiration Date
North Carolina (WW/SW)3874State Program 12-31-17
Analysis Method Prep Method Matrix Analyte
The following analytes are included in this report, but accreditation/certification is not offered by the governing authority:
Nitrate by calc Water Nitrate as N
TestAmerica Nashville
Page 33 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Page 34 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Login Sample Receipt Checklist
Client: Anchor QEA of North Carolina PLLC Job Number: 490-138924-1
Login Number: 138924
Question Answer Comment
Creator: Huskey, Adam
List Source: TestAmerica Nashville
List Number: 1
TrueRadioactivity wasn't checked or is </= background as measured by a survey
meter.
TrueThe cooler's custody seal, if present, is intact.
N/ASample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
TrueSample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
TrueContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
TrueResidual Chlorine Checked.
TestAmerica Nashville
Page 35 of 35 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
ANALYTICAL REPORT
TestAmerica Laboratories, Inc.
TestAmerica Nashville
2960 Foster Creighton Drive
Nashville, TN 37204
Tel: [phone]
TestAmerica Job ID: 490-138985-1
Client Project/Site: Madison Co Operating Landfill
For:
Anchor QEA of North Carolina PLLC
231 W Haywood Street
Asheville, North Carolina 28801
Attn: Brian Gant
Authorized for release by:
11/6/2017 2:10:39 PM
Ken Hayes, Project Manager II
[phone]
[e-mail]
The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited
parameters, exceptions are noted in this report. This report may not be reproduced except in full,
and with written approval from the laboratory. For questions please contact the Project Manager
at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
1
2
3
4
5
6
7
8
9
10
11
12
13
Table of Contents
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
TestAmerica Job ID: 490-138985-1
Page 2 of 28 TestAmerica Nashville11/6/2017
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .12
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .21
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .23
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .24
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .25
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .26
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .28
1
2
3
4
5
6
7
8
9
10
11
12
13
Sample Summary
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID Client Sample ID ReceivedCollectedMatrix
490-138985-1 SW-01 Water 10/17/17 15:35 10/18/17 09:55
490-138985-2 SW-02R Water 10/17/17 10:15 10/18/17 09:55
490-138985-3 Trip Blank Water 10/17/17 01:01 10/18/17 09:55
TestAmerica Nashville
Page 3 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Case Narrative
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-138985-1
Project/Site: Madison Co Operating Landfill
Job ID: 490-138985-1
Laboratory: TestAmerica Nashville
Narrative
Job Narrative
490-138985-1
Comments
No additional comments.
Receipt
The samples were received on 10/18/2017 9:55 AM; the samples arrived in good condition, properly preserved and, where required, on
ice. The temperature of the cooler at receipt was 2.3º C.
GC/MS VOA
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
Metals
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
VOA Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
TestAmerica NashvillePage 4 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Definitions/Glossary
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Qualifiers
Metals
Qualifier Description
^ICV,CCV,ICB,CCB, ISA, ISB, CRI, CRA, DLCK or MRL standard: Instrument related QC is outside acceptance limits.
Qualifier
F1 MS and/or MSD Recovery is outside acceptance limits.
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TestAmerica Nashville
Page 5 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-138985-1Client Sample ID: SW-01
Matrix: WaterDate Collected: 10/17/17 15:35
Date Received: 10/18/17 09:55
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/18/17 20:36 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
10.0 0.500 ug/L 10/18/17 20:36 1Acrylonitrile<0.500
1.00 0.200 ug/L 10/18/17 20:36 1Benzene<0.200
1.00 0.150 ug/L 10/18/17 20:36 1Bromochloromethane<0.150
1.00 0.170 ug/L 10/18/17 20:36 1Bromodichloromethane<0.170
1.00 0.290 ug/L 10/18/17 20:36 1Bromoform<0.290
1.00 0.350 ug/L 10/18/17 20:36 1Bromomethane<0.350
50.0 2.64 ug/L 10/18/17 20:36 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 10/18/17 20:36 1Carbon disulfide <0.220
1.00 0.180 ug/L 10/18/17 20:36 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 10/18/17 20:36 1Chlorobenzene<0.180
1.00 0.360 ug/L 10/18/17 20:36 1Chloroethane<0.360
1.00 0.230 ug/L 10/18/17 20:36 1Chloroform<0.230
1.00 0.360 ug/L 10/18/17 20:36 1Chloromethane<0.360
1.00 0.210 ug/L 10/18/17 20:36 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 10/18/17 20:36 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 10/18/17 20:36 1Dibromochloromethane<0.250
10.0 0.940 ug/L 10/18/17 20:36 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 10/18/17 20:36 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 10/18/17 20:36 1Dibromomethane<0.450
1.00 0.190 ug/L 10/18/17 20:36 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 10/18/17 20:36 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 10/18/17 20:36 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 10/18/17 20:36 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 10/18/17 20:36 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 10/18/17 20:36 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 10/18/17 20:36 1Ethylbenzene<0.190
10.0 1.28 ug/L 10/18/17 20:36 12-Hexanone <1.28
10.0 1.50 ug/L 10/18/17 20:36 1Iodomethane<1.50
5.00 1.00 ug/L 10/18/17 20:36 1Methylene Chloride <1.00
10.0 0.810 ug/L 10/18/17 20:36 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 10/18/17 20:36 1Styrene<0.280
1.00 0.150 ug/L 10/18/17 20:36 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 10/18/17 20:36 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 10/18/17 20:36 1Tetrachloroethene<0.140
1.00 0.170 ug/L 10/18/17 20:36 1Toluene<0.170
5.00 0.460 ug/L 10/18/17 20:36 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 10/18/17 20:36 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 10/18/17 20:36 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 10/18/17 20:36 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 10/18/17 20:36 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 10/18/17 20:36 1Trichloroethene<0.200
1.00 0.210 ug/L 10/18/17 20:36 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 10/18/17 20:36 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 10/18/17 20:36 1Vinyl acetate <1.71
1.00 0.180 ug/L 10/18/17 20:36 1Vinyl chloride <0.180
3.00 0.580 ug/L 10/18/17 20:36 1Xylenes, Total <0.580
TestAmerica Nashville
Page 6 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-138985-1Client Sample ID: SW-01
Matrix: WaterDate Collected: 10/17/17 15:35
Date Received: 10/18/17 09:55
4-Bromofluorobenzene (Surr)114 70-130 10/18/17 20:36 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Dibromofluoromethane (Surr)93 10/18/17 20:36 170-130
1,2-Dichloroethane-d4 (Surr)108 10/18/17 20:36 170-130
Toluene-d8 (Surr)98 10/18/17 20:36 170-130
Method: 6010D - Metals (ICP)
RL MDL
Silver <0.00300 0.00500 0.00300 mg/L 10/19/17 13:43 10/29/17 03:36 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.0100 0.00860 mg/L 10/19/17 13:43 10/21/17 03:09 1Arsenic<0.00860 ^
0.0100 0.00500 mg/L 10/19/17 13:43 10/29/17 03:36 1Barium0.0689
0.00100 0.000500 mg/L 10/19/17 13:43 10/29/17 03:36 1Cadmium<0.000500
0.00500 0.00300 mg/L 10/19/17 13:43 10/21/17 03:09 1Chromium<0.00300 ^
0.00500 0.00200 mg/L 10/19/17 13:43 10/29/17 03:36 1Lead<0.00200
0.0100 0.00500 mg/L 10/19/17 13:43 10/21/17 03:09 1Selenium<0.00500
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 10/19/17 13:31 10/20/17 14:20 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2.00 0.100 ug/L 10/19/17 13:31 10/20/17 14:20 1Beryllium<0.100
2.00 0.100 ug/L 10/19/17 13:31 10/20/17 14:20 1Cobalt1.49 J
2.00 0.800 ug/L 10/19/17 13:31 10/20/17 14:20 1Thallium<0.800
2.00 0.700 ug/L 10/19/17 13:31 10/20/17 14:20 1Vanadium<0.700
25.0 5.20 ug/L 10/19/17 13:31 10/20/17 14:20 1Zinc<5.20
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 10/23/17 22:14 10/24/17 16:58 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
TestAmerica Nashville
Page 7 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-138985-2Client Sample ID: SW-02R
Matrix: WaterDate Collected: 10/17/17 10:15
Date Received: 10/18/17 09:55
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/18/17 21:03 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
10.0 0.500 ug/L 10/18/17 21:03 1Acrylonitrile<0.500
1.00 0.200 ug/L 10/18/17 21:03 1Benzene<0.200
1.00 0.150 ug/L 10/18/17 21:03 1Bromochloromethane<0.150
1.00 0.170 ug/L 10/18/17 21:03 1Bromodichloromethane<0.170
1.00 0.290 ug/L 10/18/17 21:03 1Bromoform<0.290
1.00 0.350 ug/L 10/18/17 21:03 1Bromomethane<0.350
50.0 2.64 ug/L 10/18/17 21:03 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 10/18/17 21:03 1Carbon disulfide <0.220
1.00 0.180 ug/L 10/18/17 21:03 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 10/18/17 21:03 1Chlorobenzene<0.180
1.00 0.360 ug/L 10/18/17 21:03 1Chloroethane<0.360
1.00 0.230 ug/L 10/18/17 21:03 1Chloroform<0.230
1.00 0.360 ug/L 10/18/17 21:03 1Chloromethane<0.360
1.00 0.210 ug/L 10/18/17 21:03 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 10/18/17 21:03 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 10/18/17 21:03 1Dibromochloromethane<0.250
10.0 0.940 ug/L 10/18/17 21:03 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 10/18/17 21:03 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 10/18/17 21:03 1Dibromomethane<0.450
1.00 0.190 ug/L 10/18/17 21:03 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 10/18/17 21:03 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 10/18/17 21:03 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 10/18/17 21:03 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 10/18/17 21:03 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 10/18/17 21:03 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 10/18/17 21:03 1Ethylbenzene<0.190
10.0 1.28 ug/L 10/18/17 21:03 12-Hexanone <1.28
10.0 1.50 ug/L 10/18/17 21:03 1Iodomethane<1.50
5.00 1.00 ug/L 10/18/17 21:03 1Methylene Chloride <1.00
10.0 0.810 ug/L 10/18/17 21:03 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 10/18/17 21:03 1Styrene<0.280
1.00 0.150 ug/L 10/18/17 21:03 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 10/18/17 21:03 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 10/18/17 21:03 1Tetrachloroethene<0.140
1.00 0.170 ug/L 10/18/17 21:03 1Toluene<0.170
5.00 0.460 ug/L 10/18/17 21:03 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 10/18/17 21:03 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 10/18/17 21:03 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 10/18/17 21:03 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 10/18/17 21:03 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 10/18/17 21:03 1Trichloroethene<0.200
1.00 0.210 ug/L 10/18/17 21:03 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 10/18/17 21:03 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 10/18/17 21:03 1Vinyl acetate <1.71
1.00 0.180 ug/L 10/18/17 21:03 1Vinyl chloride <0.180
3.00 0.580 ug/L 10/18/17 21:03 1Xylenes, Total <0.580
TestAmerica Nashville
Page 8 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-138985-2Client Sample ID: SW-02R
Matrix: WaterDate Collected: 10/17/17 10:15
Date Received: 10/18/17 09:55
4-Bromofluorobenzene (Surr)117 70-130 10/18/17 21:03 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Dibromofluoromethane (Surr)92 10/18/17 21:03 170-130
1,2-Dichloroethane-d4 (Surr)105 10/18/17 21:03 170-130
Toluene-d8 (Surr)94 10/18/17 21:03 170-130
Method: 6010D - Metals (ICP)
RL MDL
Silver <0.00300 0.00500 0.00300 mg/L 10/19/17 13:43 10/29/17 03:31 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.0100 0.00860 mg/L 10/19/17 13:43 10/21/17 03:04 1Arsenic<0.00860 ^
0.0100 0.00500 mg/L 10/19/17 13:43 10/29/17 03:31 1Barium0.0582
0.00100 0.000500 mg/L 10/19/17 13:43 10/21/17 03:04 1Cadmium<0.000500 ^
0.00500 0.00300 mg/L 10/19/17 13:43 10/29/17 03:31 1Chromium<0.00300
0.00500 0.00200 mg/L 10/19/17 13:43 10/29/17 03:31 1Lead0.00340 J
0.0100 0.00500 mg/L 10/19/17 13:43 10/21/17 03:04 1Selenium<0.00500
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 10/19/17 13:31 10/20/17 14:35 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2.00 0.100 ug/L 10/19/17 13:31 10/20/17 14:35 1Beryllium<0.100
2.00 0.100 ug/L 10/19/17 13:31 10/20/17 14:35 1Cobalt0.410 J
2.00 0.800 ug/L 10/19/17 13:31 10/20/17 14:35 1Thallium<0.800
2.00 0.700 ug/L 10/19/17 13:31 10/20/17 14:35 1Vanadium1.16 J
25.0 5.20 ug/L 10/19/17 13:31 10/20/17 14:35 1Zinc<5.20
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 10/23/17 22:14 10/24/17 17:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
TestAmerica Nashville
Page 9 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-138985-3Client Sample ID: Trip Blank
Matrix: WaterDate Collected: 10/17/17 01:01
Date Received: 10/18/17 09:55
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/18/17 19:42 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
10.0 0.500 ug/L 10/18/17 19:42 1Acrylonitrile<0.500
1.00 0.200 ug/L 10/18/17 19:42 1Benzene<0.200
1.00 0.150 ug/L 10/18/17 19:42 1Bromochloromethane<0.150
1.00 0.170 ug/L 10/18/17 19:42 1Bromodichloromethane<0.170
1.00 0.290 ug/L 10/18/17 19:42 1Bromoform<0.290
1.00 0.350 ug/L 10/18/17 19:42 1Bromomethane<0.350
50.0 2.64 ug/L 10/18/17 19:42 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 10/18/17 19:42 1Carbon disulfide <0.220
1.00 0.180 ug/L 10/18/17 19:42 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 10/18/17 19:42 1Chlorobenzene<0.180
1.00 0.360 ug/L 10/18/17 19:42 1Chloroethane<0.360
1.00 0.230 ug/L 10/18/17 19:42 1Chloroform<0.230
1.00 0.360 ug/L 10/18/17 19:42 1Chloromethane<0.360
1.00 0.210 ug/L 10/18/17 19:42 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 10/18/17 19:42 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 10/18/17 19:42 1Dibromochloromethane<0.250
10.0 0.940 ug/L 10/18/17 19:42 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 10/18/17 19:42 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 10/18/17 19:42 1Dibromomethane<0.450
1.00 0.190 ug/L 10/18/17 19:42 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 10/18/17 19:42 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 10/18/17 19:42 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 10/18/17 19:42 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 10/18/17 19:42 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 10/18/17 19:42 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 10/18/17 19:42 1Ethylbenzene<0.190
10.0 1.28 ug/L 10/18/17 19:42 12-Hexanone <1.28
10.0 1.50 ug/L 10/18/17 19:42 1Iodomethane<1.50
5.00 1.00 ug/L 10/18/17 19:42 1Methylene Chloride <1.00
10.0 0.810 ug/L 10/18/17 19:42 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 10/18/17 19:42 1Styrene<0.280
1.00 0.150 ug/L 10/18/17 19:42 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 10/18/17 19:42 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 10/18/17 19:42 1Tetrachloroethene<0.140
1.00 0.170 ug/L 10/18/17 19:42 1Toluene<0.170
5.00 0.460 ug/L 10/18/17 19:42 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 10/18/17 19:42 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 10/18/17 19:42 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 10/18/17 19:42 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 10/18/17 19:42 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 10/18/17 19:42 1Trichloroethene<0.200
1.00 0.210 ug/L 10/18/17 19:42 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 10/18/17 19:42 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 10/18/17 19:42 1Vinyl acetate <1.71
1.00 0.180 ug/L 10/18/17 19:42 1Vinyl chloride <0.180
3.00 0.580 ug/L 10/18/17 19:42 1Xylenes, Total <0.580
TestAmerica Nashville
Page 10 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-138985-3Client Sample ID: Trip Blank
Matrix: WaterDate Collected: 10/17/17 01:01
Date Received: 10/18/17 09:55
4-Bromofluorobenzene (Surr)116 70-130 10/18/17 19:42 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Dibromofluoromethane (Surr)89 10/18/17 19:42 170-130
1,2-Dichloroethane-d4 (Surr)106 10/18/17 19:42 170-130
Toluene-d8 (Surr)100 10/18/17 19:42 170-130
TestAmerica Nashville
Page 11 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS)
Client Sample ID: Method BlankLab Sample ID: MB 490-468800/7
Matrix: Water Prep Type: Total/NA
Analysis Batch: 468800
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/18/17 16:02 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
<0.500 0.50010.0 ug/L 10/18/17 16:02 1Acrylonitrile
<0.200 0.2001.00 ug/L 10/18/17 16:02 1Benzene
<0.150 0.1501.00 ug/L 10/18/17 16:02 1Bromochloromethane
<0.170 0.1701.00 ug/L 10/18/17 16:02 1Bromodichloromethane
<0.290 0.2901.00 ug/L 10/18/17 16:02 1Bromoform
<0.350 0.3501.00 ug/L 10/18/17 16:02 1Bromomethane
<2.64 2.6450.0 ug/L 10/18/17 16:02 12-Butanone (MEK)
<0.220 0.2201.00 ug/L 10/18/17 16:02 1Carbon disulfide
<0.180 0.1801.00 ug/L 10/18/17 16:02 1Carbon tetrachloride
<0.180 0.1801.00 ug/L 10/18/17 16:02 1Chlorobenzene
<0.360 0.3601.00 ug/L 10/18/17 16:02 1Chloroethane
<0.230 0.2301.00 ug/L 10/18/17 16:02 1Chloroform
<0.360 0.3601.00 ug/L 10/18/17 16:02 1Chloromethane
<0.210 0.2101.00 ug/L 10/18/17 16:02 1cis-1,2-Dichloroethene
<0.170 0.1701.00 ug/L 10/18/17 16:02 1cis-1,3-Dichloropropene
<0.250 0.2501.00 ug/L 10/18/17 16:02 1Dibromochloromethane
<0.940 0.94010.0 ug/L 10/18/17 16:02 11,2-Dibromo-3-Chloropropane
<0.210 0.2101.00 ug/L 10/18/17 16:02 11,2-Dibromoethane (EDB)
<0.450 0.4501.00 ug/L 10/18/17 16:02 1Dibromomethane
<0.190 0.1901.00 ug/L 10/18/17 16:02 11,2-Dichlorobenzene
<0.170 0.1701.00 ug/L 10/18/17 16:02 11,4-Dichlorobenzene
<0.240 0.2401.00 ug/L 10/18/17 16:02 11,1-Dichloroethane
<0.200 0.2001.00 ug/L 10/18/17 16:02 11,2-Dichloroethane
<0.250 0.2501.00 ug/L 10/18/17 16:02 11,1-Dichloroethene
<0.250 0.2501.00 ug/L 10/18/17 16:02 11,2-Dichloropropane
<0.190 0.1901.00 ug/L 10/18/17 16:02 1Ethylbenzene
<1.28 1.2810.0 ug/L 10/18/17 16:02 12-Hexanone
<1.50 1.5010.0 ug/L 10/18/17 16:02 1Iodomethane
<1.00 1.005.00 ug/L 10/18/17 16:02 1Methylene Chloride
<0.810 0.81010.0 ug/L 10/18/17 16:02 14-Methyl-2-pentanone (MIBK)
<0.280 0.2801.00 ug/L 10/18/17 16:02 1Styrene
<0.150 0.1501.00 ug/L 10/18/17 16:02 11,1,1,2-Tetrachloroethane
<0.190 0.1901.00 ug/L 10/18/17 16:02 11,1,2,2-Tetrachloroethane
<0.140 0.1401.00 ug/L 10/18/17 16:02 1Tetrachloroethene
<0.170 0.1701.00 ug/L 10/18/17 16:02 1Toluene
<0.460 0.4605.00 ug/L 10/18/17 16:02 1trans-1,4-Dichloro-2-butene
<0.230 0.2301.00 ug/L 10/18/17 16:02 1trans-1,2-Dichloroethene
<0.170 0.1701.00 ug/L 10/18/17 16:02 1trans-1,3-Dichloropropene
<0.190 0.1901.00 ug/L 10/18/17 16:02 11,1,1-Trichloroethane
<0.190 0.1901.00 ug/L 10/18/17 16:02 11,1,2-Trichloroethane
<0.200 0.2001.00 ug/L 10/18/17 16:02 1Trichloroethene
<0.210 0.2101.00 ug/L 10/18/17 16:02 1Trichlorofluoromethane
<0.230 0.2301.00 ug/L 10/18/17 16:02 11,2,3-Trichloropropane
<1.71 1.7110.0 ug/L 10/18/17 16:02 1Vinyl acetate
<0.180 0.1801.00 ug/L 10/18/17 16:02 1Vinyl chloride
<0.580 0.5803.00 ug/L 10/18/17 16:02 1Xylenes, Total
TestAmerica Nashville
Page 12 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 490-468800/7
Matrix: Water Prep Type: Total/NA
Analysis Batch: 468800
4-Bromofluorobenzene (Surr)113 70-130 10/18/17 16:02 1
MB MB
Surrogate Dil FacPrepared AnalyzedQualifier Limits%Recovery
97 10/18/17 16:02 1Dibromofluoromethane (Surr)70-130
109 10/18/17 16:02 11,2-Dichloroethane-d4 (Surr)70-130
95 10/18/17 16:02 1Toluene-d8 (Surr)70-130
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-468800/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 468800
Acetone 100 104.4 ug/L 104 39-150
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Acrylonitrile 200 225.4 ug/L 113 63-135
Benzene 20.0 19.05 ug/L 95 70-130
Bromochloromethane 20.0 14.66 ug/L 73 70-130
Bromodichloromethane 20.0 21.17 ug/L 106 70-130
Bromoform 20.0 22.72 ug/L 114 70-137
Bromomethane 20.0 15.40 ug/L 77 53-150
2-Butanone (MEK)100 97.88 ug/L 98 55-143
Carbon disulfide 20.0 19.88 ug/L 99 64-135
Carbon tetrachloride 20.0 21.54 ug/L 108 70-147
Chlorobenzene 20.0 19.93 ug/L 100 70-130
Chloroethane 20.0 18.42 ug/L 92 60-138
Chloroform 20.0 18.94 ug/L 95 70-130
Chloromethane 20.0 24.47 ug/L 122 33-150
cis-1,2-Dichloroethene 20.0 17.59 ug/L 88 70-130
cis-1,3-Dichloropropene 20.0 20.26 ug/L 101 70-133
Dibromochloromethane 20.0 22.87 ug/L 114 70-133
1,2-Dibromo-3-Chloropropane 20.0 21.90 ug/L 110 45-138
1,2-Dibromoethane (EDB)20.0 19.70 ug/L 99 70-130
Dibromomethane 20.0 18.88 ug/L 94 70-130
1,2-Dichlorobenzene 20.0 19.21 ug/L 96 70-130
1,4-Dichlorobenzene 20.0 20.02 ug/L 100 70-130
1,1-Dichloroethane 20.0 19.63 ug/L 98 70-130
1,2-Dichloroethane 20.0 22.56 ug/L 113 70-130
1,1-Dichloroethene 20.0 18.05 ug/L 90 70-132
1,2-Dichloropropane 20.0 19.81 ug/L 99 70-130
Ethylbenzene 20.0 20.65 ug/L 103 70-130
2-Hexanone 100 114.1 ug/L 114 54-142
Iodomethane 20.0 12.14 ug/L 61 40-150
Methylene Chloride 20.0 17.51 ug/L 88 70-130
4-Methyl-2-pentanone (MIBK)100 107.9 ug/L 108 60-137
Styrene 20.0 18.78 ug/L 94 70-130
1,1,1,2-Tetrachloroethane 20.0 19.90 ug/L 100 70-130
1,1,2,2-Tetrachloroethane 20.0 21.66 ug/L 108 69-131
Tetrachloroethene 20.0 19.51 ug/L 98 70-130
Toluene 20.0 19.12 ug/L 96 70-130
trans-1,4-Dichloro-2-butene 20.0 18.93 ug/L 95 41-150
trans-1,2-Dichloroethene 20.0 20.94 ug/L 105 70-130
TestAmerica Nashville
Page 13 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-468800/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 468800
trans-1,3-Dichloropropene 20.0 19.50 ug/L 98 63-142
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
1,1,1-Trichloroethane 20.0 20.59 ug/L 103 70-135
1,1,2-Trichloroethane 20.0 18.49 ug/L 92 70-130
Trichloroethene 20.0 20.26 ug/L 101 70-130
Trichlorofluoromethane 20.0 21.86 ug/L 109 59-150
1,2,3-Trichloropropane 20.0 20.92 ug/L 105 70-131
Vinyl acetate 40.0 31.10 ug/L 78 54-146
Vinyl chloride 20.0 21.65 ug/L 108 57-137
Xylenes, Total 40.0 40.67 ug/L 102 70-132
4-Bromofluorobenzene (Surr)70 -130
Surrogate
109
LCS LCS
Qualifier Limits%Recovery
88Dibromofluoromethane (Surr)70 -130
1141,2-Dichloroethane-d4 (Surr)70 -130
101Toluene-d8 (Surr)70 -130
Client Sample ID: Matrix SpikeLab Sample ID: 490-138923-A-4 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 468800
Acetone <2.66 100 92.53 ug/L 93 39-150
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Acrylonitrile <0.500 200 202.5 ug/L 101 50-135
Benzene <0.200 20.0 19.74 ug/L 99 55-147
Bromochloromethane <0.150 20.0 15.33 ug/L 77 59-132
Bromodichloromethane <0.170 20.0 20.67 ug/L 103 70-140
Bromoform <0.290 20.0 21.14 ug/L 106 53-150
Bromomethane <0.350 20.0 19.26 ug/L 96 30-150
2-Butanone (MEK)<2.64 100 89.32 ug/L 89 50-143
Carbon disulfide <0.220 20.0 19.31 ug/L 97 35-150
Carbon tetrachloride <0.180 20.0 24.01 ug/L 120 56-150
Chlorobenzene <0.180 20.0 19.54 ug/L 98 70-130
Chloroethane <0.360 20.0 21.32 ug/L 107 58-141
Chloroform <0.230 20.0 19.94 ug/L 100 66-138
Chloromethane <0.360 20.0 25.05 ug/L 125 10-150
cis-1,2-Dichloroethene <0.210 20.0 18.81 ug/L 94 68-131
cis-1,3-Dichloropropene <0.170 20.0 19.09 ug/L 95 70-133
Dibromochloromethane <0.250 20.0 22.57 ug/L 113 66-140
1,2-Dibromo-3-Chloropropane <0.940 20.0 15.39 ug/L 77 38-138
1,2-Dibromoethane (EDB)<0.210 20.0 18.78 ug/L 94 65-137
Dibromomethane <0.450 20.0 17.95 ug/L 90 70-130
1,2-Dichlorobenzene <0.190 20.0 19.25 ug/L 96 70-130
1,4-Dichlorobenzene <0.170 20.0 17.40 ug/L 87 70-130
1,1-Dichloroethane <0.240 20.0 20.92 ug/L 105 61-139
1,2-Dichloroethane <0.200 20.0 22.45 ug/L 112 64-136
1,1-Dichloroethene <0.250 20.0 19.33 ug/L 97 54-150
1,2-Dichloropropane <0.250 20.0 19.00 ug/L 95 67-130
Ethylbenzene <0.190 20.0 21.05 ug/L 105 65-139
TestAmerica Nashville
Page 14 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Matrix SpikeLab Sample ID: 490-138923-A-4 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 468800
2-Hexanone <1.28 100 100.2 ug/L 100 44-150
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Iodomethane <1.50 20.0 17.61 ug/L 88 34-150
Methylene Chloride <1.00 20.0 17.49 ug/L 87 64-130
4-Methyl-2-pentanone (MIBK)<0.810 100 95.09 ug/L 95 50-140
Styrene <0.280 20.0 18.34 ug/L 92 70-130
1,1,1,2-Tetrachloroethane <0.150 20.0 20.25 ug/L 101 70-131
1,1,2,2-Tetrachloroethane <0.190 20.0 20.91 ug/L 105 56-145
Tetrachloroethene <0.140 20.0 19.12 ug/L 96 57-138
Toluene <0.170 20.0 19.18 ug/L 96 64-136
trans-1,4-Dichloro-2-butene <0.460 20.0 18.67 ug/L 93 39-150
trans-1,2-Dichloroethene <0.230 20.0 21.79 ug/L 109 59-143
trans-1,3-Dichloropropene <0.170 20.0 19.40 ug/L 97 63-142
1,1,1-Trichloroethane <0.190 20.0 22.26 ug/L 111 68-144
1,1,2-Trichloroethane <0.190 20.0 18.29 ug/L 91 70-130
Trichloroethene <0.200 20.0 19.82 ug/L 99 63-135
Trichlorofluoromethane <0.210 20.0 23.74 ug/L 119 44-150
1,2,3-Trichloropropane <0.230 20.0 20.49 ug/L 102 65-131
Vinyl acetate <1.71 40.0 30.94 ug/L 77 43-146
Vinyl chloride <0.180 20.0 21.24 ug/L 106 57-150
Xylenes, Total <0.580 40.0 40.75 ug/L 102 69-132
4-Bromofluorobenzene (Surr)70 -130
Surrogate
112
MS MS
Qualifier Limits%Recovery
94Dibromofluoromethane (Surr)70 -130
1141,2-Dichloroethane-d4 (Surr)70 -130
100Toluene-d8 (Surr)70 -130
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-138923-A-4 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 468800
Acetone <2.66 100 88.94 ug/L 89 39-150 4 28
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Acrylonitrile <0.500 200 199.1 ug/L 100 50-135 2 23
Benzene <0.200 20.0 19.75 ug/L 99 55-147 0 22
Bromochloromethane <0.150 20.0 16.14 ug/L 81 59-132 5 21
Bromodichloromethane <0.170 20.0 20.77 ug/L 104 70-140 0 196
Bromoform <0.290 20.0 20.67 ug/L 103 53-150 2 20
Bromomethane <0.350 20.0 20.72 ug/L 104 30-150 7 44
2-Butanone (MEK)<2.64 100 84.49 ug/L 84 50-143 6 28
Carbon disulfide <0.220 20.0 19.45 ug/L 97 35-150 1 34
Carbon tetrachloride <0.180 20.0 23.78 ug/L 119 56-150 1 18
Chlorobenzene <0.180 20.0 19.30 ug/L 96 70-130 1 15
Chloroethane <0.360 20.0 20.81 ug/L 104 58-141 2 31
Chloroform <0.230 20.0 20.06 ug/L 100 66-138 1 21
Chloromethane <0.360 20.0 24.40 ug/L 122 10-150 3 43
cis-1,2-Dichloroethene <0.210 20.0 18.42 ug/L 92 68-131 2 21
cis-1,3-Dichloropropene <0.170 20.0 19.21 ug/L 96 70-133 1 19
TestAmerica Nashville
Page 15 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-138923-A-4 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 468800
Dibromochloromethane <0.250 20.0 22.64 ug/L 113 66-140 0 19
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
1,2-Dibromo-3-Chloropropane <0.940 20.0 17.27 ug/L 86 38-138 12 26
1,2-Dibromoethane (EDB)<0.210 20.0 18.51 ug/L 93 65-137 1 21
Dibromomethane <0.450 20.0 17.86 ug/L 89 70-130 1 19
1,2-Dichlorobenzene <0.190 20.0 18.86 ug/L 94 70-130 2 15
1,4-Dichlorobenzene <0.170 20.0 20.03 ug/L 100 70-130 14 14
1,1-Dichloroethane <0.240 20.0 21.09 ug/L 105 61-139 1 23
1,2-Dichloroethane <0.200 20.0 21.62 ug/L 108 64-136 4 22
1,1-Dichloroethene <0.250 20.0 18.77 ug/L 94 54-150 3 24
1,2-Dichloropropane <0.250 20.0 19.47 ug/L 97 67-130 2 19
Ethylbenzene <0.190 20.0 20.35 ug/L 102 65-139 3 18
2-Hexanone <1.28 100 101.3 ug/L 101 44-150 1 21
Iodomethane <1.50 20.0 17.66 ug/L 88 34-150 0 37
Methylene Chloride <1.00 20.0 17.44 ug/L 87 64-130 0 22
4-Methyl-2-pentanone (MIBK)<0.810 100 93.25 ug/L 93 50-140 2 24
Styrene <0.280 20.0 18.40 ug/L 92 70-130 0 16
1,1,1,2-Tetrachloroethane <0.150 20.0 19.44 ug/L 97 70-131 4 16
1,1,2,2-Tetrachloroethane <0.190 20.0 20.35 ug/L 102 56-145 3 19
Tetrachloroethene <0.140 20.0 19.47 ug/L 97 57-138 2 17
Toluene <0.170 20.0 19.10 ug/L 96 64-136 0 18
trans-1,4-Dichloro-2-butene <0.460 20.0 17.72 ug/L 89 39-150 5 28
trans-1,2-Dichloroethene <0.230 20.0 21.39 ug/L 107 59-143 2 25
trans-1,3-Dichloropropene <0.170 20.0 18.98 ug/L 95 63-142 2 18
1,1,1-Trichloroethane <0.190 20.0 22.14 ug/L 111 68-144 1 17
1,1,2-Trichloroethane <0.190 20.0 17.76 ug/L 89 70-130 3 18
Trichloroethene <0.200 20.0 19.83 ug/L 99 63-135 0 17
Trichlorofluoromethane <0.210 20.0 23.57 ug/L 118 44-150 1 32
1,2,3-Trichloropropane <0.230 20.0 20.11 ug/L 101 65-131 2 19
Vinyl acetate <1.71 40.0 30.55 ug/L 76 43-146 1 20
Vinyl chloride <0.180 20.0 21.05 ug/L 105 57-150 1 37
Xylenes, Total <0.580 40.0 40.81 ug/L 102 69-132 0 17
4-Bromofluorobenzene (Surr)70 -130
Surrogate
113
MSD MSD
Qualifier Limits%Recovery
94Dibromofluoromethane (Surr)70 -130
1111,2-Dichloroethane-d4 (Surr)70 -130
101Toluene-d8 (Surr)70 -130
Method: 6010D - Metals (ICP)
Client Sample ID: Method BlankLab Sample ID: MB 490-469156/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469855 Prep Batch: 469156
RL MDL
Arsenic <0.00860 ^0.0100 0.00860 mg/L 10/19/17 13:43 10/21/17 01:25 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
<0.000500 ^0.0005000.00100 mg/L 10/19/17 13:43 10/21/17 01:25 1Cadmium
<0.00300 ^0.003000.00500 mg/L 10/19/17 13:43 10/21/17 01:25 1Chromium
TestAmerica Nashville
Page 16 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 6010D - Metals (ICP) (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 490-469156/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469855 Prep Batch: 469156
RL MDL
Selenium <0.00500 0.0100 0.00500 mg/L 10/19/17 13:43 10/21/17 01:25 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Method BlankLab Sample ID: MB 490-469156/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 471733 Prep Batch: 469156
RL MDL
Silver <0.00300 0.00500 0.00300 mg/L 10/19/17 13:43 10/29/17 02:21 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
<0.00500 0.005000.0100 mg/L 10/19/17 13:43 10/29/17 02:21 1Barium
<0.00200 0.002000.00500 mg/L 10/19/17 13:43 10/29/17 02:21 1Lead
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469156/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469855 Prep Batch: 469156
Arsenic 0.100 0.1077 ^ mg/L 108 80-120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Cadmium 0.100 0.1040 ^ mg/L 104 80-120
Chromium 0.100 0.1034 ^ mg/L 103 80-120
Selenium 0.100 0.09940 mg/L 99 80-120
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469156/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 471733 Prep Batch: 469156
Silver 0.100 0.1012 mg/L 101 80-120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Barium 0.100 0.1018 mg/L 102 80-120
Lead 0.100 0.1014 mg/L 101 80-120
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-469156/18-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469855 Prep Batch: 469156
Arsenic 0.100 0.1046 ^ mg/L 105 80-120 3 20
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Cadmium 0.100 0.1023 ^ mg/L 102 80-120 2 20
Chromium 0.100 0.1021 ^ mg/L 102 80-120 1 20
Selenium 0.100 0.1005 mg/L 101 80-120 1 20
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-469156/18-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 471733 Prep Batch: 469156
Silver 0.100 0.09990 mg/L 100 80-120 1 20
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Barium 0.100 0.1006 mg/L 101 80-120 1 20
Lead 0.100 0.09850 mg/L 99 80-120 3 20
TestAmerica Nashville
Page 17 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 6010D - Metals (ICP) (Continued)
Client Sample ID: Matrix SpikeLab Sample ID: 490-138933-G-3-B MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469855 Prep Batch: 469156
Arsenic <0.00860 ^0.100 0.1055 ^ mg/L 106 75-125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Cadmium 0.000700 J ^0.100 0.09950 ^ mg/L 99 75-125
Chromium <0.00300 ^0.100 0.1008 ^ mg/L 101 75-125
Selenium <0.00500 0.100 0.09930 mg/L 99 75-125
Client Sample ID: Matrix SpikeLab Sample ID: 490-138933-G-3-B MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 471733 Prep Batch: 469156
Silver <0.600 0.100 <0.600 mg/L NC 75-125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Barium <1.00 0.100 <1.00 mg/L NC 75-125
Lead 0.400 J F1 0.100 <0.400 F1 mg/L 0 75-125
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-138933-G-3-C MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469855 Prep Batch: 469156
Arsenic <0.00860 ^0.100 0.1082 ^ mg/L 108 75-125 3 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Cadmium 0.000700 J ^0.100 0.1010 ^ mg/L 100 75-125 1 20
Chromium <0.00300 ^0.100 0.1019 ^ mg/L 102 75-125 1 20
Selenium <0.00500 0.100 0.1022 mg/L 102 75-125 3 20
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-138933-G-3-C MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 471733 Prep Batch: 469156
Silver <0.600 0.100 <0.600 mg/L NC 75-125 NC 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Barium <1.00 0.100 <1.00 mg/L NC 75-125 NC 20
Lead 0.400 J F1 0.100 0.4200 J F1 mg/L 20 75-125 NC 20
Method: 6020B - Metals (ICP/MS)
Client Sample ID: Method BlankLab Sample ID: MB 490-469152/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469548 Prep Batch: 469152
RL MDL
Antimony <0.800 2.00 0.800 ug/L 10/19/17 13:31 10/20/17 13:56 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
<0.100 0.1002.00 ug/L 10/19/17 13:31 10/20/17 13:56 1Beryllium
<0.100 0.1002.00 ug/L 10/19/17 13:31 10/20/17 13:56 1Cobalt
<0.800 0.8002.00 ug/L 10/19/17 13:31 10/20/17 13:56 1Thallium
<0.700 0.7002.00 ug/L 10/19/17 13:31 10/20/17 13:56 1Vanadium
<5.20 5.2025.0 ug/L 10/19/17 13:31 10/20/17 13:56 1Zinc
TestAmerica Nashville
Page 18 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 6020B - Metals (ICP/MS) (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469152/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469548 Prep Batch: 469152
Antimony 100 101.0 ug/L 101 80-120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Beryllium 100 95.22 ug/L 95 80-120
Cobalt 100 99.82 ug/L 100 80-120
Thallium 100 98.41 ug/L 98 80-120
Vanadium 100 101.0 ug/L 101 80-120
Zinc 100 102.1 ug/L 102 80-120
Client Sample ID: SW-01Lab Sample ID: 490-138985-1 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469548 Prep Batch: 469152
Antimony <0.800 100 101.4 ug/L 101 75-125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Beryllium <0.100 100 94.46 ug/L 94 75-125
Cobalt 1.49 J 100 102.2 ug/L 101 75-125
Thallium <0.800 100 100.8 ug/L 101 75-125
Vanadium <0.700 100 101.4 ug/L 101 75-125
Zinc <5.20 100 102.9 ug/L 103 75-125
Client Sample ID: SW-01Lab Sample ID: 490-138985-1 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469548 Prep Batch: 469152
Antimony <0.800 100 98.52 ug/L 99 75-125 3 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Beryllium <0.100 100 94.31 ug/L 94 75-125 0 20
Cobalt 1.49 J 100 100.6 ug/L 99 75-125 2 20
Thallium <0.800 100 99.58 ug/L 100 75-125 1 20
Vanadium <0.700 100 100.4 ug/L 100 75-125 1 20
Zinc <5.20 100 102.7 ug/L 103 75-125 0 20
Method: 7470A - Mercury (CVAA)
Client Sample ID: Method BlankLab Sample ID: MB 490-470121/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470713 Prep Batch: 470121
RL MDL
Mercury <0.100 0.200 0.100 ug/L 10/23/17 22:14 10/24/17 16:01 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-470121/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470713 Prep Batch: 470121
Mercury 1.00 1.146 ug/L 115 80-120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
TestAmerica Nashville
Page 19 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 7470A - Mercury (CVAA) (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-470121/3-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470713 Prep Batch: 470121
Mercury 1.00 1.090 ug/L 109 80-120 5 20
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Client Sample ID: Matrix SpikeLab Sample ID: 490-139187-G-1-B MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470713 Prep Batch: 470121
Mercury <0.100 1.00 0.8628 ug/L 86 75-125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-139187-G-1-C MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470713 Prep Batch: 470121
Mercury <0.100 1.00 0.8608 ug/L 86 75-125 0 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
TestAmerica Nashville
Page 20 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Association Summary
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
GC/MS VOA
Analysis Batch: 468800
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 8260B490-138985-1 SW-01 Total/NA
Water 8260B490-138985-2 SW-02R Total/NA
Water 8260B490-138985-3 Trip Blank Total/NA
Water 8260BMB 490-468800/7 Method Blank Total/NA
Water 8260BLCS 490-468800/4 Lab Control Sample Total/NA
Water 8260B490-138923-A-4 MS Matrix Spike Total/NA
Water 8260B490-138923-A-4 MSD Matrix Spike Duplicate Total/NA
Metals
Prep Batch: 469152
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3010A490-138985-1 SW-01 Total/NA
Water 3010A490-138985-2 SW-02R Total/NA
Water 3010AMB 490-469152/1-A Method Blank Total/NA
Water 3010ALCS 490-469152/2-A Lab Control Sample Total/NA
Water 3010A490-138985-1 MS SW-01 Total/NA
Water 3010A490-138985-1 MSD SW-01 Total/NA
Prep Batch: 469156
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3010A490-138985-1 SW-01 Total/NA
Water 3010A490-138985-2 SW-02R Total/NA
Water 3010AMB 490-469156/1-A Method Blank Total/NA
Water 3010ALCS 490-469156/2-A Lab Control Sample Total/NA
Water 3010ALCSD 490-469156/18-A Lab Control Sample Dup Total/NA
Water 3010A490-138933-G-3-B MS Matrix Spike Total/NA
Water 3010A490-138933-G-3-C MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 469548
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020B 469152490-138985-1 SW-01 Total/NA
Water 6020B 469152490-138985-2 SW-02R Total/NA
Water 6020B 469152MB 490-469152/1-A Method Blank Total/NA
Water 6020B 469152LCS 490-469152/2-A Lab Control Sample Total/NA
Water 6020B 469152490-138985-1 MS SW-01 Total/NA
Water 6020B 469152490-138985-1 MSD SW-01 Total/NA
Analysis Batch: 469855
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6010D 469156490-138985-1 SW-01 Total/NA
Water 6010D 469156490-138985-2 SW-02R Total/NA
Water 6010D 469156MB 490-469156/1-A Method Blank Total/NA
Water 6010D 469156LCS 490-469156/2-A Lab Control Sample Total/NA
Water 6010D 469156LCSD 490-469156/18-A Lab Control Sample Dup Total/NA
Water 6010D 469156490-138933-G-3-B MS Matrix Spike Total/NA
Water 6010D 469156490-138933-G-3-C MSD Matrix Spike Duplicate Total/NA
TestAmerica Nashville
Page 21 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Association Summary
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Metals (Continued)
Prep Batch: 470121
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A490-138985-1 SW-01 Total/NA
Water 7470A490-138985-2 SW-02R Total/NA
Water 7470AMB 490-470121/1-A Method Blank Total/NA
Water 7470ALCS 490-470121/2-A Lab Control Sample Total/NA
Water 7470ALCSD 490-470121/3-A Lab Control Sample Dup Total/NA
Water 7470A490-139187-G-1-B MS Matrix Spike Total/NA
Water 7470A490-139187-G-1-C MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 470713
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A 470121490-138985-1 SW-01 Total/NA
Water 7470A 470121490-138985-2 SW-02R Total/NA
Water 7470A 470121MB 490-470121/1-A Method Blank Total/NA
Water 7470A 470121LCS 490-470121/2-A Lab Control Sample Total/NA
Water 7470A 470121LCSD 490-470121/3-A Lab Control Sample Dup Total/NA
Water 7470A 470121490-139187-G-1-B MS Matrix Spike Total/NA
Water 7470A 470121490-139187-G-1-C MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 471733
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6010D 469156490-138985-1 SW-01 Total/NA
Water 6010D 469156490-138985-2 SW-02R Total/NA
Water 6010D 469156MB 490-469156/1-A Method Blank Total/NA
Water 6010D 469156LCS 490-469156/2-A Lab Control Sample Total/NA
Water 6010D 469156LCSD 490-469156/18-A Lab Control Sample Dup Total/NA
Water 6010D 469156490-138933-G-3-B MS Matrix Spike Total/NA
Water 6010D 469156490-138933-G-3-C MSD Matrix Spike Duplicate Total/NA
TestAmerica Nashville
Page 22 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Lab Chronicle
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-138985-1
Project/Site: Madison Co Operating Landfill
Client Sample ID: SW-01 Lab Sample ID: 490-138985-1
Matrix: WaterDate Collected: 10/17/17 15:35
Date Received: 10/18/17 09:55
Analysis 8260B PS10/18/17 20:361 TAL NSH468800
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Prep 3010A 469156 10/19/17 13:43 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 469855 10/21/17 03:09 LCS TAL NSHTotal/NA
Prep 3010A 469156 10/19/17 13:43 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 471733 10/29/17 03:36 BLG TAL NSHTotal/NA
Prep 3010A 469152 10/19/17 13:31 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 469548 10/20/17 14:20 BLG TAL NSHTotal/NA
Prep 7470A 470121 10/23/17 22:14 RDF TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 470713 10/24/17 16:58 RDF TAL NSHTotal/NA
Client Sample ID: SW-02R Lab Sample ID: 490-138985-2
Matrix: WaterDate Collected: 10/17/17 10:15
Date Received: 10/18/17 09:55
Analysis 8260B PS10/18/17 21:031 TAL NSH468800
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Prep 3010A 469156 10/19/17 13:43 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 469855 10/21/17 03:04 LCS TAL NSHTotal/NA
Prep 3010A 469156 10/19/17 13:43 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 471733 10/29/17 03:31 BLG TAL NSHTotal/NA
Prep 3010A 469152 10/19/17 13:31 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 469548 10/20/17 14:35 BLG TAL NSHTotal/NA
Prep 7470A 470121 10/23/17 22:14 RDF TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 470713 10/24/17 17:01 RDF TAL NSHTotal/NA
Client Sample ID: Trip Blank Lab Sample ID: 490-138985-3
Matrix: WaterDate Collected: 10/17/17 01:01
Date Received: 10/18/17 09:55
Analysis 8260B PS10/18/17 19:421 TAL NSH468800
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Laboratory References:
TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL [phone]
TestAmerica Nashville
Page 23 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Method Summary
TestAmerica Job ID: 490-138985-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method Method Description LaboratoryProtocol
SW8468260BVolatile Organic Compounds (GC/MS)TAL NSH
SW8466010DMetals (ICP)TAL NSH
SW8466020BMetals (ICP/MS)TAL NSH
SW8467470AMercury (CVAA)TAL NSH
Protocol References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL [phone]
TestAmerica Nashville
Page 24 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Accreditation/Certification Summary
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-138985-1
Project/Site: Madison Co Operating Landfill
Laboratory: TestAmerica Nashville
The accreditations/certifications listed below are applicable to this report.
Authority Program EPA Region Identification Number Expiration Date
North Carolina (WW/SW)3874State Program 12-31-17
TestAmerica Nashville
Page 25 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Page 26 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Page 27 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Login Sample Receipt Checklist
Client: Anchor QEA of North Carolina PLLC Job Number: 490-138985-1
Login Number: 138985
Question Answer Comment
Creator: Huskey, Adam
List Source: TestAmerica Nashville
List Number: 1
TrueRadioactivity wasn't checked or is </= background as measured by a survey
meter.
TrueThe cooler's custody seal, if present, is intact.
N/ASample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
TrueContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
TestAmerica Nashville
Page 28 of 28 11/6/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
ANALYTICAL REPORT
TestAmerica Laboratories, Inc.
TestAmerica Nashville
2960 Foster Creighton Drive
Nashville, TN 37204
Tel: [phone]
TestAmerica Job ID: 490-139036-1
Client Project/Site: Madison Co Operating Landfill
For:
Anchor QEA of North Carolina PLLC
231 W Haywood Street
Asheville, North Carolina 28801
Attn: Brian Gant
Authorized for release by:
10/31/2017 6:00:55 PM
Ken Hayes, Project Manager II
[phone]
[e-mail]
The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited
parameters, exceptions are noted in this report. This report may not be reproduced except in full,
and with written approval from the laboratory. For questions please contact the Project Manager
at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
1
2
3
4
5
6
7
8
9
10
11
12
13
Table of Contents
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
TestAmerica Job ID: 490-139036-1
Page 2 of 52 TestAmerica Nashville10/31/2017
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .26
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .41
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .45
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .48
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .49
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .50
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .52
1
2
3
4
5
6
7
8
9
10
11
12
13
Sample Summary
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID Client Sample ID ReceivedCollectedMatrix
490-139036-1 MW-01 Water 10/17/17 09:51 10/19/17 09:40
490-139036-2 MW-02 Water 10/17/17 14:10 10/19/17 09:40
490-139036-3 MW-03 Water 10/18/17 12:10 10/19/17 09:40
490-139036-4 MW-04 Water 10/18/17 12:53 10/19/17 09:40
490-139036-5 MW-05 Water 10/18/17 09:51 10/19/17 09:40
490-139036-6 MW-06R Water 10/17/17 15:07 10/19/17 09:40
490-139036-7 MW-07R Water 10/17/17 12:14 10/19/17 09:40
490-139036-8 MW-08 Water 10/17/17 11:17 10/19/17 09:40
490-139036-9 MW-09 Water 10/18/17 10:56 10/19/17 09:40
490-139036-10 Trip Blank Water 10/17/17 01:01 10/19/17 09:40
TestAmerica Nashville
Page 3 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Case Narrative
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-139036-1
Project/Site: Madison Co Operating Landfill
Job ID: 490-139036-1
Laboratory: TestAmerica Nashville
Narrative
Job Narrative
490-139036-1
Comments
No additional comments.
Receipt
The samples were received on 10/19/2017 9:40 AM; the samples arrived in good condition, properly preserved and, where required, on
ice. The temperature of the cooler at receipt was 5.5º C.
GC/MS VOA
Method 8260B: The following volatile sample was analyzed with significant headspace in the sample Container(s): Trip Blank
(490-139036-10). Significant headspace is defined as a bubble greater than 6 mm in diameter.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Metals
Method 6010D: The low level continuing calibration verification (CCVL) associated with batch 490-470149 that ran before the samples
recovered outside the control limits for Silver, Arsenic, Lead and Selenium. The CCVL that ran after the samples passed; therefore, the
data have been reported.
Method 6010D: The continuing calibration verification (CCV) associated with batch 490-471259 recovered above the upper control limit for
Chromium and Silver. The samples associated with this CCV were non-detects for the affected analytes; therefore, the data have been
reported. The following samples are impacted: MW-01 (490-139036-1), MW-02 (490-139036-2), MW-03 (490-139036-3), MW-04
(490-139036-4), MW-05 (490-139036-5), MW-06R (490-139036-6), MW-07R (490-139036-7), MW-08 (490-139036-8) and MW-09
(490-139036-9).
Method 6010D: The low level continuing calibration verification (CCVL) associated with batch 490-471259 recovered above the upper
control limit for Copper and Selenium. The samples associated with this CCV were non-detects for the affected analytes; therefore, the
data have been reported.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Field Service / Mobile Lab
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
VOA Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
TestAmerica NashvillePage 4 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Definitions/Glossary
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Qualifiers
GC/MS VOA
Qualifier Description
4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not
applicable.
Qualifier
F1 MS and/or MSD Recovery is outside acceptance limits.
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Metals
Qualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Qualifier
F1 MS and/or MSD Recovery is outside acceptance limits.
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TestAmerica Nashville
Page 5 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-1Client Sample ID: MW-01
Matrix: WaterDate Collected: 10/17/17 09:51
Date Received: 10/19/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/19/17 20:25 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
10.0 0.500 ug/L 10/19/17 20:25 1Acrylonitrile<0.500
1.00 0.200 ug/L 10/19/17 20:25 1Benzene<0.200
1.00 0.150 ug/L 10/19/17 20:25 1Bromochloromethane<0.150
1.00 0.170 ug/L 10/19/17 20:25 1Bromodichloromethane<0.170
1.00 0.290 ug/L 10/19/17 20:25 1Bromoform<0.290
1.00 0.350 ug/L 10/19/17 20:25 1Bromomethane<0.350
50.0 2.64 ug/L 10/19/17 20:25 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 10/19/17 20:25 1Carbon disulfide <0.220
1.00 0.180 ug/L 10/19/17 20:25 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 10/19/17 20:25 1Chlorobenzene<0.180
1.00 0.360 ug/L 10/19/17 20:25 1Chloroethane<0.360
1.00 0.230 ug/L 10/19/17 20:25 1Chloroform<0.230
1.00 0.360 ug/L 10/19/17 20:25 1Chloromethane<0.360
1.00 0.210 ug/L 10/19/17 20:25 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 10/19/17 20:25 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 10/19/17 20:25 1Dibromochloromethane<0.250
10.0 0.940 ug/L 10/19/17 20:25 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 10/19/17 20:25 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 10/19/17 20:25 1Dibromomethane<0.450
1.00 0.190 ug/L 10/19/17 20:25 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 10/19/17 20:25 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 10/19/17 20:25 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 10/19/17 20:25 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 10/19/17 20:25 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 10/19/17 20:25 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 10/19/17 20:25 1Ethylbenzene<0.190
10.0 1.28 ug/L 10/19/17 20:25 12-Hexanone <1.28
10.0 1.50 ug/L 10/19/17 20:25 1Iodomethane<1.50
5.00 1.00 ug/L 10/19/17 20:25 1Methylene Chloride <1.00
10.0 0.810 ug/L 10/19/17 20:25 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 10/19/17 20:25 1Styrene<0.280
1.00 0.150 ug/L 10/19/17 20:25 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 10/19/17 20:25 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 10/19/17 20:25 1Tetrachloroethene<0.140
1.00 0.170 ug/L 10/19/17 20:25 1Toluene<0.170
5.00 0.460 ug/L 10/19/17 20:25 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 10/19/17 20:25 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 10/19/17 20:25 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 10/19/17 20:25 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 10/19/17 20:25 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 10/19/17 20:25 1Trichloroethene<0.200
1.00 0.210 ug/L 10/19/17 20:25 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 10/19/17 20:25 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 10/19/17 20:25 1Vinyl acetate <1.71
1.00 0.180 ug/L 10/19/17 20:25 1Vinyl chloride <0.180
3.00 0.580 ug/L 10/19/17 20:25 1Xylenes, Total <0.580
TestAmerica Nashville
Page 6 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-1Client Sample ID: MW-01
Matrix: WaterDate Collected: 10/17/17 09:51
Date Received: 10/19/17 09:40
4-Bromofluorobenzene (Surr)98 70-130 10/19/17 20:25 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Dibromofluoromethane (Surr)94 10/19/17 20:25 170-130
1,2-Dichloroethane-d4 (Surr)100 10/19/17 20:25 170-130
Toluene-d8 (Surr)105 10/19/17 20:25 170-130
Method: 6010D - Metals (ICP)
RL MDL
Silver <0.00300 0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 20:59 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.0100 0.00860 mg/L 10/20/17 10:03 10/23/17 20:59 1Arsenic<0.00860
0.0100 0.00500 mg/L 10/20/17 10:03 10/23/17 20:59 1Barium0.0856
0.00100 0.000500 mg/L 10/20/17 10:03 10/23/17 20:59 1Cadmium<0.000500
0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 20:59 1Chromium<0.00300
0.00500 0.00200 mg/L 10/20/17 10:03 10/23/17 20:59 1Lead0.00250 J
0.0100 0.00500 mg/L 10/20/17 10:03 10/23/17 20:59 1Selenium<0.00500
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 10/20/17 14:48 10/23/17 20:33 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2.00 0.100 ug/L 10/20/17 14:48 10/23/17 20:33 1Beryllium<0.100
2.00 0.100 ug/L 10/20/17 14:48 10/23/17 20:33 1Cobalt1.69 J
2.00 0.800 ug/L 10/20/17 14:48 10/23/17 20:33 1Thallium<0.800
2.00 0.700 ug/L 10/20/17 14:48 10/23/17 20:33 1Vanadium<0.700
25.0 5.20 ug/L 10/20/17 14:48 10/23/17 20:33 1Zinc<5.20
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 10/23/17 22:14 10/24/17 17:13 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
TestAmerica Nashville
Page 7 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-2Client Sample ID: MW-02
Matrix: WaterDate Collected: 10/17/17 14:10
Date Received: 10/19/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/19/17 20:50 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
10.0 0.500 ug/L 10/19/17 20:50 1Acrylonitrile<0.500
1.00 0.200 ug/L 10/19/17 20:50 1Benzene<0.200
1.00 0.150 ug/L 10/19/17 20:50 1Bromochloromethane<0.150
1.00 0.170 ug/L 10/19/17 20:50 1Bromodichloromethane<0.170
1.00 0.290 ug/L 10/19/17 20:50 1Bromoform<0.290
1.00 0.350 ug/L 10/19/17 20:50 1Bromomethane<0.350
50.0 2.64 ug/L 10/19/17 20:50 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 10/19/17 20:50 1Carbon disulfide <0.220
1.00 0.180 ug/L 10/19/17 20:50 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 10/19/17 20:50 1Chlorobenzene<0.180
1.00 0.360 ug/L 10/19/17 20:50 1Chloroethane<0.360
1.00 0.230 ug/L 10/19/17 20:50 1Chloroform<0.230
1.00 0.360 ug/L 10/19/17 20:50 1Chloromethane<0.360
1.00 0.210 ug/L 10/19/17 20:50 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 10/19/17 20:50 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 10/19/17 20:50 1Dibromochloromethane<0.250
10.0 0.940 ug/L 10/19/17 20:50 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 10/19/17 20:50 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 10/19/17 20:50 1Dibromomethane<0.450
1.00 0.190 ug/L 10/19/17 20:50 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 10/19/17 20:50 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 10/19/17 20:50 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 10/19/17 20:50 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 10/19/17 20:50 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 10/19/17 20:50 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 10/19/17 20:50 1Ethylbenzene<0.190
10.0 1.28 ug/L 10/19/17 20:50 12-Hexanone <1.28
10.0 1.50 ug/L 10/19/17 20:50 1Iodomethane<1.50
5.00 1.00 ug/L 10/19/17 20:50 1Methylene Chloride <1.00
10.0 0.810 ug/L 10/19/17 20:50 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 10/19/17 20:50 1Styrene<0.280
1.00 0.150 ug/L 10/19/17 20:50 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 10/19/17 20:50 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 10/19/17 20:50 1Tetrachloroethene<0.140
1.00 0.170 ug/L 10/19/17 20:50 1Toluene<0.170
5.00 0.460 ug/L 10/19/17 20:50 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 10/19/17 20:50 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 10/19/17 20:50 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 10/19/17 20:50 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 10/19/17 20:50 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 10/19/17 20:50 1Trichloroethene<0.200
1.00 0.210 ug/L 10/19/17 20:50 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 10/19/17 20:50 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 10/19/17 20:50 1Vinyl acetate <1.71
1.00 0.180 ug/L 10/19/17 20:50 1Vinyl chloride <0.180
3.00 0.580 ug/L 10/19/17 20:50 1Xylenes, Total <0.580
TestAmerica Nashville
Page 8 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-2Client Sample ID: MW-02
Matrix: WaterDate Collected: 10/17/17 14:10
Date Received: 10/19/17 09:40
4-Bromofluorobenzene (Surr)100 70-130 10/19/17 20:50 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Dibromofluoromethane (Surr)103 10/19/17 20:50 170-130
1,2-Dichloroethane-d4 (Surr)102 10/19/17 20:50 170-130
Toluene-d8 (Surr)103 10/19/17 20:50 170-130
Method: 6010D - Metals (ICP)
RL MDL
Silver <0.00300 0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 21:15 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.0100 0.00860 mg/L 10/20/17 10:03 10/23/17 21:15 1Arsenic<0.00860
0.0100 0.00500 mg/L 10/20/17 10:03 10/23/17 21:15 1Barium0.187
0.00100 0.000500 mg/L 10/20/17 10:03 10/23/17 21:15 1Cadmium<0.000500
0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 21:15 1Chromium<0.00300
0.00500 0.00200 mg/L 10/20/17 10:03 10/23/17 21:15 1Lead0.00400 J
0.0100 0.00500 mg/L 10/20/17 10:03 10/23/17 21:15 1Selenium<0.00500
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 10/20/17 14:48 10/23/17 20:24 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2.00 0.100 ug/L 10/20/17 14:48 10/23/17 20:24 1Beryllium<0.100
2.00 0.100 ug/L 10/20/17 14:48 10/23/17 20:24 1Cobalt26.9
2.00 0.800 ug/L 10/20/17 14:48 10/23/17 20:24 1Thallium<0.800
2.00 0.700 ug/L 10/20/17 14:48 10/23/17 20:24 1Vanadium6.77
25.0 5.20 ug/L 10/20/17 14:48 10/23/17 20:24 1Zinc12.0 J
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 10/23/17 22:14 10/24/17 17:16 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
TestAmerica Nashville
Page 9 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-3Client Sample ID: MW-03
Matrix: WaterDate Collected: 10/18/17 12:10
Date Received: 10/19/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/19/17 21:16 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
10.0 0.500 ug/L 10/19/17 21:16 1Acrylonitrile<0.500
1.00 0.200 ug/L 10/19/17 21:16 1Benzene<0.200
1.00 0.150 ug/L 10/19/17 21:16 1Bromochloromethane<0.150
1.00 0.170 ug/L 10/19/17 21:16 1Bromodichloromethane<0.170
1.00 0.290 ug/L 10/19/17 21:16 1Bromoform<0.290
1.00 0.350 ug/L 10/19/17 21:16 1Bromomethane<0.350
50.0 2.64 ug/L 10/19/17 21:16 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 10/19/17 21:16 1Carbon disulfide <0.220
1.00 0.180 ug/L 10/19/17 21:16 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 10/19/17 21:16 1Chlorobenzene<0.180
1.00 0.360 ug/L 10/19/17 21:16 1Chloroethane<0.360
1.00 0.230 ug/L 10/19/17 21:16 1Chloroform<0.230
1.00 0.360 ug/L 10/19/17 21:16 1Chloromethane<0.360
1.00 0.210 ug/L 10/19/17 21:16 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 10/19/17 21:16 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 10/19/17 21:16 1Dibromochloromethane<0.250
10.0 0.940 ug/L 10/19/17 21:16 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 10/19/17 21:16 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 10/19/17 21:16 1Dibromomethane<0.450
1.00 0.190 ug/L 10/19/17 21:16 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 10/19/17 21:16 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 10/19/17 21:16 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 10/19/17 21:16 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 10/19/17 21:16 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 10/19/17 21:16 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 10/19/17 21:16 1Ethylbenzene<0.190
10.0 1.28 ug/L 10/19/17 21:16 12-Hexanone <1.28
10.0 1.50 ug/L 10/19/17 21:16 1Iodomethane<1.50
5.00 1.00 ug/L 10/19/17 21:16 1Methylene Chloride <1.00
10.0 0.810 ug/L 10/19/17 21:16 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 10/19/17 21:16 1Styrene<0.280
1.00 0.150 ug/L 10/19/17 21:16 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 10/19/17 21:16 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 10/19/17 21:16 1Tetrachloroethene<0.140
1.00 0.170 ug/L 10/19/17 21:16 1Toluene<0.170
5.00 0.460 ug/L 10/19/17 21:16 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 10/19/17 21:16 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 10/19/17 21:16 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 10/19/17 21:16 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 10/19/17 21:16 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 10/19/17 21:16 1Trichloroethene<0.200
1.00 0.210 ug/L 10/19/17 21:16 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 10/19/17 21:16 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 10/19/17 21:16 1Vinyl acetate <1.71
1.00 0.180 ug/L 10/19/17 21:16 1Vinyl chloride <0.180
3.00 0.580 ug/L 10/19/17 21:16 1Xylenes, Total <0.580
TestAmerica Nashville
Page 10 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-3Client Sample ID: MW-03
Matrix: WaterDate Collected: 10/18/17 12:10
Date Received: 10/19/17 09:40
4-Bromofluorobenzene (Surr)99 70-130 10/19/17 21:16 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Dibromofluoromethane (Surr)101 10/19/17 21:16 170-130
1,2-Dichloroethane-d4 (Surr)99 10/19/17 21:16 170-130
Toluene-d8 (Surr)104 10/19/17 21:16 170-130
Method: 6010D - Metals (ICP)
RL MDL
Silver <0.00300 0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 19:41 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.0100 0.00860 mg/L 10/20/17 10:03 10/23/17 19:41 1Arsenic<0.00860
0.0100 0.00500 mg/L 10/20/17 10:03 10/23/17 19:41 1Barium0.157
0.00100 0.000500 mg/L 10/20/17 10:03 10/23/17 19:41 1Cadmium<0.000500
0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 19:41 1Chromium<0.00300
0.00500 0.00200 mg/L 10/20/17 10:03 10/23/17 19:41 1Lead0.0123
0.0100 0.00500 mg/L 10/20/17 10:03 10/23/17 19:41 1Selenium<0.00500
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 10/20/17 14:48 10/23/17 20:21 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2.00 0.100 ug/L 10/20/17 14:48 10/23/17 20:21 1Beryllium<0.100
2.00 0.100 ug/L 10/20/17 14:48 10/23/17 20:21 1Cobalt57.9
2.00 0.800 ug/L 10/20/17 14:48 10/23/17 20:21 1Thallium<0.800
2.00 0.700 ug/L 10/20/17 14:48 10/23/17 20:21 1Vanadium<0.700
25.0 5.20 ug/L 10/20/17 14:48 10/23/17 20:21 1Zinc<5.20
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 F1 0.200 0.100 ug/L 10/24/17 01:38 10/24/17 18:11 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
TestAmerica Nashville
Page 11 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-4Client Sample ID: MW-04
Matrix: WaterDate Collected: 10/18/17 12:53
Date Received: 10/19/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/20/17 02:23 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
10.0 0.500 ug/L 10/20/17 02:23 1Acrylonitrile<0.500
1.00 0.200 ug/L 10/20/17 02:23 1Benzene<0.200
1.00 0.150 ug/L 10/20/17 02:23 1Bromochloromethane<0.150
1.00 0.170 ug/L 10/20/17 02:23 1Bromodichloromethane<0.170
1.00 0.290 ug/L 10/20/17 02:23 1Bromoform<0.290
1.00 0.350 ug/L 10/20/17 02:23 1Bromomethane<0.350
50.0 2.64 ug/L 10/20/17 02:23 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 10/20/17 02:23 1Carbon disulfide <0.220
1.00 0.180 ug/L 10/20/17 02:23 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 10/20/17 02:23 1Chlorobenzene<0.180
1.00 0.360 ug/L 10/20/17 02:23 1Chloroethane<0.360
1.00 0.230 ug/L 10/20/17 02:23 1Chloroform<0.230
1.00 0.360 ug/L 10/20/17 02:23 1Chloromethane<0.360
1.00 0.210 ug/L 10/20/17 02:23 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 10/20/17 02:23 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 10/20/17 02:23 1Dibromochloromethane<0.250
10.0 0.940 ug/L 10/20/17 02:23 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 10/20/17 02:23 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 10/20/17 02:23 1Dibromomethane<0.450
1.00 0.190 ug/L 10/20/17 02:23 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 10/20/17 02:23 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 10/20/17 02:23 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 10/20/17 02:23 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 10/20/17 02:23 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 10/20/17 02:23 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 10/20/17 02:23 1Ethylbenzene<0.190
10.0 1.28 ug/L 10/20/17 02:23 12-Hexanone <1.28
10.0 1.50 ug/L 10/20/17 02:23 1Iodomethane<1.50
5.00 1.00 ug/L 10/20/17 02:23 1Methylene Chloride <1.00
10.0 0.810 ug/L 10/20/17 02:23 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 10/20/17 02:23 1Styrene<0.280
1.00 0.150 ug/L 10/20/17 02:23 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 10/20/17 02:23 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 10/20/17 02:23 1Tetrachloroethene<0.140
1.00 0.170 ug/L 10/20/17 02:23 1Toluene<0.170
5.00 0.460 ug/L 10/20/17 02:23 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 10/20/17 02:23 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 10/20/17 02:23 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 10/20/17 02:23 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 10/20/17 02:23 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 10/20/17 02:23 1Trichloroethene<0.200
1.00 0.210 ug/L 10/20/17 02:23 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 10/20/17 02:23 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 10/20/17 02:23 1Vinyl acetate <1.71
1.00 0.180 ug/L 10/20/17 02:23 1Vinyl chloride <0.180
3.00 0.580 ug/L 10/20/17 02:23 1Xylenes, Total <0.580
TestAmerica Nashville
Page 12 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-4Client Sample ID: MW-04
Matrix: WaterDate Collected: 10/18/17 12:53
Date Received: 10/19/17 09:40
4-Bromofluorobenzene (Surr)101 70-130 10/20/17 02:23 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Dibromofluoromethane (Surr)104 10/20/17 02:23 170-130
1,2-Dichloroethane-d4 (Surr)103 10/20/17 02:23 170-130
Toluene-d8 (Surr)104 10/20/17 02:23 170-130
Method: 6010D - Metals (ICP)
RL MDL
Silver <0.00300 0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 19:46 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.0100 0.00860 mg/L 10/20/17 10:03 10/23/17 19:46 1Arsenic<0.00860
0.0100 0.00500 mg/L 10/20/17 10:03 10/23/17 19:46 1Barium0.147
0.00100 0.000500 mg/L 10/20/17 10:03 10/23/17 19:46 1Cadmium<0.000500
0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 19:46 1Chromium<0.00300
0.00500 0.00200 mg/L 10/20/17 10:03 10/23/17 19:46 1Lead0.00430 J
0.0100 0.00500 mg/L 10/20/17 10:03 10/23/17 19:46 1Selenium<0.00500
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 10/20/17 14:48 10/23/17 20:18 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2.00 0.100 ug/L 10/20/17 14:48 10/23/17 20:18 1Beryllium<0.100
2.00 0.100 ug/L 10/20/17 14:48 10/23/17 20:18 1Cobalt0.505 J
2.00 0.800 ug/L 10/20/17 14:48 10/23/17 20:18 1Thallium<0.800
2.00 0.700 ug/L 10/20/17 14:48 10/23/17 20:18 1Vanadium7.96
25.0 5.20 ug/L 10/20/17 14:48 10/23/17 20:18 1Zinc<5.20
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.500 1.00 0.500 ug/L 10/24/17 01:38 10/25/17 21:24 5
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
TestAmerica Nashville
Page 13 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-5Client Sample ID: MW-05
Matrix: WaterDate Collected: 10/18/17 09:51
Date Received: 10/19/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/20/17 02:48 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
10.0 0.500 ug/L 10/20/17 02:48 1Acrylonitrile<0.500
1.00 0.200 ug/L 10/20/17 02:48 1Benzene0.219 J
1.00 0.150 ug/L 10/20/17 02:48 1Bromochloromethane<0.150
1.00 0.170 ug/L 10/20/17 02:48 1Bromodichloromethane<0.170
1.00 0.290 ug/L 10/20/17 02:48 1Bromoform<0.290
1.00 0.350 ug/L 10/20/17 02:48 1Bromomethane<0.350
50.0 2.64 ug/L 10/20/17 02:48 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 10/20/17 02:48 1Carbon disulfide <0.220
1.00 0.180 ug/L 10/20/17 02:48 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 10/20/17 02:48 1Chlorobenzene<0.180
1.00 0.360 ug/L 10/20/17 02:48 1Chloroethane<0.360
1.00 0.230 ug/L 10/20/17 02:48 1Chloroform<0.230
1.00 0.360 ug/L 10/20/17 02:48 1Chloromethane<0.360
1.00 0.210 ug/L 10/20/17 02:48 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 10/20/17 02:48 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 10/20/17 02:48 1Dibromochloromethane<0.250
10.0 0.940 ug/L 10/20/17 02:48 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 10/20/17 02:48 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 10/20/17 02:48 1Dibromomethane<0.450
1.00 0.190 ug/L 10/20/17 02:48 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 10/20/17 02:48 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 10/20/17 02:48 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 10/20/17 02:48 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 10/20/17 02:48 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 10/20/17 02:48 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 10/20/17 02:48 1Ethylbenzene<0.190
10.0 1.28 ug/L 10/20/17 02:48 12-Hexanone <1.28
10.0 1.50 ug/L 10/20/17 02:48 1Iodomethane<1.50
5.00 1.00 ug/L 10/20/17 02:48 1Methylene Chloride <1.00
10.0 0.810 ug/L 10/20/17 02:48 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 10/20/17 02:48 1Styrene<0.280
1.00 0.150 ug/L 10/20/17 02:48 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 10/20/17 02:48 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 10/20/17 02:48 1Tetrachloroethene<0.140
1.00 0.170 ug/L 10/20/17 02:48 1Toluene<0.170
5.00 0.460 ug/L 10/20/17 02:48 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 10/20/17 02:48 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 10/20/17 02:48 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 10/20/17 02:48 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 10/20/17 02:48 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 10/20/17 02:48 1Trichloroethene<0.200
1.00 0.210 ug/L 10/20/17 02:48 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 10/20/17 02:48 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 10/20/17 02:48 1Vinyl acetate <1.71
1.00 0.180 ug/L 10/20/17 02:48 1Vinyl chloride <0.180
3.00 0.580 ug/L 10/20/17 02:48 1Xylenes, Total <0.580
TestAmerica Nashville
Page 14 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-5Client Sample ID: MW-05
Matrix: WaterDate Collected: 10/18/17 09:51
Date Received: 10/19/17 09:40
4-Bromofluorobenzene (Surr)101 70-130 10/20/17 02:48 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Dibromofluoromethane (Surr)103 10/20/17 02:48 170-130
1,2-Dichloroethane-d4 (Surr)105 10/20/17 02:48 170-130
Toluene-d8 (Surr)104 10/20/17 02:48 170-130
Method: 6010D - Metals (ICP)
RL MDL
Silver <0.00300 0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 19:51 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.0100 0.00860 mg/L 10/20/17 10:03 10/23/17 19:51 1Arsenic<0.00860
0.0100 0.00500 mg/L 10/20/17 10:03 10/23/17 19:51 1Barium0.121
0.00100 0.000500 mg/L 10/20/17 10:03 10/23/17 19:51 1Cadmium<0.000500
0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 19:51 1Chromium<0.00300
0.00500 0.00200 mg/L 10/20/17 10:03 10/23/17 19:51 1Lead0.00230 J
0.0100 0.00500 mg/L 10/20/17 10:03 10/23/17 19:51 1Selenium<0.00500
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 10/20/17 14:48 10/23/17 20:15 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2.00 0.100 ug/L 10/20/17 14:48 10/23/17 20:15 1Beryllium<0.100
2.00 0.100 ug/L 10/20/17 14:48 10/23/17 20:15 1Cobalt1.06 J
2.00 0.800 ug/L 10/20/17 14:48 10/23/17 20:15 1Thallium<0.800
2.00 0.700 ug/L 10/20/17 14:48 10/23/17 20:15 1Vanadium5.15
25.0 5.20 ug/L 10/20/17 14:48 10/23/17 20:15 1Zinc7.35 J
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 10/24/17 01:38 10/24/17 18:28 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
TestAmerica Nashville
Page 15 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-6Client Sample ID: MW-06R
Matrix: WaterDate Collected: 10/17/17 15:07
Date Received: 10/19/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/20/17 03:14 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
10.0 0.500 ug/L 10/20/17 03:14 1Acrylonitrile<0.500
1.00 0.200 ug/L 10/20/17 03:14 1Benzene<0.200
1.00 0.150 ug/L 10/20/17 03:14 1Bromochloromethane<0.150
1.00 0.170 ug/L 10/20/17 03:14 1Bromodichloromethane<0.170
1.00 0.290 ug/L 10/20/17 03:14 1Bromoform<0.290
1.00 0.350 ug/L 10/20/17 03:14 1Bromomethane<0.350
50.0 2.64 ug/L 10/20/17 03:14 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 10/20/17 03:14 1Carbon disulfide <0.220
1.00 0.180 ug/L 10/20/17 03:14 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 10/20/17 03:14 1Chlorobenzene<0.180
1.00 0.360 ug/L 10/20/17 03:14 1Chloroethane<0.360
1.00 0.230 ug/L 10/20/17 03:14 1Chloroform<0.230
1.00 0.360 ug/L 10/20/17 03:14 1Chloromethane<0.360
1.00 0.210 ug/L 10/20/17 03:14 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 10/20/17 03:14 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 10/20/17 03:14 1Dibromochloromethane<0.250
10.0 0.940 ug/L 10/20/17 03:14 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 10/20/17 03:14 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 10/20/17 03:14 1Dibromomethane<0.450
1.00 0.190 ug/L 10/20/17 03:14 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 10/20/17 03:14 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 10/20/17 03:14 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 10/20/17 03:14 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 10/20/17 03:14 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 10/20/17 03:14 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 10/20/17 03:14 1Ethylbenzene<0.190
10.0 1.28 ug/L 10/20/17 03:14 12-Hexanone <1.28
10.0 1.50 ug/L 10/20/17 03:14 1Iodomethane<1.50
5.00 1.00 ug/L 10/20/17 03:14 1Methylene Chloride <1.00
10.0 0.810 ug/L 10/20/17 03:14 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 10/20/17 03:14 1Styrene<0.280
1.00 0.150 ug/L 10/20/17 03:14 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 10/20/17 03:14 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 10/20/17 03:14 1Tetrachloroethene<0.140
1.00 0.170 ug/L 10/20/17 03:14 1Toluene<0.170
5.00 0.460 ug/L 10/20/17 03:14 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 10/20/17 03:14 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 10/20/17 03:14 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 10/20/17 03:14 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 10/20/17 03:14 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 10/20/17 03:14 1Trichloroethene<0.200
1.00 0.210 ug/L 10/20/17 03:14 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 10/20/17 03:14 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 10/20/17 03:14 1Vinyl acetate <1.71
1.00 0.180 ug/L 10/20/17 03:14 1Vinyl chloride <0.180
3.00 0.580 ug/L 10/20/17 03:14 1Xylenes, Total <0.580
TestAmerica Nashville
Page 16 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-6Client Sample ID: MW-06R
Matrix: WaterDate Collected: 10/17/17 15:07
Date Received: 10/19/17 09:40
4-Bromofluorobenzene (Surr)100 70-130 10/20/17 03:14 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Dibromofluoromethane (Surr)101 10/20/17 03:14 170-130
1,2-Dichloroethane-d4 (Surr)103 10/20/17 03:14 170-130
Toluene-d8 (Surr)103 10/20/17 03:14 170-130
Method: 6010D - Metals (ICP)
RL MDL
Silver <0.00300 0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 19:15 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.0100 0.00860 mg/L 10/20/17 10:03 10/23/17 19:15 1Arsenic<0.00860
0.0100 0.00500 mg/L 10/20/17 10:03 10/23/17 19:15 1Barium0.0251
0.00100 0.000500 mg/L 10/20/17 10:03 10/23/17 19:15 1Cadmium<0.000500
0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 19:15 1Chromium<0.00300
0.00500 0.00200 mg/L 10/20/17 10:03 10/23/17 19:15 1Lead<0.00200
0.0100 0.00500 mg/L 10/20/17 10:03 10/23/17 19:15 1Selenium<0.00500
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 10/20/17 14:48 10/23/17 20:12 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2.00 0.100 ug/L 10/20/17 14:48 10/23/17 20:12 1Beryllium<0.100
2.00 0.100 ug/L 10/20/17 14:48 10/23/17 20:12 1Cobalt<0.100
2.00 0.800 ug/L 10/20/17 14:48 10/23/17 20:12 1Thallium<0.800
2.00 0.700 ug/L 10/20/17 14:48 10/23/17 20:12 1Vanadium0.727 J
25.0 5.20 ug/L 10/20/17 14:48 10/23/17 20:12 1Zinc<5.20
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 10/24/17 01:38 10/24/17 18:31 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
TestAmerica Nashville
Page 17 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-7Client Sample ID: MW-07R
Matrix: WaterDate Collected: 10/17/17 12:14
Date Received: 10/19/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/20/17 03:39 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
10.0 0.500 ug/L 10/20/17 03:39 1Acrylonitrile<0.500
1.00 0.200 ug/L 10/20/17 03:39 1Benzene<0.200
1.00 0.150 ug/L 10/20/17 03:39 1Bromochloromethane<0.150
1.00 0.170 ug/L 10/20/17 03:39 1Bromodichloromethane<0.170
1.00 0.290 ug/L 10/20/17 03:39 1Bromoform<0.290
1.00 0.350 ug/L 10/20/17 03:39 1Bromomethane<0.350
50.0 2.64 ug/L 10/20/17 03:39 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 10/20/17 03:39 1Carbon disulfide <0.220
1.00 0.180 ug/L 10/20/17 03:39 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 10/20/17 03:39 1Chlorobenzene<0.180
1.00 0.360 ug/L 10/20/17 03:39 1Chloroethane<0.360
1.00 0.230 ug/L 10/20/17 03:39 1Chloroform<0.230
1.00 0.360 ug/L 10/20/17 03:39 1Chloromethane<0.360
1.00 0.210 ug/L 10/20/17 03:39 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 10/20/17 03:39 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 10/20/17 03:39 1Dibromochloromethane<0.250
10.0 0.940 ug/L 10/20/17 03:39 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 10/20/17 03:39 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 10/20/17 03:39 1Dibromomethane<0.450
1.00 0.190 ug/L 10/20/17 03:39 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 10/20/17 03:39 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 10/20/17 03:39 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 10/20/17 03:39 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 10/20/17 03:39 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 10/20/17 03:39 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 10/20/17 03:39 1Ethylbenzene<0.190
10.0 1.28 ug/L 10/20/17 03:39 12-Hexanone <1.28
10.0 1.50 ug/L 10/20/17 03:39 1Iodomethane<1.50
5.00 1.00 ug/L 10/20/17 03:39 1Methylene Chloride <1.00
10.0 0.810 ug/L 10/20/17 03:39 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 10/20/17 03:39 1Styrene<0.280
1.00 0.150 ug/L 10/20/17 03:39 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 10/20/17 03:39 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 10/20/17 03:39 1Tetrachloroethene<0.140
1.00 0.170 ug/L 10/20/17 03:39 1Toluene<0.170
5.00 0.460 ug/L 10/20/17 03:39 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 10/20/17 03:39 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 10/20/17 03:39 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 10/20/17 03:39 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 10/20/17 03:39 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 10/20/17 03:39 1Trichloroethene<0.200
1.00 0.210 ug/L 10/20/17 03:39 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 10/20/17 03:39 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 10/20/17 03:39 1Vinyl acetate <1.71
1.00 0.180 ug/L 10/20/17 03:39 1Vinyl chloride <0.180
3.00 0.580 ug/L 10/20/17 03:39 1Xylenes, Total <0.580
TestAmerica Nashville
Page 18 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-7Client Sample ID: MW-07R
Matrix: WaterDate Collected: 10/17/17 12:14
Date Received: 10/19/17 09:40
4-Bromofluorobenzene (Surr)98 70-130 10/20/17 03:39 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Dibromofluoromethane (Surr)92 10/20/17 03:39 170-130
1,2-Dichloroethane-d4 (Surr)105 10/20/17 03:39 170-130
Toluene-d8 (Surr)103 10/20/17 03:39 170-130
Method: 6010D - Metals (ICP)
RL MDL
Silver <0.00300 0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 19:57 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.0100 0.00860 mg/L 10/20/17 10:03 10/23/17 19:57 1Arsenic<0.00860
0.0100 0.00500 mg/L 10/20/17 10:03 10/23/17 19:57 1Barium0.138
0.00100 0.000500 mg/L 10/20/17 10:03 10/23/17 19:57 1Cadmium0.000500 J
0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 19:57 1Chromium0.00660
0.00500 0.00200 mg/L 10/20/17 10:03 10/23/17 19:57 1Lead0.00580
0.0100 0.00500 mg/L 10/20/17 10:03 10/23/17 19:57 1Selenium<0.00500
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 10/20/17 14:48 10/23/17 20:36 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2.00 0.100 ug/L 10/20/17 14:48 10/23/17 20:36 1Beryllium0.412 J
2.00 0.100 ug/L 10/20/17 14:48 10/23/17 20:36 1Cobalt2.00
2.00 0.800 ug/L 10/20/17 14:48 10/23/17 20:36 1Thallium<0.800
2.00 0.700 ug/L 10/20/17 14:48 10/23/17 20:36 1Vanadium9.16
25.0 5.20 ug/L 10/20/17 14:48 10/23/17 20:36 1Zinc22.8 J
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 10/24/17 01:38 10/24/17 18:40 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
TestAmerica Nashville
Page 19 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-8Client Sample ID: MW-08
Matrix: WaterDate Collected: 10/17/17 11:17
Date Received: 10/19/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/20/17 04:05 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
10.0 0.500 ug/L 10/20/17 04:05 1Acrylonitrile<0.500
1.00 0.200 ug/L 10/20/17 04:05 1Benzene<0.200
1.00 0.150 ug/L 10/20/17 04:05 1Bromochloromethane<0.150
1.00 0.170 ug/L 10/20/17 04:05 1Bromodichloromethane<0.170
1.00 0.290 ug/L 10/20/17 04:05 1Bromoform<0.290
1.00 0.350 ug/L 10/20/17 04:05 1Bromomethane<0.350
50.0 2.64 ug/L 10/20/17 04:05 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 10/20/17 04:05 1Carbon disulfide <0.220
1.00 0.180 ug/L 10/20/17 04:05 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 10/20/17 04:05 1Chlorobenzene<0.180
1.00 0.360 ug/L 10/20/17 04:05 1Chloroethane<0.360
1.00 0.230 ug/L 10/20/17 04:05 1Chloroform<0.230
1.00 0.360 ug/L 10/20/17 04:05 1Chloromethane<0.360
1.00 0.210 ug/L 10/20/17 04:05 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 10/20/17 04:05 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 10/20/17 04:05 1Dibromochloromethane<0.250
10.0 0.940 ug/L 10/20/17 04:05 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 10/20/17 04:05 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 10/20/17 04:05 1Dibromomethane<0.450
1.00 0.190 ug/L 10/20/17 04:05 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 10/20/17 04:05 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 10/20/17 04:05 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 10/20/17 04:05 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 10/20/17 04:05 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 10/20/17 04:05 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 10/20/17 04:05 1Ethylbenzene<0.190
10.0 1.28 ug/L 10/20/17 04:05 12-Hexanone <1.28
10.0 1.50 ug/L 10/20/17 04:05 1Iodomethane<1.50
5.00 1.00 ug/L 10/20/17 04:05 1Methylene Chloride <1.00
10.0 0.810 ug/L 10/20/17 04:05 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 10/20/17 04:05 1Styrene<0.280
1.00 0.150 ug/L 10/20/17 04:05 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 10/20/17 04:05 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 10/20/17 04:05 1Tetrachloroethene<0.140
1.00 0.170 ug/L 10/20/17 04:05 1Toluene<0.170
5.00 0.460 ug/L 10/20/17 04:05 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 10/20/17 04:05 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 10/20/17 04:05 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 10/20/17 04:05 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 10/20/17 04:05 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 10/20/17 04:05 1Trichloroethene<0.200
1.00 0.210 ug/L 10/20/17 04:05 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 10/20/17 04:05 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 10/20/17 04:05 1Vinyl acetate <1.71
1.00 0.180 ug/L 10/20/17 04:05 1Vinyl chloride <0.180
3.00 0.580 ug/L 10/20/17 04:05 1Xylenes, Total <0.580
TestAmerica Nashville
Page 20 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-8Client Sample ID: MW-08
Matrix: WaterDate Collected: 10/17/17 11:17
Date Received: 10/19/17 09:40
4-Bromofluorobenzene (Surr)99 70-130 10/20/17 04:05 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Dibromofluoromethane (Surr)104 10/20/17 04:05 170-130
1,2-Dichloroethane-d4 (Surr)106 10/20/17 04:05 170-130
Toluene-d8 (Surr)105 10/20/17 04:05 170-130
Method: 6010D - Metals (ICP)
RL MDL
Silver <0.00300 0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 20:13 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.0100 0.00860 mg/L 10/20/17 10:03 10/23/17 20:13 1Arsenic<0.00860
0.0100 0.00500 mg/L 10/20/17 10:03 10/23/17 20:13 1Barium0.0278
0.00100 0.000500 mg/L 10/20/17 10:03 10/23/17 20:13 1Cadmium<0.000500
0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 20:13 1Chromium<0.00300
0.00500 0.00200 mg/L 10/20/17 10:03 10/23/17 20:13 1Lead0.00400 J
0.0100 0.00500 mg/L 10/20/17 10:03 10/23/17 20:13 1Selenium<0.00500
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 10/20/17 14:48 10/23/17 20:48 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2.00 0.100 ug/L 10/20/17 14:48 10/23/17 20:48 1Beryllium<0.100
2.00 0.100 ug/L 10/20/17 14:48 10/23/17 20:48 1Cobalt0.300 J
2.00 0.800 ug/L 10/20/17 14:48 10/23/17 20:48 1Thallium<0.800
2.00 0.700 ug/L 10/20/17 14:48 10/23/17 20:48 1Vanadium3.09
25.0 5.20 ug/L 10/20/17 14:48 10/23/17 20:48 1Zinc<5.20
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 10/20/17 11:00 10/23/17 14:14 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
TestAmerica Nashville
Page 21 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-9Client Sample ID: MW-09
Matrix: WaterDate Collected: 10/18/17 10:56
Date Received: 10/19/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/20/17 04:30 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
10.0 0.500 ug/L 10/20/17 04:30 1Acrylonitrile<0.500
1.00 0.200 ug/L 10/20/17 04:30 1Benzene<0.200
1.00 0.150 ug/L 10/20/17 04:30 1Bromochloromethane<0.150
1.00 0.170 ug/L 10/20/17 04:30 1Bromodichloromethane<0.170
1.00 0.290 ug/L 10/20/17 04:30 1Bromoform<0.290
1.00 0.350 ug/L 10/20/17 04:30 1Bromomethane<0.350
50.0 2.64 ug/L 10/20/17 04:30 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 10/20/17 04:30 1Carbon disulfide <0.220
1.00 0.180 ug/L 10/20/17 04:30 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 10/20/17 04:30 1Chlorobenzene<0.180
1.00 0.360 ug/L 10/20/17 04:30 1Chloroethane<0.360
1.00 0.230 ug/L 10/20/17 04:30 1Chloroform<0.230
1.00 0.360 ug/L 10/20/17 04:30 1Chloromethane<0.360
1.00 0.210 ug/L 10/20/17 04:30 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 10/20/17 04:30 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 10/20/17 04:30 1Dibromochloromethane<0.250
10.0 0.940 ug/L 10/20/17 04:30 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 10/20/17 04:30 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 10/20/17 04:30 1Dibromomethane<0.450
1.00 0.190 ug/L 10/20/17 04:30 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 10/20/17 04:30 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 10/20/17 04:30 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 10/20/17 04:30 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 10/20/17 04:30 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 10/20/17 04:30 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 10/20/17 04:30 1Ethylbenzene<0.190
10.0 1.28 ug/L 10/20/17 04:30 12-Hexanone <1.28
10.0 1.50 ug/L 10/20/17 04:30 1Iodomethane<1.50
5.00 1.00 ug/L 10/20/17 04:30 1Methylene Chloride <1.00
10.0 0.810 ug/L 10/20/17 04:30 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 10/20/17 04:30 1Styrene<0.280
1.00 0.150 ug/L 10/20/17 04:30 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 10/20/17 04:30 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 10/20/17 04:30 1Tetrachloroethene<0.140
1.00 0.170 ug/L 10/20/17 04:30 1Toluene<0.170
5.00 0.460 ug/L 10/20/17 04:30 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 10/20/17 04:30 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 10/20/17 04:30 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 10/20/17 04:30 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 10/20/17 04:30 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 10/20/17 04:30 1Trichloroethene<0.200
1.00 0.210 ug/L 10/20/17 04:30 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 10/20/17 04:30 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 10/20/17 04:30 1Vinyl acetate <1.71
1.00 0.180 ug/L 10/20/17 04:30 1Vinyl chloride <0.180
3.00 0.580 ug/L 10/20/17 04:30 1Xylenes, Total <0.580
TestAmerica Nashville
Page 22 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-9Client Sample ID: MW-09
Matrix: WaterDate Collected: 10/18/17 10:56
Date Received: 10/19/17 09:40
4-Bromofluorobenzene (Surr)98 70-130 10/20/17 04:30 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Dibromofluoromethane (Surr)107 10/20/17 04:30 170-130
1,2-Dichloroethane-d4 (Surr)109 10/20/17 04:30 170-130
Toluene-d8 (Surr)103 10/20/17 04:30 170-130
Method: 6010D - Metals (ICP)
RL MDL
Silver <0.00300 0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 20:18 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.0100 0.00860 mg/L 10/20/17 10:03 10/23/17 20:18 1Arsenic<0.00860
0.0100 0.00500 mg/L 10/20/17 10:03 10/23/17 20:18 1Barium0.162
0.00100 0.000500 mg/L 10/20/17 10:03 10/23/17 20:18 1Cadmium<0.000500
0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 20:18 1Chromium<0.00300
0.00500 0.00200 mg/L 10/20/17 10:03 10/23/17 20:18 1Lead0.00410 J
0.0100 0.00500 mg/L 10/20/17 10:03 10/23/17 20:18 1Selenium<0.00500
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 10/20/17 14:48 10/23/17 20:45 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2.00 0.100 ug/L 10/20/17 14:48 10/23/17 20:45 1Beryllium<0.100
2.00 0.100 ug/L 10/20/17 14:48 10/23/17 20:45 1Cobalt0.914 J
2.00 0.800 ug/L 10/20/17 14:48 10/23/17 20:45 1Thallium<0.800
2.00 0.700 ug/L 10/20/17 14:48 10/23/17 20:45 1Vanadium1.75 J
25.0 5.20 ug/L 10/20/17 14:48 10/23/17 20:45 1Zinc<5.20
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 10/20/17 11:00 10/23/17 14:23 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
TestAmerica Nashville
Page 23 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-10Client Sample ID: Trip Blank
Matrix: WaterDate Collected: 10/17/17 01:01
Date Received: 10/19/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/20/17 01:57 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
10.0 0.500 ug/L 10/20/17 01:57 1Acrylonitrile<0.500
1.00 0.200 ug/L 10/20/17 01:57 1Benzene<0.200
1.00 0.150 ug/L 10/20/17 01:57 1Bromochloromethane<0.150
1.00 0.170 ug/L 10/20/17 01:57 1Bromodichloromethane<0.170
1.00 0.290 ug/L 10/20/17 01:57 1Bromoform<0.290
1.00 0.350 ug/L 10/20/17 01:57 1Bromomethane<0.350
50.0 2.64 ug/L 10/20/17 01:57 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 10/20/17 01:57 1Carbon disulfide <0.220
1.00 0.180 ug/L 10/20/17 01:57 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 10/20/17 01:57 1Chlorobenzene<0.180
1.00 0.360 ug/L 10/20/17 01:57 1Chloroethane<0.360
1.00 0.230 ug/L 10/20/17 01:57 1Chloroform<0.230
1.00 0.360 ug/L 10/20/17 01:57 1Chloromethane<0.360
1.00 0.210 ug/L 10/20/17 01:57 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 10/20/17 01:57 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 10/20/17 01:57 1Dibromochloromethane<0.250
10.0 0.940 ug/L 10/20/17 01:57 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 10/20/17 01:57 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 10/20/17 01:57 1Dibromomethane<0.450
1.00 0.190 ug/L 10/20/17 01:57 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 10/20/17 01:57 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 10/20/17 01:57 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 10/20/17 01:57 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 10/20/17 01:57 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 10/20/17 01:57 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 10/20/17 01:57 1Ethylbenzene<0.190
10.0 1.28 ug/L 10/20/17 01:57 12-Hexanone <1.28
10.0 1.50 ug/L 10/20/17 01:57 1Iodomethane<1.50
5.00 1.00 ug/L 10/20/17 01:57 1Methylene Chloride <1.00
10.0 0.810 ug/L 10/20/17 01:57 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 10/20/17 01:57 1Styrene<0.280
1.00 0.150 ug/L 10/20/17 01:57 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 10/20/17 01:57 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 10/20/17 01:57 1Tetrachloroethene<0.140
1.00 0.170 ug/L 10/20/17 01:57 1Toluene<0.170
5.00 0.460 ug/L 10/20/17 01:57 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 10/20/17 01:57 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 10/20/17 01:57 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 10/20/17 01:57 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 10/20/17 01:57 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 10/20/17 01:57 1Trichloroethene<0.200
1.00 0.210 ug/L 10/20/17 01:57 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 10/20/17 01:57 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 10/20/17 01:57 1Vinyl acetate <1.71
1.00 0.180 ug/L 10/20/17 01:57 1Vinyl chloride <0.180
3.00 0.580 ug/L 10/20/17 01:57 1Xylenes, Total <0.580
TestAmerica Nashville
Page 24 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Client Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-139036-10Client Sample ID: Trip Blank
Matrix: WaterDate Collected: 10/17/17 01:01
Date Received: 10/19/17 09:40
4-Bromofluorobenzene (Surr)101 70-130 10/20/17 01:57 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Dibromofluoromethane (Surr)105 10/20/17 01:57 170-130
1,2-Dichloroethane-d4 (Surr)104 10/20/17 01:57 170-130
Toluene-d8 (Surr)104 10/20/17 01:57 170-130
TestAmerica Nashville
Page 25 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS)
Client Sample ID: Method BlankLab Sample ID: MB 490-469030/8
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469030
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/19/17 13:34 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
<0.500 0.50010.0 ug/L 10/19/17 13:34 1Acrylonitrile
<0.200 0.2001.00 ug/L 10/19/17 13:34 1Benzene
<0.150 0.1501.00 ug/L 10/19/17 13:34 1Bromochloromethane
<0.170 0.1701.00 ug/L 10/19/17 13:34 1Bromodichloromethane
<0.290 0.2901.00 ug/L 10/19/17 13:34 1Bromoform
<0.350 0.3501.00 ug/L 10/19/17 13:34 1Bromomethane
<2.64 2.6450.0 ug/L 10/19/17 13:34 12-Butanone (MEK)
<0.220 0.2201.00 ug/L 10/19/17 13:34 1Carbon disulfide
<0.180 0.1801.00 ug/L 10/19/17 13:34 1Carbon tetrachloride
<0.180 0.1801.00 ug/L 10/19/17 13:34 1Chlorobenzene
<0.360 0.3601.00 ug/L 10/19/17 13:34 1Chloroethane
<0.230 0.2301.00 ug/L 10/19/17 13:34 1Chloroform
<0.360 0.3601.00 ug/L 10/19/17 13:34 1Chloromethane
<0.210 0.2101.00 ug/L 10/19/17 13:34 1cis-1,2-Dichloroethene
<0.170 0.1701.00 ug/L 10/19/17 13:34 1cis-1,3-Dichloropropene
<0.250 0.2501.00 ug/L 10/19/17 13:34 1Dibromochloromethane
<0.940 0.94010.0 ug/L 10/19/17 13:34 11,2-Dibromo-3-Chloropropane
<0.210 0.2101.00 ug/L 10/19/17 13:34 11,2-Dibromoethane (EDB)
<0.450 0.4501.00 ug/L 10/19/17 13:34 1Dibromomethane
<0.190 0.1901.00 ug/L 10/19/17 13:34 11,2-Dichlorobenzene
<0.170 0.1701.00 ug/L 10/19/17 13:34 11,4-Dichlorobenzene
<0.240 0.2401.00 ug/L 10/19/17 13:34 11,1-Dichloroethane
<0.200 0.2001.00 ug/L 10/19/17 13:34 11,2-Dichloroethane
<0.250 0.2501.00 ug/L 10/19/17 13:34 11,1-Dichloroethene
<0.250 0.2501.00 ug/L 10/19/17 13:34 11,2-Dichloropropane
<0.190 0.1901.00 ug/L 10/19/17 13:34 1Ethylbenzene
<1.28 1.2810.0 ug/L 10/19/17 13:34 12-Hexanone
<1.50 1.5010.0 ug/L 10/19/17 13:34 1Iodomethane
<1.00 1.005.00 ug/L 10/19/17 13:34 1Methylene Chloride
<0.810 0.81010.0 ug/L 10/19/17 13:34 14-Methyl-2-pentanone (MIBK)
<0.280 0.2801.00 ug/L 10/19/17 13:34 1Styrene
<0.150 0.1501.00 ug/L 10/19/17 13:34 11,1,1,2-Tetrachloroethane
<0.190 0.1901.00 ug/L 10/19/17 13:34 11,1,2,2-Tetrachloroethane
<0.140 0.1401.00 ug/L 10/19/17 13:34 1Tetrachloroethene
<0.170 0.1701.00 ug/L 10/19/17 13:34 1Toluene
<0.460 0.4605.00 ug/L 10/19/17 13:34 1trans-1,4-Dichloro-2-butene
<0.230 0.2301.00 ug/L 10/19/17 13:34 1trans-1,2-Dichloroethene
<0.170 0.1701.00 ug/L 10/19/17 13:34 1trans-1,3-Dichloropropene
<0.190 0.1901.00 ug/L 10/19/17 13:34 11,1,1-Trichloroethane
<0.190 0.1901.00 ug/L 10/19/17 13:34 11,1,2-Trichloroethane
<0.200 0.2001.00 ug/L 10/19/17 13:34 1Trichloroethene
<0.210 0.2101.00 ug/L 10/19/17 13:34 1Trichlorofluoromethane
<0.230 0.2301.00 ug/L 10/19/17 13:34 11,2,3-Trichloropropane
<1.71 1.7110.0 ug/L 10/19/17 13:34 1Vinyl acetate
<0.180 0.1801.00 ug/L 10/19/17 13:34 1Vinyl chloride
<0.580 0.5803.00 ug/L 10/19/17 13:34 1Xylenes, Total
TestAmerica Nashville
Page 26 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 490-469030/8
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469030
4-Bromofluorobenzene (Surr)102 70-130 10/19/17 13:34 1
MB MB
Surrogate Dil FacPrepared AnalyzedQualifier Limits%Recovery
101 10/19/17 13:34 1Dibromofluoromethane (Surr)70-130
101 10/19/17 13:34 11,2-Dichloroethane-d4 (Surr)70-130
104 10/19/17 13:34 1Toluene-d8 (Surr)70-130
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469030/3
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469030
Acetone 100 113.8 ug/L 114 39-150
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Acrylonitrile 200 183.5 ug/L 92 63-135
Benzene 20.0 18.34 ug/L 92 70-130
Bromochloromethane 20.0 17.91 ug/L 90 70-130
Bromodichloromethane 20.0 19.30 ug/L 96 70-130
Bromoform 20.0 19.30 ug/L 97 70-137
Bromomethane 20.0 15.82 ug/L 79 53-150
2-Butanone (MEK)100 92.64 ug/L 93 55-143
Carbon disulfide 20.0 17.32 ug/L 87 64-135
Carbon tetrachloride 20.0 19.79 ug/L 99 70-147
Chlorobenzene 20.0 19.26 ug/L 96 70-130
Chloroethane 20.0 19.42 ug/L 97 60-138
Chloroform 20.0 18.83 ug/L 94 70-130
Chloromethane 20.0 21.63 ug/L 108 33-150
cis-1,2-Dichloroethene 20.0 18.76 ug/L 94 70-130
cis-1,3-Dichloropropene 20.0 19.05 ug/L 95 70-133
Dibromochloromethane 20.0 20.21 ug/L 101 70-133
1,2-Dibromo-3-Chloropropane 20.0 16.55 ug/L 83 45-138
1,2-Dibromoethane (EDB)20.0 19.33 ug/L 97 70-130
Dibromomethane 20.0 17.18 ug/L 86 70-130
1,2-Dichlorobenzene 20.0 19.30 ug/L 96 70-130
1,4-Dichlorobenzene 20.0 19.35 ug/L 97 70-130
1,1-Dichloroethane 20.0 18.97 ug/L 95 70-130
1,2-Dichloroethane 20.0 19.49 ug/L 97 70-130
1,1-Dichloroethene 20.0 19.13 ug/L 96 70-132
1,2-Dichloropropane 20.0 18.06 ug/L 90 70-130
Ethylbenzene 20.0 18.84 ug/L 94 70-130
2-Hexanone 100 95.05 ug/L 95 54-142
Iodomethane 20.0 12.13 ug/L 61 40-150
Methylene Chloride 20.0 18.97 ug/L 95 70-130
4-Methyl-2-pentanone (MIBK)100 99.74 ug/L 100 60-137
Styrene 20.0 17.61 ug/L 88 70-130
1,1,1,2-Tetrachloroethane 20.0 19.83 ug/L 99 70-130
1,1,2,2-Tetrachloroethane 20.0 19.56 ug/L 98 69-131
Tetrachloroethene 20.0 20.08 ug/L 100 70-130
Toluene 20.0 19.22 ug/L 96 70-130
trans-1,4-Dichloro-2-butene 20.0 19.04 ug/L 95 41-150
trans-1,2-Dichloroethene 20.0 18.70 ug/L 94 70-130
TestAmerica Nashville
Page 27 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469030/3
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469030
trans-1,3-Dichloropropene 20.0 17.98 ug/L 90 63-142
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
1,1,1-Trichloroethane 20.0 19.55 ug/L 98 70-135
1,1,2-Trichloroethane 20.0 18.63 ug/L 93 70-130
Trichloroethene 20.0 19.32 ug/L 97 70-130
Trichlorofluoromethane 20.0 19.41 ug/L 97 59-150
1,2,3-Trichloropropane 20.0 21.02 ug/L 105 70-131
Vinyl acetate 40.0 28.16 ug/L 70 54-146
Vinyl chloride 20.0 20.11 ug/L 101 57-137
Xylenes, Total 40.0 35.59 ug/L 89 70-132
4-Bromofluorobenzene (Surr)70 -130
Surrogate
104
LCS LCS
Qualifier Limits%Recovery
98Dibromofluoromethane (Surr)70 -130
1011,2-Dichloroethane-d4 (Surr)70 -130
104Toluene-d8 (Surr)70 -130
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-469030/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469030
Acetone 100 114.8 ug/L 115 39-150 1 23
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Acrylonitrile 200 189.1 ug/L 95 63-135 3 16
Benzene 20.0 18.82 ug/L 94 70-130 3 12
Bromochloromethane 20.0 17.98 ug/L 90 70-130 0 16
Bromodichloromethane 20.0 19.22 ug/L 96 70-130 0 14
Bromoform 20.0 20.29 ug/L 101 70-137 5 14
Bromomethane 20.0 14.71 ug/L 74 53-150 7 19
2-Butanone (MEK)100 97.91 ug/L 98 55-143 6 19
Carbon disulfide 20.0 17.98 ug/L 90 64-135 4 16
Carbon tetrachloride 20.0 20.06 ug/L 100 70-147 1 16
Chlorobenzene 20.0 19.40 ug/L 97 70-130 1 12
Chloroethane 20.0 19.74 ug/L 99 60-138 2 15
Chloroform 20.0 19.59 ug/L 98 70-130 4 14
Chloromethane 20.0 22.32 ug/L 112 33-150 3 20
cis-1,2-Dichloroethene 20.0 20.08 ug/L 100 70-130 7 15
cis-1,3-Dichloropropene 20.0 19.20 ug/L 96 70-133 1 15
Dibromochloromethane 20.0 20.60 ug/L 103 70-133 2 13
1,2-Dibromo-3-Chloropropane 20.0 16.03 ug/L 80 45-138 3 19
1,2-Dibromoethane (EDB)20.0 19.30 ug/L 97 70-130 0 13
Dibromomethane 20.0 17.09 ug/L 85 70-130 1 14
1,2-Dichlorobenzene 20.0 18.71 ug/L 94 70-130 3 12
1,4-Dichlorobenzene 20.0 19.14 ug/L 96 70-130 1 12
1,1-Dichloroethane 20.0 19.40 ug/L 97 70-130 2 17
1,2-Dichloroethane 20.0 20.98 ug/L 105 70-130 7 13
1,1-Dichloroethene 20.0 19.68 ug/L 98 70-132 3 20
1,2-Dichloropropane 20.0 18.68 ug/L 93 70-130 3 15
Ethylbenzene 20.0 18.89 ug/L 94 70-130 0 12
TestAmerica Nashville
Page 28 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-469030/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469030
2-Hexanone 100 99.97 ug/L 100 54-142 5 17
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Iodomethane 20.0 12.30 ug/L 62 40-150 1 20
Methylene Chloride 20.0 19.69 ug/L 98 70-130 4 15
4-Methyl-2-pentanone (MIBK)100 102.7 ug/L 103 60-137 3 21
Styrene 20.0 17.94 ug/L 90 70-130 2 12
1,1,1,2-Tetrachloroethane 20.0 19.89 ug/L 99 70-130 0 13
1,1,2,2-Tetrachloroethane 20.0 18.73 ug/L 94 69-131 4 15
Tetrachloroethene 20.0 20.65 ug/L 103 70-130 3 17
Toluene 20.0 19.55 ug/L 98 70-130 2 13
trans-1,4-Dichloro-2-butene 20.0 19.07 ug/L 95 41-150 0 20
trans-1,2-Dichloroethene 20.0 19.49 ug/L 97 70-130 4 15
trans-1,3-Dichloropropene 20.0 17.84 ug/L 89 63-142 1 13
1,1,1-Trichloroethane 20.0 19.47 ug/L 97 70-135 0 15
1,1,2-Trichloroethane 20.0 19.55 ug/L 98 70-130 5 13
Trichloroethene 20.0 19.24 ug/L 96 70-130 0 14
Trichlorofluoromethane 20.0 20.01 ug/L 100 59-150 3 22
1,2,3-Trichloropropane 20.0 21.12 ug/L 106 70-131 0 14
Vinyl acetate 40.0 28.81 ug/L 72 54-146 2 20
Vinyl chloride 20.0 20.62 ug/L 103 57-137 3 15
Xylenes, Total 40.0 36.19 ug/L 90 70-132 2 11
4-Bromofluorobenzene (Surr)70 -130
Surrogate
102
LCSD LCSD
Qualifier Limits%Recovery
99Dibromofluoromethane (Surr)70 -130
1031,2-Dichloroethane-d4 (Surr)70 -130
102Toluene-d8 (Surr)70 -130
Client Sample ID: Matrix SpikeLab Sample ID: 490-139005-A-7 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469030
Acetone <26.6 1000 1120 ug/L 112 39-150
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Acrylonitrile <5.00 2000 1935 ug/L 97 50-135
Benzene <2.00 200 202.9 ug/L 101 55-147
Bromochloromethane <1.50 200 188.2 ug/L 94 59-132
Bromodichloromethane <1.70 200 206.4 ug/L 103 70-140
Bromoform <2.90 200 202.4 ug/L 101 53-150
Bromomethane <3.50 200 170.2 ug/L 85 30-150
2-Butanone (MEK)<26.4 1000 1035 ug/L 103 50-143
Carbon disulfide <2.20 200 216.7 ug/L 108 35-150
Carbon tetrachloride <1.80 200 236.4 ug/L 118 56-150
Chlorobenzene <1.80 200 210.6 ug/L 105 70-130
Chloroethane <3.60 200 229.8 ug/L 115 58-141
Chloroform <2.30 200 210.7 ug/L 105 66-138
Chloromethane <3.60 200 243.2 ug/L 122 10-150
cis-1,2-Dichloroethene 9.46 J 200 225.1 ug/L 108 68-131
cis-1,3-Dichloropropene <1.70 200 197.5 ug/L 99 70-133
TestAmerica Nashville
Page 29 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Matrix SpikeLab Sample ID: 490-139005-A-7 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469030
Dibromochloromethane <2.50 200 211.0 ug/L 106 66-140
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
1,2-Dibromo-3-Chloropropane <9.40 200 183.6 ug/L 92 38-138
1,2-Dibromoethane (EDB)<2.10 200 196.6 ug/L 98 65-137
Dibromomethane <4.50 200 182.2 ug/L 91 70-130
1,2-Dichlorobenzene <1.90 200 201.0 ug/L 100 70-130
1,4-Dichlorobenzene <1.70 200 208.3 ug/L 104 70-130
1,1-Dichloroethane <2.40 200 216.0 ug/L 108 61-139
1,2-Dichloroethane <2.00 200 224.7 ug/L 112 64-136
1,1-Dichloroethene <2.50 200 230.4 ug/L 115 54-150
1,2-Dichloropropane <2.50 200 194.5 ug/L 97 67-130
Ethylbenzene <1.90 200 203.6 ug/L 102 65-139
2-Hexanone 78.9 J 1000 1098 ug/L 102 44-150
Iodomethane <15.0 200 117.4 ug/L 59 34-150
Methylene Chloride <10.0 200 206.6 ug/L 103 64-130
4-Methyl-2-pentanone (MIBK)<8.10 1000 1080 ug/L 108 50-140
Styrene <2.80 200 189.9 ug/L 95 70-130
1,1,1,2-Tetrachloroethane <1.50 200 211.3 ug/L 106 70-131
1,1,2,2-Tetrachloroethane <1.90 200 200.9 ug/L 100 56-145
Tetrachloroethene <1.40 200 234.8 ug/L 117 57-138
Toluene <1.70 200 214.9 ug/L 107 64-136
trans-1,4-Dichloro-2-butene <4.60 200 199.4 ug/L 100 39-150
trans-1,2-Dichloroethene <2.30 200 215.5 ug/L 108 59-143
trans-1,3-Dichloropropene <1.70 200 188.5 ug/L 94 63-142
1,1,1-Trichloroethane <1.90 200 220.3 ug/L 110 68-144
1,1,2-Trichloroethane <1.90 200 200.2 ug/L 100 70-130
Trichloroethene <2.00 200 217.7 ug/L 109 63-135
Trichlorofluoromethane <2.10 200 245.7 ug/L 123 44-150
1,2,3-Trichloropropane <2.30 200 214.2 ug/L 107 65-131
Vinyl acetate <17.1 400 342.9 ug/L 86 43-146
Vinyl chloride 138 200 345.6 ug/L 104 57-150
Xylenes, Total <5.80 400 389.5 ug/L 97 69-132
4-Bromofluorobenzene (Surr)70 -130
Surrogate
100
MS MS
Qualifier Limits%Recovery
101Dibromofluoromethane (Surr)70 -130
1061,2-Dichloroethane-d4 (Surr)70 -130
104Toluene-d8 (Surr)70 -130
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-139005-A-7 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469030
Acetone <26.6 1000 1125 ug/L 113 39-150 0 28
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Acrylonitrile <5.00 2000 1966 ug/L 98 50-135 2 23
Benzene <2.00 200 205.1 ug/L 103 55-147 1 22
Bromochloromethane <1.50 200 196.5 ug/L 98 59-132 4 21
Bromodichloromethane <1.70 200 203.8 ug/L 102 70-140 1 196
TestAmerica Nashville
Page 30 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-139005-A-7 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469030
Bromoform <2.90 200 211.8 ug/L 106 53-150 5 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Bromomethane <3.50 200 184.0 ug/L 92 30-150 8 44
2-Butanone (MEK)<26.4 1000 981.4 ug/L 98 50-143 5 28
Carbon disulfide <2.20 200 200.5 ug/L 100 35-150 8 34
Carbon tetrachloride <1.80 200 237.4 ug/L 119 56-150 0 18
Chlorobenzene <1.80 200 210.1 ug/L 105 70-130 0 15
Chloroethane <3.60 200 227.5 ug/L 114 58-141 1 31
Chloroform <2.30 200 213.2 ug/L 107 66-138 1 21
Chloromethane <3.60 200 248.5 ug/L 124 10-150 2 43
cis-1,2-Dichloroethene 9.46 J 200 225.5 ug/L 108 68-131 0 21
cis-1,3-Dichloropropene <1.70 200 198.9 ug/L 99 70-133 1 19
Dibromochloromethane <2.50 200 220.7 ug/L 110 66-140 4 19
1,2-Dibromo-3-Chloropropane <9.40 200 198.3 ug/L 99 38-138 8 26
1,2-Dibromoethane (EDB)<2.10 200 196.0 ug/L 98 65-137 0 21
Dibromomethane <4.50 200 180.1 ug/L 90 70-130 1 19
1,2-Dichlorobenzene <1.90 200 203.2 ug/L 102 70-130 1 15
1,4-Dichlorobenzene <1.70 200 203.5 ug/L 102 70-130 2 14
1,1-Dichloroethane <2.40 200 212.1 ug/L 106 61-139 2 23
1,2-Dichloroethane <2.00 200 217.4 ug/L 109 64-136 3 22
1,1-Dichloroethene <2.50 200 227.2 ug/L 114 54-150 1 24
1,2-Dichloropropane <2.50 200 198.3 ug/L 99 67-130 2 19
Ethylbenzene <1.90 200 205.4 ug/L 103 65-139 1 18
2-Hexanone 78.9 J 1000 1132 ug/L 105 44-150 3 21
Iodomethane <15.0 200 125.5 ug/L 63 34-150 7 37
Methylene Chloride <10.0 200 203.5 ug/L 102 64-130 2 22
4-Methyl-2-pentanone (MIBK)<8.10 1000 1121 ug/L 112 50-140 4 24
Styrene <2.80 200 190.8 ug/L 95 70-130 0 16
1,1,1,2-Tetrachloroethane <1.50 200 216.2 ug/L 108 70-131 2 16
1,1,2,2-Tetrachloroethane <1.90 200 205.7 ug/L 103 56-145 2 19
Tetrachloroethene <1.40 200 233.2 ug/L 117 57-138 1 17
Toluene <1.70 200 214.6 ug/L 107 64-136 0 18
trans-1,4-Dichloro-2-butene <4.60 200 202.8 ug/L 101 39-150 2 28
trans-1,2-Dichloroethene <2.30 200 214.2 ug/L 107 59-143 1 25
trans-1,3-Dichloropropene <1.70 200 189.4 ug/L 95 63-142 0 18
1,1,1-Trichloroethane <1.90 200 211.7 ug/L 106 68-144 4 17
1,1,2-Trichloroethane <1.90 200 204.0 ug/L 102 70-130 2 18
Trichloroethene <2.00 200 215.3 ug/L 108 63-135 1 17
Trichlorofluoromethane <2.10 200 238.3 ug/L 119 44-150 3 32
1,2,3-Trichloropropane <2.30 200 219.7 ug/L 110 65-131 3 19
Vinyl acetate <17.1 400 366.2 ug/L 92 43-146 7 20
Vinyl chloride 138 200 341.3 ug/L 102 57-150 1 37
Xylenes, Total <5.80 400 388.2 ug/L 97 69-132 0 17
4-Bromofluorobenzene (Surr)70 -130
Surrogate
100
MSD MSD
Qualifier Limits%Recovery
98Dibromofluoromethane (Surr)70 -130
1051,2-Dichloroethane-d4 (Surr)70 -130
104Toluene-d8 (Surr)70 -130
TestAmerica Nashville
Page 31 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Client Sample ID: Method BlankLab Sample ID: MB 490-469223/6
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469223
RL MDL
Acetone <2.66 25.0 2.66 ug/L 10/20/17 01:06 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
<0.500 0.50010.0 ug/L 10/20/17 01:06 1Acrylonitrile
<0.200 0.2001.00 ug/L 10/20/17 01:06 1Benzene
<0.150 0.1501.00 ug/L 10/20/17 01:06 1Bromochloromethane
<0.170 0.1701.00 ug/L 10/20/17 01:06 1Bromodichloromethane
<0.290 0.2901.00 ug/L 10/20/17 01:06 1Bromoform
<0.350 0.3501.00 ug/L 10/20/17 01:06 1Bromomethane
<2.64 2.6450.0 ug/L 10/20/17 01:06 12-Butanone (MEK)
<0.220 0.2201.00 ug/L 10/20/17 01:06 1Carbon disulfide
<0.180 0.1801.00 ug/L 10/20/17 01:06 1Carbon tetrachloride
<0.180 0.1801.00 ug/L 10/20/17 01:06 1Chlorobenzene
<0.360 0.3601.00 ug/L 10/20/17 01:06 1Chloroethane
<0.230 0.2301.00 ug/L 10/20/17 01:06 1Chloroform
<0.360 0.3601.00 ug/L 10/20/17 01:06 1Chloromethane
<0.210 0.2101.00 ug/L 10/20/17 01:06 1cis-1,2-Dichloroethene
<0.170 0.1701.00 ug/L 10/20/17 01:06 1cis-1,3-Dichloropropene
<0.250 0.2501.00 ug/L 10/20/17 01:06 1Dibromochloromethane
<0.940 0.94010.0 ug/L 10/20/17 01:06 11,2-Dibromo-3-Chloropropane
<0.210 0.2101.00 ug/L 10/20/17 01:06 11,2-Dibromoethane (EDB)
<0.450 0.4501.00 ug/L 10/20/17 01:06 1Dibromomethane
<0.190 0.1901.00 ug/L 10/20/17 01:06 11,2-Dichlorobenzene
<0.170 0.1701.00 ug/L 10/20/17 01:06 11,4-Dichlorobenzene
<0.240 0.2401.00 ug/L 10/20/17 01:06 11,1-Dichloroethane
<0.200 0.2001.00 ug/L 10/20/17 01:06 11,2-Dichloroethane
<0.250 0.2501.00 ug/L 10/20/17 01:06 11,1-Dichloroethene
<0.250 0.2501.00 ug/L 10/20/17 01:06 11,2-Dichloropropane
<0.190 0.1901.00 ug/L 10/20/17 01:06 1Ethylbenzene
<1.28 1.2810.0 ug/L 10/20/17 01:06 12-Hexanone
<1.50 1.5010.0 ug/L 10/20/17 01:06 1Iodomethane
<1.00 1.005.00 ug/L 10/20/17 01:06 1Methylene Chloride
<0.810 0.81010.0 ug/L 10/20/17 01:06 14-Methyl-2-pentanone (MIBK)
<0.280 0.2801.00 ug/L 10/20/17 01:06 1Styrene
<0.150 0.1501.00 ug/L 10/20/17 01:06 11,1,1,2-Tetrachloroethane
<0.190 0.1901.00 ug/L 10/20/17 01:06 11,1,2,2-Tetrachloroethane
<0.140 0.1401.00 ug/L 10/20/17 01:06 1Tetrachloroethene
<0.170 0.1701.00 ug/L 10/20/17 01:06 1Toluene
<0.460 0.4605.00 ug/L 10/20/17 01:06 1trans-1,4-Dichloro-2-butene
<0.230 0.2301.00 ug/L 10/20/17 01:06 1trans-1,2-Dichloroethene
<0.170 0.1701.00 ug/L 10/20/17 01:06 1trans-1,3-Dichloropropene
<0.190 0.1901.00 ug/L 10/20/17 01:06 11,1,1-Trichloroethane
<0.190 0.1901.00 ug/L 10/20/17 01:06 11,1,2-Trichloroethane
<0.200 0.2001.00 ug/L 10/20/17 01:06 1Trichloroethene
<0.210 0.2101.00 ug/L 10/20/17 01:06 1Trichlorofluoromethane
<0.230 0.2301.00 ug/L 10/20/17 01:06 11,2,3-Trichloropropane
<1.71 1.7110.0 ug/L 10/20/17 01:06 1Vinyl acetate
<0.180 0.1801.00 ug/L 10/20/17 01:06 1Vinyl chloride
<0.580 0.5803.00 ug/L 10/20/17 01:06 1Xylenes, Total
4-Bromofluorobenzene (Surr)101 70-130 10/20/17 01:06 1
MB MB
Surrogate Dil FacPrepared AnalyzedQualifier Limits%Recovery
TestAmerica Nashville
Page 32 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 490-469223/6
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469223
Dibromofluoromethane (Surr)103 70-130 10/20/17 01:06 1
MB MB
Surrogate Dil FacPrepared AnalyzedQualifier Limits%Recovery
105 10/20/17 01:06 11,2-Dichloroethane-d4 (Surr)70-130
101 10/20/17 01:06 1Toluene-d8 (Surr)70-130
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469223/3
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469223
Acetone 100 108.5 ug/L 108 39-150
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Acrylonitrile 200 183.7 ug/L 92 63-135
Benzene 20.0 19.04 ug/L 95 70-130
Bromochloromethane 20.0 18.68 ug/L 93 70-130
Bromodichloromethane 20.0 19.79 ug/L 99 70-130
Bromoform 20.0 18.77 ug/L 94 70-137
Bromomethane 20.0 17.59 ug/L 88 53-150
2-Butanone (MEK)100 93.67 ug/L 94 55-143
Carbon disulfide 20.0 18.06 ug/L 90 64-135
Carbon tetrachloride 20.0 21.35 ug/L 107 70-147
Chlorobenzene 20.0 19.66 ug/L 98 70-130
Chloroethane 20.0 20.55 ug/L 103 60-138
Chloroform 20.0 21.35 ug/L 107 70-130
Chloromethane 20.0 22.39 ug/L 112 33-150
cis-1,2-Dichloroethene 20.0 20.46 ug/L 102 70-130
cis-1,3-Dichloropropene 20.0 18.79 ug/L 94 70-133
Dibromochloromethane 20.0 20.31 ug/L 102 70-133
1,2-Dibromo-3-Chloropropane 20.0 16.20 ug/L 81 45-138
1,2-Dibromoethane (EDB)20.0 18.65 ug/L 93 70-130
Dibromomethane 20.0 16.81 ug/L 84 70-130
1,2-Dichlorobenzene 20.0 19.30 ug/L 96 70-130
1,4-Dichlorobenzene 20.0 19.76 ug/L 99 70-130
1,1-Dichloroethane 20.0 19.95 ug/L 100 70-130
1,2-Dichloroethane 20.0 20.33 ug/L 102 70-130
1,1-Dichloroethene 20.0 20.72 ug/L 104 70-132
1,2-Dichloropropane 20.0 18.91 ug/L 95 70-130
Ethylbenzene 20.0 18.91 ug/L 95 70-130
2-Hexanone 100 88.85 ug/L 89 54-142
Iodomethane 20.0 12.71 ug/L 64 40-150
Methylene Chloride 20.0 19.57 ug/L 98 70-130
4-Methyl-2-pentanone (MIBK)100 96.38 ug/L 96 60-137
Styrene 20.0 17.79 ug/L 89 70-130
1,1,1,2-Tetrachloroethane 20.0 20.36 ug/L 102 70-130
1,1,2,2-Tetrachloroethane 20.0 17.82 ug/L 89 69-131
Tetrachloroethene 20.0 20.65 ug/L 103 70-130
Toluene 20.0 19.86 ug/L 99 70-130
trans-1,4-Dichloro-2-butene 20.0 19.32 ug/L 97 41-150
trans-1,2-Dichloroethene 20.0 19.57 ug/L 98 70-130
trans-1,3-Dichloropropene 20.0 17.91 ug/L 90 63-142
TestAmerica Nashville
Page 33 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469223/3
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469223
1,1,1-Trichloroethane 20.0 20.38 ug/L 102 70-135
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
1,1,2-Trichloroethane 20.0 19.02 ug/L 95 70-130
Trichloroethene 20.0 20.26 ug/L 101 70-130
Trichlorofluoromethane 20.0 21.34 ug/L 107 59-150
1,2,3-Trichloropropane 20.0 21.09 ug/L 105 70-131
Vinyl acetate 40.0 30.48 ug/L 76 54-146
Vinyl chloride 20.0 21.21 ug/L 106 57-137
Xylenes, Total 40.0 36.18 ug/L 90 70-132
4-Bromofluorobenzene (Surr)70 -130
Surrogate
101
LCS LCS
Qualifier Limits%Recovery
99Dibromofluoromethane (Surr)70 -130
1051,2-Dichloroethane-d4 (Surr)70 -130
103Toluene-d8 (Surr)70 -130
Client Sample ID: Matrix SpikeLab Sample ID: 490-139030-A-5 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469223
Acetone <532 20000 21190 ug/L 106 39-150
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Acrylonitrile <100 40000 37920 ug/L 95 50-135
Benzene 13100 4000 16710 ug/L 91 55-147
Bromochloromethane <30.0 4000 3738 ug/L 93 59-132
Bromodichloromethane <34.0 4000 4075 ug/L 102 70-140
Bromoform <58.0 4000 3882 ug/L 97 53-150
Bromomethane <70.0 4000 3407 ug/L 85 30-150
2-Butanone (MEK)<528 20000 17750 ug/L 89 50-143
Carbon disulfide <44.0 4000 3896 ug/L 97 35-150
Carbon tetrachloride <36.0 4000 4676 ug/L 117 56-150
Chlorobenzene <36.0 4000 4125 ug/L 103 70-130
Chloroethane <72.0 4000 4461 ug/L 112 58-141
Chloroform <46.0 4000 4112 ug/L 103 66-138
Chloromethane <72.0 4000 4753 ug/L 119 10-150
cis-1,2-Dichloroethene <42.0 4000 4354 ug/L 109 68-131
cis-1,3-Dichloropropene <34.0 4000 3887 ug/L 97 70-133
Dibromochloromethane <50.0 4000 4169 ug/L 104 66-140
1,2-Dibromo-3-Chloropropane <188 4000 3328 ug/L 83 38-138
1,2-Dibromoethane (EDB)241 4000 4090 ug/L 96 65-137
Dibromomethane <90.0 4000 3406 ug/L 85 70-130
1,2-Dichlorobenzene <38.0 4000 3921 ug/L 98 70-130
1,4-Dichlorobenzene <34.0 4000 4000 ug/L 100 70-130
1,1-Dichloroethane <48.0 4000 4212 ug/L 105 61-139
1,2-Dichloroethane <40.0 4000 4763 ug/L 119 64-136
1,1-Dichloroethene <50.0 4000 4533 ug/L 113 54-150
1,2-Dichloropropane <50.0 4000 3952 ug/L 99 67-130
Ethylbenzene 3500 4000 6641 ug/L 79 65-139
2-Hexanone <256 20000 18450 ug/L 92 44-150
TestAmerica Nashville
Page 34 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Matrix SpikeLab Sample ID: 490-139030-A-5 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469223
Iodomethane <300 4000 3093 ug/L 77 34-150
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Methylene Chloride <200 4000 4206 ug/L 105 64-130
4-Methyl-2-pentanone (MIBK)<162 20000 19630 ug/L 98 50-140
Styrene <56.0 4000 3937 ug/L 98 70-130
1,1,1,2-Tetrachloroethane <30.0 4000 4124 ug/L 103 70-131
1,1,2,2-Tetrachloroethane <38.0 4000 3782 ug/L 95 56-145
Tetrachloroethene <28.0 4000 4511 ug/L 113 57-138
Toluene 35200 4000 36470 4 ug/L 32 64-136
trans-1,4-Dichloro-2-butene <92.0 4000 3456 ug/L 86 39-150
trans-1,2-Dichloroethene <46.0 4000 4266 ug/L 107 59-143
trans-1,3-Dichloropropene <34.0 4000 3684 ug/L 92 63-142
1,1,1-Trichloroethane <38.0 4000 4353 ug/L 109 68-144
1,1,2-Trichloroethane <38.0 4000 3889 ug/L 97 70-130
Trichloroethene <40.0 4000 4382 ug/L 110 63-135
Trichlorofluoromethane <42.0 4000 4763 ug/L 119 44-150
1,2,3-Trichloropropane <46.0 4000 4270 ug/L 107 65-131
Vinyl acetate <342 8000 7070 ug/L 88 43-146
Vinyl chloride <36.0 4000 4663 ug/L 117 57-150
Xylenes, Total 19500 F1 8000 22430 F1 ug/L 37 69-132
4-Bromofluorobenzene (Surr)70 -130
Surrogate
101
MS MS
Qualifier Limits%Recovery
95Dibromofluoromethane (Surr)70 -130
1021,2-Dichloroethane-d4 (Surr)70 -130
104Toluene-d8 (Surr)70 -130
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-139030-A-5 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469223
Acetone <532 20000 22240 ug/L 111 39-150 5 28
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Acrylonitrile <100 40000 38300 ug/L 96 50-135 1 23
Benzene 13100 4000 16360 ug/L 82 55-147 2 22
Bromochloromethane <30.0 4000 3850 ug/L 96 59-132 3 21
Bromodichloromethane <34.0 4000 4027 ug/L 101 70-140 1 196
Bromoform <58.0 4000 4058 ug/L 101 53-150 4 20
Bromomethane <70.0 4000 3583 ug/L 90 30-150 5 44
2-Butanone (MEK)<528 20000 17710 ug/L 89 50-143 0 28
Carbon disulfide <44.0 4000 3859 ug/L 96 35-150 1 34
Carbon tetrachloride <36.0 4000 4521 ug/L 113 56-150 3 18
Chlorobenzene <36.0 4000 4111 ug/L 103 70-130 0 15
Chloroethane <72.0 4000 4441 ug/L 111 58-141 0 31
Chloroform <46.0 4000 4091 ug/L 102 66-138 1 21
Chloromethane <72.0 4000 4661 ug/L 117 10-150 2 43
cis-1,2-Dichloroethene <42.0 4000 4100 ug/L 102 68-131 6 21
cis-1,3-Dichloropropene <34.0 4000 3881 ug/L 97 70-133 0 19
Dibromochloromethane <50.0 4000 4288 ug/L 107 66-140 3 19
TestAmerica Nashville
Page 35 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-139030-A-5 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 469223
1,2-Dibromo-3-Chloropropane <188 4000 3569 ug/L 89 38-138 7 26
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
1,2-Dibromoethane (EDB)241 4000 4119 ug/L 97 65-137 1 21
Dibromomethane <90.0 4000 3264 ug/L 82 70-130 4 19
1,2-Dichlorobenzene <38.0 4000 4018 ug/L 100 70-130 2 15
1,4-Dichlorobenzene <34.0 4000 4038 ug/L 101 70-130 1 14
1,1-Dichloroethane <48.0 4000 4174 ug/L 104 61-139 1 23
1,2-Dichloroethane <40.0 4000 4770 ug/L 119 64-136 0 22
1,1-Dichloroethene <50.0 4000 4491 ug/L 112 54-150 1 24
1,2-Dichloropropane <50.0 4000 3922 ug/L 98 67-130 1 19
Ethylbenzene 3500 4000 6613 ug/L 78 65-139 0 18
2-Hexanone <256 20000 19310 ug/L 97 44-150 5 21
Iodomethane <300 4000 2779 ug/L 69 34-150 11 37
Methylene Chloride <200 4000 4091 ug/L 102 64-130 3 22
4-Methyl-2-pentanone (MIBK)<162 20000 20120 ug/L 101 50-140 2 24
Styrene <56.0 4000 3937 ug/L 98 70-130 0 16
1,1,1,2-Tetrachloroethane <30.0 4000 4096 ug/L 102 70-131 1 16
1,1,2,2-Tetrachloroethane <38.0 4000 3846 ug/L 96 56-145 2 19
Tetrachloroethene <28.0 4000 4468 ug/L 112 57-138 1 17
Toluene 35200 4000 35910 4 ug/L 18 64-136 2 18
trans-1,4-Dichloro-2-butene <92.0 4000 3519 ug/L 88 39-150 2 28
trans-1,2-Dichloroethene <46.0 4000 4190 ug/L 105 59-143 2 25
trans-1,3-Dichloropropene <34.0 4000 3611 ug/L 90 63-142 2 18
1,1,1-Trichloroethane <38.0 4000 4013 ug/L 100 68-144 8 17
1,1,2-Trichloroethane <38.0 4000 3972 ug/L 99 70-130 2 18
Trichloroethene <40.0 4000 4350 ug/L 109 63-135 1 17
Trichlorofluoromethane <42.0 4000 4739 ug/L 118 44-150 1 32
1,2,3-Trichloropropane <46.0 4000 4307 ug/L 108 65-131 1 19
Vinyl acetate <342 8000 7292 ug/L 91 43-146 3 20
Vinyl chloride <36.0 4000 4752 ug/L 119 57-150 2 37
Xylenes, Total 19500 F1 8000 22210 F1 ug/L 34 69-132 1 17
4-Bromofluorobenzene (Surr)70 -130
Surrogate
100
MSD MSD
Qualifier Limits%Recovery
89Dibromofluoromethane (Surr)70 -130
1031,2-Dichloroethane-d4 (Surr)70 -130
104Toluene-d8 (Surr)70 -130
Method: 6010D - Metals (ICP)
Client Sample ID: Method BlankLab Sample ID: MB 490-469385/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470149 Prep Batch: 469385
RL MDL
Silver <0.00300 0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 18:49 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
<0.00860 0.008600.0100 mg/L 10/20/17 10:03 10/23/17 18:49 1Arsenic
<0.00500 0.005000.0100 mg/L 10/20/17 10:03 10/23/17 18:49 1Barium
<0.000500 0.0005000.00100 mg/L 10/20/17 10:03 10/23/17 18:49 1Cadmium
TestAmerica Nashville
Page 36 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 6010D - Metals (ICP) (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 490-469385/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470149 Prep Batch: 469385
RL MDL
Chromium <0.00300 0.00500 0.00300 mg/L 10/20/17 10:03 10/23/17 18:49 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
<0.00200 0.002000.00500 mg/L 10/20/17 10:03 10/23/17 18:49 1Lead
<0.00500 0.005000.0100 mg/L 10/20/17 10:03 10/23/17 18:49 1Selenium
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469385/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470149 Prep Batch: 469385
Silver 0.100 0.09780 mg/L 98 80-120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Arsenic 0.100 0.09010 mg/L 90 80-120
Barium 0.100 0.09420 mg/L 94 80-120
Cadmium 0.100 0.09360 mg/L 94 80-120
Chromium 0.100 0.09890 mg/L 99 80-120
Lead 0.100 0.09480 mg/L 95 80-120
Selenium 0.100 0.09100 mg/L 91 80-120
Client Sample ID: MW-06RLab Sample ID: 490-139036-6 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470149 Prep Batch: 469385
Silver <0.00300 0.100 0.09800 mg/L 98 75-125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Arsenic <0.00860 0.100 0.09440 mg/L 94 75-125
Barium 0.0251 0.100 0.1204 mg/L 95 75-125
Cadmium <0.000500 0.100 0.09350 mg/L 94 75-125
Chromium <0.00300 0.100 0.1004 mg/L 100 75-125
Lead <0.00200 0.100 0.09570 mg/L 96 75-125
Selenium <0.00500 0.100 0.08670 mg/L 87 75-125
Client Sample ID: MW-06RLab Sample ID: 490-139036-6 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470149 Prep Batch: 469385
Silver <0.00300 0.100 0.09840 mg/L 98 75-125 0 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Arsenic <0.00860 0.100 0.09330 mg/L 93 75-125 1 20
Barium 0.0251 0.100 0.1196 mg/L 95 75-125 1 20
Cadmium <0.000500 0.100 0.09290 mg/L 93 75-125 1 20
Chromium <0.00300 0.100 0.1009 mg/L 101 75-125 0 20
Lead <0.00200 0.100 0.09500 mg/L 95 75-125 1 20
Selenium <0.00500 0.100 0.08830 mg/L 88 75-125 2 20
TestAmerica Nashville
Page 37 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 6020B - Metals (ICP/MS)
Client Sample ID: Method BlankLab Sample ID: MB 490-469508/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470216 Prep Batch: 469508
RL MDL
Antimony <0.800 2.00 0.800 ug/L 10/20/17 14:48 10/23/17 19:44 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
<0.100 0.1002.00 ug/L 10/20/17 14:48 10/23/17 19:44 1Cobalt
<0.800 0.8002.00 ug/L 10/20/17 14:48 10/23/17 19:44 1Thallium
<0.700 0.7002.00 ug/L 10/20/17 14:48 10/23/17 19:44 1Vanadium
<5.20 5.2025.0 ug/L 10/20/17 14:48 10/23/17 19:44 1Zinc
Client Sample ID: Method BlankLab Sample ID: MB 490-469508/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470349 Prep Batch: 469508
RL MDL
Beryllium <0.100 2.00 0.100 ug/L 10/20/17 14:48 10/24/17 10:56 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469508/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470216 Prep Batch: 469508
Antimony 100 98.66 ug/L 99 80-120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Cobalt 100 94.95 ug/L 95 80-120
Thallium 100 99.18 ug/L 99 80-120
Vanadium 100 95.67 ug/L 96 80-120
Zinc 100 96.11 ug/L 96 80-120
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469508/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470349 Prep Batch: 469508
Beryllium 100 94.49 ug/L 94 80-120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: Matrix SpikeLab Sample ID: 490-139054-A-3-B MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470216 Prep Batch: 469508
Antimony 9.72 100 107.9 ug/L 98 75-125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Beryllium <0.100 100 87.38 ug/L 87 75-125
Cobalt 0.172 J 100 96.70 ug/L 97 75-125
Thallium <0.800 100 100.2 ug/L 100 75-125
Vanadium <0.700 100 99.82 ug/L 100 75-125
Zinc 223 100 311.3 ug/L 89 75-125
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-139054-A-3-C MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470216 Prep Batch: 469508
Antimony 9.72 100 108.3 ug/L 99 75-125 0 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
TestAmerica Nashville
Page 38 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 6020B - Metals (ICP/MS) (Continued)
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-139054-A-3-C MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470216 Prep Batch: 469508
Beryllium <0.100 100 84.77 ug/L 85 75-125 3 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Cobalt 0.172 J 100 93.11 ug/L 93 75-125 4 20
Thallium <0.800 100 97.92 ug/L 98 75-125 2 20
Vanadium <0.700 100 97.90 ug/L 98 75-125 2 20
Zinc 223 100 300.8 ug/L 78 75-125 3 20
Method: 7470A - Mercury (CVAA)
Client Sample ID: Method BlankLab Sample ID: MB 490-469289/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470077 Prep Batch: 469289
RL MDL
Mercury <0.100 0.200 0.100 ug/L 10/20/17 11:00 10/23/17 14:08 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-469289/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470077 Prep Batch: 469289
Mercury 1.00 0.9166 ug/L 92 80-120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: MW-08Lab Sample ID: 490-139036-8 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470077 Prep Batch: 469289
Mercury <0.100 1.00 1.021 ug/L 102 75-125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Client Sample ID: MW-08Lab Sample ID: 490-139036-8 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470077 Prep Batch: 469289
Mercury <0.100 1.00 0.9797 ug/L 98 75-125 4 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Client Sample ID: Method BlankLab Sample ID: MB 490-470121/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470713 Prep Batch: 470121
RL MDL
Mercury <0.100 0.200 0.100 ug/L 10/23/17 22:14 10/24/17 16:01 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-470121/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470713 Prep Batch: 470121
Mercury 1.00 1.146 ug/L 115 80-120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
TestAmerica Nashville
Page 39 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Sample Results
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 7470A - Mercury (CVAA) (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-470121/3-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470713 Prep Batch: 470121
Mercury 1.00 1.090 ug/L 109 80-120 5 20
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Client Sample ID: Matrix SpikeLab Sample ID: 490-139187-G-1-B MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470713 Prep Batch: 470121
Mercury <0.100 1.00 0.8628 ug/L 86 75-125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-139187-G-1-C MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470713 Prep Batch: 470121
Mercury <0.100 1.00 0.8608 ug/L 86 75-125 0 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Client Sample ID: Method BlankLab Sample ID: MB 490-470126/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470713 Prep Batch: 470126
RL MDL
Mercury <0.100 0.200 0.100 ug/L 10/24/17 01:38 10/24/17 18:05 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-470126/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470713 Prep Batch: 470126
Mercury 1.00 1.150 ug/L 115 80-120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: MW-03Lab Sample ID: 490-139036-3 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470713 Prep Batch: 470126
Mercury <0.100 F1 1.00 0.6506 F1 ug/L 65 75-125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Client Sample ID: MW-03Lab Sample ID: 490-139036-3 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 470713 Prep Batch: 470126
Mercury <0.100 F1 1.00 0.6572 F1 ug/L 66 75-125 1 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
TestAmerica Nashville
Page 40 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Association Summary
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
GC/MS VOA
Analysis Batch: 469030
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 8260B490-139036-1 MW-01 Total/NA
Water 8260B490-139036-2 MW-02 Total/NA
Water 8260B490-139036-3 MW-03 Total/NA
Water 8260BMB 490-469030/8 Method Blank Total/NA
Water 8260BLCS 490-469030/3 Lab Control Sample Total/NA
Water 8260BLCSD 490-469030/4 Lab Control Sample Dup Total/NA
Water 8260B490-139005-A-7 MS Matrix Spike Total/NA
Water 8260B490-139005-A-7 MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 469223
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 8260B490-139036-4 MW-04 Total/NA
Water 8260B490-139036-5 MW-05 Total/NA
Water 8260B490-139036-6 MW-06R Total/NA
Water 8260B490-139036-7 MW-07R Total/NA
Water 8260B490-139036-8 MW-08 Total/NA
Water 8260B490-139036-9 MW-09 Total/NA
Water 8260B490-139036-10 Trip Blank Total/NA
Water 8260BMB 490-469223/6 Method Blank Total/NA
Water 8260BLCS 490-469223/3 Lab Control Sample Total/NA
Water 8260B490-139030-A-5 MS Matrix Spike Total/NA
Water 8260B490-139030-A-5 MSD Matrix Spike Duplicate Total/NA
Metals
Prep Batch: 469289
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A490-139036-8 MW-08 Total/NA
Water 7470A490-139036-9 MW-09 Total/NA
Water 7470AMB 490-469289/1-A Method Blank Total/NA
Water 7470ALCS 490-469289/2-A Lab Control Sample Total/NA
Water 7470A490-139036-8 MS MW-08 Total/NA
Water 7470A490-139036-8 MSD MW-08 Total/NA
Prep Batch: 469385
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3010A490-139036-1 MW-01 Total/NA
Water 3010A490-139036-2 MW-02 Total/NA
Water 3010A490-139036-3 MW-03 Total/NA
Water 3010A490-139036-4 MW-04 Total/NA
Water 3010A490-139036-5 MW-05 Total/NA
Water 3010A490-139036-6 MW-06R Total/NA
Water 3010A490-139036-7 MW-07R Total/NA
Water 3010A490-139036-8 MW-08 Total/NA
Water 3010A490-139036-9 MW-09 Total/NA
Water 3010AMB 490-469385/1-A Method Blank Total/NA
Water 3010ALCS 490-469385/2-A Lab Control Sample Total/NA
Water 3010A490-139036-6 MS MW-06R Total/NA
Water 3010A490-139036-6 MSD MW-06R Total/NA
TestAmerica Nashville
Page 41 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Association Summary
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Metals (Continued)
Prep Batch: 469508
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3010A490-139036-1 MW-01 Total/NA
Water 3010A490-139036-2 MW-02 Total/NA
Water 3010A490-139036-3 MW-03 Total/NA
Water 3010A490-139036-4 MW-04 Total/NA
Water 3010A490-139036-5 MW-05 Total/NA
Water 3010A490-139036-6 MW-06R Total/NA
Water 3010A490-139036-7 MW-07R Total/NA
Water 3010A490-139036-8 MW-08 Total/NA
Water 3010A490-139036-9 MW-09 Total/NA
Water 3010AMB 490-469508/1-A Method Blank Total/NA
Water 3010ALCS 490-469508/2-A Lab Control Sample Total/NA
Water 3010A490-139054-A-3-B MS Matrix Spike Total/NA
Water 3010A490-139054-A-3-C MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 470077
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A 469289490-139036-8 MW-08 Total/NA
Water 7470A 469289490-139036-9 MW-09 Total/NA
Water 7470A 469289MB 490-469289/1-A Method Blank Total/NA
Water 7470A 469289LCS 490-469289/2-A Lab Control Sample Total/NA
Water 7470A 469289490-139036-8 MS MW-08 Total/NA
Water 7470A 469289490-139036-8 MSD MW-08 Total/NA
Prep Batch: 470121
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A490-139036-1 MW-01 Total/NA
Water 7470A490-139036-2 MW-02 Total/NA
Water 7470AMB 490-470121/1-A Method Blank Total/NA
Water 7470ALCS 490-470121/2-A Lab Control Sample Total/NA
Water 7470ALCSD 490-470121/3-A Lab Control Sample Dup Total/NA
Water 7470A490-139187-G-1-B MS Matrix Spike Total/NA
Water 7470A490-139187-G-1-C MSD Matrix Spike Duplicate Total/NA
Prep Batch: 470126
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A490-139036-3 MW-03 Total/NA
Water 7470A490-139036-4 MW-04 Total/NA
Water 7470A490-139036-5 MW-05 Total/NA
Water 7470A490-139036-6 MW-06R Total/NA
Water 7470A490-139036-7 MW-07R Total/NA
Water 7470AMB 490-470126/1-A Method Blank Total/NA
Water 7470ALCS 490-470126/2-A Lab Control Sample Total/NA
Water 7470A490-139036-3 MS MW-03 Total/NA
Water 7470A490-139036-3 MSD MW-03 Total/NA
Analysis Batch: 470149
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6010D 469385490-139036-1 MW-01 Total/NA
Water 6010D 469385490-139036-2 MW-02 Total/NA
Water 6010D 469385490-139036-3 MW-03 Total/NA
Water 6010D 469385490-139036-4 MW-04 Total/NA
TestAmerica Nashville
Page 42 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Association Summary
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Metals (Continued)
Analysis Batch: 470149 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6010D 469385490-139036-5 MW-05 Total/NA
Water 6010D 469385490-139036-6 MW-06R Total/NA
Water 6010D 469385490-139036-7 MW-07R Total/NA
Water 6010D 469385490-139036-8 MW-08 Total/NA
Water 6010D 469385490-139036-9 MW-09 Total/NA
Water 6010D 469385MB 490-469385/1-A Method Blank Total/NA
Water 6010D 469385LCS 490-469385/2-A Lab Control Sample Total/NA
Water 6010D 469385490-139036-6 MS MW-06R Total/NA
Water 6010D 469385490-139036-6 MSD MW-06R Total/NA
Analysis Batch: 470216
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020B 469508490-139036-1 MW-01 Total/NA
Water 6020B 469508490-139036-2 MW-02 Total/NA
Water 6020B 469508490-139036-3 MW-03 Total/NA
Water 6020B 469508490-139036-4 MW-04 Total/NA
Water 6020B 469508490-139036-5 MW-05 Total/NA
Water 6020B 469508490-139036-6 MW-06R Total/NA
Water 6020B 469508490-139036-7 MW-07R Total/NA
Water 6020B 469508490-139036-8 MW-08 Total/NA
Water 6020B 469508490-139036-9 MW-09 Total/NA
Water 6020B 469508MB 490-469508/1-A Method Blank Total/NA
Water 6020B 469508LCS 490-469508/2-A Lab Control Sample Total/NA
Water 6020B 469508490-139054-A-3-B MS Matrix Spike Total/NA
Water 6020B 469508490-139054-A-3-C MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 470349
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020B 469508MB 490-469508/1-A Method Blank Total/NA
Water 6020B 469508LCS 490-469508/2-A Lab Control Sample Total/NA
Analysis Batch: 470713
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A 470121490-139036-1 MW-01 Total/NA
Water 7470A 470121490-139036-2 MW-02 Total/NA
Water 7470A 470126490-139036-3 MW-03 Total/NA
Water 7470A 470126490-139036-5 MW-05 Total/NA
Water 7470A 470126490-139036-6 MW-06R Total/NA
Water 7470A 470126490-139036-7 MW-07R Total/NA
Water 7470A 470121MB 490-470121/1-A Method Blank Total/NA
Water 7470A 470126MB 490-470126/1-A Method Blank Total/NA
Water 7470A 470121LCS 490-470121/2-A Lab Control Sample Total/NA
Water 7470A 470126LCS 490-470126/2-A Lab Control Sample Total/NA
Water 7470A 470121LCSD 490-470121/3-A Lab Control Sample Dup Total/NA
Water 7470A 470126490-139036-3 MS MW-03 Total/NA
Water 7470A 470126490-139036-3 MSD MW-03 Total/NA
Water 7470A 470121490-139187-G-1-B MS Matrix Spike Total/NA
Water 7470A 470121490-139187-G-1-C MSD Matrix Spike Duplicate Total/NA
TestAmerica Nashville
Page 43 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
QC Association Summary
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Metals (Continued)
Analysis Batch: 470800
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A 470126490-139036-4 MW-04 Total/NA
TestAmerica Nashville
Page 44 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Lab Chronicle
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-139036-1
Project/Site: Madison Co Operating Landfill
Client Sample ID: MW-01 Lab Sample ID: 490-139036-1
Matrix: WaterDate Collected: 10/17/17 09:51
Date Received: 10/19/17 09:40
Analysis 8260B S1S10/19/17 20:251 TAL NSH469030
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3010A 469385 10/20/17 10:03 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 470149 10/23/17 20:59 LCS TAL NSHTotal/NA
Prep 3010A 469508 10/20/17 14:48 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 470216 10/23/17 20:33 BLG TAL NSHTotal/NA
Prep 7470A 470121 10/23/17 22:14 RDF TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 470713 10/24/17 17:13 RDF TAL NSHTotal/NA
Client Sample ID: MW-02 Lab Sample ID: 490-139036-2
Matrix: WaterDate Collected: 10/17/17 14:10
Date Received: 10/19/17 09:40
Analysis 8260B S1S10/19/17 20:501 TAL NSH469030
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3010A 469385 10/20/17 10:03 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 470149 10/23/17 21:15 LCS TAL NSHTotal/NA
Prep 3010A 469508 10/20/17 14:48 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 470216 10/23/17 20:24 BLG TAL NSHTotal/NA
Prep 7470A 470121 10/23/17 22:14 RDF TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 470713 10/24/17 17:16 RDF TAL NSHTotal/NA
Client Sample ID: MW-03 Lab Sample ID: 490-139036-3
Matrix: WaterDate Collected: 10/18/17 12:10
Date Received: 10/19/17 09:40
Analysis 8260B S1S10/19/17 21:161 TAL NSH469030
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3010A 469385 10/20/17 10:03 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 470149 10/23/17 19:41 LCS TAL NSHTotal/NA
Prep 3010A 469508 10/20/17 14:48 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 470216 10/23/17 20:21 BLG TAL NSHTotal/NA
Prep 7470A 470126 10/24/17 01:38 RDF TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 470713 10/24/17 18:11 RDF TAL NSHTotal/NA
Client Sample ID: MW-04 Lab Sample ID: 490-139036-4
Matrix: WaterDate Collected: 10/18/17 12:53
Date Received: 10/19/17 09:40
Analysis 8260B RP10/20/17 02:231 TAL NSH469223
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3010A 469385 10/20/17 10:03 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 470149 10/23/17 19:46 LCS TAL NSHTotal/NA
TestAmerica Nashville
Page 45 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Lab Chronicle
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-139036-1
Project/Site: Madison Co Operating Landfill
Client Sample ID: MW-04 Lab Sample ID: 490-139036-4
Matrix: WaterDate Collected: 10/18/17 12:53
Date Received: 10/19/17 09:40
Prep 3010A AAA10/20/17 14:48 TAL NSH469508
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 50 mL 50 mL
Analysis 6020B 1 470216 10/23/17 20:18 BLG TAL NSHTotal/NA
Prep 7470A 470126 10/24/17 01:38 RDF TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 5 470800 10/25/17 21:24 BLG TAL NSHTotal/NA
Client Sample ID: MW-05 Lab Sample ID: 490-139036-5
Matrix: WaterDate Collected: 10/18/17 09:51
Date Received: 10/19/17 09:40
Analysis 8260B RP10/20/17 02:481 TAL NSH469223
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3010A 469385 10/20/17 10:03 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 470149 10/23/17 19:51 LCS TAL NSHTotal/NA
Prep 3010A 469508 10/20/17 14:48 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 470216 10/23/17 20:15 BLG TAL NSHTotal/NA
Prep 7470A 470126 10/24/17 01:38 RDF TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 470713 10/24/17 18:28 RDF TAL NSHTotal/NA
Client Sample ID: MW-06R Lab Sample ID: 490-139036-6
Matrix: WaterDate Collected: 10/17/17 15:07
Date Received: 10/19/17 09:40
Analysis 8260B RP10/20/17 03:141 TAL NSH469223
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3010A 469385 10/20/17 10:03 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 470149 10/23/17 19:15 LCS TAL NSHTotal/NA
Prep 3010A 469508 10/20/17 14:48 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 470216 10/23/17 20:12 BLG TAL NSHTotal/NA
Prep 7470A 470126 10/24/17 01:38 RDF TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 470713 10/24/17 18:31 RDF TAL NSHTotal/NA
Client Sample ID: MW-07R Lab Sample ID: 490-139036-7
Matrix: WaterDate Collected: 10/17/17 12:14
Date Received: 10/19/17 09:40
Analysis 8260B RP10/20/17 03:391 TAL NSH469223
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3010A 469385 10/20/17 10:03 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 470149 10/23/17 19:57 LCS TAL NSHTotal/NA
Prep 3010A 469508 10/20/17 14:48 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 470216 10/23/17 20:36 BLG TAL NSHTotal/NA
Prep 7470A 470126 10/24/17 01:38 RDF TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 470713 10/24/17 18:40 RDF TAL NSHTotal/NA
TestAmerica Nashville
Page 46 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Lab Chronicle
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-139036-1
Project/Site: Madison Co Operating Landfill
Client Sample ID: MW-08 Lab Sample ID: 490-139036-8
Matrix: WaterDate Collected: 10/17/17 11:17
Date Received: 10/19/17 09:40
Analysis 8260B RP10/20/17 04:051 TAL NSH469223
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3010A 469385 10/20/17 10:03 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 470149 10/23/17 20:13 LCS TAL NSHTotal/NA
Prep 3010A 469508 10/20/17 14:48 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 470216 10/23/17 20:48 BLG TAL NSHTotal/NA
Prep 7470A 469289 10/20/17 11:00 BLG TAL NSHTotal/NA 30.0 mL 30.0 mL
Analysis 7470A 1 470077 10/23/17 14:14 RDF TAL NSHTotal/NA
Client Sample ID: MW-09 Lab Sample ID: 490-139036-9
Matrix: WaterDate Collected: 10/18/17 10:56
Date Received: 10/19/17 09:40
Analysis 8260B RP10/20/17 04:301 TAL NSH469223
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3010A 469385 10/20/17 10:03 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 470149 10/23/17 20:18 LCS TAL NSHTotal/NA
Prep 3010A 469508 10/20/17 14:48 AAA TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 470216 10/23/17 20:45 BLG TAL NSHTotal/NA
Prep 7470A 469289 10/20/17 11:00 BLG TAL NSHTotal/NA 30.0 mL 30.0 mL
Analysis 7470A 1 470077 10/23/17 14:23 RDF TAL NSHTotal/NA
Client Sample ID: Trip Blank Lab Sample ID: 490-139036-10
Matrix: WaterDate Collected: 10/17/17 01:01
Date Received: 10/19/17 09:40
Analysis 8260B RP10/20/17 01:571 TAL NSH469223
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Laboratory References:
TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL [phone]
TestAmerica Nashville
Page 47 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Method Summary
TestAmerica Job ID: 490-139036-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method Method Description LaboratoryProtocol
SW8468260BVolatile Organic Compounds (GC/MS)TAL NSH
SW8466010DMetals (ICP)TAL NSH
SW8466020BMetals (ICP/MS)TAL NSH
SW8467470AMercury (CVAA)TAL NSH
Protocol References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL [phone]
TestAmerica Nashville
Page 48 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Accreditation/Certification Summary
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-139036-1
Project/Site: Madison Co Operating Landfill
Laboratory: TestAmerica Nashville
The accreditations/certifications listed below are applicable to this report.
Authority Program EPA Region Identification Number Expiration Date
North Carolina (WW/SW)3874State Program 12-31-17
TestAmerica Nashville
Page 49 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Page 50 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Page 51 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13
Login Sample Receipt Checklist
Client: Anchor QEA of North Carolina PLLC Job Number: 490-139036-1
SDG Number:
Login Number: 139036
Question Answer Comment
Creator: Huskey, Adam
List Source: TestAmerica Nashville
List Number: 1
TrueRadioactivity wasn't checked or is </= background as measured by a survey
meter.
TrueThe cooler's custody seal, if present, is intact.
N/ASample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
TrueContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
TestAmerica Nashville
Page 52 of 52 10/31/2017
1
2
3
4
5
6
7
8
9
10
11
12
13