5803_MadisonCountyMSWLF_WQMR_20170630

July 2017
Madison County Operating Solid Waste Facility, Permit No. 58-03
Spring 2017
Semiannual Water Quality Monitoring Report
Prepared for Madison County, North Carolina

Project Number: C61500-01.01
P:\Madison County\Reports\2017\5803 - Operating\Final 5803Apr2017 Semiannual Water Quality Report.docx
July 2017
Madison County Operating Solid Waste Facility, Permit No. 58-03
Spring 2017
Semiannual Water Quality Monitoring Report
Prepared for
Madison County, North Carolina
Post Office Box 579
Marshall, North Carolina 28753
Prepared by
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801

____________________________________________
Alec Macbeth, P.G.
Project Geologist

Spring 2017
Semiannual Water Quality Monitoring Report 1 July 2017
TABLE OF CONTENTS
1 Introduction ................................................................................................................................ 3
2 Methods ....................................................................................................................................... 4
2.1 Groundwater Purging and Sampling Methods ....................................................................................... 4
2.2 Surface Water Sampling Methods ................................................................................................................ 5
2.3 Leachate Sampling Methods .......................................................................................................................... 5
2.4 Sample Handling, Documentation, and Analysis .................................................................................... 5
3 Findings ........................................................................................................................................ 6
3.1 Analytical Results ................................................................................................................................................. 6
3.1.1 Groundwater Monitoring Wells ..................................................................................................... 7
3.1.2 Surface Water ........................................................................................................................................ 8
3.1.3 Leachate .................................................................................................................................................. 8
4 Site Hydrogeology ................................................................................................................... 10
5 Summary ..................................................................................................................................... 11
5.1 Future Activities ................................................................................................................................................ 11
6 References ................................................................................................................................. 12

TABLES
Table 1 Well Construction Details and Corresponding Elevations
Table 2 Summary of Laboratory Analyses Performed on Samples
Table 3 Groundwater and Surface Water Summary of Analytical Results
Table 4 Leachate Summary of Analytical Results
FIGURES
Figure 1 Site Location Map
Figure 2 Sample Location Map
Figure 3 Generalized Groundwater Flow
APPENDICES
Appendix A Sampling Logs and Equipment Documentation and Instrument Calibration Data
Sheets
Appendix B Report of Laboratory Analysis and Chain-of-Custody Documentation

Spring 2017
Semiannual Water Quality Monitoring Report 2 July 2017
ABBREVIATIONS
µg/L micrograms per liter
µS/cm microsiemens per centimeter
Anchor QEA Anchor QEA of North Carolina, PLLC
BOD biological oxygen demand
C&D construction and demolition
COD chemical oxygen demand
DEQ Department of Environmental Quality
DO dissolved oxygen
DWM Division of Waste Management
IMAC interim maximum allowable concentration
MDL method detection limit
mg/L milligrams per liter
MRL method reporting limit
MSW municipal solid waste
mV millivolts
NCAC North Carolina Administrative Code
NTU nephelometric turbidity units
Operating Landfill Madison County Solid Waste Department solid waste facility
ORP oxidation-reduction potential
RL reporting limit
SC specific conductivity
SESD Science and Ecosystem Support Division
SU Standard Units
SWS solid waste section
SWSL solid waste section limit
TestAmerica TestAmerica Laboratories, Inc.
USEPA U.S. Environmental Protection Agency
VOC volatile organic compound

Spring 2017
Semiannual Water Quality Monitoring Report 3 July 2017
1 Introduction
Anchor QEA of North Carolina, PLLC (Anchor QEA), is pleased to present the results of the
spring 2017 water quality monitoring event at the Madison County Operating Solid Waste Facility.
The Madison County Solid Waste Department operates a solid waste facility (Operating Landfill)
located on Craig Rudisill Road, west of U.S. Highway 25/70 near Marshall, North Carolina. A site
location map is included as Figure 1. The Operating Landfill includes the following permitted
components (Figure 2):
• Operating construction and demolition (C&D) debris landfill cell (Permit No. 58-03)
• Operating transfer station (Permit No. 58-03T)
• Closed C&D landfill cell (Permit No. 58-03)
• Closed municipal solid waste (MSW) landfill cell (Permit No. 58-03)
The Operating Landfill also contains a leachate underground holding tank that was installed in
August 2011. Previously, the leachate was stored in a lined leachate basin, which is no longer in use.
State regulations applicable to landfills are enforced by the North Carolina Department of
Environmental Quality (DEQ), Division of Waste Management (DWM). The Operating Landfill is
permitted by the DEQ DWM under Permit No. 58-03. The permit requires semiannual monitoring of
groundwater, surface water, and leachate quality.
This report documents the first semiannual groundwater, surface water, and leachate monitoring
event for 2017 and is being submitted in accordance with requirements stipulated in the DEQ Solid
Waste Management Rules, Title 15A, North Carolina Administrative Code (NCAC), Subchapter 13B
(15A NCAC 13B).
This semiannual report provides an evaluation of groundwater, surface water, and leachate quality
for the Operating Landfill.
The water quality monitoring network for the Operating Landfill consists of nine compliance
monitoring wells (MW-01, MW-02, MW-03, MW-04, MW-05, MW-06R, MW-07R, MW-08, and
MW-09), two surface water sample locations (SW-01 and SW-02R) located along a tributary to
Walnut Creek, and a leachate sample (LT-01) collected from the fill port on the underground holding
tank. Monitoring well construction details are summarized in Table 1.

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Semiannual Water Quality Monitoring Report 4 July 2017
2 Methods
On April 3 and 4, 2017, Anchor QEA collected nine groundwater samples from the monitoring wells,
two surface water samples from their established locations, and one aqueous sample from the
leachate underground holding tank. One of the monitoring wells sampled, MW-06R, is upgradient
from the landfill. Groundwater collected from this well is assumed to represent background
groundwater quality at the site. This monitoring well was installed on September 30, 2008, as a
replacement for the pre-existing background monitoring well, MW-06, which had historically been
dry. Sampling locations are shown on Figures 2 and 3.
2.1 Groundwater Purging and Sampling Methods
Prior to collecting groundwater samples from the monitoring wells, the static water level was
measured and recorded for each well. The monitoring wells were purged and sampled with a
peristaltic pump or bladder pump using low-flow techniques in accordance with the procedures
described in “Low-Flow (Minimal Drawdown) Ground-Water Sampling Procedures” from the
U.S. Environmental Protection Agency’s (USEPA’s) Groundwater Issues (Puls and Barcelona 1996).
During the purging process, pH, specific conductivity (SC), dissolved oxygen (DO),
oxidation-reduction potential (ORP), turbidity, and temperature were measured and recorded
approximately every 3 minutes. Well purging continued until these parameters stabilized for three
consecutive readings. The required stabilization criteria were determined by the USEPA Region 4
Science and Ecosystem Support Division’s (SESD’s) Operating Procedure: Groundwater Sampling
(USEPA 2013) and are as follows:
• pH values within +/- 0.1 pH unit
• SC values within +/- 3 percent
• Temperature, DO, and turbidity values within +/- 10 percent
• ORP values within +/- 10 millivolts (mv)
Following stabilization of these parameters, a groundwater sample was collected by a technician
wearing a new pair of nonreactive nitrile gloves. Two metals samples were collected at each
monitoring well during this sampling event. One sample was collected through standard sample
collection measures, and the second metals sample was collected by filtering the groundwater
through a 0.45-micrometer groundwater filter that attaches in line with the sample tubing. This
sample was collected to remove suspended sediment and identify metals that were dissolved in the
groundwater. Each sample was placed directly into laboratory-supplied sample containers. Low-flow
sampling logs are included in Appendix A.

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Semiannual Water Quality Monitoring Report 5 July 2017
2.2 Surface Water Sampling Methods
Surface water samples SW-01 and SW-02R were collected at designated locations from an unnamed
tributary to Walnut Creek that flows in a northerly direction adjacent to the western border of the
Operating Landfill (Figure 2). Sample SW-01 is considered representative of surface water quality
upstream of the Operating Landfill, whereas sample SW-02R is considered representative of
surface water quality downstream from the facility. Surface water samples were collected in
laboratory-supplied sample containers by a technician wearing a new pair of nonreactive nitrile
gloves. As with groundwater sampling, temperature, pH, SC, DO, ORP, and turbidity were measured
and recorded at each surface water sampling location prior to sample collection. Field parameters
and observations pertaining to surface water quality are provided on sampling logs included in
Appendix A.
2.3 Leachate Sampling Methods
One aqueous sample was collected from the leachate underground holding tank, designated as
LT-01. Leachate was historically collected from a lined storage basin. On August 12, 2011, a leachate
underground holding tank was installed and connected to the leachate collection piping associated
with the closed MSW landfill cell. Shortly thereafter, the lined leachate basin was closed. Leachate
sample LT-01 was collected on April 3, 2017, from one of the tank’s fill ports using a new disposable
polyethylene bailer. One round of field parameters (as described above) was measured and recorded
for sample LT-01 (Appendix A). Leachate collected in the holding tank at the Operating Landfill is
trucked as needed to the sewage treatment facility for the town of Marshall, North Carolina.
2.4 Sample Handling, Documentation, and Analysis
Field parameters for groundwater and surface water were measured, and the results are provided on
the sampling logs in Appendix A. Following sample collection, each sample was immediately placed
on ice in a sample cooler for transport to TestAmerica Laboratories, Inc. (TestAmerica), a
North Carolina-certified laboratory located in Nashville, Tennessee. Anchor QEA submitted the
groundwater, surface water, and leachate samples for the required analyses summarized in Table 2.
Proper chain-of-custody documentation procedures were followed during collection and transport of
each sample. Three trip blanks provided by the laboratory, each stored in a separate sample cooler,
were analyzed for Appendix I volatile organic compounds (VOCs). The reports of laboratory analysis
and chain-of-custody documentation are provided in Appendix B.

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Semiannual Water Quality Monitoring Report 6 July 2017
3 Findings
3.1 Analytical Results
The field parameter data and laboratory analytical results for groundwater, surface water, and the
leachate sample collected at the Operating Landfill are included in Appendices A and B. Results are
also submitted separately to the DEQ DWM Solid Waste Section (SWS) in the Electronic Data
Deliverable format (a format most recently updated on May 5, 2010).
As stipulated in the May 2010 DWM documents, non-detections were reported at the
laboratory-specific method detection limit (MDL), and all concentrations exceeding the MDL were
reported and appropriately qualified (Tables 3 and 4). The MDL is the minimum concentration of a
substance that can be measured and reported by a laboratory with 99 percent confidence that the
analyte concentration is greater than zero. The laboratory’s method reporting limit (MRL) is the
minimum concentration of a target analyte that can be accurately determined by the referenced
method. The MRL is listed as the “Report Limit” (RL) column in the TestAmerica report of laboratory
analysis (Appendix B). All detections were compared to analyte-specific Solid Waste Section Limits
(SWSLs) established by the SWS. The SWSL is the lowest concentration, determined by the SWS, of
an analyte in a sample that can be quantitatively determined with suitable precision and accuracy. If
the reported concentration is greater than the laboratory MRL and less than the SWSL, the analytical
result is qualified as estimated and flagged with a “J” qualifier (italicized J-flag) by Anchor QEA, per
the DEQ requirement. A “J” qualifier (non-italicized) is assigned by the laboratory and used for
parameters detected at estimated concentrations greater than the MDL but less than the MRL.
Detected concentrations of constituents below the applicable SWSLs are not discussed in the text of
this report unless they exceed their applicable North Carolina water quality standard.
Detected concentrations of analytes in groundwater samples were compared to the values specified
in the 15A NCAC 2L.0202 groundwater quality standard (2L standard). Detected concentrations of
analytes in groundwater with no established 2L standard were compared to an updated list of the
interim maximum allowable concentrations (IMACs) for classes GA and GSA groundwater (in
accordance with 15A NCAC 02L .0202[c]). Detections of analytes in surface water samples were
compared to the 15A NCAC 2B.0200 surface water quality standard (2B standard) established for
Class C waters.
Table 3 presents the summary of detected compounds and outlines concentrations of analytes that
were above the applicable SWSLs, as well as concentrations of analytes that exceed their respective
2L standard, IMAC, or 2B standard.

Spring 2017
Semiannual Water Quality Monitoring Report 7 July 2017
3.1.1 Groundwater Monitoring Wells
The following sections summarize the results of laboratory and field parameter analyses of
groundwater samples.
3.1.1.1 Appendix I Metals
Four metals (barium, cobalt, copper, and zinc) were detected above their SWSLs in one or more of
the samples collected from the monitoring wells (Table 3). Two metals, cobalt and vanadium, were
detected at concentrations above their groundwater standards. Cobalt was detected above the
applicable IMAC in the unfiltered samples collected from monitoring wells MW-02, MW-03, and
MW-07R (Table 3). The metal exceeded the IMAC in the filtered samples from monitoring wells
MW-02 and MW-03. Vanadium was detected above the applicable IMAC standard in the unfiltered
and filtered samples collected from all site monitoring wells (Table 3). The detected vanadium
concentrations were below the SWSL. Vanadium concentrations are believed to be naturally
occurring due to comparable background monitoring well data and upstream surface water data. All
vanadium detections were also flagged by the laboratory with a “B” qualifier, which identifies
parameters that were detected in the laboratory blank and sample. This indicates a potential for the
sample results to be biased high. Standard metals and their separate dissolved analyses are
identified individually on Table 3.
3.1.1.2 Appendix I VOCs
Two VOCs (acetone and benzene) were detected in the groundwater samples. Acetone was detected
in one or more groundwater samples collected from the Operating Landfill at concentrations below
SWSLs and 2L standards. Acetone is a common laboratory contaminant that was also detected in
both trip blanks, indicating that these detections may not be representative of groundwater quality.
Benzene was detected in monitoring well MW-05 at a concentration of 0.234 J micrograms per liter
(µg/L), well below the compound’s SWSL and 2L standard. This is the first sampling event in which
benzene was detected at the Operating Landfill.
3.1.1.3 Field Parameters
Field parameters were recorded during sampling activities on April 3 and 4, 2017. Measured pH
values for samples collected from the monitoring wells ranged from 5.47 to 6.32 Standard Units (SU),
and are all below the 2L standard pH range of 6.5 to 8.5 SU (Table 3). Turbidity values for samples
collected from the monitoring wells ranged from 2.04 nephelometric turbidity units (NTU) to
108 NTU.
DO values in the samples collected from the monitoring wells ranged between 2.12 milligrams per
liter (mg/L; MW-05) to 8.99 mg/L in monitoring well MW-07R. SC measurements were recorded
between 58 microsiemens per centimeter (µS/cm; MW-01) to 271 µS/cm (MW-03). ORP values in the
samples collected from the monitoring wells ranged between 64.3 mV; MW-03) to 324.0 mV in

Spring 2017
Semiannual Water Quality Monitoring Report 8 July 2017
monitoring well MW-08. A full summary of field parameters is provided in Table 3. These field
parameters do not have established groundwater standards.
3.1.2 Surface Water
The following sections summarize the results of laboratory and field parameter analyses of surface
water samples SW-01 and SW-02R.
3.1.2.1 Appendix I Metals
In both surface water samples, four metals (barium, cobalt, vanadium, and zinc) were detected below
their respective SWSLs. All vanadium detections were also flagged by the laboratory with a “B”
qualifier, which identifies parameters that were detected in the laboratory blank and sample. No
metals were detected above applicable 2B standards (Table 3).
3.1.2.2 Appendix I VOCs
No VOCs were detected in either of the surface water samples collected from the Operating Landfill.
Acetone was detected in the trip blank associated with the surface water samples at a concentration
below the MRL.
3.1.2.3 Field Parameters
The pH values recorded for surface water samples SW-01 and SW-02R were measured at 6.33 SU
and 5.89 SU, respectively. The pH in SW-02R was outside the 2B standard pH range of 6.0 to 9.0 SU
(Table 3) but consistent with historical data.
The measured turbidity values for SW-01 and SW-02R were 16.1 NTU and 17.5 NTU, respectively.
Both readings are within the 2B standard for turbidity established at 25 NTU (Table 3).
The DO was recorded at 6.28 mg/L and 9.46 mg/L for surface water samples SW-01 and SW-02R,
respectively. These concentrations are within the 2B standard established at “equal or greater than”
5.0 mg/L.
SC measurements were recorded at 84 µS/cm and 104 µS/cm for surface water samples SW-01 and
SW-02R, respectively. ORP values for these surface water samples were recorded at 279.2 mV and
323.8 mV, respectively. These parameters do not have established 2B surface water standards.
3.1.3 Leachate
Analytical results for the leachate sample (LT-01) collected from the leachate underground holding
tank are summarized in Table 4 and discussed below.

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Semiannual Water Quality Monitoring Report 9 July 2017
3.1.3.1 Appendix I Metals
Six metals were detected in the aqueous sample collected from the leachate storage tank. Of the six
metals, three of them (barium, cobalt, and zinc) were detected above their respective SWSLs
(Table 4).
3.1.3.2 Appendix I VOCs
Acetone was detected in the leachate sample at a concentration well below the SWSL. No other
VOCs were detected in the leachate sample.
3.1.3.3 Inorganics
LT-01 was also analyzed for biological oxygen demand (BOD), chemical oxygen demand (COD),
nitrate, phosphorus, and sulfate. The analytical results for detected parameters are summarized as
follows:
• BOD: 2,240 µg/L
• COD: 130,000 µg/L
• Nitrate: 38,800 µg/L
• Total phosphorous: 107 µg/L
• Sulfate: 154,000 J µg/L
Nitrate was detected at a concentration greater than the SWSL (Table 4). All other parameters, except
for sulfate, did not have established SWSLs. Sulfate was detected well below its SWSL.
3.1.3.4 Field Parameters
Field parameters were measured and recorded for the leachate sample on April 3, 2017. Field
parameters are summarized as follows:
• pH: 6.78 SU
• DO: 9.00 mg/L
• Turbidity: 16.66 NTU
• SC: 2,246 µS/cm
• ORP: 345.2 mV
No standards exist for leachate; therefore, the recorded results are not evaluated.

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Semiannual Water Quality Monitoring Report 10 July 2017
4 Site Hydrogeology
Based on groundwater measurements taken by Anchor QEA on April 3 and 4, 2017, the predominant
groundwater flow direction within the regolith overlying the bedrock at the Operating Landfill
appears to be west-northwest toward the unnamed tributary of Walnut Creek. Figure 3 depicts the
generalized groundwater flow direction. Water level data are summarized on Table 1.

Spring 2017
Semiannual Water Quality Monitoring Report 11 July 2017
5 Summary
Anchor QEA completed the first semiannual water quality monitoring event of 2017 at the
Operating Landfill on April 3 and 4, 2017.
Tables 3 and 4 of this report, sampling logs (Appendix A), and the TestAmerica Reports of Laboratory
Analysis (Appendix B) provide detailed analytical results and field data used to interpret groundwater
and surface water quality at the Operating Landfill.
5.1 Future Activities
Anchor QEA has discussed the exceedances of applicable water quality standards with
Madison County. Anchor QEA will continue to measure field parameters and collect water quality
samples from groundwater, surface water, and leachate monitoring points associated with the
Operating Landfill. Water quality samples will be submitted to a North Carolina-certified laboratory
for analysis of Appendix I metals and VOCs on a semiannual basis. The next sampling event is
scheduled for October 2017.

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Semiannual Water Quality Monitoring Report 12 July 2017
6 References
DENR DWM SWS (Department of Environmental and Natural Resources Division of Waste
Management Solid Waste Section), 2006. New Guidelines for Electronic Submittal of
Environmental Monitoring Data. October 2006.
DENR DWM SWS, 2007. Addendum to October 27, 2006, NC SWS Memorandum Regarding New
Guidelines for Electronic Submittal of Environmental Data. February 2007.
Puls, R.W., and M. J. Barcelona, 1996. Low-Flow (Minimal Drawdown) Ground-Water Sampling
Procedures. USEPA Office of Solid Waste and Emergency Response. EPA/540/S-95/504. April
1996.
USEPA (U.S. Environmental Protection Agency), 2013. Operating Procedure: Groundwater Sampling.
Prepared for SESD. March 2013.

Tables

Table 1
Well Construction Details and Corresponding Elevations
Spring 2017 Semiannual Water Quality Monitoring Report
Madison County Operating Solid Waste Facility
Page 1 of 1
July 2017
58-03 MW-01 1,859.04 1,857.04 5.09 1,853.95 7 1,850.0 2 to 17 1,855.04
58-03 MW-02 1,898.94 1,895.94 3.81 1,895.13 6 1,889.9 1 to 16 1,892.94
58-03 MW-03 1,932.96 1,929.46 21.66 1,911.30 NA NA 15.5 to 25.5 1,913.96
58-03 MW-04 1,935.64 1,932.04 27.63 1,908.01 35.2 1,896.8 70.7 to 80.7 1,861.34
58-03 MW-05 1,972.76 1,969.26 48.73 1,924.03 NA NA 46.5 to 61.5 1,922.76
58-03 MW-06 2,082.87 2,081.87 NA NA 28 2,053.9 80 to 100 2,001.87
58-03 MW-06R 1,942.19 1,942.19 6.45 1,935.74 NA NA 10 to 25 1,932.19
58-03 MW-07R 1,919.34 1,916.64 29.53 1,889.81 NA NA 26 to 41 1,890.64
58-03 MW-08 1,899.92 1,896.92 20.48 1,879.44 NA NA 16 to 26 1,880.92
58-03 MW-09 1,949.43 1,946.43 7.05 1,942.38 NA NA 12.4 to 22.4 1,934.03
Notes:
Elevations are in feet, based on the NAVD 88 datum.
Top of casing
Not Applicable
Calculated based on TOC elevations and field measurements.
Depth-to-water measurements were obtained in the field on April 3 and 4, 2017.
Installed during closure of MSW cell.
Elevations
TOC
NA
Ground Elevations
Facility
Permit Well ID
Depth to
Bedrock
Top of Bedrock
Elevation
Ground
Elevation
Depth to
Water from
TOC
Depths are measured in feet below ground surface. Data was taken from boring logs completed on September 26, 27, 28, and 29, 1992 by
Metro Drill, Inc. and April 12, 1995 by Engineering Tectonics.
Screened
Interval
Top of Screen
Elevation
TOC
Elevation
Groundwater
Elevation
Included on the Closure Plan drawing generated by McGill Associates on January 4, 2007. Adjusted "Depth to Bedrock" and "Screened Interval" elevations
were calculated using original data from September 1992 boring logs and new data from the December 14, 2006 survey.
Depth to Water
Depth to Bedrock &
Screened Interval
TOC Elevations
MW-03 and MW-04
MW-06
Ground survey data
For MW-01, MW-02, MW-05, and MW-06, TOC elevations are based on the report, Transition Plan Application (Law Engineering, April 1994). For MW-03
and MW-04, elevations are from the survey performed on December 14, 2006 by McGill Associates staff (J. Dallas Gordon, PLS). For MW-07R and MW-08,
elevations were taken from survey data included on boring logs completed by Bunnell-Lammons Engineering, Inc. on July 28, 29, and 30, 2003. For MW-09,
elevation was taken from survey data included on boring log completed by Bunnell-Lammons Engineering, Inc. on October 13, 2006.
Monitoring of background well MW-06 was terminated in Fall 2008 because the well was dry. MW-06R was installed on September 27, 2008 to replace MW-
06. Survey data for MW-06R are based on a survey conducted on April 16, 2009 by Wes Cole Land Surveying, PA. MW-06 was gauged and recorded if
water was present, but not sampled.
Table 2
Summary of Laboratory Analyses Performed on Samples
Spring 2017 Semiannual Water Quality Monitoring Report
Madison County Operating Solid Waste Facility
Page 1 of 1
July 2017
Groundwater Samples Surface Water Samples
Metals
Dissolved
Metals VOCs Metals VOCs
EPA 6010D
EPA 6020B
EPA 7470A
EPA 6010D
EPA 6020B
EPA 7470A EPA 8260B
EPA 6010D
EPA 6020B
EPA 7470A EPA 8260B
MW-01 4/4/2017 X X X SW-01 4/4/2017 X X
MW-02 4/3/2017 X X X SW-02R 4/4/2017 X X
MW-03 4/4/2017 X X X
MW-04 4/4/2017 X X X Quality Control Sample
MW-05 4/3/2017 X X X VOCs
MW-06R 4/4/2017 X X X EPA 8260B
MW-07R 4/3/2017 X X X TRIP BLANK (LT-01)4/3/2017 X
MW-08 4/3/2017 X X X TRIP BLANK (MW)4/4/2017 X
MW-09 4/4/2017 X X X TRIP BLANK (SW)4/4/2017 X
Leachate Sample
Collect Date Metals VOCs
Biochemical
Oxygen Demand
(BOD) Nitrate as N
Chemical Oxygen
Demand
(COD)
Total
Phosphorus Sulfate
EPA 6010D
EPA 6020B
EPA 7470A EPA 8260B SM 5210B
Nitrate by
calc SM 5220D EPA 365.4 EPA 300.0
LT-01 4/3/2017 X X X X X X X
Analyses
Dissolved
Metals
Sampled by filtering groundwater through an in-line, 0.45 micrometer sampling filter.
VOCs Volatile organic compounds
LT-01 Leachate sample, collected from the leachate underground holding tank.
Metals and VOCs analyses include Appendix I metals per 40 CFR Part 258 "Appendix I Constituents for Detection Monitoring". Metals
analyses also includes mercury.
Notes:
Sample
Name Collect Date Sample Name Collect Date
Sample Name Collect Date
Sample
Name
Table 3
Groundwater and Surface Water Summary of Analytical Results
Spring 2017 Semiannual Water Quality Monitoring Report
Madison County Operating Solid Waste Facility
Page 1 of 2
July 2017
Metals
Lab Certification 387
Lab Method EPA 6010D, 6020B
Parameter Barium
Barium
(Dissolved)Beryllium
Beryllium
(Dissolved)Chromium
Chromium
(Dissolved)Cobalt
Cobalt
(Dissolved)Copper
Copper
(Dissolved)Lead
Lead
(Dissolved)Mercury
Mercury
(Dissolved)
CAS Number 7440-39-3 7440-39-3 7440-41-7 7440-41-7 7440-47-3 7440-47-3 7440-48-4 7440-48-4 7440-50-8 7440-50-8 7439-92-1 7439-92-1 7439-97-6 7439-97-6
SWS ID 15 15 23 23 51 51 53 53 54 54 131 131 132 132
Units µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L
Sample Name Collect Date Result Result Result Result Result Result Result Result Result Result Result Result Result Result
Monitoring Well Samples
MW-01 4/4/2017 103 98.1 J 0.100 U 0.100 U 3.00 U 3.00 U 0.792 J 0.813 J 5.00 U 11.7 2.00 U 3.3 J 0.100 U 0.100 U
MW-02 4/3/2017 81.4 J 64.5 J 0.100 U 0.100 U 4.9 J 3.00 U 3.18 J 1.58 J 5.00 U 5.00 U 2.00 U 2.3 J 0.100 U 0.100 U
MW-03 4/4/2017 193 194 0.100 U 0.100 U 4.3 J 4.3 J 84.4 85.2 5.00 U 5.2 J 2.00 U 5.6 J 0.100 U 0.100 U
MW-04 4/4/2017 149 152 0.100 U 0.100 U 3.00 U 3.00 U 0.100 U 0.100 U 5.00 U 12.2 2.00 U 5.7 J 0.100 U 0.100 U
MW-05 4/3/2017 133 128 0.100 U 0.100 U 3.00 U 3.00 U 0.731 J 0.649 J 5.00 U 14.5 2.00 U 5.4 J 0.102 J, B 0.100 U
MW-06R 4/4/2017 25.4 J 24.9 J 0.100 U 0.100 U 3.00 U 3.00 U 0.100 U 0.100 U 5.00 U 12.3 2.00 U 4.3 J 0.100 U 0.100 U
MW-07R 4/3/2017 178 97.6 J 0.301 J 0.100 U 7.6 J 3.00 U 2.25 J 0.100 U 5.00 U 10.3 2.00 U 4.7 J 0.100 U 0.100 U
MW-08 4/3/2017 31.6 J 28.5 J 0.100 U 0.100 U 3.00 U 3.00 U 0.288 J 0.100 U 5.00 U 11.7 2.00 J 6.8 J 0.100 U 0.100 U
MW-09 4/4/2017 159 155 0.100 U 0.100 U 3.00 U 3.00 U 0.133 J 0.100 U 5.00 U 13.4 2.00 U 6.3 J 0.100 U 0.100 U
Surface Water Samples
SW-01 4/4/2017 60.3 J NA 0.100 U NA 3.00 U NA 1.29 J NA 5.00 U NA 2.00 U NA 0.100 U 0.100 U
SW-02R 4/4/2017 54.3 J NA 0.100 U NA 3.00 U NA 0.879 J NA 5.00 U NA 2.00 U NA 0.100 U 0.100 U
Quality Control Samples
TRIP BLANK (MW)4/4/2017 NA NA NA NA NA NA NA NA NA NA NA NA NA NA
TRIP BLANK (SW)4/3/2017 NA NA NA NA NA NA NA NA NA NA NA NA NA NA
MDL 5.00 5.00 0.100 0.100 3.00 3.00 0.100 0.100 5.0 5.0 2.00 2.00 0.100 0.100
MRL 10.0 10.0 2.0 2.0 5.0 5.0 2.0 2.0 10 10 5.0 5.0 0.20 0.20
SWSL 100 100 1 1 10 10 10 10 10 10 10 10 0.2 0.2
2L 700 700 NE NE 10 10 NE NE 1000 1000 15 15 1 1
IMAC NE NE 4 4 NE NE 1 1 NE NE NE NE NE NE
GWPS NE NE 4 4 NE NE 1 1 NE NE NE NE NE NE
2B 200,000 200,000 6.5 6.5 35 35 4 4 2.7 2.7 0.54 0.54 0.012 0.012
Notes:
Detections Only detected constituents are listed on this table. Please refer to TestAmerica Laboratories, Inc., Report of Laboratory Analysis for further details.
Lab Method The analytical method used to analyze the constituents.
CAS Number A unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters.
SWS ID The solid waste section identification number.
Units
Collect Date The date on which the sample was collected in the field.
Result Analytical data reported by the laboratory or field data collected by Anchor QEA.
MDL The method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero.
MRL The method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method.
SWSL The solid waste section limit. This limit (identified by the Department of Environmental Quality [DEQ]) is the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy.
U A laboratory data qualifier used for parameters not detected at concentrations above MDL.
J A laboratory data qualifier used for parameters detected at estimated concentrations above MDL but below MRL and SWSL.
J Assigned by Anchor QEA to reflect a detected concentration that is greater than MRL and MDL but less than the SWSL.
B A laboratory data qualifier used for parameters that were detected in both the laboratory blank and the sample.
F1 A laboratory data qualifier that indicates the sample's matrix spike (MS) or matrix spike duplicate (MSD) were outside acceptance limits.
2L Groundwater standards from North Carolina Administrative Code (NCAC), Title 15A: Department of Environmental Quality, Subchapter 2L - Groundwater Classifications and Standards, DEQ (Amended April 1, 2013).
IMAC The interim maximum allowable concentration. An IMAC is applied to a constituent if there is not a 2L standard established. Standards are from NCAC 15A 02L .0202.
GWPS
2B
NE not established
NA not applicable
(Dissolved)A second metals sample was collected through a 0.45 micron groundwater filter and analyzed for dissolved metals concentrations.
106 Indicates a result in exceedance of the SWSL.
5.92 Indicates a result in exceedance of the 2L, IMAC, or 2B (surface water) standards, or greater than or equal to the GWPS (if no 2L or IMAC exist).
Micrograms per liter (µg/L) and milligrams per liter (mg/L) for analytical results, Standard Units (SU) for pH, nephelometric turbidity units (NTU) for turbidity, microsiemens per centimeter (µS/cm) for specific conductivity, degrees
celcius (°C) for temperature, and millivolts (mV) for oxidation reduction potential.
The Groundwater Protection Standard pursuant to 15A NCAC 13B .1634, DEQ. Current standards were obtained from http://deq.nc.gov/about/divisions/waste-management/waste-management-permit-guidance/solid-waste-
section/environmental-monitoring/environmental-monitoring-list.
"2B" indicates surface water standard per North Carolina Administrative Code, Title 15A: Department of Environment and Natural Resources, Subchapter 2B - Surface Water and Wetland Standards, (last amended on May 1, 2007).
For compounds with no 2B standard established, the Environmental Protection Agency (EPA) National Criteria Table (current as of May 15, 2013) was used for the most stringent of fresh water and human health.
Table 3
Groundwater and Surface Water Summary of Analytical Results
Spring 2017 Semiannual Water Quality Monitoring Report
Madison County Operating Solid Waste Facility
Page 2 of 2
July 2017
Metals VOCs Field Parameters
Lab Certification 387 387 5445 (pH only)
Lab Method EPA 6010D, 6020B EPA 8260B
Parameter Nickel
Nickel
(Dissolved)Selenium
Selenium
(Dissolved)Vanadium
Vanadium
(Dissolved)Zinc
Zinc
(Dissolved)Acetone Benzene
Dissolved
Oxygen pH Turbidity Temperature
Specific
Conductivity
Oxidation
Reduction
Potential
CAS Number 7440-02-0 7440-02-0 7782-49-2 7782-49-2 7440-62-2 7440-62-2 7440-66-6 7440-66-6 67-64-1 71-43-2 7782-44-7 SW320 SW330 SW325 SW323 SW336
SWS ID 152 152 183 183 209 209 213 213 3 16 356 320 330 325 323 336
Units µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/L SU NTU °C µS/cm mV
Sample Name Collect Date Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result
MW-01 4/4/2017 3.00 U 3.00 U 5.00 U 5.00 U 1.41 J, B 1.32 J, B 12.3 J, F1, B 18.8 J 2.66 U 0.200 U 3.63 5.47 7.03 11.43 58 302.5
MW-02 4/3/2017 3.00 U 3.00 U 5.00 U 5.00 U 13.4 J, B 1.6 J, B 5.20 U 14.1 J 2.66 U 0.200 U 4.78 6.04 65.4 11.69 82 272.1
MW-03 4/4/2017 4.2 J 3.8 J 7.3 J 5.7 J 1.12 J, B 1.19 J, B 5.20 U 14.9 J 3.81 J 0.200 U 2.93 5.93 17.6 16.94 271 64.3
MW-04 4/4/2017 3.00 U 3.00 U 5.00 U 5.00 U 4.90 J, B 4.76 J, B 5.20 U 13.7 J 2.66 U 0.200 U 4.53 6.28 2.26 16.30 182 243.1
MW-05 4/3/2017 4.9 J 5.6 J 5.00 U 5.00 U 5.04 J, B 4.6 J, B 5.75 J, B 19.4 J 2.66 J 0.234 J 2.12 5.84 4.35 13.91 216 297.2
MW-06R 4/4/2017 3.00 U 3.00 U 5.00 U 5.00 U 1.52 J, B 1.63 J, B 5.20 U 17.3 J 4.19 J 0.200 U 6.18 6.26 2.04 16.05 102 297.0
MW-07R 4/3/2017 3.8 J 3.00 U 5.00 U 5.00 U 11.0 J, B 1.69 J, B 12.5 J, B 18.1 J 2.66 U 0.200 U 8.99 5.81 108 14.50 61 306.9
MW-08 4/3/2017 3.00 U 3.00 U 5.00 U 5.00 U 4.02 J, B 4.03 J, B 7.84 J, B 17.9 J 2.66 U 0.200 U 7.32 6.23 7.37 13.75 218 324.0
MW-09 4/4/2017 3.00 U 3.00 U 5.00 U 5.00 U 2.02 J, B 2.28 J,B 5.20 U 18.7 J 4.61 J 0.200 U 2.34 6.32 6.34 18.40 162 253.5
SW-01 4/4/2017 3.00 U NA 5.00 U NA 3.26 J, B NA 6.99 J, B NA 2.66 U 0.200 U 6.28 6.33 16.1 15.69 84 279.2
SW-02R 4/4/2017 3.00 U NA 5.00 U NA 2.99 J, B NA 21.9 J, B NA 2.66 U 0.200 U 9.46 5.89 17.5 11.67 104 323.8
TRIP BLANK (MW)4/4/2017 NA NA NA NA NA NA NA NA 3.48 J 0.200 U NA NA NA NA NA NA
TRIP BLANK (SW)4/3/2017 NA NA NA NA NA NA NA NA 3.48 J 0.200 U NA NA NA NA NA NA
MDL 3.00 3.00 5.00 5.00 0.700 0.700 5.20 5.20 2.66 0.200 NA NA NA NA NA NA
MRL 10.0 10.0 10.0 10.0 2.0 2.0 25.0 25.0 25.0 1.0 NA NA NA NA NA NA
SWSL 50 50 10 10 25 25 10 10 100 1 NE NE NE NE NE NE
2L 100 100 20 20 NE NE 1,000 1,000 6,000 1 NE 6.5-8.5 NE NE NE NE
IMAC NE NE NE NE 0.3 0.3 NE NE NE NE NE NE NE NE NE NE
GWPS NE NE NE NE 0.3 0.3 NE NE NE NE NE NE NE NE NE NE
2B 16 16 5 5 NE NE 36 36 2,000 51 > 5.0 6.0-9.0 25 NE NE NE
Notes:
Detections Only detected constituents are listed on this table. Please refer to TestAmerica Laboratories, Inc., Report of Laboratory Analysis for further details.
Lab Method The analytical method used to analyze the constituents.
CAS Number A unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters.
SWS ID The solid waste section identification number.
Units
Collect Date The date on which the sample was collected in the field.
Result Analytical data reported by the laboratory or field data collected by Anchor QEA.
MDL The method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero.
MRL The method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method.
SWSL The solid waste section limit. This limit (identified by the Department of Environmental Quality [DEQ]) is the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy.
U A laboratory data qualifier used for parameters not detected at concentrations above MDL.
J A laboratory data qualifier used for parameters detected at estimated concentrations above MDL but below MRL and SWSL.
J Assigned by Anchor QEA to reflect a detected concentration that is greater than MRL and MDL but less than the SWSL.
B A laboratory data qualifier used for parameters that were detected in both the laboratory blank and the sample.
F1 A laboratory data qualifier that indicates the sample's matrix spike (MS) or matrix spike duplicate (MSD) were outside acceptance limits.
2L Groundwater standards from North Carolina Administrative Code (NCAC), Title 15A: Department of Environmental Quality, Subchapter 2L - Groundwater Classifications and Standards, DEQ (Amended April 1, 2013).
IMAC The interim maximum allowable concentration. An IMAC is applied to a constituent if there is not a 2L standard established. Standards are from NCAC 15A 02L .0202.
GWPS
2B
NE not established
NA not applicable
(Dissolved)A second metals sample was collected through a 0.45 micron groundwater filter and analyzed for dissolved metals concentrations.
106 Indicates a result in exceedance of the SWSL.
5.92 Indicates a result in exceedance of the 2L, IMAC, or 2B (surface water) standards, or greater than or equal to the GWPS (if no 2L or IMAC exist).
The Groundwater Protection Standard pursuant to 15A NCAC 13B .1634, DEQ. Current standards were obtained from http://deq.nc.gov/about/divisions/waste-management/waste-management-permit-guidance/solid-waste-section/environmental-
monitoring/environmental-monitoring-list.
Surface Water Samples
Quality Control Samples
Monitoring Well Samples
"2B" indicates surface water standard per North Carolina Administrative Code, Title 15A: Department of Environment and Natural Resources, Subchapter 2B - Surface Water and Wetland Standards, (last amended on May 1, 2007). For compounds with
no 2B standard established, the Environmental Protection Agency (EPA) National Criteria Table (current as of May 15, 2013) was used for the most stringent of fresh water and human health.
Micrograms per liter (µg/L) and milligrams per liter (mg/L) for analytical results, Standard Units (SU) for pH, nephelometric turbidity units (NTU) for turbidity, microsiemens per centimeter (µS/cm) for specific conductivity, degrees celcius (°C) for
temperature, and millivolts (mV) for oxidation reduction potential.
Table 4
Leachate Summary of Analytical Results
Spring 2017 Semiannual Water Quality Monitoring Report
Madison County Operating Solid Waste Facility
Page 1 of 1
July 2017
Metals VOCs
Lab Certification 387 387
Lab Method EPA 6010D & 6020B EPA 8260B
Parameter Barium Cobalt Copper Nickel Vanadium Zinc Acetone
CAS Number 7440-39-3 7440-48-4 7440-50-8 7440-02-0 7440-62-2 7440-66-6 67-64-1
SWS ID 15 53 54 152 209 213 3
Units µg/L µg/L µg/L µg/L µg/L µg/L µg/L
Sample Name Collect Date Result Result Result Result Result Result Result
LT-01 04/03/2017 122 12.2 9.7 J 38.1 7.53 J 19.2 J 4.76 J
TRIPBLANK (LT-01)04/03/2017 NA NA NA NA NA NA 2.66 U
MDL 5.00 0.100 5.00 3.00 0.700 5.20 2.66
MRL 10.0 2.0 10.0 10.0 2.0 25 25.0
SWSL 100 10 10 50 25 10 100
General Chemistry Field Parameters
Lab Certification 387 5445 (pH only)
Lab Method SM5210B SM 5220D Nitrate by calc EPA 365.4 EPA 300.0
Parameter BOD COD Nitrate as N
Total
Phosphorus Sulfate
Dissolved
Oxygen pH Turbidity Temperature
Specific
Conductivity
Oxidation
Reduction
Potential
CAS Number SW316 SW317 14797-55-8 7723-14-0 14808-79-8 7782-44-7 SW320 SW330 SW325 SW323 SW336
SWS ID 316 317 303 412 315 356 320 330 325 323 336
Units µg/L µg/L µg/L µg/L µg/L mg/L SU NTU °C µS/cm mV
Sample Name Collect Date Result Result Result Result Result Result Result Result Result Result Result
LT-01 04/03/2017 2,240 130,000 38,800 107 154,000 J 9.00 6.78 16.66 12.08 2,246 345.2
TRIPBLANK (LT-01)04/03/2017 NA NA NA NA NA NA NA NA NA NA NA
MDL 2,000 4,000 40.0 50.0 12,000 NA NA NA NA NA NA
MRL 2,000 20,000 100 100 20,000 NA NA NA NA NA NA
SWSL NE NE 10,000 NE 250,000 NE NE NE NE NE NE
Notes:
Detections Only detected constituents are listed on this table. Please refer to the TestAmerica Report of Laboratory Analysis for further details.
Lab Method The analytical method used to analyze the constituents.
CAS Number A unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters.
SWS ID The Solid Waste Section Identification Number.
Units
Collect Date The date on which the sample was collected in the field.
Result Analytical data reported by the laboratory or field data collected by Anchor QEA.
MDL The method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99 percent confidence that the analyte concentration is greater than zero.
MRL The method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method.
SWSL The Solid Waste Section Limit. This limit (identified by DEQ) is the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy.
U A laboratory data qualifier used for parameters not detected at concentrations above MDL.
J A laboratory data qualifier used for parameters detected at estimated concentrations above MDL but below MRL and SWSL.
J Assigned by Anchor QEA to reflect a detected concentration that is greater than MRL and MDL but less than the SWSL.
B A laboratory data qualifier used for parameters that were detected in both the laboratory blank and the sample.
VOCs volatile organic compounds
BOD biological oxygen demand
COD chemical oxygen demand
NE not established
122 Indicates a result in exceedance of the SWSL.
Micrograms per liter (µg/L) and milligrams per liter (mg/L) for analytical results, Standard Units (SU) for pH, nephelometric turbidity units (NTU) for turbidity, microsiemens per centimeter (µS/cm)
for specific conductivity, degrees celcius (°C) for temperature, and millivolts (mV) for oxidation reduction potential.

Figures
[0 2,0001,000
Feet
LEGEND:
Landfill Parcel Boundary
Publish Date: 2017/07/05, 4:26 PM | User: alesueurFilepath: P:\Madison County\Figures\GIS\GIS User\MXDs\2017\Spring\5803Apr Figure 1-Site Location Map Operating AQ.mxd
Figure 1Site Location Map
Spring 2017 Semiannual Water Quality Monitoring ReportMadison County Operating Solid Waste Facility, Permit #58-03, Marshall, North Carolina
SOURCE(S):Basemap: USGS 1:24,000 Scale Topo Maps,Marshall Quadrangle, 1990.Parcels: Madison County GIS
Anchor QEA of North Carolina, PLLC
!(#I#I@A
@A
@A
@A
@A@A
@A
@A
@A
OperatingTransfer Station
Former Leachate Basin
POND
%Tributary Flow Direction
OperatingC&D Cell
ClosedMSWCell
ClosedC&D Cell
LT-01
SW-01
SW-02R
MW-05
MW-07R
MW-02
MW-08
MW-03
MW-04
MW-09
MW-06R
MW-01
2025176521 1519451875 199517052235198520351715200520751725 1965
2105
191517 452125175518851735198518952075
21351 98519952095
1
9
2
5
1775
19251 7 2 51785 1835
1795
1715
1895191518051825
181519751935
1815
1825
20
65
1805
1835202519051725 17 95184520652065
1 9 4 519651785
222518551
9
1
5
17751735
1955
1745
1875 195520551765
18651 7 5 5
1 9 6 5
2015
1 7 3 5
19451
985
221519751755
1805
22051985
1 9 2 5 19951985188519951745
219519351975
2 0 0 52045 2185
1965
20 5 5
2175
20151955213521251945
1
9
15
2165187521152105
20452155 2145209517451755
1975
201520051995193520851 9 75
20751965
20651
7
75
1765 1785
20351795
20251 8 1 5 1825
1965
18951 8 3 5
20552045
1845
2035185518652025187520151905
18951885
20051945
1985199519
7
5
1
9
6
51955
1
9
2
5
CRAIG RUDISILL RD
[
0 500250
Feet
LEGEND:
@A Monitoring Well Location
#ISurface Water Sample Location
Unnamed Tributary
Cell Boundary Locations
!(Leachate Holding Tank
Roads
Elevation Contours (10 Foot Interval)
Publish Date: 2017/07/05, 4:30 PM | User: alesueurFilepath: P:\Madison County\Figures\GIS\GIS User\MXDs\2017\Spring\5803Apr Figure 2-Sample Location Map Operating AQ.mxd
Figure 2Sample Location Map
Spring 2017 Semiannual Water Quality Monitoring ReportMadison County Operating Solid Waste Facility, Permit #58-03, Marshall, North Carolina
SOURCE(S):Basemap: NC OneMap 2010Roads and Streams: MadisonCounty GIS 2006
Anchor QEA of North Carolina, PLLC
!(%#I#I@A
@A
@A
@A
@A@A
@A
@A
@A
OperatingTransfer Station
Former Leachate Basin
POND
%Tributary Flow Direction OperatingC&D Cell
ClosedMSW Cell
ClosedC&D Cell GroundwaterFlowDirection
2105 19051875 19951765
2235198520352095
207520051785
196517951935 1745
1915
1885
1985
1 8 1 5
18952075 1985199518251
9
2
5
1 7 5 5
192518351845
189519151765
1
9
7
5
1
9
3
5
2
0
6
5
2
06
51 7 3 51855
202519051 7 4 5
2065 196519451865
2
2
2
5
1
9
1
5
1 9 5 5 19551875
2
2
1
520552015
1965 19452205
1
985
197521951805205519 2 5
1 9 8 5 1995198518852185
199
5193519752045 2175
2 0 0 5
1965
20151875204519452165
21351955212521 151945 1915
2155
214521051745
1965
1 7 5 5
209517651975
201520051995193 5
20851 9 7 5
207520651775
1 9 65
17851795
20351815
20251825
1895
1
8
3
5
1945
2055
204
5
1 9 5 5
18 45
1855
2035
1 8 6 5
20251875
20151895
1885
19
0
5
1925
2
0
0
5
198519951975196
5
1915192519351955MW-05
(1,924.03)
MW-07R
(1,889.81)
MW-02
(1,895.13)
MW-08(1,879.44)
MW-03
(1,911.30)
MW-04
(1,908.01)
MW-09
(1,942.38)
MW-06R
(1,935.74)
MW-01
(1,853.95
SW-01
SW-02R
[
0 500 1,000250
Feet
NOTE(S):1. (1,907.80) = Groundwater Elevation2. Groundwater (GW) flow direction based onGW elevations in water table wells MW-02,MW-03, MW-05, MW-06R, MW-07R, andMW-08.3. GW elevations based on depth to watermeasurements collected on October 18 and19, 2016.
LEGEND:
@A Monitoring Well Location
Groundwater Flow Direction
!(Leachate Tank Location
Roads
Unnamed Tributary
Elevation Contours (10 Foot Interval)
Publish Date: 2017/07/05, 4:34 PM | User: alesueurFilepath: P:\Madison County\Figures\GIS\GIS User\MXDs\2017\Spring\5803Oct Figure 3-Groundwater Flow(2).mxd
Figure 3Generalized Groundwater Flow
Spring 2017 Semiannual Water Quality Monitoring ReportMadison County Operating Solid Waste Facility, Permit #58-03, Marshall, North Carolina
SOURCE(S):Basemap: NC OneMap 2010Roads and Streams: Madison County GIS 2006
Anchor QEA of North Carolina, PLLC

Appendix A
Sampling Logs and Equipment
Documentation and Instrument
Calibration Data Sheets

Appendix B
Report of Laboratory Analysis and
Chain-of-Custody Documentation
ANALYTICAL REPORT
TestAmerica Laboratories, Inc.
TestAmerica Nashville
2960 Foster Creighton Drive
Nashville, TN 37204
Tel: [phone]
TestAmerica Job ID: 490-125629-1
Client Project/Site: Madison Co Operating Landfill
For:
Anchor QEA of North Carolina PLLC
231 W Haywood Street
Asheville, North Carolina 28801
Attn: Brian Gant
Authorized for release by:
4/26/2017 1:36:46 PM
Ken Hayes, Project Manager II
[phone]
[e-mail]
The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited
parameters, exceptions are noted in this report. This report may not be reproduced except in full,
and with written approval from the laboratory. For questions please contact the Project Manager
at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
TestAmerica Job ID: 490-125629-1
Page 2 of 60 TestAmerica Nashville4/26/2017
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .35
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .46
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .51
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .56
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .57
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .58
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .60
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Sample Summary
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID Client Sample ID ReceivedCollectedMatrix
490-125629-1 MW-01 Water 04/04/17 09:42 04/05/17 09:40
490-125629-2 MW-02 Water 04/03/17 10:26 04/05/17 09:40
490-125629-3 MW-03 Water 04/04/17 11:06 04/05/17 09:40
490-125629-4 MW-04 Water 04/04/17 12:02 04/05/17 09:40
490-125629-5 MW-05 Water 04/03/17 13:33 04/05/17 09:40
490-125629-6 MW-06R Water 04/04/17 13:35 04/05/17 09:40
490-125629-7 MW-07R Water 04/03/17 09:17 04/05/17 09:40
490-125629-8 MW-08 Water 04/03/17 11:45 04/05/17 09:40
490-125629-9 MW-09 Water 04/04/17 14:53 04/05/17 09:40
490-125629-10 Trip Blank Water 04/04/17 00:01 04/05/17 09:40
TestAmerica Nashville
Page 3 of 60 4/26/2017
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Case Narrative
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-125629-1
Project/Site: Madison Co Operating Landfill
Job ID: 490-125629-1
Laboratory: TestAmerica Nashville
Narrative
Job Narrative
490-125629-1
Comments
No additional comments.
Receipt
The samples were received on 4/5/2017 9:40 AM; the samples arrived in good condition, properly preserved and, where required, on ice.
The temperature of the cooler at receipt was 2.1º C.
GC/MS VOA
Method 8260B: The method blank for analytical batch 490-421467 contained Methylene Chloride above the method detection limit. This
target analyte concentration was less than the reporting limit (RL); therefore, re-extraction and/or re-analysis of samples was not
performed.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Metals
Method 6020B: The method blanks for 490-422781 and 490-423185 contained Vanadium and Zinc above the method detection limit
(MDL). Associated samples were not re-analyzed because results were less than the reporting limit (RL) OR practical quantitation limit
(PQL).
Method 7470A: The method blank for 490-421267 contained Mercury above the method detection limit. This target analyte concentration
was less than the reporting limit (RL); therefore, re-extraction and/or re-analysis of samples was not performed.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Field Service / Mobile Lab
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
VOA Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
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Definitions/Glossary
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Qualifiers
GC/MS VOA
Qualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Qualifier
Metals
Qualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Qualifier
F1 MS and/or MSD Recovery is outside acceptance limits.
B Compound was found in the blank and sample.
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CNF Contains no Free Liquid
DER Duplicate error ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision level concentration
MDA Minimum detectable activity
EDL Estimated Detection Limit
MDC Minimum detectable concentration
MDL Method Detection Limit
ML Minimum Level (Dioxin)
NC Not Calculated
ND Not detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit
QC Quality Control
RER Relative error ratio
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-1Client Sample ID: MW-01
Matrix: WaterDate Collected: 04/04/17 09:42
Date Received: 04/05/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 04/12/17 04:02 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
10.0 0.500 ug/L 04/12/17 04:02 1Acrylonitrile<0.500
1.00 0.200 ug/L 04/12/17 04:02 1Benzene<0.200
1.00 0.150 ug/L 04/12/17 04:02 1Bromochloromethane<0.150
1.00 0.170 ug/L 04/12/17 04:02 1Bromodichloromethane<0.170
1.00 0.290 ug/L 04/12/17 04:02 1Bromoform<0.290
1.00 0.350 ug/L 04/12/17 04:02 1Bromomethane<0.350
50.0 2.64 ug/L 04/12/17 04:02 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 04/12/17 04:02 1Carbon disulfide <0.220
1.00 0.180 ug/L 04/12/17 04:02 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 04/12/17 04:02 1Chlorobenzene<0.180
1.00 0.360 ug/L 04/12/17 04:02 1Chloroethane<0.360
1.00 0.230 ug/L 04/12/17 04:02 1Chloroform<0.230
1.00 0.360 ug/L 04/12/17 04:02 1Chloromethane<0.360
1.00 0.210 ug/L 04/12/17 04:02 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 04/12/17 04:02 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 04/12/17 04:02 1Dibromochloromethane<0.250
10.0 0.940 ug/L 04/12/17 04:02 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 04/12/17 04:02 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 04/12/17 04:02 1Dibromomethane<0.450
1.00 0.190 ug/L 04/12/17 04:02 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 04/12/17 04:02 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 04/12/17 04:02 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 04/12/17 04:02 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 04/12/17 04:02 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 04/12/17 04:02 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 04/12/17 04:02 1Ethylbenzene<0.190
10.0 1.28 ug/L 04/12/17 04:02 12-Hexanone <1.28
10.0 1.50 ug/L 04/12/17 04:02 1Iodomethane<1.50
5.00 1.00 ug/L 04/12/17 04:02 1Methylene Chloride <1.00
10.0 0.810 ug/L 04/12/17 04:02 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 04/12/17 04:02 1Styrene<0.280
1.00 0.150 ug/L 04/12/17 04:02 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 04/12/17 04:02 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 04/12/17 04:02 1Tetrachloroethene<0.140
10.0 0.820 ug/L 04/12/17 04:02 1Tetrahydrofuran<0.820
1.00 0.170 ug/L 04/12/17 04:02 1Toluene<0.170
5.00 0.460 ug/L 04/12/17 04:02 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 04/12/17 04:02 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 04/12/17 04:02 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 04/12/17 04:02 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 04/12/17 04:02 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 04/12/17 04:02 1Trichloroethene<0.200
1.00 0.210 ug/L 04/12/17 04:02 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 04/12/17 04:02 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 04/12/17 04:02 1Vinyl acetate <1.71
1.00 0.180 ug/L 04/12/17 04:02 1Vinyl chloride <0.180
3.00 0.580 ug/L 04/12/17 04:02 1Xylenes, Total <0.580
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-1Client Sample ID: MW-01
Matrix: WaterDate Collected: 04/04/17 09:42
Date Received: 04/05/17 09:40
4-Bromofluorobenzene (Surr)107 70-130 04/12/17 04:02 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)101 04/12/17 04:02 170-130
1,2-Dichloroethane-d4 (Surr)91 04/12/17 04:02 170-130
Toluene-d8 (Surr)96 04/12/17 04:02 170-130
Method: 6010D - Metals (ICP)
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/17/17 16:25 04/19/17 23:17 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/17/17 16:25 04/19/17 23:17 1Barium0.103
0.00100 0.000500 mg/L 04/17/17 16:25 04/19/17 23:17 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/17/17 16:25 04/19/17 23:17 1Chromium<0.00300
0.0100 0.00500 mg/L 04/17/17 16:25 04/19/17 23:17 1Copper<0.00500
0.00500 0.00200 mg/L 04/17/17 16:25 04/19/17 23:17 1Lead<0.00200
0.0100 0.00300 mg/L 04/17/17 16:25 04/19/17 23:17 1Nickel<0.00300
0.0100 0.00500 mg/L 04/17/17 16:25 04/19/17 23:17 1Selenium<0.00500
0.00500 0.00300 mg/L 04/17/17 16:25 04/19/17 23:17 1Silver<0.00300 F1
Method: 6010D - Metals (ICP) - Dissolved
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/12/17 19:03 04/13/17 14:27 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 14:27 1Barium0.0981
0.00100 0.000500 mg/L 04/12/17 19:03 04/13/17 14:27 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/12/17 19:03 04/13/17 14:27 1Chromium<0.00300
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 14:27 1Copper0.0117
0.00500 0.00200 mg/L 04/12/17 19:03 04/13/17 14:27 1Lead0.00330 J
0.0100 0.00300 mg/L 04/12/17 19:03 04/13/17 14:27 1Nickel<0.00300
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 14:27 1Selenium<0.00500
0.00500 0.00300 mg/L 04/12/17 19:03 04/13/17 14:27 1Silver<0.00300
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 04/18/17 20:08 04/23/17 15:19 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 15:19 1Beryllium<0.100
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 15:19 1Cobalt0.792 J
2.00 0.800 ug/L 04/18/17 20:08 04/23/17 15:19 1Thallium<0.800
2.00 0.700 ug/L 04/18/17 20:08 04/23/17 15:19 1Vanadium1.41 J B
25.0 5.20 ug/L 04/18/17 20:08 04/23/17 15:19 1Zinc12.3 J F1 B
Method: 6020B - Metals (ICP/MS) - Dissolved
RL MDL
Antimony <0.000800 0.00200 0.000800 mg/L 04/17/17 15:23 04/23/17 09:00 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.00200 0.000100 mg/L 04/17/17 15:23 04/23/17 09:00 1Beryllium<0.000100
0.00200 0.000100 mg/L 04/17/17 15:23 04/23/17 09:00 1Cobalt0.000813 J
0.00200 0.000800 mg/L 04/17/17 15:23 04/23/17 09:00 1Thallium<0.000800
0.00200 0.000700 mg/L 04/17/17 15:23 04/23/17 09:00 1Vanadium0.00132 J B
0.0250 0.00520 mg/L 04/17/17 15:23 04/23/17 09:00 1Zinc0.0188 J
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 04/11/17 09:07 04/11/17 16:41 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-1Client Sample ID: MW-01
Matrix: WaterDate Collected: 04/04/17 09:42
Date Received: 04/05/17 09:40
Method: 7470A - Mercury (CVAA) - Dissolved
RL MDL
Mercury <0.000100 0.000200 0.000100 mg/L 04/11/17 09:07 04/11/17 16:14 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-2Client Sample ID: MW-02
Matrix: WaterDate Collected: 04/03/17 10:26
Date Received: 04/05/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 04/12/17 04:27 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
10.0 0.500 ug/L 04/12/17 04:27 1Acrylonitrile<0.500
1.00 0.200 ug/L 04/12/17 04:27 1Benzene<0.200
1.00 0.150 ug/L 04/12/17 04:27 1Bromochloromethane<0.150
1.00 0.170 ug/L 04/12/17 04:27 1Bromodichloromethane<0.170
1.00 0.290 ug/L 04/12/17 04:27 1Bromoform<0.290
1.00 0.350 ug/L 04/12/17 04:27 1Bromomethane<0.350
50.0 2.64 ug/L 04/12/17 04:27 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 04/12/17 04:27 1Carbon disulfide <0.220
1.00 0.180 ug/L 04/12/17 04:27 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 04/12/17 04:27 1Chlorobenzene<0.180
1.00 0.360 ug/L 04/12/17 04:27 1Chloroethane<0.360
1.00 0.230 ug/L 04/12/17 04:27 1Chloroform<0.230
1.00 0.360 ug/L 04/12/17 04:27 1Chloromethane<0.360
1.00 0.210 ug/L 04/12/17 04:27 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 04/12/17 04:27 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 04/12/17 04:27 1Dibromochloromethane<0.250
10.0 0.940 ug/L 04/12/17 04:27 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 04/12/17 04:27 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 04/12/17 04:27 1Dibromomethane<0.450
1.00 0.190 ug/L 04/12/17 04:27 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 04/12/17 04:27 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 04/12/17 04:27 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 04/12/17 04:27 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 04/12/17 04:27 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 04/12/17 04:27 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 04/12/17 04:27 1Ethylbenzene<0.190
10.0 1.28 ug/L 04/12/17 04:27 12-Hexanone <1.28
10.0 1.50 ug/L 04/12/17 04:27 1Iodomethane<1.50
5.00 1.00 ug/L 04/12/17 04:27 1Methylene Chloride <1.00
10.0 0.810 ug/L 04/12/17 04:27 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 04/12/17 04:27 1Styrene<0.280
1.00 0.150 ug/L 04/12/17 04:27 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 04/12/17 04:27 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 04/12/17 04:27 1Tetrachloroethene<0.140
10.0 0.820 ug/L 04/12/17 04:27 1Tetrahydrofuran<0.820
1.00 0.170 ug/L 04/12/17 04:27 1Toluene<0.170
5.00 0.460 ug/L 04/12/17 04:27 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 04/12/17 04:27 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 04/12/17 04:27 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 04/12/17 04:27 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 04/12/17 04:27 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 04/12/17 04:27 1Trichloroethene<0.200
1.00 0.210 ug/L 04/12/17 04:27 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 04/12/17 04:27 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 04/12/17 04:27 1Vinyl acetate <1.71
1.00 0.180 ug/L 04/12/17 04:27 1Vinyl chloride <0.180
3.00 0.580 ug/L 04/12/17 04:27 1Xylenes, Total <0.580
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-2Client Sample ID: MW-02
Matrix: WaterDate Collected: 04/03/17 10:26
Date Received: 04/05/17 09:40
4-Bromofluorobenzene (Surr)103 70-130 04/12/17 04:27 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)101 04/12/17 04:27 170-130
1,2-Dichloroethane-d4 (Surr)92 04/12/17 04:27 170-130
Toluene-d8 (Surr)97 04/12/17 04:27 170-130
Method: 6010D - Metals (ICP)
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/17/17 16:25 04/19/17 23:57 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/17/17 16:25 04/19/17 23:57 1Barium0.0814
0.00100 0.000500 mg/L 04/17/17 16:25 04/19/17 23:57 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/17/17 16:25 04/19/17 23:57 1Chromium0.00490 J
0.0100 0.00500 mg/L 04/17/17 16:25 04/19/17 23:57 1Copper<0.00500
0.00500 0.00200 mg/L 04/17/17 16:25 04/19/17 23:57 1Lead<0.00200
0.0100 0.00300 mg/L 04/17/17 16:25 04/19/17 23:57 1Nickel<0.00300
0.0100 0.00500 mg/L 04/17/17 16:25 04/19/17 23:57 1Selenium<0.00500
0.00500 0.00300 mg/L 04/17/17 16:25 04/19/17 23:57 1Silver<0.00300
Method: 6010D - Metals (ICP) - Dissolved
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/12/17 19:03 04/13/17 15:02 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:02 1Barium0.0645
0.00100 0.000500 mg/L 04/12/17 19:03 04/13/17 15:02 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/12/17 19:03 04/13/17 15:02 1Chromium<0.00300
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:02 1Copper<0.00500
0.00500 0.00200 mg/L 04/12/17 19:03 04/13/17 15:02 1Lead0.00230 J
0.0100 0.00300 mg/L 04/12/17 19:03 04/13/17 15:02 1Nickel<0.00300
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:02 1Selenium<0.00500
0.00500 0.00300 mg/L 04/12/17 19:03 04/13/17 15:02 1Silver<0.00300
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 04/18/17 20:08 04/23/17 15:46 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 15:46 1Beryllium<0.100
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 15:46 1Cobalt3.18
2.00 0.800 ug/L 04/18/17 20:08 04/23/17 15:46 1Thallium<0.800
2.00 0.700 ug/L 04/18/17 20:08 04/23/17 15:46 1Vanadium13.4 B
25.0 5.20 ug/L 04/18/17 20:08 04/23/17 15:46 1Zinc<5.20
Method: 6020B - Metals (ICP/MS) - Dissolved
RL MDL
Antimony <0.000800 0.00200 0.000800 mg/L 04/17/17 15:23 04/23/17 09:06 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.00200 0.000100 mg/L 04/17/17 15:23 04/23/17 09:06 1Beryllium<0.000100
0.00200 0.000100 mg/L 04/17/17 15:23 04/23/17 09:06 1Cobalt0.00158 J
0.00200 0.000800 mg/L 04/17/17 15:23 04/23/17 09:06 1Thallium<0.000800
0.00200 0.000700 mg/L 04/17/17 15:23 04/23/17 09:06 1Vanadium0.00160 J B
0.0250 0.00520 mg/L 04/17/17 15:23 04/23/17 09:06 1Zinc0.0141 J
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 04/11/17 09:07 04/11/17 16:44 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-2Client Sample ID: MW-02
Matrix: WaterDate Collected: 04/03/17 10:26
Date Received: 04/05/17 09:40
Method: 7470A - Mercury (CVAA) - Dissolved
RL MDL
Mercury <0.000100 0.000200 0.000100 mg/L 04/11/17 09:07 04/11/17 16:16 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-3Client Sample ID: MW-03
Matrix: WaterDate Collected: 04/04/17 11:06
Date Received: 04/05/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone 3.81 J 25.0 2.66 ug/L 04/12/17 04:52 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
10.0 0.500 ug/L 04/12/17 04:52 1Acrylonitrile<0.500
1.00 0.200 ug/L 04/12/17 04:52 1Benzene<0.200
1.00 0.150 ug/L 04/12/17 04:52 1Bromochloromethane<0.150
1.00 0.170 ug/L 04/12/17 04:52 1Bromodichloromethane<0.170
1.00 0.290 ug/L 04/12/17 04:52 1Bromoform<0.290
1.00 0.350 ug/L 04/12/17 04:52 1Bromomethane<0.350
50.0 2.64 ug/L 04/12/17 04:52 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 04/12/17 04:52 1Carbon disulfide <0.220
1.00 0.180 ug/L 04/12/17 04:52 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 04/12/17 04:52 1Chlorobenzene<0.180
1.00 0.360 ug/L 04/12/17 04:52 1Chloroethane<0.360
1.00 0.230 ug/L 04/12/17 04:52 1Chloroform<0.230
1.00 0.360 ug/L 04/12/17 04:52 1Chloromethane<0.360
1.00 0.210 ug/L 04/12/17 04:52 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 04/12/17 04:52 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 04/12/17 04:52 1Dibromochloromethane<0.250
10.0 0.940 ug/L 04/12/17 04:52 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 04/12/17 04:52 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 04/12/17 04:52 1Dibromomethane<0.450
1.00 0.190 ug/L 04/12/17 04:52 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 04/12/17 04:52 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 04/12/17 04:52 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 04/12/17 04:52 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 04/12/17 04:52 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 04/12/17 04:52 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 04/12/17 04:52 1Ethylbenzene<0.190
10.0 1.28 ug/L 04/12/17 04:52 12-Hexanone <1.28
10.0 1.50 ug/L 04/12/17 04:52 1Iodomethane<1.50
5.00 1.00 ug/L 04/12/17 04:52 1Methylene Chloride <1.00
10.0 0.810 ug/L 04/12/17 04:52 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 04/12/17 04:52 1Styrene<0.280
1.00 0.150 ug/L 04/12/17 04:52 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 04/12/17 04:52 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 04/12/17 04:52 1Tetrachloroethene<0.140
10.0 0.820 ug/L 04/12/17 04:52 1Tetrahydrofuran<0.820
1.00 0.170 ug/L 04/12/17 04:52 1Toluene<0.170
5.00 0.460 ug/L 04/12/17 04:52 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 04/12/17 04:52 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 04/12/17 04:52 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 04/12/17 04:52 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 04/12/17 04:52 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 04/12/17 04:52 1Trichloroethene<0.200
1.00 0.210 ug/L 04/12/17 04:52 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 04/12/17 04:52 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 04/12/17 04:52 1Vinyl acetate <1.71
1.00 0.180 ug/L 04/12/17 04:52 1Vinyl chloride <0.180
3.00 0.580 ug/L 04/12/17 04:52 1Xylenes, Total <0.580
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-3Client Sample ID: MW-03
Matrix: WaterDate Collected: 04/04/17 11:06
Date Received: 04/05/17 09:40
4-Bromofluorobenzene (Surr)106 70-130 04/12/17 04:52 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)101 04/12/17 04:52 170-130
1,2-Dichloroethane-d4 (Surr)92 04/12/17 04:52 170-130
Toluene-d8 (Surr)99 04/12/17 04:52 170-130
Method: 6010D - Metals (ICP)
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/17/17 16:25 04/20/17 00:03 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:03 1Barium0.193
0.00100 0.000500 mg/L 04/17/17 16:25 04/20/17 00:03 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/17/17 16:25 04/20/17 00:03 1Chromium0.00430 J
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:03 1Copper<0.00500
0.00500 0.00200 mg/L 04/17/17 16:25 04/20/17 00:03 1Lead<0.00200
0.0100 0.00300 mg/L 04/17/17 16:25 04/20/17 00:03 1Nickel0.00380 J
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:03 1Selenium0.00730 J
0.00500 0.00300 mg/L 04/17/17 16:25 04/20/17 00:03 1Silver<0.00300
Method: 6010D - Metals (ICP) - Dissolved
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/12/17 19:03 04/13/17 15:07 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:07 1Barium0.194
0.00100 0.000500 mg/L 04/12/17 19:03 04/13/17 15:07 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/12/17 19:03 04/13/17 15:07 1Chromium0.00430 J
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:07 1Copper0.00520 J
0.00500 0.00200 mg/L 04/12/17 19:03 04/13/17 15:07 1Lead0.00560
0.0100 0.00300 mg/L 04/12/17 19:03 04/13/17 15:07 1Nickel0.00420 J
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:07 1Selenium0.00570 J
0.00500 0.00300 mg/L 04/12/17 19:03 04/13/17 15:07 1Silver<0.00300
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 04/18/17 20:08 04/23/17 15:51 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 15:51 1Beryllium<0.100
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 15:51 1Cobalt84.4
2.00 0.800 ug/L 04/18/17 20:08 04/23/17 15:51 1Thallium<0.800
2.00 0.700 ug/L 04/18/17 20:08 04/23/17 15:51 1Vanadium1.12 J B
25.0 5.20 ug/L 04/18/17 20:08 04/23/17 15:51 1Zinc<5.20
Method: 6020B - Metals (ICP/MS) - Dissolved
RL MDL
Antimony <0.000800 0.00200 0.000800 mg/L 04/17/17 15:23 04/23/17 09:11 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.00200 0.000100 mg/L 04/17/17 15:23 04/23/17 09:11 1Beryllium<0.000100
0.00200 0.000100 mg/L 04/17/17 15:23 04/23/17 09:11 1Cobalt0.0852
0.00200 0.000800 mg/L 04/17/17 15:23 04/23/17 09:11 1Thallium<0.000800
0.00200 0.000700 mg/L 04/17/17 15:23 04/23/17 09:11 1Vanadium0.00119 J B
0.0250 0.00520 mg/L 04/17/17 15:23 04/23/17 09:11 1Zinc0.0149 J
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 04/11/17 09:07 04/11/17 16:46 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-3Client Sample ID: MW-03
Matrix: WaterDate Collected: 04/04/17 11:06
Date Received: 04/05/17 09:40
Method: 7470A - Mercury (CVAA) - Dissolved
RL MDL
Mercury <0.000100 0.000200 0.000100 mg/L 04/11/17 09:07 04/11/17 16:19 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-4Client Sample ID: MW-04
Matrix: WaterDate Collected: 04/04/17 12:02
Date Received: 04/05/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 04/12/17 05:17 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
10.0 0.500 ug/L 04/12/17 05:17 1Acrylonitrile<0.500
1.00 0.200 ug/L 04/12/17 05:17 1Benzene<0.200
1.00 0.150 ug/L 04/12/17 05:17 1Bromochloromethane<0.150
1.00 0.170 ug/L 04/12/17 05:17 1Bromodichloromethane<0.170
1.00 0.290 ug/L 04/12/17 05:17 1Bromoform<0.290
1.00 0.350 ug/L 04/12/17 05:17 1Bromomethane<0.350
50.0 2.64 ug/L 04/12/17 05:17 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 04/12/17 05:17 1Carbon disulfide <0.220
1.00 0.180 ug/L 04/12/17 05:17 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 04/12/17 05:17 1Chlorobenzene<0.180
1.00 0.360 ug/L 04/12/17 05:17 1Chloroethane<0.360
1.00 0.230 ug/L 04/12/17 05:17 1Chloroform<0.230
1.00 0.360 ug/L 04/12/17 05:17 1Chloromethane<0.360
1.00 0.210 ug/L 04/12/17 05:17 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 04/12/17 05:17 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 04/12/17 05:17 1Dibromochloromethane<0.250
10.0 0.940 ug/L 04/12/17 05:17 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 04/12/17 05:17 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 04/12/17 05:17 1Dibromomethane<0.450
1.00 0.190 ug/L 04/12/17 05:17 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 04/12/17 05:17 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 04/12/17 05:17 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 04/12/17 05:17 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 04/12/17 05:17 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 04/12/17 05:17 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 04/12/17 05:17 1Ethylbenzene<0.190
10.0 1.28 ug/L 04/12/17 05:17 12-Hexanone <1.28
10.0 1.50 ug/L 04/12/17 05:17 1Iodomethane<1.50
5.00 1.00 ug/L 04/12/17 05:17 1Methylene Chloride <1.00
10.0 0.810 ug/L 04/12/17 05:17 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 04/12/17 05:17 1Styrene<0.280
1.00 0.150 ug/L 04/12/17 05:17 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 04/12/17 05:17 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 04/12/17 05:17 1Tetrachloroethene<0.140
10.0 0.820 ug/L 04/12/17 05:17 1Tetrahydrofuran<0.820
1.00 0.170 ug/L 04/12/17 05:17 1Toluene<0.170
5.00 0.460 ug/L 04/12/17 05:17 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 04/12/17 05:17 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 04/12/17 05:17 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 04/12/17 05:17 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 04/12/17 05:17 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 04/12/17 05:17 1Trichloroethene<0.200
1.00 0.210 ug/L 04/12/17 05:17 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 04/12/17 05:17 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 04/12/17 05:17 1Vinyl acetate <1.71
1.00 0.180 ug/L 04/12/17 05:17 1Vinyl chloride <0.180
3.00 0.580 ug/L 04/12/17 05:17 1Xylenes, Total <0.580
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-4Client Sample ID: MW-04
Matrix: WaterDate Collected: 04/04/17 12:02
Date Received: 04/05/17 09:40
4-Bromofluorobenzene (Surr)101 70-130 04/12/17 05:17 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)99 04/12/17 05:17 170-130
1,2-Dichloroethane-d4 (Surr)91 04/12/17 05:17 170-130
Toluene-d8 (Surr)97 04/12/17 05:17 170-130
Method: 6010D - Metals (ICP)
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/17/17 16:25 04/20/17 00:08 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:08 1Barium0.149
0.00100 0.000500 mg/L 04/17/17 16:25 04/20/17 00:08 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/17/17 16:25 04/20/17 00:08 1Chromium<0.00300
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:08 1Copper<0.00500
0.00500 0.00200 mg/L 04/17/17 16:25 04/20/17 00:08 1Lead<0.00200
0.0100 0.00300 mg/L 04/17/17 16:25 04/20/17 00:08 1Nickel<0.00300
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:08 1Selenium<0.00500
0.00500 0.00300 mg/L 04/17/17 16:25 04/20/17 00:08 1Silver<0.00300
Method: 6010D - Metals (ICP) - Dissolved
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/12/17 19:03 04/13/17 15:13 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:13 1Barium0.152
0.00100 0.000500 mg/L 04/12/17 19:03 04/13/17 15:13 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/12/17 19:03 04/13/17 15:13 1Chromium<0.00300
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:13 1Copper0.0122
0.00500 0.00200 mg/L 04/12/17 19:03 04/13/17 15:13 1Lead0.00570
0.0100 0.00300 mg/L 04/12/17 19:03 04/13/17 15:13 1Nickel<0.00300
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:13 1Selenium<0.00500
0.00500 0.00300 mg/L 04/12/17 19:03 04/13/17 15:13 1Silver<0.00300
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 04/18/17 20:08 04/23/17 15:57 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 15:57 1Beryllium<0.100
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 15:57 1Cobalt<0.100
2.00 0.800 ug/L 04/18/17 20:08 04/23/17 15:57 1Thallium<0.800
2.00 0.700 ug/L 04/18/17 20:08 04/23/17 15:57 1Vanadium4.90 B
25.0 5.20 ug/L 04/18/17 20:08 04/23/17 15:57 1Zinc<5.20
Method: 6020B - Metals (ICP/MS) - Dissolved
RL MDL
Antimony <0.000800 0.00200 0.000800 mg/L 04/17/17 15:23 04/23/17 08:33 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.00200 0.000100 mg/L 04/17/17 15:23 04/23/17 08:33 1Beryllium<0.000100
0.00200 0.000100 mg/L 04/17/17 15:23 04/23/17 08:33 1Cobalt<0.000100
0.00200 0.000800 mg/L 04/17/17 15:23 04/23/17 08:33 1Thallium<0.000800
0.00200 0.000700 mg/L 04/17/17 15:23 04/23/17 08:33 1Vanadium0.00476 B
0.0250 0.00520 mg/L 04/17/17 15:23 04/23/17 08:33 1Zinc0.0137 J
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 04/11/17 09:07 04/11/17 16:49 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-4Client Sample ID: MW-04
Matrix: WaterDate Collected: 04/04/17 12:02
Date Received: 04/05/17 09:40
Method: 7470A - Mercury (CVAA) - Dissolved
RL MDL
Mercury <0.000100 0.000200 0.000100 mg/L 04/11/17 09:07 04/11/17 16:22 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-5Client Sample ID: MW-05
Matrix: WaterDate Collected: 04/03/17 13:33
Date Received: 04/05/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone 2.66 J 25.0 2.66 ug/L 04/12/17 05:42 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
10.0 0.500 ug/L 04/12/17 05:42 1Acrylonitrile<0.500
1.00 0.200 ug/L 04/12/17 05:42 1Benzene0.234 J
1.00 0.150 ug/L 04/12/17 05:42 1Bromochloromethane<0.150
1.00 0.170 ug/L 04/12/17 05:42 1Bromodichloromethane<0.170
1.00 0.290 ug/L 04/12/17 05:42 1Bromoform<0.290
1.00 0.350 ug/L 04/12/17 05:42 1Bromomethane<0.350
50.0 2.64 ug/L 04/12/17 05:42 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 04/12/17 05:42 1Carbon disulfide <0.220
1.00 0.180 ug/L 04/12/17 05:42 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 04/12/17 05:42 1Chlorobenzene<0.180
1.00 0.360 ug/L 04/12/17 05:42 1Chloroethane<0.360
1.00 0.230 ug/L 04/12/17 05:42 1Chloroform<0.230
1.00 0.360 ug/L 04/12/17 05:42 1Chloromethane<0.360
1.00 0.210 ug/L 04/12/17 05:42 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 04/12/17 05:42 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 04/12/17 05:42 1Dibromochloromethane<0.250
10.0 0.940 ug/L 04/12/17 05:42 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 04/12/17 05:42 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 04/12/17 05:42 1Dibromomethane<0.450
1.00 0.190 ug/L 04/12/17 05:42 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 04/12/17 05:42 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 04/12/17 05:42 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 04/12/17 05:42 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 04/12/17 05:42 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 04/12/17 05:42 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 04/12/17 05:42 1Ethylbenzene<0.190
10.0 1.28 ug/L 04/12/17 05:42 12-Hexanone <1.28
10.0 1.50 ug/L 04/12/17 05:42 1Iodomethane<1.50
5.00 1.00 ug/L 04/12/17 05:42 1Methylene Chloride <1.00
10.0 0.810 ug/L 04/12/17 05:42 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 04/12/17 05:42 1Styrene<0.280
1.00 0.150 ug/L 04/12/17 05:42 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 04/12/17 05:42 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 04/12/17 05:42 1Tetrachloroethene<0.140
10.0 0.820 ug/L 04/12/17 05:42 1Tetrahydrofuran<0.820
1.00 0.170 ug/L 04/12/17 05:42 1Toluene<0.170
5.00 0.460 ug/L 04/12/17 05:42 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 04/12/17 05:42 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 04/12/17 05:42 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 04/12/17 05:42 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 04/12/17 05:42 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 04/12/17 05:42 1Trichloroethene<0.200
1.00 0.210 ug/L 04/12/17 05:42 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 04/12/17 05:42 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 04/12/17 05:42 1Vinyl acetate <1.71
1.00 0.180 ug/L 04/12/17 05:42 1Vinyl chloride <0.180
3.00 0.580 ug/L 04/12/17 05:42 1Xylenes, Total <0.580
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-5Client Sample ID: MW-05
Matrix: WaterDate Collected: 04/03/17 13:33
Date Received: 04/05/17 09:40
4-Bromofluorobenzene (Surr)103 70-130 04/12/17 05:42 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)104 04/12/17 05:42 170-130
1,2-Dichloroethane-d4 (Surr)93 04/12/17 05:42 170-130
Toluene-d8 (Surr)99 04/12/17 05:42 170-130
Method: 6010D - Metals (ICP)
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/17/17 16:25 04/20/17 00:13 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:13 1Barium0.133
0.00100 0.000500 mg/L 04/17/17 16:25 04/20/17 00:13 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/17/17 16:25 04/20/17 00:13 1Chromium<0.00300
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:13 1Copper<0.00500
0.00500 0.00200 mg/L 04/17/17 16:25 04/20/17 00:13 1Lead<0.00200
0.0100 0.00300 mg/L 04/17/17 16:25 04/20/17 00:13 1Nickel0.00490 J
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:13 1Selenium<0.00500
0.00500 0.00300 mg/L 04/17/17 16:25 04/20/17 00:13 1Silver<0.00300
Method: 6010D - Metals (ICP) - Dissolved
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/12/17 19:03 04/13/17 15:18 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:18 1Barium0.128
0.00100 0.000500 mg/L 04/12/17 19:03 04/13/17 15:18 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/12/17 19:03 04/13/17 15:18 1Chromium<0.00300
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:18 1Copper0.0145
0.00500 0.00200 mg/L 04/12/17 19:03 04/13/17 15:18 1Lead0.00540
0.0100 0.00300 mg/L 04/12/17 19:03 04/13/17 15:18 1Nickel0.00560 J
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:18 1Selenium<0.00500
0.00500 0.00300 mg/L 04/12/17 19:03 04/13/17 15:18 1Silver<0.00300
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 04/18/17 20:08 04/23/17 16:13 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 16:13 1Beryllium<0.100
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 16:13 1Cobalt0.731 J
2.00 0.800 ug/L 04/18/17 20:08 04/23/17 16:13 1Thallium<0.800
2.00 0.700 ug/L 04/18/17 20:08 04/23/17 16:13 1Vanadium5.04 B
25.0 5.20 ug/L 04/18/17 20:08 04/23/17 16:13 1Zinc5.75 J B
Method: 6020B - Metals (ICP/MS) - Dissolved
RL MDL
Antimony <0.000800 0.00200 0.000800 mg/L 04/17/17 15:23 04/23/17 09:28 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.00200 0.000100 mg/L 04/17/17 15:23 04/23/17 21:30 1Beryllium<0.000100
0.00200 0.000100 mg/L 04/17/17 15:23 04/23/17 09:28 1Cobalt0.000649 J
0.00200 0.000800 mg/L 04/17/17 15:23 04/23/17 09:28 1Thallium<0.000800
0.00200 0.000700 mg/L 04/17/17 15:23 04/23/17 09:28 1Vanadium0.00460 B
0.0250 0.00520 mg/L 04/17/17 15:23 04/23/17 09:28 1Zinc0.0194 J
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury 0.102 J B 0.200 0.100 ug/L 04/11/17 09:07 04/11/17 16:52 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-5Client Sample ID: MW-05
Matrix: WaterDate Collected: 04/03/17 13:33
Date Received: 04/05/17 09:40
Method: 7470A - Mercury (CVAA) - Dissolved
RL MDL
Mercury <0.000100 0.000200 0.000100 mg/L 04/11/17 09:07 04/11/17 16:25 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
TestAmerica Nashville
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-6Client Sample ID: MW-06R
Matrix: WaterDate Collected: 04/04/17 13:35
Date Received: 04/05/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone 4.19 J 25.0 2.66 ug/L 04/12/17 06:07 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
10.0 0.500 ug/L 04/12/17 06:07 1Acrylonitrile<0.500
1.00 0.200 ug/L 04/12/17 06:07 1Benzene<0.200
1.00 0.150 ug/L 04/12/17 06:07 1Bromochloromethane<0.150
1.00 0.170 ug/L 04/12/17 06:07 1Bromodichloromethane<0.170
1.00 0.290 ug/L 04/12/17 06:07 1Bromoform<0.290
1.00 0.350 ug/L 04/12/17 06:07 1Bromomethane<0.350
50.0 2.64 ug/L 04/12/17 06:07 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 04/12/17 06:07 1Carbon disulfide <0.220
1.00 0.180 ug/L 04/12/17 06:07 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 04/12/17 06:07 1Chlorobenzene<0.180
1.00 0.360 ug/L 04/12/17 06:07 1Chloroethane<0.360
1.00 0.230 ug/L 04/12/17 06:07 1Chloroform<0.230
1.00 0.360 ug/L 04/12/17 06:07 1Chloromethane<0.360
1.00 0.210 ug/L 04/12/17 06:07 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 04/12/17 06:07 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 04/12/17 06:07 1Dibromochloromethane<0.250
10.0 0.940 ug/L 04/12/17 06:07 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 04/12/17 06:07 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 04/12/17 06:07 1Dibromomethane<0.450
1.00 0.190 ug/L 04/12/17 06:07 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 04/12/17 06:07 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 04/12/17 06:07 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 04/12/17 06:07 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 04/12/17 06:07 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 04/12/17 06:07 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 04/12/17 06:07 1Ethylbenzene<0.190
10.0 1.28 ug/L 04/12/17 06:07 12-Hexanone <1.28
10.0 1.50 ug/L 04/12/17 06:07 1Iodomethane<1.50
5.00 1.00 ug/L 04/12/17 06:07 1Methylene Chloride <1.00
10.0 0.810 ug/L 04/12/17 06:07 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 04/12/17 06:07 1Styrene<0.280
1.00 0.150 ug/L 04/12/17 06:07 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 04/12/17 06:07 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 04/12/17 06:07 1Tetrachloroethene<0.140
10.0 0.820 ug/L 04/12/17 06:07 1Tetrahydrofuran<0.820
1.00 0.170 ug/L 04/12/17 06:07 1Toluene<0.170
5.00 0.460 ug/L 04/12/17 06:07 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 04/12/17 06:07 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 04/12/17 06:07 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 04/12/17 06:07 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 04/12/17 06:07 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 04/12/17 06:07 1Trichloroethene<0.200
1.00 0.210 ug/L 04/12/17 06:07 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 04/12/17 06:07 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 04/12/17 06:07 1Vinyl acetate <1.71
1.00 0.180 ug/L 04/12/17 06:07 1Vinyl chloride <0.180
3.00 0.580 ug/L 04/12/17 06:07 1Xylenes, Total <0.580
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-6Client Sample ID: MW-06R
Matrix: WaterDate Collected: 04/04/17 13:35
Date Received: 04/05/17 09:40
4-Bromofluorobenzene (Surr)106 70-130 04/12/17 06:07 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)104 04/12/17 06:07 170-130
1,2-Dichloroethane-d4 (Surr)95 04/12/17 06:07 170-130
Toluene-d8 (Surr)98 04/12/17 06:07 170-130
Method: 6010D - Metals (ICP)
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/17/17 16:25 04/20/17 00:18 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:18 1Barium0.0254
0.00100 0.000500 mg/L 04/17/17 16:25 04/20/17 00:18 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/17/17 16:25 04/20/17 00:18 1Chromium<0.00300
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:18 1Copper<0.00500
0.00500 0.00200 mg/L 04/17/17 16:25 04/20/17 00:18 1Lead<0.00200
0.0100 0.00300 mg/L 04/17/17 16:25 04/20/17 00:18 1Nickel<0.00300
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:18 1Selenium<0.00500
0.00500 0.00300 mg/L 04/17/17 16:25 04/20/17 00:18 1Silver<0.00300
Method: 6010D - Metals (ICP) - Dissolved
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/12/17 19:03 04/13/17 15:23 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:23 1Barium0.0249
0.00100 0.000500 mg/L 04/12/17 19:03 04/13/17 15:23 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/12/17 19:03 04/13/17 15:23 1Chromium<0.00300
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:23 1Copper0.0123
0.00500 0.00200 mg/L 04/12/17 19:03 04/13/17 15:23 1Lead0.00430 J
0.0100 0.00300 mg/L 04/12/17 19:03 04/13/17 15:23 1Nickel<0.00300
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:23 1Selenium<0.00500
0.00500 0.00300 mg/L 04/12/17 19:03 04/13/17 15:23 1Silver<0.00300
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 04/18/17 20:08 04/23/17 16:19 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 16:19 1Beryllium<0.100
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 16:19 1Cobalt<0.100
2.00 0.800 ug/L 04/18/17 20:08 04/23/17 16:19 1Thallium<0.800
2.00 0.700 ug/L 04/18/17 20:08 04/23/17 16:19 1Vanadium1.52 J B
25.0 5.20 ug/L 04/18/17 20:08 04/23/17 16:19 1Zinc<5.20
Method: 6020B - Metals (ICP/MS) - Dissolved
RL MDL
Antimony <0.000800 0.00200 0.000800 mg/L 04/17/17 15:23 04/23/17 09:33 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.00200 0.000100 mg/L 04/17/17 15:23 04/23/17 21:35 1Beryllium<0.000100
0.00200 0.000100 mg/L 04/17/17 15:23 04/23/17 09:33 1Cobalt<0.000100
0.00200 0.000800 mg/L 04/17/17 15:23 04/23/17 09:33 1Thallium<0.000800
0.00200 0.000700 mg/L 04/17/17 15:23 04/23/17 09:33 1Vanadium0.00163 J B
0.0250 0.00520 mg/L 04/17/17 15:23 04/23/17 09:33 1Zinc0.0173 J
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 04/11/17 09:07 04/11/17 16:55 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-6Client Sample ID: MW-06R
Matrix: WaterDate Collected: 04/04/17 13:35
Date Received: 04/05/17 09:40
Method: 7470A - Mercury (CVAA) - Dissolved
RL MDL
Mercury <0.000100 0.000200 0.000100 mg/L 04/11/17 09:07 04/11/17 16:27 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
TestAmerica Nashville
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-7Client Sample ID: MW-07R
Matrix: WaterDate Collected: 04/03/17 09:17
Date Received: 04/05/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 04/12/17 06:32 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
10.0 0.500 ug/L 04/12/17 06:32 1Acrylonitrile<0.500
1.00 0.200 ug/L 04/12/17 06:32 1Benzene<0.200
1.00 0.150 ug/L 04/12/17 06:32 1Bromochloromethane<0.150
1.00 0.170 ug/L 04/12/17 06:32 1Bromodichloromethane<0.170
1.00 0.290 ug/L 04/12/17 06:32 1Bromoform<0.290
1.00 0.350 ug/L 04/12/17 06:32 1Bromomethane<0.350
50.0 2.64 ug/L 04/12/17 06:32 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 04/12/17 06:32 1Carbon disulfide <0.220
1.00 0.180 ug/L 04/12/17 06:32 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 04/12/17 06:32 1Chlorobenzene<0.180
1.00 0.360 ug/L 04/12/17 06:32 1Chloroethane<0.360
1.00 0.230 ug/L 04/12/17 06:32 1Chloroform<0.230
1.00 0.360 ug/L 04/12/17 06:32 1Chloromethane<0.360
1.00 0.210 ug/L 04/12/17 06:32 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 04/12/17 06:32 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 04/12/17 06:32 1Dibromochloromethane<0.250
10.0 0.940 ug/L 04/12/17 06:32 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 04/12/17 06:32 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 04/12/17 06:32 1Dibromomethane<0.450
1.00 0.190 ug/L 04/12/17 06:32 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 04/12/17 06:32 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 04/12/17 06:32 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 04/12/17 06:32 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 04/12/17 06:32 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 04/12/17 06:32 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 04/12/17 06:32 1Ethylbenzene<0.190
10.0 1.28 ug/L 04/12/17 06:32 12-Hexanone <1.28
10.0 1.50 ug/L 04/12/17 06:32 1Iodomethane<1.50
5.00 1.00 ug/L 04/12/17 06:32 1Methylene Chloride <1.00
10.0 0.810 ug/L 04/12/17 06:32 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 04/12/17 06:32 1Styrene<0.280
1.00 0.150 ug/L 04/12/17 06:32 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 04/12/17 06:32 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 04/12/17 06:32 1Tetrachloroethene<0.140
10.0 0.820 ug/L 04/12/17 06:32 1Tetrahydrofuran<0.820
1.00 0.170 ug/L 04/12/17 06:32 1Toluene<0.170
5.00 0.460 ug/L 04/12/17 06:32 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 04/12/17 06:32 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 04/12/17 06:32 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 04/12/17 06:32 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 04/12/17 06:32 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 04/12/17 06:32 1Trichloroethene<0.200
1.00 0.210 ug/L 04/12/17 06:32 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 04/12/17 06:32 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 04/12/17 06:32 1Vinyl acetate <1.71
1.00 0.180 ug/L 04/12/17 06:32 1Vinyl chloride <0.180
3.00 0.580 ug/L 04/12/17 06:32 1Xylenes, Total <0.580
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-7Client Sample ID: MW-07R
Matrix: WaterDate Collected: 04/03/17 09:17
Date Received: 04/05/17 09:40
4-Bromofluorobenzene (Surr)106 70-130 04/12/17 06:32 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)104 04/12/17 06:32 170-130
1,2-Dichloroethane-d4 (Surr)94 04/12/17 06:32 170-130
Toluene-d8 (Surr)95 04/12/17 06:32 170-130
Method: 6010D - Metals (ICP)
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/17/17 16:25 04/20/17 00:24 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:24 1Barium0.178
0.00100 0.000500 mg/L 04/17/17 16:25 04/20/17 00:24 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/17/17 16:25 04/20/17 00:24 1Chromium0.00760
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:24 1Copper<0.00500
0.00500 0.00200 mg/L 04/17/17 16:25 04/20/17 00:24 1Lead<0.00200
0.0100 0.00300 mg/L 04/17/17 16:25 04/20/17 00:24 1Nickel0.00380 J
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:24 1Selenium<0.00500
0.00500 0.00300 mg/L 04/17/17 16:25 04/20/17 00:24 1Silver<0.00300
Method: 6010D - Metals (ICP) - Dissolved
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/12/17 19:03 04/13/17 15:50 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:50 1Barium0.0976
0.00100 0.000500 mg/L 04/12/17 19:03 04/13/17 15:50 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/12/17 19:03 04/13/17 15:50 1Chromium<0.00300
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:50 1Copper0.0103
0.00500 0.00200 mg/L 04/12/17 19:03 04/13/17 15:50 1Lead0.00470 J
0.0100 0.00300 mg/L 04/12/17 19:03 04/13/17 15:50 1Nickel<0.00300
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:50 1Selenium<0.00500
0.00500 0.00300 mg/L 04/12/17 19:03 04/13/17 15:50 1Silver<0.00300
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 04/18/17 20:08 04/23/17 16:24 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 16:24 1Beryllium0.301 J
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 16:24 1Cobalt2.25
2.00 0.800 ug/L 04/18/17 20:08 04/23/17 16:24 1Thallium<0.800
2.00 0.700 ug/L 04/18/17 20:08 04/23/17 16:24 1Vanadium11.0 B
25.0 5.20 ug/L 04/18/17 20:08 04/23/17 16:24 1Zinc12.5 J B
Method: 6020B - Metals (ICP/MS) - Dissolved
RL MDL
Antimony <0.000800 0.00200 0.000800 mg/L 04/17/17 15:23 04/23/17 09:39 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.00200 0.000100 mg/L 04/17/17 15:23 04/23/17 21:41 1Beryllium<0.000100
0.00200 0.000100 mg/L 04/17/17 15:23 04/23/17 09:39 1Cobalt<0.000100
0.00200 0.000800 mg/L 04/17/17 15:23 04/23/17 09:39 1Thallium<0.000800
0.00200 0.000700 mg/L 04/17/17 15:23 04/23/17 09:39 1Vanadium0.00169 J B
0.0250 0.00520 mg/L 04/17/17 15:23 04/23/17 09:39 1Zinc0.0181 J
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 04/11/17 09:07 04/11/17 16:57 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-7Client Sample ID: MW-07R
Matrix: WaterDate Collected: 04/03/17 09:17
Date Received: 04/05/17 09:40
Method: 7470A - Mercury (CVAA) - Dissolved
RL MDL
Mercury <0.000100 0.000200 0.000100 mg/L 04/11/17 09:07 04/11/17 16:36 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
TestAmerica Nashville
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-8Client Sample ID: MW-08
Matrix: WaterDate Collected: 04/03/17 11:45
Date Received: 04/05/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 04/12/17 06:57 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
10.0 0.500 ug/L 04/12/17 06:57 1Acrylonitrile<0.500
1.00 0.200 ug/L 04/12/17 06:57 1Benzene<0.200
1.00 0.150 ug/L 04/12/17 06:57 1Bromochloromethane<0.150
1.00 0.170 ug/L 04/12/17 06:57 1Bromodichloromethane<0.170
1.00 0.290 ug/L 04/12/17 06:57 1Bromoform<0.290
1.00 0.350 ug/L 04/12/17 06:57 1Bromomethane<0.350
50.0 2.64 ug/L 04/12/17 06:57 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 04/12/17 06:57 1Carbon disulfide <0.220
1.00 0.180 ug/L 04/12/17 06:57 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 04/12/17 06:57 1Chlorobenzene<0.180
1.00 0.360 ug/L 04/12/17 06:57 1Chloroethane<0.360
1.00 0.230 ug/L 04/12/17 06:57 1Chloroform<0.230
1.00 0.360 ug/L 04/12/17 06:57 1Chloromethane<0.360
1.00 0.210 ug/L 04/12/17 06:57 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 04/12/17 06:57 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 04/12/17 06:57 1Dibromochloromethane<0.250
10.0 0.940 ug/L 04/12/17 06:57 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 04/12/17 06:57 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 04/12/17 06:57 1Dibromomethane<0.450
1.00 0.190 ug/L 04/12/17 06:57 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 04/12/17 06:57 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 04/12/17 06:57 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 04/12/17 06:57 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 04/12/17 06:57 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 04/12/17 06:57 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 04/12/17 06:57 1Ethylbenzene<0.190
10.0 1.28 ug/L 04/12/17 06:57 12-Hexanone <1.28
10.0 1.50 ug/L 04/12/17 06:57 1Iodomethane<1.50
5.00 1.00 ug/L 04/12/17 06:57 1Methylene Chloride <1.00
10.0 0.810 ug/L 04/12/17 06:57 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 04/12/17 06:57 1Styrene<0.280
1.00 0.150 ug/L 04/12/17 06:57 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 04/12/17 06:57 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 04/12/17 06:57 1Tetrachloroethene<0.140
10.0 0.820 ug/L 04/12/17 06:57 1Tetrahydrofuran<0.820
1.00 0.170 ug/L 04/12/17 06:57 1Toluene<0.170
5.00 0.460 ug/L 04/12/17 06:57 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 04/12/17 06:57 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 04/12/17 06:57 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 04/12/17 06:57 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 04/12/17 06:57 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 04/12/17 06:57 1Trichloroethene<0.200
1.00 0.210 ug/L 04/12/17 06:57 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 04/12/17 06:57 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 04/12/17 06:57 1Vinyl acetate <1.71
1.00 0.180 ug/L 04/12/17 06:57 1Vinyl chloride <0.180
3.00 0.580 ug/L 04/12/17 06:57 1Xylenes, Total <0.580
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-8Client Sample ID: MW-08
Matrix: WaterDate Collected: 04/03/17 11:45
Date Received: 04/05/17 09:40
4-Bromofluorobenzene (Surr)105 70-130 04/12/17 06:57 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)103 04/12/17 06:57 170-130
1,2-Dichloroethane-d4 (Surr)95 04/12/17 06:57 170-130
Toluene-d8 (Surr)97 04/12/17 06:57 170-130
Method: 6010D - Metals (ICP)
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/17/17 16:25 04/20/17 00:29 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:29 1Barium0.0316
0.00100 0.000500 mg/L 04/17/17 16:25 04/20/17 00:29 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/17/17 16:25 04/20/17 00:29 1Chromium<0.00300
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:29 1Copper<0.00500
0.00500 0.00200 mg/L 04/17/17 16:25 04/20/17 00:29 1Lead0.00200 J
0.0100 0.00300 mg/L 04/17/17 16:25 04/20/17 00:29 1Nickel<0.00300
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:29 1Selenium<0.00500
0.00500 0.00300 mg/L 04/17/17 16:25 04/20/17 00:29 1Silver<0.00300
Method: 6010D - Metals (ICP) - Dissolved
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/12/17 19:03 04/13/17 15:55 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:55 1Barium0.0285
0.00100 0.000500 mg/L 04/12/17 19:03 04/13/17 15:55 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/12/17 19:03 04/13/17 15:55 1Chromium<0.00300
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:55 1Copper0.0117
0.00500 0.00200 mg/L 04/12/17 19:03 04/13/17 15:55 1Lead0.00680
0.0100 0.00300 mg/L 04/12/17 19:03 04/13/17 15:55 1Nickel<0.00300
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 15:55 1Selenium<0.00500
0.00500 0.00300 mg/L 04/12/17 19:03 04/13/17 15:55 1Silver<0.00300
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 04/18/17 20:08 04/23/17 16:30 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 16:30 1Beryllium<0.100
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 16:30 1Cobalt0.288 J
2.00 0.800 ug/L 04/18/17 20:08 04/23/17 16:30 1Thallium<0.800
2.00 0.700 ug/L 04/18/17 20:08 04/23/17 16:30 1Vanadium4.02 B
25.0 5.20 ug/L 04/18/17 20:08 04/23/17 16:30 1Zinc7.84 J B
Method: 6020B - Metals (ICP/MS) - Dissolved
RL MDL
Antimony <0.000800 0.00200 0.000800 mg/L 04/17/17 15:23 04/23/17 09:44 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.00200 0.000100 mg/L 04/17/17 15:23 04/23/17 21:46 1Beryllium<0.000100
0.00200 0.000100 mg/L 04/17/17 15:23 04/23/17 09:44 1Cobalt<0.000100
0.00200 0.000800 mg/L 04/17/17 15:23 04/23/17 09:44 1Thallium<0.000800
0.00200 0.000700 mg/L 04/17/17 15:23 04/23/17 09:44 1Vanadium0.00403 B
0.0250 0.00520 mg/L 04/17/17 15:23 04/23/17 09:44 1Zinc0.0179 J
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 04/11/17 09:07 04/11/17 17:00 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-8Client Sample ID: MW-08
Matrix: WaterDate Collected: 04/03/17 11:45
Date Received: 04/05/17 09:40
Method: 7470A - Mercury (CVAA) - Dissolved
RL MDL
Mercury <0.000100 0.000200 0.000100 mg/L 04/11/17 09:07 04/11/17 16:38 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
TestAmerica Nashville
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-9Client Sample ID: MW-09
Matrix: WaterDate Collected: 04/04/17 14:53
Date Received: 04/05/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone 4.61 J 25.0 2.66 ug/L 04/12/17 07:23 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
10.0 0.500 ug/L 04/12/17 07:23 1Acrylonitrile<0.500
1.00 0.200 ug/L 04/12/17 07:23 1Benzene<0.200
1.00 0.150 ug/L 04/12/17 07:23 1Bromochloromethane<0.150
1.00 0.170 ug/L 04/12/17 07:23 1Bromodichloromethane<0.170
1.00 0.290 ug/L 04/12/17 07:23 1Bromoform<0.290
1.00 0.350 ug/L 04/12/17 07:23 1Bromomethane<0.350
50.0 2.64 ug/L 04/12/17 07:23 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 04/12/17 07:23 1Carbon disulfide <0.220
1.00 0.180 ug/L 04/12/17 07:23 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 04/12/17 07:23 1Chlorobenzene<0.180
1.00 0.360 ug/L 04/12/17 07:23 1Chloroethane<0.360
1.00 0.230 ug/L 04/12/17 07:23 1Chloroform<0.230
1.00 0.360 ug/L 04/12/17 07:23 1Chloromethane<0.360
1.00 0.210 ug/L 04/12/17 07:23 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 04/12/17 07:23 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 04/12/17 07:23 1Dibromochloromethane<0.250
10.0 0.940 ug/L 04/12/17 07:23 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 04/12/17 07:23 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 04/12/17 07:23 1Dibromomethane<0.450
1.00 0.190 ug/L 04/12/17 07:23 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 04/12/17 07:23 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 04/12/17 07:23 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 04/12/17 07:23 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 04/12/17 07:23 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 04/12/17 07:23 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 04/12/17 07:23 1Ethylbenzene<0.190
10.0 1.28 ug/L 04/12/17 07:23 12-Hexanone <1.28
10.0 1.50 ug/L 04/12/17 07:23 1Iodomethane<1.50
5.00 1.00 ug/L 04/12/17 07:23 1Methylene Chloride <1.00
10.0 0.810 ug/L 04/12/17 07:23 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 04/12/17 07:23 1Styrene<0.280
1.00 0.150 ug/L 04/12/17 07:23 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 04/12/17 07:23 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 04/12/17 07:23 1Tetrachloroethene<0.140
10.0 0.820 ug/L 04/12/17 07:23 1Tetrahydrofuran<0.820
1.00 0.170 ug/L 04/12/17 07:23 1Toluene<0.170
5.00 0.460 ug/L 04/12/17 07:23 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 04/12/17 07:23 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 04/12/17 07:23 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 04/12/17 07:23 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 04/12/17 07:23 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 04/12/17 07:23 1Trichloroethene<0.200
1.00 0.210 ug/L 04/12/17 07:23 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 04/12/17 07:23 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 04/12/17 07:23 1Vinyl acetate <1.71
1.00 0.180 ug/L 04/12/17 07:23 1Vinyl chloride <0.180
3.00 0.580 ug/L 04/12/17 07:23 1Xylenes, Total <0.580
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-9Client Sample ID: MW-09
Matrix: WaterDate Collected: 04/04/17 14:53
Date Received: 04/05/17 09:40
4-Bromofluorobenzene (Surr)108 70-130 04/12/17 07:23 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)103 04/12/17 07:23 170-130
1,2-Dichloroethane-d4 (Surr)93 04/12/17 07:23 170-130
Toluene-d8 (Surr)97 04/12/17 07:23 170-130
Method: 6010D - Metals (ICP)
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/17/17 16:25 04/20/17 00:34 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:34 1Barium0.159
0.00100 0.000500 mg/L 04/17/17 16:25 04/20/17 00:34 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/17/17 16:25 04/20/17 00:34 1Chromium<0.00300
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:34 1Copper<0.00500
0.00500 0.00200 mg/L 04/17/17 16:25 04/20/17 00:34 1Lead<0.00200
0.0100 0.00300 mg/L 04/17/17 16:25 04/20/17 00:34 1Nickel<0.00300
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:34 1Selenium<0.00500
0.00500 0.00300 mg/L 04/17/17 16:25 04/20/17 00:34 1Silver<0.00300
Method: 6010D - Metals (ICP) - Dissolved
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/12/17 19:03 04/13/17 16:01 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 16:01 1Barium0.155
0.00100 0.000500 mg/L 04/12/17 19:03 04/13/17 16:01 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/12/17 19:03 04/13/17 16:01 1Chromium<0.00300
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 16:01 1Copper0.0134
0.00500 0.00200 mg/L 04/12/17 19:03 04/13/17 16:01 1Lead0.00630
0.0100 0.00300 mg/L 04/12/17 19:03 04/13/17 16:01 1Nickel<0.00300
0.0100 0.00500 mg/L 04/12/17 19:03 04/13/17 16:01 1Selenium<0.00500
0.00500 0.00300 mg/L 04/12/17 19:03 04/13/17 16:01 1Silver<0.00300
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 04/18/17 20:08 04/23/17 16:35 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 16:35 1Beryllium<0.100
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 16:35 1Cobalt0.133 J
2.00 0.800 ug/L 04/18/17 20:08 04/23/17 16:35 1Thallium<0.800
2.00 0.700 ug/L 04/18/17 20:08 04/23/17 16:35 1Vanadium2.02 B
25.0 5.20 ug/L 04/18/17 20:08 04/23/17 16:35 1Zinc<5.20
Method: 6020B - Metals (ICP/MS) - Dissolved
RL MDL
Antimony <0.000800 0.00200 0.000800 mg/L 04/17/17 15:23 04/23/17 09:50 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.00200 0.000100 mg/L 04/17/17 15:23 04/23/17 21:52 1Beryllium<0.000100
0.00200 0.000100 mg/L 04/17/17 15:23 04/23/17 09:50 1Cobalt<0.000100
0.00200 0.000800 mg/L 04/17/17 15:23 04/23/17 09:50 1Thallium<0.000800
0.00200 0.000700 mg/L 04/17/17 15:23 04/23/17 09:50 1Vanadium0.00228 B
0.0250 0.00520 mg/L 04/17/17 15:23 04/23/17 09:50 1Zinc0.0187 J
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 04/12/17 09:48 04/12/17 14:03 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-9Client Sample ID: MW-09
Matrix: WaterDate Collected: 04/04/17 14:53
Date Received: 04/05/17 09:40
Method: 7470A - Mercury (CVAA) - Dissolved
RL MDL
Mercury <0.000100 0.000200 0.000100 mg/L 04/12/17 09:48 04/12/17 14:01 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-10Client Sample ID: Trip Blank
Matrix: WaterDate Collected: 04/04/17 00:01
Date Received: 04/05/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone 3.48 J 25.0 2.66 ug/L 04/12/17 01:56 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
10.0 0.500 ug/L 04/12/17 01:56 1Acrylonitrile<0.500
1.00 0.200 ug/L 04/12/17 01:56 1Benzene<0.200
1.00 0.150 ug/L 04/12/17 01:56 1Bromochloromethane<0.150
1.00 0.170 ug/L 04/12/17 01:56 1Bromodichloromethane<0.170
1.00 0.290 ug/L 04/12/17 01:56 1Bromoform<0.290
1.00 0.350 ug/L 04/12/17 01:56 1Bromomethane<0.350
50.0 2.64 ug/L 04/12/17 01:56 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 04/12/17 01:56 1Carbon disulfide <0.220
1.00 0.180 ug/L 04/12/17 01:56 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 04/12/17 01:56 1Chlorobenzene<0.180
1.00 0.360 ug/L 04/12/17 01:56 1Chloroethane<0.360
1.00 0.230 ug/L 04/12/17 01:56 1Chloroform<0.230
1.00 0.360 ug/L 04/12/17 01:56 1Chloromethane<0.360
1.00 0.210 ug/L 04/12/17 01:56 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 04/12/17 01:56 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 04/12/17 01:56 1Dibromochloromethane<0.250
10.0 0.940 ug/L 04/12/17 01:56 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 04/12/17 01:56 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 04/12/17 01:56 1Dibromomethane<0.450
1.00 0.190 ug/L 04/12/17 01:56 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 04/12/17 01:56 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 04/12/17 01:56 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 04/12/17 01:56 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 04/12/17 01:56 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 04/12/17 01:56 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 04/12/17 01:56 1Ethylbenzene<0.190
10.0 1.28 ug/L 04/12/17 01:56 12-Hexanone <1.28
10.0 1.50 ug/L 04/12/17 01:56 1Iodomethane<1.50
5.00 1.00 ug/L 04/12/17 01:56 1Methylene Chloride <1.00
10.0 0.810 ug/L 04/12/17 01:56 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 04/12/17 01:56 1Styrene<0.280
1.00 0.150 ug/L 04/12/17 01:56 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 04/12/17 01:56 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 04/12/17 01:56 1Tetrachloroethene<0.140
10.0 0.820 ug/L 04/12/17 01:56 1Tetrahydrofuran<0.820
1.00 0.170 ug/L 04/12/17 01:56 1Toluene<0.170
5.00 0.460 ug/L 04/12/17 01:56 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 04/12/17 01:56 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 04/12/17 01:56 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 04/12/17 01:56 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 04/12/17 01:56 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 04/12/17 01:56 1Trichloroethene<0.200
1.00 0.210 ug/L 04/12/17 01:56 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 04/12/17 01:56 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 04/12/17 01:56 1Vinyl acetate <1.71
1.00 0.180 ug/L 04/12/17 01:56 1Vinyl chloride <0.180
3.00 0.580 ug/L 04/12/17 01:56 1Xylenes, Total <0.580
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Client Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125629-10Client Sample ID: Trip Blank
Matrix: WaterDate Collected: 04/04/17 00:01
Date Received: 04/05/17 09:40
4-Bromofluorobenzene (Surr)104 70-130 04/12/17 01:56 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)102 04/12/17 01:56 170-130
1,2-Dichloroethane-d4 (Surr)94 04/12/17 01:56 170-130
Toluene-d8 (Surr)96 04/12/17 01:56 170-130
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Page 34 of 60 4/26/2017
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QC Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS)
Client Sample ID: Method BlankLab Sample ID: MB 490-421467/7
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421467
RL MDL
Acetone <2.66 25.0 2.66 ug/L 04/12/17 01:06 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<0.500 0.50010.0 ug/L 04/12/17 01:06 1Acrylonitrile
<0.200 0.2001.00 ug/L 04/12/17 01:06 1Benzene
<0.150 0.1501.00 ug/L 04/12/17 01:06 1Bromochloromethane
<0.170 0.1701.00 ug/L 04/12/17 01:06 1Bromodichloromethane
<0.290 0.2901.00 ug/L 04/12/17 01:06 1Bromoform
<0.350 0.3501.00 ug/L 04/12/17 01:06 1Bromomethane
<2.64 2.6450.0 ug/L 04/12/17 01:06 12-Butanone (MEK)
<0.220 0.2201.00 ug/L 04/12/17 01:06 1Carbon disulfide
<0.180 0.1801.00 ug/L 04/12/17 01:06 1Carbon tetrachloride
<0.180 0.1801.00 ug/L 04/12/17 01:06 1Chlorobenzene
<0.360 0.3601.00 ug/L 04/12/17 01:06 1Chloroethane
<0.230 0.2301.00 ug/L 04/12/17 01:06 1Chloroform
<0.360 0.3601.00 ug/L 04/12/17 01:06 1Chloromethane
<0.210 0.2101.00 ug/L 04/12/17 01:06 1cis-1,2-Dichloroethene
<0.170 0.1701.00 ug/L 04/12/17 01:06 1cis-1,3-Dichloropropene
<0.250 0.2501.00 ug/L 04/12/17 01:06 1Dibromochloromethane
<0.940 0.94010.0 ug/L 04/12/17 01:06 11,2-Dibromo-3-Chloropropane
<0.210 0.2101.00 ug/L 04/12/17 01:06 11,2-Dibromoethane (EDB)
<0.450 0.4501.00 ug/L 04/12/17 01:06 1Dibromomethane
<0.190 0.1901.00 ug/L 04/12/17 01:06 11,2-Dichlorobenzene
<0.170 0.1701.00 ug/L 04/12/17 01:06 11,4-Dichlorobenzene
<0.240 0.2401.00 ug/L 04/12/17 01:06 11,1-Dichloroethane
<0.200 0.2001.00 ug/L 04/12/17 01:06 11,2-Dichloroethane
<0.250 0.2501.00 ug/L 04/12/17 01:06 11,1-Dichloroethene
<0.250 0.2501.00 ug/L 04/12/17 01:06 11,2-Dichloropropane
<0.190 0.1901.00 ug/L 04/12/17 01:06 1Ethylbenzene
<1.28 1.2810.0 ug/L 04/12/17 01:06 12-Hexanone
<1.50 1.5010.0 ug/L 04/12/17 01:06 1Iodomethane
1.127 J 1.005.00 ug/L 04/12/17 01:06 1Methylene Chloride
<0.810 0.81010.0 ug/L 04/12/17 01:06 14-Methyl-2-pentanone (MIBK)
<0.280 0.2801.00 ug/L 04/12/17 01:06 1Styrene
<0.150 0.1501.00 ug/L 04/12/17 01:06 11,1,1,2-Tetrachloroethane
<0.190 0.1901.00 ug/L 04/12/17 01:06 11,1,2,2-Tetrachloroethane
<0.140 0.1401.00 ug/L 04/12/17 01:06 1Tetrachloroethene
<0.820 0.82010.0 ug/L 04/12/17 01:06 1Tetrahydrofuran
<0.170 0.1701.00 ug/L 04/12/17 01:06 1Toluene
<0.460 0.4605.00 ug/L 04/12/17 01:06 1trans-1,4-Dichloro-2-butene
<0.230 0.2301.00 ug/L 04/12/17 01:06 1trans-1,2-Dichloroethene
<0.170 0.1701.00 ug/L 04/12/17 01:06 1trans-1,3-Dichloropropene
<0.190 0.1901.00 ug/L 04/12/17 01:06 11,1,1-Trichloroethane
<0.190 0.1901.00 ug/L 04/12/17 01:06 11,1,2-Trichloroethane
<0.200 0.2001.00 ug/L 04/12/17 01:06 1Trichloroethene
<0.210 0.2101.00 ug/L 04/12/17 01:06 1Trichlorofluoromethane
<0.230 0.2301.00 ug/L 04/12/17 01:06 11,2,3-Trichloropropane
<1.71 1.7110.0 ug/L 04/12/17 01:06 1Vinyl acetate
<0.180 0.1801.00 ug/L 04/12/17 01:06 1Vinyl chloride
<0.580 0.5803.00 ug/L 04/12/17 01:06 1Xylenes, Total
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QC Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
4-Bromofluorobenzene (Surr)102 70-130 04/12/17 01:06 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
103 04/12/17 01:06 1Dibromofluoromethane (Surr)70-130
92 04/12/17 01:06 11,2-Dichloroethane-d4 (Surr)70-130
97 04/12/17 01:06 1Toluene-d8 (Surr)70-130
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-421467/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421467
Acetone 100 61.36 ug/L 61 39-150
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Acrylonitrile 200 138.5 ug/L 69 63-135
Benzene 20.0 18.62 ug/L 93 70-130
Bromochloromethane 20.0 16.38 ug/L 82 70-130
Bromodichloromethane 20.0 17.68 ug/L 88 70-130
Bromoform 20.0 14.13 ug/L 71 70-137
Bromomethane 20.0 17.73 ug/L 89 53-150
2-Butanone (MEK)100 65.11 ug/L 65 55-143
Carbon disulfide 20.0 18.82 ug/L 94 64-135
Carbon tetrachloride 20.0 18.45 ug/L 92 70-147
Chlorobenzene 20.0 18.60 ug/L 93 70-130
Chloroethane 20.0 20.93 ug/L 105 60-138
Chloroform 20.0 18.42 ug/L 92 70-130
Chloromethane 20.0 19.24 ug/L 96 33-150
cis-1,2-Dichloroethene 20.0 18.04 ug/L 90 70-130
cis-1,3-Dichloropropene 20.0 17.08 ug/L 85 70-133
Dibromochloromethane 20.0 15.58 ug/L 78 70-133
1,2-Dibromo-3-Chloropropane 20.0 11.46 ug/L 57 45-138
1,2-Dibromoethane (EDB)20.0 16.22 ug/L 81 70-130
Dibromomethane 20.0 16.82 ug/L 84 70-130
1,2-Dichlorobenzene 20.0 17.89 ug/L 89 70-130
1,4-Dichlorobenzene 20.0 18.54 ug/L 93 70-130
1,1-Dichloroethane 20.0 17.77 ug/L 89 70-130
1,2-Dichloroethane 20.0 16.30 ug/L 82 70-130
1,1-Dichloroethene 20.0 18.23 ug/L 91 70-132
1,2-Dichloropropane 20.0 16.83 ug/L 84 70-130
Ethylbenzene 20.0 18.19 ug/L 91 70-130
2-Hexanone 100 64.13 ug/L 64 54-142
Iodomethane 20.0 19.32 ug/L 97 40-150
Methylene Chloride 20.0 18.05 ug/L 90 70-130
4-Methyl-2-pentanone (MIBK)100 66.13 ug/L 66 60-137
Styrene 20.0 17.81 ug/L 89 70-130
1,1,1,2-Tetrachloroethane 20.0 17.34 ug/L 87 70-130
1,1,2,2-Tetrachloroethane 20.0 14.87 ug/L 74 69-131
Tetrachloroethene 20.0 18.88 ug/L 94 70-130
Tetrahydrofuran 40.0 25.12 ug/L 63 51-136
Toluene 20.0 18.97 ug/L 95 70-130
trans-1,4-Dichloro-2-butene 20.0 13.72 ug/L 69 41-150
trans-1,2-Dichloroethene 20.0 18.35 ug/L 92 70-130
trans-1,3-Dichloropropene 20.0 16.15 ug/L 81 63-142
1,1,1-Trichloroethane 20.0 18.78 ug/L 94 70-135
1,1,2-Trichloroethane 20.0 17.21 ug/L 86 70-130
Trichloroethene 20.0 17.41 ug/L 87 70-130
Trichlorofluoromethane 20.0 16.80 ug/L 84 59-150
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QC Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-421467/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421467
1,2,3-Trichloropropane 20.0 15.79 ug/L 79 70-131
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Vinyl acetate 40.0 44.01 ug/L 110 54-146
Vinyl chloride 20.0 17.54 ug/L 88 57-137
Xylenes, Total 40.0 34.86 ug/L 87 70-132
4-Bromofluorobenzene (Surr)70 -130
Surrogate
100
LCS LCS
Qualifier Limits%Recovery
101Dibromofluoromethane (Surr)70 -130
901,2-Dichloroethane-d4 (Surr)70 -130
100Toluene-d8 (Surr)70 -130
Client Sample ID: MW-04Lab Sample ID: 490-125629-4 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421467
Acetone <2.66 100 71.48 ug/L 71 39-150
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Acrylonitrile <0.500 200 154.9 ug/L 77 50-135
Benzene <0.200 20.0 21.16 ug/L 106 55-147
Bromochloromethane <0.150 20.0 18.23 ug/L 91 59-132
Bromodichloromethane <0.170 20.0 19.52 ug/L 98 70-140
Bromoform <0.290 20.0 15.20 ug/L 76 53-150
Bromomethane <0.350 20.0 20.29 ug/L 101 30-150
2-Butanone (MEK)<2.64 100 71.74 ug/L 72 50-143
Carbon disulfide <0.220 20.0 20.53 ug/L 103 35-150
Carbon tetrachloride <0.180 20.0 22.21 ug/L 111 56-150
Chlorobenzene <0.180 20.0 20.00 ug/L 100 70-130
Chloroethane <0.360 20.0 21.49 ug/L 107 58-141
Chloroform <0.230 20.0 21.10 ug/L 105 66-138
Chloromethane <0.360 20.0 22.43 ug/L 112 10-150
cis-1,2-Dichloroethene <0.210 20.0 20.31 ug/L 102 68-131
cis-1,3-Dichloropropene <0.170 20.0 17.39 ug/L 87 70-133
Dibromochloromethane <0.250 20.0 18.02 ug/L 90 66-140
1,2-Dibromo-3-Chloropropane <0.940 20.0 11.49 ug/L 57 38-138
1,2-Dibromoethane (EDB)<0.210 20.0 17.30 ug/L 86 65-137
Dibromomethane <0.450 20.0 18.30 ug/L 92 70-130
1,2-Dichlorobenzene <0.190 20.0 19.15 ug/L 96 70-130
1,4-Dichlorobenzene <0.170 20.0 20.50 ug/L 103 70-130
1,1-Dichloroethane <0.240 20.0 20.69 ug/L 103 61-139
1,2-Dichloroethane <0.200 20.0 18.19 ug/L 91 64-136
1,1-Dichloroethene <0.250 20.0 21.59 ug/L 108 54-150
1,2-Dichloropropane <0.250 20.0 18.55 ug/L 93 67-130
Ethylbenzene <0.190 20.0 19.39 ug/L 97 65-139
2-Hexanone <1.28 100 59.55 ug/L 60 44-150
Iodomethane <1.50 20.0 19.51 ug/L 98 34-150
Methylene Chloride <1.00 20.0 19.73 ug/L 99 64-130
4-Methyl-2-pentanone (MIBK)<0.810 100 64.72 ug/L 65 50-140
Styrene <0.280 20.0 19.31 ug/L 97 70-130
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QC Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: MW-04Lab Sample ID: 490-125629-4 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421467
1,1,1,2-Tetrachloroethane <0.150 20.0 19.08 ug/L 95 70-131
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
1,1,2,2-Tetrachloroethane <0.190 20.0 16.03 ug/L 80 56-145
Tetrachloroethene <0.140 20.0 21.19 ug/L 106 57-138
Tetrahydrofuran <0.820 40.0 21.94 ug/L 55 40-136
Toluene <0.170 20.0 20.48 ug/L 102 64-136
trans-1,4-Dichloro-2-butene <0.460 20.0 14.76 ug/L 74 39-150
trans-1,2-Dichloroethene <0.230 20.0 20.51 ug/L 103 59-143
trans-1,3-Dichloropropene <0.170 20.0 16.54 ug/L 83 63-142
1,1,1-Trichloroethane <0.190 20.0 22.69 ug/L 113 68-144
1,1,2-Trichloroethane <0.190 20.0 18.22 ug/L 91 70-130
Trichloroethene <0.200 20.0 18.88 ug/L 94 63-135
Trichlorofluoromethane <0.210 20.0 23.51 ug/L 118 44-150
1,2,3-Trichloropropane <0.230 20.0 16.09 ug/L 80 65-131
Vinyl acetate <1.71 40.0 40.72 ug/L 102 43-146
Vinyl chloride <0.180 20.0 21.42 ug/L 107 57-150
Xylenes, Total <0.580 40.0 37.30 ug/L 93 69-132
4-Bromofluorobenzene (Surr)70 -130
Surrogate
98
MS MS
Qualifier Limits%Recovery
101Dibromofluoromethane (Surr)70 -130
941,2-Dichloroethane-d4 (Surr)70 -130
97Toluene-d8 (Surr)70 -130
Client Sample ID: MW-04Lab Sample ID: 490-125629-4 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421467
Acetone <2.66 100 68.57 ug/L 69 39-150 4 28
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Acrylonitrile <0.500 200 156.0 ug/L 78 50-135 1 23
Benzene <0.200 20.0 21.32 ug/L 107 55-147 1 22
Bromochloromethane <0.150 20.0 18.52 ug/L 93 59-132 2 21
Bromodichloromethane <0.170 20.0 19.99 ug/L 100 70-140 2 196
Bromoform <0.290 20.0 15.13 ug/L 76 53-150 1 20
Bromomethane <0.350 20.0 21.56 ug/L 108 30-150 6 44
2-Butanone (MEK)<2.64 100 66.40 ug/L 66 50-143 8 28
Carbon disulfide <0.220 20.0 21.26 ug/L 106 35-150 3 34
Carbon tetrachloride <0.180 20.0 22.40 ug/L 112 56-150 1 18
Chlorobenzene <0.180 20.0 20.60 ug/L 103 70-130 3 15
Chloroethane <0.360 20.0 21.21 ug/L 106 58-141 1 31
Chloroform <0.230 20.0 21.19 ug/L 106 66-138 0 21
Chloromethane <0.360 20.0 21.85 ug/L 109 10-150 3 43
cis-1,2-Dichloroethene <0.210 20.0 21.16 ug/L 106 68-131 4 21
cis-1,3-Dichloropropene <0.170 20.0 17.87 ug/L 89 70-133 3 19
Dibromochloromethane <0.250 20.0 17.45 ug/L 87 66-140 3 19
1,2-Dibromo-3-Chloropropane <0.940 20.0 11.11 ug/L 56 38-138 3 26
1,2-Dibromoethane (EDB)<0.210 20.0 18.08 ug/L 90 65-137 4 21
Dibromomethane <0.450 20.0 18.21 ug/L 91 70-130 1 19
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QC Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: MW-04Lab Sample ID: 490-125629-4 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421467
1,2-Dichlorobenzene <0.190 20.0 20.05 ug/L 100 70-130 5 15
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
1,4-Dichlorobenzene <0.170 20.0 21.44 ug/L 107 70-130 4 14
1,1-Dichloroethane <0.240 20.0 20.89 ug/L 104 61-139 1 23
1,2-Dichloroethane <0.200 20.0 18.90 ug/L 94 64-136 4 22
1,1-Dichloroethene <0.250 20.0 21.51 ug/L 108 54-150 0 24
1,2-Dichloropropane <0.250 20.0 19.25 ug/L 96 67-130 4 19
Ethylbenzene <0.190 20.0 19.89 ug/L 99 65-139 3 18
2-Hexanone <1.28 100 60.25 ug/L 60 44-150 1 21
Iodomethane <1.50 20.0 21.63 ug/L 108 34-150 10 37
Methylene Chloride <1.00 20.0 17.85 ug/L 89 64-130 10 22
4-Methyl-2-pentanone (MIBK)<0.810 100 65.14 ug/L 65 50-140 1 24
Styrene <0.280 20.0 19.22 ug/L 96 70-130 0 16
1,1,1,2-Tetrachloroethane <0.150 20.0 19.35 ug/L 97 70-131 1 16
1,1,2,2-Tetrachloroethane <0.190 20.0 15.57 ug/L 78 56-145 3 19
Tetrachloroethene <0.140 20.0 22.38 ug/L 112 57-138 5 17
Tetrahydrofuran <0.820 40.0 23.49 ug/L 59 40-136 7 27
Toluene <0.170 20.0 21.14 ug/L 106 64-136 3 18
trans-1,4-Dichloro-2-butene <0.460 20.0 14.42 ug/L 72 39-150 2 28
trans-1,2-Dichloroethene <0.230 20.0 20.99 ug/L 105 59-143 2 25
trans-1,3-Dichloropropene <0.170 20.0 16.56 ug/L 83 63-142 0 18
1,1,1-Trichloroethane <0.190 20.0 22.40 ug/L 112 68-144 1 17
1,1,2-Trichloroethane <0.190 20.0 18.60 ug/L 93 70-130 2 18
Trichloroethene <0.200 20.0 20.30 ug/L 102 63-135 7 17
Trichlorofluoromethane <0.210 20.0 22.98 ug/L 115 44-150 2 32
1,2,3-Trichloropropane <0.230 20.0 16.64 ug/L 83 65-131 3 19
Vinyl acetate <1.71 40.0 44.57 ug/L 111 43-146 9 20
Vinyl chloride <0.180 20.0 24.70 ug/L 123 57-150 14 37
Xylenes, Total <0.580 40.0 38.57 ug/L 96 69-132 3 17
4-Bromofluorobenzene (Surr)70 -130
Surrogate
96
MSD MSD
Qualifier Limits%Recovery
101Dibromofluoromethane (Surr)70 -130
941,2-Dichloroethane-d4 (Surr)70 -130
98Toluene-d8 (Surr)70 -130
Method: 6010D - Metals (ICP)
Client Sample ID: Method BlankLab Sample ID: MB 490-422808/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 423523 Prep Batch: 422808
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/17/17 16:25 04/19/17 22:51 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<0.00500 0.005000.0100 mg/L 04/17/17 16:25 04/19/17 22:51 1Barium
<0.000500 0.0005000.00100 mg/L 04/17/17 16:25 04/19/17 22:51 1Cadmium
<0.00300 0.003000.00500 mg/L 04/17/17 16:25 04/19/17 22:51 1Chromium
<0.00500 0.005000.0100 mg/L 04/17/17 16:25 04/19/17 22:51 1Copper
<0.00200 0.002000.00500 mg/L 04/17/17 16:25 04/19/17 22:51 1Lead
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QC Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 6010D - Metals (ICP) (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 490-422808/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 423523 Prep Batch: 422808
RL MDL
Nickel <0.00300 0.0100 0.00300 mg/L 04/17/17 16:25 04/19/17 22:51 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<0.00500 0.005000.0100 mg/L 04/17/17 16:25 04/19/17 22:51 1Selenium
<0.00300 0.003000.00500 mg/L 04/17/17 16:25 04/19/17 22:51 1Silver
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-422808/22-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 423523 Prep Batch: 422808
Silver 0.0500 0.05480 mg/L 110 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-422808/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 423523 Prep Batch: 422808
Arsenic 0.100 0.09820 mg/L 98 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Barium 0.100 0.1015 mg/L 102 80-120
Cadmium 0.100 0.1019 mg/L 102 80-120
Chromium 0.100 0.1010 mg/L 101 80-120
Copper 0.100 0.1022 mg/L 102 80-120
Lead 0.100 0.1040 mg/L 104 80-120
Nickel 0.100 0.1045 mg/L 105 80-120
Selenium 0.100 0.09730 mg/L 97 80-120
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-422808/23-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 423523 Prep Batch: 422808
Silver 0.0500 0.05410 mg/L 108 80-120 1 20
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-422808/3-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 423523 Prep Batch: 422808
Arsenic 0.100 0.09900 mg/L 99 80-120 1 20
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Barium 0.100 0.1053 mg/L 105 80-120 4 20
Cadmium 0.100 0.1035 mg/L 104 80-120 2 20
Chromium 0.100 0.1029 mg/L 103 80-120 2 20
Copper 0.100 0.1050 mg/L 105 80-120 3 20
Lead 0.100 0.1070 mg/L 107 80-120 3 20
Nickel 0.100 0.1066 mg/L 107 80-120 2 20
Selenium 0.100 0.09980 mg/L 100 80-120 3 20
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QC Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 6010D - Metals (ICP) (Continued)
Client Sample ID: MW-01Lab Sample ID: 490-125629-1 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 423523 Prep Batch: 422808
Arsenic <0.00860 0.100 0.1015 mg/L 102 75-125
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Barium 0.103 0.100 0.2058 mg/L 103 75-125
Cadmium <0.000500 0.100 0.1031 mg/L 103 75-125
Chromium <0.00300 0.100 0.1048 mg/L 105 75-125
Copper <0.00500 0.100 0.1044 mg/L 104 75-125
Lead <0.00200 0.100 0.1044 mg/L 104 75-125
Nickel <0.00300 0.100 0.1068 mg/L 107 75-125
Selenium <0.00500 0.100 0.09800 mg/L 98 75-125
Silver <0.00300 F1 0.100 0.06260 F1 mg/L 63 75-125
Client Sample ID: MW-01Lab Sample ID: 490-125629-1 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 423523 Prep Batch: 422808
Arsenic <0.00860 0.100 0.09950 mg/L 100 75-125 2 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Barium 0.103 0.100 0.2060 mg/L 103 75-125 0 20
Cadmium <0.000500 0.100 0.1032 mg/L 103 75-125 0 20
Chromium <0.00300 0.100 0.1029 mg/L 103 75-125 2 20
Copper <0.00500 0.100 0.1020 mg/L 102 75-125 2 20
Lead <0.00200 0.100 0.1049 mg/L 105 75-125 0 20
Nickel <0.00300 0.100 0.1069 mg/L 107 75-125 0 20
Selenium <0.00500 0.100 0.09800 mg/L 98 75-125 0 20
Silver <0.00300 F1 0.100 0.06070 F1 mg/L 61 75-125 3 20
Client Sample ID: Method BlankLab Sample ID: MB 490-421823/1-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 422191 Prep Batch: 421823
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/12/17 19:03 04/13/17 14:11 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<0.00500 0.005000.0100 mg/L 04/12/17 19:03 04/13/17 14:11 1Barium
<0.000500 0.0005000.00100 mg/L 04/12/17 19:03 04/13/17 14:11 1Cadmium
<0.00300 0.003000.00500 mg/L 04/12/17 19:03 04/13/17 14:11 1Chromium
<0.00500 0.005000.0100 mg/L 04/12/17 19:03 04/13/17 14:11 1Copper
<0.00200 0.002000.00500 mg/L 04/12/17 19:03 04/13/17 14:11 1Lead
<0.00300 0.003000.0100 mg/L 04/12/17 19:03 04/13/17 14:11 1Nickel
<0.00500 0.005000.0100 mg/L 04/12/17 19:03 04/13/17 14:11 1Selenium
<0.00300 0.003000.00500 mg/L 04/12/17 19:03 04/13/17 14:11 1Silver
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-421823/2-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 422191 Prep Batch: 421823
Arsenic 0.100 0.1005 mg/L 101 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Barium 0.100 0.1021 mg/L 102 80-120
Cadmium 0.100 0.09970 mg/L 100 80-120
Chromium 0.100 0.1007 mg/L 101 80-120
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QC Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 6010D - Metals (ICP) (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-421823/2-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 422191 Prep Batch: 421823
Copper 0.100 0.1044 mg/L 104 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Lead 0.100 0.09780 mg/L 98 80-120
Nickel 0.100 0.1048 mg/L 105 80-120
Selenium 0.100 0.1047 mg/L 105 80-120
Silver 0.100 0.1023 mg/L 102 80-120
Client Sample ID: MW-01Lab Sample ID: 490-125629-1 MS
Matrix: Water Prep Type: Dissolved
Analysis Batch: 422191 Prep Batch: 421823
Arsenic <0.00860 0.100 0.1038 mg/L 104 75-125
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Barium 0.0981 0.100 0.1988 mg/L 101 75-125
Cadmium <0.000500 0.100 0.09900 mg/L 99 75-125
Chromium <0.00300 0.100 0.1013 mg/L 101 75-125
Copper 0.0117 0.100 0.1121 mg/L 100 75-125
Lead 0.00330 J 0.100 0.1007 mg/L 97 75-125
Nickel <0.00300 0.100 0.1055 mg/L 106 75-125
Selenium <0.00500 0.100 0.1019 mg/L 102 75-125
Silver <0.00300 0.100 0.1027 mg/L 103 75-125
Client Sample ID: MW-01Lab Sample ID: 490-125629-1 MSD
Matrix: Water Prep Type: Dissolved
Analysis Batch: 422191 Prep Batch: 421823
Arsenic <0.00860 0.100 0.1033 mg/L 103 75-125 0 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Barium 0.0981 0.100 0.2004 mg/L 102 75-125 1 20
Cadmium <0.000500 0.100 0.09990 mg/L 100 75-125 1 20
Chromium <0.00300 0.100 0.1018 mg/L 102 75-125 0 20
Copper 0.0117 0.100 0.1132 mg/L 102 75-125 1 20
Lead 0.00330 J 0.100 0.1016 mg/L 98 75-125 1 20
Nickel <0.00300 0.100 0.1069 mg/L 107 75-125 1 20
Selenium <0.00500 0.100 0.1029 mg/L 103 75-125 1 20
Silver <0.00300 0.100 0.1011 mg/L 101 75-125 2 20
Method: 6020B - Metals (ICP/MS)
Client Sample ID: Method BlankLab Sample ID: MB 490-423185/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 424428 Prep Batch: 423185
RL MDL
Antimony <0.800 2.00 0.800 ug/L 04/18/17 20:08 04/23/17 15:08 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<0.100 0.1002.00 ug/L 04/18/17 20:08 04/23/17 15:08 1Beryllium
<0.100 0.1002.00 ug/L 04/18/17 20:08 04/23/17 15:08 1Cobalt
<0.800 0.8002.00 ug/L 04/18/17 20:08 04/23/17 15:08 1Thallium
1.239 J 0.7002.00 ug/L 04/18/17 20:08 04/23/17 15:08 1Vanadium
15.47 J 5.2025.0 ug/L 04/18/17 20:08 04/23/17 15:08 1Zinc
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QC Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-423185/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 424428 Prep Batch: 423185
Antimony 100 88.13 ug/L 88 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Beryllium 100 81.62 ug/L 82 80-120
Cobalt 100 97.89 ug/L 98 80-120
Thallium 100 94.44 ug/L 94 80-120
Vanadium 100 96.95 ug/L 97 80-120
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-423185/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 425142 Prep Batch: 423185
Zinc 100 85.20 ug/L 85 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: MW-01Lab Sample ID: 490-125629-1 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 424428 Prep Batch: 423185
Antimony <0.800 100 84.23 ug/L 84 75-125
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Beryllium <0.100 100 75.30 ug/L 75 75-125
Cobalt 0.792 J 100 96.69 ug/L 96 75-125
Thallium <0.800 100 91.87 ug/L 92 75-125
Vanadium 1.41 J B 100 93.35 ug/L 92 75-125
Zinc 12.3 J F1 B 100 80.24 F1 ug/L 68 75-125
Client Sample ID: MW-01Lab Sample ID: 490-125629-1 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 424428 Prep Batch: 423185
Antimony <0.800 100 90.02 ug/L 90 75-125 7 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Beryllium <0.100 100 84.19 ug/L 84 75-125 11 20
Cobalt 0.792 J 100 101.1 ug/L 100 75-125 4 20
Thallium <0.800 100 97.44 ug/L 97 75-125 6 20
Vanadium 1.41 J B 100 101.4 ug/L 100 75-125 8 20
Zinc 12.3 J F1 B 100 80.39 F1 ug/L 68 75-125 0 20
Client Sample ID: Method BlankLab Sample ID: MB 490-422781/1-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 424396 Prep Batch: 422781
RL MDL
Antimony <0.000800 0.00200 0.000800 mg/L 04/17/17 15:23 04/23/17 08:22 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<0.000100 0.0001000.00200 mg/L 04/17/17 15:23 04/23/17 08:22 1Beryllium
<0.000100 0.0001000.00200 mg/L 04/17/17 15:23 04/23/17 08:22 1Cobalt
<0.000800 0.0008000.00200 mg/L 04/17/17 15:23 04/23/17 08:22 1Thallium
0.0009961 J 0.0007000.00200 mg/L 04/17/17 15:23 04/23/17 08:22 1Vanadium
<0.00520 0.005200.0250 mg/L 04/17/17 15:23 04/23/17 08:22 1Zinc
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QC Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 6020B - Metals (ICP/MS) (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-422781/2-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 424396 Prep Batch: 422781
Antimony 0.100 0.09924 mg/L 99 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Beryllium 0.100 0.09400 mg/L 94 80-120
Cobalt 0.100 0.1004 mg/L 100 80-120
Thallium 0.100 0.09598 mg/L 96 80-120
Vanadium 0.100 0.09884 mg/L 99 80-120
Zinc 0.100 0.09848 mg/L 98 80-120
Client Sample ID: MW-04Lab Sample ID: 490-125629-4 MS
Matrix: Water Prep Type: Dissolved
Analysis Batch: 424396 Prep Batch: 422781
Antimony <0.000800 0.100 0.09666 mg/L 97 75-125
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Beryllium <0.000100 0.100 0.08790 mg/L 88 75-125
Cobalt <0.000100 0.100 0.1005 mg/L 101 75-125
Thallium <0.000800 0.100 0.09464 mg/L 95 75-125
Vanadium 0.00476 B 0.100 0.1058 mg/L 101 75-125
Zinc 0.0137 J 0.100 0.1045 mg/L 91 75-125
Client Sample ID: MW-04Lab Sample ID: 490-125629-4 MSD
Matrix: Water Prep Type: Dissolved
Analysis Batch: 424396 Prep Batch: 422781
Antimony <0.000800 0.100 0.09883 mg/L 99 75-125 2 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Beryllium <0.000100 0.100 0.09211 mg/L 92 75-125 5 20
Cobalt <0.000100 0.100 0.1031 mg/L 103 75-125 3 20
Thallium <0.000800 0.100 0.09668 mg/L 97 75-125 2 20
Vanadium 0.00476 B 0.100 0.1068 mg/L 102 75-125 1 20
Zinc 0.0137 J 0.100 0.1089 mg/L 95 75-125 4 20
Method: 7470A - Mercury (CVAA)
Client Sample ID: Method BlankLab Sample ID: MB 490-421267/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421541 Prep Batch: 421267
RL MDL
Mercury 0.0001064 J 0.000200 0.000100 mg/L 04/11/17 09:07 04/11/17 15:44 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-421267/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421541 Prep Batch: 421267
Mercury 0.00100 0.001193 mg/L 119 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
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QC Sample Results
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 7470A - Mercury (CVAA) (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-421267/3-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421541 Prep Batch: 421267
Mercury 0.00100 0.001060 mg/L 106 80-120 12 20
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Client Sample ID: Matrix SpikeLab Sample ID: 490-125420-A-1-B MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421541 Prep Batch: 421267
Mercury <0.000100 0.00100 0.001056 mg/L 106 75-125
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-125420-A-1-C MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421541 Prep Batch: 421267
Mercury <0.000100 0.00100 0.001196 mg/L 120 75-125 12 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Client Sample ID: Method BlankLab Sample ID: MB 490-421610/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421722 Prep Batch: 421610
RL MDL
Mercury <0.100 0.200 0.100 ug/L 04/12/17 09:48 04/12/17 13:39 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-421610/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421722 Prep Batch: 421610
Mercury 1.00 1.113 ug/L 111 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: Matrix SpikeLab Sample ID: 490-125658-A-1-B MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421722 Prep Batch: 421610
Mercury <0.000100 0.00100 0.001230 mg/L 123 75-125
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-125658-A-1-C MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421722 Prep Batch: 421610
Mercury <0.000100 0.00100 0.001116 mg/L 112 75-125 10 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
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QC Association Summary
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
GC/MS VOA
Analysis Batch: 421467
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 8260B490-125629-1 MW-01 Total/NA
Water 8260B490-125629-2 MW-02 Total/NA
Water 8260B490-125629-3 MW-03 Total/NA
Water 8260B490-125629-4 MW-04 Total/NA
Water 8260B490-125629-5 MW-05 Total/NA
Water 8260B490-125629-6 MW-06R Total/NA
Water 8260B490-125629-7 MW-07R Total/NA
Water 8260B490-125629-8 MW-08 Total/NA
Water 8260B490-125629-9 MW-09 Total/NA
Water 8260B490-125629-10 Trip Blank Total/NA
Water 8260BMB 490-421467/7 Method Blank Total/NA
Water 8260BLCS 490-421467/4 Lab Control Sample Total/NA
Water 8260B490-125629-4 MS MW-04 Total/NA
Water 8260B490-125629-4 MSD MW-04 Total/NA
Metals
Prep Batch: 421267
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A490-125629-1 MW-01 Dissolved
Water 7470A490-125629-1 MW-01 Total/NA
Water 7470A490-125629-2 MW-02 Dissolved
Water 7470A490-125629-2 MW-02 Total/NA
Water 7470A490-125629-3 MW-03 Dissolved
Water 7470A490-125629-3 MW-03 Total/NA
Water 7470A490-125629-4 MW-04 Dissolved
Water 7470A490-125629-4 MW-04 Total/NA
Water 7470A490-125629-5 MW-05 Dissolved
Water 7470A490-125629-5 MW-05 Total/NA
Water 7470A490-125629-6 MW-06R Dissolved
Water 7470A490-125629-6 MW-06R Total/NA
Water 7470A490-125629-7 MW-07R Dissolved
Water 7470A490-125629-7 MW-07R Total/NA
Water 7470A490-125629-8 MW-08 Dissolved
Water 7470A490-125629-8 MW-08 Total/NA
Water 7470AMB 490-421267/1-A Method Blank Total/NA
Water 7470ALCS 490-421267/2-A Lab Control Sample Total/NA
Water 7470ALCSD 490-421267/3-A Lab Control Sample Dup Total/NA
Water 7470A490-125420-A-1-B MS Matrix Spike Total/NA
Water 7470A490-125420-A-1-C MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 421541
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A 421267490-125629-1 MW-01 Dissolved
Water 7470A 421267490-125629-1 MW-01 Total/NA
Water 7470A 421267490-125629-2 MW-02 Dissolved
Water 7470A 421267490-125629-2 MW-02 Total/NA
Water 7470A 421267490-125629-3 MW-03 Dissolved
Water 7470A 421267490-125629-3 MW-03 Total/NA
Water 7470A 421267490-125629-4 MW-04 Dissolved
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QC Association Summary
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Metals (Continued)
Analysis Batch: 421541 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A 421267490-125629-4 MW-04 Total/NA
Water 7470A 421267490-125629-5 MW-05 Dissolved
Water 7470A 421267490-125629-5 MW-05 Total/NA
Water 7470A 421267490-125629-6 MW-06R Dissolved
Water 7470A 421267490-125629-6 MW-06R Total/NA
Water 7470A 421267490-125629-7 MW-07R Dissolved
Water 7470A 421267490-125629-7 MW-07R Total/NA
Water 7470A 421267490-125629-8 MW-08 Dissolved
Water 7470A 421267490-125629-8 MW-08 Total/NA
Water 7470A 421267MB 490-421267/1-A Method Blank Total/NA
Water 7470A 421267LCS 490-421267/2-A Lab Control Sample Total/NA
Water 7470A 421267LCSD 490-421267/3-A Lab Control Sample Dup Total/NA
Water 7470A 421267490-125420-A-1-B MS Matrix Spike Total/NA
Water 7470A 421267490-125420-A-1-C MSD Matrix Spike Duplicate Total/NA
Prep Batch: 421610
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A490-125629-9 MW-09 Dissolved
Water 7470A490-125629-9 MW-09 Total/NA
Water 7470AMB 490-421610/1-A Method Blank Total/NA
Water 7470ALCS 490-421610/2-A Lab Control Sample Total/NA
Water 7470A490-125658-A-1-B MS Matrix Spike Total/NA
Water 7470A490-125658-A-1-C MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 421722
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A 421610490-125629-9 MW-09 Dissolved
Water 7470A 421610490-125629-9 MW-09 Total/NA
Water 7470A 421610MB 490-421610/1-A Method Blank Total/NA
Water 7470A 421610LCS 490-421610/2-A Lab Control Sample Total/NA
Water 7470A 421610490-125658-A-1-B MS Matrix Spike Total/NA
Water 7470A 421610490-125658-A-1-C MSD Matrix Spike Duplicate Total/NA
Prep Batch: 421823
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3005A490-125629-1 MW-01 Dissolved
Water 3005A490-125629-2 MW-02 Dissolved
Water 3005A490-125629-3 MW-03 Dissolved
Water 3005A490-125629-4 MW-04 Dissolved
Water 3005A490-125629-5 MW-05 Dissolved
Water 3005A490-125629-6 MW-06R Dissolved
Water 3005A490-125629-7 MW-07R Dissolved
Water 3005A490-125629-8 MW-08 Dissolved
Water 3005A490-125629-9 MW-09 Dissolved
Water 3005AMB 490-421823/1-A Method Blank Total Recoverable
Water 3005ALCS 490-421823/2-A Lab Control Sample Total Recoverable
Water 3005A490-125629-1 MS MW-01 Dissolved
Water 3005A490-125629-1 MSD MW-01 Dissolved
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QC Association Summary
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Metals (Continued)
Analysis Batch: 422191
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6010D 421823490-125629-1 MW-01 Dissolved
Water 6010D 421823490-125629-2 MW-02 Dissolved
Water 6010D 421823490-125629-3 MW-03 Dissolved
Water 6010D 421823490-125629-4 MW-04 Dissolved
Water 6010D 421823490-125629-5 MW-05 Dissolved
Water 6010D 421823490-125629-6 MW-06R Dissolved
Water 6010D 421823490-125629-7 MW-07R Dissolved
Water 6010D 421823490-125629-8 MW-08 Dissolved
Water 6010D 421823490-125629-9 MW-09 Dissolved
Water 6010D 421823MB 490-421823/1-A Method Blank Total Recoverable
Water 6010D 421823LCS 490-421823/2-A Lab Control Sample Total Recoverable
Water 6010D 421823490-125629-1 MS MW-01 Dissolved
Water 6010D 421823490-125629-1 MSD MW-01 Dissolved
Prep Batch: 422781
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3005A490-125629-1 MW-01 Dissolved
Water 3005A490-125629-2 MW-02 Dissolved
Water 3005A490-125629-3 MW-03 Dissolved
Water 3005A490-125629-4 MW-04 Dissolved
Water 3005A490-125629-5 MW-05 Dissolved
Water 3005A490-125629-6 MW-06R Dissolved
Water 3005A490-125629-7 MW-07R Dissolved
Water 3005A490-125629-8 MW-08 Dissolved
Water 3005A490-125629-9 MW-09 Dissolved
Water 3005AMB 490-422781/1-A Method Blank Total Recoverable
Water 3005ALCS 490-422781/2-A Lab Control Sample Total Recoverable
Water 3005A490-125629-4 MS MW-04 Dissolved
Water 3005A490-125629-4 MSD MW-04 Dissolved
Prep Batch: 422808
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3010A490-125629-1 MW-01 Total/NA
Water 3010A490-125629-2 MW-02 Total/NA
Water 3010A490-125629-3 MW-03 Total/NA
Water 3010A490-125629-4 MW-04 Total/NA
Water 3010A490-125629-5 MW-05 Total/NA
Water 3010A490-125629-6 MW-06R Total/NA
Water 3010A490-125629-7 MW-07R Total/NA
Water 3010A490-125629-8 MW-08 Total/NA
Water 3010A490-125629-9 MW-09 Total/NA
Water 3010AMB 490-422808/1-A Method Blank Total/NA
Water 3010ALCS 490-422808/22-A Lab Control Sample Total/NA
Water 3010ALCS 490-422808/2-A Lab Control Sample Total/NA
Water 3010ALCSD 490-422808/23-A Lab Control Sample Dup Total/NA
Water 3010ALCSD 490-422808/3-A Lab Control Sample Dup Total/NA
Water 3010A490-125629-1 MS MW-01 Total/NA
Water 3010A490-125629-1 MSD MW-01 Total/NA
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QC Association Summary
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Metals (Continued)
Prep Batch: 423185
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3010A490-125629-1 MW-01 Total/NA
Water 3010A490-125629-2 MW-02 Total/NA
Water 3010A490-125629-3 MW-03 Total/NA
Water 3010A490-125629-4 MW-04 Total/NA
Water 3010A490-125629-5 MW-05 Total/NA
Water 3010A490-125629-6 MW-06R Total/NA
Water 3010A490-125629-7 MW-07R Total/NA
Water 3010A490-125629-8 MW-08 Total/NA
Water 3010A490-125629-9 MW-09 Total/NA
Water 3010AMB 490-423185/1-A Method Blank Total/NA
Water 3010ALCS 490-423185/2-A Lab Control Sample Total/NA
Water 3010A490-125629-1 MS MW-01 Total/NA
Water 3010A490-125629-1 MSD MW-01 Total/NA
Analysis Batch: 423523
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6010D 422808490-125629-1 MW-01 Total/NA
Water 6010D 422808490-125629-2 MW-02 Total/NA
Water 6010D 422808490-125629-3 MW-03 Total/NA
Water 6010D 422808490-125629-4 MW-04 Total/NA
Water 6010D 422808490-125629-5 MW-05 Total/NA
Water 6010D 422808490-125629-6 MW-06R Total/NA
Water 6010D 422808490-125629-7 MW-07R Total/NA
Water 6010D 422808490-125629-8 MW-08 Total/NA
Water 6010D 422808490-125629-9 MW-09 Total/NA
Water 6010D 422808MB 490-422808/1-A Method Blank Total/NA
Water 6010D 422808LCS 490-422808/22-A Lab Control Sample Total/NA
Water 6010D 422808LCS 490-422808/2-A Lab Control Sample Total/NA
Water 6010D 422808LCSD 490-422808/23-A Lab Control Sample Dup Total/NA
Water 6010D 422808LCSD 490-422808/3-A Lab Control Sample Dup Total/NA
Water 6010D 422808490-125629-1 MS MW-01 Total/NA
Water 6010D 422808490-125629-1 MSD MW-01 Total/NA
Analysis Batch: 424396
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020B 422781490-125629-1 MW-01 Dissolved
Water 6020B 422781490-125629-2 MW-02 Dissolved
Water 6020B 422781490-125629-3 MW-03 Dissolved
Water 6020B 422781490-125629-4 MW-04 Dissolved
Water 6020B 422781490-125629-5 MW-05 Dissolved
Water 6020B 422781490-125629-6 MW-06R Dissolved
Water 6020B 422781490-125629-7 MW-07R Dissolved
Water 6020B 422781490-125629-8 MW-08 Dissolved
Water 6020B 422781490-125629-9 MW-09 Dissolved
Water 6020B 422781MB 490-422781/1-A Method Blank Total Recoverable
Water 6020B 422781LCS 490-422781/2-A Lab Control Sample Total Recoverable
Water 6020B 422781490-125629-4 MS MW-04 Dissolved
Water 6020B 422781490-125629-4 MSD MW-04 Dissolved
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QC Association Summary
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Metals (Continued)
Analysis Batch: 424428
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020B 423185490-125629-1 MW-01 Total/NA
Water 6020B 423185490-125629-2 MW-02 Total/NA
Water 6020B 423185490-125629-3 MW-03 Total/NA
Water 6020B 423185490-125629-4 MW-04 Total/NA
Water 6020B 423185490-125629-5 MW-05 Total/NA
Water 6020B 423185490-125629-6 MW-06R Total/NA
Water 6020B 423185490-125629-7 MW-07R Total/NA
Water 6020B 423185490-125629-8 MW-08 Total/NA
Water 6020B 423185490-125629-9 MW-09 Total/NA
Water 6020B 423185MB 490-423185/1-A Method Blank Total/NA
Water 6020B 423185LCS 490-423185/2-A Lab Control Sample Total/NA
Water 6020B 423185490-125629-1 MS MW-01 Total/NA
Water 6020B 423185490-125629-1 MSD MW-01 Total/NA
Analysis Batch: 424515
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020B 422781490-125629-5 MW-05 Dissolved
Water 6020B 422781490-125629-6 MW-06R Dissolved
Water 6020B 422781490-125629-7 MW-07R Dissolved
Water 6020B 422781490-125629-8 MW-08 Dissolved
Water 6020B 422781490-125629-9 MW-09 Dissolved
Analysis Batch: 425142
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020B 423185LCS 490-423185/2-A Lab Control Sample Total/NA
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Lab Chronicle
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-125629-1
Project/Site: Madison Co Operating Landfill
Client Sample ID: MW-01 Lab Sample ID: 490-125629-1
Matrix: WaterDate Collected: 04/04/17 09:42
Date Received: 04/05/17 09:40
Analysis 8260B BBR04/12/17 04:021 TAL NSH421467
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3005A 421823 04/12/17 19:03 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6010D 1 422191 04/13/17 14:27 LCS TAL NSHDissolved
Prep 3010A 422808 04/17/17 16:25 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 423523 04/19/17 23:17 LCS TAL NSHTotal/NA
Prep 3005A 422781 04/17/17 15:23 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6020B 1 424396 04/23/17 09:00 BLG TAL NSHDissolved
Prep 3010A 423185 04/18/17 20:08 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 424428 04/23/17 15:19 CME TAL NSHTotal/NA
Prep 7470A 421267 04/11/17 09:07 CAH TAL NSHDissolved30 mL 30 mL
Analysis 7470A 1 421541 04/11/17 16:14 CAH TAL NSHDissolved
Prep 7470A 421267 04/11/17 09:07 CAH TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 421541 04/11/17 16:41 CAH TAL NSHTotal/NA
Client Sample ID: MW-02 Lab Sample ID: 490-125629-2
Matrix: WaterDate Collected: 04/03/17 10:26
Date Received: 04/05/17 09:40
Analysis 8260B BBR04/12/17 04:271 TAL NSH421467
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3005A 421823 04/12/17 19:03 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6010D 1 422191 04/13/17 15:02 LCS TAL NSHDissolved
Prep 3010A 422808 04/17/17 16:25 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 423523 04/19/17 23:57 LCS TAL NSHTotal/NA
Prep 3005A 422781 04/17/17 15:23 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6020B 1 424396 04/23/17 09:06 BLG TAL NSHDissolved
Prep 3010A 423185 04/18/17 20:08 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 424428 04/23/17 15:46 CME TAL NSHTotal/NA
Prep 7470A 421267 04/11/17 09:07 CAH TAL NSHDissolved30 mL 30 mL
Analysis 7470A 1 421541 04/11/17 16:16 CAH TAL NSHDissolved
Prep 7470A 421267 04/11/17 09:07 CAH TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 421541 04/11/17 16:44 CAH TAL NSHTotal/NA
Client Sample ID: MW-03 Lab Sample ID: 490-125629-3
Matrix: WaterDate Collected: 04/04/17 11:06
Date Received: 04/05/17 09:40
Analysis 8260B BBR04/12/17 04:521 TAL NSH421467
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3005A 421823 04/12/17 19:03 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6010D 1 422191 04/13/17 15:07 LCS TAL NSHDissolved
Prep 3010A 422808 04/17/17 16:25 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 423523 04/20/17 00:03 LCS TAL NSHTotal/NA
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Lab Chronicle
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-125629-1
Project/Site: Madison Co Operating Landfill
Client Sample ID: MW-03 Lab Sample ID: 490-125629-3
Matrix: WaterDate Collected: 04/04/17 11:06
Date Received: 04/05/17 09:40
Prep 3005A JSF04/17/17 15:23 TAL NSH422781
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Dissolved 50 mL 50 mL
Analysis 6020B 1 424396 04/23/17 09:11 BLG TAL NSHDissolved
Prep 3010A 423185 04/18/17 20:08 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 424428 04/23/17 15:51 CME TAL NSHTotal/NA
Prep 7470A 421267 04/11/17 09:07 CAH TAL NSHDissolved30 mL 30 mL
Analysis 7470A 1 421541 04/11/17 16:19 CAH TAL NSHDissolved
Prep 7470A 421267 04/11/17 09:07 CAH TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 421541 04/11/17 16:46 CAH TAL NSHTotal/NA
Client Sample ID: MW-04 Lab Sample ID: 490-125629-4
Matrix: WaterDate Collected: 04/04/17 12:02
Date Received: 04/05/17 09:40
Analysis 8260B BBR04/12/17 05:171 TAL NSH421467
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3005A 421823 04/12/17 19:03 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6010D 1 422191 04/13/17 15:13 LCS TAL NSHDissolved
Prep 3010A 422808 04/17/17 16:25 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 423523 04/20/17 00:08 LCS TAL NSHTotal/NA
Prep 3005A 422781 04/17/17 15:23 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6020B 1 424396 04/23/17 08:33 BLG TAL NSHDissolved
Prep 3010A 423185 04/18/17 20:08 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 424428 04/23/17 15:57 CME TAL NSHTotal/NA
Prep 7470A 421267 04/11/17 09:07 CAH TAL NSHDissolved30 mL 30 mL
Analysis 7470A 1 421541 04/11/17 16:22 CAH TAL NSHDissolved
Prep 7470A 421267 04/11/17 09:07 CAH TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 421541 04/11/17 16:49 CAH TAL NSHTotal/NA
Client Sample ID: MW-05 Lab Sample ID: 490-125629-5
Matrix: WaterDate Collected: 04/03/17 13:33
Date Received: 04/05/17 09:40
Analysis 8260B BBR04/12/17 05:421 TAL NSH421467
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3005A 421823 04/12/17 19:03 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6010D 1 422191 04/13/17 15:18 LCS TAL NSHDissolved
Prep 3010A 422808 04/17/17 16:25 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 423523 04/20/17 00:13 LCS TAL NSHTotal/NA
Prep 3005A 422781 04/17/17 15:23 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6020B 1 424396 04/23/17 09:28 BLG TAL NSHDissolved
Prep 3005A 422781 04/17/17 15:23 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6020B 1 424515 04/23/17 21:30 CME TAL NSHDissolved
Prep 3010A 423185 04/18/17 20:08 JSF TAL NSHTotal/NA 50 mL 50 mL
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Lab Chronicle
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-125629-1
Project/Site: Madison Co Operating Landfill
Client Sample ID: MW-05 Lab Sample ID: 490-125629-5
Matrix: WaterDate Collected: 04/03/17 13:33
Date Received: 04/05/17 09:40
Analysis 6020B CME04/23/17 16:131 TAL NSH424428
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA
Prep 7470A 421267 04/11/17 09:07 CAH TAL NSHDissolved30 mL 30 mL
Analysis 7470A 1 421541 04/11/17 16:25 CAH TAL NSHDissolved
Prep 7470A 421267 04/11/17 09:07 CAH TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 421541 04/11/17 16:52 CAH TAL NSHTotal/NA
Client Sample ID: MW-06R Lab Sample ID: 490-125629-6
Matrix: WaterDate Collected: 04/04/17 13:35
Date Received: 04/05/17 09:40
Analysis 8260B BBR04/12/17 06:071 TAL NSH421467
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3005A 421823 04/12/17 19:03 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6010D 1 422191 04/13/17 15:23 LCS TAL NSHDissolved
Prep 3010A 422808 04/17/17 16:25 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 423523 04/20/17 00:18 LCS TAL NSHTotal/NA
Prep 3005A 422781 04/17/17 15:23 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6020B 1 424396 04/23/17 09:33 BLG TAL NSHDissolved
Prep 3005A 422781 04/17/17 15:23 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6020B 1 424515 04/23/17 21:35 CME TAL NSHDissolved
Prep 3010A 423185 04/18/17 20:08 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 424428 04/23/17 16:19 CME TAL NSHTotal/NA
Prep 7470A 421267 04/11/17 09:07 CAH TAL NSHDissolved30 mL 30 mL
Analysis 7470A 1 421541 04/11/17 16:27 CAH TAL NSHDissolved
Prep 7470A 421267 04/11/17 09:07 CAH TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 421541 04/11/17 16:55 CAH TAL NSHTotal/NA
Client Sample ID: MW-07R Lab Sample ID: 490-125629-7
Matrix: WaterDate Collected: 04/03/17 09:17
Date Received: 04/05/17 09:40
Analysis 8260B BBR04/12/17 06:321 TAL NSH421467
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3005A 421823 04/12/17 19:03 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6010D 1 422191 04/13/17 15:50 LCS TAL NSHDissolved
Prep 3010A 422808 04/17/17 16:25 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 423523 04/20/17 00:24 LCS TAL NSHTotal/NA
Prep 3005A 422781 04/17/17 15:23 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6020B 1 424396 04/23/17 09:39 BLG TAL NSHDissolved
Prep 3005A 422781 04/17/17 15:23 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6020B 1 424515 04/23/17 21:41 CME TAL NSHDissolved
Prep 3010A 423185 04/18/17 20:08 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 424428 04/23/17 16:24 CME TAL NSHTotal/NA
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Lab Chronicle
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-125629-1
Project/Site: Madison Co Operating Landfill
Client Sample ID: MW-07R Lab Sample ID: 490-125629-7
Matrix: WaterDate Collected: 04/03/17 09:17
Date Received: 04/05/17 09:40
Prep 7470A CAH04/11/17 09:07 TAL NSH421267
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Dissolved 30 mL 30 mL
Analysis 7470A 1 421541 04/11/17 16:36 CAH TAL NSHDissolved
Prep 7470A 421267 04/11/17 09:07 CAH TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 421541 04/11/17 16:57 CAH TAL NSHTotal/NA
Client Sample ID: MW-08 Lab Sample ID: 490-125629-8
Matrix: WaterDate Collected: 04/03/17 11:45
Date Received: 04/05/17 09:40
Analysis 8260B BBR04/12/17 06:571 TAL NSH421467
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3005A 421823 04/12/17 19:03 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6010D 1 422191 04/13/17 15:55 LCS TAL NSHDissolved
Prep 3010A 422808 04/17/17 16:25 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 423523 04/20/17 00:29 LCS TAL NSHTotal/NA
Prep 3005A 422781 04/17/17 15:23 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6020B 1 424396 04/23/17 09:44 BLG TAL NSHDissolved
Prep 3005A 422781 04/17/17 15:23 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6020B 1 424515 04/23/17 21:46 CME TAL NSHDissolved
Prep 3010A 423185 04/18/17 20:08 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 424428 04/23/17 16:30 CME TAL NSHTotal/NA
Prep 7470A 421267 04/11/17 09:07 CAH TAL NSHDissolved30 mL 30 mL
Analysis 7470A 1 421541 04/11/17 16:38 CAH TAL NSHDissolved
Prep 7470A 421267 04/11/17 09:07 CAH TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 421541 04/11/17 17:00 CAH TAL NSHTotal/NA
Client Sample ID: MW-09 Lab Sample ID: 490-125629-9
Matrix: WaterDate Collected: 04/04/17 14:53
Date Received: 04/05/17 09:40
Analysis 8260B BBR04/12/17 07:231 TAL NSH421467
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3005A 421823 04/12/17 19:03 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6010D 1 422191 04/13/17 16:01 LCS TAL NSHDissolved
Prep 3010A 422808 04/17/17 16:25 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 423523 04/20/17 00:34 LCS TAL NSHTotal/NA
Prep 3005A 422781 04/17/17 15:23 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6020B 1 424396 04/23/17 09:50 BLG TAL NSHDissolved
Prep 3005A 422781 04/17/17 15:23 JSF TAL NSHDissolved50 mL 50 mL
Analysis 6020B 1 424515 04/23/17 21:52 CME TAL NSHDissolved
Prep 3010A 423185 04/18/17 20:08 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 424428 04/23/17 16:35 CME TAL NSHTotal/NA
Prep 7470A 421610 04/12/17 09:48 CAH TAL NSHDissolved30 mL 30 mL
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Lab Chronicle
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-125629-1
Project/Site: Madison Co Operating Landfill
Client Sample ID: MW-09 Lab Sample ID: 490-125629-9
Matrix: WaterDate Collected: 04/04/17 14:53
Date Received: 04/05/17 09:40
Analysis 7470A CAH04/12/17 14:011 TAL NSH421722
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Dissolved
Prep 7470A 421610 04/12/17 09:48 CAH TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 421722 04/12/17 14:03 CAH TAL NSHTotal/NA
Client Sample ID: Trip Blank Lab Sample ID: 490-125629-10
Matrix: WaterDate Collected: 04/04/17 00:01
Date Received: 04/05/17 09:40
Analysis 8260B BBR04/12/17 01:561 TAL NSH421467
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Laboratory References:
TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL [phone]
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Method Summary
TestAmerica Job ID: 490-125629-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method Method Description LaboratoryProtocol
SW8468260BVolatile Organic Compounds (GC/MS)TAL NSH
SW8466010DMetals (ICP)TAL NSH
SW8466020BMetals (ICP/MS)TAL NSH
SW8467470AMercury (CVAA)TAL NSH
Protocol References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL [phone]
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Accreditation/Certification Summary
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-125629-1
Project/Site: Madison Co Operating Landfill
Laboratory: TestAmerica Nashville
The accreditations/certifications listed below are applicable to this report.
Authority Program EPA Region Identification Number Expiration Date
North Carolina (WW/SW)3874State Program 12-31-17
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Login Sample Receipt Checklist
Client: Anchor QEA of North Carolina PLLC Job Number: 490-125629-1
SDG Number:
Login Number: 125629
Question Answer Comment
Creator: West, Derrick D
List Source: TestAmerica Nashville
List Number: 1
TrueRadioactivity wasn't checked or is </= background as measured by a survey
meter.
TrueThe cooler's custody seal, if present, is intact.
N/ASample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
N/AContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
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ANALYTICAL REPORT
TestAmerica Laboratories, Inc.
TestAmerica Nashville
2960 Foster Creighton Drive
Nashville, TN 37204
Tel: [phone]
TestAmerica Job ID: 490-125658-1
Client Project/Site: Madison Co Operating Landfill
For:
Anchor QEA of North Carolina PLLC
231 W Haywood Street
Asheville, North Carolina 28801
Attn: Brian Gant
Authorized for release by:
4/26/2017 1:29:55 PM
Ken Hayes, Project Manager II
[phone]
[e-mail]
The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited
parameters, exceptions are noted in this report. This report may not be reproduced except in full,
and with written approval from the laboratory. For questions please contact the Project Manager
at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
TestAmerica Job ID: 490-125658-1
Page 2 of 28 TestAmerica Nashville4/26/2017
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .12
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .21
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .23
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .24
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .25
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .26
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .28
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Sample Summary
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID Client Sample ID ReceivedCollectedMatrix
490-125658-1 SW-01 Water 04/04/17 13:25 04/05/17 09:40
490-125658-2 SW-02R Water 04/04/17 10:10 04/05/17 09:40
490-125658-3 Trip Blank Water 04/04/17 00:01 04/05/17 09:40
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Case Narrative
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-125658-1
Project/Site: Madison Co Operating Landfill
Job ID: 490-125658-1
Laboratory: TestAmerica Nashville
Narrative
Job Narrative
490-125658-1
Comments
No additional comments.
Receipt
The samples were received on 4/5/2017 9:40 AM; the samples arrived in good condition, properly preserved and, where required, on ice.
The temperature of the cooler at receipt was 1.3º C.
GC/MS VOA
Method 8260B: The method blank for analytical batch 490-421467 contained Methylene Chloride above the method detection limit. This
target analyte concentration was less than the reporting limit (RL); therefore, re-extraction and/or re-analysis of samples was not
performed.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Metals
Method 6020B: The method blank for 490-423185 contained Vanadium and Zinc above the method detection limit (MDL). Associated
samples were not re-analyzed because results were less than the reporting limit (RL) OR practical quantitation limit (PQL).
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
VOA Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
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Definitions/Glossary
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Qualifiers
GC/MS VOA
Qualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Qualifier
Metals
Qualifier Description
F1 MS and/or MSD Recovery is outside acceptance limits.
Qualifier
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
B Compound was found in the blank and sample.
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CNF Contains no Free Liquid
DER Duplicate error ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision level concentration
MDA Minimum detectable activity
EDL Estimated Detection Limit
MDC Minimum detectable concentration
MDL Method Detection Limit
ML Minimum Level (Dioxin)
NC Not Calculated
ND Not detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit
QC Quality Control
RER Relative error ratio
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
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Client Sample Results
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125658-1Client Sample ID: SW-01
Matrix: WaterDate Collected: 04/04/17 13:25
Date Received: 04/05/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 04/12/17 07:48 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
10.0 0.500 ug/L 04/12/17 07:48 1Acrylonitrile<0.500
1.00 0.200 ug/L 04/12/17 07:48 1Benzene<0.200
1.00 0.150 ug/L 04/12/17 07:48 1Bromochloromethane<0.150
1.00 0.170 ug/L 04/12/17 07:48 1Bromodichloromethane<0.170
1.00 0.290 ug/L 04/12/17 07:48 1Bromoform<0.290
1.00 0.350 ug/L 04/12/17 07:48 1Bromomethane<0.350
50.0 2.64 ug/L 04/12/17 07:48 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 04/12/17 07:48 1Carbon disulfide <0.220
1.00 0.180 ug/L 04/12/17 07:48 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 04/12/17 07:48 1Chlorobenzene<0.180
1.00 0.360 ug/L 04/12/17 07:48 1Chloroethane<0.360
1.00 0.230 ug/L 04/12/17 07:48 1Chloroform<0.230
1.00 0.360 ug/L 04/12/17 07:48 1Chloromethane<0.360
1.00 0.210 ug/L 04/12/17 07:48 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 04/12/17 07:48 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 04/12/17 07:48 1Dibromochloromethane<0.250
10.0 0.940 ug/L 04/12/17 07:48 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 04/12/17 07:48 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 04/12/17 07:48 1Dibromomethane<0.450
1.00 0.190 ug/L 04/12/17 07:48 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 04/12/17 07:48 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 04/12/17 07:48 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 04/12/17 07:48 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 04/12/17 07:48 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 04/12/17 07:48 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 04/12/17 07:48 1Ethylbenzene<0.190
10.0 1.28 ug/L 04/12/17 07:48 12-Hexanone <1.28
10.0 1.50 ug/L 04/12/17 07:48 1Iodomethane<1.50
5.00 1.00 ug/L 04/12/17 07:48 1Methylene Chloride <1.00
10.0 0.810 ug/L 04/12/17 07:48 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 04/12/17 07:48 1Styrene<0.280
1.00 0.150 ug/L 04/12/17 07:48 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 04/12/17 07:48 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 04/12/17 07:48 1Tetrachloroethene<0.140
10.0 0.820 ug/L 04/12/17 07:48 1Tetrahydrofuran<0.820
1.00 0.170 ug/L 04/12/17 07:48 1Toluene<0.170
5.00 0.460 ug/L 04/12/17 07:48 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 04/12/17 07:48 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 04/12/17 07:48 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 04/12/17 07:48 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 04/12/17 07:48 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 04/12/17 07:48 1Trichloroethene<0.200
1.00 0.210 ug/L 04/12/17 07:48 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 04/12/17 07:48 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 04/12/17 07:48 1Vinyl acetate <1.71
1.00 0.180 ug/L 04/12/17 07:48 1Vinyl chloride <0.180
3.00 0.580 ug/L 04/12/17 07:48 1Xylenes, Total <0.580
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Client Sample Results
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125658-1Client Sample ID: SW-01
Matrix: WaterDate Collected: 04/04/17 13:25
Date Received: 04/05/17 09:40
4-Bromofluorobenzene (Surr)106 70-130 04/12/17 07:48 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)104 04/12/17 07:48 170-130
1,2-Dichloroethane-d4 (Surr)92 04/12/17 07:48 170-130
Toluene-d8 (Surr)96 04/12/17 07:48 170-130
Method: 6010D - Metals (ICP)
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/17/17 16:25 04/20/17 00:50 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:50 1Barium0.0603
0.00100 0.000500 mg/L 04/17/17 16:25 04/20/17 00:50 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/17/17 16:25 04/20/17 00:50 1Chromium<0.00300
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:50 1Copper<0.00500
0.00500 0.00200 mg/L 04/17/17 16:25 04/20/17 00:50 1Lead<0.00200
0.0100 0.00300 mg/L 04/17/17 16:25 04/20/17 00:50 1Nickel<0.00300
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:50 1Selenium<0.00500
0.00500 0.00300 mg/L 04/17/17 16:25 04/20/17 00:50 1Silver<0.00300
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 04/18/17 20:08 04/23/17 16:41 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 16:41 1Beryllium<0.100
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 16:41 1Cobalt1.29 J
2.00 0.800 ug/L 04/18/17 20:08 04/23/17 16:41 1Thallium<0.800
2.00 0.700 ug/L 04/18/17 20:08 04/23/17 16:41 1Vanadium3.26 B
25.0 5.20 ug/L 04/18/17 20:08 04/23/17 16:41 1Zinc6.99 J B
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 04/12/17 09:48 04/12/17 13:44 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
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Client Sample Results
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125658-2Client Sample ID: SW-02R
Matrix: WaterDate Collected: 04/04/17 10:10
Date Received: 04/05/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 04/12/17 08:13 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
10.0 0.500 ug/L 04/12/17 08:13 1Acrylonitrile<0.500
1.00 0.200 ug/L 04/12/17 08:13 1Benzene<0.200
1.00 0.150 ug/L 04/12/17 08:13 1Bromochloromethane<0.150
1.00 0.170 ug/L 04/12/17 08:13 1Bromodichloromethane<0.170
1.00 0.290 ug/L 04/12/17 08:13 1Bromoform<0.290
1.00 0.350 ug/L 04/12/17 08:13 1Bromomethane<0.350
50.0 2.64 ug/L 04/12/17 08:13 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 04/12/17 08:13 1Carbon disulfide <0.220
1.00 0.180 ug/L 04/12/17 08:13 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 04/12/17 08:13 1Chlorobenzene<0.180
1.00 0.360 ug/L 04/12/17 08:13 1Chloroethane<0.360
1.00 0.230 ug/L 04/12/17 08:13 1Chloroform<0.230
1.00 0.360 ug/L 04/12/17 08:13 1Chloromethane<0.360
1.00 0.210 ug/L 04/12/17 08:13 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 04/12/17 08:13 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 04/12/17 08:13 1Dibromochloromethane<0.250
10.0 0.940 ug/L 04/12/17 08:13 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 04/12/17 08:13 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 04/12/17 08:13 1Dibromomethane<0.450
1.00 0.190 ug/L 04/12/17 08:13 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 04/12/17 08:13 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 04/12/17 08:13 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 04/12/17 08:13 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 04/12/17 08:13 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 04/12/17 08:13 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 04/12/17 08:13 1Ethylbenzene<0.190
10.0 1.28 ug/L 04/12/17 08:13 12-Hexanone <1.28
10.0 1.50 ug/L 04/12/17 08:13 1Iodomethane<1.50
5.00 1.00 ug/L 04/12/17 08:13 1Methylene Chloride <1.00
10.0 0.810 ug/L 04/12/17 08:13 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 04/12/17 08:13 1Styrene<0.280
1.00 0.150 ug/L 04/12/17 08:13 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 04/12/17 08:13 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 04/12/17 08:13 1Tetrachloroethene<0.140
10.0 0.820 ug/L 04/12/17 08:13 1Tetrahydrofuran<0.820
1.00 0.170 ug/L 04/12/17 08:13 1Toluene<0.170
5.00 0.460 ug/L 04/12/17 08:13 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 04/12/17 08:13 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 04/12/17 08:13 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 04/12/17 08:13 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 04/12/17 08:13 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 04/12/17 08:13 1Trichloroethene<0.200
1.00 0.210 ug/L 04/12/17 08:13 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 04/12/17 08:13 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 04/12/17 08:13 1Vinyl acetate <1.71
1.00 0.180 ug/L 04/12/17 08:13 1Vinyl chloride <0.180
3.00 0.580 ug/L 04/12/17 08:13 1Xylenes, Total <0.580
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Client Sample Results
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125658-2Client Sample ID: SW-02R
Matrix: WaterDate Collected: 04/04/17 10:10
Date Received: 04/05/17 09:40
4-Bromofluorobenzene (Surr)102 70-130 04/12/17 08:13 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)102 04/12/17 08:13 170-130
1,2-Dichloroethane-d4 (Surr)95 04/12/17 08:13 170-130
Toluene-d8 (Surr)98 04/12/17 08:13 170-130
Method: 6010D - Metals (ICP)
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/17/17 16:25 04/20/17 00:55 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:55 1Barium0.0543
0.00100 0.000500 mg/L 04/17/17 16:25 04/20/17 00:55 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/17/17 16:25 04/20/17 00:55 1Chromium<0.00300
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:55 1Copper<0.00500
0.00500 0.00200 mg/L 04/17/17 16:25 04/20/17 00:55 1Lead<0.00200
0.0100 0.00300 mg/L 04/17/17 16:25 04/20/17 00:55 1Nickel<0.00300
0.0100 0.00500 mg/L 04/17/17 16:25 04/20/17 00:55 1Selenium<0.00500
0.00500 0.00300 mg/L 04/17/17 16:25 04/20/17 00:55 1Silver<0.00300
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 04/18/17 20:08 04/23/17 16:46 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 16:46 1Beryllium<0.100
2.00 0.100 ug/L 04/18/17 20:08 04/23/17 16:46 1Cobalt0.879 J
2.00 0.800 ug/L 04/18/17 20:08 04/23/17 16:46 1Thallium<0.800
2.00 0.700 ug/L 04/18/17 20:08 04/23/17 16:46 1Vanadium2.99 B
25.0 5.20 ug/L 04/18/17 20:08 04/23/17 16:46 1Zinc21.9 J B
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 04/12/17 09:48 04/12/17 13:58 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
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Client Sample Results
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125658-3Client Sample ID: Trip Blank
Matrix: WaterDate Collected: 04/04/17 00:01
Date Received: 04/05/17 09:40
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone 3.48 J 25.0 2.66 ug/L 04/12/17 02:21 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
10.0 0.500 ug/L 04/12/17 02:21 1Acrylonitrile<0.500
1.00 0.200 ug/L 04/12/17 02:21 1Benzene<0.200
1.00 0.150 ug/L 04/12/17 02:21 1Bromochloromethane<0.150
1.00 0.170 ug/L 04/12/17 02:21 1Bromodichloromethane<0.170
1.00 0.290 ug/L 04/12/17 02:21 1Bromoform<0.290
1.00 0.350 ug/L 04/12/17 02:21 1Bromomethane<0.350
50.0 2.64 ug/L 04/12/17 02:21 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 04/12/17 02:21 1Carbon disulfide <0.220
1.00 0.180 ug/L 04/12/17 02:21 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 04/12/17 02:21 1Chlorobenzene<0.180
1.00 0.360 ug/L 04/12/17 02:21 1Chloroethane<0.360
1.00 0.230 ug/L 04/12/17 02:21 1Chloroform<0.230
1.00 0.360 ug/L 04/12/17 02:21 1Chloromethane<0.360
1.00 0.210 ug/L 04/12/17 02:21 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 04/12/17 02:21 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 04/12/17 02:21 1Dibromochloromethane<0.250
10.0 0.940 ug/L 04/12/17 02:21 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 04/12/17 02:21 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 04/12/17 02:21 1Dibromomethane<0.450
1.00 0.190 ug/L 04/12/17 02:21 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 04/12/17 02:21 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 04/12/17 02:21 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 04/12/17 02:21 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 04/12/17 02:21 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 04/12/17 02:21 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 04/12/17 02:21 1Ethylbenzene<0.190
10.0 1.28 ug/L 04/12/17 02:21 12-Hexanone <1.28
10.0 1.50 ug/L 04/12/17 02:21 1Iodomethane<1.50
5.00 1.00 ug/L 04/12/17 02:21 1Methylene Chloride <1.00
10.0 0.810 ug/L 04/12/17 02:21 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 04/12/17 02:21 1Styrene<0.280
1.00 0.150 ug/L 04/12/17 02:21 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 04/12/17 02:21 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 04/12/17 02:21 1Tetrachloroethene<0.140
10.0 0.820 ug/L 04/12/17 02:21 1Tetrahydrofuran<0.820
1.00 0.170 ug/L 04/12/17 02:21 1Toluene<0.170
5.00 0.460 ug/L 04/12/17 02:21 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 04/12/17 02:21 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 04/12/17 02:21 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 04/12/17 02:21 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 04/12/17 02:21 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 04/12/17 02:21 1Trichloroethene<0.200
1.00 0.210 ug/L 04/12/17 02:21 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 04/12/17 02:21 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 04/12/17 02:21 1Vinyl acetate <1.71
1.00 0.180 ug/L 04/12/17 02:21 1Vinyl chloride <0.180
3.00 0.580 ug/L 04/12/17 02:21 1Xylenes, Total <0.580
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Client Sample Results
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Lab Sample ID: 490-125658-3Client Sample ID: Trip Blank
Matrix: WaterDate Collected: 04/04/17 00:01
Date Received: 04/05/17 09:40
4-Bromofluorobenzene (Surr)103 70-130 04/12/17 02:21 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)101 04/12/17 02:21 170-130
1,2-Dichloroethane-d4 (Surr)92 04/12/17 02:21 170-130
Toluene-d8 (Surr)97 04/12/17 02:21 170-130
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QC Sample Results
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS)
Client Sample ID: Method BlankLab Sample ID: MB 490-421467/7
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421467
RL MDL
Acetone <2.66 25.0 2.66 ug/L 04/12/17 01:06 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<0.500 0.50010.0 ug/L 04/12/17 01:06 1Acrylonitrile
<0.200 0.2001.00 ug/L 04/12/17 01:06 1Benzene
<0.150 0.1501.00 ug/L 04/12/17 01:06 1Bromochloromethane
<0.170 0.1701.00 ug/L 04/12/17 01:06 1Bromodichloromethane
<0.290 0.2901.00 ug/L 04/12/17 01:06 1Bromoform
<0.350 0.3501.00 ug/L 04/12/17 01:06 1Bromomethane
<2.64 2.6450.0 ug/L 04/12/17 01:06 12-Butanone (MEK)
<0.220 0.2201.00 ug/L 04/12/17 01:06 1Carbon disulfide
<0.180 0.1801.00 ug/L 04/12/17 01:06 1Carbon tetrachloride
<0.180 0.1801.00 ug/L 04/12/17 01:06 1Chlorobenzene
<0.360 0.3601.00 ug/L 04/12/17 01:06 1Chloroethane
<0.230 0.2301.00 ug/L 04/12/17 01:06 1Chloroform
<0.360 0.3601.00 ug/L 04/12/17 01:06 1Chloromethane
<0.210 0.2101.00 ug/L 04/12/17 01:06 1cis-1,2-Dichloroethene
<0.170 0.1701.00 ug/L 04/12/17 01:06 1cis-1,3-Dichloropropene
<0.250 0.2501.00 ug/L 04/12/17 01:06 1Dibromochloromethane
<0.940 0.94010.0 ug/L 04/12/17 01:06 11,2-Dibromo-3-Chloropropane
<0.210 0.2101.00 ug/L 04/12/17 01:06 11,2-Dibromoethane (EDB)
<0.450 0.4501.00 ug/L 04/12/17 01:06 1Dibromomethane
<0.190 0.1901.00 ug/L 04/12/17 01:06 11,2-Dichlorobenzene
<0.170 0.1701.00 ug/L 04/12/17 01:06 11,4-Dichlorobenzene
<0.240 0.2401.00 ug/L 04/12/17 01:06 11,1-Dichloroethane
<0.200 0.2001.00 ug/L 04/12/17 01:06 11,2-Dichloroethane
<0.250 0.2501.00 ug/L 04/12/17 01:06 11,1-Dichloroethene
<0.250 0.2501.00 ug/L 04/12/17 01:06 11,2-Dichloropropane
<0.190 0.1901.00 ug/L 04/12/17 01:06 1Ethylbenzene
<1.28 1.2810.0 ug/L 04/12/17 01:06 12-Hexanone
<1.50 1.5010.0 ug/L 04/12/17 01:06 1Iodomethane
1.127 J 1.005.00 ug/L 04/12/17 01:06 1Methylene Chloride
<0.810 0.81010.0 ug/L 04/12/17 01:06 14-Methyl-2-pentanone (MIBK)
<0.280 0.2801.00 ug/L 04/12/17 01:06 1Styrene
<0.150 0.1501.00 ug/L 04/12/17 01:06 11,1,1,2-Tetrachloroethane
<0.190 0.1901.00 ug/L 04/12/17 01:06 11,1,2,2-Tetrachloroethane
<0.140 0.1401.00 ug/L 04/12/17 01:06 1Tetrachloroethene
<0.820 0.82010.0 ug/L 04/12/17 01:06 1Tetrahydrofuran
<0.170 0.1701.00 ug/L 04/12/17 01:06 1Toluene
<0.460 0.4605.00 ug/L 04/12/17 01:06 1trans-1,4-Dichloro-2-butene
<0.230 0.2301.00 ug/L 04/12/17 01:06 1trans-1,2-Dichloroethene
<0.170 0.1701.00 ug/L 04/12/17 01:06 1trans-1,3-Dichloropropene
<0.190 0.1901.00 ug/L 04/12/17 01:06 11,1,1-Trichloroethane
<0.190 0.1901.00 ug/L 04/12/17 01:06 11,1,2-Trichloroethane
<0.200 0.2001.00 ug/L 04/12/17 01:06 1Trichloroethene
<0.210 0.2101.00 ug/L 04/12/17 01:06 1Trichlorofluoromethane
<0.230 0.2301.00 ug/L 04/12/17 01:06 11,2,3-Trichloropropane
<1.71 1.7110.0 ug/L 04/12/17 01:06 1Vinyl acetate
<0.180 0.1801.00 ug/L 04/12/17 01:06 1Vinyl chloride
<0.580 0.5803.00 ug/L 04/12/17 01:06 1Xylenes, Total
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QC Sample Results
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
4-Bromofluorobenzene (Surr)102 70-130 04/12/17 01:06 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
103 04/12/17 01:06 1Dibromofluoromethane (Surr)70-130
92 04/12/17 01:06 11,2-Dichloroethane-d4 (Surr)70-130
97 04/12/17 01:06 1Toluene-d8 (Surr)70-130
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-421467/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421467
Acetone 100 61.36 ug/L 61 39-150
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Acrylonitrile 200 138.5 ug/L 69 63-135
Benzene 20.0 18.62 ug/L 93 70-130
Bromochloromethane 20.0 16.38 ug/L 82 70-130
Bromodichloromethane 20.0 17.68 ug/L 88 70-130
Bromoform 20.0 14.13 ug/L 71 70-137
Bromomethane 20.0 17.73 ug/L 89 53-150
2-Butanone (MEK)100 65.11 ug/L 65 55-143
Carbon disulfide 20.0 18.82 ug/L 94 64-135
Carbon tetrachloride 20.0 18.45 ug/L 92 70-147
Chlorobenzene 20.0 18.60 ug/L 93 70-130
Chloroethane 20.0 20.93 ug/L 105 60-138
Chloroform 20.0 18.42 ug/L 92 70-130
Chloromethane 20.0 19.24 ug/L 96 33-150
cis-1,2-Dichloroethene 20.0 18.04 ug/L 90 70-130
cis-1,3-Dichloropropene 20.0 17.08 ug/L 85 70-133
Dibromochloromethane 20.0 15.58 ug/L 78 70-133
1,2-Dibromo-3-Chloropropane 20.0 11.46 ug/L 57 45-138
1,2-Dibromoethane (EDB)20.0 16.22 ug/L 81 70-130
Dibromomethane 20.0 16.82 ug/L 84 70-130
1,2-Dichlorobenzene 20.0 17.89 ug/L 89 70-130
1,4-Dichlorobenzene 20.0 18.54 ug/L 93 70-130
1,1-Dichloroethane 20.0 17.77 ug/L 89 70-130
1,2-Dichloroethane 20.0 16.30 ug/L 82 70-130
1,1-Dichloroethene 20.0 18.23 ug/L 91 70-132
1,2-Dichloropropane 20.0 16.83 ug/L 84 70-130
Ethylbenzene 20.0 18.19 ug/L 91 70-130
2-Hexanone 100 64.13 ug/L 64 54-142
Iodomethane 20.0 19.32 ug/L 97 40-150
Methylene Chloride 20.0 18.05 ug/L 90 70-130
4-Methyl-2-pentanone (MIBK)100 66.13 ug/L 66 60-137
Styrene 20.0 17.81 ug/L 89 70-130
1,1,1,2-Tetrachloroethane 20.0 17.34 ug/L 87 70-130
1,1,2,2-Tetrachloroethane 20.0 14.87 ug/L 74 69-131
Tetrachloroethene 20.0 18.88 ug/L 94 70-130
Tetrahydrofuran 40.0 25.12 ug/L 63 51-136
Toluene 20.0 18.97 ug/L 95 70-130
trans-1,4-Dichloro-2-butene 20.0 13.72 ug/L 69 41-150
trans-1,2-Dichloroethene 20.0 18.35 ug/L 92 70-130
trans-1,3-Dichloropropene 20.0 16.15 ug/L 81 63-142
1,1,1-Trichloroethane 20.0 18.78 ug/L 94 70-135
1,1,2-Trichloroethane 20.0 17.21 ug/L 86 70-130
Trichloroethene 20.0 17.41 ug/L 87 70-130
Trichlorofluoromethane 20.0 16.80 ug/L 84 59-150
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QC Sample Results
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-421467/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421467
1,2,3-Trichloropropane 20.0 15.79 ug/L 79 70-131
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Vinyl acetate 40.0 44.01 ug/L 110 54-146
Vinyl chloride 20.0 17.54 ug/L 88 57-137
Xylenes, Total 40.0 34.86 ug/L 87 70-132
4-Bromofluorobenzene (Surr)70 -130
Surrogate
100
LCS LCS
Qualifier Limits%Recovery
101Dibromofluoromethane (Surr)70 -130
901,2-Dichloroethane-d4 (Surr)70 -130
100Toluene-d8 (Surr)70 -130
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-125629-B-4 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421467
Acetone <2.66 100 68.57 ug/L 69 39-150 4 28
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Acrylonitrile <0.500 200 156.0 ug/L 78 50-135 1 23
Benzene <0.200 20.0 21.32 ug/L 107 55-147 1 22
Bromochloromethane <0.150 20.0 18.52 ug/L 93 59-132 2 21
Bromodichloromethane <0.170 20.0 19.99 ug/L 100 70-140 2 196
Bromoform <0.290 20.0 15.13 ug/L 76 53-150 1 20
Bromomethane <0.350 20.0 21.56 ug/L 108 30-150 6 44
2-Butanone (MEK)<2.64 100 66.40 ug/L 66 50-143 8 28
Carbon disulfide <0.220 20.0 21.26 ug/L 106 35-150 3 34
Carbon tetrachloride <0.180 20.0 22.40 ug/L 112 56-150 1 18
Chlorobenzene <0.180 20.0 20.60 ug/L 103 70-130 3 15
Chloroethane <0.360 20.0 21.21 ug/L 106 58-141 1 31
Chloroform <0.230 20.0 21.19 ug/L 106 66-138 0 21
Chloromethane <0.360 20.0 21.85 ug/L 109 10-150 3 43
cis-1,2-Dichloroethene <0.210 20.0 21.16 ug/L 106 68-131 4 21
cis-1,3-Dichloropropene <0.170 20.0 17.87 ug/L 89 70-133 3 19
Dibromochloromethane <0.250 20.0 17.45 ug/L 87 66-140 3 19
1,2-Dibromo-3-Chloropropane <0.940 20.0 11.11 ug/L 56 38-138 3 26
1,2-Dibromoethane (EDB)<0.210 20.0 18.08 ug/L 90 65-137 4 21
Dibromomethane <0.450 20.0 18.21 ug/L 91 70-130 1 19
1,2-Dichlorobenzene <0.190 20.0 20.05 ug/L 100 70-130 5 15
1,4-Dichlorobenzene <0.170 20.0 21.44 ug/L 107 70-130 4 14
1,1-Dichloroethane <0.240 20.0 20.89 ug/L 104 61-139 1 23
1,2-Dichloroethane <0.200 20.0 18.90 ug/L 94 64-136 4 22
1,1-Dichloroethene <0.250 20.0 21.51 ug/L 108 54-150 0 24
1,2-Dichloropropane <0.250 20.0 19.25 ug/L 96 67-130 4 19
Ethylbenzene <0.190 20.0 19.89 ug/L 99 65-139 3 18
2-Hexanone <1.28 100 60.25 ug/L 60 44-150 1 21
Iodomethane <1.50 20.0 21.63 ug/L 108 34-150 10 37
Methylene Chloride <1.00 20.0 17.85 ug/L 89 64-130 10 22
4-Methyl-2-pentanone (MIBK)<0.810 100 65.14 ug/L 65 50-140 1 24
Styrene <0.280 20.0 19.22 ug/L 96 70-130 0 16
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QC Sample Results
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-125629-B-4 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421467
1,1,1,2-Tetrachloroethane <0.150 20.0 19.35 ug/L 97 70-131 1 16
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
1,1,2,2-Tetrachloroethane <0.190 20.0 15.57 ug/L 78 56-145 3 19
Tetrachloroethene <0.140 20.0 22.38 ug/L 112 57-138 5 17
Tetrahydrofuran <0.820 40.0 23.49 ug/L 59 40-136 7 27
Toluene <0.170 20.0 21.14 ug/L 106 64-136 3 18
trans-1,4-Dichloro-2-butene <0.460 20.0 14.42 ug/L 72 39-150 2 28
trans-1,2-Dichloroethene <0.230 20.0 20.99 ug/L 105 59-143 2 25
trans-1,3-Dichloropropene <0.170 20.0 16.56 ug/L 83 63-142 0 18
1,1,1-Trichloroethane <0.190 20.0 22.40 ug/L 112 68-144 1 17
1,1,2-Trichloroethane <0.190 20.0 18.60 ug/L 93 70-130 2 18
Trichloroethene <0.200 20.0 20.30 ug/L 102 63-135 7 17
Trichlorofluoromethane <0.210 20.0 22.98 ug/L 115 44-150 2 32
1,2,3-Trichloropropane <0.230 20.0 16.64 ug/L 83 65-131 3 19
Vinyl acetate <1.71 40.0 44.57 ug/L 111 43-146 9 20
Vinyl chloride <0.180 20.0 24.70 ug/L 123 57-150 14 37
Xylenes, Total <0.580 40.0 38.57 ug/L 96 69-132 3 17
4-Bromofluorobenzene (Surr)70 -130
Surrogate
96
MSD MSD
Qualifier Limits%Recovery
101Dibromofluoromethane (Surr)70 -130
941,2-Dichloroethane-d4 (Surr)70 -130
98Toluene-d8 (Surr)70 -130
Client Sample ID: Matrix SpikeLab Sample ID: 490-125629-C-4 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421467
Acetone <2.66 100 71.48 ug/L 71 39-150
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Acrylonitrile <0.500 200 154.9 ug/L 77 50-135
Benzene <0.200 20.0 21.16 ug/L 106 55-147
Bromochloromethane <0.150 20.0 18.23 ug/L 91 59-132
Bromodichloromethane <0.170 20.0 19.52 ug/L 98 70-140
Bromoform <0.290 20.0 15.20 ug/L 76 53-150
Bromomethane <0.350 20.0 20.29 ug/L 101 30-150
2-Butanone (MEK)<2.64 100 71.74 ug/L 72 50-143
Carbon disulfide <0.220 20.0 20.53 ug/L 103 35-150
Carbon tetrachloride <0.180 20.0 22.21 ug/L 111 56-150
Chlorobenzene <0.180 20.0 20.00 ug/L 100 70-130
Chloroethane <0.360 20.0 21.49 ug/L 107 58-141
Chloroform <0.230 20.0 21.10 ug/L 105 66-138
Chloromethane <0.360 20.0 22.43 ug/L 112 10-150
cis-1,2-Dichloroethene <0.210 20.0 20.31 ug/L 102 68-131
cis-1,3-Dichloropropene <0.170 20.0 17.39 ug/L 87 70-133
Dibromochloromethane <0.250 20.0 18.02 ug/L 90 66-140
1,2-Dibromo-3-Chloropropane <0.940 20.0 11.49 ug/L 57 38-138
1,2-Dibromoethane (EDB)<0.210 20.0 17.30 ug/L 86 65-137
Dibromomethane <0.450 20.0 18.30 ug/L 92 70-130
TestAmerica Nashville
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QC Sample Results
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Matrix SpikeLab Sample ID: 490-125629-C-4 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421467
1,2-Dichlorobenzene <0.190 20.0 19.15 ug/L 96 70-130
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
1,4-Dichlorobenzene <0.170 20.0 20.50 ug/L 103 70-130
1,1-Dichloroethane <0.240 20.0 20.69 ug/L 103 61-139
1,2-Dichloroethane <0.200 20.0 18.19 ug/L 91 64-136
1,1-Dichloroethene <0.250 20.0 21.59 ug/L 108 54-150
1,2-Dichloropropane <0.250 20.0 18.55 ug/L 93 67-130
Ethylbenzene <0.190 20.0 19.39 ug/L 97 65-139
2-Hexanone <1.28 100 59.55 ug/L 60 44-150
Iodomethane <1.50 20.0 19.51 ug/L 98 34-150
Methylene Chloride <1.00 20.0 19.73 ug/L 99 64-130
4-Methyl-2-pentanone (MIBK)<0.810 100 64.72 ug/L 65 50-140
Styrene <0.280 20.0 19.31 ug/L 97 70-130
1,1,1,2-Tetrachloroethane <0.150 20.0 19.08 ug/L 95 70-131
1,1,2,2-Tetrachloroethane <0.190 20.0 16.03 ug/L 80 56-145
Tetrachloroethene <0.140 20.0 21.19 ug/L 106 57-138
Tetrahydrofuran <0.820 40.0 21.94 ug/L 55 40-136
Toluene <0.170 20.0 20.48 ug/L 102 64-136
trans-1,4-Dichloro-2-butene <0.460 20.0 14.76 ug/L 74 39-150
trans-1,2-Dichloroethene <0.230 20.0 20.51 ug/L 103 59-143
trans-1,3-Dichloropropene <0.170 20.0 16.54 ug/L 83 63-142
1,1,1-Trichloroethane <0.190 20.0 22.69 ug/L 113 68-144
1,1,2-Trichloroethane <0.190 20.0 18.22 ug/L 91 70-130
Trichloroethene <0.200 20.0 18.88 ug/L 94 63-135
Trichlorofluoromethane <0.210 20.0 23.51 ug/L 118 44-150
1,2,3-Trichloropropane <0.230 20.0 16.09 ug/L 80 65-131
Vinyl acetate <1.71 40.0 40.72 ug/L 102 43-146
Vinyl chloride <0.180 20.0 21.42 ug/L 107 57-150
Xylenes, Total <0.580 40.0 37.30 ug/L 93 69-132
4-Bromofluorobenzene (Surr)70 -130
Surrogate
98
MS MS
Qualifier Limits%Recovery
101Dibromofluoromethane (Surr)70 -130
941,2-Dichloroethane-d4 (Surr)70 -130
97Toluene-d8 (Surr)70 -130
Method: 6010D - Metals (ICP)
Client Sample ID: Method BlankLab Sample ID: MB 490-422808/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 423523 Prep Batch: 422808
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/17/17 16:25 04/19/17 22:51 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<0.00500 0.005000.0100 mg/L 04/17/17 16:25 04/19/17 22:51 1Barium
<0.000500 0.0005000.00100 mg/L 04/17/17 16:25 04/19/17 22:51 1Cadmium
<0.00300 0.003000.00500 mg/L 04/17/17 16:25 04/19/17 22:51 1Chromium
<0.00500 0.005000.0100 mg/L 04/17/17 16:25 04/19/17 22:51 1Copper
<0.00200 0.002000.00500 mg/L 04/17/17 16:25 04/19/17 22:51 1Lead
TestAmerica Nashville
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QC Sample Results
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 6010D - Metals (ICP) (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 490-422808/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 423523 Prep Batch: 422808
RL MDL
Nickel <0.00300 0.0100 0.00300 mg/L 04/17/17 16:25 04/19/17 22:51 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<0.00500 0.005000.0100 mg/L 04/17/17 16:25 04/19/17 22:51 1Selenium
<0.00300 0.003000.00500 mg/L 04/17/17 16:25 04/19/17 22:51 1Silver
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-422808/22-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 423523 Prep Batch: 422808
Silver 0.0500 0.05480 mg/L 110 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-422808/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 423523 Prep Batch: 422808
Arsenic 0.100 0.09820 mg/L 98 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Barium 0.100 0.1015 mg/L 102 80-120
Cadmium 0.100 0.1019 mg/L 102 80-120
Chromium 0.100 0.1010 mg/L 101 80-120
Copper 0.100 0.1022 mg/L 102 80-120
Lead 0.100 0.1040 mg/L 104 80-120
Nickel 0.100 0.1045 mg/L 105 80-120
Selenium 0.100 0.09730 mg/L 97 80-120
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-422808/23-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 423523 Prep Batch: 422808
Silver 0.0500 0.05410 mg/L 108 80-120 1 20
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-422808/3-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 423523 Prep Batch: 422808
Arsenic 0.100 0.09900 mg/L 99 80-120 1 20
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Barium 0.100 0.1053 mg/L 105 80-120 4 20
Cadmium 0.100 0.1035 mg/L 104 80-120 2 20
Chromium 0.100 0.1029 mg/L 103 80-120 2 20
Copper 0.100 0.1050 mg/L 105 80-120 3 20
Lead 0.100 0.1070 mg/L 107 80-120 3 20
Nickel 0.100 0.1066 mg/L 107 80-120 2 20
Selenium 0.100 0.09980 mg/L 100 80-120 3 20
TestAmerica Nashville
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QC Sample Results
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 6010D - Metals (ICP) (Continued)
Client Sample ID: Matrix SpikeLab Sample ID: 490-125629-D-1-C MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 423523 Prep Batch: 422808
Arsenic <0.00860 0.100 0.1015 mg/L 102 75-125
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Barium 0.103 0.100 0.2058 mg/L 103 75-125
Cadmium <0.000500 0.100 0.1031 mg/L 103 75-125
Chromium <0.00300 0.100 0.1048 mg/L 105 75-125
Copper <0.00500 0.100 0.1044 mg/L 104 75-125
Lead <0.00200 0.100 0.1044 mg/L 104 75-125
Nickel <0.00300 0.100 0.1068 mg/L 107 75-125
Selenium <0.00500 0.100 0.09800 mg/L 98 75-125
Silver <0.00300 F1 0.100 0.06260 F1 mg/L 63 75-125
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-125629-D-1-D MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 423523 Prep Batch: 422808
Arsenic <0.00860 0.100 0.09950 mg/L 100 75-125 2 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Barium 0.103 0.100 0.2060 mg/L 103 75-125 0 20
Cadmium <0.000500 0.100 0.1032 mg/L 103 75-125 0 20
Chromium <0.00300 0.100 0.1029 mg/L 103 75-125 2 20
Copper <0.00500 0.100 0.1020 mg/L 102 75-125 2 20
Lead <0.00200 0.100 0.1049 mg/L 105 75-125 0 20
Nickel <0.00300 0.100 0.1069 mg/L 107 75-125 0 20
Selenium <0.00500 0.100 0.09800 mg/L 98 75-125 0 20
Silver <0.00300 F1 0.100 0.06070 F1 mg/L 61 75-125 3 20
Method: 6020B - Metals (ICP/MS)
Client Sample ID: Method BlankLab Sample ID: MB 490-423185/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 424428 Prep Batch: 423185
RL MDL
Antimony <0.800 2.00 0.800 ug/L 04/18/17 20:08 04/23/17 15:08 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<0.100 0.1002.00 ug/L 04/18/17 20:08 04/23/17 15:08 1Beryllium
<0.100 0.1002.00 ug/L 04/18/17 20:08 04/23/17 15:08 1Cobalt
<0.800 0.8002.00 ug/L 04/18/17 20:08 04/23/17 15:08 1Thallium
1.239 J 0.7002.00 ug/L 04/18/17 20:08 04/23/17 15:08 1Vanadium
15.47 J 5.2025.0 ug/L 04/18/17 20:08 04/23/17 15:08 1Zinc
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-423185/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 424428 Prep Batch: 423185
Antimony 100 88.13 ug/L 88 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Beryllium 100 81.62 ug/L 82 80-120
Cobalt 100 97.89 ug/L 98 80-120
Thallium 100 94.44 ug/L 94 80-120
TestAmerica Nashville
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QC Sample Results
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 6020B - Metals (ICP/MS) (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-423185/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 424428 Prep Batch: 423185
Vanadium 100 96.95 ug/L 97 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-423185/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 425142 Prep Batch: 423185
Zinc 100 85.20 ug/L 85 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: Matrix SpikeLab Sample ID: 490-125629-E-1-B MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 424428 Prep Batch: 423185
Antimony <0.800 100 84.23 ug/L 84 75-125
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Beryllium <0.100 100 75.30 ug/L 75 75-125
Cobalt 0.792 J 100 96.69 ug/L 96 75-125
Thallium <0.800 100 91.87 ug/L 92 75-125
Vanadium 1.41 J B 100 93.35 ug/L 92 75-125
Zinc 12.3 J F1 B 100 80.24 F1 ug/L 68 75-125
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-125629-E-1-C MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 424428 Prep Batch: 423185
Antimony <0.800 100 90.02 ug/L 90 75-125 7 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Beryllium <0.100 100 84.19 ug/L 84 75-125 11 20
Cobalt 0.792 J 100 101.1 ug/L 100 75-125 4 20
Thallium <0.800 100 97.44 ug/L 97 75-125 6 20
Vanadium 1.41 J B 100 101.4 ug/L 100 75-125 8 20
Zinc 12.3 J F1 B 100 80.39 F1 ug/L 68 75-125 0 20
Method: 7470A - Mercury (CVAA)
Client Sample ID: Method BlankLab Sample ID: MB 490-421610/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421722 Prep Batch: 421610
RL MDL
Mercury <0.100 0.200 0.100 ug/L 04/12/17 09:48 04/12/17 13:39 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-421610/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421722 Prep Batch: 421610
Mercury 1.00 1.113 ug/L 111 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
TestAmerica Nashville
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QC Sample Results
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method: 7470A - Mercury (CVAA) (Continued)
Client Sample ID: SW-01Lab Sample ID: 490-125658-1 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421722 Prep Batch: 421610
Mercury <0.100 1.00 1.230 ug/L 123 75-125
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Client Sample ID: SW-01Lab Sample ID: 490-125658-1 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421722 Prep Batch: 421610
Mercury <0.100 1.00 1.116 ug/L 112 75-125 10 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
TestAmerica Nashville
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QC Association Summary
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
GC/MS VOA
Analysis Batch: 421467
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 8260B490-125658-1 SW-01 Total/NA
Water 8260B490-125658-2 SW-02R Total/NA
Water 8260B490-125658-3 Trip Blank Total/NA
Water 8260BMB 490-421467/7 Method Blank Total/NA
Water 8260BLCS 490-421467/4 Lab Control Sample Total/NA
Water 8260B490-125629-B-4 MSD Matrix Spike Duplicate Total/NA
Water 8260B490-125629-C-4 MS Matrix Spike Total/NA
Metals
Prep Batch: 421610
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A490-125658-1 SW-01 Total/NA
Water 7470A490-125658-2 SW-02R Total/NA
Water 7470AMB 490-421610/1-A Method Blank Total/NA
Water 7470ALCS 490-421610/2-A Lab Control Sample Total/NA
Water 7470A490-125658-1 MS SW-01 Total/NA
Water 7470A490-125658-1 MSD SW-01 Total/NA
Analysis Batch: 421722
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A 421610490-125658-1 SW-01 Total/NA
Water 7470A 421610490-125658-2 SW-02R Total/NA
Water 7470A 421610MB 490-421610/1-A Method Blank Total/NA
Water 7470A 421610LCS 490-421610/2-A Lab Control Sample Total/NA
Water 7470A 421610490-125658-1 MS SW-01 Total/NA
Water 7470A 421610490-125658-1 MSD SW-01 Total/NA
Prep Batch: 422808
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3010A490-125658-1 SW-01 Total/NA
Water 3010A490-125658-2 SW-02R Total/NA
Water 3010AMB 490-422808/1-A Method Blank Total/NA
Water 3010ALCS 490-422808/22-A Lab Control Sample Total/NA
Water 3010ALCS 490-422808/2-A Lab Control Sample Total/NA
Water 3010ALCSD 490-422808/23-A Lab Control Sample Dup Total/NA
Water 3010ALCSD 490-422808/3-A Lab Control Sample Dup Total/NA
Water 3010A490-125629-D-1-C MS Matrix Spike Total/NA
Water 3010A490-125629-D-1-D MSD Matrix Spike Duplicate Total/NA
Prep Batch: 423185
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3010A490-125658-1 SW-01 Total/NA
Water 3010A490-125658-2 SW-02R Total/NA
Water 3010AMB 490-423185/1-A Method Blank Total/NA
Water 3010ALCS 490-423185/2-A Lab Control Sample Total/NA
Water 3010A490-125629-E-1-B MS Matrix Spike Total/NA
Water 3010A490-125629-E-1-C MSD Matrix Spike Duplicate Total/NA
TestAmerica Nashville
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QC Association Summary
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Metals (Continued)
Analysis Batch: 423523
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6010D 422808490-125658-1 SW-01 Total/NA
Water 6010D 422808490-125658-2 SW-02R Total/NA
Water 6010D 422808MB 490-422808/1-A Method Blank Total/NA
Water 6010D 422808LCS 490-422808/22-A Lab Control Sample Total/NA
Water 6010D 422808LCS 490-422808/2-A Lab Control Sample Total/NA
Water 6010D 422808LCSD 490-422808/23-A Lab Control Sample Dup Total/NA
Water 6010D 422808LCSD 490-422808/3-A Lab Control Sample Dup Total/NA
Water 6010D 422808490-125629-D-1-C MS Matrix Spike Total/NA
Water 6010D 422808490-125629-D-1-D MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 424428
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020B 423185490-125658-1 SW-01 Total/NA
Water 6020B 423185490-125658-2 SW-02R Total/NA
Water 6020B 423185MB 490-423185/1-A Method Blank Total/NA
Water 6020B 423185LCS 490-423185/2-A Lab Control Sample Total/NA
Water 6020B 423185490-125629-E-1-B MS Matrix Spike Total/NA
Water 6020B 423185490-125629-E-1-C MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 425142
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020B 423185LCS 490-423185/2-A Lab Control Sample Total/NA
TestAmerica Nashville
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Lab Chronicle
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-125658-1
Project/Site: Madison Co Operating Landfill
Client Sample ID: SW-01 Lab Sample ID: 490-125658-1
Matrix: WaterDate Collected: 04/04/17 13:25
Date Received: 04/05/17 09:40
Analysis 8260B BBR04/12/17 07:481 TAL NSH421467
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3010A 422808 04/17/17 16:25 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 423523 04/20/17 00:50 LCS TAL NSHTotal/NA
Prep 3010A 423185 04/18/17 20:08 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 424428 04/23/17 16:41 CME TAL NSHTotal/NA
Prep 7470A 421610 04/12/17 09:48 CAH TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 421722 04/12/17 13:44 CAH TAL NSHTotal/NA
Client Sample ID: SW-02R Lab Sample ID: 490-125658-2
Matrix: WaterDate Collected: 04/04/17 10:10
Date Received: 04/05/17 09:40
Analysis 8260B BBR04/12/17 08:131 TAL NSH421467
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Prep 3010A 422808 04/17/17 16:25 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 423523 04/20/17 00:55 LCS TAL NSHTotal/NA
Prep 3010A 423185 04/18/17 20:08 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 424428 04/23/17 16:46 CME TAL NSHTotal/NA
Prep 7470A 421610 04/12/17 09:48 CAH TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 421722 04/12/17 13:58 CAH TAL NSHTotal/NA
Client Sample ID: Trip Blank Lab Sample ID: 490-125658-3
Matrix: WaterDate Collected: 04/04/17 00:01
Date Received: 04/05/17 09:40
Analysis 8260B BBR04/12/17 02:211 TAL NSH421467
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Laboratory References:
TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL [phone]
TestAmerica Nashville
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Method Summary
TestAmerica Job ID: 490-125658-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Operating Landfill
Method Method Description LaboratoryProtocol
SW8468260BVolatile Organic Compounds (GC/MS)TAL NSH
SW8466010DMetals (ICP)TAL NSH
SW8466020BMetals (ICP/MS)TAL NSH
SW8467470AMercury (CVAA)TAL NSH
Protocol References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL [phone]
TestAmerica Nashville
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Accreditation/Certification Summary
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-125658-1
Project/Site: Madison Co Operating Landfill
Laboratory: TestAmerica Nashville
The accreditations/certifications listed below are applicable to this report.
Authority Program EPA Region Identification Number Expiration Date
North Carolina (WW/SW)3874State Program 12-31-17
TestAmerica Nashville
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Login Sample Receipt Checklist
Client: Anchor QEA of North Carolina PLLC Job Number: 490-125658-1
SDG Number:
Login Number: 125658
Question Answer Comment
Creator: West, Derrick D
List Source: TestAmerica Nashville
List Number: 1
TrueRadioactivity wasn't checked or is </= background as measured by a survey
meter.
TrueThe cooler's custody seal, if present, is intact.
N/ASample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
N/AContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
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ANALYTICAL REPORT
TestAmerica Laboratories, Inc.
TestAmerica Nashville
2960 Foster Creighton Drive
Nashville, TN 37204
Tel: [phone]
TestAmerica Job ID: 490-125420-1
Client Project/Site: Madison co Operation Landfill Leachate
For:
Anchor QEA of North Carolina PLLC
231 W Haywood Street
Asheville, North Carolina 28801
Attn: Brian Gant
Authorized for release by:
4/28/2017 11:13:14 AM
Ken Hayes, Project Manager II
[phone]
[e-mail]
The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited
parameters, exceptions are noted in this report. This report may not be reproduced except in full,
and with written approval from the laboratory. For questions please contact the Project Manager
at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
TestAmerica Job ID: 490-125420-1
Page 2 of 31 TestAmerica Nashville4/28/2017
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .10
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .23
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .26
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .27
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .28
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .29
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .31
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Sample Summary
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Lab Sample ID Client Sample ID ReceivedCollectedMatrix
490-125420-1 LT-01 Water 04/03/17 12:10 04/04/17 09:35
490-125420-2 Trip Blank Water 04/03/17 00:01 04/04/17 09:35
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Case Narrative
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-125420-1
Project/Site: Madison co Operation Landfill Leachate
Job ID: 490-125420-1
Laboratory: TestAmerica Nashville
Narrative
Job Narrative
490-125420-1
Comments
No additional comments.
Receipt
The samples were received on 4/4/2017 9:35 AM; the samples arrived in good condition, properly preserved and, where required, on ice.
The temperature of the cooler at receipt was 3.5º C.
GC/MS VOA
Method(s) 8260B: Bromoform recovery was low. Data reported with marginal exceedance. (LCSD 490-421333/4)
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
HPLC/IC
Method 300.0: The following sample was diluted due to the nature of the sample matrix: LT-01 (490-125420-1). Elevated reporting limits
(RLs) are provided.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Metals
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
General Chemistry
Method 353.2: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for analytical batch 490-420141 were outside control limits.
Sample matrix interference and/or non-homogeneity are suspected because the associated laboratory control sample (LCS) recovery was
within acceptance limits.
Method SM 5220D: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for analytical batch 490-421977 were outside control
limits. Sample matrix interference and/or non-homogeneity are suspected because the associated laboratory control sample (LCS)
recovery was within acceptance limits.
Method SM 5220D: Due to the high concentration of Chemical Oxygen Demand, one of the matrix spike / matrix spike duplicate (MS/MSD)
for analytical batch 490-421977 could not be evaluated for accuracy and precision. The associated laboratory control sample (LCS) met
acceptance criteria.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
VOA Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
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Definitions/Glossary
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Qualifiers
GC/MS VOA
Qualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Qualifier
*LCS or LCSD is outside acceptance limits.
Metals
Qualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Qualifier
F1 MS and/or MSD Recovery is outside acceptance limits.
General Chemistry
Qualifier Description
F1 MS and/or MSD Recovery is outside acceptance limits.
Qualifier
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CNF Contains no Free Liquid
DER Duplicate error ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision level concentration
MDA Minimum detectable activity
EDL Estimated Detection Limit
MDC Minimum detectable concentration
MDL Method Detection Limit
ML Minimum Level (Dioxin)
NC Not Calculated
ND Not detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit
QC Quality Control
RER Relative error ratio
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
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Client Sample Results
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Lab Sample ID: 490-125420-1Client Sample ID: LT-01
Matrix: WaterDate Collected: 04/03/17 12:10
Date Received: 04/04/17 09:35
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone 4.76 J 25.0 2.66 ug/L 04/11/17 16:44 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
10.0 0.500 ug/L 04/11/17 16:44 1Acrylonitrile<0.500
1.00 0.200 ug/L 04/11/17 16:44 1Benzene<0.200
1.00 0.150 ug/L 04/11/17 16:44 1Bromochloromethane<0.150
1.00 0.170 ug/L 04/11/17 16:44 1Bromodichloromethane<0.170
1.00 0.290 ug/L 04/11/17 16:44 1Bromoform<0.290
1.00 0.350 ug/L 04/11/17 16:44 1Bromomethane<0.350
50.0 2.64 ug/L 04/11/17 16:44 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 04/11/17 16:44 1Carbon disulfide <0.220
1.00 0.180 ug/L 04/11/17 16:44 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 04/11/17 16:44 1Chlorobenzene<0.180
1.00 0.360 ug/L 04/11/17 16:44 1Chloroethane<0.360
1.00 0.230 ug/L 04/11/17 16:44 1Chloroform<0.230
1.00 0.360 ug/L 04/11/17 16:44 1Chloromethane<0.360
1.00 0.210 ug/L 04/11/17 16:44 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 04/11/17 16:44 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 04/11/17 16:44 1Dibromochloromethane<0.250
10.0 0.940 ug/L 04/11/17 16:44 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 04/11/17 16:44 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 04/11/17 16:44 1Dibromomethane<0.450
1.00 0.190 ug/L 04/11/17 16:44 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 04/11/17 16:44 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 04/11/17 16:44 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 04/11/17 16:44 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 04/11/17 16:44 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 04/11/17 16:44 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 04/11/17 16:44 1Ethylbenzene<0.190
10.0 1.28 ug/L 04/11/17 16:44 12-Hexanone <1.28
10.0 1.50 ug/L 04/11/17 16:44 1Iodomethane<1.50
5.00 1.00 ug/L 04/11/17 16:44 1Methylene Chloride <1.00
10.0 0.810 ug/L 04/11/17 16:44 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 04/11/17 16:44 1Styrene<0.280
1.00 0.150 ug/L 04/11/17 16:44 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 04/11/17 16:44 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 04/11/17 16:44 1Tetrachloroethene<0.140
10.0 0.820 ug/L 04/11/17 16:44 1Tetrahydrofuran<0.820
1.00 0.170 ug/L 04/11/17 16:44 1Toluene<0.170
5.00 0.460 ug/L 04/11/17 16:44 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 04/11/17 16:44 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 04/11/17 16:44 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 04/11/17 16:44 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 04/11/17 16:44 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 04/11/17 16:44 1Trichloroethene<0.200
1.00 0.210 ug/L 04/11/17 16:44 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 04/11/17 16:44 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 04/11/17 16:44 1Vinyl acetate <1.71
1.00 0.180 ug/L 04/11/17 16:44 1Vinyl chloride <0.180
3.00 0.580 ug/L 04/11/17 16:44 1Xylenes, Total <0.580
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Client Sample Results
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Lab Sample ID: 490-125420-1Client Sample ID: LT-01
Matrix: WaterDate Collected: 04/03/17 12:10
Date Received: 04/04/17 09:35
4-Bromofluorobenzene (Surr)106 70-130 04/11/17 16:44 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)102 04/11/17 16:44 170-130
1,2-Dichloroethane-d4 (Surr)90 04/11/17 16:44 170-130
Toluene-d8 (Surr)100 04/11/17 16:44 170-130
Method: 300.0 - Anions, Ion Chromatography
RL MDL
Sulfate 154 20.0 12.0 mg/L 04/15/17 08:58 20
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Method: 6010D - Metals (ICP)
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/13/17 20:11 04/17/17 19:53 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.0100 0.00500 mg/L 04/13/17 20:11 04/17/17 19:53 1Barium0.122
0.00100 0.000500 mg/L 04/13/17 20:11 04/17/17 19:53 1Cadmium<0.000500
0.00500 0.00300 mg/L 04/13/17 20:11 04/17/17 19:53 1Chromium<0.00300
0.0100 0.00500 mg/L 04/13/17 20:11 04/17/17 19:53 1Copper0.00970 J
0.00500 0.00200 mg/L 04/13/17 20:11 04/17/17 19:53 1Lead<0.00200
0.0100 0.00300 mg/L 04/13/17 20:11 04/17/17 19:53 1Nickel0.0381
0.0100 0.00500 mg/L 04/13/17 20:11 04/17/17 19:53 1Selenium<0.00500
0.00500 0.00300 mg/L 04/13/17 20:11 04/17/17 19:53 1Silver<0.00300
Method: 6020B - Metals (ICP/MS)
RL MDL
Antimony <0.800 2.00 0.800 ug/L 04/13/17 19:58 04/21/17 02:08 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
2.00 0.100 ug/L 04/13/17 19:58 04/21/17 18:08 1Beryllium<0.100
2.00 0.100 ug/L 04/13/17 19:58 04/21/17 02:08 1Cobalt12.2
2.00 0.800 ug/L 04/13/17 19:58 04/21/17 02:08 1Thallium<0.800
2.00 0.700 ug/L 04/13/17 19:58 04/21/17 02:08 1Vanadium7.53
25.0 5.20 ug/L 04/23/17 17:17 04/27/17 03:52 1Zinc19.2 J
Method: 7470A - Mercury (CVAA)
RL MDL
Mercury <0.100 0.200 0.100 ug/L 04/11/17 09:07 04/11/17 15:52 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
General Chemistry
RL MDL
Phosphorus, Total 0.107 0.100 0.0500 mg/L 04/05/17 10:22 04/05/17 19:54 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
0.100 0.0400 mg/L 04/05/17 09:39 1Nitrate as N 38.8
20.0 4.00 mg/L 04/13/17 10:44 1Chemical Oxygen Demand 130
RL RL
Biochemical Oxygen Demand 2.24 2.00 2.00 mg/L 04/04/17 20:26 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
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Client Sample Results
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Lab Sample ID: 490-125420-2Client Sample ID: Trip Blank
Matrix: WaterDate Collected: 04/03/17 00:01
Date Received: 04/04/17 09:35
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
Acetone <2.66 25.0 2.66 ug/L 04/11/17 16:19 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
10.0 0.500 ug/L 04/11/17 16:19 1Acrylonitrile<0.500
1.00 0.200 ug/L 04/11/17 16:19 1Benzene<0.200
1.00 0.150 ug/L 04/11/17 16:19 1Bromochloromethane<0.150
1.00 0.170 ug/L 04/11/17 16:19 1Bromodichloromethane<0.170
1.00 0.290 ug/L 04/11/17 16:19 1Bromoform<0.290
1.00 0.350 ug/L 04/11/17 16:19 1Bromomethane<0.350
50.0 2.64 ug/L 04/11/17 16:19 12-Butanone (MEK)<2.64
1.00 0.220 ug/L 04/11/17 16:19 1Carbon disulfide <0.220
1.00 0.180 ug/L 04/11/17 16:19 1Carbon tetrachloride <0.180
1.00 0.180 ug/L 04/11/17 16:19 1Chlorobenzene<0.180
1.00 0.360 ug/L 04/11/17 16:19 1Chloroethane<0.360
1.00 0.230 ug/L 04/11/17 16:19 1Chloroform<0.230
1.00 0.360 ug/L 04/11/17 16:19 1Chloromethane<0.360
1.00 0.210 ug/L 04/11/17 16:19 1cis-1,2-Dichloroethene <0.210
1.00 0.170 ug/L 04/11/17 16:19 1cis-1,3-Dichloropropene <0.170
1.00 0.250 ug/L 04/11/17 16:19 1Dibromochloromethane<0.250
10.0 0.940 ug/L 04/11/17 16:19 11,2-Dibromo-3-Chloropropane <0.940
1.00 0.210 ug/L 04/11/17 16:19 11,2-Dibromoethane (EDB)<0.210
1.00 0.450 ug/L 04/11/17 16:19 1Dibromomethane<0.450
1.00 0.190 ug/L 04/11/17 16:19 11,2-Dichlorobenzene <0.190
1.00 0.170 ug/L 04/11/17 16:19 11,4-Dichlorobenzene <0.170
1.00 0.240 ug/L 04/11/17 16:19 11,1-Dichloroethane <0.240
1.00 0.200 ug/L 04/11/17 16:19 11,2-Dichloroethane <0.200
1.00 0.250 ug/L 04/11/17 16:19 11,1-Dichloroethene <0.250
1.00 0.250 ug/L 04/11/17 16:19 11,2-Dichloropropane <0.250
1.00 0.190 ug/L 04/11/17 16:19 1Ethylbenzene<0.190
10.0 1.28 ug/L 04/11/17 16:19 12-Hexanone <1.28
10.0 1.50 ug/L 04/11/17 16:19 1Iodomethane<1.50
5.00 1.00 ug/L 04/11/17 16:19 1Methylene Chloride <1.00
10.0 0.810 ug/L 04/11/17 16:19 14-Methyl-2-pentanone (MIBK)<0.810
1.00 0.280 ug/L 04/11/17 16:19 1Styrene<0.280
1.00 0.150 ug/L 04/11/17 16:19 11,1,1,2-Tetrachloroethane <0.150
1.00 0.190 ug/L 04/11/17 16:19 11,1,2,2-Tetrachloroethane <0.190
1.00 0.140 ug/L 04/11/17 16:19 1Tetrachloroethene<0.140
10.0 0.820 ug/L 04/11/17 16:19 1Tetrahydrofuran<0.820
1.00 0.170 ug/L 04/11/17 16:19 1Toluene<0.170
5.00 0.460 ug/L 04/11/17 16:19 1trans-1,4-Dichloro-2-butene <0.460
1.00 0.230 ug/L 04/11/17 16:19 1trans-1,2-Dichloroethene <0.230
1.00 0.170 ug/L 04/11/17 16:19 1trans-1,3-Dichloropropene <0.170
1.00 0.190 ug/L 04/11/17 16:19 11,1,1-Trichloroethane <0.190
1.00 0.190 ug/L 04/11/17 16:19 11,1,2-Trichloroethane <0.190
1.00 0.200 ug/L 04/11/17 16:19 1Trichloroethene<0.200
1.00 0.210 ug/L 04/11/17 16:19 1Trichlorofluoromethane<0.210
1.00 0.230 ug/L 04/11/17 16:19 11,2,3-Trichloropropane <0.230
10.0 1.71 ug/L 04/11/17 16:19 1Vinyl acetate <1.71
1.00 0.180 ug/L 04/11/17 16:19 1Vinyl chloride <0.180
3.00 0.580 ug/L 04/11/17 16:19 1Xylenes, Total <0.580
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Client Sample Results
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Lab Sample ID: 490-125420-2Client Sample ID: Trip Blank
Matrix: WaterDate Collected: 04/03/17 00:01
Date Received: 04/04/17 09:35
4-Bromofluorobenzene (Surr)102 70-130 04/11/17 16:19 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)99 04/11/17 16:19 170-130
1,2-Dichloroethane-d4 (Surr)91 04/11/17 16:19 170-130
Toluene-d8 (Surr)98 04/11/17 16:19 170-130
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QC Sample Results
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Method: 8260B - Volatile Organic Compounds (GC/MS)
Client Sample ID: Method BlankLab Sample ID: MB 490-421333/7
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421333
RL MDL
Acetone <2.66 25.0 2.66 ug/L 04/11/17 12:58 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<0.500 0.50010.0 ug/L 04/11/17 12:58 1Acrylonitrile
<0.200 0.2001.00 ug/L 04/11/17 12:58 1Benzene
<0.150 0.1501.00 ug/L 04/11/17 12:58 1Bromochloromethane
<0.170 0.1701.00 ug/L 04/11/17 12:58 1Bromodichloromethane
<0.290 0.2901.00 ug/L 04/11/17 12:58 1Bromoform
<0.350 0.3501.00 ug/L 04/11/17 12:58 1Bromomethane
<2.64 2.6450.0 ug/L 04/11/17 12:58 12-Butanone (MEK)
<0.220 0.2201.00 ug/L 04/11/17 12:58 1Carbon disulfide
<0.180 0.1801.00 ug/L 04/11/17 12:58 1Carbon tetrachloride
<0.180 0.1801.00 ug/L 04/11/17 12:58 1Chlorobenzene
<0.360 0.3601.00 ug/L 04/11/17 12:58 1Chloroethane
<0.230 0.2301.00 ug/L 04/11/17 12:58 1Chloroform
<0.360 0.3601.00 ug/L 04/11/17 12:58 1Chloromethane
<0.210 0.2101.00 ug/L 04/11/17 12:58 1cis-1,2-Dichloroethene
<0.170 0.1701.00 ug/L 04/11/17 12:58 1cis-1,3-Dichloropropene
<0.250 0.2501.00 ug/L 04/11/17 12:58 1Dibromochloromethane
<0.940 0.94010.0 ug/L 04/11/17 12:58 11,2-Dibromo-3-Chloropropane
<0.210 0.2101.00 ug/L 04/11/17 12:58 11,2-Dibromoethane (EDB)
<0.450 0.4501.00 ug/L 04/11/17 12:58 1Dibromomethane
<0.190 0.1901.00 ug/L 04/11/17 12:58 11,2-Dichlorobenzene
<0.170 0.1701.00 ug/L 04/11/17 12:58 11,4-Dichlorobenzene
<0.240 0.2401.00 ug/L 04/11/17 12:58 11,1-Dichloroethane
<0.200 0.2001.00 ug/L 04/11/17 12:58 11,2-Dichloroethane
<0.250 0.2501.00 ug/L 04/11/17 12:58 11,1-Dichloroethene
<0.250 0.2501.00 ug/L 04/11/17 12:58 11,2-Dichloropropane
<0.190 0.1901.00 ug/L 04/11/17 12:58 1Ethylbenzene
<1.28 1.2810.0 ug/L 04/11/17 12:58 12-Hexanone
<1.50 1.5010.0 ug/L 04/11/17 12:58 1Iodomethane
<1.00 1.005.00 ug/L 04/11/17 12:58 1Methylene Chloride
<0.810 0.81010.0 ug/L 04/11/17 12:58 14-Methyl-2-pentanone (MIBK)
<0.280 0.2801.00 ug/L 04/11/17 12:58 1Styrene
<0.150 0.1501.00 ug/L 04/11/17 12:58 11,1,1,2-Tetrachloroethane
<0.190 0.1901.00 ug/L 04/11/17 12:58 11,1,2,2-Tetrachloroethane
<0.140 0.1401.00 ug/L 04/11/17 12:58 1Tetrachloroethene
<0.820 0.82010.0 ug/L 04/11/17 12:58 1Tetrahydrofuran
<0.170 0.1701.00 ug/L 04/11/17 12:58 1Toluene
<0.460 0.4605.00 ug/L 04/11/17 12:58 1trans-1,4-Dichloro-2-butene
<0.230 0.2301.00 ug/L 04/11/17 12:58 1trans-1,2-Dichloroethene
<0.170 0.1701.00 ug/L 04/11/17 12:58 1trans-1,3-Dichloropropene
<0.190 0.1901.00 ug/L 04/11/17 12:58 11,1,1-Trichloroethane
<0.190 0.1901.00 ug/L 04/11/17 12:58 11,1,2-Trichloroethane
<0.200 0.2001.00 ug/L 04/11/17 12:58 1Trichloroethene
<0.210 0.2101.00 ug/L 04/11/17 12:58 1Trichlorofluoromethane
<0.230 0.2301.00 ug/L 04/11/17 12:58 11,2,3-Trichloropropane
<1.71 1.7110.0 ug/L 04/11/17 12:58 1Vinyl acetate
<0.180 0.1801.00 ug/L 04/11/17 12:58 1Vinyl chloride
<0.580 0.5803.00 ug/L 04/11/17 12:58 1Xylenes, Total
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QC Sample Results
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
4-Bromofluorobenzene (Surr)103 70-130 04/11/17 12:58 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
102 04/11/17 12:58 1Dibromofluoromethane (Surr)70-130
90 04/11/17 12:58 11,2-Dichloroethane-d4 (Surr)70-130
97 04/11/17 12:58 1Toluene-d8 (Surr)70-130
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-421333/3
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421333
Acetone 100 63.54 ug/L 64 39-150
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Acrylonitrile 200 149.0 ug/L 75 63-135
Benzene 20.0 19.09 ug/L 95 70-130
Bromochloromethane 20.0 17.39 ug/L 87 70-130
Bromodichloromethane 20.0 17.25 ug/L 86 70-130
Bromoform 20.0 14.23 ug/L 71 70-137
Bromomethane 20.0 19.62 ug/L 98 53-150
2-Butanone (MEK)100 63.37 ug/L 63 55-143
Carbon disulfide 20.0 19.78 ug/L 99 64-135
Carbon tetrachloride 20.0 17.95 ug/L 90 70-147
Chlorobenzene 20.0 18.44 ug/L 92 70-130
Chloroethane 20.0 20.99 ug/L 105 60-138
Chloroform 20.0 18.45 ug/L 92 70-130
Chloromethane 20.0 19.99 ug/L 100 33-150
cis-1,2-Dichloroethene 20.0 18.17 ug/L 91 70-130
cis-1,3-Dichloropropene 20.0 17.43 ug/L 87 70-133
Dibromochloromethane 20.0 16.00 ug/L 80 70-133
1,2-Dibromo-3-Chloropropane 20.0 11.68 ug/L 58 45-138
1,2-Dibromoethane (EDB)20.0 16.72 ug/L 84 70-130
Dibromomethane 20.0 17.06 ug/L 85 70-130
1,2-Dichlorobenzene 20.0 18.23 ug/L 91 70-130
1,4-Dichlorobenzene 20.0 19.50 ug/L 98 70-130
1,1-Dichloroethane 20.0 18.31 ug/L 92 70-130
1,2-Dichloroethane 20.0 16.36 ug/L 82 70-130
1,1-Dichloroethene 20.0 17.30 ug/L 86 70-132
1,2-Dichloropropane 20.0 17.06 ug/L 85 70-130
Ethylbenzene 20.0 18.47 ug/L 92 70-130
2-Hexanone 100 65.00 ug/L 65 54-142
Iodomethane 20.0 19.70 ug/L 99 40-150
Methylene Chloride 20.0 18.34 ug/L 92 70-130
4-Methyl-2-pentanone (MIBK)100 65.07 ug/L 65 60-137
Styrene 20.0 18.58 ug/L 93 70-130
1,1,1,2-Tetrachloroethane 20.0 16.99 ug/L 85 70-130
1,1,2,2-Tetrachloroethane 20.0 14.96 ug/L 75 69-131
Tetrachloroethene 20.0 20.00 ug/L 100 70-130
Tetrahydrofuran 40.0 23.65 ug/L 59 51-136
Toluene 20.0 19.11 ug/L 96 70-130
trans-1,4-Dichloro-2-butene 20.0 14.43 ug/L 72 41-150
trans-1,2-Dichloroethene 20.0 18.66 ug/L 93 70-130
trans-1,3-Dichloropropene 20.0 16.24 ug/L 81 63-142
1,1,1-Trichloroethane 20.0 18.68 ug/L 93 70-135
1,1,2-Trichloroethane 20.0 17.49 ug/L 87 70-130
Trichloroethene 20.0 17.34 ug/L 87 70-130
Trichlorofluoromethane 20.0 17.72 ug/L 89 59-150
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QC Sample Results
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-421333/3
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421333
1,2,3-Trichloropropane 20.0 15.28 ug/L 76 70-131
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Vinyl acetate 40.0 47.48 ug/L 119 54-146
Vinyl chloride 20.0 16.80 ug/L 84 57-137
Xylenes, Total 40.0 36.31 ug/L 91 70-132
4-Bromofluorobenzene (Surr)70 -130
Surrogate
102
LCS LCS
Qualifier Limits%Recovery
100Dibromofluoromethane (Surr)70 -130
871,2-Dichloroethane-d4 (Surr)70 -130
99Toluene-d8 (Surr)70 -130
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-421333/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421333
Acetone 100 68.65 ug/L 69 39-150 8 23
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Acrylonitrile 200 130.4 ug/L 65 63-135 13 16
Benzene 20.0 18.17 ug/L 91 70-130 5 12
Bromochloromethane 20.0 16.11 ug/L 81 70-130 8 16
Bromodichloromethane 20.0 16.47 ug/L 82 70-130 5 14
Bromoform 20.0 13.47 *ug/L 67 70-137 5 14
Bromomethane 20.0 20.59 ug/L 103 53-150 5 19
2-Butanone (MEK)100 63.97 ug/L 64 55-143 1 19
Carbon disulfide 20.0 18.51 ug/L 93 64-135 7 16
Carbon tetrachloride 20.0 17.31 ug/L 87 70-147 4 16
Chlorobenzene 20.0 17.45 ug/L 87 70-130 5 12
Chloroethane 20.0 20.38 ug/L 102 60-138 3 15
Chloroform 20.0 17.91 ug/L 90 70-130 3 14
Chloromethane 20.0 19.34 ug/L 97 33-150 3 20
cis-1,2-Dichloroethene 20.0 17.62 ug/L 88 70-130 3 15
cis-1,3-Dichloropropene 20.0 16.37 ug/L 82 70-133 6 15
Dibromochloromethane 20.0 15.17 ug/L 76 70-133 5 13
1,2-Dibromo-3-Chloropropane 20.0 12.17 ug/L 61 45-138 4 19
1,2-Dibromoethane (EDB)20.0 16.47 ug/L 82 70-130 2 13
Dibromomethane 20.0 15.78 ug/L 79 70-130 8 14
1,2-Dichlorobenzene 20.0 17.19 ug/L 86 70-130 6 12
1,4-Dichlorobenzene 20.0 18.24 ug/L 91 70-130 7 12
1,1-Dichloroethane 20.0 17.60 ug/L 88 70-130 4 17
1,2-Dichloroethane 20.0 16.12 ug/L 81 70-130 1 13
1,1-Dichloroethene 20.0 16.81 ug/L 84 70-132 3 20
1,2-Dichloropropane 20.0 16.81 ug/L 84 70-130 1 15
Ethylbenzene 20.0 17.54 ug/L 88 70-130 5 12
2-Hexanone 100 62.73 ug/L 63 54-142 4 17
Iodomethane 20.0 20.94 ug/L 105 40-150 6 20
Methylene Chloride 20.0 17.19 ug/L 86 70-130 6 15
4-Methyl-2-pentanone (MIBK)100 61.28 ug/L 61 60-137 6 21
Styrene 20.0 17.45 ug/L 87 70-130 6 12
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QC Sample Results
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-421333/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421333
1,1,1,2-Tetrachloroethane 20.0 16.09 ug/L 80 70-130 5 13
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
1,1,2,2-Tetrachloroethane 20.0 14.21 ug/L 71 69-131 5 15
Tetrachloroethene 20.0 18.69 ug/L 93 70-130 7 17
Tetrahydrofuran 40.0 23.62 ug/L 59 51-136 0 20
Toluene 20.0 17.55 ug/L 88 70-130 9 13
trans-1,4-Dichloro-2-butene 20.0 14.58 ug/L 73 41-150 1 20
trans-1,2-Dichloroethene 20.0 17.85 ug/L 89 70-130 4 15
trans-1,3-Dichloropropene 20.0 14.82 ug/L 74 63-142 9 13
1,1,1-Trichloroethane 20.0 17.81 ug/L 89 70-135 5 15
1,1,2-Trichloroethane 20.0 16.23 ug/L 81 70-130 7 13
Trichloroethene 20.0 16.48 ug/L 82 70-130 5 14
Trichlorofluoromethane 20.0 17.42 ug/L 87 59-150 2 22
1,2,3-Trichloropropane 20.0 14.27 ug/L 71 70-131 7 14
Vinyl acetate 40.0 43.68 ug/L 109 54-146 8 20
Vinyl chloride 20.0 17.03 ug/L 85 57-137 1 15
Xylenes, Total 40.0 34.29 ug/L 86 70-132 6 11
4-Bromofluorobenzene (Surr)70 -130
Surrogate
102
LCSD LCSD
Qualifier Limits%Recovery
100Dibromofluoromethane (Surr)70 -130
911,2-Dichloroethane-d4 (Surr)70 -130
99Toluene-d8 (Surr)70 -130
Client Sample ID: Matrix SpikeLab Sample ID: 490-126006-B-1 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421333
Acetone <2.66 100 71.39 ug/L 71 39-150
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Acrylonitrile <0.500 200 160.0 ug/L 80 50-135
Benzene <0.200 20.0 22.04 ug/L 110 55-147
Bromochloromethane <0.150 20.0 17.90 ug/L 90 59-132
Bromodichloromethane <0.170 20.0 20.62 ug/L 103 70-140
Bromoform <0.290 20.0 15.81 ug/L 79 53-150
Bromomethane <0.350 20.0 18.51 ug/L 93 30-150
2-Butanone (MEK)<2.64 100 70.40 ug/L 70 50-143
Carbon disulfide <0.220 20.0 21.29 ug/L 106 35-150
Carbon tetrachloride <0.180 20.0 21.50 ug/L 108 56-150
Chlorobenzene <0.180 20.0 20.78 ug/L 104 70-130
Chloroethane <0.360 20.0 21.60 ug/L 108 58-141
Chloroform <0.230 20.0 21.50 ug/L 107 66-138
Chloromethane <0.360 20.0 22.30 ug/L 111 10-150
cis-1,2-Dichloroethene <0.210 20.0 21.21 ug/L 106 68-131
cis-1,3-Dichloropropene <0.170 20.0 19.23 ug/L 96 70-133
Dibromochloromethane <0.250 20.0 17.61 ug/L 88 66-140
1,2-Dibromo-3-Chloropropane <0.940 20.0 13.08 ug/L 65 38-138
1,2-Dibromoethane (EDB)<0.210 20.0 18.51 ug/L 93 65-137
Dibromomethane <0.450 20.0 18.87 ug/L 94 70-130
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QC Sample Results
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Matrix SpikeLab Sample ID: 490-126006-B-1 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421333
1,2-Dichlorobenzene <0.190 20.0 20.52 ug/L 103 70-130
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
1,4-Dichlorobenzene <0.170 20.0 21.43 ug/L 107 70-130
1,1-Dichloroethane <0.240 20.0 21.81 ug/L 109 61-139
1,2-Dichloroethane <0.200 20.0 19.39 ug/L 97 64-136
1,1-Dichloroethene <0.250 20.0 20.35 ug/L 102 54-150
1,2-Dichloropropane <0.250 20.0 19.88 ug/L 99 67-130
Ethylbenzene <0.190 20.0 20.52 ug/L 103 65-139
2-Hexanone <1.28 100 73.00 ug/L 73 44-150
Iodomethane <1.50 20.0 18.46 ug/L 92 34-150
Methylene Chloride <1.00 20.0 18.12 ug/L 91 64-130
4-Methyl-2-pentanone (MIBK)<0.810 100 72.34 ug/L 72 50-140
Styrene <0.280 20.0 20.21 ug/L 101 70-130
1,1,1,2-Tetrachloroethane <0.150 20.0 19.28 ug/L 96 70-131
1,1,2,2-Tetrachloroethane <0.190 20.0 17.33 ug/L 87 56-145
Tetrachloroethene <0.140 20.0 22.29 ug/L 111 57-138
Tetrahydrofuran <0.820 40.0 29.11 ug/L 73 40-136
Toluene <0.170 20.0 21.38 ug/L 107 64-136
trans-1,4-Dichloro-2-butene <0.460 20.0 16.38 ug/L 82 39-150
trans-1,2-Dichloroethene <0.230 20.0 21.65 ug/L 108 59-143
trans-1,3-Dichloropropene <0.170 20.0 17.73 ug/L 89 63-142
1,1,1-Trichloroethane <0.190 20.0 22.25 ug/L 111 68-144
1,1,2-Trichloroethane <0.190 20.0 18.89 ug/L 94 70-130
Trichloroethene <0.200 20.0 20.45 ug/L 102 63-135
Trichlorofluoromethane <0.210 20.0 22.25 ug/L 111 44-150
1,2,3-Trichloropropane <0.230 20.0 17.92 ug/L 90 65-131
Vinyl acetate <1.71 40.0 52.86 ug/L 132 43-146
Vinyl chloride <0.180 20.0 21.66 ug/L 108 57-150
Xylenes, Total <0.580 40.0 39.45 ug/L 99 69-132
4-Bromofluorobenzene (Surr)70 -130
Surrogate
101
MS MS
Qualifier Limits%Recovery
101Dibromofluoromethane (Surr)70 -130
911,2-Dichloroethane-d4 (Surr)70 -130
98Toluene-d8 (Surr)70 -130
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-126006-C-1 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421333
Acetone <2.66 100 71.23 ug/L 71 39-150 0 28
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Acrylonitrile <0.500 200 155.3 ug/L 78 50-135 3 23
Benzene <0.200 20.0 22.22 ug/L 111 55-147 1 22
Bromochloromethane <0.150 20.0 18.75 ug/L 94 59-132 5 21
Bromodichloromethane <0.170 20.0 20.10 ug/L 100 70-140 3 196
Bromoform <0.290 20.0 16.30 ug/L 82 53-150 3 20
Bromomethane <0.350 20.0 19.63 ug/L 98 30-150 6 44
2-Butanone (MEK)<2.64 100 78.96 ug/L 79 50-143 11 28
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QC Sample Results
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-126006-C-1 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421333
Carbon disulfide <0.220 20.0 21.79 ug/L 109 35-150 2 34
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Carbon tetrachloride <0.180 20.0 22.00 ug/L 110 56-150 2 18
Chlorobenzene <0.180 20.0 21.37 ug/L 107 70-130 3 15
Chloroethane <0.360 20.0 21.61 ug/L 108 58-141 0 31
Chloroform <0.230 20.0 22.18 ug/L 111 66-138 3 21
Chloromethane <0.360 20.0 22.58 ug/L 113 10-150 1 43
cis-1,2-Dichloroethene <0.210 20.0 21.64 ug/L 108 68-131 2 21
cis-1,3-Dichloropropene <0.170 20.0 19.73 ug/L 99 70-133 3 19
Dibromochloromethane <0.250 20.0 18.47 ug/L 92 66-140 5 19
1,2-Dibromo-3-Chloropropane <0.940 20.0 13.41 ug/L 67 38-138 2 26
1,2-Dibromoethane (EDB)<0.210 20.0 19.02 ug/L 95 65-137 3 21
Dibromomethane <0.450 20.0 19.18 ug/L 96 70-130 2 19
1,2-Dichlorobenzene <0.190 20.0 20.90 ug/L 105 70-130 2 15
1,4-Dichlorobenzene <0.170 20.0 22.45 ug/L 112 70-130 5 14
1,1-Dichloroethane <0.240 20.0 21.50 ug/L 108 61-139 1 23
1,2-Dichloroethane <0.200 20.0 20.11 ug/L 101 64-136 4 22
1,1-Dichloroethene <0.250 20.0 20.95 ug/L 105 54-150 3 24
1,2-Dichloropropane <0.250 20.0 19.93 ug/L 100 67-130 0 19
Ethylbenzene <0.190 20.0 21.40 ug/L 107 65-139 4 18
2-Hexanone <1.28 100 72.35 ug/L 72 44-150 1 21
Iodomethane <1.50 20.0 20.47 ug/L 102 34-150 10 37
Methylene Chloride <1.00 20.0 21.46 ug/L 107 64-130 17 22
4-Methyl-2-pentanone (MIBK)<0.810 100 75.62 ug/L 76 50-140 4 24
Styrene <0.280 20.0 20.32 ug/L 102 70-130 1 16
1,1,1,2-Tetrachloroethane <0.150 20.0 20.50 ug/L 102 70-131 6 16
1,1,2,2-Tetrachloroethane <0.190 20.0 17.07 ug/L 85 56-145 2 19
Tetrachloroethene <0.140 20.0 22.99 ug/L 115 57-138 3 17
Tetrahydrofuran <0.820 40.0 25.43 ug/L 64 40-136 14 27
Toluene <0.170 20.0 22.17 ug/L 111 64-136 4 18
trans-1,4-Dichloro-2-butene <0.460 20.0 15.68 ug/L 78 39-150 4 28
trans-1,2-Dichloroethene <0.230 20.0 21.72 ug/L 109 59-143 0 25
trans-1,3-Dichloropropene <0.170 20.0 18.45 ug/L 92 63-142 4 18
1,1,1-Trichloroethane <0.190 20.0 22.64 ug/L 113 68-144 2 17
1,1,2-Trichloroethane <0.190 20.0 19.82 ug/L 99 70-130 5 18
Trichloroethene <0.200 20.0 20.60 ug/L 103 63-135 1 17
Trichlorofluoromethane <0.210 20.0 22.25 ug/L 111 44-150 0 32
1,2,3-Trichloropropane <0.230 20.0 17.54 ug/L 88 65-131 2 19
Vinyl acetate <1.71 40.0 53.05 ug/L 133 43-146 0 20
Vinyl chloride <0.180 20.0 21.83 ug/L 109 57-150 1 37
Xylenes, Total <0.580 40.0 39.95 ug/L 100 69-132 1 17
4-Bromofluorobenzene (Surr)70 -130
Surrogate
100
MSD MSD
Qualifier Limits%Recovery
100Dibromofluoromethane (Surr)70 -130
901,2-Dichloroethane-d4 (Surr)70 -130
100Toluene-d8 (Surr)70 -130
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QC Sample Results
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Method: 300.0 - Anions, Ion Chromatography
Client Sample ID: Method BlankLab Sample ID: MB 490-422494/3
Matrix: Water Prep Type: Total/NA
Analysis Batch: 422494
RL MDL
Sulfate <0.600 1.00 0.600 mg/L 04/15/17 03:01 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-422494/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 422494
Sulfate 10.0 9.124 mg/L 91 90-110
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-422494/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 422494
Sulfate 10.0 9.215 mg/L 92 90-110 1 20
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Method: 6010D - Metals (ICP)
Client Sample ID: Method BlankLab Sample ID: MB 490-422168/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 422953 Prep Batch: 422168
RL MDL
Arsenic <0.00860 0.0100 0.00860 mg/L 04/13/17 20:11 04/17/17 18:13 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<0.00500 0.005000.0100 mg/L 04/13/17 20:11 04/17/17 18:13 1Barium
<0.000500 0.0005000.00100 mg/L 04/13/17 20:11 04/17/17 18:13 1Cadmium
<0.00300 0.003000.00500 mg/L 04/13/17 20:11 04/17/17 18:13 1Chromium
<0.00500 0.005000.0100 mg/L 04/13/17 20:11 04/17/17 18:13 1Copper
<0.00200 0.002000.00500 mg/L 04/13/17 20:11 04/17/17 18:13 1Lead
<0.00300 0.003000.0100 mg/L 04/13/17 20:11 04/17/17 18:13 1Nickel
<0.00500 0.005000.0100 mg/L 04/13/17 20:11 04/17/17 18:13 1Selenium
<0.00300 0.003000.00500 mg/L 04/13/17 20:11 04/17/17 18:13 1Silver
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-422168/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 422953 Prep Batch: 422168
Arsenic 0.100 0.09220 mg/L 92 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Barium 0.100 0.09590 mg/L 96 80-120
Cadmium 0.100 0.09430 mg/L 94 80-120
Chromium 0.100 0.09460 mg/L 95 80-120
Copper 0.100 0.09680 mg/L 97 80-120
Lead 0.100 0.09670 mg/L 97 80-120
Nickel 0.100 0.09590 mg/L 96 80-120
Selenium 0.100 0.09290 mg/L 93 80-120
Silver 0.100 0.08810 mg/L 88 80-120
TestAmerica Nashville
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QC Sample Results
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Method: 6010D - Metals (ICP) (Continued)
Client Sample ID: Matrix SpikeLab Sample ID: 490-125976-A-1-H MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 422953 Prep Batch: 422168
Arsenic <0.00860 0.100 0.1065 mg/L 107 75-125
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Barium 0.00530 J 0.100 0.1029 mg/L 98 75-125
Cadmium <0.000500 0.100 0.09000 mg/L 90 75-125
Chromium <0.00300 0.100 0.09200 mg/L 92 75-125
Copper <0.00500 0.100 0.1029 mg/L 103 75-125
Lead <0.00200 0.100 0.09180 mg/L 92 75-125
Nickel <0.00300 0.100 0.08320 mg/L 83 75-125
Selenium <0.00500 0.100 0.1086 mg/L 109 75-125
Silver <0.00300 0.100 0.09710 mg/L 97 75-125
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-125976-A-1-I MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 422953 Prep Batch: 422168
Arsenic <0.00860 0.100 0.1037 mg/L 104 75-125 3 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Barium 0.00530 J 0.100 0.1039 mg/L 99 75-125 1 20
Cadmium <0.000500 0.100 0.09100 mg/L 91 75-125 1 20
Chromium <0.00300 0.100 0.09300 mg/L 93 75-125 1 20
Copper <0.00500 0.100 0.1064 mg/L 106 75-125 3 20
Lead <0.00200 0.100 0.09320 mg/L 93 75-125 2 20
Nickel <0.00300 0.100 0.08510 mg/L 85 75-125 2 20
Selenium <0.00500 0.100 0.1089 mg/L 109 75-125 0 20
Silver <0.00300 0.100 0.09590 mg/L 96 75-125 1 20
Method: 6020B - Metals (ICP/MS)
Client Sample ID: Method BlankLab Sample ID: MB 490-422158/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 424002 Prep Batch: 422158
RL MDL
Antimony <0.800 2.00 0.800 ug/L 04/13/17 19:58 04/21/17 00:41 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<0.100 0.1002.00 ug/L 04/13/17 19:58 04/21/17 00:41 1Cobalt
<0.800 0.8002.00 ug/L 04/13/17 19:58 04/21/17 00:41 1Thallium
<0.700 0.7002.00 ug/L 04/13/17 19:58 04/21/17 00:41 1Vanadium
Client Sample ID: Method BlankLab Sample ID: MB 490-422158/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 424251 Prep Batch: 422158
RL MDL
Beryllium <0.100 2.00 0.100 ug/L 04/13/17 19:58 04/21/17 17:30 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
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QC Sample Results
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Method: 6020B - Metals (ICP/MS) (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-422158/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 424002 Prep Batch: 422158
Antimony 100 92.22 ug/L 92 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Cobalt 100 88.46 ug/L 88 80-120
Thallium 100 91.27 ug/L 91 80-120
Vanadium 100 105.1 ug/L 105 80-120
Zinc 100 91.78 ug/L 92 80-120
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-422158/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 424251 Prep Batch: 422158
Beryllium 100 97.26 ug/L 97 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: Matrix SpikeLab Sample ID: 490-125760-B-7-A MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 424002 Prep Batch: 422158
Antimony <0.800 100 99.00 ug/L 99 75-125
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Cobalt 0.678 J 100 95.48 ug/L 95 75-125
Thallium <0.800 100 97.76 ug/L 98 75-125
Vanadium 1.47 J 100 109.3 ug/L 108 75-125
Client Sample ID: Matrix SpikeLab Sample ID: 490-125760-B-7-A MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 424251 Prep Batch: 422158
Beryllium <0.100 100 94.57 ug/L 95 75-125
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-125760-B-7-B MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 424002 Prep Batch: 422158
Antimony <0.800 100 94.82 ug/L 95 75-125 4 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Cobalt 0.678 J 100 92.60 ug/L 92 75-125 3 20
Thallium <0.800 100 94.52 ug/L 95 75-125 3 20
Vanadium 1.47 J 100 106.7 ug/L 105 75-125 2 20
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-125760-B-7-B MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 424251 Prep Batch: 422158
Beryllium <0.100 100 94.56 ug/L 95 75-125 0 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
TestAmerica Nashville
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QC Sample Results
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Method: 6020B - Metals (ICP/MS) (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 490-424420/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 425465 Prep Batch: 424420
RL MDL
Zinc <5.20 25.0 5.20 ug/L 04/23/17 17:17 04/27/17 03:14 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-424420/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 425465 Prep Batch: 424420
Zinc 100 89.85 ug/L 90 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: Matrix SpikeLab Sample ID: 490-126387-A-1-B MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 425465 Prep Batch: 424420
Zinc <26.0 F1 100 135.4 F1 ug/L 135 75-125
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-126387-A-1-C MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 425465 Prep Batch: 424420
Zinc <26.0 F1 100 148.0 F1 ug/L 148 75-125 9 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Method: 7470A - Mercury (CVAA)
Client Sample ID: Method BlankLab Sample ID: MB 490-421267/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421541 Prep Batch: 421267
RL MDL
Mercury 0.1064 J 0.200 0.100 ug/L 04/11/17 09:07 04/11/17 15:44 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-421267/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421541 Prep Batch: 421267
Mercury 1.00 1.193 ug/L 119 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-421267/3-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421541 Prep Batch: 421267
Mercury 1.00 1.060 ug/L 106 80-120 12 20
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
TestAmerica Nashville
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QC Sample Results
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Method: 7470A - Mercury (CVAA) (Continued)
Client Sample ID: LT-01Lab Sample ID: 490-125420-1 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421541 Prep Batch: 421267
Mercury <0.100 1.00 1.056 ug/L 106 75-125
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Client Sample ID: LT-01Lab Sample ID: 490-125420-1 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421541 Prep Batch: 421267
Mercury <0.100 1.00 1.196 ug/L 120 75-125 12 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Method: 365.4 - Phosphorus, Total
Client Sample ID: Method BlankLab Sample ID: MB 490-419885/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 420104 Prep Batch: 419885
RL MDL
Phosphorus, Total <0.0500 0.100 0.0500 mg/L 04/05/17 10:22 04/05/17 19:49 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-419885/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 420104 Prep Batch: 419885
Phosphorus, Total 2.00 2.040 mg/L 102 90-110
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: Matrix SpikeLab Sample ID: 490-125553-E-1-E MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 420104 Prep Batch: 419885
Phosphorus, Total <0.0500 2.00 2.000 mg/L 100 73-119
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-125553-E-1-F MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 420104 Prep Batch: 419885
Phosphorus, Total <0.0500 2.00 1.830 mg/L 92 73-119 9 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Method: SM 5220D - COD
Client Sample ID: Method BlankLab Sample ID: MB 490-421977/3
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421977
RL MDL
Chemical Oxygen Demand <4.00 20.0 4.00 mg/L 04/13/17 10:44 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
TestAmerica Nashville
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QC Sample Results
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Method: SM 5220D - COD (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-421977/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421977
Chemical Oxygen Demand 50.0 49.22 mg/L 98 95-105
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-421977/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421977
Chemical Oxygen Demand 50.0 48.92 mg/L 98 95-105 1 20
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Client Sample ID: Matrix SpikeLab Sample ID: 490-125612-C-1 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421977
Chemical Oxygen Demand 12.0 J F1 50.0 58.33 F1 mg/L 93 95-105
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 490-125612-C-1 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421977
Chemical Oxygen Demand 12.0 J F1 50.0 54.71 F1 mg/L 86 95-105 6 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Client Sample ID: DuplicateLab Sample ID: 490-125845-C-3 DU ^2
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421977
Chemical Oxygen Demand 262 263.7 mg/L 0.7 20
Analyte
DU DU
DUnitResultQualifier
Sample
Result
Sample
Qualifier LimitRPD
RPD
Method: SM5210B - BOD, 5 Day
Client Sample ID: Lab Control SampleLab Sample ID: LCS 490-421409/2
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421409
Biochemical Oxygen Demand 3.96 4.145 mg/L 105 85-115
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 490-421409/3
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421409
Biochemical Oxygen Demand 3.96 3.945 mg/L 100 85-115 5 20
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
TestAmerica Nashville
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QC Sample Results
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Method: SM5210B - BOD, 5 Day (Continued)
Client Sample ID: DuplicateLab Sample ID: 490-125412-H-1 DU
Matrix: Water Prep Type: Total/NA
Analysis Batch: 421409
Biochemical Oxygen Demand 2.90 3.534 mg/L 20 20
Analyte
DU DU
DUnitResultQualifier
Sample
Result
Sample
Qualifier LimitRPD
RPD
TestAmerica Nashville
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QC Association Summary
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
GC/MS VOA
Analysis Batch: 421333
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 8260B490-125420-1 LT-01 Total/NA
Water 8260B490-125420-2 Trip Blank Total/NA
Water 8260BMB 490-421333/7 Method Blank Total/NA
Water 8260BLCS 490-421333/3 Lab Control Sample Total/NA
Water 8260BLCSD 490-421333/4 Lab Control Sample Dup Total/NA
Water 8260B490-126006-B-1 MS Matrix Spike Total/NA
Water 8260B490-126006-C-1 MSD Matrix Spike Duplicate Total/NA
HPLC/IC
Analysis Batch: 422494
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 300.0490-125420-1 LT-01 Total/NA
Water 300.0MB 490-422494/3 Method Blank Total/NA
Water 300.0LCS 490-422494/4 Lab Control Sample Total/NA
Water 300.0LCSD 490-422494/5 Lab Control Sample Dup Total/NA
Metals
Prep Batch: 421267
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A490-125420-1 LT-01 Total/NA
Water 7470AMB 490-421267/1-A Method Blank Total/NA
Water 7470ALCS 490-421267/2-A Lab Control Sample Total/NA
Water 7470ALCSD 490-421267/3-A Lab Control Sample Dup Total/NA
Water 7470A490-125420-1 MS LT-01 Total/NA
Water 7470A490-125420-1 MSD LT-01 Total/NA
Analysis Batch: 421541
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A 421267490-125420-1 LT-01 Total/NA
Water 7470A 421267MB 490-421267/1-A Method Blank Total/NA
Water 7470A 421267LCS 490-421267/2-A Lab Control Sample Total/NA
Water 7470A 421267LCSD 490-421267/3-A Lab Control Sample Dup Total/NA
Water 7470A 421267490-125420-1 MS LT-01 Total/NA
Water 7470A 421267490-125420-1 MSD LT-01 Total/NA
Prep Batch: 422158
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3010A490-125420-1 LT-01 Total/NA
Water 3010AMB 490-422158/1-A Method Blank Total/NA
Water 3010ALCS 490-422158/2-A Lab Control Sample Total/NA
Water 3010A490-125760-B-7-A MS Matrix Spike Total/NA
Water 3010A490-125760-B-7-B MSD Matrix Spike Duplicate Total/NA
Prep Batch: 422168
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3010A490-125420-1 LT-01 Total/NA
Water 3010AMB 490-422168/1-A Method Blank Total/NA
Water 3010ALCS 490-422168/2-A Lab Control Sample Total/NA
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QC Association Summary
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Metals (Continued)
Prep Batch: 422168 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3010A490-125976-A-1-H MS Matrix Spike Total/NA
Water 3010A490-125976-A-1-I MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 422953
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6010D 422168490-125420-1 LT-01 Total/NA
Water 6010D 422168MB 490-422168/1-A Method Blank Total/NA
Water 6010D 422168LCS 490-422168/2-A Lab Control Sample Total/NA
Water 6010D 422168490-125976-A-1-H MS Matrix Spike Total/NA
Water 6010D 422168490-125976-A-1-I MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 424002
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020B 422158490-125420-1 LT-01 Total/NA
Water 6020B 422158MB 490-422158/1-A Method Blank Total/NA
Water 6020B 422158LCS 490-422158/2-A Lab Control Sample Total/NA
Water 6020B 422158490-125760-B-7-A MS Matrix Spike Total/NA
Water 6020B 422158490-125760-B-7-B MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 424251
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020B 422158490-125420-1 LT-01 Total/NA
Water 6020B 422158MB 490-422158/1-A Method Blank Total/NA
Water 6020B 422158LCS 490-422158/2-A Lab Control Sample Total/NA
Water 6020B 422158490-125760-B-7-A MS Matrix Spike Total/NA
Water 6020B 422158490-125760-B-7-B MSD Matrix Spike Duplicate Total/NA
Prep Batch: 424420
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3010A490-125420-1 LT-01 Total/NA
Water 3010AMB 490-424420/1-A Method Blank Total/NA
Water 3010ALCS 490-424420/2-A Lab Control Sample Total/NA
Water 3010A490-126387-A-1-B MS Matrix Spike Total/NA
Water 3010A490-126387-A-1-C MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 425465
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020B 424420490-125420-1 LT-01 Total/NA
Water 6020B 424420MB 490-424420/1-A Method Blank Total/NA
Water 6020B 424420LCS 490-424420/2-A Lab Control Sample Total/NA
Water 6020B 424420490-126387-A-1-B MS Matrix Spike Total/NA
Water 6020B 424420490-126387-A-1-C MSD Matrix Spike Duplicate Total/NA
General Chemistry
Prep Batch: 419885
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 365.2/365.3/365490-125420-1 LT-01 Total/NA
Water 365.2/365.3/365MB 490-419885/1-A Method Blank Total/NA
Water 365.2/365.3/365LCS 490-419885/2-A Lab Control Sample Total/NA
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QC Association Summary
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
General Chemistry (Continued)
Prep Batch: 419885 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 365.2/365.3/365490-125553-E-1-E MS Matrix Spike Total/NA
Water 365.2/365.3/365490-125553-E-1-F MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 420104
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 365.4 419885490-125420-1 LT-01 Total/NA
Water 365.4 419885MB 490-419885/1-A Method Blank Total/NA
Water 365.4 419885LCS 490-419885/2-A Lab Control Sample Total/NA
Water 365.4 419885490-125553-E-1-E MS Matrix Spike Total/NA
Water 365.4 419885490-125553-E-1-F MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 421409
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water SM5210B490-125420-1 LT-01 Total/NA
Water SM5210BLCS 490-421409/2 Lab Control Sample Total/NA
Water SM5210BLCSD 490-421409/3 Lab Control Sample Dup Total/NA
Water SM5210B490-125412-H-1 DU Duplicate Total/NA
Analysis Batch: 421955
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water Nitrate by calc490-125420-1 LT-01 Total/NA
Analysis Batch: 421977
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water SM 5220D490-125420-1 LT-01 Total/NA
Water SM 5220DMB 490-421977/3 Method Blank Total/NA
Water SM 5220DLCS 490-421977/4 Lab Control Sample Total/NA
Water SM 5220DLCSD 490-421977/5 Lab Control Sample Dup Total/NA
Water SM 5220D490-125612-C-1 MS Matrix Spike Total/NA
Water SM 5220D490-125612-C-1 MSD Matrix Spike Duplicate Total/NA
Water SM 5220D490-125845-C-3 DU ^2 Duplicate Total/NA
TestAmerica Nashville
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Lab Chronicle
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-125420-1
Project/Site: Madison co Operation Landfill Leachate
Client Sample ID: LT-01 Lab Sample ID: 490-125420-1
Matrix: WaterDate Collected: 04/03/17 12:10
Date Received: 04/04/17 09:35
Analysis 8260B RP04/11/17 16:441 TAL NSH421333
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Analysis 300.0 20 422494 04/15/17 08:58 JHS TAL NSHTotal/NA
Prep 3010A 422168 04/13/17 20:11 RDF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6010D 1 422953 04/17/17 19:53 BLG TAL NSHTotal/NA
Prep 3010A 422158 04/13/17 19:58 RDF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 424002 04/21/17 02:08 BLG TAL NSHTotal/NA
Prep 3010A 422158 04/13/17 19:58 RDF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 424251 04/21/17 18:08 BLG TAL NSHTotal/NA
Prep 3010A 424420 04/23/17 17:17 JSF TAL NSHTotal/NA 50 mL 50 mL
Analysis 6020B 1 425465 04/27/17 03:52 BLG TAL NSHTotal/NA
Prep 7470A 421267 04/11/17 09:07 CAH TAL NSHTotal/NA 30 mL 30 mL
Analysis 7470A 1 421541 04/11/17 15:52 CAH TAL NSHTotal/NA
Prep 365.2/365.3/365 419885 04/05/17 10:22 LDT TAL NSHTotal/NA 20 mL 20 mL
Analysis 365.4 1 420104 04/05/17 19:54 SDL TAL NSHTotal/NA 20 mL 20 mL
Analysis Nitrate by calc 1 421955 04/05/17 09:39 BMC TAL NSHTotal/NA 50 mL 50 mL
Analysis SM 5220D 1 421977 04/13/17 10:44 MSJ TAL NSHTotal/NA 2 mL 2 mL
Analysis SM5210B 1 421409 REM TAL NSHTotal/NA
04/04/17 20:26
04/09/17 14:30
(Start)
(End)
Client Sample ID: Trip Blank Lab Sample ID: 490-125420-2
Matrix: WaterDate Collected: 04/03/17 00:01
Date Received: 04/04/17 09:35
Analysis 8260B RP04/11/17 16:191 TAL NSH421333
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 10 mL 10 mL
Laboratory References:
TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL [phone]
TestAmerica Nashville
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Method Summary
TestAmerica Job ID: 490-125420-1Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison co Operation Landfill Leachate
Method Method Description LaboratoryProtocol
SW8468260BVolatile Organic Compounds (GC/MS)TAL NSH
MCAWW300.0 Anions, Ion Chromatography TAL NSH
SW8466010DMetals (ICP)TAL NSH
SW8466020BMetals (ICP/MS)TAL NSH
SW8467470AMercury (CVAA)TAL NSH
EPA365.4 Phosphorus, Total TAL NSH
SMNitrate by calc Nitrogen, Nitrate-Nitrite TAL NSH
SMSM 5220D COD TAL NSH
SMSM5210BBOD, 5 Day TAL NSH
Protocol References:
EPA = US Environmental Protection Agency
MCAWW = "Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And Subsequent Revisions.
SM = "Standard Methods For The Examination Of Water And Wastewater",
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL [phone]
TestAmerica Nashville
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Accreditation/Certification Summary
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-125420-1
Project/Site: Madison co Operation Landfill Leachate
Laboratory: TestAmerica Nashville
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.
Authority Program EPA Region Identification Number Expiration Date
North Carolina (WW/SW)3874State Program 12-31-17
Analysis Method Prep Method Matrix Analyte
The following analytes are included in this report, but accreditation/certification is not offered by the governing authority:
Nitrate by calc Water Nitrate as N
TestAmerica Nashville
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Login Sample Receipt Checklist
Client: Anchor QEA of North Carolina PLLC Job Number: 490-125420-1
SDG Number:
Login Number: 125420
Question Answer Comment
Creator: West, Derrick D
List Source: TestAmerica Nashville
List Number: 1
TrueRadioactivity wasn't checked or is </= background as measured by a survey
meter.
TrueThe cooler's custody seal, if present, is intact.
N/ASample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
TrueSample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
TrueContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
TrueResidual Chlorine Checked.
TestAmerica Nashville
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