Loading...
HomeMy WebLinkAbout6019_MecklenburgCoFoxholeMSWLF_GWMR_20170808May 2017 Semi-Annual Monitoring Report Foxhole Landfill - Permit # 60-19 Charlotte, North Carolina S&ME Project No. 1356-07-003 Prepared for: Mecklenburg County LUESA 700 North Tryon Street Charlotte, North Carolina 28202 Prepared by: S&ME, Inc. 9751 Southern Pine Boulevard Charlotte, NC 28273 August 9, 2017 S&ME, Inc. | 9751 Southern Pine Boulevard | Charlotte, NC 28273 | p 704.523.4726 | f 704.525.3953 | www.smeinc.com August 9, 2017 Mecklenburg County LUESA 700 North Tryon Street Charlotte, North Carolina 28202 Attention: Amber Grzymski Reference: May 2017 Semi-Annual Monitoring Report Foxhole Landfill - Permit # 60-19 Charlotte, North Carolina S&ME Project No. 1356-07-003 Dear Ms. Grzymski: S&ME Inc. (S&ME) has completed the May 2017 Semi-Annual Monitoring and Reporting for Mecklenburg County’s Foxhole Landfill. This report presents the results of the second monitoring event of the year for the facility. S&ME appreciates the continued opportunity to provide services to you and Mecklenburg County. If you have any questions or need additional information regarding this report, please contact Ed Henriques at (336) 553-1209. Sincerely, S&ME, Inc. Jasmine Tayouga, E.I. Julie P. Robertson, P.G. Staff Professional Project Manager/Senior Geologist cc: Jaclynne Drummond, NCDENR – Solid Waste Section May 2017 Semi-Annual Monitoring Report Foxhole Landfill - Permit # 60-19 Charlotte, North Carolina S&ME Project No. 1356-07-003 August 9, 2017 ii Table of Contents 1.0 Introduction ............................................................................................................ 1 2.0 Groundwater Levels and Flow............................................................................ 1 3.0 Analytical Data ...................................................................................................... 1 3.1 Monitoring Well Sampling .............................................................................................. 2 3.1.1 Volatile Organic Compounds .............................................................................................. 2 3.1.2 Total Metals......................................................................................................................... 2 3.1.3 Dissolved Metals ................................................................................................................. 2 3.2 Surface Water Sampling .................................................................................................. 3 3.2.1 Volatile Organic Compounds .............................................................................................. 3 3.2.2 Metals .................................................................................................................................. 3 3.3 Lift-Station Leachate Sample .......................................................................................... 3 4.0 Statistical Analysis ................................................................................................ 4 Appendices Appendix I – Drawings Appendix II – Tables Appendix III – Well Sampling Logs and Laboratory Reports Appendix IV – Statistical Analysis Procedure Sheets Appendix V - Lift Station Laboratory Report May 2017 Semi-Annual Monitoring Report Foxhole Landfill - Permit # 60-19 Charlotte, North Carolina S&ME Project No. 1356-07-003 August 9, 2017 1 1.0 Introduction S&ME, Inc. (S&ME) was contracted by Mecklenburg County to provide groundwater and surface water monitoring services at the Highway 521 Landfill “Foxhole” located at 17131 Lancaster Highway in Charlotte, North Carolina. This monitoring event was conducted on May 9th and 10th, 2017. This report presents the results of the first monitoring event for the year 2017 at the facility, which included the sampling of one background groundwater monitoring well (MW-1R), nine compliance groundwater monitoring wells (MW-2R, MW-3, MW-7, MW-8, MW-10, MW-10A, MW-11, MW-11A, MW- 12, and MW-13), and two surface water locations (SW-1 and SW-2). Please note that five (5) compliance wells (MW-4, MW-5, MW-6, MW-6A and MW-9) were abandoned in 2011 and 2012 as part of the Phase 2 landfill expansion. The next monitoring event is scheduled for November 2017. 2.0 Groundwater Levels and Flow The water table elevations and our interpretation of the groundwater surface expressed as a potentiometric map along with groundwater flow direction are shown on Drawing 1 of 1 located in Appendix I – Drawings. Based upon the groundwater elevations in the vicinity of the landfill, groundwater in this area is projected to flow from west to east toward Six-Mile Creek. Groundwater levels obtained during the May 2017 monitoring event, as well as monitoring well construction data, are presented in Table 1 located in Appendix II – Tables. The hydraulic gradient (i) in the vicinity of each well was estimated by calculating the vertical difference between the groundwater elevation at each well and one or more nearby contour lines from Drawing 1 of 1 - Groundwater Surface Map. This value was then divided by the horizontal distance measured from the well to the selected groundwater elevation contour line. Groundwater velocity was calculated by multiplying the gradient (i) by the hydraulic conductivity (k) and dividing by the estimated effective porosity (ne) of the aquifer. Table 2 in Appendix II summarizes the groundwater flow rates for the monitoring wells. 3.0 Analytical Data Analytical results for the landfill monitoring wells are summarized in Table 4 in Appendix II. Groundwater detections at or above the 15A NCAC 2L .0202 Groundwater Standards (2L Standards) and/or Solid Waste Groundwater Protection Standards (SW GWP Standards) are highlighted in gray. Field measurements of pH, conductivity, turbidity, and temperature are summarized in Table 3 in Appendix II. Well sampling logs containing this information are included in Appendix III. Analytical results for the surface water sampling locations are summarized in Table 5 in Appendix II. Surface water detections at or above the 15A NCAC 2B Freshwater Standards (2B Standards) are highlighted in gray. The monitoring wells and surface water locations were sampled for Appendix I volatile organic compounds and metals. May 2017 Semi-Annual Monitoring Report Foxhole Landfill - Permit # 60-19 Charlotte, North Carolina S&ME Project No. 1356-07-003 August 9, 2017 2 3.1 Monitoring Well Sampling During May 2017, the compliance and background monitoring wells that are part of the routine semi- annual monitoring event were sampled. 3.1.1 Volatile Organic Compounds Chloroform was detected in compliance groundwater monitoring well MW-7 at a concentration below its respective 2L Standard of 70 µg/L. No other volatile organic compounds were detected in groundwater monitoring wells during the May 2017 sampling event. 3.1.2 Total Metals Two or more inorganic constituents (metals) were detected in each of the groundwater monitoring wells sampled. Concentrations of antimony, barium, beryllium, copper, lead, nickel, thallium, and zinc were detected at concentrations less than their respective 2L Standard and SW GWP Standard. Chromium was detected at concentrations of 14.4 µg/L and 15.8 µg/L in compliance monitoring wells MW-2R and MW-10A, respectively, these concentrations are greater than the 2L Standard of 10 µg/L. Cobalt was detected at above its respective SW GWP Standard of 1 µg/L in compliance groundwater monitoring well MW-2R at a concentration of 4.62 J µg/L. It is important to point out that cobalt was also detected in background well MW-1R at a concentration of 1.52 J µg/L, which also exceeds the published SW GWP Standard of 1 µg/L. Cobalt has generally been detected in this background well since monitoring commenced in 1999. Vanadium was detected at concentrations greater than its respective SW GWP Standard of 0.3 µg/L in compliance groundwater monitoring wells MW-2R, MW-3, MW-10, MW-10A, MW-11A, MW-12, and MW- 13 at concentrations ranging from 1.49 J to 38.8 µg/L. It is important to point out that vanadium was also detected in background well MW-1R at a concentration of 1.81 J µg/L, which is greater than the published SW GPS Standard of 0.3 µg/L. Vanadium has been detected frequently in this background well since monitoring commenced in 1999. The metals detected in the monitoring wells during the May 2017 monitoring event are summarized in Table 4A in Appendix II. Based on previous metals concentrations in the background groundwater monitoring well MW-1/1R, it appears that the metals concentrations are from naturally occurring dissolved metals extracted from suspended solids (silts and clays) collected during sample extraction rather than an anthropogenic source. 3.1.3 Dissolved Metals To initiate an assessment of groundwater sample turbidity impacts on reported metals concentrations in groundwater at the site, ‘split’ samples were taken during sampling at any groundwater well location with a turbidity reading higher than 10 NTUs (Table 3 in Appendix II). Split samples include collecting the compliance required total metals samples as well as an additional metals sample that is filtered in the lab to determine a dissolved metals concentration. This informal review was not required by the facility permit, rather it was conducted to help assess if suspended or colloidal solids in groundwater samples were influencing the total metals concentrations reported. May 2017 Semi-Annual Monitoring Report Foxhole Landfill - Permit # 60-19 Charlotte, North Carolina S&ME Project No. 1356-07-003 August 9, 2017 3 Table 4B provides a summary of the detected dissolved metals concentrations and the dissolved metals concentrations for each well where these sample pairs were obtained during this event. The table also includes the field turbidity of the samples and a calculation of the percent difference between the total metals concentrations and the dissolved metal concentrations. Note, if the metal analyte was reported as below the reporting limit, the reporting limit was used for the calculation. Monitoring well MW-2R exhibited the highest sample field turbidity at 176.40 NTU. For the analytes detected at monitoring well MW-2R with concentrations greater than 1 µg/L, the calculated percent change values ranged from 44% to 88%, indicating substantially lower metal analyte concentrations for the sample pair’s filtered, dissolved metals sample. Similarly, samples obtained from monitoring well MW-12, with a field sample turbidity of 19.4 NTU, were calculated to yield percent change values that approximate 19%. Similar trends in the data were recognized from the paired data obtained at the other wells. These observations suggest that suspended or colloidal solids in the total metals samples are contributing to the reported groundwater sample concentrations. This can be significant as indicated by the observed results for vanadium at monitoring wells MW-1R, MW-2R, and MW-13, where the filtered samples reported concentrations that were less than the corresponding 2L Standard, whereas the companion unfiltered total metal sample reported concentrations greater than the 2L Standard. A comparison of the total chromium vs dissolved chromium concentrations reported for the samples obtained from monitoring well MW-2R, suggest that the exceedance of the 2L Standard for chromium was likely due to suspended solids in the sample obtained. A comparison of the total nickel vs dissolved nickel concentrations reported for the samples obtained from monitoring well MW-13 suggest that perhaps the suspended solids in the sample obtained do not play as large of a role in concentrations as nickel was detected at a higher concentration in the dissolved sample than in the total sample. Both of these detections were well below the 2L Standard for nickel. These observations suggest that despite the use of low-flow sampling methods, some obtained samples may overestimate the metals concentrations due to suspended or colloidal solids in the samples. 3.2 Surface Water Sampling 3.2.1 Volatile Organic Compounds No volatile organic compounds were detected in the surface water samples during the May 2017 sampling event. 3.2.2 Metals Two (2) or more inorganic constituents (metals) were detected in the surface water sample locations. Concentrations of barium, nickel, and vanadium were detected in one or both surface water locations at concentrations below their respective 2B Standard. 3.3 Lift-Station Leachate Sample On May 10, 2017, a sample of landfill leachate was collected from the lift-station. The collected sample was submitted for laboratory analyses for Volatile Organic Compounds (VOCs), Semi-Volatile Organic May 2017 Semi-Annual Monitoring Report Foxhole Landfill - Permit # 60-19 Charlotte, North Carolina S&ME Project No. 1356-07-003 August 9, 2017 4 Compounds (SVOCs), Pesticides, PCBs, Appendix I total metals, Cyanide (total), Ammonia, Biological Oxygen Demand, and Chemical Oxygen Demand. Appendix V contains the laboratory analytical report for this sample. 4.0 Statistical Analysis S&ME compared the water quality data with the 2L Standards and the SW GWP standards and performed a statistical evaluation of the data. S&ME utilized three statistical methods to evaluate statistically significant increases (SSI) between the compliance monitoring wells and the background monitoring well (MW-1/1R). The first method utilized was a one-way parametric Analysis of Variance (Parametric ANOVA). The parametric ANOVA analysis is recommended by the 1992 guidance document for parameters with fewer than 15% non-detects in a specific well. The second method used was the Kruskal-Wallis non-parametric rank method. The Kruskal-Wallis method is recommended by the 1992 guidance document for parameters that have 15% to 90% non- detects in a specific well. The third method used was an inter-well non-parametric prediction limit. The prediction limit was used for parameters with greater than 90% non-detects in a specific well. The 1992 guidance document recommends this method when a significant portion of the samples are non-detect. Table 6 in Appendix II summarizes the results of the statistical analysis. No SSI were indicated by the statistical tests performed, comparing the most recent event sample results for compliance monitoring wells against background monitoring well data. Copies of the analytical procedures used to perform the analysis used by the ChemStat software are included in Appendix IV. Time vs concentrations charts for chromium in wells MW-2R and MW-10A generally depict periodic spikes in the detected concentrations; however, most were not sustained or validated during the subsequent monitoring event. Mann-Kendall trend analysis of chromium in MW-2R indicates no evidence of an upper ward trend in concentrations over time. Mann-Kendall trend analysis of chromium in MW-10A, indicated evidence of an upward trend. The historic concentrations of chromium in well MW-10A exhibit noteworthy variability, likely related to differences in turbidity in the well during sample collection. It is noted that the 2L Standards do not apply to sediment or other particulate matter preserved in groundwater samples as a result of groundwater sample collection procedures or well construction issues. Redevelopment of wells MW-2R and MW-10A, followed by verification sampling should be considered to verify these SSIs and assess current conditions at these monitoring wells. Time vs concentrations charts for cobalt in wells MW-2R generally depict stable or declining concentrations over time, which is further supported by Mann-Kendall trend analyses indicating no evidence of an upward trend in this well. It is important to point out that time vs concentrations charts for concentrations of vanadium in wells MW-3, MW-10, MW-10A, MW-11A, MW-12, and MW-13 in MW-10A generally depict stable or declining concentrations over time. These observations are further supported by Mann-Kendall trend analyses indicating no evidence of an upward trend for vanadium concentrations over time in these wells. The May 2017 Semi-Annual Monitoring Report Foxhole Landfill - Permit # 60-19 Charlotte, North Carolina S&ME Project No. 1356-07-003 August 9, 2017 5 historical concentrations of vanadium in MW-10A are likely indicative of turbidity in the well. The majority of the wells on site have historically had detections of vanadium above the published 2L standard concentration, including background monitoring well MW-1R. The presence of chromium, cobalt and vanadium in the background well coupled with no evidence of upward trends for these constituents provides solid evidence to support that these constituents likely area a natural occurrence in the facility’s groundwater. 15A NCAC 02L .0202 contains a provision for instances where a naturally occurring substances exceed the published standards, such that standard shall be the naturally occurring concentration. Appendices Appendix I – Drawings LLLLLL631.80MW-2R584.96593.77MW-10/10A601.28MW-8614.59MW-7625.36MW-3654.87PHASE 1, CELL 2(AS-BUILT)PHASE 1, CELL1(AS BUILT)PHASE 2LIMIT OF SURVEY650 SW-2SW-1LEGENDPROPERTY LINEEXISTING GRADE CONTOURSTREAM NAMEEXISTING MONITORING WELL LOCATIONEXISTING NESTED MONITORING WELL LOCATIONGROUNDWATER SURFACE (MAY 2017)GROUNDWATER SURFACE ELEVATION (FT-MSL)SURFACE WATER SAMPLING LOCATIONGROUNDWATER FLOW DIRECTION1.EXISTING TOPOGRAPHY PREPARED BY INDEPENDENT MAPPING CONSULTANTS, INC.DATE OF PHOTOGRAPHY, MARCH, 2012, PROVIDED BY HDR.2.PHASE 2 GRADING PROVIDED BY HDR.3.MONITORING WELL MW-12 AND MW-13 LOCATIONS BASED ON 2012 SURVEY BYCAROLINA SURVEYORS, INC.REFERENCE:HIGHWAY 521 S&ME ENGINEERING LICENSE NO.F-01769751 SOUTHERN PINE BLVD. CHARLOTTE, N.C. 28273 PH. (704)523-4726NO.DATE DESCRIPTION BYDRAWING:OF:DATE:SCALE:PROJECT NUMBERDESIGNED BY:APPROVED BY:DRAWN BY:CHECKED BY:WWW.SMEINC.COM GROUNDWATER SURFACE MAP MAY, 2017 FOXHOLE LANDFILL (PERMIT NO. 60-19) CHARLOTTE, NORTH CAROLINA1356-07-003AS SHOWN08-03-2017JPRWRH11JPR654.87 Appendix II – Tables LATITUDE LONGITUDE GROUND TOH DTW - TOH GW ELEV. (MM/DD/YY)(ft)(ft-MSL) MW-1R 03/23/09 35.0164638° -080.8495912° 687.40 690.65 +3 .00 to 33.0 33.0 to 48.0 0.0 to 29.0 29.0 to 31.0 #2 31.0 to 48.0 SAP 35.78 654.87 MW-2R 02/16/10 35.0129978° -080.8487614° 660.90 663.80 +2.90 to 20.0 20.0 to 35.0 0.0 to 16.0 16.0 to 18.0 #2 18.0 to 35.0 SAP 32.00 631.80 MW-3 03/19/99 35.0162047° -080.8459443° 641.68 644.08 +2.25 to 10.0 10.0 to 25.0 0.0 to 5.0 5.0 to 8.0 #1 8.0 to 25.0 SAP 18.72 625.36 MW-7 03/16/99 35.0168592° -080.8441975° 634.81 637.90 +2.86 to 10.0 10.0 to 25.0 0.0 to 5.0 5.0 to 7.0 #1 7.0 to 25.0 SAP 23.31 614.59 MW-8 03/08/99 35.0160863° -080.8419354° 618.90 620.19 +2.35 to 10.0 10.0 to 25.0 0.0 to 5.0 5.0 to 8.0 #1 8.0 to 25.0 SAP 18.91 601.28 MW-10 04/02/99 35.0148756° -080.8403383° 624.23 627.03 +2.65 to 25.0 25.0 to 40.0 0.0 to 21.0 21.0 to 23.0 #1 23.0 to 40.0 SAP 33.26 593.77 MW-10A 03/31/99 35.0148756° -080.8403383° 624.30 627.32 +2.65 to 55.0 55.0 to 60.0 0.0 to 50.0 50.0 to 53.0 #1 53.0 to 60.0 SAP 33.77 593.55 MW-11 03/06/99 35.0133929° -080.8392855° 593.53 595.67 +1.47 to 7.0 7.0 to 22.0 0.0 to 3.0 3.0 to 5.0 #1 5.0 to 22.0 SAP 10.71 584.96 MW-11A 02/26/99 35.0133929° -080.8392855° 594.12 596.38 +1.62 to 40.0 40.0 to 45.0 0.0 to 36.0 36.0 to 38.0 #1 38.0 to 45.0 SAP 11.21 585.17 MW-12 10/02/12 35.0105705° -080.8450554° 633.10 636.07 +2.94 to 15.7 15.7 to 30.7 0.0 to 11.0 11.0 to 14.0 #2 14.0 to 31.2 SAP 21.39 614.68 MW-13 10/03/12 35.0122690° -080.8405290° 619.30 622.36 +3.04 to 23.0 23.0 to 38.0 0.0 to 18.0 18.0 to 21.0 #2 21.0 to 38.5 SAP 25.98 596.38 Notes: (ft-MSL)Feet Mean Sea Level #1 Filter Sand Fine to Very Fine Grained Silica Sand (ft-bls)Feet Below Land Surface Bentonite Bentonite Pellets TOH Top of Hinge Sch. 40 Schedule 40 Pipe Ground Ground Surface 0.010 Slot 0.010-Inch Machine-Slotted Pipe DTW Depth to Water Neat Cement Cement Mixture without Bentonite GW ELEV.Groundwater Elevation NA Not Available #2 Filter Sand Medium to Fine Grained Silica Sand SAP Saprolite The "A" suffix on the well locations indicates the deep well of the pair. NM Not Measured May 2017 2-INCH, SCH. 40, PVC 2-INCH, 0.010 SLOT, PVC NEAT CEMENT BENTONITE (decimal degrees)(ft-MSL)(ft-bls)(ft-bls)(ft-bls) SCREEN INTERVAL GROUT INTERVAL SEAL INTERVAL FILTER PACK SIZE FILTER PACK INTERVAL GEOLOGY IN SCREEN INTERVAL(ft-bls)(ft-bls) Table 1 Well Construction Summary and Water Level Data Mecklenburg County Highway 521 Landfill - Foxhole S&ME Project No: 1356-07-003 WELL ID INSTALL DATE GPS COORDINATES SURVEY ELEVATIONS CASING INTERVAL Table 2 May 2017 - Groundwater Flow Velocity Mecklenburg County Highway 521 Landfill "Foxhole" Permit # 60-19 S&ME Project No. 1356-07-003 Well Identification Hydraulic Conductivity (K) ft/yr Effective Porosity (ne) % Hydraulic Gradient (i) ft/ft Seepage Velocity (v) ft/yr 6019 MW-1R 3.3E+02 0.15 0.023 51 6019 MW-2R 6.6E+02 0.13 0.008 42 6019 MW-3 3.6E+02 0.09 0.006 23 6019 MW-7 1.3E+03 0.20 0.006 38 6019 MW-8 1.6E+03 0.20 0.016 125 6019 MW-10 5.0E+02 0.23 0.012 26 6019 MW-11 1.9E+02 0.25 0.003 2 6019 MW-12 3.1E+02 0.27 0.004 4 6019 MW-13 2.8E+03 0.25 0.009 98 Notes: (1) Hydraulic Conductivity was calculated from slug tests performed after well construction. (2) Effective porosity was estimated from soils collected within the saturated portion of screen interval during well construction. (3) Hydraulic gradient calculated by measuring linear feet between selected contour intervals. (4) Seepage velocity v = (K*i)/ne Well ID Depth to Water TOC (ft-bls)pH Temperature (°C) Conductance (μS/sec) Turbidity (NTU) 6019 MW-1R 35.78 6.24 17.5 54 28.62 6019 MW-2R 32.00 5.80 17.3 37 176.40 6019 MW-3 18.72 6.57 15.8 59 2.35 6019 MW-7 23.31 6.34 15.8 66 0.28 6019 MW-8 18.91 5.81 15.0 63 0.56 6019 MW-10 33.26 6.31 17.6 56 8.13 6019 MW-10A 33.77 11.16 17.7 215 6.58 6019 MW-11 10.71 6.13 16.2 288 1.43 6019 MW-11A 11.21 7.53 17.4 212 1.05 6019 MW-12 21.39 6.68 18.7 84 19.40 6019 MW-13 25.98 6.80 15.9 55 21.34 Notes: (1) μS = microSiemens (2) ft-bls = feet below land surface (3) °C = degrees Celsius Permit # 60-19 S&ME Project No. 1356-07-003 Table 3 May 2017 - Field Parameters in Groundwater Monitoring Wells Mecklenburg County Highway 521 Landfill "Foxhole" EPA Appendix I Volatile Organic Compounds Method 8260 (µg/L) NCDENR SWSL 15A NCAC 2L Solid Waste GWP ST 6019 MW-1R 6019 MW-2R 6019 MW-3 6019 MW-7 6019 MW-8 6019 MW-10 6019 MW-10A 6019 MW-11 6019 MW-11A 6019 MW-12 6019 MW-13 Chloroform 5 70 NE 1.0 J EPA Appendix I Total Metals Method 6010D/6020B (µg/L) Antimony 6 NE 1 0.500 J Barium 100 700 NE 70.3 J 87.3 J 31.8 J 16.8 J 18.7 J 36.6 J 9.24 J 50.5 J 23.1 J 19.8 J 51.8 J Beryllium 1 NE 4 0.180 J 0.184 J Chromium 10 10 NE 2.10 J 14.4 3.94 J 1.53 J 3.47 J 15.8 3.16 J 5.01 J Cobalt 10 NE 1 1.52 J 4.62 J Copper 10 1000 NE 52.9 1.63 J Nickel 50 100 NE 6.89 J 7.29 J 3.02 J Thallium 5.5 NE 0.28 0.136 J Vanadium 25 NE 0.3 1.81 J 11.2 J 4.28 J 4.87 J 38.8 6.05 J 3.40 J 1.49 J Zinc 10 1000 NE 12.2 22.6 Notes for Table 4A: (1) µg/L = micrograms per liter (parts per billion) (2) 15A NCAC 2L = North Carolina Groundwater Quality Standards (3) GWP ST = Solid Waste Groundwater Protection Standard (4) NE = No established standard (5) J = Reported value is between method detection limit (MDL) and method reporting limit (MRL) (6) B = Analyte was detected in associated laboratory method blank. (7) Bold and highlighted indicates above 15A NCAC 2L or SW GWP standard (8) Target analytes not shown were reported as below detection limits (9) SWSL = North Carolina Department of Environmtent and Natural Resources Solid Waste Section Limit established in 2007 Table 4A May 2017 - Detected Analytes in Groundwater Monitoring Wells Mecklenburg County Highway 521 Landfill "Foxhole" Permit # 60-19 S&ME Project No. 1356-07-003 Table 4B May 2017 - Dissolved Metals in Groundwater Monitoring Wells Mecklenburg County Highway 521 Landfill "Foxhole" Permit # 60-19 S&ME Project No. 1356-07-003 6019 MW-1R 6019 MW-2R 6019 MW-12 6019 MW-13 15A NCAC 2L Solid Waste GWP ST Barium Totals 70.3 J 87.3 J 19.8 J 51.8 J 700 NE Dissolved 57.1 J 48.8 J 15.1 J 45.3 J Field Turbidity 28.62 176.40 19.4 21.34 % difference 19%44%24%13% Beryllium Totals 0.180 J 0.184 J NE 4 Dissolved 0.130 U 0.130 U Field Turbidity 28.62 176.40 % difference 28%29% Chromium Totals 2.10 J 14.4 5.01 J 10 NE Dissolved 1.00 U 2.46 J 4.30 J Field Turbidity 28.62 176.40 19.4 % difference 52%83%14% Cobalt Totals 1.52 J 4.62 J NE 1 Dissolved 1.10 U 2.20 J Field Turbidity 28.62 176.40 % difference 28%52% Copper Totals 52.9 1000 NE Dissolved 10.4 Field Turbidity 176.40 % difference 80% Nickel Totals 6.89 J 7.29 J 3.02 J 2.20 U 100 NE Dissolved 5.13 J 3.75 J 2.95 J 6.15 J Field Turbidity 28.62 176.40 19.4 21.34 % difference 26%49%2%-180% Thallium Totals 0.136 J NE 0.28 Dissolved 0.110 U Field Turbidity 176.40 % difference 19% Vanadium Totals 1.81 J 11.2 J 3.40 J 1.49 J NE 0.3 Dissolved 1.40 U 1.40 U 2.20 J 1.40 U Field Turbidity 28.62 176.40 19.4 21.34 % difference 23%88%35%6% Zinc Totals 12.2 22.6 1000 NE Dissolved 8.81 JB 10.7 B Field Turbidity 28.62 176.40 % difference 28%53% Notes for Table 4B: (1) µg/L = micrograms per liter (parts per billion) (2) 15A NCAC 2L = North Carolina Groundwater Quality Standards (3) GWP ST = Solid Waste Groundwater Protection Standard (4) NE = No established standard (5) J = Reported value is between method detection limit (MDL) and method reporting limit (MRL) (6) U = Analyte was not detected at or above the method reporting limit shown (7) Bold and highlighted indicates above 15A NCAC 2L or SW GWP standard (8) SWSL = North Carolina Department of Environmtent and Natural Resources Solid Waste Section Limit established in 2007 EPA Appendix I Metals (ug/L) (9) % Difference = Percent difference between the total metal concentration and the dissolved metal concentration. If the analyte was reported as being below the reporting limit, the reporting limit concentration was used for the calculation. Table 5 May 2017 - Detected Analytes in Surface Water Samples Mecklenburg County Highway 521 Landfill "Foxhole" Permit # 60-19 S&ME Project No. 1356-07-003 EPA Appendix I Metals Method 6010B/6020 (µg/L) 15A NCAC 2B SW-1 SW-2 EPA Appendix I Metals Method 6010B/6020 (µg/L) Barium 1,000 28.0 J 25.1 J Nickel 88 6.01 J Vanadium NE 2.52 J 1.48 J Notes: (1) µg/L = micrograms per liter (parts per billion) (2) 15A NCAC 2B = North Carolina Surface Water Quality Standards for Freshwater (3) NE = No established standard (5) B = Analyte was detected in associated laboratory method blank (6) Bold and highlighted indicates concentration reported is above 15A NCAC 2B (7) Compounds not shown were not detected. (8) Target analytes not shown were reported as below detection limits No Volatile Organic Compounds Detected in Surface Water Samples (4) J = Reported value is estimated between method detection limit (MDL) and method reporting limit (MRL) Antimony MW-10 97 PL FALSE MW-10A 79 KW FALSE MW-11 97 PL FALSE MW-2 85 KW FALSE MW-3 89 KW FALSE MW-7 94 PL FALSE MW-8 95 PL FALSE MW-13 92 PL FALSE MW-12 83 KW FALSE Arsenic MW-10 89 KW FALSE MW-10A 89 KW FALSE MW-11 89 KW FALSE MW-11A 92 PL FALSE MW-2 91 PL FALSE MW-3 89 KW FALSE MW-7 92 PL FALSE MW-8 92 PL FALSE MW-13 92 PL FALSE Barium MW-2 42 KW FALSE MW-3 37 KW FALSE MW-7 47 KW FALSE MW-8 45 KW FALSE MW-10 37 KW FALSE MW-10A 45 KW FALSE MW-11 45 KW FALSE MW-11A 45 KW FALSE MW-13 0 PA FALSE MW-12 0 PA FALSE Beryllium MW-2 79 KW FALSE MW-3 95 PL FALSE MW-7 97 PL FALSE MW-8 87 KW FALSE MW-10 84 KW FALSE MW-10A 92 PL FALSE MW-11 76 KW FALSE MW-11A 97 PL FALSE MW-13 67 KW FALSE Comments Table 6 May 2017 - Statistical Analysis Mecklenburg County Highway 521 Landfill "Foxhole" Permit # 60-19 S&ME Project No. 1356-07-003 Parameter Well ID Percent Non-Detect Statistical Analysis Method SSI Page 1 of 4 Comments Table 6 May 2017 - Statistical Analysis Mecklenburg County Highway 521 Landfill "Foxhole" Permit # 60-19 S&ME Project No. 1356-07-003 Parameter Well ID Percent Non-Detect Statistical Analysis Method SSI Cadmium MW-10 95 PL FALSE MW-10A 92 PL FALSE MW-11 92 PL FALSE MW-11A 92 PL FALSE MW-2 82 KW FALSE MW-3 95 PL FALSE MW-7 89 KW FALSE MW-8 97 PL FALSE MW-12 83 KW FALSE Chromium MW-2 55 KW FALSE MW-3 47 KW FALSE MW-7 81 KW FALSE MW-8 97 PL FALSE MW-10 45 KW FALSE MW-10A 5 PA FALSE MW-11 76 KW FALSE MW-11A 42 KW FALSE MW-13 33 KW FALSE MW-12 0 PA FALSE Cobalt MW-10 95 PL FALSE MW-10A 97 PL FALSE MW-11 87 KW FALSE MW-11A 97 PL FALSE MW-2 6 PA FALSE MW-8 97 PL FALSE MW-13 42 KW FALSE MW-12 67 KW FALSE Copper MW-10 74 KW FALSE MW-10A 47 KW FALSE MW-11 92 PL FALSE MW-11A 84 KW FALSE MW-2 42 KW FALSE MW-3 89 KW FALSE MW-7 92 PL FALSE MW-8 89 KW FALSE MW-13 67 KW FALSE MW-12 83 KW FALSE Page 2 of 4 Comments Table 6 May 2017 - Statistical Analysis Mecklenburg County Highway 521 Landfill "Foxhole" Permit # 60-19 S&ME Project No. 1356-07-003 Parameter Well ID Percent Non-Detect Statistical Analysis Method SSI Lead MW-10 97 PL FALSE MW-11 97 PL FALSE MW-11A 97 PL FALSE MW-2 82 KW FALSE MW-3 95 PL FALSE MW-7 97 PL FALSE MW-8 97 PL FALSE MW-13 75 KW FALSE MW-12 92 PL FALSE Nickel MW-10 87 KW FALSE MW-10A 92 PL FALSE MW-11 84 KW FALSE MW-11A 92 PL FALSE MW-2 48 KW FALSE MW-3 95 PL FALSE MW-7 94 PL FALSE MW-8 97 PL FALSE MW-13 83 KW FALSE MW-12 0 PA FALSE Selenium MW-10 97 PL FALSE MW-10A 97 PL FALSE MW-11 95 PL FALSE MW-11A 97 PL FALSE MW-2 97 PL FALSE MW-3 97 PL FALSE MW-7 94 PL FALSE MW-8 97 PL FALSE MW-13 92 PL FALSE Thallium MW-10A 95 PL FALSE MW-11 95 PL FALSE MW-11A 95 PL FALSE MW-2 88 KW FALSE MW-3 97 PL FALSE MW-8 97 PL FALSE MW-13 92 PL FALSE Vanadium MW-2 64 KW FALSE MW-3 45 KW FALSE MW-7 94 PL FALSE MW-8 95 PL FALSE MW-10 45 KW FALSE MW-10A 37 KW FALSE MW-11 74 KW FALSE MW-11A 45 KW FALSE MW-13 8 PA FALSE MW-12 0 PA FALSE Page 3 of 4 Comments Table 6 May 2017 - Statistical Analysis Mecklenburg County Highway 521 Landfill "Foxhole" Permit # 60-19 S&ME Project No. 1356-07-003 Parameter Well ID Percent Non-Detect Statistical Analysis Method SSI Zinc MW-10 79 KW FALSE MW-10A 79 KW FALSE MW-11 76 KW FALSE MW-11A 92 PL FALSE MW-2 48 KW FALSE MW-3 95 PL FALSE MW-7 94 PL FALSE MW-8 95 PL FALSE MW-13 17 KW FALSE MW-12 50 KW FALSE Notes: (1)SSI = Statistically Significant Increase (2)PA = One Way Parametric Analysis of Variance (Parametric ANOVA) Parametric ANOVA analysis is recommended by the 1992 guidance document for parameters with fewer than 15% non-detects in a specific well. (3)KW = Kruskal Wallis Non-Parametric Rank Analysis Kruskal-Wallis method is recommended by the 1992 guidance document for parameters that have 15% to 90% non-detects in a specific well. (4)PL = Non-Parametric Inter-Well Prediction Limit Analysis Prediction limit was used for parameters with greater than 90% non-detects in a specific well. The 1992 guidance document recommends this method when a significant portion of the samples are non-detect. Page 4 of 4 Appendix III – Well Sampling Logs and Laboratory Reports HIGHWAY 521 LANDFILL ("THE FOXHOLE") MECKLENBURG COUNTY, NORTH CAROLINA LIFT STATION SAMPLING LOG S&ME PROJECT:1356-07-003 DATE: PERSONNEL:SJT/NGS LIFT STATION Field Readings pH Conductivity (mS/sec) Temperature (°C) Parameters #Containers BOD+Ammonia as N 1 1 Liter Plastic TSS 1 1 Liter Plastic COD 1 250 mL Plastic + H2SO4 App I metals +Mo+Hg 1 250 mL Plastic + HNO3 Cyanide 1 250 mL Plastic + NaOH TTO 2 1 Liter Amber Glass VOC 624 3 40 mL Glass Vial + HCl Trip Blank 3 40 mL Glass Vial + HCl Sample Time: Laboratory: 21.3 0930 ENCO 5/10/2017 7.48 2637 HIGHWAY 521 LANDFILL ("THE FOXHOLE") MECKLENBURG COUNTY, NORTH CAROLINA SURFACE WATER SAMPLING LOG S&ME PROJECT:1356-07-003 DATE: PERSONNEL: SURFACE WATER Sample Time Observations SW-1 0900 none/clear 5/10/2017 SW-2 1215 none/clear 5/9/2017 5/9/2017 SJT/NGS HIGHWAY 521 LANDFILL ("THE FOXHOLE") MECKLENBURG COUNTY, NORTH CAROLINA MONITOR WELL SAMPLING LOG S&ME PROJECT:1356-07-003 WELL ID: DATE: PERSONNEL:WEATHER: REASON FOR SAMPLING: Total Well Depth from Hinge:51 ft Purge Pressure:20 psi Initial Depth to Water (DTW) from Hinge:35.78 ft Refill Time 11.8 sec Water Column:15.2 ft Discharge Time:5.8 sec Well Diameter:2.0 in Purge Cycle Volume:100 ml Well Casing and Sand Pack volume per foot of water in screen interval For 4-inch diameter wells =1.74 gallons 6.60 liters For 2-inch diameter wells =0.45 gallons 1.70 liters Depth to Pump from Hinge:28.5 ft Pump and Tubing Volume (liters) =0.4 (pump volume) + depth to pump (ft) * .039 Well Wizard Pump & Tubing Volume + 1 foot of water column =4 liters liters/3.785 =1.06 gallons Field Readings 1 2 3 pH 8.41 7.27 6.24 Conductivity (mS/sec)108 64 54 Temperature (°C)17.5 17.6 17.5 Turbidity (NTUs)21.83 22.46 28.62 Volume (liters)5 6 7 Parameters #Containers Appendix I VOCs 3 40-ml HCL preserved glass Vials Appendix I Metals 1 250-ml HNO3 preserved plastic bottle Dissolved Metals Sample Time: Laboratory: Shipping Date:5/10/2017 ENCO 0845 MW-1R First Semi-Annual Sampling Event 2017 SJT/NGS Sunny 5/9/2017 HIGHWAY 521 LANDFILL ("THE FOXHOLE") MECKLENBURG COUNTY, NORTH CAROLINA MONITOR WELL SAMPLING LOG S&ME PROJECT:1356-07-003 WELL ID: DATE: PERSONNEL:WEATHER: REASON FOR SAMPLING: Total Well Depth from Hinge:~37.6 ft Purge Pressure:psi Initial Depth to Water (DTW) from Hinge:32.00 ft Refill Time sec Water Column:5.6 ft Discharge Time:sec Well Diameter:2.0 in Purge Cycle Volume:100 ml Well Casing and Sand Pack volume per foot of water in screen interval For 4-inch diameter wells =1.74 gallons 6.60 liters For 2-inch diameter wells =0.45 gallons 1.70 liters Depth to Pump from Hinge:23.1 ft Pump and Tubing Volume (liters) =0.4 (pump volume) + depth to pump (ft) * .039 Well Wizard Pump & Tubing Volume + 1 foot of water column =4 liters liters/3.785 =1.06 gallons Field Readings 1 2 3 pH 6.40 5.93 5.80 Conductivity (mS/sec)43 37 37 Temperature (°C)17.9 17.0 17.3 Turbidity (NTUs)76.10 264.40 176.40 Volume (liters)5 6 7 Parameters #Containers Appendix I VOCs 3 40-ml HCL preserved glass Vials Appendix I Metals 1 250-ml HNO3 preserved plastic bottle Dissolved Metals Sample Time: Laboratory: Shipping Date: 1415 ENCO 5/10/2017 MW-2R First Semi-Annual Sampling Event 2017 SJT/NGS Sunny 5/9/2017 HIGHWAY 521 LANDFILL ("THE FOXHOLE") MECKLENBURG COUNTY, NORTH CAROLINA MONITOR WELL SAMPLING LOG S&ME PROJECT:1356-07-003 WELL ID: DATE: PERSONNEL:WEATHER: REASON FOR SAMPLING: Total Well Depth from Hinge:27.6 ft Purge Pressure:15 psi Initial Depth to Water (DTW) from Hinge:18.72 ft Refill Time 11.5 sec Water Column:8.9 ft Discharge Time:5.3 sec Well Diameter:4.0 in Purge Cycle Volume:100 ml Well Casing and Sand Pack volume per foot of water in screen interval For 4-inch diameter wells =1.74 gallons 6.60 liters For 2-inch diameter wells =0.45 gallons 1.70 liters Depth to Pump from Hinge:22.6 ft Pump and Tubing Volume (liters) =0.4 (pump volume) + depth to pump (ft) * .039 Well Wizard Pump & Tubing Volume + 1 foot of water column =8 liters liters/3.785 =2.11 gallons Field Readings 1 2 3 pH 6.46 6.54 6.57 Conductivity (mS/sec)80 70 59 Temperature (°C)16.0 15.9 15.8 Turbidity (NTUs)0.78 0.62 2.35 Volume (liters)9 10 11 Parameters #Containers Appendix I VOCs 3 40-ml HCL preserved glass Vials Appendix I Metals 1 250-ml HNO3 preserved plastic bottle Sample Time: Laboratory: Shipping Date: 0920 ENCO 5/10/2017 MW-3 First Semi-Annual Sampling Event 2017 SJT/NGS Sunny 5/9/2017 HIGHWAY 521 LANDFILL ("THE FOXHOLE") MECKLENBURG COUNTY, NORTH CAROLINA MONITOR WELL SAMPLING LOG S&ME PROJECT:1356-07-003 WELL ID: DATE: PERSONNEL:WEATHER: REASON FOR SAMPLING: Total Well Depth from Hinge:28 ft Purge Pressure:18 psi Initial Depth to Water (DTW) from Hinge:23.31 ft Refill Time 10 sec Water Column:4.7 ft Discharge Time:3.4 sec Well Diameter:4.0 in Purge Cycle Volume:100 ml Well Casing and Sand Pack volume per foot of water in screen interval For 4-inch diameter wells =1.74 gallons 6.60 liters For 2-inch diameter wells =0.45 gallons 1.70 liters Depth to Pump from Hinge:23.0 ft Pump and Tubing Volume (liters) =0.4 (pump volume) + depth to pump (ft) * .039 Well Wizard Pump & Tubing Volume + 1 foot of water column =8 liters liters/3.785 =2.11 gallons Field Readings 1 2 3 pH 6.40 6.45 6.34 Conductivity (mS/sec)111 68 66 Temperature (°C)16.2 15.9 15.8 Turbidity (NTUs)0.08 1.33 0.28 Volume (liters)9 10 11 Parameters #Containers Appendix I VOCs 3 40-ml HCL preserved glass Vials Appendix I Metals 1 250-ml HNO3 preserved plastic bottle Sample Time: Laboratory: Shipping Date: 1010 ENCO 5/10/2017 MW-7 First Semi-Annual Sampling Event 2017 SJT/NGS Sunny 5/9/2017 HIGHWAY 521 LANDFILL ("THE FOXHOLE") MECKLENBURG COUNTY, NORTH CAROLINA MONITOR WELL SAMPLING LOG S&ME PROJECT:1356-07-003 WELL ID: DATE: PERSONNEL:WEATHER: REASON FOR SAMPLING: Total Well Depth from Hinge:27.8 ft Purge Pressure:15 psi Initial Depth to Water (DTW) from Hinge:18.91 ft Refill Time 12 sec Water Column:8.89 ft Discharge Time:5.8 sec Well Diameter:4.0 in Purge Cycle Volume:100 ml Well Casing and Sand Pack volume per foot of water in screen interval For 4-inch diameter wells =1.74 gallons 6.60 liters For 2-inch diameter wells =0.45 gallons 1.70 liters Depth to Pump from Hinge:22.8 ft Pump and Tubing Volume (liters) =0.4 (pump volume) + depth to pump (ft) * .039 Well Wizard Pump & Tubing Volume + 1 foot of water column =8 liters liters/3.785 =2.11 gallons Field Readings 1 2 3 pH 6.00 5.87 5.81 Conductivity (mS/sec)72 68 63 Temperature (°C)15.9 15.6 15.6 Turbidity (NTUs)0.58 0.29 0.56 Volume (liters)9 10 11 Parameters #Containers Appendix I VOCs 3 40-ml HCL preserved glass Vials Appendix I Metals 1 250-ml HNO3 preserved plastic bottle Sample Time: Laboratory: Shipping Date: 1040 ENCO 5/10/2017 MW-8 First Semi-Annual Sampling Event 2017 SJT/NGS Sunny 5/9/2017 HIGHWAY 521 LANDFILL ("THE FOXHOLE") MECKLENBURG COUNTY, NORTH CAROLINA MONITOR WELL SAMPLING LOG S&ME PROJECT:1356-07-003 WELL ID: DATE: PERSONNEL:WEATHER: REASON FOR SAMPLING: Total Well Depth from Hinge:42.3 ft Purge Pressure:35 psi Initial Depth to Water (DTW) from Hinge:33.26 ft Refill Time 12 sec Water Column:9.0 ft Discharge Time:5.8 sec Well Diameter:2.0 in Purge Cycle Volume:100 ml Well Casing and Sand Pack volume per foot of water in screen interval For 4-inch diameter wells =1.74 gallons 6.60 liters For 2-inch diameter wells =0.45 gallons 1.70 liters Depth to Pump from Hinge:37.3 ft Pump and Tubing Volume (liters) =0.4 (pump volume) + depth to pump (ft) * .039 Well Wizard Pump & Tubing Volume + 1 foot of water column =4 liters liters/3.785 =1.05 gallons Field Readings 1 2 3 pH 6.30 6.36 6.31 Conductivity (mS/sec)67 58 56 Temperature (°C)18.3 17.9 17.6 Turbidity (NTUs)6.27 5.91 8.13 Volume (liters)5 6 7 Parameters #Containers Appendix I VOCs 3 40-ml HCL preserved glass Vials Appendix I Metals 1 250-ml HNO3 preserved plastic bottle Sample Time: Laboratory: Shipping Date: 1125 ENCO 5/10/2017 MW-10 First Semi-Annual Sampling Event 2017 SJT/NGS Sunny 5/9/2017 HIGHWAY 521 LANDFILL ("THE FOXHOLE") MECKLENBURG COUNTY, NORTH CAROLINA MONITOR WELL SAMPLING LOG S&ME PROJECT:1356-07-003 WELL ID: DATE: PERSONNEL:WEATHER: REASON FOR SAMPLING: Total Well Depth from Hinge:61.5 ft Purge Pressure:30 psi Initial Depth to Water (DTW) from Hinge:33.77 ft Refill Time 17 sec Water Column:27.7 ft Discharge Time:5 sec Well Diameter:2.0 in Purge Cycle Volume:100 ml Well Casing and Sand Pack volume per foot of water in screen interval For 4-inch diameter wells =1.74 gallons 6.60 liters For 2-inch diameter wells =0.45 gallons 1.70 liters Depth to Pump from Hinge:56.0 ft Pump and Tubing Volume (liters) =0.4 (pump volume) + depth to pump (ft) * .039 Well Wizard Pump & Tubing Volume + 1 foot of water column =4 liters liters/3.785 =1.05 gallons Field Readings 1 2 3 pH 10.39 11.13 11.16 Conductivity (mS/sec)183 218 215 Temperature (°C)18.0 17.8 17.7 Turbidity (NTUs)8.32 10.84 6.58 4.96 <--Took 4th reading to determine if Volume (liters)5 6 7 dissolved metals necessary Parameters #Containers Appendix I VOCs 3 40-ml HCL preserved glass Vials Appendix I Metals 1 250-ml HNO3 preserved plastic bottle Sample Time: Laboratory: Shipping Date: 1145 ENCO 5/10/2017 MW-10A First Semi-Annual Sampling Event 2017 SJT/NGS Sunny 5/9/2017 HIGHWAY 521 LANDFILL ("THE FOXHOLE") MECKLENBURG COUNTY, NORTH CAROLINA MONITOR WELL SAMPLING LOG S&ME PROJECT:1356-07-003 WELL ID: DATE: PERSONNEL:WEATHER: REASON FOR SAMPLING: Total Well Depth from Hinge:24.7 ft Purge Pressure:15 psi Initial Depth to Water (DTW) from Hinge:10.71 ft Refill Time 12.3 sec Water Column:14.0 ft Discharge Time:6.1 sec Well Diameter:4.0 in Purge Cycle Volume:100 ml Well Casing and Sand Pack volume per foot of water in screen interval For 4-inch diameter wells =1.74 gallons 6.60 liters For 2-inch diameter wells =0.45 gallons 1.70 liters Depth to Pump from Hinge:19.7 ft Pump and Tubing Volume (liters) =0.4 (pump volume) + depth to pump (ft) * .039 Well Wizard Pump & Tubing Volume + 1 foot of water column =8 liters liters/3.785 =2.11 gallons Field Readings 1 2 3 pH 6.69 6.24 6.13 Conductivity (mS/sec)290 289 288 Temperature (°C)17.5 16.4 16.2 Turbidity (NTUs)1.80 1.09 1.43 Volume (liters)9 10 11 Parameters #Containers Appendix I VOCs 3 40-ml HCL preserved glass Vials Appendix I Metals 1 250-ml HNO3 preserved plastic bottle Sample Time: Laboratory: Shipping Date: 1240 ENCO 5/10/2017 MW-11 First Semi-Annual Sampling Event 2017 SJT/NGS Sunny 5/9/2017 HIGHWAY 521 LANDFILL ("THE FOXHOLE") MECKLENBURG COUNTY, NORTH CAROLINA MONITOR WELL SAMPLING LOG S&ME PROJECT:1356-07-003 WELL ID: DATE: PERSONNEL:WEATHER: REASON FOR SAMPLING: Total Well Depth from Hinge:47.4 ft Purge Pressure:25 psi Initial Depth to Water (DTW) from Hinge:11.21 ft Refill Time 12 sec Water Column:36.2 ft Discharge Time:5.5 sec Well Diameter:4.0 in Purge Cycle Volume:100 ml Well Casing and Sand Pack volume per foot of water in screen interval For 4-inch diameter wells =1.74 gallons 6.60 liters For 2-inch diameter wells =0.45 gallons 1.70 liters Depth to Pump from Hinge:41.9 ft Pump and Tubing Volume (liters) =0.4 (pump volume) + depth to pump (ft) * .039 Well Wizard Pump & Tubing Volume + 1 foot of water column =9 liters liters/3.785 =2.38 gallons Field Readings 1 2 3 pH 8.37 8.20 7.53 Conductivity (mS/sec)224 206 212 Temperature (°C)18.4 17.8 17.4 Turbidity (NTUs)2.11 1.36 1.05 Volume (liters)10 11 12 Parameters #Containers Appendix I VOCs 3 40-ml HCL preserved glass Vials Appendix I Metals 1 250-ml HNO3 preserved plastic bottle Sample Time: Laboratory: Shipping Date: 1225 ENCO 5/10/2017 MW-11A First Semi-Annual Sampling Event 2017 SJT/NGS Sunny 5/9/2017 HIGHWAY 521 LANDFILL ("THE FOXHOLE") MECKLENBURG COUNTY, NORTH CAROLINA MONITOR WELL SAMPLING LOG S&ME PROJECT:1356-07-003 WELL ID: DATE: PERSONNEL:WEATHER: REASON FOR SAMPLING: Total Well Depth from Hinge:34.14 ft Purge Pressure:20 psi Initial Depth to Water (DTW) from Hinge:21.39 ft Refill Time 12 sec Water Column:12.8 ft Discharge Time:6.2 sec Well Diameter:2.0 in Purge Cycle Volume:100 ml Well Casing and Sand Pack volume per foot of water in screen interval For 4-inch diameter wells =1.74 gallons 6.60 liters For 2-inch diameter wells =0.45 gallons 1.70 liters Depth to Pump from Hinge:29.1 ft Pump and Tubing Volume (liters) =0.4 (pump volume) + depth to pump (ft) * .039 Well Wizard Pump & Tubing Volume + 1 foot of water column =4 liters liters/3.785 =1 gallons Field Readings 1 2 3 pH 6.79 6.75 6.68 Conductivity (mS/sec)92 88 84 Temperature (°C)19.4 17.7 18.7 Turbidity (NTUs)9.20 20.08 19.40 Volume (liters)5 6 7 Parameters #Containers Appendix I VOCs 3 40-ml HCL preserved glass Vials Appendix I Metals 1 250-ml HNO3 preserved plastic bottle Dissolved Metals Sample Time: Laboratory: Shipping Date: MW-12 5/9/2017 SJT/NGS Sunny First Semi-Annual Sampling Event 2017 1345 ENCO 5/10/2017 HIGHWAY 521 LANDFILL ("THE FOXHOLE") MECKLENBURG COUNTY, NORTH CAROLINA MONITOR WELL SAMPLING LOG S&ME PROJECT:1356-07-003 WELL ID: DATE: PERSONNEL:WEATHER: REASON FOR SAMPLING: Total Well Depth from Hinge:42.3 ft Purge Pressure:25 psi Initial Depth to Water (DTW) from Hinge:ft Refill Time 12 sec Water Column:ft Discharge Time:5 sec Well Diameter:2.0 in Purge Cycle Volume:100 ml Well Casing and Sand Pack volume per foot of water in screen interval For 4-inch diameter wells =1.74 gallons 6.60 liters For 2-inch diameter wells =0.45 gallons 1.70 liters Depth to Pump from Hinge:37.3 ft Pump and Tubing Volume (liters) =0.4 (pump volume) + depth to pump (ft) * .039 Well Wizard Pump & Tubing Volume + 1 foot of water column =4 liters liters/3.785 =1 gallons Field Readings 1 2 3 pH 6.95 7.00 6.80 Conductivity (mS/sec)72 56 55 Temperature (°C)17.2 16.2 15.9 Turbidity (NTUs)13.31 19.71 21.34 Volume (liters)5 6 7 Parameters #Containers Appendix I VOCs 3 40-ml HCL preserved glass Vials Appendix I Metals 1 250-ml HNO3 preserved plastic bottle Dissolved Metals Sample Time: Laboratory: Shipping Date: MW-13 5/9/2017 SJT/NGS Sunny First Semi-Annual Sampling Event 2017 1310 ENCO 5/10/2017 Appendix IV – Statistical Analysis Procedure Sheets Appendix V – Lift Station Laboratory Report