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6201_MontgomeryCountyMSWLF_GWMR_20171019
Groundwater Statistical Analysis Report Second Semi-Annual 2017 Sampling Event Montgomery County Landfill Mt. Gilead, North Carolina October 2017 Prepared by: 1002 Morgan Meadow Drive 314-496-4654 Wentzville, MO 63385 www.jettenviro.com TABLE OF CONTENTS 1.0 INTRODUCTION .............................................................................1 2.0 SITE BACKGROUND AND MONITORING NETWORK ................1 3.0 SITE HYDROGEOLOGY ................................................................2 4.0 DATA EVALUATION ......................................................................2 5.0 STATISTICAL PROCEDURES .......................................................3 5.1 Outlier Analysis ...........................................................................3 5.2 Intra-Well Prediction Intervals ....................................................3 5.3 Statistical Results Summary .......................................................3 6.0 CONCLUSIONS ..............................................................................4 TABLES Table 1 Groundwater Monitoring Program Table 2 Analytical Data Summary, Second Semi-Annual 2017 Event APPENDICES Appendix A Potentiometric Surface Map Appendix B Statistical Evaluations Appendix C Laboratory Analytical Report & Field Sampling Forms Groundwater Statistical Analysis Report Montgomery County Landfill, North Carolina 1 1.0 INTRODUCTION On behalf of Montgomery County Landfill, Jett Environmental Consulting statistically evaluated the Second Semi-Annual 2017 water quality monitoring data. Sampling and analytical testing was performed by Pace Analytical Services, LLC. The statistical analysis software package utilized, SanitasTM, follows a documented decision logic that incorporates the following applicable document: USEPA “Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance” (March 2009). 2.0 SITE BACKGROUND AND MONITORING NETWORK The Montgomery County Landfill is a closed municipal solid waste facility. Per the site’s Permit (No. 62- 01) and in compliance with North Carolina Department of Environmental Quality (NCDEQ) Solid Waste Management Regulations, Section .1600 “Requirements for Municipal Solid Waste Landfill Facilities,” Jett Environmental Consulting statistically evaluated parameters from the Second Semi-Annual (June 26) 2017 event using intra-well prediction interval analysis. Prediction intervals are considered a powerful tool for groundwater statistical analysis, when feasible, due to their inherent low false negative and false positive rates utilizing confirmatory resampling, if necessary. Groundwater monitoring was initiated in January 1994. The historical statistical database is complete dating back to at least January 2007. Background is defined as samples collected from each respective well from January 2007 through the July 2014 event. Background data will be reviewed every year or two to determine if an update is warranted. The parameters subject to statistical evaluation during detection monitoring are noted in NCDEQ Section .1633 as constituents listed in Appendix I of 40 CFR Part 258 “Appendix I Constituents for Detection Monitoring”. Table 1 lists the site’s groundwater monitoring wells. Each of the wells was sampled during the June 2017 event. In correspondence dated January 28, 2016, NCDEQ approved a request to remove mercury from the list of required analysis due to the lack of NC 2L Groundwater Standard exceedances. Therefore, mercury was not sampled/analyzed during the June 2017 event. In addition to the groundwater monitoring, the site has a surface water monitoring network consisting of one upstream surface water sampling point (SW-1) and one downstream point (SW-2). These points are sampled semi-annually for the 40 CFR Part 258 Appendix I list in conjunction with the groundwater monitoring wells. During the June 2017 event, both surface water monitoring points were able to be sampled. Based on the results of statistical evaluations of the groundwater monitoring data, an Alternate Source Demonstration (ASD) was submitted to the NCDEQ in February 1997 in response to confirmed statistically significant detections of mercury and 1,1-dichloroethane at monitoring well MW-4. The ASD attributed the low mercury concentrations detected at MW-4 to natural variability in the geologic medium at the facility, and the 1,1-dichloroethane concentrations reported at MW-4 to sampling and/or analysis error. The ASD was approved by NCDEQ in a letter dated May 22, 1997. A second ASD was submitted to NCDEQ on January 30, 2003, in response to detections of benzene and trichloroethene at MW-2 during the October 2002 event. In a letter dated February 13, 2003 NCDEQ requested that an Assessment Monitoring Program be implemented at the Montgomery County Landfill. Assessment Monitoring, as outlined in NCAC Title 15A 13B.1634, was implemented on March 19, 2003. Laboratory analytical results from the initial Appendix II sampling event indicated that there were no new Appendix II detections for the facility. In general, the detected organic constituents and concentrations were consistent with a landfill gas source. In response to comments from NCDEQ concerning the January 30, 2003 ASD, an addendum to the January 2003 ASD was submitted to NCDEQ in August 2003. Based on analysis of water quality, leachate indicator parameters, and isotopic analyses, the addendum concluded that the volatile organic compounds (VOCs) Groundwater Statistical Analysis Report Montgomery County Landfill, North Carolina 2 detected in the uppermost aquifer beneath the facility did not appear to have originated from a leachate release at the closed landfill. In a letter dated October 25, 2006 from NCDEQ, the ASD and addendum were not approved since recent detected organic constituents were different from those prior to the ASD. A third ASD was submitted on December 5, 2007 to address the detections of the following VOCs: benzene; 1,4-dichlorobenzene; chlorobenzene; 1,2-dichlorobenzene; 1,1-dichloroethane; cis-1,2-dichloroethene; methylene chloride; tetrachloroethene; toluene; trichloroethene; and vinyl chloride, in background well MW- 1R and downgradient wells MW-2 and MW-4. The ASD, which attributed the VOC detections to landfill gas-to-groundwater impacts, was approved by NCDEQ on January 28, 2008, and permitted the facility to revert to the Detection Monitoring Program. The number of VOC detections and the VOC concentrations have declined in more recent years. 3.0 SITE HYDROGEOLOGY The following site hydrogeology summary was taken from the Second Semi-Annual Water Quality Monitoring Report of 2012, dated September 2012 by Joyce Engineering. The uppermost groundwater beneath the facility is present in a shallow, unconfined aquifer comprised of partially weathered, fractured, meta-volcanic rock. Groundwater occurs at depths of approximately 40 feet below grade along the northern upgradient side of the waste disposal area, and at a depth of less than 10 feet below grade along the perimeter downgradient boundary. The groundwater flow in the uppermost aquifer beneath the site is towards the southwest, with the flow appearing to converge on the southerly flowing tributary of Rocky Creek located west of the waste areas. Appendix A provides a potentiometric surface map for the site utilizing groundwater level data from the June 2017 event. Groundwater flow direction for the June 2017 event was to the southwest, consistent with past events. Groundwater flow rate for the June 2017 event was estimated at 36 feet/year, consistent with past events. Flow rate calculations are available in Appendix A. 4.0 DATA EVALUATION The analytical results for the June 2017 event for the groundwater and surface water samples are summarized on Table 2. As presented in Table 2, four Appendix I inorganic constituents were detected in groundwater samples at quantified concentrations above the detection limits specified in the NC Solid Waste Section Reporting Limits (SWSLs): Barium: MW-1R, MW-3, and MW-4; Cobalt: MW-3 and MW-4; Copper: MW-3; and Zinc: MW-3 and MW-4. Three Appendix I VOCs were detected during the June 2017 sampling event: 1,4-dichlorobenzene and benzene at MW-4, and trichloroethylene at MW-2. The VOC constituents and concentrations are consistent with historical data, and likely related to landfill gas as presented in the ASD approved by NCDEQ on January 28, 2008. As shown on Table 2, only benzene at MW-4 exceeded a NC 2L Standard. Benzene at MW-4 (1.8 ug/L) was slightly above the 2L Standard (1 ug/L) and below the National Primary Drinking Water Standard Maximum Contaminant Level (MCL) of 5 ug/L. Consistent with past events, four Appendix I results (barium, cobalt, and benzene at MW-4; and cobalt at MW-3) were detected above a NC Solid Waste Section Groundwater Protection Standard (NC GWPS) or Groundwater Statistical Analysis Report Montgomery County Landfill, North Carolina 3 NC 2L Standard during the June 2017 sampling event. The benzene detected at MW-4 is believed to be attributed to landfill gas as described in the ASD approved by NCDEQ on January 28, 2008. No NC 2B Surface Water Standards were exceeded for surface water samples collected during the Second Semi-Annual 2017 event. 5.0 STATISTICAL PROCEDURES As noted in Section 4.0, during the June 2017 event, barium at MW-4 was detected above the NC 2L Standard and cobalt at MW-3 and MW-4 was detected above the NC GWPS, which is consistent with past events. Statistical analyses (i.e. intra-well prediction limits) were performed to establish background concentrations and determine if barium at MW-4 and cobalt at MW-3 and MW-4 exhibited statistically significant increases above background. 5.1 Outlier Analysis The background data were evaluated for the presence of statistical outliers. Methodologies for determining a statistical outlier are defined in the EPA document, Statistical Analysis of Ground-Water Monitoring Data at RCRA Facilities – Unified Guidance (March 2009). Any statistical outliers that were determined were removed from the background data set prior to performing prediction interval statistical analysis. According to the EPA guidance documents above, data that are not normally or log-normally distributed are not recommended for evaluation of outliers. In cases where the data were not normally or log-normally distributed, outliers were not removed from the data set. Background outliers flagged for removal are identified on the statistical plots provided in Appendix B. 5.2 Intra-Well Prediction Intervals The prediction interval is a statistical method used to compare a single observation to a group of observations. The prediction interval is calculated to include observations from the same population with a specified confidence. In groundwater monitoring, a prediction interval approach may be used to make comparisons between background and compliance data. The interval is developed to contain all future observations, within a certain probability. For the site, intra-well prediction intervals have been developed based on a 99% confidence that future observations will fall within the range. If any future observation exceeds the prediction interval, this is considered statistically significant evidence that the observation is not representative of the background group. During parametric prediction interval analysis, the mean and the standard deviation are calculated for the raw or transformed background data. The number of comparison observations, K, is defined to be included in the interval. If less than 15% of the background observations are nondetects, the nondetects are replaced with one half of the reporting limit prior to performing the analysis. If more than 15% but less than 50% of the background data are below the reporting limit, the data’s sample mean and standard deviation are adjusted according to the Kaplan-Meier method. However, when the background data are not transformed- normal or contain greater than 50% observations below the reporting limit, SanitasTM automatically constructs a non-parametric prediction interval. During non-parametric analysis, the highest value from the background data is used to set the upper limit of the prediction interval. Summary tables and graphs for the intra-well prediction interval analysis are available in Appendix B. The statistical results are discussed in Section 5.3. Included in Appendix B are time series plots for each of the inorganic constituents and organic detections. Appendix C contains a copy of the laboratory analytical report and field sampling forms for the June 2017 event. 5.3 Statistical Results Summary For the June 2017 event, two inorganic statistically significant increases above background were exhibited for the groundwater monitoring wells: barium at MW-4 and cobalt at MW-3. The June 2017 barium Groundwater Statistical Analysis Report Montgomery County Landfill, North Carolina 4 concentration (857 ug/L) at MW-4 was above the statistical limit (830 ug/L) and above the 2L Standard (700 ug/L), however was well below the MCL of 2,000 ug/L. The June 2017 cobalt concentration (26.2 ug/L) at MW-3 was above the statistical limit (12 ug/L) and above the NC GWPS (1 ug/L). Cobalt does not have an established MCL. As shown on the time series graph (see Appendix B), barium concentrations at MW-4 trend to follow seasonal fluctuations, with concentrations higher during the January events and lower during the July events. The June 2017 cobalt concentration at MW-3 was higher than typically reported for this well, however was still below average concentrations of cobalt at MW-4. On September 26, 2017, well MW-3 was resampled for total cobalt. The September 2017 resampling result for total cobalt at MW-3 (13.9 ug/L) was much lower than the June 2017 result (26.2 ug/L), but was still slightly above the statistical limit (12 ug/L) and above the NC GWPS (1 ug/L). The September 2017 concentration of total cobalt at MW-3 was consistent with the historical range of detections at MW-3 (10 to 18.1 ug/L). Cobalt at MW-3 has been reported at stable concentrations and does not exhibit an upward trend. 6.0 CONCLUSIONS During the June 2017 event, barium at MW-4 was detected above the NC 2L Standard and cobalt at MW- 3 and MW-4 was detected above the NC GWPS, which is consistent with past events. Statistical analyses (i.e. intra-well prediction limits) were performed to establish background concentrations and determine if barium at MW-4 and cobalt at MW-3 and MW-4 exhibited statistically significant increases above background. For the June 2017 groundwater monitoring event, two inorganic concentrations exhibited a statistically significant increase above background concentrations: barium at MW-4 and cobalt at MW-3. The June 2017 barium concentration at MW-4 was well below the MCL. The barium concentrations at MW-4 have been reported at stable levels over the last six years of monitoring. Cobalt does not have an established MCL, and though the June 2017 cobalt concentration at MW-3 was higher than typically reported for this well, was still below average concentrations of cobalt at MW-4. On September 26, 2017, well MW-3 was resampled for total cobalt. The September 2017 resampling result for total cobalt at MW-3 was much lower than the June 2017 result, but was still slightly above the statistical limit and above the NC GWPS. The September 2017 concentration of total cobalt at MW-3 was consistent with the historical range of detections at MW-3. Cobalt at MW-3 has been reported at stable concentrations and does not exhibit an upward trend. Three Appendix I VOCs were detected during the June 2017 sampling event: 1,4-dichlorobenzene and benzene at MW-4, and trichloroethylene at MW-2. The VOC constituents and concentrations are consistent with historical data, and likely related to landfill gas as presented in the ASD approved by NCDEQ on January 28, 2008. As shown on Table 2, only benzene at MW-4 exceeded a NC 2L Standard. Benzene at MW-4 (1.8 ug/L) was slightly above the 2L Standard (1 ug/L) and below the National Primary Drinking Water Standard Maximum Contaminant Level (MCL) of 5 ug/L. As shown on the attached time series plots (Appendix B), the June 2017 VOC concentrations at MW-4 are consistent with concentrations reported historically. No NC 2B Surface Water Standards were exceeded for surface water during the Second Semi-Annual 2017 event. It is recommended that the Montgomery County Landfill continue monitoring in accordance with the requirements for Detection Monitoring as outlined in Title 15A NCAC 13B .1633. The next event is tentatively scheduled for January 2018. TABLES UPGRADIENT WELL DOWNGRADIENT WELLS MW-1R MW-2, MW-3, MW-4 TABLE 1 MONTGOMERY COUNTY LANDFILL GROUNDWATER MONITORING PROGRAM SECOND SEMI-ANNUAL 2017 EVENT Constituent Units NC 2L Standard NC GWPS MDL SWSL MW-1R MW-2 MW-3 MW-4 Antimony, Total ug/L NE 1 0.6 6 <6.00 <6.00 <6.00 <6.00 Arsenic, Total ug/L 10 NE 0.52 10 J 3.81 J 0.74 J 3.87 J 4.77 Barium, Total ug/L 700 NE 0.42 100 173 J 50.2 186 857 Beryllium, Total ug/L NE 4 0.09 1 <1.00 J 0.21 J 0.35 <1.00 Cadmium, Total ug/L 2NE0.14 1 <1.00 <1.00 J 0.38 J 0.23 Chromium, Total ug/L 10 NE 0.45 10 J 1.67 J 1.25 J 3.33 <10.0 Cobalt, Total ug/L NE 1 0.26 10 J 0.54 J 0.68 26.2 / 13.9 28.9 Copper, Total ug/L 1,000 NE 0.27 10 J 2.3 J 0.79 12.2 J 0.39 Dissolved Oxygen (Field) ug/L NE NE NE NE 2480 1450 1460 1470 Lead, Total ug/L 15 NE 0.07 10 J 0.67 J 1.5 J 9.34 <10.0 Nickel, Total ug/L 100 NE 0.49 50 J 2.31 J 0.91 J 5.93 J 7.26 pH (Field) su NE NE NE NE 5.74 3.75 4.62 5.18 Redox (Field) mV NE NE NE NE 16 186 82 30 Selenium, Total ug/L 20 NE 1.76 10 J 2.76 <10.0 J 3.28 <10.0 Silver, Total ug/L 20 NE 0.23 10 <10.0 <10.0 J 3.38 J 0.54 Specific Conductance (Field) umhos/cm NE NE 1 1 230 67 209 598 Temperature (Field) Deg-C NE NE NE NE 21.6 18.2 19.1 17.4 Thallium, Total ug/L NE 0.28 0.05 5.5 J 0.17 <5.50 J 0.07 J 0.15 Turbidity (Field) NTU NE NE NE NE 0.28 35 5.99 4.62 Vanadium, Total ug/L NE 0.3 1.2 25 J 2.58 <25.0 J 2.97 <25.0 Zinc, Total ug/L 1,000 NE 1.2 10 J 8.54 J 6.45 29.8 25.3 Constituent (ug/L) Units NC 2L Standard NC GWPS MDL SWSL MW-1R MW-2 MW-3 MW-4 1,1-Dichloroethane ug/L 6NE0.4 5 <5.0 J 1.8 <5.0 J 0.7 1,4-Dichlorobenzene ug/L 6NE0.6 1 <1.0 <1.0 <1.0 3 Benzene ug/L 1NE0.2 1 <1.0 <1.0 J 0.5 1.8 Chlorobenzene ug/L 50 NE 0.5 3 <3.0 <3.0 <3.0 J 1.5 cis-1,2-Dichloroethene ug/L 70 NE 0.7 5 J 2.8 J 4 <5.0 J 3.4 Methylene Chloride ug/L 5NE0.5 1 <1.0 <1.0 J 0.6 J 0.5 Trichloroethylene ug/L 3NE0.3 1 <1.0 2.3 <1.0 <1.0 Constituent (ug/L) Units NC 2B Standard MDL SWSL SW-1 SW-2 Antimony, Total ug/L NE 0.6 6 <6.00 <6.00 Arsenic, Total ug/L 10 0.52 10 J 4.06 J 1.2 Barium, Total ug/L 1,000 0.42 100 164 J 69.2 Beryllium, Total ug/L 6.5 0.09 1 <1.00 <1.00 Cadmium, Total ug/L 2 0.14 1 <1.00 <1.00 Chromium, Total ug/L 20 0.45 10 J 0.59 J 0.58 Cobalt, Total ug/L NE 0.26 10 25.5 J 4.57 Copper, Total ug/L 3 0.27 10 J 0.41 J 1.02 Dissolved Oxygen (Field) ug/L NE NE NE 3760 2480 Lead, Total ug/L 25 0.07 10 J 0.59 J 0.67 Nickel, Total ug/L 8 0.49 50 J 2.8 J 1.47 pH (Field) su NE NE NE 4.79 4.99 Redox (Field) mV NE NE NE 58 58 Selenium, Total ug/L 5 1.76 10 <10.0 <10.0 Silver, Total ug/L 0.06 0.23 10 <10.0 <10.0 Specific Conductance (Field) umhos/cm NE 1 1 111 76 Temperature (Field) Deg-C NE NE NE 20.7 21.2 Thallium, Total ug/L NE 0.05 5.5 J 0.08 <5.50 Turbidity (Field) NTU NE NE NE 4.29 12 Vanadium, Total ug/L NE 1.2 25 <25.0 <25.0 Zinc, Total ug/L 50 1.2 10 J 4.23 J 3.2 Constituent (ug/L) Units NC 2B Standard MDL SWSL SW-1 SW-2 Methylene Chloride ug/L 4.6 0.5 1 J 0.5 <1.0 Toluene ug/L 11 0.3 1 <1.0 J 0.5 NE: Denotes a NC 2L Standard, NC 2B Standard, or NC GWPS is not established. J: Denotes Sample result above the MDL but below the SWSL; estimated value; value may not be accurate. For VOCs, only the VOCs detected during this event are displayed on the table. Denotes result above an SWSL, and NC 2L, NC 2B, or NC GWPS: Cobalt at MW-3 resampled in September 2017, with resampling result provided to right of original result. TABLE 2 ANALYTICAL DATA SUMMARY, SECOND SEMI-ANNUAL 2017 EVENT MONTGOMERY COUNTY LANDFILL GROUNDWATER SAMPLES SURFACE WATER SAMPLES APPENDICES APPENDIX A POTENTIOMETRIC SURFACE MAP Well Top of PVC Casing Elevation (fmsl)1 Depth to Water (ft)2 Groundwater Elevation (fmsl) MW-1R 695.65 40.89 654.76 MW-2 643.46 7.14 636.32 MW-3 622.94 7.15 615.79 MW-4 609.59 4.68 604.91 Note 1: Top of PVC Casing Elevations from Table 3 of the Second Semi-Annual Water Quality Monitoring Report of 2012, dated September 2012 by Joyce Engineering. Note 2: Depth to water measured by Pace Analytical Services, LLC. on June 26, 2017. Groundwater Elevation Summary Table Montgomery County Landfill Groundwater Flow Velocity Calculations Montgomery County Landfill Second Semi-Annual 2017 Event Velocity V = [(k)(i)]/(n) V = [(0.441 ft/day)(0.0278 ft/ft]/0.125 V = 0.098 ft/day V = 36 ft/year Hydraulic conductivity and effective porosity values from the following document: Second Semi-Annual Water Quality Monitoring Report of 2012, Montgomery County Landfill. Dated August 20, 2012 by Joyce Engineering. Gradient (i) is from the average gradient at site using the potentiometric surface map from Point A to Point B. Gradient (i) = Change in Groundwater Elevation along Flow Path i: From Point A (650 contour) to Point B (610 contour) = 40 ft / 1,440 ft = 0.0278 ft/ft APPENDIX B STATISTICAL EVALUATIONS ConstituentWellUpper Lim.Lower Lim.DateObserv.Sig.Bg NBg MeanStd. Dev.%NDsND Adj.TransformAlphaMethodBarium Total (ug/L) MW-4 830 n/a 6/26/2017 857 Yes 16 367837 225409 0 Nonex^2 0.01308 Param Intra 1 of 2Cobalt Total (ug/L) MW-4 46 n/a 6/26/2017 28.9 No 16 26.36 14.09 0 None No 0.01308 Param Intra 1 of 2Cobalt Total (ug/L) MW-3 12 n/a 6/26/2017 26.2 Yes 16 1.454 0.7354 25 Kaplan-Meier ln(x) 0.01308 Param Intra 1 of 2Prediction LimitMontgomery County LF Client: RSI Data: MontgomeryCounty Printed 9/5/2017, 3:18 PM 01803605407209001/10/072/12/093/18/114/20/135/24/156/26/17MW-4 backgroundMW-4 complianceLimit = 830Prediction LimitIntrawell ParametricConstituent: Barium Total Analysis Run 9/5/2017 3:20 PMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LBackground Data Summary (based on square transformation): Mean=367837, Std. Dev.=225409, n=16. Normality test: Shapiro Wilk @alpha = 0.05, calculated = 0.9336, critical = 0.887. Kappa = 1.39 (c=2, w=2, 1 of 2, event alpha = 0.05132). Report alpha = 0.01308. EPA 1989 outlier screening was performed on the background data. No background outliers were found.Exceeds Limit 010203040501/10/072/12/093/18/114/20/135/24/156/26/17MW-4 backgroundMW-4 complianceLimit = 46Prediction LimitIntrawell ParametricConstituent: Cobalt Total Analysis Run 9/5/2017 3:20 PMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LBackground Data Summary: Mean=26.36, Std. Dev.=14.09, n=16. Normality test: Shapiro Wilk @alpha = 0.05, calculated = 0.8927, critical = 0.887. Kappa = 1.39 (c=2, w=2, 1 of 2, event alpha = 0.05132). Report alpha = 0.01308. EPA 1989 outlier screening was performed on the background data. No background outliers were found.Within Limit 06121824301/10/072/12/093/18/114/20/135/24/156/26/17MW-3 backgroundMW-3 complianceLimit = 12Prediction LimitIntrawell ParametricConstituent: Cobalt Total Analysis Run 9/5/2017 3:18 PMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values.Background Data Summary (based on natural log transformation) (after Kaplan-Meier Adjustment): Mean=1.454, Std. Dev.=0.7354, n=16, 25% NDs. Normality test: Shapiro Wilk @alpha = 0.05, calculated = 0.934, critical = 0.887. Kappa = 1.39 (c=2, w=2, 1 of 2, event alpha = 0.05132). Report alpha = 0.01308. EPA 1989 outlier screening was performed on the background data. No background outliers were found.Exceeds Limit TIME SERIES TREND ANALYSIS 01.22.43.64.861/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Antimony Total Analysis Run 9/6/2017 8:49 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 0481216201/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Arsenic Total Analysis Run 9/6/2017 8:49 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 020040060080010001/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Barium Total Analysis Run 9/6/2017 8:49 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/L 00.20.40.60.811/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Beryllium Total Analysis Run 9/6/2017 8:49 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 00.61.21.82.431/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Cadmium Total Analysis Run 9/6/2017 8:49 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 02468101/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Chromium Total Analysis Run 9/6/2017 8:49 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 010203040501/10/073/2/094/23/116/14/138/5/159/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Cobalt Total Analysis Run 10/9/2017 3:59 PMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 010203040501/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Copper Total Analysis Run 9/6/2017 8:49 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 0481216201/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Lead Total Analysis Run 9/6/2017 8:49 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 010203040501/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Nickel Total Analysis Run 9/6/2017 8:49 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 02468101/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Selenium Total Analysis Run 9/6/2017 8:49 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 02468101/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Silver Total Analysis Run 9/6/2017 8:49 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 01.22.43.64.861/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Thallium Total Analysis Run 9/6/2017 8:49 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 06121824301/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Vanadium Total Analysis Run 9/6/2017 8:49 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 040801201602001/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Zinc Total Analysis Run 9/6/2017 8:49 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 01.63.24.86.481/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: 11-Dichloroethane Analysis Run 9/6/2017 8:57 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 00.81.62.43.241/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: 14-Dichlorobenzene Analysis Run 9/6/2017 8:57 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 01.22.43.64.861/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Benzene Analysis Run 9/6/2017 8:57 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 00.61.21.82.431/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Chlorobenzene Analysis Run 9/6/2017 8:57 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 0481216201/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: cis-12-Dichloroethylene Analysis Run 9/6/2017 8:57 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 00.61.21.82.431/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Methylene chloride Analysis Run 9/6/2017 8:57 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 00.81.62.43.241/10/072/12/093/18/114/20/135/24/156/26/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Trichloroethylene Analysis Run 9/6/2017 8:57 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.32 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. APPENDIX C LABORATORY ANALYTICAL REPORT & FIELD SAMPLING FORMS PACE ANALYTICAL SERVICES, LLC.Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201BFI Waste Systems of North America, LLCProject: Montgomery County LandfillConcord, NC 280275105 Morehead Rd.Mr. Mike GurleyWe appreciate the opportunity to provide the analytical support for your project. The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Pace Analytical Services, LLC. certifies that the following analytical results meet all requirements of the National Environmental Laboratory Accreditation Conference(NELAC).All test results relate only to the samples analyzed.Laboratory ReportProject #:[none]Prepared For:Attention:July 12, 2017Report Number:AAF1022Approved:This report may not be reproduced, except in full, without written approval from Pace Analytical Services, LLC.Page 1 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017Sample IDLaboratory IDMatrixDate SampledANALYTICAL REPORT FOR SAMPLESDate Received6201-MW1RAAF1022-0106/26/17 15:51 06/28/17 16:10Ground Water6201-MW2AAF1022-0206/26/17 13:02 06/28/17 16:10Ground Water6201-MW3AAF1022-0306/26/17 13:29 06/28/17 16:10Ground Water6201-MW4AAF1022-0406/26/17 14:17 06/28/17 16:10Ground Water6201-SW1AAF1022-0506/26/17 13:40 06/28/17 16:10Surface Water6201-SW2AAF1022-0606/26/17 13:58 06/28/17 16:10Surface Water6201-Field BlankAAF1022-0706/26/17 13:32 06/28/17 16:10Water6201-Trip BlankAAF1022-0806/26/17 00:00 06/28/17 16:10Water6201-DuplicateAAF1022-0906/26/17 00:00 06/28/17 16:10Ground WaterPage 2 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW1RGround WaterAAF1022-01AAF102206/26/17 15:51Project:Montgomery County Landfill06/28/17 16:10On SiteEPA 9050A230umhos/cm1Field - Specific Conductance17060971NA1COND06/26/17 15:5106/26/17 15:51SM 4500-O G2480ug/L1Dissolved Oxygen0.07060971NA0.0NA06/26/17 15:5106/26/17 15:51EPA 9040C5.74pH Units1Field - pH7060971NAPH06/26/17 15:5106/26/17 15:51NA16mV1Field - Redox7060971NAREDOX06/26/17 15:5106/26/17 15:51SM 2550 B21.6C1Field - Temperature7060971NATEMP06/26/17 15:5106/26/17 15:51EPA 180.10.28NTU1Field - Turbidity7060971NATURB06/26/17 15:5106/26/17 15:51NA40.89feet1Field - Water Level7060971NAWL06/26/17 15:5106/26/17 15:51Metals, TotalNDEPA 6020Bug/L1Antimony6.007060901EPA 3005A0.607440-36-006/29/17 18:3006/29/17 12:00EPA 6020B3.81ug/L1Arsenic10.0J7060901EPA 3005A0.527440-38-206/29/17 18:3006/29/17 12:00EPA 6020B173ug/L1Barium1007060901EPA 3005A0.427440-39-307/07/17 09:5806/29/17 12:00NDEPA 6020Bug/L1Beryllium1.007060901EPA 3005A0.097440-41-706/29/17 18:3006/29/17 12:00NDEPA 6020Bug/L1Cadmium1.007060901EPA 3005A0.147440-43-906/29/17 18:3006/29/17 12:00EPA 6020B1.67ug/L1Chromium10.0J7060901EPA 3005A0.457440-47-306/29/17 18:3006/29/17 12:00EPA 6020B0.54ug/L1Cobalt10.0J7060901EPA 3005A0.267440-48-406/29/17 18:3006/29/17 12:00EPA 6020B2.30ug/L1Copper10.0J7060901EPA 3005A0.277440-50-806/29/17 18:3006/29/17 12:00EPA 6020B0.67ug/L1Lead10.0J7060901EPA 3005A0.077439-92-106/29/17 18:3006/29/17 12:00EPA 6020B2.31ug/L1Nickel50.0J7060901EPA 3005A0.497440-02-006/29/17 18:3006/29/17 12:00EPA 6020B2.76ug/L1Selenium10.0J7060901EPA 3005A1.767782-49-206/29/17 18:3006/29/17 12:00NDEPA 6020Bug/L1Silver10.07060901EPA 3005A0.237440-22-406/29/17 18:3006/29/17 12:00Page 3 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW1RGround WaterAAF1022-01AAF102206/26/17 15:51Project:Montgomery County Landfill06/28/17 16:10Metals, TotalEPA 6020B0.17ug/L1Thallium5.50J7060901EPA 3005A0.057440-28-006/29/17 18:3006/29/17 12:00EPA 6020B2.58ug/L1Vanadium25.0J7060901EPA 3005A1.207440-62-206/29/17 18:3006/29/17 12:00EPA 6020B8.54ug/L1Zinc10.0J7060901EPA 3005A1.207440-66-606/29/17 18:3006/29/17 12:00Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007070015EPA 5030B8.267-64-106/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Acrylonitrile2007070015EPA 5030B2.5107-13-106/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Benzene1.07070015EPA 5030B0.271-43-206/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Bromochloromethane3.07070015EPA 5030B0.574-97-506/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Bromodichloromethane1.07070015EPA 5030B0.475-27-406/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Bromoform3.07070015EPA 5030B0.675-25-206/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Bromomethane107070015EPA 5030B1.074-83-906/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Carbon Disulfide1007070015EPA 5030B0.875-15-006/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Carbon Tetrachloride1.07070015EPA 5030B0.456-23-506/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Chlorobenzene3.07070015EPA 5030B0.5108-90-706/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Chloroethane107070015EPA 5030B0.575-00-306/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Chloroform5.07070015EPA 5030B0.667-66-306/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Chloromethane1.07070015EPA 5030B0.474-87-306/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Dibromochloromethane3.07070015EPA 5030B0.3124-48-106/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137070015EPA 5030B0.696-12-806/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L11,2-Dibromoethane1.07070015EPA 5030B0.3106-93-406/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Dibromomethane107070015EPA 5030B0.674-95-306/30/17 10:1606/30/17 09:01Page 4 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW1RGround WaterAAF1022-01AAF102206/26/17 15:51Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichlorobenzene5.07070015EPA 5030B0.595-50-106/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L11,4-Dichlorobenzene1.07070015EPA 5030B0.6106-46-706/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007070015EPA 5030B1.6110-57-606/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L11,1-Dichloroethane5.07070015EPA 5030B0.475-34-306/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L11,2-Dichloroethane1.07070015EPA 5030B0.7107-06-206/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L11,1-Dichloroethene5.07070015EPA 5030B0.775-35-406/30/17 10:1606/30/17 09:01EPA 8260B2.8ug/L1cis-1,2-Dichloroethene5.0J7070015EPA 5030B0.7156-59-206/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07070015EPA 5030B0.5156-60-506/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L11,2-Dichloropropane1.07070015EPA 5030B0.678-87-506/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07070015EPA 5030B0.210061-01-506/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07070015EPA 5030B0.310061-02-606/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Ethylbenzene1.07070015EPA 5030B0.4100-41-406/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Iodomethane107070015EPA 5030B3.174-88-406/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507070015EPA 5030B0.9591-78-606/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Methylene Chloride1.07070015EPA 5030B0.575-09-206/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007070015EPA 5030B3.278-93-306/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007070015EPA 5030B0.9108-10-106/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Styrene1.07070015EPA 5030B0.5100-42-506/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07070015EPA 5030B0.3630-20-606/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07070015EPA 5030B0.579-34-506/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Tetrachloroethene1.07070015EPA 5030B0.8127-18-406/30/17 10:1606/30/17 09:01Page 5 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW1RGround WaterAAF1022-01AAF102206/26/17 15:51Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Toluene1.07070015EPA 5030B0.3108-88-306/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L11,1,1-Trichloroethane1.07070015EPA 5030B0.471-55-606/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L11,1,2-Trichloroethane1.07070015EPA 5030B0.679-00-506/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Trichloroethene1.07070015EPA 5030B0.379-01-606/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Trichlorofluoromethane1.07070015EPA 5030B0.575-69-406/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L11,2,3-Trichloropropane1.07070015EPA 5030B0.596-18-406/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Vinyl Acetate507070015EPA 5030B0.4108-05-406/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Vinyl Chloride1.07070015EPA 5030B0.675-01-406/30/17 10:1606/30/17 09:01NDEPA 8260Bug/L1Xylenes, total5.07070015EPA 5030B0.91330-20-706/30/17 10:1606/30/17 09:01EPA 8260B99 %Surr: Dibromofluoromethane7070015EPA 5030B1868-53-706/30/17 10:1606/30/17 09:0180-120EPA 8260B100 %Surr: 1,2-Dichloroethane-d47070015EPA 5030B17060-07-006/30/17 10:1606/30/17 09:0178-120EPA 8260B98 %Surr: Toluene-d87070015EPA 5030B2037-26-506/30/17 10:1606/30/17 09:0180-120EPA 8260B104 %Surr: 4-Bromofluorobenzene7070015EPA 5030B460-00-406/30/17 10:1606/30/17 09:0180-120Page 6 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW2Ground WaterAAF1022-02AAF102206/26/17 13:02Project:Montgomery County Landfill06/28/17 16:10On SiteEPA 9050A67umhos/cm1Field - Specific Conductance17060971NA1COND06/26/17 13:0206/26/17 13:02SM 4500-O G1450ug/L1Dissolved Oxygen0.07060971NA0.0NA06/26/17 13:0206/26/17 13:02EPA 9040C3.75pH Units1Field - pH7060971NAPH06/26/17 13:0206/26/17 13:02NA186mV1Field - Redox7060971NAREDOX06/26/17 13:0206/26/17 13:02SM 2550 B18.2C1Field - Temperature7060971NATEMP06/26/17 13:0206/26/17 13:02EPA 180.135.0NTU1Field - Turbidity7060971NATURB06/26/17 13:0206/26/17 13:02NA7.14feet1Field - Water Level7060971NAWL06/26/17 13:0206/26/17 13:02Metals, TotalNDEPA 6020Bug/L1Antimony6.007060901EPA 3005A0.607440-36-006/29/17 18:3506/29/17 12:00EPA 6020B0.74ug/L1Arsenic10.0J7060901EPA 3005A0.527440-38-206/29/17 18:3506/29/17 12:00EPA 6020B50.2ug/L1Barium100J7060901EPA 3005A0.427440-39-306/29/17 18:3506/29/17 12:00EPA 6020B0.21ug/L1Beryllium1.00J7060901EPA 3005A0.097440-41-706/29/17 18:3506/29/17 12:00NDEPA 6020Bug/L1Cadmium1.007060901EPA 3005A0.147440-43-906/29/17 18:3506/29/17 12:00EPA 6020B1.25ug/L1Chromium10.0J7060901EPA 3005A0.457440-47-306/29/17 18:3506/29/17 12:00EPA 6020B0.68ug/L1Cobalt10.0J7060901EPA 3005A0.267440-48-406/29/17 18:3506/29/17 12:00EPA 6020B0.79ug/L1Copper10.0J7060901EPA 3005A0.277440-50-806/29/17 18:3506/29/17 12:00EPA 6020B1.50ug/L1Lead10.0J7060901EPA 3005A0.077439-92-106/29/17 18:3506/29/17 12:00EPA 6020B0.91ug/L1Nickel50.0J7060901EPA 3005A0.497440-02-006/29/17 18:3506/29/17 12:00NDEPA 6020Bug/L1Selenium10.07060901EPA 3005A1.767782-49-206/29/17 18:3506/29/17 12:00NDEPA 6020Bug/L1Silver10.07060901EPA 3005A0.237440-22-406/29/17 18:3506/29/17 12:00Page 7 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW2Ground WaterAAF1022-02AAF102206/26/17 13:02Project:Montgomery County Landfill06/28/17 16:10Metals, TotalNDEPA 6020Bug/L1Thallium5.507060901EPA 3005A0.057440-28-006/29/17 18:3506/29/17 12:00NDEPA 6020Bug/L1Vanadium25.07060901EPA 3005A1.207440-62-206/29/17 18:3506/29/17 12:00EPA 6020B6.45ug/L1Zinc10.0J7060901EPA 3005A1.207440-66-606/29/17 18:3506/29/17 12:00Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007060948EPA 5030B8.267-64-106/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Acrylonitrile2007060948EPA 5030B2.5107-13-106/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Benzene1.07060948EPA 5030B0.271-43-206/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Bromochloromethane3.07060948EPA 5030B0.574-97-506/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Bromodichloromethane1.07060948EPA 5030B0.475-27-406/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Bromoform3.07060948EPA 5030B0.675-25-206/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Bromomethane107060948EPA 5030B1.074-83-906/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Carbon Disulfide1007060948EPA 5030B0.875-15-006/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Carbon Tetrachloride1.07060948EPA 5030B0.456-23-506/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Chlorobenzene3.07060948EPA 5030B0.5108-90-706/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Chloroethane107060948EPA 5030B0.575-00-306/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Chloroform5.07060948EPA 5030B0.667-66-306/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Chloromethane1.07060948EPA 5030B0.474-87-306/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Dibromochloromethane3.07060948EPA 5030B0.3124-48-106/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137060948EPA 5030B0.696-12-806/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L11,2-Dibromoethane1.07060948EPA 5030B0.3106-93-406/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Dibromomethane107060948EPA 5030B0.674-95-306/29/17 18:2506/29/17 10:25Page 8 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW2Ground WaterAAF1022-02AAF102206/26/17 13:02Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichlorobenzene5.07060948EPA 5030B0.595-50-106/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L11,4-Dichlorobenzene1.07060948EPA 5030B0.6106-46-706/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007060948EPA 5030B1.6110-57-606/29/17 18:2506/29/17 10:25EPA 8260B1.8ug/L11,1-Dichloroethane5.0J7060948EPA 5030B0.475-34-306/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L11,2-Dichloroethane1.07060948EPA 5030B0.7107-06-206/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L11,1-Dichloroethene5.07060948EPA 5030B0.775-35-406/29/17 18:2506/29/17 10:25EPA 8260B4.0ug/L1cis-1,2-Dichloroethene5.0J7060948EPA 5030B0.7156-59-206/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07060948EPA 5030B0.5156-60-506/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L11,2-Dichloropropane1.07060948EPA 5030B0.678-87-506/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07060948EPA 5030B0.210061-01-506/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07060948EPA 5030B0.310061-02-606/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Ethylbenzene1.07060948EPA 5030B0.4100-41-406/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Iodomethane107060948EPA 5030B3.174-88-406/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507060948EPA 5030B0.9591-78-606/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Methylene Chloride1.07060948EPA 5030B0.575-09-206/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007060948EPA 5030B3.278-93-306/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007060948EPA 5030B0.9108-10-106/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Styrene1.07060948EPA 5030B0.5100-42-506/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07060948EPA 5030B0.3630-20-606/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07060948EPA 5030B0.579-34-506/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Tetrachloroethene1.07060948EPA 5030B0.8127-18-407/03/17 10:1107/03/17 09:00Page 9 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW2Ground WaterAAF1022-02AAF102206/26/17 13:02Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Toluene1.07060948EPA 5030B0.3108-88-306/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L11,1,1-Trichloroethane1.07060948EPA 5030B0.471-55-606/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L11,1,2-Trichloroethane1.07060948EPA 5030B0.679-00-506/29/17 18:2506/29/17 10:25EPA 8260B2.3ug/L1Trichloroethene1.07060948EPA 5030B0.379-01-606/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Trichlorofluoromethane1.07060948EPA 5030B0.575-69-406/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L11,2,3-Trichloropropane1.07060948EPA 5030B0.596-18-406/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Vinyl Acetate507060948EPA 5030B0.4108-05-406/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Vinyl Chloride1.07060948EPA 5030B0.675-01-406/29/17 18:2506/29/17 10:25NDEPA 8260Bug/L1Xylenes, total5.07060948EPA 5030B0.91330-20-706/29/17 18:2506/29/17 10:25EPA 8260B98 %Surr: Dibromofluoromethane7060948EPA 5030B1868-53-706/29/17 18:2506/29/17 10:2580-120EPA 8260B98 %Surr: Dibromofluoromethane7060948EPA 5030B1868-53-707/03/17 10:1107/03/17 09:0080-120EPA 8260B100 %Surr: 1,2-Dichloroethane-d47060948EPA 5030B17060-07-007/03/17 10:1107/03/17 09:0078-120EPA 8260B100 %Surr: 1,2-Dichloroethane-d47060948EPA 5030B17060-07-006/29/17 18:2506/29/17 10:2578-120EPA 8260B98 %Surr: Toluene-d87060948EPA 5030B2037-26-506/29/17 18:2506/29/17 10:2580-120EPA 8260B97 %Surr: Toluene-d87060948EPA 5030B2037-26-507/03/17 10:1107/03/17 09:0080-120EPA 8260B102 %Surr: 4-Bromofluorobenzene7060948EPA 5030B460-00-407/03/17 10:1107/03/17 09:0080-120EPA 8260B104 %Surr: 4-Bromofluorobenzene7060948EPA 5030B460-00-406/29/17 18:2506/29/17 10:2580-120Page 10 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW3Ground WaterAAF1022-03AAF102206/26/17 13:29Project:Montgomery County Landfill06/28/17 16:10On SiteEPA 9050A209umhos/cm1Field - Specific Conductance17060971NA1COND06/26/17 13:2906/26/17 13:29SM 4500-O G1460ug/L1Dissolved Oxygen0.07060971NA0.0NA06/26/17 13:2906/26/17 13:29EPA 9040C4.62pH Units1Field - pH7060971NAPH06/26/17 13:2906/26/17 13:29NA82mV1Field - Redox7060971NAREDOX06/26/17 13:2906/26/17 13:29SM 2550 B19.1C1Field - Temperature7060971NATEMP06/26/17 13:2906/26/17 13:29EPA 180.15.99NTU1Field - Turbidity7060971NATURB06/26/17 13:2906/26/17 13:29NA7.15feet1Field - Water Level7060971NAWL06/26/17 13:2906/26/17 13:29Metals, TotalNDEPA 6020Bug/L1Antimony6.007060901EPA 3005A0.607440-36-006/29/17 18:4106/29/17 12:00EPA 6020B3.87ug/L1Arsenic10.0J7060901EPA 3005A0.527440-38-206/29/17 18:4106/29/17 12:00EPA 6020B186ug/L1Barium1007060901EPA 3005A0.427440-39-307/07/17 10:0406/29/17 12:00EPA 6020B0.35ug/L1Beryllium1.00J7060901EPA 3005A0.097440-41-706/29/17 18:4106/29/17 12:00EPA 6020B0.38ug/L1Cadmium1.00J7060901EPA 3005A0.147440-43-906/29/17 18:4106/29/17 12:00EPA 6020B3.33ug/L1Chromium10.0J7060901EPA 3005A0.457440-47-306/29/17 18:4106/29/17 12:00EPA 6020B26.2ug/L1Cobalt10.07060901EPA 3005A0.267440-48-406/29/17 18:4106/29/17 12:00EPA 6020B12.2ug/L1Copper10.07060901EPA 3005A0.277440-50-806/29/17 18:4106/29/17 12:00EPA 6020B9.34ug/L1Lead10.0J7060901EPA 3005A0.077439-92-106/29/17 18:4106/29/17 12:00EPA 6020B5.93ug/L1Nickel50.0J7060901EPA 3005A0.497440-02-006/29/17 18:4106/29/17 12:00EPA 6020B3.28ug/L1Selenium10.0J7060901EPA 3005A1.767782-49-206/29/17 18:4106/29/17 12:00EPA 6020B3.38ug/L1Silver10.0J7060901EPA 3005A0.237440-22-406/29/17 18:4106/29/17 12:00Page 11 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW3Ground WaterAAF1022-03AAF102206/26/17 13:29Project:Montgomery County Landfill06/28/17 16:10Metals, TotalEPA 6020B0.07ug/L1Thallium5.50J7060901EPA 3005A0.057440-28-006/29/17 18:4106/29/17 12:00EPA 6020B2.97ug/L1Vanadium25.0J7060901EPA 3005A1.207440-62-206/29/17 18:4106/29/17 12:00EPA 6020B29.8ug/L1Zinc10.07060901EPA 3005A1.207440-66-606/29/17 18:4106/29/17 12:00Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007060948EPA 5030B8.267-64-107/03/17 10:3607/03/17 10:00NDEPA 8260Bug/L1Acrylonitrile2007060948EPA 5030B2.5107-13-106/29/17 19:4006/29/17 10:25EPA 8260B0.5ug/L1Benzene1.0J7060948EPA 5030B0.271-43-206/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Bromochloromethane3.07060948EPA 5030B0.574-97-506/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Bromodichloromethane1.07060948EPA 5030B0.475-27-406/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Bromoform3.07060948EPA 5030B0.675-25-206/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Bromomethane107060948EPA 5030B1.074-83-906/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Carbon Disulfide1007060948EPA 5030B0.875-15-006/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Carbon Tetrachloride1.07060948EPA 5030B0.456-23-506/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Chlorobenzene3.07060948EPA 5030B0.5108-90-706/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Chloroethane107060948EPA 5030B0.575-00-306/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Chloroform5.07060948EPA 5030B0.667-66-306/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Chloromethane1.07060948EPA 5030B0.474-87-306/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Dibromochloromethane3.07060948EPA 5030B0.3124-48-106/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137060948EPA 5030B0.696-12-806/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L11,2-Dibromoethane1.07060948EPA 5030B0.3106-93-406/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Dibromomethane107060948EPA 5030B0.674-95-306/29/17 19:4006/29/17 10:25Page 12 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW3Ground WaterAAF1022-03AAF102206/26/17 13:29Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichlorobenzene5.07060948EPA 5030B0.595-50-106/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L11,4-Dichlorobenzene1.07060948EPA 5030B0.6106-46-706/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007060948EPA 5030B1.6110-57-606/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L11,1-Dichloroethane5.07060948EPA 5030B0.475-34-306/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L11,2-Dichloroethane1.07060948EPA 5030B0.7107-06-206/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L11,1-Dichloroethene5.07060948EPA 5030B0.775-35-406/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07060948EPA 5030B0.7156-59-206/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07060948EPA 5030B0.5156-60-506/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L11,2-Dichloropropane1.07060948EPA 5030B0.678-87-506/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07060948EPA 5030B0.210061-01-506/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07060948EPA 5030B0.310061-02-606/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Ethylbenzene1.07060948EPA 5030B0.4100-41-406/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Iodomethane107060948EPA 5030B3.174-88-406/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507060948EPA 5030B0.9591-78-606/29/17 19:4006/29/17 10:25EPA 8260B0.6ug/L1Methylene Chloride1.0J7060948EPA 5030B0.575-09-206/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007060948EPA 5030B3.278-93-306/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007060948EPA 5030B0.9108-10-106/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Styrene1.07060948EPA 5030B0.5100-42-506/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07060948EPA 5030B0.3630-20-606/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07060948EPA 5030B0.579-34-506/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Tetrachloroethene1.07060948EPA 5030B0.8127-18-406/29/17 19:4006/29/17 10:25Page 13 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW3Ground WaterAAF1022-03AAF102206/26/17 13:29Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Toluene1.07060948EPA 5030B0.3108-88-306/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L11,1,1-Trichloroethane1.07060948EPA 5030B0.471-55-606/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L11,1,2-Trichloroethane1.07060948EPA 5030B0.679-00-506/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Trichloroethene1.07060948EPA 5030B0.379-01-606/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Trichlorofluoromethane1.07060948EPA 5030B0.575-69-406/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L11,2,3-Trichloropropane1.07060948EPA 5030B0.596-18-406/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Vinyl Acetate507060948EPA 5030B0.4108-05-406/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Vinyl Chloride1.07060948EPA 5030B0.675-01-406/29/17 19:4006/29/17 10:25NDEPA 8260Bug/L1Xylenes, total5.07060948EPA 5030B0.91330-20-706/29/17 19:4006/29/17 10:25EPA 8260B99 %Surr: Dibromofluoromethane7060948EPA 5030B1868-53-707/03/17 10:3607/03/17 10:0080-120EPA 8260B99 %Surr: Dibromofluoromethane7060948EPA 5030B1868-53-706/29/17 19:4006/29/17 10:2580-120EPA 8260B99 %Surr: 1,2-Dichloroethane-d47060948EPA 5030B17060-07-007/03/17 10:3607/03/17 10:0078-120EPA 8260B101 %Surr: 1,2-Dichloroethane-d47060948EPA 5030B17060-07-006/29/17 19:4006/29/17 10:2578-120EPA 8260B96 %Surr: Toluene-d87060948EPA 5030B2037-26-507/03/17 10:3607/03/17 10:0080-120EPA 8260B98 %Surr: Toluene-d87060948EPA 5030B2037-26-506/29/17 19:4006/29/17 10:2580-120EPA 8260B104 %Surr: 4-Bromofluorobenzene7060948EPA 5030B460-00-407/03/17 10:3607/03/17 10:0080-120EPA 8260B105 %Surr: 4-Bromofluorobenzene7060948EPA 5030B460-00-406/29/17 19:4006/29/17 10:2580-120Page 14 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW4Ground WaterAAF1022-04AAF102206/26/17 14:17Project:Montgomery County Landfill06/28/17 16:10On SiteEPA 9050A598umhos/cm1Field - Specific Conductance17060971NA1COND06/26/17 14:1706/26/17 14:17SM 4500-O G1470ug/L1Dissolved Oxygen0.07060971NA0.0NA06/26/17 14:1706/26/17 14:17EPA 9040C5.18pH Units1Field - pH7060971NAPH06/26/17 14:1706/26/17 14:17NA30mV1Field - Redox7060971NAREDOX06/26/17 14:1706/26/17 14:17SM 2550 B17.4C1Field - Temperature7060971NATEMP06/26/17 14:1706/26/17 14:17EPA 180.14.62NTU1Field - Turbidity7060971NATURB06/26/17 14:1706/26/17 14:17NA4.68feet1Field - Water Level7060971NAWL06/26/17 14:1706/26/17 14:17Metals, TotalNDEPA 6020Bug/L1Antimony6.007060901EPA 3005A0.607440-36-006/29/17 18:4706/29/17 12:00EPA 6020B4.77ug/L1Arsenic10.0J7060901EPA 3005A0.527440-38-206/29/17 18:4706/29/17 12:00EPA 6020B857ug/L5Barium5007060901EPA 3005A2.107440-39-307/07/17 10:1006/29/17 12:00NDEPA 6020Bug/L1Beryllium1.007060901EPA 3005A0.097440-41-706/29/17 18:4706/29/17 12:00EPA 6020B0.23ug/L1Cadmium1.00J7060901EPA 3005A0.147440-43-906/29/17 18:4706/29/17 12:00NDEPA 6020Bug/L1Chromium10.07060901EPA 3005A0.457440-47-306/29/17 18:4706/29/17 12:00EPA 6020B28.9ug/L1Cobalt10.07060901EPA 3005A0.267440-48-406/29/17 18:4706/29/17 12:00EPA 6020B0.39ug/L1Copper10.0J7060901EPA 3005A0.277440-50-806/29/17 18:4706/29/17 12:00NDEPA 6020Bug/L1Lead10.07060901EPA 3005A0.077439-92-106/29/17 18:4706/29/17 12:00EPA 6020B7.26ug/L1Nickel50.0J7060901EPA 3005A0.497440-02-006/29/17 18:4706/29/17 12:00NDEPA 6020Bug/L1Selenium10.07060901EPA 3005A1.767782-49-206/29/17 18:4706/29/17 12:00EPA 6020B0.54ug/L1Silver10.0J7060901EPA 3005A0.237440-22-406/29/17 18:4706/29/17 12:00Page 15 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW4Ground WaterAAF1022-04AAF102206/26/17 14:17Project:Montgomery County Landfill06/28/17 16:10Metals, TotalEPA 6020B0.15ug/L1Thallium5.50J7060901EPA 3005A0.057440-28-006/29/17 18:4706/29/17 12:00NDEPA 6020Bug/L1Vanadium25.07060901EPA 3005A1.207440-62-206/29/17 18:4706/29/17 12:00EPA 6020B25.3ug/L1Zinc10.07060901EPA 3005A1.207440-66-606/29/17 18:4706/29/17 12:00Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007060948EPA 5030B8.267-64-107/03/17 11:0107/03/17 10:00NDEPA 8260Bug/L1Acrylonitrile2007060948EPA 5030B2.5107-13-106/29/17 20:0506/29/17 10:25EPA 8260B1.8ug/L1Benzene1.07060948EPA 5030B0.271-43-206/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Bromochloromethane3.07060948EPA 5030B0.574-97-506/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Bromodichloromethane1.07060948EPA 5030B0.475-27-406/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Bromoform3.07060948EPA 5030B0.675-25-206/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Bromomethane107060948EPA 5030B1.074-83-906/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Carbon Disulfide1007060948EPA 5030B0.875-15-006/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Carbon Tetrachloride1.07060948EPA 5030B0.456-23-506/29/17 20:0506/29/17 10:25EPA 8260B1.5ug/L1Chlorobenzene3.0J7060948EPA 5030B0.5108-90-706/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Chloroethane107060948EPA 5030B0.575-00-306/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Chloroform5.07060948EPA 5030B0.667-66-306/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Chloromethane1.07060948EPA 5030B0.474-87-306/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Dibromochloromethane3.07060948EPA 5030B0.3124-48-106/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137060948EPA 5030B0.696-12-806/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L11,2-Dibromoethane1.07060948EPA 5030B0.3106-93-406/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Dibromomethane107060948EPA 5030B0.674-95-306/29/17 20:0506/29/17 10:25Page 16 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW4Ground WaterAAF1022-04AAF102206/26/17 14:17Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichlorobenzene5.07060948EPA 5030B0.595-50-106/29/17 20:0506/29/17 10:25EPA 8260B3.0ug/L11,4-Dichlorobenzene1.07060948EPA 5030B0.6106-46-706/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007060948EPA 5030B1.6110-57-606/29/17 20:0506/29/17 10:25EPA 8260B0.7ug/L11,1-Dichloroethane5.0J7060948EPA 5030B0.475-34-306/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L11,2-Dichloroethane1.07060948EPA 5030B0.7107-06-206/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L11,1-Dichloroethene5.07060948EPA 5030B0.775-35-406/29/17 20:0506/29/17 10:25EPA 8260B3.4ug/L1cis-1,2-Dichloroethene5.0J7060948EPA 5030B0.7156-59-206/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07060948EPA 5030B0.5156-60-506/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L11,2-Dichloropropane1.07060948EPA 5030B0.678-87-506/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07060948EPA 5030B0.210061-01-506/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07060948EPA 5030B0.310061-02-606/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Ethylbenzene1.07060948EPA 5030B0.4100-41-406/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Iodomethane107060948EPA 5030B3.174-88-406/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507060948EPA 5030B0.9591-78-606/29/17 20:0506/29/17 10:25EPA 8260B0.5ug/L1Methylene Chloride1.0J7060948EPA 5030B0.575-09-206/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007060948EPA 5030B3.278-93-306/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007060948EPA 5030B0.9108-10-106/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Styrene1.07060948EPA 5030B0.5100-42-506/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07060948EPA 5030B0.3630-20-606/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07060948EPA 5030B0.579-34-506/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Tetrachloroethene1.07060948EPA 5030B0.8127-18-406/29/17 20:0506/29/17 10:25Page 17 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW4Ground WaterAAF1022-04AAF102206/26/17 14:17Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Toluene1.07060948EPA 5030B0.3108-88-306/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L11,1,1-Trichloroethane1.07060948EPA 5030B0.471-55-606/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L11,1,2-Trichloroethane1.07060948EPA 5030B0.679-00-506/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Trichloroethene1.07060948EPA 5030B0.379-01-606/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Trichlorofluoromethane1.07060948EPA 5030B0.575-69-406/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L11,2,3-Trichloropropane1.07060948EPA 5030B0.596-18-406/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Vinyl Acetate507060948EPA 5030B0.4108-05-406/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Vinyl Chloride1.07060948EPA 5030B0.675-01-406/29/17 20:0506/29/17 10:25NDEPA 8260Bug/L1Xylenes, total5.07060948EPA 5030B0.91330-20-706/29/17 20:0506/29/17 10:25EPA 8260B100 %Surr: Dibromofluoromethane7060948EPA 5030B1868-53-707/03/17 11:0107/03/17 10:0080-120EPA 8260B99 %Surr: Dibromofluoromethane7060948EPA 5030B1868-53-706/29/17 20:0506/29/17 10:2580-120EPA 8260B101 %Surr: 1,2-Dichloroethane-d47060948EPA 5030B17060-07-007/03/17 11:0107/03/17 10:0078-120EPA 8260B99 %Surr: 1,2-Dichloroethane-d47060948EPA 5030B17060-07-006/29/17 20:0506/29/17 10:2578-120EPA 8260B99 %Surr: Toluene-d87060948EPA 5030B2037-26-506/29/17 20:0506/29/17 10:2580-120EPA 8260B96 %Surr: Toluene-d87060948EPA 5030B2037-26-507/03/17 11:0107/03/17 10:0080-120EPA 8260B103 %Surr: 4-Bromofluorobenzene7060948EPA 5030B460-00-407/03/17 11:0107/03/17 10:0080-120EPA 8260B104 %Surr: 4-Bromofluorobenzene7060948EPA 5030B460-00-406/29/17 20:0506/29/17 10:2580-120Page 18 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-SW1Surface WaterAAF1022-05AAF102206/26/17 13:40Project:Montgomery County Landfill06/28/17 16:10On SiteEPA 9050A111umhos/cm1Field - Specific Conductance17060971NA1COND06/26/17 13:4006/26/17 13:40SM 4500-O G3760ug/L1Dissolved Oxygen0.07060971NA0.0NA06/26/17 13:4006/26/17 13:40EPA 9040C4.79pH Units1Field - pH7060971NAPH06/26/17 13:4006/26/17 13:40NA58mV1Field - Redox7060971NAREDOX06/26/17 13:4006/26/17 13:40SM 2550 B20.7C1Field - Temperature7060971NATEMP06/26/17 13:4006/26/17 13:40EPA 180.14.29NTU1Field - Turbidity7060971NATURB06/26/17 13:4006/26/17 13:40Metals, TotalNDEPA 6020Bug/L1Antimony6.007060901EPA 3005A0.607440-36-006/29/17 18:5206/29/17 12:00EPA 6020B4.06ug/L1Arsenic10.0J7060901EPA 3005A0.527440-38-206/29/17 18:5206/29/17 12:00EPA 6020B164ug/L1Barium1007060901EPA 3005A0.427440-39-307/07/17 10:1606/29/17 12:00NDEPA 6020Bug/L1Beryllium1.007060901EPA 3005A0.097440-41-706/29/17 18:5206/29/17 12:00NDEPA 6020Bug/L1Cadmium1.007060901EPA 3005A0.147440-43-906/29/17 18:5206/29/17 12:00EPA 6020B0.59ug/L1Chromium10.0J7060901EPA 3005A0.457440-47-306/29/17 18:5206/29/17 12:00EPA 6020B25.5ug/L1Cobalt10.07060901EPA 3005A0.267440-48-406/29/17 18:5206/29/17 12:00EPA 6020B0.41ug/L1Copper10.0J7060901EPA 3005A0.277440-50-806/29/17 18:5206/29/17 12:00EPA 6020B0.59ug/L1Lead10.0J7060901EPA 3005A0.077439-92-106/29/17 18:5206/29/17 12:00EPA 6020B2.80ug/L1Nickel50.0J7060901EPA 3005A0.497440-02-006/29/17 18:5206/29/17 12:00NDEPA 6020Bug/L1Selenium10.07060901EPA 3005A1.767782-49-206/29/17 18:5206/29/17 12:00NDEPA 6020Bug/L1Silver10.07060901EPA 3005A0.237440-22-406/29/17 18:5206/29/17 12:00EPA 6020B0.08ug/L1Thallium5.50J7060901EPA 3005A0.057440-28-006/29/17 18:5206/29/17 12:00Page 19 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-SW1Surface WaterAAF1022-05AAF102206/26/17 13:40Project:Montgomery County Landfill06/28/17 16:10Metals, TotalNDEPA 6020Bug/L1Vanadium25.07060901EPA 3005A1.207440-62-206/29/17 18:5206/29/17 12:00EPA 6020B4.23ug/L1Zinc10.0J7060901EPA 3005A1.207440-66-606/29/17 18:5206/29/17 12:00Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007060948EPA 5030B8.267-64-106/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Acrylonitrile2007060948EPA 5030B2.5107-13-106/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Benzene1.07060948EPA 5030B0.271-43-206/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Bromochloromethane3.07060948EPA 5030B0.574-97-506/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Bromodichloromethane1.07060948EPA 5030B0.475-27-406/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Bromoform3.07060948EPA 5030B0.675-25-206/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Bromomethane107060948EPA 5030B1.074-83-906/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Carbon Disulfide1007060948EPA 5030B0.875-15-006/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Carbon Tetrachloride1.07060948EPA 5030B0.456-23-506/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Chlorobenzene3.07060948EPA 5030B0.5108-90-706/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Chloroethane107060948EPA 5030B0.575-00-306/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Chloroform5.07060948EPA 5030B0.667-66-306/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Chloromethane1.07060948EPA 5030B0.474-87-306/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Dibromochloromethane3.07060948EPA 5030B0.3124-48-106/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137060948EPA 5030B0.696-12-806/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L11,2-Dibromoethane1.07060948EPA 5030B0.3106-93-406/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Dibromomethane107060948EPA 5030B0.674-95-306/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L11,2-Dichlorobenzene5.07060948EPA 5030B0.595-50-106/29/17 20:3006/29/17 10:25Page 20 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-SW1Surface WaterAAF1022-05AAF102206/26/17 13:40Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,4-Dichlorobenzene1.07060948EPA 5030B0.6106-46-706/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007060948EPA 5030B1.6110-57-606/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L11,1-Dichloroethane5.07060948EPA 5030B0.475-34-306/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L11,2-Dichloroethane1.07060948EPA 5030B0.7107-06-206/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L11,1-Dichloroethene5.07060948EPA 5030B0.775-35-406/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07060948EPA 5030B0.7156-59-206/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07060948EPA 5030B0.5156-60-506/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L11,2-Dichloropropane1.07060948EPA 5030B0.678-87-506/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07060948EPA 5030B0.210061-01-506/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07060948EPA 5030B0.310061-02-606/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Ethylbenzene1.07060948EPA 5030B0.4100-41-406/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Iodomethane107060948EPA 5030B3.174-88-406/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507060948EPA 5030B0.9591-78-606/29/17 20:3006/29/17 10:25EPA 8260B0.5ug/L1Methylene Chloride1.0J7060948EPA 5030B0.575-09-206/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007060948EPA 5030B3.278-93-306/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007060948EPA 5030B0.9108-10-106/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Styrene1.07060948EPA 5030B0.5100-42-506/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07060948EPA 5030B0.3630-20-606/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07060948EPA 5030B0.579-34-506/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Tetrachloroethene1.07060948EPA 5030B0.8127-18-406/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Toluene1.07060948EPA 5030B0.3108-88-306/29/17 20:3006/29/17 10:25Page 21 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-SW1Surface WaterAAF1022-05AAF102206/26/17 13:40Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,1,1-Trichloroethane1.07060948EPA 5030B0.471-55-606/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L11,1,2-Trichloroethane1.07060948EPA 5030B0.679-00-506/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Trichloroethene1.07060948EPA 5030B0.379-01-606/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Trichlorofluoromethane1.07060948EPA 5030B0.575-69-406/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L11,2,3-Trichloropropane1.07060948EPA 5030B0.596-18-406/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Vinyl Acetate507060948EPA 5030B0.4108-05-406/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Vinyl Chloride1.07060948EPA 5030B0.675-01-406/29/17 20:3006/29/17 10:25NDEPA 8260Bug/L1Xylenes, total5.07060948EPA 5030B0.91330-20-706/29/17 20:3006/29/17 10:25EPA 8260B99 %Surr: Dibromofluoromethane7060948EPA 5030B1868-53-706/29/17 20:3006/29/17 10:2580-120EPA 8260B100 %Surr: 1,2-Dichloroethane-d47060948EPA 5030B17060-07-006/29/17 20:3006/29/17 10:2578-120EPA 8260B97 %Surr: Toluene-d87060948EPA 5030B2037-26-506/29/17 20:3006/29/17 10:2580-120EPA 8260B105 %Surr: 4-Bromofluorobenzene7060948EPA 5030B460-00-406/29/17 20:3006/29/17 10:2580-120Page 22 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-SW2Surface WaterAAF1022-06AAF102206/26/17 13:58Project:Montgomery County Landfill06/28/17 16:10On SiteEPA 9050A76umhos/cm1Field - Specific Conductance17060971NA1COND06/26/17 13:5806/26/17 13:58SM 4500-O G2480ug/L1Dissolved Oxygen0.07060971NA0.0NA06/26/17 13:5806/26/17 13:58EPA 9040C4.99pH Units1Field - pH7060971NAPH06/26/17 13:5806/26/17 13:58NA58mV1Field - Redox7060971NAREDOX06/26/17 13:5806/26/17 13:58SM 2550 B21.2C1Field - Temperature7060971NATEMP06/26/17 13:5806/26/17 13:58EPA 180.112.0NTU1Field - Turbidity7060971NATURB06/26/17 13:5806/26/17 13:58Metals, TotalNDEPA 6020Bug/L1Antimony6.007060901EPA 3005A0.607440-36-006/29/17 18:5806/29/17 12:00EPA 6020B1.20ug/L1Arsenic10.0J7060901EPA 3005A0.527440-38-206/29/17 18:5806/29/17 12:00EPA 6020B69.2ug/L1Barium100J7060901EPA 3005A0.427440-39-306/29/17 18:5806/29/17 12:00NDEPA 6020Bug/L1Beryllium1.007060901EPA 3005A0.097440-41-706/29/17 18:5806/29/17 12:00NDEPA 6020Bug/L1Cadmium1.007060901EPA 3005A0.147440-43-906/29/17 18:5806/29/17 12:00EPA 6020B0.58ug/L1Chromium10.0J7060901EPA 3005A0.457440-47-306/29/17 18:5806/29/17 12:00EPA 6020B4.57ug/L1Cobalt10.0J7060901EPA 3005A0.267440-48-406/29/17 18:5806/29/17 12:00EPA 6020B1.02ug/L1Copper10.0J7060901EPA 3005A0.277440-50-806/29/17 18:5806/29/17 12:00EPA 6020B0.67ug/L1Lead10.0J7060901EPA 3005A0.077439-92-106/29/17 18:5806/29/17 12:00EPA 6020B1.47ug/L1Nickel50.0J7060901EPA 3005A0.497440-02-006/29/17 18:5806/29/17 12:00NDEPA 6020Bug/L1Selenium10.07060901EPA 3005A1.767782-49-206/29/17 18:5806/29/17 12:00NDEPA 6020Bug/L1Silver10.07060901EPA 3005A0.237440-22-406/29/17 18:5806/29/17 12:00NDEPA 6020Bug/L1Thallium5.507060901EPA 3005A0.057440-28-006/29/17 18:5806/29/17 12:00NDEPA 6020Bug/L1Vanadium25.07060901EPA 3005A1.207440-62-206/29/17 18:5806/29/17 12:00Page 23 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-SW2Surface WaterAAF1022-06AAF102206/26/17 13:58Project:Montgomery County Landfill06/28/17 16:10Metals, TotalEPA 6020B3.20ug/L1Zinc10.0J7060901EPA 3005A1.207440-66-606/29/17 18:5806/29/17 12:00Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007070015EPA 5030B8.267-64-107/03/17 19:0207/03/17 09:01NDEPA 8260Bug/L1Acrylonitrile2007070015EPA 5030B2.5107-13-106/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Benzene1.07070015EPA 5030B0.271-43-206/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Bromochloromethane3.07070015EPA 5030B0.574-97-506/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Bromodichloromethane1.07070015EPA 5030B0.475-27-406/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Bromoform3.07070015EPA 5030B0.675-25-206/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Bromomethane107070015EPA 5030B1.074-83-906/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Carbon Disulfide1007070015EPA 5030B0.875-15-006/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Carbon Tetrachloride1.07070015EPA 5030B0.456-23-506/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Chlorobenzene3.07070015EPA 5030B0.5108-90-706/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Chloroethane107070015EPA 5030B0.575-00-306/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Chloroform5.07070015EPA 5030B0.667-66-306/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Chloromethane1.07070015EPA 5030B0.474-87-306/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Dibromochloromethane3.07070015EPA 5030B0.3124-48-106/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137070015EPA 5030B0.696-12-806/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L11,2-Dibromoethane1.07070015EPA 5030B0.3106-93-406/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Dibromomethane107070015EPA 5030B0.674-95-306/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L11,2-Dichlorobenzene5.07070015EPA 5030B0.595-50-106/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L11,4-Dichlorobenzene1.07070015EPA 5030B0.6106-46-706/30/17 10:4106/30/17 09:01Page 24 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-SW2Surface WaterAAF1022-06AAF102206/26/17 13:58Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007070015EPA 5030B1.6110-57-606/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L11,1-Dichloroethane5.07070015EPA 5030B0.475-34-306/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L11,2-Dichloroethane1.07070015EPA 5030B0.7107-06-206/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L11,1-Dichloroethene5.07070015EPA 5030B0.775-35-406/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07070015EPA 5030B0.7156-59-206/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07070015EPA 5030B0.5156-60-506/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L11,2-Dichloropropane1.07070015EPA 5030B0.678-87-506/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07070015EPA 5030B0.210061-01-506/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07070015EPA 5030B0.310061-02-606/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Ethylbenzene1.07070015EPA 5030B0.4100-41-406/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Iodomethane107070015EPA 5030B3.174-88-406/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507070015EPA 5030B0.9591-78-606/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Methylene Chloride1.07070015EPA 5030B0.575-09-206/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007070015EPA 5030B3.278-93-306/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007070015EPA 5030B0.9108-10-106/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Styrene1.07070015EPA 5030B0.5100-42-506/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07070015EPA 5030B0.3630-20-606/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07070015EPA 5030B0.579-34-506/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Tetrachloroethene1.07070015EPA 5030B0.8127-18-406/30/17 10:4106/30/17 09:01EPA 8260B0.5ug/L1Toluene1.0J7070015EPA 5030B0.3108-88-306/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L11,1,1-Trichloroethane1.07070015EPA 5030B0.471-55-606/30/17 10:4106/30/17 09:01Page 25 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-SW2Surface WaterAAF1022-06AAF102206/26/17 13:58Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,1,2-Trichloroethane1.07070015EPA 5030B0.679-00-506/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Trichloroethene1.07070015EPA 5030B0.379-01-606/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Trichlorofluoromethane1.07070015EPA 5030B0.575-69-406/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L11,2,3-Trichloropropane1.07070015EPA 5030B0.596-18-406/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Vinyl Acetate507070015EPA 5030B0.4108-05-406/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Vinyl Chloride1.07070015EPA 5030B0.675-01-406/30/17 10:4106/30/17 09:01NDEPA 8260Bug/L1Xylenes, total5.07070015EPA 5030B0.91330-20-706/30/17 10:4106/30/17 09:01EPA 8260B101 %Surr: Dibromofluoromethane7070015EPA 5030B1868-53-706/30/17 10:4106/30/17 09:0180-120EPA 8260B103 %Surr: Dibromofluoromethane7070015EPA 5030B1868-53-707/03/17 19:0207/03/17 09:0180-120EPA 8260B105 %Surr: 1,2-Dichloroethane-d47070015EPA 5030B17060-07-007/03/17 19:0207/03/17 09:0178-120EPA 8260B100 %Surr: 1,2-Dichloroethane-d47070015EPA 5030B17060-07-006/30/17 10:4106/30/17 09:0178-120EPA 8260B96 %Surr: Toluene-d87070015EPA 5030B2037-26-507/03/17 19:0207/03/17 09:0180-120EPA 8260B99 %Surr: Toluene-d87070015EPA 5030B2037-26-506/30/17 10:4106/30/17 09:0180-120EPA 8260B102 %Surr: 4-Bromofluorobenzene7070015EPA 5030B460-00-407/03/17 19:0207/03/17 09:0180-120EPA 8260B104 %Surr: 4-Bromofluorobenzene7070015EPA 5030B460-00-406/30/17 10:4106/30/17 09:0180-120Page 26 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-Field BlankWaterAAF1022-07AAF102206/26/17 13:32Project:Montgomery County Landfill06/28/17 16:10Metals, TotalNDEPA 6020Bug/L1Antimony6.007060901EPA 3005A0.607440-36-006/29/17 19:0406/29/17 12:00NDEPA 6020Bug/L1Arsenic10.07060901EPA 3005A0.527440-38-206/29/17 19:0406/29/17 12:00NDEPA 6020Bug/L1Barium1007060901EPA 3005A0.427440-39-306/29/17 19:0406/29/17 12:00NDEPA 6020Bug/L1Beryllium1.007060901EPA 3005A0.097440-41-706/29/17 19:0406/29/17 12:00NDEPA 6020Bug/L1Cadmium1.007060901EPA 3005A0.147440-43-906/29/17 19:0406/29/17 12:00NDEPA 6020Bug/L1Chromium10.07060901EPA 3005A0.457440-47-306/29/17 19:0406/29/17 12:00NDEPA 6020Bug/L1Cobalt10.07060901EPA 3005A0.267440-48-406/29/17 19:0406/29/17 12:00NDEPA 6020Bug/L1Copper10.07060901EPA 3005A0.277440-50-806/29/17 19:0406/29/17 12:00NDEPA 6020Bug/L1Lead10.07060901EPA 3005A0.077439-92-106/29/17 19:0406/29/17 12:00NDEPA 6020Bug/L1Nickel50.07060901EPA 3005A0.497440-02-006/29/17 19:0406/29/17 12:00NDEPA 6020Bug/L1Selenium10.07060901EPA 3005A1.767782-49-206/29/17 19:0406/29/17 12:00NDEPA 6020Bug/L1Silver10.07060901EPA 3005A0.237440-22-406/29/17 19:0406/29/17 12:00NDEPA 6020Bug/L1Thallium5.507060901EPA 3005A0.057440-28-006/29/17 19:0406/29/17 12:00NDEPA 6020Bug/L1Vanadium25.07060901EPA 3005A1.207440-62-206/29/17 19:0406/29/17 12:00NDEPA 6020Bug/L1Zinc10.07060901EPA 3005A1.207440-66-606/29/17 19:0406/29/17 12:00Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007070015EPA 5030B8.267-64-106/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Acrylonitrile2007070015EPA 5030B2.5107-13-106/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Benzene1.07070015EPA 5030B0.271-43-206/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Bromochloromethane3.07070015EPA 5030B0.574-97-506/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Bromodichloromethane1.07070015EPA 5030B0.475-27-406/30/17 11:0706/30/17 09:01Page 27 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-Field BlankWaterAAF1022-07AAF102206/26/17 13:32Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromoform3.07070015EPA 5030B0.675-25-206/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Bromomethane107070015EPA 5030B1.074-83-906/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Carbon Disulfide1007070015EPA 5030B0.875-15-006/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Carbon Tetrachloride1.07070015EPA 5030B0.456-23-506/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Chlorobenzene3.07070015EPA 5030B0.5108-90-706/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Chloroethane107070015EPA 5030B0.575-00-306/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Chloroform5.07070015EPA 5030B0.667-66-306/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Chloromethane1.07070015EPA 5030B0.474-87-306/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Dibromochloromethane3.07070015EPA 5030B0.3124-48-106/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137070015EPA 5030B0.696-12-806/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L11,2-Dibromoethane1.07070015EPA 5030B0.3106-93-406/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Dibromomethane107070015EPA 5030B0.674-95-306/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L11,2-Dichlorobenzene5.07070015EPA 5030B0.595-50-106/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L11,4-Dichlorobenzene1.07070015EPA 5030B0.6106-46-706/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007070015EPA 5030B1.6110-57-606/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L11,1-Dichloroethane5.07070015EPA 5030B0.475-34-306/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L11,2-Dichloroethane1.07070015EPA 5030B0.7107-06-206/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L11,1-Dichloroethene5.07070015EPA 5030B0.775-35-406/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07070015EPA 5030B0.7156-59-206/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07070015EPA 5030B0.5156-60-506/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L11,2-Dichloropropane1.07070015EPA 5030B0.678-87-506/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07070015EPA 5030B0.210061-01-506/30/17 11:0706/30/17 09:01Page 28 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-Field BlankWaterAAF1022-07AAF102206/26/17 13:32Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07070015EPA 5030B0.310061-02-606/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Ethylbenzene1.07070015EPA 5030B0.4100-41-406/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Iodomethane107070015EPA 5030B3.174-88-406/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507070015EPA 5030B0.9591-78-606/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Methylene Chloride1.07070015EPA 5030B0.575-09-206/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007070015EPA 5030B3.278-93-306/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007070015EPA 5030B0.9108-10-106/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Styrene1.07070015EPA 5030B0.5100-42-506/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07070015EPA 5030B0.3630-20-606/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07070015EPA 5030B0.579-34-506/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Tetrachloroethene1.07070015EPA 5030B0.8127-18-406/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Toluene1.07070015EPA 5030B0.3108-88-306/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L11,1,1-Trichloroethane1.07070015EPA 5030B0.471-55-606/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L11,1,2-Trichloroethane1.07070015EPA 5030B0.679-00-506/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Trichloroethene1.07070015EPA 5030B0.379-01-606/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Trichlorofluoromethane1.07070015EPA 5030B0.575-69-406/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L11,2,3-Trichloropropane1.07070015EPA 5030B0.596-18-406/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Vinyl Acetate507070015EPA 5030B0.4108-05-406/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Vinyl Chloride1.07070015EPA 5030B0.675-01-406/30/17 11:0706/30/17 09:01NDEPA 8260Bug/L1Xylenes, total5.07070015EPA 5030B0.91330-20-706/30/17 11:0706/30/17 09:01EPA 8260B100 %Surr: Dibromofluoromethane7070015EPA 5030B1868-53-706/30/17 11:0706/30/17 09:0180-120Page 29 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-Field BlankWaterAAF1022-07AAF102206/26/17 13:32Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260EPA 8260B101 %Surr: 1,2-Dichloroethane-d47070015EPA 5030B17060-07-006/30/17 11:0706/30/17 09:0178-120EPA 8260B99 %Surr: Toluene-d87070015EPA 5030B2037-26-506/30/17 11:0706/30/17 09:0180-120EPA 8260B102 %Surr: 4-Bromofluorobenzene7070015EPA 5030B460-00-406/30/17 11:0706/30/17 09:0180-120Page 30 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-Trip BlankWaterAAF1022-08AAF102206/26/17 00:00Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007070038EPA 5030B8.267-64-107/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Acrylonitrile2007070038EPA 5030B2.5107-13-107/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Benzene1.07070038EPA 5030B0.271-43-207/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Bromochloromethane3.07070038EPA 5030B0.574-97-507/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Bromodichloromethane1.07070038EPA 5030B0.475-27-407/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Bromoform3.07070038EPA 5030B0.675-25-207/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Bromomethane107070038EPA 5030B1.074-83-907/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Carbon Disulfide1007070038EPA 5030B0.875-15-007/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Carbon Tetrachloride1.07070038EPA 5030B0.456-23-507/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Chlorobenzene3.07070038EPA 5030B0.5108-90-707/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Chloroethane107070038EPA 5030B0.575-00-307/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Chloroform5.07070038EPA 5030B0.667-66-307/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Chloromethane1.07070038EPA 5030B0.474-87-307/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Dibromochloromethane3.07070038EPA 5030B0.3124-48-107/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137070038EPA 5030B0.696-12-807/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L11,2-Dibromoethane1.07070038EPA 5030B0.3106-93-407/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Dibromomethane107070038EPA 5030B0.674-95-307/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L11,2-Dichlorobenzene5.07070038EPA 5030B0.595-50-107/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L11,4-Dichlorobenzene1.07070038EPA 5030B0.6106-46-707/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007070038EPA 5030B1.6110-57-607/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L11,1-Dichloroethane5.07070038EPA 5030B0.475-34-307/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L11,2-Dichloroethane1.07070038EPA 5030B0.7107-06-207/03/17 12:4307/03/17 09:00Page 31 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-Trip BlankWaterAAF1022-08AAF102206/26/17 00:00Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,1-Dichloroethene5.07070038EPA 5030B0.775-35-407/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07070038EPA 5030B0.7156-59-207/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07070038EPA 5030B0.5156-60-507/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L11,2-Dichloropropane1.07070038EPA 5030B0.678-87-507/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07070038EPA 5030B0.210061-01-507/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07070038EPA 5030B0.310061-02-607/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Ethylbenzene1.07070038EPA 5030B0.4100-41-407/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Iodomethane107070038EPA 5030B3.174-88-407/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507070038EPA 5030B0.9591-78-607/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Methylene Chloride1.07070038EPA 5030B0.575-09-207/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007070038EPA 5030B3.278-93-307/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007070038EPA 5030B0.9108-10-107/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Styrene1.07070038EPA 5030B0.5100-42-507/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07070038EPA 5030B0.3630-20-607/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07070038EPA 5030B0.579-34-507/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Tetrachloroethene1.07070038EPA 5030B0.8127-18-407/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Toluene1.07070038EPA 5030B0.3108-88-307/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L11,1,1-Trichloroethane1.07070038EPA 5030B0.471-55-607/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L11,1,2-Trichloroethane1.07070038EPA 5030B0.679-00-507/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Trichloroethene1.07070038EPA 5030B0.379-01-607/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Trichlorofluoromethane1.07070038EPA 5030B0.575-69-407/03/17 12:4307/03/17 09:00Page 32 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-Trip BlankWaterAAF1022-08AAF102206/26/17 00:00Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2,3-Trichloropropane1.07070038EPA 5030B0.596-18-407/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Vinyl Acetate507070038EPA 5030B0.4108-05-407/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Vinyl Chloride1.07070038EPA 5030B0.675-01-407/03/17 12:4307/03/17 09:00NDEPA 8260Bug/L1Xylenes, total5.07070038EPA 5030B0.91330-20-707/03/17 12:4307/03/17 09:00EPA 8260B100 %Surr: Dibromofluoromethane7070038EPA 5030B1868-53-707/03/17 12:4307/03/17 09:0080-120EPA 8260B101 %Surr: 1,2-Dichloroethane-d47070038EPA 5030B17060-07-007/03/17 12:4307/03/17 09:0078-120EPA 8260B97 %Surr: Toluene-d87070038EPA 5030B2037-26-507/03/17 12:4307/03/17 09:0080-120EPA 8260B101 %Surr: 4-Bromofluorobenzene7070038EPA 5030B460-00-407/03/17 12:4307/03/17 09:0080-120Page 33 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-DuplicateGround WaterAAF1022-09AAF102206/26/17 00:00Project:Montgomery County Landfill06/28/17 16:10Metals, TotalNDEPA 6020Bug/L1Antimony6.007060901EPA 3005A0.607440-36-006/29/17 19:1006/29/17 12:00EPA 6020B5.01ug/L1Arsenic10.0J7060901EPA 3005A0.527440-38-206/29/17 19:1006/29/17 12:00EPA 6020B172ug/L1Barium1007060901EPA 3005A0.427440-39-307/07/17 10:2106/29/17 12:00NDEPA 6020Bug/L1Beryllium1.007060901EPA 3005A0.097440-41-706/29/17 19:1006/29/17 12:00EPA 6020B0.22ug/L1Cadmium1.00J7060901EPA 3005A0.147440-43-906/29/17 19:1006/29/17 12:00NDEPA 6020Bug/L1Chromium10.07060901EPA 3005A0.457440-47-306/29/17 19:1006/29/17 12:00EPA 6020B28.0ug/L1Cobalt10.07060901EPA 3005A0.267440-48-406/29/17 19:1006/29/17 12:00EPA 6020B0.61ug/L1Copper10.0J7060901EPA 3005A0.277440-50-806/29/17 19:1006/29/17 12:00NDEPA 6020Bug/L1Lead10.07060901EPA 3005A0.077439-92-106/29/17 19:1006/29/17 12:00EPA 6020B7.19ug/L1Nickel50.0J7060901EPA 3005A0.497440-02-006/29/17 19:1006/29/17 12:00NDEPA 6020Bug/L1Selenium10.07060901EPA 3005A1.767782-49-206/29/17 19:1006/29/17 12:00NDEPA 6020Bug/L1Silver10.07060901EPA 3005A0.237440-22-406/29/17 19:1006/29/17 12:00EPA 6020B0.14ug/L1Thallium5.50J7060901EPA 3005A0.057440-28-006/29/17 19:1006/29/17 12:00NDEPA 6020Bug/L1Vanadium25.07060901EPA 3005A1.207440-62-206/29/17 19:1006/29/17 12:00EPA 6020B24.9ug/L1Zinc10.07060901EPA 3005A1.207440-66-606/29/17 19:1006/29/17 12:00Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007070015EPA 5030B8.267-64-107/03/17 11:2707/03/17 09:01NDEPA 8260Bug/L1Acrylonitrile2007070015EPA 5030B2.5107-13-106/30/17 11:3206/30/17 09:01EPA 8260B1.7ug/L1Benzene1.07070015EPA 5030B0.271-43-206/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Bromochloromethane3.07070015EPA 5030B0.574-97-506/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Bromodichloromethane1.07070015EPA 5030B0.475-27-406/30/17 11:3206/30/17 09:01Page 34 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-DuplicateGround WaterAAF1022-09AAF102206/26/17 00:00Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromoform3.07070015EPA 5030B0.675-25-206/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Bromomethane107070015EPA 5030B1.074-83-906/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Carbon Disulfide1007070015EPA 5030B0.875-15-006/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Carbon Tetrachloride1.07070015EPA 5030B0.456-23-506/30/17 11:3206/30/17 09:01EPA 8260B1.4ug/L1Chlorobenzene3.0J7070015EPA 5030B0.5108-90-706/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Chloroethane107070015EPA 5030B0.575-00-306/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Chloroform5.07070015EPA 5030B0.667-66-306/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Chloromethane1.07070015EPA 5030B0.474-87-306/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Dibromochloromethane3.07070015EPA 5030B0.3124-48-106/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137070015EPA 5030B0.696-12-806/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L11,2-Dibromoethane1.07070015EPA 5030B0.3106-93-406/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Dibromomethane107070015EPA 5030B0.674-95-306/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L11,2-Dichlorobenzene5.07070015EPA 5030B0.595-50-106/30/17 11:3206/30/17 09:01EPA 8260B2.9ug/L11,4-Dichlorobenzene1.07070015EPA 5030B0.6106-46-706/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007070015EPA 5030B1.6110-57-606/30/17 11:3206/30/17 09:01EPA 8260B0.8ug/L11,1-Dichloroethane5.0J7070015EPA 5030B0.475-34-306/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L11,2-Dichloroethane1.07070015EPA 5030B0.7107-06-206/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L11,1-Dichloroethene5.07070015EPA 5030B0.775-35-406/30/17 11:3206/30/17 09:01EPA 8260B3.6ug/L1cis-1,2-Dichloroethene5.0J7070015EPA 5030B0.7156-59-206/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07070015EPA 5030B0.5156-60-506/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L11,2-Dichloropropane1.07070015EPA 5030B0.678-87-506/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07070015EPA 5030B0.210061-01-506/30/17 11:3206/30/17 09:01Page 35 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-DuplicateGround WaterAAF1022-09AAF102206/26/17 00:00Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07070015EPA 5030B0.310061-02-606/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Ethylbenzene1.07070015EPA 5030B0.4100-41-406/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Iodomethane107070015EPA 5030B3.174-88-406/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507070015EPA 5030B0.9591-78-606/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Methylene Chloride1.07070015EPA 5030B0.575-09-206/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007070015EPA 5030B3.278-93-306/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007070015EPA 5030B0.9108-10-106/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Styrene1.07070015EPA 5030B0.5100-42-506/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07070015EPA 5030B0.3630-20-606/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07070015EPA 5030B0.579-34-506/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Tetrachloroethene1.07070015EPA 5030B0.8127-18-406/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Toluene1.07070015EPA 5030B0.3108-88-306/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L11,1,1-Trichloroethane1.07070015EPA 5030B0.471-55-606/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L11,1,2-Trichloroethane1.07070015EPA 5030B0.679-00-506/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Trichloroethene1.07070015EPA 5030B0.379-01-606/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Trichlorofluoromethane1.07070015EPA 5030B0.575-69-406/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L11,2,3-Trichloropropane1.07070015EPA 5030B0.596-18-406/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Vinyl Acetate507070015EPA 5030B0.4108-05-406/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Vinyl Chloride1.07070015EPA 5030B0.675-01-406/30/17 11:3206/30/17 09:01NDEPA 8260Bug/L1Xylenes, total5.07070015EPA 5030B0.91330-20-706/30/17 11:3206/30/17 09:01EPA 8260B97 %Surr: Dibromofluoromethane7070015EPA 5030B1868-53-707/03/17 11:2707/03/17 09:0180-120Page 36 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-DuplicateGround WaterAAF1022-09AAF102206/26/17 00:00Project:Montgomery County Landfill06/28/17 16:10Volatile Organic Compounds by EPA 8260EPA 8260B96 %Surr: Dibromofluoromethane7070015EPA 5030B1868-53-706/30/17 11:3206/30/17 09:0180-120EPA 8260B101 %Surr: 1,2-Dichloroethane-d47070015EPA 5030B17060-07-007/03/17 11:2707/03/17 09:0178-120EPA 8260B98 %Surr: 1,2-Dichloroethane-d47070015EPA 5030B17060-07-006/30/17 11:3206/30/17 09:0178-120EPA 8260B97 %Surr: Toluene-d87070015EPA 5030B2037-26-507/03/17 11:2707/03/17 09:0180-120EPA 8260B98 %Surr: Toluene-d87070015EPA 5030B2037-26-506/30/17 11:3206/30/17 09:0180-120EPA 8260B104 %Surr: 4-Bromofluorobenzene7070015EPA 5030B460-00-407/03/17 11:2707/03/17 09:0180-120EPA 8260B104 %Surr: 4-Bromofluorobenzene7070015EPA 5030B460-00-406/30/17 11:3206/30/17 09:0180-120Page 37 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7060901 - EPA 3005ABlank (7060901-BLK1)Prepared & Analyzed: 06/29/17 Antimonyug/LND6.00Arsenicug/LND10.0Bariumug/LND100Berylliumug/LND1.00Cadmiumug/LND1.00Chromiumug/LND10.0Cobaltug/LND10.0Copperug/LND10.0Leadug/LND10.0Nickelug/LND50.0Seleniumug/LND10.0Silverug/LND10.0Thalliumug/LND5.50Vanadiumug/LND25.0Zincug/LND10.0LCS (7060901-BS1)Prepared & Analyzed: 06/29/17 Antimonyug/L1046.00100.0080-120104Arsenicug/L10110.0100.0080-120101Bariumug/L100100100.0080-120100Berylliumug/L1081.00100.0080-120108Cadmiumug/L1051.00100.0080-120105Chromiumug/L97.910.0100.0080-12098Cobaltug/L96.710.0100.0080-12097Copperug/L10210.0100.0080-120102Leadug/L10110.0100.0080-120101Nickelug/L98.650.0100.0080-12099Page 38 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7060901 - EPA 3005ALCS (7060901-BS1)Prepared & Analyzed: 06/29/17 Seleniumug/L10110.0100.0080-120101Silverug/L10310.0100.0080-120103Thalliumug/L1035.50100.0080-120103Vanadiumug/L10425.0100.0080-120104Zincug/L10310.0100.0080-120103Matrix Spike (7060901-MS1)Prepared & Analyzed: 06/29/17 Source: AAF1022-02Antimonyug/L1046.00100.00ND75-125104Arsenicug/L10110.0100.000.7475-125101Bariumug/L137100100.0050.275-12586Berylliumug/L97.01.00100.000.2175-12597Cadmiumug/L1071.00100.00ND75-125107Chromiumug/L10810.0100.001.2575-125106Cobaltug/L10410.0100.000.6875-125103Copperug/L10610.0100.000.7975-125105Leadug/L10510.0100.001.5075-125104Nickelug/L10650.0100.000.9175-125105Seleniumug/L10410.0100.00ND75-125104Silverug/L10310.0100.00ND75-125103Thalliumug/L1075.50100.00ND75-125107Vanadiumug/L10425.0100.00ND75-125104Zincug/L11910.0100.006.4575-125112Matrix Spike Dup (7060901-MSD1)Prepared & Analyzed: 06/29/17 Source: AAF1022-02Antimonyug/L1036.00100.00ND2075-1251030.05Arsenicug/L10010.0100.000.742075-125991Bariumug/L139100100.0050.22075-125892Berylliumug/L96.01.00100.000.212075-125961Page 39 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7060901 - EPA 3005AMatrix Spike Dup (7060901-MSD1)Prepared & Analyzed: 06/29/17 Source: AAF1022-02Cadmiumug/L1071.00100.00ND2075-1251070.3Chromiumug/L10610.0100.001.252075-1251051Cobaltug/L10210.0100.000.682075-1251012Copperug/L10010.0100.000.792075-1251006Leadug/L10510.0100.001.502075-1251040.4Nickelug/L10150.0100.000.912075-1251005Seleniumug/L96.510.0100.00ND2075-125968Silverug/L10110.0100.00ND2075-1251013Thalliumug/L1075.50100.00ND2075-1251070.1Vanadiumug/L10525.0100.00ND2075-1251051Zincug/L11510.0100.006.452075-1251083Post Spike (7060901-PS1)Prepared & Analyzed: 06/29/17 Source: AAF1022-02Antimonyug/L84.7100.00-0.0280-12085Arsenicug/L104100.000.7480-120104Bariumug/L139100.0050.280-12089Berylliumug/L96.2100.000.2180-12096Cadmiumug/L104100.000.0280-120104Chromiumug/L109100.001.2580-120108Cobaltug/L104100.000.6880-120103Copperug/L104100.000.7980-120104Leadug/L105100.001.5080-120104Nickelug/L108100.000.9180-120107Seleniumug/L105100.000.8980-120104Silverug/L105100.000.1980-120105Thalliumug/L107100.000.0480-120107Vanadiumug/L111100.000.9980-120110Zincug/L115100.006.4580-120108Page 40 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7060901 - EPA 3005APage 41 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7060948 - EPA 5030BBlank (7060948-BLK1)Prepared & Analyzed: 06/29/17 Acetoneug/LND100Acrylonitrileug/LND200Benzeneug/LND1.0Bromochloromethaneug/LND3.0Bromodichloromethaneug/LND1.0Bromoformug/LND3.0Bromomethaneug/LND10Carbon Disulfideug/LND100Carbon Tetrachlorideug/LND1.0Chlorobenzeneug/LND3.0Chloroethaneug/LND10Chloroformug/LND5.0Chloromethaneug/LND1.0Dibromochloromethaneug/LND3.01,2-Dibromo-3-chloropropaneug/LND131,2-Dibromoethaneug/LND1.0Dibromomethaneug/LND101,2-Dichlorobenzeneug/LND5.01,4-Dichlorobenzeneug/LND1.0trans-1,4-Dichloro-2-buteneug/LND1001,1-Dichloroethaneug/LND5.01,2-Dichloroethaneug/LND1.01,1-Dichloroetheneug/LND5.0cis-1,2-Dichloroetheneug/LND5.0trans-1,2-Dichloroetheneug/LND5.01,2-Dichloropropaneug/LND1.0cis-1,3-Dichloropropeneug/LND1.0Page 42 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7060948 - EPA 5030BBlank (7060948-BLK1)Prepared & Analyzed: 06/29/17 trans-1,3-Dichloropropeneug/LND1.0Ethylbenzeneug/LND1.0Iodomethaneug/LND10Methyl Butyl Ketone (2-Hexanone)ug/LND50Methylene Chlorideug/L0.71.0JMethyl Ethyl Ketone (2-Butanone)ug/LND1004-Methyl-2-pentanone (MIBK)ug/LND100Styreneug/LND1.01,1,1,2-Tetrachloroethaneug/LND5.01,1,2,2-Tetrachloroethaneug/LND3.0Tetrachloroetheneug/LND1.0Tolueneug/LND1.01,1,1-Trichloroethaneug/LND1.01,1,2-Trichloroethaneug/LND1.0Trichloroetheneug/LND1.0Trichlorofluoromethaneug/LND1.01,2,3-Trichloropropaneug/LND1.0Vinyl Acetateug/LND50Vinyl Chlorideug/LND1.0Xylenes, totalug/LND5.0ug/L50.00080-120Surr: Dibromofluoromethane9447ug/L50.00078-120Surr: 1,2-Dichloroethane-d49648ug/L50.00080-120Surr: Toluene-d810050ug/L50.00080-120Surr: 4-Bromofluorobenzene10452LCS (7060948-BS1)Prepared & Analyzed: 06/29/17 Benzeneug/L5250.00067-134104Page 43 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7060948 - EPA 5030BLCS (7060948-BS1)Prepared & Analyzed: 06/29/17 Chlorobenzeneug/L5050.00069-122991,1-Dichloroetheneug/L4050.00058-14281Tolueneug/L4850.00068-12797Trichloroetheneug/L4450.00072-13287ug/L50.00080-120Surr: Dibromofluoromethane9749ug/L50.00078-120Surr: 1,2-Dichloroethane-d49547ug/L50.00080-120Surr: Toluene-d89849ug/L50.00080-120Surr: 4-Bromofluorobenzene10653Matrix Spike (7060948-MS1)Prepared & Analyzed: 06/29/17 Source: AAF1022-02Benzeneug/L5350.0000.067-134106Chlorobenzeneug/L5150.0000.069-1221011,1-Dichloroetheneug/L4950.0000.058-14299Tolueneug/L5150.0000.068-127102Trichloroetheneug/L4750.0002.372-13289ug/L50.00080-120Surr: Dibromofluoromethane9949ug/L50.00078-120Surr: 1,2-Dichloroethane-d410050ug/L50.00080-120Surr: Toluene-d89849ug/L50.00080-120Surr: 4-Bromofluorobenzene10754Matrix Spike Dup (7060948-MSD1)Prepared & Analyzed: 06/29/17 Source: AAF1022-02Benzeneug/L5350.0000.0967-1341060.1Chlorobenzeneug/L4950.0000.01369-1229931,1-Dichloroetheneug/L4850.0000.0958-142972Tolueneug/L5250.0000.0968-1271030.6Trichloroetheneug/L4850.0002.31172-132922Page 44 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7060948 - EPA 5030BMatrix Spike Dup (7060948-MSD1)Prepared & Analyzed: 06/29/17 Source: AAF1022-02ug/L50.00080-120Surr: Dibromofluoromethane9950ug/L50.00078-120Surr: 1,2-Dichloroethane-d410251ug/L50.00080-120Surr: Toluene-d89748ug/L50.00080-120Surr: 4-Bromofluorobenzene10351Batch 7070015 - EPA 5030BBlank (7070015-BLK1)Prepared & Analyzed: 06/30/17 Acetoneug/LND100Acrylonitrileug/LND200Benzeneug/LND1.0Bromochloromethaneug/LND3.0Bromodichloromethaneug/LND1.0Bromoformug/LND3.0Bromomethaneug/LND10Carbon Disulfideug/LND100Carbon Tetrachlorideug/LND1.0Chlorobenzeneug/LND3.0Chloroethaneug/LND10Chloroformug/LND5.0Chloromethaneug/LND1.0Dibromochloromethaneug/LND3.01,2-Dibromo-3-chloropropaneug/LND131,2-Dibromoethaneug/LND1.0Dibromomethaneug/LND101,2-Dichlorobenzeneug/LND5.01,4-Dichlorobenzeneug/LND1.0Page 45 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7070015 - EPA 5030BBlank (7070015-BLK1)Prepared & Analyzed: 06/30/17 trans-1,4-Dichloro-2-buteneug/LND1001,1-Dichloroethaneug/LND5.01,2-Dichloroethaneug/LND1.01,1-Dichloroetheneug/LND5.0cis-1,2-Dichloroetheneug/LND5.0trans-1,2-Dichloroetheneug/LND5.01,2-Dichloropropaneug/LND1.0cis-1,3-Dichloropropeneug/LND1.0trans-1,3-Dichloropropeneug/LND1.0Ethylbenzeneug/LND1.0Iodomethaneug/LND10Methyl Butyl Ketone (2-Hexanone)ug/LND50Methylene Chlorideug/LND1.0Methyl Ethyl Ketone (2-Butanone)ug/LND1004-Methyl-2-pentanone (MIBK)ug/LND100Styreneug/LND1.01,1,1,2-Tetrachloroethaneug/LND5.01,1,2,2-Tetrachloroethaneug/LND3.0Tetrachloroetheneug/LND1.0Tolueneug/LND1.01,1,1-Trichloroethaneug/LND1.01,1,2-Trichloroethaneug/LND1.0Trichloroetheneug/LND1.0Trichlorofluoromethaneug/LND1.01,2,3-Trichloropropaneug/LND1.0Vinyl Acetateug/LND50Vinyl Chlorideug/LND1.0Page 46 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7070015 - EPA 5030BBlank (7070015-BLK1)Prepared & Analyzed: 06/30/17 Xylenes, totalug/LND5.0ug/L50.00080-120Surr: Dibromofluoromethane9749ug/L50.00078-120Surr: 1,2-Dichloroethane-d410251ug/L50.00080-120Surr: Toluene-d810050ug/L50.00080-120Surr: 4-Bromofluorobenzene10452LCS (7070015-BS1)Prepared & Analyzed: 06/30/17 Benzeneug/L5750.00067-134115Chlorobenzeneug/L5450.00069-1221081,1-Dichloroetheneug/L5750.00058-142113Tolueneug/L5350.00068-127105Trichloroetheneug/L4850.00072-13297ug/L50.00080-120Surr: Dibromofluoromethane10050ug/L50.00078-120Surr: 1,2-Dichloroethane-d410251ug/L50.00080-120Surr: Toluene-d89949ug/L50.00080-120Surr: 4-Bromofluorobenzene10351Matrix Spike (7070015-MS1)Prepared & Analyzed: 06/30/17 Source: AAF1024-01Benzeneug/L5950.0000.067-134118Chlorobenzeneug/L5550.0000.069-1221101,1-Dichloroetheneug/L6650.0000.058-142132Tolueneug/L5650.0000.068-127112Trichloroetheneug/L5150.0000.072-132101ug/L50.00080-120Surr: Dibromofluoromethane9949ug/L50.00078-120Surr: 1,2-Dichloroethane-d410352Page 47 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7070015 - EPA 5030BMatrix Spike (7070015-MS1)Prepared & Analyzed: 06/30/17 Source: AAF1024-01ug/L50.00080-120Surr: Toluene-d89849ug/L50.00080-120Surr: 4-Bromofluorobenzene10351Matrix Spike Dup (7070015-MSD1)Prepared & Analyzed: 06/30/17 Source: AAF1024-01Benzeneug/L5850.0000.0967-1341161Chlorobenzeneug/L5350.0000.01369-12210741,1-Dichloroetheneug/L6550.0000.0958-1421311Tolueneug/L5650.0000.0968-1271130.3Trichloroetheneug/L5250.0000.01172-1321042ug/L50.00080-120Surr: Dibromofluoromethane10050ug/L50.00078-120Surr: 1,2-Dichloroethane-d410352ug/L50.00080-120Surr: Toluene-d89648ug/L50.00080-120Surr: 4-Bromofluorobenzene10352Batch 7070038 - EPA 5030BBlank (7070038-BLK1)Prepared & Analyzed: 07/03/17 Acetoneug/LND100Acrylonitrileug/LND200Benzeneug/LND1.0Bromochloromethaneug/LND3.0Bromodichloromethaneug/LND1.0Bromoformug/LND3.0Bromomethaneug/LND10Carbon Disulfideug/LND100Carbon Tetrachlorideug/LND1.0Page 48 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7070038 - EPA 5030BBlank (7070038-BLK1)Prepared & Analyzed: 07/03/17 Chlorobenzeneug/LND3.0Chloroethaneug/LND10Chloroformug/LND5.0Chloromethaneug/LND1.0Dibromochloromethaneug/LND3.01,2-Dibromo-3-chloropropaneug/LND131,2-Dibromoethaneug/LND1.0Dibromomethaneug/LND101,2-Dichlorobenzeneug/LND5.01,4-Dichlorobenzeneug/LND1.0trans-1,4-Dichloro-2-buteneug/LND1001,1-Dichloroethaneug/LND5.01,2-Dichloroethaneug/LND1.01,1-Dichloroetheneug/LND5.0cis-1,2-Dichloroetheneug/LND5.0trans-1,2-Dichloroetheneug/LND5.01,2-Dichloropropaneug/LND1.0cis-1,3-Dichloropropeneug/LND1.0trans-1,3-Dichloropropeneug/LND1.0Ethylbenzeneug/LND1.0Iodomethaneug/LND10Methyl Butyl Ketone (2-Hexanone)ug/LND50Methylene Chlorideug/LND1.0Methyl Ethyl Ketone (2-Butanone)ug/LND1004-Methyl-2-pentanone (MIBK)ug/LND100Styreneug/LND1.01,1,1,2-Tetrachloroethaneug/LND5.0Page 49 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7070038 - EPA 5030BBlank (7070038-BLK1)Prepared & Analyzed: 07/03/17 1,1,2,2-Tetrachloroethaneug/LND3.0Tetrachloroetheneug/LND1.0Tolueneug/LND1.01,1,1-Trichloroethaneug/LND1.01,1,2-Trichloroethaneug/LND1.0Trichloroetheneug/LND1.0Trichlorofluoromethaneug/LND1.01,2,3-Trichloropropaneug/LND1.0Vinyl Acetateug/LND50Vinyl Chlorideug/LND1.0Xylenes, totalug/LND5.0ug/L50.00080-120Surr: Dibromofluoromethane9949ug/L50.00078-120Surr: 1,2-Dichloroethane-d49949ug/L50.00080-120Surr: Toluene-d89748ug/L50.00080-120Surr: 4-Bromofluorobenzene10151LCS (7070038-BS1)Prepared & Analyzed: 07/03/17 Benzeneug/L6050.00067-134120Chlorobenzeneug/L5650.00069-1221111,1-Dichloroetheneug/L6050.00058-142121Tolueneug/L5750.00068-127114Trichloroetheneug/L5250.00072-132104ug/L50.00080-120Surr: Dibromofluoromethane9949ug/L50.00078-120Surr: 1,2-Dichloroethane-d410050ug/L50.00080-120Surr: Toluene-d89748Page 50 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7070038 - EPA 5030BLCS (7070038-BS1)Prepared & Analyzed: 07/03/17 ug/L50.00080-120Surr: 4-Bromofluorobenzene9950Matrix Spike (7070038-MS1)Prepared & Analyzed: 07/03/17 Source: AAF1024-17Benzeneug/L6250.0000.067-134125Chlorobenzeneug/L5750.0000.069-1221131,1-Dichloroetheneug/L6650.0000.058-142131Tolueneug/L5950.0000.068-127117Trichloroetheneug/L5450.0000.072-132107ug/L50.00080-120Surr: Dibromofluoromethane10151ug/L50.00078-120Surr: 1,2-Dichloroethane-d410653ug/L50.00080-120Surr: Toluene-d89648ug/L50.00080-120Surr: 4-Bromofluorobenzene10150Matrix Spike Dup (7070038-MSD1)Prepared & Analyzed: 07/03/17 Source: AAF1024-17Benzeneug/L5850.0000.0967-1341158Chlorobenzeneug/L5250.0000.01369-12210581,1-Dichloroetheneug/L6150.0000.0958-1421228Tolueneug/L5550.0000.0968-1271097Trichloroetheneug/L5050.0000.01172-1321007ug/L50.00080-120Surr: Dibromofluoromethane10251ug/L50.00078-120Surr: 1,2-Dichloroethane-d410452ug/L50.00080-120Surr: Toluene-d89748ug/L50.00080-120Surr: 4-Bromofluorobenzene10050Page 51 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017Laboratory CertificationsCodeDescriptionNumberExpires812Georgia DW Inorganics Eff: 07/01/201608/30/2017GADW812Georgia DW Microbiology Eff: 07/01/201512/09/2019GADWM381North Carolina12/31/2017NCE87315FL DOH (Non-Pot. Water, Solids) Eff:: 07/01/201606/30/2018NELACE87315FL DOH NELAC (Drinking Water) Eff: 07/01/201606/30/2018NELDW98011001South Carolina08/30/2017SCT104704397-08-TXTexas03/31/2018TX460204Virginia12/14/2017VAPage 52 of 55 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyJuly 12, 2017LegendDefination of Laboratory Terms - Not Detected at levels greater than or equal to SWSL/RLNDSWSL/RLMDL - NC DENR Solid Waste Section LImit/Reporting Limit (Adjusted for DF/Prep Factor) - Method Detection LimitQualifiers - Dilution FactorDFJEstimated value less than Reporting Limit (RL) but greater than Method Detection Limit(MDL) (CLP J-Flag).Note: Unless otherwise noted, all results are reported on an as received basis.Page 53 of 55 Page 54 of 55 LOG-IN CHECKLIST BFI Waste Systems of North America, LLC Montgomery County LandfillProject: Client: Printed: 6/29/2017 12:32:16PM Environmental Monitoring & Laboratory Analysis (770) 734-4200 FAX (770) 734-4201 110 Technology Parkway, Peachtree Corners, GA 30092 PACE ANALYTICAL SERVICES, LLC. Date Received:06/28/17 16:10 Logged In By:Mohammad M. Rahman Work Order:AAF1022 OBSERVATIONS Attn: Mr. Mike Gurley #Samples: 9 #Containers: 39 4.0 4.0 YES Minimum Temp(C):Maximum Temp(C): CHECKLIST ITEMS COC included with Samples Sample Container(s) Intact Chain of Custody Complete Sample Container(s) Match COC Custody seal Intact Temperature in Compliance Sufficient Sample Volume for Analysis Zero Headspace Maintained for VOA Analyses Samples labeled preserved (If Applicable) Samples received within Allowable Hold Times Samples Received on Ice Preservation Confirmed YES YES YES N/A YES YES YES YES YES YES YES Custody Seal(s) Used:N/A Comments: Page 1 of 1Page 55 of 55 PACE ANALYTICAL SERVICES, LLC.Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201BFI Waste Systems of North America, LLCProject: Montgomery County ResampleConcord, NC 280275105 Morehead Rd.Mr. Mike GurleyWe appreciate the opportunity to provide the analytical support for your project. The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Pace Analytical Services, LLC. certifies that the following analytical results meet all requirements of the National Environmental Laboratory Accreditation Conference(NELAC).All test results relate only to the samples analyzed.Laboratory ReportProject #:6201-MW3Prepared For:Attention:October 09, 2017Report Number:AAI0862Approved:This report may not be reproduced, except in full, without written approval from Pace Analytical Services, LLC.Page 1 of 9 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyOctober 09, 2017Sample IDLaboratory IDMatrixDate SampledANALYTICAL REPORT FOR SAMPLESDate Received6201-MW3AAI0862-0109/26/17 16:08 09/27/17 13:00Ground WaterPage 2 of 9 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyOctober 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW3Ground WaterAAI0862-01AAI086209/26/17 16:08Project:Montgomery County Resample09/27/17 13:00On SiteEPA 9050A261umhos/cm1Field - Specific Conductance17090826NA1COND09/26/17 16:0809/26/17 16:08SM 4500-O G870ug/L1Dissolved Oxygen0.07090826NA0.0NA09/26/17 16:0809/26/17 16:08EPA 9040C4.61pH Units1Field - pH7090826NAPH09/26/17 16:0809/26/17 16:08NA-100mV1Field - Redox7090826NAREDOX09/26/17 16:0809/26/17 16:08SM 2550 B20.6C1Field - Temperature7090826NATEMP09/26/17 16:0809/26/17 16:08EPA 180.14.96NTU1Field - Turbidity7090826NATURB09/26/17 16:0809/26/17 16:08NA12.69feet1Field - Water Level7090826NAWL09/26/17 16:0809/26/17 16:08Metals, TotalEPA 6020B13.9ug/L1Cobalt10.07090819EPA 3005A0.267440-48-410/02/17 16:4010/02/17 11:15Metals, DissolvedEPA 6020B13.9ug/L1Cobalt10.07100081EPA 3005A0.267440-48-410/04/17 14:2910/04/17 10:00Page 3 of 9 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyOctober 09, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7090819 - EPA 3005ABlank (7090819-BLK1)Prepared & Analyzed: 10/02/17 Cobaltug/LND10.0LCS (7090819-BS1)Prepared & Analyzed: 10/02/17 Cobaltug/L10310.0100.0080-120103Matrix Spike (7090819-MS1)Prepared & Analyzed: 10/02/17 Source: AAI0873-01Cobaltug/L11410.0100.0021.475-12593Matrix Spike Dup (7090819-MSD1)Prepared & Analyzed: 10/02/17 Source: AAI0873-01Cobaltug/L12010.0100.0021.42075-125985Post Spike (7090819-PS1)Prepared & Analyzed: 10/02/17 Source: AAI0873-01Cobaltug/L113100.0021.480-12091Page 4 of 9 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyOctober 09, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Dissolved - Quality ControlBatch 7100081 - EPA 3005ABlank (7100081-BLK1)Prepared & Analyzed: 10/04/17 Cobaltug/LND10.0LCS (7100081-BS1)Prepared & Analyzed: 10/04/17 Cobaltug/L98.410.0100.0080-12098Matrix Spike (7100081-MS1)Prepared & Analyzed: 10/04/17 Source: AAI0862-01Cobaltug/L11310.0100.0013.975-12599Matrix Spike Dup (7100081-MSD1)Prepared & Analyzed: 10/04/17 Source: AAI0862-01Cobaltug/L11310.0100.0013.92075-125990.02Post Spike (7100081-PS1)Prepared & Analyzed: 10/04/17 Source: AAI0862-01Cobaltug/L520500.0013.980-120101Page 5 of 9 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyOctober 09, 2017Laboratory CertificationsCodeDescriptionNumberExpires812Georgia DW Inorganics Eff: 07/01/201606/30/2018GADW812Georgia DW Microbiology Eff: 07/01/201512/09/2019GADWM381North Carolina12/31/2017NCE87315FL DOH (Non-Pot. Water, Solids) Eff:: 07/01/201606/30/2018NELACE87315FL DOH NELAC (Drinking Water) Eff: 07/01/201606/30/2018NELDW98011001South Carolina10/31/2017SCT104704397-08-TXTexas03/31/2018TX460204Virginia12/14/2017VAPage 6 of 9 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyOctober 09, 2017LegendDefination of Laboratory Terms - Not Detected at levels greater than or equal to SWSL/RLNDSWSL/RLMDL - NC DENR Solid Waste Section LImit/Reporting Limit (Adjusted for DF/Prep Factor) - Method Detection LimitQualifiers - Dilution FactorDFNote: Unless otherwise noted, all results are reported on an as received basis.Page 7 of 9 Page 8 of 9 Page 9 of 9