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HomeMy WebLinkAbout6201_MontgomeryCountyMSWLF_GWMR_20170222 Groundwater Statistical Analysis Report First Semi-Annual 2017 Sampling Event Montgomery County Landfill Mt. Gilead, North Carolina February 2017 Prepared by: 10 Quiet Brook Court 314-496-4654 St. Charles, MO 63303 www.jettenviro.com TABLE OF CONTENTS 1.0 INTRODUCTION .............................................................................1  2.0 SITE BACKGROUND AND MONITORING NETWORK ................1  3.0 SITE HYDROGEOLOGY ................................................................2  4.0 DATA EVALUATION ......................................................................2  5.0 STATISTICAL PROCEDURES .......................................................3  5.1 Outlier Analysis ...........................................................................3  5.2 Intra-Well Prediction Intervals ....................................................3  5.3 Statistical Results Summary .......................................................3  6.0 CONCLUSIONS ..............................................................................4  TABLES Table 1 Groundwater Monitoring Program Table 2 Analytical Data Summary, First Semi-Annual 2017 Event APPENDICES Appendix A Potentiometric Surface Map Appendix B Statistical Evaluations Appendix C Laboratory Analytical Report & Field Sampling Forms Groundwater Statistical Analysis Report Montgomery County Landfill, North Carolina 1 1.0 INTRODUCTION On behalf of Montgomery County Landfill, Jett Environmental Consulting statistically evaluated the First Semi-Annual 2017 water quality monitoring data. Sampling and analytical testing was performed by Pace Analytical Services, Inc. The statistical analysis software package utilized, SanitasTM, follows a documented decision logic that incorporates the following applicable document: USEPA “Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance” (March 2009). 2.0 SITE BACKGROUND AND MONITORING NETWORK The Montgomery County Landfill is a closed municipal solid waste facility. Per the site’s Permit (No. 62- 01) and in compliance with North Carolina Department of Environmental Quality (NCDEQ) Solid Waste Management Regulations, Section .1600 “Requirements for Municipal Solid Waste Landfill Facilities,” Jett Environmental Consulting statistically evaluated parameters from the First Semi-Annual (January) 2017 event using intra-well prediction interval analysis. Prediction intervals are considered a powerful tool for groundwater statistical analysis, when feasible, due to their inherent low false negative and false positive rates utilizing confirmatory resampling, if necessary. Groundwater monitoring was initiated in January 1994. The historical statistical database is complete dating back to at least January 2007. Background is defined as samples collected from each respective well from January 2007 through the July 2014 event. Background data will be reviewed every year or two to determine if an update is warranted. The parameters subject to statistical evaluation during detection monitoring are noted in NCDEQ Section .1633 as constituents listed in Appendix I of 40 CFR Part 258 “Appendix I Constituents for Detection Monitoring”. Table 1 lists the site’s groundwater monitoring wells. Each of the wells was sampled during the January 2017 event. In correspondence dated January 28, 2016, NCDEQ approved a request to remove mercury from the list of required analysis due to the lack of NC 2L Groundwater Standard exceedances. Therefore, mercury was not sampled/analyzed during the January 2017 event. In addition to the groundwater monitoring, the site has a surface water monitoring network consisting of one upstream surface water sampling point (SW-1) and one downstream point (SW-2). These points are sampled semi-annually for the 40 CFR Part 258 Appendix I list in conjunction with the groundwater monitoring wells. During the January 2017 event, both surface water monitoring points were able to be sampled. Based on the results of statistical evaluations of the groundwater monitoring data, an Alternate Source Demonstration (ASD) was submitted to the NCDEQ in February 1997 in response to confirmed statistically significant detections of mercury and 1,1-dichloroethane at monitoring well MW-4. The ASD attributed the low mercury concentrations detected at MW-4 to natural variability in the geologic medium at the facility, and the 1,1-dichloroethane concentrations reported at MW-4 to sampling and/or analysis error. The ASD was approved by NCDEQ in a letter dated May 22, 1997. A second ASD was submitted to NCDEQ on January 30, 2003, in response to detections of benzene and trichloroethene at MW-2 during the October 2002 event. In a letter dated February 13, 2003 NCDEQ requested that an Assessment Monitoring Program be implemented at the Montgomery County Landfill. Assessment Monitoring, as outlined in NCAC Title 15A 13B.1634, was implemented on March 19, 2003. Laboratory analytical results from the initial Appendix II sampling event indicated that there were no new Appendix II detections for the facility. In general, the detected organic constituents and concentrations were consistent with a landfill gas source. In response to comments from NCDEQ concerning the January 30, 2003 ASD, an addendum to the January 2003 ASD was submitted to NCDEQ in August 2003. Based on analysis of water quality, leachate indicator parameters, and isotopic analyses, the addendum concluded that the volatile organic compounds (VOCs) Groundwater Statistical Analysis Report Montgomery County Landfill, North Carolina 2 detected in the uppermost aquifer beneath the facility did not appear to have originated from a leachate release at the closed landfill. In a letter dated October 25, 2006 from NCDEQ, the ASD and addendum were not approved since recent detected organic constituents were different from those prior to the ASD. A third ASD was submitted on December 5, 2007 to address the detections of the following VOCs: benzene; 1,4-dichlorobenzene; chlorobenzene; 1,2-dichlorobenzene; 1,1-dichloroethane; cis-1,2-dichloroethene; methylene chloride; tetrachloroethene; toluene; trichloroethene; and vinyl chloride, in background well MW- 1R and downgradient wells MW-2 and MW-4. The ASD, which attributed the VOC detections to landfill gas-to-groundwater impacts, was approved by NCDEQ on January 28, 2008, and permitted the facility to revert to the Detection Monitoring Program. The number of VOC detections and the VOC concentrations have declined in more recent years. 3.0 SITE HYDROGEOLOGY The following site hydrogeology summary was taken from the Second Semi-Annual Water Quality Monitoring Report of 2012, dated September 2012 by Joyce Engineering. The uppermost groundwater beneath the facility is present in a shallow, unconfined aquifer comprised of partially weathered, fractured, meta-volcanic rock. Groundwater occurs at depths of approximately 40 feet below grade along the northern upgradient side of the waste disposal area, and at a depth of less than 10 feet below grade along the perimeter downgradient boundary. The groundwater flow in the uppermost aquifer beneath the site is towards the southwest, with the flow appearing to converge on the southerly flowing tributary of Rocky Creek located west of the waste areas. Appendix A provides a potentiometric surface map for the site utilizing groundwater level data from the January 2017 event. Groundwater flow direction for the January 2017 event was to the southwest, consistent with past events. Groundwater flow rate for the January 2017 event was estimated at 36 feet/year, consistent with past events. Flow rate calculations are available in Appendix A. 4.0 DATA EVALUATION The analytical results for the January 2017 event for the groundwater and surface water samples are summarized on Table 2. As presented in Table 2, three Appendix I inorganic constituents were detected in groundwater samples at quantified concentrations above the detection limits specified in the NC Solid Waste Section Reporting Limits (SWSLs):  Barium: MW-1R, MW-2, and MW-4;  Cobalt: MW-4; and  Zinc: MW-1R, MW-2, and MW-4. Two Appendix I VOCs were detected during the January 2017 sampling event: 1,4-dichlorobenzene and benzene at MW-4. The VOC constituents and concentrations are consistent with historical data, and likely related to landfill gas as presented in the ASD approved by NCDEQ on January 28, 2008. As shown on Table 2, only benzene at MW-4 exceeded a NC 2L Standard. Benzene at MW-4 (1.4 ug/L) was above the 2L Standard (1 ug/L) and below the National Primary Drinking Water Standard Maximum Contaminant Level (MCL) of 5 ug/L. Consistent with past events, three Appendix I results (barium, cobalt, and benzene at MW-4) were detected above a NC Solid Waste Section Groundwater Protection Standard (NC GWPS) or NC 2L Standard during the January 2017 sampling event. The benzene detected at MW-4 is believed to be attributed to landfill gas as described in the ASD approved by NCDEQ on January 28, 2008. Groundwater Statistical Analysis Report Montgomery County Landfill, North Carolina 3 No NC 2B Surface Water Standards were exceeded for surface water samples collected during the First Semi-Annual 2017 event. 5.0 STATISTICAL PROCEDURES Statistical analyses (i.e. intra-well prediction limits) were performed to establish background concentrations and determine if the NC GWPS/NC 2L value-to-value exceedances for barium and cobalt at MW-4 exhibited statistically significant increases. 5.1 Outlier Analysis The background data were evaluated for the presence of statistical outliers. Methodologies for determining a statistical outlier are defined in the EPA document, Statistical Analysis of Ground-Water Monitoring Data at RCRA Facilities – Unified Guidance (March 2009). Any statistical outliers that were determined were removed from the background data set prior to performing prediction interval statistical analysis. According to the EPA guidance documents above, data that are not normally or log-normally distributed are not recommended for evaluation of outliers. In cases where the data were not normally or log-normally distributed, outliers were not removed from the data set. Background outliers flagged for removal are identified on the statistical plots provided in Appendix B. 5.2 Intra-Well Prediction Intervals The prediction interval is a statistical method used to compare a single observation to a group of observations. The prediction interval is calculated to include observations from the same population with a specified confidence. In groundwater monitoring, a prediction interval approach may be used to make comparisons between background and compliance data. The interval is developed to contain all future observations, within a certain probability. For the site, intra-well prediction intervals have been developed based on a 99% confidence that future observations will fall within the range. If any future observation exceeds the prediction interval, this is considered statistically significant evidence that the observation is not representative of the background group. During parametric prediction interval analysis, the mean and the standard deviation are calculated for the raw or transformed background data. The number of comparison observations, K, is defined to be included in the interval. If less than 15% of the background observations are nondetects, the nondetects are replaced with one half of the reporting limit prior to performing the analysis. If more than 15% but less than 50% of the background data are below the reporting limit, the data’s sample mean and standard deviation are adjusted according to the Kaplan-Meier method. However, when the background data are not transformed- normal or contain greater than 50% observations below the reporting limit, SanitasTM automatically constructs a non-parametric prediction interval. During non-parametric analysis, the highest value from the background data is used to set the upper limit of the prediction interval. Summary tables and graphs for the intra-well prediction interval analysis are available in Appendix B. Included in Appendix B are time series plots for each of the inorganic constituents and organic detections. Appendix C contains a copy of the laboratory analytical report and field sampling forms for the January 2017 event. 5.3 Statistical Results Summary For the January 2017 event, one inorganic statistically significant increase was exhibited for the groundwater monitoring wells: barium at MW-4. The January 2017 barium concentration (957 ug/L) was above the statistical limit (790 ug/L) and above the 2L Standard (700 ug/L), however was well below the MCL of 2,000 ug/L. As shown on the time series graph (see Appendix B), barium concentrations at MW- 4 trend to follow seasonal fluctuations, with concentrations higher during the January events and lower during the July events. Groundwater Statistical Analysis Report Montgomery County Landfill, North Carolina 4 6.0 CONCLUSIONS For the January 2017 groundwater monitoring event, one inorganic concentration that was detected above an NC GWPS/NC 2L was determined to exhibit a statistically significant increase above background concentrations: barium at MW-4. The January 2017 barium concentration at MW-4 was well below the MCL. The barium concentrations at MW-4 have been reported at stable levels over the last five years of monitoring. Two Appendix I VOCs were detected during the January 2017 sampling event: 1,4-dichlorobenzene and benzene at MW-4. The VOC constituents and concentrations are consistent with historical data, and likely related to landfill gas as presented in the ASD approved by NCDEQ on January 28, 2008. As shown on Table 2, only benzene at MW-4 exceeded a NC 2L Standard. Benzene at MW-4 (1.4 ug/L) was above the 2L Standard (1 ug/L) and below the MCL of 5 ug/L. As shown on the attached time series plots (Appendix B), the January 2017 VOC concentrations at MW-4 are consistent with concentrations reported historically. No NC 2B Surface Water Standards were exceeded for surface water during the First Semi-Annual 2017 event. It is recommended that the Montgomery County Landfill continue monitoring in accordance with the requirements for Detection Monitoring as outlined in Title 15A NCAC 13B .1633. The next event is tentatively scheduled for July 2017. TABLES UPGRADIENT WELL DOWNGRADIENT WELLS MW-1R MW-2, MW-3, MW-4 TABLE 1 MONTGOMERY COUNTY LANDFILL GROUNDWATER MONITORING PROGRAM FIRST SEMI-ANNUAL 2017 EVENT Constituent Units NC 2L Standard NC GWPS MDL SWSL MW-1R MW-2 MW-3 MW-4 Antimony, Total ug/L NE 1 0.85 6 J 0.85 <6 <6 <6 Arsenic, Total ug/L 10 NE 1.64 10 J 2.78 J 2.19 <10 J 4.2 Barium, Total ug/L 700 NE 0.44 100 110 109 J 84 957 Beryllium, Total ug/L NE 4 0.08 1 <1 J 0.52 J 0.24 <1 Cadmium, Total ug/L 2NE0.07 1 J 0.19 <1 <1 J 0.47 Chromium, Total ug/L 10 NE 0.94 10 J 2.15 J 3.97 J 2.57 <10 Cobalt, Total ug/L NE 1 0.52 10 <10 J 1.02 J 7.54 33.9 Copper, Total ug/L 1,000 NE 0.54 10 J 9.08 J 2.27 J 3.47 J 1.15 Dissolved Oxygen (Field) ug/L NE NE 0 0 2860 4820 2080 2850 Lead, Total ug/L 15 NE 0.12 10 J 1.54 J 5.61 J 4.09 J 0.15 Nickel, Total ug/L 100 NE 0.55 50 J 2.79 J 2.33 J 3.32 J 9.57 pH (Field) su NE NE NE NE 5.66 4.01 4.25 5.21 Redox (Field) mV NE NE NE NE 110 189 210 68 Selenium, Total ug/L 20 NE 1 10 J 1.87 J 2.86 <10 <10 Silver, Total ug/L 20 NE 0.48 10 <10 J 0.5 <10 J 1.31 Specific Conductance (Field) umhos/cm NE NE 1 1 282 49 126 560 Temperature (Field) Deg-C NE NE NE NE 14.9 13.7 13.7 14 Thallium, Total ug/L NE 0.28 0.21 5.5 J 0.27 <5.5 <5.5 <5.5 Turbidity (Field) NTU NE NE NE NE 1.48 74 4.7 1.11 Vanadium, Total ug/L NE 0.3 7.14 25 <25 <25 <25 <25 Zinc, Total ug/L 1,000 NE 2.1 10 20.6 17.9 J 9.05 38.5 Constituent (ug/L) Units NC 2L Standard NC GWPS MDL SWSL MW-1R MW-2 MW-3 MW-4 1,1-Dichloroethane ug/L 6NE0.4 5 <5 J 0.9 <5 J 0.6 1,4-Dichlorobenzene ug/L 6NE0.6 1 <1 <1 <1 2.5 Benzene ug/L 1NE0.2 1 <1 <1 <1 1.4 Chlorobenzene ug/L 50 NE 0.5 3 <3 <3 <3 J 1.2 cis-1,2-Dichloroethene ug/L 70 NE 0.7 5 <5 J 0.7 <5 J 1.4 Constituent (ug/L) Units NC 2B Standard MDL SWSL SW-1 SW-2 Antimony, Total ug/L NE 0.85 6 <6 <6 Arsenic, Total ug/L 10 1.64 10 <10 <10 Barium, Total ug/L 1,000 0.44 100 J 87.3 J 45.3 Beryllium, Total ug/L 6.5 0.08 1 J 0.1 <1 Cadmium, Total ug/L 2 0.07 1 <1 <1 Chromium, Total ug/L 20 0.94 10 J 0.99 <10 Cobalt, Total ug/L NE 0.52 10 J 4.24 J 0.96 Copper, Total ug/L 3 0.54 10 J 1.01 J 1.13 Dissolved Oxygen (Field) ug/L NE 0 0 4050 6570 Lead, Total ug/L 25 0.12 10 J 1.06 J 0.92 Nickel, Total ug/L 8 0.55 50 J 1.31 J 0.9 pH (Field) su NE NE NE 4.79 5.07 Redox (Field) mV NE NE NE 300 203 Selenium, Total ug/L 5 110<10<10 Silver, Total ug/L 0.06 0.48 10 <10 <10 Specific Conductance (Field) umhos/cm NE 118673 Temperature (Field) Deg-C NE NE NE 12.5 12.4 Thallium, Total ug/L NE 0.21 5.5 <5.5 <5.5 Turbidity (Field) NTU NE NE NE 14 6.24 Vanadium, Total ug/L NE 7.14 25 <25 <25 Zinc, Total ug/L 50 2.1 10 J 9.3 J 6.75 Constituent (ug/L) Units NC 2B Standard MDL SWSL SW-1 SW-2 Acetone ug/L 2,000 100 8.2 <100 J 20 Methyl Ethyl Ketone (2-Butanone) ug/L 20,000 100 3.2 <100 J 14 NE: Denotes a NC 2L Standard, NC 2B Standard, or NC GWPS is not established. J: Denotes Sample result above the MDL but below the SWSL; estimated value; value may not be accurate. For VOCs, only the VOCs detected during this event are displayed on the table. Denotes result above an SWSL, and NC 2L, NC 2B, or NC GWPS: TABLE 2 ANALYTICAL DATA SUMMARY, FIRST SEMI-ANNUAL 2017 EVENT MONTGOMERY COUNTY LANDFILL GROUNDWATER SAMPLES SURFACE WATER SAMPLES APPENDICES APPENDIX A POTENTIOMETRIC SURFACE MAP Well Top of PVC Casing Elevation (fmsl)1 Depth to Water (ft)2 Groundwater Elevation (fmsl) MW-1R 695.65 41.45 654.20 MW-2 643.46 4.55 638.91 MW-3 622.94 4.17 618.77 MW-4 609.59 3.90 605.69 Note 1: Top of PVC Casing Elevations from Table 3 of the Second Semi-Annual Water Quality Monitoring Report of 2012, dated September 2012 by Joyce Engineering. Note 2: Depth to water measured by Pace Analytical Services, Inc. on January 23, 2017. Groundwater Elevation Summary Table Montgomery County Landfill Groundwater Flow Velocity Calculations Montgomery County Landfill First Semi-Annual 2017 Event Velocity V = [(k)(i)]/(n) V = [(0.441 ft/day)(0.0278 ft/ft]/0.125 V = 0.098 ft/day V = 36 ft/year Hydraulic conductivity and effective porosity values from the following document: Second Semi-Annual Water Quality Monitoring Report of 2012, Montgomery County Landfill. Dated August 20, 2012 by Joyce Engineering. Gradient (i) is from the average gradient at site using the potentiometric surface map from Point A to Point B. Gradient (i) = Change in Groundwater Elevation along Flow Path i: From Point A (650 contour) to Point B (610 contour) = 40 ft / 1,440 ft = 0.0278 ft/ft APPENDIX B STATISTICAL EVALUATIONS ConstituentWellUpper Lim.Lower Lim.DateObserv.Sig.Bg NBg MeanStd. Dev.%NDsND Adj.TransformAlphaMethodCobalt Total (ug/L) MW-4 42 n/a 1/23/2017 33.9 No 16 26.36 14.09 0 None No 0.026 Param Intra 1 of 2Barium Total (ug/L) MW-4 790 n/a 1/23/2017 957 Yes 16 367837 225409 0 Nonex^2 0.026 Param Intra 1 of 2Prediction LimitMontgomery County LF Client: RSI Data: MontgomeryCounty Printed 2/14/2017, 9:47 AM 020040060080010001/10/071/12/091/15/111/17/131/20/151/23/17MW-4 backgroundMW-4 complianceLimit = 790Prediction LimitIntrawell ParametricConstituent: Barium Total Analysis Run 2/14/2017 9:46 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.30 Software licensed to Jett Environmental Consulting. UGug/LBackground Data Summary (based on square transformation): Mean=367837, Std. Dev.=225409, n=16. Normality test: Shapiro Wilk @alpha = 0.05, calculated = 0.9336, critical = 0.887. Kappa = 1.13 (c=2, w=1, 1 of 2, event alpha = 0.05132). Report alpha = 0.026. EPA 1989 outlier screening was performed on the background data. No background outliers were found.Exceeds Limit 010203040501/10/071/12/091/15/111/17/131/20/151/23/17MW-4 backgroundMW-4 complianceLimit = 42Prediction LimitIntrawell ParametricConstituent: Cobalt Total Analysis Run 2/14/2017 9:46 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.30 Software licensed to Jett Environmental Consulting. UGug/LBackground Data Summary: Mean=26.36, Std. Dev.=14.09, n=16. Normality test: Shapiro Wilk @alpha = 0.05, calculated = 0.8927, critical = 0.887. Kappa = 1.13 (c=2, w=1, 1 of 2, event alpha = 0.05132). Report alpha = 0.026. EPA 1989 outlier screening was performed on the background data. No background outliers were found.Within Limit TIME SERIES TREND ANALYSIS 01.22.43.64.861/10/071/12/091/15/111/17/131/20/151/23/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Antimony Total Analysis Run 2/14/2017 9:56 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.30 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 0481216201/10/071/12/091/15/111/17/131/20/151/23/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Arsenic Total Analysis Run 2/14/2017 9:56 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.30 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 020040060080010001/10/071/12/091/15/111/17/131/20/151/23/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Barium Total Analysis Run 2/14/2017 9:56 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.30 Software licensed to Jett Environmental Consulting. UGug/L 00.20.40.60.811/10/071/12/091/15/111/17/131/20/151/23/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Beryllium Total Analysis Run 2/14/2017 9:56 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.30 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 00.61.21.82.431/10/071/12/091/15/111/17/131/20/151/23/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Cadmium Total Analysis Run 2/14/2017 9:56 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.30 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 02468101/10/071/12/091/15/111/17/131/20/151/23/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Chromium Total Analysis Run 2/14/2017 9:56 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.30 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 010203040501/10/071/12/091/15/111/17/131/20/151/23/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Cobalt Total Analysis Run 2/14/2017 9:56 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.30 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 010203040501/10/071/12/091/15/111/17/131/20/151/23/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Copper Total Analysis Run 2/14/2017 9:56 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.30 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 0481216201/10/071/12/091/15/111/17/131/20/151/23/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Lead Total Analysis Run 2/14/2017 9:56 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.30 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 010203040501/10/071/12/091/15/111/17/131/20/151/23/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Nickel Total Analysis Run 2/14/2017 9:56 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.30 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 02468101/10/071/12/091/15/111/17/131/20/151/23/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Selenium Total Analysis Run 2/14/2017 9:56 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.30 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 02468101/10/071/12/091/15/111/17/131/20/151/23/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Silver Total Analysis Run 2/14/2017 9:56 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.30 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 01.22.43.64.861/10/071/12/091/15/111/17/131/20/151/23/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Thallium Total Analysis Run 2/14/2017 9:56 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.30 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 06121824301/10/071/12/091/15/111/17/131/20/151/23/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Vanadium Total Analysis Run 2/14/2017 9:56 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.30 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 040801201602001/10/071/12/091/15/111/17/131/20/151/23/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Zinc Total Analysis Run 2/14/2017 9:56 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.30 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 01.22.43.64.861/10/071/12/091/15/111/17/131/20/151/23/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: Benzene Analysis Run 2/14/2017 10:00 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.30 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. 00.81.62.43.241/10/071/12/091/15/111/17/131/20/151/23/17MW-1R (bg)MW-2MW-3MW-4Time SeriesConstituent: 14-Dichlorobenzene Analysis Run 2/14/2017 9:59 AMMontgomery County LF Client: RSI Data: MontgomeryCountySanitas™ v.9.5.30 Software licensed to Jett Environmental Consulting. UGug/LHollow symbols indicate censored values. APPENDIX C LABORATORY ANALYTICAL REPORT & FIELD SAMPLING FORMS PACE ANALYTICAL SERVICES, LLC.Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201BFI Waste Systems of North America, LLCProject: Montgomery County LandfillConcord, NC 280275105 Morehead Rd.Mr. Mike GurleyWe appreciate the opportunity to provide the analytical support for your project. The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Pace Analytical Services, LLC. certifies that the following analytical results meet all requirements of the National Environmental Laboratory Accreditation Conference(NELAC).All test results relate only to the samples analyzed.Laboratory ReportProject #:[none]Prepared For:Attention:February 09, 2017Report Number:AAA0878Approved:This report may not be reproduced, except in full, without written approval from Pace Analytical Services, LLC.Page 1 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017Sample IDLaboratory IDMatrixDate SampledANALYTICAL REPORT FOR SAMPLESDate Received6201-MW1RAAA0878-0101/23/17 15:48 01/26/17 13:50Ground Water6201-MW2AAA0878-0201/23/17 15:1101/26/17 13:50Ground Water6201-MW3AAA0878-0301/23/17 14:02 01/26/17 13:50Ground Water6201-MW4AAA0878-0401/23/17 14:33 01/26/17 13:50Ground Water6201-DuplicateAAA0878-0501/23/17 00:00 01/26/17 13:50Ground Water6201-Field BlankAAA0878-0601/23/17 15:50 01/26/17 13:50Water6201-Trip BlankAAA0878-0701/23/17 00:00 01/26/17 13:50Water6201-SW1AAA0878-0801/23/17 13:49 01/26/17 13:50Surface Water6201-SW2AAA0878-0901/23/17 14:15 01/26/17 13:50Surface WaterPage 2 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW1RGround WaterAAA0878-01AAA087801/23/17 15:48Project:Montgomery County Landfill01/26/17 13:50On SiteEPA 9050A282umhos/cm1Field - Specific Conductance17010773NA1COND01/23/17 15:4801/23/17 15:48SM 4500-O G2860ug/L1Dissolved Oxygen0.07010773NA0.0NA01/23/17 15:4801/23/17 15:48EPA 9040C5.66pH Units1Field - pH7010773NAPH01/23/17 15:4801/23/17 15:48NA110mV1Field - Redox7010773NAREDOX01/23/17 15:4801/23/17 15:48SM 2550 B14.9C1Field - Temperature7010773NATEMP01/23/17 15:4801/23/17 15:48EPA 180.11.48NTU1Field - Turbidity7010773NATURB01/23/17 15:4801/23/17 15:48NA41.45feet1Field - Water Level7010773NAWL01/23/17 15:4801/23/17 15:48Metals, TotalEPA 6020B0.85ug/L1Antimony6.00J7020139EPA 3005A0.857440-36-002/07/17 19:4202/06/17 18:25EPA 6020B2.78ug/L1Arsenic10.0J7020139EPA 3005A1.647440-38-202/07/17 19:4202/06/17 18:25EPA 6020B110ug/L1Barium1007020139EPA 3005A0.447440-39-302/07/17 19:4202/06/17 18:25NDEPA 6020Bug/L1Beryllium1.007020139EPA 3005A0.087440-41-702/08/17 13:3102/06/17 18:25EPA 6020B0.19ug/L1Cadmium1.00J7020139EPA 3005A0.077440-43-902/07/17 19:4202/06/17 18:25EPA 6020B2.15ug/L1Chromium10.0J7020139EPA 3005A0.947440-47-302/07/17 19:4202/06/17 18:25NDEPA 6020Bug/L1Cobalt10.07020139EPA 3005A0.527440-48-402/07/17 19:4202/06/17 18:25EPA 6020B9.08ug/L1Copper10.0J7020139EPA 3005A0.547440-50-802/07/17 19:4202/06/17 18:25EPA 6020B1.54ug/L1Lead10.0J7020139EPA 3005A0.127439-92-102/07/17 19:4202/06/17 18:25EPA 6020B2.79ug/L1Nickel50.0J7020139EPA 3005A0.557440-02-002/07/17 19:4202/06/17 18:25EPA 6020B1.87ug/L1Selenium10.0J7020139EPA 3005A1.007782-49-202/07/17 19:4202/06/17 18:25NDEPA 6020Bug/L1Silver10.07020139EPA 3005A0.487440-22-402/07/17 19:4202/06/17 18:25Page 3 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW1RGround WaterAAA0878-01AAA087801/23/17 15:48Project:Montgomery County Landfill01/26/17 13:50Metals, TotalEPA 6020B0.27ug/L1Thallium5.50J7020139EPA 3005A0.217440-28-002/07/17 19:4202/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020139EPA 3005A7.147440-62-202/07/17 19:4202/06/17 18:25EPA 6020B20.6ug/L1Zinc10.07020139EPA 3005A2.107440-66-602/07/17 19:4202/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010703EPA 5030B8.267-64-101/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Acrylonitrile2007010703EPA 5030B2.5107-13-101/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Benzene1.07010703EPA 5030B0.271-43-201/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Bromochloromethane3.07010703EPA 5030B0.574-97-501/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Bromodichloromethane1.07010703EPA 5030B0.475-27-401/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Bromoform3.07010703EPA 5030B0.675-25-201/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Bromomethane107010703EPA 5030B1.074-83-901/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Carbon Disulfide1007010703EPA 5030B0.875-15-001/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Carbon Tetrachloride1.07010703EPA 5030B0.456-23-501/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Chlorobenzene3.07010703EPA 5030B0.5108-90-701/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Chloroethane107010703EPA 5030B0.575-00-301/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Chloroform5.07010703EPA 5030B0.667-66-301/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Chloromethane1.07010703EPA 5030B0.474-87-301/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Dibromochloromethane3.07010703EPA 5030B0.3124-48-101/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010703EPA 5030B0.696-12-801/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L11,2-Dibromoethane1.07010703EPA 5030B0.3106-93-401/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Dibromomethane107010703EPA 5030B0.674-95-301/27/17 12:1701/27/17 08:50Page 4 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW1RGround WaterAAA0878-01AAA087801/23/17 15:48Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010703EPA 5030B0.595-50-101/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010703EPA 5030B0.6106-46-701/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010703EPA 5030B1.6110-57-601/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L11,1-Dichloroethane5.07010703EPA 5030B0.475-34-301/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L11,2-Dichloroethane1.07010703EPA 5030B0.7107-06-201/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L11,1-Dichloroethene5.07010703EPA 5030B0.775-35-401/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010703EPA 5030B0.7156-59-201/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010703EPA 5030B0.5156-60-501/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L11,2-Dichloropropane1.07010703EPA 5030B0.678-87-501/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010703EPA 5030B0.210061-01-501/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010703EPA 5030B0.310061-02-601/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Ethylbenzene1.07010703EPA 5030B0.4100-41-401/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Iodomethane107010703EPA 5030B3.174-88-401/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010703EPA 5030B0.9591-78-601/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Methylene Chloride1.07010703EPA 5030B0.575-09-201/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010703EPA 5030B3.278-93-301/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010703EPA 5030B0.9108-10-101/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Styrene1.07010703EPA 5030B0.5100-42-501/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010703EPA 5030B0.3630-20-601/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010703EPA 5030B0.579-34-501/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Tetrachloroethene1.07010703EPA 5030B0.8127-18-401/27/17 12:1701/27/17 08:50Page 5 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW1RGround WaterAAA0878-01AAA087801/23/17 15:48Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Toluene1.07010703EPA 5030B0.3108-88-301/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010703EPA 5030B0.471-55-601/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010703EPA 5030B0.679-00-501/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Trichloroethene1.07010703EPA 5030B0.379-01-601/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Trichlorofluoromethane1.07010703EPA 5030B0.575-69-401/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010703EPA 5030B0.596-18-401/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Vinyl Acetate507010703EPA 5030B0.4108-05-401/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Vinyl Chloride1.07010703EPA 5030B0.675-01-401/27/17 12:1701/27/17 08:50NDEPA 8260Bug/L1Xylenes, total5.07010703EPA 5030B1.41330-20-701/27/17 12:1701/27/17 08:50EPA 8260B91 %Surr: Dibromofluoromethane7010703EPA 5030B1868-53-701/27/17 12:1701/27/17 08:5080-120EPA 8260B102 %Surr: 1,2-Dichloroethane-d47010703EPA 5030B17060-07-001/27/17 12:1701/27/17 08:5078-120EPA 8260B103 %Surr: Toluene-d87010703EPA 5030B2037-26-501/27/17 12:1701/27/17 08:5080-120EPA 8260B101 %Surr: 4-Bromofluorobenzene7010703EPA 5030B460-00-401/27/17 12:1701/27/17 08:5080-120Page 6 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW2Ground WaterAAA0878-02AAA087801/23/17 15:11Project:Montgomery County Landfill01/26/17 13:50On SiteEPA 9050A49umhos/cm1Field - Specific Conductance17010773NA1COND01/23/17 15:1101/23/17 15:11SM 4500-O G4820ug/L1Dissolved Oxygen0.07010773NA0.0NA01/23/17 15:1101/23/17 15:11EPA 9040C4.01pH Units1Field - pH7010773NAPH01/23/17 15:1101/23/17 15:11NA189mV1Field - Redox7010773NAREDOX01/23/17 15:1101/23/17 15:11SM 2550 B13.7C1Field - Temperature7010773NATEMP01/23/17 15:1101/23/17 15:11EPA 180.174.0NTU1Field - Turbidity7010773NATURB01/23/17 15:1101/23/17 15:11NA4.55feet1Field - Water Level7010773NAWL01/23/17 15:1101/23/17 15:11Metals, TotalNDEPA 6020Bug/L1Antimony6.007020139EPA 3005A0.857440-36-002/07/17 19:4802/06/17 18:25EPA 6020B2.19ug/L1Arsenic10.0J7020139EPA 3005A1.647440-38-202/07/17 19:4802/06/17 18:25EPA 6020B109ug/L1Barium1007020139EPA 3005A0.447440-39-302/07/17 19:4802/06/17 18:25EPA 6020B0.52ug/L1Beryllium1.00J7020139EPA 3005A0.087440-41-702/07/17 19:4802/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020139EPA 3005A0.077440-43-902/07/17 19:4802/06/17 18:25EPA 6020B3.97ug/L1Chromium10.0J7020139EPA 3005A0.947440-47-302/07/17 19:4802/06/17 18:25EPA 6020B1.02ug/L1Cobalt10.0J7020139EPA 3005A0.527440-48-402/07/17 19:4802/06/17 18:25EPA 6020B2.27ug/L1Copper10.0J7020139EPA 3005A0.547440-50-802/07/17 19:4802/06/17 18:25EPA 6020B5.61ug/L1Lead10.0J7020139EPA 3005A0.127439-92-102/07/17 19:4802/06/17 18:25EPA 6020B2.33ug/L1Nickel50.0J7020139EPA 3005A0.557440-02-002/07/17 19:4802/06/17 18:25EPA 6020B2.86ug/L1Selenium10.0J7020139EPA 3005A1.007782-49-202/07/17 19:4802/06/17 18:25EPA 6020B0.50ug/L1Silver10.0J7020139EPA 3005A0.487440-22-402/07/17 19:4802/06/17 18:25Page 7 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW2Ground WaterAAA0878-02AAA087801/23/17 15:11Project:Montgomery County Landfill01/26/17 13:50Metals, TotalNDEPA 6020Bug/L1Thallium5.507020139EPA 3005A0.217440-28-002/07/17 19:4802/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020139EPA 3005A7.147440-62-202/07/17 19:4802/06/17 18:25EPA 6020B17.9ug/L1Zinc10.07020139EPA 3005A2.107440-66-602/07/17 19:4802/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010703EPA 5030B8.267-64-101/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Acrylonitrile2007010703EPA 5030B2.5107-13-101/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Benzene1.07010703EPA 5030B0.271-43-201/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Bromochloromethane3.07010703EPA 5030B0.574-97-501/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Bromodichloromethane1.07010703EPA 5030B0.475-27-401/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Bromoform3.07010703EPA 5030B0.675-25-201/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Bromomethane107010703EPA 5030B1.074-83-901/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Carbon Disulfide1007010703EPA 5030B0.875-15-001/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Carbon Tetrachloride1.07010703EPA 5030B0.456-23-501/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Chlorobenzene3.07010703EPA 5030B0.5108-90-701/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Chloroethane107010703EPA 5030B0.575-00-301/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Chloroform5.07010703EPA 5030B0.667-66-301/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Chloromethane1.07010703EPA 5030B0.474-87-301/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Dibromochloromethane3.07010703EPA 5030B0.3124-48-101/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010703EPA 5030B0.696-12-801/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L11,2-Dibromoethane1.07010703EPA 5030B0.3106-93-401/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Dibromomethane107010703EPA 5030B0.674-95-301/27/17 12:4201/27/17 08:50Page 8 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW2Ground WaterAAA0878-02AAA087801/23/17 15:11Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010703EPA 5030B0.595-50-101/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010703EPA 5030B0.6106-46-701/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010703EPA 5030B1.6110-57-601/27/17 12:4201/27/17 08:50EPA 8260B0.9ug/L11,1-Dichloroethane5.0J7010703EPA 5030B0.475-34-301/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L11,2-Dichloroethane1.07010703EPA 5030B0.7107-06-201/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L11,1-Dichloroethene5.07010703EPA 5030B0.775-35-401/27/17 12:4201/27/17 08:50EPA 8260B0.7ug/L1cis-1,2-Dichloroethene5.0J7010703EPA 5030B0.7156-59-201/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010703EPA 5030B0.5156-60-501/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L11,2-Dichloropropane1.07010703EPA 5030B0.678-87-501/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010703EPA 5030B0.210061-01-501/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010703EPA 5030B0.310061-02-601/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Ethylbenzene1.07010703EPA 5030B0.4100-41-401/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Iodomethane107010703EPA 5030B3.174-88-401/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010703EPA 5030B0.9591-78-601/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Methylene Chloride1.07010703EPA 5030B0.575-09-201/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010703EPA 5030B3.278-93-301/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010703EPA 5030B0.9108-10-101/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Styrene1.07010703EPA 5030B0.5100-42-501/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010703EPA 5030B0.3630-20-601/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010703EPA 5030B0.579-34-501/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Tetrachloroethene1.07010703EPA 5030B0.8127-18-401/27/17 12:4201/27/17 08:50Page 9 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW2Ground WaterAAA0878-02AAA087801/23/17 15:11Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Toluene1.07010703EPA 5030B0.3108-88-301/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010703EPA 5030B0.471-55-601/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010703EPA 5030B0.679-00-501/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Trichloroethene1.07010703EPA 5030B0.379-01-601/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Trichlorofluoromethane1.07010703EPA 5030B0.575-69-401/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010703EPA 5030B0.596-18-401/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Vinyl Acetate507010703EPA 5030B0.4108-05-401/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Vinyl Chloride1.07010703EPA 5030B0.675-01-401/27/17 12:4201/27/17 08:50NDEPA 8260Bug/L1Xylenes, total5.07010703EPA 5030B1.41330-20-701/27/17 12:4201/27/17 08:50EPA 8260B89 %Surr: Dibromofluoromethane7010703EPA 5030B1868-53-701/27/17 12:4201/27/17 08:5080-120EPA 8260B101 %Surr: 1,2-Dichloroethane-d47010703EPA 5030B17060-07-001/27/17 12:4201/27/17 08:5078-120EPA 8260B104 %Surr: Toluene-d87010703EPA 5030B2037-26-501/27/17 12:4201/27/17 08:5080-120EPA 8260B103 %Surr: 4-Bromofluorobenzene7010703EPA 5030B460-00-401/27/17 12:4201/27/17 08:5080-120Page 10 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW3Ground WaterAAA0878-03AAA087801/23/17 14:02Project:Montgomery County Landfill01/26/17 13:50On SiteEPA 9050A126umhos/cm1Field - Specific Conductance17010773NA1COND01/23/17 14:0201/23/17 14:02SM 4500-O G2080ug/L1Dissolved Oxygen0.07010773NA0.0NA01/23/17 14:0201/23/17 14:02EPA 9040C4.25pH Units1Field - pH7010773NAPH01/23/17 14:0201/23/17 14:02NA210mV1Field - Redox7010773NAREDOX01/23/17 14:0201/23/17 14:02SM 2550 B13.7C1Field - Temperature7010773NATEMP01/23/17 14:0201/23/17 14:02EPA 180.14.70NTU1Field - Turbidity7010773NATURB01/23/17 14:0201/23/17 14:02NA4.17feet1Field - Water Level7010773NAWL01/23/17 14:0201/23/17 14:02Metals, TotalNDEPA 6020Bug/L1Antimony6.007020139EPA 3005A0.857440-36-002/07/17 19:5302/06/17 18:25NDEPA 6020Bug/L1Arsenic10.07020139EPA 3005A1.647440-38-202/07/17 19:5302/06/17 18:25EPA 6020B84.0ug/L1Barium100J7020139EPA 3005A0.447440-39-302/07/17 19:5302/06/17 18:25EPA 6020B0.24ug/L1Beryllium1.00J7020139EPA 3005A0.087440-41-702/07/17 19:5302/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020139EPA 3005A0.077440-43-902/07/17 19:5302/06/17 18:25EPA 6020B2.57ug/L1Chromium10.0J7020139EPA 3005A0.947440-47-302/07/17 19:5302/06/17 18:25EPA 6020B7.54ug/L1Cobalt10.0J7020139EPA 3005A0.527440-48-402/07/17 19:5302/06/17 18:25EPA 6020B3.47ug/L1Copper10.0J7020139EPA 3005A0.547440-50-802/07/17 19:5302/06/17 18:25EPA 6020B4.09ug/L1Lead10.0J7020139EPA 3005A0.127439-92-102/07/17 19:5302/06/17 18:25EPA 6020B3.32ug/L1Nickel50.0J7020139EPA 3005A0.557440-02-002/07/17 19:5302/06/17 18:25NDEPA 6020Bug/L1Selenium10.07020139EPA 3005A1.007782-49-202/07/17 19:5302/06/17 18:25NDEPA 6020Bug/L1Silver10.07020139EPA 3005A0.487440-22-402/07/17 19:5302/06/17 18:25Page 11 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW3Ground WaterAAA0878-03AAA087801/23/17 14:02Project:Montgomery County Landfill01/26/17 13:50Metals, TotalNDEPA 6020Bug/L1Thallium5.507020139EPA 3005A0.217440-28-002/07/17 19:5302/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020139EPA 3005A7.147440-62-202/07/17 19:5302/06/17 18:25EPA 6020B9.05ug/L1Zinc10.0J7020139EPA 3005A2.107440-66-602/07/17 19:5302/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010703EPA 5030B8.267-64-101/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Acrylonitrile2007010703EPA 5030B2.5107-13-101/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Benzene1.07010703EPA 5030B0.271-43-201/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Bromochloromethane3.07010703EPA 5030B0.574-97-501/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Bromodichloromethane1.07010703EPA 5030B0.475-27-401/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Bromoform3.07010703EPA 5030B0.675-25-201/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Bromomethane107010703EPA 5030B1.074-83-901/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Carbon Disulfide1007010703EPA 5030B0.875-15-001/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Carbon Tetrachloride1.07010703EPA 5030B0.456-23-501/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Chlorobenzene3.07010703EPA 5030B0.5108-90-701/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Chloroethane107010703EPA 5030B0.575-00-301/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Chloroform5.07010703EPA 5030B0.667-66-301/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Chloromethane1.07010703EPA 5030B0.474-87-301/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Dibromochloromethane3.07010703EPA 5030B0.3124-48-101/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010703EPA 5030B0.696-12-801/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L11,2-Dibromoethane1.07010703EPA 5030B0.3106-93-401/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Dibromomethane107010703EPA 5030B0.674-95-301/27/17 13:0701/27/17 08:50Page 12 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW3Ground WaterAAA0878-03AAA087801/23/17 14:02Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010703EPA 5030B0.595-50-101/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010703EPA 5030B0.6106-46-701/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010703EPA 5030B1.6110-57-601/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L11,1-Dichloroethane5.07010703EPA 5030B0.475-34-301/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L11,2-Dichloroethane1.07010703EPA 5030B0.7107-06-201/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L11,1-Dichloroethene5.07010703EPA 5030B0.775-35-401/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010703EPA 5030B0.7156-59-201/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010703EPA 5030B0.5156-60-501/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L11,2-Dichloropropane1.07010703EPA 5030B0.678-87-501/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010703EPA 5030B0.210061-01-501/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010703EPA 5030B0.310061-02-601/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Ethylbenzene1.07010703EPA 5030B0.4100-41-401/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Iodomethane107010703EPA 5030B3.174-88-401/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010703EPA 5030B0.9591-78-601/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Methylene Chloride1.07010703EPA 5030B0.575-09-201/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010703EPA 5030B3.278-93-301/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010703EPA 5030B0.9108-10-101/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Styrene1.07010703EPA 5030B0.5100-42-501/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010703EPA 5030B0.3630-20-601/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010703EPA 5030B0.579-34-501/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Tetrachloroethene1.07010703EPA 5030B0.8127-18-401/27/17 13:0701/27/17 08:50Page 13 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW3Ground WaterAAA0878-03AAA087801/23/17 14:02Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Toluene1.07010703EPA 5030B0.3108-88-301/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010703EPA 5030B0.471-55-601/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010703EPA 5030B0.679-00-501/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Trichloroethene1.07010703EPA 5030B0.379-01-601/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Trichlorofluoromethane1.07010703EPA 5030B0.575-69-401/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010703EPA 5030B0.596-18-401/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Vinyl Acetate507010703EPA 5030B0.4108-05-401/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Vinyl Chloride1.07010703EPA 5030B0.675-01-401/27/17 13:0701/27/17 08:50NDEPA 8260Bug/L1Xylenes, total5.07010703EPA 5030B1.41330-20-701/27/17 13:0701/27/17 08:50EPA 8260B94 %Surr: Dibromofluoromethane7010703EPA 5030B1868-53-701/27/17 13:0701/27/17 08:5080-120EPA 8260B104 %Surr: 1,2-Dichloroethane-d47010703EPA 5030B17060-07-001/27/17 13:0701/27/17 08:5078-120EPA 8260B104 %Surr: Toluene-d87010703EPA 5030B2037-26-501/27/17 13:0701/27/17 08:5080-120EPA 8260B103 %Surr: 4-Bromofluorobenzene7010703EPA 5030B460-00-401/27/17 13:0701/27/17 08:5080-120Page 14 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW4Ground WaterAAA0878-04AAA087801/23/17 14:33Project:Montgomery County Landfill01/26/17 13:50On SiteEPA 9050A560umhos/cm1Field - Specific Conductance17010773NA1COND01/23/17 14:3301/23/17 14:33SM 4500-O G2850ug/L1Dissolved Oxygen0.07010773NA0.0NA01/23/17 14:3301/23/17 14:33EPA 9040C5.21pH Units1Field - pH7010773NAPH01/23/17 14:3301/23/17 14:33NA68mV1Field - Redox7010773NAREDOX01/23/17 14:3301/23/17 14:33SM 2550 B14.0C1Field - Temperature7010773NATEMP01/23/17 14:3301/23/17 14:33EPA 180.11.11NTU1Field - Turbidity7010773NATURB01/23/17 14:3301/23/17 14:33NA3.90feet1Field - Water Level7010773NAWL01/23/17 14:3301/23/17 14:33Metals, TotalNDEPA 6020Bug/L1Antimony6.007020139EPA 3005A0.857440-36-002/07/17 19:5902/06/17 18:25EPA 6020B4.20ug/L1Arsenic10.0J7020139EPA 3005A1.647440-38-202/07/17 19:5902/06/17 18:25EPA 6020B957ug/L1Barium1007020139EPA 3005A0.447440-39-302/07/17 19:5902/06/17 18:25NDEPA 6020Bug/L1Beryllium1.007020139EPA 3005A0.087440-41-702/07/17 19:5902/06/17 18:25EPA 6020B0.47ug/L1Cadmium1.00J7020139EPA 3005A0.077440-43-902/07/17 19:5902/06/17 18:25NDEPA 6020Bug/L1Chromium10.07020139EPA 3005A0.947440-47-302/07/17 19:5902/06/17 18:25EPA 6020B33.9ug/L1Cobalt10.07020139EPA 3005A0.527440-48-402/07/17 19:5902/06/17 18:25EPA 6020B1.15ug/L1Copper10.0J7020139EPA 3005A0.547440-50-802/07/17 19:5902/06/17 18:25EPA 6020B0.15ug/L1Lead10.0J7020139EPA 3005A0.127439-92-102/07/17 19:5902/06/17 18:25EPA 6020B9.57ug/L1Nickel50.0J7020139EPA 3005A0.557440-02-002/07/17 19:5902/06/17 18:25NDEPA 6020Bug/L1Selenium10.07020139EPA 3005A1.007782-49-202/07/17 19:5902/06/17 18:25EPA 6020B1.31ug/L1Silver10.0J7020139EPA 3005A0.487440-22-402/07/17 19:5902/06/17 18:25Page 15 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW4Ground WaterAAA0878-04AAA087801/23/17 14:33Project:Montgomery County Landfill01/26/17 13:50Metals, TotalNDEPA 6020Bug/L1Thallium5.507020139EPA 3005A0.217440-28-002/07/17 19:5902/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020139EPA 3005A7.147440-62-202/07/17 19:5902/06/17 18:25EPA 6020B38.5ug/L1Zinc10.07020139EPA 3005A2.107440-66-602/07/17 19:5902/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010703EPA 5030B8.267-64-101/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Acrylonitrile2007010703EPA 5030B2.5107-13-101/27/17 13:3201/27/17 08:50EPA 8260B1.4ug/L1Benzene1.07010703EPA 5030B0.271-43-201/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Bromochloromethane3.07010703EPA 5030B0.574-97-501/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Bromodichloromethane1.07010703EPA 5030B0.475-27-401/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Bromoform3.07010703EPA 5030B0.675-25-201/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Bromomethane107010703EPA 5030B1.074-83-901/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Carbon Disulfide1007010703EPA 5030B0.875-15-001/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Carbon Tetrachloride1.07010703EPA 5030B0.456-23-501/27/17 13:3201/27/17 08:50EPA 8260B1.2ug/L1Chlorobenzene3.0J7010703EPA 5030B0.5108-90-701/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Chloroethane107010703EPA 5030B0.575-00-301/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Chloroform5.07010703EPA 5030B0.667-66-301/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Chloromethane1.07010703EPA 5030B0.474-87-301/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Dibromochloromethane3.07010703EPA 5030B0.3124-48-101/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010703EPA 5030B0.696-12-801/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L11,2-Dibromoethane1.07010703EPA 5030B0.3106-93-401/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Dibromomethane107010703EPA 5030B0.674-95-301/27/17 13:3201/27/17 08:50Page 16 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW4Ground WaterAAA0878-04AAA087801/23/17 14:33Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010703EPA 5030B0.595-50-101/27/17 13:3201/27/17 08:50EPA 8260B2.5ug/L11,4-Dichlorobenzene1.07010703EPA 5030B0.6106-46-701/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010703EPA 5030B1.6110-57-601/27/17 13:3201/27/17 08:50EPA 8260B0.6ug/L11,1-Dichloroethane5.0J7010703EPA 5030B0.475-34-301/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L11,2-Dichloroethane1.07010703EPA 5030B0.7107-06-201/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L11,1-Dichloroethene5.07010703EPA 5030B0.775-35-401/27/17 13:3201/27/17 08:50EPA 8260B1.4ug/L1cis-1,2-Dichloroethene5.0J7010703EPA 5030B0.7156-59-201/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010703EPA 5030B0.5156-60-501/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L11,2-Dichloropropane1.07010703EPA 5030B0.678-87-501/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010703EPA 5030B0.210061-01-501/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010703EPA 5030B0.310061-02-601/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Ethylbenzene1.07010703EPA 5030B0.4100-41-401/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Iodomethane107010703EPA 5030B3.174-88-401/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010703EPA 5030B0.9591-78-601/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Methylene Chloride1.07010703EPA 5030B0.575-09-201/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010703EPA 5030B3.278-93-301/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010703EPA 5030B0.9108-10-101/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Styrene1.07010703EPA 5030B0.5100-42-501/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010703EPA 5030B0.3630-20-601/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010703EPA 5030B0.579-34-501/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Tetrachloroethene1.07010703EPA 5030B0.8127-18-401/27/17 13:3201/27/17 08:50Page 17 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-MW4Ground WaterAAA0878-04AAA087801/23/17 14:33Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Toluene1.07010703EPA 5030B0.3108-88-301/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010703EPA 5030B0.471-55-601/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010703EPA 5030B0.679-00-501/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Trichloroethene1.07010703EPA 5030B0.379-01-601/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Trichlorofluoromethane1.07010703EPA 5030B0.575-69-401/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010703EPA 5030B0.596-18-401/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Vinyl Acetate507010703EPA 5030B0.4108-05-401/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Vinyl Chloride1.07010703EPA 5030B0.675-01-401/27/17 13:3201/27/17 08:50NDEPA 8260Bug/L1Xylenes, total5.07010703EPA 5030B1.41330-20-701/27/17 13:3201/27/17 08:50EPA 8260B92 %Surr: Dibromofluoromethane7010703EPA 5030B1868-53-701/27/17 13:3201/27/17 08:5080-120EPA 8260B100 %Surr: 1,2-Dichloroethane-d47010703EPA 5030B17060-07-001/27/17 13:3201/27/17 08:5078-120EPA 8260B102 %Surr: Toluene-d87010703EPA 5030B2037-26-501/27/17 13:3201/27/17 08:5080-120EPA 8260B102 %Surr: 4-Bromofluorobenzene7010703EPA 5030B460-00-401/27/17 13:3201/27/17 08:5080-120Page 18 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-DuplicateGround WaterAAA0878-05AAA087801/23/17 00:00Project:Montgomery County Landfill01/26/17 13:50Metals, TotalNDEPA 6020Bug/L1Antimony6.007020139EPA 3005A0.857440-36-002/07/17 20:0502/06/17 18:25EPA 6020B6.06ug/L1Arsenic10.0J7020139EPA 3005A1.647440-38-202/07/17 20:0502/06/17 18:25EPA 6020B930ug/L1Barium1007020139EPA 3005A0.447440-39-302/07/17 20:0502/06/17 18:25NDEPA 6020Bug/L1Beryllium1.007020139EPA 3005A0.087440-41-702/07/17 20:0502/06/17 18:25EPA 6020B0.56ug/L1Cadmium1.00J7020139EPA 3005A0.077440-43-902/07/17 20:0502/06/17 18:25NDEPA 6020Bug/L1Chromium10.07020139EPA 3005A0.947440-47-302/07/17 20:0502/06/17 18:25EPA 6020B33.7ug/L1Cobalt10.07020139EPA 3005A0.527440-48-402/07/17 20:0502/06/17 18:25EPA 6020B1.85ug/L1Copper10.0J7020139EPA 3005A0.547440-50-802/07/17 20:0502/06/17 18:25EPA 6020B0.23ug/L1Lead10.0J7020139EPA 3005A0.127439-92-102/07/17 20:0502/06/17 18:25EPA 6020B8.33ug/L1Nickel50.0J7020139EPA 3005A0.557440-02-002/07/17 20:0502/06/17 18:25NDEPA 6020Bug/L1Selenium10.07020139EPA 3005A1.007782-49-202/07/17 20:0502/06/17 18:25EPA 6020B1.54ug/L1Silver10.0J7020139EPA 3005A0.487440-22-402/07/17 20:0502/06/17 18:25NDEPA 6020Bug/L1Thallium5.507020139EPA 3005A0.217440-28-002/07/17 20:0502/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020139EPA 3005A7.147440-62-202/07/17 20:0502/06/17 18:25EPA 6020B37.9ug/L1Zinc10.07020139EPA 3005A2.107440-66-602/07/17 20:0502/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010703EPA 5030B8.267-64-101/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Acrylonitrile2007010703EPA 5030B2.5107-13-101/27/17 13:5801/27/17 08:50EPA 8260B1.4ug/L1Benzene1.07010703EPA 5030B0.271-43-201/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Bromochloromethane3.07010703EPA 5030B0.574-97-501/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Bromodichloromethane1.07010703EPA 5030B0.475-27-401/27/17 13:5801/27/17 08:50Page 19 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-DuplicateGround WaterAAA0878-05AAA087801/23/17 00:00Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromoform3.07010703EPA 5030B0.675-25-201/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Bromomethane107010703EPA 5030B1.074-83-901/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Carbon Disulfide1007010703EPA 5030B0.875-15-001/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Carbon Tetrachloride1.07010703EPA 5030B0.456-23-501/27/17 13:5801/27/17 08:50EPA 8260B1.2ug/L1Chlorobenzene3.0J7010703EPA 5030B0.5108-90-701/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Chloroethane107010703EPA 5030B0.575-00-301/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Chloroform5.07010703EPA 5030B0.667-66-301/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Chloromethane1.07010703EPA 5030B0.474-87-301/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Dibromochloromethane3.07010703EPA 5030B0.3124-48-101/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010703EPA 5030B0.696-12-801/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L11,2-Dibromoethane1.07010703EPA 5030B0.3106-93-401/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Dibromomethane107010703EPA 5030B0.674-95-301/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010703EPA 5030B0.595-50-101/27/17 13:5801/27/17 08:50EPA 8260B2.6ug/L11,4-Dichlorobenzene1.07010703EPA 5030B0.6106-46-701/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010703EPA 5030B1.6110-57-601/27/17 13:5801/27/17 08:50EPA 8260B0.7ug/L11,1-Dichloroethane5.0J7010703EPA 5030B0.475-34-301/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L11,2-Dichloroethane1.07010703EPA 5030B0.7107-06-201/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L11,1-Dichloroethene5.07010703EPA 5030B0.775-35-401/27/17 13:5801/27/17 08:50EPA 8260B1.3ug/L1cis-1,2-Dichloroethene5.0J7010703EPA 5030B0.7156-59-201/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010703EPA 5030B0.5156-60-501/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L11,2-Dichloropropane1.07010703EPA 5030B0.678-87-501/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010703EPA 5030B0.210061-01-501/27/17 13:5801/27/17 08:50Page 20 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-DuplicateGround WaterAAA0878-05AAA087801/23/17 00:00Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010703EPA 5030B0.310061-02-601/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Ethylbenzene1.07010703EPA 5030B0.4100-41-401/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Iodomethane107010703EPA 5030B3.174-88-401/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010703EPA 5030B0.9591-78-601/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Methylene Chloride1.07010703EPA 5030B0.575-09-201/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010703EPA 5030B3.278-93-301/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010703EPA 5030B0.9108-10-101/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Styrene1.07010703EPA 5030B0.5100-42-501/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010703EPA 5030B0.3630-20-601/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010703EPA 5030B0.579-34-501/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Tetrachloroethene1.07010703EPA 5030B0.8127-18-401/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Toluene1.07010703EPA 5030B0.3108-88-301/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010703EPA 5030B0.471-55-601/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010703EPA 5030B0.679-00-501/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Trichloroethene1.07010703EPA 5030B0.379-01-601/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Trichlorofluoromethane1.07010703EPA 5030B0.575-69-401/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010703EPA 5030B0.596-18-401/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Vinyl Acetate507010703EPA 5030B0.4108-05-401/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Vinyl Chloride1.07010703EPA 5030B0.675-01-401/27/17 13:5801/27/17 08:50NDEPA 8260Bug/L1Xylenes, total5.07010703EPA 5030B1.41330-20-701/27/17 13:5801/27/17 08:50EPA 8260B91 %Surr: Dibromofluoromethane7010703EPA 5030B1868-53-701/27/17 13:5801/27/17 08:5080-120Page 21 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-DuplicateGround WaterAAA0878-05AAA087801/23/17 00:00Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260EPA 8260B100 %Surr: 1,2-Dichloroethane-d47010703EPA 5030B17060-07-001/27/17 13:5801/27/17 08:5078-120EPA 8260B101 %Surr: Toluene-d87010703EPA 5030B2037-26-501/27/17 13:5801/27/17 08:5080-120EPA 8260B101 %Surr: 4-Bromofluorobenzene7010703EPA 5030B460-00-401/27/17 13:5801/27/17 08:5080-120Page 22 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-Field BlankWaterAAA0878-06AAA087801/23/17 15:50Project:Montgomery County Landfill01/26/17 13:50Metals, TotalNDEPA 6020Bug/L1Antimony6.007020139EPA 3005A0.857440-36-002/07/17 20:2202/06/17 18:25NDEPA 6020Bug/L1Arsenic10.07020139EPA 3005A1.647440-38-202/07/17 20:2202/06/17 18:25NDEPA 6020Bug/L1Barium1007020139EPA 3005A0.447440-39-302/07/17 20:2202/06/17 18:25NDEPA 6020Bug/L1Beryllium1.007020139EPA 3005A0.087440-41-702/07/17 20:2202/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020139EPA 3005A0.077440-43-902/07/17 20:2202/06/17 18:25NDEPA 6020Bug/L1Chromium10.07020139EPA 3005A0.947440-47-302/07/17 20:2202/06/17 18:25NDEPA 6020Bug/L1Cobalt10.07020139EPA 3005A0.527440-48-402/07/17 20:2202/06/17 18:25EPA 6020B1.32ug/L1Copper10.0J7020139EPA 3005A0.547440-50-802/07/17 20:2202/06/17 18:25NDEPA 6020Bug/L1Lead10.07020139EPA 3005A0.127439-92-102/07/17 20:2202/06/17 18:25NDEPA 6020Bug/L1Nickel50.07020139EPA 3005A0.557440-02-002/07/17 20:2202/06/17 18:25NDEPA 6020Bug/L1Selenium10.07020139EPA 3005A1.007782-49-202/07/17 20:2202/06/17 18:25NDEPA 6020Bug/L1Silver10.07020139EPA 3005A0.487440-22-402/07/17 20:2202/06/17 18:25NDEPA 6020Bug/L1Thallium5.507020139EPA 3005A0.217440-28-002/07/17 20:2202/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020139EPA 3005A7.147440-62-202/07/17 20:2202/06/17 18:25NDEPA 6020Bug/L1Zinc10.07020139EPA 3005A2.107440-66-602/07/17 20:2202/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010703EPA 5030B8.267-64-101/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Acrylonitrile2007010703EPA 5030B2.5107-13-101/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Benzene1.07010703EPA 5030B0.271-43-201/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Bromochloromethane3.07010703EPA 5030B0.574-97-501/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Bromodichloromethane1.07010703EPA 5030B0.475-27-401/27/17 10:1001/27/17 08:50Page 23 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-Field BlankWaterAAA0878-06AAA087801/23/17 15:50Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromoform3.07010703EPA 5030B0.675-25-201/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Bromomethane107010703EPA 5030B1.074-83-901/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Carbon Disulfide1007010703EPA 5030B0.875-15-001/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Carbon Tetrachloride1.07010703EPA 5030B0.456-23-501/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Chlorobenzene3.07010703EPA 5030B0.5108-90-701/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Chloroethane107010703EPA 5030B0.575-00-301/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Chloroform5.07010703EPA 5030B0.667-66-301/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Chloromethane1.07010703EPA 5030B0.474-87-301/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Dibromochloromethane3.07010703EPA 5030B0.3124-48-101/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010703EPA 5030B0.696-12-801/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L11,2-Dibromoethane1.07010703EPA 5030B0.3106-93-401/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Dibromomethane107010703EPA 5030B0.674-95-301/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010703EPA 5030B0.595-50-101/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010703EPA 5030B0.6106-46-701/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010703EPA 5030B1.6110-57-601/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L11,1-Dichloroethane5.07010703EPA 5030B0.475-34-301/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L11,2-Dichloroethane1.07010703EPA 5030B0.7107-06-201/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L11,1-Dichloroethene5.07010703EPA 5030B0.775-35-401/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010703EPA 5030B0.7156-59-201/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010703EPA 5030B0.5156-60-501/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L11,2-Dichloropropane1.07010703EPA 5030B0.678-87-501/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010703EPA 5030B0.210061-01-501/27/17 10:1001/27/17 08:50Page 24 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-Field BlankWaterAAA0878-06AAA087801/23/17 15:50Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010703EPA 5030B0.310061-02-601/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Ethylbenzene1.07010703EPA 5030B0.4100-41-401/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Iodomethane107010703EPA 5030B3.174-88-401/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010703EPA 5030B0.9591-78-601/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Methylene Chloride1.07010703EPA 5030B0.575-09-201/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010703EPA 5030B3.278-93-301/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010703EPA 5030B0.9108-10-101/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Styrene1.07010703EPA 5030B0.5100-42-501/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010703EPA 5030B0.3630-20-601/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010703EPA 5030B0.579-34-501/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Tetrachloroethene1.07010703EPA 5030B0.8127-18-401/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Toluene1.07010703EPA 5030B0.3108-88-301/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010703EPA 5030B0.471-55-601/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010703EPA 5030B0.679-00-501/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Trichloroethene1.07010703EPA 5030B0.379-01-601/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Trichlorofluoromethane1.07010703EPA 5030B0.575-69-401/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010703EPA 5030B0.596-18-401/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Vinyl Acetate507010703EPA 5030B0.4108-05-401/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Vinyl Chloride1.07010703EPA 5030B0.675-01-401/27/17 10:1001/27/17 08:50NDEPA 8260Bug/L1Xylenes, total5.07010703EPA 5030B1.41330-20-701/27/17 10:1001/27/17 08:50EPA 8260B91 %Surr: Dibromofluoromethane7010703EPA 5030B1868-53-701/27/17 10:1001/27/17 08:5080-120Page 25 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-Field BlankWaterAAA0878-06AAA087801/23/17 15:50Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260EPA 8260B100 %Surr: 1,2-Dichloroethane-d47010703EPA 5030B17060-07-001/27/17 10:1001/27/17 08:5078-120EPA 8260B103 %Surr: Toluene-d87010703EPA 5030B2037-26-501/27/17 10:1001/27/17 08:5080-120EPA 8260B102 %Surr: 4-Bromofluorobenzene7010703EPA 5030B460-00-401/27/17 10:1001/27/17 08:5080-120Page 26 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-Trip BlankWaterAAA0878-07AAA087801/23/17 00:00Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010703EPA 5030B8.267-64-101/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Acrylonitrile2007010703EPA 5030B2.5107-13-101/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Benzene1.07010703EPA 5030B0.271-43-201/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Bromochloromethane3.07010703EPA 5030B0.574-97-501/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Bromodichloromethane1.07010703EPA 5030B0.475-27-401/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Bromoform3.07010703EPA 5030B0.675-25-201/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Bromomethane107010703EPA 5030B1.074-83-901/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Carbon Disulfide1007010703EPA 5030B0.875-15-001/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Carbon Tetrachloride1.07010703EPA 5030B0.456-23-501/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Chlorobenzene3.07010703EPA 5030B0.5108-90-701/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Chloroethane107010703EPA 5030B0.575-00-301/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Chloroform5.07010703EPA 5030B0.667-66-301/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Chloromethane1.07010703EPA 5030B0.474-87-301/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Dibromochloromethane3.07010703EPA 5030B0.3124-48-101/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010703EPA 5030B0.696-12-801/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L11,2-Dibromoethane1.07010703EPA 5030B0.3106-93-401/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Dibromomethane107010703EPA 5030B0.674-95-301/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010703EPA 5030B0.595-50-101/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010703EPA 5030B0.6106-46-701/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010703EPA 5030B1.6110-57-601/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L11,1-Dichloroethane5.07010703EPA 5030B0.475-34-301/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L11,2-Dichloroethane1.07010703EPA 5030B0.7107-06-201/27/17 09:4601/27/17 08:50Page 27 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-Trip BlankWaterAAA0878-07AAA087801/23/17 00:00Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,1-Dichloroethene5.07010703EPA 5030B0.775-35-401/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010703EPA 5030B0.7156-59-201/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010703EPA 5030B0.5156-60-501/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L11,2-Dichloropropane1.07010703EPA 5030B0.678-87-501/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010703EPA 5030B0.210061-01-501/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010703EPA 5030B0.310061-02-601/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Ethylbenzene1.07010703EPA 5030B0.4100-41-401/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Iodomethane107010703EPA 5030B3.174-88-401/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010703EPA 5030B0.9591-78-601/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Methylene Chloride1.07010703EPA 5030B0.575-09-201/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010703EPA 5030B3.278-93-301/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010703EPA 5030B0.9108-10-101/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Styrene1.07010703EPA 5030B0.5100-42-501/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010703EPA 5030B0.3630-20-601/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010703EPA 5030B0.579-34-501/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Tetrachloroethene1.07010703EPA 5030B0.8127-18-401/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Toluene1.07010703EPA 5030B0.3108-88-301/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010703EPA 5030B0.471-55-601/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010703EPA 5030B0.679-00-501/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Trichloroethene1.07010703EPA 5030B0.379-01-601/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Trichlorofluoromethane1.07010703EPA 5030B0.575-69-401/27/17 09:4601/27/17 08:50Page 28 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-Trip BlankWaterAAA0878-07AAA087801/23/17 00:00Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010703EPA 5030B0.596-18-401/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Vinyl Acetate507010703EPA 5030B0.4108-05-401/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Vinyl Chloride1.07010703EPA 5030B0.675-01-401/27/17 09:4601/27/17 08:50NDEPA 8260Bug/L1Xylenes, total5.07010703EPA 5030B1.41330-20-701/27/17 09:4601/27/17 08:50EPA 8260B91 %Surr: Dibromofluoromethane7010703EPA 5030B1868-53-701/27/17 09:4601/27/17 08:5080-120EPA 8260B99 %Surr: 1,2-Dichloroethane-d47010703EPA 5030B17060-07-001/27/17 09:4601/27/17 08:5078-120EPA 8260B103 %Surr: Toluene-d87010703EPA 5030B2037-26-501/27/17 09:4601/27/17 08:5080-120EPA 8260B104 %Surr: 4-Bromofluorobenzene7010703EPA 5030B460-00-401/27/17 09:4601/27/17 08:5080-120Page 29 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-SW1Surface WaterAAA0878-08AAA087801/23/17 13:49Project:Montgomery County Landfill01/26/17 13:50On SiteEPA 9050A86umhos/cm1Field - Specific Conductance17010773NA1COND01/23/17 13:4901/23/17 13:49SM 4500-O G4050ug/L1Dissolved Oxygen0.07010773NA0.0NA01/23/17 13:4901/23/17 13:49EPA 9040C4.79pH Units1Field - pH7010773NAPH01/23/17 13:4901/23/17 13:49NA300mV1Field - Redox7010773NAREDOX01/23/17 13:4901/23/17 13:49SM 2550 B12.5C1Field - Temperature7010773NATEMP01/23/17 13:4901/23/17 13:49EPA 180.114.0NTU1Field - Turbidity7010773NATURB01/23/17 13:4901/23/17 13:49Metals, TotalNDEPA 6020Bug/L1Antimony6.007020139EPA 3005A0.857440-36-002/07/17 20:2802/06/17 18:25NDEPA 6020Bug/L1Arsenic10.07020139EPA 3005A1.647440-38-202/07/17 20:2802/06/17 18:25EPA 6020B87.3ug/L1Barium100J7020139EPA 3005A0.447440-39-302/07/17 20:2802/06/17 18:25EPA 6020B0.10ug/L1Beryllium1.00J7020139EPA 3005A0.087440-41-702/07/17 20:2802/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020139EPA 3005A0.077440-43-902/07/17 20:2802/06/17 18:25EPA 6020B0.99ug/L1Chromium10.0J7020139EPA 3005A0.947440-47-302/07/17 20:2802/06/17 18:25EPA 6020B4.24ug/L1Cobalt10.0J7020139EPA 3005A0.527440-48-402/07/17 20:2802/06/17 18:25EPA 6020B1.01ug/L1Copper10.0J7020139EPA 3005A0.547440-50-802/07/17 20:2802/06/17 18:25EPA 6020B1.06ug/L1Lead10.0J7020139EPA 3005A0.127439-92-102/07/17 20:2802/06/17 18:25EPA 6020B1.31ug/L1Nickel50.0J7020139EPA 3005A0.557440-02-002/07/17 20:2802/06/17 18:25NDEPA 6020Bug/L1Selenium10.07020139EPA 3005A1.007782-49-202/07/17 20:2802/06/17 18:25NDEPA 6020Bug/L1Silver10.07020139EPA 3005A0.487440-22-402/07/17 20:2802/06/17 18:25NDEPA 6020Bug/L1Thallium5.507020139EPA 3005A0.217440-28-002/07/17 20:2802/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020139EPA 3005A7.147440-62-202/07/17 20:2802/06/17 18:25Page 30 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-SW1Surface WaterAAA0878-08AAA087801/23/17 13:49Project:Montgomery County Landfill01/26/17 13:50Metals, TotalEPA 6020B9.30ug/L1Zinc10.0J7020139EPA 3005A2.107440-66-602/07/17 20:2802/06/17 18:25Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007010703EPA 5030B8.267-64-101/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Acrylonitrile2007010703EPA 5030B2.5107-13-101/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Benzene1.07010703EPA 5030B0.271-43-201/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Bromochloromethane3.07010703EPA 5030B0.574-97-501/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Bromodichloromethane1.07010703EPA 5030B0.475-27-401/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Bromoform3.07010703EPA 5030B0.675-25-201/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Bromomethane107010703EPA 5030B1.074-83-901/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Carbon Disulfide1007010703EPA 5030B0.875-15-001/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Carbon Tetrachloride1.07010703EPA 5030B0.456-23-501/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Chlorobenzene3.07010703EPA 5030B0.5108-90-701/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Chloroethane107010703EPA 5030B0.575-00-301/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Chloroform5.07010703EPA 5030B0.667-66-301/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Chloromethane1.07010703EPA 5030B0.474-87-301/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Dibromochloromethane3.07010703EPA 5030B0.3124-48-101/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010703EPA 5030B0.696-12-801/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L11,2-Dibromoethane1.07010703EPA 5030B0.3106-93-401/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Dibromomethane107010703EPA 5030B0.674-95-301/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010703EPA 5030B0.595-50-101/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010703EPA 5030B0.6106-46-701/27/17 14:2301/27/17 08:50Page 31 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-SW1Surface WaterAAA0878-08AAA087801/23/17 13:49Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010703EPA 5030B1.6110-57-601/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L11,1-Dichloroethane5.07010703EPA 5030B0.475-34-301/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L11,2-Dichloroethane1.07010703EPA 5030B0.7107-06-201/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L11,1-Dichloroethene5.07010703EPA 5030B0.775-35-401/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010703EPA 5030B0.7156-59-201/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010703EPA 5030B0.5156-60-501/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L11,2-Dichloropropane1.07010703EPA 5030B0.678-87-501/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010703EPA 5030B0.210061-01-501/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010703EPA 5030B0.310061-02-601/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Ethylbenzene1.07010703EPA 5030B0.4100-41-401/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Iodomethane107010703EPA 5030B3.174-88-401/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010703EPA 5030B0.9591-78-601/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Methylene Chloride1.07010703EPA 5030B0.575-09-201/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007010703EPA 5030B3.278-93-301/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010703EPA 5030B0.9108-10-101/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Styrene1.07010703EPA 5030B0.5100-42-501/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010703EPA 5030B0.3630-20-601/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010703EPA 5030B0.579-34-501/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Tetrachloroethene1.07010703EPA 5030B0.8127-18-401/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Toluene1.07010703EPA 5030B0.3108-88-301/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010703EPA 5030B0.471-55-601/27/17 14:2301/27/17 08:50Page 32 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-SW1Surface WaterAAA0878-08AAA087801/23/17 13:49Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010703EPA 5030B0.679-00-501/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Trichloroethene1.07010703EPA 5030B0.379-01-601/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Trichlorofluoromethane1.07010703EPA 5030B0.575-69-401/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010703EPA 5030B0.596-18-401/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Vinyl Acetate507010703EPA 5030B0.4108-05-401/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Vinyl Chloride1.07010703EPA 5030B0.675-01-401/27/17 14:2301/27/17 08:50NDEPA 8260Bug/L1Xylenes, total5.07010703EPA 5030B1.41330-20-701/27/17 14:2301/27/17 08:50EPA 8260B92 %Surr: Dibromofluoromethane7010703EPA 5030B1868-53-701/27/17 14:2301/27/17 08:5080-120EPA 8260B102 %Surr: 1,2-Dichloroethane-d47010703EPA 5030B17060-07-001/27/17 14:2301/27/17 08:5078-120EPA 8260B102 %Surr: Toluene-d87010703EPA 5030B2037-26-501/27/17 14:2301/27/17 08:5080-120EPA 8260B104 %Surr: 4-Bromofluorobenzene7010703EPA 5030B460-00-401/27/17 14:2301/27/17 08:5080-120Page 33 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-SW2Surface WaterAAA0878-09AAA087801/23/17 14:15Project:Montgomery County Landfill01/26/17 13:50On SiteEPA 9050A73umhos/cm1Field - Specific Conductance17010773NA1COND01/23/17 14:1501/23/17 14:15SM 4500-O G6570ug/L1Dissolved Oxygen0.07010773NA0.0NA01/23/17 14:1501/23/17 14:15EPA 9040C5.07pH Units1Field - pH7010773NAPH01/23/17 14:1501/23/17 14:15NA203mV1Field - Redox7010773NAREDOX01/23/17 14:1501/23/17 14:15SM 2550 B12.4C1Field - Temperature7010773NATEMP01/23/17 14:1501/23/17 14:15EPA 180.16.24NTU1Field - Turbidity7010773NATURB01/23/17 14:1501/23/17 14:15Metals, TotalNDEPA 6020Bug/L1Antimony6.007020139EPA 3005A0.857440-36-002/07/17 20:3402/06/17 18:25NDEPA 6020Bug/L1Arsenic10.07020139EPA 3005A1.647440-38-202/07/17 20:3402/06/17 18:25EPA 6020B45.3ug/L1Barium100J7020139EPA 3005A0.447440-39-302/07/17 20:3402/06/17 18:25NDEPA 6020Bug/L1Beryllium1.007020139EPA 3005A0.087440-41-702/07/17 20:3402/06/17 18:25NDEPA 6020Bug/L1Cadmium1.007020139EPA 3005A0.077440-43-902/07/17 20:3402/06/17 18:25NDEPA 6020Bug/L1Chromium10.07020139EPA 3005A0.947440-47-302/07/17 20:3402/06/17 18:25EPA 6020B0.96ug/L1Cobalt10.0J7020139EPA 3005A0.527440-48-402/07/17 20:3402/06/17 18:25EPA 6020B1.13ug/L1Copper10.0J7020139EPA 3005A0.547440-50-802/07/17 20:3402/06/17 18:25EPA 6020B0.92ug/L1Lead10.0J7020139EPA 3005A0.127439-92-102/07/17 20:3402/06/17 18:25EPA 6020B0.90ug/L1Nickel50.0J7020139EPA 3005A0.557440-02-002/07/17 20:3402/06/17 18:25NDEPA 6020Bug/L1Selenium10.07020139EPA 3005A1.007782-49-202/07/17 20:3402/06/17 18:25NDEPA 6020Bug/L1Silver10.07020139EPA 3005A0.487440-22-402/07/17 20:3402/06/17 18:25NDEPA 6020Bug/L1Thallium5.507020139EPA 3005A0.217440-28-002/07/17 20:3402/06/17 18:25NDEPA 6020Bug/L1Vanadium25.07020139EPA 3005A7.147440-62-202/07/17 20:3402/06/17 18:25Page 34 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-SW2Surface WaterAAA0878-09AAA087801/23/17 14:15Project:Montgomery County Landfill01/26/17 13:50Metals, TotalEPA 6020B6.75ug/L1Zinc10.0J7020139EPA 3005A2.107440-66-602/07/17 20:3402/06/17 18:25Volatile Organic Compounds by EPA 8260EPA 8260B20ug/L1Acetone100J7010703EPA 5030B8.267-64-101/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Acrylonitrile2007010703EPA 5030B2.5107-13-101/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Benzene1.07010703EPA 5030B0.271-43-201/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Bromochloromethane3.07010703EPA 5030B0.574-97-501/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Bromodichloromethane1.07010703EPA 5030B0.475-27-401/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Bromoform3.07010703EPA 5030B0.675-25-201/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Bromomethane107010703EPA 5030B1.074-83-901/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Carbon Disulfide1007010703EPA 5030B0.875-15-001/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Carbon Tetrachloride1.07010703EPA 5030B0.456-23-501/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Chlorobenzene3.07010703EPA 5030B0.5108-90-701/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Chloroethane107010703EPA 5030B0.575-00-301/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Chloroform5.07010703EPA 5030B0.667-66-301/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Chloromethane1.07010703EPA 5030B0.474-87-301/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Dibromochloromethane3.07010703EPA 5030B0.3124-48-101/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137010703EPA 5030B0.696-12-801/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L11,2-Dibromoethane1.07010703EPA 5030B0.3106-93-401/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Dibromomethane107010703EPA 5030B0.674-95-301/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L11,2-Dichlorobenzene5.07010703EPA 5030B0.595-50-101/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L11,4-Dichlorobenzene1.07010703EPA 5030B0.6106-46-701/27/17 14:4801/27/17 08:50Page 35 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-SW2Surface WaterAAA0878-09AAA087801/23/17 14:15Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007010703EPA 5030B1.6110-57-601/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L11,1-Dichloroethane5.07010703EPA 5030B0.475-34-301/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L11,2-Dichloroethane1.07010703EPA 5030B0.7107-06-201/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L11,1-Dichloroethene5.07010703EPA 5030B0.775-35-401/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07010703EPA 5030B0.7156-59-201/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07010703EPA 5030B0.5156-60-501/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L11,2-Dichloropropane1.07010703EPA 5030B0.678-87-501/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07010703EPA 5030B0.210061-01-501/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07010703EPA 5030B0.310061-02-601/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Ethylbenzene1.07010703EPA 5030B0.4100-41-401/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Iodomethane107010703EPA 5030B3.174-88-401/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507010703EPA 5030B0.9591-78-601/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Methylene Chloride1.07010703EPA 5030B0.575-09-201/27/17 14:4801/27/17 08:50EPA 8260B14ug/L1Methyl Ethyl Ketone (2-Butanone)100J7010703EPA 5030B3.278-93-301/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007010703EPA 5030B0.9108-10-101/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Styrene1.07010703EPA 5030B0.5100-42-501/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07010703EPA 5030B0.3630-20-601/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07010703EPA 5030B0.579-34-501/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Tetrachloroethene1.07010703EPA 5030B0.8127-18-401/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Toluene1.07010703EPA 5030B0.3108-88-301/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L11,1,1-Trichloroethane1.07010703EPA 5030B0.471-55-601/27/17 14:4801/27/17 08:50Page 36 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:6201-SW2Surface WaterAAA0878-09AAA087801/23/17 14:15Project:Montgomery County Landfill01/26/17 13:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,1,2-Trichloroethane1.07010703EPA 5030B0.679-00-501/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Trichloroethene1.07010703EPA 5030B0.379-01-601/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Trichlorofluoromethane1.07010703EPA 5030B0.575-69-401/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L11,2,3-Trichloropropane1.07010703EPA 5030B0.596-18-401/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Vinyl Acetate507010703EPA 5030B0.4108-05-401/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Vinyl Chloride1.07010703EPA 5030B0.675-01-401/27/17 14:4801/27/17 08:50NDEPA 8260Bug/L1Xylenes, total5.07010703EPA 5030B1.41330-20-701/27/17 14:4801/27/17 08:50EPA 8260B92 %Surr: Dibromofluoromethane7010703EPA 5030B1868-53-701/27/17 14:4801/27/17 08:5080-120EPA 8260B100 %Surr: 1,2-Dichloroethane-d47010703EPA 5030B17060-07-001/27/17 14:4801/27/17 08:5078-120EPA 8260B101 %Surr: Toluene-d87010703EPA 5030B2037-26-501/27/17 14:4801/27/17 08:5080-120EPA 8260B105 %Surr: 4-Bromofluorobenzene7010703EPA 5030B460-00-401/27/17 14:4801/27/17 08:5080-120Page 37 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020139 - EPA 3005ABlank (7020139-BLK1)Prepared: 02/06/17 Analyzed: 02/07/17 Antimonyug/LND6.00Arsenicug/LND10.0Bariumug/LND100Berylliumug/LND1.00Cadmiumug/LND1.00Chromiumug/LND10.0Cobaltug/LND10.0Copperug/LND10.0Leadug/LND10.0Nickelug/LND50.0Seleniumug/LND10.0Silverug/LND10.0Thalliumug/LND5.50Vanadiumug/LND25.0Zincug/LND10.0LCS (7020139-BS1)Prepared: 02/06/17 Analyzed: 02/07/17 Antimonyug/L1016.00100.0080-120101Arsenicug/L98.210.0100.0080-12098Bariumug/L100100100.0080-120100Berylliumug/L97.41.00100.0080-12097Cadmiumug/L1021.00100.0080-120102Chromiumug/L10610.0100.0080-120106Cobaltug/L10210.0100.0080-120102Copperug/L10710.0100.0080-120107Leadug/L98.110.0100.0080-12098Nickelug/L10850.0100.0080-120108Page 38 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020139 - EPA 3005ALCS (7020139-BS1)Prepared: 02/06/17 Analyzed: 02/07/17 Seleniumug/L96.910.0100.0080-12097Silverug/L10110.0100.0080-120101Thalliumug/L1005.50100.0080-120100Vanadiumug/L10625.0100.0080-120106Zincug/L10410.0100.0080-120104Matrix Spike (7020139-MS1)Prepared: 02/06/17 Analyzed: 02/07/17 Source: AAA0878-02Antimonyug/L83.66.00100.00ND75-12584Arsenicug/L10110.0100.002.1975-12598Bariumug/L227100100.0010975-125118Berylliumug/L1005.00100.000.5275-125100Cadmiumug/L1061.00100.00ND75-125106Chromiumug/L11410.0100.003.9775-125110Cobaltug/L10510.0100.001.0275-125104Copperug/L10810.0100.002.2775-125106Leadug/L10710.0100.005.6175-125101Nickelug/L10850.0100.002.3375-125105Seleniumug/L94.910.0100.002.8675-12592Silverug/L10610.0100.000.5075-125105Thalliumug/L1035.50100.00ND75-125103Vanadiumug/L10825.0100.00ND75-125108Zincug/L12410.0100.0017.975-125106Matrix Spike Dup (7020139-MSD1)Prepared: 02/06/17 Analyzed: 02/07/17 Source: AAA0878-02Antimonyug/L84.26.00100.00ND2075-125840.7Arsenicug/L10010.0100.002.192075-125980.7Bariumug/L230100100.001092075-1251211Berylliumug/L97.85.00100.000.522075-125972Page 39 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020139 - EPA 3005AMatrix Spike Dup (7020139-MSD1)Prepared: 02/06/17 Analyzed: 02/07/17 Source: AAA0878-02Cadmiumug/L1041.00100.00ND2075-1251042Chromiumug/L11010.0100.003.972075-1251064Cobaltug/L10910.0100.001.022075-1251074Copperug/L11110.0100.002.272075-1251092Leadug/L10510.0100.005.612075-1251002Nickelug/L11250.0100.002.332075-1251094Seleniumug/L99.010.0100.002.862075-125964Silverug/L10510.0100.000.502075-1251041Thalliumug/L99.65.50100.00ND2075-1251003Vanadiumug/L11025.0100.00ND2075-1251102Zincug/L12410.0100.0017.92075-1251060.2Post Spike (7020139-PS1)Prepared: 02/06/17 Analyzed: 02/07/17 Source: AAA0878-02Antimonyug/L35.9100.000.31QM-0580-12036Arsenicug/L102100.002.1980-120100Bariumug/L226100.0010980-120117Berylliumug/L96.2100.000.5280-12096Cadmiumug/L108100.000.0680-120108Chromiumug/L109100.003.9780-120105Cobaltug/L107100.001.0280-120106Copperug/L108100.002.2780-120105Leadug/L104100.005.6180-12099Nickelug/L106100.002.3380-120104Seleniumug/L98.6100.002.8680-12096Silverug/L105100.000.5080-120104Thalliumug/L98.8100.000.1080-12099Vanadiumug/L109100.004.5180-120104Zincug/L123100.0017.980-120105Page 40 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020139 - EPA 3005APage 41 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010703 - EPA 5030BBlank (7010703-BLK1)Prepared & Analyzed: 01/27/17 Acetoneug/LND100Acrylonitrileug/LND200Benzeneug/LND1.0Bromochloromethaneug/LND3.0Bromodichloromethaneug/LND1.0Bromoformug/LND3.0Bromomethaneug/LND10Carbon Disulfideug/LND100Carbon Tetrachlorideug/LND1.0Chlorobenzeneug/LND3.0Chloroethaneug/LND10Chloroformug/LND5.0Chloromethaneug/LND1.0Dibromochloromethaneug/LND3.01,2-Dibromo-3-chloropropaneug/LND131,2-Dibromoethaneug/LND1.0Dibromomethaneug/LND101,2-Dichlorobenzeneug/LND5.01,4-Dichlorobenzeneug/LND1.0trans-1,4-Dichloro-2-buteneug/LND1001,1-Dichloroethaneug/LND5.01,2-Dichloroethaneug/LND1.01,1-Dichloroetheneug/LND5.0cis-1,2-Dichloroetheneug/LND5.0trans-1,2-Dichloroetheneug/LND5.01,2-Dichloropropaneug/LND1.0cis-1,3-Dichloropropeneug/LND1.0Page 42 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010703 - EPA 5030BBlank (7010703-BLK1)Prepared & Analyzed: 01/27/17 trans-1,3-Dichloropropeneug/LND1.0Ethylbenzeneug/LND1.0Iodomethaneug/LND10Methyl Butyl Ketone (2-Hexanone)ug/LND50Methylene Chlorideug/LND1.0Methyl Ethyl Ketone (2-Butanone)ug/LND1004-Methyl-2-pentanone (MIBK)ug/LND100Styreneug/LND1.01,1,1,2-Tetrachloroethaneug/LND5.01,1,2,2-Tetrachloroethaneug/LND3.0Tetrachloroetheneug/LND1.0Tolueneug/LND1.01,1,1-Trichloroethaneug/LND1.01,1,2-Trichloroethaneug/LND1.0Trichloroetheneug/LND1.0Trichlorofluoromethaneug/LND1.01,2,3-Trichloropropaneug/LND1.0Vinyl Acetateug/LND50Vinyl Chlorideug/LND1.0Xylenes, totalug/LND5.0ug/L50.00080-120Surr: Dibromofluoromethane9246ug/L50.00078-120Surr: 1,2-Dichloroethane-d49849ug/L50.00080-120Surr: Toluene-d810351ug/L50.00080-120Surr: 4-Bromofluorobenzene10553LCS (7010703-BS1)Prepared & Analyzed: 01/27/17 Benzeneug/L5250.00067-134105Page 43 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010703 - EPA 5030BLCS (7010703-BS1)Prepared & Analyzed: 01/27/17 Chlorobenzeneug/L5150.00069-1221011,1-Dichloroetheneug/L5950.00058-142119Tolueneug/L4750.00068-12795Trichloroetheneug/L5150.00072-132102ug/L50.00080-120Surr: Dibromofluoromethane9648ug/L50.00078-120Surr: 1,2-Dichloroethane-d410251ug/L50.00080-120Surr: Toluene-d810251ug/L50.00080-120Surr: 4-Bromofluorobenzene10452Matrix Spike (7010703-MS1)Prepared & Analyzed: 01/27/17 Source: AAA0878-02Benzeneug/L5750.0000.067-134113Chlorobenzeneug/L5450.0000.069-1221081,1-Dichloroetheneug/L6650.0000.058-142132Tolueneug/L5050.0000.068-127101Trichloroetheneug/L5450.0000.072-132108ug/L50.00080-120Surr: Dibromofluoromethane9145ug/L50.00078-120Surr: 1,2-Dichloroethane-d410352ug/L50.00080-120Surr: Toluene-d810352ug/L50.00080-120Surr: 4-Bromofluorobenzene10150Matrix Spike Dup (7010703-MSD1)Prepared & Analyzed: 01/27/17 Source: AAA0878-02Benzeneug/L5550.0000.0967-1341112Chlorobenzeneug/L5250.0000.01369-12210441,1-Dichloroetheneug/L6650.0000.0958-1421310.4Tolueneug/L5050.0000.0968-127992Trichloroetheneug/L5450.0000.01172-1321080.8Page 44 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7010703 - EPA 5030BMatrix Spike Dup (7010703-MSD1)Prepared & Analyzed: 01/27/17 Source: AAA0878-02ug/L50.00080-120Surr: Dibromofluoromethane9146ug/L50.00078-120Surr: 1,2-Dichloroethane-d410552ug/L50.00080-120Surr: Toluene-d810251ug/L50.00080-120Surr: 4-Bromofluorobenzene10151Page 45 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017Laboratory CertificationsCodeDescriptionNumberExpires812Georgia DW Inorganics Eff: 07/01/201606/30/2017GADW812Georgia DW Microbiology Eff: 07/01/201503/09/2017GADWM381North Carolina12/31/2017NCE87315FL DOH (Non-Pot. Water, Solids) Eff:: 07/01/201606/30/2017NELACE87315FL DOH NELAC (Drinking Water) Eff: 07/01/201606/30/2017NELDW98011001South Carolina06/30/2017SCT104704397-08-TXTexas03/31/2017TX1340Virginia12/14/2017VAPage 46 of 48 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX (770) 734-4201PACE ANALYTICAL SERVICES, LLC.BFI Waste Systems of North America, LLC5105 Morehead Rd.Concord NC, 28027Attention: Mr. Mike GurleyFebruary 09, 2017LegendDefination of Laboratory Terms - Not Detected at levels greater than or equal to SWSL/RLNDSWSL/RLMDL - NC DENR Solid Waste Section LImit/Reporting Limit (Adjusted for DF/Prep Factor) - Method Detection LimitQualifiers - Dilution FactorDFQM-05The spike recovery was outside acceptance limits for the MS and/or MSD and/or PDS due to suspected matrix interference. Sample results for the QC batch were accepted based on acceptable LCS recoveries.JEstimated value less than Reporting Limit (RL) but greater than Method Detection Limit(MDL) (CLP J-Flag).Note: Unless otherwise noted, all results are reported on an as received basis.Page 47 of 48 Page 48 of 48