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HomeMy WebLinkAbout9202_EastWakeLandfill_MSWLF_GWMR_20171220East Wake Landfill Facility Permit No. 9202- MSWLF-1981 Semi-Annual Sampling Report (April 2017 Sampling Event) Wake County Report Prepared June 2017 5400 Glenwood Avenue, Suite 400 Raleigh, North Carolina 27612 tel: 919 325-3500 fax: 919 781-5730 June 27, 2017 Ms. Jaclynne Drummond North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section 2090 U.S. 70 Highway Swannanoa, North Carolina 28778 Subject: April 2017 (Spring) Semi-Annual Groundwater Sampling Report East Wake Landfill - Rigsbee Property Facility Permit No. 9202-MSWLF-1981 Dear Ms. Drummond: CDM Smith Inc., on behalf of Wake County (County), is submitting an electronic copy of the April 2017 semi-annual sampling event report for the East Wake Landfill - Rigsbee Property. This letter report presents the results of the most recent semi-annual sampling event and constitutes the first semi- annual sampling event for 2017. The approved groundwater monitoring network consists of one background well (i.e. MW-1), and ten downgradient monitoring wells (i.e. MW-2, -3, -4S, -4D, -5, -6, -7, -8, -9, and -10). Field activities and sampling results are discussed below. Background The East Wake Landfill (landfill) is located on two parcels. One of the parcels as shown on Figure 1 is owned by Carolyn Properties, LLC and contains approximately 27 acres of waste. This parcel is referred to as the J.T. Knott property and is currently part of the North Carolina Department of Environmental Quality’s Inactive Hazardous Sites Pre-Regulatory Landfill program. The background monitoring well for the portion of the landfill located on the James Ervin Rigsbee (Rigsbee) property, MW-1, is located on this parcel along with a private airport and several businesses. The parcel owned by Mr. Rigsbee contains approximately 46 acres of waste located in two separate areas as shown on Figure 1. This parcel borders the J.T. Knott property to the south and west. A large portion of the parcel is used for cattle pasture and includes an explosive storage company and associated storage and office trailers, a home with a detached garage and two barns, and a storage area for abandoned automobiles. All monitoring wells for the landfill, with the exception of the background well, are located on this parcel. This portion of the landfill operated under Permit Number 92-02 until the two waste disposal areas ceased operations in 1983 (Area C) and 1985 (Area D). Ms. Jaclynne Drummond June 27, 2017 Page 2 The two areas of waste located on the Rigsbee property are known as Areas C and D as shown on Figure 1. Groundwater assessment for Area C is being conducted under the supervision of the Inactive Hazardous Sites Pre-Regulatory Landfill Unit (Unit) after this area of waste was determined to be eligible for the program in the fall of 2012. The County will continue the semi-annual monitoring program for Area C until the Unit finalizes its assessment of groundwater. Field Activities Groundwater samples from the landfill monitoring wells were collected on April 27, 2017. Monitoring well MW-5 was buried underneath a stockpile and was not sampled during the spring 2017 sampling event. All samples were collected by use of disposable, laboratory decontaminated bailers. Monitoring well sampling locations are presented on Figure 1. Well construction details are provided in Table 1. Groundwater elevations were measured at each well prior to sampling and are presented in Table 2. These groundwater elevations were used to construct potentiometric contours for this sampling event and are presented on Figure 1. The groundwater elevations and potentiometric contours were used to estimate the groundwater velocity at each well. Groundwater velocity values are provided in Table 3. After depth to groundwater was determined, three well volumes of water were removed from each well prior to sampling to provide fresh formation water within the well water column. Each well volume was measured for pH, conductivity, temperature, turbidity, dissolved oxygen, and oxidation-reduction potential using a YSI-556 multi-parameter water quality meter and a HANNA HI 98703 turbidity meter. Wells that had elevated turbidity were allowed to stabilize prior to sample collection. The water quality parameters at the time of sampling are presented in Table 2. Sampling Results Shealy Environmental Services, Inc. located in West Columbia, South Carolina, analyzed the groundwater samples for the North Carolina Appendix I volatile organic compounds and metals. In accordance with Solid Waste Section (SWS) guidelines the analytical results were reported to the laboratory specific method detection limit (MDL) and are quantifiable at or below SWS Limits (SWSLs). All monitoring well locations had detections of analytes above the MDL with a majority of the detections below SWSLs. These detections were qualified as estimated or “J” flags. The following list indicates the analytes detected above the MDL at each sampling location (Area C and D monitoring wells). No “J” flag detections are provided. Underlined analytes exceeded the 15A NCAC 02L .0202 (NC 2L) Groundwater Standard or Groundwater Protection Standard. A complete summary of all detected and estimated concentrations for the April 2017 sampling event is provided in Table 4. The laboratory analytical data report is provided in Appendix A. Ms. Jaclynne Drummond June 27, 2017 Page 3 MW-1 (Background) Metals: Barium, Beryllium, Copper, Zinc Volatile Organic Compounds: None Detected AREA C MW-5 Metals: Not Sampled Volatile Organic Compounds: Not Sampled MW-6 Metals: Barium, Copper, Zinc Volatile Organic Compounds: Benzene, Chlorobenzene, 1,4-Dichlorobenzene MW-8 Metals: Barium Volatile Organic Compounds: Benzene, Chlorobenzene, 1,4-Dichlorobenzene MW-9 Metals: Barium, Cobalt Volatile Organic Compounds: Benzene, Chlorobenzene, 1,4-Dichlorobenzene MW-10 Metals: Barium Volatile Organic Compounds: Benzene, Chlorobenzene, 1,4-Dichlorobenzene AREA D MW-2 Metals: Barium, Beryllium, Copper, Lead, Vanadium, Zinc Volatile Organic Compounds: None Detected MW-3 Metals: Barium Volatile Organic Compounds: Chlorobenzene MW-4S Metals: Barium Volatile Organic Compounds: None Detected MW-4D Metals: Barium, Cobalt, Copper, Zinc Volatile Organic Compounds: Chlorobenzene, 1,4-Dichlorobenzene Ms. Jaclynne Drummond June 27, 2017 Page 4 MW-7 Metals: Beryllium, Zinc Volatile Organic Compounds: None Detected “J” flags were not included in the previous list, but several locations had “J” flag detections that exceeded the standards. The “J” flag constituents above the standards along with their locations are listed below. Cobalt: MW-1, -2, -4S, -6, -7, and -10 Thallium: MW-1, -2, and -9 Vanadium: MW-1, -3, -4S, -4D, -6, -7, -8, and -10 Vinyl Chloride: MW-9 Equipment and trip blanks were analyzed for quality control. A duplicate sample was also collected for quality control. Acetone, 2-butanone, and copper were detected as estimated concentrations in the equipment blank below their respective NC 2L Standards. No analytes were detected in the trip blank above the MDL. The duplicate sample, identified as MW-10 dup, was collected from MW-10 and had similar analyte concentrations as those detected in MW-10. Table 5 presents a summary of all parameters detected during the April 2017 sampling event that exceeded the NC 2L or Groundwater Protection Standards. Metals exceeding the standards are likely a result from elevated turbidity at the time of sample collection. Future analytical results above the standards will be monitored to determine if a trend appears. The County will continue with the semi-annual groundwater monitoring program. The next sampling event will take place during the Fall of 2017. If you have any questions or require further explanation, do not hesitate to call me at (919) 325-3500. Very truly yours, Mathew F. Colone, P.G. CDM Smith Inc. cc: John Roberson, WCSWM Elliott Cornell, WCSWM Facility Permit Number Monitoring Well Code Installation Date Latitude Longitude Geology of Screened Interval Total Depth (feet bgs) Top of Casing Elevation (feet AMSL) Screened Interval (feet) Depth to Top of Screened Interval (feet bgs) Well Diameter (inches) 9202-MSWLF-1981 MW-1 Mar 11 35.80356 78.43632 Regolith 22 305.74 13-22 13 2.0 9202-MSWLF-1981 MW-5 Mar 11 35.79453 78.44193 Regolith 16 233.60 6-16 6 2.0 9202-MSWLF-1981 MW-6 Mar 11 35.79364 78.43951 Regolith 16 244.97 7-16 7 2.0 9202-MSWLF-1981 MW-8 Mar 11 35.79216 78.44083 Regolith 17 229.83 7-17 7 2.0 9202-MSWLF-1981 MW-9 Mar 11 35.78976 78.43896 Regolith 19 229.96 10-19 10 2.0 9202-MSWLF-1981 MW-10 Mar 11 35.79106 78.43716 Bedrock 25 243.58 17-25 17 2.0 Notes: 1. bgs - Below Ground Surface 2. AMSL - Above Mean Sea Level 3. TOC - Top of Casing 4. Latitude and longitude - World Geodetic System 1984 Table 1A Well Construction Summary April 2017 Semi-Annual Sampling Event East Wake Landfill - Area C Permit Number 9202-MSWLF-1981 Page 1 of 2 June 2017 Facility Permit Number Monitoring Well Code Installation Date Latitude Longitude Geology of Screened Interval Total Depth (feet bgs) Top of Casing Elevation (feet AMSL) Screened Interval (feet) Depth to Top of Screened Interval (feet bgs) Well Diameter (inches) 9202-MSWLF-1981 MW-1 Mar 11 35.80356 78.43632 Regolith 22 305.74 13-22 13 2.0 9202-MSWLF-1981 MW-2 Mar 11 35.79904 78.44039 Regolith 16 252.38 7-16 7 2.0 9202-MSWLF-1981 MW-3 Mar 11 35.79777 78.44123 Regolith 15 237.63 7-15 7 2.0 9202-MSWLF-1981 MW-4S Mar 11 35.79566 78.44124 Bedrock 16 233.90 7-16 7 2.0 9202-MSWLF-1981 MW-4D Mar 11 35.79563 78.44121 Bedrock 21 234.32 11-21 11 2.0 9202-MSWLF-1981 MW-7 Mar 11 35.79444 78.43871 Regolith 22 261.81 13-22 13 2.0 Notes: 1. bgs - Below Ground Surface 2. AMSL - Above Mean Sea Level 3. TOC - Top of Casing 4. Latitude and longitude - World Geodetic System 1984 Table 1B Well Construction Summary April 2017 Semi-Annual Sampling Event East Wake Landfill - Area D Permit Number 9202-MSWLF-1981 Page 2 of 2 June 2017 pH Conductivity Temperature Turbidity DO ORP TOC Elevation Depth to Groundwater Groundwater Elevation (S.U.)(µS/cm)(deg. C)(NTUs)(mg/L)(mVs)(feet AMSL)(feet bgs)(feet AMSL) 9202-MSWLF-1981 MW-1 5.47 117 17.0 126 14.92(14)40.4 305.74 14.49 291.25 9202-MSWLF-1981 MW-5 233.60 9202-MSWLF-1981 MW-6 6.20 1,212 16.0 11 3.44 80.4 244.97 3.68 241.29 9202-MSWLF-1981 MW-8 6.21 688 5.0 27 6.43 78.5 229.83 3.48 226.35 9202-MSWLF-1981 MW-9 6.20 577 14.8 82 5.41 51.8 229.96 10.02 219.94 9202-MSWLF-1981 MW-10 6.49 812 15.6 18 4.58 72.8 243.58 9.51 234.07 Notes: 1. Water quality measurements were collected on April 26-27, 2017. 2. AMSL - Above Mean Sea Level 3. TOC - Top of Casing 4. bgs - Below Ground Surface 5. µS/cm - Microsiemens per centimeter 6. mg/L - Milligrams per liter 7. ORP - Oxidation-Reduction Potential 8. NTUs - Nephelometric Turbidity Units 9. mVs - Millivolts 10. S.U. - Standard Units 11. DO - Dissolved Oxygen 12. Monitoring wells with high turbidity were allowed to settle prior to sampling; turbidity shown in table was recorded at the time of sampling. 13. --(13) - Monitoring well MW-5 was inaccessible during the Spring 2017 sampling event. 14. (14) - The high DO measurement for MW-1 was due to equipment malfuction. Facility Permit Number Table 2A Water Quality Parameters April 2017 Semi-Annual Sampling Event East Wake Landfill - Area C Permit Number 9202-MSWLF-1981 --(13)--(13) Monitoring Well Code Groundwater Elevations - Measured 4/26/2017Water Quality Parameters Page 1 of 2 June 2017 pH Conductivity Temperature Turbidity DO ORP TOC Elevation Depth to Groundwater Groundwater Elevation (S.U.)(µS/cm)(deg. C)(NTUs)(mg/L)(mVs)(feet AMSL)(feet bgs)(feet AMSL) 9202-MSWLF-1981 MW-1 5.47 117 17.0 126 14.62(13)40.4 305.74 14.49 291.25 9202-MSWLF-1981 MW-2 5.61 61 17.0 291 9.50(13)118.1 252.38 8.27 244.11 9202-MSWLF-1981 MW-3 6.41 1,375 15.3 75 7.75(13)94.4 237.63 5.32 232.31 9202-MSWLF-1981 MW-4S 6.51 1,245 18.3 38 3.57 132.8 233.90 4.68 229.22 9202-MSWLF-1981 MW-4D 6.56 1,760 16.1 300 5.07 117.8 234.32 5.23 229.09 9202-MSWLF-1981 MW-7 4.98 50 19.3 64 8.53 122.9 261.81 13.28 248.53 Notes: 1. Water quality measurements were collected on April 26-27, 2017. 2. AMSL - Above Mean Sea Level 3. TOC - Top of Casing 4. bgs - Below Ground Surface 5. µS/cm - Microsiemens per centimeter 6. mg/L - Milligrams per liter 7. ORP - Oxidation-Reduction Potential 8. NTUs - Nephelometric Turbidity Units 9. mVs - Millivolts 10. S.U. - Standard Units 11. DO - Dissolved Oxygen 12. Monitoring wells with high turbidity were allowed to settle prior to sampling; turbidity shown in table was recorded at the time of sampling. 13. (13) - The high DO measurements for MW-1 through -3 were due to equipment malfuction. Facility Permit Number Monitoring Well Code Water Quality Parameters Groundwater Elevations - Measured 4/26/2017 Table 2B Water Quality Parameters April 2017 Semi-Annual Sampling Event East Wake Landfill - Area D Permit Number 9202-MSWLF-1981 Page 2 of 2 June 2017 Monitoring Well Code Hydraulic Conductivity (feet/day) Gradient Effective Porosity Average Linear Velocity (feet/day) MW-1 0.4927 0.0137 0.3 2.25E-02 MW-5 0.4927 --(3)0.3 --(3) MW-6 0.4927 0.0134 0.3 2.20E-02 MW-8 0.4927 0.0149 0.3 2.45E-02 MW-9 0.4927 0.0140 0.3 2.30E-02 MW-10 0.4927 0.0126 0.3 2.06E-02 Notes: 1. Hydraulic conductivity and porosity was based on values from HDR's 2014 Fall Semi-Annual Report. 2. Hydraulic gradient was calculated using MW-1. 3. --(3) - Monitoring well MW-5 was inaccessible during the Spring 2017 sampling event. Table 3A Summary of Calculated Groundwater Flow Velocities April 2017 Semi-Annual Sampling Event East Wake Landfill - Area C Permit Number 9202-MSWLF-1981 Page 1 of 2 June 2017 Monitoring Well Code Hydraulic Conductivity (feet/day) Gradient Effective Porosity Average Linear Velocity (feet/day) MW-1 0.4927 0.0194 0.3 3.19E-02 MW-2 0.4927 0.0231 0.3 3.80E-02 MW-3 0.4927 0.0230 0.3 3.78E-02 MW-4S 0.4927 0.0192 0.3 3.16E-02 MW-4D 0.4927 0.0192 0.3 3.16E-02 MW-7 0.4927 0.0126 0.3 2.07E-02 Notes: 1. Hydraulic conductivity and porosity was based on values from HDR's 2014 Fall Semi-Annual Report. 2. Hydraulic gradient was calculated using MW-1. Table 3B Summary of Calculated Groundwater Flow Velocities April 2017 Semi-Annual Sampling Event East Wake Landfill - Area D Permit Number 9202-MSWLF-1981 Page 2 of 2 June 2017 Table 4A Detected Groundwater Constituents April 2017 Semi-Annual Sampling Event East Wake Landfill - Area C Permit Number 9202-MSWLF-1981 Monitoring Well CodeParameterResultQualifierNorth Carolina 2L or Groundwater Protection StandardMDLSWSLUnitsBarium 230 700 0.63 100 µg/L Beryllium 1.4 4*0.13 1 µg/L Chromium 8.1 J 10 1.3 10 µg/L Cobalt 4.4 J 1*0.63 10 µg/L Copper 18 1,000 0.63 10 µg/L Lead 6.1 J 15 0.25 10 µg/L Nickel 6.4 J 100 1.3 50 µg/L Thallium 0.55 J 0.2*0.13 5.5 µg/L Vanadium 24 J 0.3*1.5 25 µg/L Zinc 54 1,000 2.5 10 µg/L MW-5 Barium 370 700 0.63 100 µg/L Beryllium 0.13 J 4*0.13 1 µg/L Cobalt 1.1 J 1*0.63 10 µg/L Copper 24 1,000 0.63 10 µg/L Lead 0.42 J 15 0.25 10 µg/L Nickel 5.7 J 100 1.3 50 µg/L Selenium 2.2 J 20 1.3 10 µg/L Vanadium 4.4 J 0.3*1.5 25 µg/L Zinc 12 1,000 2.5 10 µg/L Benzene 4.3 1 0.4 1 µg/L Chlorobenzene 9.7 50 0.4 3 µg/L 1,4-Dichlorobenzene 2.8 6 0.4 1 µg/L Dichlorodifluoromethane 1.2 J 1,000 0.4 5 µg/L 1,1-Dichloroethane 4.4 J 6 0.4 5 µg/L cis-1,2-Dichloroethene 1.7 J 70 0.4 5 µg/L Methylene Chloride 0.56 J 5 0.4 1 µg/L Arsenic 1.3 J 10 1.3 10 µg/L Barium 210 700 0.63 100 µg/L Copper 0.76 J 1,000 0.63 10 µg/L Lead 0.42 J 15 0.25 10 µg/L Vanadium 2.7 J 0.3*1.5 25 µg/L Zinc 9.4 J 1,000 2.5 10 µg/L Acetone 5.7 J 6,000 2 100 µg/L Benzene 1.6 1 0.4 1 µg/L Chlorobenzene 6.8 50 0.4 3 µg/L Chloroethane 8.3 J 3,000 0.4 10 µg/L 1,4-Dichlorobenzene 3.2 6 0.4 1 µg/L 1,1-Dichloroethane 1.0 J 6 0.4 5 µg/L MW-6 MW-1 Not Sampled(7) MW-8 Page 1 of 3 June 2017 Table 4A Detected Groundwater Constituents April 2017 Semi-Annual Sampling Event East Wake Landfill - Area C Permit Number 9202-MSWLF-1981 Monitoring Well CodeParameterResultQualifierNorth Carolina 2L or Groundwater Protection StandardMDLSWSLUnitsArsenic 1.7 J 10 1.3 10 µg/L Barium 210 700 0.63 100 µg/L Cobalt 50 1*0.63 10 µg/L Copper 0.90 J 1,000 0.63 10 µg/L Lead 0.48 J 15 0.25 10 µg/L Thallium 0.27 J 0.2*0.13 5.5 µg/L Zinc 6.7 J 1,000 2.5 10 µg/L Acetone 8.4 J 6,000 2 100 µg/L Benzene 2.3 1 0.4 1 µg/L Chlorobenzene 8.3 50 0.4 3 µg/L 1,4-Dichlorobenzene 8.9 6 0.4 1 µg/L Dichlorodifluoromethane 0.42 J 1,000 0.4 5 µg/L 1,1-Dichloroethane 0.70 J 6 0.4 5 µg/L Vinyl Chloride 0.72 J 0.03 0.4 1 µg/L Barium 300 700 0.63 100 µg/L Beryllium 0.32 J 4*0.13 1 µg/L Cobalt 8.1 J 1*0.63 10 µg/L Copper 1.9 J 1,000 0.63 10 µg/L Lead 0.32 J 15 0.25 10 µg/L Vanadium 2.6 J 0.3*1.5 25 µg/L Zinc 3.4 J 1,000 2.5 10 µg/L Acetone 4.9 J 6,000 2 100 µg/L Benzene 1.7 1 0.4 1 µg/L Chlorobenzene 19 50 0.4 3 µg/L 1,2-Dichlorobenzene 0.67 J 20 0.4 5 µg/L 1,4-Dichlorobenzene 4.2 6 0.4 1 µg/L 1,1-Dichloroethane 0.55 J 6 0.4 5 µg/L MW-9 MW-10 Page 2 of 3 June 2017 Table 4A Detected Groundwater Constituents April 2017 Semi-Annual Sampling Event East Wake Landfill - Area C Permit Number 9202-MSWLF-1981 Monitoring Well CodeParameterResultQualifierNorth Carolina 2L or Groundwater Protection StandardMDLSWSLUnitsBarium 320 700 0.63 100 µg/L Beryllium 0.35 J 4*0.13 1 µg/L Cobalt 8.5 J 1*0.63 10 µg/L Copper 2.3 J 1,000 0.63 10 µg/L Lead 0.40 J 15 0.25 10 µg/L Vanadium 2.5 J 0.3*1.5 25 µg/L Zinc 3.6 J 1,000 2.5 10 µg/L Acetone 4.4 J 6,000 2 100 µg/L Benzene 1.7 1 0.4 1 µg/L Chlorobenzene 19 50 0.4 3 µg/L 1,2-Dichlorobenzene 0.67 J 20 0.4 5 µg/L 1,4-Dichlorobenzene 4.3 6 0.4 1 µg/L 1,1-Dichloroethane 0.56 J 6 0.4 5 µg/L Notes: 1. All units are in micrograms per liter (parts per billion). 2. * - Groundwater Protection Standard 3. MDL - Method Detection Limit 4. SWSL - Solid Waste Section Limit 5. dup - Duplicate Sample 6. J - Indicates the analytical result is an estimated concentration between the method detection limit and the Solid Waste Section Reporting Limit. 7. (7) - MW-5 was inaccessible during the Spring 2017 sampling event and was not sampled. - Concentration exceeds the 15A NCAC 02L .0202 or Groundwater Protection Standard MW-10 (dup) Page 3 of 3 June 2017 Table 4B Detected Groundwater Constituents April 2017 Semi-Annual Sampling Event East Wake Landfill - Area D Permit Number 9202-MSWLF-1981 Monitoring Well CodeParameterResultQualifierNorth Carolina 2L or Groundwater Protection StandardMDLSWSLUnitsBarium 230 700 0.63 100 µg/L Beryllium 1.4 4*0.13 1 µg/L Chromium 8.1 J 10 1.3 10 µg/L Cobalt 4.4 J 1*0.63 10 µg/L Copper 18 1,000 0.63 10 µg/L Lead 6.1 J 15 0.25 10 µg/L Nickel 6.4 J 100 1.3 50 µg/L Thallium 0.55 J 0.2*0.13 5.5 µg/L Vanadium 24 J 0.3*1.5 25 µg/L Zinc 54 1,000 2.5 10 µg/L Antimony 0.63 J 1*0.5 6 µg/L Barium 120 700 0.63 100 µg/L Beryllium 1.5 4*0.13 1 µg/L Chromium 8.1 J 10 1.3 10 µg/L Cobalt 4.7 J 1*0.63 10 µg/L Copper 23 1,000 0.63 10 µg/L Lead 14 15 0.25 10 µg/L Nickel 3.4 J 100 1.3 50 µg/L Thallium 0.56 J 0.2*0.13 5.5 µg/L Vanadium 25 0.3*1.5 25 µg/L Zinc 140 1,000 2.5 10 µg/L Barium 370 700 0.63 100 µg/L Copper 1.0 J 1,000 0.63 10 µg/L Lead 0.26 J 15 0.25 10 µg/L Selenium 2.0 J 20 1.3 10 µg/L Vanadium 1.6 J 0.3*1.5 25 µg/L Acetone 13 J 6,000 2 100 µg/L Benzene 0.77 J 1 0.4 1 µg/L Chlorobenzene 3.6 50 0.4 3 µg/L 1,4-Dichlorobenzene 0.94 J 6 0.4 1 µg/L Barium 150 700 0.63 100 µg/L Cobalt 2.1 J 1*0.63 10 µg/L Copper 1.6 J 1,000 0.63 10 µg/L Lead 0.37 J 15 0.25 10 µg/L Vanadium 2.6 J 0.3*1.5 25 µg/L Zinc 4.1 J 1,000 2.5 10 µg/L MW-1 MW-2 MW-4S MW-3 Page 1 of 2 June 2017 Table 4B Detected Groundwater Constituents April 2017 Semi-Annual Sampling Event East Wake Landfill - Area D Permit Number 9202-MSWLF-1981 Monitoring Well CodeParameterResultQualifierNorth Carolina 2L or Groundwater Protection StandardMDLSWSLUnitsArsenic 3.5 J 10 1.3 10 µg/L Barium 940 700 0.63 100 µg/L Cobalt 17 1*0.63 10 µg/L Copper 17 1,000 0.63 10 µg/L Lead 1.4 J 15 0.25 10 µg/L Nickel 9.7 J 100 1.3 50 µg/L Selenium 3.9 J 20 1.3 10 µg/L Vanadium 6.9 J 0.3*1.5 25 µg/L Zinc 28 1,000 2.5 10 µg/L Acetone 4.3 J 6,000 2 100 µg/L Benzene 0.41 J 1 0.4 1 µg/L Chlorobenzene 5.3 50 0.4 3 µg/L 1,1-Dichloroethane 0.57 J 6 0.4 5 µg/L 1,4-Dichlorobenzene 1.5 6 0.4 1 µg/L Barium 93 J 700 0.63 100 µg/L Beryllium 1.1 4*0.13 1 µg/L Cobalt 2.2 J 1*0.63 10 µg/L Copper 2.3 J 1,000 0.63 10 µg/L Lead 1.3 J 15 0.25 10 µg/L Vanadium 5.4 J 0.3*1.5 25 µg/L Zinc 11 1,000 2.5 10 µg/L Notes: 1. All units are in micrograms per liter (parts per billion). 2. * - Groundwater Protection Standard 3. MDL - Method Detection Limit 4. SWSL - Solid Waste Section Limit Section Reporting Limit. - Concentration exceeds the 15A NCAC 02L .0202 or Groundwater Protection Standard 5. J - Indicates the analytical result is an estimated concentration between the method detection limit and the Solid Waste MW-7 MW-4D Page 2 of 2 June 2017 Table 5A Constituents Detected Above Standards April 2017 Semi-Annual Sampling Event East Wake Landfill - Area C Permit Number 9202-MSWLF-1981 APRIL 2017 CONSTITUENTS EXCEEDING THE NORTH CAROLINA 2L or GROUNDWATER PROTECTION STANDARDS MW-1 Cobalt*, Thallium*, Vanadium* MW-5 Not Sampled(3) MW-6 Cobalt*, Vanadium*, Benzene MW-8 Vanadium*, Benzene MW-9 Cobalt*, Thallium*, Benzene, 1,4-Dichlorobenzene, Vinyl Chloride MW-10 Cobalt*, Vanadium*, Benzene Notes: 1. * - Groundwater Protection Standard 3. (3) - MW-5 was inaccessible during the Spring 2017 sampling event and was not sampled. 2. Bold - Indicates a "J" flag detection in which the analytical result is an estimated concentration between the laboratory method detection limit and the Solid Waste Section Limit. MONITORING WELL CODE Page 1 of 2 June 2017 Table 5B Constituents Detected Above Standards April 2017 Semi-Annual Sampling Event East Wake Landfill - Area D Permit Number 9202-MSWLF-1981 APRIL 2017 CONSTITUENTS EXCEEDING THE NORTH CAROLINA 2L or GROUNDWATER PROTECTION STANDARDS MW-1 Cobalt*, Thallium*, Vanadium* MW-2 Cobalt*, Thallium*, Vanadium* MW-3 Vanadium* MW-4S Cobalt*, Vanadium* MW-4D Barium, Cobalt*, Thallium* MW-7 Cobalt*, Vanadium* Notes: 1. * - Groundwater Protection Standard MONITORING WELL CODE 2. Bold - Indicates a "J" flag detection in which the analytical result is an estimated concentration between the laboratory method detection limit and the Solid Waste Section Limit. Page 2 of 2 June 2017 Appendix A Analytical Data SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis CDM Smith 5400 Glenwood Avenue Suite 400 Raleigh, NC 27612 Attention: Mathew Colone SD28010Lot Number: East Wake LandfillProject Name: 05/09/2017Date Completed: Catherine S. Dover Project Manager This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Page: 1 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Case Narrative CDM Smith Lot Number: SD28010 SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329 Project Name: East Wake Landfill Project Number: This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. VOC 8260B The associated continuing calibration verification (CCV) recovered above the upper control limit for DCDFM, Acetone and Acrylonitrile. The associated samples for this CCV were non-detect for these three analytes; therefore, the data has been reported except sample SD28010-003 (MW-3) for Acetone and SD28020-006 (MW-6) for DCDFM. Both of these samples were rerun for affected targets. The CCV associated with the re-analysis passed criteria. Page: 2 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary CDM Smith Lot Number: SD28010 Project Name: East Wake Landfill Project Number: Sample Number Sample ID Matrix Date Sampled Date Received 001 04/27/2017 1420MW-1 Aqueous 04/28/2017 002 04/27/2017 1130MW-2 Aqueous 04/28/2017 003 04/27/2017 1145MW-3 Aqueous 04/28/2017 004 04/27/2017 1200MW-4s Aqueous 04/28/2017 005 04/27/2017 1215MW-4d Aqueous 04/28/2017 006 04/27/2017 1305MW-6 Aqueous 04/28/2017 007 04/27/2017 1245MW-7 Aqueous 04/28/2017 008 04/27/2017 1330MW-8 Aqueous 04/28/2017 009 04/27/2017 1345MW-9 Aqueous 04/28/2017 010 04/27/2017 1030MW-10 Aqueous 04/28/2017 011 04/27/2017 1000DUPAqueous 04/28/2017 012 04/27/2017 1400EQ BLANK Aqueous 04/28/2017 013 04/27/2017TRIP BLANK Aqueous 04/28/2017 (13 samples) Page: 3 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-1 SD28010-001 04/27/2017 1420 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1322 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B 10 U 1ug/L2.010 Acrylonitrile 107-13-1 8260B 5.0 U 1ug/L0.805.0 Benzene 71-43-2 8260B 0.50 U 1ug/L0.400.50 Bromochloromethane 74-97-5 8260B 0.50 U 1ug/L0.400.50 Bromodichloromethane 75-27-4 8260B 0.50 U 1ug/L0.400.50 Bromoform 75-25-2 8260B 0.50 U 1ug/L0.400.50 Bromomethane (Methyl bromide)74-83-9 8260B 0.50 U 1ug/L0.400.50 2-Butanone (MEK)78-93-3 8260B 10 U 1ug/L2.010 Carbon disulfide 75-15-0 8260B 0.50 U 1ug/L0.400.50 Carbon tetrachloride 56-23-5 8260B 0.50 U 1ug/L0.400.50 Chlorobenzene 108-90-7 8260B 0.50 U 1ug/L0.400.50 Chloroethane 75-00-3 8260B 0.50 U 1ug/L0.400.50 Chloroform 67-66-3 8260B 0.50 U 1ug/L0.400.50 Chloromethane (Methyl chloride)74-87-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B 0.50 U 1ug/L0.400.50 Dibromochloromethane 124-48-1 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromoethane (EDB)106-93-4 8260B 0.50 U 1ug/L0.400.50 Dibromomethane (Methylene bromide)74-95-3 8260B 0.50 U 1ug/L0.400.50 trans-1,4-Dichloro-2-butene 110-57-6 8260B 2.0 U 1ug/L0.402.0 1,2-Dichlorobenzene 95-50-1 8260B 0.50 U 1ug/L0.400.50 1,4-Dichlorobenzene 106-46-7 8260B 0.50 U 1ug/L0.400.50 Dichlorodifluoromethane 75-71-8 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethane 75-34-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloroethane 107-06-2 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethene 75-35-4 8260B 0.50 U 1ug/L0.400.50 cis-1,2-Dichloroethene 156-59-2 8260B 0.50 U 1ug/L0.400.50 trans-1,2-Dichloroethene 156-60-5 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloropropane 78-87-5 8260B 0.50 U 1ug/L0.400.50 cis-1,3-Dichloropropene 10061-01-5 8260B 0.50 U 1ug/L0.400.50 trans-1,3-Dichloropropene 10061-02-6 8260B 0.50 U 1ug/L0.400.50 Ethylbenzene 100-41-4 8260B 0.50 U 1ug/L0.400.50 2-Hexanone 591-78-6 8260B 10 U 1ug/L2.010 Methyl iodide (Iodomethane)74-88-4 8260B 5.0 U 1ug/L0.405.0 4-Methyl-2-pentanone 108-10-1 8260B 10 U 1ug/L2.010 Methylene chloride 75-09-2 8260B 0.50 U 1ug/L0.400.50 Styrene 100-42-5 8260B 0.50 U 1ug/L0.400.50 1,1,1,2-Tetrachloroethane 630-20-6 8260B 0.50 U 1ug/L0.400.50 1,1,2,2-Tetrachloroethane 79-34-5 8260B 0.50 U 1ug/L0.400.50 Tetrachloroethene 127-18-4 8260B 0.50 U 1ug/L0.400.50 Toluene 108-88-3 8260B 0.50 U 1ug/L0.400.50 1,1,1-Trichloroethane 71-55-6 8260B 0.50 U 1ug/L0.400.50 1,1,2-Trichloroethane 79-00-5 8260B 0.50 U 1ug/L0.400.50 Trichloroethene 79-01-6 8260B 0.50 U 1ug/L0.400.50 Trichlorofluoromethane 75-69-4 8260B 0.50 U 1ug/L0.400.50 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 4 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-1 SD28010-001 04/27/2017 1420 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1322 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,2,3-Trichloropropane 96-18-4 8260B 0.50 U 1ug/L0.400.50 Vinyl acetate 108-05-4 8260B 5.0 U 1ug/L1.25.0 Vinyl chloride 75-01-4 8260B 0.50 U 1ug/L0.400.50 Xylenes (total)1330-20-7 8260B 1.0 U 1ug/L0.401.0 AcceptanceRun 1 Surrogate Q % Recovery Limits Bromofluorobenzene 104 70-130 1,2-Dichloroethane-d4 106 70-130 Toluene-d8 103 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 5 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-1 SD28010-001 04/27/2017 1420 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/04/2017 1006 BNW 04/28/2017 1749 40786 2 3005A 6020B 1 05/05/2017 2014 MJI 04/28/2017 1749 40786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Antimony 7440-36-0 6020B 6.0 U 1ug/L0.506.0 Arsenic 7440-38-2 6020B 10 U 1ug/L1.310 Barium 7440-39-3 6020B 230 1ug/L0.63100 Beryllium 7440-41-7 6020B 1.4 1ug/L0.131.0 Cadmium 7440-43-9 6020B 1.0 U 2ug/L0.131.0 Chromium 7440-47-3 6020B 8.1 J 1ug/L1.310 Cobalt 7440-48-4 6020B 4.4 J 1ug/L0.6310 Copper 7440-50-8 6020B 18 1ug/L0.6310 Lead 7439-92-1 6020B 6.1 J 1ug/L0.2510 Nickel 7440-02-0 6020B 6.4 J 1ug/L1.350 Selenium 7782-49-2 6020B 10 U 1ug/L1.310 Silver 7440-22-4 6020B 10 U 1ug/L0.2510 Thallium 7440-28-0 6020B 0.55 J 1ug/L0.135.5 Vanadium 7440-62-2 6020B 24 J 1ug/L1.525 Zinc 7440-66-6 6020B 54 1ug/L2.510 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 6 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-2 SD28010-002 04/27/2017 1130 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1343 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B 10 U 1ug/L2.010 Acrylonitrile 107-13-1 8260B 5.0 U 1ug/L0.805.0 Benzene 71-43-2 8260B 0.50 U 1ug/L0.400.50 Bromochloromethane 74-97-5 8260B 0.50 U 1ug/L0.400.50 Bromodichloromethane 75-27-4 8260B 0.50 U 1ug/L0.400.50 Bromoform 75-25-2 8260B 0.50 U 1ug/L0.400.50 Bromomethane (Methyl bromide)74-83-9 8260B 0.50 U 1ug/L0.400.50 2-Butanone (MEK)78-93-3 8260B 10 U 1ug/L2.010 Carbon disulfide 75-15-0 8260B 0.50 U 1ug/L0.400.50 Carbon tetrachloride 56-23-5 8260B 0.50 U 1ug/L0.400.50 Chlorobenzene 108-90-7 8260B 0.50 U 1ug/L0.400.50 Chloroethane 75-00-3 8260B 0.50 U 1ug/L0.400.50 Chloroform 67-66-3 8260B 0.50 U 1ug/L0.400.50 Chloromethane (Methyl chloride)74-87-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B 0.50 U 1ug/L0.400.50 Dibromochloromethane 124-48-1 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromoethane (EDB)106-93-4 8260B 0.50 U 1ug/L0.400.50 Dibromomethane (Methylene bromide)74-95-3 8260B 0.50 U 1ug/L0.400.50 trans-1,4-Dichloro-2-butene 110-57-6 8260B 2.0 U 1ug/L0.402.0 1,2-Dichlorobenzene 95-50-1 8260B 0.50 U 1ug/L0.400.50 1,4-Dichlorobenzene 106-46-7 8260B 0.50 U 1ug/L0.400.50 Dichlorodifluoromethane 75-71-8 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethane 75-34-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloroethane 107-06-2 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethene 75-35-4 8260B 0.50 U 1ug/L0.400.50 cis-1,2-Dichloroethene 156-59-2 8260B 0.50 U 1ug/L0.400.50 trans-1,2-Dichloroethene 156-60-5 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloropropane 78-87-5 8260B 0.50 U 1ug/L0.400.50 cis-1,3-Dichloropropene 10061-01-5 8260B 0.50 U 1ug/L0.400.50 trans-1,3-Dichloropropene 10061-02-6 8260B 0.50 U 1ug/L0.400.50 Ethylbenzene 100-41-4 8260B 0.50 U 1ug/L0.400.50 2-Hexanone 591-78-6 8260B 10 U 1ug/L2.010 Methyl iodide (Iodomethane)74-88-4 8260B 5.0 U 1ug/L0.405.0 4-Methyl-2-pentanone 108-10-1 8260B 10 U 1ug/L2.010 Methylene chloride 75-09-2 8260B 0.50 U 1ug/L0.400.50 Styrene 100-42-5 8260B 0.50 U 1ug/L0.400.50 1,1,1,2-Tetrachloroethane 630-20-6 8260B 0.50 U 1ug/L0.400.50 1,1,2,2-Tetrachloroethane 79-34-5 8260B 0.50 U 1ug/L0.400.50 Tetrachloroethene 127-18-4 8260B 0.50 U 1ug/L0.400.50 Toluene 108-88-3 8260B 0.50 U 1ug/L0.400.50 1,1,1-Trichloroethane 71-55-6 8260B 0.50 U 1ug/L0.400.50 1,1,2-Trichloroethane 79-00-5 8260B 0.50 U 1ug/L0.400.50 Trichloroethene 79-01-6 8260B 0.50 U 1ug/L0.400.50 Trichlorofluoromethane 75-69-4 8260B 0.50 U 1ug/L0.400.50 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 7 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-2 SD28010-002 04/27/2017 1130 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1343 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,2,3-Trichloropropane 96-18-4 8260B 0.50 U 1ug/L0.400.50 Vinyl acetate 108-05-4 8260B 5.0 U 1ug/L1.25.0 Vinyl chloride 75-01-4 8260B 0.50 U 1ug/L0.400.50 Xylenes (total)1330-20-7 8260B 1.0 U 1ug/L0.401.0 AcceptanceRun 1 Surrogate Q % Recovery Limits Bromofluorobenzene 108 70-130 1,2-Dichloroethane-d4 109 70-130 Toluene-d8 105 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 8 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-2 SD28010-002 04/27/2017 1130 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/04/2017 1043 BNW 04/28/2017 1749 40786 2 3005A 6020B 1 05/05/2017 2040 MJI 04/28/2017 1749 40786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Antimony 7440-36-0 6020B 0.63 J 1ug/L0.506.0 Arsenic 7440-38-2 6020B 10 U 1ug/L1.310 Barium 7440-39-3 6020B 120 1ug/L0.63100 Beryllium 7440-41-7 6020B 1.5 1ug/L0.131.0 Cadmium 7440-43-9 6020B 1.0 U 2ug/L0.131.0 Chromium 7440-47-3 6020B 8.1 J 1ug/L1.310 Cobalt 7440-48-4 6020B 4.7 J 1ug/L0.6310 Copper 7440-50-8 6020B 23 1ug/L0.6310 Lead 7439-92-1 6020B 14 1ug/L0.2510 Nickel 7440-02-0 6020B 3.4 J 1ug/L1.350 Selenium 7782-49-2 6020B 10 U 1ug/L1.310 Silver 7440-22-4 6020B 10 U 1ug/L0.2510 Thallium 7440-28-0 6020B 0.56 J 1ug/L0.135.5 Vanadium 7440-62-2 6020B 25 1ug/L1.525 Zinc 7440-66-6 6020B 140 1ug/L2.510 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 9 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-3 SD28010-003 04/27/2017 1145 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1405 ALL 40863 2 5030B 8260B 1 05/02/2017 0454 ECP 40923 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B 13 2ug/L2.010 Acrylonitrile 107-13-1 8260B 5.0 U 1ug/L0.805.0 Benzene 71-43-2 8260B 0.77 1ug/L0.400.50 Bromochloromethane 74-97-5 8260B 0.50 U 1ug/L0.400.50 Bromodichloromethane 75-27-4 8260B 0.50 U 1ug/L0.400.50 Bromoform 75-25-2 8260B 0.50 U 1ug/L0.400.50 Bromomethane (Methyl bromide)74-83-9 8260B 0.50 U 1ug/L0.400.50 2-Butanone (MEK)78-93-3 8260B 10 U 1ug/L2.010 Carbon disulfide 75-15-0 8260B 0.50 U 1ug/L0.400.50 Carbon tetrachloride 56-23-5 8260B 0.50 U 1ug/L0.400.50 Chlorobenzene 108-90-7 8260B 3.6 1ug/L0.400.50 Chloroethane 75-00-3 8260B 0.50 U 1ug/L0.400.50 Chloroform 67-66-3 8260B 0.50 U 1ug/L0.400.50 Chloromethane (Methyl chloride)74-87-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B 0.50 U 1ug/L0.400.50 Dibromochloromethane 124-48-1 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromoethane (EDB)106-93-4 8260B 0.50 U 1ug/L0.400.50 Dibromomethane (Methylene bromide)74-95-3 8260B 0.50 U 1ug/L0.400.50 trans-1,4-Dichloro-2-butene 110-57-6 8260B 2.0 U 1ug/L0.402.0 1,2-Dichlorobenzene 95-50-1 8260B 0.50 U 1ug/L0.400.50 1,4-Dichlorobenzene 106-46-7 8260B 0.94 1ug/L0.400.50 Dichlorodifluoromethane 75-71-8 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethane 75-34-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloroethane 107-06-2 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethene 75-35-4 8260B 0.50 U 1ug/L0.400.50 cis-1,2-Dichloroethene 156-59-2 8260B 0.50 U 1ug/L0.400.50 trans-1,2-Dichloroethene 156-60-5 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloropropane 78-87-5 8260B 0.50 U 1ug/L0.400.50 cis-1,3-Dichloropropene 10061-01-5 8260B 0.50 U 1ug/L0.400.50 trans-1,3-Dichloropropene 10061-02-6 8260B 0.50 U 1ug/L0.400.50 Ethylbenzene 100-41-4 8260B 0.50 U 1ug/L0.400.50 2-Hexanone 591-78-6 8260B 10 U 1ug/L2.010 Methyl iodide (Iodomethane)74-88-4 8260B 5.0 U 1ug/L0.405.0 4-Methyl-2-pentanone 108-10-1 8260B 10 U 1ug/L2.010 Methylene chloride 75-09-2 8260B 0.50 U 1ug/L0.400.50 Styrene 100-42-5 8260B 0.50 U 1ug/L0.400.50 1,1,1,2-Tetrachloroethane 630-20-6 8260B 0.50 U 1ug/L0.400.50 1,1,2,2-Tetrachloroethane 79-34-5 8260B 0.50 U 1ug/L0.400.50 Tetrachloroethene 127-18-4 8260B 0.50 U 1ug/L0.400.50 Toluene 108-88-3 8260B 0.50 U 1ug/L0.400.50 1,1,1-Trichloroethane 71-55-6 8260B 0.50 U 1ug/L0.400.50 1,1,2-Trichloroethane 79-00-5 8260B 0.50 U 1ug/L0.400.50 Trichloroethene 79-01-6 8260B 0.50 U 1ug/L0.400.50 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 10 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-3 SD28010-003 04/27/2017 1145 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1405 ALL 40863 2 5030B 8260B 1 05/02/2017 0454 ECP 40923 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Trichlorofluoromethane 75-69-4 8260B 0.50 U 1ug/L0.400.50 1,2,3-Trichloropropane 96-18-4 8260B 0.50 U 1ug/L0.400.50 Vinyl acetate 108-05-4 8260B 5.0 U 1ug/L1.25.0 Vinyl chloride 75-01-4 8260B 0.50 U 1ug/L0.400.50 Xylenes (total)1330-20-7 8260B 1.0 U 1ug/L0.401.0 AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ Bromofluorobenzene 100 70-130 104 70-130 1,2-Dichloroethane-d4 107 70-130 109 70-130 Toluene-d8 102 70-130 103 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 11 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-3 SD28010-003 04/27/2017 1145 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/04/2017 1049 BNW 04/28/2017 1749 40786 2 3005A 6020B 1 05/05/2017 2057 MJI 04/28/2017 1749 40786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Antimony 7440-36-0 6020B 6.0 U 1ug/L0.506.0 Arsenic 7440-38-2 6020B 10 U 1ug/L1.310 Barium 7440-39-3 6020B 370 1ug/L0.63100 Beryllium 7440-41-7 6020B 1.0 U 1ug/L0.131.0 Cadmium 7440-43-9 6020B 1.0 U 2ug/L0.131.0 Chromium 7440-47-3 6020B 10 U 1ug/L1.310 Cobalt 7440-48-4 6020B 10 U 1ug/L0.6310 Copper 7440-50-8 6020B 1.0 J 1ug/L0.6310 Lead 7439-92-1 6020B 0.26 J 1ug/L0.2510 Nickel 7440-02-0 6020B 50 U 1ug/L1.350 Selenium 7782-49-2 6020B 2.0 J 1ug/L1.310 Silver 7440-22-4 6020B 10 U 1ug/L0.2510 Thallium 7440-28-0 6020B 5.5 U 1ug/L0.135.5 Vanadium 7440-62-2 6020B 1.6 J 1ug/L1.525 Zinc 7440-66-6 6020B 10 U 1ug/L2.510 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 12 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-4s SD28010-004 04/27/2017 1200 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1427 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B 10 U 1ug/L2.010 Acrylonitrile 107-13-1 8260B 5.0 U 1ug/L0.805.0 Benzene 71-43-2 8260B 0.50 U 1ug/L0.400.50 Bromochloromethane 74-97-5 8260B 0.50 U 1ug/L0.400.50 Bromodichloromethane 75-27-4 8260B 0.50 U 1ug/L0.400.50 Bromoform 75-25-2 8260B 0.50 U 1ug/L0.400.50 Bromomethane (Methyl bromide)74-83-9 8260B 0.50 U 1ug/L0.400.50 2-Butanone (MEK)78-93-3 8260B 10 U 1ug/L2.010 Carbon disulfide 75-15-0 8260B 0.50 U 1ug/L0.400.50 Carbon tetrachloride 56-23-5 8260B 0.50 U 1ug/L0.400.50 Chlorobenzene 108-90-7 8260B 0.50 U 1ug/L0.400.50 Chloroethane 75-00-3 8260B 0.50 U 1ug/L0.400.50 Chloroform 67-66-3 8260B 0.50 U 1ug/L0.400.50 Chloromethane (Methyl chloride)74-87-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B 0.50 U 1ug/L0.400.50 Dibromochloromethane 124-48-1 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromoethane (EDB)106-93-4 8260B 0.50 U 1ug/L0.400.50 Dibromomethane (Methylene bromide)74-95-3 8260B 0.50 U 1ug/L0.400.50 trans-1,4-Dichloro-2-butene 110-57-6 8260B 2.0 U 1ug/L0.402.0 1,2-Dichlorobenzene 95-50-1 8260B 0.50 U 1ug/L0.400.50 1,4-Dichlorobenzene 106-46-7 8260B 0.50 U 1ug/L0.400.50 Dichlorodifluoromethane 75-71-8 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethane 75-34-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloroethane 107-06-2 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethene 75-35-4 8260B 0.50 U 1ug/L0.400.50 cis-1,2-Dichloroethene 156-59-2 8260B 0.50 U 1ug/L0.400.50 trans-1,2-Dichloroethene 156-60-5 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloropropane 78-87-5 8260B 0.50 U 1ug/L0.400.50 cis-1,3-Dichloropropene 10061-01-5 8260B 0.50 U 1ug/L0.400.50 trans-1,3-Dichloropropene 10061-02-6 8260B 0.50 U 1ug/L0.400.50 Ethylbenzene 100-41-4 8260B 0.50 U 1ug/L0.400.50 2-Hexanone 591-78-6 8260B 10 U 1ug/L2.010 Methyl iodide (Iodomethane)74-88-4 8260B 5.0 U 1ug/L0.405.0 4-Methyl-2-pentanone 108-10-1 8260B 10 U 1ug/L2.010 Methylene chloride 75-09-2 8260B 0.50 U 1ug/L0.400.50 Styrene 100-42-5 8260B 0.50 U 1ug/L0.400.50 1,1,1,2-Tetrachloroethane 630-20-6 8260B 0.50 U 1ug/L0.400.50 1,1,2,2-Tetrachloroethane 79-34-5 8260B 0.50 U 1ug/L0.400.50 Tetrachloroethene 127-18-4 8260B 0.50 U 1ug/L0.400.50 Toluene 108-88-3 8260B 0.50 U 1ug/L0.400.50 1,1,1-Trichloroethane 71-55-6 8260B 0.50 U 1ug/L0.400.50 1,1,2-Trichloroethane 79-00-5 8260B 0.50 U 1ug/L0.400.50 Trichloroethene 79-01-6 8260B 0.50 U 1ug/L0.400.50 Trichlorofluoromethane 75-69-4 8260B 0.50 U 1ug/L0.400.50 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 13 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-4s SD28010-004 04/27/2017 1200 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1427 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,2,3-Trichloropropane 96-18-4 8260B 0.50 U 1ug/L0.400.50 Vinyl acetate 108-05-4 8260B 5.0 U 1ug/L1.25.0 Vinyl chloride 75-01-4 8260B 0.50 U 1ug/L0.400.50 Xylenes (total)1330-20-7 8260B 1.0 U 1ug/L0.401.0 AcceptanceRun 1 Surrogate Q % Recovery Limits Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 109 70-130 Toluene-d8 100 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 14 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-4s SD28010-004 04/27/2017 1200 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/04/2017 1054 BNW 04/28/2017 1749 40786 2 3005A 6020B 1 05/05/2017 2102 MJI 04/28/2017 1749 40786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Antimony 7440-36-0 6020B 6.0 U 1ug/L0.506.0 Arsenic 7440-38-2 6020B 10 U 1ug/L1.310 Barium 7440-39-3 6020B 150 1ug/L0.63100 Beryllium 7440-41-7 6020B 1.0 U 1ug/L0.131.0 Cadmium 7440-43-9 6020B 1.0 U 2ug/L0.131.0 Chromium 7440-47-3 6020B 10 U 1ug/L1.310 Cobalt 7440-48-4 6020B 2.1 J 1ug/L0.6310 Copper 7440-50-8 6020B 1.6 J 1ug/L0.6310 Lead 7439-92-1 6020B 0.37 J 1ug/L0.2510 Nickel 7440-02-0 6020B 50 U 1ug/L1.350 Selenium 7782-49-2 6020B 10 U 1ug/L1.310 Silver 7440-22-4 6020B 10 U 1ug/L0.2510 Thallium 7440-28-0 6020B 5.5 U 1ug/L0.135.5 Vanadium 7440-62-2 6020B 2.6 J 1ug/L1.525 Zinc 7440-66-6 6020B 4.1 J 1ug/L2.510 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 15 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-4d SD28010-005 04/27/2017 1215 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1449 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B 4.3 J 1ug/L2.010 Acrylonitrile 107-13-1 8260B 5.0 U 1ug/L0.805.0 Benzene 71-43-2 8260B 0.41 J 1ug/L0.400.50 Bromochloromethane 74-97-5 8260B 0.50 U 1ug/L0.400.50 Bromodichloromethane 75-27-4 8260B 0.50 U 1ug/L0.400.50 Bromoform 75-25-2 8260B 0.50 U 1ug/L0.400.50 Bromomethane (Methyl bromide)74-83-9 8260B 0.50 U 1ug/L0.400.50 2-Butanone (MEK)78-93-3 8260B 10 U 1ug/L2.010 Carbon disulfide 75-15-0 8260B 0.50 U 1ug/L0.400.50 Carbon tetrachloride 56-23-5 8260B 0.50 U 1ug/L0.400.50 Chlorobenzene 108-90-7 8260B 5.3 1ug/L0.400.50 Chloroethane 75-00-3 8260B 0.50 U 1ug/L0.400.50 Chloroform 67-66-3 8260B 0.50 U 1ug/L0.400.50 Chloromethane (Methyl chloride)74-87-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B 0.50 U 1ug/L0.400.50 Dibromochloromethane 124-48-1 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromoethane (EDB)106-93-4 8260B 0.50 U 1ug/L0.400.50 Dibromomethane (Methylene bromide)74-95-3 8260B 0.50 U 1ug/L0.400.50 trans-1,4-Dichloro-2-butene 110-57-6 8260B 2.0 U 1ug/L0.402.0 1,2-Dichlorobenzene 95-50-1 8260B 0.50 U 1ug/L0.400.50 1,4-Dichlorobenzene 106-46-7 8260B 1.5 1ug/L0.400.50 Dichlorodifluoromethane 75-71-8 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethane 75-34-3 8260B 0.57 1ug/L0.400.50 1,2-Dichloroethane 107-06-2 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethene 75-35-4 8260B 0.50 U 1ug/L0.400.50 cis-1,2-Dichloroethene 156-59-2 8260B 0.50 U 1ug/L0.400.50 trans-1,2-Dichloroethene 156-60-5 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloropropane 78-87-5 8260B 0.50 U 1ug/L0.400.50 cis-1,3-Dichloropropene 10061-01-5 8260B 0.50 U 1ug/L0.400.50 trans-1,3-Dichloropropene 10061-02-6 8260B 0.50 U 1ug/L0.400.50 Ethylbenzene 100-41-4 8260B 0.50 U 1ug/L0.400.50 2-Hexanone 591-78-6 8260B 10 U 1ug/L2.010 Methyl iodide (Iodomethane)74-88-4 8260B 5.0 U 1ug/L0.405.0 4-Methyl-2-pentanone 108-10-1 8260B 10 U 1ug/L2.010 Methylene chloride 75-09-2 8260B 0.50 U 1ug/L0.400.50 Styrene 100-42-5 8260B 0.50 U 1ug/L0.400.50 1,1,1,2-Tetrachloroethane 630-20-6 8260B 0.50 U 1ug/L0.400.50 1,1,2,2-Tetrachloroethane 79-34-5 8260B 0.50 U 1ug/L0.400.50 Tetrachloroethene 127-18-4 8260B 0.50 U 1ug/L0.400.50 Toluene 108-88-3 8260B 0.50 U 1ug/L0.400.50 1,1,1-Trichloroethane 71-55-6 8260B 0.50 U 1ug/L0.400.50 1,1,2-Trichloroethane 79-00-5 8260B 0.50 U 1ug/L0.400.50 Trichloroethene 79-01-6 8260B 0.50 U 1ug/L0.400.50 Trichlorofluoromethane 75-69-4 8260B 0.50 U 1ug/L0.400.50 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 16 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-4d SD28010-005 04/27/2017 1215 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1449 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,2,3-Trichloropropane 96-18-4 8260B 0.50 U 1ug/L0.400.50 Vinyl acetate 108-05-4 8260B 5.0 U 1ug/L1.25.0 Vinyl chloride 75-01-4 8260B 0.50 U 1ug/L0.400.50 Xylenes (total)1330-20-7 8260B 1.0 U 1ug/L0.401.0 AcceptanceRun 1 Surrogate Q % Recovery Limits Bromofluorobenzene 105 70-130 1,2-Dichloroethane-d4 109 70-130 Toluene-d8 105 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 17 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-4d SD28010-005 04/27/2017 1215 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/04/2017 1100 BNW 04/28/2017 1749 40786 2 3005A 6020B 1 05/05/2017 2107 MJI 04/28/2017 1749 40786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Antimony 7440-36-0 6020B 6.0 U 1ug/L0.506.0 Arsenic 7440-38-2 6020B 3.5 J 1ug/L1.310 Barium 7440-39-3 6020B 940 1ug/L0.63100 Beryllium 7440-41-7 6020B 1.0 U 1ug/L0.131.0 Cadmium 7440-43-9 6020B 1.0 U 2ug/L0.131.0 Chromium 7440-47-3 6020B 10 U 1ug/L1.310 Cobalt 7440-48-4 6020B 17 1ug/L0.6310 Copper 7440-50-8 6020B 17 1ug/L0.6310 Lead 7439-92-1 6020B 1.4 J 1ug/L0.2510 Nickel 7440-02-0 6020B 9.7 J 1ug/L1.350 Selenium 7782-49-2 6020B 3.9 J 1ug/L1.310 Silver 7440-22-4 6020B 10 U 1ug/L0.2510 Thallium 7440-28-0 6020B 5.5 U 1ug/L0.135.5 Vanadium 7440-62-2 6020B 6.9 J 1ug/L1.525 Zinc 7440-66-6 6020B 28 1ug/L2.510 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 18 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-6 SD28010-006 04/27/2017 1305 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1510 ALL 40863 2 5030B 8260B 1 05/02/2017 0516 ECP 40923 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B 10 U 1ug/L2.010 Acrylonitrile 107-13-1 8260B 5.0 U 1ug/L0.805.0 Benzene 71-43-2 8260B 4.3 1ug/L0.400.50 Bromochloromethane 74-97-5 8260B 0.50 U 1ug/L0.400.50 Bromodichloromethane 75-27-4 8260B 0.50 U 1ug/L0.400.50 Bromoform 75-25-2 8260B 0.50 U 1ug/L0.400.50 Bromomethane (Methyl bromide)74-83-9 8260B 0.50 U 1ug/L0.400.50 2-Butanone (MEK)78-93-3 8260B 10 U 1ug/L2.010 Carbon disulfide 75-15-0 8260B 0.50 U 1ug/L0.400.50 Carbon tetrachloride 56-23-5 8260B 0.50 U 1ug/L0.400.50 Chlorobenzene 108-90-7 8260B 9.7 1ug/L0.400.50 Chloroethane 75-00-3 8260B 0.50 U 1ug/L0.400.50 Chloroform 67-66-3 8260B 0.50 U 1ug/L0.400.50 Chloromethane (Methyl chloride)74-87-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B 0.50 U 1ug/L0.400.50 Dibromochloromethane 124-48-1 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromoethane (EDB)106-93-4 8260B 0.50 U 1ug/L0.400.50 Dibromomethane (Methylene bromide)74-95-3 8260B 0.50 U 1ug/L0.400.50 trans-1,4-Dichloro-2-butene 110-57-6 8260B 2.0 U 1ug/L0.402.0 1,2-Dichlorobenzene 95-50-1 8260B 0.50 U 1ug/L0.400.50 1,4-Dichlorobenzene 106-46-7 8260B 2.8 1ug/L0.400.50 Dichlorodifluoromethane 75-71-8 8260B 1.2 2ug/L0.400.50 1,1-Dichloroethane 75-34-3 8260B 4.4 1ug/L0.400.50 1,2-Dichloroethane 107-06-2 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethene 75-35-4 8260B 0.50 U 1ug/L0.400.50 cis-1,2-Dichloroethene 156-59-2 8260B 1.7 1ug/L0.400.50 trans-1,2-Dichloroethene 156-60-5 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloropropane 78-87-5 8260B 0.50 U 1ug/L0.400.50 cis-1,3-Dichloropropene 10061-01-5 8260B 0.50 U 1ug/L0.400.50 trans-1,3-Dichloropropene 10061-02-6 8260B 0.50 U 1ug/L0.400.50 Ethylbenzene 100-41-4 8260B 0.50 U 1ug/L0.400.50 2-Hexanone 591-78-6 8260B 10 U 1ug/L2.010 Methyl iodide (Iodomethane)74-88-4 8260B 5.0 U 1ug/L0.405.0 4-Methyl-2-pentanone 108-10-1 8260B 10 U 1ug/L2.010 Methylene chloride 75-09-2 8260B 0.56 1ug/L0.400.50 Styrene 100-42-5 8260B 0.50 U 1ug/L0.400.50 1,1,1,2-Tetrachloroethane 630-20-6 8260B 0.50 U 1ug/L0.400.50 1,1,2,2-Tetrachloroethane 79-34-5 8260B 0.50 U 1ug/L0.400.50 Tetrachloroethene 127-18-4 8260B 0.50 U 1ug/L0.400.50 Toluene 108-88-3 8260B 0.50 U 1ug/L0.400.50 1,1,1-Trichloroethane 71-55-6 8260B 0.50 U 1ug/L0.400.50 1,1,2-Trichloroethane 79-00-5 8260B 0.50 U 1ug/L0.400.50 Trichloroethene 79-01-6 8260B 0.50 U 1ug/L0.400.50 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 19 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-6 SD28010-006 04/27/2017 1305 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1510 ALL 40863 2 5030B 8260B 1 05/02/2017 0516 ECP 40923 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Trichlorofluoromethane 75-69-4 8260B 0.50 U 1ug/L0.400.50 1,2,3-Trichloropropane 96-18-4 8260B 0.50 U 1ug/L0.400.50 Vinyl acetate 108-05-4 8260B 5.0 U 1ug/L1.25.0 Vinyl chloride 75-01-4 8260B 0.50 U 1ug/L0.400.50 Xylenes (total)1330-20-7 8260B 1.0 U 1ug/L0.401.0 AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ Bromofluorobenzene 103 70-130 102 70-130 1,2-Dichloroethane-d4 108 70-130 110 70-130 Toluene-d8 102 70-130 103 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 20 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-6 SD28010-006 04/27/2017 1305 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/04/2017 1105 BNW 04/28/2017 1749 40786 2 3005A 6020B 1 05/05/2017 2113 MJI 04/28/2017 1749 40786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Antimony 7440-36-0 6020B 6.0 U 1ug/L0.506.0 Arsenic 7440-38-2 6020B 10 U 1ug/L1.310 Barium 7440-39-3 6020B 370 1ug/L0.63100 Beryllium 7440-41-7 6020B 0.13 J 1ug/L0.131.0 Cadmium 7440-43-9 6020B 1.0 U 2ug/L0.131.0 Chromium 7440-47-3 6020B 10 U 1ug/L1.310 Cobalt 7440-48-4 6020B 1.1 J 1ug/L0.6310 Copper 7440-50-8 6020B 24 1ug/L0.6310 Lead 7439-92-1 6020B 0.42 J 1ug/L0.2510 Nickel 7440-02-0 6020B 5.7 J 1ug/L1.350 Selenium 7782-49-2 6020B 2.2 J 1ug/L1.310 Silver 7440-22-4 6020B 10 U 1ug/L0.2510 Thallium 7440-28-0 6020B 5.5 U 1ug/L0.135.5 Vanadium 7440-62-2 6020B 4.4 J 1ug/L1.525 Zinc 7440-66-6 6020B 12 1ug/L2.510 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 21 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-7 SD28010-007 04/27/2017 1245 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1532 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B 10 U 1ug/L2.010 Acrylonitrile 107-13-1 8260B 5.0 U 1ug/L0.805.0 Benzene 71-43-2 8260B 0.50 U 1ug/L0.400.50 Bromochloromethane 74-97-5 8260B 0.50 U 1ug/L0.400.50 Bromodichloromethane 75-27-4 8260B 0.50 U 1ug/L0.400.50 Bromoform 75-25-2 8260B 0.50 U 1ug/L0.400.50 Bromomethane (Methyl bromide)74-83-9 8260B 0.50 U 1ug/L0.400.50 2-Butanone (MEK)78-93-3 8260B 10 U 1ug/L2.010 Carbon disulfide 75-15-0 8260B 0.50 U 1ug/L0.400.50 Carbon tetrachloride 56-23-5 8260B 0.50 U 1ug/L0.400.50 Chlorobenzene 108-90-7 8260B 0.50 U 1ug/L0.400.50 Chloroethane 75-00-3 8260B 0.50 U 1ug/L0.400.50 Chloroform 67-66-3 8260B 0.50 U 1ug/L0.400.50 Chloromethane (Methyl chloride)74-87-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B 0.50 U 1ug/L0.400.50 Dibromochloromethane 124-48-1 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromoethane (EDB)106-93-4 8260B 0.50 U 1ug/L0.400.50 Dibromomethane (Methylene bromide)74-95-3 8260B 0.50 U 1ug/L0.400.50 trans-1,4-Dichloro-2-butene 110-57-6 8260B 2.0 U 1ug/L0.402.0 1,2-Dichlorobenzene 95-50-1 8260B 0.50 U 1ug/L0.400.50 1,4-Dichlorobenzene 106-46-7 8260B 0.50 U 1ug/L0.400.50 Dichlorodifluoromethane 75-71-8 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethane 75-34-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloroethane 107-06-2 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethene 75-35-4 8260B 0.50 U 1ug/L0.400.50 cis-1,2-Dichloroethene 156-59-2 8260B 0.50 U 1ug/L0.400.50 trans-1,2-Dichloroethene 156-60-5 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloropropane 78-87-5 8260B 0.50 U 1ug/L0.400.50 cis-1,3-Dichloropropene 10061-01-5 8260B 0.50 U 1ug/L0.400.50 trans-1,3-Dichloropropene 10061-02-6 8260B 0.50 U 1ug/L0.400.50 Ethylbenzene 100-41-4 8260B 0.50 U 1ug/L0.400.50 2-Hexanone 591-78-6 8260B 10 U 1ug/L2.010 Methyl iodide (Iodomethane)74-88-4 8260B 5.0 U 1ug/L0.405.0 4-Methyl-2-pentanone 108-10-1 8260B 10 U 1ug/L2.010 Methylene chloride 75-09-2 8260B 0.50 U 1ug/L0.400.50 Styrene 100-42-5 8260B 0.50 U 1ug/L0.400.50 1,1,1,2-Tetrachloroethane 630-20-6 8260B 0.50 U 1ug/L0.400.50 1,1,2,2-Tetrachloroethane 79-34-5 8260B 0.50 U 1ug/L0.400.50 Tetrachloroethene 127-18-4 8260B 0.50 U 1ug/L0.400.50 Toluene 108-88-3 8260B 0.50 U 1ug/L0.400.50 1,1,1-Trichloroethane 71-55-6 8260B 0.50 U 1ug/L0.400.50 1,1,2-Trichloroethane 79-00-5 8260B 0.50 U 1ug/L0.400.50 Trichloroethene 79-01-6 8260B 0.50 U 1ug/L0.400.50 Trichlorofluoromethane 75-69-4 8260B 0.50 U 1ug/L0.400.50 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 22 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-7 SD28010-007 04/27/2017 1245 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1532 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,2,3-Trichloropropane 96-18-4 8260B 0.50 U 1ug/L0.400.50 Vinyl acetate 108-05-4 8260B 5.0 U 1ug/L1.25.0 Vinyl chloride 75-01-4 8260B 0.50 U 1ug/L0.400.50 Xylenes (total)1330-20-7 8260B 1.0 U 1ug/L0.401.0 AcceptanceRun 1 Surrogate Q % Recovery Limits Bromofluorobenzene 106 70-130 1,2-Dichloroethane-d4 111 70-130 Toluene-d8 103 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 23 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-7 SD28010-007 04/27/2017 1245 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/04/2017 1110 BNW 04/28/2017 1749 40786 2 3005A 6020B 1 05/05/2017 2118 MJI 04/28/2017 1749 40786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Antimony 7440-36-0 6020B 6.0 U 1ug/L0.506.0 Arsenic 7440-38-2 6020B 10 U 1ug/L1.310 Barium 7440-39-3 6020B 93 J 1ug/L0.63100 Beryllium 7440-41-7 6020B 1.1 1ug/L0.131.0 Cadmium 7440-43-9 6020B 1.0 U 2ug/L0.131.0 Chromium 7440-47-3 6020B 10 U 1ug/L1.310 Cobalt 7440-48-4 6020B 2.2 J 1ug/L0.6310 Copper 7440-50-8 6020B 2.3 J 1ug/L0.6310 Lead 7439-92-1 6020B 1.3 J 1ug/L0.2510 Nickel 7440-02-0 6020B 50 U 1ug/L1.350 Selenium 7782-49-2 6020B 10 U 1ug/L1.310 Silver 7440-22-4 6020B 10 U 1ug/L0.2510 Thallium 7440-28-0 6020B 5.5 U 1ug/L0.135.5 Vanadium 7440-62-2 6020B 5.4 J 1ug/L1.525 Zinc 7440-66-6 6020B 11 1ug/L2.510 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 24 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-8 SD28010-008 04/27/2017 1330 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1553 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B 5.7 J 1ug/L2.010 Acrylonitrile 107-13-1 8260B 5.0 U 1ug/L0.805.0 Benzene 71-43-2 8260B 1.6 1ug/L0.400.50 Bromochloromethane 74-97-5 8260B 0.50 U 1ug/L0.400.50 Bromodichloromethane 75-27-4 8260B 0.50 U 1ug/L0.400.50 Bromoform 75-25-2 8260B 0.50 U 1ug/L0.400.50 Bromomethane (Methyl bromide)74-83-9 8260B 0.50 U 1ug/L0.400.50 2-Butanone (MEK)78-93-3 8260B 10 U 1ug/L2.010 Carbon disulfide 75-15-0 8260B 0.50 U 1ug/L0.400.50 Carbon tetrachloride 56-23-5 8260B 0.50 U 1ug/L0.400.50 Chlorobenzene 108-90-7 8260B 6.8 1ug/L0.400.50 Chloroethane 75-00-3 8260B 8.3 1ug/L0.400.50 Chloroform 67-66-3 8260B 0.50 U 1ug/L0.400.50 Chloromethane (Methyl chloride)74-87-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B 0.50 U 1ug/L0.400.50 Dibromochloromethane 124-48-1 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromoethane (EDB)106-93-4 8260B 0.50 U 1ug/L0.400.50 Dibromomethane (Methylene bromide)74-95-3 8260B 0.50 U 1ug/L0.400.50 trans-1,4-Dichloro-2-butene 110-57-6 8260B 2.0 U 1ug/L0.402.0 1,2-Dichlorobenzene 95-50-1 8260B 0.50 U 1ug/L0.400.50 1,4-Dichlorobenzene 106-46-7 8260B 3.2 1ug/L0.400.50 Dichlorodifluoromethane 75-71-8 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethane 75-34-3 8260B 1.0 1ug/L0.400.50 1,2-Dichloroethane 107-06-2 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethene 75-35-4 8260B 0.50 U 1ug/L0.400.50 cis-1,2-Dichloroethene 156-59-2 8260B 0.50 U 1ug/L0.400.50 trans-1,2-Dichloroethene 156-60-5 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloropropane 78-87-5 8260B 0.50 U 1ug/L0.400.50 cis-1,3-Dichloropropene 10061-01-5 8260B 0.50 U 1ug/L0.400.50 trans-1,3-Dichloropropene 10061-02-6 8260B 0.50 U 1ug/L0.400.50 Ethylbenzene 100-41-4 8260B 0.50 U 1ug/L0.400.50 2-Hexanone 591-78-6 8260B 10 U 1ug/L2.010 Methyl iodide (Iodomethane)74-88-4 8260B 5.0 U 1ug/L0.405.0 4-Methyl-2-pentanone 108-10-1 8260B 10 U 1ug/L2.010 Methylene chloride 75-09-2 8260B 0.50 U 1ug/L0.400.50 Styrene 100-42-5 8260B 0.50 U 1ug/L0.400.50 1,1,1,2-Tetrachloroethane 630-20-6 8260B 0.50 U 1ug/L0.400.50 1,1,2,2-Tetrachloroethane 79-34-5 8260B 0.50 U 1ug/L0.400.50 Tetrachloroethene 127-18-4 8260B 0.50 U 1ug/L0.400.50 Toluene 108-88-3 8260B 0.50 U 1ug/L0.400.50 1,1,1-Trichloroethane 71-55-6 8260B 0.50 U 1ug/L0.400.50 1,1,2-Trichloroethane 79-00-5 8260B 0.50 U 1ug/L0.400.50 Trichloroethene 79-01-6 8260B 0.50 U 1ug/L0.400.50 Trichlorofluoromethane 75-69-4 8260B 0.50 U 1ug/L0.400.50 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 25 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-8 SD28010-008 04/27/2017 1330 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1553 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,2,3-Trichloropropane 96-18-4 8260B 0.50 U 1ug/L0.400.50 Vinyl acetate 108-05-4 8260B 5.0 U 1ug/L1.25.0 Vinyl chloride 75-01-4 8260B 0.50 U 1ug/L0.400.50 Xylenes (total)1330-20-7 8260B 1.0 U 1ug/L0.401.0 AcceptanceRun 1 Surrogate Q % Recovery Limits Bromofluorobenzene 104 70-130 1,2-Dichloroethane-d4 110 70-130 Toluene-d8 105 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 26 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-8 SD28010-008 04/27/2017 1330 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/04/2017 1116 BNW 04/28/2017 1749 40786 2 3005A 6020B 1 05/05/2017 2123 MJI 04/28/2017 1749 40786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Antimony 7440-36-0 6020B 6.0 U 1ug/L0.506.0 Arsenic 7440-38-2 6020B 1.3 J 1ug/L1.310 Barium 7440-39-3 6020B 210 1ug/L0.63100 Beryllium 7440-41-7 6020B 1.0 U 1ug/L0.131.0 Cadmium 7440-43-9 6020B 1.0 U 2ug/L0.131.0 Chromium 7440-47-3 6020B 10 U 1ug/L1.310 Cobalt 7440-48-4 6020B 10 U 1ug/L0.6310 Copper 7440-50-8 6020B 0.76 J 1ug/L0.6310 Lead 7439-92-1 6020B 0.42 J 1ug/L0.2510 Nickel 7440-02-0 6020B 50 U 1ug/L1.350 Selenium 7782-49-2 6020B 10 U 1ug/L1.310 Silver 7440-22-4 6020B 10 U 1ug/L0.2510 Thallium 7440-28-0 6020B 5.5 U 1ug/L0.135.5 Vanadium 7440-62-2 6020B 2.7 J 1ug/L1.525 Zinc 7440-66-6 6020B 9.4 J 1ug/L2.510 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 27 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-9 SD28010-009 04/27/2017 1345 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1615 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B 8.4 J 1ug/L2.010 Acrylonitrile 107-13-1 8260B 5.0 U 1ug/L0.805.0 Benzene 71-43-2 8260B 2.3 1ug/L0.400.50 Bromochloromethane 74-97-5 8260B 0.50 U 1ug/L0.400.50 Bromodichloromethane 75-27-4 8260B 0.50 U 1ug/L0.400.50 Bromoform 75-25-2 8260B 0.50 U 1ug/L0.400.50 Bromomethane (Methyl bromide)74-83-9 8260B 0.50 U 1ug/L0.400.50 2-Butanone (MEK)78-93-3 8260B 10 U 1ug/L2.010 Carbon disulfide 75-15-0 8260B 0.50 U 1ug/L0.400.50 Carbon tetrachloride 56-23-5 8260B 0.50 U 1ug/L0.400.50 Chlorobenzene 108-90-7 8260B 8.3 1ug/L0.400.50 Chloroethane 75-00-3 8260B 0.50 U 1ug/L0.400.50 Chloroform 67-66-3 8260B 0.50 U 1ug/L0.400.50 Chloromethane (Methyl chloride)74-87-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B 0.50 U 1ug/L0.400.50 Dibromochloromethane 124-48-1 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromoethane (EDB)106-93-4 8260B 0.50 U 1ug/L0.400.50 Dibromomethane (Methylene bromide)74-95-3 8260B 0.50 U 1ug/L0.400.50 trans-1,4-Dichloro-2-butene 110-57-6 8260B 2.0 U 1ug/L0.402.0 1,2-Dichlorobenzene 95-50-1 8260B 0.50 U 1ug/L0.400.50 1,4-Dichlorobenzene 106-46-7 8260B 8.9 1ug/L0.400.50 Dichlorodifluoromethane 75-71-8 8260B 0.42 J 1ug/L0.400.50 1,1-Dichloroethane 75-34-3 8260B 0.70 1ug/L0.400.50 1,2-Dichloroethane 107-06-2 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethene 75-35-4 8260B 0.50 U 1ug/L0.400.50 cis-1,2-Dichloroethene 156-59-2 8260B 0.50 U 1ug/L0.400.50 trans-1,2-Dichloroethene 156-60-5 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloropropane 78-87-5 8260B 0.50 U 1ug/L0.400.50 cis-1,3-Dichloropropene 10061-01-5 8260B 0.50 U 1ug/L0.400.50 trans-1,3-Dichloropropene 10061-02-6 8260B 0.50 U 1ug/L0.400.50 Ethylbenzene 100-41-4 8260B 0.50 U 1ug/L0.400.50 2-Hexanone 591-78-6 8260B 10 U 1ug/L2.010 Methyl iodide (Iodomethane)74-88-4 8260B 5.0 U 1ug/L0.405.0 4-Methyl-2-pentanone 108-10-1 8260B 10 U 1ug/L2.010 Methylene chloride 75-09-2 8260B 0.50 U 1ug/L0.400.50 Styrene 100-42-5 8260B 0.50 U 1ug/L0.400.50 1,1,1,2-Tetrachloroethane 630-20-6 8260B 0.50 U 1ug/L0.400.50 1,1,2,2-Tetrachloroethane 79-34-5 8260B 0.50 U 1ug/L0.400.50 Tetrachloroethene 127-18-4 8260B 0.50 U 1ug/L0.400.50 Toluene 108-88-3 8260B 0.50 U 1ug/L0.400.50 1,1,1-Trichloroethane 71-55-6 8260B 0.50 U 1ug/L0.400.50 1,1,2-Trichloroethane 79-00-5 8260B 0.50 U 1ug/L0.400.50 Trichloroethene 79-01-6 8260B 0.50 U 1ug/L0.400.50 Trichlorofluoromethane 75-69-4 8260B 0.50 U 1ug/L0.400.50 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 28 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-9 SD28010-009 04/27/2017 1345 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1615 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,2,3-Trichloropropane 96-18-4 8260B 0.50 U 1ug/L0.400.50 Vinyl acetate 108-05-4 8260B 5.0 U 1ug/L1.25.0 Vinyl chloride 75-01-4 8260B 0.72 1ug/L0.400.50 Xylenes (total)1330-20-7 8260B 1.0 U 1ug/L0.401.0 AcceptanceRun 1 Surrogate Q % Recovery Limits Bromofluorobenzene 107 70-130 1,2-Dichloroethane-d4 110 70-130 Toluene-d8 104 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 29 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-9 SD28010-009 04/27/2017 1345 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/04/2017 1121 BNW 04/28/2017 1749 40786 2 3005A 6020B 1 05/05/2017 2129 MJI 04/28/2017 1749 40786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Antimony 7440-36-0 6020B 6.0 U 1ug/L0.506.0 Arsenic 7440-38-2 6020B 1.7 J 1ug/L1.310 Barium 7440-39-3 6020B 210 1ug/L0.63100 Beryllium 7440-41-7 6020B 1.0 U 1ug/L0.131.0 Cadmium 7440-43-9 6020B 1.0 U 2ug/L0.131.0 Chromium 7440-47-3 6020B 10 U 1ug/L1.310 Cobalt 7440-48-4 6020B 50 1ug/L0.6310 Copper 7440-50-8 6020B 0.90 J 1ug/L0.6310 Lead 7439-92-1 6020B 0.48 J 1ug/L0.2510 Nickel 7440-02-0 6020B 50 U 1ug/L1.350 Selenium 7782-49-2 6020B 10 U 1ug/L1.310 Silver 7440-22-4 6020B 10 U 1ug/L0.2510 Thallium 7440-28-0 6020B 0.27 J 1ug/L0.135.5 Vanadium 7440-62-2 6020B 25 U 1ug/L1.525 Zinc 7440-66-6 6020B 6.7 J 1ug/L2.510 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 30 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-10 SD28010-010 04/27/2017 1030 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1636 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B 4.9 J 1ug/L2.010 Acrylonitrile 107-13-1 8260B 5.0 U 1ug/L0.805.0 Benzene 71-43-2 8260B 1.7 1ug/L0.400.50 Bromochloromethane 74-97-5 8260B 0.50 U 1ug/L0.400.50 Bromodichloromethane 75-27-4 8260B 0.50 U 1ug/L0.400.50 Bromoform 75-25-2 8260B 0.50 U 1ug/L0.400.50 Bromomethane (Methyl bromide)74-83-9 8260B 0.50 U 1ug/L0.400.50 2-Butanone (MEK)78-93-3 8260B 10 U 1ug/L2.010 Carbon disulfide 75-15-0 8260B 0.50 U 1ug/L0.400.50 Carbon tetrachloride 56-23-5 8260B 0.50 U 1ug/L0.400.50 Chlorobenzene 108-90-7 8260B 19 1ug/L0.400.50 Chloroethane 75-00-3 8260B 0.50 U 1ug/L0.400.50 Chloroform 67-66-3 8260B 0.50 U 1ug/L0.400.50 Chloromethane (Methyl chloride)74-87-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B 0.50 U 1ug/L0.400.50 Dibromochloromethane 124-48-1 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromoethane (EDB)106-93-4 8260B 0.50 U 1ug/L0.400.50 Dibromomethane (Methylene bromide)74-95-3 8260B 0.50 U 1ug/L0.400.50 trans-1,4-Dichloro-2-butene 110-57-6 8260B 2.0 U 1ug/L0.402.0 1,2-Dichlorobenzene 95-50-1 8260B 0.67 1ug/L0.400.50 1,4-Dichlorobenzene 106-46-7 8260B 4.2 1ug/L0.400.50 Dichlorodifluoromethane 75-71-8 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethane 75-34-3 8260B 0.55 1ug/L0.400.50 1,2-Dichloroethane 107-06-2 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethene 75-35-4 8260B 0.50 U 1ug/L0.400.50 cis-1,2-Dichloroethene 156-59-2 8260B 0.50 U 1ug/L0.400.50 trans-1,2-Dichloroethene 156-60-5 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloropropane 78-87-5 8260B 0.50 U 1ug/L0.400.50 cis-1,3-Dichloropropene 10061-01-5 8260B 0.50 U 1ug/L0.400.50 trans-1,3-Dichloropropene 10061-02-6 8260B 0.50 U 1ug/L0.400.50 Ethylbenzene 100-41-4 8260B 0.50 U 1ug/L0.400.50 2-Hexanone 591-78-6 8260B 10 U 1ug/L2.010 Methyl iodide (Iodomethane)74-88-4 8260B 5.0 U 1ug/L0.405.0 4-Methyl-2-pentanone 108-10-1 8260B 10 U 1ug/L2.010 Methylene chloride 75-09-2 8260B 0.50 U 1ug/L0.400.50 Styrene 100-42-5 8260B 0.50 U 1ug/L0.400.50 1,1,1,2-Tetrachloroethane 630-20-6 8260B 0.50 U 1ug/L0.400.50 1,1,2,2-Tetrachloroethane 79-34-5 8260B 0.50 U 1ug/L0.400.50 Tetrachloroethene 127-18-4 8260B 0.50 U 1ug/L0.400.50 Toluene 108-88-3 8260B 0.50 U 1ug/L0.400.50 1,1,1-Trichloroethane 71-55-6 8260B 0.50 U 1ug/L0.400.50 1,1,2-Trichloroethane 79-00-5 8260B 0.50 U 1ug/L0.400.50 Trichloroethene 79-01-6 8260B 0.50 U 1ug/L0.400.50 Trichlorofluoromethane 75-69-4 8260B 0.50 U 1ug/L0.400.50 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 31 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-10 SD28010-010 04/27/2017 1030 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1636 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,2,3-Trichloropropane 96-18-4 8260B 0.50 U 1ug/L0.400.50 Vinyl acetate 108-05-4 8260B 5.0 U 1ug/L1.25.0 Vinyl chloride 75-01-4 8260B 0.50 U 1ug/L0.400.50 Xylenes (total)1330-20-7 8260B 1.0 U 1ug/L0.401.0 AcceptanceRun 1 Surrogate Q % Recovery Limits Bromofluorobenzene 108 70-130 1,2-Dichloroethane-d4 109 70-130 Toluene-d8 105 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 32 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith MW-10 SD28010-010 04/27/2017 1030 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/04/2017 1137 BNW 04/28/2017 1749 40786 2 3005A 6020B 1 05/05/2017 2134 MJI 04/28/2017 1749 40786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Antimony 7440-36-0 6020B 6.0 U 1ug/L0.506.0 Arsenic 7440-38-2 6020B 10 U 1ug/L1.310 Barium 7440-39-3 6020B 300 1ug/L0.63100 Beryllium 7440-41-7 6020B 0.32 J 1ug/L0.131.0 Cadmium 7440-43-9 6020B 1.0 U 2ug/L0.131.0 Chromium 7440-47-3 6020B 10 U 1ug/L1.310 Cobalt 7440-48-4 6020B 8.1 J 1ug/L0.6310 Copper 7440-50-8 6020B 1.9 J 1ug/L0.6310 Lead 7439-92-1 6020B 0.32 J 1ug/L0.2510 Nickel 7440-02-0 6020B 50 U 1ug/L1.350 Selenium 7782-49-2 6020B 10 U 1ug/L1.310 Silver 7440-22-4 6020B 10 U 1ug/L0.2510 Thallium 7440-28-0 6020B 5.5 U 1ug/L0.135.5 Vanadium 7440-62-2 6020B 2.6 J 1ug/L1.525 Zinc 7440-66-6 6020B 3.4 J 1ug/L2.510 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 33 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith DUP SD28010-011 04/27/2017 1000 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1658 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B 4.4 J 1ug/L2.010 Acrylonitrile 107-13-1 8260B 5.0 U 1ug/L0.805.0 Benzene 71-43-2 8260B 1.7 1ug/L0.400.50 Bromochloromethane 74-97-5 8260B 0.50 U 1ug/L0.400.50 Bromodichloromethane 75-27-4 8260B 0.50 U 1ug/L0.400.50 Bromoform 75-25-2 8260B 0.50 U 1ug/L0.400.50 Bromomethane (Methyl bromide)74-83-9 8260B 0.50 U 1ug/L0.400.50 2-Butanone (MEK)78-93-3 8260B 10 U 1ug/L2.010 Carbon disulfide 75-15-0 8260B 0.50 U 1ug/L0.400.50 Carbon tetrachloride 56-23-5 8260B 0.50 U 1ug/L0.400.50 Chlorobenzene 108-90-7 8260B 19 1ug/L0.400.50 Chloroethane 75-00-3 8260B 0.50 U 1ug/L0.400.50 Chloroform 67-66-3 8260B 0.50 U 1ug/L0.400.50 Chloromethane (Methyl chloride)74-87-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B 0.50 U 1ug/L0.400.50 Dibromochloromethane 124-48-1 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromoethane (EDB)106-93-4 8260B 0.50 U 1ug/L0.400.50 Dibromomethane (Methylene bromide)74-95-3 8260B 0.50 U 1ug/L0.400.50 trans-1,4-Dichloro-2-butene 110-57-6 8260B 2.0 U 1ug/L0.402.0 1,2-Dichlorobenzene 95-50-1 8260B 0.67 1ug/L0.400.50 1,4-Dichlorobenzene 106-46-7 8260B 4.3 1ug/L0.400.50 Dichlorodifluoromethane 75-71-8 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethane 75-34-3 8260B 0.56 1ug/L0.400.50 1,2-Dichloroethane 107-06-2 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethene 75-35-4 8260B 0.50 U 1ug/L0.400.50 cis-1,2-Dichloroethene 156-59-2 8260B 0.50 U 1ug/L0.400.50 trans-1,2-Dichloroethene 156-60-5 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloropropane 78-87-5 8260B 0.50 U 1ug/L0.400.50 cis-1,3-Dichloropropene 10061-01-5 8260B 0.50 U 1ug/L0.400.50 trans-1,3-Dichloropropene 10061-02-6 8260B 0.50 U 1ug/L0.400.50 Ethylbenzene 100-41-4 8260B 0.50 U 1ug/L0.400.50 2-Hexanone 591-78-6 8260B 10 U 1ug/L2.010 Methyl iodide (Iodomethane)74-88-4 8260B 5.0 U 1ug/L0.405.0 4-Methyl-2-pentanone 108-10-1 8260B 10 U 1ug/L2.010 Methylene chloride 75-09-2 8260B 0.50 U 1ug/L0.400.50 Styrene 100-42-5 8260B 0.50 U 1ug/L0.400.50 1,1,1,2-Tetrachloroethane 630-20-6 8260B 0.50 U 1ug/L0.400.50 1,1,2,2-Tetrachloroethane 79-34-5 8260B 0.50 U 1ug/L0.400.50 Tetrachloroethene 127-18-4 8260B 0.50 U 1ug/L0.400.50 Toluene 108-88-3 8260B 0.50 U 1ug/L0.400.50 1,1,1-Trichloroethane 71-55-6 8260B 0.50 U 1ug/L0.400.50 1,1,2-Trichloroethane 79-00-5 8260B 0.50 U 1ug/L0.400.50 Trichloroethene 79-01-6 8260B 0.50 U 1ug/L0.400.50 Trichlorofluoromethane 75-69-4 8260B 0.50 U 1ug/L0.400.50 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 34 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith DUP SD28010-011 04/27/2017 1000 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1658 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,2,3-Trichloropropane 96-18-4 8260B 0.50 U 1ug/L0.400.50 Vinyl acetate 108-05-4 8260B 5.0 U 1ug/L1.25.0 Vinyl chloride 75-01-4 8260B 0.50 U 1ug/L0.400.50 Xylenes (total)1330-20-7 8260B 1.0 U 1ug/L0.401.0 AcceptanceRun 1 Surrogate Q % Recovery Limits Bromofluorobenzene 107 70-130 1,2-Dichloroethane-d4 109 70-130 Toluene-d8 105 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 35 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith DUP SD28010-011 04/27/2017 1000 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/04/2017 1143 BNW 04/28/2017 1749 40786 2 3005A 6020B 1 05/05/2017 2139 MJI 04/28/2017 1749 40786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Antimony 7440-36-0 6020B 6.0 U 1ug/L0.506.0 Arsenic 7440-38-2 6020B 10 U 1ug/L1.310 Barium 7440-39-3 6020B 320 1ug/L0.63100 Beryllium 7440-41-7 6020B 0.35 J 1ug/L0.131.0 Cadmium 7440-43-9 6020B 1.0 U 2ug/L0.131.0 Chromium 7440-47-3 6020B 10 U 1ug/L1.310 Cobalt 7440-48-4 6020B 8.5 J 1ug/L0.6310 Copper 7440-50-8 6020B 2.3 J 1ug/L0.6310 Lead 7439-92-1 6020B 0.40 J 1ug/L0.2510 Nickel 7440-02-0 6020B 50 U 1ug/L1.350 Selenium 7782-49-2 6020B 10 U 1ug/L1.310 Silver 7440-22-4 6020B 10 U 1ug/L0.2510 Thallium 7440-28-0 6020B 5.5 U 1ug/L0.135.5 Vanadium 7440-62-2 6020B 2.5 J 1ug/L1.525 Zinc 7440-66-6 6020B 3.6 J 1ug/L2.510 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 36 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith EQ BLANK SD28010-012 04/27/2017 1400 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1029 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B 3.3 J 1ug/L2.010 Acrylonitrile 107-13-1 8260B 5.0 U 1ug/L0.805.0 Benzene 71-43-2 8260B 0.50 U 1ug/L0.400.50 Bromochloromethane 74-97-5 8260B 0.50 U 1ug/L0.400.50 Bromodichloromethane 75-27-4 8260B 0.50 U 1ug/L0.400.50 Bromoform 75-25-2 8260B 0.50 U 1ug/L0.400.50 Bromomethane (Methyl bromide)74-83-9 8260B 0.50 U 1ug/L0.400.50 2-Butanone (MEK)78-93-3 8260B 9.6 J 1ug/L2.010 Carbon disulfide 75-15-0 8260B 0.50 U 1ug/L0.400.50 Carbon tetrachloride 56-23-5 8260B 0.50 U 1ug/L0.400.50 Chlorobenzene 108-90-7 8260B 0.50 U 1ug/L0.400.50 Chloroethane 75-00-3 8260B 0.50 U 1ug/L0.400.50 Chloroform 67-66-3 8260B 0.50 U 1ug/L0.400.50 Chloromethane (Methyl chloride)74-87-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B 0.50 U 1ug/L0.400.50 Dibromochloromethane 124-48-1 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromoethane (EDB)106-93-4 8260B 0.50 U 1ug/L0.400.50 Dibromomethane (Methylene bromide)74-95-3 8260B 0.50 U 1ug/L0.400.50 trans-1,4-Dichloro-2-butene 110-57-6 8260B 2.0 U 1ug/L0.402.0 1,2-Dichlorobenzene 95-50-1 8260B 0.50 U 1ug/L0.400.50 1,4-Dichlorobenzene 106-46-7 8260B 0.50 U 1ug/L0.400.50 Dichlorodifluoromethane 75-71-8 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethane 75-34-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloroethane 107-06-2 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethene 75-35-4 8260B 0.50 U 1ug/L0.400.50 cis-1,2-Dichloroethene 156-59-2 8260B 0.50 U 1ug/L0.400.50 trans-1,2-Dichloroethene 156-60-5 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloropropane 78-87-5 8260B 0.50 U 1ug/L0.400.50 cis-1,3-Dichloropropene 10061-01-5 8260B 0.50 U 1ug/L0.400.50 trans-1,3-Dichloropropene 10061-02-6 8260B 0.50 U 1ug/L0.400.50 Ethylbenzene 100-41-4 8260B 0.50 U 1ug/L0.400.50 2-Hexanone 591-78-6 8260B 10 U 1ug/L2.010 Methyl iodide (Iodomethane)74-88-4 8260B 5.0 U 1ug/L0.405.0 4-Methyl-2-pentanone 108-10-1 8260B 10 U 1ug/L2.010 Methylene chloride 75-09-2 8260B 0.50 U 1ug/L0.400.50 Styrene 100-42-5 8260B 0.50 U 1ug/L0.400.50 1,1,1,2-Tetrachloroethane 630-20-6 8260B 0.50 U 1ug/L0.400.50 1,1,2,2-Tetrachloroethane 79-34-5 8260B 0.50 U 1ug/L0.400.50 Tetrachloroethene 127-18-4 8260B 0.50 U 1ug/L0.400.50 Toluene 108-88-3 8260B 0.50 U 1ug/L0.400.50 1,1,1-Trichloroethane 71-55-6 8260B 0.50 U 1ug/L0.400.50 1,1,2-Trichloroethane 79-00-5 8260B 0.50 U 1ug/L0.400.50 Trichloroethene 79-01-6 8260B 0.50 U 1ug/L0.400.50 Trichlorofluoromethane 75-69-4 8260B 0.50 U 1ug/L0.400.50 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 37 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith EQ BLANK SD28010-012 04/27/2017 1400 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1029 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,2,3-Trichloropropane 96-18-4 8260B 0.50 U 1ug/L0.400.50 Vinyl acetate 108-05-4 8260B 5.0 U 1ug/L1.25.0 Vinyl chloride 75-01-4 8260B 0.50 U 1ug/L0.400.50 Xylenes (total)1330-20-7 8260B 1.0 U 1ug/L0.401.0 AcceptanceRun 1 Surrogate Q % Recovery Limits Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 103 70-130 Toluene-d8 103 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 38 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith EQ BLANK SD28010-012 04/27/2017 1400 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/04/2017 1148 BNW 04/28/2017 1749 40786 2 3005A 6020B 1 05/05/2017 2145 MJI 04/28/2017 1749 40786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Antimony 7440-36-0 6020B 6.0 U 1ug/L0.506.0 Arsenic 7440-38-2 6020B 10 U 1ug/L1.310 Barium 7440-39-3 6020B 100 U 1ug/L0.63100 Beryllium 7440-41-7 6020B 1.0 U 1ug/L0.131.0 Cadmium 7440-43-9 6020B 1.0 U 2ug/L0.131.0 Chromium 7440-47-3 6020B 10 U 1ug/L1.310 Cobalt 7440-48-4 6020B 10 U 1ug/L0.6310 Copper 7440-50-8 6020B 1.8 J 1ug/L0.6310 Lead 7439-92-1 6020B 10 U 1ug/L0.2510 Nickel 7440-02-0 6020B 50 U 1ug/L1.350 Selenium 7782-49-2 6020B 10 U 1ug/L1.310 Silver 7440-22-4 6020B 10 U 1ug/L0.2510 Thallium 7440-28-0 6020B 5.5 U 1ug/L0.135.5 Vanadium 7440-62-2 6020B 25 U 1ug/L1.525 Zinc 7440-66-6 6020B 10 U 1ug/L2.510 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 39 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith TRIP BLANK SD28010-013 04/27/2017 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1050 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B 10 U 1ug/L2.010 Acrylonitrile 107-13-1 8260B 5.0 U 1ug/L0.805.0 Benzene 71-43-2 8260B 0.50 U 1ug/L0.400.50 Bromochloromethane 74-97-5 8260B 0.50 U 1ug/L0.400.50 Bromodichloromethane 75-27-4 8260B 0.50 U 1ug/L0.400.50 Bromoform 75-25-2 8260B 0.50 U 1ug/L0.400.50 Bromomethane (Methyl bromide)74-83-9 8260B 0.50 U 1ug/L0.400.50 2-Butanone (MEK)78-93-3 8260B 10 U 1ug/L2.010 Carbon disulfide 75-15-0 8260B 0.50 U 1ug/L0.400.50 Carbon tetrachloride 56-23-5 8260B 0.50 U 1ug/L0.400.50 Chlorobenzene 108-90-7 8260B 0.50 U 1ug/L0.400.50 Chloroethane 75-00-3 8260B 0.50 U 1ug/L0.400.50 Chloroform 67-66-3 8260B 0.50 U 1ug/L0.400.50 Chloromethane (Methyl chloride)74-87-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B 0.50 U 1ug/L0.400.50 Dibromochloromethane 124-48-1 8260B 0.50 U 1ug/L0.400.50 1,2-Dibromoethane (EDB)106-93-4 8260B 0.50 U 1ug/L0.400.50 Dibromomethane (Methylene bromide)74-95-3 8260B 0.50 U 1ug/L0.400.50 trans-1,4-Dichloro-2-butene 110-57-6 8260B 2.0 U 1ug/L0.402.0 1,2-Dichlorobenzene 95-50-1 8260B 0.50 U 1ug/L0.400.50 1,4-Dichlorobenzene 106-46-7 8260B 0.50 U 1ug/L0.400.50 Dichlorodifluoromethane 75-71-8 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethane 75-34-3 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloroethane 107-06-2 8260B 0.50 U 1ug/L0.400.50 1,1-Dichloroethene 75-35-4 8260B 0.50 U 1ug/L0.400.50 cis-1,2-Dichloroethene 156-59-2 8260B 0.50 U 1ug/L0.400.50 trans-1,2-Dichloroethene 156-60-5 8260B 0.50 U 1ug/L0.400.50 1,2-Dichloropropane 78-87-5 8260B 0.50 U 1ug/L0.400.50 cis-1,3-Dichloropropene 10061-01-5 8260B 0.50 U 1ug/L0.400.50 trans-1,3-Dichloropropene 10061-02-6 8260B 0.50 U 1ug/L0.400.50 Ethylbenzene 100-41-4 8260B 0.50 U 1ug/L0.400.50 2-Hexanone 591-78-6 8260B 10 U 1ug/L2.010 Methyl iodide (Iodomethane)74-88-4 8260B 5.0 U 1ug/L0.405.0 4-Methyl-2-pentanone 108-10-1 8260B 10 U 1ug/L2.010 Methylene chloride 75-09-2 8260B 0.50 U 1ug/L0.400.50 Styrene 100-42-5 8260B 0.50 U 1ug/L0.400.50 1,1,1,2-Tetrachloroethane 630-20-6 8260B 0.50 U 1ug/L0.400.50 1,1,2,2-Tetrachloroethane 79-34-5 8260B 0.50 U 1ug/L0.400.50 Tetrachloroethene 127-18-4 8260B 0.50 U 1ug/L0.400.50 Toluene 108-88-3 8260B 0.50 U 1ug/L0.400.50 1,1,1-Trichloroethane 71-55-6 8260B 0.50 U 1ug/L0.400.50 1,1,2-Trichloroethane 79-00-5 8260B 0.50 U 1ug/L0.400.50 Trichloroethene 79-01-6 8260B 0.50 U 1ug/L0.400.50 Trichlorofluoromethane 75-69-4 8260B 0.50 U 1ug/L0.400.50 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 40 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: CDM Smith TRIP BLANK SD28010-013 04/27/2017 04/28/2017 Aqueous Project Name: East Wake Landfill Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 05/01/2017 1050 ALL 40863 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,2,3-Trichloropropane 96-18-4 8260B 0.50 U 1ug/L0.400.50 Vinyl acetate 108-05-4 8260B 5.0 U 1ug/L1.25.0 Vinyl chloride 75-01-4 8260B 0.50 U 1ug/L0.400.50 Xylenes (total)1330-20-7 8260B 1.0 U 1ug/L0.401.0 AcceptanceRun 1 Surrogate Q % Recovery Limits Bromofluorobenzene 108 70-130 1,2-Dichloroethane-d4 109 70-130 Toluene-d8 107 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time D = Dilution > 1 Page: 41 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. QC Summary Page: 42 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - MB Batch:Prep Method: Sample ID:SQ40863-001 40863 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q PQL MDL Units Analysis DateDil Acetone 10 05/01/2017 0934U102.0 ug/L1 Acrylonitrile 5.0 05/01/2017 0934U5.0 0.80 ug/L1 Benzene 0.50 05/01/2017 0934U0.50 0.40 ug/L1 Bromochloromethane 0.50 05/01/2017 0934U0.50 0.40 ug/L1 Bromodichloromethane 0.50 05/01/2017 0934U0.50 0.40 ug/L1 Bromoform 0.50 05/01/2017 0934U0.50 0.40 ug/L1 Bromomethane (Methyl bromide)0.50 05/01/2017 0934U0.50 0.40 ug/L1 2-Butanone (MEK)10 05/01/2017 0934U102.0 ug/L1 Carbon disulfide 0.50 05/01/2017 0934U0.50 0.40 ug/L1 Carbon tetrachloride 0.50 05/01/2017 0934U0.50 0.40 ug/L1 Chlorobenzene 0.50 05/01/2017 0934U0.50 0.40 ug/L1 Chloroethane 0.50 05/01/2017 0934U0.50 0.40 ug/L1 Chloroform 0.50 05/01/2017 0934U0.50 0.40 ug/L1 Chloromethane (Methyl chloride)0.50 05/01/2017 0934U0.50 0.40 ug/L1 1,2-Dibromo-3-chloropropane (DBCP)0.50 05/01/2017 0934U0.50 0.40 ug/L1 Dibromochloromethane 0.50 05/01/2017 0934U0.50 0.40 ug/L1 1,2-Dibromoethane (EDB)0.50 05/01/2017 0934U0.50 0.40 ug/L1 Dibromomethane (Methylene bromide)0.50 05/01/2017 0934U0.50 0.40 ug/L1 trans-1,4-Dichloro-2-butene 2.0 05/01/2017 0934U2.0 0.40 ug/L1 1,4-Dichlorobenzene 0.50 05/01/2017 0934U0.50 0.40 ug/L1 1,2-Dichlorobenzene 0.50 05/01/2017 0934U0.50 0.40 ug/L1 Dichlorodifluoromethane 0.50 05/01/2017 0934U0.50 0.40 ug/L1 1,2-Dichloroethane 0.50 05/01/2017 0934U0.50 0.40 ug/L1 1,1-Dichloroethane 0.50 05/01/2017 0934U0.50 0.40 ug/L1 trans-1,2-Dichloroethene 0.50 05/01/2017 0934U0.50 0.40 ug/L1 cis-1,2-Dichloroethene 0.50 05/01/2017 0934U0.50 0.40 ug/L1 1,1-Dichloroethene 0.50 05/01/2017 0934U0.50 0.40 ug/L1 1,2-Dichloropropane 0.50 05/01/2017 0934U0.50 0.40 ug/L1 trans-1,3-Dichloropropene 0.50 05/01/2017 0934U0.50 0.40 ug/L1 cis-1,3-Dichloropropene 0.50 05/01/2017 0934U0.50 0.40 ug/L1 Ethylbenzene 0.50 05/01/2017 0934U0.50 0.40 ug/L1 2-Hexanone 10 05/01/2017 0934U102.0 ug/L1 Methyl iodide (Iodomethane)5.0 05/01/2017 0934U5.0 0.40 ug/L1 4-Methyl-2-pentanone 10 05/01/2017 0934U102.0 ug/L1 Methylene chloride 0.50 05/01/2017 0934U0.50 0.40 ug/L1 Styrene 0.50 05/01/2017 0934U0.50 0.40 ug/L1 1,1,2,2-Tetrachloroethane 0.50 05/01/2017 0934U0.50 0.40 ug/L1 1,1,1,2-Tetrachloroethane 0.50 05/01/2017 0934U0.50 0.40 ug/L1 Tetrachloroethene 0.50 05/01/2017 0934U0.50 0.40 ug/L1 Toluene 0.50 05/01/2017 0934U0.50 0.40 ug/L1 1,1,2-Trichloroethane 0.50 05/01/2017 0934U0.50 0.40 ug/L1 1,1,1-Trichloroethane 0.50 05/01/2017 0934U0.50 0.40 ug/L1 Trichloroethene 0.50 05/01/2017 0934U0.50 0.40 ug/L1 Trichlorofluoromethane 0.50 05/01/2017 0934U0.50 0.40 ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 43 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - MB Batch:Prep Method: Sample ID:SQ40863-001 40863 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q PQL MDL Units Analysis DateDil 1,2,3-Trichloropropane 0.50 05/01/2017 0934U0.50 0.40 ug/L1 Vinyl acetate 5.0 05/01/2017 0934U5.0 1.2 ug/L1 Vinyl chloride 0.50 05/01/2017 0934U0.50 0.40 ug/L1 Xylenes (total)1.0 05/01/2017 0934U1.0 0.40 ug/L1 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 103 70-130 1,2-Dichloroethane-d4 108 70-130 Toluene-d8 103 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 44 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - LCS Batch:Prep Method: Sample ID:SQ40863-002 40863 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Acetone 130 05/01/2017 083612710060-1401 Acrylonitrile 110 05/01/2017 083611310060-1401 Benzene 52 05/01/2017 08361045070-1301 Bromochloromethane 55 05/01/2017 08361105070-1301 Bromodichloromethane 54 05/01/2017 08361085070-1301 Bromoform 52 05/01/2017 08361035070-1301 Bromomethane (Methyl bromide)61 05/01/2017 08361235060-1401 2-Butanone (MEK)110 05/01/2017 083611310060-1401 Carbon disulfide 57 05/01/2017 08361145060-1401 Carbon tetrachloride 50 05/01/2017 08361015070-1301 Chlorobenzene 54 05/01/2017 08361075070-1301 Chloroethane 58 05/01/2017 08361155060-1401 Chloroform 58 05/01/2017 08361155070-1301 Chloromethane (Methyl chloride)59 05/01/2017 08361185060-1401 1,2-Dibromo-3-chloropropane (DBCP)48 05/01/2017 0836965070-1301 Dibromochloromethane 54 05/01/2017 08361085070-1301 1,2-Dibromoethane (EDB)51 05/01/2017 08361025070-1301 Dibromomethane (Methylene bromide)52 05/01/2017 08361035070-1301 trans-1,4-Dichloro-2-butene 46 05/01/2017 0836925034-1421 1,4-Dichlorobenzene 53 05/01/2017 08361075070-1301 1,2-Dichlorobenzene 54 05/01/2017 08361095070-1301 Dichlorodifluoromethane 69 05/01/2017 08361385060-1401 1,2-Dichloroethane 54 05/01/2017 08361085070-1301 1,1-Dichloroethane 58 05/01/2017 08361165070-1301 trans-1,2-Dichloroethene 59 05/01/2017 08361185070-1301 cis-1,2-Dichloroethene 57 05/01/2017 08361145070-1301 1,1-Dichloroethene 54 05/01/2017 08361085070-1301 1,2-Dichloropropane 53 05/01/2017 08361055070-1301 trans-1,3-Dichloropropene 53 05/01/2017 08361075070-1301 cis-1,3-Dichloropropene 53 05/01/2017 08361075070-1301 Ethylbenzene 54 05/01/2017 08361085070-1301 2-Hexanone 93 05/01/2017 08369310060-1401 Methyl iodide (Iodomethane)58 05/01/2017 08361165070-1301 4-Methyl-2-pentanone 97 05/01/2017 08369710060-1401 Methylene chloride 55 05/01/2017 08361095070-1301 Styrene 54 05/01/2017 08361075070-1301 1,1,2,2-Tetrachloroethane 52 05/01/2017 08361055070-1301 1,1,1,2-Tetrachloroethane 53 05/01/2017 08361055070-1301 Tetrachloroethene 56 05/01/2017 08361125070-1301 Toluene 57 05/01/2017 08361135070-1301 1,1,2-Trichloroethane 51 05/01/2017 08361015070-1301 1,1,1-Trichloroethane 52 05/01/2017 08361035070-1301 Trichloroethene 51 05/01/2017 08361015070-1301 Trichlorofluoromethane 60 05/01/2017 08361215060-1401 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 45 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - LCS Batch:Prep Method: Sample ID:SQ40863-002 40863 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) 1,2,3-Trichloropropane 53 05/01/2017 08361065070-1301 Vinyl acetate 57 05/01/2017 08361145060-1401 Vinyl chloride 61 05/01/2017 08361235060-1401 Xylenes (total)110 05/01/2017 083610610070-1301 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 102 70-130 1,2-Dichloroethane-d4 102 70-130 Toluene-d8 105 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 46 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - MB Batch:Prep Method: Sample ID:SQ40923-001 40923 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q PQL MDL Units Analysis DateDil Acetone 10 05/01/2017 2142U102.0 ug/L1 Dichlorodifluoromethane 0.50 05/01/2017 2142U0.50 0.40 ug/L1 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 104 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 105 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 47 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - LCS Batch:Prep Method: Sample ID:SQ40923-002 40923 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Acetone 120 05/01/2017 204311610060-1401 Dichlorodifluoromethane 50 05/01/2017 2043995060-1401 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 102 70-130 1,2-Dichloroethane-d4 102 70-130 Toluene-d8 104 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 48 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Metals - MB Batch:Prep Method: Prep Date: Sample ID:SQ40786-001 40786 3005A 04/28/2017 1749Analytical Method:6020B Matrix:Aqueous Parameter Result Q PQL MDL Units Analysis DateDil Antimony 6.0 05/04/2017 0955U6.0 0.50 ug/L1 Arsenic 10 05/04/2017 0955U101.3 ug/L1 Barium 100 05/04/2017 0955U1000.63 ug/L1 Beryllium 1.0 05/04/2017 0955U1.0 0.13 ug/L1 Cadmium 1.0 05/05/2017 2003U1.0 0.13 ug/L1 Chromium 10 05/04/2017 0955U101.3 ug/L1 Cobalt 10 05/04/2017 0955U100.63 ug/L1 Copper 10 05/04/2017 0955U100.63 ug/L1 Lead 10 05/04/2017 0955U100.25 ug/L1 Nickel 50 05/04/2017 0955U501.3 ug/L1 Selenium 10 05/04/2017 0955U101.3 ug/L1 Silver 10 05/04/2017 0955U100.25 ug/L1 Thallium 5.5 05/04/2017 0955U5.5 0.13 ug/L1 Vanadium 25 05/04/2017 0955U251.5 ug/L1 Zinc 10 05/04/2017 0955U102.5 ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 49 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Metals - LCS Batch:Prep Method: Prep Date: Sample ID:SQ40786-002 40786 3005A 04/28/2017 1749Analytical Method:6020B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Antimony 100 05/04/2017 100010310080-1201 Arsenic 110 05/04/2017 100010810080-1201 Barium 100 05/04/2017 100010310080-1201 Beryllium 100 05/04/2017 100010110080-1201 Cadmium 99 05/05/2017 20089910080-1201 Chromium 100 05/04/2017 100010010080-1201 Cobalt 110 05/04/2017 100010710080-1201 Copper 110 05/04/2017 100010810080-1201 Lead 100 05/04/2017 100010210080-1201 Nickel 110 05/04/2017 100010610080-1201 Selenium 100 05/04/2017 100010510080-1201 Silver 100 05/04/2017 100010410080-1201 Thallium 100 05/04/2017 100010210080-1201 Vanadium 100 05/04/2017 100010310080-1201 Zinc 110 05/04/2017 100010610080-1201 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 50 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Metals - MS Batch:Prep Method: Prep Date: Sample ID:SD28010-001MS 40786 3005A 04/28/2017 1749Analytical Method:6020B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(ug/L)(ug/L)(ug/L) Antimony 95 05/04/2017 10119510070-1300.0 1 Arsenic 88 05/04/2017 10118810070-1300.0 1 Barium 340 05/04/2017 101111510070-1302301 Beryllium 98 05/04/2017 10119710070-1301.4 1 Cadmium 95 05/05/2017 20199510070-1300.0 1 Chromium 93 05/04/2017 10118510070-1308.1 1 Cobalt 94 05/04/2017 10119010070-1304.4 1 Copper 110 05/04/2017 10119210070-130181 Lead 110 05/04/2017 101110310070-1306.1 1 Nickel 92 05/04/2017 10118510070-1306.4 1 Selenium 82 05/04/2017 10118210070-1300.0 1 Silver 94 05/04/2017 10119410070-1300.0 1 Thallium 100 05/04/2017 101110010070-1300.55 1 Vanadium 110 05/04/2017 10118610070-130241 Zinc 140 05/04/2017 10118610070-130541 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 51 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Metals - MSD Batch:Prep Method: Prep Date: Sample ID:SD28010-001MD 40786 3005A 04/28/2017 1749Analytical Method:6020B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(ug/L)(ug/L)(ug/L) Antimony 97 05/04/2017 10169710070-1302.2 200.0 1 Arsenic 90 05/04/2017 10169010070-1302.8 200.0 1 Barium 340 05/04/2017 101611810070-1300.88 202301 Beryllium 98 05/04/2017 10169610070-1300.77 201.4 1 Cadmium 96 05/05/2017 20249610070-1301.9 200.0 1 Chromium 96 05/04/2017 10168810070-1302.9 208.1 1 Cobalt 95 05/04/2017 10169110070-1300.83 204.4 1 Copper 110 05/04/2017 10169510070-1302.9 20181 Lead 110 05/04/2017 101610310070-1300.64 206.1 1 Nickel 93 05/04/2017 10168610070-1300.79 206.4 1 Selenium 86 05/04/2017 10168610070-1304.3 200.0 1 Silver 96 05/04/2017 10169610070-1302.1 200.0 1 Thallium 100 05/04/2017 101610110070-1300.69 200.55 1 Vanadium 110 05/04/2017 10168910070-1302.3 20241 Zinc 140 05/04/2017 10168610070-1300.071 20541 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit U = Not detected at or above the detection limit Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 52 of 52 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Chain of Custody and Miscellaneous Documents 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. cdmsmith.com