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HomeMy WebLinkAbout9209_NorthWakeMSWLF_14DayNotification_GWMR_20170920 5400 Glenwood Avenue, Suite 400 Raleigh, North Carolina 27612 tel: 919 325-3500 fax: 919 781-5730 October 23, 2017 Ms. Jaclynne Drummond North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section 2090 U.S. 70 Highway Swannanoa, North Carolina 28778 Subject: 14-Day Notification of Groundwater Protection Exceedance September 2017 Semi-Annual Monitoring North Wake Closed Unlined Landfill Facility Permit No. 9209-MSWLF-1984 Dear Ms. Drummond: CDM Smith Inc., on behalf of Wake County (County), is submitting an electronic copy of the 14-day notification of groundwater exceedance (Notification) for the September 2017 semi-annual sampling event for the North Wake Closed Unlined Landfill. This letter report provides the signed Notification, a summary of the groundwater monitoring wells with tabulated laboratory analytical results and comparisons to the 15A NCAC 02L .0202 (NC 2L) or Groundwater Protection Standards, and a site map (Figure 1). The following list indicates the analytes detected above their respective NC 2L or Groundwater Protection Standards at each sampling location. Estimated or ā€œJā€ flag detections are also provided and are identified with an ā€œ*ā€ qualifier. A complete summary of all detected and estimated concentrations from March 2011 to September 2017 is provided in Table 1. Laboratory analytical data reports will be provided with the semi-annual sampling report. MW-11 (Shallow Background) Metals: Vanadium* Volatile Organic Compounds: None Detected MW-11d (Deep Background) Metals: Vanadium* Volatile Organic Compounds: None Detected Ms. Jaclynne Drummond October 23, 2017 Page 2 MW-5R Metals: Cobalt Volatile Organic Compounds: Benzene, 1,4-Dichlorobenzene, Vinyl Chloride MW-6 Metals: Cobalt* Volatile Organic Compounds: None Detected MW-6d Metals: Cobalt*, Vanadium* Volatile Organic Compounds: None Detected MW-7 Metals: Cobalt Volatile Organic Compounds: None Detected MW-8 Metals: Vanadium* Volatile Organic Compounds: None Detected MW-8d Metals: Vanadium* Volatile Organic Compounds: None Detected MW-9 Metals: Chromium, Cobalt*, Lead, Thallium*, Vanadium Volatile Organic Compounds: None Detected MW-10 Metals: Cobalt*, Vanadium* Volatile Organic Compounds: Tetrachloroethene, Trichloroethene MW-10d Metals: None Detected Volatile Organic Compounds: None Detected MW-23 Metals: Chromium, Cobalt*, Lead, Thallium*, Vanadium Volatile Organic Compounds: None Detected Ms. Jaclynne Drummond October 23, 2017 Page 3 MW-23d Metals: Vanadium* Volatile Organic Compounds: None Detected MW-24 Metals: Vanadium* Volatile Organic Compounds: None Detected MW-29d Metals: Vanadium* Volatile Organic Compounds: None Detected MW-31d Metals: Vanadium* Volatile Organic Compounds: None Detected MW-32 Metals: None Detected Volatile Organic Compounds: None Detected TB-1a deep Metals: Vanadium* Volatile Organic Compounds: None Detected MW-36 Metals: Chromium, Cobalt*, Vanadium* Volatile Organic Compounds: None Detected MW-36d Metals: Vanadium* Volatile Organic Compounds: None Detected Vanadium was detected in the shallow and deep background monitoring wells (MW-11 and -11D) above its Groundwater Protection Standard. Historically, cobalt has also been detected in the background monitoring wells above the Groundwater Protection Standard. The chromium, cobalt, thallium, and vanadium concentrations in the compliance monitoring wells above the NC 2L or Groundwater Protection Standards are likely naturally occurring based on the historical detections and concentrations in the background and compliance monitoring wells at the site. These concentrations are being evaluated as part of an ongoing Alternate Source Demonstration (ASD). Filtered samples were collected from monitoring wells (MW-9, -23, -24, and -36) with an elevated turbidity (i.e. greater than 10 nephelometric turbidity units) during the September 2017 sampling event in order to demonstrate that select metals exceeding the NC 2L or Groundwater Protection Ms. Jaclynne Drummond October 23, 2017 Page 4 Standards are not related to a release from the landfill. Total metals that exceeded the NC 2L or Groundwater Protection Standards from these wells were analyzed for dissolved metals to determine if turbidity was a contributing factor to total reported metals. Dissolved metal sample results are provided in Table 1. The ASD will be submitted following evaluation of the current and historic data and site conditions. If you have any questions or require further explanation, do not hesitate to call me at (919) 325-3500. Very truly yours, Mathew F. Colone, P.G. CDM Smith Inc. cc: John Roberson, WCSWM Elliott Cornell, WCSWM Table 1a Detected Groundwater Constituents - Metals September 2017 Semi-Annual Sampling Event North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984 Monitoring Well CodeSample DateAntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperLeadMercuryNickelSeleniumSilverThalliumVanadiumZincNorth Carolina 2L or Groundwater Protection Standard 1*10 700 4*2 10 1*1,000 15 1 100 20 20 0.2*0.3*1,000 6 10 100 1 1 10 10 10 10 0.2 50 10 10 5.5 25 10 MW-11 17-Mar-11 76.7J 1.6J 3.88J 0.265J 3.51J 24.3 MW-11 1-Nov-11 80.7J 1.9J 6.33JB 2.14JB 3.61J 19.6 MW-11 25-Apr-12 65.3J 2.37J 3.23J 12.1 MW-11 23-Oct-12 80.6J 1.42J 3.66J 5.32J 19.7 MW-11 17-Apr-13 90J 0.2J 2J 2J 8J 1J 1J 9J 20B MW-11 16-Oct-13 100 0.1J 0.2J 2J 1J 4J 0.5J 0.9J 5J 15B MW-11 16-Apr-14 170 0.5J 0.2J 4J 6J 18 3J 3J 0.08J 40 50B MW-11 12-Nov-14 90J 0.2J 0.2J 2J 2J 8J 1J 1J 0.05J 7J 24 MW-11 30-Apr-15 100 0.2J 2J 3J 10J 1J 2J 0.06J 12J 27 MW-11 15-Oct-15 110 0.3J 0.1J 3J 3J 11 1J 0.04J 2J 0.05J 13JB 27 MW-11 21-Apr-16 0.5J 130 0.3J 3J 4J 16 2J 2J 0.1JB 18J 32 MW-11 1-Sep-16 90J 0.28J 0.54J 2.4J 2.6J 8.3J 1.3J 1.6J 11J 20 MW-11 20-Apr-17 61J 1.2J 1.5J 11 MW-11 22-Sep-17 45J 2.4J 1.8J 3.7J 6.3J MW-11d 18-Mar-11 0.852J 51.2J 3.43J 4.41J 3.73J 8.04J MW-11d 2-Nov-11 45.5J 2.18J 4.14JB 2.45J 5.86J MW-11d 26-Apr-12 0.247J 44.2J 3.04J 9.68JB 3.31J 2.05J 4.62J MW-11d 24-Oct-12 43.7J 0.375J 2.40J 2.53J 5.10J MW-11d 18-Apr-13 0.4J 50J 0.1J 2JB 0.2J 1J 0.6J 4JB MW-11d 17-Oct-13 0.6J 0.6J 50J 0.3J 1J 0.2J 1J 0.02J 0.6J 2J 2JB MW-11d 17-Apr-14 300 2.1 0.2J 15 13 56 11 9J 0.2J 99 88 MW-11d 13-Nov-14 150 0.7J 0.1J 5J 4J 18 4J 3J 0.07J 37 35 MW-11d 29-Apr-15 0.6J 0.5J 60J 0.1J 0.1J 2J 0.6J 3J 0.6J 0.9J 5J 8J MW-11d 15-Oct-15 0.4J 90J 0.3J 0.1J 3J 2J 9J 2J 0.05J 2J 14JB 16 MW-11d 21-Apr-16 0.3J 60J 2J 0.3J 4J 0.5J 2J 12 MW-11d 1-Sep-16 0.43BJ 45J 0.076J 1.2J 2.1J 0.25J 0.75J 2.7J 9.2JB MW-11d 20-Apr-17 48J 2.2J 2.2J 2.2J 5.0J MW-11d 22-Sep-17 45J 2.8J 1.6J 3.3J 5.1J MW-5R 16-Mar-11 95J 4.62J 3.39J 0.267J 6.9J MW-5R 31-Oct-11 123 3.28J 2.17J 5.83JB 1.13J 0.152J 8.33J MW-5R 24-Apr-12 0.411J 97.3J 2.79J 2.47J 0.170J 4.28J MW-5R 22-Oct-12 99.3J 1.82J 3.61J 0.114J 23.9 MW-5R 17-Apr-13 80J 0.08J 2J 0.3J 3J 0.1J 5JB MW-5R 16-Oct-13 90J 0.05J 1J 0.5J 0.4J 3J 0.1J 5JB MW-5R 16-Apr-14 80J 0.3J 0.3J 0.2J 0.5J 1J 0.2J 2J 5JB MW-5R 12-Nov-14 80J 2J 0.2J 2J 0.3J 6JB MW-5R 30-Apr-15 70J 0.1J 0.8J 0.1J 1J 0.1J 4J MW-5R 15-Oct-15 110 0.2J 7J 0.8J 2J 0.6J 0.04J 4J 0.1J 6J MW-5R 21-Apr-16 60J 0.07J 1J 0.2J 0.4J 1J 0.1JB 2J MW-5R 14-Sep-16 79J 0.063J 1.7J 0.45JB 0.046JB 2.4J 0.080J 1.1J 5.3JB MW-5R 20-Apr-17 71J 1.5J MW-5R 20-Sep-17 430 13 1.7J 1.4J 5.8J MW-6 16-Mar-11 365 7.08J 57.7 4.66J 11.5J 2.68J 3.18J 0.741J 51.3 MW-6 1-Nov-11 0.229J 3.98J 454 6.35J 65.7 4.04JB 18.2JB 2.55J 4.11J 5.36J MW-6 24-Apr-12 0.244J 182 3.49J 54.9 8.45J 2.18J 0.134J 117 MW-6 22-Oct-12 258 0.148J 1.59J 80.4 15.1J MW-6 17-Apr-13 100J 0.05J 1.6 35 4J 0.17J 6J 0.3J 9JB MW-6 16-Oct-13 90J 0.04J 0.3J 34 2J 0.02J 5J 2J 0.2J 3J 5JB MW-6 (dup)16-Oct-13 90J 0.2J 0.6J 35 2J 0.04J 6J 2J 0.2J 3J MW-6 16-Apr-14 0.2J 60J 0.10J 0.8J 1J 18 3J 0.21 4J 0.3J 2J 8JB MW-6 (dup)16-Apr-14 60J 0.07J 0.7J 1J 18 2J 0.21 4J 0.2J 3J 8JB MW-6 12-Nov-14 0.8J 310 49 1J 0.02J 15J 2J 0.1J 2JB MW-6 30-Apr-15 70J 0.06J 0.1J 25 1J 0.08J 4J 0.1J 3J MW-6 14-Oct-15 230 0.2J 32 4J 0.03J 13J 2J 0.3J MW-6 20-Apr-16 70J 0.04J 8J 0.5J 0.03J 3J 1J 0.08J MW-6 (dup)20-Apr-16 70J 0.3J 7J 0.6J 0.03J 3J 1J 0.07J MW-6 14-Sep-16 0.19JB 0.29J 210 0.13J 19 2.1JB 0.032JB 9.3J 1.1J 0.084J 1.2J 6.0JB MW-6 20-Apr-17 120 2.5J 8.3J 0.98J 0.40 4.2J MW-6 20-Apr-17 130 2.6J 8.2J 1.0J 0.41 4.8J 21 MW-6 21-Sep-17 160 5.3J 2.2J 7.6J Solid Waste Section Limit Page 1 of 12 October 2017 Table 1a Detected Groundwater Constituents - Metals September 2017 Semi-Annual Sampling Event North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984 Monitoring Well CodeSample DateAntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperLeadMercuryNickelSeleniumSilverThalliumVanadiumZincNorth Carolina 2L or Groundwater Protection Standard 1*10 700 4*2 10 1*1,000 15 1 100 20 20 0.2*0.3*1,000 6 10 100 1 1 10 10 10 10 0.2 50 10 10 5.5 25 10Solid Waste Section Limit MW-6d 16-Mar-11 0.961J 68.2J 3.05J 3.91J 0.428J 3.28J 6.94J MW-6d 2-Nov-11 2.63J 100 5.42J 1.26J 6.46JB 4.68J 3.98J 13.1 MW-6d 26-Apr-12 1.59J 72J 5.68J 7.24JB 2.37J 2.61J 4J 6.97J MW-6d (dup)26-Apr-12 1.22J 66J 5.53J 6.45JB 2.10J 2.20J 3.78J 5.88J MW-6d 23-Oct-12 1.21J 2.84J 71.1J 0.407J 4.83J 2.83J 2.11J 3.59J 6.02J MW-6d 18-Apr-13 3.1J 80J 0.1J 0.5J 4J 0.9J 3J 0.4J 2J 8JB MW-6d (dup)18-Apr-13 2.8J 70J 0.09J 0.4J 4J 0.8J 3J 0.4J 2J 6JB MW-6d 17-Oct-13 6.9 80J 0.1J 0.5J 4J 1J 4J 0.6J 0.03J 3J 3J 7JB MW-6d 17-Apr-14 1.2J 60J 0.1J 0.1J 4J 1.0J 2J 0.3J 2J 6J 7JB MW-6d 12-Nov-14 1.2J 60J 0.1J 0.2J 3J 1J 2J 0.3J 2J 4JB MW-6d 30-Apr-15 1.7J 0.6J 50J 0.08J 0.1J 4J 0.9J 2J 0.2J 2J 3J 4J MW-6d (dup)30-Apr-15 2.1J 80J 0.05J 0.2J 4J 0.9J 2J 0.3J 0.05J 2J 3J 6JB MW-6d 15-Oct-15 1.1J 60J 0.1J 0.2J 4J 0.6J 2J 0.4J 0.04J 3J 2JB 6J MW-6d 20-Apr-16 0.4J 50J 0.07J 0.1J 4J 0.6J 2J 3J 4J MW-6d 12-Sep-16 1.0J 65J 0.21J 4.4J 0.85J 6.6JB 1.7J 2.4J 0.34J 4.7J 15 MW-6d 20-Apr-17 51J 2.6J 2.4J 1.6J 2.6J 9.1J MW-6d 22-Sep-17 0.66J 33J 4.2J 3.1J 4.1J 6.3J MW-7 16-Mar-11 51.7J 1.2 6.76J 30.5 4.81J 11.8J 1.42J 3.14J 0.36J 1.73J 11.8 MW-7 2-Nov-11 67.1J 0.38J 14.9 31.6 21.2B 13.4J 1.17J 3.27J 9.74J 44.8 MW-7 26-Apr-12 50.3J 0.805J 13.3 27.1 10.7B 4.04J 10.9J 3.63J 7.24J 13.9 MW-7 22-Oct-12 80.7J 29.6 30.8 37.4 6.69J 11.5J 2.02J 0.152J 24.2J 24.1 MW-7 16-Apr-13 80J 0.5J 0.6J 35 27 61 9J 0.18J 13J 2J 0.2J 24J 25B MW-7 16-Oct-13 60J 0.1J 0.6J 5J 37 11 1J 0.04J 12J 3J 12J 11B MW-7 16-Apr-14 50J 0.2J 1.1 10J 46 19 3J 0.04J 17J 3J 0.09J 23J 40B MW-7 11-Nov-14 0.5J 70J 0.4J 0.7J 23 26 45 7J 0.28 13J 2J 0.2J 5J 22 MW-7 30-Apr-15 60J 0.1J 0.9J 5J 48 11 2J 0.04J 17J 0.08J 33 MW-7 14-Oct-15 40J 0.1J 0.4J 7J 30 10 2J 0.02J 10J 1J 0.05J 31 MW-7 20-Apr-16 40J 0.06J 1.0 2J 52 7J 2J 0.03J 17J 2J 11 MW-7 13-Sep-16 0.24J 44J 1.6 1.4J 41 5.5JB 1.1J 12J 4.0J 13 MW-7 18-Apr-17 34J 0.13J 0.83J 6.1J 31 30 16 0.037J 9.2J 8.1J 7.4J MW-7 18-Sep-17 0.52J 27J 23 1.1J 6.8J MW-8 16-Mar-11 41.1J 2.83J 1.63J 2.22J 0.873J 0.279J 1.65J 6.42J MW-8 31-Oct-11 56.5J 7.42J 4.53JB 4.95JB 5.18J 7.32J MW-8 24-Apr-12 0.937J 41.3J 1.21J 3.19J 1.83J 515 MW-8 22-Oct-12 41.8J 0.146J 0.404J 1.20J 2.76J 1.97J MW-8 17-Apr-13 0.8J 50J 0.08J 2J 1J 0.03J 4J 9JB MW-8 16-Oct-13 50J 0.1J 0.2J 2J 2J 4J MW-8 16-Apr-14 50J 0.07J 1J 1J 5J 5J 107 MW-8 12-Nov-14 50J 0.6J 0.4J 5J 5JB MW-8 30-Apr-15 80J 0.1J 0.1J 4J 2J 2J 0.2J 7J 14 MW-8 15-Oct-15 80J 0.08J 0.1J 2J 2J 0.3J 0.04J 6J 6J MW-8 21-Apr-16 70J 0.8J 2J 0.02J 6J 0.05JB 6J MW-8 14-Sep-16 65J 0.13J 1.9J 0.27JB 6.6J 2.9J 8.5JB MW-8 20-Apr-17 61J 4.9J 1.8J 4.7J MW-8 18-Sep-17 73J 0.14J 0.85J 4.6J 3.0J 5.7J MW-8d 18-Mar-11 0.512J 28.7J 5.85J 4.41J 2.19J 5.18J 4.47J MW-8d 2-Nov-11 0.724J 25.0J 1.05 5.02J 5.02JB 2.00J 4.22J 7.28J MW-8d 26-Apr-12 1.63J 34.5J 11B 2.82J 4.15J 7.52J MW-8d 24-Oct-12 1.59J 30.6J 0.483J 5.46J 3.21J 4.79J 9.99J MW-8d 18-Apr-13 0.6J 20J 4J 0.3J 1J 0.2J 1J 0.06J 2JB MW-8d 17-Oct-13 40J 0.2J 0.3J 6J 1J 6J 1J 0.03J 2J 7J MW-8d 17-Apr-14 0.9J 20J 0.1J 4J 0.4J 2J 0.3J 0.8J 7J 5JB MW-8d 12-Nov-14 1.0J 20J 4J 0.3J 2J 0.3J 0.9J 2JB MW-8d 30-Apr-15 2.5J 0.6J 20J 0.1J 3J 0.4J 1J 0.4J 1J 2J 4J MW-8d 15-Oct-15 0.2J 20J 3J 0.06J 0.05J 0.5J 1JB MW-8d 21-Apr-16 20J 3J 0.5J MW-8d 14-Sep-16 16J 1.7J 0.60JB 0.047JB 0.72J 4.8J 2.0JB MW-8d 20-Apr-17 19J 2.6J 4.3J 4.0J 3.1J MW-8d 18-Sep-17 16J 2.9J 3.3J MW-8d (dup)18-Sep-17 17J 3.2J 2.8J Page 2 of 12 October 2017 Table 1a Detected Groundwater Constituents - Metals September 2017 Semi-Annual Sampling Event North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984 Monitoring Well CodeSample DateAntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperLeadMercuryNickelSeleniumSilverThalliumVanadiumZincNorth Carolina 2L or Groundwater Protection Standard 1*10 700 4*2 10 1*1,000 15 1 100 20 20 0.2*0.3*1,000 6 10 100 1 1 10 10 10 10 0.2 50 10 10 5.5 25 10Solid Waste Section Limit MW-9 17-Mar-11 176 0.241J 7.36J 4.82J 2.1J 3.79J 0.841J 3.51J 0.405J 13.2 MW-9 1-Nov-11 209 0.425J 14.9 6.79J 8.83JB 6.37J 4.11JB 0.982J 4.52J 0.164J 6.88J 69.2 MW-9 (dup)1-Nov-11 191 0.256J 10.4 5.81J 5.32JB 3.99J 3.08JB 0.874J 3.66J 0.127J 3.26J 50.1 MW-9 25-Apr-12 176 0.220J 5.68J 4.81J 2.72J 13.5 MW-9 23-Oct-12 5.17J 210 0.711J 4.13 19.7 6.96J 17.1 27.2 3.41J 7.49J 0.521J 30.2 141 MW-9 17-Apr-13 160 0.3JB 2 3J 4J 4J 4J 4J 0.3J 8J 27B MW-9 16-Oct-13 120 0.2J 1.1 2J 0.4J 2J 1J 2J 0.2J 6J 16B MW-9 16-Apr-14 130 0.4J 1.3 4J 0.8J 5J 4J 3J 0.3J 16J 36B MW-9 12-Nov-14 120 0.3J 0.4J 4J 0.6J 4J 3J 2J 0.2J 17 MW-9 (dup)12-Nov-14 140 0.5J 0.4J 6J 1J 6J 6J 2J 0.3J 4J 28 MW-9 29-Apr-15 0.7J 90J 0.1J 0.3J 2J 0.1J 1J 0.8J 0.8J 0.2J 3J 8J MW-9 15-Oct-15 160 0.7J 0.2J 9J 1J 6J 7J 0.07J 1J 0.3J 11JB 31 MW-9 20-Apr-16 150 0.2J 2J 0.2J 1J 0.7J 0.9J 0.1J 3J MW-9 13-Sep-16 100 0.15J 0.12J 1.7J 1.3JB 1.0J 1.2J 0.16J 11JB 9.4J MW-9 19-Apr-17 130 2.1J 1.0J 0.52J 7.4J 4.6J MW-9 21-Sep-17 160 1.4 0.37J 13 1.9J 11 15 2.1J 0.40J 34 49 MW-9 (dissolved)21-Sep-17 NA NA NA NA NA NA NA NA NA NA NA 11J NA MW-10 17-Mar-11 34J 0.285J 2.22J 1.93J 4.17J 2.25J 0.388 2.48J 0.352J 14.1 MW-10 31-Oct-11 28.1J 1.72J 1.61J 3.56JB 3.00J 1.94J 12.8 MW-10 25-Apr-12 34.7J 0.320J 0.438J 1.79J 2.04J 4.81J 2.64J 0.538 2.25J 21.7 MW-10 23-Oct-12 31.1J 0.302J 0.965J 2.07J 2.51J 2.57J 0.910 2.07J 16.5 MW-10 17-Apr-13 30J 0.3JB 0.4J 0.4J 2J 2JB 1J 0.43 3J 0.06J 14B MW-10 16-Oct-13 30J 0.3J 0.2J 0.4J 2J 2J 1J 0.29 3J 0.05J 4J 9JB MW-10 16-Apr-14 30J 0.3J 0.2J 2J 1J 0.5J 0.05J 3J 4J 38B MW-10 12-Nov-14 30J 0.3J 2J 0.03J 3J 9JB MW-10 29-Apr-15 0.2J 40J 0.3J 0.1J 3J 2J 1J 0.10J 5J 0.05J 10 MW-10 14-Oct-15 30J 0.3J 0.2J 2J 0.8J 0.4J 0.08J 3J 27 MW-10 20-Apr-16 30J 0.3J 0.1J 4J 0.6J 0.3J 0.03J 5J 1J 0.05J 4J MW-10 13-Sep-16 0.47J 31J 0.36J 0.19J 3.8J 2.0JB 1.2J 0.14J 4.8J 3.6J 280 MW-10 19-Apr-17 27J 0.32J 2.9J 0.93J 0.38J 0.064J 3.4J 17 MW-10 22-Sep-17 17J 0.18J 1.3J 2.2J 0.30J 2.3J 2.1J 8.9J MW-10d 18-Mar-11 3.88J 2.16J 4.02J MW-10d 2-Nov-11 3.81J 2.10J 3.18JB 4.14J MW-10d 26-Apr-12 0.232J 4.36J 3.50J 3.47JB 4.57J MW-10d 24-Oct-12 3.11J MW-10d 18-Apr-13 4JB 1JB 0.07J 0.7J 1J MW-10d 16-Oct-13 0.3J 3JB 0.2J 1J 0.05J 0.7J 0.6J MW-10d 17-Apr-14 2J 0.4J 0.6J 4J 3JB MW-10d 12-Nov-14 3J 0.5J 0.04J 0.4J MW-10d 30-Apr-15 0.8J 0.5J 3J 0.3J 0.3J 0.05J 0.6J 4J MW-10d 15-Oct-15 0.5J 5J 0.07J 0.8J 0.08J 1J 0.2J 0.07J 0.6J 5J MW-10d 21-Apr-16 0.3J 5J 0.2J 2J 1J 2J 6J MW-10d 14-Sep-16 2.5J 0.67JB 0.15J 3.3J 5.5JB MW-10d 19-Apr-17 2.5J 0.14J 0.70J MW-10d 18-Sep-17 4.1J 0.35J 1.4J 3.1J 0.32J 6.9J MW-22 18-Mar-11 40.7J 0.105J 2.21 4.1J 14.8 2.71J 3.69J 7.49J 4.89J 16.1 MW-22 1-Nov-11 41.2J 7.96 4.25J 46.7 5.24JB 17.2JB 2.87J 3.22J 43.9 MW-22 25-Apr-12 61.5J 0.224J 4.78 4.77J 63.8 14J 2.56J 0.162J 33.1 18.4 MW-22 23-Oct-12 34.7J 8.27 2.28J 44.7 16.8J 4.02J 19.2 MW-22 17-Apr-13 70J 0.1J 4 0.9J 76 1JB 0.7J 15J 0.06J 12B MW-22 16-Oct-13 50J 0.1J 3.5 1J 25 1J 1J 10J 3J 8JB MW-22 16-Apr-14 50J 0.1J 2.5 0.9J 43 1J 1J 14J 4J 14B MW-22 12-Nov-14 40J 0.1J 2.5 3J 17 2J 2J 10J 9J MW-22 30-Apr-15 50J 1.5 0.6J 31 0.7J 0.6J 10J 9J MW-22 15-Oct-15 80J 0.7J 3.4 9J 29 5J 9J 0.05J 13J 4J 0.2J 14JB 56 MW-22 20-Apr-16 40J 0.07J 1.3 18 0.5J 0.3J 7J 6J MW-22 13-Sep-16 82J 0.82J 3.1 12 38 6.9JB 11 14J 3.1J 0.20J 18J 47 MW-22 19-Apr-17 45J 0.26J 2.8 1.9J 18 2.6J 1.6J 6.5J 0.93J 6.4J 13 MW-22 18-Sep-17 Not Sampled(4) Page 3 of 12 October 2017 Table 1a Detected Groundwater Constituents - Metals September 2017 Semi-Annual Sampling Event North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984 Monitoring Well CodeSample DateAntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperLeadMercuryNickelSeleniumSilverThalliumVanadiumZincNorth Carolina 2L or Groundwater Protection Standard 1*10 700 4*2 10 1*1,000 15 1 100 20 20 0.2*0.3*1,000 6 10 100 1 1 10 10 10 10 0.2 50 10 10 5.5 25 10Solid Waste Section Limit MW-23 18-Mar-11 43.3J 5.52J 9.92J 6.42J 3.64J 11.4J 23.7 MW-23 2-Nov-11 43.5J 5.93J 11.0B 2.79J 4.01J 9.10J 14.8 MW-23 26-Apr-12 42.7J 6.68J 1.63J 10.4B 7.07J 4.20J 12.5J 17.5 MW-23 24-Oct-12 38.9J 5.76J 1.83J 8.02J 4.12J 3.92J 13.3J 18.5 MW-23 18-Apr-13 0.2J 240 1.8 0.1J 30 15 56 30 0.06J 28J 1J 106 147 MW-23 16-Oct-13 30J 0.2J 0.1J 3J 0.7J 4J 2J 0.02J 2J 5J 6JB MW-23 16-Apr-14 50J 0.3J 0.2J 7J 2J 10 5J 4J 0.1J 16J 25B MW-23 12-Nov-14 50J 0.4J 7J 2J 12 6J 0.02J 5J 0.1J 12J 19 MW-23 30-Apr-15 0.4J 50J 0.3J 7J 2J 13 6J 0.03J 6J 0.1J 15J 26 MW-23 15-Oct-15 110 1.1 20 7J 34 18 0.06J 16J 0.5J 39 69 MW-23 (dup)15-Oct-15 170 1.6 32 11 51 30 0.12J 25J 0.8J 60 112 MW-23 20-Apr-16 40J 0.3J 5J 1J 9J 5J 4J 0.1J 9J 21 MW-23 13-Sep-16 54J 0.59J 0.083J 8.9J 3.3J 15B 7.7J 6.9J 0.22J 23J 39 MW-23 19-Apr-17 26J 0.19J 3.3J 4.5J 2.1J 2.4J 6.5J 7.2J MW-23 20-Sep-17 110 1.5 0.14J 19 6.6J 33 17 16J 0.48J 59 67 MW-23 (dissolved)20-Sep-17 NA NA NA NA NA NA NA NA NA NA 3.3J NA MW-23d 17-Mar-11 0.561J 41.7J 4.14J 4.38J 1.04J 5.04J 5.36J MW-23d 1-Nov-11 0.798J 35.8J 3.92J 4.12JB 3.75J 10.9 MW-23d 25-Apr-12 0.754J 35J 0.746J 4.03J 16.8B 3.32J 4.05J 6.65J MW-23d 23-Oct-12 0.552J 33.2J 0.644J 4.73J 4.38J 4.48J 8.66J MW-23d 18-Apr-13 2.6J 40J 1.5 3JB 0.3J 4J 0.4J 1J 12B MW-23d 17-Oct-13 1.7J 40J 0.05J 0.7J 2J 0.3J 3J 0.3J 0.02J 1J 3J 3JB MW-23d 17-Apr-14 1.3J 30J 0.3J 2J 0.3J 2J 0.3J 1J 6J 8JB MW-23d 13-Nov-14 1.1J 40J 0.2J 2J 0.3J 2J 0.3J 0.8J 2J 6J MW-23d 29-Apr-15 1.6J 40J 0.2J 2J 0.3J 2J 0.3J 0.9J 2J 6J MW-23d 15-Oct-15 3.6J 40J 0.04J 0.5J 3J 0.4J 4J 0.6J 0.05J 1J 2JB 13 MW-23d 20-Apr-16 1.1J 40J 0.2J 3J 0.3J 2J 0.2J 4J 7J MW-23d 13-Sep-16 1.2J 37J 0.23J 2.3J 0.26J 2.5JB 0.48J 2.5J 6.1J 13 MW-23d (dup)13-Sep-16 0.97J 36J 0.22J 1.9J 2.2JB 0.36J 2.2J 5.7J 10 MW-23d 19-Apr-17 0.53J 34J 0.24J 2.0J 4.9J 1.4J 3.7J 6.9J MW-23d 21-Sep-17 34J 2.7J 3.8J 3.5J 5.8J MW-24 18-Mar-11 3.98J 33J 2.17J 2.92J 3.62J 1.13J 4.25J 27.1 MW-24 2-Nov-11 48.8J 3.81J 6.75JB 4.69J 2.13J 6.26J 43.6 MW-24 26-Apr-12 57.6J 0.281J 7.54J 7.09JB 9.80J 3.35J 1.82J 0.190J 8.38J 58.7 MW-24 23-Oct-12 35.9J 2.10J 2.50J 4.01J 0.120J 5.34J 28.3 MW-24 17-Apr-13 120 1.4J 0.1J 9J 2J 11 17 0.24 5J 0.5J 17J 128 MW-24 16-Oct-13 60J 0.6J 0.1J 4J 0.9J 5J 7J 0.09J 2J 0.2J 8J 46 MW-24 16-Apr-14 120 1.1 6J 2J 9J 14 0.17J 4J 0.4J 22J 120 MW-24 12-Nov-14 130 1.5 8J 2J 11 17 0.21 5J 0.6J 14J 117 MW-24 29-Apr-15 80J 0.8J 4J 1J 7J 9J 0.12J 3J 0.3J 10J 69 MW-24 14-Oct-15 240 2.5 0.2J 12 4J 18 29 0.43 7J 0.9J 34 182 MW-24 20-Apr-16 170 1.8 10J 3J 13 22 0.21 6J 0.7J 23J 140 MW-24 13-Sep-16 34J 0.37J 0.086J 1.4J 0.55J 2.3JB 3.6J 1.5J 0.12J 7.5J 31 MW-24 19-Apr-17 66J 0.77J 3.8J 0.98J 5.0J 7.9J 0.086J 2.5J 0.24J 9.1J 56 MW-24 20-Sep-17 51J 0.76J 3.9J 0.71J 4.6J 5.8J 2.4J 0.19J 7.5J 47 MW-24 (dissolved)20-Sep-17 NA NA NA NA NA NA NA NA NA NA NA NA NA 3.6J NA MW-28 18-Mar-11 51.5J 9.81J 1.82J 2.29J 5.21J 2.92J 1.45J 0.179J 14J 40.5 MW-28 26-Apr-12 67.7J 14.2 3.90J 2.81JB 5.18J 5.84J 0.229J 20.7J 69.8 MW-28 18-Apr-13 60J 0.3J 10 3J 1J 1J 4J 0.2J 10J 34B MW-28 17-Apr-14 170 1.5 41 14 5J 7J 0.02J 20J 1.0J 53 159 MW-28 30-Apr-15 80J 0.5J 16 5J 2J 2J 0.02J 7J 0.4J 22J 62 MW-28 21-Apr-16 20J 4J 0.06J 9J MW-28 20-Apr-17 29J 0.18J 3.9J 0.30J 1.3J 6.1J 11 MW-28d 18-Mar-11 14.3J 4.17J 2.91J 2.31J 2.08J 1.59J 4.96J 16.8 MW-28d 26-Apr-12 1.46J 28.7J 10.1 1.34J 13.3B 4.99J 9.42J 4.73J 106 MW-28d 18-Apr-13 0.3J 9JB 2JB 0.1J 0.9J 0.9J 4JB MW-28d 17-Apr-14 0.4J 1J 6J 4J 0.4J 3J 1.0J 5J 6J 10B MW-28d 30-Apr-15 0.2J 10J 2J 0.09J 0.6J 0.9J 7J MW-28d 21-Apr-16 9J 2J 0.8J 9J 9J MW-28d 20-Apr-17 8.1J 1.3J 0.68J 3.3J 5.9J Page 4 of 12 October 2017 Table 1a Detected Groundwater Constituents - Metals September 2017 Semi-Annual Sampling Event North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984 Monitoring Well CodeSample DateAntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperLeadMercuryNickelSeleniumSilverThalliumVanadiumZincNorth Carolina 2L or Groundwater Protection Standard 1*10 700 4*2 10 1*1,000 15 1 100 20 20 0.2*0.3*1,000 6 10 100 1 1 10 10 10 10 0.2 50 10 10 5.5 25 10Solid Waste Section Limit MW-29d 18-Mar-11 0.391J 3.08J 54.8J 9.57J 16.2 4.09J 4.15J 7.4J 15.5 MW-29d 1-Nov-11 42.7J 6.46J 1.21J 12.4B 2.70J 4.25J 17.2 MW-29d 26-Apr-12 0.317J 41.5J 6.48J 8.73JB 3.94J 1.97J 3.72J 23.2 MW-29d 24-Oct-12 38.0J 4.87J 6.36J 2.48J 4.36J 7.64J MW-29d 18-Apr-13 40J 0.08J 4J 0.4J 5J 0.3J 1J 0.05J 3JB MW-29d 17-Oct-13 40J 0.1J 4J 0.2J 3J 1J MW-29d 17-Apr-14 40J 0.08J 3J 0.2J 3J 0.8J 5J 25B MW-29d 13-Nov-14 40J 0.07J 3J 0.5J 4J 0.3J 2J 2J MW-29d 29-Apr-15 0.2J 0.5J 40J 0.1J 4J 0.3J 4J 0.3J 1J 13 MW-29d 15-Oct-15 0.2J 40J 0.1J 4J 0.3J 4J 0.6J 0.04J 1J 8J MW-29d 21-Apr-16 0.6J 40J 4J 0.3J 5J 0.2J 1J 6J MW-29d 12-Sep-16 0.38J 39J 2.7J 3.1JB 0.25J 0.90J 4.8J 22 MW-29d 19-Apr-17 36J 2.7J 1.9J 2.3J 13 MW-29d 22-Sep-17 35J 3.9J 2.8J 5.9J MW-30 18-Mar-11 91.1J 0.202J 29 4.25J 37.1 8.69J 11.2J 1.12J 27 37.1 MW-30 1-Nov-11 147 0.302J 47.5 8.80J 69.8B 3.90J 22.2JB 3.51J 0.196J 44 60.8 MW-30 25-Apr-12 169 0.773J 58 9.94J 73.9 9.17J 22.7J 2.15J 0.360J 51.7 54.7 MW-30 23-Oct-12 197 57.5 11.3 80.2 9.44J 26.3 0.359J 54.4 62.6 MW-30 17-Apr-13 450 2.8 0.1J 124 24 155 17 0.04J 56 1J 146 141 MW-30 16-Oct-13 220 1.4 49 9J 63 6J 0.03J 21J 0.3J 50 40 MW-30 16-Apr-14 220 1.4 66 11 78 7J 0.02J 26J 0.5J 73 71 MW-30 12-Nov-14 500 3.0 0.2J 148 24 169 19 0.07J 59 2J 1.1J 154 148 MW-30 29-Apr-15 180 1.2 59 9J 67 6J 23J 0.4J 48 53 MW-30 15-Oct-15 0.4J 60J 1.2 0.7J 48 1J 12 2J 0.05J 10J 0.06J 63 44 MW-30 21-Apr-16 150 0.8J 46 7J 54 5J 0.02J 18J 0.3JB 29 38 MW-30 14-Sep-16 0.17JB 50J 0.36J 0.053J 8.8J 1.6J 11B 0.95J 4.5J 11J 18B MW-30 20-Apr-17 79J 0.56J 25 3.1J 28 2.2J 8.7J 0.14J 19J 22 MW-30 22-Sep-17 MW-31 17-Mar-11 42.6J 14 7.79J 4.47J 3.2J 0.255J 9.69J 26.3 MW-31 1-Nov-11 84.2J 0.151J 33.3 2.57J 23.9B 7.27J 13.7JB 2.66J 0.129J 26.2 57.9 MW-31 25-Apr-12 33.4J 0.122J 13.1 6.71J 3.56J 5.40J 0.904J 9.25J 33.1 MW-31 23-Oct-12 35.7J 14 6.52J 3.76J 5.09J 9.26J 53.6 MW-31 17-Apr-13 70J 0.4J 24 1J 14 7J 0.03J 8J 0.05J 18J 29B MW-31 16-Oct-13 30J 0.1J 11 0.4J 5J 2J 5J 5J 13B MW-31 16-Apr-14 90J 0.5J 0.2J 32 2J 18 10 0.07J 8J 0.07J 35 70 MW-31 12-Nov-14 0.5J 110 0.7J 41 2J 26 14 0.08J 11J 0.1J 37 29 MW-31 29-Apr-15 50J 0.2J 14 0.6J 7J 4J 0.03J 3J 13J 14 MW-31 14-Oct-15 0.5J 120 0.6J 38 2J 24 13 0.11J 9J 0.08J 37 37 MW-31 21-Apr-16 0.6J 70J 0.5J 30 2J 17 12 0.14J 5J 0.07JB 26 17 MW-31 13-Sep-16 29J 0.23J 13 0.64J 5.6B 3.4J 2.0J 12J 12 MW-31 19-Apr-17 28J 8.3J 3.9J 1.8J 2.6J 0.22J 5.2J 12 MW-31 21-Sep-17 MW-31d 16-Mar-11 1.19J 20.3J 9.86J 4.08J 2.56J 1.24J 0.327J 9.46J 30.5 MW-31d 31-Oct-11 1.21J 21.2J 13.4 34.2B 4.99JB 10.2J 69.6 MW-31d 24-Apr-12 1.68J 17.1J 6.79J 26.5 0.944J 7.62J 12.6 MW-31d 22-Oct-12 7.20J 19.3J 8.24J 1.82J 7.99J 43.5 MW-31d 16-Apr-13 0.5J 20J 6J 0.08J 0.8JB 1J 6J 21B MW-31d 15-Oct-13 0.8J 20J 6J 0.06J 1J 0.8J 5J 16B MW-31d 15-Apr-14 0.7J 20J 5J 0.09J 0.8J 0.9J 9J 24B MW-31d 11-Nov-14 0.5J 20J 6J 0.08J 0.8J 0.7J 2J 7J MW-31d 28-Apr-15 1.1J 20J 6J 0.07J 0.9J 0.8J 5J 24 MW-31d 13-Oct-15 1.2J 20J 0.3J 6J 0.05J 3J 0.2J 0.04J 1J 4J 30 MW-31d 21-Apr-16 20J 4J 0.7J 0.9J 2J 5J MW-31d 13-Sep-16 0.59J 18J 0.14J 5.3J 1.5JB 1.2J 7.2J 56 MW-31d 19-Apr-17 18J 5.4J 2.6J 6.6J 53 MW-31d 18-Sep-17 19J 4.4J 1.0J 7.8J 2.6J Not Sampled(4) Not Sampled(4) Page 5 of 12 October 2017 Table 1a Detected Groundwater Constituents - Metals September 2017 Semi-Annual Sampling Event North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984 Monitoring Well CodeSample DateAntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperLeadMercuryNickelSeleniumSilverThalliumVanadiumZincNorth Carolina 2L or Groundwater Protection Standard 1*10 700 4*2 10 1*1,000 15 1 100 20 20 0.2*0.3*1,000 6 10 100 1 1 10 10 10 10 0.2 50 10 10 5.5 25 10Solid Waste Section Limit MW-32 17-Mar-11 21.8J 0.145J 4.58J 2.91J 18.2 2.11J 3.91J 0.276J 7.49J 29.5 MW-32 1-Nov-11 5.75J 14.2J 3.41J 1.47J 10.0B 3.39J 2.96J 27.7 MW-32 25-Apr-12 0.393J 3.37J 15.4J 0.261J 1.92J 2.34J 8.49J 1.96J 5.71J 6.22J MW-32 23-Oct-12 30J 6.71J 3.30J 27.2 5.04J 11.8J 13.1 MW-32 17-Apr-13 30J 0.3J 5J 3J 22 0.5J 5J 9J 8JB MW-32 16-Oct-13 70J 0.6J 0.3J 11 6J 50 0.9J 10J 0.1J 32 25 MW-32 16-Apr-14 20J 0.3J 2J 2J 8J 0.2J 2J 7J 10B MW-32 12-Nov-14 50J 0.5J 11 5J 37 0.9J 9J 0.1J 15J 18 MW-32 29-Apr-15 0.6J 140 1.6 0.1J 27 18 131 3J 24J 0.3J 77 58 MW-32 14-Oct-15 170 1.4 0.1J 29 18 135 2J 0.04J 25J 0.3J 91 53 MW-32 21-Apr-16 40J 0.5J 6J 5J 28 0.5J 6J 0.08JB 17J 18 MW-32 13-Sep-16 40J 0.63J 0.20J 8.5J 5.6J 27B 0.75J 7.2J 0.086J 18J 19 MW-32 20-Apr-17 11J 0.30J 1.6J 0.90J 5.1J 1.4J 2.7J 3.5J MW-32 22-Sep-17 0.66J 14J 0.17J 1.6J 1.3J 1.3J 4.0J TB-1a 17-Mar-11 32.7J 2.46J 2.23J 11.6 2.68J 3.14J 0.849J 0.332J 7.45J 16.3 TB-1a 1-Nov-11 126 5.39 19.1 11.5 99.3B 19.0J 40.5 91.8 TB-1a 25-Apr-12 0.269J 190 1.5 29 22 158 7.33J 0.348 27.9J 0.186J 61.3 89.4 TB-1a 23-Oct-12 85.4J 0.584J 11.3 14.8 59.6 2.35J 13.3J 25 48.2 TB-1a 17-Apr-13 40J 0.06J 0.3J 5J 9J 24 0.9J 0.1J 6J 9J 11B TB-1a 16-Oct-13 60J 0.08J 0.3J 6J 10 35 1J 0.12J 9J 14J 14B TB-1a 16-Apr-14 10J 1.2 0.7J 5J 3J 0.3J 0.13J 3J 5J 16B TB-1a 12-Nov-14 80J 0.2J 2.7 10J 9J 54 2J 0.34 12J 0.08J 19J 41 TB-1a 29-Apr-15 0.6J 30J 0.06J 1.9 4J 5J 18 1J 0.22 6J 6J 17 TB-1a 15-Oct-15 70J 0.1J 2.5 8J 11 40 2J 0.22 13J 17JB 45 TB-1a 21-Apr-16 50J 0.7J 6J 6J 33 1J 0.22 7J 0.06JB 6J 18 TB-1a 14-Sep-16 0.17JB 99J 0.23J 1.7 12 11 72B 3.5J 0.72B 15J 0.11J 29 49B TB-1a 20-Apr-17 17J 0.37J 1.0J 3.6J 0.050J 1.9J 5.1J 5.5J TB-1a 22-Sep-17 TB-1a deep 16-Mar-11 1.19J 14.9J 16.7 3.97J 2.03J 4.68J 0.946J 0.338J 7.43J 12.4 TB-1a deep 31-Oct-11 0.865J 14.2J 22.9 4.52JB 6.60JB 1.13J 7.66J 13.2 TB-1a deep 24-Apr-12 0.928J 15.5J 15 11.5 3.87J 1.23J 6.58J 8.41J TB-1a deep 23-Oct-12 18.0J 14.9 6.85J 8.29J 6.51J 10.4 TB-1a deep 16-Apr-13 2.3J 20J 0.2J 12 0.9J 8J 0.5J 5J 2J 16B TB-1a deep 15-Oct-13 2.2J 20J 0.1J 6J 1J 6J 5J 4J 3J 9JB TB-1a deep 15-Apr-14 2.1J 20J 0.1J 7J 0.8J 5J 0.4J 3J 8J 17B TB-1a deep 11-Nov-14 2.9J 30J 0.1J 7J 1J 5J 0.5J 4J 18 TB-1a deep 28-Apr-15 2.4J 30J 0.1J 7J 0.8J 4J 0.4J 5J 2J 12 TB-1a deep 14-Oct-15 10J 4J 0.04J 1J TB-1a deep 20-Apr-16 0.4J 20J 4J 0.7J 2J 0.2J 3J 6J TB-1a deep 13-Sep-16 0.66J 22J 0.070J 3.1J 0.46J 1.7JB 0.26J 3.2J 6.4J 12 TB-1a deep 19-Apr-17 0.74J 25J 3.2J 3.0J 3.3J 3.9J 13 TB-1a deep 22-Sep-17 0.76J 15J 3.4J 3.4J 6.8J MW-33 16-Mar-11 66.9J 21.1 5.46J 14.9 4.04J 7.61J 0.298J 29 45.9 MW-33 25-Apr-12 112 0.208J 44.4 15.1 37 6.44J 20.2J 0.917J 72.1 102 MW-33 17-Apr-13 70J 0.3J 17 5J 13 2J 7J 34 33 MW-33 15-Apr-14 40J 5J 0.6J 1J 2J 8J 9JB MW-33 29-Apr-15 50J 0.07J 7J 1J 3J 0.4J 3J 8J 15 MW-33 21-Apr-16 0.5J 100J 0.1J 17 4J 12 2J 7J 21J 35 MW-33 20-Apr-17 29J 5.1J 1.5J 5.9J 7.4J MW-34 17-Mar-11 238 2.19 37.2 8.32J 46.3 13.7 24.9J 2.47J 0.254J 72 94.5 MW-34 26-Apr-12 0.261J 184 1.27 25.4 4.77J 23.8B 8.3J 0.255 13.2J 37.4 53.7 MW-34 17-Apr-13 560 5 0.3J 75 17 90 21 0.45 49J 0.3J 239 282 MW-34 15-Apr-14 110 0.3J 0.2J 3J 1J 0.8J 0.25 2J 3J 16B MW-34 29-Apr-15 220 1.5 0.2J 24 5J 24 5J 0.33 15J 0.1J 47 76 MW-34 21-Apr-16 150 0.5J 9J 2J 5J 0.8J 0.17J 5J 0.08JB 2J 32 MW-34 20-Apr-17 84J 0.29J 4.4J 1.4J 0.25 2.0J 1.5J 13 Not Sampled(4) Page 6 of 12 October 2017 Table 1a Detected Groundwater Constituents - Metals September 2017 Semi-Annual Sampling Event North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984 Monitoring Well CodeSample DateAntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperLeadMercuryNickelSeleniumSilverThalliumVanadiumZincNorth Carolina 2L or Groundwater Protection Standard 1*10 700 4*2 10 1*1,000 15 1 100 20 20 0.2*0.3*1,000 6 10 100 1 1 10 10 10 10 0.2 50 10 10 5.5 25 10Solid Waste Section Limit MW-34d 16-Mar-11 0.351J 33.2J 9.87J 8.59J 2.06J 0.946J 0.209J 1.83J 11.2 MW-34d 25-Apr-12 0.575J 32.5J 8.02J 5.86JB 2.66J 1.57J 7.83J MW-34d 16-Apr-13 0.6J 20J 0.1J 0.3J 4J 0.1J 1JB 0.6J 0.7J 2JB MW-34d 15-Apr-14 0.4J 0.5J 20J 0.1J 0.2J 4J 0.09J 2J 0.5J 4J 11B MW-34d 28-Apr-15 0.8J 20J 0.1J 0.3J 5J 0.08J 1J 0.5J 0.05J 0.5J 6J MW-34d 21-Apr-16 180 0.8J 0.1J 15 3J 12 2J 0.19J 8J 1J 0.1JB 12J 35 MW-34d 20-Apr-17 20J 0.14J 6.4J 0.073J 2.0J 3.0J MW-35 17-Mar-11 52.9J 0.536J 5.36J 2.04J 7.03J 2.33J 3.08J 0.192J 10.2J 23.2 MW-35 25-Apr-12 51.3J 0.616J 3.96J 2.36J 5.67J 3.10J 11.3J 17.8 MW-35 17-Apr-13 60J 0.8J 0.1J 5J 2J 7J 2J 4J 16J 12B MW-35 16-Apr-14 60J 1.0J 0.3J 6J 3J 8J 2J 4J 22J 26B MW-35 29-Apr-15 70J 1.0 0.1J 7J 4J 9J 2J 0.02J 5J 0.06J 22J 20 MW-35 20-Apr-16 50J 0.7J 4J 2J 5J 1J 3J 11J 12 MW-35 20-Apr-17 38J 0.39J 2.3J 6.5J 2.4J 5.0J 3.7J 3.9J 66 MW-36 17-Mar-11 69.7J 10.4 2.66J 9.6J 2.28J 4.16J 0.962J 0.282J 10.7JB 13.8 MW-36 1-Nov-11 74.6J 12.1 3.63J 14.7B 7.15JB 14.8J 31.8 MW-36 25-Apr-12 64.7J 7.90J 2.61J 9.44J 4.33J 12.5J 12.1 MW-36 23-Oct-12 216 68.8 18.8 84 8.62J 29.3J 0.420J 91.7 72 MW-36 (dup)23-Oct-12 73.7J 11.6 3.49J 13.4 6.09J 0.121J 16.8J 18.4 MW-36 17-Apr-13 50J 0.1J 6J 2J 6J 0.5J 4J 8J 12B MW-36 16-Oct-13 0.6J 60J 0.2J 7J 2J 8J 0.6J 4J 0.05J 10J 4JB MW-36 16-Apr-14 90J 0.3J 19 5J 23 2J 9J 0.1J 33 32B MW-36 12-Nov-14 130 0.6J 32 9J 39 3J 15J 0.3J 40 46 MW-36 30-Apr-15 0.6J 100J 0.3J 24 7J 27 2J 0.02J 11J 0.2J 29 27 MW-36 15-Oct-15 130 0.7J 38 10 46 3J 0.05J 16J 0.3J 37 41 MW-36 20-Apr-16 70J 0.3J 13 3J 15 1J 6J 0.1J 11J 17 MW-36 13-Sep-16 62J 0.24J 0.047J 11 3.0J 10B 0.88J 5.3J 0.088J 14J 16 MW-36 20-Apr-17 40J 2.8J 2.9J 1.8J 4.4J 11 MW-36 22-Sep-17 70J 0.32J 16 3.3J 18 1.3J 6.6J 20J 16 MW-36 (dissolved)22-Sep-17 NA NA NA NA NA NA NA NA NA NA NA NA 4.9J NA MW-36d 18-Mar-11 98.4J 32.3 2J 32.5 4.8J 15.5J 1.73J 29.3 17.8 MW-36d (dup)18-Mar-11 88.4J 27.1 1.35J 27.3 2.51J 12.7 0.845J 24.5J 14.2 MW-36d 2-Nov-11 60.3J 10.2 12.0B 6.22J 11.1J 5.45J MW-36d 26-Apr-12 53.7J 2.26J 10.5B 2.44J 2.23J 2.20J 4.59J MW-36d 24-Oct-12 77.7J 18.4 1.59J 31.1 8.03J 19.8J 12.7 MW-36d 18-Apr-13 0.3J 80J 0.1J 12 2J 33 1J 0.02J 6J 0.08J 13J 7JB MW-36d 17-Oct-13 60J 0.04J 3J 0.5J 10J 0.03J 3J 3J MW-36d 17-Apr-14 0.4J 0.6J 70J 0.08J 0.2J 14 1J 50 0.9J 0.03J 8J 0.07J 30 14B MW-36d 13-Nov-14 60J 0.05J 5J 0.9J 13 0.4J 4J 7J 5J MW-36d 29-Apr-15 60J 0.1J 3J 0.4J 15 0.3J 0.03J 3J 6J 4J MW-36d 15-Oct-15 0.2J 70J 0.07J 0.2J 9J 1J 24 0.7J 0.05J 5J 0.06J 18JB 11 MW-36d 20-Apr-16 0.5J 50J 5J 0.3J 10 0.2J 2J 33 MW-36d 14-Sep-16 52J 0.26J 2.3J 10B 4.1J 25 11B MW-36d 20-Apr-17 52J 4.8J 2.2J 3.6J 3.9J MW-36d 21-Sep-17 43J 2.4J 6.9J 1.9J 4.1J 8.6J Notes: 1. All units are in micrograms per liter (parts per billion). 2. * - Groundwater Protection Standard 3. dup - Duplicate Sample 4. (4) - Monitoring wells MW-22, -30, -31, and TB-1a were not sampled during the September 2017 sampling event due to insufficient volumes of water in the wells. 5. J - Indicates the analytical result is an estimated concentration between the method detection limit and the Solid Waste Section Reporting Limit. 6. B - The analyte concentration detected in the method blank was greater than the method detection limit. 7. Monitoring wells MW-28, -28d, -33, -34, -34d, and -35 are sampled yearly during the spring event. 8. Dissolved metal samples were collected to evaluate the influence of turbidity on total metal concentrations as part of an ongoing Alternate Source Demonstration. 9. NA - Not Analyzed - Concentration exceeds the 15A NCAC 02L .0202 or Groundwater Protection Standard. - Indicates the result is below the detection limit. Page 7 of 12 October 2017 Table 1b Detected Groundwater Constituents - Volatile and Semi-Volatile Organic Compounds September 2017 Semi-Annual Sampling Event North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984 Monitoring Well CodeSample DateAcetoneBenzeneBromomethaneChlorobenzeneChloroethaneChloroformChloromethaneDibromochloromethane1,4-Dichlorobenzene1,3-Dichlorobenzene1,2-DichlorobenzeneDichlorodifluoromethane1,1-Dichloroethane1,2-Dichloroethane1,1-Dichloroethenecis-1,2-Dichloroethenetrans-1,2-Dichloroethene1,2-DichloropropaneEthylbenzeneMethylene ChlorideTetrachloroetheneTolueneTrichloroetheneTrichlorofluoromethaneVinyl Chloridem,p-Xyleneso-XyleneTotal Xylenesbis(2-ethylhexyl) Phthalate6,000 1 10**50 3,000 70 3 0.4 6 200 20 1,000 6 0.4 7 70 100 0.6 600 5 0.7 600 3 2,000 0.03 500 500 500 3 100 1 10 3 10 5 1 3 1 5 5 5 5 1 5 5 5 1 1 1 1 1 1 1 1 5 5 5 15 MW-11 17-Mar-11 MW-11 1-Nov-11 MW-11 25-Apr-12 MW-11 23-Oct-12 MW-11 17-Apr-13 MW-11 16-Oct-13 MW-11 16-Apr-14 MW-11 12-Nov-14 MW-11 30-Apr-15 0.54J MW-11 15-Oct-15 0.28JB MW-11 21-Apr-16 MW-11 1-Sep-16 MW-11 20-Apr-17 MW-11 22-Sep-17 MW-11d 18-Mar-11 MW-11d 2-Nov-11 MW-11d 26-Apr-12 MW-11d 24-Oct-12 MW-11d 18-Apr-13 MW-11d 17-Oct-13 MW-11d 17-Apr-14 MW-11d 13-Nov-14 MW-11d 29-Apr-15 MW-11d 15-Oct-15 0.24JB MW-11d 21-Apr-16 1.3J 0.71J MW-11d 1-Sep-16 MW-11d 20-Apr-17 MW-11d 22-Sep-17 MW-5R 16-Mar-11 2.1 MW-5R 31-Oct-11 MW-5R 24-Apr-12 MW-5R 22-Oct-12 0.67J MW-5R 17-Apr-13 0.22J MW-5R 16-Oct-13 MW-5R 16-Apr-14 MW-5R 12-Nov-14 MW-5R 30-Apr-15 MW-5R 15-Oct-15 0.49J 0.34JB MW-5R 21-Apr-16 MW-5R 14-Sep-16 MW-5R 20-Apr-17 MW-5R 20-Sep-17 5.0J 2.7 3.4 1.1J 15 0.61J 0.72J 4.8 MW-6 16-Mar-11 3.4 1.3J 1.6 0.42J 1.3J 1.8 MW-6 1-Nov-11 3.6 1.1J 1.7 1.0J 0.95J MW-6 24-Apr-12 0.7J 0.5J 0.5J 0.42J 0.56J MW-6 22-Oct-12 4.6J 2.3 1.7J 1.3 2.5J 0.58J 1.4 MW-6 17-Apr-13 0.79J 1.7J 0.43J MW-6 16-Oct-13 0.48J 3.0J 0.60J 0.57J MW-6 (dup)16-Oct-13 8.2J 0.54J 3.0J 0.55J 0.54J MW-6 16-Apr-14 0.52J 0.97J MW-6 (dup)16-Apr-14 0.50J 1.0J MW-6 12-Nov-14 1.1 0.25J 1.2J 1.3 0.80J MW-6 30-Apr-15 0.48J 0.60J 1.2J MW-6 14-Oct-15 0.62J 2.3J 0.50J MW-6 20-Apr-16 0.45J 0.52J 3.0J MW-6 (dup)20-Apr-16 0.38J 0.58J MW-6 14-Sep-16 0.83J 1.5J MW-6 20-Apr-17 0.82J 0.98J MW-6 (dup)20-Apr-17 0.90J 1.2J MW-6 21-Sep-17 0.83J 2.8J 0.61J 0.56J MW-6d 16-Mar-11 0.91J 3.2J 0.49J MW-6d 2-Nov-11 0.72J 1.5J 3.4J 0.43J MW-6d 26-Apr-12 0.61J 0.53J 2.3J 0.40J 0.42J MW-6d (dup)26-Apr-12 0.58J 2.3J 0.43J MW-6d 23-Oct-12 0.77J 1.1J 3.0J 0.54J 0.48J 0.53J 0.52J MW-6d 18-Apr-13 0.52J 2.3J 0.48J 0.3J 0.39J MW-6d (dup)18-Apr-13 0.58J 2.4J 0.47J 0.39J 0.44J 0.36J MW-6d 17-Oct-13 0.75J 1.8J 3.3J 0.65J 0.53J MW-6d 17-Apr-14 0.42J 0.93J 0.28J MW-6d 12-Nov-14 0.51J 1.5J 0.38J MW-6d 30-Apr-15 0.30J 0.50J 0.87J 1.5JB 0.22J MW-6d (dup)30-Apr-15 0.40J 0.83J 1.5JB MW-6d 15-Oct-15 0.35J 0.37J 0.82J 0.25JB MW-6d 20-Apr-16 0.51J 2.0J 0.35JB MW-6d 12-Sep-16 0.41J 1.0J MW-6d 20-Apr-17 0.51J 0.43J 1.5J 0.51J 1.6J MW-6d 22-Sep-17 0.60J 0.71J 1.9J 0.49J MW-7 16-Mar-11 1.8 1.6 0.74J 1.5 MW-7 2-Nov-11 7.6J 1.3 1.6 1.4 MW-7 26-Apr-12 120 0.66J 0.79J 0.49J MW-7 22-Oct-12 15 0.75J 1.4 0.93 MW-7 16-Apr-13 0.66J 0.25J 1.2 1.2J MW-7 16-Oct-13 0.81J 0.40J 1.5 MW-7 16-Apr-14 0.61J 0.52J 1.2 0.31J MW-7 11-Nov-14 0.70J 0.57J 0.56J 1.2 0.32J 0.80J MW-7 30-Apr-15 1.1 0.69J 2.7 2.8J 0.51J 0.59J 1.5JB 0.85J MW-7 14-Oct-15 0.52J 0.69J 1.1 MW-7 20-Apr-16 0.83J 0.52J 2.2 0.46J 1.6J 1.5 MW-7 13-Sep-16 1.0 1.3J 1.6 0.42J 0.41J 0.60J MW-7 18-Apr-17 0.74J 1.1J 1.4 MW-7 18-Sep-17 0.55J 0.94J 0.73J Solid Waste Section Limit North Carolina 2L or Groundwater Protection Standard Page 8 of 12 October 2017 Table 1b Detected Groundwater Constituents - Volatile and Semi-Volatile Organic Compounds September 2017 Semi-Annual Sampling Event North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984 Monitoring Well CodeSample DateAcetoneBenzeneBromomethaneChlorobenzeneChloroethaneChloroformChloromethaneDibromochloromethane1,4-Dichlorobenzene1,3-Dichlorobenzene1,2-DichlorobenzeneDichlorodifluoromethane1,1-Dichloroethane1,2-Dichloroethane1,1-Dichloroethenecis-1,2-Dichloroethenetrans-1,2-Dichloroethene1,2-DichloropropaneEthylbenzeneMethylene ChlorideTetrachloroetheneTolueneTrichloroetheneTrichlorofluoromethaneVinyl Chloridem,p-Xyleneso-XyleneTotal Xylenesbis(2-ethylhexyl) Phthalate6,000 1 10**50 3,000 70 3 0.4 6 200 20 1,000 6 0.4 7 70 100 0.6 600 5 0.7 600 3 2,000 0.03 500 500 500 3 100 1 10 3 10 5 1 3 1 5 5 5 5 1 5 5 5 1 1 1 1 1 1 1 1 5 5 5 15Solid Waste Section Limit North Carolina 2L or Groundwater Protection Standard MW-8 16-Mar-11 0.61J 17 MW-8 31-Oct-11 0.66J 14 MW-8 24-Apr-12 0.75J 23 MW-8 22-Oct-12 0.47J 0.40J 1.1J 25 0.65J 0.41J MW-8 17-Apr-13 0.51J 0.23J 0.53J 0.77J 35 0.32J 0.47J MW-8 16-Oct-13 0.48J 0.17J 0.47J 0.62J 37 MW-8 16-Apr-14 0.47J 0.67J 0.58J 39 0.40J MW-8 12-Nov-14 0.50J 0.18J 0.54J 0.64J 48 0.32J MW-8 30-Apr-15 0.84J 0.35J 1.1 0.94J 98 1.6JB 0.29J 0.64J 0.40J MW-8 15-Oct-15 0.56J 0.27J 1.0 0.55J 64 0.44JB 0.54J MW-8 21-Apr-16 0.70J 0.36J 1.4 0.74J 100 0.25J 0.45J MW-8 14-Sep-16 0.53J 1.2 0.71J 61 0.72J MW-8 20-Apr-17 0.49J 1.2 0.50J 48 0.61J 0.57J MW-8 18-Sep-17 0.54J 1.4 0.44J 46 0.52J MW-8d 18-Mar-11 MW-8d 2-Nov-11 MW-8d 26-Apr-12 0.42J MW-8d 24-Oct-12 0.51J MW-8d 18-Apr-13 0.36J MW-8d 17-Oct-13 0.43J MW-8d 17-Apr-14 MW-8d 12-Nov-14 MW-8d 30-Apr-15 0.38J MW-8d 15-Oct-15 0.44J MW-8d 21-Apr-16 0.60J MW-8d 14-Sep-16 0.48J MW-8d 20-Apr-17 0.50J MW-8d 18-Sep-17 MW-8d (dup)18-Sep-17 MW-9 17-Mar-11 1.1 6 12 0.92J 13 0.61J 14 MW-9 1-Nov-11 1.3 5.9 11 11 12 MW-9 (dup)1-Nov-11 6.1J 1.0 1.3J 5.9 10 12 10 MW-9 25-Apr-12 1.8 8.1 9.8 15 0.68J 0.54J 0.47J 19 MW-9 23-Oct-12 2.0J 3.3J MW-9 17-Apr-13 1.3J 2.1J MW-9 16-Oct-13 2.0J 4.2J MW-9 16-Apr-14 0.37J 0.25J 2.8J 6.4 0.36J MW-9 12-Nov-14 2.3J 0.25J 5.3 MW-9 (dup)12-Nov-14 2.1J 4.6J MW-9 29-Apr-15 2.1J 5.9 MW-9 15-Oct-15 0.42J 2.9J 8.6 0.25J 0.28JB MW-9 20-Apr-16 0.29J 2.5J 0.27J 5.7 1.0 MW-9 13-Sep-16 2.7J 8.6 MW-9 19-Apr-17 2.3J 7.2 MW-9 21-Sep-17 1.8J 6.2 MW-10 17-Mar-11 3.3 1.1 4.2J 48 2.5 2.6 1.6 MW-10 31-Oct-11 3.2 1.4J 0.90J 4.9J 42 2.9 2.6 1.3 MW-10 25-Apr-12 10J 2.3 1 3.2J 44 2.9 2.5 1.4 MW-10 23-Oct-12 3.3 1.8J 1.3 5.3 52 0.41J 2.3 2.6 3.1 MW-10 17-Apr-13 3.2 0.23J 2.3 6.3 0.23J 39 0.21J 0.26J 4.7 6.1 0.18J MW-10 16-Oct-13 1.1 0.17J 2.4 4.0J 23 2.1 3.0 0.76J MW-10 16-Apr-14 1.4 0.68J 2.0 2.9J 24 2.6 2.5 0.16J MW-10 12-Nov-14 1.5 1.0J 2.4 4.6J 0.24J 39 0.27J 10 12 3.9 MW-10 29-Apr-15 2.6 0.29J 2.6 2.4J 29 2.5 3.7 1.5 MW-10 14-Oct-15 1.2 0.36J 4.4 3.4J 0.34J 29 0.21J 3.0 3.3 MW-10 20-Apr-16 2.9 2.4 1.7J 0.31J 18 0.37JB 2.2 3.4 2.0 0.23J MW-10 13-Sep-16 2.9 4.5 2.7J 25 1.6 1.3 MW-10 19-Apr-17 1.5 0.50J 6.7 0.56J 3.5J 0.50J 22 0.56J 4.9 1.9 MW-10 22-Sep-17 0.95J 4.6 2.6J 0.42J 7.1 1.0 3.4 MW-10d 18-Mar-11 2J 1 MW-10d 2-Nov-11 2.2J 0.92J MW-10d 26-Apr-12 0.70J 2.2J 0.6J 0.52J 0.50J MW-10d 24-Oct-12 0.55J 2.3J 0.47J 0.64J 0.67J 0.45J MW-10d 18-Apr-13 2J 0.62J 0.57J 0.64J 0.36J MW-10d 16-Oct-13 1.8J 0.56J 0.57J MW-10d 17-Apr-14 1.8J 0.54J 0.70J 0.42J MW-10d 12-Nov-14 2.0J 0.68J 0.25J 0.24J MW-10d 30-Apr-15 0.56J 0.45J 1.7J 0.56J 1.9JB 0.61J MW-10d 15-Oct-15 0.46J 1.4J 0.45J 0.55JB 0.42J 0.38J MW-10d 21-Apr-16 0.51J 1.4J 0.39J 0.39J MW-10d 14-Sep-16 1.5J 0.49J MW-10d 19-Apr-17 0.59J 1.3J 0.45J 0.47J MW-10d 18-Sep-17 1.1J MW-22 18-Mar-11 0.79J MW-22 1-Nov-11 MW-22 25-Apr-12 MW-22 23-Oct-12 MW-22 17-Apr-13 MW-22 16-Oct-13 MW-22 16-Apr-14 MW-22 12-Nov-14 5.9J MW-22 30-Apr-15 0.43J MW-22 15-Oct-15 MW-22 20-Apr-16 0.80J MW-22 13-Sep-16 MW-22 19-Apr-17 Not sampled(4) Page 9 of 12 October 2017 Table 1b Detected Groundwater Constituents - Volatile and Semi-Volatile Organic Compounds September 2017 Semi-Annual Sampling Event North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984 Monitoring Well CodeSample DateAcetoneBenzeneBromomethaneChlorobenzeneChloroethaneChloroformChloromethaneDibromochloromethane1,4-Dichlorobenzene1,3-Dichlorobenzene1,2-DichlorobenzeneDichlorodifluoromethane1,1-Dichloroethane1,2-Dichloroethane1,1-Dichloroethenecis-1,2-Dichloroethenetrans-1,2-Dichloroethene1,2-DichloropropaneEthylbenzeneMethylene ChlorideTetrachloroetheneTolueneTrichloroetheneTrichlorofluoromethaneVinyl Chloridem,p-Xyleneso-XyleneTotal Xylenesbis(2-ethylhexyl) Phthalate6,000 1 10**50 3,000 70 3 0.4 6 200 20 1,000 6 0.4 7 70 100 0.6 600 5 0.7 600 3 2,000 0.03 500 500 500 3 100 1 10 3 10 5 1 3 1 5 5 5 5 1 5 5 5 1 1 1 1 1 1 1 1 5 5 5 15Solid Waste Section Limit North Carolina 2L or Groundwater Protection Standard MW-23 18-Mar-11 MW-23 2-Nov-11 MW-23 23-Apr-12 MW-23 24-Oct-12 MW-23 18-Apr-13 MW-23 16-Oct-13 MW-23 16-Apr-14 MW-23 12-Nov-14 MW-23 30-Apr-15 MW-23 15-Oct-15 MW-23 (dup)15-Oct-15 MW-23 20-Apr-16 0.72J MW-23 13-Sep-16 MW-23 19-Apr-17 MW-23d 17-Mar-11 MW-23d 1-Nov-11 MW-23d 25-Apr-12 MW-23d 23-Oct-12 MW-23d 18-Apr-13 MW-23d 17-Oct-13 MW-23d 17-Apr-14 MW-23d 13-Nov-14 MW-23d 29-Apr-15 MW-23d 15-Oct-15 MW-23d 20-Apr-16 0.61J MW-23d 13-Sep-16 MW-23d (dup)13-Sep-16 MW-23d 19-Apr-17 0.44J MW-23d 21-Sep-17 3.4J MW-24 18-Mar-11 13 MW-24 2-Nov-11 8.9 MW-24 26-Apr-12 7.3 MW-24 23-Oct-12 8 MW-24 17-Apr-13 8.7 MW-24 16-Oct-13 7.9 MW-24 16-Apr-14 6.2 MW-24 12-Nov-14 5.9 MW-24 29-Apr-15 6.0 MW-24 14-Oct-15 4.9J MW-24 20-Apr-16 4.7J 0.46J MW-24 13-Sep-16 3.8J MW-24 19-Apr-17 4.3J MW-24 20-Sep-17 3.6J MW-28 18-Mar-11 MW-28 26-Apr-12 0.53J MW-28 18-Apr-13 0.58J MW-28 17-Apr-14 0.38J MW-28 30-Apr-15 MW-28 21-Apr-16 MW-28 20-Apr-17 MW-28d 18-Mar-11 MW-28d 26-Apr-12 19J MW-28d 18-Apr-13 MW-28d 17-Apr-14 MW-28d 30-Apr-15 0.29J MW-28d 21-Apr-16 MW-28d 20-Apr-17 MW-29d 18-Mar-11 1.8J MW-29d 1-Nov-11 MW-29d 26-Apr-12 MW-29d 24-Oct-12 MW-29d 18-Apr-13 MW-29d 17-Oct-13 MW-29d 17-Apr-14 28.5 MW-29d 13-Nov-14 0.23J 4.61J MW-29d 29-Apr-15 6.7J MW-29d 15-Oct-15 0.29JB 0.25J MW-29d 21-Apr-16 MW-29d 12-Sep-16 MW-29d 19-Apr-17 MW-29d 22-Sep-17 MW-30 18-Mar-11 MW-30 1-Nov-11 MW-30 25-Apr-12 MW-30 23-Oct-12 MW-30 17-Apr-13 MW-30 16-Oct-13 MW-30 16-Apr-14 MW-30 12-Nov-14 MW-30 29-Apr-15 MW-30 15-Oct-15 MW-30 21-Apr-16 MW-30 14-Sep-16 MW-30 20-Apr-17 MW-30 22-Sep-17 Not sampled(4) Page 10 of 12 October 2017 Table 1b Detected Groundwater Constituents - Volatile and Semi-Volatile Organic Compounds September 2017 Semi-Annual Sampling Event North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984 Monitoring Well CodeSample DateAcetoneBenzeneBromomethaneChlorobenzeneChloroethaneChloroformChloromethaneDibromochloromethane1,4-Dichlorobenzene1,3-Dichlorobenzene1,2-DichlorobenzeneDichlorodifluoromethane1,1-Dichloroethane1,2-Dichloroethane1,1-Dichloroethenecis-1,2-Dichloroethenetrans-1,2-Dichloroethene1,2-DichloropropaneEthylbenzeneMethylene ChlorideTetrachloroetheneTolueneTrichloroetheneTrichlorofluoromethaneVinyl Chloridem,p-Xyleneso-XyleneTotal Xylenesbis(2-ethylhexyl) Phthalate6,000 1 10**50 3,000 70 3 0.4 6 200 20 1,000 6 0.4 7 70 100 0.6 600 5 0.7 600 3 2,000 0.03 500 500 500 3 100 1 10 3 10 5 1 3 1 5 5 5 5 1 5 5 5 1 1 1 1 1 1 1 1 5 5 5 15Solid Waste Section Limit North Carolina 2L or Groundwater Protection Standard MW-31 17-Mar-11 2.5J MW-31 1-Nov-11 2.1J MW-31 25-Apr-12 1.3J MW-31 23-Oct-12 2.0J MW-31 17-Apr-13 1.4J MW-31 16-Oct-13 1.4J MW-31 16-Apr-14 1.6J MW-31 12-Nov-14 1.0J MW-31 29-Apr-15 1.6J MW-31 14-Oct-15 0.82J MW-31 21-Apr-16 2.1J MW-31 13-Sep-16 0.76J MW-31 19-Apr-17 0.41J MW-31 21-Sep-17 MW-31d 16-Mar-11 28 MW-31d 31-Oct-11 23 MW-31d 24-Apr-12 23 MW-31d 22-Oct-12 22 MW-31d 16-Apr-13 21 MW-31d 15-Oct-13 17 MW-31d 15-Apr-14 17 MW-31d 11-Nov-14 17 MW-31d 28-Apr-15 16 MW-31d 13-Oct-15 12 MW-31d 21-Apr-16 13 MW-31d 13-Sep-16 10 MW-31d 19-Apr-17 13 MW-31d 18-Sep-17 12 MW-32 17-Mar-11 MW-32 1-Nov-11 MW-32 25-Apr-12 MW-32 23-Oct-12 MW-32 17-Apr-13 MW-32 16-Oct-13 MW-32 16-Apr-14 MW-32 12-Nov-14 MW-32 29-Apr-15 0.41J MW-32 14-Oct-15 MW-32 21-Apr-16 MW-32 13-Sep-16 MW-32 20-Apr-17 MW-32 22-Sep-17 TB-1a 17-Mar-11 2.5J TB-1a 1-Nov-11 1.6J TB-1a 25-Apr-12 0.9J TB-1a 23-Oct-12 0.74J TB-1a 17-Apr-13 0.70J TB-1a 16-Oct-13 0.35J TB-1a 16-Apr-14 0.45J 0.32J TB-1a 12-Nov-14 0.60J TB-1a 29-Apr-15 1.5J TB-1a 15-Oct-15 0.45J 0.27JB TB-1a 21-Apr-16 TB-1a 14-Sep-16 0.65J TB-1a 20-Apr-17 0.42J TB-1a 22-Sep-17 TB-1a deep 16-Mar-11 31 TB-1a deep 31-Oct-11 31 TB-1a deep 24-Apr-12 23 TB-1a deep 23-Oct-12 22 TB-1a deep 16-Apr-13 20 TB-1a deep 15-Oct-13 16 TB-1a deep 15-Apr-14 13 TB-1a deep 11-Nov-14 10 TB-1a deep 28-Apr-15 8.9 0.42J TB-1a deep 14-Oct-15 4.9J TB-1a deep 20-Apr-16 2.6J 0.41J TB-1a deep 13-Sep-16 2.6J TB-1a deep 19-Apr-17 2.7J 1.4J TB-1a deep 22-Sep-17 1.9J MW-33 16-Mar-11 MW-33 25-Apr-12 MW-33 17-Apr-13 MW-33 15-Apr-14 MW-33 29-Apr-15 MW-33 21-Apr-16 MW-33 20-Apr-17 MW-34 17-Mar-11 0.89J 10 11 11 2.2 3.4 MW-34 26-Apr-12 0.60J 0.62J 0.60J 1.2 1.8J 14 9 7.6 2.2 3.3 0.92J MW-34 17-Apr-13 0.56J 0.60J 0.52J 1.1 1.8J 13 9.1 7.6 2.1 2.6 0.70J 0.19J MW-34 15-Apr-14 0.50J 0.99J 0.41J 1.0 1.4J 14 7.5 4.1J 1.0 2.2 0.59J MW-34 29-Apr-15 0.85J 0.35J 0.51J 0.65J 1.5 1.7J 18 0.34J 10 7.2 1.3 3.0 0.64J 1.7J MW-34 21-Apr-16 0.77J 0.71J 1.9 2.0J 17 0.30J 11 6.4 2.3 1.0J MW-34 20-Apr-17 0.75J 0.65J 1.4 2.6J 13 0.51J 12 9.3 2.4 2.9 1.2 Not sampled(4) Not sampled(4) Page 11 of 12 October 2017 Table 1b Detected Groundwater Constituents - Volatile and Semi-Volatile Organic Compounds September 2017 Semi-Annual Sampling Event North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984 Monitoring Well CodeSample DateAcetoneBenzeneBromomethaneChlorobenzeneChloroethaneChloroformChloromethaneDibromochloromethane1,4-Dichlorobenzene1,3-Dichlorobenzene1,2-DichlorobenzeneDichlorodifluoromethane1,1-Dichloroethane1,2-Dichloroethane1,1-Dichloroethenecis-1,2-Dichloroethenetrans-1,2-Dichloroethene1,2-DichloropropaneEthylbenzeneMethylene ChlorideTetrachloroetheneTolueneTrichloroetheneTrichlorofluoromethaneVinyl Chloridem,p-Xyleneso-XyleneTotal Xylenesbis(2-ethylhexyl) Phthalate6,000 1 10**50 3,000 70 3 0.4 6 200 20 1,000 6 0.4 7 70 100 0.6 600 5 0.7 600 3 2,000 0.03 500 500 500 3 100 1 10 3 10 5 1 3 1 5 5 5 5 1 5 5 5 1 1 1 1 1 1 1 1 5 5 5 15Solid Waste Section Limit North Carolina 2L or Groundwater Protection Standard MW-34d 16-Mar-11 1.7J 1.6J 0.43J MW-34d 25-Apr-12 0.77J 0.93J MW-34d 16-Apr-13 0.83J 1.1J MW-34d 15-Apr-14 0.46J 0.99J 3.4J 2.7J 0.96J 0.58J 0.76J 0.75J MW-34d 28-Apr-15 0.27J 0.42J 0.65J 0.70J 3.1J 2.3J 2.1J 0.54J 0.67J 0.38J MW-34d 21-Apr-16 0.79J 0.66J 2.0 2.1J 17 0.33J 10 6.1 2.3 1.1 MW-34d 20-Apr-17 0.49J 1.0J 3.1J 2.9J 0.78J 0.72J 0.85J 0.59J MW-35 17-Mar-11 MW-35 25-Apr-12 MW-35 17-Apr-13 0.53J MW-35 16-Apr-14 0.25J MW-35 29-Apr-15 0.44J 0.62J 0.27J MW-35 20-Apr-16 0.88J 0.39J 0.41J MW-35 20-Apr-17 1.6J 0.62J 0.61J 1.2 MW-36 17-Mar-11 1.1 9.1 6.3 0.47J 1.7 0.8J MW-36 1-Nov-11 0.86J 8.9 4.3J 1.1 MW-36 25-Apr-12 5.5 3.3J 0.74J MW-36 23-Oct-12 5 2.9J 0.66J MW-36 (dup)23-Oct-12 5.4 2.8J 0.67J MW-36 18-Apr-13 0.18J 3.7J 2.3J 0.42J MW-36 16-Oct-13 3.8J 2.5J MW-36 16-Apr-14 3.1J 2.1J 0.26J 0.37J MW-36 12-Nov-14 3.5J 2.5J MW-36 30-Apr-15 0.46J 2.8J 2.3J 0.23J MW-36 15-Oct-15 2.4J 2.1J 0.37JB 0.25J MW-36 20-Apr-16 1.8J 2.1J MW-36 13-Sep-16 4.5J 4.3J MW-36 20-Apr-17 2.4J 2.6J MW-36 22-Sep-17 2.4J 3.1J MW-36d 18-Mar-11 1.4J 8.8 5.2 1 1.0 1.7 MW-36d (dup)18-Mar-11 1.2J 8.9 5.1 1.1 1.1 1.7 MW-36d 2-Nov-11 1.4J 9.2 4.0J 0.89J 1.0 1.4 MW-36d 26-Apr-12 0.53J 1.4J 8 4.0J 0.86J 1.3 MW-36d 24-Oct-12 0.45J 0.56J 1.3J 7.6 3.8J 0.58J 0.68J 1.3 MW-36d 18-Apr-13 0.25J 7.1 4.0J 0.54J 0.73J 1 MW-36d 17-Oct-13 0.26J 0.63J 1.7J 7.9 5.5 0.63J 1.1 MW-36d 17-Apr-14 5.7 4.6J 0.68J 0.87J MW-36d 13-Nov-14 0.54J 0.44J 0.66J 0.53J 6.4 5.5 0.72J 7.9 10 MW-36d 29-Apr-15 0.75J 0.54J 6.7 6.5 2.1J 0.64J 0.87J MW-36d 15-Oct-15 0.37J 4.8J 4.7J 0.62J 0.33J 0.68J MW-36d 20-Apr-16 0.67J 3.9J 0.25J 4.9J 0.56JB 0.40J MW-36d 14-Sep-16 0.69J 5.5 5.8 0.54J 0.50J 0.63J MW-36d 20-Apr-17 0.62J 5.4 5.9 0.43J 0.59J 0.63J MW-36d 21-Sep-17 1.2J 1.3J Notes: 1. All units are in micrograms per liter (parts per billion). 2. ** Groundwater Protection Standard 3. NS - Not Sampled; NE - Standard Not Established; dup - Duplicate Sample 4. (4) - Monitoring wells MW-22, -30, -31, and TB-1a were not sampled during the September 2017 sampling event due to insufficient volumes of water in the wells. 5. J - Indicates the analytical result is an estimated concentration between the method detection limit and the Solid Waste Section Reporting Limit. 6. B - The analyte concentration detected in the method blank was greater than the method detection limit. 7. Monitoring wells MW-28, -28d, -33, -34, -34d, and -35 are sampled yearly during the spring event. - Concentration exceeds the 15A NCAC 02L .0202 or Groundwater Protection Standard - Indicates the result is below the detection limits. Page 12 of 12 October 2017