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HomeMy WebLinkAbout6002_Mecklenburg_HolbrooksRoad_GW_FID1087985_20180307#=CL# March 16, 2018 LIMS USE: FR - AMBER GRZYMSKI LIMS OBJECT ID: 92376030 92376030 Project: Pace Project No.: RE: Amber Grzymski Mecklenburg County Solid Waste 2145 Suttle Avenue Charlotte, NC 28208 Holbrooks Rd. Landfill P#60-02 Dear Amber Grzymski: Enclosed are the analytical results for sample(s) received by the laboratory on March 07, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com Project Manager (704)875-9092 Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 39 #=CP# CERTIFICATIONS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Minnesota Certification IDs 1700 Elm Street SE, Suite 200, Minneapolis, MN 55414- 2485 A2LA Certification #: 2926.01 Alabama Certification #: 40770 Alaska Contaminated Sites Certification #: 17-009 Alaska DW Certification #: MN00064 Arizona Certification #: AZ0014 Arkansas Certification #: 88-0680 California Certification #: 2929 CNMI Saipan Certification #:MP0003 Colorado Certification #: MN00064 Connecticut Certification #: PH-0256 EPA Region 8+Wyoming DW Certification #: via MN 027- 053-137 Florida Certification #: E87605 Georgia Certification #: 959 Guam EPA Certification #: MN00064 Hawaii Certification #: MN00064 Idaho Certification #: MN00064 Illinois Certification #: 200011 Indiana Certification #: C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky DW Certification #: 90062 Kentucky WW Certification #: 90062 Louisiana DEQ Certification #: 03086 Louisiana DW Certification #: MN00064 Maine Certification #: MN00064 Maryland Certification #: 322 Massachusetts Certification #: M-MN064 Michigan Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: MN00064 Montana Certification #: CERT0092 Nebraska Certification #: NE-OS-18-06 Nevada Certification #: MN00064 New Hampshire Certification #: 2081 New Jersey Certification #: MN002 New York Certification #: 11647 North Carolina DW Certification #: 27700 North Carolina WW Certification #: 530 North Dakota Certification #: R-036 Ohio DW Certification #: 41244 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon NwTPH Certification #: MN300001 Oregon Secondary Certification #: MN200001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification #: MN00064 South Carolina Certification #:74003001 Tennessee Certification #: TN02818 Texas Certification #: T104704192 Utah Certification #: MN00064 Virginia Certification #: 460163 Washington Certification #: C486 West Virginia DW Certification #: 9952 C West Virginia DEP Certification #: 382 Wisconsin Certification #: 999407970 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 39 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92376030001 6002-HRW7 EPA 6010 15 PASI-ASH1 EPA 6020B 1 PASI-MTT3 EPA 8260 52 PASI-CSWB 92376030002 6002-HRW18 EPA 6010 15 PASI-ASH1 EPA 6020B 1 PASI-MTT3 EPA 8260 52 PASI-CSWB 92376030003 6002-HRW19 EPA 6010 15 PASI-ASH1 EPA 6020B 1 PASI-MTT3 EPA 8260 52 PASI-CSWB 92376030004 6002-HRW20 EPA 6010 15 PASI-ASH1 EPA 6020B 1 PASI-MTT3 EPA 8260 52 PASI-CSWB 92376030005 6002-HRW21 EPA 6010 15 PASI-ASH1 EPA 6020B 1 PASI-MTT3 EPA 8260 52 PASI-CSWB 92376030006 6002-HRW10 EPA 6010 15 PASI-ASH1 EPA 6020B 1 PASI-MTT3 EPA 8260 52 PASI-CSWB 92376030007 6002-HRW11R EPA 6010 15 PASI-ASH1 EPA 6020B 1 PASI-MTT3 EPA 8260 52 PASI-CSWB 92376030008 6002-HRW13 EPA 6010 15 PASI-ASH1 EPA 6020B 1 PASI-MTT3 EPA 8260 52 PASI-CSWB 92376030009 Trip Blank EPA 8260 52 PASI-CSWB REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Sample:6002-HRW7 Lab ID:92376030001 Collected:03/07/18 11:32 Received:03/07/18 14:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 03/14/18 21:39 7440-36-003/08/18 05:355.0 1 Arsenic ND ug/L 03/14/18 21:39 7440-38-203/08/18 05:3510.0 1 Barium 101 ug/L 03/14/18 21:39 7440-39-303/08/18 05:355.0 1 Beryllium ND ug/L 03/14/18 21:39 7440-41-703/08/18 05:351.0 1 Cadmium 19.4 ug/L 03/14/18 21:39 7440-43-903/08/18 05:351.0 1 Chromium ND ug/L 03/14/18 21:39 7440-47-303/08/18 05:355.0 1 Cobalt ND ug/L 03/14/18 21:39 7440-48-403/08/18 05:355.0 1 Copper 16.5 ug/L 03/14/18 21:39 7440-50-803/08/18 05:355.0 1 Lead ND ug/L 03/14/18 21:39 7439-92-103/08/18 05:355.0 1 Nickel 5.8 ug/L 03/14/18 21:39 7440-02-003/08/18 05:355.0 1 Selenium ND ug/L 03/14/18 21:39 7782-49-203/08/18 05:3510.0 1 Silver ND ug/L 03/14/18 21:39 7440-22-403/08/18 05:355.0 1 Thallium ND ug/L 03/14/18 21:39 7440-28-003/08/18 05:3510.0 1 Vanadium 9.1 ug/L 03/14/18 21:39 7440-62-203/08/18 05:355.0 1 Zinc 101 ug/L 03/14/18 21:39 7440-66-603/08/18 05:3510.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 30206020B MET ICPMS Thallium ND ug/L 03/15/18 13:35 7440-28-003/14/18 10:250.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 03/10/18 19:35 67-64-125.0 1 Acrylonitrile ND ug/L 03/10/18 19:35 107-13-110.0 1 Benzene ND ug/L 03/10/18 19:35 71-43-21.0 1 Bromochloromethane ND ug/L 03/10/18 19:35 74-97-51.0 1 Bromodichloromethane ND ug/L 03/10/18 19:35 75-27-41.0 1 Bromoform ND ug/L 03/10/18 19:35 75-25-21.0 1 Bromomethane ND ug/L 03/10/18 19:35 74-83-92.0 1 2-Butanone (MEK)ND ug/L 03/10/18 19:35 78-93-35.0 1 Carbon disulfide ND ug/L 03/10/18 19:35 75-15-02.0 1 Carbon tetrachloride ND ug/L 03/10/18 19:35 56-23-51.0 1 Chlorobenzene ND ug/L 03/10/18 19:35 108-90-71.0 1 Chloroethane ND ug/L 03/10/18 19:35 75-00-31.0 1 Chloroform ND ug/L 03/10/18 19:35 67-66-31.0 1 Chloromethane ND ug/L 03/10/18 19:35 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 03/10/18 19:35 96-12-82.0 1 Dibromochloromethane ND ug/L 03/10/18 19:35 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 03/10/18 19:35 106-93-41.0 1 Dibromomethane ND ug/L 03/10/18 19:35 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 03/10/18 19:35 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 03/10/18 19:35 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 03/10/18 19:35 110-57-61.0 1 1,1-Dichloroethane ND ug/L 03/10/18 19:35 75-34-31.0 1 1,2-Dichloroethane ND ug/L 03/10/18 19:35 107-06-21.0 1 1,1-Dichloroethene ND ug/L 03/10/18 19:35 75-35-41.0 1 cis-1,2-Dichloroethene 2.6 ug/L 03/10/18 19:35 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 03/10/18 19:35 156-60-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Sample:6002-HRW7 Lab ID:92376030001 Collected:03/07/18 11:32 Received:03/07/18 14:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 1,2-Dichloropropane ND ug/L 03/10/18 19:35 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 03/10/18 19:35 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 03/10/18 19:35 10061-02-61.0 1 Ethylbenzene ND ug/L 03/10/18 19:35 100-41-41.0 1 2-Hexanone ND ug/L 03/10/18 19:35 591-78-65.0 1 Iodomethane ND ug/L 03/10/18 19:35 74-88-45.0 1 Methylene Chloride ND ug/L 03/10/18 19:35 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 03/10/18 19:35 108-10-15.0 1 Styrene ND ug/L 03/10/18 19:35 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 03/10/18 19:35 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 03/10/18 19:35 79-34-51.0 1 Tetrachloroethene ND ug/L 03/10/18 19:35 127-18-41.0 1 Toluene ND ug/L 03/10/18 19:35 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 03/10/18 19:35 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 03/10/18 19:35 79-00-51.0 1 Trichloroethene 1.1 ug/L 03/10/18 19:35 79-01-61.0 1 Trichlorofluoromethane ND ug/L 03/10/18 19:35 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 03/10/18 19:35 96-18-41.0 1 Vinyl acetate ND ug/L 03/10/18 19:35 108-05-42.0 1 Vinyl chloride ND ug/L 03/10/18 19:35 75-01-41.0 1 Xylene (Total)ND ug/L 03/10/18 19:35 1330-20-71.0 1 m&p-Xylene ND ug/L 03/10/18 19:35 179601-23-12.0 1 o-Xylene ND ug/L 03/10/18 19:35 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)94 %03/10/18 19:35 460-00-470-130 1 1,2-Dichloroethane-d4 (S)93 %03/10/18 19:35 17060-07-070-130 1 Toluene-d8 (S)101 %03/10/18 19:35 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Sample:6002-HRW18 Lab ID:92376030002 Collected:03/07/18 11:09 Received:03/07/18 14:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 03/14/18 21:42 7440-36-003/08/18 05:355.0 1 Arsenic ND ug/L 03/14/18 21:42 7440-38-203/08/18 05:3510.0 1 Barium 277 ug/L 03/14/18 21:42 7440-39-303/08/18 05:355.0 1 Beryllium ND ug/L 03/14/18 21:42 7440-41-703/08/18 05:351.0 1 Cadmium ND ug/L 03/14/18 21:42 7440-43-903/08/18 05:351.0 1 Chromium ND ug/L 03/14/18 21:42 7440-47-303/08/18 05:355.0 1 Cobalt 6.0 ug/L 03/14/18 21:42 7440-48-403/08/18 05:355.0 1 Copper ND ug/L 03/14/18 21:42 7440-50-803/08/18 05:355.0 1 Lead ND ug/L 03/14/18 21:42 7439-92-103/08/18 05:355.0 1 Nickel 9.0 ug/L 03/14/18 21:42 7440-02-003/08/18 05:355.0 1 Selenium ND ug/L 03/14/18 21:42 7782-49-203/08/18 05:3510.0 1 Silver ND ug/L 03/14/18 21:42 7440-22-403/08/18 05:355.0 1 Thallium ND ug/L 03/14/18 21:42 7440-28-003/08/18 05:3510.0 1 Vanadium ND ug/L 03/14/18 21:42 7440-62-203/08/18 05:355.0 1 Zinc ND ug/L 03/14/18 21:42 7440-66-603/08/18 05:3510.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 30206020B MET ICPMS Thallium ND ug/L 03/15/18 13:38 7440-28-003/14/18 10:250.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 03/10/18 19:53 67-64-125.0 1 Acrylonitrile ND ug/L 03/10/18 19:53 107-13-110.0 1 Benzene 10.3 ug/L 03/10/18 19:53 71-43-21.0 1 Bromochloromethane ND ug/L 03/10/18 19:53 74-97-51.0 1 Bromodichloromethane ND ug/L 03/10/18 19:53 75-27-41.0 1 Bromoform ND ug/L 03/10/18 19:53 75-25-21.0 1 Bromomethane ND ug/L 03/10/18 19:53 74-83-92.0 1 2-Butanone (MEK)ND ug/L 03/10/18 19:53 78-93-35.0 1 Carbon disulfide ND ug/L 03/10/18 19:53 75-15-02.0 1 Carbon tetrachloride ND ug/L 03/10/18 19:53 56-23-51.0 1 Chlorobenzene 2.4 ug/L 03/10/18 19:53 108-90-71.0 1 Chloroethane 7.1 ug/L 03/10/18 19:53 75-00-31.0 1 Chloroform ND ug/L 03/10/18 19:53 67-66-31.0 1 Chloromethane ND ug/L 03/10/18 19:53 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 03/10/18 19:53 96-12-82.0 1 Dibromochloromethane ND ug/L 03/10/18 19:53 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 03/10/18 19:53 106-93-41.0 1 Dibromomethane ND ug/L 03/10/18 19:53 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 03/10/18 19:53 95-50-11.0 1 1,4-Dichlorobenzene 8.0 ug/L 03/10/18 19:53 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 03/10/18 19:53 110-57-61.0 1 1,1-Dichloroethane 27.4 ug/L 03/10/18 19:53 75-34-31.0 1 1,2-Dichloroethane 1.4 ug/L 03/10/18 19:53 107-06-21.0 1 1,1-Dichloroethene ND ug/L 03/10/18 19:53 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 03/10/18 19:53 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 03/10/18 19:53 156-60-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Sample:6002-HRW18 Lab ID:92376030002 Collected:03/07/18 11:09 Received:03/07/18 14:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 1,2-Dichloropropane 3.5 ug/L 03/10/18 19:53 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 03/10/18 19:53 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 03/10/18 19:53 10061-02-61.0 1 Ethylbenzene ND ug/L 03/10/18 19:53 100-41-41.0 1 2-Hexanone ND ug/L 03/10/18 19:53 591-78-65.0 1 Iodomethane ND ug/L 03/10/18 19:53 74-88-45.0 1 Methylene Chloride ND ug/L 03/10/18 19:53 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 03/10/18 19:53 108-10-15.0 1 Styrene ND ug/L 03/10/18 19:53 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 03/10/18 19:53 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 03/10/18 19:53 79-34-51.0 1 Tetrachloroethene ND ug/L 03/10/18 19:53 127-18-41.0 1 Toluene ND ug/L 03/10/18 19:53 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 03/10/18 19:53 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 03/10/18 19:53 79-00-51.0 1 Trichloroethene 1.5 ug/L 03/10/18 19:53 79-01-61.0 1 Trichlorofluoromethane ND ug/L 03/10/18 19:53 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 03/10/18 19:53 96-18-41.0 1 Vinyl acetate 2.3 ug/L 03/10/18 19:53 108-05-42.0 1 Vinyl chloride 9.6 ug/L 03/10/18 19:53 75-01-41.0 1 Xylene (Total)ND ug/L 03/10/18 19:53 1330-20-71.0 1 m&p-Xylene ND ug/L 03/10/18 19:53 179601-23-12.0 1 o-Xylene ND ug/L 03/10/18 19:53 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)95 %03/10/18 19:53 460-00-470-130 1 1,2-Dichloroethane-d4 (S)97 %03/10/18 19:53 17060-07-070-130 1 Toluene-d8 (S)99 %03/10/18 19:53 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Sample:6002-HRW19 Lab ID:92376030003 Collected:03/07/18 10:35 Received:03/07/18 14:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 03/14/18 21:44 7440-36-003/08/18 05:355.0 1 Arsenic ND ug/L 03/14/18 21:44 7440-38-203/08/18 05:3510.0 1 Barium 69.8 ug/L 03/14/18 21:44 7440-39-303/08/18 05:355.0 1 Beryllium ND ug/L 03/14/18 21:44 7440-41-703/08/18 05:351.0 1 Cadmium ND ug/L 03/14/18 21:44 7440-43-903/08/18 05:351.0 1 Chromium ND ug/L 03/14/18 21:44 7440-47-303/08/18 05:355.0 1 Cobalt ND ug/L 03/14/18 21:44 7440-48-403/08/18 05:355.0 1 Copper ND ug/L 03/14/18 21:44 7440-50-803/08/18 05:355.0 1 Lead ND ug/L 03/14/18 21:44 7439-92-103/08/18 05:355.0 1 Nickel ND ug/L 03/14/18 21:44 7440-02-003/08/18 05:355.0 1 Selenium ND ug/L 03/14/18 21:44 7782-49-203/08/18 05:3510.0 1 Silver ND ug/L 03/14/18 21:44 7440-22-403/08/18 05:355.0 1 Thallium ND ug/L 03/14/18 21:44 7440-28-003/08/18 05:3510.0 1 Vanadium 6.1 ug/L 03/14/18 21:44 7440-62-203/08/18 05:355.0 1 Zinc ND ug/L 03/14/18 21:44 7440-66-603/08/18 05:3510.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 30206020B MET ICPMS Thallium ND ug/L 03/15/18 13:41 7440-28-003/14/18 10:250.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 03/10/18 20:11 67-64-125.0 1 Acrylonitrile ND ug/L 03/10/18 20:11 107-13-110.0 1 Benzene ND ug/L 03/10/18 20:11 71-43-21.0 1 Bromochloromethane ND ug/L 03/10/18 20:11 74-97-51.0 1 Bromodichloromethane ND ug/L 03/10/18 20:11 75-27-41.0 1 Bromoform ND ug/L 03/10/18 20:11 75-25-21.0 1 Bromomethane ND ug/L 03/10/18 20:11 74-83-92.0 1 2-Butanone (MEK)ND ug/L 03/10/18 20:11 78-93-35.0 1 Carbon disulfide ND ug/L 03/10/18 20:11 75-15-02.0 1 Carbon tetrachloride ND ug/L 03/10/18 20:11 56-23-51.0 1 Chlorobenzene ND ug/L 03/10/18 20:11 108-90-71.0 1 Chloroethane ND ug/L 03/10/18 20:11 75-00-31.0 1 Chloroform ND ug/L 03/10/18 20:11 67-66-31.0 1 Chloromethane ND ug/L 03/10/18 20:11 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 03/10/18 20:11 96-12-82.0 1 Dibromochloromethane ND ug/L 03/10/18 20:11 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 03/10/18 20:11 106-93-41.0 1 Dibromomethane ND ug/L 03/10/18 20:11 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 03/10/18 20:11 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 03/10/18 20:11 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 03/10/18 20:11 110-57-61.0 1 1,1-Dichloroethane ND ug/L 03/10/18 20:11 75-34-31.0 1 1,2-Dichloroethane ND ug/L 03/10/18 20:11 107-06-21.0 1 1,1-Dichloroethene ND ug/L 03/10/18 20:11 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 03/10/18 20:11 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 03/10/18 20:11 156-60-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Sample:6002-HRW19 Lab ID:92376030003 Collected:03/07/18 10:35 Received:03/07/18 14:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 1,2-Dichloropropane ND ug/L 03/10/18 20:11 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 03/10/18 20:11 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 03/10/18 20:11 10061-02-61.0 1 Ethylbenzene ND ug/L 03/10/18 20:11 100-41-41.0 1 2-Hexanone ND ug/L 03/10/18 20:11 591-78-65.0 1 Iodomethane ND ug/L 03/10/18 20:11 74-88-45.0 1 Methylene Chloride ND ug/L 03/10/18 20:11 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 03/10/18 20:11 108-10-15.0 1 Styrene ND ug/L 03/10/18 20:11 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 03/10/18 20:11 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 03/10/18 20:11 79-34-51.0 1 Tetrachloroethene ND ug/L 03/10/18 20:11 127-18-41.0 1 Toluene ND ug/L 03/10/18 20:11 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 03/10/18 20:11 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 03/10/18 20:11 79-00-51.0 1 Trichloroethene ND ug/L 03/10/18 20:11 79-01-61.0 1 Trichlorofluoromethane ND ug/L 03/10/18 20:11 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 03/10/18 20:11 96-18-41.0 1 Vinyl acetate ND ug/L 03/10/18 20:11 108-05-42.0 1 Vinyl chloride ND ug/L 03/10/18 20:11 75-01-41.0 1 Xylene (Total)ND ug/L 03/10/18 20:11 1330-20-71.0 1 m&p-Xylene ND ug/L 03/10/18 20:11 179601-23-12.0 1 o-Xylene ND ug/L 03/10/18 20:11 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)95 %03/10/18 20:11 460-00-470-130 1 1,2-Dichloroethane-d4 (S)91 %03/10/18 20:11 17060-07-070-130 1 Toluene-d8 (S)99 %03/10/18 20:11 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Sample:6002-HRW20 Lab ID:92376030004 Collected:03/07/18 10:54 Received:03/07/18 14:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 03/14/18 21:47 7440-36-003/08/18 05:355.0 1 Arsenic ND ug/L 03/14/18 21:47 7440-38-203/08/18 05:3510.0 1 Barium 92.2 ug/L 03/14/18 21:47 7440-39-303/08/18 05:355.0 1 Beryllium ND ug/L 03/14/18 21:47 7440-41-703/08/18 05:351.0 1 Cadmium ND ug/L 03/14/18 21:47 7440-43-903/08/18 05:351.0 1 Chromium ND ug/L 03/14/18 21:47 7440-47-303/08/18 05:355.0 1 Cobalt ND ug/L 03/14/18 21:47 7440-48-403/08/18 05:355.0 1 Copper ND ug/L 03/14/18 21:47 7440-50-803/08/18 05:355.0 1 Lead ND ug/L 03/14/18 21:47 7439-92-103/08/18 05:355.0 1 Nickel ND ug/L 03/14/18 21:47 7440-02-003/08/18 05:355.0 1 Selenium ND ug/L 03/14/18 21:47 7782-49-203/08/18 05:3510.0 1 Silver ND ug/L 03/14/18 21:47 7440-22-403/08/18 05:355.0 1 Thallium ND ug/L 03/14/18 21:47 7440-28-003/08/18 05:3510.0 1 Vanadium 9.0 ug/L 03/14/18 21:47 7440-62-203/08/18 05:355.0 1 Zinc ND ug/L 03/14/18 21:47 7440-66-603/08/18 05:3510.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 30206020B MET ICPMS Thallium ND ug/L 03/15/18 13:44 7440-28-003/14/18 10:250.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 03/10/18 20:28 67-64-125.0 1 Acrylonitrile ND ug/L 03/10/18 20:28 107-13-110.0 1 Benzene ND ug/L 03/10/18 20:28 71-43-21.0 1 Bromochloromethane ND ug/L 03/10/18 20:28 74-97-51.0 1 Bromodichloromethane ND ug/L 03/10/18 20:28 75-27-41.0 1 Bromoform ND ug/L 03/10/18 20:28 75-25-21.0 1 Bromomethane ND ug/L 03/10/18 20:28 74-83-92.0 1 2-Butanone (MEK)ND ug/L 03/10/18 20:28 78-93-35.0 1 Carbon disulfide ND ug/L 03/10/18 20:28 75-15-02.0 1 Carbon tetrachloride ND ug/L 03/10/18 20:28 56-23-51.0 1 Chlorobenzene ND ug/L 03/10/18 20:28 108-90-71.0 1 Chloroethane ND ug/L 03/10/18 20:28 75-00-31.0 1 Chloroform ND ug/L 03/10/18 20:28 67-66-31.0 1 Chloromethane ND ug/L 03/10/18 20:28 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 03/10/18 20:28 96-12-82.0 1 Dibromochloromethane ND ug/L 03/10/18 20:28 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 03/10/18 20:28 106-93-41.0 1 Dibromomethane ND ug/L 03/10/18 20:28 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 03/10/18 20:28 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 03/10/18 20:28 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 03/10/18 20:28 110-57-61.0 1 1,1-Dichloroethane 5.1 ug/L 03/10/18 20:28 75-34-31.0 1 1,2-Dichloroethane ND ug/L 03/10/18 20:28 107-06-21.0 1 1,1-Dichloroethene ND ug/L 03/10/18 20:28 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 03/10/18 20:28 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 03/10/18 20:28 156-60-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Sample:6002-HRW20 Lab ID:92376030004 Collected:03/07/18 10:54 Received:03/07/18 14:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 1,2-Dichloropropane ND ug/L 03/10/18 20:28 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 03/10/18 20:28 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 03/10/18 20:28 10061-02-61.0 1 Ethylbenzene ND ug/L 03/10/18 20:28 100-41-41.0 1 2-Hexanone ND ug/L 03/10/18 20:28 591-78-65.0 1 Iodomethane ND ug/L 03/10/18 20:28 74-88-45.0 1 Methylene Chloride ND ug/L 03/10/18 20:28 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 03/10/18 20:28 108-10-15.0 1 Styrene ND ug/L 03/10/18 20:28 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 03/10/18 20:28 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 03/10/18 20:28 79-34-51.0 1 Tetrachloroethene ND ug/L 03/10/18 20:28 127-18-41.0 1 Toluene ND ug/L 03/10/18 20:28 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 03/10/18 20:28 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 03/10/18 20:28 79-00-51.0 1 Trichloroethene ND ug/L 03/10/18 20:28 79-01-61.0 1 Trichlorofluoromethane ND ug/L 03/10/18 20:28 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 03/10/18 20:28 96-18-41.0 1 Vinyl acetate ND ug/L 03/10/18 20:28 108-05-42.0 1 Vinyl chloride ND ug/L 03/10/18 20:28 75-01-41.0 1 Xylene (Total)ND ug/L 03/10/18 20:28 1330-20-71.0 1 m&p-Xylene ND ug/L 03/10/18 20:28 179601-23-12.0 1 o-Xylene ND ug/L 03/10/18 20:28 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)95 %03/10/18 20:28 460-00-470-130 1 1,2-Dichloroethane-d4 (S)93 %03/10/18 20:28 17060-07-070-130 1 Toluene-d8 (S)99 %03/10/18 20:28 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Sample:6002-HRW21 Lab ID:92376030005 Collected:03/07/18 10:00 Received:03/07/18 14:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 03/14/18 21:56 7440-36-003/08/18 05:355.0 1 Arsenic ND ug/L 03/14/18 21:56 7440-38-203/08/18 05:3510.0 1 Barium 61.9 ug/L 03/14/18 21:56 7440-39-303/08/18 05:355.0 1 Beryllium ND ug/L 03/14/18 21:56 7440-41-703/08/18 05:351.0 1 Cadmium ND ug/L 03/14/18 21:56 7440-43-903/08/18 05:351.0 1 Chromium ND ug/L 03/14/18 21:56 7440-47-303/08/18 05:355.0 1 Cobalt ND ug/L 03/14/18 21:56 7440-48-403/08/18 05:355.0 1 Copper ND ug/L 03/14/18 21:56 7440-50-803/08/18 05:355.0 1 Lead ND ug/L 03/14/18 21:56 7439-92-103/08/18 05:355.0 1 Nickel ND ug/L 03/14/18 21:56 7440-02-003/08/18 05:355.0 1 Selenium ND ug/L 03/14/18 21:56 7782-49-203/08/18 05:3510.0 1 Silver ND ug/L 03/14/18 21:56 7440-22-403/08/18 05:355.0 1 Thallium ND ug/L 03/14/18 21:56 7440-28-003/08/18 05:3510.0 1 Vanadium 7.1 ug/L 03/14/18 21:56 7440-62-203/08/18 05:355.0 1 Zinc ND ug/L 03/14/18 21:56 7440-66-603/08/18 05:3510.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 30206020B MET ICPMS Thallium ND ug/L 03/15/18 14:04 7440-28-003/14/18 10:250.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 03/10/18 20:46 67-64-125.0 1 Acrylonitrile ND ug/L 03/10/18 20:46 107-13-110.0 1 Benzene ND ug/L 03/10/18 20:46 71-43-21.0 1 Bromochloromethane ND ug/L 03/10/18 20:46 74-97-51.0 1 Bromodichloromethane ND ug/L 03/10/18 20:46 75-27-41.0 1 Bromoform ND ug/L 03/10/18 20:46 75-25-21.0 1 Bromomethane ND ug/L 03/10/18 20:46 74-83-92.0 1 2-Butanone (MEK)ND ug/L 03/10/18 20:46 78-93-35.0 1 Carbon disulfide ND ug/L 03/10/18 20:46 75-15-02.0 1 Carbon tetrachloride ND ug/L 03/10/18 20:46 56-23-51.0 1 Chlorobenzene ND ug/L 03/10/18 20:46 108-90-71.0 1 Chloroethane ND ug/L 03/10/18 20:46 75-00-31.0 1 Chloroform ND ug/L 03/10/18 20:46 67-66-31.0 1 Chloromethane ND ug/L 03/10/18 20:46 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 03/10/18 20:46 96-12-82.0 1 Dibromochloromethane ND ug/L 03/10/18 20:46 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 03/10/18 20:46 106-93-41.0 1 Dibromomethane ND ug/L 03/10/18 20:46 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 03/10/18 20:46 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 03/10/18 20:46 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 03/10/18 20:46 110-57-61.0 1 1,1-Dichloroethane ND ug/L 03/10/18 20:46 75-34-31.0 1 1,2-Dichloroethane ND ug/L 03/10/18 20:46 107-06-21.0 1 1,1-Dichloroethene ND ug/L 03/10/18 20:46 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 03/10/18 20:46 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 03/10/18 20:46 156-60-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Sample:6002-HRW21 Lab ID:92376030005 Collected:03/07/18 10:00 Received:03/07/18 14:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 1,2-Dichloropropane ND ug/L 03/10/18 20:46 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 03/10/18 20:46 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 03/10/18 20:46 10061-02-61.0 1 Ethylbenzene ND ug/L 03/10/18 20:46 100-41-41.0 1 2-Hexanone ND ug/L 03/10/18 20:46 591-78-65.0 1 Iodomethane ND ug/L 03/10/18 20:46 74-88-45.0 1 Methylene Chloride ND ug/L 03/10/18 20:46 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 03/10/18 20:46 108-10-15.0 1 Styrene ND ug/L 03/10/18 20:46 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 03/10/18 20:46 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 03/10/18 20:46 79-34-51.0 1 Tetrachloroethene ND ug/L 03/10/18 20:46 127-18-41.0 1 Toluene ND ug/L 03/10/18 20:46 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 03/10/18 20:46 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 03/10/18 20:46 79-00-51.0 1 Trichloroethene ND ug/L 03/10/18 20:46 79-01-61.0 1 Trichlorofluoromethane ND ug/L 03/10/18 20:46 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 03/10/18 20:46 96-18-41.0 1 Vinyl acetate ND ug/L 03/10/18 20:46 108-05-42.0 1 Vinyl chloride ND ug/L 03/10/18 20:46 75-01-41.0 1 Xylene (Total)ND ug/L 03/10/18 20:46 1330-20-71.0 1 m&p-Xylene ND ug/L 03/10/18 20:46 179601-23-12.0 1 o-Xylene ND ug/L 03/10/18 20:46 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)95 %03/10/18 20:46 460-00-470-130 1 1,2-Dichloroethane-d4 (S)93 %03/10/18 20:46 17060-07-070-130 1 Toluene-d8 (S)98 %03/10/18 20:46 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Sample:6002-HRW10 Lab ID:92376030006 Collected:03/07/18 14:05 Received:03/07/18 14:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 03/14/18 21:59 7440-36-003/08/18 05:355.0 1 Arsenic ND ug/L 03/14/18 21:59 7440-38-203/08/18 05:3510.0 1 Barium 132 ug/L 03/14/18 21:59 7440-39-303/08/18 05:355.0 1 Beryllium ND ug/L 03/14/18 21:59 7440-41-703/08/18 05:351.0 1 Cadmium ND ug/L 03/14/18 21:59 7440-43-903/08/18 05:351.0 1 Chromium ND ug/L 03/14/18 21:59 7440-47-303/08/18 05:355.0 1 Cobalt ND ug/L 03/14/18 21:59 7440-48-403/08/18 05:355.0 1 Copper 7.5 ug/L 03/14/18 21:59 7440-50-803/08/18 05:355.0 1 Lead ND ug/L 03/14/18 21:59 7439-92-103/08/18 05:355.0 1 Nickel 12.1 ug/L 03/14/18 21:59 7440-02-003/08/18 05:355.0 1 Selenium ND ug/L 03/14/18 21:59 7782-49-203/08/18 05:3510.0 1 Silver ND ug/L 03/14/18 21:59 7440-22-403/08/18 05:355.0 1 Thallium ND ug/L 03/14/18 21:59 7440-28-003/08/18 05:3510.0 1 Vanadium 9.0 ug/L 03/14/18 21:59 7440-62-203/08/18 05:355.0 1 Zinc ND ug/L 03/14/18 21:59 7440-66-603/08/18 05:3510.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 30206020B MET ICPMS Thallium ND ug/L 03/15/18 14:07 7440-28-003/14/18 10:250.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 03/10/18 21:04 67-64-125.0 1 Acrylonitrile ND ug/L 03/10/18 21:04 107-13-110.0 1 Benzene ND ug/L 03/10/18 21:04 71-43-21.0 1 Bromochloromethane ND ug/L 03/10/18 21:04 74-97-51.0 1 Bromodichloromethane ND ug/L 03/10/18 21:04 75-27-41.0 1 Bromoform ND ug/L 03/10/18 21:04 75-25-21.0 1 Bromomethane ND ug/L 03/10/18 21:04 74-83-92.0 1 2-Butanone (MEK)ND ug/L 03/10/18 21:04 78-93-35.0 1 Carbon disulfide ND ug/L 03/10/18 21:04 75-15-02.0 1 Carbon tetrachloride ND ug/L 03/10/18 21:04 56-23-51.0 1 Chlorobenzene ND ug/L 03/10/18 21:04 108-90-71.0 1 Chloroethane ND ug/L 03/10/18 21:04 75-00-31.0 1 Chloroform ND ug/L 03/10/18 21:04 67-66-31.0 1 Chloromethane ND ug/L 03/10/18 21:04 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 03/10/18 21:04 96-12-82.0 1 Dibromochloromethane ND ug/L 03/10/18 21:04 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 03/10/18 21:04 106-93-41.0 1 Dibromomethane ND ug/L 03/10/18 21:04 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 03/10/18 21:04 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 03/10/18 21:04 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 03/10/18 21:04 110-57-61.0 1 1,1-Dichloroethane ND ug/L 03/10/18 21:04 75-34-31.0 1 1,2-Dichloroethane ND ug/L 03/10/18 21:04 107-06-21.0 1 1,1-Dichloroethene ND ug/L 03/10/18 21:04 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 03/10/18 21:04 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 03/10/18 21:04 156-60-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Sample:6002-HRW10 Lab ID:92376030006 Collected:03/07/18 14:05 Received:03/07/18 14:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 1,2-Dichloropropane ND ug/L 03/10/18 21:04 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 03/10/18 21:04 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 03/10/18 21:04 10061-02-61.0 1 Ethylbenzene ND ug/L 03/10/18 21:04 100-41-41.0 1 2-Hexanone ND ug/L 03/10/18 21:04 591-78-65.0 1 Iodomethane ND ug/L 03/10/18 21:04 74-88-45.0 1 Methylene Chloride ND ug/L 03/10/18 21:04 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 03/10/18 21:04 108-10-15.0 1 Styrene ND ug/L 03/10/18 21:04 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 03/10/18 21:04 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 03/10/18 21:04 79-34-51.0 1 Tetrachloroethene ND ug/L 03/10/18 21:04 127-18-41.0 1 Toluene ND ug/L 03/10/18 21:04 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 03/10/18 21:04 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 03/10/18 21:04 79-00-51.0 1 Trichloroethene ND ug/L 03/10/18 21:04 79-01-61.0 1 Trichlorofluoromethane ND ug/L 03/10/18 21:04 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 03/10/18 21:04 96-18-41.0 1 Vinyl acetate ND ug/L 03/10/18 21:04 108-05-42.0 1 Vinyl chloride ND ug/L 03/10/18 21:04 75-01-41.0 1 Xylene (Total)ND ug/L 03/10/18 21:04 1330-20-71.0 1 m&p-Xylene ND ug/L 03/10/18 21:04 179601-23-12.0 1 o-Xylene ND ug/L 03/10/18 21:04 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)96 %03/10/18 21:04 460-00-470-130 1 1,2-Dichloroethane-d4 (S)95 %03/10/18 21:04 17060-07-070-130 1 Toluene-d8 (S)97 %03/10/18 21:04 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Sample:6002-HRW11R Lab ID:92376030007 Collected:03/07/18 13:18 Received:03/07/18 14:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 03/14/18 22:02 7440-36-003/08/18 05:355.0 1 Arsenic ND ug/L 03/14/18 22:02 7440-38-203/08/18 05:3510.0 1 Barium 183 ug/L 03/14/18 22:02 7440-39-303/08/18 05:355.0 1 Beryllium ND ug/L 03/14/18 22:02 7440-41-703/08/18 05:351.0 1 Cadmium ND ug/L 03/14/18 22:02 7440-43-903/08/18 05:351.0 1 Chromium ND ug/L 03/14/18 22:02 7440-47-303/08/18 05:355.0 1 Cobalt ND ug/L 03/14/18 22:02 7440-48-403/08/18 05:355.0 1 Copper 5.5 ug/L 03/14/18 22:02 7440-50-803/08/18 05:355.0 1 Lead ND ug/L 03/14/18 22:02 7439-92-103/08/18 05:355.0 1 Nickel 8.9 ug/L 03/14/18 22:02 7440-02-003/08/18 05:355.0 1 Selenium ND ug/L 03/14/18 22:02 7782-49-203/08/18 05:3510.0 1 Silver ND ug/L 03/14/18 22:02 7440-22-403/08/18 05:355.0 1 Thallium ND ug/L 03/14/18 22:02 7440-28-003/08/18 05:3510.0 1 Vanadium 8.0 ug/L 03/14/18 22:02 7440-62-203/08/18 05:355.0 1 Zinc ND ug/L 03/14/18 22:02 7440-66-603/08/18 05:3510.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 30206020B MET ICPMS Thallium ND ug/L 03/15/18 14:10 7440-28-003/14/18 10:250.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 03/10/18 21:21 67-64-125.0 1 Acrylonitrile ND ug/L 03/10/18 21:21 107-13-110.0 1 Benzene ND ug/L 03/10/18 21:21 71-43-21.0 1 Bromochloromethane ND ug/L 03/10/18 21:21 74-97-51.0 1 Bromodichloromethane ND ug/L 03/10/18 21:21 75-27-41.0 1 Bromoform ND ug/L 03/10/18 21:21 75-25-21.0 1 Bromomethane ND ug/L 03/10/18 21:21 74-83-92.0 1 2-Butanone (MEK)ND ug/L 03/10/18 21:21 78-93-35.0 1 Carbon disulfide ND ug/L 03/10/18 21:21 75-15-02.0 1 Carbon tetrachloride ND ug/L 03/10/18 21:21 56-23-51.0 1 Chlorobenzene ND ug/L 03/10/18 21:21 108-90-71.0 1 Chloroethane ND ug/L 03/10/18 21:21 75-00-31.0 1 Chloroform ND ug/L 03/10/18 21:21 67-66-31.0 1 Chloromethane ND ug/L 03/10/18 21:21 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 03/10/18 21:21 96-12-82.0 1 Dibromochloromethane ND ug/L 03/10/18 21:21 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 03/10/18 21:21 106-93-41.0 1 Dibromomethane ND ug/L 03/10/18 21:21 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 03/10/18 21:21 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 03/10/18 21:21 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 03/10/18 21:21 110-57-61.0 1 1,1-Dichloroethane ND ug/L 03/10/18 21:21 75-34-31.0 1 1,2-Dichloroethane ND ug/L 03/10/18 21:21 107-06-21.0 1 1,1-Dichloroethene ND ug/L 03/10/18 21:21 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 03/10/18 21:21 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 03/10/18 21:21 156-60-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Sample:6002-HRW11R Lab ID:92376030007 Collected:03/07/18 13:18 Received:03/07/18 14:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 1,2-Dichloropropane ND ug/L 03/10/18 21:21 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 03/10/18 21:21 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 03/10/18 21:21 10061-02-61.0 1 Ethylbenzene ND ug/L 03/10/18 21:21 100-41-41.0 1 2-Hexanone ND ug/L 03/10/18 21:21 591-78-65.0 1 Iodomethane ND ug/L 03/10/18 21:21 74-88-45.0 1 Methylene Chloride ND ug/L 03/10/18 21:21 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 03/10/18 21:21 108-10-15.0 1 Styrene ND ug/L 03/10/18 21:21 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 03/10/18 21:21 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 03/10/18 21:21 79-34-51.0 1 Tetrachloroethene ND ug/L 03/10/18 21:21 127-18-41.0 1 Toluene ND ug/L 03/10/18 21:21 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 03/10/18 21:21 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 03/10/18 21:21 79-00-51.0 1 Trichloroethene ND ug/L 03/10/18 21:21 79-01-61.0 1 Trichlorofluoromethane ND ug/L 03/10/18 21:21 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 03/10/18 21:21 96-18-41.0 1 Vinyl acetate ND ug/L 03/10/18 21:21 108-05-42.0 1 Vinyl chloride ND ug/L 03/10/18 21:21 75-01-41.0 1 Xylene (Total)ND ug/L 03/10/18 21:21 1330-20-71.0 1 m&p-Xylene ND ug/L 03/10/18 21:21 179601-23-12.0 1 o-Xylene ND ug/L 03/10/18 21:21 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)96 %03/10/18 21:21 460-00-470-130 1 1,2-Dichloroethane-d4 (S)93 %03/10/18 21:21 17060-07-070-130 1 Toluene-d8 (S)99 %03/10/18 21:21 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Sample:6002-HRW13 Lab ID:92376030008 Collected:03/07/18 13:43 Received:03/07/18 14:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 03/14/18 22:05 7440-36-003/08/18 05:355.0 1 Arsenic ND ug/L 03/14/18 22:05 7440-38-203/08/18 05:3510.0 1 Barium 251 ug/L 03/14/18 22:05 7440-39-303/08/18 05:355.0 1 Beryllium ND ug/L 03/14/18 22:05 7440-41-703/08/18 05:351.0 1 Cadmium ND ug/L 03/14/18 22:05 7440-43-903/08/18 05:351.0 1 Chromium 50.8 ug/L 03/14/18 22:05 7440-47-303/08/18 05:355.0 1 Cobalt 17.1 ug/L 03/14/18 22:05 7440-48-403/08/18 05:355.0 1 Copper 75.8 ug/L 03/14/18 22:05 7440-50-803/08/18 05:355.0 1 Lead ND ug/L 03/14/18 22:05 7439-92-103/08/18 05:355.0 1 Nickel 30.9 ug/L 03/14/18 22:05 7440-02-003/08/18 05:355.0 1 Selenium ND ug/L 03/14/18 22:05 7782-49-203/08/18 05:3510.0 1 Silver ND ug/L 03/14/18 22:05 7440-22-403/08/18 05:355.0 1 Thallium ND ug/L 03/14/18 22:05 7440-28-003/08/18 05:3510.0 1 Vanadium 76.9 ug/L 03/14/18 22:05 7440-62-203/08/18 05:355.0 1 Zinc 83.6 ug/L 03/14/18 22:05 7440-66-603/08/18 05:3510.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 30206020B MET ICPMS Thallium ND ug/L 03/15/18 14:13 7440-28-003/14/18 10:250.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 03/11/18 07:14 67-64-125.0 1 Acrylonitrile ND ug/L 03/11/18 07:14 107-13-110.0 1 Benzene ND ug/L 03/11/18 07:14 71-43-21.0 1 Bromochloromethane ND ug/L 03/11/18 07:14 74-97-51.0 1 Bromodichloromethane ND ug/L 03/11/18 07:14 75-27-41.0 1 Bromoform ND ug/L 03/11/18 07:14 75-25-21.0 1 Bromomethane ND ug/L 03/11/18 07:14 74-83-92.0 1 2-Butanone (MEK)ND ug/L 03/11/18 07:14 78-93-35.0 1 Carbon disulfide ND ug/L 03/11/18 07:14 75-15-02.0 1 Carbon tetrachloride ND ug/L 03/11/18 07:14 56-23-51.0 1 Chlorobenzene ND ug/L 03/11/18 07:14 108-90-71.0 1 Chloroethane ND ug/L 03/11/18 07:14 75-00-31.0 1 Chloroform ND ug/L 03/11/18 07:14 67-66-31.0 1 Chloromethane ND ug/L 03/11/18 07:14 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 03/11/18 07:14 96-12-82.0 1 Dibromochloromethane ND ug/L 03/11/18 07:14 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 03/11/18 07:14 106-93-41.0 1 Dibromomethane ND ug/L 03/11/18 07:14 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 03/11/18 07:14 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 03/11/18 07:14 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 03/11/18 07:14 110-57-61.0 1 1,1-Dichloroethane ND ug/L 03/11/18 07:14 75-34-31.0 1 1,2-Dichloroethane ND ug/L 03/11/18 07:14 107-06-21.0 1 1,1-Dichloroethene ND ug/L 03/11/18 07:14 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 03/11/18 07:14 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 03/11/18 07:14 156-60-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Sample:6002-HRW13 Lab ID:92376030008 Collected:03/07/18 13:43 Received:03/07/18 14:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 1,2-Dichloropropane ND ug/L 03/11/18 07:14 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 03/11/18 07:14 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 03/11/18 07:14 10061-02-61.0 1 Ethylbenzene ND ug/L 03/11/18 07:14 100-41-41.0 1 2-Hexanone ND ug/L 03/11/18 07:14 591-78-65.0 1 Iodomethane ND ug/L 03/11/18 07:14 74-88-45.0 1 Methylene Chloride ND ug/L 03/11/18 07:14 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 03/11/18 07:14 108-10-15.0 1 Styrene ND ug/L 03/11/18 07:14 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 03/11/18 07:14 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 03/11/18 07:14 79-34-51.0 1 Tetrachloroethene ND ug/L 03/11/18 07:14 127-18-41.0 1 Toluene ND ug/L 03/11/18 07:14 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 03/11/18 07:14 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 03/11/18 07:14 79-00-51.0 1 Trichloroethene ND ug/L 03/11/18 07:14 79-01-61.0 1 Trichlorofluoromethane ND ug/L 03/11/18 07:14 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 03/11/18 07:14 96-18-41.0 1 Vinyl acetate ND ug/L 03/11/18 07:14 108-05-42.0 1 Vinyl chloride ND ug/L 03/11/18 07:14 75-01-41.0 1 Xylene (Total)ND ug/L 03/11/18 07:14 1330-20-71.0 1 m&p-Xylene ND ug/L 03/11/18 07:14 179601-23-12.0 1 o-Xylene ND ug/L 03/11/18 07:14 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)97 %03/11/18 07:14 460-00-470-130 1 1,2-Dichloroethane-d4 (S)102 %03/11/18 07:14 17060-07-070-130 1 Toluene-d8 (S)97 %03/11/18 07:14 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Sample:Trip Blank Lab ID:92376030009 Collected:03/07/18 00:00 Received:03/07/18 14:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 03/11/18 07:32 67-64-125.0 1 Acrylonitrile ND ug/L 03/11/18 07:32 107-13-110.0 1 Benzene ND ug/L 03/11/18 07:32 71-43-21.0 1 Bromochloromethane ND ug/L 03/11/18 07:32 74-97-51.0 1 Bromodichloromethane ND ug/L 03/11/18 07:32 75-27-41.0 1 Bromoform ND ug/L 03/11/18 07:32 75-25-21.0 1 Bromomethane ND ug/L 03/11/18 07:32 74-83-92.0 1 2-Butanone (MEK)ND ug/L 03/11/18 07:32 78-93-35.0 1 Carbon disulfide ND ug/L 03/11/18 07:32 75-15-02.0 1 Carbon tetrachloride ND ug/L 03/11/18 07:32 56-23-51.0 1 Chlorobenzene ND ug/L 03/11/18 07:32 108-90-71.0 1 Chloroethane ND ug/L 03/11/18 07:32 75-00-31.0 1 Chloroform ND ug/L 03/11/18 07:32 67-66-31.0 1 Chloromethane ND ug/L 03/11/18 07:32 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 03/11/18 07:32 96-12-82.0 1 Dibromochloromethane ND ug/L 03/11/18 07:32 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 03/11/18 07:32 106-93-41.0 1 Dibromomethane ND ug/L 03/11/18 07:32 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 03/11/18 07:32 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 03/11/18 07:32 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 03/11/18 07:32 110-57-61.0 1 1,1-Dichloroethane ND ug/L 03/11/18 07:32 75-34-31.0 1 1,2-Dichloroethane ND ug/L 03/11/18 07:32 107-06-21.0 1 1,1-Dichloroethene ND ug/L 03/11/18 07:32 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 03/11/18 07:32 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 03/11/18 07:32 156-60-51.0 1 1,2-Dichloropropane ND ug/L 03/11/18 07:32 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 03/11/18 07:32 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 03/11/18 07:32 10061-02-61.0 1 Ethylbenzene ND ug/L 03/11/18 07:32 100-41-41.0 1 2-Hexanone ND ug/L 03/11/18 07:32 591-78-65.0 1 Iodomethane ND ug/L 03/11/18 07:32 74-88-45.0 1 Methylene Chloride ND ug/L 03/11/18 07:32 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 03/11/18 07:32 108-10-15.0 1 Styrene ND ug/L 03/11/18 07:32 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 03/11/18 07:32 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 03/11/18 07:32 79-34-51.0 1 Tetrachloroethene ND ug/L 03/11/18 07:32 127-18-41.0 1 Toluene ND ug/L 03/11/18 07:32 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 03/11/18 07:32 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 03/11/18 07:32 79-00-51.0 1 Trichloroethene ND ug/L 03/11/18 07:32 79-01-61.0 1 Trichlorofluoromethane ND ug/L 03/11/18 07:32 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 03/11/18 07:32 96-18-41.0 1 Vinyl acetate ND ug/L 03/11/18 07:32 108-05-42.0 1 Vinyl chloride ND ug/L 03/11/18 07:32 75-01-41.0 1 Xylene (Total)ND ug/L 03/11/18 07:32 1330-20-71.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Sample:Trip Blank Lab ID:92376030009 Collected:03/07/18 00:00 Received:03/07/18 14:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill m&p-Xylene ND ug/L 03/11/18 07:32 179601-23-12.0 1 o-Xylene ND ug/L 03/11/18 07:32 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)95 %03/11/18 07:32 460-00-470-130 1 1,2-Dichloroethane-d4 (S)95 %03/11/18 07:32 17060-07-070-130 1 Toluene-d8 (S)110 %03/11/18 07:32 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 401084 EPA 3010A EPA 6010 6010 MET Associated Lab Samples:92376030001, 92376030002, 92376030003, 92376030004, 92376030005, 92376030006, 92376030007, 92376030008 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2224608 Associated Lab Samples:92376030001, 92376030002, 92376030003, 92376030004, 92376030005, 92376030006, 92376030007, 92376030008 Matrix:Water Analyzed Antimony ug/L ND 5.0 03/14/18 21:24 Arsenic ug/L ND 10.0 03/14/18 21:24 Barium ug/L ND 5.0 03/14/18 21:24 Beryllium ug/L ND 1.0 03/14/18 21:24 Cadmium ug/L ND 1.0 03/14/18 21:24 Chromium ug/L ND 5.0 03/14/18 21:24 Cobalt ug/L ND 5.0 03/14/18 21:24 Copper ug/L ND 5.0 03/14/18 21:24 Lead ug/L ND 5.0 03/14/18 21:24 Nickel ug/L ND 5.0 03/14/18 21:24 Selenium ug/L ND 10.0 03/14/18 21:24 Silver ug/L ND 5.0 03/14/18 21:24 Thallium ug/L ND 10.0 03/14/18 21:24 Vanadium ug/L ND 5.0 03/14/18 21:24 Zinc ug/L ND 10.0 03/14/18 21:24 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2224609LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 475500 95 80-120 Arsenic ug/L 480500 96 80-120 Barium ug/L 480500 96 80-120 Beryllium ug/L 492500 98 80-120 Cadmium ug/L 488500 98 80-120 Chromium ug/L 482500 96 80-120 Cobalt ug/L 487500 97 80-120 Copper ug/L 490500 98 80-120 Lead ug/L 473500 95 80-120 Nickel ug/L 474500 95 80-120 Selenium ug/L 467500 93 80-120 Silver ug/L 245250 98 80-120 Thallium ug/L 481500 96 80-120 Vanadium ug/L 484500 97 80-120 Zinc ug/L 483500 97 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2224610MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92375805002 2224611 MSD Result MSD % Rec RPD MSDMS Spike Conc. Antimony ug/L 500 104 75-12598 550089.2 611 579 Arsenic ug/L 500 102 75-12597 5500ND509484 Barium ug/L 500 97 75-12592 550017.1 504 477 Beryllium ug/L 500 103 75-12599 4500ND516496 Cadmium ug/L 500 99 75-12594 5500ND494472 Chromium ug/L 500 97 75-12592 550025.7 512 488 Cobalt ug/L 500 101 75-12596 5500ND503480 Copper ug/L 500 103 75-12597 55005.8 519 492 Lead ug/L 500 96 75-12591 5500ND479455 Nickel ug/L 500 96 75-12591 5500ND480456 Selenium ug/L 500 103 75-12598 4500ND514492 Silver ug/L 250 104 75-12599 5250ND259246 Thallium ug/L 500 95 75-12591 4500ND473455 Vanadium ug/L 500 100 75-12595 5500ND502478 Zinc ug/L 500 101 75-12595 550078.2 584 553 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 527206 EPA 3020 EPA 6020B 6020B Water UPD5 Associated Lab Samples:92376030001, 92376030002, 92376030003, 92376030004, 92376030005, 92376030006, 92376030007, 92376030008 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2860303 Associated Lab Samples:92376030001, 92376030002, 92376030003, 92376030004, 92376030005, 92376030006, 92376030007, 92376030008 Matrix:Water Analyzed Thallium ug/L ND 0.10 03/15/18 13:32 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2860304LABORATORY CONTROL SAMPLE: LCSSpike Thallium ug/L 101100 101 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 2860305MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92376367001 2860306 MSD Result MSD % Rec RPD MSDMS Spike Conc. Thallium ug/L 100 99 75-125106 7100ND99.2 106 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 401466 EPA 8260 EPA 8260 8260 MSV Low Level Landfill Associated Lab Samples:92376030001, 92376030002, 92376030003, 92376030004, 92376030005, 92376030006, 92376030007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2226998 Associated Lab Samples:92376030001, 92376030002, 92376030003, 92376030004, 92376030005, 92376030006, 92376030007 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 03/10/18 13:06 1,1,1-Trichloroethane ug/L ND 1.0 03/10/18 13:06 1,1,2,2-Tetrachloroethane ug/L ND 1.0 03/10/18 13:06 1,1,2-Trichloroethane ug/L ND 1.0 03/10/18 13:06 1,1-Dichloroethane ug/L ND 1.0 03/10/18 13:06 1,1-Dichloroethene ug/L ND 1.0 03/10/18 13:06 1,2,3-Trichloropropane ug/L ND 1.0 03/10/18 13:06 1,2-Dibromo-3-chloropropane ug/L ND 2.0 03/10/18 13:06 1,2-Dibromoethane (EDB)ug/L ND 1.0 03/10/18 13:06 1,2-Dichlorobenzene ug/L ND 1.0 03/10/18 13:06 1,2-Dichloroethane ug/L ND 1.0 03/10/18 13:06 1,2-Dichloropropane ug/L ND 1.0 03/10/18 13:06 1,4-Dichlorobenzene ug/L ND 1.0 03/10/18 13:06 2-Butanone (MEK)ug/L ND 5.0 03/10/18 13:06 2-Hexanone ug/L ND 5.0 03/10/18 13:06 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 03/10/18 13:06 Acetone ug/L ND 25.0 03/10/18 13:06 Acrylonitrile ug/L ND 10.0 03/10/18 13:06 Benzene ug/L ND 1.0 03/10/18 13:06 Bromochloromethane ug/L ND 1.0 03/10/18 13:06 Bromodichloromethane ug/L ND 1.0 03/10/18 13:06 Bromoform ug/L ND 1.0 03/10/18 13:06 Bromomethane ug/L ND 2.0 03/10/18 13:06 Carbon disulfide ug/L ND 2.0 03/10/18 13:06 Carbon tetrachloride ug/L ND 1.0 03/10/18 13:06 Chlorobenzene ug/L ND 1.0 03/10/18 13:06 Chloroethane ug/L ND 1.0 03/10/18 13:06 Chloroform ug/L ND 1.0 03/10/18 13:06 Chloromethane ug/L ND 1.0 03/10/18 13:06 cis-1,2-Dichloroethene ug/L ND 1.0 03/10/18 13:06 cis-1,3-Dichloropropene ug/L ND 1.0 03/10/18 13:06 Dibromochloromethane ug/L ND 1.0 03/10/18 13:06 Dibromomethane ug/L ND 1.0 03/10/18 13:06 Ethylbenzene ug/L ND 1.0 03/10/18 13:06 Iodomethane ug/L ND 5.0 03/10/18 13:06 m&p-Xylene ug/L ND 2.0 03/10/18 13:06 Methylene Chloride ug/L ND 1.0 03/10/18 13:06 o-Xylene ug/L ND 1.0 03/10/18 13:06 Styrene ug/L ND 1.0 03/10/18 13:06 Tetrachloroethene ug/L ND 1.0 03/10/18 13:06 Toluene ug/L ND 1.0 03/10/18 13:06 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2226998 Associated Lab Samples:92376030001, 92376030002, 92376030003, 92376030004, 92376030005, 92376030006, 92376030007 Matrix:Water Analyzed trans-1,2-Dichloroethene ug/L ND 1.0 03/10/18 13:06 trans-1,3-Dichloropropene ug/L ND 1.0 03/10/18 13:06 trans-1,4-Dichloro-2-butene ug/L ND 1.0 03/10/18 13:06 Trichloroethene ug/L ND 1.0 03/10/18 13:06 Trichlorofluoromethane ug/L ND 1.0 03/10/18 13:06 Vinyl acetate ug/L ND 2.0 03/10/18 13:06 Vinyl chloride ug/L ND 1.0 03/10/18 13:06 Xylene (Total)ug/L ND 1.0 03/10/18 13:06 1,2-Dichloroethane-d4 (S)%84 70-130 03/10/18 13:06 4-Bromofluorobenzene (S)%92 70-130 03/10/18 13:06 Toluene-d8 (S)%99 70-130 03/10/18 13:06 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2226999LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 57.250 114 80-125 1,1,1-Trichloroethane ug/L 44.950 90 71-129 1,1,2,2-Tetrachloroethane ug/L 51.050 102 79-124 1,1,2-Trichloroethane ug/L 50.550 101 85-125 1,1-Dichloroethane ug/L 40.850 82 73-126 1,1-Dichloroethene ug/L 44.750 89 66-135 1,2,3-Trichloropropane ug/L 51.550 103 75-130 1,2-Dibromo-3-chloropropane ug/L 59.550 119 71-133 1,2-Dibromoethane (EDB)ug/L 56.050 112 83-124 1,2-Dichlorobenzene ug/L 55.150 110 80-133 1,2-Dichloroethane ug/L 40.150 80 67-128 1,2-Dichloropropane ug/L 50.550 101 75-132 1,4-Dichlorobenzene ug/L 55.250 110 78-130 2-Butanone (MEK)ug/L 97.6100 98 61-144 2-Hexanone ug/L 109100 109 68-143 4-Methyl-2-pentanone (MIBK)ug/L 94.4100 94 72-135 Acetone ug/L 104100 104 48-146 Acrylonitrile ug/L 231250 92 40-160 Benzene ug/L 49.050 98 80-125 Bromochloromethane ug/L 44.650 89 71-125 Bromodichloromethane ug/L 48.050 96 78-124 Bromoform ug/L 61.750 123 71-128 Bromomethane ug/L 37.250 74 40-160 Carbon disulfide ug/L 42.550 85 50-160 Carbon tetrachloride ug/L 50.950 102 69-131 Chlorobenzene ug/L 54.750 109 81-122 Chloroethane ug/L 35.850 72 39-148 Chloroform ug/L 39.350 79 73-127 Chloromethane ug/L 40.950 82 44-146 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2226999LABORATORY CONTROL SAMPLE: LCSSpike cis-1,2-Dichloroethene ug/L 42.650 85 74-124 cis-1,3-Dichloropropene ug/L 49.550 99 72-132 Dibromochloromethane ug/L 58.650 117 78-125 Dibromomethane ug/L 53.450 107 82-120 Ethylbenzene ug/L 52.750 105 79-121 Iodomethane ug/L 70.1100 70 39-154 m&p-Xylene ug/L 107100 107 81-124 Methylene Chloride ug/L 40.250 80 64-133 o-Xylene ug/L 54.650 109 79-131 Styrene ug/L 53.750 107 84-126 Tetrachloroethene ug/L 55.850 112 78-122 Toluene ug/L 47.750 95 80-121 trans-1,2-Dichloroethene ug/L 43.750 87 71-127 trans-1,3-Dichloropropene ug/L 47.950 96 69-141 trans-1,4-Dichloro-2-butene ug/L 71.450 143 40-160 Trichloroethene ug/L 52.950 106 78-122 Trichlorofluoromethane ug/L 38.150 76 53-137 Vinyl acetate ug/L 78.4100 78 40-160 Vinyl chloride ug/L 47.050 94 58-137 Xylene (Total)ug/L 162150 108 81-126 1,2-Dichloroethane-d4 (S)%84 70-130 4-Bromofluorobenzene (S)%93 70-130 Toluene-d8 (S)%94 70-130 Parameter Units MS Result % Rec Limits Qual% RecConc. 2227000MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92376219007 2227001 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 20 117 70-130116 220ND23.5 23.1 1,1,1-Trichloroethane ug/L 20 104 70-130102 220ND20.8 20.4 1,1,2,2-Tetrachloroethane ug/L 20 113 70-130109 320ND22.6 21.9 1,1,2-Trichloroethane ug/L 20 111 70-130109 220ND22.2 21.7 1,1-Dichloroethane ug/L 20 98 70-13097 120ND19.6 19.3 1,1-Dichloroethene ug/L 20 109 70-166109 020ND21.8 21.8 1,2,3-Trichloropropane ug/L 20 117 70-130112 420ND23.4 22.5 1,2-Dibromo-3-chloropropane ug/L 20 124 70-130122 120ND24.7 24.4 1,2-Dibromoethane (EDB)ug/L 20 120 70-130116 320ND24.0 23.3 1,2-Dichlorobenzene ug/L 20 114 70-130119 420ND22.8 23.8 1,2-Dichloroethane ug/L 20 100 70-13096 420ND20.1 19.3 1,2-Dichloropropane ug/L 20 114 70-130113 120ND22.8 22.6 1,4-Dichlorobenzene ug/L 20 113 70-130118 520ND22.6 23.7 2-Butanone (MEK)ug/L 40 116 70-130104 1140ND46.4 41.7 2-Hexanone ug/L 40 130 70-130120 840ND51.9 48.0 4-Methyl-2-pentanone (MIBK)ug/L 40 112 70-130106 640ND44.8 42.3 Acetone ug/L 40 117 70-130103 1340ND46.6 41.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2227000MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92376219007 2227001 MSD Result MSD % Rec RPD MSDMS Spike Conc. Acrylonitrile ug/L 100 114 70-130105 8100ND114105 Benzene ug/L 20 110 70-148110 120ND22.0 21.9 Bromochloromethane ug/L 20 106 70-130105 120ND21.2 21.0 Bromodichloromethane ug/L 20 109 70-130108 020ND21.7 21.7 Bromoform ug/L 20 117 70-130115 120ND23.3 23.0 Bromomethane ug/L M1204270-13053 2220ND8.5 10.6 Carbon disulfide ug/L 20 88 70-13097 1020ND17.5 19.4 Carbon tetrachloride ug/L 20 108 70-130112 420ND21.5 22.5 Chlorobenzene ug/L 20 118 70-146117 120ND23.6 23.3 Chloroethane ug/L 20 87 70-13096 920ND17.4 19.1 Chloroform ug/L 20 97 70-13092 520ND19.4 18.4 Chloromethane ug/L 20 97 70-13098 120ND19.5 19.6 cis-1,2-Dichloroethene ug/L 20 103 70-130101 220ND20.6 20.3 cis-1,3-Dichloropropene ug/L 20 106 70-130106 020ND21.1 21.2 Dibromochloromethane ug/L 20 122 70-130121 120ND24.3 24.2 Dibromomethane ug/L 20 109 70-130111 220ND21.7 22.2 Ethylbenzene ug/L 20 112 70-130112 120ND22.5 22.4 Iodomethane ug/L M1405470-13069 2440ND21.7 27.6 m&p-Xylene ug/L 40 112 70-130111 140ND45.0 44.4 Methylene Chloride ug/L 20 105 70-13099 620ND20.9 19.8 o-Xylene ug/L 20 117 70-130116 120ND23.4 23.2 Styrene ug/L 20 110 70-130111 020ND22.1 22.1 Tetrachloroethene ug/L 20 105 70-130103 120ND21.0 20.7 Toluene ug/L 20 101 70-155102 120ND20.3 20.4 trans-1,2-Dichloroethene ug/L 20 106 70-130103 320ND21.2 20.6 trans-1,3-Dichloropropene ug/L 20 104 70-130100 420ND20.7 20.0 trans-1,4-Dichloro-2-butene ug/L 20 93 70-13089 520ND18.7 17.8 Trichloroethene ug/L 20 106 69-151107 120ND21.2 21.4 Trichlorofluoromethane ug/L 20 97 70-13098 120ND19.4 19.6 Vinyl acetate ug/L 40 88 70-13095 840ND35.1 38.0 Vinyl chloride ug/L 20 108 70-130106 220ND21.6 21.2 Xylene (Total)ug/L 60 114 70-130113 160ND68.3 67.6 1,2-Dichloroethane-d4 (S)%97 70-13096 4-Bromofluorobenzene (S)%97 70-13095 Toluene-d8 (S)%94 70-13097 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 401467 EPA 8260 EPA 8260 8260 MSV Low Level Landfill Associated Lab Samples:92376030008, 92376030009 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2227009 Associated Lab Samples:92376030008, 92376030009 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 03/11/18 00:54 1,1,1-Trichloroethane ug/L ND 1.0 03/11/18 00:54 1,1,2,2-Tetrachloroethane ug/L ND 1.0 03/11/18 00:54 1,1,2-Trichloroethane ug/L ND 1.0 03/11/18 00:54 1,1-Dichloroethane ug/L ND 1.0 03/11/18 00:54 1,1-Dichloroethene ug/L ND 1.0 03/11/18 00:54 1,2,3-Trichloropropane ug/L ND 1.0 03/11/18 00:54 1,2-Dibromo-3-chloropropane ug/L ND 2.0 03/11/18 00:54 1,2-Dibromoethane (EDB)ug/L ND 1.0 03/11/18 00:54 1,2-Dichlorobenzene ug/L ND 1.0 03/11/18 00:54 1,2-Dichloroethane ug/L ND 1.0 03/11/18 00:54 1,2-Dichloropropane ug/L ND 1.0 03/11/18 00:54 1,4-Dichlorobenzene ug/L ND 1.0 03/11/18 00:54 2-Butanone (MEK)ug/L ND 5.0 03/11/18 00:54 2-Hexanone ug/L ND 5.0 03/11/18 00:54 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 03/11/18 00:54 Acetone ug/L ND 25.0 03/11/18 00:54 Acrylonitrile ug/L ND 10.0 03/11/18 00:54 Benzene ug/L ND 1.0 03/11/18 00:54 Bromochloromethane ug/L ND 1.0 03/11/18 00:54 Bromodichloromethane ug/L ND 1.0 03/11/18 00:54 Bromoform ug/L ND 1.0 03/11/18 00:54 Bromomethane ug/L ND 2.0 03/11/18 00:54 Carbon disulfide ug/L ND 2.0 03/11/18 00:54 Carbon tetrachloride ug/L ND 1.0 03/11/18 00:54 Chlorobenzene ug/L ND 1.0 03/11/18 00:54 Chloroethane ug/L ND 1.0 03/11/18 00:54 Chloroform ug/L ND 1.0 03/11/18 00:54 Chloromethane ug/L ND 1.0 03/11/18 00:54 cis-1,2-Dichloroethene ug/L ND 1.0 03/11/18 00:54 cis-1,3-Dichloropropene ug/L ND 1.0 03/11/18 00:54 Dibromochloromethane ug/L ND 1.0 03/11/18 00:54 Dibromomethane ug/L ND 1.0 03/11/18 00:54 Ethylbenzene ug/L ND 1.0 03/11/18 00:54 Iodomethane ug/L ND 5.0 03/11/18 00:54 m&p-Xylene ug/L ND 2.0 03/11/18 00:54 Methylene Chloride ug/L ND 1.0 03/11/18 00:54 o-Xylene ug/L ND 1.0 03/11/18 00:54 Styrene ug/L ND 1.0 03/11/18 00:54 Tetrachloroethene ug/L ND 1.0 03/11/18 00:54 Toluene ug/L ND 1.0 03/11/18 00:54 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2227009 Associated Lab Samples:92376030008, 92376030009 Matrix:Water Analyzed trans-1,2-Dichloroethene ug/L ND 1.0 03/11/18 00:54 trans-1,3-Dichloropropene ug/L ND 1.0 03/11/18 00:54 trans-1,4-Dichloro-2-butene ug/L ND 1.0 03/11/18 00:54 Trichloroethene ug/L ND 1.0 03/11/18 00:54 Trichlorofluoromethane ug/L ND 1.0 03/11/18 00:54 Vinyl acetate ug/L ND 2.0 03/11/18 00:54 Vinyl chloride ug/L ND 1.0 03/11/18 00:54 Xylene (Total)ug/L ND 1.0 03/11/18 00:54 1,2-Dichloroethane-d4 (S)%87 70-130 03/11/18 00:54 4-Bromofluorobenzene (S)%94 70-130 03/11/18 00:54 Toluene-d8 (S)%99 70-130 03/11/18 00:54 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2227010LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 56.150 112 80-125 1,1,1-Trichloroethane ug/L 46.850 94 71-129 1,1,2,2-Tetrachloroethane ug/L 50.950 102 79-124 1,1,2-Trichloroethane ug/L 51.150 102 85-125 1,1-Dichloroethane ug/L 42.850 86 73-126 1,1-Dichloroethene ug/L 45.250 90 66-135 1,2,3-Trichloropropane ug/L 51.350 103 75-130 1,2-Dibromo-3-chloropropane ug/L 62.250 124 71-133 1,2-Dibromoethane (EDB)ug/L 56.250 112 83-124 1,2-Dichlorobenzene ug/L 55.650 111 80-133 1,2-Dichloroethane ug/L 43.550 87 67-128 1,2-Dichloropropane ug/L 51.050 102 75-132 1,4-Dichlorobenzene ug/L 54.350 109 78-130 2-Butanone (MEK)ug/L 111100 111 61-144 2-Hexanone ug/L 114100 114 68-143 4-Methyl-2-pentanone (MIBK)ug/L 99.6100 100 72-135 Acetone ug/L 118100 118 48-146 Acrylonitrile ug/L 257250 103 40-160 Benzene ug/L 48.250 96 80-125 Bromochloromethane ug/L 49.050 98 71-125 Bromodichloromethane ug/L 48.750 97 78-124 Bromoform ug/L 58.550 117 71-128 Bromomethane ug/L 35.450 71 40-160 Carbon disulfide ug/L 35.950 72 50-160 Carbon tetrachloride ug/L 48.650 97 69-131 Chlorobenzene ug/L 52.050 104 81-122 Chloroethane ug/L 33.750 67 39-148 Chloroform ug/L 41.850 84 73-127 Chloromethane ug/L 41.950 84 44-146 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2227010LABORATORY CONTROL SAMPLE: LCSSpike cis-1,2-Dichloroethene ug/L 45.150 90 74-124 cis-1,3-Dichloropropene ug/L 49.450 99 72-132 Dibromochloromethane ug/L 59.250 118 78-125 Dibromomethane ug/L 52.650 105 82-120 Ethylbenzene ug/L 50.050 100 79-121 Iodomethane ug/L 72.1100 72 39-154 m&p-Xylene ug/L 101100 101 81-124 Methylene Chloride ug/L 47.650 95 64-133 o-Xylene ug/L 53.050 106 79-131 Styrene ug/L 51.950 104 84-126 Tetrachloroethene ug/L 46.950 94 78-122 Toluene ug/L 44.750 89 80-121 trans-1,2-Dichloroethene ug/L 44.850 90 71-127 trans-1,3-Dichloropropene ug/L 48.550 97 69-141 trans-1,4-Dichloro-2-butene ug/L 64.750 129 40-160 Trichloroethene ug/L 50.350 101 78-122 Trichlorofluoromethane ug/L 38.350 77 53-137 Vinyl acetate ug/L 81.9100 82 40-160 Vinyl chloride ug/L 46.150 92 58-137 Xylene (Total)ug/L 154150 103 81-126 1,2-Dichloroethane-d4 (S)%94 70-130 4-Bromofluorobenzene (S)%93 70-130 Toluene-d8 (S)%96 70-130 Parameter Units MS Result % Rec Limits Qual% RecConc. 2227011MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92376383002 2227012 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 20 121 70-130125 320ND24.2 25.0 1,1,1-Trichloroethane ug/L 20 119 70-130116 320ND23.8 23.2 1,1,2,2-Tetrachloroethane ug/L 20 114 70-130125 920ND22.7 25.0 1,1,2-Trichloroethane ug/L M12013270-130108 2020ND26.3 21.5 1,1-Dichloroethane ug/L 20 120 70-130109 1020ND24.1 21.8 1,1-Dichloroethene ug/L 20 136 70-166124 920ND27.2 24.9 1,2,3-Trichloropropane ug/L 20 115 70-130119 320ND23.1 23.8 1,2-Dibromo-3-chloropropane ug/L 20 123 70-130119 320ND24.5 23.7 1,2-Dibromoethane (EDB)ug/L 20 113 70-130111 220ND22.7 22.1 1,2-Dichlorobenzene ug/L 20 115 70-130111 420ND23.0 22.1 1,2-Dichloroethane ug/L 20 99 70-13097 220ND19.9 19.4 1,2-Dichloropropane ug/L 20 110 70-130111 120ND22.0 22.2 1,4-Dichlorobenzene ug/L 20 114 70-130111 320ND22.8 22.2 2-Butanone (MEK)ug/L 40 107 70-130107 040ND42.9 42.7 2-Hexanone ug/L 40 107 70-130107 040ND42.9 42.7 4-Methyl-2-pentanone (MIBK)ug/L 40 120 70-130101 1740ND48.1 40.4 Acetone ug/L 40 119 70-130105 1240ND47.5 41.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2227011MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92376383002 2227012 MSD Result MSD % Rec RPD MSDMS Spike Conc. Acrylonitrile ug/L 100 121 70-130112 7100ND121112 Benzene ug/L 20 121 70-148114 620ND24.1 22.7 Bromochloromethane ug/L 20 120 70-130116 420ND24.0 23.1 Bromodichloromethane ug/L 20 110 70-130113 320ND22.0 22.6 Bromoform ug/L 20 114 70-130113 220ND22.9 22.5 Bromomethane ug/L M12015570-130131 1720ND30.9 26.1 Carbon disulfide ug/L M12013470-130118 1320ND26.8 23.6 Carbon tetrachloride ug/L M12013370-130127 520ND26.6 25.4 Chlorobenzene ug/L 20 116 70-146114 220ND23.1 22.7 Chloroethane ug/L M12014770-130121 1920ND29.3 24.3 Chloroform ug/L 20 109 70-130107 320ND21.9 21.3 Chloromethane ug/L M12013170-130109 1820ND26.3 21.9 cis-1,2-Dichloroethene ug/L 20 121 70-130114 620ND24.3 22.8 cis-1,3-Dichloropropene ug/L 20 116 70-130108 620ND23.1 21.7 Dibromochloromethane ug/L 20 105 70-130109 420ND20.9 21.7 Dibromomethane ug/L 20 111 70-130115 320ND22.3 23.0 Ethylbenzene ug/L 20 116 70-130115 120ND23.1 22.9 Iodomethane ug/L M14014170-130124 1340ND56.3 49.4 m&p-Xylene ug/L 40 118 70-130118 040ND47.0 47.0 Methylene Chloride ug/L 20 121 70-130107 1220ND24.1 21.4 o-Xylene ug/L 20 121 70-130119 120ND24.1 23.9 Styrene ug/L 20 117 70-130116 120ND23.4 23.2 Tetrachloroethene ug/L 20 94 70-13098 420ND18.8 19.6 Toluene ug/L 20 115 70-155108 720ND23.1 21.6 trans-1,2-Dichloroethene ug/L M12013470-130119 1220ND26.8 23.8 trans-1,3-Dichloropropene ug/L 20 130 70-130109 1720ND25.9 21.8 trans-1,4-Dichloro-2-butene ug/L 20 103 70-130110 720ND20.5 22.0 Trichloroethene ug/L 20 117 69-151114 320ND23.5 22.8 Trichlorofluoromethane ug/L 20 130 70-130111 1620ND26.0 22.2 Vinyl acetate ug/L 40 103 70-13097 640ND41.2 38.9 Vinyl chloride ug/L M12015670-130130 1820ND31.3 26.1 Xylene (Total)ug/L 60 119 70-130118 060ND71.1 70.9 1,2-Dichloroethane-d4 (S)%87 70-13091 4-Bromofluorobenzene (S)%100 70-130108 Toluene-d8 (S)%97 70-13094 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 39 #=QL# QUALIFIERS Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C Pace Analytical Services - MinneapolisPASI-M ANALYTE QUALIFIERS Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 39 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92376030 Holbrooks Rd. Landfill P#60-02 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92376030001 401084 4011826002-HRW7 EPA 3010A EPA 6010 92376030002 401084 4011826002-HRW18 EPA 3010A EPA 6010 92376030003 401084 4011826002-HRW19 EPA 3010A EPA 6010 92376030004 401084 4011826002-HRW20 EPA 3010A EPA 6010 92376030005 401084 4011826002-HRW21 EPA 3010A EPA 6010 92376030006 401084 4011826002-HRW10 EPA 3010A EPA 6010 92376030007 401084 4011826002-HRW11R EPA 3010A EPA 6010 92376030008 401084 4011826002-HRW13 EPA 3010A EPA 6010 92376030001 527206 5273736002-HRW7 EPA 3020 EPA 6020B 92376030002 527206 5273736002-HRW18 EPA 3020 EPA 6020B 92376030003 527206 5273736002-HRW19 EPA 3020 EPA 6020B 92376030004 527206 5273736002-HRW20 EPA 3020 EPA 6020B 92376030005 527206 5273736002-HRW21 EPA 3020 EPA 6020B 92376030006 527206 5273736002-HRW10 EPA 3020 EPA 6020B 92376030007 527206 5273736002-HRW11R EPA 3020 EPA 6020B 92376030008 527206 5273736002-HRW13 EPA 3020 EPA 6020B 92376030001 4014666002-HRW7 EPA 8260 92376030002 4014666002-HRW18 EPA 8260 92376030003 4014666002-HRW19 EPA 8260 92376030004 4014666002-HRW20 EPA 8260 92376030005 4014666002-HRW21 EPA 8260 92376030006 4014666002-HRW10 EPA 8260 92376030007 4014666002-HRW11R EPA 8260 92376030008 4014676002-HRW13 EPA 8260 92376030009 401467Trip Blank EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:46 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 39 Page 35 of 39 Page 36 of 39 Page 37 of 39 Page 38 of 39 Page 39 of 39 #=CL# March 16, 2018 LIMS USE: FR - AMBER GRZYMSKI LIMS OBJECT ID: 92376204 92376204 Project: Pace Project No.: RE: Amber Grzymski Mecklenburg County Solid Waste 2145 Suttle Avenue Charlotte, NC 28208 HOLBROOKS RD LANDFILL (#60-02) Dear Amber Grzymski: Enclosed are the analytical results for sample(s) received by the laboratory on March 08, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com Project Manager (704)875-9092 Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 23 #=CP# CERTIFICATIONS Pace Project No.: Project: 92376204 HOLBROOKS RD LANDFILL (#60-02) Minnesota Certification IDs 1700 Elm Street SE, Suite 200, Minneapolis, MN 55414- 2485 A2LA Certification #: 2926.01 Alabama Certification #: 40770 Alaska Contaminated Sites Certification #: 17-009 Alaska DW Certification #: MN00064 Arizona Certification #: AZ0014 Arkansas Certification #: 88-0680 California Certification #: 2929 CNMI Saipan Certification #:MP0003 Colorado Certification #: MN00064 Connecticut Certification #: PH-0256 EPA Region 8+Wyoming DW Certification #: via MN 027- 053-137 Florida Certification #: E87605 Georgia Certification #: 959 Guam EPA Certification #: MN00064 Hawaii Certification #: MN00064 Idaho Certification #: MN00064 Illinois Certification #: 200011 Indiana Certification #: C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky DW Certification #: 90062 Kentucky WW Certification #: 90062 Louisiana DEQ Certification #: 03086 Louisiana DW Certification #: MN00064 Maine Certification #: MN00064 Maryland Certification #: 322 Massachusetts Certification #: M-MN064 Michigan Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: MN00064 Montana Certification #: CERT0092 Nebraska Certification #: NE-OS-18-06 Nevada Certification #: MN00064 New Hampshire Certification #: 2081 New Jersey Certification #: MN002 New York Certification #: 11647 North Carolina DW Certification #: 27700 North Carolina WW Certification #: 530 North Dakota Certification #: R-036 Ohio DW Certification #: 41244 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon NwTPH Certification #: MN300001 Oregon Secondary Certification #: MN200001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification #: MN00064 South Carolina Certification #:74003001 Tennessee Certification #: TN02818 Texas Certification #: T104704192 Utah Certification #: MN00064 Virginia Certification #: 460163 Washington Certification #: C486 West Virginia DW Certification #: 9952 C West Virginia DEP Certification #: 382 Wisconsin Certification #: 999407970 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 23 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92376204 HOLBROOKS RD LANDFILL (#60-02) Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92376204001 6002-HRW8 EPA 6010 15 PASI-ASH1 EPA 6020B 1 PASI-MTT3 EPA 8260 52 PASI-CSWB 92376204002 6002-HRW9 EPA 6010 15 PASI-ASH1 EPA 6020B 1 PASI-MTT3 EPA 8260 52 PASI-CSWB 92376204003 6002-HRW16 EPA 6010 15 PASI-ASH1 EPA 6020B 1 PASI-MTT3 EPA 8260 52 PASI-CSWB 92376204004 TRIP BLANK EPA 8260 52 PASI-CSWB REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 23 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376204 HOLBROOKS RD LANDFILL (#60-02) Sample:6002-HRW8 Lab ID:92376204001 Collected:03/08/18 11:53 Received:03/08/18 12:34 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 03/14/18 20:58 7440-36-003/09/18 03:005.0 1 Arsenic ND ug/L 03/14/18 20:58 7440-38-203/09/18 03:0010.0 1 Barium 96.6 ug/L 03/14/18 20:58 7440-39-303/09/18 03:005.0 1 Beryllium ND ug/L 03/14/18 20:58 7440-41-703/09/18 03:001.0 1 Cadmium ND ug/L 03/14/18 20:58 7440-43-903/09/18 03:001.0 1 Chromium 15.0 ug/L 03/14/18 20:58 7440-47-303/09/18 03:005.0 1 Cobalt 6.9 ug/L 03/14/18 20:58 7440-48-403/09/18 03:005.0 1 Copper 22.4 ug/L 03/14/18 20:58 7440-50-803/09/18 03:005.0 1 Lead ND ug/L 03/14/18 20:58 7439-92-103/09/18 03:005.0 1 Nickel 7.4 ug/L 03/14/18 20:58 7440-02-003/09/18 03:005.0 1 Selenium ND ug/L 03/14/18 20:58 7782-49-203/09/18 03:0010.0 1 Silver ND ug/L 03/14/18 20:58 7440-22-403/09/18 03:005.0 1 Thallium ND ug/L 03/14/18 20:58 7440-28-003/09/18 03:0010.0 1 Vanadium 54.6 ug/L 03/14/18 20:58 7440-62-203/09/18 03:005.0 1 Zinc 20.7 ug/L 03/14/18 20:58 7440-66-603/09/18 03:0010.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 30206020B MET ICPMS Thallium ND ug/L 03/15/18 14:16 7440-28-003/14/18 10:250.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 03/11/18 01:47 67-64-125.0 1 Acrylonitrile ND ug/L 03/11/18 01:47 107-13-110.0 1 Benzene ND ug/L 03/11/18 01:47 71-43-21.0 1 Bromochloromethane ND ug/L 03/11/18 01:47 74-97-51.0 1 Bromodichloromethane ND ug/L 03/11/18 01:47 75-27-41.0 1 Bromoform ND ug/L 03/11/18 01:47 75-25-21.0 1 Bromomethane ND ug/L 03/11/18 01:47 74-83-92.0 1 2-Butanone (MEK)ND ug/L 03/11/18 01:47 78-93-35.0 1 Carbon disulfide ND ug/L 03/11/18 01:47 75-15-02.0 1 Carbon tetrachloride ND ug/L 03/11/18 01:47 56-23-51.0 1 Chlorobenzene ND ug/L 03/11/18 01:47 108-90-71.0 1 Chloroethane ND ug/L 03/11/18 01:47 75-00-31.0 1 Chloroform ND ug/L 03/11/18 01:47 67-66-31.0 1 Chloromethane ND ug/L 03/11/18 01:47 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 03/11/18 01:47 96-12-82.0 1 Dibromochloromethane ND ug/L 03/11/18 01:47 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 03/11/18 01:47 106-93-41.0 1 Dibromomethane ND ug/L 03/11/18 01:47 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 03/11/18 01:47 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 03/11/18 01:47 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 03/11/18 01:47 110-57-61.0 1 1,1-Dichloroethane ND ug/L 03/11/18 01:47 75-34-31.0 1 1,2-Dichloroethane ND ug/L 03/11/18 01:47 107-06-21.0 1 1,1-Dichloroethene ND ug/L 03/11/18 01:47 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 03/11/18 01:47 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 03/11/18 01:47 156-60-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:47 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 23 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376204 HOLBROOKS RD LANDFILL (#60-02) Sample:6002-HRW8 Lab ID:92376204001 Collected:03/08/18 11:53 Received:03/08/18 12:34 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 1,2-Dichloropropane ND ug/L 03/11/18 01:47 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 03/11/18 01:47 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 03/11/18 01:47 10061-02-61.0 1 Ethylbenzene ND ug/L 03/11/18 01:47 100-41-41.0 1 2-Hexanone ND ug/L 03/11/18 01:47 591-78-65.0 1 Iodomethane ND ug/L 03/11/18 01:47 74-88-45.0 1 Methylene Chloride ND ug/L 03/11/18 01:47 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 03/11/18 01:47 108-10-15.0 1 Styrene ND ug/L 03/11/18 01:47 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 03/11/18 01:47 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 03/11/18 01:47 79-34-51.0 1 Tetrachloroethene ND ug/L 03/11/18 01:47 127-18-41.0 1 Toluene ND ug/L 03/11/18 01:47 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 03/11/18 01:47 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 03/11/18 01:47 79-00-51.0 1 Trichloroethene ND ug/L 03/11/18 01:47 79-01-61.0 1 Trichlorofluoromethane ND ug/L 03/11/18 01:47 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 03/11/18 01:47 96-18-41.0 1 Vinyl acetate ND ug/L 03/11/18 01:47 108-05-42.0 1 Vinyl chloride ND ug/L 03/11/18 01:47 75-01-41.0 1 Xylene (Total)ND ug/L 03/11/18 01:47 1330-20-71.0 1 m&p-Xylene ND ug/L 03/11/18 01:47 179601-23-12.0 1 o-Xylene ND ug/L 03/11/18 01:47 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)93 %03/11/18 01:47 460-00-470-130 1 1,2-Dichloroethane-d4 (S)92 %03/11/18 01:47 17060-07-070-130 1 Toluene-d8 (S)105 %03/11/18 01:47 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:47 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 23 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376204 HOLBROOKS RD LANDFILL (#60-02) Sample:6002-HRW9 Lab ID:92376204002 Collected:03/08/18 10:38 Received:03/08/18 12:34 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 03/14/18 21:01 7440-36-003/09/18 03:005.0 1 Arsenic ND ug/L 03/14/18 21:01 7440-38-203/09/18 03:0010.0 1 Barium 289 ug/L 03/14/18 21:01 7440-39-303/09/18 03:005.0 1 Beryllium ND ug/L 03/14/18 21:01 7440-41-703/09/18 03:001.0 1 Cadmium ND ug/L 03/14/18 21:01 7440-43-903/09/18 03:001.0 1 Chromium ND ug/L 03/14/18 21:01 7440-47-303/09/18 03:005.0 1 Cobalt ND ug/L 03/14/18 21:01 7440-48-403/09/18 03:005.0 1 Copper ND ug/L 03/14/18 21:01 7440-50-803/09/18 03:005.0 1 Lead ND ug/L 03/14/18 21:01 7439-92-103/09/18 03:005.0 1 Nickel 5.5 ug/L 03/14/18 21:01 7440-02-003/09/18 03:005.0 1 Selenium ND ug/L 03/14/18 21:01 7782-49-203/09/18 03:0010.0 1 Silver ND ug/L 03/14/18 21:01 7440-22-403/09/18 03:005.0 1 Thallium ND ug/L 03/14/18 21:01 7440-28-003/09/18 03:0010.0 1 Vanadium ND ug/L 03/14/18 21:01 7440-62-203/09/18 03:005.0 1 Zinc ND ug/L 03/14/18 21:01 7440-66-603/09/18 03:0010.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 30206020B MET ICPMS Thallium ND ug/L 03/15/18 14:19 7440-28-003/14/18 10:250.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 03/11/18 03:05 67-64-125.0 1 Acrylonitrile ND ug/L 03/11/18 03:05 107-13-110.0 1 Benzene ND ug/L 03/11/18 03:05 71-43-21.0 1 Bromochloromethane ND ug/L 03/11/18 03:05 74-97-51.0 1 Bromodichloromethane ND ug/L 03/11/18 03:05 75-27-41.0 1 Bromoform ND ug/L 03/11/18 03:05 75-25-21.0 1 Bromomethane ND ug/L 03/11/18 03:05 74-83-92.0 1 2-Butanone (MEK)ND ug/L 03/11/18 03:05 78-93-35.0 1 Carbon disulfide ND ug/L 03/11/18 03:05 75-15-02.0 1 Carbon tetrachloride ND ug/L 03/11/18 03:05 56-23-51.0 1 Chlorobenzene ND ug/L 03/11/18 03:05 108-90-71.0 1 Chloroethane ND ug/L 03/11/18 03:05 75-00-31.0 1 Chloroform ND ug/L 03/11/18 03:05 67-66-31.0 1 Chloromethane ND ug/L 03/11/18 03:05 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 03/11/18 03:05 96-12-82.0 1 Dibromochloromethane ND ug/L 03/11/18 03:05 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 03/11/18 03:05 106-93-41.0 1 Dibromomethane ND ug/L 03/11/18 03:05 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 03/11/18 03:05 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 03/11/18 03:05 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 03/11/18 03:05 110-57-61.0 1 1,1-Dichloroethane ND ug/L 03/11/18 03:05 75-34-31.0 1 1,2-Dichloroethane ND ug/L 03/11/18 03:05 107-06-21.0 1 1,1-Dichloroethene ND ug/L 03/11/18 03:05 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 03/11/18 03:05 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 03/11/18 03:05 156-60-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:47 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 23 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376204 HOLBROOKS RD LANDFILL (#60-02) Sample:6002-HRW9 Lab ID:92376204002 Collected:03/08/18 10:38 Received:03/08/18 12:34 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 1,2-Dichloropropane ND ug/L 03/11/18 03:05 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 03/11/18 03:05 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 03/11/18 03:05 10061-02-61.0 1 Ethylbenzene ND ug/L 03/11/18 03:05 100-41-41.0 1 2-Hexanone ND ug/L 03/11/18 03:05 591-78-65.0 1 Iodomethane ND ug/L 03/11/18 03:05 74-88-45.0 1 Methylene Chloride ND ug/L 03/11/18 03:05 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 03/11/18 03:05 108-10-15.0 1 Styrene ND ug/L 03/11/18 03:05 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 03/11/18 03:05 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 03/11/18 03:05 79-34-51.0 1 Tetrachloroethene ND ug/L 03/11/18 03:05 127-18-41.0 1 Toluene ND ug/L 03/11/18 03:05 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 03/11/18 03:05 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 03/11/18 03:05 79-00-51.0 1 Trichloroethene ND ug/L 03/11/18 03:05 79-01-61.0 1 Trichlorofluoromethane ND ug/L 03/11/18 03:05 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 03/11/18 03:05 96-18-41.0 1 Vinyl acetate ND ug/L 03/11/18 03:05 108-05-42.0 1 Vinyl chloride ND ug/L 03/11/18 03:05 75-01-41.0 1 Xylene (Total)ND ug/L 03/11/18 03:05 1330-20-71.0 1 m&p-Xylene ND ug/L 03/11/18 03:05 179601-23-12.0 1 o-Xylene ND ug/L 03/11/18 03:05 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)94 %03/11/18 03:05 460-00-470-130 1 1,2-Dichloroethane-d4 (S)91 %03/11/18 03:05 17060-07-070-130 1 Toluene-d8 (S)98 %03/11/18 03:05 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:47 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 23 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376204 HOLBROOKS RD LANDFILL (#60-02) Sample:6002-HRW16 Lab ID:92376204003 Collected:03/08/18 10:24 Received:03/08/18 12:34 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 03/14/18 21:04 7440-36-003/09/18 03:005.0 1 Arsenic ND ug/L 03/14/18 21:04 7440-38-203/09/18 03:0010.0 1 Barium 126 ug/L 03/14/18 21:04 7440-39-303/09/18 03:005.0 1 Beryllium ND ug/L 03/14/18 21:04 7440-41-703/09/18 03:001.0 1 Cadmium ND ug/L 03/14/18 21:04 7440-43-903/09/18 03:001.0 1 Chromium 14.8 ug/L 03/14/18 21:04 7440-47-303/09/18 03:005.0 1 Cobalt 6.5 ug/L 03/14/18 21:04 7440-48-403/09/18 03:005.0 1 Copper 32.2 ug/L 03/14/18 21:04 7440-50-803/09/18 03:005.0 1 Lead ND ug/L 03/14/18 21:04 7439-92-103/09/18 03:005.0 1 Nickel 8.4 ug/L 03/14/18 21:04 7440-02-003/09/18 03:005.0 1 Selenium ND ug/L 03/14/18 21:04 7782-49-203/09/18 03:0010.0 1 Silver ND ug/L 03/14/18 21:04 7440-22-403/09/18 03:005.0 1 Thallium ND ug/L 03/14/18 21:04 7440-28-003/09/18 03:0010.0 1 Vanadium 53.6 ug/L 03/14/18 21:04 7440-62-203/09/18 03:005.0 1 Zinc 25.9 ug/L 03/14/18 21:04 7440-66-603/09/18 03:0010.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 30206020B MET ICPMS Thallium ND ug/L 03/15/18 14:21 7440-28-003/14/18 10:250.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 03/11/18 03:23 67-64-125.0 1 Acrylonitrile ND ug/L 03/11/18 03:23 107-13-110.0 1 Benzene ND ug/L 03/11/18 03:23 71-43-21.0 1 Bromochloromethane ND ug/L 03/11/18 03:23 74-97-51.0 1 Bromodichloromethane ND ug/L 03/11/18 03:23 75-27-41.0 1 Bromoform ND ug/L 03/11/18 03:23 75-25-21.0 1 Bromomethane ND ug/L 03/11/18 03:23 74-83-92.0 1 2-Butanone (MEK)ND ug/L 03/11/18 03:23 78-93-35.0 1 Carbon disulfide ND ug/L 03/11/18 03:23 75-15-02.0 1 Carbon tetrachloride ND ug/L 03/11/18 03:23 56-23-51.0 1 Chlorobenzene ND ug/L 03/11/18 03:23 108-90-71.0 1 Chloroethane ND ug/L 03/11/18 03:23 75-00-31.0 1 Chloroform ND ug/L 03/11/18 03:23 67-66-31.0 1 Chloromethane ND ug/L 03/11/18 03:23 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 03/11/18 03:23 96-12-82.0 1 Dibromochloromethane ND ug/L 03/11/18 03:23 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 03/11/18 03:23 106-93-41.0 1 Dibromomethane ND ug/L 03/11/18 03:23 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 03/11/18 03:23 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 03/11/18 03:23 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 03/11/18 03:23 110-57-61.0 1 1,1-Dichloroethane ND ug/L 03/11/18 03:23 75-34-31.0 1 1,2-Dichloroethane ND ug/L 03/11/18 03:23 107-06-21.0 1 1,1-Dichloroethene ND ug/L 03/11/18 03:23 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 03/11/18 03:23 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 03/11/18 03:23 156-60-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:47 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 23 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376204 HOLBROOKS RD LANDFILL (#60-02) Sample:6002-HRW16 Lab ID:92376204003 Collected:03/08/18 10:24 Received:03/08/18 12:34 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 1,2-Dichloropropane ND ug/L 03/11/18 03:23 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 03/11/18 03:23 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 03/11/18 03:23 10061-02-61.0 1 Ethylbenzene ND ug/L 03/11/18 03:23 100-41-41.0 1 2-Hexanone ND ug/L 03/11/18 03:23 591-78-65.0 1 Iodomethane ND ug/L 03/11/18 03:23 74-88-45.0 1 Methylene Chloride ND ug/L 03/11/18 03:23 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 03/11/18 03:23 108-10-15.0 1 Styrene ND ug/L 03/11/18 03:23 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 03/11/18 03:23 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 03/11/18 03:23 79-34-51.0 1 Tetrachloroethene ND ug/L 03/11/18 03:23 127-18-41.0 1 Toluene ND ug/L 03/11/18 03:23 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 03/11/18 03:23 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 03/11/18 03:23 79-00-51.0 1 Trichloroethene ND ug/L 03/11/18 03:23 79-01-61.0 1 Trichlorofluoromethane ND ug/L 03/11/18 03:23 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 03/11/18 03:23 96-18-41.0 1 Vinyl acetate ND ug/L 03/11/18 03:23 108-05-42.0 1 Vinyl chloride ND ug/L 03/11/18 03:23 75-01-41.0 1 Xylene (Total)ND ug/L 03/11/18 03:23 1330-20-71.0 1 m&p-Xylene ND ug/L 03/11/18 03:23 179601-23-12.0 1 o-Xylene ND ug/L 03/11/18 03:23 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)93 %03/11/18 03:23 460-00-470-130 1 1,2-Dichloroethane-d4 (S)89 %03/11/18 03:23 17060-07-070-130 1 Toluene-d8 (S)99 %03/11/18 03:23 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:47 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 23 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376204 HOLBROOKS RD LANDFILL (#60-02) Sample:TRIP BLANK Lab ID:92376204004 Collected:03/08/18 12:12 Received:03/08/18 12:34 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 03/11/18 03:41 67-64-125.0 1 Acrylonitrile ND ug/L 03/11/18 03:41 107-13-110.0 1 Benzene ND ug/L 03/11/18 03:41 71-43-21.0 1 Bromochloromethane ND ug/L 03/11/18 03:41 74-97-51.0 1 Bromodichloromethane ND ug/L 03/11/18 03:41 75-27-41.0 1 Bromoform ND ug/L 03/11/18 03:41 75-25-21.0 1 Bromomethane ND ug/L 03/11/18 03:41 74-83-92.0 1 2-Butanone (MEK)ND ug/L 03/11/18 03:41 78-93-35.0 1 Carbon disulfide ND ug/L 03/11/18 03:41 75-15-02.0 1 Carbon tetrachloride ND ug/L 03/11/18 03:41 56-23-51.0 1 Chlorobenzene ND ug/L 03/11/18 03:41 108-90-71.0 1 Chloroethane ND ug/L 03/11/18 03:41 75-00-31.0 1 Chloroform ND ug/L 03/11/18 03:41 67-66-31.0 1 Chloromethane ND ug/L 03/11/18 03:41 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 03/11/18 03:41 96-12-82.0 1 Dibromochloromethane ND ug/L 03/11/18 03:41 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 03/11/18 03:41 106-93-41.0 1 Dibromomethane ND ug/L 03/11/18 03:41 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 03/11/18 03:41 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 03/11/18 03:41 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 03/11/18 03:41 110-57-61.0 1 1,1-Dichloroethane ND ug/L 03/11/18 03:41 75-34-31.0 1 1,2-Dichloroethane ND ug/L 03/11/18 03:41 107-06-21.0 1 1,1-Dichloroethene ND ug/L 03/11/18 03:41 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 03/11/18 03:41 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 03/11/18 03:41 156-60-51.0 1 1,2-Dichloropropane ND ug/L 03/11/18 03:41 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 03/11/18 03:41 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 03/11/18 03:41 10061-02-61.0 1 Ethylbenzene ND ug/L 03/11/18 03:41 100-41-41.0 1 2-Hexanone ND ug/L 03/11/18 03:41 591-78-65.0 1 Iodomethane ND ug/L 03/11/18 03:41 74-88-45.0 1 Methylene Chloride ND ug/L 03/11/18 03:41 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 03/11/18 03:41 108-10-15.0 1 Styrene ND ug/L 03/11/18 03:41 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 03/11/18 03:41 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 03/11/18 03:41 79-34-51.0 1 Tetrachloroethene ND ug/L 03/11/18 03:41 127-18-41.0 1 Toluene ND ug/L 03/11/18 03:41 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 03/11/18 03:41 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 03/11/18 03:41 79-00-51.0 1 Trichloroethene ND ug/L 03/11/18 03:41 79-01-61.0 1 Trichlorofluoromethane ND ug/L 03/11/18 03:41 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 03/11/18 03:41 96-18-41.0 1 Vinyl acetate ND ug/L 03/11/18 03:41 108-05-42.0 1 Vinyl chloride ND ug/L 03/11/18 03:41 75-01-41.0 1 Xylene (Total)ND ug/L 03/11/18 03:41 1330-20-71.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:47 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 23 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376204 HOLBROOKS RD LANDFILL (#60-02) Sample:TRIP BLANK Lab ID:92376204004 Collected:03/08/18 12:12 Received:03/08/18 12:34 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill m&p-Xylene ND ug/L 03/11/18 03:41 179601-23-12.0 1 o-Xylene ND ug/L 03/11/18 03:41 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)95 %03/11/18 03:41 460-00-470-130 1 1,2-Dichloroethane-d4 (S)92 %03/11/18 03:41 17060-07-070-130 1 Toluene-d8 (S)100 %03/11/18 03:41 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:47 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 23 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376204 HOLBROOKS RD LANDFILL (#60-02) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 401294 EPA 3010A EPA 6010 6010 MET Associated Lab Samples:92376204001, 92376204002, 92376204003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2225833 Associated Lab Samples:92376204001, 92376204002, 92376204003 Matrix:Water Analyzed Antimony ug/L ND 5.0 03/14/18 19:48 Arsenic ug/L ND 10.0 03/14/18 19:48 Barium ug/L ND 5.0 03/14/18 19:48 Beryllium ug/L ND 1.0 03/14/18 19:48 Cadmium ug/L ND 1.0 03/14/18 19:48 Chromium ug/L ND 5.0 03/14/18 19:48 Cobalt ug/L ND 5.0 03/14/18 19:48 Copper ug/L ND 5.0 03/14/18 19:48 Lead ug/L ND 5.0 03/14/18 19:48 Nickel ug/L ND 5.0 03/14/18 19:48 Selenium ug/L ND 10.0 03/14/18 19:48 Silver ug/L ND 5.0 03/14/18 19:48 Thallium ug/L ND 10.0 03/14/18 19:48 Vanadium ug/L ND 5.0 03/14/18 19:48 Zinc ug/L ND 10.0 03/14/18 19:48 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2225834LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 510500 102 80-120 Arsenic ug/L 513500 103 80-120 Barium ug/L 514500 103 80-120 Beryllium ug/L 527500 105 80-120 Cadmium ug/L 524500 105 80-120 Chromium ug/L 516500 103 80-120 Cobalt ug/L 525500 105 80-120 Copper ug/L 526500 105 80-120 Lead ug/L 505500 101 80-120 Nickel ug/L 508500 102 80-120 Selenium ug/L 500500 100 80-120 Silver ug/L 262250 105 80-120 Thallium ug/L 524500 105 80-120 Vanadium ug/L 518500 104 80-120 Zinc ug/L 518500 104 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:47 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 23 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376204 HOLBROOKS RD LANDFILL (#60-02) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2225835MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 35378299001 2225836 MSD Result MSD % Rec RPD MSDMS Spike Conc. Antimony ug/L 500 102 75-125106 35003.9U 512 529 Arsenic ug/L 500 102 75-125106 45005.0U 510 530 Barium ug/L 500 95 75-12598 25009.3 487 499 Beryllium ug/L 500 102 75-125106 45000.50U 512 530 Cadmium ug/L 500 98 75-125102 45000.50U 491 510 Chromium ug/L 500 97 75-125100 35002.5U 487 504 Cobalt ug/L 500 99 75-125102 35002.5U 495 512 Copper ug/L 500 99 75-125103 45002.5U 498 517 Lead ug/L 500 94 75-12598 45002.5U 472 489 Nickel ug/L 500 95 75-12598 35002.5U 474 489 Selenium ug/L 500 104 75-125107 35005.0U 518 536 Silver ug/L 250 103 75-125108 52502.5U 257 269 Thallium ug/L 500 98 75-125102 45005.0U 492 512 Vanadium ug/L 500 99 75-125102 35007.9 505 520 Zinc ug/L 500 98 75-125101 45005.0U 489 507 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:47 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 23 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376204 HOLBROOKS RD LANDFILL (#60-02) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 527206 EPA 3020 EPA 6020B 6020B Water UPD5 Associated Lab Samples:92376204001, 92376204002, 92376204003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2860303 Associated Lab Samples:92376204001, 92376204002, 92376204003 Matrix:Water Analyzed Thallium ug/L ND 0.10 03/15/18 13:32 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2860304LABORATORY CONTROL SAMPLE: LCSSpike Thallium ug/L 101100 101 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 2860305MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92376367001 2860306 MSD Result MSD % Rec RPD MSDMS Spike Conc. Thallium ug/L 100 99 75-125106 7100ND99.2 106 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:47 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 23 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376204 HOLBROOKS RD LANDFILL (#60-02) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 401467 EPA 8260 EPA 8260 8260 MSV Low Level Landfill Associated Lab Samples:92376204001, 92376204002, 92376204003, 92376204004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2227009 Associated Lab Samples:92376204001, 92376204002, 92376204003, 92376204004 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 03/11/18 00:54 1,1,1-Trichloroethane ug/L ND 1.0 03/11/18 00:54 1,1,2,2-Tetrachloroethane ug/L ND 1.0 03/11/18 00:54 1,1,2-Trichloroethane ug/L ND 1.0 03/11/18 00:54 1,1-Dichloroethane ug/L ND 1.0 03/11/18 00:54 1,1-Dichloroethene ug/L ND 1.0 03/11/18 00:54 1,2,3-Trichloropropane ug/L ND 1.0 03/11/18 00:54 1,2-Dibromo-3-chloropropane ug/L ND 2.0 03/11/18 00:54 1,2-Dibromoethane (EDB)ug/L ND 1.0 03/11/18 00:54 1,2-Dichlorobenzene ug/L ND 1.0 03/11/18 00:54 1,2-Dichloroethane ug/L ND 1.0 03/11/18 00:54 1,2-Dichloropropane ug/L ND 1.0 03/11/18 00:54 1,4-Dichlorobenzene ug/L ND 1.0 03/11/18 00:54 2-Butanone (MEK)ug/L ND 5.0 03/11/18 00:54 2-Hexanone ug/L ND 5.0 03/11/18 00:54 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 03/11/18 00:54 Acetone ug/L ND 25.0 03/11/18 00:54 Acrylonitrile ug/L ND 10.0 03/11/18 00:54 Benzene ug/L ND 1.0 03/11/18 00:54 Bromochloromethane ug/L ND 1.0 03/11/18 00:54 Bromodichloromethane ug/L ND 1.0 03/11/18 00:54 Bromoform ug/L ND 1.0 03/11/18 00:54 Bromomethane ug/L ND 2.0 03/11/18 00:54 Carbon disulfide ug/L ND 2.0 03/11/18 00:54 Carbon tetrachloride ug/L ND 1.0 03/11/18 00:54 Chlorobenzene ug/L ND 1.0 03/11/18 00:54 Chloroethane ug/L ND 1.0 03/11/18 00:54 Chloroform ug/L ND 1.0 03/11/18 00:54 Chloromethane ug/L ND 1.0 03/11/18 00:54 cis-1,2-Dichloroethene ug/L ND 1.0 03/11/18 00:54 cis-1,3-Dichloropropene ug/L ND 1.0 03/11/18 00:54 Dibromochloromethane ug/L ND 1.0 03/11/18 00:54 Dibromomethane ug/L ND 1.0 03/11/18 00:54 Ethylbenzene ug/L ND 1.0 03/11/18 00:54 Iodomethane ug/L ND 5.0 03/11/18 00:54 m&p-Xylene ug/L ND 2.0 03/11/18 00:54 Methylene Chloride ug/L ND 1.0 03/11/18 00:54 o-Xylene ug/L ND 1.0 03/11/18 00:54 Styrene ug/L ND 1.0 03/11/18 00:54 Tetrachloroethene ug/L ND 1.0 03/11/18 00:54 Toluene ug/L ND 1.0 03/11/18 00:54 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:47 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 23 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376204 HOLBROOKS RD LANDFILL (#60-02) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2227009 Associated Lab Samples:92376204001, 92376204002, 92376204003, 92376204004 Matrix:Water Analyzed trans-1,2-Dichloroethene ug/L ND 1.0 03/11/18 00:54 trans-1,3-Dichloropropene ug/L ND 1.0 03/11/18 00:54 trans-1,4-Dichloro-2-butene ug/L ND 1.0 03/11/18 00:54 Trichloroethene ug/L ND 1.0 03/11/18 00:54 Trichlorofluoromethane ug/L ND 1.0 03/11/18 00:54 Vinyl acetate ug/L ND 2.0 03/11/18 00:54 Vinyl chloride ug/L ND 1.0 03/11/18 00:54 Xylene (Total)ug/L ND 1.0 03/11/18 00:54 1,2-Dichloroethane-d4 (S)%87 70-130 03/11/18 00:54 4-Bromofluorobenzene (S)%94 70-130 03/11/18 00:54 Toluene-d8 (S)%99 70-130 03/11/18 00:54 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2227010LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 56.150 112 80-125 1,1,1-Trichloroethane ug/L 46.850 94 71-129 1,1,2,2-Tetrachloroethane ug/L 50.950 102 79-124 1,1,2-Trichloroethane ug/L 51.150 102 85-125 1,1-Dichloroethane ug/L 42.850 86 73-126 1,1-Dichloroethene ug/L 45.250 90 66-135 1,2,3-Trichloropropane ug/L 51.350 103 75-130 1,2-Dibromo-3-chloropropane ug/L 62.250 124 71-133 1,2-Dibromoethane (EDB)ug/L 56.250 112 83-124 1,2-Dichlorobenzene ug/L 55.650 111 80-133 1,2-Dichloroethane ug/L 43.550 87 67-128 1,2-Dichloropropane ug/L 51.050 102 75-132 1,4-Dichlorobenzene ug/L 54.350 109 78-130 2-Butanone (MEK)ug/L 111100 111 61-144 2-Hexanone ug/L 114100 114 68-143 4-Methyl-2-pentanone (MIBK)ug/L 99.6100 100 72-135 Acetone ug/L 118100 118 48-146 Acrylonitrile ug/L 257250 103 40-160 Benzene ug/L 48.250 96 80-125 Bromochloromethane ug/L 49.050 98 71-125 Bromodichloromethane ug/L 48.750 97 78-124 Bromoform ug/L 58.550 117 71-128 Bromomethane ug/L 35.450 71 40-160 Carbon disulfide ug/L 35.950 72 50-160 Carbon tetrachloride ug/L 48.650 97 69-131 Chlorobenzene ug/L 52.050 104 81-122 Chloroethane ug/L 33.750 67 39-148 Chloroform ug/L 41.850 84 73-127 Chloromethane ug/L 41.950 84 44-146 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:47 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 23 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376204 HOLBROOKS RD LANDFILL (#60-02) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2227010LABORATORY CONTROL SAMPLE: LCSSpike cis-1,2-Dichloroethene ug/L 45.150 90 74-124 cis-1,3-Dichloropropene ug/L 49.450 99 72-132 Dibromochloromethane ug/L 59.250 118 78-125 Dibromomethane ug/L 52.650 105 82-120 Ethylbenzene ug/L 50.050 100 79-121 Iodomethane ug/L 72.1100 72 39-154 m&p-Xylene ug/L 101100 101 81-124 Methylene Chloride ug/L 47.650 95 64-133 o-Xylene ug/L 53.050 106 79-131 Styrene ug/L 51.950 104 84-126 Tetrachloroethene ug/L 46.950 94 78-122 Toluene ug/L 44.750 89 80-121 trans-1,2-Dichloroethene ug/L 44.850 90 71-127 trans-1,3-Dichloropropene ug/L 48.550 97 69-141 trans-1,4-Dichloro-2-butene ug/L 64.750 129 40-160 Trichloroethene ug/L 50.350 101 78-122 Trichlorofluoromethane ug/L 38.350 77 53-137 Vinyl acetate ug/L 81.9100 82 40-160 Vinyl chloride ug/L 46.150 92 58-137 Xylene (Total)ug/L 154150 103 81-126 1,2-Dichloroethane-d4 (S)%94 70-130 4-Bromofluorobenzene (S)%93 70-130 Toluene-d8 (S)%96 70-130 Parameter Units MS Result % Rec Limits Qual% RecConc. 2227011MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92376383002 2227012 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 20 121 70-130125 320ND24.2 25.0 1,1,1-Trichloroethane ug/L 20 119 70-130116 320ND23.8 23.2 1,1,2,2-Tetrachloroethane ug/L 20 114 70-130125 920ND22.7 25.0 1,1,2-Trichloroethane ug/L M12013270-130108 2020ND26.3 21.5 1,1-Dichloroethane ug/L 20 120 70-130109 1020ND24.1 21.8 1,1-Dichloroethene ug/L 20 136 70-166124 920ND27.2 24.9 1,2,3-Trichloropropane ug/L 20 115 70-130119 320ND23.1 23.8 1,2-Dibromo-3-chloropropane ug/L 20 123 70-130119 320ND24.5 23.7 1,2-Dibromoethane (EDB)ug/L 20 113 70-130111 220ND22.7 22.1 1,2-Dichlorobenzene ug/L 20 115 70-130111 420ND23.0 22.1 1,2-Dichloroethane ug/L 20 99 70-13097 220ND19.9 19.4 1,2-Dichloropropane ug/L 20 110 70-130111 120ND22.0 22.2 1,4-Dichlorobenzene ug/L 20 114 70-130111 320ND22.8 22.2 2-Butanone (MEK)ug/L 40 107 70-130107 040ND42.9 42.7 2-Hexanone ug/L 40 107 70-130107 040ND42.9 42.7 4-Methyl-2-pentanone (MIBK)ug/L 40 120 70-130101 1740ND48.1 40.4 Acetone ug/L 40 119 70-130105 1240ND47.5 41.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:47 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 23 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376204 HOLBROOKS RD LANDFILL (#60-02) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2227011MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92376383002 2227012 MSD Result MSD % Rec RPD MSDMS Spike Conc. Acrylonitrile ug/L 100 121 70-130112 7100ND121112 Benzene ug/L 20 121 70-148114 620ND24.1 22.7 Bromochloromethane ug/L 20 120 70-130116 420ND24.0 23.1 Bromodichloromethane ug/L 20 110 70-130113 320ND22.0 22.6 Bromoform ug/L 20 114 70-130113 220ND22.9 22.5 Bromomethane ug/L M12015570-130131 1720ND30.9 26.1 Carbon disulfide ug/L M12013470-130118 1320ND26.8 23.6 Carbon tetrachloride ug/L M12013370-130127 520ND26.6 25.4 Chlorobenzene ug/L 20 116 70-146114 220ND23.1 22.7 Chloroethane ug/L M12014770-130121 1920ND29.3 24.3 Chloroform ug/L 20 109 70-130107 320ND21.9 21.3 Chloromethane ug/L M12013170-130109 1820ND26.3 21.9 cis-1,2-Dichloroethene ug/L 20 121 70-130114 620ND24.3 22.8 cis-1,3-Dichloropropene ug/L 20 116 70-130108 620ND23.1 21.7 Dibromochloromethane ug/L 20 105 70-130109 420ND20.9 21.7 Dibromomethane ug/L 20 111 70-130115 320ND22.3 23.0 Ethylbenzene ug/L 20 116 70-130115 120ND23.1 22.9 Iodomethane ug/L M14014170-130124 1340ND56.3 49.4 m&p-Xylene ug/L 40 118 70-130118 040ND47.0 47.0 Methylene Chloride ug/L 20 121 70-130107 1220ND24.1 21.4 o-Xylene ug/L 20 121 70-130119 120ND24.1 23.9 Styrene ug/L 20 117 70-130116 120ND23.4 23.2 Tetrachloroethene ug/L 20 94 70-13098 420ND18.8 19.6 Toluene ug/L 20 115 70-155108 720ND23.1 21.6 trans-1,2-Dichloroethene ug/L M12013470-130119 1220ND26.8 23.8 trans-1,3-Dichloropropene ug/L 20 130 70-130109 1720ND25.9 21.8 trans-1,4-Dichloro-2-butene ug/L 20 103 70-130110 720ND20.5 22.0 Trichloroethene ug/L 20 117 69-151114 320ND23.5 22.8 Trichlorofluoromethane ug/L 20 130 70-130111 1620ND26.0 22.2 Vinyl acetate ug/L 40 103 70-13097 640ND41.2 38.9 Vinyl chloride ug/L M12015670-130130 1820ND31.3 26.1 Xylene (Total)ug/L 60 119 70-130118 060ND71.1 70.9 1,2-Dichloroethane-d4 (S)%87 70-13091 4-Bromofluorobenzene (S)%100 70-130108 Toluene-d8 (S)%97 70-13094 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:47 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 23 #=QL# QUALIFIERS Pace Project No.: Project: 92376204 HOLBROOKS RD LANDFILL (#60-02) DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C Pace Analytical Services - MinneapolisPASI-M ANALYTE QUALIFIERS Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:47 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 23 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92376204 HOLBROOKS RD LANDFILL (#60-02) Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92376204001 401294 4013926002-HRW8 EPA 3010A EPA 6010 92376204002 401294 4013926002-HRW9 EPA 3010A EPA 6010 92376204003 401294 4013926002-HRW16 EPA 3010A EPA 6010 92376204001 527206 5273736002-HRW8 EPA 3020 EPA 6020B 92376204002 527206 5273736002-HRW9 EPA 3020 EPA 6020B 92376204003 527206 5273736002-HRW16 EPA 3020 EPA 6020B 92376204001 4014676002-HRW8 EPA 8260 92376204002 4014676002-HRW9 EPA 8260 92376204003 4014676002-HRW16 EPA 8260 92376204004 401467TRIP BLANK EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/16/2018 06:47 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 23 Page 21 of 23 Page 22 of 23 Page 23 of 23 #=CL# March 19, 2018 LIMS USE: FR - AMBER GRZYMSKI LIMS OBJECT ID: 92376367 92376367 Project: Pace Project No.: RE: Amber Grzymski Mecklenburg County Solid Waste 2145 Suttle Avenue Charlotte, NC 28208 HOLBROOKS ROAD LANDFILL (PERMI Dear Amber Grzymski: Enclosed are the analytical results for sample(s) received by the laboratory on March 09, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com Project Manager (704)875-9092 Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 23 #=CP# CERTIFICATIONS Pace Project No.: Project: 92376367 HOLBROOKS ROAD LANDFILL (PERMI Minnesota Certification IDs 1700 Elm Street SE, Suite 200, Minneapolis, MN 55414- 2485 A2LA Certification #: 2926.01 Alabama Certification #: 40770 Alaska Contaminated Sites Certification #: 17-009 Alaska DW Certification #: MN00064 Arizona Certification #: AZ0014 Arkansas Certification #: 88-0680 California Certification #: 2929 CNMI Saipan Certification #:MP0003 Colorado Certification #: MN00064 Connecticut Certification #: PH-0256 EPA Region 8+Wyoming DW Certification #: via MN 027- 053-137 Florida Certification #: E87605 Georgia Certification #: 959 Guam EPA Certification #: MN00064 Hawaii Certification #: MN00064 Idaho Certification #: MN00064 Illinois Certification #: 200011 Indiana Certification #: C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky DW Certification #: 90062 Kentucky WW Certification #: 90062 Louisiana DEQ Certification #: 03086 Louisiana DW Certification #: MN00064 Maine Certification #: MN00064 Maryland Certification #: 322 Massachusetts Certification #: M-MN064 Michigan Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: MN00064 Montana Certification #: CERT0092 Nebraska Certification #: NE-OS-18-06 Nevada Certification #: MN00064 New Hampshire Certification #: 2081 New Jersey Certification #: MN002 New York Certification #: 11647 North Carolina DW Certification #: 27700 North Carolina WW Certification #: 530 North Dakota Certification #: R-036 Ohio DW Certification #: 41244 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon NwTPH Certification #: MN300001 Oregon Secondary Certification #: MN200001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification #: MN00064 South Carolina Certification #:74003001 Tennessee Certification #: TN02818 Texas Certification #: T104704192 Utah Certification #: MN00064 Virginia Certification #: 460163 Washington Certification #: C486 West Virginia DW Certification #: 9952 C West Virginia DEP Certification #: 382 Wisconsin Certification #: 999407970 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 23 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92376367 HOLBROOKS ROAD LANDFILL (PERMI Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92376367001 6002-HRSW2 EPA 6010 15 PASI-ASH1 EPA 6020B 1 PASI-MTT3 EPA 8260 52 PASI-CSWB 92376367002 6002-HRSW3 EPA 6010 15 PASI-ASH1 EPA 6020B 1 PASI-MTT3 EPA 8260 52 PASI-CSWB 92376367003 6002-HRSW4 EPA 6010 15 PASI-ASH1 EPA 6020B 1 PASI-MTT3 EPA 8260 52 PASI-CSWB 92376367004 TRIP BLANK EPA 8260 52 PASI-CSWB REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 23 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376367 HOLBROOKS ROAD LANDFILL (PERMI Sample:6002-HRSW2 Lab ID:92376367001 Collected:03/09/18 11:09 Received:03/09/18 12:09 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 03/17/18 03:02 7440-36-003/10/18 04:205.0 1 Arsenic ND ug/L 03/17/18 03:02 7440-38-203/10/18 04:2010.0 1 Barium 48.5 ug/L 03/17/18 03:02 7440-39-303/10/18 04:205.0 1 Beryllium ND ug/L 03/17/18 03:02 7440-41-703/10/18 04:201.0 1 Cadmium ND ug/L 03/17/18 03:02 7440-43-903/10/18 04:201.0 1 Chromium ND ug/L 03/17/18 03:02 7440-47-303/10/18 04:205.0 1 Cobalt ND ug/L 03/17/18 03:02 7440-48-403/10/18 04:205.0 1 Copper 6.1 ug/L 03/17/18 03:02 7440-50-803/10/18 04:205.0 1 Lead ND ug/L 03/17/18 03:02 7439-92-103/10/18 04:205.0 1 Nickel ND ug/L 03/17/18 03:02 7440-02-003/10/18 04:205.0 1 Selenium ND ug/L 03/17/18 03:02 7782-49-203/10/18 04:2010.0 1 Silver ND ug/L 03/17/18 03:02 7440-22-403/10/18 04:205.0 1 Thallium ND ug/L 03/17/18 03:02 7440-28-003/10/18 04:2010.0 1 Vanadium 12.4 ug/L 03/17/18 03:02 7440-62-203/10/18 04:205.0 1 Zinc ND ug/L 03/17/18 03:02 7440-66-603/10/18 04:2010.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 30206020B MET ICPMS Thallium ND ug/L 03/15/18 13:47 7440-28-003/14/18 10:250.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 03/11/18 04:16 67-64-125.0 1 Acrylonitrile ND ug/L 03/11/18 04:16 107-13-110.0 1 Benzene ND ug/L 03/11/18 04:16 71-43-21.0 1 Bromochloromethane ND ug/L 03/11/18 04:16 74-97-51.0 1 Bromodichloromethane ND ug/L 03/11/18 04:16 75-27-41.0 1 Bromoform ND ug/L 03/11/18 04:16 75-25-21.0 1 Bromomethane ND ug/L 03/11/18 04:16 74-83-92.0 1 2-Butanone (MEK)ND ug/L 03/11/18 04:16 78-93-35.0 1 Carbon disulfide ND ug/L 03/11/18 04:16 75-15-02.0 1 Carbon tetrachloride ND ug/L 03/11/18 04:16 56-23-51.0 1 Chlorobenzene ND ug/L 03/11/18 04:16 108-90-71.0 1 Chloroethane ND ug/L 03/11/18 04:16 75-00-31.0 1 Chloroform ND ug/L 03/11/18 04:16 67-66-31.0 1 Chloromethane ND ug/L 03/11/18 04:16 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 03/11/18 04:16 96-12-82.0 1 Dibromochloromethane ND ug/L 03/11/18 04:16 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 03/11/18 04:16 106-93-41.0 1 Dibromomethane ND ug/L 03/11/18 04:16 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 03/11/18 04:16 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 03/11/18 04:16 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 03/11/18 04:16 110-57-61.0 1 1,1-Dichloroethane ND ug/L 03/11/18 04:16 75-34-31.0 1 1,2-Dichloroethane ND ug/L 03/11/18 04:16 107-06-21.0 1 1,1-Dichloroethene ND ug/L 03/11/18 04:16 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 03/11/18 04:16 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 03/11/18 04:16 156-60-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/19/2018 06:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 23 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376367 HOLBROOKS ROAD LANDFILL (PERMI Sample:6002-HRSW2 Lab ID:92376367001 Collected:03/09/18 11:09 Received:03/09/18 12:09 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 1,2-Dichloropropane ND ug/L 03/11/18 04:16 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 03/11/18 04:16 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 03/11/18 04:16 10061-02-61.0 1 Ethylbenzene ND ug/L 03/11/18 04:16 100-41-41.0 1 2-Hexanone ND ug/L 03/11/18 04:16 591-78-65.0 1 Iodomethane ND ug/L 03/11/18 04:16 74-88-45.0 1 Methylene Chloride ND ug/L 03/11/18 04:16 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 03/11/18 04:16 108-10-15.0 1 Styrene ND ug/L 03/11/18 04:16 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 03/11/18 04:16 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 03/11/18 04:16 79-34-51.0 1 Tetrachloroethene ND ug/L 03/11/18 04:16 127-18-41.0 1 Toluene ND ug/L 03/11/18 04:16 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 03/11/18 04:16 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 03/11/18 04:16 79-00-51.0 1 Trichloroethene ND ug/L 03/11/18 04:16 79-01-61.0 1 Trichlorofluoromethane ND ug/L 03/11/18 04:16 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 03/11/18 04:16 96-18-41.0 1 Vinyl acetate ND ug/L 03/11/18 04:16 108-05-42.0 1 Vinyl chloride ND ug/L 03/11/18 04:16 75-01-41.0 1 Xylene (Total)ND ug/L 03/11/18 04:16 1330-20-71.0 1 m&p-Xylene ND ug/L 03/11/18 04:16 179601-23-12.0 1 o-Xylene ND ug/L 03/11/18 04:16 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)94 %03/11/18 04:16 460-00-470-130 1 1,2-Dichloroethane-d4 (S)96 %03/11/18 04:16 17060-07-070-130 1 Toluene-d8 (S)102 %03/11/18 04:16 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/19/2018 06:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 23 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376367 HOLBROOKS ROAD LANDFILL (PERMI Sample:6002-HRSW3 Lab ID:92376367002 Collected:03/09/18 10:53 Received:03/09/18 12:09 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 03/17/18 03:05 7440-36-003/10/18 04:205.0 1 Arsenic ND ug/L 03/17/18 03:05 7440-38-203/10/18 04:2010.0 1 Barium 52.6 ug/L 03/17/18 03:05 7440-39-303/10/18 04:205.0 1 Beryllium ND ug/L 03/17/18 03:05 7440-41-703/10/18 04:201.0 1 Cadmium ND ug/L 03/17/18 03:05 7440-43-903/10/18 04:201.0 1 Chromium ND ug/L 03/17/18 03:05 7440-47-303/10/18 04:205.0 1 Cobalt ND ug/L 03/17/18 03:05 7440-48-403/10/18 04:205.0 1 Copper 5.6 ug/L 03/17/18 03:05 7440-50-803/10/18 04:205.0 1 Lead ND ug/L 03/17/18 03:05 7439-92-103/10/18 04:205.0 1 Nickel ND ug/L 03/17/18 03:05 7440-02-003/10/18 04:205.0 1 Selenium ND ug/L 03/17/18 03:05 7782-49-203/10/18 04:2010.0 1 Silver ND ug/L 03/17/18 03:05 7440-22-403/10/18 04:205.0 1 Thallium ND ug/L 03/17/18 03:05 7440-28-003/10/18 04:2010.0 1 Vanadium 12.0 ug/L 03/17/18 03:05 7440-62-203/10/18 04:205.0 1 Zinc ND ug/L 03/17/18 03:05 7440-66-603/10/18 04:2010.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 30206020B MET ICPMS Thallium ND ug/L 03/15/18 14:41 7440-28-003/14/18 10:250.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 03/11/18 04:34 67-64-125.0 1 Acrylonitrile ND ug/L 03/11/18 04:34 107-13-110.0 1 Benzene ND ug/L 03/11/18 04:34 71-43-21.0 1 Bromochloromethane ND ug/L 03/11/18 04:34 74-97-51.0 1 Bromodichloromethane ND ug/L 03/11/18 04:34 75-27-41.0 1 Bromoform ND ug/L 03/11/18 04:34 75-25-21.0 1 Bromomethane ND ug/L 03/11/18 04:34 74-83-92.0 1 2-Butanone (MEK)ND ug/L 03/11/18 04:34 78-93-35.0 1 Carbon disulfide ND ug/L 03/11/18 04:34 75-15-02.0 1 Carbon tetrachloride ND ug/L 03/11/18 04:34 56-23-51.0 1 Chlorobenzene ND ug/L 03/11/18 04:34 108-90-71.0 1 Chloroethane ND ug/L 03/11/18 04:34 75-00-31.0 1 Chloroform ND ug/L 03/11/18 04:34 67-66-31.0 1 Chloromethane ND ug/L 03/11/18 04:34 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 03/11/18 04:34 96-12-82.0 1 Dibromochloromethane ND ug/L 03/11/18 04:34 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 03/11/18 04:34 106-93-41.0 1 Dibromomethane ND ug/L 03/11/18 04:34 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 03/11/18 04:34 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 03/11/18 04:34 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 03/11/18 04:34 110-57-61.0 1 1,1-Dichloroethane ND ug/L 03/11/18 04:34 75-34-31.0 1 1,2-Dichloroethane ND ug/L 03/11/18 04:34 107-06-21.0 1 1,1-Dichloroethene ND ug/L 03/11/18 04:34 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 03/11/18 04:34 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 03/11/18 04:34 156-60-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/19/2018 06:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 23 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376367 HOLBROOKS ROAD LANDFILL (PERMI Sample:6002-HRSW3 Lab ID:92376367002 Collected:03/09/18 10:53 Received:03/09/18 12:09 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 1,2-Dichloropropane ND ug/L 03/11/18 04:34 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 03/11/18 04:34 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 03/11/18 04:34 10061-02-61.0 1 Ethylbenzene ND ug/L 03/11/18 04:34 100-41-41.0 1 2-Hexanone ND ug/L 03/11/18 04:34 591-78-65.0 1 Iodomethane ND ug/L 03/11/18 04:34 74-88-45.0 1 Methylene Chloride ND ug/L 03/11/18 04:34 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 03/11/18 04:34 108-10-15.0 1 Styrene ND ug/L 03/11/18 04:34 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 03/11/18 04:34 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 03/11/18 04:34 79-34-51.0 1 Tetrachloroethene ND ug/L 03/11/18 04:34 127-18-41.0 1 Toluene ND ug/L 03/11/18 04:34 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 03/11/18 04:34 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 03/11/18 04:34 79-00-51.0 1 Trichloroethene ND ug/L 03/11/18 04:34 79-01-61.0 1 Trichlorofluoromethane ND ug/L 03/11/18 04:34 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 03/11/18 04:34 96-18-41.0 1 Vinyl acetate ND ug/L 03/11/18 04:34 108-05-42.0 1 Vinyl chloride ND ug/L 03/11/18 04:34 75-01-41.0 1 Xylene (Total)ND ug/L 03/11/18 04:34 1330-20-71.0 1 m&p-Xylene ND ug/L 03/11/18 04:34 179601-23-12.0 1 o-Xylene ND ug/L 03/11/18 04:34 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)94 %03/11/18 04:34 460-00-470-130 1 1,2-Dichloroethane-d4 (S)91 %03/11/18 04:34 17060-07-070-130 1 Toluene-d8 (S)102 %03/11/18 04:34 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/19/2018 06:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 23 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376367 HOLBROOKS ROAD LANDFILL (PERMI Sample:6002-HRSW4 Lab ID:92376367003 Collected:03/09/18 10:21 Received:03/09/18 12:09 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 03/17/18 03:08 7440-36-003/10/18 04:205.0 1 Arsenic ND ug/L 03/17/18 03:08 7440-38-203/10/18 04:2010.0 1 Barium 48.0 ug/L 03/17/18 03:08 7440-39-303/10/18 04:205.0 1 Beryllium ND ug/L 03/17/18 03:08 7440-41-703/10/18 04:201.0 1 Cadmium ND ug/L 03/17/18 03:08 7440-43-903/10/18 04:201.0 1 Chromium ND ug/L 03/17/18 03:08 7440-47-303/10/18 04:205.0 1 Cobalt ND ug/L 03/17/18 03:08 7440-48-403/10/18 04:205.0 1 Copper 6.3 ug/L 03/17/18 03:08 7440-50-803/10/18 04:205.0 1 Lead ND ug/L 03/17/18 03:08 7439-92-103/10/18 04:205.0 1 Nickel ND ug/L 03/17/18 03:08 7440-02-003/10/18 04:205.0 1 Selenium ND ug/L 03/17/18 03:08 7782-49-203/10/18 04:2010.0 1 Silver ND ug/L 03/17/18 03:08 7440-22-403/10/18 04:205.0 1 Thallium ND ug/L 03/17/18 03:08 7440-28-003/10/18 04:2010.0 1 Vanadium 12.4 ug/L 03/17/18 03:08 7440-62-203/10/18 04:205.0 1 Zinc ND ug/L 03/17/18 03:08 7440-66-603/10/18 04:2010.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 30206020B MET ICPMS Thallium ND ug/L 03/15/18 14:44 7440-28-003/14/18 10:250.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 03/11/18 03:58 67-64-125.0 1 Acrylonitrile ND ug/L 03/11/18 03:58 107-13-110.0 1 Benzene ND ug/L 03/11/18 03:58 71-43-21.0 1 Bromochloromethane ND ug/L 03/11/18 03:58 74-97-51.0 1 Bromodichloromethane ND ug/L 03/11/18 03:58 75-27-41.0 1 Bromoform ND ug/L 03/11/18 03:58 75-25-21.0 1 Bromomethane ND ug/L 03/11/18 03:58 74-83-92.0 1 2-Butanone (MEK)ND ug/L 03/11/18 03:58 78-93-35.0 1 Carbon disulfide ND ug/L 03/11/18 03:58 75-15-02.0 1 Carbon tetrachloride ND ug/L 03/11/18 03:58 56-23-51.0 1 Chlorobenzene ND ug/L 03/11/18 03:58 108-90-71.0 1 Chloroethane ND ug/L 03/11/18 03:58 75-00-31.0 1 Chloroform ND ug/L 03/11/18 03:58 67-66-31.0 1 Chloromethane ND ug/L 03/11/18 03:58 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 03/11/18 03:58 96-12-82.0 1 Dibromochloromethane ND ug/L 03/11/18 03:58 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 03/11/18 03:58 106-93-41.0 1 Dibromomethane ND ug/L 03/11/18 03:58 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 03/11/18 03:58 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 03/11/18 03:58 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 03/11/18 03:58 110-57-61.0 1 1,1-Dichloroethane ND ug/L 03/11/18 03:58 75-34-31.0 1 1,2-Dichloroethane ND ug/L 03/11/18 03:58 107-06-21.0 1 1,1-Dichloroethene ND ug/L 03/11/18 03:58 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 03/11/18 03:58 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 03/11/18 03:58 156-60-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/19/2018 06:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 23 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376367 HOLBROOKS ROAD LANDFILL (PERMI Sample:6002-HRSW4 Lab ID:92376367003 Collected:03/09/18 10:21 Received:03/09/18 12:09 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 1,2-Dichloropropane ND ug/L 03/11/18 03:58 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 03/11/18 03:58 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 03/11/18 03:58 10061-02-61.0 1 Ethylbenzene ND ug/L 03/11/18 03:58 100-41-41.0 1 2-Hexanone ND ug/L 03/11/18 03:58 591-78-65.0 1 Iodomethane ND ug/L 03/11/18 03:58 74-88-45.0 1 Methylene Chloride ND ug/L 03/11/18 03:58 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 03/11/18 03:58 108-10-15.0 1 Styrene ND ug/L 03/11/18 03:58 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 03/11/18 03:58 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 03/11/18 03:58 79-34-51.0 1 Tetrachloroethene ND ug/L 03/11/18 03:58 127-18-41.0 1 Toluene ND ug/L 03/11/18 03:58 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 03/11/18 03:58 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 03/11/18 03:58 79-00-51.0 1 Trichloroethene ND ug/L 03/11/18 03:58 79-01-61.0 1 Trichlorofluoromethane ND ug/L 03/11/18 03:58 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 03/11/18 03:58 96-18-41.0 1 Vinyl acetate ND ug/L 03/11/18 03:58 108-05-42.0 1 Vinyl chloride ND ug/L 03/11/18 03:58 75-01-41.0 1 Xylene (Total)ND ug/L 03/11/18 03:58 1330-20-71.0 1 m&p-Xylene ND ug/L 03/11/18 03:58 179601-23-12.0 1 o-Xylene ND ug/L 03/11/18 03:58 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)97 %03/11/18 03:58 460-00-470-130 1 1,2-Dichloroethane-d4 (S)93 %03/11/18 03:58 17060-07-070-130 1 Toluene-d8 (S)94 %03/11/18 03:58 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/19/2018 06:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 23 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376367 HOLBROOKS ROAD LANDFILL (PERMI Sample:TRIP BLANK Lab ID:92376367004 Collected:03/09/18 00:00 Received:03/09/18 12:09 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 03/11/18 04:52 67-64-125.0 1 Acrylonitrile ND ug/L 03/11/18 04:52 107-13-110.0 1 Benzene ND ug/L 03/11/18 04:52 71-43-21.0 1 Bromochloromethane ND ug/L 03/11/18 04:52 74-97-51.0 1 Bromodichloromethane ND ug/L 03/11/18 04:52 75-27-41.0 1 Bromoform ND ug/L 03/11/18 04:52 75-25-21.0 1 Bromomethane ND ug/L 03/11/18 04:52 74-83-92.0 1 2-Butanone (MEK)ND ug/L 03/11/18 04:52 78-93-35.0 1 Carbon disulfide ND ug/L 03/11/18 04:52 75-15-02.0 1 Carbon tetrachloride ND ug/L 03/11/18 04:52 56-23-51.0 1 Chlorobenzene ND ug/L 03/11/18 04:52 108-90-71.0 1 Chloroethane ND ug/L 03/11/18 04:52 75-00-31.0 1 Chloroform ND ug/L 03/11/18 04:52 67-66-31.0 1 Chloromethane ND ug/L 03/11/18 04:52 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 03/11/18 04:52 96-12-82.0 1 Dibromochloromethane ND ug/L 03/11/18 04:52 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 03/11/18 04:52 106-93-41.0 1 Dibromomethane ND ug/L 03/11/18 04:52 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 03/11/18 04:52 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 03/11/18 04:52 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 03/11/18 04:52 110-57-61.0 1 1,1-Dichloroethane ND ug/L 03/11/18 04:52 75-34-31.0 1 1,2-Dichloroethane ND ug/L 03/11/18 04:52 107-06-21.0 1 1,1-Dichloroethene ND ug/L 03/11/18 04:52 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 03/11/18 04:52 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 03/11/18 04:52 156-60-51.0 1 1,2-Dichloropropane ND ug/L 03/11/18 04:52 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 03/11/18 04:52 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 03/11/18 04:52 10061-02-61.0 1 Ethylbenzene ND ug/L 03/11/18 04:52 100-41-41.0 1 2-Hexanone ND ug/L 03/11/18 04:52 591-78-65.0 1 Iodomethane ND ug/L 03/11/18 04:52 74-88-45.0 1 Methylene Chloride ND ug/L 03/11/18 04:52 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 03/11/18 04:52 108-10-15.0 1 Styrene ND ug/L 03/11/18 04:52 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 03/11/18 04:52 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 03/11/18 04:52 79-34-51.0 1 Tetrachloroethene ND ug/L 03/11/18 04:52 127-18-41.0 1 Toluene ND ug/L 03/11/18 04:52 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 03/11/18 04:52 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 03/11/18 04:52 79-00-51.0 1 Trichloroethene ND ug/L 03/11/18 04:52 79-01-61.0 1 Trichlorofluoromethane ND ug/L 03/11/18 04:52 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 03/11/18 04:52 96-18-41.0 1 Vinyl acetate ND ug/L 03/11/18 04:52 108-05-42.0 1 Vinyl chloride ND ug/L 03/11/18 04:52 75-01-41.0 1 Xylene (Total)ND ug/L 03/11/18 04:52 1330-20-71.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/19/2018 06:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 23 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92376367 HOLBROOKS ROAD LANDFILL (PERMI Sample:TRIP BLANK Lab ID:92376367004 Collected:03/09/18 00:00 Received:03/09/18 12:09 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill m&p-Xylene ND ug/L 03/11/18 04:52 179601-23-12.0 1 o-Xylene ND ug/L 03/11/18 04:52 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)93 %03/11/18 04:52 460-00-470-130 1 1,2-Dichloroethane-d4 (S)93 %03/11/18 04:52 17060-07-070-130 1 Toluene-d8 (S)96 %03/11/18 04:52 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/19/2018 06:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 23 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376367 HOLBROOKS ROAD LANDFILL (PERMI Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 401451 EPA 3010A EPA 6010 6010 MET Associated Lab Samples:92376367001, 92376367002, 92376367003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2226935 Associated Lab Samples:92376367001, 92376367002, 92376367003 Matrix:Water Analyzed Antimony ug/L ND 5.0 03/17/18 02:47 Arsenic ug/L ND 10.0 03/17/18 02:47 Barium ug/L ND 5.0 03/17/18 02:47 Beryllium ug/L ND 1.0 03/17/18 02:47 Cadmium ug/L ND 1.0 03/17/18 02:47 Chromium ug/L ND 5.0 03/17/18 02:47 Cobalt ug/L ND 5.0 03/17/18 02:47 Copper ug/L ND 5.0 03/17/18 02:47 Lead ug/L ND 5.0 03/17/18 02:47 Nickel ug/L ND 5.0 03/17/18 02:47 Selenium ug/L ND 10.0 03/17/18 02:47 Silver ug/L ND 5.0 03/17/18 02:47 Thallium ug/L ND 10.0 03/17/18 02:47 Vanadium ug/L ND 5.0 03/17/18 02:47 Zinc ug/L ND 10.0 03/17/18 02:47 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2226936LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 506500 101 80-120 Arsenic ug/L 463500 93 80-120 Barium ug/L 500500 100 80-120 Beryllium ug/L 447500 89 80-120 Cadmium ug/L 464500 93 80-120 Chromium ug/L 472500 94 80-120 Cobalt ug/L 490500 98 80-120 Copper ug/L 454500 91 80-120 Lead ug/L 493500 99 80-120 Nickel ug/L 450500 90 80-120 Selenium ug/L 521500 104 80-120 Silver ug/L 240250 96 80-120 Thallium ug/L 460500 92 80-120 Vanadium ug/L 463500 93 80-120 Zinc ug/L 491500 98 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/19/2018 06:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 23 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376367 HOLBROOKS ROAD LANDFILL (PERMI Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2226937MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92376383002 2226938 MSD Result MSD % Rec RPD MSDMS Spike Conc. Antimony ug/L 500 103 75-125104 1500ND516522 Arsenic ug/L 500 95 75-12595 1500ND475478 Barium ug/L 500 101 75-125103 250022.0 529 537 Beryllium ug/L 500 93 75-12594 2500ND465472 Cadmium ug/L 500 94 75-12595 1500ND472477 Chromium ug/L 500 96 75-12597 2500ND480487 Cobalt ug/L 500 98 75-12599 1500ND492497 Copper ug/L 500 93 75-12594 1500ND466471 Lead ug/L 500 99 75-12599 0500ND495494 Nickel ug/L 500 92 75-12593 15006.1 464 469 Selenium ug/L 500 104 75-125104 0500ND519520 Silver ug/L 250 98 75-12598 0250ND245246 Thallium ug/L 500 93 75-12593 0500ND465465 Vanadium ug/L 500 96 75-12598 2500ND484492 Zinc ug/L 500 99 75-125100 1500ND497501 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/19/2018 06:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 23 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376367 HOLBROOKS ROAD LANDFILL (PERMI Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 527206 EPA 3020 EPA 6020B 6020B Water UPD5 Associated Lab Samples:92376367001, 92376367002, 92376367003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2860303 Associated Lab Samples:92376367001, 92376367002, 92376367003 Matrix:Water Analyzed Thallium ug/L ND 0.10 03/15/18 13:32 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2860304LABORATORY CONTROL SAMPLE: LCSSpike Thallium ug/L 101100 101 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 2860305MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92376367001 2860306 MSD Result MSD % Rec RPD MSDMS Spike Conc. Thallium ug/L 100 99 75-125106 7100ND99.2 106 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/19/2018 06:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 23 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376367 HOLBROOKS ROAD LANDFILL (PERMI Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 401467 EPA 8260 EPA 8260 8260 MSV Low Level Landfill Associated Lab Samples:92376367001, 92376367002, 92376367003, 92376367004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2227009 Associated Lab Samples:92376367001, 92376367002, 92376367003, 92376367004 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 03/11/18 00:54 1,1,1-Trichloroethane ug/L ND 1.0 03/11/18 00:54 1,1,2,2-Tetrachloroethane ug/L ND 1.0 03/11/18 00:54 1,1,2-Trichloroethane ug/L ND 1.0 03/11/18 00:54 1,1-Dichloroethane ug/L ND 1.0 03/11/18 00:54 1,1-Dichloroethene ug/L ND 1.0 03/11/18 00:54 1,2,3-Trichloropropane ug/L ND 1.0 03/11/18 00:54 1,2-Dibromo-3-chloropropane ug/L ND 2.0 03/11/18 00:54 1,2-Dibromoethane (EDB)ug/L ND 1.0 03/11/18 00:54 1,2-Dichlorobenzene ug/L ND 1.0 03/11/18 00:54 1,2-Dichloroethane ug/L ND 1.0 03/11/18 00:54 1,2-Dichloropropane ug/L ND 1.0 03/11/18 00:54 1,4-Dichlorobenzene ug/L ND 1.0 03/11/18 00:54 2-Butanone (MEK)ug/L ND 5.0 03/11/18 00:54 2-Hexanone ug/L ND 5.0 03/11/18 00:54 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 03/11/18 00:54 Acetone ug/L ND 25.0 03/11/18 00:54 Acrylonitrile ug/L ND 10.0 03/11/18 00:54 Benzene ug/L ND 1.0 03/11/18 00:54 Bromochloromethane ug/L ND 1.0 03/11/18 00:54 Bromodichloromethane ug/L ND 1.0 03/11/18 00:54 Bromoform ug/L ND 1.0 03/11/18 00:54 Bromomethane ug/L ND 2.0 03/11/18 00:54 Carbon disulfide ug/L ND 2.0 03/11/18 00:54 Carbon tetrachloride ug/L ND 1.0 03/11/18 00:54 Chlorobenzene ug/L ND 1.0 03/11/18 00:54 Chloroethane ug/L ND 1.0 03/11/18 00:54 Chloroform ug/L ND 1.0 03/11/18 00:54 Chloromethane ug/L ND 1.0 03/11/18 00:54 cis-1,2-Dichloroethene ug/L ND 1.0 03/11/18 00:54 cis-1,3-Dichloropropene ug/L ND 1.0 03/11/18 00:54 Dibromochloromethane ug/L ND 1.0 03/11/18 00:54 Dibromomethane ug/L ND 1.0 03/11/18 00:54 Ethylbenzene ug/L ND 1.0 03/11/18 00:54 Iodomethane ug/L ND 5.0 03/11/18 00:54 m&p-Xylene ug/L ND 2.0 03/11/18 00:54 Methylene Chloride ug/L ND 1.0 03/11/18 00:54 o-Xylene ug/L ND 1.0 03/11/18 00:54 Styrene ug/L ND 1.0 03/11/18 00:54 Tetrachloroethene ug/L ND 1.0 03/11/18 00:54 Toluene ug/L ND 1.0 03/11/18 00:54 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/19/2018 06:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 23 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376367 HOLBROOKS ROAD LANDFILL (PERMI Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2227009 Associated Lab Samples:92376367001, 92376367002, 92376367003, 92376367004 Matrix:Water Analyzed trans-1,2-Dichloroethene ug/L ND 1.0 03/11/18 00:54 trans-1,3-Dichloropropene ug/L ND 1.0 03/11/18 00:54 trans-1,4-Dichloro-2-butene ug/L ND 1.0 03/11/18 00:54 Trichloroethene ug/L ND 1.0 03/11/18 00:54 Trichlorofluoromethane ug/L ND 1.0 03/11/18 00:54 Vinyl acetate ug/L ND 2.0 03/11/18 00:54 Vinyl chloride ug/L ND 1.0 03/11/18 00:54 Xylene (Total)ug/L ND 1.0 03/11/18 00:54 1,2-Dichloroethane-d4 (S)%87 70-130 03/11/18 00:54 4-Bromofluorobenzene (S)%94 70-130 03/11/18 00:54 Toluene-d8 (S)%99 70-130 03/11/18 00:54 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2227010LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 56.150 112 80-125 1,1,1-Trichloroethane ug/L 46.850 94 71-129 1,1,2,2-Tetrachloroethane ug/L 50.950 102 79-124 1,1,2-Trichloroethane ug/L 51.150 102 85-125 1,1-Dichloroethane ug/L 42.850 86 73-126 1,1-Dichloroethene ug/L 45.250 90 66-135 1,2,3-Trichloropropane ug/L 51.350 103 75-130 1,2-Dibromo-3-chloropropane ug/L 62.250 124 71-133 1,2-Dibromoethane (EDB)ug/L 56.250 112 83-124 1,2-Dichlorobenzene ug/L 55.650 111 80-133 1,2-Dichloroethane ug/L 43.550 87 67-128 1,2-Dichloropropane ug/L 51.050 102 75-132 1,4-Dichlorobenzene ug/L 54.350 109 78-130 2-Butanone (MEK)ug/L 111100 111 61-144 2-Hexanone ug/L 114100 114 68-143 4-Methyl-2-pentanone (MIBK)ug/L 99.6100 100 72-135 Acetone ug/L 118100 118 48-146 Acrylonitrile ug/L 257250 103 40-160 Benzene ug/L 48.250 96 80-125 Bromochloromethane ug/L 49.050 98 71-125 Bromodichloromethane ug/L 48.750 97 78-124 Bromoform ug/L 58.550 117 71-128 Bromomethane ug/L 35.450 71 40-160 Carbon disulfide ug/L 35.950 72 50-160 Carbon tetrachloride ug/L 48.650 97 69-131 Chlorobenzene ug/L 52.050 104 81-122 Chloroethane ug/L 33.750 67 39-148 Chloroform ug/L 41.850 84 73-127 Chloromethane ug/L 41.950 84 44-146 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/19/2018 06:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 23 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376367 HOLBROOKS ROAD LANDFILL (PERMI Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2227010LABORATORY CONTROL SAMPLE: LCSSpike cis-1,2-Dichloroethene ug/L 45.150 90 74-124 cis-1,3-Dichloropropene ug/L 49.450 99 72-132 Dibromochloromethane ug/L 59.250 118 78-125 Dibromomethane ug/L 52.650 105 82-120 Ethylbenzene ug/L 50.050 100 79-121 Iodomethane ug/L 72.1100 72 39-154 m&p-Xylene ug/L 101100 101 81-124 Methylene Chloride ug/L 47.650 95 64-133 o-Xylene ug/L 53.050 106 79-131 Styrene ug/L 51.950 104 84-126 Tetrachloroethene ug/L 46.950 94 78-122 Toluene ug/L 44.750 89 80-121 trans-1,2-Dichloroethene ug/L 44.850 90 71-127 trans-1,3-Dichloropropene ug/L 48.550 97 69-141 trans-1,4-Dichloro-2-butene ug/L 64.750 129 40-160 Trichloroethene ug/L 50.350 101 78-122 Trichlorofluoromethane ug/L 38.350 77 53-137 Vinyl acetate ug/L 81.9100 82 40-160 Vinyl chloride ug/L 46.150 92 58-137 Xylene (Total)ug/L 154150 103 81-126 1,2-Dichloroethane-d4 (S)%94 70-130 4-Bromofluorobenzene (S)%93 70-130 Toluene-d8 (S)%96 70-130 Parameter Units MS Result % Rec Limits Qual% RecConc. 2227011MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92376383002 2227012 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 20 121 70-130125 320ND24.2 25.0 1,1,1-Trichloroethane ug/L 20 119 70-130116 320ND23.8 23.2 1,1,2,2-Tetrachloroethane ug/L 20 114 70-130125 920ND22.7 25.0 1,1,2-Trichloroethane ug/L M12013270-130108 2020ND26.3 21.5 1,1-Dichloroethane ug/L 20 120 70-130109 1020ND24.1 21.8 1,1-Dichloroethene ug/L 20 136 70-166124 920ND27.2 24.9 1,2,3-Trichloropropane ug/L 20 115 70-130119 320ND23.1 23.8 1,2-Dibromo-3-chloropropane ug/L 20 123 70-130119 320ND24.5 23.7 1,2-Dibromoethane (EDB)ug/L 20 113 70-130111 220ND22.7 22.1 1,2-Dichlorobenzene ug/L 20 115 70-130111 420ND23.0 22.1 1,2-Dichloroethane ug/L 20 99 70-13097 220ND19.9 19.4 1,2-Dichloropropane ug/L 20 110 70-130111 120ND22.0 22.2 1,4-Dichlorobenzene ug/L 20 114 70-130111 320ND22.8 22.2 2-Butanone (MEK)ug/L 40 107 70-130107 040ND42.9 42.7 2-Hexanone ug/L 40 107 70-130107 040ND42.9 42.7 4-Methyl-2-pentanone (MIBK)ug/L 40 120 70-130101 1740ND48.1 40.4 Acetone ug/L 40 119 70-130105 1240ND47.5 41.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/19/2018 06:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 23 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92376367 HOLBROOKS ROAD LANDFILL (PERMI Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2227011MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92376383002 2227012 MSD Result MSD % Rec RPD MSDMS Spike Conc. Acrylonitrile ug/L 100 121 70-130112 7100ND121112 Benzene ug/L 20 121 70-148114 620ND24.1 22.7 Bromochloromethane ug/L 20 120 70-130116 420ND24.0 23.1 Bromodichloromethane ug/L 20 110 70-130113 320ND22.0 22.6 Bromoform ug/L 20 114 70-130113 220ND22.9 22.5 Bromomethane ug/L M12015570-130131 1720ND30.9 26.1 Carbon disulfide ug/L M12013470-130118 1320ND26.8 23.6 Carbon tetrachloride ug/L M12013370-130127 520ND26.6 25.4 Chlorobenzene ug/L 20 116 70-146114 220ND23.1 22.7 Chloroethane ug/L M12014770-130121 1920ND29.3 24.3 Chloroform ug/L 20 109 70-130107 320ND21.9 21.3 Chloromethane ug/L M12013170-130109 1820ND26.3 21.9 cis-1,2-Dichloroethene ug/L 20 121 70-130114 620ND24.3 22.8 cis-1,3-Dichloropropene ug/L 20 116 70-130108 620ND23.1 21.7 Dibromochloromethane ug/L 20 105 70-130109 420ND20.9 21.7 Dibromomethane ug/L 20 111 70-130115 320ND22.3 23.0 Ethylbenzene ug/L 20 116 70-130115 120ND23.1 22.9 Iodomethane ug/L M14014170-130124 1340ND56.3 49.4 m&p-Xylene ug/L 40 118 70-130118 040ND47.0 47.0 Methylene Chloride ug/L 20 121 70-130107 1220ND24.1 21.4 o-Xylene ug/L 20 121 70-130119 120ND24.1 23.9 Styrene ug/L 20 117 70-130116 120ND23.4 23.2 Tetrachloroethene ug/L 20 94 70-13098 420ND18.8 19.6 Toluene ug/L 20 115 70-155108 720ND23.1 21.6 trans-1,2-Dichloroethene ug/L M12013470-130119 1220ND26.8 23.8 trans-1,3-Dichloropropene ug/L 20 130 70-130109 1720ND25.9 21.8 trans-1,4-Dichloro-2-butene ug/L 20 103 70-130110 720ND20.5 22.0 Trichloroethene ug/L 20 117 69-151114 320ND23.5 22.8 Trichlorofluoromethane ug/L 20 130 70-130111 1620ND26.0 22.2 Vinyl acetate ug/L 40 103 70-13097 640ND41.2 38.9 Vinyl chloride ug/L M12015670-130130 1820ND31.3 26.1 Xylene (Total)ug/L 60 119 70-130118 060ND71.1 70.9 1,2-Dichloroethane-d4 (S)%87 70-13091 4-Bromofluorobenzene (S)%100 70-130108 Toluene-d8 (S)%97 70-13094 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/19/2018 06:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 23 #=QL# QUALIFIERS Pace Project No.: Project: 92376367 HOLBROOKS ROAD LANDFILL (PERMI DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C Pace Analytical Services - MinneapolisPASI-M ANALYTE QUALIFIERS Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/19/2018 06:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 23 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92376367 HOLBROOKS ROAD LANDFILL (PERMI Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92376367001 401451 4014906002-HRSW2 EPA 3010A EPA 6010 92376367002 401451 4014906002-HRSW3 EPA 3010A EPA 6010 92376367003 401451 4014906002-HRSW4 EPA 3010A EPA 6010 92376367001 527206 5273736002-HRSW2 EPA 3020 EPA 6020B 92376367002 527206 5273736002-HRSW3 EPA 3020 EPA 6020B 92376367003 527206 5273736002-HRSW4 EPA 3020 EPA 6020B 92376367001 4014676002-HRSW2 EPA 8260 92376367002 4014676002-HRSW3 EPA 8260 92376367003 4014676002-HRSW4 EPA 8260 92376367004 401467TRIP BLANK EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 03/19/2018 06:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 23 Page 21 of 23 Page 22 of 23 Page 23 of 23