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HomeMy WebLinkAbout10001_YanceyMitchellMSWLF_1987_GWMR_FID1086147Jan 24, 2018 January 2018 Yancey-Mitchell County Closed Municipal Solid Waste Landfill Fall 2017 Semiannual Water Quality Monitoring Report Yancey County, North Carolina, Permit No. 100-01 Prepared for Yancey County, North Carolina Project Number: C61485-01.01.02 \\Asheville1\asheville\Projects\Yancey County\Solid Waste\Reports\2017\Fall\MSW LF\FINAL 100-01 Fall 2017 Water Quality Report.docx January 2018 Yancey-Mitchell County Closed Municipal Solid Waste Landfill Fall 2017 Semiannual Water Quality Monitoring Report Yancey County, North Carolina, Permit No. 100-01 Prepared for 110 Town Square Yancey County Courthouse, Room 11 Burnsville, North Carolina 28714 Prepared by Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Alec Macbeth, PG Staff 2 Geologist Fall 2017 Semiannual Water Quality Monitoring Report i January 2018 TABLE OF CONTENTS 1 Introduction ................................................................................................................................ 1 2 Methods ....................................................................................................................................... 2 2.1 Groundwater and Surface Water Sampling .............................................................................................. 2 2.1.1 Groundwater Purging and Sampling Methods ........................................................................ 2 2.1.2 Surface Water Sampling Methods ................................................................................................ 4 2.2 Sample Handling, Documentation, and Analysis .................................................................................... 4 3 Findings ........................................................................................................................................ 6 3.1 Analytical Results ................................................................................................................................................. 6 3.1.1 Groundwater Samples ....................................................................................................................... 7 3.1.2 Surface Water Samples ..................................................................................................................... 8 3.2 Hydrogeology ....................................................................................................................................................... 9 4 Summary .................................................................................................................................... 10 4.1 Future Activities ................................................................................................................................................ 10 5 References .................................................................................................................................. 11 TABLES Table 1 Monitoring Well Construction Summary Table 2 Summary of Laboratory Analyses Performed on Samples Table 3 Summary of Analytical Results FIGURES Figure 1 Site Location Map Figure 2 Sample Location and Posted Data Map Figure 3 Generalized Groundwater Flow Direction Map APPENDICES Appendix A Sampling Logs and Equipment Documentation and Instrument Calibration Data Sheets Appendix B Reports of Laboratory Analysis and Chain-of-Custody Documentation Fall 2017 Semiannual Water Quality Monitoring Report ii January 2018 ABBREVIATIONS µg/L micrograms per liter µS/cm microsiemens per centimeter Anchor QEA Anchor QEA of North Carolina, PLLC C&D Landfill construction and demolition debris landfill DEQ North Carolina Department of Environmental Quality DO dissolved oxygen DWM Division of Waste Management feet-TOC feet below the top of the well casing MDL method detection limit mg/L milligrams per liter MRL method reporting limit MSW Landfill municipal solid waste landfill mV millivolt NCAC North Carolina Administrative Code NTU nephelometric turbidity unit ORP oxidation reduction potential Prism Prism Laboratories SC specific conductivity SU standard unit SWS Solid Waste Section SWSL Solid Waste Section Limit VOC volatile organic compound Fall 2017 Semiannual Water Quality Monitoring Report 1 January 2018 1 Introduction This Fall 2017 Semiannual Water Quality Monitoring Report is presented by Anchor QEA of North Carolina, PLLC (Anchor QEA). The Yancey County Solid Waste Department operates a solid waste facility located on Landfill Road near NC Highway 80 in Burnsville, North Carolina (Figure 1). The facility accepts solid waste from both Yancey County and Mitchell County and includes the following permitted components: • A closed municipal solid waste landfill (MSW Landfill) (Permit No. 100-01) • A closed construction and demolition debris landfill (C&D Landfill) (Permit No. 100-02) • An active transfer station (Permit No. 100-03T) The approximate locations of the two landfill units within the solid waste facility are shown in Figure 2. This report addresses water quality associated with the MSW Landfill only. Water quality at the C&D Landfill is addressed in a separate report because the C&D Landfill is permitted separately under the rules codified in Title 15A, Subchapter 13B, Sections .0500 and .0601 of the North Carolina Administrative Code (NCAC) (15A NCAC 13B. 0500 and 15A NCAC 13B .0601). This report documents the second semiannual groundwater and surface water monitoring event for 2017. It is being submitted in accordance with the requirements stipulated in the letter regarding “Closure of the Yancey-Mitchell County Landfill Permit #100-01” (DENR 1995a), issued by the North Carolina Department of Environmental Quality (DEQ), Division of Waste Management (DWM) for the MSW Landfill on December 21, 1995, with regulations codified in the DEQ Solid Waste Management Rules 15A NCAC 13B .0510. The letter requires semiannual monitoring of groundwater and surface water quality. This report provides an evaluation of surface water and groundwater quality for the MSW Landfill. The water quality monitoring network for the MSW Landfill consists of four compliance monitoring wells (MW 2, MW-3, MW-AR, and MW-B), one background monitoring well (MW-J), and two surface water sampling locations (SW-1 and SW-2) positioned along the North Toe River (Figure 2). Fall 2017 Semiannual Water Quality Monitoring Report 2 January 2018 2 Methods 2.1 Groundwater and Surface Water Sampling On September 26 and 27, 2017, groundwater and surface water samples were collected by Anchor QEA. Sampling locations are shown in Figure 2. Summaries of monitoring well construction and water level measurement are presented in Table 1. This table includes both the closed MSW Landfill wells and the closed C&D Landfill wells to provide a more comprehensive dataset for evaluating groundwater flow direction. Table 2 provides a list of groundwater and surface water samples collected from the MSW Landfill and the analyses performed on each sample. 2.1.1 Groundwater Purging and Sampling Methods Groundwater purging and sampling was performed using either a disposable bailer or downhole pump, as described in Sections 2.1.1.1 through 2.1.1.3. Prior to purging and sampling of the monitoring wells, the static water level was gauged with a decontaminated Geotech ET Water Level Meter. Field parameters—pH, specific conductivity (SC), dissolved oxygen (DO), turbidity, oxidation reduction potential (ORP), and temperature—were measured and recorded during purging with a YSI 556 Multiprobe Water Quality Meter. Well sampling logs with static water level measurements and the field parameter data are included in Appendix A. Static water level measurements are also provided in Table 1. Groundwater samples were collected after the monitoring wells had been purged and field parameters had stabilized. When monitoring wells were purged with a disposable bailer, a minimum of three well volumes was purged from the monitoring well, or if the monitoring well recharged slowly, the monitoring well was bailed dry and allowed to recharge prior to sampling. The total depth of each monitoring well, the condition of the well casing, the groundwater recharge rate as determined during purging, and the respective sample collection method(s) used were recorded in sampling logs, provided in Appendix A. Groundwater purging and sampling was performed by Anchor QEA personnel wearing new nitrile gloves, and samples were collected in laboratory-supplied sample containers. The specific purging methodologies used for the individual monitoring wells are described in Sections 2.1.1.1 through 2.1.1.3. These methodologies are consistent with historical practices. 2.1.1.1 Monitoring Well MW-2 Monitoring well MW-2 was purged and sampled on September 27, 2017. No well construction log or drilling record is available for MW-2 (Table 1). The screened interval for monitoring well MW-2 is assumed to be constructed in saprolite. The well’s total depth is 56.30 feet below the top of the well casing (feet-TOC), as measured with the water level meter on the day of sampling. Although the well’s surface completion is capped and secure, the casing is bent and likely cracked at approximately 10 feet below ground surface. This bend obstructed the downhole pump, so Fall 2017 Semiannual Water Quality Monitoring Report 3 January 2018 Anchor QEA personnel used a more flexible dedicated Teflon bailer (rather than a polyethylene bailer) to bypass the bend in the casing, purged three well volumes, and subsequently collected a groundwater sample. Field parameters were recorded for the initial groundwater withdrawal and after each consecutive well volume was purged. 2.1.1.2 Monitoring Wells MW-AR, MW-B, and MW-3 A bladder pump and low-flow sampling techniques were used to purge and sample compliance monitoring wells MW-3, MW-AR, and MW-B. No well construction log or drilling record is available for monitoring wells MW-3 or MW-AR (Table 1). The screened interval for monitoring well MW-3 is assumed to be constructed in saprolite. Monitoring well MW-3 has a total well depth of 38.0 feet- TOC, as measured with a water level meter on the day of sampling. Monitoring well MW-AR has a total depth of 71.4 feet-TOC, and its screened interval is assumed to be constructed in bedrock. The screened interval for monitoring well MW-B is constructed in bedrock, with a total well depth of 70 feet-TOC. Total well depths for monitoring wells MW-AR and MW-B were measured with a water level meter during prior sampling events. These three monitoring wells were purged using low-flow sampling techniques in accordance with the procedures described in Ground Water Issue: Low-Flow (Minimal Drawdown) Ground-Water Sampling Procedures (Puls and Barcelona 1996). During purging, field parameters were measured and recorded approximately every 3 minutes. Well purging continued until these parameters stabilized for three consecutive readings, as outlined in the U.S. Environmental Protection Agency Region 4 Science and Ecosystem Support Division Operating Procedure: Groundwater Sampling (EPA 2017). The required stabilization criteria were as follows: • pH values within ± 0.1 standard unit (SU) • SC values within ± 3% • Temperature, DO, and turbidity values within ± 10% • ORP values within ± 10 millivolts (mV) Once the parameters stabilized, a groundwater sample was collected by an Anchor QEA technician wearing a new pair of nitrile gloves. 2.1.1.3 Monitoring Well MW-J Monitoring well MW-J, which has a total depth of 194.5 feet below ground surface (Table 1), is located on a ridge in the western part of the C&D Landfill. It is screened in bedrock and serves as a background well for the water quality monitoring network. A bladder pump could not be used to purge or sample this well due to the pressure head caused by the deep groundwater level in the well (146.01 feet-TOC). Instead, Anchor QEA technicians used a GeoTech Geosub pump and performed low-flow sampling techniques to purge and sample the well on September 26, 2017. During purging, Fall 2017 Semiannual Water Quality Monitoring Report 4 January 2018 the field parameters for groundwater were measured and recorded approximately every 3 minutes. Well purging continued until these parameters stabilized for three consecutive readings. The stabilization criteria were the same as for other wells (as described in Section 2.1.1.2). Once the parameters had stabilized, groundwater samples were collected and placed into laboratory-supplied sample bottles by a technician wearing a new pair of nitrile gloves. 2.1.2 Surface Water Sampling Methods Surface water samples SW-1 and SW-2 were collected on September 26, 2017, from designated locations in the North Toe River, which is located just east of the MSW Landfill. The SW-1 sample represents surface water quality upstream of the MSW Landfill, and the SW-2 sample represents surface water quality downstream of the landfill. One round of field parameters—consisting of temperature, pH, SC, DO, ORP, and turbidity—was measured and recorded at each surface water sampling location prior to collecting the sample. Each sample was collected in laboratory-supplied sample containers by a technician wearing a new pair of nitrile gloves. 2.2 Sample Handling, Documentation, and Analysis Field parameters and additional observations pertaining to the MSW Landfill sampling locations are provided in sampling logs included in Appendix A. Following collection, each groundwater and surface water sample was immediately placed on ice in a sample cooler for shipment to Prism Laboratories (Prism), a North Carolina-certified laboratory located in Charlotte, North Carolina. The 1995 closure letter (DENR 1995a) refers to Appendix 2 of Sampling and Analysis Requirements for Construction and Demolition Landfills and Closed Sanitary Landfills of the North Carolina Water Quality Monitoring Guidance Document for Solid Waste Facilities (DENR 1995b) for the required list of parameters to be monitoring at the Site. Table 2 provides details of the analyses performed on collected samples. Proper chain-of-custody documentation procedures were followed during collection and transportation of each sample to the laboratory. The documentation is included in Appendix B of this report. A trip blank, provided by the laboratory, was placed in each sample cooler and analyzed for volatile organic compounds (VOCs) specified in Appendix I of Title 40 of the Code of Federal Regulations, Part 258. The laboratory analytical reports are provided in Appendix B. The Prism laboratory report of analysis, presented in Appendix B, contains results for selected constituents that are not discussed in the text of this report. These constituents include eight additional metals from the Appendix I constituent list, as well as tetrahydrofuran, chloride, manganese, sulfate, iron, alkalinity, and total dissolved solids. The additional constituents were included in the laboratory analyses performed on three samples: the two surface water locations (SW-1 and SW-2) and monitoring well MW-J. Samples were collected from these points to satisfy monitoring requirements for both the MSW Landfill and C&D Landfill. Samples collected from the Fall 2017 Semiannual Water Quality Monitoring Report 5 January 2018 three referenced sampling points were analyzed for the additional constituents to meet the requirements of the 15A NCAC 13B .0500 and .0601 rules pertaining to construction and demolition debris landfills. A discussion of results for the applicable constituents is included in the Fall 2017 Semiannual Water Quality Monitoring Report, Yancey-Mitchell County Construction and Demolition Debris Landfill submitted in January 2018 (Anchor QEA 2018). Fall 2017 Semiannual Water Quality Monitoring Report 6 January 2018 3 Findings 3.1 Analytical Results The laboratory analytical results and field parameter data for the groundwater and surface water samples collected at the landfill are included in Appendices A and B, as well as in the Electronic Data Deliverable, which has been submitted separately to the DEQ DWM Solid Waste Section (SWS), per applicable guidelines. As stipulated in the SWS documents referenced in the preceding paragraph, laboratory analytical results were reported and appropriately qualified as follows: • Non-Detections: Non-detections (non-detects) are values reported by the laboratory as below method detection limits (MDLs). They are tabulated in Table 3 and are flagged with a “U” qualifier. The MDL is the minimum concentration of a substance that can be measured and reported by a laboratory with 99% confidence that the constituent concentration is greater than zero. • Solid Waste Section Limits: Detections (values above the MDL) were compared to constituent-specific Solid Waste Section Limits (SWSLs) established by DEQ. The SWSL is defined as the lowest concentration of a constituent in a sample that can be quantitatively determined with suitable precision and accuracy. A non-italicized “J” qualifier is used by the laboratory to flag parameters that are detected at estimated concentrations greater than the MDL but less than the laboratory’s method reporting limit (MRL). The MRL is the minimum concentration of a target analyte that can be accurately determined by the referenced method. • Estimated or “J”-Qualified: If the reported concentration is greater than the laboratory MDL and MRL but less than the SWSL, the analytical result is qualified as estimated and flagged with an italicized “J” qualifier by Anchor QEA, per SWS reporting requirements. In addition to non-detects, detected constituent concentrations below the applicable SWSLs are included in Table 3. • 2L Standard: Detected concentrations of constituents in groundwater samples were compared to the applicable North Carolina groundwater quality standards. For most constituents, this standard is the 2L standard, defined in 15A NCAC 2L .0202. Detected concentrations of analytes in groundwater with no established 2L standard were compared either to the interim maximum allowable concentrations for Class GA and GSA groundwater (in accordance with 15A NCAC 02L .0202 [c]) or to the Groundwater Protection Standards, pursuant to 15A NCAC 13B .1634. • 2B Standard: Detections of analytes in surface water samples were compared to the surface water quality standards described in 15A NCAC 2B (2B standards). Fall 2017 Semiannual Water Quality Monitoring Report 7 January 2018 Table 3 presents a summary of detected constituents and outlines concentrations of analytes that were above applicable SWSLs, as well as detected analytes that exceeded their respective 2L standard, interim maximum allowable concentration, or 2B standard. 3.1.1 Groundwater Samples The following sections summarize detections of field parameters, Appendix I VOCs, and metals in groundwater. 3.1.1.1 Field Parameters The pH readings for the samples collected from all of the monitoring wells were below the acceptable range of 6.5 to 8.5 SUs specified in the 2L standards (Table 3). The pH readings recorded for this event are consistent with historical data. Turbidity values at the time of sampling the monitoring wells ranged from 2.95 nephelometric turbidity units (NTUs) in MW-B to 57.6 NTUs in MW-3 (Table 3). MW-2, which was purged and sampled with a bailer, showed a turbidity value of 3.40 NTUs. DO readings for the samples collected from the monitoring wells ranged between 1.38 milligrams per liter (mg/L) in MW-AR to 5.57 mg/L in MW-J. SC measurements ranged between 61 microsiemens per centimeter (µS/cm) in MW-AR to 2,142 µS/cm in MW-B. ORP values measured in the samples collected from the monitoring wells ranged between -88.1 mV in MW-B to 526.7 mV in MW-AR. No SWSLs or 2L standards are established for DO, SC, or ORP. 3.1.1.2 Volatile Organic Compounds Fifteen VOCs were detected in the groundwater samples collected from one or more of the monitoring wells (Table 3). Seven of the 15 VOCs (1,4-dichlorobenzene, benzene, chlorobenzene, ethylbenzene, toluene, vinyl chloride, and total xylenes) were detected at concentrations above their respective SWSLs in samples from one or more monitoring wells (Table 3). Three compounds (1,4-dichlorobenzene, benzene, and vinyl chloride) were detected at concentrations above their 2L standards. These exceedances occurred in the groundwater sample collected from MW-B, at 8.1 micrograms per liter (µg/L), 5.4 µg/L, and 3.8 µg/L, respectively (Table 3 and Figure 2). Historical data for monitoring well MW-B show consistent exceedances of these constituents during prior sampling events. 3.1.1.3 Metals Six metals were detected in the groundwater samples collected from one or more monitoring wells (Table 3). Barium was detected at a concentration above its SWSL in the sample collected from monitoring well MW-2 (Table 3). Chromium was detected above its 2L standard in monitoring well MW-J (Table 3). Concentrations of the detected metals are consistent with historical data. Fall 2017 Semiannual Water Quality Monitoring Report 8 January 2018 3.1.2 Surface Water Samples The following sections summarize detections of field parameters, VOCs, metals, and field parameters in surface water. The location of sample point SW-1 in the North Toe River is upstream of the landfill and is assumed to represent surface water quality upstream of the Yancey County MSW and C&D landfills. The location of sample point SW-2 in the North Toe River is downstream of the landfill and is assumed to represent surface water quality downstream of the landfills (Figure 2). 3.1.2.1 Field Parameters Surface water sample pH readings were obtained on September 26, 2017. The pH readings measured 6.14 and 6.55 SU for surface water samples SW-1 and SW-2, respectively. Both results are within the 2B standard range for pH, established at 6.0 to 9.0 SU (Table 3), and are consistent with historical readings. Turbidity was measured and recorded for SW-1 and SW-2 at 2.81 and 4.75 NTUs, respectively. Both values are within the 2B standard of 10 NTUs (Table 3) and are consistent with historical readings. DO was measured at 8.52 mg/L for SW-1 and 8.07 mg/L at SW-2. Both values are within the established DO 2B standard of 6.0 mg/L (the 2B standard indicates “equal to or greater than 6.0 mg/L” for trout water) and are consistent with historical readings. SC measurements in surface water samples SW-1 and SW-2 were recorded at 116 and 85 µS/cm, respectively. ORP measurements for SW-1 and SW-2 were recorded at 347.6 and 262.5 mV, respectively. 2B standards do not exist for these field parameters. Detailed field parameter results are provided in Appendix A and Table 3 of this report. 3.1.2.2 Volatile Organic Compounds No VOCs were detected in either of the surface water samples collected from the landfill. 3.1.2.3 Metals Three metals (barium, chromium, and lead) were detected in both surface water samples (Table 3). None of the detected metals exceeded their respective SWSLs or 2B standards. The relationship of overall metal concentrations between the upstream and downstream surface water samples does not show evidence of the landfill impacting surface water downstream. Metals in the downstream sample location were detected in similar concentration ranges to those in the upstream sample location, supporting the conclusion that the metal concentrations in the landfill groundwater monitoring wells are not impacting the surface water. Fall 2017 Semiannual Water Quality Monitoring Report 9 January 2018 3.2 Hydrogeology Groundwater elevations were calculated for the fall 2017 semiannual water quality monitoring event using the measured depths to water and the associated top-of-casing elevations determined from a survey of the monitoring wells performed in October 2009. Groundwater elevation data are reported in Table 1. Figure 3 presents the generalized groundwater flow direction for bedrock and saprolite, respectively. Generalized groundwater flow directions were estimated using groundwater elevation data associated with a limited number of monitoring well locations in an area of complex topographic and geologic conditions. The estimated groundwater flow directions indicate that groundwater in the bedrock is generally flowing in a northeasterly direction and that groundwater in the saprolite is generally mimicking topography. In the area for which data are available, groundwater flow in the saprolite is interpreted to be convergent toward a topographic trough in a northerly direction. The apparent groundwater flow directions and the local topography suggest that groundwater in both the saprolite and the bedrock is flowing toward the North Toe River. Fall 2017 Semiannual Water Quality Monitoring Report 10 January 2018 4 Summary Anchor QEA completed the second semiannual water quality monitoring event of 2017 at the Yancey-Mitchell County MSW Landfill on September 26 and 27, 2017. Table 3 of this report and the Prism analytical reports (Appendix B) provide detailed analytical results and field data representing the groundwater and surface water quality at the MSW Landfill. Generally, the groundwater and surface water analytical results show that constituent concentrations are below their respective SWSLs, 2B standards, and 2L standards, with the exception of 1,4-dichlorobenzene, benzene, and vinyl chloride in groundwater samples from compliance monitoring well MW-B. These VOCs have never been detected in downstream surface water samples. The similarity in concentrations of metals in both surface water samples supports the conclusion that groundwater flow from the landfill toward the North Toe River is not impacting surface water. 4.1 Future Activities Anchor QEA will continue to measure field parameters and collect water quality samples from groundwater and surface water monitoring points associated with the MSW Landfill. Water quality samples will be submitted to a North Carolina-certified laboratory for analysis for eight metals and Appendix I VOCs on a semiannual basis. The next sampling event is scheduled for March 2018. Fall 2017 Semiannual Water Quality Monitoring Report 11 January 2018 5 References Anchor QEA (Anchor QEA of North Carolina, PLLC), 2018. Fall 2017 Semiannual Water Quality Monitoring Report, Yancey-Mitchell County Construction and Demolition Debris Landfill. January 2018. DENR (North Carolina Department of Environment and Natural Resources), 1995a. Letter to: Earl Tipton, Yancey County. Regarding: Closure of the Yancey-Mitchell County Landfill Permit #100-01. Division of Waste Management, Solid Waste Section. December 21, 1995. DENR, 1995b. North Carolina Water Quality Monitoring Guidance Document for Solid Waste Facilities. EPA (U.S. Environmental Protection Agency), 2017. Operating Procedure: Groundwater Sampling. Science and Ecosystem Support Division. Revised April 26, 2017. Puls, R.W., and M.J. Barcelona, 1996. Ground Water Issue: Low-Flow (Minimal Drawdown) Ground-Water Sampling Procedures. Prepared for U.S. Environmental Protection Agency Office of Research and Development and Office of Solid Waste and Emergency Response. EPA/540/S-95/504. April 1996. Tables Table 1 Monitoring Well Construction Summary Northing Easting Ground Surface Elevation TOC Elevation Stick Up Total Well Depth Depth to Water Groundwater Elevation Approximate Depth to Bedrock Approximate Bedrock Elevation Depth to Top of Screened Interval Depth to Bottom of Screened Interval Top of Screen Elevation Bottom of Screen Elevation (NAD83; 2007) (NAD83; 2007)(feet NAVD88)(feet NAVD88) (feet above ground surface) (feet- TOC) (feet- TOC)(feet NAVD88) (feet below ground surface)(feet NAVD88) (feet below ground surface) (feet below ground surface)(feet NAVD88)(feet NAVD88) MW-2 809474.01 1059181.42 2,568.85 2,572.06 3.21 56.30 36.20 2,535.86 MW-3 809357.74 1058830.13 2,551.34 2,553.57 1.70 38.00 32.84 2,520.73 MW-AR 808483.97 1059176.2 2,688.76 2,691.17 2.30 71.40 63.08 2,628.09 Assumed Bedrock MW-B 12/02/1996 809020.07 1059514.58 2,624.07 2,626.27 2.00 70.00 60.95 2,565.32 18.00 2,606.07 53.00 68.00 2,571.07 2,556.07 Bedrock 100-01 MW-J 11/26/1996 808698.05 1057994.86 2,873.58 2,875.99 2.30 196.80 148.06 2,727.93 2.00 2,871.58 179.50 194.50 2,694.08 2,679.08 Bedrock MW-H 12/04/1996 809563.75 1058698.38 2,566.36 2,568.68 2.32 64.50 60.75 2,507.93 62.00 2,504.36 47.00 62.00 2,519.36 2,504.36 Saprolite MW-I 12/02/1996 809923.04 1058531.91 2,596.57 2,598.77 2.00 83.00 65.95 2,532.82 85.0 2,512.00 64.00 79.00 2,532.57 2,517.57 Saprolite Notes: Survey data showing the horizontal and vertical positions of the monitoring wells were presented in Appendix A of the Fall 2009 Semiannual Water Quality Monitoring Report, Yancey-Mitchell County Municipal Solid Waste Landfill, dated December 31, 2009. Depth to water was measured on September 26 and 27, 2017. "No Well Record" indicates that the well record, if it exists, was not readily obtainable. C&D: construction and demolition debris MSW: municipal solid waste NAD83: North American Datum of 1983 NAVD88: North American Vertical Datum of 1988 feet-TOC: feet below the top of the well casing 100-02 100-01 No Well Construction/ Drilling Record is Available DENR Well Construction/ Drilling Log Record, dated 12/31/1996 DENR Well Construction/ Drilling Log Record, dated 12/31/1996 No Well Record No Well Record No Well Record No Well Record No Well Record No Well Record Assumed Saprolite C&D Landfill Monitoring Wells No Well Record MSW Landfill Monitoring Wells Well ID Date Drilled Geology of Screened Interval Source of Well Construction Information Facility Permit Fall 2017 Semiannual Water Quality Monitoring Report Yancey-Mitchell County Closed Municipal Solid Waste Landfill Page 1 of 1 January 2018 Table 2 Summary of Laboratory Analyses Performed on Samples Groundwater Samples VOCs Metals EPA 8260B EPA 6020B, EPA 7470A 100-01 MW-2 09/27/2017 X X 100-01 MW-3 09/26/2017 X X 100-01 MW-AR 09/26/2017 X X 100-01 MW-B 09/27/2017 X X 100-01 MW-J 09/26/2017 X X Surface Water Samples VOCs Metals EPA 8260B EPA 6020B, EPA 7470A 100-01 SW-1 09/26/2017 X X 100-01 SW-2 09/26/2017 X X Quality Control Samples VOCs EPA 8260B 100-01 TRIP BLANK (MSW)09/26/2017 X 100-01 TRIP BLANK (J)09/26/2017 X 100-01 TRIP BLANK (SW)09/26/2017 X Notes: EPA: U.S. Environmental Protection Agency MSW: municipal solid waste VOC: volatile organic compound Facility Permit Well ID Collect Date Facility Permit Sample ID Collect Date Tetrahydrofuran: Analysis has been performed since the spring 2011 sampling event, per the North Carolina Division of Waste Management, Solid Waste Section requirement specified in the June 25, 2010 memorandum. VOC analyses include Appendix I constituents per 40 Code of Federal Regulations Part 258. Facility Permit Sample ID Collect Date Fall 2017 Semiannual Water Quality Monitoring Report Yancey-Mitchell County Closed Municipal Solid Waste Landfill Page 1 of 1 January 2018 Table 3 Summary of Analytical Results Metals (RCRA)Field Parameters Lab Certification 402 5445 (pH only) Lab Method EPA 6020B, EPA 7470A Parameter Arsenic Barium Cadmium Chromium Lead Selenium pH Turbidity Dissolved Oxygen Temperature Specific Conductivity Oxidation Reduction Potential CAS Number 7440-38-2 7440-39-3 7440-43-9 7440-47-3 7439-92-1 7782-49-2 SW320 SW330 7782-44-7 SW325 SW323 SW336 SWS ID 14 15 34 51 131 183 320 330 356 325 323 336 Units µg/L µg/L µg/L µg/L µg/L µg/L SU NTU mg/L °C µS/cm mV Collect Date Result Result Result Result Result Result Result Result Result Result Result Result 09/27/2017 0.45 U 160 0.053 U 0.41 J 0.25 J 0.45 U 5.95 3.40 2.97 13.93 497 139.0 09/26/2017 0.45 U 92 J 0.084 J 0.84 J 0.18 J 0.45 U 5.91 57.6 1.99 16.03 287 164.3 09/26/2017 0.45 U 47 J 0.35 J 0.68 J 0.25 J 0.45 U 5.25 4.03 1.38 13.94 61 526.7 09/27/2017 3.5 J 75 J 0.053 U 0.89 J 0.091 J 0.45 U 6.49 2.95 1.80 15.41 2,142 -88.1 09/26/2017 1.7 J 24 J 0.064 J 12 1.1 J 1.2 J 6.67 22.8 5.57 14.76 273 220.4 09/26/2017 0.45 U 23 J 0.053 U 0.30 J 0.14 J 0.45 U 6.14 2.81 8.52 19.56 116 347.6 09/26/2017 0.45 U 18 J 0.053 U 0.29 J 0.15 J 0.45 U 6.55 4.75 8.07 20.23 85 262.5 09/26/2017 NA NA NA NA NA NA NA NA NA NA NA NA 09/26/2017 NA NA NA NA NA NA NA NA NA NA NA NA 09/26/2017 NA NA NA NA NA NA NA NA NA NA NA NA MDL 0.45 0.120 0.053 0.081 0.061 0.45 NA NA NA NA NA NA MRL 1.0 5.0 1.0 1.0 1.0 5.0 NA NA NE NE NE NE SWSL 10 100 1 10 10 10 NE NE NE NE NE NE 2L 10 700 2 10 15 20 6.5-8.5 NE NE NE NE NE IMAC NE NE NE NE NE NE NE NE NE NE NE NE GWPS NE NE NE NE NE NE NE NE NE NE NE NE 2B 10 200,000 0.15 35 0.54 5 6.0-9.0 10 ≥6.0 NE NE NE.Notes: Only detected constituents are listed on this table. Please refer to the Prism laboratory report of analyses for further details. Bold numbers indicate an SWSL exceedance. Appendix I: indicates volatile organic compounds and metals per 40 Code of Federal Regulations Part 258 B: a laboratory data qualifier used to indicate an analyte that is found in the associated blank at a concentration greater than one half of the report limit CAS Number: a unique number assigned by the Chemical Abstracts Service to all identified parameters Collect Date: the date on which the sample was collected in the field EPA: U.S. Environmental Protection Agency MRL: method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method MSW: municipal solid waste NA: not applicable NE: not established Result: analytical data reported by the laboratory or field data collected by Anchor QEASWS ID: Solid Waste Section Identification Number SWSL: Solid Waste Section Limit (identified by the Department of Environmental Quality), which is the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy U: a laboratory data qualifier used for parameters not detected at concentrations above the MDL IMAC: Interim Maximum Allowable Concentration. IMAC concentrations are listed in Appendix #1 of the 2L. J: a laboratory data qualifier used for parameters detected at estimated concentrations above the MDL but below the MRL 2L: Subchapter 2L – Groundwater Classifications and Standards, Department of Environmental Quality (Amended April 1, 2013). Groundwater standard from North Carolina Administrative Code, Title 15A. 2B: surface water standard per NCAC, Title 15A: DEQ, Subchapter 2B – Surface Water and Wetland Standards (last amended in March 2016), or the standard obtained from National Criteria, per the EPA table (current as of May 15, 2013). Shaded cells indicate the result is in exceedance of the 2L, IMAC, GWPS, or 2B standard. Sample ID Groundwater Samples MW-2 MW-3 MW-AR MW-B MW-J Surface Water Samples SW-1 SW-2 Quality Control Samples TRIP BLANK (MSW) TRIP BLANK (J) TRIP BLANK (SW) Units: micrograms per liter (µg/L) and milligrams per liter (mg/L) for analytical results, Standard Units (SU) for pH, nephelometric turbidity units (NTU) for turbidity, microsiemens per centimeter (µS/cm) for specific conductivity, degrees Celsius (°C) for temperature, and millivolts (mV) for oxidation reduction potential GWPS: Groundwater Protection Standard pursuant to 15A NCAC 13B .1634, Department of Environmental Quality. Current standards were obtained from https://deq.nc.gov/about/divisions/waste-management/waste-management-permit-guidance/solid-waste- section/environmental-monitoring/environmental-monitoring-list (last updated June, 2011). GWPS is used only if 2L or IMAC standards are not established for a specific constituent. J: a qualifier assigned by Anchor QEA to reflect a detected concentration that is greater than the MRL and MDL, but less than the SWSL Lab Method: the analytical method used to analyze the constituents MDL: method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero Fall 2017 Semiannual Water Quality Monitoring Report Yancey-Mitchell County Closed Municipal Solid Waste Landfill Page 1 of 2 January 2018 Table 3 Summary of Analytical Results VOCs (Appendix I) Lab Certification 402 Lab Method EPA 8260B Parameter 1,4-Dichloro- benzene Acetone Benzene Chloro- benzene Chloro- ethane cis-1,2- Dichloro- ethylene Ethyl- benzene m,p-Xylenes Methyl Butyl Ketone (2- Hexanone) Methyl Isobutyl Ketone o-Xylene Tetra- hydrofuran Toluene Vinyl Chloride Xylenes, Total CAS Number 106-46-7 67-64-1 71-43-2 108-90-7 75-00-3 156-59-2 100-41-4 108-38-3 591-78-6 108-10-1 95-47-6 109-99-9 108-88-3 75-01-4 1330-20-7 SWS ID 71 3 16 39 41 78 110 359 124 147 408 458 196 211 346 Units µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L Sample ID Collect Date Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Groundwater Samples MW-2 09/27/2017 3.5 0.31 U 0.86 J 4.3 0.55 J 0.60 J 0.061 U 0.12 U 0.065 U 0.078 U 0.044 U 0.16 U 0.044 U 0.097 U 0.15 U MW-3 09/26/2017 1.9 0.31 U 0.048 U 3.9 0.22 U 0.056 U 0.061 U 0.12 U 0.065 U 0.078 U 0.044 U 0.16 U 0.044 U 0.097 U 0.15 U MW-AR 09/26/2017 0.050 U 0.31 U 0.048 U 0.062 U 0.22 U 0.056 U 0.061 U 0.12 U 0.065 U 0.078 U 0.044 U 0.16 U 0.044 U 0.097 U 0.15 U MW-B 09/27/2017 8.1 5.3 J 5.4 11 0.22 U 0.056 U 3.8 12 1.1 J 9.3 J 5.2 170 3.6 3.8 18 MW-J 09/26/2017 0.050 U 0.31 U 0.048 U 0.062 U 0.22 U 0.056 U 0.061 U 0.71 J 0.065 U 0.078 U 0.044 U 0.16 U 0.044 U 0.097 U 0.71 J Surface Water Samples SW-1 09/26/2017 0.050 U 0.31 U 0.048 U 0.062 U 0.22 U 0.056 U 0.061 U 0.12 U 0.065 U 0.078 U 0.044 U 0.16 U 0.044 U 0.097 U 0.15 U SW-2 09/26/2017 0.050 U 0.31 U 0.048 U 0.062 U 0.22 U 0.056 U 0.061 U 0.12 U 0.065 U 0.078 U 0.044 U 0.16 U 0.044 U 0.097 U 0.15 U Quality Control Samples TRIP BLANK (MSW)09/26/2017 0.050 U 0.31 U 0.048 U 0.062 U 0.22 U 0.056 U 0.061 U 0.12 U 0.065 U 0.078 U 0.044 U 0.16 U 0.044 U 0.097 U 0.15 U TRIP BLANK (J)09/26/2017 0.050 U 0.31 U 0.048 U 0.062 U 0.22 U 0.056 U 0.061 U 0.12 U 0.065 U 0.078 U 0.044 U 0.16 U 0.044 U 0.097 U 0.15 U TRIP BLANK (SW)09/26/2017 0.050 U 0.31 U 0.048 U 0.062 U 0.22 U 0.056 U 0.061 U 0.12 U 0.065 U 0.078 U 0.044 U 0.16 U 0.044 U 0.097 U 0.15 U MDL 0.050 0.31 0.048 0.062 0.22 0.056 0.061 0.12 0.065 0.078 0.044 0.16 0.044 0.097 0.15 MRL 0.50 5.0 0.50 0.50 0.50 0.50 0.50 1.0 5.0 5.0 0.50 10 0.50 0.50 1.5 SWSL 1 100 1 3 10 5 1 NE 50 100 NE NE 1 1 5 2L 6 6000 1 50 3000 70 600 NE NE NE NE NE 600 0.03 500 IMAC NE NE NE NE NE NE NE NE 40 100 NE NE NE NE NE GWPS NE NE NE NE NE NE NE NE 40 560 NE NE NE NE NE 2B 56 2,000 51 140 NE 720 97 550 NE 26,000 400 NE 0.36 2.4 450 Notes: GWPS: The Groundwater Protection Standard pursuant to 15A NCAC 13B .1634, Department of Environmental Quality. Current standards were obtained from https://deq.nc.gov/about/divisions/waste-management/waste-management-permit-guidance/solid-waste-section/environmental- monitoring/environmental-monitoring-list (last updated June, 2011). GWPS is used only if 2L or IMAC standards are not established for a specific constituent.IMAC: Interim Maximum Allowable Concentration. IMAC concentrations are listed in Appendix #1 of the 2L. J: a laboratory data qualifier used for parameters detected at estimated concentrations above the MDL but below the MRL J: a qualifier assigned by Anchor QEA to reflect a detected concentration that is greater than the MRL and MDL, but less than the SWSL Lab Method: the analytical method used to analyze the constituents Appendix I: indicates volatile organic compounds and metals per 40 Code of Federal Regulations Part 258 B: a laboratory data qualifier used to indicate an analyte that is found in the associated blank at a concentration greater than one half of the report limit CAS Number: a unique number assigned by the Chemical Abstracts Service to all identified parameters Collect Date: the date on which the sample was collected in the field EPA: U.S. Environmental Protection Agency Only detected constituents are listed on this table. Please refer to the Prism laboratory report of analyses for further details. Bold numbers indicate an SWSL exceedance. Shaded cells indicate the result is in exceedance of the 2L, IMAC, GWPS, or 2B standard. 2B: surface water standard per NCAC, Title 15A: DEQ, Subchapter 2B – Surface Water and Wetland Standards (last amended in March 2016), or the standard obtained from National Criteria, per the EPA table (current as of May 15, 2013). 2L: Subchapter 2L – Groundwater Classifications and Standards, Department of Environmental Quality (Amended April 1, 2013). Groundwater standard from North Carolina Administrative Code, Title 15A. Result: analytical data reported by the laboratory or field data collected by Anchor QEASWS ID: Solid Waste Section Identification Number SWSL: Solid Waste Section Limit (identified by the Department of Environmental Quality), which is the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy U: a laboratory data qualifier used for parameters not detected at concentrations above the MDL Units: micrograms per liter (µg/L) and milligrams per liter (mg/L) for analytical results, Standard Units (SU) for pH, nephelometric turbidity units (NTU) for turbidity, microsiemens per centimeter (µS/cm) for specific conductivity, degrees Celsius (°C) for temperature, and millivolts (mV) for oxidation reduction potential MDL: method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zeroMRL: method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method MSW: municipal solid waste NA: not applicable NE: not established Fall 2017 Semiannual Water Quality Monitoring Report Yancey-Mitchell County Closed Municipal Solid Waste Landfill Page 2 of 2 January 2018 Figures [ 0 2,0001,000 Feet NOTE:Burnsville, North Carolina is located approximately 7.0miles southwest of the landfill parcel boundary. LEGEND: Landfill Property Boundary Publish Date: 2018/01/23, 4:16 PM | User: alesueurFilepath: \\Asheville1\Asheville\Projects\Yancey County\Solid Waste\Figures\GIS\MXD\2017\Fall\Figure 1 - Site Location Map MSW AQ.mxd Figure 1Site Location Map Fall 2017 Semiannual Water Quality Monitoring ReportYancey-Mitchell County Closed Municipal Solid Waste Landfill SOURCES:Basemap: USGS 1:24,000 Scale Topo Maps, Micaville Quadrangle, 1987Site Property Boundary: Yancey County GIS Anchor QEA of North Carolina, PLLC%7 miles to Burnsville, NC %NC Highway 80 #* !U !U !U !U !U MW-2pH (5.95 SU) MW-3 pH (5.91 SU) MW-B 1,4-Dichlorobenzene (8.1 µg/L) Benzene (5.4 µg/L) Vinyl Chloride (3.8 µg/L)pH (6.49 SU) MW-AR pH (5.25 SU) MW-J (Background Well) (No Exceedances) SW-1 No Exceedances Municipal Solid Waste Landfill Construction and Demolition Debris Landfill REBELS CREEKREBELS CREEKNORTH TOE RIVERNORTH TOE RIVER WOLF BRANCHWOLF BRANCH[ 0 500 1,000250 Feet NOTES:1. Posted data indicate constituents detected atconcentrations above their respective water qualitystandard (2L standard, Interim Maximum AllowableConcentration [IMAC], or 2B standard)2. Sample dates: September 26 and 27, 20173. Surface water sample locations are approximate.The downstream surface water sample (SW-2) isshown on the map inset. LEGEND: !U Bedrock Monitoring Well Location !U Saprolite Monitoring Well Location #*Surface Water Location Approximate Landfill Boundaries Streams Landfill Parcel Boundary Publish Date: 2018/01/23, 4:31 PM | User: alesueurFilepath: \\Asheville1\Asheville\Projects\Yancey County\Solid Waste\Figures\GIS\MXD\2017\Fall\Figure 2 - MSW Sample Location Map AQ.mxd Figure 2Sample Location and Posted Data Map Fall 2017 Semiannual Water Quality Monitoring ReportYancey-Mitchell County Closed Municipal Solid Waste Landfill SOURCE(S):Basemap: NC OneMap 2010Parcels and Streams: Yancey County GISMonitoring Wells: Survey Data from Webb A. Morganand Associates, P.A. (2009) #* #* SW-2 No Exceedances Anchor QEA of North Carolina, PLLC 0 6,0003,000Feet 2L Groundwater Standards or IMAC1,4-Dichlorobenzene (6 µg/L)Benzene (1.0 µg/L)Vinyl Chloride (0.03 µg/L)pH (6.5-8.5 Standard Units [SU]) % Transfer Station %Fl o w D i r e c t i o n Flo w D i r e c t i o n %%%% !U !U !U !U !U !U !U %Flow Direction Flow Direction Generalized Bedrock Groundwater Flow Generalized SaproliteGroundwater Flow Construction and DemolitionDebris Landfill Municipal SolidWaste Landfill MW-2 (2,535.86)MW-3 (2,520.73) MW-AR (2,628.09) MW-B (2,565.32) MW-J (2,727.93) MW-H (2,507.93) MW-I (2,532.82)25402580 25202380 25202560 2460 2680 2 5 6 0 2440 2 4 8 0 2420 266026402620 2420 2540 24602520 24402480 2360 2600 2500 2400 25002 5 0 0 27002600 24002700 24002500 27002400 2700 280025802420256028602480 2620272027802 7 4 0 2480 268025 4 0 252024402860272 0 24202520 2380 244024202640 2840 244027202460 28202620 2 4 602680 278026602760 2480264027602680 2360 WOLF BRANCHWOLF BRANCHREBELS CREEKREBELS CREEKNORTH TOE RIVERNORTH TOE RIVER Publish Date: 2018/01/23, 4:38 PM | User: alesueurFilepath: \\Asheville1\Asheville\Projects\Yancey County\Solid Waste\Figures\GIS\MXD\2017\Fall\Fig3AQ.mxd [ 0 400200 Feet NOTES:1. (2,522.73): Calculated groundwaterelevation2. Groundwater elevations are based ondepth to water measurements collectedon September 26 and 27, 2017. Figure 3Generalized Groundwater Flow Direction Map Fall 2017 Semiannual Water Quality ReportYancey-Mitchell County Closed Municipal Solid Waste Landfill LEGEND: !U Bedrock Monitoring Well Location !U Saprolite Monitoring Well Location Approximate Landfill Boundaries Elevation Contour (20-Foot Interval) Landfill Parcel Boundary Streams SOURCES:1. Parcels: Yancey County GIS2. Monitoring Wells: Survey data fromWebb A. Morgan and Associates, P.A.(2009)3. Elevation Contours: NCDOT Lidar,20074. Roads: Yancey County and MitchellCounty GIS Anchor QEA of North Carolina, PLLC Appendix A Sampling Logs and Equipment Documentation and Instrument Calibration Data Sheets Appendix B Reports of Laboratory Analysis and Chain- of-Custody Documentation Page 1 of 20 Page 2 of 20 Page 3 of 20 Page 4 of 20 Page 5 of 20 Page 6 of 20 Page 7 of 20 Page 8 of 20 Page 9 of 20 Page 10 of 20 Page 11 of 20 Page 12 of 20 Page 13 of 20 Page 14 of 20 Page 15 of 20 Page 16 of 20 Page 17 of 20 Page 18 of 20 Page 19 of 20 Page 20 of 20 Page 1 of 17 Page 2 of 17 Page 3 of 17 Page 4 of 17 Page 5 of 17 Page 6 of 17 Page 7 of 17 Page 8 of 17 Page 9 of 17 Page 10 of 17 Page 11 of 17 Page 12 of 17 Page 13 of 17 Page 14 of 17 Page 15 of 17 Page 16 of 17 Page 17 of 17 Page 1 of 20 Page 2 of 20 Page 3 of 20 Page 4 of 20 Page 5 of 20 Page 6 of 20 Page 7 of 20 Page 8 of 20 Page 9 of 20 Page 10 of 20 Page 11 of 20 Page 12 of 20 Page 13 of 20 Page 14 of 20 Page 15 of 20 Page 16 of 20 Page 17 of 20 Page 18 of 20 Page 19 of 20 Page 20 of 20