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HomeMy WebLinkAbout1107_Buncombe_MSWLF_GW_DIN28761_20171016SCS Engineers, P.C. Environmental Consultants 4767 New Broad Street 407 514-2766 and Contractors Suite 222 FAX 407 514-2604 Orlando, FL 32814 www.scsengineers.com Offices Nationwide January 30, 2018 File No. 09204072.15 Mrs. Jackie Drummond Compliance Hydrogeologist Division of Waste Management - Solid Waste Section NC Department of Environmental Quality Asheville Regional Office 2090 US Highway 70, Swannanoa, NC 28778 Subject: Fall 2017 Semi-Annual Sampling Report Buncombe County Solid Waste Management Facility- New Landfill Permit No. 1107 Dear Mrs. Drummond: On behalf of the Buncombe County Solid Waste Division, SCS Engineers, PC (SCS) respectfully submits this report summarizing the findings of the fall 2017 semi-annual sampling event to the Solid Waste Section of the North Carolina Department of Environmental Quality (DEQ). SCS conducted semi-annual sampling at the Buncombe County Solid Waste Management Facility New Landfill (permit no. 1107) on October 16th through October 20th, 2017. This report summarizes the sampling methodology, results and recommendations from this semi-annual sampling event. Sampling Methodology Water samples were collected by Pace Laboratories from each of the 25 monitoring wells, six surface water sampling locations, and six leachate sampling locations. All groundwater sampling and analyses were performed in accordance with 15A NCAC 13B .1632. In order to achieve DEQ’s recommended turbidity standard of 10 nephelometric turbidity units (NTUs) for groundwater sampling at background and compliance wells for the municipal landfill (MW-1, MW-1D, MW-2, MW-2D, MW-3R, MW-4, MW-4D, MW-5, MW-5D, , MW-6, MW-7, MW-8, MW-8D, MW-10, MW-10D, MW-11, MW-11D, MW-13 and MW-13D) the low-flow groundwater sampling method was used to reduce turbidity levels in the monitoring wells during sampling. The low-flow sampling procedures were performed in accordance with EPA guidelines (Puls and Barcelona 2016). Field parameters including pH, temperature, specific conductivity, turbidity, dissolved oxygen, oxidative/reductive potential (ORP) and water level were measured and recorded at each groundwater, surface water and leachate sampling site. Field logs with recorded parameters are included in Attachment A and well condition summary forms are included in Attachment B. Turbidity of less than 10 NTUs at each groundwater monitoring well was achieved utilizing the low-flow method. After samples were collected, they were placed on ice, logged on a chain of custody and sent to Pace Laboratories in Asheville, NC, a laboratory certified by the State of North Carolina for all applicable analyses. A copy of the chain of custody is provided as Attachment C. Jackie Drummond January 30, 2018 Page 2 Laboratory Methods and Analysis All samples were analyzed by Pace Laboratories in Asheville, NC for the following constituents using the method listed: • Appendix I VOC (EPA 8260); • Appendix I Metals (EPA 6010) plus mercury (EPA 7470), • sulfate (EPA 300.0), • chloride (SM 4500-Cl-E), • alkalinity (SM 2320B), and • Total Dissolved Solids (SM 2540C). Results Groundwater Groundwater contour maps were created for both shallow and deep aquifers using the recorded field data. The groundwater contour maps are provided in Attachment D. Metals and chloride were the only constituents detected in monitoring well samples which exceeded the MCLs (MCL) set by North Carolina 2L (NC2L). A summary of groundwater detections is included in Attachment E. Metal constituents detected include barium, chromium, cobalt, iron, manganese, nickel, vanadium, and zinc. These detections are consistent with previous sampling results and are generally recognized as naturally occurring. Eleven of the 25 monitoring wells (including one of the background wells, MW-1) had concentrations in exceedance of the North Carolina 2L Groundwater Standards. A summary of groundwater exceedances is provided in Attachment F. Total Dissolved Solids was detected above the MCL of 500,000 µg/L in MW-12 (560,000 µg/L). Chromium was detected above the MCL of 10 µg/L in MW-4D (10.1 µg/L). Cobalt was detected above the MCL of 1 µg/L in MW-11D (19.8 µg/L), MW-13 (27.2 µg/L), and MW-15S (80.8 µg/L). Iron was detected above the MCL of 300 µg/L in MW-1 (722 µg/L), MW-12D (453 µg/L), MW-14 (2,460 µg/L), and MW-15S (2,640 µg/L). Manganese was detected above the MCL of 50 µg/L in MW-12 (462 µg/L), MW-15S (12,600 µg/L), and MW-15D (308 µg/L). Vanadium was detected above the maximum contaminant level of 0.3 µg/L in MW-14 (8.1 µg/L). No Appendix I VOCs were detected in groundwater samples. Surface Water A summary of surface water detections is included in Attachment G. Metal constituents detected in surface water samples include barium, chromium, cobalt, copper, nickel, and zinc. No Appendix I VOCs were detected in surface water samples. One surface water sample, SW-2, had concentrations in excess of their associated MCLs-copper was detected above the MCL of 7 µg/L in SW-2 (12.1 µg/L). A summary of surface water exceedances is provided in Attachment H. Attachments Buncombe County New Landfill Fall 2017 Semi-Annual Sampling A TTACHMEN T A FIELD LOGS Buncombe County New Landfill Fall 2017 Semi-Annual Sampling A TTACHMEN T B WELL CONDITION FORMS Buncombe County New Landfill Fall 2017 Semi-Annual Sampling A TTACHMEN T C CHAIN OF CUSTODY Buncombe County New Landfill Fall 2017 Semi-Annual Sampling A TTACHMEN T D GROUNDWATER CONTOUR MAPS Monitoring Well Locations Figure 1 Buncombe County New Landfill81 Panther Branch RoadAlexander, North Carolina 28701 Tampa, FL January 2018 Document Path: F:\PROJECT\09204072.15\GIS\BuncombeCo_NewLF.mxd &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< !< !< !< !< !< !< !< !< !<!< !< MW-1 MW-2MW-3R MW-4 MW-5 MW-6 MW-7 MW-8 MW-10 MW-11 MW-12 MW-13 MW-14 MW-15 MW-1D MW-2D MW-4D MW-5D MW-8D MW-10D MW-11D MW-13D MW-14D MW-12D MW-15D Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AeroGRID,IGN, and the GIS User Community² 0 250 500 750 1,000125Feet LegendGroundwater Monitoring Wells &<Shallow Well !<Deep WellProperty Boundary 1 inch = 500 feet Buncombe County New Landfill Fall 2017 Semi-Annual Sampling A TTACHMEN T E GROUNDWATER DETECTION SUMMARY Groundwater Detection Summary Report Buncombe County New Facility From:10/01/2017 To:12/01/2017 Well ID Parameter Sample Date Result Flags Units MW‐1 Alkalinity, Total 10/19/2017 46800 ug/L Barium, Total 10/19/2017 116 ug/L Chloride 10/19/2017 4170 ug/L Dissolved Oxygen 10/19/2017 5.41 mg/L Iron, Total 10/19/2017 722 ug/L Manganese, Total 10/19/2017 19.3 ug/L pH ‐ Field 10/19/2017 6.2 Std. Units Specific Conductivity ‐ Field 10/19/2017 146 umhos/cm Sulfate 10/19/2017 16900 ug/L Temperature ‐ Field 10/19/2017 15.1 deg C Total Dissolved Solids 10/19/2017 121000 ug/L Turbidity ‐ Field 10/19/2017 9.86 NTU MW‐10 Barium, Total 10/18/2017 124 ug/L Dissolved Oxygen 10/18/2017 1.27 mg/L pH ‐ Field 10/18/2017 5.9 Std. Units Specific Conductivity ‐ Field U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Thursday, December 21, 2017 Page 1 of 13 Well ID Parameter Sample Date Result Flags Units MW‐10 Specific Conductivity ‐ Field 10/18/2017 316 umhos/cm Temperature ‐ Field 10/18/2017 18.7 deg C Turbidity ‐ Field 10/18/2017 0.25 NTU Zinc, Total 10/18/2017 12.3 ug/L MW‐10D Barium, Total 10/18/2017 24 ug/L Dissolved Oxygen 10/18/2017 0.34 mg/L Nickel, Total 10/18/2017 9 ug/L pH ‐ Field 10/18/2017 6.2 Std. Units Specific Conductivity ‐ Field 10/18/2017 262 umhos/cm Temperature ‐ Field 10/18/2017 16.4 deg C Turbidity ‐ Field 10/18/2017 5.19 NTU MW‐11 Barium, Total 10/20/2017 99.8 ug/L Dissolved Oxygen 10/20/2017 0.62 mg/L pH ‐ Field 10/20/2017 6.5 Std. Units Specific Conductivity ‐ Field 10/20/2017 417 umhos/cm Temperature ‐ Field 10/20/2017 16.7 deg C Turbidity ‐ Field 10/20/2017 0.6 NTU U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Thursday, December 21, 2017 Page 2 of 13 Well ID Parameter Sample Date Result Flags Units MW‐11D Barium, Total 10/20/2017 337 ug/L Cobalt, Total 10/20/2017 19.8 ug/L Dissolved Oxygen 10/20/2017 0.4 mg/L Nickel, Total 10/20/2017 23.5 ug/L pH ‐ Field 10/20/2017 6.6 Std. Units Specific Conductivity ‐ Field 10/20/2017 421 umhos/cm Temperature ‐ Field 10/20/2017 16.7 deg C Turbidity ‐ Field 10/20/2017 5.9 NTU MW‐12 Alkalinity, Total 10/19/2017 199000 ug/L Barium, Total 10/19/2017 75.2 ug/L Chloride 10/19/2017 39600 ug/L Dissolved Oxygen 10/19/2017 1.59 mg/L Iron, Total 10/19/2017 77.2 ug/L Manganese, Total 10/19/2017 462 ug/L Nickel, Total 10/19/2017 14.9 ug/L pH ‐ Field 10/19/2017 6.3 Std. Units Specific Conductivity ‐ Field 10/19/2017 852 umhos/cm Sulfate U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Thursday, December 21, 2017 Page 3 of 13 Well ID Parameter Sample Date Result Flags Units MW‐12 Sulfate 10/19/2017 150000 ug/L Temperature ‐ Field 10/19/2017 852 deg C Total Dissolved Solids 10/19/2017 560000 ug/L Turbidity ‐ Field 10/19/2017 3.99 NTU MW‐12D Alkalinity, Total 10/19/2017 152000 ug/L Barium, Total 10/19/2017 41 ug/L Chloride 10/19/2017 13700 ug/L Dissolved Oxygen 10/19/2017 2.06 mg/L Iron, Total 10/19/2017 453 ug/L Manganese, Total 10/19/2017 45.5 ug/L pH ‐ Field 10/19/2017 6.6 Std. Units Specific Conductivity ‐ Field 10/19/2017 474 umhos/cm Sulfate 10/19/2017 66000 ug/L Temperature ‐ Field 10/19/2017 16.6 deg C Total Dissolved Solids 10/19/2017 304000 ug/L Turbidity ‐ Field 10/19/2017 13.57 NTU MW‐13 Barium, Total 10/20/2017 311 ug/L U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Thursday, December 21, 2017 Page 4 of 13 Well ID Parameter Sample Date Result Flags Units MW‐13 Cobalt, Total 10/20/2017 27.2 ug/L Dissolved Oxygen 10/20/2017 0.46 mg/L pH ‐ Field 10/20/2017 6.5 Std. Units Specific Conductivity ‐ Field 10/20/2017 450 umhos/cm Temperature ‐ Field 10/20/2017 17.7 deg C Turbidity ‐ Field 10/20/2017 8.54 NTU MW‐13D Barium, Total 10/20/2017 22.4 ug/L Dissolved Oxygen 10/20/2017 0.54 mg/L pH ‐ Field 10/20/2017 6.1 Std. Units Specific Conductivity ‐ Field 10/20/2017 452.2 umhos/cm Temperature ‐ Field 10/20/2017 18.3 deg C Turbidity ‐ Field 10/20/2017 1.92 NTU Zinc, Total 10/20/2017 10.5 ug/L MW‐14 Alkalinity, Total 10/19/2017 71600 ug/L Barium, Total 10/19/2017 54.7 ug/L Chloride 10/19/2017 3280 ug/L Dissolved Oxygen 10/19/2017 6.48 mg/L U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Thursday, December 21, 2017 Page 5 of 13 Well ID Parameter Sample Date Result Flags Units MW‐14 Iron, Total 10/19/2017 2460 ug/L Manganese, Total 10/19/2017 15.3 ug/L pH ‐ Field 10/19/2017 6.5 Std. Units Specific Conductivity ‐ Field 10/19/2017 199 umhos/cm Sulfate 10/19/2017 24900 ug/L Temperature ‐ Field 10/19/2017 13.1 deg C Total Dissolved Solids 10/19/2017 192000 ug/L Turbidity ‐ Field 10/19/2017 62.7 NTU Vanadium, Total 10/19/2017 8.1 ug/L MW‐14D Alkalinity, Total 10/19/2017 128000 ug/L Chloride 10/19/2017 1130000 ug/L Dissolved Oxygen 10/19/2017 8.24 mg/L Iron, Total 10/19/2017 64 ug/L pH ‐ Field 10/19/2017 6.2 Std. Units Specific Conductivity ‐ Field 10/19/2017 276 umhos/cm Sulfate 10/19/2017 21100 ug/L Temperature ‐ Field 10/19/2017 13.2 deg C Total Dissolved Solids U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Thursday, December 21, 2017 Page 6 of 13 Well ID Parameter Sample Date Result Flags Units MW‐14D Total Dissolved Solids 10/19/2017 190000 ug/L Turbidity ‐ Field 10/19/2017 3.41 NTU MW‐15d Alkalinity, Total 10/19/2017 156000 ug/L Barium, Total 10/19/2017 132 ug/L Chloride 10/19/2017 10500 ug/L Dissolved Oxygen 10/19/2017 4.92 mg/L Iron, Total 10/19/2017 164 ug/L Manganese, Total 10/19/2017 308 ug/L pH ‐ Field 10/19/2017 6 Std. Units Specific Conductivity ‐ Field 10/19/2017 402 umhos/cm Sulfate 10/19/2017 46500 ug/L Temperature ‐ Field 10/19/2017 14.6 deg C Total Dissolved Solids 10/19/2017 268000 ug/L Turbidity ‐ Field 10/19/2017 6.14 NTU MW‐15s Alkalinity, Total 10/19/2017 202000 ug/L Barium, Total 10/19/2017 152 ug/L Chloride 10/19/2017 18600 ug/L U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Thursday, December 21, 2017 Page 7 of 13 Well ID Parameter Sample Date Result Flags Units MW‐15s Cobalt, Total 10/19/2017 80.8 ug/L Dissolved Oxygen 10/19/2017 2.63 mg/L Iron, Total 10/19/2017 2640 ug/L Manganese, Total 10/19/2017 12600 ug/L Nickel, Total 10/19/2017 7.2 ug/L pH ‐ Field 10/19/2017 6.3 Std. Units Specific Conductivity ‐ Field 10/19/2017 464 umhos/cm Sulfate 10/19/2017 29400 ug/L Temperature ‐ Field 10/19/2017 15.3 deg C Total Dissolved Solids 10/19/2017 279000 ug/L Turbidity ‐ Field 10/19/2017 16.5 NTU MW‐1D Alkalinity, Total 10/19/2017 69100 ug/L Barium, Total 10/19/2017 39.8 ug/L Chloride 10/19/2017 2260 ug/L Dissolved Oxygen 10/19/2017 5.14 mg/L Iron, Total 10/19/2017 192 ug/L Nickel, Total 10/19/2017 5.6 ug/L pH ‐ Field U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Thursday, December 21, 2017 Page 8 of 13 Well ID Parameter Sample Date Result Flags Units MW‐1D pH ‐ Field 10/19/2017 6.6 Std. Units Specific Conductivity ‐ Field 10/19/2017 216.5 umhos/cm Sulfate 10/19/2017 44300 ug/L Temperature ‐ Field 10/19/2017 17.5 deg C Total Dissolved Solids 10/19/2017 179000 ug/L Turbidity ‐ Field 10/19/2017 5.15 NTU Zinc, Total 10/19/2017 17.1 ug/L MW‐2 Barium, Total 10/20/2017 89.4 ug/L Dissolved Oxygen 10/20/2017 1.63 mg/L pH ‐ Field 10/20/2017 6 Std. Units Specific Conductivity ‐ Field 10/20/2017 243 umhos/cm Temperature ‐ Field 10/20/2017 12.8 deg C Turbidity ‐ Field 10/20/2017 5.02 NTU MW‐2D Barium, Total 10/20/2017 116 ug/L Dissolved Oxygen 10/20/2017 2.92 mg/L pH ‐ Field 10/20/2017 6.2 Std. Units Specific Conductivity ‐ Field 10/20/2017 309.1 umhos/cm U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Thursday, December 21, 2017 Page 9 of 13 Well ID Parameter Sample Date Result Flags Units MW‐2D Temperature ‐ Field 10/20/2017 12.6 deg C Turbidity ‐ Field 10/20/2017 0.15 NTU MW‐3R Barium, Total 10/18/2017 94.6 ug/L Dissolved Oxygen 10/18/2017 4.4 mg/L Nickel, Total 10/18/2017 5.2 ug/L pH ‐ Field 10/18/2017 5.34 Std. Units Specific Conductivity ‐ Field 10/18/2017 163 umhos/cm Temperature ‐ Field 10/18/2017 16.1 deg C Turbidity ‐ Field 10/18/2017 7.06 NTU MW‐4 Barium, Total 10/20/2017 64.9 ug/L Dissolved Oxygen 10/20/2017 1.42 mg/L pH ‐ Field 10/20/2017 5.9 Std. Units Specific Conductivity ‐ Field 10/20/2017 211 umhos/cm Temperature ‐ Field 10/20/2017 16.2 deg C Turbidity ‐ Field 10/20/2017 6.47 NTU MW‐4D Barium, Total 10/20/2017 34 ug/L Chromium, Total U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Thursday, December 21, 2017 Page 10 of 13 Well ID Parameter Sample Date Result Flags Units MW‐4D Chromium, Total 10/20/2017 10.1 ug/L Dissolved Oxygen 10/20/2017 0.79 mg/L Nickel, Total 10/20/2017 5.3 ug/L pH ‐ Field 10/20/2017 6.2 Std. Units Specific Conductivity ‐ Field 10/20/2017 273 umhos/cm Temperature ‐ Field 10/20/2017 18.2 deg C Turbidity ‐ Field 10/20/2017 9.62 NTU MW‐5 Barium, Total 10/19/2017 103 ug/L Dissolved Oxygen 10/19/2017 0.56 mg/L pH ‐ Field 10/19/2017 43027 Std. Units Specific Conductivity ‐ Field 10/19/2017 210.2 umhos/cm Temperature ‐ Field 10/19/2017 18.2 deg C Turbidity ‐ Field 10/19/2017 2.17 NTU MW‐5D Barium, Total 10/19/2017 63.2 ug/L Dissolved Oxygen 10/19/2017 0.69 mg/L pH ‐ Field 10/19/2017 5.5 Std. Units Specific Conductivity ‐ Field 10/19/2017 205 umhos/cm U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Thursday, December 21, 2017 Page 11 of 13 Well ID Parameter Sample Date Result Flags Units MW‐5D Temperature ‐ Field 10/19/2017 17.5 deg C Turbidity ‐ Field 10/19/2017 1.93 NTU MW‐6 Barium, Total 10/19/2017 50 ug/L Dissolved Oxygen 10/19/2017 1.48 mg/L pH ‐ Field 10/19/2017 5.2 Std. Units Specific Conductivity ‐ Field 10/19/2017 138 umhos/cm Temperature ‐ Field 10/19/2017 16.5 deg C Turbidity ‐ Field 10/19/2017 8.8 NTU Zinc, Total 10/19/2017 10.1 ug/L MW‐7 Barium, Total 10/18/2017 139 ug/L Dissolved Oxygen 10/18/2017 0.61 mg/L pH ‐ Field 10/18/2017 6.1 Std. Units Specific Conductivity ‐ Field 10/18/2017 660 umhos/cm Temperature ‐ Field 10/18/2017 16.4 deg C Turbidity ‐ Field 10/18/2017 9.55 NTU MW‐8 Barium, Total 10/20/2017 136 ug/L Chromium, Total U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Thursday, December 21, 2017 Page 12 of 13 Well ID Parameter Sample Date Result Flags Units MW‐8 Chromium, Total 10/20/2017 6.2 ug/L Dissolved Oxygen 10/20/2017 0.3 mg/L Nickel, Total 10/20/2017 6 ug/L pH ‐ Field 10/20/2017 6.4 Std. Units Specific Conductivity ‐ Field 10/20/2017 392 umhos/cm Temperature ‐ Field 10/20/2017 17.6 deg C Turbidity ‐ Field 10/20/2017 7.4 NTU Zinc, Total 10/20/2017 12.9 ug/L MW‐8D Barium, Total 10/20/2017 158 ug/L Dissolved Oxygen 10/20/2017 0.2 mg/L pH ‐ Field 10/20/2017 6.4 Std. Units Specific Conductivity ‐ Field 10/20/2017 421.4 umhos/cm Temperature ‐ Field 10/20/2017 16.1 deg C Turbidity ‐ Field 10/20/2017 0.3 NTU U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Thursday, December 21, 2017 Page 13 of 13 Buncombe County New Landfill Fall 2017 Semi-Annual Sampling A TTACHMEN T F GROUNDWATER EXCEEDANCE SUMMARY Groundwater MCL Exceedance Summary Report Buncombe County New Facility From:10/01/2017 To:12/01/2017 Well ID Parameter Sample Date Result Flags UnitsMCL MW‐1 Iron, Total 300 10/19/2017 722 ug/L MW‐11D Cobalt, Total 1 10/20/2017 19.8 ug/L MW‐12 Manganese, Total 50 10/19/2017 462 ug/L Total Dissolved Solids 500000 10/19/2017 560000 ug/L MW‐12D Iron, Total 300 10/19/2017 453 ug/L MW‐13 Cobalt, Total 1 10/20/2017 27.2 ug/L MW‐14 Iron, Total 300 10/19/2017 2460 ug/L Vanadium, Total 0.3 10/19/2017 8.1 ug/L MW‐14D Chloride 250000 10/19/2017 1130000 ug/L MW‐15d Manganese, Total 50 10/19/2017 308 ug/L MW‐15S Cobalt, Total 1 10/19/2017 80.8 ug/L Iron, Total 300 10/19/2017 2640 ug/L U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Thursday, December 21, 2017 Page 1 of 2 Well ID Parameter Sample Date Result Flags UnitsMCL MW‐15S Manganese, Total 50 10/19/2017 12600 ug/L MW‐4D Chromium, Total 10 10/20/2017 10.1 ug/L U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Thursday, December 21, 2017 Page 2 of 2 Buncombe County New Landfill Fall 2017 Semi-Annual Sampling A TTACHMEN T G SURFACE WATER DETECTION SUMMARY Surface Water Detection Summary Report Buncombe County New Facility From:10/01/2017 To:12/01/2017 Well ID Parameter Sample Date Result Flags Units SW‐2 Barium, Total 10/16/2017 56.9 ug/L Chromium, Total 10/16/2017 311 ug/L Copper, Total 10/16/2017 12.1 ug/L Dissolved Oxygen 10/16/2017 7.5 mg/L Nickel, Total 10/16/2017 85.5 ug/L ORP ‐ Field 10/16/2017 157.3 mV pH ‐ Field 10/16/2017 7.7 Std. Units Specific Conductivity ‐ Field 10/16/2017 157.5 umhos/cm Temperature ‐ Field 10/16/2017 15.6 deg C Turbidity ‐ Field 10/16/2017 23.05 NTU Zinc, Total 10/16/2017 25.5 ug/L SW‐5 Barium, Total 10/16/2017 89.6 ug/L Chromium, Total 10/16/2017 6.8 ug/L Dissolved Oxygen 10/16/2017 8.7 mg/L Nickel, Total 10/16/2017 11.1 ug/L ORP ‐ Field U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Tuesday, December 26, 2017 Page 1 of 2 Well ID Parameter Sample Date Result Flags Units SW‐5 ORP ‐ Field 10/16/2017 184.1 mV pH ‐ Field 10/16/2017 8.3 Std. Units Specific Conductivity ‐ Field 10/16/2017 1281 umhos/cm Temperature ‐ Field 10/16/2017 14.9 deg C Turbidity ‐ Field 10/16/2017 4.1 NTU SW‐6 Barium, Total 10/16/2017 139 ug/L Cobalt, Total 10/16/2017 11.6 ug/L Dissolved Oxygen 10/16/2017 9.6 mg/L ORP ‐ Field 10/16/2017 151.7 mV pH ‐ Field 10/16/2017 6.4 Std. Units Specific Conductivity ‐ Field 10/16/2017 266.6 umhos/cm Temperature ‐ Field 10/16/2017 17 deg C Turbidity ‐ Field 10/16/2017 1.47 NTU U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Tuesday, December 26, 2017 Page 2 of 2 Buncombe County New Landfill Fall 2017 Semi-Annual Sampling A TTACHMEN T H SURFACE WATER EXCEEDANCE SUMMARY Surface Water MCL Exceedance Summary Report Buncombe County New Facility From:10/01/2017 To:12/01/2017 Well ID Parameter Sample Date Result Flags UnitsMCL SW‐2 Copper, Total 7 10/16/2017 12.1 ug/L U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Friday, February 2, 2018 Page 1 of 1 Buncombe County New Landfill Fall 2017 Semi-Annual Sampling A TTACHMEN T I LEACHATE DETECTION SUMMARY Leachate Detection Summary Report Buncombe County New Facility From:10/01/2017 To:12/01/2017 Well ID Parameter Sample Date Result Flags Units LD‐1 1,1‐Dichloroethane 10/16/2017 1.7 ug/L Barium, Total 10/16/2017 59.7 ug/L Cobalt, Total 10/16/2017 176 ug/L Dissolved Oxygen 10/16/2017 5.5 mg/L Nickel, Total 10/16/2017 48.6 ug/L ORP ‐ Field 10/16/2017 102.2 mV pH ‐ Field 10/16/2017 5.7 Std. Units Specific Conductivity ‐ Field 10/16/2017 301.9 umhos/cm Temperature ‐ Field 10/16/2017 18.6 deg C Turbidity ‐ Field 10/16/2017 5.01 NTU LD‐2 1,1‐Dichloroethane 10/16/2017 2.7 ug/L Barium, Total 10/16/2017 204 ug/L Cobalt, Total 10/16/2017 11.9 ug/L Dissolved Oxygen 10/16/2017 2.23 mg/L ORP ‐ Field 10/16/2017 ‐92.7 mV pH ‐ Field U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Friday, February 2, 2018 Page 1 of 6 Well ID Parameter Sample Date Result Flags Units LD‐2 pH ‐ Field 10/16/2017 6 Std. Units Specific Conductivity ‐ Field 10/16/2017 413.3 umhos/cm Temperature ‐ Field 10/16/2017 17.5 deg C Turbidity ‐ Field 10/16/2017 39.08 NTU LD‐3 Barium, Total 10/16/2017 225 ug/L Cobalt, Total 10/16/2017 6 L2 ug/L Dissolved Oxygen 10/16/2017 2.2 mg/L ORP ‐ Field 10/16/2017 68 mV pH ‐ Field 10/16/2017 6 Std. Units Specific Conductivity ‐ Field 10/16/2017 516.4 umhos/cm Temperature ‐ Field 10/16/2017 16.9 deg C Turbidity ‐ Field 10/16/2017 58.12 NTU Vinyl chloride 10/16/2017 1.4 ug/L LD‐4 1,1‐Dichloroethane 10/16/2017 1.4 ug/L Arsenic, Total 10/16/2017 481 ug/L Barium, Total 10/16/2017 965 ug/L Benzene 10/16/2017 3.4 ug/L U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Friday, February 2, 2018 Page 2 of 6 Well ID Parameter Sample Date Result Flags Units LD‐4 Chromium, Total 10/16/2017 287 L2 ug/L Cobalt, Total 10/16/2017 62 L2 ug/L Copper, Total 10/16/2017 213 ug/L Dissolved Oxygen 10/16/2017 2.2 mg/L Nickel, Total 10/16/2017 106 L2 ug/L ORP ‐ Field 10/16/2017 60.1 mV pH ‐ Field 10/16/2017 6 Std. Units Specific Conductivity ‐ Field 10/16/2017 657 umhos/cm Temperature ‐ Field 10/16/2017 16.3 deg C Turbidity ‐ Field 10/16/2017 16.28 NTU Vanadium, Total 10/16/2017 8.6 L2 ug/L Vinyl chloride 10/16/2017 1.7 ug/L Zinc, Total 10/16/2017 24.4 ug/L LD‐5 Arsenic, Total 10/16/2017 505 ug/L Barium, Total 10/16/2017 182 ug/L Cobalt, Total 10/16/2017 52.6 L2 ug/L Dissolved Oxygen 10/16/2017 5.6 mg/L Nickel, Total U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Friday, February 2, 2018 Page 3 of 6 Well ID Parameter Sample Date Result Flags Units LD‐5 Nickel, Total 10/16/2017 16.1 L2 ug/L ORP ‐ Field 10/16/2017 204.1 mV pH ‐ Field 10/16/2017 6.4 Std. Units Specific Conductivity ‐ Field 10/16/2017 681 umhos/cm Temperature ‐ Field 10/16/2017 18.8 deg C Turbidity ‐ Field 10/16/2017 68.22 NTU LD‐6 Barium, Total 10/16/2017 420 ug/L Cobalt, Total 10/16/2017 60.2 L2 ug/L Dissolved Oxygen 10/16/2017 3 mg/L ORP ‐ Field 10/16/2017 41.1 mV pH ‐ Field 10/16/2017 6.5 Std. Units Specific Conductivity ‐ Field 10/16/2017 612 umhos/cm Temperature ‐ Field 10/16/2017 17.7 deg C Turbidity ‐ Field 10/16/2017 41.11 NTU LD‐LECHATE Arsenic, Total 10/16/2017 13.8 ug/L Barium, Total 10/16/2017 44.5 ug/L Cobalt, Total 10/16/2017 82.6 ug/L U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Friday, February 2, 2018 Page 4 of 6 Well ID Parameter Sample Date Result Flags Units LD‐LECHATE Copper, Total 10/16/2017 29.9 ug/L Dissolved Oxygen 10/16/2017 6.63 mg/L Nickel, Total 10/16/2017 481 M1 ug/L ORP ‐ Field 10/16/2017 104.5 mV pH ‐ Field 10/16/2017 4.7 Std. Units Specific Conductivity ‐ Field 10/16/2017 452.4 umhos/cm Temperature ‐ Field 10/16/2017 17.4 deg C Turbidity ‐ Field 10/16/2017 15.37 NTU Zinc, Total 10/16/2017 218 M1 ug/L Leachate 1,4‐Dichlorobenzene 10/16/2017 1.8 ug/L Antimony, Total 10/16/2017 8.5 ug/L Barium, Total 10/16/2017 309 ug/L Chromium, Total 10/16/2017 51.4 ug/L Cobalt, Total 10/16/2017 11.9 ug/L Copper, Total 10/16/2017 7.4 ug/L Dissolved Oxygen 10/16/2017 0.7 mg/L Nickel, Total 10/16/2017 82.4 ug/L ORP ‐ Field U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Friday, February 2, 2018 Page 5 of 6 Well ID Parameter Sample Date Result Flags Units Leachate ORP ‐ Field 10/16/2017 158.4 mV pH ‐ Field 10/16/2017 7.9 Std. Units Specific Conductivity ‐ Field 10/16/2017 5570 umhos/cm Temperature ‐ Field 10/16/2017 18.6 deg C Toluene 10/16/2017 3.7 ug/L Turbidity ‐ Field 10/16/2017 42.07 NTU Vanadium, Total 10/16/2017 31.1 ug/L Zinc, Total 10/16/2017 50.2 ug/L U  =     Indicates that the compound was analyzed for but not detected. BDL =  Indicates that the compound was analyzed for but not detected. I    =     The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V  =     Indicates the anlyte was detected in both the sample and the associated method blank. Friday, February 2, 2018 Page 6 of 6