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HomeMy WebLinkAbout10002_YanceyCountyCDLF_20180124Jan 24, 2018 January 2018 Yancey-Mitchell County Closed Construction and Demolition Debris Landfill Fall 2017 Semiannual Water Quality Monitoring Report Yancey County, North Carolina, Permit No. 100-02 Prepared for Yancey County, North Carolina Project Number: C61485-01.01.01 \\Asheville1\asheville\Projects\Yancey County\Solid Waste\Reports\2017\Fall\C&D LF\FINAL10002September 2017 Water Quality Report .docx January 2018 Yancey-Mitchell County Closed Construction and Demolition Debris Landfill Fall 2017 Semiannual Water Quality Monitoring Report Yancey County, North Carolina, Permit No. 100-02 Prepared for 110 Town Square Yancey County Courthouse, Room 11 Burnsville, North Carolina 28714 Prepared by Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Alec Macbeth, PG Project Geologist Fall 2017 Semiannual Water Quality Monitoring Report i January 2018 TABLE OF CONTENTS 1 Introduction ................................................................................................................................ 1 2 Methods ....................................................................................................................................... 2 2.1 Groundwater and Surface Water Sampling .............................................................................................. 2 2.1.1 Groundwater Purging and Sampling Methods ........................................................................ 2 2.1.2 Surface Water Sampling Methods ................................................................................................ 3 2.2 Sample Handling, Documentation, and Analysis .................................................................................... 4 3 Findings ........................................................................................................................................ 5 3.1 Analytical Results ................................................................................................................................................. 5 3.1.1 Groundwater Samples ....................................................................................................................... 6 3.1.2 Surface Water Samples ..................................................................................................................... 7 3.2 Hydrogeology ....................................................................................................................................................... 8 4 Summary ...................................................................................................................................... 9 4.1 Future Activities ................................................................................................................................................... 9 5 References ................................................................................................................................. 10 TABLES Table 1 Monitoring Well Construction Summary Table 2 Summary of Laboratory Analyses Performed on Samples Table 3 Summary of Analytical Results FIGURES Figure 1 Site Location Map Figure 2 Sample Location and Posted Data Map Figure 3 Generalized Groundwater Flow Direction Map APPENDICES Appendix A Sampling Logs and Equipment Documentation and Instrument Calibration Datasheets Appendix B Reports of Laboratory Analysis and Chain-of-Custody Documentation Fall 2017 Semiannual Water Quality Monitoring Report ii January 2018 ABBREVIATIONS µS/cm microsiemens per centimeter Anchor QEA Anchor QEA of North Carolina, PLLC C&D construction and demolition debris DENR North Carolina Department of Environment and Natural Resources DEQ Department of Environmental Quality DO dissolved oxygen EPA U.S. Environmental Protection Agency feet-TOC feet below the top of the well casing IMAC interim maximum allowable concentration MDL method detection limit mg/L milligrams per liter MRL method reporting limit MSW Municipal Solid Waste mV millivolt NCAC North Carolina Administrative Code NTU nephelometric turbidity unit ORP oxidation reduction potential SC specific conductivity SU Standard Units SWS Solid Waste Section SWSL Solid Waste Section Limit TDS total dissolved solids VOC volatile organic compound Fall 2017 Semiannual Water Quality Monitoring Report 1 January 2018 1 Introduction This Fall 2017 Semiannual Water Quality Monitoring Report is presented by Anchor QEA of North Carolina, PLLC (Anchor QEA). The Yancey County Solid Waste Department operates a solid waste facility located on Landfill Road near U.S. Highway 80, 7 miles from Burnsville, North Carolina (Figure 1). The facility accepts solid waste from Yancey and Mitchell Counties and includes the following permitted components: • A closed municipal solid waste (MSW) landfill (Permit No. 100-01) • A closed construction and demolition debris (C&D) landfill (Permit No. 100-02) • An active transfer station (Permit No. 100-03T) The approximate locations of the two landfill units within the solid waste facility are shown in Figure 2. This report addresses water quality associated with the C&D Landfill. Water quality at the MSW Landfill is addressed in a separate report (Anchor QEA 2018). This report documents the second semiannual groundwater and surface water monitoring event for 2017 and is being submitted in accordance with requirements stipulated in the North Carolina Department of Environment and Natural Resources (DENR)1 letter, “Construction & Demolition Debris Unit Closure – Yancey/Mitchell Landfill” (DENR 2008a), issued to the county on December 30, 2008; and in accordance with regulations codified in the Department of Environmental Quality (DEQ) Solid Waste Management Rules Title 15A, North Carolina Administrative Code (NCAC) Subchapter 13B, Section .0531 (15A NCAC 13B .0531). This report provides an evaluation of surface water and groundwater quality for the C&D Landfill. The water quality monitoring network for the C&D Landfill consists of two compliance monitoring wells (MW-H and MW-I), one background monitoring well (MW-J), and two surface water sampling locations (SW-1 and SW-2) positioned along the North Toe River (Figure 2). 1 The former DENR is now known as the Department of Environmental Quality (DEQ). Fall 2017 Semiannual Water Quality Monitoring Report 2 January 2018 2 Methods 2.1 Groundwater and Surface Water Sampling On September 26 and 27, 2017, groundwater and surface water samples were collected by Anchor QEA. The sampling locations are shown in Figure 2. A summary of monitoring well construction and water level measurement is presented in Table 1. This table includes both the closed C&D Landfill wells and the closed MSW Landfill wells to provide a more comprehensive dataset for evaluating groundwater flow direction. Table 2 provides a list of collected groundwater and surface water samples that are associated with the C&D Landfill and the laboratory analyses performed on each sample. 2.1.1 Groundwater Purging and Sampling Methods Prior to purging the monitoring wells, the static water level was gauged with a decontaminated Geotech ET Water Level Meter. During the purging process, field parameters—pH, specific conductivity (SC), dissolved oxygen (DO), turbidity, oxidation reduction potential (ORP), and temperature—were recorded with a YSI 556 Multiprobe Water Quality Meter. Well sampling logs with static water level measurements and field parameter data are included in Appendix A. Static water level measurements are also provided in Table 1. Groundwater samples were collected after the monitoring wells had been purged and field parameters had stabilized. When monitoring wells were purged with a disposable bailer, a minimum of three well volumes were purged or, if the well recharged slowly, the monitoring well was bailed dry and allowed to recharge prior to sampling. Anchor QEA personnel used a disposable bailer, a bladder pump, or a downhole GeoTech Geosub pump to purge the wells and collect groundwater samples. Total well depth, condition of the casing, and the groundwater recharge rate were used to determine the purging and sample collection method employed at each monitoring well. Sample collection methods were recorded in the sampling logs provided in Appendix A. The specific purging methodologies used for the individual monitoring wells are described in Sections 2.1.1.1 through 2.1.1.3. These methodologies are consistent with historical practices. 2.1.1.1 Monitoring Well MW-H The total depth of monitoring well MW-H is 64.50 feet below the top of the well casing (feet-TOC), as measured on the day of purging, and it is screened within the saprolite portion of the aquifer (Table 1). A new disposable bailer was used to sample this well because it recharges slowly. Anchor QEA technicians purged the monitoring well dry after purging approximately one well volume on September 26, 2017, and returned on September 27, once the well had recharged, to collect the groundwater sample. Field parameters were recorded for the initial groundwater Fall 2017 Semiannual Water Quality Monitoring Report 3 January 2018 withdrawal and prior to collecting the sample. Groundwater samples were placed in laboratory- supplied sample bottles by a technician wearing a new pair of nitrile gloves. 2.1.1.2 Monitoring Well MW-I The total depth of monitoring well MW-I is 83.00 feet-TOC, as measured with a water level meter during a prior sampling event, and it is screened within the saprolite portion of the aquifer. A bladder pump and low-flow sampling techniques were used to purge and sample this well on September 26, 2017, in accordance with the procedures described in Low-Flow (Minimal Drawdown) Ground-Water Sampling Procedures (Puls and Barcelona 1996). During purging, field parameters were measured and recorded approximately every 3 minutes. Well purging continued until these parameters stabilized for three consecutive readings, as outlined by the U.S. Environmental Protection Agency (EPA) Region 4 Science and Ecosystem Support Division in Operating Procedure: Groundwater Sampling (EPA 2017). Stabilization criteria were as follows: • pH values within 0.1 unit • SC values within 3% • Temperature, DO, and turbidity values within 10% • ORP values within 10 millivolts (mV) Once the parameters stabilized, groundwater samples were collected and placed in laboratory-supplied sample bottles by a technician wearing a new pair of nitrile gloves. 2.1.1.3 Monitoring Well MW-J MW-J has a total depth of 196.80 feet-TOC (Table 1) and is located on a ridge in the southwestern area of the C&D Landfill (Figure 2). It is screened in bedrock and serves as the background monitoring well for the water quality monitoring network. A bladder pump could not be used to purge or sample this well, due to the pressure head caused by the deep groundwater level (146.01 feet-TOC). Instead, Anchor QEA technicians used a Geotech Geosub pump and performed low-flow sampling techniques to purge and sample the well on September 26, 2017. During purging, the field parameters for groundwater were measured and recorded approximately every 3 minutes. Well purging continued until these parameters stabilized for three consecutive readings. The stabilization criteria were the same as for well MW-I (as described in Section 2.1.1.2). Once the parameters stabilized, groundwater samples were collected and placed in laboratory-supplied sample bottles by a technician wearing a new pair of nitrile gloves. 2.1.2 Surface Water Sampling Methods Surface water samples SW-1 and SW-2 were collected on September 26, 2017, from designated locations on the North Toe River, which is located east of the C&D Landfill (Figures 1 and 2). Sample SW-1 represents surface water quality upstream of the C&D Landfill, and sample SW-2 represents Fall 2017 Semiannual Water Quality Monitoring Report 4 January 2018 surface water quality downstream of the C&D Landfill. One round of surface water field parameters, consisting of temperature, pH, SC, DO, ORP, and turbidity, was measured and recorded at each sampling location prior to collecting the sample. The collected samples were placed in laboratory-supplied sample containers by a technician wearing a new pair of nitrile gloves. 2.2 Sample Handling, Documentation, and Analysis Field parameters and additional observations pertaining to the C&D Landfill sampling locations are provided in sampling logs included in Appendix A. Following collection, each groundwater and surface water sample was immediately placed on ice in a sample cooler for shipment to Prism Laboratories, a North Carolina-certified laboratory located in Charlotte, North Carolina. Table 2 provides details of the laboratory analyses performed on the samples. Proper chain-of-custody documentation practices were followed during collection and transportation of each sample; this documentation is included in Appendix B of this report. For each of the sampling groups collected on September 26 and 27, 2017, a trip blank provided by the laboratory was placed in the sample cooler and analyzed for Appendix I volatile organic compounds (VOCs). The laboratory analytical reports are provided in Appendix B. Fall 2017 Semiannual Water Quality Monitoring Report 5 January 2018 3 Findings 3.1 Analytical Results The laboratory analytical results and field parameter data for the groundwater and surface water samples collected at the landfill are included in Appendices A and B, as well as in the Electronic Data Deliverable, which is submitted separately to the DEQ Division of Waste Management, Solid Waste Section (SWS), per applicable guidelines. As stipulated in the SWS documents referenced in the preceding paragraph, all laboratory analytical results were reported and appropriately qualified as follows: • Non-detections: Non-detections (non-detects) are values reported by the laboratory as below method detection limits (MDLs). They are tabulated in Table 3 and are flagged with a “U” qualifier. The MDL is the minimum concentration of a substance that can be measured and reported by a laboratory with 99% confidence that the constituent concentration is greater than 0. • Solid Waste Section Limits: All detections (values above the MDL) were compared to constituent-specific Solid Waste Section Limits (SWSLs) established by DEQ. The SWSL is defined as the lowest concentration of a constituent in a sample that can be quantitatively determined with suitable precision and accuracy. A non-italicized “J” qualifier is used by the laboratory to mark parameters that are detected at estimated concentrations greater than the MDL, but less than the laboratory’s method reporting limit (MRL). The MRL is the minimum concentration of a target analyte that can be accurately determined by the referenced method. • Estimated or “J”-Qualified: If the reported concentration is greater than the laboratory MDL and MRL, but less than the SWSL, the analytical result is qualified as estimated and is flagged with an italicized “J” qualifier by Anchor QEA, per SWS reporting requirements. In addition to non-detects, detected concentrations of constituents below the applicable SWSLs are included in Table 3. • 2L Standard: Detected concentrations of constituents in groundwater samples were compared to applicable North Carolina groundwater quality standards. For most constituents, this standard is the 2L standard, defined in 15A NCAC 2L .0202. Detected concentrations of analytes in groundwater with no established 2L standard were compared either to the interim maximum allowable concentrations (IMACs) for Class GA and GSA groundwater (in accordance with 15A NCAC 02L .0202 [c]) or to Groundwater Protection Standards, pursuant to 15A NCAC 13B .1634. • 2B Standard: Detections of analytes in surface water samples were compared to the surface water quality standards described in 15A NCAC 2B (2B standards). Fall 2017 Semiannual Water Quality Monitoring Report 6 January 2018 Table 3 presents a summary of detected constituents and outlines concentrations of analytes that were above applicable SWSLs, as well as detected analytes that exceeded their respective 2L standard, IMAC, or 2B standard. 3.1.1 Groundwater Samples The following sections summarize detections of field parameters, VOCs, and metals (including Appendix I metals) in groundwater. 3.1.1.1 Field Parameters Measurements of pH were obtained on September 26 and 27, 2017, from groundwater samples collected from the monitoring wells. The pH readings from wells MW-H and MW-I were 5.50 Standard Units (SU) and 5.18 SU, respectively. Both results are below the 2L standard pH range of 6.5 to 8.5 SU (Table 3). The pH reading from MW-J was 6.67 SU, which is within the 2L standard range. These recorded pH readings are consistent with historical data. Turbidity values at the time of sampling the monitoring wells ranged from 1.13 nephelometric turbidity units (NTUs) in MW-I to 22.80 NTUs in MW-J (Table 3). Turbidity values for MW-I have generally been recorded at or close to 0.00 NTUs, with occasional spikes in the data. Turbidity values for MW-H have historically ranged from 0.00 to 147.10 NTUs. DO readings from the samples collected from the monitoring wells ranged from 2.44 milligrams per liter (mg/L) in MW-H to 5.57 mg/L in MW-J. SC measurements ranged from 81 microsiemens per centimeter (µS/cm) in MW-I to 443 µS/cm in MW-H. ORP values measured in the samples ranged from 196.1 mV in MW-H to 262.7 mV in MW-I. No SWSLs or 2L standards are established for DO, SC, or ORP. 3.1.1.2 VOCs Six VOCs were detected in groundwater samples collected from one or more of the monitoring wells (Table 3). Acetone was detected in MW-H at a concentration greater than the SWSL, but well below the applicable 2L standard (Table 3). No VOCs were detected at concentrations at or above applicable water quality standards (2L standards or IMACs). For more detail regarding VOC analytical results, refer to Table 3 and Appendix B. 3.1.1.3 Metals Eighteen metals were detected in groundwater samples collected from one or more of the monitoring wells (Table 3). Six of the metals (i.e., barium, chromium, copper, iron, manganese, and zinc) were present at concentrations above the associated SWSLs (Table 3). Cobalt, iron, and vanadium concentrations exceeded their respective water quality standards (2L standards or IMACs) in groundwater samples collected from monitoring wells MW-H and MW-J (Figure 2 and Table 3). Fall 2017 Semiannual Water Quality Monitoring Report 7 January 2018 Manganese concentrations exceeded the 2L standard in groundwater samples collected from monitoring wells MW-H and MW-I (Figure 2 and Table 3). The detected chromium concentration exceeded its 2L standard in the groundwater sample collected from monitoring well MW-J (Figure 2 and Table 3). The detected concentrations of these metals are generally consistent with historical data. 3.1.1.4 Additional Water Quality Parameters All additional water quality parameters and constituents (alkalinity, chloride, sulfate, and total dissolved solids [TDS]) that were measured or detected in the groundwater samples collected from the monitoring wells are summarized in Table 3. SWSLs are not established for these parameters, with the exception of sulfate. The detected concentrations of sulfate were below its SWSL. Chloride, sulfate, and TDS have established 2L standards. All detected concentrations of these parameters were below their applicable groundwater standards. 3.1.2 Surface Water Samples The following sections summarize detections of Appendix I VOCs, metals (including Appendix I metals), and measured field parameters in surface water samples collected during the fall 2017 sampling event. The location of sample point SW-1 in the North Toe River is upstream of the landfills and is considered to represent surface water quality at an upstream location. The location of sample point SW-2 in the North Toe River is downstream of the landfills and is considered to represent surface water quality at a downstream location (Figure 2). 3.1.2.1 Field Parameters Field parameters were obtained on September 26, 2017, for surface water samples. The pH readings were 6.14 SU and 6.55 SU for surface water samples SW-1 and SW-2, respectively. Both results are within the 2B standard range for pH and are consistent with historical data. Turbidity was measured and recorded for SW-1 and SW-2 at 2.81 NTUs and 4.72 NTUs, respectively, and both values are within the 2B standard established at 10 NTUs for trout waters (Table 3). These turbidity results are consistent with historical data. DO concentrations were compliant with the established 2B standard of greater than or equal to 6.0 mg/L. SC measurements in surface water samples SW-1 and SW-2 were recorded at 116 µS/cm and 85 µS/cm, respectively. ORP measurements in SW-1 and SW-2 were recorded at 347.6 mV and 262.5 mV, respectively. 2B standards do not exist for these field parameters. Detailed field parameter results are provided in Appendix A and Table 3. Fall 2017 Semiannual Water Quality Monitoring Report 8 January 2018 3.1.2.2 Volatile Organic Compounds No VOCs were detected in either of the surface water samples collected from the landfill. 3.1.2.3 Metals Ten metals were detected in surface water samples collected from one or both sampling locations (Table 3). None of the ten detected metals exceeded their respective SWSLs or 2B surface water standards. The variations in overall concentrations of metals between the upstream and downstream surface water samples do not show evidence of the landfill impacting surface water downstream of the landfill. Anchor QEA will continue to monitor surface water quality in the North Toe River upstream and downstream of the landfill, paying close attention to any new detections of metals in the samples. 3.1.2.4 Additional Water Quality Parameters Additional water quality parameters and constituents (alkalinity, chloride, sulfate, and TDS) were measured or detected in the surface water samples collected from the SW-1 and SW-2 locations (Table 3). SWSLs are not established for these parameters, with the exception of sulfate. The detected concentrations of sulfate were below its SWSL. Of these constituents, only chloride has an established 2B standard. Detected concentrations of chloride in both surface water samples were found to be below this standard (Table 3). 3.2 Hydrogeology Groundwater elevations were calculated for the fall 2017 semiannual water quality monitoring event using the measured depths to water and the associated top-of-casing elevations from the survey performed on the monitoring wells in October 2009. Groundwater elevation data for the C&D Landfill monitoring wells and the MSW Landfill monitoring wells are reported in Table 1. Figure 3 presents the generalized groundwater flow direction for both bedrock and saprolite. Generalized groundwater flow directions were estimated using groundwater elevation data associated with a limited number of data points in an area of complex topographic and geologic conditions. The estimated groundwater flow directions indicate groundwater in the bedrock is flowing in a generally northeasterly direction. Groundwater flow in the saprolite seems to be generally mimicking topography in the areas where data is available, and appears to be convergent toward a topographic trough in a northerly direction in the water table aquifer. Apparent groundwater flow directions and the local topography suggest groundwater is flowing toward the North Toe River. Fall 2017 Semiannual Water Quality Monitoring Report 9 January 2018 4 Summary Anchor QEA completed the second semiannual water quality monitoring event of 2017 at the Yancey-Mitchell County Closed C&D Landfill on September 26 and 27, 2017. Table 3 of this report and the Prism Reports of Laboratory Analysis included in Appendix B provide detailed analytical results and field data summarizing the groundwater and surface water quality at the Yancey-Mitchell County Closed C&D Landfill. Generally, the groundwater and surface water analytical results show constituent concentrations are below the respective SWSLs and water quality standards (2L standards and IMACs for groundwater; 2B standards for surface water), with the exception of chromium, cobalt, iron, manganese, and vanadium. Cobalt, iron, and vanadium concentrations exceeded their respective 2L standards or IMACs in groundwater samples collected from monitoring wells MW-H and MW-J. Manganese concentrations exceeded the 2L standard in groundwater samples collected from monitoring wells MW-H and MW-I. Chromium was detected at a concentration exceeding its 2L standard in the groundwater sample collected from monitoring well MW-J. No constituents exceeded any of the respective 2B surface water standards in either the upstream or the downstream surface water sample. Based on these data, it appears unlikely groundwater from the landfill is impacting the North Toe River. 4.1 Future Activities Anchor QEA will continue to measure field parameters and monitor Appendix I VOCs, metals (including Appendix I constituents), and inorganic water quality parameters in the groundwater and surface water monitoring network at the Yancey-Mitchell Closed C&D Landfill on a semiannual basis. The next sampling event is scheduled for March 2018. Fall 2017 Semiannual Water Quality Monitoring Report 10 January 2018 5 References Anchor QEA (Anchor QEA of North Carolina, PLLC), 20187. Fall 2017 Semiannual Water Quality Monitoring Report – Yancey County Closed MSW Landfill. January 2018. DENR (North Carolina Department of Environment and Natural Resources), 2008a. Letter to: Mr. Nathan Bennett, Yancey County. Regarding: Construction & Demolition Debris Unit Closure – Yancey/Mitchell Landfill. Yancey County, Permit No. 100-02, Document ID No. 6314. Division of Waste Management, Solid Waste Section. December 30, 2008. EPA (U.S. Environmental Protection Agency), 2017. Operating Procedure: Groundwater Sampling. Science and Ecosystem Support Division. April 26, 2017. Puls, R.W., and M.J. Barcelona, 1996. Low-Flow (Minimal Drawdown) Ground-Water Sampling Procedures. Prepared for the U.S. Environmental Protection Agency. OSWER, EPA/540/S- 95/504. Tables Table 1 Monitoring Well Construction Summary Northing Easting Ground Surface Elevation TOC Elevation Stick Up Total Well Depth Depth To Water Groundwater Elevation Approximate Depth to Bedrock Approximate Bedrock Elevation Depth to Top of Screened Interval Depth to Bottom of Screened Interval Top of Screen Elevation Elevation of Bottom of Screen (NAD 83; 2007)(NAD 83; 2007) (feet NAVD 88) (feet NAVD 88) (feet above ground surface) (feet below TOC) (feet below TOC) (feet NAVD 88) (feet below ground surface) (feet NAVD 88) (feet below ground surface) (feet below ground surface) (feet NAVD 88) (feet NAVD 88) C&D Landfill Monitoring Wells 100-02 MW-H 12/04/1996 809563.75 1058698.38 2,566.36 2,568.68 2.3 64.5 60.75 2,507.93 62 2,504 47.0 62.0 2,519.4 2,504.4 100-02 MW-I 12/02/1996 809923.04 1058531.91 2,596.57 2,598.77 2.0 83.0 65.95 2,532.82 ~85 2,512 64.0 79.0 2,532.6 2,517.6 100-02 MW-J 11/26/1996 808698.05 1057994.86 2,873.58 2,875.99 2.3 196.80 148.06 2,727.93 2 2,872 179.5 194.5 2,694.1 2,679.1 Bedrock MSW Landfill Monitoring Wells 100-01 MW-2 No Well Record 809474.01 1059181.42 2,568.85 2,572.06 3.2 56.3 36.20 2,535.86 100-01 MW-3 No Well Record 809357.74 1058830.13 2,551.34 2,553.57 1.7 38.0 32.84 2,520.73 100-01 MW-AR No Well Record 808483.97 1059176.2 2,688.76 2,691.17 2.3 71.4 63.08 2,628.09 Assumed Bedrock 100-01 MW-B 12/02/1996 809020.07 1059514.58 2,624.07 2,626.27 2.0 70.0 60.95 2,565.32 18 2,606 53.0 68.0 2,571.1 2,556.1 Bedrock DENR Well Construction/ Drilling Log Record, dated 12/31/1996 Notes: Survey data showing the horizontal and vertical positions of the monitoring wells were presented in Appendix A of the Fall 2009 Semiannual Water Quality Monitoring Report, Yancey-Mitchell County Construction and Demolition Debris Landfill, dated November 16, 2009. Depth to water was measured on September 26 and 27, 2017. "No Well Record" indicates that the well record, if it exists, was not readily obtainable. C&D: construction and demolition debris MSW: municipal solid waste NAD: North American Datum 1983 NAVD: North American Vertical Datum 1988 TOC: top of casing Saprolite DENR Well Construction/ Drilling Log Record, dated 12/31/1996 Assumed Saprolite No Well Construction/ Drilling Record is Available No Well Record No Well Record No Well Record No Well Record No Well Record No Well Record Source of Well Construction InformationFacility Permit Well ID Date Drilled Geology of Screened Interval Fall 2017 Semiannual Water Quality Monitoring Report Yancey-Mitchell County Closed Construction and Demolition Debris Landfill Page 1 of 1 January 2018 Table 2 Summary of Laboratory Analyses Performed on Samples Groundwater Samples VOCs Metals Sulfate Chloride TDS Alkalinity EPA 8260B EPA 6020B EPA 7470A EPA 9056A EPA 9056A SM 2540C SM 2320B 100-02 MW-H 09/27/2017 X X X X X X 100-02 MW-I 09/26/2017 X X X X X X 100-02 MW-J 09/26/2017 X X X X X X Surface Water Samples VOCs Metals Sulfate Chloride TDS Alkalinity EPA 8260B EPA 6020B EPA 7470A EPA 9056A EPA 9056A SM 2540C SM 2320B 100-02 SW-1 09/26/2017 X X X X X X 100-02 SW-2 09/26/2017 X X X X X X Quality Control Samples VOCs EPA 8260B 100-02 TRIP BLANK (C&D)09/27/2017 X 100-02 TRIP BLANK (J)09/26/2017 X 100-02 TRIP BLANK (SW)09/26/2017 X Notes: VOC: volatile organic compound C&D: construction and demolition debris landfill EPA: U.S. Environmental Protection Agency SM: Standard Method TDS: total dissolved solid Facility Permit Well ID Collect Date Facility Permit Well ID Collect Date Facility Permit Sample ID Collect Date VOCs and metals analysis include Appendix I constituents per 40 Code of Federal Regulations Part 258. Metals include manganese, iron, and mercury, in addition to Appendix I constituents. Tetrahydrofuran analysis has been performed since the spring 2011 sampling event, per the North Carolina Division of Waste Management, Solid Waste Section requirement specified in the June 25, 2010 memorandum. Fall 2017 Semiannual Water Quality Monitoring Report Yancey-Mitchell County Closed Construction and Demolition Debris Landfill Page 1 of 1 January 2018 Table 3 Summary of Analytical Results Metals (including Appendix I) Lab Certification 40 Lab Methods EPA 6020B and EPA 7470A (Mercury) Parameter Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Iron Lead Manganese Mercury Nickel Selenium Silver Thallium Vanadium Zinc CAS Number 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-89-6 7439-92-1 7439-96-5 7439-97-6 7440-02-0 7782-49-2 7440-22-4 7440-28-0 7440-62-2 7440-66-6 SWS ID 13 14 15 23 34 51 53 54 340 131 342 132 152 183 184 194 209 213 Units µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L Sample ID Collect Date Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result MW-H 09/27/2017 0.41 U 0.45 U 120 0.38 J 0.35 J 9.6 J 3.2 J 11 4,700 1.8 J 1,300 0.090 J 6.8 J 0.62 J 0.20 J 0.20 J 5.6 J 26 MW-I 09/26/2017 0.41 U 0.45 U 95 J 0.27 J 0.11 J 0.38 J 0.58 J 0.74 J 21 J 0.17 J 100 0.036 U 1.7 J 0.45 U 0.067 U 0.13 J 0.79 U 18 MW-J 09/26/2017 0.90 J 1.7 J 24 J 0.068 U 0.064 J 12 1.6 J 7.7 J 1,200 1.1 J 50 J 0.036 U 12 J 1.2 J 0.067 U 0.040 J 1.1 J 8.5 J SW-1 09/26/2017 0.41 U 0.45 U 23 J 0.068 U 0.053 U 0.30 J 0.081 J 0.89 J 210 J 0.14 J 19 J 0.036 U 0.37 J 0.45 U 0.067 U 0.028 J 0.79 U 4.4 JSW-2 09/26/2017 0.41 U 0.45 U 18 J 0.068 U 0.053 U 0.29 J 0.074 J 0.79 J 170 J 0.15 J 13 J 0.036 U 0.14 J 0.45 U 0.067 U 0.028 J 0.79 U 3.7 J TRIP BLANK (C&D)09/27/2017 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA TRIP BLANK (J)09/26/2017 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA TRIP BLANK (SW)09/26/2017 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA MDL 0.41 0.450 0.12 0.068 0.053 0.081 0.056 0.41 20 0.061 0.76 0.036 0.082 0.45 0.067 0.018 0.79 1.3 MRL 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 100 1.0 5.0 0.20 2.0 5.0 5.0 1.0 1.0 10 SWSL 6 10 100 1 1 10 10 10 300 10 50 0.2 50 10 10 5.5 25 10 2L NE 10 700 NE 2 10 NE 1,000 300 15 50 1 100 20 20 NE NE 1,000 IMAC 1 NE NE 4 NE NE 1 NE NE NE NE NE NE NE NE 0.2 0.3 NE GWPS 1 NE NE 4 NE NE 1 NE NE NE NE NE NE NE NE 0.28 0.3 NE 2B 640 10 200,000 6.5 0.15 35 4 2.7 NE 0.54 NE 0.012 16 5 0.06 0.47 NE 36 Groundwater Samples Surface Water Samples Quality Control Samples Fall 2017 Semiannual Water Quality Monitoring Report Yancey-Mitchell County Closed Construction and Demolition Debris Landfill Page 1 of 2 January 2018 Table 3 Summary of Analytical Results VOCs (Appendix I)Inorganics Field Parameters Lab Certification 12 Lab Methods EPA 8260B EPA 9056A EPA 9056A SM2320 B SM2540 C 5445 (pH only) Parameter Acetone cis-1,2- Dichloro- ethene m & p Xylene Tetra- hydrofuran Trichloro- fluoro- methane Xylene (Total)Chloride Sulfate Total Alkalinity to pH 4.5 Total Dissolved Solids pH Dissolved Oxygen Turbidity Temperature Specific Conductivity Oxidation Reduction Potential CAS Number 67-64-1 156-59-2 108-38-3 109-99-9 75-69-4 1330-20-7 16887-00-6 14808-79-8 NA NA SW320 7782-44-7 SW330 SW325 SW323 SW336 SWS ID 3 78 359 458 203 346 301 315 337 311 320 356 330 325 323 336 Units µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L SU mg/L NTU °C µS/cm mV Sample ID Collect Date Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result MW-H 09/27/2017 140 0.58 J 0.12 U 37 0.062 U 0.15 U 29,000 110,000 J 120,000 330,000 5.50 2.44 4.09 14.88 443 196.1 MW-I 09/26/2017 0.31 U 0.056 U 0.12 U 30 0.52 J 0.15 U 13,000 200 U 21,000 44,000 J 5.18 3.05 1.13 14.36 81 262.7 MW-J 09/26/2017 0.31 U 0.056 U 0.71 J 0.16 U 0.062 U 0.71 J 1,400 55,000 77,000 160,000 6.67 5.57 22.8 14.76 273 220.4 SW-1 09/26/2017 0.31 U 0.056 U 0.12 U 0.16 U 0.062 U 0.15 U 7,000 17,000 J 20,000 54,000 6.14 8.52 2.81 19.56 116 347.6SW-2 09/26/2017 0.31 U 0.056 U 0.12 U 0.16 U 0.062 U 0.15 U 5,300 10,000 J 17,000 40,000 J 6.55 8.07 4.72 20.23 85 262.5 TRIP BLANK (C&D)09/26/2017 0.31 U 0.056 U 0.12 U 0.16 U 0.062 U 0.15 U NA NA NA NA NA NA NA NA NA NA TRIP BLANK (J)09/27/2017 0.31 U 0.056 U 0.12 U 0.16 U 0.062 U 0.15 U NA NA NA NA NA NA NA NA NA NA TRIP BLANK (SW)09/26/2017 0.31 U 0.056 U 0.12 U 0.16 U 0.062 U 0.15 U NA NA NA NA NA NA NA NA NA NA MDL 0.31 0.056 0.12 0.16 0.062 0.15 40 200 770 1,400 NA NA NA NA NA NA MRL 5.0 0.50 1.0 10 0.50 1.5 1,000 1,000 5,000 50,000 NA NA NA NA NA NA SWSL 100 5 NE NE 1 5 NE 250,000 NE NE NE NE NE NE NE NE 2L 6,000 70 NE NE 2000 500 250,000 250,000 NE 500,000 6.5-8.5 NE NE NE NE NE IMAC NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE GWPS NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE 2B 2,000 720 550 NE 67,000 450 230,000 NE NE NE 6.0-9.0 > 6.0 10 NE NE NE Groundwater Samples Surface Water Samples Quality Control Samples Fall 2017 Semiannual Water Quality Monitoring Report Yancey-Mitchell County Closed Construction and Demolition Debris Landfill Page 2 of 2 January 2018 Figures [ 0 2,0001,000 Feet NOTE:Burnsville, North Carolina is located approximately 7.0 milessouthwest of the landfill parcel boundary. LEGEND: Landfill Property Boundary Publish Date: 2018/01/23, 4:13 PM | User: alesueurFilepath: \\Asheville1\Asheville\Projects\Yancey County\Solid Waste\Figures\GIS\MXD\2017\Fall\Figure 1 - Site Location Map CD AQ.mxd Figure 1Site Location Map Fall 2017 Semiannual Water Quality Monitoring ReportYancey-Mitchell County Closed Construction and Demolition Landfill SOURCES:Basemap: USGS 1:24,000 Scale Topo Maps, Micaville Quadrangle, 1987Site Property Boundary: Yancey County GIS Anchor QEA of North Carolina, PLLC%7 miles to Burnsville, NC %NC Highway 80 [ 0 500 1,000250 Feet NOTES:1. Posted data indicate constituents detected atconcentrations above their respective water qualitystandard (2L standard, Interim Maximum AllowableConcentration [IMAC], or 2B standard)2. Sample dates: September 26 and 27, 20173. Surface water sample locations are approximate. Thedownstream surface water sample (SW-2) is shown onthe map inset. LEGEND: !U Bedrock Monitoring Well Location !U Saprolite Monitoring Well Location #*Surface Water Sample Location Approximate Landfill Boundaries Landfill Parcel Boundary Streams Publish Date: 2018/01/23, 4:30 PM | User: alesueurFilepath: \\Asheville1\Asheville\Projects\Yancey County\Solid Waste\Figures\GIS\MXD\2017\Fall\Figure 2 - C&D Sample Location Map AQ.mxd Figure 2Sample Location and Posted Data Map Fall 2017 Semiannual Water Quality Monitoring ReportYancey-Mitchell County Closed Construction and Demolition Landfill SOURCES:Basemap: NC OneMap 2010Parcels and Streams: Yancey County GISMonitoring Wells: Survey data from Webb A. Morganand Associates, P.A. (2009) Anchor QEA of North Carolina, PLLC 2L Groundwater Standards or IMACIron (300 µg/L)Manganese (50 µg/L)Vanadium (0.3 µg/L)pH (6.5-8.5 Standard Units [SU]) #*!U !U !U MW-I Manganese (100 µg/L)pH (5.18 SU) MW-H Iron (4,700 µg/L) Manganese (1,300 µg/L)Vanadium (5.6 J µg/L)pH (5.50 SU) MW-J (Background Well) Iron (1,200 µg/L) Vanadium (1.1 J µg/L) Construction and Demolition Debris Landfill Municipal Solid Waste Landfill SW-1 No Exceedances%Flo w D i r e c t i o n Transfer Station NORTH TOE R IVERNORTH TOE R IVER WOLF BRANCHWOLF BRANCHUTUT#* #* SW-2 No Exceedances 0 6,0003,000Feet %%%% !U !U !U !U !U !U !U %Flow Direction Flow Direction Generalized Bedrock Groundwater Flow Generalized SaproliteGroundwater Flow Construction and DemolitionDebris Landfill Municipal SolidWaste Landfill MW-2 (2,535.86)MW-3 (2,520.73) MW-AR (2,628.09) MW-B (2,565.32) MW-J (2,727.93) MW-H (2,507.93) MW-I (2,532.82)25402580 25202380 25202560 2460 2680 2 5 6 0 2440 2 4 8 0 2420 266026402620 2420 2540 24602520 24402480 2360 2600 2500 2400 25002 5 0 0 27002600 24002700 24002500 27002400 2700 280025802420256028602480 2620272027802 7 4 0 2480 268025 4 0 252024402860272 0 24202520 2380 244024202640 2840 244027202460 28202620 2 4 602680 278026602760 2480264027602680 2360 WOLF BRANCHWOLF BRANCHREBELS CREEKREBELS CREEKNORTH TOE RIVERNORTH TOE RIVER Publish Date: 2018/01/23, 4:37 PM | User: alesueurFilepath: \\Asheville1\Asheville\Projects\Yancey County\Solid Waste\Figures\GIS\MXD\2017\Fall\Fig3AQ.mxd [ 0 400200 Feet NOTES:1. (2,522.73): Calculated groundwaterelevation2. Groundwater elevations are based ondepth to water measurements collectedon September 26 and 27, 2017. Figure 3Generalized Groundwater Flow Direction Map Fall 2017 Semiannual Water Quality ReportYancey-Mitchell County Closed Construction and Demolition Landfill LEGEND: !U Bedrock Monitoring Well Location !U Saprolite Monitoring Well Location Approximate Landfill Boundaries Elevation Contour (20-Foot Interval) Landfill Parcel Boundary Streams SOURCES:1. Parcels: Yancey County GIS2. Monitoring Wells: Survey data fromWebb A. Morgan and Associates, P.A.(2009)3. Elevation Contours: NCDOT Lidar,20074. Roads: Yancey County and MitchellCounty GIS Anchor QEA of North Carolina, PLLC Appendix A Sampling Logs and Equipment Documentation and Instrument Calibration Datasheets Appendix B Reports of Laboratory Analysis and Chain- of-Custody Documentation Page 1 of 21 Page 2 of 21 Page 3 of 21 Page 4 of 21 Page 5 of 21 Page 6 of 21 Page 7 of 21 Page 8 of 21 Page 9 of 21 Page 10 of 21 Page 11 of 21 Page 12 of 21 Page 13 of 21 Page 14 of 21 Page 15 of 21 Page 16 of 21 Page 17 of 21 Page 18 of 21 Page 19 of 21 Page 20 of 21 Page 21 of 21 Page 1 of 17 Page 2 of 17 Page 3 of 17 Page 4 of 17 Page 5 of 17 Page 6 of 17 Page 7 of 17 Page 8 of 17 Page 9 of 17 Page 10 of 17 Page 11 of 17 Page 12 of 17 Page 13 of 17 Page 14 of 17 Page 15 of 17 Page 16 of 17 Page 17 of 17 Page 1 of 20 Page 2 of 20 Page 3 of 20 Page 4 of 20 Page 5 of 20 Page 6 of 20 Page 7 of 20 Page 8 of 20 Page 9 of 20 Page 10 of 20 Page 11 of 20 Page 12 of 20 Page 13 of 20 Page 14 of 20 Page 15 of 20 Page 16 of 20 Page 17 of 20 Page 18 of 20 Page 19 of 20 Page 20 of 20