9601_WayneCountyC&DWQMR_20180112

Wayne County Active C&D and Closed MSWLF
Dudley, North Carolina
October 2017
MESCO Project Number: G17016.0
Semi-Annual Water Quality Monitoring Report
with Corrective Action Update
Prepared for
Municipal Engineering Services Company, P.A.Garner and Boone, North Carolina
P.O. Box 97
Garner, NC 27529
License No. C-0281

Permit Number: 96-01
TABLE OF CONTENTS
SECTION
Introduction Page 1
Background Page 1
Sampling Procedure Page 2
Field Parameter Data Page 2
Laboratory Results Page 3
Quality Control Samples Page 3
Groundwater Samples Detected Above Standards Page 3
Surface Water Samples Detected Above Standards Page 3
Corrective Action Update Page 3
Groundwater and Surface Water Characterization Page 4
Findings Page 4
Closing Page 4
FIGURES
Topographic Map with Site Location Figure 1
Potentiometric Map of Uppermost Aquifer w/ VOC Detection Above 2L Standard Figure 2
TABLES
Groundwater Monitoring Well Construction Table Table 1
Field Observations of Monitoring Locations Table 2
Field Parameter Data Summary Table 3
Sampling and Analysis Summary Table 4
Groundwater Sample Detections Table 5
Surface Water Sample Detections Table 6
MNA Parameter Data Summary Table 7
Hydrologic Properties at Monitoring Well Locations Table 8
APPENDICIES
Laboratory Analysis Reports and Chains of Custody Appendix A
Field Sampling Data Sheet(s) Appendix B
January 12, 2018
Ms. Christine Ritter
Solid Waste Section (SWS)
Division of Waste Management
North Carolina Department of Environmental Quality (NCDEQ)
217 West Jones Street
Raleigh, NC 27603
Re: Semi-Annual Water Quality Monitoring Report with Corrective Action Update
Wayne County Active C&D and Closed MSWLF (Dudley)
Permit No. 96-01
MESCO Project No. G17016.0
Event Date(s): October 4-5, 2017
Dear Ms. Ritter,
Introduction
The Wayne County Landfill (Permit #96-01) is located at 460 S Landfill Road (SR 1129), Dudley, Wayne County,
North Carolina. A topographic map showing the location of the site is included as Figure 1.
The Wayne County unlined closed Municipal Solid Waste Landfill (MSWLF) and active Construction and
Demolition (C&D) Landfill located in Dudley NC, currently operating under Permit #96-01 is required to submit
semi-annual compliance reports as a condition of 15A NCAC 13B.1630. This report documents the quality of the
ground and surface waters during this monitoring event performed on October 4-5, 2017. Laboratory analytical
results, which consisted of targeting Appendix I constituents, indicate that four metals were detected above
applicable regulatory groundwater Standards in samples collected from five wells including the background well.
Benzene was also detected above groundwater Standards in sample MW-2. No contaminants were detected above
applicable surface water Standards in any surface water sample sample collected during this event. A Corrective
Action Evaluation Report (CAER) dated June 5, 2017 concluded groundwater quality has improved. Corrective
action via monitored natural attenuation (MNA) will continue and phytoremediation is planned to be initiated in the
spring of 2018.
As specified within 15A NCAC 13B.1632(j), the SWS Environmental Monitoring Report Form and SWS
memorandums this report contains sampling procedures, field and laboratory results, corrective action update,
ground/surface water characterization, and findings. Well construction summary table, field observations table, field
parameter data table, sampling and analysis summary table, detections compared to Standards tables, MNA
parameter summary table, a groundwater flow directions/rates table, potentiometric map, quality assurance/quality
control data, and laboratory analytical data results are enclosed herein.
Background
Prior to operating as a C&D landfill the site operated as a Municipal Solid Waste (MSW) unlined sanitary landfill
that consisted of two units. The first unit (Unit 1) was closed prior to October 1991 with a 24 inch final soil cover.
The second unit (Unit 2) was closed with a low permeability cohesive cap and erosive layer prior to December 31,
1998 in accordance with the Transition Plan. The C&D landfill is operating on top of the Unit 2 MSW landfill.
The separate active Subtitle D Lined MSWLF (permit #96-06), located adjacent to the C&D landfill across an
unnamed tributary of Edward's Branch, was monitored in conjunction with this site but reported separately.
Water quality at this landfill has been monitored at least semi-annually since 1991. Current data was compared to data
compiled since 1994 in support of this report. Municipal Engineering Services Company, P.A. (MESCO) submitted an
Assessment and Corrective Action (ACM) [DIN8821] report dated August 30, 2007 which was approved by the NC Solid
Waste Section (SWS) on November 1, 2007 [DIN3328]. MESCO then developed a Corrective Action Plan (CAP)
[DIN8821] on October 22, 2009 which was approved by the SWS on October 23, 2009 [DIN8822]. A CAP-Addendum
which provided details concerning phytoremediation in addition to monitored natural attenuation (MNA) near MW-2 was
submitted to the SWS on December 20, 2017.
Groundwater remediation using Monitored Natural Attenuation (MNA) was initiated on August 6, 2009 and has
continued on a semi-annual basis. Following establishment of the two year MNA baseline, MESCO completed a CAER
[DIN 13923] on May 10, 2011. The CAER was reviewed and the proposed modifications of MNA parameters and
frequency were approved by the SWS [DIN 16967]. Background well MW-1 was abandoned and replaced by MW-1R
as pre-authorized by SWS [DIN 19050] on June 4, 2013. MESCO submitted a Request for Appendix II Groundwater
Monitoring Modification dated April 24, 2014 which was approved by the SWS. The Water Quality Sampling and
Analysis Plan (SAP) which provides for a subset of wells to decrease Appendix II monitoring frequency was revised and
submitted on December 15, 2014 as requested by the SWS. A second CAER which proposes modifications to the
parameters, frequency and wells to continue MNA was submitted to the SWS on June 5, 2017.
Sampling Procedure
MESCO performed this sampling event utilizing portable monitoring methodology in accordance with the approved SAP
based on the Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling revised April 2008.
The site-specific SAP entails continued semi-annual water quality monitoring which includes annual corrective action
monitoring and targeting of specific Appendix II constituents at a subset of wells once every three years. Keeping with
the established schedule this event consists of targeting Appendix I contaminants and tetrahydrofuran at all groundwater
locations and an abbreviated set of MNA performance parameters at MW-1R, MW-2 and MW-8. Water samples were
collected from monitoring locations designated in the SAP with the exception of SW-2 and SW-3 which were dry. Water
quality monitoring was performed on eight wells (MW-2, MW-3, MW-4, MW-5, MW-6, MW-7, MW-8 and MW-11),
background well (MW-1R) and surface water point (SW-1). Quality control measures implemented during this event
included quantification of an equipment blank (EB), field blank (FB) and travel blank (TB). A supplemental surface
water sample (SW-By_MW-2) was collected from the western tributary of Edward's Branch directly downgradient of
MW-2 to ensure contaminants remain delineated within the property boundary. Data from a surface water location from
the Subtitle D Lined SAP SW-6 (shared) is presented because both units share this local discharge feature. Monitoring
locations are depicted on the potentiometric map, included as Figure 2.
A summary detailing the construction of the water monitoring wells is presented on Table 1. The function and integrity
of all monitoring locations were visually evaluated and minor deficiencies documented on Table 2. The depth to water in
each well was electronically gaged prior to purging to quantify the static water level elevation. Low-flow pumping
methodology or bailing was utilized to adequately purge the wells a minimum of three times the volume of standing water
in the well or until dry. Surface water samples were dipped from the surface of the creeks at previously designated
locations. Samples were then placed into laboratory-prepared, pre-preserved containers. Samples were kept on ice and
transported to a NC-certified laboratory under proper chain of custody (C-O-C) protocol and analyzed within the required
hold times.
Field Parameter Data
Stabilized field parameters were recorded during purging which included pH, specific conductance, temperature,
dissolved oxygen (DO), oxidation reduction potential (ORP) and turbidity. Turbidity was measured in the field during
pre-purge (composite of the first bailer) which represents the approximate lowest turbidity levels. Pre-purge turbidity
levels were only slightly (< 10%) lower than post-purge. A summary of the field parameter data is presented in Table 3
and the field sampling data sheet is enclosed in Appendix B.
2
Laboratory Results
Pace Analytical Laboratories (PACE) performed the laboratory analysis. All water samples were analyzed for
constituents listed in Appendix I 40 CFR 258, CDLF parameter tetrahydrofuran and turbidity. A sampling and analysis
table summarizing the locations, targeted constituents and methods is presented as Table 4. Laboratory results and C-O-
Cs are contained in Appendix A.
Water samples were analyzed to the laboratory-established Method Detection Limits (MDL), which are at or below the
current Solid Waste Section Limit (SWSL). Table 5 summarizes constituents detected in groundwater and QC samples
compared to current SWSL, SWS adopted Groundwater Protection Standards (GWP), North Carolina Groundwater
Standards (2L) and the Maximum Contaminant Level (MCL) commonly referenced as the Federal “Drinking Water
Standard”. Table 6 lists the constituents detected in surface water samples compared SWSL, the North Carolina Surface
Water Standards (2B) for a Class C water-body and the MCL.
Quality Control Samples
No contaminants were detected in any of the quality control blanks (EB, FB, TB), therefore the data set appears to be
valid.
Groundwater Samples Detected Above Standards
Metals
A total of four metals were detected above their respective 2L/GWP Standard in samples collected from five wells
including the upgradient background well as summarized below.
Constituents Detected Above 2L/GWP Standards in Groundwater
Ar Cd Co Va
2L/GWP STD.10 2 1 0.3
MW-1R (BG Well)6 J
MW-2 22.2 4.9 J
MW-3 4 J
MW-7 3.5
MW-11 2.3 5.6 J 7.2 J
Concentrations in ug/L. J = “j-qualified” since below the SWSL thus value is considered an estimate
VOCs
Benzene was detected in sample MW-2 (1.8 ug/L) which is above the 2L Standard (1.0 ug/L).
Surface Water Samples Detected Above Standards
Constituents were not detected in any surface water sample in concentrations above the established 2B Standards.
Supplemental surface water sample SW-By_MW-2 collected at the property line approximately 166 feet hydraulically
downgradient of MW-2 continues to lack contaminants.
Corrective Action Update
Groundwater remediation measures through MNA continues to be implemented at the facility. Semi-annual MNA
monitoring of MW-2, MW-8 and background well MW-1 was initiated on August 6, 2009 and was consistently
performed for the full suite of SWS recommended parameters for seven consecutive semi-annual events. The SAP
prescribes MNA monitoring for specific constituents to be performed annually or bi-annually. MNA field parameters
were analyzed during this event with concentrations presented on Table 7.
3
Figures
FIGURE 1Wayne County Landfill (Dudley)SITE LOCATION (USGS TOPO)
DATEDRAWING NO.SHEET NO.
SCALE:
DATE:
DRWN. BY:
CHKD. BY:
PROJECT NUMBERBYREV.DESCRIPTION
Table
Table 1
Groundwater Monitoring Well Construction Table
October 5, 2017
Well
Diameter
Total
Well
Depth
Top of
Screen
Depth
Screen
Length
Top of
Casing
Elevation
Ground
Elevation
Groundwater
Elevation
Depth
to Water
(inches)(ft bgs)(ft bgs)(ft)(ft amsl)(ft amsl)(ft amsl)(ft btoc)
MW-1R 6/4/13 2 27.32 12.32 15 Soil Sand 169.64 166.64 147.89 21.75 35.292408 -78.064431
MW-2 8/28/90 2 15 10 5 Soil Sand 134.52 132.78 128.33 6.19 35.290714 -78.076225
MW-3 8/27/90 2 18 12 6 Soil Sand 134.81 133.03 134.08 0.73 35.293192 -78.072156
MW-4 8/28/90 2 15 10 5 Soil Sand 150.20 148.17 142.75 7.45 35.293003 -78.066253
MW-5 8/31/94 2 18 3 15 Soil Sand 124.78 120.56 122.39 2.39 35.292597 -78.075936
MW-6 8/31/94 2 18.14 3.14 15 Soil Sand 145.53 143.62 138.34 7.19 35.293439 -78.068656
MW-7 8/31/94 2 19 4 15 Soil Sand 143.59 140.74 134.10 9.49 35.288761 -78.074700
MW-8 8/30/94 2 29 14 15 Soil Sand 161.88 160.88 142.27 19.61 35.290178 -78.068706
MW-9 7/9/09 2 25 10 15 Soil Sand 162.96 159.78 143.18 19.78 35.290025 -78.068242
MW-10 7/9/09 2 25 10 15 Soil Sand 162.90 160.01 145.78 17.12 35.289869 -78.069167
MW-11 7/9/09 2 15 5 10 Soil Sand 127.23 124.50 124.39 2.84 35.291844 -78.076250
NOTE:
na = not available
bgs = below ground surface
amsl= above mean sea level
btoc = below top of PVC well casing
Monitoring
Well
Date
Installed
Geology of
Screened
Interval
Latitude Longitude
Wayne County Active CDLF and Closed MSWLF (Dudley)Page 1 of 1
Table 2
Field Observations of Monitoring Locations
October 5, 2017
Sample
Location
Viable
Monitoring
Location
Lack of Any
Evidence of
Tampering
Locked Hinge/Hasp
Operational
Tagged
or
Labeled
Concrete
Surface
Pad
Effective
Comments
MW-1R Yes Yes Yes Yes Yes Yes Upgradient background well
MW-2 Yes Yes Yes Yes Yes Yes reducing odor, ants
MW-3 Yes Yes No Yes Yes Yes Flowing artesian, needs a lock
MW-4 Yes Yes Yes Yes Yes Yes
MW-5 Yes Yes Yes Yes Yes Yes
MW-6 Yes Yes Yes Yes Yes Yes
MW-7 Yes Yes Yes Yes Yes Yes New erosion next to pad
MW-8 Yes Yes Yes Yes Yes Yes
MW-9 Yes Yes Yes Yes Yes Yes
MW-10 Yes Yes Yes Yes Yes Yes
MW-11 Yes Yes Yes Yes Yes Yes
SW-1 Yes -----Shared Downstream of SW-3
SW-2 No -----Dry Upstream nearest MW-7.
SW-3 No -----Dry-Shared Upstream nearest MW-4
SW-6 Yes -----Shared nearest MW-5
SW-By _MW-2 Yes -----Not required but supplemental sample
Any unusual field conditions, observations, or events:
SW-2 (Closed) upstream nearest MW-7 was dry which is typical.
SW-3 (Closed) upstream nearest MW-4 was dry which is typical
Wetlands west of landfill are flooded which is likely caused by beaver dam(s)
Observed lots of fish at SW-ByMW-2 which indicates consisitant water and sufficient quality for aquatic life.
Wayne County Active CDLF and Closed MSWLF Page 1 of 1
Table 3
Field Parameter Data Summary
October 5, 2017
Parameter
Depth to
Water
Water
Elevation
TOC
Elevation Temp.ORP DO pH
Specific
Conductance TDS Turbidity
Units ft (btoc)ft (amsl)ft (amsl) C mV mg/L SU umhos/cm mg/L NTU or Visual
MW-1R 21.75 147.88 169.63 18.9 168 5.3 4.9 17 33.7 9.81
MW-2 6.19 128.33 134.52 21.5 -27 0.7 6.5 1360 45.3 46.1
MW-3 0.73 134.08 134.81 20.3 247 2.2 4.5 46 1.62 1.73
MW-4 7.45 142.75 150.20 19.7 237 2.1 5.1 279 2.56 2.72
MW-5 2.39 122.39 124.78 20.6 186 2.2 4.9 71 7.54 7.79
MW-6 7.19 138.34 145.53 19.1 113 2.1 5.3 389 4.32 4.41
MW-7 9.49 134.10 143.59 21.1 281 2.2 4.6 73 1.33 1.43
MW-8 19.61 142.27 161.88 18.7 297 2.3 4.5 58 3.56 3.75
MW-9 19.78 143.18 162.96 NR NR NR NR NR NR NR
MW-10 17.12 145.78 162.90 NR NR NR NR NR NR NR
MW-11 2.84 124.39 127.23 20.9 129 4.3 5.4 1247 28.4 15.2
Minimum 0.73 122.39 124.78 18.7 -27 0.7 4.5 17 1.33 1.43
Average 10.41 136.68 147.09 20.1 181 2.6 5.1 393 14 10
Maximum 21.75 147.88 169.63 21.5 297 5.3 6.5 1360 45.3 46.1
SW-1 ---22.7 --6.5 291 NR Clear
SW-2 Dry ---------
SW-ByMW-2 ---22.3 --6.2 227 NR Clear
SW-3 Dry ---------
SW-6 ---25.3 --6.4 321 NR Slight
Minimum ---22.3 --6.2 227 NR Clear
Average ---23.4 --6.4 280 NR Slight
Maximum ---25.3 --6.5 321 NR Slight
NR = No reading attempted
Wayne County Active CDLF and Closed MSWLF (Dudley)Page 1 of 1
Table 4
Sampling and Analysis Summary
October 4-5, 2017
CDLF App. II
VOCsTotal MetalsTetrahydrofuranDissolved Oxygen (DO)Oxidation Reduction Potential (ORP)TemperatureConductivitypHVFAHydrogenMethane/Ethene/EthaneDissolved CO2AlkalinitySulfateSulfideChlorideBODCODTOCFerrous IronNitrateTurbidityTotal Suspended SolidsTotal MetalsLab EPA 8260B Lab EPA 6000/7000Lab EPA 8260BField MeterField MeterField MeterField MeterField MeterLab AM23GLab AM20GAXLab AM20GAXField Hach KitEPA 310.2EPA 300.0Lab SM18 4500-S DEPA 300.0SM 5210BSM 5220DSM 5310BLab EPA 8270DLab EPA 9014Lab EPA 180.1Lab SM 2540D Lab EPA 6000/7000MW-1 x x x x x x x x x x
MW-2 x x x x x x x x x
MW-3 x x x x x x x x x
MW-4 x x x x x x x x x
MW-5 x x x x x x x x x
MW-6 x x x x x x x x x
MW-7 x x x x x x x x x
MW-8 x x x x x x x x x
MW-11 x x x x x x x x x
SW-1 x x x x x x x x
SW-2
SW-ByMW-2 x x x x x
SW-3
SW-6 x x x x x x
EB x x x
FB x x x
TB x x
Dry so not sampled
App I & II = Appendix I & II List from current 40 CFR 258
App. I
Dry so not sampled
Field Parameter MNA
Wayne County Active CDLF and Closed MSWLF (Dudley)Page 1 of 1
Table 5
Groundwater Sample Detections
October 5, 2017
MW-1R MW-2 MW-3 MW-4 MW-5 MW-6 MW-7 MW-8 MW-11 EB FB TB
BG S S S S S S S S QC QC QC
10/5/17 10/5/17 10/5/17 10/5/17 10/5/17 10/5/17 10/5/17 10/5/17 10/5/17 10/5/17 10/5/17 10/5/17
Arsenic, total 5 10 10 10 22.2 (N)6.4 J --
Barium, total 2.5 100 700 2000 13.1 J 158 17.9 J 65.8 J 38.8 J 127 43.6 J 86.6 J 407 --
Beryllium, total 0.5 1 4 4 0.59 J 0.73 J --
Cadmium, total 0.5 1 2 5 0.83 J 1.3 1.7 1.6 3.5 (N)1.3 2.3 (N)--
Chromium, total 2.5 10 10 100 5.6 J --
Cobalt, total 2.5 10 1 NE 5.6 J (N)--
Copper, total 2.5 10 1000 1300 3.7 J --
Nickel, total 2.5 50 100 NE 2.5 J 7.7 J --
Selenium, total 5 10 20 50 8.6 J --
Thallium, total 0.02 5.5 0.28 2 0.043 J 0.074 J 0.05 J 0.09 J 0.041 J --
Vanadium, total 2.5 25 0.3 NE 6 J (N)4.9 J (N)4 J (N)7.2 J (N)--
Zinc, total 5 10 1000 NE 6 J 11.5 5.4 J 5.5 J 8.3 J --
1,2-Dichlorobenzene 0.3 5 20 NE 0.49 J
1,4-Dichlorobenzene 0.33 1 6 75 5.2 0.58 J
Benzene 0.25 1 1 5 1.8 (L)
Bromomethane 0.29 10 10 NE 0.62 J
Chlorobenzene 0.23 3 50 100 15.7 0.71 J
Chloroform 0.14 5 70 NE 0.25 J
Tetrahydrofuran 3.1 NE NE NE 7.5 ------
Turbidity 0.5 NE NE NE 9 48.6 0.65 1.2 6.9 4.5 0.68 3 14.4 ------
Units ug/L
Red Bold Above Established MCL/2L/GWP Std.
Above Established Federal MCL Drinking Water Std. No regulatory compliance significance.
(N) Preliminary source is believed to be Natural originating from erosion of natural deposits. Source not anthropogenic.
(L) Preliminary source is believed to be a realease of leachate &/or landfill gas. Source is anthropogenic.
A definitive source of the detections was not determined as part of this report.
-- = Not Tested, J = Detected >MDL<SWSL
BG = Background Well Sample, QC = Quality Control Sample, S = Sentinal Well Sample
CDLF Specific Parameter
Miscellenous Parameter
Appendix I VOCs
2L/GWP MCLParameter Name SWSL
Appendix I Metals
MDL
Wayne County Active CDLF and Closed MSWLF (Dudley)
Table 6
Surface Water Sample Detections
October 4-5, 2017
SW-1 SW-6
D D
10/5/17 10/4/17
Arsenic, total 5 10 10 10 5.5 J
Barium, total 2.5 100 200000 2000 11.8 J 73.8 J
Cadmium, total 0.5 1 2 5 0.82 J
Chromium, total 2.5 10 50 100 5.6 J
Copper, total 2.5 10 7 1300 2.5 J
Lead, total 2.5 10 25 15 3.8 J
Vanadium, total 2.5 25 NE NE 6.8 J 5.2 J
Zinc, total 5 10 50 NE 10.6 6.3 J
2-Butanone (MEK)1 100 160000 NE 1.8 J
Acetone 10 100 2000 NE 14.7 J
Toluene 0.3 1 11 1000 0.45 J
Units ug/L
Red Bold Above Established 2B Std.
Above Established Federal MCL Drinking Water Std
D = Downstream of the facility
Appendix I VOCs
Parameter Name 2B MCLSWSL
Appendix I Metals
MDL
Wayne County Active CDLF and Closed MSWLF (Dudley)
Table 7
MNA Parameter Data Summary
October 5, 2017
MW-1R MW-2 MW-8
10/05/17 10/05/17 10/05/17
VFA – Acetic Acid AM23G NS ug/L NS NS NS
VFA – Butyric Acid AM23G NS ug/L NS NS NS
VFA – Hexanoic Acid AM23G NS ug/L NS NS NS
VFA – i-Hexanoic Acid AM23G NS ug/L NS NS NS
VFA – i-Pentanoic Acid AM23G NS ug/L NS NS NS
VFA – Lactic Acid AM23G NS ug/L NS NS NS
VFA – Pentaonic Acid AM23G NS ug/L NS NS NS
VFA – Propionic Acid AM23G NS ug/L NS NS NS
VFA – Pyruvic Acid AM23G NS ug/L NS NS NS
Hydrogen AM20GAX NS nM NS NS NS
Methane AM20GAX NS ug/L NS NS NS
Ethene AM20GAX NS ug/L NS NS NS
Ethane AM20GAX NS ug/L NS NS NS
CO2-Dissolved Field Hach Kit NS mg/L NS NS NS
Alkalinity SM 2320B NS ug/L NS NS NS
Sulfate EPA 300.0 NS ug/L NS NS NS
Sulfide SM 4500-S2D NS ug/L NS NS NS
Chloride SM 4500-Cl-E NS ug/L NS NS NS
TOC SM 5310B NS ug/L NS NS NS
COD SM 5220D NS ug/L NS NS NS
BOD SM 5210B NS ug/L NS NS NS
Iron, ferrous SM 3500-Fe B NS ug/L NS NS NS
Nitrate EPA 353.2 NS ug/L NS NS NS
Temperature Field Instrument 0 Degrees C 18.9 21.5 18.7
ORP Field Instrument -900 mV 168 -27 297
DO Field Instrument 0 ug/L 5.3 0.7 2.3
pH Field Instrument 0.00 SU 4.9 6.5 4.5
Specific Conductance Field Instrument 0 uMhos 17 1360 58
Turbidity Field Instrument 1.00 NTU 9.81 46.1 3.75
Notes:
VFA = Volatile Fatty Acids
MDL* = Lowest Method Detection Limit for Lab Parameters or Lowest Field Measurement Possible
NS = Not Sampled as not required during this specific event.
Parameters Method MDL*Units
Wayne County Active CDLF and Closed MSWLF (Dudley)Page 1 of 1
Table 8
Hydrogeologic Properties at Monitoring Well Locations
October 5, 2017
Hydraulic
Conductivity
Effective
Porosity
Hydraulic
Gradient
Linear
Velocity
Depth to
Groundwater
Groundwater
Potentiometric
Elevation
(cm/sec)(%)(ft/ft)(ft/yr)(ft btoc)(ft amsl)
MW-1R na 20 0.011 na N71W 21.75 147.89
MW-2 3.00E-04 20 0.007 11 N68W 6.19 128.33
MW-3 6.40E-03 20 0.003 84 N54W 0.73 134.08
MW-4 9.90E-04 20 0.011 55 N50W 7.45 142.75
MW-5 3.10E-05 20 0.019 3 N46W 2.39 122.39
MW-6 1.60E-04 20 0.006 5 N31W 7.19 138.34
MW-7 7.30E-05 20 0.004 2 N89W 9.49 134.10
MW-8 3.40E-04 20 0.020 36 N10E 19.61 142.27
Minimum 3.10E-05 20 0.003 2 0.73 122.39
Average 1.18E-03 20 0.010 28 9.35 136.27
Maximum 6.40E-03 20 0.020 84 21.75 147.89
NOTE:Data for conductivities and effective porosity obtained from GAI Consultants' Water Sampling Report (January, 1995).
Hydrologic Gradient from groundwater elevations recorded on October 5, 2017
Linear Velocity (Q) is defined by modified Darcy's equation:
where
K = hydraulic conductivity
ne = effective porosity
dh = head difference
dl = horizontal distance
Monitoring
Well
Flow
Direction
dl
dh
n
KQ
e
×-=
Wayne County Active CDLF and Closed MSWLF (Dudley)Page 1 of 1
Appendix A
Laboratory Analysis Reports
Chains of Custody
#=CL#
October 25, 2017
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92358257
92358257
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
68 Shipwash Dr.
Garner, NC 27529
WAYNE CLOSED LF
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on October 06, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 39
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 39
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Lab ID Sample ID Matrix Date Collected Date Received
92358257001 MW-1R Water 10/05/17 13:20 10/06/17 09:51
92358257002 MW-2 Water 10/05/17 11:30 10/06/17 09:51
92358257003 MW-3 Water 10/05/17 11:00 10/06/17 09:51
92358257004 MW-4 Water 10/05/17 14:00 10/06/17 09:51
92358257005 MW-5 Water 10/05/17 16:50 10/06/17 09:51
92358257006 MW-6 Water 10/05/17 15:25 10/06/17 09:51
92358257007 MW-7 Water 10/05/17 17:40 10/06/17 09:51
92358257008 MW-8 Water 10/05/17 17:10 10/06/17 09:51
92358257009 MW-11 Water 10/05/17 16:20 10/06/17 09:51
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
Page 3 of 39
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92358257001 MW-1R EPA 6010 14 PASI-ADS
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CGAW
EPA 180.1 1 PASI-AKMM
SM 2540D 1 PASI-ASLB
92358257002 MW-2 EPA 6010 14 PASI-ADS
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CGAW
EPA 180.1 1 PASI-AKMM
92358257003 MW-3 EPA 6010 14 PASI-ASER
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CGAW
EPA 180.1 1 PASI-AKMM
92358257004 MW-4 EPA 6010 14 PASI-ASER
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CGAW
EPA 180.1 1 PASI-AKMM
92358257005 MW-5 EPA 6010 14 PASI-ASER
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CGAW
EPA 180.1 1 PASI-AKMM
92358257006 MW-6 EPA 6010 14 PASI-ASER
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CGAW
EPA 180.1 1 PASI-AKMM
92358257007 MW-7 EPA 6010 14 PASI-ASER
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CGAW
EPA 180.1 1 PASI-AKMM
92358257008 MW-8 EPA 6010 14 PASI-ASER
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CGAW
EPA 180.1 1 PASI-AKMM
92358257009 MW-11 EPA 6010 14 PASI-ASER
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CGAW
EPA 180.1 1 PASI-AKMM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Sample:MW-1R Lab ID:92358257001 Collected:10/05/17 13:20 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 10/14/17 19:25 7440-36-010/11/17 17:406.0 3.9 1
Arsenic ND ug/L 10/14/17 19:25 7440-38-210/11/17 17:4010.0 5.0 1
Barium 13.1J ug/L 10/14/17 19:25 7440-39-310/11/17 17:401002.5 1
Beryllium ND ug/L 10/14/17 19:25 7440-41-710/11/17 17:401.0 0.50 1
Cadmium 0.83J ug/L 10/14/17 19:25 7440-43-910/11/17 17:401.0 0.50 1
Chromium 5.6J ug/L 10/14/17 19:25 7440-47-310/11/17 17:4010.0 2.5 1
Cobalt ND ug/L 10/14/17 19:25 7440-48-410/11/17 17:4010.0 2.5 1
Copper 3.7J ug/L 10/14/17 19:25 7440-50-810/11/17 17:4010.0 2.5 1
Lead ND ug/L 10/14/17 19:25 7439-92-110/11/17 17:4010.0 2.5 1
Nickel ND ug/L 10/14/17 19:25 7440-02-010/11/17 17:4050.0 2.5 1
Selenium ND ug/L 10/14/17 19:25 7782-49-210/11/17 17:4010.0 5.0 1
Silver ND ug/L 10/14/17 19:25 7440-22-410/11/17 17:4010.0 2.5 1
Vanadium 6.0J ug/L 10/14/17 19:25 7440-62-210/11/17 17:4025.0 2.5 1
Zinc ND ug/L 10/14/17 19:25 7440-66-610/11/17 17:4010.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium 0.043J ug/L 10/24/17 13:57 7440-28-010/09/17 08:555.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/18/17 15:06 67-64-110010.0 1
Acrylonitrile ND ug/L 10/18/17 15:06 107-13-12001.9 1
Benzene ND ug/L 10/18/17 15:06 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/18/17 15:06 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/18/17 15:06 75-27-41.0 0.18 1
Bromoform ND ug/L 10/18/17 15:06 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/18/17 15:06 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/18/17 15:06 78-93-31000.96 1
Carbon disulfide ND ug/L 10/18/17 15:06 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/18/17 15:06 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/18/17 15:06 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/18/17 15:06 75-00-3 L110.0 0.54 1
Chloroform 0.25J ug/L 10/18/17 15:06 67-66-3 B,C95.0 0.14 1
Chloromethane ND ug/L 10/18/17 15:06 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/18/17 15:06 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/18/17 15:06 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/18/17 15:06 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/18/17 15:06 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/18/17 15:06 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 10/18/17 15:06 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/18/17 15:06 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/18/17 15:06 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/18/17 15:06 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/18/17 15:06 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/18/17 15:06 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/18/17 15:06 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/18/17 15:06 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Sample:MW-1R Lab ID:92358257001 Collected:10/05/17 13:20 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 10/18/17 15:06 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 10/18/17 15:06 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/18/17 15:06 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/18/17 15:06 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/18/17 15:06 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/18/17 15:06 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/18/17 15:06 108-10-11000.33 1
Styrene ND ug/L 10/18/17 15:06 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/18/17 15:06 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/18/17 15:06 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/18/17 15:06 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 10/18/17 15:06 109-99-910.0 3.1 1
Toluene ND ug/L 10/18/17 15:06 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/18/17 15:06 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/18/17 15:06 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/18/17 15:06 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/18/17 15:06 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/18/17 15:06 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/18/17 15:06 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/18/17 15:06 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/18/17 15:06 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)97 %10/18/17 15:06 460-00-470-130 1
1,2-Dichloroethane-d4 (S)83 %10/18/17 15:06 17060-07-070-130 1
Toluene-d8 (S)110 %10/18/17 15:06 2037-26-570-130 1
Analytical Method: EPA 180.1180.1 Turbidity
Turbidity 9.0 NTU 10/07/17 01:30 D61.0 0.50 1
Analytical Method: SM 2540D2540D Total Suspended Solids
Total Suspended Solids 44700 ug/L 10/09/17 12:44417041701
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Sample:MW-2 Lab ID:92358257002 Collected:10/05/17 11:30 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 10/14/17 19:28 7440-36-010/11/17 17:406.0 3.9 1
Arsenic 22.2 ug/L 10/14/17 19:28 7440-38-210/11/17 17:4010.0 5.0 1
Barium 158 ug/L 10/14/17 19:28 7440-39-310/11/17 17:401002.5 1
Beryllium ND ug/L 10/14/17 19:28 7440-41-710/11/17 17:401.0 0.50 1
Cadmium ND ug/L 10/14/17 19:28 7440-43-910/11/17 17:401.0 0.50 1
Chromium ND ug/L 10/14/17 19:28 7440-47-310/11/17 17:4010.0 2.5 1
Cobalt ND ug/L 10/14/17 19:28 7440-48-410/11/17 17:4010.0 2.5 1
Copper ND ug/L 10/14/17 19:28 7440-50-810/11/17 17:4010.0 2.5 1
Lead ND ug/L 10/14/17 19:28 7439-92-110/11/17 17:4010.0 2.5 1
Nickel ND ug/L 10/14/17 19:28 7440-02-010/11/17 17:4050.0 2.5 1
Selenium 8.6J ug/L 10/14/17 19:28 7782-49-210/11/17 17:4010.0 5.0 1
Silver ND ug/L 10/14/17 19:28 7440-22-410/11/17 17:4010.0 2.5 1
Vanadium 4.9J ug/L 10/14/17 19:28 7440-62-210/11/17 17:4025.0 2.5 1
Zinc ND ug/L 10/14/17 19:28 7440-66-610/11/17 17:4010.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium 0.074J ug/L 10/24/17 14:09 7440-28-010/09/17 08:555.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/18/17 15:23 67-64-110010.0 1
Acrylonitrile ND ug/L 10/18/17 15:23 107-13-12001.9 1
Benzene 1.8 ug/L 10/18/17 15:23 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/18/17 15:23 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/18/17 15:23 75-27-41.0 0.18 1
Bromoform ND ug/L 10/18/17 15:23 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/18/17 15:23 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/18/17 15:23 78-93-31000.96 1
Carbon disulfide ND ug/L 10/18/17 15:23 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/18/17 15:23 56-23-51.0 0.25 1
Chlorobenzene 15.7 ug/L 10/18/17 15:23 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/18/17 15:23 75-00-3 L110.0 0.54 1
Chloroform ND ug/L 10/18/17 15:23 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/18/17 15:23 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/18/17 15:23 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/18/17 15:23 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/18/17 15:23 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/18/17 15:23 74-95-310.0 0.21 1
1,2-Dichlorobenzene 0.49J ug/L 10/18/17 15:23 95-50-15.0 0.30 1
1,4-Dichlorobenzene 5.2 ug/L 10/18/17 15:23 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/18/17 15:23 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/18/17 15:23 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/18/17 15:23 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/18/17 15:23 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/18/17 15:23 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/18/17 15:23 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/18/17 15:23 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Sample:MW-2 Lab ID:92358257002 Collected:10/05/17 11:30 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 10/18/17 15:23 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 10/18/17 15:23 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/18/17 15:23 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/18/17 15:23 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/18/17 15:23 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/18/17 15:23 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/18/17 15:23 108-10-11000.33 1
Styrene ND ug/L 10/18/17 15:23 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/18/17 15:23 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/18/17 15:23 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/18/17 15:23 127-18-41.0 0.46 1
Tetrahydrofuran 7.5J ug/L 10/18/17 15:23 109-99-910.0 3.1 1
Toluene ND ug/L 10/18/17 15:23 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/18/17 15:23 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/18/17 15:23 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/18/17 15:23 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/18/17 15:23 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/18/17 15:23 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/18/17 15:23 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/18/17 15:23 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/18/17 15:23 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)102 %10/18/17 15:23 460-00-470-130 1
1,2-Dichloroethane-d4 (S)87 %10/18/17 15:23 17060-07-070-130 1
Toluene-d8 (S)111 %10/18/17 15:23 2037-26-570-130 1
Analytical Method: EPA 180.1180.1 Turbidity
Turbidity 48.6 NTU 10/07/17 01:301.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Sample:MW-3 Lab ID:92358257003 Collected:10/05/17 11:00 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 10/16/17 01:00 7440-36-010/13/17 20:306.0 3.9 1
Arsenic ND ug/L 10/16/17 01:00 7440-38-210/13/17 20:3010.0 5.0 1
Barium 17.9J ug/L 10/16/17 01:00 7440-39-310/13/17 20:301002.5 1
Beryllium ND ug/L 10/16/17 01:00 7440-41-710/13/17 20:301.0 0.50 1
Cadmium 1.3 ug/L 10/16/17 01:00 7440-43-910/13/17 20:301.0 0.50 1
Chromium ND ug/L 10/16/17 01:00 7440-47-310/13/17 20:3010.0 2.5 1
Cobalt ND ug/L 10/16/17 01:00 7440-48-410/13/17 20:3010.0 2.5 1
Copper ND ug/L 10/16/17 01:00 7440-50-810/13/17 20:3010.0 2.5 1
Lead ND ug/L 10/16/17 01:00 7439-92-110/13/17 20:3010.0 2.5 1
Nickel ND ug/L 10/16/17 01:00 7440-02-010/13/17 20:3050.0 2.5 1
Selenium ND ug/L 10/16/17 01:00 7782-49-210/13/17 20:3010.0 5.0 1
Silver ND ug/L 10/16/17 01:00 7440-22-410/13/17 20:3010.0 2.5 1
Vanadium 4.0J ug/L 10/16/17 01:00 7440-62-210/13/17 20:3025.0 2.5 1
Zinc 6.0J ug/L 10/16/17 01:00 7440-66-610/13/17 20:3010.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 10/24/17 14:11 7440-28-010/09/17 08:555.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/18/17 15:57 67-64-110010.0 1
Acrylonitrile ND ug/L 10/18/17 15:57 107-13-12001.9 1
Benzene ND ug/L 10/18/17 15:57 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/18/17 15:57 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/18/17 15:57 75-27-41.0 0.18 1
Bromoform ND ug/L 10/18/17 15:57 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/18/17 15:57 74-83-9 M110.0 0.29 1
2-Butanone (MEK)ND ug/L 10/18/17 15:57 78-93-31000.96 1
Carbon disulfide ND ug/L 10/18/17 15:57 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/18/17 15:57 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/18/17 15:57 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/18/17 15:57 75-00-3 L110.0 0.54 1
Chloroform ND ug/L 10/18/17 15:57 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/18/17 15:57 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/18/17 15:57 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/18/17 15:57 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/18/17 15:57 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/18/17 15:57 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/18/17 15:57 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 10/18/17 15:57 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/18/17 15:57 110-57-6 M11001.0 1
1,1-Dichloroethane ND ug/L 10/18/17 15:57 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/18/17 15:57 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/18/17 15:57 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/18/17 15:57 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/18/17 15:57 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/18/17 15:57 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Sample:MW-3 Lab ID:92358257003 Collected:10/05/17 11:00 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 10/18/17 15:57 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 10/18/17 15:57 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/18/17 15:57 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/18/17 15:57 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/18/17 15:57 74-88-4 M110.0 0.32 1
Methylene Chloride ND ug/L 10/18/17 15:57 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/18/17 15:57 108-10-11000.33 1
Styrene ND ug/L 10/18/17 15:57 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/18/17 15:57 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/18/17 15:57 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/18/17 15:57 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 10/18/17 15:57 109-99-910.0 3.1 1
Toluene ND ug/L 10/18/17 15:57 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/18/17 15:57 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/18/17 15:57 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/18/17 15:57 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/18/17 15:57 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/18/17 15:57 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/18/17 15:57 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/18/17 15:57 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/18/17 15:57 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)111 %10/18/17 15:57 460-00-470-130 1
1,2-Dichloroethane-d4 (S)87 %10/18/17 15:57 17060-07-070-130 1
Toluene-d8 (S)113 %10/18/17 15:57 2037-26-570-130 1
Analytical Method: EPA 180.1180.1 Turbidity
Turbidity 0.65J NTU 10/07/17 01:301.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Sample:MW-4 Lab ID:92358257004 Collected:10/05/17 14:00 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 10/16/17 01:09 7440-36-010/13/17 20:306.0 3.9 1
Arsenic ND ug/L 10/16/17 01:09 7440-38-210/13/17 20:3010.0 5.0 1
Barium 65.8J ug/L 10/16/17 01:09 7440-39-310/13/17 20:301002.5 1
Beryllium ND ug/L 10/16/17 01:09 7440-41-710/13/17 20:301.0 0.50 1
Cadmium 1.7 ug/L 10/16/17 01:09 7440-43-910/13/17 20:301.0 0.50 1
Chromium ND ug/L 10/16/17 01:09 7440-47-310/13/17 20:3010.0 2.5 1
Cobalt ND ug/L 10/16/17 01:09 7440-48-410/13/17 20:3010.0 2.5 1
Copper ND ug/L 10/16/17 01:09 7440-50-810/13/17 20:3010.0 2.5 1
Lead ND ug/L 10/16/17 01:09 7439-92-110/13/17 20:3010.0 2.5 1
Nickel ND ug/L 10/16/17 01:09 7440-02-010/13/17 20:3050.0 2.5 1
Selenium ND ug/L 10/16/17 01:09 7782-49-210/13/17 20:3010.0 5.0 1
Silver ND ug/L 10/16/17 01:09 7440-22-410/13/17 20:3010.0 2.5 1
Vanadium ND ug/L 10/16/17 01:09 7440-62-210/13/17 20:3025.0 2.5 1
Zinc ND ug/L 10/16/17 01:09 7440-66-610/13/17 20:3010.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium 0.050J ug/L 10/24/17 14:13 7440-28-010/09/17 08:555.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/18/17 16:14 67-64-110010.0 1
Acrylonitrile ND ug/L 10/18/17 16:14 107-13-12001.9 1
Benzene ND ug/L 10/18/17 16:14 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/18/17 16:14 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/18/17 16:14 75-27-41.0 0.18 1
Bromoform ND ug/L 10/18/17 16:14 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/18/17 16:14 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/18/17 16:14 78-93-31000.96 1
Carbon disulfide ND ug/L 10/18/17 16:14 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/18/17 16:14 56-23-51.0 0.25 1
Chlorobenzene 0.71J ug/L 10/18/17 16:14 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/18/17 16:14 75-00-3 L110.0 0.54 1
Chloroform ND ug/L 10/18/17 16:14 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/18/17 16:14 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/18/17 16:14 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/18/17 16:14 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/18/17 16:14 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/18/17 16:14 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/18/17 16:14 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 10/18/17 16:14 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/18/17 16:14 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/18/17 16:14 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/18/17 16:14 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/18/17 16:14 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/18/17 16:14 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/18/17 16:14 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/18/17 16:14 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Sample:MW-4 Lab ID:92358257004 Collected:10/05/17 14:00 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 10/18/17 16:14 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 10/18/17 16:14 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/18/17 16:14 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/18/17 16:14 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/18/17 16:14 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/18/17 16:14 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/18/17 16:14 108-10-11000.33 1
Styrene ND ug/L 10/18/17 16:14 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/18/17 16:14 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/18/17 16:14 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/18/17 16:14 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 10/18/17 16:14 109-99-910.0 3.1 1
Toluene ND ug/L 10/18/17 16:14 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/18/17 16:14 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/18/17 16:14 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/18/17 16:14 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/18/17 16:14 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/18/17 16:14 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/18/17 16:14 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/18/17 16:14 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/18/17 16:14 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)106 %10/18/17 16:14 460-00-470-130 1
1,2-Dichloroethane-d4 (S)81 %10/18/17 16:14 17060-07-070-130 1
Toluene-d8 (S)110 %10/18/17 16:14 2037-26-570-130 1
Analytical Method: EPA 180.1180.1 Turbidity
Turbidity 1.2 NTU 10/07/17 01:301.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Sample:MW-5 Lab ID:92358257005 Collected:10/05/17 16:50 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 10/16/17 01:12 7440-36-010/13/17 20:306.0 3.9 1
Arsenic ND ug/L 10/16/17 01:12 7440-38-210/13/17 20:3010.0 5.0 1
Barium 38.8J ug/L 10/16/17 01:12 7440-39-310/13/17 20:301002.5 1
Beryllium 0.59J ug/L 10/16/17 01:12 7440-41-710/13/17 20:301.0 0.50 1
Cadmium 1.6 ug/L 10/16/17 01:12 7440-43-910/13/17 20:301.0 0.50 1
Chromium ND ug/L 10/16/17 01:12 7440-47-310/13/17 20:3010.0 2.5 1
Cobalt ND ug/L 10/16/17 01:12 7440-48-410/13/17 20:3010.0 2.5 1
Copper ND ug/L 10/16/17 01:12 7440-50-810/13/17 20:3010.0 2.5 1
Lead ND ug/L 10/16/17 01:12 7439-92-110/13/17 20:3010.0 2.5 1
Nickel ND ug/L 10/16/17 01:12 7440-02-010/13/17 20:3050.0 2.5 1
Selenium ND ug/L 10/16/17 01:12 7782-49-210/13/17 20:3010.0 5.0 1
Silver ND ug/L 10/16/17 01:12 7440-22-410/13/17 20:3010.0 2.5 1
Vanadium ND ug/L 10/16/17 01:12 7440-62-210/13/17 20:3025.0 2.5 1
Zinc 11.5 ug/L 10/16/17 01:12 7440-66-610/13/17 20:3010.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 10/24/17 14:14 7440-28-010/09/17 08:555.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/18/17 16:31 67-64-110010.0 1
Acrylonitrile ND ug/L 10/18/17 16:31 107-13-12001.9 1
Benzene ND ug/L 10/18/17 16:31 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/18/17 16:31 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/18/17 16:31 75-27-41.0 0.18 1
Bromoform ND ug/L 10/18/17 16:31 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/18/17 16:31 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/18/17 16:31 78-93-31000.96 1
Carbon disulfide ND ug/L 10/18/17 16:31 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/18/17 16:31 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/18/17 16:31 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/18/17 16:31 75-00-3 L110.0 0.54 1
Chloroform ND ug/L 10/18/17 16:31 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/18/17 16:31 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/18/17 16:31 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/18/17 16:31 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/18/17 16:31 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/18/17 16:31 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/18/17 16:31 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 10/18/17 16:31 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/18/17 16:31 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/18/17 16:31 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/18/17 16:31 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/18/17 16:31 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/18/17 16:31 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/18/17 16:31 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/18/17 16:31 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Sample:MW-5 Lab ID:92358257005 Collected:10/05/17 16:50 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 10/18/17 16:31 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 10/18/17 16:31 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/18/17 16:31 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/18/17 16:31 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/18/17 16:31 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/18/17 16:31 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/18/17 16:31 108-10-11000.33 1
Styrene ND ug/L 10/18/17 16:31 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/18/17 16:31 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/18/17 16:31 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/18/17 16:31 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 10/18/17 16:31 109-99-910.0 3.1 1
Toluene ND ug/L 10/18/17 16:31 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/18/17 16:31 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/18/17 16:31 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/18/17 16:31 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/18/17 16:31 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/18/17 16:31 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/18/17 16:31 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/18/17 16:31 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/18/17 16:31 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)101 %10/18/17 16:31 460-00-470-130 1
1,2-Dichloroethane-d4 (S)79 %10/18/17 16:31 17060-07-070-130 1
Toluene-d8 (S)118 %10/18/17 16:31 2037-26-570-130 1
Analytical Method: EPA 180.1180.1 Turbidity
Turbidity 6.9 NTU 10/07/17 01:301.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Sample:MW-6 Lab ID:92358257006 Collected:10/05/17 15:25 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 10/16/17 01:15 7440-36-010/13/17 20:306.0 3.9 1
Arsenic ND ug/L 10/16/17 01:15 7440-38-210/13/17 20:3010.0 5.0 1
Barium 127 ug/L 10/16/17 01:15 7440-39-310/13/17 20:301002.5 1
Beryllium 0.73J ug/L 10/16/17 01:15 7440-41-710/13/17 20:301.0 0.50 1
Cadmium ND ug/L 10/16/17 01:15 7440-43-910/13/17 20:301.0 0.50 1
Chromium ND ug/L 10/16/17 01:15 7440-47-310/13/17 20:3010.0 2.5 1
Cobalt ND ug/L 10/16/17 01:15 7440-48-410/13/17 20:3010.0 2.5 1
Copper ND ug/L 10/16/17 01:15 7440-50-810/13/17 20:3010.0 2.5 1
Lead ND ug/L 10/16/17 01:15 7439-92-110/13/17 20:3010.0 2.5 1
Nickel 2.5J ug/L 10/16/17 01:15 7440-02-010/13/17 20:3050.0 2.5 1
Selenium ND ug/L 10/16/17 01:15 7782-49-210/13/17 20:3010.0 5.0 1
Silver ND ug/L 10/16/17 01:15 7440-22-410/13/17 20:3010.0 2.5 1
Vanadium ND ug/L 10/16/17 01:15 7440-62-210/13/17 20:3025.0 2.5 1
Zinc ND ug/L 10/16/17 01:15 7440-66-610/13/17 20:3010.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium 0.090J ug/L 10/24/17 14:16 7440-28-010/09/17 08:555.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/18/17 16:48 67-64-110010.0 1
Acrylonitrile ND ug/L 10/18/17 16:48 107-13-12001.9 1
Benzene ND ug/L 10/18/17 16:48 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/18/17 16:48 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/18/17 16:48 75-27-41.0 0.18 1
Bromoform ND ug/L 10/18/17 16:48 75-25-23.0 0.26 1
Bromomethane 0.62J ug/L 10/18/17 16:48 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/18/17 16:48 78-93-31000.96 1
Carbon disulfide ND ug/L 10/18/17 16:48 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/18/17 16:48 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/18/17 16:48 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/18/17 16:48 75-00-3 L110.0 0.54 1
Chloroform ND ug/L 10/18/17 16:48 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/18/17 16:48 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/18/17 16:48 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/18/17 16:48 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/18/17 16:48 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/18/17 16:48 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/18/17 16:48 95-50-15.0 0.30 1
1,4-Dichlorobenzene 0.58J ug/L 10/18/17 16:48 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/18/17 16:48 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/18/17 16:48 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/18/17 16:48 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/18/17 16:48 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/18/17 16:48 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/18/17 16:48 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/18/17 16:48 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Sample:MW-6 Lab ID:92358257006 Collected:10/05/17 15:25 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 10/18/17 16:48 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 10/18/17 16:48 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/18/17 16:48 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/18/17 16:48 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/18/17 16:48 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/18/17 16:48 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/18/17 16:48 108-10-11000.33 1
Styrene ND ug/L 10/18/17 16:48 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/18/17 16:48 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/18/17 16:48 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/18/17 16:48 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 10/18/17 16:48 109-99-910.0 3.1 1
Toluene ND ug/L 10/18/17 16:48 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/18/17 16:48 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/18/17 16:48 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/18/17 16:48 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/18/17 16:48 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/18/17 16:48 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/18/17 16:48 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/18/17 16:48 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/18/17 16:48 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %10/18/17 16:48 460-00-470-130 1
1,2-Dichloroethane-d4 (S)79 %10/18/17 16:48 17060-07-070-130 1
Toluene-d8 (S)117 %10/18/17 16:48 2037-26-570-130 1
Analytical Method: EPA 180.1180.1 Turbidity
Turbidity 4.5 NTU 10/07/17 01:301.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Sample:MW-7 Lab ID:92358257007 Collected:10/05/17 17:40 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 10/16/17 01:31 7440-36-010/13/17 20:306.0 3.9 1
Arsenic ND ug/L 10/16/17 01:31 7440-38-210/13/17 20:3010.0 5.0 1
Barium 43.6J ug/L 10/16/17 01:31 7440-39-310/13/17 20:301002.5 1
Beryllium ND ug/L 10/16/17 01:31 7440-41-710/13/17 20:301.0 0.50 1
Cadmium 3.5 ug/L 10/16/17 01:31 7440-43-910/13/17 20:301.0 0.50 1
Chromium ND ug/L 10/16/17 01:31 7440-47-310/13/17 20:3010.0 2.5 1
Cobalt ND ug/L 10/16/17 01:31 7440-48-410/13/17 20:3010.0 2.5 1
Copper ND ug/L 10/16/17 01:31 7440-50-810/13/17 20:3010.0 2.5 1
Lead ND ug/L 10/16/17 01:31 7439-92-110/13/17 20:3010.0 2.5 1
Nickel ND ug/L 10/16/17 01:31 7440-02-010/13/17 20:3050.0 2.5 1
Selenium ND ug/L 10/16/17 01:31 7782-49-210/13/17 20:3010.0 5.0 1
Silver ND ug/L 10/16/17 01:31 7440-22-410/13/17 20:3010.0 2.5 1
Vanadium ND ug/L 10/16/17 01:31 7440-62-210/13/17 20:3025.0 2.5 1
Zinc 5.4J ug/L 10/16/17 01:31 7440-66-610/13/17 20:3010.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium 0.041J ug/L 10/24/17 14:18 7440-28-010/09/17 08:555.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/18/17 17:05 67-64-110010.0 1
Acrylonitrile ND ug/L 10/18/17 17:05 107-13-12001.9 1
Benzene ND ug/L 10/18/17 17:05 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/18/17 17:05 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/18/17 17:05 75-27-41.0 0.18 1
Bromoform ND ug/L 10/18/17 17:05 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/18/17 17:05 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/18/17 17:05 78-93-31000.96 1
Carbon disulfide ND ug/L 10/18/17 17:05 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/18/17 17:05 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/18/17 17:05 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/18/17 17:05 75-00-3 L110.0 0.54 1
Chloroform ND ug/L 10/18/17 17:05 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/18/17 17:05 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/18/17 17:05 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/18/17 17:05 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/18/17 17:05 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/18/17 17:05 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/18/17 17:05 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 10/18/17 17:05 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/18/17 17:05 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/18/17 17:05 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/18/17 17:05 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/18/17 17:05 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/18/17 17:05 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/18/17 17:05 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/18/17 17:05 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Sample:MW-7 Lab ID:92358257007 Collected:10/05/17 17:40 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 10/18/17 17:05 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 10/18/17 17:05 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/18/17 17:05 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/18/17 17:05 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/18/17 17:05 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/18/17 17:05 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/18/17 17:05 108-10-11000.33 1
Styrene ND ug/L 10/18/17 17:05 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/18/17 17:05 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/18/17 17:05 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/18/17 17:05 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 10/18/17 17:05 109-99-910.0 3.1 1
Toluene ND ug/L 10/18/17 17:05 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/18/17 17:05 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/18/17 17:05 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/18/17 17:05 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/18/17 17:05 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/18/17 17:05 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/18/17 17:05 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/18/17 17:05 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/18/17 17:05 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %10/18/17 17:05 460-00-470-130 1
1,2-Dichloroethane-d4 (S)79 %10/18/17 17:05 17060-07-070-130 1
Toluene-d8 (S)115 %10/18/17 17:05 2037-26-570-130 1
Analytical Method: EPA 180.1180.1 Turbidity
Turbidity 0.68J NTU 10/07/17 01:301.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Sample:MW-8 Lab ID:92358257008 Collected:10/05/17 17:10 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 10/16/17 01:34 7440-36-010/13/17 20:306.0 3.9 1
Arsenic ND ug/L 10/16/17 01:34 7440-38-210/13/17 20:3010.0 5.0 1
Barium 86.6J ug/L 10/16/17 01:34 7440-39-310/13/17 20:301002.5 1
Beryllium ND ug/L 10/16/17 01:34 7440-41-710/13/17 20:301.0 0.50 1
Cadmium 1.3 ug/L 10/16/17 01:34 7440-43-910/13/17 20:301.0 0.50 1
Chromium ND ug/L 10/16/17 01:34 7440-47-310/13/17 20:3010.0 2.5 1
Cobalt ND ug/L 10/16/17 01:34 7440-48-410/13/17 20:3010.0 2.5 1
Copper ND ug/L 10/16/17 01:34 7440-50-810/13/17 20:3010.0 2.5 1
Lead ND ug/L 10/16/17 01:34 7439-92-110/13/17 20:3010.0 2.5 1
Nickel ND ug/L 10/16/17 01:34 7440-02-010/13/17 20:3050.0 2.5 1
Selenium ND ug/L 10/16/17 01:34 7782-49-210/13/17 20:3010.0 5.0 1
Silver ND ug/L 10/16/17 01:34 7440-22-410/13/17 20:3010.0 2.5 1
Vanadium ND ug/L 10/16/17 01:34 7440-62-210/13/17 20:3025.0 2.5 1
Zinc 5.5J ug/L 10/16/17 01:34 7440-66-610/13/17 20:3010.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 10/24/17 14:20 7440-28-010/09/17 08:555.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/18/17 17:22 67-64-110010.0 1
Acrylonitrile ND ug/L 10/18/17 17:22 107-13-12001.9 1
Benzene ND ug/L 10/18/17 17:22 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/18/17 17:22 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/18/17 17:22 75-27-41.0 0.18 1
Bromoform ND ug/L 10/18/17 17:22 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/18/17 17:22 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/18/17 17:22 78-93-31000.96 1
Carbon disulfide ND ug/L 10/18/17 17:22 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/18/17 17:22 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/18/17 17:22 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/18/17 17:22 75-00-3 L110.0 0.54 1
Chloroform ND ug/L 10/18/17 17:22 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/18/17 17:22 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/18/17 17:22 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/18/17 17:22 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/18/17 17:22 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/18/17 17:22 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/18/17 17:22 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 10/18/17 17:22 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/18/17 17:22 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/18/17 17:22 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/18/17 17:22 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/18/17 17:22 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/18/17 17:22 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/18/17 17:22 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/18/17 17:22 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Sample:MW-8 Lab ID:92358257008 Collected:10/05/17 17:10 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 10/18/17 17:22 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 10/18/17 17:22 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/18/17 17:22 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/18/17 17:22 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/18/17 17:22 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/18/17 17:22 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/18/17 17:22 108-10-11000.33 1
Styrene ND ug/L 10/18/17 17:22 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/18/17 17:22 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/18/17 17:22 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/18/17 17:22 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 10/18/17 17:22 109-99-910.0 3.1 1
Toluene ND ug/L 10/18/17 17:22 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/18/17 17:22 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/18/17 17:22 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/18/17 17:22 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/18/17 17:22 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/18/17 17:22 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/18/17 17:22 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/18/17 17:22 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/18/17 17:22 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)97 %10/18/17 17:22 460-00-470-130 1
1,2-Dichloroethane-d4 (S)87 %10/18/17 17:22 17060-07-070-130 1
Toluene-d8 (S)116 %10/18/17 17:22 2037-26-570-130 1
Analytical Method: EPA 180.1180.1 Turbidity
Turbidity 3.0 NTU 10/07/17 01:301.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Sample:MW-11 Lab ID:92358257009 Collected:10/05/17 16:20 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 10/16/17 01:37 7440-36-010/13/17 20:306.0 3.9 1
Arsenic 6.4J ug/L 10/16/17 01:37 7440-38-210/13/17 20:3010.0 5.0 1
Barium 407 ug/L 10/16/17 01:37 7440-39-310/13/17 20:301002.5 1
Beryllium ND ug/L 10/16/17 01:37 7440-41-710/13/17 20:301.0 0.50 1
Cadmium 2.3 ug/L 10/16/17 01:37 7440-43-910/13/17 20:301.0 0.50 1
Chromium ND ug/L 10/16/17 01:37 7440-47-310/13/17 20:3010.0 2.5 1
Cobalt 5.6J ug/L 10/16/17 01:37 7440-48-410/13/17 20:3010.0 2.5 1
Copper ND ug/L 10/16/17 01:37 7440-50-810/13/17 20:3010.0 2.5 1
Lead ND ug/L 10/16/17 01:37 7439-92-110/13/17 20:3010.0 2.5 1
Nickel 7.7J ug/L 10/16/17 01:37 7440-02-010/13/17 20:3050.0 2.5 1
Selenium ND ug/L 10/16/17 01:37 7782-49-210/13/17 20:3010.0 5.0 1
Silver ND ug/L 10/16/17 01:37 7440-22-410/13/17 20:3010.0 2.5 1
Vanadium 7.2J ug/L 10/16/17 01:37 7440-62-210/13/17 20:3025.0 2.5 1
Zinc 8.3J ug/L 10/16/17 01:37 7440-66-610/13/17 20:3010.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 10/24/17 14:22 7440-28-010/09/17 08:555.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/18/17 17:39 67-64-110010.0 1
Acrylonitrile ND ug/L 10/18/17 17:39 107-13-12001.9 1
Benzene ND ug/L 10/18/17 17:39 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/18/17 17:39 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/18/17 17:39 75-27-41.0 0.18 1
Bromoform ND ug/L 10/18/17 17:39 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/18/17 17:39 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/18/17 17:39 78-93-31000.96 1
Carbon disulfide ND ug/L 10/18/17 17:39 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/18/17 17:39 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/18/17 17:39 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/18/17 17:39 75-00-3 L110.0 0.54 1
Chloroform ND ug/L 10/18/17 17:39 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/18/17 17:39 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/18/17 17:39 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/18/17 17:39 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/18/17 17:39 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/18/17 17:39 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/18/17 17:39 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 10/18/17 17:39 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/18/17 17:39 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/18/17 17:39 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/18/17 17:39 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/18/17 17:39 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/18/17 17:39 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/18/17 17:39 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/18/17 17:39 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Sample:MW-11 Lab ID:92358257009 Collected:10/05/17 16:20 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 10/18/17 17:39 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 10/18/17 17:39 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/18/17 17:39 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/18/17 17:39 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/18/17 17:39 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/18/17 17:39 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/18/17 17:39 108-10-11000.33 1
Styrene ND ug/L 10/18/17 17:39 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/18/17 17:39 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/18/17 17:39 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/18/17 17:39 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 10/18/17 17:39 109-99-910.0 3.1 1
Toluene ND ug/L 10/18/17 17:39 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/18/17 17:39 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/18/17 17:39 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/18/17 17:39 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/18/17 17:39 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/18/17 17:39 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/18/17 17:39 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/18/17 17:39 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/18/17 17:39 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %10/18/17 17:39 460-00-470-130 1
1,2-Dichloroethane-d4 (S)84 %10/18/17 17:39 17060-07-070-130 1
Toluene-d8 (S)110 %10/18/17 17:39 2037-26-570-130 1
Analytical Method: EPA 180.1180.1 Turbidity
Turbidity 14.4 NTU 10/07/17 01:301.0 0.50 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
381897
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples:92358257001, 92358257002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2116269
Associated Lab Samples:92358257001, 92358257002
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 5.0 10/14/17 18:253.9
Arsenic ug/L ND 10.0 10/14/17 18:255.0
Barium ug/L ND 5.0 10/14/17 18:252.5
Beryllium ug/L ND 1.0 10/14/17 18:250.50
Cadmium ug/L ND 1.0 10/14/17 18:250.50
Chromium ug/L ND 5.0 10/14/17 18:252.5
Cobalt ug/L ND 5.0 10/14/17 18:252.5
Copper ug/L ND 5.0 10/14/17 18:252.5
Lead ug/L ND 5.0 10/14/17 18:252.5
Nickel ug/L ND 5.0 10/14/17 18:252.5
Selenium ug/L ND 10.0 10/14/17 18:255.0
Silver ug/L ND 5.0 10/14/17 18:252.5
Vanadium ug/L ND 5.0 10/14/17 18:252.5
Zinc ug/L ND 10.0 10/14/17 18:255.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2116270LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 531500 106 80-120
Arsenic ug/L 521500 104 80-120
Barium ug/L 526500 105 80-120
Beryllium ug/L 519500 104 80-120
Cadmium ug/L 528500 106 80-120
Chromium ug/L 525500 105 80-120
Cobalt ug/L 539500 108 80-120
Copper ug/L 547500 109 80-120
Lead ug/L 532500 106 80-120
Nickel ug/L 523500 105 80-120
Selenium ug/L 540500 108 80-120
Silver ug/L 267250 107 80-120
Vanadium ug/L 520500 104 80-120
Zinc ug/L 530500 106 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2116271MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92358008010
2116272
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 108 75-125104 3 20500ND538521
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2116271MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92358008010
2116272
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic ug/L 500 104 75-125102 2 20500ND524512
Barium ug/L 500 106 75-125103 3 20500ND531514
Beryllium ug/L 500 105 75-125102 3 20500ND525511
Cadmium ug/L 500 106 75-125103 3 20500ND532515
Chromium ug/L 500 104 75-125102 3 20500ND522508
Cobalt ug/L 500 107 75-125104 3 20500ND537520
Copper ug/L 500 110 75-125107 3 20500ND549534
Lead ug/L 500 105 75-125103 3 20500ND527513
Nickel ug/L 500 104 75-125101 3 20500ND521504
Selenium ug/L 500 108 75-125105 3 20500ND542526
Silver ug/L 250 107 75-125104 3 20250ND267259
Vanadium ug/L 500 105 75-125102 3 20500ND525510
Zinc ug/L 500 106 75-125103 3 20500ND535518
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
382384
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples:92358257003, 92358257004, 92358257005, 92358257006, 92358257007, 92358257008, 92358257009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2119150
Associated Lab Samples:92358257003, 92358257004, 92358257005, 92358257006, 92358257007, 92358257008, 92358257009
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 5.0 10/16/17 00:543.9
Arsenic ug/L ND 10.0 10/16/17 00:545.0
Barium ug/L ND 5.0 10/16/17 00:542.5
Beryllium ug/L ND 1.0 10/16/17 00:540.50
Cadmium ug/L ND 1.0 10/16/17 00:540.50
Chromium ug/L ND 5.0 10/16/17 00:542.5
Cobalt ug/L ND 5.0 10/16/17 00:542.5
Copper ug/L ND 5.0 10/16/17 00:542.5
Lead ug/L ND 5.0 10/16/17 00:542.5
Nickel ug/L ND 5.0 10/16/17 00:542.5
Selenium ug/L ND 10.0 10/16/17 00:545.0
Silver ug/L ND 5.0 10/16/17 00:542.5
Vanadium ug/L ND 5.0 10/16/17 00:542.5
Zinc ug/L ND 10.0 10/16/17 00:545.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2119151LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 469500 94 80-120
Arsenic ug/L 461500 92 80-120
Barium ug/L 483500 97 80-120
Beryllium ug/L 487500 97 80-120
Cadmium ug/L 477500 95 80-120
Chromium ug/L 481500 96 80-120
Cobalt ug/L 481500 96 80-120
Copper ug/L 476500 95 80-120
Lead ug/L 474500 95 80-120
Nickel ug/L 471500 94 80-120
Selenium ug/L 477500 95 80-120
Silver ug/L 238250 95 80-120
Vanadium ug/L 476500 95 80-120
Zinc ug/L 484500 97 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2119152MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92358257003
2119153
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 95 75-12595 0 20500ND479477
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2119152MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92358257003
2119153
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic ug/L 500 92 75-12592 0 20500ND460460
Barium ug/L 500 95 75-12597 1 2050017.9J 495 501
Beryllium ug/L 500 97 75-12598 1 20500ND483490
Cadmium ug/L 500 96 75-12597 1 205001.3 482 485
Chromium ug/L 500 94 75-12596 2 20500ND472482
Cobalt ug/L 500 96 75-12596 0 20500ND478480
Copper ug/L 500 98 75-12599 0 20500ND491493
Lead ug/L 500 94 75-12595 0 20500ND472473
Nickel ug/L 500 93 75-12594 1 20500ND467471
Selenium ug/L 500 96 75-12597 1 20500ND483488
Silver ug/L 250 96 75-12597 1 20250ND241242
Vanadium ug/L 500 95 75-12595 0 205004.0J 477 478
Zinc ug/L 500 95 75-12595 1 205006.0J 479 483
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
381406
EPA 3010A
EPA 6020B
6020 MET
Associated Lab Samples:92358257001, 92358257002, 92358257003, 92358257004, 92358257005, 92358257006, 92358257007,
92358257008, 92358257009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2113684
Associated Lab Samples:92358257001, 92358257002, 92358257003, 92358257004, 92358257005, 92358257006, 92358257007,
92358257008, 92358257009
Matrix:Water
AnalyzedMDL
Thallium ug/L ND 0.10 10/24/17 13:530.020
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2113685LABORATORY CONTROL SAMPLE:
LCSSpike
Thallium ug/L 102100 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2113686MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92358257001
2113687
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Thallium ug/L 100 103 75-125101 2 201000.043J 103 101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
382904
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92358257001, 92358257002, 92358257003, 92358257004, 92358257005, 92358257006, 92358257007,
92358257008, 92358257009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2121854
Associated Lab Samples:92358257001, 92358257002, 92358257003, 92358257004, 92358257005, 92358257006, 92358257007,
92358257008, 92358257009
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 10/18/17 10:160.33
1,1,1-Trichloroethane ug/L ND 1.0 10/18/17 10:160.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 10/18/17 10:160.40
1,1,2-Trichloroethane ug/L ND 1.0 10/18/17 10:160.29
1,1-Dichloroethane ug/L ND 5.0 10/18/17 10:160.32
1,1-Dichloroethene ug/L ND 5.0 10/18/17 10:160.56
1,2,3-Trichloropropane ug/L ND 1.0 10/18/17 10:160.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 10/18/17 10:162.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 10/18/17 10:160.27
1,2-Dichlorobenzene ug/L ND 5.0 10/18/17 10:160.30
1,2-Dichloroethane ug/L ND 1.0 10/18/17 10:160.24
1,2-Dichloropropane ug/L ND 1.0 10/18/17 10:160.27
1,4-Dichlorobenzene ug/L ND 1.0 10/18/17 10:160.33
2-Butanone (MEK)ug/L ND 100 10/18/17 10:160.96
2-Hexanone ug/L ND 50.0 10/18/17 10:160.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 10/18/17 10:160.33
Acetone ug/L ND 100 10/18/17 10:1610.0
Acrylonitrile ug/L ND 200 10/18/17 10:161.9
Benzene ug/L ND 1.0 10/18/17 10:160.25
Bromochloromethane ug/L ND 3.0 10/18/17 10:160.17
Bromodichloromethane ug/L ND 1.0 10/18/17 10:160.18
Bromoform ug/L ND 3.0 10/18/17 10:160.26
Bromomethane ug/L ND 10.0 10/18/17 10:160.29
Carbon disulfide ug/L ND 100 10/18/17 10:161.2
Carbon tetrachloride ug/L ND 1.0 10/18/17 10:160.25
Chlorobenzene ug/L ND 3.0 10/18/17 10:160.23
Chloroethane ug/L ND 10.0 10/18/17 10:160.54
Chloroform ug/L 0.39J 5.0 10/18/17 10:160.14
Chloromethane ug/L ND 1.0 10/18/17 10:160.11
cis-1,2-Dichloroethene ug/L ND 5.0 10/18/17 10:160.19
cis-1,3-Dichloropropene ug/L ND 1.0 10/18/17 10:160.13
Dibromochloromethane ug/L ND 3.0 10/18/17 10:160.21
Dibromomethane ug/L ND 10.0 10/18/17 10:160.21
Ethylbenzene ug/L ND 1.0 10/18/17 10:160.30
Iodomethane ug/L ND 10.0 10/18/17 10:160.32
Methylene Chloride ug/L ND 1.0 10/18/17 10:160.97
Styrene ug/L ND 1.0 10/18/17 10:160.26
Tetrachloroethene ug/L ND 1.0 10/18/17 10:160.46
Tetrahydrofuran ug/L ND 10.0 10/18/17 10:163.1
Toluene ug/L ND 1.0 10/18/17 10:160.26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2121854
Associated Lab Samples:92358257001, 92358257002, 92358257003, 92358257004, 92358257005, 92358257006, 92358257007,
92358257008, 92358257009
Matrix:Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 5.0 10/18/17 10:160.49
trans-1,3-Dichloropropene ug/L ND 1.0 10/18/17 10:160.26
trans-1,4-Dichloro-2-butene ug/L ND 100 10/18/17 10:161.0
Trichloroethene ug/L ND 1.0 10/18/17 10:160.47
Trichlorofluoromethane ug/L ND 1.0 10/18/17 10:160.20
Vinyl acetate ug/L ND 50.0 10/18/17 10:160.35
Vinyl chloride ug/L ND 1.0 10/18/17 10:160.62
Xylene (Total)ug/L ND 5.0 10/18/17 10:160.66
1,2-Dichloroethane-d4 (S)%83 70-130 10/18/17 10:16
4-Bromofluorobenzene (S)%100 70-130 10/18/17 10:16
Toluene-d8 (S)%108 70-130 10/18/17 10:16
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2121855LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.050 102 80-125
1,1,1-Trichloroethane ug/L 54.150 108 71-129
1,1,2,2-Tetrachloroethane ug/L 49.950 100 79-124
1,1,2-Trichloroethane ug/L 50.750 101 85-125
1,1-Dichloroethane ug/L 48.850 98 73-126
1,1-Dichloroethene ug/L 49.050 98 66-135
1,2,3-Trichloropropane ug/L 53.550 107 75-130
1,2-Dibromo-3-chloropropane ug/L 42.950 86 71-133
1,2-Dibromoethane (EDB)ug/L 56.350 113 83-124
1,2-Dichlorobenzene ug/L 49.350 99 80-133
1,2-Dichloroethane ug/L 52.750 105 67-128
1,2-Dichloropropane ug/L 53.850 108 75-132
1,4-Dichlorobenzene ug/L 48.250 96 78-130
2-Butanone (MEK)ug/L 104100 104 61-144
2-Hexanone ug/L 95.4100 95 68-143
4-Methyl-2-pentanone (MIBK)ug/L 99.9J100 100 72-135
Acetone ug/L 106100 106 48-146
Acrylonitrile ug/L 263250 105 40-160
Benzene ug/L 54.350 109 80-125
Bromochloromethane ug/L 52.750 105 71-125
Bromodichloromethane ug/L 55.750 111 78-124
Bromoform ug/L 43.250 86 71-128
Bromomethane ug/L 52.850 106 40-160
Carbon disulfide ug/L 51.3J50 103 50-160
Carbon tetrachloride ug/L 53.750 107 69-131
Chlorobenzene ug/L 48.350 97 81-122
Chloroethane ug/L 76.0 L15015239-148
Chloroform ug/L 47.350 95 73-127
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2121855LABORATORY CONTROL SAMPLE:
LCSSpike
Chloromethane ug/L 46.450 93 44-146
cis-1,2-Dichloroethene ug/L 51.550 103 74-124
cis-1,3-Dichloropropene ug/L 56.050 112 72-132
Dibromochloromethane ug/L 48.450 97 78-125
Dibromomethane ug/L 50.250 100 82-120
Ethylbenzene ug/L 49.450 99 79-121
Iodomethane ug/L 93.7100 94 39-154
Methylene Chloride ug/L 48.550 97 64-133
Styrene ug/L 49.550 99 84-126
Tetrachloroethene ug/L 50.450 101 78-122
Tetrahydrofuran ug/L 555500 111 69-148
Toluene ug/L 48.450 97 80-121
trans-1,2-Dichloroethene ug/L 48.350 97 71-127
trans-1,3-Dichloropropene ug/L 54.650 109 69-141
trans-1,4-Dichloro-2-butene ug/L 37.1J50 74 40-160
Trichloroethene ug/L 56.850 114 78-122
Trichlorofluoromethane ug/L 47.850 96 53-137
Vinyl acetate ug/L 92.8100 93 40-160
Vinyl chloride ug/L 52.350 105 58-137
Xylene (Total)ug/L 152150 101 81-126
1,2-Dichloroethane-d4 (S)%107 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2121857MATRIX SPIKE SAMPLE:
MSSpike
Result
92358257003
1,1,1,2-Tetrachloroethane ug/L 17.720 89 70-130ND
1,1,1-Trichloroethane ug/L 19.720 98 70-130ND
1,1,2,2-Tetrachloroethane ug/L 18.520 92 70-130ND
1,1,2-Trichloroethane ug/L 18.520 93 70-130ND
1,1-Dichloroethane ug/L 19.820 99 70-130ND
1,1-Dichloroethene ug/L 20.520 103 70-166ND
1,2,3-Trichloropropane ug/L 21.720 108 70-130ND
1,2-Dibromo-3-chloropropane ug/L 18.320 92 70-130ND
1,2-Dibromoethane (EDB)ug/L 19.620 98 70-130ND
1,2-Dichlorobenzene ug/L 19.820 99 70-130ND
1,2-Dichloroethane ug/L 18.220 91 70-130ND
1,2-Dichloropropane ug/L 17.820 89 70-130ND
1,4-Dichlorobenzene ug/L 19.820 99 70-130ND
2-Butanone (MEK)ug/L 36.0J40 90 70-130ND
2-Hexanone ug/L 38.1J40 95 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 38.1J40 95 70-130ND
Acetone ug/L 32.8J40 82 70-130ND
Acrylonitrile ug/L 98.8J100 99 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2121857MATRIX SPIKE SAMPLE:
MSSpike
Result
92358257003
Benzene ug/L 18.820 94 70-148ND
Bromochloromethane ug/L 18.620 93 70-130ND
Bromodichloromethane ug/L 18.220 91 70-130ND
Bromoform ug/L 18.620 93 70-130ND
Bromomethane ug/L 12.6 M1206370-130ND
Carbon disulfide ug/L 20.5J20 103 70-130ND
Carbon tetrachloride ug/L 20.320 102 70-130ND
Chlorobenzene ug/L 17.820 89 70-146ND
Chloroethane ug/L 20.020 100 70-130ND
Chloroform ug/L 18.020 90 70-130ND
Chloromethane ug/L 14.720 73 70-130ND
cis-1,2-Dichloroethene ug/L 19.920 99 70-130ND
cis-1,3-Dichloropropene ug/L 17.620 88 70-130ND
Dibromochloromethane ug/L 18.420 92 70-130ND
Dibromomethane ug/L 20.120 100 70-130ND
Ethylbenzene ug/L 18.420 92 70-130ND
Iodomethane ug/L 17.0 M1404370-130ND
Methylene Chloride ug/L 19.020 95 70-130ND
Styrene ug/L 19.320 96 70-130ND
Tetrachloroethene ug/L 17.720 89 70-130ND
Tetrahydrofuran ug/L 199200 100 70-130ND
Toluene ug/L 17.620 88 70-155ND
trans-1,2-Dichloroethene ug/L 19.220 96 70-130ND
trans-1,3-Dichloropropene ug/L 17.220 86 70-130ND
trans-1,4-Dichloro-2-butene ug/L 11.2J M1205670-130ND
Trichloroethene ug/L 19.420 97 69-151ND
Trichlorofluoromethane ug/L 19.720 98 70-130ND
Vinyl acetate ug/L 31.3J40 78 70-130ND
Vinyl chloride ug/L 18.220 91 70-130ND
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%95 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92358257002
2121856SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
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Page 31 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92358257002
2121856SAMPLE DUPLICATE:
1,2-Dichlorobenzene ug/L 0.73J 300.49J
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 4.9 7 305.2
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L 1.9 3 301.8
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 16.4 4 3015.7
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L 7.4J 307.5J
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%85 287
4-Bromofluorobenzene (S)%103 1102
Toluene-d8 (S)%109 2111
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
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[phone]
Page 32 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
381305
EPA 180.1
EPA 180.1
180.1 Turbidity
Associated Lab Samples:92358257001, 92358257002, 92358257003, 92358257004, 92358257005, 92358257006, 92358257007,
92358257008, 92358257009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2113401
Associated Lab Samples:92358257001, 92358257002, 92358257003, 92358257004, 92358257005, 92358257006, 92358257007,
92358257008, 92358257009
Matrix:Water
AnalyzedMDL
Turbidity NTU ND 1.0 10/07/17 01:300.50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2113402LABORATORY CONTROL SAMPLE:
LCSSpike
Turbidity NTU 10.710 107 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92358232001
2113403SAMPLE DUPLICATE:
Turbidity NTU 0.51J H310ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92358257001
2113404SAMPLE DUPLICATE:
Turbidity NTU 26.5 D699109.0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
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Huntersville, NC 28078
[phone]
Page 33 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
381454
SM 2540D
SM 2540D
2540D Total Suspended Solids
Associated Lab Samples:92358257001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2113858
Associated Lab Samples:92358257001
Matrix:Water
AnalyzedMDL
Total Suspended Solids ug/L ND 2500 10/09/17 12:412500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2113859LABORATORY CONTROL SAMPLE:
LCSSpike
Total Suspended Solids ug/L 260000250000 104 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92358196001
2113860SAMPLE DUPLICATE:
Total Suspended Solids ug/L ND 5ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92357535007
2113861SAMPLE DUPLICATE:
Total Suspended Solids ug/L ND 5ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
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Huntersville, NC 28078
[phone]
Page 34 of 39
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Analyte was detected in the associated method blank.B
Common Laboratory Contaminant.C9
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
Sample was received or analysis requested beyond the recognized method holding time.H3
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.L1
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 39
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92358257
WAYNE CLOSED LF
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92358257001 381897 382071MW-1R EPA 3010A EPA 6010
92358257002 381897 382071MW-2 EPA 3010A EPA 6010
92358257003 382384 382448MW-3 EPA 3010A EPA 6010
92358257004 382384 382448MW-4 EPA 3010A EPA 6010
92358257005 382384 382448MW-5 EPA 3010A EPA 6010
92358257006 382384 382448MW-6 EPA 3010A EPA 6010
92358257007 382384 382448MW-7 EPA 3010A EPA 6010
92358257008 382384 382448MW-8 EPA 3010A EPA 6010
92358257009 382384 382448MW-11 EPA 3010A EPA 6010
92358257001 381406 381512MW-1R EPA 3010A EPA 6020B
92358257002 381406 381512MW-2 EPA 3010A EPA 6020B
92358257003 381406 381512MW-3 EPA 3010A EPA 6020B
92358257004 381406 381512MW-4 EPA 3010A EPA 6020B
92358257005 381406 381512MW-5 EPA 3010A EPA 6020B
92358257006 381406 381512MW-6 EPA 3010A EPA 6020B
92358257007 381406 381512MW-7 EPA 3010A EPA 6020B
92358257008 381406 381512MW-8 EPA 3010A EPA 6020B
92358257009 381406 381512MW-11 EPA 3010A EPA 6020B
92358257001 382904MW-1R EPA 8260
92358257002 382904MW-2 EPA 8260
92358257003 382904MW-3 EPA 8260
92358257004 382904MW-4 EPA 8260
92358257005 382904MW-5 EPA 8260
92358257006 382904MW-6 EPA 8260
92358257007 382904MW-7 EPA 8260
92358257008 382904MW-8 EPA 8260
92358257009 382904MW-11 EPA 8260
92358257001 381305MW-1R EPA 180.1
92358257002 381305MW-2 EPA 180.1
92358257003 381305MW-3 EPA 180.1
92358257004 381305MW-4 EPA 180.1
92358257005 381305MW-5 EPA 180.1
92358257006 381305MW-6 EPA 180.1
92358257007 381305MW-7 EPA 180.1
92358257008 381305MW-8 EPA 180.1
92358257009 381305MW-11 EPA 180.1
92358257001 381454MW-1R SM 2540D
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 03:56 PM
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[phone]
Page 36 of 39
Page 37 of 39
Page 38 of 39
Page 39 of 39
#=CL#
October 25, 2017
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92358246
92358246
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
68 Shipwash Dr.
Garner, NC 27529
Wayne MSWLF Blanks
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on October 06, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 1 of 30
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 2 of 30
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Lab ID Sample ID Matrix Date Collected Date Received
92358246001 EB Water 10/05/17 00:00 10/06/17 09:51
92358246002 FB Water 10/05/17 00:00 10/06/17 09:51
92358246003 TB Water 10/05/17 00:00 10/06/17 09:51
REPORT OF LABORATORY ANALYSIS
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Page 3 of 30
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92358246001 EB EPA 8081 21 PASI-CPKS
EPA 6010 15 PASI-ADS
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AKAL
EPA 8260 67 PASI-CGAW
SM 4500-CN-E 1 PASI-ACJH1
92358246002 FB EPA 6010 15 PASI-ADS
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AKAL
EPA 8260 67 PASI-CGAW
92358246003 TB EPA 8260 67 PASI-CGAW
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Sample:EB Lab ID:92358246001 Collected:10/05/17 00:00 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 10/16/17 18:55 309-00-210/09/17 13:000.050 0.050 1
alpha-BHC ND ug/L 10/16/17 18:55 319-84-610/09/17 13:000.050 0.050 1
beta-BHC ND ug/L 10/16/17 18:55 319-85-710/09/17 13:000.050 0.050 1
delta-BHC ND ug/L 10/16/17 18:55 319-86-810/09/17 13:000.050 0.050 1
gamma-BHC (Lindane)ND ug/L 10/16/17 18:55 58-89-910/09/17 13:000.050 0.050 1
Chlordane (Technical)ND ug/L 10/16/17 18:55 57-74-910/09/17 13:000.50 0.20 1
4,4'-DDD ND ug/L 10/16/17 18:55 72-54-810/09/17 13:000.10 0.050 1
4,4'-DDE ND ug/L 10/16/17 18:55 72-55-910/09/17 13:000.10 0.050 1
4,4'-DDT ND ug/L 10/16/17 18:55 50-29-310/09/17 13:000.10 0.050 1
Dieldrin ND ug/L 10/16/17 18:55 60-57-110/09/17 13:000.075 0.050 1
Endosulfan I ND ug/L 10/16/17 18:55 959-98-810/09/17 13:000.10 0.050 1
Endosulfan II ND ug/L 10/16/17 18:55 33213-65-910/09/17 13:000.10 0.050 1
Endosulfan sulfate ND ug/L 10/16/17 18:55 1031-07-810/09/17 13:000.10 0.050 1
Endrin ND ug/L 10/16/17 18:55 72-20-810/09/17 13:000.10 0.050 1
Endrin aldehyde ND ug/L 10/16/17 18:55 7421-93-410/09/17 13:000.10 0.050 1
Heptachlor ND ug/L 10/16/17 18:55 76-44-810/09/17 13:000.050 0.050 1
Heptachlor epoxide ND ug/L 10/16/17 18:55 1024-57-310/09/17 13:000.075 0.050 1
Methoxychlor ND ug/L 10/16/17 18:55 72-43-510/09/17 13:001.0 0.15 1
Toxaphene ND ug/L 10/16/17 18:55 8001-35-210/09/17 13:001.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)96 %10/16/17 18:55 877-09-810/09/17 13:0020-130 1
Decachlorobiphenyl (S)29 %10/16/17 18:55 2051-24-310/09/17 13:0020-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 10/14/17 19:18 7440-36-010/11/17 17:406.0 3.9 1
Arsenic ND ug/L 10/14/17 19:18 7440-38-210/11/17 17:4010.0 5.0 1
Barium ND ug/L 10/14/17 19:18 7440-39-310/11/17 17:401002.5 1
Beryllium ND ug/L 10/14/17 19:18 7440-41-710/11/17 17:401.0 0.50 1
Cadmium ND ug/L 10/14/17 19:18 7440-43-910/11/17 17:401.0 0.50 1
Chromium ND ug/L 10/14/17 19:18 7440-47-310/11/17 17:4010.0 2.5 1
Cobalt ND ug/L 10/14/17 19:18 7440-48-410/11/17 17:4010.0 2.5 1
Copper ND ug/L 10/14/17 19:18 7440-50-810/11/17 17:4010.0 2.5 1
Lead ND ug/L 10/14/17 19:18 7439-92-110/11/17 17:4010.0 2.5 1
Nickel ND ug/L 10/14/17 19:18 7440-02-010/11/17 17:4050.0 2.5 1
Selenium ND ug/L 10/14/17 19:18 7782-49-210/11/17 17:4010.0 5.0 1
Silver ND ug/L 10/14/17 19:18 7440-22-410/11/17 17:4010.0 2.5 1
Tin ND ug/L 10/14/17 19:18 7440-31-510/11/17 17:401002.5 1
Vanadium ND ug/L 10/14/17 19:18 7440-62-210/11/17 17:4025.0 2.5 1
Zinc ND ug/L 10/14/17 19:18 7440-66-610/11/17 17:4010.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 10/24/17 13:48 7440-28-010/09/17 08:555.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 10/10/17 16:18 7439-97-610/09/17 00:450.20 0.10 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Sample:EB Lab ID:92358246001 Collected:10/05/17 00:00 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/18/17 13:59 67-64-110010.0 1
Acetonitrile ND ug/L 10/18/17 13:59 75-05-855.0 2.2 1
Acrolein ND ug/L 10/18/17 13:59 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 10/18/17 13:59 107-13-12001.9 1
Allyl chloride ND ug/L 10/18/17 13:59 107-05-110.0 1.5 1
Benzene ND ug/L 10/18/17 13:59 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/18/17 13:59 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/18/17 13:59 75-27-41.0 0.18 1
Bromoform ND ug/L 10/18/17 13:59 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/18/17 13:59 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/18/17 13:59 78-93-31000.96 1
Carbon disulfide ND ug/L 10/18/17 13:59 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/18/17 13:59 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/18/17 13:59 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/18/17 13:59 75-00-3 L110.0 0.54 1
Chloroform ND ug/L 10/18/17 13:59 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/18/17 13:59 74-87-31.0 0.11 1
Chloroprene ND ug/L 10/18/17 13:59 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 10/18/17 13:59 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/18/17 13:59 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/18/17 13:59 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/18/17 13:59 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/18/17 13:59 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 10/18/17 13:59 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 10/18/17 13:59 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/18/17 13:59 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 10/18/17 13:59 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 10/18/17 13:59 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/18/17 13:59 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/18/17 13:59 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/18/17 13:59 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/18/17 13:59 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/18/17 13:59 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 10/18/17 13:59 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 10/18/17 13:59 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 10/18/17 13:59 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 10/18/17 13:59 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 10/18/17 13:59 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/18/17 13:59 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 10/18/17 13:59 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 10/18/17 13:59 87-68-310.0 0.71 1
2-Hexanone ND ug/L 10/18/17 13:59 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/18/17 13:59 74-88-410.0 0.32 1
Isobutanol ND ug/L 10/18/17 13:59 78-83-110035.0 1
Methacrylonitrile ND ug/L 10/18/17 13:59 126-98-71000.93 1
Methylene Chloride ND ug/L 10/18/17 13:59 75-09-21.0 0.97 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Sample:EB Lab ID:92358246001 Collected:10/05/17 00:00 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Methyl methacrylate ND ug/L 10/18/17 13:59 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/18/17 13:59 108-10-11000.33 1
Naphthalene ND ug/L 10/18/17 13:59 91-20-310.0 0.24 1
Propionitrile ND ug/L 10/18/17 13:59 107-12-01503.6 1
Styrene ND ug/L 10/18/17 13:59 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/18/17 13:59 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/18/17 13:59 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/18/17 13:59 127-18-41.0 0.46 1
Toluene ND ug/L 10/18/17 13:59 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 10/18/17 13:59 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 10/18/17 13:59 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/18/17 13:59 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/18/17 13:59 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/18/17 13:59 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/18/17 13:59 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/18/17 13:59 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/18/17 13:59 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/18/17 13:59 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %10/18/17 13:59 460-00-470-130 1
1,2-Dichloroethane-d4 (S)85 %10/18/17 13:59 17060-07-070-130 1
Toluene-d8 (S)111 %10/18/17 13:59 2037-26-570-130 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 10/11/17 04:25 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
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Page 7 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Sample:FB Lab ID:92358246002 Collected:10/05/17 00:00 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 10/14/17 19:22 7440-36-010/11/17 17:406.0 3.9 1
Arsenic ND ug/L 10/14/17 19:22 7440-38-210/11/17 17:4010.0 5.0 1
Barium ND ug/L 10/14/17 19:22 7440-39-310/11/17 17:401002.5 1
Beryllium ND ug/L 10/14/17 19:22 7440-41-710/11/17 17:401.0 0.50 1
Cadmium ND ug/L 10/14/17 19:22 7440-43-910/11/17 17:401.0 0.50 1
Chromium ND ug/L 10/14/17 19:22 7440-47-310/11/17 17:4010.0 2.5 1
Cobalt ND ug/L 10/14/17 19:22 7440-48-410/11/17 17:4010.0 2.5 1
Copper ND ug/L 10/14/17 19:22 7440-50-810/11/17 17:4010.0 2.5 1
Lead ND ug/L 10/14/17 19:22 7439-92-110/11/17 17:4010.0 2.5 1
Nickel ND ug/L 10/14/17 19:22 7440-02-010/11/17 17:4050.0 2.5 1
Selenium ND ug/L 10/14/17 19:22 7782-49-210/11/17 17:4010.0 5.0 1
Silver ND ug/L 10/14/17 19:22 7440-22-410/11/17 17:4010.0 2.5 1
Tin ND ug/L 10/14/17 19:22 7440-31-510/11/17 17:401002.5 1
Vanadium ND ug/L 10/14/17 19:22 7440-62-210/11/17 17:4025.0 2.5 1
Zinc ND ug/L 10/14/17 19:22 7440-66-610/11/17 17:4010.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 10/24/17 13:50 7440-28-010/09/17 08:555.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 10/10/17 16:21 7439-97-610/09/17 00:450.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/18/17 14:16 67-64-110010.0 1
Acetonitrile ND ug/L 10/18/17 14:16 75-05-855.0 2.2 1
Acrolein ND ug/L 10/18/17 14:16 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 10/18/17 14:16 107-13-12001.9 1
Allyl chloride ND ug/L 10/18/17 14:16 107-05-110.0 1.5 1
Benzene ND ug/L 10/18/17 14:16 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/18/17 14:16 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/18/17 14:16 75-27-41.0 0.18 1
Bromoform ND ug/L 10/18/17 14:16 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/18/17 14:16 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/18/17 14:16 78-93-31000.96 1
Carbon disulfide ND ug/L 10/18/17 14:16 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/18/17 14:16 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/18/17 14:16 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/18/17 14:16 75-00-3 L110.0 0.54 1
Chloroform ND ug/L 10/18/17 14:16 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/18/17 14:16 74-87-31.0 0.11 1
Chloroprene ND ug/L 10/18/17 14:16 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 10/18/17 14:16 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/18/17 14:16 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/18/17 14:16 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/18/17 14:16 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/18/17 14:16 95-50-15.0 0.30 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
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Page 8 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Sample:FB Lab ID:92358246002 Collected:10/05/17 00:00 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,3-Dichlorobenzene ND ug/L 10/18/17 14:16 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 10/18/17 14:16 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/18/17 14:16 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 10/18/17 14:16 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 10/18/17 14:16 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/18/17 14:16 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/18/17 14:16 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/18/17 14:16 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/18/17 14:16 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/18/17 14:16 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 10/18/17 14:16 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 10/18/17 14:16 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 10/18/17 14:16 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 10/18/17 14:16 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 10/18/17 14:16 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/18/17 14:16 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 10/18/17 14:16 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 10/18/17 14:16 87-68-310.0 0.71 1
2-Hexanone ND ug/L 10/18/17 14:16 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/18/17 14:16 74-88-410.0 0.32 1
Isobutanol ND ug/L 10/18/17 14:16 78-83-110035.0 1
Methacrylonitrile ND ug/L 10/18/17 14:16 126-98-71000.93 1
Methylene Chloride ND ug/L 10/18/17 14:16 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 10/18/17 14:16 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/18/17 14:16 108-10-11000.33 1
Naphthalene ND ug/L 10/18/17 14:16 91-20-310.0 0.24 1
Propionitrile ND ug/L 10/18/17 14:16 107-12-01503.6 1
Styrene ND ug/L 10/18/17 14:16 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/18/17 14:16 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/18/17 14:16 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/18/17 14:16 127-18-41.0 0.46 1
Toluene ND ug/L 10/18/17 14:16 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 10/18/17 14:16 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 10/18/17 14:16 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/18/17 14:16 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/18/17 14:16 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/18/17 14:16 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/18/17 14:16 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/18/17 14:16 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/18/17 14:16 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/18/17 14:16 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)97 %10/18/17 14:16 460-00-470-130 1
1,2-Dichloroethane-d4 (S)80 %10/18/17 14:16 17060-07-070-130 1
Toluene-d8 (S)117 %10/18/17 14:16 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Sample:TB Lab ID:92358246003 Collected:10/05/17 00:00 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/18/17 14:32 67-64-110010.0 1
Acetonitrile ND ug/L 10/18/17 14:32 75-05-855.0 2.2 1
Acrolein ND ug/L 10/18/17 14:32 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 10/18/17 14:32 107-13-12001.9 1
Allyl chloride ND ug/L 10/18/17 14:32 107-05-110.0 1.5 1
Benzene ND ug/L 10/18/17 14:32 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/18/17 14:32 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/18/17 14:32 75-27-41.0 0.18 1
Bromoform ND ug/L 10/18/17 14:32 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/18/17 14:32 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/18/17 14:32 78-93-31000.96 1
Carbon disulfide ND ug/L 10/18/17 14:32 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/18/17 14:32 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/18/17 14:32 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/18/17 14:32 75-00-3 L110.0 0.54 1
Chloroform ND ug/L 10/18/17 14:32 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/18/17 14:32 74-87-31.0 0.11 1
Chloroprene ND ug/L 10/18/17 14:32 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 10/18/17 14:32 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/18/17 14:32 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/18/17 14:32 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/18/17 14:32 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/18/17 14:32 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 10/18/17 14:32 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 10/18/17 14:32 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/18/17 14:32 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 10/18/17 14:32 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 10/18/17 14:32 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/18/17 14:32 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/18/17 14:32 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/18/17 14:32 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/18/17 14:32 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/18/17 14:32 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 10/18/17 14:32 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 10/18/17 14:32 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 10/18/17 14:32 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 10/18/17 14:32 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 10/18/17 14:32 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/18/17 14:32 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 10/18/17 14:32 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 10/18/17 14:32 87-68-310.0 0.71 1
2-Hexanone ND ug/L 10/18/17 14:32 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/18/17 14:32 74-88-410.0 0.32 1
Isobutanol ND ug/L 10/18/17 14:32 78-83-110035.0 1
Methacrylonitrile ND ug/L 10/18/17 14:32 126-98-71000.93 1
Methylene Chloride ND ug/L 10/18/17 14:32 75-09-21.0 0.97 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 10 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Sample:TB Lab ID:92358246003 Collected:10/05/17 00:00 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Methyl methacrylate ND ug/L 10/18/17 14:32 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/18/17 14:32 108-10-11000.33 1
Naphthalene ND ug/L 10/18/17 14:32 91-20-310.0 0.24 1
Propionitrile ND ug/L 10/18/17 14:32 107-12-01503.6 1
Styrene ND ug/L 10/18/17 14:32 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/18/17 14:32 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/18/17 14:32 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/18/17 14:32 127-18-41.0 0.46 1
Toluene ND ug/L 10/18/17 14:32 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 10/18/17 14:32 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 10/18/17 14:32 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/18/17 14:32 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/18/17 14:32 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/18/17 14:32 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/18/17 14:32 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/18/17 14:32 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/18/17 14:32 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/18/17 14:32 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %10/18/17 14:32 460-00-470-130 1
1,2-Dichloroethane-d4 (S)79 %10/18/17 14:32 17060-07-070-130 1
Toluene-d8 (S)112 %10/18/17 14:32 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
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Page 11 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
381413
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92358246001, 92358246002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2113720
Associated Lab Samples:92358246001, 92358246002
Matrix:Water
AnalyzedMDL
Mercury ug/L ND 0.20 10/10/17 15:550.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2113721LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.42.5 94 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2113722MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92357829010
2113723
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 94 75-12598 3 252.5ND 2.4 2.4
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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Page 12 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
381897
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples:92358246001, 92358246002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2116269
Associated Lab Samples:92358246001, 92358246002
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 5.0 10/14/17 18:253.9
Arsenic ug/L ND 10.0 10/14/17 18:255.0
Barium ug/L ND 5.0 10/14/17 18:252.5
Beryllium ug/L ND 1.0 10/14/17 18:250.50
Cadmium ug/L ND 1.0 10/14/17 18:250.50
Chromium ug/L ND 5.0 10/14/17 18:252.5
Cobalt ug/L ND 5.0 10/14/17 18:252.5
Copper ug/L ND 5.0 10/14/17 18:252.5
Lead ug/L ND 5.0 10/14/17 18:252.5
Nickel ug/L ND 5.0 10/14/17 18:252.5
Selenium ug/L ND 10.0 10/14/17 18:255.0
Silver ug/L ND 5.0 10/14/17 18:252.5
Tin ug/L ND 5.0 10/14/17 18:252.5
Vanadium ug/L ND 5.0 10/14/17 18:252.5
Zinc ug/L ND 10.0 10/14/17 18:255.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2116270LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 531500 106 80-120
Arsenic ug/L 521500 104 80-120
Barium ug/L 526500 105 80-120
Beryllium ug/L 519500 104 80-120
Cadmium ug/L 528500 106 80-120
Chromium ug/L 525500 105 80-120
Cobalt ug/L 539500 108 80-120
Copper ug/L 547500 109 80-120
Lead ug/L 532500 106 80-120
Nickel ug/L 523500 105 80-120
Selenium ug/L 540500 108 80-120
Silver ug/L 267250 107 80-120
Tin ug/L 534500 107 80-120
Vanadium ug/L 520500 104 80-120
Zinc ug/L 530500 106 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2116271MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92358008010
2116272
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 108 75-125104 3 20500ND538521
Arsenic ug/L 500 104 75-125102 2 20500ND524512
Barium ug/L 500 106 75-125103 3 20500ND531514
Beryllium ug/L 500 105 75-125102 3 20500ND525511
Cadmium ug/L 500 106 75-125103 3 20500ND532515
Chromium ug/L 500 104 75-125102 3 20500ND522508
Cobalt ug/L 500 107 75-125104 3 20500ND537520
Copper ug/L 500 110 75-125107 3 20500ND549534
Lead ug/L 500 105 75-125103 3 20500ND527513
Nickel ug/L 500 104 75-125101 3 20500ND521504
Selenium ug/L 500 108 75-125105 3 20500ND542526
Silver ug/L 250 107 75-125104 3 20250ND267259
Tin ug/L 500 108 75-125104 4 20500ND540521
Vanadium ug/L 500 105 75-125102 3 20500ND525510
Zinc ug/L 500 106 75-125103 3 20500ND535518
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
381405
EPA 3010A
EPA 6020B
6020 MET
Associated Lab Samples:92358246001, 92358246002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2113678
Associated Lab Samples:92358246001, 92358246002
Matrix:Water
AnalyzedMDL
Thallium ug/L ND 0.10 10/24/17 12:420.020
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2113679LABORATORY CONTROL SAMPLE:
LCSSpike
Thallium ug/L 99.2100 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2113680MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92358245004
2113681
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Thallium ug/L 100 97 75-12595 2 201000.047J 97.2 95.0
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2113682MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92358245014
2113683
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Thallium ug/L 100 100 75-125101 1 20100ND100101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
382904
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92358246001, 92358246002, 92358246003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2121854
Associated Lab Samples:92358246001, 92358246002, 92358246003
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 10/18/17 10:160.33
1,1,1-Trichloroethane ug/L ND 1.0 10/18/17 10:160.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 10/18/17 10:160.40
1,1,2-Trichloroethane ug/L ND 1.0 10/18/17 10:160.29
1,1-Dichloroethane ug/L ND 5.0 10/18/17 10:160.32
1,1-Dichloroethene ug/L ND 5.0 10/18/17 10:160.56
1,1-Dichloropropene ug/L ND 5.0 10/18/17 10:160.49
1,2,3-Trichloropropane ug/L ND 1.0 10/18/17 10:160.41
1,2,4-Trichlorobenzene ug/L ND 10.0 10/18/17 10:160.35
1,2-Dibromo-3-chloropropane ug/L ND 13.0 10/18/17 10:162.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 10/18/17 10:160.27
1,2-Dichlorobenzene ug/L ND 5.0 10/18/17 10:160.30
1,2-Dichloroethane ug/L ND 1.0 10/18/17 10:160.24
1,2-Dichloropropane ug/L ND 1.0 10/18/17 10:160.27
1,3-Dichlorobenzene ug/L ND 5.0 10/18/17 10:160.24
1,3-Dichloropropane ug/L ND 1.0 10/18/17 10:160.28
1,4-Dichlorobenzene ug/L ND 1.0 10/18/17 10:160.33
2,2-Dichloropropane ug/L ND 15.0 10/18/17 10:160.13
2-Butanone (MEK)ug/L ND 100 10/18/17 10:160.96
2-Hexanone ug/L ND 50.0 10/18/17 10:160.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 10/18/17 10:160.33
Acetone ug/L ND 100 10/18/17 10:1610.0
Acetonitrile ug/L ND 55.0 10/18/17 10:162.2
Acrolein ug/L ND 53.0 10/18/17 10:161.6
Acrylonitrile ug/L ND 200 10/18/17 10:161.9
Allyl chloride ug/L ND 10.0 10/18/17 10:161.5
Benzene ug/L ND 1.0 10/18/17 10:160.25
Bromochloromethane ug/L ND 3.0 10/18/17 10:160.17
Bromodichloromethane ug/L ND 1.0 10/18/17 10:160.18
Bromoform ug/L ND 3.0 10/18/17 10:160.26
Bromomethane ug/L ND 10.0 10/18/17 10:160.29
Carbon disulfide ug/L ND 100 10/18/17 10:161.2
Carbon tetrachloride ug/L ND 1.0 10/18/17 10:160.25
Chlorobenzene ug/L ND 3.0 10/18/17 10:160.23
Chloroethane ug/L ND 10.0 10/18/17 10:160.54
Chloroform ug/L 0.39J 5.0 10/18/17 10:160.14
Chloromethane ug/L ND 1.0 10/18/17 10:160.11
Chloroprene ug/L ND 20.0 10/18/17 10:160.27
cis-1,2-Dichloroethene ug/L ND 5.0 10/18/17 10:160.19
cis-1,3-Dichloropropene ug/L ND 1.0 10/18/17 10:160.13
Dibromochloromethane ug/L ND 3.0 10/18/17 10:160.21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2121854
Associated Lab Samples:92358246001, 92358246002, 92358246003
Matrix:Water
AnalyzedMDL
Dibromomethane ug/L ND 10.0 10/18/17 10:160.21
Dichlorodifluoromethane ug/L ND 5.0 10/18/17 10:160.21
Ethyl methacrylate ug/L ND 10.0 10/18/17 10:160.20
Ethylbenzene ug/L ND 1.0 10/18/17 10:160.30
Hexachloro-1,3-butadiene ug/L ND 10.0 10/18/17 10:160.71
Iodomethane ug/L ND 10.0 10/18/17 10:160.32
Isobutanol ug/L ND 100 10/18/17 10:1635.0
Methacrylonitrile ug/L ND 100 10/18/17 10:160.93
Methyl methacrylate ug/L ND 30.0 10/18/17 10:162.0
Methylene Chloride ug/L ND 1.0 10/18/17 10:160.97
Naphthalene ug/L ND 10.0 10/18/17 10:160.24
Propionitrile ug/L ND 150 10/18/17 10:163.6
Styrene ug/L ND 1.0 10/18/17 10:160.26
Tetrachloroethene ug/L ND 1.0 10/18/17 10:160.46
Toluene ug/L ND 1.0 10/18/17 10:160.26
trans-1,2-Dichloroethene ug/L ND 5.0 10/18/17 10:160.49
trans-1,3-Dichloropropene ug/L ND 1.0 10/18/17 10:160.26
trans-1,4-Dichloro-2-butene ug/L ND 100 10/18/17 10:161.0
Trichloroethene ug/L ND 1.0 10/18/17 10:160.47
Trichlorofluoromethane ug/L ND 1.0 10/18/17 10:160.20
Vinyl acetate ug/L ND 50.0 10/18/17 10:160.35
Vinyl chloride ug/L ND 1.0 10/18/17 10:160.62
Xylene (Total)ug/L ND 5.0 10/18/17 10:160.66
1,2-Dichloroethane-d4 (S)%83 70-130 10/18/17 10:16
4-Bromofluorobenzene (S)%100 70-130 10/18/17 10:16
Toluene-d8 (S)%108 70-130 10/18/17 10:16
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2121855LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.050 102 80-125
1,1,1-Trichloroethane ug/L 54.150 108 71-129
1,1,2,2-Tetrachloroethane ug/L 49.950 100 79-124
1,1,2-Trichloroethane ug/L 50.750 101 85-125
1,1-Dichloroethane ug/L 48.850 98 73-126
1,1-Dichloroethene ug/L 49.050 98 66-135
1,1-Dichloropropene ug/L 47.850 96 74-135
1,2,3-Trichloropropane ug/L 53.550 107 75-130
1,2,4-Trichlorobenzene ug/L 48.650 97 75-134
1,2-Dibromo-3-chloropropane ug/L 42.950 86 71-133
1,2-Dibromoethane (EDB)ug/L 56.350 113 83-124
1,2-Dichlorobenzene ug/L 49.350 99 80-133
1,2-Dichloroethane ug/L 52.750 105 67-128
1,2-Dichloropropane ug/L 53.850 108 75-132
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2121855LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 45.050 90 77-130
1,3-Dichloropropane ug/L 56.950 114 76-131
1,4-Dichlorobenzene ug/L 48.250 96 78-130
2,2-Dichloropropane ug/L 53.050 106 40-160
2-Butanone (MEK)ug/L 104100 104 61-144
2-Hexanone ug/L 95.4100 95 68-143
4-Methyl-2-pentanone (MIBK)ug/L 99.9J100 100 72-135
Acetone ug/L 106100 106 48-146
Acetonitrile ug/L 497500 99 62-150
Acrolein ug/L 330250 132 24-160
Acrylonitrile ug/L 263250 105 40-160
Allyl chloride ug/L 50.450 101 66-137
Benzene ug/L 54.350 109 80-125
Bromochloromethane ug/L 52.750 105 71-125
Bromodichloromethane ug/L 55.750 111 78-124
Bromoform ug/L 43.250 86 71-128
Bromomethane ug/L 52.850 106 40-160
Carbon disulfide ug/L 51.3J50 103 50-160
Carbon tetrachloride ug/L 53.750 107 69-131
Chlorobenzene ug/L 48.350 97 81-122
Chloroethane ug/L 76.0 L15015239-148
Chloroform ug/L 47.350 95 73-127
Chloromethane ug/L 46.450 93 44-146
Chloroprene ug/L 57.250 114 75-145
cis-1,2-Dichloroethene ug/L 51.550 103 74-124
cis-1,3-Dichloropropene ug/L 56.050 112 72-132
Dibromochloromethane ug/L 48.450 97 78-125
Dibromomethane ug/L 50.250 100 82-120
Dichlorodifluoromethane ug/L 40.950 82 34-157
Ethyl methacrylate ug/L 45.050 90 82-121
Ethylbenzene ug/L 49.450 99 79-121
Hexachloro-1,3-butadiene ug/L 47.750 95 72-131
Iodomethane ug/L 93.7100 94 39-154
Isobutanol ug/L 8871000 89 34-160
Methacrylonitrile ug/L 463500 93 74-134
Methyl methacrylate ug/L 47.350 95 84-124
Methylene Chloride ug/L 48.550 97 64-133
Naphthalene ug/L 49.950 100 73-133
Propionitrile ug/L 507500 101 73-140
Styrene ug/L 49.550 99 84-126
Tetrachloroethene ug/L 50.450 101 78-122
Toluene ug/L 48.450 97 80-121
trans-1,2-Dichloroethene ug/L 48.350 97 71-127
trans-1,3-Dichloropropene ug/L 54.650 109 69-141
trans-1,4-Dichloro-2-butene ug/L 37.1J50 74 40-160
Trichloroethene ug/L 56.850 114 78-122
Trichlorofluoromethane ug/L 47.850 96 53-137
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2121855LABORATORY CONTROL SAMPLE:
LCSSpike
Vinyl acetate ug/L 92.8100 93 40-160
Vinyl chloride ug/L 52.350 105 58-137
Xylene (Total)ug/L 152150 101 81-126
1,2-Dichloroethane-d4 (S)%107 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2121857MATRIX SPIKE SAMPLE:
MSSpike
Result
92358257003
1,1,1,2-Tetrachloroethane ug/L 17.720 89 70-130ND
1,1,1-Trichloroethane ug/L 19.720 98 70-130ND
1,1,2,2-Tetrachloroethane ug/L 18.520 92 70-130ND
1,1,2-Trichloroethane ug/L 18.520 93 70-130ND
1,1-Dichloroethane ug/L 19.820 99 70-130ND
1,1-Dichloroethene ug/L 20.520 103 70-166ND
1,1-Dichloropropene ug/L 17.820 89 70-130ND
1,2,3-Trichloropropane ug/L 21.720 108 70-130ND
1,2,4-Trichlorobenzene ug/L 19.020 95 70-130ND
1,2-Dibromo-3-chloropropane ug/L 18.320 92 70-130ND
1,2-Dibromoethane (EDB)ug/L 19.620 98 70-130ND
1,2-Dichlorobenzene ug/L 19.820 99 70-130ND
1,2-Dichloroethane ug/L 18.220 91 70-130ND
1,2-Dichloropropane ug/L 17.820 89 70-130ND
1,3-Dichlorobenzene ug/L 17.520 88 70-130ND
1,3-Dichloropropane ug/L 20.220 101 70-130ND
1,4-Dichlorobenzene ug/L 19.820 99 70-130ND
2,2-Dichloropropane ug/L 18.020 90 70-130ND
2-Butanone (MEK)ug/L 36.0J40 90 70-130ND
2-Hexanone ug/L 38.1J40 95 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 38.1J40 95 70-130ND
Acetone ug/L 32.8J40 82 70-130ND
Acetonitrile ug/L 187200 93 70-130ND
Acrolein ug/L 129100 129 70-130ND
Acrylonitrile ug/L 98.8J100 99 70-130ND
Allyl chloride ug/L 19.820 99 70-130ND
Benzene ug/L 18.820 94 70-148ND
Bromochloromethane ug/L 18.620 93 70-130ND
Bromodichloromethane ug/L 18.220 91 70-130ND
Bromoform ug/L 18.620 93 70-130ND
Bromomethane ug/L 12.6 M1206370-130ND
Carbon disulfide ug/L 20.5J20 103 70-130ND
Carbon tetrachloride ug/L 20.320 102 70-130ND
Chlorobenzene ug/L 17.820 89 70-146ND
Chloroethane ug/L 20.020 100 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2121857MATRIX SPIKE SAMPLE:
MSSpike
Result
92358257003
Chloroform ug/L 18.020 90 70-130ND
Chloromethane ug/L 14.720 73 70-130ND
Chloroprene ug/L 18.5J20 92 70-130ND
cis-1,2-Dichloroethene ug/L 19.920 99 70-130ND
cis-1,3-Dichloropropene ug/L 17.620 88 70-130ND
Dibromochloromethane ug/L 18.420 92 70-130ND
Dibromomethane ug/L 20.120 100 70-130ND
Dichlorodifluoromethane ug/L 13.8 M1206970-130ND
Ethyl methacrylate ug/L 17.420 87 70-130ND
Ethylbenzene ug/L 18.420 92 70-130ND
Hexachloro-1,3-butadiene ug/L 20.320 102 70-130ND
Iodomethane ug/L 17.0 M1404370-130ND
Isobutanol ug/L 320400 80 70-130ND
Methacrylonitrile ug/L 181200 90 70-130ND
Methyl methacrylate ug/L 18.4J20 92 70-130ND
Methylene Chloride ug/L 19.020 95 70-130ND
Naphthalene ug/L 18.820 94 70-130ND
Propionitrile ug/L 189200 94 70-130ND
Styrene ug/L 19.320 96 70-130ND
Tetrachloroethene ug/L 17.720 89 70-130ND
Toluene ug/L 17.620 88 70-155ND
trans-1,2-Dichloroethene ug/L 19.220 96 70-130ND
trans-1,3-Dichloropropene ug/L 17.220 86 70-130ND
trans-1,4-Dichloro-2-butene ug/L 11.2J M1205670-130ND
Trichloroethene ug/L 19.420 97 69-151ND
Trichlorofluoromethane ug/L 19.720 98 70-130ND
Vinyl acetate ug/L 31.3J40 78 70-130ND
Vinyl chloride ug/L 18.220 91 70-130ND
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%95 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92358257002
2121856SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,1-Dichloropropene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2,4-Trichlorobenzene ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92358257002
2121856SAMPLE DUPLICATE:
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L 0.73J 300.49J
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichlorobenzene ug/L 0.38J 300.30J
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 4.9 7 305.2
2,2-Dichloropropane ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acetonitrile ug/L ND 30ND
Acrolein ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Allyl chloride ug/L ND 30ND
Benzene ug/L 1.9 3 301.8
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 16.4 4 3015.7
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
Chloroprene ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Ethyl methacrylate ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Hexachloro-1,3-butadiene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Isobutanol ug/L ND 30ND
Methacrylonitrile ug/L ND 30ND
Methyl methacrylate ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Naphthalene ug/L 0.40J 300.41J
Propionitrile ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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Page 21 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92358257002
2121856SAMPLE DUPLICATE:
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%85 287
4-Bromofluorobenzene (S)%103 1102
Toluene-d8 (S)%109 2111
REPORT OF LABORATORY ANALYSIS
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Page 22 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
381490
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples:92358246001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2114004
Associated Lab Samples:92358246001
Matrix:Water
AnalyzedMDL
4,4'-DDD ug/L ND 0.10 10/15/17 23:090.050
4,4'-DDE ug/L ND 0.10 10/15/17 23:090.050
4,4'-DDT ug/L ND 0.10 10/15/17 23:090.050
Aldrin ug/L ND 0.050 10/15/17 23:090.050
alpha-BHC ug/L ND 0.050 10/15/17 23:090.050
beta-BHC ug/L ND 0.050 10/15/17 23:090.050
Chlordane (Technical)ug/L ND 0.50 10/15/17 23:090.20
delta-BHC ug/L ND 0.050 10/15/17 23:090.050
Dieldrin ug/L ND 0.075 10/15/17 23:090.050
Endosulfan I ug/L ND 0.10 10/15/17 23:090.050
Endosulfan II ug/L ND 0.10 10/15/17 23:090.050
Endosulfan sulfate ug/L ND 0.10 10/15/17 23:090.050
Endrin ug/L ND 0.10 10/15/17 23:090.050
Endrin aldehyde ug/L ND 0.10 10/15/17 23:090.050
gamma-BHC (Lindane)ug/L ND 0.050 10/15/17 23:090.050
Heptachlor ug/L ND 0.050 10/15/17 23:090.050
Heptachlor epoxide ug/L ND 0.075 10/15/17 23:090.050
Methoxychlor ug/L ND 1.0 10/15/17 23:090.15
Toxaphene ug/L ND 1.5 10/15/17 23:090.20
Decachlorobiphenyl (S)%66 20-130 10/15/17 23:09
Tetrachloro-m-xylene (S)%72 20-130 10/15/17 23:09
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2114005LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2114006
4,4'-DDD ug/L 0.24.25 98 20-1501040.26 6 30
4,4'-DDE ug/L 0.21.25 85 20-150890.22 5 30
4,4'-DDT ug/L 0.26.25 106 20-1501120.28 6 30
Aldrin ug/L 0.16.25 64 20-150680.17 6 30
alpha-BHC ug/L 0.20.25 81 20-150830.21 2 30
beta-BHC ug/L 0.19.25 76 20-150790.20 5 30
delta-BHC ug/L 0.23.25 94 20-150980.24 4 30
Dieldrin ug/L 0.22.25 90 20-150940.23 4 30
Endosulfan I ug/L 0.21.25 87 20-150900.22 4 30
Endosulfan II ug/L 0.23.25 93 20-150980.24 6 30
Endosulfan sulfate ug/L 0.24.25 97 20-1501030.25 6 30
Endrin ug/L 0.25.25 99 20-1501030.26 4 30
Endrin aldehyde ug/L 0.21.25 86 20-150880.22 2 30
gamma-BHC (Lindane)ug/L 0.21.25 85 20-150870.21 2 30
Heptachlor ug/L 0.19.25 77 20-150810.20 5 30
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2114005LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2114006
Heptachlor epoxide ug/L 0.22.25 90 20-150920.23 3 30
Methoxychlor ug/L 0.84J.74 114 20-1501210.90J 6 30
Decachlorobiphenyl (S)%81 20-13081
Tetrachloro-m-xylene (S)%81 20-13084
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
381588
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples:92358246001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2114636
Associated Lab Samples:92358246001
Matrix:Water
AnalyzedMDL
Cyanide ug/L ND 10.0 10/11/17 03:584.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2114637LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 113100 113 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2114638MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92358029012
2114639
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 85 80-12083 3 1010011.4 96.8 94.1
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2114640MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92357792012
2114641
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 111 80-120110 1 10100ND113112
REPORT OF LABORATORY ANALYSIS
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Page 25 of 30
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.L1
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
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[phone]
Page 26 of 30
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92358246
Wayne MSWLF Blanks
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92358246001 381490 382194EBEPA 3510 EPA 8081
92358246001 381897 382071EBEPA 3010A EPA 6010
92358246002 381897 382071FBEPA 3010A EPA 6010
92358246001 381405 381510EBEPA 3010A EPA 6020B
92358246002 381405 381510FBEPA 3010A EPA 6020B
92358246001 381413 381461EBEPA 7470 EPA 7470
92358246002 381413 381461FBEPA 7470 EPA 7470
92358246001 382904EBEPA 8260
92358246002 382904FBEPA 8260
92358246003 382904TBEPA 8260
92358246001 381588EBSM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
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Page 27 of 30
Page 28 of 30
Page 29 of 30
Page 30 of 30
#=CL#
October 20, 2017
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92358258
92358258
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
68 Shipwash Dr.
Garner, NC 27529
Wayne SW-BYMW2
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on October 06, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 1 of 16
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92358258
Wayne SW-BYMW2
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
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Page 2 of 16
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92358258
Wayne SW-BYMW2
Lab ID Sample ID Matrix Date Collected Date Received
92358258001 SW-BYMW2 Water 10/05/17 11:35 10/06/17 09:51
REPORT OF LABORATORY ANALYSIS
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Page 3 of 16
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92358258
Wayne SW-BYMW2
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92358258001 SW-BYMW2 EPA 8260 51 PASI-CGAW
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358258
Wayne SW-BYMW2
Sample:SW-BYMW2 Lab ID:92358258001 Collected:10/05/17 11:35 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/19/17 00:23 67-64-110010.0 1
Acrylonitrile ND ug/L 10/19/17 00:23 107-13-12001.9 1
Benzene ND ug/L 10/19/17 00:23 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/19/17 00:23 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/19/17 00:23 75-27-41.0 0.18 1
Bromoform ND ug/L 10/19/17 00:23 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/19/17 00:23 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/19/17 00:23 78-93-31000.96 1
Carbon disulfide ND ug/L 10/19/17 00:23 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/19/17 00:23 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/19/17 00:23 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/19/17 00:23 75-00-310.0 0.54 1
Chloroform ND ug/L 10/19/17 00:23 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/19/17 00:23 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/19/17 00:23 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/19/17 00:23 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/19/17 00:23 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/19/17 00:23 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/19/17 00:23 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 10/19/17 00:23 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/19/17 00:23 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/19/17 00:23 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/19/17 00:23 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/19/17 00:23 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/19/17 00:23 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/19/17 00:23 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/19/17 00:23 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 10/19/17 00:23 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 10/19/17 00:23 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/19/17 00:23 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/19/17 00:23 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/19/17 00:23 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/19/17 00:23 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/19/17 00:23 108-10-11000.33 1
Styrene ND ug/L 10/19/17 00:23 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/19/17 00:23 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/19/17 00:23 79-34-5 L23.0 0.40 1
Tetrachloroethene ND ug/L 10/19/17 00:23 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 10/19/17 00:23 109-99-910.0 3.1 1
Toluene ND ug/L 10/19/17 00:23 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/19/17 00:23 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/19/17 00:23 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/19/17 00:23 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/19/17 00:23 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/19/17 00:23 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/19/17 00:23 108-05-450.0 0.35 1
REPORT OF LABORATORY ANALYSIS
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Page 5 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358258
Wayne SW-BYMW2
Sample:SW-BYMW2 Lab ID:92358258001 Collected:10/05/17 11:35 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Vinyl chloride ND ug/L 10/19/17 00:23 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/19/17 00:23 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)102 %10/19/17 00:23 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %10/19/17 00:23 17060-07-070-130 1
Toluene-d8 (S)100 %10/19/17 00:23 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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Page 6 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358258
Wayne SW-BYMW2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
382978
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92358258001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2122612
Associated Lab Samples:92358258001
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 10/18/17 23:510.33
1,1,1-Trichloroethane ug/L ND 1.0 10/18/17 23:510.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 10/18/17 23:510.40
1,1,2-Trichloroethane ug/L ND 1.0 10/18/17 23:510.29
1,1-Dichloroethane ug/L ND 5.0 10/18/17 23:510.32
1,1-Dichloroethene ug/L ND 5.0 10/18/17 23:510.56
1,2,3-Trichloropropane ug/L ND 1.0 10/18/17 23:510.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 10/18/17 23:512.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 10/18/17 23:510.27
1,2-Dichlorobenzene ug/L ND 5.0 10/18/17 23:510.30
1,2-Dichloroethane ug/L ND 1.0 10/18/17 23:510.24
1,2-Dichloropropane ug/L ND 1.0 10/18/17 23:510.27
1,4-Dichlorobenzene ug/L ND 1.0 10/18/17 23:510.33
2-Butanone (MEK)ug/L ND 100 10/18/17 23:510.96
2-Hexanone ug/L ND 50.0 10/18/17 23:510.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 10/18/17 23:510.33
Acetone ug/L ND 100 10/18/17 23:5110.0
Acrylonitrile ug/L ND 200 10/18/17 23:511.9
Benzene ug/L ND 1.0 10/18/17 23:510.25
Bromochloromethane ug/L ND 3.0 10/18/17 23:510.17
Bromodichloromethane ug/L ND 1.0 10/18/17 23:510.18
Bromoform ug/L ND 3.0 10/18/17 23:510.26
Bromomethane ug/L ND 10.0 10/18/17 23:510.29
Carbon disulfide ug/L ND 100 10/18/17 23:511.2
Carbon tetrachloride ug/L ND 1.0 10/18/17 23:510.25
Chlorobenzene ug/L ND 3.0 10/18/17 23:510.23
Chloroethane ug/L ND 10.0 10/18/17 23:510.54
Chloroform ug/L 0.42J 5.0 10/18/17 23:510.14
Chloromethane ug/L ND 1.0 10/18/17 23:510.11
cis-1,2-Dichloroethene ug/L ND 5.0 10/18/17 23:510.19
cis-1,3-Dichloropropene ug/L ND 1.0 10/18/17 23:510.13
Dibromochloromethane ug/L ND 3.0 10/18/17 23:510.21
Dibromomethane ug/L ND 10.0 10/18/17 23:510.21
Ethylbenzene ug/L ND 1.0 10/18/17 23:510.30
Iodomethane ug/L ND 10.0 10/18/17 23:510.32
Methylene Chloride ug/L ND 1.0 10/18/17 23:510.97
Styrene ug/L ND 1.0 10/18/17 23:510.26
Tetrachloroethene ug/L ND 1.0 10/18/17 23:510.46
Tetrahydrofuran ug/L ND 10.0 10/18/17 23:513.1
Toluene ug/L ND 1.0 10/18/17 23:510.26
trans-1,2-Dichloroethene ug/L ND 5.0 10/18/17 23:510.49
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/20/2017 02:30 PM
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Page 7 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358258
Wayne SW-BYMW2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2122612
Associated Lab Samples:92358258001
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 10/18/17 23:510.26
trans-1,4-Dichloro-2-butene ug/L ND 100 10/18/17 23:511.0
Trichloroethene ug/L ND 1.0 10/18/17 23:510.47
Trichlorofluoromethane ug/L ND 1.0 10/18/17 23:510.20
Vinyl acetate ug/L ND 50.0 10/18/17 23:510.35
Vinyl chloride ug/L ND 1.0 10/18/17 23:510.62
Xylene (Total)ug/L ND 5.0 10/18/17 23:510.66
1,2-Dichloroethane-d4 (S)%99 70-130 10/18/17 23:51
4-Bromofluorobenzene (S)%104 70-130 10/18/17 23:51
Toluene-d8 (S)%101 70-130 10/18/17 23:51
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2122613LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 44.650 89 80-125
1,1,1-Trichloroethane ug/L 51.050 102 71-129
1,1,2,2-Tetrachloroethane ug/L 38.8 L2507879-124
1,1,2-Trichloroethane ug/L 47.850 96 85-125
1,1-Dichloroethane ug/L 50.150 100 73-126
1,1-Dichloroethene ug/L 55.250 110 66-135
1,2,3-Trichloropropane ug/L 39.450 79 75-130
1,2-Dibromo-3-chloropropane ug/L 35.450 71 71-133
1,2-Dibromoethane (EDB)ug/L 43.150 86 83-124
1,2-Dichlorobenzene ug/L 43.750 87 80-133
1,2-Dichloroethane ug/L 48.150 96 67-128
1,2-Dichloropropane ug/L 49.850 100 75-132
1,4-Dichlorobenzene ug/L 43.850 88 78-130
2-Butanone (MEK)ug/L 71.4J100 71 61-144
2-Hexanone ug/L 69.2100 69 68-143
4-Methyl-2-pentanone (MIBK)ug/L 84.4J100 84 72-135
Acetone ug/L 75.4J100 75 48-146
Acrylonitrile ug/L 199J250 79 40-160
Benzene ug/L 48.250 96 80-125
Bromochloromethane ug/L 50.150 100 71-125
Bromodichloromethane ug/L 49.150 98 78-124
Bromoform ug/L 41.050 82 71-128
Bromomethane ug/L 51.250 102 40-160
Carbon disulfide ug/L 55.9J50 112 50-160
Carbon tetrachloride ug/L 52.850 106 69-131
Chlorobenzene ug/L 44.450 89 81-122
Chloroethane ug/L 52.550 105 39-148
Chloroform ug/L 48.050 96 73-127
Chloromethane ug/L 46.350 93 44-146
cis-1,2-Dichloroethene ug/L 50.450 101 74-124
REPORT OF LABORATORY ANALYSIS
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Page 8 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358258
Wayne SW-BYMW2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2122613LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,3-Dichloropropene ug/L 49.250 98 72-132
Dibromochloromethane ug/L 44.550 89 78-125
Dibromomethane ug/L 48.550 97 82-120
Ethylbenzene ug/L 44.650 89 79-121
Iodomethane ug/L 98.6100 99 39-154
Methylene Chloride ug/L 53.350 107 64-133
Styrene ug/L 45.150 90 84-126
Tetrachloroethene ug/L 45.750 91 78-122
Tetrahydrofuran ug/L 378500 76 69-148
Toluene ug/L 49.350 99 80-121
trans-1,2-Dichloroethene ug/L 51.850 104 71-127
trans-1,3-Dichloropropene ug/L 47.150 94 69-141
trans-1,4-Dichloro-2-butene ug/L 26.4J50 53 40-160
Trichloroethene ug/L 51.350 103 78-122
Trichlorofluoromethane ug/L 50.250 100 53-137
Vinyl acetate ug/L 92.3100 92 40-160
Vinyl chloride ug/L 55.250 110 58-137
Xylene (Total)ug/L 133150 89 81-126
1,2-Dichloroethane-d4 (S)%93 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%102 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2122615MATRIX SPIKE SAMPLE:
MSSpike
Result
92359468008
1,1,1,2-Tetrachloroethane ug/L 19.720 98 70-130ND
1,1,1-Trichloroethane ug/L 22.620 113 70-130ND
1,1,2,2-Tetrachloroethane ug/L 18.420 92 70-130ND
1,1,2-Trichloroethane ug/L 21.120 105 70-130ND
1,1-Dichloroethane ug/L 22.520 112 70-130ND
1,1-Dichloroethene ug/L 24.220 121 70-166ND
1,2,3-Trichloropropane ug/L 18.920 95 70-130ND
1,2-Dibromo-3-chloropropane ug/L 16.120 81 70-130ND
1,2-Dibromoethane (EDB)ug/L 19.920 100 70-130ND
1,2-Dichlorobenzene ug/L 18.820 94 70-130ND
1,2-Dichloroethane ug/L 21.020 105 70-130ND
1,2-Dichloropropane ug/L 21.920 109 70-130ND
1,4-Dichlorobenzene ug/L 19.320 97 70-130ND
2-Butanone (MEK)ug/L 38.7J40 97 70-130ND
2-Hexanone ug/L 35.1J40 88 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 39.6J40 99 70-130ND
Acetone ug/L 37.5J40 94 70-130ND
Acrylonitrile ug/L 98.5J100 99 70-130ND
Benzene ug/L 21.820 109 70-148ND
Bromochloromethane ug/L 22.320 111 70-130ND
REPORT OF LABORATORY ANALYSIS
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Page 9 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358258
Wayne SW-BYMW2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2122615MATRIX SPIKE SAMPLE:
MSSpike
Result
92359468008
Bromodichloromethane ug/L 20.620 103 70-130ND
Bromoform ug/L 18.020 90 70-130ND
Bromomethane ug/L 19.720 98 70-130ND
Carbon disulfide ug/L 24.4J20 122 70-130ND
Carbon tetrachloride ug/L 22.720 113 70-130ND
Chlorobenzene ug/L 20.020 100 70-146ND
Chloroethane ug/L 23.120 116 70-130ND
Chloroform ug/L 20.820 104 70-130ND
Chloromethane ug/L 19.320 97 70-130ND
cis-1,2-Dichloroethene ug/L 22.620 113 70-130ND
cis-1,3-Dichloropropene ug/L 20.620 103 70-130ND
Dibromochloromethane ug/L 19.120 96 70-130ND
Dibromomethane ug/L 20.920 104 70-130ND
Ethylbenzene ug/L 20.120 101 70-130ND
Iodomethane ug/L 22.4 M1405670-130ND
Methylene Chloride ug/L 15.620 78 70-130ND
Styrene ug/L 20.020 100 70-130ND
Tetrachloroethene ug/L 20.720 103 70-130ND
Tetrahydrofuran ug/L 192200 96 70-130ND
Toluene ug/L 21.520 108 70-155ND
trans-1,2-Dichloroethene ug/L 22.820 114 70-130ND
trans-1,3-Dichloropropene ug/L 20.120 100 70-130ND
trans-1,4-Dichloro-2-butene ug/L 9.8J M1204970-130ND
Trichloroethene ug/L 22.220 111 69-151ND
Trichlorofluoromethane ug/L 22.520 112 70-130ND
Vinyl acetate ug/L 41.4J40 103 70-130ND
Vinyl chloride ug/L 23.420 117 70-130ND
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%104 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92359468007
2122614SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/20/2017 02:30 PM
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Page 10 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358258
Wayne SW-BYMW2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92359468007
2122614SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L 0.49J 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%101 1100
4-Bromofluorobenzene (S)%103 2101
Toluene-d8 (S)%100 0100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/20/2017 02:30 PM
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Page 11 of 16
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92358258
Wayne SW-BYMW2
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.L2
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/20/2017 02:30 PM
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Page 12 of 16
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92358258
Wayne SW-BYMW2
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92358258001 382978SW-BYMW2 EPA 8260
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/20/2017 02:30 PM
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Page 13 of 16
Page 14 of 16
Page 15 of 16
Page 16 of 16
#=CL#
October 25, 2017
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92358054
92358054
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
68 Shipwash Dr.
Garner, NC 27529
WAYNE SWs
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory between October 05,
2017 and October 06, 2017. The results relate only to the samples included in this report. Results
reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's
Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 1 of 29
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92358054
WAYNE SWs
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 2 of 29
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92358054
WAYNE SWs
Lab ID Sample ID Matrix Date Collected Date Received
92358054001 SW-6 Water 10/04/17 15:10 10/05/17 08:10
92358054002 SW-1 Water 10/05/17 16:55 10/06/17 09:51
REPORT OF LABORATORY ANALYSIS
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Page 3 of 29
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92358054
WAYNE SWs
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92358054001 SW-6 EPA 6010 14 PASI-ADS
EPA 8260 51 PASI-CZDO
92358054002 SW-1 EPA 6010 14 PASI-ADS
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CZDO
REPORT OF LABORATORY ANALYSIS
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Page 4 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358054
WAYNE SWs
Sample:SW-6 Lab ID:92358054001 Collected:10/04/17 15:10 Received:10/05/17 08:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 10/14/17 19:06 7440-36-010/11/17 17:406.0 3.9 1
Arsenic 5.5J ug/L 10/14/17 19:06 7440-38-210/11/17 17:4010.0 5.0 1
Barium 73.8J ug/L 10/14/17 19:06 7440-39-310/11/17 17:401002.5 1
Beryllium ND ug/L 10/14/17 19:06 7440-41-710/11/17 17:401.0 0.50 1
Cadmium ND ug/L 10/14/17 19:06 7440-43-910/11/17 17:401.0 0.50 1
Chromium ND ug/L 10/14/17 19:06 7440-47-310/11/17 17:4010.0 2.5 1
Cobalt ND ug/L 10/14/17 19:06 7440-48-410/11/17 17:4010.0 2.5 1
Copper ND ug/L 10/14/17 19:06 7440-50-810/11/17 17:4010.0 2.5 1
Lead 3.8J ug/L 10/14/17 19:06 7439-92-110/11/17 17:4010.0 2.5 1
Nickel ND ug/L 10/14/17 19:06 7440-02-010/11/17 17:4050.0 2.5 1
Selenium ND ug/L 10/14/17 19:06 7782-49-210/11/17 17:4010.0 5.0 1
Silver ND ug/L 10/14/17 19:06 7440-22-410/11/17 17:4010.0 2.5 1
Vanadium 5.2J ug/L 10/14/17 19:06 7440-62-210/11/17 17:4025.0 2.5 1
Zinc 6.3J ug/L 10/14/17 19:06 7440-66-610/11/17 17:4010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 14.7J ug/L 10/17/17 20:48 67-64-110010.0 1
Acrylonitrile ND ug/L 10/17/17 20:48 107-13-12001.9 1
Benzene ND ug/L 10/17/17 20:48 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/17/17 20:48 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/17/17 20:48 75-27-41.0 0.18 1
Bromoform ND ug/L 10/17/17 20:48 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/17/17 20:48 74-83-910.0 0.29 1
2-Butanone (MEK)1.8J ug/L 10/17/17 20:48 78-93-31000.96 1
Carbon disulfide ND ug/L 10/17/17 20:48 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/17/17 20:48 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/17/17 20:48 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/17/17 20:48 75-00-310.0 0.54 1
Chloroform ND ug/L 10/17/17 20:48 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/17/17 20:48 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/17/17 20:48 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/17/17 20:48 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/17/17 20:48 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/17/17 20:48 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/17/17 20:48 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 10/17/17 20:48 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/17/17 20:48 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/17/17 20:48 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/17/17 20:48 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/17/17 20:48 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/17/17 20:48 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/17/17 20:48 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/17/17 20:48 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 10/17/17 20:48 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 10/17/17 20:48 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/17/17 20:48 100-41-41.0 0.30 1
REPORT OF LABORATORY ANALYSIS
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Page 5 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358054
WAYNE SWs
Sample:SW-6 Lab ID:92358054001 Collected:10/04/17 15:10 Received:10/05/17 08:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
2-Hexanone ND ug/L 10/17/17 20:48 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/17/17 20:48 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/17/17 20:48 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/17/17 20:48 108-10-11000.33 1
Styrene ND ug/L 10/17/17 20:48 100-42-5 L21.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/17/17 20:48 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/17/17 20:48 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/17/17 20:48 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 10/17/17 20:48 109-99-910.0 3.1 1
Toluene 0.45J ug/L 10/17/17 20:48 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/17/17 20:48 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/17/17 20:48 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/17/17 20:48 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/17/17 20:48 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/17/17 20:48 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/17/17 20:48 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/17/17 20:48 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/17/17 20:48 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)92 %10/17/17 20:48 460-00-470-130 1
1,2-Dichloroethane-d4 (S)94 %10/17/17 20:48 17060-07-070-130 1
Toluene-d8 (S)109 %10/17/17 20:48 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
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Huntersville, NC 28078
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Page 6 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358054
WAYNE SWs
Sample:SW-1 Lab ID:92358054002 Collected:10/05/17 16:55 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 10/14/17 19:31 7440-36-010/11/17 17:406.0 3.9 1
Arsenic ND ug/L 10/14/17 19:31 7440-38-210/11/17 17:4010.0 5.0 1
Barium 11.8J ug/L 10/14/17 19:31 7440-39-310/11/17 17:401002.5 1
Beryllium ND ug/L 10/14/17 19:31 7440-41-710/11/17 17:401.0 0.50 1
Cadmium 0.82J ug/L 10/14/17 19:31 7440-43-910/11/17 17:401.0 0.50 1
Chromium 5.6J ug/L 10/14/17 19:31 7440-47-310/11/17 17:4010.0 2.5 1
Cobalt ND ug/L 10/14/17 19:31 7440-48-410/11/17 17:4010.0 2.5 1
Copper 2.5J ug/L 10/14/17 19:31 7440-50-810/11/17 17:4010.0 2.5 1
Lead ND ug/L 10/14/17 19:31 7439-92-110/11/17 17:4010.0 2.5 1
Nickel ND ug/L 10/14/17 19:31 7440-02-010/11/17 17:4050.0 2.5 1
Selenium ND ug/L 10/14/17 19:31 7782-49-210/11/17 17:4010.0 5.0 1
Silver ND ug/L 10/14/17 19:31 7440-22-410/11/17 17:4010.0 2.5 1
Vanadium 6.8J ug/L 10/14/17 19:31 7440-62-210/11/17 17:4025.0 2.5 1
Zinc 10.6 ug/L 10/14/17 19:31 7440-66-610/11/17 17:4010.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 10/24/17 14:37 7440-28-010/09/17 08:555.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/18/17 12:39 67-64-110010.0 1
Acrylonitrile ND ug/L 10/18/17 12:39 107-13-12001.9 1
Benzene ND ug/L 10/18/17 12:39 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/18/17 12:39 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/18/17 12:39 75-27-41.0 0.18 1
Bromoform ND ug/L 10/18/17 12:39 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/18/17 12:39 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/18/17 12:39 78-93-31000.96 1
Carbon disulfide ND ug/L 10/18/17 12:39 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/18/17 12:39 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/18/17 12:39 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/18/17 12:39 75-00-310.0 0.54 1
Chloroform ND ug/L 10/18/17 12:39 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/18/17 12:39 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/18/17 12:39 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/18/17 12:39 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/18/17 12:39 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/18/17 12:39 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/18/17 12:39 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 10/18/17 12:39 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/18/17 12:39 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/18/17 12:39 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/18/17 12:39 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/18/17 12:39 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/18/17 12:39 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/18/17 12:39 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/18/17 12:39 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
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Page 7 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92358054
WAYNE SWs
Sample:SW-1 Lab ID:92358054002 Collected:10/05/17 16:55 Received:10/06/17 09:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 10/18/17 12:39 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 10/18/17 12:39 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/18/17 12:39 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/18/17 12:39 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/18/17 12:39 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/18/17 12:39 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/18/17 12:39 108-10-11000.33 1
Styrene ND ug/L 10/18/17 12:39 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/18/17 12:39 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/18/17 12:39 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/18/17 12:39 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 10/18/17 12:39 109-99-910.0 3.1 1
Toluene ND ug/L 10/18/17 12:39 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/18/17 12:39 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/18/17 12:39 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/18/17 12:39 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/18/17 12:39 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/18/17 12:39 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/18/17 12:39 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/18/17 12:39 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/18/17 12:39 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %10/18/17 12:39 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %10/18/17 12:39 17060-07-070-130 1
Toluene-d8 (S)109 %10/18/17 12:39 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358054
WAYNE SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
381897
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples:92358054001, 92358054002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2116269
Associated Lab Samples:92358054001, 92358054002
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 5.0 10/14/17 18:253.9
Arsenic ug/L ND 10.0 10/14/17 18:255.0
Barium ug/L ND 5.0 10/14/17 18:252.5
Beryllium ug/L ND 1.0 10/14/17 18:250.50
Cadmium ug/L ND 1.0 10/14/17 18:250.50
Chromium ug/L ND 5.0 10/14/17 18:252.5
Cobalt ug/L ND 5.0 10/14/17 18:252.5
Copper ug/L ND 5.0 10/14/17 18:252.5
Lead ug/L ND 5.0 10/14/17 18:252.5
Nickel ug/L ND 5.0 10/14/17 18:252.5
Selenium ug/L ND 10.0 10/14/17 18:255.0
Silver ug/L ND 5.0 10/14/17 18:252.5
Vanadium ug/L ND 5.0 10/14/17 18:252.5
Zinc ug/L ND 10.0 10/14/17 18:255.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2116270LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 531500 106 80-120
Arsenic ug/L 521500 104 80-120
Barium ug/L 526500 105 80-120
Beryllium ug/L 519500 104 80-120
Cadmium ug/L 528500 106 80-120
Chromium ug/L 525500 105 80-120
Cobalt ug/L 539500 108 80-120
Copper ug/L 547500 109 80-120
Lead ug/L 532500 106 80-120
Nickel ug/L 523500 105 80-120
Selenium ug/L 540500 108 80-120
Silver ug/L 267250 107 80-120
Vanadium ug/L 520500 104 80-120
Zinc ug/L 530500 106 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2116271MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92358008010
2116272
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 108 75-125104 3 20500ND538521
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358054
WAYNE SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2116271MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92358008010
2116272
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic ug/L 500 104 75-125102 2 20500ND524512
Barium ug/L 500 106 75-125103 3 20500ND531514
Beryllium ug/L 500 105 75-125102 3 20500ND525511
Cadmium ug/L 500 106 75-125103 3 20500ND532515
Chromium ug/L 500 104 75-125102 3 20500ND522508
Cobalt ug/L 500 107 75-125104 3 20500ND537520
Copper ug/L 500 110 75-125107 3 20500ND549534
Lead ug/L 500 105 75-125103 3 20500ND527513
Nickel ug/L 500 104 75-125101 3 20500ND521504
Selenium ug/L 500 108 75-125105 3 20500ND542526
Silver ug/L 250 107 75-125104 3 20250ND267259
Vanadium ug/L 500 105 75-125102 3 20500ND525510
Zinc ug/L 500 106 75-125103 3 20500ND535518
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358054
WAYNE SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
381406
EPA 3010A
EPA 6020B
6020 MET
Associated Lab Samples:92358054002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2113684
Associated Lab Samples:92358054002
Matrix:Water
AnalyzedMDL
Thallium ug/L ND 0.10 10/24/17 13:530.020
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2113685LABORATORY CONTROL SAMPLE:
LCSSpike
Thallium ug/L 102100 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2113686MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92358257001
2113687
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Thallium ug/L 100 103 75-125101 2 201000.043J 103 101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358054
WAYNE SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
381403
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92358054001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2113668
Associated Lab Samples:92358054001
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 10/17/17 14:460.33
1,1,1-Trichloroethane ug/L ND 1.0 10/17/17 14:460.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 10/17/17 14:460.40
1,1,2-Trichloroethane ug/L ND 1.0 10/17/17 14:460.29
1,1-Dichloroethane ug/L ND 5.0 10/17/17 14:460.32
1,1-Dichloroethene ug/L ND 5.0 10/17/17 14:460.56
1,2,3-Trichloropropane ug/L ND 1.0 10/17/17 14:460.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 10/17/17 14:462.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 10/17/17 14:460.27
1,2-Dichlorobenzene ug/L ND 5.0 10/17/17 14:460.30
1,2-Dichloroethane ug/L ND 1.0 10/17/17 14:460.24
1,2-Dichloropropane ug/L ND 1.0 10/17/17 14:460.27
1,4-Dichlorobenzene ug/L ND 1.0 10/17/17 14:460.33
2-Butanone (MEK)ug/L ND 100 10/17/17 14:460.96
2-Hexanone ug/L ND 50.0 10/17/17 14:460.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 10/17/17 14:460.33
Acetone ug/L ND 100 10/17/17 14:4610.0
Acrylonitrile ug/L ND 200 10/17/17 14:461.9
Benzene ug/L ND 1.0 10/17/17 14:460.25
Bromochloromethane ug/L ND 3.0 10/17/17 14:460.17
Bromodichloromethane ug/L ND 1.0 10/17/17 14:460.18
Bromoform ug/L ND 3.0 10/17/17 14:460.26
Bromomethane ug/L ND 10.0 10/17/17 14:460.29
Carbon disulfide ug/L ND 100 10/17/17 14:461.2
Carbon tetrachloride ug/L ND 1.0 10/17/17 14:460.25
Chlorobenzene ug/L ND 3.0 10/17/17 14:460.23
Chloroethane ug/L ND 10.0 10/17/17 14:460.54
Chloroform ug/L ND 5.0 10/17/17 14:460.14
Chloromethane ug/L ND 1.0 10/17/17 14:460.11
cis-1,2-Dichloroethene ug/L ND 5.0 10/17/17 14:460.19
cis-1,3-Dichloropropene ug/L ND 1.0 10/17/17 14:460.13
Dibromochloromethane ug/L ND 3.0 10/17/17 14:460.21
Dibromomethane ug/L ND 10.0 10/17/17 14:460.21
Ethylbenzene ug/L ND 1.0 10/17/17 14:460.30
Iodomethane ug/L ND 10.0 10/17/17 14:460.32
Methylene Chloride ug/L ND 1.0 10/17/17 14:460.97
Styrene ug/L ND 1.0 10/17/17 14:460.26
Tetrachloroethene ug/L ND 1.0 10/17/17 14:460.46
Tetrahydrofuran ug/L ND 10.0 10/17/17 14:463.1
Toluene ug/L ND 1.0 10/17/17 14:460.26
trans-1,2-Dichloroethene ug/L ND 5.0 10/17/17 14:460.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358054
WAYNE SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2113668
Associated Lab Samples:92358054001
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 10/17/17 14:460.26
trans-1,4-Dichloro-2-butene ug/L ND 100 10/17/17 14:461.0
Trichloroethene ug/L ND 1.0 10/17/17 14:460.47
Trichlorofluoromethane ug/L ND 1.0 10/17/17 14:460.20
Vinyl acetate ug/L ND 50.0 10/17/17 14:460.35
Vinyl chloride ug/L ND 1.0 10/17/17 14:460.62
Xylene (Total)ug/L ND 5.0 10/17/17 14:460.66
1,2-Dichloroethane-d4 (S)%86 70-130 10/17/17 14:46
4-Bromofluorobenzene (S)%94 70-130 10/17/17 14:46
Toluene-d8 (S)%105 70-130 10/17/17 14:46
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2113669LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 44.350 89 80-125
1,1,1-Trichloroethane ug/L 48.450 97 71-129
1,1,2,2-Tetrachloroethane ug/L 45.550 91 79-124
1,1,2-Trichloroethane ug/L 47.050 94 85-125
1,1-Dichloroethane ug/L 48.350 97 73-126
1,1-Dichloroethene ug/L 44.950 90 66-135
1,2,3-Trichloropropane ug/L 45.650 91 75-130
1,2-Dibromo-3-chloropropane ug/L 50.150 100 71-133
1,2-Dibromoethane (EDB)ug/L 48.950 98 83-124
1,2-Dichlorobenzene ug/L 43.050 86 80-133
1,2-Dichloroethane ug/L 44.050 88 67-128
1,2-Dichloropropane ug/L 50.550 101 75-132
1,4-Dichlorobenzene ug/L 41.350 83 78-130
2-Butanone (MEK)ug/L 100100 100 61-144
2-Hexanone ug/L 91.8100 92 68-143
4-Methyl-2-pentanone (MIBK)ug/L 89.4J100 89 72-135
Acetone ug/L 92.9J100 93 48-146
Acrylonitrile ug/L 247250 99 40-160
Benzene ug/L 49.850 100 80-125
Bromochloromethane ug/L 48.550 97 71-125
Bromodichloromethane ug/L 45.850 92 78-124
Bromoform ug/L 43.550 87 71-128
Bromomethane ug/L 44.850 90 40-160
Carbon disulfide ug/L 46.8J50 94 50-160
Carbon tetrachloride ug/L 45.850 92 69-131
Chlorobenzene ug/L 43.250 86 81-122
Chloroethane ug/L 43.750 87 39-148
Chloroform ug/L 46.950 94 73-127
Chloromethane ug/L 35.150 70 44-146
cis-1,2-Dichloroethene ug/L 49.450 99 74-124
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358054
WAYNE SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2113669LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,3-Dichloropropene ug/L 48.850 98 72-132
Dibromochloromethane ug/L 46.150 92 78-125
Dibromomethane ug/L 45.650 91 82-120
Ethylbenzene ug/L 42.150 84 79-121
Iodomethane ug/L 72.2100 72 39-154
Methylene Chloride ug/L 49.950 100 64-133
Styrene ug/L 40.2 L2508084-126
Tetrachloroethene ug/L 41.750 83 78-122
Tetrahydrofuran ug/L 494500 99 69-148
Toluene ug/L 45.050 90 80-121
trans-1,2-Dichloroethene ug/L 47.650 95 71-127
trans-1,3-Dichloropropene ug/L 45.450 91 69-141
trans-1,4-Dichloro-2-butene ug/L 33.5J50 67 40-160
Trichloroethene ug/L 49.350 99 78-122
Trichlorofluoromethane ug/L 38.850 78 53-137
Vinyl acetate ug/L 99.5100 99 40-160
Vinyl chloride ug/L 46.250 92 58-137
Xylene (Total)ug/L 124150 83 81-126
1,2-Dichloroethane-d4 (S)%88 70-130
4-Bromofluorobenzene (S)%94 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2113670MATRIX SPIKE SAMPLE:
MSSpike
Result
92357792014
1,1,1,2-Tetrachloroethane ug/L 20.220 101 70-130ND
1,1,1-Trichloroethane ug/L 24.420 122 70-130ND
1,1,2,2-Tetrachloroethane ug/L 18.320 91 70-130ND
1,1,2-Trichloroethane ug/L 19.120 95 70-130ND
1,1-Dichloroethane ug/L 23.020 115 70-130ND
1,1-Dichloroethene ug/L 24.120 121 70-166ND
1,2,3-Trichloropropane ug/L 18.120 90 70-130ND
1,2-Dibromo-3-chloropropane ug/L 15.420 77 70-130ND
1,2-Dibromoethane (EDB)ug/L 18.220 91 70-130ND
1,2-Dichlorobenzene ug/L 19.520 97 70-130ND
1,2-Dichloroethane ug/L 19.820 99 70-130ND
1,2-Dichloropropane ug/L 21.820 109 70-130ND
1,4-Dichlorobenzene ug/L 19.120 95 70-130ND
2-Butanone (MEK)ug/L 53.4J M14013470-130ND
2-Hexanone ug/L 50.740 127 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 34.9J40 87 70-130ND
Acetone ug/L 68.7J M14017270-130ND
Acrylonitrile ug/L 104J100 104 70-130ND
Benzene ug/L 22.820 112 70-1480.36J
Bromochloromethane ug/L 20.720 104 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358054
WAYNE SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2113670MATRIX SPIKE SAMPLE:
MSSpike
Result
92357792014
Bromodichloromethane ug/L 20.020 100 70-130ND
Bromoform ug/L 12.9 M1206470-130ND
Bromomethane ug/L 18.820 94 70-130ND
Carbon disulfide ug/L 22.9J20 115 70-130ND
Carbon tetrachloride ug/L 23.120 116 70-130ND
Chlorobenzene ug/L 21.020 105 70-146ND
Chloroethane ug/L 20.920 105 70-130ND
Chloroform ug/L 22.120 111 70-130ND
Chloromethane ug/L 23.520 118 70-130ND
cis-1,2-Dichloroethene ug/L 22.820 114 70-130ND
cis-1,3-Dichloropropene ug/L 18.320 92 70-130ND
Dibromochloromethane ug/L 15.920 79 70-130ND
Dibromomethane ug/L 19.720 98 70-130ND
Ethylbenzene ug/L 21.220 106 70-130ND
Iodomethane ug/L 37.640 94 70-130ND
Methylene Chloride ug/L 21.620 108 70-130ND
Styrene ug/L 18.820 94 70-130ND
Tetrachloroethene ug/L 19.820 99 70-130ND
Tetrahydrofuran ug/L 240200 120 70-130ND
Toluene ug/L 21.820 109 70-155ND
trans-1,2-Dichloroethene ug/L 23.320 116 70-130ND
trans-1,3-Dichloropropene ug/L 16.120 80 70-130ND
trans-1,4-Dichloro-2-butene ug/L 13.3J M1206770-130ND
Trichloroethene ug/L 23.420 117 69-151ND
Trichlorofluoromethane ug/L 20.320 102 70-130ND
Vinyl acetate ug/L 28.7J40 72 70-130ND
Vinyl chloride ug/L 25.920 129 70-130ND
1,2-Dichloroethane-d4 (S)%93 70-130
4-Bromofluorobenzene (S)%96 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92357792015
2113671SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 15 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358054
WAYNE SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92357792015
2113671SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L 0.26J 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%99 1189
4-Bromofluorobenzene (S)%93 396
Toluene-d8 (S)%110 2108
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358054
WAYNE SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
382868
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92358054002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2121696
Associated Lab Samples:92358054002
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 10/18/17 03:250.33
1,1,1-Trichloroethane ug/L ND 1.0 10/18/17 03:250.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 10/18/17 03:250.40
1,1,2-Trichloroethane ug/L ND 1.0 10/18/17 03:250.29
1,1-Dichloroethane ug/L ND 5.0 10/18/17 03:250.32
1,1-Dichloroethene ug/L ND 5.0 10/18/17 03:250.56
1,2,3-Trichloropropane ug/L ND 1.0 10/18/17 03:250.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 10/18/17 03:252.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 10/18/17 03:250.27
1,2-Dichlorobenzene ug/L ND 5.0 10/18/17 03:250.30
1,2-Dichloroethane ug/L ND 1.0 10/18/17 03:250.24
1,2-Dichloropropane ug/L ND 1.0 10/18/17 03:250.27
1,4-Dichlorobenzene ug/L ND 1.0 10/18/17 03:250.33
2-Butanone (MEK)ug/L ND 100 10/18/17 03:250.96
2-Hexanone ug/L ND 50.0 10/18/17 03:250.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 10/18/17 03:250.33
Acetone ug/L ND 100 10/18/17 03:2510.0
Acrylonitrile ug/L ND 200 10/18/17 03:251.9
Benzene ug/L ND 1.0 10/18/17 03:250.25
Bromochloromethane ug/L ND 3.0 10/18/17 03:250.17
Bromodichloromethane ug/L ND 1.0 10/18/17 03:250.18
Bromoform ug/L ND 3.0 10/18/17 03:250.26
Bromomethane ug/L ND 10.0 10/18/17 03:250.29
Carbon disulfide ug/L ND 100 10/18/17 03:251.2
Carbon tetrachloride ug/L ND 1.0 10/18/17 03:250.25
Chlorobenzene ug/L ND 3.0 10/18/17 03:250.23
Chloroethane ug/L ND 10.0 10/18/17 03:250.54
Chloroform ug/L 0.23J 5.0 10/18/17 03:250.14
Chloromethane ug/L ND 1.0 10/18/17 03:250.11
cis-1,2-Dichloroethene ug/L ND 5.0 10/18/17 03:250.19
cis-1,3-Dichloropropene ug/L ND 1.0 10/18/17 03:250.13
Dibromochloromethane ug/L ND 3.0 10/18/17 03:250.21
Dibromomethane ug/L ND 10.0 10/18/17 03:250.21
Ethylbenzene ug/L ND 1.0 10/18/17 03:250.30
Iodomethane ug/L ND 10.0 10/18/17 03:250.32
Methylene Chloride ug/L ND 1.0 10/18/17 03:250.97
Styrene ug/L ND 1.0 10/18/17 03:250.26
Tetrachloroethene ug/L ND 1.0 10/18/17 03:250.46
Tetrahydrofuran ug/L ND 10.0 10/18/17 03:253.1
Toluene ug/L ND 1.0 10/18/17 03:250.26
trans-1,2-Dichloroethene ug/L ND 5.0 10/18/17 03:250.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358054
WAYNE SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2121696
Associated Lab Samples:92358054002
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 10/18/17 03:250.26
trans-1,4-Dichloro-2-butene ug/L ND 100 10/18/17 03:251.0
Trichloroethene ug/L ND 1.0 10/18/17 03:250.47
Trichlorofluoromethane ug/L ND 1.0 10/18/17 03:250.20
Vinyl acetate ug/L ND 50.0 10/18/17 03:250.35
Vinyl chloride ug/L ND 1.0 10/18/17 03:250.62
Xylene (Total)ug/L ND 5.0 10/18/17 03:250.66
1,2-Dichloroethane-d4 (S)%92 70-130 10/18/17 03:25
4-Bromofluorobenzene (S)%94 70-130 10/18/17 03:25
Toluene-d8 (S)%106 70-130 10/18/17 03:25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2121697LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 47.150 94 80-125
1,1,1-Trichloroethane ug/L 51.250 102 71-129
1,1,2,2-Tetrachloroethane ug/L 46.050 92 79-124
1,1,2-Trichloroethane ug/L 48.750 97 85-125
1,1-Dichloroethane ug/L 51.050 102 73-126
1,1-Dichloroethene ug/L 46.850 94 66-135
1,2,3-Trichloropropane ug/L 47.550 95 75-130
1,2-Dibromo-3-chloropropane ug/L 50.050 100 71-133
1,2-Dibromoethane (EDB)ug/L 50.650 101 83-124
1,2-Dichlorobenzene ug/L 42.150 84 80-133
1,2-Dichloroethane ug/L 45.050 90 67-128
1,2-Dichloropropane ug/L 50.550 101 75-132
1,4-Dichlorobenzene ug/L 40.850 82 78-130
2-Butanone (MEK)ug/L 105100 105 61-144
2-Hexanone ug/L 98.3100 98 68-143
4-Methyl-2-pentanone (MIBK)ug/L 94.5J100 95 72-135
Acetone ug/L 99.1J100 99 48-146
Acrylonitrile ug/L 253250 101 40-160
Benzene ug/L 50.350 101 80-125
Bromochloromethane ug/L 48.750 97 71-125
Bromodichloromethane ug/L 47.550 95 78-124
Bromoform ug/L 46.050 92 71-128
Bromomethane ug/L 43.350 87 40-160
Carbon disulfide ug/L 47.0J50 94 50-160
Carbon tetrachloride ug/L 46.550 93 69-131
Chlorobenzene ug/L 45.250 90 81-122
Chloroethane ug/L 47.250 94 39-148
Chloroform ug/L 47.550 95 73-127
Chloromethane ug/L 37.150 74 44-146
cis-1,2-Dichloroethene ug/L 51.250 102 74-124
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358054
WAYNE SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2121697LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,3-Dichloropropene ug/L 49.950 100 72-132
Dibromochloromethane ug/L 46.750 93 78-125
Dibromomethane ug/L 47.050 94 82-120
Ethylbenzene ug/L 44.350 89 79-121
Iodomethane ug/L 79.8100 80 39-154
Methylene Chloride ug/L 49.450 99 64-133
Styrene ug/L 44.750 89 84-126
Tetrachloroethene ug/L 45.550 91 78-122
Tetrahydrofuran ug/L 531500 106 69-148
Toluene ug/L 46.350 93 80-121
trans-1,2-Dichloroethene ug/L 49.450 99 71-127
trans-1,3-Dichloropropene ug/L 47.550 95 69-141
trans-1,4-Dichloro-2-butene ug/L 31.8J50 64 40-160
Trichloroethene ug/L 52.350 105 78-122
Trichlorofluoromethane ug/L 43.250 86 53-137
Vinyl acetate ug/L 90.0100 90 40-160
Vinyl chloride ug/L 46.750 93 58-137
Xylene (Total)ug/L 130150 86 81-126
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2122397MATRIX SPIKE SAMPLE:
MSSpike
Result
92358149001
1,1,1,2-Tetrachloroethane ug/L 17.220 86 70-130ND
1,1,1-Trichloroethane ug/L 23.420 117 70-130ND
1,1,2,2-Tetrachloroethane ug/L 18.720 94 70-130ND
1,1,2-Trichloroethane ug/L 20.420 102 70-130ND
1,1-Dichloroethane ug/L 22.520 113 70-130ND
1,1-Dichloroethene ug/L 23.320 117 70-166ND
1,2,3-Trichloropropane ug/L 18.420 92 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.220 96 70-130ND
1,2-Dibromoethane (EDB)ug/L 20.020 100 70-130ND
1,2-Dichlorobenzene ug/L 17.520 88 70-130ND
1,2-Dichloroethane ug/L 20.620 103 70-130ND
1,2-Dichloropropane ug/L 21.420 107 70-130ND
1,4-Dichlorobenzene ug/L 16.820 84 70-130ND
2-Butanone (MEK)ug/L 40.4J40 101 70-130ND
2-Hexanone ug/L 36.7J40 92 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 36.5J40 91 70-130ND
Acetone ug/L 37.9J40 95 70-130ND
Acrylonitrile ug/L 105J100 105 70-130ND
Benzene ug/L 21.320 107 70-148ND
Bromochloromethane ug/L 21.020 105 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358054
WAYNE SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2122397MATRIX SPIKE SAMPLE:
MSSpike
Result
92358149001
Bromodichloromethane ug/L 20.220 101 70-130ND
Bromoform ug/L 17.420 87 70-130ND
Bromomethane ug/L 16.820 84 70-130ND
Carbon disulfide ug/L 23.7J20 118 70-130ND
Carbon tetrachloride ug/L 22.420 112 70-130ND
Chlorobenzene ug/L 19.320 97 70-146ND
Chloroethane ug/L 23.320 116 70-130ND
Chloroform ug/L 21.020 105 70-130ND
Chloromethane ug/L 21.120 105 70-130ND
cis-1,2-Dichloroethene ug/L 22.920 115 70-130ND
cis-1,3-Dichloropropene ug/L 19.720 98 70-130ND
Dibromochloromethane ug/L 18.620 93 70-130ND
Dibromomethane ug/L 21.520 107 70-130ND
Ethylbenzene ug/L 19.420 97 70-130ND
Iodomethane ug/L 32.940 82 70-130ND
Methylene Chloride ug/L 21.620 108 70-130ND
Styrene ug/L 17.120 85 70-130ND
Tetrachloroethene ug/L 18.920 94 70-130ND
Tetrahydrofuran ug/L 208200 104 70-130ND
Toluene ug/L 20.620 103 70-155ND
trans-1,2-Dichloroethene ug/L 23.120 115 70-130ND
trans-1,3-Dichloropropene ug/L 18.920 95 70-130ND
trans-1,4-Dichloro-2-butene ug/L 12.2J M1206170-130ND
Trichloroethene ug/L 21.720 109 69-151ND
Trichlorofluoromethane ug/L 23.320 117 70-130ND
Vinyl acetate ug/L 35.9J40 90 70-130ND
Vinyl chloride ug/L 24.320 122 70-130ND
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%102 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92358008005
2122396SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92358054
WAYNE SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92358008005
2122396SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L 11.2J 3013.7J
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%98 097
4-Bromofluorobenzene (S)%95 095
Toluene-d8 (S)%109 4114
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 29
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92358054
WAYNE SWs
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.L2
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92358054
WAYNE SWs
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92358054001 381897 382071SW-6 EPA 3010A EPA 6010
92358054002 381897 382071SW-1 EPA 3010A EPA 6010
92358054002 381406 381512SW-1 EPA 3010A EPA 6020B
92358054001 381403SW-6 EPA 8260
92358054002 382868SW-1 EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2017 12:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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Appendix B
Field Sampling Parameter Data Sheet(s)