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NCG030412_MONITORING INFO_20181218
STORMWATER DIVISION CODING SHEET NCG PERMITS PERMIT NO. /V A,LI 0 DOC TYPE ❑HIS RICAL FILE L,FdONITORING REPORTS DOC DATE ❑ o` 0/ YYYYMMDD a ENVIRONMEIVTAI SERVICES, INC. ASSESSMENT & REMEDIAL SERVICES DIVISION December 4, 2018 REcFIVED Ms. Amanda McAllister Mann -Hummel - Allen Plant DEC 1 8 2D18 2900 Northwest Blvd. CENTRAL FILES Gastonia, NC 28052 0VVR S-ECTION RE: Stormwater Sampling Results - North Carolina General Permit No. NCG030000 Certificate of Coverage Number NCG030412 2nd Semi -Annual 2018 Storm Water Sampling Mann -Hummel — (Former Wix Filtration) Allen Plant 2900 Northwest Blvd., Gastonia, NC 28052 ARM Project No. 12-4003-14 Ms. McAllister: In accordance with the North Carolina Department of Environment, and Natural Resources (NC DENR) stormwater discharge permit, ARM collected the second semi-annual stormwater samples at the referenced facility on November 12, 2018. The samples consisted of one stormwater grab sample from the facility stormwater outfall location, and the sample was collected during the rain event in Laboratories clean, pre -preserved, laboratory -prepared sample bottles. The sample was then delivered to Prism, Inc., which is a North Carolina -accredited analytical laboratory. The sample was analyzed for oil and grease, total suspended solids (TSS), copper, lead, zinc, and total toxic organic compounds (volatile and semi -volatile organic compounds) via EPA Methods 624 and 625, per the permit requirements. The attached Table 1 provides a summary of the analytical results (also attached), total flow, and total rainfall. All parameters were below the permitted range benchmarks in the sample, except for the exceedances of copper and zinc. The pH was performed in the field upon sample collection; was within the recommended holding time of 15 minutes; and showed results within the permitted range benchmark value of 6.0-9.0. The Stormwater Discharge Monitoring Report (SDO), which also shows the analytical results for the outfalls are attached. During sample collection, qualitative monitoring of certain parameters was performed and the Qualitative Monitoring Report for each outfall is attached. ARM appreciates the opportunity to provide environmental services to Mann -Hummel. As required by the stormwater permit, please sign the second page of the SDO and then forward the report to the NC DENR-Central Files at the Division of Energy, Mineral, and Land Resources at the address shown on page 2 of the Stormwater Discharge Monitoring Report. Please call us at 704-369-0621, if you have any questions. Sincerely, AR Environmental Services, Inc. im cCorkle Project Manager cc: Central Files, DENR-Division of Energy, Mineral, and Land Resources / www.armenv.com 11164 DOWNS ROAD, PINEVILLE, NC 28134 / (704) 369-0621 fax (704)369-0623 Table I. Stormwater Sampling Results Stormwater Parameters Units Outfall1 Benchmark Oil And Grease mg/L ND 15 pH S.U. 6.0-field Within 6.0-9.0 Total Suspended Solids mg/L 38 100 Copper mg/L 0.058 0.010 Lead mglL 0.0083 0.075 Zinc mg/L 1.3 0.126 Total Toxic I Organics mg/L ND; See analytical 1 Total Rainfall inches 0.38 - Storm Duration minutes 480 - Total Flow ri gallons/ minute 5.0 - ND = Not Detected mg/L = micrograms per liter (parts per million equivalent) s.u.= standard pH units Stormwater Discharge Monitoring Report for North Carolina Division of Energy, Mineral and Pnd Resources General Permit No. NCG030000 Date submitted i' CERTIFICATE OF COVERAGE NO. G03�L_i2� q ( FACILITY OUNT2N!M E AAµn- NL C`6 --z'— i► ¢r n__ _ PERSON COLLECVIN6G SAMPLES- , /1/t c&,6A ->42M LABORATORY i r. Lab Cert. # °�2— Comments on sample collection or analysis: Part A. Stormwater Benchmarks and Monitoring Results SAMPLE COLLECTION YEAR Z0 L SAMPLE PERIOD ❑ Jan -June my -Dec or ❑ Monthly'_ (month) DISCHARGING TO CLASS ❑ORW ❑HQW ❑Trout ❑PNA ❑Zero -flow ❑Water Supply ❑SA ❑Other PLEASE REMEMBER TO SIGN ON PAGES 2 AND/OR 3 4 ❑ No discharge this period?z Outfall No. Date Sample Collected (mo/dd/yr) 24-hour rainfall amount, Inches Total Suspended Solids PH, Standard units Total Copper Total Lead Total Zinc Non -Polar O&G/Total Total Petroleum Hydrocarbons Toxic Organicss Benchmarks _ 100 mg/L or 50 mg/L4 6.0 - 9.0 0.010 mg/L 0.075 mg/L 0.126 mg/L 15 mg/L 1 mg/L Parameter Code - 46529 C0530 00400 01119 010S3 01094 00SS2 78141 ��-- ' Monthly sampling (instead of semi-annual) must begin with the second consecutive benchmark exceedance for the same parameter at the same outfall. 2 For sampling periods with no discharge at any single outfall, you must still submit this discharge monitoring report with a checkmark here. 'The total precipitation must be recorded using data from an on -site rain gauge. Unattended sites may be eligible for a waiver of the rain gauge requirement. " See General Permit, Section B, Table 1 to identify the especially sensitive receiving water classifications where the more protective benchmark applies. 'Total Toxic Organics sampling is applicable only for those facilities which perform metal finishing operations, manufacture semiconductors, manufacture electronic crystals, or manufacture cathode ray tubes. For purposes of this permit the definition of Total Toxic Organics is that definition contained in the EPA Effluent Guidelines for the facility subject to the requirement to sample (for metal finishing use the definition as found in 40 CFR 433.11; for semiconductor manufacture use the definition as found in 40 CFR 469.12; for electronic crystal manufacture use the definition as found in 40 CFR 469.22; and for cathode ray tube manufacture use the definition found in 40 CFR 469.31). Permit Date: 11/1/2018-05/31/2021 SWU-245, last revised 11/1/2018 Page 1 of 3 Facilities that incorporate a solvent management plan into the Stormwater Pollution Prevention Plan may so certify, and the requirement for TTO monitoring may be waived. The solvent management plan shall include a list of the total toxic organic compounds used and the other elements listed in the General Permit. For those facilities electing to employ the TTO monitoring waiver, the discharger shall sign the following certification statement: "Based upon my inquiry of the person or persons directly responsible for managing compliance with the permit monitoring requirement for total toxic organics (TTO), I certify that to the best of my knowledge and belief, no dumping of concentrated toxic organics into the stormwater or areas which are exposed to rainfall or stormwater runoff has occurred since filing the last discharge monitoring report. I further certify that this facility is implementing the all the provisions of the solvent management plan included in the Stormwater Pollution Prevention Plan." Ram l ll.--c.a,-l_ Name (Print name) IWL MAI)A444r Title (Print title) J PkS lZ- 1i-18 Signature Date Note: Results must be reported in numerical format. Do not report Below Detection Limit, BDL, <PQL, Non -detect, ND, or other similar non -numerical format. When results are below the applicable limits, they must be reported in„the formats <XX mg/L", where XX is the numerical value of the detection limit, reporting limit, etc. in mg/L. Note: if you repot a sample value in excess of the benchmark, you must implement Tier 1, Tier 2, or Tier 3 responses. See General Permit text. Part B: Vehicle Maintenance Area Monitoring Results: only for facilities averaging > 55 gal of new oil per month. ❑ No discharge this period ?2 Outfall No. Date Sample Collected' (mo/dd/yr) 24-hour rainfall amount, Inches-' New Motor Oil or Hydraulic Oil Usage Non -Polar O&G/ Total Petroleum Hydrocarbons Total Suspended Solids Benchmarks - - - 15 mg/L 100 mg/L or 50 mg/O Parameter Code - 46529 NCOIL 00552 C0530 Footnotes from Part A also apply to Part B Note: If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 2, or Tier 3 responses, See General Permit text Permit Date: 1111/2018-05/31/2021 SWU-245, last revised 11/1/2018 Page 2 of 3 FOR PART A AND PART B MONITORING RESULTS: • A BENCHMARK EXCEEDANCE TRIGGERS TIER 1 REQUIREMENTS. SEE PERMIT PART II SECTION B. • 2 EXCEEDANCES IN A ROW FOR THE SAME PARAMETER AT THE SAME OUTFALL TRIGGER TIER 2 REQUIREMENTS. SEE PERMIT PART II SE ON B. • TIER 3: HAS YOUR FACILITY HAD 4 OR MORE BENCHMARK EXCEEDENCES ♦ R THE SAME PARAMETER AT ANY ONE OUTFALL? YES [� NO ❑ IF YES, HAVE YOU CONTACTED THE DEM�jRtREGIONAL OF ICE7 YES VO REGIONAL OFFICE CONTACT NAME: Sa nnc�` i�1.� az e_ Mail an original copy of this OMR, _ including off "No Discharge" reports, within 30 days of receipt of the tab results for at end of monitorina Period in the case oL" No Discharge" reports) to: Division of Water Quality Attn: DWQ Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED: "1 certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I pig-aiwa that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Permittee Permit Date: 11/1/2018-05/31/2021 12-11-is Date SWU-245, last revised 11/1/2018 Page 3 of 3 tnviranmenlal Quality Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance on filling nut thisform, please visir https://deq.ne.gov/about/divisions/energy-mineral-land-resources/ npdes-stonnwater-gps Permit No.: N/C!a /O /3/0 /0/0 /o / or Certificate of Coverage No.: NIC/GkD / `3io /It/ 1 /24 Facility Name: A ,ten-4yn..a_} — At er1 �'�.T �-�-„�t{�.�e'e4) Countv(,aS_4�, Phone No. Inspector'-' r!=_ I ft1_lv�Cl� C AC, ✓1 ✓ r ,1 _ f Date of Inspection: I i [ C1 t t Time of inspection: t-� D,�— Total Event Precipitation (inches): 0.3 b All permits require qualitative monitoring to be performed during a "measurable storm event." A "measurable storm event" is a storm event that results in an actual discharge from the permitted site outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter interval is representative for local storm events during the sampling period. and the permittee obtains approval from the local DEMLR Regional Office. By this signature, I certify that this report is accurate and complete to the best of my knowledge: ignature of Permittee or Designee) 1. Outfall Description: , Outfall No. DD I Structure (pipe, ditch, etc.): 2 t 0 Receiving Stream: Describe the indu trial activities that occur within the t tfall drainage area: t �� MlLr�l���v_C SV� ` C-11- C ..,nAtnf 4— �rs�tJ L. Page I of 2 SWU-232. Last modified 06YO11201S 2. Color: Describe the color of tie discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: 1`�. __ -; C1 3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): 4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: 1 3 4 5 5. Floating Solids: Choose the number which best describes the amount of floating solids in the stonmwater discharge, where I is no solids and 5 is the surface covered with floating solids: (y. 2 3 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy: 0 2 3 4 5 7. Is there any foam in the stormwater discharge? O Yes 4D No. 8. Is there an oil sheen in the stormwater discharge? OYes 9 No. 9. Is there evidence of erosion or deposition at the outfall? o Yes ® No. 10. Other Obvious Indicators of Stormwater Pollution: List and describe Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may he indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 SWU-242. Last modified 06i01l2018 iCIR-i ISM �7LABORATOAIES. WC. Full -Service Analytical & Environmental Solutions ARM Environmental - Charlotte Tim McCorkle 11164 Downs Rd. Pineville, NC 28134 INC Certification No. 402 Case Narrative INC Drinking Water Carl No. 37735 12/05/2018 SC Certification No, 99012 Project: Mans -Hummel Allen Plant (Gastonia, NC) Lab Submittal Date: 11/12/2018 Prism Work Order: 8110201 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: The pH was reported by the client. This is a Revised Report and supercedes the original laboratory report dated 11128/18. Lead result added at the client's request. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. Terri W. Cole Project Manager Data Qualifiers Key Reference: Kivu=rR� Reviewed By Terri W. Cole Project Manager CCV CCV result is above the control limits. Analyte not detected in the sample. No further action taken. D RPD value outside of the control limits. L Parameter reported with possible low bias. LCS recovery below the QC limit. L1 LCS recovery outside of the QC limits. LCSD recovery within the limits. No further action taken. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Pli 7041529.6364 - Toll Free Number: 1-8001529-6364 - Fax: 704l525.0409 Page 1 of 17 j c� .� ti Fall-Servico An¢lytical 8 Sample Receipt Summary JP R'I M Environmental Solutions 1210512018 �'uecn�saaea 1N Prism Work Order: 8110201 Client Sample ID Lab Sample ID Matrix DatelTime Sampled Date/Time Received 001 8110201-01 Water 11 /09/18 17:05 11 /12/18 11:50 Samples were received in good condition at 3.0 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704l529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 2 of 17 /,,PRISM Full -Service Analytical A I Environmental Solutions Z'71 AWe TOAIES, IWI ARM Environmental - Charlotte Attn: Tim McCorkle 11164 Downs Rd. Pineville, NC 28134 Field Data Project: Mans -Hummel Allen Plant (Gastonia, NC) Laboratory Report 12/05/2018 Prism Work Order: 8110201 Laboratory ID Client ID Field Parameter Result 8110201-01 001 pH 6.0 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529.6364 - Toll Free Number: 1-8001529.6364 - Fax: 7041525.0409 Page 3 of 17 PaFull-Service Analytical & �R'I S M I Envlronmentel Solutions ILIBORAIORIE6 IHG Laboratory Report 12/05/201 B ARM Environmental - Charlotte Attn: Tim McCorkle 11164 Downs Rd. Pineville, NC 28134 Project: Mans -Hummel Allen Plant (Gastonia, NC) Sample Matrix: Water Client Sample ID: 001 Prism Sample ID: 8110201-01 Prism Work Order: 8110201 Time Collected: 11/09/18 17:05 Time Submitted: 11/12/18 11:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters Oil & Grease (HEM) BRL mg/L 5.0 1.4 1 "1664B 11/21/18 8:20 SLS P81<0389 Total Suspended Solids 38 mglL 7.1 0.40 1 'SM2540 D 11/16/18 13:01 CBP PBK0310 Semivolatile Organic Compounds by GCIMS 1,2,4-Trichlorobenzene BRL ug/L 10 1.5 1 '625.1 11/16/18 2:57 JMV P81<0266 1,2-Dichlorobenzene BRL ug/L 10 1.4 1 `625.1 11116/18 2:57 JMV PSK0266 1,3-Dichlorobenzene BRL ug/L 10 1.3 1 `625.1 11/16/18 2:57 JMV P8K0266 1,4-Dichforobenzene BRL ug/L 10 1.4 1 - `625.1 11/16/18 2:57 JMV 1`81<0266 1-Methylnaphthalene BRL ug/L 10 2.1 1 '625.1 11/16/18 2:57 JMV PBK0266 2,4,6-Trichlorophenol BRL ug/L 10 1.8 1 '625.1 11116/18 2:57 JMV 1`61<0266 2,4-Dichlorophenol BRL ug/L 10 1.6 1 *625.1 11116/18 2:57 JMV PBK0266 2,4-Dimethylphenol BRL ug/L 10 2.1 1 *625.1 11116/18 2:57 JMV PBK0266 2,4-Dinitrophenol BRL ug/L 10 1.2 1 *625.1 11116/18 2:57 JMV PBK0266 2,4-Dinitrotoluene BRL ug/L 10 2.9 1 *625.1 11116118 2:57 JMV PBK0266 2,6-Dinitrotoluene BRL ug/L 10 2.9 1 `625.1 11/16/18 2:57 JMV 1`81<0266 2-Chloronaphthalene BRL ug/L 10 2.3 1 *625.1 11/16/18 2:57 JMV P81<0266 2-Chlorophenol BRL ug/L 10 1.1 1 625.1 11/16/16 2:57 JMV P8K0266 2-Methylnaphthalene BRL u91L 10 1.8 1 *625.1 11/16/18 2:57 JMV P8K0266 2-Nitrophenol BRL ug/L 10 1.4 1 *625.1 11/16/18 2:57 JMV P8K0266 3,3'-Dichlorobenzidine BRLCCV ug/L 10 2.8 1 '625.1 11/16/18 2:57 JMV P81<0266 3/4-Methyl phenol BRL ug/L 10 1.2 1 *625.1 11/16/18 2:57 JMV 1`81<0266 4,6-13initro-2-methyl phenol BRL ug/L 10 1.9 1 *625.1 11/16/18 2:57 JMV P81<0266 4-Bromophenyl phenyl ether BRL ug/L 10 3.2 1 *625.1 11/16/18 2:57 JMV P8K0266 4-Chloro-3-methylphenol BRL ug/L 10 2.3 1 *625.1 11/16/18 2:57 JMV P81<0266 4-Chloroaniline BRL ug/L 10 1.7 1 *625.1 11/16/18 2:57 JMV P81<0266 4-Chlorophenyl phenyl ether BRL ug/L 10 2.2 1 `625.1 11116/18 2:57 JMV PBK0266 4-Nitrophenol BRL ug/L 50 1,7 1 '625.1 11116/18 2:57 JMV PSK0266 Acenaphthene BRL ug/L 10 2.3 1 *625,1 11/16/18 2:57 JMV P811<0266 Acenaphthylene BRL ug/L 10 2.3 1 '625,1 11/16/18 2:57 JMV P81<0266 Anthracene BRL ug1L 10 3.2 1 "625.1 11/16/18 2:57 JMV P8K0266 Benzidine BRL ug/L 100 14 1 `625.1 11/16/18 2:57 JMV P8K0266 Benzo(a)anthracene BRL ug/L 10 3.1 1 '625.1 11/16/18 2:57 JMV P8K0266 Benzo(a)pyrene BRL ug/L 10 3.6 1 `625.1 11/16/18 2:57 JMV P8K0266 Benzo(b)fluoranthene BRL uglL 10 3.5 1 `625.1 11/16/18 2:57 JMV P81<0266 Benzo(g,hJ)perylene BRL uglL 10 3.5 1 `625.1 11/16/18 2:57 JMV P8K0266 Benzo(k)fluoranthene BRL ug/L 10 3.8 1 *625.1 11/16/18 2:57 JMV P8K0266 Benzoic Acid BRL ug/L 100 0.74 1 `625.1 11/16/18 2:57 JMV P8K0266 Benzyl alcohol BRL ug/L 10 1.6 1 '625.1 11/16/18 2 57 JMV P8K0266 bis(2-CInloroethoxy)methane BRL ug/L 10 1.8 1 *625.1 11/16/18 2:57 JMV P81<0266 Bis(2-Chloroethyl)ether BRL ug/L 10 1.6 1 *625.1 11/16/18 2:57 JMV P8K0266 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Spring brook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 7041529-6364 - Toll Free Number: l-6001529-6364- Fax: 70a1525-0409 Page 4 of17 Laboratory Report P'R.I M Full -Service Analytical S `7ueanvon�s Environmental al5plutiona Solutions 12/05l2018 ARM Environmental - Charlotte Project: Mans -Hummel Allen Plant Client Sample ID: 001 Attn: Tim McCorkle (Gastonia, NC) Prism Sample ID: 8110201-01 11164 Downs Rd. Prism Work Order: 8110201 Pineville, NC 28134 Sample Matrix: Water Time Collected: 11/09/18 17:05 Time Submitted: 11/12/18 11:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor DatefTime ID Bis(2-chloroisopropyl)ether BRL ug1L 10 1.7 1 '625.1 11/16/18 2:57 JMV P8K0266 Bis(2-Ethylhexyl)phthalate BRL ug/L 10 3.1 1 *625.1 11/16118 2:57 JMV P81<0266 Butyl benzyl phthalate BRL ug/L 10 2.6 1 '625.1 11/16/18 2:57 JMV P81<0266 Chrysene BRL ug1L 10 3.4 1 '625.1 11/16/18 2:57 JMV P81<0266 . Dibenzo(a,h)anthracene BRL ug/L 10 3.4 1 *625.1 11/16118 2:57 JMV P8K0266 Dibenzofuran BRL ug1L 10 2.3 1 '625.1 11/16/18 2:57 JMV P81<0266 Diethyl phthalate BRL ug1L 10 2.3 1 *625.1 11/16/18 2:57 JMV P81<0266 Dimethyl phthalate BRL ug1L 10 1.5 1 '625.1 11/16118 2:57 JMV P81<0266 Di-n-butyl phthalate BRL ug1L 10 3.4 1 *625.1 11/16/18 2:57 JMV P81<0266 Di-n-octyl phthaiate BRL ug1L 10 3.6 1 '625.1 11/16/18 2:57 JMV P81<0266 Fluoranthene BRL ug1L 10 3.5 1 'S25.1 11/16/18 2:57 JMV P81<0266 Fluorene BRL ug1L 10 2.8 1 'fi25.1 11/16/18 2:57 JMV P81<0266 Hexachlorobenzene BRL ug1L 10 2.5 1 'fi25.1 11/16/18 2:57 JMV P81<0266 Hexachlorobutadiene BRL ug1L 10 2.0 1 'fi25.1 11/16118 2:57 JMV P81<0266 Hexachlorocyclopentadiene BRL ug1L 10 1.6 1 '625.1 11/16118 2:57 JMV P81<0266 Hexachloroethane BRL ug1L 10 1.5 1 '625.1 11116/18 2:57 JMV P81<0266 Indeno(1,2,3-cd)pyrene BRL ug/L 10 3.1 1 *625.1 11116/18 2:57 JMV P8K0266 Isophorone BRL ug/L 10 2.1 1 '625.1 11/16118 2:57 JMV P8K0266 Naphthalene BRL ug/L 10 2.1 1 *625.1 11116/18 2:57 JMV P8K0266 Nitrobenzene BRL ug/L 10 1A 1 *625.1 11/16118 2:57 JMV P8K0266 N-Nitrosodimethylamine BRL ug/L 10 0.83 1 '625.1 11/16118 2:57 JMV P8K0266 N-Nitroso-di-n-propylamine BRL ug/L 10 2.0 1 '625.1 11116/18 2:57 JMV P8K0266 N-Nitrosodiphenylamine BRL ug1L 10 2.9 1 '625.1 11116118 2:57 JMV P81<0266 Pentachlorophenol BRL ug1L 10 2.1 1 '625.1 11/16118 2:57 JMV P8K0266 Phenanthrene BRL ug1L 10 3.2 1 '625.1 1 V16118 2:57 JMV P8K0266 Phenol BRL ug1L 10 0,48 1 '625.1 11/16/18 2:57 JMV P81<0266 Pyrene BRL ug1L 10 3.5 1 '625.1 11/16/18 2:57 JMV P8K0266 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 66 % 31-144 2-Fluorobiphenyl 85 % 49-118 2-Fluorophenol 49 % 22-84 Nitrobenzene-d5 77 % 43-123 Phenol-d5 34 % 10-63 Terphenyl-d14 92 % 49-151 Total Metals Copper 0.058 mg1L 0.010 0.0010 1 *200.7 11/16118 12:15 JAB P8K0269 Lead 0.0083 mg1L 0.0050 0.0010 1 *200.7 11/16118 12:15 JAB P8K0269 Zinc 1.3 mg1L 0.030 0.0013 1 *200.7 11/16118 12:15 JAB P8K0269 Volatile Organic Compounds by GC/MS 1,1,1-Trichloroethane BRL ug/L 5.0 0.061 1 624.1 11/20/18 21:57 KDM P8K0374 1,1,2,2-Tetrachloroethane BRL ug1L 5.0 0.036 1 624.1 11/20118 21:57 KDM P81<0374 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224.0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of17 1 Laboratory Report L..J�1 ., .I S n A EunviService Analytical BS 12/05/2018 r ' V I Environmental Solutions 7 ABOMTORIE$ INC ARM Environmental - Charlotte Project: Mans -Hummel Allen Plant Client Sample ID: 001 Attn: Tim McCorkle (Gastonia, NC) Prism Sample ID: 8110201-01 11164 Downs Rd. Prism Work Order: 8110201 Pineville, NC 28134 Sample Matrix: Water Time Collected: 11/09/18 17:05 Time Submitted: 11/12/18 11:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,1,2-Trichloroethane BRL ug1L 5.0 0.066 1 '624,1 11120/18 21:57 KDM P81<0374 1,1-Dichloroethane BRL ug/L 5.0 0.083 1 '624.1 11/20/18 21:57 KDM PSK0374 1,1-Dichloroethyiene BRL ug/L 50 0 083 1 '624 1 11/20/18 21:57 KDM PBK0374 1,2-Dichlorobenzene BRL ug/L 5.0 0.076 1 '624.1 11/20/18 21:57 KDM PBK0374 12-Dichloroethane BRL ug1L 5.0 0.066 1 '624.1 11/20/18 21:57 KDM PBK0374 1,2-Dichloropropane BRL ug1L 5.0 0,11 1 '624.1 11/20/18 21:57 KDM P8K0374 1,3-Dichlorobenzene BRL ug1L 5.0 0.054 1 '624,1 11/20/18 21:57 KDM P8K0374 1,4-Dichlorobenzene BRL ug1L 5.0 0.050 1 '624,1 11/20/18 21:57 KDM P8KG374 2-Chloroethyl Vinyl Ether BRL ug1L 10 0.37 1 *624.1 11/20/18 21:57 KDM P8K0374 Acrolein BRL ug1L 1c0 0.20 1 *624.1 11/20/18 21:57 KDM P8K0374 Acrylonitrile BRL ug1L 100 0.20 1 '624,1 11/20/18 21:57 KDM P8K0374 Benzene BRL ug1L 5.0 0.048 1 '624.1 11/20/18 21:57 KDM P8K0374 Bromodichloromethane BRL ug1L 5.0 0.062 1 '624.1 11/20/18 21:57 KDM 1`81<0374 Bromoform BRL ug1L 5.0 0.040 1 '624.1 11/20/18 21:57 KDM P81<0374 Bromomethane BRL ug1L 10 0.18 1 '624.1 11/20/18 21:57 KDM P8K0374 Carbon Tetrachloride BRL ug1L 5.0 0.11 1 '624.1 11/20/18 21:57 KDM P8K0374 Chlorobenzene BRL ug1L 5.0 0.062 1 '624.1 11/20/18 21:57 KDM P8K0374 Chloroethane BRL ug1L 10 0.22 1 '624.1 11/20118 21:57 KDM P81<0374 Chloroform BRL ug1L 5.0 0.076 1 *624.1 11/20118 21:57 KDM P8K0374 Chloromethane BRL ug/L 10 0,079 1 "624.1 11/20/18 21:57 KDM PBK0374 cis-1,3-Dichloroprcpylene BRL ug/L 5,0 0,079 1 '624.1 11/20/18 21:57 KDM PBK0374 Dibromochloromethane BRL ug/L 5,0 0.081 1 '624.1 11/20/18 21:57 KDM PBK0374 Ethylbenzene BRL ug/L 5.0 0.061 1 '624.1 11/20/18 21:57 KDM PBK0374 Methylene Chloride BRL ug/L 5.0 0.083 1 '624.1 11/20/18 21:57 KDM PSK0374 Tetrachloroethylene BRL ug1L 5.0 0.098 1 '624,1 11/20/18 21:57 KDM PBK0374 Toluene BRL ug1L 5.0 0.044 1 '624.1 11/20/18 21:57 KDM PBK0374 trans- 1,2-Dichloroethylene BRL ug1L 5.0 0.094 1 '624,1 11/20/18 21:57 KDM PBK0374 trans- 1,3-Dichloropropylene BRL ug111 5.0 c.070 1 '624.1 11/20/18 21:57 KDM P81<0374 Trichloroethylene BRL ug/L 5.0 0.078 1 '624.1 11/20118 21:57 KDM P81<0374 Trichlorofluoromethane BRL ug1L 10 0.062 1 '624.1 11/20118 21:57 KDM P8Ko374 Vinyl chloride BRL ug1L 10 0.097 1 '624.1 11120/18 21:57 KDM P81<0374 Surrogate Recovery Control Limits 4-Bromofluorobenzene 96 % 74-126 ❑ibromofluoromethane 95 % 75-127 Toluene-d8 89 % 74-122 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc, 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529.6364 - Toll Free Number: "001529-6364 - Fax: 7041626-0409 Page 6 of 17 Full -Service AnalyticalIsm I & Environmental Solutions ter*—:7� --TC�Ea--C� Level II QC Report 1215/18 ARM Environmental - Charlotte Attn: Tim McCorkle 11164 Downs Rd. Pineville, NC 28134 Project: Mans -Hummel Allen Plant (Gastonia, NC) Volatile Organic Compounds by GC/MS - Quality Control Prism Work Order: 8110201 Time Submitted: 11/12/2018 11:50:00AM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P8K0374 - 624 Blank (P81<0374-BLK1) 1,1,1-Trichloroethane BRL 5.0 uglL 1,1,2,2-Tetrachloroethane BRL 50 uglL 1,1,2-Trichloroethane BRL 5,0 ug1L 1,1-Dichloroethane BRL 50 uglL 1,1-Dichloroethylene BRL 5.0 ug1L 1,2-Dichlorobenzene BRL 5.0 ug1L 1,2-Dichloroethane BRL 5.0 ug1L 1,2-Dichloropropane BRL 5.0 ug1L 1,3-Dichlorobenzene BRL 5.0 ug1L 1,4-Dichlorobenzene BRL 5.0 ug1L 2-Chloroethyl Vinyl Ether BRL 10 ug1L Acroiein BRL 100 ug1L Acrylonit(le BRL 100 ug1L Benzene BRL 5.0 ug1L Bromodichloromethane BRL 5.0 uglL Bromoform BRL 5.0 uglL Bromomethane BRL 10 uglL Carbon Tetrachloride BRL 5.0 ug1L Chlorobenzene BRL 5.0 uglL Chloroethane BRL 10 uglL Chloroform BRL 5.0 uglL Chloromethane BRL 10 uglL cis-1,3-Dichloropropylene BRL 5.0 ug1L Dibromochloromethane BRL 5.0 ug1L Ethylbenzene BRL 5.0 uglL Methylene Chloride BRL 5.0 ug1L Tetrachloroethylene 8RL 5.0 uglL Toluene BRL 5.0 ug1L trans-1,2-Dichloroethylene BRL 5,0 ug1L trans-1,3-Dichloropropylene BRL 5.0 ug1L Trichloroethylene BRL 5.0 uglL Trichlorofluoromethane BRL 10 uglL Vinyl chloride BRL 10 uglL Surrogate: 4-8rornotluorobenzene 48.4 ug/L Surrogate: Drbromofluoromethane 49.8 ug/L Surrogate: To)uene-d8 43.5 ug/L 50.00 50.00 50.00 11/20/18 97 74-125 100 75-127 87 74-122 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704152M364 - Toll Free Number: t-800t529-6364 - Fax: 7041525-0409 Page 7 0€17 K,\ Level II QC Report inm�P;R S M Full -Service Analytical & 1215I18 Environmental Solutions 1(r . aurwsiea INC ARM Environmental - Charlotte Attn: Tim McCorkle 11164 Downs Rd. Pineville, NC 28134 Project: Mans -Hummel Allen Plant (Gastonia, NC) Volatile Organic Compounds by GClMIS - Quality Control Prism Work Order: 8110201 Time Submitted: 11/12/2018 11:50:00AM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P8K0374 - 624 LCS (P8K0374-BS1 ) Prepared & Analyzed: 11/20/18 1,1,1-Trichloroethane 20.2 5.0 ug1L 20.00 101 52-162 1,1,2,2-Tetrachloroethane 20.6 5.0 uglL 20.00 103 46-157 1,1,2-Trichloroethane 22.9 5.0 ug1L 20.00 115 52-150 1, 1 -Dichloroetha ne 20.6 5.0 uglL 20.00 103 59-155 1,1-Dichloroethylene 21.8 5.0 uglL 20.00 109 10-234 1,2-Dichlorobenzene 19.0 5.0 uglL 20.00 95 18-190 1,2-Dichloroethane 23.0 5.0 uglL 20.00 115 49-155 1,2-Dichloropropane 22.6 5.0 ug1L 20.00 113 10-210 1,3-Dichlorobenzene 18.1 5.0 ug1L 20.00 90 59-156 1,4-Dichlorobenzene 18.3 5.0 uglL 20.00 92 18-190 2-Chloroethyl Vinyl Ether 22.0 10 ug1L 20.00 110 10-305 Acrolein 81.4 100 ug1L 40.00 204 10-196 L1 Acrylonitrite 47,6 100 ug/L 40.00 119 60-134 Benzene 22.2 5.0 ug1L 20.00 ill 37-151 Bromodichlorc methane 23,1 5,0 ug1L 20.00 116 35-155 Bromoform 231 5.0 ug1L 20.00 116 45-169 Bromomethane 17.0 10 ug1L 20.00 85 10-242 Carbon Tetrachloride 20.5 5.0 ug1L 20.00 102 70-140 Chlorobenzene 19.4 5.0 ug1L 20.00 97 37-160 Chloroethane 24.6 10 ugtL 20.00 123 14-230 Chloroform 21.5 5.0 uglL 20.00 107 51-138 Chloromethane 26.9 10 ug1L 20.00 135 10-273 cis- 1,3- Dichloropropylene 22.2 5.0 uglL 20.00 ill 10-227 Dibromochloromethane 19.4 5.0 uglL 20,00 97 53-149 Ethylbenzene 19.9 5.0 ug1L 20.00 99 37-162 Methylene Chloride 23.0 5.0 uglL 20.00 115 10-221 Tetrachloroethylene 17.5 5.0 ug1L 20.00 88 64-148 Toluene 21.8 5.0 ug1L 20.00 109 47-150 trans-1,2-Dichloroethylene 22.3 5.0 uglL 20.00 112 54-156 trans-1,3-Dichloropropylene 25.2 5.0 uglL 20.00 126 17-183 Trichtoroethylene 22.2 5.0 ug1L 20.00 111 71-157 Trichlorofluoromethane 2&7 10 ug1L 20.00 143 17-181 Vinyl chloride 25,3 10 ug1L 20.00 127 10-251 Surrogate:4-Bromofluorobenzene 48.1 ug/L 50.00 96 74-126 Surrogate: Dibromofluoromethane 48.0 ug/L 50.00 96 75-127 Surrogate: Toluene -dB 44,4 ug/L 50.00 89 74-122 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toil Free Number: t-B001529-6364 - Fax: 7041625-0409 Page 8 ofl7 PL. 1 Full -Service Analytical 8 11 ,"PLR R M ( Environmental Solutions �'/t.wonAr IEs 1N Level 11 QC Report 12/5118 ARM Environmental - Charlotte Attn: Tim McCorkle 11164 Downs Rd. Pineville, NC 28134 Project: Mans -Hummel Allen Plant (Gastonia, NC) Volatile Organic Compounds by GCIMS - Quality Control Prism Work Order: 8110201 Time Submitted: 11/12/2018 11:50:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P8K0374 - 624 LCS Dup (1P8K0374-BSD1) Prepared & Analyzed: 11/20/18 1, 1, 1 -Trichloroethane 20.6 5.0 ug1L 20.00 103 52-162 2 20 1,1,2,2-Tetrachloroethane 21.0 5.0 uglL 20.00 105 46-157 2 20 1,1,2-Trichloroethane 23.9 5.0 uglL 20.00 119 52-150 4 20 1,1-Dichloroethane 20.6 5.0 uglL 20.00 103 59-155 0.1 20 1,1-Dichloroethylene 21.8 5.0 uglL 20.00 109 10-234 0.4 20 1,2-Dichlorobenzene 19.0 5.0 uglL 20.00 95 18.190 0.2 20 1,2-Dichloroethane 23.4 5.0 uglL 20.00 117 49-155 2 20 1,2-Dichloropropane 23.7 5.0 uglL 20.00 119 10-210 5 20 1,3-Dichlorobenzene 18.2 5.0 uglL 20.00 91 59-156 0.3 20 1,4-Dichlorobenzene 18.6 5.0 uglL 20.00 93 18-190 2 20 2-Chloroethyl Vinyl Ether 22.3 10 uglL 20.00 112 10-305 1 20 Acrolein 78.4 100 uglL 40.00 196 10-196 4 20 Acrylonitrile 47.8 100 uglL 40.00 120 60-134 0.5 20 Benzene 23.0 5.0 uglL 20.00 115 37-151 3 20 Bromodichloromethane 22.9 5.0 uglL 20.00 114 35-155 1 20 Bromoform 23.2 5.0 ug1L 20.00 116 45-169 0.1 20 Bromomethane 19.1 10 uglL 20.00 96 10-242 12 20 Carbon Tetrachloride 21.0 5.0 uglL 20.00 105 70-140 2 20 Chlorobenzene 19.6 5.0 ug1L 20.00 98 37-160 1 20 Chloroethane 25.1 10 ug1L 20.00 125 14-230 2 20 Chloroform 22.3 5.0 ug1L 20.00 112 51-138 4 20 Chloromethane 27.5 10 ug/L 20.00 138 10-273 2 20 cis- 1,3-D ichloropropylene 23.3 5.0 uglL 20.00 116 10-227 5 20 Dibromochloromethane 19.5 5.0 ug1L 20.00 97 53-149 0.2 20 Ethylbenzene 20.0 5.0 uglL 20.00 100 37-162 0.8 20 Methylene Chloride 23.4 5.0 uglL 20.00 117 10-221 2 20 Tetrachlaroethylene 17.3 5.0 uglL 20.00 87 64-148 1 20 Toluene 22.4 5.0 uglL 20.00 112 47-150 3 20 trans-1,2-Dichloroethylene 23.2 5.0 uglL 20.00 116 54-156 4 20 trans-1,3-Dichloropropytene 25.2 5.0 uglL 20.00 126 17-183 02 20 Trichloroethylene 22.7 5.0 ugtL 20.00 113 71-157 2 20 Trichtorofluoromethane 26.6 10 uglL 20.00 143 17-181 0.1 20 Vinyl chloride 25.5 10 ugtL 20.00 128 10-251 0.8 20 Surrogate:4-Bromofluorobenzene 49.2 ug1L 50.00 98 74-126 Surrogate: Dibromofluoromefhane 47.6 ug1L 50.00 95 75-127 Surrogate: Toluene-d8 45.2 ug/L 50.00 90 74-122 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1.800152M364 - Fax: 704t525-0409 Page 9 of 17 .-I\ Level II QC Report p I S n /� Funvi service Analytical 8 1215118 �vn � �/ � Environmental Solutions 1^%LA00RAlC%11ES 1N ARM Environmental - Charlotte Attn: Tim McCorkle 11164 Downs Rd. Pineville, NC 28134 Project: Mans -Hummel Allen Plant (Gastonia, NC) Semivolatile Organic Compounds by GClMS - Quality Control Prism Work Order: 8110201 Time Submitted: 11/12/2018 11:50WAM Reporting Spike Source %aREC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P8K0266 - 3510C MS Blank (P13KD266-BLK1) Prepared & Analyzed: 11/15/18 1,2,4-Trichlombenzene BRL 10 ug/L 1,2-Dichlorobenzene BRL 10 ug/L 1,3-Dichlorobenzene BRL 10 ug1L 1,4-Dichlorobenzene BRL 10 ug/L 1-Methyl naphthalene BRL 10 ug/L 2,4,6-Trichlorcphenol BRL 10 ug1L 2,4-Dichtorophenol BRL 10 ug/L 2,4-Dimethylphenol BRL 10 ug/L 2,4-Dinitrophenol BRL 10 ug/L 2,4-Dinitrotoluene BRL 10 ug/L 2,6-Dinitrotoluene BRL 10 ug/L 2-Chloronaphthatene BRL 10 ug/L 2-Chlorophenol BRL 10 ug/L 2-Methylnaphthalene BRL 10 ug/L 2-Nitrophenol BRL 10 ug/L 3,3'-Dichlorobenzidine BRL 10 ug/L 3/4-Methyl phenol BRL 10 ug/L 4,6-Dinitro-2-methylphenol BRL 10 ug/L 4-Bromophenyl phenyl ether BRL 10 ug/L 4-Ch loro-3-methyl phenol BRL 10 ug/L 4-Chloroaniline BRL 10 ug/L 4-Chlorophenyl phenyl ether BRL 10 ug/L 4-Nitrophenol BRL 50 uglL Acenaphthene BRL 10 ug1L Acenaphthylene BRL 10 ug/L Anthracene BRL 10 ug/L Benzidine BRL 100 ug/L Benzo(a)anthracene BRL 10 ug/L Benzo(a)pyrene BRL 10 ug/L Benzo(b)fluoranthene BRL 10 ug/L Benzo(g,h,i)perylene BRL 10 ug/L Benzo(k)fluoranthene BRL 10 ug/L Benzoic Acid BRL 100 ug/L Beryl alcohol BRL 10 ug/L bis(2-Ch loroethoxy) methane BRL 10 ug/L Bis(2-Chloroethyl)ether BRL 10 ug/L Bis(2-chloroisopropyl)ether BRL 10 ug/L Bis(2-Ethylhexyl)phthalate BRL 10 uglL Butyl benzyl phthalate BRL 10 ug/L Chrysene BRL 10 ug1L Dibenzo(a,h)anthracene BRL 10 ug/L Dibenzofuran BRL 10 ug1L Diethyl phthalate BRL 10 ug1L Dimethyl phthalate BRL 10 ug1L Di-n-butyl phthalate BRL 10 ug/L Di-n-octyl phthalate BRL 10 ug1L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 5pringbrook Road - P.O. Box 240643 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 17 ?' N P�+ I Full -Service Analytical & SIR I S M Environmental Solutions �' �1�UB0144TpUE81NG Level II QC Report 1215118 ARM Environmental - Charlotte Attn: Tim McCorkle 11164 Downs Rd. Pineville, NC 28134 Project: Mans -Hummel Allen Plant (Gastonia, NC) Semivoiatile Organic Compounds by GC1MS - Quality Control Prism Work Order: 8110201 Time Submitted: 11/12/2018 11:50:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P811<0266 - 351 OC MS Blank (PBK0266-BLK1) Prepared & Analyzed: 11/15/18 Fluoranthene BRL 10 ug/L Flucrene BRL 10 uglL Hexachlorobenzene BRL 10 uglL Hexachlorobutadiene BRL 10 ug/L Hexachlorocyclopentadiene BRL 10 ug/L Hexachloroethane BRL 10 uglL Indeno(1,2,3-cd)pyrene BRL 10 ug/L Isophorone BRL 10 ug/L Naphthalene BRL 10 ug/L Nitrobenzene BRL 10 ug/L N-Nitrosodimethylamine BRL 10 uglL N-Nitroso-di-n-propylemine BRL 10 uglL N-Nitrosodiphenylamine BRL 10 ug/L Pentachlorophenol BRL 10 uglL Phenanthrene BRL 10 uglL Phenol BRL 10 uglL Pyrene BRL 10 uglL Surrogate:2,4,6-Tribromophenol 122 ug/L 100.0 122 31-144 Surrogate:2-Fluorobiphenyl 58.3 ug/L 50.00 117 49-118 Surrogate:2-Fluorophenol 77.5 ug/L 100.0 78 22-84 Surrogate: Nitrobenzene-d5 55.8 ug/L 50.00 112 43-123 Surrogate: Phenol-d5 49.1 ug/L 100.0 49 1CL63 Surrogate: Terphenyl-d14 62.3 ug/L 50.00 125 49-151 LCS (P8K0266-BS1) Prepared &Analyzed: 11/15/18 1,2,4-Trichlorobenzene 373 10 uglL 50.00 75 44-142 1,2-Dichlorobenzene 39.1 10 uglL 50.00 78 32-129 1,3-Dichlorobenzene 37.1 10 ug1L 50.00 74 20-124 1,4-Dichlorobenzene 38A 10 ugtL 50.00 77 20-124 1-Methylnaphthalene 44.7 10 ug1L 50.00 89 40-135 2,4,6-Trichlorophenol 52.2 10 ug1L 50.00 104 37-144 2,4-Dichlorophenol 44.3 10 ug/L 50.00 89 39-135 2,4-Dimethylphenol 54,8 10 ug1L 50.00 110 32-119 2,4-Dinitrophenol 42.4 10 ug1L 50.00 85 10-191 2,4-Dinitrotoluene 55.9 10 ug/L 50.00 112 39-139 2,6-Dinitrotoluene 556 10 ug1L 50.00 ill 50-158 2-Chloronaphthalene 50.1 10 ug1L 50.00 100 60-118 2-Chlorophenol 46.7 10 uglL 50.00 93 23-134 2-Methylnaphthalene 42.2 10 ug1L 5C.00 84 18-121 2-Nitrophenol 42.7 10 uglL 50.00 85 29-182 3,3'-Dichlorobenzidine 66.7 10 uglL 50.00 133 10-262 3/4-Methyl phenol 36.9 10 ug/L 50.00 74 76-107 L 4,6-Dinitro-2-methylphenol 51.3 10 ugiL 50.00 103 10-181 4-Bromophenyl phenyl ether 56.1 10 ug/L 50.00 112 53-127 4-Chloro-3-methylphenol 43.0 10 ug/L 50.00 86 22-147 4-Chloroaniline 50.6 10 ug/L 50.00 101 44-163 4-Chlorophenyl phenyl ether 52.7 10 ug/L 50.00 105 25-158 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.Q. Box 240543 - Charlotte, NC 28224.0543 Phone: 704/529.6364 - Toll Free Number: 1-8001529-6364 - Fax: 704152"409 Page 11 of 17 Level II QC Report L� i �.� Full -Service Analytical & 12/5118 PRISMPEnvironmental Solutions '7ieaoa�muEs iac ARM Environmental - Charlotte Attn: Tim McCorkle 11164 Downs Rd. Pineville, NC 28134 Project: Mans -Hummel Allen Plant (Gastonia, NC) Semivolatile Organic Compounds by GC1MS - Quality Control Prism Work Order: 8110201 Time Submitted: 11/12/2018 11:50:OOAM Reporting Spike Source %REC RPO Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P8K0266 - 351 OC MS LCS (P8K0288-BS1) Prepared & Analyzed: 11/15/18 4-Nitrophenol 24.8 50 ug1L 50.00 50 10-132 Acenaphthene 51.9 10 ug1L 50.00 104 47-145 Acenaphthylene 53.6 10 uglL 50.00 107 33-145 Anthracene 61.2 10 ug1L 50.00 122 27-133 Benzidine 28.0 100 ug1L 50.00 56 15-150 Benzo(a)anthracene 58.6 10 ug1L 50.00 117 33-143 Benzc(a)pyrene 58.5 10 uglL 50.00 117 17-163 Benzo(b)fluoranthene 58.6 10 ug1L 50.00 117 24-159 Benzo(g,h,i)perylene 58.8 10 ug1L 50.00 118 10-219 Benzo(k)fluoranthene 55.9 10 uglL 50.00 112 11-162 Benzoic Acid 3.28 100 ug1L 50.00 7 10-125 L Benzyl alcohol 46.7 10 uglL 50.00 93 16-107 bis(2-Chloroethoxy)methane 50.2 10 ug/L 50.00 100 33-184 Bis(2-Chloroethyl)ether 43.4 10 uglL 50.00 87 12-158 Bis(2-chloroisopropyl)ether 49.4 10 uglL 50,00 99 36-166 Bis(2- Ethyl hexyl)phtha late 60.3 10 uglL 50.00 121 10-158 Butyl benzyl phthalate 59.3 10 uglL 50.00 119 10-152 Chrysene 59.3 10 uglL 50.00 119 17-168 Dibenzo(a,h)anthracene 41.2 10 uglL 50.00 82 10.227 Oibenzofuran 52.8 10 uglL 50.00 106 39-114 Diethyl phthalate 55.4 10 uglL 50.00 111 10-114 Dimethyl phthalate 54.5 10 uglL 50.00 109 10-112 Di-n-butyl phthalate 59.2 10 uglL 50,00 118 10-118 Di-n-octyl phthalate 62.2 10 ug/L 50.00 124 10-146 Fluoranthene 57.2 10 ug/L 50.00 114 26.137 Fluorene 55.2 10 ug& 50,00 110 59-121 Hexachlorobenzene 54.2 10 uglL 50,00 108 10-152 Hexachlorobutadiene 37.1 10 uglL 50.00 74 24-116 Hexachlorocyclopentadiene 42.8 10 ug1L 50.00 86 32-117 Hexachloroethane 36.3 10 uglL 50.00 73 40-113 Indeno(1,2,3-cd)pyrene 64.9 10 ug/L 50.00 130 10-171 Isophorone 50.9 10 uglL 50.00 102 21-196 Naphthalene 42.0 10 uglL 50,00 84 21-133 Nitrobenzene 45.6 10 uglL 50,00 91 35-180 N-Nitrosodimethyiamine 32.3 10 ug1L 50,00 65 10-119 N-Nitroso-di-n-propylamine 46.8 10 ug1L 50.00 94 10-230 N-Nltrosodipheny%mine 66.8 10 ugtL 50,00 134 69-152 Pentachlorophenol 54.8 10 ugtL 50,00 110 14-176 Phenanthrene 57.4 10 ugtL 50.00 115 54-120 Phenol 24,8 10 ug1L 50.00 50 10-112 Pyrene 58.6 10 ugtL 50.00 117 52-115 L Surrogate: 2,4,6-Trrbromophenof 107 uglL 100.0 107 31-144 Surrogate:2-Fluoroblphenyl 49.2 ug/L 50.00 96 49-118 Surrogate:2-Fluorophenol 65.0 uglL ?00.0 65 22-84 Surrogate: Nitrobenzene-d5 42.7 ug/L 50.00 85 43-123 Surrogate: Phenol-d5 41.8 ug& 100,0 42 10-63 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1.8001529-6364 - Fax: 7041525-0409 Page 12 ot17 Full-Samice Analytical 6 /P R ' �/' Environmental Solutions uDORATORIE& ING' Level II QC Report 12I5118 ARM Environmental - Charlotte Attn: Tim McCorkle 11164 Downs Rd. Pineville, NC 28134 Project: Mans -Hummel Allen Plant (Gastonia, NC) Semivolatife Organic Compounds by GCIMS - Quality Control Prism Work Order: 8110201 Time Submitted: 11/12/2018 11:50:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P8K0266 - 351 OC MS LCS (P8K0266-BSI) Prepared & Analyzed: 11/15/18 Surrogate: Terphenyf-04 53.9 ug/L 50.00 108 49-151 LCS Dup (PSK0266-BSDI) Prepared & Analyzed: 1 I/15118 1,2,4-Trichlorobenzene 36.5 10 ug/L 50.00 73 44-142 2 20 1,2-Dichlorobenzene 38.8 10 ug/L 50.00 78 32-129 0.8 20 1,3-Dichlorobenzene 36.9 10 ug/L 50.00 74 20-124 0.5 20 1,4-Dichlorobenzene 37.3 10 ug/L 50.00 75 20-124 3 20 1-Methylnaphthalene 44.6 10 ug/L 50.00 89 40-135 0.2 20 2,4,6-Trichlorophenol 46.5 10 ug/L 50.00 93 37-144 12 20 2,4-Dichlorophenol 41.2 10 ug/L 50.00 82 39-135 7 20 2,4-Dimethylphenol 53.9 10 ug/L 50,00 108 32-119 2 20 2,4-Dinitrophenol 28.7 10 ug/L 50.00 57 10-191 39 20 D 2,4-Dinitrotoluene 55.9 10 ug/L 50.00 112 39-139 0 20 2,6-Dinitrotoluene 56.3 10 ug1L 50.00 113 50-158 1 20 2-Chloronaphthalene 50.3 10 ug/L 50.00 101 60-118 0,5 20 2-Chlcrophenol 43.8 10 ug1L 50,00 88 23-134 6 20 2-Methylnaphthalene 42.0 10 ug1L 50.00 84 18-121 0.4 20 2-Nitrophenol 41.2 10 ug/L 50.00 82 29-182 4 20 3,3'-Dichlorobenzidine 68.1 10 ug/L 50.00 136 10-262 2 20 3/4-Methyl phenol 37.2 10 ug/L 50.00 74 76-107 0.8 20 L 4,6-Dinitro-2-methyl phenol 39.8 10 ug]L 50.00 80 10-181 25 20 D 4-13romophenyl phenyl ether 56,8 10 ug/L 50.00 114 53-127 1 20 4-Chloro-3-methylphenol 43.7 10 ug/L 50.00 87 22-147 2 20 4-Chloroaniline 51.4 10 ugtL 50.00 103 44-163 2 20 4-Chlorophenyl phenyl ether 52.7 10 ug/L 50,00 105 25-158 0.02 20 4-Nitrophenol 23.1 50 ug/L 50.00 46 10-132 7 20 Acenaphthene 52.7 10 ug/L 50.00 105 47-145 2 20 Acenaphthylene 54.2 10 ug1L 50.00 108 33-145 1 20 Anthracene 61.8 10 ug/L 50.00 124 27-133 0.8 20 Benzidine 43.8 1o0 ug/L 50,00 88 15-150 44 20 0 Benzo(a)anthracene 59,2 10 ug/L 50.00 118 33-143 1 20 Benzo(a)pyrene 61.1 10 ug/L 50.00 122 17-163 4 20 Benzo(b)fluoranthene 57.8 10 ug/L 50.00 116 24-159 1 20 Benzo(g,h,i)perylene ME! 10 ug/L 50.00 122 10-219 3 20 Benzo(k)fluoranthene 60.7 10 ug/L 50.00 121 11-162 8 20 Benzoic Acid 3.41 100 ug/L 50A0 7 10-125 4 20 L Benzyl alcohol 46.9 10 ug/L 50.00 94 16-107 0.4 20 bis(2-Chloroethoxy)methane 48.8 10 ug/L 50.00 98 33-184 3 20 Bis(2-Chloroethyl)ether 42.1 10 ug/L 5D.00 84 12-158 3 20 Bis(2-chloroisopropyl)ether 50.6 10 ug/L 50.00 101 36-166 2 20 Bis(2-Ethylhexyl)phthalate 60.5 10 ug/L 50.00 121 10-158 0.4 20 Butyl benzyl phthalate 59.3 10 uglL 50.00 119 10-152 0 20 Chrysene 59,7 10 ug/L 50.00 119 17-168 0.6 20 ❑ibenzo(a,h)anthracene 42.3 10 ug/L 50.00 85 10-227 3 20 Dibenzofuran 54A 10 ug/L 50.00 108 39-114 2 20 Diethyl phthalate 56.7 10 ug/L 50.00 113 10-114 2 20 Dimethyl phthalate 55.4 10 ug/L 50.00 111 10-112 2 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1.8001529-6364 - Fax: 7041525-0409 Page 13 of 17 Level 11 QC Report d U R Full -Service Analytical 8 v P�R S M Environmental Solutions 1215118 �iJiaoN�TORIEB iac ARM Environmental - Charlotte Attn: Tim McCorkle 11164 Downs Rd. Pineville, NC 28134 Project: Mans -Hummel Allen Plant (Gastonia, NC) Semivolatile Organic Compounds by GC1MS - Quality Control Prism Work Order: 8110201 Time Submitted: 11/12/2018 11:50:00AM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P81<0266 - 3510C MS LCS Dup (P8K0266-BSDI) Prepared & Analyzed: 11/15/18 Di-n-butyl phthalate 60.6 10 ugtL 50.00 121 10-118 2 20 L Di-n-octyl phthalate 653 10 ugiL 50.00 131 10-146 5 20 Fluoranthene 587 10 ugiL 50.00 117 26-137 3 20 Fluorene 56.0 10 ugtL 50.00 112 59-121 1 20 Hexachlorcbenzene 55.5 10 ugtL 50.00 ill 10-152 2 20 Hexachlorobutadiene 36.9 10 uglL 50.00 74 24-116 0.6 20 Hexachlorocyclopentadiene 43.2 10 ug1L 50.00 86 32-117 0.9 20 Hexachloroethane 35.9 10 uglL 50.00 72 40-113 0.9 20 Indeno(1,2,3-cd)pyrene 67.3 10 uglL 50.00 135 10-171 4 20 Isophorone 50.7 10 uglL 50.00 101 21-196 0.4 20 Naphthalene 41.9 10 ug1L 50.00 84 21-133 0.2 20 Nitrobenzene 45.5 10 ug1L 50.00 91 35-180 0.2 20 N-Nitrosodimethylamine 32.3 10 ug1L 50.00 65 10-119 0.2 20 N-Nitroso-di-n-propylamine 48.8 10 uglL 50.00 98 10-230 4 20 N-Nitrosodiphenylamine 6T9 10 ugiL 50.00 136 69-152 2 20 Pentachlorophenol 39.9 10 ugtL 50.00 80 14-176 31 20 D Phenanthrene 59,0 10 uglL 50.00 118 54-120 3 20 Phenol 24.6 10 uglL 50.00 49 10-112 0.8 20 Pyrene 58.9 10 ugtL 50.00 118 52-115 0.5 20 L Surrogate:2,4,6-Tribromophenol 100 ug/L 100,0 100 31-144 Surrogate:2-Fluorobiphenyl 49.4 ug/L 50.00 99 49-118 Surrogate:2-Fluorophenol 57.0 ug/L 100.0 57 22-84 Surrogate: Nitrobenzene-d5 41,8 ug/L 50.00 84 43-123 Surrogate: Phenol-d5 40.5 ug/L 10Q0 40 10-63 Surrogate: Terphenyl-d14 53.8 ug/L 50.00 108 49-151 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Spring brook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041525-0409 Page 14 of 17 2' /'d'L R I S M EnvirFull.onmental al Solution s Environmentak Solutions 'JLrBORATOR'M iNc. Level II QC Report 1215/18 ARM Environmental - Charlotte Attn: Tim McCorkle 11164 Downs Rd. Pineville, NC 28134 Total Metals - Quality Control Analyte Project: Mans -Hummel Allen Plant (Gastonia, NC) Prism Work Order: 8110201 Time Submitted: 11/12/2018 11:50MAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P8K0269 - 200.7 Blank(P8K0269-BLK1) Prepared:11/15118 Analyzed:11116/18 Copper BRL 0.010 mg/L Lead BRL 0.0050 mg/L Zinc BRL 0,030 mg/L LCS (PBK0269-BS1) Prepared: 11/15/18 Analyzed: 11/16/18 Copper 0.511 0.010 mg1L 0.5001 102 85-115 Lead 0.515 0.0050 mg1L 0,5001 103 85-115 Zinc 0.533 0.030 mg/L 0.5001 107 85-115 This report shou3d not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041526-0409 Page 15 of 17 Level II QC Report Full -Service Analytical & 1215l18 PRISM I Environmental Solutions 1I90RAlORIEG IMG ARM Environmental - Charlotte Project: Mans -Hummel Allen Plant Prism Work Order: 8110201 Attn: Tim McCorkle (Gastonia, NC) Time Submitted: 11/12/2018 11:50:OOAM 11164 Downs Rd. Pineville, NC 28134 General Chemistry Parameters - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P8K0310 - NO PREP Blank (P81<0310-BLKI) Prepared & Analyzed: 11/16/18 Total Suspended Solids BRL 5.0 mglL LCS (P8K0310-BSI) Prepared & Analyzed: 11/16/18 Total Suspended Solids 520 5.0 mglL 477.0 108 90-110 Batch P8K0389 - NO PREP Blank (P8K0389-BLK1) Prepared & Analyzed: 11/21/18 Oil & Grease (HEM) BRL 5.0 mg1L LCS (P8K0389-BSI) Prepared & Analyzed: 11/21/18 Oil & Grease (HEM) 36.2 5.0 mg1L 40.00 90 78-114 Sample Extraction Data Prep Method: 3510C MS Lab Number Batch Initial Final DatelTime 8110201-01 P81<0266 1000 mL 1 mL 11/15/18 9:35 Prep Method: 200.7 Lab Number Batch Initial Final DatelTime 8110201-01 1381<0269 50 mL 50 mL 11/15/18 8:35 Prep Method: 624 Lab Number Batch Initial Final Date/Time 8110201-01 PSK0374 10 mL 10 mL 11120/18 16:20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-8001529.6364 - Fax: 704/525-0409 Page 16 of 17 Full -Service Analytical Environmental Solutions 449 Springbrook Road - Charlotte, INC 28217 Phone 7041529.SM - Fax: 70415254W9 Client Company Name: n f Report To/Contact Nam IWO Reporting dress: +#-r CHAIN OF CUSTODY RECORD PAGE OF QUO -E # TO ENSURE PROPER 13iLL1N0: Project Name: JvLt S Short Hold Analysis: (Yes) (No) UST Project: (Yes) (NO) "Please ATTACH any project specific reporting (QC LEVEL 1 11 III IV) provisions and/or QC Requirements Invoice To: Address: �•� & < cx Samples INTACT upon arrival? )Recetved ON WET ICE? PROPER PRESERVATIVES Indicated? Received WITHIN HOLDING TIMES? CUSTODY SEALS INTACT? VOLATILES rec'd WIOUT HEADSPACE? PROPER CONTAINERS used? TEMP: Therm ID: t 2S"q Observed: YES NO NIA 4-4 O � U ' w !'C I Corr • t7 °C Phone. —. Fa'(Yes) No): /x 6a Purchase Order No./Billing Reference TO BE FILLED IN BY CLIENTISAMPLING PERSONNE Email Address: e r �I'� (p 1~115F.i\ti' CE;d ` .Reiqu�,ted Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days Certification: NELAC DOD FL NC EDD Type: PDF. CIS Oth r "WorkingDays" O B-9 Da ❑ Standard 10 days ❑ Rush Work Must Be y y Site Location Name. %. �' Pre -Approved Samples received after 14:00 will be processed next business day. Sc OTHERS INiA Site Location Physical ddress: , > Turnaround time is based an business days, excluding weekends and holidays. Water Chlorinated: YES NO �? �* (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES ao L e Q_ �[�] `f Sample Iced Upon Collection: YES_Z NO_ _i — f�F/y-w RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) CLIENT RI SAMPLE QESCPTION DATE COLLECTED TIME COLLECTED MILITARY MATRIX (SOIL, WATER OR SAMPLE CONTAINER PRESERVA- TNES ANALYSI$ REQUESTED / �jt �f �� REMARKS V/ 4' PRISM LAB 'TYPE NO. SIZE ID NO. HOURS SLUDGE) SEE BELOW , ` C i � I I 1. .- Sampler's Sig to ! Sampled By (Print Name) Affiliation Upon relinqUiphing, this Chain of Custody is your Lion for Prism to proceed with the analyses as requested above. Any changes must be PRISM USE ONLY submiljt,dln ting tot a Prism Project Manager. There w e c arges for any changes after analyses have been initialized. ",q igna Received y: (Signature) Date ,inary ours Additional Comments: Site Arrival Time: e�_Dffw; (SigtatureTReceived By: (Signature) Date f, O GD D Site Departure Time: V Relinquished By: (Signature) Reoeived For Prism Laboratories By: ate Field Ted? Fee: Ah�»IvCi; vt" j )15 Mileage: Method of Shipment: NOW: ALL SAMPLE COOLERS S ULb 139 TAPED SAMPLES ARE NOT ACCEPTED AND VERIFIED SN WITIJ CUSTIODY SEALSRANS RTATION TO THE LA RATORY. C Group o. AGAINST COC UNTIL RECEIVED AT THE LAB TORY. /A' t` n r}r A } awn lE• r 1 L 1 O Fed Ea 0 UPS O Hand -delivered U Prism Field Service El Other 4 ^ t t 0 NC ❑ SC ❑❑ NC 0SC ❑❑ NC ❑ SCTER; 0 NC I❑ SCAR � SOLID ❑ NG O SC E ❑ NC Ell SC ❑ NC ❑ SC ❑ NC LANDFILL❑ SC © NC ❑ SC � M•t I I r 'CONTAINER TYPE CODES: A = AmhPr C = Clear P = Plactirr TI = Taflnn-I inari Can VOA n Vnlatila Ornanirc Analvcic 17orn Hnnr1 GnanaS _ ..- --•• - Semi-annual Stormwater Discharge Monitoring Report for North Carolina Division of Water QU lity General Permit No. NCG030000 Date submitted CERTIFICATE OF COVItRAGJ NO. NCGO30 FACILITY N COUNTY'- / PERSON COLLEING SAMPLE LABORATORY R' I �V1 _ lab Cert. # VDT Comments on sample collection or analysis: Part A: Stormwater Benchmarks and Monitoring Results SAMPLE COLLECTION YEAR SAMPLE PERIOD ❑ Jan -June ❑ July -Dec or ❑ Monthly'- n e _ (month DISCHARGING TO CLASS ❑ORW ❑HQW ❑Trout ❑PNA ❑Zero -flow ❑Water Supply [:]SA ❑Other RECE,,Vp-�? OLEASE REMEMBER TO SIGN ON PAGES 2 AND/OR 3 4 AUG ] 0 260 CENT Eu. rin-,6,No discharge this period?z outfall No. Date Sample Collected" (me/dd/yr) 24-hour rainfall amount, Inches3 Total Suspended Solids pH, Standard units Copper Lead Zinc Non -Polar O&G/Total Total Petroleum Hydrocarbons Toxic Organicss Benchmarks =_-> _ - 100 mg/L or So mg/L 6.0 - 9.0 0.007 mg/L 0.03 mg/L 0.067 mg/L 15 mg/L 1 mg/L oo/ A io.l "/c 1. / " Monthly sampling (instead of semi-annual) must begin with the second consecutive benchmark exceedance for the same parameter at the same outfail. 2, For sampling periods with no discharge at any single outfall, you must still submit this discharge monitoring report with a checkmark here. 3The total precipitation must be recorded using data from an on -site rain gauge. Unattended sites may be eligible for a waiver of the rain gauge requirement. " See General Permit, Table 3 identifying the especially sensitive receiving water classifications where the more protective benchmark applies. 5 Total Toxic Organics sampling is applicable only for those facilities which perform metal finishing operations, manufacture semiconductors, manufacture electronic crystals, or manufacture cathode ray tubes. For purposes of this permit the definition of Total Toxic Organics is that definition contained in the EPA Effluent Guidelines for the facility subject to the requirement to sample (for metal finishing use the definition as found in 40 CFR 433.11; for semiconductor manufacture use the definition as found in 40 CFR 469.12; for electronic crystal manufacture use the definition as found in 40 CFR 469.22; and for cathode ray tube manufacture use the definition found in 40 CFR 469.31). RECEIV 3 AUG 16 -"' Cep, _c . Permit Date: il/1/2012-10/31/2017 M = SWU-245, last revised 10/25/2012 Page 1 of 3 Facilities that incorporate a solvent management plan into the Stormwater Pollution Prevention Plan may so certify, and the requirement for TTO monitoring may be waived. The solvent management plan shall include a list of the total toxic organic compounds used and the other elements listed in the General Permit. For those facilities electing to employ the TTO monitoring waiver, the discharger shall sign the following certification statement: "Based upon my inquiry of the person or persons directly responsible for managing compliance with the permit monitoring requirement for total toxic organics (TTO), I certify that to the best of my knowledge and belief, no dumping of concentrated toxic organics into the stormwater or areas which are exposed to rainfall or stormwater runoff has occurred since filing the last discharge monitoring report. I further certify that this facility is implementing the all the provisions of the solvent management plan included in the Stormwater Pollution Prevention Plan." Tl__A Ca,�, Ord Z R Name (Print name) CIS E Yhn tn,aae r Title (Print title) paj k- ajw�- (Signature) I (Date) Note: Results must be reported in numerical format. Do not report Below Detection Limit, BDL, <PQL, Non -detect, ND, or other similar non -numerical format. When results are below the applicable limits, they must be reported in the format. "<XX me/L". where XX is the numerical value of the detection limit, reporting limit, etc. in mg/L. Note: If you report a sample value in excess of the benchmark, you must Implement Tier 1, Tier 2, or Tier 3 responses. See General Permit text. Part B: Vehicle Maintenance Area Monitoring Results: only for facilities averaging > 55 gal of new oil per month. M No discharge this period ?2 Outfall No. Date Sample Collected' (mo/dd/yr) 24-hour rainfall amount, Inches' Non -polar O&G/TPH by EPA 1664 (SGT-HEM) Total Suspended Solids pH Benchmarks =__> _ - 15 mg/L 100 mg/L or 50 mg/L* 6.0 — 9.0 SU Footnotes from Part A also apply to this Part B * See General Permit text, Table 5, identifying the especially sensitive receiving water classifications where the more protective benchmark applies. Permit Date: 11/1/2012-10/31/2017 SWU-245, last revised 10/25/2012 Page 2 of 3 Note: If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 2, or Tier 3 responses. See General Permit text. FOR PARTA AND PART B MONITORING RESULTS: • A BENCHMARK EXCEEDANCE TRIGGERS TIER 1 REQUIREMENTS, SEE PERMIT PART II SECTION B. • 2 EXCEEDANCES IN A ROW FOR THE SAME PARAMETER AT THE SAME OUTFALL TRIGGER TIER 2 REQUIREMENTS. SEE PERMIT PART II SE ION B. • TIER 3: HAS YOUR FACILITY HAD 4 OR MORE BENCHMARK EXCEEDENCE OR THE SAME PARAMETER AT ANYONE OUTFALL? YES No ❑ IF YES, HAVE YOU CONTACTS TMDWEGIONAL OFFICE. YES NO ❑ REGIONAL OFFICE CONTACT NAME c� Mail an ariainal and one copy of this DMR. including all "No Discharge" reports within 30 days of receipt of the lab results (or at end of monitoring period in the case of "No Discharge" reports) to: Division of Water Quality Attn: DWQ Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED: "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." (Signature of Permittee] Permit Date: 11/1/2012-10/31/2017 -7-tZ-(g (Date) SWU-245, last revised 10/25/2012 Page 3 of 3 Full -Service Analytical 8 Environmental Solutions �ivueoa,wn��s, u+c ARM Environmental - Charlotte Tim McCorkle 11164 Downs Rd. Pineville, NC 28134 NC Certification No. 402 Case Narrative NC prinking Water Cert No. 37735 07/1012018 SC Certification No. 99012 Project: Wix- Allen Plant (now Mann 8 Hummel) Lab Submittal Date: 06/2712018 Prism Work Order: 8060378 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. Terri W. Cole Project Manager Data Qualifiers Key Reference: Reviewed By Jackie Ziner For Terri W. Cole Project Manager DM Sample diluted and RL increased due to the matrix. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except In its entirety, vAthout the written consent of Prism Laboratories, Inc. 449 9pringbmok Road - P.O. Box 240543 - Charlotte, NC 28224-OW Phone: T041529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 70CS25-0409 Page 1 of 5 / Full•Samloo Arnalytisal 8 � P- R �l I S i T /A, 1 I Envlronmentat Solutlons �uscwtamca �c Sample Receipt Summary 07/10/2018 Prism Work Order: 8060378 Client Sample ID Lab Sample 10 Matrix Daterrime Sampled DateMme Received 001 8060378-01 Water 06/25/18 20:10 06/27/18 13:00 Samples were received in good condition at 3.6 degrees C unless otherwise noted. This report should not be reproduced, except in Its entirety, without the written consent of Prism Laboratories, Inc. 449 Sprinpbrook Road - P.O. Box 240S43 - Charlotte, NC•28224-0543 Phone: 7041529 b364 • Toll Free Number: 1 80U15241i354 - Fax: 7011525-0409 Page 2 Of 5 LZRI Full-service Anal Ical 3 Ls M ( Environmental Solution$ Laboratory Report 07/1012018 ARM Environmental - Charlotte Project: Wix- Allen Plant (now Mann & Client Sample ID: 001 Attn: Tim McCorkle Hummel) Prism Sample 1D: 8060378-01 11164 Downs Rd. Prism Work Order: 8060378 Pineville, NC 28134 Sample Matrix: Water Time Collected: 06/25/18 20:10 Time Submitted: 06/27/18 13:00 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Datefrime ID Total Metals copper 0,10 0M Zinc 1.5 0M mgk 0.050 0.0050 5 '200.7 7110118 12:39 JAB P8F0475 mglL 0.15 0.0065 5 '200.7 7110/18 12:39 JAB P8F0475 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704l52"354 - Tall Free Number. 1-80015294364 - Fax: 7041525-0409 Page 3 of 5 Fuca lcal Environmen7W Solutions �iweaMra�n;l ��C ARM Environmental - Charlotte Attn: Tim McCorkle 11164 Dawns Rd. Pineville, NC 28134 Total Metals - Quality Control Anatyte Batch PSF0475 - 200.7 Project: Wix- Allen Plant (now Mann & Hummel) Level II QC Report 7/10118 Prism Work Order: 8060378 Time Submitted: 6/27/2018 1:00:OOPM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Blank (PBF0475-BLK1) Prepared: 06129/18 Analyzed: 07/05/18 Copper BRL 0.010 M91 Zinc BRL 0.030 mg1L LCS (PBF0475-651) Prepared: 0612911E Analyzed: 07105/18 Copper 0.551 0,010 mg1L 0.5001 110 85-115 Zinc 0.554 0.030 mg/L 0.5001 ill 85-115 Sample Extraction Data Prop Method: 200.7 Lab Number Batch Initial Final aatemme 8060378-01 PBF0475 So mL 50 mL 06/29/18 7:40 This report should not be reproduced, except in its entirety, without the wntten consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240S43 - Charlotte, NC 28224-0543 Phone: 704l529-6364 - Toll Free Number: 1.800/529-6364 - Fax: 7041525."09 Page 4 of 5 SHEALY ENVIRONMENTAL SERVICES, INC. S 106 Vantage Point Drive • West Columbia, SC 2917216 Chain of Custody Record Telephone No. 803-791-9700 Fax No. 803-791-9111 Number vrww.shealylab.com i Z C`3.( U) Ln � Client Report to Contact Telephone No. / E-mail Lhroto No. Address Sampfer'6 Signature x Artafysis (Attach fist if more space is needed) page —of City State zip code Laboratory Lot Number — Pnntad Name Proiect Name Protect No, RO. No. $ ou Matrix No of conraunis by Pmsarva6vu Typo Sample ID / Description (Copra-rs for each sample may be mrnb ned on pea Gm.) Date Time d 7 Remarks / Cooler I.D. FLI 'rum Around 71me Required (Prfar lab approral required fat expedited rAF i Standard . Rush (Sp@elly) Sample Disposal p Retum to menl Disposal by !ab Possible Hazard Identification ❑ Non•Hazard 0 Flammable I--1 Skin Irritant f:S Poison L7 Unknown OC Requirements (Spectly) 1. 5elfngnlshed by Dale Timo 1_ Received by Date Time 2. Relnquished by Data Time 2. Received by Date 'rime 3. ReirrNulshed by I Dale 1 Irmo 3. Received by { Date Time 4. Relinquished by Date Time 4. laboratory received by Data Time Note: Al) samples are retained for four weeks from receipt unless other arrangements are made. LAB USE ONLY Rocaivad on ico (Circle) Yes No ice Pack � Retcipt temp C SOW OW DISTRIBUTION: WHITE A YELLOW-Ranim to laboratory with Semple(s); PiNK-F7ald/C1ienf Copy Document Number. 1=AD-133 ENactivo Dato: 08-Dr-2014 Envlronmenlal Quality Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance on filling out this form, please visit https:/� /deq.ne.�lov/about/divisions/energy-mineral-land- resources/eneray-mineral-land pertnits/stormwater-permitslnnpdcs-industrial-sw•4tab-4 Permit Na.: N1C,C:�JICU' or Certificate of Coverage No.: NICIG/ bIQ1111�L Facility Name: r` — kge4xQ t . County: S Phone No. 7�- Date of Inspection: T� Time of Inspection: _.., t a 17 Total Event Precipitation (inches): , L0 All permits require qualitative monitoring to be performed during a "measurable storm event." A "measurable storm event" is a storm event that results in an actual discharge from the permitted site outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter interval is representative for local storm events during the sampling period, and the permittee obtains approval from the local DE1N4LR Regional Office. By this signature, I certify that this report is accurate and complete to the best of my knowledge: _(Sigiftiture df Ferinittee or Designee) 1. Outfall Description: Outfall No .4t Structure (pipe; ditch etc.): D 4 P_ Receiving Stream: Describe the ' dustrial activities that occur ithin a outfa` drainage area: draina1�c lv -/- f /' I Page I of 2 $WU-242. Wt modified 0712812017 2. Color: Describe the color of th discharge (light, medium, dark) as descriptors: �[ basic colors (red, brown, blue, etc.) and tint 3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): 4. Clarity: Choose the number which best describes the clarity of the discharge, where l is clear and 5 is very cloudy: 0 2 3 4 5 5. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where i is no solids and 5 is the surface covered with floating solids: 1 (D 3 4 5 5. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where l is no solids and 5 is extremely muddy: 1 � 3 4 5 7. Is there any foam in the stormwater discharge? o Yes 0, No. 8. Is there an oil sheen in the stormwater discharge? OYes ® No. 4. is there evidence of erosion or deposition at the outfall? O Yes A No. 10. Other Obvious Indicators of Stormwater Pollution: List and describe Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be Indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 SWU-242, Last modified 07C28/2017