NCG100033_MONITORING INFO_20170321

STORMWATER DIVISION CODING SHEET
NCG PERMITS
PERMIT NO.
IV U&oq o-03 3
DOC TYPE
❑HISTORICAL FILE
� MONITORING REPORTS
DOC DATE
❑ 02 o) 7 03
YYYYMMDD

.a
Semi-annual Stormwater Discharge Monitoring Report
` for North Carolina Division of Water Quality General Permit No. NCG090000
Date submitted 3AR,///-7
CERTIFICATE OF COVERAGE NO. NCG09_D�_3 3
FACILITY NAME , J.Is i- C'AcPc�rr ma�
COUNTY %'SFr teA., lrr►j 3aL4w
PERSON COLLECTING SAMPLES
LABORATORY AGF_ AvAjvXQtgti Lab Cert. #
Comments on sample collection or analysis:
Part A: Stormwater Benchmarks and Monitoring Results
SAMPLE COLLECTION YEAR >
SAMPLE PERIOD Jan -June ❑ July -Dec
or Monthly' (month'
DISCHARGING TO CLASS ❑ORW ❑HQW ❑Trout ❑PNA
RECEIVED
I n ❑Zero -flow ❑Water supply []SA�+ V �CJ ❑Other
MAR 2 7 2011
CENTRAL FILES
PLEASE REMEMBER TO SIGN ON THE REVERSE 4
DWR SECTl01V
❑ No discharge this period?'
Ouytffall No.
�
�^-rl
Date Sample
Collected'
(mo/dd/yr)
24-hour rainfall
amount,
Inches3
Total Cadmium
Total Chromium
Total Lead
Benchmarks
0.001 mg/L
1.0 mg/L
0.03 mg/L ,
lr
• 3 o
L , c>l &.
G , 005
.005 ," r,
' Monthly sampling (instead of semi-annual) must begin with the second consecutive benchmark exceedance for the same parameter at the same outfall.
z For sampling periods with no discharge at any single outfall, you must still submit this discharge monitoring report with a checkmark here.
3The total precipitation must be recorded using data from an on -site rain gauge. Unattended sites may be eligible for a waiver of the rain gauge requirement.
Note: Results must be reported in numerical format. Do not report Below Detection Limit, BDL, <PQL, Non -detect, ND, or other similar non -numerical
format. When results are below the applicable limits, they be reposed in the format, ma/L"be reported in the format, "<XX ma/L", where XX is the numerical value of the detection
limit, reporting limit, etc. in mg/L.
Note. If you report a sample value In excess of the benchmark, you must Implement Tier 1, Tier 2, or Tier 3 responses. See General Permit text.
Permit Date:11/1/2012-10/31/2017 SWU-255, last revised 10/25/2012
Page 1 of 2

Part B: Vehicle Maintenance Area Monitoring Results: only for facilities averaging > 55 gal of new oil per month. Q/A
❑ No discharge this period?Z
Outfall No.
Date Sample
Collected'
(mo/dd/yr)
24-hour rainfall
amount,
Inches
Non -polar O&G/TPH by
EPA 1664 (SGT-HEM)
Total Suspended Solids
pH
Benchmarks
15 mg/L
100 mg/L or 50 mg/L*
6.0 — 9.0 SU
Footnotes from Part A also apply to this Part B
* See General Permit text, Table 5, identifying the especially sensitive receiving water classifications where the more protective benchmark applies.
Note: if you report a sample value in excess of the benchmark, you must Implement Tier 1, rier 2, or Tier 3 responses. See General Permit text.
FOR PART A AND PART B MONITORING RESULTS_
• A BENCHMARK EXCEEDANCE TRIGGERS TIER 1 REQUIREMENTS, SEE PERMIT PART li SECTION B.
• 2 EXCEEDENCES IN A ROW FOR THE SAME PARAMETER AT THE SAME OUTFALL TRIGGER TIER 2 REQUIREMENTS. SEE PERMIT PART II SECTION B.
• TIER 3: HAS YOUR FACILITY HAD 4 OR MORE BENCHMARK EXCEEDENCES FOR THE SAME PARAMETER AT ANYONE OUTFALL? YES ❑ NO [
IF YES, HAVE YOU CONTACTED THE DWQ REGIONAL OFFICE? YES ❑ NO ❑ 14
REGIONAL OFFICE CONTACT NAME:
Mail an orialnal and one co�v of this 1?MR—irrcludina all "No Discharae" renorts, within 30 days of recelot of the lab results for at end of monitorina period
in the case of "No Discharae" revortsJ to:
Division of Water Quality
Attn: DWQ Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED:
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or
those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I
am awarq.that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
(Signature of Perm"W) (Date)
Permit Date: 11/1/2012-10/31./2017
SWU-255, last revised 10/25/2012
Page 2 of 2

�aceAnalAca1"
1,1 paaawmoum
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersvilte, NC 28078
VO4)87rr9092
February 21, 2017
Adam Brockway
Valspar
10300 Claude Freeman Drive
Charlotte, NC 28262
RE: Project: Bi-Annual Quantitative Analysi
Pace Project No.: 92330147
Dear Adam Brockway:
Enclosed are the analytical results for sample(s) received by the laboratory on February 15, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNIINELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Od*k VAI -
Angela Baioni
[e-mail]
Project Manager
Endosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 11

Pace Analytical Services, LLC
aceAnalytical a 9800 Kinsey Ave. Suite 100
Huntersville, NC 28078
` "w'"` ft=n [phone]
i
CERTIFICATIONS
Project: Bi-Annual Quantitative Analysi
Pace Project No.: 92330147
Asheville Certification IQg
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Gedificatiore #. M-NC030
North Carolina Drinking Water Certification M 37712
North Carolina Wastewater Certification fit: 40
South Carolina Cercticalian #: 99030001
VarginialVELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in foil,
without the written consent of Pace Analytical Services, LLC. Page 2 of 11

awc.eAnalytical"
www.pacewmccm
Pace Analytical Services, LLC
980D Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: Bi Annual Quantitative Analysi
Pace Project No.: 92330147
Analyses
Lab ID Sample ID Method Analysts Reported Laboratory
92330147001 A EPA200.7 SER 3 PASI-A
92330147002 B EPA200.7 SER 3 PASI-A
REPORT OF LABORATORY ANALYSIS
This repot shall not be reproduced, except in full,
Without the written consent of Pace Analytical Services, LLC.
Page 3 of 11

ace Analytical "
wwwps,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
ANALYTICAL RESULTS
Project: Bi-Annual Quantitative Analysi
Pace Project No.: 92330147
Sample: A Lab ID: 92330147001 Collected: 02/15/17 15:41 Received: 02/15/17 16:18 Matrix: Water
Parameters Results ilniis Report Linil DF Prepared Analyzed GAS No. Qual
200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7
Cadmium ND Iron- 1.0 1 02118/17 01:25 02120117 22:07 7440-43-9
Chromium ND ug/L 5.0 1 02/18117 01:25 02/20/17 22:07 7440.47-3
Loud ND ug1L 5.0 1 02/18/17 01;25 02/20/17 22:07 7439-92-1
Dale: 02/21/2017 11 A9 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 11

�eAnalytical"
www.pscela mcom
Pace Analytical Services, LLC
9800 Kinoey Ave. Suite 100
Huntersville, NC 28078
(704)8A-9092
ANALYTICAL RESULTS
Project: Bi-Annual Quantitative Analysi
Pace Project No.. 92330147
Sample: 13 Lab ID: 92330147002 Collected: 02/15/17 15:42 Received: 02/15/17 16:18 Matrix: Water
Parameters Results Units Report Limit DE Prepared Analyzed CAS No. Qual
200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7
Cadmium NO ug/L 1.0 1 02/18/17 01:25 02/20/17 22.16 7440-43-9
Chromium NO ugfL 5.0 1 02/18/17 01:25 02/20/17 22.16 7440-47-3
Lead NO ug/L 5.0 1 02/18/17 01:25 02/20/17 22:16 7439-92-1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/21/2017 11:49 AM without the written consent of Pace Analytical Services, LLC.
Page 5 of 11

ace Analytical*
wwwPacefab&txrn
i
QUALITY CONTROL DATA
Project: Bi-Annual Quantitative Analysi
Pace Project No.: 92330147
QC Batch; 3413730 Analysis Method: EPA 200.7
QC Batch Method: EPA 200.7 Analysis Description: 200,7 MET
Associated Lap Samples: 92330147001, 92330147002
METHOD BLANK: 1934752
Associated Lab Samples: 92330147001, 92330147002
Parameter Units
Cadmium ug/L
Chromium ug/L
Lead ug/L
Matrix: Water
Blank Reporting
Result Limit Analyzed
NO 1.0 GZ20117 21:6221:r;2
NO 5.0 02/20/17 21:52
ND &0 02120117 21:52
Qualifiers
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
1934753
Spike
LCS LCS % Rec
Parameter
Units
Conc.
Result % Rec Limits Qualifiers
Cadmium
ug/L
500
491 98 85-115
Chromium
ug/L
500
481 96 851115
Lead
ug/L
500
488 98 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1934754
1934755
MS
MSD
92330147001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Conc_
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Quai
Cadmium ug/L
ND
500
500
481
479
96
96
70-130
0
Chromium ug/L
NO
500
500
474
466
95
93
70-130
2
Lead ug/L
NO
500
500
469
468
93
93
70-130
0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1934756
1934757
MS
MSD
92329937002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Cadmium ug/L
NO
500
500
479
482
96
96
70-130
1
Chromium ug/L
NO
500
500
480
473
96
94
70-130
1
Lead ugfL
3.iJ
500
500
471
477
94
95
70-130
1
Results presented on this page are in the units indicated try the 'Units' column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/21/2017 11:49 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 1 i

Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
�ac
eAnalytical Huntersviile, NC 28078
rr ww.p s.wm (704)875-J092
QUALIFIERS
Project: Bi-Annual Quantitative Analysi
Pace Project No.: 92330147
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
POL - Practical Quantitatvn Limit.
RL - Reporting Limit
S - Surrogate
1,2-Dipheny1hydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calrndate % recovery and RPD values_
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each anatyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute_
LABORATORIES
PASI-A Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/21/2017 11:49 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 11

aceAnalytical.
rww.Pacata a="
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 26078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Bi-Annual Quantitative Analysi
Pace Project No.: 92330147
Analytical
Lacs 10 Sample ID QC Batch Method QC- Batch Analytical Method Batch
02330147001 A EPA 200.7 348730 EPA 2003 348920
02330147002 B EPA 200.7 34873n FPA 200 7 348920
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/21/2017 11 A9 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 11

w W11M111 ~11W.
���1ytlC8/�
Laboratory receiving samples:
Asheville ❑ Eden[:]
Document No.: —
.01
Greenwood ❑ Huntersville
uvwment Keviseo: Sept. it, tulb ..
Page I of 2 - -
issuing Authority: .
Pace Quality Office
Raleigh❑ Mechanicsville❑
Client Name:
V �"�' P
WOW • 92330 14?
.
Courier.
Fed Ex
MClient
UPS ❑USPS
❑ Commertial
❑Pace
❑Other:
92330147
Custody Seal Preserd?
❑Yes, QoNo
Seals intact? ❑Yes
Wo .. I�
Date/Initials Person Examning Li
Packing Material:
❑Bubble Wrap
❑Bubble Bags WNone
[]Other
Thermometer:
❑ IR Gun iD:
�
t � U
jXWet
Type of Ice
1
❑Blue ©i �ui�e. []Samples on ice, cooling process has begun
Correction Factor:
Cooler Temp Corrected ('Q: L
Blologital Tissue Froze? ❑Yes MNa ❑N/A
Temp should be above freezing to VC
USDA Regulated Sail (❑
N/A, water sample)
Old samples arlgtnate In a quarantine
zone within the United States: CA, NY, or SC (check maps)? Old samples originate from a foreign source (rtemationaiiy,
Elias 19Yo
including Hawaii and Puerto Rim)? Dyes . Oft
Present?
vithln Hold Time?
Short Hold Time Analysis
Rush Turn Around Time 1h
Sufficleht Volume?-
Correct'Containers Used?
-Pace Containers Used?
Containers Intact?
Sample Labels Match COC?
Yes ONO N/A 1.
e3 No N/A 2.
es No N/A 3. {
❑Yes Up. ONIA 4.
1MYes ONO ❑N/A I S.
Wfes ©No ❑NIA 16.
No N/A 7.
No N A 8. Note If sediment is visible In the dissolved container
§[No
Headspace In VOA Vials (>5-fimm)? Dyes ND []NIA 10,
Trip Blank Present? Oyes o ❑N/A 11. '
Tri Blank Custody Seals Present? ❑Yes o ❑N/A
amffNDTIFl ATioN/REsowriON Field Data Required? ❑Yes []No
Person Contacted: Date/7ime:
Comments/Sample
Discrepancy: -
Project Manager SCURF Review:
Project Manager 5RF Review: Date;
Nate: Whenever there Is a discrepancy affecting North Carolina. compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
Jut of hoid; incorrect preservative out of temp, Inoomect containers)
Page 9 of 11

Sample Condition Upon Recel SCUA) Page 2 of 2
CeAnaOcal � Document No.: Issuing Authority:
F-CAR-CS-033-Rev.01 Pace QuaG Office
"Check mark top half of box if pH and/or dechlorination Project #i WO# ; 92330147
Is verified and within the acceptance range for
preservation samples. PM: RMI3 Due Dale: 02f22/17
"Bottom half of box is to list number of bottles CLIENT: 92—Valepar
pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of presentative
added
lots
Page 10 of 11

iectlon A
tequlred Client Intortnatlon:
Section a
Roqulred Project Irtfarrnatlon:
CHAIN -OF -CUSTODY 1 Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All felevant fields must be completed accurately.
Sectlon C
Imoke IntorrnWon:
a�
rn
Pans • t Of t
a
%omarY. vals ar
Report To: Adam Brodwgy
Attention:
tress: 10300 Claude Freeman
Cupy To:
Cnntpany Name:
;harlupa NC 28M
Address:
_•;,# � 'Regulatory A `enc
:mall! s
Purchase Order 4:
Pace QuOle:
'hone: Fax
Projecl Name: TCLP And ato"rwater se lea
Peas Project Manager: anlye10.6a1on1aeWN corn,
toquestod Due Data:
Project#
Psae Profiler. 9192.1 2
NC
rrl „rrr• }
�
r
mmm cow
�
COLLECTED
Preservatives
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weer wT
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SAMPLE ID
START
END
C)
?
04 o�
<
Ono Character r box. w+We uvP
y�
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Sample Ids must be udgw TNew
S
2
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DATE
TIME
DATE
TIME
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= 4
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SAMPLER NAM AND, SIGNATUREej
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PRINT Name of SAMPLER44,
of
Q.
.
SIGNATURE PLE I
I DATE Signed;
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