NCS000389_MONITORING INFO_20061215

STORMWATER DIVISION CODING SHEET
NCS PERMITS
PERMIT NO.
A j GIZ6 oo0 37
DOC TYPE
❑ FINAL PERMIT
C2� MONITORING REPORTS
❑ APPLICATION
0 COMPLIANCE
❑ OTHER
DOC DATE
❑ 2 oc>{-e
YYYYM M DD

DAKAmericas
;aHBERS. MONOMERS & RESINS
< <. December-1 S, 2006,,.
REF: NPDES Permit No. NCS000389
Division of Water Quality
N. C? DENR
1617 Mail Service Center
Raleigh N.C. 27699-1617
ATTN: Central Files
Dear Sirs:
Enclosed are the Stormwater discharge,monitoring•reports submitted by DAK Americas
for.your records., These results represent the Analytical Monitoring Requirements for year
471' quarter sampling as detailed in NPDES Permit No. NCS000389 Table 2 Part Il page
Sincerely,
- Donald Allbright
ORC -
CERI'IFTED MAIL N 7002 2030 0002 8853, 9310

Permit Numbe : NCS000389 .
STORMWATER DISCHARGE OUTFALL
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2006
FACILITY NAME DAK RESINS LLC
PERSON COLLECTING SAMPLE(S) DONALD ALLBRIGHT
CERTIFIED LABORATORY(S) TBL Lab# 37
Paradigm Anal ical Laboratories INC. LAB# 481
Part A: Specific Monitoring Requirements
COUNTY CUMBERLAND
PHONE NO. 910 4 3-8 27
(SIGNATUR OF PERMITTEE OR DESIGNEE)
By this signature, I certify that this report is accurate
complete to the best of my knowledge.
Outfall
No.
Date
Sample
Collected
50050
00340
82388
Total
Flow
COD
1,4 DIOXANE
molddlyr
MG
MGIL
MGIL
003
11 /8/2006
1 1.2
1 195
0.00792
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? yes X no

STORM EVENT CHARACTERISTICS:
Date 11/8/2006
Total Event Precipitation (inches): 1_8
Event duration (hours): 24
Mail Original and one copy to:
Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
" I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the Information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
Including the possibility of fines and imprisonment for knowing violations.
(Signature of Permittee)

STORMWATER DISCHARGE OUTFALL
MONITORING REPORT
Permit Numb r�t)38SAMPLES COLLECTED DURING CALENDAR YEAR: 2006
FACILITY NAME DAK RESINS LLC COUNTY CUMBERLAND
PERSON COLLECTING SAMPLE(S) DONALD ALLBRIGHT PHO 910 433-822
CERTIFIED LABORATORY(S) TBL Lab# 37
420
Paradigm Analytical Laboratories _INC._ LAB#_48 f (SIGNATUR PERMITTEE OR DESIGNEE)
By this signature, I certify that this report is accurate
complete to the best of my knowledge.
Part A: Specific Monitoring Requirements
Outfall
No.
Date
Sample
Collected
50050
00340
82388
Total
Flow
COD
1,4 DIOXANE
molddlyr
MG
MGIL
MG1L
003
11/8/2005
1 1.2
1 195
0.00792
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? yes X no

STORM EVENT CHARACTERISTICS:
Date 11/8/2006
Total Event Precipitation (inches): 1.8
Event duration (hours): 24
Mail Original and one copy to:
Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
" I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted Is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false Information,
including the possibility of fines and imprisonment for knowing violations.
(Signature of Permittee)
.. : I

DAK Americas
FIBERS, MONOMERS & RESINS
To: NCDENR, DWQ
From: DAK Americas, LLC (Anthony Hudson)
Subject: NPDES # NCS000389, Analytical Monitoring
Date: 9-21-05
DAK Americas operates under NPDES Permit NCS000389 for its Cedar Creek
operations near Fayetteville, North Carolina. The permit requires that samples be
collected at Outfall 003 after a qualifying rainfall event. Given the weather over
the past several months, there have been little opportunity to collect samples, as
there have been few qualifying rainfall events. On July 29, 2005, however, there
was a qualifying rain event, and thus, a routine monitoring sample was taken
from Outfall 003.
The laboratory we use for the storm water samples was sent the samples for
analysis for chemical oxygen demand (COD) and 1,4-dioxane, in accordance
with the specifications of the permit. The outside lab provided a verbal report of
the results: COD analysis of 2,040 mg/L and total dioxin. (We received written
analysis of Outfall 003 sample on 9-6-05.) The COD results were remarkable,
given our typical levels; for example, based on previous samples, the average
COD from Outfall 003 is 13 mg/L, meaning the results reported verbally were
about 200 times the typical or expected results. Further, the laboratory reported
results for dioxin, where we had requested (as per our permit) analysis for
1,4-dioxane. There appeared to be some confusion between the primary
laboratory and subcontracted laboratory around the target compound for the
second analysis, conducting an analysis of the sample for dioxin rather than
1,4-dioxane.
The laboratory stated they could use the remaining water sample to complete an
analysis for 1,4-dioxane, were it not for the duration between collection, analysis,
and follow-up analysis. The sample collected during the qualified rain event was,
by then, "out of hold date" and would have to be prepared differently, which could
alter test results. We elected to have the sample, even though beyond the
normally accepted hold time, analyzed -for 1,4-dioxane and prepare for a back-up
sample to be collected from Outfall 003 during the next qualifying rain event. The
results of the analysis of this initial sample was BDL, which is consist with
historical results.
Given the magnitude of the COD result from the sample collected, we
immediately conducted a visual search of the site for potential contamination that
may have entered the storm water drain system. Our thesis was that anything
that contributed to such an abnormal COD result would be visibly evident at one
'.di
. i "..�
of the storm water drains.`Nb visible detection of any contaminate that would
DAK Americas LLC
3216 Cedar Creek Road • PO Box 1690 (28302) - Fayetteville, NC 28312
410-433-8300 - fax: [phone]

contribute to such an abnormal COD level was found throughout the site. Site
logbooks were checked and no documented incident around the storm water
drains had been recorded during the time period when the sample was collected.
Our storm water collection system includes a retention basin which allows us to
normalize flow to the outfall. The contents of this retention basin would, therefore,
be representative of the water that is directed to the outfall. The site collected
another water sample from the storm water retention pond, which feeds directly
to Outfall 003, and sent it to the same outside laboratories for analyses for COD
and 1, 4-dioxane. The laboratory again verbally provided the results for COD of
13.3 mg/L and 1,4-dioxane of BDL. These results are expected, being consistent
with the historical results of analyses of samples from Outfall 003.
The site believes the original sample is invalid based on:
• The results of the visual inspection for potential contamination at storm
water drains and
■ The results of the sample from the retention basin being in the normal
range for samples from Outfall 003.
The site will resample Outfall 003 during the next rain event to ensure that
parameters in the water discharging Outfall 003 are within acceptable limits
provided in the permit. These results will be provided to NCDENR when
available.
If additional information or actions are required please contact me at
910433-8338.

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC S000389 or SAMPLES COLLECTED DURING CALENDAR YEAR: 2003
Certificiate of Coverage Number: NCG (This monitoring report shall be received by the Division no later than 30
days from the date the facility receives the sampling results from the
laboratory)
FACILITY NAME DAK Resins, LLC, Cedar Creek Site
PERSON COLLECTING SAMPLE(S Jamie Honeycutt (S&ME, Inc.)
CERTIFIED LABORATORY (S) Compuchem. Laborato!j Lab # 79
Lab #
r8rt A: bnecine ivionitorme xeautrements
Outfal.1 Date' 50050
No. Sample Total A 4
Collected, Flow. Djo'xane C'OD...:;,i .17..-
'MG mg/LL"
mo/dd/yr
003 11/19/2003 0.71 <0.025 17
COUNTY Cumberland
P77E NUMBE� (910 433-8331
f
adz-4.9
(SPNATURE OF PERMITTEIr OR DESIGNEE)
j4y this signature, I certify, that this report is accurate and
complete to the best of my knowledge.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?
(if yes, complete Part B)
cart B: Vehicle Maintenance Activity MonitorInar Heouirements
Outfau
Date
1 50050-
00556:,:1it�
00530'1[
711.1�
No.
Oil
0 an
i3l: rjr;,�*;. 1
�: 3 jr 1
'!4`�
H
P
New Motor:
Collected
ow.
Flow"
!Grease.�.-_!
S uspended
16i I Usage.`
i-AbIL';
mo/dd/
MG
)4�
'.14"I'unit L-L,.,
_`
! .. allmo..
003
n/a
___yes _4_no
Form SWU-246-051 100
Pagel of

STORM EVENT CHARACTERISTICS:
Date: _11/19/03
Total Event Precipitation (inches): _1
Event Duration (hours): _Z
(if more than one storm event was sampled)
Date:
Total Event Precipitation (inches):
Event Duration (hours):
Mail Original and one copy to:
Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-16I7
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who
manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and
belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of tines and
imprisonment for knowing violations."
C. ,, -k ", -
(Signature rmittee)
!L-(�+-r
(Date)
Form SWU-246-051100
Page 2 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NCS000389 or SAMPLES COLLECTED DURING CALENDAR YEAR: 2004
Certificate of Coverage Number: NCG (This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
FACILITY NAME DAK RESINS LLC COUNTY CUMBERLAND
PERSON COLLECTING SAMPLE(S) DONALD ALLBRIGHT PHON NO. 91 -43 8227
CERTIFIED LABORATORY(S) TBL Lab# 37 - Z-1 0�
Environmental Science Corp Lab# ENV 375 (SIGNATU F PERMITTEE OR DESIGNEE)
By this signature, I certify that this report is accurate
complete to the best of my knowledge.
Part A: Specific Monitoring Requirements
Outfall
No.
Date
Sample
Collected
50050
00340
82388
Total
Flow
COD
1,4,DIOXANE
molddlyr
MG
MGlL
MGIL
003
61412004
1 0.218
13.3
1 <.10
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? yes X no

STORM EVENT CHARACTERISTICS:
Date 614104
Total Event Precipitation (inches):.3
Event duration (hours): .67
Mali Original and one copy to:
Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
" I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. i am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations.
(Signature of Permittee)
(Date) .