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HomeMy WebLinkAboutWQ0006242_Residual Annual Report 2014_20150211TOWN OF SPARTA, NC . RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0006242 2014 ANNUAL REPORT Town of Sparta, NC Residuals Land Application Program 2014 Annual Report TABLE OF CONTENTS 1. Certification Form, Annual Operations Summary, Facility and Land Applier Contact Information 2. Annual Residual Sampling Summary Forms, Residuals Analyses, & SAR Calculation Pages 3. Annual Land Application Field Summary Forms 4. TCLP Analysis 5. Pathogen ReductionNector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analyses ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: W00006242 County Alleahany Year 2014 Facility Name (as shown on permit) Town of Sparta WWTP NPDES No. NCO026913 Land Application Operator Synagro Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip PartA, and PartB and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A— Residuals Application Summary: Total number of application fields in the permit: 12 Total number of fields utilized for land application during the year: 3 Total amount of dry tons applied during the year for all application sites: 51.68 Total number of acres utilized for land application during the year: 42.9 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2014 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .I 105(a) or the Pollutant Loading Rates in 15A NCAC 02T .I 105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .I I I I were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Bryan Edwards. Town Manaeer Permittee N d 'tle (t pe r f8 I�4 2015 Si ture of Prepare Date '(if Jifferent from Permittee) P i ee WDa!e F F'M4 2015 ignature of LanApIilier Date (if different from Permittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) 2014 ANNUAL OPERATIONS SUMMARY - LAND APPLICATION SPARTA, NC SPARTA, NC LIME STABILIZED LIQUID MONTH/YEAR April 2014 July 2014 October 2014 YEARLY TOTAL AMOUNT UNIT 115,200.00 G 124,800.00 G 117,600.00 G 357,600.00 G DRY TONS UNIT 14.18 D 15.77 D 21.73 D 51.68 D DRY METRIC TONS 12.86 14.30 19.71 46.87 1 /26/2015 2014 ANNUAL REPORT PROJECT: FACILITY: NPDES PERMIT NUMBER: RESPONSIBLE OFFICIAL:. FACILITY OPERATOR: LAND APPLIER AND PREPARER OF LAND APPLICATION ANNUAL REPORT: Town of Sparta, NC Town of Sparta WWTP P.O. Box 99 Sparta, NC 28675 NCO026913 Bryan Edwards, Town Manager' Town of Sparta P.O. Box 99 Sparta, NC 28675 336-372-4257 Bobby Shaw, ORC Town of Sparta P.O. Box 99 Sparta, NC 28675 339-372-5015 Synagro Central, LLC Contact: Marshall Puryear (336) 998-7150 ext. 17 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0006242 Facility Name: SPARTA, NC NPDES# : NCO026913 or WQ# (residual only) WWTP Name: SPARTA Residuals Analysis Data Product Type LSLIQ LSLIQ LSLIQ Date Sampled (grab) or 03/28/14 07/07/14 10/20/14 Date Composited Percent Solids 2.95 3.03 4.43 PARAMETERS (mg/kg dry weight) Arsenic <3 <3 <3 Cadmium <2 <2 <2 Mercury 0.4 1.2 0.8 Chromium 24 34 23 Copper 354 459 438 Lead 14 19 16 Molybdenum <5 <5 <5 Nickel 20 25 19 Selenium <5 <5 <5 Zinc 419 547 525 Total Phosphorus 12500 14600 11100 TKN 33200 28400 21900 Ammonia -Nitrogen 3050 4290 1350 Nitrate and Nitrite 74.6 <2 <2 Laboratory A&L Eastern Laboratories Inc. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." i X Date 3 REOF PREPARER) DENR FORM RSSF (5/2003) Printed: Monday - January 26, 2015 at 14:27:06 for: 2040 01 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0006242 Facility Name: SPARTA, NC NPDES# : NCO026913 or WQ# (residual only) WWTP Name: SPARTA Residuals Analysis Data Product Type LSLIQ LSLIQ LSLIQ Date Sampled (grab) or 03/28/14 07/07/14 10/20/14 Date Composited Percent Solids 2.95 3.03 4.43 PARAMETERS (mg/kg dry weight) Aluminum 28200 29400 23500 Calcium 174000 163000 243000 Magnesium 7350 7450 13000 pH 12.33 12.35 12.35 Potassium 3340 2670 2370 Sodium 1250 1120 867 Laboratory A&L Eastern Laboratories Inc. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." M (SIGNATURE OF REP NR - Data Not Reported or Data Not Required Date d/. L DENR FORM RSSF-B (7/2002) Printed: Monday - January 26, 2015 at 14:27:28 for: 2040 01 Page: 1 of 2 Report Number: 14-092-0206 Account Number: 46491 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL LLC/SPARTA Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 98721 Sample Id: SPARTA @P, A&L Eastern- Laboratories, Inc. 7621 Whitepine Road Richmond, Virginia.23237 (804) 743-9401 Fax (804) 271-6446 wwwaleastern.com Project: SPARTA NC CERT#257 REPORT OF ANALYSIS Date Sampled: 3/28/2014 09:00:00 Date Received: 04/02/2014 00:00 Date Reported: 04/07/2014 Total Solids * 2.95 29500 100.0 JM 04/02/2014 14:39 SM-2540G Moisture * 97.05 100.0 JM 04/02/2014 14:39 SM-2540G Total Kjeldahl Nitrogen 3.32 33200 10.0 JM 04/03/2014 08:24 SM-4500-NH3C-TKN Total Phosphorus 1.25 12500 100 KM 04/04/2014 09:04 SW 6010C Total Potassium 0.33 3340 100 KM 04/04/2014 09:04 SW 6010C Total Sulfur 0.43 4280 100 KM 04/04/2014 09:04 SW 6010C Total Calcium 17.40 174000 100 KM 04/04/2014 09:04 SW 6010C Total Magnesium 0.74 7350 100 KM 04/04/2014 09:04 SW 6010C Total Sodium 0.13 1250 100 KM 04/04/2014 09:04 SW 6010C Total Iron 12600 100 KM 04/04/2014 09:04 SW 6010C Total Aluminum 28200 100 KM 04/04/2014 09:04 SW 6010C Total Manganese 634 5 KM 04/04/2014 09:04 SW 6010C Total Copper 354 5 KM 04/04/2014 09:04 SW 6010C Total Zinc 419 5 KM 04/04/2014 09:04 SW 6010C Ammonia Nitrogen 0.31 3050 10.0 JM 04/03/2014 08:24 SM-4500-NH3C Organic N 3.01 30150 10.0 04/03/2014 08:24 CALCULATION Nitrate+Nitrite-N 74.6 2.00 JM 04/03/2014 08:25 SM-450ONO3F Total Cadmium <2.0 2.0 KM 04/04/2014 09:04 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 14-092-0206 Account Number: 46491 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL LLC/SPARTA Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 98721 Sample Id: SPARTA yw A&L Eastern Laboratories, Inc._ 7621 Whitepine Road Richmond, Virginia,23237 (804) 743-9401 Fax (804) 271.6446 0 www.aleastern.com Project: SPARTA NC CERT#257 REPORT OF ANALYSIS Date Sampled: 3/28/2014 09:00:00 Date Received: 04/02/2014 00:00 Date Reported: 04/07/2014 Total Chromium 24 5 KM 04/04/2014 09:04 SW 6010C Total Nickel 20 5 KM 04/04/2014 09:04 SW 6010C Total Lead 14 5 KM 04/04/2014 09:04 SW 6010C Total Arsenic <3.0 3.0 KM 04/04/2014 09:04 SW 6010C Total Mercury 0.4 0.4 KM 04/02/2014 09:00 SW-7471 B Total Selenium <5.0 5.0 KM 04/04/2014 09:04 SW 6010C pH (Standard Units) * 12.33 2.00 JM 04/03/2014 08:24 SW-9045D Total Molybdenum <5 5 KM 04/04/2014 09:04 SW 6010C Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other pubfic announcements without obtaining our prior written authorization. Debbie Holt SAMPLING LOG # A CUSTOMER: SYNAGRG SOUTHEAST RI 8 PROJECT MANAGER: rl�s crJ Phone,-( � } '� - �'p A & L CUSTOMER SAMPLING SAMPLE LAB k SAMPLE I.D. LOCATION TYPE Relinquished � Relinquished by: l Ws I Fs2! .� SPECIAL INSTRUCTIONS: For SAMPLE I 21'. vUU��-3Z N� monitoring purposes. (STATE) &L 621 1 chm Q4/771 Date Time t° l /' Y . D�Jat Time IUIIIIIaIa�II�II�IIIIIIIiIIIIIINI�lllll�l�illll�� 464 1014OF CUSTODY ANALYSIS SYNAGRG CENTRAL LLCiSPARTA 12 yg 5y RECORD SPARTA rmpling procedures '"Cr tly, Gv ;aon of these samples. f A PLER # OF SAMPLING METHOD METHOD CONTAINERS DATE TIME PRESERVED SHIPPED I 4(z iy G3-, C) C,:-, -� L"A� ��Recieved by: Recieved by: Da##e Time Recieved by: Hlz)l`( 11:10 ANALYSIS REQUEST POI#: r 'GCS L/ REMARKS: SL1 SL2 NH4 N' NO3-N u` N°'r'+ Cd Cr Ni Pb As I Hg Se pH CaCO3 e uiv. Volatile Solids Mo Cl NO2 N 3 J� �, /1 y '''` `/ '.-� �-- �'' c� v- �....- ✓ `.- �--� �..,.- i✓' Cam• -- --- _._. _,, .w, „j�,,,,�,,1, ,,,,,,vyuns C, ru5pnoru, ano t'Otasslum SL2: Basic Test SL1 plus Sulfur, Calcium, Magnesium, Sodium, Iron, Aluminum, Manganese, Copper and Zinc White -A & L Canary - MANAGER COPY Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date Report Range Ratio 2040-01-LSLIQ-NC SPAR TA, NC LIME STABILIZED LIQUID 3/28/2014 4/112014-4/30/2014 0.1368 Na mg/I = (Na mg/kg x % Solids) = 100 = (1250 x 2.9500) =100 = 36.875 Ca mg/I = (Ca mg/kg x % Solids) _ 100 = (174000 x 2.9500) = 100 = 5133 Mg mg/I = (mg mg/kg x % Solids) = 100 = (7350 x 2.9500) = 100 = 216.825 Na meq = Na mg/I t- Molec.Wgt.Na = 36.875 = 23 = 1.60326 Ca meq = Ca mg/I = Molec.Wgt.Ca = 5133 _ 20 = 256.65 Mg meq = Mg mg/I = Molec.Wgt.Mg = 216.825 = 12 = 18.0687 SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 1.60326 = SgrRoot[0.5(256.65+18.0687)] = 0.136797 Printed: 1 /26/2015 Page 1 14:31 Page: 1 of 2 Report Number: 14-191-0201 A&L Eastern Laboratories, Inc.. Account Number: 46491 7621 Whitepine Road Richmond, Virginia 23237 .(80.4)743-9401 Fax (804)271-6446 Submitted By: ERIC THOMPSON wwwaleastem.com Send To: SYNAGRO CENTRAL LLC/SPARTA Project: SPARTA Mary Brewer SC CERT # 9007001 . 284 BOGER RD MOCKSVILLE , NC 27028 REPORT OF ANALYSIS Date Sampled: 7/7/2014 10:00:00 Lab Number: 56411 Date Received: 07/10/2014 00:00 Sample Id : SPARTA DIGESTER Date Reported: 07/17/2014 Total Solids 3.03 30300 100.0 JM 07/10/2014 15:40 SM-2540G Moisture * 96.97 100.0 JM 07/10/2014 15:40 SM-2540G Total Kjeldahl Nitrogen 2.84 28400 10.0 JM 07/11/2014 09:15 SM-4500-NH3C-TKN Total Phosphorus 1.46 14600 100 KM 07/11/2014 13:35 SW 6010C Total Potassium 0.27 2670 100 KM 07/11/2014 18:35 SW 6010C Total Sulfur 0.52 5180 100 KM 07/11/2014 13:35 SW 6010C Total Calcium 16.30 163000 100 KM 07/11/2014 13:35 SW 6010C Total Magnesium 0.75 7450 100 KM 07/11/2014 13:35 . SW 6010C Total Sodium 0.11 1120 100 KM 07/11/2014 13:35 SW 6010C Total Iron 15500 100 KM 07/11/2014 13:35 SW 6010C Total Aluminum 29400 100 KM 07/11/2014 13:35 SW 6010C Total Manganese 687 5 KM 07/11/2014 13:35 SW 6010C Total Copper 459 5 KM 07/11/2014 13:35 SW 6010C Total Zinc 547 5 KM 07/11/2014 13:35 SW 6010C Ammonia Nitrogen 0.43 4290 10.0 JM 07/11/2014 09:15 SM-4500-NI3C Organic N 2.41 24110 10.0 07/11/2014 09:15 CALCULATION Nitrate+Nitrite-N <2.00 2.00 JM 07/11/2014 09:15 SM-450ONO3F Total Cadmium <2.0 2.0 KM 07/11/2014 13:35 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or art, nor may an reference be made P P Y Y to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 14-191-0201 Account Number: 46491 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL LLC/SPARTA Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 56411 , Sample Id: SPARTA DIGESTER �L A&L Eastern- Laboratories, Inc:_ 7621 Whitepine Road Richmond, Virginia 23237 (804) 743.9401, Fax (804) 271.6446 WwW,aleastern.com Project: SPARTA SC CERT # 9007001 REPORT OF ANALYSIS Date Sampled: 7/7/2014 10:00:00 Date Received: 07/10/2014 00:00 Date Reported: 07/17/2014 Total Chromium 34 5 KM "07/11/2014.13:35 SW 6010C Total Nickel 25 5 KM 07/11/2014 13:35 SW 6010C Total Lead 19 5 KM 07/11/2014 13:35 SW 6010C Total Arsenic <3.0 3.0 KM 07/11/2014 13:35 SW 6010C Total Mercury 1.2 0.4 KM 07/11/2014 09:00 SW-7471 B Total Selenium <5.0 6.0 KM 07/11/2014 13:35 SW 6010C pH (Standard Units) * 12.35 2.00 JM 07/11/2014 09:15 SW-9045D Calcium Carbonate Equivalent 39.60 396000 100 JM 07/11/2014 14:15 AOAC 955.01 Total Molybdenum <5 5 KM 07/11/2014 13:35 SW 6010C Comments: SULFUR, CCE AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE MSD WAS OUT OF LIMITS FOR "Al" AND "K". ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date Report Range Ratio 2040-01-LSLIQ-NC SPARTA, NC LIME STABILIZED LIQUID 7/7/2014 7/112014-7131/2014 0.1280 Na mg/I = (Na mg/kg x % Solids) _ 100 = (1120 x 3.0300) -= 100 = 33.936 Ca mg/I = (Ca mg/kg x % Solids) = 100 = (163000 x 3.0300) + 100 = 4938.9 Mg mg/I = (mg mg/kg x % Solids) _ 100 = (7450 x 3.0300) =100 = 225.735 Na meq = Na mg/I = Molec.Wgt.Na = 33.936 = 23 = 1.47548 Ca meq = Ca mg/I _ Molec.Wgt.Ca = 4938.9 = 20 = 246.945 Mg-meq = Mg mg/I + Molec.Wgt.Mg = 225.735 = 12 = 18.8113 SAR = Na meq = SgrR66t[0.5 x (Ca meq + Mg meq)] = 1.47548 _ SgrRoot[0.5(246.945+18.8113)] = 0.127999 Printed: 1 /26/2015 Page 1- 14:31 Page: 1 of 2 Report Number: 14-295-0202 Account Number: 46491 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL LLC/SPARTA Mary Brewer 284 ROGER RD MOCKSVILLE , NC 27028 Lab Number : 58281 Sample Id : SPARTA A&L Eastern Laboratories, Inc. 7621 Whitepine Road Richmond, Virginia 23237 (804) 743.9401 _Fax (804) 271-6446 www.aleastern.com Project: SPARTA NC CERT#257 REPORT OF ANALYSIS Date Sampled: 10/20/2014 08:00:00 Date Received: 10/22/2014 00:00 Date Reported: 10/28/2014 Total Solids * 4.43 44300 100.0 JM 10/22/2014 14:30 SM-2540G Moisture * 95.57 100.0 JM 10/22/2014 14:30 SM-2540G Total Kjeldahl Nitrogen 2.19 21900 10.0 JM 10/23/2014 08:39 SM-4500-NH3C-TKN Total Phosphorus 1.11 11100 100 KM 10/23/2014 12:35 SW 6010C Total Potassium 0.24 2370 100 KM 10/23/2014 12:35 SW 6010C Total Sulfur 0.40 4010 100 KM 10/23/2014 12:35 SW 6010C Total Calcium 24.30 243000 100 KM 10/23/2014 12:35 SW 6010C Total Magnesium 1.30 13000 100 KM 10/23/2014 12:35 SW 6010C Total Sodium 0.09 867 100 KM 10/23/2014 12:35 SW 6010C Total Iron 12400 100 KM 10/23/2014 12:35 SW 6010C Total Aluminum 23500 100 KM 10/23/2014' 12:35 SW 6010C Total Manganese 490 5 KM 10/23/2014 12:35 SW 6010C Total Copper 438 5 KM 10/23/2014 12:35 SW 6010C Total Zinc 525 5 KM 10/23/2014 12:35 SW 6010C Ammonia Nitrogen 0.14 - 1350 10.0 JM 10/23/2014 08:39 SM-4500-NH3C Organic N 2.05 20550 10.0 10/23/2014 08:39 CALCULATION Nitrate+Nitrite-N <2.00 2.00 JM 10/23/2014 08:40 SM-450ONO3F Total Cadmium <2.0 2.0 KM 10/23/2014 12:35 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive. and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 14-295-0202 Account Number: 46491 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL LLC/SPARTA Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 58281 Sample Id: SPARTA A� A&L Eastern Laboratories, Inc. 7621 Whitepine Road Richmond, Virginia 23237 (604)'743.9401 Fax (604) 271-WG www.aleastern.com Project: SPARTA NC CERT#257 REPORT OFANALYSIS Date Sampled: 10/20/2014 08:00:00 Date Received: 10/22/2014 00:00 Date Reported: 10/28/2014 Total Chromium 23 5 KM 10/23/2014 12:35 SW 6010C Total Nickel 19 5 KM 10/23/2014 12:35 SW 6010C Total Lead 16 5 KM 10/23/2014 12:35 SW 6010C Total Arsenic <3.0 3.0 KM 10/23/2014 12:35 SW 6010C Total Mercury 0.8 0.4 KM 10/23/2014 09:00 SW-7471 B Total Selenium <5.0 5.0 KM 10/23/2014 12:35 SW 6010C pH (Standard Units) * 12.35 2.00 JM 10/23/2014 08:39 SW-9045D Calcium Carbonate Equivalent 60.80 608000 100 JM 10/23/2014 12:54 AOAC 955.01 Total Molybdenum <5 5 KM 10/23/2014 12:35 SW 6010C Comments: CCE, SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Se". ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Sodium Absorption Ratio Calculation (SAR) C Product Code Product Name Sample Date Report Range Ratio 2040-01-LSLIQ-NC SPARTA, NC LIME STABILIZED LIQUID 10/20/2014 10/112014-10/31/2014 0.0975 Na mg/1= (Na mg/kg x % Solids) _ 100 = (867 x 4.4300) _ 100 = 38.4081 Ca mg/1= (Ca mg/kg x % Solids) _ 100 = (243000 x 4.4300) + 100 = 10764.9 Mg mg/I = (mg mg/kg x % Solids) _ 100 = (13000 x 4.4300) = 100 = 575.9 Na meq = Na mg/I + Molec.Wgt.Na = 38.4081 = 23 = 1.66992 Ca meq = Ca mg/I _ Molec.Wgt.Ca = 10764.9 + 20 = 538.245 Mg meq = Mg mg/I + Molec.Wgt.Mg = 675.9 _ 12 = 47.9917 SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 1.66992 = SgrRoot[0.5(538.245+47.9917)] = 0.0975379 • Wil Printed: 1 /26/2015 Page 1 14:31 FACILITY NAME: SPARTA, NC OWNER: ANNA MILES EDWARDS SITE #: NC AG 00006 FIELD# : AG 00006 0001 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: WATAUGA PERMIT #: WQ0006242 ANNUAL DRY TONS APPLIED: 3.10 OPERATOR: STEVENSON ROTEN CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 5.70 ACRES PERMITTED: 5.70 Page Lime Applied *** DatE::::T Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) 0 Tons Cond. Precip. cation tili- ali- Ammonia _ Nitrate PAN DATE or per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids 4/4/14 25,200.00 (G) 4421.053 2.95 0.544 SPLSL MOIST 0-<1/2" SUR 0.5 0.30 33,200. p 3,050.00 p 74.60 p 10645 FESCUE Apr-14 25,200.00 (G) 4,421.053 Total Gallons/Ac: 4,421.05 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 0.003 0.002 0.026 0.385 0.015 <.001 0.005 0.022 0.005 0.456 13.60 12 Cumulative lbs/acre 0.036 0.028 0.587 8.192 0.512 0.019 0.252 0.500 0.037 11.989 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 78 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 SPLSL = SPARTA, NC LIME STABILIZED LIQUID X (SIGNATURE AND LIER) DATE "I certify, unde penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = pp- or mg/lcg ** Volatilization Rate: Surface 0.5, htjection/hicorporation 1.0 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: SPARTA, NC OWNER: RANOS HOKE ANDREWS SITE #: NC AG 00006 FIELD# : AG 00006 0002 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: CHESTER PERMIT #: W00006242 ANNUAL DRY TONS APPLIED: 15.77 OPERATOR: STEVENSON ROTEN CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 12.80 ACRES PERMITTED: 12.80 Page Lime Applied *** Date Lbs/Ac DATE or allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) Dry Tons Per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppm) Crop MONTH Total Per Acre Solids 7/8/14 28,800.00 (G) 2250.000 3.03 0.284 SPLSL DRY 0-<1/2" SUR 0.5 0.30 28,400.p 4,290.00 p 2.00 p 9380 I FESCUE 7/9/14 36,400.00 (G) 2843.750 3.03 0.359 SPLSL DRY 0-<1/2" SUR 0.5 0.30 28,400. p 4,290.00 p 2.00 p 9380 I FESCUE 7/10/14 11,000.00 (G) 859.375 3.03 0.109 SPLSL MOIST 0-<1/2" SUR 0.5 0.30 28,400. p 4,290.00 p 2.00 p 9380 I FESCUE 7/11/14 48,600.00 (G) 3796.875 3.03 0.480 SPLSL MOIST 0-<1/2" SUR 0.5 0.30 28,400. p 4,290.00 p 2.00 p 9380 FESCUE Jul-14 124,800.00 (G) 9,750.000 Total Gallons/Ac: 9,750.00 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 0.007 0.005 0.084 1.131 0.047 0.003 0.012 0.062 0.012 1.348 35.97 23 Cumulative lbs/acre 0.043 0.033 0.839 9.133 0.571 0.036 0.213 0.760 0.056 16.402 Permit PAN Limit (lbs/acre) Ist Crop/2nd Crop 179 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 SPLSL = SPARTA, NC LIME STABILIZED LIQUID X (SIGNATU OF L APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR= Not Reported or Not Required % = percent p = ppm or mgAg ** Volatilization Rate: Surface 0.5, Injection/Licorporation 1.0 Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: SPARTA, NC PREDOMINANT SOIL SERIES: CLIFTON OWNER: PEGGY EDWARDS BLEVINS PERMIT #: WQ0006242 ANNUAL DRY TONS APPLIED: 32.80 SITE #: NC AG 00006 FIELD# : AG 00006 0005 OPERATOR: STEVENSON ROTEN CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: '2'4.40 ACRES PERMITTED: 24.40 Page Lime Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (pptn) Crop MONTH Total Per Acre Solids 4/1/14 32,400.00 (G) 1327.869 2.95 0.163 SPLSL MOIST 0-<1/2" SUR 0.5 0.30 33,200. p 3,050.00 p 74.60 p 10645 I FESCUE 4/2/14 46,800.00 (G) 1918.033 2.95 0.236 SPLSL DRY 0-<I/2" SUR 0.5 0.30 33,200. p 3,050.00 p 74.60 p 10645 I FESCUE 4/3/14 10,800.00 (G) 442.623 2.95 0.054 SPLSL MOIST 0-<1/2" SUR 0.5 0.30 33,200. p 3,050.00 p 74.60 p 11645 FESCUE Apr-14 90,000.00 (G) 3,688.525 10/21/14 59,200.00 (G) 2426.230 4.43 0.448 SPLSL DRY 0-<1/2" SUR 0.5 0.30 21,900. p 1,350.00 p 2.00 p 6842 I FESCUE 10/22/14 36,800.00 (G) 1508.197 4.43 0.279 SPLSL DRY 0-<1/2" SUR 0.5 6.30 21,900. p 1,350.00 p 2.00 p 6842 I FESCUE 10/23/14 21,600.00 (G) 885.246 4.43 0.164 SPLSL DRY 0-<I/2" SUR 0.5 0.30 21,900. p 1,350.00 p 2.00 p 6842 FESCUE Oct-14 117,600.00 (G) 4,819.673 Total Gallons/Ac: 8,508.20 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 22 0.008 0.005 0.063 1.101 0.041 0.002 0.013 0.052 0.013 1.315 31.11 Cumulative lbs/acre 0.041 0.036 0.558 7.137 0.483 0.020 0.211 0.478 0.054 11.932 " 32 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 SPLSL = SPARTA, NC LIME STABILIZED LIQUID X / Z)` ?0 is (SIGN TU ' OF D APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 InSlUmma 1?U4rIRO'NhIEtJTAL g14lE?0L0C-Jos;➢Ei+.:. Arrily�c:-01 lut'! April 11, 2014 Eric Thompson Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: (336) 998-7150 FAX: (336) 998-8450 RE: Sparta Dear Eric Thompson: Summit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: &W.- /tvww.settek.com Order No.: 14040178 Summit Environmental Technologies, Inc. received 1 sample(s) on 4/2/2014 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Alr-� Dr. Mo Osman N� Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 A2LA 0724.01, Alabama 41600, Arkansas 88-0735, California 07256CA, Colorado, Connecticut PH-0105, Delaware, Florida NELAC E87688, Georgia E87688 and 943, Idaho 01100923, Illinois 200061 and Reg.5, Indiana C-OH-13, Kansas E-10347, Kentucky (underground Storage Tank) 3, Kentucky 90146, Louisiana 04061 and LA12004, Maine 2012015, Maryland 339, Massachusetts M-OPH923, Minnesota 409711, Montana CERT0099, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, Ohio 4170, Ohio VAP CL0052, Oklahoma 9940, Oregon OH2O0001, Pennsylvania 68-01335, Rhode Island LA000317, South Carolina 92016001, Tennessee TN04018, Texas T104704466-1 I-5, Region 8 8TMS- L, USDA/APHIS P330-11-00244, Utah OH009232011-1, Vermont VT-87688, Virginia 00440 and 1581, Washington C891, West Virginia 248 and 9957C and E87688, Wisconsin 399013010 Page 1 of 8 Summit Environmental Technologies, Inc. Workorder ffi"'S a _ 3310 Win St. MV11?tit77Of:? "I'ALTECH6N'QLO:G:="Si7NO. Cuyahoga Falls, Ohio 44223 Sample Summary tI'i ,rytrcpl TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 14040178 Website: htto://wwiv.settek.com ll Apr-14 CLIENT: Synagro Project: Sparta Lab SampleID Client Sample ID Tag No Date Collected Date Received Matrix 14040178-001 Sparta 3/28/2014 9:00:00 AM 4/2/2014 11:15:00 AM Sludge Page 2 of 8 t a Summit Environmental Technologies, Inc. Case Narrative ' 3310 Win St. P,4�I dt�9�1Eh1'PCtL SPC�$�•9(}Ltl �.=s; WC. Cuyahoga Falls, Ohio 44223 WO#: 14040178 .+b'Fs3i�trtFG'! `C.sY.airTt�:f TEL: (330) 253-8211 FAX. • (330) 253-4489 Website: huy.-Aviviv.settek.com Date: 4/11/2014 CLIENT: Synagro Project: Sparta This report in its entirety consists of the documents listed below. All documents contain the Summit Environmental Technologies, Inc. Work Order Number assigned to this report. Paginated Report including: Cover Letter, Case Narrative, Analytical Results, Applicable Quality Control Summary Reports and copies of the Chain of Custody Documents supplied with this sample set. Concentrations reported with a J flag in the Qual field are values below the Limit of Quantitation (LOQ) but greater than -the established Limit of Detection (LOD). There is greater uncertainty associated with these results and data should be considered as estimated. Method numbers, unless specified as SM (Standard Methods) or ASTM, are EPA methods. Estimated uncertainty values are available upon request. Any comments or problems with the analytical events associated with this report are noted below. Original Page 3 of 8 Summit Environmental Technologies, Inc. 3310 Win St. WO#: 14040178 - toEbVIRC7Nla11=t1'rl.3L`)i`g��6CdF��.,+j•�i,sS;.5i'�'C' Cuyahoga Falls, Ohio 44223 Date Reported: 4/11/2014 f�'ria#Pt/�a1 Lei'�f�iaalc TEL: (330) 253-8211 FAX.- (330) 253-4489 Company: Synagro Website: hitp://ivwiv.settek.com Address: 284 Boger Rd. Mocksville NC 27028 Received: 4/2/2014 Project#: Sparta TCLP Metals Analysis (6010) Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Sparta 001 3/28/2014 TCLP Arsenic(As) 0.50 ND mg/L Sludge EPA 6010 C 1 5.0 4/8/2014 VVK Sparta 001 3/28/2014 TCLP Barium(Ba) 5.0 ND mg/L Sludge EPA 6010 C 1 100 4/8/2014 VVK Sparta 001 3/28/2014 TCLP Cadmium(Cd) 0.10 ND mg/L Sludge EPA 6010 C 1 1.0 4/8/2014 VVK Sparta 001 3/28/2014 TCLP Chromium(Cr) 0.20 ND mg/L Sludge EPA 6010 C 1 5.0 4/8/2014 VVK Sparta 001 3/28/2014 TCLP Lead(Pb) 0.50 ND mg/L Sludge EPA 6010 C 1 • . 5.0 4/8/2014 VVK Sparta 001 3/28/2014 TCLP Selenium(Se) 0.50 ND mg/L Sludge EPA 6010 C 1 1.0 4/8/2014 VVK Sparta 001 3/28/2014 TCLP Silver(Ag) 0.50 ND mg/L Sludge EPA 6010 C 1 5.0 4/8/2014 VVK TCLP Mercury Analysis (1311/7470) Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Sparta 001 3/28/2014 TCLP Mercury 0.0020 ND mg/L Sludge EPA 7470 A 1 0.20 4/8/2014 ALJ SVOC SW-846: 8081 Pesticides-TCLP Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Sparta 001 3/28/2014 Chlordane, total 0.010 ND mg/L Sludge EPA 8081 B 1 0.030 4/8/2014 JBN Sparta 001 3/28/2014 Toxaphene 0.10 ND mg/L Sludge EPA 8081 B 1 0.50 4/8/2014 JBN Sparta 001 3/28/2014 Endrin 0.0020 ND mg/L Sludge EPA 8081 B 1 0.020 4/8/2014 JBN Sparta 001 3/28/2014 gamma-BHC 0.0020 ND mg/L Sludge EPA 8081 B 1 0.40 4/8/2014 JBN Sparta 001 3/28/2014 Heptachlor 0.0020 ND mg/L Sludge EPA 8081 B 1 0.0080 4/8/2014 JBN Sparta 001 3/28/2014 Heptachlor epoxide 0.0020 ND mg/L Sludge EPA 8081 B 1 0.0080 4/8/2014 JBN Sparta 001 3/28/2014 Methoxychlor 0.0020 ND mg/L Sludge EPA 8081 B 1 10 4/8/2014 JBN VOC by GC/MS (8260)-TCLP Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Sparta 001 3/28/2014 1,1-Dichloroethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.70 4/8/2014 MES Sparta 001 3/28/2014 1,2-Dichloroethane 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 4/8/2014 MES Sparta 001 3/28/2014 Benzene 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 4/8/2014 MES Sparta 001 3/28/2014 Carbon tetrachloride 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 4/8/2014 MES Sparta 001 3/28/2014 Chlorobenzene 0.10 ND mg/L Sludge EPA 8260 B 1 100 4/8/2014 MES Sparta 001 3/28/2014 Chloroform_ 0.10 ND mg/L Sludge EPA 8260 B 1 6.0 4/8/2014 MES Sparta 001 3/28/2014 Tetrachloroethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.70 4/8/2014 MES Sparta 001 3/28/2014 Trichloroethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 4/8/2014 MES Sparta 001 3/28/2014 Vinyl chloride 0.20 ND mg/L Sludge EPA 8260 B 1 0.20 4/8/2014 MES Sparta 001 3/28/2014 MEK 2.0 ND mg/L Sludge EPA 8260 B 1 200 4/8/2014 MES Page 4 of 8 Summit Environmental Technologies, Inc. t- WO#: 14040178 3310 Win St. prkrlpg�},t8#jL�tlg�r��rr=� yNO Cuyahoga Falls, Ohio 44223 Date Reported: 4/11/2014 1dc aE�'tr3sa La`cara��ir,+e TEL: (330) 253-8211 FAX.- (330) 253-4489 Company: Synagro Website: httn://ivivw.settek.com Address: 284 Boger Rd. Mocksville NC 27028 Received: 4/2/2014 Project#: Sparta SVOC 8270 TCLP BNA List Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Sparta 001 3/28/2014 1,4-Dichlorobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 7.5 4/8/2014 AKE Sparta 001 3/28/2014 2,4,5-Trichlorophenol 0.25 ND mg/L Sludge EPA 8270 C 1 400 4/8/2014 AKE Sparta 001 3/28/2014 2,4,6-Trichlorophenol 0.25 ND mg/L Sludge EPA 8270 C 1 2.0 4/8/2014 AKE Sparta 001 3/28/2014 2,4-Dinitrotoluene 0.10 ND mg/L Sludge EPA 8270 C 1 0.13 4/8/2014 AKE Sparta 001 3/28/2014 Cresols, Total 5.0 ND mg/L Sludge EPA 8270 C 1 200 4/8/2014 AKE Sparta 001 3/28/2014 Hexachloro-1,3- 0.10 ND mg/L Sludge EPA 8270 C 1 0.50 4/8/2014 AKE butadiene Sparta 001 3/28/2014 Hexachlorobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 0.13 4/8/2014 AKE Sparta 001 3/28/2014 Hexachloroethane 0.10 ND mg/L Sludge EPA 8270 C 1 3.0 4/8/2014 AKE Sparta 001 3/28/2014 Nitrobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 2.0 4/8/2014 AKE Sparta 001 3/28/2014 Pentachlorophenol 0.25 ND mg/L Sludge EPA 8270 C 1 100 4/8/2014 AKE Sparta 001 3/28/2014 Pyridine 0.25 ND mg/L Sludge EPA 8270 C 1 5.0 4/8/2014 AKE SVOC SW-846: 8321 Herbicides-TCLP Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Sparta 001 3/28/2014 2,4-D 5.0 ND mg/L Sludge EPA 8321 A 1 10 4/8/2014 AMZ Sparta 001 3/28/2014 2,4,5-TP 0.50 ND mg/L Sludge EPA 8321 A 1 1.0 4/8/2014 AMZ Page 5 of 8 Summit Environmental Technologies, Inc. 1- WO#: 14040178 3310 Win St. S EittJl M' i4IUP+1�iJTgL S �'�vt�3 tPi CagvahogaFalls, Ohio 44223 Date Reported: 4/11/2014 Arpralyticat L'qt�4r�5fories TEL: (330) 253-8211 FAX.- (330) 253-4489 Company: Synagro Webslte: hM.-Ilivwiv.settek con Address: 284 Boger Rd. Mocksville NC 27028 Received: 4/2/2014 Project#: Sparta Client ID# Lab ID# Collected Analyte Result Units Matrix Method DF RL Run Analyst Sparta 001 3/28/2014 Flashpoint (140°F) >140 °F Sludge EPA 1010 1 4/3/2014 TJR Sparta 001 3/28/2014 Cyanide, Reactive ND ppm Sludge EPA 9014 1 0.50 4/3/2014 TIR Sparta 001 3/28/2014 pH 13 s.u. Sludge EPA 9045 D 1 4/2/2014 AYS Sparta 001 3/28/2014 Sulfide, Reactive ND ppm Sludge EPA 9034 1 25 4/3/2014 TIR Page 6 of 8 Siimmit Eiivironmental Technologi6, lnc�. r=02 s MM-40111 Ana1v is Reque9t/Chain of Custody 3310 Win Street r-br Suminit 1-:iivironmeiii.ii,Tecliiiolooics, Inc. use only Cuyahogga,Fallg. Ohio, 44223 T81:,330.253.S2-11 Fax--33U53.4489- Page E ofL�._. 'Fs-FrNa ,Qprnpany NwIle (Please Print) Project Name Analy'fical-Paraineters. and M thods Company Address Prpj'ert A-cldnis,,; - A ClientPhoneNo. Reportto'W Client 17ax No: 1, .. e IjIx Results,/ PO# 12 Pleaw ET Client'Email IrAILI-4-03-ID5 L/ Ej Quote -No. e, '8 J3 tgl x— wi Contact Pe'rsorr AA,- y jj,jjfCheck-if Ohio, VAP samples ✓ Ej Sa Identiricalion Date - T Inle ple la I oll ected. Collected 0 U.,a,ct' MOMMEME■MEMEMEN . -Rec6lved b0ahI)y: Mitd rinse Rush Rctpwsted By: Must bcapprovM I L*4P—fIA M. 1 11 . . I . gate I�Yjab �ialiagcr I Wfilicaad yellow rxiges'shouldaccoinpanysamples to the laboratory. MCI Rev. 12 Date: 07/27/13 - SuMhAt Env'tyrQr�mcanfi i Techinclogiesf mt, Cooler Recelpi FE'Ifll 1 Initials of:pers on inspecting cooler and samples:` t Order td ,umbzri Date Received: Time Received: _ ) Date cooler(s) dpsample's inspected: and Number of cololerslB x6SU .erred Shipper: FED EX UP DHL Airborne US Postal Walk in Pickup Other: Packaging: Peanuts (ubble Wr p• Pape Foam None-Oiher: Tape'on`'cooleitb'oxi YD N I_d!A Custody Seals intact NIA C-O-C,in plastid ( N N/A Ice Blue ice .__ prase t / abserii / melied Nlq temple TempeFatiire, 112 Gun * 6P!( 459 CF °G °G ; IJlA Radiological Testing Instrunieni serial ft35127 Y N IfIA (,ee'pa'ge 2 for'scab results) p'Use 1•'sheat per sample for Radiological Testing: immediately. If sample is t-IbY, the Radiological safety Officer must be notified C=O.•C filled out properly N` MIA Samples-in'separate bags y Nl 'Sample containers)ntact" N WA 41' na, list broken sample(s): Sample label(s),complete (ID, date, etc,) (j}. N fl/A Labbl(s) agree Voith C-O=C N MIA Carrectcontainers used By: N MIA Suffident'sampie received � 1 v l N N/A Bubbles absentfromAo mLvlafs- y N1A �Sampteswith bubbles,<6mmare acceptable, IndicatE156bbie.size'if>8mm: Was client contacted about samples Y Id Will client send'new samples y N Client contacts DateTme: Logged in by: G;1QC SHARED1Document Control Templates _TracklhyIG06ler receipt form Rev. 12 07 27-13.doc �age,1 of 2 Page 8 of 8 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Town of Sparta WQ Permit Number: WQ 00006242 WWTP Name: Town of Sparta WWTP NPDES Number: NCO026913 Monitoring Period: From 01/01/ 2014 To 12/31/14 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. l/A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/1) (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens X If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization X Air Drying Composting Aerobic Digestion Anaerobic Digestion If nnnlirahlP fn alfernnfivP nPrfnrmPd Wince A nr Clace Rl rmmnla4a fha fnllnw:na mn 4—i— d.f.- Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2x10 to the 6 1h MPN MPN/g Coliform power per gram of total solids CFU CFU/g 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0 tion/Alt. 1 Option/Alt.2 Option/Alt.3 Option/Alt.4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Mt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) X (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Todd Larson, Operations Director Preparer Name and Title peK)r print v31y Signature of e arer* D e Land Applier Name and Title (if applicable) (type or print) Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and I5A NCAC 2T.1102 (26) CLASS 6/PSRP pH LOG SHEET Using a pH Meter with Two -Point Standardization and Automatic Temperature Compensation (ATC) Probe Analysis Method: SW-846 Method 9040S, jH Electrometric Measurement MONTH/YEAR: 03 - ZS -- 14 FACILITY/LOCATION: ie, vo N o F SP;rJ--44 lti j -P SAMPLING LOCATION: Date Sample Time Sampler Initials PH Testing Start Start pH/ Adjusted 2-Hr.: pH/ Adjusted 24-Hr pH**/ Adjusted Time Temp EC Start pH* Temp EC 2-Hr pH* Temp EC 24-Hr pH* Analyst Initials 2 24 Start Hrs Hrs /-j45�-, .S, g'45; 12.�I� z 12-5& IZ.0�zd lZ.S� �z•�l z-� �a_s� &s. 3_S i�.s. I Equivalent pH value ** If the reading is not at 25EC; Correction Factor (CF) = 0.03 pH units x (EC done 24 hours after the Rtnrt ramp n„ to +ho sr.,o r�„a Temperature measurement- 25EC); Equivalent ,�_+s ,f .. ,+.._C r.r �J LL- J_-- t_I�_-. .. _ .. - . ... pH = Measured pH +/-the,CF. ram, u,c uay wsifjwnicj tllo irnuai sampce sate) the reading was taken. Comments: CLASS 13/PSRP pH LOG SHEET Using a pH Meter with Two -Point Standardization and Automatic Temperature Compensation (ATC) Probe Analysis Method: SW-846 Method 904013,12H Electrometric Measurement MONTHIYEAR: 4) 7- 0G-/- FACILITY/LOCATION: /Q4 64? �S�Gyr�q SAMPLING LOCATION: 7�r ®ate Time Sampler Initials PH Testing Sta ff Time Start pH/ Temp EC Adjusted Start pH* 2-Hr.: pH/ Temp lEC Adjusted 2-Hr pH* 24-Hr pH**/ Temp EC Adjusted24 24-Hr tedpH* S 7AnalysttialsSaratple Hrs Equivalent If the reading pH value is not at 25EC; done 24 hnnrs Correction nftartha Factor (CF) = 0.03 ctn.+'Mynn pH units x (EC Temperature measurement - 25EC); Equivalent pH = Measured DH +/- the CF_ - -- - - --• • •- --•�•• �_� kilo Wilt; vallu date a not performed the day following the initial sample date) the reading was taken, Comments: CLASS 13I]PSIti' pH LOG SST 'Using a pX Meter with. Two -Point Standardization and Automatic 'Temperature Compensation (ATC) Probe Analysis Method: SW-S46 Method 9045ID, Soil And Waste WT MONTE'1%'iJAR: lb 20- Z6FACYI,=/LocAnon / Oi�.aJ`.. t4— JT,plr + cz �✓GV %� SAMPLING LOCATION /�;� .• �-�.- IG�nta 2 Hour ]PR > 12.0 S.U. 24 Hour pH ?17I.5 S.U. .. e 73 i-n fc� °= .0co '° a �y 1m ,E T ^ Initial pl17su Teznp/°C Adjusted 1 Initial PE* p y d �''R M� N °_� �vl y s � '° u 2 ]Ear pH*/su 'Temp/°C Ire Adjusted 2- PEE*/su wG -0 0 � 0, � N N y f � n mrs� a 5 N � ^ U �l Kyiy 24✓JF�x PEVSU Temp/°C Adjusted 24-�x l%�' l5u G Comments: -2s- I Agricultural Lime Application Log Year: 2014 Project: Town of Sparta __ FField (state -county -site -field) NC-AG-6-1 Soil pH 6.4 Lime Requirement (from soil analysis) N/A;: Tons/Acre Applied Date Applied NC-AG-6-2 5.4 1.1 0.5 July 20114* NC-AG-6-5 6.6 N/A> additional lime will be spread on next application of this field (lime -stabilized biosolids) I k NCDA&C —,f nomic Division Phone: (919) 733-2666 Website: www...----:r.gov/a9ronomi[ Report No. F`f -i -z' 034329 u�rr, Client: Stevenson Roten Advisor: Synagro Central �`ar$ Predictive 'i- 230 Orchard Rd. Sparta, NC 28765 Attn:Eric Thompson 284 Boger d } oil Report Mehlich-3 Extraction S„ M cvile, 27028 N Sampled County: Alleghany Sampled: 04/01/2014 Received: 04/28/2014 completed: 05/06/2014 Farm: AG-06 Links to Helpful Information Sample.ID: 01 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2Oe K2O Mg S Mn Zn Cu. B Information Lime History: 1-Fescue/OGrass/Tim, I. 0.0_ 120-200 0 70 0 0 0 0 0 0 Note: 12 2-Fescue/OGrass/Tim, 0.0 120-200 0 70 0 0 0 01 0 0 Note:12 Test Results [units - W/V in g/crap; CEC and Na in meq/100 crrr3; NO3-N in mg/dd]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-1 Zn-AI Cu-I Na ESP SS-1 NO3-N 0.46 0.88 11.8 87 1.5 6.4 69 35 75 11 40 354 224 224 365 365 301 0.1 1 NrJrkh,'Carolina.; A. t +Ti�tiace:o �i�u�tEurcrJ.�boniet6ssleia= Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture is Division -Phone: (919) 733-2665 - Website: www�.,...�r.gov/agronomi/ Report No. Stevenson Roten Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at Ca% % CEC occupied by calcium one time, even if the report recommends more. You can apply the rest in similar increments every six months until the CEC cation exchange capacity full rate is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-I values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-AI2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$; $pH, C or Z M-O mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients• In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium neagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations forsmall areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot pH current soil pH find the exact fertilizer grade recommended on the report, visit www.ncagr.pov/aaronomi/obpart4.htm#fs to find P-1 phosphorus index information that may help you choose a comparable alternate. For more information, readA Homeowner's Guide to Fertilizer P206 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, WN, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index remaining 16 [P-1, K-I, Ca%, Mg%, Mn-1, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-1, SS -I, Na, ESP, SS -I, NO3-N (not Zn-I zinc index routinely available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncaar.pov/aaronomi/uyrst.htm for more information. NCDA&CS=& __� iriomic Division Phone: (919) 733-2655 Website: mT4L.,.Ir.gov/agronomi/ Report No. FY' �-0L006894. 1Texr: ' Client: Stephen Roten Advisor: Synagro Central 4`r Predictive 230 Orchard Rd Attn:Eric Thompson Sparta, NC 28165 284 Boger Rd :.,. Soil Report Mehlich-3 Extraction Sam Mocksville, NC 27028 pled County : Alleghany Wilt Sampled: Received: 09/25/2014 Completed: 10/06/2014 Farm: AG-06 Links to Helpful Information Sample ID: 2 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O6 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, 1 1.1 120-200 0 0 0 0 0 0 0 0 Note: 12 2-Fescue/OGrass/Tim, 0.0 120-200 0 0 0 0 0 0 0 0 Note: 12 Test Results [units -WIV in g/crrr3; CEC and Na in meq/100 crrr3; NO3-N in mg/dd]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2. Zn-1 Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.46 0.88 11.8 80 2.3 5.4 83 80 68 9 47 130 95 95 207 207 188 0.1 1 Nordh,-,Carolina= "gi,�c�c►:�'rusr�F'i�ail:�i�nfiaUsalaa. Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. Steve Troxler, Commissioner of Agriculture NCDA&CSL_, Gnomic Division Phone: (919) 733-2656 Website: www?._-,&r.gov/agronomi/ Report No. FY- 5=5006894 Stephen Roten Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at Ca% % CEC occupied by calcium one time, even if the report recommends more. You can apply the rest in similar increments every six months until the CEC cation exchange capacity full rate is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-I potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Farmers and other commercial producers should pay special attention to m"icronutrient levels. If $, pH$, $pH, C or Z Mn-n- 1 manganese index mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients. In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations forsmall areas, such as home lawns/gardens, are listed in units of lb/1000 sq ft. If you cannot pH current soil pH find the exact fertilizer grade recommended on the report, visit www.ncaar.pov/aaronomi/oboart4.htm#fs to find P-I phosphorus index information that may help you choose a comparable alternate. For more information, readA Homeowner's Guide to Fertilizer. P206 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-At zinc availability index remaining 16 [P-1, K-I, Ca%, Mg%, Mn-1, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-1, SS -I, Na, ESP, SS -I, NO3-N (not Zn-I zinc index routinely available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncaar.pov/aaronomi/uvrst.htm for more information. NCDA&CV- , i:4;nomic Division Phone: (919) 733-2656 Website: www ..- ,r.gov/agronomi/ Report No. FY14-8L032427 . Client: Stevenson Roten Advisor: Synagro Central Predictive 230 Orchard Rd. Sparta, NC 28765..• Attn:Eric Thompson 284 Boger Rd = S' o i l Re„o r Mehlich-3 Extraction N Sampled County: Alleghany Mocksville, NC 27028, - a'YIij7 I;'i ., Sampled: Received: 04/07/2014 completed: 04/16/2014 Farm: AG-06 Links to Helpful Information Sample ID: 05 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O6 K2O Mg S Mn Zn Cu B Information Lime History: 1- Fescue/OGrass/Tim, 1 0.0 120-200 0 0 0 0 pH$ 0 0 0 Note: 12 Note: 2-Fescue/OGrass/Tim, 0.0 120-200 0 0 0 0 pH$ 0 0 0 Note: 12Note: Test Results [units -W/V in g/crrP; CEC and Na in meq/100 ca; NO3-N in mg/drrr3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-1 Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.46 0.91 13.0 91 1.2 6.6 102 81 75 12 31 199 127 127 311 311 232 0.1 1 £ 1Vorlh Carolina.- Toll k o'fii st FUjld-Cnnrikassron Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. Steve Troxler, Commissioner of Agriculture NCDA&CE:.__,0nomic Division Phone: (919) 733-2655: Website: wwwL_-,-r.gov/agronomi/ Report No. FY'i4=aL032427 Stevenson Roten Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Lime If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at one time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate is applied. If MG is recommended and lime is needed, use dolomitric lime. Fertilizer Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear only on reports for greenhouse soil or problem samples. Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH,...0 or Z notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients• In general, homeowners do not need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit ncagr.gov/agronomi/pubs.htm. Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find the exact fertilizer grade recommended on the report, visit www.ncagrpov/agronomi/obPart4.htm#fs to find information that may help you choose a comparable alternate. For more information, readA Homeowners Guide to Fer Test Results The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The remaining 16 [P-I, K-1, Ca%, Mg%, Mn-1, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-1, SS-1, Na, ESP, SS -I, NO3-N (not . routinely available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncaar.pov/aaronomi/uyrst.htm for more information. Report Abbreviations Ac exchangeable acidity B boron BS% % CEC occupied by basic cations Ca% % CEC occupied by calcium CEC cation exchange capacity Cu-I copper index ESP exchangeable sodium percent HM% percent humic matter K-1 potassium index K2O potash Mg% % CEC occupied by magnesium MIN mineral soil class Mn manganese Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index M-0 mineral -organic soil class N nitrogen Na sodium NO3-N nitrate nitrogen ORG organic soil class pH current soil pH P-1 phosphorus index P206 phosphate S-1 sulfur index SS-1 soluble salt index WN weight per volume Zn-AI zinc availability index Zn-I zinc index