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Home My WebLink AboutWQ0003487_Residual Annual Report 2018_20190301CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM WQ PERMIT #: 3487 Novozymes North America, Inc. PHONE: (919) 494-7056 Franklin OPERATOR: Novozymes North America, Inc. FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A(Source(s) and "Residual In" Volume Only) and Part C) El Distribution and Marketing ( complete Parts A, B, and C) Was the facility in operation during the past calendar year? Yes No p ❑ If No skip parts A, B, C and certify form below Part A*: Part B*: Month Sources(s) (include NPDES # if applicable) Volume (dry tons) Recipient Information Amendment/ Bulking Agent Residual In Product Out Name(s) Volume (dry tons) Intended use(s) WAS SBM January 148 130 1097 1375 see attached DMSDF (Supp) February 105 84 1393 1582 see attached DMSDF (Supp) March 107 108 914 1129 see attached DMSDF (Supp) April 138 99 1142 1379 see attached DMSDF (Supp) May 150 56 947 1153 see attached DMSDF (Supp) June 158 22 1210 1390 see attached DMSDF (Supp) July 126 79 820 1025 see attached DMSDF (Supp) August 179 46 1615 1840 see attached DMSDF (Supp) September 186 42 899 1 127 see attached DMSDF (Supp) October 158 73 1031 1262 see attached DMSDF (Supp) November 129 82 887 1098 see attached DMSDF (Supp) December 105 55 829 989 see attached DMSDF (Supp) Total from FORM DMSDF (sup) 0 0 0 0 .................. Totals: Annual (dry tons): 1689 876 1 12784 15349 ........................ 15349 Amendment(s) used: I Hydrated Lime Bulking Agent(s) used: None * If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp)I10 Part C: Facility was compliant during the past calendar year with all conditions of the land application permit (including a] Yes but not limited to items 1-3 below) issued by the Division of Water Quality: ❑No If No, Explain in Narrative 1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached. 2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 3. No contravention of Ground Water Quality Standards occurred at a monitoring well. "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." R �plN�l�`CQIDw Signatu of Permittee Dak Signature of Preparer** Date _ 1 2019 **Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)(if different from Permittee) MAR 0 2019 permittm9 INFORhM D N PROCESSING UNIT DENR FORM DMSDF (12/2006) CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM Supplemental Information WQ PERMIT #: 3487 FACILITY NAME: Novozymes North America, Inc. PHONE: (919) 494-7056 COUNTY: Franklin OPERATOR: Novozymes North America, Inc. FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A - "Month", "Source(s)" and "Residual In" columns only) 0 Distribution and Marketing (complete Parts A, and B) Part A*: Part B*• Month Sources(s) (include NPDES # if applicable) Volume (dry tons) Recipient Information Amendment/ Bulking Agent Residual In Product Out Name(s) Volume (dry tons) Intended use(s) January RICKY AYCOCK 12 Agricultural January JASON AYCOCK 117 Agricultural January DONALD BAKER 45 Agricultural January ROBERT BLACKLEY 75 Agricultural January TALMADGE BURGESS 51 Agricultural January SAM CANNADY 117 Agricultural January GREG HOLTZMANN 76 Agricultural January ROBERT LOYD 219 Agricultural January BETTY MATTHEWS 117 Agricultural January ED MOORE 165 Agricultural January JEREMY PASCHALL 122 Agricultural January DANNY PAYNTER 53 Agricultural January THOMAS PERDUE 118 Agricultural January AL PRIVETTE 81 Agricultural January TOM TRAYLOR 7 Agricultural February DAVID CLARY 10 Agricultural February RC CREECH 128 Agricultural February DAVID DUKE 32 Agricultural Februa JOHN GARRETT 59 Agricultural February ALPHEUS JONES 57 Agricultural February EARLY JOURNIGAN 220 Agricultural Totals: Annual (d tons): 0 0 0 1,881 Amendments us d:j Bulking Agent(s) used: (supp)): Total Number of Form DMSDF (Supp)j 9 * If more space is required, attach additional information sheets (FORM DMSDF DENR FORM DMSDF (Supp) (12/2006) CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM Supplemental Information WQ PERMIT #: 3487 FACILITY NAME: Novozymes North America, Inc. PHONE: (919) 494-7056 COUNTY: Franklin OPERATOR: Novozymes North America, Inc. FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A - "Month", "Source(s)" and "Residual In" columns only) 0 Distribution and Marketing (complete Parts A, and B) Part A*• Part B*• Month Sources(s) (include NPDES # if applicable) Volume (dry tons) Recipient Information Amendment/ Bulking Agent Residual In Product Out Name(s) Volume (dry tons) Intended use(s) February EMERY KEETER 43 Agricultural February DAVID KEMP 270 Agricultural February DOUG MAY 113 Agricultural Februa ED MOORE 105 Agricultural February DANNY PAYNTER 322 Agricultural February THOMAS PERDUE 79 Agricultural February ROBERT SOUTHERLAND 50 Agricultural February JOE THARRINGTON 51 Agricultural February TOM TRAYLOR 42 Agricultural March JASON AYCOCK 285 Agricultural March RC CREECH 22 Agricultural March NATHANIEL DAVIS 27 Agricultural March JAMES DAVIS 38 Agricultural March CRAIG FAULKNER 46 Agricultural March WILSON FLEMING 88 Agricultural March EMERY KEETER 126 Agricultural March DAVID KEMP 176 Agricultural March RANDY MARTIN 34 Agricultural March GREG MAY 14 Agricultural March D A N N Y PAYNTER 1 69 1 Agricultural Totals: Annual (d tons): 0 0 0 2000 Amendments used: Bulking Agent(s) used: * If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp) 9 DENR FORM DMSDF (Supp) (12/2006) CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM Supplemental Information WQ PERMIT #: 3487 FACILITY NAME: Novozymes North America, Inc. PHONE: (919) 494-7056 COUNTY: Franklin OPERATOR: Novozymes North America, Inc. FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A - "Month", "Source(s)" and "Residual In" columns only) 0 Distribution and Marketing (complete Parts A, and B) Part A*• Part B*• Month Sources(s) (include NPDES # if applicable) Volume (dry tons) Recipient Information Amendment/ Bulking Agent Residual In Product Out Name(s) Volume (dry tons) Intended use(s) March LEE SHORT 45 Agricultural March GOINS SNEED 35 Agricultural March ROBERT SOUTHERLAND 9 Agricultural March TOM TRAYLOR 44 Agricultural March LEN WESTER 72 A ricultural April JAMES ALLEN 48 Agricultural April JASON AYCOCK 245 Agricultural April TALMADGE BURGESS 82 Agricultural April SIDNEY BURTON 3 Agricultural April TOMMY BURTON 34 Agricultural April MICHAEL CLOPTON 57 Agricultural April NATHANIEL DAVIS 56 Agricultural April JOHN GARRETT 98 Agricultural April ANDY GARRETT 45 Agricultural April KELLY HARRIS 22 Agricultural April HERMAN HAWKINS 70 Agricultural April ALPHEUS JONES 27 Agricultural April EMERY KEETER 68 Agricultural April DANNY PAYNTER 30 Agricultural April BRIAN PERNELL 1 32 Agricultural April LEE SHORT 43 Agricultural Totals: Annual (dry tons): 0 0 0 1165 Amendments used: Bulking Agent(s) used: * If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp)l 9 DENR FORM DMSDF (Supp) (12/2006) CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM Supplemental Information WQ PERMIT #: 3487 FACILITY NAME: Novozymes North America, Inc. PHONE: (919) 494-3390 COUNTY: Franklin OPERATOR: Novozymes North America, Inc. FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A - "Month", "Source(s)" and "Residual In" columns only) p Distribution and Marketing (complete Parts A, and B) Part A*• Part B*• Month Sources(s) (include NPDES # if applicable) Volume (dry tons) Recipient Information Amendment/ Bulking Agent Residual In Product Out Name(s) Volume (dry tons) Intended use(s) April ROBERT SOUTHERLAND 16 Agricultural April BILL STEVENSON 11 Agricultural April LARRY THOMPSON 16 Agricultural April LEN WESTER 353 Agricultural April LARRY WILLIAMS 22 Agricultural May RICKY ABBOTT 30 Agricultural May TOMMY BURTON 45 Agricultural May DAVID CLARY 64 A ricultral May HERMAN COLLIER 149 Agricultural May BOB FOWLER 250 Agricultural May KELLY HARRIS 28 Agricultural May KAREN JORDAN 12 Agricultural May SAM LEONARD 35 Agricultural May CHARLES LYNCH 66 Agricultural May BILL STEVENSON 100 Agricultural May DARYL THARRINGTON 27 Agricultural May TOM TRAYLOR 96 Agricultural May LEN WESTER 74 Agricultural May LARRY WILLIAMS 109 Agricultural May DWIGHT WILLIAMS 32 Agricultural May BILLY WOOD 37 Agricultural Totals: Annual (d tons): 0 0 0 1572 Amendments used: I I Bulking Agent(s) used: * If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp)l 9 DENR FORM DMSDF (Supp) (12/2006) CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM Supplemental Information WQ PERMIT #: 3487 FACILITY NAME: Novozymes North America, Inc. PHONE: (919) 494-3390 COUNTY: Franklin OPERATOR: Novozymes North America, Inc FACILITY TYPE (please check one): p Surface Disposal (complete Part A - "Month", "Source(s)" and "Residual In" columns only) 0 Distribution and Marketing (complete Parts A, and B) Part A*• Part B*• Month Sources(s) (include NPDES # if applicable) Volume (dry tons) Recipient Information Amendment/ Bulking Agent Residual In Product Out Name(s) Volume (dry tons) Intended use(s) June DANNY BOLTON 138 A ricultual June HUNTER CHOPLIN 66 A ricultual June HERMAN COLLIER 371 A ricultual June BOB FOWLER 199 A ricultual June HENRY NELMS 58 A ricultual June THOMAS PERDUE 23 A ricultual June CLARENCE PHELPS 27 A ricultual June AL PRIVETTE 124 A ricultual June MARTY ROOKER 173 A ricultual June LEE SHORT 20 A ricultual June BILL STEVENSON 19 A ricultual June BILLY WOOD 172 A ricultral July DANNY BOLTON 141 A ricultual July CALVIN BRODIE 20 A ricultual July HERMAN COLLIER 188 A ricultual July FRANK GANTT 31 A ricultual July BENNIE GUPTON 24 A ricultual July JERRY JONES 37 A ricultual July THOMAS KING 9 A ricultual July JUSTIN LEONARD 63 A ricultual July LESLIE LONG 26 A ricultual Totals: Annual (dry tons): 0 0 0 1929 Amendments used: Bulking Agent(s) used: * If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp)l 9 DENR FORM DMSDF (Supp) (12/2006) CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM Supplemental Information WQ PERMIT #: 3487 FACILITY NAME: PHONE: (919) 494-3390 COUNTY: FACILITY TYPE (please check one): L1 Surface Disposal (complete Part A - "Month", "Source(s)" and "Residual In" columns only) 0 Distribution and Marketing (complete Parts A, and B) Franklin North America, Inc. OPERATOR: Novozymes Part A*• Part B*• Month Sources(s) (include NPDES # if applicable) Volume (dry tons) Recipient Information Amendment/ Bulking Agent Residual In Product Out Name(s) Volume (dry tons) Intended use(s) July HENRY NELMS 263 A ricultual July THOMAS PERDUE 18 A ricultual July MARTY ROOKER 16 A ricultual July LEE SHORT 129 A ricultual July DAVID VICK 20 A ricultual July LEN WESTER 29 A ricultual July BILLY WOOD 14 A ricultual August WILSON FLEMING 138 A ricultual August FRANK GANTT 9 A ricultual August BILL GARDNER 65 A ricultual August JIMMY HARRIS 167 A ricultual August GREG HOLTZMAN 29 A ricultual August MATT HORTON 141 A ricultual August EMERY KEETER 46 A ricultual August KEN KREGER 24 A ricultual August LESLIE LONG 35 A ricultual August DALE MOSS 106 A ricultual August MIKE NORWOOD 79 A ricultual August JEREMY PASCHALL 93 A ricultual August JOE RADFORD 79 A ricultual August GLENN RIGGAN 106 A ricultual August LEE SHORT 110 A ricultual August I LARRY SHORT 140 A ricultual August RANDY THOMAS 327 A ricultual Totals: Annual (d tons): 0 0 0 2183 .. Amendment(s) used: Bulking A ent(s) used: * If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp) 9 DENR FORM DMSDF (Supp) (12/2006) CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM Supplemental Information WQ PERMIT #: 3487 FACILITY NAME: Novozymes North America, Inc. PHONE: (919) 494-3390 COUNTY: Franklin OPERATOR: Novozymes North America, Inc FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A - "Month", "Source(s)" and "Residual In" columns only) p Distribution and Marketing (complete Parts A, and B) Part A*• Part B*• Month Sources(s) (include NPDES # if applicable) Volume (dry tons) Recipient Information Amendment/ Bulking Agent Residual In Product Out Name(s) Volume (dry tons) Intended use(s) August TOM TRAYLOR 82 A ricultual August PRESTON WILLIAMS 62 A ricultual September GILLIS ALSTON 50 A ricultual September GLENN COLEMAN 21 A ricultual September HERMAN COLLIER 73 A ricultual September JAMES DAVIS 163 A ricultual September NATHANIEL DAVIS 75 A ricultual September OSCAR DAVIS 44 A ricultual September SPENCER DEAN 80 A ricultual September LEON DILLARD 108 A ricultual September MELVIN EDWARDS 15 A ricultual September FRANK FURLOW 49 A ricultual September JIMMY HARRIS 120 A ricultual September MATT HORTON 97 A ricultual September WOODY KING 19 A ricultual September GLENN RIGGAN 59 A ricultual September TOM TRAYLOR 68 A ricultual September PRESTON WILLIAMS 80 A ricultual September ROBERT WILLIAMS 5 A ricultual October JASON AYCOCK 64 A ricultual October RUSSELL BOTTOMS 39 A ricultual Totals: Annual (dry tons): 0 1 0 1 0 1373 Amendment(s) used: Bulking Agent(s) used: * If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp)l 9 DENR FORM DMSDF (Supp) (12/2006) CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM Supplemental Information WQ PERMIT #: 3487 FACILITY NAME: Novozymes North America, Inc. PHONE: (919) 494-3390 COUNTY: Franklin OPERATOR: Novozymes North America, Inc FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A - "Month", "Source(s)" and "Residual In" columns only) H1 Distribution and Marketing (complete Parts A, and B) Part A*• Part B*• Month Sources(s) (include NPDES # if applicable) Volume (dry tons) Recipient Information Amendment/ Bulking Agent Residual In Product Out Name(s) Volume (dry tons) Intended use(s) October DAVID CLARY 38 A ricultual October SPENCER DEAN 309 A ricultual October JOEL HARRIS 42 A ricultual October STEVE HICKS 30 A ricultual October RANDY MARTIN 30 A ricultual October MIKE NEWTON 52 A ricultual October JEREMY PASCHALL 315 A ricutural October NICHOLAS PEDIADITAKIS 101 A ricutural October MARK PERKINSON 44 A ricutural October SHERBY SLAUGHTER 100 A ricutural October ROBERT SOUTHERLAND 56 A ricutural October TOM TRAYLOR 42 A ricutural November SID COOPER 33 A ricutural November RC CREECH 80 A ricutural November TIM DUKE 24 A ricutural November NOVOZYMES FARM 5 126 A ricutural November WILSON FLEMING 142 A ricutural November JOEL HARRIS 16 A ricutural November ROBERT JOHNSON 16 A ricutural November ALPHEUS JONES 28 A ricutural November DOUG KNUDSON 9 A ricutural Totals: Annual (d tons): 0 0 0 1633 Amendment(s) used: Bulking Agent(s) used: (supp)): Total Number of Form DMSDF (Supp)l 9 * If more space is required, attach additional information sheets (FORM DMSDF DENR FORM DMSDF (Supp) (12/2006) CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM Supplemental Information WQ PERMIT #: 3487 FACILITY NAME: PHONE: (919) 494-3390 COUNTY: FACILITY TYPE (please check one): Franklin North America, Inc. OPERATOR: ❑ Surface Disposal (complete Part A - "Month", "Source(s)" and "Residual In" columns only) 0 Distribution and Marketing (complete Parts A, and B) ca. inc Part A*• Part B*• Month Sources(s) (include NPDES # if applicable) Volume (dry tons) Recipient Information Amendment/ Bulking Agent Residual In Product Out Name(s) Volume (dry tons) Intended use(s) November ROBERT LOYD 90 A ricultual November GREG MAY 109 A ricultual November ED MOORE 60 A ricultual November JEREMY PASCHALL 20 A ricultual November WILLIAM PEOPLES 47 A ricultual November THOMAS PERDUE 208 A ricutural November MARTY ROOKER 15 A ricutural November MIKE SMITH 23 A ricutural November LEN WESTER 51 A ricutural December DANNY BOLTON 141 A ricutural December JEFF CARROLL 100 A ricutural December DONALD EDWARDS 11 A ricutural December CRAIG FALKNER 9 A ricutural December ROBERT FRAZIER 19 A ricutural December DAVID KEMP 86 A ricutural December ROBERT LOYD 39 A ricutural December ED MOORE 137 A ricutural December BARRY MURPHY 259 A ricutural December JEREMY PASCHALL 57 A ricutural December JOE THARINGTON 49 A ricutural December NOVOZYMES FARM 5 82 A ricutural Totals: Annual (d tons): 0 0 0 1612 Amendment(s) used: Bulking Agent(s) used: * If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp)l 9 DENR FORM DMSDF (Supp) (12/2006) ' - - ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: 3487 Laboratory: Facility Name:' Novozymes North America, Inc. Residual Source WQ # or NPDES #: WWTP Name: Recidnnl AnAvcic Dntn' 1) ENCO 2)I` 3)t 4)' 5)' Parameter (mpg) Ceiling Co'nc: Limit Sample or Composite Date Jan Feb Mar Apr May Jun ,, Jul Aug ; 'Sep Oct Nov Dec Percent Solids (%) NA 4.20 4.50 160 4.20 4.40 ' 5.30 , ' 3:90 6.00 4.50 `; 4.70 4.30 4.80 Arsenic 75 .1.62 0.09 1.51 1.89 4.88 1.55 1.68 , ;' 1.95 1.50 1.85 1.62 1.77 1.58 Cadmium 85 0.08 0.10 0.09 0.08 0.07. 0.09 0.06 0.08 0.08 0.08 `; 0.07 Copper, -4,300 10.05 9.93 12.47 16.17 9.75 0.37; . 5.26 7.63 9.29 ' 7.98 3.98 11.29 Chromium ; NA NA NA NA NA NA NA NA NA NA` NA NA - NA Lead . 840 0.74 0.69 1.31 0.87 030 0.58 0.79 0.52 j 0.69 ;. 0'66 '; 0.72 0.65 Mercury 57 0.01 0.02 0.02 0.00 0.02 0.00 0.00 0.01 0:02 0.02 0.02 .' Molybdenum 75 0.62 0.71 1.28 0.64 0.67 0.53 0.64 . 0.72 ' 1'.44 I A& 1.32 139 Nickel 420 1.17 - 1.19 . 2.15 1.46 0:98 0.42 ; 1.20 1.06 ' -1.55 , 1.07, 1.19 -1.10 Selenium 100 1.48 1.38 1.72 1.48 1.41. ' 1.17, _ ; 1.59 1.03 ' 1'.38 " 1.32. 1.44 1.29 Zinc 7,500 20.69 18.29 33:33 29.76 34.09 .3.57 9.08 19.83 19.64 - 43:11 16.26 14.71 Total Phosphorus NA 12,143 13,778 15,000 16,190 17,045 13,019' 12,308 11,167 10,889` 11,702' 15,581 ',10,417 TKN NA 54,762 48,889 41,667 50,000 54,545 47,170 41,026 35,000 44,444 38,298 44J86 -37,500 .Ammonia-Mirogen NA 2,619 1, 1,733 2,222 2,048 3,182 2,642 2,821 16,333 3,111, 3,617 2,047 1,729. Nitrate and Nitrite NA . 1026- 1175 869 917 1048 359 491 5 1407 281 ' 232 603 r a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. I ".I certify, under penalty of law, that this ,document was prepared under ' direction or supervision in accordance with' a'system designed to assure that qualified personnel properly gathered and evaluated the information;submitted. I; am aware' that: there are significant penalt' for submitting false information, including the possibility of fines and imprisonment for knowing violations." a hq I► q ; .� 'Si atur f Preparer * Date *Prepares is defined in 40 CFR Part 503.9-(r) and 15A NCAC 2T .1102 (26) D.ENR FORM RSSF (12/2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B�.� Report all sampling analysis results for parameters'not listed in FORM RSSF that are part of the WQ permit or were analyze6d for over the'past. r calendar'year. Use additional forms as needed.if j aj .�' WQ Per 'I 3487 " Laboratory: i 1) t ENCO ' Facility Facility Name: Novoyzmes North America; Inc. 2) 1, Residual Source'i;' 3)�:�.; . NPDES # or WQ#: I WWTP Name: 5) Residual Anal sis Data i Parameter, l (mg/kg) Sample or Composite Date Jan Feb - Mar Apr I May Jun Jul Aug Sep =Oct IVov • D'ec Aluminum. 7,714- . . 7,044, 9,861 ' 8,162 4,023 228 3,308-' 4,850 .6,42,2 4,298' 2,814 6,292 .Magnesium 1,279. -1,000 1,586 988 1,416 647 6529 . 1,147 1,000 749 1,3.16 1,223 Calcium 75,952 47,556 62,778 57;381 67,273 52,642 ;51,538' 82,167 75,333 70 000 %'1140 64,375 C Potassium 10,476 19,489. 25,667 15;,786 17;182 12,887 13,7,69 9,650 9,644 14;702 ; 13,535, 17,708 Sodium- 7,095 4,467 - 3,417 4,!976 " 3,591 3,151 4,128. ' . 2,3.83 2,073 .2;617 3,209, ; , 8,5.00 PAN .17,455 , - 15,841- 13,369 15,917 17,411 ' 1.4,510 12,798; 10,505. 14,7,40 11J70 13 488 ; 11,853 SAR 1.43 1.17 0.70 1,.15 0.79 0.86 0.98 0.55 ` 0.44 0:5.8 '0.69, • , 1.99 pH - 12.16 12.4 12.25 121.24 12.14. 12.4 1212 12.2 12.4 ' 12.4 . ,i 12.4 12.3 i, I,. If - r - i 1, `I' certify, under penalty of law, that this document was prepared under my direction or supervision in 'accordance ,with a system 'designed to assure that qualified personnel properly gathered and evaluated the information submitted'.' I am' aware; that there are I. ' ;signific alties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 4)q ,it Signa a q0reparer Oate If *Preparer'is defined in 40iCFR Part 503.9(r) and' 15A NCAC j2T .1102 (26) i DEN, FORM RSSF B (12/2006) :, ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Novozymes-North America, Inc. WQ Permit Number: 3487 WWTP Name: NPDES Number: Monitoring Period: From 1/1/2018 ' To 3/31/2018 Pathogen Reduction (15A NCAC 02T .1106) = Please indicate level achieved and alternative performed: Class A: Alt. A (time/tem) ® Alt B (Alk Treatment) ® Alt. C (Prior Testin )EI AIt..ID (No Prior Test) ® Process to Further Reduce. Pathogengs If applicable to alternative.pert`ormed (Class A only) indicate "Process to Further -Reduce Pathogens": Compost 11 Heat Drying ® Heat Treatment 11 Thermophilic Beta Ray 0 am G � ma Ray 11 teuri tion E3 -Pasteurization Class B: Alt. (1) Fecal Density ® Alt. (2) Process .to Significantly Reduce Pathogens p If applicable to alternative performed=(Class-B only) indicate "Process to -Significantly Reduce Pathogens"; - � _ Lime Stabilization El Air Drying El Composting El Aerobic Digestion E7 Anaerobic Digestion n .......................................................................................................................................... . If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g Ty um er.o Excee- Frequency of Analysis Sample Type Analytical Tech-nique MinimumGeo. Mean aximu Units Fecal-Colifonn- 2 x 10 to the 6th power per gram of —total-solids-- MPN 1000 mpri per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) . 3 MPN.per 4 grams total solid (dry weight) <3.0 MPN/4g 0 QTLY G EPA 1682 Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.l'(VS reduction) ® Alt. 2 (40-day bench) D Alt. 3 (30-day bench) ®Alt. 4 (Spec. 02 uptake) CJ Alt. 5 (14-Day Aerobic) El Alt. 6 (Alk. Stabilization R] Alt 7 (Drying - Stable) El I Alt. 8 (Drying - Unstable) El Alt. 9 (Injection) [l Alt. 10 (Incorporation) Lj INo vector attraction reduction alternatives were performed CERTIFICATION. STATEMENT (please check the appropriate statement) L "I certify, -under penalty of law, that- the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ® "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false vertification including fine and imprisonment.", Angela Walsh Environmental Manager - Pre t met -d Titl --(type or -print) - a Sign ure of Preparer* Date Land_ Applier Name--and-Title (ifapplicable)(type -or print) Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) A ,_Facility Name:.- :Novozymes North America, Inc. - -- - WQ Permit Number: 3487 - T WWTP Name: NPDES Number: i Monitoring Period: From 4/1/2018 To 6/30/2018 Pathogen-Reduction-(15ANC-AC 02T .1106) - Please.indicate level achieved and alternative performed- .- Class A: Alt. A (time/tem) ❑ : Alt B (Alk Treatment) ❑ Alt. C (Prior Testin )0 . ................... A1t.D o Prior Test) p - --Process to Further Reduce Patho en s ............. If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathog ens"•-' C_ ompost -❑ - ' Heat D . 'n ®. - Heat Treatment ❑ - Thermo hilic ❑ ❑ Beta Rayamm G a R a aste ion ❑ P unzat Class B: 1Alt, 1) Fecal Density ❑ Alt. 2) Process to SigEficantly Reduce Pathogens ❑, If applicable to alternative performed(Class-B only):iridic�te=��Process�to �Significaritly Reduce Pathogens": =- - __ - ___ Lime Stabilization ❑ Air Drying .. ❑ Composting ❑ Aerobic Digestion ❑ Anaerobic robic Digestion . If applicable •to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level Sludge g Pathogen Density Number oFrequency Excee- of Analysis Y Sample Type . Analytical Tech-ni ue q Minimum Geo. Mean Maximum Unitsenn&q -Fecal Coliform - -. ., - - - 2 x 10 to the 6th power per gram of total solids CFU- — - - -- - 1000 mpn.per-gram. of total solid . - (dry weight) _-- - Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry wei t <3.0 - MPN/4g 0 QTLY G EPA 1682 . Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.1 (VS reduction) , ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. OZ uptake) ❑ Alt. 5 (14-Day Aerobic) ® Alt. 6 (Alk. Stabilization Q Alt 7 (Drying - Stable) ® I Alt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ® Alt. -1.0 (Incorporation) ® No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 15A.-NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." - "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reductionrequirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "-This-determination has- been -made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction. reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Angela Walsh Environmental Manager Prep Name and Title (type -or print) Land Applier Name and Title (if applicable)(type or print) Signatu of Preparer* Da a Signature of Land Applier (if applicable) Date ' *Preparer is defined in 40. CFR Part-503.9(r) and 15A NCAC 2T..1102 (26) - -DENR FORM PVRF 02T (12/2006) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) ,Facility Name: Novozymes North. America; Inc. -.__ ___,__ _ _ : _ __ _ __ ... _. _. WQ-P-_ermit.Number-i - . 3487=_._ - . _ - WWTP Name: - .. � - _ NPDES Number: Monitoring Period• From 7/l/2018 To 9/30/2018 Pathogen Reduction (15A NCAC 02T .1106) - Please -indicate level achieved and alternative nerformed- Class A: Alt. A (time/tem) ❑'. Alt B (Alk Treatment) ❑ . Alt. C (Prior Testing) ` .............. . . . . . . .". . . . . . . . . ................ . AIt:D o Prior Test Li — - - -Process-to Further Reduce Patho en s ❑ If 'applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑- Heat Dryi n - -Heat. Treatment I1 The _rmo-hilic- ❑ - Beta Ra ❑ Gamma Ra ❑ amm Pasteurization - Class B Alt, l Fecal Density--,- ® Alt. (2) Process to Si 'fioaiitl :Re'duce Patlio ens ❑." � `.' .. `" If applicable:fo alternative-performed=(C-lass-B=.only)=indicate-f�Process-to Significantly Reduce-P-a�hogehs"e="=-=T= T- Lime Stabilization Stabilization ❑ Air Drying ryi g Corn osting 11 Aerobic Digestion;11 Anaerobic Digestion estion El ......................................................................................................................:.::::................. . If applicable to -alternative performed (Class A or Class 'B) complete the following monitoring'data: Parameter Allowable Level in Sludge Pathogen Density Number o Excee- enoes Frequency of Analysis Sample Type Analytical Tech-nique Minimum Geo. Mean aximu Units Fecal Coliform =..10.00.mpn.pergram- - 2 x 10 to the 6th power, -per gram of total solids MPN cFu :. of total solid d- --- - - - Salmonella bacteria (in lieu of fecal_ coliform 3 MPN per 4 grams total solid (dry wei ht <3.0 MPN/4g - 0 QTLY _ ,- G EPA 1682 v ector Attraction neutiction (13A 1rl:Au uz I .IIU/ i - Please indicate alternative nertormeci: Alt.I (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-daybench) ❑ jAlt. 4 (Spec. O2 uptake) ❑ Alt. 5 (14-Day Aerobic). ❑ Alt. 6 (Alk. Stabilization, 21 Alt 7 (Drying - Stable) Q jAlt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) ❑ . No vector attraction reduction alternatives were performed ❑ UER I IVIUA I MIN a I ATEIV1L1VT (please check the appropriate statement) -'r "I certify, under penalty of law, that the -pathogen -requirements in 15A NCAC 02T :1106 and the - - , vector- attraction -reduction -requirement in 15A NCAC 02T .-1107-have been met." =_ ❑ . I� "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement. in 15A NCAC 02T .1107 have .not been met:" (Please note if . you check this statement attach an explanation why you have not met one or both of the requirements.) j - "This determination has-been made under my direction and supervision in accordance. with -the systemdesigned to ensure that qualified personnel properly gather and evaluate the'information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant . penalties for false certification including fine and imprisonment." Angela Walsh Environmental Manager - Preps er Name and Title -(type or print) Land Applier Name and Title.(if applicable)(type or print) .-- -- - -_ -.- . i natu of Pr S e arer � . p Date Signature of Land Appher (if applicable), Date -. *Preparer is defined in 40 CFR Part,503.9(r) and 15A NCAC 2T .1102 (26) ANNUAL -PATHOGEN AND VECTOR ATTRACTION REDUCTION YORM, (02T Rules) - -__ Facility Name: - Novozymes_North America, Inc. -- - .__ -_ . ._ _ _ _ _ _ _ WQ. Permit -Number:-- - - 3487 - _. _ _ -W-WTP Name: --- - -= - - = NPDES Number :- Monitoring Period: From 10/l/2018-- - To .12/31/2018 Pathoueir Reduction-(15A NCAC 02T--.-1-106) Please -indicate -level -achieved- and--alternative-nerformed:- • - Class A: Alt. A time/tem) _ ❑ Alt B Alk Treatment p 'Alt. C (Prior Testin )0 A1t.D(No-Prior Test) ❑ Process to Further Reduce Patho ens ❑ ............. If applicable to -alternative -performed (Class A only) indicate ".Process to Further Reduce Pathogens": Compost El` Heat D '❑ 'n -- - Heat Treatment ❑ " Thermo hilic ❑ ............. Beta Ray ❑ Gamma Ra ❑ Pasteurization ❑ �; Class_Bc -Alt, 1 Fecal Densi --❑ - Alt. 2Process-t6-Sigoficantl-Reduce Patho ens 0- Lime Stabilization ❑ _ Air Drying ❑ Co ostin ❑ JAerobic Digestion- ❑ Anaerobic Digestion- - If applicable to alternative performed (Class A or Class-B) complete the.following monitoring data: Parameter Allowable Level .- in Sludge Pathogen Density Number oFrequency Excee- of Analysis Sample Type Analytical Tech-nique Minimum Geo. Mean MaximumUnits Fecal Coliform T 2 x 10 to. the 6th power per gram of total solids MPN eFu 1000 mpn.per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN. per 4 grams total solid (dry weight) <3.0 _ MPN/4g 0 QTLY G EPA 1682 vector Attraction Keouction (13A 1rl:AU tiz i .11U/) - Please indicate alternative nerformed: Alt.I (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt: 4 (Spec. 02 uptake) ❑ Alt. 5 (14-Day Aerobic) ® Alt. 6 (Alk. Stabilization El Alt 7 (Drying - Stable) ® JAIt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) . ® Alt. 10 (Incorporation) ® No vector attraction reduction alternatives were performed Cl UEKIII+'IUATI0iN a'IA'I'EMENT (please check the appropriate statement) "I certify, under penalty.of law, that the pathogen requirements in 15A NCAC 02T .1106 and the — ---vector-- attraction reduction -requirement -in 15A •NCAC-02T .110-7-have been met.'-'-- . "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector *attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if . you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Angela Walsh Environmental Manager Preparer Name and Title (type or print) Land Applier Name and Title (if-applicable)(type or print) , W��j of Preparer* C� gn p Signature of Land Applier (if applicable) Date Si atu *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .l 102 (26)'. DENR FORM PVRF 02T_(12/2006) AKALINE STABILIZATION OF WASTEWATER BIOSOLIDS Facility Novozymes North America Inc. i ' I FFI 96 (SBM Initial) FHG 409 SBM/WAS Initial FHG 407A'(>2 Hour pH) FLF 96',24 Hour pH Date pH �emp*CCorr. Factor Corr. pH Time pH Temp *C Corr. Factor Corr. pH Time pH Temp *C Corr. Factor Corr. pH Time pH Temp * ;; Corr. Factor Corr. pH Time i Operatoi* Initials 3/4/2018 12.14 25.00 0.00 12.14 2:00'PM 12.07 25.00 0.00 12.07 2:00 PM 12.00 25.00 0.00 12.00 4:20 PM socr 3/5/2018 12.1 22.00 -0.09 12.01 4:00, PM socr I 4/19/2018 12.00 25.00 0.001 12.00 9:30 AMI 12.20 25.001 0.00 12.20 9:30AM 12.20 1 25.00 '0.001 12.20 11:30 AM socr 4/20/2018 12.35 24.00 -0.03 12.32 11:00 AM socr i 8/8/2018 11.83 28.00 0.09 , 11.92 9:00 AM 12.25 28.00 0.09 12.34 9:00 AM 12.23 28.00 0.09 12.32 11:00 AM 1 �' socr 8/9/2018 12.10 27.00 ' 0.06 12.16 11:00 AM socr i 10/30/2018 12.11 25 0.001 12.11 11:30 AMI 11.96 25 10.00 11.96 11:30 AM 12.04 1 25' 0,0D 12.04 2:00 PM socr 10/31 /2018 12.13 22.00 -0.09 12.04 12:00 m . socr i . I ' Signature Date � I 4 I' FFI 96, FHG409, and FHG407 readings are from pH probes FLF 96 pH is manually read from lab pH meter within 15 min. of taking sample i i i HOOSIER MI C RO-B I O.L O G' I C A L Ar AN -f L A B O R A T O R Y Testing o Research a Consulting i Multiple Analysis Report Sample:.360731 March 9, 2018 Novozymes N.A. PO Box 576 Franklinton, NC 27525 . RE: PWS ID#: Unavailable Novozymes N.A. 'SBM 77 Perry Chapel Church Rd. Franklinton, NC 27525 �. Dear Sir/Madam: The following are the result(S) of the test(s) performed on the sample(s) received at HML, Inc. at 9:46 AM, 01 /31 /2018, and collected at 9:00 AM; 01 /30/2018: TEST - METHOD RESULT MDL* Date Complete Solids,'total-SM 2546G 3.68% 0.605% 02/07/2018 Salmonella -EPA 1682 <3 MPN/4 g dry 3 MPN/4 g dry 02/02/2018 *Minimum Detection Level This testing was completed by J.B. Please feel free to contact us if we can be of further service to you. Sincerely, Do President - Microbiologist Chemistry Lab #C-18-01 Microbiological Lab #M-18-03 DAH/skp 912 West McGalliard,. Muncie, IN 47303-1702 Phone: (765) 288-1124 Fax: (765) 288-8378 page: 1 E niaiL• 102255:152@cotyipuse"e.cone Web Site: h tp✓/www.hnd.cona j HOOSIER M I C R O B I O L O G I C A L ,Illlllllllll� �, 1 1 L A B O. R A T O R Y Testing ' o Research o Consulting (Multiple Analysis Report Sample: 350732 - - -- - --- -- ------- -- — March 9, 201 t3 Novozymes N.A. PO Box 576 . Franklinton, NC 27525 RE: PWS ID#: Unavailable Novozymes N.A. - - - - — - -- - - - ------ WAS 77 Perry Chapel Church Rd. _---� — Franklinton, NC 27525 Dear Sir/Madam: The following are the result(s) of the tests) performed on the sample(s) received at HML, Inc. at 9:46 AM, 01/31/2018, and collected at 9:00 AM, 01/3012018: TEST - METHOD RESULT MDL* Date Complete Solids, 'total-SM 2540G 1.89.% 0.005% 02/07/2018 Salmonella -EPA 1682 <3 MPN/4 g dry .. 3 MPN/4 g dry 02/02/2018 Helminth Ova-EPA/625/R-92-013 <1 ovum/4 g dry 1 ovum/4 g dry 03/07/2018 *Minimum Detection Level This testing was completed by M.Q. and J.B. Please feel free to contact us'if we can be of further service to you. Sirerely, ((( Donald A. Hendrickson, Ph.D. President - Microbiologist Chemistry Lab #C-18-01 Microbiological Lab #M-18-03 DAH/skp f 912 West McGalharrl, Mancie, IN 47303-1702 .Phone. (76S) 288-1124 Fax. (765) 288-8378 page: 9 __ E +nail.• 102255.152@compuservecont Web Site: hap✓/www1unl.con: H'O O S LER M ICROB I OLOG ICAL ft OF L A B O R A T O R Y Testing, a Research a Consulting Multiple Analysis Report 1 :Sample: 364672 July 17, 2018 Novozymes N.A. PO Box 576 Franklinton, NC 27525 RE: PWS ID#: Unavailable - Novozymes N.A. WAS _I 77 Perry Chapel Church Rd. Franklinton, NC 27525 Dear Sir/Madam: The following are the, result(s) of the test(s) performed on the sample(s) received at HML, Inc. at 9:43 AM, I 05/03/2018, and collected at 9:15 AM, 05/02/2018: TEST - METHOD RESULT MDL* Date Complete Solids, total-SM 2540G 1.49% 0.005% 05/08/2018 Salmonella -EPA 1682 <3 MPN/4 g dry 3 MPN/4 g dry 05/05/2018 Helminth Ova-EPA/625/R-92/01.3 <1 ovum/4g dry 1 ovum/4 g dry 06/06/2018 *Minimum Detection Level This testing was completed by M.Q.'and K.L. Please feel free to contact us if we can be of further service to you. Sincerely, i, Donald A. Hendrickson, Ph.D. President - Microbiologist Chemistry Lab #C-18-01 Microbiological Lab #M-18-03 DAH/skp 912 West McGalliard, Muncie, IN47303-1702 Phone: (765) 288-1124 Fax: (765) 288-8378 page: 1 E-mail. 102255.152@compuservecom Web Site: http.1Avww.hmLcom H O G S I E R M IC ROB 1 U LOG I CA L AW i A B O R A T O R Y Testing a Multiple Analysis Report Sample: 364673 July 17, 2018 Novozymes N.A.. PO Box 576 Franklinton, NC 27525 RE: PWS ID#: Unavailable Novozymes N.A. SBM 77 Perry Chapel Church Rd. Franklinton, NC 27525 Dear Sir/Madam: Research • Consulting The following are the result(s) of the test(s) performed on the sample(s) received at HML, Inc. at 9:43 AM, 05/03/2018, and collected at 9:30 AM, 05/02/2018: TEST - METHOD RESULT MDL* Date Complete Solids, total-SM 264OG 3.58% 0.005% 05/08/2018 Salmonella -EPA 1682 <3 MPN/4 g dry. 3 MPN/4 g dry 05/05/2018 *Minimum Detection Level This testing was completed by M.Q. and K.L. Please feel free to contact us if we can be of further service to you. Sincerely, Donald A. Hendrickson, Ph.D. President - Microbiologist Chemistry Lab #C-18-01 Microbiological Lab #M-18-03 DAH/skp 912 West McGalliard, Muncie, IN 47303-1702 Phone: (765) 2884124 Fax: (765) 288-8378 page: 1 E-mail. 102255.152@compuserve.com Web Site: http✓Avww.hmLcom H O G S I E R M I C R O B I O L O GI C A L L A B O R A T O R Y Testing Research.® Consulting Multiple Analysis Report . Sample 359341 September 13, 2018 Novozymes N.A. PO Box 576 4 Franklinton, N.0 27525 - RE: PWS ID#: Unavailable Novozymes N.A. WAS 77 Perry Chapel Church Rd. Franklinton, NC 27525 Dear Sir/Madam: The following are the result(s) of the test(s) performed on the sample(§) received at HML, Inc. at 10:18 AM, 07/19/2018, and collected at 10:30 AM, 07/18/2018: TEST - METHOD RESULT MDL* Date Complete Salmonella -EPA 1682 <3 MPN/4 g dry 3 MPN14 g dry 07/21/2018 Helminth Ova-EPA/625/R-92-013 <1 ovum/4 g.dry 1.ovum/4 g dry 08/17/2018 Solids, total-SM 2540G 1.51% 0.005% 07124/2018 *Minimum Detection Level This testing was completed by M.Q. Please feel free to contact us if we can be of further service to you. gcerely, Donald A. Hendrickson, Ph.D. -' President - Microbiologist Chemistry Lab #C-1 B-01 Microbiological Lab #M-18-03 DAH%skp 912 West McGalllard, Muncie, IN 47303-1702 Phone: (765) 288-1124 Fax. (765) 288-83.78 page: 9 E-mail: 102255.152@con:puserve.cou: Web Site: hnp.Ilit ww.hnil.com H O O S I E R. MICROBIOLOGICAL - 4-Ar Lj R Y Testing e = Research o Consulting Multiple Analysis Report L A B O R A T O Sample: 369446 September 13, 2018 Novozymes N.A. PO Box 676 Franklinton, NC 27525 RE: PWS ID#: Unavailable Novozymes N.A. SBM 77 Perry Chapel Church Rd. Franklinton, NC 27525 Dear Sir/Madam: The following are the result(s) of the test(s) performed on the sample(s) received at HML, Inc. at 10:40 AM, 07/19/2018, and collected at 10:30 AM, 07/18/2018: TEST - METHOD RESULT MDV Date Complete Salmonella -EPA 1682 <3 MPN/4 g dry 3 MPN/4 g dry 07/23/2018 Solids, total-SM 264OG 3.14% 0.005% 07/24/2018 *Minimum Detection Level This testing was completed by M.Q. and K.L. Please feel free .to contact us if we can be of further service to you. Sind. ,•.., �i:i"'i1.�-.s"1t� • a""" •�Li;iT'� "�.',w' �::�1'�=�+1+i3:'•?K.•`i7:+�='�+.`�5' Donald A. Hendrickson, Ph.D. President - Microbiologist Chemistry Lab #C-18-01 Microbiological Lab #M-18-03 j DAH/skp 912 West McGalliard, Muncie, IN 47303-1702 Phone: (765) 288-1124 Fax: (765) 288-8378 Page: 9 E-mail: 102255.152@compuserve.com Web Site. hap://wivw.hmL con: HOOS IL• R MICROBIOLOGICAL AW 1 L A B O R A T Q R Y Testin g Multiple Analysis Report Sample: 364968 November 16, 2018 Novozymes N.A. PO Box 576 L Franklinton, NC 27525 RE: PWS ID#: Unavailable Novozymes N.A. L SBM 77 PerryChapel Church Rd.- Franklinton, NC 27525 Dear Sir/Madam: Research • Consulting The following are the result(s) of the test(s) performed on the sample(s) received at HML, Inc. at 10:03 AM, 10/17/2018, and collected at 9:00 AM, 10116/2018: TEST - METHOD RESULT MDL* Date Complete Solids, total-SM 2546G 5.25% 0.005% 10/23/2018 Salmonella -EPA 1682 <3 MPN/4 g dry 3 MPN/4 g dry 10/19/2018 *Minimum Detection Level This testing was completed by M.Q. and K.L. Please feel free to contact us if we can be of further service to you. Sincerely, no .President -Microbiologist Chemistry Lab #C-18-01 Microbiological Lab #M-18-03 DAH/skp 912 West McGalliard, Muncie, IN 47303-1702. Phone: (765) 288-1124 . Fax: (765) 288-8378 Page: 1 E-mail: 102255.152@compuserve.copi Web Site. hitp://www.hnAconr H O O s I E R M I CROB I OLOG I CAL AV L A B O R A T O R Y Testing o Research a Consulting Mlultiple Analysis Report Sample: 364969 November 16, 2018 Novozymes N.A. PO Box 576 Franklinton, NC 27525 RE: PWS ID#: Unavailable Novozymes N.A. WAS 77 Perry Chapel Church Rd. Franklinton, NC 27525 Dear Sir/Madam: The following are the result(s) of the test(s) performed on the sample(s) received at HML, Inc. at '10:03 AM, 10/17/2018, and collected at 9:00 AM, 10/1612018: TEST - METHOD RESULT MDL* Date Complete Solids, total-SM 264OG 1.38% 0.005% 10/23/2018 Salmonella -EPA 1.682 <3 MPN/4 g dry 3 MPN/4 g dry 10/19/2018 Helminth Ova-EPA/625/R-92/013 <1 ovum/4g dry 1 ovum/4 g dry 11/16/2018 *Minimum Detection Level This testing was completed by M.O. and K.L. Please feel free to contact us if we can be of further service to you. Sincgr,:�Jy, jeN OW 1ktn;,TV I - Donald k kindrickson,VitD. " President -'Microbiologist . Chemistry Lab #C-18-01 Microbiological Lab #M-18-03 DAH/skp I -912 West McGal lard, Muncie, IN 47303-1702 Phone: (765) 288-1124 Fax: (765) 288-8378 Page: I ,_ E-mail: 102255.152&onipuserve.con: Web Site: I:ttp✓/www.1unLcoin I- - - 2�, EN Q.-.,_'bOr - ' -- — - - -- - - - ---- -- tn a 0 Accurate. � . Timely, Res c� s'fve. Movativea -102-A-Woodwinds.Industrial Court - Cary' NC, 27511 — Phone: 919.467.3090 FAX: 919.467.3515 jThursday, -January 11, 2018 - --- - - - - - Novozymes North America (N0008) - - Attn:. Scott Creech - I 77 PerryChapel Church Road Franklinton, NC 27525 RE: Laboratory Results for Project Number: [none], Project Name/Desc: Monthly - Week One - SSM ENCO Workorder(s): CA19791 Dear Scott Creech, Enclosed is a copy of your laboratory report for test samples received by our laboratory on . Tuesday, January 2, 2018. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. " Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except „ as, noted in the project narrative. This report shall not be reproduced except in full, without, the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation ! Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary.' Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, r-nclosureks) FINAL- - . 'This report relates onlyto'the sample as received by the laboratory, -and may only be reproduced in full. — Page 1 of 12 - i� wwtni.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: SBM Lab ID: CA19791-01 Sampled: 01/02/18 07:15 Received: 01/02/18 11:00 Parameter Hold Date/Time(s) prep Date/Time(sl Analysis Date/Time(s) CSU Method 09/27/20 01/04/18 13:21 01/08/18 14:39 EPA 350.1 01/30/18 01/09/18 12:55 01/09/18 12:55 EPA 351-:2,- 01/30/18 01/08/18 12:40 01/10/18 10:13 EPA 353.2-- ' 01/04/18 07:15 01/02/18 14:41-" 01/02/18 14:41 -EP6353.2 `_ = 09/27/20 01/09/18 13:51 01/09/18 13:56 EPA 365.4 01/30/18 01/08/18 12:40 01/10/18 11:43 EPA 6010D 07/01/18 01/04/18 13:21 01/08/18 12:54 EPA 7470A 01/30/18 01/03/18 10:22 01/04/18 11:27 SM 2540B-1997 01/09/18 01/05/18 15:40 01/05/18 15:40 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 2 of 12 _I Nk� l� www.encolabs.com. SAMPLE DETECTION SUMMARY Client ID: S13M Lab ID: CA19791-01 Analvte Results W2 Hu EQL -Y-Elm Method Notes ' Aluminum - Total 324 0.420 1.00 mg/L EPA 6010D Ammonia as N 110 D 4.5 10 mg/L EPA 350.1 Calcium - Total 3190 0.390 1.00 mg/L EPA 6010D _ Copper- Total 0.422 0.0160 0.100 mg/L EPA 6010D Magnesium - Total - - 53.7 0.290 1.00 mg/L EPA 6010D Molybdenum - Total. - _ 0.0261 J ---0.0250 0r100 mg/L EPA 6010D Nickel'- Total 0.0493 J 0.0220 0.100 mg/L EPA 6010D - - Nitrate as N 43 0.025 0.10 mg/L EPA 353.2 Nitrite as N 0.097 J 0.017 0.10 mg/L EPA 353.2 Phosphorus 510 D 10 40 mg/L EPA 365.4 Potassium - Total 440 1.50 5.00 mg/L EPA 6010D Sodium - Total 298 4.00 5.00 mg/L EPA 6010D Sodium Adsorption Ratio 1.43 [blank] CSU Method _ Total Kjeldahl Nitrogen 2300 D 52 96 mg/L EPA 351.2 Total Solids 4.2 0.25 0.25 % by Volume SM 2540B-1997 Zinc - Total 0.869 0.0440 6.100 mg/L EPA 6010D I FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 12 ANALYTICAL RESULTS Description: SBM Lab Sample ID:CA19791-01 Matrix: Sludge Sampled:01/02/18 07:15 Project: Monthly - Week One - SBM Sampled By:Troy Strand Metals by EPA 6000/7000 Series Methods www.encolabs.com Received: 01/02/1811:00 Work Order: CA19791 ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Iraq Units DF MDL POLL Batch Method Anal yzed By Notes Mercury [7439-97-6]^ 0.000495 U mg/L 5 0.000495 0.00100 BA03013 EPA 7470A 01/04/18 11:27 CMK Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Qry certified analyte [NC 591] Analyte rCAS Numberl Results Has Units RE MPS M Batch Method Analyzed @y Notes Aluminum [7429-90-5]^ 324 mg/L 10 0.420 1.00 8A04007 EPA 6010D 01/08/18 12:54 JDH Arsenic [7440-38-2]^ 0.0680 U mg/L 10 0.0680 0.100 8A04007 EPA 6010D 01/08/18 12:54 JDH Cadmium [7440-43-9]^ 0.00360 U mg/L 10 0.00360 0.0100 8A04007 EPA 6010D 01/08/18 12:54 JDH Calcium [7440-70-2]^ 3190 mg/L 10 0.390 1.00 8A04007 EPA 6010D 01/08/18 12:54 JDH Copper[7440-50-8]^ 0.422 mg/L 10 0.0160 0.100 BA04007 EPA 6010D 01/08/18 12:54 JDH Lead [7439-92-1]^ 0.0310 U mg/L 10 0.0310 0.100 8AO4007 EPA 6010D 01/08/18 12:54 JDH Magnesium [7439-95-4]^ 53.7 mg/L 10 0.290 1.00 8AO4007 EPA 6010D 01/08/18 12:54 JDH Molybdenum [7439-98-7]^ 0.0261 J mg/L 10 0.0250 0.100 8AO4007 EPA 6010D 01/08/18 12:54 JDH Nickel[7440-02-0]^ 0.0493 J mg/L 10 0.0220 0.100 8AO4007 EPA 6010D 01/08/18 12:54 JDH Potassium [7440-09-7]^ 440 mg/L 10 1.50 5.00 8AO4007 EPA 6010D 01/08/18 12:54 JDH Selenium [7782-49-2]^ 0.0620 U mg/L 10 0.0620 0.100 8AO4007 EPA 6010D 01/08/18 12:54 JDH Sodium [7440-23-5]^ 298 mg/L 10 4.00 5.00 BA04007 EPA 6010D 01/08/18 12:54 JDH Zinc[7440-66-6]^ 0.869 mg/L 10 0.0440 0.100 8A04007 EPA 6010D 01/08/18 12:54 JDH Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 5911 Analyte rCAS Numberl Results Flao Units DF MDL POL Batch Method Analyzed Notes Ammonia as N [7664-41-7]^ 110 D mg/L 100 4.5 10 BA09014 EPA 350.1 01/09/18 12:55 JU Nitrate as N [14797-55-8]^ 43 mg/L 1 0.025 0.10 8AO9024 EPA 353.2 01/09/18 13:56 JU Nitrite as N [14797-65-0]^ 0.097 J mg/L 1 0.017 0.10 8A02013 EPA 353.2 01/02/18 14:41 JU Phosphorus[7723-14-O]^ 510 D mg/L 400 10 40 8AO8008 EPA 365.4 01/10/18 11:43 JU Sodium Adsorption Ratio 1.43 [blank] 1 BA04007 CSU Method 01/08/18 14:39 JDH Total Kjeldahl Nitrogen' 2300 D mg/L 200 52 96 8AO8007 EPA 351.2 01/10/18 10:13 JU Total Solids^ 4.2 % by Volume 50 0.25 0.25 BA05010 SM 254OB-1997 01/05/18 15:40 OMR FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 12 www.encolabs.com QUALITY CONTROL_DATA Metals by EPA,6000/7000 Series Methods - Quality Control Batch SA03013 - EPA 245.E Blank (8A03013-BLK1) Prepared: 01/03/2018 10:22 Analyzed: 01/04/2018 10:59 Spike Source - - %REC RPD - AniL1ftD ----- - - - Result-:�Flaa_- .__Units- --Level-. -Result : %REC- -L[mM RPD- Limit Notes, Mercury 9.90E-5 U 0.000200 mg/L LCS (8A03013-BS1) Prepared: 01/03/2018 10:22 Analyzed: 01/04/2018 11:01 Spike Source %REC RPD Anal ttte Result Flag PGL Units Level Result . %REC Limits RPD Limit Notes Mercury 0.00484 01000200 mg/L 0.00500 97 . 80-120 Matrix Spike (8A03013-MS1) Prepared: 01/03/2018 10:22 Analyzed: 01/04/2018 11:06 Source: CB00214-10 Spike Source %REC RPD Analvte" " LL - Result Elm POL Units Level Resu %REC Lipp RPD Limit Notes Mercury 0.00469 0.000200 mg/L 0.00500 9.90E-5 U 94, 75-125 Matrix Spike Dup (8A03013-MSDI) Prepared: 01/03/2018 10:22 Analyzed: 01/04/2018 11:08 Source: CB00214-10 _ r- i i Analvte Mercury Result Flag PMQL Units 0.00454 0.000200 mg/L Spike Source %REC Level Result %REC Limits RPD 0.00500 9.90E-5 U 91' 75-125 3 RPD Limit Notes 25 Post Spike (SA03013-PSI) Prepared: 01/03/2018 10:22 Analyzed: 01/04/2018 11:18 Source: C600214-10 Anal lfte Mercury Result Elan PQL Units 5.87 0200 ug/L Spike Source %REC Level Result %REC Limits RPD 5.00-0.0810 117 75-125 RPD Limit Notes Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch SA04007 - EPA 3005A Blank (8A04007-BLK1) Prepared: 01/04/2018 13:21 Analyzed: 01/08/2018 11:54 Spike Source 9/oREC RPD Anal lt Resul Elan P-M UlD M Level Result %REC Limits RPD Limit Notes Aluminum 0.0420 U 0.100 mg/L Arsenic 0.00680 U 0.0100 mg/L Cadmium 0.000360 U 0.00100 mg/L Calcium 0.0390 U - 0.100 mg/L Copper 0.00160 U 0.0100 mg/L Lead 0.00310 U 0.0100 mg/L Magnesium 0.0290 U 0.100 mg/L Molybdenum 0.00250 U 0.0100 mg/L Nickel 0.00220 U 0.0100 mg/L Potassium 0.150 U 0.500 mg/L Selenium 0.00620 U 0.0100 mg/L Sodium 0.400 U 0.500 mg/L Zinc 0.00440 U 0.0100 mg/L LCS (iA04007-13SI) Prepared: 01/04/2018 13:21 Analyzed: 01/08/2018 11:57 Spike _ Source%REC RPD Anale Result Elan P91 11111its Level Result' %REC Limits RPD Limit Aluminum 2.09 • 0.100 mg/L .2.00 105 80-120 Arsenic 0.206 0.0100 mg/L 0.200 103 80-120 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 5of12, FIIIJ\lCCa - -_ _ www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch BA04007 - EPA 3005A - Continued LCS (BA04007-BSI) Continued Prepared: 01/04/2018 13:21 Analyzed: 01/08/2018 11:57 Spike Source %REC RPD Anal vte _-- Ela4 l'41. lJ�it�- Level Result %REC Limits RPD Notes. Cadmium 0.0204 0.00300 mg/L 0.0200 102 80-120 Calcium __2.12__0.100 ___my/L__ 2.00 106 80-120 _ Copper 0.212 0.0100 mg/L 0.200 106 80-120 Lead 0.205 0.0100 mg/L 0.200 103 80-120 Magnesium 2.10 0.100 mg/L 2.00 105 80-120 Molybdenum 0.207 0.0100 mg/L 0.200 --- - - 103 -- 80-120 Nickel 0.216 0.0100 mg/L 0.200 108 80-120 Potassium 10.7 0.500 mg/L 10.0 107 80-120 Selenium 0.202 0.0100 mg/L 0.200 101 80-120 Sodium 10.8 0.500 mg/L 10.0 108 80-120 Zinc 0.207 0.0100 mg/L 0.200 104 80-120 Matrix Spike (8A04007=MS1)- - - - -- Prepared: 01/04/2018 13:21 Analyzed: 01/08/2018 12:02 Source: CA18659-01 Spike Source %REC RPD Analltte -Result FLU PQL Units Level Result %REC Limits RPD lilllit Notes - Aluminum 2.14 0.100 mg/L 2.00 0.0420 U 107 75-125 Arsenic 0.208 0.0100 mg/L 0.200 0.00680 U 104 75-125 Cadmium 0.0202. _ ._ _ _0.00100 . -- mg/L 0.0200 0.000360-U 101 75-125 Calcium 18.1 0.100 mg/L 2.00 15.9 114 75-125 Copper 0.208 0.0100 mg/L 0.200' 0.00213 103 75-125 Lead 0.210 0.0100 _ mg/L 0.200 0.00310 U 105 75-125 Magnesium 5.74 0.100 mg/L 2.00 3.39 118 75-125 Molybdenum 0.211 0.0100 mg/L 0.200 0.00250 U 105 75-125 Nickel 0.207 0.0100 mg/L 0.200 0.00220 U 104 75-125 Potassium 15.2 0.500 mg/L 10.0 4.54 106 75-125 Selenium 0.213 0.0100 mg/L 0.200 0.00620 U 106 75-125 Sodium 25.9 0.500 mg/L 10.0 15.3 106 75-125 Zinc 0.251 0.0100 mg/L 0.200 0.0439 104 75-125 Matrix Spike Dup (BA04007-MSD1) Prepared: 01/04/2018 13:21 Analyzed: 01/08/2018 12:33 11 Source: CA18659-01 Spike Source %REC ;RPD Anal Result Elan PQL units Level Result %REC Limits RPD LjM t` Aluminum 2.06 0.100 mg/L 2.00 0.0420 U 103 75-125 4' 20 Arsenic 0.200 0.0100 mg/L 0.200 0.00686 U 100 75-125 4 20 Cadmium 0.0200 0.00100 mg/L 0.0200 0.000360 U 100 75-125 1 " 20 Calcium 18.0 0.100 mg/L 2.00 15.9 109 75-125 0.6. 20 Copper 0.204 0.0100 mg/L 0.200 0.00213 101 75-125 2' 20 Lead 0.199 0.0100 mg/L 0.200 0.00310 U 100 75-125 5, 20 Magnesium 5.48 0.100 mg/L 2.00 3.39 104 75-125 5 20 Molybdenum 0.202 0.0100 mg/L 0.200 0.00250 U 101 75-125 4 20 Nickel 0.207 0.0100 mg/L 0.200 0.00220 U 104 75-125 0.1 20 Potassium 15.2 0.500 mg/L 10.0 4.54 107 75-125 0.05 20 Selenium 0.204 0.0100 mg/L 0.200 0.00620 U 102 75-125 4 20 Sodium 25.9 0.500 mg/L 10.0 15.3 106 75-125 0.1 20 Zinc 0.249 0.0100 mg/L 0.200 0.0439 103 -75-125 0.8 - '20 FINAL - This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 6 of 12 C0 f WWW.encolabs.com- CONTROL DATA ------ - - - - - -- -- -- - - - Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 8A04007 - EPA 3005A -Continued Post Spike (SA04007-PSI) Prepared: 01/04/2018 13:21 Analyzed: 01/08/2018 12:36 Source: CA18659-01 - Spike Source %REC RPD Analyte - - -Result --Elan- -PQL-- Units--- -Level - -Reiait"' %REC 'Limits -RPD._._ - Limft Notes Aluminum 2.03 0.100 mg/L 2.00 0.00332, 102 80-120 Arsenic 0.211 0.0100 mg/L 0.200 -0.000265 105 80-120 Cadmium 0.0210 -0.00100 mg/L 0.0200 7.22E=5 105 80-120 - Calcium - - - 18.1 0.100 mg/L 2.00 15.9 111 80-120 " Copper 0.215. 0.0100 mg/L 0.20.0 0.00213 106 80-120 Lead 0.216 0.0100 mg/L 0.200 -0.000423 108 80-120 Magnesium 5.44 0.100 mg/L 2.00 3.39 103 80-120 Molybdenum 0.214 0.0100 mg/L 0.200 0.000612 107 80-120 Nickel 0.217 0.0100 mg/L 0.200 0.000566 108 80-120 Potassium 15.4 0.500 mg/L 10.0 4.54 108 80-120 Selenium 0.216 0.0100 mg/L 0.200 -0.00851 108 80-120 'Sodium. :_ ._ _ -26.0 �-0.500_.-'- --,mg/L-- . - ._40.0 _.. _ _15:3. -807120----_-- _ Zinc 0.260 0.0100 mg/L 0.200 0.0439 108 80-120 Classical Chemistry Parameters - Quality Control Batch 8A02013 - NO PREP Blank (BA02013-BLK1) Prepared: 01/02/2018 14:37 Analyzed: 01/02/2018 14:37 Spike Source %REC RPD AnalYts Result Flan PQL Units Level Result %REC Limits RPD Limit Notes Nitrite as N 0.017 U 0.10 mg/L 'LCS (BA02013-B51) Prepared: 01/02/2018 14:36 Analyzed: 01/02/2018 14:36 Spike Source %REC RPD ABalYte Resuult Elan POL units Level Result %REC Limits RPD Lima Notes Nitrite as N 0.97 0.10 mg/L 1.00 97 90-110 LCS (BA02013-BS2) Prepared: 01/02/2018 14:50 Analyzed: 01/02/2018 14:50 Spike Source 0/aREC RPD AnalResult EJa4 PQL Units Level Result %REC - Limes RPD Limit Notes Nitrite as N 0.98 0.10 mg/L 1.00 98 90-110 Matrix Spike (BA02013-MS3) Prepared: 01/02/2018 14:39 Analyzed: 01/02/2018 14:39 Source: CA19790-01 Spike Source %REC RPD AnalYte Result Elm PQL units Level Result %REC Limits RPD Limit Notes Nitrite as N 1.1 0.10. mg/L 1.00 0.11 96 90-110 Matrix Spike Dup (BA02013-MSD1) Prepared: 01/02/2018 14:40 Analyzed: 01/02/2018 14:40 Source: CA19790-01 Spike Source %REC RPD Anande Result Etas EM units Level Result %REC Limits RPD' Limit Notes Nitrite as N 1.1 0.10 mg/L 1.00 0.11 99 90-110 3 . 10 Batch 8A04007 - EPA 3005A Blank (8A04007-BLKI) Prepared:.01/04/2018 13:21 Analyzed: 01/08/2018 14:39 Spike Source %REC RPD Anal Yte Result flag. POL !!nits Level Result 0/aREC Limits RPD Limit Notes FINAL This report relates only -to the sample as received by the laboratory, and may only be reproduced in full. Page 7 of-12 cemw www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 8AO4007 - EPA 3005A - Continued Blank (8A04007-BLK1) Continued Prepared: 01/04/2018 13:21 Analyzed: O1/08/2018 14:39 Spike Source %REC RPD Anal vtg _- ' - Bes6lt Flan PQL Units Level Result %REC LLimits RPD Limit Notes Sodium Adsorption Ratio 0.00 U [blank] Batch 8AO5010 - NO PREP Blank (8A115010-BLKi) - Prepared & Analyzed: 01/05/2018 15:40 Spike Source %REC RPD Analyte Result Flag PQL Unit£ Level Result %REC Limits RPD Limit Notes Total Solids 0.0050 U 0.0050 % by Volume LCS (BA05010-BSI) Prepared & Analyzed: O1/05/2018 15:40 Spike Source %REC RPD Anal Result Elan POL !!Oita Level Result %REC Limits RPD Limit Notes Total Solids 1100 50 mg/L 1100 102 80-120 Duplicate (8A05010-DUP3) Prepared & Analyzed: 01/05/2018 15:40 Source:CA19790-OS Spike Source %REC RPD Anal lde Resin Elan PAL Unite Level Result o/aREC Limits RPD Lima Notes Total Solids 0.23 0.0050 % by Volume 0.23 0.6 20 Batch 8A08007 - Same Blank (SA08007-BLK1) Prepared: 01/08/2018 12:40 Analyzed: 01/10/2018 09:31 Spike Source %REC RPD AnalYle Results Elm POL Units Level Resul %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 0.26 U 0.48 mg/L LCS (8A08007-BSI) Prepared: O1/08/2018 12:40 Analyzed: O1/10/2018 09:33 Spike Source %REC RPD Anal lde Result Flag M Units Level Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 11 . 0.48 mg/L 11.9 96 90-110 Matrix Spike (8A08007-MSi) Prepared: 01/08/2018 12:40 Analyzed: 01/10/2018 09:37 Source: CA18659-01 Spike Source %REC RPD AnalResult Flag M UJIM Level Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 4.4 0.48 mg/L 4.75 0.26 U 93 90-110 Matrix Spike (BA08007-MS2) Prepared: O1/08/2018 12:40 Analyzed: 01/10/2018 09:42 Source: CA18661-01 Spike Source %REC RPD Ana11ltg Result Mu POL Units Level Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 4.4 0.48 mg/L 4.75 0.26 U 93 90-110 Matrix Spike Dup (8A08007-MSDI) Prepared: O1/08/2018 12:40 Analyzed: O1/10/2018 09:38 Source: CA18659-01 Anal Total Kjeldahl Nitrogen Batch 8A08008 - Same - FINAL ... Spike Source %REC Result Flea PQL Units Level Result ' %REC Limits RPD 4.5 0.48 mg/L 4.75 0.26 U 95 90-110 2 This report relates only to the sample as received by the laboratory, and may only be reproduced in full. RPD Limit !Votes 10 Page 8of12 C 9 W..e www.encolabs.com. QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 8A08008 -Same -Continued Blank (SA08008-BLK1) _ . Prepared: 01/08/2018 12:40 Analyzed: 01/10/2018-11:15 Spike Source %REC RPD " - -Analyze - - - ----Result- -Flag; -P91 Units --.Level- Result %REC- Limits- -RPD-" Limit Notes - - `, Phosphorus 0.025 U 6.10 mg/L LCS (SA08008-BS1) Prepared: 01/08/2018 12:40 Analyzed: 01/10/2018 11:16 i Spike Source %REC RPD Anal 7de Resul Flan P_QL Units Level Result' %REC Wilts RPD limit Notes Phosphorus 13 0.10 mg/L 1.60 . 106 80-120 Matrix Spike (8A08008-MS1) Prepared: 01/08/2018 12:40 Analyzed: 01/10/2018 11:19 Source: CA18659-01 Spike Source %REC RPD Analvte Result Flaa PP 6 Units "Level „ Result, %REC Limits RPD limit Notes - - - Phosphorus - 0.79 '0.10- mg/L 0.640 0.16 98- 80-120 Matrix Spike Duo (8A08008=MSD1) Prepared: 01/08/2018 12:40Artalyzed: 01/10/2018 11:21 I „ Source: CA18659-01 .. i -- Spike Source %REC RPD Anal vte Result Elan, PQL Units Level Result %REC Limits RPD Limit Notes Phosphorus 0.79 '0.10mg/L 0.640 0.16 99 80-120 0.9. 25 I i Batch 8A08021- NO PREP LCS (SA0811il BSc) Prepared: 01/09/2018 09:07 Analyzed: 01/09/2018 09:07 Spike Source %REC RPD Anallde Result Elan PM Units Level Result %REC Limits RPD limit Notes Nitrate/Nitrite as N i 1.3 0.10 mg/L 1.25 101 90-110 Duplicate (SA08021-DUPi) Prepared: 01/09/2018 10:14 Analyzed: 01/09/2018 10:14 Source: CA18751-01RE1 \ Spike Source %REC RPD J r- Anabtte Result Flagg P_QL Units Level Result %REC Limits RPD limit Notes Nitrate/Nitrite as N 68 D 8.0 mg/L 68 .0.005 10. Matrix Spike (8A08021-MS3) Prepared: 01/09/2018 09:10 Analyzed: 01/09/2018 09:10 Source: CA16627-01 Spike Source %REC RPD Anal lf#e Result Ela4 P9L Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N r 120 10 mg/L 50.0 60 121 90-110 QM-07 _ ' Matrix Spike (8A08021-MS2) Prepared: 01/69/2018 09:16 Analyzed: 01/09/2018 09:16 Source: CA16628-01 I rr Spike Source %REC RPD Anal vte Result Ela4 ' P9L Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 89 10 mg/L 50.0 34 112 90-110 QM-07 Matrix Spike Dup (BA08021-MSD1) Prepared: 01/09/2018 09:12 Analyzed: 01/09/2018 09:12 Source: CA16627-01 AnalYte Nitrate/Nitrite as N Batch 8A09014 - NO PREP Spike. Source %REC IRPD Result Elan P4L Units Level Bed %REC Limits RPD Limit Notes 120 10 mg/L 50.0 60 119 90-110 0.8 10 QM-07 r--I FINAL This, report relates only to the sample as received -by the laboratory; and may onlybe reproduced in full: r '--- ---- Page 9 of 12 - www.encolabs.com QUALITY CONTROL. DATA Classical Chemistry Parameters - Quality Control Batch SAOPO14 - NO PREP - Continued Blank (8A09014-BLKI) Prepared: 01/09/2018 12:21 Analyzed: 01/09/2018 12:21 Spike Source %REC RPD Anal vte Result flan PQL Units Level Result %REC Limits RPD Limit Notes Ammonia as N 0.045 U 0.10 mg/L LCS (SA09014-BSI) Prepared: 01/09/2018 12:23 Analyzed: 01/09/2018 12:23 Spike Source %REC RPD Anal Result Elm P91 Units Level Result %REC Limits RPD Limit Notes Ammonia as N 1.0 0.10 mg/L 0.989 101 90-110 Matrix Spike (SA09014-MS3) Prepared: 01/09/2018 12:27 Analyzed: 01/09/2018 12:27 Source: CA14788-01 Spike Source %REC RPD Analyte R su t Flan Ply Units Level Result %REC Limits RPD Limit Notes Ammonia as N 88 10 mg/L 39.6 46 106 90-110 Matrix Spike (SA09014-MS2) Prepared: 01/09/2018 12:32 Analyzed: 01/09/2018 12:32 Source: CA18751-01 Spike Source %REC RPD Analvte Result Ela_4 POL Units Level Result %REC Limits RPD Limit Notes Ammonia as N 12 2.0 mg/L 7.92 4.3 96 90-110 Matrix Spike Dup (SA09014-MSD3) Prepared: 01/09/2018 12:28 Analyzed: 01/09/2018 12:28 Source: CA14788-01 Spike Source %REC RPD Anal vte Result Elan P-01 Units Level Result %REC Limits RPD Limit Notes Ammonia as N 87 10 mg/L 39.6 46 101 90-110 2 10 i FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 10 of 12 NCO www.encolabs.com -FLAGS/NOTES AND_DEFINITIONS- B The analyte was detected in the associated method blank. . . D The sample was analyzed at dilution. --] - - =---The_reported _value:is-between-the_laboratory method- detection limit (MDL) and the laboratory_ method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable: _ U The analyte was analyzed for but not -detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration, indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method. Reporting Limit. The MRL is, roughly equivalent to the practical quantitation.limit (PQL) and is based on the low point of the calibration. curve, when applicable, sample preparation factor, dilution ' factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. IN The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to makea' "tentative identification". - P Greater than 25%concentration difference was observed between the primary and secondary GC'column. The lower concentration is reported. QM-07 The spike recovery was outside acceptance limits.for the MS and/or MSD- The batch was accepted based on acceptable LCS recovery. j I. 1 FINAL This report relates only to the'sample as received by the laboratory, and may only.be reproduced in full: Page 11 of 12 ENVIRONMENTAL CONSERVATION LABORATORIES CHAIN -OF -CUSTODY RECORD 10775 Central Port Dr. - 481C Executive Park Court Suite i i 1 102-A Woodwinds Industrial Ct. Orlando. FL 32824 Jacksonvyte, FL 32216-6069. Cary, NG 27511 (407) 626-S314 Fax (407) 850-6945 (904) 296-3007 Fax (934) 2964210 (919) 467-3090 Fax (919) 467.3515 www.encolabs.c®lrr>I Page Of Client Name ct{Y Ptajeumber Requested Analyses Requested'Tumaround Times Note: Rush requests subject to acceptance by the facility Standard . :_ Expedited - Due. z Y ` U Q. N � o G +- ® E _ C!I {� e '13 m - _ - Address 77- Per Cne pol Church Read Prajec NamcfDz sc M-3nth} - %W 6, One �:8 1� CityfST(Zip Frartkrntor? f C: 275i5 PO 0I Wring Into W'0030",)1 Tel cc 1 ci t94- 3tiip Fax -Reporing Contact S:,e` t Gt �ec3 Sample s) Name. Affiliation (Print) - Billing Contact - Sa+tlp9a s�,` gnature - - - Ste Location / Tme Zone tab Workorder - - Preservation (See Codes) (Combine ar. necessary) r Item 9 Sample i0 (Feld ldent1cafion) CohectionlDate Collection - Tuna Compiamb - PRasr x Total ci (s€e codes} camlV of f Sample Comments �Y �/ ' �j' e/ I 1ij ; <—Total # of Cnntainers Sample Kit Prepared By Oate me Relinquist4ed By Cat !rime Received ty Date//�rim(e � Commonts Special Reporting Requirements E inq`s ed4 i 1 Date�mee Received By / Ilk- Datefrime . - - - P.elinquished.6y, - Datemnte qeceivad By -. Dater.rime - Cooler 0's 8 Temps on Receipt- Condition Upon Receipt acceptable — Unacceptable Matrix: GW-Groundwator SO -Solt DIN-DrinkingWater 5t-Semment .5av-6urrace wean; ............. j ..��_..- _ ........ _ .._ ...._.. _ _..._. - Note : Ali samples submitted to UtCO LZs see in acco?dance Wlh the terms and conditions fisted on the reveere of this form, unless prior Written agreements exist - - -Sample Preservation Verification ENCO Cary Work Order: CA19791 Project: Monthly - Week One - SBM Client: Novozymes North America (N0008) Project #: [none] Logged In- 02-Jan-1 8 11:26 Logged By: John C King Preservation Check Performed By, Date/Time: 1-2'ee 12Z&-I =_CA19791.w01-_-_-- Cons , Type pH, Checked L pH juste Dateme 4, e Re'quire F,6 d' A 25OmLP+H2SO4 <2 Y /T/ NA NA B. 250 m,LP+HNO3 <2 YT l NA g Y fl/ NA MC' pev" 5 Reagent Name, 'ID Reagent Name ID 3 - - C/ __V_4u:00 3 . i, 2 41 pH Strip ID: r%71=3 RAKMD M-L, M se auonG"eck.rpE----------- Reaqent Name ID Page 1 of 1 - - - -ENIC', -0 tori ... .4, e._ -ion _ 102-A Woodwinds Industrial Court _ I Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3.515 - - -- -- --- -- - - - =- ---=_ _ -_-- -=- Thursday_, January 11, 2018 ---- - - - ----- - --- - -- ' - - -- - - =-- -- - - - • Novozymes North America (N0008) Attu:' Scott Creech - 77 Perry Chapel Church Road Franklinton, NC 27525 Ili . RE: Laboratory Results for Project Number: [none], Project Name/Desc: Monthly.- SBM ENCO Workorder(s): CA19789 Dear Scott Creech, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Tuesday, January 2, 2018.. Unless otherwise noted in an attached project narrative; all samples were received.in. acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are incompliance with, NELAC standards, except �j as noted in the project narrative. This report.shall not be reproduced except in full,' without. „ f the written approval of the Laboratory. . This report:contains only those.analyses performed by Environmental Conservation Laboratories: Unless otherwise noted, all analyses were performed at ENCO Cary: Data from - outside organizations will be reported under.separate cover. If you have any questions or require further information, please 'do not hesitate to contact.me. ti Sincerely, �i Chuck Smith Project Manager Enclosure(s) I FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in'full. Page 1 of 8 • - ' -I - - -- - - - - - - -- --- -- - -- - www.encolabs.com SAMPLE _SUMMARY/ LABORATORY CHRONICLE_ Client ID: SBM Sampled: 01/02/18 07:15 Received: 01/02/18 11:00 Lab ID: CA19789-01 Parameter Hold Date/Time(s). Prep Date/Time(s) Analysis Date/Time(s) SM 254OD-1997 01/09/18 01/09/18 15:00 i 01/09/18 15:00 SM 5210E-2001 0_1/04/18 ___07:15 _ __ = 01/03/18 14:42 01/03/18 14:42 - SM 52201D=1997 01/30/18 01/08/18 12:05 01/08/18 16:45 I FINAL-- - - - --------This report relates only to the sample as received by the laboratory, and may only be reproduced in full. - - Page 2 of 8 Client ID: SBM Analvte Biochemical Oxygen Demand Chemical Oxygen Demand Total Suspended Solids I www.encolabs.com SAMPLE DETECTION SUMMARY Lab ID: CAL9789-01 Results fW9 MDR, P_Q.6 Units Method Notes 6800 2.0 2.0 mg/L SM 5210E-2001 28000 800 800 mg/L SM 5220D-1997 24000 2500 2500 mg/L SM 2540D-1997 FINAL - This report relates only to the sample as received by the laboratory, and may only.be reproduced in full. Page 3 of 8 EGG www.encolabs.com ANALYTICAL RESULTS Description: SBM Lab Sample IWCA19789-01 - Received: 01/02/18 11:00 Matrix: Sludge Sampled:01/02/18 07:15 Work Order: CA19789 Project: Monthly - SBM Sampled By:Troy Strand Classical Chenhistry Parameters ^ - ENCO Cary certified anatyte [Nc 5911 ' Analvte r6S Numberl- — - Results Flaa nits DFF MDL PP L- Batch . MethodAnalyzed By Notes Biochemical Oxygen Demand^ 6800 mg/L 1 2.0 2.0 BA03014 SM 521OB-2001 01/03/18 14:42 30C Chemical Oxygen Demand^ 28000 mg/L 80 800 800 8AO8013 SM 5220D-1997 01/08/18 16:45, 30C . Total Suspended Solids^ 24000 mg/L 1000 2500 2500 BA09012 SM 2540D-1997 01/09/18 15:00 OMR ` �J FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. i1 Page 4 of B ' Ilk www.encolabs.com -- QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Gntrol Batch 8A03014 - NO PREP Blank (SA03014-BLK3) Prepared & Analyzed: 01/03/2018 14:42 i Spike Source %REC RPD HeSult- -FJa9' T-E41- - lln114- --- Level - --Besul ---- "/oREC--- Limits-- --RPD _ - LiMiL -- -- Noun _. ` Biochemical Oxygen Demand 2.0 U 2.0 mg/L LCS (SA03014-BS1) Prepared & Analyzed: 01/03/2018 14:42 — Spike Source %REC RPD Analvte Result Elan POL Units Level Result %REC Limits RPD Limit Notes Biochemical Oxygen Demand 170 2:0 mg/L 198 .. 88 85-115 Duplicate (8Ao3014-DUP3) Prepared & Analyzed: 01/03/2018 14:42 Source: CA16600-03 Spike Source %REC RPD . Anal vte Result Ela9 POL Units Level Result %REC Limits RPD Lim(t Notes Biochemical Oxygen Demand 250 2.0. mg/L 240 3 30, Batch 8AOBO13 - Same Blank (BA08013-BLKl) Prepared: 01/08/201.8 12:05 Analyzed: 01/08/2018 16:45 Spike Source %REC RPD . Anal Result Elas P_QL U ift Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 10 U 10 mg/L LCS (8A08,913-1151) Prepared: 01/08/2018 12:05 Analyzed: 01/08/2018 16:45 Spike Source %REC RPD Anal Xte Result Elm PAL Units Level Result %REC Limits RPD Limit' Notes Chemical Oxygen Demand 490 10 mg/L 500 . 97 90-110 Matrix Spike (BA08013-MS1) Prepared: 01/08/2018 12:05 Analyzed: 01/08/2018 16:45 Source: CA15892-01 Spike Source %REC RPD .AnaLlLtf: Result Elan P_QL Units , Level Result "/oREC Limits RPD Limit Notes Chemical Oxygen Demand 2500 40, mg/L 2000 530 97 90-110 Matrix Spike Dup (SA08013-MSD1) Prepared: 01/08/2018 12:05 Analyzed: 01/08/2018 16:45 Source: CA15892-01 i Spike Source %REC RPD Ana11lte Result Elan PQL Units Level Result '/oREC Limits RPD Limit ." Notes . ..' Chemical Oxygen Demand 2500 40 mg/L 2000 530 98 90-110 0.7 10 Batch 8AO9012 -NO PREP Blank (BAC9012-BLK3) Prepared & Analyzed: 01/09/2018 15:00 ! Spike Source %REC RPD 1, Anal lt Result Eiag' PAL U 1111S Level Resul %REC Limits RPD Limit Notes Total Suspended Solids 2.5 U 2.5 rig/L LCS (8A09012-BS1) Prepared & Analyzed: 01/09/2018 15:00 Spike Source %REC RPD Analyte Result Elan. P4L Units Level Result. %REC LiMMtS:. RPD ' Lim!! Notes . Total Suspended Solids 93 . 2.5 mg/L 100 93 80-120 FINAL - _ -. _-.• . -This report relates only to thesample as received by.the laboratory,.and may only be.reproduced' in full. - Page s of B-'- www.encolabs.com QUALITY -CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 8AO9012 - NO PREP - Continued Duplicate (8A09012-DUP1) Prepared & Analyzed: 01/09/2018 15:00 Source: CA18730-01 Spike Source %REC RPD -- - _ ----.ADaly_te -- - -. -- _Result —Elsa - - POL- _ - _ Units - Level- Result _ o/aREC- _ Limits RPD Limit Total Suspended Solids 6600 250 mg/L 3900 51 20 QM-12 Duplicate (8A09012-DUP2) Prepared & Analyzed: 01/09/2018 1500 Source: CA18892-01 Spike Source %REC RPD - Analvte Resul Elaa POL units Level Result %REC Limits RPD Limit Notes Total Suspended Solids 320 50 mg/L 310 1 20 1 FINAL- - -This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 6 of 8 I 41 . Ilk C M M Nei- www.encolabs..com. FLAGS/NOTES AND DEFINITIONS . : B The analyte was detected in the associated method blank. - _ . _. D The sample was analyzed at dilution. -- - 7 : The reported,value is between the laboratory method detection limit (MDL):and the, laboratory method reporting limit'(MRL), adjusted for actual sample preparation.data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level-shown,.adjusted for actual sample preparation '- data and moisture content, where applicable. - E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate: MRL Method Reporting Limit. The MRL is, roughly equivalent to the practical quantitation. limit (PQL) and is. based on,the low,point of the calibration curve, when applicable, sample preparation factor, dilution ` factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. I N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or. greater confidence) to make a "tentative identification". P Greater than 250% concentration difference was observed between the primary and secondary. GC column. I The lower concentration is reported. QM-12 Precision between duplicate samples was outside acceptance limits. - FINAL ., _ _ _ • _-- ' This report relates only -to the sample as receivedbythe laboratory, and may only.be reproduced in'full. ; — :- ___.___,„ __ _._ __ _._ _ Page 7 of 8 - - X, ENVIRONMENTALCONSERVATION LABORATORIES CHAIN -OF -CUSTODY RECORD- 10775 Central Port Dr. 4510 aaculh/e Park Court, Suite 111- 102-A Woodwinds Industrial Ct. Orlando, F(. 32E24 3acksomil„ FL 32215-5059 Cary, NC 27511 (407) 826-5314 -Fax (407) 850.6945 (904) of W7 Fax (9B4) 295.6210 (919) 467-3090 Fax (919) 467-3515 www.encola.bs.com Page.— of _ Client Name zyp1e_ North r`' meric .' Address a t o / Fri ' is'Jc. el r✓bur& 1 o3d Project Number f9.Y$ie3' Ptaiact 142me/Deso 'f Srr �Pi YI�I -S�aPSIi Requested Analyses 1. Requested Turnaround Times . Note: Rush requests subject to acceptance by the (ae�iity _ Standard _ Expedited Due _�_1 t� � Ct � !! r� . 1.0 - 35 ";17 - " - - City/swap - - Frark;=nton NC 2: 7525 PO 4.1 Ming Into 3EO0 04409 Tel 9 i r j d -:3COC Fax . Reporting Contact Scba t Creech Sampler(s) Name, Affihation (Print) : � _W:' "r Samplers) Sigiahtre - B11ing Contact -M -ACQ)Lnts Pzva;)Ie Site Location / Tame Zone tab Workorder `p'" jjy AI - - Preservation (See Codes) (Combine as necessary) �-°f `*`� Item a Sample to (Field Identification) Cotlactton Date Cede0on - Time Comp/Grab Matrix (see codes) Total v of Comainers Sample!Comments < Total of Containers " Sample Kit Prepared By "Date/Time " - - Relinquished By - Date/T;rre Reccimd By s Daat/tel��Tiime - Comments/Special Reporting Requirements . _ - - nquished /� DateRme f R 'ad B - - - Date/Time t� Relinquished By Datemme Received By Daternme Cooler t?'s & Temps on Rsocial Cono pdn Receipt . . rJ Acceptable _Unacceptable Matrix : GW-Groundwater SOSoil DW-Drinking Water SE -Sediment SiV-Surtace water ww-wastewarer w-rur v-utner tutwis it, 1..,..,...,�,.. ,-,�� ,.-, , � u ., ..,.— ,............ -.:---- Note : All samples submitted to ENCO Labs are in accordance with the terms and conii:tions listed on the reverse of this town: unless prior written agreements exist. -.QUM Sample Preservation Verification ENCO Cary Work Order: CA1 9789 Project: Monthly - SBM Client: - Novozymes North America (N0008) Project #: [none] Logged In: 02-Jan-1 8 1116 Logged By: John C King 'Preservation Check Performed By: Rip Date/Time: CA197RMI p!I�edlj, , P4�p Date Mm W Reagent se n C ato 5pH Adjusted A 250mLP+H2SO4 all N / NA Y 6�1)1 NA Reagent Name ID 11. .21 1 ----pk'StripID: -C2 �F20 Reaqent Name ID 3.1 41 Reaqent Name ID 5 6 I C:kELMN-RPrintXwko—PreservationCheck.rpt Page 1 of 1 - i I .�° IX- a Ora ft to s s. Innovative. 102-A Woodwinds- Industrial Court j Cary NC, 27511 — �• -" Phone: 919.467.3090 ` FAX: 919.467:3515 Thursday, February 15, 2.0.18 Novoiymes North America (N0008) Attn: Scott Creech - 77 Perry Chapel Church Road . Franklinton, NC 27525 '- RE: Laboratory Results for i Project Number: [none], Project Name/Desc:.Monthly ENCO Workorder(s):: CB01009 Dear Scott Creech, Enclosed is a copy of your laboratory report for test samples received by our laboratory -on 'Tuesday, February 6, 2018. i. 1j, Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. i. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in f full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from -outside organizations will be reported under separate cover. ` r If you have any questions or require further information, please do not hesitate to contact me. f Sincerely, I Chuck Smith ` Project Manager Enclosure(s) FINAL - — This report- relatesonly to the sample as -received by -the laboratory, -and may only -be reproduced in full:— -- Page 1 of 8 www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE - I Client ID: SBM Lab ID: CB01009-01 Sampled: 02/06/18 08:45 Received: 02/06/18 09:00 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) } SM 254OD-1997 NO PREP 02/13/18 02/09/18 10:25 02/09/18 10:25 } SM 521OB-2001 NO PREP 02/08/18 08:45 02/07/18 12:11 02/07/18 12:11 "I SM 5220D-1997 Same 03/06/18 02/09/18 10:13 02/09/18 15:00 FINAL This report relates only -to the sample as received by the laboratory, and may only be reproduced in full. Page 2 of 8 Sample Preservation, Verification EtV,CO Cary cam low. ! Work Order: CB01516 Project: Monthl SBM x;Y Client: °Novozymes North America (N0008) Project #: [none) Logged In: 13-Mar-18 12:17 Logged By: John C King Preservation Check Performed By-, Date/Time: Cusrtr Type Requ ren ep.)rat p {r Cone of . Ghebke i pHdisted Atlj ted - Y Peagent IJSedJComrrierat ,;' A 250mLP+H2SO4 <2 . Y J N 1 NA -17 ,12'/07 ENVIRONMENTAL CONSERVATION LABORATORIES CHAIN70E-CUSTODY RECORD www.encolabs.com 10775 Central Port Dr. - 41910 EuEmti�a PrIA court, S to 1111 102-A Woodsuinds fn lustrai'Ct. - - - Cirianeo, Fi 32824 Jac'kzcrwapi FL 32211£r£rtrt9 Cary, NG 27511 - - - - - (407) 625-5314 Fax (407) 6511;6945 : - $ f1&p ^r9r-tea Fax iC�) 2aE-F210 .. (9187 4s7.300 Fax (919) 4s7-35t5 - Page ,�_, of Client Name —: y feff rt��rnPrra;4^l?(3r Projecll Number ? - Reguestetf Analyses Requested Turtlar0und Times Noto :-Rush requests subject to acceptance by thetacilily __ _ Standard - __ Expedited 47UP Q } �, - - Address -- 7 F e: il' G4lg; ('4 `41urc` 4 aca Praec8 Nametlte.,c - 4V4r�r9t4 i� _ sot City/sTlzip Frark' riior-- 44C 2,7525 PO d-l.iiiling into 3EGOS50507 Tel ;c 4 s) � E)i- 301) Fax Repor(ing Contact Scat Cree�1- Sampler(s) Name, Affiliation (Prot) 7 . { Billing Cyrrtact . Accou-'ifs 4'acya/ )3r- Samps gnaiure ° site Location t Time Ions Lab WDrkOrder 1,01'5 $RtTlple CoMmentSs .✓` - ' item q Sample ID (Field Identdica',son) Coaection Date ccinarlion matfcs _ Time Con f Grab (see cores) Containers Pr4ssr1ea139n (See Codes) � - . - (Combine as necessary) Y. _ <- iGiai ;F o; uontai ers Sampt/e} Kit Prepared 6y (DatePTima Relinqui.2letiHy I DatcfB'ime ReceNedBy .7. 3" Reporting 0 1 . CooL1r V's E T mps on Retzi yt - ��/ _ Condition Upon Recc Matrix : GW-Groundwater SO -soil DW-Drin:;in ly Water SE-Seed5raart SVJ-Sursace Water ierraler A -Air o-oiher (detail in:Crarmems) Preservation: MCI) H-HCH 5_ 4 25Oa 110-NaOH o-Other (detail in comments). Note: All samples submitted to ENCO Labs are in accordance u'!h 1ho terms and conditions Fstad on the mvarso of this form, unless prior written agreements exist M www.encwlabs.com -I FLAGS/NOTES AND DEFINITIONS B . The analyte was detected in the associated method blank. D The sample was analyzed at dilution. ] The reported value is between the laboratory method detection limit (MDL) and the laboratory method — reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. _ U The-analyte was analyzed for -but -not detected_ to the level shown, -adjusted for -actual sample preparation : - data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent.to the practical quantitation limit (PQL) and is based on the low -point of the calibration curve, when applicable, sample preparation factor, dilution —� factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". I P - Greater. than 25% concentration difference was observed between the primaryand secondary GC column. The lower concentration is reported. i FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Is.,■�0 www.encolabs.cwm. QUALITY CONTROL DATA . Classical Chemistry Parameters - Quality Control. Batch 8C21010 - Same - Continued Matrix Spike (SC21010-MS1) Prepared: 03/21/2018 11:15 Analyzed: 03/21/2018 18:55 Source: C803895-02 Spike Source %REC RPD -- Anal Yte _ _ - = _ — - - --- -Resu t __Elan_ _P91= - -. Units _ Level. Result %REC _ .Limits RPD _ _Limit--.-.. -Ms AL=_ - Chemical Oxygen Demand 520 10 mg/L 526 17 95 90-110 Matrix Spike Dup (8C21010-MSDi) Prepared: 03/21/2018 11:15-Analyzed: 03/21/2018 18:55 Source: C003895-02 Spike Source. %REC RPD AnalYte Result Elan MQL Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 520 • i , 10 mg/L .526.. 17 95 90-110 .0.4 10 www.encolabs.com QUALITY CONTROL, DATA Classical Chemistry Parameters - Quality Control Batch 8C14014 - NO PREP Blank (8C14014-BLK1) Prepared & Analyzed: 03/14/2018 14:32 Spike Source %REC, _ RPD PUl Level ----Result_ --%REC---=V----RPD - Limit -----Notes - - Biochemical Oxygen Demand 2.0 U. 2.0 mg/L LCS (8C14014-BS1)' Prepared & Analyzed:'03/14/2019 14:32 Spike Source, %REC RPD — Analvte RResult Flaa l'QL Units Level Result %REC . Limits RPD Limit Notes BiochemicalOxygen Demand 210 2.0 mg/L 198 104 85-115 i Duplicate (8C14014-DUPi) Prepared & Analyzed: 03/14/2018 14:32 Source: CB03895-02' Spike Source %REC RPD Analvte Result HIM POL Units Level Result %REC LIMM RPD Limit Notes Biochemical Oxygen Demand 2.0 U 2.0 mg/L 2.0 U 30 Batch SC14021- NO PREP I Blank (8C14021-BLK3) Prepared & Analyzed: 03/14/2018 14:20 Spike Source %REC RPD AnalYte .Result, •Ela4 POL units Level Resin %REC J"imi RPD Limit Notes Total, Suspended Solids, 2.5 U 2.5 mg/L LCS (SC34021-BS1) _ Prepared &Analyzed: 03/14/2018 14:20 Spike Source %REC RPD Anal vte Result Hm PQL Units Level Result %REC Limits RPD Limit Notes Total Suspended Solids 95' 2.5 mg/L 100 95 80-120 Duplicate (SC14021-DUPi) Prepared & Analyzed: 03/14/2018 14:20 Source: CB01409-01 Spike Source, %REC RPD Anal ltte _ Result Flag M Units Level Result, %REC, Limji RPD Lima Notes Total Suspended Solids 200 50 mg/L 200 3 20 Duplicate (SC14021-DUP2) Prepared & Analyzed: 03/14/2018 14:20 Source: CB01516-01 - Spike Source %REC .. RPD Anal .' . . .' Result F1aa EM Units Level Besul %REC Limits RPD Limit Notes Total Suspended Solids 28000 2500 mg/L 28000 0 20 Batch 8C21010 - Same I Blank (SC21010-BLK1) Prepared: 03/21/2018 11:15 Analyzed: 03/21/2018 18:55 --1 Spike Source %REC RPD" Anal Yte Result Elan OQL Units Level Result %REC ,Limits RPD Limit Notes J Chemical Oxygen Demand 10 U 10 mg/L LCS (8C21010-BS1) Prepared: 03/21/2018 11:15 Analyzed: 03/21/2018 18:55 Spike Source P/oREC RPD Anal lde lResult flag MI. Units Level Result %REC Limits" RPD. Limit Notes Chemical, Oxygen Demand 480, 10 mg/L 500 97 90-110 FINAL - - - -- - -This report relates only to the sample as received by the laboratory, and may only be reproduced -in full. Page 5 of 8 www.encolabs.com ANALYTICAL RESULTS Description: SBM Lab Sample ID;CB01516-01 Received: 03/13/18 12:00 Matrix: Sludge Sampled:03/13/18 07:00 Work Order: CB01516 Project: Monthly - SBM Sampled By:Troy Strand Classical Chemistry Parameters - ^ - ENCO Cary ceitified analyte [NC 591] — -Analvte rCAS-Numberl -- - Results Flaa Units -DF - MDL, PDL, Batch Method Analyzed Notes Biochemical Oxygen Demand^ 12000 mg/L 1 2.0 2.0 8C14014 SM 521OB-2001 03/14/18 14:32 JOC Chemical Oxygen Demand^ 31000 mg/L 80 800 800 BC21010 SM 5220D-1997 03/21/18 18:55 ]OC j Total Suspended Solids^ 28000 mg/L 1000 2500 2500 BC14021 SM 254OD-1997 03/14/18 14:20 OMR --- FINAL This report relates only to the sample as received b the laboratory, and may only be reproduced in full. Page 4 of 8 i � P Y P Y rY. Y Y P � 9 WWW.encolabs.com SAMPLE DETECTION SUMMARY. Client ID: SBM Lab ID: CB01516-01 Aeil6 Resultsflag Hn EQL Units Method Notes Biochemical Oxygen Demand 12000 2.0 2.0 mg/L ! SM 5210B-2001 Chemical Oxygen Demand 31000 800 800 mg/L SM 5220D-1997 I Total Suspended Solids 28060 2500 2500 mg/L SM 2540D-1997 _ I _ I � � I FINAL This report relates only to the sample as received by the laboratory, and may only -be reproduced In full, Page 3 of 8 - II co www.encolabs.com. SAMPLE SUMMARY/LABORATORY CHROiNICLE Client ID: SBM Received: 03/13/18 12:00 Lab ID: CB01516-01 Sampled: 03/13/18 07:00 - Parameter Preparation Hold Date/Time(s) Pren Date/Time(s] Analysis Date/TimoW ^_ SM 254OD-1997 _ NO PREP 03/20/18 03/14/18 14:20 03/14/18 14:20 = SM 521OB-2001 "NO PREP _ 03/15/18 07:00 03/14/18 14:32- "' _ ` 03/14/18 14:32 SM 5220D-1997 Same i 04/10/18 03/21/18 - 11:15- -03/21/18 18:55 Nc e . s E NCO Labor to. l ecurate. Timely. Responsive. Innovative® 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: ' 919.467.3515 Friday, March 23, 2018 Novozymes North America (N0008) Attn: Scott Creech 77 Perry Chapel Church Road Franklinton, NC 27525 RE: Laboratory Results for — Project Number: [none], Project Name/Desc: Monthly - SBM ENCO Workorder(s): CB01516 Dear Scott Creech, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Tuesday, March 13, 2018. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. I The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without -the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation j Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not'hesitate to contact me. i Sincerely,UA-0 - - I� Chuck Smith Project Manager _ Enclosure(s) ------ FINAL —= • - -' - -= - - ---This report relates onlyto'the sample as received by the laboratory, and may only be reproduced -in full: -- - -- - — - -' . _ Page 1 of B- - Sample Preservation. Verification ENCO Cary Work Order: CB01011 Project: Monthly - Week One - SBM Client: Novozymes North America (N0008) Project #: [none) Logged In: 06-Feb-18 10:43 Logged By: John C King Preservation Check Performed By: Date/Time: �-tv-q /8b& - C801011-01 Cont. Typ t2�Wrem6nt.. pHOhecKed l In 6ntrol pHAdju�ted, �at� lT�me Atl'usted RegentaJsetllCornnients - A 250mLP+H2SO4 <2 Y 1.61 NA Y NA 8 250mLP+HNO3 <2 /._N / NA Y /ott, / NA ENVIRONMENTAL CONSERVATION LABORATORIES CHAIN -OF -CUSTODY RECORD www.encolabs.C®on 1 on5 Cenbral.Port Dr. 4810 executive -Park Covrt, Suite III 102 A Woodwinds Industrial Ct., - Orlando, FL Z2624 .. &cksoniiilla, FL =16-WG9 Cary, NC 27511 .. (407) 026-5314 Fax (407) BW6945 - 4904) 296.30U7 Fax (9D4) 296-62t0 (919) 467-3090 Fax (919) 467-3515 page of' Client Name Project Number Requested Analyses Requested Turnaround c)v:�� rlm:� lr:sti�.,n:ricsslC)fl-3 €n.r?1 Q ILt Times ILI Address Project NameJDesc Note: Rush requests subject to Ti Perry CUphi i tuich Rcad Monthly -:'Veep One 1c,8,M ae�,ptal��thalachty City1ST/Zip PO # f Billing lift � =r ar.kFntori, UG :7� 23- 380OB3,0507 Standard . Tel _ Fax Reporting Contact - x 'M =� ° _ _ Expedited (c, 1c,) c1.�t�.-iC3i% Sruc't d:ri;eci� � z � :ems Sampler(s/) 4ame,AffiffalloniPrini) Wingcontacl xrw& ji&MC avaZV,-5 1 Ac;wunts Payable Die---�-1— Sampl } Sig urea �- SYe.LgcafpdnJTlme Zone n IN r3 Lab Workorder Ok i; M 1011 . Preservation (See Codes) (Combine as necessary) - - . ... COIIgCtien matrix Total e of Item a Sampta ID (Fisid Identification) Colteclion Date - -rime Comp! Grab (seo cogs) Containers. - -Sample Comments <— Total n of Containers Sample Kit Prepare Ey Dat€r"fiime Rehi and t3� Dat€iTii/m' e Received By a - - Daterrme �iJ gnu Comments Special Reportin9 Requirements ni lied a flecgvea by DatdlTmo R€fnquighed By Da eJTimo Received By Datelrmo Cooler u's 8"Temps on Receipt (-; Condition pon Receipt. Acceptable Unacceptable Matrix : GW-Groundwater SO -Sat DW-Drinking 6^Jater SE•Sedimenl S%V-Surface Water . W W-Waetesvatdr A -Air U-U'nDr 10e1a0 in COmment8) YMOTWatf00; I-!C€ ii-nt:a •FI-tiNU3. 9-rti'.SUC NUTNaUM U-U.Mcf (delail.in comments)- " _ Note: AEI same ees smisir filed to ENCO tabs are in accordance v4di Ina terms and concififions Gsled on tho reverse of this form, unless prior tvritien agreements exist - www.encolabs.com FLAGS/NOTES AND DEFINITIONS j B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. J The reported value, is between the laboratory method detection limit (MDL) and the laboratory method _ reporting limit (MRL), adjusted for actual sample preparation, data- and moisture content, where applicable. _ U The analyte was analyzed for but not detected e to the level w I shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the _ - instrument. This value is considered an estimate. MRL - Method Reporting Limit. The MRL is roughly equivalent.to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification": - — _ -- P Greater -than 25% concentration difference was observed -between the primary -and secondary GC column. The lower concentration is reported. I QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. QM-08 Post -digestion spike did not meet method requirements' due to confirmed matrix effects j (dilution test). . r l • FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 11 of 12 U we wwW.encolabs.com• I QUALITY CONTROL DATA - Classical Chemistry Parameters -Quality Control Batch 8B08010 - Same - Continued Matrix -Spike (811308010-MS3) Prepared: 02/08/2018 11:50 Analyzed: 02/12/2018 11:46 Source: ---- Spike Source %REC RPD AnaUde_ _ _. — = — Basalt Elan P91 Units Level Result_ %REC Limits RPD Limit Notes ..Phosphorus 1.1 0.10 mg/L 0.640 0.41 106 80-120 Matrix Spike Dup (811308010-MSD1) Prepared: 02/08/2018 11:50 Analyzed: 02/12/2018 11:48 , Source: CA15910-02 Spike Source %REC RPD. Besiilt F109 P91 Units Level Result %REC Limits RPD Lipp Notes Phosphorus 1.1 0.10 mg/L 0.640. 0.41 107 80-120 0.9 25 Batch 8809014 - NO PREP LCS (8809014-113SI) Prepared: 02/09/2018 11:43 Analyzed: 02/09/2018 11:43 I 'Spike Source %REC RPD Anal lttQ Result Elm M Units Level Result %REC Limits RPD Limit Notes' Nitrate/Nitrite, as N 1.2 0.10 mg/L 1.25 96 907110 Matrix Spike (8B09014-MSS) Prepared: 02/09/2018 11:59 Analyzed: 02/09/2018 11:59 Source: CA18891-01' - Spike Source %REC RPD Anallte Result flag P4L Units Level Result %REC Limits, RPD Limit Notes Nitrate/Nitrite as N 0.73 0.10 mg/L 0.521 0.21 100 90-110 Matrix Spike (8609014-MS2) Prepared: 02/09/2018 12:08 Analyzed: 02/09/2018 12:08 Source: CB00147-01 Spike Source %REC RPD Anal Result EtasPM Units Level Result %REC limits RPD Limit Notes Nitrate/Nitrite as N 110 10 mg/L 50.0 61 92 90-110 Matrix Spike Dup (811309014=MSD1) Prepared: 02/09/2018 12:01 Analyzed: 02/d9/2018 12:01 Source: CAIM91-01. Spike Source %REC RPD AnalYte Result Elan P4L Units Level Result %REC Limits, RPD Limit Notes Nitrate/Nitrite as N 0,72 0.10 mg/L 0.521 .0.21 98 90-11.0 2 10 Batch 9812024 - EPA 3005A Blank (81312024-13LKI) Prepared: 02/12/2018 13:17 Analyzed: 02/16/2018 13:46 Spike Source %REC RPD Anale Result Elm P4L units Level Result %REC Limits. RPD 'Limit Notes Sodium Adsor lion Ratio P 0.00 U [blank] www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 8007017 - NO PREP - Continued Matrix Spike (BB07017-MS2) Continued Prepared: 02/07/2018 12:58 Analyzed:' 02/07/2018 12:58 Source: CA16572-01RE3 Anal_-- Result Ammonia as N 31, Elm ' POL 2.0 Spike Units. Level _ mg/L 7.92 Source Result _. 23 %REC 98 %REC ' Limits RPD- -, 90-110 RPD i Limit ----Notes. i Matrix Spike Dup (SB07017-MSDI) Prepared: 02/07/2018 11:19 Analyzed: 02/07/2018 11:19 Source: CA15910-02 Spike Source %REC RPD Anal Yte .,-.- -- - -- --- - - - - Result _- Fla4 .. P91 Units =- Level Result %REC- _ .Limits _ RPD - - Limit - -Note.i Ammonia as N 0.45 0.10 mg/L 0.385 .0.086 95 90-110 0.02 10 Batch 8508009 - Same Blank (8B08009-BLK1) Prepared: 02/08/2018 11:50 Analyzed: 02/12/2018 10:44 Spike Source %REC RPD _ Anal ttSe Result Etas PQL tlnfta Level Result %REC Llmitp. RPD Limit Notes ` - Total Kjeldahl Nitrogen 0.26 U 0.48 mg/L LCS (BB08009-BSI) Prepared: 02/08/2018 11:50 Analyzed: 02/12/2018 10:45 t_ Spike Source %REC RPD Anal Result flag PQL Units Level Result %REC limits RPD Limit Motes Total Kjeldahl Nitrogen 13 0.48. mg/L 11.9 107 90-110 Matrix Spike (8B08009-MS1) Prepared: 02/08/2018 11:50 Analyzed: 02/12/2018 10:49 Source: CA15910-02 Spike Source %REC RPD Ana Result flag EM Units Level Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 6.8 '0.48 mg/L 4.75 1.4 112 90-110 QM-07 Matrix Spike (SB08009-MS2) Prepared: 02/08/2018 11:50 Analyzed:, 02/12/2018 10:54 Source: CA18891-01 Spike Source %REC RPD Anal tlte Result. flan PM Units Level Result %REC "Limitts RPD Limit Notes Total Kjeldahl Nitrogen: 11 0.48 mg/L 4.75 6.1 106 90-110 Matrix Spike Dup (8608009-MSDi) Prepared: 02/08/2018 11:50 Analyzed: 02/12/2018 10:51 Source: CA15910-02 Spike Source %REC RPD Anal ytg R4will; flan P-QL Units Level Result %REC Limits .RPD' L1IDit Notes Total Kjeldahl Nitrogen 6.6 0.48 mg/L 4.75 1.4 108 , 90-110 '3 10 Batch 8008010 - Same. Blank (8608010-BLKi) Prepared: 02/08/2018 11:50 Analyzed: 02/12/2018 11:42 Spike Source %REC RPD Analt(te Resul flan PQL Unites Level Result %REC Limits RPD Limit Motes Phosphorus 0.025 U' 0.10Lmg/L LCS (8B08030-BSI) Prepared: 02/08/2018 11:50 Analyzed: 02/12/2018 11:44 Spike Source %REC RPD Anal Yta: 'Result flag P4L !!nits . Level Result %REC Limits RPD. Limit Motu Phosphorus 1.7 0.10 mg/L 1.60 105 80-120 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 9 of 12 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch SBO6023 - NO PREP - Continued .LCS (813106023-SS2) Continued _ _ Prepared: 02/06/2018 15:03 Analyzed: 02/06/2018 15:03 _ _ _ . ---- Spike Source %REC RPD Anal Yte . Result Elan POL _ Units _ _ Level Result %REC Limits RPD Limit Notes Nitrite as N 0.95 0.10 mg/L 1.00 95 90-110 LCS (BB06023-BS3) r Prepared: 02/06/2018 16:12 Analyzed: 02/06/2018 1612 Spike Source %REC RPD - ---.. ----- Analvte _ -- -- - - Result Elan PQL --- Units Level - ._ Result %REC _ Limits RPD Limit N=s Nitrite as N 0.97 0.10 mg/L 1.00 97 90-110 LCS (SB06023-BS4) Prepared: 02/06/2018 16:15 Analyzed: 02/06/2018 16:15 Spike Source o/aREC RPD Analvte I Result ELan M Units Level Resul %REC Limits RPD Limit Notes - Nitrite as N 0.97 0.10 mg/L - 1.00 - 97 90-110 Matrix Spike (BB06023-MS3) Prepared: 02/06/2018 14:47 Analyzed: 02/06/2018 14:47 Source: CB00957-01 Spike Source %REC RPD Anal Resul Elan RQL knits Level Result o/aREC Limits RPD Lips Notes Nitrite as N 0.91 0.10 mg/L 1.00 0.017 U 91 90-110 Matrix Spike (8806023-MS2) Prepared: 02/06/2018 14:50 Analyzed: 02/06/2018 14:50 Source:CB00957-02 Spike Source %REC RPD AnalRex01t Elan, PQL Units Level Result %REC Limits RPD Limit Notes '. Nitrite as N 0.84 0.10 mg/L 1.00 0.017 U 84 90-110 QM-07 Matrix Spike Dup (SB06023-MSDI) Prepared: 02/06/2018 14:48 Analyzed: 02/06/2018 14:48 Source: CB00957-01 Spike Source %REC RPD Analvte Result Elan P4L Units Level Result o/aREC Limits RPD Limit Notes - Nitrite as N 0.91 0.10 mg/L 1.00 0.017 U 91 90-110 0.2 10 L Batch 8B07017 - NO PREP Blank (811107017-BLKI) Prepared: 02/07/2018 11:12 Analyzed: 02/07/2018 11:12 Spike Source %REC RPD Anal Yte Result Elan PQL Units Level Result %REC Limits RPD Limit Notes Ammonia as N 0.045 U 0.10 mg/L i LCS (8B07017-BSI) Prepared: 02/07/2018 11:14 Analyzed: 02/07/2018 11:14 Spike Source %REC RPD AnalYte Resul t Elan PQL units Level Result %REC Limits RPD Limit Notes Ammonia as N 1.0 0.10 mg/L 0.989 103 90-110 Matrix Spike (8607017-MS1) Prepared: 02/07/2018 11:18 Analyzed: 02/07/2018,11:18 ' Source: CA15910-02 Spike Source %REC RPD Anal Result Elan PQL Units Level Result %REC Limits RPD Limit Notes . Ammonia as N 0.45 0.10 mg/L 0.385 0.086 95 90-110 II(�� Matrix Spike (8807017-MS2) Prepared: 02/07/2018 12:58 Analyzed: 02/07/2018 12:58 Source: CA16572-01RE1 Spike Source %REC RPD -- Anal Resul Elan, PQL Units Level Rut %REC Limits RPD Limit Notes - - FINAL - This report relates only to the sample as received -by -the laboratory, and -may only be reproduced -in full. - - - Page 8 of 12 - -- www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OB12024 - EPA 3005A - Continued Post Spike (BB12024-PSI) Prepared: 02/12/2018 13:17 Analyzed: 02/16/2018 10:34 Source:CB00023-05 Spike Source %REC RPD Anal ytg _ _Result E1a_4 P4L lJnits Level Result ._. °/aREC Limits RPD_ Limit Notes Aluminum 2.09 0.100 mg/L 2.00 0.0319 103 80-120 Arsenic 0.212 0.0100 mg/L 0.200 0.00122 105 80-120 Cadmium 0.0210 0.00100 mg/L 0.0200 -0.000113 105 80-120 Calcium 34.1 0.100 mg/L 2.00 35.0 NR 80-120 QM-08 Copper 0.207 0.0100 mg/L 0.200 0.00147 103 80-120 Lead 0.210 0.0100 mg/L 0.200 -0.000194 105 80-120 Magnesium 4.71 0.100 mg/L 2.00 3.04 83 80-120 Molybdenum 0.214 0.0100 mg/L 0.200 0.00202 106 80-120 Nickel 0.205 0.0100 mg/L 0.200 -0.000795 102 80-120 Potassium 12.0 0.500 mg/L 10.0 1.78 102 80-120 Selenium 0.212 0.0100 mg/L 0.200 -0.00603 106 80-120 Sodium 46.7 0.500 mg/L 10.0 39.7 70 80-120 QM-08 Zinc 0.309 0.0100 mg/L 0.200 0.117 96 80-120 Classical Chemistry Parameters - Quality Control Batch BB06017 - NO PREP Blank (SB06017-BLK3) Prepared & Analyzed: 02/06/2018 12:18 Spike Source %REC RPD Anal vte Result Ela9 PQL units Level Result %REC Limits RPD Limit Notes Total Solids 0.0050 U 0.0050 % by Volume LCS (BB06017-BSI) Prepared & Analyzed: 02/06/2018 12:18 Spike Source %REC RPD AnalYte Result Elaa PQL Units Level Result %REC Limits RPD Limit Notes Total Solids 1100 50 mg/L 1100 99 80-120 Duplicate (8B06017-DUP1) Prepared & Analyzed: 02/06/2018 12:18 Source:CA18906-01 Spike Source %REC RPD ADalyte Result Elan P01 !!nits Level Result %REC Limits RPD Limit Notes Total Solids 0.23 0.0050 % by Volume 0.23 0.5 20 Batch OB0O023 - NO PREP Blank (SB06023-BLK1) Prepared: 02/06/2018 14:45 Analyzed: 02/06/2018 14:45 Spike Source %REC RPD Anal Ytg Result Elan PQL units Level Result %REC Limits RPD Limit Notes Nitrite as N 0.017 U 0.10 mg/L LCS (8B06023-BS3) Prepared: 02/06/2018 14:09 Analyzed: 02/06/2018 14:09 Spike Source %REC RPD Anal t Result Elm PQL Units Level Result %REC Limits RPD !!MR Notes Nitrite as N 0.98 0.10 mg/L 1.00 98 90-110 LCS (8806023-BS2) Prepared: 02/06/2018 15:03 Analyzed: 02/06/2018 15:03 Spike Source 0/aREC RPD Anal1te Resul Elan P4L Units Level Result %REC Limits RPD Limit Notes I� 1� a I0 i FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 7 of 12 �� LI www.encolabs.com f QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 8812024 - EPA 3005A - Continued I _Prepared: 02/12/2018 13:17 Analyzed: 02/16/,2018_10:26_ . • Spike Source %REC RPD Level'- -Result - %REC_--limits -RPD=_l lBti1 Notes Aluminum 2.14 0.100 mg/L 2.00 107 • 80-120 Arsenic 0.215 0.0100 mg/L 0.200 108 80-120 Cadmium 0.0216' 0.00100 mg/L 0:0200 108 80-120 Calcium 2.16 . 0.100 mg/L 2.00 108 80-120 Copper 0.205 0.0100 mg/L 0:200.' 102 80-120 Lead 0.2170'0100 mg/L 0.200 108 80-120 " Magnesium 2.08 0.100 mg/L 2.00 104 80-120 Molybdenum 0.210 0.0100 mg/L 0.200 105 80-120 Nickel 0.210 0.0100 mg/L 0.200 105 80-120 Potassium 10.7 0.500 mg/L 10.0 107 80-120 { t . Selenium ,- . - - 0114 - - 0.0100 - mg/L 0.200 - - ---- =307 •80-120.-- - - - - -- - Sodium 10.8 0.500 mg/L 10.0 108 80-120 Zinc 0.224 0.0100 mg/L 0.200 112 80-120 Matrix Spike (8612624-MS3) Prepared: 02/12/2018 13:17 Analyzed: 02/16/2018 10:31 Source: CB00023-05 Spike Source %REC RPD Analyte Result Flan P-QL bits Level Result %REC Limits RPD Limit Notes Aluminum 2.13 0.100 mg/L 2.00 0.0420 U 107 75-125 Arsenic 0.216 0.0100 mg/L 0.200 0.00680 U 108 75-125 Cadmium 0.0214 0.00100 mg/L 0.0200, 0.000360 U 107 75-125 Calcium. 35.8 0.100 mg/L 2.00 35.0 41 .75-125 QM-07 Copper 0.212 0.0100 mg/L •0.200 0.00160 U 106 75-125 Lead 0.215 0.0100 mg/L 0.200 0.00310 U 108 75-125 Magnesium 4.92 0.100 mg/L 2.00 3.04 94 75425 Molybdenum 0.217 0.0100 mg/L 0.200 6.00250 U 109 75-125 Nickel 0.211 0.0100 mg/L 0.200 0.00220 U 105 75-125 Potassium 12.1 0.500 mg/L 10.0 1.78 104 75-125 Selenium 0.219 0.0100 mg/L 0.200 0.00620 U 109 75-125 Sodium 48.6 0.500 mg/L 10.0 39.7 89 75-125 Zinc' 0.325 0.0100 mg/L 0.200 0.117 104 75-125 Matrix Spike Dup (8812024-MSD1) Prepared: 02/12/2018 13:17 Analyzed: 02/16/2018 10:36 ' Source: C600023-05 Spike Source %REC RPD Analvte Result Elan P-QL Units Level Resu t %REC Limit RPD Limit Notes Aluminum 2.05 0.100 mg/L 2.00 0.0420 U 103 75-125 4 20 ! Arsenic 0.209 0.0100 mg/L 0.200 0.00680 U 104 75-125 3 20 Cadmium 0.0208 0.00100 mg/L 0.0200 0.000360 U 104 75-125 3 20 i Calcium 35.3 0.100 mg/L 2.00 35.0 16 75125 1 20 QM-07 Copper 0.207 0.0100 mg/L 0.200 0.00160 U 104 75-125 2 20 Lead 0.205 0.0100 mg/L 0.260 0.00310 U .103 75-125 5 20, Magnesium 4.92 0.100 mg/L 2.00 3.04' 94 75-125 0.1 20 Molybdenum .0.209 0.0100 mg& 0.200 0.00250 U 105 75-125 4 20 Nickel 0.207 0.0100 mg/L 0.200 0.00220 U 104 75-125 2.. 20 Potassium 11.8 0.500 mg/L 10.0 1.78 100 75-125 3 20 Selenium 0.208 0.0100 mg/L 0.200 70.00620 U. 104 75-125 5- 20 ` Sodium 47.8 0.500 mg/L 10.0 39.7 81. 75-125 2 20 Zinc 0.320 0.0100 mg/L, 6.200 0.117 102 75-125 1 20 { - - FINAL- - - - ----This report relates onlyto the sample as received by the laboratory, and may only be reproducecHn full, - - - - - Page 6 of 12 - -" www.encolabs.com QUALITY CONTROL DATA i Metals by EPA 6600/7000 Series Methods -Quality Control Batch 9807031- EPA 245,1 Blank (8607031-BLKl), Prepared: 02/07/2018 12:34 Analyzed: 02/08/2018 13,19 Spike Source %REC RPD , Anal -- -Result- -_Elea _ -PQL. Units . _ Level-- .--Result %REC -_Limits. RPD- it _--- LimNotes, - --- Mercury 0.000150 U, 0.000200 mg/L Blank (SB07031-BLK2) Prepared: 02/07/2018 12:34 Analyzed: 02/08/2018 13:22 _ Spike Source %REC RPD Anal .. Result Elan P4L !J9ts Level Rio %REC Limits RPD Limit Notes Mercury 0.000150 U 0.000200 mg/L LCS (8607031-BS3) Prepared: 02/07/2018 12:34 Analyzed: 02/08/2018 13:24 Spike Source %REC RPD Analvte Result ran POL UnitsLevel Result %REC Limits RPD Mad Notes Mercury 0.00563 0.000200 mg/L 0.00500 113 80-120 Matrix Spike (BB07031-MS1) Prepared: 02/07/2018 12:34 Analyzed: 02/08/2018 13:29 Source: CA18891-01 Spike Source %REC RPD Anal Result Etas MQL Units Level Result %REC , Limits RPD )inift Notes Mercury 0.00573 0.000200 mg/L 0.00500 0.000150 U 115 75-125 Matrix Spike Dup (8B07031-MSD1) Prepared: 02/07/2018 12:34 Analyzed: 02/08/2018 13:32 Source: CA18891-01 Spike, Source %REC RPD Anal vte Result;. Elan. P_QL Units Level Result %REC. Limits RPD imit Notes Mercury 0.00563 0.000200 mg/L 0.00500 0.000150 U 113 75-125 2 25 Post Spike (8B07031-PS3) Prepared: 02/07/2018 12:34 Analyzed: 02/08/2018 13:38 Source: CA18891-01 Spike Source '/oREC RPD .AnalYte Result Eland PQL Units Level Result %REC Limits RPD ,Limit Notes Mercury 7.14 0.200 ug/L 5.00 0.0710 141 75-125 QM-08 Metals (total recoverable) by EPA, 6000/7000 Series Methods - Quality Control Batch 8B12024 - EPA 3005A Blank (811112024-BLKl) Prepared: 02/12/2018 13:17 Analyzed: 02/16/2018 10:23 Spike Source %REC RPD ' Anal ldB Result , E1as. P9l Units, Level Result %REC Limits RPD Lm1i5 Nates Aluminum 0.0420 U': 0.100 • mg/L Arsenic 0.00680 U 0.0100 mg/L ' Cadmium o.d00360 U ' 0.00100 mg/L Calcium 0.0390 U 0.100 mg/L Copper 0.00160 U 0.0100 mg/L Lead 0.00310 U 0.0100 mg/L Magnesium . 0.0290 U 0.100 mg/L Molybdenum 0.00250 - U 0.0100 mg/L Nickel '0.00220 U. 0.0100 mg/L Potassium 0.150 U 0.500 mg/L Selenium 0.00620 U 0.0100 mg/L Sodium 0.400 U 0.500 mg/L Zinc 0.00440 U 0.0100 mg/L FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 5 of 12 - www.encolabs.com.. ANALYTICAL RESULTS • , _J Description: SBM Lab Sample ID:CB01011-01 Received: 02/06/18 09:00 Matrix: Sludge Sampled: 02/06/18 08145 Work Order: CB01011 Project: Monthly = Week One - SBM Sampled By: Brooks Williams Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] � _---Analyte-ICAS Number-l--=-=__ _= -=Results-= =F a =-, = Units. =- =DF MDL POL, Batch Method Analyzed Notes - - Mercury [7439-97-6]^ 0.000750 U mg/L 5 0.000750'0.00100 8BO7031 EPA 7470A 02/08/18 13:43. CMK Metals.(total recoverable) by EPA 6606/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Results flog Units RE d4M M Batch Method Analyzed Aluminum [7429-90-5]^ 317 mg/L 10 0.420 1.00 BB12024 EPA 6010D 02/16/18 11:06 JDH Arsenic[7440-38-2]^ 0.0680 U mg/L 10 0.0680 0.100 BB12024 EPA 6010D 02/16/18 11:06 JDH - Cadmium [7440-43-9]^ 0.00360 U mg/L 10 0.00360 0.01.00 . 8B12024 EPA 6010D 02/16/18 11:06 JDH Calcium [7440-70-2]^ 2140 mg/L 10 0.390 1.00 8E112024 EPA 6010D 02/16/18 11:06, JDH Copper [7440=50-8]'^ 0.447 nig/L 10' 0.016.0 0.100 8612024 EPA 6010D 02/16/18 11:06 JDH' 1 Lead.[7439-92-1]^ ` 0.0310 U mg/L 10 0.0310 ,'0.100 BB12024 EPA 6010D '02/16/18 11:06' ;JDH, Magnesium [7439-95-4]^ 45.0 mg/L 10 0.290 1.00 812112024 EPA 6010D 02/16/18 11:06 JDH Molybdenum [7439-,98-7]^ 0.0321 J mg/L 10 0.0250 0.100 812112024 EPA 6010D 02/16/18 11:06 JDH. N ickel [7440-02- 0]^ 0.0536 J mg/L 10 0.0220 .0.100 812112024 EPA 6010D 02/16/18 11:06 JDH Potassium [7440-09-7]^ 877 mg/L 10 1.50 5.00 812112024 EPA 6010D 02/16/18 11:06 JDH'. Selenium [7782-49-2]^ 0.0620 U mg/L 10 0.0620 0.100 BB12024 EPA 6010D 02/16/18 11:06 'JDH Sodium [7440-23-5]^ 201 mg/L 10 4.00 5.00 8E112024 EPA 6010D 02/16/18 11:06 JDH Zinc[7440-66-6]^ 0.823 mg/L 10 0.0440 0.100 8B12024 EPA 6010D 02/16/18 11:06 :JDH, I Classical Chemistry Parameters . ^ - ENQ7 Cary ceKifred analyte [NC 5911 Analyte rCAS Numberl Results Flaa Units DF MDL POL• Batch Method Analyzed [sy Notes Ammonia as N [7664-41-7]^ 78 D mg/L 100 4.5 10 BB07017 EPA 350.1 02/07/18 11:40 JL1 Nitrate as N [14797-55-8]^ 52 mg/L 1 0.025 0.10 .8B12028 EPA 353.2 02/12/18 14:42 71-3 1 Nitrite as N [14797-65-0]^ 0.86 mg/L 1 0.017 0.10 8B06023 EPA 353.2 02/06/18 14:56 JU . Phosphorus[7723-14-0]^ 620, D mg/L 250 6.2 25 8B08010 EPA 365.4 02/12/18 12:03 'JU .- Sodium Adsorption Ratio 1.17 [blank] I. 8B12024 CSU Method 02/16/18 13:45 JDH Total Kjeldahl Nitrogen^ 2200 D mg/L 250 65 ' 120 ' SBOB009 EPA 351.2 02/12/18 11:12 ' JU " ". Total Solids^ 4.5 % by Volume 50 0.25 0.25 8BO6017 SM,254OB-1997 02/06/18 12:18 OMR FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 12. I ! www.encolabs.com SAMPLE DETECTION SUMMARY I Client ID: . SBM Lab ID: C801011-01. i Analvte Results flog MM EQL Units .Method Notes Aluminum - Total 317 0.420 1.00 mg/L EPA 6010D Ammonia as N 78 D 4.5 10 mg/L EPA 350.1 Calcium = Total 2140 -' 0.390 1.00 mg/L EPA 601013 Copper -Total 0.447 0.0160 0.100 mg/L EPA 6010D Magnesium - Total 45.0 0.290 1.00 mg/L EPA 6010D , -- Molybdenum = Total: - — ---- - ' ——0:0321----- ] 0.0250--- - 0:100 - - mg/L- - ---EPA 6010D -_ - - --- Nickel - Total 0.0536 3 0.0220 0.100 mg/L EPA 6010D Nitrate as N 52 0.025 0.10 mg/L 'EPA 353.2 Nitrite as N 0.86 0.017 0.10 mg/L EPA 353.2 Phosphorus 620 D 6.2 25. mg/L EPA,365.4 Potassium - Total 877 _ 1.50 5:00 mg/L EPA 6010D Sodium - Total 201 4:00 5.00 mg/L ' EPA 6010D Sodium Adsorption Ratio 1.17 [blank] CSU Method Total Kjeldahl"Nitrogen 2200 D 65 120 mg/L EPA 351:2 I Total Solids 4.5 ' 0.25 0.25 % by, Volume SM 25401]1-1997 Zinc - Total 0.823 0.0440 0.100 mg/L EPA 6010D -- --- - - FINAL -This report relates only to the sample as received by the laboratory, and may only -be reproduced in full: -- Page 3 of 12 -- www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: SBM Lab ID: CB01011-01 Sampled: 02/06/18 08:45 Received: 02/06/18 09:00 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(sl CSU Method NO PREP 11/01/20 02/12/18 13:17 02/16/18 13:45 EPA 350.1 NO PREP - ---- ---03106/18 02/07/18- 11:40 - 02/07/18`11:40 -- EPA 351.2 Same 03/06/18 02/08/18 11:50 02/12/18 11:12 . EPA 353.2 NO PREP 02/08/18 08:45. 02/06/18 14:56 02/06/18 14:56. EPA 353.2 --NO-PREP - 13(01�20 - 02/12/18 13:31 02/12/18 14:42 - -- EPA 365.4 Same 03/06/18 02/08/18 11:50 02/12/18 12:03 EPA 6010D EPA 3005A 08/05/18 02/12/18 13:17 02/16/18 11:06 EPA 7470A EPA 7470A 03/06/18 02/07/18 12:34 02/08/18 13:43 SM 254OB-1997 NO PREP 02/15/18 02/06/18 12:18 02/06/18 12:18 i FINAL . - This report -relates only -to the -sample -as received -by -the laboratory, and may only be reproduced in full. - Page 2 of 12 E-5 NCO " a�Y rat ! 1:: CCUra e. Timely. Responsive. Innovative... 102-A Woodwinds Industrial Court Cary NC, 27511 . Phone: 919.467.3090 FAX: '919'467.3515 Friday, February 16, 2018 Novozymes North America (N0008) T Attn: Scott Creech -77 Perry Chapel Church Road Franklinton, NC 27525 _ RE: Laboratory Results for — Project Number: [none], Project Name/Desc: Monthly - Week One - SBM ENCO Workorder(s): CB01011 Dear Scott Creech; i-- Enclosed is a copy of your laboratory report for test samples received by our laboratory, on Tuesday, February 6, 2018. Unless otherwise noted in an attached project narrative, all samples were received in — acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. 1 The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in r full, without the written approval of the Laboratory. j This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, r - a Chuck Smith Project Manager Enclosure(s) ' - - - -- - FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in.full. - Page 1 of 12 - - -{ Sample Preservation Verification ENC• Cary am am •fin' �* Work Order: CB01009 Project: Monthly - SBM Client: Novozymes North America (NO008) Project #: [none] Logged In: 06-Feb-18 10:54 Logged By: John C King Preservation Check Performed By: S , Date/Time: _.CB01009-01 Cont T e yP _ Pres (pFI) Requirement pH Checked / In Control f"im Datefe pH Adjusted Adjusted Reagent Used/Comments A 250mLP+H2SO4 <2 Y / f�,/ NA Y / N / NA �. . 1,V , }#ZJ`br/L Reagent Name ID Rea ent Name ID 1 3 ._ e 2 a _ pH Strip ID: CO�2c� -C:IELMNT1Printlwko_PreservationCheck. rpt - - --- - -Reagent- Name ID 5 6 1 Page 1 of 1 ENVIRONMENTAL CONSERVATION LABORATORIES CHAIN -OF -CUSTODY RECORD 10775 Contra! Pon! Dr. 4810 ire utive Park Court, Suite 111 - 102-A Vloodwinds Industrial CL _ Orlando, FL'32824 . .lacksonvi :, F132210-6059 Cary, N027311 (407) 825-5314- Fax (407) 850-ES45 (904) 296-3007 Faax"(904) 296-6210 (919) 467-W-% Fax (919) 457-3515 www.encolabs.com Page _ of Ment Name wziz nies North I" r1.eri W-0008) Project Number RequeSted Analyses Requested Tllrflaf0lJ11d Times Note: Rush requests subject -to acceptance by the facility _ Standard _Expedited Due � ; j� `� ��l . Address • 77 Pei Ty Crhri of Chu, ch Fzi3 d . Project Name90esc month - 8131 i Clty/ST/Z'rp Erar ki intor), WC 27525 P4-(t l ailling Inlo . W00330507 Tel 1 Fax Reporting Contact- Scott Creech ` Sampler(s) ` amra, Att6lalion (Prim) c41C_S At ,Gy-s hoviz � f Bilung Contact j Accounts Payable Sam Sagnatwa _ .. Site Location t Tune Zone , Lab Workorder . . 4 reservallon (See Codes) (Combine as necessary) " °. a' Item a - Sample ID (Field Identification) Coiluc on PAatrix Total it of Collection Date TimeComp I Grab (sea codes) Containers - Sample. Comments. . i - 1 IOIa1 It oT uontainers Sample Kit Preparctjjlr fP- Dole/Time Refin. Bp % Datefrima e .� 9- co Raoo3vad B Date/Time. ' !ate' 2:-U GO lCommdritstSpecial Reporting Requirements aqu . d By Dale urt, Received By DaUdGe Refinquished By Datem-ma Race v d By DateMme Coder la's & Tempts on Receipt _ . - _ - - Condition Upon Receipt - - _, Acceptable -Unacceptable Matrix : GW-Ground ater'SOSolf DW-Drinking Water- SE-ScOmem Sly -Surface War A -Air "that (dote.,] inconanams) Preservation: f-ace H44CI N-HNO3 S-tl29SO4 NO-NaOH. O.Other (detail in comments) Note: All r vnples submitted to EINCO Cabs are in accordance , tth the terms and cond€rions listed on 'tha reverse of this form, unlass pr'or wifttan agreements exist B D 7- U E MRL PQL N P www.encolabs.com FLAGS/NOTES AND DEFINITIONS The analyte was detected in the associated method blank. The sample was analyzed at dilution. The reported value is between the laboratory method detection limit (MDQ and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. The analyte was analyzed -for but not detected to the_ level shown, adjusted for actual sample preparation data and moisture content, where applicable. The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL: Practical Quantitation Limit. The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. FINAL -This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 7 of 8 www.encolabs.com . QUALITY CONTROL,DATA - Classical Chemistry Parameters- Quality Control --= • Batch 8809013 - Same - Continued Matrix Spike.(8609013-MS1) _ Prepared: 02/09/2018 16:13 Analyzed: 02/09/2018 15:00 Source: CA17061-01 Spike Source %REC RPD ` -Anal -- - -- --. - - - - - - BO—Flag P91 ylu�---- -Level Result '/oREC---) ---=-RPD _ Limit '-_ _ NotSs..—�:-- - -. ` Chemical Oxygen Demand 630 10 mg/L 526 100 100 90-110 Matrix Spike Dup(81309013-11MISM).- __ Prepared: 02/09%201810:13 Analyied: 02/09/2018.15:00 Source: CA17001-01 — — - - ---- - - - - - Spike" . Source, %REC RPD . Analyte Result Flag PAL Units Level Result '/oREC Limits RPD Limit Notes Chemical Oxygen Demand, 610 10, mg/L 526 100 97 907110 QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 8807020 - NO PREP j� Blank (8B07020-BLK1) Prepared. & Analyzed: 02/07/2018 12:11 L_ Spike Source %REC RPD --_--_ - AnaIYIC _ Bpculh _ P91_.._ lJA( Level,- _--Result---%REC----.Limit"—__RPD,_--. Limit. - Notes-.'__ _--- Biochemical Oxygen Demand 2.0 U , 2.0 mg/L LCS (6B07020-BS1)- . Prepared & Analyzed: 02/07/2018 12:11 Spike Source %REC RPD — Anal vte Result Flan MOL Units- _Level RPSNIt-. _%RECLimit- _ RPD LImjL ... Notes -- - " Biochemical Oxygen Demand 200 2.0 mg/L 198 102 85-115 a Duplicate (BB07020-DUPl) Prepared & Analyzed: 02/07/2018 12:11 i_ Source: CA18891-01 Spike Source %REC RPD Anal vte Besot Flaq POL Units Level Res I %REC Limlits RPD Limit Notes Biochemical Oxygen Demand 200 2.0 mg/L 200 2 30, Batch 8809012 - NO PREP Prepared & Analyzed: 02/09/2018 10:25 Blank (BB09012-BLK3) 1 Spike Source %REC RPD Analyte Result Flaq POL units Level Remit %REC Limits RPD Limit Notes Total Suspended Solids 2 .51 U 2.5 mg/L L LCS (8809012-BS1) Prepared & Analyzed: 02/09/2018 10:25 Spike Source %REC RPD Anal vSQ Result Flan PQL units Level Result %REC Limits RPD Limit jyotes Total Suspended Solids 91 2.5 mg/L 100 91 80-120 Duplicate (SB09012-DUPl) Prepared & Analyzed: 02/09/2018 10:25 Source: C000147-01 Spike Source %REC RPD Anaivtir Result Han P-QL Units Level Result %REC Limits RPD Limit Notes Total Suspended Solids 44 33 mg/L 41 6 20 Duplicate (8B09012-DUP2) Prepared & Analyzed: 02/09/2018 10:25 Source:CB01009-01 Spike Source %REC RPD ,- Analyse R4.Sti(t Flan FQL Units, . Level Result %REC Limits RPD Limit Notes„ Total Suspended Solids 27000 2500 mg/L 28000 2 20 Batch 8809013 - Same Blank (8B09013-BLK1) Prepared: 02/09/2018 10:13 Analyzed: 02/09/2018 15:00 L - Spike Source %REC RPD I� AnaLltte Result Flan M Units Level Result %REC Limits RPD limit ', !votes Chemical Oxygen Demand 10 U 10 mg/L LCS (BB09013-BS1) Prepared: 02/09/2018 10:13 Analyzed: 02/09/2018 15:00 Spike Source %REC RPD - Anal Chemical Oxygen Demand Result 490 Flag PGL 10 Units mg/L Level Result %REC Limits 98 90-110 RPD limit Dotes .500 FINAL This report relates only to the sample as received by the1aboratory; and,may only be -reproduced -in full, -- — - - - Page 5 of 8 - Www.encolabs.com. ANALYTICAL RESULTS Description: SBM _ Lab Sample ID: CB010.09-01 _ - _ Received: 02/06/18 09:00 Matrix: Sludge Sampled:02/06/18 08:45 Work Order: CB01009 Project: Monthly - SBM Sampled By: Brooks Williams Classical Chemistry Parameters A - ENCO Cary ceitiAed analyte [NC 5911 Y- — — Analyte- fCAS Numberl -- - Results - - 1eta - -UmIt!;---- - - -bF- --MDL- - POIL - ---Batch- --Method ----Analyzed - -ft—Notes----- Biochemical Oxygen DemandA 12000 mg/L 1 2.6 2.0 8B07020 SM 521OB-2001 02/07/18 12:11 ]OC Chemical Oxygen DemandA 31000 mg/L 40 400 400-8B09013 - SM 5220D-1997 - 02/09/18 15:00 -30C - ___.___Total.Suspended-Solids^.__. - __ _ __ ___ ____ 28000-_ _ I i ' I t _ mg/L_ 1000 . 2500.-2500__:.8B09012 _SM-2540D-1997- . 02/09/1810:25. OMR FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 8 www.encolabs.com SAMPLE DETECTION SUMMARY ! Client ID: SBM Lab ID: CB01009-01 Analvte Results fla9 MDL E" Units Method Notes Biochemical Oxygen Demand 12000 2.0 2.0 mg/L SM 521OB-2001 Chemical Oxygen Demand 31000 400 400 mg/L SM 5220D-1997 Total Suspended Solids 28000 2500 2500 mg/L SM 254OD-1997 I t I , FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 8 j 0 EN t-Ni`Crafontzes Accurate. - - 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Friday, March.23, 2018 --- - - - - - -- Novozymes North America (N0008) Attn: Scott Creech - ---- 77 Perry Chapel -Church Road - - - - — — - Franklinton, NC 27525 RE: Laboratory Results for _- Project Number: [none], Project Name/Desc: Monthly - Week One - 513M ENCO Workorder(s): CB01518 i - Dear Scott Creech, Enclosed is a copy of your laboratory report .for test samples received by our laboratory on -3 Tuesday, March 6, 2018. Unless otherwise'noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as, noted in, the project narrative if applicable. This report shall not be reproduced except in -full,_without-the-written -approval of the -Laboratory. ---- This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. _ If you have any questions or require further information, please do not hesitate to contact me. Sincerely, CIL - Chuck Smith - Project Manager Enclosure(s) FINAL _ _ This report relates only to the sample as received by the laboratory, and may only -be reproduced in full. Page 1 of 11 - - CS N www.encolabs.com SAMPLESUMMARY/LABORATORY CHRONICLE Client ID: SBM Lab ID: CB01518-01 Sampled: 03/06/18 OBAS Received: 03/06/18 09:00 Parameter preparation Hold Date/Timers) Preo Date/Time(s) Analysis Date/Timers) CALC 300.0 NO PREP 11/29/20 03/12/18 14:08 03/12/18 14:08 CSU Method NO PREP 11/29/20 03/07/18 09:14 03/13/18 09:05 EPA 300.0 NO PREP -03/08/18 08:45 -03/07/18 23:31 03/07/18 23:31 EPA 350.1 NO PREP 04/03/18 03/17/18 11:21 03/17/18 11:21 EPA 6010D ' _ EPA 3005A - 09/02/18 -- 03/07/18 09:14 `: 03/12/18 14:26 EPA 7470A EPA 7470A 04/03/18 03/07/18 13:22 03/08/18 10:16 SM 254OB-1997 NO PREP 03/13/18 03/13/18 12:25 03/13/18 12:25 Client ID: SBM Lab ID: CB01518-01RE1 Sampled: 03/06/18 08:45 Received: 03/06/18 09:00 Parameter EPA 351.2 Preoaration _ _ Same _ _ , . Hold Date/Timers) 04/03/18 Prep Date/Time(s) 03/13/18 12:28 Analysis Date/TimeW _ 03/15/18 13:54 EPA 365.4 Same 04/03/18 03/13/18 12:37 03/21/18 14:17 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. ,I www.encwlabs.com _ _ __ _ _ _ _ •'_ SAMPLE DETECTION SUMMARY Client ID: SBM Lab ID: CB01518-61 Analyte Results Elks MDDL POL Units Method Notes Aluminum - Total . 355 0.420 1.00 _ mg/L EPA 6010D Ammonia as N 80 D 4.5 10 mg/L EPA 350.1 - Calcium -Total - 2260 0.390 1.00 mg/L EPA 6010D Copper- Total 0.449 0.0160 0.100 mg/L EPA 6010D Lead.- Total' 0.0473 3 0.0310 .0.100 . mg/L , EPA 6010D - Magnesium ---Total-- - - --- - - - ----57.1 -- - - -0:290 - 1.00 --' . mg/L -' ---EPA 6010D-- Molybdenum - Total 0.0460 1 0.0250 0.100 mg/L . EPA 6010D Nickel- Total , 0.0775 3 0.0220 0.100 mg/L EPA 6010D Nitrate as N', 30 _ .' _ D 2.0 . _ - 5.0 - _ mg/L - _ _ _ _ - EPA 300.0 R-05 Nitrate/Nitrite as N 31 0.20 0:50 mg/L CALC 300:0 Nitrite as N 1.3 D 0.080 1.0 mg/L EPA 300.0 R-05 Potassium - Total 924 1.50 5:00 mg/L EPA 6010D Sodium - Total 123 4.00 5.00 mg/L EPA 6010D Sodium Adsorption Ratio 0.697 [blank] CSU Method Total Solids 3.6 0.25 0.25 % by Volume SM z540B-1997 Zinc - Total 1.20 0.0440 " 0.100 mg/L EPA 6010D Client ID: SBM Lab ID: CB01518-01RE1 . Analvte - - Results Hn MDL PPOL Units Method Notes Phosphorus 540 BD 4.0 6.0 mg/L EPA 365.4 QB-01 Total Kjeldahl Nitrogen 1500 D 18 25 mg/L EPA 351.2 _- - FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 11 WWW.encolabs.com ANALYTICAL RESULTS Description: SBM Lab Sample ID:CB01518-01 ' Received: 03/06/18 09:00 J Matrix: Sludge - . Sampled:03/06/18 08:45 'Work Order: CB01518 Project: Monthly - Week One - SBM Sampled By: Brooks Williams Metals by EPA 6000/7000 Series Methods I ^ - ENCO Cary rectified analyte [NC 591] - Aname rCAS-Numberl-- - - Results Mercury[7439-97-6]^ 0.0007510 Flag U Units' mg/L bF 5 MD 5' -' gi 0.000750 0.00100' Batch 8C07024 - -Method EPA 7470A na ed 03/08/18 10:16 By Notes CMK �I Metals (total recoverable) by.EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 5911 Analvte rCAS Numbed -- - Results- - --Units.- - PE MPUL -- - Batch-- Method- - --' Analyked Aluminum [7429-90-5]^ 355 mg/L 10 0.420 1.60 '8C07008 EPA 6010D` 03/12/18 14:26 JDH Arsenic[7440-38-2]^ 0.0680 U mg/L 10 0.0660 0.100 8607008, EPA 6010D 03/12/18 14:26 JDH Cadmium [7440-43-9]^ 0.00360 U mg/L 10 0.00360 .0.0100 BC07008 EPA 6010D 03/12/18 14:26 JDH Calcium [7440-7072]^ 2260 - mg/L 10 0.390 1.00 BC07008 EPA 6010D, 03/12/18 14:26 JDH _ Copper[7440-50-8]^ 0.449 mg/L 10 0.0160 0.100 8C07008 EPA 6010D 03/12/18 14:26 JDH Lead [7439-92-1]^ -" 0.0473 1— mg/C, 10 0.0310 0.100 BC07008' "EPA 6010D - 03/12/18 1426 JDH _ Magnesium [7439-95-4]^ 57.1 mg/L 10 0.290 1.00 8C07008 EPA 6010D 03/12/18 14:26 JDH �I Molybdenum [7439-98-7]^- 0.0460 J mg/L 10 0.0250. 0.100 8C07008 EPA 6010D 03/12/18 14:26 JDH .- Nickel[7440-02-0]^ 0.0775 jr mg/L. 10 --0.0220 0.100 8C07008 EPA 6010D_ 03/12/18 14:26 _ JDH Potassium [7440-09-7]^ 924 mg/L 10 1.50 5.00 8C07008 EPA 6010D 03/12/18 14:26 JDH Selenium [7782-49-2]^ 0.0620 U mg/L 10 0.0620 0.100 8C07008 EPA 6010D 03/12/18 14:26 JDH Li Sodium [7440-23-5]^ '123 mg/L 10 4.00 5.00 BC07008, EPA 6010D 03/12/18 14:26 JDH Zinc[7440-66-6]^ 1.20 mg/L 10 0.0440, 0.100 8C07008 EPA'6010D 03/12/18 14:26 JDH Classical Chemistry Parameters I ^ - ENCO Cary rectified analyte [NC 5911 Analvte rCAS Numberl Results Flaa Uni DF MDL P L Batch Method Analyzed Notes Ammonia as N [7664-41-7]^ 8o D mg/L" 100 4.5 10 8C17002 'EPA 350.1 03/17/18 11:21 JLI j Nitrate as N [14797-55-8]^ 30 D mg/L 10 2.0 5.0 8CO8020 EPA 300.0 03/07/18 23:31 MKS R-05 Nitrate/Nitrite as N^ 31 • mg/L 1 0.20 0.50 BC12015 CALC 300.0 03/12/18 14:08 MKS Nitrite as N [14797-65-0]^ 1.3 D mg/L 10 0.080 1.0 BC08020 EPA 300.6 03/07/18 23:31 MKS R-05 Sodium Adsorption Ratio 0.697 [blank] 1 8C07008 CSU Method 03/13/18,09:05 JDH Total Solids^ 3.6 % by Volume '50 0.25 0.25 8C13013 SM 254OB-1997 03/13/18 12:25 OMR Classical ChemistryParameters ^ - ENCO Orlando rectified analyte [NC 424] , w_ Analyte rCAS Numbed Results Flaa Units DF MDL POIPOL Batch Method Analyzed B Notes Phosphorus[7723-14-0]^, 540 BD mg/L_ 200 4.0 6.0 - 8C13031 EPA 365.4 03/21/18 14:17 Kdonz QB-01 Total Kjeldahl Nitrogen 1500 D mg/L , '500 18, 25 8C13030 EPA 351:2 03/15/18 13:54 kgonz I I FINAL - - This report relates only to the sample as received by the laboratory, and may only be reproduced in'fult, Page 4 of 11 i www.encolabs.com, _._ QUALITY CONTROL DATA _ --_ Metals by-EPA-6000/7000 Series -Methods --Quality Control --- Batch 8CO7024 - EPA 245.1 Blank (8C07024-BLK1) Prepared: 03/07/2018 13:22 Analyzed: 03/08/2018 09:55 - - = - - %REC ROD - - - Spike Source Result - Flag P91- ft --Level- - /oREC 61p]I�E- --RPD`, !milt - 1YGus - - Bgsillt - P . Mercury 0.000150 U 0.000200 mg/L - ` Blank (BC07024-BLK2) Prepared: 03/07/2018 13:22 Analyzed: 03/08/2018 09:57 Spike Source - %REC RPD r �Dande - _--- --� _»3esult Flag P-4L Units _T. _Level - Result "/oREC ..Limits.._ Mercury 0.00300 U 0.00400 mg/L LCS (8C07024-BSI) Prepared: 03/07/2018 13:22 Analyzed: 03/08/2018 10:00 I Spike Source- '. %REC RPD . Anal Ytg Result. 'flam POL Moft. Level Result %REC Limits RPD Limit Notes Mercury 0.00561 0.000200 rrg/L 0.00500 112 80-120 - Matrix Spike (8CO7024-MS1) ;_ _ _ _ Prepared: 03/07/2018 13:22 Analyzed: 03/08/2018 30:05 Source: CB02742-02 Spike Source %REC RPD AnalYte Result Elan ' P-L Ueits Level Result ' %REC Limits RPD Limit Notes Mercury 0.00609 0.000200 mg/L 0.00500 0.000150 U 122 75-125 Matrix Spike Dup (SC07024=MSD1) Prepared: 03/07/2018 13:22 Analyzed: 03/08/2018 10:07 Source: CB02742-02 Spike Source %REC RPD Analvte Result Elag P_QL Units • Level Result %REC Limits RPD Limit Notes Mercury 0.00602 0.000200 mg/L 0.00500 0.000150 U 120 75-125 1 25 Post Spike (SC07024-PS1) Prepared: 03/07/2018 13:22 Analyzed: 03/08/2018 10:09 Source: CB02742-02 Spike Source %REC RPD Anal Ytg Result Elao M Units, Level Result %REC Limits RPD Limit Notes Mercury 6.96 0.200 ug/L 5.00 0.0100 139 75-125 QM-08 Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 8CO7008 - EPA 3005A Blank (SC07608-BLK3) Prepared: 03/07/2018 09:14 Analyzed: 03/12/2018 13:55 Anal 1d8 Result Flao, EM Units Aluminum 0.0420 U 0.300 mg/L Arsenic 0.00680 U 0.0100 mg/L Cadmium 0.000360 U ' 0.00100 mg/L Calcium 0.0390 U 0.100 mg/L Copper 0.00160 U • 0.0100 mg/L i Lead- 0.00310 U 0.0100 mg/L Magnesium 0.0290: U 0.100 mg/L Molybdenum 0,00150 _ . U _ 070100 mg/L l Nickel 0.00220 U 0.0100 mg/L Potassium 0.150 U 0.500 mg/L Selenium 0.00620 U 0.0100 mg/L Sodium 0.400 U 0.500 mg/L Zinc I 0.00440 U . 0.0100 mg/L Spike Source %REC Level Result %REC Limits RPD RPD Limit FINAL_ _ _ This report relates only-fA the sample as received by the laboratory, and may only be reproduced in full. 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OOT'O - _ b0'Z _ _ wntsau6eW LI OZI-08 OZT-08. b0I 86 - O0Z'0 ..00Z"O 1/6w OOTO'O 8OZ'O peal l/6w OOTO'O S6T'0 OZT-08 b0T - - 00'Z l/6ui, - OOT'0 60'Z wnl:)IL 0ZT=08 - - EOT - -: OOZO'0 - - l/6w OOT00'0 - - - -LOZO'0 _ -- -- wnlwpQ OZT-08 b0T OOZ'O l/6w- . • --OOTO'0- -- — — 60Z'O----- -- - aluasiy OZI-08 66 00'Z 1/6w OOT'0 86'T wnulwnly 7?IQf� ad8 3MM :)38% �jii5a$ Canal — - — - ad8 - D38% aamoS aHlds 00•bi 8TOZ/ZT/£0 •paleW bT•60 8TOZ/LO/EO .paiedaJd (T58-800L0)8) Sal pangiau0.7 - V900S W3 - 800L0.78 9-74e8 louuo:) Atpena _ spoglaN sai1as OOOL-/0009-Vda-A4(algeAanooaa ligm) sle;aW V1V01O81N00 A-LiiV t) ! woo-sgelooue-mmm ra I- -- — -- - - -_ - -- - - QUALITY CONTROL DATA Metals (total -recoverable) by EPA 6000/7000 Series Methods - Quality Control - - " _"- - • " - Batch 8CO7008 - EPA 3005A - Continued Post Spike (SC070087PS1) Prepared: 03/07/2018 09:14 Analyzed: 03/12/2018 14:07 - -Source:-CB03667-03 - - - - - - - = - _ - -- '---Spi - ke- Source- -- _--- %REC - _ - _. '=RPD Analybe =PQL - 'Slnitf_"_-Leve1-- - -gg£411�- %-REC- �� - �RPD_T -- LlBllt -- ._._ Notes. - - - Aluminum 3.34 0.100 mg/L 2.00 1.31 102 80-120 Arsenic 0.196 0.0100 mg/L 0.200' -0.000196 98 80-120 . , , Cadmium' 0.0196 0.00100 mg/L 0.0200 -0.000101 - -` 98 80-120 - Calcium. 5.94 0.100 mg/L 2.00. 3.87 103 80-120'' 0.203 - _0.0_1_00 _` mg%L 0:200� ^ 0.0132. __95 80420 - Lead '0.201 0.0100 mg/L 0.200 0.00235 100 80-120 ' Magnesium. 7.39 0.100 mg/L 2.00. 5.20 109 80-120 Molybdenum 0.188 0.0100 mg/L 0.200 0.000529 94 80-120 Nickel 0.196 0.0100 mg/L 0.200 0.00550. 95 80-120 Potassium .12.8 0.500 . mg/L . 10.0 2.76 100 80-120 r. �. Selenium - - - --- - --- 0.198. - - - - 0.0100 -. mg/L. - - .0.200 - -0.00266 - - 99 -86-120L --- --s= Sodium -- --.. _ ---- : _-- =--=;21.5: --- - - - - 0.500 -mg/L-- -10.0- - - -11.5---- - - 100- -- 80 120 _ - - - Zinc --- _ - 0.215 - 0.0100 - mg/L 0.200 - 0.0103 102 '- 80-120 - - - - Classical Chemistry Parameters - Quality Control Batch 8CO7008 -'EPA 3005A - Blank (SC07008-BLKI) Prepared: 03/07/2018 09:14 Analyzed: 03/13/2018 09:06 i� Spike Source %REC RPD Anal lRe Result Flan P-41- Unim Level Result %REC Limits RPD Limit Notes Sodium Adsorption Ratio 0.00 U [blank] Batch 8CO8020 -'NO PREP Blank (81t0B020-6LK1) Prepared & Analyzed: 03/07/2018 19:52 Spike Source %REC RPD Anal vte' Result Flan RM Uloitf Level Rat %REC Limits RPD Limit Notes Nitrate as N 0.20 U 0.50 mg/L Nitrite as N 0.0080 U 0.10 mg/L LCS (8C08020-BSI) - Prepared & Analyzed:.03/07/2018 21:05 Spike. Source, P/oREC RPD Anal 1[t0 Result ElM Eft UDi= Level Result %REC Limits RPD Limit Notes . Nitrate as N - 4.8 0.50 mg/L 5.00 96 90-110 Nitrite as N 1.0 0.10 mg/L 1.00 101 90-110 Matrix Spike (BC68020-MSI) . Prepared & Analyzed: 03/08/2018 03:38 1 Source: CB01519-07 - Spike Source %REC RPD Anal Result Flan POL Unite Level Result'. %REC Limits RPD, Limit 1. Notes Nitrate as N 4.8 0.50 mg/L 5.00 0.05 95. 90-110 Nitrite as N ,' 1.1 0.10 mg/L 1.00 0.101. 100 90-110: Matrix Spike (SC68020-MS2) - Prepared & Analyzed: 03/08/2018 04:07 i Source: CB01519-04 Spike Source. = %REC RPD Anal Result Flan DQL Unitf Level Result %REC Limits , RPD Limit Notes Nitrate as N 6.3 0.50 mg/L 5.00 1.2 103 . 90-110 Nitrite as N 1.1 0.10 mg/L 1.60 0.12 101 90-110 _ . _ FINAL _ _ _ _ _ - :.This report relates only to the _sample as received by the laboratory, and_ may -only be reproduced in full. - Page 7 of 11 - OE Mhk 00 www.encolabs.com QUALITY CONTROL DATA - Classical Chemistry Parameters - Quality Control. Batch 8CO8020 = NO PREP - Continued Matrix S ike Du .(8C08020-MSD1) Prepared, & Analyzed: 03/08/2018 03:52 Source: C601519-07- Spike Source %REC RPD - _ Anal Result Elag P-QL Units Level Result %REC .Limits RPD Mmit Notes _ Nitrate as N 4.8 0.50 mg/L 5.00 0.05 96 90-110 1 10 1 Nitrite as N 1.1 0.10 mg/L 1.00 0.10 100 '90-110 _ 0.3 10 I Batch BC13013 - NO PREP ((( Blank (8C13013-BLK1) Prepared & Analyzed: 03/13/2018 12:25 { j t Spike Source %REC RPD { Anal vte Result flag PQL Units Level Result %REC Limits RPD Limit Notes Total Solids 0.0050 U 0.0050 % by Volume LCS (8C13013-BS1) Prepared &Analyzed: 03/13/2018 12:25 Spike Source %REC RPD Anal lf Result fla_o EM Units Level Res 1 %REC Limits RPD Limit Notes Total Solids 1100 50 mg/L 1100 99 80-120 Duplicate (BC13013-DUPl) Prepared & Analyzed: 03/13/2018 12:25 Source: CB01517-01 Spike Source %REC RPD Analvt8 Result Elaa P9L Units Level Result %REC Limits RPD Limt Notes Total Solids 0.23 0.0050 % by Volume 0.22 1 20 Batch 8C17002 - NO PREP Blank (8Cl7002-BLK1) Prepared: 03/17/2018 10:55 Analyzed: 03/17/2018 10:55 Spike Source %REC RPD AnalResult Flag EM Units Level Result o/aREC Limits RPD Limit Notes Ammonia as N 0.045 U 0.10 mg/L LCS (8C17002-6Sl) Prepared: 03/17/2018 10:56 Analyzed: 03/17/2018 10:56 Spike Source %REC RPD Analvte Result ft" PQL Units Level . Result %REC Limits RPD Limit Notes Ammonia as N 1.0 0.10 mg/L 0.989 104 90-110 Matrix Spike (8C17002-MS1) Prepared: 03/17/2018 11:00 Analyzed: 03/17/2018 11:00 Source: CA15909-02 Spike Source %REC RPD AualYie Result Elan P-M :Units Level Result. %REC Limits RPD Limit Notes Ammonia as N 0.60 0.10 mg/L 0.385 0.24 95 90-110 Matrix Spike (8C17002-MS2) Prepared: 03/17/2018 11:08 Analyzed: 03/17/2018 11:08 Source: CA16631-01 Spike Source %REC RPD Analybe Result Elan P-QL units. Level Result %REC Limits RPD Limit Notes Ammonia as N 0.31 0.10 mg/L 0.385 0.045 U 80 90-110 QM-07 Matrix Spike Dup (8C17002-MSD3) Prepared & Analyzed: 03/17/2618 11:02 Source: CA15909-02 . Spike Source %REC' RPD Analtlte Result Elm PGL Units Level Result %REC Limits RPD Limit Notes Ammonia as N 0.61 0.10 mg/L 0.385 0.24 96 90-110 0.8 10 Classical Chemistry Parameters - Quality Control FINAL This report relates onlyto the sample as received by the laboratory, and may only be reproduced in full. Page 8 of 11 I� www.enoolabs,corn. I ( I, QUALITY CONTROL DATA � - -Classical i Chemistry Parameters -Quality Control- - _ I Batch SC13030 - NO PREP Blank (8C13030-BLKl) Prepared: 03/13/2018 12:28 Analyzed: 03/15/2018 13:06 Spike_—., Source -------, -- %REC— = �- —RPD -Anal -.. ' --- -- -- -_- _Result- Result- ._:F184- = P91' - Units.--._ Levef=== Result _--%REC==_.Limits-_-= RPD-_ __thi t-__--- Notctz__ Total Kjeldahl Nitrogen 0.037 U 0.050 mg/L LCS CBC13030-BSi} Prepared: 03/13/2018 12:28 Analyzed: 03/15/2018 13:07. Spike Source %REC RPD ' Anal vte Result Elan . PQl" Units "Level Result _ - %REC-----J6jmj Total, Kjeldahl Nitrogen 14 D 0.25 mg/L 12.5 108, 90-110 Matrix Spike (8C13030-MS1) Prepared: 03/13/2018 12:28 Analyzed: 03/15/2018 13:19 Source: ABO1886-01 Spike Source %REC RPD Anal Ytta• Result - Ehas P41 Units Level Result %REC --- Limits - RPD---- - lImit -Notes i Total Kjeldahl Nitrogen 6.8 D 0.25 mg/L 12:5 1.1 45 90-110 QM-07 - --- -- Matrix Spike (8C13030-MS2) _ _ _ _ - _ _ Prepared:_03/13/2018 12:28_Analyzed: 03/15/2018-13:15 — Source: ABO1895-01 r- • Spike , - Source - LL --%REC RPD Analyte Result Flao P-QL Urns Level' Result r-%REC Limits RPD Limit-'., Notes Total Kjeldahl Nitrogen 9.2 D 0.25 mg/L 12.5 2.1 5790-110 QM-07 ,— Matrix Spike Dup (8C13030-MSD3) Prepared: 03/13/2018 12:28 Analyzed: 03/15/2018 13:20 Ir Source: AB01886-01 III Spike Source %REC RPD Anal vte ResuIl Flaa POL Wit£ Level Re ul %REC Limits. RPD Limit Notes Total Kjeldahl Nitrogen 6.6 D 0.25 mg/L 12.5 1.1 44 90-110 2 10 QM-07 Batch BC13031 - NO PREP Blank (8C13031-BLK1) Prepared: 03/13/2018 12:37 Analyzed: 03/21/2018 13:34 I I_ ... Spike Source %REC RPD . Ana11(te Result Elan PM Units Level Result %REC Limits RPD Limit Notes Phosphorus 0.023 ] 0.030 mg/L QB-01 LCS (SC13031-8S1) Prepared: 03/13/2018 12:37 Analyzed: 03/21/2018 13:35 L'I Spike Source %REC RPD Anal ltie Result EIBs4. FQL '..Units Level Result' %REC_ ','Limits RPD' Limit '• Notes , Phosphorus 1.6 B' 0.030 mg/L 1.60 103. 90-110 QB-01 Matrix Spike (8C13031-MSi) Prepared: 03/13/2018 12:37 Analyzed: 03/21/2018 13:38 Source: ABO1886-03 Spike Source %REC RPD Anale Result Elm POL Units Level Result %REC Limits . RPD Limit Notes Phosphorus 0.85 B 0.030 mg/L 1'.60 0.18 42, 907110 QB-01' 1 Matrix Spike Dup (8C13031-MSDl) Prepared: 03/13/2018 12,37 Analyzed: 03/21/2018 13:39 Source:.A601886-01 Spike Source. . ' . - %REC RPD . Analtte Result Fps P46 Units Level Result %REC Limits - RPD limit Notes ,. . . I 'Phosphorus 0.85 B 0.030 mg/L 1.60'''. 0.18 42 . 90=110 0.2 '. 10 QB-Ol. - -FINAL: - -. - _ -received-by _ _ _ _ - - _ - ' This -report relates only tothe sample as .. ... . received by the laboratory, and may only be'repraduced (n full., ' . .. .. 9 of 1'1 www.encolabs.com j {L FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at'dilution. ] The reported value is between the laboratory method detection limit (MDL) and the laboratory method repotting limit (MRL); adjusted for actual sample -preparation data and moisture content, where applicable. _ U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation _ data and moisture content, where applicable. E - The concentration indicated for this analyte is an estimated value above the calibration range of the _ instrument. This value is considered an estimate. _ MRL . Method Reporting Limit. The MRL is roughly a uivalent to the practical qqagKitation limit PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution — factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit.. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. -' „ The lower concentration is reported. QB-01 The method blank had a positive result for the analyte; however; the concentration in the method blank is less than 10%, of the sample result. There is minimal impact to the data. QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. QM-08 Post -digestion spike did not meet method requirements due to confirmed matrix effects (dilution test). R-05 The sample was diluted due to the presence of high levels of non -target analytes resulting in elevated reporting limits. ENVIRONMENTAL CONSERVATION LABORATORIES CHAIN -OF -CUSTODY RECORD www.encolabs.com ' 10773 Central art Dt - - - 48110 Executive Faek Court, Stilts 111 - 102=A Woodwinds industrial CL - .. Criando, FL 31 8 4 .1atksmrx"„Pc, FL 32216-6M Cary, NO 27511 . (407) 821r5314 Fast i4o7) M-6WT (MA) 2aa-3307 . Fax (Diiwl) 29s-6210 3cso Fax (Jts)467-Mks Page' � of Client Name Proved Number Requested Analyses Requested Turnaround .71meS WO . RuSn 1e(iUe518 SW)JeCt to accsptancslly(hafaciiiry- Standard Expedited D'Ue...___l____�— . � 0 n ...a s � ' � O in _ �?' N C�55 (ri t[3 faj V .Address 7 F �( 'Cat : eI Church Road Month!-arVl•�k One - Sam CitylSTlZip PO d / Billet9 info' Tel t .;tea.-30t?Li Fax neForihtg Contat t Scutt Creech Sampler(' Name, Affiliation (Prin)) 511ing Contact Sam Sig are �.teLrac^9urJTimeZone !ab},Vorkorder C 0 �I rj Item a Sample ID (Fidld tdsnlc:icat dn) Collection Date Time Comp/ Gjab ispe codes) Con MIers Preservation (Se: Ccdes) (Compute as necessary) 1 �z Sample Comments t i<--Total tt of Containers SamQfe Kit Prepared By . Datel ime Rat! e Dalaifttns Rece)sed By % Daternme -111/ rljz) CammentslSQee a1'RapOriing Hequitsmsnts... R ' hed 8 - i natbTime Racenttt By Datelrme . Reiraq shed By Dates m Received By ' . Datemme . Cooier4'sBTernpsdXilReceipl' v . i. . . Condition pan Receipt - - . Acceptable Unacceptable Matrix: GW-Groundwater so -Soil DW-Drinking Water SE -Sediment S:N-Surtan'-Water wtv-vtasttvr3ter a -tart v-tarter tcte7a�r us cammeu,st rreseruacwre: Face n-es ny; ry c�j �•na�va Wv-Navas v-vuiar taemi, m commgmsl - Note: All samples sutalined io ENGO Lets are in aowada =1 Winn late :arms and candrtiDns listed on the rsrarsaof 11ft form, unless price written agreements exist - . Sample Preservation Verification ENCO Cary Work Order: CB01518 Project: Monthly - Week One - SBM Client: Novozymes North America (N0008) Project #: [none] Logged.ln: 06-Mar-I8 11-.32 Logged By: John. C King Preservation Check Performed By: j Date/Time:'� -CB01618-01 Cont. i " ti YP v '.:.P�res 4i?) ,. ' Requirement-' ;PH Che ked* In,r�nfrot. pH AdjGstedr °. `. Da f Fime Adjusted Reagent, Used/Comments - • A 250mLP+H2SO4 <2 YIN / 'NA / N / NA B 250mLP+HNO3 e2 Y I _ / NA Y / rN ! NA ' .} Reagent Name ID 1 2 Fq pH Strip ID:�� C:\ELMNT\Print\wko_PreservationCheck. rpt Reagent Name ID Rea ent Name ID 3 5 4 6 Page 1 of 1 Name ID Rea ent Name ID 3 5 4 6 Page 1 of 1 Laborat - I C160 )0�14 1 t . es onsive, Innovative. 102-A-Woodwinds Industrial Court- Cary NC, 27511 Phone: - 919.467.3090 FAX: 919.467.3515 Tuesday, April Novozymes North America (N0008) Attn: Scott Creech -77 Perry Chapel Church Road - - ------ Franklinton, NC 27525 RE:, Laboratory Results for' - _ Project Number: [none], Project Name/Desc: Monthly - SBM - ----ENCO-Workorder(s): CB03654 -- -- - -, - - - - - - _ _ - • ----- ---- --- — - l- — -- = --= - Dear Scott Creech, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Tuesday, April 3, 2018. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in'accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with. NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in. full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise' noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, -! Chuck Smith - Project Manager Enclosure(s) FINAL This report relates only.to the sample as received by the laboratory, and may only be reproduced in* full. _ - - - Pages of s -' == ccw=�_ www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: SBM Received: 04/03/18 09:00 --Lab ID: CB03654-01 Sampled: 04/03/18 08:09 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) ,Analysis Date/Time(s) SM 254OD-1997 NO PREP 04/10/18 04/09/18 14:00 04/09/18 14:00 SM 521OB-2001 NO PREP 04/05/18 08:00 04/04/18 14:27 04/04/18 14:27 SM 5220D-1997 Same 05/01/18 04/05/18 10:54 04/05/18 17:41 -- FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. - - - Page 2 of 8 www.encolabs.com SAMPLE DETECTION SUMMARY J. Client ID:= SBM - _ ___ _ __ _ _-- Lab ID:. CB03654-01__ Analvte Results, Ells4 MP-L M Units Method Notes Biochemical Oxygen Demand 11000 2.0 - 2.0 mg/L SM 5210E-2001 Chemical Oxygen Demand 28000 400 400 mg/L SM 5220D-1997 Total Suspended Solids 24000 2500 2560 nig/L SM 2540D-1997 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. -Page 3 of'8- ' ` - cl ' www.encolabs.com ANALYTICAL RESULTS Description: SBM_ _ _ _ _ _- . _ _ Lab Sample ID:CB03654-01 _ - Received: 04/03/18 09:00 - Matrix: Sludge Sampled:04/03/18 08:00 Work Order: CB03654 Project: Monthly - SBM Sampled By: Brooks Williams _ Classical Chemistry Parameters r a n_ENCOo2wceiinedanaW[NC 591] --—Analvte fCAS Numbed - -- - -Results-- -Flaa----Units-: - - - - - — DF- - 1DI - - POLL h -- at ----Met --Method' --�— n I - A a vied - - -� ---Notes Biochemical Oxygen Demand^ 11000 mg/L 1 2.0 2.0 6D04018 SM 521OB-2001 04/04/18 14:27 JOC Chemical Oxygen Demand^ 29000 mg/L 40 400 .400 . 8DO5005 SM 522013-1997 04/05/18 17:41 . ]OC Total Suspended SolldsA 24000 mg/L 1000 2500 .2500 - 8DO9010 SM 254OD-1997 04/09/18 14:00 OMR- - -- = - - - -__ FINAL - - This report relates'only to the sample as received by the laboratory, and may only be reproduced in full.- _ I page 4 of 8 - QUALITY CONTROL -:DATA ------ Classical ChemistryParameters---Qua ityContra,-=--- - ------------------ -- - -- — ---- -"------- ------ -- -- - - - -- - Batch 8004018 - NO PREP Blank (8D04018,BLK1) Prepared & Analyzed: 04/04/2018 14:27 - -- -- -- Spike Source - .%REC - RPD - _ Ana17CtQ Result Mau M Units Level Result. %REC Limits _ RPD _. Limit Notes 1 . Biochemical Oxygen Demand I • 2.0 U 2.0 mg/L '. LCS (8D04018-BSI) Prepared & Analyzed: 04/04/2018 14:27 ISpike Source%REC RPD Analytg, _ Result - Han, MQL .Units Level _ - Result %REC _-Limits_ RPD b1011t ., _- Notes Biochemical Oxygen Demand 210 2.0 mg/L 198 104 857115 Duplicate (8D04018-DUPl) Prepared & Analyzed: 04/04/2018 14:27 Source: CB02991-01 Spike Source %REC - RPD - -._- -Result-,-=F2a9e------PP.L---------Units - Level Result, _ %REC--Ljmjt�.----RPD- - - - - - Limit - Notes - Biochemical Oxygen Demand 750 2.0 mg/L ,_ 1100 40 30 QM-12, Batch 8005005 - Same Blank (8D05005-BLKl) Prepared: 04/05/2018 10:54 Analyzed: 04/05/2018 17:41 - Spike Source' %REC RPD AnalYffi Result Elan PQL Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 10 U 10 mg/L LCS (8DOS005-BSI) Prepared: 04/05/2018 10:54 Analyzed: 04/05/2018 17:41 Spike Source %REC RPD ABalyte Result Elan PQL Units Level Result %REC Limits RPD Limit' Notes Chemical Oxygen Demand 510 10. mg/L 500 102 90-110 Matrix Spike'(8D05005-MSI) Prepared: 04/05/2018 10:54,Analyzed: 04/65/2018 17:41 Source: CA15890-03 Spike Source. %REC RPD Anal Yte Result Flan M Units; Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 1600 20 mg/L 1000 630 95 90-110 Matrix Spike Dup (8D05005-MSDI) Prepared: 04/05/2018 10:54 Analyzed: 04/05/2018,17:41 Source: CA15890701 - - Spike Source %REC RPD Analyse .. Result Flan PQL Units Level Result %REC. Limits w ,. RPD Limit Notes Chemical Oxygen Demand 160Q 20 mg/L 1000 630 94 90-1'SO 0.5 10 Batch 8D09010 - NO PREP Blank (8D09010 BLKl) I Prepared & Analyzed: 04/09/2018 14:00 Spike Source %REC RPD Anil lde Result Flan, PQL Unft Level Result %REC -Limits . RPD Limit Notes Total Suspended Solids . 2.5 . U 2.5 mg/L LCS (SD09010-BS1) Prepared & Analyzed: 04/09/2018 14:00 _ Spike ' Source .- : %REC -- _ RPD Anal vte Result Elan P46 Unitf.. Level ResulE %REC Limits.. RPD 11I8jt, Total -Suspended Solids 88 2.5 mg/L .100 88 80-120 FINAL -'•This report relatevonly to the sample as received by the laboratory, and may only be reproduced in full. -' ---- - -- - Page-5 of 8 - www.encolabs.com QUALITY CONTROL DATA - - Classical Chemistry Parameters - Quality Control Batch 8DO9010 - NO PREP - Continued Duplicate (81i)(119010-DUPi) Prepared & Analyzed: 04/09/2018 14:00 Source: CB02991-01 -- - • - Spike Source %REC RPD ---. _ —_— _ _ -. _ _B£SSllt . FJaA _ PQL Units - Level _ Result = %REC. _ .1101L7•^£ _ - RPD j,jD1[t Notes - .. Total Suspended Solids - . 1300 170 mg/L 1900 38 20 QM-12 Duplicate (8D09010-DUP2) Prepared & Analyzed: 04/09/2018 14:00 Source: CB03654-01 - - - _ - - Spike Source %REC RPD Analvte Result Flan PM Units Level Result %REC Limits RPD l.lmlt Notes . Total Suspended Solids 23000 2500 mg/L 24000 • 2 20 t i - _ -- - •--. - FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. i 1 i i .. - Page 6 of 8 - a www.encolabs.com, _ FLAGS/NOTES AND DEFINITIONS L B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. 7 The reported. value is between the laboratory method detection limit (MDL) and the laboratory -method -=-_ reporting -limit (MRL).-adjusted for actual sample preparation -data and moisture content, where applicable. - U The analyte was analyzed for but not detected to the a level shown, adjusted_ for actual sample preparation data and moisture content, where applicable. E. The concentration indicated -for this analyte is an estimated value above the calibration range of the — =- --- — - -instrument.-This value is considered an estimate. - - - - - 1 I MRL Method Reporting Limit. The MRL is roughly equivalent.to the practical quantitation limit (PQL) and is ' based on the low. point of the calibration 'curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL ' PQL: Practical Quantitation Limit. N . The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater r < - - confidence) to make-a"tentative. identification":_ P --- -• Greater than 25% concentration difference -was observed between the primary and secondary GC -column. -- The lower concentration is reported. r ; QM-12 Precision between duplicate samples was outside acceptance limits. . i L__ I . A -' = FINAL 2-This report, relates only to the sample as received'by the laboratory, and may only be reproduced in full. - : • - = Page 7 of 8 - ENVIRONMENTAL CONSERVATION (LABORATORIES CHAIN -OF -CUSTODY RECORD.. wut+ver.encolabs.com ).i 10775 Central Port Dr. 4910 Executive Park Court. Suite .111 . 1027A Woodwinds, Industrial:,_ L Orlando. FL 32824 Jacksonville, FL 3MI."069 Cary, NC27511 (407) 826-5314 Fax (407) 850.6945 (904) 29&3097 Fax (904) 29"210 (919) 457-2090 Fair (919) 467-35i 5 Page: Of. CGeni Name Project ]Number Requested Analyses. Requested Turnaround Nov:gyr11es North America (N-0.08) fnonei Times. Address C Project NarnelDesc Nate :Rush requests subject to .77 F ei ry Cnv= el Glwrchr Read Monthly - SOM acceplanre by Ihefacility . QitylsTIZIP FO 0/-Billing into Frark!'Wor, i1C 21752.E k 31&00850507 _ Standard Tel Fax Reporting Contact {C-1 E9 Etc, .-3000 Scott Creech � ��., 1. Expedited 11 Samplers) eme,Affiliation(Print) Wing Contact M 7 � ACCOUntf3 Paya ble 'Ja Due tSign tore S ra Laca4rore/ Tnrm.%ne U3 LaMorkordec' i f^;. Preservation (See Codes) (Combine as necessary)`36 Fd: Collection Malrix Tarai t of Item rr Sample to (Fleld Identification) i Collection Date Tmae Camp 1 Grab (see codes) Containers -Sample.CUmments �t n 4't3 j 8: �,j�I77�— _ - - - _ _ -- . . i I � } - �- t--Tnlal R of rnnfninprc Sample Kit Prepared By Date paternmeRe!' edq �Q/ m DatelnmRd/ o CommenislSpecial Repoding Requirements I i DaterFune Received 8y Date/Time Re7lnquishad By Date.Tirne Received ey Datarrilme Crwiara's K1emps,onFlecelpJ _ Conrftia�nReceipt _v Acceptable _ Unacceptable ... u+u�uuevu)nr avow+ uw-unm it g vvarar ae-beoimam aw-5uraaceioarer-aura-vvasrcwares a -nor u-urrer tasrau tin commems} rreservauon. race n-nur ry-riraua s-rwsu4 no-Naun u-umer toetau in comments) Note ; All samples submitted to ENCO tabs are In-aamrdanca with the terms and conditions listed on the reverse of INS ram), unless prior written agreements exist ii r - }i Sample PeeserVation. Verification ENO,'Cary EN .---Work. Order: -CB0654- --Project: Monthly = SBM - Client: Novozymes North America (N0008) Project '[none) Loggddlh: 03-Aot-1810:10 Logged By: John C King Preservation -Check Performed By: Date/Time:I 4�3r1c dB0365,4-01 A 250MLP+H2SO4 , <2- Y "NA Y I CR1 NA tf- 3, K I ?SYLA Rgagent Name ID Reagent Name ID '(*6O'CISIO .3 2 4F OH Strip ID: ic:\ELMNT.\Print\wko.Preservation-Check.rpt Rea-qent Name ID 5 61 Page 1 of 1 -- - - - - - - -- -- --- - - - ----- - - - -- - -- - --- -- - -- - --- - -- - --- -- 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Thursday, April 12, 2018 Novozymes North America (N0008) -- Attn:' Scott Creech 77 Perry Chapel Church Road Franklinton, NC 27525 RE: Laboratory Results for . Project Number: [none], Project Name/Desc: Monthly - Week One - SBM -- - - -- - ENCO Workorder(s):.CB03656 ------ - ----- --- -- -- - -- ------------- ----- --- ------ Dear Scott Creech; I - - Enclosed iss-a copy'of your laboratory report for test samples received by our laboratory on Tuesday, April 3, 2018. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This reportcontains only those analyses performed by Environmental Conservation Laboratories...Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Chuck Smith, Project Manager Enclosure(s). . _------ - - FINAL This report relates'only Wthe sample as received by the laboratory; and may only be reproduced -in -full. --- -Page 1 of-12 ' _ www.encolabs.com — ---- ------ -- - ----- SAMPLE SUMMARY/LABORATORY CHRONICLE____. ___-_ -_ _ _ -- --.-_ Client ID: SBM Received:- 04/03/1809:00-- _--_-LatrID:-CB0365&01-- Sampled: 04/03/18 08:00 — - -- Parameter Preparation- Mold Date/Time(s) P1ep Date/Time(51 Analysis Date/Time(s) CSU Method NO PREP 12/27/20 04/06/18 09:06 04/09/18 16:16 EPA 350.1 NO PREP 05/01/18 04/11/18 10:13 04/11/18 10:13 EPA 351.2 Same 6/01/18 04/06/18 11:56 04/09/18 11:11 EPA 353.2 . -NO PREP _ 04/05/.18 -08:00 04/03/18 17:30 04/03/18 17:30 - " EPA 353.2 -- —IVO PREP 12 27 20 -04/06/18 10:11— --04/06/18 10:30- EPA 365.4 Same 05/01/18 04/06/18 11:56. 04/09/18 12:44 EPA 6010D EPA-3005A---------- --09/30/18 - 04/06/18 09:06 04/09/18 14:41 EPA 7470A EPA 7470A 05/01/18 04/04/18 11:19 04/6/18 15:10 SM 2540B-1997 NO PREP - — 04/10/18— 04/10/18' 11:50 04/10/18 11:50 FINAL _ _ - Thisreportrelatgsonly _Wthe-sampleasreceived'bythe laboratory, and may only be reproduced in full. - - Page 2 of-12 - - - www.encolabsxom SAMPLE DETECTION SUMMARY Client ID:- SBM_ _____-- . ___ _- .- _-.- --_ _ .. Lab ID: - _CB03656-01._ Anallyte Results EL49 t9DL P46 .UnLts Method Notes Aluminum - Total 368 0.420 1.00 mg/L EPA 6010D Ammonia as'N 86 D 4.5 10 mg/L EPA 350'1 Arsenic - Total 0.205 0.0680. 0.100 mg/L EPA 6010D Calcium- Total - 2410 0.390 1.00 mg/L EPA 6010D' topper -,Total. _ _0.679 - ' _ 0.0160 0.100 mg/L EPA6010D. -- - Lead = Total--- - -' - -0.0367- 3 0.0310 - ; 0.100-- - -mg/L -' EPA 6010D Magnesium- Total 41.5 0.290 .1.00 mg/L EPA 6016D Molybdenum - Total 0.0270 3 0.0250 0.100 mg/L EPA 6010D • Nickel - Total 0.0615 1 ' 0.0220 0.100' mg/L EPA 6010D Nitrate as N 38 0.025 - 0.10 mg/L EPA 353.2 Nitrite as N; 0.50 0.017 0.10 mg/L EPA 353.2 Phosphorus, 680 D 10 40 mg/L EPA 365.4 QB-01 Potassium - Total, 663 1.50 5.00 mg/L EPA 6010D Sodium - Total 209 4.00 5.00 mg/L EPA 6010D Sodium Adsorption Ratio 1.15 [blank] CSU Method Total Kjeidahl Nitrogen 2100 D. 52 96 mg/L EPA 351.2 Total Solids 4.2 0.25 0.25 % by Volume SM 254OB-1997 Zinc - Total 1.25 0.0440 0.100 mg/L EPA 6010D This report relates only to the sample as received�by the laboratory, and may only be reproduced in.full. Page 3 of 12 - - - -- ANALYTICAL,RESULTS Description: ,SBM Lab Sample ID:CB03656-01 Received: 04/03/18 09:00 Matrix: Sludge Sampled: 04/03/18 08:00 Work Order: CB03656 Project: Monthly - Week One - SBM Sampled By: Brooks Williams Metals by EPA 6000/7000 Series Methods' . ^ - ENCO Cary certified analAe [NC 591] - - - Analyte rCAS Numberl Results F_la ,g ..Units DF MDL SL Batch Method Analyzed -Notes -- - i - Mercury,[7439-97-6]^ 0.000150 U mg/L 1 0.000150 0.000200 8D04024 EPA 7470A 04/05/18 15:10 CMK Metals (total recoverable) by. EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 5911 Analvte rCAS Numberl - Results Had Units gg. MU . pQL Batch Method, Analyzed 1>31C Notes. _ L Aluminum [7429-90-5]^ 368 mg%L 10 0.420 1.00 8D06010 EPA 6010D 04/09/18 14:41 JDH Arsenic[7440-38-2]^ 0.205 mg/L 10 0.0680 0.100, 8DO6010 EPA 6010D 04/09/18 14:41 JDH Cadmium [7440-43-9]^ 0.00360 U mg/L 10 0.00360 0.0100 8D06010 EPA 6010D 04/09/18 14:41 JDH" Calcium [7440-7072]^. 2410 mg/L 10 0.390 .1.00 8D06010 EPA 6010D 04/09/18 14:41 JDH Copper[7440-50-8]^ 0.679 mg/L 10 0.0160 0.100 8D06010 EPA 6010D 04/09/18 14:41 JDH •___ ___ _ Lead [7439-92-1]^ 0.0367 J mg/L 10 0.0310 0.100 8D06010 EPA 6010D 04/09/18 14:41 JDH -- Magnesium [7439-95-4]^ 41.5 mg/L 10 0.290 1.00 8D06010 EPA 6010D 04/09/18 14:41 JDH j " - Molybdenum [7439-98-7]^ 0.0270 J mg/L- 10 0.0250 0.100 8D06010 EPA 6010D 04/09/18 14:41 JDH Nickel[7440-02-0]^ 0.0615 '1 mg/L 10 0.0220 0.100 8D06010 EPA 6010D 04/09/18 14:41 JDH Potassium [7440-09-7]^ 663 mg/L 10 1.50 5.00 8D06010 EPA 6010D 04/09/18 14:41 JDH Selenium [7782-49-2]^ 0.0620 - U mg/L 10' 0.0620 0.100 8DO6010 EPA 6010D 04/09/18 14:41 JDH _ Sodium [7440-23-5]^ 209 mg/L 10 4.00 5.00 8D06010 EPA 6010D 04/09/18 14:41 .JDH Zinc17440-66-6]^ 1.25 mg/L' 10 0.0440 0.100 8D06010 EPA 6010D 04/09/18 14:41 JDH Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 5911 Analvte WAS Numberl Results Flag Units : DF MDL PP L Batch Method Analyzed l3jt Notes � Ammonia as N [7664-41-7]^ 86 D mg/L 100 4.5 10 81)11009 EPA 350.1 04/11/18 10:13 JU Nitrate as N [14797-55-8]^ 38 mg/L' 1 0.025 0.10 8D06016 EPA 353.2 04/06/18 10:30 JU Nitrite as N [14797-65-0]^ 0.50 mg/L 1 0.017 0.10 8D03028 EPA 353.2 04/03/18 17:30 JLI Phosphorus[7723-14-0]^ 680, D mg/L 400 10 40 8D06006 EPA 365.4 04/09/18 12:44 . JLI QB-'01 �^ Sodium Adsorption Ratio 1.15 [blank] 1 8D06010 CSU Method 04/09/18 16:16 JDH I - Total Kjeldahl Nitrogen^ 2100 D mg/L 200 52 " 96 8D06005 EPA 351.2 04/09/18 11:11 JLI Total Solids^ 4.2 % by Volume 50 0.25 0.25 8D10003 SM 254OB-1997 04/10/18 11:56 OMR' I = --- - FINAL .This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 12 - - www.encoiaos.com, I � . - - -QUALITY CONTROL -DATA- -.-._ __ _ - Metals by EPA.6000/7000 Series Methods - Quality"Control - - -- _ - .- - "--- - - -- -- - -- ---- - - --- -- - - - - - -' Batch 8DO4024 - EPA 245.1 f Blank (BD04024-BLKI)Prepared: 04/04/2018 11:19 Analyzed: 04/05/2018 14:46 Spike Source %REC RPD Anal Yte -.- Result .,- Ejag----P_QL __Units -- Level_ Result _ _%REC ( RPD _ Limit Notes { Mercury 0.000150 U 0.000200 mg/L •_ LCS (004024-111S1) Prepared: 04/04/2018 11:19 Analyzed: 04/05/2018 14:48 Spike , Source: %REC RPD Anal llte . Result Flag P91 Units Level Result %REC Limits RPD Limit Notes Mercury 0.00565 0.060206 mg/L 0.00500 113 80-120 Matrix Spike (SD04024-MS1) Prepared:' 04/04/2018 11:19 Analyzed: 04/05/2018 14:53 Source: CB03686-04 Spike Source %REC RPD Anal vte Result Flag POL Units. Level Re ul o/aREC Limit4. RPD Umit Notes Mercury I 0.00304 0.000200 mg/L 0.00500 0.600150 U 61 75-125 QM-07 Matrix Spike Dup (8Q04O24r.MSD1) -__ _ _ _ _ . _ _ _ ____. _ __ _ _ Prepared: 04/04/2018,11:19'Analyzed: 04/05/2018 14:55 _- Source: CB03686-04 I -- - - -T - -- Spike Source %REC RPD Anande - - - - - - Result ----Elan,- - M --- - Units-- Level'. Result --%REC---Ljm(ts -- -RPD-- -Limit Notes - Mercury 0.00311 0.000200 mg/L 0.00500 0.000150 U 62 75-125 2 25 QM-07 ' -- Post Spike (BD04024-PS1) I Prepared: 04/04/2018 11:19 Analyzed: 04/05/2018 14:58 i Source: C603686'-04 '- Spike Source %REC RPD Anal vte .. Result Flag Pr![, Units Level Result %REC 'Limits RPD Notes Mercury " 4.09 0.200 ug/L 5.00-0.0230 82 75-125 (_ Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 8D06010 - EPA 3005A _ ` Blank (8D06010-BLK3) i Prepared: 04/06/2018 09:06 Analyzed: 04/09/2018 13:17 - - Spike Source %REC RPD Anal lds Result _ Elm P91 Units Level Result %REC Limits RPD Limit Notes Aluminum 0.0420 U 0.100 mg/L Arsenic 0.00680 U 0.0100 mg/L.' Cadmium 0.000360 U 0.00100 mg/L Calcium 0.0390 U 0.100 mg/L Copper 0.00160 U 0.0100 mg/L Lead 0.010310' U 0.0100 mg/L Magnesium 0.0290 U 0.100 mg/L Molybdenum 6.00250 U 0.0100 mg/L Nickel 0.00220 U 0.0100 mg/L Potassium 0.150 U 0.500 mg/L I Selenium - 0.00620 U - 0.0100, mg/L Sodium 0.400 . U 0.500 mg/L Zinc 0.00440 U 0.0100 mg/L LCS (8D06010-13SI) Prepared: 04/06%2018 09:06 Analyzed: 04/09/201813:35 Spike Source' %REC RPD I' Anal ldg Result Flag PQL Units Level Result %REC Limits RPD Limit Notes i Aluminum 2.08 0.100 mg/L 2.00 .. 104 80-120 Arsenic 0.221 0.0100 mg/L 0.200. 111 8117120 __- ----FINAL- _-- _ - '.This report -relates only to the -sample as -received by the laboratory,- and may only -be reproduced in full: - _ - _--- - - ' _ - -Page 5 of-12 CS CM 0) www.encolabs.com ---QUALITY CONTROL DATA -- - Metals -(total recoverable)-by-EPA-6000/7000 Series-Methods---Quality-Control - - Batch 8DO6010 - EPA 3005A - Continued LCS (8D06010-BS1)'Continued Prepared: 04/06/2018 09:06 Analyzed: 04/09/2618 13:35 i Spike Source %REC RPD Analyte - - Result FJaa POL Units_ Level - Result „ _%REC_._Lmmmts__- _RPD - __ bjmft -_ _•_ Notes Cadmium 0.0217 0.00100 mg/L 0.0200 108. 80-120 Calcium 2.16 0.100 mg/L 2.00 108 80-120 Copper 0.216 0.0100 mg/L 0.200 108 80-120 Lead 0.217 0.0100 mg/L 0.200 .108 80-120 Magnesium T 2.03 0.100 . mg/L 2.00 302' 80-120 Molybdenum 0.220 0.0100 mg/L 0.200 110 80-120 - Nickel 0.222 0.0100 mg/L 0.200 111 80-120 Potassium 10.3 0.500 mg/L 10.0 103 80-120 j Selenium 0.226 0.0100 mg/L 0.200 113 80-120 Sodium 10.6 0.500 mg/L 10.0 106 80-120 Zinc 0.227 0.0100 mg/L 0.200 113 80-120 Matrix Spike (BD06010-MS1) Prepared: 04/06/2018 09:06 Analyzed: 04/09/2018 13:37 Source: CB010SS-01 Spike Source 0/aREC RPD Anal vte Result Eau P" Units Level Result o/aREC Limits RPD Limit Notes Aluminum 2.23 0.100 mg/L 2.00 0.0420 U 111 75 125 L� Arsenic 0.224 0.0100 mg/L 0.200 0.00680 U 112 75-125 Cadmium 0.0205 0.00100 mg/L 0.0200 0.000360 U 102 75-125 Calcium 80.8 0.100 mg/L 2.00 84.0 NR 75-125 QM-07 Copper 0.217 0.0100 mg/L 0.200 0.00160 U 108 75-125 Lead 0.212 0.0100 mg/L 0.200. 0.00310 U 106 75-125 Magnesium 13.4 0.100 mg/L 2.00 12.0 69 75-125 QM-07 Molybdenum 0.218 0.0100 mg/L 0.200 0.00250 U 109 Nickel 0.207 0.0100 mg/L 0.200 0.00220 U 104 75-125 Potassium - _ _15.9 0.500 mg/L 10.0 5.45 105 75-125 Selenium 0.212 0.0100 mg/L 0.200 0.00620 U 106 75-125 Sodium 24.5 0.500 mg/L 10.0 14.4 102 75-125 Zinc 2.42 0.0100 mg/L 0.200 2.29 66 75-125 QM-07 Matrix Spike Dup (8D06010-MSD1) Prepared: 04/06/2018 09:06 Analyzed: 04/09/2018 13:40 Source: CB010SS-01 Spike Source %REC RPD Anal Yte Result Flan . PGL Units Level Result. %REC Limits RPD UnI t Notes rL Aluminum 2.09 0.100 mg/L 2.00 0.0420 U 104 75-125 6 20 Arsenic 0.225 0.0100 mg/L 0.200 0.00680 U 112 75-125 0.6 20 I _ Cadmium 0.0210 0.00100 mg/L 0.0200 ' 0.000360 U 105 75-125 2 20 Calcium 83.0 0.100 mg/L 2.00 84.0 NR 75-125 3 20 QM-07 Copper 0.218 0.0100 mg/L 0.200 0.00160 U 109 75-125 0.6 20 Lead 0.212 0.0100 mg/L 0.200 0.00310 U 106 75-125 0.2 20 Magnesium 12.9 0.100 mg/L 2.00 12.0 44 75-125 4 20 QM-07 Molybdenum 0.220 0.0100 mg/L 0.200 0.00250 U .110 75-125 0.7 20 Nickel 0.214 0.0100 mg/L 0.200 0.00220 U 107 75-125 3 20 Potassium 16.1 0.500 mg/L 10.0 5.45 107 .75-125 1 20 Selenium 0.214 0.0100 mg/L 0.200 0.00620 U 107 75-125 0.7 20 Sodium 24.9 0.500 mg/L 10.0 14.4 105 '75-125 2- 20 Zinc 2.46 0.0100 mg/L 0.200 2,29 85 75-125 2 20 - -- - - • =-- - = - -FINAL-=----- - _' TMIs3eporFrelates-only-to4he3ample-asreceived-by-the laboratory, and may only be reproduced in full. -- - ' Page 6 of-12- --, - I www.encolabs.com i QUALITY -CONTROL DATA j Metals (total recoverable) by EPA 6000/7060 Series Methods - Quality Control Batch 8DO6010 - EPA 3005A - Continued Post Spike (8D06030-PS3) Prepared: 04/06/2018 09:06 Analyzed: 04/09/2018 13:42 Source: CB01058-01 Spike Source %REC RPD _ -- Analvte- _ _ --- - ------Result-_�7Flas=TP91----SJnitS -Level--- -Result----%REC----Limits ---RPD _ Lima _ = Notes Aluminum 2.01 0.100 mg/L 2.00 0.0337 99 80-120 - Arsenic .0.234 0.0100 mg/L 0.200 0.00444 115 80-120 Cadmium 0.0213 0.00100 mg/L 0.0200 -0.000624 107 80-120 Calcium- - 77.1 0.100 mg/L 2.00 -- 84.0 - NR - 80-120 -- QM-08 Copper 0.213 0.0100 mg/L 0.200 0.000240 106 80-120 " Lead 0.218 0.0100 mg/L 0.200 -0.000989 109 80-120 Magnesium 12.8 0.100 mg/L 2.00 12.0 39 80-120 QM-08 Molybdenum 0.222 0.0100 mg/L 0.200 0.00104 111 80-120 Nickel 0.210 0.0100 mg/L 0.200 0.000376 105 80-120 Potassium 15.0 0,500 mg/L 10.0 5.45 96 80-120 - Selenium 0.221 0.0100 mg/L 0.200 -0.00998 111 80-120 Sodium 23.0 0.500 mg/L 10.0 14.4 86 80-120 -- - - Zinc - -2.47 0.0100 mg/L 0.200 2.29 88 80-120 Classical Chemistry Parameters - Quality Control. Batch-8DO3028. - NO PREP - Blank (8D03028-BLKI) Prepared: 04/03/2018 17:24 Analyzed:. 04/03/2018 17:24 Spike Source %REC RPD Analyte Result Flan POL Units Level Result %REC Limits RPD Limit Notes Nitrite as N 0.017 U 0:10 mg/L LCS (SD03028-BSI) Prepared: 04/03/2018 17:40 Analyzed: 04/03/2018 17:40 Spike Source %REC RPD f Anal lCte Result Flag M Units Level Result %REC Limits RPD Limit Notes Nitrite as N 0.94 0.10 mg/L 1.00 94 90-110 Matrix Spike (8D03028-MS1) Prepared: 04/03/2018 17:26 Analyzed: 04/03/2018 17:26 i Source: CB03655-01 Spike Source %REC RPD - Anal YtO Result Flan PM Units Level Result %REC Limits RPD Limit Notes Nitrite as N 1.1 0.10 mg/L 1.00 0.14 96 90-110 Matrix Spike (8D03028-MS2) Prepared: 04/03/2018 17:29 Analyzed: 04/03/2018 17:29 Source: CB03655-02 Spike Source %REC RPD Analyte Result Elad PAX Units Level - Result %REC Limits RPD Limit Notes Nitrite as N 1.3 0.10, mg/L' 1.00 0.36 95 90-110 Matrix Spike Dup (8D03028-MSD1) Prepared: 04/03/2018 17:27 Analyzed: 04/03/2018 17:27 Source: CB03655-01 Spike Source %REC RPD Analyte Result Elan P91 Units Level Result %REC Limits RPD Limit Notes Nitrite as N 1.1 0.10 mg/L 1.00 0.14 93 90-110 3 10 Batch 8D05012 - NO PREP LCS (8D05012-BSI) Prepared: 04/05/2018 14:04 Analyzed: 04/05/2018 14:04 Spike Source %REC RPD l Anal Ytf: Result Elao P4L units Level Result %REC Limits RPD Limit Notes FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full.- - Page 7 of 12 -- . co www.encolabs.cotn QUALITY CONTROL DATA — Classical Chemistry Parameters - Quality Control - - - - - -_ Batch 8005012 - NO PREP - Continued LCS (8D05012-BS1) Continued Prepared: 04/05/2018 14:04 Analyzed: 04/05/2618 14:04 • Spike Source %REC ROD AnalvSe Result Elan. Pal Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 1.2 - _ 0.10 mg/L 1.25 98 90-110 Matrix Spike (8D05012-MS1) Prepared: 04/05/2018 14:08 Analyzed: 04/05/2018 14:08 - Source: CA18896-02 Spike Source - %REC RPD (`) Anal Yte Result Elan . Pal Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 24 2.0 mg/L 10.0 15 94. 90-110 Matrix Spike (8D05012-MS2) Prepared: 04/05/2018 14:14 Analyzed: 04/05/2018 14:14 Source: C000106-01 Spike Source %REC RPD Analvte Result Elao POL Units Level Result o/aREC Limits RPD Limit Notes Nitrate/Nitrite as N 0.56 0.10 mg/L 0.521 0.041 U 107 90-110 j Matrix Spike Dup (8D05012-MSDi) Prepared: 04/05/2018 14:10 Analyzed: 04/05/2018 14:10 Source: CA18896-02 Spike Source %REC RPD -- -- -- -- Anal - - --- --- - -- — Result---Ela9.' P91--- '.lJ�its-----Level ------ g ylt -- %REC-,--Urnit4 RPD Lima ` lYQtai . Nitrate/Nitrite as N 24 2.0 mg/L 10.0 15 95 90-110 0.4 . 10 Batch 8DO6005 = Same Blank (8D06005-BLKl) Prepared: 04/06/2018 11:56-Analyzed: 04/09/2018 10:50 Spike Source %REC RPD - Analliia Result Elan- PaL Units Level Result %REC Limits RPD Limit Notes I Total Kjeldahl Nitrogen 0.26 U 0.48 mg/L , LCS (8D06005-BSI) Prepared: 04/06/2018 11:56 Analyzed: 04/09/2018 10:52 Spike Source %REC RPD II r Anal Result Elan PDL Uni15 Level Result %REC Limits RPD Limit Notes . Total Kjeldahl Nitrogen 12 0.48 mg/L 12.0 101 90-110 Matrix Spike (8D06005-MS1) IPrepared: 04/06/2018 11:56 Analyzed: 04/09/2018 10:55 Source: C604409-01 - Anai4te Result Elan ' M !Unit;: Spike Source %REC LevelResult %REC . 'Limits RPD RPD' Limit Notes F-1 Total Kjeldahl Nitrogen 3:8 0.48 mg/L 4.80 1.0 59 90-1110 QM-07. Matrix Spike (8D06005-MS2) Prepared: 04/06/2018 11:56 Analyzed:'04/09/2018 11:04 Source: CB04413-01 +- Spike Source %REC RPD I Anal Result Elm Pal Units, Level gesult %REC Limits RPD Limit • Notes Total Kjeldahl Nitrogen Matrix Spike Dup (8D06005-MSDI) 4.6 0.48 mg/L 4.80 1.1 73 90-110 QM-07 Prepared: 04/06/2018 11:56 Analyzed: 04/09/2018.10:57 Source: CB04409-01 Spike Source %REC RPD _ Analyte Result F&a Pal Units Level Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 4.9 0.48 mg/L 4.80 1.0 80 90-110 23 10 QM-07, — QM-11 Batch 8DO6006 - Same - FINAL This report relates only to the sample as received by -the laboratory, and may only be reproduced in'fulL -- - Page 8 of 12 www.encolabs:com - QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control _ Batch 8DO6006 - Same - Continued Blank (11D06006-BLKl) Prepared: 04/06/2018 11:56 Analyzed: 04/09/2018 12:33 Spike Source %REC RPD -- -- - Anil vte -_ =- --- - - -liesult - rF1ag-..— P91 —Units --Level- --Result.---%REC--J�i !� -_ - RP.D: - -Limit-- - - - Notes - Phosphorus 0.035 3, 0.10 mg/L - LCS (8D06006-BS1) Prepared: 04/06/2018 11:56 Analyzed: 04/09/2018 12:35 Spike Source %REC RPD ADalyte. -• - -• .. ---- Besul ._Flan PM__ ...Units- ".. -Level, Result ,-_ %REC _ _. _limits RPD. Limit Notes Phosphorus 1.6 0.10 mg/L 1.60 100 80-126 Matrix Spike (8D06006-MS1) Prepared: 04/06/2018 11:56 Analyzed: 04/09/2018 12:37 Source: CB04409-01 Spike Source %REC RPD Anal Result. FI 3 POL Units Level Result %REC Limits RPD Limit Notes Phosphorus 8.3 D 0.50 mg/L 0.640 7.8 86 80-120 Matrix Spike Dup (8D06006-MSDI) , Prepared: 04/06/2018 11:56 Analyzed: 04/09/2018 12:39 Source: C1304409-01. . Spike - Source %REC-- -- RPD --- 'Analvte - - - '. Result slag-- P91 - Unite - -- Level- Result %REC- limits-- -- RPD limit - Notes Phosphorus 8.5 D 0.50 mg/L 0.640 7.8 113 80-120 2 25 Batch 8DO6010 - EPA 3005A Blank (8D06010-BLKI) Prepared: 04/06/2018 09:06 Analyzed: 04/09/2018 13:17 Spike Source %REC RPD Anal vte Result Flag P9b Units Level Result %REC Limits RPD limit Notes Sodium Adsorption Ratio 0.00 U [blank] Blank (8D06010-BLK2) Prepared: 04/06/2018 09:06 Analyzed: 04/09/2018 16:16 Spike Source %REC RPD Anal Yte Re.4uit Flan POL Units Level Result %REC Limits RPD limit Notes Sodium Adsorption Ratio 0.00 U [blank] Batch 8DI0003 - NO PREP Blank (8D10003-131.11(1) Prepared & Analyzed: 04/10/2018 11:50 i Spike Source %REC RPD Anal vte Result Flan M Units Level Result %REC Limits RPD Limit Notes - Total Solids 0.0050 U 0.0050 % by Volume • LCS (SD100037BSI) 'Prepared &Analyzed: 04/10/2018 11:50 Spike Source %REC RPD Analltte Result Flag P.4L Units Level Result %REC Limits RPD Limit Notes Total Solids 1100 50 mg/L 1100 97 80-120 Duplicate (8D10003-DUPI) Prepared & Analyzed: 04/10/2018 11:50 Source: C1103063-01 Spike Source %REC RPD Anal Resul . Flag P9l_ Units Level Result %REC Limits RPD Limit Notes Total Solids 0.33 0.0050 % by Volume 0.33 0.9 20 Batch 8D11009 - NO PREP •"-=-=-_� - -- - FINAL ' -- - This report relates only to the sample as received by the laboratory, and may only be reproduced in -full. Page 9 of 12 CS Nk www.encolabs.com QUALITY CONTROLDATA-- - -- = - Classical Chemistry Parameters - Quality Control LBatch 8D11009 - NO PREP - Continued ; Blank (811311009-BLKi) Prepared: 04/11/2018 09:50 Analyzed: 04/11/2018 09:50 Spike Source- %REC RP.D Anil vte Result Flaa P91 Wift Level Result %REC limits -RPD bjpi Notes Ammonia as N 0.045 U 0.10 mg/L LCS (81311009-BSi) Prepared: 04/11/2018 09:52 Analyzed: 04/11/2018 09:52 I — Spike Source %REC RPD nalvie Result Elm DQL Units Level %REC Limits RPD Limit Notes Ammonia as N .. 0.98 0.10 mg/L 1.00 98 90-110 Matrix Spike (8D11009-MS3) Prepared: 04/11/2018 09:55 Analyzed: 04/11/2018 09:55 Source: CA18896-02' Spike Source %REC RPD Analvte Result Flao M Units Level Result %REC Limits RPD Limit Notes Ammonia as N 0.35 0.10 mg/L 0.389 0.045 U 91 90-110 CI Matrix Spike (8D31009-MS2) Prepared: 04/11/2018 10:00 Analyzed: 04/11/2018 10:00 Source: CA18904-02 — Spike Source %REC RPD - _. _. Anal Result ;- Flao ' P-QL -- Units - - Level Result %REC )Limits RPD Limit Notes I I Ammonia as N 0.33 0.10 mg/L 0.389 6.045 U 85 90-110 QM-07 Matrix Spike Dup,(8Dll009-MSD1) Prepared: 04/11/2018 09:57 Analyzed: 04/11/2018 09:57 Source: CA18896-02 Spike Source %REC RPD Analvte Result Flan. M llniti: Level Result. %REC Limits RPD Limit Notes . Ammonia as N 0.34 0.30 mg/L 0:369 0.045 U 87 90-110 5 10 QM 07 � • I i • I I I_ ji FINAL = = - --" -- - 'This report relates only to' the sample as received by'the laboratory, and may only be reproduced in full. -- - - - -- - - _ . _- Page 10 of 12-- wwW.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. ! I The reported value is between the laboratory method detection limit (MDQ and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. = U _ The analyte was analyzed for but not detected to the level -shown, adjusted for actual sample preparation I data and moisture content, where'applicable. -". E - The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. I MRL . Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit_(PQQ and is ' w based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater ' confidence) to make a "tentati_veJdentification". ------- -----P--- —= --Greater than 25%-concentration difference was observed -between, the primary -and secondary GC column.- - - - The lower concentration is -reported. QB-01 ,_ The method blank,had a positive resultforthe,analyte;-however, the concentration in the - method blank is less than 10% of the sample result. There is minimal impact to the data. QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. ! QM-08 Post -digestion spike did not meet method requirements due to confirmed matrix effects (dilution test). QM-11 Precision between duplicate matrix spikes of the same sample was outside acceptance limits. = FINAL This report relates only to'the sample as receivedby the laboratory, and may only be reproduced In full. - -' - - Page 11 of 12 -- -- ENVIRONMENTAL CONSERVATION LABORATORIES CHAIN -OF -CUSTODY RECORD www.encolabs.com 1075 Central Pori Or. 4810 Execulive ParK Colin, Suite Ill 102-A Wooft"s Musbial Cl. Cary, NC 275l. 1 (407) 826-5314 FAN (41M 850-51945 (934)296-3007 rax(90-1)295-6210 J919).467-X90 Fax (919)467-3515 Cjlieni Name Proiecl Number Requested Analyses Requested Turnaround IN —1) 17 niesAo—rthL'1P-_'I,_'C3�N')(fQ,3 Times I Note. Flush requests subject to Address Project Nam - C)DW M acceptance by the facility Cityis-rizip PO 01 9111ing Wo :T! 2.0 Standard ;:I-airkl nion, NC 27625 380033C-507 Tel Fax. Reporting Contact F-�. - Q Expedited fG9P) 494- 3000 Sco-It Creect, L) Z — Sampler(s) Name, Affiliation (Print). Biding Contact - M 6 -Due /r"'e AcCGL-ItS POYBNe nVOZI _ Sam Sign re site Locabon Time Zone, Lab Workorder Z CB656 Preservation (See Codes) (Combi.ra as necessary) 03 Collection maciX Total # of i_Ier_n# Sample 10 (Field Ido entificwn) fection DaiTuna Comp tGrab (st___ codaz Containers sampie comments sl N of rnnisinnn, sarrip Kit Prepared By atelTme Ra rs By Dale/Time Received By, Dia V-31 Comments'special Reporting Requirements JirlctLks By Dalefrime naileive d By Dalefriele Relinquished By 03tellime Received By DalaMme CorciereS & Tenpeon );SCeiPl ConditionReceipt MatrIK: GW-Grounciviater SO -Soil DW-Drinking Water SE-Sedvmsnt SVI-Sunica Water A -Au U-umy Wela" In rorwullls7 _1 "rn— ' ! - 0Note: All samples subriulted to EUGO Labs are in accofdzmce wfli the lemrs and ccizefrkons Wed on the Y&ierse of ?his form, unless pric»r written agreements _2xis1 '.-Sample Preservation Verification ENCO Cary VVo_rk_Ord6r CB036561., Project., Monthly - Week'One SBM —-Client: -..--.-Nvozymes-Nor.th-America-(NO008) Project #: [none] ,o Logged In: _03-Apr7181 0..'67 Logged By: John q King Preservation Check Performed BY. DaWffime: gc: CB03666-01----- Copt- Type4" 4 A 250mLP4-H2SO4-7-_ <2-.- Y I NA- -N I -NA B. 250mLP+HNO3 <2 NA Y In/ NA Reap ID Reagent Name' ient Name ID 3 4 pH Strip 113: C�kELMNtPrintlwko�-PreservabonCheck.rpt- 10fi ra nes, Lobo 'to �BVBII�� ENCO 0. Accurate® Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Friday, May 11, 2018 Novozymes North America (N0008) Attn: Scott Creech 77 Perry Chapel Church Road Franklinton, NC 27525 RE: Laboratory Results for - Project Number: [none], Project Name/Desc: Monthly - SBM ENCO Workorder(s): CB05460 !i Dear Scott Creech, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Tuesday, May 1, 2018. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, CLLC----�O Chuck Smith Project Manager Enclosure(s) FINAL _ This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 1 of 8 Q 9 �Ee) www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE � :j Client ID: SBM—Lab-ID:—CB05460-01- Sampled: 05/01/18 08:00 Received: 05/01/18 10:50 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Timels) SM 254OD-1997 NO PREP 05/08/18 05/08/18 14:20 05/08/18 14:20 SM 521OB-2001 NO PREP 05/03/18 08:00 05/02/18 17:31 05/02/18 17:31 SM 5220D-1997 Same 05/29/18 05/07/18 15:06 05/08/18 10:51 FINAL - This-reportrelates only to the-sampl&as received`by the laboratory, and may only be reproduced in full. Page 2 of 8 wmermencolabs.com SAMPLE DETECTION SUMMARY, —_ Client ID:_.-.SBM _ - . = - - Lab ID:- .C805460-01 Analvte Results Eiia MDL EQL Units Method Notes Biochemical Oxygen Demand. 12000 2.0 2.0 mg/L SM 5210B-2001 B-07 Chemical Oxygen Demand 29.000 800 800 mg/L SM 5220D-1997 I Total Suspended Solids 27000 2500 2560 mg/L SM 254OD-1997 i . I _ FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 8 www.encolabs.com ANALYTICAL RESULTS Description: SBM _ _ _ Lab Sample ID:'CB05460-01 Received: 05/01/18 10:50 " Matrix: Sludge . , Sampled:05/01/18 08:00 Work Order: CB05460 Project: Monthly - SBM Sampled By: Brooks Williams Classical Chemistry Parameters ^ - ENCO Cary certfied analyte [NC 5911 Analyte rCAS Numberl Resuft, -Flag Units PLF MDL POLL Batch Method Analwed vied Notes Biochemical' Oxygen DemandA '12600 mg/L 1 2.0 2.0 8E02050 SM 5230B-2001 05/02/18 17:31 30C B-07 Chemical Oxygen DemandA 29000 mg/L 80 800 800 . BE07034 SM 5220D-1997 - 05/08/18 10:51 30C Total Suspended SolidsA 27000 mg/L 1000 2500 2500 8E08006 SM 2540D=1997 05/08/18 14:20 OMR I I I i -" FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. page 4 of QUALITY CONTROLMATA ' --- Classical-Che-mistry-Parameters --Quality Control --- Batch 8E02050 - NO PREP Blank (SE02050-BLKI) Prepared & Analyzed: 05/02/2018 17:31 Analyte _ Result-- - Elan-_ --- M _-- ,- Units Level -- - --Result__,_ -%REC Limits- RPD _ -Limit -Notes - -- - Biochemical Oxygen Demand 2.0 U 2.0 mg/L —' LCS (SE02050-BSI) Prepared & Analyzed: 05/02/2018 17:31 j Spike Source %REC RPD Analltte.. _ Result , Elm, _ PGL_ MdW Level - Result-. %REC ..Limits RPD_ Limit Notes Biochemical Oxygen Demand 150 2.0 mg/L 198 77 85-115 B-07 Duplicate (SE02050-DUPI) Prepared & Analyzed: 05/02/2018 17:3.1 Source: CB05460-01 Spike Source %REC RPD Analyte Result Elan POL Units Level Result %REC Limits RPD limit Notes 1 • ; Biochemical Oxygen Demand 11000 2.0 - mg/L 12000 7 30 B-07 Batch 8E07034 - Same Blank (SE07034-BLK1) Prepared: 05/07/2018 15:06 Analyzed: 05/08/2018 10:51 ' Spike Source %REC RPD Analyte Result Elan PGL Units Level Result %REC Limits RPD Limit Notes .Chemical Oxygen Demand 10 U 10 mg/L 1 i LCS (8E07034-BSI) Prepared: 05/07/2018 15:06 Analyzed: 05/08/2018 10:51 Spike Source 0/aREC RPD Analyte Result Elan PQL Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 500 10 mg/L 500 100 90-110 Matrix Spike (SE07034-MS3) Prepared: 05/07/2018 15:06 Analyzed: 05/08/2018 10:51 �- Source: 601172-01 i - Spike Source %REC RPD Anal a Besult . Elan POI. Units Level Result %REC Limits RPD Lima Notes Chemical Oxygen Demand 800 10 mg/L 526 270 100 90-110 Matrix Spike Dup (SE07034-MSD1) Prepared: 05/07/2018 15:06 Analyzed: 05/08/2018 10:51 Source: CB01172-01 Spike Source %REC RPD ADal1lffi Result `E1i10. I P91 Units Level Result %REC Limits RPD Limit Notes 'Chemical Oxygen Demand 800 10 mg/L 526 270 99 90-310 0.6 10 Batch SEOS006 - NO PREP r Blank (8E08006-61.1(3) Prepared & Analyzed: 05/08/2018 14:20 Spike Source %REC RPD Anal vte Resul Elan POL Units Level Result %REC Limits RPD Limit Notes Total Suspended Solids 2.5 U 2.5 mg/L LCS (SE08006-13SI) Prepared & Analyzed: 05/08/2018 14:20 Spike Source %REC RPD Anal Yte Result Elan PQL Units Level Result %REC Limits RPD Limit Notes TotaLSuspended Solids 98 2.5. mg/L 100 98 80-120 FINAL This report relates only to the'sample as received by the laboratory, and may only -be reproduced in full. Page 5 of 8 . www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters---Quality-Control — 1 Batch BEOB006 - NO PREP - continued Duplicate (8E08006-131.1133) Prepared & Analyzed: 05/08/2018 14:20 Source:CB03155-01 Spike Source %REC RPD Analvte _Result_Fla4 —P91 Units Level Result %REC Limits RPD Limit Notes Total Suspended Solids 200 50 mg/L 190 3 20 Duplicate (8E08006-DUP2) _ _ _ Prepared & Analyzed: 05/08/2018 14:20 Source:CB04582-01 Spike Source %REC RPD Anal Yte .__ _ ResultF1aaP91�__...Mnits— Level Result '/oREC Limits RPD Limit (Votes Total Suspended Solids 310 100 mg/L 330 8 20 FINAL - TThisreportrelates only to the sample as received by the laboratory, and may only be reproduced in full. Page 6 of 8 �ee vVww.encolabs..com, FLAGS/NOTES AND DEFINITIONS • . ! B The analyte was detected in the associated method blank. D The sample was -analyzed at dilution. - - - I The reported value• is between the laboratory method detection limit (MDL);and the, laboratory method 'reporting limit (MRL ,_ adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample'preparation data 'and moisture content, where applicable. r - E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This `value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and -is based on the low. point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples,, moisture content. PQL PQL: Practical Quentitation Limit. N The analysis indicates the presence of, an analyte for which there is presumptive, evidence.(85%0 or. greater confidence) to make a "tentative, identification". --- -- . - P- -Greater, than 25% concentration difference was observed between'the primary and -secondary. GC, column- .---- . - - - _ T_ he •lower concentration is reported. B-07 1 LCS exceeded control limits for this test. The test can not be repeated due to method, constraints. The result "should be considered an estimated value. _ _ _�� _ _ _J -� T -" , —_-_ - —'_- --� Baru avaaosaa.av�•ar.vvawa..aa�a••auva� re�u.vaar-a�vaiary vaarau� v vvva.vv.a aawvaau vv W tvae!�f..V�Y V.7avV�a■ awe ® 10775 Central Port Dr. .. 4810 Executive Park Court Suftaa 11 , l02-A Woodwinds Jndustrial Ct... .. . Orlando, FL 32824 Jacksonville, FL 32216.6069 Cary, NC 27511 L-1. (407)826-5314 Fax (407) 850-6945 - - (904)295-3007 .Fax(904)29o-6210 (919)467-3oso Fax(s19)467-3s15. - Pa e. - of . - 9. - Client Name _ Novinzymes North America Project Number [none] Requested An*ses Requested Turnaround .(N0008-) Times Address ,., , 7 -77 Perry Chapel Ghur+ch-Road Pro Nam esm i�1®il y —.8BA4 Note :Rush re nests subject to' . acceptance by the facility .- Ci !ST 4 0r arikiinton,' NC 27526 PO # / Biltin info. 380� 05t97 . O �. _Standard".: Tel (919) 494-2004-. Paz . Reporting contact . ': Sc6ft Crews .. i CM - Expedited- S_ ampter(s) N o, At(trillion (Print) pp lidv�5 Riliin Contact . nth -Payable � �' C� ' -Due — J /� OiOQS li.Jr� /UfNdL /�� ® . Sample Signa ; . Site Location / rlme Zone ' lab Wo� kQQofd{{eir ,.'. IM Preservation (See Codes) (Combine as necessary) Collection . Matrix Total # bf Item # Sample ID (Feld Identification) Collection Date: Time Comp/ Grab ' (sea codes) Containers Sarilple Comments ' " < - Total # of Containers Sample Kit Prepared By. Dat�ine. Rel' eci 8 Datefrime 18 At..6 Received By DateMme ' 012t Comments/Special Reporting Requirements efin Baterl-ime• Rem d By DateMime . _ %sbd : qui Refsnshed By aieri D ceived"B Daterl'ime Cooler #'a &Temps on Receipt L. Condition U n.ReceipI . - acceptable- Unacceptable Matrix : GW-Groundwater SO -Soil DW-Drinking Water" SE -Sediment SW -Surface Water WW-Wastewater A -Air O-Other (detail in comments) Preservation:14ce H-HCl N-HNO3 S-H2SO4 NO-NaOH O-Other (detai(in comments) Nolec All samples submitted to ENCO Labs are in accordance with the terms and Conditions iistep on the reverse of this form, unless prior written agreements exist Sample Preservation Verification ENCO Cary. Work Order: CB05460 Project. Monthly - SBM Client: Novo±ymes North America- (N0008) Project #: [none] Logged In: 01-May-18 11:47 Logged By: John C King Preservation Check Performed By: Dat6fTime: &2u() CB05460-01 0 'D M 'w" 41- ly qNA A 250mLP+H2SO4 <2 Y NA Reagent Name ID 21 pH Strip ID: Z�G-�zo C:kELMNTAPrintNW.ko-PreservationCheck.rpt Reaoent Name ID Reacient Name ID 31 1 1 5 41 1 6 Page 1 - - oorativ � ►cr f _ Mw 102=A Woodwinds.Industrial Court , Cary NC; 27511 Phone: 919.467.3090 FAX: 919.467.3515 Tuesday, May 15, 2018 - - - -- - Novozymes North America (N0008) Attn: Scott Creech - - 77 Perry Chapel'Church Road Franklinton, NC-27525 RE:. Laboratory Results for Project Number: [none], Project Name/Desc: Monthly - Week One - SBM - - - ENCO- Workorder(s): CB05462 - - - - Dear Scott Creech. - Enclosed is a copy of your laboratory report for test samples received by our laboratory.on Tuesday, May,1, 2018.- Unless otherwise -noted in an attached project narrative; all samples were received -in acceptable condition and processed in accordance with .the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The. analytical results contained in this report are in compliance with NELAC standards,, except as noted in, the project narrative if applicable.• This report,shall not be reproduced except in full, without the written approval of the Laboratory... ' This report.contains only those analyses •performed by Environmental Conservation Laboratories.. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported underseparate cover. If you have any questions or require further'information, please do not hesitate to contact.me. Sincerely, PI ` Chuck Smith Project Manager Enclosure(s) FINAL "This report relates only to the sample as received by the laboratory, -and may only -be reproduced in'full. Page 1 of 12 ' Q9 NC0 www.encwlabs.com - SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: SBM _ - -- -T T_Cab-ID: =CB05462-01 Sampled: 05/01/18 08:00 'Received: 05/01/18 30:50 parameter Preparation - Hold Date/Time(si Prep Date/Time(sl ___ _._- _ Analysis Date/Time(s1 _ CSU Method NO PREP 01/24/21 -05/09/18 08:56 05/11/18 13:26 EPA 350.1 NO PREP 05/29/18 05/11/18 10:32 05/11/18 10:32 EPA 351.2 _ ` Same 05/29/18 -_ __ __- _ - 05/04/18 12:30 05/08/18 10:58' _-- EPA 353.2 . NO PREP 05/03/18 08:00 . .05/01/18 18:15 .05/01/18 18:15 EPA 353:2 - - -NO PREP - —` ---—01/24/21 --- —� :. ' - - : `05/15/18 .. _ 10:42 - 05/15/18 -10:56 EPA 365:4 _ Same 05/29/18 05/04/18 12:30 05/08/18 12:35 EPA 6010D EPA 3005A 10/28/18 '.- 05/09/18 08:56 05/11/18 11:40 EPA 7470A . EPA 7470A 05/29/1-8 05/07/18 11:38 05/68/18 13:59 SM 2540E-1997 NO PREP 05/08/18 05/08/18' 11:28 05/08/18 11:28 - F1, __ _ FINAL _ - - - _ _ _-This report _relates onlyto the sample;as receiVed by the laboratory, and may only be reproduced in full. ' ' t - _ Page 2 of 12 . www.encolabs.com SAMPLE DETECTION•SUMMARY- ------ -Client ID: SBM 7_ Lab ID: C805462-01 -- - -_ - - - - _ Analvte :.- Results fin HU M Method Notes Aluminum -Total 177 0.420 1.00 mg/L EPA 60,10D . Ammonia as N 140 D 4.5 10 mg/L EPA 350.1 Calcium -Total 2960 0.390 1.00 mg/L . ' EPA 6010D Copper - Total` - - ` - " `-' - T= { -0-.429 - - 0.0160 0.100 mg/L EPA 6010D "- - Magnesium - Total 62.3 B 0.290 1.00 mg/L' EPA 60101), ----Molybdenum-=Total—� -- _ _____,—,0:0297 Y'J- "-0:0250- T,-0,100--"-- 'mg/L"" EPA 6010D =----- Nickel -Total 0.0430 1 0.0220 0.100 mg/L EPA 6010D " - Nitrate• as-N 46 0.025 o.16 mg/L J EPA 353.2 Nitrite as N 0.093 1 0.017 - 0.10 mg/L EPA 353.2 Phosphorus -. - - 750 - D -10 40 mg/L EPA 365.4 Potassium'r,Total _ 756 1.50 5.00 - mg/L 'EPA 6010D Sodium = Total 158 4.00 - 5.00 - mg/L EPA 6010D Sodium Adsorption Ratio 0.785 [blank] CSu Method Total Kjeldahl Nitrogen 2400 D 52 96 mg/L EPA 351.2 Total Solids 4.4 0.25 6.25 % by Volume SM 25406-1997' Zinc,- Total 1.50 0.0440 0.100 mg/L EPA 6010D } FINAL This report relates only to the sample as received by the -laboratory, and may only be reproduced in full. - Page 3 of 12 www.encolabs.com ANALYTICAL RESULTS Description: SBM Lab Sample ID: CB05462-01 Received: 05/01/18 10:50 Matrix: Sludge Sampled: 05/01/18 08:00 Work Order: CB05462 Project: Monthly - Week One - SBM Sampled By: Brooks Williams Metals by EPA 6000/7000 Series Methods , I ^ - ENCO Cary certified analyte [NC 591] - Analyte FCAS Numberl Results Flaa Units -DF MDL- - - Q Batch MethodAnalyzed Notes Mercury [7439-97-6]A 0.000750 U mg/L 5 0.000750 0.00100 8EO7027 EPA 7470A 05/08/18 13:59 NMN Metals (total 'recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591J - Analvte [CAS Numbed Results fag •Units DF MDL fps Batch Method Analyzed ¢y Notes" T Aluminum [7429-90-5]^ . 177 mg/L 10 0.420 1.00 8E09013 EPA 6010D� 05/11/18 11:40 JDH i Arsenic[7440-38-2]^. 0.0680 U mg/L 10 0.0680 0.100 BE09013 EPA 6010D. 05/11/18 11:40 JDH Cadmium [7440-43-9]^ 0.00360 U mg/L 10 0.00360 0.0100 8EO9013 EPA 6010D 05/11/18 11:40. JDH Calcium•[7440-70-2]^ 2960 mg/L 10 0.390 1.00 8EO9013 EPA 6010D 05/11/18 11:40 JDH Copper[7440-50-B]^ 0.429 mg/L 10 0.0160 0.100 BE09013 EPA 6010D 05/11/18 11:40 JDH Lead [7439-92-1]^ 0.0310 U mg/L 10 0.0310 0.100 SE09013 EPA 6010D 05/11/18 11:40 JDH Magnesium [7439-95-4]^ 62.3 B mg/L 10 0.290 1.00 SE09013 EPA 6010D 05/11/18 11:40 JDH Molybdenum [7439-98-7]^ 0.0297 J mg/L 10 0.0250 0.100 8E09013 EPA 6010D 05/11/18 11:40 JDH J Nickel[7440-02-0]^ 0.0430 J mg/L.•. 10 0.0220 0.100 8E09013 EPA 6010D 05/11/18 11:40 JDH Potassium [7440-09-7]^ 756 mg/L 10 1.50 5.00 8E09013 EPA 6010D ,' 05/11/18 11:40 JDH �- Selenium [7782-49-2]^ 0.0620 lJ mg/L 10 0.0620 0.100 BE09013 EPA'6010D 05/11/18 11:40 JDH Sodium [7440-23-5]^ 158 mg/L 10 4.00 5.00 8EO9013 EPA 6010D 05/11/18 11:40 JDH Zinc[7440-66-6]^ 1.50 mg/L 10 6.0440 0.100 8EO9013 EPA 6010D 05/11/18 11:40 JDH _l Classical Chemistry Parameters 1_.l ^ - ENCO Cary -r fred analyte [NC 591J Analyte rCAS Numberl Results Flag Units DF MDL P L Batch Method A nal vzed By Not s �i Ammonia as N [7664-41-7]^ 140 D mg/L 100 4.5 10 BE11007 EPA 350.1 05/11/18 10:32 JL1 I Nitrate as N [14797-55-8]^ 46 mg/L 1 0.025 0.10 BE15009 EPA 353.2 05/15/18 10:56 JU Nitrite as N [14797-65-0]^ Phosphorus[7723-14-0]^ 0.093 750 J D mg/L mg/L 1 400 0.017 10 0.10 40 BE01025 8EO4014 EPA 353.2 EPA 365.4 05/01/18 18:15 05/08/18 12:35 JL1 JI.J Sodium Adsorption Ratio 0.785 [blank] 1 BE09013 CSU Method 05/11/18 13:26 JDH -- Total,Kjeldahl Nitrogen^ 2400 D mg/L 200 52 96 8EO4013 EPA 351.2 05/08/18 10:58 JLJ Total Solids^ 4.4 % by Volume 50 0.25 0.25 8EO8009 SM 254OB-1997 05/08/18 11:28 OMR r FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 12 QUALM CONTROL'DATA- - ' -:- Metals by-EPA_6000/-7000-Series Methods -Quality Control-== -- - _ - - Batch SE07027 - EPA 245.1 Blank (8E07027-BLK3) Prepared: 05/07/2018 11:38 Analyzed: 05/08/2018 12:56 Spike Source %REC h� RPD _-:- Anar_ _ --Basalt__ .Fle4 _P91_ Units _ _._.Level.- -- -gg�y� _--%REC Jlp1L�£-- - RPD z -. LIBILL -Notes : -- Mercury 0.000150 U 0.000200 mg/L = _ - LCS (8E07027-BSI) - - - Prepared: 05/07/2018 11:38 Analyzed:.05/08/2018 12:58 Spike Source, %REC RPD ; Anal Result Ela4 P91 Units Level Result' "/oREC )his RPD UMit Notes Mercury 0.00562 0.000200 mg/L 0.00500, 112 80-120 Matrix Spike (SE07027-MS1) Prepared: 05/07/2018 11:38 Analyzed: 05/08/2018 13:03 Source: CB04461-01 Spike Source%REC RPD -_ 'Anal vte ftu t Flaa POL Units Level a ult, %REC Limits RPD Limit Notes Mercury 0.00561 0.000200 mg/L 0.00500 0.000150 U 112 75-125 Matrix Spike Dup (8E07027-MSD1) Prepared: 05/07/2018 11:38 Analyzed: 05/08/2018 13:05 Source: CB04461-01 Spike Source %REC RPD Anabde .. Result Elm P91 Units Level Result 6/oREC Limits RPD Limit Notes Mercury 0.00537 0.000200 mg/L 0.00500 0.000150 U 107 75-125 4 25 Post Spike (8E07027-PSI) Prepared: 05/07/2018 11:38 Analyzed: 05/08/2018 13:08 Source_ : CB04461-01 Spike Source %REC RPD Anake Result Elan, P4L Units Level Result %REC Limits . RPD imit Notes 'Mercury 6.19 0.200 ug/L 5.00-0.0490 124 75-125 Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch SE09013 - EPA 3005A Blank (BE09013-13LKi) 'Prepared: 05/09/2018 08:56 Analyzed: 05/11/2018 10:24 Spike Source %REC RPD Anal Yte Result Elaa' P91 Units Level Result.' %REC Limits RPD Limit Notes 'Aluminum 0.0420 U . 0.100 mg/L Arsenic 0.00680 U 0.0100 mg/L Cadmium 0.000360 U 0.00100 mg/L Calcium 0.0390 U 0.100 mg/L Copper 0.00160, U 0.0100 mg/L Lead 0.00310 U 0.0100 mg/L Magnesium 0.0363 .3 0.160 mg/L Molybdenum 0.00250 U 0.0100 mg/L Nickel 0.00220 U 0.0100 mg/L' Potassium' 0.150 U 0.500 mg/L _ .Selenium. 0.00620 U 0.0100 mg/L Sodium 0.400 U 0.500 mg/L Zinc 0.00440 U 0.0100 mg/L LCS (13E09013-BSI) Prepared: 05/09%2018 08:56 Analyzed: 05/11/2018 10:36 , Spike Source %REC ` Anal lf Result Elm M !!f Level Result o/oREC Limits RPD Aluminum 1.99 0.100 mg/L 2.00 . 100 80-120 Arsenic 0.203 0.0100 mg/L 0.200 101 80-120 FINAL This report relates only to the sample as'received by the laboratory, and may only be -reproduced in full. RPD Limit Notes - - Page of 12 www.encolabs.com - QUALITY CONTROL DATA _ - Metals (total recoverable) -by -EPA 6000/7000 Series Methods - Quality Control . Batch BE09013 - EPA 3005A - COntinued LCS (BE09013-BSI) Continued Prepared: 05/09/2018 08:56 Analyzed: 05/11/2018 10:36 Spike Source %REC RPD - Analyte - --Result_ - - Flaa__ __ P_46___ _ -Units. Level --- gesult _ '/oREC Limits RPD _ LiMit. Cadmium 0.0200 0.00100 mg/L 0.0200 100 80-120 Calcium _ 2.08 _ 6.100 _ mg/L 2.00 104 80-120 Copper 0.199 -- - - -- 0.0100 mg/L 0.200 99 80-120 Lead 0.201 0.0100 mg/L 0.200 101 80-120 Magnesium , 2.00 B 0.100 mg/L 2.00 . 100 80-120 Molybdenum 0.196 0.0100 mg& 0.200 98 80-120 - - Nickel 0.200 0.0100 mg/L 0.200 100 80-120 Potassium 9.95 0.500 mg/L 10,0 99 80-120 Selenium 0.193 0.0100 mg/L 0.200 97 '80-120 Sodium_ 10.2 0.500 mg/L 10.0 102 80-120 Zinc 0.208 0.0100 mg/L 0.200 104 80-120 Matrix Spike (8E09013-MS1) Prepared: 05/09/2018 08:56 Analyzed: 05/11/2018 10:39 Source: CB04461-01 Spike ' Source %REC RPD AnalYte -- - Result flag- - Pal. units- Level ----Result o/oREC Limits RPD Unlit - Notes Aluminum 2.61 0.100 mg/L 2.00 0.294 116 75-125 Arsenic 0.211• 0.0100 mg/L 0,200 0.00680 U 105• 75-125 Cadmium 0.0205 0.00100 mg/L 0.0260 0.000360 U 103 75-125 Calcium 2.85 0.100 mg/L 2.00 0.773 104 75-125 Copper 0.201 0.0100 . mg/L 0.200 0.00187 100 75-125 Lead 0.206 0.0100 mg/L 0.200 0.00310 U 103 75-125, Magnesium 3.54, B 0.100 mg/L 2.00 1.57 98 75-125 Molybdenum 0.202 0.0100 mg/L 0.200 0.00250 U 101 75-125 Nickel 0.205 0.0100 mg/L 0.200 0.00220 U 103 75-125 Potassium _ 11.8 - 0.500 mg/L 10.0 1.75 101 75-125 Selenium 0.197 0.0100 mg/L 0.200 0.00620 Ur 99 75-125 Sodium 11.9 0.500 mg/L 10.0 1.44 104 75-125 Zinc 0.213 0.0100 mg/L 0.200 0.0105 101 75-125 Matrix Spike Dup (SE09013-MS131) Prepared: 05/09/2018 08:56 Analyzed: 05/11/2018 10:42 Source:CB04461-01 Spike Source AnalYte Resul I flag: POL Units Level Result %REC Aluminum 2.47 0.100 . mg/L 2.00 0.294 109 Arsenic 0.208 0.0100 mg/L 0.200 0.00680 U 104 Cadmium 0.0202 0.00100 mg/L 0.0200 0.000360 U 101 Calcium 2.73 0.100 mg/L 2.00 0.773 98 Copper 0.201 0.0100 mg/L 0.200 0.00187 100 Lead 0.206 0.0100 mg/L 0.200 0.00310 U " 103 Magnesium 3.41 B 0.100 mg/L 2.00 1.57 92. Molybdenum 0.201 0.0100 mg/L 0.200 0.00250 U 101 Nickel 0.206 0.0106 mg/L 0.200 0.00220 U' .103 Potassium 11.3 0.500 mg/L 10.0- .1.75 96 Selenium 0.206 0:0100 mg/L 0.200 0.00620 U 103 Sodium 11.4 0.500 mg/L 10.0 1.44 99 Zinc 0.212 0.0100 mg/L 0.200 0.0105 101 %REC RPD Limits RPD LiM t Notes - 75-125 5 20 75-125 2 20 75-125' 1 20 ; 75-125 4 20 i! 75-125 0.05 20 ; 75-125 0.2 ,,20 75-125 4 20 75-125 0.3 20 75-125 0.1 " . 20 75-125 4 20 -75-125 4 20 75-125 4 20 75-125 0.4 20 _ - FINAL - ------This report relates only to the sample as -received by the laboratory, and may only be reproduced in full.- Page 6 of 12 - jwww.encolabs.com- - " QUALITY CONTROL -DATA -- Metals -(total -recoverable) by-EPA-6000/7000_Series Methods - Quality Control- - Batch BE09013 - EPA 3005A - Continued - . ' Post Spike (SE09013-PSI) Prepared: 05/09/2018 08:56 Analyzed: 05/11/2018 10:44 -.,Source: CB04461-01---- Spike Source %REC RPD - - -Analyze-- _ � = - -' - - -=---Riasul - "= -- EM-= - Unit4_r: /DREG_ ,Limits .- cRP-RPD . --Limit- Level._= _ gg zyll �° _ _ --Notes' - - Aluminum 2.32 0.100 mg/L" 2.00 0.294, 101 80120 Arsenio._ .._.._.�.__._.:.- w , a .._=::.0.207__= d: ,_c,:.i, �0.0100:: mg/L _. .;. 0.200-- 0,000650:_ 303_'_'80120- - - - -----Cadmium - - -- - - ---- - - =- - 0.0203- -- ---' .--0.00100-- mg/L - 0:0200 - -----2.16E-5 - -- -101-80-120 -= -•---- -- _.. _ . _ ___ _ �_- .. __ Calcium 2.90 0.100 mg/L 2.00 0.773 106 80-120 Copper 0.203 0.0100 mg/L 0.200.'. 0.00187: .101 80-120 Lead 0.205 0.0100 mg/L" 0.200 6.000157 102 80-120 Magnesium 3.59 B . " 0.100 mg/L 2.00 1.57 . 101 80-120 Molybdenum 0.201 0.0100 mg/L 0.200 0.000344 101 80-120 Nickel ".' 0.207 0.0100 mg/L - 0.200 0.00179,103 80-120 -Potassium - - 117 -' '0.500-- mg/L - - -10.0 1.75- 300 80-120 Selenium 0.201 0.0100 mg/L .0.200-0.00554, 100 80120 Sodium 11.8. 0.500 mg/L 10'.0 1.44 .. 103 80-120 Zinc 0.215 0.0100 mg/L 0.200 0.0105. 102 80-120 _ Classical Chemistry Parameters - Quality Control ` Batch BEO1025 - NO PREP Blank (8EO1025-BLK1) Prepared: 05/01/2018 18:07 Analyzed: 05/01/2018 18:07 j Spike Source %REC RPD Anal lde Result Rau . P91 Units Lever Result %REC Limits RPD Limit Notes Nitrite as N 0.017 ` U 0.10 mg/L i LCS (8E01025-BS1) Prepared: OS/01/2018 18:34 Analyzed: 05/01/2018 18:34 Spike Source, %REC ' 'RPD Anal Result Flag. PQL Units Level, Result -°hREC Limier . ' RPD Limit Notes -� Nitrite as N., 1.1 0.10 mg/L 1.00 106 90-110 Matrix Spike (8E03025-MSI) Prepared: 05/91/2018 18:09 Analyzed: 05/O3/2018 18:09 Source: CB05461-01 Spike Source %REC RPD ADalttte . - _. Result -.Ela_tt -- P% . Units Level Result %REC Limits RPD Limit Notes Nitrite as N 2.1 E 0.10 mg/L 1.00 1.1 -102 90-110 QM-07 Matrix Spike (8E01025-MS2) Prepared: 65/01/2618 18:12 Analyzed: 05/Ol/2018 "18:12 Source: CB05461-02 " Spike Source %REC RPD: -`•, Anal llte Result Flag POL Units Level Result %REC •""•LimIS3 ' ' RPD Limit • .Notes' - Nitrite as N 1.0. 0.10 mg/L" 1.00 0.020 102 90-110 Matrix Spike,Dup (8E01025-MSDI) Prepared: 05/01/2018 18:10 Analyied:: O5/01/2018 18:10 r Source:_ CB05461-01 Spike Source %REC RPD Anal Result flag 'EM - Untts Level Result %REC Limits RPD Lbn t Notes Nitrite as N 2.1 E _ - -- 6.10 mg/L 1.00 1.1 . 103 " 90-116 0.3. 10 QM-07 - Batch 8E04013 - Same 81aok (8E04013-BLKI) - Prepared: OS/04/2018 1230 Analyzed: 05%O8/2018 10:35 .. _.I Spike Source b/oREC' RPD - Anal Result Flag PQC Units Level Result "/°REC . Limits RPD Limit M4tg,4- -- FINAL This report relates,only to the sample as received by the laboratory, and -may only be reproduced In full. - -Page 7 of 12 . RICO www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 8E04013 -"Same, Continued ' Blank (8E04013-BLKl) Continued Prepared: 05/04/2018 12:30 Analyzed:'05/08/2018 10:35 : Spike Source %REC RPD Result Elan P91. Units Level Resin %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 0:26. U 0.48 mg/L j— + LCS (8E04013-Bsl) Prepared: 05/04/2018 12:30 Analyzed: 05/08/2018 10:36 _J Spike Source "/.REC RPD Analyte Result Flan PQL Units Level' Res%REC limits RPD_ Result' Limit Notes Total Kjeldahl Nitrogen 12 0.48 mg/L 12:0.. 104 90-110 Matrix Spike (8E04013-MSi) Prepared: 05/04/2018 12:30 Analyzed: 05/08/2018 10:42 Source: CB05461-01 Spike Source %REC RPD Anal vte Result Fla4 P_QL Units Level Result • "/oREC Limits RPD Limit Notes Total Kjeldahl Nitrogen 20 D 0.96 mg/L 4.80 13 132 90-110 QM-07 Matrix Spike (8E04013-MS2) Prepared: 05/04/2018 12:30 Analyzed: 05/08/2018 10:47 Source: C805461-02 Spike Source b/oREC RPD Analvte BQsult _ lla9 P91 Units Level Result "%REC 'Limits RPD limit Notes Total Kjeldahl Nitrogen 10 0.48 mg/L 4.80 4.9 108 90-110 Matrix Spike Dup (8E04013-MSD1) Prepared: 05/04/2018 12:30 Analyzed: 05/08/2018 10:43 Source: CB05461-01 Spike Source %REC RPD Anal vte Result HAA P_QL Units Level Result %REC . Limits RPD imit Notes Total Kjeldahl Nitrogen 18 D 0.96 mg/L 4.80 13, 103 90-110 7 10 Batch 8E04014 -Same Blank (8E04014-BLKl) Prepared: 05/04/2018 12:30 Analyzed: 05/08/2018 12:26 Yl Spike Source %REC RPD AnaiYte Result Elan PQL Units Level Result %REC Limits RPD limit Notes Phosphorus 0.026 3 0.10 mg/L LCS'(8E04014-BS1) Prepared: 05/04/2018 12:30 Analyzed: 05/08/2018 12:27 Spike Source "/oREC RPD 9naLYtO Result E1a4 PM Units Level Result "/oREC . 'Limits RPD Limit Notes Phosphorus 1.7 ' 0.10 mg/L 1.60 104 80-120 Matrix Spike t8E04014-MS1) Prepared: 05/04/2018 12:30 Analyzed:* 05/08/2018 12:30 Source: CB05461-01 Spike Source ' ' %REC RPD Anal R4sul Him PGL Units • Level Result '/oREC Limits RPD Limit Notes Phosphorus 6.5 D 1.0 mg/L 0.640 5.6 .143 80-120 . ' QM-07 Matrix Spike Dup (SE04014-MSD1) Prepared: 05/04/2018 12:30 Analyzed: 05/08/2018 12:31, Source: CB05461-01 Spike Source %REC RPD AnalKte Result Flag PQL Units Level Result %REC. Limits RPD limit Notes Phosphorus 6.4 D 1.0 mg/L 0.646 5.6 1.13 • 807120 3 25 {1 Batch 8E08009 - NO PREP FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in'full. Page of 12 ' C www.encolabs.com QUALITY CONTROL -DATA Classical Chemistry Parameters -Quality Control-' Batch 8EO8009 - NO PREP - Continued, Blank (SE08009-BLK3) Prepared & Analyzed: 05/08/2018 11:28 Spike Source %REC RPD 9nallde-- -- --_ _ __Besult-.-___Ela9_P4L___-_Vnitf._-.-LevelResult. ---%REC----Limits_— RPD_ - --1,!®lL- -- - Notes- ---- ___ Total Solids, 0.0050 U 0.0050. % by Volume -= - LCS.(SE08009-BSi). a. _ -_ -w -=- _ __-.-Prepared &.Analyzed: Spike Source %REC RPD Anal lt Result flan M' Units Level Result °/aREC Limits RPD Lka Note Total Solids 1000 50 mg/L 1100 95 80-120 Duplicate (8E08009-DUPl)' Prepared & Analyzed:.05108/2018 11:28 Source: CB05461-01, Spike Source %REC RPD -- — — Anal 1Lt0- - --- - - - - - sul =Flaq-- - P9h- ------Unite -- Level- Result. '" %REC Jet RPD Limit Notes • - - Total Solids - 0,26 0.0050 % by Volume- 0.26 1 _. 20 Batch 8E11007 - NO PREP Blank (SE11007-BLKl) Prepared: 05/11/2018 10:16 Analyzed: 05/11/2018 10:16 Spike Source %REC RPD Anal YYe -Result Elan M Units Level Result %REC Limits, RPD Limit Notes Ammonia as N 0.045 U 0.10 . mg/L LCS (SE11007-BSI) Prepared: 05/11/2018 10:18 Analyzed: 05/11/2018 10:18 Spike Source %aREC RPD Anal Result Elan M Units Level Result '/oREC Limits RPD Limit Notes Ammonia as N 1.0 0.10 mg/L 1.00 102 90-110 Matrix'Splke (8E11007-MS1) Prepared: 05/11/2018 10:21 Analyzed: 05/11/2018 10:21 Source: CB04606-01. - Spike Source %REC RPD Anal vte Result Elan PQL Units Level Result %REC_ Limits RPD. 1,M t Notes Ammonia as N 17 1.0 mg/L 4.00 13 112 90-110 QM-07 Matrix Spike (8E11007-MS2) LLL Prepared: 05/11/2018 10:26 Analyzed: 05/11/2018 10:26 Source: CB05043-02 Spike , Source %REC RPD Anale Result Elan- PQL Units Level Result %REC, Limits RPD Limit Notes . Ammonia as N 0.41, 0.10 mg/L 0.389 0.045 U 104 90-110 Matrix Spike Dup (8E11007-MSD1) Prepared: 05/11/2018 10:23 Analyzed: 05/11/2018 10:23 i . Source: CB04606-01 Spike Source %REC RPD Anal Result - Mau OQL Units Level Result "/oREC Limits- RPD Limit Notes i Ammonia as -N - 16 1.0- mg/L 4.00 . 13 86 907110 .6 30 QM-07 Batch 8E14017- NO PREP . I , LCS (8E14017-BSI) Prepared- 05/14/2018 12:02.Analyzed: 05/14/2018 12:02 I. Spike Source %REC RPD Analyte '. Result Elan. PQL Units Level Result _ %REC. Limits RPD J,j1Bit Notes Nitrate/Nitrite as N 1,2 0.10 mg/L 1.25 97 90-110 FINAL '.This report relates only to'the-sample as received'by, the laboratory, and may only be reproduced in full. Page 9 of 12 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - quality Control Batch 8E14O17 - NO PREP - Continued Matrix Spike (BE14017-MS1) Prepared: 05/14/2018 12:05 Analyzed: 05/14/2018 12:05 Source:C803155-02 Spike Source %REC ROD Anal Result Elan PQL units Level Result o/aREC limits RPD Lima Notes Nitrate/Nitrite as N 21 2.0 mg/L 10:0 13 85 90-110 QM-07 Matrix Spike (SE14017-MS2) Prepared: 05/14/2018 12:11 Analyzed: 05/14/2018 12:11 Source: CB04350-01 Spike Source %REC RPD Analvte Result Mau P_QL units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 160 10 mg/L 50.0 110 92 90-110 Matrix Spike Dup (SE14017-MSDS) Prepared: 05/14/2018 12:07 Analyzed: 05/14/2018 12:07 Source: CB03155-02 Spike Source %REC RPD A_n_aL1 tt Result E1a4 PQL Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 22 2.0 mg/L 10.0 13 92 90-110 3 10 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 10 of 12 www.encolabs.com FLAGS/NOTES AND DEFINITIONS " B. The analyte was detected in the associated method blank. D The sample was analyzed at dilution. I The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, -where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation - data and moisture content, where applicable. = " E--- The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 11 of 12 ENVIRONMENTAL CONSERVATION LABORATORIES CHAIN -OF -CUSTODY RECORD ' 113775 Central Part Dr. 4310 Executive Park Court, Suite 111 102-A Woodwinds Industrial CL Orlando, FL 32824 Jaclrsonvi le, FL 32216-6069 Cary. NC 27511 (407) 826.5314 Fay: (407) 650-6945 (904) 26a---aM7 Fax (904) 296-6210 (919) 467-3090 Fax (919) 467-3515 www.+encolabs.com Page of Client blame i�ovozyrne5 North Amerce (NO008) Protect Number [none] Requested Analyses Requested Turnaround Times Note: Rush requests subject to acceptance by thefacility _ Standard _ __ Expedited Due m v) ii 2;c� Z IS a � C � >Z !V � p o m off in fl "" crj C o a+ & 0 O E o 5 N � {� ;� �? in � co f2 N tM to Z a Address 77 Pernj Chapel Church Road Protect Name/Dasc Monthly - Week One - SBM CilylSTrZip Franklinton, NC 27526 PO #, Billino Info 3800360507 Tel (919) 494-3000 Fax Reporting Contact Scott Creech Sampler(s). Name. Affiliation (Print) asf61L r von r'v5 BrAin Contact Accounts Payable Sign re Site Location ITune Zone LabWofkOrder Preservation iSee Codes) (Combine as necessary) Item p Sample ID (Field identification) Co1laction Data Cot+eovon Tims Comps Grab h1-3;r'rx (sap codes) 1ot;31 +: of Conlairmts Sample Comments <--Total #t of Containers Sample Kit Prepared By Datefrime Reli -d By Dateliime Received By 1 Datefrime CommentslSpecial Reporting Requirements Rat ns ishad 'Daterrune He coed y Date/Tim Refinqu shed By DaletTlm.e Race ad By OateTme Coa!er :'s d oemps on Recaiol CandillReceipt - �7 L eptable Unacceptable nnatnx : vw-urounmvater 5u-5em ova-unnt:mg water 5E-SeMment sw-surface Water WVJ-1r aS1rY1ater A -Air cr-utn2r loetau m cernmems) rrPsenacron: 1-105 n-nw ra-r,nw —.— — , .— t..— ,,, Note: All sample; submitted toEMCO Lahs are in accordance vath me terms and ccridi?ions liisied on the reverse of this form, unless,prior written agreements exist Sample Preservation ENCO Cary Work Order: C805462 ---Client: Novozymes North America-( Logged In:, 01-May-18 11:49 Preservation Check- Performed By: C605462-01 7,77proict7pH N lion 111C,�r! rm .' Project: Monthly - Week One - SBM Project [none] Logged By: John C King Date/Time: 5z& !Q60— 0HZChbckW' 7, 0 St ed- patpirnme�11` dthmen t ic 6qUiretner t A 250mLP4;H2SO4 <2 - Y_ NA Y 1(5 NA B 1250rnLP+HNO3 <2 Y A NA 76 NA Reagent Name ID 2 pH Strip ID: C:\ELMNT1Print\wko—PreservationChec1, Rea-qent Name ID 3 4 Reagent Name ID 6 Page 1 of 1 .._.... - _- 1 .. .. : Ac n or. tories � . hhel . Resps ve. Innavatite. - - -102-A Woodwinds Industrial -Court---- --- -- - - - _ - - - - _ Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 • --Thursday, June 14, 2018- Novozymes North America (NO008) __-_-..-Attn:_. Scott Creech 77 Perry Chapel=Church -Road ==--- = == --- —_ —.-- - -- - - — - --- -- --- --- - -- - _ — ----- - -=- Franklinton, NC 27525 RE: Laboratory Results for Project Number: [none], Project Name/Desc: Monthly - SBM ENCO Workorder(s): CB06935 - Dear Scott Creech, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Tuesday, June 5, 2018. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Chuck Smith Project Manager - Enclosure(s) FINAL 'This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 1 of 8 ce�O i www.encolabs.coib SAMPLE SUMMARY/LABORATORY CHRONICLE "'-' Sampledi 06/05/18 0730 ReceiVedd 06J05%18-30:10 '" " Parameter Preparation_- Hold Date/Tlme(s) Prep Date/Time(s) Analysis Date/Time(s) SM 254OD-1997 NO PREP 06/12/18 06/05/18 12:25 06/05/18 12:25 SM 52108-2001 NO PREP 06/07/18 07:30 06/05/18 14:44 06/OS/18 14:44 _ { SM 5220D-1997 --Same . '"-07/03/18T —' 06/07/18 07:41 06/07/18 10:15 _.". I ' I i L i r— I FINAL ^—ffiis report relates only to ttiesaniple as-asthe laboratory, and may only be reproduced in full. page 2 of 8 - (� �61 1 9G�J) www.encolabs.com SAMPLE DETECTION SUMMARY --------ClilentID:. SBM----------- - -------LabID:- CB06935-01 i AnalAe Results Elis Hu M mufts MethQd Moto Biochemical Oxygen Demand 14000 2.0 2.0 mg/L SM 5210E-2001 Chemical Oxygen Demand 35000 800 800 mg/L SM 5220D-1997 Total Suspended Solids 34000 2500 2500 mg/L SM 254OD-1997 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 3 of 8 Ca N104, 0 www.encolabs.com ANALYTICAL RESULTS Description: SBM Lab Sample ID: CB06935-01 Received: 06/05/18 10:10 Matrix: Sludge Sampled: 06/05/18 07:30 Work Order: CB06935 Project: Monthly - SBM Sampled By: Elbert Alston Classical Chemistry Parameters ^ - ENCO Cary certified analAe (NC 5911 Analt+te rCAS Numberl Results Flag Units DF MD6 POL Batch Method Analyzed - Notes 1 Biochemical Oxygen DemandA 14000 mg/L 1 2.0 2.0 8FO5026 SM 521OB-2001 06/05/18 14:44 ASC j Chemical Oxygen DemandA 35000 - mg/L 80 800 800 - 8F07001 - SM 5220D-1997 06/07/18 10:15- - ]OC - ` Total Suspended SolidsA - 34000 - mg/L ` - 1000 2500 2500 - 8F05024 SM 254OD-1997 06/05/18-12:25 - ` LBG - I I r- .. I FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 8 ' EIVCO www.encolabs.com- i QUALITY CONTROLMATA _- -' Classical Che_mistr1rParameters-- Quality Control' �' - - --- -- - Batch SF05024 - NO PREP Blank (8F05024-BLKi) — - -- - --- - Prepared & Analyzed: 06/05/2018 12:25-- - . - --. -- - - - Spike Source %REC — - RPD _ - — Anal 5ltE - --- --- - - Result - -Elm - - P91-- units Level-. - --Result _ . %REC Limits RPD -. Limit - - -Notes - - ----- ' Total Suspended Solids 2.5 U 2.5 mg/L LCS (BF05024-BS1) Prepared & Analyzed: 06/05/2018 12:25 Spike Source %REC RPD Anal Result Elan PSL. Units Level Result %REC Limits RPD Lim Notes Total Suspended Solids 99 2.5 mg/L 100 99 80-120 Duplicate (811`05024-DUK) Prepared & Analyzed: 06/05/2018 12:25 Source: CB03164-01 Spike Source %REC RPD Anal vte Result Flag M Units Level Result %REC Limits RPD Limit Notes Total Suspended Solids 190 50 . mg/L 180 2 20 Batch 8F05026 - NO PREP Blank (8F05026-BLK1) Prepared & Analyzed: 06/05/2018 14:44 Spike Source %REC RPD Ana11de Result Flaa PSlL Unib Level Result %REC Limits RPD Limit Notes Biochemical Oxygen Demand 2.0 U 2.0 mg/L LCS (8F05026-BS3) Prepared & Analyzed: 06/05/2018 14:44 Spike Source %REC RPD Analyte Result Elan PQl. Units Level Result %REC Limits RPD Limit Notes Biochemical Oxygen Demand 210 2.0 mg/L 198 106 85-115 _ Duplicate (SF05026-DUPl) Prepared & Analyzed: 06/05/2018 14:44 Source: CB03017-01 Spike Source %REC RPD Anal lde Result Flan P91. Units Level Result %REC Limits RPD Limit Notes Biochemical Oxygen Demand 11 2.0 mg/L 11 3 30 Batch SF07001- Same Blank (SF07001-BLKi) Prepared: 06/07/2018 07:41 Analyzed: 06/07/2018 10:15 Spike Source %REC RPD Anal Yte Result Elan Em Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 10 U 10 mg/L LCS (BF07001-BSI) Prepared: 06/07/2018 07:41 Analyzed: 06/07/2018 10:15 Spike Source %REC RPD Analyse Result Eaag P91 Units Level Result %REC Limft RPD Limit Notes Chemical Oxygen Demand 490 10 mg/L 500 99 90-110 Matrix Spike (BF07001-MS1) Prepared: 06/07/2018 07:41 Analyzed: 06/07/2018 10:15 Source: CB03044-01 Spike Source %REC RPD Anal ltte Result Elan EM Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 860 10 mg/L 526 340 98 90-110 C� • FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. - - Page 5 of 8 ' �60 www.encolabs.com QUALITY CONTROL DATA. Classical Chemistry Parameters -Quality Control-- - --- - Batch SF07001- Same =-Continued Matrix Spike Dup (8F07001-MSDI) Prepared: 06/07/2018 07:41 Analyzed: 06/07/2018 10:15 —_-- _ Source: CB03044-01 _ Spike Source %REC RPD Anal F184 _ - M Units Level Result %REC - Limps - RPD - Limft --Motes - - --- --—geSult -- - Chemical Oxygen Demand 840 10 mg/L 526 340 96 90-110 1 10 " j • l J i � 1 i i 1 I 1� - I --i i FINAL ;__ -This report relates only to the -sample as received by the laboratory, and may only be reproduced in full. 'Page 6-of 8 I www.encolabs.com. FLAGS/NOTES AND DEFINITIONS' B. -The-analyte was detected in the associated method blank. D The sample was analyzed at dilution.. 7 The reported value is between the laboratory method detection limit (MDLj -and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. " - U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation !:- data and moisture content, where applicable. • E--- The concentration indicated for this analyte is an estimated value above the calibration range of the ------- ----- ----- -_-.=-..insfrument l' Is va ue Isconsl ere -an es Imate: ---- -.- ----- ---.---------- -.------------ ----•------------ ---. i MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL). and is - based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: 'Practical Quantitation Limit. The PQL presented is the laboratory MRL:. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or,greater confidence) to make a "tentative identification". iP Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. _ - - - - -- FINAL - '-" 'This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 7 of 8 EN1fIRONMENTALCONSERVATION LABORATORIES CHAIN-OF=OUSTODY RIECORO www.entolabs.com = 10775 Central Port Dr. 4010 Executive ParkCaul, Suite-111 102-A Woodwinds industrial Cti Odando, FL 32824 - Jacksomrillo, FL 3221Sw(1069Cary; NG27511 - - (407) 820r5314. Fax (407) 850-6945 (9&%) 295-3007 Far (904") 295.6210 - (9191467ti0i0 Fax (919) 467-351 a Page - Of " Client name Project Number Requested Analyses Regitested Turnaround Novozymes Borth America (I40008) [Bane] . " Times Address Project NamolDese _ - _ Note: Rush requests subject to 77 Perry Chapel Church Road Monthly - SSNIJ acceptance, by the facility CitylSTTziP PO"41 Billfng Into - Frenklinton, NC-27 525 3800360507 Standard Tel Fax Reporting Contact i (019) 494-3000 Sett Creech U) in � Expedited Sam to ) N' e. Aftiliati n (Priki Bill", Contact. pL77 `� L Accaunts Payable � � Due u. �l 4 0 0 Sampior(s) Sipnatur" "Site Location 7 Time Zorn - CO CO - Ub Woritord2r - - See Codes Combine as necessary). - _ Preservat(an ( ) ( GaNecucn Matrix Total4-of Item N Sample ID (Feld Identification) Collection Date Time Comp / Grab (see caves) Containers Sample Comments S iVf 0731). SI_ - 3 X x X . ¢--Tnta(# of Cnntain�+rc . Sample U Prepared By 7'emme . Is Reli d By D i:lttrrP Ret<ed Bye DateiTme Commenis/Speciai Reporting Requiremcnis - Relinquished DalefUme Recu' - By Date im Relinquished By Datefl-1m E- Received By Da{effima: Goals e's & Temps on Receipt - _ _ I J • E—f[ �- Condition Upon Receipt _acceptable Unacceptable matrix; wrrumunuwator av-aon uuv-unmung water se-zaotment tow-bunace water very-viaslewater A -Air o-comer ((retail incomments) Preservation: Has K-HM N-HNO3 S-HZS04 NO-NaCH O-Other (detail in comments) Note: All samples submitted to ENCO Labs are in accordance with the terms and candi5ans listed on the reverse of (ills form, unless priorwrilten agreements exist Sample'Preservation Verification' ENCO Cary Work Order. CB08935 -Project. Monthly - SBM Client: Novozymes North America (N0008) Project #: [none] .- :-Logged in: 05-Jun -1 8 10:16 Preservation Logged By: Rachel Ann Yonis Che'ck'.P'e'rformed By: Date/Time: CB06936-01 F; FlIg "g zq, J)H','Ch W di/X,�� Re 4Jpe -A 250mLP+H28O4- T N't- NA, -4- NA-- 06 L-4 �sb- Rea-qent Name ID Reacient Name ID Reagent Name ID KISQ q 3 .5 2 4. 6 pH Strip ID: PH Strips C7.10820 -C-.kelmht\Ptint\wk6.Ptegetvc1fi6nChOck.tof- - Page 1 of 1 T,NC0.ta_bor#ton,,_s _ Accurate. ThoieI912esp onsive. Innovative. . 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Thursday, June 14, 2018 Novozymes North America (N0008) -Attn: Scott Creech- - - -. 77-Perry Chapel-Chuech Road- Franklinton, NC'27525 RE: Laboratory Results for Project Number: [none], Project Name/Desc: Monthly - Week One - SBM ENCO Workorder(s): C806937 Dear Scott Creech, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Tuesday, June 5, 2018. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in I full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under. separate cover. If you have any questions.or require further information, please do not hesitate to contact me. Sincerely, Chuck Smith. Project Manager Enclosure(s) rc FINAL This report relates only to the sample as.received by the laboratory, and may only be reproduced in full. Page 1 of 12 CSNg CO www.encolabs.com -- --- - SAMPLE-SUMMARY/LABORATORY CHRONICLE ClientIDi SBM i _ - _—__ _� - --- CatiID:YCB06937=01 Sampled: 06/05/18 07:30 Received: 06/05/18 10.10 Parameter Preparation-� __- _ _ __ Hold-Date/Tlme(s) - -- Prep Date/Time(sl Analysis Date/Time(s) CSU Method NO PREP 02/28/21 06/07/18 10:14 06/11/18 15:49 EPA 350.1 NO PREP 07/03/18 06/05/18 13:53 06/05/18 13:53 EPA 351.2 Same 07/03/18 06/08/18 11:16 06/11/18 11:23 EPA 353.2 NO PREP 06/07/18 07:30 06/05/18 17:37 06/05/18 17:37 EPA 3512 --NO-PREP 02/28%21 06/07/18 14:15 06/07/18 14:26 "^ EPA 365.4 Same 07/03/18 06/08/18 11:16 06/11/18 12:44 A ' EPA 60101) EPA-3005A,-- -_` -- 12/02/18 -06/07/18-- --10:14 EPA 7470A -" .—EPA 7470A - 07/03/18 06/06/18 11:11"- 06/07/18-11i35---- SM 254OB-1997 NO PREP 06/12/18 06/06/18 15:22 06/06/18 15:22 1 II 1 I I� ' FINAL -- -- Thisreportrelates only to the`sample-as received by the laboratory, and may -only be reproduced in full. - Page 2 of 12 SAMPLE DETECTION SUMMARY 0 9 �60 www.encolabs.com Client ID: SBM Lab ID:. CB06937-01 Anallyte Results fim Mob P46 ymm Method Notes Aluminum - Total 12.1 0.420 1.00 mg/L EPA 6010D Ammonia as N 140 D 4.5 10 mg/L EPA 350.1 Arsenic - Total 0.0892 3 0.0680 0.100 mg/L EPA 6010D Calcium -Total T _ ` 2790 0.390 UO mg/L EPA 6010D Copper- Total 0.0194 ] 0.0160 0.100 mg/L EPA 6010D Magnesium - Total 34.3 0.290 1.00 mg/L EPA 6010D Molybdenum - Total 0.0282 3 0.0250 0.100 mg/L EPA 6010D -� Nitrate as N _.-19 0.025 0.10 mg/L EPA 353.2 Nitrite as N -0.041 J 0.017 0.10 mg/L EPA 353.2 Phosphorus 690 D 10 40 mg/L EPA 365.4 Potassium - Total 683 1.50 5.00 mg/L EPA 6010D -- Sodium - Total 167 4.00 5.00 mg/L EPA 6010D Sodium Adsorption Ratio 0.861 [blank] CSU Method Total Kjeldahl Nitrogen 2500 D 52 96 mg/L EPA 351.2 Total Solids 5.3 0.25 0.25 % by Volume SM 2540B-1997 Zinc - Total 0.189 0.0440 0.100 mg/L EPA 6010D FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 12 CeNO www.encolabs.com ANALYTICAL RESULTS Description: SBM Lab Sample ID:CB06937-01 Received: 06/05/18 10:10 Matrix: Sludge Sampled: 06/05/18 07:30 Work Order: CB06937 Project: Monthly - Week One - SBM Sampled By: Elbert Alston Metals by EPA 6000/7000 Series Methods ' ^ - ENCO Cary certified analyte [NC 5911 Analyte rCAS Numberl Results Flaa Units DF MDL POL Batch Method Analyzed By Notes Mercury [7439-97-6]^ 0.000150 U mg/L 1 0.000150 0.000200 8F06016 EPA 7470A 06/07/18 11:35 NMN - Metals (total recoverable) by EPA 6000/7000 Series -Methods. ^ - ENCO Cary certified analyte [NC 591] Analyft rCAS Numberl Results flag Units PE MU p" Batch Method Analw7ed A1C Notes Aluminum [7429-90-5]A 12.1 mg/L 10 0.420 1.00 8FO7008 EPA 6010D 06/11/18 13:31 JDH Arsenic [7440-38-2]A 0.0892 J mg/L 10 0.0680 0.100 8F07008 EPA 6010D 06/11/18 13:31 JDH Cadmium [7440-43-9]A 0.00360 U mg/L 10 0.00360 0.0100 81`07008 EPA 6010D 06/11/18 13:31, JDH Calcium [7440-70-2]A 2790 mg/L 10 0.390 1.00 8F07008 EPA 6010D 06/11/18 13:31 JDH Copper[7440-50-B]A 0.0194 J mg/L 10 0.0160 0.100 8F07008 EPA 6010D 06/11/18 13:31 JDH Lead [7439-92-1]^ 0.0310 U mg/L 10 0.0310 0.100 8F07008 EPA 6010D 06/11/18 13:31 JDH Magnesium [7439-95-4]A 34.3 mg/L 10 0.290 1.00 8F07008 EPA 6010D 06/11/18 13:31 JDH Molybdenum [7439-98-7]A 0.0282 J mg/L 10 0.0250 0.100 8F07008 EPA 6010D 06/11/18 13:31 JDH Nickel[7440-02-0]A 0.0220 U mg/L 10 0.0220 0.100 8F07008 EPA 6010D 06/11/18 13:31 JDH Potassium [7440-09-7]A 683 mg/L 10 1.50 5.00 8FO7008 EPA 6010D 06/11/18 13:31 JDH Selenium [7782-49-2]^ 0.0620 U mg/L 10 0.0620 0.100 8F07008 EPA 6010D 06/11/18 13:31 JDH Sodium [7440-23-5]A 167 mg/L 10 4.00 5.00 8F0700B EPA 6010D 06/11/18 13:31 JDH Zinc'[7440-66-6]A 0.189 mg/L 10 0.0440 0.100 8F07008 EPA 6010D 06/11/18 13:31 JDH Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flag Units DF 7MDD1, POLL Batch Method Analyzed By Notes Ammonia as N [7664-41-7]A 140 D mg/L 100 4.5 10 8F05022 EPA 350.1 06/05/18 13:53 JU Nitrate as N [14797-55-S]A 19 mg/L 1 0.025 0.10 8F07021 EPA 353.2 06/07/18 14:26 JU Nitrite as N [14797-65-0]A 0.041 J mg/L 1 0.017 0.10 8FO5033 EPA 353.2 06/05/18 17:37 JU, Phosphorus[7723-14-0]A 690 D mg/L 400 10 40 8FO8010 EPA 365.4 06/11/18 12:44, JU Sodium Adsorption Ratio 0.861 [blank] I 8FO7008 CSU Method 06/11/18 15:49 JDH Total Kjeldahl Nitrogen 2500 D mg/L 200 52 96 8FO8009 EPA 351.2 06/11/18 11:23 _ JL1 Total SolidsA 5.3 % by Volume 50 0.25 0.25 8F06007 SM 254OB-1997 06/06/18 15:22 OMR 0, FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 4 of 12 60 i wmrvir.encolabs.com. _ - QUALITY CONTROL DATA __-- Metals.by EPA 6000/7000 Series Methods,- Quality Control, - Batch-8FO6016 -EPA 245:1 Blank (8F06016-BLK1) Prepared: 06/06/2018 11:11 Analyzed: 06/07/2618 11:10 Spike Source - %REC RPD AnaL1rt& Resul Elaq PQL Units Level EMU %REC Limits RPD Limit Notes. Mercury 0.000150 U 0.000200 mg/L Blank-(8F06016-BLK2)-------__._- __ -,__ __ _ __ _ _ -_'_ _- - -_-_prepared:-06/06/2018-b1:11-Analyzed:-06/07/2018.11:13 Spike Source %REC RPD Anal Result Flag - P91 Units Level Result %REC - .Limits RPD. Limit Notes, Mercury 0.00300 U 0.60400 mg/L LCS (SF06016-BSI) Prepared: 06/06/2018 11:11 Analyzed:, 06/07/2018 11:15 Spike. Source_... %REC RPD Anal Result flag POL Units Level Resul %REC Limitk RPD Limit Notes. Mercury 0.00566 ' 0.000200 mg/L 0.00500 113- 80-120 Matrix Spike (8F06016-MS1) Prepared: 06/06/2018 11:11 Analyzed: 06/07/2018 11:19 Source: CB07357-01: 'Spike ' Source - %REC RPD Analye Re.4ulL Ela4 PQL Units Level Result 0/.REC. Limits RPD Limit Notes Mercury 0.0054.4 0.000200 mg/L 0.00500 0.000150 U 109 75-125 Matrix Spike Dup (8F06016-MSD1) Prepared: 06/06/2018 11:11 Analyzed: 06/07/2018 11:22 i Source: CB07357-01 Spike Source . %REC RPD Analvte Result flag PQL Units Level Result %REC Limits RPD Lima Notes j Mercury 0.00548 0.000200 . mg/L 0.00500 0.000150 U 110 75-125 0.8, 25• Post Spike (81F06016-PS1) Prepared: 06/06/2018 11:11 Analyzed: 06/07/2018 11:24 Source: CB07357-01 Spike Source - %REC RPD Analyte Result Flag PQL Units Level Result %REC Limits RPD " Limit Notes Mercury 6.64 0.200 ug/L 5.00-0.0400 133. 75-125 "QM-08 Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 8F07008'- EPA 3005A Blank (8F07008-BLK3) Prepared: 06/07/2018 10:14 Analyzed: 06/11/2018 13:03 Spike Source %REC RPD Anal Result flag, PM Units Level Result %REC Limits RPD Limit Notes . 1 . Aluminum 0.0420 U 0.100 mg/L Arsenic 0.00680 U 0.0100 mg/L Cadmium 0.000360 U 0.00100 mg/L Calcium 0.0390 U 0.300 mg/L Copper 0.00160 U 0:0100 mg/C Lead 0.00310 U 0.0100 mg/L Magnesium .. 0.0290.. U .. 0.100 mg/L . _Molybdenum 0.00250 _ U 0.0100 mg/L Nickel 0.00220 .,U, -0.0100- , --mg/L Potassium 0.150 U 0.500 mg/L Selenium 0.00620 U 0.6100 mg/L Sodium 0.400 U 0.500 mg/L Zinc 0.00440 U . 0.6100 mg/L FINAL -This report relates only.to'the sample as received by the laboratory, and may onlybe reproduced in full. - Page 5 of 12 . i www.encolabs.com __QUALITY CONTROL DATA.. ` Metals (total recoverable)-bTEPA=6000/7000_Series-Methods = Quality Control Batch 8F07008 - EPA MOSA - Continued LCS (8F07008-BSl) Prepared: 06/07/2018 16:14 Analyzed: 06/11/2618 13:08 - - - --- Spike Source .REC - RPD - - - Anal ltte -. - - - esulF Fhi4 - P91 - Units Level Result %REC u[ili s _ ROD L![nk Notes Aluminum ..1.98 0.100 mg/L 2.00 99 80-120 __ ---- _-,Arsenic.. - _,----- _-------�0.207 U.0100 _=m9/L 0.200 104._ _ 80-120 ..._. _- - --Cadmium= :- :- :'- -_. _:0202 ^ 00300= mg/L- 0.0200 101 80-120- Calcium 2.09 0.100 mg/L 2.00 105 80-120 Copper -0.189. 0.0100 mg/L 0.200 '94 80-120 Lead :0.204 0.0100 mg/L 0.200 102 80-120 ` Magnesium 1.90 0.100 mg/L 2.00 95 80-120 Molybdenum 0.199 0.0100 mg/L 0.200 99 80-120 3 Nickel 0.196 0.0100 mg/L 0.200 98 80-120 Potassium - -- 10.0 - -- - -0.500 mg/L 10.0 "" 100 �I 80-120 - -- ---- - Selenium 0.211 0.0100 mg/L 0.200 105 80-120 Sodium 10.3 0.500 mg/L 10.0 103 80-120 Zinc 0.209 0.0100 mg/L 0.200 105 80-120 - - Matrix Spike (8F07008-MSI) Prepared: 06/07/2018 10:14 Analyzed: 06/11/2018 13:11 Source: CB07889-02 _•_ - _ Spike Source %REC RPD_ .. _ �naUde Resin Hau Pal. Units Level get %REC Limits, RPD Limit Notes. Aluminum 1.99 0:100 mg/L 2.06 0.0420 U 99 75-125 Arsenic 0.206 0.0100 mg/L 0.200 0.00680 U 103 75-125 Cadmium 0.0194 0.00100 mg/L 0.0200 0.000360 U 97 75-125 , Calcium 77.5 0.100 mg/L 2.00 77.1 22 75-125 . QM-07 Copper 0.191 0.0100 mg/L 0.200 0.00160 U 96 75-125 Lead 0.198 0.0100 mg/L 0.200 0.00310 U 99 75-125 Magnesium 39.5 0.100 mg/L 2.00 36.0 176 75-125 QM-07 Molybdenum 0.201 0.0100 mg/L 0.200 0.00284 99 75-125 Nickel 0.192 0.0100 mg/L 0.200 0.00220 U 96 75-125 Potassium 12.5 0.500 mg/L 10.0 2.45 100 75-125 Selenium 0.204. 0.0100 mg/L 0.200 0.00620 U 102 75-125 Sodium 12.4, 0.500 mg/L 10.0 2.40 100 75-125 . Zinc 0.234 0.0100 mg/L 0.200 0.0313 101 75-125 Matrix Spike Dup (8F07068-MSD1) Prepared: 06/07/2018 10:14 Analyzed: 06/11/2018 13:13 Source: CB07889-02 Spike Source %REC RPD Analvte Result Flan POOL Units Level Result %REC Limier RPD LImIY Notes Aluminum 1.98 0.100 mg/L 2.00 0.0420 U 99 75-125 0.3 20 Arsenic 0.204 0.0100 mg/L 0.200 0.00680 U 102 75-125 0.6 20 Cadmium 0.0196 0.00100 mg/L 0.020,0 0.000360 U 98_ 75-125 1 20 Calcium 78.6 0.100 mg/L 2.00 77.1 73 75-125 _1 " 20 QM-07 " Copper 0.192 0.0100 mg/L 0.200 0.00160 U 96 75-125 0:5, 20 Lead 0.202 0.0100 mg/L 0.200 0.00310 U .101 75-125 • 2 20 Magnesium 38.9. 0.100 mg/L 2.00 36.0 148 75425 1 26 QM-07 Molybdenum 0.203 0.0100 mg/L 0.200 0.00284 100 75-125 1 . 20 Nickel 0.193 0.0100 mg/L 0.200 0.00220 U 97 75-125 0.5 S. -20 Potassium 12.7 0.500 mg/L 10.0 , 2.45 102 75-125 2 20 Selenium 0.202 0.0100 mg/L 0.200 0.00620 U 101 75-125 - 1- , ,' 20 Sodium 12.6 0.500 mg/L 10.0 2.40 102 75-125 2 20 Zinc 0.236 0.0100 mg/L 0.200 0.0313 102 75-125 0.9 20 _. _.._. FINAL -_- =-_=This report -relates only_toahe=sample as received by the laboratory, and may only be reproduced In full._, ___ page 6 of-12 QUALITY CONTROL DATA _. lMetals _(total recoverable) by -EPA 6000/7000.Serie§ Methods - Quality Control Batch 8F07008 - EPA 3005A - Continued - Post Spike (8F07008rPS1) Prepared: 06/07/2018 10:14 Analyzed: 06/11/2018 13:16 - Source: CB07889-02 ` - Spike Source %REC _ RPD --Analyte _ Result - Flan_'_ _-P44 ---=.•Units __- Level - -' = -Result r =9/oREC' ' -Limits_ __ RPD - -- J,jpljs _Notes _ ,Aluminum , 2.01 0.100 mg/L 2.00 -0.0143, 101 80-120 Arsenic.___ _. _�r _.'_.0.217 _0.0100.-_"'„_mg/L --_, _0.200.. .,,.70.000109 . 108 80-120-- :_Cadmium _ 0.0199 0.00100 mg/L 0.0200 -0:000191 99- 80-120 Calcium 78.3 0.100 mg/L 2.00 77.1 61 80-120 QM-08 Copper 0.193 0.0100• mg/L 0.200 -_0.000787 97 80-120 Lead .0.203 0.0100 ' v mg/L 0.200 -6.53E-5 101 80-120 Magnesium. 40.1 0.100 mg/L 2.00 36.0 208 .80-120, QM-08 Molybdenum 0.205 0.0100 mg/L 0.200 0.00284 101, 80-120 Nickel 0.192 0.0100 mg/L 0,200 8.11E-5 96 80-120 - Potassium 12.6 0.500 mg/L - - -10.0 • 2-.45 102 80-120 Selenium 0.205 0.0160 mg/L 0.200 -0.0123 .103 80-120 Sodium 12.5 0.500 mg/L 10.0 2.40' 101 80-120 Zinc 0.22.7 0.0100 mg/L 0.200 0.0313. 98 80-120 Classical Chemistry Parameters - Quality Control Batch 8F05022 - NO PREP Blank (8F05022-BLK3) Prepared: 06/05/2018 13:32Analyzed: 06/05/2018 13:32 Spike Source %REC RPD Analyte Result Elm OQL MdM Lever Result %REC Limits RPD Limit Notes Ammonia as N 0.045 U 0.10 mg/L LCS (81`05022=1151) Prepared: 06/05/2018 13:37 Analyzed: 06/05/2018 13:37 Spike Source %REC RPD Anallttq- BEsuli Elan; PQL Units Level. ' Result '%REC Limits RPD Limit Notes , Ammonia as N T 1.0 0.10 mgIL 1.00 101 90-110 Matrix Spike.(SF05022-MSS) Prepared: 06/05/2018 13:41 Analyzed: 06/05/2018 13:41 Source: CB03017-01 Spike Source %REC RPD AnaLlLte Resul Elan P91.. Units Lever Result %REC Limits RPD Limit' Notes Ammonia as N 1.9 0.20 mg/L 0.800 1.2 94 90-110 Matrix Spike (8F05022-MS2) Prepared: 06/05/2018 14:51 Analyzed: 06/05/2018 14:51 Source: CB04621-01RE1 ;Spike Source %REC RPD �naLltSe Result Elao PQL Units Level Result %REC Limits RPD Limit Notes Ammonia as N 1.1 0.10 mg/L 0.389 .0.75 99 90-110 Matrix Spike Dup (8F05022-MSD3) Prepared: 06/05/2018 13:42 Analyzed: 06/OS/2018 13:42 Source: CB03017-01 Spike Source %REC RPD 9nMYle Result F1a4 M Units Level Result %REC Limits RPD Limit Notes Ammonia as N 2.0 0.20 mg/L 0.800 1.2 102 90-110 3 10 Batch 8F05033 - NO PREP- Blank (8F05033-BLK1) Prepared: 06/05/2018 17:29 Analyzed: 06/05/2018 17:29 Spike Source %REC RPD Anil Result Elan PQL Units Lever Result %REC Limits RPD Limit Notes FINAL _ _ - This report relates only .to the sample as received by the laboratory; and may only be reproduced in full. Page 7 of 12 ' QUALITY CONTROL DATA Classical Chemistry Parameters.- Quality Control Batch 8F05033.- NO PREP - Continued Blank (SF05033-BLKi) Continued Prepared: 06/05/2018 17:29 Analyzed: 06/05/2018 17:29 Spike Source %REC RPD Result Elan P-01. Units Level Result %REC Limits RPD' Limit Notes Nitrite as N 0.017 U 0.10 mg/L LCS•(SF05033-BS1)- :-_ . -- - -Prepared: 06/05/2018 17:21-Analyzed: 06/05/20,18 17:21 - - - - - Spike Source %REC RPD .Analyte Resuli Elan PGL Units Level Result %REC Limits RPD Limit Notes Nitrite as. N 0.96 0.10 mg/L 1.00 96 90-110 Matrix Spike (8F05033-MSi) Prepared: 06/05/2018 17:31 Analyzed: 06/05/2018 17:31 Source: CB06478-01 - —• - Spike Source %REC RPD Anal vte Result Fla PAL Units Level gesult %REC Limit's RPD Limit Notes w Nitrite as N 0.94 0.10. mg/L 1.00 0.017 U 94 900110 Matrix Spike Dup (8F05033-MSD3) Prepared: 06/05/2018 17:32 Analyzed: 06/05/2018 17:32 _ Source: CB06478-01 Spike Source %REC RPD ADalYte Result _ _Elan, PQL - _' Units Level Result %REC Limits RPD Limit Notes Nitrite as N 0.96 0.10 mg/L 1.00 0.017 U 96 90-110 2 10 _ Batch 8F06007 - NO PREP Blank (8F06007-BLK1) Prepared & Analyzed: 06/06/2018 15:22 Spike Source %REC RPD Analvtfl Result Elan, P" WAS Level Besul %REC Limits RPD Limit Notes Total Solids 0.0050 U 0.0050 % by Volume LCS (8F06007-BSI) Prepared & Analyzed: 06/06/2018 15:22 Spike Source %REC RPD - AnalvtL' .. Resuli Elan POL Units Level Result %REC Limits RPD Limit Notes Total Solids 1100 50 mg/L 1100 98 80-120 Duplicate (8F06007-DUPi) Prepared & Analyzed: 06/06/201815:22 Source: CB06936-01 Spike Source %REC RPD Anal Result flag. PQL ..'Mau Level' Result %REC Limits - .RPD limit Notes Total Solids 0.24 0.0050• % by Volume 0.24 0.3 20 ' Batch 8F0602.1 NO PREP LCS (8F06021-BS3) Prepared: 06/06/2018 13:24 Analyzed: 06/06/2018 13:24 Spike Source '%REC RPD AnalYte Result Elm RQL Units Level Result. %REC Limits RPD Limit Notes - ' ,' 1 Nitrate/Nitrite as N 1.3 0.10 mg/L 1.25 103 90-110 Matrix Spike (8F06021-MS1) . Prepared: 06/06/2018 13:28' Analyzed: 06/06/2018 13:28 ' Source: CB05033-01 Analtle Nitrate/Nitrite as N Spike Source %REC Result flag. . PQL UUnM . Level Result %REC Limits RPD 0.56 0.10, mg/L 0.521 0.041 U , 107 90-110 RPD Limit Notes . - FINAL This report relates'only to the sample as received by the laboratory, and may only be reproduced in full. Page 8 of 12 i www.encolabs.com QUALITY CONTROL DATA _ Classical Chemistry Parameters - Quality Control_ - - Batch 8F06021 - NO PREP - Continued Matrix Spike (81`06021-MS2) Prepared: 06/06/2018 13:33 Analyzed: 06/06/2018 13:33 'Source: C605507-01 - -_--. Spike Source - - -- %REC -. - - RP,D _ - - Analyte - _ Result Elan P91 Units Level Result %REC Limits- - RPD" Limit -Notes Nitrate/Nitrite is N 260 E 10 mg/L . 50.0 210 88 90-110 QM-07 Matrix,Spike Dup-(8F.06021-MSD1) Prepared:-06/06J2018-13:30 Analyzed:_06/06/2018-13:30- Source. CB05033-01 - - Spike Source%REC r RPD _9nalt�' _.�- ___ _ :_: _ _ _Result--_F)an— __.P91 _-- _1lnits.—: _Level _--Result __%REC- --.Limits. -= RPD _._ Limit _.-_Notes____._._ .Nitrate/Nitrite as N 0.54 0.10 mg/L 0.521 0.041 U 104 90-110 3 10 Batch 8F07008 -. EPA 3005A Blank (81F07008-13LKi) Prepared: 06/07/2018 10:14 Analyzed: 06/11/2018 15:50 Spike Source %REC RPD Analyte Result Elan M Units Level Result- %REC Limits RPD Limit Notes Sodium Adsorption Ratio 0.00 U [blank] Batch 8F08009 -,Same - Blank (8F08009-BLKi) Prepared: 06/08/2018 11:16 Analyzed: 06/11/2018 09:58 Spike Source %REC RPD Apalvte - Result Elm OQL llnits Level Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 0.26 U 0.48 mg/L LCS (8F08009-BS1) Prepared: 06/08/2018 11:16 Analyzed: 06/11/2018 10:00 Spike Source %REC RPD Analvte Result Flao POL Units Level Result %REC Limits RPD - Limit Notes Total Kjeldahl Nitrogen - 12- - 0.48 mg/L 12.0 101, 1 90-110 Matrix Spike (8F08009-MS1) Prepared: 06/08/2018 11:16 Analyzed: 06/11/2018 11:11 Source: CB06478-01 Spike Source %REC RPD Analyse Result Flan P91 Units Level Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen .13 0.48 mg/L 4.80 8.0 111 90-110 QM-07 Matrix Spike (8F08009-MS2) Prepared: 06/08/2018 11:16 Analyzed: 06/11/2018 111:16 Source: CB05033-01 Spike Source %REC RPD Anal lde Result Elan PQL Units Level Result %REC Limits RPD ina Notes Total Kjeldahl Nitrogen 23 0.48 mg/L 4.80 18 102 907110 Matrix Spike Dup (8F08009-MSD1) Prepared: 06/08/2018 11:16 Analyzed: 06/11/2018 11:13 Source: CB06478-01 Spike Source %REC RPD Anal Yte Result Elan P91. Units Level Result' %REC LimjM RPD Limit Notes Total Kjeldahl Nitrogen .12 0.48 mg/L 4.80 8.0 91 90-110 7 10 Batch 8F08010 = Same Blank (8F08010-BLK1) i Prepared: 06/08/2018 11:16 Analyzed: 06/11/2018 10:35 Spike Source: %REC RPD Analyte Result Fian P91 llnit£ Level Result' %REC Limits RPD Limit Notes Phosphorus - 0.025 U 0.10 mg/L i FINAL This report relates only to.the sample as.receivedby-the laboratory, and.may only,be reproduced in full. — ____ __ - Page 9 of 12 _ CSN� www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 8F08010 - Same - Continued LCS (81`08010-11SI) Prepared: 06/08/2018 11:16 Analyzed: 06/11/2018 10:36 Spike Source %REC RPD Anahtte _ Resin Flan 13.4E Level Resul %REC Limits RPD Limit Notes Phosphorus , 1.6 0.10 _ mg/L 1.60 102, 80-120 Matrix Spike (8FOB010-MS1) Prepared: 06/08/2018 11:16 Analyzed: 06/12/2018 10:10 Source:CB06478-OIREi Spike Source %REC RPD Anal Yte RentIt Elm PQL Units Level Result %REC Limits RPD Limit Notes Phosphorus 7.9 D 0.50 mg/L 0.640 7.2 110 80-120 Matrix Spike Dup (BFOB010-MSD1) Prepared: 06/08/2018 11:16 Analyzed: 06/12/2018 10:11 Source: CB06478-OIRE1 — Spike Source %REC RPD ABalyte Result Flag p46 units Level Result %REC Limits RPD Limit Notes Phosphorus 7.6 D 0.50 mg/L 0.640 7.2 76 80-120 3 25 QM-07 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full._ - - Page 10 of 12 ' 'E") www,encolabs.com . FLAGS/NOTES AND.DEFINITIONS -- B The analyte was detected in the associated method blank. D The sample -was analyzed at dilution. 7 : The reported value_ is between the laboratory method detection limit (MDL) and the laboratory method _ reporting limit (MRL), adjusted for actual sample preparation data and moisture content,.where applicable. U The analyte was analyzed for but not -detected tothelevel. shown, adjusted -for actual sample'preparation- f data and moisture content, where applicable. - - E _ . The concentration indicated for this analyte is an value -above the calibration ran e•of the-- i "- instrument. This value is considered an est'imate.. - - - MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitabon limit (PQL) and is - - - - based on the low point of the calibration curve, when applicable, sample preparation factor, dilution . factor, and, in the case of soil samples,, moisture content. PQL PQL: Practical Quantitation Limit:. The PQL presented is the laboratory MRL. - N . The analysis indicates the presence of an analyte for which there is presumptive-evidence-(85% or greater - { confidence) to make a "tentative identification". I P - Greater than'25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. l QM-07 -The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. QM-08 Post -digestion spike did not meet method requirements due to confirmed matrix effects (dilution test). - - Page 11 of 12 . ... ENVIRONMENTAL CONSERVATION LABORATORIES. CHAIN -OF -CUSTODY RECORD 10775 Central Parr Dr. - 481D Executive Park Cart, Suite t1 t -- 102-A WoDeWnds Industrial Ct_ - Odehdo. FL 32624 Jacksonfrille. FL.322 &W63 Car%= 27o1 / - (407) 826-5314 Fax:(407) 65tt-6945 . (9tt4) M6-30t}7 Fax (904) 22&(M0 - - -(919) 467-3090- Fax (919) 467-3515 www.enco1abs.coM Page. of . .• Client Naine idaulazyrrles iVorth America (hlOOt?8) -.. -.. Project Numtrer [n0t7] Requested analyses- . '. Requested TUmarourld Times .Note : Rush requests subject to - cceptanca'iryth facility ' - Standard — Expedited J3 a - Z _: H.. �- ,rani_:.. A.. .-`. III. ey - - Cra ° ICU % -• to �° �• 4 0- z Address - '77.,Rprry� Chapel Church R6ad Pro act NamelDesc 1 " thly =.Week One;- SBM _. CI"ipTIM ....... ....... . h/. P Fr&iklinton,-NC -7525 P041B61in 'Info B .3800360607 Tel - (9'B9)-494-3000 :. Fax . RapaArigConW. Stet 06t ch " Sampl®r(s) Na Illation ( ' it); _ : '' 6lring C(nfa�: .:. ccaunts Payable : - Sampier(s)Signatu "c ` SitaLTime Lati;ldVtSrltgder 00 Preservation (See -Codas) (Corii6 rre as raecesry) Itom 4 Sample lD (Field Identification) Collection Data, Coltration Time _ Camp/Grab tdahb (sae ogdes) Total#ot - Cantahrers - Sample Comments _ - .- c--jotat # of Containers . Sample Kit Prepared By DateTrita .. 51 ReG qu By Date/flare . Rerivad Sy- DatelFme CommentalSpacial Reporting Requirements , ' ;. 1 Relinquish ad a Datelt-rsrre Rece Dat M elitrquishedBy Dava r-vm Received By Datemme:. Coaler 4's &.Temps on Recelpt CandtUon Upon;Recelpl s- . Acceptable:. =Unacceptable Matrix : GW,GrobndwalerSO-Soil DW-Ddnkfng Water SE-Ssdiment SW-Sddace Water W W-Wsstawa(er:A-Afr "Iher(detmlin'wmments) Preservation: Flce H-HCl N-HNO3 54{2SO4 NO finCH'O-Other (dgial fn comments) ';. Note: All samples s6birritted to ENCO tabs are. in accordance whir the ferms and cpncR qnS listed on the reran e'oi th s form, uat2ss prras wdtteti agr cements exist -, Sample Preservation Verification ENCO Cary Work Order: CB06937 Project: Monthly - Week One - SBM Client: Novozymes, North America (N0008) Project #: [none] Logged In: 05-Jun-18 10:25 Logged -By: Rachel Ann Yonis - Preservation Check Performed By: cr> DatelTime: �� ( �0 i CB06937-01 �'�.:? Cant `� ` a vx•7 t �� ,�.!. i� ,ge � '��`��` fig. yP ��,I'�reu,.(Yn ?.'#rs .pFf'%tom �irl�ed�7� � � � � �� }� x..�"w� ,w.f # '�; . AkLJ e! k��e �d � p1 t;Adufed . �� i,,: Via. :.ti�j',; "`.r-"^^ .�` .;k.*ivA.��F��+"'zt8ki;i?�+;c ' a' lfSecCa s ,,, r.- Regirreine►tm; n .! Coatrot r=;,° 3 vAtlwsked: <Ragenf mentsa' z, . ,.. .3;, ::.4_ ... w x :A 250mLP+H2804 -- <2: i NA Y / N / NA f 103i7 -'I" L-I(Y1J�� /- B 250niLP+HNO3 c2 Y ! N / NA / N / NA - Reacent Name ID Rea ent Name ID Rea ent Name ID �- 2 41 g pH Strip ID: PH -Strips C7]0$20 - C:lelmnt\Print%wicu_-rreservationunecK.tpt - - - _ - =_-_ _= = - -- - - - -_ - - Page 1 of 1 � '�rpouSG - Ac_e r te. % jly. Al -gip onsive. Ir�reo� € xvle, 102-A Woodwinds Industrial Court Cary NC; 27511 Phone: 919.467.3090 FAX: 919.467.3515 Friday, July 13, 2018 - Novozymes North America (N0008) Attu: Scott Creech 77 Perry Chapel Church Road--- Franklinton, NC 27525 RE: Laboratory Results for - Project Number: [none], Project Name/Desc: Monthly - SBM ENCO'Workorder(s): CB08876 Dear Scott Creech, Enclosed is a copy of your laboratory report for test samples received by our -laboratory on Tuesday, July 3, 2018. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the -Laboratory.- - This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, -Chuck Smith Project Manager Enclosure(s) FINAL ... This report relates only t6the sample as received by the laboratory, and may only be reproduced in full. Page 1 of 8 (e� ee) www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: SBM Lab ID: CB08876-01 Sampled: 67/03/18 08,00 Received: 07/03/18 10:10 Parameter Preparation -- - Hold-Date/Time(s]- Prep Date/Time(s) Analysis Date/Time(s) SM 254OD-1997 NO PREP 07/10/18 07/05/18 12:41 07/05/18 12:41 SM 521OB-2001 NO PREP 07/05/18 08:00 07/04/18 11:43 07/04/18 11:43 SM 5220D-1997 Same 07/31/18 07/05/18 09:46 07/05/18 12:20 FINAL = - - __ --This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 2 of 8 CqNclmej www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: SBM Lab ID: CB08876-01 @IIallft Results Elm MP1 M Units Method Notes Biochemical Oxygen Demand 9300 2.0 2.0 mg/L SM 5210E-2001 B-07 Chemical Oxygen Demand 32000 800 800 mg/L SM 5220D-1997 Total Suspended Solids 27000 2500 2500 mg/L SM 2590D-1997 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 8 www.encolabs.com ANALYTICAL RESULTS Description: SBM Lab Sample ID:CB08876-01 Received: 07/03/18 10:10 Matrix: Sludge Sampled:07/03/18 08:00 Work Order: CB08876 Project: Monthly - SBM Sampled By: Elbert Alston Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flaa Units DF MDL Q Batch Method Analyzed By (Votes Biochemical Oxygen Demand^ 9300 mg/L 1 2.0 2.0 8G04001 SM 521OB-2001 07/04/18 11:43 30C B-07 Chemical Oxygen Demand^ 32000 mg/L 80 800 800 8GO5007 SM 5220D-1997 07/05/18 12:20 30C Total Suspended Solids^ - 27000 mg/L 1000 2500 2500 8GO5023 SM 2540D-1997 07/05/18 12:41 LBG- FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 8 --` CMMW lab wvuw.encolabs.com . QUALITY CONTROL -DATA Classical Chemistry Parameters .-Quality Control: - - - Batch 8GO4001 - NO PREP Blank (8G04001-BLK1)--..,_ Prepared.& Analyzed: 07/04/2018-11:43- _. -' - - Spike-- -Source- --- - %REC- - RPD = _- . -Al1aLVte - -- -- - - - -Result -- 'ilea - P_Q6 -- - -Units - -Level -- Result %REC- RPD Limit Notes ' Biochemical 0 _ xygen Demand 2.0 U 2.0 mg/L , _- LCS (BG04001-BSi) _M__ �r____ _ ;. _ . ._ _ _ __._._____ .__.__ _.__._Prepared & Analyzed: 07/091201B.11:43-_ Spike Source %REC RPD , Analtde_..:_-- -- -- _ ._ Result . __Etas:_ _ PQL_ __Units- -.---Level--- _-Result- -- _%REC.__ -Lint RPD------)fit _ Notes - Biochemical Oxygen Demand 150' 2.0 mg/L - 198 77 85-115 B-07 Duplicate (8G04001-DUPl) Prepared & Analyzed: 07/04/2018 11:43 Source: CB08531-01 Spike Source %REC RPD Anal lt Resul Flaq POL llnft . Level Result %REC Limits RPD Limit Notes j Biochemical Oxygen Demand 1600 2.0 mg/L 1500 6 30 B-07 -- Batch 8GOS007 - Same Blank (8G05007-BLKl) Prepared: 07/05/2018 09:46 Analyzed: 07/05/2018 12:20 - - -=- -- _ Spike Source %REC RPD . �nalldg Result flan MQL Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 10 U . 10 mg/L LCS (8G05007-13SI) Prepared: 07/05/2018 09:46 Analyzed: 67/05/2018 12:20 Spike Source %REC RPD Anal ldg Result flag PQL Units Level Result %REC Limits RPD b101it Notes Chemical Oxygen Demand 500 10 mg/L 500 10090-110 _- Matrix Spike (BG05007-MSI) Prepared: 07/05/2018 09:46 Analyzed: 07/05/2018 12:20 - Source: CA11357-01 - Spike Source %REC RPD AnaltCtg Be:ult, Flan P41 Units Level RJR %REC Limits , RPD Limit Notes Chemical Oxygen Demand 820 10 mg/L 526 .290 101 907110 Matrix Spike Dup (8G05007-MSD1) Prepared: 07/05/2018 09:46 Analyzed: 07/05/2018 12:20 Source: CA11357-01 Spike Source %REC RPD AnalYte Result leas P_4L Units Level Result. %REC, . Limits RPD Limit Notes Chemical Oxygen Demand 810 10 mg/L 526 290 99 90-110 2 10 Batch 8GO5023 - NO PREP. Blank (8G05023-BLK3) Prepared & Analyzed: 07/05/2018 12:41 _ Spike Source %REC RPD Anal Result flea POL Units Level Result %REC ' 'Limits RPD - Limit Notes Total Suspended Solids 2.5 U 2.5 mg/L LCS (8G05023-BS1) Prepared & Analyzed: 07/05/2018 12:41 Spike Source %REC RPD 9naLlLte 'Result flan PQL Units Level Result. %REC. Limits RPD 611nit Notes Total Suspended Solids I i 92 2.5 mg/L 100 92., 80-120 . FINAL This report relates only -to the sample as received by the laboratory, and may only be reproduced in full. Page 5 of 8 - www.encolabs.com -- -- -- -----QUAL-I-TY CONTROL,DATA - Classical Chemistry Parameters - Quality Control Batch 8G05023 - MD PREP - Continued Duplicate (8G05023-DUP3) Prepared & Analyzed: 07/05/2018 12:41 Source: CB08047-01 - - - - - - Spike Source %REC RPD Anal Result Flag PQL Units Level Result %REC Limits RPD Limit Notes Total Suspended Solids 280 60 mg/L 230 17 20 Duplicate (BG05023-DUP2) _ _ _ Prepared & Analyzed: 07/05/2018 12:41 Source: CB08877-01 Spike Source %REC Anal lde Result Elan . PGL Units Level Result %REC Limits RPD Total Suspended Solids 110 25 mg/L 110 2 RPD Limit Notes 20 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 6 of 8 ��C%GW www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. - - - D The sample was analyzed at dilution. ] The reported value is between the laboratory method detection limit (MDL).and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated -for this-analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. B-07 LCS exceeded control limits for this test. The test can not be repeated due to method constraints. The result should be considered an estimated value. FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 7 of 8 ENVIRONMENTAL CONSERVATION LABORATORIES CHAIN-OF-CUSTdDY RECORD www.encolabs.com 10775 Central Pon Dr. .1810 Executivo Part: Court, Suilo 111 102•A Woodwinds Industrial Ct- Odando. FL 32824 Jacksonville, FL 32216.6069 Cary, NC 27511 (407) 626.5314 Fax (407) 850.6945 (904) 296.3007 Fax (904) 296.6210 (919) 457.3090 Fax (919) 467-3515 Page Of Client Name Project Number Requested Analyses Requested Turnaround Novozymes North America (NO008) [motile] Times Address Project NamelDesc Note: Rush requests subject to 77 Pern7 Chapel Church Road Monthly - SSM acceptance by the facility City/ST2ip PO * i Billing into Franklinton, NC 27525 3800360507 ® Standard Tel Far. Reporting Contact a O (919) 494-3000 Scott Creech _Expedited Sam er(s) 3me, Affiliation (Print) BilGrl2 g Contact Z 2 Aceounts Payable CO (0 (J) Due Sam pl r(s S' nalur Site Location /Time Zone .. C) Q � Lab Workorderr - 876 _ 4M•' Present ton (te Cedes) (Combine as n.cessary) " Coliaction Matrix Tonal n 01 item tl Sample ID (Field Identification) Cd+action Date- nn.Time Comp/Grab (see codes) Cor"Wrials Sample Comments SBM !_ G SL. 3 X h R i i <-- Total; of Containers Sample tit Prepared By Oat;/Time -�gfgR ` Dst- 73-ff e"r1 Rece(rodBy DateTmew 7-� �5 '0� VQ Comments+Speclal Reposing Requifemerds Retinquished Carol ime I RecA Dam a In f Relinquished By Daramme Received By Date/Tme Cooler k's 8 Temps on Receipt � v Condition Upon Receipt X_ Acceptable Unacceptable u. ru ' ung vidwr SE-Seuanerrl SW -Surface crater ww-wastewarer A -Air a-uther (detail in comments) Preservation: t-Ice H-HCl 14-1,11403 S-1-128O4 NO-NaOH O-Other (detail In comments) Note: All samples submitted to ENCO Labs are in accordance with the terms and conditions listed on the reverse of this form, unless prior written agreements exist Sample Preservation Verification ENCO Cary Work Order: CR08876 Project: Monthly - SBM Client: Novozymes North America'(NO008) Project;f: [none] Logged In-.- 03-JUI-I 8 12.40- Logged By: Rachel Ann, Y.ni h_ Preservation Check Performed By: 136terrime: ZOO CB08876-01 P Y, ' R i" equ rjo P A 250mLP+H2Sb47___'----- <2 OY N NA NA buf Reagent Name ID Reaqent Name ID_ Readent Name ID cyy7 3 -5 2 41- ra pH Strip ID: PH Strips C7.10820 yi C:\elmnt\PrfiILI..,I. Page 1 of 1 E NCO Laboratones, Accurate. Timely% Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: - 919.467.3090 FAX: 919.467.3515 Friday, July 13, 2018 Novozymes North America (N0008) Attn: -Scott Creech - - _ -_- - 7-7-Perry Chapel Church Road -.- - - - Franklinton, NC 27525 RE: Laboratory Results for Project Number: [none], Project Name/Desc: Monthly - Week One - SBM ENCO Workorder(s): CB08878 - Dear Scott Creech, _ Enclosed is a copy of your laboratory report for test samples received by our laboratory on Tuesday, July 3, 2018.. Unless otherwise noted in an attached project narrative, all samples were received in -_ acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. _ This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary: Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, i 1 Chuck Smith Project Manager ( Enclosure(s) :.- FINAL This report relates only to the sample as received by the laboratory, -and may only be reproduced in'full.. Page 1 of 12 (9 �60 www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: SBM _ _ _ _ _ _ _Lab ID:_ _CB08878-03 Sampled: 07/03/18 08:00 Received: 07/03/18 30:10 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) CSU Method NO PREP 03/28/21 07/05/18 08:53 07/12/18 16:19 EPA 350.1 NO PREP 07/31/18 07/10/18 10:28 07/10/18 10:28 EPA 351.2 Same 07/31/18 07/06/18 11:26 07/09/18 12:18 EPA 353.2 NO PREP 07/05/18 08:00 07/03/18 17:35 07/03/18 17:35 EPA 353.2 NO PREP 03/28/21 07/09/18 14:59 07/09/18 15:09 EPA 365.4 Same 07/31/18 07/06/18 11:26 07/09/18 13:57 EPA 6010D EPA 3005A - -- 12/30/18- — 07/05/18 08:53 07/12/18 11:20 EPA 7470A EPA 7470A 07/31/18 07/05/18 12:13 07/06/18 15:14 SM 2540B-1997 NO PREP 07/10/18 07/05/18 11:37 07/05/18 11:37 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 2 of 12 e wwW.encolabs.com SAMPLE DETECTION SUMMARY Client ID: SBM Lab ID: CB08878-01 Analyte Results floss mm - - - - P-QL Units Method Notes Aluminum - Total 129 0.420 1.00 mg/L EPA 6010D Ammonia as N 110 4*5 30 mg/L EPA 350.1 Calcium - Total 2010 0.390 1.00 mg/L EPA 6010D' --- Copper - Total 0.205 B 0.0160 0.100 mg/L EPA 6010D Magnesium - Total 25.7 0.290 1.00 mg/L EPA 6010D Nickel- Total 0.0-469 _ 1 0.0220 0.100 mg/L EPA 6010D Nitrate as N 19 0.025 0.10 mg/L EPA 353.2 Nitrite as N 0.13 0.017 0.10 mg/L EPA 353.2 Phosphorus — — 480 D- -- 30--- 40 mg/L EPA 365.4 Potassium - Total 537 1.50 5.00 mg/L EPA 6010D Sodium - Total-- -- _ _. , _ ` _ -- -- .. , -- - -- _ _ _161- 4.00 - _ 5.9 mg/�_ Sodium Adsorption Ratio 0.977 [blank] CSU Method Total Kjeldahl Nitrogen 1600 D 52 96 mg/L EPA 351.2 Total Solids 3.9 0.25 0.25 % by Volume SM 2540B-1997 Zinc- Total 0.354 0.0440 0.100 mg/L EPA 6010D -- - - - FINAL _ This report relates only to the sample as received by the laboratory, and may only be reproduced in.full. - - Page 3 of 12 - - - www.pndolabs.00m 7 1 ANALYTICAL RESULTS Description: SBM Lab Sample ID:CB08878-01 Received: 07/03/18 10:10 Matrix: Sludge Sampled:07/03/18 08:00 Work Order: CB08878 Project: Monthly - Week One - SBM Sampled By: Elbert Alston - Metals by EPA 6000/7000 Series Methods - ^ - ENCO Cary certified analyte [NC 5911 Analyte IcAS Numberl Results Flag Units DF DLD1 P 1 Batch Method na ed Notes Mercury [7439-97-6]^ 0.000150 U mg/L 1 0.000150 0.000200 8GO5025 EPA 7470A 07/06/18 15:14 NMN _ - - Metals (total recoverable) by EPA 6000/7000 Series Methods f ^ - ENCO Cary cert fled analyte [NC 5911 1 Analyte rCAS Numberl - Results flag . _Units: P-E MU p$6 _ -Batch - Method Analyzed Notes ... Aluminum [7429-90-5]^ 129 mg/L 10 0.420 1.00 8G05011 EPA 6010D 07/12/18 11:20 JDH Arsenic[7440-38-2]^ 0.0760 U mg/L 10 0.0760 0.100 8605011 EPA 6010D 07/12/18 11:20 JDH Cadmium [7440-43-9]^ 0.00360 U mg/L 10 0.00360 0.0100 8G05011 EPA 6010D 07/12/18 11:20, JDH Calcium [7440-70-2]^ 2010 mg/L 10 0.390 1.00 8G05011 EPA 6010D 07/12/18 11:20 JDH Copper[7440-50-8]^ 0.205 B mg/L 10 0.0160 0.100 8GO5011 EPA 6010D 07/12/18 11:20 JDH Lead [7439-92-1]^ 0.0310 U mg/L 10 0.0310 0.100 8GO5011 EPA 6010D 07/12/18 11:20 JDH Magnesium [7439-95-4]^ 25.7 mg/L 10 0.290 1.00 8GO5011 EPA'6010D 07/12/18 11:20 JDH Molybdenum [7439-98-7]^ 0.0250 U mg/L 10 0.0250 0.100 8G05011 EPA 6010D 07/12/18 11:20 - JDH T Nickel[7440-02-0]^ Potassium [7440-09-7]^ 0.0469 537 J mg/L mg/L 10 10 0.0220 1.50 0.100 _ 5.00'- 8GO5011 8GO5011 EPA 6010D - EPA 6010D 07/12/18 11:20 07/12/18 11:20' JDH - - . 'JDH Selenium [7782-49-2]^ 0.0620' U mg/L' 10 0.0620 0.100" 8GO5011 EPA 6010D '07/12/18 11:20 'JDH Sodium [7440-23-5]^ 161 mg/L 10 4.00 5.00 8GO5011 EPA 6010D - 07/12/18 11:20 JDH Zinc[7440-66-6]^ 0.354 mg/L 10 0.0440 0.100 8G0501'1 ". EPA 6010D 07/12/18 11:20 JDH Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 5911 Analyte rCAS Numberl Results Flag Units DF MDL PPOL Batch Method Analyzed Notes Ammonia as N [7664-41-7]^ 110 mg/L 100 4.5 10 8G10004 EPA 350.1 07/10/18 10:28 JU i Nitrate as N [14797-55-B]^ 19 mg/L 1 0.025 0.10 8G09024 EPA 353.2 07/09/18 15:09 JU Nitrite as N [34797-65-0]^ 0.13 mg/L 1 0.017 0.10 8G03007 EPA 353.2 07/03/18 17:35 JLI Phosphorus [7723-14-0]^ 480 D mg/L 400 10' 40 8G06002 EPA 365.4 07/09/18 13:57 JU 1 Sodium Adsorption Ratio 0.977 [blank] 1 8GO5011 CSU Method 07/12/18 16:19 JDH Total Kjeldahl Nitrogen^ 1600 D mg/L 200 52 96 8G06001 EPA 351.2 07/09/18 12:18 JLI Total Solids^ 3.9 % by Volume 50 0.25 0.25 8G05006 SM 254OB-1997 07/03/18 11:37 OMR FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I . vrwub.encolabs.corn • QUALITY- CONTROL -DATA Metals by EPA6000/-7000 Series -Methods. --Quality Control -=------ - Batch 8G06 025 - EPA 245.1 __ Blank (8G05025-BLK1)' Prepared: 07/05/2018 12:13 Analyzed: 07/06/2018 14:55 Spike Source %REC ROD get= - Fla -a" -P-QL -; Units - - ' Level - ` Result ' %REC Limits RPD LiID15 Notes Mercury, 0.000150 U 0.000200. mg/L LCS (8G05025-BS1) Prepared: 07/05/2018 12:13 Analyzed: 07/06/2018 14:59 Spike Source %REC RPD _AnalYte-_ - __- - _ Re51dt--=-Elan_ P_QL- 11�--- -Level•-- -=B€�Slll "/oREC__. Limits--RP_D. - .Notes - LIBILL - -:_ _-- - - '" Mercury 0.00554 .0.000200 mg/L 0.00500 111 80420 Matrix Spike (SG05025-MSI) Prepared: 07/05/2018 12:13 Analyzed: 07/06/2018 15:03 Source: CB10084-01 Spike Source . %REC RPD Anal vte Result Elan RQL, Units. Level Result %REC Limits, RPD Li01it Notes Mercury 0.00542 0:000200 mg/L 0.00500 0.000150 U - 108 _ 75-125- _ Matrix Spike Dup (SG0502S-MSD1) Prepared: 07/05/2018 12:13 Analyzed: 07/06/2018 15:06 Source: CB10084-01, Spike Source %REC RPD Analvte. Result Elan PSl1. - Units Level Result. %REC Limits RPD !!Bill: 'Notes - Mercury 0.00531 0.000200 mg/L 0.00500 0.000150 U ' 106 75-125 2 25 Post Spike (8G05025-PS1) Prepared: 07/05/2018 12:13 Analyzed: 07/06/2018 15:09 Source: CB10084-01 Spike Source %REC RPD -Analvte Result ElaA PM !bits:. Level Result %REC Limits RPD Lim Notes Mercury 6.73 0.200 ,' ug/L 5.00-0.0800135 757125 QM-08 Metals (total recoverable).by EPA 6000/7000.Series Methods -Quality Control Batch BGO5011- EPA 3005A Blank (8G05011-BLK3) Prepared: 07/05/2018 08:53 Analyzed: 07/12/2018 10:56 Spike Source. %REC RPD Anal Ytg Result Flan POL Units Level: Result.' %REC 610]Lt RPD Lin1(t Notes ' Aluminum 0.0420 U 0.100 mg/L Arsenic 0.00760 U 0:0100 mg/L Cadmium 6.000360 U 0.00100 mg/L Calcium 0.0390 U 0.160 mg/L Copper 0.00265 3 0.0100 mg/L , Lead 0.00310 U. 0.0100 mg/L Magnesium 0.0290 U 0.100 mg/L Molybdenum 0.00250 U 0.0100 mg/L Nickel 0.00220 U 0.0100 mg/L Potassium 0.150 U' 0.500 mg/L Selenium , 0.00620 U, 0.0100 mg/L Sodium 0.400 U 0.500 mg/L Zinc 0.00440 U 0.0100 mg/L LCS (B113105011-BSI) Prepared: 07/05/2018 08:53 Analyzed: 07/12/2018 11:02 Spike Source' %REC RPD Analyte Result Elm PQL !bits Level Result %REC Limits RPD LIBI t Notes Aluminum 2.23 0.100 mg/L 2.00 112 80-120 Arsenic 0.213 0.0100 mg/L. 0.200 106 'BO-120, FINAL -This report relates onlyto:the sample as received by the laboratory, and may only be reproduced in full. Page 5 of 12 '- www.encolabs.com -- ---- - - QUALITY- CONTROL- DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 8G05011 - EPA 3005A - Continued LCS (SG05011-BSI) Continued Prepared: 07/05/2018 06:53 Analyzed: 07/12/2018 11:02 Spike Source- °/oREC RPD Analyte Resin Ela9 :. P91 Units Level Result ' a/oREC Limits RPD Notes Cadmium 0.0223 0.00100 mg/L 0.0200 112 80-120 Calcium, T _ 2.28-_-0.100T-_ mg/L -_ 2.00 114 80-120 -Copper- _ _ . -:.-_ ___. _ _ -__ --- = 0.2-16- --- B-_- _ - - _ - - :0.0100 mg/L-- 0.200 • - `' - - ..:' 108- ---_ _80-120_-: - - - Lead 0.211, 0.0100 mg/L-106 - 80-120 { 2.19.__ 0.100 __ . mg/L _ -2.00-, _. _ _ -110_ _ . -_80-120 Molybdenum .0.218 0.0100 mg/L 0.200 109 80-120- Nickel 0.228 0.0100 mg/L 0.200 114 80-120 Potassium 10.8 0.500 mg/L 10.0 108 80-120 Selenium 0.219 0.0100 mg/L 6.200 116 80-120 Sodium 11.1 0.500 mg/L 10.0 ill 80-120 Zinc 0.221 0.0100 mg/L 0.200 Ill 80-120 - Matrix Spike (8605011-MS1) Prepared: 07/05/2018 08:53 Analyzed: 07/12/2018 11:05 Source: CB09366-01 --- - - - - - Spike Source °/oREC RPD 9naLtRe _ . -- _ _-_ _ Besitlt- - _Elas_- PQJ - - -Units Level Result a/aREC Limits RPD Limit Notes - - Aluminum _ -_ _--_ 2:21-= - =- -0.100__.___ mg/L- 2.00 0.0510 108 75-125 Arsenic 0.212 0.0100 mg/L 0.200 0.00760 U 106 75-125 Cadmium 0.0219 0.00100 mg/L" 0.0200 6.000360 U 110 75-125 Calcium ' 42.5 0.100 mg/L 2.00 39.5 - ' 152 75-125, QM-07 Copper 0.221 B 0.6100 mg/L 0.200- 0.00160 U 110 75-125 Lead 0.205 0.0100 mg/L 0.200. 0.00310 U 102 75-125 Magnesium 23.7 0.100. m L _ 9/ 2.00 21.6 1 06 - 75 125 Molybdenum 0.223 0.0100 mg/L 0.200 0.00250 U 111 75-125 Nickel 0.220 0.0100 mg/L 0.200 0.00220 U 110 75-125 Potassium 43.7 0.500 mg/L 10.0 34.1 96 75-125 Selenium 0.2240.0100 mg/L 0.200 0.00620 U 112- 75-125 Sodium 261 0.500 mg/L 10.0 254 65 75-125 QM-07 Zinc 0.225 0.0100 mg/L 0.200 0.00440 U 113 75-125 Matrix Spike Dup (8G05011-MSD1) Prepared: 07/05/2018 68:53 Analyzed: 07/12/2018 11:08 Source: CB09366-01 Spike Source. '/oREC RPD - -Analyte Result .Flan. PM Units Level .- a/oREC Lj(ni6 RPD CIS Aluminum 2.23 0.100 mg/L, 2.00 - - 0.0510 - __109 75-125 - - --0.8 20 Arsenic 0.215 0.0100 mg/L 0.200 0.00760 U ' .107 75-125 1 20 Cadmium 0.0221 0.00100' mg/L '. 0.0200 0.000360 U 111 75-125 0.7. 20 Calcium 41.7 0.100 mg/L 2.00 39.5 .. 109 75-125 2 20' Copper 0.220 B 0.0100 mg/L 0.200 „• 0.00160 U 110 75-125 0.5 20 Lead 0.209 0.0100 mg/L 0.200 0.00310 U 105 75-125 ,. 2 Magnesium 24.0 0.100 mg/L 2.00 21.6 123 75-125 1 20. " Molybdenum 0.223 0.0100, mg/L, 0.200 0:00250 U '111' 75-125, 0.04 Nickel 0.218 0.0100 mg/L 0.200 0.00220 U " ,109. 75-125 0.6 20 ' Potassium 414 0.500 mg/L 10.0 34:1 93 75-125 0.7. 20 Selenium 0.230 0.0100 mg/L 0.200 0.00620 U _ 115 .75-125 _-2.: :- 20 Sodium 266 0.500 mg/L 10.0 254 112 75-125 2 '_ 20' Zinc 0.222 0.0100 mg/L 0.200 0.00440 U ill 75-125 , 1', „20 Notes . I FINAL c _ _ ----This report relates only .to.the sample as received by.tlie laboratory, and may only -be reproduced in full. _.:_Page 6 of 12 J- �eo www.encolabs.wm_ _ QUALITY -CONTROL DATA Metals (total recoverable).by EPA 6000/7000 Series Methods - Quality Control Batch 8G05011- EPA 3005A - COkilnued - --- - Post Spike (8605011-PSl) Prepared: 07/05/2018 08:53 Analyzed: 07/12/2018 11:10 _ Source: CB09366-01 Spike Source ---- %REC RPD �naltds Result Him- -' POl Units Level - Result %REC Limits RPD Limit : Notes_ Aluminum 2.34 0.100 mg/L 2.00 0.0510 115 80-120 Arsenic 0.218 0.0100 mg/L 0.200 -0.00341 109 80-120 _ - Cadmium 0.0225 0.00100 _ mg/L 0.0200 4.43E-6 112 80-120 Calcium 43.0 0.100 mg/L 2.00 39.5 173 80-120, QM-08 y Copper - 0.227 B 0.0100 mg/L 0.200 0.00127 113 80-120 - : - Lead ----_ -- - _ -: _ 0.211. _ - _ 0.0100 mg/L 0.200, -0.000470 105 80-120 I _ Magnesium 24.4 0.100 mg/L 2.00 21.6 144 80-120 • QM-08 Molybdenum 0.224 OA100 mg/L 0.200 0.000184 112 80-120 -_ Nickel 0.226 0.0100 mg/L 0.200 0.00156 112 80-120 Potassium 44.5 0.500 mg/L 10.0 34.1 104 80-120 Selenium 0.231 0.0100 mg/L 0.200 -0.00340 116 80-120' J Sodium 266 0.500, mg/L 10.0 254 115 80-120 _ _.. Zinc 0.229, 0.0100 mg/L 0.200 0.00272 113 80-120 Classical Chemistry Parameters - Quality Control Batch 8GO3007 - NO PREP Blank (8G03007-BLKS) Prepared: 07/03/2018 10:00 Analyzed: 07/03/2018 10:00 Spike Source %REC RPD Anal Result Elan POI. Units Level Result %REC Limits RPD Limit Notes Nitrite as N 0.017 U 0.10 mg/L y FEES (SG03007-BSI) Prepared: 07/03/2018 09:51 Analyzed: 07/03/2018 09:51 Spike Source %REC RPD AnalYte Result Elm POL - Units Level Result %REC Limits RPD Limit Notes Nitrite as N 0.98 0.10 mg/L 1.00 98 90-110 LCS (811303007-B52) Prepared: 07/03/2018 17:44 Analyzed: 07/03/2018 17:44 Spike Source %REC RPD ` Anal Y1b' Result Elan PM units Level Result %REC Limits RPD Limit Notes Nitrite as N 0.98 0.10 mg/L 1.00 98 90-110 Matrix Spike (8G03007-MSI) Prepared: 07/03/2018 10:01 Analyzed: 07/03/2018 10:01 Source: C809451-01 Spike Source %REC RPD Anal Result Flaa PQL Units Level Result %REC Limits RPD Limit Notes.• Nitrite as N 0.88 - - _ 0.10. mg/L 1.00 0.017 U 88 90-110 QM-07 Matrix Spike (8G03007-MS2) Prepared: 07/03/2018 17:22 Analyzed: 07/93/2018 17:22 Source: CB10084-01 Spike Source %REC RPD Anal ttte Result Elan POL units Level ggsult %REC Limits RPD' Limit Notes Nitrite as N 0.90 0.10 mg/L 1.00 0.017 U 90 90-110 Matrix Spike Dup (8Gb3007-MSD1) Prepared: 07/03/2018 10:02 Analyzed: 07/03/2018 10:02 Source: CB09451-01 Spike Source %REC RPD Anal Yte Result Elaa POL Units Level Result %REC Limits RPD Limit Notes Nitrite as N " 0.88 0.10 mg/L 1.00 0.017 U 88 90-110 0.7 . , 10 QM-07 Batch 8605006 - NO PREP FINAL This report relates only.tuthe•sample as received by the laboratory, and may only be reproduced In full.. - - Page 7 of 12 _ �J'�lCO www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Blank (8G05006-BLKi) Prepared & Analyzed: 07/05/2018 11:37 Spike Source %REC RPD J 9nalvte Result Elm PQL units Level Result' %REC Limits RPD Limit Notes U —.Total Solids 0.0050 U 0.0050 % by Volume LCS (8G05006-BSi) Prepared & Analyzed: 07/05/2018 11:37 ' _ Spike Source %REC RPD 9[IaL13esult : Ills' P91 Units Level Result %REC Limits RPD Notes Total Solids 1000 50 mg/L 1100 93. 80-120 Duplicate (8G05006-DUPS) Prepared & Analyzed: 07/05/2018 11:37 Source:, CB08877-01 Spike Source %REC RPD Analvte Result _Flat POL Units Level Result %REC Limits RPD Limit Notes Total Solids 0.26 0.0050 % by Volume 0.25 0.3 20 Batch 8G05011- EPA 3005A _ Blank (8G05011-BLK3) Prepared: 07/05/2018 08:53 Analyzed: 07/12/2018 16:20 Spike Source %REC RPD Anal vte Result Elan , _ P41. Units ,Level Result %REC Limits RPD Limit Notes Sodium Adsorption Ratio 0.00 _ U [blank] Batch 8G05022 - NO PREP LCS (SG05022-BS1) Prepared: 07/05/2018 12:57 Analyzed: 07/05/2018 12:57 Spike Source %REC RPD Anal a Result EI14 00L Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 1.3 0.10 mg/L 1.25 107 90-110 Matrix Spike (SG05022-MS1) Prepared: 07/05/2018 13:01 Analyzed: 07/05/2018 13:01 _ Source: CB08417-03 Spike Source %REC RPD 9nlLYtQ Resul Sias PQL Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 1.8 0.10 mg/L 0.521 1.2 129 ' 90-110 QM-07 Matrix Spike (8G05022-MS2) Prepared: 07/05/2018 13:10 Analyzed: 07/05/2018 13:10 Source: CB06907-01 Spike Source %REC RPD Anaiyte Result Elan PQL Units Level Rgail* %REC Limits RPD Limit Notes Nitrate/Nitrite as N 0.80 0.10 mg/L 0.521 0.19 .117 , 90-110 QM-07 Matrix Spike Dup (811305022-11WISM) Prepared: 07/05/2018 13:03 Analyzed: 07/05/2018 13:03 Source: CB08417-03 Spike Source %REC RPD Anal tdg Result. Elan PUL Units Level Result %REC Limits. RPD Limit Notes Nitrate/Nitrite as N 1.8 0.10 mg/L 0.521 1.2 120 90-110 3 10 QM-07 Batch 8606001- Same Blank (8G06001-BLKi) Prepared: 07/66/2018 11:26 Analyzed: 07/09/2018 11:47 Spike Source %REC RPD Anal YIk Result Ella PQL Units Level Result %REC Limits RPD Limi Notes Total Kjeldahl Nitrogen " 0.26 U 0.48 mg/L I i -; - - FINAL - • ". - This report relates only to the sample as received by the laboratory, and may only. be reproduced in full. - - _ .. Page 8 4 12 - www.endolabs.com QUALITY CONTROL DATA Classical Chemistry_ Parameters - Quality Control Batch 8GO6001 - Same - Continued LCS (8G06001-BS1) Prepared: 07/06/2018 11:26 Analyzed: 07/09/2018 11:49 - Spike Source %REC RPD Result - _Flao - pQI---Units -_-.-.Level - : -- `-Resul%REC—Limits- -RPD---],!mR- t-` '__ Notes - ----- - Total Kjeldahl Nitrogen 12 0.48 mg/L 12.0 100 90-110 ` Matrix Spike (SG06001-MS1) • Prepared: 07/06/2018 11:26 Analyzed: 07/09/2018 11:53 Source: CB06952-02 - - f Spike Source °/aREC RPD _ - Analvte.._ --_ _- .__.. _ Result . .Flans -P-Q:-- :-Units- _ --Level---- - Result ---9/oREC _[units_ --RPD _ -Limit ._. -Notes - --:=- Total Kjeldahl Nitrogen 5.3 0.48 mg/L 4.80- -0.70 ' 96 90-110 Matrix Spike (BG06001-MS2) Prepared: 07/66/2018 11:26 Analyzed: 07/09/2018 11:58 Source: CB07933, 01 Spike Source %REC RPD Ana[ Result Flag POL Units Level R sul %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 5.8 0.48 mg/L 4.80 0.74 106. 90-110 - Matrix Spike Dup (SG06001=MSD3)' _ _ - 'Prepared:_ 07/06/2018 11:26'Analyzed: 07/09/2018 11:54 Source: CB06952-02 Spike Source %REC RPD Anal vte Result Fla4 P4L Units Level Result %REC, Limits RPD' Limit Notes Total Kjeldahl Nitrogen 5.4 0.48 mg/L 4.80 0.70 99 90-110 2 10 --I Batch 8G06002'-Same ! i Blank (811306002-BLKI) Prepared: 07/06/2018 11:26 Analyzed: 07/09/2018 13:45 Spike Source %REC RPD Anallte Result Elan PAL Units Level Result '/oREC Limits RPD Limit Notes Phosphorus 0.025 U 0.10 mg/L LCS (8G06002-1111SI) " Prepared: 07/06/2018 11:26 Analyzed: 07/09/2018 13:46 Spike Source %REC RPD Anal vte Result Elau Pl?L Units Level Result %REC Limits RPD Limit Notes Phosphorus 1.7 0.10 mg/L 1.60 - 104 80-120 Matrix Spike (8G06002-MS3) Prepared: 07/06/2018 11:26 Analyzed: 07/09/2018 13:49 Source: CB06952-02 Spike Source %REC RPD Anal vte Result Haa P-46 Units Level Result %REC Limits .RPD Limit Notes . Phosphorus 1.0 0.10 mg/L 0.640 0.34 104 80-120 Matrix Spike Dup (8G06002-MSD1) Prepared: 07/06/2018 11:26 Analyzed: 07/09/2018 13:50 Source: CB06952-02 Spike Source %REC RPD Anal vte Result Flaa PQL Units Level Result %REC - Limits RPD Limit Notes - Phosphorus 1.0 0.10 mg/L 0.640 .0.34 106 80-120 1 25 Batch 8610004 - NO PREP Blank (8G10004-BLK3) Prepared: 07/10/2018 10:24 Analyzed: 07/10/20i8 10:24 Spike Source ... -%REC _ RPD ' Anahibe 'Result Elan PAL Units Level gesulE %REC. Limits RPD . limit !Votes . Ammonia as N 0.045 U 0.10 mg/L - FINAL - --_ ..-- .-- __-, -. -This report relates only to the sample as received bythe_laboratory, and may onlybe reproduced in full.- --. • _- - - Page 9 of 12. EI�lCO www.encolabs.com QUALITY CONTROL DATA - Classical ChemistryParameters.- Quality_ Control_._-__ Batch BGI0004 -NO PREP -Continued LCS (8G10004-BSI) 'Prepared: 07/10/2018 10:26 Analyzed: 07/10/2018 10:26 Spike Source %REC RPD —"" Anal Yte Result Flan PGL Units Level Result' "/oREC Limits RPD Limit -Notes --- Ammonia as N 1.1 0.10 mg/L 1.00 108 90-110 Matrix Spike (8G10004-MSI) Prepared: 07/10/2018 10:29 Analyzed: 07/10/2018 1029 Source: CB08878-01 Spike Source %REC RPD Anande... _. Result Flan •- - - BQL _ .Units Level, Result %REC Limits RPD Limit .. Notes Ammonia as N 150 10 mg/L 40.0 110 106 90-110 Matrix Spike (81310004-11WIS2) Prepared: 07/10/2018 10:35 Analyzed: 07/10/2018 10:35 Source: CB08879-01 Spike Source %REC RPD Anal vte Result' Flag P9Jz Units Level Result %REC Limits RPD Limit Notes Ammonia as N 110 10 mg/L 40.0 62 129 90-110 QM-07 Matrix Spike Dup (8G30004-MSDI.) Prepared: 07/10/2018 10:31 Analyzed: 07/10/2018 10:31 Source: C808878-01 Spike Source %REC RPD Anal vts Result Flag P91. Units Level Result %REC ..Limits RPD limit Notes Ammonia as N 150 10 mg/L 40.0 110, 94 90-110 3 10 FINAL This report relates only to the sample as received by -the laboratory, and may only be reproduced in full. I www.encolabs.cwm" FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. - D The sample was analyzed at dilution. The reported value is between the laboratory method detection limit (MDQ and the laboratory method reporting limit (MRL), adjusted for actual sample preparation.data and moisture content, where applicable. - U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. _ E The concentration indicated for this analyte is an estimated value above the calibration range of the, instrument. This value is considered an estimate. MR_ L Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation.limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples,, moisture content. PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which_ there is presumptive evidence (85% or greater confidence) to make a "tentative :identification". P Greater than =25%concentration difference was observed Between the primary and secondary GC column: - The lower concentration is reported.." QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery.- QM-08 -Post-digestion spike did not meet method requirements due to confirmed matrix effects . (dilution test). FINAL This report relates'only to"the sample as received by the laboratory, and may only be reproduced in full. Page 1i of 12 ENVIRONMENTAL CONSERVATION LABORATORIES CHAIN -OF -CUSTODY RECORD w Ww.encolabs.corea 10775 Central Port Dr. 4810 Executive park Court, Suite t11 _ t02-A Woodwinds industrial CL ARM "Mmo- Orlando, FL 32824 - -Jacksonville; FL 32216-6069 Cary, UC 27511 - (407) 626-5314 Fax (407) e50-6945 - (a-04) 2?a'-3aC17 Fa4 (904129fi-E•2t0 - - (9191467-3090 FAX (919) 467-3515 Page Of Client Name Project Number - Requested Analyses RG'QUeSted Turnaround Novozymes North -America (N0008) [none] r� Times Addmss Project Namel0esc Q 77--Perry Chapel Ghureh Road tt�onth� �%Vt � Q(tQ - j� z it . C��t Note: Rush requests subject to City/ST/Zlp .. - .. PO fi! Billing (n�to 2 0 a y a lac N cceptanceb the iU 91 Frank6nton;" NC 27625 3800360807 = co rn. . Tei Fax Reporting Contact c ] . —Standard (919)-494-3000 Scott Creech r �' u �?- Expedited I�1CCCltintrs I�� BIS�e - -��,- ESampler{s}Nama,Arliatio (Pnt) ` � ,1. I - - L �.. Due ' a t-Sam l Site Location imZone c- /-CU J_ lib WDYkorder Preservation (See Codes) (Com6tna as neca sary) Collection Matrix Total S of — Item N Sampla ID (Field Identification) Ca)ieclion Dat Time Comp / Gmh (see codas) Coritama 3 Sample Comments SBM Sample tUt Prepared By DrttelTime - Relln ut e 113 on atners DateT ime Rece ved By . DateTme CommanisrSpecial Reporting Requirements Reliequish Da[a itme sec-" is I :- Da 7(i R_ inquished By Date/nme Received By Dateirme .. ... .. .. Cooler q's 8 Temps an Receipt 1 9' Condition Upon Receipt Matrix: GW-Gioun6mler'SO.SOII DNJ-Dnnkina Water SE-Sedimanr SW :4 idaro ` ' — v r io. vuweu.c.e �.e, n n,.., „ _._ x_ ___-__ _ _ _ __.. - _ . __ , _ ,._ __- _ _ _ _ _- _cheptable _Unacceptable ""' "_._..-._. ,,,,,,inert.,, r,r,m.�auurcrrce rrrn.r W-M)ZU6 an_sua RU-NaUR O-O)lter.(detailincomments) . Note: Alt sampres submitted to ENCO Laitsare in accordance vmn the lerms and candtions 11sted on the rnverse of this lorm,untess prior tvritterragreements exist Sample Preservation Verification Z_ ENCO Cary ............. ......... C. ............ Work Order: dB08878 Project Monthly -'Week One - SBM Client: 14ovo'Zymes North America (NO008) Project [none] ---Logged In __ 0 3-J_u PA 8 Logged By: :Rachel Ann Y h on�s Preservation Check Performed By: Daiteftme:l 5( IeY Z DO' ,CB08879-01 w .. . ..... .. 4ant. 'Prqvw "t" _00 3* C AM 0 iib A 250m_LP+H2SO4, <2 N /_ NA YIN I.NA -1 15 hT 8 1 250mLP+.HNO3 <2 "v'/ N 'I NA Y I _)/'NA' Reagent Name ID - Reagent Name, ID Reagent Name 10 .1 WSOLI _X?e0q0 3 .5 .2 4 pH Strip ID: PH Strips C7)0920' .:.Page-1 of 1 __J hora, -ories, FCO La Aloe rate.Timely. Respo"sine. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 - Phone: 919.467.3090 FAX: 919.467.3515 - i Thursday, August 16, 2018 Novozymes North America (N0008) Attn: Scott Creech - -r-----------7-7-Per Cha el-ChurchRoad -- f rY- - P - -- I Franklinton, NC 27525 RE: Laboratory Results for Project Number: [none], Project Name/Desc: Monthly - SBM ENCO Workorder(s): CB10719 Dear Scott Creech,. . Enclosed is a copy of your laboratory report for test samples received by our laboratory on Tuesday, August 7, 2018. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results forthese procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. l This report. contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO'Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. I� Sincerely, . Chuck Smith Project Manager - Enclosure(s) FINAL _ . _ _ - _This report relates only.to the sample as received by the laboratory, and may only be reproduced In full. -Page 1 of 8 N1 CE W) UUMMANNEMNIV www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: SBM - _ _ __Lab_ID:-_CB10719-01_ Sampled: 08/07/18 07:15 Received: 08/07/18 09:00 - Parameter Preparation Hold Date/Time(s) p Date/Time(s) Analysis Date/Timefs) SM 254OD-2011 NO PREP 08/14/18 08/09/18 07:21 08/09/18 07:21 SM 5210 B-2011 NO PREP 08/09/18 07:15 08/08/18 12:14 08/08/18 12:14 SM 5220D-2011 Same 09/04/18 08/13/18 10:48 08/13/18 13:29 FINAL ----This report relates only -to -the -sample as received by the laboratory, and may only be reproduced in full. Page 2 of 8 f www.encwlabs.com: SAMPLE DETECTION SUMMARY Client ID: SBM Lab3D: C810719-01 AnaNue Results fin MPS - - -EQL- Units Method - - - Notes Biochemical Oxygen Demand . 13000 2.0 2.0 mg/L SM 5210 B-2011 B-07 Chemical Oxygen Demand 34000 800 800 mg/L SM 5220D-2011 __- -Total Suspended Solids = r - -- 46000 - - r -- -2500- " ' ' ` -2500 -" 'mg/L- SM 2540D-2011 - - - - FINAL This report relates onlyto the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 8 . Et�lCC7 www.encolabs.com ANALYTICAL RESULTS Description: SBM Lab Sample ID:CB10719-01 Received: 08/07/18 09:00 Matrix: Sludge Sampled:08/07/18 07:15 Work Order: CB10719 _ Project: Monthly - SBM Sampled By:Adam Fauccette Classical Chemistry Parameters ^ - ENCO Cary certified anali to ANC 5911 Analyte rCAS Numbed Results Flaa Units DF MDL SL Batch Method Analyzed Notes Biochemical Oxygen DemandA ' 13600 mg/L 1 2.0 2.0 8HO8006 SM 5210 B-2011 08/08/18 12:14 JOC B-07 Chemical Oxygen DemandA 34000 mg/L 80, 800 800 8H13015 SM 522013-2011 08/13/18 13:29 JOC Total Suspended SolidsA - 46000 mg/L - 1000 2500 2500 8HO9001 SM 254OD-2011 -.-08109/18.07:21------LBG _ 1 i . I i FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. _ page 4 of 8 - T ' C� www.encolabs,com- ROL-DATA,-- Classical Chemistry Parameters - Quality. Control= y Batch 8H08006 - NO PREP - Blank (BH08006-BLRlj',_. __. __ __.___. ._-_ - _ .. _ -_ Prepared & Analyzed: 08/08/2018 12:14 _ Spike . Source %REC _ - - - - -_ -- _ — __ - _ ._ - --- Analvte- -:'.-_ _' Result= -F1as,- .- P46 = units Level Result = r %REC ):imits Biochemical Oxygen Demand, �.0, lJ 2.0 mg/L - LCS (SH08006-BSi)= Prepared &Analyzed: 08/98/20,18 12.14 - _ _ --- - - Spike Source, %REC RPD _._Anal- .. -:_.__---------..ResuB__ Elaa.:__ __P91:.. -_ Units -Level- Result -%REC- Limits.-- _''RPDLimM M WIL-- =- Biochemical Oxygen Demand - 160 . 2:0. mg/L 198 8385-115 B-07 ' Duplicate (8H08006-DUPl) Prepared & Analyzed: 08/08/2018 12:14 S96rce:CA09736-01 ; Spike.. Source' %REC ---RPD Anal yte iesult Elaq P� Units , Level Result %REC Limits RPD 'Limit Notes Biochemical Oxygen Demand 2.0 _ , ,- U 2.0. mg/L 2.0 U. _ _ _ _ __ 30'B-07 -Batch 8H09001 - NO -PREP - • --- . ; -- ._ Blank.(8H09001-BLKi), -- • -_ • - -- Prepared -& Analyzed: 08/09/2018-&:2l Spike Source %REC RPD- Anal Result • Elm PQL Units Level Result %REC Limits RPD Limit Notes Total Suspended Solids 2.5 U .: 2.5 mg/L LCS (BH09001-BSI) Prepared & Analyzed: 08/09/2018 07:21 Spike Source %REC RPD Analyte Result Etas PM Units Level Result %REC Limits RPD Limit Notes Total Suspended Solids' 94 2.5 mg/L 100 94 80-120 Duplicate (8H09001-DUPi) Prepared & Analyzed: 08/09/2018 07:21 Source: CB05635-01 ' Spike Source %REC RPD Analtite Result ' Elaa PQL .Units Level Result .. %REC Limits RPD , Limit Notes Total Suspended Solids. 330 50 mg/L 400 20 20 . Duplicate (8H09001-DUP2) Prepared & Analyzed: 08/09/2018 07:21 Source: _ C B 11225-01 Spike Source %REC RPD Anal t(te Result Elm. PQL - . .' Units Level Result. %REC . Limig ,RPD Limit .. Notes Total Suspended Solids . 25' .7.1' . mg/L 39' 44 20 QM-12 -• - -Batch 8H13015-Same - _ -• - : -- - - - -' - - - - ----- =-- -- - - '- -'---•. _. . -:- = Blank (BH13015-BLK1) 1, Prepared: 08/13/2018 10:48 Analyzed: 08/13/2018 13:29 Spike Source %REC RPD Anal ' Result Elul' PQL • Units Level %REC Result Limits RPD' limit ,' Notes - Chemical Oxygen -Demand = r =-' 10 U' ` -- 10- ; mg/L _ LCS (8H13015-BS1) Prepared: 08/13/2018 10:48 Analyzed: 08/13/2018 13:29 Spike Source %REC RPD AnalYte Result .. Ela ..' PQL Units . Level Result %REC. ' Llinit$ RPD . Limit. Motes . Chemical Oxygen'Demand 490 . .10, mg/L 500 98 ' 90_110 - — '_ . _ T FINAL - _`- '. • • -- _ This report relates only to the'sample as received by the laboratory, and may only be reproduced In full. = - - -- : Page 5 of-8 - - - - - www.encolabs.corh . QUALITY CONTROL DATA Classical Chemistry Parameters - Quality -Control Batch 8H13015 - Same - Continued Matrix Spike (8H13015-MS1) Prepared: 08/13/2018 10:48 Analyzed: 08/13/2018 13:29 Source: CB10719-01 Spike Source %REC RPD Anal vte . ' -- --Result _-- Flan _-- PDL - - Units Level Result "/oREC Limits RPD Jet Notes. Chemical Oxygen Demand 61000 800 mg/L 40000 34000 67 90-110 QM-07, .. . - Matrix Spike Dup(SH13015-MSD1-)-=--==-T=----____ __—_ ---. -.Prepared: 08/13/201810:48Analyzed: 08/13/2018-13:29 -- -- - ._ --- ----'Source:"CB10719=01'- - - -- - - - -_-- - --- � - - - - ----- -- ------------- - -- _._ _ __._ _ __��_.-r��_: -------- Spike Source %REC RPD AnaLytC _ _ _ _ _- =- -- - _-- = Result = Flan- - - POL- — --Units - - Level- Result 9/oREC .. RPD : - - ' 1U111si Limit- - � . -: Notes Chemical Oxygen Demand 62000 800 mg/L 40000 34000 69 90-110 1 10 QM-07 FINAL -- This report -relates only-tathe.sample as receivedbythe laboratory, and may only be reproduced in full. -• - - - -- - — Page 6 of 8 • I .- _ .. �=NC� wwvif.encolabs.com ' ''FLAGS/NOTES_AND_DEFINITIONS �_— ----- - S. The analyte was detected in -the associated- method blank. -- -- D The sample was.analyzed at'dilution. - - -' - }-The reported,value�is between -the -laboratory method -detection limit (MDL).and-the laboratory -method - reporting limit MRL ad usted,for actual sample re aration data -and -moisture content where a licable. - = U The analyte was'analyzed for but not detected to the level shown, adjusted for actual sample preparation data'and.moisture content, where applicable. . E • The concentration indicated for this analyte is -an estimated value -above the calibration range of the - instrument. This value is considered an, estimate. _MRL . Method Reporting Limit. The MRL is roughly equivalent.to the practical quantitation limit (PQL) and -is - -based on, the low, point of the calibration curve; when applicable, sample preparation factor, dilution----- -- --'-- -.- -- - -- --- factor, and, in the -ease of soil samples,, moisture content. j PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. - N '. . The analysis indicates the presence of_an-analyte for which there'is.presumptive, evidence.(85% or, -greater confidence) to make a "tentative: identification": P . Greater, than.25% concentration difference was observed between' the primaryand secondary GC column. The lower concentration is reported. B-07-• LCS exceeded control limits for this test.. The test can not•be-repeated due to method. constraints. The result should be considered'an estimated value. QM-07 The spike recovery'was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. QM-12 i Precision between duplicate samples was outside acceptance limits.. I. . - - - - - FINAL ' _-- This report relates'only to the sample as received by the laboratory, and may only be reproduced In full. ' - ` - ' - Page 7 of 8' - +.- - — ® �® :ioMceritrd Pert Dr.. 4810 Execufr.e Park.Cowt Suile-111 10?-A Woodwinds Industrial Ct.. Orlando, FL 32824 . - Jacksonville, FL=11"C6 Cary, NC 27511 (904) 29"007 (S 7-3515. (407) 89&5314 Fax (407) 850-69.45 Fax(904)266-6210. 10.) 467-3WO Fax (91ii)46 Page., of . Client Name. NOVOZYM'es North Arrioadca (NO008). Pro ect Number" - [none] . Requested Analyses RequestedTumaroUnd Ti mes ....... ...... Note' Rush requests subject to . acceptanceb y1hefacility 5tandard. .. ....... -.Rpedltbizl - :,Due I . LO N v Addreis 77-PerPj,Ghdpe[ Churbhftad' PrdIvictAameffiesc- --Monthly--�-SBIVI—. City/ST/Zip Franklinton, NC 27525 Pp # ailing into .-380036050t'- Tel (91-9) 490P00-- Fax Reporting C6ntact Scott Cree& . . . Sample �() NaTe, Affiliationp(p: 'nt) BA, C. ct Contact ... . ... M unts Payable Samplerls) Signature: Site Location I Time ZDne Lab Workorder. Preservatkm (See Codes) (Combine as necessary) Item 0 Sample ID (Field Identification) Collection Data - Collection TMM Comp I Grab Mahlx '(sec codes) TOO 4f of C=Iahars Sample Comments Sam - :--:8L- 3- "--.x -'X- :kl . . . . . . . . . . a.... .... 7 . % . 77777 7", 77 7,7 7 -v . . . . . . Total 4 of Contatfi&s ............ Sample Kit Prepared By ILJI fR wish -7-Ib Received By Datei Comments/Special-Roporing Requirements RPJ qistied y Dalarrms ReceftBy % ishgd B Relinquy Date rime Received w BY 'Date'rime. ool4me'I. ifl cblnaccCceipt Can n.elp Accapta Matirli: PW-Groundwatei, SO -Sad , DW-bririMpgMater 'SE -Sediment SW-Sudaci6 Water VVVY-Wastinater. A -Air 6-0ther (delay in comments) Preservation: JI-Ice H-HCl H7HNO3 S-H2SO4 NO-NaOH Q-01her(detail,incomments) -Note :All �samples sutsmiled toENCOLam are in accordance mfilkthe tams and conditions listed on the reverse of this form, uoless prior written agreements exist Sa.rhple.'PreservationfVerification ENCO Cary Work Order. CB10719 _ .Project: Monthly SBM Client: e Novorymes North America (N0008) Project #: (none] Logged In: 07-Aug-18 10:58 Preservation Check Performed By: Logged By: John C King Date/Time: 0 �p CB10719-01 Rea ent.Name . ID Rea ent Name 1 3 ID Reapent Name ID -2 5 4 pH Strip ID: C:IELMIVT1Printlwko_PreservationCheck.rpt . Page 1 of 1 i E-,Nv`C0-La,-bo. ratories-1; Accurate. Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090, FAX: - 919.467.3515- Wednesday, August 15, 2018 Novozymes North America (N0008) Attn: Scott Creech 77 Perry Chapel Church Road Franklinton, NC 27525 RE: Laboratory Results for Project Number: [none], Project Name/Desc: Monthly - Week One - SBM ENCO Workorder(s): CB10721 Dear'Scott Creech, Enclosed is a copy of your laboratory report for test samples received by our laboratory, on Tuesday, August 7, 2018. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for, these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of, the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. ,Unless otherwise noted,.all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Chuck Smith Project Manager Enclosure(s) FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 1 of 12 www.encolabs.com -- SAMP_LE_SUMMARY/LABORATORY CHRONICLE__-__ Client ID: SBM Lab ID: CB10721-01 Sampled: 08/07/18.07:15 Received: 08/07/18 09:00 - Parameter Prenaration Hold Date/Time(s) Preo Date/Time(s) - - Analysis Date/Time(s)' - - CSU Method' ' NO PREP- _ T =. - OS/02/21 - _ _ _ 08/08/18 .09:00 _, _ _ _ 08/13/16 14:59 EPA351.2 -Same- -=--_— . ---09/04/18-- ---= --.-- - - 08/08/18-- 11:23 = r -" 08/13/18 10:29 ' EPA 353:2 —NO-PREP - _ _ _ - 08/09/18 07:15 - 08/08/18 09:11 08/08/18 09i11 " EPA 353.2 NO -PREP - -- - - -- - -'=' = 05/02/21-- - -==--- 08/08/18 18:50 08/08/18 19:07 - EPA 365.4 Same 09/94/18 08/08/18 11:23 08/13/18 12:33 EPA 6010D EPA 3005A 02/03/19 08/08/18 .-09:00 08/13/18 12:32 EPA 7470A EPA 7470A -' " 09/04/18 - 08/13/18 12:09 08/14/18 14:28 SM 2540B=2011 NO -PREP-"--- - _ __ `08/14/18 '——`- -- 08/09/18 14:15 ' - 08/09/18 14:15 Client ID:. - SBM Lab ID: CB30721-01RE1 Sampled:' 08/07/18 07:15 Received:. 08/07/18 Parameter - Preoakation- --bold DateMme(s)- . -- - Prep Date/Time(s) - Analysis Date/Time(s) - EPA 350.1 'NO PREP 09/04/18 08/10/18 14:49 08/10/18 14:49 - -- rl- I _ FINAL ` ' " _ ' �_ This reportrelatesonly-to thesampleas-receivedby the laboratory, and may only be reproduced In full. T' - . _ - . Page 2 of 12 `.- - Ce �C.. -� www.encolabs,Cotn_ ---. = -- SAMPLE DETECTION SUMMARY ClientID: , SBM_ Lab ID:. CB10721-01 AOaIYLe -FLi4-.1LQt Aluminum - Total 291 0.420 1.00 mg/L EPA 6010D - Arsenic- Total 0.0901 3 0.0760 0.100 mg/L EPA 6010D ' Calcium = Total - 4930- 0.390 1.00 mg/L EPA 6010D _ Copper - Total ' _ - - 0.458 -0.0160 0.100 mg/L EPA 6010D Magnesium _ Total 68.8 0.290 1.00, mg/L EPA 6016D _ -Molybdenum = Total'—'------ " — ` - `--0.0434--- J — -0:0250--- -0-.100 -- --mg& ---EPA 6030D — - --�-- -Nickel--Total .. 0.0636. ] .' 0.0220. 0.100 mg/L EPA 6010D - Nitrite as N . 0.28 0.017 0.10 mg/L EPA 353.2 . Phosphorus 670' D 10 40 mg/L__--____---EPA365.4_ Potassium - Total 579 1.50 5.00 mg/L EPA 6010D Sodium -.Total , _ 143. 4.00 5.00, mg/L EPA 6010D ,.' - -- Sodium Adsorption Ratio.- ----- --_- -_- - _ _ - 0.554. -_ - - - _ - - - - -. - [blank] CSU Method- .- -. Total Kjeldahl Nitrogen 2100 D' 26 48 mg/L EPA 351.2 Total Solids 6.0 0.25 0:25 % by Volume SM 254OB-2011 Zinc -Total, 1.19 0.0440 0.100 mg/L EPA 6010D - Client ID: SBIM Lab ID: CB10721-OIRE1 Anal Results Eh9.:. ML6 P46 Units Method Notes Ammonia as N - 980 . D .40 - 90 mg/L EPA 350.1 - I ' - - _- -FINAL - • This report relates -only to the'sample as received by the laboratory, -and may only be reproduced in full: Page of 12 -' Ef�ICO - www.encolabs.com L . ANALYTICAL RESULTS . Description: SBM Lab Sample ID: CB10721-01 Received: 08/07/18 09:00 Matrix: Sludge Sampled:08/07/18 07:15 Work Order: CB10721 Project: Monthly - Week One - SBM Sampled'By:Adam Fauccette Metals by EPA 6000/.7000. Series Methods ^ c ENCO Cary certified analyze [NC 5911 �- Analyte rCAS Numberl Results flag Units _ DF MQL POL Batch Analyzed By Notes . Mercury[7439-97-6]^ 0.000750 U -' mg/L 5 0.000750 0.00100 8H13023 EPA 7470A -- 08/14/18-14:28. NMN Metals (total recoverable) by EPA 6000/7000 Series Methods' _ ^ - ENCO Cary certified anaiyte [NC 5911 AnalM [CAS Numberl Results Units RE Au- M h, Method Analyzed _gy Notes, Aluminum [7429-90-5]^ " - 291' mg/L 10 0.420 1.00 8HO8010 EPA 6010D 08/13/18.12:32 ]DH Arsenic[7440-38-2]^ 0.0901 J mg/L 10 0.0760 0.100 8HO8010 EPA 6010D. 08/13/18 12:32 JDH Cadmium [7440-43-9]^ 0.00360 U _ mg/L 10 0.00360, 0.0100 8HO8010 EPA 6010D 08/13/18 12:32 ]DIH ' Calcium [7440-70-2]^ 4930 mg/L 10 0:390 1.00 8HO8010 EPA 601013 08/13/18 12:32 JDH , Copper[7440-50-8]^ 0.458 mg/L 10 0.0160 0.100 8HO8010 EPA 6010D 08/1-3/18 12:32' JDH' Lead [7439-92-1]^ 0.0310 U mg/L 10, 0.0310 0.100 8HO8010 EPA 6010D 08/13/18 12:32 JDH Magnesium [7439-95-4]^ 68.8 mg/L 10 0.290 1.06 8HO8010 EPA 6010D 08/13/18 12:32 JDH Molybdenum [7439-98-7]^' -0.0434 3 mg/L .. 10 0.0250 6.100 8HO8010 EPA 6010D 08/13/18 12:32 JDH.- Nickel[7440-02-0]^ - 0.0636, ] mg/L 10 0.0220 0.100 8HOS010 EPA 6010D 08/13/18 12:32 JDH _ Potassium [7440-09-7]^ 579 mg/L 10 '• 1.50 5.00 8HO8010 - EPA 6010D 08/13/18 12:32 - JDH Selenium [7782-49-2]^ 0.0620 U mg/L 10 0.0620 . 0.100 BHO8010 EPA 6010D 08/13/18 12:32 JDH Sodium [7440-23-5]^ 143 mg/L -10 4.00 5.00 8HO8010 EPA 6010D. 08/13/18 12:32 JDH Zinc[7440-66-6]^ 1.19 - mg/L 10 '0.0446 0.100 BH08010 EPA 6010D 08/13/18 12:32 JDH Classical Chemistry Parameters ^ - ENCO Cary ceKifled analAe [NC 5911 Analvte fCAS Numberl Res is Flea Units PF MDL POL Batch Method Analyzedpy Notes Ammonia as N [7664-41-7]^ 980 D mg/L 900 40 90 8H10006 EPA 350.1 08/10/18 14:49 JLI Nitrate as N [14797-55-8]^ .' 0.025 U mg/L 1 0.025 0.10 BHO8056 EPA 353.2 08/08/18 19:07 JL1, Nitrite as N [14797-65-O]^ 0.28 mg/,L 1 0.017 0.10 8H07035 EPA 353.2 '08108/18 09:11 JU Phosphorus[7723-14-O]^ 670 D mg/L 400 30 40 8HO8005 EPA 365.4 68/13/18 12:33 23 Sodium Adsorption Ratio 0.554 [blank] 1 SH08010 CSU Method 08/13/18 14:59 JDH - Totai Kjeldahl Nitrogen^ 2100 D mg/L 100 26 48 8H08004 EPA 351.2 08/13/18 10:29 JU Total SOIidS^ 6.0' % by Volume 50 0.25 0.25 RHn9n1n SM 2S4nR-0n11 ORi09/1R 14.19 t1MR - k www.encolabs.com. - _ QUALITY CONTROL' DATA .. Metals byEPA 6000%7000 Series Methods..; Quality Control- s Batch 8H13023 - EPA 245.'1-:. - - Blank (8H33023-BLK3) Prepared:. 08/13/2018 12:09 Analyzed: 08/14/2018 13:59 - - - - -- -- Spike .' Source %REC RPD -� Anal Yte- -- :--------Result Flan-= P91__= 11e11�44--�-Level'-- -Bg�SIIS- %REC---IaINJ�- -RPD-__-LIBll1; -- --H4 - -'--. Mercury 0:000150 U 0.00020.0 _ mg/L - LCS (9H13023-8S1)' ` Prepared: 08/13%2018 12:09 Analyzed: 08/14/2018 14i02 - Spike Source_ %REC RPD . AnalVteL.- Result. _F13a _ PGL Units Level, '. Result-. :_%REC _Limits. RPD_ Limit . - Notes ... ... - Mercury 0.00522 0.000200 mg/L 0.00500 104 80420 - Matrix Spike (SH13023-MS7) Prepared: 08/13/2018 12:09 Analyzed: 08/14/2018 14:07 Source: CB11054,-03 . _ -. _ - • -' Spike- Source ._ %REC RPD _. Anal -Result • Plan POL Units. Level Resu t • %REC Limits RPD Limit Notes. Mercury - - -_ 0.00504 -0.000200' -- mg/L _ 0.00500 . 0.000150 U _ 101. __ 75-125 - Matrix Spike Dup (BH13023-MSD3)' ' -- - Prepared: 08/13/2018 12:09'Analyzed: 08/14/2018 44:09 Source: CB11054-03 Spike Source, %REC RPD JAmllfte Result _ Elaa, PAX Units level Result %RiEC Limits RPD Limit , • Notes Mercury 0.00539 0.000200 ,mg/L 0:00500 0.000150 U 108 75-125 7 25 Post Spike (8H13023-PS3) Prepared: 08/13/2018 12:09 Analyzed: 08/14/2018 14:11 Source: C811054-0.1 Spike Source %REC RPD Anal vte- -Result .. Flaw.. PM Units_. Level Result %REC Limits , RPD Limit Notes Mercury 6.25 0.200' : ug/L 5.00 0.0200 125 75-125 Metals (total recoverable) by EPA 6000/7000.Series Methods -.Quality Control Batch 8H08010 - EPA 3005A kBlank (8H08010-BLKi) Prepared: 08/08/2018 09:00 Analyzed: 08/13/2018.11:31 - - Spike Source. %REC RPD Anal Result Flag; P9L Units Level Result %REC Limits RPD Limit Notes _ Aluminum 0.0420 U 0.100 mg/L Arsenic . 0.00760' U 0.0100 • mg/L Cadmium 0.000360 U. .. . 0.00100 mg/L Calcium 0.0390 U 0.100 mg/L Copper 0.00160 U 0.0100 mg/L Lead 0.00310 U 0.0100 mg/L Magnesium .' 0.0290 • Ll . _ 0.100 mg/L Molybdenum. 0.0025.0 U 0.0100 mg/L Nickel 0.00220 U 0.0100 mg/L. -- Potassium ,. 0.150 U 0.500 mg/L Selenium 0.00620 U 0.0100 mg/L" Sodium 0.400 U 0.500 mg/L Zinc 0.00440 U 0.0100 mg/L LCS (SH08010-BS1) Prepared: 08/08/2618 09:00 Analyzed: 08/13/2018 11.26 Spike Source' %REC RPD - Ana( ... Result Flan' PQL Units Level Result %REC Limits RPD Limit Notes Aluminum 1.97 0.100 mg/L 2.00 99 80-120 Arsenic. .0.188 0.0100 . mg/L 0.200 94 80; 120_:. FINAL This report relates onlyto the sample as received"by the laboratory, and may only be reproduced in full. Page 5 of 12 -'- - www.endolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods -Quality Control Batch 8H08010„-.EPA 3005A - Continued MS (81-1108010-13SI) Continued _. _ __ _ Prepared: 08/08/2018 09:00 Analyzed: 08/13/2018 11:36 Spike Source %REC ROD Anal -- : -'`------- _- __ __ B4xulL-Flag -P91 _ UnJts-_ --Level - --Bg l� -- '/oREC ----)mitts-- .--RPD.' _ - . . -)jp -- - --Notes--- -- - Cadmium 0.0198 0.00100 mg/L 0.0200 ,. 99 80-120 Calcium -.'2.09--______-L_0.100___mg/L_ 2.00 104 ,-80-120 _ Copper -- - - -- - - - - - - 0.193 ---_ --0.0100 _ mg/L 0.200 - - 97 80-120 Lead 0.198 0.0100 mg/L 0.200, 99 80-120." Magnesium _ - - _ 2.01 = 1- 0.100 - mg/L - - 2:00 . 101 80=120 _ - Molybdenum - - - - -' _0.195- __ 0.0100-_--- m /L g 0. 200: - - ^' -- 98 -' ; - Nickel 0.202 0.0100 mg/L 0.200 101 80-120 Potassium 9.93• 0.500 mg/L 10.0 99 80-120 - Selenium 0.207 0.0100 'mg/L 0.200 104 80-120 - - - Sodium - __ _� 30.0== = - -_ - 0:500 _ =mg/L----- 10.0-- •- - - 100 80-120- Zinc 0.204 0.0100 mg/L 0.200 102 80-120 Matrix Spike (8H08010-MS1) Prepared: 08/08/2018 09:00 Analyzed: 08/13/2018 11:38 I Source: C009772-01 - - - = Spike Source .' %REC'- :RPD- Anal __^_^-.BeSBIt ----= Elan -- _ - hQl._-_ _ Units. _ _ _ Level Result %REC _ . Limits_ RPD ... bIQ11C- Notes 1 Aluminum 2.08 0.100 mg/L 2.00 0.0441 102 75-125 Arsenic 0.212 - - 0.0100 - mg/L 6.200 70.00760 U .106- 75-125 Cadmium 6.0204 0.00100 mg/L 0.0200 0.000360 U 102 75-125 ' Calcium 15.9 0.100 mg/L 2.00 13.8 104 75-125 Copper '0.205 0.0100 mg/L 0.200 0.00307 101 75-125 Lead -----•-:: - --- - 0.205 0.0100-,- - mg/L -. . 0.200 .0.00310 U . 103 - 75-125, Magnesium 5.13,' 0.100 mg/L 2'.00 3.07 103 75-125 Molybdenum 0.210 0.0100 mg/L 0.200 0.00250 U 105 75-125 ' Nickel 0.207 0.0100 mg/L 0.200 0.00220 U 103 757125 Potassium 20A 0.500 mg/L .10.0 9.80 103 75-125 Selenium' '0.213 0.0100 mg/L 0.200 O'.00620 U 106 75-125 ' Sodium 109 0.500 mg/L 10.0 99.2 94 75-125 _ Zinc 0.245 0.0100 mg/L 0.200. 0.0346 105 75-125 Matrix Spike Dup (81-1108010-MSD1) Prepared: 08/08/2018 09:00 Analyzed: 08/13/2018 11:41 Source: CB09772-01 . L Spike Source . _ :. %REC: RPD Analyte Result Flan P91 units Level Result' .%REC Limits RPD Notes - Aluminum 2.01 0.100 mg/L 2.60 0.0441 98 75-125 4 20 Arsenic 0.202. 0.0100 mg/L 0.200 0.00760 U 101. 75-125 5 20 L Cadmium _ -0.0195 = _ - 0.00100 : - - mg/L 0.0200 0.000360 U 98 75-125 4 20 Calcium 15.3 0.100 mg/L 2.00 13.8 78 75-125 3 20 r Copper 0.198 0.0100 mg/L 0.200 0.60307 ,• 98. 75-125 4 20 Lead 0.201 0.0100 mg/L 0.200' 0.00310 U ' 101 75-125:, 2 20 Magnesium _ 5.07 0.100 mg/L 2.00 3.07 1001, 75-125 1 20 Molybdenum - _ _ _. _-----0:205 ' --- - 0:0100 - mg/L 0.200 0.00250 U 102 75-125 3 20 'Nickel t, 0.199 0.0100 - mg/L 0.200 `' 0.00220 U ` " .100'. -' - 75-125 4 ' `` 20 Potassium 19.5 0.500 mg/L 50:0 9.80 97 75-12.5 3 20 Selenium - 0.215 -` ." 0.0100 mg/L 0.200 0.00620 U 107 75-125 0.8 , 20 - Sodium 106 0.500 mg/L 10.0 99.2 64 75=125 .3 - 20- QM-07 Zinc 0.235 0.0100 mg/L 0.200 0.0346., 100 75-125:, 4 20 . FINAL _ ___ -,This report relates only -to the sampleasreceived by the laboratory, and may onlybe reproduced in full. Page 6 of 12 _ V C . www.encolabs.com- - QUALITY CONTROL -DATA - Metals (total recoverable) by EPA 6000/7000 Series Methods_- Quality Control = - - - - - Batch 8H08010 __-EPA;3005A-- CdniffWed- Post Spike (8H08010-PSI) - Prepared: 08/08/2018 09:00 Analyzed: 08/13/2018 11:43 - - -Source; C009772-01 Spike Source %REC RPD -- - - Ana1 �Result -- Flaa- - - pQL--- - - --Units- ----Level- - ResulE ` %REC- --L!MitS - -RPD- - Limit--. Notes ---- Aluminum 1.96 0.100 mg/L 2.00 0.0441 96.. - 80-120 Arsenic - 0.204 _ 0.0100 mg/L 0.200 = __0.00599. _ 99 - _80-120 Cadmium 0.0193 0.00100 - mg/L_ 0.0200 3.25E-5 96 80-120 - Calcium 15.0 0.100 mg/L 2.00 13.8 .61 80-120QM-08 Copper 0.198. 0.0109 mg/L 0.200 0.00307 98 80-120 - - Lead - 0.201 0.0100 mg/L 0.200-0.00161 100. 80-120 Magnesium 4.91 0.100- mg/L 2.00 3.07 92 80-120 r Molybdenum 0.204 0.0100 mg/L 0.200 0.000214 102 80-120 Nickel 0.198 0.0100 mg/L 0.200 - 0.00144 98 80-120 'Potassium --- .19.1-- - --0.500 mg/L -10.0 9.80 93'- 80-120 Selenium Sodium 0.209 103 _ 0.0106 0.500 mg/L mg/L 0.200-0.00340 10.0 99.2 104 41 80-120 80-120 QM-OB - Zinc 0.233 0.0100 mg/L 0.200 0.0346 99 80-120 - Classical Chemistry Parameters - Quality Control Batch'8HO7O30 - NO PREP LCS (SH07030-BS1) Prepared: 08/07/2018 15:32 Analyzed: 08/07/2018 15:32 FI Spike Source %REC RPD Anal Resul Elan PQL- units Level Result %REC Limits RPD. Limit Notes Nitrate/Nitrite'as N "` 1.3 ` 0.40 mg/L 1.25 107 90-110 , Matrix Spike (81407030-MSI) Prepared: 08/07/2018 15:36 Analyzed: 08/07/2018 15:36 Source: C805035-02 Spike Source, %REC RPD' Anal Result _ 'Elas 'PQI, Units Level, Result %REC Limits RPD Limit'. Notes Nitrate/Nitrite as N 17 2.0 mg/L 10.0 6.6 101 90-110 Matrix Spike (SH07030-MS2) Prepared: 08/07/2018 15:45 Analyzed: 08/07/2018 15:45 Source: C809772-01. Spike Source %REC RPD' Anal Ytn Result .Flag P-QL Spnits Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 31 2.0 mg/L 10.0 22 95 90-110 Matrix Spike Dup (SH07030-MSDI) Prepared: 08/07/2018 15:38 Analyzed: 08/07/2018 15:38 Source: CB05635-02 -- - - _ -, - - - Spike - Source--- - - - •-- - %REC- _- _..,_ ---RPD ADalyte Result Elaa PQL Units Level Result %REC Limits RPD. Limit Notes Nitrate/Nitrite as N 26 . 2.0. mg/L 10:0 6.6 192 90-110 43 SO • QM-071 QM-11 Batch 8H07035 - NO PREP Blank (SH07035-BLKl) Prepared & Analyzed: 08/07/2018 18:03 Spike Source' a/oREC RPD . Anal lOe Result Elan PQL Units Level Result a/oREC Limits RPD LM Notes Nitrite as N - - 0.017 U 0.10 mg/L LCS (SH07035-BS1) Prepared: 08/07/2018 17,53 Analyzedi O8/07/2018 17:53 Analvte FINAL Spike Source %REC RPD Result Elan PQL Splits Level Result %REC Limits RPD Llm(t Notes This report relates only to the sample as received by the laboratory, and.niay only.be reproduced in full. Page 7 of 12 , www.encolabs.com QUALITY CONTROL DATA i Classical Chemistry Parameters - Quality Control Batch 8HO7035 - NO PREP --Continued - LCS (8H07035-BS3) Continued Prepared: 08/07/2018 17:53 Analyzed: 08/07/2018 17:53 Spike Source %REC ROD Analyze---, -- ` -_ - -Result _ —_EIaQ- --- FQL- _-- - -Units Level _%REC. -_-: RPD--- —Limit . Nitrite as N 0.97 0.10. mg/L 1.00 _ 97 90-110 _ LCS(BH07035-BS2) Prepared: 08/08/2018 09:08 Analyzed: 08/08/2018 09i08 Spike Source %REC RPD AnalYte._•Result -1 Flag.. P-QL •, .'.units Level Result _ %REC_ .Limits RPD Limit =_.. ',Notes- Nitrite as N 0.97 0.10 mg/L 1.00 - 97 90-110 Matrix Spike (8H07035-MSI) Prepared: 08/07/2018 18:06 Analyzed: 08/07/2018 18:06 F�I Source:CB11926-08 { J Spike Source %REC RPD Anal Result FJ-M POL Units Level Result %REC Limits RPD Limit Notes Nitrite as N 0.96 0.10 mg/L 1.00 0.019 94 90-110 Matrix Spike (8H07035-MS2) Prepared: 08/07/2018 18:09 Analyzed: 08/07/2018 18:09 u Source: CB11926-09 Spike Source %REC RPD Anal vSe Result Flag P91 Units Level Result, - %REC Limits RPD Limit . , Notes Nitrite as N 0.99 0.10 mg/L 1.00 0.034 96 90-110 j Matrix Spike Dup (8H07035-MSD1) Prepared: 08/07/2018 18:07 Analyzed: 08/07/2018 18:07 71, Source: CB11926-08 Spike , Source %REC RPD Anlllltti' Resin Ela-Q P91 - - .!!nits' ..,Level.-- Result %REC ,Limits RPD. Limi - . • Notes Nitrite as N 0.95 0.10 ' mg/L 1.00 0.019 93 90-110 1 10 Batch 8H08004 - Same Blank (8H08004-BLKI) -- - Prepared: 08/08/2018 11:23 Analyzed: 08/13/2018 10:14 Spike Source %REC RPDI Aoalyte Result ELM PQL Units Level Result %REC Limns RPD Limit Notes Total Kjeldahl Nitrogen 0.26 U 0.48 mg/L LCS (8H08004-BSI) Prepared: 08/08/2018 11:23 Analyzed: 08/13/2018 10:16 I Spike Source, %REC RPD' Anal Result ' . Elan PQL 'Units Level Result. %REC. Limits RPD' Limit Notes Total Kjeldahl Nitrogen 13 0.48 mg/L 12.0 .105 90-110 Matrix Spike (8H08004-MS1) Prepared: 08/08/2018 11:23 Analyzed: 08/13/2018 16:19 Source: CB05035-02 Spike Source %REC RPD Anal1Re Result Elea PGL Units Level Result %REC Limits RPb Lim1L, Notes Total Kjeldahl Nitrogen 6.0 0.48 mg/L 4.80 0.92105 90-110 Matrix Spike (BH08004-MS2) Prepared: 08/08/2018 1123 Analyzed: OB/13/2018 13:45 Source: CB10720-OiRE1 • LJ Spike. Source %REC RPD _ Anal Result Flag M , !!nits. Level Result %REC Limits RPD Lima Notes I Total Kjeldahl Nitrogen 190 b , 4.8 mg/L 4.80 200 NR 90-110 QM-67 Matrix Spike Dup (8H08004-MSD1) Prepared: 08/08/2018 11:23 Analyzed: 08/13/2018 10:21 . Source: CB05035-02 Spike Source %REC RPD Anal Yte Result Elan PQL !!nits Level Result %REC Limits RPD Limit, Notes `- - FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 8 of 12 i - - - co abs. wuvw.en I com. - QUALITY -CONTROL DATA Classical Chemist Parameters --Quality Control Batch 8H0800 — - - - 4 - Same - Continued Matrix Spike Dup (8H08004-MSD1) Continued Prepared:. 08/08/2018 11:23 Analyzed: 08/13/2018 10:21 'Source: CB05035-02 --- - Spike Source- -. -%REC - - RPD 9oahRg - -.--- - - - ----13e1t - --EIaA---1'41-- - !!nits. -—Leve1— --_ /oREC-_--- ' —-<- - B4�slIS --- ° - Total Kjeldahl Nitrogen - 6.4 0.48 mg/L 4.80 0.92 _ 114 . 90-110 . 7 _ 10 QM-07_ . Batch 8H08005, - Same i3lank(8H080(15-BLK1) Prepared: 08/08/201.811:23 Analyzed: 08/13/2018 12:24 -- - - - - - - - - — ----- Spike - Source... -_ -...%REC ., --- RPD, 9nahfta Result Ele_4 P9h Units Level Result ' %REC Linj(tili RPD- limit Notes Phosphorus 0.025 U 0.10 mg/L' LCS (8H08005-BS1)'.' Prepared: 08/0812018 11:23 Analyzed: 08/13/2018 12:25 Spike Source %REC RPD Anelvte - - Result Ran OQL Units Level - Result'.- %REC- .Limier 'RPD Limit Notes Phosphorus - 1.6 030 mg/L 1.60 - - 97 - - 80 120 Matrix Spike (8H08005-MSi) Prepared: 08/08/2018 11:23 Analyzed:-08/13/2018 12:28 ; Source: CB05035-02 Spike Source %REC RPD Anal Yte RResul Elao P4L Units Level Result %REC Limits . RPD Limit Notes .Phosphorus' 0.89 0.10 mg/L 0.640 0.23 103 80-120 Matrix Spike Dup (8H08005-MSD1) Prepared: 08/08/2018 11:23 Analyzed: 08/13/2018 12:29 Sources CB05035-02 Spike Source. %REC RPD Anal tde Result Elm P_QL Units Level Result %REC Limits RPD Limit Notes -Phosphorus - 0.87 0.10' mg/L 0.640- 0.23 99 80-120 3 25 Batch 8HO8010 - EPA 3005A Blank (81-108010-BLKl) Prepared: 08/08/2018 09:00 Analyzed: 08/13/2018 15:00 Spike Source %REC RPD Anallde Result Elan Pl?L Un tE Level Result 0%REC Limits RPD Limit Notes Sodium Adsorption Ratio 0.00 U [blank] Batch 8H00010 - NO PREP Blank (8H09010-BLK1) Prepared & Analyzed: 08/99/2018 1415 Spike Source %REC RPD Anal . Result Elan P9L Units Level Result %REC Limits RPD Limit Notes Total Solids 0.0050 U 0.0050 % by Volume LCS (8H09030-BSI) Prepared & Analyzed: 08/09/2018 14:15 Spike, , Source_ _ .. • %REC RPD '. Anal vtg Result Etas POI. Units Level Result %REC LimM RPD Limit Notes .Total Solids 1100 50 mg/L 1100 98' . . 80-120 Duplicate (8H09010-DUPi) Prepared 8i Analyzed: 08/09/2018 14:15 Source: CB10720-03 Spike Source: %REC RPD Anal Result Elm POL 'Units Level Result %REC Limits RPD Limit Notes Total Solids 0.49 0.010 % by Volume' 0.45 10 . 20 Batch, 8fi10006 - NO PREP FINAL - _ _ _ _ _ _ This report relates only to the sample as received by the laboratory, and may only be -reproduced in full.•_ _ __ _ Page 9 of 12 �Eo www.encolabs.com QUALITY CONTROL DATA — Classical Chemistry Parameters- Quality Control - Blank (81110006-BLKl) Prepared: 08/10/2018 10:53 Analyzed: 08/10/2018 10:53 - - - _ - Spike Source — %REC —1 RPD ' Anal lde Resul ELM P-OL Un < Level Result. %REC Limits RPD Limit- -' - Notes Ammonia as N 0.045 U 0.10 mg/L LCS (8H10006-BSI) Prepared: 08/10/2018 11:16.Analyzed: 08/10/2018 11:16 Spike Source . %REC_ _ RPD Analtite Result. Elm PU Units Level Result %REC. �(ts-. .RPD Limit ' ..' Notes ' Ammonia as N ' . 1.1 0.10 mg/L 1.00 109 90-110 " Matrix Spike(8H10006-MS1) Prepared: 08/10/2018 11:20 Analyzed: 08/10/2018 11:20 Source: CB07916-Oi Spike Source' %REC RPD Analvte Result ilea PQL Units Level: Result %REC Limits RPD Limit Notes Ammonia as N 0.65. 0.10 mig/L 0.389 0.40 64 90-110 QM-07- Matrix Spike (8H30006-MS2) Prepared: 08/10/2018 1128 Analyzed: 08/10/2018 11:28 j Source: CB07919-01 U Spike Source %REC RPD Anal vte Result %laa POL Units Level Result %REC . jests RPD kklfd Notes Ammonia as N kl 0.10" mg/L 0.389 0.68 .. - 99 .90-110 C Matrix Spike Dup (8H10006-MSDI) Prepared: 08/10/2018 11:22 Analyzed: 08/10/2018 11:22 U Source: CB07916-01 Spike. Source %REC RPD AnaLytC Result Elm PQL " Unite Level Resuls %REC Limits RPD Limit Notes Ammonia as N 2.1 E 0.10 mg/L 0.389 0.40 439 90-110 106 10 QM-07, QM-11 L1 FINAL This report relates only. to the sample as received by the laboratory, and may only be reproduced in full. 'Page 10 of 12 • 4 • _ wurwi.encolabs. m co --- - - GS/NOTE - - --. - FLAGS/NOTES S AND DEFINITIONS ,. L-, The analyte was detected in -the associated:m thod blank. D" . , The sample was analyzed at dilution..-.--- - ..----- --- - - - — - - .. - - - __,__-__The,reported value-is.between-the laboratory method_ detection limit_(MDL);and the, laboratory method, ::reporting:limit'(MRL)--adjusted-for-actual.-ample.oreparation.data and moisture -content; .where applicable:_:__---� - - --- -- - V • - The analyte-was analyzed for but not detected to the level shown,.adjusted for actual sample preparation data and. moisture content,.where applicable. - - E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This -value is considered an estimate..' MRL . Method Reporting Limit..The:MRL is. roughly_equivalent..to the practical quantitabon-limit (PQC). and is. -based on the low,point of. the calibration curve; when applicable, sample preparation factor, dilution, factor, and, in the case of soil samples, moisture content. PQL -PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL:. - N The analysis indicates the presence of an analyte for which there is presumptive evidence 85% or greater confidence)to make a"tentative identification"... -- — P ;Greater than 25%:concentration-difference was observed between=the-primary=artd secondary -GC column-'- - The lower concentration is reported. ' QM-07. • The spike recovery was outside acceptance limits, for the. MS and/or MSD.. The batch ,was accepted- based on, acceptable LCS recovery. QM-08 Post -digestion spike did not meet method requirements due to confirmed matrix effects (dilution test). QM-11 Precision between duplicate ;matrix spikes of the same sample was outside acceptance limits. ®� 10775 Central Port Ds• '—_-•-a�4810Executive Perk,Ccurt. Suife+111•-•a _•••'•••—• 102-A W oodivinds Industrial Ct.v °�tp°°"'■w■v+v.■•�.vo■ Orlando, FL BM4 Jacksonville, FL M16-6059 Cary, NC 27511 40 82 ( 7) 8 5314 Fax (4t17) 850.694s (904) 29B-3097 Fax (904) 296-n270 (919) 4S7•; I) Fax (919) 467-3515 . Page Of Client.Name Navozymes North'Amel>aca (NOOO�j . Project Number [none] Requested Analyses Requested Turnaround Ames Note :Rush requests subject to acceptance Dythe-facility _ St811d8id. . E )edited Due N CC .. UL v � �a � �. � `- o C p � O Z w CV � / Address 77 Perm chapel Church Road Projectname0eso Monthly-.VVeek One - SBll9 CirylST21p I ;fl Frankbnton, NC 27525 ' Tel fax -3.000 PO # I Billing into 3800360507 Reporting Contact Scott Creech Samplers) Name, Affiliation (Print) B31SContact Accounts Payable Sampler(s) Signature Site Location/ TimeZona. L"ab_Woi korder's .: . ., - - Preservation (See Codes)•(Combine as necessary). Item # _ Sample ID (Flald Identification) Collection Collect on Matrix Time Comp / Grab (see codes) Total s.. of Containers Sample Comments -Date p y y - y it X - - - - 1. � . it, < - - Total # of Conta)riers Sample Kit Prepared By Datum® evIf Comments/Special Reporting Requirements I Reli hed By Ilnq he Dame Datume Received By Rec d By VDale�l, 6o 7; at III Mail Retgtquished By L. Date/Time Received BY Datetrime Cooler. s&Temps onReceipt _ • Condition UU& Receipt-', " _Acceptable-' !Unacceptable l, Matrix'- GW-Groundwater SO -Soil DW-Drinking Water SE Sediment SMI-Surface Water Wilt -Waste water A -Air O-Otoer.(detell in comments) Preservation-.14ce H-HCI MHNO3 S-HPZ04 NO-NaOH O-Other (deta'sl in.comments) Note : AH samples submitted to ENCO Labs are in accordance with the terms and conditions listed on the reverse of this form, unless prior written agreements exist �; Saniple -Preserv.ation'Verification ENCO Ceiry Work Order: Z1310721. Project: Monthly - Week One, -,SBM Cli6nt: Novozym'e.s N6rth Amerita (N0008) [none] Project --Logged-E§Y7- -..-.---.-JOtln-C-King-:-f-- L 'd ln,:-'---07-Aug-1-8----11-,03- ogge Preservation th-eick"Peribrm e-d.By: DatefTime': -.CB10721-01 W "R IpH'-`C 16 0144 A 250mL.P+H2504 < 2 . Y IV /. NA Nr 'I NAA ZM4— Hzsoq B r 250MLP+H.NO3 <.2 Y / 0/ NA Y /(/ 'NA servg C:\ELMNT-\PrifitNwkb Pre -tionCheck-rpt' Page 4 ..fCO L 1-� the _ es"posve.e' Innovative. - -- - - - 102-A Woodwinds Industrial Court - -. - - - - - - - - - --- - - - Cary NC, 27511 Phone:- 919.467.3090 FAX: 919.467.3515 - - ` - - -- - - - --- - - - - - -- - - _.- ThursdayySeptember_13, 2018__-__ - - Novozymes North America (N0008). - - �._ Attn: Scott Creech = 77 Perry Chapel Church Road Franklinton, NC 27525 RE: Laboratory Results for Project Number: [none], Project Name/Desc: Monthly - SBM -, ENCO.Workorder(s): CB11658 Dear Scott Creech, Enclosed is a copy, of your laboratory report for test samples received by our laboratory on Tuesday, September 4, 2018. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the -project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report.contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If, you have any questions or require further information, please do not hesitate to contact me. Sincerely, Chuck Smith Project Manager Enclosure(s) FINAL ; - - This report relates only to the sample as received by the laboratory, and may -only -be reproduced in'full. Page 1 of 8 SAMPLE SUMMARY/LABORATORY CHRONICLE I Client -ID:- SBM - __ -____ — _-_—_ _ _ Lab=ID:_CB11658=01 Sample& 09/04/18 07,00 Received: 09/04/18 10:15 Parameter Preparation-- -- -- - - - Hold-Date%Timers) Prep Date/Timers) Analysis Date/Timers) SM 254013-2011 NO PREP — 09/11/18 09/05/18 16:40 09/05/18 16:40 SM 5210 B-2011 -NO PREP - --09/06/-18--07:00---- 09/05/18 11:47 - 09/05/18 11:47 SM 5220D-2011 Same _ - - _-_10/02/18 = _ - - 09/04/18 16:00 09/05/18 07:10 -FINAL ---- _�This7epdrt relates only -to -the sample .as.received by the laboratory, and may only be reproduced in full. - Page 2 of 8 www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: SBM Lab-ID:-CB31656 Ol. @Oaljdg Results Elm MDL M Units Method Notes Biochemical Oxygen Demand' 9200 2.0 2.0 mg/L SM 5210 B-2011 Chemical Oxygen Demand 27000 400 400 mg/L SM 5220D-2011 Total Suspended Solids 27000 2500 2500 mg/L SM 254OD-2011 FINAL -This report relates only to the sample as received by the laboratory, and may only be reproduced in full. - Page 3 of 8 EIVCO www.encolabs.com ANALYTICAL RESULTS Description: SBM Lab Sample ID: CB11658-01 Received: 09/04/18 10:15 Matrix: Sludge, Sampled:09/04/18 07:00 Work Order: CB11658 . Project: Monthly = SBM Sampled By: Client Classical Chemistry Parameters ^ - ENCO Cary certified analyte [Nc 5911 Analvte ICAS Numberl Resu - llaaq` Units ' DF MDL POL -Batch --Method' --Analvied- jay Notes Biochemical Oxygen Demand^ 9200 mg/L 1 2.0 2.0 8I05002 SM 5210 B-2011 09/05/18 11:47 ]OC Chemical Oxygen Demand^ 27000 mg/L 40 400 400 8I04034 SM 5220D-2011 09/05/18 07:10 10C Total Suspended Solids^ 27000 mg/L 1000 2500 2500 8I05006 SM 254OD-2011 09/05/18 16:40 OMR 1 1 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. page 4 of 8 Hi vifWW.encolabs.com — QUALITY CONTROL DATA Classical Chemistry Parameters - Quality -Control= - _- - - Batch 8104034-- Same - — - - Blank (8I04034-BLKi). - _ -.. Prepared:. 09/04/2018 16:00 Analyzed: 09/05/2018 07:10 Spike Source %REC RPD ___=- ---=- Anal ----.-=-----'.__—�___Rei6lt-�Flaa--PQI-- --Units— Level--- —Result-=—%REC---unit£- — RPD'----Limi -$4t4.£- -- — . Chemical Oxygen Demand- . - _-40 -U _ - ---M -mg/L-- --- -- LCS (6I04034-BS1) Prepared: 09/04/2618 16:00. Analyzed: 09/05/2018 0 :10 1 - -- Spike Source %REC RPD _ . Analvtg ' . -. Result Flag'- -' RQL . ... Units - ---Level _.Res_ ult... %REC- .'Limits RPD -- Limit - ---Notes - - Chemical Oxygen Demand 470 10 mg/L 500 93 90-110 ` Matrix Spike (8I04034-MS3) Prepared: 09/04/2018 16:00 Analyzed: 09/05/2018 07:10 ` Source: CB11044-01 Spike Source %REC RPD Analvte Result Fla4 ML Units Level gjgULt 0/aREC Limits RPD Limit Notes Chemical Oxygen Demand 590 10' mg/L 526 79 97 90-110 Matrix Spike Dup (8I04034-MSD3) Prepared: 09/04/2018 16:00 Analyzed: 09/05/2018 07:10 Source: CB11044701 Spike Source %REC RPD Analvte Resul Elan, P91 Unity Level Result', %REC. Limits RPD Limit Notes ' Chemical Oxygen Demand 590 10 mg/L 526 79 98 90-110 0.7 10 - Batch 8105002 - NO PREP Blank (8I05002-BLK1) Prepared & Analyzed: 09/05/2018 11:47 Spike Source %REC RPD Anal fdg Result Ela_4, PDL Units Level Result ' %REC Limits RPD Limit Notes -- Biochemical Oxygen Demand 2.0 U 2.0 mg/L LCS (8I05002-BS1) Prepared & Analyzed: 09/05/2018 11:47 Spike Source %REC RPD Anal Result Flag PQL Units Level Result %REC Limits RPD Limit Notes Biochemical Oxygen Demand 200 2.0 mg/L 198 100 85-115 Duplicate (8I05002-DUPl) Prepared & Analyzed: 09/05/2018 11:47 Source: CB11238-03 -- Spike Source %REC RPD Analltte Result Flan PM Units Level Result . %REC Limits RPD Limit Notes Biochemical Oxygen Demand 1300 .2.0 mg/L 1600 25 30 Batch 8105006 - NO PREP Blank (8I05006-BLKl) Prepared & Analyzed: 09/05/2018 16:40 Spike Source %REC RPD Anal Result E[m MX Units Level Result %REC Limit RPD Limit Notes Total Suspended Solids 2.5 U 2.5 mg/L LCS (8I05006-1111Sl) Prepared & Analyzed: 09/05/2018 16:40 Spike Source %REC RPD 9nallite Result Elan P_QL Units. Level Result . %REC Limits RPD Limit Notes Total Suspended Solids' 95 2.5 mg/L 100 95 80-120 i FINAL This report relates only to the sample as received by the laboratory, and may only. be reproduced in full. Page 5 of 8 �I i I L i - --- - -- - — -- www.encolab.s.com _ -QUALITY CONTROL DATA Classical=Chemistry-ParametersmQuality-Control_-�_-- - r--------Batch 8105006-NOPP.EP- Conffnued----------- — — T-- - -- -- ----- ----- --- --- - --- „ Prepared.&Analyzed: 09/05/201816:40 -Source: CB11238-01= - _ _- _- _ - - _ , — __= '--_- Spike Source %REC RPD - - Anal Yte- - - -- - - - . --- Beault =Ela9 _ 41 Unita= --Level - - ggsyl- %REC _--Limits- RPD - - - Illl - Notes - - - Total Suspended Solids -820 - 150 mg/L 1100 31 20 QM-12 Duplicate (8I05006-DUP2) _ _ _ __ __ ___ _ Prepared & Analyzed: 09/05/2018.16:40 - Source: CB11381-01 Spi'ke Source%REC RPD Anal _.. _ Result__Elflq-_—P91 Units= .Level ResulE %REC Limits RPD _ Limit- Notes Total Suspended Solids 300 50 mg/L 290 3 20 17 j • i FINAL -- Thls report relatos only -to .thesarnole-as received by -the laboratory, and may only be reproduced in full. = Page 6 of 8 I B U E. MRL - PQL N P QM-12 www.encolabs.com FLAGS/NOTES AND DEFINITIONS The analyte was detected in the associated method blank. The sample was analyzed at dilution. The reported value, is between the laboratory method detection limit (MDQ and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable: The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. Method Reporting Limit. The MRL is -roughly equivalent to the practical quantitation limit,(PQL) and is'. . based on the low point of the calibration curve, when applicable, sample preparation factor, dilution' factor, and, in the case of soil samples, moisture content. PQL: Practical Quantitation Limit.. The PQL presented is the laboratory MRL. The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. Precision between duplicate samples was outside acceptance limits. FINAL- This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 7 of 8 ENVIRONMENTAL CONSERVATION LABORATORIES CHAIN -OF -CUSTODY RECORD ® �) 10775 Central Port Dr. 4B10 Executive Park Court, Swe t 11 102-A Woodwinds Industrial Cf. Orlando. FL 32024 Jacksonville. FL 32216-6069 Cary, NC 27511 (407)826-5314 Fax (407)850.6945 (9D4)296.3007 Fax(904)296.6210 (919)467-3090 Fax(919)467-3515 www.encolabs.com Pane of Client Name Novozymes North America (1,40008) Project Number jrdone] Project Namemesc Motithly - SBM Requested Analyses Requested Turnaround Times uthe fests subjubjecec acceptance Nate :Rush reqt to _ Standard _Expedited Due t� 0 m cm c.l Lo G co 4 U p y UCNI G (0 )--j Address 77 Perry Chapel Church Road City/ST2ip - Franklinton, NC 27525 PO r l Billing Into 3800360507 Tel - 919 494-3000 ( ) Fax Reporting Contact Scott Creech Sampler(s) Name. Affiliation (Print) Billing Contact Acc®urns Payable Sampler(s) Signature Site Location! Time Zone Lab Workorder - :- -_ Preservation (See Codes) ICombine as necessary)_ Iterrr u Sample fD (Reid Identification) SBrvl ' . CCoollecnon Date i��,� Collection Time � Comp 1 Grab matrix .(see codes) SL Total k at Containers 3 t� .r'>. X - { I Sample Comments <- Tota) N of Containers Sample Kit Prepared By Dat me GammerrfsiSpecial Reporting Requirements ne'r.t.. • rw_r_...�...a..,�.,,. — — ..,., .,.�_, :__ ,.,_.__ -- ,._ -.,- _-. - - ^ Relinquished By Oatafi)ma Received ey DateTma AaLnqursh Da4ieR)me Recei B Daletl7me Ret' quished By OatEnime R relve 8y DateRme Cooler Ws &Temps on Receipt Con61 pon Receipt .-. � � _ Acceptable Una cceptable H-HU N-HNCTJ 5-HZJU4 NO-NaUll O.Omer (detail in comments) Note : All Barr+p le,submilted to FNCO Lail_ in accordance With 1he.erms and conditions listed on the reverse of Iles form, unless prior lvritten agreements exist Sample Preservation Verification ENCO Cary Work .Order: CB11658 Projedt: -Monthly - SBM Client: Novozyrnes North America.(NO008) Project .1n.bne] Logged In; , 04-Sep-18 10'33 Lbggdd By: John C King Preservation rvation Check. Performed By: Date/Time: CB11668.01 T P_ C '6&6 —MadeM t u -—A htg "'R -I,equireme 0' ontrol 9 fq�e A 250mLP+H2SO4 <2 Y /(4) NA Y' N NA 1,;?LV +2M E V. (24 -56 Reaqent Name ID Reaaent Name ID Reagent Name ID -1 3 5 2 4 .6 pH Strip ID: C:\ELMN-RPrint\wl<-o- -P.r6se.rvAtionCheck:rpt - -'Page- 1 of-1 ENVC0 -, Accurate. Tim el�r. Responsive. Innovative. 102-A Woodwinds Industrial Court - Cary NC, 27511 _ - -- - - - - - - - Phonef 919.467.9090 FAX: - 919.467.3515 Monday, September 17, 2018 Novozymes North America (N0008) - Attn: Scott Creech 77 Perry Chapel Church Road Franklinton, NC 27.525 RE: Laboratory Results for Project Number: [none], Project Name/Desc: Monthly - Week One - SBM ENCO Workorder(s): CB11660 Dear Scott Creech, Enclosed 'is a copy of your laboratory report for test samples received by our laboratory on Tuesday, September 4, 2018. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation -,I Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. FINAL This report relates onlyto the sample as received by the laboratory, and may only. be reproduced in full. Page 1 of 12 — - - — — — www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Received: -09/04/1 8 10:15-, Client ID: SBM ______ ____-____-__Lab=ID:-CB1-1660-01 Sampled: 09/04/18 07:00 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) CSU Method NO PREP 05/30/21 09/05/18 10:55 09/07/18 11:08 EPA 350.1 NO -PREP-- - ----10/02/-18- - --- 09/05/18 10:46 09/05/18 -10:46 EPA 351.2 Same - 10/02/18 _ 09/10/18 11:10 09/11/18 09:50 EPA 353.2 NO PREP 09/06/18 07:00 09/05/18 17:59 09/05/18 17:59 EPA 353.2 NO PREP 05/30/21 - 09/11/18 10:30 09/11/18 10:48 EPA 365.4 Same 10/02/18 09/10/18 11:10 09/11/18 11:45 EPA 6010D EPA 3005A 03/03/19 09/05/18 10:55 09/07/18 11:08 EPA 7470A EPA 7470A _ 10/02118-- -. 09/10/18 09:31 09/12/18 13:56 SM 254OB-2011 NO PREP 09/11/18 09/07/18 14:35 09/07/18 14:35 - - FINAL . - - - ____ —This report relates only -to the.sample as.received .by the laboratory, and may only be reproduced in full. Page 2 of 12 www.encolabs.cow- -- - I "- SAMPLE DETECTION SUMMARY = ' Client ID: SBM . ... . . . ... . .. _ - . , .- - .. _ _ _= b LaIDd. 'C611660-01.--- - Analyte - -- - - Results fin mu P_Q6 Units Methodi. Notes Aluminum - Total _ ' - - 289 - -- 0.420 , --- -1.60 - mg/L _ EPA 6010D- Ammonia as N 140 D 40 90 mg/L EPA 350.1 Arsenic - Total 0.0833 J 0.0760 0.100 - mg/L EPA 6010D Calcium -Total _ 3390, 0.390 - 1:00 mg/L EPA 6010D _ Copper - Total 0.418 B 0.0160 • 0.100 mg/L EPA 6016D Magnesium - Total 45.0 0.290 1.00 mg/L EPA 6010D Molybdenum - Total 0.0647- -J 0.0250. ---0.100- mg/L EPA 6010D Nickel -Total 0.0696 J 0.0220 0.100 mg/L EPA 6010D . Nitrate as N . 63- 0.025 0.10 mg/L EPA 353.2 Nitrite as N 0.30 0.017 0.10 mg/L. EPA 353.2 I Phosphorus 490. : D - _ 12 - __' S0 , mg/L fmg/L E PA 365.4 . _ potassium.- Total 434 1.50 5:00 EPA 6010D Sodium - Total 93.3 4.00 5.00' mg/L EPA 6010D Sodium Adsorption Ratio 0.440 [blank] CSU Method Total Kjeldahl Nitrogen 2000 D 52 96 mg/L EPA 351.2 Total Solids 4.5 0.25 0.25 % by Volume SM 2540B-2011 —I -- Zinc - Total 0.884 _ 0.0440 0.100 mg/L EPA.6010D I i i FINAL This report relates only to the sample as received by the laboratory, and may only, be reproduced in'full. t Page 3 of 12 .' CS N Www.encolabs.cwm ANALYTICAL RESULTS Description: SBM Lab Sample ID:CB11660-01 Received: 09/04/18 10:15 Matrix: Sludge Sampled:09/04/18 07:00 Work Order: CB11660 Project: Monthly - Week One - SBM Sampled By: Client Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591J Analvte rCAS Numberl Results Flaa Units QF M13L PQL Batch Method' Analyzed )ay Notes Mercury[7439-97-6]^ 0.000750 U mg/L 5 0.000750 0.00100' 8I10011 EPA 7470A 09/12/18 13:56 . NMN Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte WAS Numbed _ .. Results • fig . Units. p� MDL EM Batch Method. .Ana[yod . _Notes _ _ • ! j Aluminum [7429-90-5]^ 289 mg/L 10 0.420 1.00 SI05017 EPA 6010D 09%07/18 11:08 JDH Arsenic[7440-38-2]^ 0.0833 J mg/L 10 0.0760 0.100 8I05017 EPA 6010D 09/07/18 11:08 JDH l Cadmium [7440-43-9]^ 0.00360 U mg/L 10 0.00360 0.0100 8I05017 EPA 6010D 09/07/18 11:08 JDH Calcium [7440-70-2]^ 3390 mg/L 10 0.390 1.00 BI05017 EPA 6010D 09/07/18 11:08 JDH I Copper[7440-50-8]^ 0.418 B mg/L 10 0.0160 0.100 8I05017 EPA 6010D 09/07/18 11:08 JDH Lead [7439-92-1]^ 0.0310 U mg/L fl) 0.0330 0.100 BI05017' EPA 6010D 09/07/18 11:08 JDH Magnesium [7439-95-4]^ 45.0 mg/L 10 0.290 1.00 8I05017 EPA 6010D 09/07/18 11:08 JDH Molybdenum [7439-98-7]^ 0.0647 J mg/L 10 0.0250 0.100 SIO5017 EPA 6010D 09/07/18 11:08 JDH Nickel[7440-02-0]^ 0.0696 .J mg/L 10 0.0220 0.100 BI05017 EPA 6010D 09/07/18 11:08 JDH Potassium [7440-09-7]^, 434 mg/L 10 1.50 ,5.00 8I05017 EPA 6010D 09/07/18 11:08 JDH I I Selenium [7782-49-2]^ 0.0620 U mg/L 10 0.0626 0.100 8I05017 EPA 6010D 09/07/18 11:08 JDH u Sodium [7440-23-5]^ 93.3 mg/L 10 4.00 5.00 BI05017 EPA 6010D 09/07/18 11:08 JDH Zinc[7440-66-6]^ 0.884 mg/L 10 0.0440 0.100 8I05017 EPA 6010D 09/07/18 11:08 JDH Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 5911 Analvte rCAS Numberl Resul Flaa Units DF MDL PQL Batch MethodAnalyzed Notes Ammonia as N [7664-41-7]^ •140 D mg/L 900 40 90 BI05012 EPA 350.1 09/05/18 10:46 JU Nitrate as N [14797-55-8]^ 63 mg/L 1 0.025 0.10 8I11011 EPA 353.2 09/11/18 10:48 JU Nitrite as N [14797-65-0]^ 0.30 mg/L 1 0.017 0,10 8I05043 EPA 353.2 09/05/18 17:59 JU - Phosphorus [7723-14-0]^. - 490 D mg/L 500 12 50 8I10003 EPA 365.4 69/11/18 11:45 JU, , Sodium Adsorption Ratio 0.440 [blank] 1 8I05017 CSU Method 09/07/18 11:08 JDH -' Total Kjeldahl Nitrogen^ 2000 D mg/L 200 52 96 BI10002 EPA 351.2 09/11/18 00:50 JU Total Solids^ 4.5 % by Volume 50 0.25 0.25 8I07007 SM 25406-2011 09/07/18 14:35 OMR FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 12 i I -I _ • -. www.encolabs.com QUALITY' CONTROL DATA Metals_by EPA-6000/7000 Series Methods-- Quality Control== ---_4rT-=�= == =- - - Batch 8110011- EPA 245.1 Blank (8I10011-BLK1) Prepared: 09/10/2018 09:31 Analyzed: 09/12/2018 12:59 Spike Source %REC RPD _--Anal Result =' Elan- ='.=---RQL-- ---Mnits-- - Level %REC _Mmita- - -RPD'- - Limit - --Notes Mercury 0.000150 U 0.000200 mg/L LES (8I10011-BS3) Prepared: 09/10/2018 09:31 Analyzed: 09/12/2018 13:01 Spike Source %REC RPD _ - Anal Yti - _. Resydt F1as _ _ __ POL _.. Units _ Level Result • %REC Limits RPD Limit - N=S - - -" Mercury 0.00470 0.600206 mg/L 0.00500 94 80-120 Matrix Spike (8I10011-MSi) Prepared: 09/10/2018 09:31 Analyzed: 09/12/2018 13:18 Source: CB11591-01 Spike Source %REC RPD Anal vte Resin ELa4 POL units Level Resul %REC Limits RPD Limit Notes Mercury 0.00481 -0.000200 mg/L 0.00500 0.000150 U 96 75-125 I Matrix Spike.Dup.(8I10011-MSDI)________ _____: ___ ____- --____-.- __ Prepared:_09/10/201809:31Analyzed:-09/12/201813:38 - _- Source: CB11591-01 - Spike Source %REC RPD Anaivte Resu1L Flag PQL llldit Level Result %REC Limits RPD Limit Notes • Mercury 0.00551 0.000200 mg/L 0.00500 0.000150 U 110 75-125 14. 25 Post Spike (8I10011-PS1) Prepared: 09/10/2018 09:31 Analyzed: 09/12/2018 13:40 Source: CB11591-01 Spike Source %REC RPD AnalYte Result Elan, EM Units Level, Result %REC Limits RPD. Limit Notes Mercury 5.70 0.200 ug/L 5.00 -0.120 114 75-125 Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 8105017 - EPA 3005A fBlank (8I05017-BLK1) Prepared: 09/05/2018 10:55 Analyzed: 09/07/2018 10:23 �j Spike Source %REC RPD Anal Result Elm PGL Smite Level Result %REC Limits RPD Limit Notes Aluminum 0.0420 U 0.100 mg/L Arsenic 0.00760 U 0.0100 mg/L Cadmium 0.000360 U 0.00100 mg/L Calcium 0.0390 U 0.100 mg/L -� Copper 0.00207 3 0.0100 mg/L Lead 0.00310 U 0.0100 mg/L Magnesium 0.0290 U 0.100 mg/L Molybdenum 0.00250 U 0.0100 mg/L Nickel 0.00220 U 0.0100 mg/L - Potassium 0.150 U 0.500 mg/L Selenium 0.00620 U 0.0100 mg/L Sodium 0.400 U 0.500 mg/L Zinc .0.00440 U 0.0100 mg/L LCS (SI05017-111SI) r Prepared: 09/05/2018 10:55 Analyzed: 09/07/2018 1029 Spike Source %REC RPD - Anal Result Elam P.OL Units Level Result %REC Limits RPD Limit Notes i j Aluminum 2.02 0.100 mg/L .2.0.0 101 80-120 Arsenic. 0.193 0.0100. mg/L 0.200 96 80-120 -I FINAL i This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 5 of 12 EINCo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable)-by-EPA:6000/7000-Series-Methods:--Quality Control - - Batch 9105017 - EPA 3005A-Continued= --- - - -.- LCS (8I05017-13S1.) Continued _ Prepared: 09/05/2018 10:55 Analyzed: 09/07/2018 10:29 --- - - - --- - Spike Source %REC RPD Anal vte Besul Elan _ P91 _ _ _ lldb Level Result %REC Limits RPD Lima Notes Cadmium - 0.0206. 0.00100 _ mg/L 0.0200 103 80-120 Calcium = 2.00 -0.100 mg/L 2.00 100 -80-120 _ Copper .0.187 B -0.0100 mg/L 0.200 93 80-120 Lead 0.195 0.0100 mg/L 0.200 97 80-120 Magnesium _ _ _ _ 2.02 _ __ 0.100 _ - mg/L 2.00 101 80-120 _ Molybdenum 0.197 0.0100 mg/L 0.200 99 80-120 Nickel 0.205 0.0100 mg/L 0.200 102 80-120 Potassium 10.0 0.500 mg/L 10.0 100 80-120 Selenium 0.194 0.0100 mg/L 0.200 97 80-120 Sodium 10.2 0.500 mg/L 10.0 102 80-120 Zinc 0.211 0.0100 . _ mg/L 0.200 _ 105 80-120 Matrix Spike (8I05017-MS3) Prepared: 09/05/2018 10:55 Analyzed: 09/07/2018 10:32 Source: CB11592-01 - Spike Source %REC RPD Anal vte Result Elau EM Units Level Result %REC Limits RPD Limit Notes Aluminum - 3.41 - - -0.100 mg/L 2.00 1.44 99 75-125 Arsenic 0.191 0.0100 mg/L 0.200 0.00760 U 95 75-125 Cadmium 0.0201 0.00100 mg/L 0.0200 0.000360 U 101 75-125 Calcium 11.5 0.100 mg/L 2.00 9.66 91 75-125 Copper 0.190 B 0.0100 mg/L 0.200 0.00306 93 75-125 Lead 0.194 0.0100 mg/L 0.200 0.00310 U 97 75-125 Magnesium 5.26 0.100 mg/L 2.00 3.31 98 75-125 Molybdenum 0.197 0.0100 mg/L 0.200 0.00250 U 98 75-125 Nickel 0.201 0.0100 mg/L 0.200 0.00220 U 100 75-125 Potassium 29.1 0.500 mg/L 10.0 19.6 95 75-125 Selenium 0.198 0.0100 mg/L 0.200 0.00620 U 99 75-125 Sodium 107 0.500 mg/L 10.0 99.4 77 75-125 Zinc 0.213 0.0100 mg/L 0.200 0.00458 104 75-125 Matrix Spike Dup (BI05017-MSD1) Prepared: 09/05/2018 10:55 Analyzed: 09/07/2018 10:34 Source: CB11592-01 Spike Source %REC RPD Analyte Result Elea PQL _ Units Level Result %REC _ Limits RPD Limit Aluminum 3.52 - "- 0.100 mg/L 2.00 1.44 104 75-125 3 20 Arsenic 0.191 0.0100 mg/L 0.200 0.00760 U 95 75-125 0.02 20 Cadmium 0.0203 0.00100 mg/L 0.0200 0.000360 U 101 75-125 0.8 20 Calcium 11.5 0.100 mg/L 2.00 9.66 91 75-125 0.07 20 Copper 0.190 B 0.0100 mg/L _ 0.200 0.00306, 93 75-125 0.07 20 Lead 0.195 0.0100 mg/L 0.200 0.00310 U 98 75-125 0.4 20 Magnesium 5.37 0.100 mg/L 2.00 3.31 103 75-125 2 20 Molybdenum 0.198 0.0100 mg/L 0.200 0.00250 U 99 75-125 0.8 20 Nickel 0.201 omoo mg/L 0.200 0.00220 U lbl. 75-125 0.5 20 Potassium 29.3 0.500 -mg/L 10.0 19.6 96 75-125 '. 0.6 20 Selenium 0.199 0.0100 �mg/L 0.200 0.00620 U 100 75-125 0.8 20 Sodium 107 0.500 mg/L 10.0 99.4 80 75-125 0.3 20 Zinc 0.214 0.0100 mg/L 0.200 0.00458 105 '75-125 0.6 20 FINAL --- This report relates only-to.fhesample as received by the laboratory, and may only be reproduced in full. Page 6 of 12 I wwW.encolabs.coln- - QUALITY CONTROL DATA Metals -,(total recoverable) _by1PA 6000/7000 Series Methods - Quality Control . Batch 8105017 - EPA 3005A - Continued • - - - Post Spike (8I050177PS3) - _'- - -_ -- _ _ Prepared: 09/05/2018 10:55 Analyzed: 09/07/2018 10:36 -: - - `-Source:-C811592-01 - - Spike Source %REC ROD ------ -Anal _-Resul Level --Result --0/WRFC --Limits.RPD-- -�11Y=-- -Notes Aluminum 3.44 0.100 mg/L 2.00 1.44 100 80-120 Arsenic 0.198 0.0100 mg/L 0.200 -0.00346 99 ,'.80-120 . Cadmium 0.0212 0.00100 mg/L 0:0200 0.000174. 105 80-120 Calcium 11.5 0.100 mg/L 2.00 9.66 - 91 80-120 Copper 0.195 _' B _ 0.0100 _ mg/L 0.200_ 0.00306 96 80-120 _ -' Lead -'0,202- 0.0100 % mg/L 0.200 --0.000903 101 '80-120 - - - _ Magnesium --' _ 5.38'-, " - 0.100 mg/L 2.00 3.31 104 - 80-120 Molybdenum :0.207 0.0100 mg/L 0.200 - 0.000866 103 ;BO-120 f - Nickel .0.209 0.0100 mg/L 0.200 0.00179 104 80-120 Potassium - _ 29.3 '0.500 mg/L 10.0 19.6` - 96' 80-120 - Selenium 0.207 0.0100 mg/L 0.200 0.000517 103 80-120 Sodium 107 0.500 mg/L 10.0 99.4 73 80-120 QM-08 -� Zinc _ _ .... 0.225 0.0100 mg/L- 0:200 0.00458 110 80-120 -- - . Classical Chemistry Parameters - Quality Control Batch 8105012 - NO PREP Blank (8I05012-BLK3) Prepared: 09/05/2018 10:31 Analyzed: 09/05/2018 10:31 -I Spike Source %REC RPD -` Anal yte Result Elau PULL Units Level Result %REC Limits RPD. Limit Notes _ Ammonia as N 0.045 '" U 0.10 mg/L i 4 LCS (8I05012-6Si) Prepared: 09/05/2018 10:32 Analyzed: 09/05/2618 10:32 l Spike Source' %REC' RPD Anal BesalY Flaa P_QL Units Level Result' %REC Limits RPD Limit , Notes Ammonia as N 1.1 0.10 mg/L 1.00 110 .90-110 Matrix Spike (8I05012-MS1) Prepared: 09/05/2018 10:36 Analyzed: 09/OS/2018 10:36 Source: C809693-01 Spike Source' %REC RPD' Anal Result Elan OQL Units Level Result %REC Limits- RPD Limit Notes Ammonia as N . ' 0.42 0.10 mg/L 0.389 0.057 94 90-110 Matrix'Spike (8I05012-MS2) Prepared: 69/05/2018.10:41 Analyzed: 09/05j2018 10:41 Source: CB11381-02 Spike Source %REC RPD Anal vte Result Flag EM Units Level Result %REC Limits RPD, Limit Notes Ammonia as N 0.3.B 0.10 mg/L 0.389 0.045 U 98. 907110 Matrix Spike Dup (8I05012-MSDi) Prepared: 09/05/2018 10:38 Analyzed•; 09/05/2018 10:38 'Source: CB09645-01 Spike Source %REC RPD Anal s Result Elaa PU26 -Units Level Result %REC Limit RPD . Limit Notes Ammonia as N 0.42 0.10 mg/L 0.3.89 0.057 94 90-110 0.@ 10 Batch 8105017 - EPA 3005A Blank (8I05017-1111.1(1)' Prepared: 09/05/2018 10:55 Analyzed: 09/07/2018 10:23 I Spike Source %REC RPD AnaLltte R4.Ssllt' Elact P_U. Units Level. Result %REC Limits RPD Limit Notes _ _ _ E1NAL -: _- _ . _ .- -_ _ '.This report relates'only-to'.the sample as received by the laboratory, and may only be reproduced in full. Page 7 of 12 EtVC www.encolabs.com. QUALITY CONTROL DATA — Classical Chemistry Parameters.- Quality Control Batch 8105017 - EPA 3005A - Continued Blank (8I05017-BLK1) Continued Prepared: 09/05/2018 10:55 Analyzed: 09/07/2018 10:23 Spike Source %REC RPD t a - Anal lde Resul Elan P-QL ynit;: Level Result %REC Limits _ RPD Limit . ' Notes _ Sodium Adsorption Ratio . 0.00 U .[blank] - i Batch 8.105043.- NO PREP . Blank (8I05043-BLKi) Prepared: 09/05/2018 17:53 Analyzed: 09/05/2018 17:53 ' Spike Source %REC RPD Anal vte Result Elm ' P9L Units Level Result %REC Limits RPD Limit Notes' ` Nitrite as N 0.017 U 0.10 ing/L LCS (8I05043-BS3) Prepared: 09/05/2018 18:03 Analyzed: 09/05/2018 18:03 Spike Source %REC RPD (I� Anal tfte Result Elan PQL, Units Level R sul %REC Limits RPD Limit Notes Nitrite as N 1.0 - 0.10 mg/L 1.00 103 90-110 Matrix Spike (8I05043-MS3) Prepared: 09/05/2018 18:44 Analyzed: 09/05/2018 18:44 Source: CB11659-01 - 1 Spike Source %REC RPD lli--- Anal Result Elan PQL units Level Result %REC Limits RPD - Limit Notes' Nitrite as N 7.5 D 2.7 mg/L 1.00 6.5 107 90-110 j- Matrix Spike (8I05043-MS2) Prepared: 09/06/2018 15:43 Analyzed: 09/06/2018 15:43 1 Source: CB12678-03 ' 'Spike Source' %REC RPD Anale Result Elan` PQL Units Level Result %REC Limier RPD Limit Notes 1 Nitrite as N 1.1 0.10 mg/L 1.00 0.17 96 90-110 �- Matrix Spike'Dup (8I05043-MSD1) Prepared: 09/05/2018 18:45 Analyzed: 09/05/2018 18:45 Source: C511659-01 Spike Source %REC RPD AnaLtLtS Result Elau PDL Units Level Result %REC Limits RPD Limit Notes Nitrite as N 7.5 D 2.7 mg/L 1.00 6.5 109 90-110 0.3 10 Batch 8107007 - NO PREP 1— (, Blank (8I07007-BLK1) Prepared & Analyzed: 09/07/2018 14:35 Spike. Source . , %REC 1. RPD 9nalyte Result Elm PQL units Level Result %REC Limits RPD Limit Notes — Total Solids 0.0050 U 0.0050 % by Volume LCS (8I07007-BSI) Prepared & Analyzed: 09/07/2018 14:35 Spike Source %REC RPD Anal YJe Result Elan P-QL Units Level Result %REC Limits RPD Limit _ Notes Total Solids 1100 50 mg/L 1100 98 80-120 � - Duplicate (8I07007-DUPi) Prepared & Analyzed: 09/07/2018 14:35 - Source: C011659-01 {� Spike Source %REC RPD j{ AnalV.te Result Elan PQL Units, Level Result %REC Limits RPD, Limit Notes - Total Solids 0.24 0.0050 % by Volume 0.25 ' 1 20 Batch 81.10002 - Same FINAL This report relates only.to the sample as received by the laboratory, and may only be reproduced in full. Page 8 of 12 www.encolabs.com, I i QUALITY CONTROL DATA c, Classical Chemistry Parameters --Quality Control - Batch 8I10002 - Same - Continued Blank (8I10002-BLKi) -Prepared:- 09/10/2018 11:10 Analyzed: 09/1-1/2018 09:34-: Spike Source %REC RPD ------- - Analvte------ - -- -- --- ------Bewt— E1ag--P_QL— _—Units -—Level_�Result _ %REC Limits ____.RPD'- Limit Notes - Total Kjeldahl Nitrogen 0.26 U 0.48 mg/L LCS (8I10002-BSI) _ Prepared: 09/10/2018 11:10 Analyzed: 09/11/2018 09:36 _ Spike Source 0.%REC RPD Anal Yte Result Flan PQL . Units Level Result %REC limits RPD Limit Notes Total Kjeldahl Nitrogen 13 0.'48 mg/L 12.0 105 90-.110 Matrix Spike (8I10002-MSi) Prepared: 09/10/2018 11:10 Analyzed: 09/11/2018 09:40 Source: CB08048-02 Spike Source %REC RPD Analvte Resul Fl�tca PQL Units Level Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 5.6 0.48. mg/L 4.80 0.65 104.. 90-110 Matrix Spike (8I30002-MS2) _' _ Prepared: 09/10/2018-11:10 Analyzed: 09/11/2018 09:45 Source: CB11659-01 Spike Source %REC RPD Analyte Resul Elan P_GL Units Level Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 14 D 0.96 mg/L 4.80 8.9 104 90-110 Matrix Spike Dup (8I30002-MSD1) Prepared: 09/10/2018 11:10 Analyzed: 09/11/2018 09:41 Source: CB08048-02 Spike Source %REC RPD Anal Resul S E1a9 PQL Units, Level Result, %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 6.0 0.48 mg/L 4.80 0.65 ill 907110 5 10 QM-07 Batch 8110003 - Same Blank (8I30003-BLKi) Prepared: 09/10/2018 11:10 Analyzed: 09/11/2018 11:36 Spike Source %REC RPD Anal YYe Resul Y Ela9 P_QL Units Level Result %REC Limits RPD Limit Notes Phosphorus 0.025 U 0.10 mg/L LCS (8I10003-BSI) Prepared: 09/10/2018 11:10 Analyzed: 09/11/2018 11:37 Spike Source %REC RPD Anal Result Flag POL Units . Level Result %REC Limits RPD Limit Notes Phosphorus 1.6 0.10 mg/L 1.60 99 80-120 Matrix Spike (8I10003-MSi) Prepared: 09/10/2018 11:10 Analyzed: 09/11/2018 11:40 Source: CB08048-02 Spike Source %REC RPD Anal Result Flag P_QL Units Level Result . %REC Limits RPD limit Notes Phosphorus 0.83 0.10 mg/L 0.640 •0.27 88 80-120 Matrix Spike Dup (8I30003-MSDI) Prepared: 09/10/2018 11:10 Analyzed; 09/11/2018 11:41, Source: CB08048-02 Anallte Phosphorus Batch 8710018 - NO PREP Spike Source %REC RPD Result Flag M Units Level Result %REC Limits RPD Limit Notes 0.83 0.10 mg/L 0.640 0.27 88 80-120 0.3 25 This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 12 CaNc www.enc6labs'.Com . QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control- - - Batch 8110018 - NO PREP - Continued LCS (8I10018-BSI) Prepared: 09/10/2018 13:09 Analyzed: 09/10/2018 13:09 Spike Source %REC RPD Anal Resul .Flan P_QL - units Level Result '/oREC- Mmitig RPD' Limit -. Notes Nitrate/Nitrite as N 1.4 0.10 • mg/L 1.25 110 . 90-110 Matrix Spike (8I10018-MS1) Prepared: 09/10/2018 13:13 Analyzed: 09/10/2018 13:13 Source: CB11046-03 Spike Source %REC a RPD ( j Anal vY�_ Resin EAQ- - P-M . -- ' Units Level ' Result %REC' Limits RPD. Limit ...._. Notes Nitrate/Nitrite as N 120 10 mg/L 50.0 70 98 90-110 Matrix Spike (8I10018-MS2) Prepared: 09/10/2018 14:56 Analyzed: 09/10/2018 14:56 Source:CB11659-01RE3 Spike Source %REC RPD Anal vte Result fLa_4 POL Units Level Result %REC Limits. RPD Limit Notes - Nitrate/Nitrite as N 34 2.0 , mg/L 10.0 25 91 90-110 Matrix Spike Dup (8I10018-MSD1) Prepared: 09/10/2018 13:15 Analyzed: 09/10/2018 13:15 C� Source: CB11046-01 Spike Source - %REC RPD Analtde lResult .. Elm P91 knits Level Result . . %REC Limits RPD J,Unit Notes . Nitrate/Nitrite as N 120 10 nI 50.0 70 98 90-110 0.06 10 . -IF l FINAL This report relates only to - the sample as received by the laboratory, and may only be reproduced in'fuli. - Page 10 of 12 I~ www.encolabs.coM- - —' .FLAGS/NOTES AND DEFINITIONS- B. The analyte was detected in the as method blank.-; D The sample was analyzed at dilution. 7 ' :_. _= _The reported -value is -between the -laboratory method detection limit (MDL) and.the laboratory method reporting limit (MRL), adjusted for actual sample preparation data -and moisture content,.where applicable. - _- U -_ The arfalyte was analyzed for but not detected to the level shown, -adjusted for actual sample preparation_ _. data and moisture content, where. applicable: E The concentration indicated for this analyte'is•an estimated value above the calibretion.iange of the instrument. This value is considered an estimate.. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation.limit (PQL) and is = _based on the low point of the calibration curve; when applicable, sample preparation factor, dilution factor, and, in• the case of soil samples,, moisture content. PQL PQL Practical Quantitation Limit. The PQL presented is the.laboratory MRL. N The analysis indicates the presence of an analyse for which there is presumptive. evidence or greater - confidence),to make.a "tentative identification": - - - P ; _--:_ Greater -than 259% concentration difference-wesobserved between the-primary=and secondary GC column. The lower concentration is reported. QM-07 The spike recovery, was, outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. QM-08 Post -digestion spike did not meet method requirements duetoconfirmed matrix effects (dilution test). Page 11 of-12 _ 10775 Central Port Dr - 4810 Executive Park Court, Suite 111 - 102-A.Woodrmuls industrial Ct - O dando, FL 32824 - Jacksonville, FL 32216-6059 Cary, NC 27511 (407) 82r s314 Fax (407) 850-6945 (904) 298-3007 Fax (904) 296-r-M - . (919) 467.3D90 Fax (919) 467-3515 - _ Page of ' Client Name. Project Number Requested Analyses Requested Turnaround Novozymes North Arnerica (NO008) [none] :.. :. o . a 2 � ' . o � . ;Times Note : Rush requests subject to acceptance by the.facility-, Address 77' .Pergj.Cha¢ei Church road ProjectNamefDesc: Monthly ee1 -One'= SBN1 .- z e City1ST/7p , . .: Franklinton, (�C'27a�5 PD # J Billing irdo 3800350507- Z a w in `o Standard . o - CO),_ Tel Fax .. ; .. . RepDrting Contact . :.Y (919)84-300t). : Stitt Creech z Q m." Expedited ' Sampler(s) Name, Affiliation (Print) Billing Contact Accourms Payable ' R a , ' Z` ` Due w Q to ea Samplers)Signature Site Location ✓ Time Zone _ - a' r rn CabWorkofder,".; '. a� �. Z 0 Preservation (See Codes) (Combine as necessary). . Item # . Sample ID (Field Idehtiiication) Collection Date Collection Time Comp! Grab fttatrix (see codes) Tow d of Conta-mers Sample Comments 0 <=Total # of Containers Sample Kit Prepared By. Daiefr" e. 1. k 'shed 8y - - . Daiefrime Re�- - - - - DatelTme �y tY aterfin Racal day Dqushed atemmeConmonis/Speeial•ReportingRaquiremetls tq Relinq ' edBy DatelTime He ived y Daterl•Ime pondifio. Upon,Receipf Gooier #5 8 Temps on Reeeiph - %=. ' '= Acceptable. Unacceptable NIT Jx:OlN-G.Undwatef-SOSollDW-DrinWn0Nater'SE-Sediment SY!-SwlaceWater VVW-Wastertater A-Ar O-Other(detail incomments) 'Presennrionni-lce WHO 14-HNW S442SO4 NO-NaOH O-Qiher(detailin_ comments) Nole :A4 samples submitted to ENGO Labs are in accordance with -the terms and conditions WEd Dn the re+erse of this form, unless prior written agreements exist Sarnole Preservation Verification ENCO Cary Nkr o- :7 7 Work Order:, CB11660 Project: Monthly - Week One - SBM Client� Novozyres North America (NO . 008) Project #: [none] Logged In: 04-Sep-18 10:37 t Logged By: John C King Preservatio'n'Check Performed By: Da . tefrime: mil6so-oll C°pt` Type gym., pM Adjusted } Reagent ZAI Used/Comments ', In Control Ad u ed #Requir`enent;, A 250mLP+H2SO4 NA VN -INA G�.r�� .,G/1'IC,v� 'B-- 250rhLP+HNO3 <2 Y i C1 NA Y ^1 NA Rebqent Name 10 Reagent Name ID ID, Reaqent Name 3 5 2 0 0 4 6 i L pH Strip ID: C:\EL.MNT\Print\wko_PreservationCheck:rpt ... ckspt Pade.1 0* , Labor, tones. C ra m Innovative. 102-A Woodwinds Industrial Court -- Cary NC, 27511 - Phone: 919.467.3090 FAX:--919.467.3515- - -- - - - Thursday, October 11,_2018 I _ -- -- --Novozymes North America (N0008) I Attn: Scott Creech - - 77 Pery Chapel Church Road Franklinton, NC 27525 RE: Laboratory Results for Project Number: [none], Project Name/Desc: Monthly - SBM , - - ENCO Workorder(s)t C1314230- - Dear Scott Creech; Enclosed is a copy of your laboratory report for test samples received by our laboratory on Tuesday, October 2, 2018. ' f Unless otherwise noted in an attached project narrative, all samples were'received in L : acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to .the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except . as noted in the, project narrative if applicable. This report shall. not be reproduced except in full, without the written approval of the Laboratory. This .report contains only those analyses performed by Environmental Conservation I� Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do' not hesitate to contact.me. Sincerely, Chuck Smith Project Manager . Enclosure(s) —:_. _ -FINAL _ ___ __ _ ____ _ This report,relates only to -the sample as received by-theaaboratory, and may only be reproduced_in.full.. - _ _ _ .. _ - .. _ ._ Page 1 of 8 __'_ - _- ---- — ----- ---- www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: 'SBM J Received: 10)02%18 11:00 Wti3D CB14230-01- Sampled: 10/02/18 07:00 Parameter -Preparation Hold-Date/Time(s)— — Prep Date/Time(s) Analysis Date/Time(s) SM 254OD-2011 NO PREP 10/09/18 - 10/04/18 15:09 10/04/18 15:09 SM 5210 B-2011 -'NO-PRE - - — 10/04/-18— —07i00 10/03/18 12:47 - 10/03/18 12:47 -.- =-- - SM 5220D-2011 Same 10/30/18 - - ---10/04/18---10:42--- -10/04/18- 15:15_----- - FINAL - - ----This reportrelatesonly-to the -sample asreceived by the laboratory, and may only be reproduced in full. - Page 2 of 8 www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: SBM Lab -ID: - C814230-01 --- I Anah ft Results flag MA1, EQL Units. Method Notes Biochemical Oxygen Demand 8900 2.0 2.0 mg/L SM 5210 B-2011 Chemical Oxygen Demand 26000 400 400 mg/L SM 5220D-2011 Total Suspended Solids 26000 5000 5000 mg/L SM 254OD-2011 This report relates only-W-the sample as received by the laboratory, and may only be reproduced In full. Page 3 of 8 ' '- --- EIVCO . www.encolabs.com ANALYTICAL RESULTS Description: SBM _ Lab Sample ID:CB14230-01 Received: 10/02/18 11:00 Matrix: Sludge Sampled:10/02/18 07:00 Work Order: CB14230 Project: Monthly - SBM Sampled By: Client Classical Chemistry Parameters l ENCO Cary certified ana/yte [NC 5911 Analvte fCASNumberl _ = _-- - Re -wits llaaq-' Units DF ' 'Mp3 pQ Batch Method nal ed Ay Note d Biochemical Oxygen DemaodA 8900 mg/L 1 2.0 2.0 8J03013 SM 5210 B-2011 10/03/18 12:47 JOC Chemical Oxygen DemandA 26000 mg/L 40 400 400 . 8J04011 SM 5220D-2011 10/04/18 15:15 - JOC Total Suspended SolidsA 26000 mg/L 2000 5000 5000 8J04002 SM 254OD-2011 10/04/18 15:09 OMR QUALITY CONTROL DATA "Classical Chemistry parameters- QualityControl: Batch W03013 - NO PREP - - Blank (8303013-OLK1) - -- Prepared & Analyzed: 10/03/2018 12:47 Spike Source %REC RPD �Dal1�— -- - - _ Result`-=�Ela4=PS26_-,Tllnite--Level-- —Result---%REC __J,jp --_RPD— =-Li011�- —=M4t&£ :-- - Biochemical Oxygen Demand- —---2.0•-- - -- U-, ,----2.0 --mg/L- - - LCS (8303013-11IS1)_ Prepared & Analyzed: 10/03/2018 12:47 Spike Source %REC RPD Analyze Result Magi,, FM - Units Level Resul %REC .. Limits RPD Limit ' Notes Biochemical Oxygen Demand .. 190 2.0 mg/L 198 98 85-115 — Duplicate (8303013-13UPi) Prepared & Analyzed: 10/03/2018 12:47 Source: CB12918-01 Spike Source %REC RPD Anal vte Resul t Flan POL Units Level Resul %REC Limits RPD' Limit Notes Biochemical Oxygen Demand 640 2.0 - mg/L 680 5 30 -_ Batch 8JO4002 : NO PREP Blank (8304002-BLK1) Prepared & Analyzed: 10/04/2018 15:09 Spike Source %REC RPD Anal Result Elaa MI. Units Level Result %REC Limits RPD Limit Notes Total Suspended Solids 2.5 U 2.5 mg/L LCS (8704002-BS3) Prepared & Analyzed: 10/04/2018 15:09 Spike Source %REC RPD Anal lfte Result Elan P_QL Units Level Result %REC Limits RPD Liput Notes - - Total Suspended Solids' - 92- -- 2.5 mg/L 100 92 80-120 - Duplicate (8704002-DUPi) Prepared & Analyzed: 10/04/2018 15:09 Source: C812918-01 . Spike Source %REC RPD Anal ttte Result Flan P91 Units Level Result %REC Limb RPD Limit Notes Total Suspended Solids 920 100 mg/L 940 3 20 Duplicate (8704002-DUP2) Prepared & Analyzed: 10/04/2018 15:09 Source: CB13031-01 Spike Source %REC RPD AnaL1(te '- Remit - Fla-4. P/21 Unite Level Result. %REC Limits RPD' Limit - Notes Total Suspended Solids 190 .50 mg/L 210 7 20 Batch 8104011- Same Blank (8704011-BLKi) Prepared: 10/04/2018 10:42 Analyzed: 10/04/2018 15:15 Spike Source %REC RPD Anal yde Result Elsa M& Units Level Result %REC Limits• RPD' Limit Notes Chemical Oxygen Demand 10 U 10 mg/L LCS (8304011-13SS) Prepared: 10/04/2018 10:42 Analyzed: 10/04/2018 15:15 Spike Source %REC RPD Anal Result Elan P-QL Units Level . Result %REC Limits .RPD Limit. Notes Chemical Oxygen Demand 490 10 mg/L 500 98 90-110 ,_ FINAL This report relates only to the'sample as received by the laboratory, and may only be reproduced in full. Page 5 of 8 - Calloco wwww.encolabs.com QUALITY CONTROL DATA lClassicall Chemistry Parameters =Quality-Cdntrol7--------- Batch 8104011 - Same— Continued--- - Matrix Spike (8304011-MSI) Prepared: 10/04/201810:42 Analyzed: 10/04/2018 15:15 Source: C511375-01- Spike Source %REC RPD -Resu[t—Elaa.FQL-- -__Units Level -gesul -0/bREC - - -Urnits __RPD Chemical Oxygen Demand 690 10 mg/L 526 190 94 90-110 Matrix Spike Dup (004011- Prepared: 16/k/k18 10:42 Analyzed: 10/04/2018 15: . 15 Source: CB11375-01 Spike Source %REC RPD Analvte Resul - 13% -units Level Result %REC Limits RPD Notes Chemical OxygenDemand660 —1 6—mg- /1— 526 190 90 90-110 3 10 -1 -- - '- --- ----FINAL .-This report relates only -to the sample as received by -the laboratory, and may only be reproduced In full. .-Page 6 of 8- ---- I www.encolabs..com. ,FLAGS/NOTES AND DEFINITIONS i— -. B.. The anal a was detected --_ - ---_ - ---_ - -r- -- - --_ . -__-_ _-----=--'_= _------ ---- - ---=- - - - -- -:_- -- - ' - - - yt in the associated method blank. _..- D The sample was analyzed at dilution.- 3 _ The reported value is between the laboratory method detection limit (MDL) and -the laboratory method -reporting limit (MRQ, adjusted for actual sample preparation data and moisture content,.where applicable. _- __ U - The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the . --- --= -instrument. This value is considered an estimate.. MRL .:. Method Reporting'Limit. The MRL is roughly equivalent to the practical quantitation limit'(PQL). and is ' based on the low, point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples,, moisture content. i PQL PQL: 'Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or, greater k _ _ confidence) to make a"tentative:identification" P Greater than 25% concentration difference was observed between the primary and secondary. GC column. The lower concentration is reported. Page 7 of'8, - , ENVIRONMENTAL CONSERVATION LABORATORIES 'CHAIN-OF-CUSTdbY RECORD . 10775 Central Part or - 4810 Executiv® Parts Court, Sui€e 171 tA2 A Woodwinds industrial CL ' Orlando. FL 32M - .Jacksonville; R..32216'-6089 - - -Cary; NC 27511 (407) 82&53/4 Fax (407) 8504P-45 (904) 296-3007 Fax (98q 29tr6210 (919) 4S7-3090' Fade (912) 497351.5 wmimenc®labs.c®re . Page - --of . - clientPame Novnzymes North Amdric a (140008) Project Number f 6ane1- Requested!AnaWes- Requested Turnaround Times Note: Rgshraq srsagbject10 acoeplance by the facility f - Standard _ Expedited Due. . - _ J Address 77 -Perry Cha*i Church Road Project Name!De= - = . Monthl� -'SBNI' CitylsTrzi :. ..PO 1'rattkllriton EIC -275 5 # 1 BiE6ng info 3S0Lt3 f75�7 Tel (�OA� 494-3040 . Fax Reporting Canlacl - .-Scott Cret cFi Samptar(s) Name. Al ipalion-(Print) - - < _ _ :. - Biitirfa,Contac) :...... tc:cot�st Paybls : ' siteLoccationlTimsZone TLabSompter(s)Signoture-. WlSrkotder ,14 0;1� $Presensatioat (S C es) (Cnenbi hom,# Sample ID {Field Iderniflcatiion) -. Coltection-D Collection Time - Camp l Grab flratdx isee codas) Total K of Conminars Sample Comments' _ 1,4' - <—Total i# of Containers - as Sample Kt Prepared By DalaTme _ , Reii By - Datefiona Received By' Uat me ! . GomnieritsJSpaciaLReportingRequirements n Tintl9lafied • DatefTnne Date me mjo Relinquished By DateTme Received By. DataTme -. Cooler#'a &Temps on Recelpf Conlon Upon Receipt •' `c Acceptable,:- Unacceptable rurarnx ; taw-uTmmovlarar by -Jon uw-unmmng vuater- st-Segunom-5w.-sunace water wW wastewater A-Atr 040iper (detail in Comments) Pieservattan. 1-16ce €{-Hut N-k.NO3 S-HZSO4. Nv-NaL7H o-Other{detail in.comments) . Note :'All•sampte$ submitted to ENCO Labs are in accordance with the terms and cdnddiens listed an the reverse at this -form; gniesS prtor vrfilten agreements exist Sample Preservation Verification ENCO Cary A� 11 =eNC749 Work Oirder: CB14230 Project-. Monthly - SBIVI Client: 'Novozymes North America (N0008) Project [none] LQg 'ed,ln: 02-Oct-18 11:52 h 9 Logged By: Rachel,A YO Is Pr eservation Check Performed By: Date/Time: CB14230-01 Gout ;.{I; v, -1 Type, " ... Reagent "on A 25OrnLP+H2sb4 <2 19 N. NA.1 'Y N) NA Reagent Name ID Rea'-qbnt Name ID -3 • 2 4 pIH-Strip ID; PH Strips C7.10820 ----C:Wrft6t\PrintIWKO -vreservatio n(.;heck.*rpt Reagent Name ID 5 6 Page 1 of I a or a I" 'e �COI N E, Ni y06) - ccurate.----..Thiiely. . Responsive.. Innovative., 102-A Woodwindsdustrial In - - court._ ___:_ �_ -• ---- - ��---- �._.._-•__ Cary NC, 27511 Phone: 919.4673090 . -FAX:- 919.467.3515 > Friday, October 12, 2018 , Novozymes North America (N0008) - Attn: Scott Creech 77 Perry Chapel'Church Road - Franklinton, NC 27525 RE: Laboratory Results for Project Number: [none], Project NamejDesc: Monthly - Week One - SBM ENCO Workorder(s): CB14232 Dear Scott Creech, _ Enclosed is a copy of your laboratory report for test samples received by our laboratory on Tuesday, October 2, 2018. Unless otherwise noted in an attached project narrative; all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. . The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. i This report contains only those analyses performed by Environmental Conservation - Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from L' outside organizations will be reported under separate'cover. If you have any questions or require further information, please do not hesitate to contact.me. Sincerely, . Chuck Smith Project Manager I- Enclosure(s) �_ __ FINAL _ This report relates only to the'sample as received by the laboratory, and may only be reproduced imfull. Page 1 of 12 . - ' f� MiLlco www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: SOW— } —_____—____= __ _=.-=Cab=ID:=CBf4232=0f -- --Sampled:`10/02/18 07:00 Received:--10/02j18'11:00- Parameter Preparation - — Hold-Date/Time(s)— - -- Prep Date/Time( Analysis Date/Time(sl _ _ CSU Method NO PREP __ _ __ _ _ _ _ _ O6/27/21 __ 10/04/18 09:32 10/09/18 15:41 - -EPA-3501- -- --No-PREP - --10/30%18- - 10/10/18 17:43 -- - = 10/10%18--17:43- EPA 351.2 Same 10/30/18 10/06/18 11:00 10/08/18 Bi04 " EPA353.2 NOPREP-- --- --- --d0/04/18----07:00----- - 10/02/18 17:13 10/02/18 17:13 `--- EPA353:2-"'----- -NO-PREP 06/2T/21 10/12%18 14:03--' - 10/12j18-14:16 ''-`-" - ---- " EPA 365.4 Same - 10/30/18 - 10/06/18 11:00 10/08/18 14:51 EPA 6010D EPA 3005A -------- ----03/31/19 --- - ---- - - - - 10/04/18 09:32 10/09/18 12:21 EPA 7470A EPA 7470A 10/30/18 - - 10/10/18 15:02 10/11/18 14:49 - SM 2540E-2011 NO PREP 10/09/18 10/09/18 14:11 10/09/18 14:11 UII • I _J �I L_J FINAL• - - - — _— _ - —This report relates only to the -sample as received by the laboratory, and may only be reproduced In full. page 2 of 12 -_ _ www.encolabs.com 1 SAMPLE DETECTION SUMMARY - Client IDr SBM - - Lab ID: - CB14232-01 AnalM Results E1@8 MU EQL Units Method Notes Aluminum - Total 202 0:420 1.00 mg/L EPA 6010D Ammonia as IN 170 D 4.5 10 mg/L EPA 350.1 - = Calcium - Total -- _ - 3290 — 0.390-' _ '-' 1.00 --mg/L EPA 6010D - Copper - Total 0.375 0:0160 0.100 mg/L EPA 6010D Magnesium - Total 33.8 0.290 1.00 mg/L EPA 6010D = _ - Molybdenum=Total — -' — "' - U.696- =3----- 0.0250= -- -0.100 mg/L —EPA-6010D ---'- - - Nickel - Total 0.0504 1 0.0220 -0.100 mg/L EPA 6010D Nitrate as N 12 - - .0.025 0.10 mg/L EPA 353.2 Nitrite as N - - - - - -- 1.2 - - - 0.017 0.10 mg/L EPA 353.2 Phosphorus 550 D 25 100 mg/L EPA 365.4 Potassium,- Total 691 1.50 5.00 mg/L EPA 6010D Sodium - Total 123 4.00 5.00 mg/L EPA 6010D Sodium Adsorption Ratio 0.585 [blank] CSU Method Total Kjeldahl Nitrogen 1800 D 52 96 mg/L EPA 351.2 Total Solids 4.7 0.25 0.25 % by Volume SM 2540B-2011 Zinc - Total 0.616 0.0440 0.100 mg/L EPA 6010D FINAL This report relates 'only to the sample as received by the laboratory, and may -only be reproduced in full. Page 3 of 12 cEIVCO www.encolabs.com ANALYTICAL RESULTS Description: SBM Lab Sample ID:CB14232-01 Received: 10/02/18 11:00 Matrix: Sludge Sampled:10/02/18 07:00 Work Order: CB14232 Project: Monthly - Week One - SBM Sampled By: Client Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 5911 -�---Analvte-fCAS Numbed----- Resul -Fla6--SJnits DF= D -- rL4 P2L-'---Batch ----Method---- -Anal ----py --- Mercury [7439-97-6]^ 0.000750 U mg/L 5 0.000750 0.00100 11130032 EPA 7470A 10/11/18 14:49 NMN Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 5911 j Analyte rCAS Numbed = . Results - F18g Units PE MP-L . _E" Batch Method. Analyzed - @1C Notes-,_ Aluminum [7429-90-5]^ 262 mg/L 10 0.420 1.00 8104015 EPA 6010D 10/09/18 12:21 JDH Arsenic[7440-38-2]^. 0.0760 U mg/L 10 0.0760 0.100 8104015 EPA 6010D 10/09/18 12:21 JDH Cadmium [7440-43-9]^ 0.00360 U mg/L 10 0.00360 0.0100 8304015 EPA 6010D 10/09/18 12:21 JDH Calcium [7440-70-2]^ 3290 mg/L 10 0.390 1.00 8104015 EPA 6010D 10/09/18 12:21 JDH Copper[7440-50-8]^ 0.375 mg/L 10 0.0160 0.100 8104015 EPA 6010D 10/09/18 12:21 JDH Lead [7439-92-1]^ 0.0310 U mg%L 10 '0.0310 0.100 8304015 EPA 6010D 10/09/18 12:21 JDH Magnesium [7439-95-4]^ 33.8 mg/L 10 0.290 1.00 8304015 EPA 6010D 10/09/18 12:21 JDH Molybdenum [7439-98-7]^ 0.0696 J mg/L 10 0.0250 O'.100 8304015 EPA 6010D 10/09/18 12:21 JDH Nickel[7440-02-0]^ 0.0504 J mg/L 10 0.0220 0.100 8104015 EPA 6010D 10/09/18 12:21 JDH Potassium [7440-09-7]^ 691 mg/L 10 1.50 5.00 8104015 EPA 6010D 10/09/18 12:21 JDH a Selenium [7782-49-2]^ 0.0620 U mg/L 10 '0.0620 0.100 8J04015 EPA 6010D 10/09/18 12:21 JDH Sodium [7440-23-5]^ 123 mg/L 10 4.00 5.00 8104015 EPA 6010D 10/09/18 12:21 JDH Zinc[7440-66-6]^ 0.616 mg/L 10 6.0440 0.100 8104015 EPA 6010D 10/09/18 12:21 JDH j 1 Classical Chemistry Parameters III ^ - ENCO Cary certified analyte [NC 591] - Analvte ICAS Numbed Resultslava UnitsDF MDS P L _ at Method Analyzed Notes Ammonia as N [7664-41-7]^ 170 D mg/L 100 4.5 30 8110021 EPA 350.1 10/10/18 17:43 JLJ Nitrate as N [14797-55-8]^ 12 mg/L 1 0.025 0.10 8112026 EPA 353.2 10/12/18 14:16 JL1 Nitrite as N [14797-65-0]^ 1.2 mg/L 1 0.017 0.10 8102040 EPA 353.2 10/02/18 17:13 JLJ Phosphorus[7723-14-0]^ 550 D mg/L 1000 25 100 8106002 EPA 365.4 10/08/18 14:51 JL1 Sodium Adsorption Ratio 0.585 [blank] ' 1 8104015 CSU Method 10/09/18 15:41 JDH Total Kjeldahl Nitrogen^ 1800 D mg/L 200 52 96 8306001 EPA 351.2 10/08/18 13:04 31_1 Total Solids^ 4.7 0/ by Vnhfma rn n 99 n,)c cinoma C. FINAL This report relates only to the sample as received by the laboratory, and may only -be reproduced In full. Page 4 of 12 www.encolabs.com._, , - QUALITY CONTROL DATA Metals by EPA 6000/7000 Series Methods = Quality Control ` Batch 8710032 - EPA-245.1 - Blank (8310032-BLK3) Prepared: 10/10/2018 15:02 Analyzed: 10/11/2018 14:26 Spike Source %REC RPD _ --: - 9pal�.-Result=AP/REC. -.LIIDiTE----RPD- Mercury 0.000150 U --0.000200 mg/L. Blank (8310032-BLK2) Prepared: 10/10/2018 15:02 Analyzed: 10/11/2018 14:29 Spike Source %REC RPD Anal Besul Elam E41 - Units Level Bed %REC Limits RPD Limlt Notes - Mercury , 0.00300 U 0.00400 mg/L LCS (8310032-BS1) Prepared: 10/10/2018 15:02 Analyzed: 10/11/2018 14:31 Spike Source %REC RPD - Anal vte Result E134 POL its Level Result %REC Limits RPD Lima , Notes Mercury 0.00484 0.000200 mg/L 0.00500 97 80-120 _ Matrix Spike (8310032-MS1) Prepared: 10/10/2018 15:02 Analyzed: 10/11/2018 14:36 Source: CB14826-03 Spike Source %REC RPD Anal vte Result Elam, - P91 Units Level Result %REC Limits RPD Limit Hates Mercury 0.00489 0.000200 mg/L 0.00500 0.000150 U 98 75-125 Matrix Spike Dup (8310032-MSD1) Prepared: 10/10/2018 15:02 Analyzed: 10/11/2018 14:38 Source: C614826-03 Spike Source %REC RPD Anal ldg Result Elam E46 !!.nits Level Result %REC Limits RPD . i i Notes Mercury 0.00483 0.000200 mg/L 0.00500 0.000150 U 97 75-125 1 25 Post Spike (8310032-PSl) Prepared: 10/10/201.8 15:02 Analyzed: 10/11/2018 14:45 Source: C814826-03 Spike Source %REC RPD Anal Yte Result Elam E91 Units Level Result %REC Limits RPD L'Imlt Notes Mercury 6.26 0.200 ug/L 5.00-0.0480 125 75-125 Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 8JO4015 - EPA 3005A Blank (8304015-BLK3) Prepared: 10/04/2018 09:32 Analyzed: 10/09/2018 11:51 Spike Source %REC RPD Anal vte Result Elam EM Units Level Result %REC Limits RPD Limit Notes _ Aluminum _ _ 0.0420 U 0.100 mg/L_ Arsenic 0.00760 U 0.0100 mg/L Cadmium 0.000360 U 0.00100 mg%L Calcium 0.0390 U 0.100 mg/L Copper 0.00160 U 0.0100 mg/L Lead 0.00310 U 0.0100 mg/L Magnesium 0.0290 U 0.100 mg/L Molybdenum 0.00250 U 0.0100 mg/L ' Nickel 0.00220 U 0.0100 mg/L l_ Potassium 0.150 U . 0.500 mg/L Selenium 0.00620 U 0.0100 mg/L -, Sodium 0.400 U 0.500 mg/L Zinc 0.00440 U 0.0100 mg/L -, -- - FINAL This report relates only -to the sample as received'by the laboratory; and'may only be reproduced in full.- ' Page 5 of 12 ENCO www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) -by EPA 6000/7000 Series Methods= Quality Control -Batch &704015 = EPA 3005A---Continued LCS (8]04015-BS1) Prepared: 10/04/2018 09:32 Analyzed: 10/09/2018 11:56 _ Spike Source %REC RPD _-_.- Analvt�_ _----- _=------- - =_ - -----IBe4J41t' Flaa P_OL -LIIL- -Level, _--- Result %REC - Limits __RPD----_-Limit Notes -.- Aluminum -1.88 0.100 mg/L 2.00 94 80-120 Arsenic - _-0.193 _ 0.0100_ = mg/L 0.200 96 80-120 Cadmium 0.0196 0.00100 mg/L 0.0200 98 80-120 Calcium 2.02 0.100 mg/L 2.00 101 80-120 Copper- . _ _, _ _= :- - 0.185 __ _ ,_ ___ ,_ = 0.0100 _ = mg/L ._ 0.200 Lead 0.195 0.0100 mg/L 0.200 98 80-120 _ T Magnesium 1.94 0.100 mg/L 2.00 97 80-120 Molybdenum 0.188 0.0100 mg/L 0.200 94 80-120 Nickel 0.193 0.0100 mg/L 0.200 96 80-120 Potassium ___ 9.60__ _ _____0.500 -_____mg/L__ __ 10.0 96 80-120 Selenium -- 0..196 - - 0.0100 mg/L--- 0.200 - - _- 98- - 80-120 _ - - Sodium 9.64 0.500 mg/L 10.0 96 80-120 Zinc - - 0.198 0.0100 mg/L - 0.200 99 80-120 - Matrix Spike (8104015-MS1) Prepared: 10/04/2018 09:32 Analyzed: 10/09/2018 11:59 Source: CB15429-01 Spike Source %REC RPD Ana<vte Re.4ult Elaa PUL units Level Result %REC Limits RPD Limit Notes Aluminum 1.88 0.100 mg/L 2.00 0.0420 U 94 75-125 Arsenic 0.180 0.0100 mg/L 0.200 0.00760 U 90 75-125 Cadmium 0.0190 0.00100 mg/L 0.0200 0.000360 U . 95 75-125 - Calcium -4.87 0.100 mg/L 2.00 3.15 86 75-125 Copper 0.182 0.0100 mg/L 0.200 0.00160 U 91 75-125 Lead 0.186 0.0100 mg/L 0.200 0.00310 U 93 75-125 Magnesium 3.44 uoo mg/L 2.00 1.68 88 75-125 Molybdenum 0.183 0.0100 mg/L 0.200 0.00250 U 91 75-125 Nickel 0.190 0.0100 mg/L 0.200 0.00390 93 75-125 Potassium 11.0 0.500 mg/L 10.0 1.56 94 75-125 Selenium 0.186 0.0100 mg/L 0.200 0.00620 U 93 75-125 Sodium 12.0 0.500 mg/L 10.0 2.49 95 75-125 Zinc 0.194 0.0100 mg/L 0.200 0.00496 95 75-125 Matrix Spike Dup (8704015-MSD1) Prepared: 10/04/2018 09:32 Analyzed: 10/09/2018 12:01 Source: CB15429-01 - Spike Source - %REC RPD Anal vte Result Elam PQL Units Level Result %REC Limits RPD limit Notes Aluminum 1.84 0.100 mg/L 2.00 0.0420 U 92 75-125 2 20 Arsenic 0.182 0.0100 mg/L 0.200 0.00760 U 91 75-125 1 20 Cadmium--------0.0191" --- - --- 0.00100- -- mg/L -- 0.0200 0.000360 U 95- - 75-125 - 0.3 - - 20 Calcium 4.89 0.100 mg/L 2.00 3.15 87 75-125 0.3. 20 Capper 0.180 0.010D mg/L 0.200 0.00160 U 90 75-125 1 20 Lead 0.191 0.0100 mg/L 0.200 0.00310 U 95 75-125 3 20 Magnesium 3.45 0.100 mg/L 2.00 1.68 88 . 75-125 0.3 20 Molybdenum 0.184 0.0100 mg/L 0.200 0.00250 U 92 75-125 ' 1 20 Nickel 0.189 0.0100 mg/L 0.200 0.00390 93 75-125 0.7 20 -- Potassium 11.0 0.500 mg/L 10.0 1.56 94 75-125 0.1 20 Selenium 0.197 0.0100 mg/L 0.200 0.00620 U -99 75-125 • 6 20 - Sodium 12.0 0.500 mg/L 10.0 2.49 95 75-125 0.6 20 Zinc 0.201 0.0100 mg/L 0.200 0.00496 98 75-125 3' 20 FINAL 7=- - --,This report relates only.to the sample as received by the laboratory, and may only be reproduced in full. Page 6 of 12 www.encolabs.Com. QUALITY CONTROL DATA -- Metals (total -recoverable) -by -EPA 6000/7000 Series Methods - Quality Control - ----- Batch 8JO4015 - EPA 3005A - Continued I Post Spike (8304015-PSI) Prepared: 10/04/2018 09:32 Analyzed: 10/09/2018 12:04 , i _ Source: CB15429-01 Spike Source %REC RPD -?_ _ _ •- .AnaLytL' ._ ' . _ _ Basalt Elan, _P.91:. __1inft_=_ _.Level _ - --Result . __%REC- ---Limits- - RPD _ _ Limit _Notes - - f Aluminum 1.84 0.100 - - mg/L- 2.00 -0;0213, 92 80-120 Arsenic 0.180 0.0100 mg/L 0.200 -0.00101 90 80-120 Cadmium 0.0196 0.00100 mg/L 0.0200 0.0100299 97 80-120 Calcium 4.77 0.100 mg/L 2.00 315 81 80-120 Copper_, -0.179 ' ': 0.0100 mg/L 0.200 70.001.21 89 _80420 - Lead 0.190 0.0100 mg/L 0.200 -0.1000709 95 80-120 Magnesium 3.43 0.100 mg/L 2.00 1.68 87 80-120. Molybdenum 0.187 0.0100 mg/L 0.200 -5.17E-5 93 . 80-120 Nickel 0.188 0.0100 mg/L 0.200 0.00390 92 80-120 Potassium 10.8 0.500 mg/L 10.0 '1.56 92_ 80-120 Selenium 0.187 0.0100 mg/L 0.200 0.000561 93 80-120 r ' Sodium 11.7 0.500 mg/L 10.0 -2.49 92 80-120 Zinc 0.204 0.0100 mg/L 0.200 0.00496 100 80-120 Classical Chemistry Parameters - Quality Control 7771 Batch 8JO2040 - NO PREP Blank (8302040-BLK1) Prepared: 10/02/2018 17:07 Analyzed: 10/02/2018 17:07 Spike Source %REC RPD- Analyte Resul Elm BQL Units Level Result %REC Limits RPD Limit !votes _ Nitrite as N 0.017 U 0.10 mg/L " 17:00 LCS (8302040-BSI) Prepared: 10j02/2018 17:00 Analyzed: 10/02/2018 Spike Source %REC RPD Anal Result Han PM Units Level %REC Limits RPD Limit Notes Nitrite as N 0.99 0.10 mg/L 1.00 99 90-110 LCS (8302040-BS2) Prepared: 10/93/2018 08:47 Analyzed: 10/03/2018 08:47 Spike Source %REC RPD - Anal Yt>: Result flag POL Units Level Result %REC Limits RPD Limit Notes Nitrite as N 1.0 .0.10 mg/L 1.00100 90-110 LCS (8302040-BS3). Prepared: 10/03/2018 08:52.Analyzed: 10/03/2018 08:52 Spike Source %REC RPD Analyte Result Elk OIL Units Level ' Result-, %REC Limits RPD - Limit Notes Nitrite as N 1.0 0.10 mg/L 1.00 100 90-110 Matrix Spike (8702040-MSI) Prepared: 10/03/2018 08:49 Analyzed: 10/03/2018 08:49 Source: CB14231-OIRE1 Spike Source %REC RPD Analyte Resul Elan P-QL 1.1111125. Level Result %REC Limits RPD limit Notes Nitrite as N 7.7 0.50 mg/L 5.00 3.2. 91 90-110 Matrix Spike Dup (8302040-11WIS131) Prepared: 10/03j2018 08:50 Analyzed: 10/03/2018 08:50 f Source: CB14231-OIREi Spike Source %REC RPD Analyte Resul Etas P_QL Units Level' Resin %REC Limits RPD Limit Notes Nitrite as N 8.0 0.50 mg/L 5.00 3.2 96 90-110 3 ' 10 Batch W05001- Same FINAL ---This report relates only to'the sample as received by the laboratory, and may only be'reproduced in full. Page 7 of 12 - �VCO www.encolabs.com QUALITY CONTROL DATA I _I Classical Chemistry Parameters - Quality Control Blank (8706OW131-11(i) - - Prepared: 10/06/2018 11:00 Analyzed: 10/08/2018 12:49 - - - -- -- --_ —_ — - _ Spike Source %REC RPD Anal vte Result Elm P_OL units Level Result' %REC Limits RPD Limit; Notes Total Kjeldahl Nitrogen 0.26. U 0.48 mg/L FEES (8106001-BSI) Prepared: 10/06/2018 11:00 Analyzed: 10/08/2018 12:51 Spike Source %REC RPD AnalResult Elm P_4L MAU Level Result %REC Limits RPD, Limit Notes � Total Kjeldahl Nitrogen 12 0.48 . mg/L 12.1 103 90-110 Matrix Spike (8306001-MS1) Prepared: 10/06/2018 11:00 Analyzed: 10/08/2018 12:54 Source: CB12918-02 Spike Source %REC RPD o Anal vte Result flag P9L Units Level Resul %REC Limits RPD Lima Notes Total Kjeldahl Nitrogen 6.3 0.48 mg/L 4.85 0.26 U 130 90-110 QM-07 ' Matrix Spike (8706001-MS2) Prepared: 10/06/2018 11:00 Analyzed: 10/08/2018 12:59 Source: CB12959-01 Spike Source %REC RPD Anal Yte Result Elm P9L lints Level Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 18 0.48 mg/L 4.85 '12 112 90-110 QM-07 Matrix Spike Dup (8306001-MSD1) Prepared: 10/06/2018 11:00 Analyzed: 10/08/2018 12:56 Source: CB12918-02 Spike Source LiREC RPD -y I_ Anal vte Result flag PQL !)nits Le el o Result /oREC Limits RPD Limit Notes _ J Total Kjeldahl Nitrogen 5.5 -0.48 mg/L 4.85 0.26 U 113 90-110 14 . 10 QM-07, QM-11 Batch 8.706002 - Same Blank (8706002-BLKI) Prepared: 10/06/2018 11:00 Analyzed: 10/08/2018 14:41 Spike Source %REC RPD Anal Result flag P_4L lllliM . Level Result %REC Limits RPD Limit Notes Phosphorus 0.025 U 0.10 mg/L LCS (8706002-BSI) Prepared: 10/06/2018 11:00 Analyzed: 10/08/2018 14:42 Spike %REC Source RPD Analvte Resul[ flay POL nits %REC Result Limits RPD Limit Notes Phosphorus 1.5 0.10 mg/L 1.60 95 80420 Matrix Spike (8706002-MSI) Prepared: 10/06/2018 11:00 Analyzed: 10/08/2018 14:45 Source: CB12918-02 Spike Source %REC RPD Analyte Result Flag POI. !!OILS Level Result . %REC Limits RPD Limit Notes Phosphorus 2.0 D 0.50 mg/L 0.640 1.4 105 80-120 Matrix Spike Dup (8706002-MSD1) Prepared: 10/06/2018 11:00 Analyzed: 10/08/2018 14:46 111 Source:CB12918-02 Anelvte Phosphorus Batch SJO9016 - NO PREP Spike Source %REC I • RPD Result Elan POL !!Bits. Level Result %REC Limits RPD Limit 'Notes 1.9 D 0.50 mg/L 0.640 1.4 89 80-120 5 25 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 8 of 12 1 tsQ www.encolabs.com QUALITY CONTROL DATA (-,_--:-== Classical-Chemiitry=Parameters:- Quality Control-=;— `- - - --- - - _ --Batch B709016-, NO PREP -Continued. . -- _ ...' Blank (8309016-BLKI)' _ _ Prepared & Analyzed: 10/09/2018 14:11 = - T Spike Source %REC RPD :9n1� ---Level- . Result-%REC�-almll£ =RPD-= d1R1Lt = :-l114"- - --_ - Total Solids 0.0050- -= U -- 0.0050- - % by Volume LCS (8709016-BSI) Prepared & Analyzed: 10/09/2018 MAI - Spike Source - - - . %REC RPD -- .-Anal = _----'-- "- _ .-.Result---- Flaa=-- --P91-_- Units_ . - - Level -_ - Result .-`- %REC-=.-Limits - -- -RPD - -` "--Limit- !Votes --- Total Solids' 1200 50. mg/L 1100 106 80-120 `- Duplicate (8709016-DUPl) Prepared & Analyzed: 10/09/2018 14:11 tt Source: 'CB14231-01 Spike Source %REC RPD -- Analvte - --- es I wag. PO ;�-- Unit% Level Result 9/oREC Limits._. RPD.: Limit Notes - Total Solids 0.25 0.0050 % by Volume 0.25 0.2 20 Batch SYIO021- NO PREP. - Blank (8330021-BLK1) Prepared: 30/10/2018 17:15 Analyzed: 10/10/2018 17:15 Spike Source %REC RPD Anal Resin Flag P-QL Units Level Result %REC Limits RPD Limit Notes Ammonia as N 0.045 U. 0.10 mg/L LCS (8310021-BS1) Prepared: 10/10/2018 17:20 Analyzed: 10/10/2018 17:20 Spike Source %REC RPD If Rnall�e Besul Mau OQL lJ IM Level Result %REC Limits RPD )fit Notes 'Ammonia as N 1.1' 0.10 mg/L - 1.00 - 106 , 90-110 - Matrix Spike (8710021-MSi) . Prepared: 10/10/2018 17:25 Analyzed: 10/10/2018 17:25 I Source" C912418-62 " - - Spike Source, %REC RPD Anal 7tte R4.sul Elm POL Units Level Rea£ut %REC Limits RPD Limit Notes Ammonia, as N 0.36 0.10 mg/L 0.389 0.045 U 92 90-110 Mat ix Spike (8310021-MS2) Prepared: 10/11/2018 07:53 Analyzed: 30/11/2018 07:53 Source, CB12962702RE1 Spike Source %REC RPD 9naltfte . ,' Remelt F1a44, PQL Units .Level Result.' %REC, Limits RPD Limit Notes 'Ammonia as N 14 1.0 mg/L 4.00 .11 90 90-110 Matrix Spike Dup (8710021-MSM) Prepared: 10/10/2018 17:27 Analyzed: 10/10/2018 17:27 ' Source: CB12918-02 Spike Source %REC '. RPD Anal vta - - Result F1as POL Units Level Result %REG Limits RPD Limit Notes Ammonia as N . 0.36 0.10' mg/L 0.389 0.045 U. 93 90-110 1 10 Batch MU021- NO PREP 1. . LCS (8311021-BS1) Prepared: 10/11/2018 13:25 Analyzed: 10/11/2018 13:25 I i Spike Source %REC RPD Anallte '. Result.. Flag.. PQL Units. Level ResulE.. %REC. Limits . RPD. Limit Motes Nitrate/Nitrite as N 1.3 0.10 mg/L 1.2'5 . ' . 107' 907110 - - -- _ —FINAL-' This report relates"only to the sample as received by the laboratory, and may only be reproduced in full. Page 9 of 12 = :� am wrwrw.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control - _ Batch W11021 -NO PREP - Continued Matrix Spike (8313021-MS3) Prepared: 10/11/2018 12:13 Analyzed: 10/11/2018 12:13 Source: CB07177-01 Spike Source %REC RPD Anal vte Result flag P_QL Units Level Result ' o/aREC Limits RPD Limit Notes Nitrate/Nitrite as.N 54 10 mg/L . 50.0 5.2 97 90-110 Matrix Spike (8311021-MS2) Prepared: 10/11/2018 14:21 Analyzed: 10/11/2018 14:21 Source: CB12918-02RE1 Spike Source %REC RPD �nalYte Result Flag PQL Units Level Result %REC Limits RPD Notes Nitrate/Nitrite as N 35 E 1.0 mg/L 5.00 31 86 90-110 QM-07 Matrix Spike Dup (8713021-MSD3) Prepared: 10/11/2018 12:15 Analyzed: 10/11/2018 12:15 Source:CB07177-01 Spike Source %REC RPD Analvte Result Pla_u POL Units Level Result o/aREC Limits RPD Limit Notes _ Nitrate/Nitrite as N 57 10 mg/L 50.0 5.2 103 90-110 5 10 FINAL - This report relates only to the sample as received'by the laboratory, and may only be reproduced in full. Page 10 of 12 - -FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the .associated method blank.._. i D The sample was analyzed at dilution.. _ 7 - _ The reported value,is between the laboratory -method. --detection limit (MDL) and the laboratory_method - reporting limit (MRL), adjusted Wactual.sample-preparatioh,data-and moisture-content,,where applicable. -- • U The analyte was analyzed for but not detected to the level shown,. adjusted for actual sample preparation data and moisture content, where applicable. -. E The'concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL . - .Method. Reporting Limit.. The MRL is roughly equiv-alent.to the practical-quantitation-limit_(PQL). and is based on the low point of the calibration curve,when applicable, sample preparation factor, dilution factor, and, in the case of soil samples,, moisture content. PQL PQL: Practical Quantitation Limit. The PQL-presented is the laboratory MRL. N - The analysis indicates the presence of an analyte for which there is presumptive evidence_(85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed -between the primary and secondary GC column. The lower concentration is. reported. QM-07 The spike recovery was outside acceptance limits -for the MS and/or MSD. The batch was - accepted, based on acceptable LCS recovery. QM-11 Precision between duplicate matrix spikes of the same sample was outside acceptance limits. Fl_ `�.-- - k. I This report relates only to the sample as receivedby the laboratory, and may only -be reproduced in full: - I ENVIRONMENTAL CONSERVATION LABORATORIES CHAIN-OF-CUST b Y RECORD www.encolabs.com 10775 Central Port Dr. 46t0 Executive Park Gcun; Suite f tt t02-Av;oa35wreds Industrial Ct., Orlando, FL'32824 3acksarraiite, FL=--2f8.6059 Cary, HC P75ti (407) M-5314 .Fax (407) 850.6S45 (904) 296-30it7 Fax (904) 296-62f0 (9191467-3630 Fax (9f 9) 4E?-35t5 Page of Client Name Protect Number Requested Analyses- Requested Turnaround Novozymes North America Q40008) [none. P Times Address Project NamaiDes.:` _ _ _ ' Note : Resh requests Subject to -7`7 Pel GhepIS Church .Road i< onthl eekOne '-SW � accaplancebythe facility Ciiyl$TlZlp. PO a ! Billing into Freni<iirtton, NG 275-5 3300360507 � _Standard Tel Fax Reporting Contact (919) 494-3000 Scott Creech - Expedited Samplers) Name, Afffliallon{Print) Billing Contact - -,Accounts Payable � V t 5 DueSw Samplor(e} Siitrrsture Site Location ITime Zone Lab Wdikorddr SZ t' s I; _ r -y�e!pl Preservatferi (&w Codes) (Combine as rraceaswy) .I G -- . - - - - Collection . Matrix Total u ai ttem a Sample ID (Fleld ldcntillcatfon) Calleclion Date Time Camp Grab (see codes) Co rea neaSS3tiip!S GOftlfrtent5 ' 1 -SL 4. .. K. . . <--Total n of Cnnfainers Sample Kit Prepared By D�rat]�emme c Refmqui - By DateMme - Reeeked By , DateMme Comment>rSpeclal.Reponfng Requirements ReRngiri_hsd i DateMme R {ev Date tme F ReiinquishedBy Dateiiime J Received By. Datefrune - - - - - Caofer its & Temps on Receipt [- Condition Upon Receipt VAcceptable' Unacceptable rmamx : uw-ureunowater 5u-bou uw-unnxing water 5t-5eaimen1-bw-tzunarsa water wvr-vle9teviater A -Air v-uMer (damn to comments) Preservation: Wee H-HGl f7-HNt33 S-H2504• ND-NeOH G-Other(datail in comments) Note : Atilsamples submitted to ENCO Labs are in accordance with the tents and aondifions fisted an the rwerse of this form; unfass prior virilten agreements exist i - C_ Sample Preservation Vdrifidatibn ENCO Cary Work Order: C814232 Project: Month[ Week One - SBM Client: Noyozymes North America (N0008)' Project#: [none] ogged In: 02-Oct-1 8 11:48 Logged'By: Rachel.Ann Yiqnish Preservation Check -Performed By: Dateffirne: CB14232.01 Cont Type eM�jj'- —�`!Pr6t, (0,H) )KChecked h 14� Re-gent.,u ON -A d A -250ml-P+H2904 <2 Y'l N, / NA -Y- N NA-- B 250mLP+HNO3 <2 Y N.1 NA N NAti� 4, _11f �j Reagent Name ID' Rea Qefit Name ID 1 3 pH Strip ID: PH Strips C7.16820- .C.1eImnt\PrinT%WKq -Pi U�=1 V'OLIV3 M:l pt ,Reagefit Name ID 5 E 61 Page 1 of 1 E.-NNCO-Lah 0 V a to r11 1"O'S, AccUrate. Timely. lie' ons ve, Innovative. 102-A Woodwinds Industrial Court.. -'-- Cary NC, 27511 _ -Phone: 919.467.3090 FAX: 919.467.3515- - - - — - - Wednesday, November 14, 2018 Novozymes North America (NO008) Attn: Scott Creech 77 Perry Chapel Church Road Franklinton, NC 27525 RE: (Laboratory Results for Project Number: [none], Project Name/Desc: Monthly - SBM ENCO Workorder(s)h C615975 - - _- Dear Scott Creech, Enclosed is a copy of your laboratory report for test -samples received by our laboratory on . Tuesday, November 6, 2018. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except, as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories.. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Chuck Smith Project Manager . Enclosure(s) FINAL -This report relates'only to the sample as received by the laboratory, and may only be reproduced In full. Page 1 of 8 CSNg www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE - Client1D:=-SBM==- - _ -_- - _--- LaTiD-C815975-01- Sampled: 11/06/18-'07:30- - Received: 11/06/18 09:00 Paramete -Hold-Date/Time(s)- - Prep Date/Time(s) _ Analysis Date/Time(s) SM 254OD-2011 NO PREP 11/13/18 11/12/18 13:17 11/12/18 13:17 -- -- - ----SM-5210 B-2011 - ---NO--PREP -- --- — -- 1-1/08/-18-07 30 --- - - - 11/07/18 09:56--- - - 11/07/18 09:56- --- -- - _- _ - SM 5220D-2011 ---- --Same . — - 12/04/18 -- -- -- 11/08/18--09:52— - ----•11/OS/18 15:40 L� FINAL =- -_ _ --This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 2 of 8 - — �CM . 4 www.encolabs.com i _• SAMPLE DETECTION SUMMARY. Client ID: : SBM - - - — -- — = __�__- - _ . ,_'_._Lab ID: CB15975-01": - - ----- - __ ADB11Cl Results ", . flag .JHU -- EQL units Method - _ .Notes ' Biochemical Oxygen Demand - 8800 '2.0 2:0 mg/L SM 5210 B-2011 Chemical Oxygen Demand 28000 - 400 400 mg/L SM 5220D-2011 -- Total Suspended Solids i { _ - 33000 ' - -5000- : - 5000- mg/L SM 254OD-2011 - - �60 www.encolabs.com ANALYTICAL RESULTS Description: SBM Lab Sample ID:CB15975-01 Received: 11/06/18 09:00 Matrix: Sludge Sampled:11/06/18 07:30 Work Order: CB15975 Project: Monthly - SBM Sampled By: VINCE WILKINS Classical Chemistry Parameters ^ - ENCO Cary ceiSfied XUTAe [NC 5911 Analvte MAS Numberl- - - Results Flaa- - Units -- DF MDL- P L Batch Method Analwed By Notes Biochemical Oxygen Demand^ 8800 mg/L 1 2.0 2.0 8K07001 SM 5210 B-2011 11/07/18 09:56 30C Chemical Oxygen Demand^ 28000 mg/L 40 400 400 8K08006 SM 522OD-2011 11/08/18 15:40 )OC Total Suspended Solids^ 33000 mg/L 2000 5000 5000 81<12022 SM 254OD-2011 11/12/18 13:17 OMR FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 8 _ EI\iCQ www.encolabs.com —' QUALITY CONTROL ;DATA- - - — = - =_= Classical Chemistry-Parameters.--Quality-Control---- - - r. . ---_ _— - - Batch 8K07001---N0-PREP =--------_ _ _—_--_- - = Blank (8K07001-BLK3) Prepared &Analyzed: 11/07/201&09:56 Spike Source %REC RPD - Anal Yi� - - _ -- - - -- ------.=Result—Ela4" : P91=--9�iSs= - - -Level _ Result %REC RPD limit . _ _ . 'Notes Biochemical Oxygen Demand . 2.0 U 2.0 mg/L LCS (SK07001-BS3) Prepared & Analyzed: 11/07/2018'09:56 Spike Source %REC RPD Anal Result ELM PQL Units Level Result %REC Limits RPD, Limit Notes Biochemical Oxygen Demand 200 2.0 mg/L 198 102 85-115 Duplicate (8KO7001-DUPi) Prepared & Analyzed: 11/07/2018 09:56 Source: CB15183-01 Spike Source %REC _ RPD Anal vte - -- Re�iu t. =FL4 °.. jk% 1nJt%_ _--- :Level __ '__..Result.. _ %REC.-- Limits. - -. RPD-- - -- Wit- - - - .r{Qfgs' . Biochemical Oxygen Demand 3.8 2.0 mg/L 3.8 2 30 Batch BK08006 - NO PREP - Blank (8K08006-BLK1), Prepared: 11/08/2018 09:52 Analyzed: 11/08/2018 15:40 Anal Result Elan P91 Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 10 U 10 mg/L LCS (8K08006-BSS) Prepared: 11/08/2018 09:52 Analyzed: 11/08/2018 15:40 Spike Source. %REC RPD Anal ldL' Result Flag PQL Units Level Result %REC Limits RPD Lippt Notes Chemical Oxygen Demand 480 10 mg/L 500 9790-110 Matrix Spike (81(08006-MS1) Prepared: 11/08/2018 09:52 Analyzed: 11/08/2018 15:40 Source: CB08935-01 Spike Source %REC RPD Anal Yte Result.. Flan, P9L Units Level Result, o/aREC Limits- RPD Limit Notes ChemicalOxygen'Demand 540 10.. mg/L 526 56 92 90-110 Matrix Spike Dup (8K08006-MSDi) Prepared: 11/08/2018 09:52 Analyzed: 11/08/2018 15:40 Source, CB08935-01. Spike Source %REC RPD Result Elan P(X Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand' 540 10 mg/L 526 56 92 90-110 0.4 10 ' Batch 8K12022 - NO PREP Blank (8K12022-BLKi) Prepared & Analyzed: 11/12/2018 13:17 Spike Source %REC RPD Anal vle Result Rau PQL Units Level Result %REC Limits RPD Limit Notes Total Suspended Solids 2.5 U 2.5 mg/L LCS (8K12022-BS1) Prepared & Analyzed: 11/12/2018 13:17 Spike Source %REC RPD 9DaLVSe Result Flag. P91 Units Level Remit %REC limits RPD Limit Notes Total Suspended'Solids 100 2.5 mg/ .L 100 .100 80-120 FINAL - - - - - -This report relates only to the sample as -received by the.laboratory, and may only be reproduced in full. - - Page 5 of 8 - www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters =-Quality=Control= Batch 8K12012 - NO PREP --Continued - - - - — Duplicate (8K12022-DUP-1)__=—_ _ _ _— —_ _ __ — Prepared &Analyzed: 11/12/2018 13:17 Source:CB15201-01 _ Spike Source %REC RPD Anal vte _ _ . _ _ _ = Result---Flaa POL =_ —Units-= Level Result %REC _ Limps - RPD _ Lim(t . _ Notes Total Suspended Solids 1000 100 mg/L 1100 10 20 Duplicate (8K12022-DUP_2)_ __ _---- __ _ — Prepared & Analyzed: 11/12/2018 13:17 Source: CB15975-01 Spike Source %REC RPD Analvte Result flag- P91 -Units Level Result %REC Limits RPD Limit Notes Total Suspended Solids 35000 5000 mg/L 33000 4 20 r- 1 FINAL - - - - --This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 6 of 8 www.encolabs.com i ;_FLAGS/NOTES.AND-DEFINITIONS=. B The analyte was detected in the associated method blank. . - - D The sample was analyzed at dilution. ] The reported value; is between the laboratory method -detection limit (MDQ and the laboratory method L�.. F}_._. _ reporting limit (MRL), adjusted for actual.sample preparation_data and moisture content; -where applicable. U The analyte was analyzed :for but not -detected -to the level shown, adjusted_'for actual sample preparation data and moisture content, where applicable. E , The- concentration indicated -for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate: MRL . Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples,. moisture content. PQL PQL: Practical'Quantitation Limit., The PQL presented is the laboratory MRL. - y N - The analysis indicates the presence of. an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 250% concentration difference was observed betwee.n-the primary_ and secondary GC column. The lower concentration is reported. • • 10776 Central Port Dr. 4810 Executive Park -Court, Suite-111 102-A Woodwinds Industrial CL. Orlando, FL 32824 Jacksonville, FL 322166069 Cary. NC 27511 L (407) 826-5314 Fax (407) 850-6945 (904)295-3067 Fax (904)296-6210 (919)467-30--0 Fax (919)467-3515 Page Of Client Name Nmozymes North Amedca'(NO008) Project Number [none] Requested Analyses Requested.Turriaround Times Not . a :Rush requests subject to acceptance by the facility Standard. Expedited Due CM to co __ 0 C%1 La .0 04 Address 7.7' Perry Chapel -Church Road Project NamefDesc Monthly-. SBM City/sTop Franklinton, NC 27525 PO # I Billing Into 3800360507 Tel . - (919)49473000 Fax Reporting contact Soot Creech Sampler(s) Name, Affiliation (Print) lllwc,e k1,A-4,r15 Btlin Contact ecounts- Payable Saiiipfer(s) Signature Jdl;t'e� 4 Site Location /Time Zone Lab Workorder , -459 Preservation (See Codes) (Combine as necessary) Item # Sample 10 (Field, Identification Collection Date Collection Time Comp I Grab Matrix (see codes) Total 4 of 7 Containers Sample Comments L 7 A -7- 7 I <—, Total 9 of rnnt;iinpi-, Sample Kit Prepared By i ,Tme Datarri M7 Daterri Re -calved By, > �6 Dateffirrio Comments/S ecial Reporting Requirements p Relinquished By Datarrime Received By Datefrimo/' Ar Relinquished By Datefrime Received By Daterrim Coder.4s & Terrips on .Receipt Can 7Acdfi U n,Receipt Acceptable Unacceptable Q=jnmm Qunacuvvarar ww-viasiewmer A-wr u-inner jaeraom comments) Preservation: Hce H-HUI H-HIS103 5-H2Zi04 NO-NaOH 0-01her (detail in comments), Note: All samples submitted to ENCO Labs are in accordance with the terms and conditions listed on the reverse of this form -unless prior written agreements exist S.a' m p- Fe" Preservation Verification e Nait' 16 ENCO Cary C� Work. Order. CB15975 Project: Monthly - SBM' Client: Novozymes North America (N0008) Project #: [none] Logged In: 06-Nov-1 8 10: ' 40 Lodged -By: John C King Preservation Check Performed By: Date/Time: CBI 5975-01 " q M A. '260ml_P-�H2SO4 <2--- Y Vb/ NA (7)/ N t NA, _.. - EN ora 102-A Woodwinds Industrial Court _ -- — - ,--- -= -- ---- - - -- - -- -- Cary NC, 27511 - Phone: 919.467.3090- - -FAX:: 919.467.3515 --= - - Frida , November 16,-201'g • -:: , - - - _ - _ : - I Novoiymes North America (N0008) 7 _ _: - Attri: Scott Creech 77 Perry Chapel 'Church Road . Franklinton, NC 27525 RE:, Laboratory Results for Project Number: [none], Project Name/Desc: Monthly - Week One - SBM ENCO Workorder(s Dear Scott Creech; Enclosed is a copy of your laboratory report for test samples received by our laboratory on . Tuesday; November 6, 2018.' Unless otherwise noted in an attached project narrative, all samples were'received'In. acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted.' The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable., This report shall not be reproduced except in, - --- - full, without the written approval of -the Laboratory. -- - - - - - - This report contains only those analyses performed by Environmental' Conservation' Laboratories, Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under,separate cover. If you have any questions.or require further' information, please do not hesitate to contact.me. Sincerely, . Chuck Smith. Project Manager Enclosure(s) FINAL This report relates only to the'sample as received by the laboratory, and may only.be reproduced In full. Page 1 of 12 - ufvwu.encolabs.com - -- -- ------ - SAMPLE -SUMMARY -/LABORATORY CHRONICLE Received: 11/06/18 09:00 Client ID: SBM - --_-W1536CB35977-01= Sampled: 11/06/18 07:30 Parameter Preparation-- --- __ _ Hold-Date/-Time(s)— - Preo Date/Time(s) Analysis Date/Time(s) CSU Method NO PREP_- 08/01/21 11/13/18 10:18 11/14/18 16:09 EPA 350.1 -NO-PREP- -- —--12/04/18 -- - - - 11/07/18 11:39 11/07/18 11:39 EPA 351.2 Same -- - 12/04/18 - 11/09/18 10:55 11/12/18 11:10 EPA 353.2 NO PREP 11/08/18 07:30 - 11/06/18 16:52 11/06/18 16:52 EPA 3512 -NO�REP� 08/O1/21 11/07/18 11:34 11/07/18 13:45 EPA 365.4 Same 12/04/18 11/09/18 10:55 11/12/18 13:03 EPA 6010D EPA 3005A 05/05/19 11/13/18 10:18' 11/14/18 14:10 EPA 7470A EPA 7470A 12/04/18, 11/14/18 14:42 11/15/18 16:16 SM 254OB-2011 NO PREP 11/13/18 11/09/18 13:09' 11/09/18 13:09 FINAL -- - This report relates only -to the sample as received by the laboratory, and may only be reproduced in•full. Page 2 of 12 ( I , www.encolabsxom SAMPLE DETECTION SUMMARY - -' Client ID: SBM Lab ID:- CB15977-01 - -'. AB8lyte ... -- - - Results Elan MU -----_PS?1. -_Units Method-.. ----_-Notes Aluminum - Total _ 121 _ _ - -_ 0.420__ _ _ 1.00 mg/L EPA 6010D Ammonia as N 88 D 4.5 10 mg/L EPA 350.1 -- Calcium Total --2930 - - -0.390 1.00 - mg/L EPA 6010D Copper - Total 0.171 0.0160 0.100 mg/L EPA 6010D - Magnesium - Total 56.6 •0.290 1.00 mg/L EPA 6010D - - ' - Molybdenum -Total - - �-', ^- - ` '-"0.0567 - ` ] - -- -0.0250 - - 0.100 "mg/L -- EPA 6010D Nickel -Total -0.0512 3 0.0220 0.100 mg/L EPA 6010D Nitrate as N - _ 9.3 _ _ 0.025 0.10 mg/L EPA 353.2 Nitrite as IN 0.67 - 0.017 0.10 mg/L EPA 353.2 Phosphorus 670 D 12 50 mg/L EPA 365.4 Potassium - Total 582 1.50 5.00 mg/L EPA 6010D Sodium - Total 138 4.00 5.00 mg/L EPA 6010D Sodium Adsorption Ratio 0.696 [blank] CSLI Method Total Kjeldahl Nitrogen 1900 D 65 120 mg/L EPA 351.2 Total Solids 4.3 0.25 0.25 % by Volume SM 2540B-2011 Zinc - Total 0.699 0.0440 0.100 mg/L EPA 6010D FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 12 CS Nik co www.encolabs.com ANALYTICAL RESULTS Description: SBM Lab Sample ID:CB15977-01 Received: 11/06/18 09- Matrix: Sludge Sampled: 11/06/18 07:30 Work Order: CB15977 Project: Monthly - Week One - SBM Sampled By:VINCE WILKINS Metals by EPA 6000/7000 Series Methods ^ - ENCO City certified analyte [NC 59v Analyte rCAS Numberl - Results -Flan Units DF MDL POL Batch Method nal A vied By Notes Mercury[7439-97-6]A 0.000750 U mg/L 5 0.000750 0.00100 BK14044 EPA 7470A 11/15/18 16:16 NMN Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] AnalM [CAS Numberl Resultsfin Units PE MU ps], Bch Method Analyzed py Notes Aluminum [7429-90-5]^ 121 mg/L 10 0.420 1.00 8K13011 EPA 6010D 11/14/18 14:10 JDH Arsenic[7440-38-2]A 0.0760 U mg/L 10 0.0760 0.100 81<13011 EPA 6010D 11/14/18 14:10 JDH Cadmium [7440-43-9]A 0.00360 U mg/L 10 0.00360 0.0100 BK13011 EPA 6010D 11/14/18 14:10 JDH Calcium [7440-70-2]^ 2930 mg/L 10 0.390 1.00 8K13011 EPA 6010D 11/14/18 14:10 JDH Copper[7440-50-8]^ 0.171 mg/L 10 0.0160 0.100 8K13011 EPA 6010D 11/14/18 14:10 JDH Lead [7439-92-1]A 0.0310 U mg/L 10 0.0310 0.100 8K13011 EPA 6010D 11/14/18 14:10 JDH Magnesium [7439-95-4]^ 56.6 mg/L 10 0.290 1.00 8K13011 EPA 6010D 11/14/18 14:10 JDH Molybdenum [7439-98-7]^ 0.0567 J mg/L 10 0.0250 0.100 8K13011 EPA 6010D 11/14/18 14:10 JDH Nickel[7440-02-0]^ 0.0512 J -. mg/L - 10- 0.0220 0.100 8K13011 EPA 6010D 11/14/18 14:10 JDH Potassium [7440-09-7]^ 582 mg/L 10 1.50 5.00 8K13011 EPA 6010D 11/14/18 14:10 JDH Selenium [7782-49-2]A' 0.0620 U mg/L 10 0.0620 0.100 81(13011 EPA 6010D 11/14/18 14:10 JDH Sodium [7440-23-5]^ 138 mg/L 10 4.00 5.00 8K13011 EPA 6010D 11/14/18 14:10 JDH Zinc[7440-66-6]^ 0.699 mg/L 10 0.0440 0.100 8K13011 EPA 6010D 11/14/18 14:10 JDH Classical Chemistry Parameters ^ - ENCO Cary certified ana#te [NC 591] Analvte ICAS Numberl Results Ran Units DF MDL PO6 Batch Method Analyzed vied Notes Ammonia as N [7664-41-7]^ 88 D mg/L 100 4.5 10 8K07005 EPA 350.1 11/07/18 11:39 JU Nitrate as N [14797-55-8]^ 9.3 mg/L 1 0.025 0.10 8K07028 EPA 353.2 11/07/18- 13:45 JLl Nitrite as N [14797-65-0]^ 0.67 mg/L 1 0.017 0.10 8K06029 EPA 353.2 11/06/18 16:52 JLJ Phosphorus[7723-14-O]^ 670 D mg/L 500 12 50 8KO9007 EPA 365.4 11/12/18 13:03 JU Sodium Adsorption Ratio 0.690 [blank] 1 8K13011 CSU Method 11/14/18 16:09 JDH Total Kjeldahl Nitrogen^ 1900 D mg/L 250 65 120 8K09006 EPA 351.2 11/12/18 11:10 JL1 Total Solids^ 4.3 % by Volume 50 0.25 0.25 8K09027 SM 254OB-2011 11/09/18 13:09 OMR r L FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 12 QUALITY.CONTROL=DATA- __ - Metals by EPA 6000/7000 Series -Methods - Quality Control - Batch SK14044-- EPA 245.1 - - Blank (SK14044-BLKl) Prepared: 11/14/2018 14:42 Analyzed: 11/15/2018 15:44 ,• .,` Spike Source %REC RPD Result F16a PQL _ Units -_Level- Result - %REC-Liffo - RPD__ LIID11 --Notes - Mercury 0.000150 U 0.000200 mg/L LCS (SK14044-BS1) - Prepared: 11/14/2018 14:42 Analyzed: 11/15/2016 15:47 Spike Source %REC RPD Anal 1(Ye Result Elaa POL Units. Level jgsy& %REC Limits RPD Limit Notes Mercury 0.00531 0.000200 mg/L 0.00500 106 80-126 Matrix Spike (SK14044-MSi) Prepared: 11/14/2018 14:42 Analyzed: 11/15/2018 15:52 Source: CB16623-01 Spike Source %REC RPD . Analvte . _- Result E&O P_QL units Level Resu %REC Limits RPD Lhn t Motes Mercury 0.00559 0.000200 mg/L 0.00500 0.000150 U 112 75-125 I.Mabrix Spike Dup:(81(14044-MSD1) _ _ Prepared: 11/14/2018 14:42 Analyzed: 11/15/2018 15:55 = Source: CB16623-01 Spike Source %REC RPD Anal yte Result Elaq M Units Level Result %REC Limits RPD Limit totes Mercury 0.00531 0:000200 mg/L 0.00500 0.000150 U 106 75-125 5 25 Post Spike (SK14044-PS1) Prepared: 11/14/2018 14:42 Analyzed: 11/15/2018 16:03 Source: C016623-01 Spike Source %REC RPD 9oalyte Besul rim PM units Level Result %REC Limits RPD limit Notes . Mercury 5.27 0.200 ug/L 5.00-0.0430 105 75-125 Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch SK13011- EPA 3005A Blank (8K13011-BLKl) Prepared: 11/13/2018 10:18 Analyzed: 11/14/2018 13:35 Spike Source %REC RPD -Analytg Result Ela_q POL Units Level Result o/oREC Limits RPD Limit Notes Aluminum 0.0420 U 0.100 mg/L Arsenic . 0.00760 U 0.0100 mg/L Cadmium 0.000360 U 0.00100 mg/L Calcium 0.0390 U 0.100 mg/L Copper 0.00160. U 0.0100 mg/L Lead 0.00310 U 0.0100 mg/L Magnesium 0.0290 U 6.100 mg/L Molybdenum 0.00250 U 0.0100 mg/L Nickel 0.00220t U 0.0100 mg/L Potassium 0.150 U 0.500 mg/L Selenium 0.00620 U. 0.0100 mg/L Sodium 0.400 U 0.500 mg/L Zinc 0.00440 U 0.0100 mg/L LCS (8K13011-BSS) Prepared: 11/13/2018 10:18 Analyzed: 11/14/2018 13:41 Spike Source- a/oREC RPD Anal Result Elm P_QL units Level Result a/oREC Limits RPD Limit Notes Aluminum 1.94 0.100 mg/L 2.00 97 80-120 Arsenic . 0.185 0.0100 mg/L 0.200 93 ' 80-120 . FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 5 of 12 F1JVC0 www.encolabs.com - ----- -- ----------QUALLT-Y-CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control . Batch BK13011 - EPA 3005A---00ntinued - - - - - LCS (BK13011-BS3) Continued Prepared: 11/13/2018 1 0: 18 Analyzed: 11/14/2018 13:41 - -- Spike Source %REC RPD 9oaLlttE _ -- - - Result-- Elaa -- M - __ Units Level_ %REC- Rt�e�JF. _- - Limits.- RPD -- --- . Llellt ---- Notes- Cadmium 0.0195 0.00100 mg/L 0.0200 97 80-120 Calcium , - _ _ 1.97-_-- - ___ - - -_-0.300-____-_ mg/L - _ ' 2.00 98. 80-120 Copper ----- 0.182 0.0100 mg/L 0.200 91 80-120 Lead 0.189 0.0100 mg/L 0.200 95 80-120 -Magnesium _ 1.88 0.100_ - _ mg/L 2.00 94 80-120 Molybdenum 0.187 0.0100 mg/L 0.200 94 80-120 - - Nickel 0.193 0.0100 mg/L 0.200 97 80-120 Potassium 9.54 0.500 mg/L 10.0 95 80-120 Selenium - --0.-190 -- - ' 0-.0100 ---mg/L 0.200 95 80-120 - -1 Sodium _ - _ - 9.69 0.500- mg/L 10.0 97 80-120 Zinc 0.199 0.0100 mg/L 0.200 99 80-120 Matrix Spike (8K13011-MS1) Prepared: 11/13/2018 10:18 Analyzed: 11/14/2018 13:43 Source: C616043-01 - -- Spike Source - - %REC RPD Anale Resul PQL Units Level Result %REC Limits RPD Limit Notes Aluminum 6.26 0.100 mg/L 2.00 3.64 131 75-125 QM-07 Arsenic 0.190 0.01d0 mg/L 0.200 0.00760 U 95 75-125 Cadmium 0.0197 0.00100 mg/L 0.0200 0.000360 U 99 75-125 Calcium 3.94 0.100 mg/L 2.00 1.97 98 75-125 Copper 0.183 0.0100 mg/L 0.200 0.00172 91 75-125 Lead 0.197 0.0100 mg/L 0.200 0.00343 97 75-125 Magnesium 2.60 0.100 mg/L 2.00 0.713 94 75-125 Molybdenum 0.191 0.0100 mg/L 0.200 0.00250 U 95 75-125 Nickel 0.196 0.0100 mg/L 0.200 0.00245 97 75-125 Potassium 10.3 0.500 mg/L 10.0 0.821 95 75-125 Selenium 0.187 0.0100 mg/L 0.200 0.00620 U 94 75-125 Sodium 28.8 0.500 mg/L 10.0 19.8 90 75-125 Zinc 0.217 0.0100 mg/L 0.200 0.0156 101 75-125 Matrix Spike Dup (8K13011-MSD1) Prepared: 11/13/2018 10:18 Analyzed: 11/14/2018 13:46 Source: CB16043-01 Spike Source %REC RPD Anal Result Elm PQL Units Level Result %REC Limits RPD Limit Notes Aluminum 6.29 0.100 mg/L 2.00 3.64 132 75-125 0.5 20 QM-07, Arsenic 0.191 0.0100 mg/L 0.200 0.00760 U 95 75-125 0.4 20, Cadmium 0.0202 0.00100 mg/L 0.0200 0.000360 U 101- 75-125 2 20 Calcium 3.98 0.100 mg/L 2.00 1.97 100 75-125 1 20 Copper 0.186 0.0100 mg/L 0.200 0.00172 92 75-125 1 20 Lead 0.191 0.0100 mg/L 0.200 0.00343 94 75-125 3 20 Magnesium 2.61 0.100 mg/L 2.60 0.713 95 75-125 0.3 20 Molybdenum 0.195 0.0100 mg/L 0.200 0.00250 U 97, 75-125 2 20 Nickel - 0.200 0.0100 mg/L 0.200 0.00245 99 75-125 2 20 Potassium 10.4 0.500 mg/L 10.r0 0.821 95 75-125 0.7 20 Selenium 0.198 0:0100 mg/L 0.200 0.00620 U 99 .75-125 6 ' 20 Sodium 29.4 0.500 mg/L 10.0 19.8 96 75-125 2 ' 20 Zinc 0.222 0.0100 mg/L 0.200 0.0156 103 75-125 2 20 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 6 of 12 www.encolabs.com. QUALITY CONTROL -DATA ' Metals (total-recoverable)=byLEPA 6000/7900 Series Methods - Quality Control -- -__- Batch SK13011- EPA 3005A -Continued -- - Post Spike (8K13011-PS1) _.. _.. _ '._ Prepared: 11/13/2018 10:18 Analyzed-' 11/14/2018 13:48 _ Source: CB16043-01 Spike Source • b/oREC RPD --'_---- -- Analldg Level ---Re�-%REC «Limits=RP_D;"LIIDLt=- - _M4=: ----- Aluminum . 5.88 0A00 - mg/L 2.00 3.64 112 _ 80-120 . Arsenic 0.190 0.0100 mgJL 0.200 0.000982 95 80-120 • -- -- .-- Cadmium - - 0.0198 -0.00100 - mg/L 0.0200 0.000129 98 80-120 Calcium 3.90 . 0.100 mg/L 2.00 1.97 96 80-120, Copper 0.183 0.0100 mg/L 0.200 0.00172' 91 80,120 Lead :0.190 0.0100 mg/L 0.200 0.00343- 93. 80-120- _ Magnesium 2.55 0.100• mg/L 2.00 0.713 92 80-120 Molybdenum :0.192 0.0100 mg/L' 0.200 2.39E-5, 96' 80-120 Nickel .0.199 0.0100 mg/L 0.200 0.00245 9$ '. 80-120 .. Potassium 10.2 0.500 mg/L 10.0- 0.821- - •' 94 80-120 Selenium Sodium 0.205.' 28.5 , 0.0100 0.500 mg/L mg/L 0.200, 10.0 -0.00135 '19.8 103 87. -80-120" 80-120 Zinc -- ------ 0.219',- 0.0100 mg/L 0.200--- 0.0156 . -102 80-120 - Classical Chemistry Parameters - Quality Control Batch SK06019 - NO PREP LCS (811(06019-BSI) ' . Prepared: 11/06/2018 13:25 Analyzed: ll/06/2018 13:25 Spike Source %REC RPD Anal Ressllt Elarr PQL Units Level Result %REC Limits RPD blmlt Notes Nitrate/Nitrite as N 1.3 0.10 mg/L 1.25 101 90-110 `' Matrix Spike (8K06019-MSl) ' Prepared: 11/06/2018 13:49 Analyzed: 11/06/2018 13:49 Source: CB15976-01 Spike 'Source %REC RPD Anal vte Besul -Elan- -P-QL• Units Level Result' . A/oREC'. ;Limits RPD Wit:,. Notes Nitrate/Nitrite as N '28 2.0 mg/L 10.0 19 90 90-110 Matrix Spike (SK06019-MS2) Prepared: 11/06/201.8 13:54 Analyzed: 11/06/2018 13:54 Source: CB15976-02_ . C Spike Source "/oREC RPD Anal Yffi Result Elan P9b . Units Level Result '"/oREC LWIjtg RPD LjBI[t Notes- Nitrate/Nitrite as N 16 1.0 mg/L 5.00 12 71 90-110 QM-07 Matrix Spike Dup (8K06019-MSD3) .' Prepared: 11/06/2018 13:51 Analyzed: 11/06/2018.13:51.-, Source: CB15976-61 Spike Source: %REC RPD ' ' Anal ldg Result Elan P-QL Units Level Result o/oREC 'UrrIf RPD. LiMit , Notes Nitrate/Nitrite as N 29 2.0 mg/L 10.0 19 . '95 90-110 2 10' Batch SK06029 - NO PREP j Blank ill)6029-BLK1) Prepared: 11/96/2018 16:42 Analyzed: 11/06/2018 16:42 Spike Source %REC RPD- . Analvte Result flagi P9L-- units .. . Level Result .. "/oREC_ Limits _, RPD- . imit Notes Nitrite as N -0.017 U 0.10, mg/L LCS (SK06629-6Sl) Prepared: 11/06/2018 16:55 Analyzed: 31j06/2018 16:55 Spike Source %REC RPD �J Anal Re;:tllt E[im PM Units Level Result %REC Limits RPD' Limit Notes FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full., Page 7 of 12 a Nkc� www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 8K06029 - NO PREP - Continued, LCS (8K06029-BSI) Continued Prepared: 11/06/2018 16:55 Analyzed: 11/06/2018 16:55 APailvte Result Elm Nitrite as N 1.0 F-QL 0.10 Spike Source %REC unm Level Result %REC Limits ROD mg/L 1.00 103 90-110 RPD Limit Notes Matrix Spike (811(06029=MS1) Prepared: 11/06%2018 16:44 Analyzed: 11/06/2018'16:44 Source: CB15132-01 Anal lde Result flag Nitrite as N 0.97 PQL 0.10 Spike Source a%REC Units Level Result %REC limits RPD mg/L 1.00 0.017 U 97 90410 RPD Limit Notes Matrix Spike (8K06029-MS2) Prepared: 11/06/2018 16:47 Analyzed: 11/06/2018 16:47 Source: CB16251-01 Spike Source %REC RPD Analvte Re£ul Flaa P_OL Units, Level Result %REC Limits RPD Limit Notes Nitrite as N 0.84 0.10 mg/L 1.00 0.017 U 84 90-110 QM-07 Matrix Spike Dup (SK06029-MSD3) Prepared: 11/06/2018 16:45 Analyzed: 11/06/2018 16:45 Source: CB15132-01 _ Spike Source,%REC RPD - Anal tde - Result flag P91 Units Level Result„ - o/aREC, Limits RPD Limit Notes Nitrite as N 1.0 0.10 mg/L 1.00 0.017 U . 101 90-110 4 10 Batch 8KO7905 - NO PREP Blank (8K07005-BLKI) Prepared: 11/07/2018 10:22 Analyzed: 11/07/2018 10:22 Spike Source %REC RPD AnalYte Result Elan PQL Units Level Result %REC Limits RPD Limit Notes Ammonia as N 0.045 U 0.10 mg/L �- LCS (SK07005-BSI) Prepared: 11/07/2018 10:27 Analyzed: 11/07/2018 10:27 Spike Source %REC RPD Anal vte Result Elan PGL Units Level Result a/.REC Limits RPD Limit Notes Ammonia as N 1.1 0.10 mg/L 1.00 110 . 90-110 Matrix Spike (8K07005-MSI) Prepared: 11/07/2018 11:20 Arialyzed: 11/07/2018 11:20 II I J Source: CB15142-01 Spike Source %REC RPD ((`` Analyte Result Elan PQL Units Level Result %REC, ..Limits RPD Limit '. Notes Ammonia as N 0.39. 0.10 mg/L 0.389 0.045 U 101. 90-110 Il Matrix Spike (8K07005-MS2) Prepared: 11/07/2018 11:28 Analyzed: 11/07/2018 11:28 . Source: CB15142-02 Spike Source 0/aREC RPD Anal vte Result Elan PUI. Units Level Result a/aREC •Limits RPD Limit Notes Ammonia as N 0.42 0.10 mg/L 0.389 0.045 U .108 90-110 Matrix Spike Dup (8K07005-MSD1) Prepared: 11/07/2018 11:21 Analyzed: 11/07/2018 11:21 Source: CB15142-01 — Spike Sourcea/oREC RPD . Anal Yte Result Elan P9L Units Level Result %REC Limits RPD Limit Notes Ammonia as N 0.40 0.10 mg/L 0.389. 0.045 U 102 90-110 1 10 {_ Batch 8K09006 = Same FINAL This report relates only, to the sample as received by the laboratory, and may only be reproduced in full. Page 8 of 12 - www.eneolabs.com _ --- - --- -__.. ---. QUALITY CONTROL DATA Classical Chemistry_Par_ameter's =-Quality Control- - B7tch 8K09006 - Same - Continued Blank (BK09006-BLKi) Prepared: 11/09/2018 10:55 Analyzed: 11/12/2018 10:57 —° -- - - - Spike Source %REC RPD �T9nal =^T '=-BeSlllt_^Plaa P9b_ On1M= bevel`'` Result`-%REC'- -.Limits =-- RPD_—D.-- 1 2tW— --- Total Kjeldahl Nitrogen 0.26 U 0.48 mg/L — LCS (13K09006-BS1) Prepared: 11/09/2018 10:55.Analyzed: 11/12/2018 10:59 Spike Source %REC RPD AnalYte ... Result Ran P9L 110its Level Result %REC Limits RPD Limit Notes Total Kjeldahl. Nitrogen .13 0.48 mg/L 12.1 103 90-110 "- Matrix Spike (8K09006-MS3) Prepared: 11/09/2018 10:55 Analyzed: 11/12/2018 11:03 Source: C615976-01' Spike.. Source %REC RPD Anal Result: - Ran- . PQV - Units- - Level: - Rgesult °/aREC: Limits.: RPD Limit Notes Total Kjeldahl Nitrogen 7.3 0.48 mg/L 4.85 2.8 91 90-110 Matrix Spike (8K09006-MS2). _ - _ Prepared: 11/09/2018 10:55 Analyzed: 11/12/2018 11:08 Spike Source %REC RPD AnalResult Flag PQL Units Level Result., %REC Limits RPD Limit Notes Total'Kjeldahi Nitrogen 10 0.48, mg/L 4.85 4.4 121 90-110 QM-07 - Matrix Spike Duo (8K09006-MSD3) Prepared: 11/09/2018 10:55 Analyzed: 11/12/2018 11:04 Source: CB15976-01 Spike Source %REC RPD AnalResult Flag P9L 111ft LevelResult. %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 7.9 0.48 mg/L 4.85' 2.8 104 90-110 8 10 Batch 8K0OW'- Same Blank (8K09007-BLK1)' Prepared: 11/09/2018 10:55 Analyzed: 11/12/2018 12:55 Spike Source %REC RPD Anal tfte Result Elm, POL Units Level Result. %REC Limits; RPD Limit Notes Phosphorus 0.025 U 0.10 mg/L LCS (8K09007-BS1) Prepared: 11/09/2018 10:55 Analyzed: 11/12/2018 12:57 Spike Source %REC RPD Anal . RCUR Flag PQL Units _ Level ResulE %REC - Limits RPD Limit Notes Phosphorus 1.6 . 0.10 mg/L 1.60 .102 80-120 Matrix Spike (BK09007-MS1) - Prepared: 11/09/2018 10:55 Analyzed: 11/12/20iB 12:59 Source: CB15976-01 Spike' Source %REC RPD ApaLvte Result Elag PDL Units Level Result %REC Limits RPD Lill & Notes Phosphorus 3.5 D 0.50 mg/L 0:640 2.8 114 80-120 Matrix Spike Dup (SK09007-MSD1) Prepared: 11/09/2018 10:55 Analyzed: 11/12/2018 13:01 Source: CB15976-01 Spike. Source. . ' 9/oREC .. RPD t' Anal vte - Result Elag; P4L Units Level Result °/aREC Limits -RPD -Limit Notes . Phosphorus 3.5 D 0.50 mg/L 0.64Q 2.8 104 80420 2 25 -Batch 81C0-0027 - NO PREP FINAL _- _ — _=_ _ _- _ __ :.This -report relates only to the sample as received by theiaboratory, and may only be reproduced in full. _ _ - - `- Page 9 of 12 - ACC-' www.encolabs.com QUALITY'CONTROL DATA = =- Classical Chemistry Parameters_-_ Quality Control Batch 8K09027 - NO PREP - Continued Blank (131(09027-BLKS) Prepared & Analyzed: 11/09/2018 13:09 Spike Source_ %REC RPD ----Result-Elat4--P91 Total Solids 0.0050 U 0.0050 % by Volume - LCS (81(09027-13SI) Prepared &Analyzed: 11/09/2018 13:09 - Spike Source %REC r RPD .Anal vte Resin flag' PMOL .Units Level Result %REC limits RPD Limit Notes Total Solids 1000 50 mg/L 1100 92 80-120 Duplicate (8K09027-DUP1) Prepared & Analyzed: 11/09/2018 13:09 - Source: CB15976-01 Spike Source %REC RPD Analyte Result F a JfQ Units Level R sul %REC limits RPD Limit Notes Total Solids 0.24 0.0050 % by Volume - 0.23 0.3 20 Batch 8K13011- EPA 3005A Blank (8K13011-BLK3) Prepared: 11/13/2018 10:18 Analyzed: 11/14/2018 16:10 Spike Source %REC i RPD I AnalResult. Ela9 PQL Smite Level Result %REC Limits, RPD Lipp Notes Sodium Adsorption Ratio 0.00 U [blank] ,^ I L , www.encolabs.com ;- FLAGS/NOTES AND DEFINITIONS'. . _J B The analyte was detected in the associated method blank. D The sample was analyzed at dilution.__ 7 _ The reported value.is between the laboratory method detection limit (MDL)-and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. T U - —The analyte was _analyzed -for but -not -detected to -the level-show_n_;_adjusted-for-actual_sample-preparation F' data and moisture content, where'applicable. - E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL _ Method -Reporting Limit. The MRL is roughly equivalent to -the practical quantitation-limit(PQL) and is _ -_ __- •.__ _ :. _ .. _ _. ._ ... - ' based on the low point of the calibration curve, when applicable, sample preparation factor, dilution . factor, ,and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence_(85% or. greater -- confidence) to -make a "tentative,identification".-- - - P Greater than 25% concentration difference was observed between -the primaryand secondary. GC column. The lower concentration is reported. J QM-07 The spike recovery, was outside acceptance limits for the MS and/or MSD." The"batch was accepted based on acceptable LCS recovery. i Lei VS C� '71r776 Certraf Port Or."•"'Yv•_ —4810 Executive Park Court, Suite.777•••—_ _•�•_.__ 102-A Woodwinds Industrial Ct.'--- -•-_.__.____�� Q_ _ Odando, F132624 9aci sonville, F1 32276 ti469 ' Cary, NC 27511 (407)826-5314 Fax (407)SO4.6945 (904)296-3007 Fax(904) 296-6210 (919)467-3090 Fax (919) 467-35.15, Page of. client Name Project Number ' Requested Analyses Requested Turnaround i1 ovazymes North'AmeriCa; (NO008) [none] a t . .p m Times ' m q? a `� � - Note': Rush requests subject to . acce_ptance.by the facility- Address 77 Perry Chape[Church Re6d . "I Project Nameveso Monthly -.,Week One ' SSAA CitylST2p Franklinlon, PAC 2762�: ; i PO # 18i7t ng in7o 3800.360607 as O " a � O � . � t.-j G) f"' � _ . . : . o Standard . Tel Fax Reporting Contact X. -(919) 494-3000 .' Scott Creech �c Expedited' Samplers) Name, Affiliation (Print) { 8illin Contact t;CQUnta Payable U -: e m Z .. Due _I_/ i?►.cG - tl%4 'S ; _ Samplers) Signature: { r to iacatian Time Zone Q g r �. - :. - ` - _ z Preservation (See Codes) (Combine as necessary - I .. C01iet�ian Kfatrix _ Totaf U ot-- Item fi Sample ID (Field Identification) . Collection Date Time Comp! Grab , (see codes) Corru hers - 'Sample Comments {. . --------------- . . . <— Tot Total 4 of Containers - .. Sample Kit Prepared By i.: .:'i✓vl { Datelrime l. �li'�'�.� IDiefmquistied By --� Oii�G%� .r/ Received By D%attenim Comments/Special Reporting Requirements Relinquished By _ DateTrrib Received By Date/fame' j I Relingttished8y Dateflime Received BY .- . Datefrime- Cooler Jrs 8 Temps on Receipt IL Condition U n Receipt ' Acceptable • - _Unacceptable widulit: uw-umun qv uir aV-Ael1 YYY-vmmung Water aCU=imim aW-Dunace.vvalEr Y✓w-mYasielvdler A-fiu iYVSnertaeiau in eommams) Yreservanon_ r-tce Fl-HC:i N-Hmus S-HLSU4 No-MvFl-v-timer (oetap in comments) - - - - - ftle : Af samplessubmitted to ENCO Labs are in accordance with the terns and condbons fisted on the reverse of. diis form, unless prior written agreements exist ' i -Sample Preservation Verification - ENCO Ciry aN _ 'tB15977 Monthly - Week One -,SBM Work Order: Project., Client:- Novozymes North America (N0008) Project .[none] Logged -in: 06-Nov-1 8 10:24 L6d§_dd_By:_ John C King PreOrvaitior! Check Performed -By: Pres gip) MZb6cked'J' Ur "8A,2:;0wyI "'PaWif 'lit 7r big, did Mik l'o-MR A 260MILP41HI2804, <2 Y d NA,J)/ N NA'CO _t4j> + ZMC B' _250rnLP+HNO3 A, Y�A N4 If zft, H-WA • v 0 17-74,00. bw b E - Nm,, "a � Accurate. are. c el . Responsive.,, idif va.�ive. y 102-A Woodwinds Industrial Court - _ CaryNC, 27511 - - -Phone: - 919.467.3090 FAX: 919.467.3515 - - _. _ -Thursday,_December 13, 2018�_ -� -_: -.- - ---� _�_—__------_---- =-=----=-===--T-T--_.. _..----=:_ ===----•-T-�__- :_ _--_,_-_.� _^ Novozymes North America (N0008) Attn: Scott Creech 77'Perry Chapel Church Road _ f "Franklinton, NC 27525 ^' RE: Laboratory Results for Project Number: [none], Project Name/Desc: Monthly - SBM ENCO. Workorder(s): CB17598 _ • _ - . -- - _-_ _ ...-- - ---. _ • _ - _ .- _-_-- _- __ .- Dear Scott Creech, Enclosed is a copy of your laboratory report for test samples received by our laboratory. on Tuesday, December 4,• 2018. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for.these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted -in.the . project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report, contains only those analyses performed by Environmental, Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to'contact me. Sincerely, Chuck Smith - Project Manager Enclosure(s) FINAL -This report relates only to the sample as received by the laboratory, and mayonly be reproduced in full. Page 1 of 8 I 4i9 ' 1 www.encolabs.com - _- — --SAMPLE-SUMMARY/LABORATORY CHRONICLE 1 Client ID: SBM - -- _ _ _.==LabID:_ CB37598-03 Sampled: 12/04/18 07:15 Received: 12/04/18 10:55 Parameter Preparation--- - -- -- =Hold-Date/Time(s)--- Prep Date/Timefs) Analysis Date/Time(s) —_— SM 254OD-2011 NO PREP 12/11/18 12/07/18 10:29 12/07/1 8 -14:15 SM 5210 B-2011 -NO-PREP 12/06/18---07:45 12/05/18 13:22 12/05/18 13:22 SM 5220D-2011 Same 01/01/19 12/07/18 10:29 12/07/18 15:30 • 1. l_.,I i FINAL = _ - - - _- _ — This report -relates only to -the sample as_received_by-the laboratory, and may only be reproduced in full. - - .. - - -._ - - Page 2 of B - — - Www.encolabs.com SAMPLE DETECTION SUMMARY Client IM. . SBM Lab ID:. CB17598-01 - -' Auk - - - .- .-- ll_ ... -Ehs MDL - - P3� - . _ _Units . Method - - Notes - Biochemical Oxygen Demand 3500 2.0 2.0 mg/L. SM 5210 B-2011 Chemical Oxygen Demand �32000 _— _ 400 T_ 400._ mg/L _ SM 5220D-2011 Total Suspended Solids _ . 29000 _ 5000 5000 mg/L. SM 254OD-2011 i i I. _ _ FINAL. This report relates only -to the sample as received byAthe laboratory, and may only be reproduced Mull—— - - - - Page 3 of 8 - - - �60 www.encolabs.com ANALYTICAL RESULTS Description: SBM Lab Sample ID:CB17598-01 Received: 12/04/18 10:55 Matrix: Sludge Sampled:12/04/18 07:15 Work Order: CB17598 Project: Monthly - SBM Sampled By: Elbert Alston Classical Chemistry Parameters ENCO Cary certified analyte [NC 591] — Analvte-rCAS Numberl - -- - Results Flaa -Units DF MOIL POLL Batch Method Analyzed Notes Biochemical Oxygen Demand^ 3500 mg/L 1 2.0 2.0 8L05026 SM 5210 B-2011 12/05/18 13:22 ]OC Chemical Oxygen Demand^ 32000 mg/L 40 406 400 8LO7010 SM 5220D-2011 12/07/18 15:30 30C Total Suspended Solids^ 29000 mg/L 2000 5000 5000 8LO7017 SM 254OD-2011 12/07/18 14:15 OMR FINAL - This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 8 www.encolabs.corh - QUALITY CONTROL DATA I - Classical Chemistry Parameters - Quality Control - Batch SLOS026 - NO PREP Blank (8L05026-BLKL) - i Prepared &Analyzed: 12/05/2018-13:22 Spike -= _ Source -' %REC RPD - ---- Analyde—--,---- Result —EhL4 --P91- - --ynilrt-f— Level- —gg ------9/oREC-_.Limits'-_RP_D-Y__ _-Limit -__,.Note------ Biochemical Oxygen Demand 2.0 U - 2.0 mg/L - - -' LCS (8105026-BS1) Prepared &Analyzed: 12/05/2018 13:22 Spike Source %REC RPD AnalYte... -,Result Film __ I3111. _ ._Units Level _Result - .?/oREC_ Limits _: RPD. king =Notes -- - Biochemical Oxygen Demand 190 2.0-- mg/L .198 94 85-115 I Duplicate (BL05026-DUPI) Prepared & Analyzed: 12/05/2018 13:22 Source: CBI6760-03 Spike Source %REC RPD Anal Result Elks POL ' Units Level Result "/oREC Limits. RPD Lima Notes' Biochemical Oxygen Demand 1500 2.0 mg/L 1300 18 30 Batch 8LO7010 - Same Blank (BL07010-BLKi) Prepared: 12/07/2018 10:29 Analyzed: 12/07/2018 15:30 I i Spike Source %REC RPD E Result Elm PQL units Level Result "/oREC Limits RPD umit Notes Chemical Oxygen. Demand 10 U 10 mg/L LCS (01-07010-BSI) Prepared: 12/07/2018 10:29 Analyzed: 12/07/2018 15:30 Spike Source %REC RPD Anal Besul Eras PiZL Units Level gesyg %REC Limits RPD Limit Notes Chemical Oxygen Demand 470 10 mg/L 500 95, 90-110 Matrix Spike (81-07010-MSI) Prepared: 12/07/2018 10:29 Analyzed: 12/07/2018 15:30 I' Source: C815970-01 Spike Source %REC RPD Anal vtg Result . Elm PQL Units Level Result, %REC Limits RPD Limit Notes f Chemical Oxygen Demand 1200 20 mg/L 1000 490 75 . ' 90-110 QM-07 I 111 Matrix Spike Dup (SL07010-MSDI) Prepared: 12/07/2018 10:29 Analyzed: 12/07/2018 15:30 Source: CB15970-01 Spike Source %REC RPD Anal vte Result Fias P91 - Units Level Result %REC Limits RPD Limit .. Notes Chemical Oxygen Demand 1200 20 mg/L 1000 490 74 90-110 1 10 QM-07 Batch OLO7O17 - NO PREP I Blank (8L07017-BLKi) Prepared: 12/07/2018 10:29 Analyzed: 12/07/2018 14:15 Spike Source %REC RPD AnalSffid: Result Fla_R PQL Units Level Result %REC Limits RPD Limit -' Notes Total Suspended Solids 2:5 U` 2.5 mg/L, LCS (81-07017-BS1) Prepared: 12/07/2018 10:29 Analyzed: 12/07/2018 14:15 f- Spike Source %REC RPD Anallf#0 Result Flan' EQL Units Level Result "/oREC Limits RPD .' Limit Notes Total Suspended Solids 100 2.5 mg/L 100 100 80-120 1 -FINAL - - - - This report relates only to the sample as received by the laboratory, and may only be reproduced in'full: - - - Page 5 of 8 i www.encolabs.cwm QUALITYCONTROL DATA Classical Chemistry Parameters -_Quality Control_ - Hatch A07017 - NO PREP -Continued -- -- -Duplicate (8L07017-DUP1)-- Prepared:, 12/07/2018 10:29 Analyzed: 12/07/2618 14:35- - --_ - -- ------- -- Source: C816760-01 - -- --- ----- - - ----_ Spike Source "/oREC RPD - ResultiFlag _ P-OL - Units— -Level Result___,?/oREC Limits __=RPD _—Limit _,Notes.__ ^� Total Suspended Solids _4400 360 mg/L 5000 13 20 Duplicate (SL07017-DUP2) Prepared: 12/07/2018 10:29 Analyzed: 12/07/2018 14:15 - Source:CB16857-01 Spike Source "/oREC RPD Anal YYe _-_ _ _ _ -—BLsult--Flal3--P91---l1DIUe-- Level Result. -'/oREC =_.-)fit _ -RPD-: --11D1j� ... Notes'. ---- � Total Suspended Solids 170 50 mg/L 170 2 20 v FINAL - - . - - --This-report relates only to the.sample as_received by the a laboratory, and may only be reproduced in -full. - Page 6 of 8- i www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated -method blank. - D The sample was analyzed at dilution. 7 The reported,value•is between the laboratory method detection limit (MDL):and the laboratory method , reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation _ data and moisture content, where applicable. - E .- - - The concentration indicated for this analyte is an estimated value above the calibration range of the - instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation.limit (PQL) and is. based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. I PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or.greater ( confidence).to make a "tentative identification". ---� P . Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. I I i FINAL This report relates only.to the sample as received by the laboratory, and may only be reproduced in full. Page 7 of 8 ENVIRONMENTAL CONSERVATION LABORATORIES CHAIN -OF CUSTODY RECORD'. 10775C6nUalPdrtDr._ ill 10ZA;NoGdV-;indg Industrial CL Orlando, FL32824 Jaci=nville FL32216-6069 Ca—NC27511 v4w*.encq1,ths.com • (407) e--r,5314, FaX_(467) 850-6945 (904129638(37 Fax (904)22"210 (919k 46.7-3040 - Fax (919) 4 . 67-3515 of Client Name N6vozmes' North �rrtedca (N0008) Proect Number [nafiel Requested-Anaryses; ..Page : Requested Turn-ar u Times Address 77' ftrnj (hapsl Churcti Rbad Project Kamefl)zs,- Wnthly -88M -Note Rush requests subject to 'ity acceptance try the Mcil alwsTmp - - PO 4 1 Billing Info' Frank finton'NG 27525: 3000360507 M. 0, . . . . . ..' . . . Standard Tel : Fax . Reporting Contact . Cq C4. _04 % N Expedited - Sampler(s) Name. Affiliation (Print) % . bcou ni Piyable co Due L_ _L_ saI S, t -Site Locatibn f TdeZone "0o , L C817,598 Preservation (.see Codes) (Gombirfe as nrcessary) Collection matrix -Iolaf'-1 or 116M 4 Sample ID (Field Identificallon) Collection Date: Time : Comp/Grab (see codes) Containers Sample Comments SW _46 3 X X. I % I <- ThIRI a of rrintpini-rz Sample M1 Prepared By Date(Time Rat q *ed 9w Dalemme Received By. Date ]rime . ca., C"n CommentsiSl3eclal Reporting Requirements Relinquished By- DaterrIme Recahred EA, DaWTime RefinquIshed 00 Received By Daterrime. I Cooler 4's & Temps on Receipt Condition Upon Receipt- _�_Alceptable Unacceptablel Matrix: GIV-Groundwater'SO-Sall OW -Drinking Water SE -Sediment S%V-Surface Water WW-Wasteraler -A-Air O-Olher(detall in comments) Preservation: )-Ice H-HC1 N-1-9403 S F42SO4 NO-NaOH O-Other (deta'ji in comments) Note -All samples submitted 16 ENCO Labs are in . accordance with the terms and conditions listed an Hie reverse of his form. unless piforwriften agreements exist m. / _ �`. � ~ ' ` -_ ( � Reagent Name ID Reacient Name ID. Reagent Name ID 3 5 .c 4 6 / mHStrip |[� � _! ' ' ' PH Strips CBJ0741� � ^ � _ .,C: ew/o/ur/» �� ~ - — � ----- -- — � _ _____� Page 1of1 '' -ra �0 0 w F, N C -0 a b - Acc ate. lu-sp ns ve. .innovative. 102-A Woodwinds -Industrial Court-- - -- -- - .Cary NC, 27511 . Phone: 919.467.3090 FAX: 919.467.3515 Thursday, December 13, 2018 Noyozymes North America (N0008) Attn: Scott -Creech - -- - - - - - --- - - - 77-Perry Chapel Church Road Franklinton, NC 27525 RE: Laboratory Results for _ Project Number: [none], Project Name/Desc: Monthly - Week One - SBM ENCO Workorder(s): CB17600 . Dear Scott Creech, - Enclosed is a copy of your laboratory report for test samples received by our laboratory on Tuesday, December 4, 2018. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in — full, without the written approval of the Laboratory. 1. This report contains only those'analyses performed by Environmental. Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from joutside organizations.will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Chuck Smith .. . ' Project Manager Enclosure(s) FINAL - _ _ This report relates only -to the sample as received by the laboratory, -and may only be'reproduced in full. - Page 1 of 12 SAMPLE SUMMARY/LABORATORY CHRONICLE �eo www.encolabs.com ! Client ID: SBM"' _ _ _ _==_Lab.ID:_CB17600-01 Sampled: 12/04/18 07:15 Received: 12/04/18-10:55 -, Parameter Preparation- - -___ _ Hold Date/Time(s5 --- - Prep Date/Time(g- Analysis Date/rime(j) CSU Method NO PREP 08/29/2T - 12/05/18 11:22 12/10/18 13:44 EPA 350.1 NO PREP 01/01/19 12/11/18 11:54 12/11/18 11:54 -EPA 351.2. - _ Same 01/01/19 _ - 12/05/18 10:45 12/06/18 -15:40 EPA353.2 NO PREP_____-- -12106/18--07:15---- 12/04/18 17:00 12/04/18 17:00 — - - EPA 353 2 --WO-PREP OS/29/21 - - - —--12/13/18 3258 _- - _ - - -' 12/13/18 13:44 EPA 365.4 Sarre — 01/01/19 - 12/05/18 10:45 12/06/18 16:55 EPA-6010D - .:-' - EPA 3005A 06/02/19 ----12/05/18 11:22- 12/10/18-11:28 — EPA 74704 EPA 7470A Ol/01/19 12/11/18 15:22 12/12/18 15:28 SM 254OB-2011 NO PREP 12/11/18 12/10/18 12:11 12/10/18 12:11 J I 1 . i I� I FINAL -_ —_--This report relates only_ta the sample as.received_by the laboratory, and may only be reproduced in full. _ - - Page 2 of 12 www.encolabs.com J SAMPLE DETECTION SUMMARY ^ Client ID: SBM Lab ID: C517600-01 -x Anal Fin Hu Egi Units Method Notes Aluminum - Total 302 0.420 1.00 mg/L EPA 6010D Ammonia as N _- 83 D " _ 4.5 _ _ 10 _ _ _ mgJL EPA 350.1 Calcium - Total 3090 0.390 1.00 mg/L EPA 6010D - Copper - Total 0.542 0:0160 ' 0.100 mg/L EPA 6010D Magnesium - Total 58.7 0.290 1.00, mg/L EPA 6010D - `Molybdenum = Total - - 0.0860 -3 — - :0.0250 0.100 "mg/L EPA-6010D' Nickel- Total 0.0529 3 0.0220 0.100 mg/L EPA 6010D Nitrate as N 28 0.025 0.10 mg/L EPA 353.2 Nitrite as N - - - - — 0.94 0.017 0.10 mg/L EPA 353.2 - Phosphorus 500 D 10 40 mg/L EPA 365.4 Potassium - Total 850 1.50 - 5.00 mg/L EPA 6010D - Sodium - Total 408 4.00 5.00 mg/L EPA 6010D Sodium Adsorption Ratio 1.99 [blank] CSU Method Total Kjeldahl Nitrogen 1800 D 26 48 mg/L EPA 351.2 Total Solids 4.8 0.25 0.25 % by Volume SM 254OB-2011 Zinc - Total 0.706 0.0440 0.100 mg/L EPA 6010D FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 12 ENCfl WWW.encolabs.com ANALYTICAL RESULTS Description: SBM Lab Sample ID: CB17600-01 Received: 12/04/18 10:55 i Matrix: Sludge Sampled: 12/04/18 07:15 Work Order: CB17600 Project: Monthly - Week One - SBM Sampled By: Elbert Alston - Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 5911 -- Analyte rCAS Numberl - - - -----Results ults - ]_aq- -Units- - - DF --MDL - PPQLL -Batch - Method - Analyzed - - B - - -�(--- --Notes--- Mercury [7439-97-6]^ 0.000750 U mg/L 5 0.000750 0.00100 8L11043 EPA 7470A 12/12/18 15:28 NMN Metals (total recoverable) by EPA 6000/7000 Series Methods - - ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results E199 Units RE bpi ka DAM Method Ana17zed @!C Notes Aluminum [7429-90-5]^ 302 mg/L 10 0.420 1.00 SLO5020 EPA 6010D 12/10/18 11:28 JDH Arsenic[7440-38-2]^ 0.0760 U mg/L 10 0.0760 0.100 BL05020 EPA 6010D 12/10/18 11:28 JDH Cadmium [7440-43-9]^ 0.00360 U mg/L 10 0.00360 0.0100 8L05020 EPA 6010D 12/10/18 11:28 JDH Calcium [7440-70-2]^ 3090 mg/L 10 0.390 1.00 8LO5020 EPA 6010D 12�10/18 11:28 JDH Copper[7440-50-8]^ 0.542 mg/L 10 0.0160 0.100 8LO5020 EPA 6010D 12/10/18 11:28 JDH Lead [7439-92-1]^ 0.0310 U mg/L 10 0.0310 0.100 8L05020 EPA 6010D 12/10/18 11:28 JDH Magnesium [7439-95-4]^ 58.7 mg/L 10 0.290 1.00 BL05020 EPA 6010D 12/30/18 11:28 I JDH Molybdenum [7439-98-7]^ 0.0860 1 mg/L 10 0.0250 0.100 8LO5020 EPA 6010D 12/10/18 11:28 JDH Nickel[7440-02-O]^ 0.0529 1 mg/L 10 0.0220 0.100 BL05020 EPA 6010D 12/10/18 11:28 JDH Potassium [7440-09-7]^ 850 mg/L 10 1.50 5.00 BL05020 EPA 6010D 12/10/18 11:28 JDH 1 Selenium [7782-49-2]^ 0.0620 U mg/L 10 0.0620 0.100 8L05020 EPA 6010D 12/10/18 11:28' JDH Sodium [7440-23-5]^ 408 mg/L 10 4.00 5.00 8LOS020' EPA 6010D 12/10/18 11:28 JDH Zinc[7440-66-6]^ 0.706 mg/L 10 0.0440 0.100 8L05020 EPA 6010D 12/10/18 11:28 JDH Classical Chemistry Parameters - ^ - ENCO Cary certified analyte [NC 591] Analyze rCAS Numberl Results Flaq Units PFF MDL POL Batch Method Analyzed ft Notes Ammonia as N [7664-41-7]^ 83 D mg/L 100 4.5 10 81-11007 EPA 350.1 12/11/18 11:54 JU Nitrate as N [14797-55-8]^ 28 mg/L 1 0.025 0.10 8L13030 EPA 353.2 12/13/18 13:44 JU Nitrite as N [14797-65-0]^ 0.94 mg/L 1 0.017 0.10 8LO4027 EPA 353.2 12/04/18 17:00 ]U Phosphorus[7723-14-0]^ Soo D mg/L 400 10 40 BLO5009 EPA 365.4 12/06/18 16:55 JLI Sodium Adsorption Ratio 1.99 [blank] 1 SL05020 CSU Method 12/10/18 13:44 JDH Total Kjeldahl Nitrogen^ 1800 D mg/L 100 26 48 SL05008 EPA 351.2 12/06/18 15:40 JU Total Solids^ 4.8 % by Volume 50 0.25 0.25 8L10014 SM 254OB-2011 12/10/18 12:11 OMR A FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 12 �Cme www.encolabs.com QUALITY CONTROL DATA j Metals by EPA 6000/7000 Series Methods - Quality Control - - Batch 8L11043-- EPA 245.1 = - Blank (81.13043-BLI(1) - -- - - Prepared:- 12/11/2018 15:22 Analyzed: 12/12/2018 -14:43 Spike Source - '-- %REC RPD - _-=-- Analyte_- ___-_- -_-_-- ---- -=-.-BeSSllt_-=Ela9,- �P46 - 1lBMGi --Level--=--Result-._=%REC =___ � . -.--RPD- J,jpljl --�---lY4tS--------_`- Mercury 0.000150 U 0.000200 mg/L LCS (S1.31043-13SI) Prepared: 12/11/2018 15:22 Analyzed: 12/12/2018 14.46 Spike Source %REC RPD Anal vte Result Pla_4. N& Units Level Result %REC Limits RPD Limit Notes • Mercury 0.00556 6.060206 mg/L 0.00500 111 80-120 Matrix Spike (SL11043-MS1) Prepared: 12/11/2018 15:22 Analyzed: 12/12/2018 14:58 Source: CB17700-03 Spike.. Source %REC RPD Anal Result... Ela9 _=--P_QL.: -_.._ Units Level -- _ Res 1 "/aREC_ - Limits. RPD Limit . -Notes Mercury 0.00538 _ 0:000200 mg& 0.00800 0.000150 U 108 , 75-125 - Matrix Spike (8LI1043-MS2) Prepared: 12/11/2018 15:22 Analyzed: 12/12/2018 15:00 Source: CB17863-02 Spike Source %REC RPD Analyte Result Bag P91 Units Level Result %REC Limits RPD' Lj®lt Notes Mercury 0.00549 0.000200 mg/L 0:00500 0.000150 U 110 75-125 Matrix Spike Dup (BL11043-MSD1) Prepared: 12/11/2018 15:22 Analyzed: 12/12/2018 15:03 Source: CB17700-03 Spike Source %REC RPD Analyte Result Hag PAL units Level . Result %REC Limits RPD Limit Notes . Mercury 0.00556 0.000200 mg/L 0.00500 0.000150 U , 111 75-125 3 25 Matrix Spike Dup (81.11043-MSD2) Prepared: 12/11/2018 15:22 Analyzed: 12/12/2018 15:05 Source: C817863-02 Spike Source, %REC RPD Analyte' - - Result Etas - PUL- units Level Result "/aREC iimM RPD Limit Notes Mercury 0.00536 0.000200 mg/L 0.00500 . 0.000150 U 107 75-125 3 25 Post Spike (8L11043-PS3) Prepared: 12/11/2018 15:22 Analyzed: 12/12/2018 15:07 Source: CB17700-03 Spike Source %REC RPD Analyte Result Elan P.4L Units Level B6sul %REC Limits RPD Limit Notes Mercury 5.83 0.200 ug/L 5.00-0.0300 117 75-125 Post Spike (8L11043-1PS2) Prepared: 12/11/2018 15:22 Analyzed: 12/12/2018 15:09 . Source: CB17863-02 - Spike Source %REC RPD Analyte Result E1M PQL Units Level Res I %REC Limits RPD Limit Notes Mercury 6.15 0.200 ug/L 5.00 0.0320 122 75-125 --- Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OL05020 -EPA 3005A Blank (81.05020-131.11(l) Prepared: 12/05/2018 11:22 Analyzed: 12/10/2018 10:48 . Spike Source %REC RPD Anal YtC Result' Elan P91 UniU Level Result o/ciREC Limits RPD Limit Notes - Aluminum 0.0420 U : - 0.100 mg/L Arsenic 0.00760 U 0.0100 mg/L _ Cadmium 0.000360 U 0.00100 mg/L , FINAL _ _ This report relates only.to:the sample as received by the laboratory, and may only be reproduced in full. Page 5 of 12 www.encolabs.com QUALITY CONTROL DATA - Metals (total recoverable) by EPA.6000/7000 Series Methods - Quality Control Batch 8L05020 - EPA 3005A - Continued - Blank (BL05020-BLKi) Continued ---- - -- - - -- Prepared: 12/05/2018 11:22 Analyzed: 12/10/2018 10:48 - -- - - Spike Source %REC RPD Anal tde - -Result--_-Elaa --POL- -Units. Level -- -Result '/aREC _Urnits _ _RPD _ _ Limit --Notes - Calcium 0.0390 U - 0.100 mg/L Copper - - - --_0.001_60 --- U---- 0.0100__ mg/L - - - -- Lead 0.00310 U 0.0100 mg/L - Magnesium 0.0290 U 0.100 mg/L Molybdenum 0.00250 U 0.0100 mg/L Nickel 0.00220 U 0.0100 mg/L - Potassium I 0.150 U 0.500 mg/L Selenium 0.00620 U 0.0100 mg/L Sodium 0.400 U 0.500 mg/L Zinc 0.00440 U 0.0100 mg/L LCS (8105020-BS1) Prepared: 12/05/2018 11:22 Analyzed: 12/10/2018 10:53 Spike Source %REC RPD Anal vte Result Elim PsiL Units Level Resul %REC limits RPD Limit; Notes Aluminum 2.22 0.100 • mg/L 2.00 ill _ ,- 80-120 Arsenic 0.196 0.0100 mg/L 0.200 98 80-120 1' Cadmium 0.0214 0.00100 mg/L 0.0200 107 80-120 Calcium 2.18 0.100 mg/L 2.00 109 80-120 Copper '0.207 0.0100 mg/L 0.200 104 80-120 Lead 0.215 0.0100 mg/L 0.200 108 80-120 Magnesium 2.20 0.100 mg/L 2.00 110 '80-120 Molybdenum 0.217 0.0100 mg/L 0.200 108 80-120 Nickel 0.216 0.0100 mg/L 0.200 108 80-120 Potassium 11.0 0.500 mg/L 10.0 110 80-120 Selenium 0.214 0.0100 mg/L 0.200 107 80-120 - Sodium 11.0 0.500 mg/L 10.0 110 80-120 Zinc 0.217 0.0100 mg/L 0.200 109 80-120 Matrix Spike (SL05020-MS1) Prepared: 12/05/2018 11:22 Analyzed: 12/10/2018 10:56 Source: CB18520-01 r- { Spike Source a/oREC RPD Anal Result • faa P qL Units Level Result o/aREC Limit, RPD • Limit Notes - Aluminum 2.38 0.100 mg/L 2.00 0.0665 116 75-125 Arsenic 0.216 0.0100 mg/L 0.200 0.00760 U 108 75-125 Cadmium 0.0219 0.00100 mg/L 0.0200 0.000360 U 109 75-125 Calcium 10.3 0:100 mg/L 2.00 8.07 110 75-125 Copper 0.207 0.0100 mg/L 0.200 0.00160 U 104 75-125 Lead 0..215 0.0100 mg/L 0.200 , 0.00310 U 108 75-125 Magnesium 7.69 0.100 mg/L 2.00 5.50 110 -_ 75-125 Molybdenum 0.217 0.0100 mg/L 0.200 0.00250 U 109 75-125 Nickel 0.226 0.0100 mg/L 0.200 0.00220 U 113 75-125 Potassium 21.9 0.500 mg/L 10.0 10.9 110 75-125 Selenium 0.197 0.0100 mg%L 0.200 0.00620 U 99 75-125 " Sodium 32.2 0.500 mg/L 10.0 21.9 103 75-125 - Zinc 0.228 0.0100 mg/L 0.200 0.00440 U 114 75-125 Matrix Spike Dup (8L05020-MSD1) Prepared: 12/05/2018 11:22 Analyzed: 12/10/2018 10:59 Source: CB18520-01 _ Spike Source i %REC RPD Anal tde Result Etas P-OL Units Level Result a/oREC Limits RPD Limit Notes FINAL =_--_ This report relates only to the_sample as received by the laboratory, and may only be reproduced in full. Page 6 of 12 www.encolabs.com - QUALITY CONTROL DATA :-" Metals (total recoverable) by=EPA 6000/7000.Series Methods - Quality Control Batch SLOS020'- EPA 30054- Continued Matrix Spike Dup (811.05020-11YISDI) Continued - --Prepared: 12/05/2018-11:22 Analyzed: 12/10/2018 10:59- - - - Source: C818520-01 Spike Source %REC RPD Analyte - - --- - Besult- afla4=__-=E91== ==-un►ts- _-=-=Level_ -" -Resin ----.--RPD' _-= Limit - -Notes. -. Aluminum -- 2.34 0.100 mg/L .2.00 0.0665 114 75-125 2 20 j _ ! Arsenic 0.220 0.0100 mg/L 0.200 0.00760 U 110 75-125 2 20 Cadmium - 0.0223-- - - 0.00300 mg/L 0.0200 0.000360 U - ill 75-125 - 2 20 Calcium 10.1 0.100 mg/L 2.00 8.07 102 75-125 2 20 Copper -__. _..' .. _- - :0.206 __, 0.0100 : mg& 0.200. 0.00160 U 103 75-125 0.5 20 -� Lead .0.220 0.0100 mg/L 0.200 0.00310 U 110 75-125 2 : 20 _ Magnesium 7.63 0.100 mg/L 2.00 5.50 106 75-125 0.9 20 Molybdenum 0.221 0.0100 mg/L 0.200 0.00250 U 110 75-125 1 20 Nickel 0.224 0.0100 mg/L 0.200 0.00220 U 112 75-125 ' 0.8 20 _ Potassium' 21.6 0.500 mg/L 10.0 30.9 107 75-125 1 20 - Selenium 0.206 - 0.0100 - --mg/L 0.200 0.00620-U _103- 75-125- 4 20 Sodium 31.8 -0.500 mg/L 10.0 -21.9 99- 75-125 1 20 _ Zinc' 0.232 0.0100 mg/L 0.200 0.004400 116 75-125 2 20 Post Spike (4L05020-PSI)_ _. Prepared: 12/05/2018 11:22 Analyzed: 12/10/2018 11:01 j Source: C818520-01 Spike Source %REC 'RPD Anal yYg Result Elm PGL Units Level Result %REC Limits RPD limit Notes Aluminum 2.26 0.100 mg/L 2.00 0.0665 110 80-120 Arsenic 0.216 0.0100 mg/L 0.200 0.00580 105 80-120 Cadmium 0.0212 0.00100 mg/L 0.0200 3.61E-5 106 80-120 Calcium 10.3 0.100 mg/L 2.00 8.07 ill 80-120 Copper 0.201 0.0100 mg/L 0.200 -0.00175 100 80-120 Lead 0.212 0.0100 mg/L 0.200 0.00145 105 80-120 Magnesium 7.70 0.100 mg/L 2.00 5.50 110 80-120 Molybdenum 0.217 0.0100 mg/L 0.200 -0.00147 108 80-120 Nickel 0.225 0.0100 mg/L 0.200 0.000621 112 80-120 Potassium 21.8 0.500 mg/L 10.0 10.9 109 80-120 Selenium 0.196 0.0100 mg/L 0.200 -0.0119 98 80-120 Sodium 32.2 0.500 mg/L 10.0 21.9 103 80-120 Zinc 0.227 0.0100 mg/L 0.200 -0.00406 114 80-120 Classical Chemistry Parameters - Quality Control Batch SLO4027 - NO PREP Blank (8L040Z7-BLKl) Prepared: 12/04/2018 16:51 Analyzed: 12/04/2018 16:51 Spike Source %REC RPD Anal vte Result flag - POL Units - Level Result -%REC Limits - RPD- Limit Notes Nitrite as N 0.017 U 0.10 mg/L LCS (SL04027-13SI) Prepared: 12/04/2018 17:03 Analyzed: 12/04/2018 17:03 Spike Source %REC' RPD .: Analyse Result Elam I'0L Units Level Result %REC Limits RPD Limit Notes Nitrite as N 1.0 0.10 mg/L 1.00 103 90-110 LCS (SL04027-BS2) Prepared,: 12/05/2618 09:38 Analyzed:-12/05/2018 09:38 Spike Source %REC RPD Anal Residt Elam EM Units Level Result %REC Limits RPD Limit Notes Nitrite as N 0.97 0A0 mg/L 1.00 97 90-110' _ _ _ FINAL This report relates only to the sample asreceivedby-the laboratory, and may only be reproduced in full. Page 7 of 12 co www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 8L04027 - NO PREP - Continued -- Matrix Spike (8L04027=MSi) Prepared: 12/04/2018 16:53 Analyzed: 12/04/2018 16:53 Source: CB16915-01 Spike -- . - Source %REC RPD Analyte Resin Flag ROL Unft Level Result %REC Limits RPD spit Notes Nitrite as N 1.3 0.10 mg/L 1.00 0.35 94 90-110 Matrix Spike (8L04027-MS2) Prepared: 12/04/2018 16:56 Analyzed: 12/04/2018 16:56 Source: CB17822-01 Spike Source %REC RPD Analyte Result Fla_u P-QL Units Level Result %REC Limits RPD limit Notes Nitrite as N 0.95 0.10 mg/L 1.00 0.018 94 90-110 Matrix Spike Dup (BL04027-MSD1) Prepared: 12/04/2018 16:54 Analyzed: 12/04/2018 16:54 Source: CB16915-01 Spike Source %REC RPD Analvte - Result F1SL4 Untts Level R sul %REC Limits RPD Limit Notes Nitrite as N 1.3 0.10 mg/L 1.00 0.35 99 90-110 3 10 Batch 8L05008 - Same Blank (81.05008-BLK3) Prepared: 12/05/2018 10:45 Analyzed: 12/06/2018 13:11 Spike Source o RPD Anal Yte Resul Flag PQL Units Le el Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 0.26 U 0.48 mg/L LCS (8L05008-BS1) Prepared: 12/05/2018 10:45 Analyzed: 12/06/2018 13:14 Spike Source %REC RPD Anal e Result Flag P4L units Level Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 12 0.48 mg/L 12.1 98 90-110 Matrix Spike (BL05008-MSi) Prepared: 12/05/2018 10:45 Analyzed: 12/06/2018 15:26 Source: CB16857-02 Spike Source o/aREC RPD Ana a Result Flag P_4.L Units Level Result o/aREC Jests RPD Limit Notes Total Kjeldahl Nitrogen 5.9 0.48 mg/L 4.85 1.2 96 90-110 Matrix Spike (8L05008-MS2) Prepared: 12/05/2018 10:45 Analyzed: 12/06/2018 15:29 Source: CB17043-01 Spike Source LiREC RPD Anal Besult Flag PS�L units Level o Result /oREC Limits RPD 1'Imit Notes Total Kjeldahl Nitrogen 7.2 0.48 mg/L 4.85 .2.2 104. 90-110 Matrix Spike Dup (811.05008-MSDI) Prepared: 12/05/2018 10:45 Analyzed: 12/06/2018 15:28 Source: CB16857-02 . I Spike Source %REC RPD Anal Result FJag P9L Units Level o Result /oREC Limits RPD Limit Notes Total Kjeldahl Nitrogen 5.9 0.48 mg/L 4.85 1.2 98 90-110 1 10 Batch 8L05009 - Same Blank (81.05009-BLKi) Prepared: 12/05/2018 10:45 Analyzed: 12/06/2018 14:36 Analvte Phosphorus Spike Source %REC Result Flag P-QL Units Level Result %REC Limits 0.038 3 0.10 mg/L RPD RPD Limit Notes f FINAL This report relates only to the sample as received by the laboratory, and may -only be reproduced In full. - Page 8 of 12- _ - _ QUALITY CONTROL DATA Classical Chemistry_Parameters_-_Quality Control,_._ Batch 8L05009 - Bain ='Continued-- ----- -- LCS (8L05009-BSi) — -- ,_ - - -_- - - --- - — Prepared:-12/05/2018-10:45 Analyzed: 12/06/2018-14:39 - ---- --- Spike Source %REC -.' 'RPD Anal tdg= '-__ Result =-: 'E11Q=- POL=-= - lljft-_ - =Lever_ .—Aesult -`—%REC-= ljllllt4 ---RPD=—_-:-11IBLt==-== -I14=- _ — -- Phosphorus-- -1.6- 0.10_ mg/L - - 1.60 -101 _ _80-120 Matrix Spike (8L05009-MS1) = Prepared: 12/05/2018 10:45 Analyzed: 12/06/2018-16:49' Source: CB16857-02 Spike Source, %REC RPD Anallde, Result. Fias=- POL- Units : Level . Result'. '9/aREC _fit --RPD. Limit ... Notes-, - Phosphorus - 0.88 0.10 mg/L 0.640 0.28 94 80-120 Matrix Spike Dup (SL05009-MSD1) Prepared: 12/05/2018 10:45 Analyzed:.12/06/2018 16:50 Source: CB16857-02 Spike Source %REC RPD r _ Anal vte - Result Ela_q PD1 Unit£_., Level Result '/oREC Limits. RPD - Lima Notes Phosphorus 0.88 0.10, mg/L 0.640 0.28 94 80-120 0.3 25, Batch BL10014-= NO PREP - - - Blank (8L10014-111M) Prepared & Analyzed:12/10/2018 12:11 i f Spike Source %REC RPD Anal vtg Result Etag POL, Units. Level Result . o/aREC Limits RPD Limit Notes Total Solids 0.0050 U 0.0050 % by Volume " •LCS (8L10014-BSI) Prepared & Analyzed: 12/10/2018 12:11 , Spike Source %REC RPD AnalYte' Resul Elm PGL Units Level Result %REC Limits RPD Limit Notes Total Solids 1100 5o mg/L 1100 98 80-120 Duplicate (8L10014-DUPI) - ' --Prepared & Analyzed: 12/10/2018 12:11 Source: CB17599-01 Spike Source %REC RPD AnalYte Result Etas POL units Level Result %REC Limits, RPD Limit Notes Total Solids 0.22 0.0050 % by Volume 0.22 0.09 20 i Batch BLI1007 - NO PREP Blank (BL31007-BLKI) Prepared: 12/11/2018 11:30 Analyzed: 12/11/2018 11:30 Spike Source %REC RPD Analyte Result Etas POL Units. Level Result %REC Limits RPD imi Notes. - Ammonia as N 0.045 U 0.10 mg/L LCS (SL13007-BS1) Prepared: 12/11/2018 11:32'Analyzed: 12/11/2018 11:32 Spike Source %REC RPD' AnalYtq Result Elaa POL UnitS Level Result '/oREC ', Limits RPD Limit Notes Ammonia as N .1.0 0.10 mg/L 1.00 102 90-110 - Matrix Spike (8L11007-MS1) Prepared: 12/11/2018 11:35 Analyzed: 12/11/2018 11:35 Source: CB07910-01 Spike Source %REC RPD -- - Anal Result Flag POL Units- Level Result %REC Limits RPD : Limit Notes Ammonia as N I 0.64. 0.10 mg/L 0.389 0.29 9Q 90-110 _FINAL_ - __,._ _ _ _- __. _ This report relates only_m the sample as received by.the laboratory, and -may only_beyeproduced in full._ __ _' __ _ _ _ . _ ' -' _ .' Page 9,012_-.:___ _-_ �60 www.enoolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 8L11007 - NO PREP - Continued Matrix Spike (8L11007-MS2) Prepared: 12/11/2018,11:44 Analyzed: 12/11/2018 11:44 Soume: CB16760-02 Spike Source %REC RPD _ Analvte Result Elm PIQL units Level Result %REC_ Limits RPD Limit __ Notes Ammonia as N 2.3 E 0.10 mg/L 0.389 1.9 98. 90-110 QM-07 Matrix Spike Dup (8L11007-MSDI) Prepared: 12/11/2018 11:37 Analyzed: 12/11/2018 11:37 Source: CB07910-01 i Spike Source %REC RPD AnalResult flag PQL Units Level Result o/aREC 11BI1G£ "RPD Limit Notes Ammonia as N 0.65 0.10 mg/L 0.389 0.29 92 90-110 0.9. 10 Batch 8L12010 - NO PREP f LCS (8L12010-BSI) Prepared: 12/12/2018 13:06 Analyzed: 12/12/2018 13:06 Spike Source %REC RPD Anal vte Result Flan PQL Units Level Result o/aREC )its RPD Limit Notes ' Nitrate/Nitrite as N 1.3 0.10 mg/L 1.25 105 90-110 Matrix Spike (811-32030-MS3) Prepared: 12/12/2018 13:12 Analyzed: 12/12/2018 13:12 Source: CB15970-01 Spike Source %REC RPD Anal vte Result Flan PQL Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 55 10 mg/L 50.0 4.1 U 110 90-110 Matrix Spike (8L32010-MS2) Prepared: 12/12/2018 13:17 Analyzed: 12/12/2018 13:17 Source: CB16857-02 Spike Source %REC RPD Anal Result flag P" Units Level Result %REC Limits RPD Limit Notes y Nitrate/Nitrite as N 31 0.50 mg/L 2.50 9.6 67 90-110 QM-07 Matrix Spike Dup (8L12010-MSDI) Prepared: 12/12/2018 13:14 Analyzed: 12/12/2018 13:14 Source: C615970-01 Spike Source %REC RPD - Anal Basalt Flan BQL Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 55 10 mg/L 50.0 4.1 U 109 90-110 1 10 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 10 of 12_ - _ - - " - www.encolabs.com._ FLAGS/NOTES AND DEFINITIONS 1�' •- .• B -, 7he.analyte was detected in the associated method blank._ D . The sample was analyzed at dilution: I The reported valueis between -the laboratory method detection limit-(MDL)'-and-the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. _ U The analyte was analyzed for but not detected to the level shown, _adjusted for, actual sample preparation data and.moisture content, where applicable. -- - - - .- E The concentration indicated for this analyte is -an estimated value above the calibration range of the instrument. This value is considered an estimate.. MRL . . = . Method_ Reporting Limit. .The- MRL is'roughly equivailent,to the practical quantitation-limit (P_QQ and is -= based on.the.low point,of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence .(85% or greater confidence) to make a "tentative.identiflcation". _- - - P. `Greater- than-25% concentrationdifference was observed betweeh-the primaryand-secondary GC column.The -lower concentration is reported. . QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The -batch -was - accepted based on acceptable LCS recovery. i -- - FINAL J This report relates only to the sample as received by the laboratory, and may only be reproduced in full.'Page 11 of 12 _ KPmparad By Datemme F ab-ad BSample ��jr.Datetrme CommentstspedaJReporlingRequ(rernents RetinquisttedBy' DatjfCiine Eteee dE! -e DataTme- RetingafshedBy - Qatett'une - REeefvedBy Da4emmo Csb(er^&TbrrOswi Recelpl CondiIton Upon Receipt - - cceptable - _Unacceptable. uiaura . rarr-raruuuuwo�er aV-adll YYY-VIiflRllig YYAIdI ze-aduu cm-awouuaca watur. YYrr•YYasrdva[er n-tru v-umertualaw racommerns) Presewanort_ Ftce n-hut 1V-mNw S-F12SsJ'4. NIQ-NflQFt o-umsr(dew in commenis) Note: Ali samples submitted to ENCO Cats are in accordance %Ywi the terms and condtgans fisted an ttse reverse'c(t€ris farm, unless prior wrcten agroernirp exist ' .Sample 'Preservati.on= Verification 4Oil ENCO Cary Work Order: CB.1 V,B00 Project: Monthly -Week One - SBM. Client: Novoaymes. North America (N0008) 'Project #: [none] Logged',ln; 04�Dee-1811; 26 ' Logged By: Rachel Ann Yojh f Preservation Check Performed .By: Date/Time:.�21 CB17600-01_. Cohn. T te�me�,, �.� .�� -...;f�equ�remen�, ents� , a N= 7-NA- Y N / NA i- B 250mLP*HN0 =2 Y / N / NA / N / NARM IDS