NCS000115_MONITORING INFO_20180524

--—STORIVIVHATER-DIVISION-CODiNG-SHEET
PERMIT NO.
�CSO�'J i1S
DOC TYPE
❑FINAL PERMIT
MONITORING INFO
❑ APPLICATION
❑ COMPLIANCE
❑ OTHER
DOC DATE
❑ aUl$V�dH
YYYYMMDD

Y w TV
NPDES PERMIT NO. NCS000115
FACILITY NAME NOVOZymeS, NA Inc.
OPERATOR IN RESPONSIBLE CHARGE (ORC)
CERTIFIED LABORATORIES (1) Enco
CHECK BOX IF ORC HAS CHANGED E= PERSON(S) COLLECTING SAMPLES
Mail ORIGINAL and ONE COPY to:
EFFLUENT
DISCHARGE NO. 1
CLASS
NIA
(2)
MONTH May YEAR 2018
COUNTY: Franklin
PHONE [phone]
Joe Ladd
ATN: CENTRAL FILES x NIA
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
107 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY
RALEIGH, NC 27699-1617 KNOWLEDGE.
DWQ Form MR-1 (11/04)

' .V1Y
Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
(including weekly averages, if applicable)
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements ❑
Noncompliant
The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially
threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the
pen -nittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the
permittee becomes aware of the circumstances.
If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for
improvements to be made as required by Part II.E.G of the NPDES permit.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly
responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Randy Green
Permittee (Please print or type)
Si'nature Permtttee* Date
�(Requir less submitted electronically)
Permittee Address Phone Number e-mail address Permit Expiration Date
Certified Laboratory (2)
Certified Laboratory (3)
Certified Laboratory (4)
Certified Laboratory (5)
ADDITIONAL CERTIFIED LABORATORIES
PARAMETER CODES
Certification No.
Certification No.
Certification No.
Certification No.
Parameter Code assistance may be obtained by calling the NPDES Unit at [phone] or by visiting the Surface
Water Protection Section's web site at h2o.enr.state.nc.uslwas and linking to the unit's information pages.
Use only units of measurement designated in the reporting facility's NPDES permit for reporting data.
* No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be
entered for all of the parameters on the DMR for the entire monitoring period.
ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204.
Page 2

NPDES PERMIT NO. NCS000115
FACILITY NAME Novozymes, NA Inc.
OPERATOR IN RESPONSIBLE CHARGE (ORC)
CERTIFIED LABORATORIES (1) Enco
EFFLUENT
DISCHARGE NO.
CLASS
NIA
(2)
CHECK BOX IF ORC HAS CHANGED C==fl PERSON(S) COLLECTING SAMPLES
Mail ORIGINAL and ONE COPY to:
MONTH May YEAR 2018
COUNTY: Ffanklin
PHONE [phone]
Joe Ladd
ATTN: CENTRAL FILES K WA
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY
RALEIGH, NC 27699-1617 KNOWLEDGE.
Monthly Limit
DWQ Form MR-1 (11/04)

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
(including weekly averages, if applicable)
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements ❑
Noncompliant
The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially
threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the
permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the
permittee becomes aware of the circumstances.
If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for
improvements to be made as required by Part i1.E.6 of the NPDES permit.
"1 certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly
responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Permittee Address
Certified Laboratory (2)
Randy Green
Permittee (Please print or type)
Si ture P ittee ** Date
equired unIUs submitted electronically)
Phone Number e-mail address Permit Expiration Date
ADDITIONAL CERTIFIED LABORATORIES
Certification No.
Certified Laboratory (3) Certification No.
Certified Laboratory (4)
Certified Laboratory (5)
PARAMETER CODES
Certification No.
Certification No.
Parameter Code assistance may be obtained by calling the NPDES Unit at [phone] or by visiting the Surface
Water Protection Section's web site at h2o.enr.state.nc.us/wgs and linking to the unit's information pages.
Use only units of measurement designated in the reporting facility's NPDES permit for reporting data.
* No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be
entered for all of the parameters on the DMR for the entire monitoring period.
ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204.
Page 2

#; .ENCO Laboratories
Accurate. Timer. Responsive. Innovative.
102-A woodwinds Industrial Court
Cary NC, 27511
Phone: [phone] FAX: [phone]
Tuesday, May 8, 2018
Novozgmes North America (N0008)
Attn: Joe Ladd
77 Perry Chapel Church Road
Frankiinton, NC 27525
RE: Laboratory Results for
Project Number: [nonej, Project Name/Desc: Stormwater Testing
ENCO Workorder(s): CB01514
Dear Joe Ladd,
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Wednesday, April 25, 2018.
Unless otherwise noted in an attached project narrative, all samples were received in
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are in compliance with NELAC standards, except
as noted in the project narrative if applicable. This report shall not be reproduced except in
full, without the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
Chuck Smith
Project Manager
Enclosure(s)
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full, Page 1 of 10

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SAMPLE SUMMARY/LABORATORY CHRONICLE
Client ID: Outfa111
lab ID: CB01514-01
Sampled: 04/24/18 11:40
Received: 04/25/18 08.07
Parameter
EPA 351.2
Preoaradon
Same
Hold Data/Tlme(s)
05/22/18
Pren DatelTlme(s)
04/30/18 11:44
Analysts Date/Time(s)
05/03/18 14:03
EPA 353.2
NO PREP
04/26/18 11:40
04/25/18 18:02
04/Z5/18 18:02
EPA 353.2
NO PREP
01/17/21
05/07/18 14:55
05/07/18 15:07
EPA 365.4
Same
05/22/18
04/30/18 11:44
05/03/18 14:57
SM 2540D-1997
NO PREP
05/01/18
05/01/18 15:35
05/01/18 15:35
SM 5210B-2001
NO PREP
04/26/18 11:40
04/25/18 11:05
04/25/18 11:05
SM 5220D-1997
Same
05/22/18
04/26/18 10:42
04/26/18 21:06
Client ID: Outfail 1
Lab ID: CB01514-01RE1
Sampled: 04/24/18 11:40
Received: 04/25/19 08:07
Parameter
EPA 353.2
Preoaradon
NO PREP
Hold Date/Timefs)
05/22/18
Prep Date/Time(s)
05/04/18 16:39
Analysts Date/Tlme(s)
05/04/18 16:39
Client 10: Outfall 2
Lab ID: CB01514-02
Sampled: 04/24/18 12:30
Received: 04/23/18 08:07
Parameter
EPA 351.2
Preparation
Same
Hold Date/Time(s)
05/22/18
Prep Date/Time(s)
04/30/18 11:44
Analysis DatelTlme(sl
05/03/18 14:08
EPA 353.2
NO PREP
04/26/18 1230
0405/18 18:05
04/25/18 18:05
EPA 353.2
NO PREP
05/22/18
05/04/18 15:39
05/04/18 15:39
EPA 353.2
NO PREP
01/17/21
05/07/18 14755
OS/07/18 15:07
EPA 365.4
Same
05/22/18
04/30/18 11:44
05/03/18 15:01
SM 2540D-1997
NO PREP
05/01/18
05/01/18 15:35
05/01/18 15:35
SM 52108-2001
NO PREP
04/26/18 12:30
04/25/18 11:05
04/25/18 IhOS
SM 5220D-1997
Same
05/22/18
04/26/18 10:42
04/26/18 21:06
FINAL This report relates only to the sample as recelved by the laboratory, and may only be reproduced in full. Page 2 of 10

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SAMPLE DETECTION SUMMARY
Client ID: _ Outfall 1
tab ID:
CB01514-01
Anallrlm
Results
E11tU
Hu
Eltl.
mom
M13th� �L4t1:9
Biochemical Oxygen Demand
2.7
2.0
2.0
mg/L
SM 52108-2001
Chemical Oxygen Demand
14
10
10
mg/L
SM 5220D-1997
Nitrate as N
2.9
0.025
0.10
mg/L
EPA 3531
Nitrite as N
0.086
3
0.017
0.10
mg/L
EPA 353.2
Phosphorus
0.16
0.025
0.10
mg/L
EPA 365.4
Total Kjeldahl Nitrogen
1.3
0.26
0.48
mg/L
EPA 351.2
Total Suspended Solids
57
10
10
mg/L
SM 254OD-1997
Client ID: OuHell 1
Lab ID:
CB01514-OLRE1
Anal lda
Results
fhm
MU
EQL
malb
HeMod Notes
Nitrate/Nibl as N
3.0
0.20
0.50
mg/L
EPA 353.2
Client ID: Outfall 2
Lab ID:
CB01514-02
Al
Rssulta
Elan
MBL
EQL
Units
Mathes Notes
Biochemical Oxygen Demand
14
2.0
2.0
mg/L
SM 521OB-2001
Chemical Oxygen Demand
55
10
10
mg/L
SM 5220D-1997
Nitrate as N
0.046
3
0.025
0.10
mg/L
EPA 353.2
Nitrate/Nitrite as N
0.046
3
0.041
0.10
mglL
EPA 353.2
Phosphorus
0.10
0.025
0110
mg/L
EPA 365.4
Total Kjeldahl Nitrogen
1.0
0.26
0.48
mglL
EPA 351.2
Total Suspended Solids
16
10
10
mg/L
SM 254OD-1997
a
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In Full. Page 3 of 10

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ANALYTICAL RESULTS
Description: Outfall 1 Lab Sample ID. CB015 14-01 Received: 04/25/18 08:07
Matrix: Surface Water Sampled:04/24/18 11:40 Work Order: CB01514
Project: Stormwater Testing Sampled By:]oe Ladd
Classical Chemistry Parameters
^-EACOCary cer0 da-6-(NC 5911
Agaiyte [CAS Numberl Results
flag
Units
PE MU E91
ARI&h
Method
Analyzed
Notes
Biochemical Oxygen Demand^
2.7
mg/L
1 2.0 2.0
BD25014
SM 52148-2001
04/25/18 11:05
10C
Chemical Oxygen Demand^
14
mg/L
1 10 10
8D26008
SM 5220D-1997
04/26/18 21:D6
30C
Nitrate as N [14797-SS-8]^
2.9
mg/L
1 0,025 0.10
8E07038
EPA 353.2
05/07/18 15:07
3L]
Nitrate/Nlbite as N^
3.0
mg/L
5 0.20 0.50
8ED4037
EPA 353.2
05/04/18 16:39
3L1
Nitrite as N [14797-65-0]^
0.086 3
mg/L
1 0.017 0:10
8D25032
EPA 353.2
04/25/18 18:02
ILI
Phosphorus [7723-14-0]^
0.16
mg/L
1 0.025 0.10
8D30011
EPA 365.4
05/03/18 14:57
3U
Total Kjeldahl Nitrogen^
1.3
mg/L
1 0.26 0.48
BD30010
EPA 351.2
05/03/18 14:03
ILI
Total Suspended Solids
57
mg/L
4 10 10
8E01002
SM 7540D-1997
05/01/18 15:35
0MR
Description: Out%ll 2
Lab Sample ID-.CB01514-02
Received: 04/25/18 08:07
Matrix: Surface Water
Sampled:04/24/18 12:30
Work Order: CB01514
Project: Stormwater Testing
Sampled By:]oe Ladd
Classical Chemistry Parameters
^ - ENCO Cary certified analyre [NC 5911
Analyte rCAS Number] 801111to
gin
Units
QF
► u
pU
g=
Method
Analyzed
ax Note
Biochemical Oxygen Demand^
14
mg/L
1
2.0
2.0
8D25014
SM 52108-2001
04/25/18 11:05
10C
Chemical Oxygen Demand^
55
mg/L
1
10
10
8D26008
SM 5220D-1997
04/26/18 21:06
30C
Nitrate as N [14797-55-8]^
0.046
3
mg/L
1
0.025
0.10
8E07038
EPA 353.2
05/07/18 15:07
3U
Nitrate/Nitrite as N^
0.046
3
mg/L
1
0.041
0.10
8ED4037
EPA 353.2
05/04/18 15:39
3u
Nitrite as N [14797-65-0]^
0.017
u
mg/L
1
0.017
0.10
8D25032
EPA 353.2
04/25/18 18:05
3U
Phosphorus17723-14-0]^
0.10
mg/L
1
0.025
0.10
SD30011
EPA 365.4
05/03/18 15:01
3U
Total KJeldahl Nitrogen^
1.0
mg/L
1
0.26
0.48
8D30D10
EPA 351.2
05/03/18 14:08
3u
Total Suspended Solids^
16
mg/L
4
10
10
BE01002
SM 254OD-1997
05/01/18 15:35
DMR
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 4 of 10

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QUALIFY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch BD25014 - NO PREP
Blank (BD25014-BLKl) Prepared & Analyzed: 04/25/2018 11:05
Spike Source %REC RPD
.Anallds Result F.184 ML Volts Level Result %REC Limits RPD Llm(t Notes
Biochemical Oxygen Demand 2.0 U 2.0 mg/L
LCS (8D25014-BSL) Prepared & Analyzed: 04/25/2018 11:05
Spike Source %REC
RPD
Anal tds
Reiuit Elan
P41
Units
Level Resul %REC Limits
RPD Limit Notes
Biochemical Oxygen Demand
210
2.0
mg/L
198 107 85-115
Duplicate (8025014-DUPl)
Prepared & Analyzed: 04/25/2018 11:05
Source. C501314-01
Spike Source %REC
RPD
Anal ][te
RUMM E109
PAL
UwU
Level Result %REC Limits
RPD Limit Notes
Biochemical Oxygen Demand
216
2.0
mg/L
2.7
3 30
Batch OD25032 - NO PREP
Blank (BD25032-BLK1)
Prepared: 04/25/2018 18:01 Analyzed: 04/25/2018 18:01
Spike Source %REC
RPD
Anal lrt®
Result
Ela2
P4L
Units
Level Result %REC Limits RPD
Lbh Note
Nitrite as N
0.017
U
0.10
mg/L
LCS (8D25032.851)
Prepared: 04/25/2018 18:12 Analyzed: 04/25/2018 18:12
Spike Source %REC
RPD
Aneltte
Result
Elan
M
Units
Level Result %REC Limits RPD
Limp Notes
Nitrite as N
0.99
0.10
mg/L
1.00 99 90.110
LCS (8D25032-BS2)
Prepared: 04/26/2018 10:43 Analyzed: 04/26/2018 10:43
Spike Source %REC
RPD
-Analyze
Result
Elan
POL
Units
Level Result %REC Limits RPD
Ljm[t Notes
Nitrite as N
0.96
0.10
mg/L
1.00 96 90-I10
LCS (8D25032-BS3)
Prepared: 04/26/2018 10:46 Analyzed: 04/26/2018 10:46
Spike Source %REC
RPD
Anal Yte
Result
Elan
PM
Units
Level Result %REC Limits RPD
Llm[t Notes
Nitrite as N
0.96
0.10
mg/L
1.00 96 90-110
Matrix Spike (8D25032-MS1)
Prepared: 04/25/2018 18:03 Analyzed: 04/25/2018 18:03
Source: C001514-01
Spike Source %REC
RPD
Anal Yta
Result
F1ao
P4L
Units
Level flasult %REC . Llmlts RPD
limit Notes
Nitrite as N
1.1
0.10
mg/L
1.00 0.086 99 90-110
Matrix Spike (8025032-MS2)
Prepared: 04/25/2018 18:06 Analyzed: 04/25/2018 18:06
Source: CROIS14-02
Spike Source %REC
RPD
.Anal lfte
Result
flag
P4L
Unita
Level Result %REC Limltg RPD
Limit Notes
Nitrite as N
0.98
0.10
mg/L
1.00 0.017 U 98 90-110
Matrix Spike Dup (BD25032-MSD1)
Prepared: 04/25/2018 18:04 Analyzed: 04/25/2018 18:04
Source: C001514-01
Spike Source %REC
RPD
Anal fde
112sulf
EI84
E41
Units
Level Result %REC Limits RPD
LIMR Notes
FINAL
This report relates
only to the sample as recelved by the laboratory, and may only be reproduced In full.
Page 5 of 10

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 8D25032 - NO PREP - Condhoed
Matrix Spike Dup (BD25032-MSDI) Continued Prepared: 04/25/2018 18:04 Analyzed: 04/25/2018 18:04
Source: CB01514-01
Spike Source %REC RPD
Anallds Result film POL tln[ts Level Result %REC Llmlta RPD Limit Notes
Nitrite as N 1.1 0.10 mg/L 1.00 0.086 100 90-110 0.9 10
Balch 8D26008 - Same
Blank (SD26008-BLKl) Prepared: 04/26/2018 10:42 Analyzed: 04/26/2018 21:06
Spike Source %REC
RPD
Anal 1
ies111t
Elea
IPQL
Slnits
Level Result %REC Limits RPD
Llmlt Notes
Chemical Oxygen Demand
10
U
10
mg/L
LCS (8D26008-BS3)
Prepared: 04/26/2018 10:42 Analyzed: 04/26/2018 21:06
Spike Source %REC
RPD
Anal srte
Result
Elan
PQL
units
Level Result %REC u nrits RPD
LltDlt dotes
Chemical Oxygen Demand
480
10
mg/L
500 96 90-110
Matrix Spike (8026008-MSI)
Prepared: 04/261201B 10:42 Analyzed: 04/26/2018 21:06
Source: CB01514-01
Spike Source %REC
RPD
Anal 1
Result
Flag
POL
Units
Level Result %REC Limits RPD
Limb Notes
Chemical Oxygen demand
550
10
mg/L
526 14 101 90.110
Matrix Spike Dup (BD26008-MSD3)
Prepared: 04/26/2018 10:42 Analyzed: 04/26/2018 21:06
Source:CB01514-01
Spike Source %REC
RPD
Anall[te
Result Elaa P- 1
uAlta
Level Result %REC Limits RPD
Limit Notes
Chemical Oxygen Demand
550 10
mg/L
526 14 101 90-110 0.4
10
Batch 8030010 - Same
Blank (BD30010-BLK1)
Prepared: 04/30/2018 11:44 Analyzed: 05/03/2018 13:59
Spike Source %REC
RPD
.AnalYts
Result Elan M
clops
Level Result %REC Limi>s RPD
Limit Notes
Total Kjeldahl Nitrogen
0.26 U 0.48
mglL
LCS (8D30030-BSI)
Prepared: 04/30/2018 11:44 Analyzed: 05/03/2018 14:01
Spike
Source
%REC
RPD
Anal ][t8
Result fin PM
!lops
Level
Sesuls
%REC
LIMjg RPD
Limit Notes
Total Kjeldahl Nitrogen
12 0.48
mg/L
12.0
97
90-110
Matrix Spike (811330010-M53)
Prepared: 04/30/2018 11:44 Analyzed: 05/03/2018 14:05
Source: C001514-01
Spike
Source
%REC
RPD
-llnallde
Result Flag P_QL
units
Level
Result
%REC
Limits RPD
Llmlt Notes
Total Kjeldahl Nitrogen
5.9 0.48
mg/L
4.80
1.3
96
90-110
Matrix Spike (811)30010-M52)
Prepared: 04/30/2018 11:44 Analyzed: 05/03/2018 14: 10
Source: C001514-02
Spike
Source
%REC
RPD
.Anal Yil4
Result Elan PM
Units
Level
Maul
%REC
Limits RPD
Limn )Votes
Total Kjeldahl Nitrogen
5.9 0,48
mg/L
4.80
1.0
102
90-110
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 6 of 1a

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch SD30010 - Same - Continued
Matrix Spike Dup (81330010-11411501)
Prepared: 04/30/2018 11:44 Analyzed: 05/03/2018 14:06
Source: CB01514-01
Spike Source %REC
RPD
Anal
Result
Sao
POL
Units
Level Result %REC Limltt RPD
Limit Nme9_
Total Kjeldahl Nitrogen
6.0
0.48
mg/L
4.80 1.3 98 90-110 1
10
Batch BD30011 - same
Blank (8D30011-8LK1)
Prepared: 04/30/2018 11:44 Analyzed: 05/03/2018 14:54
Spike Source %REC
RPD
Anal
Result
fin
PQL
UAM
Level Result %REC Lialb RPD
UMR tiotes
Phosphorus
0.042
3
0.10
mg/L
LCS (BD30011-BS3)
Prepared: 04/30/2018 11:44 Analyzed: 05/03/2018 14:56
Spike Source %REC
RPD
Ana
Result
Flap
POL
Unm
Level Reallii %REC Limits RPD
Limit Notes
Phosphorus
1.5
0.10
mg/L
1.60 96 BO-120
Matrix Spike (BD30011-MS1)
Prepared: 04/30/2018 11:44 Analyzed: 05/03/2018 14:58
Source: CB01514-01
Spike Source %REC
RPD
Anal lrse
Rumit
Elan
EM
Units
Level Resin %REC Limits RIND
Limit dotes
Phosphorus
0.82
0.10
mg/L
0.640 0.16 102 80-120
Matrix Spike Dup (81330011-M51131)
Prepared: 04/30/2018 11:44 Analyzed: 05/03/2018 15:00
Source: C001514-01
Spike Source %REC
RPD
AnaL1tt®
Result
Elate
PQL
Units
Level Result %REC Limits RPD
Limit Notes
Phosphorus
0.77
0.10
mg/L
0.640 0.16 95 80-120 6
25
Batch SEOIOOZ - NO PREP
Blank (8E01002-BLK1) Prepared & Analyzed: 05/01/2018 15:35
Spike Source - %REC RPD
Anal vte Result Elal7 POL Units Level Result %REC LimJtg RPD ;unit Notes
Total Suspended Solids 2.5 U 2.5 mg/L
LCS (SE01002-BS1) Prepared & Analyzed: 05/01/2018 15:35
Spike Source %REC
RPD
Anal Yte
Resin flag P4L
11111113
Level Resin %REC Limits
RPD
j,imit Notes -
Total Suspended Solids
88 2.5
mg/L
100 88 80-120
Duplicate (BE01002-131JI131)
Prepared & Analyzed: 05/01/2018 15:35
Source: CRO1514-01
Spike Source %REC
RPD
Anal
Result Elan POL
Units
Level Besult %REC Limlt>}
RPD
Limit Notes
Total Suspended Solids
53 10
mg/L
57
7
20
Duplicate (SE01002-DUP2)
Prepared & Analyzed: 05/01/2018 15:35
Source: CB01690-01
Spike Source %REC
RPD
Anal tda
Result Flag PQL
units
Level ResulF %REC Limits
RPD
Limit !Notes
Total Suspended Solids
100 12
mg/L
110
0.5
20
Batch BE04037 - NO PREP
FINAL
This report relates only to the sample as recelwd by the laboratory, and may only be reproduced In full.
Page 7 of 10

www.encolabs.com
QUALITY CONTROL DATA
Classical Chemistry Parameters - quality Control
Batch 8E04037 - NO PREP - Candnued
Blank (BE04037-BLKi) Prepared: 05/04/2018 15:30 Analyzed: 05/04/2018 15:30
Spike Source %REC RPD
Anal lfts Result Etna POL halts Level USUIi %REC Limits RPD Limit Notes
Nitrate/Nitrite as N 0.041 U 0.10 mg/L
LCS (8E04037-111S3) Prepared: 05/04/2018 15:32 Analyzed: 05/04/2018 15:32
Spike Source %REC
RPD
Anal l[ts
Result
Elan
POL
Lill ie
Level Result a/aREC Limits RPD
Limit Notes
Nitrate/Nitrite as N
1.2
0.10
mg/L
1.25 99 90-110
Matrix Spike (SE04037-MS1)
Prepared: 05/04/2018 16:40 Analyzed: 05/04/2018 16:40
Source: CBOLS14-01RE1
Spike Source %REC
RIM
Anal
Res11it
Elea
P_QL
hells
Level Result %REC LWIM RPD
Limit Notes
Nitrate/Nitrite as N
5.3
0.50
mg/L
2.50 3.0 93 90-110
Matrix Spike (BE04037-MS2)
Prepared: 05/04/2018 15:41 Analyzed: 05/04/2018 15:41
Source: CB0LS14-02
Spike Source %REC
RPD
Anal Yte
Result
an
P- 1
iialcs
Level Result %REC Limits RPD
Limit Notes
Nitrate/Nitrite as N
0.61
0.10
mg/L
0.521 0.046 108 90-110
Matrix Spike Dup (SE04037-MSDi)
prepared: 05/04/2018 16:41 Analyzed: 05/04/2018 16:41
Source: CB01514-0111M
Spike Source %REC
RIM
Anal ldn
Result
Elan
POL
ilnits
Level Result %REC Limits RPD
Limit Notes
Nltrate/Nitrite as N
5.2
0.50
mg/L
2.50 3.0 91 90-110 0.9
10
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 8 of 10

www.enoDiabs.com
FLAGS/NOTES AND DEFINITIONS
B The analyte was detected in the associated method blank.
D The sample was analyzed at dilution.
3 The reported value is between the laboratory method detection limit (MDQ and the laboratory method
reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable.
U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
E The concentration indicated for this analyte is an estimated value above the calibration range of the
instrument. This value is considered an estimate.
MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution
factor, and, in the case of soil samples, moisture content.
PQL PQL: Practical Quantitation Limit.
N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater
confidence) to make a "tentative identification".
P Greater than 25% concentration difference was observed between the primary and secondary GC column.
The lower concentration is reported.
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 9 of 10

enrsnvnen�taxrlLLAJlVar-nVM11Moll LJ4OUnMlUrilC.7 L.r1Hl1Y-Uti.U,IULJT Kt%;UKU www.encolabS.COM
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Sample Preservation Verification
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12-OCT-2007 - 2007-50
05-JUL-2010 2010-2589 Notification
DREWCHLORO 4107
INDUSTRIAL
GUARANTEE:
SODIUM CHLORITE ...... 25%
REGISTRATION No. 24887 PEST CONTROL PRODUCTS ACT
KEEP OUT OF REACH OF CHILDREN
DANGER
POISON - CORROSIVE
CORROSIVE TO EYES AND SKIN
READ THE LABEL BEFORE USING
NET CONTENTS XWGTX
LOT # X BATX
DREW CANADA, ASHLAND CANADA CORP. Ashland Canada Corp.
525 FINLEY AVE., AJAX, ONTARIO L1S 2E5 2620 Royal Windsor Drive
Tel: [phone] Mississauga, Ontario
Fax: [phone]
AFTER HOURS: 1-800-274-5263 L5J 4E7
LIQUID BLEND OF SODIUM CHLORITE FOR USE AS ALGICIDE AND SLIMICIDE IN
RECIRCULATING COOLING WATER SYSTEMS.
USE RESTRICTION:
This product is to be used only in closed system chlorine dioxide generators for controlling slime
forming organisms in industrial re -circulating cooling waters. Follow all instructions for the chlorine
dioxide generator carefully and follow all safety measures required for the use of this product and
the generator. Generators are to be installed, adjusted and maintained by specially trained service
representatives only.
DIRECTIONS FOR USE:
RECIRCULATING COOLING WATER SYSTEMS

0 0,
1) Drewchlor 4107 is to be used only in closed system generators designed specifically for
generating chlorine dioxide. Eg. GENEROX one, or three pump systems. Read carefully and follow
all instructions for operating and maintaining the chlorine dioxide generator. Operators and
maintenance personnel require specialized training.
2) For continuous treatment, maintain a point source residual chlorine dioxide level of 0.5 ppm to
5.0 ppm depending on microbial pressure on the system. For cleaning systems and for slug or
intermittent treatment, treat the system to obtain a point source level of 5.0 ppm to 100 ppm chlorine
dioxide in the system. Refer to Drew analytical methods to determine the chlorine dioxide demand
and to calculate appropriate residual chlorine dioxide levels for the system."
3) "Read the product safety bulletin for Drewchlor 4107 and the product safety bulletin and MSDS
sheets for co -reactants prior to using this product.
ONE PUMP METHOD:
For intermittent feed add 2.555 to 51.1 ppm DREWCHLOR* 4107 and 2.630 to 52.6 ppm chlorine
gas. For continuous feed add 0.255 to 2.555 ppm of DREWCHLORO 4107 and 0.263 to 2.630 ppm
of chlorine gas.
THREE PUMP SYSTEM:
For intermittent feed add 2.555 to 51.1 ppm DREWCHLOe 4107, 2.15 to 43.0 ppm DREW 6110
(sodium hypochlorite) and 0.90 to 18.0 ppm DREW 6005 (hydrochloric acid). For continuous feed
add 0.255 to 2.555 ppm DREWCHLOR® 4107, 0.215 to 2.15 ppm DREW 6110 (sodium
hypochlorite) and 0.09 to 0.9 ppm DREW 6005 (hydrochloric acid).
i;1:��L�I1��C�L`L•�
KEEP OUT OF REACH OF CHILDREN. DANGER - CORROSIVE TO EYES AND SKIN. Harmful if
swallowed or inhaled. Do not get in eyes, on skin, mucous membranes or on clothing. Do not
inhale. Wear long sleeved shirt and long pants, chemical resistant gloves, goggles or face shield, a
chemical resistant apron and boots when handling this product. Wash thoroughly with soap and
water after handling and before eating, drinking, smoking and using toilet. Remove contaminated
clothing and wash before reuse. DO NOT WEAR contaminated clothing.
PHYSICAL AND CHEMICAL CAUTIONS:
This material is corrosive and a strong oxidizing agent. Contact with organic matter may cause fire
or explosion. Mixing with acids or alcohol or other chemicals may cause evolution of chlorine and
chlorine dioxide gas mixture which is toxic and may be explosive. Avoid contamination with
combustible materials such as oils, grease, solvents, paint products etc as rapid burning may occur.
STORAGE: Store in a cool, dry area. (<250C)
FIRST AID:
CONTACT WITH SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20
minutes. Cali a poison control centre or doctor for treatment advice.
INGESTION: Call a poison control centre or doctor immediately for treatment advice. Have person sip a
glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control centre
or doctor. Do not give anything by mouth to an unconscious person.
CONTACT WITH EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove
contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control centre or
doctor for treatment advice.
INHALATION: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial
respiration, preferably by mouth -to mouth, if possible. Call a poison control centre or doctor for further treatment'
advice.
Take container, label or product name and Pest Control Product Registration Number with you
when seeking medical attention.

TOXICOLOGICAL INFORMATION: Treat symptomatically.
DISPOSAL:
1. Triple- or pressure- rinse the empty container. Add the rinsings to the treatment site.
2. Follow provincial instruction for any required additional cleaning of the container prior to its
disposal,
3. Make the empty container unsuitable for further use.
4. Dispose of the container in accordance with provincial requirements.
5. For information on disposal of unused, unwanted product, contact the manufacturer or the
provincial regulatory agency. Contact the manufacturer and the provincial regulatory agency in
case,of a spill, and for clean-up of spills.
ENVIRONMENTAL PRECAUTIONS;
This product is highly toxic to aquatic invertebrates and moderately toxic to water fowl. Do not
contaminate lakes, ponds, rivers, streams, estuaries, or oceans, by direct application, cleaning of
equipment or disposal of wastes. Do not discharge effluent that has been treated with chlorine
dioxide generated by this product into these waters unless the effluent has been detoxified by
suitable means such as waste treatment. For further environmental information refer to Drew
Environmental Profile sheet OX-EP-003 . Open dumping is prohibited.
DECONTAMINATION:
Contain spilled material, then add sodium sulfite at 2.8 parts per 1 part of sodium chlorite. Do not
allow oxidizable or other incompatible materials to come into contact with spilled material. Use
copious amounts of water to flush the residual to a sanitary sewer or waste treatment plant. DO
NOT FLUSH INTO SURFACE WATERS.
NOTICE TO USER: This pest control product is to be used only in accordance with the directions on the
label. It is an offence under the Pest Control Products Act to use this product in a way that is inconsistent
with the directions on the label. The user assumes the risk to persons or property that arises from any such
use of this product.
UN# 1908 Sodium chlorite solution, with more than 5% available chlorine

This label transcript service is offered by the Pest Management Regulatory Agency to provide
efficient searching for label information. This service and this information do not replace the
official hard -copy label. The PMRA does not provide any guarantee or assurance that the
information obtained through this service is accurate, current or correct, and is therefore not
liable for any loss resulting, directly or indirectly, from reliance upon this service.

r1
30-JUL-2007
22-APR-2010 2010-1112 Notification : Change in registrant name
CLOSURE CENTRAL PM
For use in Closed System Mechanical Generation of Chlorine Dioxide only for Microbial
Control in Recirculating Cooling Systems and Pulp and Paper Mills
COMMERCIAL
READ THE LABEL BEFORE USING
GUARANTEE:
Chlorine Dioxide from Sodium Chlorite.............................25% (nominal)
DANGER
POISON
CORROSIVE
TO EYES AND SKIN
REGISTRATION NO 28674 PEST CONTROL PRODUCTS ACT
Net Contents; (5L to 1249L)
JohnsonDiverscy Canada, Inc. Diversey Canada Inc.
2401 Bristol Circle, Oakville, Ontario L6H 6P 1
Canada 800-668-7171

0
0
,
4-3.
.
�
4 1
.
4

Use Restriction: This product is only to be used in closed system chlorine dioxide
generators for controlling slime forming organisms in pulp and paper process waters.
Follow all instructions for the chlorine dioxide generator carefully and follow all safety
measures required for the use of this product and generator. Generators are to be
installed, adjusted and maintained by specially trained service representatives only.
DIRECTIONS FOR USE
CLOSURE CENTRAL PM is a source of chlorine dioxide used for microbial control in
recirculating cooling towers and pulp and paper mill processing water. The required dosage rate,
frequency and concentration will'vary for each user depending on the degree of microbiological
and process contamination present, the temperature and.the pH. Typical concentrations of
chlorine dioxide are between 0.5 - 5.0 ppm for continuous doses, and between 5.0 ppm and 100
ppm for intermittent shock doses.
To generate chlorine dioxide, use a chlorine dioxide generator. Consult product bulletin and also
the instructions on the chlorine dioxide generation system before using CLOSURE CENTRAL
PM. Your JohnsonDiversey representative can guide you in the selection, installation and
operation for feed systems. The generators react CLOSURE CENTRAL PM to produce an
aqueous solution of chlorine dioxide. This solution is then added at a point in the.processing
system to be treated which ensures uniform mixing. Feed points should be well below the surface
of the water to prevent volatilization of the chlorine dioxide. Do not apply CLOSURE
CENTRAL PM directly to the system being treated. Follow all instructions in the chlorine
dioxide generator manual carefully.
PRECAUTIONS
KEEP OUT OF REACH OF CHILDREN. DANGER - CORROSIVE TO EYES AND SKIN.
Maybe fatal if absorbed through the skin, swallowed or inhaled. Do not get in eyes, or on skin,
or clothing. Do not inhale. Wear a long sleeved shirt and long pants, chemical resistant gloves,
goggles or face shield and chemical resistant apron and boots when handling this product. Wash
thoroughly with soap and water after handling and before eating, drinking,
smoking and using the toilet. Remove contaminated clothing and wash before reuse. DO
NOT WEAR contaminated clothing.
Environmental Hazards: This product is highly toxic to aquatic invertebrates and
moderately toxic to waterfowl. Do not contaminate lakes, ponds, rivers, streams, estuaries
or oceans by direct application, cleaning of equipment or disposal of wastes. Open
dumping is prohibited. Do not discharge effluent that has been treated with chlorine
dioxide generated by this product into these waters unless the effluent has been
detoxified by suitable means such as waste treatment.
Chemical Hazards: Sodium chlorite is corrosive and a strong oxidizing agent. Contact
with organic matter may cause fire or explosion. Mix only into water. Mixing with acids,
alcohol or other chemicals may cause evolution of chlorine and chlorine dioxide gas which
is toxic and may be explosive. Avoid contaminating with combustible materials, such as
oils, grease, solvents, and paint products as rapid burning may occur.

FIRST AID
If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water
for 15-20 minutes. Call a poison control centre or doctor for treatment advice.
If swallowed: Call a poison control centre or doctor immediately for treatment advice. Have person
sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control
centre or doctor. Do not give anything by mouth to an unconscious person.
If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact
lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control centre or doctor
for treatment advice.
If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial
respiration, preferably by mouth-to-mouth, if possible. Call a poison control centre or doctor for further
treatment advice.
Take container, label or product name and Pest Control Product Registration Number with you when seeking
medical attention.
TOXICOLOGICAL INFORMATION
Treat symptomatically.
STORAGE:
Do not contaminate water, food or feed by storage or disposal. Keep product in tightly closed
container when not in use. Do not drop, roll or skid drum. Keep upright. Always replace cover.
Store in a cool (< 25°C), dry, well -ventilated area away from heat or open flame.
DISPOSAL:
• Triple or pressure -rinse the empty container. Add the rinsings to the treatment site.
• Follow provincial instruction for any required additional cleaning of the container prior to its disposal.
• Make the empty container unsuitable for further use. Dispose of the container in accordance with provincial
requirements.
• For information on disposal of unused, unwanted product, contact the manufacturer or the provincial
regulatory agency. Contact the manufacturer and the provincial regulatory agency in case of a spill, and
for clean-up of spills.
DECONTAMINATION
• Contain spilled material.
• Do not allow oxidizable or other incompatible materials to come into contact with spilled materials.
• DO NOT FLUSH INTO SURFACE WATERS.
NOTICE TO USER
This pest control product is to be used only in accordance with the directions 'on the label. It is an
offence under the Pest Control Products Act to use this product in a way that is inconsistent with
the directions on the label. The user assumes the risk to persons or property that arises from any
such use of this product.

Y • •
This label transcript service is offered by the Pest Management Regulatory Agency to provide
efficient searching for label information. This service and this information do not replace the
official hard -copy label. The PMRA does not provide any guarantee or assurance that the
information obtained through this service is accurate, current or correct, and is therefore not
liable for any loss resulting, directly or indirectly, from reliance upon this service.

•
v
ASHLAIO
SAFETY DATA SHEET
DREWTM 6134 DECHLORINATING
AGENT 51057
Page: 1
Revision Date: 01/24/2008
Print Date: 6/11/2008
MSDS Number: R0290797
Version: 1.2
1.. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Ashland Regulatory Information Number 1-800-325-3751
P.O. Box 2219 Telephone [phone]
Columbus, OH 43216 Emergency telephone 1-800-ASHLAND
(1-800-274-5263)
Product name DREW rm 6134 DECHLORINATING AGENT
Product code 51057
Product Use Description No data
2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance: liquid„ light yellow
DANGER! MAY BE HARMFUL IF INHALED. HARMFUL IF SWALLOWED.
CAUSES EYE IRRITATION. MAY CAUSE SKIN AND RESPIRATORY TRACT
IRRITATION. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND
CAUSE DERMATITIS AND BURNS.
Potential Health Effects
Routes of exposure
Inhalation, Skin contact, Eye Contact
Eye contact
Can cause severe eye irritation. Symptoms include stinging, tearing, redness, and
swelling of eyes. Can injure eye tissue.
Skin contact
Can cause skin irritation. Symptoms may include redness and burning of skin,
and other skin damage. Additional symptoms of skin contact may include: allergic skin
reaction (delayed skin rash which may be followed by blistering, scaling and other skin
effects)
Ingestion
Swallowing this material may be harmful.
Page 1 / 8

•
•
jASWLAN13.
SAFETY DATA SHEET
DREWTM 6134 DECHLORINATING
AGENT 51057
Page: 2
Revision Date: 01 /24/2008
Print Date: 6/11/2008
MSDS Number: R0290797
Version: 1.2
Inhalation
It is possible to breathe this material under certain conditions of handling and use
(for example, during heating, spraying, or stirring). Breathing small amounts of this
material during normal handling is not likely to cause harmful effects. Breathing large
amounts may be harmful. Excessive heat or contact with acids, water and/or ice, releases
sulfur dioxide gas which may be harmful or deadly'if inhaled.
Aggravated Medical -Condition
Preexisting disorders of the following organs (or organ systems) may be
aggravated by exposure to this material:, Skin, lung (for example, asthma -like conditions)
Symptoms
Signs and symptoms of exposure to this material through breathing, swallowing,
and/or passage of the material through the skin may include:, stomach or intestinal upset
(nausea, vomiting, diarrhea), irritation (nose, throat, airways), convulsions, and death,
Exposure to this product (or a component) may cause an allergic reaction (narrowing of
the air passages of the lungs resulting in difficult breathing, tightness in the chest,
coughing and wheezing) in some sensitive individuals. Other symptoms of an allergic
reaction may include itchy and watery eyes, runny and stuffy nose, sweating, flushing,
hives, rapid heart, rate, and lowered blood pressure.
Target Organs
No data
Carcinogenicity
No data
Reproductive hazard
No data
Other information
Exposure to this material may cause severe or fatal allergic reaction in some
asthmatics and sulfite sensitive individuals. Allergic reactions are immediate following
breathing, injection or ingestion of oral solutions. Ingestion of solids or food particles
may delay the onset of symptoms, with a maximal effect 30 to 90 minutes after ingestion.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Paget/8

ONE
•
ASHLAND
SAFETY DATA SHEET
DREWTM 6134 DECHLORINATING
AGENT 51057
Page: 3
Revision Date: 01/24/2008
Print Date: 6/11/2008
MSDS Number: R0290797
Version: 1.2
_Components CAS -No. _ _ _ Concentration
SODIUM HYDROGEN SULFITE 7631-90-5 >=40-<50%
INORGANIC SALT NJTS# 254504001-5245 >=5-<10%
SODIUM SULFITE 7757-83-7 >= 5-<10%
4. FIRST AID MEASURES
Eyes
If symptoms develop, immediately move individual away from exposure and into
fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids
apart; seek immediate medical attention.
Skin
Remove contaminated clothing. - Flush exposed area with large amounts of water.
If skin is damaged, seek immediate medical attention. If skin is not damaged and
symptoms persist, seek medical attention. Launder clothing before reuse.
Ingestion
Seek medical attention. If individual is drowsy or unconscious, do not give
anything by mouth; place individual on the left side with the head down. Contact a
physician, medical facility, or poison control center for advice about whether to induce
vomiting. If possible, do not leave individual unattended.
Inhalation
If symptoms develop, immediately move individual away from exposure and into
fresh air. Seek immediate medical attention; keep person warm and quiet.' If person is
not breathing, begin artificial respiration. If breathing is difficult, administer oxygen.
Notes to physician
Hazards: No information available.
Treatment: No information available.
5. FIRE -FIGHTING MEASURES
Suitable extinguishing media
Water spray
Hazardous combustion products
May form:, sulfur dioxide
Page 3 / 8

•
C
SAFETY DATA SHEET
DREWTM 6134 DECHLORINATING
AGENT 51057
Page: 4
Revision Date: 01/24/2008
Print Date: 6/11 /2008
MSDS Number: R0290797
Version: 1.2
Precautions for tire -fighting
No special fire hazards are known to be associated with this product.Wear full
firefighting turn -out gear (full Bunker gear), and respiratory protection (SCBA). Use
water spray to cool fire exposed containers and structures until fire is out if it can be done
with minimal risk. Avoid spreading burning liquid with water used for cooling purposes.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
No data
Environmental precautions
No data
Methods for cleaning up
Persons not wearing protective equipment should be excluded from area of spill
until clean-up has been completed. Stop spill at source, dike area of spill to prevent
spreading, pump liquid to salvage tank. Remaining liquid may be taken up on sand, clay,
earth, floor absorbent, or other absorbent material and shoveled into containers. Absorb
liquid on vermiculite, floor absorbent or other absorbent material.
7. HANDLING AND STORAGE
Handling
Containers of this material may be hazardous when emptied. Since emptied
containers retain product residues (vapor, liquid, and/or solid), all hazard precautions
given in the data sheet must be observed.
Storage
No data
$. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
SODIUM HYDROGEN SULFITE 7631-90-5
ACGIH time weighted average 5 mg/m3
NIOSH Recommended exposure limit 5 mg/m3
Page 4 / 8

11
ASHLANI.
SAFETY DATA SHEET
DREWTM 6134 DECHLORINATING
AGENT 51057
(REQ:
General advice
Page: 5
Revision Date: 01/24/2008
Print Date: 6/ 11 /2008
MSDS Number: R0290797
Version: 1.2
These recommendations provide general guidance for handling this product.
Personal protective equipment should be selected for individual applications and should
consider factors which affect exposure potential, such as handling practices, chemical
concentrations and ventilation. It is ultimately the responsibility of the employer to
follow regulatory guidelines established by local authorities.
Exposure controls
Provide sufficient mechanical (general and/or local exhaust) ventilation to
maintain exposure below TLV(s).
Eye protection
Chemical splash goggles in compliance with OSHA regulations are advised;
however, OSHA regulations also permit other type safety glasses. Consult your safety
representative.
Skin and body protection
Wear resistant gloves (consult your safety equipment supplier).
To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
Respiratory protection
If workplace exposure limit(s) of product or any component is exceeded (see
exposure guidelines), a NIOSH-approved air supplied respirator is advised in absence of
proper environmental control. OSHA regulations also permit other NIOSH respirators
(negative pressure type) under specified conditions (see your industrial hygienist).
Engineering or administrative controls should be implemented to reduce exposure.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state
Form
Colour
Odour
Boiling pointlboilingrange
Melting point/range
PH
Flash point
Evaporation rate
Page 5/8
liquid
No data
light yellow
sulphurous
216.00 OF / 216 OF@ 760.00 mmHg
26 °F / -3 °C
4.5
No data
< 1 (N-Butyl Acetate)

ASHLANa
SAFETY DATA SHEET
DREWTM 6134 DECHLORINATING
AGENT 51057
Explosion limits
Vapour pressure
Vapour density
Density
Solubility
Partition coefficient: n-
octanol/water
Autoignition temperature
10. STABILITY AND REACTIVITY
Stability
Stable.
Conditions to avoid
Avoid contact with:
Page: 6 .
Revision Date: 01/24/2008
Print Date: 6/11/2008
MSDS Number: R0290797
Version: 1.2
No data
14.00 mmHg @ 77.00 °F / 25.00 °C
0.6 (A1R=1)
1.34 g/cm3 @ 68.00 °F 120.00 °C
11.23 lb/gal @ 68.00 °F 120.00 °C
completely soluble in water
No data
No data
Incompatible products
Avoid contact with:, strong acids, strong oxidizing agents
Hazardous decomposition products
May form:, sulfur dioxide
Hazardous reactions
Product will not undergo hazardous polymerization.
Thermal decomposition
No data
It. TOXICOLOGICAL INFORMATION
Acute oral toxicity
SODIUM HYDROGEN SULFITE
INORGANIC SALT
SODIUM SULFITE
Page 6 / 8
LD 50 Rat: 2,000 mg/kg
LD 50 Mouse: 5,989 mgtkg
LD 50 Mouse: 820 mgtkg

•
ASHLAN13.
SAFETY DATA SHEET
DREW'rm 6134 DECHLORINATING
AGENT 51057
Acute inhalation toxicity
Acute dermal toxicity
12. ECOLOGICAL INFORMATION
Aquatic toxicity
Acute and Prolonged Toxicity to Fish
No data
Acute Toxicity to Aquatic Invertebrates
No data
Environmental fate and pathways
No data
13. DISPOSAL CONSIDERATIONS
Page; 7
Revision Date: 01 /24/2008
Print Date: 6/11/2008
MSDS Number: R0290797
Version: 1.2
Waste disposal methods
Dispose of in accordance with all applicable local, state and federal regulations.
For assistance with your waste management needs - including disposal, recycling and
waste stream reduction, contact Ashland Distribution's Environmental Services Group at
800-637-7922.
14. TRANSPORT INFORMATION
IMDG:
UN2693, BISULPHITES, AQUEOUS SOLUTION, N,O.S. (SODIUM HYDROGEN
SULFITE, ) 8, III
IATA_P:
UN2693, Bisulphites, aqueous solution, n.o.s. (SODIUM HYDROGEN SULFITE,
8,111
IATA_C:
UN2693, Bisulphites, aqueous solution, n.o.s. (SODIUM HYDROGEN SULFITE,
8,111
CFR ROAD:
Page 718

SHLAND.
SAFETY DATA SHEET
DREWTm 6134 DECHLORINATING
AGENT 51057
Page: 8
Revision Date: 01 /24/2008
Print Date: 6/11/2008
MSDS Number: R0290797
Version: 1.2
UN2693, Bisulfites, aqueous solutions, n.o.s. (SODIUM HYDROGEN SULFITE, )
8,111
CFR_RAIL:
UN2693, Bisulfites, aqueous solutions, n.o.s. (SODIUM HYDROGEN SULFITE, }
8,111
CFR iNWTR:
UN2693, Bisulfites, aqueous solutions, n.o.s. (SODIUM HYDROGEN SULFITE, }
8,111
Dangerous goods descriptions (if indicated above) may not reflect package size, quantity,
end -use or region -specific exceptions that can be applied. Consult shipping documents for
descriptions that are specific to the shipment.
15. REGULATORY INFORMATION
California Prop. 65
This product does not contain any chemicals known to State of California to cause cancer,
birth, or any other reproductive defects.'
SARA Hazard Classification Acute Health Hazard
SARA 313 Component(s)
Health Flammability Reactivity Other
HMIS 2* 0 0
NFPA 2 0 0
16.OTHER INFORMATION
The information accumulated herein is believed to be accurate but is -not warranted to be
whether originating with the company or not. Recipients are'advised to confirm in advance
of need that the information is current, applicable, and suitable to their circumstances. This
MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-
800-325-3751).
Page 8 / 8

•
00
BIOCIDE/CHEMICAL TREATMENT
WORKSHEET-FORM 16
lowin calculations are to be performed on any biocidai products, ultimately discharged to the surface waters of
The fol �
North Carolina. This worksheet must be completed separately for each blocidal product in use. This worksheet is to e
retumed with all appropriate data entered into the designated areas with calculations performed as indicated.
Facility Name
#
NPDES # NC Outfall
County
7Q10 D• S- (cfs)
Receiving Stream
(All above information supplied by the Division of Water Quality)
What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water body?
A.D.D. = V. 2XV (in M.G.D.)
Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered
above.
IWC = (A•D.D.) X 100 _
(M 10)(0.646) + (A. D. D)
O'Oa v
X 100
W (n.iA(0.646) + (ooj,){
This value (IWC) represents the waste concentration to the receiving stream during low flow conditions.
What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I?
,�IPewBIe0 AJ D�tJ-. L .
Plee�ase list the activeingredientsand percent composition:
w.POMI/N2.� al0l dam! _ - �� %
Rio
What feed or dosage rate (D.R.) is used in this application? The units must be converted to maximum grams
of whole product used in a 24hr period.
D.R.= J-6*7 grams124hr period
Please note, fluid ounces (a volume) must be converted to grams (a mass). The formula for this conversion is:
Grams of product = fluid oz. of product X 1 gal. water X 8.34 lbs. X specific gravity of product X 45359g.
128 fl. oz. 1 gal. water 1 lb.

0
w "'
�� •�
Facility Name: NPDES #: NC c e-coal
Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge point.
On an attached sheet please provide justification for this estimate (system volume, average cycles per blowdown,,
holding lagoon size, etc.)
Volume- O AS —million gallons
What is the pH of the handling system prior to biocide addition? If unknown, enter NIA. 9.0
What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.=O) and proceed to asterisk.
The degradation must be stated at pH level within 112 pH standard unit within handling system. Enter the half life
(Half Life is the time required for the initial product to degrade to half of its original concentration). Please provide
copies of the sources of this data.
H.L. _ 0, O'Ya Days
The decay rate is equal to H1L X 0.69 = A0 =Decay Rate (D.K.)
Calculate degradation factor (D.F.). This.is the first order loss coefficient.
d • Oa.Y
• D.F. = A.D.D. + (D.K.) _ + ( ) _ 17.
(Volume)
Calculate Steady State Discharge Concentration: ,
Dischg Conc. =-(D.R.) - 7 ) _ [�. 3V mgll
(D.F.)(Volume)(3785) - (11.y )(v,a.%r)(3785)
Calculate concentration of biocide instream during low flow conditions.
(Receiving Stream Concentration)
(Dischq. Conc.) x (IWC%) _ �_35f) x (_14_1) 0.07 mgll
100 - 100
Receiving Stream Concentration
III. Calculate regulated limitation.
List all LC50 and EC50 data available for the whole product according to the following columns. (Note that units
should be in mg/l). Please provide copies of the sources of this data.
Organism
^
Test Duration
LC501EC50 (moll)
Q/uP2)1/
fv..fis4
96
3,
l� ##;0
j All
D. W. Q. Form 101 (612000) 2

i 00 •�
i
Facility Name:_ _aZ2w _ NPDES * NC rr�
Choose the lowest LC501EC50 listed above:
Enter the LC501EC50: _ 3.
If the half life (H.L.) is less than 4 days, perform the following calculation.
Regulated Limitation = 0.05 x LC50 = ev' /? mgll
If the half life (H.L.) is greater than or equal to 4 days or unknown, perform the following calculation.
Regulated Limitation = 0.01 x LC50 =
mgll
Choose the appropriate regulated limitation from the calculations immediately above and place in this blank:
eq. mg/liter
From Part II enter the receiving stream concentration:
0. Q 71' mg/liter
IV. Analysis.
If the receiving stream concentration is greater than the calculated regulated limitation, then this biocide is
unacceptable for use,
Person in Responsible Charge
Date
Person Completing This Worksheet (If different from above)
w- s �O 5'
Name (Print)
TSignature Date
Please submit to: Division of Water Quality
Aquatic Toxicology Unit
1621 Mail Service Center
Raleigh, NC 27699-1621
Attn: Todd Christenson
D. W. Q. Form 101 (612000) 3

Ashland
DREWBROM•ONE L
MATERIAL SAFETY DATA SHEET
Page 001
Date Prepared: 07/10/03
MSDS NO: 306.0371031-004.003
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Material Identity
Product Name: DREWBROM ONE L
General or Generic ID: MICROBIOCIDE
Company Emergency Telephone Number:
Ashland 1-800-ASHLAND' (1-800-274-5263)
Ashland Distribution Co. & 24 hours everyday
Ashland Specialty Chemical Co.
P. 0. Box 2219 Regulatory Information Number:
Columbus, OH 43216 1-800-325-3751
614-790-3333
2. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient(s) CAS Number % (by weight)
----------------------------------------------------------------------
BROMINE CHLORIDE 11.0
SODIUM HYDROXIDE 1310-73-2 10.0
3. HAZARDS IDENTIFICATION
Potential Health Effects
Eye
Skin
Can cause permanent eye injury. Symptoms include stinging,
tearing, redness, and swelling of eyes. Can injure the cornea and
cause blindness.
Can cause permanent skin damage. Symptoms may include redness,
burning, and swelling of skin, burns, and other skin damage. The
feeling of irritation or pain may not occur until several hours
after the exposure. Additional symptoms of skin contact may
include: hair loss, Passage of this material into the body
through the skin is possible, and,skin contact may be harmful.
Swallowing
Swallowing this material may be harmful or fatal. Symptoms may
include severe stomach and intestinal irritation (nausea,
vomiting, diarrhea), abdominal pain, and vomiting of blood.
Swallowing this material may cause burns and destroy tissue in the

mouth, throat, and digestive tract. Low blood pressure and shock
may occur as a result of severe tissue injury.
Inhalation
Breathing this material may be harmful or fatal. Symptoms may
include severe irritation and burns to the nose, throat, and
respiratory tract. Symptoms usually occur at air concentrations
higher than the recommended exposure limits (See Section 8).
Symptoms of Exposure
Signs and symptoms of exposure to this material through breathing,
swallowing, and/or passage of the material through the skin may
include: irritation (nose, throat, airways), cough, difficult
breathing, lung edema (fluid buildup in the lung tissue), lung
.damage, damage to the mouth, throat, and/or airways, shock.
Target Organ Effects
No data
Developmental Information
Based on the available information, risk to the fetus from
maternal exposure to this material cannot be assessed.
c
Cancer information
There is no information available. The chance of this material
causing cancer is unknown. This material is not listed as a
carcinogen by the International Agency for Research on Cancer, the
National Toxicology Program, or the Occupational Safety and Health
.Administration.
Other Health Effects
No data
Primary Route(s) of Entry
Inhalation, Skin absorption, Skin contact, Eye contact, Ingestion'.
4. FIRST AID MEASURES
Eyes
Skin
If material gets into the eyes, immediately flush eyes gently with
water for at least 15 minutes while holding eyelids apart. If
symptoms develop as a result of vapor exposure, immediately move
individual away from exposure and into fresh air before flushing
as recommended above. Seek immediate medical attention. Do not
remove the victim from water access for transport to a medical
facility unless instructed to do so by qualified medical
personnel. If possible, continue flushing the eye gently with
water while transporting the victim.
Immediately flush skin with water for at least 15 minutes while
removing contaminated clothing and shoes. Seek immediate medical
attention. Wash clothing before reuse and discard contaminated
shoes.

Swallowing
Seek immediate medical attention. Do not induce vomiting.
Vomiting will cause further damage to the mouth and throat. If
individual is conscious and alert, immediately rinse mouth with
water and give milk or water to drink. If possible, do not leave
individual unattended.
Inhalation
If symptoms develop, immediately move individual away from
exposure and into fresh air. Seek immediate medical attention;
keep person warm and quiet. If person is not breathing, begin
artificial respiration. If breathing is difficult, administer
oxygen.
Note to Physicians
Probable mucosal damage may contraindicate the use of gastric
lavage. Preexisting disorders of the following organs (or organ
systems) may be aggravated by exposure to this material:
respiratory tract, skin, lung (for example, asthma -like
conditions).
5. FIRE FIGHTING MEASURES
Flash Point
Not applicable
Explosive Limit•
Not applicable
Autoignition Temperature
No data
Hazardous Products of Combustion
May form: bromine, chlorine compounds.
Fire and Explosion Hazards
No special fire hazards are known to be associated with this
product.
Extinguishing Media
Use an extinguishing media appropriate for surrounding fire.
Fire Fighting Instructions
Wear a self-contained breathing apparatus with a full facepiece
operated in the positive pressure demand mode with appropriate
turn -out gear and chemical resistant personal protective
equipment. Refer to the personal protective equipment section of
this MSDS.
NFPA Rating
Health - 3, Flammability - 0, Reactivity - 0
G. ACCIDENTAL RELEASE MEASURES

Small Spill
Scoop or scrape up: Put in container for recovery or disposal.
Comply with all applicable federal, state, and local regulations.
Large Spill.
Prevent run-off to sewers, streams or other bodies of water. If
run-off occurs, notify proper authorities as required, that a
spill has occurred. Persons not wearing protective equipment
should be excluded from area of spill until clean-up has been
completed. Stop spill at source, dike area of spill to prevent
spreading, pump liquid to salvage tank. Remaining liquid may be
taken up on sand, clay, earth, floor absorbent, or other absorbent
material and shoveled into containers.
7. HANDLING AND STORAGE
Handling
Containers of this material may be hazardous when emptied. Since
emptied containers retain product residues (vapor, liquid, and/or
solid), all hazard precautions given in the data sheet must be
observed. Emergency eyewash fountains and safety showers should
be available in the immediate vicinity of potential exposure. Use
good personal hygiene practices. wash hands before eating,
drinking, smoking, or using toilet facilities. Promptly remove
soiled clothing and wash before reuse. Shower after work using
plenty of soap and water.
Storage
Product solutions are corrosive to many commonly used materials of
construction such as steel, galvanized iron, aluminum, tin and
zinc. These solutions can be stored and handled in baked
phenolic -lined steel, polyethylene, stainless steel, or reinforced
epoxy -plastic equipment. Keep product dry in tightly closed
original container when not in use, Store in a cool, dry,
well -ventilated area away from heat, open flames, organic
chemicals and sunlight. Do not contaminate water, food, or feed
by storage or disposal. Open dumping is prohibited.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye Protection
Chemical splash goggles and face shield (8" min.) in compliance
with.OSHA regulations are advised; however, OSHA regulations also
permit other type safety glasses. (Consult your industrial
hygienist.)
Skin Protection
Wear resistant gloves such as: natural rubber, Wear
chemical -resistant apron, or in emergency conditions,
chemical -resistant clothing and boots.
Respiratory Protections

If workplace exposure limit(s) of product or any component is
exceeded (see exposure guidelines), a NIOSH/MSHA approved air
supplied respirator is advised in absence of proper environmental
control. OSHA regulations also permit other NIOSH/MSHA
respirators (negative pressure type) under specified conditions
(see your industrial hygienist). Engineering or administrative
controls should be implemented to reduce exposure.
Engineering Controls
Provide sufficient mechanical (general and/or local exhaust)
ventilation to maintain exposure below TLV(s).
Exposure Guidelines
Component
BROMINE CHLORIDE
No exposure limits established
SODIUM HYDROXIDE (1310-73-2)
OSHA PEL 2.000 mg/m3 - TWA
OSHA VPEL 2.000 mg/m3•- Ceiling
ACGIH TLV 2.000 mg/m3 - Ceiling
9. PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point
(for product) 214.0 - 216.0 F (101.1 - 102.2 C) ® 760 mmHg
Vapor Pressure
(for product) 19.000 mmHg @ 77.00 F
Specific Vapor Density
No data
Specific Gravity
1.320 - 1.370 Q 77.00 F
Liquid Density
10.900 - 11.400 lbs/gal 0 77.00 F
1.320 - 1.370 kg/1 9 25.00 C
Percent Volatiles
No data
Evaporation Rate
No data
Appearance
CLEAR
State
LIQUID
Physical Form

00
HOMOGENEOUS SOLUTION
Color
YELLOW TO ORANGE
Odor
MILD, SWEAT ODOR
PH
12.4 - 13.7
Freezing Point
21.2 F (-6.0 C)
Solubility in Water
FREELY SOLUBLE IN WATER
10. STABILITY AND REACTIVITY
Hazardous Polymerization
Product will not undergo hazardous polymerization.
Hazardous Decomposition
May form: bromine, chlorine compounds.
Chemical Stability
Stable.
Incompatibility
Avoid contact with: acids, alcohols, aldehydes, aluminum, ammonia
copper, iron, strong reducing agents.
11. TOXICOLOGICAL INFORMATION
LD 50 and LC 50 Data
Oral LD50 (rat): 2491 mg/kg
Dermal LD50 (rat): >2000 mg/kg
Inhalation LC50 (rat, 1 hour): >20.37 mg/1
12. ECOLOGICAL INFORMATION
Ecotoxicological Information'
96 hour LC50 bluegill sunfish (static conditions): 3.8 mg/l
48 hour EC50 Daphnia magna (static conditions): 4.9 mg/l
96 hour IC50 green algae: 2.6 mg/l
13. DISPOSAL CONSIDERATION
Waste Management Information

Improper disposal of excess pesticide, spray mixture, or rinsate
is a violation of Federal Law. If these wastes cannot be disposed
of by use according to label instructions, contact your State
Pesticide or Environmental Control Agency or the Hazardous Waste
Representative at the nearest EPA Regional Office for guidance.
Do not contaminate water, food, or feed, by storage or disposal or
cleaning of equipment. Do not put product, spilled product, or
filled or partially filled containers into the trash or waste
compactor. Contact with incompatible materials could cause a
reaction or fire. Do not reuse container. Rinse thoroughly
before discarding in trash. Triple rinse (or equivalent) then
offer drum for recycling or reconditioning, or puncture. Dispose
of drum in a sanitary landfill, or by incineration, if allowed by
state and local authorities.' If burned, stay out of smoke. For
assistance with your waste management needs - including disposal,
recycling and waste stream reduction, contact Ashland Distribution
Company, IC&S Environmental Services Group at 800-637-7922.
14. TRANSPORT INFORMATION
DOT Information - 49 CFR 172.101
DOT Description:
CORROSIVE LIQUID, BASIC, INORGANIC, N.0.S.,8,UN3266,III
Container/Mode:
55 GAL DRUM/TRUCK PACKAGE
NOS Component:
SODIUM HYDROXIDE
HALOGENATED COMPLEX
RQ (Reportable Quantity) - 49 CFR 172.101
Product•Quantity (lbs) Component
---------------------- ---------- ----------------------------------------
10000 SODIUM HYDROXIDE
Other Transportation Information
The DOT Transport Information may vary with the container and mode
of shipment.
15. REGULATORY INFORMATION
US Federal Regulations
TSCA (Toxic Substances Control Act) Status
TSCA (UNITED STATES) The intentional ingredients of this
product are listed.
CERCLA RQ - 40 CFR 302.4(a)
Component RQ (lbs)
SODIUM HYDROXIDE 1000
CERCLA RQ - 40 CFR 302.4(b)

00
This material has a RQ of 100 lbs as a D002 Corrosive
unlisted hazardous substance.
SARA 302 Components - 40 CFR 355 Appendix A
None
Section 311/312 Hazard Class - 40 CFR 370.2
Immediate(X) Delayed( } Fire( ) Reactive( } Sudden
Release of Pressure( )
SARA 313 Components - 40 CFR 372.65
None
OSHA Process Safety Management 29 CFR 1910
None listed
EPA Accidental Release Prevention 40 CFR 68
None listed
International Regulations
Inventory Status
Not determined
State and Local Regulations
California Proposition 65
None
New Jersey RTK Label Information
SODIUM HYDROXIDE 1310-73-2
Pennsylvania RTK Label Information
SODIUM HYDROXIDE (NA(OH)) 1310-73-2
16. OTHER INFORMATION
It is a violation of federal law to use this product in a manner
inconsistent with its labeling. The information accumulated
herein is believed to be accurate but is not warranted to be
whether originating with the company or not. Recipients are
advised to confirm in advance of need that the information is
current, applicable, and suitable to their circumstances.
Last page

400
BIOCIDE/CHEMICAL TREATMENT
WQRKSHEET-FORM 101
The following calculations are to be performed on any blocidal products ultimately discharged to the surface waters of
North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet is to be
returned with all appropriate data entered into the designated areas with calculations performed as indicated.
Facility Name
NPDES # NC,r=,_n=T Outfall # r
County Fra% Xci" rn
Receiving Stream 33C'4e'4zSlr:j 7Q10 (cfs)
(All above information supplied by the Division of Water Quality)
What is the Average Daily Discharge (A.D.D.) volume of the, water handling systems to the receiving water body?
A.D.D. _ �• �� (in M.G.D.)
Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered
above.
(A.D.D.) X 100
IWC =
(71Q10)(0.646) + (A.D.D)
o. oaY
X 100
(0./31(0.646) + (o.nTY
This value (IWC) represents the waste concentration to the receiving stream during low flow conditions.
What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I?
ffio_ s'ew/s ire 1y 5�
Please list the active ingredients and percent composition:
?2-��'�B,eo�ro -3egeA o r�yL 20 pro
dRoxeO A l b�v.T�t'�G�" /. D %
MGA-)O 949AOo -3— Ae %
2,r2-�,a�aH n �c ��� 440
What feed or dosage rate (D.R.) is used in this application? The units must be converted to maximum grams
of whole product used in a 24hr period.
D.R.= �23 S' _ grams/24hr period
Please note, fluid ounces (a volume) must be converted to grams (a mass). The formula for this conversion is:
Grams of product = fluid oz. of product X 1 gal. water X 8.34 lbs. X specific gravity of product X 45359g.
128 fl. oz. 1 gal. water 1 lb.

Facility Name:-•r�•.z�4 ..�� �[.z — NPDES #: NC��6ra�6s
Estimate totai volume of the water handling system between entry of biocidal product and NPDES discharge point.
On an attached sheet please provide justification for this estimate (system volume, average cycles per blowdown,
holding lagoon size, etc.)
Volume= d r 2Y _ million gallons
What is the pH of the handling system prior to biocide addition? If unknown, enter NIA. �-
What is the decay rate (D.K.) of the product? if unknown, assume no decay (D.K.=O) and proceed to asterisk.
The degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the half life
(Half Life is the time required for the initial product to degrade to half of its original concentration). Please provide
copies of the sources of this data.
H. L. _ l Days
The decay rate is equal to H1L X 0.69 = 419. 3 .=Decay Rate (D.K.)
Calculate degradation factor (D.F.). This is the first order loss coefficient.
O.O a-`f !L
D.F. = (Volume)
' ( + (D.K.) = + ( (49..3
Calculate Steady State Discharge Concentration: A3s
Disch Conc. = (D.R.) _ Q, dS,3 m /l
g (D.F.)(Volume)(3785) - (�y,cj )(p..2y )(3785) = g
Calculate concentration of biocide instream during low flow conditions.
(Receiving Stream Concentration)
Disch . Conc. x IWC% (aa5'3 x { 9• $) _ d , p t mg1l
100 y 100
Receiving Stream Concentration
III. Calculate regulated limitation.
List all LC50 and EC50 data available for the whole product according to the following columns. (Note that units
should be in mg/1). Please provide copies of the sources of this data.
Organism Test Duration LC501EC50 (mall)
&,yoo w 7-e.,"7- q6 S'v
A W. Q. Form 101 (612000) 2

W*
Facility Name:
Choose the lowest LC501EC50 listed above:
Enter the LC50/EC50:
So
10.0
NPDES #: NC is
if the half life (H.L.) is less than 4 days, perform the following calculation.
Regulated Limitation = 0.05 x LC50 = CO. as mg/l
If the half life (H.L.) is greater than or equal to 4 days or unknown, perform the following calculation.
Regulated Limitation = 0.01 x LC50 mg/I
Choose the appropriate regulated limitation from the calculations immediately above and place in this blank:
0 -.2 S' mg/liter
From Part II enter the receiving stream concentration:
O. O / -mg/liter
IV. Analysis.
If the receiving stream concentration is greater than the calculated regulated limitation, then this biocide is
unacceptable for use,
Person in Responsible Charge
am Prin )
Tature Date
V
Person Completing This Worksheet (If different from above)
Name (Print)
e�at"I I'I1,12av
Signature Date
Please submit to: Division of Water Quality
Aquatic Toxicology Unit
1621 Mail Service Center
Raleigh, NC 27699-1621
Attn: Todd Christenson
D. W Q. Form 101 (612000) 3

00
Ashland
BIOSPERSE 244
MATERIAL SAFETY DATA SHEET
Page 001
Date Prepared: 08/18/04
MSDS No: 306,0176184-011.003
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Material Identity
Product Name: BIOSPERSE 244
General or Generic ID: MICROBIOCIDE
Company Emergency Telephone Number:
Ashland 1-800-ASHLAND (1-800-274-5263)
Ashland Distribution Co. & 24 hours everyday
Ashland Specialty Chemical Co.
P. 0. Box 2219 Regulatory Information Number:
Columbus, OH 43216 1-800-325-3751
614-790-3333
2. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient(s) CAS Number % (by weight)
POLYETHYLENE GLYCOL 25322-68-3
TETRAETHYLENE GLYCOL 112-60-7
2,2-DIBROMO-3-NITRILOPROPIONAMIDE 10222-01-2 20.0
SO I BROMIDE 7647-15-6
DIBROMOACETONITRILE 3252-43-5 1.0
MONOBROMO-3-NITRILOPROPIONAMIDE 1113-55-9 1.0
2,2-DIBROMOMALONAMIDE 73003-80-2 1.0
3. HAZARDS IDENTIFICATION
Potential Health Effects
Eye
Skin
Can cause permanent eye injury. Symptoms include stinging,
tearing, redness, and swelling of eyes. Can injure the cornea and
cause blindness.
Can cause skin irritation. Symptoms may include redness and
burning of'skin, and other skin damage. Additional symptoms of
skin contact may include: allergic skin reaction (delayed skin
rash which may be followed by blistering, scaling and other skin
effects), Passage of this material into the body through the skin
is possible, but it is unlikely that this would result in harmful
effects during safe handling and use. .

Swallowing
Swallowing this material may be harmful or fatal. Symptoms may
include severe stomach and intestinal irritation (nausea,
vomiting, diarrhea), abdominal pain, and vomiting of blood.
Swallowing this material may cause burns and destroy tissue in the
mouth, throat, and digestive tract. Low blood pressure and shock
may occur as a result of severe tissue in}ury.
Inhalation
Breathing of vapor or mist is possible. Breathing this material
may be harmful.
Symptoms of Exposure
Signs and symptoms'of exposure to this material through breathing,
swallowing, and/or passage of the material through the skin may
include: irritation (nose, throat, airways).
Target Organ Effects
overexposure to this material (or its components) has been
suggested as a cause of the following effects in laboratory
animals: mild, reversible kidney effects.
Developmental. Information
Based on the available information, risk to the fetus from
maternal exposure to this material cannot be assessed.
cancer Information
This material is not listed as a carcinogen by the International'
Agency for Research on Cancer, the National Toxicology Program, or
the Occupational Safety and Health Administration.
Other Health Effects
No data
Primary Route(s) of Entry
Inhalation, Skin contact, Eye contact, Ingestion -'Industrial
products are not meant to be swallowed.
4. FIRST AID MEASURES
Eyes
Skin
If material gets into the eyes, immediately flush eyes gently with
water for at least 15 minutes while holding eyelids apart. If
symptoms develop as'a result of vapor exposure, immediately move
individual away from exposure and into fresh air before flushing
as recommended above. Seek immediate medical attention.
Remove contaminated clothing. Flush exposed area with large
amounts of water. If skin is damaged, seek immediate medical
attention. If skin is not damaged and symptoms persist, seek
medical attention. Launder clothing before reuse.
Swallowing

Seek medical attention. If individual is drowsy or unconscious,
do not give anything by mouth; place individual on the left side
with the head down. Contact a physician, medical facility, or
poison control center for advice about whether to induce vomiting.
If possible, do not leave individual unattended.
Inhalation
If symptoms develop, immediately move•individual away from
exposure and into fresh air. Seek immediate medical attention;
keep person warm and quiet. If person is not breathing, begin
artificial respiration. If breathing is difficult, administer
oxygen.
Note to Physicians
Probable mucosal damage may contraindicate the use of gastric
lavage. Preexisting disorders of the following organs (or organ
systems) may be aggravated by exposure to this material: skin,
lung (for example, asthma -like conditions), eye.
5. FIRE FIGHTING MEASURES
Flash Point
> 175.0 F (79.4 C) COC
Explosive Limit
(for component) Lower .9
Autoignition Temperature
No data
Hazardous Products of Combustion
May form: bromine, carbon oxides, nitrogen oxides, toxic fumes.
Fire and Explosion Hazards
No special fire hazards are known to be associated with this
product. During a fire, irritating or toxic decomposition
products may be generated.
Extinguishing Media
alcohol foam, water fog, dry chemical.
Fire Fighting Instructions
wear a self-contained breathing apparatus with a full facepiece
operated in the positive pressure demand mode with appropriate
turn -out gear and chemical resistant personal protective
equipment. Refer to the personal protective equipment section of
this MSDS.
NFPA Rating
Health - 3, Flammability - 1, Reactivity - 1
6. ACCIDENTAL RELEASE MEASURES

040
Small Spill
Absorb liquid on vermiculite,
material. Scoop or scrape up
disposal.
floor absorbent or other absorbent
Put in container for recovery or
Large Spill
Persons not wearing protective equipment should be excluded from
area.of spill until clean-up has been completed. Stop spill at
source, dike area of spill to prevent spreading, pump liquid to
salvage tank, Remaining liquid may be taken up on sand, clay,
earth, floor absorbent, or other absorbent material and shoveled
into containers.
7. HANDLING AND STORAGE
Handling
Containers of this material may be hazardous when emptied. Since
emptied containers retain product residues (vapor, liquid, and/or
,solid), all hazard precautions given in the data sheet must be
observed. For optimum product quality, avoid dilution'with water.
Storage
Keep product dry in tightly closed original container when not in
use. Store in a cool, dry, well -ventilated area away from heat,
open flames, organic chemicals and sunlight. Do not contaminate
water, food, or feed by storage or disposal. Open dumping is
prohibited.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye Protection
Chemical splash goggles and face shield (8" min.) in compliance
with OSHA regulations are advised; however, OSHA regulations also
permit other type safety glasses. (Consult your industrial
hygienist.)
Skin Protection
Wear resistant gloves such as: neoprene, To prevent skin contact,
wear impervious clothing and boots. Other protective equipment:
eyewash station, emergency shower.
Respiratory Protections
Exposures in the workplace should be monitored to determine if
worker exposure to vapor or mist air concentrations exceeds the
facility specified exposure "action level" or the use of the
product produces adverse health effects or symptoms of exposure.
Only a NIOSH/MSHA approved respirator and cartridge (TC-23C) is to
be used. Monitoring results must be used to assess the proper
level of respiratory protection necessary (such as: full face
piece respirator with chemical cartridges or self-contained
breathing apparatus {scuba}, etc.). Proper engineering and/or
administrative controls should be used to reduce worker exposure.
The facility's respiratory protection program must meet the

0
.requirements established in 29 CPR 1910.134, which includes a
program for medical evaluation.
Engineering Controls
Provide sufficient mechanical (general and/or local exhaust)
ventilation to maintain exposure below level of overexposure (from
known, suspected or apparent adverse effects).
Exposure Guidelines
Component
POLYETHYLENE GLYCOL (25322-68-3).
No exposure limits established
TETRAETHYLENE GLYCOL (112-60-7)
No exposure limits established
2,2-DIBROMO-3-NITRILOPROPIONAMIDE (10222-01-2)
OTHER LIMIT 2.000 mg/m3 - Ceiling (Recommended)
SODIUM BROMIDE (7647-15-6)
OTHER LIMIT 10.000 mg/m3 - TWA (Recommended)
DIBROMOACETONITRILE (3252-43-5)
OTHER LIMIT 0.100 mg/m3 - Ceiling (Recommended)
MONOBROMO-3-NITRILOPROPIONAMIDE (1113-55-9)
No exposure limits established
2,2-DIBROMOMALONAMIDE (73003-80-2)
No exposure limits established
9. PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point
(for product) a 158.0 P (70.0 C) @ 760 mmHg
Vapor Pressure
(for product) < 10.000 mmHg @ 77.00 F
Specific Vapor bensity
< 1.000 ® AIR=1
Specific Gravity
1.200 - 1.300 @ 73.40 F
Liquid Density
10.400 lbs/gal ® 73.40 F
1.200 - 1.300 kg/1 (P 23.00 C
Percent Volatiles
20.0 - 25.0 %
Volatile Organic Compounds (VOC)

.000 %
Evaporation Rate
SLOWER THAN ETHYL ETHER
Appearance
CLEAR, LIGHT YELLOW TO AMBER LIQD.
State
LIQUID
Physical Form
HOMOGENEOUS SOLUTION
Color
LIGHT YELLOW TO AMBER
Odor
LIGHT, DISINFECTANT
pH
3.4
Freezing Point
-58.0 F (-50.0 C)
Solubility in Water
APPRECIABLE
10. STABILITY AND REACTIVITY
Hazardous Polymerization
Product will not undergo hazardous polymerization.
Hazardous Decomposition
May form: bromine, carbon oxides, cyanogen bromide,
dibromoacetonitrile, nitrogen oxides, toxic fumes.
Chemical Stability
Stable.
Incompatibility
Avoid contact with: strong bases, strong oxidizing agents,
temperatures above 140 degrees F (60 C degrees).
11. TOXICOLOGICAL INFORMATION
LD 50 and LC 50 Data
Oral LD50 (rat): 510 mg/kg
Dermal LD50 (rabbit): >2000 mg/kg
Inhalation LC50 (male rat, 4 hour): 1.4 mg/1
Inhalation LC50 (female rat, 4 hour): 1.25 mg/1

12. ECOLOGICAL INFORMATION
Ecotoxicological Information
This material (or a component) is toxic to fish and aquatic
organisms.
13. DISPOSAL CONSIDERATION
Waste Management Information
Dispose of in accordance with all applicable local, state and
federal regulations. For assistance with your waste management
needs - including disposal, recycling and waste stream reduction,
contact Ashland Distribution Company, IC&S Environmental Services
Group at 800-637-7922.
14. TRANSPORT INFORMATION
DOT Information - 49 CFR 172,101
DOT Description:
NON -REGULATED BY D.O.T.
Container/Mode:
55 GAL DRUM/TRUCK PACKAGE
NOS Component:
Not applicable
RQ (Reportable Quantity) - 49 CFR 172.101
Not applicable
Other Transportation Information
The Transport Information may vary with the container and mode of
shipment.
15. REGULATORY INFORMATION
US Federal Regulations
CERCLA RQ•- 40 CFR 302.4(a)
None
SARA 302 Components - 40 CFR 355 Appendix A
None
Section 311/312 Hazard Class - 40 CFR 370.2
Immediate(X) Delayed( } Fire( ) Reactive( } Sudden
Release of Pressure( )
SARA 313 Components - 40 CFR 372.65
Section 313 Component(s) CAS Number

- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -
2,2-DIBROMO-3-NITRILOPROPIONAMIDE 10222-01-2 20.00
OSHA Process Safety Management 29 CFR 1910
None listed
EPA Accidental Release Prevention 40 CFR 68
None listed
International Regulations
Inventory Status
Not determined
State and Local Regulations
California Proposition 65
None
16. OTHER INFORMATION
The information accumulated herein is believed to be accurate but
is not warranted'to be whether originating with the company or
not. Recipients are advised to confirm in advance of need that the
information is current, applicable, and suitable to their
circumstances.
Last page

BIOCIDE/CHEMICAL TREATMENT
WOF*SHEET-FORM 101
The following calculations are to be performed on any biocidali products ultimately discharged to the surface waters of
North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet is to be
returned with all appropriate data entered into the designated areas with calculations performed as indicated.
Facility Name
NPDES # NC Outfall # I
County
Receiving Stream _—I LS AR�I ft 7Q10 (cfs)
(All above information supplied by the Division of Water Quality)
What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water body?
A.D.D. = CJ• Oay (in M.G.D.)
Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered
above.
IWC = (A.D.D.) X 100
(7Q10)(0.646) + (A.D.D)
m•oaay
( ) X 1.00 �9.8
(a/5g0.646) + ( )
a•v�y
This value (IWC) represents the waste concentration to the receiving stream during low flow conditions.
11. What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I?
Please list the active ingredients and percent composition:
%
�GPy l�2la y �►Q,- 2. z - r z Rio
S&ifvA' , fv/7 AZak
What feed or dosage rate (D.R.) is used in this application? The units must be converted to maximum grams
of whole product used in a 24hr period.
D.R.= ��� grams124hr period
Please note, fluid ounces (a volume) must be converted to grams (a mass). The formula for this conversion is:
Grams of product = fluid oz. of product X 1 gal. water X 8.34 lbs. X specific gravity of product X 453.59g.
128 fl. oz. 1 gal. water 1 lb.

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NPDES #: f
Facility Name.Ege point.
Estimate total volume of the water handling system be entry of biocidal produavera a cycles pd NPDES er b ovvd@W,
E stem volume, 9
On an attached sheet please provide justification for this estimate (system
holding lagoon size, etc.)
Volume= g Z
million gallons
handling system prior to biocide addition? If unknown, enter NIA. r
What is the pH of the 9 Y
What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.=0) and proceed to asterisk.
The degradation must be stated at pH level within 112 pH standard unit within handling system. Enter the half life
(Half Life is the time required for the initial product to degrade to half of its original concentration). Please provide
copies of the sources of this data.
H.L. = 4, Days
The decay rate is equal to H1L X 0.69 = -Decay Rate (D.K.)
Calculate degradation factor (D.F.). This is the first order loss coefficient.
CO. bob- y
• D.F. _ (VoD D. ). + (D.K.) _ (L— + ( O } = O • /
Calculate Steady State Discharge Concentration: x�
Dischg Conc. = D.R. - {�� _) - 3 O mgll
(D.F.)(Volume)(3785) O..tY }(3785) -
Calculate concentration of biocide instream during low flow conditions.
(Receiving Stream Concentration)
Disch . Conc. x IWC% ( 3 0 ) x ( 19 9) _ S. 9�1{ mg/I
100 - 100 -
Receiving Stream Concentration
III. Calculate regulated limitation.
List all LC50 and EC50 data available for the whole product according to the following columns. (Note that units
should be in mgll). Please provide copies of the sources of this data.
Organism
1P*.A.'.&g„e AlOW -
Test Duration
96
9G
v$
LC50/EC50 (mglll
aV
3s Va
D.W.Q.. Form 101 (612000) 2

f 0• so
Facility Name: NPDES #:
Choose the lowest LC501EC50 listed above:
Enter the LC501EC50: _ 689
If the half life (H.L.) is less than 4 days, perform the following calculation.
Regulated Limitation = 0.05 x LC50 = mg/i
If the half life (H.L.) is greater than or equal to 4 days or unknown, perform the following calculation.
Regulated Limitation = 0.01 x LC50
Choose the appropriate regulated limitation from the calculations immediately above and place in this blank:
�- SO? _ _ mg/liter
From Part II enter the receiving stream concentration:
S- 95( _mglliter
IV. Analysis.
If the receiving stream concentration is greater than the calculated regulated limitation, then this biocide is
unacceptable for use,
Person in Responsible Charge
Na rint) '
S' a ure Date
Person Completing 15is Worksheet (if different from above)
24-wel et/ 5 C%S
Name (Print)
G✓ / y .20d
Signature Date
Please submit to: Division of Water Quality
Aquatic Toxicology Unit
1621 Mail Service Center
Raleigh, NC 27699-1621
Attn: Todd Christenson
D. W Q. Form 101 (612000) 3

ASHLAND SPECIALTY CHEMICAL
DREW BUSINESS GROUPS
PRODUCT NAME: DIOLTECHO 424 A COOLING WATER TREATMENT
Aquatic Toxicity (Static Acute Tests)
96 Hour LC50 Rainbow Trout: 689 mg/L
(Confidence Limits 95%: 564-843 mg/L Test date 1/07/97)
96 Hour LC50 Fathead Minnow: 804 mg/L
(Confidence Limits 95%: 648-996 mg/L Test date 1/27/97)
96 Hour EC50 Fathead Minnow: 700 mg/L
(Confidence Limits 95%: 565-867 mg/L Test date 1/27/97)
48 Hour LC50 Daphnia Magna: 3540 mg/L
(Confidence Limits 95%: 2500-5000 mg/L Test date 1/13/97)
SOD5: 290,000 mg/L Test date 12/18/96
COD: 313,000 mg/L Test date 12/18/96
aR gwcred trademark of Ashland lac
pdF 5 ltech424p Dcc6
Dcc FS37
page l of 1
Environmental, Health A Safety Department
Product & Regulmory Information. Dram- Team -
All statements, information and data presetted herein are believed to be accurate and reliable but are not to be taken as a guarantee. express warranty or implied warranty of
merrhamability or fitness for a p iculm purpose, or representation, express or implied, far which seller assumes legal responsibility, and they are offered solely for your
consideration, inv�yligadan and verification. This information is believed no be accurate and reliable as of dam shove. It is recommended you make your own determination on the
suitability of ihis product fory+our particular application.

BIOCIDEICHEMICAL TREATMENT
WORKSHEET-FORM 101
The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of
North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet is to be
returned with all appropriate data entered into the designated areas with calculations performed as indicated.
Facility Name
NPDES # NC If 4r Outfall #_ t
County rar-k=:.�_
Receiving Stream Z j:' ' 1 n ir-'= EC - __ 7Q10 m' (cfs)
(All above information supplied by the Division of Water Quality)
What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water body?
A.D.D. _ d7. O (in M.G.D.)
Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using.the data entered
above.
A.D.D. X 100
IWC = (7Q10)(0.646) + (A.D.D)
_ ( ) X 100 _
(0./,f O.646) + (�• ct�.y
/9 %
This value (IWC) represents the waste concentration to the receiving stream during low flow conditions.
What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I?
4940w C/i /yr
Please list the active ingredients and percent composition:
�� vim GILLLD/iT�rr �`" YO %
What feed or dosage rate (D.R.) is used in this application? The units must be converted to maximum grams
of whole product used in a 24hr period.
D.R.= -may- J/ grams/24hr period
Please note, fluid ounces (a volume) must be converted to grams (a mass). The formula for this conversion is:
Grams of product = fluid oz. of product X 1 Qal. water X 8.34 lbs. X specific gravity of product X 453.594.
128 fl. oz. 1 gal. water 1 lb.

Facility Name: NPDES #:
Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge point.
On an attached sheet please provide justification for this estimate (system volume, average cycles per blowdown,
holding lagoon size, etc.)
Volume= d• / :�L million gallons
What is the pH of the handling system prior to biocide addition? If unknown, enter NIA. /, o
What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.=O) and proceed to asterisk.
The degradation must be stated at pH level within 112 pH standard unit within handling system. Enter the half life
(Half Life is the time required for the initial product to degrade to half of its original concentration). Please provide
copies of the sources of this data.
H.L. = m- lira: Days
The decay rate is equal to H1L X 0.69 'fr" =Decay Rate (D.K.)
Calculate degradation factor (D.F.). This is the first order loss coefficient.
D.F. = A.D.D. + (D.K.) _ �--� +
(Volume)
Calculate Steady State Discharge Concentration:
(D.R. )D+ 00-5-m Il
Dischg Conc. _ (D.F.)(Volume)(3785) _ Ao, )( 0, �)(3785) = g
Calculate concentration of biocide instream during low flow conditions.
(Receiving Stream Concentration)
(Dischg. Conc.) x(IWC%) _ �_ ?_X (19 00099 mg/I
100 - 100
Receiving Stream Concentration
III. Calculate regulated limitation.
List all LC50 and EC50 data available for the whole product according to the following columns. (Note that units
should be in mgll). Please provide copies of the sources of this data.
Organism Test Duration LC501EC50 lmq/0
D ,o�G,�•,� 9.(0 0,29
SAM 9!;// 96 Z
IL?A.Oyho . -//ya r _ 9G z9d
D. W.Q. Form 101 (612000) 2

P 3 ,. - ".Y _ `S
r .
•

Facility Name: NPDES #: NC pry
Choose the lowest LC501EC50 listed above:
Enter the LC501EC50: _ 6V ,.29—
If the half life' (H.L.) is less than 4 days, perform the following calculation.
Regulated Limitation = 0.05 x LC50 = V. 0!,< mgll
If the half life (H.L.) is greater than or equal to 4 days or unknown, perform the following calculation.
Regulated Limitation = 0.01 x LC50 = mg/l
Choose the appropriate regulated limitation from the calculations immediately above and place in this blank:
(V- 4 !� mg/liter
From Part II enter the receiving stream concentration:
Q. 0 00 ?9-mg/liter
IV. Analysis.
If the receiving stream concentration is greater than the calculated regulated limitation, then this biocide is
unacceptable for use.
Person in Responsible Charge
n ..emu I pP l /�—
Nfame -
Sign re Date
Person Completing This Worksheet (If different from above)
All s-alos
Name (Print)
!Ls aea �
Signature Date
Please submit to: Division of Water Quality
Aquatic 'Toxicology Unit
1621 Mail Service Center
Raleigh, NC 27699-1621
Atfn: Todd Christenson
D. W. Q. Form 101 (612000) 3

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DREW INDUSTRIAL DIVISION
OXIDATIVE CHEMICALS
DREWCHLORe 4107 Chlorine Dioxide Precursor
Environmental Profile
General
DREWCHLOR 4107 precursor Is a stabilized, non-volatile,
chlorite formulation specifically designed for use with the
patented CENEROXr"' unit for on -site generation of chlorine
dioxide. Chlorine dioxide has numerous industrial and
municipal applications as a disinfectant and as a chemical
oxidant. Chlorine dioxide is stable and highly active over a
wide pH range, will not react. with ammonia nitrogen
compounds, eliminates taste and odor -causing by-product's
such as chlorophenols and will cause a minimum of
corrosion of system metals at use dosages. This
Environmental Profile is designed to address common.
questions about the impact of DREWCHLOR 4107 chlorine
dioxide precursor on the environment.
Active Ingredients
Sodium Chlorite 25-40%
CAS #7758-19-2
Sodium Chloride 1-10%
CAS #7647-14-5
EPA Registration Number 1757-96.
Toxicity Studies
Animal Toxicology
Inhalation LCSo: No available data
Dermal LD58: >2g/kg (rabbit)'
Oral LD59: Approximately 350 mg/kg (rat)
Irritation Severe irritant with corrosive action
to skin (of rabbit)
Severe irritant to eyes (of rabbit)
Aquatic Toxicity
Sluegill LC50: 265-31 mg/i
Rainbow trout LC56: 290 mg/1
Daphnia LC50: 0.29 mg/l
Disassociation/Degradation Data
Sodium chlorite is utilized to produce chlorine dioxide. The
disassociation scheme for chlorine dioxide is chlorite and
chlorate ions. Ultimately, the chlorite and chlorate ion will
degrade to chloride and oxygen.
Spill Procedure
In case of small spills, absorb liquid on vermiculite, floor
absorbent or other absorbent material. Flush area with water
when absorbent material is cleaned up. In the event of large
spills, all persons not wearing protective equipment should
be excluded from the area of the spill. Stop the spill at its
source and dike to prevent spreading, Pump liquid to a
salvage tank and take up remaining liquid on sand, clay,
earth floor absorbent or other absorbent material. Shovel
material into containers and Flush area with water.
Do not use sawdust, cat litter (except clay) or other organic
based absorbents.
Dispose of all waste material as directed by local, state and
federal regulations.
Handling Precautions
DREWCHLOR 4107 chlorine dioxide precursor is a severe
eye and skin irritant. If DREWCHLOR 4107 precursor
contacts the eyes or skin, the affected areas must be flushed
with large amounts of water. See the MSDS for additional
information.
Important Information
This Environmental Profile is designed to address common
questions about the impact ofDREWCHLOR 4107precursor on
the environment andisnot a substitutefar the product'sMaterial
Safety Data Sheet
Ashland maintains Material Safety Data Sheets on all of its
products: Material Safety Data Sheets contain health and safety
information for your development of appropriate product
handling procedures to protect your employees and customers
Our Material Safety Data Sheets should be read and understood
by all ofyour supervisory personnel and employees before using
Ashland products in your facilities
OD Registered trademark and TM trademark ofAshlartd Inc.
'Registered service mark of the American Chemistry Council.
01994, 20DI Ashland Inc. All Rights Reserved. Created to U.S.A. • OX-EP-003 Rev. 2
All statements, information and data presented heroin are believed to be accurate and reliable but are not to be taken as a guarantee, express warrantyor
wetrkwhot ial
implied warranty of merchantability or fitness for a particular purpose, or representation, express or implied, for which seller assumes legal responsibility, and
ppb�
they are offered soiely for your consideration, inyselgatlon and verification. Statements or suggestions concerning possible use of this product are made
without representaeon or warranty that any such use Is free of patent Infringement and are not recommendations to infringe on any patent
�*
A5M8Ade
For more information on Ashland Specialty Chemical Company and its divisions, visit our Internet web site at ht1p:1 wmv.eshspec.com
qqmmmw
DREW INDUSTRIAL DIVISION • One Drew Plaza, Boonton, New Jersey 07005 • Tel: [phone] • Fax: [phone]
Ashland 5paciatty chemical Company
� ' ommon ofAstYard Inc

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Date: October 31, 2017
Novozymes, NA Inc.
77 Perry's Chapel Church Rd.
Franklinton, N.C. 27525
NCDEQ Division Of Water Quality
1617 Mail Service Center Raleigh, N.C. 27699-1617
Attn: Division Of Water Quality
Storm Water Sampling, NPDES Permit No. NCS000115
Dear Sir/Madam,
novozymes•
Rethink Tomorrow
RECIV
NOV
CENTRAL FILES
oWR SECTION
During review of storm water sampling results, it was observed that there was an exceeded benchmark in
Biological Oxygen Demand (BOD) from our Outfall 2 location.
Upon immediate investigation, per Tier One requirements, it was discovered that although during sample
event no signs of potential issues were present, the area approximately 20 yards from where samples are
collected the combination of filtration systems not properly being maintained/serviced and the off-loading of
raw materials are being considered direct causes of the recent exceeding of BOD. Plans are in place to have
personnel in area begin with cleaning filtration systems and more caution taken place while material is being
handled.
Continued monitoring by Environmental Services Department will take place in order to prevent future
exceeded benchmarks in Biological Oxygen Demand (BOD) from Outfall 2.
Kind Regar ,
Joe Ladd
Environmental Compliance Coordinator
Environmental Services

EFFLUENT
NPDES PERMIT NO. NCS000115 DISCHARGE NO. 1
FACILITY NAME Novozymes, NA Inc. CLASS
OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA
CERTIFIED LABORATORIES (1) Enco (2)
CHECK BOX IF ORC HAS CHANGED E:=Fl PERSON(S) COLLECTING SAMPLES
Mail ORIGINAL and ONE COPY to:
MONTH October YEAR 2017
COUNTY: Franklin
PHONE _L919) 494-3001
Joe Ladd
ATTN: CENTRAL FILES x NIA
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
1617 MAIL SERVICE CENTER
RALEIGH, NC 27699-1617
BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY
KNOWLEDGE.
Lm����mm�
.
DWQ Form MR-1 (I 1/04)

r
Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
(including weekly averages, if applicable)
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially
threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the
permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the
permittee becomes aware of the circumstances.
If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for
improvements to be made as required by Part II.E.6 of the NPDES permit.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly
responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Pennittee Address
Certified Laboratory (2)
Certified Laboratory (3)
Certified Laboratory (4)
Certified Laboratory (5)
Randy Green
Permittee (Please print or type) _
Signature inn' *** Date
(Required unless kul5mitted electronically)
Phone Number e-mail address Permit Expiration Date
ADDITIONAL CERTIFIED LABORATORIES
PARAMETER CODES
Certification No.
Certification No.
Certification No.
Certification No.
Parameter Code assistance may be obtained by calling the NPDES Unit at [phone] or by visiting the Surface
Water Protection Section's web site at h2o.enr.state.nc.us/was and linking to the unit's information pages.
Use only units of measurement designated in the reporting facility's NPDES permit for reporting data.
* No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be
entered for all of the parameters on the DMR for the entire monitoring period.
** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204.
*'* Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on
file with the state per 15A NCAC 2B .0506(b)(2)(D).
Page 2

EFFLUENT
NPDES PERMIT NO. NCS000115 DISCHARGE NO. 2
FACILITY NAME NoVozymes, NA Inc. CLASS
OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA
CERTIFIED LABORATORIES (1) Enco (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES
Mail ORIGINAL and ONE COPY to:
MONTH October YEAR 2017
COUNTY: Franklin
PHONE [phone]
Joe Ladd
ATTN: CENTRAL FILES x NIA
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
1617 MAIL SERVICE CENTER BY THIS SIGNATURE. I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY
RALEIGH, NC 27699-1617 KNOWLEDGE.
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DWQ Form MR-1 (I 1/04)

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
(including weekly averages, if applicable)
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially
threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the
permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the
permittee becomes aware of the circumstances.
If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for
improvements to be made as required by Part II.E.6 of the NPDES permit.
"I certity, under penalty of law, that this document and all attachments were prepared under my direction or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly
responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Permittee Address
Certified Laboratory (2)
Randy Green
Permittee (Please prko or -type)
Signature of ermittee*** Date
(Require nless submitted electronically)
Phone Number a -mail address Permit Expiration Date
ADDITIONAL CERTIFIED LABORATORIES
Certification No.
Certified Laboratory (3)
Certification No.
Certified Laboratory (4)
Certification No.
Certified Laboratory (5)
Certification No.
PARAMETER CODES
Parameter Code assistance may be obtained by calling the NPDES Unit at [phone] or by visiting the Surface
Water Protection Section's web site at h2o.ennstate.nc.us/was and linking to the unit's information pages.
Use only units of measurement designated in the reporting facility's NPDES permit for reporting data.
No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be
entered for all of the parameters on the DMR for the entire monitoring period.
'* ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 80.0204,
'Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on
file with the state per 15A NCAC 2B .0506(b)(2)(D).
Page 2

T
COEN
0
L�bor��ories
Accurate Trmely. Responsive. Innovative.
102-A woodwinds Industrial court
Cary NC, 27511
Phone: [phone] FAX: [phone]
Thursday, October 26, 2017
Novozymes North America (NO008)
Attn: Joe Ladd
77 Perry Chapel Church Road
Franklinton, NC 27525
RE: Laboratory Results for
Project Number: [none], Project Name/Desc: Stormwater Testing
ENCO Workorder(s): CA01243
Dear Joe Ladd,
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Tuesday, October 17, 2017.
Unless otherwise noted in an attached project narrative, all samples were received in
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are in compliance with NELAC standards, except
as noted in the project narrative. This report shall not be reproduced except in full, without
the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
Chuck Smith
Project Manager
Enclosure(s)
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in fill. Pape 1 of 10

www.encolobs.com
SAMPLE SUMMARY/LABORATORY CHRONICLE
Client ID: OutfallI
Lab ID: CA01243-01
Sampled:
10/16/17 13:00
Received: 10/17/17 08:05
PaElMgt
EPA 351.2
Hold Date/TFmefsl
11/13/17
Prep Date/Tlmefsl
10/20/17'
14:35
Analvals
10/23/17
DatalTime/sl
09:23
EPA 353.2
10/18117
13:00
10/17/17
15:12
10/17/17
15:12
EPA 353.2
11/13117
10/17/17
13:32
10/17/17
1132
EPA 353.2
07/11120
10/18/17
11:02
10/18/17
14:59
EPA 365.4
11/13117
10/20/17
14:35
10/23/17
11:03
SM 254OD-1997
10/23117
10/23/17
18:35
10/23/17
18:35
SM 521OB-2001
10/18,117
13:00
10/17/17
17:13
10/17/17
17:13
SM 522OD-1997
11/13117
10/19/17
18:02
10/20/17
11:00
Client ID: Outfall2
Lab ID: CA01243-02
Sampled:
10/16/17 12:30
Received: 10/17/17 08:05
ate
EPA 351.2
Hold oatelllmefsl
11/13117
Prep Date/Timefsl
10/20/27
14:35
Analysis
10/23/17
Date/Time(s)
09:28
EPA 353.2
10/18117
12:30
10/17/17
15:17
10/17/17
15:17
EPA 353.2
11/13117
10/17/17
13:37
10/17/17
13:37
EPA 353.2
07/11120
10/18/17
11:02
10/18/17
14:59
EPA 365.4
11/13117
10/20/17
14:35
10/23/17
11:08
SM 254OD-1997
10/23117
10/23/17
18:35
10/23/17
18:35
SM 521OB-2001
10/18117
12:30
10/17/17
17:13
10/17/17
17:13
SM 5220D-1997
11/13117
10/19/17
18:02
10/20/17
11:00
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 2 of 10

www.encolabs.com
SAMPLE DETECTION SUMMARY
Client ID: Outfall 1
Lab ID:
CA01243-01
Anal
Results
EU9
Hu
Ea
llnitg
Method tYotes
Biochemical Oxygen Demand
5.0
2.0
2,0
mg/L
SM 521OD-2001
Chemical Oxygen Demand
27
10
10
mg/L
SM 5220D-1997
Nitrate as N
0.088
1
0.025
0,10
mg/L
EPA 353,2
NitrateAtrite as N
0.088
1
O.D41
0.10
mg/L
EPA 353.2
Phosphorus
0.41
0.025
0.10
mg/L
EPA 365.4
Total Kjeldahl Nitrogen
1.1
0.26
0.48
mg/L
EPA 351.2
Total Suspended Solids
32
6.7
6.7
mg/L
SM 254OD-1997
Client ID: Outfall 2
Lab ID:
CA01243-02
Analyze
Results
flag
MRL
Ea
Mau
Method 1i4ku
Biochemical Oxygen Demand
49
2.0
2.0
mg/L
SM 521OB-2001
Chemical Oxygen Demand
96
10
10
mg/L
SM 5220D-1997
Nitrate as N
0.78
0.025
0.10
mg/L
EPA 353.2
Nitrate/Nitrite as N
0181
0,041
0.10
mg/L
EPA 353.2
Nitrite as N
0.029
1
0.017
0.10
mg/L
EPA 353.2
Phosphorus
0.36
0.D25
0.10
mg/L
EPA 365,4
Total Kjeldahl Nitrogen
2.0
0.26
0,48
mg/L
EPA 351.2
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in lull. Page 3 of LO

www.encolabs.com
ANALYTICAL RESULTS
Descrlption: Outfall 1 Lab Sample ID: CA01243-01 Received; 10/17/17 08:05
Matrix: Surface Water Sampled:10/16/17 13:00 Work Order: CA01243
Project: Stormwater Testing Sampled By. -Joe Ladd
LClassical Chemistry Parameters
^ - EACO Cary certl8ed o-lyte (ABC 5911
Analvte rCAS Numberl Results
Elm
Mau
QE MU pa
A=
Math
Analvzed
By ly4ies
Biochemical Oxygen Demand^
S.0
mg/L
1 2.0 2.0
7117040
SM 52108-2001
10/17/17 17:13
JOC
Chemical Oxygen Demand^
27
mg/L
1 10 10
7J19032
SM 5224D-1997
10/20/17 11:00
JOC
Nitrate as N [14797-SS-8]A
0.088
J
mg/L
1 0,025 0.10
7J18024
EPA 353.2
10/18/17 14:59
Jul
Nitrate/Nitrite as NA
0.098
J
mg/L
1 0.041 0110
7317026
EPA 353.2
10/17/17 13:32
JLJ
Nitrite as N [14797-65-0]^
0,017
U
mg/L
1 0.017 0.10
7317033
EPA 353.2
10/17/17 15:12
JLJ
Phosphorus 17723-14-0]A
0.41
mg/L
1 0.025 0.10
7320011
EPA 365.4
10/23/17 11:03
JLJ
Total Kjeldahl Nitrogen^
1.1
mg/L
1 0.26 0.48
7320010
EPA 351.2
10/23/17 09:23
JLJ
Total Suspended Solids^
32
mg/L
2.67 6.7 6.7
7323030
SM 254OD-1997
10/23/17 18:35
OMR
Description. Outfall 2
Lab Sample ID. CAO 1243-02
Received: 10/17/17 08:05
Matrix. Surface Water
Sampled: 10116117 12:30
Work Order: CA01243
Project: StormwaterTesting
Sampled By,Joe Ladd
Chemistry Parameters
Analvte rCAS Numberl
Results
an unjts
of
Hu
j4L
@7Mh
Method
Analyzed
am Hato
Biochemical Oxygen Demand^
49
mg/L
1
2.0
2.0
7117040
SM 521OB-2001
10/17/17 17:13
JOC
Chemical Oxygen Demand'
96
mg/L
1
10
10
7319032
SM 5220D-1997
10/20/17 11:00
30C
Nitrate as N [14797-55-e]A
0.78
mg/L
1
0.025
0.10
7J18024
EPA 353.2
10/18/17 14:59
JLJ
Nitrate/Nitrite as NA
0.81
mg/L
1
0.041
0.10
7317026
EPA 353,2
10/17/17 13:37
JLJ
Nitrite as N [14797-65-0]A
0.029
J mg/L
1
0.017
0.10
7117033
EPA 353.2
10/17/17 15:17
IL1
Phosphorus [7723-14-Or
0.36
mg/L
1
0.025
0.10
7120011
EPA 365.4
10/23/17 11:08
IL1
Total IQeldahl Nitrogen^
2.0
mg/L
1
0.26
0.48
7120010
EPA 351.2
10/23/17 09:28
31-7
Total Suspended Sollds^
25
U mg/L
10
25
25
7323030
SM 254OD-1997
10/23/17 18:35
OMR
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 10

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batd17J17026 - NO PREP
Blank (7317026-BLK1) Prepared: 10/17/2017 13:28 Analyzed: 10/17/2017 13:28
Spike Source %REC RPD
_AnaResult Flail PQL Units Level Result %REC Limits RPD Limit Notes
Nitrate/Nitrite as N 0.041 U 0.10 m91L
LCS (7317026-BSL) Prepared: 10/17/2017 13:30 Analyzed: 10/17/2017 13:30
Spike Source %REC
RPD
Anal
Result
Fail
POL
units
Level Result a/oREC Limps RPD
Limit Notes_
Nitrate/Nitrite as N
1.2
0.10
mg/L
1.25 98 90-110
Matrix Spike (7317026-MS3)
Prepared: 10/17/2017 13:33 Analyzed: 10/17/2017 13:33
Source: CA01243-01
Spike Source %REC
RPD
Anal
Result
ELM
POL
Unitx
Level Result a/aREC LIMIts RPD
Limit Notes
Nitrate/Nitrite as N
0.59
0.10
mg/L
0.521 0.088 96 90-110
Matrix Spike (7317025-MS2)
Prepared: 10/17/2017 13:39 Analyzed: 10/17/2017 13:39
Source: CA01243-02
Spike Source a/oREC
RPD
Anallda
Resui!
ELIQ
POL
U11Its
Level Re6LR %REC Limits RPD
Limp Notes
Nitrate/Nitrite as N
1.3
0.10
mg/L
0.521 0.81 100 90.110
Matrix Spike Dup (7317026-MSD3)
Prepared: 10/17/2017 13:35 Analyzed: 10/17/2017 13:35
Source: CA01243-01
Spike Source R/aREC
RPD
Anahctll
Result
Elan
Pall.
units
Level Result 0/oREC Limits RPD
Limp lY4teS
Nitrate/Nitrite as N
0.60
0.10
mg/L
0.521 0.088 99 90-110 3
10
Be[dl 7JI7033 - NO PREP
Blank (7317033-BLKI) Prepared: 10/17/2017 15:11 Analyzed: 10/17/2017 15:11
Spike Source %REC RPD
AnalYte Resit Elaa PQL Units Level Result %REC Llmlts RPD Limit Notes
Nitrite as N 0.017 U 0.10 mg/L
LCS (7317033-BSI) Prepared: 10/17/2017 15:03 Analyzed: 10/17/2017 15:03
Spike Source 9/oREC
RPD
Anal
Result Elan
ML
Units
Level Result %REC Llmlts RPD
Limit Notes
Nitrite as N
0.99
0.10
mg/L
1.00 99 90-110
Matrix Spike (7317033-MSI)
Prepared: 10/17/2017 15:13 Analyzed: 10/17/2017 15:13
Source: CA01243-01
Spike Source a/oREC
RPD
Ana 4rt9
Result Flag
WL
Units
Level Resul! a/oREC Limits RPD
Ulmlt dotes_
Nitrite as N
0.99
0.10
mg/L
1.00 0.017 U 99 90-110
Matrix Spike (7317033-MS2)
Prepared: 10/17/2017 15:18 Analyzed: 10/17/2017 15:18
Source: CA01243-02
Spike Source %REC
RPD
Anal
Result Flail
POL
Units
Level Be5Llt a/aREC Limits RPD
Limp Notes
Nitrite as N
1.0
0.10
mg/L
1.00 0.029 99 90-110
Matrix Spike Dup (7317033-MSDI)
Prepared: 10/17/2017 15:14 Analyzed: 10/17/2017 15:14
Source: CA01243-01
Spike Source %REC
RPD
.Armll(t®
Result Baa
POL
units
Level Result %REC Limits RPD
Limit dotes
FINAL This report relates only to
the sample as
received by the laboratory, and may only be reproduced in full.
Page 5 of 10

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 7JI7033 - NO PREP - Condnued
Matrix Spike Dup (7317033-MSD3) Continued
Prepared: 10/17/2017 15:14 Analyzed: 10/17/2017 15:14
Source: CA01243-01
Spike Source %REC
RPD
Anal 1[te
Result
Flag
P41
Lnit9
Level Result %REC Limlti RPD
Limit Notes
Nitrite as N
0.97
0.10
mg/L
1.00 0.017 U 97 90-110 2
10
Batch 7JI7014O - NO PREP
Blank (7317040-BLKi)
Prepared & Analyzed: 10/17/2017 17:13
Spike Source a/aREC
RPD
Ana
RffLwt
Hd4
M
Sln1Li
Level ( %REC Limits RPD
Limit Notes
Biochemical Oxygen Demand
2.0
U
2.0
mg/L
LCS (7317040-BSI)
Prepared IN Analyzed: 10/17/2017 17:13
Spike Source %REC
RPD
Anal
Result
Elan
PQL
Un(t9
Level Result %REC Limits RPD
Limit hotel
Biochemical Oxygen Demand
170
2.0
mg/L
198 88 85-115
Duplicate (7317040-DUP3)
Prepared & Analyzed: 10/17/2017 17:13
Source: CA13061-02
Spike Source °/oREC
RPD
Ana hds
Result
Else
PQL
Un[tl
Level Result %REC Limits RPD
Limit Notes
Biochemical Oxygen Demand
8.9
2.0
mg/L
9.1 3
30
Batch 7a19032 - Same
Blank (7319032-BLKi)
Prepared: 10/19/2017 18:02 Analyzed: 10/20/2017 11:00
Spike Source %REC
RPD
_Ananda
RCsul
FIN
Pal.
Unit4
Level Result %REC Limits RPD
Limit Notes
Chemical Oxygen Demand
10
U
10
mg/L
LCS (7319032-BS3)
Prepared: 10/19/2017 18:02 Analyzed: 10/20/2017 11:00
Spike Source a/oREC
RPD
9ml]de
Result
am
ROL
Units
Level Result %REC Nm]tg RPD
Limit Notes
Chemical Oxygen Demand
500
10
mg/L
500 101 90-110
Matrix Spike (7319032-MS1)
Prepared: 10/19/2017 18:02 Analyzed: 10/20/2017 11:00
Source: CA01243-01
Spike Source %REC
RPD
Anal
Result
Elan
EOL
1lnits
Level Result %REC Llmitfi RPD
Limit Notes
Chemical Oxygen Demand
560
10
mg/L
526 27 101 • 90.110
Matrix Spike Dup (7319032-MSDI)
Prepared: 10/19/2017 18:02 Analyzed: 10/20/2017 11:00
Source: CA01243-01
Spike Source °/oREC
RPD
Ana lsda
Result
"M
ROL
Unlls
Level Result %REC Limits RPD
Limit r!letes
Chemical Oxygen Demand
570
10
mg/L
526 27 102 90-110 0.8
10
Batch 712OO1O - Same
Blank (7220010-BLK1)
Prepared: 10/20/2017 14:35 Analyzed: 10/23/2017 09:19
Spike Source a/oREC
RPD
Ana
Result
Elan
PQL
Liam
Level Result %REC Lim[ tg RPD
Limit Notes
Total Kjeldahl Nitrogen
0.26
U
0.48
mg/L
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 6 at 10

www.encolabs.com
QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 7J20010 - Same - Continued
LCS (7320030-BSI) Prepared: 10/20/2017 14:35 Analyzed: 10/23/2017 09:21
Spike Source %REC
RPD
9nande
Result
Flag
POL
units
Level Result %REC Limits RPD
Limit Notes
Total Kjeldahl Nitrogen
12
0,48
mg/L
11.9 104 90-110
Matrix Spike (7320010-MS3)
Prepared: 10/20/2017 14:35 Analyzed: 10/23/2017 09:24
Source,CA01243-01
Spike Source %REC
RPD
Ana
Result
Flag
POL
Unita
Level Result %REC Limits RPD
Li01it Notes
Total Kjeldahl Nitrogen
5.8
0.48
mg/L
4.75 1.1 100 90-110
Matrix Spike (7320010-MS2)
Prepared: 10/20/2017 14:35 Analyzed: 10/23/2017 09:29
Source: CA01243-02
Spike Source 0/aREC
RPD
_Anah ttC
Result
Hag
M
llnits
Level Result %REC Limits RPD
Limit Notes
Total Kjeldahl Nitrogen
6.7
0.48
mg/L
4.75 2.0 98 90-110
Matrix Spike Dup (7320010-MSDL)
Prepared: 10/20/2017 14:35 Analyzed: 10/23/2017 09:26
Source: CA01243-01
Spike Source %REC
RPD
_Anahft
Result
Hag
P_41
units
Level Resul} %REC Limits RPD
Limit Notes
Total Kjeldahl Nitrogen
6.0
0.48
mg/L
4.75 1.1 103 90-110 3
10
Batch 7J20011 - Same
Blank (7320011-BLKI) Prepared: 10/20/2017 14:35 Analyzed: 10/23/2017 11 A 1
Spike Source %REC RPD
Ana lYtg Result Hag PQL Unm Level Result %REC Llmitp RPD Limit Notes
Phosphorus 0.025 U 0.10 mg/L
LCS (7320011-BS1) Prepared: 10/20/2017 14:35 Analyzed: 10/23/2017 11:02
Spike
Source
%REC
RPD
Anatift Result
Hag PQL
Units
Level
Result
%REC
Limits RPD
Limit Notes
Phosphorus 1.6
0.10
mg/L
1.60
100
80-120
Matrix Spike (7320011-MSi)
Prepared: 10/20/2017 14:35 Analyzed: 10/23/2017 11:05
Source,CA01243-01
Spike
Source
%REC
RPD
Anal YtA Result
Hag PQL
Units
Level
Result
%REC
Limitre RPD
Limit Notes
Phosphorus 1.1
0.10
mg/L
0.640
0.41
103
80.120
Matrix Spike Dup (7320011-MSD1)
Prepared: 10/20/2017 14:35 Analyzed: 10/23/2017 11:06
Source: CA01243-01
Spike
Source
%REC
RPD
Ana hds Result
Hag P91
Units
Level
Res,llt
%REC
Limb RPD
Limit Notes
Phosphorus 1.1
0.10
mg/L
0.640
0.41
104
80-120 0.3
25
Batch 7J23030 - NO PREP
Blank (7323030-BLKL) Prepared & Analyzed: 10/23/2017 18:35
Spike Source %REC RPD
Anahf17H Result Elm PAL units Level Result %REC Limits RPD Limit Motes
Total Suspended Solids 2.5 U 2.5 mg/L
FINAL This report relates only to the sample as recelved by the laboratory, and may only he reproduced In full. Pape 7 of 10

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 7J23030 - NO PREP - Condnued
LCS (7323030-BSI) Prepared & Analyzed: 10/23/2017 18:35
Spike Source %REC
RPD
Ana
Result Elm
P01.
Units
Level Result %REC Limits
RPD
Lim(t Notes
Total Suspended Solids
90
2.5
mg/L
100 90 80-120
Duplicate (7323030-DUPI)
Prepared & Analyzed: 10/23/2017 18:35
Source: CAL3516-01
Spike Source %REC
RPD
Ana
Result Flag
PM
Units
Level 1 asult %REC Limits
RPD
MMIA i'iPW
Total Suspended Solids
490
50
mg/L
630
26
20 QM-12
Duplicate (7323030-DUP2)
Prepared & Analyzed: 10/23/2017 18:35
Source: CA13516-03
Spike Source %REC
RPD
Anal lde
Result Elan
PQL
Units
Level Result %REC Limits
RPD
Limit Notes
Total Suspended Solids
440
50
mg/L
S00
12
20
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 8 of 10

www.encolabs.com
FLAGS/NOTES AND DEFINITIONS
B The analyte was detected in the associated method blank,
D The sample was analyzed at dilution,
J The reported value is between the laboratory method detection limit (MIL) and the laboratory method
reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable.
U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
E The concentration indicated for this analyte is an estimated value above the calibration range of the
instrument. This value is considered an estimate.
MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution
factor, and, in the case of soil samples, moisture content.
PQL PQL: Practical Quantitation Limit.
N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater
confidence) to make a "tentative identification".
P Greater than 25% concentration difference was observed between the primary and secondary GC column.
The lower concentration is reported.
QM-12 Precision between duplicate samples was outside acceptance limits.
FINAL This report relates only to the sample as recetved by the laboratory, and may only be reproduced in full. Pape 9 of 10

'ENVIRONMENTAL CONSERVATION LABORATORIES CHAIN -OF -CUSTODY RECORD www.encolabs.com
_ 10775 CenNal Fbn Dr. 48141=.rr,.l m Park Corot, SLd* III 102-A Woodwktds Industrial 1--L
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Work Order:
CA01243
Project:
St �mwater Testing
Client:
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Project M
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Page 1 of 1

77
Date: June 9, 2017
Novozymes, NA Inc.
77 Perry's Chapel Church Rd.
Franklinton, N.C. 27525
NCDENR Division Of Water Quality
1617 Mail Service Center Raleigh, N.C. 27699-1617
Attn: Division Of Water Quality
Storm Water Sampling, NPDES Permit No. NCS000115
Dear Sir/Madam
novozymes•
Rethink Tomorrow
Per our Tier Two requirements, regarding the exceeded benchmark in Biological Oxygen Demand, (BOD)
and Chemical Oxygen Demand, (COD), our implementation of a monthly monitoring in area of concern,
"Outfall 2", beginning in March has resulted in three consecutive sample results that are within required
benchmark range.
Test results from May mark the third consecutive month that our SOD and COD readings have been within
benchmark range. With May's testing complete, and compliance established, this will conclude our monthly
monitoring for BOD and COD.
We will continue our second of two required Storm Water sampling events prior to the end of the calendar
year.
Kind Re s,
Joe Ladd '
Environmental Compliance Coordinator
Environmental Services

EFFLUENT
NPDES PERMIT NO. NCS000115 DISCHARGE NO. 2
FACILITY NAME Novozymes, NA Inc. CLASS
OPERATOR IN RESPONSIBLE CHARGE (ORC) N/A
CERTIFIED LABORATORIES (1) Enco (2)
CHECK BOX IF ORC HAS CHANGED C==Fl PERSON(S) COLLECTING SAMPLES
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES x NIA
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY
RALEIGH, INC 27699-1617 KNOWLEDGE.
MONTH May YEAR 2017
COUNTY: Franklin
PHONE i919) 494-3001
Joe Ladd
Lill
DWQ Form MR -I (11/04)

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
(including weekly averages, if applicable)
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially
threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the
permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the
permittee becomes aware of the circumstances.
If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for
improvements to be made as required by Part II.E.6 of the NPDES permit.
-I certity, under penalty of taw, that this document and all attachments were prepared under my direction or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly
responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Randy Green
Permittee (Please print or type)
4 W V�
re of P ittee*** Date
(Required u e s submitted electronically)
Permittee Address Phone Number e-mail address Permit Expiration Date
Certified Laboratory (2)
Certified Laboratory (3)
Certified Laboratory (4)
Certified Laboratory (5)
ADDITIONAL CERTIFIED LABORATORIES
PARAMETER CODES .
Certification No.
Certification No.
Certification No.
Certification No,
Parameter Code assistance may be obtained by calling the NPDES Unit at [phone] or by visiting the Surface
Water Protection Section's web site at h2o.enr.state.nc.us/was and linking to the unit's information pages.
Use only units of measurement designated in the reporting facility's NPDES permit for reporting data.
* No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be
entered for all of the parameters on the DMR for the entire monitoring period.
** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204.
*** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on
file with the state per 15A NCAC 2B .0506(b)(2)(D).
Page 2

JX CO Laboratories
Accurate. Timely. Responsive. Innovative.
102-A Woodwinds Industrial Court
Cary NC, 27511
Phone: [phone] FAX: [phone]
Monday, June 5, 2017
Novozymes North America (NO008)
Attn: Joe Ladd
77 Perry Chapel Church Road
i=ranklinton, NC 27525
RE: Laboratory Results for
Project Number: [none], Project Name/Desc: Stormwater CA
ENCO Workorder(s): CZ19514
Dear Joe Ladd,
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Wednesday, May 24, 2017.
Unless otherwise noted in an attached project narrative, all samples were received in
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are in compliance with NELAC standards, except
as noted in the project narrative. This report shall not be reproduced except in full, without
the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
Chuck Smith
Project Manager
Enclosure(s)
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 1 of 7

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SAMPLE SUMMARY/ LABORATORY CHRONICLE
Client In, Outfall2 Lab ID: a19514-01 Sampled: 05/23/17 14:30 Received: 05/24/17 08:07
Parameter Hold DatelTimefsl Prep Date/Tlmefsl Analysis Date/11me(s)
SM 5210B-2001 05/25/17 14:30 05/24/17 13:18 05/24/17 1118
SM 5220D-1997 06/20/17 05/26/17 12:59 05/26/17 17:05
FINAL This report relates only to the sample as recehied by the laboratory, and may only be reproduced In fufl. Pape 2 of 7

www.encGlabs.com
SAMPLE DETECTION SUMMARY
Client ID: Outtall 2 Lab ID: CZ19514-01
BnalM Res" fin Hu E" lWSa Methad KQ=
Biochemical Oxygen Demand 5.4 2.0 2.0 mg/L SM 521OB-2001
Chemical Oxygen Demand 58 10 10 mg/L 5M 5220D-1997
FINAL This report relates only to trm sample as reoeKed by the laboraoory, and may only be reproduced In full. Faye 3 of 7

www.encolabs.com
ANALYTICAL RESULTS
Description: Outfall 2 Lab Sample ID: CZ19514-01 Received: 05/24/17 08:07
Matrix: Surface Water Sampled:05/23/17 14:30 Work Order: CZ19514
Project: Storrnwater CA Sampled By:Joe Ladd
Classical Chemistry Parameters
- L%W Cary C"*d cmlNft PC 5911
Analvte rCAS Number] R9sul an Units pf M" p" lagh lei Analyzed NoUs
Biochemical Oxygen Demand^ 5.4 rng/L 1 2.0 2.0 7E24020 SM 521OB-2001 05/24/17 13:18 30C
Chemical Oxygen Demand^ 58 mglL 1 10 10 7E26013 SM 5220D-1997 05/26/17 I.T05 30C
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 4 of 7

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 7E24020 - NO PREP
Blank (7E24020-BLK3) Prepared & Analyzed: 05/24/2017 13:18
Spike Source %REC RPD
Ana hds Result Else ML units Level Result %REC Limits RPD Limit Notes
Biochemical Oxygen Demand 2.0 U 2.0 mg/L
LCS (7E24020-OSI) Prepared & Analyzed: 05/24/2017 13:18
Spike Source %REC
RPD
Anah[t0
Result Elm PAL
!!nits
Level Resul( %REC Limits RPD
Limit Notes -
Biochemical Oxygen Demand
180 2.0
mg/L
198 91 85-115
Duplicate (7E24020-DUP1)
Prepared & Analyzed: 05/24/2017 13:18
Source: CA00231-01
Spike Source %REC
RPD
AnBhdA
Result Flan POL
Units
level Result %REC Limits RPD
Limit Notes
Biochemical Oxygen Demand
180 2.0
mg/L
I70 1
30
Batcyi 7E260.13 - Same
Blank (7E26013-BLK3) Prepared: 05/26/2017 12:59 Analyzed: 05/26/2017 17:05
Spike Source %REC RPD
Analvts Result Elea PQL flnita Level Besult %REC Limb RPD Limit Well
Chemical Oxygen Demand 10 U 10 mg/L
LCS (7E26013-BS1) Prepared: 05/26/2017 12:59 Analyzed: 05/26/2017 17:05
Spike
Source
%PEC
RPD
Anal lda Result
Has EGL
units
Level
Result
%REC
Limits RPD
Limit Notes
Chemical Oxygen Demand 500
10
mg/L
500
101
90-110
Matrix Spike (7E260i3-MSi)
Prepared: 05/26/2017 12:59 Analyzed: 05/26/2017 17:05
Source. CA00213-01
Spike
. Source
%REC
RPD
Ann hds Resul
Has ROL
units
Level
Result
%REC
Limits RPD
Limit Notes
Chemical Oxygen Demand 2700
40
mg/L
2000
670
101
90-110
Matrix Spike Dup (7E26013-MSDI)
Prepared: 05/26/2017 12:59 Analyzed: 05/26/2017 17:05
Source:CA00213-01
Spike
Source
%REC
RPD
Anal lde REsul
Has P01
llnb
Level
Result
%REC
Limits RPD
limit liter
Chemical Oxygen Demand 2700
40
mg/L
2000
670
103
90-110 2
10
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full, Page 5 of 7

www.encolobs.com
FLAGS/NOTES AND DEFINITIONS
8 The analyte was detected in the associated method blank.
D The sample was analyzed at dilution.
] The reported value is between the laboratory method detection limit (MDL) and the laboratory method
reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable.
U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
E The concentration indicated for this analyte is an estimated value above the calibration range of the
instrument. This value is considered an estimate.
MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution
factor, and, in the case of soil samples, moisture content.
N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater
confidence) to make a "tentative identification".
Greater than 25% concentration difference was observed between the primary and secondary GC column.
The lower concentration is reported.
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 6 of 7

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Sample Preservation Verification
ENCO Cary
Work Order:
CZ19514
Project:
Stormwater CA
Client:
Novorymes North America (N0008)
Project M
[none]
Logged In:
24-May-17 09:38
Logged By:
John C King
CZ19314-01
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Page 1 c

Date: May 4, 2017
Novozymes, NA Inc.
77 Perry's Chapel Church Rd.
Franklinton, N.C. 27525
NC DEQ Division Of Water Quality
1617 Mail Service Center Raleigh, N.C. 27699-1617
Attn: Division Of Water Quality
Storm Water Sampling, NPDES Permit No. NCS000115
Dear Sir/Madam
novozymese
Rethink Tomorrow
ft
RECEIVED
MAY 19 2017
owkF
Per our Tier Two requirements, regarding the exceeded benchmark in Chemical Oxygen Demand, (COD)
and Biological Oxygen Demand (BOD), our implementation of monthly monitoring in area of concern,
"Outfall 2", beginning in January has resulted in the second of three being within required benchmark range
during April event.
Test results from April mark the second consecutive month that our BOD and COD readings have been
within benchmark range. With April's testing complete, we will collect samples again from Outfall 2 for
BOD and COD only until three consecutive sample results are within required benchmark range.
We will continue our second of two required Storm Water sampling events prior to the end of the calendar
year.
Kind
Joe Ladd
Environmental Complia
Environmental Services
Coordinator

EFFLUENT
NPDES PERMIT NO. NCS000115 DISCHARGE NO.
FACILITY NAME NOVOZyme5, NA Inc. CLASS
OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA
CERTIFIED LABORATORIES (1) Enco
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES
Mail ORIGINAL and ONE COPY to:
2 MONTH April YEAR
(2)
Jae Ladd
COUNTY: Franklin
PHONE i9191494-3001
ATTN: CENTRAL FILES x NIA
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY
RALEIGH, NC 27699-1617 KNOWLEDGE.
2017
DWQ Farm MR-1 (11/04)

0 EJVCO Laboratories
Accurate. Timely. Responsive. Innovative.
102-A Woodwinds Industrial Court
Cary NC, 27511
Phone: [phone] FAX: [phone]
Tuesday, May 2, 2017
Novozymes North America (NO008)
Attn: Joe Ladd
77 Perry Chapel Church Road
Franklinton, NC 27525
RE: Laboratory Results for
Project Number: [none], Project Name/Desc: Stormwater CA
ENCO Workorder(s): CZ19516
Dear Joe Ladd,
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Monday, April 24, 2017.
Unless otherwise noted in an attached project narrative, all samples were received in
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are In compliance with NELAC standards, except
as noted in the project narrative. This report shall not be reproduced except in full, without
the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
Chuck Smith
Project Manager
Enclosure(s)
FINAL This report mates only to the sample as received by the laboratory, and may only be reproduced !n full. Page t of 7

www.encolabs.com
SAMPLE SUMMARY/LABORATORY CHRONICLE
CllentID: OWN12 Lab ID: CZ1951e-Ol Sampled: 04/23/17 15:00 Received: 04/24/17 08;00
Parameter Hold Date/Timefsl Prep Date/Time(a) Analysls Date/Time(s)
5M 52108-2001 04/25/17 15:00 04/25/17 14:06 04/25/17 14:06
SM 5220D-1997 05/21/17 04/27/17 18:24 04/28/17 10:37
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 2 of 7

SAMPLE DETECTION SUMMARY
I Client ID: Outfall 2 Lab ID: CZ19516-01
Biochemical Oxygen Demand
Chemical Oxygen Demand
3.3 2.0 2.0 mg/L
28 10 10 mg/L
www.encolabs.com
SM 521OB-2001
SM 522OD-1997
FINAL Thfs report relates only to the sample as reoelved by the laboratory, and may only be reproduced In full. Pape 3 of 7

www.encolabs.corn
ANALYTICAL RESULTS
Description: Outfall 2 Lab Sample ID:CZ19516-01 Received: 04/24/17 08:00
Matrix: Surface Water Sampled:04/23/17 15:00 Work Order: CZ19516
project: Storrnwater CA Sampled By:Joe Ladd
Classical Chemistry Parameters
^ - EAM Cary CerVAed enalyte PVC 691)
Analvbe rCAS Numberl Results fin Unih PE HU 1'9.6 Adds 1Method Analyzed By Notes
Biochemical Oxygen Demand^ 3.3 mg/L 1 2.0 2.0 71325023 SM 52108-2001 04/25/17 14:06 30C
Chemical Oxygen Demand^ 28 mg/L 1 10 10 7D27049 SM 5220D-1997 04/28/17 10:37 30C
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 4 of 7

Ce ML9
www.encolabs.com
QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batt* 7D25O23 - NO PREP
Blank (7DZ5023-BLK3)
Prepared 8: Analyzed: 04/25/2017 14:06
Spike Source %REC
RFD
Anal
Resul
ElaO
PDL
Ulnits
Level Result %REC Lets RPD
LID1lt Notes
Biochemical Oxygen Demand
2.0
U
2.0
mg/L
B-03
LCS (7D25023-BSI)
Prepared 8. Analyzed: 04/25/2017 14:06
Spike Source %REC
RPD
Auanda
Result
Has
PQL
units
Level Resin %REC Limits RPD
LLD11t Notes
BiochemicalOxygen Demand
200
2.0
mg/L
198 100 85-115
Duplicate (7025023-DUPl)
Prepared 8. Analyzed: 04/25/2017 14:06
Source: CZ19516-01
Spike Source %REC
RPD
Anal
Result
Elm
PQL
Ulnlffi
Level B28ult %REC Limb RPD
Limit Notes
Biochemical Oxygen Demand
3.1
2.0
mg/L
3.3 5
30
Bak* 7027O49 - Some
Blank (7D27049-BLKI)
Prepared: 04/27/2017 18:24 Analyzed: D4/28/2017 10:37
Spike Source %REC
RPD
Ana bds
Result
Hag
MIL
IInEtB
Level Reslilt %REC LIMI i RPD
Limit Notes
Chemical Oxygen Demand
10
U
10
mg/L
LCS (7D27049-BSI)
Prepared: 04/27/2017 18:24 Analyzed: 04/28/2017 10:37
Spike Source %REC
RPD
.AnandO
Result
Flan
P41
llnits
Level Result %REC L(n RPD
Limit Notes
Chemical Oxygen Demand
500
10
mg/L
500 100 90-110
Matrix Spike (7D27049-MSI)
Prepared: 04/27/2017 18:24 Analyzed: 04/28/2017 10:37
Source:CA00065-01
Spike Source 9/oREC
RPD
Anal YD9
Result
Hall
POL
Mnits
Level Resul a/aREC Limb RPD
Limit Notes
Chemical Oxygen Demand
560
10
mg/L
526 43 98 90-110
Matrix Spike Dup (7D27049-MSD1)
Prepared: 04/27/2017 18:24 Analyzed: 04/28/2017 10:37
Source:CA000SS-01
Ana4tte
Chemical Oxygen Demand
Spike Source %REC
Result Elan PQL !!nits Level Result %REC Limits RPD
570 10 mg/L 526 43 100 90-110 2
RPD
Limit !hates
10
FINAL This report relates only to the sample as receKed by the laboratory, and may only be reproduced In full. Pape 5 of 7

E�69
www.encolobs.com
FLAGS/NOTES AND DEFINITION5
B The analyte was detected in the associated method blank.
D The sample was analyzed at dilution.
3 The reported value is between the laboratory method detection limit (MDL) and the laboratory method
reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable.
U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
E The concentration indicated for this analyte is an estimated value above the calibration range of the
instrument. This value is considered an estimate.
MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution
factor, and, in the case of soil samples, moisture content.
N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater
confidence) to make a "tentative identification".
P Greater than 25% concentration difference was observed between the primary and secondary GC column.
The lower concentration is reported.
B-03 Blank exceeds the method required oxygen depletion of <0.20 mg/L.
FINAL This report relates only to the sample as recehed by the laboratory, and may only be reproduced In full. Page 6 of 7

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Sample Preservation Verification
•ENCO Cary
Work Order. CZ19516 Project: Stormwater CA
Client: Novozyme& North America (N0008) Project #: [none]
Logged In: 24-Apr-17 08:19 Logged By: John C King
CZ19616-M _
Conk Ty
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Reacient Name ID
1
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3
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5
61
Page 1 c

Date: March 28, 2017
Novozymes, NA Inc.
77 Perry's Chapel Church Rd.
Franklinton, N.C. 27525
NC DEQ Division Of Water Quality
1617 Mail Service Center Raleigh, N.C. 27699-1617
Attn: Division Of Water Quality
FEE I V E D
APR 2 0 2017
CENTRAL FILES
DWR SECTION
Storm Water Sampling, NPDES Permit No. NCS000115
Dear Sir/Madam
novozymesm
Rethink Tomorrow
Per our Tier Two requirements, regarding the exceeded benchmark in Chemical Oxygen Demand, (COD)
and Biological Oxygen Demand (HOD), our implementation of monthly monitoring in area of concern,
"Outfall 2", beginning in January has resulted in the first of three being within required benchmark range.
Test results from March mark the first month that our BOD and COD readings have been within benchmark
range. With March's testing complete, along with other required parameters tested, we will collect samples
again from Outfall 2 for HOD and COD only until three consecutive sample results are within required
benchmark range.
We will continue our second of two required Storm Water sampling events prior to the end of the calendar
year.
Kind Reg
Joe Ladd
Environmental Compliance Coordinator
Environmental Services

EFFLUENT
NPDES PERMIT NO. NCS000115 DISCHARGE NO.
FACILITY NAME Novozymes, NA Inc. CLASS
OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA
CERTIFIED LABORATORIES (1) Enco
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES
Mail ORIGINAL and ONE COPY to:
MONTH March YEAR
Joe Ladd
COUNTY: Franklin
PHONE [phone]
A I I N: CENTRAL FILES x NIA
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY
RALEIGH, NC 27699-1617 KNOWLEDGE,
2017
DWQ Form MR-1 (11/04)

EFFLUENT
NPDES PERMIT NO, NCS000115 DISCHARGE NO. 2
FACILITY NAME Novozymes, NA Inc. CLASS
OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA
CERTIFIED LABORATORIES (1) Enco (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES : MA
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY
RALEIGH, NC 27699-1617 KNOWLEDGE.
MONTH March YEAR 2017
COUNTY: Franklin
PHONE [phone]
Joe Ladd
�.
DWQ Form MR-1 (11/04)

0 CO Laboratories
Accurate. Timely. Responsive. Innovative.
102-A Woodwinds Industrial Court
Cary NC, 27511
Phone: [phone] FAX: [phone]
Friday, March 24, 2017
Novozymes North America (NO008)
Attn: Joe Ladd
77 Perry Chapel Church Road
Franklinton, NC 27525
RE: Laboratory Results for
Project Number: [none], Project Name/Desc: Stormwater Testing
ENCO Workorder(s): CZ19517
Dear Joe Ladd,
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Wednesday, March 15, 2017.
Unless otherwise noted in an attached project narrative, all samples were received in
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are in compliance with NELAC standards,, except
as noted in the project narrative. This report shall not be reproduced except in full, without
the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
Chuck Smith
Project Manager
Enclosure(s)
FINAL This report relates aNy to the sample as rem+oed by the laboratory, and may only be reproduced 0 ful. Pape 1 of 10

www.encolabs.com
SAMPLE SUMMARY/ LABORATORY CHRONICLE
Client ID: Outfall 1
Lab ID: CZ19517-01
Sampled: 03/24/17 11:00 Recelved: 03/15/17 08:00
Parametg
EPA 351.2
Hold Date/Tlmefsli
04/11/17
Prep DatelTimefsl
03/16/17
Analysis Date/Tlmefsl
11:55 03/20/17 10:24
EPA 353.2
03/16/17 11:00
03/15/17
13:01 03/15/17 13:01
EPA 353.2
04/11/17
03/21/17
12:11 03/21/17 12:11
EPA 353.2
12/08/19
03/22/17
11:28 03/22/17 12:19
EPA 365.4
D4/11/17
03/16/17
11:55 03/20/17 11:21
SM 254OD-1997
03/21/17
03/20/17
09:40 03/20/17 09:40
SM 52108-2001
03/16/17 11:00
03/15/17
1327 03/15/17 1127
SM 5220D-1997
04/11/17
03/20/17
14:21 03/20/17 18:08
Client ID: Outfall2
Lab ID: CZ19517-02
Sampled: 03/14/17 10:00 Received: 03/15/17 OB:00
umme
EPA 351.2
Hold Date/31mefsl
04/11/17
Prep Datefflmg{;]
03/16/17
11:55 03/20/17 10:26
EPA 353.2
03/16/17 10:00
03/15/17
13:D2 03/15/17 13:02
EPA 353.2
04/11/17
03/21/17
13:28 03/21/17 13:28
EPA 353.2
12/08/19
03/22/17
11:28 03/22/17 12:19
EPA 365.4
04/11/17
03/16/17
11:55 03/20/17 11:22
SM 254OD-1997 03/21/17
SM 521OB-2001 03/16/17 10:00
SM 522OD-1997 04/11/17
03/20/17 09:40 03/20/17 09:40
03/15/17 13:27 03/15/17 1127
03/20/17 14:21 03/20/17 18:08
FINAL This report relates only to the sample as received by the laboratory, and may only ba reproduced In full. Pape 2 of 10

www.encolobs.com
SAMPLE DETECTION SUMMARY
Client ID: Out/all 1
Lab ID:
Cz195I7-01
Anal1te
sllte
Aas Hu
EQL
ft=
Biochemical Oxygen Demand
2.9
2.0
2.0
mg/L
SM 521OB-2001
Chemical Oxygen Demand
30
10
10
mg/L
SM 5220D-1997
Nitrate as N
1.1
0.025
0.10
mg/L
EPA 353.2
Nitrate/Nitrite as N
1.1
0.041
0.10
mg/L
EPA 353.2
Nitrite as N
0.017
1 0.017
0.10
mg/L
EPA 353.2
Phosphorus
0,21
0.025
0.10
mg/L
EPA 365.4
Total Kjeldahl Nitrogen
0.97
0.26
0.48
mg/L
EPA 351.2
Total Suspended Solids
11
3.3
3.3
mg/L
5M 254OD•1997
Client M. Outrall 2
Lab ID:
CZ19517-02
Biochemical Oxygen Demand
13
2.0
2.0
mg/L
SM 521OB-2001
Chemical Oxygen Demand
41
10
10
mg/L
SM 522OD-1997
Nitrate as N
0.16
0.025
0.10
mg/L
EPA 353.2
Nitrate/Nitrite as N
0.16
0.041
0.10
mg/L
EPA 353.2
Total Kjeldahl Nitrogen
0.60
0.26
0.48
mg/L
EPA 351.2
FINAL This report relates only to the sample as recehred by Me laboratory, and may only be reproduced In full. Pape 3 of 10

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ANALYTICAL RESULTS
Description: Outfa[I 1 Lab Sample ID: CZ19517-01 Received: 03/15/17 08:00
Matrix: Surface Water Sampled:03/14/17 11:00 Work Order: CZ19517
Project, Stormwater Testing Sampled By:Joe Ladd
Classical Chemistry Parameters
^ - SWO Cory c"Oed lmelyra (MC 591]
Anafvte XAS Numberl Results
rig ynb
jf M[, EQL
j=
Method
Ana
11121211111
Biochemical Oxygen Demand^
2.9
mg/L
1 2.0 2.0
7C15009
SM 5210B-2001
03/15/17 13:27
JOC
Chemical Oxygen Demand
30
mg/L
1 10 10
7C20018
SM 5220D-1997
03/20/17 18:08
JOC
Nitrate as N [34797-55-8]^
1.1
mg/L
1 0.025 0.10
7C22020
EPA 353.2
03/22/17 12:19
JU
Nitrate/Nittite as N^
1.1
mg/L
1 0.041 0.10
7C21003
EPA 353.2
03/21/17 12:11
ILI
Nitrite as N [14797-65-0]A
0.017
J mg/L
1 0.017 0.10
7C15020
EPA 353.2
03/15/17 13:01
ILI
Phosphorus [7723-14-0]^
0.21
mg/L
1 0.025 0.10
7C16006
EPA 365.4
03/20/17 11:21
3L3
Total Kjeldahl Nlbogen^
0.97
mg/L
1 0.26 0.48
7C16005
EPA 351.2
03/20/17 10:24
313
Total Suspended Solids^
11
mg/L
1.33 3.3 3.3
7C20002
SM 254OD-1997
03/20/17 09:40
014R
Description: Outfali 2
Lab Sample ID: CZ19517-02
Received: 03/15/17 08:00
Matrix: Surface Water
Sampled:03/14/17
10:00
Work Order: CZ19517
Project* 5tonwater Testing
Sampled By:Joe Ladd
lClassical Chemistry Parameters
^ - SACO Ciry errd&!d anMty [NC 59t1
i;Cdulti
Elm
Unb
RE
MU
P4L
ARM
Method
Auahlsed
!£IL 11211111
Biochemical Oxygen Demand^
13
mg/L
1
2.0
2.0
705009
SM 521OB-2001
03/15/17 13:27
JOC
Chemical Oxygen Demand"
41
mg/L
1
10
10
7C20018
SM 5220D-1997
03/20/17 18:08
30C
Nitrate as N [34797-55-8]^
0.16
mg/L
1
0.025
0.10
7C22020
EPA 353.2
03/22/17 12:19
JU
Nitrate/Nitrite as NA
0.16
mg/L
1
0.041
0.10
7C21004
EPA 353.2
03/21/17 13:28
JU
Nitrite as N [14797-65-0]^
0.017
U
mg/L
1
-0,017
0.10
7C15020
EPA 353.2
03/15/17 13:02
JU
Phosphorus[7723-14-0]^
0.025
U
mg/L
1
0.025
0.10
7C16006
EPA 365.4
03/20/17 I.L22
JLl
Total Vjeldahl Nitrogen^
0.60
mg/L
1
0.26
0.48
7C16005
EPA 351.2
03/20/17 10:26
JU
Total Suspended Solids^
2.S
U
mg/L
1
2.5
2.5
7C20002
SM 254OD-1997
03/20/17 09:40
OMR
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 4 of 10

www.encolobs.com
QUALITY CONTROL DATA
Classlcal Chemistry Parameters - Quality Control
Batch 7CI5009 - NO PREP
Blank (7C15009-81.91)
Prepared & Analyzed: 03/15/2017 13:27
Spike Source %REC
RPD
Ana hde
Result
Elan
INIX
UnIl
Level Rat %REC Limits RPD
Limit Notn
Biochemical Oxygen Demand
2.0
U
2.0
mg/L
B-03
LCS (7C15009-051)
Prepared & Analyzed: 03/15/2017 13:27
Spike Source %REC
RPO
Ana llde
Reed
Elan
PQL
uAlu
Leval Resin %REC Limits RPD
Limit Notes
Biochemical Oxygen Demand
170
2.0
mg/L
198 85 85-115
Duplicate (7C35009-DUPI)
Prepared IN Analyzed: 03/15/2017 13:27
Source: CZ1676a-01
Spike Source %REC
RPD
Ana hrte
Result
an
PQL
llnitt
Level Resul %REC Limits RPD
Limit Notes
Biochemical Oxygen Demand
6.3
2.0
mg/L
6.4 2
30
Duplicate (7C15009-DU112)
Prepared & Analyzed: 03/15/2017 13:27
Source: a16769-02
Spike Source %REC
RPD
Ana lYte
Resin
Elao
P.QL
units
Level Result %REC Limits RPD
Limit Notes
Biochemical Oxygen Demand
11
2.0
mg/L
11 DA
30
Betdr 7CI5020 - NO PREP
Blank (7C35020-BLK1)
Prepared; 03/15/2017 12:48 Analyzed: 03/15/2017 12:48
Spike Source %REC
RPD
Ana hde
Result
HZI
EQL
units
Level Result %REC Limits RPD
Limit �igypg
Nitrite as N
0.017
U
0.10
mg/L
LCS (7C25020-BS1)
Prepared: 03/15/2017 1 2: 39 Analyzed: 03/15/2017 12:39
Spike Source %REC
RPD
AOaI]da
Result
an
P41
Units
Level Rat %REC Limits RPD
Limit Notes
Nitrite as N
0.96
0.10
mg/t
1.00 96 9D-110
Matrix Spike (7C15020-MS1)
Prepared: 03/15/2017 12:49 Analyzed: 03/15/2017 12:49
Source: CA03754-01
Spike Source %REC
RPD
Anal
Result
flea
PM
Uzi=
Level Rejul %REC Limits RPD
Limit Notes
Nitrite as N
0.93
0.10
mg/L
1.00 0.017 U 93 90.110
Matrix Spike Dup (7C15020-MSD1)
Prepared: 03/15/2017 12:52 Analyzed: 03/15/2017 12:52
Source:CA03754-01
Spike Source %REC
RPD
Ana lYte
Result
Elan
RQL
Units
Level Result %REC Limits RPD
Limit Not"
Nitrite as N
0.92
0.10
mg/L
1.00 0,017 U 92 90-110 2
10
Betdi 7CI6005 - Same
Blank (7C36005-BLK3)
Prepared: 03/16/2017 11:55 Analyzed: 03/20/2017 0926
Spike Source %REC
RPD
Ana 4rte
Result
Haa
EM
Lifi to
Level Riesutt %REC Limits RPD
Limit Notes
Total Kjeldahl Nitrogen
0.26
U
0.48
mg/L
FINAL This report relates only to the sample as received by the laboratory, and may only to reproduced In full. Page 5 of 10

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 7CI6005 - same - Continued
LCS (7C16005-BS1)
Prepared: 03/16/2017 11:55 Analyzed: 03/20/2017 09:28
Spike Source %REC
RPD
Ana 4ltp
Result
an
F9L
units
Level Ulm, t %REC Limits RPD
Limit Nefts
Total Kjeldahl Nitrogen
12
0.48
mg/L
11.9 101 90-110
Matrix Spike (7C16005-MSi)
Prepared: 03/16/2017 11:55 Analyzed: 03/20/2017 09:30
Source: CA01544-02
Spike Source %REC
RPD
-Anandn
Result
Elm
PQL
Units
Level Result %REC limits RPD
Limit Not"_
Total Kjeldahl Nitrogen
8.4
0.48
mg/L
4.75 3.5 103 90-110
Matrix Spike (7C16005-MS2)
Prepared: 03/16/2017 1I:55 Analyzed: 03/20/2017 09:39
SourcesCAD1310-01
Spike Source %REC
RPD
Ana lldo
Result
RM
PQL
ti0lts
Level Result %REC Nmlts RPO
Llmlt Notes
Total Kjeldahl Nitrogen
31
D
0,96
mg/L
435 28 65 90-110
QM-07
Matrix Spike Dup (7C16005-MSDi)
Prepared: 03/16/2017 11:55 Analyzed: 03/20/2017 09:35
Source: CA01644-02
Spike Source %REC
RPD
Ana htte
Result
Elm
ML
Unia
Level Result %REC Limb RPD
Limit Notes -
Total Kjeldahl Nitrogen
8.2
0.48
mg/L
4.75 3,5 98 90-110 3
10
Batch 7117-16006 - same
Blank (7C36006-BLK1)
Prepared: 03/16/2017 11:55 Analyzed: 03/20/2017 10:59
Spike Source %REC
RPD
Ana hde
Reach
Elan
PQL
!knits
Level BeSult %REC Limits RPD
Limit Notes
Phosphorus
0.025
U
0.10
mg/L
LCS (7C16006-051)
Prepared: 03/16/2017 11:55 Analyzed: 03/20/2017 11:01
Spike Source %REC
RPD
Ana hds
Result
Flag
PQL
!units
Level Result %REC Limits RPO
limit Jyotn
Phosphorus
1.6
0.10
mg/L
1.60 100 80-120
Matrix Spike (7C16006-MS1)
Prepared: 03/16/2017 11:55 Analyzed: 03/20/2017 11:02
Source: CA01644-02
Spike source %REC
RPD
Ana
Result
Elan
MI.
Units
Level Besult %REC limits RPD
Limit flout
Phosphorus
2.0
0.10
mg/L
0.640 1.2 118 80-120
Matrix Spike Dup (7C16006-MSD1)
Prepared: 03/16/2017 M55 Analyzed: 03/20/2017 11:06
Source: CA01644-02
Spike Source %REC
RPD
Ana hda
Result
Has
POL
shire
Level Result %REC Limits RPD
Limit Moto
Phosphorus
2.0
0,10
mg/L
01640 1.2 113 80-120 2
25
Botch 7C2Oi702 - NO PREP
Blank (7C20002-BLKL)
Prepared & Analyzed: 03/20/2017 09:40
Spike Source %REC
RPD
Ana hds
Result
Flag
PQL
finite
Level BeSY1t %REC Limits RPD
Limit Mobat
Total Suspended Solids
2.5
U
2.5
mg/L
FINAL This report relates only to the sample as receNed by the laboratory, and may only he reproduced In full. Page 6 of 10

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QUALITY CONTROL DATA
Classical Chemistry parameters - Quality Control
Batt* 7C20001- NO PREP - Continued
LCS (7C20002-BSI)
Prepared & Analyzed: 03/20/2017 09:40
Spike Source %REC
RPD
Anailrra
Result an
PQL
Units
Level Sesult %REC limits RPD
Limit 119ws
Total Suspended Solids
98
2.5
mg/L
100 98 BD-120
Duplicate (7C20002-DUP1)
Prepared & Analyzed: 03/20/2017 09:40
Source; CA01292-01
Spike Source %REC
RPD
Ana hde
Result Fleq
P_QL
units
Level Result %REC Limits RPD
Limit Notes_
Total Suspended Solids
99
33
mg/L
110 11
20
Duplicate (7C20002-DUP2)
Prepared & Analyzed: 03/20/2017 09:40
Source: CA03877-01
Spike Source %REC
RPD
Ann hdo
Resin Elan
POL
Units
Level Result %REC Limital RPD
Lima Notes
Total Suspended Solids
260
33
mg/L
260 3
20
Bauch 7C20018 - Same
Blank (7C2001"LKI)
Prepared: 03/20/2017 14:21 Analyzed: 03/20/2017 18:08
Spike Source %REC
RPD
Anehde
Resu1L Bag
Pal.
Units
Level Result %REC Limits RPD
Limit Nogg
Chemical Oxygen Demand
10 U
10
mg/L
LCS (7C20018-BSI)
Prepared: 03/20/2017 14:21 Analyzed: 03/20/2017 18:08
Spike Source %REC
RPb
ADandzs
Result Hag
M
Unm
Level Result 0/aREC Limits RPD
limit Notes
Chemical Oxygen Demand
500
10
mg/L
500 100 90-110
Matrix Spike (7C20018-MSI)
Prepared: 03/20/2017 14:21 Analyzed: 03/20/2017 18:08
Source: CA02355-02
Spike Source 0/aREC
RPD
Anetfde
Result Bag
PM
Units
Level Resul %REC Limits RPD
Limit !Totes
Chemical Oxygen Demand
580
10
mg/L
526 54 100 90-110
Matrix Spike Dup (700(III&MSDi)
Prepared: 03/20/2017 14:21 Analyzed: 03/20/2017 18:08
Source: CA02355412
Spike Source %REC
RPD
AnatddLa
Result flag
EQL
Units
Level Result %REC Limits RPD
limit Notes
Chemical oxygen Demand
590
10
mg/L
526 54 101 90-110 2
10
Betch 7C21003 - NO PREP
Blank (7C21003-BLK1)
Prepared: 03/21/2017 11:17 Analyzed: 03/21/2017 11:17
Spike Source %REC
RPD
Ann hde
Result Bag
ML
Uhlb
Level Result %REC Limited RPD
Limit NRIN
Nitrate/Nitrite as N
0.041 U
0.10
mg/L
LCS (7C21003-BS1)
Prepared: 03/21/2017 11:15 Analyzed: 03/21/2017 11:15
Spike Source %REC
RPD
ADalYfie
Result Hag
e41
Units
Level Result %REC Llmlts RPD
Limit Notes
Nitrate/Nitrite as N
1.3
0.10
mg/L
1.25 106 90-110
FINAL This report relates only to the sample as received by the laboratory, and mayonly be reproduced In full. Page 7 of 1C

CS Nkkl
s i
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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 7C21O03 - NO PREP - Condnged
Matrix Spike (7C21003-MS1)
Prepared; 03/21/2017 11:19 Analyzed: 03/21/2017 11:19
Source: CA01362-01
Spike Source %REC
RPD
Ananda Result
Elan PDL
MIA
Level Resu(t %REC Limits RPD
Limit
Notes
Nitrate/Nitrite as N 160
10
mg/L
50.0 110 111 90-110
QM-07
Matrix Spike (7C21003-MS2)
Prepared: 03/21/2017 1L33 Analyzed: 03/21/2017 11:33
Source: CA01644-02
Spike Source %REC
RPD
Anal lda Result
Hag P_OL
Units
Level RCSA %REC Limits RPD
Llmlt
Notes
Nltrate/Nitrite as N 18
1.0
mg/L
5.00 14 76 90-110
QM-07
Matrix Spike Dup (7C21003-MSD1)
Prepared: 03/21/2017 11:28 Analyzed: 03/21/2017 11:28
Source: CA01362-01
Spike Source %REC
RPD
Ana hda Resit
fho QOL
Uriffa
Level Rem %REC Limits RPD
Llmlt
Notes
Nitrate/Nitrite as N 170
10
mg/L
50.0 110 130 90-110 6
10
QM-07
Balrli 7C21004 - NO PREP
Blank (7C21004-51.11(1)
Prepared: 03/21/2017 13:09 Anayzed: 03/21/2017 13:09
Spike Source %REC RPD
Ana lYtA Result Hag eal. Unfts Level Result %REC Llmlta RPD Llmlt Notes
Nitrate/Nitrite as N 0.042 U 0.10 mg/L
LCS (7C23004-BSL) Prepared: 03/21/2017 13:11 Analyzed: 03/21/2017 13:11
Spike Source %REC
RPD
Anal
Result Result
lice
P.f71
Units
Level $Ds& %REC Limits RPD
Llmlt Nabn
Nitrate/Nityke as N
1.1
0.10
mg/L
1.25 90 90-110
Matrix Spike (7C21004-1I51)
Prepared: 03/21/2017 13:17 Analyzed: 03/21/2017 13:17
Source: CA01308-01
Spike Source %REC
RPD
ADa4da
Resit
flag
POL
Unlfa
Level Result %REC Limits RPD
Llmlt Notes
Nitrate/Nitrite as N
0.53
0.10
mg/L
0.513 0.041 U 104 90-110
Matrix Spike (7C21004-MS2)
Prepared: 03/21/2017 13:26 Analyzed: 03/21/2017 13:26
Source: CA01310.01
Spike Source %REC
RPD
Anal ld0
Result
19;1g
Eal.
Units
Level Rusin %REC Unift RPD
LEmEt Notes
Nitrale/Nitrite as N
0.62
0.10
mg/L
0.513 0.093 102 90-110
Matrix Spike Dup (7C21004-MSD3)
Prepared: 03/21/2017 13:22 Analyzed: 03/21/2017 13:22
Source: CA01309-01
Spike Source %REC
RPD
Ana hd0
Result
flag
RQL
hails
' Level Resin %REC QUM RPD
Limit Notes
Nitrate/Nitrite as N
0.51
0,10
mg/L
0.513 0.041 U 99 90.110 5
10
FINAL This report relates only to the sample as receNed by the laboratory, and may only be reproduced in lull. Pape a of 10

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FLAGS/NOTES AND DEFINITIONS
B The analyte was detected in the associated method blank.
D The sample was analyzed at dilution.
I The reported value is between the laboratory method detection limit (MDQ and the laboratory method
reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable.
U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
E The concentration indicated for this analyte is an estimated value above the calibration range of the
instrument. This value is considered an estimate.
MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quandtation limit (PQQ and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution
factor, and, in the case of soil samples, moisture content.
N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater
confidence) to make a "tentative identification".
P Greater than 25% concentration difference was observed between the primary and secondary GC column.
The lower concentration is reported.
B-03 Blank exceeds the method required oxygen depletion of <0.20 mg/L.
QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was
accepted based on acceptable LCS recovery.
FINAL This report reiates only to the sample as received by the laboratory, and may only be reproduced In full. Page 9 of 10

, Lf\ft/1ys�lntl\1ML a.+<.are\.yC17tMeeV1\LMOVRl�1 Ve11CJ V.'1W�iR/rti�IJ�VY■ nC4.InLP www.m'mumus-com
70M Central Part Dr. 4e10 EmKm p Park Court. Sufp 111 102-A Wboamn$ bxbxaug CL
Orbndq FL 32W4 .hd®ooriaa, FL 32216.6069 Cary. NC 27511 j
(4M CM-014 Feu (407) 850-OM (904) 2W3oW7 Fax (W4) 29G-W10 (919) 467-MM Fla (919) 4673515 Page --L ut F
C W Name
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Franklinton, NC 27525
PO e 1 S&V bdo -
38=45169
Tel - - Fax
494-•3370,
Reporting Cord-
Joe Ladd
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Note : AN sanWi s submdhed to ENCO Lake we in awardarxe w M the brass aril mrlQdi m lftd an the mvem d this form. {mess pdm wrillen aWeE nwo mW

Sample Preservation Verification
ENCO Cary C
Work Order: CZ19517 Project: Stormwate_r Testing
Client: Novozymes North America (NO008) Project #: [none]
Logged In: 15-Mar-17 08:19 Logged By: John C King
CZ19517-01
Cont
type
Pres (pH .,
Re uirement
pH Checked i
In Controt .
D.at ime
pHAdjusted. `Adjusted
i
ReagentUsedlCamrttents {
D
250mLP+H2SO4
<2
/ N! NA
Y I C1 NA
E
250mLP+H2SO4
<2
! N I NA
Y I 0 ! NA
CZ19517-02
Cont
Type
Pres (pH)
Requirement
p Checked
In Control'
• .. ate me
pH Adjusted; 'Adjusted
Reagent;Used1comments..
D
250mLP+H2SO4
<2
/ N / NA
Y ! / NA
E
25OmLP+H2SO4
<2
I N ! NA
Y / ! NA
Rea ent Name ID
1
2
Rea ent Name ID
3
4
Reagent Name ID
5
6
Page 1 o

Date: March 1, 2017
Novozymes, NA Inc.
77 Perry's Chapel Church Rd.
Franklinton, N.C. 27525
NC DEQ Division Of Water Quality
1617 Mail Service Center Raleigh, N.C. 27699-1617
Attn: Division Of Water Quality
Storm Water Sampling, NPDES Permit. o. NCS000115
Dear Sir/Madam
novozymesm
Rethink Tomorrow
RECEIVED
APR 10 2017
CENTRAL FILES
DWR SECTION
Per our Tier Two requirements, regarding the exceeded benchmark in Chemical Oxygen Demand, (COD)
and Biological Oxygen Demand (HOD), our implementation of a monthly monitoring in area of concern,
"Outfall 2", beginning in January has resulted in "No Flow" for the month of February.
We therefore were unable to collect a sample for this month. We plan to continue to diligently with our
monthly monitoring for the parameters of COD and BOD until we obtain three consecutive sample results
within the benchmark range.
Kind Re
VIV
Joe Ladd
Environmental Compliance Coordinator
Environmental Services
RECEIVED
APR o 5 2017
DENR-LAND QUALITY
STORMWATER PERMITTING

Date: March 1, 2017
Novozymes, NA Inc.
77 Perry's Chapel Church Rd.
Franklinton, N.C. 27525
NC DEQ Division Of Water Quality
1617 Mail Service Center Raleigh, N.C. 27699-1617
Attn: Division Of Water Quality
Storm Water Sampling, NPDES Permit o. NCS000115
Dear Sir/Madam
novozY mes°
Rethink Tomorrow
Per our Tier Two requirements, regarding the exceeded benchmark in Chemical Oxygen Demand, (COD)
and Biological Oxygen Demand (BOD), our implementation of a monthly monitoring in area of concern,
"Outfall 2", beginning in January has resulted in "No Flow" for the month of January.
We therefore were unable to collect a sample for this month. We plan to continue to diligently with our
monthly monitoring for the parameters of COD and BOD until we obtain three consecutive sample results
within the benchmark range.
Kind Regards-
9/4
1 �4
Joe Ladd
Environmental Compliance Coordinator
Environmental Services
ls
JNI�1Wdf1V GNV �INBG
LICZ L 0 W
a3n1305*8

CO Laboratories
Accurate. Timely. Responsive. Innovative.
102-A Woodwinds Industrial Court
Cary Nc, 27511
Phone: [phone] FAX: [phone]
Tuesday, December 20, 2016
Novozymes North America (N0008)
Attn: Joe Ladd
77 Perry Chapel Church Road
Franklinton, NC 27525
RE: Laboratory Results for
Project Number: (none], Project Name/Desc: Stormwater Testing
ENCO Workorder(s): CZ17991
Dear Joe Ladd,
N GS D
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Wednesday, December 7, 2016.
Unless otherwise noted in an attached project narrative, all samples were received In
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are in compliance with NELAC standards, except
as noted in the project narrative. This report shall not be reproduced except in full, without
the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
Stephanie Franz For Chuck Smith
Project Manager
Enclosure(s)
RECEIVED
JAN 2 0 2017
CENTRAL FILES
DWR SECTION
FIMAL This report relates only to the sample as receNed by the labmsbory, and may only be reproduced In hull, I Page 1 of 1 1

1 q)
Ce NS a! w
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SAMPLE SUMMARY/ LABORATORY CHRONICLE
CllentID: OuftliI
Lab ID: CZ17991-01
Sampled: 12/06/1613:30 Received: 12/07/1607:15
ParametaC
EPA 351.2
Hald Date/Tlme(sI
01/03/17
Prep DateITlmefsl
12J08/16
10:10
Analysis Date/Time(s)
12/13/16 OX
EPA 353.2
12/08/16
13:30
12/07/16
14:57
12/07/16 15:59
EPA 353.2
01/03/17
12/16/16
07:54
12/16/16 10:37
EPA 353.2
09/01/19
12/16/16
14a6
12/16/16 14:16
EPA 365.4
01/03/17
12/08/16
10:10
12/13/16 14:32
SM 2-WD-1997
12/13/16
12/12/16
09:00
12/12/16 09:00
SM 521OB-2001
12/08/16
13:30
12/07/16
14:19
12/07/16 14:19
SM 5220D-1997
01/03/17
12/13/16
10:48
12/13/16 1510
Client ID: WWI 2
Lab ID: CZ17991-02
Sampled: 12/06/16 14:40 Received: 12/07/16 07:25
Parameter
EPA 351.2
Hold Date/Tlme(e)
01/03/17
Prep DateITlmefsl
12/08/16
10:10
Analysis DateMmefsl
12/13/16 13:35
EPA 353.2
12/08/16
14:40
12/07/16
14:57
12/07/16 16:02
EPA 353.2
01/03/17
12/20/16
07:57
12/20/16 10:22
EPA 353.2
09/01/19
12/20/16
1130
12/20/16 13:43
EPA 365.4
01/03/17
12/08/16
10:10
12/13/16 14:34
SM 254OD•1997
12/13/16
12/07/16
13:00
12/07/16 13:00
SM 521OB-2001
12/08/16
14:40
17J07/16
14:19
12/07/16 14:19
SM 522013-1997
01/03/17
12/13/16
10:48
12/13/16 15:10
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 2 Of 'I

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ANALYTICAL RESULTS
Description: Outfall 1 Lab Sample ID: CZ1799 1-01 Received: 12/07/16 07a5
Matrix; Surface Water Sampled:12/06/16 13:30 Work Order: CZ17991
Project: StonnwaterTesting Sampled By. -Joe Ladd
Classical Chemistry Parameters
^ - EAM Lary [e U&,d analyle [AC 5911
flag
ynb
2E
MU
PQL
1=
Method
Analyzed
�][
Biochemical Oxygen Demand^
3.0
mg/L
1
2.0
2,0
6LO7025
SM 521OB-2001
12/07/16 14:19
10C
0-07
Chemical Oxygen Demand^
30
mg/L
1
10
10
61.13013
SM 522OD-1997
12/13/16 15:10
30C
Nitrate as N [14797-55-B]^
0.57
mg/L
1
0,025
0.10
61.16034
EPA 353.2
12/16/16 14:16
IL)
Nltrate/Nltrite as N^
0.59
mg/L
1
0.041
0.10
6L16008
EPA 353.2
12/16/16 10:37
JU
Nitrite as N [14797-65-0]^
0.018
3
mg/L
1
0.017
0.10
6LO7006
EPA 353.2
12/07/16 15:59
31-3
Phosphorus [7723-14-0]^
0.24
mg/L
1
0.025
0.10
61-08006
EPA 365.4
12/13/16 14:32
ILI
Total K161dahl Nitrogen^
0.89
mg/L
1
0.26
0.48
6LO8005
EPA 351.2
12/13/16 13:33
ILI
Total Suspended Solids^
30
mg/L
5
12
12
6L12003
SM 2SQD-1997
12/12/16 09:00
MMR
Description: Outfall 2
Lab Sample ID: CZ17991-02
Received: 12/07/16 07:15
Matrix: Surface Water
Sampled.12/06/16 14:40
Work Order: CZ17991
Project: StormwaterTesting
Sampled By: Joe Ladd
Classical Chemistry Parameters
^ - &,C0 Cary c&VAed anaryre [NC 5911
Anahrte rCAS Numberl Results
Elm
mob
2E
HU
PQL
RaUh
Hadlod
Analyzed
gy
Raw
Biochemical Oxygen Demand-
33
mg/L
1
2.0
2.0
6LO7025
SM 521OB-2001
12/07/16 14:19
30C
B-07
Chemical Oxygen Demand^
130
mg/L
1
10
10
6L13013
SM 5220D-1997
12/13/16 15:10
J0C
Nitrate as N (14797-55-B]^
0.19
mg/L
1
0.025
0.10
6L20028
EPA 353.2
12/20/16 13:43
JU
Nitrate/Nitrite as N^
0.19
mg/L
1
0.041
0.10
6L20003
EPA 353.2
12/20/16 10:22
JU
Nitrite as N [14797-65-0]^
0.017
U
mg/L
1
0,017
0.10
61LO7006
EPA 353.2
12/07/16 16:02
3L3
Phosphorus [7723-14-0]^
0.11
mg/L
1
0.025
0.10
6LOS006
EPA 365.4
12/13/16 14:34
310
Total I(jeldahl Nitrogen^
2.2
mg/L
1
0.26
0.48
6LO8005
EPA 351.2
12/13/16 13:35
3L3
Total Suspended Solids^
13
mg/L
4
t0
30
6L07003
SM 254OD-1997
12/07/16 13:00
MMR
FINAL This report relates only to the sample as receKmd by the laboratory, and may only be reproduced In fuel, Page 4 Of 11

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SAMPLE DETECTION SUMMARY
Client ID: Outfall 1
Lab ID:
CZ17992-01
Anatyte
Results
H92 MU
E"
lhliLa
Martbod Notes
Biochemical Oxygen Demand
3.0
2.0
2.0
mg/L
SM 521OB-2001 B-07
Chemical Oxygen Demand
30
10
10
mg/L
SM 5220D-1997
Nitrate as N
0.57
0.025
0.10
mg/L
EPA 353.2
Nitrate/Nitrite as N
0.59
0.041
0.10
mg/L
EPA 353.2
Nitrite as N
0.018
1 0.017
0.10
mg/L
EPA 353.2
Phosphorus
0.24
0.025
0.10
mg/L
EPA 365.4
Total Kjeldahl Nitrogen
0.89
0.26
0.48
mg/L
EPA 351.2
Total Suspended Solids
30
12
12
mg/L
SM 2WD-1997
Client ID: outfall 2
Lab ID:
CZ17991-02
AgA1Yl:C
RUMIM
E109 Hu
M
!l11ltIF
Mt1t1t9d Notes
Biochemical Oxygen Demand
33
2.0
2.0
mg/L
SM 521OB-2001 B-07
Chemical Oxygen Demand
130
10
10
mg/L.
SM 5220D-1997
N Itrate as N
0.19
0.025
0.10
mg/L
EPA 353.2
Nitrate/Nitrite as N
0.19
0.041
0.10
mg/L
EPA 353.2
Phosphorus
0.11
0.025
0.10
mg/L
EPA 365.4
Total Kjeldahl Nitrogen
2.2
0.26
0.48
mg/L
EPA 351.2
Total Suspended Solids
13
10
10
mg/L
SM 254OD-1997
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced 0 full. I Page 3 Of 'I

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QUALITY CONTROL. DATA
Classical Chemistry parameters - Quality Control
Batch 6L07003 - NO PREP
Blank (6L07003-BLKi) Prepared & Analyzed: 12/07/2016 13:00
Spike Source %REC RPD
Anahft Result ElaO POL Units Level get %REC Limps RPD Lump Notes
Total Suspended Solids 2.5 u 2.5 mg/L
LCS (61.07003-111SI) Prepared & Analyzed: 12/07/2016 13:00
Spike Source %REC
RPD
Anal
Result Elm PQL
Units
Level get %REC Limns
RPD
Limit Notes
Total Suspended Solids
100 2.5
mg/L
100 100 80-120
Duplicate (6L07003-DUP3)
Prepared & Analyzed: 12/07/2016 13:00
Source: CZ07886-01
Spike Source %REC
RPD
Anal
Result Elag P"
Units
Level Result %REC limits
RPD
Limit Notes
Total Suspended Solids
110 33
mg/L
110
0
20
Duplicate (6L07003-DUP2)
Prepared & Analyzed: 12/07/2016 13:00
Source: CZ16257-01
Spike source %REC
RPD
Anal wa
Result Elm ML
Units
Level get %REC Limits
RPD
LiIDlt !!Notes_
Total Suspended Solids
450 71
mg/L
370
17
20
Batch 6107006 - NO PREP
Blank (61.07006-81.1(i) Prepared: 12/07/2016 07:39 Analyzed: 12/07/2016 09:33
Spike Source %REC RPD
Ana hrta Result ew EQL units Level Result %REC Limits Rpo Limit Jg
Nitrite as N 0.017 U 0.10 mg/L
LCS (61.07006-851) Prepared: 12/07/2016 07:39 Analyzed: 12/07/2016 09:46
Spike Source %REC
RPD
AnaResult
HM EQL
Units
Level Result %REC Limits RPD
Limit Flours_
Nitrite as N 0.98
0.10
mg/L
1.00 98 90.110
Matrix Spike (61.07006-MS1)
Prepared: 12/07/2016 07:39 Analyzed: 12/07/2016 09:34
Source: CZ17398-01
Spike Source %REC
RPD
Anatfrilz Result
Elm EQL
UnlU
Level gesy(t %REC Limits RPD
umill Notes
Nitrite as N 0.97
0.10
mg/L
1.00 0.049 92 90.110
Matrix Spike (61.07006-M52)
Prepared: IW07/2016 07:39 Analyzed: 12/07/2016 16:01
Source: CZ17991-01
Spike Source %REC
RPD
Ana 6rse Result
Ilag EQL
Units
Level gesult %REC Limits RPD
Limit Notes
Nitrite as N 0.92
0.10
mg/L
1.00 0.018 90 90-I10
Matrix Spike Dup (61.07006-MSDL)
Prepared: 12/07/2016 07:39 Analyzed: 12/07/2016 09:37
111
Source: CZ27398-01
ADand®
Nitrite as N
Batch 6LO7025 - NO PREP
Spike Source %REC
Result Elm P01 Units Level Result %REC Limps RPD
0.99 0.10 mg/L 1.00 0.049 95 90-110 2
RPD
Limit Notes
10
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 5 Of 11

(9 �Ew'
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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Battle 6LO7025 - NO PREP - Conf lnntred
Blank (6L07025-BLK1) Prepared & Analyzed: W0712016 14:19
Spike Source %REC RPO
Anal r Result Flea POL UnRs Level Result %REC Limits RPD Limit Notes
Biochemical Oxygen Demand 2.0 U 2.0 mg/L
LCS (6L07025-0S1) Prepared & Analyzed: 12/07/2016 14:19
Spike Source a/oREC
RPD
Anande,
Result Elan POL
UnFts
Level Result %REC Urnits RPD
Limit Notes -
Biochemical Oxygen Demand
130 2.0
m91L
198 68 85-115
B-07
Duplicate (GL0702S-DUP1)
Prepared & Analyzed: 12/07/2016 14:19
Source: CZ15428-01
Spike Source %REC
RPD
Ana tlta
Result flag POL
Smite
Level Result %REC Limits RPD
Limit Notes_
Biochemical Oxygen Demand
160 2.0
mg/L
140 ' 7
30 B-07
Batch 6L08005 - Some
Blank (611.08005-BLKl) Prepared: 12/08/2016 10:10 Analyzed: 12/13/2016 10:52
Spike Source %REC RPD
AndSYte Result Elm POL Unitf Level Result %REC Limits RPD Limit Notes
Total Kjeldahl Nitrogen 0.26 U 0,48 mg/L
LCS (61.08005-BS1) Prepared: 12/DS/2016 10:10 Analyzed: 12/13/2016 10:54
Spike Source %REC
RPD
Ana htLo
Result
Hd0
POL
unb
Level Result %REC Limits RPD
Limit
Notes
Total Kjeldahl Nitrogen
12
0.48
mg/L
11.9 99 90-110
Matrix Spike (6L08005-MS1)
Prepared: 12/08/2016 10:10 Analyzed: 12/13/2016 10:57
Source: CZ17389-01
Spike Source %REC
RPD
Ann i]de
Result
i3eaq
POL
Units
Level Result %REC Limits RPD
Limit
Notes
Total Kjeldahl Nitrogen
4.9
0,48
mg/L
4.75 0.88 84 90-110
QM-07
Matrix Spike (61.08005-MS2)
Prepared: 12/08/2016 10:10 Analyzed: 12/13/2016 11:10
Source: CZLS428-01
Spike Source %REC
RPD
AnalStlD
Result
on
PUL
units
Level Result %REC Limits RPD
Limit
Notn
Total Kjeldahl Nitrogen
130
D
4.8
mg/L
4,75 120 137 90-110
QM-07
Matrix Spike Dup (61.08005-MSDi)
Prepared: 12/08/2016 10:10 Analyzed: 12/13/2016 11:01
Source; CZ17369-01
Spike Source %REC
RPD
Ann
Result
Elm
POL
unite
Level Result %REC Limits RPD
Limit
Notes
Total Kjeldahl Nitrogen
5.0
0.48
mg/L
4.75 0.88 87 90.110 3
10
QM-07
Battle 6LOB006 - Same
Blank (611.08006-BLKL)
Prepared: 12/08/2016 10:10 Analyzed: 12/13/2016 12:45
Spike Source %REC
RPD
Ana 4tta
Result
Elm
POL
Unb
Level Result %REC Limits RPD
Limit
Notes
Phosphorus
0.025
U
0.10
mg/L
ANAL This report relates only to the sample as receNad by the laboratory, and may only be reproduced in U. I Page 6 Qf 11

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 6108005 - Same - Continued
LCS (61.08006-B51)
Prepared: 12/08/2016 10:10 Analyzed: 12/13/2016 12:46
Spike Source %REC
RPD
Ana hde
Result
Hag
F!QL
UrI tf
Level Result %REC LiMig
RPD
Limit Notes
Phosphorus
1.6
0.10
mg/L
1.60 98 80-120
Matrix Spike (6108006-MS1)
Prepared: 12/08/2016 10:10 Analyzed: 12/13/2016 12:48
Source: CZ17389-01
Spike Source %REC
RPD
Anik
Result
ENM
ML
Unite
Level Result %REC Limits
RPD
Limit !Votes
Phosphorus
4.5
D
0.50
mg/L
0,640 4.0 90 80.120
Matrix Spike Dup (61.08006-MSD1)
Prepared: 12/08/2016 10:10 Analyzed: 12/13/2016 12:51
Source: CZ17389-01
Spike Source %REC
RPD
Ana
Result
Hag
PAL
Units
Level Resu1i %REC Limits
RPD
Limit Notes
Phosphorus
5.0
D
0.50
mg/L
0.640 4.0 167 80-120
10
25 QM-07
Batt* 6L12003 - NO PREP
Blank (6L12003-Ba~Kl)
Prepared & Analyzed: 12/12/2016 09:00
Spike Source %REC
RPD
Anal 1Re
Result
Hag
PQL
Units
Level Result %REC Limits
RPD
LIIDR Notes
Total Suspended Solids
2.5
U
2.5
mg/L
LCS (61.12003-851)
Prepared IN Analyzed: 12/12/2016 09:00
Spike Source %REC
RPD
80a
Result
Hen
Poll.
Lmb
Level 1esult %REC Limits
RPD
Limit Notes
Total Suspended Solids
92
2.5
mg/L
100 92 80-120
Duplicate (61-12003-DUP3)
Prepared & Analyzed: 12/12/2016 09:00
Source: CZ07895-01
Spike Source %REC
RPD
Anal !!ta
Result
Elm
PQL
Units
Level Ressiit %REC Limits
RPD
Limit Notes
Total Suspended Solids
59
17
mg/L
61 '
2
20
Duplicate (6L12003-DUP2)
Prepared & Analyzed: 12/12/2016 09M
Source: CZ07895-02
Spike Source %REC
RPD
Ana
Result
Hag
M
Units
Level Result %REC Limits
RPD
Limit Notes_
Total Suspended Solids
87
25
mg/L
93
7
20
Ba" 6L13013 - some
Blank (61.13013-111M) Prepared: 12/13/2016 10:48 Analyzed: 12/13/2016 15:10
Spike Source %REC RPD
Ana hde Result Hag P41 Units Level Result %REC Limits RPD Limit Notes
Chemical Oxygen Demand 10 U 10 mg/L
LCS (6L13013-BSI) Prepared: 12/13/2016 10:48 Analyzed: 12/13/2016 IS: 10
Spike Source %REC RPD
Anal lft8 Result Hag PQL Units Level Besult %REC Limits RPD Limit Notes
Chemical Oxygen Demand 510 10 mg/L 500 102 90-110
FINAL This report relates only to the sample as reoeived by the laboratory, arid may only be reproduced In full, I Page 7 Of 14

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 6L13013 - Some - Condbued
Matrix Spike (61.13013-MSl)
Prepared: 12/13/2016 10:48 Analyzed: 12/13/2016 15:10
Source: CZ15423-02
Spike Source %REC
RPD
Ana hd® Result
Hoe PQL
Units
Level Result %REC Limits RPD
Limit Notes
Chemical Oxygen Demand 550
10
mall.
526 41 97 90-110
Matrix Spike Dup (6L13013-MSDi)
Prepared; 12/13/2016 10:48 Analyzed: 12/13/2016 IS! 10
Source: CZ15413-02
Spike Source %REC
RPD
.Ana ivtp Result
Elm PM
units
Level Resin %REC LWIM RPD
Llmlt Notes
Chemical Oxygen Demand 580
10
mg/L
526 41 102 90.110 5
10
Batch 6116O08 - NO PREP
Blank (6L16008-BLKl) Prepared: 12/16/2016 07:54 Analyzed: 12116/2016 10:01
Spike Source %REC RPD
Gnat Result Hag Pal. Units Level Result %REC Limits RPD Limit Notes
Nitrate/Nitrite as N 0.041 U 0.10 mg/L
LCS (61.16008-BS1) Prepared: 12/16/2016 07:54 Analysed: 12/16/2016 09:59
Spike source %REC
RPD
Ana hda
Result
flan
PQL
knits
Level Result %REC Llm& RPD
Limit Notes
Nltrate/NitriteasN
1.2
0.10
mg/L
1.25 99 90.110
Matrix Spike (61.16008-101SI)
Prepared: 12/16/2016 07:54 Analyzed: 12116/2016 10:03
Source: CZ16370-01
Spike Source %REC
RPD
flllallrffi
Resin
Hall
EQL
Units
Level Besult %REC LURE RPD
Limit Notes
Nitrate/Nitrite as N
11
1.0
mg/L
5.00 6.3 98 90-110
Matrix Spike (61.16008-M51)
Prepared: 12/16/2016 07:54 Analyzed: 12/16/2016 10:12
Source: CZ17188-01
Spike Source %REC
RPD
Anal fine
Result
Fin
PQL
Units
Level Result %REC Limits RPD
Lima Notes
Nitrate/Nitrite as N
96
10
mg/L
50.0 43 105 90-110
Matrix Spike Dup (61.36008-MS01)
Prepared: 12/16/2016 07:54 Analyzed: 12/16/2016 10:07
Source: aL6370-01
Spike Source %REC
RPD
Anal Yte
Result
Flan
EQL
Units
Level Besult %REC Lilillld RPD
Limit Notes
Nitrate/Nitrite as N
11
1.0
mg/L
5.00 6.3 94 90-110 2
10
Batch 6L20003 - NO PREP
Blank (6L20003-BLKl) Prepared: 12/20/2016 07:57 Analyzed: 12/20/2016 10:09
Spike source a/oREC RPD
Ana hde Res -it Else ROL Units Level Resul %REC Limits RPD Limit Notes
Ntuate/Nitrite as N 0.041 U 0.t0 mg/L
LCS (6L20003-BS1) Prepared: 12/20/2016 07:57 Analyzed: 12/20/2016 10:07
Spike Source %REC RPD
Ana iYtB Result Fin PQL units Level Be5Y1t %REC Llmlta RPD Llmlt Notes
NitmWfiitrite as N 1.2 0.10 mg/L 1.25 97 90.110
FINAL This report relates only to the sample as receMed by the laboratory, and may only be reproduced In full. I Page 8 0 11

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 6L20003 - NO PREP - Continued
Matrix Spike (611.20003-4151)
Prepared: W20/2016 07:57 Analyzed: 12/20/2016 10:11
Source: CZ17391-01
Spike Source %REC
RPD
AnaResult
Sao PQL
Units
Level $erult %REC Limits RPD
Limit Notes
Nitrate/Nitrite as N 9.2
1.0
mg/L
5.00 3.8 108 90-110
Matrix Spike (6L20003-M52)
Prepared: 12/20/2016 07:57 Analyzed: 12/20/2016 10:20
Source: CZ17395-01
Spike Source %REC
RPD
Anal sds Result
Elaa i?QL
units
Level Result %REC LIB RPD
Limit Mates
Nitrate/Nitrite as N 37
5.0
mg/L
25.0 12 99 90-110
Matrix Spike Dup (6L20003-MSDi)
Prepared: 12/20/2016 07:57 Analyzed: 12/20/2016 10:16
Source:CZIL7391-01
Spike Source %REC
RPD
Anands Result
flan PDL
llnita
Level gesul%REC Limits RPD
Limit Notes
Wtrate/Nitrlte as N 8.9
1.0
mg/L
5.00 3.8 101 90-110 4
10
FINAL This report relates only to the sample as received by the laboratory, and may only be reGroduced In full. I Page 9 o

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FLAGS/NOTES AND DEFINITIONS
B The analyte was detected in the associated method blank.
D The sample was analyzed at dilution.
The reported value is between the laboratory method detection limit (MDL) and the laboratory method
reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable.
U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
E The concentration indicated for this analyte is an estimated value above the calibration range of the
Instrument. This value is considered an estimate.
MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution
factor, and, in the case of soil samples, moisture content.
N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater
confidence) to make a "tentative identification".
P Greater than 25% concentration difference was observed between the primary and secondary GC column.
The lower concentration is reported.
B-07 LCS exceeded control limits for this test. The test can not be repeated due to method
constraints. The result should be considered an estimated value.
QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was
accepted based on acceptable LCS recovery.
FINAL This report relates onry to the sample as recelved by the laboratory, and may onh' be reproduced in full. IPage 10 ci 11

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4.
Date: December 23, 2016
RECEIVED
Novozymes, NA Inc. JAB 0 Z�17
77 Perry's Chapel Church Rd.
Franklinton, N.C. 27525 CENTRAL FILES
DWR SECTION
NCDEQ Division Of Water Quality
1617 Mail Service Center Raleigh, N.C. 27699-1617
Attn: Division Of Water Quality
Storm Water Sampling, NPDES Permit No. NCS000115
Dear Sir/Madam,
novozymes•
Rethink Tomorrow
RECEIVED
JAN 2 0 2011
CENTRAL FILES
DWR SECTION
During review of storm water sampling results, it was observed that there was an exceeded benchmark in
Biological Oxygen Demand (BOD), and Chemical Oxygen Demand (COD) from our Outfall 2 location.
This was the second exceedance in as many sampling events for BOD and COD.
Upon immediate investigation, per Tier One requirements, it was discovered that although during sample
event no signs of potential issues were present, the area approximately 20 yards from where samples are
collected the combination of filtration systems not cleaned properly, the off-loading of raw materials along
with containers of product that had been rinsed prior to being disposed have been considered direct cause of
the recent exceeding of both BOD and COD benchmarks. Plans are in place to have personnel in area begin
with cleaning filtration systems and more caution taken place while material is being handled, containers
rinsed.
Progress has been made reducing BOD and COD readings; however they were still not below benchmark
standards. Therefore, per Tier Two requirements we will begin monthly monitoring of Outfall 2 until three
consecutive sample results are below benchmark values.
Continued monitoring by Environmental Services Department will take place in order to prevent future
exceeded benchmarks in Biological Oxygen Demand (BOD), and Chemical Oxygen Demand (COD)
from Outfall 2.
Kind Re s,
Joe Lad
Environmental Compliance Coordinator
Environmental Services

RECEIVED
JAN 2 0 2017
CENTRAL FILES
DWR SECTION
EFFLUENT
NPDES PERMIT NO. NCS000115 DISCHARGE NO.
FACILITY NAME Novozymes, NA Inc. CLASS
OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA
CERTIFIED LABORATORIES (1) Enco
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES
Mail ORIGINAL and ONE COPY to:
�I
(z)
RECEIVED a.
JAN 2 0 Zw17
CENTRAL. FILES
DWR SECTION
MONTH Decemer YEAR 2016
COUNTY: Franklin
PHONE [phone]
Joe Ladd
ATTN: CENTRAL FILES x NIA
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY
RALEIGH, NC 27699-1617 KNOWLEDGE.
LOL�L�LI•�L��L�t•�Ll•����L�L�r�
L1I�7L1•�L��L�L����L��®��L�LI•r
�L�L�L��L��L�L��LI•����L�L>•�
Lml�l�l��l��l���l�r���l�l>•�
L®�L�LI•�L���L��t•����L�L��
DWQ Form MR-] (11/04)

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
(including weekly averages, if applicable)
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially
threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the
permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the
permittee becomes aware of the circumstances.
If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for
improvements to be made as required by Part II.E.6 of the NPDES permit.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly
responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Randv Green
Permittee (Please print or type)
�-2.
S' a P ittee*** Date
(Required u ss submitted electronically)
Permittee Address Phone Number e-mail address Permit Expiration Date
Certified Laboratory (2)
Certified Laboratory (3)
ADDITIONAL CERTIFIED LABORATORIES
Certification No.
Certification No.
Certified Laboratory (4) Certification No.
Certified Laboratory (5) Certification No.
PARAMETER CODES
Parameter Code assistance may be obtained by calling the NPDES Unit at [phone] or by visiting the Surface
Water Protection Section's web site at h2o.enrstate.nc.uslwas and linking to the unit's information pages.
Use only units of measurement designated in the reporting facility's NPDES permit for reporting data.
* No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be
entered for all of the parameters on the DMR for the entire monitoring period.
** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204.
*** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on
file with the state per 15A NCAC 2B .0506(b)(2)(D).
Page 2

EFFLUENT
NPDES PERMIT NO. NCS000115 DISCHARGE NO. 2
FACILITYNAME NOVOZymeS, NA Inc. CLASS
OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA
CERTIFIED LABORATORIES (1) Enco (2)
CHECK BOX IF ORC HAS CHANGED PERSON($) COLLECTING SAMPLES
Mail ORIGINAL and ONE COPY to:
RECEIVED
AN 2 0 2017
CENTL FILES
DWR SECTION
MONTH Decemer YEAR 2016
COUNTY: Franklin
PHONE [phone]
Joe Ladd
ATTN: CENTRAL FILES x NIA
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY
RALEIGH, NC 27699-1617 KNOWLEDGE.
�wm��mlm�
mcm
DWQ Form MR-1 (11/04)

Facility Status: (Please check one of the following) J
All monitoring data and sampling frequencies meet permit requirements
(including weekly averages, if applicable)
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially
threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the
permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the
permittee becomes aware of the circumstances.
If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for
improvements to be made as required by Part II.E.6 of the NPDES permit.
"I certity, under penalty of law, that this document and all attachments were prepared under my direction or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly
responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Randy Green
Permittee (Please print or type)
Si a r e ittee*** Date
(Required un submitted electronically)
Permittee Address Phone Number e-mail. address Permit Expiration Date
Certified Laboratory (2)
Certified Laboratory (3)
Certified Laboratory (4)
ADDITIONAL CERTIFIED LABORATORIES
Certification No.
Certification No.
Certification No.
Certified Laboratory (5) Certification No.
PARAMETER CODES
Parameter Code assistance may be obtained by calling the NPDES Unit at [phone] or by visiting the Surface
Water Protection Section's web site at h2o.enr.state.nc.us/ s and linking to the unit's information pages.
Use only units of measurement designated in the reporting facility's NPDES permit for reporting data.
* No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be
entered for all of the parameters on the DMR for the entire monitoring period.
** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204.
***Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on
file with the state per 15A NCAC 2B..0506(b)(2)(D).
Page 2

ENCO Laboratories
Accurate. Timely. Responsive. Innovative.
102-A Woodwinds Industrial Court
Cary NC, 27511
Phone: [phone] FAX: [phone]
Friday, April 22, 2016
Novozymes North America (NO008)
Attn: Joe Ladd
77 Perry Chapel Church Road
Franklinton, NC 27525
RE: Laboratory Results for
Project Number: [none], Project Name/Desc: Stormwater Testing
ENCO Workorder(s): CZ01509
Dear Joe Ladd,
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Wednesday, April 13, 2016.
Unless otherwise noted in an attached project narrative, all samples were received in
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are in compliance with NELAC standards, except
as noted in the project narrative. This report shall not be reproduced except in full, without
the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
Chuck Smith
Project Manager
Enclosure(s)
0vw
RECEIVED
JUN 16 2016
CENTRAL FILES
DWR SECTION
FINAL This report relates only to the sample as receNed by the laboratory, and may only be reproduced h full, Page 1 of 10

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SAMPLE SUMMARY/LABORATORY CHRONICLE
Client ID: Outfall -1
Lab ID: CZ01509-01
Sampled: 04/12/16 09:00 Received: 04/13/16 07:25
Parameter
EPA 351.2
Hold Date/Tlmefs]
05/10/16
Pren DatelTlmefsl
04/16/16
Analrsls DatelTimefsl
11:30 04/19/16 08:27
EPA 353.2
04/14/16 09:00
04/13/16
14:29 04/13/16 16:21
EPA 353.2
05/10/16
04/21/16
07:46 04/21/16 11:39
EPA 353.2
01/06/19
04/22/16
08:47 04/22/16 09:11
EPA 365.4
05/10/16
04/16/16
11:30 D4/19/16 10:29
SM 254OD-1997
04/19/16
D4/18/16
09:19 D4/18/16 09:19
SM 521OB-20DI
04/14/16 09:00
D4/13/16
14:36 04/13/16 14:36
SM 5220D-1997
05/10/16
D4/21/16
11:57 04/21/16 18:20
Client ID: Outfall - 2
Lab ID: CZ01509-02
Sampled: 04/12/16 09:35 Received: 04/13/16 07:25
Parameter
EPA 351.2
Hold DatelTlmelsl
05/10/16
Prep Date/3lmefs1
D4/16/16
Analysis D0�/Tlmefsl
11:30 04/19/16 08:31
EPA 353.2
04/14/16 09:35
D4/13/16
14:29 04/13/16 16:24
EPA 353.2
05/10/16
04/21/16
07:46 04/21/16 11:43
EPA 353.2
01/06/19
D4/22/16
08:47 04/22/16 09:11
EPA 365.4
05/10/16
04/16/16
11:30 04/19/16 10:32
SM 2540D-1997
04/19/16
04/14/16
13:00 04/14/16 13:00
SM 5214B-2001 04/14/16 09:35
SM 52200-1997 05/10/16
D4/13/16 14:36 04/13/16 14:36
04/21/16 11:57 04/21/16 18:20
F[NAL TNs report relates only to the sample as recelved try the laboratory, and may only be reproduced in full. Page 2 of 10

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SAMPLE DETECTION SUMMARY
client ID: Outrall -1
Lab ID: CZ01509-01
Auahte
Results
an X"
E"
dolts
Method ll9sea
Biochemical Oxygen Demand
3.6
2.0
2.0
mg/L
SM 521OB-2001
Chemical Oxygen Demand
14
10
10
mg/L
SM 5220D-1997
Nitrate as N
0.90
0,025
0.10
mg/L
EPA 353.2
Nitrate/Nitrlte as N
0.93
0.041
0.10
mg/L
EPA 353.2
Nitrite as N
0.030
3 0.017
0.10
mg/L
EPA 353.2
Phosphorus
0.18
0.025
0.10
mg/L
EPA 365.4
Total Kfeldahl Nitrogen
0.99
0.26
0.48
mgtL
EPA 351.2
Total Suspended Solids
15
5.0
5.0
ma/L
SM 2540D-1997
AualYte
Results Piaui
M"
ML
M1 k
Method Notes
Biochemical Oxygen Demand
>73
2.0
2.0
mg/L
SM 521OB•2001 8-02
Chemical Oxygen Demand
190
10
10
mgjL
SM 5220D-1997
Nitrate as N
0.11
0.025
0.10
mg/L
EPA 353.2
Nitrate/Nltrlte as N
0.14
0.041
0.10
mg/L
EPA 353.2
Nitrite as N
0.030 3
0.017
0.10
mg/L
EPA 353.2
Phosphorus
0.16
0.025
0.10
mg/L
EPA 365.4
Total Kjeldahl Nitrogen
6.7
0.26
0.48
mg/L
EPA 351.2
Total Suspended Solids
17
17
17
mg/L
SM 254OD-1997
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 3 of 10

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ANALYTICAL RESULTS
Description: Outfall - 1 Lab Sample ID:CZ01509-01 Received: 04/13/16 07:25
Matrix: Surface Water Sampled:04/12/16 09:00 Work Order: CZ01509
Project: Stormwater Testing Sampled By:Joe Ladd
Classical Chemistry Parameters
^ - &WO ca y c&VW anadyte JAC 5vr1
AnabEW [CAS Numbed Resu
Bala ]]niu
12E HK EQL
fi b
Hetggd
Analyzed
ft Notes
Biochemical Oxygen Demand^
3.6
mg/L
1 2.0 2.0
6D13035
SM S21OB-2001
04/13/16 14:36
JOC
Chemical oxygen DemandA
14
mg/L
1 10 t0
6DZ1017
SM 522OD-1997
04/21/16 18:20
]OC
Nitrate as N [34797-55-8]^
0.90
mg/L
1 0.025 0.10
6D22011
EPA 353.2
04/22/16 09:11
JU
Nitrata/Nitrlte as NA
0.93
mg/L
1 0.041 0.10
6D21002
EPA 353.2
04/21/16 11:39
JU
Nitrite as N [14797-65-0]^
0.030
J mg/L
1 0.017 0.10
6D13040
EPA 353.2
04/13/16 16:21
JU
Phosphorus[7723-14-0]^
0.18
mg/L
1 0.025 0.10
61)16004
EPA 365.4
04/19/16 10:29
JU
Total Kjeldahl Nitrogen^
0.99
mg/L
1 0.26 0.48
61)16002
EPA 351.2
04/19/16 08:27
JLI
Total Suspended Solhls^
15
mg/L
2 5.0 5.0
61)16002
SM 254OD-1997
04/18/16 09:19
MMR
Description: Outfall - 2
Lab Sample ID:CZ01509-02
Received: 04/13/16 07:25
Matrix: Surface Water
Sampled:04/12/16 09:35
Work Order. CZ01509
Project: Stormwater Testing
Sampled By:30e Ladd
Classical Chemistry Parameters
A - EACO Cary -nWkd a x*M JAC 5911
Results
1la9 units
PE
H L
EQL
ftuh
ti
Analned
Bu Notes
Biochemical Oxygen Demand-
>73
mg/L
1
2.0
2.0
6D13035
SM 52108-2001
04/13/16 14:36
30C B-02
Chemical Oxygen Demand^
190
mg/L
1
10
LD
6D21017
SM 522OD-1997
04/21/16 18:20
10C
Nitrate as N [14797-55-B]^
0.11
mg/L
1
0.025
0.10
6D22011
EPA 353.2
04/22/16 09:11
3U
Nitrate/Nitrite as NA
0.14
mg/L
1
0.041
0.10
6D21002
EPA 353.2
04/21/16 11:43
JU
Nitrite as N [14797-65-0]^
0.030
J mg/L
1
0.017
0.10
6D13D40
EPA 353.2
04/13/16 16:24
JU
Phosphorus [7723-14-0]^
0.16
mg/L
1
0.025
0.10
61)16004
EPA 365.4
04/19/16 10:32
JU
Total Kjoldahl Nitrogen^
6.7
mg/L
1
0.26
0.48
61)16002
EPA 351.2
04/19/16 08:31
JLI
Total Suspended Solids^
17
mg/L
6.67
17
17
61)14005
SM 254OD-1097
04/14/16 13:00
MMR
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 4 of 10

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
fate* 6013035 - NO PREP
Blank (61)13035-BLK3)
Prepared & Analyzed: 04/13/2016 14:36
Spike Source %REC
RPD
Ana h[ta
Result
Elas
241
units
Level Resu %REC Limim RPO
Limit notes
Biochemical Oxygen Demand
2.0
U
2.0
mg/L
LCS (6D13035-851)
Prepared & Analyzed: 04/13/2016 14:36
Spike Source %REC
RPD
-Analwto
Result
Elan
P"
Units
Level Raul %REC Limits RPD
Limit Notes
Biochemical Oxygen Demand
210
2.0
mg/L
198 108 BS-115
Duplicate (6D13035-DUPE)
Prepared & Analyzed: 04/13/2016 14:36
Source: CZ01509-01
Spike Source %REC
RPD
Analvts
Result
Elan
PDI,
units
Level Result %REC Llmita RPD
Llmlt (des
Biochemical Oxygen Demand
3.6
2.0
mg/L
3.6 0.4
30
feet* 60.93040 - NO PREP
Blank (6D13040-BLKi)
Prepared: 04/13/2016 14:29 Analyzed: 04/13/2016 16:16
Spike Source %REC
RPD
Ana iYtp
Result
Etas
M
llnit8
Level Result %REC Limits RPD
Limit Notes
Nitrite as N
0.017
U
0.10
mg/L
LCS (6D13040-B51)
Prepared: 04/13/2016 14:29 Analyzed: 04/13/2016 15:48
Spike Source %REC
RPD
Ana hdo
Result
Eft
ML
Units
Level RS51iit %REC Limlta RPD
Limit notes
Nitrite as N
0.99
0.10
mg/L
1.00 99 90-110
Matrix Spike (6D33040-MS1)
Prepared: 04/13/2016 14:29 Analyzed: 04/13/2016 16:17
Source: CZ01509-01
Spike Source %REC
RPD
AnaiYte
Result
Elas
RQL
!units
Level Result %REC Limps RPD
Limit Notes
Nitrite as N
0.96
0.10
mg/L
1,00 0,030 93 90-110
Matrix Spike (6D33040-MS2)
Prepared: 04/13/2016 14:29 Analyzed: 0Q13/2016 16:25
Source: CZ01S09-02
Spike Source %REC
RPD
ADaly
Result
Elan
P9L
Urns
Level get %REC Limp& RPD
Limit Notes
Nitrite as N
0.95
0.10
mg/L
1.00 0.030 92 90-110
Matrix Spike Dup (6D33040-MSDi)
Prepared: 04/13/2016 14:29 Analyzed: 04/13/2016 16:22
Source: CZ01509-01
Spike Source %REC
RPD
Analy
Result
Elan
PQL
units
Level Result %REC Limps RPD
Limit Notes
Nitrite a5 N
0.98
0.10
mg/L
1,00 0.030 95 90.110 1
10
fatrh 6014005 - NO PREP
Blank (6D14005-BLK1) Prepared & Analyzed: 04/14/2016 13:04
Spike Source %REC RPD
Ananda Result Elio PQL Units Level Result %REC Llmlts RPD Limit Notes
Total Suspended Solids 2.5 U 2.5 mg/L
FINAL This report relates only to the sample as receK" by the laboratory, and may only be reproduced In full. Page 5 Of 10

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
1118fich 6D14005 - NO PREP - Condnifed
LCS (6014005-BS1)
Prepared & Analyzed: 04/14/2016 13:00
Spike Source %REC
RPD
Anallrte
Result
Flag
El)1
MOM
Level b51l1t %REC Limits RPD
LM Notes
Total Suspended Solids
91
2.5
mg/L
100 91 80.120
Duplicate (6D14005-DUPl)
Prepared & Analyzed: 04/14/2016 13:00
Source: CZ02408-01
Spike Source %REC
RPD
Arta hde
Result
flea
R"
Units
Level Result %REC Limits RPD
Limit Notes
Total Suspended Solids
770
170
mg/L
500 43
20 QM-12
Duplicate (6D34005-DUP2)
Prepared & Analyzed: 04/14/2016 13:00
Source: CZ02434-01
Spike Source %REC
RPD
Ana!>de
Result
flab
ML
Sinus
Level Result %REC LIM& RPD
Limit Notes_
Total Suspended Solids
220
100
mg/L
270 18
20
Raft* 6D16002 - Some
Blank (6D15002-BLKI)
Prepared: 04/16/2016 11:30 Analyzed: 04/19/2016 08:20
Spike Source %REC
RPD
Anah[te
Result
Flag
E41
Lnita
Level Result %REC Limits RPD
Limit Notes
Total Kjeldahl Nitrogen
0.26
U
0.48
mg/L
LCS (6016002-BSI)
Prepared: 04/16/2016 11:30 Analyzed: 04/19/2016 08:22
Spike Source %REC
RPD
Analytic
Result
Flag
ROL
Unita
Level Result %REC Limits RPD
Llmlt Notes
Total Kjeldahl Nitrogen
13
0.48
mg/L
12.0 105 90-110
Matrix Spike (6D16002-MS1)
Prepared: 04/16/2016 11:30 Analyzed: 04/19/2016 08:25
Source: CZ01509-01
Spike Source %REC
RPD
AnallLte
Result
Flag
E01
Unita
Level Result %REC Limits RPD
Limit Notes
Total Kjeldahl Nitrogen
5.9
0.48
mg/L
4.80 0.99 103 90-110
Matrix Spike (6D16002-MS2)
Prepared: 04/16/2016 11:30 Analyzed: 04/19/2016 08:33
Source: CZ01509-02
Spike Source %REC
RPD
Anal 1[te
Result
flau
$4L
Units
Level R" %REC JjMlU RPD
Lbh Notes
Total Kjeldahl Nitrogen
11
0.48
mg/L
4.80 6.7 99 90.110
Matrix Spike Dup (6D16002-MSD1)
Prepared: 04/16/2016 11:30 Analyzed; 04/19/2016 08:29
Source: CZ01S09-01
Spike Source %REC
RPD
Ana hde
Result
Flag
EDL
units
Level Resul %REC Limits RPD
Limit Notes
Total Kjeldahl Nitrogen
5.8
0.48
mg/L
4.80 0.99 too 90.110 3
10
Batch 6DI6004 - Same
Blank (6D36004-BLK1) Prepared: 04/16/2016 11:30 Analyzed: 04/19/2016 10:24
Spike Source %REC RPD
Anands Result flag E41 Unita Level Result %REC Limit RPD Limit Notes
Phosphorus 0.025 U 0.10 mg/L
FINAL This report mates only to the sample as reoeived by the laboralnry, and may only be reproduced in ruil. Page 6 of 10

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Qualitq Control
Batch 6D16OO4 - Some - Condwed
LCS (6DIS004-BSI) Prepared: 04/16/2016 11:30 Analyzed: 04/19/2016 10:26
Spike Source %REC
RPD
Ana hdm Result
Eli= Pal
Unite
Level ResYll %REC Limits RPD
Lb= Notes
Phosphorus 1.5
0.10
mg/L
1.60 95 80-120
Matrix Spike (61316004-MSI)
Prepared: 04/16/2016 11:30 Analyzed: 04/19/2016 10:27
Source: C201509-01
Spike Source %REC
RPD
AnaResult
Fla4 ML
Units
Level Result %REC Limits RPD
LI01lt Rotes
Phosphorus 0.80
0.10
mg/L
0.640 0.18 98 BO.120
Matrix Spike Dup (6016004-MS01)
Prepared: 04/16/2016 11:30 Analyzed: 04/19/2016 10:31
Source:CZ01509-01
Spike Source %REC
RPD
Analvte Result
Flan EQL
Unite
Level Resin %REC limits RPD
a = Motes
Phosphorus 0181
0.10
mg/L
0.640 0.18 99 80-120 0.6
25
Batch 6D18OO2 - NO PREP
Blank (6D18002-BLKi) Prepared & Analyzed: 04/18/2016 09:19
Spike Source %REC RPD
ADah[te Result flim E41 Units Level Result %REC LIB RPD Llml= Notes
Total Suspended Solids 2.5 U 2.5 mg/L
LCS (61)18002-01) Prepared & Analyzed: 04/18/2016 09:19
Spike Source %REC
RPD
Ana hda
Result ELU E41
Unib
Level Result %REC NDtlta
RPD
Limit Notes
Total Suspended Solids
90 2.5
mg/L
100 90 80-120
Duplicate (6D38002-DUP3)
Prepared & Analyzed: 04/18/2016 09:19
Source: CZ02441-01
Spike Source %REC
RPD
Anal lde
Result Flan M
Units
Level Result %REC 6110lts
RPD
Llmlt Notes
Total Suspended Solids
250 50
mg/L
230
9
20
Duplicate (6D18002-DUP2)
Prepared & Analyzed: 04/18/2016 09:19
Source: CZ02444-01
Spike Source %REC
RPD
Ana hlta
Result lieu EQL
units
Level Result %REC limits
RPD
LIM Notes
TotalSuspended Solids
300 5o
mg/L
270
9
20
Batch 6D21OO2 - NO PREP
Blank (6D21002-6LKi) Prepared: 04/21/2016 07:46 Analyzed: 04/21/2016 11:35
Spike Source %REC
RPD
Anahftls
Result Rae PAL
Units
Level Resu %REC Limits RPD
limit Notes
Nltrate/Nltrite as N
0.041 U 0.t0
mg/L
LCS (6D21002-BSI)
Prepared: 04/21/2016 07:46 Analyzed: 04/21/2016 11:28
Spike Source %REC
RPD
Anal lfts
Result FLU MI,
bits
Level Result %REC Limits RPD
limit Notes
Nitrate/Ntrite as N
1.2 0.10
mg/L
1.25 99 90.110
FINAL
This report (dates only to the sample as received by the laboramry, and may only be reproduced In full.
Page 7 of LO

www.encolabs.com
QUALM CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batas 6D21001- NO PREP - Continued
Matrix Spike (6D21002-MS1)
Prepared: 04/21/2016 07:46 Analyzed: 04/21/2016 11:37
Source:CZ01509-01
Spike Source %REC
RPD
Anahtffi
Result Hag
EOL
Units
Level get %REC Limits RPD
l,jayt l 85
Nitrate/Nltrite as N
1.4
0.10
mg/L
0.513 0.93 88 90.110
QM-07
Matrix Spike (6D21002-M52)
Prepared: 04/21/2016 07:46 Analyzed: 04/21/2016 11:46
Source: CZ01509-02
Spike Source %REC
RPD
Anil
Result Hag
E4L
unita
Level Resu %REC Limits RPD
Limit Motes
Nitrate/Nitrite as N
0.65
0.10
mg/L
0,513 0.14 99 90-110
Matrix Spike Dup (6D21002-MSD1)
Prepared: 04/21/2016 07A6 Analyzed: 04/21/2016 11:41
Source. CZ01309-01
Spike Source %REC
RPD
.Anal YtA
Result Flag
ROL
units
Level get %REC Limits RPD
Llmt Notes
Nitrate/Nltrlbe as N
1.4
0.10
mg/L
0.513 0.93 102 90-110 5
10
Batch OD21017 - Same
Blank (61321017-13LK1)
Prepared: 04/21/2016 11:57 Analyzed: 04/21/2016 18:20
Spike Source %REC RPD
Ana hdrs Result MCI M units Level gesul %REC Limits RPD Limit Notes
Chemical Oxygen Demand 10 U 10 mg/L
LCS (BD21017-BSI) Prepared: D4/21/2016 11:57 Analyzed: 04/21/2016 18:20
Spike Source %REC
RPD
Anahltn Result
Hag EOL
!!nits
Level gesult %REC Llmitea RPD
Llmlt Notes
Chemical Oxygen Demand 470
10
mg/L
500 95 90-110
Matrix Spike (6D21017-MS1)
Prepared: 04/21/2016 11:57 Analyzed: 04/21/2016 18:20
Source: CZ00875-01
Spike Source %REC
RPD
AnaResult
Flag QOL
unitil
Level gesu)t %REC LEmlts RPD
Limit Notes_
Chemical Oxygen Demand 920
10
mg/L
526 440 92 90-110
Matrix Spike Dup (6D21017-MSD1)
Prepared: 04/21/2016 11:57 Analyzed: 04/21/2016 18:20
Source: CZ00875-01
Ananda
Chemical Oxygen Demand
Spike Source %REC
Result flag P-QL units Level &ME %REC Limits RPD
920 10 mg/L 526 440 91 90.110 0.7
RPD
Limit Notes
10
FINAL This report relates only to the sample as recelved by the laboratory, and may only be reproduced In full. Pape 8 of 10

www.encolabs.com
FLAGS/ NOTES AND DEFINITIONS
B The analyte was detected in the associated method blank.
D The sample was analyzed at dilution.
] The reported value is between the laboratory method detection limit (MDQ and the laboratory method
reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable.
U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
E The concentration Indicated for this analyte is an estimated value above the calibration range of the
instrument. This value is considered an estimate.
MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQQ and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution
factor, and, in the case of soil samples, moisture content.
N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater
confidence) to make a "tentative identification".
Greater than 25% concentration difference was observed between the primary and secondary GC column.
The lower concentration is reported,
B-02 The sample dilutions set up for the analysis failed to meet the criteria of a residual dissolved
oxygen of at least 1 mg/I. Therefore the reported result is an estimated value only.
QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was
accepted based on acceptable LCS recovery.
QM-12 Precision between duplicate samples was outside acceptance limits.
FINAL This resort relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 9 of 10

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Page 1

4
Date: May 2, 2016
Novozymes, NA Inc.
77 Perry's Chapel Church Rd.
Franklinton, N.C. 27525
NCDEQ Division Of Water Quality
1617 Mail Service Center Raleigh, N.C. 27699-1617
Attn: Division Of Water Quality
Storm Water Sampling, NPDES Permit No.
Dear Sir/Madam
Dear, Sir/Madam
novozY mes
Rethink Tomorrow
UN 16 2016
CENTRAL FILES F
DWR SECTION
During review of storm water sampling results, it was observed that there was an exceeded benchmark in
Biological Oxygen Demand (BOD), and Chemical Oxygen Demand (COD) from our Outfall 2 location.
Upon immediate investigation, per Tier One requirements, it was discovered that although during sample
event no signs of potential issues were present, the area approximately 20 yards from where samples
collected containers of product were rinsed prior to being disposed. There are drains specifically used for
rinsing purposes, however, during clean-up activities the area was hosed down and some product may have
been pushed outside drain borders. We have concluded that since this rinsing took place the day before rain
event with which samples were taken, it could have caused the higher than normal BOD, and COD readings.
We have taken measures to ensure this process is more carefully performed especially during cleaning of
area post work.
Continued monitoring by Environmental Services Department will take place in order to prevent future
exceeded benchmarks in Biological Oxygen Demand (BOD), and Chemical Oxygen Demand (COD)
from Outfall 2.
Kind ds,
Joe L d
Environmental Compliance Coordinator
Environmental Services

m

NPDES PERMIT NO. NCS000115
FACILITY NAME Novozymes, NA Inc.
OPERATOR IN RESPONSIBLE CHARGE (ORC)
EFFLUENT
DISCHARGE NO. 1
CLASS
NIA
CERTIFIED LABORATORIES (1) Enco (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES : N/A
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY
RALEIGH. INC 27699-1617 KNOWLEDGE.
MONTH April ^ YEAR 2016
COUNTY: Franklin
PHONE [phone]
Joe Ladd
Lim
1�mmlllmlmuml
•

s
Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
(including weekly averages, if applicable) Fx_1
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements F1
Noncompliant
The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially
threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the
permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time
the permittee becomes aware of the circumstances.
If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for
improvements to be made as required by Part II.E.b of the NPDES permit.
"I certity, unaer penalty of law, that this document ants all attachments were prepared uncer my direction or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly
responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,
accurate, and complete. 1 am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Randy Green
Permittee (Please print or type) _-
r'
Sig re of P tttee*** pate
(Required u s submitted electronically)
Permittee Address Phone Number e-mail address Permit Expiration Date
ADDITIONAL CERTIFIED LABORATORIES
Certified Laboratory (2) Certification No.
Certified Laboratory (3) Certification No.
Certified Laboratory (4)
Certified Laboratory (5)
PARAMETER CODES
Certification No.
Certification No.
Parameter Code assistance may be obtained by calling the NPDES Unit at [phone] or by visiting the Surface
Water Protection Section's web site at h2o.ennstate.nc.us/ s and linking to the unit's information pages.
Use only units of measurement designated in the reporting facility's NPDES permit for reporting data.
* No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be
entered for all of the parameters on the DMR for the entire monitoring period.
** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204.
*** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on
file with the state per 15A NCAC 2B .0506(b)(2)(D).

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EFFLUENT
NPDES PERMIT NO. NCS000115 DISCHARGE NO. 2
FACILITY NAME NOVOZymeS, NA Inc. CLASS
OPERATOR IN RESPONSIBLE CHARGE (ORC) N!A
CERTIFIED LABORATORIES (1) Enco
CHECK BOX IF ORC HAS CHANGED PERSON(Sj COLLECTING SAMPLES
Mail ORIGINAL and ONE COPY to:
(2)
MONTH April YEAR 2016
COUNTY: Franklin
PHONE [phone]
Joe Ladd
ATTN: CENTRAL FILES x NIA
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY
RALEIGH, NC 27699-1617 KNOWLEDGE.
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Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
(including weekly averages, if applicable)
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements [K]
Noncompliant
The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially
threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the
permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time
the permittee becomes aware of the circumstances.
If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for
improvements to be made as required by Part II.E.b of the NPDES permit.
"I certtty, under penalty of taw, that this nocument and all attachments were prepares unuer my airection or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly
responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Randy Green
Permittee (Please print or type)
Sign re of P ittee*** Date
(Required un)Ks submitted electronically)
Permittee Address Phone Number a -mail address Permit Expiration Date
ADDITIONAL CERTIFIED LABORATORIES
Certified Laboratory (2)
Certification No.
Certified Laboratory (3)
Certification No.
Certified Laboratory (4)
Certification No.
Certified Laboratory (5)
Certification No.
PARAMETER CODES
Parameter Code assistance may be obtained by calling the NPDES Unit at [phone] or by visiting the Surface
Water Protection Section's web site at h2o.enr.state.nc.us/was and linking to the unit's information pages.
Use only units of measurement designated in the reporting facility's NPDES permit for reporting data.
* No Flaw/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be
entered for all of the parameters on the DMR for the entire monitoring period.
** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204.
*** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on
file with the state per 15A NCAC 213 .0506(b)(2)(D).

r
` Date: May 0,2015
Novozymes, NA Inc.
77 Perry's Chapel Church Rd.
Franklinton, N.C. 27525
NCDENR Division Of Water Quality
1617 Mail Service Center Raleigh, N.C. 76 61
Attn: Division Of Water Quality
Storm Water Sampling, NPDES Permit No. NCS000115
Dear Sir/Madam
mes novoz �
Y
Rethink Tomorrow
Per our Tier Two requirements, regarding the exceeded benchmark in Total Suspended Solids, (TSS), our
implementation of a monthly monitoring in area of concern, "Outfall 1", beginning in January have resulted
in "No Flow" for the month of April.
We therefore were unable to collect a sample for this month. We plan to continue to diligently with our
monthly monitoring for the parameter of TSS until we obtain three consecutive sample results within the
benchmark range.
Kind Regard ,
Joe Lad
Environmental Compliance Coordinator
Environmental Services
RECEIVED
juiik4, 9 3 2015
DENR-LAND QUALITY
STORMWATER PERMITTING
I

EFFLUENT
NPDES PERMIT NO. NCS000115 DISCHARGE NO. 1
FACILITY NAME Novozymes, NA Inc. CLASS
OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA
CERTIFIED LABORATORIES (1) EnCo (2)
CHECK Box IF ORC HAS CHANGED 0E] PERSON(S) COLLECTING SAMPLES
Mail ORIGINAL and ONE COPY to:
MONTH August YEAR 2015
COUNTY: Franklin
PHONE [phone]
Joe Ladd
ATTN: CENTRAL FILES K NIA
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
1617 MAIL SERVICE CENTER
RALEIGH, INC 27699-1617
BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY
KNOWLEDGE.
■
i
m
loom
DWQ Form MR-i (11/04)

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
(including weekly averages, if applicable)
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially
threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the
permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the
permittee becomes aware of the circumstances.
If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for
improvements to be made as required by Part II.E.6 of the NPDES permit.
"I certity, under penalty of law, that this document and all attachments were prepared under my direction or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly
responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Randv Green
Permittee (Please print or type)
Sig ure of Pe ttee*** Date
(Required unless submitted electronically)
Permiuce Address Phone Number e-mail address Permit Expiration Date
Certified Laboratory (2)
Certified Laboratory (3)
ADDITIONAL CERTIFIED LABORATORIES
Certification No.
Certification No.
Certified Laboratory (4) Certification No.
Certified Laboratory (5) Certification No.
PARAMETER CODES
Parameter Code assistance may be obtained by calling the NPDES Unit at [phone] or by visiting the Surface
Water Protection Section's web site at h2o.enr.state.nc.uslwas and linking to the unit's information pages.
Use only units of measurement designated in the reporting facility's NPDES permit for reporting data.
No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be
entered for all of the parameters on the DMR for the entire monitoring period.
** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204.
Signature of Permittee: If signed by other than the permitter, then the delegation of the signatory authority must be on
file with the state per 15A NCAC 2B .0506(b)(2)(D).
Page 2

EFFLUENT
NPOES PERMIT NO. NCS000115 DISCHARGE NO. 2
FACILITY NAME Novozymes, NA Inc. CLASS
OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA
CERTIFIED LABORATORIES (1) Enco (2)
CHECK BOX IF ORC HAS CHANGED Q© PERSON(S) COLLECTING SAMPLES
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES x NIA
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY
RALEIGH, NC 27699-1617 KNOWLEDGE.
MONTH August YEAR 2015
COUNTY: Franklin
PHONE [phone]
Joe Ladd
DWQ Form MR-1 (11/04)

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
(including weekly averages, if applicable)
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially
threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the
permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the
permittee becomes aware of the circumstances.
If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for
improvements to be made as required by Part II.E.6 of the NPDES permit.
"I certity, under penalty of law, that this document and all attachments were prepared under my direction or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly
responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Randy Green
Permittee (Please print or type)
S - 2O/ S
Signafw#V Permi a *** Date
(Required unless submitted electronically)
Pennittee Address Phone Number e-mail address Permit Expiration Date
Certified Laboratory (2)
ADDITIONAL CERTIFIED LABORATORIES
Certification No.
Certified Laboratory (3) Certification No.
Certified Laboratory (4)
Certified Laboratory (5)
PARAMETER CODES
Certification No.
Certification No.
Parameter Code assistance may be obtained by calling the NPDES Unit at [phone] or by visiting the Surface
Water Protection Section's web site at h2o.enr.state.nc.uslwas and linking to the unit's information pages.
Use only units of measurement designated in the reporting facility's NPDES permit for reporting data.
* No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be
entered for all of the parameters on the DMR for the entire monitoring period.
** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .020C
**" Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on
file with the state per 15A NCAC 213.0506(b)(2)(D).
Page 2

r
ENCO Laboratories
Accurate. Timely. Responsive. Innovative.
102-A Woodwinds Industrial Court
Cary NC, 27311
Phone: [phone] FAX: [phone]
Thursday, September 17, 2015
Novozymes North America (NO008)
Attn: Joe Ladd
77 Perry Chapel Church Road
Franklinton, NC 27525
RE: Laboratory Results for
Project Number: [nonel Project Name/Desc: 5tormwater Testing
ENCO Workorder(s): C416992
Dear Joe Ladd,
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Monday, August 31, 2015.
Unless otherwise noted in an attached project narrative, all samples were received In
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained In this report are in compliance with NELAC standards, except
as noted In the project narrative. This report shall not be reproduced except In full, without
the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further Information, please do not hesitate to contact me.
Sincerely,
Chuck Smith
Project Manager
Enclosure(s)
FIAIX This report elates only to the sample as received by the laboratory, and may only be reproduced In M. Papa 1 of 11

rwwv encolabe.com
SAMPLE SUMMARY/LABORATORY CHRONICLE
Client ID: OLM11.1
lab I0: C416992-01
Sampled: 08/31/1S 09:40 Reaelved: 08/31/15 16:30
ParameterHdd
EPA 351.2
DatelTlmer[a]
09/28/15
Prep Date/Tlma(a]
09/11/15
13:22
09/15/15 10:02
EPA 353.2
09/02/15
09:40
09/01/15
14:11
09/01/15 16:01
EPA 353.2
09/28/15
09/11/15
08:23
09/11/15 12:49
EPA 353.2
05/26/18
09/16/15
16:21
09/16/15 16:21
EPA 365.4
09/28/15
09/11/15
09:28
09/15/15 12:22
SM 254OD-1997
09/07/15
09/02/15
17:10
09/02/15 17:10
SM 521OB-2001
09/02/15
09:40
09/02/15
07:27
09/02/15 07:27
SM 5220D-1997
09/28/15
09/01/15
16:38
09/02/15 15:00
Ghent IDt Outtall- 2
Lab rD: C416992-02
Sampled: 08/31/15 09:20 ReoNved: 08/31/13 1.6:30
Pamowder
EPA 351.2
Hold Date/Tlme(a]
09/28/15
Prep Date/Tlme[a]
09/03/15
10:03
Lei
09/08/15 11:39
EPA 353.2
09/02/15
09:20
09/01/15
14:11
09/01/15 16:03
EPA 353.2
09/28/15
09/11/15
08:23
09/11/15 12:54
EPA 353.2
05/26/18
09/16/15
16:21
09/16/15 16:21
EPA 365.4
09/28/15
09/03/15
10:03
09/08/15 13:04
SM 254OD-1997
09/07/15
09/02/15
17:10
09/02/15 17:10
SM 52100.2001
09/02/15
09:20
09/02/15
07:27
09/02/15 07:27
SM 522OD-1997
09/28/15
09/01/15
16:38
09/07115 15:00
FW& This report relates only to the sample as reoCved by the lebore[ory, and may only be reproduced In fuH. Pepe 2 of 11

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SAMPLE DETECTION SUMMARY
Client IDr OutfaU -1
Lab ID:
C416992-0i
AnRbu
flm&
an
M"
Pal.
lhtb
Mf d H91112
BbchemkzJ Oxygen Demand
2.8
2.0
2.0
mg/L
SM 52108-2001
Chemical Oxygen Demand
25
10
10
mg/L
SM 522OD-1997
Nitrate as N
0.87
0.025
0.10
mg/L
EPA 353.2
Nitrate/Nitrite as N
0,87
]
0.41
1.0
mg/L
EPA 353.2 R-01
Phosphorus
0.35
0,025
0.10
mg/L
EPA 365.4
Total Kjeldahl Nitrogen
0.84
0.26
0.48
mg/L
EPA 351.2
Total Suspended Solids
39
7.1
7.1
mg/L
SM 254OD-1997
Client IO: OutfaU - 2
Lab IO:
C416992-02
ADeba
Baum
am
HU
RU
Unm
Method Not"
Blodremkal Oxygen Demand
5.3
2.0
2.0
mg/L
SM 52108-2001
Chemical Oxygen Demand
49
10
10
mg/L
SM 522OD-1997
Nitrate as N
0.38
0.025
0.10
mg/L
EPA 353.2
Nitrate/Nitrite as N
0.41
J
0.41
1.0
mg/L
EPA 353.2 R-01
Nitrite as N
0.026
]
0.017
0.10
mg/L
EPA 353.2
Phosphorus
0.15
0.025
0.10
mg/L
EPA 365.4
Total i(jeldahl Nitrogen
0.72
0.26
0.48
mg/L
EPA 351.2
Total Suspended Solids
93
20
20
mg/L
SM 254OD-1997
FINAL This report Males only to the sample as M&ied by the laboratory, and may only be reproduced in full. Page 3 or it

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ANALYTICAL RESULTS
Description: Outfall - i Lab Sample ID: C416992-01 Received: 08/31/15 16:30
Matrix: Surface water Sampled:08/31/15 09:40 Work Order: C416992
Project: Stormwater Testing Sampled By:Joe Ladd
Classical Chemistry Parameters
^-61C0Cary o<&W[AC 5111
Anahrts [CAS Numllerl Room
an
11010
12E
HM
P91
AlUb
1191111w
AO bud
f1
AdU
Biochemical Oxygen Demand^
2.8
mg/L
1
2.0
2.0
5102001
SM 52105-2001
09/02/15 07:27
30C
Chemical Oxygen Demand^
25
nng/L
1
10
10
5101011
SM 5220D-1997
09/07J15 15:00
30C
Nitrate as N [14797-88-8]^
0.87
mg/L
1
0.025
0.10
5116038
EPA 353.2
09/16/15 16:21
MILS
Nhtrata/Nit"te as N^
0.87
J
mg/L
10
0.41
1.0
SID9002
EPA 353.2
O9/11115 12:49
JL]
R-01
Nttrlhe as N [14797-15-0]^
0.017
U
mg/L
1
0.017
0.10
5101025
EPA 353.2
D9101/15 16:01
JLJ
Phosphorus [7723-14-0]^
0.35
mg/L
1
0.025
0.10
5111009
EPA 365.4
09/15/15 12:22
JLJ
Tots) KJddahl Nitrogen^
0.84
mg/L
1
0.26
0.48
5111007
EPA 351.2
09/15/15 10:02
JU
Total Suspended Solids^
39
mg/L
2.86
7.1
7.1
5102004
SM 2WD-1997
09/02/15 17:10
MMR
Description: Outfall - 2
Lab Sample ID:C416992-02
Recehred, 08/31/15 15:30
Matrix: Surface Water
Sampled:08/31/15 09:20
Work Order: C416992
Project: Storrnwater Testing
Sampled By:Joe Ladd
Classical Chemistry Parameters
^ - EKV Quy mtMY arrAoyta [AC 5YJJ
Balm
no
1lnits
RE
Hu
ML
90tsit
Kum
ADBhf11111d
a
now
Biochemical Oxygen Demand^
B.3
mg/L
1
2.0
2.0
5102001
SM 52105-2001
09/02/15 07:27
30C
Chemical Oxygen Demand^
40
mg/L
1
10
10
5101011
SM 5220D-1997
09/02/15 15:00
30C
Nitrate as N [14797-5"]^
0.38
mg/L
1
0.025
0.10
5116038
EPA 353.2
09/16/15 16:21
MKS
Nkmto/Nkdte as NA
0.41
J
mg/L
10
0.41
1.0
5109002
EPA 353.2
09/11/15 12:54
JU
R-01
Nitrite as N [14797-63-0]A
O.026
J
mg/L
1
0.017
0.10
SI01025
EPA 353.2
09/Ol/15 16:03
JLJ
Phosphorus [7723-14-0]^
0.15
mg/L
1
0.025
0,10
5103004
EPA 365.4
09/08/15 13:04
JU
Total Kjeldahl Nitrogen-
0.72
mg/L
1
0.26
0.48
SIG3003
EPA 351.2
O9/08/15 11:39
JU
Total Sumpndad Solids^
93
mg/L
8
20
20
5102004
SM 2540D-1997
09/02/15 17:10
MMR
6
9
FINAL This report rtlatrs only to the sample as retched by the laboratory, and may only be reproduoad in full. Page 4 of It
h
I
}

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
DR" M01011- Same
Wank (SIOL011•BLKl)
Prepared: 09/01/2015 16:38 Analyzed: 09/02/2015 15:00
Spike Source %REC
RPD
Aftalvise
Bss1iB
San
EM
delta
Leval gAUH %REC Limits RPD
Limit Motu
Chemical Oxygen Demand
10
U
10
mg/L
LCS (5I01011-BSS)
Prepared: 09/01/2015 16:38 Analyzed: 09/02/2015 15:00
Spike Source %REC
RPD
�aanda
Ba�1it
Elan
e1111
linos
Level BREY$ %REC Limil6 RPD
Limit Notm
Chemical OxyW Demand
510
10
mg/L
500 101 90-110
Matrix Spike (510101L-MSL)
Prepared: 09/01/2015 16:38 Analyzed: 09/02/2015 15:00
Source: C416992-01
Spike Source %REC
RPD
Ananda
Beiult
Elam
POL
Units
Level Baulilt %REC UMB& RPO
Limit mass
Chemical Oxygen Demand
520
10
mg/L
500 .25 98 90-110
Metrhr Spike Dup (5I01O11-MSD3)
Prepared: 09/01/2015 16:38 Analyzed: 09/02/2015 15:00
Source: C416992-01
Spike Source %REC
RPD
A3d[Ls
Be"
Hs0
POL
llalti
Laval g %REC Limit RPD
Limit
Chemical Oxygen Demand
530
10
mg/L
500 25 101 90-110 2
10
Bahl/ SI01025 - NO PREP
Btmk (5101025-Bu(l)
Prepared: 09/01/2015 14:11 Analyzed: 09101/201515:58
Spike Source %REC
RPD
Anabma
Rent
Elan
ML
Limn
Level BAUH %REC L Wk RPD
Limit Noted
Ml[s as N
0.017
U
0,10
mg/L
LCS (SI01025-BST)
Prepared: 09/01/2015 14:11 Analyzed: 09/01/2015 15:41
Spike Source %REC
RPD
Amlybo
Bawlt
Hag
MI.
Unite
Level gn ilit %REC LimM RPD
Una Wall
Nhrft as N
0.99
0.10
mg/L
1.00 99 90-110
LCS (5I01.023-02)
Prepared: 09/01/2015 14:11 Analyzed: 09/02J2015 07:58
Spike Source %REC
RPD
Aoehda
ltasnit
an
Ml.
Unitb
Level %REC Limns RPa
Limit 111,1119114111111.
NIVRe as N
0.98
0.10
M91L
1.00 98 90.110
Matrix Spike (SI01025-MS1)
Prepared: 09/01/2015 14:11 Analyzed: 09/01/2015 16:00
Source: C416992-01
Spike Source %REC
RIND
Ananda
Bawlt
Elan
e"
Y111te
Level gMggft %REC Limb RPD
Limit Notes
Nitrite as N
0.94
0.10
mg/L
1.00 0.017 U 94 90-110
Matrix Spike (5I01025-MS2)
Prepared: 09/01/2015 14:11 Analyzed: 09/02/2015 08:01
Source: C509613-01
Spike Source %REC
RIND
Anahuo
Bsn11t
Elag
P.OL
Units
Level Remit %REC LMMI RPD
Limit Notes
Nitrite as N
0.96
0.10
mg/L
1.00 0.017 U 96 90-110
Matrtx Spike Dup (SI01025-MSD1)
Prepared: 09/01/2015 14:11 Analyzed: 09/01/2015 16:02
Source: C416992-01
Spike Source %REC
RIND
l;aaht:a
RIM
an
PQL
Tinto
Level Bond %REC Limits RPD
Limit 11101b ,
FINAL
This report relates only to the sample asteed by the IaborMory, and may only be reproduced In fug.
page 5 of 11

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch SM1025 - AfO PREP - Conhrnued
Matrix Spike Dup (3101025-MSD1) Continued Prepared: 09/01/2015 14AL Anah7ed: 09/01/2015 16:02
Source: C416992-0i
Spike Source %REC RPD
Asabme Basu$ Belt P" !)Olin Loral Mauls %REC jMfta RPD LM Not"
Nitrite as N 0.93 0.10 mp/L 1.00 0.017 U 93 90.110 1 10
Saudi 5I02001- AID PREP
Blank (5I02001-BLI(1) Prepared & Analyzed: 09/02/2015 07:27
Spike Source %REC RPD
Ana hrta BM Mall ML S)llltl Level gligigft %REC jlmils RPD Llm)t Notell-
Blochemlcal Oxygen Demand 2.0 U 2.0 mp/L
LC9 (3102001-01) Prepared & AnaWW: 09/02/2015 07:27
Spike Source %REC
RPD
Reedit Bea ML
ilBIC1
Level Rm %REC LWIft RPD
Nmlt Noteff-
Biochemical Oxylpen Demand
210 2.0
mg/1-
193 100 85-115
DupW to (5I02001-DUPI.)
Prepared & Analyzed: 09/02J2015 07:27
Source: C416992-01
Spike Source %REC
RPD
AOa:IDa
Rena Elffi Pal
UnRa
Level RMM %REC LLMM RPD
Nlmlt ems.
Biochemical Oxygen Demand
2.2 2.0
ng/L
2.0 27
30
JIM* SM20M - NO PREP
Blank (3I02004-BLK3)
Prepared & AnaWW: 09/02/2015 17:10
Spike scum %REC
RPD
Allahlta
Result
Has
i'..OL
ultltt
Level Elila z %REC Llmlta
RPD
LlBtlt WMAL
Total Suspended Solids
2.S
U ,
2.5
mp/L
LCS (3I02004-BS1)
Prepared & AnaWW: 09/02/2015 17:10
Spike Source %REC
RPD
Anando
Bank
Elan
ML
unitl
Level geau %REC Limb
RPD
LIMIR Motall-
Total Suspended Solids
100
2.5
mp/L
100 100 80.120
Duplicate (5I02004-DUPl)
Prepared & Analyzed: 09/02/2015 17:10
Source: C510390-01
Spike Source %REC
RPD
Ana hda
Read
Bea
PQL
Unitl
Larval g %REC Limns
RPD
Llmlt Notes
Total Suspended Solids
220
50
m0/L
220
0.9
20
Duplixaie (SI02004-pUP2)
Prepared & Analyzed: 09/0712015 17:10
Source: C416992-02
Spike Source %REC
RPD
�Bahrte
&rite$
Halt
p41
Unit1
Level g %REC Limb
RPD
Limit Motes
Total Suspended Solids
93
20
my/L
93
0
20
Batdl 5I03M - Same
Blank (5I03003-OLKI)
Prepared: 09/03/2015 10:03 Analyzed: 09/08/2015 11:28
Spike Source %REC
KPD
ADahfSs
Basult
Elm
EEL
Liam
Level get %REC Uj U&
RPD
LWR Not"
Total IUeldehl Nltro9w
0.26
U
0.48
mp/L
FINAL
This report relates ony bo UM sample as receNed by the labDratory, end may only be reproduced In full.
Pape 6 of 11

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Als" 57030M - mama - Cbndm4ed
LCS (3103003-BSI) Prepared: 09/03/2015 10:03 Analyzed: 09/08/2015 11:30
Spike Source %REC
RPD
Anahme
BeiuR
Ellen
PRL
Uft
Level Bai& %REC Limb RPD
Limit 110M
Total Kjeldahl Nitrogen
12
0.48
mg/L
12.0 102 90-110
Matrix Spike (3103003-1451)
Prepared: 09/03/2015 10:03 Analyzed: 09/08/2015 11:32
Source: C416992-02
Spike Source %REC
RPD
Anahte
BaN N
Elm
21111.
Units
Loral BAGH %REC UMU RPD
1.111111 12111111.
Total Kjeldahl NXMM
5.6
0.48
mWL
4.80 0.72 102 90.110
Matrix Spike (3I03003-101152)
Prepared: 09/03/2015 10:03 Analyzed: 09/08/2015 11:35
Source: C509662-01
Spike Sourca %REC
RPD
Aoehma
Rana
Elm
e"
Unite
Level agel t %REC Llalits RPD
Llmlt Notes
Total Kjeldahl Narogen
73
D
2.4
mg/L
4,80 66 142 90-I10
QM-05
Metrhr Spike Dup (6I03003-MSD1)
Prepared: 09/03/2015 10:03 Analyzed: 09/08/2015 11:37
Source: C416992-02
Spike Source %REC
RPD
AnandR
BARR
EIM
Eat.
units
Level &"it %REC LlmIM RPD
Limit Notes
Total Kjeldahl Nitrogen
5.9
0.48
mg/L
4.80 0.72 107 90-110 4
10
AN&* 3Iwoof - some
Blank (3103004-BLKI)
Prepared: 09/03/2015 10:03 Analyzed: 09/08/2015 12:57
Spike Source %REC RPD
Anahma Bela t Elan EQL Units Level S481it %REC Limits RPD Limit M92CL
Phosphorus 0.025 U 0.10 mg/L
LCS (3103004-01) Prepared: 09/03/2015 10:03 Analyzed: 09/08/2015 12:59
Spike Source %REC
RPD
Anando BARR
EIM 2QL
Smite
Leval Bomb %REC Limb RPD
Limit )jows-
Phosphorus 1.5
0.10
mg/L
1.60 95 80.120
141 r Spam (5303004-10131)
Prepared: 09/03/2015 10:03 Analyzed: 09/08/2015 13:01
Source: C416992-02
Spike Source %REC
RPD
Anahma Result
Harr ML
Unite
Level BLUM %REC Limits RPD
haft not"
Phosphorus 0.77
0.10
mg/L
0.640 0.15 97 80-120
Matrix Spike Dup (9103004-MSD3)
Prepared: 09/03/2015 10:03 Analyzed: 09/08/2015 13:02
Source: C416992-02
Spike Source %REC
RPD
Ana lYta Bosun
Elea PGL
Unite
Lave] jig %REC limits RPD
Limit Nobas
Phosphorus 0.77
0.10
mg/L
0.640 0.15 97 M120 0.4
25
Ballots 5I�A02 - HO PIREP
I
Blank (6109002-SM) Prepared: 09/11/2015 08:23 Anayzed: 09/11/2015 12:45
Spike Source %REC RPD
ADahLte RMU[t Elea PQ.L Units Level %REC Limb RPD Limit Notes-
Narete/Ntbr to as N 0.041 U 0.10 mg/L
l
i
i
i
F1IrAL This report rdlates only to the sampe as rwdved *the laboratory, and may any be nepmduood in NO. Page 7 of 11
k!
f

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I QUALITY CONTROL DATA f
Parame6ato - Quality Control
Batch 5AVW2.194Q PREP - Cmdawd
I LCS (3I09002-BS3) Prepared: 09/11/2015 08:23 Analyzed: 09/11/2015 12:38
Spike Source %REC
RPD
AIlafthe
Bonk
Bea
POL
!lnh
Level gft&IB %REC UMJM RPD
Limit motw
Nltrate/Nb to as N
1.2
0.10
rnWL
1.25 1 99 90.110
Matrht $pike (3I09002-M5i)
Prepared: 09/11/2015 08:23 Analyzed: 09/11/2015 12:47
Source: C416992-01
Spike Source %AEC
RPD
�Oandap
Bend
Has
2QL
Unite
Level gM& %REC Umlta RPD
LbA Motes
NltratrJNlt ita as N
5.9
1.0
mg/L
5.00 6.87 100 90-110
Matrix Spire (5I09002-M52)
Prepared: 09/11/2015 08:23 Analyzed: 09/11/2015 12:56
Source: C416992.02
Spike Source %REC
RPD
Anahfta
RMR
flag
MI.
M1111
Level Result %REC Llmitl RPD
L(m(t jw
NftWNitrlte a8 N
5.6
1.0
mg/L
5.00 0.41 U 112 90-110
QM-05
Matrix Wks Duo (5109002-14SDI)
Prepared: 09/11/2015 08:23 Analyzed: D9/11/2015 12:52
Source: C416992-01
Spike Source %REC
RPD
Anatvto
BsMdt
fin
MI.
Lk ft
Level RtMg %REC UDgk RPD
Lba motes
NarstaiNitrlte as N
5.8
1.0
mg/L
5.00 0.87 99 90-110 0.9
10
Batch SZ1.900f - Sama
Blank (9111007-BLK1) Prepared: 09/11/2015 13:22 Analyzed: 09/15/2015 09:51
Spike source %REC RPD
Anahme Bond Biw P4L Chili Level BANg %REC MMU RPD Limit not"
Total K)eldahl Nitrogen 0.26 U 0.48 mg/L
LCS (5I31007-BS1) Prepared: 09/11/2015 13:22 Analyzed: 09/15/2015 09:53
Spike Source %REC
RPD
linandas Bl3Ml$
an ML
llnh
Leval gann %REC LIMU RPD
Limit Notew.
Tote K*dandNitrogen 12
0.48
mg/l.
12.0 102 90.110
Matrix Spike (5111007-MS1)
Prepared: 09/11/2015 13:22 Analyzed: 09/15/2015 09:55
Source: C416992-01
Spike Source %REC
RPD
ADanda R11=11
Han POL
11nu
Level BWM %REC NmBa RPD
Limit mom
Total Kleldahl Nitrogen 5.5
0.48
mg/L
4.80 0.84 97 9D-110
Matrix Spike (5I11007-MS2)
Prepared: 09/11/2015 13:22 Analyzed: 09/15/2015 09:57
Source: C503193-0IREL
Spike Source %REC
RAD
Ananda BaRR
Bea PL
Mau
Level gesil %REC Lialb RPD
Limit NOW
Toted Kjeldahl Nitrogen 6.6
0.48
mg/L
4.80 2.8 79 90.110
QM -OS
Matrix Spike DuP (5111007•MSDi)
Prepared: 09/11/2015 13:22 Analyzed: 09/15/2015 09:59
Source. C416092-01
Spike Source %REC RPD
l aahma RMR Bas P9L Chili Level gjag %REC Nmlta RP11 LlmLt dotes
Total Neldahl NI0DW 5.7 0.48 mg/L 4.80 0.84 102 90-110 4 10
Bauch 5I110M - Arm* I
1
FINAL Yhls repW relates only tD the sample as reoeMed by the laboratory, and mpy only be reproduced In fut. page 8 or 11
I

www.encolabs.com
QUALITY CONTROL DATA
tlamical Chemistry Parameters - Quality Control
Be" 'iM0" - gMnw - LMwfiiwd
s
Blank (SI11009-BL1(3)
Prepared: 09/11/2015 09:28 Analyzed: 09/15/2015 12:15
Spike Source %REC
RPD
JDanda 8e.ult Elm
POL
Units
Laval get %REC Limb RPD
Lim Notes_
phosphorus 0.025 U
0.10
mp/L
LCS (33ilo0WBS11
Prepared: 09/11/2015 09:28 Analyzed: 09/15/2015 12:17
Spike Source %REC
RPD
Ananda Result Has
Pal.
knits
Level ReM %REC UMU& RPD
Lkaft Notes
Phosphorus 1.6
0.10
mp/L
1.60 100 80-120
Matrix Spike (5I11009-11415L)
Prepared: 09/11/2015 09:28 Analyzed: 09/15/2015 12:18
Source: C416992-01
Spike Source %REC
RPD
Anna111112111111; Hao
ML
Units
Level geau %REC LWIM RPD
Phosphorus 0.90
0.10
mp/L
0.640 0.35 85 80-120
MaWx Spike Dup (5111009-114SD3)
Prepared: 09/11/2015 09:28 Analyzed: 09/15/2015 12:20
Source: C416992-01
Phosphorus
Spike Source %REC
RONK Ban ML Laid Level Resu %REC Lhn& RPO
0.89 0.10 mp/L 0.640 0.35 84 80-120 1
I
This report relates only to the sample as reodved by the laboratory, and may oniy be reproduced In full.
RPD
Nmlt NWMs.
25
Pape 9 Or 11

I www.encolaba.aom
FLAGS/NOTES AND DEFINITIONS
,
B The analyte was detected in the associated method blank.
D The sample was analyzed at dilution. 6
6
J The reported value Is between the laboratory method detection limit (MDL) and the laboratory method
reporting limit (MRQ, adjusted for actual sample preparation data and;moisture content, where applicable.
U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
l
E The concentration Indicated for this analyte is an estimated value above the calibration range of the
Instrument. This value is considered an estimate.
MRL Method Reporting Limit The MRL Is roughly equivalent to the practical quantitation limit (PQL) and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution
factor, and, in the case of soil samples, moisture content I
N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater
confidence) to make a "tentative identification".
P Grater than 25% concentration difference was observed between the primary and secondary GC column.
The lower concentration is reported. r
QM-05 The splice recovery was outside acceptance limits for the MS and/or MSD due to matrix
interference. The LCS and/or LCSD were within acceptance limits showing that the laboratory is
In control and the data is acceptable. ,
R-01 The Reporting Limit for this analyte has been raised to account for matrix interference.
I
I
E�i
�4
4�
I
FINAL This fePon rdabes only to the sample as received by the laboratory, and mey only be reproduced In Nil. Page 10 of 11

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Page 1: df 1

I%
EFFLUENT
NPDES PERMIT NO. NCS000115 DISCHARGE NO. 1
FACILITY NAME NOV02ymeS, NA Inc. CLASS
OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA
CERTIFIED LABORATORIES (1) Enco (2)
CHECK BOX IF ORC HAS CHANGED ©0 PERSON(S) COLLECTING SAMPLES
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES x NIA
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY
RALEIGH, NC 27699-1617 KNOWLEDGE.
MONTH July YEAR 6&= 2015
COUNTY: Franklin
PHONE [phone]
Joe Ladd
MIN
DWQ Form MR -I (1 1/04)

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
(including weekly averages, if applicable)
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially
threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the
permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the
permittee becomes aware of the circumstances.
If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for
improvements to be made as required by Part II.E.6 of the NPDES permit.
"I certtty, under penalty of law, that this document and all attachments were prepared under my direction or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly
responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Randy Green
Permittee (Please print or type)
_24t,99-f - S�-((? 201_65,
Signi!0 of Perini a*** Date
(Required unless mitted electronically)
Permittee Address Phone Number a -mail address Permit Expiration Date
Certified Laboratory (2)
ADDITIONAL CERTIFIED LABORATORIES
Certification No.
Certified Laboratory (3) Certification No.
Certified Laboratory (4) Certification No.
Certified Laboratory (5) Certification No.
PARAMETER CODES
Parameter Code assistance may be obtained by calling the NPDES Unit at [phone] or by visiting the Surface
Water Protection Section's web site at h2o.enr.state.ne.us/wcgs and linking to the unit's information pages.
Use only units of measurement designated in the reporting facility's NPI)ES permit for reporting data.
* No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be
entered for all of the parameters on the DMR for the entire monitoring period.
** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204.
*** Signature of Permittee: if signed by other than the permittee, then the delegation of the signatory authority must be on
file with the state per 15A NCAC 213.0506(b)(2)(D).
Page 2

Date: August 12, 2015
Novozymes, NA Inc.
77 Perry's Chapel Church Rd.
Franklinton, N.C. 27525
RECEIVED
NCDENR Division Of Water Quality AUG 19 2015
1617 Mail Service Center Raleigh, N.C. 27699-1617 CENTRAL FILES
Attn: Division Of Water Quality DWR SECTION
Storm Water Sampling, NPDES Permit No. NCS000115
Dear Sir/Madam
novozY mese
Rethink Tomorrow
Per our Tier Two requirements, regarding the exceeded benchmark in Total Suspended Solids, (TSS), our
implementation of a monthly monitoring in area of concern, "Outfall I", beginning in January has resulted
in three consecutive sample results that are within required benchmark range.
Test results from July mark the third consecutive month that our TSS readings have been within benchmark
range. With July's testing complete, and compliance established, this will conclude our monthly monitoring
for Total Suspended Solids.
We will continue our second of two required Storm Water sampling events prior to the end of the calendar
year.
Kind Regards,
Joe Ladd
Environmental Compliance Coordinator
Environmental Services

ENCO Laboratorses,
Accurate. Timely, Responsive. Innovative.
202-A Woodwinds Industrial Court
Cary NC, 27511
Phone: [phone] FAX: [phone]
Thursday, April 9, 2015
Novozymes North America (N0008)
Attn: Joe Ladd
77 Perry Chapel Church Road
Franklinton, NC 27525
RE: Laboratory Results for
Project Number. [none], Project Name/Desc: 5tormwater Testing
ENCO Workorder(s): C500084
Dear Joe Ladd,
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Friday, March 27, 2015.
Unless otherwise noted in an attached project narrative, all samples were received In
acceptable condition and processed In accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are in compliance with NELAC standards, except
as noted In the project narrative, This report shall not be reproduced except in full, without
the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
Chuck Smith
Project Manager
Enclosure(s)
FINAL This report relates only to the sample as receHed by the laboratory, and may only be reproduced In full. Page 1 of 10

CS
� �119
www.enoolabs.aom
SAMPLE SUMMARY/LABORATORY CHRONICLE
talent ID: Outfall -1
Lab ID: C500084-01
Sampled: 03/27/15 11,50 Reoelved: 03/27/15 15:22
PL
EPA 351.2
Hdd Datel7lmefsi
04/24/15
Prep bate/17me(sl
D4/03/1S
10:58
Analysis Datel7lmefsi
04/06/15 09:24
EPA 353.2
03/29/15 11:50
03/27/15
15:54
03/27/15 17:32
EPA 353.2
D4/24/15
04/01/15
07:29
04/01/15 11:59
EPA 353.2
1VZ0117
04/03/15
09:35
04/03/15 09:45
EPA 365.4
D4/24/15
04/03/15
10:58
04/06/15 10:40
SM 254OD-1997
04/03/15
04/01/15
12:55
04/01/15 12:55
SM 52109-2001
03/29/15 11:50
03/27/15
15:14
03/27/15 15:11
SM 5220D-1997
D4/24/15
03/30/15
11:10
03/30/15 15:55
FINAL This report relates only to the sample as recelved by the laboratory, and may Onty be reproduced In full, Page 2 of 10

Suco
www.eneolabs.com
SAMPLE DETECTION SUMMARY
Client ID: OutfaU - 1
Lab ID: C500084-01
ADandn
6saYltaE
Hale
H"
12L
U111M
PtafhsA
Bbohemikal Oxygen Demand
15
2.0
2.0
mg/L
SM 52108-2001
Chemical Oxygen Demand
44
10
10
mg/L
SM 52200-1997
Nitrate as N
4.5
0.025
0.10
mg/L
EPA 353.2
NitraWNitrlte As N
4.5
D
0.41
1.0
mg/L
EPA 353.2
Nitrite as N
0.030
J
0.017
0.10
mg/L
EPA 353.2
Phosphorus
0.080
7
0.025
0.10
mg/L
EPA 365.4
Total KJeldahl Nitrogen
1.8
0.26
0.48
mg/L
EPA 351.2
Total Suspended Solids
38
1.0
1.0
mg/L
SM 254OD-1997
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 10

www.encolabs.com
ANALYTICAL RESULTS
Description: Outfall - I Lab Semple ID: C500084-M Received: 03/27/15 16:22
Matrix: Surface Water Sampled:03/27/15 11:50 Work Order: C500084
Project: Stormwater Testing Sampled BV:Joe Ladd
Classical Chemistry Parameters
Biochemical Oxygen Demand
Chemical Oxygen Demand^
Nitrate as N [14797-55-8]^
Nitrate/Nltrite as N^
Nitrite as N [14797-65-03^
Phosphorus [7713-14-0]^
Total Itjeldahl Nltmgen^
Total Suspended Sollds^
BASUM
B"
l,Inm
15
mp/L
44
mg/L
4.5
mp/L
4.5
D
mg/L
0.030
3
OVA
0.080
3
mq/L
1.8
mq/L
38
mp/L
H"
l!"
1151rh
1
ft Notes
1 2.0
2.0
SC270A4
SM 521OB-2001
03/27/15 15:14
JOC
1 10
10
SC30010
SM 522OD-1997
03/30/15 15:55
30C
1 0.025
0.10
5D03011
EPA 353.2
04/03/15 09:45
SHA
10 0.41
1.0
5DO1004
EPA 353.2
04/01/15 11:59
SHA
1 0.017
0.10
5C27030
EPA 353.2
03/27/15 17:32
30C
1 0.025
0.10
5DO3004
EPA 365.4
04/06/15 10:40
SHA
1 0.26
0.48
5DO3003
EPA 3S1.2
04/06/15 09:24
SHA
1 1.0
1.0
5DO1017
SM 254OD-1997
W01/15 12:55
MMR
FINAL This report relates only to the sample as remNed by the laboratory, end may only be reprodwW in full. Pape 4 of 10

0 mmN64
www.encolabs.com
QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Baud+ 5C27024 - NO PREP
Blank (SC27024-BLKI) Prepared & Analyzed: 03/27/2015 15:14
Spike Source %REC
RPD
Anaildae
Rgsitlt
ELM
PQL
Units
Level Result %REC Limits RPD
Limit Nat"
Bkxhemical Oxygen Demand
2.0
U
2.0
mg/L
LCS (SC27024-BSI)
Prepared & Analyzed: 03/27/2015 15:14
Spike Source %REC
RPD
AnatlRe
Result
flag
M
Emits
Level Result %REC Limits RPD
Limit Notes.
Blodiemlcal Oxygen Demand
200
2.0
mg/L
198 102 85-115
Duplicate (SC27024-DUP3)
Prepared & Analyzed: 03/27/2015 15:14
Source: C501935-01
Spike Source %REC
RPD
Anal lrta
13eEult
Eats
P_RL
units
Level Result %REC Limilii RPD
Limit Nntes.
Bbchemical Oxygen Demand
16
2.0
mg/L
16 0.6
30
Duplicate (5C27024-DUP2)
Prepared & Analyzed: 03/27/2015 15:14
Source: C501964-01
Spike Source %REC
RPD
ABabtin
ReiLlt
flag
P)l
Units
Level Result %REC Limits RPD
Limit Notes
Biochemical Oxygen Demand
460
D
20
mg/L
500 7
30
Batch SC27030 - NO PREP
Blank (SC27030-BLK1)
Prepared: 03/27/2015 15:54 Analyzed: 03/27/2015 16:23
Spike Source %REC
RPD
Analfdg
Result
flag
EM
units
Level FArult %REC Ltmlla RPD
Limit Notes
Nitrite as N
0.017
U
0.10
mg/L
LCS {5CZ7030-BS3)
Prepared: 03/27/2015 15:54 Analyzed; 03/27/2015 16:20
Spike Source %REC
RPD
Ana
RUm t
Eats
PGL
Units
Level gsult %REC Lbnits RPD
Limit hotes
Nltrtte as N
0.99
0.10
mg/L
1.00 99 90-110
LCS (5C27030-8S2)
Prepared: 03/27/7015 15:54 Analyzed: 03/27/2015 16:45
Spike Source %REC
RPD
_Analf!!s
Result
flag
M
units
Level Sasu %REC LID1ltf RPD
Limit Nobel
Nitrite as N
0.97
0.10
mg/L
1.00 97 90.110
LCS (SC27030-BS3)
Prepared: 03/27/2015 15:54 Analyzed: 03/27/2015 17:31
Spike Source %REC
RPD
Ana hRa
ROsiiit
Elm
EQL
units
Level Result %REC Limits RPD
Limit Ng%L
Nitrite as N
0.97
0.10
mg/L
1.00 97 90-110
LCS (5C27030-6S4)
Prepared: 03/27/2015 15:54 Analyzed: 03/27/2015 17:35
Spike Source %REC
RPD
AnalYte
Result
Eats
P4L
Units
Level Result %REC Limb RPD
Limit Kolas
Nitrite as N
0.99
0.10
mg/L
1.00 99 90-110
Matrix Spike (SC27030-MSi)
Prepared; 03/27/2015 15:54 Analyzed: 03/27/2015 16:25
Source: C502864-01
Splice Source %REC
RPD
Ana hda
Roan
Eats
ROL
Units
Level Result %REC Limits RPD
Limit Notes
FINAL
This report relates any to the sample as remNcd by the laboratory, ano may only be reprodumd in full.
Page 5 of 10

�co
www.encolabs.com
QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Bahoh SC27030 - NO PREP - CDndnued
Matrix Spike (5C27030-M51) Continued
Prepared; 03/27/2015 15:54 Analyzed: 03/27/2015 16:25
Source: C502864-01
Spike Sauna %REC
RPD
An31Yt0 Result
Hag M
Llnits
Level Hlia t %REC LA011tg RPD
LlDtit Hogs
Nitrite as N 0.95
0.10
mg/L
1,00 0.017 U 95 90-110
Matrix Spike Pup (5C27030-MSD1)
Prepared: 03/27/2015 15:54 Analyzed: 03/27/2015 16:27
Source: C502864-01
Spike Source %REC
RPD
Analtrt0 Resuls
Hag EQL
Units
Level Reau %REC Llmlu RPD
LIMB Notes
Nitrite as N 0.96
0.10
mg/L
1.00 0.017 U 96 90-110 1
10
Batd►i 50!0010 - Same
Blank (5C30010-BLKI)
Prepared: 03/30/2015 11:10 Analyzed: 03/30/2015 15:55
Spike Source %REC
RPD
Ana htts
&GLUA
Hag
EQL
Units
Level Result %REC Limits RPD
Limit NOW,
Chemical Oxygen Demand
10
U
10
mg/L
LCS (SC30010-13SI)
Prepared: 03/30/2015 11:10 Analyzed; 03/30/2015 15:55
Spike Source %REC
R1110
Ana lYtp
R.es"i
Hag
ML
Units
Level Result %REC Limits RPD
U111% Notes
Chemical Oxygen Demand
S00
10
mg/L
500 99 90-110
Martz Spike (5C30010-MSi)
Prepared: 03/30/2015 11:10 Analyzed: 03/30/2015 15:55
Source: C413566-01
Spike Source %REC
RPD
Ana
Result
Hag
P91
Un1b
Level Result %REC L mitg RPD
Limit Hogg,
Chemical Oxygen Demand
2700
40
mg/L
2000 610 103 90-110
Matrix Spike Dup (3C30010-MSDl)
Prepared: 03/30/2015 11:10 Analyzed; 03/30/2015 15:55
Source: C413566-01
Spike Source %REC
RPD
Anal Yte
Rnult
Hag
BUL
Units
Level Regylt %REC Limits RPD
Limit Notes
Chemical Oxygen Demand
2700
40
mg/L
2000 610 105 9D-110 2
10
Batnh 5DO1004 - NO PREP
Blank (SDD1004-01.11(i)
Prepared: 04/01/2015 07:29 Analyzed: 04/01/2015 11:50
Spike Source %REC
RPD
Ana hr30
Result
19"
PM
Upiu
Level Result %REC Ltal" RPD
UM Notes
Nitrate/Nitrite as N
0,041
U
0,10
mg/L
LCS (5001004-851)
Prepared: 04/01/2015 07:29 Analyzed; 04/01/2015 11:48
Spike Source %REC
RPD
Ana hda
Result
Hag
e01
Unit:
Level R4111R %REC Limits RPD
Llmkt Notes
Nltrate/Nltrite as N
1.2
0.10
mg/L
1125 99 90.110
Matrix Spike (SD(11004-Ut51)
Prepared: 04/01/2015 0719 Analyzed: 04/01/2015 11:54
Source: C413566-01
Spike Source %REC
RPD
Anabtte
Reim
Hag
eQl
Units
Level Resat %REC LLmitg RPD
Limit dotal
Nitrate/Nitrite as N
1.3
0.10
mg/L
0.513 0.82 89 90-110
QM-05
FINAL This report relates only to the sample as reeNved by the laboratory, and may only be reproduced In NIL Page 6 of 10

OF 14
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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
aa" .001004 - NO PREP - Continued
Matrix Spike pup (5D01004-MS01)
Prepared: 04/01/2015 07:29 Analyzed: 04/01/2015 11',57
Source: C413366-01
Spike Source %REC
RPD
Arid
Result
flag
E9L
Units
Lewd StGg %REC LIMJU
RPD
Llmlt NalL
Nitrate/Nitrite as N
1.2
0.10
mg/L
0,513 0.82 66 90-110
10
10 QM-05
Rate* 5DO1017 - NO PREP
Blank (5001017-BLK3)
Prepared & Analyzed: 04/01/2015 12:55
Spike Source %REC
RPD
Anah<te
Reiul
flag
E41
units
Loved 029FAIt %REC Llmlta
RPD
Ltll1t Notes
Total Suspended Solids
1.0
U
1.0
mg/L
LCS (SD01017-051)
Prepared & Analyzed: 04/01/2015 12:55
Spike Source %REC
RPD
Anolwte
Result
Elea
R"
Units
Level Result %REC Limits
RPD
Limit Notes
Total Suspended Solids
97
1.0
mg/L
100 97 80-120
Duplicate (5001017-DUPi)
Prepared & Analyzed: 04/01/2015 12:55
Source: C413566-01
Spike Source %REC
RPD
Anal1[tA
Result
Hale
P91
UAM
Level gMWU %REC Llinitd
RPD
LIi9)t Notes
Total Suspended Solids
65
1.0
mg/L
71
9
10
Duplicate (5D01017-DUP2)
Prepared & Analyzed: 04/01/2015 12:55
Source: C500094-01
Spike Source %REC
RPD
Anahltae
Seesu)t
flea
PM
units
Level Result %REC Lkab
RPD
Llmlt Upton
Total Suspended Solids
36
1.0
mg/L
38
7
10
Rahn 5D03003 - Same
Blank (5003003-BLKl)
Prepared: D4/03/2015 10:58 Analyzed: 04/06/2015 09:11
Spike Source %REC
RPD
Ana hlSe
Result
flag
PQL
U41w
Level mut %REC Llmlts
RPD
Limit Notes
Total K)eldattl Nitrogen
0.26
U
0.48
mg/L
LCS (SD03003-BS3)
Prepared: 04/03/2015 10:58 Analyzed: 04/06/2015 09:13
Spike Source %REC
RP0
-Ananda
Rea-dt
Elm
P41
Unita
Level Result %REC Lh IU
RPD
UU11111 Notes
Total Neldahl Nitrogen
12
0.48
mg/L
12.0 104 90-110
Matrix Spike (5003003-MS1)
Prepared: 04/03/2015 10:58 Analyzed: 04/06/2015 09:18
Source: C413566-01
Spike Source %REC
RPD
Anande
Result
flog
EQL
Units
Level Result %REC Limits
RPD
Limit Notes
Total Kleldahl Nitrogen
62
D
2.7
mg/L
4.79 60 45 90.110
QM-17
Matrix Spike Dup (SD03003-MSDi)
Prepared: 04/03/2015 10,58 Analyzed', 04/06/2015 09,20
Source-. C41356"1
Spike Source %REC
RPD
Anah[ta
Result
flag
E41
tlgitE
Level Result %REC Llmit9
RPD
LWH Notes
Total kgeldahl Nitrogen
63
D
2.7
mg/L
4.79 60 57 90-110
0.9
10 QM-17
Ratdl SD0300w - Same
FUM This report rekates only to the sample as receKed try the lauxatory, and may only be reproduced In full. Page 7 of 10

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quaf)ty Control
Balch 51WO04 - Same - Continues
Blank (5D03004-BLK1) Prepared: 04/03/2015 10:58 Analyzed: 04/D6/2015 10:30
Spike Source %REC RPD
Ana hde 8C4illt H" 2QL 191W Level %REC llrnits RPD UIULt Nolms
Phosphorus 0.025 U 0.10 mg/L
LCS (51303004-8S1) Prepared: 04/03/2015 10:58 Analyzed: 04/06/2015 10:31
Spike Source %REC
RPD
Anal sewn
14aR
EAL
limb
Level gesul %REC Witi RPo
u1nit Notes
Phosphorus 1.5
0.10
mg/L
1.60 92 80-120
Matrix Spike (5D03004-MS1)
Prepared: 04/03/2015 10:58 Analyzed: 04/06/2015 10:35
Source: C413566-01
Spike Sou %REC
RPD
Anatltfe ResufZ
flag
PD1.
Unlu
Level get %REC Lbb RPD
LiBfIL Notes
Phosphorus 7.5
D
0.59
mg/L
0.640 7.3 43 60-120
QM-17
Matrix Spike pup (SD03004-MSD1)
Prepared: D4/03/2015 10:58 Analyzed: 04/06/2015 10:36
Source*C413366-01
Spike Source %REC
RPD
Ann!][fe Result
flag
P_Ql.
141J i
Level gesu%REC LLm& RPD
l.jluft Notes
Phosphorus 7.6
D
0.59
mg/L
0.640 7.3 47 80-120 0.3
25 QM-17
F1nni. This report relates only to the sample as received by the laboratory, and may only be neproducad In full, Page 8 or 10

AV- ENCO Laboratorse-S
Accurate. Timely. .Responsive. Innovative.
102-A Woodwinds Industrial Court
Cary NC, 27511
Phone: [phone] FAX: [phone]
Thursday, May 14, 2015
Novozymes North America (N0008)
Attn: Joe Ladd
77 Perry Chapel Church Road
Franklinton, NC 27525
RE: Laboratory Results for
Project Number: [none], Project Name/Desc: Stormwater Testing
ENCO Workorder(s): C500085
Dear Joe Ladd,
Enclosed Is a copy of your laboratory report for test samples received by our laboratory on
Friday, May 1, 2015.
Unless otherwise noted in an attached project narrative, all samples were received in
acceptable condition and processed In accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are in compliance with NELAC standards, except
as noted in the project narrative, This report shall not be reproduced except In full, without
the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further Information, please do not hesitate to contact me.
Sincerely,
Chuck Smith
Project Manager
Enclosure(s)
FINAL This report relates only to the sample as rcceWed by the laboratory, and may only be reproduced M rull. Page I of 7

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SAMPLE SUMMARY&ABORATORY CHRONICLE
Client to: Outran -1 Lab to: C500085-01 Sampled: 05/01/15 09:00 Recelved: 03/01/15 16.30
Parameter Hold Date(Timefs4 Prep DaWITlme(s)Analysis Date/Tlme(s]
SM 2540D-1997 05/08/15 05/05/15 09:09 05/05/15 09:09
FINAL This report relates only to the sample as r"hmd py the laboratory, and may only be reproduced In full. Pepe 2 of 7

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SAMPLE DETECTION SUMMARY
Client ID: Outfall -1 Lab IDt CSOOCSS-01
ADanda Results au H" RQL llnu Method NOWS
Total Suspended Solids
mg/L SM 25411D•1997
FINAL This report relates only to the sample as receWed by the laboratory, and may only be reproduced In full. Pape 3 of 7

C, wwi arl rrr►
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ANALYTICAL RESULTS
Description: Outfall - 1 tab Sample ID: C500085-01 Received: 05/01/15 16:30
Matrix: Surface Water Sampled:05/O1/15 09:00 Work Order: C500085
Project: StormwaterTesting Sampled By. Joe Ladd
Classical Chemistry parameters
^ - BWO Cary C-OW arxlpta (AC 5Y11
Results an Units RE H" EI L @etch Method head IN lotus
Tobl Suspended SolldaA 46 mp/L 1 10 10 SE05004 SM 2540D-1997 05/05/15 09:09 MMR
d
FINAL This report relates only m the sample as receNcd by the laboratory, and may only be reproduced in full. Faye 4 of 7

1�0-0)
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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch SE05004 - NO PREP
Blank (SE05004-OLK1) Prepared & Analyzed: 05/05/2015 09:09
Spike Source %REC RPD
Ana hds Result E1w P41 knits Level Result %REC 1.111301(ts RPD 1.1111111 ILL
Total Suspended Solids 2.5 U 2.5 np/L
LCS (SE05004-653) Prepared & Analyzed: 05/05/2015 09:09
Spike Source %REC
RPD
AnahCEa
Result Ela2 PDl
Dill
Level Result %REC Lim RPD
khm Notes
Total Suspended Solids
97 2.5
mg/L
100 97 80-120
Duplicate (3E05004-DUP1)
Prepared & Analyzed: 05/05/2015 09:09
Source: C50 9"2
Spike Source %REC
RPD
Analllt
Result Flan e4.L
knits
Level Result %REC LIB RPD
Lwa dotes
Total Suspended Solids
390 62
mg/L
380 3
20
Duplkate (SEOSO04-DUP2)
Prepared S Analyzed: 05/05/201S 09:09
Source: C505434-02
Spike Source %REC
Analyts RO5Ult flog M Units Level Result %REC Limits RPD
Total Suspended Solids 5100 500 mg/L 4500 13
RPD
Llmlt dates
20
FINAL This report relates only to the sample as receJvad by the laWratory, and may only he reproduced In full. Pape 5 of 7

Nu Iq - SS 5C*tI9)i lS
ENCO Laboratories
Accurate, Timely. Responsive. Innovative.
102-A Woodwinds Industrial Court
Cary NC, 27511
Phone: [phone] FAX: 919A67.3515
Wednesday, August 5, 2015
Novozymes North America (NO008)
Attn: Joe Ladd
77 Perry Chapel Church Road
Franklinton, NC 27525
RE: Laboratory Results for
Project Number: (none], Project Name/Desc. Stormwater Testing
ENCO Workorder(s): C309405
Dear Joe Ladd,
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Friday, July 24, 2015.
Unless otherwise noted in an attached project narrative, all samples were received In
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained In this report are in compliance with NELAC standards, except
as noted in the project narrative. This report shall not be reproduced except in full, without
the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
Chuck Smith
Project Manager
Enclosure(s)
FINAL This iePon relates only to the sample as received by the laboramry, and may only he reproduced in full, I Page 1 of 7

NCO
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SAMPLE SUMMARY/LABORATORY CHRONICLE
Cllent ID: outra0 -1 Lab 1D, C509405-01 Sampled! 07/23/15 11:50 Received: 07/24/15 06:37
Parameter Hold DaWT1mef4j EMU Datlinmefol
SM 254OD-1997 07/30/15 07/27/15 11:00 07/27/15 11:00
FINAL This report relates only to b* sample as rccePeW by the laboratory, and may only be reproduced In full. Page 2 of 7

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SAMPLE DETECTION SUMMARY
Client ID., Outrall -1 Lab ID. C509405-01
A09hU H41Llts an Hu EQL U= Method Notes
Total Suspended Solids
3.3 3.3 mp/L SM 254OD•1997
FINAL This repot relates only t0 the sample as received try the laboratory, and may any be reproduced In full. I Page 3 Of 7

.rrr. N ww �r
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ANALYTICAL RESULTS
Description: Outfall - 1 Lab sample I0:C509405-01 Recehred: 07/24/15 08:37
Matrix: Surface Water Sampled:07/23/15 11:50 Work Order: C509405
Project: Stormwater Testing Sampled sy:]oe Ladd
Maslow
Classical Chemistry Parameters
Bessltts an MMM t}E M E L datrh Heumd 6nak7ed 21 Hdw
Total Suspended Sollds^ 14 mg/L 1.33 3.3 3.3 5G27003 SM 2540D-1997 07JZ7/15 11:00 MMR
FINAL This report relates only to the sample as McWvW by the laboratory, anC may only be rewad=W in rui6 Page 4 Of 7

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Sofx* SC27003 - NO PREP
Blank (5627003-BLKI) Prepared & Analyzed: 07/27/2015 11:00
Spike Source %REC RPD
AnandO Result lie0 P4L UA)ts level Read %REC LLMb RPD LIBI(t Notes
Total Suspended Solids 2,5 U 2,5 mg/L
LCS (SG27003-BSI) Prepared & Analyzed: 07/27/2015 11:00
Spike Source %REC
RPD
Anal Y±a
Result Elm POL
UAlb
Level Resu %REC Limits
RPD
Lind Kota@
Total Suspended Solids
94 2,5
mg/L
100 94 80-120
Duplicate (5627003-OUPI)
Prepared a Analyzed: 07/27/2015 11:00
Source: C508053-01
Spike Source %REC
RPD
Anal
Result fin PQL
Units
Level Result %REC Limits
RPD
L(mlt KQtaq-
Total Suspended Solids
230 50
mg/L
220
4
20
Duplicate (5627003-DUP2)
Prepared & Analyzed: 07/27120i5 11:00
Source., C406179-01
Spike Source %REC
RPD
Anabfts
Result Elan P-QL
units
Level Resin %REC Limits
RPD
LIMB Notes
Total Suspended Solids
180 12
mg/L
170
6
20
FINAL This report relates only to the sample as receNed by the laboratory, and may only be reproduced in full. I Page 5 Of 7

I y�
'yTy�
T�
F;
I

Date: July 6, 2015
Novozymes, NA Inc.
77 Perry's Chapel Church Rd.
Franklinton, N.C. 27525
NCDENR Division Of Water Quality
1617 Mail Service Center Raleigh, N.C. 27699-1617
Attn: Division Of Water Quality
Storm Water Sampling, NPDES Permit No. NCS000115
Dear Sir/Madam
novozY mes,,
Rethink Tomorrow
RECEIVED
AUG 19 2015
CENTRAL FILES
DWR SECTION
Per our Tier Two requirements, regarding the exceeded benchmark in Total Suspended Solids, (TSS), our
implementation of a monthly monitoring in area of concern, "Outfall I", beginning in January have resulted
in "No Flow" for the month of June.
We therefore were unable to collect a sample for this month. We plan to continue to diligently with our
monthly monitoring for the parameter of TSS until we obtain three consecutive sample results within the
benchmark range.
Kind Regards,
Joe Ladd
Environmental Compliance Coordinator
Environmental Services
C7)

EFFLUENT
NPDES PERMIT NO. NCS000115 DISCHARGE NO. 1
FACILITY NAME NOVOZymes, NA Inc. CLASS
OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA
CERTIFIED LABORATORIES (1) Enco (2)
CHECK BOX IF ORC HAS CHANGED 0 PERSON(S) COLLECTING SAMPLES
Mail ORIGINAL and ONE COPY to:
MONTH May YEAR 2015
COUNTY: Franklin
PHONE [phone]
Joe Ladd
ATTN: CENTRAL FILES x NIA
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY
RALEIGH, NC 27699-1617 KNOWLEDGE.
mmmmmEmmm
DWQ Form MR -I (11/04)

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
�- (including weekly averages, if applicable)
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially
threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the
permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the
permittee becomes aware of the circumstances.
If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for
improvements to be made as required by Part Il.E.6 of the NPDES permit.
"I certity, under penalty of law, that this document and all attachments were prepared under my direction or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly
responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Randv Green
Pertnittee (Please print or type)
Signatu f Permitt ** Date
(Required unless su mitted electronically)
Permittce Address Phone Number e-mail address Permit Expiration Date
Certified Laboratory (2)
Certified Laboratory (3)
Certified Laboratory (4)
Certified Laboratory (5)
ADDITIONAL CERTIFIED LABORATORIES
PARAMETER CODES
Certification No,
Certification No.
Certification No,
Certification No.
Parameter Code assistance may be obtained by calling the NPDES Unit at [phone] or by visiting the Surface
Water Protection Section's web site at h2o.enr.state.nc.us/was and linking to the unit's information pages.
Use only units of measurement designated in the reporting facility's NPDES permit for reporting data.
* No Flow/Discharge From Site: Check this box ifno discharge occurs and, as a result, there are no data to be
entered for all of the parameters on the DMR for the entire monitoring period.
** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204.
*** Signature of Permittee: if signed by other than the permittee, then the delegation of the signatory authority must be on
file with the state per 15A NCAC 2B .0506(b)(2)(D).
Page 2

EFFLUENT
NPDES PERMIT NO. NCS000115 DISCHARGE NO. 1
FACILITY NAME Novozymes, NA Inc. CLASS
OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA
CERTIFIED LABORATORIES (1) Enco (2)
CHECK BOX IF ORC HAS CHANGED ©0 PERSON(S) COLLECTING SAMPLES
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES x NIA
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY
RALEIGH INC 27699-1617 KNOWLEDGE.
MONTH March YEAR I 2015
COUNTY: Franklin
PHONE [phone]
Joe Ladd
L11IM11111111M.":
DWQ Form MR-1 (11/04)

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
(including weekly averages, if applicable)
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially
threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the
permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the
permittee becomes aware of the circumstances.
If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for
improvements to be made as required by Part ILE.6 of the NPDES permit.
"1 certity, under penalty of law, that this document and all attachments were prepared under my direction or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly
responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Randy Green
Permittee (Please print or type)
Sign ur of Perm' ee*** Date
(Required unless Wbmitted electronically)
Permittee Address Phone Number e-mail address Permit Expiration Date
Certified Laboratory (2)
ADDITIONAL CERTIFIED LABORATORIES
Certification No.
Certified Laboratory (3) Certification No.
Certified Laboratory (4) Certification No.
Certified Laboratory (5)
PARAMETER CODES
Certification No.
Parameter Code assistance may be obtained by calling the NPDES Unit at [phone] or by visiting the Surface
Water Protection Section's web site at h2o,enr.state,nc.us/wqs and linking to the unit's information pages.
Use only units of measurement designated in the reporting facility's NPDES permit for reporting data.
* No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be
entered for all of the parameters on the DMR for the entire monitoring period.
** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204.
*** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on
file with the state per 15A NCAC 213.0506(b)(2)(D).
Page 2

Date: January 31, 2015
Novozymes, NA Inc.
77 Perry's Chapel Church Rd.
Franklinton, N.C. 27525
NCDENR Division Of Water Quality
1617 Mail Service Center Raleigh, N.C. 27699-1617
Attn: Division Of Water Quality
novozY mes,
Rethink Tomorrow
RECEIVED
MAY 0 4 Z515
CENTRAL FILES DWR s C� ON f"�r'I
CMA
Storm Water Sampling, NPDES Permit No. 'NCS000115
Dear Sir/Madam
Per our Tier Two requirements, regarding the exceeded benchmark in Total Suspended Solids,
(TSS), our implementation of a monthly monitoring in area of concern, "Qutfall 1", beginning in
January have resulted in "No Flow" for the month of January.
We therefore were unable to collect a sample for this moth. We plan to continue to diligently with
our monthly monitoring for parameter of TSS until we obtain three consecutive sample results
within the benchmark range.
Kind Regards,
)tm awl
Joe Ladd
Environmental Compliance Coordinator
Environmental Services

Environmental Conservation LaboraPories, Inc.
•
102-A Woodwlnds Industrial Court
Cary NC, 27511
Phone: [phone] FAX: [phone]
Monday, February 21, 2011
Novozymes North America (N0008)
Attn: Joe Ladd
77 Perry Chapel Church Road
Franklinton, NC 27525
RE: Laboratory Results for
Project Number: [none], Project Name/Desc: Outfall 1 Sampling
ENCO Workorder: C101326
Dear Joe Ladd,
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Friday, February 11, 2011.
Unless otherwise noted in an attached project narrative, all samples were received in
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are in compliance with NELAC standards, except
as noted in the project narrative. This report shall not be reproduced except in full, without
the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
Chuck Smith
Project Manager
Enclosure(s)
The total number of pages in this report, including this page is 13.
www.encolabs.com

i •
�uco
www.encolabs.com
Parameter Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Tlme(s)
..--..--�.......................... ........................ . -- . ----- ------------- ----------
EPA 200.7 08/09/11 02/16/11 10:16 2/17/2011 11:27
EPA 200.7 08/09/11 02/16/11 10:16 2/17/2011 11:29
SM 2540D 02117/11 02/14/11 12:35 2/14/2011 12:35
Parameter
-----------
Hold Date/Time(s)
------------ -- -- - ...... .................
Prep Date/Time(s)
I......... .
Analysis Date/Time(s)
........... . ....... I-------......
EPA 200.7
08/09/11
02/16/11 10:16
2/17/2011 11:31
EPA 200.7
08/09/11
02/16/11 10:16
2/17/2011 11:34
SM 2540D
02/17/11
02/14/11 12:35
2/14/2011 12:35
Page 2 of 13

(S. NS gg
www.encolabs.com
--tent ID: Sample A
Lab�ID: C1o1326_01
'�"'�*
Analyte
Results
Flag MDL
PQL
Units
Method Notes
---- ------------------------------------
Aluminum - Total
...............
218
. -- -- .......................
17
100
•-----........
ugX
EPA 200.7
Aluminum - Dissolved
49
J 17
100
ug/L
EPA 200.7
Copper - Dissolved
18.1
1.60
10.0
ug/L
EPA 200.7
Copper - Total
22.9
1.60
10.0
ug/L
EPA 200.7
Iran - Dissolved
346
22
50
ug/L
EPA 200.7
Iran - Total
509
22
50
ug/L
EPA 200.7
Total Suspended Solids
2.7
1.0
1.0
mg/L
SM 2540D
Zinc - Total
217
3.8
10.0
ug/L
EPA 2D0.7
Zinc - Dissolved
197
3.8
10.0
ug/L
EPA 200.7
Analyte
Results Flag
MDL
PQL
Units
Method Notts
........
.... .................. .---------
Aluminum - Total
-- -- ............................
249
--
17
. •.... .-................
100
ug/L
...-...............
EPA 200.7
Aluminum - Dissolved
17 3
17
100
ug/L
EPA 200.7
Copper - Dissolved
17.8
1.60
10.0
ug/L
EPA 200.7
Copper - Total
22.1
1.60
10.0
ug/L
EPA 200.7
Iron - Dissolved
320
22
50
ugIL
EPA 200.7
Iron - Total
529
22
50
ug/L
EPA 200.7
Total Suspended Solids
17
1.0
1'0
mg/L
SM 2540D
Zinc - Total
227
3.8
10.0
ug/L
EPA 2003
Zinc - Dissolved
188
3.8
10.0
ug/L
EPA 2003
Page 3 of 13

www.encolabs.com
ANALYTICAL RESULTS
Description: Sample A Lab Sample ID: C101326-01 Received: 02/11/11 07:50
Matrix: Waste Water Sampled: 02/10/11 16:00 Work Order. C101326
Project: Outfall 1 Sampling Sampled By. Joe Ladd
Metals by EPA 200 Series Methods
.....
^ ENCO Cary rertiixd a-W [NC 591]
Analog rCAS Numberl
Resin Ebw
Vohs
2E HU
MU
Batch
Meth
A[MlYZed
$y �
Aluminum [7429-90-51 ^
218
ug/L
1 17
100
1B16014
EPA 200.7
02/17/11 11:29
1DH
Copper 17440.50-81 ^
22.9
ug/L
1 1.5C
1010
1B16014
EPA 200.7
02/17/11 11:29
1DH
Iron [7439-09-6] ^
509
u9/1-
1 22
50
1B16014
EPA 2001
02/17/11 1129
7OH
Zinc [7440.66.6] ^
217
ug/L
1 3.0
10.0
IB16014
EPA 200.7
02/17/11 11:29
]DH
Page 4 of 13

i •
-
www.encolabs.com
Description: Sample A Lab Sample ID: C101326-01 Received: 02/11/11 07:50
Matrix: Waste Water Sampled: 02/10/11 16:00 Work Order: C101326
Project: Outfall 1 Sampling Sampled By: Joe Ladd
Metals (Dissolved) by EPA 200 Series Methods
------------------ ---.................. ............................
--..............................
......................
-.,-...-..-..
^ e X Cary Cert A'd analyte (NC 591)
Analog [CAS Numbcd gesu11s flag
1!n[1s
pf
MU
MAL
A=h
Method
AnalWod
gx 1y=
Aluminum [7429.90-51 ^ 49 J
ug1L
1
17
100
LB16014
EPA 200.7
02/17/11 11:27
JDH
Copper [7440-50.81 ^ 18.1
ug/L
1
1.60
10.0
LB16014
EPA 200.7
02/17/11 11:27
JDH
Iron [7439-89-fi] A 346
ug1L
1
22
50
1B16014
EPA 200.7
02117/1111:27
JDH
Zinc [7440.65.6] ^ 197
ug/L
1
3.8
10.0
LB16014
EPA 200.7
02117/11 11:77
JDH
Page 5 of 13

Ce NS gg
www.encolabs,com
Description: Sample A Lab Sample ID: C101326-01 Received: 02/11/11 07:50
Matrix: Waste Water Sampled: 02/10/11 16:00 Work Order: C101326
Project: Outfall 1 Sampling Sampled By: Joe Ladd
Classical Chemistry Parameters
... ... ............................. ....... ............ ...........
^ - ENCO ary certified anayie[NC 591]
Analyte NA5 Numberl gam] Elg Units Df HU MU @azb Method Analyzed BY Jr pto
Total Suspended Solids [ECL-0169] ^ 2.7 mp11- 1 1.0 1.0 1B14009 SM 2540D 02114/11 12:35 KLl
TM report relates only to the sample as received by the laboratory, and may only be reproduced in full.
Page 6 of 13

www.encolabs.com
Descriptions: Sample B
Lab Sample ID: C101326-02
Received: 02/11/11 07:50
Matrix: Waste Water
Sampled: 02/10/11 16:15
Work Order, C101326
Project: Outfall 1 Sampling
Sampled By: Jae Ladd
Metals by EPA 200 Series Methods
....................................................
.............................
...................................................
^ - ENCO Cary -rorvd a-Ve (NC 5911
AnalvW [CAS Numberl Sys DU
Uhm
pF M & Bin Batch
Method Analyzed lac JNotes
Aluminum [7429-90-5] ^ 249
ug/L
1 17 100 1916014
EPA 200.7 02/17/11 11:34 )DH
Copper [7440-50-8] ^ 22.1
ug/L
1 1,60 10.0 1516014
EPA 2003 02/17/11 11:34 10H
Iron [7439-89-61 ^ 529
ug/L
1 22 50 1B16014
EPA 200.7 02/17/11 11:34 7DH
Zinc [7440-66.61 ^ 227
ug/L
1 3.8 10.0 1B16014
EPA 2003 02/17/11 11:34 )DH
Page 7 of 13

• 0
Ce gg
www,encolabs.com
Description: Sample B
Lab Sample ID: C101326-02
Received: 02/11/11 07:50
Matrix: Waste Water
Sampled: 02/10/11 16:15
Work Order: C101326
Project: Outfall 1 Sampling
Sampled By: Joe Ladd
Metals (Dissolved) by EPA 200 Series Methods
..............
... ..
^ - ENCO Cary -r0'fied analyze (NC 59IJ
Analvte rCAS Numberl Results Flag
Units
DE Via Vin Batch
Meth Analyzed lix lYs?Ss�
Aluminum (7429.90-51 ^ 17 1
ug/L
1 17 100 LB16014
EPA 200.7 02/17/11 11:31 JDH
Copper [7440.50-8] ^ 17.8
ug/L
1 .1.60 10.0 LB16014
EPA 200.7 02/17/11 11:31 JDH
Iron [7439-89-51 ^ 320
ug/L
1 22 50 IB16014
EPA 200.7 02117/1111:31 JDH
Zinc [7440-66-61 ^ 188
ug/C
1 3.8 10.0 1816014
EPA 200.7 02/17/11 11:31 JDH
Page 8 of 13

rlrr rrr
www.encolabs.com
Description: Sample B
Lab Sample ID: C101326-02
Received: 02/11/11 07:50
Matrix: Waste Water
Sampled: 02/10/11 16:15
Work Order: C101326
Project: Outrall 1 Sampling
Sampled By: ]De Ladd
Classical Chemistry Parameters
------------------------------ --------------
--------------------•......---.--
--.._.... --••- ..................
..-- --.._ ..
^ - ENCO Cary certifrEd aW4 a (NC 5911
Analvte [CAS Numberl
$esul ELAG
1l= 9E HU MU Batch Meth
Analyzed JAY lYQw
Total Suspended Solids [ECL-01691 ^
17
mg/L 1 1.0 1.0 1814009 SM 2S40D
02/14/11 12:35 KU
This report relates only to the sample as received by the laboratory, and may only be reproduced In full.
Page 9 of I3

www.encolabs.com
QUALITY CONTROL
Metals by EPA 200 Series Methods - Quality Control
Batch I816014 - EPA 3005A
Blank (1B 16014-BLK1) Prepared: 02/16/2011 10:16 Analyzed: 02/ 1712011 11:12
Aluminum 17 U 100 ug/L
Copper 1.60 U 10.0 ug/L
Iron 22 U 50 ug/L
Zinc 3.8 U too ug/L
LCS (1B16014-BSI) Prepared: 02/16/2011 10:16 Analyzed: 02/17/2011 11:04
Aluminum
5420
100
ug/L
5000 100 85-115
Copper
273
10.0
Ug/L
250 109 85-115
Iron
5440
50
ug/L
5000 109 8S-115
Zinc
549
10.0
ug/L
500 110 85.115
Matrix Spike (1816014-MS3)
Prepared: 02116/2011 10:16 Analyzed: 02/17/2011 11:19
Source: CL00$25-01
Aluminum
SOO
190
ug/L
5000 18 108 75-125
Copper
263
10.0
Ug/L
250 1.60 U 105 7S-12S
Iron
5260
50
4/L
5000 41 104 75-125
Zinc
537
10.0
u0/1.
500 11.8 105 75.125
'-" '-"'..................................
Matrix Spike pup (1615014-11WISDI)
"'.............
" " .................'-
...... "'............. --.._.............I..., ........
Prepared: 02/16/2011 10:16 Analyzed: 02/17/2011 11:20
Source:C100525-01
Aluminum
5220
100
u9/L
5000
18
104
75-125 3
25
Copper
262
10.0
Ug/L
250
1.60 U
105
75.125 OA
25
Iron
5240
SO
ug/L
5000
41
104
75.125 0.4
25
Zinc -
...................................
536
--I•---•-----.-.-..-..
10.0
..........................
ag/L
500
11,8
--...--..
105
............................
75-125 0.2
25
........... ...--
Metals (Dissolved) by EPA 200 Series Methods - Quality Control
Batch I816014 - EPA 3005A
Blank (1B16014-BLKI) prepared: 02/16/2011 10:16 Analyzed: 02/17/2011 11:12
Aluminum 17 U 100 ug/L
Copper 1.60 U 10.0 ug/L
Iron 22 U 50 ug/L
Zinc 3.8 U 10.0 ug/L
......................................................... ............................................ I .......................
.- .-....
LCS (1B16014-BSI) Prepared: 02/16/2011 10:16 Analyzed: 02/17/2011 11:04
Aluminum
Copper
5420 100 ug/L 5000 108 85-115
273 10.0 ug/L 250 109 85-115
Page 10 of 13

www.encolabs.com
QUALITY CONTROL
Metals (Dissolved) by EPA 200 Series Methods - Quality Control
Batch I8I6014 - EPA 3005A
LCS (016014-BSI) Continued Prepared: 02/16/2011 10:16 Analyzed: 02/17/2011 11:04
Iron 5440 50 ug/L 5000 109 85-115
Zinc 549 10.0 ug/L 500 110 85.115
--'-......'--'.................................'....................._...................................
Matrix Spike (IB16014-MS1) Prepared: 02/16/2011 10:16 Analyzed: 02/17/2011 11:19
Source: C10052S-01
Aluminum
5400
100
ug/L
5000 18 108 75-125
Copper
263
10.0
ug/L
2S0 1.60 U 105 75-125
Iron
5260
50
ug/L
5000 41 104 75-125
Zinc
537
10.0
ug/L
500 11.8 105 75-125
Matrix Spike Dup (1B16014-MSD1)
Prepared: 02/16/2011 10:16 Analyzed: 02/17/2011 11:20
Source:C100S25-01
'r
Spike %REC)' 'RPD'� <.
3Flag.
Ana
Rewlt;
MRL
Units,
Y Le el. Result'' ; 9/aREC Limits RPD. Limit. r Not09 ,'
Aluminum
5220
100
ug/L
5000 18 IN 75-125 3 25
Copper
262
10.0
ug/L
250 1.60 U 105 75-125 0.1 25
Iron
5240
5C
uglL
5000 41 104 75-125 0.4 25
Zinc
.........................'-.............................................._..._......_........................_..........------------.....
516
10.0
ug/L
500 11.8 105 75-125 0.2 25
Classical Chemistry Parameters - Quality Control
Batch 1614009 - NO PREP
Blank (014009-BLKI) Prepared & Analyzed: 02/14/2011 12:35
Total Suspended Solids 1.0 U 1.0 mg/L
LCS (1B14009-BSI) Prepared & Analyzed: 02/14/2011 12:35
Total Suspended Solids 83 1.0 mg/L 60.0 104 90-122
Duplicate (IS14009-DUPi) Prepared & Analyzed: 02/14/2011 12:35
Source: C015873-01
Total Suspended Solids 1800 1.0 mg/L 1800 2 25
Page l l of 13

CS NS CEO
www.encolabs.com
B The analyte was detected in the associated method blank.
D The sample was analyzed at dilution.
J The reported value is between the laboratory method detection limit (MDL) and the laboratory method
reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable.
U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
B The concentration indicated for this analyte is an estimated value above the calibration range of the
instrument. This value is considered an estimate.
MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution
factor, and, in the case of soil samples, moisture content.
QB-01 The method blank had a positive result for the analyte; however, the concentration in the
method blank is less than 10% of the sample result, which minimizes the impact of the
deviation.
Pagc 12 of 13

w
ENVIRONMENTAL CONSERVATION LABORATORIES CHAIN -OF -CUSTODY RECORD www.encolabs.com
�a xtl Industrial Ct.
Or. 4Ja(*WM11a.FL
ID775C nlial Red orOdarWo
FL 32824 3221 G6oeq Gwy NWC�a1e1lyds
(4O7) 826.5314 Fax [phone]-W5 (91>412963007 Fax 1gD41296-210 191 ej 457-Ja90 FaJ (919)4fi7-3515 Page -j— of t
Gent Name
Pm Nu
'�noneq
RJVaesled
AmlyJes
Requested Turnaround
Nova4mes North America (NO008)
Times
N a-pih+e?4a� to
LL
Address 77 Perry Chapel Church Road
�6tiFa�Sampling
N
p
auepaxe by Me fatifty
CitylStlZp -
Franklinton, NC 27525
PD Jl allig Irdo
�
N
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—Standard
Tel
[phone]
JoeLadd
L
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(D
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�
— Expedited
Sampletts)Nor+o.AlMafianlPr;•y
B �q �rlriPa
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HtS y able
U
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Due —1-1—
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Fr�enatl-
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of
Catlectiar
Matrix
1O1w r of
ttamJ
SampleID(FWdldentificaeon)
Collection Dale
Time
CamplGrah
(wemdes)
Cmranars
Sample Comments
%fi:, r_
VIfVV
t1
X
X
X
- -
AA
c t t 1; �f
10 l l
1Lc D
�r r
YVW
2 0
X
X
X
Ww
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X
X
X
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<— Total of Containers,
SaVa NA Prepared By oatmlfvne
Reinoutseed By 7+
Dale,Te
F;acakvd By:
pale•T�e
Can¢nent&Gpemd Re" " n
RGdngWj -0d By
Dale.?me
lW.—d By
[err
,. ,rfi j:•I -AG Li►ieId c'r(1>r+S f1S6 k?
nprisaed By
DalwTtne
Re=.d By
9aiariuna
'I<5�0[IfF{
�4A id 7EG¢ . 14
Cooler J's a iemQJ on Recep
Conddim llpmn Rerripl
G1 Y d l ail 2r w l rJ{
a `1 r
AccePtade Unacceptable
Matrix: GW-Gmxdwater Sd.Sd OW-Dm*k p Water SE-Setlmnt SWSurlace Water Y W-Wastewater A -Air O9thm (delai n mnmerds) Pmwrvallan:l-ke WHO N-HND3 54112504 M044X N 0,40lher(deral in comments)
Naw : AI samples submleed m ENCO Leta ary n homiarlce x m the terms end curdtirrs listed m the rrn:rrc at mG Corot, W ess Prior arisen ayeemanls a.isi
•
07

County: FRANKLIN
River Basin TAR
,Report To RROS
Collector: A-ROMANSKI
Region: RR0
Sample Matrix: SURFACFWATER
Lac. Type; RIVERISTREAM
Emergency Yes/No'
COC Yes/No:
. I I Location 10: NOVOUPSTRM
Sample ID: • 1 AB66107
A
PO Number 1OW9750
Date Received:
I 1210212010
Time Received:
.10:56
Labworks Logln[D
SFAATHiS.
$
Report Ganeraczd-
1110/11
Date
; . 101110/2011
�y sid D.
7
Loc. Descr.: NOVOBUFFCK-5.
12010
Collect Time: 12.-30Sample Depth
.
Result/
Method Analysis
CAS AnalYte Name
P
Units
Q60fier
Validated by
Reference Date
LAB
temperature at receipt b�. lab",. Sample t
-C
12/2/10 SMATHIS-
MIC
BOD, 5-Day in liquid�
2,
2 U G8 mg/L
APHA521013, 12/11/10 MOVERMAN
WET
Ion Chromatography
$Q,
TITLE
mgll-
EPA 300.0
12/6110
CGREEN
Chloride
1
17
mg/L
EPA 300.0
1216/10
CGREEN
Fluoride
0.4
0.4 U
mg/L
EPA 300,0
121W10
CGREEN
Sulfate
'2 ;t- 2.0
mgIL
EPA 300.0
1216110
CGREEN
Total Dissolved Solids in.liquid
w12.-
98,
mg/L
APHA254OC-18TH
12121I.0
CGREEN
NUT
NI-113'as N. in liquid
0.02
q' 0.02 U
mg/L as N
LeCI0-107-06-1-J
1. 12t3110
CGREEN
Total Kjeldahl N as IN in liquid.
0.5
mg/L as N
Larha1107-06-2-H
1217110.
CGREEN
NO2+NC3 as N in liquid
;t-Ail
2.0,
mg)L as N
LaclO.107-04-1-c
1218/10
CGREEN'
Phosphorus -total as P in liquid
0.02
0.10
mg/L as P
Lac10-I 15-01-1 EF
12/3110
CGREEN
MET
74 40-22-4
Ag by,ICPMS
5.0 U,
ug/L
EPA 200.8
12/8/10
ESTAFFORDI
7429.90-5
Al by ICP
50
72
ug]L
EPA 2007
12191110
...ESTAFFORD1
7440-38-2
As by ICPMS
2..
2.0 U
ug/L
EPA 200.8
i 1218110
ESTAFFORDI
74.40-38-3
Ba by .ICP
ug1L
EPA 200.7
1218110
ESTAFFORDI
7440-41-7
Be by ICP
5.0 U
ug/L
EPA 200.7
1219/10
ESTAFFORDI
7440-70-2
Ca by ICP
0.1
9.3
mg1L
EPA 200.7
12/8/10
ESTAFFORDI
744043-9
Cd by ICPMS.
0i 1.0 U
ug/L
EPA 200,8.
1218/10
ESTAFFORDI
7440-48-4
Cobalt by ICP
50
-,%: ?'t .50 U.
U011-
EPA 200.7
i 12/9110
ESTAFFORDI
744"7-3
Cr by ICPMS-
10.
10 U-
ug/L
EPA 200.8
1218110
ESTAFFORDI.
7440-50-8
Cu by ICPMS
2,
2.0 U
ug/L
EPA 200.8
1 12/8110.
ESTAFFORDI
.7439-89-6
Fe by ICP
'50
310
up/L.
EPA 200'.7
1219/10
ESTAFFORD1
7439-97-6
Hg 245.1'
''0.20 U
ug/L
EPA 245.1
12/14/10
ESTAFFORD1
7440.09-7
K by ICP
mg/L
EPA 200.7
1218110'
ESTAFFORD1
7439-93-2
Li ICP
26
.25 U
ug/L
EPA 200.7
1218110
ESTAFFORDI
7439-95-4
Mg by ICP
mg/L
EPA200.7
1218110.
ESTAFFORDI
7439-96-.5
Mnb ICIP
10
24
ugjL
EPA 200.7-
12/9110
ESTAFFORDI
7439-98-7
Mo by ICPMS
10,
IOU
EPA 200.8
R.1 2/811 d
ESTAFFORD1;
Laboratory
For m deteged descripUm ol the qualfler owes rife
Page of-2
'Lull
NG DENR
R61.0ftional office

`r .NC (D'WQ Laboratory Section *saka .
!
Location ID:
NOVOLIPSTRM .;
Sample ID: AB66107
Collect Date:
11210112010
Collect Time::
12:30
MET
:.
.: w a#iw • '': Resultl.-�';
Method
Analvsis
Validated by
CAS .#
Analyte Name
;.;t..J P U:e. `°,'r,
., r uaGfier. '' ..
Units
Reference
Date
7440-23-5
Na by ICP
` i,
0.1 14
me 1L
EPA 200.7
1218110 ,
ESTAFfpRD1
7440-02-0 .
Ni by ICPMS
; .:• ., . • :' "" ' `.'1Q ",-:.,:,,,, `; le, 10 U ' `
u01L .
EPA 200.81
1 12/8110
ESTAFFORDI
7439-92-1
Pb by ICPMS
10 ":?f;•c, vI :..10:�1,
ug1L
EPA200.0
12/8110
ESTAFFORDI
7440 36 0
Sb by'ICPMS . • ;-
— 10 10 U
ug/L
EPA 200.8
1216110
ESTAFFORD1
778249-2
Se by ICPMS.
5 ! 5.0 U
ug(L
EPA 200.6
1218110'
ESTAFFORDI
7440.31-5
Sn by ICPMS
1 Q..., . ' , .'Ya 10 U
ug1L ..:
EPA 200.8_
! 12/8110
ESTAFFORDI
7440728-0
Thallium (71) ICPMS.
`ti°:10`,?� f.:'; .-!``'f'''''% IOU
uglL
EPA200.8
12/8110
ESTAFFORDI
7440-326
Ti (Titanium) by iCP
' ,t:' 1. 1Oi'?:`w�?.' '` "7O.U.'
ug1L
EPA200:7
12J8110
ESTAFFORDI "
7440-62-2
V by ICP
25 25 U :'
ug1L
EPA 200.7
12/9110
ESTAFFORDI
744o-sfi-6
Zn by ICPMS
10 Ii'�- '-IO U.
ugfL ``
EPA.200.8
1218110
ESTAFFORDi
:i.
.
J
�� • ' ��':1.
-
'ply_.:.
• -' f
..
-
` . i •,- � : �� -11i
..
it
•.
'
'Laboratory Section>>'1623 Mall Sece Center, Raleigh, NC 27699-1023 t919j 733.3908
!t l '
n',
'
For a detailed desvlption of the qualifier codes mfer to n, It OAh tvwfoa ffirt AMOData
Q,al0e
I o-'
-Page 2 of 2
..
r
',>:-:.

COUNTY
R WR BASIN :
YL
- REPORTTO
r "L� Repw lOffice
Otber
` COLLECTOR(S)
Estimated DOD Rainey.
DIVISION OF WATER QUALITY
Chemistry lAboratory Report / Water Quality
SAMPLE TYPE
AM131ENf QA 1 ;3 57RF.AM EFFLUENT
COMPLIANCE ID CHAIN OF CUSTODY !7❑�I WE KFUTEN3
EMERGENCY VISIT TD 0 ESTUARY
Station Location. LO {i'-1f r�P'�.- .
T
PV
Lab Ntatsher
Date Received
T:me Received
Reeetved BY J(D��)�y�.- yip"+,
Data Released
Dine Reported
Seed: Cbloritrated: Remarks: !1-P n— OLD VVOC
. b .
Statlaa 011-otation Code - - Date Be6i�trrinrddl bate :ad f3�lmm! Time 83 Time End Depth - DM, DB, DBM Valoe T A, H. L Com
l�gY iq u l' s t%� �'�'� ) ( I !t ! I / L 1 � 2 I t t -2 " 3 1,s ' 3 0 Type Petite T, S. a aS
HOD 310 mgAL
COD High 340
COD Low 335
Coliform- MF Fecal 31616 /100m1
Colifbrm. MF Tota131504 /100m1
Coliform: tube Fecal 31615 /100ml
Coliform: Fecal Strep 31673 /loons)
Residue. TOW 500
Volatile 505 inglL
Fixed 510 mgiL
Residue- S 530 m
Volatile 535
Fixed 540 Mai
H 403 units
Acidity to pH 4.5 436 m
Acidity to pff 8.3 435 WL
AJkalinrty to pH 8.3 415
Alkalinity to pH 4 5 410 m
TOC 690 m
Turbidity 76 NTU
Coliform Total Tvhe 1100 ail
Chloride 940
Chlorophyfl a EPA 40 0 modified ion
Color. True 80 c.v.
'
Coksr: H 83 cu.
Color: pH 7.6 82 C.U. '
Cyanide 720 m
Fluoride 951
F 7I880
Grease grid Oils 556 mwL
Hanhsoas Total goo
S ific Cool 95 umbits/cv
MBAS 38260
Phenols32730
Sulfate 945 m
Sulfde 745
Homo
Twins & Li to
HcxevaErnt Chromium u
Bicarbohite mgfL
Carbonate mgAL
Total Dis,aN.d Solid. m
NH3 as N 610
TKN an N 625 mwL
'NO2 h s NO3 as N 630
P: ToW as P 665
PO4 as P 705017
P: Dissolved as P 666 m
K-Poomium
Cd- Cadmium 1027 u
Cr-CSvomismt Total 1034 u
Cu- CopM 1042 uPJL
Ni-Nickel 1067
Pb- Lad 1051
Zn- Zinc I D92 .
V-Vanadium UWL
- SthTr 1077
M-Aluminum 1105,
BeBeryllium 1012 uWL
Ca- Calcium 9I6 m
Co- Cobalt 1037 VL
Fe- Iren 1045
Mo-Mp urn u&fL
.j
SarAm' .
Sn-Tin u
TI-Thallium UWL
Ti-Titan' :m: ugfL
1631 rt
Li -Lithium 1132. u
hi - M slum 927 - sr,
Mn-Man x 1055 u
NaSodium929 - mWL
-
Arsenic Total 1002 u
Se- Selenium 1147 u
H - Mere 71000 ' u grL
Ba-Barium USA
K hlonne Pesticides'
Orgami,phosphorus Pesticides
t Pestscides
Acid Herbicides
`
baselNeutraIAAssd Enuactable Or ics
TPH Diesel kitrike
nzZabteorgmcs,VOAbofiles 'd -
.
TPH Gasoline Ran -
TPH/BTEX Gasoline Range
ftrytopimiktan
T stet on arrival ("C),

Report to: _RRO 77
Lab Number:
Station Location:
A B66107
• NC DENR/DWQ Laboratory
Sample Anomaly Report (SAR)
Sample ID: NOVO upstream
NOVOBUFFCK County: - Franklin Region: Tar -Pam
Upstream of
outfall 002
Sample Type: stream
Date collected: 12/01/10
Affected Parameter(s): - BOD
Priority: compliance
Date received: 12/02/10
Analytical Area (check one):
❑ WCH ❑METALS
❑NUT ®MICRO
The following anomalies occurred (check all that apply):
❑Samples
❑Improper container used
❑VOA vials with hcadspacc
❑Sulfide samples with headspace
❑Samples not received, but listed on fieldsheet
❑Samples received, but not listed on fieldslteet
❑Mislabeled as to tests, preservatives, etc.
❑Holding time expired
❑Prior to receipt in lab
❑Alter receipt in lab
❑Insufficient quantity -for analysis
❑Sample exhibits gross non -homogeneity
El Sample not chemically preserved properly
❑pl-I out of range (record pl-1):
❑Impro per chemical
❑Residual chlorine present in sample
❑Color interference
❑Heavy emulsion formed during extraction
❑Sample bottle broken in lab - no reportable results
®Other (specify):
Collector:
Date analyzed
A. Romanski
12/02/10
❑VOA ❑SVOA
❑PEST
❑Quality Control
❑Instrument failure— no reportable results
❑Analyst error — no reportable results
❑Surrogates
❑None added ,
[]Recovery outside acceptance limits
❑Spike recovery
❑None added
❑Recovery outside acceptance limits
❑Failed to meet criteria for precision
❑Internal standards
❑Blank contamination
❑QC data reported outside of controls (e'.g-,•QCS, LCS)
❑Incorrect procedure used
❑SOP intentionally modified with QA and Branch 1-lead
approval
❑Invalid instrument calibration
❑l;levated detection limits due to:
❑Insufiiciei t sample volume
Comments: Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is
calculated for the dilution using the most amount of sample.
Corrective Action:
❑Samples were rejected by DWQ Lab. Authorized by: Date:
❑Accepted and analyzed after notifying the collector or contact person and determining that another sample could not be secured.
❑Sample(s) on hold until:
®Sample reported with qualification. Data qualification code used:G8
❑Other (explain):
Notification Required? ❑ Yes ❑ No
Person Contacted: Date:
Dorm completed by:
Lead Chemist Review (initial):
�BIOCHEM n^D ❑PEST_
MG'TALS ❑VOA_
Branch Head Review (initial): `Y/ J90
QA/QC Review (ini
QA%Farm sV.aboratgrySS A R
Date: 12/11 /2010.
❑SVOA
Logged into database by (initial): /I -"A �
t IG123/01dbs

County:
FRANKLIN
River Basin
TAR
Report To
RROSP
Collector:
A ROMANSKI
Region:
RRO `
Sample Matrix: WASTEWATER
Loc. Type: EFFLUENT
Emergency YertNo
COC Yes/No
imi
Sample ID:
10F'VA rFiq
l
PO Number#
n O -
O�
a
Date Received:
> [
Time Received:
1
Lebworks LoginiD
1 .6
Report Generated:
i
Date Reported:
F, t.Aly iSf'• ... �.tiy
Vi5'rUD
AB66105 ;+
1OW9754
'12/0212010
10-55
SMATHIS
12/16/10
12/16/2010
Loc. Dascr.: NOVO-002
Location ID: NCGS00915.002 .Collect Date: 1210112010 '- Collect Time: 12.15 Sample Depth
Resu
Method
Analyils
CAS #
Analyte Name
Units
Validated_�x
ualifier
Reference
Date
LAB
Sample temperature at receipt by lab
::' i'
2.1
'C
12010
SMATHIS
MIC
BOD, 5-Day in liquid
2
2,5
mg1L
APHA5210B
12/11110
MOVERMAN
WET
r: '
Ion CtlromatD�rBpfly
_TITLE
mg1L•
EPA 300.6
1219110
MOVERMAN
Chloride
1
-73
mg1L
EPA 300.0
1219/10
MOVERMAN
Fluoride
0.4
4.3
mg1L
EPA 300.0
1219110
MOVERMAN
Sulfate
2 °�'",. ;f.
'" 130
m911.
EPA 30D.o
1219110
MOVERMAN
Total Dissolved Solids in liquid
12"
612
mg/L
APHA2540C-18TH
1212110
CGREEN
NUT
.
NH3 as N in.liquid
0.02.
`. i `,0.50
mg/L a3 N
Lac10-107-06-14
1213110
CGREEN
Total Kjeldahl N as N in liquid .
0.2.
2.0
mg1L as N
Lachat107-06-2-1-11
1217110
CGREEN
NO2+•NO3 as N in liquid
0.02
2.4
mg1L as N
1_600-107-04-1-c
1216110
CGREEN
Phosphorus_ total as P in liquid
0.02
2,0
mg1L as P
LBCIO-115-01-1EF
1213110
CGREEN
MET
7429-90-5
Al by ICP
50 , a ' w , ,�'` y.'
760
ug1L
EPA 200.7
1219110
ESTAFFORD1
7440-38-3
Ba by, ICP
10
82
ug[L
EPA 200.7
1218110
ESTAFFORDI
7440-70-2
Ca by ICP
0.1
59
mg/L
EPA 200.7
1218110
ESTAFFORDI
7440-50-8
Cu by ICPMS
2
' 43
ug1L
EPA200.8
1218110
ESTAFFORDI
7439-69-6
Fe by ICP
50
850
ug1L
EPA 200.7
12/9110
'ESTAFFORDI
7440-09-7
K by ICP
0.1
25
mWL
EPA 200.7
12]B110
ESTAFFORDI
7439-93-2
Li ICP
25 '.
1 -
25 U
ug/L
EPA 200,7
1218/10
ESTAFFORDI
7439-95-4
Mg by ICP
0:1 ''eo 9
16
mg/L
EPA 200.7
1218110
ESTAFFORDI
7439-96-5
Mn by ICP
10'
39
ug1L
EPA 200.7
121911D
ESTAFFORDI
7439-96-7
Mo by ICPMS
10
10 U
ug1L
EPA 200.8
12/8110
ESTAFFORDI
7440-23-5
Na by ICP
0.1
�.7Do.. •
mg1L
EPA 200.7
1218/10
ESTAFFORDI
7440-66-6
Zn by ICPMS
,. 10
370
u91L
EPA 200.8
1218110
ESTAFFORDI
Laboratory Section» 1623 Mall Service Center, Raleigh, NC 27699-1623 t919) 733.3908 1
For a detalled desorlpton ofthe qualifier codes warto hlln:lroo,tal1�ncdn�n/wntVwnllaNstnfhnfoAa l j. sfs Oala Qualifier Codes c11110:ponalrrfdenf.oivnn�ah,WollaAJslaFFinfMlec:he l>
Page 1 0f 1

DiV[SiON
OF WATER QUALM
J
'
Ciemian
Laborstory Report / Water Qaafity
❑ SAMELE T_YK
b N
Date Received
COU►r1w
RIVER BASM :
AMBIENT
QA SiRFAM EFFLUENT
Tlmc Re ceieed :
Received By
f
t
' REPORT TO Regional Office
COMPUANCE
CHALN OF CUSTODY LACE fNFL.UENf
Im i
Other
❑ EMFRGETICY
VISIT M E$1l1ARY
Data Released
COLLECTIDW(S) : �3 j � .t n.4
Date Reported
Estimated DOD Rae{e:
Seed: Chhriaated:
Station Leeafim: �{ �V s � a �}}���
Remarks: _�cS w t li *max C opG - BJ, kth,
Station I AAK31tion Code
5—DDa
Date n /mmldd)
Date Fad !m
d)
Time SetFa
Time End
Depth - DM, DR, DDM
Va[ae Type - A. H. L
ComposittT, S, B
Samp y
C oD
o a v
o
: i5
a:i5
SOD 31 D mWL
COD High 340 m
COD Low 335
Coliform- MF Fees] 11616 1100ral
Colif=i MFTOW 31304 !1OOinl
Coliform: tube Fecal 3161$ llUOnd
Coliform: Fecal Stimp 31673 11001111
Residue. ToW 500
Volatile 505 m
Fixed 510
Residue. Suamided 530 m
Volatile 535
Fund 540 m
H 403 units
Acidity to PH 4 5 436
Acids tq PH 8 3 435
Alkalinity to PH 8.3 415
Alkalinity to PH 4 5 410 m
TOC 680 mon-
TwNdM76 NTU
Colifmm Total Tubs 1100 ml
Chliaide 940 m
I a EPA 445 0 modified opdon
Color_ True 80 c.u.
Color: 83 H- c,u
Colm pH 7.6 82 c,a.
cywn& 720 m
F7umide 951 ITISIL
Famaldehyde 71990 myfL
Grease and Oils 556
Hadress T.W 900 TWWL
5 tfrc Cond. 95 urnhol/cm
MBAS 38260 m
Phenols 32730
Sulfate 945 m
Sulfide 745 ITIVIL
Baton
Tamiin & Li in
Hummsh! eCLaaoiiimm
Bicarbonate m
Carbonate m
TuW Divolved Solids
NH3 as N 61 o m
TKN an N 625 m
NO2 NM as N 630 m
P: Totid as P 663 m
PO4 as P 70507 mEVL
P: Dissolved as P 666MWL
-Pmmiran m
Cd. Csshanaa 1027 u
Cr-Clanmium?oW 1034
Cu- Fmm 1042
Ni-Nicket 1067 u /L.
Pb- lead 1051
Zn-Zirx 1092 11911,
V-Varadn'zm
Silver 1077 uA
AI- Ahaaiman 1105 WILL
Be- Beryllitm 1012
Ca-Calcium916'
Co- Cobalt 1031 1191
Fe- Iron 1 D45
Ma-Molybdenurn
Sb-AMmwrrf
Tl-Thallhtm u
Ti-TiLnium uFVL
Rg-1631 nlVL
Li -Lithium 1 132 u
M - Nl sium 927 m
Msi-Mni 1DS5 � 'L
Na- Sodium 929 m
Arscniffutal 1062
Se- Selmitaa 1147
H - Mere 71900 u
Sa,Banum u 1-
hla nc Pesticides
s Pesticides
en Pesticides
Acid Herbicides
BasdNeutral&Acrd Ectrattable ice
TPH Diesel Ran
le Ctr iu VOA bottle 'd
TPH Gasoline Ran
TPWBTF,C Casaltrn Range
P*Oplanktori
T on arrival ['C 1
r.

County: FRANKLIN
River Basin TAR OF WAr�R
Report To RROSP
i _.. C,
Collector: A ROMAN
Region: RR 1 ��� I
Sample Matrix: SURFACEW� 1 3 ?l � �
Loc. Type: EFFLUENT - ~~ - -A
Emergency YeslNo DENR RA! SQH REGIGIN LUi§,661 i
COC Yes/No
Loc. Dow.: NCG500115
Sample ID:
AB63613
PO Number #
1OW7782
Date Received:
09/17/2010
Time Received:
09:15
Labworks LogWD
HPARKER
Report Generated;
1018110
Date Reported:
10/08/2010
4
io-lt- ID
Location lD: NCG50NOVO ^Collect Date: 09l16l2010 Collect Time: 11:OS Sample Depth
Result/ Method Analysis Validated by
CAS # Analyte dame POL qualifier Units Reference Date
LAB
WET
Sample temperature at receipt by lab
0.9 °C
9/17/10 SMATHIS
otal Dissolved Solids In liquid ) 12 788 mglL APHA2540C-18TH 9/22/10 CGREEN
MET'
7440-22-4
Ag by ICPMS
5
5.0 U
ug1L
EPA 200.8
10010
ESTAFFORDI
7429-90-5
Al by ICP
50
50 U
uglL
EPA 200.7
9124110
ESTAFFORD1
7440-38-2
As by furnace
2
2.0 U
ug1L
EPA, 200.9
9/28110
ESTAFFORDI
7440-38-3
B by ICP
10
120
uglL
EPA 2003
9127110
ESTAFFORDI.
7440-41-7
Be by ICP
5
5.0 U
uglL
EPA 200.7
9/24/10
ESTAFFORDI
51 mg1L
7440-43-9
Cd by ICPMS
1
1.0 U
uglL
EPA 200.8
9/30110 ESTAFFURDI
7440-48-4
Cobalt by ICP
50
50 U
uglL
EPA 200.7
9/24110 ESTAFFORDI
7440-47-3
Cr by ICPMS
10
IOU
ug1L
EPA 200.8
9/30110 ' ESTAFFORDI
20
7439-89-6
Fe by ICP
50
240
ug1L
EPA 200.7
9124/10
ESTAFFORDI
7439-97-6
Hg 245.1
0.2
0.20 U
uglL
EPA 245.1
1011110
ESTAFFORDI
7440-09-7
K by ICP
0.1
29
mglL
EPA 200.7
9127/10
ESTAFFORDI
7439-93-2
Li ICP
25
25 U
ug1L
EPA 200.7
9/27/10
ESTAFFORDI
7439-95-4 f Mg by ICP 0.1 13 mg& EPA 200.7 9127/10 ESTAFFURDI
7439-96-5 - fn by ICP 10 19 uglL EPA 200.7 9/24110 ESTAFFORDI
7439-98-7 Mo by ICPMS 10 IOU ug/L EPA 200.8 1014110 ESTAFFORDI
60
10U
7439-92-1 Pb by ICPMS
10
IOU
uglL
EPA 200.8
9130110
ESTAFFORDI
7440-36-0 Sb by ICPMS
10
IOU
uglL
EPA 200.8
1014/10
ESTAFFORDI
7782-49-2 Se by furnace
5
5.0 U
ug1L
EPA 200.9
9129110
ESTAFFORDI
7440-31-5 Sn by ICPMS
10
IOU
uglL
EPA 200.8
1014/10
ESTAFFORDI
7440-28.0 Thallium (TI) ICPMS
10
IOU
ug1L
EPA 200.8
1014/10
ESTAFFORDI
7440-32-6 Ti (Titanium) by ICP
10
IOU
ug1L
EPA 200.7
9127110
ESTAFFORDI
7440-62-2 V by ICP
25
25 U
ug1L
EPA 200.7
9124/10
ESTAFFORDI
7440-66.6 (Zn by 1CP
10
180
ug1L
EPA 200.7
9/28/10
ESTAFFORDI
Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 t9191 733-3908
For a detailed description of the qualifier codes rater 10 hj1Q,lroonal,ncdanr.0rrVweblwallah�! IaNinfo( hassistt#Data qua mar Cndes �hd ro tal n encoralweblwnfla�f la inforlecha�t>
Paae 1 of 1

DTVFSTON OF WATER QUALM
i
r
Checistry Laboratory
Report! Water Quality
Lab Number
.-
ry' ~COUNTY
��
❑ SAMPL TYPE
Date Received Cj. l -7•
_ .l?•, ~ 'L f t�
RIVER BASIN:
FRIO
❑ AMEkENT ❑ QA ❑ STREAM .,UENT
Time Received :G�'
Received By
REPORT TO ; Regional Office
�/, COMPLIANCE CHAIN OF CUSTODY ❑ LAKE El INFLUENT
'�❑
Otbrc :
r�
EMERGENCY
VISIT ID ❑ ESTUARY
Data Released .
COLLECTORS) : _ 5 L f —
C�
+
Date Reported
Estimated ROD R: zW.
5tatlaa Lontioa: 5(.• C !r!S
r
Seed: Cbkoriaated-
Remarks:. :SLJ 11AJ tit) i ...- I, a .
Sfatiee o tisa Cade
Date Bella yy!
Date Ead ' lnrm!
Trme i3me Eel[
Depth - DM, m [IBM
=-TH, L
ComposOnT, S, B JSmzpke Type
0
BOO 310 nWL
COD High 340
COD Low 335
Coliform- MF Fein 31616 1100101
Cdif6,.� MF Totd 3 t 504 1100ml
Colif. tube Fecal 31611 1100101
Coliform: Fecal StrW 31673 /100trtl
Residue. Total 500 m
Volatile 505 m
Fixed i10
Residue: Suspermled 530 m
Volatile 535 MWL
Fixed 540 m
y 403 rmtu
Acidity to pH 4.5 436
Acidity to pH 8.3 435
Alkalm' to H 83 415 -811-
Alkalinity to pH 4 5 410 nwL
TOC 680
Turbidity 76 NTU
Coliform Total Tube 1100 W
Chloride 940 m
Chlomptryll a EPA 445.0 moditred cp6m
Color. True 80 C.U.
Color: H 83 H- c.a
Cotm- pH 7.6 82 o,u
EZ=da 720
Fluoride 951
F=Tnm1d4rj& 711190
Greaae and Oils 556 mak
Hardness Total900 Til
Specie Conti 95 umhos/cm
M13AS 38260
Phenols 32730
Sulfate 945
Sulfide 745
Baron
Tarmin & Lviin'
HM—Wem Chromium uWL
Betasbotude ffLWL
Carbottata m
Tool Dissolved Solids m
NH3 as N 610
TKN an N 625 msfL
NO2 phis NO3 as N 630 m
P. Total as P 665
PG4 as-P 70507
P: Dissolved as P 666 mgft
K-Potassium MWL
Cd- Cadmim 1027
C1-Qtrgrnium:T.W 1034
Cu- Copp. 1042
Ni-Nickel 1067 UWL
Pb- lead 1051 u
Zn-Zinc 1092
V-Vmadit.
Silver 1077
Al- Ahmuznmt 1105
Be 0iunt1012 u gLl
Ca- Cakium 916 m
Co- Cobalt 1037 u
FLL
Fe- hrnn 1045 yja
M--Mo um
Sb
Sn-Tilt UWL
TI-Thallium ustl-
Ti-Titanium
URI
H -1631 n
Li-Lithitart 1132 u
MR- MM110um 927
Mn-Man ese 1055 u L
Na- Sodi.929
Arseme-Total 1002
Se- Selenium 1147
li- Mercuty 71900 u
Ba-Barium u
lmme Pesticides
0qpnoph*2tL(MPesticides
Oqpzuinftopn Pesticide
Acid Herbicides
Ba3dNeu6al&Acid Extractable Or ics
TPH Diesel Ran
sable 2EMics VOA bottle 'd)
TPH Gasolme
TPHBTEX Gmaiine Range
vn
T an mri—I (IC):
7 0
" (�2rr mil. EIT.�aj'�,st, e 5

County:
FRANKLIN
River Basin
10
Report To
RROSP.
Collector:
AROMANSKI
Region:
RRO
Sample Matrix:
WASTEWATER
Loc. Type:
INFLUENT
Emergency Yes/No
COC Yes/No
`pS16 A
r�R pG
Loc. Desar.: NOVOCTMU
Sample ID: -,
A666106 .
PO Number#
1OW9766
Date, Received:
12102/2010
Time Received:
10:55
Lobworks LogWO
SMATHIS
Report Generated:
12/21110
Date Reported:
122//2112010
+
{� zz 1V
Location 10: NCGS001151NF
Collect Data:
1210112010
Collect Time:
11:50
Sample Depth
CAS #
LAB '
Analyte Name z''
Sample temperature at receipt by lab'
•"" Resu •
p ,Ar" Ih:,,,
/Qualifier
2.1
Units
'C
Method_
Reference
-.Analysis
Date
12010
Validated by
SMATHIS
MIC
BOO, 5-Day In liquid.
"• 2
2 U G8
mg1L
APHA5210B
12/11/10
MOVERMAN
WET
Ion Chromatography,
TITLE_
mg1L
EPA 300.0
1219/10'
MOVERMAN
Chloride
mg1L'
EPA 300.0
12010
'MOVERMAN
Fluoride "
0'4 ;I
0.8
mg1L
EPA300.0
1219i10
MOVERMAN
Sulfate
.2
20
mg1L
EPA300.0
1219H0
MOVERMAN
Total Dissolved Solids in liquid
12
96
mg1L
APHA254OC-18TH
1212110
CGREEN
NUT
NH3 as N in liquid
0.02
0.02 U
mg1L as N
LacIO-107-06-1-J
12/3110
CGREEN
Total Kjeldahl N as N In liquid
0,2
0.2 U
mg/L as N
Lachatl07-06-2-H
1217/10
CGREEN
NO2+NO3 as N in liquid
0.02 ".
0.02 U
mg1L as N
Lac10-107-04-1-c
1213110
CGREEN
Phosphorus_total as P in liquid
0.02 -.1 :
0.14
7 mg/L as P
Lac10-115-01-1EF
1213/10
CGREEN
MET
7440-22.4
Ag by ICPMS
5.
6.0 U
ug/L
EPA 200.E
1218/10 '
ESTAFFORDI
7429-90.5
AI by ICP
50
n,ES0 U
ug1L
EPA 200.7
1219i10
ESTAFFORg1
7440-38.2
.As by ICPMS
2
2.0 U '
ug1L
EPA 200.8
12/8110
ESTAFFOR01
7440-38-3
Ba by ICP
10
17
ug1L
EPA 200.7
1218/10
ESTAFFORD1
7440-41.7
Be by ICP'
5' {i
5.0 U
ug1L .'
EPA 200.7
12/9110
1-STAFFOR01
7440-70.2
Ca by ICP 0:1 ' i`' , ,t
' ' 11
mg1L
EPA 200.7
1218110
ESTAFFORD1
7440-43.9'
Cd by ICPMS
1 "' :'
1.0 U
ug1L
EPA 200,8
1218110
ESTAFFORD1
7440-48-4
Cobalt by ICP
50
50 U
ug1L
EPA 200.7
1219110
ESTAFFORDI
744.0.47-3
Cr by ICPMS;
10 ' i ' 10 U
ug1L
EPA 200.8
1218/10
ESTAFFORD1
7440-50-8
'Cu by ICPMS
2
21
ug/L
EPA 200.0
-1218110
ESTAFFORD1 .
7,439-89-6
Fe by ICP
50
50 U
ug1L.
EPA 200.7
1219110
ESTAFFORD1
7439-97-6
Hg 245.1 '
0.2
0.20 U
ug1L
EPA 245.1
' 12114110
ESTAFFORD1
7440-09-7
K by ICP
0,1r ;' i : ` �, :.. 2.5
y...>._
mg/L
EPA 200.7
1218110
ESTAFFORD1
7439-93-2
Li ICP
25 ':
25 U
ug1L
EPA 200.7
1218110
ESTAFFORD1
7439-95-4
Mg by ICP
0.1
3.3
mg/L
EPA 200.7
12/8110
ESTAFFOR01
7439-96-5
Mn by ICP
-10
10 U
uglL
EPA 200.7
12/9110
ESTAFFOR01
7439-98.7
Mo by ICPMS
10
10 U
ug1L
EPA 200.8
1218110
ESTAFFORD1
REUIV
U_
Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
For a detailed descripllor of the quallrier codes rater to h11RJ1VQrtai.nalenr�nrnhvohlwnLp�steYflnlahnr, p a li i c r r
,.' .. TPage 1 of.2
1 ...
C n n 2010
NC 1}ENR
Raleigh Regional NO '

VCtDq+ ,LaboratorySection(RSaults
Location ID: NCGS001151NF- Sample ID: AB88106 Collect Date: 1210112010 Collect Time:: 11:60
MET
CAS #
7440-23-5
AnalyteNarne-
Na by ICP
0.1
Resultl.
Qualifier
16
Units
mg/L
Meth
Reference
EPA 200.7
;Ana^ I�rs!s
Date
121B110
Validateo b
ESTAFFOR01)
7440.02-0
Ni by ICPMS
10'
j IOU
ug1L
EPA200,8
1218110
ESTAFFORDI,
7439-92-1
"Pb by ICPMS
10', r+'
:- 1 O U
uglL
EPA 200.8
12l8110
ESTAFFORDI,
7440-36.0
Sb by ICPMS
10"'
I IOU
uglL
EPA 200.8
12I8110
ESTAFFORD -
7782-49-2
Se by ICPMS
.5
5,0.0 .'
ug1L
EPA200.8
1218110
ESTAFFORDI
7440-31-5
Sn by ICPMS
10
., `r. IOU
ug1L
EPA200.8
1218/10
ESTAFFOR01
7440-28-0
Thallium (TI) 1CPMS
10
IOU
ug1L
EPA200,8
1218110
ESTAFFORDI
7440.32-6
Ti (Titan -sum) by ICP
10 '
10 U
ug1L
EPA200.7
1218/10
ESTAFFORD1
7440.62-2
V by-1CP -
25
25 U
ug1L
EPA 200.7
1219110
ESTAFFORDI
7440-66-5 . Zn by ICPMS
I
EPA 200.8
1218110 ESTAFFORDI
Laboratory Section>> 1023 Mall,Servlce Center, Raleigh, NC 27699.1623 [phone]
For a detated description at the quoErwr codes refer to hltnllnortnl.nafenr.nrnlwehAvnAahJslnllinfndechasshlsDare Qualifier Crotles,chlloWpodal ncoenr.aln+weh+walliWttaffinfuABChefalsl�
Page 2 of 2
• .- ii:it`r5i -

l Z)'V) gT56
DIVISION OF WATER QUALITY
Cb mistry
Laboratory Report I Water Quality
o �
y6 N�bv
eceive D. Rd
jar
Colnrty - _;_ : 1b, 0 1 (n _ YS148ITY
Tune Recewed
OVERRASFN: �p%}VIN
o
❑ AMBIENT
E3 QA -
STV,9AM
FFFLUENT
Recelite'd•By
REPORT TO
Rtgioral Office KCOMPLIANCE
CHAIN OF Ci3STODY
1 AKE
rRI MFLUi M
Otbier
Q EMERGENCY,
VISIT ID
ESTUARY
Data Messed
COLLECTORM :
—
�/
CJ�
Date Reported
Extim+trd ROD Rafter
��1—
�} 1- 9�
i1C %.VOID: c.� S � f O O� 6� 1�1Di SYLZ�I.J Statiaa Locatioe:�_�vo-_c �l•Yl
-
!
-
f
�� Lt�
Seed:
Clds arated:
Ressarks: � r 7 l� ✓� k'�
�' T
-
S4tioft /I.ocatipft Code
CG,5o0IST1vr
-
Date "a (yy ra/ddl
Data Ead Ito
o
'Ilse a
i �
Time Ead
: so
DgXh - DM, D% DBM
Valet: Type - A. H. L
Camst mite-T. S, B
Sam gle T
BOD 310
COD Hle 340
COD Low 335
Coliform- MF Fecal 31616 11001111
Coltfb mMF Total 31504 /IOQmI
Coliferm: tubc Fecal31615 /1001d
Coliform: Fecal Strep 31673 1100m1
Rcsiduc. Total 500 "
Volatile 505
Feed 510
Resider Suspmded 530 mgfL
Voimle535 '
Fixed 540 mWL
H 403 - units
Acidity to pH 4 5 436 Mal
Acidity to pH 8 3 435
AlUmity to pH 9,3 415
Allmlintry to pFi 4.5 41 O.
TOC 690 Mwt
Turbidity 76 NTU
ColiformToW Tulx /3Ooml
Chloride 940 UIJVL
■ EPA 445.0 pwdificd 2eon
Color: True a0 c-4,
Color: N 83 H= cu.
Cola. pM 7.6 82 C.U.
ide 72a
Fluoride 951
FonnalddTk 71880
Cave trd Ods 556 MPIL
Harut m Tow 9O0 Tai
Spmfic Conti 95 umhos/cm
MBAS 382150 MVL
Pheswls 32730
Sulfate 945 m
Sulfide 745 MOIL
Baron
Tam m a Ltpm'
Hexavalent Cbaomium
Bicubonate m
Carbonate m -
ToW Dissobred Solids L
NH3 as N 610 mgIL
TKN an N 625 m
NO2 pkis NO3 as N 630 m
P. Total as P 665
PO4 as P 70507
P: Dissolvtxl n P 666 mgfL
K-Potassismt MWL
Cd- Cadmium 1027
-
G-Chro nitaa:ToW 1034 Ed
Cw CcipM 1042
Ni-Nirkcl 1067 UEVL
Pb- Lead I O51
Zn-ZincIM
V-Vanadiuw ut
-Silver ID77
Al-Al.1105
Be- Rium to12 UVL
Ca- Calcitan 916 m
Co- Cobalt b037
Fe- Iron 1045
Mo-M
Sb-
Sn-Tat Uez
TI-Thallium tmrL
Ti-Titattium - u
1631 n
Li-Lithimn 1132 LqYL
Mg- Magnmimn 927 MEE
Mt Mwlswwse 1055 ug,L
Na- Sodium 929 '
ArsenieTwit] 1002
Se- Selenium 1147 a fl.
H - mcrcury 71900
- 13a-Bariian I.
2senochlonm Pesticide '
Orgmw3phosphorus Pesticides
Pesticides
Acid Hcrbicidcs
BasclNeuU-A&Actd Extractable ics
3PH Diesel Ran c
bleOrganics(VOA bottter 'd
TPH Gasalinc Ran
TPHMTEX GwIme Ran
Pbytoplanktan
Tcmperst= on arrival I �' F

County: FRANKLIH Semple ID; AI366109
River Basin TAB it t <bF WAT�q PO Number* 1OW9758
P
Re ort To RROSP .y taH°i�
ki,sF y Date Received: .12102/2010
Time Received: 10:56 -
Collector: A ROMANSKI _
Region: �O `; Lebworks LoginlD SMATHIS
Report Generated: 12/21/14
Sample Matrix: WASTEWATER Data Reported: 1212112010
Loc. Type: EFFLUENT.
Emergency •YOS]No VlsltlD
COC Yes/No 7
Loc. Descr.: NOVOFEHCTBD
Location ID: FEHCTBD - . I Collect Daietl" 1210112010 I Collect Time: 12:00 I Sample Depth
CAS # Analyte_Narne esul Units Method AnYalldated by
Qualifier Reference Date
LAB
Sample temperature at receipt by lab • u 2,1° 'C 121z110 SMATHIS
MIC
BOD, 5-Day in liquid.
2 • 2 mg1L APHA52108 12/11/10 MOVERMAN
WET
Ion Chromatography
" ' 14.
TITLE'I"
mg1L
EPA 300.0
1210110
MOVERMAN
Chloride
1
100
mg1L
EPA 300.0
1219110
MOVERMAN
Fluoride
0.4 ,:
=' 6.1
mg1L'
EPA 30o.a
1219110
MOVERMAN
Sulfate
2
160
mg1L
EPA 300.0
1219/10
MOVERMAN
Total Dissolved Solids in liquid
12
764
mg1L
APHA254OC-18TH
1212110
CGREEN
NUT
NH3 as IN in liquid
0.02 ; ..
.• '. OX
mg/Las N
LaC10-107-06-1-J
12/3/to
CGREEN
Total Kjeldahl N as N in,llquid Y
0.2 'ti,,,M''lii'
..; 1.7.
mglLasN
Lachat10706-2-H
5217110
CGREEN
NO2+NO3 as N in liquid
0.02
3.2
mg1L as N
Loci 0-107.04-1-c
1218/10 :
CGREEN
'
Phosphorus' total as P in liquid
0.02
2.2
mg1L as P
Lac10.115-01-1EF .
1213110
CGREEN
MET
7440-22-4
Ag by ICPMS
5
rc
5.0 U
• ug1L' ' .
EPA 200.8
12/8110 '
. ESTAFFORDI
7429-90-5
Al by ICP
50
50 U
ug1L
EPA 200.7
1219110
ESTAFFORDI
7440-38-2
As by ICPMS
' 2 • . i �,
22
ug1L
EPA 200.8
1218110
ESTAFFORDI
7440-38-3
Ba by ICP
:`. 10°a .,'
.
' : ' 100
ug1L
EPA200,7
1218110
ESTAFFORDI
7440-41-7
Be by ICP
5 :' :!
5.0 U
ug/L
EPA 200.7
1219110
ESTAFFORDI
7440-70-2
Ca by ICP
0.1
75
mgk
EPA 200.7
1218/10,
ESTAFFORDI
7440-43-9
Cd by ICPMS
.1 4
11.Q U
ug1L
EPA 200.8
1218110
ESTAFFORDI
.7440-40-4
Cobalt by ICP
50
5Q U •
ug1L
EPA 200.7
12/9110
ESTAFFORDI
7440-47-3
Cr by ICPMS
10
10 U
ug1L
EPA 200.8
,12/8110 ..
ESTAFFORDI
7440-50-8
Cu by ICPMS.
2
12
uglL
EPA 200.8
1218110
ESTAFFORDI
7439.89-8
Fe by ICP
5011""'. .?',
;;,q 250. '
ug1L
EPA 200.7
1219110
ESTAFFORD1
7439-97-6
Hg 245.1
0;2; e:: w rl}M''
0.20 U
ug11-
EPA 245.1
12/14/10
ESTAFFORDI
7440-09-7
K by ICP
0.1
29
mg1L
EPA 200.7
1218/10
ESTAFFORDI
7439793-2
Li ICP
25
25 U
ug1L "
EPA 200.7
1218110
ESTAFFORDI
7439-95-4
Mg by ICP
0.1
" 2ZJ
mg1L
EPA 200.7
1218110
ESTAFFORD1
7439-96-5
Mn by ICP
10
13
ug1L
EPA 200.7
1219110
ESTAFFORDI
7439-98-7
Mo by ICPMS
10
10 U
uglL
EPA 200.8
12116/10
'ESTAFFORD1
Laboratory Section» 1623 Mo 1 Service Center, Raleigh, NC 27699.1523 [phone]
For a eelailed descriollm of the ouaYrier codes refer io s..im$Dwa Qm0pr CnAns<1xra;Unr,rislnMenr.nmrwenlwoMNslaf
'
�2P2010
..Page 1 of 2,
NC UFNR .
Raleigh Regional -Office

""� NC (D'lVQ LaboratorySection vmi(ts
Location ID: FEHCTED Sample ID: A866109 Collect Date: 12101/2010 Collect Time:: 12:00
MCI
AS #
y44C-23-5 -
..
Analvte Name .
Na by ICP
.. r;•
:. ;'Result/
P k'''�
";a':- i4i ualifierM
0.1140
Units
mglL
Method_
Reference
EPA 200.7
Analysis
Date
1218110
validated by
ESTAFFORDI
7440-D2-0
Ni by ICPMS
10
100 %
ug1l,,
EPA 200.8
1218110•
ESTAFFORDI
7439-92-I
Pb by ICPMS
10 •' , A::.,
,�...74.0
uglL
EPA 200.8
1218110.
ESTAFFORDI
7440-36-0
Sb by ICPMS ..
�: 10
10 U .
•• . ug/L
EPA 200:8 .
1218110
ESTAFFORDI
7782-49-2
Se by ICPMS
5
66
ug1L
EPA200,8
! 1210/10
ESTAFFORDI
7440-31-5
Sn by ICPMS
1Q.
IOU
uglL
EPA 200.8
12JW10
ESTAFFORDI
7440-28-10
Thallium (TI)ICPMS
; 10"'E;t;' '.'•..,
10U
ug1L
EPA200.8
1218110
ESTAFFORDI
7440-32-e
Ti (Titanium) by ICP
10, '
AO U'
ug1L
EPA 200.7
1218/10
ESTAFFORDI
7440-62-2
V by ICP .
25
25 U
ug1L
EPA 200.7
1219110
ESTAFFORDI
7440-86-6
Zn by ECPMS
10 _.
"' 83
uglL
EPA 200.8
'1218H0
ESTAFFORDI
k!
. Ir,
lip
yl. ...
Laboratory Section» :1523 Mall Service Canter, Raleigh, NC 27699.1623 (9101 733.3008
For a detailed desuipllon of the qualifier Cedes refer to h 101p.Qrt11Itl 1plT'4jfo4fff;bpsijst#Qf1a Qualifier<hVr1#mrWin >
Page 2 of 2

DIVISION OF WATER QUALITY
f
t�istry Laboratory
Report 1 Water Qsstity
b Nmobet
�F/Y's� �i
SAMPf E TYPE
Date Received
COLTIP:Y
BAS(N:
f ✓j g$LQg�
fi AMBIENT QA
STREAM XEFFLUENT
Tom ReceivedRIVER
Recalved ByREPORT
TO
n Regular! OfF. COMPLIANCE CHAINOF CUSTODY
LAKE � INFLUENT
Odw
EMERGENCY
VISIT in
- El ESTUARY
Data Released
i
COLLECTORS) :
15k ut, Z5 r
Date Reported
Estimated ROD Raa=r
Stativa Locatiov: JV P 1/0 i( H 0 I T 6,
Y•h`
1 o[-tJ
L'oya�
Seed:
Chloe #Ad-
Rpaar4a:
(-00
statim!iLacative Code
Da4 Befin (3'y m/dd)
Date End ad
Time &jia Time End
Oept4 - DM, D$, DHM
Llue Type - A, A, L
Compmile-T, 5, H
pl Ty
J�n
00
HIP.-
HOD 310
Chloride 940 m
COD High 340 myjL
COD Low 335
Chlmoyfl ti EPA 445.0 modified
Coliform MF Fecal 31616 /loom]
Colifeem MF TaW 31504 /1009d
Color: True 8o c.u.
Ceilifar tube Fecal 31615 !loom[
Color EI 83 - H- c.u.
Colirmm: Fecal Swep 31673 /i oonil
Color: pH 7.6 82 c.o.
Residue. Total 500
Cyanide 720
Volatile 505
951
Fixed 510 mgfL
F 71880 m
Residue; S 530 mRfL
Grease and Oils 556
Volatnk 535
Hz*.n TOW 90D
Fixed 540 TngIL
S rtc Cond. 95 umhosi m
H 403 - mots
MBAS 39260 m
Acidity to pH 4 5 436 m
Pbesnb 32730 ug(L
Acidity to pH 8.3 435 mJvL
Sulfate 945
Alkalmity to RK 8 3 415
Sulfide 743
ARuhni to pH-4-5 410
Baron
TOC 680
Tam m & U in
:rwbidtty 76 NTU
Hexavalent Chromic 'L
Coldarm Total Tuts /100 ml
Bicarbonate
Carbonate m
-
Total Dmsohv d Solids m
23 as N 610
TKN an N 625 m
NO2 Eta NO3 as N 630
P- Total as P 665
PO4 m p 76507 MEVL
P: Dissolved as P 666
-potassium
ol
Cd- Cadmium 027 u
Cr1CbrMiure:Tura) 1034
C.-CI,;,1042
Ni-Nic3:el 1067 u
Pb- Lead 1051
Zn- Zinc 1092
V-Vanadium
FI
F
- Silver 1077
Al- Ahmun mn 1105
Be limo 1012 u
Ca -Calcium 916 m
C, Cobalt 1037 UWL
Fe- Iron 1045
MvM um u
Sb
S.-Tot
T)-Thallzum UEVL
Ti-Titzniu m ugft
H -1631 n
Li-Lith. 1132 uttl-
Mg- MWmi. 927 12191L
M.-M.P. 1055 u 'L
Na-S.&= 929
Arsrnic:Total1002 'L
Sc- Selenitmi 1 l47 u fl-
H - MacM 71 Wo
Bar Banutn u 1_
hlarim Pesticides
OqEnopbtsphorns pesitcidrs
Organonzogeti Pesticides
Acid Herbicides
BsulNmtral&Aud Extractable Orga,,ics
TPH Diesel Ran
tTyeable Or ics VOA bottle r 'd)
TPH Gasolinc Range
TPHlBTE{ Gasoline Rmse
lankton
L
G�
T On arrival (°C

0
0
County:
RA�LIN
River Basin
Report To
RROSP
Collector:
A ROMANSKI
Region:
RRO
Semple Matrix:
WASTEWATER
Loc. Type: '
EFFLUENT
Emergency Yes/No
COG Yes/No
Location ID: EFFLNDPOND
WA7'�,�G ..
4
VisIfID�. �Ic;
Loc. Dow.: NOVONOPOND
Sample ID: '
AB$6110
PO Number#
14W9759
Date Received:.
12102120110
Time Received:
10:66
Labworka LoginID
SMATHIS
Report Generated:
12/21/10
Date Reported:
12121/2010
12/01/2010 Collect Time:,
12:60 'Sample Dapth '
;+'
;`..p yf' ijj;,r° Resul :
Method
. Analysis
CAS #
Analvte Name .,
.. ,
��' 'Qualifier
U 1 s
vaudatad by'
;�
Reference
Date
LAB
r i
Sample temperature at receipt by lab
2.1 ''
°G.
12l2110
"' SMATHIS
MIC
BOD, 5-pay in liquid
M 2 9.1
mg!L
APHA5210B
12/11/10
MOVERMAN
WET
lon'Chromatography
i? ..7TITLE_
mglL '
EPA 300.0
12/8110
CGREEN
Chloride
mglL
EPA 300.0
12/6110 ..
CGREEN-
Fluoride
0.4 0.6
mg1L
EPA 300.0
12/6110
CGREEN
Sulfate '2 140
mglL
EPA 300.0
1216110
CGREEN
Total Dissolved Solids in liquid
12 1> , I$10..';'
mglL,.
APHA2540C-18TH
12.16110
MOVERMAN
NUT
NH3 as N in liquid
0.02 0.03
mglL,as N
1-6010-107-06-14
1213110
CGREEN
Total Kjeldahl N as.N in liquid
0.2 _ 6.1
mg1L as N
Lachat107-06-2-1-1
12UM0
CGREEN
NO2+NO3 as N in liquid
47 .
mg1L as N
Loc14-107-04-1-c
1218110
CGREEN
Phosphorus total as P in liquid
0.02 'r 79
mg1L as P
Lac10-115-01-1EF
12/8110
CGREEN
MET
7440-22-4
Ag by ICPMS
5 5.0 U
uglL
EPA 200.8
1218110
ESTAFFORDI
7429-90-5
Al by ICP
50 62'3
ug1L
EPA 200.7
1219/10
ESTAFFORD1
7440-38-2
As by ICPMS
Z 2.0 U
ug/L .
EPA 200.8
1218l10
ESTAFFORDI
7440-38-3
Ba by ICP
10 IOU
ug1L
EPA 200.7 .
1218/10
ESTAFFORDI
7440-41-7
Be by ICP
5;�.?7! ;,, =ri ..
5,0 U
uglL
EPA 200.7
? . - 1219110
ESTAFFORD1
7440a0-2
Ca by ICP
22
mg1L
EPA 200.7
1218/10
ESTAFFORDI
7440-43-9
Cd by ICPMS•
1
1.0 U
uglL
EPA 200.8
1218l10
ESTAFFORDI
7440-48-4 .
Cobalt by ICP
" 50 .
50 U
ug1L
EPA 200.7
1219110
ESTAFFORDI
7440.47-3
Cr by ICPMS
10 1-!-,,10,
tJ
u91L
EPA 200.8
12/8110
ESTAFFORDI
7440.50-6
Cu by ICPMS
2
3.1
ugli-
EPA 200.8
12l8110
ESTAFFORDI
7439-89-6
Fe by 1CP
50
53
ug1L
EPA 200.7
12I9110
ESTAFFORDI
7439-97-6
Hg 245.1
0.2 -, y 0.20 U
uglL
EPA 245.1
12114110
ESTAFFORDI
7440-09-7
K by-ICP
'"' 0;1. fir,';
600 '
mg1L
EPA 200.7
121810
ESTAFFORDi
,�..'!"I'I'
7439-93-2
Li ICP
25o "4'
25U.
ug1L
EPA 200.7
12/8110
ESTAFFORDI
7439-95-4
Mg by ICP.
0.1
2,3 +
mglL
EPA 200.7
12I8110
ESTAFFORDI
7439-96-5
Mn by ICP
10 "'�
10 U
uglL
EPA 200.7
1219/10
ESTAFFORD1
7439.98-7
Mo by ICPMS
10
10 U.
uglL
EPA 200.8
12I8110
ESTAFFORDI
tH
CEI11
Laboratory Sel:tlon>> 1623 Mail Service Center, Raleigh, NC 27699.1623 [phone]
Fora detallnd deacrlpllon of
the quallller codes refer to httn,!l�gy�l.nr.4r nr-�nmhvnhilwnlla l�ittii
r
! n !
!
2010
Page 1
of 2
ND DENR
:.
Raleigh Regional Office

NC eDq4,2 Laboratgry Section �Zrsults
Location ID: EFFLNDPOND Sample 10: j. Collect Date: 12101/2010 Collect Time:: 12:80
MET t ,
L Result/
Method
AnaNsis
CAS # Analyte. Name
Un' s
ualifier
Reference
Vaildated by
Date
7440-23-5 Na by ICP' '
0.1 130 mg1L
EPA 200,7.
' 12/8110 ESTAFFORD1
7440-02-0 Ni by JCPMS
10?'''x" '•' :;, IOU ug1L
EPA200,8
12/8110 ESTAFFORD1
7439.92-1
Pb by ICPMS
1Q U
u97L ' '
EPA 200.8
1218/10
ESTAFFORD1
7440-36-0
Sb by ICPMS.
10
IOU
uglL
EPA200.8
1218/10
ESTAFFORD1
.7782-49-2
Se. by ICPMS
5;
;. • 5.0 U
ug1L
EPA 200.8
12/8110:
ESTAFFORD1
7440-31-5
$n by ICPMS
" ' .' 10
tf" "(Q'U
uglL
EPA200.8
1218M0
ESTAFFORD1
7440-28-0
Thallium (T4) ICPMS
' 10
IOU
" ug/L
EPA 200:8
,1218I70 .
ESTAFFORD1
7440-32-6
Ti (Titanium) by ICP
10
IOU
ug/L
'EPA 200.7
i • 1216i10
ESTAFFORD1
7440-62-2
V by JCP '
25MG,,..7� .:�.
r, 25 U
ug/L':
EPA200.7
1279/10
ESTAFFORD1
7440.66-6
Zn.by ICPMS
"'
240 -,
ug/L .
EPA200,8
12/8110 .'
ESTAFFORDI
r'
lien,.
:L.
Laboratory Secllon>> 1623 Mall Service Center, Raleigh, NC' 27699.1823 [phone]
For a detRaed desalption of 1he qualllfer codes refer 10 Kip -Nllo tnl ncdenr OrplweGrW n8bJ4Saftlnto.'lectlasslslllf]ala Qunlifinr (�'Q�pS <IIIlellflennl OfYlenr.010NIHNMNrIFSbie101hMa[CChneSV31> '
;�u.•"'..:. Pape 2 of 2

100 �A,5�
DIVISION OF WATER QUALITY
Chenth" Laboratory Report I Water QuAity
❑ SAMPLE TYPE
COUNTY I � t�RLY
RIVER BASIN : ❑ AMBIENT QA STREAM I JY EFFLUENT
REPORT TO ^ Regional Office )R COMPLIANCE CHAIN OF CUSTODY LAKE ❑`-" INFLUENT
Other - ❑ EMERGENCY VISIT ID [D ESTUARY
COLLECTOR(S) : , a� ` �� ❑
i'
Up Numbs
Date Received:
'
f t� • i/ 0
Time Received :
O�r
✓,J
Received By
Data Meased
.
Date Reported
Estimated ROD RanLc Station Location: / vU U L11V V 0
Seed: � Cibriaated: Reauriu: _
Station #A ocat' a Code Date (yylm dd) Date $ad (yy/ ail Time lactic Time End Depth - DM, DB, ASH Vale Type - A, H. L Composite-T, S, B
F;4Ls �f) i9DAj,n IID �� � to ii2 t 1�-5o J� s°,
B0D 310 m
COD High 340 m
COD Low 335 MBIL
Coliform- MF Fecal 31616 /100m1
Colifarrn: MF Total 31504 /100qu1
Co iform: tube Fecal 31615 1100m1
Coliform. Fecal Shrp 31673 - /I00m1
Residue: Total 500
Volatile 505 m
Fixed 514 VL
Residue: Suspentled 530 m
Volatile 535
Fixed 540 m
H 403 units
Acidity to pH 4, 5 436 mgL
Acidity to pH 8.3 435 m
Aikaliniry to pH 9.3 415
Alkalini to H4.5410 m
TOC 690 m
Tmbidi 76 NTU
Colifmm Total Tube 1100 tal
Chloride 94o mgtL
Chlorophyll a EPA 445.0 modified option gLL
Color. Tnae 80 CA
Color: H 83 H- C.U.
Color-. pH 7.6 82 c.0
ide 720 m
Fluoride 951
Famaldchyde 71880 m
Grease and Oils 556 mBi
Hardtteas T0a1900 m
Spccific Cond. 95 umhos/cm
MBAS 39260 MVL
Plimals 32730
ulfate 945 m
Sulfide 745 m
Baron
Taru�in & Li in UELL
Hcxavalent Chromium usfL
Birarbtmare mSIL
Carbonate Mall,
Total Dissolved Solids MSIL
NH3 as N 610 m
TKN att N 625 m
NO2 phis NO3 as N 630 m
P: Total as P 665 m
PO4 as P 70507 m
P: Dissolved as P 666 MwL
K-Potassium m
Cd-Cadmium 1027 u
Cr-CFnomium:Tota11034 ugfL
Cu-C f042 uglL
Ni-Nickel 1067 u
Pb- Lead 1051
Z, Zinc 1092 ai
V-Vanadium ugfL
AR- S',I w 1077
Al- Altananan 1105
Be- Bylh. f 012
Ca- Calcium 916 m
Co Cobair 1037 ugfL
Fe- fron HX5 uRIL
M.-M.. u
56-Anti u rl-
SurTin
Tl-Thalhurn u
Ti-Titaniumt u
1631 ngfL
Li -Lithium It 32 ug/L
Ms- Magricsitan 927
Mn-Mangwesc 1055 u
Na-Sadn. 929
Arsenic:Tota11002 UFA
Sc- Selenium 1 147 u
H - Mercury 71900 USX
Ba-Basivau u
achlorirue Pesticides
Or hos horus Pesticides
Orgaticeii"llen Pesticides
Acid Herbicides -
BasilNouuai&Acid Extractable aaics
TPH Diesel Ran e '
Purgcablc Dr ics VOA bottle r 'd)
TPH Gasolate Range
TPMTEX Gasoline Range
lankton
iTei,perature on arrival (^C

County:
FRAM LIN
Sample ID:
ABS6108
RIvor Basin
OF WArE4'
" lit ¢ ;j
PO Number#
10W9757
t ReporTo
RROSP
.0� " •`
Date Received:
1210212010
Collector:
A-ROMANSKI
Time Received:
10:55
a `s
Labworks LaginlD
SMATHIS
Region;
RAF O
,.
Report Generated:
12I21110 '
Sample Matrix:
SURFACEWATER
"-.•;"'
Date Reported:
1212112010
Loa Typa:
RIVER/STREAM
Emergency•Yes/No
VIsRI1)
COC Yes/No
Loc. Dascr.:, N,�( VONDOWNSTREAM
+
Location ID:
WILLMITCHNERRID
CollecfDate;'''-,_ 12101/2010
Collect Time: 15:30 ,
Sample Depth
Result/
Method
Analysis
CAS #
Analyse Name
Units
yalidated_bY
.
ualifier
Reference
Date- •
LAB ,
Sample temperature,at receipt by lab
Jj'''."''"' ;';2.1
°C
1212110 SMATHIS .
MIC
;.
BOO, 5-Day in liquid ,
2 2.2
m91L APHA5210B
12/11/10 MOVERMAN
WET
I h h
T
no/L EPA 300 0
1216110 CGREEN
on C romat
ograp y
Chloride
Fluoride
Sulfate
Total Dissolved Solids in liquid
NUT
g
EPA 300,0 12/6110 CGREEN
tIL EPA 300.0 1216110 CGREEN
'L EPA 300.0' 1218110 CGREEN
APHA2540C-IBTH 1212/10 CGREEN
NH3 as N in liquid
Total Kjeldahl N as N in liquid
NO2•+•NO3 as N in liquid
D D;,
©, S
„t
1.3
s N
mg/L as N
mg1L as N
Lac10-107-06-1-J
Lachat107-O6-2-1-t
Loc10-107.04-1-c
1213110
12/10/10
1213110
CGREEN
CGREEN
CGREEN
Phosphorus -total as P in liquid
0.02
0.23
mg1L as P
Lac10-115-01-1EF
1213/10
CGREEN '
MET
7440-22-4
Ag by ICPMS
g
5 ?: „s':}
;..y> .; , 5.0.0
ug1L
EPA 200.8
1218/10
ESTAFFORDI
7429.90-5
Al by ICP
50 '"pit, i�1' 200
+
ug/L
EPA 200.7
12/9/1a
ESTAFFORD1
7440-38-2
As by ICPMS
2
2.0 U
ug1L
EPA 200.8
12I8110 ESTAFFORDI.
7440-38-3
Ba by ICP
10
- -
~. 1, 100
ug1L
EPA 200.7
121B110
ESTAFFOR91
7440.41-7
Be by ICP
5
5.0 U',
ug1L
EPA 200.7
.1219/10
ESTAFFORDI
7440.70-2
Ca by ICP
,. 0.1
17
mg1L
EPA 200.7
12/8110
ESTAFFORDI
7440.43-9
Cd by ICPMS
1
. 1.0 U
ug1L
EPA200..8
1218/10'
ESTAFFORDI
7440-48-4
Cobalt by ICP
50;1 "
SO U
ug1L
EPA 200.7
12I9110
ESTAFFORD1
7440-47-3
Cr by ICPMS,
10.'-:'" '''', IOU
ug1L
EPA 200.8
121fl/IOL
ESTAFFORDI
7440-50-8
Cu by ICPMS
2 •
2.0 U
ug1L
EPA 200.8
1218/10
ESTAFFORDI
7439-69-6
Fe by ICP
50
�. 1500
ug1L
EPA 200.7
1219110
ESTAFFORDI '
7439.97-6
Hg 245.1
0.2 „," , ,0.20 U
ug1L
EPA 245.1
12/14110
ESTAFFORDI
7440.09.7
K by ICP
' 0.1
10
mg1L
EPA 200.7
1218110
ESTAFFORDI
7439-93-2
Li 1CP
25
25 U
ug1L
EPA 200.7
12! 110
.. ESTAFFORDI'
7439-96.4
Mg by ICP
0.1
5A
mg1L
EPA 200.7
1218/10
ESTAFFORDI
7439-96-5
Mn by ICP
.. 10'`�-,;, '•
,.'�:; 120"
Ug1L
EPA 200.7
1219H0
ESTAFFORDI
7439-98-7
Mo by ICPMS
10. •`'' r'
" IOU
ug1L
EPA 200.8
12/8110
ESTAFFORD1
Laboratory. Soctlon» 1623 Mall Service Center, Raleigh, NC 27699.1623 [phone]
I'
For a detailed dwriptloll of the Cj1191lr1af Codes refer 10' T 11 Ia.11rflell f 1 1 i t 1 I -I 9< 1'. 1 f ! r
Page 1 of 2
R
ULU 2 9 2010
"NC DENR
Pafeigh Reqional Office

i NC(D`VQLaboratorySection(Rvsizfts
Location ID: WILLMITCHNERRD Sample AB66108 Collect Data; 12/0112010 Golfed Time:: 15:10
MET F;
M1 :; r Result/Method
'knits
na is
CAS #
Analyte Name
P L
, Vatidated by
ualifier
Reference
Date
7440-23.5'
Na by ICP
0.1 18
mg1L
EPA 200.7
1218110
ESTAFFQRDI
7440-02.0
Ni by ICPMS
10. IOU
ug1L
EPA200.8
12/8110
ESTAFFORDI
7439-92-1
Pb by ICPMS
10 IOU
ugrL
EPA200.8
1218110
ESTAFFORDI
7440-36-0
Sb by ICPMS
10 10 U
ug1L
EPA200.8
1218110
ESTAFFORDI
7782-49.2
Se by ICPMS `
5;; , .ji.,.r;t _;. 5.0 U
uglL
EPA200.8 ,.
1218110.
ESTAFFORDI
7440-31-5
SD by ICPMS
10�,,m' fl+- i .19U
ug1L
EPA200.8
12/8110
ESTAFFORDI
7440-28.0
Thallium (TI) ICPMS
10 IOU
ug1L
EPA200.8
12/8110
ESTAFFORDI
7440-32-6
Ti (Titanium) by ICP
10 -10 U
ugrL
EPA 200.7
' ' 12/8110
ESTAFFORDI
7440-62-2
V by ICP
25 25 Y
ug1L.
EPA 200.7
12/9110
ESTAFFOR01
7440-66-6
Zn by ICPMS
tc' 10 10 U
ug1L
EPA 200.8
1218110
ESTAFFORDI
Laboratory Sactiana> 1623 Mall Service Center, Raleigh, NC 27699-1623 [phone]
Fora detailed description of the quallfler codes refer to htimilli2ctel nodritf 011olifirrs � - I
Page 2 of 2'

CGuwTV -
iE• `t f-i
RIVER BASIN
REPORT TO
4 Regional Office
Otlscr
o
• COLLECMR(S) :
..- e,..74B/Ls rfrt- -
Eafmated ROD Raab .
Seed_
-47btariaaeed:
D 314 M94-
COD HtAh 340
COD Lars 335
Cefiform'. MF Fecal 31616 /loom]
Colifarm MF Total31504 lI00ml
Colifnrm- tube Focal 31615 /100tu1
Coliform: Fecal SVrp 31673 /100m1
Residue. Total 500
Volatile 505
Fixed 310
Resrdue, Suwerbded 530 mFVL
Volatle 335 MWL
Fucd Sao MWL
H 403 units
Ac,dity to pH 4.5 436
Acidity to pH 8 3 435 TOO-
AlkahniTy to pH9.3415
Alkalinity to 9H 4 5 410 mwL
TOC 680
Twbidny 76 NTU
Coldoun Top! Tube lF00 to!
DWiSION OF WATER QUALITY
C7semdWy Laboratory Report / Water Quality
El SAMPLE ME
AMBIENT E3QA ST'4LFAM El EFFLUENT
',�CGMPUANCE CHAIN OF CUSTODY LAKE INkUENT
EMERGENCY VISTTIU NARY
Sgtiaaluntioe_ �vyo 4�Occlii�Y' <
Chloride 940 MWL
Chi a EPA 445 0 modified
Color. True 80 c
-
Cokw: H 83 c.u.
Color: ptl 7.6 82 c.u.
Cywudu 720 ut
Fluoride 951
Fvrma4 71$80
Crease and Oils 556
Hardnen Total 900
Spec&u Cmtd. 95 umhaslcto
MBAS 33260
Phenob 32730
Sulfate 945
Sulfide 145 MWL
Baran
Tamin
Haavalud Clvotm= u
Btewbonate m
CarbrnateMWL
Dial Dissohed Solids
'
NH3mN610
TKN an N 625
N02 phu NO3 as N 630 m IL
P. Total as P 665
I
PO4 as P 70507
PDissolved as P 666
K-Potassium
Cd- Cadmhan 1027
Cr1'hroraium:Total F034 u
Cu- C I042
Ni-Ntckcl 1067
Pb� Lead 1051
Zto- Zinc1092 PEEL
V-Vanadium
- Sily 1077
Al- Ahmr— 1105
Be- Ekryflim 1012 UWL
Ca- Ca cimo 916 ro
Co- Cobalt 1037
Ft- Iran 1045 ti.
mmdybd. USIL
Sir fl,
Sn-Tin u L
T?_ U911,
Ti-Titanium v
1631 n
lab Number
'
Date Re"mcd
e!
Tmie Received
Received By
D 5
Data Relcased
Date Reported
Li -Lithium 1132 us"],
mg- iuro 927
Mn-Manwmese 1055 u 'L
Na- Soditan 929 nE
Arsenic'ToW 1002 1
Se- Selenium l 147 WrL
Ns- mercn 71900 U91,
8a-Batum u 'L
iorine Pcs[icrdcs
Or horns Pesticides
Organontbwen Pesticides
Acid Hcrbim&3
8a3e/Neuual&Acad ExtractabieOraamc
TPH Diesel Ran c
cable Or ies VOA bottle • 'd
TPH Crasaline ltan
TPHlBTFY Gasoltne RanSt
P i lankton

l
LAGOaN 2
N DISCHARGE WASTEWATER MONITORING REPORT
I'}:RIti'I'SUV11tER: WQ0 SG6 MONTH Stptember
FACILITY N'A%IF.; Novo mes N, th America, Inc. CLASS: 2 COUNTY:
Page 1 of I_
YEAR: 201(1
FRANKLIN
12Sarnol
I
l
t�pclplur
Arna111
'kmc 2.100
Cluck
htxremi
'I'inie un
Sile
ORC
On
Sile".
40000 00940
7 0,0
6i0.000
530 70300
9290
1 916.0 1 927,00 1 931,00 1 620.00
r,23,0
665.00
Daily Rate
(Flow) into
Treatment
system
ada he DOW
DriOrtoInIoefionf11£�31hf-
Tl r
i i4P.
1'KN
Pha urus
I{
Chloride
BOD-5
20 C
NH3•N
rSS
TDS
Na
Ca
Mg
SAR
NO3•N
IIRS
I YIN
MGD
UNITS
M01L
MG/L
MOIL
MOIL
MOIL
MO/L
MGlL
MOIL
MQL
M(llL
MG1
1
0800
: 8.0
:'. ;'
:'.0:635::::;:$
13::::
:::::
::..::.:.::
: :.'.::.:.::::::....:::::::
,.:;::,:;::;::::
2
0800
8.0
Y
0,804
8.16
3
0800
.. 8:0
:Y .
:':0:687.:::812.
..
1
0.725
6
0800
8.0
Y
0,707
8.10
7
0800
,, : •8;0
:�•�Y `�
': '0:55G�� �
�:�822:'.
�:;';:�:.'.:�:.:.
�:�:.•,:::.:..:
�•::• • ' � ':'
�:�: '�'�:: '•..'.:,:•'
:::
��.•::• ....
.
8
0800
8.0
Y
0.655
8.23
330
12.0
1.500
28
2100
153.0
22.8
4.60
7.62
12,00
6.7
50
u
ON
. , 8:0
. Y
0:580.:
' '8:28`
:: :: :'
:: ':
1(1
0800
8.0
Y
0,599
12
0.571
13
0800
8.0
. v
0:657::
: 8 39:':::
::::::':':::`
::
. :: : ::: :::.:.:...:.::::::::::::..
......::
1 i
0800
8.0
Y
0.446
8.43
15
o8w
8.0
V'.
':0.638:.
:'8:1 2
16
080o
8.0
Y
0,532
8.07
171
1180O
9.0
,::•:y.:;.:.':�:6f31
::
: 8 1 }:::::::::>
:::::::::
::::::::::::::::::::::::::':::,:;:.::::;
:;:.:::.:,:.::::,
;::;:
;::;;;:.:.: ;:::;:;
::, ::
:::': ' ::::
.: ;: ; .
::
181
0.510
20
0800
8.0
Y
0,634
8,09
21
0800
' KOY
:
'.'0:63(f'.'•'
':' 8.h7.':::.:.'.'•'
.';
:::'' ::.':::
',': .':',';;
::.'< .'.':.:
.':•>.':
'''.'' .'.•, .'
.':', :.
22
U800
8.0
Y
0.532
8.94
2-10900
9.0
Y,.-
:'0362:';::.:&56.:'
:: ::
; 8a}':':::4:640:
'
;:• :.::.:;
:: '
.
720
5,7
45
2.1
0800
8.0
Y
0.625
8.63
r,
0,680
27
0800
8.0
` y
:O:7f?8:
: 8:52 ::'::'::
::::::
:': ::::':::::::::':;
:'::.....:::.
.::::.:;
28
0800
8.0
Y
0.661
8,59
,,I
(J800
9.0
r:':.`0:836:!'"
.42.
...
;I]
0800
8.0
Y
U.9?7
8.56
��'F:ItAGE
0,628
NIA
10.0
1.070
28
NIA
153.0
22.8
4.60
7.62
9.60
6.2
47.50
alAxtsluM:....' :::':0:927::::::8
y4::
NIA
:: a2aa :'
:':T:504::::<:
28 ::
.:N/A':;::::1:53;A':
22:$::.
:` :60:':::::7:62:.
'':12,00::::0,7:
50-00..
�1rvl�tukl
0.432
8.07
NIA
8.0
0.640
28
NIA
153.0
22.8
4.60
7.62
7.20
5.7
-15,00
�lunthl .Limit..
('urnnsilc (C crab(
! CI
G
NIA
G
G
G
NIA
G
C
G
G
G
G
U
A AFI'tc:1 r UrIN E'N L.ItAKIiG tUlILL) KAINU7 4.k;ILtrl rr GKAUP .f ruunlr. (viv)4vw-.»yv
CHECK I3OX ] h ORC HAS CHANGED 0
('ha T11:11-:I) LABORA-MRIES (1) ENCO (2)
1'1i14SONtS) ('OI.I.f'C'1'IN(r SAMPI,ES: Runde Cutchin
,i0r+RhfINA1.and TWO 00P1 Nto:
A I"1 \; ('(INIPLIANCE GROUP
lilt.OF h:NVIRON'.NIF..vTAE. NIANAGENIENI'
PI-AINR
P.O. 15OX 2953S
RALEIGII, NC 27626-0535
NDIOR-I (7:94)
Y 4,64 t%VL� -
(SI(WA,rURJ1 OF OPEYATORi RFSPONSI i0KNOWIXI)GE,
E) RECEIVED
BY THIS SIGNATU �� �RT IS ACCURATE ANT) CO I
OCT 2 8 2010 NOV - 1 2019
Inlo(mation ptocessiA Unit NG OENR
D\N0jB0G Raleigh RagiOrlar Otfir,n

r , .
Cooling Tower Flow Totals
Start
End
Time interval
0
Gallons
8/15/2010
1d
Date
FEH Cooling
FEH Cooling
Delta
FEH cooling
Total based on
tower city
tower city
tower
flow rate
water makeup
water makeup .>
blowdown RT
based on
based on flow
running total
rate
15-Sep-10 00:00:00
139,168
138,437 '
731
12,292
12,161
14-Sep-10 00:00:00
169,783
170,637.
-854
37,523
37,202
13-Sep-10 00:00.00
147,448
144,075
3,373
20,000
19,896
12-Sep-10 00:00:00
111,312
113,738
-20426
1,364
1,275
11-Sep-10 00:00:00
97,188
97,632 ..
` -444
936
885
10-Sep-1000:00:00
117,748
117,942 ''.
. =194'
2,369
2,252
09-Sep-10 00:00:00
1310228
131,115
114.
1,496
1,431
08-Sep-10 00:00:00
1620681
161,868 `:
8.1311
32,101
32,229
07-Sep-10 00:00:00
1650927
166,050
-123'
28,812
28,676
06-Sep-10 00:00:00
196,965
196,813
151.
10,795
10,817
05-Sep-10 00:00:00
155,047
155,605'..°
-558
12,308
12,325
04-Sep-10 00:00:00
1660356
166,364 !`:
-8
36,830
36,804
03-Sep-10 00:00:00
151,325
151,605
_ -280,:
27,328
27,221
02-Sep-10 00:00:00
126,783
126,274 ;;,.
509'
21,559
21,554
01-Sep-1000:00:00
186,978
186,325'
653
71,895
71,181
31-Aug-10 00:00:00
187,282
186,620
662'
71,606
72,327
30-Aug-10 00:00:00
177,360
178,501
-10142
27,737
27,686
29-Aug-10 00:00:00
142,572
142,753 .:
-182
15,674
15,735
28-Aug-10 00:00:00
146,996
147,312
-316;
26,034
26,300
27-Aug-1000:00:00
116,886
117,121 '.
-235
20,045
20,068
26-Aug-10 00:00:00
127,056
r.
1260757 ::
299
20,495
19,602
25-Aug-10 00:00:00
118,256
118,895
. -639
15,952
16,689
24-Aug-10 00:00:00
99,769
99,441 `
328
11,426
11,339
23-Aug-10 00:00:00
96,375
97,146
-771
12,681
12,676
22-Aug-10 00:00:00
114,234
114,297
-63
16,089
16,124
21-Aug-10 00:00:00
97,662
970056
607�
14,346
14,357
20-Aug-10 00:00:00
79,409
800261
-852
5,456
5,478
19-Aug-10 00:00:00
74,852
74,529
324
11,467
11,428
18-Aug-10 00:00:00
83,329
83,779 -=
-449';
18,369
18,342
17-Aug-10 00:00:00
112,760
112,893
-133
20,441
20,402
16-Aug-10 00:00:00
66,029
66,148
-119
10,308
10,307
15-Aug-10 00:00:00
114,367
114,455,
-87,
9,223
9,214

FFI cooling
tower city
water makeup
RT
60,126
46,420
58,320
50,853
39,644
58,424
45,349
69,594
87,416
94,876
82,774
100,413
104,011
93,236
78,979
21,987
497
0
0
716
1,119
0
0
0
612
748
14,135
0
3,611
25,707
38,901
32,636
FFI cooling
tower city
water makeup
based on Flow
Rate
87,762
67,013
83,126
63,909
65,341
89,836
72,206
82,079
100,391
104,606
92,665
103,278
110,716
93,596
87,306
24,787
498
22
9
681
1,137
53
13
18
643
688
23,333
0
6,801
40,953
71,286
46,692
FFI cooling
tower
Blowdown
baed on
running total
8,924
4,735
10,239
6,469
6,817
7,042
1,967
14,480
27,992
33,312
35,026
36,007
33,126
34,895
17,039
2,047
0
0
29
5
33
86
1,124
3,163
3,252
4,977
4,161
4,496
9,200
18,374
0
0
FFI cooling
tower
Blowdown
baed on flow
rate
11,850
9,534
12,603
7,025
7,392
12,236
2,477
13,797
31,643
36,494
36,444
36,343
36,370
36,532
18,374
2,123
6
11
120
51
99
153
1,232
3,768
4,120
7,328
6,823
5,359
8,816
21,992
5
1

i
{k
Delta
FHG Cooling
FHG cooling
tower city
tower city
j
water make up
water makeup
Ned on
based on flow
running total
rate
i
-2,9261
0
-267,693
-4,8001
0
-267,962'
-2,3641
0
-268,0561.
-556;
0
-267,793.
-574i
0
-268,034
-5,194{
0
-267,754'
-510`
0
-267,624
683'
0
-267,890
-3,651,
0
-267,955.
-3,183!
0
-267,919
-1,4181
0
-267,927
-33&
0
-268,099
-3,244'
0
-268,040'
-1,637`
0
-267,990
-1,335iF
0
-267,974
-76E
0
-267,721.
-6;
0
-267,282
-11
0
-267,3241
-91',
0
-267,532
-46`
0
-267,016
-66`
0
-261,696
-67
0
-201,728,
-108:
98,544
46,888 ;
-605r
131,952
156,740
-869i
312
-119,898;
-2,3503
0
-46,114'
-2,66Z
272
36,359
-863
206,080
411,574,
384�
752,200
1,080,000
-3,618j
752,528
1,080,000
-5,
752,832
1,080,000�
-1;
751,848
1,080,000
Delta
FHG cooling
i tower
Blowdown
baed on
running total
267,693
267,962'
268,0561
267,793
268,034
267,754
2 67, 624
267,890.
267,955.
267,919
267,9271
268,099'
2681040'
267,990'
267,974,
267,721
267,282;
267,324;
267,532.
267,016;
261,696
201,728'
51,656:
-24,788
120,210!
46,114
-36,087
-205,494-
-327,800;
-327,472:
-327,16&
-328,152'
3,249
4,833
2,529
4,795
4,304
2,812
2,393
4,745
3,763
4,080
4,497
4,635
7,623
3,271
5,343
7,785
7,021
5,387
6,101
3,654
0
10,416
1,418
6,855
6,135
8,549
7,113
5,458
8,213
6,939
0
0
FHG cooling
tower
Blowdown
baed on flow
rate
3,524
5,231
2,7611
5,216;
4,668;
3,102,
2,574:
5,060,
4,064
4,4681
4,9271
5,0451
8,176,
3,308
5,393,
7,795
6,841
5,296
5,986
3,543
-4
10,084
1,3711
6,586 i
5,887
8,252
7,144
5,253
7,993;
6,857
-4,
-4
delta
1
-274�1
-3981
-232
-421 1
-364:
-290
-1$11
-316
-301
-388
-4301
-410
-553
-37
-50 i
-101
180
91!
115<
111
4
332
47
270'
248.
298
-31,
205
221'
82 i
41
4

Permit # NCS000115 Month: December. Year: 2010
Facility: NOVO mes, NA, Inc. Class: County: Franklin
ORC: Grade: ORC Certification #
Has,ORC Clanged?: i' Phone: [phone]
Certifed.Lab Name: Prism Laboratories Lab#:
Person(s) Collecting samples: Houston,Cash, Joe Ladd
Comments: Effluent -collected fromFEG cooling tower at 1308; analyzed at 1310.
Sampling Location: Effluent Discharge #
VEO
DER
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I
Permit # NCS000115 • Month: December Year: 2D10
Facility: Novoz mes,'NA, Inc. Class: County: Franklin
ORC: Grade: ORC Certification #
Has ORC Changed?: r Phone: [phone]
Certifed Lab Name: Prism Laboratories tab#:
Person(e) Collecting samples: Houston Cash, Joo Ladd
Comments: Effluent collected from FHG cooling tower at 1338, analyzed at 1341.
Sampling Location: Effluent Discharge #
t"IECEIVE®
FEB 1 12011
NO DENR
RaNgh Reaional Of f
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�■■
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Permit # NCS000115 • Month: December, Year: 2010 •
Facility: Novozyi-nes, NA, Inc, Class: County: Franklin
ORC: Grade: �ORC Certification #`
Has ORC Changed?; r Phone: [phone]
Certifed Lab Name: Prism Laboratories Lab#:
Pereon(s) Collecting samples: Houston Cosh, Joe Ladd
Comments: Effluent collected from FEH cooling tower at 1320, analyzed at 1322.
Sampling Location: Effluent Discharge #
RECE1 VED
EER 1 12011
Nclati
'?*k Rea on i nfgce
-----
1 1 1
1 1 1 1
1 11 1
i l: l
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Penmit #' NCSOOO115 Month: June Year: 2010
Facility: Novozymes; NA, Inc. Class: County: Franklin
ORC: Grade: ORC Certification #
Has ORC Changed?: r Phone: [phone]M
Certifed Lab Name: Prism Laboratories Lab#:
Person(s) Collecting samples: Houston Cash, Joe Ladd
Comments: Effluent collected'from Cooling Tower FHG at 1449, analyzed at 1458
Sampling Location: Effluent Discharge #
:.:��.
Daily
�rn�����■r�

Permit # NCS000115 Month: June Year. 2010
Facility_ Nnvo mes„NA, Inc. Class: County: Franklin
ORC: Grade: ORC Certincatlon #
Has O.ft.0 Changed?: . 17, Phone: [phone]D
Certifed Lab Name: Prism Laboratories LabO-.
Person(ej Collecting samples: Houston Cash. Joe Ladd
Comments: Effluent collected from Cooling Tower FEH at 1411. analyzed'at 1422
.-...
Samplirig,Location: Effluent Discharge #.
RECEIVED
FEB 1 12011
Rafeigh eaionaloft
■■ice
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Mon*WAVerag:
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Permit # NC5UU0115 MOrIthr June. Year: 2010
Facility: Novozymes, NA, Inc. Class: County: Franklin
ORC: Grade: ORC Certification # KOM
Has ORC Changed: r Phone: [phone] FEB I 17011
Certifed'L.ab Name: Prism Laboratorles Lab#: HOW
Person(s) Collecting samples: 'Houston Cash, Joe Ladd
�e4elah �aafanal ilt�cs
Comments: 9#16ont collected from Cooling Tower FEG at 1355, analyzed at 1402
Sampling Location: Effluent Discharge #
Aver -age Limit
DailyMonthly
:
1
Monthly Avg . :
----
- ! 1

W
Emergencies — Ext. 2222 Site Map 1 Evacuation Gathering Areas Security — Ext. 3220
LEGEND
A Evacuation Area for FIH
B Evacuation Area for FHG. FGH. FFF. and FFG
C Evacuation Area for FHI and FFI
D Evacuation Area for FFK
E Evacuation Area for FEI. Eng. & Env. Ops. ................
F Evacuation Area for
G Site -Wide Evacuatioa Are
H Emergency Evacuation Crates
Ammonia Alarm "Shelter in Place" Locations
Coaling Tower
Chiller Buildin
A-oi�
(FF ) T
i
Receiving
Warehouse
Receiving Office
Ext. # 3248
Contractor "Trailers
utility
Control
(FFG) Room
Fermentation
Co"trc Room
Lt. 4 4300
trol Roo
E t. # 4370
(FGH) . Pilot Plant
(Fence Line)
....................
Waste Water
Lagoons
Utilities
Building
Control Room
Ext. # 4600 ❑ O
Recovery
. (FFI)
Control Room
Ext. # 4400
* conaol
Shipping Warehouse
/ Granulation Tower
(FFK)
07
�I L
.. . ...............
(P
Production Admin &
Employee Sv
Building � . Business
(FHG) ■■■■■■ ................
From Lobby ................................
Control Room r;st. # 3225
Ext. # 4700 Operations
..................................... ......
(FH) (F)
Administration
Building
Front Hall BOB Man Coe[ w Room f
Ext, # 4214 rr Ii dldd I

Visitor's Safety Information
novozymes®
Rethink Tomorrow
Welcome!
This Safety Information sheet contains important information which is vital to your health and safety. Please read it
before entering.
General Plant Information
1. In case of an emergency dial 2222, give the location of the emergency and state your name clearly.
2. While on the Novozymes site, visitors must remain with Novozymes personnel who will inform them of potential
hazards. Please stay alert and avoid moving traffic and machinery. In the unlikely event of an evacuation or
shelter in place, your Novozymes contact will instruct you on the proper procedures. Eye wash and safety
showers are located throughout the facility for emergency use.
3. Visitors are only allowed in authorized locations.
4. ABSOLUTELY NO TOBACCO USE OR SMOKING is allowed on Novozymes company property
S. Alcohol, drugs and weapons are not permitted on Novozymes property.
6. Safety glasses, hearing protection, and hard hats are required in designated areas.
7. No film photography, digital photography, or video recording is allowed in the facility unless authorized in writing
by a member of NZNA site management.
8. Novozymes !North America maintains a certified environmental management system called EQS (Environmental
Quality System) to assure compliance and continually Improve environmental performance, A copy of the
Novozymes Environment and Bioethics Policy is available upon request
9. Always return your visitors pass to the Receptionist, Weigh Station, or the Security Console to ensure proper
head count in the event of an emergency.
VISITOR EMERGENCY PROCEDURES
Fire Alarm
• Fire alarms are identified by the loud continuous horn and strobe lights. If the alarm sounds during
your visit, walk directly to the nearest exit and use the map on the reverse side of this document to
identify your evacuation assembly area. Each area is identified by a red circular sign with an
accompanying letter. Assemble with your Novozymes contact for the headcount and return to the
building only when the all clear is given.
Ammonia Alarm
• Novozymes uses anhydrous ammonia in its production process. In the unlikely event of a large
ammonia release, please proceed to the closest shelter -in -place location marked on the map. The
ammonia alarms can be recognized by the outdoor sirens, announcements made over the plant
paging and radio systems, and by the on/off sequence from the building fire alarms. Each shelter area
is marked by a green star hanging from the ceiling. Make sure to identify yourself as a visitor when
gathering in the shelter area for the headcount and await further instructions from emergency
officials.
Plant -Wide Evacuation
• if a plant evacuation is ordered via the paging and radio systems, please proceed to the evacuation
assembly area marked by a blue circle on your emergency map.
Severe Weather
• If a tornado or other significant severe weather is reported in close proximity to the facility, a severe
weather shelter order will be given via the paging and radio systems. Severe weather shelter areas
are identified by the projecting wall signs with a tornado on them and are located at interior restrooms
and stairwells throughout the facility. When in the shelter, crouch down low to the floor and protect
your head/face with your arms.

Environmental Conservation Labolories, Inc.
102-A Woodwinds Industrial Court
Cary NC, 27511
Phone; 919.467.3090 FAX: [phone]
Thursday, December 16, 2010
Novozymes North America (N0008)
Attn: Joe Ladd
77 Perry Chapel Church Road
Franklinton, NC 27525
RE: Laboratory Results for
Project Number: 12110, Project Name/Desc: Outfall Sampling
ENCO Workorder: C014251
Dear Joe Ladd,
•
www.encolabs.com
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Thursday, December 2, 2010.
Unless otherwise noted in an attached project narrative, all samples were received in
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are in compliance with NELAC standards, except
as noted in the project narrative. This report shall not be reproduced except in full, without
the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
s
Chuck Smith
Project Manager
Enclosure(s)
The total number of pages in this report, including this page is 19.
RECEIVED
FFp 1 11011
NO DER
4�a1e1g1�Rantonal D�CB

! RECEIVE[*
EEB 1 12011 E,N MM)
NC DENR www.encolabs.com
Raleigh Regional fjf ce
l
Parameter
-----------------------------------------
Hold Date/Time(s) ---------------------
Prep Date/Time(s)
----------------------------------
Analysis Date/Time(s)
------- ------ ---------------------
EPA 200.7
05/30/11
12/02/10
14:51
12/8/2010 13:59
EPA 350.1
12/29/10
12/09/10
07:49
12/9/2010 11:11
EPA 351.2 -
12/29/10
12/09/10
11:12
12/10/2010 14:00
EPA 353.2
12/29/10
12/03/10
07:16
12/3/2010 12:31
EPA 353.2
12/29/10
12/06/10
10:41
12/6/2010 10:58
EPA 365.4
12/29/10
12/09/10
11:12
12/10/2010 16:57
SM 2540C
12/08/10
12/07/10
16:28
12/7/2010 16:28
SM 5210B
12/03/10 11:50
12/02/10
16:07
12/2/2010 16:07
Parameter Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s)
...................... . ...................... .................
EPA 300.0 12/29/10 12/06/10 07:27 12/7/2010 06:51
Parameter
.......................................
Hold Date/Time(s)
Prep Date/Time(s)
---- -- --
Analysis Date/Time(s)
... ...........................
EPA 200.7
.
05/30/11
12/02/10
.................
14:51
12/8/2010 14:02
EPA 300.0
12/29/10
12/06/10
07:27
12/6/2010 18:00
EPA 350.1
12/29/10
12/09/10
07:49
12/9/2010 11:17
EPA 351.2
12/29/10
12/09/10
11:12
12/10/2010 14:03
EPA 353.2
12/29/10
12/03/10
07:16
12/3/2010 12:33
EPA 353.2
12/29/10
12/06/10
10:41
12/6/2010 10:58
EPA 365.4
12/29/10
12/09/10
11:12
12/10/2010 16:58
SM 2540C
12/08/10
12/07/10
16:28
12/7/2010 16:28
SM 5210B
12/03/10 13:35
12/02/10
16:07
12/2/2010 16:07
Parameter Hold Date/Tlme(s) Prep Date/Time(s) Analysis Date/Time(s)
......................................... ................. ... ------------ .....................
EPA 300.0 12/29/10 M06/10 07:27 12/7/2010 07:10
Parameter
Hold Date /Tlme(s)
Prep Date/Tlme(s}
Analysis Date/Time(s)
EPA 200.7
05/30/11
12/02/10
14:51
12/8/2010 14:05
EPA 300.0
12/29/10
12/06/10
07:27
12/6/2010 18:18
EPA 350.1
12/29/10
12/09/10
07:49
12/9/2010 11:19
EPA 351.2
12/29/10
12/09/10
11:12
12/10/2010 14:05
EPA 353.2
12/29/10
12/03/10
07:16
12/3/2010 12:35
EPA 353.2
12/29/10
12/06/10
10:41
12/6/2010 10:58
EPA 365.4
12/29/10
•12109110
11:12
12/10/2010 17:00
SM 2540C
12/08/10
12/07/10
16:28
12/7/2010 16:28
SM 5210B
12/03/10 12:50
12/02/10
16:07
12/2/2010 M07
Page 2 of 19

CSN9 - -
www.enwlabs.com
Parameter Mold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s)
EPA 200,7 05/30/11 12/02/10 14:51 12/8/2010 14:09
RECEIVED
FFR 1 1 101
NC DENh
RaleighReainnai("cG
Page 3 of 19

• MOVED
FEB 1 12011 EEJNO r`
AIG DENR www.encolabs.com
Raleigh Replonal Me@
SAMPLE DETECTION SUMMARY
Analyte
. .......................
Results
Flag
MDL
..... ........
PQL
Units
--....
Method Notes
...............
Barium - Total
. ...............
87.9
3
10.0
....
100
ug/L
EPA 200.7
Calcium - Total
73500
200
1000
ug/L
EPA 200.7
Magnesium - Total
20300
230
1000
ug/L
EPA 200.7
Manganese - Total
15.4
JB
11.0
100
tog/L
EPA 200.7 QB-01
Nitrate as N
3.4
0.025
0.10
mg/L
EPA 353.2
Nitrate/Nitrite as N
3.7
D
0.25
1.0
mg/L
EPA 353.2
Phosphorus
2.5
0.021
0.10
mg/L
EPA 365.4
Potassium -Total
29300
1500
5000
ug/L
EPA 200.7
Sodium - Total
132000
4000
5000
ug/L
EPA 200.7
Total Dissolved Solids
730
10
10
mg/L
SM 2540C
Total Kjeldahl Nitrogen
1.7
0.14
0.48
mg/L
EPA 351.2
Zinc - Total
88.5
3
38.0
100
ug/L
EPA 200.7
Analyte
Results
Flag
MDL
PQL
Units
Method Notes
Chloride
100
D
0.072
20
mg/L
EPA 300.0
Fluoride
6.7
D
0.017
0.80
mg/L
EPA 300.0
Sulfate as SO4
140
D
0.48
20
mg/L
EPA 300.0
Ilent ID: OF
Up 13TI-D-3
Wg14251=UX
Analyte
Results
Flag
MDL
PQL
Units
Method Notes
........ .... ........ .........
Ammonia as N
.................
0.45
.....................
.................
0.0096
0.10
I......
mg/L
................ ---------
EPA 350.1
Barium - Total
72.9
3
10.0
100
ug/L
EPA 200.7
Biochemical oxygen Demand
2.0
2.0
2.0
mg/L
SM 52108
Calcium - Total
57400
200
1000
ug/L
EPA 200.7
Chloride
84
0.018
5.0
mg/L
EPA 300.0
Copper - Total
54.7
3
16.0
100
ug/L
EPA 200.7
Magnesium - Total
15400
230
1000
ug/L
EPA 200.7
Manganese - Total
41.6
JB
11.0
100
ug/L
EPA 2003 QB-01
Nitrate as N
3.0
0.025
0.10
mg/L
EPA 353.2
Nitrate/Nitrite as N
3.1
D
0.25
1.0
mg/L
EPA 353.2
Phosphorus
2.0
0.021
0.10
mg/L
EPA 365.4
Potassium -Total
24900
1500
5000
ug/L
EPA 200.7
Sodium - Total
101000
4000
5000
uglL
EPA 200.7
Total Dissolved Solids
600
10
10
mg/L
SM 2540C
Total Kjeldahl Nitrogen
1.9
0.14
0.48
mg/L
EPA 351.2
Zinc - Total
330
38.0
100
ug/L
EPA 200.7
Analyte Results Flag MDL PQL Units Method Notes
..... .... ................ -... ...... .............. ..
Fluoride 5.1 D 0.017 0.80 mg/L EPA 300.0
Sulfate as SO4 120 D 0.48 20 mg/L EPA 300.0
Analyte
Results Flag
MDL
PQL
Units
Method Notes
......... ........ ..... ............
Barium - Total
............................
66.5 J
......
10.0
... .......................
100
ug/L
......--------------
EPA 200.7
Calcium - Total
9100
200
1000
ug/L
EPA 200.7
Chloride
14
0.018
5.0
mg/L
EPA 300.0
Fluoride
0.092 ]
�0.0043
0.20
mg/L
EPA 300.0
Page 4 of 19

• i
www.encolahs.com
Analyte
........ ...........
Results
Flag
MDL
PQL
Units
Method Notes
............
Magnesium -Total
........ ...............................
2540
230
........
1000
---- ...................................
ug/L
.
EPA 200.7
Manganese- Totai
18.3
]B
11.0
100
ug/L
EPA 200.7 QB-01
Nitrate as N
2.4
0.025
0.10
mg/L
EPA 353.2
Nitmte/Nitrite as N
2.4
D
0.25
1.0
mg/L
EPA 353.2
Phosphorus
0.076
1
0.021
0.10
mg/L
EPA 365.4
Potassium -Total
5510
1500
5000
ug/L
EPA 200.7
Sodium - Total
13700
4000
5000
ug/L
EPA 200.7
Sulfate as SO4
3.3
3
0.12
5.0
mg/L
EPA 300.0
Total Dissolved Solids
100
10
10
mg/L
SM 2540C
Total Kjeldahl Nitrogen
0.58
0.14
0.48
mg/L
EPA 351.2
Analyte Results Flag MDL PQL Units Method Notes
................................................................ ....... ................................ ...................
Potassium -Total 583000 1500 5000 ug/L EPA 200.7
Sodium - Total 127000 4000 5000 ug/L EPA 200,7
RECEIVED
FEB 1 12011
NC DENh
Raleigh Replonal NO
Page 5 of 19

Ce Nhk' :d�� -
www.encolabs.com
Description: FEH BD
Lab Sample ID: C014251-01
Received: 12/02/10 09:32
Matrix: Waste Water
Sampled: 12/01/10 11:50
Work Order: C014251
Project: Outfall Sampling
Sampled By: Joe Ladd
Metals by EPA 200 Series Methods
........
...................
..........
^ - ENCO Cary -rbrAE d a-" [NC 591]
Eeslllta
flag
!lulu
DE MU HU
Batch
Meths
Anal
Notes
Barium [7440-39-31 ^
67.9
]
u91L
1 10.0 too
OL02030
EPA 200.7
12/08/10 13:59
)DH
Calcium [7440-70-21 ^
73500
ug/L
1 200 1000
OL02038
EPA 200.7
12/08110 13:59
JDH
Copper [7440-W8] ^
16.0
U
upfL
1 16.0 l00
OL02D38
EPA 200.7
12/08/10 13:59
)DH
Magnesium [7439-95-41 ^
20300
ug/L
1 230 1000
OL0203B
EPA 200.7
12/08/10 13:59
3DH
Manganese [7439-96.51 ^
15.4
313
ug/L
1 11.0 100
OL02038
EPA 200.7
12/08/10 13:59
JDH QB-CI
PoUsslum [7440-09-71 ^
29300
ug/L
1 1500 5000
OL02038
EPA 200.7
12/08110 13:59
JDH
Sodium [7440-23-S] ^
132000
ug1L
1 4000 5000
OL02038
EPA 200.7
12/08/10 13:59
4H
Zinc [7440-66-6] ^
98.5
J
u911.
1 38.0 160
OL02038
EPA 200.7
12/08/10 13:59
)DH -
'RECEIVED
FEB 1 12011
NO DENR
Raleigh Realollal Office
Page 6 of 19

EN r
www.encolabs.com
Description. FEH BD
Lab Sample ID: C014251-01
Received: 12/02/10 09:32
Matrix: Waste Water
Sampled: 12/01/10 11:50
Work Order: CO14251
Project: Outfali Sampling
Sampled By: Joe Ladd
Classical Chemistry Parameters
...............................
...........
^ - ENCO Cary certified a-&W [NC 591]
Analft [CAS Numbed
Resull
EAU
units
RE
K" HU
A=b
Method
AnIlZ d
ft Note
Ammonia as N [7664-41.7] A
0.0096
U
mg/L
1
0.0096 010
OL09004
EPA 350.1
12/09/10 11:11
CCB
Blochemiml Oxygen Demand [ECL-0017] ^
2.0
U
mg/L
1
2.0 2.0
OL02031
SM 5210B
12/02/20 16:07
]OC
Chloride [16867-00-6] ^
100
D
mgiL
4
0.072 20
OL06002
EPA 300.0
12/07/10 06:51
PEV
Fluoride [16984-48.8] ^
6.7
D
mg/L
4
0.017 0.80
OL06002
EPA 300.0
12/07i10 06:51
PEV
Nitrate as N [14797-SS-B] A
3.4
mg/L
1
0.025 0AC
CLC6016
EPA 353.2
12/06/10 10:5B
PEV
Nitrate/Nitrite as N [ECL-0010] ^
3.7
D
mg/L
10
0.25 1.0
CLC3003
EPA 353.2
12/03/10 12:31
PEV
Phosphorus [7723-14-0] ^
2.S
mg/L
1
0.021 0.10
048027
EPA 365.4
12/10/10 16:57
CCB
Sulfate as SO4 (14808.79.81 ^
140
D
mg/L
4
0.48 20
OL06002
EPA 300.0
12/07/10 06:51
PEV
Total Dissolved Solids [ECL-0156] ^
730
mg/L
1
10 10
OL03019
SM 2S40C
12/07/10 16:28
CCB
Total Kjeldahl Nitrogen [ECL-01621 ^
1.7
mg/L
1
0.14 0.48
OWS026
EPA 351.2
12/10/10 14:00
CCB
This report relates only to the sample as received by the laboratory, and may only be reproduced In full.
Page 7 of 19

www.encolabs.00m
Description; OF Lab Sample ID: C014251-02 Received: 12/02/10 09:32
Matrix: Surface Water Sampled: 12/01/10 13:35 Work Order: C014251
Project:-Outfall Sampling Sampled By: Joe Ladd
Metals by EPA 200 Series Methods
.........................................................................
.
.. .........
...........
. ..........----....--........
^ - ENCO Cary C-tfied analyte (NC 591]
Analvte [CAS Numberl
gesu11g
EhQ
Unlu
QF
MIZL
HU
@=
McUwd
Analyzed
Jay )fig
Barium [7440-39.3] ^
72.9
J
ug/L
1
10.0
100
OLD2038
EPA 200.7
12/08/10 14:02
JDH
Calcium [7440-70-2] ^
57400
ug/L
1
200
1000
OL02038
EPA 200.7
12/08/10 14:02
JDH
Copper [7440-50-a] ^
54.7
3
ugtL
1
16.0
100
OL02038
EPA 200.7
12/08/10 14:02
JDH
Magneslum [7439-95-4] ^
15400
ug/L
1
23D
1000
OL02038
EPA 200.7
12/08/10 14:02
JDH
Manganese [7439-96-51 ^
41.6
38
ugtL
1
11.0
100
OL02038
EPA 200.7
12/08/10 14:02
JDH QB-01
Potasslom [7440.09-7] ^
24900
ug/L
1
1500
5000
OL02038
EPA 200.7
12/08/10 14:02
JDH
5odlum [7440.23.5] ^
101000
ug/L
1
4000
5000
OL02038
EPA 200.7
12/08/10 14:02
JDH
Zinc [7440-66-6] ^
330
ug/L
1
38.0
100
OL02038
EPA 200.7
12/08/10 14:02
JDH
�Eg���p11
�alelah�n°lanai
Page 8 of 19

EN
WWW.enCD]abs.com
Description: OF Lab Sample ID: C014251-02 Received: 12/02/10 09:32
Matrix: Surface Water Sampled: 12/01/10 13:35 Work Order: C014251
Project: Outfall Sampling Sampled By: )De Ladd
Classical Chemistry Parameters
.--.-- . • ..........................................I........_.....
--.--.--.I-.--
----.--.--.--.....
.....................
........
^ - ENCC Cary certified,3n,7 a ANC 591]
AnalM MAS Numberl
gesul
Ems
gnb
DE
HU
HU
A=b
M
Analyzed
fx fi=
Ammonia as N [7664-41-7] ^
0.45
mg/L
1
0.0096
0.10
OL09004
EPA 350.1
12/09/10 11717
CCB
Biochemical Oxygen Demand
2.0
mp/L
1
2.0
2.0
OL02031
SM 5210B
12/02/10 16:07
30C
[ECL-0017] ^
Chloride [16887-00-6] ^
84
mg/L
1
0.018
5.0
OL06002
EPA 300.0
12/06/10 18:00
PEV
Fluoride [16984-48-8] ^
5.1
D
mg/L
4
0.017
0.80
OL06002
EPA 30C.0
12/07/10 07:10
PEV
Nitrate as N [14797-55-81 ^
3.0
mg/L
1
0.025
0.10
OL06016
EPA 353.2
12/06/10 10:58
PEV
Nitrate/Nitrite as N [ECL-0010] ^
3.1
D
mg/L
10
0.25
1.0
OL03003
EPA 353.2
12/03/10 12:33
PEV
Phosphorus [7723-14-0] ^
2.0
mg/L
1
0.021
0.10
OL08027
EPA 365A
12/10/10 16:58
CM
Sulrata as SD4 [1480B-79-8] ^
120
D
mg/L
4
0.48
20
OL06002
EPA 300.0
12/07/10 07:10
PEV
Total Dissolved Solids [ECL-0156] ^
500
mg/L
1
10
10
OL03019
SM 2540C
12/07/10 16:28
CCB
Total Kjeldahl Nitrogen [ECL-0162] ^
1.9
mg/L
1
0.14
0.48
OLD8026
EPA 351.2
12/10/10 14:03
CCB
IntleVED
���9hgeaional
This report relates only to the sample as received by tlx laboratory, and may only be reproduced In full.
Page 9 of 19

Ce Nhk'
www.encolabs.com
Description: Creek Lab Sample ID: C014251-03 Received: 12/02/10 09:32
Matrix: Surface Water Sampled: 12/01/10 12:50 Work Order: C014251
Project: Outfall Sampling Sampled By: he Ladd
Metals by EPA 200 Series Methods
^ - ENCO Cary ceRified ana4dr (NC 5911
Analvte rCAS Numbed
Results
fig
UAIA
pE
MU
MILL
fig,[]
Method
Armed
By Note
Barium [7440-39-3] ^
66.5
3
ug/L
1
10.0
100
OL02038
EPA 200.7
12/08/10 14:OS
]DH
Uldum [7440.70-2] ^
9100
ug/L
1
200
1000
OL02038
EPA 200.7
12108/10 KOS
3DH
Copper [7440-W8] ^
16.0
u
ug/L
1
16.0
100
OL02038
EPA 200.7
12/08/10 14:05
]DH
Magnesium [7439-95-4] ^
2540
ug/L
1
230
LOW
OL02038
EPA 200.7
12/08/10 14:05
IDH
Manganese [7439-96-5] ^
18.3
13
ugA
1
11.0
100
OL02038
EPA 200.7
12/08/10 14:05
]DH QB-01
Potassium [7440.09-7] ^
5510
ug/L
1
1500
5000
OL02038
EPA 200.7
12/08/10 14:05
)DH
Sodium [7440.23.5] A
13700
ug/L
1
4000
5000
OL02038
EPA 200.7
12/08/10 14:05
7DH
Zinc [7440.66.6] A
38.0
u
ug/L
1
38.0
100
OL02038
EPA 200.7
12/08/10 14:05
7DH
RsEWED
FEB 2011
A1C UENR
Raleigh Reaialial ("flee
Page 10 of 19

www.encDlabs.com
Description: Creek lab Sample ID: C014251-03 Received: 12/02/10 09:32
Matrix: Surface Water Sampled: 12/01/10 12:50 Work Order: C014251
Project: Outfall Sampling Sampled By: Joe Ladd
Classical Chemistry Parameters
^ - t VC0 Cary CerBW atw#te [NC S911
Analvte rCAS Number]
Results
flag
Sf=
jE
MIX
MU
Batch
fJgltliod
Analyzed
AX Noteg
Ammonia as N (7664 41.7] ^
0.0096
u
mg/L
1
0.0096
0.10
OL09004
EPA 350.1
12/09/10 1 L19
CCB
Biochemical Oxygen Demand [ECL-00171 ^
2.0
V
mg/4
1
2.0
2.0
OL02031
Sr4 5210E
12/02/10 16:07
30C
Chloride [16887-00-6] ^
14
mg/L
1
0.018
5.0
OL06002
EPA 300.0
12/06/10 18:18
PEV
Fluoride [16984-48-8] ^
0.092
1
m91L
1
0.0043
0.20
OL06002
EPA 300.0
12/06/10 18:18
PEV
Nitrate as N [14797-55-8] ^
2.4
mgJL
1
0.025
0.10
OL06016
EPA 353.2
12/06/10 10:58
PEV
Nitrate/Nitrite as N [ECL-0010] ^
2.4
D
mg/L
l0
0.25
1.0
OL03003
EPA 353.2
L2/03/10 12:35
PEV
phosphorus [7723-14-0] ^
0.076
)
mg/L
1
0.021
0.10
OL08027
EPA 365.4
12/10/10 17:00
CCB
Sulfate as 504 [1480a-79-8] ^
3.3
1
mgJL
:
O.12
5.0
OL06002
EPA 300.0
12/06/10 18:18
PEV
Total Dissolved Solids [ECL-0156] ^
100
mgJL
1
10
LO
OL03019
SM 2540C
12/07/10 16:28
CCB
Total xjeldahl Nitrogen [ECL-0162] ^
0.58
mg/L
1
0.14
0.48
OL08026
EPA 351.2
12/10/10 14:05
CCB
rn
REGEWCU
fE81 12011
RaleighR a�a alOf�ic�
This report relates only to the sample as received b/ the laboratory, and may only be reproduced in full.
Page I 1 of 19

www.encolabs.com
Description: Lagoon 2 Lab Sample ID: C014251-04 Received: 12/02/10 09:32
Matrix: Surface Water Sampled: 12/01/10 14:00 Work Order: CO14251
Project: Outfall Sampling Sampled By: Joe Ladd
Metals by EPA 200 Series Methods
^ ENCO Cary [ertlW a-lyte (NC 5911
Analvte [CAS Humberl Resull!g fin MEILU pE HU MU AlItch Method Auall13sd 1r dole,
Potassium [7440.09-71 ^ 583000 ug/L 1 1500 5000 CLO2038 EPA 200.7 12/08/10 14:09 JDH
WJum [7440-23-5] ^ 127000 ug/L 1 4000 5000 OL02038 EPA 200.7 12/OB/10 14:09 JDH
RECEIVED
� R 1 11011
NC OENk
331eigil Regional1lifice
This report relates only to the sample as received by the laboratory, and may only be reproduced In full.
Page 12 of 19

RREIVED
�__
www.encDlabs.com
NC DENH
QUALM CONTROL +Raleiah Regional Wee
Metals by EPA 200 Series Methods - Quality Control
Batch OL02038 - EPA 300M
Blank (OL02038-BLK1) Prepared: 12/02/2010 14:51 Analyzed: 12/08/2010 12:44
Barium
1.00
U
10.0
ug/L
Calcium
20.0
U
100
ug/L
Copper
1.60
U
10.0
ug/L
Magnesium
23
U
100
ug/L
Manganese
1.4
3
10.0
uglL
Potassium
150
U
500
ug/L
Sodium
400
U
Soo
ug/L
Zinc
3.8
U
10.0
ug/L
LCS (01.02038-651)
. ............
..................................................................
...... '
Prepared: 12102/2010 14:51 Analyzed: 12/08/2010 12:56
Barium
485
10.0
ug/L
500 97 85.115
Calcium
4910
100
ug/L
5000 98 85-115
Copper
249
10.0
ug/L
250 99 85.115
Magnesium
4770
100
ug/L
5000 95 85-115
Manganese
239 B
10.0
ug/L
250 96 85-115
Potassium
24700
S00
ug/L
25000 99 85-115
Sodium
24900
500
ug/L
25000 100 65-115
Zinc
......... .----- ...................
487
.'---'--........-..-...........................
10.0
ug/L
500 97 SS-115
...---......................... ............ ....
Matrix Spike (OL02038-MS1)
.........
Prepared: 12/02/2010 M51 Analyzed: 12/08/2010 13:11
Source: C013611-05
Barium
556
10.0
ug/L
500
71.1
97
75-125
Caidum
27200
l00
u9A
5000
21500
112
75.125
Copper
314
10.0
ug/L
250
66.5
99
75.125
Magnesium
20500
too
ug/L
5000
i5700
96
75.125
Manganese
800 B
10.0
ug/L
250
562
95
75.125
Potassium
28100
S00
ug/L
25000
2950
101
75.125
Sodium
46300
500
ug/L
25000
22000
97
75-125
Zinc
611
10.0
ug/L
500
136
95
75.123
........-'--'-.................'--'--..-'--
Matrix Spike Dup (OL02038-MSD1)
..--'--'--'--'--'--'--'--
..
----...........--.................................................
Prepared: 12/02/2010 14:51 Analyzed:
12/08/2010 13:13
Source, C013611-05
Barium
559
10.0
ug/L
500
71.1
98
75-125
0.7
25
Caldum
28100
100
ug/L
5000
21500
132
75-125
4
25 QM-07
Copper
312
10.0
ug/L
250
663
98
75.125
0.7
25
Magnesium
21400
100
ug/L
5000
15700
114
75.125
4
25
Manganese
809 B
10.0
ug/L
250
562
99
75-125
1
25
Potassium
28400
500
u911-
26000
2950
102
75-125
1
25
Sodium
4690C
500
ug/L
25000
22000
100
75-125
1
25
Zinc
619
10.0
ug/L
500
136
97
75-125
1
25
Page 13 of 19

RECEIVED N6 9)
FFR 1 12011 www.encolabs.com
NC DENn
QUALITY CONTROL NC
Reaianal Office
Classical Chemistry Parameters - Quality Control
Batch OL02031 - NO PREP
Blank (OL02031-BLK1) Prepared & Analyzed: 12(02/2010 16:07
Biochemical Oxygen Demand 2.0 U 2.0 mglL •
...........................................................................................................................
LCS (OL02031-BS1) Prepared & Analyzed: 12/02/2010 16:07
Biochemical Oxygen Demand l80 2.0 mg/L 198 92 85-115
.................... .......... ........................................... .......... -.............. ------.............--.--'- -
Duplicate (OL02031-DUP1) Prepared & Analyzed: 12/02/2010 16:07
Source: C012812-01
Biochemical Oxygen Demand 320 2.0 mg/L 330 2 25
.................................... -........ -........................... ----....................... .....................................
Ba" OL03003 - NO PREP
Blank (OL03003-BLK3) Prepared: 1403/2010 07:16 Analyzed: 12/031201G 10:49
Nltrate/Nitrtte as N 0.025 U 0.10 mg/L
LCS (OL03003-BSI) Prepared: 12/03/2o10 07:16 Analyzed: 12/03/2010 11:17
Nitrate/Nb ite as N 1.2 0.10 mg/L 1.25 93 90-110 -
----" ....-" ..............'-----'- "......... .......................--------.................'--.'-------..--.--.--.--......-------."
Matrix Spike (OL03003-MS1) Prepared: 12/03/2010 07:16 Analyzed: 12/03/2010 11:21
Source: COIIS19-01
NiVaWNWte as N 0.043 0.10 mg/L 0.513 0.006 7 90-110 QM-05
Matrix Spike Dup (OL03003-MSDI) Prepared: 12/03/2010 07:16 Analyzed: 12/03/2010 11:23
Source: C011819-01
' l a Spike' 5ouroea „ iV9raREC § & RPD
/lnalytell za _ �) di' ,Result Flap.,, .? MRL Onitsry .".Level -. a�Result��.d,.°JaRBC r,i<;Llmits7.;�a.RpD ,; Limit'.;' Nobel,
Nitrate/Nitrite as N 0.040 0.10 mg/L 0-513 0.006 7 90-110 7 10 QM-05
Batch OL03019 - NO PREP
Blank (OL03019-BLK1) Prepared & Analyzed: 12/07/2010 16:28
Total Dissolved Solids 10 U 10 mg/L
.............."'.............................-" -" .... ------ .......----" ..........--" '-'......-----....--.--.--.-...-•.••.--
LCS (OL03019-BSI) Prepared & Analyzed: 12/07/2010 16:28
' ike �'�i Source , 4�ICEC P r RPD s Lfr
Ana[yte Rewlt Flap MRL Units Cevel Rewlt l 9 REC - Limits RPD L mlt KaEes7
Page 14 of 19

•
� VED
REc CS N
FEB1 I �U� ! www.encolabs.com
NO UENR
QUALITY CONTROL RaWighReoionaInft
Classical Chemistry Parameters -Quality Control
Batch OL03019 - NO PREP r
LCS (OL03019-BSI) Continued Prepared & Analyzed: 12/07/2010 16:28
Total Dissolved Solids 290 10 mg/L 300 96 90-110
................... ........................ -------------- ........... ........ ................
Duplicate (OL03019-DUPl) Prepared & Analyzed: 12J07/2010 16:28
Source: C011969-02
Total Dissolved Solids 110 10 mg/L 110 6 10
Batch OL06002 - NO PREP
Blank (OL06002-BLKI) Prepared: 12/06/2010 07:27 Analyzed: 12/06/2010 12:42
Chlodde 0.018 U 5.0 mg/L
Fluoride 0,0043 U 0.20 mg/L
Sulfate as SO4 C.12 U 5.0 mg/L
--.......... ...................... --............................................. -........................ .. ........................ .
LCS (OL0600Z-BSI) Prepared: 12/06/2010 07:27 Anayzed: 12 O612010 13:01
Chloride 53
510 mg/L
50.0 106 90-110
Fluoride 1.0
0.20 mg/L
1.00 101 90-110
Sulfate as SO4 48
5.0 mg/L
50.0 96 90-110
......
...... ................................. .......
Matrix Spike (OL06002-MS1)
...'- "-.....................
........... ........... ....................... ....... I —
Prepared: 12/06/2010 07:27 Analyzed: 12/06/2010 13:20
Source: C014465-02
Chloride 21 5.0 mg/L 20.0 2.5 94 90-110
Fluoride 0.47 0.20 mg/L 0.400 0.063 101 90-110
Sulfate as SO4 20 5.0 mgIL 20.0 2.3 87 90-110 QM -OS
Matrix Spike Dup (OL06002-MSD1) Prepared: 12/06/2010 07:27 Analyzed: 12J06/2010 13:38
Source: C014465-02
Chloride
21
5.0
mg/L
20.0
2.5
94
90-I10
0.5
10
Fluoride
0.46
0.20
mg/L
0.400
0.063
100
90-110
0.8
10
Sulfate as SO4
...................--'--'--'--'--'--'-...........'--'--....-----............................'-------..................-'----.....,.......
19
5.0
mg/L
20.0
2.3
86
90-110
1
10 QM-05
Batch OL08016 - Same
Blank (OL08026-BLKI) Prepared: 12/09/2010 1IAZ Analyzed: 1211012010 13:32
Total Kjeldahl Nitrogen 0.14 U 0.48 mg/L
DECEIVED
Page 15 of 14
SCR 1 � Vi
%G OEN"A nut
-,_r..l�h Rani111i1I1111'��

0
QUALITY CONTROL
Classical Chemistry Parameters - Quality Control
Batdr 0L08026 - Same
www.encolabs.com
LCS (OL08026-BSI) Prepared: 12/09/2010 11:12 Analyzed: 12/10/2010 13:34
Total Kjddahl Nltrogen 12 0.48 mg/L 12.0 101 90-110
.......... -"................................"'....-......---'••." ...........-"...........................................-.....---'
Matrix Spike (OL08026-MS1) Prepared: 12/09/2010 11:12 Analyzed: 12/10/2010 13:36
Source:C0013988-01
Totak Kjeldahl Nitrogen 5.4 0.48 mg/L 4.80 0.87 94 90-110
................................... ..................... ......................... '....... ...................................... ..........
Matrix Spike Dup (OL08026-MSD1) Prepared: 12/09/2010 11:12 Analyzed: 12/10/2010 13:39
Source: C013988-01
Total Kjeldahl Nitrogen 5.7 0.48 mg/L 4.80 0.07 101 90-110 6 10
"""'---""...............'--"""'----------""'---"""'-----.....--"•......................--.......-'-"""""""
Batch OL08027 - Same
Blank (OL08027-BLKI) Prepared: 12/09/2010 11:12 Analyzed: 12/10/2010 16:48
Phosphorus 0.021 U 0.10 mg/L
.... I............................... •-'--- ..'- .. " .............."'.......---...." --- " - ".............. I.............................
LCS (OLOS027-BS1) Prepared: 12/09/2010 11:12 Analyzed: 12/10/2010 16:50
Phosphorus 1.7 0.10 mg/L 1.60 103 80.120
......................................................................................................................... .... --.........
Matrix Spike (01.08027-114S1) Prepared: 12/09/2010 11:12 Analyzed: 1ZI10/2010 16:51
Source;C013988-01
Phosphorus 0.98 0.10 mg/L 0.640 0.34 101 80-120
............................................................................................................................... .....
Matrix Spike Dup (OL08027-MSD1) Prepared: 12/09/2010 11:12 Analyzed: 12/10/2010 16:53
Source:C013988-OL
Phosphorus 0.96 0.10 mg/L 0.640 0.34 97 80.120 3 25
—.—..... .-""""'-"-"-""'-""""""....."-""-'--- ........ --- .""""""-""'--.-............... .............
Batch OL09004 - NO PREP
Blank (OL09004-BLK1) Prepared: 12/09/2010 07:49 Analyzed: 12/09/2010 10:27
Ammonia as N 0.0096 U 0.10 mg/L
LCS (OL09004-BSI) Prepared: 12/09/2010 07:49 Analyzed: 12/09/2010 10:29
Page 16 of 19

a �
www.encolabs.com
Classical Chemi= Parameters - Quality Control
Batch OL09004 - NO PREP
LCS (01-09004-130) Continued Prepared: 12/09/2010 07:49 Analyzed: 12/09/2010 10:29
Ammonia as N 1.1 0.10 mg/L 1.00 106 90.110
Matrix Spike (OL09004-MSi) Prepared: 12/09/2010 07:49 Analyzed: 12/09/2010 13:58
Source: C013984-02RE1
Ammonia as N 0.58 0.10 mg/L 0.400 0.18 100 90-110
..---• ............ ........ ........................................ ............... --- ........................ .....................
Matrix Spike Dup (OL09004-MSD1) Prepared: 12/09/2010 07:49 Analyzed: 12/09/2010 14:00
Source: C013984-02RE1
Ammonia as N 0.62 0.10 mg/L 0.400 0.16 110 90.110 7 10
'- ....-'..........'-'........................ ........................."'....................._.............._...............
Page 17 of 19

www.entolabs.com
B The analyte was detected in the associated method blank.
D The sample was analyzed at dilution.
] The reported value is between the laboratory method detection limit (MDL) and the laboratory method
reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable.
U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
E The concentration indicated for this analyte is an estimated value above the calibration range of the
instrument. This value is considered an estimate.
MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution .
factor, and, in the case of soil samples, moisture content.
QB-01 The method blank had a positive result for the analyte; however, the concentration in the
method blank is less than 10% of the sample result, which minimizes the impact of the
deviation.
QM-05 The spike recovery was outside acceptance limits for the HIS and/or MSD due to matrix
interference. The LCS and/or LCSD were within acceptance limits showing that the laboratory is
in control and the data is acceptable.
QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was
accepted based on acceptable LCS recovery.
RECEIVE®
FFR 11 201 1
I G DENR
Page 18 of 19 Ralefoh Reolonal ON

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General Location Map
Scale 1:62,500 (at center)
1 Miles
2 KM
Secondary SA, Road, Hwy
Major Connector
State Route
US Highway
Railroad
Town, Small Clty
U.T. Populalfon Center
Lake, Ocean, Large River
River, Canal
Intermittent River

Y
�r Permit No. NCS000115
SECTION C: LOCATION MAP
Part I Page 2 of 2

Permit No, NCS000115
PART 11 MONITORING, CONTROLS, AND LIMITATIONS FOR PERMITTED DISCHARGES
SECTION A: STORMWATER POLLUTION PREVENTION PLAN
The permittee shall develop a Stormwater Pollution Prevention Plan, herein after referred to as the Plan. This Plan
shall be considered public information in accordance with Para 1II, Standard Conditions, Section E, Paragraph 3 of
this individual permit. The Plan shall include, at a minimum, the following items:
Site Plan. The site plan shall provide a description of the physical facility and the potential pollutant
sources which may be expected to contribute to contamination of stormwater discharges. The site plan shall
contain the following:
(a) A general location map (USGS quadrangle map or appropriately drafted equivalent map),
showing the facility's location in relation to transportation routes and surface waters, the name of
the receiving waters) to which the Stormwater outfall(s) discharges, or if the discharge is to a
municipal separate storm sewer system, the name of the municipality and the ultimate receiving
waters; and accurate latitude and longitude of the point(s) of discharge.
_ (bl A narrative description of storage practices, loading and unloading activities, outdoor. process
areas, dust or pantculite generating or control processes, and waste disposal practices.
(c) A site map drawn to scale with the distance legend indicating location of industrial activities
(including storage of materials, disposal areas, process areas and loading and unloading areas),
drainage structures, drainage areas for each outfall and activities occurring in the drainage area,
building locations, existing BMPs and impervious surfaces, and the percentage of each drainage
area that is impervious. For each outfall, a narrative description of the potential pollutants which
could be expected to be present in the stormwater discharge.
(d) ::A list of significant spills or leaks of pollutants that have occurred at the facility during the 3
previous years and any corrective actions taken to mitigate spill impacts.
(e) Certification that the Stormwater outfalls have been evaluated. for, the presence of non-Stormwater
discharges:' The certification statement will be signed in accordance with the requirements found
in Pan III, Standard Conditions, Section B, Paragraph 3.
2. Stormwater Management Plan. The stormwater management plan shall contain a narrative description of
the materials management practices employed which control or minimize the exposure of, significant
materials to stormwater, including structural and nonstructural measures. The stormwater management
plan, at a minimum, shall incorporate the following:
(a) Feasibility Study. A review of the technical and economic feasibility of changing the methods of
operations and/or storage practices to eliminate or reduce exposure of materials and processes to
stormwater. Wherever practical, the permittee shall prevent exposure of all storage areas, material
handling operations, and manufacturing or fueling operations. In areas where elimination of
exposure is not practical, the stormwater management plan shall document the feasibility of
diverting the stormwater runoff away from areas of potential contamination.
(h) Secondary Containm rit Schedule. A schedule to provide secondary containment for bulk storage
of liquid materials, storage of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act (SARA) water priority chemicals, or storage of haiardous substances to
prevent leaks and spills from contaminating stormwater runoff. if the secondary containment
devices are connected directly to stormwater conveyance systems, the connection shall be
controlled by manually activated valves or other similar devices [which shall be secured with a
locking mechanism] and any stormwater that accumulates in the containment area shall be at a
Part II Page 1 of 5

Permit No. NCSOOO115
minimum visually observed for color, foam, outfall staining, visible sheens and dry weather flow,
pi for to release of the accumulated stormwater. Accumulated stormwater shall be released if found
to be uncontaminated by the material stored within the containment area, Records documenting
the individual making the observation, the description of the accumulated stormwater and the date
and time of the release shall be kept for a period of five years.
(c) BMP Summary. A narrative description shall be provided of Best Management Practices (BMPs)
to be considered such as, but not limited to, oil and grease separation, debris control, vegetative
filter strips, infiltration and stormwater detention or retention, where necessary. The need for
structural BMPs shall be based on the assessment of potential of sources to contribute significant
quantities of pollutants to stormwater discharges and data collected through monitoring of
stormwater discharges.
3. Spill Prevention and Response Plan. The Spill Prevention and Response Plan (SPRP) shall incorporate an
assessment of potential pollutant sources based on iii ateTials inventory of the facility. Facility personnel
(or team) responsible for implementing the SPRP shall be identified. A responsible person shall be on -site
at all times during facility operations that have the potential to contaminate stormwater runoff through spills
or exposure of materials associated with the facility operations. The SPRP must be site stormwater specific.
efoi e, a SPCC plan may be a component of the SPRP, but may not be suf iciem to completely address
the stormwater aspects of the SPRP. The common elements of the SPCC with the SPRP may be
incorporated by reference into the SPRP.
4. Preventative Maintenance and Good Housekeeping Program. A preventative maintenance program shall be
developed. The program shall document schedules of inspections and maintenance activities of stormwater
control systems, plant equipment and systems. Inspection of material handling areas and regular cleaning
schedules of these areas shall be incorporated into the program.
5. Employee Training. Training schedules shall be developed and training provided at a minimum on an
annual basis on proper spill response and cleanup procedures and preventative maintenance activities for all
personnel involved in any of the facility's operations that have the potential to contaminate stormwater
runoff. Facility personnel (or team) responsible for implementing the training shall be identified.
6. Responsible Party. The Stormwater Pollution Prevention Plan shall identify a specific position(s)
responsible for the overall coordination, development, implementation, and revision to the Plan.
Responsibilities for all components of the Plan shall be documented and position assignments provided.
7. Plan Amendment. The permittee shall amend the Plan whenever there is a change in design, construction,
operation, or maintenance which has a significant effect on the potential for the discharge of pollutants to
surface waters. The Stormwater Pollution Prevention Plan shall be reviewed and updated on an annual
basis.
The Director may notify the perrrtittee when the Plan does not meet one or more of the minimum
requi-ements of the permit. Within 30 days of such notice, the permittee shall submit a time schedule to the
Director for modifying the Plan to meet minimum requirements. The permittee shall provide certification in
writing (ire accordance with Part I11, Standard Conditions, Section B. Paragraph 3) to the Director that the
changes have been made.
8. Facility Inspection Program. Facilities are required to inspect all stormwater systems on at least a
semiannual schedule, once in the fall (September -November) and once in the spring (April - June). The
inspection and any subsequent maintenance activities performed shall be documented, recording date and
time of inspection, individual(s) making the inspection and a narrative description of the facility's
stormwater control systems, plant equipment and systems. Records of these inspections shall be
incorporated into the Stormwater Pollution Prevention Plan.
Stormwater discharge characteristic monitoring as required in Part II of this permit shall be performed in
addition to facility inspections.
Part II Page 2 of 5

Permit No. NCS000115
9. Implementation. The permittee shall document all monitoring, measurements, inspections and maintenance
activities and training provided to employees, including the log of the sampling data and of activities taken
to implement BMPs associated with the industrial activities, including vehicle maintenance activities. Such
documentation shall be kept on -site for a period of five years and made available to the Director or his
authorized representative immediately upon request.
SECTION B. ANALYTICAL MONITORING REQUIREMENTS
During the period beginning on the effective date of the permit and lasting until expiration, the permittee is
authorized to discharge stormwater subject to the provisions of this permit. Analytical monitoring of stormwater
discharges shall be performed as specified below in Table 1.
All analytical monitoring shall be performed during a representative storm event. 'The required monitoring will
result in a minimum of 4 analytical satiiplings being conducted over the term of the permit at each stormwater.
discharge outfall (SDO). ' The permittee shall complete the minimum 4 analyticaI samplings�in accordance with the
schedule specified below in Table 2.
Tal,le 1. Analytical Monitorine Reauirements
Discharge
Characteristics 41
units
Measurement
n 1
Sample
2
.8ample
., AX8tion3
BOD5
PM/1
Quarterly- 4's year
Grab
SDO
Chemical Ox .en Demand
mg/1
Quarterly- 4's year
Grab
SDO
Total Suspended Solids
me 1
Quarterly- 4`s year
Grab
SDO
Total K'eldahl Nitro en
m
Quarterly- Wh year
Grab
SDO
Nitrate -Nitrite Nitrogen
m I
Quarterly- 41e year
Grab
SDO
Total Phosphorus
m
Quarterly- 4's year
Grab
SDO
Total Rainfall4
inches
Quarterly- 0 year
Event Duration4
minutes
Quarterly- Wh year
Total Flow4
MG
Quarterly- 4's year
_
SDO
Footnotes:
1 Measurement Frequency: Once per quarter during the 40' year of the'permit term. A year is defined as the 12
month period beginning on the month and day of issuance of the Permit. See Table 2 for schedule of monitoring
periods.
2 If the stormwater runoff is controlled by a stormwater detention pond, a grab sample of the discharge from the
pond shall be collected within the first 30 minutes of discharge. If the detention pond discharges only in response
to a storm event exceeding a ten year design storm, then no analytical monitoring is required and only qualitative
monitoring shall be performed.
3 Sample Location: Samples shall be collected at each stormwater discharge outfall (SDO) unless represettative
outfall status has been granted.
4 For each sampled representative storm event the total precipitation, storm duration, and total flow must be
monitored. Total flow shall be either, (a) measured continuously, (b) calculated based on the amount of area
draining to the outfall, the amount of built -upon (impervious) area, and the total amount of rainfall, or (c)
estimated by the measurement of flow at 20 minute intervals during the rainfall event.
Part II Page 3 of 5

Permit No. NCS000115
Table 2. Monitorin schedule
Monitoring period
Sample Number
Start
End
Year 4 - I" quarter
1
October 1, 2002
December 31, 2002
Year 4 - 2"0 quarter
2
January 1, 2003
March 31, 2003
Year 4 - 3"' quarter
3
April 1, 2003
June 30. 2003
Year 4 - 4's quarter
4
July 1, 2003
September 30, 2003
SECTION C: QUALITATIVE MONITORING REQUIREMENTS
Qualitative monitoring requires a visual inspection of each stormwater outfall regardless of representative outfall
status and shall be performed as specified below in Table 3. Qualitative monitoring is for the purpose of evaluating
the effectiveness of the Stormwater Pollution Prevention Plan (SPPP) and assessing new sources of stormwater
pollution. No analytical tests are mquircd. 'Qualitative monitoring of stormwater outfalls does not.need to be
performed during apresent reative storm event.
In the event an atypical condition is noted at a stormwater discharge outfall, the Permittee shall document the
suspected cause of the condition and any actions taken in response to the discovery. This documentation will be
maintained with the Stormwater Pollution Prevention Plan.
All ,qualitative. monitoring .will be perfortiied.ftwice: per' -year; once in the spring (April"= June) aid once in the fall
(September` November).
Table 3. unlitative Mo Itorine Requirements
Discharge Characteristics
Frequency
Monitoring
Locationl
Color
Semi -Annual
SDO
Odor
Semi -Annual
SDO
Clarity
Semi -Annual
SDO
Floating Solids
Semi -Annual
SDO
Suspended Solids
Semi -Annual
SDO
Foam
Semi -Annual
SDO
Oil Sheen
Semi -Annual
SDO
Other obvious indicators
of stormw'ater pollution
Semi -Annual
SDO
Footnotes:
1 Monitoring Location: Qualitative monitoring shall be performed at each stormwater discharge outfall (SDO)
regardless of representative outfall status.
SECTION D: ON -SITE VEHICLE MAINTENANCE MONITORING REQUIREMENTS
Facilities which have any vehicle maintenance activity occurring on -site which uses more than 55 gallons of new
motor oil per month when averaged over the calendar year shall perform analytical monitoring as specified below in
Table 4. This monitoring shall be performed at all outfalls which discharge stormwater runoff from ,vehicle
maintenance areas., - +
All analytical monitoring shall be performed during a representative storm event. The required monitoring will
result in a minimum of 4 analytical samplings being conducted over the term of the permit at each stormwater
Pan II Page 4 of 5

Permit No. NCS000115
discharge outfall (SDO) which discharges stormwater runoff from vehicle maintenance areas. The permittee shall
complete the minimum 4analytical samplings in accordance with the schedule specified in Table 2 (Part Il, Section
B).
Table 4. Analvtical Monitoring Requirements for On -Site Vehicle Maintenance
Discharge Characteristics
units
Measurement
Frequencyl
Sample
TYE±2
Sample
L&Mtion3
H
standard
Quarterly- 0 year
Grab
SDO
Oil and Grease
mo
Quarterly- 0 year
Grab
SDO
Total suspended Solids
m&2
Quarterly- 0 year
Grab
SDO .
New Motor Oil Usage
allonslmonth
Quarterly- 0 year
Estimate
-
Total Flow4
MG
Quarterly- 40s year
Grab I
SDO
Footnotes:
Measurement Frequency: Once per quarter during the 4's year of the permit term. A year is defined as the 12
month period beginning on the month and day of issuance of the Permit. See Table 2 for schedule of monitoring
periods.
2 If the stormwater runoff is controlled by a stormwater detention pond, a grab sample of the discharge from the
pond shall be collected within the first 30 minutes of discharge. If the detention pond discharges only in response
to a storm event exceeding a ten year design storm, then no analytical monitoring is required and only qualitative
monitoring shall be performed.
3 Sample Location: Samples shall be collected at each stormwater discharge outfall (SDO) that discharges
stormwater runoff from area(s) where vehicle maintenance activities occur.
4 Total flow shall be; (a) measured continuously, (b) calculated based on the amount of area draining to the outfall,
the amount of built -upon (impervious) area, and the total amount of rainfall, or (c) estimated by the measurement
of flow at 20 minute intervals during the rainfall event. Total precipitation ind duration of the rainfall event
measured shall result from the sampled representative storm event.
Part I1 Page 5 of 5

Permit No. NCS000115
PART III STANDARD CONDITIONS FOR NPDES STORMWATER INDIVIDUAL PERMITS
SECTION A: COMPLIANCE AND LIABILITY
Compliance Schedule
The permittee shall comply with Limitations and Controls specified for stormwater discharges in
accordance with the following schedule:
Existing Facilities The Stohrwater Pollution Prevention Plan shall be developed and implemented within
12 months of the effective date of the initial permit and updated thereafter on an annual basis. Secondary
containment, as specified in Part I1, Section A, Paragraph 2(b) of this permit, shall be accomplished within
12 months of the effective date of the initial permit issuance.
Proposed Facilities: The Stormwater Pollution Prevention Plan shall be developed and implemented prior to
the beginning of discharges from the operation of the industrial activity and be updated thereafter on an
annual basis. Secondary containment, as specified in Part II, Section A, Paragraph 2(b) of this permit shall
oc accomplished prior to the beginning of discharges from the operation of in; industrial actiViiy.
Duty to ComI213
The permittee must comply with all conditions of this individual permit. Any permit noncompliance
constitutes a violation of the Clean Water Act and is grounds for enforcement action; for permit
termination, revocation and reissuance, or modification; or denial of a permit upon renewal application.
a. The permittee shall comply with standards or prohibitions established under section 307(a) of the
Clean Water Act for toxic pollutants within the time provided in the regulations that establish these
standards or prohibitions, even if the permit has not yet been modified to incorporate the
requirement.
b. The Clean Water Act provides that any person who violates a permit condition is subject to a civil
penalty not to exceed $25,000 per day for each violation. Any person who negligently violates any
permit condition is subject to criminal penalties of $2,500 to $25,000 per day of violation, or
imprisonment for not more than 1 year, or both. Any person who knowingly violates permit
conditions is subject to criminal penalties of $5,000 to $50,000 per day of violation. or
imprisonment for not more than 3 years, or both. Also, any person who violates a perinit condition
may be assessed an administrative penalty not to exceed $10.000 per violation with the maximum
amount not to exceed $125,000. [Ref: Section 309 of the Federal Act 33 USC 1319 and 40 CFR
122.41(a).]
Under state law, a daily civil penalty of not more than ten thousand dollars ($10,000) per violation
may be assessed against any person who violates or fails to act in accordance with the terms,
conditions, or requirements of a permit. [Ref: North Carolina General Statutes 143-215.6A]
d. Any person may be assessed an administrative penalty by the Director for violating section 301,
302, 306, 307, 308, 318, or 405 of the Act, or any permit condition or limitation implementing any
of such sections in a permit issued under section 402 of the Act. Administrative penalties for Class
I violations are not to exceed $10,000 per violation, with the maximum amount of any Class I
penalty assessed not to exceed $25,000. Penalties for Class 11 violations are not to exceed $10,000
per day for each day during which the violation continues, with the maximum amount of any Class
Il penalty not to exceed $125,000.
Part III Page I of 8 Pages

Permit No. NCS000115
Duty to Mitigate
The permittee shall take all reasonable steps to minimize or prevent any discharge in violation of this
individual permit which has a reasonable likelihood of adversely affecting human health or the environment.
Civil and Criminal Liability
Except as provided in Part III, Section C of this permit regarding bypassing of stormwater control facilities,
nothing in this individual permit shall be construed to relieve the permittee from any responsibilities,
liabilities, or penalties for noncompliance pursuant to NCGS 143-215.3,143-215.6A, 143-215,6B, 143-
215.6C,or. Section .309,of the Federal�Act, 33-USC•1319:-4Furthermore, the permittee is respotislble'for
consequential damages, such as fish kills, even though the responsibility for effective compliance may be
temporarily suspended.
S. Oil and Hazardous Substance Liability ,
Nothing in this individual permit shall be construed to preclude the institution of any legal action or relieve
the permittee from any responsibilities, liabilities, or penalties to which the permittee is or may be subject to
--reer'+?CGS 143-215.75 et seq. or Section 311 of th`e Fed al�ct;'33 LTSC-I3_^
6. Property Rights
The issuance of this individual permit does not convey any property rights in either real or personal
property, or any exclusive privileges, not does it authorize any injury to private property or any invasion of
personal rights, nor any infringement of Federal, State or local laws or regulations.
7. Severability
The provisions of this individual permit are severable, and if any provision of this individual permit, or the
application of any provision of this individual permit to any circumstances, is held invalid, the application
of such provision to other circumstances, and the remainder of this individual permit, shall not be affected
thereby.
Duty_ to Provide Information
The permittee shall furnish to the Director, within a reasonable time, any information which the Director
may request to determine whether cause exists for modifying, revoking and reissuing, or terminating the
permit issued pursuant to this individual permit or to determine compliance with this individual permit. The
permittee shall also furnish to the Director upon request, copies of records required to be kept by this
individual perniit.
9. Penalties for Tam erin
The Clean Water Act provides that any person who falsifies, tampers with, or knowingly renders inaccurate,
any monitoring device or method required to be maintained under this individual permit shall, upon
conviction, be punished by a fine of not more than $10,000 per violation, or by imprisonment for not more
than two years per violation, or by both. If a conviction of a person is for a violation committed after a first
conviction of such person under this paragraph, punishment is a fine of not more that $20,000 per day of
violation, or by imprisonment of not more than 4 years, or both.
10. Penalties for Falsification of Reports
The Clean Water Act provides that any person who knowingly makes any false statement, representation, or
certification in any record or other document submitted or required to be maintained under this individual
Part III Page 2 of 8 Pages

Permit No. NCS000115
permit, including monitoring reports or reports of compliance or noncompliance shall, upon conviction, be
punished by a fine of not more than $10,000 per violation, or by imprisonment for not more than two years
per violation, or by both.
SECTION B: GENERAL CONDITIONS
Individual Permit Expiration
The permittee is not authorized to discharge after the expiration date. In order to receive automatic
authorization to discharge beyond the expiration date, the permittee shall submit forms and fees as are
required by the agency authorized to issue permits no later than 180 days prior to the expiration date. Any
permittee that has not requested renewal at least 180 days prior to expiration, or any permittee that does not
have a permit after the expiration and has not requested renewal at least 180 days prior to expiration, will be
subjected to enforcement procedures as provided in NCGS § 143-2153.6 and 33 USC 1251 et. seq.
2. Transfers
This permit is not transferable to any person except after notice to and approval by the Director. The
Director may require modification or revocation and reissuance of the permit to change the name and
incorporate such other requirements as may be necessary under the Clean Water Act. Permittee is required
to notify the Division in writing in the event the permitted facility is sold or closed.
Signatoryequirements
All applications, reports, or information submitted to the Director shall be signed and certified.
a. All applications to be covered under this individual permit shall be signed as follows:
(I) For a corporation: by a responsible corporate officer. For the purpose of this Section, a
responsible corporate officer means: (a) a president, secretary, treasurer or vice president
of the corporation in charge of a principal business function, or any other person who
performs similar policy or decision making functions for the corporation, or (b) the
manager of one or more manufacturing production or operating facilities employing more
than 250 persons or having gross annual sales or expenditures exceeding 25 million (in
second quarter 1980 dollars), if authority to sign documents has been assigned or
delegated to the manager in accordance with corporate procedures.
(2) For a partnership or sole proprietorship; by a general partner or the proprietor,
respectively; or
(3) ' For a municipality, State, Federal, or other public agency: by either a principal executive
officer or ranking elected official.
h. All reports required by the individual permit and other information requested by the Director shall
be signed by a person described above or by a duly authorized representative of that person. A
person is a duly authorized representative only if:
(1) The authorization is made in writing by a person described above;'
(2) The authorization specified either an individual or a position having responsibility for the
overall operation of the regulated facility or activity, such as the position of plant
manager, operator of a well or well field, superintendent, a.position of equivalent
responsibility, or an individual or position having overall responsibility for environmental
Part III Page 3 of 8 Pages

Ll
Permit No. NCS000115
matters for the company. (A duly authorized representative may thus be either a named
individual or any individual occupying a named position.);,and
(3) The written authorization is submitted to the Director.
Any person signing a document under paragraphs a. or b. of this section shall make the following
certification:
"I certify, under penalty of law, that this document and all attachmeints were prepared under my
direction or supervision in accordance with a system designed to assure that qualified personnel
properly gather and evaluate the information submitted. Based on my inquiry of the person or
persons who manage the system, or those persons directly responsible for gathering the
information, the information submitted is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
4. Individua]_Permit Modification, Revocation and Reissuance, or Termination
T ��- issuance of this individual permit does not prohibit the Director from reopening and modifying the
individual permit, revoking and reissuing the individual permit, or terminating the individual permit as
allowed by the laws, rules, and regulations contained in Title 40, Code of Federal Regulations, Parts 122
and 123; Title 15A of the North Carolina Administrative Code, Subchapter 2H .0100; and North Carolina
General Statute 143-215.1 et. al.
After public notice and opportunity for a hearing, the individual permit may be terminated for cause. The
filing of a request for a individual permit modification, revocation and reissuance, or termination does not
stay any individual permit condition. The permit shall expire when the individual permit is terminated.
5. Fern -tit Actions
The permit may be modified, revoked and reissued, or terminated for cause. The notification of planned
changes or anticipated noncompliance does not stay any individual permit condition.
SECTION C: OPERATION AND MAINTENANCE OF POLLUTION CONTROLS
i . Proper QReTatio and Maintenance
The permittee shall at all times properly operate and maintain all facilities and systems of treatment and
control (and related appurtenances) which are installed or used by the permittee to achieve compliance with
the conditions of this individual permit. Proper operation and maintenance also includes adequate
laboratory controls and appropriate quality assurance procedures. This provision requires the operation of
back-up or auxiliary facilities or similar systems which are installed by a permittee only when the operation
is necessary to achieve compliance with the conditions of this individual permit.
Need to Halt or Reduce Not a Defense
It shall not be a defense for a permittee in an enforcement action that it would have been necessary to halt or
reduce the permitted activity in order to maintain compliance with the condition of this individual permit.
3. 13yipassin&of Stormwater Control Facilities
Bypass is prohibited and the Director may take enforcement action against a permittee for bypass unless:
Part III Page 4 of 8 Pages

Permit No. NCS000115
a. Bypass was unavoidable to prevent loss of life, personal injury or severe property damage; and
b. There were no feasible alternatives to the bypass, such as the use of auxiliary control facilities,
retention of stormwater or maintenance during normal periods of equipment downtime or dry
weather. This condition is not satisfied if adequate backup controls should have been installed in
the exercise of reasonable engineering judgment to prevent a bypass which occurred during normal
periods of equipment downtime or preventive maintenance; and
C. The permittee submitted notices as required. under, Part III, Section E of this permit.
If the Director determines that it will meet the three conditions listed above, the Director may approve an
anticipated bypass after considering its adverse effects.
SECTION D: MONITORING AND RECORDS
1. Representative Sampling
Samples collected and measurements taken, as required herein, shall be characteristic of the volume and
nature of the permitted discharge. Analytical sampling shall be performed during a representative storm
event. Samples shall be taken on a day and time that is characteristic of the discharge,, All samples shall be
taken before the discharge joins or is diluted by any other waste stream, body of water, or substance.
Monitoring points as specified in this. permit shall not be changed without notification to and approval of
the Director.
2. R_ecordinp, Results
For each measurement, sample, inspection or maintenance activity performed or collected pursuant to the
requirements of this individual permit, the permittee shall record the following information:
a. The date, exact place, and time of sampling, measurements, inspection or maintenance activity,
b. The individual(s) who performed the sampling, measurements, inspection or maintenance activity;
C. The date(s) analyses were performed;
d. The individual(s) who performed the analyses;
e. The analytical techniques or methods used; and
f. The results of such analyses.
low Measurements
Where required, appropriate flow measurement devices and methods consistent with accepted scientific
practices shall be selected and used to ensure the accuracy and reliability of measurements of the volume of
monitored discharges.
Test Procedures
Test procedures for the analysis of pollutants shall conform to the EMC regulations published pursuant to
NCGS 143-215.63 et. seq, the Water and Air Quality Reporting Acts, and to regulations published pursuant
to Section 304(g), 33 USC 1314, of the Federal Water Pollution Control Act, as Amended, and Regulation
40 CFR 136.
Part III Page 5 of 8 Pages

*,
Permit No. NCS000115
To meet the intent of the monitoring required by this individual permit, all test procedures must produce
nir.?mutn detection and reporting levels and all data generated must be reported down to the minimum
detection or lower reporting level of the procedure.
5. Representative Outfall
If a facility has multiple discharge locations with substantially identical stormwater discharges that are
required to be sampled, the permittee may petition the Director for representative outfall status. If it is
established that the stormwater discharges are substantially identical and the permittee is granted
representative outfall status, then sampling requirements maybeperforated at a reduced number of outfalls.
6. Records Retention
Visual monitoring shall be documented and records maintained at the facility along with the Stormwater
Pollution Prevention Plan. Copies of analytical monitoring results shall also be maintained on -site. The
permittee shall retain records of all monitoring information, including all calibration and maintenance
records and all original strip chart recordings for continuous monitoring instrumentation, and copies of all
reports required by this individual permit for a period of at least 5 years from the date of the sample,
wcasurement, report or application. This period may be extended by request of the Director at anytime:
7. inspection and Entry
The permittee shall allow the Director, or an authorized representative (including an authorized contractor
acting as a representative of the Director), or in the case of a facility which discharges through a municipal
separate storm sewer system, an authorized representative of a municipal operator or the separate storm
sewer system receiving the discharge, upon the presentation of credentials and other documents as may be
required by law, to;
Enter upon the pern-duee's premises where a regulated facility or activity is located or conducted,
or where records must be kept under the conditions of this individual permit;
Have access to and copy, at reasonable times, any records that must be kept under the conditions of
this individual permit;
C. Inspect at reasonable times any facilities, equipment (including monitoring and control equipment),
practices, or operations regulated or required under this individual permit; and
d. Sample or monitor at reasonable times, for the purposes of assuring individual permit compliance
or as otherwise authorized by the Clean Water Act, any substances or parameters at any location.
SECTION E: REPORTING REQUIREMENTS
Discharge Monitoring Resorts
Samples analyzed in accordance with the terms of this permit shall be submitted to the Division on
Discharge Monitoring Report forms provided by the Director. Submittals shall be received by the Division
no later than 30 days from the date the facility receives the sampling results from the laboratory.
Part III Page 6 of 8 Pages

Permit No. NCS0001 15
Submitting Reports
Duplicate signed copies of all reports required herein, shall be submitted to the following address:
Division of Water Quality
Water Quality Section
ATTENTION: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
3. Availability of Reports
Except for data determined to be confidential under NCGS 143-215.3(a)(2) or Section 308 of the Federal
Act, 33 USC 1318, all reports prepared in accordance with the terms shall be available for public inspection
at the offices of the Division of Water Quality. As required by the Act, analytical data shall not be
considered confidential. Knowingly making any false statement on any such report may result in the
imposition of criminal penalties as provided for in NCGS 143-215.613 or in Section 309 of the Federal Act.
4. Non-Stormwater Discharges -
If the storm event monitored in accordance with this individual permit coincides with a non-stormwater
discharge, the permittee shall separately monitor all parameters as required under the non-stormwater
discharge permit and provide this information with the stormwater discharge monitoring report.
5. finned Changes
The permittee shall give notice to the Director as soon as possible of any planned changes at the permitted
facility which could significantly alter the nature or quantity of pollutants discharged. This notification
requirement includes pollutants which are not specifically listed in the individual permit or subject to
notification requirements under 40 CFR Part 122.42 (a).
6. Antici ated Noncom li nc
The permittee shall give notice to the Director as soon as possible of any planned changes at the permitted
facility which may result in noncompliance with the individual permit requirements.
a55
a. Anticipated bypass. If the permittee knows in advance of the need for a bypass, it shall submit
prior notice, if possible at least ten days before the date of the bypass, including an evaluation of
the anticipated quality and affect of the bypass.
b. Unanticipated bypass, The permittee shall submit notice within 24 hours of becoming aware of an
unanticipated bypass.
Twenty-four Hour Reportins'
The permittee shall report to the ceatral office or the appropriate regional office any noncompliance which
may endanger health of the environment. Any infonwtion shall be provided orally m ithin 24 hours from
the time the permittee became aware of the circumstances. A written submission shall also be provided
within 5 days of the time the permittee becomes aware of the circumstances.
The written submission shall contain a description of the noncompliance, and its causes, the period of
noncompliance, including exact dates and times, and if the noncompliance has not been corrected, the
Part Ill Page 7 of 8 Pages

C .
I
Permit No. NCSOOOJ 15
anticipated time compliance is expected to continue; and steps taken or planned to reduce, eliminate, and
prevent reoccurrence of the noncompliance.
The Director may waive the written report on a case -by -case basis if the oral report has been received
within 24 hours.
9. Other Noncompliance
The permittee shall report all instances of noncompliance not reported under 24 hour reporting at the time
monitoring reports are submitted.
10, Other Information
Where the permittee becomes aware that it failed to submit any relevant facts in an application for an
individual permit or in any report to the Director, it shall promptly submit such facts or information.
Part III Page 8 of 8 Pages

Permit No. NCS000115
PART IV LIMITATIONS REOPENER
This individual permit shall be modified or alternatively, revoked and reissued, to comply with any applicable
effluent guideline or water quality standard issued or approved under Sections 302(b) (2) (c), and (d), 304(b) (2) and
307(a) of the Clean Water Act, if the effluent guideline or water quality standard so issued or approved:
a. Contains different conditions or is otherwise more stringent than any effluent limitation in the individual
permit; or
b. Controls any pollutant not limited in the individual permit.
The individual permit as modified or reissued under this paragraph shall also contain any other requirements in the
Act then applicable.
PART V ADMINISTERING AND COMPLIANCE MONITORING FEE
REQUIREMENTS
The pernuttee must pay the administering and compliance monitoring fee within 30 (thirty) days after being billed by
the Division. Failure to pay the fee in timely manner in accordance with 15A NCAC 2H .0105(b)(4) may cause this
Division to initiate action to revoke the Individual Permit.
PART VI DEFINITIONS
Act
See Clean Water Act.
Arithmetic Mean
The arithmetic mean of any set of values is the summation of the individual values divided by the number of
individual values.
Allowable Non-Stormwater Discharges
This permit regulates stormwateridischarges. Nan-stormwater discharges which shall be allowed in the
stormwater conveyance system are:
(a) All other discharges that are authorized by a non-stormwater NPDES permit,
(b) Uncontaminated groundwater, foundation drains, air -conditioner condensate without added
chemicals, springs, discharges of uncontaminated potable water, waterline and fire hydrant
flushings, water from footing drains, flows from riparian habitats and wetlands.
(c) Discharges resulting from fire -fighting or fire -fighting training.
BestManagementPractices (BMPs)
Measures or practices used to reduce the amount of pollution entering surface waters. BMPs may take the
form of a process, activity, or physical structure.
Parts IV, V and VI Page 1 of 5

Permit No. NCS000115
5. Bypass
A bypass is the known diversion of stormwater from any portion of a stormwater control facility including
the collection system, which is not a designed or established operating mode for the facility.
6. Bulk Storagg of Li uid Produw
Liquid raw materials, manufactured products, waste materials or by-products with a single above ground
storage container having a capacity of greater than 660 gallons or with multiple above ground storage
containers located in close proximity to each other having a total combined storage capacity of greater than
1,320 gallons.
7. Clean Water Act
The Federal Water Pollution Control Act, -also known as the Clean Water Act (CWA), as amended, 33
USC 1251, et. seq.
E. ' -—DrjsionorDWO
The Division of Water Quality, Department of Environment and Natural Resources.
9. Director
The Director of the Division of Water Quality; the permit issuing authority.
10. EMC
The North Carolina Environmental Management Commission.
11, Grab Sample
An individual sample collected instantaneously. Grab samples that will be directly analyzed or qualitatively
monitored must be taken within the first 30 minutes of discharge.
12. Hazardous Substance
Any substance designated under 40 CFR Part 116 pursuant to Section 311 of the Clean Watei Act.
13. Landfill
A disposal facility or part of a disposal facility where waste is placed in or on land and which is not a land
treatment facility, a surface impoundment, an injection well, a hazardous waste long-term storage facility or
a surface storage facility.
14, Municipal -Separate Storm Sewer System
A stormwater collection system within an incorporated area of local self-government such as a city or town.
15. Overburden
Any material of any nature, consolidated or unconsolidated, that overlies a mineral deposit, excluding
topsoil or similar naturally -occurring surface materials that are not disturbed by mining operations.
Part VI Page 2 of 5 Pages

71/
Tar Pamlico River Basin Subbasin 03-03-01
Assessment Impaired Year WNaterbody and Description Unit (AU) Class Subbasin Use liPotential Source(s) Category and Reason for Listing e(s) Miles or Acres
Tar Pamlico River Basin Subbasin 03-03-01
Fishing Creek 28-11a C NSW 03-03-01 6 2.4 FW Miles
From source to SR 1649 AL 1998 6 Impaired biological integrity
Fishing Creek 2841b C NSW 03-03-01 6 0.5 FW Miles
From SR 1649 to #1 outfall AL 1998 6 Impaired biological integrity
Fishing Creek 2841c C NSW 03-03-01 6 0.9 FW Miles
From #1 outfall to SR 1608 AL 1998 6 Impaired biological integrity Major Municipal Point Source
Urban Runoff/Stone Sewers
Major Municipal Point Source
Fishing Creek 28-11d C NSW 03-03-01 6 1.0 FW Miles
From SR 1608 to Coon Creek AL 1998 6 Impaired biological integrity Major Municipal Point Source
Urban Runoff/Storm Sewers
Tar Pamlico River Basin Subbasin 03-03-02
Sandy Creek 28-78-1-(8)b S NSW 03-03-02 6 11.3 FW Miles
From NC 401to N.C. Hwy, 561 O 2000 6 Impaired biological integrity
Stony Creek (Boddies 28-Rb C NSW 03-03-02 6 5.9 FW Miles
Millpond)
From Lassilers Creek to Tar River AL 1998 6 impaired biological integrity
TAR RIVER 28{66.5) WSaV 03-03-02 5 0.7 FW Miles
NSW CA
From Maple Creek to a point 100 feet downstream from Old Rocky Mount Water FC 2006 5 Fish Advisory- Mercury
intake, downstream from U.S. Hwy. 64
North Carolina 303(d) List 2006 Tuesday, June 19, 2007
Tar Pamlico Basin 03-03-02 Page 81 of 125

Tar Pamlico River Basin Subbasin 03-03-03
Assessment Class Subbasin Impaired Year Miles or Acres
Waterbody and Description Unit (AU} USe Listed Category and Reason for Lisfing Potential Source(s)
Tar Pamlico River Basin Subbasin 03-03-03
Ballahack Canal 28-87-1.2 C NSW 03-03-03 6 8.4 FW Miles
From source to Conetoe Creek AL 2006 6 Impaired biological integrity Agriculture
Agriculture
Synums Mill Creek 28-83.4 C NSW 03-03-03 6 9.7 FW Miles
From source to Town Creek - AL 2006 6 Impaired biological integrity Source Unknown
Minor Municipal Point Source
Cokey Swamp 28-833a
C NSW 03-03-03 6
8.6 FW Miles
From source to Dickson Branch
AL 2006 6
Impaired biological integrity
Urban Runoff/Storm Sewers
Conetoe Creek 28-87{0.5)a
C NSW 03-03-03 6
3.9 FW Miles
From source to SR 1516
AL 1998 6
Impaired biological integrity
Channelization
Agriculture
Concentrated Animal Feeding
Operations (permitted, point
source)
Conetoe Creek 28-0740.5)b
C NSW 03-03-03 6
6.9 FW Miles
From SR 1516 to 1350 meters North of NC 42
AL 1998 6
Impaired biological integrity
Channelization
Agriculture
Concentrated Animal Feeding
Operations (permitted, point
source)
Conetoe Creek 28-87{0.5)d C NSW 03-03-03 6 6.7 FW Miles
From Crisp Creek to Pitt County SR 1404 AL 1998 6 Impaired biological integrity Channelization
Agriculture
Concentrated Animal Feeding
Operations (permitted, point
source)
North Carolina 303(co List 2006 Tuesday, June 19, 2007
Tar Pamlico Basin 03-03-03 Page 82 of.125

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Tar River,
1.1 Subbasin Overview
Subbasin 03-03-01 at a Glance
Land and Water Area
Total area: 642 mil
Land area: 635 mil
Water area: 7 miz
Population
2000 Est. Pop.: 65,205 people
Pop. Density: 101 persons/miz
Land Cover [vercent
Forest/Wetland:
76
Water:
1
Urban:
2
Cultivated Crop:
12
Pasture/
Managed Herbaceous:
9
Counties
Franklin, Granville, Person and
Vance r -
Section B - Chapter 1
Tar -Pamlico River Subbasin 03-03-01
:reek. Cedar Creek, Coon Creek and Tabbs Creek
Population growth in this subbasin is occurring between
Franklinton and Louisburg on the border with the Neuse
River basin and along the I-85 corridor near Oxford and
Henderson. Population growth from 1990 to 2000 in the
four counties with land area in this subbasin ranges from
10 percent in Vance County to nearly 30 percent in
Franklin County. The population in these four counties is
expected to increase by 60,000 people (34%) by 2020.
There are 10 individual NPDES wastewater discharge .
permits in this subbasin with a total permitted flow of 6.8
MGD (Figure B-1). The largest are Franklin County
WWTP (3 MGD), Louisburg WWTP (1.37 MGD) and
City of Oxford WWTP (2.7 MGD). There arc also ten
general NPDES wastewater discharge permits, five
individual NPDES stormwater permits, and 30 general
NPDES stormwater permits issued in this subbasin. Refer
to Appendix I for more information on NPDES permit
holders.
The Town of Henderson and Nash County will be
required to develop stormwater programs under Phase 11
(page 75). Henderson and Oxford, and Franklin and Nash
counties will also have to submit model stormwater
ordinances as required by the Tar -Pamlico NSW strategy
stormwater rules (page 61). Issues related to compliance with NPDES permit conditions are
discussed below in Part 1.3 or Part 1.4 for Impaired waters and in Part 1.5 for other waters.
There is also one registered animal operation in this subbasin.
There were seven benthic macroinveitebrate community samples and 12 fish community
samples (Figure 13-1 and Table B-1) collected during this assessment period. Four sites
improved, 1 I sites remained the same, one site had a lower bioclassification, and three sites were
sampled for the first time during this assessment period. Data were also collected from four
ambient monitoring stations as well. Refer to 2003 Tar=Pamlico River Basinwide Assessment
Report at http://www.esb.enr.state.nc.us/bar.html and Section A, Chapter 3 for more information on
monitoring.
Section B: Chapter 1— Tar -Pamlico River Subbasin 03-03-01
96

PERSON
oSubbasm
cow
Boundary
Wnbwd MmftmV Station
©
Fish c«m w* Stabon
NPDES
DWchwgm
♦
Minor
Use Support Rating
A/
SUPPD"
Ntmpawd
NO Rayed
No Data
Primary Raads
o
J
LumvpItay
Figure B-1 Tar -Pamlico III r Subbasin 03-03 1
GRANWLLE
VANCE
SF-t
Henderson
SF-2 Oxfo
SF-3 ti ta�
F SS-1
� F-1' B� `S 0 1
�nr2 Kittrell I
A-t ; B-1 SF�
F3 -f
SF-7' r
Franfdinton
1 QouisbuA-S
F-4-- .�
1a o ra goes
WARREN
FRANKUN
NASH
A-4 !
B-4
r
AMA
NCDEM
Planning Branch
Basinwide Planning Program Unit
April 22, 2004

Table B-1 DWQ Assessment and Use Support Ratings Summary for Monitored Waters in Subbasin 03-03-01
Waterbody
Assessment Unit
Number
DWQ Classification
Length/
Area
Category
Data Type with Map Number
and Data Results
Use Sup rt Rahn
2004
1998
Biological
Ambient
Other
TAR RIVER
28-(1)
WS-rV NSW
20.1 mi
AL
SF-1 E--99
S
ST
Shelton Creek
28-4
WS-IV NSW
13.9 mi
AL
SF-2 E-99
S
.FS
North Fork Tar River
28-5
WS-IV NSW
8.8 mi
AL
SF-3 G-99
S
ST
TAR RIVER
28-(5.3)
WS-IV NSW CA
0.5 mi
AL
SF-5 E--97
A-1 nce.
S
FS
TAR RIVER
28-(5.7)
WS-V NSW
20.5 nu
AL
SF-5 E--97
B-1 G--02
A-1 nce
S
FS
Fishing Creek
28-1le
CNSW
6.1 mi
AL
F-1 G--02
S
PS
Fishing Creek
28-11c
C NSW
0.9 mi
AL
SB-I P-99
I
NS
Fishing Creek
28-1 ld
C NSW
1.0 mi
AL
SB-1 P--99
I
PS
Hachers Run
(Devin Lake)
28-11-3-(1)
WS-II NSW CA
98.9 ac
AL
L-1 nce
S
FS
Coon Creek
28-11-5
C NSW
10.1 mi.
AL
F-2 E--02
S
NR
Middle Creek
28-15
C NSW
8.4 mi.
AL
F-3 G-02
S
FS
TAR RIVER
28-(15.5)
WS-IV NSW
14.8 nu.
AL
SF-6 G--97
S
FS
Tabbs Creek
28-17-(0.5)b
C NSW
12.0 mi.
AL
SF-4 G-99
SB-2 GF-99
S
ST
Lynch Creek
28-21-(0.7)
WS-IV NSW
9.2 mi.
AL
SF-7 G-99
S
FS
TAR RIVER
28-(24.3)
WS-IV NSW CA
0.6 mi.
AL
B-3 GF-02
A-3 nce
S
ST
TAR RIVER
28-(24.7)a
WS-V NSW
20.3 mi.
AL
B-3 GF--02
B-4 G- 02
A4 nce
S
ST
TAR RIVER
28-(24.7)a .
WS-V NSW
20.3 mi.
REC
A-3 nce
A4 nce
S
N/A
Cedar Creek
28-29-(2)b
C NSW
12.1 mi.
AL
F-4 E-02
B-5 GF--02
S
ST
Crooked Creek
28-30b
IC NSW
1 5.4 mi.
I AL
I F-5 GF-02
I
I
S
ST
TAR RIVER
28-(5.7)
WS-V NSW
1 20.5 mi.
I REC
I
I A-1 nce
S
N/A
Fishing Creek
28-1 le
IC NSW
1 6.1 mi.
I REC
A-2 nce
S
NIA
Assessment Unit Number - Portion of DWQ Classified Index where monitoring is applied to assign a use support rating.
Use'Categories:
Monitoring data type:
AL - Aquatic Life
F - Fish Community Survey
REC - Recreation
B - Benthic Community Survey
FC - Fish
SF - Special Fish Community Study
Consumption
SB - Special Benthic Community Study
A - Ambient Monitoring Site
L - Lakes Assessment
FT - Fish Tissue Site
sioctassitcations:
E - Excellent N - Natural
G - Good MS - Moderate Stress
GF - Good -Fair SS - Severe Stress
F - Fair
P - Poor
nce - no criteria exceeded
ce - criteria exceeded
S - Supporting, I - impaired, NR - Not Rated
Use Support Ratings 1998:
FS - fully supporting, ST - supporting but threatened,
PS - partially supporting, NS - not supporting,
NR - not rated, N/A - not applicable
Section B: Chapter 1 - Tar -Pamlico River Subbasin 03-03-01 98
r'

Use support ratings for all waters. in subbasin 03-03-01 are summarized in Part 1.2 below.
Recommendations, current status and future recommendations for waters that were Impaired in
1999 are discussed in Part 1.3 below. Current status and future recommendations for newly
Impaired waters are discussed in Part 1.4 below. Waters with noted water quality impacts are
discussed in Part 1.5 below. Water quality issues related to the entire subbasin are discussed in
Part 1.6. Refer to Appendix III for a complete list of monitored waters and for more information
on Supporting monitored waters.
1.2 Use Support Assessment Summary
Use support ratings were assigned for waters in subbasin 03-03-01 in the aquatic life, recreation,
fish consumption and water supply categories. All waters are Impaired on an evaluated basis in
the fish consumption category because of statewide fish consumption advice for mercury that is
applied in this category to basins east and south of 1-85 (page 90). In the water supply category,
all waters are Supporting on an evaluated basis based on reports from DEH regional water
treatment plant consultants.
There were 469.3 stream miles (35 percent) and 98.9 freshwater acres (100 percent) monitored
during this assessment period in the aquatic life category. Approximately 1.9 stream miles (L'.
percent) are Impaired. Refer to Table B-2 for a summary of use support ratings for waters in
subbasin 03-03-01.
Section B: Chapter I - Tar -Pamlico River Subbasin 03-03-01 99

1. 14
Table B-2 Summary of Use Support Ratings by Category in Subbasin 03-03-01
Use Support
Rating
Aquatic
Life
Fish
Consumption
Recreation
Water
Supply
f
Monitored Waters
Supporting
162.8 mi
98.9 ac
0
469 mi
0
Impaired
1.9 mi
0
0
0
Not' Rated
0
0
0
0
Total
164.8 mi
98.9 ac
0
46.9 mi.
0
Unmonitored Waters
Supporting
15.2 mi
0
0
182.7 mi
98.9 ac
Impaired
0
469.3 mi
98.9 ac
_
0
0
Not Rated
18.5 mi
0
0
0
No Data
270.7 mi
0
422.4 mi
98.9 ac
0
Total
304.5 mi
469.3 mi
98.9 ac
422.4 mi
98.9 ac
182.7 mi
98.9 ac
Totals
All Waters*
469.3 mi
98.9 ac
469.3 mi
98.9 ac
469.3 mi
98.9 ac
182.7 mi
98.9 ac
' Total Monitored + Total Unmonitored = Total All Waters.
1.3 Status and Recommendations of Previously Impaired Waters
Waters in the following section are identified by assessment unit number (AU#). This number is
used to track defined segments in the water quality assessment database, 303(d) Impaired waters
list, and the various tables in this basin plan. The assessment unit number is a subset of the
DWQ index number. (classification identification number). A letter attached to the end of the
AU# indicates that the assessment is smaller than the DWQ index segment. No letter indicates
that the assessment unit and the DWQ index segment are the same.
1.3.1 Fishing Creek [AU# 28-11a through 28-11e]
1999 Recommendations
It was recommended that no new or expanding wastewater dischargers be connected to the
Oxford wastewater treatment plant.
Current Status
Fishing Creek (1.9 miles) is currently Impaired from the Oxford WWTP outfall #1 to Coon
Creek [AU# 2 8-1lc] because of a Poor bioclassification at site SB-1 in 1999. SB-I was also
Section B: Chapter 1, - Tar -Pamlico River Subbasin 03-03-01 100

Poor in 1990. The entire length (I I miles) of Fishing Creek was Impaired in 1999. In 1997, the
Oxford WWTP was upgraded and water quality improvements were observed downstream. Site
F-1 improved from Good -Fair in 1997 to Good in 1999 and 2002. Site B-1 also improved from
Fair in 1999 to Good -Fair in 2002. Above the WWTP, Fishing Creek and Foundry Branch are
impacted by urban runoff from the City of Oxford. Oxford WWTP was placed under a
moratorium after the Poor bioclassification in 1999. The requirements of a prior Special Order
by Consent (SOC) have been met and the associated moratorium has been lifted. Overflows
from the collection system have been reduced due to pipe replacement/rehabilitation work.
However, Oxford WWTP has continued to have problems with overflows, specifically at the
headworks of the WWTP. For approximately 11 months of the assessment period, Oxford
WWTP exceeded permit limits for selenium. An industrial user was determined to be the source
of selenium. Oxford also modified a pretreatment permit of a significant industrial user to
address selenium violations. The industrial user is now using a chemical that does not contain
selenium.
2004 Recommendations
DWQ will continue to monitor water quality in the Fishing Creek watershed. DWQ Raleigh
Regional Office staff will continue to work with Oxford WWTP to remedy plant problems that
may be adversely impacting water quality in Fishing Creek including influent overflows and
infiltration and inflow in the Foundry Branch watershed. Oxford WWTP is expanding from 2.17
MGD to 3.5 MGD and will ,receive permit limits of 5 mg/1 BOD5 and 1 mg/1 NH3-N down from
15 mg/l BOD5 and 4 mg/l NH3-N, representing a decrease in loading of these two parameters.
The new limits as well as those improvements being implemented by Oxford (see below) should
further reduce impacts to Fishing Creek.
Oxford is also required to address nutrients in stormwater as part of the Tar -Pamlico NSW
strategy (page 73) and should take the opportunity to address the more acute impacts to Fishing
Creek when developing a stormwater program.
Current Water Quality Initiatives
Oxford WWTP received a state -revolving loan of $813,514 in January 2001 to rehabilitate the
outfall to Fishing Creek and is awaiting a loan of $10,000,000 to upgrade and expand the plant.
The proposed upgrade will include biological nutrient removal as well as upgrades to the Coon
Creek lift station.
1.4 Status and Recommendations of Newly Impaired Waters
There are no newly Impaired waters in subbasin 03-03-01. Refer to Part 1.5 below for
information on waters with noted water quality impacts.
1.5 Status and Recommendations for Waters with Noted Impacts
The surface waters discussed in this section are not Impaired. However, notable water quality
problems and concerns have been documented for some waters based on this assessment. While
these waters are not Impaired, attention and resources should be focused on these waters to
prevent additional degradation or facilitate water quality improvement.
Section B: Chapter I - Tar -Pamlico River Subbasin 03-03-01 101

Waters in the following section are identified by assessment unit number (AU#). This number is
used to track defined segments in the water quality assessment database, 303(d) Impaired waters
list, and the various tables in this basin plan. The assessment unit number is a subset of the
DWQ index number (classification identification number). A letter attached to the end of the
AU# indicates that the assessment is smaller than the DWQ index segment. No letter indicates
that the assessment unit and the DWQ index segment are the same.
1.5.1 Cedar Creek [AU# 28-29-(2)b]
Current Status and 2064 Recommendations
The benthic bioclassification of lower Cedar Creek (12.15 miles) has been Good -Fair at site 13-5
since 1990. The fish community bioclassification at site F-4 improved to Excellent in 2002. The
upper segment of Cedar Creek [AU# 28-29-(2)a] receives a discharge from the Franklin WWTP
which had three WET test failures during the assessment period. This segment (6.18 miles) is
currently Not Rated. A pretreatment audit was performed in 2002 by DWQ staff to determine if
the one significant industrial user was the source of toxicity. There has not been a WET test fail
since 2002. DWQ will continue to work with the Franklin WWTP. Cedar Creek also crosses the
rapidly growing area of NC 401 between Raleigh and Louisburg. Water quality should be
considered during planning and development activities in this watershed.
1.5.2 Hatchers Run (Devin Lake) [AU# 28-11-3-(1)]
Current Status and 2004 Recommendations
Hatchers Run (Devin Lake) is a 98.9-acre impoundment west of Oxford that was a water supply
until 1993. During lake monitoring in 2002, the reservoir was stratified with hypoxic conditions
three meters from the surface. Chemical monitoring and observed green water color suggested
that algal blooms were occurring although the chlorophyll a criterion was not exceeded.
Nutrient levels were greater than observed in 1997, and copper was higher than the action level.
Water quality in Hatchers Run should be considered during land development activities, and
BMPs should be implemented on all land use activities to reduce the potential for algal blooms.
1.5.3 Tar River [AU# 28-(24.7)a]
Current Status and 2004 Recommendations
This 20.3-mile segment of the Tar River is currently Supporting because of Good -Fair and Good
bioclassification at sites B-3 and B-4, respectively. The change in bioclassification at site B-3
(from Good in 1997) is likely related to the drought of 1998 to 2002 and does not indicate any
real changes in water quality. Water quality standards were not exceeded at sites A-3 and A-4.
DWQ will continue to monitor this segment of the Tar River. This area is experiencing growth
from the Neuse River basin to the south. Louisburg received a $252,000 CWMTF grant to
acquire 50 acres to add to the existing greenway system at Joyner Town Park. Louisburg has
also been offered a $2,295,500 grant through DWQ Construction Grants and Loans for
rehabilitation of the existing WWTP and a wastewater reuse project.
Section B: Chapter I - Tar -Pamlico River Sabbasin 03-03-01 102

1.5.4 Billys Creek [AU# 28-201
Current Status and 2004 Recommendations
The current use support rating of Billys Creek is No Data. Billys Creek has never been
monitored by DWQ; however, EEP (page 168) has a planned project in this local watershed.
This is one of 27 local watersheds in the Tar -Pamlico River basin that has been identified by
EEP as an area with the greatest need and opportunity for stream and wetland restoration efforts.
This watershed will be given higher priority than nontargeted watersheds for implementation of
EEP restoration projects.
1.5.5 Bear Swamp Creek JAU# 28-231
Current Status and 2004 Recommendations
The current use support rating of Bear Swamp Creek is No Data. Bear Swamp Creek has never
been monitored by DWQ; however, EEP (page 168) has a planned project in this local
watershed. This is one of 27 local watersheds in the Tar -Pamlico River basin that has been
identified by EEP as an area with the greatest need and opportunity for stream and wetland
restoration efforts. This watershed will be given higher priority than nontargeted watersheds for
implementation of EEP restoration projects.
1.5.6 Wolfpen Creek [AU# 28-271
Current Status and 2004 Recommendations
The current use support rating of Wolfpen Creek is No Data. Wolfpen Creek has never been
monitored by DWQ; however, EEP (page 168) has a planned project in this local watershed.
This is one of 27 local watersheds in the Tar -Pamlico River basin that has been identified by
EEP as an area with the greatest need and opportunity for stream and wetland restoration efforts.
This watershed will be given higher priority than nontargeted watersheds for implementation of
EEP restoration projects.
Section 6: Chapter 1 - Tar -Pamlico River Subbasin 03-03-01 103

2.1 Subbasin Overview
Subbasin 03-03-02 at a Glance
Land and Water Area
Total area: 663 mil
Land area: 654 miz
Water area: 9 mi2
1
Population Statistics
2000 Est. Pop.: 91,606 people
Pop. Density: 101 persons/Mi2
Land Cover {percents f
`E Forest/ Wetland: 64
Surface Water: 1
Urban: 3
Cultivated Crop: 27
Pasture/
Managed Herbaceous: 4.6
Counties
Edgecombe, Franklin, Nash,
Vance, Warren and Wilson
Municipalities
Centerville, Nashville, Henderson, `
Rocky Mount, Spring Hope,
Tarboro and Whitakers
Section B - Chapter 2
Tar -Pamlico River Subbasin 03-03-02 ($lms
Tar River
Creek and Swift Creek S�
c cc �ccc�s� i
Population growth is occurring around Rocky Mount,
which is the largest urbanized area in the subbasin. The
fastest growing area is Franklin County near the boundary
with subbasin 03-03-01. Much of the subbasin, which
includes the Swift Creek watershed, is rural and little
development is occurring.
There are 12 individual NPDES wastewater discharge
permits in this subbasin with a permitted flow of 23 MGD
(Figure B-2). The largest is the Tar River Regional
WWTP (21 MGD). There are also 15 general NPDES
wastewater permits, two individual NPDES stormwater
permits, and 58 general NPDES stormwater permits in the
subbasin. Refer to Appendix i for identification and more
information on individual NPDES permit holders.
Henderson, Nashville, Rocky Mount, Tarboro, as well as
Edgecombe, Franklin and Nash counties, will be required
to develop stormwater programs under Phase II (page 75).
Henderson, Nashville, Rocky Mount, Tarboro, and
Edgecombe, Nash and Franklin counties will also have to
submit model stormwater ordinances as required by the
Tar -Pamlico NSW strategy (page 61) stormwater rules.
Significant issues related to compliance with NPDES
permit conditions are discussed below. There are also 32
registered animal operations in this subbasin.
There were eight benthic macroinvertebrate community samples and seven fish community
samples (Figure B-2 and Table B-3) collected in 2002 as part of basinwide monitoring. Two
sites improved; one site remained the same, and three sites had lower bioclassifications. Seven
sites were monitored for the first time, and there were two special study samples collected in the
subbasin during the assessment period. Data were collected from nine ambient monitoring
stations and one lake was monitored as well.
Refer to 2003 Tar -Pamlico Raver Basinwide Assessment Report at
http://www.esb.dnr.state.nc.us/bar.html and Section A, Chapter 3 for more information on monitoring.
Section B: Chapter 2 — Tar -Pamlico River Suhbasin 03-03-02 104

Henderson
SS-2
VANCE
f� L .- LTi
Figure B 2 Tar -Pamlico Riveo Subbasin 03-03-02
WARREN
HAUFAX
Pr8 it
Castakia_, WhitaKers
L�
wRedf Oak t
cogerra F-2 - ' 7 Dortrhes Rocky
Qsu n Bwwary -- Mount ,
m Amniem Monitoring Station Spring Momeyer B-1
i Hope Nash ville♦1 �a
© Fieh Communo Station - r F-I
MIMES OWchargas
A major
5j
use support Rang
L.
ICI SUPPAV NASH
Nimpalmd
Not Rated
No Date MLSON
PrAwyRoads
O Cy
Municipal ty 10 0 10 Mlles
Leggett
,- iarbaro
EDGECOMSE
Piginfiing Branch
asinwide Planning Program Unit
April 22, 2004

aI
Table B-3 DWQ Assessment and Use Sunnort Ratings Summary for Monitored Waters in Subbasin 03-03-02
Waterbody
Assessment
Unit Number
DWQ
Classification
Length/
Area
Category
Data Type with Map Number
and Data Results
Use Support Ratio
2004
1998
Biological
Ambient
Other
Sapony Creek
28-55-(1)
C NSW
7.7 nu
AL
F-1 NR--02
S
NR
TAR RIVER
(Reservoir)
28-(63)
WS-IV NSW CA
98.8 ac.
AL
L-1 nee
S
ST
TAR RIVER
28-(66.5)
WS-IV NSW CA
0.7 mi.
FC
FT-1 ce
I
N/A
Stony Creek
28-68a
C NSW
19.4 mi
AL
B-1 GF-02
S
PS
Pigbasket Creek
28-68-3-(2)
C NSW
11.2 mi
AL
F-2 NR--02
NR
NR
TAR RIVER
28-(69)
C NSW
11.3 mi
AL
B-2 GF--02
A-5 nee
S
ST
TAR RIVER
28-(69)
C NSW
11.3 mi.
REC
A-5 nee
S
NIA
TAR RIVER
28-(74)a
WS-IV NSW
21.0 mi
AL
B-3 GF--02
A-6 nee
S
FS
TAR RIVER
28-(74)a
WS-IV NSW
21.0 mi.
REC
A-6 nee
S
NIA
Beech Branch
28-75-(4)
WS-IV NSW
1.0 mi
AL
F-3 NR--02
NR
FS
Swift Creek
28-78-(0.5)
C NSW
37.7 ac
AL
A-8 nee
A-9 nee
S
FS
Swift Creek
28-78-(0.5)
C NSW
37.7 mi.
REC
A-8 nee
A-9 nee
S
N/A
Martin Creek
28-78-1-3
C NSW
4.2 mi.
AL
SB-1 NR-02
NR
NR
Weaver Creek
28-78-1-7
C NSW
6.5 mi.
AL
SB-2 NR--02
NR
ST
Sandy Creek
28-78-1-(8)b
B NSW
11.3 mi.
AL
A-7 nee
S
PS
Sandy Creek
28-78-1-(8)b
B NSW
11.3 nu.
REC
A-7 nee
S
N/A
Sandy Creek
28-78-1-(8)a
B NSW
3.8 mi,
AL
F-4 GF--02
S
PS
Flatrock Creek
28-78-1-12
B NSW
9.1 mi.
AL
F-5 G--02
S
NR
Sandy Creek
28-78-1-(14)
C NSW
20.3 mi.
AL
B-4 GF-02
S
FS
Red Bud Creek
28-78-1-17
C NSW
10.6 mi.
AL
F-6 G--02
S
FS
Swift Creek
28-78-(6.5)
WS-IV NSW
10.0 mi.
AL
B-5 G- 02
S
FS
Whiteoak Swam
28-78-7-(2)
WS-IV NSW
1 2.8 mi.
AL
B-6 MS--02
F-7 NR- 02
S
FS
Assessment Unit Number - Portion of DWQ Classified Index where monitorine is annlied to assign a use sunnort ratine.
Use Categories: Monitoring data type:
AL - Aquatic Life F - Fish Community Survey
REC - Recreation B - Benthic Community Survey
FC - Fish SF - Special Fish Community Study
Consumption SB - Special Benthic Community Study
A - Ambient Monitoring Site
L - Lakes Assessment
FT - Fish Tissue Site
- Excellent N - Natural
- Good MS - Moderate Stress
F - Good -Fair SS - Severe Stress
- Fair
- Poor
Ambient Data
- no criteria exceeded
- criteria exceeded - -
se Support Ratings 2004:
- Supporting, I - impaired, NR - Not Rated
se Support Ratings 1998:
5 - fully supporting, ST - supporting but threatened,
S - partially supporting, NS - not supporting,
R - not rated, NIA - not anolicable
Section B: Chapter 2 - Tar -Pamlico River Subbasin 03-03-02 106

Use support ratings for all waters in subbasin 03-03-02 are summarized in Part 2.2 below.
Recommendations, current status and future recommendations for waters that were Impaired in
1999 are discussed in Part 2.3 below. Current status and future recommendations for newly
Impaired waters are discussed in Part 2.4 below. Waters with noted water quality impacts are
discussed in Part 2.5 below. Water quality issues related to the entire subbasin are discussed in
Part 2.6. Refer to Appendix III for a complete list of monitored waters and more information on
Supporting monitored waters.
2.2 Use Support Assessment Summary
Use support ratings were assigned for waters in subbasin 03-03-02 in the aquatic life, recreation,
fish consumption and water supply categories. All waters are Impaired on an evaluated basis in
the fish consumption category because of statewide fish consumption advice for mercury that is
applied in this category to basins east and south of I-85 (page 90). Also, 0.7 miles of the Tar
River are Impaired in the fish consumption category based on fish tissue monitoring data. In the
water supply category, all waters are Supporting on an evaluated basis based on reports from
DEH regional water treatment plant consultants.
There were 187.9 stream miles (37 percent) and 717.6 freshwater acres (99 percent) monitored
during this assessment period in the aquatic life category. There were no Impaired waters in this
use category. Refer to Table B-4 for a summary of use support ratings for waters in subbasin 03-
03-02.
Section B: Chapter 2 — Tar -Pamlico River Subbasin 03-03-02 107

Table B-4 Summary of Use Support Ratings by Category in Subbasin 03-03-02
Use Support
Rating
Aquatic
Life
Fish
Consumption
Recreation
Water
Supply
Monitored Waters
Supporting
165.0 mi
717.6 ac
0
81.2
0
Impaired
0
0.7
0
0
Not Rated
22.9
0
0
0
Total
187.9 mi
717.6 ae
0.7
j 81.2 mi
j 0
Unmonitored Waters
Supporting
0
0
0
129.3 mi
722.0 ac
Impaired
0
510.5
722.0
0
0
Not Rated
0
0
0
0
No Data
323.3 mi
4.4 ac
0
430.0 mi
722 ac
0
Total
323.3 mi
4.4 ac
510.5
722.0
422.4
98.9
129.3 mi
722.0 ae
Totals
All Waters
511.2 mi
722 ae
511.2 mi
722 ac
511.2 mi
722 ac
129.3 mi
722.0 ae
2.3 Status and Recommendations of Previously Impaired Waters
Waters in the following section are identified by assessment unit number (AU#). This number is
used to track defined segments in the water quality assessment database, 303(d) Impaired waters
list, and the various tables in this basin plan. The assessment unit number is a subset of the
DWQ index number (classification identification number). A letter attached to the end of the
AU# indicates that the assessment is smaller than the DWQ index segment. No letter indicates
that the assessment unit and the DWQ index segment are the same.
2.3.1 Sandy Creek [AU# 28-78-1-(8)a, b and 28-78-1-(14)]
1999 Recommendations
It was recommended that Sandy Creek be resampled to determine if the water Quality impacts
noted in 1997 were related to the 1996 Hurricane Fran.
Current Status
Sandy Creek (35.4 miles) from NC 401 to Swift Creek is currently Supporting in the aquatic life
category because of Good -Fair bioclassifications at sites B-4 and F-4 in 2002. No criteria were
Section B: Chapter 2 - Tar -Pamlico River Subbasin 03-03-02 108

exceeded at site A-7. Based on bacteriological monitoring (site A-7), Sandy Creek [AU# 28-78-
1-(8)b only] is Supporting in the recreation category.
In the 1999 plan, Sandy Creek was Impaired from NC 401 to NC 561 (15.1 miles). Possible
causes of the impairment were thought to be related to the hurricane and possibly to logging and
a milldam just upstream of site B-4. Intolerant species were collected in 2002, indicating
reduced impact to the stream. The biological community may also have been adversely
impacted by the four-year drought, although nonpoint source runoff impacts may have been
minimized during this time.
The High Roost Poultry Farm has been an inactive operation since 1998. The farm lagoon has
had overflows during some rain events and there have been civil penalty assessments against the
farm.
2004 Recommendations
DWQ will continue to monitor water quality in Sandy Creek to determine if the cause of the
depressed biological community is from extreme meteorological events or land use activities.
Land -disturbing activities should implement BMPs to minimize or prevent future impacts to
water quality in the Sandy Creek watershed. The Sandy Creek watershed is also part of a
proposed ORW management strategy to protect water quality in downstream portions of Swift
Creek. The Raleigh Regional Office staff will continue to monitor the High Roost farm.
Additionally, DWQ will continue to work with the Office of the Attorney General in pursuit of
obtaining corrective actions to cease the overflows and will also work with farm owners and
other agencies to find a permanent solution.
2.3.2 Stoney Creek [AU## 28-68a]
1999 Recommendations
Because of low flow in 1997, Stoney Creek was not resampled in 1997, although it remained on
the 303(d) list of Impaired waters. No recommendations were made to address water quality
issues in the 1999 plan.
Current Status
Stoney Creek (Boddies Mill Pond 19.4 miles) from the source to Lassiters Creek is currently
Supporting because of Good -Fair bioclassification at site B-1. No data were collected on the
lower segment from Lassiters Creek to the Tar River (segment runs through urban areas in
southwest Rocky Mount). Although most of the watershed is in forest and agricultural land use,
there is development occurring both upstream and downstream of site B-1. The cause of the
depressed bioclassification is likely habitat degradation, as there was little riparian area and
moderate to severe bank erosion noted at site B-1. Also, drought conditions limited available
habitat in Stoney Creek during monitoring (page 82).
2004 Recommendations
DWQ will continue monitoring Stoney Creek to determine if the cause of the depressed
biological community is from extreme meteorological events or land use activities. Water
quality should be considered during land -disturbing activities, and BMPs should be implemented
to minimize or prevent future impacts to water quality in the Stoney Creek watershed.
Section B: Chapter 2 — Tar -Pamlico River Subhasin 03-03-02 109

Current Water QuafiU Initiatives
Because of previous impairment and current water quality degradation, this is one of 27 local
watersheds in the Tar -Pamlico River basin that has been identified by EEP as an area with the
greatest need and opportunity for stream and wetland restoration efforts.
2.4 Status and Recommendations of Newly Impaired Waters
Waters in the following section are identified by assessment unit number (AU#). This number is
used to track defined segments in the water quality assessment database, 303(d) Impaired waters
list, and the various tables in this basin plan. The assessment unit number is a subset of the
DWQ index number (classification identification number). A letter attached to the end of the
AU# indicates that the assessment is smaller than the DWQ index segment. No letter indicates
that the assessment unit and the DWQ index segment are the same.
2.4.1 Tar River ]AU# 28-(66.5)]
Current Status
The Tar River (0.7 miles) is currently Impaired in the fish consumption category from Maple
Creek to Old Rocky Mount water intake because fish tissue collected in this segment exceeded
the state criterion of 0.4 µg of methylmercury per gram of fish tissue. Five of 13 large mouth
bass collected in this segment also exceeded this criterion. There is also statewide consumption
advice for mercury in fish tissue that is applied to waters east and south of I-85.
2002 Recommendations
Contamination of fish tissue with mercury is a regional issue. Refer to page 90 for more
information on plans to address mercury.
2.5 Status and Recommendations for Waters with Noted Impacts
The surface waters discussed in this section are not Impaired. However, notable water quality
problems and concerns have been documented for these waters based on this assessment. While
these waters are not Impaired, attention and resources should be focused on these waters to
prevent additional degradation or facilitate water quality improvement.
Waters in the following section are identified by assessment unit number (AU#). This number is
used to track defined segments in the water quality assessment database, 303(d) Impaired waters
list, and the various tables in this basin plan. The assessment unit number is a subset of the
DWQ index number (classification identification number). A letter attached to the end of the
AU# indicates that the assessment is smaller than the DWQ index segment. No letter indicates
that the assessment unit and the DWQ index segment are the same.
Section B: Chapter 2 -- Tar -Pamlico River Subbasin 03-03-02 110

2.5.1 White Oak Swamp [AU# 28-78-7-(2)]
Current Status and 2004 Recommendations
White Oak Swamp (2.8 miles) is currently Supporting because of a moderate stress
bioclassification at site B-6 in 2002. The stream was channelized in the past, but habitat is good
and the stream appears to be recovering.
DWQ will continue to monitor White Oak Swamp to assess further recovery. Water quality
should be considered during land -disturbing activities, and BMPs should be implemented to
minimize or prevent future impacts to water quality in the White Oak Swamp watershed.
2.5.2 Beech Branch [AU# 28-75-(4)]
Current Status and 2004 Recommendations
The current use support rating of Beech Branch is Not Rated because site F-3 could not be rated
as criteria for assigning bioclassifications to fish community samples have riot been developed
for coastal plain streams (page 73). Past channelization was noted at site F-3 and the area had
been recently logged. The fish community was diverse; however, and more fish were collected
here than at other coastal plain sites.
DWQ will continue to monitor Beech Branch to assess changes in the fish community that might
be related to land -disturbing activities. Water quality should be considered during land -
disturbing activities, and BMPs should be implemented to minimize or prevent future impacts to
water quality in the Beech Branch watershed. DWQ will continue to develop criteria to assign
bioclassifications for coastal plain fish communities.
2.5.3 Tar River Reservoir [AU# 28-(63) and 28-(36)]
Current Status and 2004 Recommendations
The Tar River Reservoir is Supporting in the aquatic life category based on monitoring during
the summer of 2002. Because of the drought, water levels dropped four feet during the summer,
and nutrients and chlorophyll a increased during the summer. Increased turbidity levels were
likely (from 1997 levels) related to the lower lake levels. DWQ will continue to monitor the
lake.
Because of the potential water quality problems noted above and because the Tar River
Reservoir is a public water supply, it has been identified by EEP as one of 27 local watersheds in
the basin with the greatest need and opportunity for stream and wetland restoration efforts. This
watershed will be given higher priority than nontargeted watersheds for implementation of EEP
restoration projects.
2.5.4 Tar River [AU# 28-(69) and 28-(74)a]
Current Status and 2004 Recommendations
The current use support rating of the Tar River from Rocky Mount Mills to the subbasin
boundary is Supporting because of Good -Fair bioclassifications at sites B-2 and B-3 in 2002.
Both of these bioclassifications are lower than in 1997. Trash was noted as well as eroding
Section B: Chapter 2 — Tar -Pamlico River Suhhasin 03-03-02 H ]

streambanks at site B-2. The lower bioclassification at site B-3 is attributed to drought. No
stoneflies were present at site B-2, indicating some water quality problems in this segment. No
criteria were exceeded at sites A-5 and A-6, although total suspended solids and total phosphorus
were elevated at both sites.
DWQ will continue to monitor the Tar River to determine if the lower bioclassifications were
because of drought or other water quality problems related to land disturbances or discharges.
2.5.5 Pig Basket Creek [AU# 28-68-3-(1) and (2)]
Current Status and 2004 Recommendations
The lower portion of Pig Basket Creek is currently Not Rated because a bioclassification could
not be assigned at site F-2 in 2002. Low dissolved oxygen levels were noted at F-2 as well.
There is currently no data available to assign use support ratings to the upper portion of Pig
Basket Creek.
Production Enterprises poultry farm has had overflows of the treatment lagoon near the source of
Pig Basket Creek. The facility is presently abandoned by its owners and has had no poultry
since 2001. The Raleigh Regional Office staff will continue to monitor the Production Farm.
Additionally, DWQ will continue to work with the Office of the Attorney General in pursuit of
obtaining corrective actions to cease the overflows and will also work with farm owners and
other agencies to find a permanent solution.
2.5.6 Red Bud Creek [AU# 28-78-1-171
Current Status and 2004 Recommendations
Red Bud Creek (10.6 miles) from the source to Sandy Creek is currently Supporting in the
aquatic life category because of Good bioclassification at site F-6 in 2002. The Yang Poultry
Farm has had overflows of the treatment lagoon near an unnamed tributary to Red Bud Creek.
The facility was assessed a civil penalty for a discharge in 2000. This farm was depopulated of
birds in October of 2003 and is presently abandoned.
The Raleigh Regional Office staff will continue to monitor the Yang Farm. Additionally, DWQ
will continue to work with the Office of the Attorney General in pursuit of obtaining corrective
actions to cease the overflows and will also work with farm owners and other agencies to find a
permanent solution.
2.6 Additional Water Quality Issues within Subbasin 03-03-05
2.6.1 Swift Creek and Sandy Creek
Portions of these two creeks have been reclassified to ORW because of excellent water quality.
Refer to page 41 for more information on this reclassification.
Section B: Chapter 2 — Tar -Pamlico River Subbasin 03-03-02 112

Date: January 31, 2015
Novozymes, NA Inc.
77 Perry's Chapel Church Rd.
Franklinton, N.C. 27525
NCDENR Division Of Water Quality
1617 Mail Service Center Raleigh, N.C. 27699-1617
Attn: Division Of Water Quality
Storm Water Sampling, NPDES Permit No. NCS000115
Dear Sir/Madam
novozy mes�
Rethink Tomorrow
Per our Tier Two requirements, regarding the exceeded benchmark in Total Suspended Solids,
(TSS), our implementation of a monthly monitoring in area of concern, "Outfall 1", beginning in
January have resulted in "No Flow" for the month of January.
We therefore were unable to collect a sample for this moth. We plan to continue to diligently with
our monthly monitoring for parameter of TSS until we obtain three consecutive sample results
within the benchmark range.
Kind Regar
Joe Ladd
Environmental Compliance Coordinator
Environmental Services
NJ"
RECEIVED
MAY 10t5
DENR-LAND QUALITY
STORMWATER PERMITTING

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Date: December 31, 2014
Novozymes, NA Inc.
77 Perry's Chapel Church Rd.
Franklinton, N.C. 27525
NCDENR Division Of Water Quality
1617 Mail Service Center Raleigh, N.C. 27699-1617
Attn: Division Of Water Quality
Storm Water Sampling, NPDES Permit No. NCS000115
Dear Sir/Madam
novozy mes• �: )
Rethink Tomorrow
During review of storm water sampling results, it was observed that there was an exceeded
benchmark in Total Suspended Solids, (TSS) deriving from Outfall 1.
Upon immediate investigation, per Tier One requirements, it was concluded that recent
construction on site has created much exposed soil in areas of close proximity to storm drains.
Works being performed using heavy equipment, dump trucks, and tracked vehicles for example,
have resulted in exposed soil in high traffic areas as well. Also, there have been multiple projects
taking place on site during recent months, along with frequent heavy rains directly impacting
turbidity readings.
Environmental Services will be updating and replacing current BMP's placed throughout site
including more strategic locations the current construction areas are impacting. Upgrades made
from previous sampling lowered TSS readings however not below benchmark standards.
Therefore, per Tier Two requirements, we will begin monthly monitoring of Outfall 1 until three
consecutive sample results are below benchmark values.
Continued monitoring by Environmental Services Department will take place in order to prevent
future exceeded benchmarks in Total Suspended Solids, (TSS).
Kind Regards,
Joe Lad
Environmental Compliance Coordinator
Environmental Services

EFFLUENT
NPDES PERMIT NO. NCS000115 DISCHARGE NO. 1 MONTH December YEAR 2014
FACILITY NAME NOVOzymes, NA Inc. CLASS COUNTY: Franklin
OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA PHONE [phone] _
CERTIFIED LABORATORIES (1) Enco (2)
CHECK BOX IF ORC HAS CHANGED 17 PERSONS) COLLECTING SAMPLES Joe Ladd
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES x NIA
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
'1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY
RALEIGH, NC 27699-1617 KNOWLEDGE.
mom
DWQ Form MR-1 (11/04)

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
(including weekly averages, if applicable)
Compliant
Ail monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially
threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the
permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the
permittee becomes aware of the circumstances.
If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for
improvements to be made as required by Part II.E.6 of the NPDES permit.
-I certity, under penalty of law, that this document and all attachments were prepared under my direction or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly
responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Randy Green _
Permittee (Please print or type)
SignatuLQ,df Per t to * Date
(Required unless su itted electronically)
Permittee Address Phone Number e-mail address Permit Expiration Date
ADDITIONAL CERTIFIED LABORATORIES
Certified Laboratory (2) Certification No.
Certified Laboratory (3) Certification No.
Certified Laboratory (4)
Certified Laboratory (5)
PARAMETER CODES
Certification No.
Certification No.
Parameter Code assistance may be obtained by calling the NPDES Unit at [phone] or by visiting the Surface
Water Protection Section's web site at h2o.enr.state.nc.us/was and linking to the unit's information pages.
Use only units of measurement designated in the reporting facility's NPDES permit for reporting data.
* No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be
entered for all of the parameters on the DMR for the entire monitoring period.
•* ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204,
*** Signature of Permittee: if signed by other than the permittee, then the delegation of the signatory authority must be on
file with the state per 15A NCAC 2B .0506(b)(2)(D).
Page 2

EFFLUENT
NPDES PERMIT NO. NCS000115 DISCHARGE NO. 2
FACILITY NAME Novozymes, NA Inc. CLASS
OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA
CERTIFIED LABORATORIES (1) Enco (2)
CHECK BOX IF ORC HAS CHANGED =0 PERSON(S) COLLECTING SAMPLES
Mail ORIGINAL and ONE COPY to:
MONTH December YEAR
Joe Ladd
COUNTY: Franklin
PHONE [phone]
A I I N: CENTRAL FILES x NIA
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY
RALEIGH, NC 27699-1617 KNOWLEDGE.
2014
MEMO
mmmgwffl�
imummosmaw
DWQ Form MR -I (11104)

:'W7 JW
Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
(including weekly averages, if applicable)
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially
threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the
permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the
permittee becomes aware of the circumstances.
If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for
improvements to be made as required by Part II.E.b of the NPDES permit.
"I certity, under penalty of law, that this document and all attachments were prepared under my direction or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly
responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Randy Green
Permittee (Please print or type)
—:: -
Sign a of ittee*** Date
(Required submitted electronically)
Permittee Address Phone Number c-mail address Permit Expiration Date
ADDITIONAL CERTIFIED LABORATORIES
Certified Laboratory (2) Certification No.
Certified Laboratory (3) Certification No.
Certified Laboratory (4) Certification No.
Certified Laboratory (5) Certification No.
PARAMETER CODES
Parameter Code assistance may be obtained by calling the NPDES Unit at [phone] or by visiting the Surface
Water Protection Section's web site at h2o.ennstate.nc.us/LALgs and linking to the unit's information pages.
Use only units of measurement designated in the reporting facility's NPDES permit for reporting data.
* No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be
entered for all of the parameters on the DMR for the entire monitoring period.
** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204,
*** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on
file with the state per I SA NCAC 2B .0506(b)(2)(D).
Page 2

1p ENCO Laboratories
Accurate. Timely. Responsive. Innovative.
102-A woodwinds Industrial Court
Cary NC, V511
Phone: [phone] FAX: [phone]M
Wednesday, December 24, 2014
Novorymes North America (N0008)
Attn: Joe Ladd
77 Perry Chapel Church Road
Franklinton, NC 27525
RE: Laboratory Results for
Project Number: [none], Project Name/Desc: Stormwater Testing
ENCO Workordler(s): C415936
Dear Joe Ladd,
Enclosed Is a copy of your laboratory report for test samples received by our laboratory on
Wednesday, December 10, 2014.
Unless otherwise noted in an attached project narrative, all samples were received in
acceptable condition and processed In accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained In this report are in compliance with NELAC standards, except
as noted in the project narrative. This report shall not be reproduced except in full, without
the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
Stephanie Franz For Chuck Smith
Project Manager
Enclosure(s)
FD AL This report relates onty to the sample as reaWed ty the laboratory, and may any he reproduced in ma. Pagel of 11

WwW.encolabo.com
SAMPLE SUMMARY/LABORATORY CHRONICLE
Client ID: OutfAO -1
Lab ID: C415036-01
Sampled: 12/09/14 15:45 Reodved: 12/10►14 08:03
parameter
EPA 351.2
Held beteMme(ai
01/06/15
Prep Date171mel:1
12/19/14
10:52
12/22/14 12:34
EPA 353.2
12/11/14
15:45
12/10/14
14:39
12/10/14 15:46
EPA 353.2
01/06/15
12/18/14
12:01
12/18/14 12:01
EPA 353.2
09/03/17
12/24/14
10:10
12/24/14 10:15
EPA 365.4
01/06/15
12/19/14
10:52
12/22/14 14:18
SM 2540D-1997
12/16/14
12/15/14
08:45
12/15/14 0B:45
SM 5210B-2001
12/11/14
15:45
12/10/14
12:36
12/10/14 12:36
SM 5220D-1997
01/06/15
12/15/14
11:05
12/15/14 15:33
Client ID: Outfa0.2
Lab ID: 041593"2
Sampled: 12/02/14 16:20 Received: 12/10/14 08:03
Ponsmater
EPA 351.2
Hold Data/71me(sl
01/06/15
12/12/14
10:39
12/16/14 19:22
EPA 353.2
12/11/14
16:20
IVIO/14
14:39
12/10/14 15:47
EPA 353.2
01/06/15
12/18/14
12:03
12/18/14 12:03
EPA 353.2
09/03/17
12/24/14
10:10
12/24/14 10:15
EPA 365.4
01/06/15
12/17/14
10:39
12/16/14 19:58
SM 2540D-1997
12/16/14
12/15/14
08:45
Q/15/14 08:45
SM 521OB-2001
12/11/14
16:20
12/10/14
12:36
12/10/14 12.35
SM 5220D-1997
01/06/15
12j15/14
11:05
12/15/14 15:33
MAL This report rdeus a* to ft sample as revel by me may, and may ony be reprodumd In AA. Paps 2 of 1 t

00 s� ttir
www.enoolaba=m
SAMPLE DETECTION SUMMARY
client ID: Outta9 -1
lab IDr
C415936-01
6Dpdt>A
112W l6
an
Ha
ML
lWlt
memo M21M
Biochemical Oxygen Demand
3.5
2.0
2.0
mg/L
SM 5210E-2001
Chemical Oxygen Demand
54
10
10
mg/L
SM 5220D-1997
Nitrate as N
0.41
0.025
0.10
mg/L
EPA 353.2
Nitra*Nft to as N
0.41
0.041
0.10
mg/L
EPA 353.2
Phosphorus
0.29
0.025
0.10
mg/L
EPA 365.4
Total igeldaht Nitrogen
1.2
0.26
0.48
rrg/L
EPA 351.2
Total Suspended Solids
120
1.0
1.0
L
SM 2540D-1997
Client ID: Outfall - 2
Lab ID:
C415236-02
An w n
81111illib
on
Ma
ML
mum
NeUmd flow
Chemical Oxygen Demand
12
10
10
mg/L
SM 5220D-1997
Nitrate as N
0.080
]
0.025
0.10
mg/L
EPA 353.2
Nbate/Nttrtte as N
0.080
1
0.041
0.10
mg/L
EPA 353.2
Total Kjeldahi Nitrogen
0.30
1
0.26
0.48
mg/L
EPA 351.2
FINAL This report ndapes only to the sample as reed by dm Iabara0ory, and may only be reproduced In full. Paps 3 of 11

www.encolabs.com
ANALYTICAL RESULTS
DGMAptlon. Ounil - 1 Lob Sample ID: C41593601 Received: 12/10/14 09:05
Matrix: Surface Water Sampled:12/09/14 15:45 Work Order: C415936
Projed: Stormwater Tesdng Sampled By:]oe Ladd
Classical Chemistry Parameters
^ - E7VX Cbr mVkder *M (AC S911
Andyte MM Numbed Rumb
an lithe
DE MRL EM
AWMh
Medwd
ADW=d
ft ham
Modiverniral Oxygen Demand-
3.S
mg/L
1 2.0 2.0
4L10013
SM 52108-2001
12/10/14 12:36
30C
Chemical Oxygen Demand^
54
mg/L
1 10 10
4L15008
SM 522OD-1997
12/15/14 15:33
10C
N11 I I as N [14797-3S-E]^
0.41
mg/L
1 0.025 0.10
4LZ4018
EPA 353.2
IV24114 10:15
AM
NNrote/NNiibe w N^
0.41
mg/L
1 0.041 0.10
4L18005
EPA 353.2
12/18/14 12:01
AM
Nftrihe as N [14797-65-0]^
0.017
U mg/L
1 0.017 0.10
4L10030
EPA 353.2
12/10/14 15:46
SHA
Phosphorus [7723-14.01^
0.29
rtg/L
1 0.025 0.10
4L19003
EPA 365.4
12/22/14 14:18
SHA
Total KjeWahl Nlhogen^
1.2
ng/L
1 0.26 0.48
4L19001
EPA 351.2
12/22/14 12:34
SHA
Total Suspended Sollds^
120
rtg/L
1 1.0 1.0
4L15002
SM 2MOD-1997
12/15/14 08:45
MR
Description: Outrall - 2
Lab Sample ID:C415936-02
Remind: 12/10/14 08:05
Matrbc: Surface Water
Sampled:12/09/14 16:20
Ware Order: C415936
Project: Stormwater Tesdng
Sampled By:]oe Ladd
Classical Chemistry Parameters
f
^•MX CIWY avlk m*ftPC 5911
Anahft MAS Numberl Baum
an
linill
of
Mu
12L
IBM
Mfdtmd
hnwmd
MR ado
Biochemical 0xygen Demand-
2.0
u
mg/L
1
2.0
2.0
4L10013
SM 5210f1-2001
12/10/14 12:36
3oC
Chamkel Oxygen bamand^
12
mg/L
1
10
10
41,15008
SM 522OD-1997
12/15/14 15:33
30C
Nitrate as N [14797-5S-a]^
0A80
1
mg/L
1
0.025
0.10
4LZ4018
EPA 353.2
12/24/14 10:15
AM
Nitrate/Na21te as N^
0.080
1
mg/L
1
0.041
0.10
4L18005
EPA 353.2
12/18/14 12:03
A38
Nitrite as N [14797-05-0]^
0.017
U
ng/L
1
0.017
0.10
4L1D030
EPA 353.2
12/10/14 15:47
SHA
Phosphorus [7723-14-0]^
0.025
U
mg/L
1
0.025
0.10
4L12009
EPA 365.4
12/16/14 19:58
A18
Total KjeidaM Nldogen^
0."
3
mg/L
1
0.26
0.48
4L12008
EPA 351.2
IV16/14 19:22
A1B
Totat Suspended Sands^
1.0
U
mg/L
1
1.0
1.0
4LIS002
SM 25MD•1997
12/15/14 08:45
MMR
FINAL This Report mdaonly m me woe as reorhra by the iabarahmy. and may o* be reprv6xzd In ruff. Pegs 4 of 1 I

www.ancolabo.com
QUALITY CONTROL DATA
Clasalml Chemistry Paramabero - QualltY Control
Bach 4LIP013 -IUD P1RM
Blank (41.1001"Ll(1)
Prepared & AnoWecl: 12/10/2014 12:36
Spike Source %REC
RPD
1
RAIUM
Beg
POL
UBlle
Level gCEM %REC UmBi RPD
Limit NotelL
Bl diemlcal Oxygen Demand
2.0
U
2.0
mg/L
0-03
LCS (4L10013-BSl)
Prepared & Analyzed: 12/10/2014 12:36
Spike Source %REC
RPD
An
Besl1B
Bea
POL
Units
Level ggaft %REC Umb RPD
L(mlt M20
Bkidiernlal Oxygen Demand
180
2.0
mg/L
198 93 85-115
Duplicate (4L10013-DUP3)
Prepared & Anayzed: 12/10/2014 12:36
Source: C413466-01
Spike Source %REC
RPD
�nehde
Bawa
Ben
POL
Units
Laval gpnig %REC Llmile RPD
LM not"
Bbdiemlal Oxygen Demand
1800
2.0
mg/L
law 1
30
Be" 4110WO-AV MID
ZZ (41.10030-111M)
Prepared: 12110/2014 14:39 Analyzed: 12/10/2014 ISM
Spice Source %REC
RPD
JDehme
Remo
Beg
PAL
Units
Level g2aft %REC UMMI RPD
Limit Not"L
Nitrite as N
0.017
U
0.10
mp/L
LCS (4L10030-BSI)
Prepared: 12/10/2014 14:39 Analyzed: 12/10/2014 15:41
Spike Source %REC
RPD
Ana Lda
Bamit
Beg
ML
llnlsi
Level gAM& %REC UMM RPD
Limit Notes
Nitrite as N
1.0
0.10
mg/L
1.00 101 90-110
LCS (4L10030-BS2)
Prepared: 12/10/2014 14:39 Analyzed: 12/10/2014 15:49
Spike Source %REC
RPD
Ana hda
911111911
Beg
POL
UBlts
Leval goo %REC LWIM RPO
Limit Notes,
Nllrlte as N
1.0
0.10
rrrg/L
1.00 100 90-110
LCS (4L10030-BS3)
Prepared: 12/10/2014 14:39 Analyzed: 12/10/2014 16:53
Spike Source %REC
RPD
Ana hd11
Raub
Beg
PAL
UDlte
Level 8oiyg %REC Limits RPD
Limit Notea,
Nitrite as N
0.96
0.10
mg/L
1.00 98 90-110
LCS (41.10030-111S4)
Prepared: 12/10/2014 14:39 Analyzed: 12/10/2014 17:01
SPUN Source %REC
RPD
�oanda
Result
Beg
POL
UDlti
Level BIM& %REC Limits RPD
Limit Notes,
Nitrite as N
1.0
0.10
mg/L
1.00 101 90-110
Matrix Spike (4L10030-MSl)
Prepared: 12/10/2014 14:39 Analyzed: 12/10/2014 15:43
Source: C415177-01
$Oka Source %RRC
RPD
Am
Haigh
Bea
ML
Units
Level golift %REC Limits RPD
Limit Notes
Nitrite as N
0.76
0.10
mg/L
1.00 0.023 74 90-110
QM-05
Matrix Spike Dup (4L10030-MSD1)
Prepared: 12/30/2014 14:39 Analyzed: 12/10/2014 15:44
Source. C413177-01
Spica Source %REC
RPD
Ana hda
Rena
Bea
POL
Unks
Leval gaM %REC Limits RPD
Limit Notes
FINAL
This report relates only t0 the sample as remtvW by the laboratory, and may only be nVroducad In full.
Page 5 of 11

www.ancelabo.com
QUALITY CONTROL DATA
Claealcal Chemistry Parameters - Quality Control
Anldl 4LIOV" - NO PREP - Condnued
Matrix Splice Will (4110030-11SD1) Coat Ued Prepared: 12/10/201414:39 Analyzed: 12/10/201415:44
Source: C419177-01
Spike Source %REC RPD
Ann BEilllt gad pal 11BBa Lard g&ng %REC Limits RPD L(mlt NotaL
NItrft as N 0.76 0.10 mg/L 1.00 0.023 74 90-110 0.4 10 QM-05
Bald► 4L.920M - Soma
Blank (411.12008-0LRl) Prepared: 12/12/201410:39 Analyzed: 12/16/201419:08
Spike Source %REC RPD
.Au011t% BagIB Had ML 1111111231 Lard gll& %REC Limns RPD Llm11 Notes
Total Kjeldahl Nitrogen 0.26 U 0.48 MWL
LCS (4L12008-BSk) Prepared: 12/12/201410:39 Analyzed: 12/16/2014 19:11
Spike Source %REC
RPD
�tlanda Bradt
Has E41
Units
Lord good %REC 1,(m(ta RPD
Llmlt notes
Total i(leklahl Nitrogen 12
0.48
mg/l.
12.0 98 90.110
Matrtx Spike (4L12008-MS1)
Prepared: 12/12/2014 10:39 Analyzed: 12/16/2014 19:15
Source: C411111-01
Spike Source %REC
RPD
Anaba BdWR
Had E4L
Unbs
Lord fthdt %RFC USM RPD
Limit Kotft
Total igeldahl Nib ow 5.8
0.48
mg/L
4.79 1.3 94 90-110
Matrix Spike Dup (4L32008-MSDl)
Prepared: IV12/2014 10:39 Analyzed: 12/16/2014 19:17
Source: C411111-01
Spike Source %REC
RPD
ADahtta Beloit
Had P9L
111ft
Laval g§Ug %REC Limits RPD
LIMB Fiats".
Total I(jeldahl Nitrogen 5.9
0.48
mg/L
4.79 1.3 95 90.110 1
10
Batrli 4L12Wg - SNIM
Blank (4L11008-SM)
Prepared: 12/12/2014 10:39 Analzed: 12/16/2014 19:50
Spike Source %REC RPD
�da!ffi Result Had e91 Lined Lmd ggSift %REC LMM RPD Limit NON
Phosphorus 0,025 U 0.10 mg/L
LCS (4L12009-BS1) Prepared: 12/12/2014 10:39 Analyzed: 12/16/2014 19:51
Spike Source %REC
RPD
Aoanda Result
Elad P91
UnIL1
Level gMM %REC Nmlta RPD
1llllit Notes
Phosphorus 1.7
0.10
mg/L
1.60 103 80.120
Mstrhc SpBoe (4111.12000-Ml)
Prepared: 12/12/2014 10:39 Analyzed: 12/16/2014 19:54
Source: C411111-01
Bpika Source %REC
RPD
Ananda Result
Elan FOL
1,11111113
Lavd gM %REC LlMB& RPD
Llmlt Hates
Phosphorus 0.68
0.10
mg/L
0.640 0.051 98 80-120
Matrix Spike Dup (411.12009-MSD1)
Prepared: 12/12/2014 10:39 Analyzed: 12/16/2014 19:56
Source: C411111-01
Phosphoms
Adtr,:h 4U50102 - NO PREP
spike source %REC
Begin Had EQL 1111111131 Level SMU %REC L MUR RPD
0.69 0.10 M91L 0.640 0.051 99 80-120 1
RPD
Limit Not"
25
FINAL This report ml3tas any to the sonpie as rwdved by the laeoretory, and may only be reproduced In full.
Page a of 11

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QUALITY CONTROL DATA
Classiml Chemistry Paramobars - Quality Control
Aetcli 4 X VD2 - NO PAW - CamObLed
Blank (4L18002-ELKS)
Prepared & Analyzed: 12/15/2014 0BAS
Spike Source %REC
RPD
Analvia
Bend
BaR
e41
UDltt
Lord gAWR %REC Umaa
RPO
I.IB1it BRiIw-
Total Suspended Solids
1.0
U
1.0
mg/L
LCS (41.18002-BS1)
Prepared & Analyzed: 12/15/2014 08:45
Spike Source %REC
RPD
AmbW
gonft
an
P"
Unlis
Level Remit %REC Umat
RPD
LIIDi! motes,
Total Suspended Solids
93
1.0
mg/L
100 93 80.120
Duplicate (41.15002-DUP1)
Prepared & Analyzed: 12/15/2014 08:45
Source: C416385.01
Spike Source C116REC
RPD
ADands
Basalt
EiaO
eOI.
Unite
Level BEWR %REC UMU
RPD
U" Notes
Total Suspended Solids
1600
1.0
mg/L
1800
12
10 QM-12
Duplicate (411.15002-DUP2)
Prepared & Analyzed: 12/15/2014 08:45
Source: C416383-02
Space Source %REC
RPD
ABanda
Bailie
Emu
eQL
U1111a
Level gang %REC Umb
RPD
Llmlt Notes
Total Suspended Solids
Astrb 4USM - Sww
140
1.0
mg/L
140
0
10
Blank (411.1500"UU)
Prepared: i2/15/2014 11:05 Analyzed: 12/15/2014 15:33
Spike Source %REC
RPD
Anabu
HOWU
iials
F4L
UBa6
Level gaBift %REC Nmlti
RPD
lima AW
Chemical Oxygen Demand
10
U
10
mg/L
LCS (41.15008-11381)
Prepared: 12/15/2014 11:05 Analyzed: 12/15/2014 15:33
Spike Source %REC
RPD
Anahtta
Baas$
Ertl
$QL
Untla
Lard g2j& %REC NMb
RPD
lba Notes.
Chemical Oxygen Demand
490
10
mg/L
500 98 90-110
Matrix Spike (41.15008-MSl)
Prepared: 12/15/2014 11:05 Analyzed: 12/15/2014 15:33
Source: C414995-01
Spike Source %REC
RPD
ADahte
BBslilt
Flan
RM
Untie
Lend ROM %REC Limas
RIND
Lfmlt Notes
Chemical Oxygen Demand
520
10
mg/L
500 10 U 103 90-110
Matrht SpUro Dup (41.15008-111111SDl)
Prepared: 12/15/2014 11:05 Analyzed: 12/15/2014 15:33
Source: C414993-01
Spike Source %REC
RPD
Ana hdel
Boault
Elm
POI.
Ulm
Level 920d %REC UMU
RPD
1.111111(1 Nome
Chemical oxygen Demand
510
10
mg/L
500 10 U 101 90.110
2
10
Batt* AIRMS - NO AW
Blank (411.18005-BLK1) Prepared: 12/18/2014 11:13 Analyzed: 12/18/2014 11:13
Spike Source %REC RPD
Aoahttla Basalt Flan MI. Lb al Level AMA %REC Llmltt RPD Limit motet
Nitrate/Nitrtte as N 0.041 U 0.10 mg/L
r
I1Hu This report relates only to the sample as recall vetl by tee laboratory, and may only to reprodLx etl In Ice. Pegs 7 of 11

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Befd1l &18" - AND PREP - Coaffh W
LCS (41.18003-01)
Prepared: 12/18/2014 11:11 Analyzed: 12/18/2014 11:11
Spike Source %REC
RPD
�ndhma
Biel$
Elm
M1
Milne,
Lard B4i& %REC MmU RPD
LIMB W.
Nltrate/Nroft as N
1.3
0.10
mg/L
1.25 101 90-110
Matrix Spike (41.18009-MS1)
Prepared: 12/18/2014 11:18 Analyzed: 12/18J2014 11.18
Mae
Source: C414405-01
Spike Source %REC.
RPD
Anahtta
Ralad
Ella
PQL
U»ila
Laval Be811L %REC 1(mMit RPD
U11111: NoW
Nitrate/Nitrtte as N
1.0
0.10
mg/L
0,513 0.53 96 9o-110
Matrix Spike Dup (41.18003-MS01)
Prepared: 12/18/2014 11:20 Analyzed: 12/18/2014 11:20
Source: C41491113.01
Spike Source %REC
RPD
boande
Sta t
Elea
PQL
llalti
Level Besllt %REC 1rlmft RPD
Lump; n0W
NitrateMb1te as N
1.0
0.10
mg/L
0.513 0.53 92 90.110 2
10
ffatch 4L Owl - sSama
Blank (4L19001-51.1(1)
Prepared: 12/19/2014 10:52 Analyzed: 12/22/2014 11:50
Spike Source %REC
RPD
Anlllllt0
Secant
an
241
Usti
Laval Ralilt %REC Lkab RPD
LIMM Notm
Total lyeldahl Nitrogen
0.26
U
0.48
mg/L
LCS (41.19001$Sl)
Prepared: 12/19/2014 10:52 Analyzed: 12/22J2014 11:52
Spike. Source %REC
RPD
�0ab�a
Result
ila0
Pak
UnH2
Level BOsu)t %REC Limb RPD
1.111111; 02W
Total Kjeldahl Nitrogen
13
0.48
mg/L
12.0 104 90-110
Matrix Spike (4L39001-MS1)
Prepared: 12/19/2014 10:52 Analyzed: 12/22J2014 11:56
Source. C413281-01
Spike source %REC
RPD
llnabma
ftaltt
In
P"
lhnita
Laval goij& %REC 1W RPD
LWO W
Total K)eldahl Nitrogen
7.0
0.48
mg/L
4.79 2.1 101 90-110
Matrix Spike Dup (4L19001-MSDl)
Prepared: 12/19/2014 10:52 Analyzed; 12/22J2014 11:58
Source: C413261-01
Spike Source %REC
RPD
llnabma
Basil!
!%e
POL
UAL
Lard MW= %REC UMM RPD
1.181ift Not"
Total K)eldahl Nitrogen
6.8
0.48
MWL
4.79 2.1 97 90-110 3
10
OafCh 4" 003 - Samp
Blank (4L39003-BLKl)
Prepared: 12/19/2014 10:52 Analyzed: 12122/2014 13:56
Spike Source %REC
kpb
Anah[4e
Result
Ha0
PQl
Ualfa
Lend goNft %REC Umb RPD
Limit d9W.
Phosphorus
0.025
u
0.to
mglL
LCB (4L3900343Sl)
Prepared: 12/19/201410:52 Analyzed: 12/22/2014 13:58
Spike Source %REC
RPD
Anahtm
Bait$
Ha0
ML
Units
Level BaW t %REC Nmbs RPD
1f110 notes
Phosphorus
1.6
0.10
mg/L
1.60 49 W120
FINAL ThIS report relates ,niy to the Sample as =04A d by the labaratury, and may Only be reproduced in rul. Paps 9 or 11

wwwAnoolabs.00m
QUALITY CONTROL DATA
(laas al CbemWy Parameters -Quality Control
Bated+ 4110= -'raise - CwWnrned
Matrix Spike (41.19003-MSi)
Prepared: 12/19/2014 10:52 Melyzed: 12/27/2014 14:01
Source: C415291-01
Spike Source
%REC
RPD
�nabda BEBIIt EIM
PQL
UjMb
Leval $gaft
%REC lMIM RPD
Lwa Motu
Phosphorus 1.4
0.10
M91L
0.640 0.78
101 80.120
Mabft Spike Dup (41.19003-MSD1)
Prepared: 12/19/2014 10:52 ArmWed: 12/22/2014 14:03
Source: C4152e1-01
Spike Source
%REC
RPD
AnEhSE BMWH 9dd
201
Ilnlia
Loral gMM
%REC i MJ%g RPD
UmS l
Phosphorus 1.4
0.10
mp/L
0.640 0.78
101 80.120 0.1
25
FUM This report rNaCes ordy to the sample as mWved by the laboft", end may only be reproduced in full. Pages d 11

www.encoU ba mm
FLAGS/NOTES AND DEFINMONS
B The analyte was detected in the associated method blank.
D The sample was analyzed at dilution.
] . The reported value Is between the laboratory method detection limit (MDL) and the laboratory method
reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable.
U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
E The concentration indicated for this analyte Is an estimated value above the calibration range of the
Instrument This value is considered an estimate.
MILL Method Reporting Umit The MRL Is roughly equivalent to the practical quantitation limit (PQL) and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution
factor, and, in the case of soil samples, moisture content
N The analysis indicates the presence of an anatyts for which there is presumptive evidence (85% or greater
confidence) to make a "tentative identification".
Greater than 25% concentration difference was observed between the primary and secondary GC column.
The lower concentration is reported.
B-03 Blank exceeds the method required oxygen depletion of < 0.2 mg/L.
QM-05 The spike recovery was outside acceptance limits for the MS and/or MSD due to matrix
interference. The LCS and/or LCSD were within acceptance limits showing that the laboratory is
in control and the data is acceptable.
QM-12 Precision between duplicate samples was outside acceptance limits.
FINAL This report relabes only t0 the Sample as IeCNVed tH the laboratory, and may only be reproduced In Nil. Page 10 of 11

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