Loading...
The URL can be used to link to this page
Your browser does not support the video tag.
Home
My WebLink
About
NCS000115_MONITORING INFO_20180524
--—STORIVIVHATER-DIVISION-CODiNG-SHEET PERMIT NO. �CSO�'J i1S DOC TYPE ❑FINAL PERMIT MONITORING INFO ❑ APPLICATION ❑ COMPLIANCE ❑ OTHER DOC DATE ❑ aUl$V�dH YYYYMMDD Y w TV NPDES PERMIT NO. NCS000115 FACILITY NAME NOVOZymeS, NA Inc. OPERATOR IN RESPONSIBLE CHARGE (ORC) CERTIFIED LABORATORIES (1) Enco CHECK BOX IF ORC HAS CHANGED E= PERSON(S) COLLECTING SAMPLES Mail ORIGINAL and ONE COPY to: EFFLUENT DISCHARGE NO. 1 CLASS NIA (2) MONTH May YEAR 2018 COUNTY: Franklin PHONE (919) 494-3001 Joe Ladd ATN: CENTRAL FILES x NIA DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) 107 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY RALEIGH, NC 27699-1617 KNOWLEDGE. DWQ Form MR-1 (11/04) ' .V1Y Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) Compliant All monitoring data and sampling frequencies do NOT meet permit requirements ❑ Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the pen -nittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.G of the NPDES permit. "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Randy Green Permittee (Please print or type) Si'nature Permtttee* Date �(Requir less submitted electronically) Permittee Address Phone Number e-mail address Permit Expiration Date Certified Laboratory (2) Certified Laboratory (3) Certified Laboratory (4) Certified Laboratory (5) ADDITIONAL CERTIFIED LABORATORIES PARAMETER CODES Certification No. Certification No. Certification No. Certification No. Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.uslwas and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. Page 2 NPDES PERMIT NO. NCS000115 FACILITY NAME Novozymes, NA Inc. OPERATOR IN RESPONSIBLE CHARGE (ORC) CERTIFIED LABORATORIES (1) Enco EFFLUENT DISCHARGE NO. CLASS NIA (2) CHECK BOX IF ORC HAS CHANGED C==fl PERSON(S) COLLECTING SAMPLES Mail ORIGINAL and ONE COPY to: MONTH May YEAR 2018 COUNTY: Ffanklin PHONE (919) 494-3001 Joe Ladd ATTN: CENTRAL FILES K WA DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) 1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY RALEIGH, NC 27699-1617 KNOWLEDGE. Monthly Limit DWQ Form MR-1 (11/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) Compliant All monitoring data and sampling frequencies do NOT meet permit requirements ❑ Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part i1.E.6 of the NPDES permit. "1 certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Permittee Address Certified Laboratory (2) Randy Green Permittee (Please print or type) Si ture P ittee ** Date equired unIUs submitted electronically) Phone Number e-mail address Permit Expiration Date ADDITIONAL CERTIFIED LABORATORIES Certification No. Certified Laboratory (3) Certification No. Certified Laboratory (4) Certified Laboratory (5) PARAMETER CODES Certification No. Certification No. Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.us/wgs and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. Page 2 #; .ENCO Laboratories Accurate. Timer. Responsive. Innovative. 102-A woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Tuesday, May 8, 2018 Novozgmes North America (N0008) Attn: Joe Ladd 77 Perry Chapel Church Road Frankiinton, NC 27525 RE: Laboratory Results for Project Number: [nonej, Project Name/Desc: Stormwater Testing ENCO Workorder(s): CB01514 Dear Joe Ladd, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Wednesday, April 25, 2018. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Chuck Smith Project Manager Enclosure(s) FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full, Page 1 of 10 CaNS Ili: go www.encolabs.00m SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: Outfa111 lab ID: CB01514-01 Sampled: 04/24/18 11:40 Received: 04/25/18 08.07 Parameter EPA 351.2 Preoaradon Same Hold Data/Tlme(s) 05/22/18 Pren DatelTlme(s) 04/30/18 11:44 Analysts Date/Time(s) 05/03/18 14:03 EPA 353.2 NO PREP 04/26/18 11:40 04/25/18 18:02 04/Z5/18 18:02 EPA 353.2 NO PREP 01/17/21 05/07/18 14:55 05/07/18 15:07 EPA 365.4 Same 05/22/18 04/30/18 11:44 05/03/18 14:57 SM 2540D-1997 NO PREP 05/01/18 05/01/18 15:35 05/01/18 15:35 SM 5210B-2001 NO PREP 04/26/18 11:40 04/25/18 11:05 04/25/18 11:05 SM 5220D-1997 Same 05/22/18 04/26/18 10:42 04/26/18 21:06 Client ID: Outfail 1 Lab ID: CB01514-01RE1 Sampled: 04/24/18 11:40 Received: 04/25/19 08:07 Parameter EPA 353.2 Preoaradon NO PREP Hold Date/Timefs) 05/22/18 Prep Date/Time(s) 05/04/18 16:39 Analysts Date/Tlme(s) 05/04/18 16:39 Client 10: Outfall 2 Lab ID: CB01514-02 Sampled: 04/24/18 12:30 Received: 04/23/18 08:07 Parameter EPA 351.2 Preparation Same Hold Date/Time(s) 05/22/18 Prep Date/Time(s) 04/30/18 11:44 Analysis DatelTlme(sl 05/03/18 14:08 EPA 353.2 NO PREP 04/26/18 1230 0405/18 18:05 04/25/18 18:05 EPA 353.2 NO PREP 05/22/18 05/04/18 15:39 05/04/18 15:39 EPA 353.2 NO PREP 01/17/21 05/07/18 14755 OS/07/18 15:07 EPA 365.4 Same 05/22/18 04/30/18 11:44 05/03/18 15:01 SM 2540D-1997 NO PREP 05/01/18 05/01/18 15:35 05/01/18 15:35 SM 52108-2001 NO PREP 04/26/18 12:30 04/25/18 11:05 04/25/18 IhOS SM 5220D-1997 Same 05/22/18 04/26/18 10:42 04/26/18 21:06 FINAL This report relates only to the sample as recelved by the laboratory, and may only be reproduced in full. Page 2 of 10 www.eneciabs.com SAMPLE DETECTION SUMMARY Client ID: _ Outfall 1 tab ID: CB01514-01 Anallrlm Results E11tU Hu Eltl. mom M13th� �L4t1:9 Biochemical Oxygen Demand 2.7 2.0 2.0 mg/L SM 52108-2001 Chemical Oxygen Demand 14 10 10 mg/L SM 5220D-1997 Nitrate as N 2.9 0.025 0.10 mg/L EPA 3531 Nitrite as N 0.086 3 0.017 0.10 mg/L EPA 353.2 Phosphorus 0.16 0.025 0.10 mg/L EPA 365.4 Total Kjeldahl Nitrogen 1.3 0.26 0.48 mg/L EPA 351.2 Total Suspended Solids 57 10 10 mg/L SM 254OD-1997 Client ID: OuHell 1 Lab ID: CB01514-OLRE1 Anal lda Results fhm MU EQL malb HeMod Notes Nitrate/Nibl as N 3.0 0.20 0.50 mg/L EPA 353.2 Client ID: Outfall 2 Lab ID: CB01514-02 Al Rssulta Elan MBL EQL Units Mathes Notes Biochemical Oxygen Demand 14 2.0 2.0 mg/L SM 521OB-2001 Chemical Oxygen Demand 55 10 10 mg/L SM 5220D-1997 Nitrate as N 0.046 3 0.025 0.10 mg/L EPA 353.2 Nitrate/Nitrite as N 0.046 3 0.041 0.10 mglL EPA 353.2 Phosphorus 0.10 0.025 0110 mg/L EPA 365.4 Total Kjeldahl Nitrogen 1.0 0.26 0.48 mglL EPA 351.2 Total Suspended Solids 16 10 10 mg/L SM 254OD-1997 a FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In Full. Page 3 of 10 CaNS go www.encolobs.com ANALYTICAL RESULTS Description: Outfall 1 Lab Sample ID. CB015 14-01 Received: 04/25/18 08:07 Matrix: Surface Water Sampled:04/24/18 11:40 Work Order: CB01514 Project: Stormwater Testing Sampled By:]oe Ladd Classical Chemistry Parameters ^-EACOCary cer0 da-6-(NC 5911 Agaiyte [CAS Numberl Results flag Units PE MU E91 ARI&h Method Analyzed Notes Biochemical Oxygen Demand^ 2.7 mg/L 1 2.0 2.0 BD25014 SM 52148-2001 04/25/18 11:05 10C Chemical Oxygen Demand^ 14 mg/L 1 10 10 8D26008 SM 5220D-1997 04/26/18 21:D6 30C Nitrate as N [14797-SS-8]^ 2.9 mg/L 1 0,025 0.10 8E07038 EPA 353.2 05/07/18 15:07 3L] Nitrate/Nlbite as N^ 3.0 mg/L 5 0.20 0.50 8ED4037 EPA 353.2 05/04/18 16:39 3L1 Nitrite as N [14797-65-0]^ 0.086 3 mg/L 1 0.017 0:10 8D25032 EPA 353.2 04/25/18 18:02 ILI Phosphorus [7723-14-0]^ 0.16 mg/L 1 0.025 0.10 8D30011 EPA 365.4 05/03/18 14:57 3U Total Kjeldahl Nitrogen^ 1.3 mg/L 1 0.26 0.48 BD30010 EPA 351.2 05/03/18 14:03 ILI Total Suspended Solids 57 mg/L 4 10 10 8E01002 SM 7540D-1997 05/01/18 15:35 0MR Description: Out%ll 2 Lab Sample ID-.CB01514-02 Received: 04/25/18 08:07 Matrix: Surface Water Sampled:04/24/18 12:30 Work Order: CB01514 Project: Stormwater Testing Sampled By:]oe Ladd Classical Chemistry Parameters ^ - ENCO Cary certified analyre [NC 5911 Analyte rCAS Number] 801111to gin Units QF ► u pU g= Method Analyzed ax Note Biochemical Oxygen Demand^ 14 mg/L 1 2.0 2.0 8D25014 SM 52108-2001 04/25/18 11:05 10C Chemical Oxygen Demand^ 55 mg/L 1 10 10 8D26008 SM 5220D-1997 04/26/18 21:06 30C Nitrate as N [14797-55-8]^ 0.046 3 mg/L 1 0.025 0.10 8E07038 EPA 353.2 05/07/18 15:07 3U Nitrate/Nitrite as N^ 0.046 3 mg/L 1 0.041 0.10 8ED4037 EPA 353.2 05/04/18 15:39 3u Nitrite as N [14797-65-0]^ 0.017 u mg/L 1 0.017 0.10 8D25032 EPA 353.2 04/25/18 18:05 3U Phosphorus17723-14-0]^ 0.10 mg/L 1 0.025 0.10 SD30011 EPA 365.4 05/03/18 15:01 3U Total KJeldahl Nitrogen^ 1.0 mg/L 1 0.26 0.48 8D30D10 EPA 351.2 05/03/18 14:08 3u Total Suspended Solids^ 16 mg/L 4 10 10 BE01002 SM 254OD-1997 05/01/18 15:35 DMR FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 4 of 10 www.encolabs.com QUALIFY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch BD25014 - NO PREP Blank (BD25014-BLKl) Prepared & Analyzed: 04/25/2018 11:05 Spike Source %REC RPD .Anallds Result F.184 ML Volts Level Result %REC Limits RPD Llm(t Notes Biochemical Oxygen Demand 2.0 U 2.0 mg/L LCS (8D25014-BSL) Prepared & Analyzed: 04/25/2018 11:05 Spike Source %REC RPD Anal tds Reiuit Elan P41 Units Level Resul %REC Limits RPD Limit Notes Biochemical Oxygen Demand 210 2.0 mg/L 198 107 85-115 Duplicate (8025014-DUPl) Prepared & Analyzed: 04/25/2018 11:05 Source. C501314-01 Spike Source %REC RPD Anal ][te RUMM E109 PAL UwU Level Result %REC Limits RPD Limit Notes Biochemical Oxygen Demand 216 2.0 mg/L 2.7 3 30 Batch OD25032 - NO PREP Blank (BD25032-BLK1) Prepared: 04/25/2018 18:01 Analyzed: 04/25/2018 18:01 Spike Source %REC RPD Anal lrt® Result Ela2 P4L Units Level Result %REC Limits RPD Lbh Note Nitrite as N 0.017 U 0.10 mg/L LCS (8D25032.851) Prepared: 04/25/2018 18:12 Analyzed: 04/25/2018 18:12 Spike Source %REC RPD Aneltte Result Elan M Units Level Result %REC Limits RPD Limp Notes Nitrite as N 0.99 0.10 mg/L 1.00 99 90.110 LCS (8D25032-BS2) Prepared: 04/26/2018 10:43 Analyzed: 04/26/2018 10:43 Spike Source %REC RPD -Analyze Result Elan POL Units Level Result %REC Limits RPD Ljm[t Notes Nitrite as N 0.96 0.10 mg/L 1.00 96 90-I10 LCS (8D25032-BS3) Prepared: 04/26/2018 10:46 Analyzed: 04/26/2018 10:46 Spike Source %REC RPD Anal Yte Result Elan PM Units Level Result %REC Limits RPD Llm[t Notes Nitrite as N 0.96 0.10 mg/L 1.00 96 90-110 Matrix Spike (8D25032-MS1) Prepared: 04/25/2018 18:03 Analyzed: 04/25/2018 18:03 Source: C001514-01 Spike Source %REC RPD Anal Yta Result F1ao P4L Units Level flasult %REC . Llmlts RPD limit Notes Nitrite as N 1.1 0.10 mg/L 1.00 0.086 99 90-110 Matrix Spike (8025032-MS2) Prepared: 04/25/2018 18:06 Analyzed: 04/25/2018 18:06 Source: CROIS14-02 Spike Source %REC RPD .Anal lfte Result flag P4L Unita Level Result %REC Limltg RPD Limit Notes Nitrite as N 0.98 0.10 mg/L 1.00 0.017 U 98 90-110 Matrix Spike Dup (BD25032-MSD1) Prepared: 04/25/2018 18:04 Analyzed: 04/25/2018 18:04 Source: C001514-01 Spike Source %REC RPD Anal fde 112sulf EI84 E41 Units Level Result %REC Limits RPD LIMR Notes FINAL This report relates only to the sample as recelved by the laboratory, and may only be reproduced In full. Page 5 of 10 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 8D25032 - NO PREP - Condhoed Matrix Spike Dup (BD25032-MSDI) Continued Prepared: 04/25/2018 18:04 Analyzed: 04/25/2018 18:04 Source: CB01514-01 Spike Source %REC RPD Anallds Result film POL tln[ts Level Result %REC Llmlta RPD Limit Notes Nitrite as N 1.1 0.10 mg/L 1.00 0.086 100 90-110 0.9 10 Balch 8D26008 - Same Blank (SD26008-BLKl) Prepared: 04/26/2018 10:42 Analyzed: 04/26/2018 21:06 Spike Source %REC RPD Anal 1 ies111t Elea IPQL Slnits Level Result %REC Limits RPD Llmlt Notes Chemical Oxygen Demand 10 U 10 mg/L LCS (8D26008-BS3) Prepared: 04/26/2018 10:42 Analyzed: 04/26/2018 21:06 Spike Source %REC RPD Anal srte Result Elan PQL units Level Result %REC u nrits RPD LltDlt dotes Chemical Oxygen Demand 480 10 mg/L 500 96 90-110 Matrix Spike (8026008-MSI) Prepared: 04/261201B 10:42 Analyzed: 04/26/2018 21:06 Source: CB01514-01 Spike Source %REC RPD Anal 1 Result Flag POL Units Level Result %REC Limits RPD Limb Notes Chemical Oxygen demand 550 10 mg/L 526 14 101 90.110 Matrix Spike Dup (BD26008-MSD3) Prepared: 04/26/2018 10:42 Analyzed: 04/26/2018 21:06 Source:CB01514-01 Spike Source %REC RPD Anall[te Result Elaa P- 1 uAlta Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 550 10 mg/L 526 14 101 90-110 0.4 10 Batch 8030010 - Same Blank (BD30010-BLK1) Prepared: 04/30/2018 11:44 Analyzed: 05/03/2018 13:59 Spike Source %REC RPD .AnalYts Result Elan M clops Level Result %REC Limi>s RPD Limit Notes Total Kjeldahl Nitrogen 0.26 U 0.48 mglL LCS (8D30030-BSI) Prepared: 04/30/2018 11:44 Analyzed: 05/03/2018 14:01 Spike Source %REC RPD Anal ][t8 Result fin PM !lops Level Sesuls %REC LIMjg RPD Limit Notes Total Kjeldahl Nitrogen 12 0.48 mg/L 12.0 97 90-110 Matrix Spike (811330010-M53) Prepared: 04/30/2018 11:44 Analyzed: 05/03/2018 14:05 Source: C001514-01 Spike Source %REC RPD -llnallde Result Flag P_QL units Level Result %REC Limits RPD Llmlt Notes Total Kjeldahl Nitrogen 5.9 0.48 mg/L 4.80 1.3 96 90-110 Matrix Spike (811)30010-M52) Prepared: 04/30/2018 11:44 Analyzed: 05/03/2018 14: 10 Source: C001514-02 Spike Source %REC RPD .Anal Yil4 Result Elan PM Units Level Maul %REC Limits RPD Limn )Votes Total Kjeldahl Nitrogen 5.9 0,48 mg/L 4.80 1.0 102 90-110 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 6 of 1a www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch SD30010 - Same - Continued Matrix Spike Dup (81330010-11411501) Prepared: 04/30/2018 11:44 Analyzed: 05/03/2018 14:06 Source: CB01514-01 Spike Source %REC RPD Anal Result Sao POL Units Level Result %REC Limltt RPD Limit Nme9_ Total Kjeldahl Nitrogen 6.0 0.48 mg/L 4.80 1.3 98 90-110 1 10 Batch BD30011 - same Blank (8D30011-8LK1) Prepared: 04/30/2018 11:44 Analyzed: 05/03/2018 14:54 Spike Source %REC RPD Anal Result fin PQL UAM Level Result %REC Lialb RPD UMR tiotes Phosphorus 0.042 3 0.10 mg/L LCS (BD30011-BS3) Prepared: 04/30/2018 11:44 Analyzed: 05/03/2018 14:56 Spike Source %REC RPD Ana Result Flap POL Unm Level Reallii %REC Limits RPD Limit Notes Phosphorus 1.5 0.10 mg/L 1.60 96 BO-120 Matrix Spike (BD30011-MS1) Prepared: 04/30/2018 11:44 Analyzed: 05/03/2018 14:58 Source: CB01514-01 Spike Source %REC RPD Anal lrse Rumit Elan EM Units Level Resin %REC Limits RIND Limit dotes Phosphorus 0.82 0.10 mg/L 0.640 0.16 102 80-120 Matrix Spike Dup (81330011-M51131) Prepared: 04/30/2018 11:44 Analyzed: 05/03/2018 15:00 Source: C001514-01 Spike Source %REC RPD AnaL1tt® Result Elate PQL Units Level Result %REC Limits RPD Limit Notes Phosphorus 0.77 0.10 mg/L 0.640 0.16 95 80-120 6 25 Batch SEOIOOZ - NO PREP Blank (8E01002-BLK1) Prepared & Analyzed: 05/01/2018 15:35 Spike Source - %REC RPD Anal vte Result Elal7 POL Units Level Result %REC LimJtg RPD ;unit Notes Total Suspended Solids 2.5 U 2.5 mg/L LCS (SE01002-BS1) Prepared & Analyzed: 05/01/2018 15:35 Spike Source %REC RPD Anal Yte Resin flag P4L 11111113 Level Resin %REC Limits RPD j,imit Notes - Total Suspended Solids 88 2.5 mg/L 100 88 80-120 Duplicate (BE01002-131JI131) Prepared & Analyzed: 05/01/2018 15:35 Source: CRO1514-01 Spike Source %REC RPD Anal Result Elan POL Units Level Besult %REC Limlt>} RPD Limit Notes Total Suspended Solids 53 10 mg/L 57 7 20 Duplicate (SE01002-DUP2) Prepared & Analyzed: 05/01/2018 15:35 Source: CB01690-01 Spike Source %REC RPD Anal tda Result Flag PQL units Level ResulF %REC Limits RPD Limit !Notes Total Suspended Solids 100 12 mg/L 110 0.5 20 Batch BE04037 - NO PREP FINAL This report relates only to the sample as recelwd by the laboratory, and may only be reproduced In full. Page 7 of 10 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - quality Control Batch 8E04037 - NO PREP - Candnued Blank (BE04037-BLKi) Prepared: 05/04/2018 15:30 Analyzed: 05/04/2018 15:30 Spike Source %REC RPD Anal lfts Result Etna POL halts Level USUIi %REC Limits RPD Limit Notes Nitrate/Nitrite as N 0.041 U 0.10 mg/L LCS (8E04037-111S3) Prepared: 05/04/2018 15:32 Analyzed: 05/04/2018 15:32 Spike Source %REC RPD Anal l[ts Result Elan POL Lill ie Level Result a/aREC Limits RPD Limit Notes Nitrate/Nitrite as N 1.2 0.10 mg/L 1.25 99 90-110 Matrix Spike (SE04037-MS1) Prepared: 05/04/2018 16:40 Analyzed: 05/04/2018 16:40 Source: CBOLS14-01RE1 Spike Source %REC RIM Anal Res11it Elea P_QL hells Level Result %REC LWIM RPD Limit Notes Nitrate/Nitrite as N 5.3 0.50 mg/L 2.50 3.0 93 90-110 Matrix Spike (BE04037-MS2) Prepared: 05/04/2018 15:41 Analyzed: 05/04/2018 15:41 Source: CB0LS14-02 Spike Source %REC RPD Anal Yte Result an P- 1 iialcs Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 0.61 0.10 mg/L 0.521 0.046 108 90-110 Matrix Spike Dup (SE04037-MSDi) prepared: 05/04/2018 16:41 Analyzed: 05/04/2018 16:41 Source: CB01514-0111M Spike Source %REC RIM Anal ldn Result Elan POL ilnits Level Result %REC Limits RPD Limit Notes Nltrate/Nitrite as N 5.2 0.50 mg/L 2.50 3.0 91 90-110 0.9 10 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 8 of 10 www.enoDiabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. 3 The reported value is between the laboratory method detection limit (MDQ and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 9 of 10 enrsnvnen�taxrlLLAJlVar-nVM11Moll LJ4OUnMlUrilC.7 L.r1Hl1Y-Uti.U,IULJT Kt%;UKU www.encolabS.COM �O 10775 Central Port Dr. 4816 Executive Park Court, Suite 111 102-A WoodwnMs CL Orlando, FL 32ti'M4 -hdaorwft, FL 32216-6MG Cary, NC 27511 l (407) U6.5314 Fax (407) M 945 (904) 296,lw Fax (904) 296-WiO (9t9) 467-MM Fax (s19) "7-MI s Page —L Dt Client Name Prajed Number 1 Rqe-sted Requested Tumaround Times til+sh requests 51WjBCi w ON bici - Standard — EXPedied Due _lam pp C - , to m p M %j cn ° N C� ro a) M 1 z rV. LO Z m I z � MU') `s' 2 a cj Cn X © 0 A to (n z ICE301514 Address 77 Peny Oisgul Chtirch Road Pmjed NamaloescNote:- water Tesfing CuyIST/Z7p Frankfinton NC 27525 PO a l wirg Irdo 3800384801 Tel 494-3370 Fax Reporting Contact .hie Ladd Sarn;i"s) Name, Affiliation (Print) oZ Gr fS, Aj,4 Trlc Bffmg Corded Accounts Peyable Sam 04.J Sue Location / Time Zone Lab Workarder Preservation ISee Codes) (Combine as ) (tern $ Sample ID (Field tdentirica m) Cd 'Cixin Cous ctidt T-ena Comp I Grab wtd. (see codes) TOW i of Curdainere Sample Comments s-}-��1-� }l' O Gra4c + - �e M f -- 3G Grr�b <-- Total H of Containerq Sample Wt Prepared 8 DetrJf /A Relinquished By DauVrOne Received _ .. , L— . e t Commfann`tI'aiS�pecialll Replorfingtl aq ii�rements Relinquished By DaUdTime ta/ilme V l.e ITrn 1 L f ' Rarveyuished By Date/T•m1e Received By Dateltime Cooler t'a d Temps on Receipt (� � •� Conditbn U Receipt Acceptable Unacceptable Ailab'6t : GW-Gmund++ater SO•Sal DW-Drinking Water SE-Setlment SIV-Srrtace Water WW-Wastewater A -Air o-Other WOW in POrmnerts) Prue: Mice WHCI N-HNO3 S4M22SO4 NO-NaCH Other (datai in comments) Moto: M samples su6nvW to ENCD Labs are in ammdarxx rsth pro terms and con libons ksted on lire revere of ads berm, lades prior written agreements exist Sample Preservation Verification ENCO Cary i Work Order: CB01514 Project: Stormwater Testing Client: Novozymes North America (N0008) Project M (none) Logged In: 25-Apr-18 08:31 Logged By: John C King Preservation Check Performed By: � Date7ime: CB01614-01 Cant .�, Type �t _ rss� p Re quire , p ' i ticks1� -. In 3, ate imea �pHtRd�ustea� „, ,;Adjusted >. �, 6V�� Reagent UsadlGomments �i D 250mLP+H2SO4 <2 I N I NA Y I 1 NA CB01514-02 ,Counts )ype�� .' .88_-� p s ' - e ate me pH:Ad)usted n �s90 Reagent{�UsedlGomments _.,`_ _ : 5,°rt ,#RequirementIri Control:. yAdlustect-. r� _ _05 D 250mLP+H2SO4 <2 Y I N I NA Y/ 1 NA Reagent Name ID 1 1. 2 pH Strip ID: Cn—EUF20 Reacient Name ID Reacient Name ID 3 5 4 6 C:1ELMN'RPdntlwko_PreservatlonCheck.rpt Page 1 12-OCT-2007 - 2007-50 05-JUL-2010 2010-2589 Notification DREWCHLORO 4107 INDUSTRIAL GUARANTEE: SODIUM CHLORITE ...... 25% REGISTRATION No. 24887 PEST CONTROL PRODUCTS ACT KEEP OUT OF REACH OF CHILDREN DANGER POISON - CORROSIVE CORROSIVE TO EYES AND SKIN READ THE LABEL BEFORE USING NET CONTENTS XWGTX LOT # X BATX DREW CANADA, ASHLAND CANADA CORP. Ashland Canada Corp. 525 FINLEY AVE., AJAX, ONTARIO L1S 2E5 2620 Royal Windsor Drive Tel: (905) 683-0150 Mississauga, Ontario Fax: (905) 427-0688 9 AFTER HOURS: 1-800-274-5263 L5J 4E7 LIQUID BLEND OF SODIUM CHLORITE FOR USE AS ALGICIDE AND SLIMICIDE IN RECIRCULATING COOLING WATER SYSTEMS. USE RESTRICTION: This product is to be used only in closed system chlorine dioxide generators for controlling slime forming organisms in industrial re -circulating cooling waters. Follow all instructions for the chlorine dioxide generator carefully and follow all safety measures required for the use of this product and the generator. Generators are to be installed, adjusted and maintained by specially trained service representatives only. DIRECTIONS FOR USE: RECIRCULATING COOLING WATER SYSTEMS 0 0, 1) Drewchlor 4107 is to be used only in closed system generators designed specifically for generating chlorine dioxide. Eg. GENEROX one, or three pump systems. Read carefully and follow all instructions for operating and maintaining the chlorine dioxide generator. Operators and maintenance personnel require specialized training. 2) For continuous treatment, maintain a point source residual chlorine dioxide level of 0.5 ppm to 5.0 ppm depending on microbial pressure on the system. For cleaning systems and for slug or intermittent treatment, treat the system to obtain a point source level of 5.0 ppm to 100 ppm chlorine dioxide in the system. Refer to Drew analytical methods to determine the chlorine dioxide demand and to calculate appropriate residual chlorine dioxide levels for the system." 3) "Read the product safety bulletin for Drewchlor 4107 and the product safety bulletin and MSDS sheets for co -reactants prior to using this product. ONE PUMP METHOD: For intermittent feed add 2.555 to 51.1 ppm DREWCHLOR* 4107 and 2.630 to 52.6 ppm chlorine gas. For continuous feed add 0.255 to 2.555 ppm of DREWCHLORO 4107 and 0.263 to 2.630 ppm of chlorine gas. THREE PUMP SYSTEM: For intermittent feed add 2.555 to 51.1 ppm DREWCHLOe 4107, 2.15 to 43.0 ppm DREW 6110 (sodium hypochlorite) and 0.90 to 18.0 ppm DREW 6005 (hydrochloric acid). For continuous feed add 0.255 to 2.555 ppm DREWCHLOR® 4107, 0.215 to 2.15 ppm DREW 6110 (sodium hypochlorite) and 0.09 to 0.9 ppm DREW 6005 (hydrochloric acid). i;1:��L�I1��C�L`L•� KEEP OUT OF REACH OF CHILDREN. DANGER - CORROSIVE TO EYES AND SKIN. Harmful if swallowed or inhaled. Do not get in eyes, on skin, mucous membranes or on clothing. Do not inhale. Wear long sleeved shirt and long pants, chemical resistant gloves, goggles or face shield, a chemical resistant apron and boots when handling this product. Wash thoroughly with soap and water after handling and before eating, drinking, smoking and using toilet. Remove contaminated clothing and wash before reuse. DO NOT WEAR contaminated clothing. PHYSICAL AND CHEMICAL CAUTIONS: This material is corrosive and a strong oxidizing agent. Contact with organic matter may cause fire or explosion. Mixing with acids or alcohol or other chemicals may cause evolution of chlorine and chlorine dioxide gas mixture which is toxic and may be explosive. Avoid contamination with combustible materials such as oils, grease, solvents, paint products etc as rapid burning may occur. STORAGE: Store in a cool, dry area. (<250C) FIRST AID: CONTACT WITH SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Cali a poison control centre or doctor for treatment advice. INGESTION: Call a poison control centre or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control centre or doctor. Do not give anything by mouth to an unconscious person. CONTACT WITH EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control centre or doctor for treatment advice. INHALATION: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by mouth -to mouth, if possible. Call a poison control centre or doctor for further treatment' advice. Take container, label or product name and Pest Control Product Registration Number with you when seeking medical attention. TOXICOLOGICAL INFORMATION: Treat symptomatically. DISPOSAL: 1. Triple- or pressure- rinse the empty container. Add the rinsings to the treatment site. 2. Follow provincial instruction for any required additional cleaning of the container prior to its disposal, 3. Make the empty container unsuitable for further use. 4. Dispose of the container in accordance with provincial requirements. 5. For information on disposal of unused, unwanted product, contact the manufacturer or the provincial regulatory agency. Contact the manufacturer and the provincial regulatory agency in case,of a spill, and for clean-up of spills. ENVIRONMENTAL PRECAUTIONS; This product is highly toxic to aquatic invertebrates and moderately toxic to water fowl. Do not contaminate lakes, ponds, rivers, streams, estuaries, or oceans, by direct application, cleaning of equipment or disposal of wastes. Do not discharge effluent that has been treated with chlorine dioxide generated by this product into these waters unless the effluent has been detoxified by suitable means such as waste treatment. For further environmental information refer to Drew Environmental Profile sheet OX-EP-003 . Open dumping is prohibited. DECONTAMINATION: Contain spilled material, then add sodium sulfite at 2.8 parts per 1 part of sodium chlorite. Do not allow oxidizable or other incompatible materials to come into contact with spilled material. Use copious amounts of water to flush the residual to a sanitary sewer or waste treatment plant. DO NOT FLUSH INTO SURFACE WATERS. NOTICE TO USER: This pest control product is to be used only in accordance with the directions on the label. It is an offence under the Pest Control Products Act to use this product in a way that is inconsistent with the directions on the label. The user assumes the risk to persons or property that arises from any such use of this product. UN# 1908 Sodium chlorite solution, with more than 5% available chlorine This label transcript service is offered by the Pest Management Regulatory Agency to provide efficient searching for label information. This service and this information do not replace the official hard -copy label. The PMRA does not provide any guarantee or assurance that the information obtained through this service is accurate, current or correct, and is therefore not liable for any loss resulting, directly or indirectly, from reliance upon this service. r1 30-JUL-2007 22-APR-2010 2010-1112 Notification : Change in registrant name CLOSURE CENTRAL PM For use in Closed System Mechanical Generation of Chlorine Dioxide only for Microbial Control in Recirculating Cooling Systems and Pulp and Paper Mills COMMERCIAL READ THE LABEL BEFORE USING GUARANTEE: Chlorine Dioxide from Sodium Chlorite.............................25% (nominal) DANGER POISON CORROSIVE TO EYES AND SKIN REGISTRATION NO 28674 PEST CONTROL PRODUCTS ACT Net Contents; (5L to 1249L) JohnsonDiverscy Canada, Inc. Diversey Canada Inc. 2401 Bristol Circle, Oakville, Ontario L6H 6P 1 Canada 800-668-7171 0 0 , 4-3. . � 4 1 . 4 Use Restriction: This product is only to be used in closed system chlorine dioxide generators for controlling slime forming organisms in pulp and paper process waters. Follow all instructions for the chlorine dioxide generator carefully and follow all safety measures required for the use of this product and generator. Generators are to be installed, adjusted and maintained by specially trained service representatives only. DIRECTIONS FOR USE CLOSURE CENTRAL PM is a source of chlorine dioxide used for microbial control in recirculating cooling towers and pulp and paper mill processing water. The required dosage rate, frequency and concentration will'vary for each user depending on the degree of microbiological and process contamination present, the temperature and.the pH. Typical concentrations of chlorine dioxide are between 0.5 - 5.0 ppm for continuous doses, and between 5.0 ppm and 100 ppm for intermittent shock doses. To generate chlorine dioxide, use a chlorine dioxide generator. Consult product bulletin and also the instructions on the chlorine dioxide generation system before using CLOSURE CENTRAL PM. Your JohnsonDiversey representative can guide you in the selection, installation and operation for feed systems. The generators react CLOSURE CENTRAL PM to produce an aqueous solution of chlorine dioxide. This solution is then added at a point in the.processing system to be treated which ensures uniform mixing. Feed points should be well below the surface of the water to prevent volatilization of the chlorine dioxide. Do not apply CLOSURE CENTRAL PM directly to the system being treated. Follow all instructions in the chlorine dioxide generator manual carefully. PRECAUTIONS KEEP OUT OF REACH OF CHILDREN. DANGER - CORROSIVE TO EYES AND SKIN. Maybe fatal if absorbed through the skin, swallowed or inhaled. Do not get in eyes, or on skin, or clothing. Do not inhale. Wear a long sleeved shirt and long pants, chemical resistant gloves, goggles or face shield and chemical resistant apron and boots when handling this product. Wash thoroughly with soap and water after handling and before eating, drinking, smoking and using the toilet. Remove contaminated clothing and wash before reuse. DO NOT WEAR contaminated clothing. Environmental Hazards: This product is highly toxic to aquatic invertebrates and moderately toxic to waterfowl. Do not contaminate lakes, ponds, rivers, streams, estuaries or oceans by direct application, cleaning of equipment or disposal of wastes. Open dumping is prohibited. Do not discharge effluent that has been treated with chlorine dioxide generated by this product into these waters unless the effluent has been detoxified by suitable means such as waste treatment. Chemical Hazards: Sodium chlorite is corrosive and a strong oxidizing agent. Contact with organic matter may cause fire or explosion. Mix only into water. Mixing with acids, alcohol or other chemicals may cause evolution of chlorine and chlorine dioxide gas which is toxic and may be explosive. Avoid contaminating with combustible materials, such as oils, grease, solvents, and paint products as rapid burning may occur. FIRST AID If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control centre or doctor for treatment advice. If swallowed: Call a poison control centre or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control centre or doctor. Do not give anything by mouth to an unconscious person. If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control centre or doctor for treatment advice. If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by mouth-to-mouth, if possible. Call a poison control centre or doctor for further treatment advice. Take container, label or product name and Pest Control Product Registration Number with you when seeking medical attention. TOXICOLOGICAL INFORMATION Treat symptomatically. STORAGE: Do not contaminate water, food or feed by storage or disposal. Keep product in tightly closed container when not in use. Do not drop, roll or skid drum. Keep upright. Always replace cover. Store in a cool (< 25°C), dry, well -ventilated area away from heat or open flame. DISPOSAL: • Triple or pressure -rinse the empty container. Add the rinsings to the treatment site. • Follow provincial instruction for any required additional cleaning of the container prior to its disposal. • Make the empty container unsuitable for further use. Dispose of the container in accordance with provincial requirements. • For information on disposal of unused, unwanted product, contact the manufacturer or the provincial regulatory agency. Contact the manufacturer and the provincial regulatory agency in case of a spill, and for clean-up of spills. DECONTAMINATION • Contain spilled material. • Do not allow oxidizable or other incompatible materials to come into contact with spilled materials. • DO NOT FLUSH INTO SURFACE WATERS. NOTICE TO USER This pest control product is to be used only in accordance with the directions 'on the label. It is an offence under the Pest Control Products Act to use this product in a way that is inconsistent with the directions on the label. The user assumes the risk to persons or property that arises from any such use of this product. Y • • This label transcript service is offered by the Pest Management Regulatory Agency to provide efficient searching for label information. This service and this information do not replace the official hard -copy label. The PMRA does not provide any guarantee or assurance that the information obtained through this service is accurate, current or correct, and is therefore not liable for any loss resulting, directly or indirectly, from reliance upon this service. • v ASHLAIO SAFETY DATA SHEET DREWTM 6134 DECHLORINATING AGENT 51057 Page: 1 Revision Date: 01/24/2008 Print Date: 6/11/2008 MSDS Number: R0290797 Version: 1.2 1.. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Ashland Regulatory Information Number 1-800-325-3751 P.O. Box 2219 Telephone 614-790-3333 Columbus, OH 43216 Emergency telephone 1-800-ASHLAND (1-800-274-5263) Product name DREW rm 6134 DECHLORINATING AGENT Product code 51057 Product Use Description No data 2. HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid„ light yellow DANGER! MAY BE HARMFUL IF INHALED. HARMFUL IF SWALLOWED. CAUSES EYE IRRITATION. MAY CAUSE SKIN AND RESPIRATORY TRACT IRRITATION. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE DERMATITIS AND BURNS. Potential Health Effects Routes of exposure Inhalation, Skin contact, Eye Contact Eye contact Can cause severe eye irritation. Symptoms include stinging, tearing, redness, and swelling of eyes. Can injure eye tissue. Skin contact Can cause skin irritation. Symptoms may include redness and burning of skin, and other skin damage. Additional symptoms of skin contact may include: allergic skin reaction (delayed skin rash which may be followed by blistering, scaling and other skin effects) Ingestion Swallowing this material may be harmful. Page 1 / 8 • • jASWLAN13. SAFETY DATA SHEET DREWTM 6134 DECHLORINATING AGENT 51057 Page: 2 Revision Date: 01 /24/2008 Print Date: 6/11/2008 MSDS Number: R0290797 Version: 1.2 Inhalation It is possible to breathe this material under certain conditions of handling and use (for example, during heating, spraying, or stirring). Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. Excessive heat or contact with acids, water and/or ice, releases sulfur dioxide gas which may be harmful or deadly'if inhaled. Aggravated Medical -Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, Skin, lung (for example, asthma -like conditions) Symptoms Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways), convulsions, and death, Exposure to this product (or a component) may cause an allergic reaction (narrowing of the air passages of the lungs resulting in difficult breathing, tightness in the chest, coughing and wheezing) in some sensitive individuals. Other symptoms of an allergic reaction may include itchy and watery eyes, runny and stuffy nose, sweating, flushing, hives, rapid heart, rate, and lowered blood pressure. Target Organs No data Carcinogenicity No data Reproductive hazard No data Other information Exposure to this material may cause severe or fatal allergic reaction in some asthmatics and sulfite sensitive individuals. Allergic reactions are immediate following breathing, injection or ingestion of oral solutions. Ingestion of solids or food particles may delay the onset of symptoms, with a maximal effect 30 to 90 minutes after ingestion. 3. COMPOSITION/INFORMATION ON INGREDIENTS Paget/8 ONE • ASHLAND SAFETY DATA SHEET DREWTM 6134 DECHLORINATING AGENT 51057 Page: 3 Revision Date: 01/24/2008 Print Date: 6/11/2008 MSDS Number: R0290797 Version: 1.2 _Components CAS -No. _ _ _ Concentration SODIUM HYDROGEN SULFITE 7631-90-5 >=40-<50% INORGANIC SALT NJTS# 254504001-5245 >=5-<10% SODIUM SULFITE 7757-83-7 >= 5-<10% 4. FIRST AID MEASURES Eyes If symptoms develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. Skin Remove contaminated clothing. - Flush exposed area with large amounts of water. If skin is damaged, seek immediate medical attention. If skin is not damaged and symptoms persist, seek medical attention. Launder clothing before reuse. Ingestion Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. Inhalation If symptoms develop, immediately move individual away from exposure and into fresh air. Seek immediate medical attention; keep person warm and quiet.' If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen. Notes to physician Hazards: No information available. Treatment: No information available. 5. FIRE -FIGHTING MEASURES Suitable extinguishing media Water spray Hazardous combustion products May form:, sulfur dioxide Page 3 / 8 • C SAFETY DATA SHEET DREWTM 6134 DECHLORINATING AGENT 51057 Page: 4 Revision Date: 01/24/2008 Print Date: 6/11 /2008 MSDS Number: R0290797 Version: 1.2 Precautions for tire -fighting No special fire hazards are known to be associated with this product.Wear full firefighting turn -out gear (full Bunker gear), and respiratory protection (SCBA). Use water spray to cool fire exposed containers and structures until fire is out if it can be done with minimal risk. Avoid spreading burning liquid with water used for cooling purposes. 6. ACCIDENTAL RELEASE MEASURES Personal precautions No data Environmental precautions No data Methods for cleaning up Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source, dike area of spill to prevent spreading, pump liquid to salvage tank. Remaining liquid may be taken up on sand, clay, earth, floor absorbent, or other absorbent material and shoveled into containers. Absorb liquid on vermiculite, floor absorbent or other absorbent material. 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Storage No data $. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines SODIUM HYDROGEN SULFITE 7631-90-5 ACGIH time weighted average 5 mg/m3 NIOSH Recommended exposure limit 5 mg/m3 Page 4 / 8 11 ASHLANI. SAFETY DATA SHEET DREWTM 6134 DECHLORINATING AGENT 51057 (REQ: General advice Page: 5 Revision Date: 01/24/2008 Print Date: 6/ 11 /2008 MSDS Number: R0290797 Version: 1.2 These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities. Exposure controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below TLV(s). Eye protection Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Consult your safety representative. Skin and body protection Wear resistant gloves (consult your safety equipment supplier). To prevent repeated or prolonged skin contact, wear impervious clothing and boots. Respiratory protection If workplace exposure limit(s) of product or any component is exceeded (see exposure guidelines), a NIOSH-approved air supplied respirator is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH respirators (negative pressure type) under specified conditions (see your industrial hygienist). Engineering or administrative controls should be implemented to reduce exposure. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state Form Colour Odour Boiling pointlboilingrange Melting point/range PH Flash point Evaporation rate Page 5/8 liquid No data light yellow sulphurous 216.00 OF / 216 OF@ 760.00 mmHg 26 °F / -3 °C 4.5 No data < 1 (N-Butyl Acetate) ASHLANa SAFETY DATA SHEET DREWTM 6134 DECHLORINATING AGENT 51057 Explosion limits Vapour pressure Vapour density Density Solubility Partition coefficient: n- octanol/water Autoignition temperature 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid Avoid contact with: Page: 6 . Revision Date: 01/24/2008 Print Date: 6/11/2008 MSDS Number: R0290797 Version: 1.2 No data 14.00 mmHg @ 77.00 °F / 25.00 °C 0.6 (A1R=1) 1.34 g/cm3 @ 68.00 °F 120.00 °C 11.23 lb/gal @ 68.00 °F 120.00 °C completely soluble in water No data No data Incompatible products Avoid contact with:, strong acids, strong oxidizing agents Hazardous decomposition products May form:, sulfur dioxide Hazardous reactions Product will not undergo hazardous polymerization. Thermal decomposition No data It. TOXICOLOGICAL INFORMATION Acute oral toxicity SODIUM HYDROGEN SULFITE INORGANIC SALT SODIUM SULFITE Page 6 / 8 LD 50 Rat: 2,000 mg/kg LD 50 Mouse: 5,989 mgtkg LD 50 Mouse: 820 mgtkg • ASHLAN13. SAFETY DATA SHEET DREW'rm 6134 DECHLORINATING AGENT 51057 Acute inhalation toxicity Acute dermal toxicity 12. ECOLOGICAL INFORMATION Aquatic toxicity Acute and Prolonged Toxicity to Fish No data Acute Toxicity to Aquatic Invertebrates No data Environmental fate and pathways No data 13. DISPOSAL CONSIDERATIONS Page; 7 Revision Date: 01 /24/2008 Print Date: 6/11/2008 MSDS Number: R0290797 Version: 1.2 Waste disposal methods Dispose of in accordance with all applicable local, state and federal regulations. For assistance with your waste management needs - including disposal, recycling and waste stream reduction, contact Ashland Distribution's Environmental Services Group at 800-637-7922. 14. TRANSPORT INFORMATION IMDG: UN2693, BISULPHITES, AQUEOUS SOLUTION, N,O.S. (SODIUM HYDROGEN SULFITE, ) 8, III IATA_P: UN2693, Bisulphites, aqueous solution, n.o.s. (SODIUM HYDROGEN SULFITE, 8,111 IATA_C: UN2693, Bisulphites, aqueous solution, n.o.s. (SODIUM HYDROGEN SULFITE, 8,111 CFR ROAD: Page 718 SHLAND. SAFETY DATA SHEET DREWTm 6134 DECHLORINATING AGENT 51057 Page: 8 Revision Date: 01 /24/2008 Print Date: 6/11/2008 MSDS Number: R0290797 Version: 1.2 UN2693, Bisulfites, aqueous solutions, n.o.s. (SODIUM HYDROGEN SULFITE, ) 8,111 CFR_RAIL: UN2693, Bisulfites, aqueous solutions, n.o.s. (SODIUM HYDROGEN SULFITE, } 8,111 CFR iNWTR: UN2693, Bisulfites, aqueous solutions, n.o.s. (SODIUM HYDROGEN SULFITE, } 8,111 Dangerous goods descriptions (if indicated above) may not reflect package size, quantity, end -use or region -specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. 15. REGULATORY INFORMATION California Prop. 65 This product does not contain any chemicals known to State of California to cause cancer, birth, or any other reproductive defects.' SARA Hazard Classification Acute Health Hazard SARA 313 Component(s) Health Flammability Reactivity Other HMIS 2* 0 0 NFPA 2 0 0 16.OTHER INFORMATION The information accumulated herein is believed to be accurate but is -not warranted to be whether originating with the company or not. Recipients are'advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1- 800-325-3751). Page 8 / 8 • 00 BIOCIDE/CHEMICAL TREATMENT WORKSHEET-FORM 16 lowin calculations are to be performed on any biocidai products, ultimately discharged to the surface waters of The fol � North Carolina. This worksheet must be completed separately for each blocidal product in use. This worksheet is to e retumed with all appropriate data entered into the designated areas with calculations performed as indicated. Facility Name # NPDES # NC Outfall County 7Q10 D• S- (cfs) Receiving Stream (All above information supplied by the Division of Water Quality) What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water body? A.D.D. = V. 2XV (in M.G.D.) Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered above. IWC = (A•D.D.) X 100 _ (M 10)(0.646) + (A. D. D) O'Oa v X 100 W (n.iA(0.646) + (ooj,){ This value (IWC) represents the waste concentration to the receiving stream during low flow conditions. What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I? ,�IPewBIe0 AJ D�tJ-. L . Plee�ase list the activeingredientsand percent composition: w.POMI/N2.� al0l dam! _ - �� % Rio What feed or dosage rate (D.R.) is used in this application? The units must be converted to maximum grams of whole product used in a 24hr period. D.R.= J-6*7 grams124hr period Please note, fluid ounces (a volume) must be converted to grams (a mass). The formula for this conversion is: Grams of product = fluid oz. of product X 1 gal. water X 8.34 lbs. X specific gravity of product X 45359g. 128 fl. oz. 1 gal. water 1 lb. 0 w "' �� •� Facility Name: NPDES #: NC c e-coal Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge point. On an attached sheet please provide justification for this estimate (system volume, average cycles per blowdown,, holding lagoon size, etc.) Volume- O AS —million gallons What is the pH of the handling system prior to biocide addition? If unknown, enter NIA. 9.0 What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.=O) and proceed to asterisk. The degradation must be stated at pH level within 112 pH standard unit within handling system. Enter the half life (Half Life is the time required for the initial product to degrade to half of its original concentration). Please provide copies of the sources of this data. H.L. _ 0, O'Ya Days The decay rate is equal to H1L X 0.69 = A0 =Decay Rate (D.K.) Calculate degradation factor (D.F.). This.is the first order loss coefficient. d • Oa.Y • D.F. = A.D.D. + (D.K.) _ + ( ) _ 17. (Volume) Calculate Steady State Discharge Concentration: , Dischg Conc. =-(D.R.) - 7 ) _ [�. 3V mgll (D.F.)(Volume)(3785) - (11.y )(v,a.%r)(3785) Calculate concentration of biocide instream during low flow conditions. (Receiving Stream Concentration) (Dischq. Conc.) x (IWC%) _ �_35f) x (_14_1) 0.07 mgll 100 - 100 Receiving Stream Concentration III. Calculate regulated limitation. List all LC50 and EC50 data available for the whole product according to the following columns. (Note that units should be in mg/l). Please provide copies of the sources of this data. Organism ^ Test Duration LC501EC50 (moll) Q/uP2)1/ fv..fis4 96 3, l� ##;0 j All D. W. Q. Form 101 (612000) 2 i 00 •� i Facility Name:_ _aZ2w _ NPDES * NC rr� Choose the lowest LC501EC50 listed above: Enter the LC501EC50: _ 3. If the half life (H.L.) is less than 4 days, perform the following calculation. Regulated Limitation = 0.05 x LC50 = ev' /? mgll If the half life (H.L.) is greater than or equal to 4 days or unknown, perform the following calculation. Regulated Limitation = 0.01 x LC50 = mgll Choose the appropriate regulated limitation from the calculations immediately above and place in this blank: eq. mg/liter From Part II enter the receiving stream concentration: 0. Q 71' mg/liter IV. Analysis. If the receiving stream concentration is greater than the calculated regulated limitation, then this biocide is unacceptable for use, Person in Responsible Charge Date Person Completing This Worksheet (If different from above) w- s �O 5' Name (Print) TSignature Date Please submit to: Division of Water Quality Aquatic Toxicology Unit 1621 Mail Service Center Raleigh, NC 27699-1621 Attn: Todd Christenson D. W. Q. Form 101 (612000) 3 Ashland DREWBROM•ONE L MATERIAL SAFETY DATA SHEET Page 001 Date Prepared: 07/10/03 MSDS NO: 306.0371031-004.003 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Material Identity Product Name: DREWBROM ONE L General or Generic ID: MICROBIOCIDE Company Emergency Telephone Number: Ashland 1-800-ASHLAND' (1-800-274-5263) Ashland Distribution Co. & 24 hours everyday Ashland Specialty Chemical Co. P. 0. Box 2219 Regulatory Information Number: Columbus, OH 43216 1-800-325-3751 614-790-3333 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient(s) CAS Number % (by weight) ---------------------------------------------------------------------- BROMINE CHLORIDE 11.0 SODIUM HYDROXIDE 1310-73-2 10.0 3. HAZARDS IDENTIFICATION Potential Health Effects Eye Skin Can cause permanent eye injury. Symptoms include stinging, tearing, redness, and swelling of eyes. Can injure the cornea and cause blindness. Can cause permanent skin damage. Symptoms may include redness, burning, and swelling of skin, burns, and other skin damage. The feeling of irritation or pain may not occur until several hours after the exposure. Additional symptoms of skin contact may include: hair loss, Passage of this material into the body through the skin is possible, and,skin contact may be harmful. Swallowing Swallowing this material may be harmful or fatal. Symptoms may include severe stomach and intestinal irritation (nausea, vomiting, diarrhea), abdominal pain, and vomiting of blood. Swallowing this material may cause burns and destroy tissue in the mouth, throat, and digestive tract. Low blood pressure and shock may occur as a result of severe tissue injury. Inhalation Breathing this material may be harmful or fatal. Symptoms may include severe irritation and burns to the nose, throat, and respiratory tract. Symptoms usually occur at air concentrations higher than the recommended exposure limits (See Section 8). Symptoms of Exposure Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: irritation (nose, throat, airways), cough, difficult breathing, lung edema (fluid buildup in the lung tissue), lung .damage, damage to the mouth, throat, and/or airways, shock. Target Organ Effects No data Developmental Information Based on the available information, risk to the fetus from maternal exposure to this material cannot be assessed. c Cancer information There is no information available. The chance of this material causing cancer is unknown. This material is not listed as a carcinogen by the International Agency for Research on Cancer, the National Toxicology Program, or the Occupational Safety and Health .Administration. Other Health Effects No data Primary Route(s) of Entry Inhalation, Skin absorption, Skin contact, Eye contact, Ingestion'. 4. FIRST AID MEASURES Eyes Skin If material gets into the eyes, immediately flush eyes gently with water for at least 15 minutes while holding eyelids apart. If symptoms develop as a result of vapor exposure, immediately move individual away from exposure and into fresh air before flushing as recommended above. Seek immediate medical attention. Do not remove the victim from water access for transport to a medical facility unless instructed to do so by qualified medical personnel. If possible, continue flushing the eye gently with water while transporting the victim. Immediately flush skin with water for at least 15 minutes while removing contaminated clothing and shoes. Seek immediate medical attention. Wash clothing before reuse and discard contaminated shoes. Swallowing Seek immediate medical attention. Do not induce vomiting. Vomiting will cause further damage to the mouth and throat. If individual is conscious and alert, immediately rinse mouth with water and give milk or water to drink. If possible, do not leave individual unattended. Inhalation If symptoms develop, immediately move individual away from exposure and into fresh air. Seek immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen. Note to Physicians Probable mucosal damage may contraindicate the use of gastric lavage. Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material: respiratory tract, skin, lung (for example, asthma -like conditions). 5. FIRE FIGHTING MEASURES Flash Point Not applicable Explosive Limit• Not applicable Autoignition Temperature No data Hazardous Products of Combustion May form: bromine, chlorine compounds. Fire and Explosion Hazards No special fire hazards are known to be associated with this product. Extinguishing Media Use an extinguishing media appropriate for surrounding fire. Fire Fighting Instructions Wear a self-contained breathing apparatus with a full facepiece operated in the positive pressure demand mode with appropriate turn -out gear and chemical resistant personal protective equipment. Refer to the personal protective equipment section of this MSDS. NFPA Rating Health - 3, Flammability - 0, Reactivity - 0 G. ACCIDENTAL RELEASE MEASURES Small Spill Scoop or scrape up: Put in container for recovery or disposal. Comply with all applicable federal, state, and local regulations. Large Spill. Prevent run-off to sewers, streams or other bodies of water. If run-off occurs, notify proper authorities as required, that a spill has occurred. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source, dike area of spill to prevent spreading, pump liquid to salvage tank. Remaining liquid may be taken up on sand, clay, earth, floor absorbent, or other absorbent material and shoveled into containers. 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Emergency eyewash fountains and safety showers should be available in the immediate vicinity of potential exposure. Use good personal hygiene practices. wash hands before eating, drinking, smoking, or using toilet facilities. Promptly remove soiled clothing and wash before reuse. Shower after work using plenty of soap and water. Storage Product solutions are corrosive to many commonly used materials of construction such as steel, galvanized iron, aluminum, tin and zinc. These solutions can be stored and handled in baked phenolic -lined steel, polyethylene, stainless steel, or reinforced epoxy -plastic equipment. Keep product dry in tightly closed original container when not in use, Store in a cool, dry, well -ventilated area away from heat, open flames, organic chemicals and sunlight. Do not contaminate water, food, or feed by storage or disposal. Open dumping is prohibited. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection Chemical splash goggles and face shield (8" min.) in compliance with.OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. (Consult your industrial hygienist.) Skin Protection Wear resistant gloves such as: natural rubber, Wear chemical -resistant apron, or in emergency conditions, chemical -resistant clothing and boots. Respiratory Protections If workplace exposure limit(s) of product or any component is exceeded (see exposure guidelines), a NIOSH/MSHA approved air supplied respirator is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH/MSHA respirators (negative pressure type) under specified conditions (see your industrial hygienist). Engineering or administrative controls should be implemented to reduce exposure. Engineering Controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below TLV(s). Exposure Guidelines Component BROMINE CHLORIDE No exposure limits established SODIUM HYDROXIDE (1310-73-2) OSHA PEL 2.000 mg/m3 - TWA OSHA VPEL 2.000 mg/m3•- Ceiling ACGIH TLV 2.000 mg/m3 - Ceiling 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point (for product) 214.0 - 216.0 F (101.1 - 102.2 C) ® 760 mmHg Vapor Pressure (for product) 19.000 mmHg @ 77.00 F Specific Vapor Density No data Specific Gravity 1.320 - 1.370 Q 77.00 F Liquid Density 10.900 - 11.400 lbs/gal 0 77.00 F 1.320 - 1.370 kg/1 9 25.00 C Percent Volatiles No data Evaporation Rate No data Appearance CLEAR State LIQUID Physical Form 00 HOMOGENEOUS SOLUTION Color YELLOW TO ORANGE Odor MILD, SWEAT ODOR PH 12.4 - 13.7 Freezing Point 21.2 F (-6.0 C) Solubility in Water FREELY SOLUBLE IN WATER 10. STABILITY AND REACTIVITY Hazardous Polymerization Product will not undergo hazardous polymerization. Hazardous Decomposition May form: bromine, chlorine compounds. Chemical Stability Stable. Incompatibility Avoid contact with: acids, alcohols, aldehydes, aluminum, ammonia copper, iron, strong reducing agents. 11. TOXICOLOGICAL INFORMATION LD 50 and LC 50 Data Oral LD50 (rat): 2491 mg/kg Dermal LD50 (rat): >2000 mg/kg Inhalation LC50 (rat, 1 hour): >20.37 mg/1 12. ECOLOGICAL INFORMATION Ecotoxicological Information' 96 hour LC50 bluegill sunfish (static conditions): 3.8 mg/l 48 hour EC50 Daphnia magna (static conditions): 4.9 mg/l 96 hour IC50 green algae: 2.6 mg/l 13. DISPOSAL CONSIDERATION Waste Management Information Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency or the Hazardous Waste Representative at the nearest EPA Regional Office for guidance. Do not contaminate water, food, or feed, by storage or disposal or cleaning of equipment. Do not put product, spilled product, or filled or partially filled containers into the trash or waste compactor. Contact with incompatible materials could cause a reaction or fire. Do not reuse container. Rinse thoroughly before discarding in trash. Triple rinse (or equivalent) then offer drum for recycling or reconditioning, or puncture. Dispose of drum in a sanitary landfill, or by incineration, if allowed by state and local authorities.' If burned, stay out of smoke. For assistance with your waste management needs - including disposal, recycling and waste stream reduction, contact Ashland Distribution Company, IC&S Environmental Services Group at 800-637-7922. 14. TRANSPORT INFORMATION DOT Information - 49 CFR 172.101 DOT Description: CORROSIVE LIQUID, BASIC, INORGANIC, N.0.S.,8,UN3266,III Container/Mode: 55 GAL DRUM/TRUCK PACKAGE NOS Component: SODIUM HYDROXIDE HALOGENATED COMPLEX RQ (Reportable Quantity) - 49 CFR 172.101 Product•Quantity (lbs) Component ---------------------- ---------- ---------------------------------------- 10000 SODIUM HYDROXIDE Other Transportation Information The DOT Transport Information may vary with the container and mode of shipment. 15. REGULATORY INFORMATION US Federal Regulations TSCA (Toxic Substances Control Act) Status TSCA (UNITED STATES) The intentional ingredients of this product are listed. CERCLA RQ - 40 CFR 302.4(a) Component RQ (lbs) SODIUM HYDROXIDE 1000 CERCLA RQ - 40 CFR 302.4(b) 00 This material has a RQ of 100 lbs as a D002 Corrosive unlisted hazardous substance. SARA 302 Components - 40 CFR 355 Appendix A None Section 311/312 Hazard Class - 40 CFR 370.2 Immediate(X) Delayed( } Fire( ) Reactive( } Sudden Release of Pressure( ) SARA 313 Components - 40 CFR 372.65 None OSHA Process Safety Management 29 CFR 1910 None listed EPA Accidental Release Prevention 40 CFR 68 None listed International Regulations Inventory Status Not determined State and Local Regulations California Proposition 65 None New Jersey RTK Label Information SODIUM HYDROXIDE 1310-73-2 Pennsylvania RTK Label Information SODIUM HYDROXIDE (NA(OH)) 1310-73-2 16. OTHER INFORMATION It is a violation of federal law to use this product in a manner inconsistent with its labeling. The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Last page 400 BIOCIDE/CHEMICAL TREATMENT WQRKSHEET-FORM 101 The following calculations are to be performed on any blocidal products ultimately discharged to the surface waters of North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet is to be returned with all appropriate data entered into the designated areas with calculations performed as indicated. Facility Name NPDES # NC,r=,_n=T Outfall # r County Fra% Xci" rn Receiving Stream 33C'4e'4zSlr:j 7Q10 (cfs) (All above information supplied by the Division of Water Quality) What is the Average Daily Discharge (A.D.D.) volume of the, water handling systems to the receiving water body? A.D.D. _ �• �� (in M.G.D.) Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered above. (A.D.D.) X 100 IWC = (71Q10)(0.646) + (A.D.D) o. oaY X 100 (0./31(0.646) + (o.nTY This value (IWC) represents the waste concentration to the receiving stream during low flow conditions. What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I? ffio_ s'ew/s ire 1y 5� Please list the active ingredients and percent composition: ?2-��'�B,eo�ro -3egeA o r�yL 20 pro dRoxeO A l b�v.T�t'�G�" /. D % MGA-)O 949AOo -3— Ae % 2,r2-�,a�aH n �c ��� 440 What feed or dosage rate (D.R.) is used in this application? The units must be converted to maximum grams of whole product used in a 24hr period. D.R.= �23 S' _ grams/24hr period Please note, fluid ounces (a volume) must be converted to grams (a mass). The formula for this conversion is: Grams of product = fluid oz. of product X 1 gal. water X 8.34 lbs. X specific gravity of product X 45359g. 128 fl. oz. 1 gal. water 1 lb. Facility Name:-•r�•.z�4 ..�� �[.z — NPDES #: NC��6ra�6s Estimate totai volume of the water handling system between entry of biocidal product and NPDES discharge point. On an attached sheet please provide justification for this estimate (system volume, average cycles per blowdown, holding lagoon size, etc.) Volume= d r 2Y _ million gallons What is the pH of the handling system prior to biocide addition? If unknown, enter NIA. �- What is the decay rate (D.K.) of the product? if unknown, assume no decay (D.K.=O) and proceed to asterisk. The degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the half life (Half Life is the time required for the initial product to degrade to half of its original concentration). Please provide copies of the sources of this data. H. L. _ l Days The decay rate is equal to H1L X 0.69 = 419. 3 .=Decay Rate (D.K.) Calculate degradation factor (D.F.). This is the first order loss coefficient. O.O a-`f !L D.F. = (Volume) ' ( + (D.K.) = + ( (49..3 Calculate Steady State Discharge Concentration: A3s Disch Conc. = (D.R.) _ Q, dS,3 m /l g (D.F.)(Volume)(3785) - (�y,cj )(p..2y )(3785) = g Calculate concentration of biocide instream during low flow conditions. (Receiving Stream Concentration) Disch . Conc. x IWC% (aa5'3 x { 9• $) _ d , p t mg1l 100 y 100 Receiving Stream Concentration III. Calculate regulated limitation. List all LC50 and EC50 data available for the whole product according to the following columns. (Note that units should be in mg/1). Please provide copies of the sources of this data. Organism Test Duration LC501EC50 (mall) &,yoo w 7-e.,"7- q6 S'v A W. Q. Form 101 (612000) 2 W* Facility Name: Choose the lowest LC501EC50 listed above: Enter the LC50/EC50: So 10.0 NPDES #: NC is if the half life (H.L.) is less than 4 days, perform the following calculation. Regulated Limitation = 0.05 x LC50 = CO. as mg/l If the half life (H.L.) is greater than or equal to 4 days or unknown, perform the following calculation. Regulated Limitation = 0.01 x LC50 mg/I Choose the appropriate regulated limitation from the calculations immediately above and place in this blank: 0 -.2 S' mg/liter From Part II enter the receiving stream concentration: O. O / -mg/liter IV. Analysis. If the receiving stream concentration is greater than the calculated regulated limitation, then this biocide is unacceptable for use, Person in Responsible Charge am Prin ) Tature Date V Person Completing This Worksheet (If different from above) Name (Print) e�at"I I'I1,12av Signature Date Please submit to: Division of Water Quality Aquatic Toxicology Unit 1621 Mail Service Center Raleigh, NC 27699-1621 Attn: Todd Christenson D. W Q. Form 101 (612000) 3 00 Ashland BIOSPERSE 244 MATERIAL SAFETY DATA SHEET Page 001 Date Prepared: 08/18/04 MSDS No: 306,0176184-011.003 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Material Identity Product Name: BIOSPERSE 244 General or Generic ID: MICROBIOCIDE Company Emergency Telephone Number: Ashland 1-800-ASHLAND (1-800-274-5263) Ashland Distribution Co. & 24 hours everyday Ashland Specialty Chemical Co. P. 0. Box 2219 Regulatory Information Number: Columbus, OH 43216 1-800-325-3751 614-790-3333 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient(s) CAS Number % (by weight) POLYETHYLENE GLYCOL 25322-68-3 TETRAETHYLENE GLYCOL 112-60-7 2,2-DIBROMO-3-NITRILOPROPIONAMIDE 10222-01-2 20.0 SO I BROMIDE 7647-15-6 DIBROMOACETONITRILE 3252-43-5 1.0 MONOBROMO-3-NITRILOPROPIONAMIDE 1113-55-9 1.0 2,2-DIBROMOMALONAMIDE 73003-80-2 1.0 3. HAZARDS IDENTIFICATION Potential Health Effects Eye Skin Can cause permanent eye injury. Symptoms include stinging, tearing, redness, and swelling of eyes. Can injure the cornea and cause blindness. Can cause skin irritation. Symptoms may include redness and burning of'skin, and other skin damage. Additional symptoms of skin contact may include: allergic skin reaction (delayed skin rash which may be followed by blistering, scaling and other skin effects), Passage of this material into the body through the skin is possible, but it is unlikely that this would result in harmful effects during safe handling and use. . Swallowing Swallowing this material may be harmful or fatal. Symptoms may include severe stomach and intestinal irritation (nausea, vomiting, diarrhea), abdominal pain, and vomiting of blood. Swallowing this material may cause burns and destroy tissue in the mouth, throat, and digestive tract. Low blood pressure and shock may occur as a result of severe tissue in}ury. Inhalation Breathing of vapor or mist is possible. Breathing this material may be harmful. Symptoms of Exposure Signs and symptoms'of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: irritation (nose, throat, airways). Target Organ Effects overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals: mild, reversible kidney effects. Developmental. Information Based on the available information, risk to the fetus from maternal exposure to this material cannot be assessed. cancer Information This material is not listed as a carcinogen by the International' Agency for Research on Cancer, the National Toxicology Program, or the Occupational Safety and Health Administration. Other Health Effects No data Primary Route(s) of Entry Inhalation, Skin contact, Eye contact, Ingestion -'Industrial products are not meant to be swallowed. 4. FIRST AID MEASURES Eyes Skin If material gets into the eyes, immediately flush eyes gently with water for at least 15 minutes while holding eyelids apart. If symptoms develop as'a result of vapor exposure, immediately move individual away from exposure and into fresh air before flushing as recommended above. Seek immediate medical attention. Remove contaminated clothing. Flush exposed area with large amounts of water. If skin is damaged, seek immediate medical attention. If skin is not damaged and symptoms persist, seek medical attention. Launder clothing before reuse. Swallowing Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. Inhalation If symptoms develop, immediately move•individual away from exposure and into fresh air. Seek immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen. Note to Physicians Probable mucosal damage may contraindicate the use of gastric lavage. Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material: skin, lung (for example, asthma -like conditions), eye. 5. FIRE FIGHTING MEASURES Flash Point > 175.0 F (79.4 C) COC Explosive Limit (for component) Lower .9 Autoignition Temperature No data Hazardous Products of Combustion May form: bromine, carbon oxides, nitrogen oxides, toxic fumes. Fire and Explosion Hazards No special fire hazards are known to be associated with this product. During a fire, irritating or toxic decomposition products may be generated. Extinguishing Media alcohol foam, water fog, dry chemical. Fire Fighting Instructions wear a self-contained breathing apparatus with a full facepiece operated in the positive pressure demand mode with appropriate turn -out gear and chemical resistant personal protective equipment. Refer to the personal protective equipment section of this MSDS. NFPA Rating Health - 3, Flammability - 1, Reactivity - 1 6. ACCIDENTAL RELEASE MEASURES 040 Small Spill Absorb liquid on vermiculite, material. Scoop or scrape up disposal. floor absorbent or other absorbent Put in container for recovery or Large Spill Persons not wearing protective equipment should be excluded from area.of spill until clean-up has been completed. Stop spill at source, dike area of spill to prevent spreading, pump liquid to salvage tank, Remaining liquid may be taken up on sand, clay, earth, floor absorbent, or other absorbent material and shoveled into containers. 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or ,solid), all hazard precautions given in the data sheet must be observed. For optimum product quality, avoid dilution'with water. Storage Keep product dry in tightly closed original container when not in use. Store in a cool, dry, well -ventilated area away from heat, open flames, organic chemicals and sunlight. Do not contaminate water, food, or feed by storage or disposal. Open dumping is prohibited. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection Chemical splash goggles and face shield (8" min.) in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. (Consult your industrial hygienist.) Skin Protection Wear resistant gloves such as: neoprene, To prevent skin contact, wear impervious clothing and boots. Other protective equipment: eyewash station, emergency shower. Respiratory Protections Exposures in the workplace should be monitored to determine if worker exposure to vapor or mist air concentrations exceeds the facility specified exposure "action level" or the use of the product produces adverse health effects or symptoms of exposure. Only a NIOSH/MSHA approved respirator and cartridge (TC-23C) is to be used. Monitoring results must be used to assess the proper level of respiratory protection necessary (such as: full face piece respirator with chemical cartridges or self-contained breathing apparatus {scuba}, etc.). Proper engineering and/or administrative controls should be used to reduce worker exposure. The facility's respiratory protection program must meet the 0 .requirements established in 29 CPR 1910.134, which includes a program for medical evaluation. Engineering Controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below level of overexposure (from known, suspected or apparent adverse effects). Exposure Guidelines Component POLYETHYLENE GLYCOL (25322-68-3). No exposure limits established TETRAETHYLENE GLYCOL (112-60-7) No exposure limits established 2,2-DIBROMO-3-NITRILOPROPIONAMIDE (10222-01-2) OTHER LIMIT 2.000 mg/m3 - Ceiling (Recommended) SODIUM BROMIDE (7647-15-6) OTHER LIMIT 10.000 mg/m3 - TWA (Recommended) DIBROMOACETONITRILE (3252-43-5) OTHER LIMIT 0.100 mg/m3 - Ceiling (Recommended) MONOBROMO-3-NITRILOPROPIONAMIDE (1113-55-9) No exposure limits established 2,2-DIBROMOMALONAMIDE (73003-80-2) No exposure limits established 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point (for product) a 158.0 P (70.0 C) @ 760 mmHg Vapor Pressure (for product) < 10.000 mmHg @ 77.00 F Specific Vapor bensity < 1.000 ® AIR=1 Specific Gravity 1.200 - 1.300 @ 73.40 F Liquid Density 10.400 lbs/gal ® 73.40 F 1.200 - 1.300 kg/1 (P 23.00 C Percent Volatiles 20.0 - 25.0 % Volatile Organic Compounds (VOC) .000 % Evaporation Rate SLOWER THAN ETHYL ETHER Appearance CLEAR, LIGHT YELLOW TO AMBER LIQD. State LIQUID Physical Form HOMOGENEOUS SOLUTION Color LIGHT YELLOW TO AMBER Odor LIGHT, DISINFECTANT pH 3.4 Freezing Point -58.0 F (-50.0 C) Solubility in Water APPRECIABLE 10. STABILITY AND REACTIVITY Hazardous Polymerization Product will not undergo hazardous polymerization. Hazardous Decomposition May form: bromine, carbon oxides, cyanogen bromide, dibromoacetonitrile, nitrogen oxides, toxic fumes. Chemical Stability Stable. Incompatibility Avoid contact with: strong bases, strong oxidizing agents, temperatures above 140 degrees F (60 C degrees). 11. TOXICOLOGICAL INFORMATION LD 50 and LC 50 Data Oral LD50 (rat): 510 mg/kg Dermal LD50 (rabbit): >2000 mg/kg Inhalation LC50 (male rat, 4 hour): 1.4 mg/1 Inhalation LC50 (female rat, 4 hour): 1.25 mg/1 12. ECOLOGICAL INFORMATION Ecotoxicological Information This material (or a component) is toxic to fish and aquatic organisms. 13. DISPOSAL CONSIDERATION Waste Management Information Dispose of in accordance with all applicable local, state and federal regulations. For assistance with your waste management needs - including disposal, recycling and waste stream reduction, contact Ashland Distribution Company, IC&S Environmental Services Group at 800-637-7922. 14. TRANSPORT INFORMATION DOT Information - 49 CFR 172,101 DOT Description: NON -REGULATED BY D.O.T. Container/Mode: 55 GAL DRUM/TRUCK PACKAGE NOS Component: Not applicable RQ (Reportable Quantity) - 49 CFR 172.101 Not applicable Other Transportation Information The Transport Information may vary with the container and mode of shipment. 15. REGULATORY INFORMATION US Federal Regulations CERCLA RQ•- 40 CFR 302.4(a) None SARA 302 Components - 40 CFR 355 Appendix A None Section 311/312 Hazard Class - 40 CFR 370.2 Immediate(X) Delayed( } Fire( ) Reactive( } Sudden Release of Pressure( ) SARA 313 Components - 40 CFR 372.65 Section 313 Component(s) CAS Number - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 2,2-DIBROMO-3-NITRILOPROPIONAMIDE 10222-01-2 20.00 OSHA Process Safety Management 29 CFR 1910 None listed EPA Accidental Release Prevention 40 CFR 68 None listed International Regulations Inventory Status Not determined State and Local Regulations California Proposition 65 None 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is not warranted'to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Last page BIOCIDE/CHEMICAL TREATMENT WOF*SHEET-FORM 101 The following calculations are to be performed on any biocidali products ultimately discharged to the surface waters of North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet is to be returned with all appropriate data entered into the designated areas with calculations performed as indicated. Facility Name NPDES # NC Outfall # I County Receiving Stream _—I LS AR�I ft 7Q10 (cfs) (All above information supplied by the Division of Water Quality) What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water body? A.D.D. = CJ• Oay (in M.G.D.) Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered above. IWC = (A.D.D.) X 100 (7Q10)(0.646) + (A.D.D) m•oaay ( ) X 1.00 �9.8 (a/5g0.646) + ( ) a•v�y This value (IWC) represents the waste concentration to the receiving stream during low flow conditions. 11. What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I? Please list the active ingredients and percent composition: % �GPy l�2la y �►Q,- 2. z - r z Rio S&ifvA' , fv/7 AZak What feed or dosage rate (D.R.) is used in this application? The units must be converted to maximum grams of whole product used in a 24hr period. D.R.= ��� grams124hr period Please note, fluid ounces (a volume) must be converted to grams (a mass). The formula for this conversion is: Grams of product = fluid oz. of product X 1 gal. water X 8.34 lbs. X specific gravity of product X 453.59g. 128 fl. oz. 1 gal. water 1 lb. � V „ -�5 .�.Y 6 k: i• y ,:. ,Y� s dAIY i NPDES #: f Facility Name.Ege point. Estimate total volume of the water handling system be entry of biocidal produavera a cycles pd NPDES er b ovvd@W, E stem volume, 9 On an attached sheet please provide justification for this estimate (system holding lagoon size, etc.) Volume= g Z million gallons handling system prior to biocide addition? If unknown, enter NIA. r What is the pH of the 9 Y What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.=0) and proceed to asterisk. The degradation must be stated at pH level within 112 pH standard unit within handling system. Enter the half life (Half Life is the time required for the initial product to degrade to half of its original concentration). Please provide copies of the sources of this data. H.L. = 4, Days The decay rate is equal to H1L X 0.69 = -Decay Rate (D.K.) Calculate degradation factor (D.F.). This is the first order loss coefficient. CO. bob- y • D.F. _ (VoD D. ). + (D.K.) _ (L— + ( O } = O • / Calculate Steady State Discharge Concentration: x� Dischg Conc. = D.R. - {�� _) - 3 O mgll (D.F.)(Volume)(3785) O..tY }(3785) - Calculate concentration of biocide instream during low flow conditions. (Receiving Stream Concentration) Disch . Conc. x IWC% ( 3 0 ) x ( 19 9) _ S. 9�1{ mg/I 100 - 100 - Receiving Stream Concentration III. Calculate regulated limitation. List all LC50 and EC50 data available for the whole product according to the following columns. (Note that units should be in mgll). Please provide copies of the sources of this data. Organism 1P*.A.'.&g„e AlOW - Test Duration 96 9G v$ LC50/EC50 (mglll aV 3s Va D.W.Q.. Form 101 (612000) 2 f 0• so Facility Name: NPDES #: Choose the lowest LC501EC50 listed above: Enter the LC501EC50: _ 689 If the half life (H.L.) is less than 4 days, perform the following calculation. Regulated Limitation = 0.05 x LC50 = mg/i If the half life (H.L.) is greater than or equal to 4 days or unknown, perform the following calculation. Regulated Limitation = 0.01 x LC50 Choose the appropriate regulated limitation from the calculations immediately above and place in this blank: �- SO? _ _ mg/liter From Part II enter the receiving stream concentration: S- 95( _mglliter IV. Analysis. If the receiving stream concentration is greater than the calculated regulated limitation, then this biocide is unacceptable for use, Person in Responsible Charge Na rint) ' S' a ure Date Person Completing 15is Worksheet (if different from above) 24-wel et/ 5 C%S Name (Print) G✓ / y .20d Signature Date Please submit to: Division of Water Quality Aquatic Toxicology Unit 1621 Mail Service Center Raleigh, NC 27699-1621 Attn: Todd Christenson D. W Q. Form 101 (612000) 3 ASHLAND SPECIALTY CHEMICAL DREW BUSINESS GROUPS PRODUCT NAME: DIOLTECHO 424 A COOLING WATER TREATMENT Aquatic Toxicity (Static Acute Tests) 96 Hour LC50 Rainbow Trout: 689 mg/L (Confidence Limits 95%: 564-843 mg/L Test date 1/07/97) 96 Hour LC50 Fathead Minnow: 804 mg/L (Confidence Limits 95%: 648-996 mg/L Test date 1/27/97) 96 Hour EC50 Fathead Minnow: 700 mg/L (Confidence Limits 95%: 565-867 mg/L Test date 1/27/97) 48 Hour LC50 Daphnia Magna: 3540 mg/L (Confidence Limits 95%: 2500-5000 mg/L Test date 1/13/97) SOD5: 290,000 mg/L Test date 12/18/96 COD: 313,000 mg/L Test date 12/18/96 aR gwcred trademark of Ashland lac pdF 5 ltech424p Dcc6 Dcc FS37 page l of 1 Environmental, Health A Safety Department Product & Regulmory Information. Dram- Team - All statements, information and data presetted herein are believed to be accurate and reliable but are not to be taken as a guarantee. express warranty or implied warranty of merrhamability or fitness for a p iculm purpose, or representation, express or implied, far which seller assumes legal responsibility, and they are offered solely for your consideration, inv�yligadan and verification. This information is believed no be accurate and reliable as of dam shove. It is recommended you make your own determination on the suitability of ihis product fory+our particular application. BIOCIDEICHEMICAL TREATMENT WORKSHEET-FORM 101 The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet is to be returned with all appropriate data entered into the designated areas with calculations performed as indicated. Facility Name NPDES # NC If 4r Outfall #_ t County rar-k=:.�_ Receiving Stream Z j:' ' 1 n ir-'= EC - __ 7Q10 m' (cfs) (All above information supplied by the Division of Water Quality) What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water body? A.D.D. _ d7. O (in M.G.D.) Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using.the data entered above. A.D.D. X 100 IWC = (7Q10)(0.646) + (A.D.D) _ ( ) X 100 _ (0./,f O.646) + (�• ct�.y /9 % This value (IWC) represents the waste concentration to the receiving stream during low flow conditions. What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I? 4940w C/i /yr Please list the active ingredients and percent composition: �� vim GILLLD/iT�rr �`" YO % What feed or dosage rate (D.R.) is used in this application? The units must be converted to maximum grams of whole product used in a 24hr period. D.R.= -may- J/ grams/24hr period Please note, fluid ounces (a volume) must be converted to grams (a mass). The formula for this conversion is: Grams of product = fluid oz. of product X 1 Qal. water X 8.34 lbs. X specific gravity of product X 453.594. 128 fl. oz. 1 gal. water 1 lb. Facility Name: NPDES #: Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge point. On an attached sheet please provide justification for this estimate (system volume, average cycles per blowdown, holding lagoon size, etc.) Volume= d• / :�L million gallons What is the pH of the handling system prior to biocide addition? If unknown, enter NIA. /, o What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.=O) and proceed to asterisk. The degradation must be stated at pH level within 112 pH standard unit within handling system. Enter the half life (Half Life is the time required for the initial product to degrade to half of its original concentration). Please provide copies of the sources of this data. H.L. = m- lira: Days The decay rate is equal to H1L X 0.69 'fr" =Decay Rate (D.K.) Calculate degradation factor (D.F.). This is the first order loss coefficient. D.F. = A.D.D. + (D.K.) _ �--� + (Volume) Calculate Steady State Discharge Concentration: (D.R. )D+ 00-5-m Il Dischg Conc. _ (D.F.)(Volume)(3785) _ Ao, )( 0, �)(3785) = g Calculate concentration of biocide instream during low flow conditions. (Receiving Stream Concentration) (Dischg. Conc.) x(IWC%) _ �_ ?_X (19 00099 mg/I 100 - 100 Receiving Stream Concentration III. Calculate regulated limitation. List all LC50 and EC50 data available for the whole product according to the following columns. (Note that units should be in mgll). Please provide copies of the sources of this data. Organism Test Duration LC501EC50 lmq/0 D ,o�G,�•,� 9.(0 0,29 SAM 9!;// 96 Z IL?A.Oyho . -//ya r _ 9G z9d D. W.Q. Form 101 (612000) 2 P 3 ,. - ".Y _ `S r . • Facility Name: NPDES #: NC pry Choose the lowest LC501EC50 listed above: Enter the LC501EC50: _ 6V ,.29— If the half life' (H.L.) is less than 4 days, perform the following calculation. Regulated Limitation = 0.05 x LC50 = V. 0!,< mgll If the half life (H.L.) is greater than or equal to 4 days or unknown, perform the following calculation. Regulated Limitation = 0.01 x LC50 = mg/l Choose the appropriate regulated limitation from the calculations immediately above and place in this blank: (V- 4 !� mg/liter From Part II enter the receiving stream concentration: Q. 0 00 ?9-mg/liter IV. Analysis. If the receiving stream concentration is greater than the calculated regulated limitation, then this biocide is unacceptable for use. Person in Responsible Charge n ..emu I pP l /�— Nfame - Sign re Date Person Completing This Worksheet (If different from above) All s-alos Name (Print) !Ls aea � Signature Date Please submit to: Division of Water Quality Aquatic 'Toxicology Unit 1621 Mail Service Center Raleigh, NC 27699-1621 Atfn: Todd Christenson D. W. Q. Form 101 (612000) 3 . . \ . j • \ � . y \ � � v. � ^ ,.—,b&:.SWA�.�.2> * 0 is * DREW INDUSTRIAL DIVISION OXIDATIVE CHEMICALS DREWCHLORe 4107 Chlorine Dioxide Precursor Environmental Profile General DREWCHLOR 4107 precursor Is a stabilized, non-volatile, chlorite formulation specifically designed for use with the patented CENEROXr"' unit for on -site generation of chlorine dioxide. Chlorine dioxide has numerous industrial and municipal applications as a disinfectant and as a chemical oxidant. Chlorine dioxide is stable and highly active over a wide pH range, will not react. with ammonia nitrogen compounds, eliminates taste and odor -causing by-product's such as chlorophenols and will cause a minimum of corrosion of system metals at use dosages. This Environmental Profile is designed to address common. questions about the impact of DREWCHLOR 4107 chlorine dioxide precursor on the environment. Active Ingredients Sodium Chlorite 25-40% CAS #7758-19-2 Sodium Chloride 1-10% CAS #7647-14-5 EPA Registration Number 1757-96. Toxicity Studies Animal Toxicology Inhalation LCSo: No available data Dermal LD58: >2g/kg (rabbit)' Oral LD59: Approximately 350 mg/kg (rat) Irritation Severe irritant with corrosive action to skin (of rabbit) Severe irritant to eyes (of rabbit) Aquatic Toxicity Sluegill LC50: 265-31 mg/i Rainbow trout LC56: 290 mg/1 Daphnia LC50: 0.29 mg/l Disassociation/Degradation Data Sodium chlorite is utilized to produce chlorine dioxide. The disassociation scheme for chlorine dioxide is chlorite and chlorate ions. Ultimately, the chlorite and chlorate ion will degrade to chloride and oxygen. Spill Procedure In case of small spills, absorb liquid on vermiculite, floor absorbent or other absorbent material. Flush area with water when absorbent material is cleaned up. In the event of large spills, all persons not wearing protective equipment should be excluded from the area of the spill. Stop the spill at its source and dike to prevent spreading, Pump liquid to a salvage tank and take up remaining liquid on sand, clay, earth floor absorbent or other absorbent material. Shovel material into containers and Flush area with water. Do not use sawdust, cat litter (except clay) or other organic based absorbents. Dispose of all waste material as directed by local, state and federal regulations. Handling Precautions DREWCHLOR 4107 chlorine dioxide precursor is a severe eye and skin irritant. If DREWCHLOR 4107 precursor contacts the eyes or skin, the affected areas must be flushed with large amounts of water. See the MSDS for additional information. Important Information This Environmental Profile is designed to address common questions about the impact ofDREWCHLOR 4107precursor on the environment andisnot a substitutefar the product'sMaterial Safety Data Sheet Ashland maintains Material Safety Data Sheets on all of its products: Material Safety Data Sheets contain health and safety information for your development of appropriate product handling procedures to protect your employees and customers Our Material Safety Data Sheets should be read and understood by all ofyour supervisory personnel and employees before using Ashland products in your facilities OD Registered trademark and TM trademark ofAshlartd Inc. 'Registered service mark of the American Chemistry Council. 01994, 20DI Ashland Inc. All Rights Reserved. Created to U.S.A. • OX-EP-003 Rev. 2 All statements, information and data presented heroin are believed to be accurate and reliable but are not to be taken as a guarantee, express warrantyor wetrkwhot ial implied warranty of merchantability or fitness for a particular purpose, or representation, express or implied, for which seller assumes legal responsibility, and ppb� they are offered soiely for your consideration, inyselgatlon and verification. Statements or suggestions concerning possible use of this product are made without representaeon or warranty that any such use Is free of patent Infringement and are not recommendations to infringe on any patent �* A5M8Ade For more information on Ashland Specialty Chemical Company and its divisions, visit our Internet web site at ht1p:1 wmv.eshspec.com qqmmmw DREW INDUSTRIAL DIVISION • One Drew Plaza, Boonton, New Jersey 07005 • Tel: (973) 263.7600 • Fax: (973) 263.4463 Ashland 5paciatty chemical Company � ' ommon ofAstYard Inc ' .. I S } \ - a 32\ > :a� �\< . . %. . y>) Date: October 31, 2017 Novozymes, NA Inc. 77 Perry's Chapel Church Rd. Franklinton, N.C. 27525 NCDEQ Division Of Water Quality 1617 Mail Service Center Raleigh, N.C. 27699-1617 Attn: Division Of Water Quality Storm Water Sampling, NPDES Permit No. NCS000115 Dear Sir/Madam, novozymes• Rethink Tomorrow RECIV NOV CENTRAL FILES oWR SECTION During review of storm water sampling results, it was observed that there was an exceeded benchmark in Biological Oxygen Demand (BOD) from our Outfall 2 location. Upon immediate investigation, per Tier One requirements, it was discovered that although during sample event no signs of potential issues were present, the area approximately 20 yards from where samples are collected the combination of filtration systems not properly being maintained/serviced and the off-loading of raw materials are being considered direct causes of the recent exceeding of BOD. Plans are in place to have personnel in area begin with cleaning filtration systems and more caution taken place while material is being handled. Continued monitoring by Environmental Services Department will take place in order to prevent future exceeded benchmarks in Biological Oxygen Demand (BOD) from Outfall 2. Kind Regar , Joe Ladd Environmental Compliance Coordinator Environmental Services EFFLUENT NPDES PERMIT NO. NCS000115 DISCHARGE NO. 1 FACILITY NAME Novozymes, NA Inc. CLASS OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA CERTIFIED LABORATORIES (1) Enco (2) CHECK BOX IF ORC HAS CHANGED E:=Fl PERSON(S) COLLECTING SAMPLES Mail ORIGINAL and ONE COPY to: MONTH October YEAR 2017 COUNTY: Franklin PHONE _L919) 494-3001 Joe Ladd ATTN: CENTRAL FILES x NIA DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) 1617 MAIL SERVICE CENTER RALEIGH, NC 27699-1617 BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE. Lm����mm� . DWQ Form MR-1 (I 1/04) r Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) Compliant All monitoring data and sampling frequencies do NOT meet permit requirements Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.6 of the NPDES permit. "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Pennittee Address Certified Laboratory (2) Certified Laboratory (3) Certified Laboratory (4) Certified Laboratory (5) Randy Green Permittee (Please print or type) _ Signature inn' *** Date (Required unless kul5mitted electronically) Phone Number e-mail address Permit Expiration Date ADDITIONAL CERTIFIED LABORATORIES PARAMETER CODES Certification No. Certification No. Certification No. Certification No. Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.us/was and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. *'* Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 2B .0506(b)(2)(D). Page 2 EFFLUENT NPDES PERMIT NO. NCS000115 DISCHARGE NO. 2 FACILITY NAME NoVozymes, NA Inc. CLASS OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA CERTIFIED LABORATORIES (1) Enco (2) CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Mail ORIGINAL and ONE COPY to: MONTH October YEAR 2017 COUNTY: Franklin PHONE (919) 494-3001 Joe Ladd ATTN: CENTRAL FILES x NIA DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) 1617 MAIL SERVICE CENTER BY THIS SIGNATURE. I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY RALEIGH, NC 27699-1617 KNOWLEDGE. Lu _ � & O '. U 50050 00010 FLOW W � H LU S z �w 0 �' v ❑ mO ❑ U V HE� Z Z O Z W 2 � a a (m 3w0 o EvE ¢ 0:» zO w o�zO j� ~V c �f z� b FFX INF � �O HRS HRS Y1NI13 MGD 'C UNITS UGIL MG/L MGIL MGIL MGIL MG1L MGIL Inches MGIL LBS1MO LBSIYR min 11113111111 11111mom Cm Him h wz 2 I ?.: ?i 'Atftfp l w WsFt AW 9W 2 931 S < 3'w�«z; W `F PW!Fm 'I _Rum 4 1511 . F;'M' Jaewrlwl 4 K Mam 4 E 6 1230 6.9 49.00 96.0 25.0 2.0 0.81 0.4 0.50 8 191 10 12 14 1155? Ix. 16 11,74 k�M MW 11 �f SWO MERW tj�24 E 7 M' 18 619; WrIm mW14104W11 gum Ummw Mow :79* 20 F2dl �9® s�` .. �''� �� :�'"' • xt� �``- �r :amtF ; �, �: xu � � ^+a�-s e �. � '� ���rr �` �+.`f 22 F231 M '' 119 M.Off� F '04, i vW4 P F: ,^ �. :fir 24 F251® J �MWM0 AE s r:.j- ` e ':r. ':,� ^' r, r', k :i L ; 'r ', � .2 26 F27A ! ?' �F '' Fes• , L '41*Z.: rF, Ix < �? A r, x'n P. `. ,.2'' Q� 3t l28 f29; g.. ,. �RAp 1 .:.-u.v"? f� f yam, �iY'0.....N'�:1!'.?..�i :' , n�� FA.H'�$(�1 �ku. �:i Ji A. � 1"".,��"+:�Ps .: �@ L i7 yg lffw- % 30 AVERAGE MAXIMLMMNN RIMM 4W.c I 6 '� * te," �' r ',F ire MINIMUM Monthly Limit DWQ Form MR-1 (I 1/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) Compliant All monitoring data and sampling frequencies do NOT meet permit requirements Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.6 of the NPDES permit. "I certity, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Permittee Address Certified Laboratory (2) Randy Green Permittee (Please prko or -type) Signature of ermittee*** Date (Require nless submitted electronically) Phone Number a -mail address Permit Expiration Date ADDITIONAL CERTIFIED LABORATORIES Certification No. Certified Laboratory (3) Certification No. Certified Laboratory (4) Certification No. Certified Laboratory (5) Certification No. PARAMETER CODES Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.ennstate.nc.us/was and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. '* ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 80.0204, 'Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 2B .0506(b)(2)(D). Page 2 T COEN 0 L�bor��ories Accurate Trmely. Responsive. Innovative. 102-A woodwinds Industrial court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Thursday, October 26, 2017 Novozymes North America (NO008) Attn: Joe Ladd 77 Perry Chapel Church Road Franklinton, NC 27525 RE: Laboratory Results for Project Number: [none], Project Name/Desc: Stormwater Testing ENCO Workorder(s): CA01243 Dear Joe Ladd, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Tuesday, October 17, 2017. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Chuck Smith Project Manager Enclosure(s) FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in fill. Pape 1 of 10 www.encolobs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: OutfallI Lab ID: CA01243-01 Sampled: 10/16/17 13:00 Received: 10/17/17 08:05 PaElMgt EPA 351.2 Hold Date/TFmefsl 11/13/17 Prep Date/Tlmefsl 10/20/17' 14:35 Analvals 10/23/17 DatalTime/sl 09:23 EPA 353.2 10/18117 13:00 10/17/17 15:12 10/17/17 15:12 EPA 353.2 11/13117 10/17/17 13:32 10/17/17 1132 EPA 353.2 07/11120 10/18/17 11:02 10/18/17 14:59 EPA 365.4 11/13117 10/20/17 14:35 10/23/17 11:03 SM 254OD-1997 10/23117 10/23/17 18:35 10/23/17 18:35 SM 521OB-2001 10/18,117 13:00 10/17/17 17:13 10/17/17 17:13 SM 522OD-1997 11/13117 10/19/17 18:02 10/20/17 11:00 Client ID: Outfall2 Lab ID: CA01243-02 Sampled: 10/16/17 12:30 Received: 10/17/17 08:05 ate EPA 351.2 Hold oatelllmefsl 11/13117 Prep Date/Timefsl 10/20/27 14:35 Analysis 10/23/17 Date/Time(s) 09:28 EPA 353.2 10/18117 12:30 10/17/17 15:17 10/17/17 15:17 EPA 353.2 11/13117 10/17/17 13:37 10/17/17 13:37 EPA 353.2 07/11120 10/18/17 11:02 10/18/17 14:59 EPA 365.4 11/13117 10/20/17 14:35 10/23/17 11:08 SM 254OD-1997 10/23117 10/23/17 18:35 10/23/17 18:35 SM 521OB-2001 10/18117 12:30 10/17/17 17:13 10/17/17 17:13 SM 5220D-1997 11/13117 10/19/17 18:02 10/20/17 11:00 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 2 of 10 www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: Outfall 1 Lab ID: CA01243-01 Anal Results EU9 Hu Ea llnitg Method tYotes Biochemical Oxygen Demand 5.0 2.0 2,0 mg/L SM 521OD-2001 Chemical Oxygen Demand 27 10 10 mg/L SM 5220D-1997 Nitrate as N 0.088 1 0.025 0,10 mg/L EPA 353,2 NitrateAtrite as N 0.088 1 O.D41 0.10 mg/L EPA 353.2 Phosphorus 0.41 0.025 0.10 mg/L EPA 365.4 Total Kjeldahl Nitrogen 1.1 0.26 0.48 mg/L EPA 351.2 Total Suspended Solids 32 6.7 6.7 mg/L SM 254OD-1997 Client ID: Outfall 2 Lab ID: CA01243-02 Analyze Results flag MRL Ea Mau Method 1i4ku Biochemical Oxygen Demand 49 2.0 2.0 mg/L SM 521OB-2001 Chemical Oxygen Demand 96 10 10 mg/L SM 5220D-1997 Nitrate as N 0.78 0.025 0.10 mg/L EPA 353.2 Nitrate/Nitrite as N 0181 0,041 0.10 mg/L EPA 353.2 Nitrite as N 0.029 1 0.017 0.10 mg/L EPA 353.2 Phosphorus 0.36 0.D25 0.10 mg/L EPA 365,4 Total Kjeldahl Nitrogen 2.0 0.26 0,48 mg/L EPA 351.2 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in lull. Page 3 of LO www.encolabs.com ANALYTICAL RESULTS Descrlption: Outfall 1 Lab Sample ID: CA01243-01 Received; 10/17/17 08:05 Matrix: Surface Water Sampled:10/16/17 13:00 Work Order: CA01243 Project: Stormwater Testing Sampled By. -Joe Ladd LClassical Chemistry Parameters ^ - EACO Cary certl8ed o-lyte (ABC 5911 Analvte rCAS Numberl Results Elm Mau QE MU pa A= Math Analvzed By ly4ies Biochemical Oxygen Demand^ S.0 mg/L 1 2.0 2.0 7117040 SM 52108-2001 10/17/17 17:13 JOC Chemical Oxygen Demand^ 27 mg/L 1 10 10 7J19032 SM 5224D-1997 10/20/17 11:00 JOC Nitrate as N [14797-SS-8]A 0.088 J mg/L 1 0,025 0.10 7J18024 EPA 353.2 10/18/17 14:59 Jul Nitrate/Nitrite as NA 0.098 J mg/L 1 0.041 0110 7317026 EPA 353.2 10/17/17 13:32 JLJ Nitrite as N [14797-65-0]^ 0,017 U mg/L 1 0.017 0.10 7317033 EPA 353.2 10/17/17 15:12 JLJ Phosphorus 17723-14-0]A 0.41 mg/L 1 0.025 0.10 7320011 EPA 365.4 10/23/17 11:03 JLJ Total Kjeldahl Nitrogen^ 1.1 mg/L 1 0.26 0.48 7320010 EPA 351.2 10/23/17 09:23 JLJ Total Suspended Solids^ 32 mg/L 2.67 6.7 6.7 7323030 SM 254OD-1997 10/23/17 18:35 OMR Description. Outfall 2 Lab Sample ID. CAO 1243-02 Received: 10/17/17 08:05 Matrix. Surface Water Sampled: 10116117 12:30 Work Order: CA01243 Project: StormwaterTesting Sampled By,Joe Ladd Chemistry Parameters Analvte rCAS Numberl Results an unjts of Hu j4L @7Mh Method Analyzed am Hato Biochemical Oxygen Demand^ 49 mg/L 1 2.0 2.0 7117040 SM 521OB-2001 10/17/17 17:13 JOC Chemical Oxygen Demand' 96 mg/L 1 10 10 7319032 SM 5220D-1997 10/20/17 11:00 30C Nitrate as N [14797-55-e]A 0.78 mg/L 1 0.025 0.10 7J18024 EPA 353.2 10/18/17 14:59 JLJ Nitrate/Nitrite as NA 0.81 mg/L 1 0.041 0.10 7317026 EPA 353,2 10/17/17 13:37 JLJ Nitrite as N [14797-65-0]A 0.029 J mg/L 1 0.017 0.10 7117033 EPA 353.2 10/17/17 15:17 IL1 Phosphorus [7723-14-Or 0.36 mg/L 1 0.025 0.10 7120011 EPA 365.4 10/23/17 11:08 IL1 Total IQeldahl Nitrogen^ 2.0 mg/L 1 0.26 0.48 7120010 EPA 351.2 10/23/17 09:28 31-7 Total Suspended Sollds^ 25 U mg/L 10 25 25 7323030 SM 254OD-1997 10/23/17 18:35 OMR FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 10 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batd17J17026 - NO PREP Blank (7317026-BLK1) Prepared: 10/17/2017 13:28 Analyzed: 10/17/2017 13:28 Spike Source %REC RPD _AnaResult Flail PQL Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 0.041 U 0.10 m91L LCS (7317026-BSL) Prepared: 10/17/2017 13:30 Analyzed: 10/17/2017 13:30 Spike Source %REC RPD Anal Result Fail POL units Level Result a/oREC Limps RPD Limit Notes_ Nitrate/Nitrite as N 1.2 0.10 mg/L 1.25 98 90-110 Matrix Spike (7317026-MS3) Prepared: 10/17/2017 13:33 Analyzed: 10/17/2017 13:33 Source: CA01243-01 Spike Source %REC RPD Anal Result ELM POL Unitx Level Result a/aREC LIMIts RPD Limit Notes Nitrate/Nitrite as N 0.59 0.10 mg/L 0.521 0.088 96 90-110 Matrix Spike (7317025-MS2) Prepared: 10/17/2017 13:39 Analyzed: 10/17/2017 13:39 Source: CA01243-02 Spike Source a/oREC RPD Anallda Resui! ELIQ POL U11Its Level Re6LR %REC Limits RPD Limp Notes Nitrate/Nitrite as N 1.3 0.10 mg/L 0.521 0.81 100 90.110 Matrix Spike Dup (7317026-MSD3) Prepared: 10/17/2017 13:35 Analyzed: 10/17/2017 13:35 Source: CA01243-01 Spike Source R/aREC RPD Anahctll Result Elan Pall. units Level Result 0/oREC Limits RPD Limp lY4teS Nitrate/Nitrite as N 0.60 0.10 mg/L 0.521 0.088 99 90-110 3 10 Be[dl 7JI7033 - NO PREP Blank (7317033-BLKI) Prepared: 10/17/2017 15:11 Analyzed: 10/17/2017 15:11 Spike Source %REC RPD AnalYte Resit Elaa PQL Units Level Result %REC Llmlts RPD Limit Notes Nitrite as N 0.017 U 0.10 mg/L LCS (7317033-BSI) Prepared: 10/17/2017 15:03 Analyzed: 10/17/2017 15:03 Spike Source 9/oREC RPD Anal Result Elan ML Units Level Result %REC Llmlts RPD Limit Notes Nitrite as N 0.99 0.10 mg/L 1.00 99 90-110 Matrix Spike (7317033-MSI) Prepared: 10/17/2017 15:13 Analyzed: 10/17/2017 15:13 Source: CA01243-01 Spike Source a/oREC RPD Ana 4rt9 Result Flag WL Units Level Resul! a/oREC Limits RPD Ulmlt dotes_ Nitrite as N 0.99 0.10 mg/L 1.00 0.017 U 99 90-110 Matrix Spike (7317033-MS2) Prepared: 10/17/2017 15:18 Analyzed: 10/17/2017 15:18 Source: CA01243-02 Spike Source %REC RPD Anal Result Flail POL Units Level Be5Llt a/aREC Limits RPD Limp Notes Nitrite as N 1.0 0.10 mg/L 1.00 0.029 99 90-110 Matrix Spike Dup (7317033-MSDI) Prepared: 10/17/2017 15:14 Analyzed: 10/17/2017 15:14 Source: CA01243-01 Spike Source %REC RPD .Armll(t® Result Baa POL units Level Result %REC Limits RPD Limit dotes FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 5 of 10 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 7JI7033 - NO PREP - Condnued Matrix Spike Dup (7317033-MSD3) Continued Prepared: 10/17/2017 15:14 Analyzed: 10/17/2017 15:14 Source: CA01243-01 Spike Source %REC RPD Anal 1[te Result Flag P41 Lnit9 Level Result %REC Limlti RPD Limit Notes Nitrite as N 0.97 0.10 mg/L 1.00 0.017 U 97 90-110 2 10 Batch 7JI7014O - NO PREP Blank (7317040-BLKi) Prepared & Analyzed: 10/17/2017 17:13 Spike Source a/aREC RPD Ana RffLwt Hd4 M Sln1Li Level ( %REC Limits RPD Limit Notes Biochemical Oxygen Demand 2.0 U 2.0 mg/L LCS (7317040-BSI) Prepared IN Analyzed: 10/17/2017 17:13 Spike Source %REC RPD Anal Result Elan PQL Un(t9 Level Result %REC Limits RPD Limit hotel Biochemical Oxygen Demand 170 2.0 mg/L 198 88 85-115 Duplicate (7317040-DUP3) Prepared & Analyzed: 10/17/2017 17:13 Source: CA13061-02 Spike Source °/oREC RPD Ana hds Result Else PQL Un[tl Level Result %REC Limits RPD Limit Notes Biochemical Oxygen Demand 8.9 2.0 mg/L 9.1 3 30 Batch 7a19032 - Same Blank (7319032-BLKi) Prepared: 10/19/2017 18:02 Analyzed: 10/20/2017 11:00 Spike Source %REC RPD _Ananda RCsul FIN Pal. Unit4 Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 10 U 10 mg/L LCS (7319032-BS3) Prepared: 10/19/2017 18:02 Analyzed: 10/20/2017 11:00 Spike Source a/oREC RPD 9ml]de Result am ROL Units Level Result %REC Nm]tg RPD Limit Notes Chemical Oxygen Demand 500 10 mg/L 500 101 90-110 Matrix Spike (7319032-MS1) Prepared: 10/19/2017 18:02 Analyzed: 10/20/2017 11:00 Source: CA01243-01 Spike Source %REC RPD Anal Result Elan EOL 1lnits Level Result %REC Llmitfi RPD Limit Notes Chemical Oxygen Demand 560 10 mg/L 526 27 101 • 90.110 Matrix Spike Dup (7319032-MSDI) Prepared: 10/19/2017 18:02 Analyzed: 10/20/2017 11:00 Source: CA01243-01 Spike Source °/oREC RPD Ana lsda Result "M ROL Unlls Level Result %REC Limits RPD Limit r!letes Chemical Oxygen Demand 570 10 mg/L 526 27 102 90-110 0.8 10 Batch 712OO1O - Same Blank (7220010-BLK1) Prepared: 10/20/2017 14:35 Analyzed: 10/23/2017 09:19 Spike Source a/oREC RPD Ana Result Elan PQL Liam Level Result %REC Lim[ tg RPD Limit Notes Total Kjeldahl Nitrogen 0.26 U 0.48 mg/L FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 6 at 10 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 7J20010 - Same - Continued LCS (7320030-BSI) Prepared: 10/20/2017 14:35 Analyzed: 10/23/2017 09:21 Spike Source %REC RPD 9nande Result Flag POL units Level Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 12 0,48 mg/L 11.9 104 90-110 Matrix Spike (7320010-MS3) Prepared: 10/20/2017 14:35 Analyzed: 10/23/2017 09:24 Source,CA01243-01 Spike Source %REC RPD Ana Result Flag POL Unita Level Result %REC Limits RPD Li01it Notes Total Kjeldahl Nitrogen 5.8 0.48 mg/L 4.75 1.1 100 90-110 Matrix Spike (7320010-MS2) Prepared: 10/20/2017 14:35 Analyzed: 10/23/2017 09:29 Source: CA01243-02 Spike Source 0/aREC RPD _Anah ttC Result Hag M llnits Level Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 6.7 0.48 mg/L 4.75 2.0 98 90-110 Matrix Spike Dup (7320010-MSDL) Prepared: 10/20/2017 14:35 Analyzed: 10/23/2017 09:26 Source: CA01243-01 Spike Source %REC RPD _Anahft Result Hag P_41 units Level Resul} %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 6.0 0.48 mg/L 4.75 1.1 103 90-110 3 10 Batch 7J20011 - Same Blank (7320011-BLKI) Prepared: 10/20/2017 14:35 Analyzed: 10/23/2017 11 A 1 Spike Source %REC RPD Ana lYtg Result Hag PQL Unm Level Result %REC Llmitp RPD Limit Notes Phosphorus 0.025 U 0.10 mg/L LCS (7320011-BS1) Prepared: 10/20/2017 14:35 Analyzed: 10/23/2017 11:02 Spike Source %REC RPD Anatift Result Hag PQL Units Level Result %REC Limits RPD Limit Notes Phosphorus 1.6 0.10 mg/L 1.60 100 80-120 Matrix Spike (7320011-MSi) Prepared: 10/20/2017 14:35 Analyzed: 10/23/2017 11:05 Source,CA01243-01 Spike Source %REC RPD Anal YtA Result Hag PQL Units Level Result %REC Limitre RPD Limit Notes Phosphorus 1.1 0.10 mg/L 0.640 0.41 103 80.120 Matrix Spike Dup (7320011-MSD1) Prepared: 10/20/2017 14:35 Analyzed: 10/23/2017 11:06 Source: CA01243-01 Spike Source %REC RPD Ana hds Result Hag P91 Units Level Res,llt %REC Limb RPD Limit Notes Phosphorus 1.1 0.10 mg/L 0.640 0.41 104 80-120 0.3 25 Batch 7J23030 - NO PREP Blank (7323030-BLKL) Prepared & Analyzed: 10/23/2017 18:35 Spike Source %REC RPD Anahf17H Result Elm PAL units Level Result %REC Limits RPD Limit Motes Total Suspended Solids 2.5 U 2.5 mg/L FINAL This report relates only to the sample as recelved by the laboratory, and may only he reproduced In full. Pape 7 of 10 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 7J23030 - NO PREP - Condnued LCS (7323030-BSI) Prepared & Analyzed: 10/23/2017 18:35 Spike Source %REC RPD Ana Result Elm P01. Units Level Result %REC Limits RPD Lim(t Notes Total Suspended Solids 90 2.5 mg/L 100 90 80-120 Duplicate (7323030-DUPI) Prepared & Analyzed: 10/23/2017 18:35 Source: CAL3516-01 Spike Source %REC RPD Ana Result Flag PM Units Level 1 asult %REC Limits RPD MMIA i'iPW Total Suspended Solids 490 50 mg/L 630 26 20 QM-12 Duplicate (7323030-DUP2) Prepared & Analyzed: 10/23/2017 18:35 Source: CA13516-03 Spike Source %REC RPD Anal lde Result Elan PQL Units Level Result %REC Limits RPD Limit Notes Total Suspended Solids 440 50 mg/L S00 12 20 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 8 of 10 www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank, D The sample was analyzed at dilution, J The reported value is between the laboratory method detection limit (MIL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. QM-12 Precision between duplicate samples was outside acceptance limits. FINAL This report relates only to the sample as recetved by the laboratory, and may only be reproduced in full. Pape 9 of 10 'ENVIRONMENTAL CONSERVATION LABORATORIES CHAIN -OF -CUSTODY RECORD www.encolabs.com _ 10775 CenNal Fbn Dr. 48141=.rr,.l m Park Corot, SLd* III 102-A Woodwktds Industrial 1--L 11111111110 OrlarKkx F-L 32824 Jeruwwise, FL 32216,60B9 Cary, NC 27511 �wd(407) 826 6314 Fax (4CM 8504945 (904) 296.3007 Fax (904) 2964327o (919j 497,3o90 Fm (919) 457-515 Page Of mm CS"Nam Pmjca Mercer xd Arm"" Requested Turnaround Times No*. Rush roquesb subject la by"*W1" f� Standard i _ Expedited Due— m o C14 c/a O CID ❑ c*4 cn Q N ch W U m �� z N Z fA w � z r Z CL cq U) O z © a 2 � Zo (J) I (P v� naryerm 77 Perry Che pe.1 Churct Ra ad Storrn►araterTest) cilyfsrrzp 4 Franklirlton NC 27S2,5 PO f 1 Sam tea 3f;00245169 Tel 494-3370 Fax Rapwtug Cor4w Jcie Ladd Sam or(s) Nmne. Arritfadan (Pr") 13aig contact A(:crourlts Payable ____ SarrpNr(al lure Me Locabon / TWm Zone LabWOrkorder CA01243 1 Preservation (See Cadesl (Cambhre a, neaesaan) Item f Sam* ID (Hold Iderdr "Jor0 Cogacbm Date Cofxtion TkIm CwWl Grab Flatrix (see codes] Tatal f q CuTwnms Sample Comments o-t4 • aw 6tib .See Wmtvmk -►tea! sw s X Xfro jig <-- Total tt of conWners j Sang" Nit PrePered W I g-L,F - 30 11 KWII;tAshed By 1•c�dQ►Q DaRrntme lo•l�i•?w�1 HBCeired Da me �7 ts Q/i{Zd fS y 9. 2 By Dawrmw pebpmhed � By Dalarrime nemired By >)owfime fh R on RecetPt ] � ` t,ondffiwe LlPon kerRp i�CCRPi3lJle Uf12CL'e�tA�l$ Ustft : C.W-Gmtmdriraiw 50-sol DM-odn)ml Water SE-Sadknom SWSrrrlaoe Water W W-Wastewater A -Air 0 400ter (deW In cwm mU) PrepnatkmL LIcII MCI UMN03 &H2SO4 No-WOH o43uw (dataf in cwnments) • Naln : AN san4 as subammW to ENCO Labs are in eccerdanm with the tams and cartd4iom listed on the reverse of thb 1wm, w*m prtm wrmen ageww" goal i Sample Preservation ENCO Cary cation �uco Work Order: CA01243 Project: St �mwater Testing Client: Novozymes North America (N0008) Project M (none) Logged In: 17-Oct-17 08:27 Logged By: Johin C-King I CA01243-01 1 Cant: Type ': res. p Requirem nt p acked . In Control pH Adjusted atelTime Adjusted Reagent Used/Comments , D 250mLP+H2SO4 <2 I N I NA Y/ 61 NA E 250mLP+H2SO4 <2 1 N I NA Y I d I NA CA01243-02 Cont- Type - Requi em nt p In Control ate ime pH Adjusted Adjusted Reagent Used/Co D 250mLP+H2SO4 <2 Ji N I NA Y I 1 NA E 250mLP+H2SO4 <2 I N I NA Y! V NA Reagent Name ID 1 2 Reagent Name ID 3 4 Rea ent Name ID 3 I 3 Page 1 of 1 77 Date: June 9, 2017 Novozymes, NA Inc. 77 Perry's Chapel Church Rd. Franklinton, N.C. 27525 NCDENR Division Of Water Quality 1617 Mail Service Center Raleigh, N.C. 27699-1617 Attn: Division Of Water Quality Storm Water Sampling, NPDES Permit No. NCS000115 Dear Sir/Madam novozymes• Rethink Tomorrow Per our Tier Two requirements, regarding the exceeded benchmark in Biological Oxygen Demand, (BOD) and Chemical Oxygen Demand, (COD), our implementation of a monthly monitoring in area of concern, "Outfall 2", beginning in March has resulted in three consecutive sample results that are within required benchmark range. Test results from May mark the third consecutive month that our SOD and COD readings have been within benchmark range. With May's testing complete, and compliance established, this will conclude our monthly monitoring for BOD and COD. We will continue our second of two required Storm Water sampling events prior to the end of the calendar year. Kind Re s, Joe Ladd ' Environmental Compliance Coordinator Environmental Services EFFLUENT NPDES PERMIT NO. NCS000115 DISCHARGE NO. 2 FACILITY NAME Novozymes, NA Inc. CLASS OPERATOR IN RESPONSIBLE CHARGE (ORC) N/A CERTIFIED LABORATORIES (1) Enco (2) CHECK BOX IF ORC HAS CHANGED C==Fl PERSON(S) COLLECTING SAMPLES Mail ORIGINAL and ONE COPY to: ATTN: CENTRAL FILES x NIA DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) 1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY RALEIGH, INC 27699-1617 KNOWLEDGE. MONTH May YEAR 2017 COUNTY: Franklin PHONE i919) 494-3001 Joe Ladd Lill DWQ Form MR -I (11/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) Compliant All monitoring data and sampling frequencies do NOT meet permit requirements Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.6 of the NPDES permit. -I certity, under penalty of taw, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Randy Green Permittee (Please print or type) 4 W V� re of P ittee*** Date (Required u e s submitted electronically) Permittee Address Phone Number e-mail address Permit Expiration Date Certified Laboratory (2) Certified Laboratory (3) Certified Laboratory (4) Certified Laboratory (5) ADDITIONAL CERTIFIED LABORATORIES PARAMETER CODES . Certification No. Certification No. Certification No. Certification No, Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.us/was and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. *** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 2B .0506(b)(2)(D). Page 2 JX CO Laboratories Accurate. Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Monday, June 5, 2017 Novozymes North America (NO008) Attn: Joe Ladd 77 Perry Chapel Church Road i=ranklinton, NC 27525 RE: Laboratory Results for Project Number: [none], Project Name/Desc: Stormwater CA ENCO Workorder(s): CZ19514 Dear Joe Ladd, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Wednesday, May 24, 2017. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Chuck Smith Project Manager Enclosure(s) FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 1 of 7 www.encolabs.com SAMPLE SUMMARY/ LABORATORY CHRONICLE Client In, Outfall2 Lab ID: a19514-01 Sampled: 05/23/17 14:30 Received: 05/24/17 08:07 Parameter Hold DatelTimefsl Prep Date/Tlmefsl Analysis Date/11me(s) SM 5210B-2001 05/25/17 14:30 05/24/17 13:18 05/24/17 1118 SM 5220D-1997 06/20/17 05/26/17 12:59 05/26/17 17:05 FINAL This report relates only to the sample as recehied by the laboratory, and may only be reproduced In fufl. Pape 2 of 7 www.encGlabs.com SAMPLE DETECTION SUMMARY Client ID: Outtall 2 Lab ID: CZ19514-01 BnalM Res" fin Hu E" lWSa Methad KQ= Biochemical Oxygen Demand 5.4 2.0 2.0 mg/L SM 521OB-2001 Chemical Oxygen Demand 58 10 10 mg/L 5M 5220D-1997 FINAL This report relates only to trm sample as reoeKed by the laboraoory, and may only be reproduced In full. Faye 3 of 7 www.encolabs.com ANALYTICAL RESULTS Description: Outfall 2 Lab Sample ID: CZ19514-01 Received: 05/24/17 08:07 Matrix: Surface Water Sampled:05/23/17 14:30 Work Order: CZ19514 Project: Storrnwater CA Sampled By:Joe Ladd Classical Chemistry Parameters - L%W Cary C"*d cmlNft PC 5911 Analvte rCAS Number] R9sul an Units pf M" p" lagh lei Analyzed NoUs Biochemical Oxygen Demand^ 5.4 rng/L 1 2.0 2.0 7E24020 SM 521OB-2001 05/24/17 13:18 30C Chemical Oxygen Demand^ 58 mglL 1 10 10 7E26013 SM 5220D-1997 05/26/17 I.T05 30C FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 4 of 7 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 7E24020 - NO PREP Blank (7E24020-BLK3) Prepared & Analyzed: 05/24/2017 13:18 Spike Source %REC RPD Ana hds Result Else ML units Level Result %REC Limits RPD Limit Notes Biochemical Oxygen Demand 2.0 U 2.0 mg/L LCS (7E24020-OSI) Prepared & Analyzed: 05/24/2017 13:18 Spike Source %REC RPD Anah[t0 Result Elm PAL !!nits Level Resul( %REC Limits RPD Limit Notes - Biochemical Oxygen Demand 180 2.0 mg/L 198 91 85-115 Duplicate (7E24020-DUP1) Prepared & Analyzed: 05/24/2017 13:18 Source: CA00231-01 Spike Source %REC RPD AnBhdA Result Flan POL Units level Result %REC Limits RPD Limit Notes Biochemical Oxygen Demand 180 2.0 mg/L I70 1 30 Batcyi 7E260.13 - Same Blank (7E26013-BLK3) Prepared: 05/26/2017 12:59 Analyzed: 05/26/2017 17:05 Spike Source %REC RPD Analvts Result Elea PQL flnita Level Besult %REC Limb RPD Limit Well Chemical Oxygen Demand 10 U 10 mg/L LCS (7E26013-BS1) Prepared: 05/26/2017 12:59 Analyzed: 05/26/2017 17:05 Spike Source %PEC RPD Anal lda Result Has EGL units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 500 10 mg/L 500 101 90-110 Matrix Spike (7E260i3-MSi) Prepared: 05/26/2017 12:59 Analyzed: 05/26/2017 17:05 Source. CA00213-01 Spike . Source %REC RPD Ann hds Resul Has ROL units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 2700 40 mg/L 2000 670 101 90-110 Matrix Spike Dup (7E26013-MSDI) Prepared: 05/26/2017 12:59 Analyzed: 05/26/2017 17:05 Source:CA00213-01 Spike Source %REC RPD Anal lde REsul Has P01 llnb Level Result %REC Limits RPD limit liter Chemical Oxygen Demand 2700 40 mg/L 2000 670 103 90-110 2 10 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full, Page 5 of 7 www.encolobs.com FLAGS/NOTES AND DEFINITIONS 8 The analyte was detected in the associated method blank. D The sample was analyzed at dilution. ] The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 6 of 7 cam*er.vnari���r�a-a+vnocn�n�w��u�suvstiriwn�c� a.r�rrae�„tir-a.v.�wvr n>�a.vnv WWW.rn%vJIdVa.cAnn- �O lom CW3:ra Pat E1r: 4f110 ExKxtd" Part C4)vM Skco,111 102-A VOODOsNIQ9 hlCeatltal C1. grfand . FL 3M4 dadwnrnm9le, FL 32216MO: Cary, He 27511 Lem (4CMJ20-M14 Fm.(40nSM- 945 (904) 296-3W7 Fax(" 296.5210 (919) 46 -3090 Fax (919) 4U-3515. Page _J_ Of . Clary Name ....... .. _ , � :....... .. . . . � .. ... . 1 Pm od "Let ar .: ..: k -.. , .., � Paquesua Armlyass Requested Turnaround TirtMs [tolB: Ru!h nques7s suOjaM70 ig—by Ito br .__ Standard _Expedited° Due ��J 1� m Ln chi] Addrm 77 Perry Chapel Church Road Stormwater CA CiymTrzp - - - - .. - -.. FrankGntoni NC 27525 -.. vo s! E MSIV 3SW246169 .. Tel Fear 4n4-�3370 Samp"s) Hams. Afr*atm R�rB Cored Joe Ladd . Bib* Card- Accou;ft Payable r(s1 S r Sselon! Tsne zone. 1r Lab Workorder CZ19514 ProsavvUen (sae c:odeal (carrhq:ve as rockasary) stern a Smioe 10 (Field wsrail,ratiart) Coambn Dsts c49ac m Cep 1 Grab matrix:. (--OS) -fowl I of. Contafnwe Sa ote corrlrrler t5 ,,Tana . 6 1. i c--'total # of Containeis Sarhpte Ka.Prepared By .. , :- Dele/Tshhe FteWwgwisrwed BY -� fT °. }f E>ptdrioe S. caww"Mmmal Rmwtmg Rem . ? - - r CWAL63 ed ay netdr Sm Br oetdrsns Re6q at" By Oaterrmw R fay •. - •.. - patmff Vm - , C:oofu s's d Tempe an no=" � - - �- - L ear41 1'7vcptableUnatx epfable UsVls : Gw-Grarmdeala' SO•Sd OW-OnrdwV WSWf SE.Sadmierd. SW S'rutace Waler WW-W A -Air CK)t1 r (detail in corarn�r9) - Pressrwa lea: Hce WHO WiNM 5-H2504. NO-NaGH G-O (detail In oormr uft) . t4ca -AN san%ibs eLdxT% ad 10 ENCO labs ass in aocrxdm with the terms aid cardOwis ictsd an da romm d tlis komh, wdaaa prior uainm apeerrarta edit Sample Preservation Verification ENCO Cary Work Order: CZ19514 Project: Stormwater CA Client: Novorymes North America (N0008) Project M [none] Logged In: 24-May-17 09:38 Logged By: John C King CZ19314-01 ,Conn Y e res f3 h e pH Adjusted ai ime . �� € , Use on menis s ; R uNmen ln,Contral Adiusted - zReagent . B 250rnLP+H2SO4 <2 • I N / NA Y / 1 NA Reacient Name ID 1 2 Reac3ent Name ID 3 4 Rea ent Name ID 5 6 Page 1 c Date: May 4, 2017 Novozymes, NA Inc. 77 Perry's Chapel Church Rd. Franklinton, N.C. 27525 NC DEQ Division Of Water Quality 1617 Mail Service Center Raleigh, N.C. 27699-1617 Attn: Division Of Water Quality Storm Water Sampling, NPDES Permit No. NCS000115 Dear Sir/Madam novozymese Rethink Tomorrow ft RECEIVED MAY 19 2017 owkF Per our Tier Two requirements, regarding the exceeded benchmark in Chemical Oxygen Demand, (COD) and Biological Oxygen Demand (BOD), our implementation of monthly monitoring in area of concern, "Outfall 2", beginning in January has resulted in the second of three being within required benchmark range during April event. Test results from April mark the second consecutive month that our BOD and COD readings have been within benchmark range. With April's testing complete, we will collect samples again from Outfall 2 for BOD and COD only until three consecutive sample results are within required benchmark range. We will continue our second of two required Storm Water sampling events prior to the end of the calendar year. Kind Joe Ladd Environmental Complia Environmental Services Coordinator EFFLUENT NPDES PERMIT NO. NCS000115 DISCHARGE NO. FACILITY NAME NOVOZyme5, NA Inc. CLASS OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA CERTIFIED LABORATORIES (1) Enco CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Mail ORIGINAL and ONE COPY to: 2 MONTH April YEAR (2) Jae Ladd COUNTY: Franklin PHONE i9191494-3001 ATTN: CENTRAL FILES x NIA DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) 1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY RALEIGH, NC 27699-1617 KNOWLEDGE. 2017 DWQ Farm MR-1 (11/04) 0 EJVCO Laboratories Accurate. Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Tuesday, May 2, 2017 Novozymes North America (NO008) Attn: Joe Ladd 77 Perry Chapel Church Road Franklinton, NC 27525 RE: Laboratory Results for Project Number: [none], Project Name/Desc: Stormwater CA ENCO Workorder(s): CZ19516 Dear Joe Ladd, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Monday, April 24, 2017. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are In compliance with NELAC standards, except as noted in the project narrative. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Chuck Smith Project Manager Enclosure(s) FINAL This report mates only to the sample as received by the laboratory, and may only be reproduced !n full. Page t of 7 www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE CllentID: OWN12 Lab ID: CZ1951e-Ol Sampled: 04/23/17 15:00 Received: 04/24/17 08;00 Parameter Hold Date/Timefsl Prep Date/Time(a) Analysls Date/Time(s) 5M 52108-2001 04/25/17 15:00 04/25/17 14:06 04/25/17 14:06 SM 5220D-1997 05/21/17 04/27/17 18:24 04/28/17 10:37 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 2 of 7 SAMPLE DETECTION SUMMARY I Client ID: Outfall 2 Lab ID: CZ19516-01 Biochemical Oxygen Demand Chemical Oxygen Demand 3.3 2.0 2.0 mg/L 28 10 10 mg/L www.encolabs.com SM 521OB-2001 SM 522OD-1997 FINAL Thfs report relates only to the sample as reoelved by the laboratory, and may only be reproduced In full. Pape 3 of 7 www.encolabs.corn ANALYTICAL RESULTS Description: Outfall 2 Lab Sample ID:CZ19516-01 Received: 04/24/17 08:00 Matrix: Surface Water Sampled:04/23/17 15:00 Work Order: CZ19516 project: Storrnwater CA Sampled By:Joe Ladd Classical Chemistry Parameters ^ - EAM Cary CerVAed enalyte PVC 691) Analvbe rCAS Numberl Results fin Unih PE HU 1'9.6 Adds 1Method Analyzed By Notes Biochemical Oxygen Demand^ 3.3 mg/L 1 2.0 2.0 71325023 SM 52108-2001 04/25/17 14:06 30C Chemical Oxygen Demand^ 28 mg/L 1 10 10 7D27049 SM 5220D-1997 04/28/17 10:37 30C FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 4 of 7 Ce ML9 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batt* 7D25O23 - NO PREP Blank (7DZ5023-BLK3) Prepared 8: Analyzed: 04/25/2017 14:06 Spike Source %REC RFD Anal Resul ElaO PDL Ulnits Level Result %REC Lets RPD LID1lt Notes Biochemical Oxygen Demand 2.0 U 2.0 mg/L B-03 LCS (7D25023-BSI) Prepared 8. Analyzed: 04/25/2017 14:06 Spike Source %REC RPD Auanda Result Has PQL units Level Resin %REC Limits RPD LLD11t Notes BiochemicalOxygen Demand 200 2.0 mg/L 198 100 85-115 Duplicate (7025023-DUPl) Prepared 8. Analyzed: 04/25/2017 14:06 Source: CZ19516-01 Spike Source %REC RPD Anal Result Elm PQL Ulnlffi Level B28ult %REC Limb RPD Limit Notes Biochemical Oxygen Demand 3.1 2.0 mg/L 3.3 5 30 Bak* 7027O49 - Some Blank (7D27049-BLKI) Prepared: 04/27/2017 18:24 Analyzed: D4/28/2017 10:37 Spike Source %REC RPD Ana bds Result Hag MIL IInEtB Level Reslilt %REC LIMI i RPD Limit Notes Chemical Oxygen Demand 10 U 10 mg/L LCS (7D27049-BSI) Prepared: 04/27/2017 18:24 Analyzed: 04/28/2017 10:37 Spike Source %REC RPD .AnandO Result Flan P41 llnits Level Result %REC L(n RPD Limit Notes Chemical Oxygen Demand 500 10 mg/L 500 100 90-110 Matrix Spike (7D27049-MSI) Prepared: 04/27/2017 18:24 Analyzed: 04/28/2017 10:37 Source:CA00065-01 Spike Source 9/oREC RPD Anal YD9 Result Hall POL Mnits Level Resul a/aREC Limb RPD Limit Notes Chemical Oxygen Demand 560 10 mg/L 526 43 98 90-110 Matrix Spike Dup (7D27049-MSD1) Prepared: 04/27/2017 18:24 Analyzed: 04/28/2017 10:37 Source:CA000SS-01 Ana4tte Chemical Oxygen Demand Spike Source %REC Result Elan PQL !!nits Level Result %REC Limits RPD 570 10 mg/L 526 43 100 90-110 2 RPD Limit !hates 10 FINAL This report relates only to the sample as receKed by the laboratory, and may only be reproduced In full. Pape 5 of 7 E�69 www.encolobs.com FLAGS/NOTES AND DEFINITION5 B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. 3 The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. B-03 Blank exceeds the method required oxygen depletion of <0.20 mg/L. FINAL This report relates only to the sample as recehed by the laboratory, and may only be reproduced In full. Page 6 of 7 - -� - 4n�n�v/��u�nrYlLw,.v�•.71Cs7rMIrvl�LMtt7V1'1AIVlfliC.l $-rt TFl-a_,rr-'l:VatVu1 n=%LVMP vivimencoiamcom �O TOM Central Pot Dr. ,4810 F_x MMW Perk CqM. SLft 111 tt12-A Woodwhula bxktsb a! CL - Orlando. FL 32824 ,ladcaaa8fs FL W, 16-6= Ce►n NC a511 - (407) CWW14 Pax (407) aW-e 45 - (904) M&,- 07 Fax (904) 288-6210 _ . (91 s) 467-30M Fa[ (919) 467-3515 Page Of -. cwd Narlre -: = Pro)ert Nrpnber 1 Ri d Arrellrasa `.... R ed TulTmmnd - Times NM. Rlrslr requests mbjed to a-optb ehy1Yie%CWY Standard- - _ Expedited Due m O � t� O 0 r . AWress 77 Per Cha el Church d Praler! MamdDeit - - Stormwater CA FranftEireton NC 27525 PO a 1 SOM lnb 380t?245169 Tel - 4 4 3370 Fax - Rapoiiiep cortad Joe Ledd SanWlar(s) Name, AlOW im (Prim) Ilk i 6Urarq corRau Aca)urrts Payable s Sampler[) SV a Locabw r roe xorre lab Workorder CZ1 9516 PmaervaUm (Sae Codes) (Carrrbkw as m&war►) R— r SaTols ID (>-iM MwM=tbn) Coftc& n Dffis Coieetion rare .. C MI Grab - .. Matrix (sea codes) ..Tonal 1 o1 - ors - - - - Samoe GOmment5 -3 _ -- Total a of Containers Sample ril Prepared 8y - -". Dslefrime , -. Raliaryisbed B -. - Datr/rime -. .. ReoChrod .- ;yi - . DaWTow i \ Qmwr ntsSpacEal Repm" Raq x marts - r- ., ROWIL bed By j DatslTm e . DatslTWm RekqukhW@y - --� - -- .. - Dawrl"Ilvey ,.- .... Cooler Vs d Temps on Recatpt _ ...... - - _.. - , _ . . - -, .. - .. _ • _.. CmOition - .. - - � y - ... • - - y - - � CC6ptablB. — Unacceptable Matft: GOw-onx"rdrratm SO-SO t]WDrhgdng Wafer; SE-SeWmerrt SW-SUrlace water W W-Wastewater A -Air O.Olher (dateii in tenure ts) - Preservation: Was, M-HCl N-HNO3 S 4t2S(34 NO•NaON aCter Wetal in, m ,nti) 1leCB :Al sorrow raftT=o to F-NW Lan we m oomoonve with the am.. end CO!rdiaarla a8fed Ort Cis raOrae d title Io++rL IglrB9a prig rrrltarr aQroE(rlaritS CxfSt ' Ry... �•...:.,',a_..:--:�._..--...�...�•�.1,=-Jf a-"� � -� _. �a �� _sw! _- � t •-+. �...- _a-.c.�....� :.-..�..-.yat.4..�.�-t-.+..er--�"'----..-,.�v--�. �..-.• �. —.. --. „--_. - --. _-.. - . - .. _ _ . r � _ - _ - -- Sample Preservation Verification •ENCO Cary Work Order. CZ19516 Project: Stormwater CA Client: Novozyme& North America (N0008) Project #: [none] Logged In: 24-Apr-17 08:19 Logged By: John C King CZ19616-M _ Conk Ty R uirerne IM PH Adjunad Adiustad i'Y R9a—a t lI: dlCommenN 8 250mLP+H2SO4 <2 '/ N / NA 1 1 NA Reacient Name ID 1 2 Rea ent Name ID 3 4 Rea ent Name ID 5 61 Page 1 c Date: March 28, 2017 Novozymes, NA Inc. 77 Perry's Chapel Church Rd. Franklinton, N.C. 27525 NC DEQ Division Of Water Quality 1617 Mail Service Center Raleigh, N.C. 27699-1617 Attn: Division Of Water Quality FEE I V E D APR 2 0 2017 CENTRAL FILES DWR SECTION Storm Water Sampling, NPDES Permit No. NCS000115 Dear Sir/Madam novozymesm Rethink Tomorrow Per our Tier Two requirements, regarding the exceeded benchmark in Chemical Oxygen Demand, (COD) and Biological Oxygen Demand (HOD), our implementation of monthly monitoring in area of concern, "Outfall 2", beginning in January has resulted in the first of three being within required benchmark range. Test results from March mark the first month that our BOD and COD readings have been within benchmark range. With March's testing complete, along with other required parameters tested, we will collect samples again from Outfall 2 for HOD and COD only until three consecutive sample results are within required benchmark range. We will continue our second of two required Storm Water sampling events prior to the end of the calendar year. Kind Reg Joe Ladd Environmental Compliance Coordinator Environmental Services EFFLUENT NPDES PERMIT NO. NCS000115 DISCHARGE NO. FACILITY NAME Novozymes, NA Inc. CLASS OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA CERTIFIED LABORATORIES (1) Enco CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Mail ORIGINAL and ONE COPY to: MONTH March YEAR Joe Ladd COUNTY: Franklin PHONE (919) 494-3001 A I I N: CENTRAL FILES x NIA DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) 1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY RALEIGH, NC 27699-1617 KNOWLEDGE, 2017 DWQ Form MR-1 (11/04) EFFLUENT NPDES PERMIT NO, NCS000115 DISCHARGE NO. 2 FACILITY NAME Novozymes, NA Inc. CLASS OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA CERTIFIED LABORATORIES (1) Enco (2) CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Mail ORIGINAL and ONE COPY to: ATTN: CENTRAL FILES : MA DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) 1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY RALEIGH, NC 27699-1617 KNOWLEDGE. MONTH March YEAR 2017 COUNTY: Franklin PHONE (919) 494-3001 Joe Ladd �. DWQ Form MR-1 (11/04) 0 CO Laboratories Accurate. Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Friday, March 24, 2017 Novozymes North America (NO008) Attn: Joe Ladd 77 Perry Chapel Church Road Franklinton, NC 27525 RE: Laboratory Results for Project Number: [none], Project Name/Desc: Stormwater Testing ENCO Workorder(s): CZ19517 Dear Joe Ladd, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Wednesday, March 15, 2017. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards,, except as noted in the project narrative. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Chuck Smith Project Manager Enclosure(s) FINAL This report relates aNy to the sample as rem+oed by the laboratory, and may only be reproduced 0 ful. Pape 1 of 10 www.encolabs.com SAMPLE SUMMARY/ LABORATORY CHRONICLE Client ID: Outfall 1 Lab ID: CZ19517-01 Sampled: 03/24/17 11:00 Recelved: 03/15/17 08:00 Parametg EPA 351.2 Hold Date/Tlmefsli 04/11/17 Prep DatelTimefsl 03/16/17 Analysis Date/Tlmefsl 11:55 03/20/17 10:24 EPA 353.2 03/16/17 11:00 03/15/17 13:01 03/15/17 13:01 EPA 353.2 04/11/17 03/21/17 12:11 03/21/17 12:11 EPA 353.2 12/08/19 03/22/17 11:28 03/22/17 12:19 EPA 365.4 D4/11/17 03/16/17 11:55 03/20/17 11:21 SM 254OD-1997 03/21/17 03/20/17 09:40 03/20/17 09:40 SM 52108-2001 03/16/17 11:00 03/15/17 1327 03/15/17 1127 SM 5220D-1997 04/11/17 03/20/17 14:21 03/20/17 18:08 Client ID: Outfall2 Lab ID: CZ19517-02 Sampled: 03/14/17 10:00 Received: 03/15/17 OB:00 umme EPA 351.2 Hold Date/31mefsl 04/11/17 Prep Datefflmg{;] 03/16/17 11:55 03/20/17 10:26 EPA 353.2 03/16/17 10:00 03/15/17 13:D2 03/15/17 13:02 EPA 353.2 04/11/17 03/21/17 13:28 03/21/17 13:28 EPA 353.2 12/08/19 03/22/17 11:28 03/22/17 12:19 EPA 365.4 04/11/17 03/16/17 11:55 03/20/17 11:22 SM 254OD-1997 03/21/17 SM 521OB-2001 03/16/17 10:00 SM 522OD-1997 04/11/17 03/20/17 09:40 03/20/17 09:40 03/15/17 13:27 03/15/17 1127 03/20/17 14:21 03/20/17 18:08 FINAL This report relates only to the sample as received by the laboratory, and may only ba reproduced In full. Pape 2 of 10 www.encolobs.com SAMPLE DETECTION SUMMARY Client ID: Out/all 1 Lab ID: Cz195I7-01 Anal1te sllte Aas Hu EQL ft= Biochemical Oxygen Demand 2.9 2.0 2.0 mg/L SM 521OB-2001 Chemical Oxygen Demand 30 10 10 mg/L SM 5220D-1997 Nitrate as N 1.1 0.025 0.10 mg/L EPA 353.2 Nitrate/Nitrite as N 1.1 0.041 0.10 mg/L EPA 353.2 Nitrite as N 0.017 1 0.017 0.10 mg/L EPA 353.2 Phosphorus 0,21 0.025 0.10 mg/L EPA 365.4 Total Kjeldahl Nitrogen 0.97 0.26 0.48 mg/L EPA 351.2 Total Suspended Solids 11 3.3 3.3 mg/L 5M 254OD•1997 Client M. Outrall 2 Lab ID: CZ19517-02 Biochemical Oxygen Demand 13 2.0 2.0 mg/L SM 521OB-2001 Chemical Oxygen Demand 41 10 10 mg/L SM 522OD-1997 Nitrate as N 0.16 0.025 0.10 mg/L EPA 353.2 Nitrate/Nitrite as N 0.16 0.041 0.10 mg/L EPA 353.2 Total Kjeldahl Nitrogen 0.60 0.26 0.48 mg/L EPA 351.2 FINAL This report relates only to the sample as recehred by Me laboratory, and may only be reproduced In full. Pape 3 of 10 www.encolabs.com ANALYTICAL RESULTS Description: Outfa[I 1 Lab Sample ID: CZ19517-01 Received: 03/15/17 08:00 Matrix: Surface Water Sampled:03/14/17 11:00 Work Order: CZ19517 Project, Stormwater Testing Sampled By:Joe Ladd Classical Chemistry Parameters ^ - SWO Cory c"Oed lmelyra (MC 591] Anafvte XAS Numberl Results rig ynb jf M[, EQL j= Method Ana 11121211111 Biochemical Oxygen Demand^ 2.9 mg/L 1 2.0 2.0 7C15009 SM 5210B-2001 03/15/17 13:27 JOC Chemical Oxygen Demand 30 mg/L 1 10 10 7C20018 SM 5220D-1997 03/20/17 18:08 JOC Nitrate as N [34797-55-8]^ 1.1 mg/L 1 0.025 0.10 7C22020 EPA 353.2 03/22/17 12:19 JU Nitrate/Nittite as N^ 1.1 mg/L 1 0.041 0.10 7C21003 EPA 353.2 03/21/17 12:11 ILI Nitrite as N [14797-65-0]A 0.017 J mg/L 1 0.017 0.10 7C15020 EPA 353.2 03/15/17 13:01 ILI Phosphorus [7723-14-0]^ 0.21 mg/L 1 0.025 0.10 7C16006 EPA 365.4 03/20/17 11:21 3L3 Total Kjeldahl Nlbogen^ 0.97 mg/L 1 0.26 0.48 7C16005 EPA 351.2 03/20/17 10:24 313 Total Suspended Solids^ 11 mg/L 1.33 3.3 3.3 7C20002 SM 254OD-1997 03/20/17 09:40 014R Description: Outfali 2 Lab Sample ID: CZ19517-02 Received: 03/15/17 08:00 Matrix: Surface Water Sampled:03/14/17 10:00 Work Order: CZ19517 Project* 5tonwater Testing Sampled By:Joe Ladd lClassical Chemistry Parameters ^ - SACO Ciry errd&!d anMty [NC 59t1 i;Cdulti Elm Unb RE MU P4L ARM Method Auahlsed !£IL 11211111 Biochemical Oxygen Demand^ 13 mg/L 1 2.0 2.0 705009 SM 521OB-2001 03/15/17 13:27 JOC Chemical Oxygen Demand" 41 mg/L 1 10 10 7C20018 SM 5220D-1997 03/20/17 18:08 30C Nitrate as N [34797-55-8]^ 0.16 mg/L 1 0.025 0.10 7C22020 EPA 353.2 03/22/17 12:19 JU Nitrate/Nitrite as NA 0.16 mg/L 1 0.041 0.10 7C21004 EPA 353.2 03/21/17 13:28 JU Nitrite as N [14797-65-0]^ 0.017 U mg/L 1 -0,017 0.10 7C15020 EPA 353.2 03/15/17 13:02 JU Phosphorus[7723-14-0]^ 0.025 U mg/L 1 0.025 0.10 7C16006 EPA 365.4 03/20/17 I.L22 JLl Total Vjeldahl Nitrogen^ 0.60 mg/L 1 0.26 0.48 7C16005 EPA 351.2 03/20/17 10:26 JU Total Suspended Solids^ 2.S U mg/L 1 2.5 2.5 7C20002 SM 254OD-1997 03/20/17 09:40 OMR FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 4 of 10 www.encolobs.com QUALITY CONTROL DATA Classlcal Chemistry Parameters - Quality Control Batch 7CI5009 - NO PREP Blank (7C15009-81.91) Prepared & Analyzed: 03/15/2017 13:27 Spike Source %REC RPD Ana hde Result Elan INIX UnIl Level Rat %REC Limits RPD Limit Notn Biochemical Oxygen Demand 2.0 U 2.0 mg/L B-03 LCS (7C15009-051) Prepared & Analyzed: 03/15/2017 13:27 Spike Source %REC RPO Ana llde Reed Elan PQL uAlu Leval Resin %REC Limits RPD Limit Notes Biochemical Oxygen Demand 170 2.0 mg/L 198 85 85-115 Duplicate (7C35009-DUPI) Prepared IN Analyzed: 03/15/2017 13:27 Source: CZ1676a-01 Spike Source %REC RPD Ana hrte Result an PQL llnitt Level Resul %REC Limits RPD Limit Notes Biochemical Oxygen Demand 6.3 2.0 mg/L 6.4 2 30 Duplicate (7C15009-DU112) Prepared & Analyzed: 03/15/2017 13:27 Source: a16769-02 Spike Source %REC RPD Ana lYte Resin Elao P.QL units Level Result %REC Limits RPD Limit Notes Biochemical Oxygen Demand 11 2.0 mg/L 11 DA 30 Betdr 7CI5020 - NO PREP Blank (7C35020-BLK1) Prepared; 03/15/2017 12:48 Analyzed: 03/15/2017 12:48 Spike Source %REC RPD Ana hde Result HZI EQL units Level Result %REC Limits RPD Limit �igypg Nitrite as N 0.017 U 0.10 mg/L LCS (7C25020-BS1) Prepared: 03/15/2017 1 2: 39 Analyzed: 03/15/2017 12:39 Spike Source %REC RPD AOaI]da Result an P41 Units Level Rat %REC Limits RPD Limit Notes Nitrite as N 0.96 0.10 mg/t 1.00 96 9D-110 Matrix Spike (7C15020-MS1) Prepared: 03/15/2017 12:49 Analyzed: 03/15/2017 12:49 Source: CA03754-01 Spike Source %REC RPD Anal Result flea PM Uzi= Level Rejul %REC Limits RPD Limit Notes Nitrite as N 0.93 0.10 mg/L 1.00 0.017 U 93 90.110 Matrix Spike Dup (7C15020-MSD1) Prepared: 03/15/2017 12:52 Analyzed: 03/15/2017 12:52 Source:CA03754-01 Spike Source %REC RPD Ana lYte Result Elan RQL Units Level Result %REC Limits RPD Limit Not" Nitrite as N 0.92 0.10 mg/L 1.00 0,017 U 92 90-110 2 10 Betdi 7CI6005 - Same Blank (7C36005-BLK3) Prepared: 03/16/2017 11:55 Analyzed: 03/20/2017 0926 Spike Source %REC RPD Ana 4rte Result Haa EM Lifi to Level Riesutt %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 0.26 U 0.48 mg/L FINAL This report relates only to the sample as received by the laboratory, and may only to reproduced In full. Page 5 of 10 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 7CI6005 - same - Continued LCS (7C16005-BS1) Prepared: 03/16/2017 11:55 Analyzed: 03/20/2017 09:28 Spike Source %REC RPD Ana 4ltp Result an F9L units Level Ulm, t %REC Limits RPD Limit Nefts Total Kjeldahl Nitrogen 12 0.48 mg/L 11.9 101 90-110 Matrix Spike (7C16005-MSi) Prepared: 03/16/2017 11:55 Analyzed: 03/20/2017 09:30 Source: CA01544-02 Spike Source %REC RPD -Anandn Result Elm PQL Units Level Result %REC limits RPD Limit Not"_ Total Kjeldahl Nitrogen 8.4 0.48 mg/L 4.75 3.5 103 90-110 Matrix Spike (7C16005-MS2) Prepared: 03/16/2017 1I:55 Analyzed: 03/20/2017 09:39 SourcesCAD1310-01 Spike Source %REC RPD Ana lldo Result RM PQL ti0lts Level Result %REC Nmlts RPO Llmlt Notes Total Kjeldahl Nitrogen 31 D 0,96 mg/L 435 28 65 90-110 QM-07 Matrix Spike Dup (7C16005-MSDi) Prepared: 03/16/2017 11:55 Analyzed: 03/20/2017 09:35 Source: CA01644-02 Spike Source %REC RPD Ana htte Result Elm ML Unia Level Result %REC Limb RPD Limit Notes - Total Kjeldahl Nitrogen 8.2 0.48 mg/L 4.75 3,5 98 90-110 3 10 Batch 7117-16006 - same Blank (7C36006-BLK1) Prepared: 03/16/2017 11:55 Analyzed: 03/20/2017 10:59 Spike Source %REC RPD Ana hde Reach Elan PQL !knits Level BeSult %REC Limits RPD Limit Notes Phosphorus 0.025 U 0.10 mg/L LCS (7C16006-051) Prepared: 03/16/2017 11:55 Analyzed: 03/20/2017 11:01 Spike Source %REC RPD Ana hds Result Flag PQL !units Level Result %REC Limits RPO limit Jyotn Phosphorus 1.6 0.10 mg/L 1.60 100 80-120 Matrix Spike (7C16006-MS1) Prepared: 03/16/2017 11:55 Analyzed: 03/20/2017 11:02 Source: CA01644-02 Spike source %REC RPD Ana Result Elan MI. Units Level Besult %REC limits RPD Limit flout Phosphorus 2.0 0.10 mg/L 0.640 1.2 118 80-120 Matrix Spike Dup (7C16006-MSD1) Prepared: 03/16/2017 M55 Analyzed: 03/20/2017 11:06 Source: CA01644-02 Spike Source %REC RPD Ana hda Result Has POL shire Level Result %REC Limits RPD Limit Moto Phosphorus 2.0 0,10 mg/L 01640 1.2 113 80-120 2 25 Botch 7C2Oi702 - NO PREP Blank (7C20002-BLKL) Prepared & Analyzed: 03/20/2017 09:40 Spike Source %REC RPD Ana hds Result Flag PQL finite Level BeSY1t %REC Limits RPD Limit Mobat Total Suspended Solids 2.5 U 2.5 mg/L FINAL This report relates only to the sample as receNed by the laboratory, and may only he reproduced In full. Page 6 of 10 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry parameters - Quality Control Batt* 7C20001- NO PREP - Continued LCS (7C20002-BSI) Prepared & Analyzed: 03/20/2017 09:40 Spike Source %REC RPD Anailrra Result an PQL Units Level Sesult %REC limits RPD Limit 119ws Total Suspended Solids 98 2.5 mg/L 100 98 BD-120 Duplicate (7C20002-DUP1) Prepared & Analyzed: 03/20/2017 09:40 Source; CA01292-01 Spike Source %REC RPD Ana hde Result Fleq P_QL units Level Result %REC Limits RPD Limit Notes_ Total Suspended Solids 99 33 mg/L 110 11 20 Duplicate (7C20002-DUP2) Prepared & Analyzed: 03/20/2017 09:40 Source: CA03877-01 Spike Source %REC RPD Ann hdo Resin Elan POL Units Level Result %REC Limital RPD Lima Notes Total Suspended Solids 260 33 mg/L 260 3 20 Bauch 7C20018 - Same Blank (7C2001"LKI) Prepared: 03/20/2017 14:21 Analyzed: 03/20/2017 18:08 Spike Source %REC RPD Anehde Resu1L Bag Pal. Units Level Result %REC Limits RPD Limit Nogg Chemical Oxygen Demand 10 U 10 mg/L LCS (7C20018-BSI) Prepared: 03/20/2017 14:21 Analyzed: 03/20/2017 18:08 Spike Source %REC RPb ADandzs Result Hag M Unm Level Result 0/aREC Limits RPD limit Notes Chemical Oxygen Demand 500 10 mg/L 500 100 90-110 Matrix Spike (7C20018-MSI) Prepared: 03/20/2017 14:21 Analyzed: 03/20/2017 18:08 Source: CA02355-02 Spike Source 0/aREC RPD Anetfde Result Bag PM Units Level Resul %REC Limits RPD Limit !Totes Chemical Oxygen Demand 580 10 mg/L 526 54 100 90-110 Matrix Spike Dup (700(III&MSDi) Prepared: 03/20/2017 14:21 Analyzed: 03/20/2017 18:08 Source: CA02355412 Spike Source %REC RPD AnatddLa Result flag EQL Units Level Result %REC Limits RPD limit Notes Chemical oxygen Demand 590 10 mg/L 526 54 101 90-110 2 10 Betch 7C21003 - NO PREP Blank (7C21003-BLK1) Prepared: 03/21/2017 11:17 Analyzed: 03/21/2017 11:17 Spike Source %REC RPD Ann hde Result Bag ML Uhlb Level Result %REC Limited RPD Limit NRIN Nitrate/Nitrite as N 0.041 U 0.10 mg/L LCS (7C21003-BS1) Prepared: 03/21/2017 11:15 Analyzed: 03/21/2017 11:15 Spike Source %REC RPD ADalYfie Result Hag e41 Units Level Result %REC Llmlts RPD Limit Notes Nitrate/Nitrite as N 1.3 0.10 mg/L 1.25 106 90-110 FINAL This report relates only to the sample as received by the laboratory, and mayonly be reproduced In full. Page 7 of 1C CS Nkkl s i www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 7C21O03 - NO PREP - Condnged Matrix Spike (7C21003-MS1) Prepared; 03/21/2017 11:19 Analyzed: 03/21/2017 11:19 Source: CA01362-01 Spike Source %REC RPD Ananda Result Elan PDL MIA Level Resu(t %REC Limits RPD Limit Notes Nitrate/Nitrite as N 160 10 mg/L 50.0 110 111 90-110 QM-07 Matrix Spike (7C21003-MS2) Prepared: 03/21/2017 1L33 Analyzed: 03/21/2017 11:33 Source: CA01644-02 Spike Source %REC RPD Anal lda Result Hag P_OL Units Level RCSA %REC Limits RPD Llmlt Notes Nltrate/Nitrite as N 18 1.0 mg/L 5.00 14 76 90-110 QM-07 Matrix Spike Dup (7C21003-MSD1) Prepared: 03/21/2017 11:28 Analyzed: 03/21/2017 11:28 Source: CA01362-01 Spike Source %REC RPD Ana hda Resit fho QOL Uriffa Level Rem %REC Limits RPD Llmlt Notes Nitrate/Nitrite as N 170 10 mg/L 50.0 110 130 90-110 6 10 QM-07 Balrli 7C21004 - NO PREP Blank (7C21004-51.11(1) Prepared: 03/21/2017 13:09 Anayzed: 03/21/2017 13:09 Spike Source %REC RPD Ana lYtA Result Hag eal. Unfts Level Result %REC Llmlta RPD Llmlt Notes Nitrate/Nitrite as N 0.042 U 0.10 mg/L LCS (7C23004-BSL) Prepared: 03/21/2017 13:11 Analyzed: 03/21/2017 13:11 Spike Source %REC RPD Anal Result Result lice P.f71 Units Level $Ds& %REC Limits RPD Llmlt Nabn Nitrate/Nityke as N 1.1 0.10 mg/L 1.25 90 90-110 Matrix Spike (7C21004-1I51) Prepared: 03/21/2017 13:17 Analyzed: 03/21/2017 13:17 Source: CA01308-01 Spike Source %REC RPD ADa4da Resit flag POL Unlfa Level Result %REC Limits RPD Llmlt Notes Nitrate/Nitrite as N 0.53 0.10 mg/L 0.513 0.041 U 104 90-110 Matrix Spike (7C21004-MS2) Prepared: 03/21/2017 13:26 Analyzed: 03/21/2017 13:26 Source: CA01310.01 Spike Source %REC RPD Anal ld0 Result 19;1g Eal. Units Level Rusin %REC Unift RPD LEmEt Notes Nitrale/Nitrite as N 0.62 0.10 mg/L 0.513 0.093 102 90-110 Matrix Spike Dup (7C21004-MSD3) Prepared: 03/21/2017 13:22 Analyzed: 03/21/2017 13:22 Source: CA01309-01 Spike Source %REC RPD Ana hd0 Result flag RQL hails ' Level Resin %REC QUM RPD Limit Notes Nitrate/Nitrite as N 0.51 0,10 mg/L 0.513 0.041 U 99 90.110 5 10 FINAL This report relates only to the sample as receNed by the laboratory, and may only be reproduced in lull. Pape a of 10 www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. I The reported value is between the laboratory method detection limit (MDQ and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quandtation limit (PQQ and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. B-03 Blank exceeds the method required oxygen depletion of <0.20 mg/L. QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. FINAL This report reiates only to the sample as received by the laboratory, and may only be reproduced In full. Page 9 of 10 , Lf\ft/1ys�lntl\1ML a.+<.are\.yC17tMeeV1\LMOVRl�1 Ve11CJ V.'1W�iR/rti�IJ�VY■ nC4.InLP www.m'mumus-com 70M Central Part Dr. 4e10 EmKm p Park Court. Sufp 111 102-A Wboamn$ bxbxaug CL Orbndq FL 32W4 .hd®ooriaa, FL 32216.6069 Cary. NC 27511 j (4M CM-014 Feu (407) 850-OM (904) 2W3oW7 Fax (W4) 29G-W10 (919) 467-MM Fla (919) 4673515 Page --L ut F C W Name Praod Number Reg Requested Turrlarow' d Times obis :Rush requests strbjert to �'""' '' _. Standard Expedited Due �/ 1 1 m � N f/) ❑ O CD ❑ N N S� ❑ v Cy 2 " U m � (V c� Z m � . r LID Z Y i- C% tt7 X O C] � 2 Addr= - 77 P Che el Church Road Pr*d NanelDem StonTwater Testi CeyrS'rizo Franklinton, NC 27525 PO e 1 S&V bdo - 38=45169 Tel - - Fax 494-•3370, Reporting Cord- Joe Ladd �NamA allrliabanpa,a,v j T-t'c� +oAccaf.+rsts Payable saverW sft�� ► T-ww Zane r► l� f Lab wor► order Lab CZ 19517 (Sm CZadmi (Comomb= as rmomwy) Item. . Smos IQ (Feld ► CaoecM n Date cafoaion Time Carp 1 Grab MOO (see miles) Total. at Corlfaems sampEe Commelsts < Total # of Containers j 6enpb Kit Prepared 6y DalelTere ey DatJfffm Received By 1 DaWfn >a � gad A ti P H: G -6 RmmiwW By o�teirime HebuMshed ey Date/lime Received By 4atlwTv r Coder 4k & TonVs on Receipt r 9' #r Condtio/Ups RooW V zptable UnaocepMMe Mgtdx: GW4'arotx GG-OW DW-Ddneing Wow SE•5ed&nad 5W-SUdweV6Ww WW-V:azUw&W A•Ar 0400 r(deW in con nw4s) Pmadratlac Mm H•HCI N+9403 "M04 MO-NaOH-O-Oftt jd" it�rrpr>ads) Note : AN sanWi s submdhed to ENCO Lake we in awardarxe w M the brass aril mrlQdi m lftd an the mvem d this form. {mess pdm wrillen aWeE nwo mW Sample Preservation Verification ENCO Cary C Work Order: CZ19517 Project: Stormwate_r Testing Client: Novozymes North America (NO008) Project #: [none] Logged In: 15-Mar-17 08:19 Logged By: John C King CZ19517-01 Cont type Pres (pH ., Re uirement pH Checked i In Controt . D.at ime pHAdjusted. `Adjusted i ReagentUsedlCamrttents { D 250mLP+H2SO4 <2 / N! NA Y I C1 NA E 250mLP+H2SO4 <2 ! N I NA Y I 0 ! NA CZ19517-02 Cont Type Pres (pH) Requirement p Checked In Control' • .. ate me pH Adjusted; 'Adjusted Reagent;Used1comments.. D 250mLP+H2SO4 <2 / N / NA Y ! / NA E 25OmLP+H2SO4 <2 I N ! NA Y / ! NA Rea ent Name ID 1 2 Rea ent Name ID 3 4 Reagent Name ID 5 6 Page 1 o Date: March 1, 2017 Novozymes, NA Inc. 77 Perry's Chapel Church Rd. Franklinton, N.C. 27525 NC DEQ Division Of Water Quality 1617 Mail Service Center Raleigh, N.C. 27699-1617 Attn: Division Of Water Quality Storm Water Sampling, NPDES Permit. o. NCS000115 Dear Sir/Madam novozymesm Rethink Tomorrow RECEIVED APR 10 2017 CENTRAL FILES DWR SECTION Per our Tier Two requirements, regarding the exceeded benchmark in Chemical Oxygen Demand, (COD) and Biological Oxygen Demand (HOD), our implementation of a monthly monitoring in area of concern, "Outfall 2", beginning in January has resulted in "No Flow" for the month of February. We therefore were unable to collect a sample for this month. We plan to continue to diligently with our monthly monitoring for the parameters of COD and BOD until we obtain three consecutive sample results within the benchmark range. Kind Re VIV Joe Ladd Environmental Compliance Coordinator Environmental Services RECEIVED APR o 5 2017 DENR-LAND QUALITY STORMWATER PERMITTING Date: March 1, 2017 Novozymes, NA Inc. 77 Perry's Chapel Church Rd. Franklinton, N.C. 27525 NC DEQ Division Of Water Quality 1617 Mail Service Center Raleigh, N.C. 27699-1617 Attn: Division Of Water Quality Storm Water Sampling, NPDES Permit o. NCS000115 Dear Sir/Madam novozY mes° Rethink Tomorrow Per our Tier Two requirements, regarding the exceeded benchmark in Chemical Oxygen Demand, (COD) and Biological Oxygen Demand (BOD), our implementation of a monthly monitoring in area of concern, "Outfall 2", beginning in January has resulted in "No Flow" for the month of January. We therefore were unable to collect a sample for this month. We plan to continue to diligently with our monthly monitoring for the parameters of COD and BOD until we obtain three consecutive sample results within the benchmark range. Kind Regards- 9/4 1 �4 Joe Ladd Environmental Compliance Coordinator Environmental Services ls JNI�1Wdf1V GNV �INBG LICZ L 0 W a3n1305*8 CO Laboratories Accurate. Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary Nc, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Tuesday, December 20, 2016 Novozymes North America (N0008) Attn: Joe Ladd 77 Perry Chapel Church Road Franklinton, NC 27525 RE: Laboratory Results for Project Number: (none], Project Name/Desc: Stormwater Testing ENCO Workorder(s): CZ17991 Dear Joe Ladd, N GS D Enclosed is a copy of your laboratory report for test samples received by our laboratory on Wednesday, December 7, 2016. Unless otherwise noted in an attached project narrative, all samples were received In acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Stephanie Franz For Chuck Smith Project Manager Enclosure(s) RECEIVED JAN 2 0 2017 CENTRAL FILES DWR SECTION FIMAL This report relates only to the sample as receNed by the labmsbory, and may only be reproduced In hull, I Page 1 of 1 1 1 q) Ce NS a! w www.encolabs.com SAMPLE SUMMARY/ LABORATORY CHRONICLE CllentID: OuftliI Lab ID: CZ17991-01 Sampled: 12/06/1613:30 Received: 12/07/1607:15 ParametaC EPA 351.2 Hald Date/Tlme(sI 01/03/17 Prep DateITlmefsl 12J08/16 10:10 Analysis Date/Time(s) 12/13/16 OX EPA 353.2 12/08/16 13:30 12/07/16 14:57 12/07/16 15:59 EPA 353.2 01/03/17 12/16/16 07:54 12/16/16 10:37 EPA 353.2 09/01/19 12/16/16 14a6 12/16/16 14:16 EPA 365.4 01/03/17 12/08/16 10:10 12/13/16 14:32 SM 2-WD-1997 12/13/16 12/12/16 09:00 12/12/16 09:00 SM 521OB-2001 12/08/16 13:30 12/07/16 14:19 12/07/16 14:19 SM 5220D-1997 01/03/17 12/13/16 10:48 12/13/16 1510 Client ID: WWI 2 Lab ID: CZ17991-02 Sampled: 12/06/16 14:40 Received: 12/07/16 07:25 Parameter EPA 351.2 Hold Date/Tlme(e) 01/03/17 Prep DateITlmefsl 12/08/16 10:10 Analysis DateMmefsl 12/13/16 13:35 EPA 353.2 12/08/16 14:40 12/07/16 14:57 12/07/16 16:02 EPA 353.2 01/03/17 12/20/16 07:57 12/20/16 10:22 EPA 353.2 09/01/19 12/20/16 1130 12/20/16 13:43 EPA 365.4 01/03/17 12/08/16 10:10 12/13/16 14:34 SM 254OD•1997 12/13/16 12/07/16 13:00 12/07/16 13:00 SM 521OB-2001 12/08/16 14:40 17J07/16 14:19 12/07/16 14:19 SM 522013-1997 01/03/17 12/13/16 10:48 12/13/16 15:10 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 2 Of 'I www.encolabs.com ANALYTICAL RESULTS Description: Outfall 1 Lab Sample ID: CZ1799 1-01 Received: 12/07/16 07a5 Matrix; Surface Water Sampled:12/06/16 13:30 Work Order: CZ17991 Project: StonnwaterTesting Sampled By. -Joe Ladd Classical Chemistry Parameters ^ - EAM Lary [e U&,d analyle [AC 5911 flag ynb 2E MU PQL 1= Method Analyzed �][ Biochemical Oxygen Demand^ 3.0 mg/L 1 2.0 2,0 6LO7025 SM 521OB-2001 12/07/16 14:19 10C 0-07 Chemical Oxygen Demand^ 30 mg/L 1 10 10 61.13013 SM 522OD-1997 12/13/16 15:10 30C Nitrate as N [14797-55-B]^ 0.57 mg/L 1 0,025 0.10 61.16034 EPA 353.2 12/16/16 14:16 IL) Nltrate/Nltrite as N^ 0.59 mg/L 1 0.041 0.10 6L16008 EPA 353.2 12/16/16 10:37 JU Nitrite as N [14797-65-0]^ 0.018 3 mg/L 1 0.017 0.10 6LO7006 EPA 353.2 12/07/16 15:59 31-3 Phosphorus [7723-14-0]^ 0.24 mg/L 1 0.025 0.10 61-08006 EPA 365.4 12/13/16 14:32 ILI Total K161dahl Nitrogen^ 0.89 mg/L 1 0.26 0.48 6LO8005 EPA 351.2 12/13/16 13:33 ILI Total Suspended Solids^ 30 mg/L 5 12 12 6L12003 SM 2SQD-1997 12/12/16 09:00 MMR Description: Outfall 2 Lab Sample ID: CZ17991-02 Received: 12/07/16 07:15 Matrix: Surface Water Sampled.12/06/16 14:40 Work Order: CZ17991 Project: StormwaterTesting Sampled By: Joe Ladd Classical Chemistry Parameters ^ - &,C0 Cary c&VAed anaryre [NC 5911 Anahrte rCAS Numberl Results Elm mob 2E HU PQL RaUh Hadlod Analyzed gy Raw Biochemical Oxygen Demand- 33 mg/L 1 2.0 2.0 6LO7025 SM 521OB-2001 12/07/16 14:19 30C B-07 Chemical Oxygen Demand^ 130 mg/L 1 10 10 6L13013 SM 5220D-1997 12/13/16 15:10 J0C Nitrate as N (14797-55-B]^ 0.19 mg/L 1 0.025 0.10 6L20028 EPA 353.2 12/20/16 13:43 JU Nitrate/Nitrite as N^ 0.19 mg/L 1 0.041 0.10 6L20003 EPA 353.2 12/20/16 10:22 JU Nitrite as N [14797-65-0]^ 0.017 U mg/L 1 0,017 0.10 61LO7006 EPA 353.2 12/07/16 16:02 3L3 Phosphorus [7723-14-0]^ 0.11 mg/L 1 0.025 0.10 6LOS006 EPA 365.4 12/13/16 14:34 310 Total I(jeldahl Nitrogen^ 2.2 mg/L 1 0.26 0.48 6LO8005 EPA 351.2 12/13/16 13:35 3L3 Total Suspended Solids^ 13 mg/L 4 t0 30 6L07003 SM 254OD-1997 12/07/16 13:00 MMR FINAL This report relates only to the sample as receKmd by the laboratory, and may only be reproduced In fuel, Page 4 Of 11 www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: Outfall 1 Lab ID: CZ17992-01 Anatyte Results H92 MU E" lhliLa Martbod Notes Biochemical Oxygen Demand 3.0 2.0 2.0 mg/L SM 521OB-2001 B-07 Chemical Oxygen Demand 30 10 10 mg/L SM 5220D-1997 Nitrate as N 0.57 0.025 0.10 mg/L EPA 353.2 Nitrate/Nitrite as N 0.59 0.041 0.10 mg/L EPA 353.2 Nitrite as N 0.018 1 0.017 0.10 mg/L EPA 353.2 Phosphorus 0.24 0.025 0.10 mg/L EPA 365.4 Total Kjeldahl Nitrogen 0.89 0.26 0.48 mg/L EPA 351.2 Total Suspended Solids 30 12 12 mg/L SM 2WD-1997 Client ID: outfall 2 Lab ID: CZ17991-02 AgA1Yl:C RUMIM E109 Hu M !l11ltIF Mt1t1t9d Notes Biochemical Oxygen Demand 33 2.0 2.0 mg/L SM 521OB-2001 B-07 Chemical Oxygen Demand 130 10 10 mg/L. SM 5220D-1997 N Itrate as N 0.19 0.025 0.10 mg/L EPA 353.2 Nitrate/Nitrite as N 0.19 0.041 0.10 mg/L EPA 353.2 Phosphorus 0.11 0.025 0.10 mg/L EPA 365.4 Total Kjeldahl Nitrogen 2.2 0.26 0.48 mg/L EPA 351.2 Total Suspended Solids 13 10 10 mg/L SM 254OD-1997 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced 0 full. I Page 3 Of 'I www.encolabs.com QUALITY CONTROL. DATA Classical Chemistry parameters - Quality Control Batch 6L07003 - NO PREP Blank (6L07003-BLKi) Prepared & Analyzed: 12/07/2016 13:00 Spike Source %REC RPD Anahft Result ElaO POL Units Level get %REC Limps RPD Lump Notes Total Suspended Solids 2.5 u 2.5 mg/L LCS (61.07003-111SI) Prepared & Analyzed: 12/07/2016 13:00 Spike Source %REC RPD Anal Result Elm PQL Units Level get %REC Limns RPD Limit Notes Total Suspended Solids 100 2.5 mg/L 100 100 80-120 Duplicate (6L07003-DUP3) Prepared & Analyzed: 12/07/2016 13:00 Source: CZ07886-01 Spike Source %REC RPD Anal Result Elag P" Units Level Result %REC limits RPD Limit Notes Total Suspended Solids 110 33 mg/L 110 0 20 Duplicate (6L07003-DUP2) Prepared & Analyzed: 12/07/2016 13:00 Source: CZ16257-01 Spike source %REC RPD Anal wa Result Elm ML Units Level get %REC Limits RPD LiIDlt !!Notes_ Total Suspended Solids 450 71 mg/L 370 17 20 Batch 6107006 - NO PREP Blank (61.07006-81.1(i) Prepared: 12/07/2016 07:39 Analyzed: 12/07/2016 09:33 Spike Source %REC RPD Ana hrta Result ew EQL units Level Result %REC Limits Rpo Limit Jg Nitrite as N 0.017 U 0.10 mg/L LCS (61.07006-851) Prepared: 12/07/2016 07:39 Analyzed: 12/07/2016 09:46 Spike Source %REC RPD AnaResult HM EQL Units Level Result %REC Limits RPD Limit Flours_ Nitrite as N 0.98 0.10 mg/L 1.00 98 90.110 Matrix Spike (61.07006-MS1) Prepared: 12/07/2016 07:39 Analyzed: 12/07/2016 09:34 Source: CZ17398-01 Spike Source %REC RPD Anatfrilz Result Elm EQL UnlU Level gesy(t %REC Limits RPD umill Notes Nitrite as N 0.97 0.10 mg/L 1.00 0.049 92 90.110 Matrix Spike (61.07006-M52) Prepared: IW07/2016 07:39 Analyzed: 12/07/2016 16:01 Source: CZ17991-01 Spike Source %REC RPD Ana 6rse Result Ilag EQL Units Level gesult %REC Limits RPD Limit Notes Nitrite as N 0.92 0.10 mg/L 1.00 0.018 90 90-I10 Matrix Spike Dup (61.07006-MSDL) Prepared: 12/07/2016 07:39 Analyzed: 12/07/2016 09:37 111 Source: CZ27398-01 ADand® Nitrite as N Batch 6LO7025 - NO PREP Spike Source %REC Result Elm P01 Units Level Result %REC Limps RPD 0.99 0.10 mg/L 1.00 0.049 95 90-110 2 RPD Limit Notes 10 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 5 Of 11 (9 �Ew' www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Battle 6LO7025 - NO PREP - Conf lnntred Blank (6L07025-BLK1) Prepared & Analyzed: W0712016 14:19 Spike Source %REC RPO Anal r Result Flea POL UnRs Level Result %REC Limits RPD Limit Notes Biochemical Oxygen Demand 2.0 U 2.0 mg/L LCS (6L07025-0S1) Prepared & Analyzed: 12/07/2016 14:19 Spike Source a/oREC RPD Anande, Result Elan POL UnFts Level Result %REC Urnits RPD Limit Notes - Biochemical Oxygen Demand 130 2.0 m91L 198 68 85-115 B-07 Duplicate (GL0702S-DUP1) Prepared & Analyzed: 12/07/2016 14:19 Source: CZ15428-01 Spike Source %REC RPD Ana tlta Result flag POL Smite Level Result %REC Limits RPD Limit Notes_ Biochemical Oxygen Demand 160 2.0 mg/L 140 ' 7 30 B-07 Batch 6L08005 - Some Blank (611.08005-BLKl) Prepared: 12/08/2016 10:10 Analyzed: 12/13/2016 10:52 Spike Source %REC RPD AndSYte Result Elm POL Unitf Level Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 0.26 U 0,48 mg/L LCS (61.08005-BS1) Prepared: 12/DS/2016 10:10 Analyzed: 12/13/2016 10:54 Spike Source %REC RPD Ana htLo Result Hd0 POL unb Level Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 12 0.48 mg/L 11.9 99 90-110 Matrix Spike (6L08005-MS1) Prepared: 12/08/2016 10:10 Analyzed: 12/13/2016 10:57 Source: CZ17389-01 Spike Source %REC RPD Ann i]de Result i3eaq POL Units Level Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 4.9 0,48 mg/L 4.75 0.88 84 90-110 QM-07 Matrix Spike (61.08005-MS2) Prepared: 12/08/2016 10:10 Analyzed: 12/13/2016 11:10 Source: CZLS428-01 Spike Source %REC RPD AnalStlD Result on PUL units Level Result %REC Limits RPD Limit Notn Total Kjeldahl Nitrogen 130 D 4.8 mg/L 4,75 120 137 90-110 QM-07 Matrix Spike Dup (61.08005-MSDi) Prepared: 12/08/2016 10:10 Analyzed: 12/13/2016 11:01 Source; CZ17369-01 Spike Source %REC RPD Ann Result Elm POL unite Level Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 5.0 0.48 mg/L 4.75 0.88 87 90.110 3 10 QM-07 Battle 6LOB006 - Same Blank (611.08006-BLKL) Prepared: 12/08/2016 10:10 Analyzed: 12/13/2016 12:45 Spike Source %REC RPD Ana 4tta Result Elm POL Unb Level Result %REC Limits RPD Limit Notes Phosphorus 0.025 U 0.10 mg/L ANAL This report relates only to the sample as receNad by the laboratory, and may only be reproduced in U. I Page 6 Qf 11 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 6108005 - Same - Continued LCS (61.08006-B51) Prepared: 12/08/2016 10:10 Analyzed: 12/13/2016 12:46 Spike Source %REC RPD Ana hde Result Hag F!QL UrI tf Level Result %REC LiMig RPD Limit Notes Phosphorus 1.6 0.10 mg/L 1.60 98 80-120 Matrix Spike (6108006-MS1) Prepared: 12/08/2016 10:10 Analyzed: 12/13/2016 12:48 Source: CZ17389-01 Spike Source %REC RPD Anik Result ENM ML Unite Level Result %REC Limits RPD Limit !Votes Phosphorus 4.5 D 0.50 mg/L 0,640 4.0 90 80.120 Matrix Spike Dup (61.08006-MSD1) Prepared: 12/08/2016 10:10 Analyzed: 12/13/2016 12:51 Source: CZ17389-01 Spike Source %REC RPD Ana Result Hag PAL Units Level Resu1i %REC Limits RPD Limit Notes Phosphorus 5.0 D 0.50 mg/L 0.640 4.0 167 80-120 10 25 QM-07 Batt* 6L12003 - NO PREP Blank (6L12003-Ba~Kl) Prepared & Analyzed: 12/12/2016 09:00 Spike Source %REC RPD Anal 1Re Result Hag PQL Units Level Result %REC Limits RPD LIIDR Notes Total Suspended Solids 2.5 U 2.5 mg/L LCS (61.12003-851) Prepared IN Analyzed: 12/12/2016 09:00 Spike Source %REC RPD 80a Result Hen Poll. Lmb Level 1esult %REC Limits RPD Limit Notes Total Suspended Solids 92 2.5 mg/L 100 92 80-120 Duplicate (61-12003-DUP3) Prepared & Analyzed: 12/12/2016 09:00 Source: CZ07895-01 Spike Source %REC RPD Anal !!ta Result Elm PQL Units Level Ressiit %REC Limits RPD Limit Notes Total Suspended Solids 59 17 mg/L 61 ' 2 20 Duplicate (6L12003-DUP2) Prepared & Analyzed: 12/12/2016 09M Source: CZ07895-02 Spike Source %REC RPD Ana Result Hag M Units Level Result %REC Limits RPD Limit Notes_ Total Suspended Solids 87 25 mg/L 93 7 20 Ba" 6L13013 - some Blank (61.13013-111M) Prepared: 12/13/2016 10:48 Analyzed: 12/13/2016 15:10 Spike Source %REC RPD Ana hde Result Hag P41 Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 10 U 10 mg/L LCS (6L13013-BSI) Prepared: 12/13/2016 10:48 Analyzed: 12/13/2016 IS: 10 Spike Source %REC RPD Anal lft8 Result Hag PQL Units Level Besult %REC Limits RPD Limit Notes Chemical Oxygen Demand 510 10 mg/L 500 102 90-110 FINAL This report relates only to the sample as reoeived by the laboratory, arid may only be reproduced In full, I Page 7 Of 14 www.eneolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 6L13013 - Some - Condbued Matrix Spike (61.13013-MSl) Prepared: 12/13/2016 10:48 Analyzed: 12/13/2016 15:10 Source: CZ15423-02 Spike Source %REC RPD Ana hd® Result Hoe PQL Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 550 10 mall. 526 41 97 90-110 Matrix Spike Dup (6L13013-MSDi) Prepared; 12/13/2016 10:48 Analyzed: 12/13/2016 IS! 10 Source: CZ15413-02 Spike Source %REC RPD .Ana ivtp Result Elm PM units Level Resin %REC LWIM RPD Llmlt Notes Chemical Oxygen Demand 580 10 mg/L 526 41 102 90.110 5 10 Batch 6116O08 - NO PREP Blank (6L16008-BLKl) Prepared: 12/16/2016 07:54 Analyzed: 12116/2016 10:01 Spike Source %REC RPD Gnat Result Hag Pal. Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 0.041 U 0.10 mg/L LCS (61.16008-BS1) Prepared: 12/16/2016 07:54 Analysed: 12/16/2016 09:59 Spike source %REC RPD Ana hda Result flan PQL knits Level Result %REC Llm& RPD Limit Notes Nltrate/NitriteasN 1.2 0.10 mg/L 1.25 99 90.110 Matrix Spike (61.16008-101SI) Prepared: 12/16/2016 07:54 Analyzed: 12116/2016 10:03 Source: CZ16370-01 Spike Source %REC RPD flllallrffi Resin Hall EQL Units Level Besult %REC LURE RPD Limit Notes Nitrate/Nitrite as N 11 1.0 mg/L 5.00 6.3 98 90-110 Matrix Spike (61.16008-M51) Prepared: 12/16/2016 07:54 Analyzed: 12/16/2016 10:12 Source: CZ17188-01 Spike Source %REC RPD Anal fine Result Fin PQL Units Level Result %REC Limits RPD Lima Notes Nitrate/Nitrite as N 96 10 mg/L 50.0 43 105 90-110 Matrix Spike Dup (61.36008-MS01) Prepared: 12/16/2016 07:54 Analyzed: 12/16/2016 10:07 Source: aL6370-01 Spike Source %REC RPD Anal Yte Result Flan EQL Units Level Besult %REC Lilillld RPD Limit Notes Nitrate/Nitrite as N 11 1.0 mg/L 5.00 6.3 94 90-110 2 10 Batch 6L20003 - NO PREP Blank (6L20003-BLKl) Prepared: 12/20/2016 07:57 Analyzed: 12/20/2016 10:09 Spike source a/oREC RPD Ana hde Res -it Else ROL Units Level Resul %REC Limits RPD Limit Notes Ntuate/Nitrite as N 0.041 U 0.t0 mg/L LCS (6L20003-BS1) Prepared: 12/20/2016 07:57 Analyzed: 12/20/2016 10:07 Spike Source %REC RPD Ana iYtB Result Fin PQL units Level Be5Y1t %REC Llmlta RPD Llmlt Notes NitmWfiitrite as N 1.2 0.10 mg/L 1.25 97 90.110 FINAL This report relates only to the sample as receMed by the laboratory, and may only be reproduced In full. I Page 8 0 11 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 6L20003 - NO PREP - Continued Matrix Spike (611.20003-4151) Prepared: W20/2016 07:57 Analyzed: 12/20/2016 10:11 Source: CZ17391-01 Spike Source %REC RPD AnaResult Sao PQL Units Level $erult %REC Limits RPD Limit Notes Nitrate/Nitrite as N 9.2 1.0 mg/L 5.00 3.8 108 90-110 Matrix Spike (6L20003-M52) Prepared: 12/20/2016 07:57 Analyzed: 12/20/2016 10:20 Source: CZ17395-01 Spike Source %REC RPD Anal sds Result Elaa i?QL units Level Result %REC LIB RPD Limit Mates Nitrate/Nitrite as N 37 5.0 mg/L 25.0 12 99 90-110 Matrix Spike Dup (6L20003-MSDi) Prepared: 12/20/2016 07:57 Analyzed: 12/20/2016 10:16 Source:CZIL7391-01 Spike Source %REC RPD Anands Result flan PDL llnita Level gesul%REC Limits RPD Limit Notes Wtrate/Nitrlte as N 8.9 1.0 mg/L 5.00 3.8 101 90-110 4 10 FINAL This report relates only to the sample as received by the laboratory, and may only be reGroduced In full. I Page 9 o www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the Instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. B-07 LCS exceeded control limits for this test. The test can not be repeated due to method constraints. The result should be considered an estimated value. QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. FINAL This report relates onry to the sample as recelved by the laboratory, and may onh' be reproduced in full. IPage 10 ci 11 ....... ..� ..v�......•v..�.-rs.+v..�. v.n�w v+�e+s.�-vs-�rv.a�%~s vItwtty WWW.Cf"A"OLib:LW:� i 10775 Cereal Part Dr. f 10 Pack Clot. Sedle 111 1132-A Waodrmrds kxkmmw CL 4 OdWIL96FL, 32824 .ladtSOMOO. FL 32210410fi9 Cary, NC 27511 (407) CS4314 Few (407) 8WHS94.5 (9M) 2%-30<f7 Fex (9M) 298.8210 , (919) 4U-3D90 Fax (919) 467-WI5 Page J_ .of r Prgep Nub - Rwqueatad Aaalysea Reque dad Turnaro 0 Times r NM : REMI Mq+ 4) mocepterme by ttm m 'Standard . Expedited . Due I I _ O �. < v) m. Q to U ca C V m - Z N Z w i.+ I Z CY �. CO Z C M M X I Z 0 cm 0) CO I 1W- Adds Chapel Church, Road Ptaiac! .. - Stormw E Testingchysrrr�p an nto 27525 Po. t � hdo . , -69 Ter 4 -3370 Frepon;,,q Caraao Jae Ladd Samplers) Name. Alfr7ntion (t}ruls) CorUa A1xat oils Payabie Saalpler(S) .$�!R rSi:e Localim% "1"iale Z07i9 -' tab Workorder Z1-} 9reswvatlar (Sea codes) (Carrearle as n-5-y) !no Sample ID (Feld IdenG6cation) CQ%x:bon Date Coeecbm Time Comp 1 Grab . Matrix (ma codes! Tatal a of Cardainers Sample Comments !/ /���C�7 ITYv <- Tote) # of Containers Swn;Av Kit Prepared BY ( -� DsietTime I ZZLOl Rebwp isned By DalatTm±e / R DaiaT CornF pl," Q[L�ii J ' - r f , Refal pahed By DsteTrme Relinquished ey Oat&TCM Racehwl By DatofTLna Coder fa 8 Temps on Receipl _ C Corrmtion I,lpm Receipt . ,—// A Urmccepmwe Umbilm : GW-Groundwow. St}Soi OW-DrkAdrg water SE•God'aaad SW-Surf=v wrier WW-Wastewater A-Alr 0-00wr (detail in COMM Rs): Prrarvatlom I -Ice IMCI N4iNO3 3-N25O4 N)6-MOh 0-0O er (deter In Lbrmrmm) Note: AS sarnpl9s sub"umW to ENGO Lets we in atzwdwv a with the mras atld cor.2bom Esmd on ft rmeme of V a lotto utYeU prior wrftn aproernests exist 4. Date: December 23, 2016 RECEIVED Novozymes, NA Inc. JAB 0 Z�17 77 Perry's Chapel Church Rd. Franklinton, N.C. 27525 CENTRAL FILES DWR SECTION NCDEQ Division Of Water Quality 1617 Mail Service Center Raleigh, N.C. 27699-1617 Attn: Division Of Water Quality Storm Water Sampling, NPDES Permit No. NCS000115 Dear Sir/Madam, novozymes• Rethink Tomorrow RECEIVED JAN 2 0 2011 CENTRAL FILES DWR SECTION During review of storm water sampling results, it was observed that there was an exceeded benchmark in Biological Oxygen Demand (BOD), and Chemical Oxygen Demand (COD) from our Outfall 2 location. This was the second exceedance in as many sampling events for BOD and COD. Upon immediate investigation, per Tier One requirements, it was discovered that although during sample event no signs of potential issues were present, the area approximately 20 yards from where samples are collected the combination of filtration systems not cleaned properly, the off-loading of raw materials along with containers of product that had been rinsed prior to being disposed have been considered direct cause of the recent exceeding of both BOD and COD benchmarks. Plans are in place to have personnel in area begin with cleaning filtration systems and more caution taken place while material is being handled, containers rinsed. Progress has been made reducing BOD and COD readings; however they were still not below benchmark standards. Therefore, per Tier Two requirements we will begin monthly monitoring of Outfall 2 until three consecutive sample results are below benchmark values. Continued monitoring by Environmental Services Department will take place in order to prevent future exceeded benchmarks in Biological Oxygen Demand (BOD), and Chemical Oxygen Demand (COD) from Outfall 2. Kind Re s, Joe Lad Environmental Compliance Coordinator Environmental Services RECEIVED JAN 2 0 2017 CENTRAL FILES DWR SECTION EFFLUENT NPDES PERMIT NO. NCS000115 DISCHARGE NO. FACILITY NAME Novozymes, NA Inc. CLASS OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA CERTIFIED LABORATORIES (1) Enco CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Mail ORIGINAL and ONE COPY to: �I (z) RECEIVED a. JAN 2 0 Zw17 CENTRAL. FILES DWR SECTION MONTH Decemer YEAR 2016 COUNTY: Franklin PHONE (919) 494-3001 Joe Ladd ATTN: CENTRAL FILES x NIA DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) 1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY RALEIGH, NC 27699-1617 KNOWLEDGE. LOL�L�LI•�L��L�t•�Ll•����L�L�r� L1I�7L1•�L��L�L����L��®��L�LI•r �L�L�L��L��L�L��LI•����L�L>•� Lml�l�l��l��l���l�r���l�l>•� L®�L�LI•�L���L��t•����L�L�� DWQ Form MR-] (11/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) Compliant All monitoring data and sampling frequencies do NOT meet permit requirements Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.6 of the NPDES permit. "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Randv Green Permittee (Please print or type) �-2. S' a P ittee*** Date (Required u ss submitted electronically) Permittee Address Phone Number e-mail address Permit Expiration Date Certified Laboratory (2) Certified Laboratory (3) ADDITIONAL CERTIFIED LABORATORIES Certification No. Certification No. Certified Laboratory (4) Certification No. Certified Laboratory (5) Certification No. PARAMETER CODES Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enrstate.nc.uslwas and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. *** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 2B .0506(b)(2)(D). Page 2 EFFLUENT NPDES PERMIT NO. NCS000115 DISCHARGE NO. 2 FACILITYNAME NOVOZymeS, NA Inc. CLASS OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA CERTIFIED LABORATORIES (1) Enco (2) CHECK BOX IF ORC HAS CHANGED PERSON($) COLLECTING SAMPLES Mail ORIGINAL and ONE COPY to: RECEIVED AN 2 0 2017 CENTL FILES DWR SECTION MONTH Decemer YEAR 2016 COUNTY: Franklin PHONE (919) 494-3001 Joe Ladd ATTN: CENTRAL FILES x NIA DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) 1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY RALEIGH, NC 27699-1617 KNOWLEDGE. �wm��mlm� mcm DWQ Form MR-1 (11/04) Facility Status: (Please check one of the following) J All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) Compliant All monitoring data and sampling frequencies do NOT meet permit requirements Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.6 of the NPDES permit. "I certity, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Randy Green Permittee (Please print or type) Si a r e ittee*** Date (Required un submitted electronically) Permittee Address Phone Number e-mail. address Permit Expiration Date Certified Laboratory (2) Certified Laboratory (3) Certified Laboratory (4) ADDITIONAL CERTIFIED LABORATORIES Certification No. Certification No. Certification No. Certified Laboratory (5) Certification No. PARAMETER CODES Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.us/ s and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. ***Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 2B..0506(b)(2)(D). Page 2 ENCO Laboratories Accurate. Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Friday, April 22, 2016 Novozymes North America (NO008) Attn: Joe Ladd 77 Perry Chapel Church Road Franklinton, NC 27525 RE: Laboratory Results for Project Number: [none], Project Name/Desc: Stormwater Testing ENCO Workorder(s): CZ01509 Dear Joe Ladd, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Wednesday, April 13, 2016. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Chuck Smith Project Manager Enclosure(s) 0vw RECEIVED JUN 16 2016 CENTRAL FILES DWR SECTION FINAL This report relates only to the sample as receNed by the laboratory, and may only be reproduced h full, Page 1 of 10 www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: Outfall -1 Lab ID: CZ01509-01 Sampled: 04/12/16 09:00 Received: 04/13/16 07:25 Parameter EPA 351.2 Hold Date/Tlmefs] 05/10/16 Pren DatelTlmefsl 04/16/16 Analrsls DatelTimefsl 11:30 04/19/16 08:27 EPA 353.2 04/14/16 09:00 04/13/16 14:29 04/13/16 16:21 EPA 353.2 05/10/16 04/21/16 07:46 04/21/16 11:39 EPA 353.2 01/06/19 04/22/16 08:47 04/22/16 09:11 EPA 365.4 05/10/16 04/16/16 11:30 D4/19/16 10:29 SM 254OD-1997 04/19/16 D4/18/16 09:19 D4/18/16 09:19 SM 521OB-20DI 04/14/16 09:00 D4/13/16 14:36 04/13/16 14:36 SM 5220D-1997 05/10/16 D4/21/16 11:57 04/21/16 18:20 Client ID: Outfall - 2 Lab ID: CZ01509-02 Sampled: 04/12/16 09:35 Received: 04/13/16 07:25 Parameter EPA 351.2 Hold DatelTlmelsl 05/10/16 Prep Date/3lmefs1 D4/16/16 Analysis D0�/Tlmefsl 11:30 04/19/16 08:31 EPA 353.2 04/14/16 09:35 D4/13/16 14:29 04/13/16 16:24 EPA 353.2 05/10/16 04/21/16 07:46 04/21/16 11:43 EPA 353.2 01/06/19 D4/22/16 08:47 04/22/16 09:11 EPA 365.4 05/10/16 04/16/16 11:30 04/19/16 10:32 SM 2540D-1997 04/19/16 04/14/16 13:00 04/14/16 13:00 SM 5214B-2001 04/14/16 09:35 SM 52200-1997 05/10/16 D4/13/16 14:36 04/13/16 14:36 04/21/16 11:57 04/21/16 18:20 F[NAL TNs report relates only to the sample as recelved try the laboratory, and may only be reproduced in full. Page 2 of 10 www.encolabs.com SAMPLE DETECTION SUMMARY client ID: Outrall -1 Lab ID: CZ01509-01 Auahte Results an X" E" dolts Method ll9sea Biochemical Oxygen Demand 3.6 2.0 2.0 mg/L SM 521OB-2001 Chemical Oxygen Demand 14 10 10 mg/L SM 5220D-1997 Nitrate as N 0.90 0,025 0.10 mg/L EPA 353.2 Nitrate/Nitrlte as N 0.93 0.041 0.10 mg/L EPA 353.2 Nitrite as N 0.030 3 0.017 0.10 mg/L EPA 353.2 Phosphorus 0.18 0.025 0.10 mg/L EPA 365.4 Total Kfeldahl Nitrogen 0.99 0.26 0.48 mgtL EPA 351.2 Total Suspended Solids 15 5.0 5.0 ma/L SM 2540D-1997 AualYte Results Piaui M" ML M1 k Method Notes Biochemical Oxygen Demand >73 2.0 2.0 mg/L SM 521OB•2001 8-02 Chemical Oxygen Demand 190 10 10 mgjL SM 5220D-1997 Nitrate as N 0.11 0.025 0.10 mg/L EPA 353.2 Nitrate/Nltrlte as N 0.14 0.041 0.10 mg/L EPA 353.2 Nitrite as N 0.030 3 0.017 0.10 mg/L EPA 353.2 Phosphorus 0.16 0.025 0.10 mg/L EPA 365.4 Total Kjeldahl Nitrogen 6.7 0.26 0.48 mg/L EPA 351.2 Total Suspended Solids 17 17 17 mg/L SM 254OD-1997 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 3 of 10 www.enoolabs.com ANALYTICAL RESULTS Description: Outfall - 1 Lab Sample ID:CZ01509-01 Received: 04/13/16 07:25 Matrix: Surface Water Sampled:04/12/16 09:00 Work Order: CZ01509 Project: Stormwater Testing Sampled By:Joe Ladd Classical Chemistry Parameters ^ - &WO ca y c&VW anadyte JAC 5vr1 AnabEW [CAS Numbed Resu Bala ]]niu 12E HK EQL fi b Hetggd Analyzed ft Notes Biochemical Oxygen Demand^ 3.6 mg/L 1 2.0 2.0 6D13035 SM S21OB-2001 04/13/16 14:36 JOC Chemical oxygen DemandA 14 mg/L 1 10 t0 6DZ1017 SM 522OD-1997 04/21/16 18:20 ]OC Nitrate as N [34797-55-8]^ 0.90 mg/L 1 0.025 0.10 6D22011 EPA 353.2 04/22/16 09:11 JU Nitrata/Nitrlte as NA 0.93 mg/L 1 0.041 0.10 6D21002 EPA 353.2 04/21/16 11:39 JU Nitrite as N [14797-65-0]^ 0.030 J mg/L 1 0.017 0.10 6D13040 EPA 353.2 04/13/16 16:21 JU Phosphorus[7723-14-0]^ 0.18 mg/L 1 0.025 0.10 61)16004 EPA 365.4 04/19/16 10:29 JU Total Kjeldahl Nitrogen^ 0.99 mg/L 1 0.26 0.48 61)16002 EPA 351.2 04/19/16 08:27 JLI Total Suspended Solhls^ 15 mg/L 2 5.0 5.0 61)16002 SM 254OD-1997 04/18/16 09:19 MMR Description: Outfall - 2 Lab Sample ID:CZ01509-02 Received: 04/13/16 07:25 Matrix: Surface Water Sampled:04/12/16 09:35 Work Order. CZ01509 Project: Stormwater Testing Sampled By:30e Ladd Classical Chemistry Parameters A - EACO Cary -nWkd a x*M JAC 5911 Results 1la9 units PE H L EQL ftuh ti Analned Bu Notes Biochemical Oxygen Demand- >73 mg/L 1 2.0 2.0 6D13035 SM 52108-2001 04/13/16 14:36 30C B-02 Chemical Oxygen Demand^ 190 mg/L 1 10 LD 6D21017 SM 522OD-1997 04/21/16 18:20 10C Nitrate as N [14797-55-B]^ 0.11 mg/L 1 0.025 0.10 6D22011 EPA 353.2 04/22/16 09:11 3U Nitrate/Nitrite as NA 0.14 mg/L 1 0.041 0.10 6D21002 EPA 353.2 04/21/16 11:43 JU Nitrite as N [14797-65-0]^ 0.030 J mg/L 1 0.017 0.10 6D13D40 EPA 353.2 04/13/16 16:24 JU Phosphorus [7723-14-0]^ 0.16 mg/L 1 0.025 0.10 61)16004 EPA 365.4 04/19/16 10:32 JU Total Kjoldahl Nitrogen^ 6.7 mg/L 1 0.26 0.48 61)16002 EPA 351.2 04/19/16 08:31 JLI Total Suspended Solids^ 17 mg/L 6.67 17 17 61)14005 SM 254OD-1097 04/14/16 13:00 MMR FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 4 of 10 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control fate* 6013035 - NO PREP Blank (61)13035-BLK3) Prepared & Analyzed: 04/13/2016 14:36 Spike Source %REC RPD Ana h[ta Result Elas 241 units Level Resu %REC Limim RPO Limit notes Biochemical Oxygen Demand 2.0 U 2.0 mg/L LCS (6D13035-851) Prepared & Analyzed: 04/13/2016 14:36 Spike Source %REC RPD -Analwto Result Elan P" Units Level Raul %REC Limits RPD Limit Notes Biochemical Oxygen Demand 210 2.0 mg/L 198 108 BS-115 Duplicate (6D13035-DUPE) Prepared & Analyzed: 04/13/2016 14:36 Source: CZ01509-01 Spike Source %REC RPD Analvts Result Elan PDI, units Level Result %REC Llmita RPD Llmlt (des Biochemical Oxygen Demand 3.6 2.0 mg/L 3.6 0.4 30 feet* 60.93040 - NO PREP Blank (6D13040-BLKi) Prepared: 04/13/2016 14:29 Analyzed: 04/13/2016 16:16 Spike Source %REC RPD Ana iYtp Result Etas M llnit8 Level Result %REC Limits RPD Limit Notes Nitrite as N 0.017 U 0.10 mg/L LCS (6D13040-B51) Prepared: 04/13/2016 14:29 Analyzed: 04/13/2016 15:48 Spike Source %REC RPD Ana hdo Result Eft ML Units Level RS51iit %REC Limlta RPD Limit notes Nitrite as N 0.99 0.10 mg/L 1.00 99 90-110 Matrix Spike (6D33040-MS1) Prepared: 04/13/2016 14:29 Analyzed: 04/13/2016 16:17 Source: CZ01509-01 Spike Source %REC RPD AnaiYte Result Elas RQL !units Level Result %REC Limps RPD Limit Notes Nitrite as N 0.96 0.10 mg/L 1,00 0,030 93 90-110 Matrix Spike (6D33040-MS2) Prepared: 04/13/2016 14:29 Analyzed: 0Q13/2016 16:25 Source: CZ01S09-02 Spike Source %REC RPD ADaly Result Elan P9L Urns Level get %REC Limp& RPD Limit Notes Nitrite as N 0.95 0.10 mg/L 1.00 0.030 92 90-110 Matrix Spike Dup (6D33040-MSDi) Prepared: 04/13/2016 14:29 Analyzed: 04/13/2016 16:22 Source: CZ01509-01 Spike Source %REC RPD Analy Result Elan PQL units Level Result %REC Limps RPD Limit Notes Nitrite a5 N 0.98 0.10 mg/L 1,00 0.030 95 90.110 1 10 fatrh 6014005 - NO PREP Blank (6D14005-BLK1) Prepared & Analyzed: 04/14/2016 13:04 Spike Source %REC RPD Ananda Result Elio PQL Units Level Result %REC Llmlts RPD Limit Notes Total Suspended Solids 2.5 U 2.5 mg/L FINAL This report relates only to the sample as receK" by the laboratory, and may only be reproduced In full. Page 5 Of 10 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control 1118fich 6D14005 - NO PREP - Condnifed LCS (6014005-BS1) Prepared & Analyzed: 04/14/2016 13:00 Spike Source %REC RPD Anallrte Result Flag El)1 MOM Level b51l1t %REC Limits RPD LM Notes Total Suspended Solids 91 2.5 mg/L 100 91 80.120 Duplicate (6D14005-DUPl) Prepared & Analyzed: 04/14/2016 13:00 Source: CZ02408-01 Spike Source %REC RPD Arta hde Result flea R" Units Level Result %REC Limits RPD Limit Notes Total Suspended Solids 770 170 mg/L 500 43 20 QM-12 Duplicate (6D34005-DUP2) Prepared & Analyzed: 04/14/2016 13:00 Source: CZ02434-01 Spike Source %REC RPD Ana!>de Result flab ML Sinus Level Result %REC LIM& RPD Limit Notes_ Total Suspended Solids 220 100 mg/L 270 18 20 Raft* 6D16002 - Some Blank (6D15002-BLKI) Prepared: 04/16/2016 11:30 Analyzed: 04/19/2016 08:20 Spike Source %REC RPD Anah[te Result Flag E41 Lnita Level Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 0.26 U 0.48 mg/L LCS (6016002-BSI) Prepared: 04/16/2016 11:30 Analyzed: 04/19/2016 08:22 Spike Source %REC RPD Analytic Result Flag ROL Unita Level Result %REC Limits RPD Llmlt Notes Total Kjeldahl Nitrogen 13 0.48 mg/L 12.0 105 90-110 Matrix Spike (6D16002-MS1) Prepared: 04/16/2016 11:30 Analyzed: 04/19/2016 08:25 Source: CZ01509-01 Spike Source %REC RPD AnallLte Result Flag E01 Unita Level Result %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 5.9 0.48 mg/L 4.80 0.99 103 90-110 Matrix Spike (6D16002-MS2) Prepared: 04/16/2016 11:30 Analyzed: 04/19/2016 08:33 Source: CZ01509-02 Spike Source %REC RPD Anal 1[te Result flau $4L Units Level R" %REC JjMlU RPD Lbh Notes Total Kjeldahl Nitrogen 11 0.48 mg/L 4.80 6.7 99 90.110 Matrix Spike Dup (6D16002-MSD1) Prepared: 04/16/2016 11:30 Analyzed; 04/19/2016 08:29 Source: CZ01S09-01 Spike Source %REC RPD Ana hde Result Flag EDL units Level Resul %REC Limits RPD Limit Notes Total Kjeldahl Nitrogen 5.8 0.48 mg/L 4.80 0.99 too 90.110 3 10 Batch 6DI6004 - Same Blank (6D36004-BLK1) Prepared: 04/16/2016 11:30 Analyzed: 04/19/2016 10:24 Spike Source %REC RPD Anands Result flag E41 Unita Level Result %REC Limit RPD Limit Notes Phosphorus 0.025 U 0.10 mg/L FINAL This report mates only to the sample as reoeived by the laboralnry, and may only be reproduced in ruil. Page 6 of 10 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Qualitq Control Batch 6D16OO4 - Some - Condwed LCS (6DIS004-BSI) Prepared: 04/16/2016 11:30 Analyzed: 04/19/2016 10:26 Spike Source %REC RPD Ana hdm Result Eli= Pal Unite Level ResYll %REC Limits RPD Lb= Notes Phosphorus 1.5 0.10 mg/L 1.60 95 80-120 Matrix Spike (61316004-MSI) Prepared: 04/16/2016 11:30 Analyzed: 04/19/2016 10:27 Source: C201509-01 Spike Source %REC RPD AnaResult Fla4 ML Units Level Result %REC Limits RPD LI01lt Rotes Phosphorus 0.80 0.10 mg/L 0.640 0.18 98 BO.120 Matrix Spike Dup (6016004-MS01) Prepared: 04/16/2016 11:30 Analyzed: 04/19/2016 10:31 Source:CZ01509-01 Spike Source %REC RPD Analvte Result Flan EQL Unite Level Resin %REC limits RPD a = Motes Phosphorus 0181 0.10 mg/L 0.640 0.18 99 80-120 0.6 25 Batch 6D18OO2 - NO PREP Blank (6D18002-BLKi) Prepared & Analyzed: 04/18/2016 09:19 Spike Source %REC RPD ADah[te Result flim E41 Units Level Result %REC LIB RPD Llml= Notes Total Suspended Solids 2.5 U 2.5 mg/L LCS (61)18002-01) Prepared & Analyzed: 04/18/2016 09:19 Spike Source %REC RPD Ana hda Result ELU E41 Unib Level Result %REC NDtlta RPD Limit Notes Total Suspended Solids 90 2.5 mg/L 100 90 80-120 Duplicate (6D38002-DUP3) Prepared & Analyzed: 04/18/2016 09:19 Source: CZ02441-01 Spike Source %REC RPD Anal lde Result Flan M Units Level Result %REC 6110lts RPD Llmlt Notes Total Suspended Solids 250 50 mg/L 230 9 20 Duplicate (6D18002-DUP2) Prepared & Analyzed: 04/18/2016 09:19 Source: CZ02444-01 Spike Source %REC RPD Ana hlta Result lieu EQL units Level Result %REC limits RPD LIM Notes TotalSuspended Solids 300 5o mg/L 270 9 20 Batch 6D21OO2 - NO PREP Blank (6D21002-6LKi) Prepared: 04/21/2016 07:46 Analyzed: 04/21/2016 11:35 Spike Source %REC RPD Anahftls Result Rae PAL Units Level Resu %REC Limits RPD limit Notes Nltrate/Nltrite as N 0.041 U 0.t0 mg/L LCS (6D21002-BSI) Prepared: 04/21/2016 07:46 Analyzed: 04/21/2016 11:28 Spike Source %REC RPD Anal lfts Result FLU MI, bits Level Result %REC Limits RPD limit Notes Nitrate/Ntrite as N 1.2 0.10 mg/L 1.25 99 90.110 FINAL This report (dates only to the sample as received by the laboramry, and may only be reproduced In full. Page 7 of LO www.encolabs.com QUALM CONTROL DATA Classical Chemistry Parameters - Quality Control Batas 6D21001- NO PREP - Continued Matrix Spike (6D21002-MS1) Prepared: 04/21/2016 07:46 Analyzed: 04/21/2016 11:37 Source:CZ01509-01 Spike Source %REC RPD Anahtffi Result Hag EOL Units Level get %REC Limits RPD l,jayt l 85 Nitrate/Nltrite as N 1.4 0.10 mg/L 0.513 0.93 88 90.110 QM-07 Matrix Spike (6D21002-M52) Prepared: 04/21/2016 07:46 Analyzed: 04/21/2016 11:46 Source: CZ01509-02 Spike Source %REC RPD Anil Result Hag E4L unita Level Resu %REC Limits RPD Limit Motes Nitrate/Nitrite as N 0.65 0.10 mg/L 0,513 0.14 99 90-110 Matrix Spike Dup (6D21002-MSD1) Prepared: 04/21/2016 07A6 Analyzed: 04/21/2016 11:41 Source. CZ01309-01 Spike Source %REC RPD .Anal YtA Result Flag ROL units Level get %REC Limits RPD Llmt Notes Nitrate/Nltrlbe as N 1.4 0.10 mg/L 0.513 0.93 102 90-110 5 10 Batch OD21017 - Same Blank (61321017-13LK1) Prepared: 04/21/2016 11:57 Analyzed: 04/21/2016 18:20 Spike Source %REC RPD Ana hdrs Result MCI M units Level gesul %REC Limits RPD Limit Notes Chemical Oxygen Demand 10 U 10 mg/L LCS (BD21017-BSI) Prepared: D4/21/2016 11:57 Analyzed: 04/21/2016 18:20 Spike Source %REC RPD Anahltn Result Hag EOL !!nits Level gesult %REC Llmitea RPD Llmlt Notes Chemical Oxygen Demand 470 10 mg/L 500 95 90-110 Matrix Spike (6D21017-MS1) Prepared: 04/21/2016 11:57 Analyzed: 04/21/2016 18:20 Source: CZ00875-01 Spike Source %REC RPD AnaResult Flag QOL unitil Level gesu)t %REC LEmlts RPD Limit Notes_ Chemical Oxygen Demand 920 10 mg/L 526 440 92 90-110 Matrix Spike Dup (6D21017-MSD1) Prepared: 04/21/2016 11:57 Analyzed: 04/21/2016 18:20 Source: CZ00875-01 Ananda Chemical Oxygen Demand Spike Source %REC Result flag P-QL units Level &ME %REC Limits RPD 920 10 mg/L 526 440 91 90.110 0.7 RPD Limit Notes 10 FINAL This report relates only to the sample as recelved by the laboratory, and may only be reproduced In full. Pape 8 of 10 www.encolabs.com FLAGS/ NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. ] The reported value is between the laboratory method detection limit (MDQ and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration Indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQQ and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported, B-02 The sample dilutions set up for the analysis failed to meet the criteria of a residual dissolved oxygen of at least 1 mg/I. Therefore the reported result is an estimated value only. QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. QM-12 Precision between duplicate samples was outside acceptance limits. FINAL This resort relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 9 of 10 .-.. v v V V s-r7CGV1'7t? www.encolabs.com So779 Cmrdral FVn ilr. 461oEm=b6v Pah Court. Su4r 111 .. .. 1o2-A WOOdwbft hl3atr W C1. Odardq FL 3MM4 .i="=wft FL 37258-6069 Coy, NC 27511 f ?) (4137) W15' U F8f (4107) 650.6945 (got) 290 3007 Fa11 ") 29B•6210 - (919) 467,JWp Fax (919) 467.3515 Page _ _l of - CiwraNmne.- t prn-N_ber.. >. -. ---: RagwsrstlArWy-W - - ReQUOSted Turnaround - Times Nofa: Ruth reciumn subject I* - accoplarzo by rw 000ty Standard _ Expedited DueQy � V to 2 � 0 O � � Cc)?rrawa� � M CV) cc () � ro � m m m ` cv r LO t� Z a �i tYi 1n cra a Ul Gn (U) J - Adtlrm- _ " Chapel aroEx'.. - C"wr4p - - -.. - nk3fnt n NC 27525 pl7 e 1 luwv Into 3801933 id - - 494-3370 Fa, iiipOraq Contad .. .toe Ladd Sanrpler(a] flame, AKnauon 1 +1 . o fJ} _ B e.,Q coinei3 ' Accounts payable serp,r(s) m® sae 1 Trim zms a!� ^/t La_ b Waftrder CZO 1509 Ism I(owtaMAM ) . ben 0 Sarrp4 m (Freed a bR) Cp&Ki wr D- C44rdfal rm. comp I crab elatrir (sme codes) - Tres) a m1 Cardainera - - Sample Cornments D u -1-e2ilLo S l X K X - <- Tots! 0 Of GonWners Svrgk KA Rtep&-W 80. ..- . Daemrrram . r�-I 2-_1 `, _ 8r-Roy - - -- dalNfinm - _per Rrcaivad •. - ... .. - - t , oawrww -^ �,(_13! D V �,L II 1 -� � • fL+ a144<< z.: pig- 79 r'4`ins'e6 ... Oamelri„m � � - - Dasmlrinm - Rdrqukflwd By - _ caoteras/TerepsalRmcarpl Dmdr-uno FlpwBy - - DAte/Tim - - .. , . llcoept34[e �Unacce table Yeah:GW-Gtouidrratmr MSc* tf_W-Drl "Wales BESmdhwm SW-SuAac,aWater. WW-Nlaus+fer;A•Air'"Um (d"M=UrWM5)' pf!oWrsteal:I H•HA N4ikW S4VS04 K"aOH"o•Oe1wr(detailhmnvner a) " Ham : Aq >mr� tarlxrptteA tra EHCO Labs arm m �arordarlca wqh itle mrae end omdNgru PsOed m Rra ra>rmrtta of this tarlrl. uriloss psis rrnden egearrknts mdsl Sample Preservation Verification X.�^ ENCO Cary =eNm Work Order: CZ01509 Project: Stormwater Testing Client: Novozymes North America (N0008) Project #: [none] Logged In: 13-Apr-16 08:03 Logged By: John C King CZ01509-01 Co A rHr us a Reagent �lAed/Comme h rament n Cotst(ot Adjusted D 250mLP+H2SO4 42 I N I NA Y! 1 NA E 250mLP+H2SO4 42 YIN/NA Y / / NA CZ01509-02 Cont R lrorrser�ti A Cwttr.+al PHAdjustedsw"wStu �s tRea r►li se IComme-M a", D 250mLP+H2804 a2 I N/ NA Y I / NA E 250mLP+H2SO4 <2 / N I NA Y I 1 NA Reacient Name ID 1 2 Rea ent Name ID 3 4 Rea ent Name 10 5 6 Page 1 4 Date: May 2, 2016 Novozymes, NA Inc. 77 Perry's Chapel Church Rd. Franklinton, N.C. 27525 NCDEQ Division Of Water Quality 1617 Mail Service Center Raleigh, N.C. 27699-1617 Attn: Division Of Water Quality Storm Water Sampling, NPDES Permit No. Dear Sir/Madam Dear, Sir/Madam novozY mes Rethink Tomorrow UN 16 2016 CENTRAL FILES F DWR SECTION During review of storm water sampling results, it was observed that there was an exceeded benchmark in Biological Oxygen Demand (BOD), and Chemical Oxygen Demand (COD) from our Outfall 2 location. Upon immediate investigation, per Tier One requirements, it was discovered that although during sample event no signs of potential issues were present, the area approximately 20 yards from where samples collected containers of product were rinsed prior to being disposed. There are drains specifically used for rinsing purposes, however, during clean-up activities the area was hosed down and some product may have been pushed outside drain borders. We have concluded that since this rinsing took place the day before rain event with which samples were taken, it could have caused the higher than normal BOD, and COD readings. We have taken measures to ensure this process is more carefully performed especially during cleaning of area post work. Continued monitoring by Environmental Services Department will take place in order to prevent future exceeded benchmarks in Biological Oxygen Demand (BOD), and Chemical Oxygen Demand (COD) from Outfall 2. Kind ds, Joe L d Environmental Compliance Coordinator Environmental Services m NPDES PERMIT NO. NCS000115 FACILITY NAME Novozymes, NA Inc. OPERATOR IN RESPONSIBLE CHARGE (ORC) EFFLUENT DISCHARGE NO. 1 CLASS NIA CERTIFIED LABORATORIES (1) Enco (2) CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Mail ORIGINAL and ONE COPY to: ATTN: CENTRAL FILES : N/A DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) 1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY RALEIGH. INC 27699-1617 KNOWLEDGE. MONTH April ^ YEAR 2016 COUNTY: Franklin PHONE (919) 494-3001 Joe Ladd Lim 1�mmlllmlmuml • s Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) Fx_1 Compliant All monitoring data and sampling frequencies do NOT meet permit requirements F1 Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.b of the NPDES permit. "I certity, unaer penalty of law, that this document ants all attachments were prepared uncer my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Randy Green Permittee (Please print or type) _- r' Sig re of P tttee*** pate (Required u s submitted electronically) Permittee Address Phone Number e-mail address Permit Expiration Date ADDITIONAL CERTIFIED LABORATORIES Certified Laboratory (2) Certification No. Certified Laboratory (3) Certification No. Certified Laboratory (4) Certified Laboratory (5) PARAMETER CODES Certification No. Certification No. Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.ennstate.nc.us/ s and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. *** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 2B .0506(b)(2)(D). / � \ } . \ < \ j © , � \ \ :ƒ § \ :A- �� �p . \ \ j - � 4 » EFFLUENT NPDES PERMIT NO. NCS000115 DISCHARGE NO. 2 FACILITY NAME NOVOZymeS, NA Inc. CLASS OPERATOR IN RESPONSIBLE CHARGE (ORC) N!A CERTIFIED LABORATORIES (1) Enco CHECK BOX IF ORC HAS CHANGED PERSON(Sj COLLECTING SAMPLES Mail ORIGINAL and ONE COPY to: (2) MONTH April YEAR 2016 COUNTY: Franklin PHONE (919) 494-3001 Joe Ladd ATTN: CENTRAL FILES x NIA DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) 1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY RALEIGH, NC 27699-1617 KNOWLEDGE. H~ C o U E i= C1. y O 50050 00010 FLOW H v w c Z � 0.p OLu O Z w a o c c W toH cc w zz2 = o.Z J�1 z EFF X INFO Wa o HRS HRS YIN1B MGD I "C UNITS UGA- MGIL MG& MG1L MGIL MG1L MG1L Inches MGIL LBSIMO LBS/YR Mir. s, t fpl F-lam Ulkeir?y, qE-,'r24 �i�J � .?°����+�? � 1 2 �t �r �?�P. s'-cc"•, 2 F3'4 ti'S -9;6ff?fflrA WJ& ow W�misl rrvsjml^ we '.7m mom EqAmw a 1-0ilk , I F .-i a 4 6 I 6 1 1 1 119] MWI -1 :'°' **� i I 10 I I -1.1i!RF-w -am HBO :..:1 I I fffim : k"rm �.t_ nf'-mily vv'. _ , �1m z 12 0935 7.9 73.00 190.000 17.0 6.7 0.11 1 10,16 0.5 14 i 16 i I 1`7d �,. �� I+t?? v w;�>�` .; !R _�;`< � t�..�'�.� "•?'+�.. .'' k�..W..r��f��'`. x�'.•�'i' ° �R�;="� s�.!'k�' Ir'�::;,; ���F�a� �!+�,' y:� 16 I M 91 #TWIA affin sue' ,*Eh ?"�8 s `,r? ? �Ea sci- :?s' tom" :tip is 6 :: _ m TRIM mr. 7 `�T-77 7 20 I' �21fi � � ILA'; +r.: � '�� ��.,i� xn'�'�`.a� � �`� a� ..��ni' 11x;=:i(• � � m< aft w�'� 22 II ! 4 1002 h, 1♦ di 1p-S .n �_-.N.ii'' r -1 i..0 4AL91 1_" � % ' 1fU 'sf... w�M 'Wwtvj 9*." �'w' g� 24 I it . ' 25 3r',a a p T <r15 ; _ ; sty 3fi n . a ._ ht x� C ."dEF; ',s r 3.. 26 1 rf' ! '27, "sue", �?tffWl s KM; ,,f4 9w.Al'� r,.& — LV"k*; ! o$ i 0IM0 KIM ::: 7 28 29! s ,a 'l v R,,*rT 91Ls imm-ft mww IG.i�W 5w 1wi 30 f' t3i( 4 "e? 0'rt'" aimmJ t"x ai,•z. u4e a, `As vw—: " wa mw1m &'. AVERAGE r MAXIMUM ,. r' 5y_m P. x `MI t A �? " W"-Ma mm MINIMUM j Monthly Limit My, 12w F '?fit I J Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) Compliant All monitoring data and sampling frequencies do NOT meet permit requirements [K] Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.b of the NPDES permit. "I certtty, under penalty of taw, that this nocument and all attachments were prepares unuer my airection or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Randy Green Permittee (Please print or type) Sign re of P ittee*** Date (Required un)Ks submitted electronically) Permittee Address Phone Number a -mail address Permit Expiration Date ADDITIONAL CERTIFIED LABORATORIES Certified Laboratory (2) Certification No. Certified Laboratory (3) Certification No. Certified Laboratory (4) Certification No. Certified Laboratory (5) Certification No. PARAMETER CODES Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.us/was and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flaw/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. *** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 213 .0506(b)(2)(D). r ` Date: May 0,2015 Novozymes, NA Inc. 77 Perry's Chapel Church Rd. Franklinton, N.C. 27525 NCDENR Division Of Water Quality 1617 Mail Service Center Raleigh, N.C. 76 61 Attn: Division Of Water Quality Storm Water Sampling, NPDES Permit No. NCS000115 Dear Sir/Madam mes novoz � Y Rethink Tomorrow Per our Tier Two requirements, regarding the exceeded benchmark in Total Suspended Solids, (TSS), our implementation of a monthly monitoring in area of concern, "Outfall 1", beginning in January have resulted in "No Flow" for the month of April. We therefore were unable to collect a sample for this month. We plan to continue to diligently with our monthly monitoring for the parameter of TSS until we obtain three consecutive sample results within the benchmark range. Kind Regard , Joe Lad Environmental Compliance Coordinator Environmental Services RECEIVED juiik4, 9 3 2015 DENR-LAND QUALITY STORMWATER PERMITTING I EFFLUENT NPDES PERMIT NO. NCS000115 DISCHARGE NO. 1 FACILITY NAME Novozymes, NA Inc. CLASS OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA CERTIFIED LABORATORIES (1) EnCo (2) CHECK Box IF ORC HAS CHANGED 0E] PERSON(S) COLLECTING SAMPLES Mail ORIGINAL and ONE COPY to: MONTH August YEAR 2015 COUNTY: Franklin PHONE 919 494-3001 Joe Ladd ATTN: CENTRAL FILES K NIA DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) 1617 MAIL SERVICE CENTER RALEIGH, INC 27699-1617 BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE. ■ i m loom DWQ Form MR-i (11/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) Compliant All monitoring data and sampling frequencies do NOT meet permit requirements Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.6 of the NPDES permit. "I certity, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Randv Green Permittee (Please print or type) Sig ure of Pe ttee*** Date (Required unless submitted electronically) Permiuce Address Phone Number e-mail address Permit Expiration Date Certified Laboratory (2) Certified Laboratory (3) ADDITIONAL CERTIFIED LABORATORIES Certification No. Certification No. Certified Laboratory (4) Certification No. Certified Laboratory (5) Certification No. PARAMETER CODES Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.uslwas and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. Signature of Permittee: If signed by other than the permitter, then the delegation of the signatory authority must be on file with the state per 15A NCAC 2B .0506(b)(2)(D). Page 2 EFFLUENT NPOES PERMIT NO. NCS000115 DISCHARGE NO. 2 FACILITY NAME Novozymes, NA Inc. CLASS OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA CERTIFIED LABORATORIES (1) Enco (2) CHECK BOX IF ORC HAS CHANGED Q© PERSON(S) COLLECTING SAMPLES Mail ORIGINAL and ONE COPY to: ATTN: CENTRAL FILES x NIA DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) 1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY RALEIGH, NC 27699-1617 KNOWLEDGE. MONTH August YEAR 2015 COUNTY: Franklin PHONE (919) 494-3001 Joe Ladd DWQ Form MR-1 (11/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) Compliant All monitoring data and sampling frequencies do NOT meet permit requirements Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.6 of the NPDES permit. "I certity, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Randy Green Permittee (Please print or type) S - 2O/ S Signafw#V Permi a *** Date (Required unless submitted electronically) Pennittee Address Phone Number e-mail address Permit Expiration Date Certified Laboratory (2) ADDITIONAL CERTIFIED LABORATORIES Certification No. Certified Laboratory (3) Certification No. Certified Laboratory (4) Certified Laboratory (5) PARAMETER CODES Certification No. Certification No. Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.uslwas and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .020C **" Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 213.0506(b)(2)(D). Page 2 r ENCO Laboratories Accurate. Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27311 Phone: 919.407.3090 FAX: 919.467.3515 Thursday, September 17, 2015 Novozymes North America (NO008) Attn: Joe Ladd 77 Perry Chapel Church Road Franklinton, NC 27525 RE: Laboratory Results for Project Number: [nonel Project Name/Desc: 5tormwater Testing ENCO Workorder(s): C416992 Dear Joe Ladd, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Monday, August 31, 2015. Unless otherwise noted in an attached project narrative, all samples were received In acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained In this report are in compliance with NELAC standards, except as noted In the project narrative. This report shall not be reproduced except In full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further Information, please do not hesitate to contact me. Sincerely, Chuck Smith Project Manager Enclosure(s) FIAIX This report elates only to the sample as received by the laboratory, and may only be reproduced In M. Papa 1 of 11 rwwv encolabe.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: OLM11.1 lab I0: C416992-01 Sampled: 08/31/1S 09:40 Reaelved: 08/31/15 16:30 ParameterHdd EPA 351.2 DatelTlmer[a] 09/28/15 Prep Date/Tlma(a] 09/11/15 13:22 09/15/15 10:02 EPA 353.2 09/02/15 09:40 09/01/15 14:11 09/01/15 16:01 EPA 353.2 09/28/15 09/11/15 08:23 09/11/15 12:49 EPA 353.2 05/26/18 09/16/15 16:21 09/16/15 16:21 EPA 365.4 09/28/15 09/11/15 09:28 09/15/15 12:22 SM 254OD-1997 09/07/15 09/02/15 17:10 09/02/15 17:10 SM 521OB-2001 09/02/15 09:40 09/02/15 07:27 09/02/15 07:27 SM 5220D-1997 09/28/15 09/01/15 16:38 09/02/15 15:00 Ghent IDt Outtall- 2 Lab rD: C416992-02 Sampled: 08/31/15 09:20 ReoNved: 08/31/13 1.6:30 Pamowder EPA 351.2 Hold Date/Tlme(a] 09/28/15 Prep Date/Tlme[a] 09/03/15 10:03 Lei 09/08/15 11:39 EPA 353.2 09/02/15 09:20 09/01/15 14:11 09/01/15 16:03 EPA 353.2 09/28/15 09/11/15 08:23 09/11/15 12:54 EPA 353.2 05/26/18 09/16/15 16:21 09/16/15 16:21 EPA 365.4 09/28/15 09/03/15 10:03 09/08/15 13:04 SM 254OD-1997 09/07/15 09/02/15 17:10 09/02/15 17:10 SM 52100.2001 09/02/15 09:20 09/02/15 07:27 09/02/15 07:27 SM 522OD-1997 09/28/15 09/01/15 16:38 09/07115 15:00 FW& This report relates only to the sample as reoCved by the lebore[ory, and may only be reproduced In fuH. Pepe 2 of 11 www.encolabo.com SAMPLE DETECTION SUMMARY Client IDr OutfaU -1 Lab ID: C416992-0i AnRbu flm& an M" Pal. lhtb Mf d H91112 BbchemkzJ Oxygen Demand 2.8 2.0 2.0 mg/L SM 52108-2001 Chemical Oxygen Demand 25 10 10 mg/L SM 522OD-1997 Nitrate as N 0.87 0.025 0.10 mg/L EPA 353.2 Nitrate/Nitrite as N 0,87 ] 0.41 1.0 mg/L EPA 353.2 R-01 Phosphorus 0.35 0,025 0.10 mg/L EPA 365.4 Total Kjeldahl Nitrogen 0.84 0.26 0.48 mg/L EPA 351.2 Total Suspended Solids 39 7.1 7.1 mg/L SM 254OD-1997 Client IO: OutfaU - 2 Lab IO: C416992-02 ADeba Baum am HU RU Unm Method Not" Blodremkal Oxygen Demand 5.3 2.0 2.0 mg/L SM 52108-2001 Chemical Oxygen Demand 49 10 10 mg/L SM 522OD-1997 Nitrate as N 0.38 0.025 0.10 mg/L EPA 353.2 Nitrate/Nitrite as N 0.41 J 0.41 1.0 mg/L EPA 353.2 R-01 Nitrite as N 0.026 ] 0.017 0.10 mg/L EPA 353.2 Phosphorus 0.15 0.025 0.10 mg/L EPA 365.4 Total i(jeldahl Nitrogen 0.72 0.26 0.48 mg/L EPA 351.2 Total Suspended Solids 93 20 20 mg/L SM 254OD-1997 FINAL This report Males only to the sample as M&ied by the laboratory, and may only be reproduced in full. Page 3 or it www.encolobs.com ANALYTICAL RESULTS Description: Outfall - i Lab Sample ID: C416992-01 Received: 08/31/15 16:30 Matrix: Surface water Sampled:08/31/15 09:40 Work Order: C416992 Project: Stormwater Testing Sampled By:Joe Ladd Classical Chemistry Parameters ^-61C0Cary o<&W[AC 5111 Anahrts [CAS Numllerl Room an 11010 12E HM P91 AlUb 1191111w AO bud f1 AdU Biochemical Oxygen Demand^ 2.8 mg/L 1 2.0 2.0 5102001 SM 52105-2001 09/02/15 07:27 30C Chemical Oxygen Demand^ 25 nng/L 1 10 10 5101011 SM 5220D-1997 09/07J15 15:00 30C Nitrate as N [14797-88-8]^ 0.87 mg/L 1 0.025 0.10 5116038 EPA 353.2 09/16/15 16:21 MILS Nhtrata/Nit"te as N^ 0.87 J mg/L 10 0.41 1.0 SID9002 EPA 353.2 O9/11115 12:49 JL] R-01 Nttrlhe as N [14797-15-0]^ 0.017 U mg/L 1 0.017 0.10 5101025 EPA 353.2 D9101/15 16:01 JLJ Phosphorus [7723-14-0]^ 0.35 mg/L 1 0.025 0.10 5111009 EPA 365.4 09/15/15 12:22 JLJ Tots) KJddahl Nitrogen^ 0.84 mg/L 1 0.26 0.48 5111007 EPA 351.2 09/15/15 10:02 JU Total Suspended Solids^ 39 mg/L 2.86 7.1 7.1 5102004 SM 2WD-1997 09/02/15 17:10 MMR Description: Outfall - 2 Lab Sample ID:C416992-02 Recehred, 08/31/15 15:30 Matrix: Surface Water Sampled:08/31/15 09:20 Work Order: C416992 Project: Storrnwater Testing Sampled By:Joe Ladd Classical Chemistry Parameters ^ - EKV Quy mtMY arrAoyta [AC 5YJJ Balm no 1lnits RE Hu ML 90tsit Kum ADBhf11111d a now Biochemical Oxygen Demand^ B.3 mg/L 1 2.0 2.0 5102001 SM 52105-2001 09/02/15 07:27 30C Chemical Oxygen Demand^ 40 mg/L 1 10 10 5101011 SM 5220D-1997 09/02/15 15:00 30C Nitrate as N [14797-5"]^ 0.38 mg/L 1 0.025 0.10 5116038 EPA 353.2 09/16/15 16:21 MKS Nkmto/Nkdte as NA 0.41 J mg/L 10 0.41 1.0 5109002 EPA 353.2 09/11/15 12:54 JU R-01 Nitrite as N [14797-63-0]A O.026 J mg/L 1 0.017 0.10 SI01025 EPA 353.2 09/Ol/15 16:03 JLJ Phosphorus [7723-14-0]^ 0.15 mg/L 1 0.025 0,10 5103004 EPA 365.4 09/08/15 13:04 JU Total Kjeldahl Nitrogen- 0.72 mg/L 1 0.26 0.48 SIG3003 EPA 351.2 O9/08/15 11:39 JU Total Sumpndad Solids^ 93 mg/L 8 20 20 5102004 SM 2540D-1997 09/02/15 17:10 MMR 6 9 FINAL This report rtlatrs only to the sample as retched by the laboratory, and may only be reproduoad in full. Page 4 of It h I } www.encolahs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control DR" M01011- Same Wank (SIOL011•BLKl) Prepared: 09/01/2015 16:38 Analyzed: 09/02/2015 15:00 Spike Source %REC RPD Aftalvise Bss1iB San EM delta Leval gAUH %REC Limits RPD Limit Motu Chemical Oxygen Demand 10 U 10 mg/L LCS (5I01011-BSS) Prepared: 09/01/2015 16:38 Analyzed: 09/02/2015 15:00 Spike Source %REC RPD �aanda Ba�1it Elan e1111 linos Level BREY$ %REC Limil6 RPD Limit Notm Chemical OxyW Demand 510 10 mg/L 500 101 90-110 Matrix Spike (510101L-MSL) Prepared: 09/01/2015 16:38 Analyzed: 09/02/2015 15:00 Source: C416992-01 Spike Source %REC RPD Ananda Beiult Elam POL Units Level Baulilt %REC UMB& RPO Limit mass Chemical Oxygen Demand 520 10 mg/L 500 .25 98 90-110 Metrhr Spike Dup (5I01O11-MSD3) Prepared: 09/01/2015 16:38 Analyzed: 09/02/2015 15:00 Source: C416992-01 Spike Source %REC RPD A3d[Ls Be" Hs0 POL llalti Laval g %REC Limit RPD Limit Chemical Oxygen Demand 530 10 mg/L 500 25 101 90-110 2 10 Bahl/ SI01025 - NO PREP Btmk (5101025-Bu(l) Prepared: 09/01/2015 14:11 Analyzed: 09101/201515:58 Spike Source %REC RPD Anabma Rent Elan ML Limn Level BAUH %REC L Wk RPD Limit Noted Ml[s as N 0.017 U 0,10 mg/L LCS (SI01025-BST) Prepared: 09/01/2015 14:11 Analyzed: 09/01/2015 15:41 Spike Source %REC RPD Amlybo Bawlt Hag MI. Unite Level gn ilit %REC LimM RPD Una Wall Nhrft as N 0.99 0.10 mg/L 1.00 99 90-110 LCS (5I01.023-02) Prepared: 09/01/2015 14:11 Analyzed: 09/02J2015 07:58 Spike Source %REC RPD Aoehda ltasnit an Ml. Unitb Level %REC Limns RPa Limit 111,1119114111111. NIVRe as N 0.98 0.10 M91L 1.00 98 90.110 Matrix Spike (SI01025-MS1) Prepared: 09/01/2015 14:11 Analyzed: 09/01/2015 16:00 Source: C416992-01 Spike Source %REC RIND Ananda Bawlt Elan e" Y111te Level gMggft %REC Limb RPD Limit Notes Nitrite as N 0.94 0.10 mg/L 1.00 0.017 U 94 90-110 Matrix Spike (5I01025-MS2) Prepared: 09/01/2015 14:11 Analyzed: 09/02/2015 08:01 Source: C509613-01 Spike Source %REC RIND Anahuo Bsn11t Elag P.OL Units Level Remit %REC LMMI RPD Limit Notes Nitrite as N 0.96 0.10 mg/L 1.00 0.017 U 96 90-110 Matrtx Spike Dup (SI01025-MSD1) Prepared: 09/01/2015 14:11 Analyzed: 09/01/2015 16:02 Source: C416992-01 Spike Source %REC RIND l;aaht:a RIM an PQL Tinto Level Bond %REC Limits RPD Limit 11101b , FINAL This report relates only to the sample asteed by the IaborMory, and may only be reproduced In fug. page 5 of 11 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch SM1025 - AfO PREP - Conhrnued Matrix Spike Dup (3101025-MSD1) Continued Prepared: 09/01/2015 14AL Anah7ed: 09/01/2015 16:02 Source: C416992-0i Spike Source %REC RPD Asabme Basu$ Belt P" !)Olin Loral Mauls %REC jMfta RPD LM Not" Nitrite as N 0.93 0.10 mp/L 1.00 0.017 U 93 90.110 1 10 Saudi 5I02001- AID PREP Blank (5I02001-BLI(1) Prepared & Analyzed: 09/02/2015 07:27 Spike Source %REC RPD Ana hrta BM Mall ML S)llltl Level gligigft %REC jlmils RPD Llm)t Notell- Blochemlcal Oxygen Demand 2.0 U 2.0 mp/L LC9 (3102001-01) Prepared & AnaWW: 09/02/2015 07:27 Spike Source %REC RPD Reedit Bea ML ilBIC1 Level Rm %REC LWIft RPD Nmlt Noteff- Biochemical Oxylpen Demand 210 2.0 mg/1- 193 100 85-115 DupW to (5I02001-DUPI.) Prepared & Analyzed: 09/02J2015 07:27 Source: C416992-01 Spike Source %REC RPD AOa:IDa Rena Elffi Pal UnRa Level RMM %REC LLMM RPD Nlmlt ems. Biochemical Oxygen Demand 2.2 2.0 ng/L 2.0 27 30 JIM* SM20M - NO PREP Blank (3I02004-BLK3) Prepared & AnaWW: 09/02/2015 17:10 Spike scum %REC RPD Allahlta Result Has i'..OL ultltt Level Elila z %REC Llmlta RPD LlBtlt WMAL Total Suspended Solids 2.S U , 2.5 mp/L LCS (3I02004-BS1) Prepared & AnaWW: 09/02/2015 17:10 Spike Source %REC RPD Anando Bank Elan ML unitl Level geau %REC Limb RPD LIMIR Motall- Total Suspended Solids 100 2.5 mp/L 100 100 80.120 Duplicate (5I02004-DUPl) Prepared & Analyzed: 09/02/2015 17:10 Source: C510390-01 Spike Source %REC RPD Ana hda Read Bea PQL Unitl Larval g %REC Limns RPD Llmlt Notes Total Suspended Solids 220 50 m0/L 220 0.9 20 Duplixaie (SI02004-pUP2) Prepared & Analyzed: 09/0712015 17:10 Source: C416992-02 Spike Source %REC RPD �Bahrte &rite$ Halt p41 Unit1 Level g %REC Limb RPD Limit Motes Total Suspended Solids 93 20 my/L 93 0 20 Batdl 5I03M - Same Blank (5I03003-OLKI) Prepared: 09/03/2015 10:03 Analyzed: 09/08/2015 11:28 Spike Source %REC KPD ADahfSs Basult Elm EEL Liam Level get %REC Uj U& RPD LWR Not" Total IUeldehl Nltro9w 0.26 U 0.48 mp/L FINAL This report relates ony bo UM sample as receNed by the labDratory, end may only be reproduced In full. Pape 6 of 11 www.enwinbs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Als" 57030M - mama - Cbndm4ed LCS (3103003-BSI) Prepared: 09/03/2015 10:03 Analyzed: 09/08/2015 11:30 Spike Source %REC RPD Anahme BeiuR Ellen PRL Uft Level Bai& %REC Limb RPD Limit 110M Total Kjeldahl Nitrogen 12 0.48 mg/L 12.0 102 90-110 Matrix Spike (3103003-1451) Prepared: 09/03/2015 10:03 Analyzed: 09/08/2015 11:32 Source: C416992-02 Spike Source %REC RPD Anahte BaN N Elm 21111. Units Loral BAGH %REC UMU RPD 1.111111 12111111. Total Kjeldahl NXMM 5.6 0.48 mWL 4.80 0.72 102 90.110 Matrix Spike (3I03003-101152) Prepared: 09/03/2015 10:03 Analyzed: 09/08/2015 11:35 Source: C509662-01 Spike Sourca %REC RPD Aoehma Rana Elm e" Unite Level agel t %REC Llalits RPD Llmlt Notes Total Kjeldahl Narogen 73 D 2.4 mg/L 4,80 66 142 90-I10 QM-05 Metrhr Spike Dup (6I03003-MSD1) Prepared: 09/03/2015 10:03 Analyzed: 09/08/2015 11:37 Source: C416992-02 Spike Source %REC RPD AnandR BARR EIM Eat. units Level &"it %REC LlmIM RPD Limit Notes Total Kjeldahl Nitrogen 5.9 0.48 mg/L 4.80 0.72 107 90-110 4 10 AN&* 3Iwoof - some Blank (3103004-BLKI) Prepared: 09/03/2015 10:03 Analyzed: 09/08/2015 12:57 Spike Source %REC RPD Anahma Bela t Elan EQL Units Level S481it %REC Limits RPD Limit M92CL Phosphorus 0.025 U 0.10 mg/L LCS (3103004-01) Prepared: 09/03/2015 10:03 Analyzed: 09/08/2015 12:59 Spike Source %REC RPD Anando BARR EIM 2QL Smite Leval Bomb %REC Limb RPD Limit )jows- Phosphorus 1.5 0.10 mg/L 1.60 95 80.120 141 r Spam (5303004-10131) Prepared: 09/03/2015 10:03 Analyzed: 09/08/2015 13:01 Source: C416992-02 Spike Source %REC RPD Anahma Result Harr ML Unite Level BLUM %REC Limits RPD haft not" Phosphorus 0.77 0.10 mg/L 0.640 0.15 97 80-120 Matrix Spike Dup (9103004-MSD3) Prepared: 09/03/2015 10:03 Analyzed: 09/08/2015 13:02 Source: C416992-02 Spike Source %REC RPD Ana lYta Bosun Elea PGL Unite Lave] jig %REC limits RPD Limit Nobas Phosphorus 0.77 0.10 mg/L 0.640 0.15 97 M120 0.4 25 Ballots 5I�A02 - HO PIREP I Blank (6109002-SM) Prepared: 09/11/2015 08:23 Anayzed: 09/11/2015 12:45 Spike Source %REC RPD ADahLte RMU[t Elea PQ.L Units Level %REC Limb RPD Limit Notes- Narete/Ntbr to as N 0.041 U 0.10 mg/L l i i i F1IrAL This report rdlates only to the sampe as rwdved *the laboratory, and may any be nepmduood in NO. Page 7 of 11 k! f www.encolabo.com I QUALITY CONTROL DATA f Parame6ato - Quality Control Batch 5AVW2.194Q PREP - Cmdawd I LCS (3I09002-BS3) Prepared: 09/11/2015 08:23 Analyzed: 09/11/2015 12:38 Spike Source %REC RPD AIlafthe Bonk Bea POL !lnh Level gft&IB %REC UMJM RPD Limit motw Nltrate/Nb to as N 1.2 0.10 rnWL 1.25 1 99 90.110 Matrht $pike (3I09002-M5i) Prepared: 09/11/2015 08:23 Analyzed: 09/11/2015 12:47 Source: C416992-01 Spike Source %AEC RPD �Oandap Bend Has 2QL Unite Level gM& %REC Umlta RPD LbA Motes NltratrJNlt ita as N 5.9 1.0 mg/L 5.00 6.87 100 90-110 Matrix Spire (5I09002-M52) Prepared: 09/11/2015 08:23 Analyzed: 09/11/2015 12:56 Source: C416992.02 Spike Source %REC RPD Anahfta RMR flag MI. M1111 Level Result %REC Llmitl RPD L(m(t jw NftWNitrlte a8 N 5.6 1.0 mg/L 5.00 0.41 U 112 90-110 QM-05 Matrix Wks Duo (5109002-14SDI) Prepared: 09/11/2015 08:23 Analyzed: D9/11/2015 12:52 Source: C416992-01 Spike Source %REC RPD Anatvto BsMdt fin MI. Lk ft Level RtMg %REC UDgk RPD Lba motes NarstaiNitrlte as N 5.8 1.0 mg/L 5.00 0.87 99 90-110 0.9 10 Batch SZ1.900f - Sama Blank (9111007-BLK1) Prepared: 09/11/2015 13:22 Analyzed: 09/15/2015 09:51 Spike source %REC RPD Anahme Bond Biw P4L Chili Level BANg %REC MMU RPD Limit not" Total K)eldahl Nitrogen 0.26 U 0.48 mg/L LCS (5I31007-BS1) Prepared: 09/11/2015 13:22 Analyzed: 09/15/2015 09:53 Spike Source %REC RPD linandas Bl3Ml$ an ML llnh Leval gann %REC LIMU RPD Limit Notew. Tote K*dandNitrogen 12 0.48 mg/l. 12.0 102 90.110 Matrix Spike (5111007-MS1) Prepared: 09/11/2015 13:22 Analyzed: 09/15/2015 09:55 Source: C416992-01 Spike Source %REC RPD ADanda R11=11 Han POL 11nu Level BWM %REC NmBa RPD Limit mom Total Kleldahl Nitrogen 5.5 0.48 mg/L 4.80 0.84 97 9D-110 Matrix Spike (5I11007-MS2) Prepared: 09/11/2015 13:22 Analyzed: 09/15/2015 09:57 Source: C503193-0IREL Spike Source %REC RAD Ananda BaRR Bea PL Mau Level gesil %REC Lialb RPD Limit NOW Toted Kjeldahl Nitrogen 6.6 0.48 mg/L 4.80 2.8 79 90.110 QM -OS Matrix Spike DuP (5111007•MSDi) Prepared: 09/11/2015 13:22 Analyzed: 09/15/2015 09:59 Source. C416092-01 Spike Source %REC RPD l aahma RMR Bas P9L Chili Level gjag %REC Nmlta RP11 LlmLt dotes Total Neldahl NI0DW 5.7 0.48 mg/L 4.80 0.84 102 90-110 4 10 Bauch 5I110M - Arm* I 1 FINAL Yhls repW relates only tD the sample as reoeMed by the laboratory, and mpy only be reproduced In fut. page 8 or 11 I www.encolabs.com QUALITY CONTROL DATA tlamical Chemistry Parameters - Quality Control Be" 'iM0" - gMnw - LMwfiiwd s Blank (SI11009-BL1(3) Prepared: 09/11/2015 09:28 Analyzed: 09/15/2015 12:15 Spike Source %REC RPD JDanda 8e.ult Elm POL Units Laval get %REC Limb RPD Lim Notes_ phosphorus 0.025 U 0.10 mp/L LCS (33ilo0WBS11 Prepared: 09/11/2015 09:28 Analyzed: 09/15/2015 12:17 Spike Source %REC RPD Ananda Result Has Pal. knits Level ReM %REC UMU& RPD Lkaft Notes Phosphorus 1.6 0.10 mp/L 1.60 100 80-120 Matrix Spike (5I11009-11415L) Prepared: 09/11/2015 09:28 Analyzed: 09/15/2015 12:18 Source: C416992-01 Spike Source %REC RPD Anna111112111111; Hao ML Units Level geau %REC LWIM RPD Phosphorus 0.90 0.10 mp/L 0.640 0.35 85 80-120 MaWx Spike Dup (5111009-114SD3) Prepared: 09/11/2015 09:28 Analyzed: 09/15/2015 12:20 Source: C416992-01 Phosphorus Spike Source %REC RONK Ban ML Laid Level Resu %REC Lhn& RPO 0.89 0.10 mp/L 0.640 0.35 84 80-120 1 I This report relates only to the sample as reodved by the laboratory, and may oniy be reproduced In full. RPD Nmlt NWMs. 25 Pape 9 Or 11 I www.encolaba.aom FLAGS/NOTES AND DEFINITIONS , B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. 6 6 J The reported value Is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRQ, adjusted for actual sample preparation data and;moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. l E The concentration Indicated for this analyte is an estimated value above the calibration range of the Instrument. This value is considered an estimate. MRL Method Reporting Limit The MRL Is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content I N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Grater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. r QM-05 The splice recovery was outside acceptance limits for the MS and/or MSD due to matrix interference. The LCS and/or LCSD were within acceptance limits showing that the laboratory is In control and the data is acceptable. , R-01 The Reporting Limit for this analyte has been raised to account for matrix interference. I I E�i �4 4� I FINAL This fePon rdabes only to the sample as received by the laboratory, and mey only be reproduced In Nil. Page 10 of 11 _� �..-� _.� � �_ •.i -� ...fir. i._ � � ]c`�.._ __......-_ ENVIRONMENTAL,CONSERVATION;. LABORATORIES CHAIWOF-CUSTODY, RECORD_ . Www erkglabs.cdM -• : • . - 1675 CaltEtnl.Pplt t?l A919 %ai..rrNll fUrk Cacnl Scorn 1 [ I. t11�-� %yab"WA t}itMrihw cl.ce-N Qi1a117o Fl.92924 �a[IornNntlo,Fl.•7^2, /f16 Cxy.Nl28.Y311. IL - 40T}BQ&•a31� Fs�(467�850i69a3 {d4)s}74,90G7Fyij4ds}y7'H�}fi�:C {9S91aGJ•3U50 £e,{9�7yM17.3i55' pg�gr:_.O. awa rums' - ca NOMB t�rnpan nL-retc/. ocibe n. ..lra �;,.tsa.� PkquesWd Twmmun_d` Times . r'IWP : R1C11 +eq-M151s ,1� 5 °"`6S'""°"'rtrio1�`� Standard - _ Expedited' ao Q 'Lo c in o m O i O - � a i !�' Q o �(. u�i M —"!i (L 07 �7 z CO. Z.. fA : .m. *" z' 'H T (L �i ?C o z p O u`�` N co, �1 s " ' 77 P d6pdl Church Fto®d F'i�aa Narr�'fJeec SEariiwater.`Testin C"STrzp. FfankGnton; NC 27526 POr!Udo" 4550648327 Tel - 043374 RRI- _Rvp t*V Cw&W Joe Udd Somplerja) Apirtrc: Athl4pion {Praal BlWiig Ccry a l Aunts Payabte sorr�lortsl - site Lbea �enr Tom Low Lab y W _ - C4' :fi99z- -- - - , Pieshr.sWm, fSoa tades> (Carre;iir as r�cres.w_•vi I:amx _ ID{Fhi'•lhknbkhbwl 03k, i(I}tMh .CpR.clWs,.. '(,pt71•lGNi Kitria: -_IcnaCOA4}j •. -Tnrnl i 19 �p111]m0tl .. Saii3pks_COtRments _ A _ iT- Outfaa -.T:- 15� 5W .16— X' Xz :X X- t-- Tmil d of r"dtahma" _&-.pk KO Pad of Da:e/nm rftwm,+sr 67 17afa+thae _ - - Cv,mwat Spot fto-i g iavey muoft 4r Pei/ 10 V•4 plow-tu +-aa Coomr ae aTamps oa - _ / -- Ccrrdi� Ilpm RrV .. ple lhtacceptablD GIWah;[iWrMOaNOw.Yaf$�So7 v9r•(�IRwg LYaler-,Se,S-aWrvYSl1•Srslaon Walh1IINFv�•••�•`� A•A"v D•�Or lOeialnc�rlvnoncsf- Ar:t-ICY H•MP r+v+00�li�x:Im[li(111 oUOQ pulpsamurrrnarls{ I!lalei M eamC4s sty b ENCQ Ids ao in semnLiratr nCA Oio.tmr+n irar eortidores i1Jcd pn It+f rwNa�a ct fia koWL UrdM p!lur a.rRleri *DgWW'O"M edsl SOn-0.16:Prds.0vation Verification, ENM-1cory C Workbrder: C416092' Projet0l Stormwaler.Testing clibric Nbv6zym'ei North Amefica.(NO008) Prpiect [honal Lqg&d, In. 31-Aug-,15116:42, L"ged�,By: AndreWS-Coons CAI s9n'4- i ype -Prew Require PH Checked'i PH Adjusted DateMme te lAdjus 'd Reagent Wed/Comments, b 2&IiLO+H2 I SO4 <2 Y N I NA _Y N -1 NA E 1250inLP-+H2s'04' 2 — Y) N I NA- ;Y'(N),NA 1 C41699242 Corte . . . . . . Zjrpe'Wiig6ht Pm,(PHY PH,.Checked'l Controli, at me PH. A ,Mlusw. !�e00e'nt,uie,,CkQmrhe.* c2 Y 1 N I Nk '-Y ( N NA E 250i-nLP.+H2SO4 -c2 Y N I Nk., 7.y rN 1 NA Rigacj&it dame M 2 ReananMawe- ID 5 Page 1: df 1 I% EFFLUENT NPDES PERMIT NO. NCS000115 DISCHARGE NO. 1 FACILITY NAME NOV02ymeS, NA Inc. CLASS OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA CERTIFIED LABORATORIES (1) Enco (2) CHECK BOX IF ORC HAS CHANGED ©0 PERSON(S) COLLECTING SAMPLES Mail ORIGINAL and ONE COPY to: ATTN: CENTRAL FILES x NIA DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) 1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY RALEIGH, NC 27699-1617 KNOWLEDGE. MONTH July YEAR 6&= 2015 COUNTY: Franklin PHONE (919) 494-3001 Joe Ladd MIN DWQ Form MR -I (1 1/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) Compliant All monitoring data and sampling frequencies do NOT meet permit requirements Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.6 of the NPDES permit. "I certtty, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Randy Green Permittee (Please print or type) _24t,99-f - S�-((? 201_65, Signi!0 of Perini a*** Date (Required unless mitted electronically) Permittee Address Phone Number a -mail address Permit Expiration Date Certified Laboratory (2) ADDITIONAL CERTIFIED LABORATORIES Certification No. Certified Laboratory (3) Certification No. Certified Laboratory (4) Certification No. Certified Laboratory (5) Certification No. PARAMETER CODES Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.ne.us/wcgs and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPI)ES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. *** Signature of Permittee: if signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 213.0506(b)(2)(D). Page 2 Date: August 12, 2015 Novozymes, NA Inc. 77 Perry's Chapel Church Rd. Franklinton, N.C. 27525 RECEIVED NCDENR Division Of Water Quality AUG 19 2015 1617 Mail Service Center Raleigh, N.C. 27699-1617 CENTRAL FILES Attn: Division Of Water Quality DWR SECTION Storm Water Sampling, NPDES Permit No. NCS000115 Dear Sir/Madam novozY mese Rethink Tomorrow Per our Tier Two requirements, regarding the exceeded benchmark in Total Suspended Solids, (TSS), our implementation of a monthly monitoring in area of concern, "Outfall I", beginning in January has resulted in three consecutive sample results that are within required benchmark range. Test results from July mark the third consecutive month that our TSS readings have been within benchmark range. With July's testing complete, and compliance established, this will conclude our monthly monitoring for Total Suspended Solids. We will continue our second of two required Storm Water sampling events prior to the end of the calendar year. Kind Regards, Joe Ladd Environmental Compliance Coordinator Environmental Services ENCO Laboratorses, Accurate. Timely, Responsive. Innovative. 202-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3315 Thursday, April 9, 2015 Novozymes North America (N0008) Attn: Joe Ladd 77 Perry Chapel Church Road Franklinton, NC 27525 RE: Laboratory Results for Project Number. [none], Project Name/Desc: 5tormwater Testing ENCO Workorder(s): C500084 Dear Joe Ladd, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Friday, March 27, 2015. Unless otherwise noted in an attached project narrative, all samples were received In acceptable condition and processed In accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted In the project narrative, This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Chuck Smith Project Manager Enclosure(s) FINAL This report relates only to the sample as receHed by the laboratory, and may only be reproduced In full. Page 1 of 10 CS � �119 www.enoolabs.aom SAMPLE SUMMARY/LABORATORY CHRONICLE talent ID: Outfall -1 Lab ID: C500084-01 Sampled: 03/27/15 11,50 Reoelved: 03/27/15 15:22 PL EPA 351.2 Hdd Datel7lmefsi 04/24/15 Prep bate/17me(sl D4/03/1S 10:58 Analysis Datel7lmefsi 04/06/15 09:24 EPA 353.2 03/29/15 11:50 03/27/15 15:54 03/27/15 17:32 EPA 353.2 D4/24/15 04/01/15 07:29 04/01/15 11:59 EPA 353.2 1VZ0117 04/03/15 09:35 04/03/15 09:45 EPA 365.4 D4/24/15 04/03/15 10:58 04/06/15 10:40 SM 254OD-1997 04/03/15 04/01/15 12:55 04/01/15 12:55 SM 52109-2001 03/29/15 11:50 03/27/15 15:14 03/27/15 15:11 SM 5220D-1997 D4/24/15 03/30/15 11:10 03/30/15 15:55 FINAL This report relates only to the sample as recelved by the laboratory, and may Onty be reproduced In full, Page 2 of 10 Suco www.eneolabs.com SAMPLE DETECTION SUMMARY Client ID: OutfaU - 1 Lab ID: C500084-01 ADandn 6saYltaE Hale H" 12L U111M PtafhsA Bbohemikal Oxygen Demand 15 2.0 2.0 mg/L SM 52108-2001 Chemical Oxygen Demand 44 10 10 mg/L SM 52200-1997 Nitrate as N 4.5 0.025 0.10 mg/L EPA 353.2 NitraWNitrlte As N 4.5 D 0.41 1.0 mg/L EPA 353.2 Nitrite as N 0.030 J 0.017 0.10 mg/L EPA 353.2 Phosphorus 0.080 7 0.025 0.10 mg/L EPA 365.4 Total KJeldahl Nitrogen 1.8 0.26 0.48 mg/L EPA 351.2 Total Suspended Solids 38 1.0 1.0 mg/L SM 254OD-1997 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 10 www.encolabs.com ANALYTICAL RESULTS Description: Outfall - I Lab Semple ID: C500084-M Received: 03/27/15 16:22 Matrix: Surface Water Sampled:03/27/15 11:50 Work Order: C500084 Project: Stormwater Testing Sampled BV:Joe Ladd Classical Chemistry Parameters Biochemical Oxygen Demand Chemical Oxygen Demand^ Nitrate as N [14797-55-8]^ Nitrate/Nltrite as N^ Nitrite as N [14797-65-03^ Phosphorus [7713-14-0]^ Total Itjeldahl Nltmgen^ Total Suspended Sollds^ BASUM B" l,Inm 15 mp/L 44 mg/L 4.5 mp/L 4.5 D mg/L 0.030 3 OVA 0.080 3 mq/L 1.8 mq/L 38 mp/L H" l!" 1151rh 1 ft Notes 1 2.0 2.0 SC270A4 SM 521OB-2001 03/27/15 15:14 JOC 1 10 10 SC30010 SM 522OD-1997 03/30/15 15:55 30C 1 0.025 0.10 5D03011 EPA 353.2 04/03/15 09:45 SHA 10 0.41 1.0 5DO1004 EPA 353.2 04/01/15 11:59 SHA 1 0.017 0.10 5C27030 EPA 353.2 03/27/15 17:32 30C 1 0.025 0.10 5DO3004 EPA 365.4 04/06/15 10:40 SHA 1 0.26 0.48 5DO3003 EPA 3S1.2 04/06/15 09:24 SHA 1 1.0 1.0 5DO1017 SM 254OD-1997 W01/15 12:55 MMR FINAL This report relates only to the sample as remNed by the laboratory, end may only be reprodwW in full. Pape 4 of 10 0 mmN64 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Baud+ 5C27024 - NO PREP Blank (SC27024-BLKI) Prepared & Analyzed: 03/27/2015 15:14 Spike Source %REC RPD Anaildae Rgsitlt ELM PQL Units Level Result %REC Limits RPD Limit Nat" Bkxhemical Oxygen Demand 2.0 U 2.0 mg/L LCS (SC27024-BSI) Prepared & Analyzed: 03/27/2015 15:14 Spike Source %REC RPD AnatlRe Result flag M Emits Level Result %REC Limits RPD Limit Notes. Blodiemlcal Oxygen Demand 200 2.0 mg/L 198 102 85-115 Duplicate (SC27024-DUP3) Prepared & Analyzed: 03/27/2015 15:14 Source: C501935-01 Spike Source %REC RPD Anal lrta 13eEult Eats P_RL units Level Result %REC Limilii RPD Limit Nntes. Bbchemical Oxygen Demand 16 2.0 mg/L 16 0.6 30 Duplicate (5C27024-DUP2) Prepared & Analyzed: 03/27/2015 15:14 Source: C501964-01 Spike Source %REC RPD ABabtin ReiLlt flag P)l Units Level Result %REC Limits RPD Limit Notes Biochemical Oxygen Demand 460 D 20 mg/L 500 7 30 Batch SC27030 - NO PREP Blank (SC27030-BLK1) Prepared: 03/27/2015 15:54 Analyzed: 03/27/2015 16:23 Spike Source %REC RPD Analfdg Result flag EM units Level FArult %REC Ltmlla RPD Limit Notes Nitrite as N 0.017 U 0.10 mg/L LCS {5CZ7030-BS3) Prepared: 03/27/2015 15:54 Analyzed; 03/27/2015 16:20 Spike Source %REC RPD Ana RUm t Eats PGL Units Level gsult %REC Lbnits RPD Limit hotes Nltrtte as N 0.99 0.10 mg/L 1.00 99 90-110 LCS (5C27030-8S2) Prepared: 03/27/7015 15:54 Analyzed: 03/27/2015 16:45 Spike Source %REC RPD _Analf!!s Result flag M units Level Sasu %REC LID1ltf RPD Limit Nobel Nitrite as N 0.97 0.10 mg/L 1.00 97 90.110 LCS (SC27030-BS3) Prepared: 03/27/2015 15:54 Analyzed: 03/27/2015 17:31 Spike Source %REC RPD Ana hRa ROsiiit Elm EQL units Level Result %REC Limits RPD Limit Ng%L Nitrite as N 0.97 0.10 mg/L 1.00 97 90-110 LCS (5C27030-6S4) Prepared: 03/27/2015 15:54 Analyzed: 03/27/2015 17:35 Spike Source %REC RPD AnalYte Result Eats P4L Units Level Result %REC Limb RPD Limit Kolas Nitrite as N 0.99 0.10 mg/L 1.00 99 90-110 Matrix Spike (SC27030-MSi) Prepared; 03/27/2015 15:54 Analyzed: 03/27/2015 16:25 Source: C502864-01 Splice Source %REC RPD Ana hda Roan Eats ROL Units Level Result %REC Limits RPD Limit Notes FINAL This report relates any to the sample as remNcd by the laboratory, ano may only be reprodumd in full. Page 5 of 10 �co www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Bahoh SC27030 - NO PREP - CDndnued Matrix Spike (5C27030-M51) Continued Prepared; 03/27/2015 15:54 Analyzed: 03/27/2015 16:25 Source: C502864-01 Spike Sauna %REC RPD An31Yt0 Result Hag M Llnits Level Hlia t %REC LA011tg RPD LlDtit Hogs Nitrite as N 0.95 0.10 mg/L 1,00 0.017 U 95 90-110 Matrix Spike Pup (5C27030-MSD1) Prepared: 03/27/2015 15:54 Analyzed: 03/27/2015 16:27 Source: C502864-01 Spike Source %REC RPD Analtrt0 Resuls Hag EQL Units Level Reau %REC Llmlu RPD LIMB Notes Nitrite as N 0.96 0.10 mg/L 1.00 0.017 U 96 90-110 1 10 Batd►i 50!0010 - Same Blank (5C30010-BLKI) Prepared: 03/30/2015 11:10 Analyzed: 03/30/2015 15:55 Spike Source %REC RPD Ana htts &GLUA Hag EQL Units Level Result %REC Limits RPD Limit NOW, Chemical Oxygen Demand 10 U 10 mg/L LCS (SC30010-13SI) Prepared: 03/30/2015 11:10 Analyzed; 03/30/2015 15:55 Spike Source %REC R1110 Ana lYtp R.es"i Hag ML Units Level Result %REC Limits RPD U111% Notes Chemical Oxygen Demand S00 10 mg/L 500 99 90-110 Martz Spike (5C30010-MSi) Prepared: 03/30/2015 11:10 Analyzed: 03/30/2015 15:55 Source: C413566-01 Spike Source %REC RPD Ana Result Hag P91 Un1b Level Result %REC L mitg RPD Limit Hogg, Chemical Oxygen Demand 2700 40 mg/L 2000 610 103 90-110 Matrix Spike Dup (3C30010-MSDl) Prepared: 03/30/2015 11:10 Analyzed; 03/30/2015 15:55 Source: C413566-01 Spike Source %REC RPD Anal Yte Rnult Hag BUL Units Level Regylt %REC Limits RPD Limit Notes Chemical Oxygen Demand 2700 40 mg/L 2000 610 105 9D-110 2 10 Batnh 5DO1004 - NO PREP Blank (SDD1004-01.11(i) Prepared: 04/01/2015 07:29 Analyzed: 04/01/2015 11:50 Spike Source %REC RPD Ana hr30 Result 19" PM Upiu Level Result %REC Ltal" RPD UM Notes Nitrate/Nitrite as N 0,041 U 0,10 mg/L LCS (5001004-851) Prepared: 04/01/2015 07:29 Analyzed; 04/01/2015 11:48 Spike Source %REC RPD Ana hda Result Hag e01 Unit: Level R4111R %REC Limits RPD Llmkt Notes Nltrate/Nltrite as N 1.2 0.10 mg/L 1125 99 90.110 Matrix Spike (SD(11004-Ut51) Prepared: 04/01/2015 0719 Analyzed: 04/01/2015 11:54 Source: C413566-01 Spike Source %REC RPD Anabtte Reim Hag eQl Units Level Resat %REC LLmitg RPD Limit dotal Nitrate/Nitrite as N 1.3 0.10 mg/L 0.513 0.82 89 90-110 QM-05 FINAL This report relates only to the sample as reeNved by the laboratory, and may only be reproduced In NIL Page 6 of 10 OF 14 www.encolahs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control aa" .001004 - NO PREP - Continued Matrix Spike pup (5D01004-MS01) Prepared: 04/01/2015 07:29 Analyzed: 04/01/2015 11',57 Source: C413366-01 Spike Source %REC RPD Arid Result flag E9L Units Lewd StGg %REC LIMJU RPD Llmlt NalL Nitrate/Nitrite as N 1.2 0.10 mg/L 0,513 0.82 66 90-110 10 10 QM-05 Rate* 5DO1017 - NO PREP Blank (5001017-BLK3) Prepared & Analyzed: 04/01/2015 12:55 Spike Source %REC RPD Anah<te Reiul flag E41 units Loved 029FAIt %REC Llmlta RPD Ltll1t Notes Total Suspended Solids 1.0 U 1.0 mg/L LCS (SD01017-051) Prepared & Analyzed: 04/01/2015 12:55 Spike Source %REC RPD Anolwte Result Elea R" Units Level Result %REC Limits RPD Limit Notes Total Suspended Solids 97 1.0 mg/L 100 97 80-120 Duplicate (5001017-DUPi) Prepared & Analyzed: 04/01/2015 12:55 Source: C413566-01 Spike Source %REC RPD Anal1[tA Result Hale P91 UAM Level gMWU %REC Llinitd RPD LIi9)t Notes Total Suspended Solids 65 1.0 mg/L 71 9 10 Duplicate (5D01017-DUP2) Prepared & Analyzed: 04/01/2015 12:55 Source: C500094-01 Spike Source %REC RPD Anahltae Seesu)t flea PM units Level Result %REC Lkab RPD Llmlt Upton Total Suspended Solids 36 1.0 mg/L 38 7 10 Rahn 5D03003 - Same Blank (5003003-BLKl) Prepared: D4/03/2015 10:58 Analyzed: 04/06/2015 09:11 Spike Source %REC RPD Ana hlSe Result flag PQL U41w Level mut %REC Llmlts RPD Limit Notes Total K)eldattl Nitrogen 0.26 U 0.48 mg/L LCS (SD03003-BS3) Prepared: 04/03/2015 10:58 Analyzed: 04/06/2015 09:13 Spike Source %REC RP0 -Ananda Rea-dt Elm P41 Unita Level Result %REC Lh IU RPD UU11111 Notes Total Neldahl Nitrogen 12 0.48 mg/L 12.0 104 90-110 Matrix Spike (5003003-MS1) Prepared: 04/03/2015 10:58 Analyzed: 04/06/2015 09:18 Source: C413566-01 Spike Source %REC RPD Anande Result flog EQL Units Level Result %REC Limits RPD Limit Notes Total Kleldahl Nitrogen 62 D 2.7 mg/L 4.79 60 45 90.110 QM-17 Matrix Spike Dup (SD03003-MSDi) Prepared: 04/03/2015 10,58 Analyzed', 04/06/2015 09,20 Source-. C41356"1 Spike Source %REC RPD Anah[ta Result flag E41 tlgitE Level Result %REC Llmit9 RPD LWH Notes Total kgeldahl Nitrogen 63 D 2.7 mg/L 4.79 60 57 90-110 0.9 10 QM-17 Ratdl SD0300w - Same FUM This report rekates only to the sample as receKed try the lauxatory, and may only be reproduced In full. Page 7 of 10 691MMIlklmco www.encolab&com QUALITY CONTROL DATA Classical Chemistry Parameters - Quaf)ty Control Balch 51WO04 - Same - Continues Blank (5D03004-BLK1) Prepared: 04/03/2015 10:58 Analyzed: 04/D6/2015 10:30 Spike Source %REC RPD Ana hde 8C4illt H" 2QL 191W Level %REC llrnits RPD UIULt Nolms Phosphorus 0.025 U 0.10 mg/L LCS (51303004-8S1) Prepared: 04/03/2015 10:58 Analyzed: 04/06/2015 10:31 Spike Source %REC RPD Anal sewn 14aR EAL limb Level gesul %REC Witi RPo u1nit Notes Phosphorus 1.5 0.10 mg/L 1.60 92 80-120 Matrix Spike (5D03004-MS1) Prepared: 04/03/2015 10:58 Analyzed: 04/06/2015 10:35 Source: C413566-01 Spike Sou %REC RPD Anatltfe ResufZ flag PD1. Unlu Level get %REC Lbb RPD LiBfIL Notes Phosphorus 7.5 D 0.59 mg/L 0.640 7.3 43 60-120 QM-17 Matrix Spike pup (SD03004-MSD1) Prepared: D4/03/2015 10:58 Analyzed: 04/06/2015 10:36 Source*C413366-01 Spike Source %REC RPD Ann!][fe Result flag P_Ql. 141J i Level gesu%REC LLm& RPD l.jluft Notes Phosphorus 7.6 D 0.59 mg/L 0.640 7.3 47 80-120 0.3 25 QM-17 F1nni. This report relates only to the sample as received by the laboratory, and may only be neproducad In full, Page 8 or 10 AV- ENCO Laboratorse-S Accurate. Timely. .Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Thursday, May 14, 2015 Novozymes North America (N0008) Attn: Joe Ladd 77 Perry Chapel Church Road Franklinton, NC 27525 RE: Laboratory Results for Project Number: [none], Project Name/Desc: Stormwater Testing ENCO Workorder(s): C500085 Dear Joe Ladd, Enclosed Is a copy of your laboratory report for test samples received by our laboratory on Friday, May 1, 2015. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed In accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative, This report shall not be reproduced except In full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further Information, please do not hesitate to contact me. Sincerely, Chuck Smith Project Manager Enclosure(s) FINAL This report relates only to the sample as rcceWed by the laboratory, and may only be reproduced M rull. Page I of 7 www.encolabs.com SAMPLE SUMMARY&ABORATORY CHRONICLE Client to: Outran -1 Lab to: C500085-01 Sampled: 05/01/15 09:00 Recelved: 03/01/15 16.30 Parameter Hold Date(Timefs4 Prep DaWITlme(s)Analysis Date/Tlme(s] SM 2540D-1997 05/08/15 05/05/15 09:09 05/05/15 09:09 FINAL This report relates only to the sample as r"hmd py the laboratory, and may only be reproduced In full. Pepe 2 of 7 www.encolabmom SAMPLE DETECTION SUMMARY Client ID: Outfall -1 Lab IDt CSOOCSS-01 ADanda Results au H" RQL llnu Method NOWS Total Suspended Solids mg/L SM 25411D•1997 FINAL This report relates only to the sample as receWed by the laboratory, and may only be reproduced In full. Pape 3 of 7 C, wwi arl rrr► www.encolabs.com ANALYTICAL RESULTS Description: Outfall - 1 tab Sample ID: C500085-01 Received: 05/01/15 16:30 Matrix: Surface Water Sampled:05/O1/15 09:00 Work Order: C500085 Project: StormwaterTesting Sampled By. Joe Ladd Classical Chemistry parameters ^ - BWO Cary C-OW arxlpta (AC 5Y11 Results an Units RE H" EI L @etch Method head IN lotus Tobl Suspended SolldaA 46 mp/L 1 10 10 SE05004 SM 2540D-1997 05/05/15 09:09 MMR d FINAL This report relates only m the sample as receNcd by the laboratory, and may only be reproduced in full. Faye 4 of 7 1�0-0) www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch SE05004 - NO PREP Blank (SE05004-OLK1) Prepared & Analyzed: 05/05/2015 09:09 Spike Source %REC RPD Ana hds Result E1w P41 knits Level Result %REC 1.111301(ts RPD 1.1111111 ILL Total Suspended Solids 2.5 U 2.5 np/L LCS (SE05004-653) Prepared & Analyzed: 05/05/2015 09:09 Spike Source %REC RPD AnahCEa Result Ela2 PDl Dill Level Result %REC Lim RPD khm Notes Total Suspended Solids 97 2.5 mg/L 100 97 80-120 Duplicate (3E05004-DUP1) Prepared & Analyzed: 05/05/2015 09:09 Source: C50 9"2 Spike Source %REC RPD Analllt Result Flan e4.L knits Level Result %REC LIB RPD Lwa dotes Total Suspended Solids 390 62 mg/L 380 3 20 Duplkate (SEOSO04-DUP2) Prepared S Analyzed: 05/05/201S 09:09 Source: C505434-02 Spike Source %REC Analyts RO5Ult flog M Units Level Result %REC Limits RPD Total Suspended Solids 5100 500 mg/L 4500 13 RPD Llmlt dates 20 FINAL This report relates only to the sample as receJvad by the laWratory, and may only he reproduced In full. Pape 5 of 7 Nu Iq - SS 5C*tI9)i lS ENCO Laboratories Accurate, Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919A67.3515 Wednesday, August 5, 2015 Novozymes North America (NO008) Attn: Joe Ladd 77 Perry Chapel Church Road Franklinton, NC 27525 RE: Laboratory Results for Project Number: (none], Project Name/Desc. Stormwater Testing ENCO Workorder(s): C309405 Dear Joe Ladd, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Friday, July 24, 2015. Unless otherwise noted in an attached project narrative, all samples were received In acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained In this report are in compliance with NELAC standards, except as noted in the project narrative. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Chuck Smith Project Manager Enclosure(s) FINAL This iePon relates only to the sample as received by the laboramry, and may only he reproduced in full, I Page 1 of 7 NCO www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Cllent ID: outra0 -1 Lab 1D, C509405-01 Sampled! 07/23/15 11:50 Received: 07/24/15 06:37 Parameter Hold DaWT1mef4j EMU Datlinmefol SM 254OD-1997 07/30/15 07/27/15 11:00 07/27/15 11:00 FINAL This report relates only to b* sample as rccePeW by the laboratory, and may only be reproduced In full. Page 2 of 7 www.anoolabs.com SAMPLE DETECTION SUMMARY Client ID., Outrall -1 Lab ID. C509405-01 A09hU H41Llts an Hu EQL U= Method Notes Total Suspended Solids 3.3 3.3 mp/L SM 254OD•1997 FINAL This repot relates only t0 the sample as received try the laboratory, and may any be reproduced In full. I Page 3 Of 7 .rrr. N ww �r www.encolabs.com ANALYTICAL RESULTS Description: Outfall - 1 Lab sample I0:C509405-01 Recehred: 07/24/15 08:37 Matrix: Surface Water Sampled:07/23/15 11:50 Work Order: C509405 Project: Stormwater Testing Sampled sy:]oe Ladd Maslow Classical Chemistry Parameters Bessltts an MMM t}E M E L datrh Heumd 6nak7ed 21 Hdw Total Suspended Sollds^ 14 mg/L 1.33 3.3 3.3 5G27003 SM 2540D-1997 07JZ7/15 11:00 MMR FINAL This report relates only to the sample as McWvW by the laboratory, anC may only be rewad=W in rui6 Page 4 Of 7 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Sofx* SC27003 - NO PREP Blank (5627003-BLKI) Prepared & Analyzed: 07/27/2015 11:00 Spike Source %REC RPD AnandO Result lie0 P4L UA)ts level Read %REC LLMb RPD LIBI(t Notes Total Suspended Solids 2,5 U 2,5 mg/L LCS (SG27003-BSI) Prepared & Analyzed: 07/27/2015 11:00 Spike Source %REC RPD Anal Y±a Result Elm POL UAlb Level Resu %REC Limits RPD Lind Kota@ Total Suspended Solids 94 2,5 mg/L 100 94 80-120 Duplicate (5627003-OUPI) Prepared a Analyzed: 07/27/2015 11:00 Source: C508053-01 Spike Source %REC RPD Anal Result fin PQL Units Level Result %REC Limits RPD L(mlt KQtaq- Total Suspended Solids 230 50 mg/L 220 4 20 Duplicate (5627003-DUP2) Prepared & Analyzed: 07/27120i5 11:00 Source., C406179-01 Spike Source %REC RPD Anabfts Result Elan P-QL units Level Resin %REC Limits RPD LIMB Notes Total Suspended Solids 180 12 mg/L 170 6 20 FINAL This report relates only to the sample as receNed by the laboratory, and may only be reproduced in full. I Page 5 Of 7 I y� 'yTy� T� F; I Date: July 6, 2015 Novozymes, NA Inc. 77 Perry's Chapel Church Rd. Franklinton, N.C. 27525 NCDENR Division Of Water Quality 1617 Mail Service Center Raleigh, N.C. 27699-1617 Attn: Division Of Water Quality Storm Water Sampling, NPDES Permit No. NCS000115 Dear Sir/Madam novozY mes,, Rethink Tomorrow RECEIVED AUG 19 2015 CENTRAL FILES DWR SECTION Per our Tier Two requirements, regarding the exceeded benchmark in Total Suspended Solids, (TSS), our implementation of a monthly monitoring in area of concern, "Outfall I", beginning in January have resulted in "No Flow" for the month of June. We therefore were unable to collect a sample for this month. We plan to continue to diligently with our monthly monitoring for the parameter of TSS until we obtain three consecutive sample results within the benchmark range. Kind Regards, Joe Ladd Environmental Compliance Coordinator Environmental Services C7) EFFLUENT NPDES PERMIT NO. NCS000115 DISCHARGE NO. 1 FACILITY NAME NOVOZymes, NA Inc. CLASS OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA CERTIFIED LABORATORIES (1) Enco (2) CHECK BOX IF ORC HAS CHANGED 0 PERSON(S) COLLECTING SAMPLES Mail ORIGINAL and ONE COPY to: MONTH May YEAR 2015 COUNTY: Franklin PHONE (919) 494-3001 Joe Ladd ATTN: CENTRAL FILES x NIA DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) 1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY RALEIGH, NC 27699-1617 KNOWLEDGE. mmmmmEmmm DWQ Form MR -I (11/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements �- (including weekly averages, if applicable) Compliant All monitoring data and sampling frequencies do NOT meet permit requirements Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part Il.E.6 of the NPDES permit. "I certity, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Randv Green Pertnittee (Please print or type) Signatu f Permitt ** Date (Required unless su mitted electronically) Permittce Address Phone Number e-mail address Permit Expiration Date Certified Laboratory (2) Certified Laboratory (3) Certified Laboratory (4) Certified Laboratory (5) ADDITIONAL CERTIFIED LABORATORIES PARAMETER CODES Certification No, Certification No. Certification No, Certification No. Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.us/was and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box ifno discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. *** Signature of Permittee: if signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 2B .0506(b)(2)(D). Page 2 EFFLUENT NPDES PERMIT NO. NCS000115 DISCHARGE NO. 1 FACILITY NAME Novozymes, NA Inc. CLASS OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA CERTIFIED LABORATORIES (1) Enco (2) CHECK BOX IF ORC HAS CHANGED ©0 PERSON(S) COLLECTING SAMPLES Mail ORIGINAL and ONE COPY to: ATTN: CENTRAL FILES x NIA DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) 1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY RALEIGH INC 27699-1617 KNOWLEDGE. MONTH March YEAR I 2015 COUNTY: Franklin PHONE (919) 494-3001 Joe Ladd L11IM11111111M.": DWQ Form MR-1 (11/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) Compliant All monitoring data and sampling frequencies do NOT meet permit requirements Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part ILE.6 of the NPDES permit. "1 certity, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Randy Green Permittee (Please print or type) Sign ur of Perm' ee*** Date (Required unless Wbmitted electronically) Permittee Address Phone Number e-mail address Permit Expiration Date Certified Laboratory (2) ADDITIONAL CERTIFIED LABORATORIES Certification No. Certified Laboratory (3) Certification No. Certified Laboratory (4) Certification No. Certified Laboratory (5) PARAMETER CODES Certification No. Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o,enr.state,nc.us/wqs and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. *** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 213.0506(b)(2)(D). Page 2 Date: January 31, 2015 Novozymes, NA Inc. 77 Perry's Chapel Church Rd. Franklinton, N.C. 27525 NCDENR Division Of Water Quality 1617 Mail Service Center Raleigh, N.C. 27699-1617 Attn: Division Of Water Quality novozY mes, Rethink Tomorrow RECEIVED MAY 0 4 Z515 CENTRAL FILES DWR s C� ON f"�r'I CMA Storm Water Sampling, NPDES Permit No. 'NCS000115 Dear Sir/Madam Per our Tier Two requirements, regarding the exceeded benchmark in Total Suspended Solids, (TSS), our implementation of a monthly monitoring in area of concern, "Qutfall 1", beginning in January have resulted in "No Flow" for the month of January. We therefore were unable to collect a sample for this moth. We plan to continue to diligently with our monthly monitoring for parameter of TSS until we obtain three consecutive sample results within the benchmark range. Kind Regards, )tm awl Joe Ladd Environmental Compliance Coordinator Environmental Services Environmental Conservation LaboraPories, Inc. • 102-A Woodwlnds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Monday, February 21, 2011 Novozymes North America (N0008) Attn: Joe Ladd 77 Perry Chapel Church Road Franklinton, NC 27525 RE: Laboratory Results for Project Number: [none], Project Name/Desc: Outfall 1 Sampling ENCO Workorder: C101326 Dear Joe Ladd, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Friday, February 11, 2011. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Chuck Smith Project Manager Enclosure(s) The total number of pages in this report, including this page is 13. www.encolabs.com i • �uco www.encolabs.com Parameter Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Tlme(s) ..--..--�.......................... ........................ . -- . ----- ------------- ---------- EPA 200.7 08/09/11 02/16/11 10:16 2/17/2011 11:27 EPA 200.7 08/09/11 02/16/11 10:16 2/17/2011 11:29 SM 2540D 02117/11 02/14/11 12:35 2/14/2011 12:35 Parameter ----------- Hold Date/Time(s) ------------ -- -- - ...... ................. Prep Date/Time(s) I......... . Analysis Date/Time(s) ........... . ....... I-------...... EPA 200.7 08/09/11 02/16/11 10:16 2/17/2011 11:31 EPA 200.7 08/09/11 02/16/11 10:16 2/17/2011 11:34 SM 2540D 02/17/11 02/14/11 12:35 2/14/2011 12:35 Page 2 of 13 (S. NS gg www.encolabs.com --tent ID: Sample A Lab�ID: C1o1326_01 '�"'�* Analyte Results Flag MDL PQL Units Method Notes ---- ------------------------------------ Aluminum - Total ............... 218 . -- -- ....................... 17 100 •-----........ ugX EPA 200.7 Aluminum - Dissolved 49 J 17 100 ug/L EPA 200.7 Copper - Dissolved 18.1 1.60 10.0 ug/L EPA 200.7 Copper - Total 22.9 1.60 10.0 ug/L EPA 200.7 Iran - Dissolved 346 22 50 ug/L EPA 200.7 Iran - Total 509 22 50 ug/L EPA 200.7 Total Suspended Solids 2.7 1.0 1.0 mg/L SM 2540D Zinc - Total 217 3.8 10.0 ug/L EPA 2D0.7 Zinc - Dissolved 197 3.8 10.0 ug/L EPA 200.7 Analyte Results Flag MDL PQL Units Method Notts ........ .... .................. .--------- Aluminum - Total -- -- ............................ 249 -- 17 . •.... .-................ 100 ug/L ...-............... EPA 200.7 Aluminum - Dissolved 17 3 17 100 ug/L EPA 200.7 Copper - Dissolved 17.8 1.60 10.0 ug/L EPA 200.7 Copper - Total 22.1 1.60 10.0 ug/L EPA 200.7 Iron - Dissolved 320 22 50 ugIL EPA 200.7 Iron - Total 529 22 50 ug/L EPA 200.7 Total Suspended Solids 17 1.0 1'0 mg/L SM 2540D Zinc - Total 227 3.8 10.0 ug/L EPA 2003 Zinc - Dissolved 188 3.8 10.0 ug/L EPA 2003 Page 3 of 13 www.encolabs.com ANALYTICAL RESULTS Description: Sample A Lab Sample ID: C101326-01 Received: 02/11/11 07:50 Matrix: Waste Water Sampled: 02/10/11 16:00 Work Order. C101326 Project: Outfall 1 Sampling Sampled By. Joe Ladd Metals by EPA 200 Series Methods ..... ^ ENCO Cary rertiixd a-W [NC 591] Analog rCAS Numberl Resin Ebw Vohs 2E HU MU Batch Meth A[MlYZed $y � Aluminum [7429-90-51 ^ 218 ug/L 1 17 100 1B16014 EPA 200.7 02/17/11 11:29 1DH Copper 17440.50-81 ^ 22.9 ug/L 1 1.5C 1010 1B16014 EPA 200.7 02/17/11 11:29 1DH Iron [7439-09-6] ^ 509 u9/1- 1 22 50 1B16014 EPA 2001 02/17/11 1129 7OH Zinc [7440.66.6] ^ 217 ug/L 1 3.0 10.0 IB16014 EPA 200.7 02/17/11 11:29 ]DH Page 4 of 13 i • - www.encolabs.com Description: Sample A Lab Sample ID: C101326-01 Received: 02/11/11 07:50 Matrix: Waste Water Sampled: 02/10/11 16:00 Work Order: C101326 Project: Outfall 1 Sampling Sampled By: Joe Ladd Metals (Dissolved) by EPA 200 Series Methods ------------------ ---.................. ............................ --.............................. ...................... -.,-...-..-.. ^ e X Cary Cert A'd analyte (NC 591) Analog [CAS Numbcd gesu11s flag 1!n[1s pf MU MAL A=h Method AnalWod gx 1y= Aluminum [7429.90-51 ^ 49 J ug1L 1 17 100 LB16014 EPA 200.7 02/17/11 11:27 JDH Copper [7440-50.81 ^ 18.1 ug/L 1 1.60 10.0 LB16014 EPA 200.7 02/17/11 11:27 JDH Iron [7439-89-fi] A 346 ug1L 1 22 50 1B16014 EPA 200.7 02117/1111:27 JDH Zinc [7440.65.6] ^ 197 ug/L 1 3.8 10.0 LB16014 EPA 200.7 02117/11 11:77 JDH Page 5 of 13 Ce NS gg www.encolabs,com Description: Sample A Lab Sample ID: C101326-01 Received: 02/11/11 07:50 Matrix: Waste Water Sampled: 02/10/11 16:00 Work Order: C101326 Project: Outfall 1 Sampling Sampled By: Joe Ladd Classical Chemistry Parameters ... ... ............................. ....... ............ ........... ^ - ENCO ary certified anayie[NC 591] Analyte NA5 Numberl gam] Elg Units Df HU MU @azb Method Analyzed BY Jr pto Total Suspended Solids [ECL-0169] ^ 2.7 mp11- 1 1.0 1.0 1B14009 SM 2540D 02114/11 12:35 KLl TM report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 6 of 13 www.encolabs.com Descriptions: Sample B Lab Sample ID: C101326-02 Received: 02/11/11 07:50 Matrix: Waste Water Sampled: 02/10/11 16:15 Work Order, C101326 Project: Outfall 1 Sampling Sampled By: Jae Ladd Metals by EPA 200 Series Methods .................................................... ............................. ................................................... ^ - ENCO Cary -rorvd a-Ve (NC 5911 AnalvW [CAS Numberl Sys DU Uhm pF M & Bin Batch Method Analyzed lac JNotes Aluminum [7429-90-5] ^ 249 ug/L 1 17 100 1916014 EPA 200.7 02/17/11 11:34 )DH Copper [7440-50-8] ^ 22.1 ug/L 1 1,60 10.0 1516014 EPA 2003 02/17/11 11:34 10H Iron [7439-89-61 ^ 529 ug/L 1 22 50 1B16014 EPA 200.7 02/17/11 11:34 7DH Zinc [7440-66.61 ^ 227 ug/L 1 3.8 10.0 1B16014 EPA 2003 02/17/11 11:34 )DH Page 7 of 13 • 0 Ce gg www,encolabs.com Description: Sample B Lab Sample ID: C101326-02 Received: 02/11/11 07:50 Matrix: Waste Water Sampled: 02/10/11 16:15 Work Order: C101326 Project: Outfall 1 Sampling Sampled By: Joe Ladd Metals (Dissolved) by EPA 200 Series Methods .............. ... .. ^ - ENCO Cary -r0'fied analyze (NC 59IJ Analvte rCAS Numberl Results Flag Units DE Via Vin Batch Meth Analyzed lix lYs?Ss� Aluminum (7429.90-51 ^ 17 1 ug/L 1 17 100 LB16014 EPA 200.7 02/17/11 11:31 JDH Copper [7440.50-8] ^ 17.8 ug/L 1 .1.60 10.0 LB16014 EPA 200.7 02/17/11 11:31 JDH Iron [7439-89-51 ^ 320 ug/L 1 22 50 IB16014 EPA 200.7 02117/1111:31 JDH Zinc [7440-66-61 ^ 188 ug/C 1 3.8 10.0 1816014 EPA 200.7 02/17/11 11:31 JDH Page 8 of 13 rlrr rrr www.encolabs.com Description: Sample B Lab Sample ID: C101326-02 Received: 02/11/11 07:50 Matrix: Waste Water Sampled: 02/10/11 16:15 Work Order: C101326 Project: Outrall 1 Sampling Sampled By: ]De Ladd Classical Chemistry Parameters ------------------------------ -------------- --------------------•......---.-- --.._.... --••- .................. ..-- --.._ .. ^ - ENCO Cary certifrEd aW4 a (NC 5911 Analvte [CAS Numberl $esul ELAG 1l= 9E HU MU Batch Meth Analyzed JAY lYQw Total Suspended Solids [ECL-01691 ^ 17 mg/L 1 1.0 1.0 1814009 SM 2S40D 02/14/11 12:35 KU This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 9 of I3 www.encolabs.com QUALITY CONTROL Metals by EPA 200 Series Methods - Quality Control Batch I816014 - EPA 3005A Blank (1B 16014-BLK1) Prepared: 02/16/2011 10:16 Analyzed: 02/ 1712011 11:12 Aluminum 17 U 100 ug/L Copper 1.60 U 10.0 ug/L Iron 22 U 50 ug/L Zinc 3.8 U too ug/L LCS (1B16014-BSI) Prepared: 02/16/2011 10:16 Analyzed: 02/17/2011 11:04 Aluminum 5420 100 ug/L 5000 100 85-115 Copper 273 10.0 Ug/L 250 109 85-115 Iron 5440 50 ug/L 5000 109 8S-115 Zinc 549 10.0 ug/L 500 110 85.115 Matrix Spike (1816014-MS3) Prepared: 02116/2011 10:16 Analyzed: 02/17/2011 11:19 Source: CL00$25-01 Aluminum SOO 190 ug/L 5000 18 108 75-125 Copper 263 10.0 Ug/L 250 1.60 U 105 7S-12S Iron 5260 50 4/L 5000 41 104 75-125 Zinc 537 10.0 u0/1. 500 11.8 105 75.125 '-" '-"'.................................. Matrix Spike pup (1615014-11WISDI) "'............. " " .................'- ...... "'............. --.._.............I..., ........ Prepared: 02/16/2011 10:16 Analyzed: 02/17/2011 11:20 Source:C100525-01 Aluminum 5220 100 u9/L 5000 18 104 75-125 3 25 Copper 262 10.0 Ug/L 250 1.60 U 105 75.125 OA 25 Iron 5240 SO ug/L 5000 41 104 75.125 0.4 25 Zinc - ................................... 536 --I•---•-----.-.-..-.. 10.0 .......................... ag/L 500 11,8 --...--.. 105 ............................ 75-125 0.2 25 ........... ...-- Metals (Dissolved) by EPA 200 Series Methods - Quality Control Batch I816014 - EPA 3005A Blank (1B16014-BLKI) prepared: 02/16/2011 10:16 Analyzed: 02/17/2011 11:12 Aluminum 17 U 100 ug/L Copper 1.60 U 10.0 ug/L Iron 22 U 50 ug/L Zinc 3.8 U 10.0 ug/L ......................................................... ............................................ I ....................... .- .-.... LCS (1B16014-BSI) Prepared: 02/16/2011 10:16 Analyzed: 02/17/2011 11:04 Aluminum Copper 5420 100 ug/L 5000 108 85-115 273 10.0 ug/L 250 109 85-115 Page 10 of 13 www.encolabs.com QUALITY CONTROL Metals (Dissolved) by EPA 200 Series Methods - Quality Control Batch I8I6014 - EPA 3005A LCS (016014-BSI) Continued Prepared: 02/16/2011 10:16 Analyzed: 02/17/2011 11:04 Iron 5440 50 ug/L 5000 109 85-115 Zinc 549 10.0 ug/L 500 110 85.115 --'-......'--'.................................'....................._................................... Matrix Spike (IB16014-MS1) Prepared: 02/16/2011 10:16 Analyzed: 02/17/2011 11:19 Source: C10052S-01 Aluminum 5400 100 ug/L 5000 18 108 75-125 Copper 263 10.0 ug/L 2S0 1.60 U 105 75-125 Iron 5260 50 ug/L 5000 41 104 75-125 Zinc 537 10.0 ug/L 500 11.8 105 75-125 Matrix Spike Dup (1B16014-MSD1) Prepared: 02/16/2011 10:16 Analyzed: 02/17/2011 11:20 Source:C100S25-01 'r Spike %REC)' 'RPD'� <. 3Flag. Ana Rewlt; MRL Units, Y Le el. Result'' ; 9/aREC Limits RPD. Limit. r Not09 ,' Aluminum 5220 100 ug/L 5000 18 IN 75-125 3 25 Copper 262 10.0 ug/L 250 1.60 U 105 75-125 0.1 25 Iron 5240 5C uglL 5000 41 104 75-125 0.4 25 Zinc .........................'-.............................................._..._......_........................_..........------------..... 516 10.0 ug/L 500 11.8 105 75-125 0.2 25 Classical Chemistry Parameters - Quality Control Batch 1614009 - NO PREP Blank (014009-BLKI) Prepared & Analyzed: 02/14/2011 12:35 Total Suspended Solids 1.0 U 1.0 mg/L LCS (1B14009-BSI) Prepared & Analyzed: 02/14/2011 12:35 Total Suspended Solids 83 1.0 mg/L 60.0 104 90-122 Duplicate (IS14009-DUPi) Prepared & Analyzed: 02/14/2011 12:35 Source: C015873-01 Total Suspended Solids 1800 1.0 mg/L 1800 2 25 Page l l of 13 CS NS CEO www.encolabs.com B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. J The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. B The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. QB-01 The method blank had a positive result for the analyte; however, the concentration in the method blank is less than 10% of the sample result, which minimizes the impact of the deviation. Pagc 12 of 13 w ENVIRONMENTAL CONSERVATION LABORATORIES CHAIN -OF -CUSTODY RECORD www.encolabs.com �a xtl Industrial Ct. Or. 4Ja(*WM11a.FL ID775C nlial Red orOdarWo FL 32824 3221 G6oeq Gwy NWC�a1e1lyds (4O7) 826.5314 Fax (4071850-W5 (91>412963007 Fax 1gD41296-210 191 ej 457-Ja90 FaJ (919)4fi7-3515 Page -j— of t Gent Name Pm Nu '�noneq RJVaesled AmlyJes Requested Turnaround Nova4mes North America (NO008) Times N a-pih+e?4a� to LL Address 77 Perry Chapel Church Road �6tiFa�Sampling N p auepaxe by Me fatifty CitylStlZp - Franklinton, NC 27525 PD Jl allig Irdo � N o —Standard Tel (919) 494-3000 JoeLadd L � (D LL � — Expedited Sampletts)Nor+o.AlMafianlPr;•y B �q �rlriPa _ HtS y able U U) Due —1-1— ' U ( SBmaledal SI9 ; See Loraaon!Tine Zane Q Q ' °C101:32fi_ - - - Fr�enatl- (Se Codes! Ieanlline as rfte y, of Catlectiar Matrix 1O1w r of ttamJ SampleID(FWdldentificaeon) Collection Dale Time CamplGrah (wemdes) Cmranars Sample Comments %fi:, r_ VIfVV t1 X X X - - AA c t t 1; �f 10 l l 1Lc D �r r YVW 2 0 X X X Ww � X X X r J� �� ,-a <— Total of Containers, SaVa NA Prepared By oatmlfvne Reinoutseed By 7+ Dale,Te F;acakvd By: pale•T�e Can¢nent&Gpemd Re" " n RGdngWj -0d By Dale.?me lW.—d By [err ,. ,rfi j:•I -AG Li►ieId c'r(1>r+S f1S6 k? nprisaed By DalwTtne Re=.d By 9aiariuna 'I<5�0[IfF{ �4A id 7EG¢ . 14 Cooler J's a iemQJ on Recep Conddim llpmn Rerripl G1 Y d l ail 2r w l rJ{ a `1 r AccePtade Unacceptable Matrix: GW-Gmxdwater Sd.Sd OW-Dm*k p Water SE-Setlmnt SWSurlace Water Y W-Wastewater A -Air O9thm (delai n mnmerds) Pmwrvallan:l-ke WHO N-HND3 54112504 M044X N 0,40lher(deral in comments) Naw : AI samples submleed m ENCO Leta ary n homiarlce x m the terms end curdtirrs listed m the rrn:rrc at mG Corot, W ess Prior arisen ayeemanls a.isi • 07 County: FRANKLIN River Basin TAR ,Report To RROS Collector: A-ROMANSKI Region: RR0 Sample Matrix: SURFACFWATER Lac. Type; RIVERISTREAM Emergency Yes/No' COC Yes/No: . I I Location 10: NOVOUPSTRM Sample ID: • 1 AB66107 A PO Number 1OW9750 Date Received: I 1210212010 Time Received: .10:56 Labworks Logln[D SFAATHiS. $ Report Ganeraczd- 1110/11 Date ; . 101110/2011 �y sid D. 7 Loc. Descr.: NOVOBUFFCK-5. 12010 Collect Time: 12.-30Sample Depth . Result/ Method Analysis CAS AnalYte Name P Units Q60fier Validated by Reference Date LAB temperature at receipt b�. lab",. Sample t -C 12/2/10 SMATHIS- MIC BOD, 5-Day in liquid� 2, 2 U G8 mg/L APHA521013, 12/11/10 MOVERMAN WET Ion Chromatography $Q, TITLE mgll- EPA 300.0 12/6110 CGREEN Chloride 1 17 mg/L EPA 300.0 1216/10 CGREEN Fluoride 0.4 0.4 U mg/L EPA 300,0 121W10 CGREEN Sulfate '2 ;t- 2.0 mgIL EPA 300.0 1216110 CGREEN Total Dissolved Solids in.liquid w12.- 98, mg/L APHA254OC-18TH 12121I.0 CGREEN NUT NI-113'as N. in liquid 0.02 q' 0.02 U mg/L as N LeCI0-107-06-1-J 1. 12t3110 CGREEN Total Kjeldahl N as IN in liquid. 0.5 mg/L as N Larha1107-06-2-H 1217110. CGREEN NO2+NC3 as N in liquid ;t-Ail 2.0, mg)L as N LaclO.107-04-1-c 1218/10 CGREEN' Phosphorus -total as P in liquid 0.02 0.10 mg/L as P Lac10-I 15-01-1 EF 12/3110 CGREEN MET 74 40-22-4 Ag by,ICPMS 5.0 U, ug/L EPA 200.8 12/8/10 ESTAFFORDI 7429.90-5 Al by ICP 50 72 ug]L EPA 2007 12191110 ...ESTAFFORD1 7440-38-2 As by ICPMS 2.. 2.0 U ug/L EPA 200.8 i 1218110 ESTAFFORDI 74.40-38-3 Ba by .ICP ug1L EPA 200.7 1218110 ESTAFFORDI 7440-41-7 Be by ICP 5.0 U ug/L EPA 200.7 1219/10 ESTAFFORDI 7440-70-2 Ca by ICP 0.1 9.3 mg1L EPA 200.7 12/8/10 ESTAFFORDI 744043-9 Cd by ICPMS. 0i 1.0 U ug/L EPA 200,8. 1218/10 ESTAFFORDI 7440-48-4 Cobalt by ICP 50 -,%: ?'t .50 U. U011- EPA 200.7 i 12/9110 ESTAFFORDI 744"7-3 Cr by ICPMS- 10. 10 U- ug/L EPA 200.8 1218110 ESTAFFORDI. 7440-50-8 Cu by ICPMS 2, 2.0 U ug/L EPA 200.8 1 12/8110. ESTAFFORDI .7439-89-6 Fe by ICP '50 310 up/L. EPA 200'.7 1219/10 ESTAFFORD1 7439-97-6 Hg 245.1' ''0.20 U ug/L EPA 245.1 12/14/10 ESTAFFORD1 7440.09-7 K by ICP mg/L EPA 200.7 1218110' ESTAFFORD1 7439-93-2 Li ICP 26 .25 U ug/L EPA 200.7 1218110 ESTAFFORDI 7439-95-4 Mg by ICP mg/L EPA200.7 1218110. ESTAFFORDI 7439-96-.5 Mnb ICIP 10 24 ugjL EPA 200.7- 12/9110 ESTAFFORDI 7439-98-7 Mo by ICPMS 10, IOU EPA 200.8 R.1 2/811 d ESTAFFORD1; Laboratory For m deteged descripUm ol the qualfler owes rife Page of-2 'Lull NG DENR R61.0ftional office `r .NC (D'WQ Laboratory Section *saka . ! Location ID: NOVOLIPSTRM .; Sample ID: AB66107 Collect Date: 11210112010 Collect Time:: 12:30 MET :. .: w a#iw • '': Resultl.-�'; Method Analvsis Validated by CAS .# Analyte Name ;.;t..J P U:e. `°,'r, ., r uaGfier. '' .. Units Reference Date 7440-23-5 Na by ICP ` i, 0.1 14 me 1L EPA 200.7 1218110 , ESTAFfpRD1 7440-02-0 . Ni by ICPMS ; .:• ., . • :' "" ' `.'1Q ",-:.,:,,,, `; le, 10 U ' ` u01L . EPA 200.81 1 12/8110 ESTAFFORDI 7439-92-1 Pb by ICPMS 10 ":?f;•c, vI :..10:�1, ug1L EPA200.0 12/8110 ESTAFFORDI 7440 36 0 Sb by'ICPMS . • ;- — 10 10 U ug/L EPA 200.8 1216110 ESTAFFORD1 778249-2 Se by ICPMS. 5 ! 5.0 U ug(L EPA 200.6 1218110' ESTAFFORDI 7440.31-5 Sn by ICPMS 1 Q..., . ' , .'Ya 10 U ug1L ..: EPA 200.8_ ! 12/8110 ESTAFFORDI 7440728-0 Thallium (71) ICPMS. `ti°:10`,?� f.:'; .-!``'f'''''% IOU uglL EPA200.8 12/8110 ESTAFFORDI 7440-326 Ti (Titanium) by iCP ' ,t:' 1. 1Oi'?:`w�?.' '` "7O.U.' ug1L EPA200:7 12J8110 ESTAFFORDI " 7440-62-2 V by ICP 25 25 U :' ug1L EPA 200.7 12/9110 ESTAFFORDI 744o-sfi-6 Zn by ICPMS 10 Ii'�- '-IO U. ugfL `` EPA.200.8 1218110 ESTAFFORDi :i. . J �� • ' ��':1. - 'ply_.:. • -' f .. - ` . i •,- � : �� -11i .. it •. ' 'Laboratory Section>>'1623 Mall Sece Center, Raleigh, NC 27699-1023 t919j 733.3908 !t l ' n', ' For a detailed desvlption of the qualifier codes mfer to n, It OAh tvwfoa ffirt AMOData Q,al0e I o-' -Page 2 of 2 .. r ',>:-:. COUNTY R WR BASIN : YL - REPORTTO r "L� Repw lOffice Otber ` COLLECTOR(S) Estimated DOD Rainey. DIVISION OF WATER QUALITY Chemistry lAboratory Report / Water Quality SAMPLE TYPE AM131ENf QA 1 ;3 57RF.AM EFFLUENT COMPLIANCE ID CHAIN OF CUSTODY !7❑�I WE KFUTEN3 EMERGENCY VISIT TD 0 ESTUARY Station Location. LO {i'-1f r�P'�.- . T PV Lab Ntatsher Date Received T:me Received Reeetved BY J(D��)�y�.- yip"+, Data Released Dine Reported Seed: Cbloritrated: Remarks: !1-P n— OLD VVOC . b . Statlaa 011-otation Code - - Date Be6i�trrinrddl bate :ad f3�lmm! Time 83 Time End Depth - DM, DB, DBM Valoe T A, H. L Com l�gY iq u l' s t%� �'�'� ) ( I !t ! I / L 1 � 2 I t t -2 " 3 1,s ' 3 0 Type Petite T, S. a aS HOD 310 mgAL COD High 340 COD Low 335 Coliform- MF Fecal 31616 /100m1 Colifbrm. MF Tota131504 /100m1 Coliform: tube Fecal 31615 /100ml Coliform: Fecal Strep 31673 /loons) Residue. TOW 500 Volatile 505 inglL Fixed 510 mgiL Residue- S 530 m Volatile 535 Fixed 540 Mai H 403 units Acidity to pH 4.5 436 m Acidity to pff 8.3 435 WL AJkalinrty to pH 8.3 415 Alkalinity to pH 4 5 410 m TOC 690 m Turbidity 76 NTU Coliform Total Tvhe 1100 ail Chloride 940 Chlorophyfl a EPA 40 0 modified ion Color. True 80 c.v. ' Coksr: H 83 cu. Color: pH 7.6 82 C.U. ' Cyanide 720 m Fluoride 951 F 7I880 Grease grid Oils 556 mwL Hanhsoas Total goo S ific Cool 95 umbits/cv MBAS 38260 Phenols32730 Sulfate 945 m Sulfde 745 Homo Twins & Li to HcxevaErnt Chromium u Bicarbohite mgfL Carbonate mgAL Total Dis,aN.d Solid. m NH3 as N 610 TKN an N 625 mwL 'NO2 h s NO3 as N 630 P: ToW as P 665 PO4 as P 705017 P: Dissolved as P 666 m K-Poomium Cd- Cadmium 1027 u Cr-CSvomismt Total 1034 u Cu- CopM 1042 uPJL Ni-Nickel 1067 Pb- Lad 1051 Zn- Zinc I D92 . V-Vanadium UWL - SthTr 1077 M-Aluminum 1105, BeBeryllium 1012 uWL Ca- Calcium 9I6 m Co- Cobalt 1037 VL Fe- Iren 1045 Mo-Mp urn u&fL .j SarAm' . Sn-Tin u TI-Thallium UWL Ti-Titan' :m: ugfL 1631 rt Li -Lithium 1132. u hi - M slum 927 - sr, Mn-Man x 1055 u NaSodium929 - mWL - Arsenic Total 1002 u Se- Selenium 1147 u H - Mere 71000 ' u grL Ba-Barium USA K hlonne Pesticides' Orgami,phosphorus Pesticides t Pestscides Acid Herbicides ` baselNeutraIAAssd Enuactable Or ics TPH Diesel kitrike nzZabteorgmcs,VOAbofiles 'd - . TPH Gasoline Ran - TPH/BTEX Gasoline Range ftrytopimiktan T stet on arrival ("C), Report to: _RRO 77 Lab Number: Station Location: A B66107 • NC DENR/DWQ Laboratory Sample Anomaly Report (SAR) Sample ID: NOVO upstream NOVOBUFFCK County: - Franklin Region: Tar -Pam Upstream of outfall 002 Sample Type: stream Date collected: 12/01/10 Affected Parameter(s): - BOD Priority: compliance Date received: 12/02/10 Analytical Area (check one): ❑ WCH ❑METALS ❑NUT ®MICRO The following anomalies occurred (check all that apply): ❑Samples ❑Improper container used ❑VOA vials with hcadspacc ❑Sulfide samples with headspace ❑Samples not received, but listed on fieldsheet ❑Samples received, but not listed on fieldslteet ❑Mislabeled as to tests, preservatives, etc. ❑Holding time expired ❑Prior to receipt in lab ❑Alter receipt in lab ❑Insufficient quantity -for analysis ❑Sample exhibits gross non -homogeneity El Sample not chemically preserved properly ❑pl-I out of range (record pl-1): ❑Impro per chemical ❑Residual chlorine present in sample ❑Color interference ❑Heavy emulsion formed during extraction ❑Sample bottle broken in lab - no reportable results ®Other (specify): Collector: Date analyzed A. Romanski 12/02/10 ❑VOA ❑SVOA ❑PEST ❑Quality Control ❑Instrument failure— no reportable results ❑Analyst error — no reportable results ❑Surrogates ❑None added , []Recovery outside acceptance limits ❑Spike recovery ❑None added ❑Recovery outside acceptance limits ❑Failed to meet criteria for precision ❑Internal standards ❑Blank contamination ❑QC data reported outside of controls (e'.g-,•QCS, LCS) ❑Incorrect procedure used ❑SOP intentionally modified with QA and Branch 1-lead approval ❑Invalid instrument calibration ❑l;levated detection limits due to: ❑Insufiiciei t sample volume Comments: Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. Corrective Action: ❑Samples were rejected by DWQ Lab. Authorized by: Date: ❑Accepted and analyzed after notifying the collector or contact person and determining that another sample could not be secured. ❑Sample(s) on hold until: ®Sample reported with qualification. Data qualification code used:G8 ❑Other (explain): Notification Required? ❑ Yes ❑ No Person Contacted: Date: Dorm completed by: Lead Chemist Review (initial): �BIOCHEM n^D ❑PEST_ MG'TALS ❑VOA_ Branch Head Review (initial): `Y/ J90 QA/QC Review (ini QA%Farm sV.aboratgrySS A R Date: 12/11 /2010. ❑SVOA Logged into database by (initial): /I -"A � t IG123/01dbs County: FRANKLIN River Basin TAR Report To RROSP Collector: A ROMANSKI Region: RRO ` Sample Matrix: WASTEWATER Loc. Type: EFFLUENT Emergency YertNo COC Yes/No imi Sample ID: 10F'VA rFiq l PO Number# n O - O� a Date Received: > [ Time Received: 1 Lebworks LoginiD 1 .6 Report Generated: i Date Reported: F, t.Aly iSf'• ... �.tiy Vi5'rUD AB66105 ;+ 1OW9754 '12/0212010 10-55 SMATHIS 12/16/10 12/16/2010 Loc. Dascr.: NOVO-002 Location ID: NCGS00915.002 .Collect Date: 1210112010 '- Collect Time: 12.15 Sample Depth Resu Method Analyils CAS # Analyte Name Units Validated_�x ualifier Reference Date LAB Sample temperature at receipt by lab ::' i' 2.1 'C 12010 SMATHIS MIC BOD, 5-Day in liquid 2 2,5 mg1L APHA5210B 12/11110 MOVERMAN WET r: ' Ion CtlromatD�rBpfly _TITLE mg1L• EPA 300.6 1219110 MOVERMAN Chloride 1 -73 mg1L EPA 300.0 1219/10 MOVERMAN Fluoride 0.4 4.3 mg1L EPA 300.0 1219110 MOVERMAN Sulfate 2 °�'",. ;f. '" 130 m911. EPA 30D.o 1219110 MOVERMAN Total Dissolved Solids in liquid 12" 612 mg/L APHA2540C-18TH 1212110 CGREEN NUT . NH3 as N in.liquid 0.02. `. i `,0.50 mg/L a3 N Lac10-107-06-14 1213110 CGREEN Total Kjeldahl N as N in liquid . 0.2. 2.0 mg1L as N Lachat107-06-2-1-11 1217110 CGREEN NO2+•NO3 as N in liquid 0.02 2.4 mg1L as N 1_600-107-04-1-c 1216110 CGREEN Phosphorus_ total as P in liquid 0.02 2,0 mg1L as P LBCIO-115-01-1EF 1213110 CGREEN MET 7429-90-5 Al by ICP 50 , a ' w , ,�'` y.' 760 ug1L EPA 200.7 1219110 ESTAFFORD1 7440-38-3 Ba by, ICP 10 82 ug[L EPA 200.7 1218110 ESTAFFORDI 7440-70-2 Ca by ICP 0.1 59 mg/L EPA 200.7 1218110 ESTAFFORDI 7440-50-8 Cu by ICPMS 2 ' 43 ug1L EPA200.8 1218110 ESTAFFORDI 7439-69-6 Fe by ICP 50 850 ug1L EPA 200.7 12/9110 'ESTAFFORDI 7440-09-7 K by ICP 0.1 25 mWL EPA 200.7 12]B110 ESTAFFORDI 7439-93-2 Li ICP 25 '. 1 - 25 U ug/L EPA 200,7 1218/10 ESTAFFORDI 7439-95-4 Mg by ICP 0:1 ''eo 9 16 mg/L EPA 200.7 1218110 ESTAFFORDI 7439-96-5 Mn by ICP 10' 39 ug1L EPA 200.7 121911D ESTAFFORDI 7439-96-7 Mo by ICPMS 10 10 U ug1L EPA 200.8 12/8110 ESTAFFORDI 7440-23-5 Na by ICP 0.1 �.7Do.. • mg1L EPA 200.7 1218/10 ESTAFFORDI 7440-66-6 Zn by ICPMS ,. 10 370 u91L EPA 200.8 1218110 ESTAFFORDI Laboratory Section» 1623 Mall Service Center, Raleigh, NC 27699-1623 t919) 733.3908 1 For a detalled desorlpton ofthe qualifier codes warto hlln:lroo,tal1�ncdn�n/wntVwnllaNstnfhnfoAa l j. sfs Oala Qualifier Codes c11110:ponalrrfdenf.oivnn�ah,WollaAJslaFFinfMlec:he l> Page 1 0f 1 DiV[SiON OF WATER QUALM J ' Ciemian Laborstory Report / Water Qaafity ❑ SAMELE T_YK b N Date Received COU►r1w RIVER BASM : AMBIENT QA SiRFAM EFFLUENT Tlmc Re ceieed : Received By f t ' REPORT TO Regional Office COMPUANCE CHALN OF CUSTODY LACE fNFL.UENf Im i Other ❑ EMFRGETICY VISIT M E$1l1ARY Data Released COLLECTIDW(S) : �3 j � .t n.4 Date Reported Estimated DOD Rae{e: Seed: Chhriaated: Station Leeafim: �{ �V s � a �}}��� Remarks: _�cS w t li *max C opG - BJ, kth, Station I AAK31tion Code 5—DDa Date n /mmldd) Date Fad !m d) Time SetFa Time End Depth - DM, DR, DDM Va[ae Type - A. H. L ComposittT, S, B Samp y C oD o a v o : i5 a:i5 SOD 31 D mWL COD High 340 m COD Low 335 Coliform- MF Fees] 11616 1100ral Colif=i MFTOW 31304 !1OOinl Coliform: tube Fecal 3161$ llUOnd Coliform: Fecal Stimp 31673 11001111 Residue. ToW 500 Volatile 505 m Fixed 510 Residue. Suamided 530 m Volatile 535 Fund 540 m H 403 units Acidity to PH 4 5 436 Acids tq PH 8 3 435 Alkalinity to PH 8.3 415 Alkalinity to PH 4 5 410 m TOC 680 mon- TwNdM76 NTU Colifmm Total Tubs 1100 ml Chliaide 940 m I a EPA 445 0 modified opdon Color_ True 80 c.u. Color: 83 H- c,u Colm pH 7.6 82 c,a. cywn& 720 m F7umide 951 ITISIL Famaldehyde 71990 myfL Grease and Oils 556 Hadress T.W 900 TWWL 5 tfrc Cond. 95 urnhol/cm MBAS 38260 m Phenols 32730 Sulfate 945 m Sulfide 745 ITIVIL Baton Tamiin & Li in Hummsh! eCLaaoiiimm Bicarbonate m Carbonate m TuW Divolved Solids NH3 as N 61 o m TKN an N 625 m NO2 NM as N 630 m P: Totid as P 663 m PO4 as P 70507 mEVL P: Dissolved as P 666MWL -Pmmiran m Cd. Csshanaa 1027 u Cr-Clanmium?oW 1034 Cu- Fmm 1042 Ni-Nicket 1067 u /L. Pb- lead 1051 Zn-Zirx 1092 11911, V-Varadn'zm Silver 1077 uA AI- Ahaaiman 1105 WILL Be- Beryllitm 1012 Ca-Calcium916' Co- Cobalt 1031 1191 Fe- Iron 1 D45 Ma-Molybdenurn Sb-AMmwrrf Tl-Thallhtm u Ti-TiLnium uFVL Rg-1631 nlVL Li -Lithium 1 132 u M - Nl sium 927 m Msi-Mni 1DS5 � 'L Na- Sodium 929 m Arscniffutal 1062 Se- Selmitaa 1147 H - Mere 71900 u Sa,Banum u 1- hla nc Pesticides s Pesticides en Pesticides Acid Herbicides BasdNeutral&Acrd Ectrattable ice TPH Diesel Ran le Ctr iu VOA bottle 'd TPH Gasoline Ran TPWBTF,C Casaltrn Range P*Oplanktori T on arrival ['C 1 r. County: FRANKLIN River Basin TAR OF WAr�R Report To RROSP i _.. C, Collector: A ROMAN Region: RR 1 ��� I Sample Matrix: SURFACEW� 1 3 ?l � � Loc. Type: EFFLUENT - ~~ - -A Emergency YeslNo DENR RA! SQH REGIGIN LUi§,661 i COC Yes/No Loc. Dow.: NCG500115 Sample ID: AB63613 PO Number # 1OW7782 Date Received: 09/17/2010 Time Received: 09:15 Labworks LogWD HPARKER Report Generated; 1018110 Date Reported: 10/08/2010 4 io-lt- ID Location lD: NCG50NOVO ^Collect Date: 09l16l2010 Collect Time: 11:OS Sample Depth Result/ Method Analysis Validated by CAS # Analyte dame POL qualifier Units Reference Date LAB WET Sample temperature at receipt by lab 0.9 °C 9/17/10 SMATHIS otal Dissolved Solids In liquid ) 12 788 mglL APHA2540C-18TH 9/22/10 CGREEN MET' 7440-22-4 Ag by ICPMS 5 5.0 U ug1L EPA 200.8 10010 ESTAFFORDI 7429-90-5 Al by ICP 50 50 U uglL EPA 200.7 9124110 ESTAFFORD1 7440-38-2 As by furnace 2 2.0 U ug1L EPA, 200.9 9/28110 ESTAFFORDI 7440-38-3 B by ICP 10 120 uglL EPA 2003 9127110 ESTAFFORDI. 7440-41-7 Be by ICP 5 5.0 U uglL EPA 200.7 9/24/10 ESTAFFORDI 51 mg1L 7440-43-9 Cd by ICPMS 1 1.0 U uglL EPA 200.8 9/30110 ESTAFFURDI 7440-48-4 Cobalt by ICP 50 50 U uglL EPA 200.7 9/24110 ESTAFFORDI 7440-47-3 Cr by ICPMS 10 IOU ug1L EPA 200.8 9/30110 ' ESTAFFORDI 20 7439-89-6 Fe by ICP 50 240 ug1L EPA 200.7 9124/10 ESTAFFORDI 7439-97-6 Hg 245.1 0.2 0.20 U uglL EPA 245.1 1011110 ESTAFFORDI 7440-09-7 K by ICP 0.1 29 mglL EPA 200.7 9127/10 ESTAFFORDI 7439-93-2 Li ICP 25 25 U ug1L EPA 200.7 9/27/10 ESTAFFORDI 7439-95-4 f Mg by ICP 0.1 13 mg& EPA 200.7 9127/10 ESTAFFURDI 7439-96-5 - fn by ICP 10 19 uglL EPA 200.7 9/24110 ESTAFFORDI 7439-98-7 Mo by ICPMS 10 IOU ug/L EPA 200.8 1014110 ESTAFFORDI 60 10U 7439-92-1 Pb by ICPMS 10 IOU uglL EPA 200.8 9130110 ESTAFFORDI 7440-36-0 Sb by ICPMS 10 IOU uglL EPA 200.8 1014/10 ESTAFFORDI 7782-49-2 Se by furnace 5 5.0 U ug1L EPA 200.9 9129110 ESTAFFORDI 7440-31-5 Sn by ICPMS 10 IOU uglL EPA 200.8 1014/10 ESTAFFORDI 7440-28.0 Thallium (TI) ICPMS 10 IOU ug1L EPA 200.8 1014/10 ESTAFFORDI 7440-32-6 Ti (Titanium) by ICP 10 IOU ug1L EPA 200.7 9127110 ESTAFFORDI 7440-62-2 V by ICP 25 25 U ug1L EPA 200.7 9124/10 ESTAFFORDI 7440-66.6 (Zn by 1CP 10 180 ug1L EPA 200.7 9/28/10 ESTAFFORDI Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 t9191 733-3908 For a detailed description of the qualifier codes rater 10 hj1Q,lroonal,ncdanr.0rrVweblwallah�! IaNinfo( hassistt#Data qua mar Cndes �hd ro tal n encoralweblwnfla�f la inforlecha�t> Paae 1 of 1 DTVFSTON OF WATER QUALM i r Checistry Laboratory Report! Water Quality Lab Number .- ry' ~COUNTY �� ❑ SAMPL TYPE Date Received Cj. l -7• _ .l?•, ~ 'L f t� RIVER BASIN: FRIO ❑ AMEkENT ❑ QA ❑ STREAM .,UENT Time Received :G�' Received By REPORT TO ; Regional Office �/, COMPLIANCE CHAIN OF CUSTODY ❑ LAKE El INFLUENT '�❑ Otbrc : r� EMERGENCY VISIT ID ❑ ESTUARY Data Released . COLLECTORS) : _ 5 L f — C� + Date Reported Estimated ROD R: zW. 5tatlaa Lontioa: 5(.• C !r!S r Seed: Cbkoriaated- Remarks:. :SLJ 11AJ tit) i ...- I, a . Sfatiee o tisa Cade Date Bella yy! Date Ead ' lnrm! Trme i3me Eel[ Depth - DM, m [IBM =-TH, L ComposOnT, S, B JSmzpke Type 0 BOO 310 nWL COD High 340 COD Low 335 Coliform- MF Fein 31616 1100101 Cdif6,.� MF Totd 3 t 504 1100ml Colif. tube Fecal 31611 1100101 Coliform: Fecal StrW 31673 /100trtl Residue. Total 500 m Volatile 505 m Fixed i10 Residue: Suspermled 530 m Volatile 535 MWL Fixed 540 m y 403 rmtu Acidity to pH 4.5 436 Acidity to pH 8.3 435 Alkalm' to H 83 415 -811- Alkalinity to pH 4 5 410 nwL TOC 680 Turbidity 76 NTU Coliform Total Tube 1100 W Chloride 940 m Chlomptryll a EPA 445.0 moditred cp6m Color. True 80 C.U. Color: H 83 H- c.a Cotm- pH 7.6 82 o,u EZ=da 720 Fluoride 951 F=Tnm1d4rj& 711190 Greaae and Oils 556 mak Hardness Total900 Til Specie Conti 95 umhos/cm M13AS 38260 Phenols 32730 Sulfate 945 Sulfide 745 Baron Tarmin & Lviin' HM—Wem Chromium uWL Betasbotude ffLWL Carbottata m Tool Dissolved Solids m NH3 as N 610 TKN an N 625 msfL NO2 phis NO3 as N 630 m P. Total as P 665 PG4 as-P 70507 P: Dissolved as P 666 mgft K-Potassium MWL Cd- Cadmim 1027 C1-Qtrgrnium:T.W 1034 Cu- Copp. 1042 Ni-Nickel 1067 UWL Pb- lead 1051 u Zn-Zinc 1092 V-Vmadit. Silver 1077 Al- Ahmuznmt 1105 Be 0iunt1012 u gLl Ca- Cakium 916 m Co- Cobalt 1037 u FLL Fe- hrnn 1045 yja M--Mo um Sb Sn-Tilt UWL TI-Thallium ustl- Ti-Titanium URI H -1631 n Li-Lithitart 1132 u MR- MM110um 927 Mn-Man ese 1055 u L Na- Sodi.929 Arseme-Total 1002 Se- Selenium 1147 li- Mercuty 71900 u Ba-Barium u lmme Pesticides 0qpnoph*2tL(MPesticides Oqpzuinftopn Pesticide Acid Herbicides Ba3dNeu6al&Acid Extractable Or ics TPH Diesel Ran sable 2EMics VOA bottle 'd) TPH Gasolme TPHBTEX Gmaiine Range vn T an mri—I (IC): 7 0 " (�2rr mil. EIT.�aj'�,st, e 5 County: FRANKLIN River Basin 10 Report To RROSP. Collector: AROMANSKI Region: RRO Sample Matrix: WASTEWATER Loc. Type: INFLUENT Emergency Yes/No COC Yes/No `pS16 A r�R pG Loc. Desar.: NOVOCTMU Sample ID: -, A666106 . PO Number# 1OW9766 Date, Received: 12102/2010 Time Received: 10:55 Lobworks LogWO SMATHIS Report Generated: 12/21110 Date Reported: 122//2112010 + {� zz 1V Location 10: NCGS001151NF Collect Data: 1210112010 Collect Time: 11:50 Sample Depth CAS # LAB ' Analyte Name z'' Sample temperature at receipt by lab' •"" Resu • p ,Ar" Ih:,,, /Qualifier 2.1 Units 'C Method_ Reference -.Analysis Date 12010 Validated by SMATHIS MIC BOO, 5-Day In liquid. "• 2 2 U G8 mg1L APHA5210B 12/11/10 MOVERMAN WET Ion Chromatography, TITLE_ mg1L EPA 300.0 1219/10' MOVERMAN Chloride mg1L' EPA 300.0 12010 'MOVERMAN Fluoride " 0'4 ;I 0.8 mg1L EPA300.0 1219i10 MOVERMAN Sulfate .2 20 mg1L EPA300.0 1219H0 MOVERMAN Total Dissolved Solids in liquid 12 96 mg1L APHA254OC-18TH 1212110 CGREEN NUT NH3 as N in liquid 0.02 0.02 U mg1L as N LacIO-107-06-1-J 12/3110 CGREEN Total Kjeldahl N as N In liquid 0,2 0.2 U mg/L as N Lachatl07-06-2-H 1217/10 CGREEN NO2+NO3 as N in liquid 0.02 ". 0.02 U mg1L as N Lac10-107-04-1-c 1213110 CGREEN Phosphorus_total as P in liquid 0.02 -.1 : 0.14 7 mg/L as P Lac10-115-01-1EF 1213/10 CGREEN MET 7440-22.4 Ag by ICPMS 5. 6.0 U ug/L EPA 200.E 1218/10 ' ESTAFFORDI 7429-90.5 AI by ICP 50 n,ES0 U ug1L EPA 200.7 1219i10 ESTAFFORg1 7440-38.2 .As by ICPMS 2 2.0 U ' ug1L EPA 200.8 12/8110 ESTAFFOR01 7440-38-3 Ba by ICP 10 17 ug1L EPA 200.7 1218/10 ESTAFFORD1 7440-41.7 Be by ICP' 5' {i 5.0 U ug1L .' EPA 200.7 12/9110 1-STAFFOR01 7440-70.2 Ca by ICP 0:1 ' i`' , ,t ' ' 11 mg1L EPA 200.7 1218110 ESTAFFORD1 7440-43.9' Cd by ICPMS 1 "' :' 1.0 U ug1L EPA 200,8 1218110 ESTAFFORD1 7440-48-4 Cobalt by ICP 50 50 U ug1L EPA 200.7 1219110 ESTAFFORDI 744.0.47-3 Cr by ICPMS; 10 ' i ' 10 U ug1L EPA 200.8 1218/10 ESTAFFORD1 7440-50-8 'Cu by ICPMS 2 21 ug/L EPA 200.0 -1218110 ESTAFFORD1 . 7,439-89-6 Fe by ICP 50 50 U ug1L. EPA 200.7 1219110 ESTAFFORD1 7439-97-6 Hg 245.1 ' 0.2 0.20 U ug1L EPA 245.1 ' 12114110 ESTAFFORD1 7440-09-7 K by ICP 0,1r ;' i : ` �, :.. 2.5 y...>._ mg/L EPA 200.7 1218110 ESTAFFORD1 7439-93-2 Li ICP 25 ': 25 U ug1L EPA 200.7 1218110 ESTAFFORD1 7439-95-4 Mg by ICP 0.1 3.3 mg/L EPA 200.7 12/8110 ESTAFFOR01 7439-96-5 Mn by ICP -10 10 U uglL EPA 200.7 12/9110 ESTAFFOR01 7439-98.7 Mo by ICPMS 10 10 U ug1L EPA 200.8 1218110 ESTAFFORD1 REUIV U_ Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 For a detailed descripllor of the quallrier codes rater to h11RJ1VQrtai.nalenr�nrnhvohlwnLp�steYflnlahnr, p a li i c r r ,.' .. TPage 1 of.2 1 ... C n n 2010 NC 1}ENR Raleigh Regional NO ' VCtDq+ ,LaboratorySection(RSaults Location ID: NCGS001151NF- Sample ID: AB88106 Collect Date: 1210112010 Collect Time:: 11:60 MET CAS # 7440-23-5 AnalyteNarne- Na by ICP 0.1 Resultl. Qualifier 16 Units mg/L Meth Reference EPA 200.7 ;Ana^ I�rs!s Date 121B110 Validateo b ESTAFFOR01) 7440.02-0 Ni by ICPMS 10' j IOU ug1L EPA200,8 1218110 ESTAFFORDI, 7439-92-1 "Pb by ICPMS 10', r+' :- 1 O U uglL EPA 200.8 12l8110 ESTAFFORDI, 7440-36.0 Sb by ICPMS 10"' I IOU uglL EPA 200.8 12I8110 ESTAFFORD - 7782-49-2 Se by ICPMS .5 5,0.0 .' ug1L EPA200.8 1218110 ESTAFFORDI 7440-31-5 Sn by ICPMS 10 ., `r. IOU ug1L EPA200.8 1218/10 ESTAFFOR01 7440-28-0 Thallium (TI) 1CPMS 10 IOU ug1L EPA200,8 1218110 ESTAFFORDI 7440.32-6 Ti (Titan -sum) by ICP 10 ' 10 U ug1L EPA200.7 1218/10 ESTAFFORD1 7440.62-2 V by-1CP - 25 25 U ug1L EPA 200.7 1219110 ESTAFFORDI 7440-66-5 . Zn by ICPMS I EPA 200.8 1218110 ESTAFFORDI Laboratory Section>> 1023 Mall,Servlce Center, Raleigh, NC 27699.1623 (919) 733.3908 For a detated description at the quoErwr codes refer to hltnllnortnl.nafenr.nrnlwehAvnAahJslnllinfndechasshlsDare Qualifier Crotles,chlloWpodal ncoenr.aln+weh+walliWttaffinfuABChefalsl� Page 2 of 2 • .- ii:it`r5i - l Z)'V) gT56 DIVISION OF WATER QUALITY Cb mistry Laboratory Report I Water Quality o � y6 N�bv eceive D. Rd jar Colnrty - _;_ : 1b, 0 1 (n _ YS148ITY Tune Recewed OVERRASFN: �p%}VIN o ❑ AMBIENT E3 QA - STV,9AM FFFLUENT Recelite'd•By REPORT TO Rtgioral Office KCOMPLIANCE CHAIN OF Ci3STODY 1 AKE rRI MFLUi M Otbier Q EMERGENCY, VISIT ID ESTUARY Data Messed COLLECTORM : — �/ CJ� Date Reported Extim+trd ROD Rafter ��1— �} 1- 9� i1C %.VOID: c.� S � f O O� 6� 1�1Di SYLZ�I.J Statiaa Locatioe:�_�vo-_c �l•Yl - ! - f �� Lt� Seed: Clds arated: Ressarks: � r 7 l� ✓� k'� �' T - S4tioft /I.ocatipft Code CG,5o0IST1vr - Date "a (yy ra/ddl Data Ead Ito o 'Ilse a i � Time Ead : so DgXh - DM, D% DBM Valet: Type - A. H. L Camst mite-T. S, B Sam gle T BOD 310 COD Hle 340 COD Low 335 Coliform- MF Fecal 31616 11001111 Coltfb mMF Total 31504 /IOQmI Coliferm: tubc Fecal31615 /1001d Coliform: Fecal Strep 31673 1100m1 Rcsiduc. Total 500 " Volatile 505 Feed 510 Resider Suspmded 530 mgfL Voimle535 ' Fixed 540 mWL H 403 - units Acidity to pH 4 5 436 Mal Acidity to pH 8 3 435 AlUmity to pH 9,3 415 Allmlintry to pFi 4.5 41 O. TOC 690 Mwt Turbidity 76 NTU ColiformToW Tulx /3Ooml Chloride 940 UIJVL ■ EPA 445.0 pwdificd 2eon Color: True a0 c-4, Color: N 83 H= cu. Cola. pM 7.6 82 C.U. ide 72a Fluoride 951 FonnalddTk 71880 Cave trd Ods 556 MPIL Harut m Tow 9O0 Tai Spmfic Conti 95 umhos/cm MBAS 382150 MVL Pheswls 32730 Sulfate 945 m Sulfide 745 MOIL Baron Tam m a Ltpm' Hexavalent Cbaomium Bicubonate m Carbonate m - ToW Dissobred Solids L NH3 as N 610 mgIL TKN an N 625 m NO2 pkis NO3 as N 630 m P. Total as P 665 PO4 as P 70507 P: Dissolvtxl n P 666 mgfL K-Potassismt MWL Cd- Cadmium 1027 - G-Chro nitaa:ToW 1034 Ed Cw CcipM 1042 Ni-Nirkcl 1067 UEVL Pb- Lead I O51 Zn-ZincIM V-Vanadiuw ut -Silver ID77 Al-Al.1105 Be- Rium to12 UVL Ca- Calcitan 916 m Co- Cobalt b037 Fe- Iron 1045 Mo-M Sb- Sn-Tat Uez TI-Thallium tmrL Ti-Titattium - u 1631 n Li-Lithimn 1132 LqYL Mg- Magnmimn 927 MEE Mt Mwlswwse 1055 ug,L Na- Sodium 929 ' ArsenieTwit] 1002 Se- Selenium 1147 a fl. H - mcrcury 71900 - 13a-Bariian I. 2senochlonm Pesticide ' Orgmw3phosphorus Pesticides Pesticides Acid Hcrbicidcs BasclNeuU-A&Actd Extractable ics 3PH Diesel Ran c bleOrganics(VOA bottter 'd TPH Gasalinc Ran TPHMTEX GwIme Ran Pbytoplanktan Tcmperst= on arrival I �' F County: FRANKLIH Semple ID; AI366109 River Basin TAB it t <bF WAT�q PO Number* 1OW9758 P Re ort To RROSP .y taH°i� ki,sF y Date Received: .12102/2010 Time Received: 10:56 - Collector: A ROMANSKI _ Region: �O `; Lebworks LoginlD SMATHIS Report Generated: 12/21/14 Sample Matrix: WASTEWATER Data Reported: 1212112010 Loc. Type: EFFLUENT. Emergency •YOS]No VlsltlD COC Yes/No 7 Loc. Descr.: NOVOFEHCTBD Location ID: FEHCTBD - . I Collect Daietl" 1210112010 I Collect Time: 12:00 I Sample Depth CAS # Analyte_Narne esul Units Method AnYalldated by Qualifier Reference Date LAB Sample temperature at receipt by lab • u 2,1° 'C 121z110 SMATHIS MIC BOD, 5-Day in liquid. 2 • 2 mg1L APHA52108 12/11/10 MOVERMAN WET Ion Chromatography " ' 14. TITLE'I" mg1L EPA 300.0 1210110 MOVERMAN Chloride 1 100 mg1L EPA 300.0 1219110 MOVERMAN Fluoride 0.4 ,: =' 6.1 mg1L' EPA 30o.a 1219110 MOVERMAN Sulfate 2 160 mg1L EPA 300.0 1219/10 MOVERMAN Total Dissolved Solids in liquid 12 764 mg1L APHA254OC-18TH 1212110 CGREEN NUT NH3 as IN in liquid 0.02 ; .. .• '. OX mg/Las N LaC10-107-06-1-J 12/3/to CGREEN Total Kjeldahl N as N in,llquid Y 0.2 'ti,,,M''lii' ..; 1.7. mglLasN Lachat10706-2-H 5217110 CGREEN NO2+NO3 as N in liquid 0.02 3.2 mg1L as N Loci 0-107.04-1-c 1218/10 : CGREEN ' Phosphorus' total as P in liquid 0.02 2.2 mg1L as P Lac10.115-01-1EF . 1213110 CGREEN MET 7440-22-4 Ag by ICPMS 5 rc 5.0 U • ug1L' ' . EPA 200.8 12/8110 ' . ESTAFFORDI 7429-90-5 Al by ICP 50 50 U ug1L EPA 200.7 1219110 ESTAFFORDI 7440-38-2 As by ICPMS ' 2 • . i �, 22 ug1L EPA 200.8 1218110 ESTAFFORDI 7440-38-3 Ba by ICP :`. 10°a .,' . ' : ' 100 ug1L EPA200,7 1218110 ESTAFFORDI 7440-41-7 Be by ICP 5 :' :! 5.0 U ug/L EPA 200.7 1219110 ESTAFFORDI 7440-70-2 Ca by ICP 0.1 75 mgk EPA 200.7 1218/10, ESTAFFORDI 7440-43-9 Cd by ICPMS .1 4 11.Q U ug1L EPA 200.8 1218110 ESTAFFORDI .7440-40-4 Cobalt by ICP 50 5Q U • ug1L EPA 200.7 12/9110 ESTAFFORDI 7440-47-3 Cr by ICPMS 10 10 U ug1L EPA 200.8 ,12/8110 .. ESTAFFORDI 7440-50-8 Cu by ICPMS. 2 12 uglL EPA 200.8 1218110 ESTAFFORDI 7439.89-8 Fe by ICP 5011""'. .?', ;;,q 250. ' ug1L EPA 200.7 1219110 ESTAFFORD1 7439-97-6 Hg 245.1 0;2; e:: w rl}M'' 0.20 U ug11- EPA 245.1 12/14/10 ESTAFFORDI 7440-09-7 K by ICP 0.1 29 mg1L EPA 200.7 1218/10 ESTAFFORDI 7439793-2 Li ICP 25 25 U ug1L " EPA 200.7 1218110 ESTAFFORDI 7439-95-4 Mg by ICP 0.1 " 2ZJ mg1L EPA 200.7 1218110 ESTAFFORD1 7439-96-5 Mn by ICP 10 13 ug1L EPA 200.7 1219110 ESTAFFORDI 7439-98-7 Mo by ICPMS 10 10 U uglL EPA 200.8 12116/10 'ESTAFFORD1 Laboratory Section» 1623 Mo 1 Service Center, Raleigh, NC 27699.1523 (919) 733-3908 For a eelailed descriollm of the ouaYrier codes refer io s..im$Dwa Qm0pr CnAns<1xra;Unr,rislnMenr.nmrwenlwoMNslaf ' �2P2010 ..Page 1 of 2, NC UFNR . Raleigh Regional -Office ""� NC (D'lVQ LaboratorySection vmi(ts Location ID: FEHCTED Sample ID: A866109 Collect Date: 12101/2010 Collect Time:: 12:00 MCI AS # y44C-23-5 - .. Analvte Name . Na by ICP .. r;• :. ;'Result/ P k'''� ";a':- i4i ualifierM 0.1140 Units mglL Method_ Reference EPA 200.7 Analysis Date 1218110 validated by ESTAFFORDI 7440-D2-0 Ni by ICPMS 10 100 % ug1l,, EPA 200.8 1218110• ESTAFFORDI 7439-92-I Pb by ICPMS 10 •' , A::., ,�...74.0 uglL EPA 200.8 1218110. ESTAFFORDI 7440-36-0 Sb by ICPMS .. �: 10 10 U . •• . ug/L EPA 200:8 . 1218110 ESTAFFORDI 7782-49-2 Se by ICPMS 5 66 ug1L EPA200,8 ! 1210/10 ESTAFFORDI 7440-31-5 Sn by ICPMS 1Q. IOU uglL EPA 200.8 12JW10 ESTAFFORDI 7440-28-10 Thallium (TI)ICPMS ; 10"'E;t;' '.'•.., 10U ug1L EPA200.8 1218110 ESTAFFORDI 7440-32-e Ti (Titanium) by ICP 10, ' AO U' ug1L EPA 200.7 1218/10 ESTAFFORDI 7440-62-2 V by ICP . 25 25 U ug1L EPA 200.7 1219110 ESTAFFORDI 7440-86-6 Zn by ECPMS 10 _. "' 83 uglL EPA 200.8 '1218H0 ESTAFFORDI k! . Ir, lip yl. ... Laboratory Section» :1523 Mall Service Canter, Raleigh, NC 27699.1623 (9101 733.3008 For a detailed desuipllon of the qualifier Cedes refer to h 101p.Qrt11Itl 1plT'4jfo4fff;bpsijst#Qf1a Qualifier<hVr1#mrWin > Page 2 of 2 DIVISION OF WATER QUALITY f t�istry Laboratory Report 1 Water Qsstity b Nmobet �F/Y's� �i SAMPf E TYPE Date Received COLTIP:Y BAS(N: f ✓j g$LQg� fi AMBIENT QA STREAM XEFFLUENT Tom ReceivedRIVER Recalved ByREPORT TO n Regular! OfF. COMPLIANCE CHAINOF CUSTODY LAKE � INFLUENT Odw EMERGENCY VISIT in - El ESTUARY Data Released i COLLECTORS) : 15k ut, Z5 r Date Reported Estimated ROD Raa=r Stativa Locatiov: JV P 1/0 i( H 0 I T 6, Y•h` 1 o[-tJ L'oya� Seed: Chloe #Ad- Rpaar4a: (-00 statim!iLacative Code Da4 Befin (3'y m/dd) Date End ad Time &jia Time End Oept4 - DM, D$, DHM Llue Type - A, A, L Compmile-T, 5, H pl Ty J�n 00 HIP.- HOD 310 Chloride 940 m COD High 340 myjL COD Low 335 Chlmoyfl ti EPA 445.0 modified Coliform MF Fecal 31616 /loom] Colifeem MF TaW 31504 /1009d Color: True 8o c.u. Ceilifar tube Fecal 31615 !loom[ Color EI 83 - H- c.u. Colirmm: Fecal Swep 31673 /i oonil Color: pH 7.6 82 c.o. Residue. Total 500 Cyanide 720 Volatile 505 951 Fixed 510 mgfL F 71880 m Residue; S 530 mRfL Grease and Oils 556 Volatnk 535 Hz*.n TOW 90D Fixed 540 TngIL S rtc Cond. 95 umhosi m H 403 - mots MBAS 39260 m Acidity to pH 4 5 436 m Pbesnb 32730 ug(L Acidity to pH 8.3 435 mJvL Sulfate 945 Alkalmity to RK 8 3 415 Sulfide 743 ARuhni to pH-4-5 410 Baron TOC 680 Tam m & U in :rwbidtty 76 NTU Hexavalent Chromic 'L Coldarm Total Tuts /100 ml Bicarbonate Carbonate m - Total Dmsohv d Solids m 23 as N 610 TKN an N 625 m NO2 Eta NO3 as N 630 P- Total as P 665 PO4 m p 76507 MEVL P: Dissolved as P 666 -potassium ol Cd- Cadmium 027 u Cr1CbrMiure:Tura) 1034 C.-CI,;,1042 Ni-Nic3:el 1067 u Pb- Lead 1051 Zn- Zinc 1092 V-Vanadium FI F - Silver 1077 Al- Ahmun mn 1105 Be limo 1012 u Ca -Calcium 916 m C, Cobalt 1037 UWL Fe- Iron 1045 MvM um u Sb S.-Tot T)-Thallzum UEVL Ti-Titzniu m ugft H -1631 n Li-Lith. 1132 uttl- Mg- MWmi. 927 12191L M.-M.P. 1055 u 'L Na-S.&= 929 Arsrnic:Total1002 'L Sc- Selenitmi 1 l47 u fl- H - MacM 71 Wo Bar Banutn u 1_ hlarim Pesticides OqEnopbtsphorns pesitcidrs Organonzogeti Pesticides Acid Herbicides BsulNmtral&Aud Extractable Orga,,ics TPH Diesel Ran tTyeable Or ics VOA bottle r 'd) TPH Gasolinc Range TPHlBTE{ Gasoline Rmse lankton L G� T On arrival (°C 0 0 County: RA�LIN River Basin Report To RROSP Collector: A ROMANSKI Region: RRO Semple Matrix: WASTEWATER Loc. Type: ' EFFLUENT Emergency Yes/No COG Yes/No Location ID: EFFLNDPOND WA7'�,�G .. 4 VisIfID�. �Ic; Loc. Dow.: NOVONOPOND Sample ID: ' AB$6110 PO Number# 14W9759 Date Received:. 12102120110 Time Received: 10:66 Labworka LoginID SMATHIS Report Generated: 12/21/10 Date Reported: 12121/2010 12/01/2010 Collect Time:, 12:60 'Sample Dapth ' ;+' ;`..p yf' ijj;,r° Resul : Method . Analysis CAS # Analvte Name ., .. , ��' 'Qualifier U 1 s vaudatad by' ;� Reference Date LAB r i Sample temperature at receipt by lab 2.1 '' °G. 12l2110 "' SMATHIS MIC BOD, 5-pay in liquid M 2 9.1 mg!L APHA5210B 12/11/10 MOVERMAN WET lon'Chromatography i? ..7TITLE_ mglL ' EPA 300.0 12/8110 CGREEN Chloride mglL EPA 300.0 12/6110 .. CGREEN- Fluoride 0.4 0.6 mg1L EPA 300.0 12/6110 CGREEN Sulfate '2 140 mglL EPA 300.0 1216110 CGREEN Total Dissolved Solids in liquid 12 1> , I$10..';' mglL,. APHA2540C-18TH 12.16110 MOVERMAN NUT NH3 as N in liquid 0.02 0.03 mglL,as N 1-6010-107-06-14 1213110 CGREEN Total Kjeldahl N as.N in liquid 0.2 _ 6.1 mg1L as N Lachat107-06-2-1-1 12UM0 CGREEN NO2+NO3 as N in liquid 47 . mg1L as N Loc14-107-04-1-c 1218110 CGREEN Phosphorus total as P in liquid 0.02 'r 79 mg1L as P Lac10-115-01-1EF 12/8110 CGREEN MET 7440-22-4 Ag by ICPMS 5 5.0 U uglL EPA 200.8 1218110 ESTAFFORDI 7429-90-5 Al by ICP 50 62'3 ug1L EPA 200.7 1219/10 ESTAFFORD1 7440-38-2 As by ICPMS Z 2.0 U ug/L . EPA 200.8 1218l10 ESTAFFORDI 7440-38-3 Ba by ICP 10 IOU ug1L EPA 200.7 . 1218/10 ESTAFFORDI 7440-41-7 Be by ICP 5;�.?7! ;,, =ri .. 5,0 U uglL EPA 200.7 ? . - 1219110 ESTAFFORD1 7440a0-2 Ca by ICP 22 mg1L EPA 200.7 1218/10 ESTAFFORDI 7440-43-9 Cd by ICPMS• 1 1.0 U uglL EPA 200.8 1218l10 ESTAFFORDI 7440-48-4 . Cobalt by ICP " 50 . 50 U ug1L EPA 200.7 1219110 ESTAFFORDI 7440.47-3 Cr by ICPMS 10 1-!-,,10, tJ u91L EPA 200.8 12/8110 ESTAFFORDI 7440.50-6 Cu by ICPMS 2 3.1 ugli- EPA 200.8 12l8110 ESTAFFORDI 7439-89-6 Fe by 1CP 50 53 ug1L EPA 200.7 12I9110 ESTAFFORDI 7439-97-6 Hg 245.1 0.2 -, y 0.20 U uglL EPA 245.1 12114110 ESTAFFORDI 7440-09-7 K by-ICP '"' 0;1. fir,'; 600 ' mg1L EPA 200.7 121810 ESTAFFORDi ,�..'!"I'I' 7439-93-2 Li ICP 25o "4' 25U. ug1L EPA 200.7 12/8110 ESTAFFORDI 7439-95-4 Mg by ICP. 0.1 2,3 + mglL EPA 200.7 12I8110 ESTAFFORDI 7439-96-5 Mn by ICP 10 "'� 10 U uglL EPA 200.7 1219/10 ESTAFFORD1 7439.98-7 Mo by ICPMS 10 10 U. uglL EPA 200.8 12I8110 ESTAFFORDI tH CEI11 Laboratory Sel:tlon>> 1623 Mail Service Center, Raleigh, NC 27699.1623 (919) 733-3908 Fora detallnd deacrlpllon of the quallller codes refer to httn,!l�gy�l.nr.4r nr-�nmhvnhilwnlla l�ittii r ! n ! ! 2010 Page 1 of 2 ND DENR :. Raleigh Regional Office NC eDq4,2 Laboratgry Section �Zrsults Location ID: EFFLNDPOND Sample 10: j. Collect Date: 12101/2010 Collect Time:: 12:80 MET t , L Result/ Method AnaNsis CAS # Analyte. Name Un' s ualifier Reference Vaildated by Date 7440-23-5 Na by ICP' ' 0.1 130 mg1L EPA 200,7. ' 12/8110 ESTAFFORD1 7440-02-0 Ni by JCPMS 10?'''x" '•' :;, IOU ug1L EPA200,8 12/8110 ESTAFFORD1 7439.92-1 Pb by ICPMS 1Q U u97L ' ' EPA 200.8 1218/10 ESTAFFORD1 7440-36-0 Sb by ICPMS. 10 IOU uglL EPA200.8 1218/10 ESTAFFORD1 .7782-49-2 Se. by ICPMS 5; ;. • 5.0 U ug1L EPA 200.8 12/8110: ESTAFFORD1 7440-31-5 $n by ICPMS " ' .' 10 tf" "(Q'U uglL EPA200.8 1218M0 ESTAFFORD1 7440-28-0 Thallium (T4) ICPMS ' 10 IOU " ug/L EPA 200:8 ,1218I70 . ESTAFFORD1 7440-32-6 Ti (Titanium) by ICP 10 IOU ug/L 'EPA 200.7 i • 1216i10 ESTAFFORD1 7440-62-2 V by JCP ' 25MG,,..7� .:�. r, 25 U ug/L': EPA200.7 1279/10 ESTAFFORD1 7440.66-6 Zn.by ICPMS "' 240 -, ug/L . EPA200,8 12/8110 .' ESTAFFORDI r' lien,. :L. Laboratory Secllon>> 1623 Mall Service Center, Raleigh, NC' 27699.1823 (919) 733.3908 For a detRaed desalption of 1he qualllfer codes refer 10 Kip -Nllo tnl ncdenr OrplweGrW n8bJ4Saftlnto.'lectlasslslllf]ala Qunlifinr (�'Q�pS <IIIlellflennl OfYlenr.010NIHNMNrIFSbie101hMa[CChneSV31> ' ;�u.•"'..:. Pape 2 of 2 100 �A,5� DIVISION OF WATER QUALITY Chenth" Laboratory Report I Water QuAity ❑ SAMPLE TYPE COUNTY I � t�RLY RIVER BASIN : ❑ AMBIENT QA STREAM I JY EFFLUENT REPORT TO ^ Regional Office )R COMPLIANCE CHAIN OF CUSTODY LAKE ❑`-" INFLUENT Other - ❑ EMERGENCY VISIT ID [D ESTUARY COLLECTOR(S) : , a� ` �� ❑ i' Up Numbs Date Received: ' f t� • i/ 0 Time Received : O�r ✓,J Received By Data Meased . Date Reported Estimated ROD RanLc Station Location: / vU U L11V V 0 Seed: � Cibriaated: Reauriu: _ Station #A ocat' a Code Date (yylm dd) Date $ad (yy/ ail Time lactic Time End Depth - DM, DB, ASH Vale Type - A, H. L Composite-T, S, B F;4Ls �f) i9DAj,n IID �� � to ii2 t 1�-5o J� s°, B0D 310 m COD High 340 m COD Low 335 MBIL Coliform- MF Fecal 31616 /100m1 Colifarrn: MF Total 31504 /100qu1 Co iform: tube Fecal 31615 1100m1 Coliform. Fecal Shrp 31673 - /I00m1 Residue: Total 500 Volatile 505 m Fixed 514 VL Residue: Suspentled 530 m Volatile 535 Fixed 540 m H 403 units Acidity to pH 4, 5 436 mgL Acidity to pH 8.3 435 m Aikaliniry to pH 9.3 415 Alkalini to H4.5410 m TOC 690 m Tmbidi 76 NTU Colifmm Total Tube 1100 tal Chloride 94o mgtL Chlorophyll a EPA 445.0 modified option gLL Color. Tnae 80 CA Color: H 83 H- C.U. Color-. pH 7.6 82 c.0 ide 720 m Fluoride 951 Famaldchyde 71880 m Grease and Oils 556 mBi Hardtteas T0a1900 m Spccific Cond. 95 umhos/cm MBAS 39260 MVL Plimals 32730 ulfate 945 m Sulfide 745 m Baron Taru�in & Li in UELL Hcxavalent Chromium usfL Birarbtmare mSIL Carbonate Mall, Total Dissolved Solids MSIL NH3 as N 610 m TKN att N 625 m NO2 phis NO3 as N 630 m P: Total as P 665 m PO4 as P 70507 m P: Dissolved as P 666 MwL K-Potassium m Cd-Cadmium 1027 u Cr-CFnomium:Tota11034 ugfL Cu-C f042 uglL Ni-Nickel 1067 u Pb- Lead 1051 Z, Zinc 1092 ai V-Vanadium ugfL AR- S',I w 1077 Al- Altananan 1105 Be- Bylh. f 012 Ca- Calcium 916 m Co Cobair 1037 ugfL Fe- fron HX5 uRIL M.-M.. u 56-Anti u rl- SurTin Tl-Thalhurn u Ti-Titaniumt u 1631 ngfL Li -Lithium It 32 ug/L Ms- Magricsitan 927 Mn-Mangwesc 1055 u Na-Sadn. 929 Arsenic:Tota11002 UFA Sc- Selenium 1 147 u H - Mercury 71900 USX Ba-Basivau u achlorirue Pesticides Or hos horus Pesticides Orgaticeii"llen Pesticides Acid Herbicides - BasilNouuai&Acid Extractable aaics TPH Diesel Ran e ' Purgcablc Dr ics VOA bottle r 'd) TPH Gasolate Range TPMTEX Gasoline Range lankton iTei,perature on arrival (^C County: FRAM LIN Sample ID: ABS6108 RIvor Basin OF WArE4' " lit ¢ ;j PO Number# 10W9757 t ReporTo RROSP .0� " •` Date Received: 1210212010 Collector: A-ROMANSKI Time Received: 10:55 a `s Labworks LaginlD SMATHIS Region; RAF O ,. Report Generated: 12I21110 ' Sample Matrix: SURFACEWATER "-.•;"' Date Reported: 1212112010 Loa Typa: RIVER/STREAM Emergency•Yes/No VIsRI1) COC Yes/No Loc. Dascr.:, N,�( VONDOWNSTREAM + Location ID: WILLMITCHNERRID CollecfDate;'''-,_ 12101/2010 Collect Time: 15:30 , Sample Depth Result/ Method Analysis CAS # Analyse Name Units yalidated_bY . ualifier Reference Date- • LAB , Sample temperature,at receipt by lab Jj'''."''"' ;';2.1 °C 1212110 SMATHIS . MIC ;. BOO, 5-Day in liquid , 2 2.2 m91L APHA5210B 12/11/10 MOVERMAN WET I h h T no/L EPA 300 0 1216110 CGREEN on C romat ograp y Chloride Fluoride Sulfate Total Dissolved Solids in liquid NUT g EPA 300,0 12/6110 CGREEN tIL EPA 300.0 1216110 CGREEN 'L EPA 300.0' 1218110 CGREEN APHA2540C-IBTH 1212/10 CGREEN NH3 as N in liquid Total Kjeldahl N as N in liquid NO2•+•NO3 as N in liquid D D;, ©, S „t 1.3 s N mg/L as N mg1L as N Lac10-107-06-1-J Lachat107-O6-2-1-t Loc10-107.04-1-c 1213110 12/10/10 1213110 CGREEN CGREEN CGREEN Phosphorus -total as P in liquid 0.02 0.23 mg1L as P Lac10-115-01-1EF 1213/10 CGREEN ' MET 7440-22-4 Ag by ICPMS g 5 ?: „s':} ;..y> .; , 5.0.0 ug1L EPA 200.8 1218/10 ESTAFFORDI 7429.90-5 Al by ICP 50 '"pit, i�1' 200 + ug/L EPA 200.7 12/9/1a ESTAFFORD1 7440-38-2 As by ICPMS 2 2.0 U ug1L EPA 200.8 12I8110 ESTAFFORDI. 7440-38-3 Ba by ICP 10 - - ~. 1, 100 ug1L EPA 200.7 121B110 ESTAFFOR91 7440.41-7 Be by ICP 5 5.0 U', ug1L EPA 200.7 .1219/10 ESTAFFORDI 7440.70-2 Ca by ICP ,. 0.1 17 mg1L EPA 200.7 12/8110 ESTAFFORDI 7440.43-9 Cd by ICPMS 1 . 1.0 U ug1L EPA200..8 1218/10' ESTAFFORDI 7440-48-4 Cobalt by ICP 50;1 " SO U ug1L EPA 200.7 12I9110 ESTAFFORD1 7440-47-3 Cr by ICPMS, 10.'-:'" '''', IOU ug1L EPA 200.8 121fl/IOL ESTAFFORDI 7440-50-8 Cu by ICPMS 2 • 2.0 U ug1L EPA 200.8 1218/10 ESTAFFORDI 7439-69-6 Fe by ICP 50 �. 1500 ug1L EPA 200.7 1219110 ESTAFFORDI ' 7439.97-6 Hg 245.1 0.2 „," , ,0.20 U ug1L EPA 245.1 12/14110 ESTAFFORDI 7440.09.7 K by ICP ' 0.1 10 mg1L EPA 200.7 1218110 ESTAFFORDI 7439-93-2 Li 1CP 25 25 U ug1L EPA 200.7 12! 110 .. ESTAFFORDI' 7439-96.4 Mg by ICP 0.1 5A mg1L EPA 200.7 1218/10 ESTAFFORDI 7439-96-5 Mn by ICP .. 10'`�-,;, '• ,.'�:; 120" Ug1L EPA 200.7 1219H0 ESTAFFORDI 7439-98-7 Mo by ICPMS 10. •`'' r' " IOU ug1L EPA 200.8 12/8110 ESTAFFORD1 Laboratory. Soctlon» 1623 Mall Service Center, Raleigh, NC 27699.1623 (919) 733-3908 I' For a detailed dwriptloll of the Cj1191lr1af Codes refer 10' T 11 Ia.11rflell f 1 1 i t 1 I -I 9< 1'. 1 f ! r Page 1 of 2 R ULU 2 9 2010 "NC DENR Pafeigh Reqional Office i NC(D`VQLaboratorySection(Rvsizfts Location ID: WILLMITCHNERRD Sample AB66108 Collect Data; 12/0112010 Golfed Time:: 15:10 MET F; M1 :; r Result/Method 'knits na is CAS # Analyte Name P L , Vatidated by ualifier Reference Date 7440-23.5' Na by ICP 0.1 18 mg1L EPA 200.7 1218110 ESTAFFQRDI 7440-02.0 Ni by ICPMS 10. IOU ug1L EPA200.8 12/8110 ESTAFFORDI 7439-92-1 Pb by ICPMS 10 IOU ugrL EPA200.8 1218110 ESTAFFORDI 7440-36-0 Sb by ICPMS 10 10 U ug1L EPA200.8 1218110 ESTAFFORDI 7782-49.2 Se by ICPMS ` 5;; , .ji.,.r;t _;. 5.0 U uglL EPA200.8 ,. 1218110. ESTAFFORDI 7440-31-5 SD by ICPMS 10�,,m' fl+- i .19U ug1L EPA200.8 12/8110 ESTAFFORDI 7440-28.0 Thallium (TI) ICPMS 10 IOU ug1L EPA200.8 12/8110 ESTAFFORDI 7440-32-6 Ti (Titanium) by ICP 10 -10 U ugrL EPA 200.7 ' ' 12/8110 ESTAFFORDI 7440-62-2 V by ICP 25 25 Y ug1L. EPA 200.7 12/9110 ESTAFFOR01 7440-66-6 Zn by ICPMS tc' 10 10 U ug1L EPA 200.8 1218110 ESTAFFORDI Laboratory Sactiana> 1623 Mall Service Center, Raleigh, NC 27699-1623 (919) 733.3908 Fora detailed description of the quallfler codes refer to htimilli2ctel nodritf 011olifirrs � - I Page 2 of 2' CGuwTV - iE• `t f-i RIVER BASIN REPORT TO 4 Regional Office Otlscr o • COLLECMR(S) : ..- e,..74B/Ls rfrt- - Eafmated ROD Raab . Seed_ -47btariaaeed: D 314 M94- COD HtAh 340 COD Lars 335 Cefiform'. MF Fecal 31616 /loom] Colifarm MF Total31504 lI00ml Colifnrm- tube Focal 31615 /100tu1 Coliform: Fecal SVrp 31673 /100m1 Residue. Total 500 Volatile 505 Fixed 310 Resrdue, Suwerbded 530 mFVL Volatle 335 MWL Fucd Sao MWL H 403 units Ac,dity to pH 4.5 436 Acidity to pH 8 3 435 TOO- AlkahniTy to pH9.3415 Alkalinity to 9H 4 5 410 mwL TOC 680 Twbidny 76 NTU Coldoun Top! Tube lF00 to! DWiSION OF WATER QUALITY C7semdWy Laboratory Report / Water Quality El SAMPLE ME AMBIENT E3QA ST'4LFAM El EFFLUENT ',�CGMPUANCE CHAIN OF CUSTODY LAKE INkUENT EMERGENCY VISTTIU NARY Sgtiaaluntioe_ �vyo 4�Occlii�Y' < Chloride 940 MWL Chi a EPA 445 0 modified Color. True 80 c - Cokw: H 83 c.u. Color: ptl 7.6 82 c.u. Cywudu 720 ut Fluoride 951 Fvrma4 71$80 Crease and Oils 556 Hardnen Total 900 Spec&u Cmtd. 95 umhaslcto MBAS 33260 Phenob 32730 Sulfate 945 Sulfide 145 MWL Baran Tamin Haavalud Clvotm= u Btewbonate m CarbrnateMWL Dial Dissohed Solids ' NH3mN610 TKN an N 625 N02 phu NO3 as N 630 m IL P. Total as P 665 I PO4 as P 70507 PDissolved as P 666 K-Potassium Cd- Cadmhan 1027 Cr1'hroraium:Total F034 u Cu- C I042 Ni-Ntckcl 1067 Pb� Lead 1051 Zto- Zinc1092 PEEL V-Vanadium - Sily 1077 Al- Ahmr— 1105 Be- Ekryflim 1012 UWL Ca- Ca cimo 916 ro Co- Cobalt 1037 Ft- Iran 1045 ti. mmdybd. USIL Sir fl, Sn-Tin u L T?_ U911, Ti-Titanium v 1631 n lab Number ' Date Re"mcd e! Tmie Received Received By D 5 Data Relcased Date Reported Li -Lithium 1132 us"], mg- iuro 927 Mn-Manwmese 1055 u 'L Na- Soditan 929 nE Arsenic'ToW 1002 1 Se- Selenium l 147 WrL Ns- mercn 71900 U91, 8a-Batum u 'L iorine Pcs[icrdcs Or horns Pesticides Organontbwen Pesticides Acid Hcrbim&3 8a3e/Neuual&Acad ExtractabieOraamc TPH Diesel Ran c cable Or ies VOA bottle • 'd TPH Crasaline ltan TPHlBTFY Gasoltne RanSt P i lankton l LAGOaN 2 N DISCHARGE WASTEWATER MONITORING REPORT I'}:RIti'I'SUV11tER: WQ0 SG6 MONTH Stptember FACILITY N'A%IF.; Novo mes N, th America, Inc. CLASS: 2 COUNTY: Page 1 of I_ YEAR: 201(1 FRANKLIN 12Sarnol I l t�pclplur Arna111 'kmc 2.100 Cluck htxremi 'I'inie un Sile ORC On Sile". 40000 00940 7 0,0 6i0.000 530 70300 9290 1 916.0 1 927,00 1 931,00 1 620.00 r,23,0 665.00 Daily Rate (Flow) into Treatment system ada he DOW DriOrtoInIoefionf11£�31hf- Tl r i i4P. 1'KN Pha urus I{ Chloride BOD-5 20 C NH3•N rSS TDS Na Ca Mg SAR NO3•N IIRS I YIN MGD UNITS M01L MG/L MOIL MOIL MOIL MO/L MGlL MOIL MQL M(llL MG1 1 0800 : 8.0 :'. ;' :'.0:635::::;:$ 13:::: ::::: ::..::.:.:: : :.'.::.:.::::::....::::::: ,.:;::,:;::;:::: 2 0800 8.0 Y 0,804 8.16 3 0800 .. 8:0 :Y . :':0:687.:::812. .. 1 0.725 6 0800 8.0 Y 0,707 8.10 7 0800 ,, : •8;0 :�•�Y `� ': '0:55G�� � �:�822:'. �:;';:�:.'.:�:.:. �:�:.•,:::.:..: �•::• • ' � ':' �:�: '�'�:: '•..'.:,:•' ::: ��.•::• .... . 8 0800 8.0 Y 0.655 8.23 330 12.0 1.500 28 2100 153.0 22.8 4.60 7.62 12,00 6.7 50 u ON . , 8:0 . Y 0:580.: ' '8:28` :: :: :' :: ': 1(1 0800 8.0 Y 0,599 12 0.571 13 0800 8.0 . v 0:657:: : 8 39:'::: ::::::':':::` :: . :: : ::: :::.:.:...:.::::::::::::.. ......:: 1 i 0800 8.0 Y 0.446 8.43 15 o8w 8.0 V'. ':0.638:. :'8:1 2 16 080o 8.0 Y 0,532 8.07 171 1180O 9.0 ,::•:y.:;.:.':�:6f31 :: : 8 1 }:::::::::> ::::::::: ::::::::::::::::::::::::::':::,:;:.::::; :;:.:::.:,:.::::, ;::;: ;::;;;:.:.: ;:::;:; ::, :: :::': ' :::: .: ;: ; . :: 181 0.510 20 0800 8.0 Y 0,634 8,09 21 0800 ' KOY : '.'0:63(f'.'•' ':' 8.h7.':::.:.'.'•' .'; :::'' ::.'::: ',': .':',';; ::.'< .'.':.: .':•>.': '''.'' .'.•, .' .':', :. 22 U800 8.0 Y 0.532 8.94 2-10900 9.0 Y,.- :'0362:';::.:&56.:' :: :: ; 8a}':':::4:640: ' ;:• :.::.:; :: ' . 720 5,7 45 2.1 0800 8.0 Y 0.625 8.63 r, 0,680 27 0800 8.0 ` y :O:7f?8: : 8:52 ::'::':: :::::: :': ::::':::::::::':; :'::.....:::. .::::.:; 28 0800 8.0 Y 0.661 8,59 ,,I (J800 9.0 r:':.`0:836:!'" .42. ... ;I] 0800 8.0 Y U.9?7 8.56 ��'F:ItAGE 0,628 NIA 10.0 1.070 28 NIA 153.0 22.8 4.60 7.62 9.60 6.2 47.50 alAxtsluM:....' :::':0:927::::::8 y4:: NIA :: a2aa :' :':T:504::::<: 28 :: .:N/A':;::::1:53;A': 22:$::. :` :60:':::::7:62:. '':12,00::::0,7: 50-00.. �1rvl�tukl 0.432 8.07 NIA 8.0 0.640 28 NIA 153.0 22.8 4.60 7.62 7.20 5.7 -15,00 �lunthl .Limit.. ('urnnsilc (C crab( ! CI G NIA G G G NIA G C G G G G U A AFI'tc:1 r UrIN E'N L.ItAKIiG tUlILL) KAINU7 4.k;ILtrl rr GKAUP .f ruunlr. (viv)4vw-.»yv CHECK I3OX ] h ORC HAS CHANGED 0 ('ha T11:11-:I) LABORA-MRIES (1) ENCO (2) 1'1i14SONtS) ('OI.I.f'C'1'IN(r SAMPI,ES: Runde Cutchin ,i0r+RhfINA1.and TWO 00P1 Nto: A I"1 \; ('(INIPLIANCE GROUP lilt.OF h:NVIRON'.NIF..vTAE. NIANAGENIENI' PI-AINR P.O. 15OX 2953S RALEIGII, NC 27626-0535 NDIOR-I (7:94) Y 4,64 t%VL� - (SI(WA,rURJ1 OF OPEYATORi RFSPONSI i0KNOWIXI)GE, E) RECEIVED BY THIS SIGNATU �� �RT IS ACCURATE ANT) CO I OCT 2 8 2010 NOV - 1 2019 Inlo(mation ptocessiA Unit NG OENR D\N0jB0G Raleigh RagiOrlar Otfir,n r , . Cooling Tower Flow Totals Start End Time interval 0 Gallons 8/15/2010 1d Date FEH Cooling FEH Cooling Delta FEH cooling Total based on tower city tower city tower flow rate water makeup water makeup .> blowdown RT based on based on flow running total rate 15-Sep-10 00:00:00 139,168 138,437 ' 731 12,292 12,161 14-Sep-10 00:00:00 169,783 170,637. -854 37,523 37,202 13-Sep-10 00:00.00 147,448 144,075 3,373 20,000 19,896 12-Sep-10 00:00:00 111,312 113,738 -20426 1,364 1,275 11-Sep-10 00:00:00 97,188 97,632 .. ` -444 936 885 10-Sep-1000:00:00 117,748 117,942 ''. . =194' 2,369 2,252 09-Sep-10 00:00:00 1310228 131,115 114. 1,496 1,431 08-Sep-10 00:00:00 1620681 161,868 `: 8.1311 32,101 32,229 07-Sep-10 00:00:00 1650927 166,050 -123' 28,812 28,676 06-Sep-10 00:00:00 196,965 196,813 151. 10,795 10,817 05-Sep-10 00:00:00 155,047 155,605'..° -558 12,308 12,325 04-Sep-10 00:00:00 1660356 166,364 !`: -8 36,830 36,804 03-Sep-10 00:00:00 151,325 151,605 _ -280,: 27,328 27,221 02-Sep-10 00:00:00 126,783 126,274 ;;,. 509' 21,559 21,554 01-Sep-1000:00:00 186,978 186,325' 653 71,895 71,181 31-Aug-10 00:00:00 187,282 186,620 662' 71,606 72,327 30-Aug-10 00:00:00 177,360 178,501 -10142 27,737 27,686 29-Aug-10 00:00:00 142,572 142,753 .: -182 15,674 15,735 28-Aug-10 00:00:00 146,996 147,312 -316; 26,034 26,300 27-Aug-1000:00:00 116,886 117,121 '. -235 20,045 20,068 26-Aug-10 00:00:00 127,056 r. 1260757 :: 299 20,495 19,602 25-Aug-10 00:00:00 118,256 118,895 . -639 15,952 16,689 24-Aug-10 00:00:00 99,769 99,441 ` 328 11,426 11,339 23-Aug-10 00:00:00 96,375 97,146 -771 12,681 12,676 22-Aug-10 00:00:00 114,234 114,297 -63 16,089 16,124 21-Aug-10 00:00:00 97,662 970056 607� 14,346 14,357 20-Aug-10 00:00:00 79,409 800261 -852 5,456 5,478 19-Aug-10 00:00:00 74,852 74,529 324 11,467 11,428 18-Aug-10 00:00:00 83,329 83,779 -= -449'; 18,369 18,342 17-Aug-10 00:00:00 112,760 112,893 -133 20,441 20,402 16-Aug-10 00:00:00 66,029 66,148 -119 10,308 10,307 15-Aug-10 00:00:00 114,367 114,455, -87, 9,223 9,214 FFI cooling tower city water makeup RT 60,126 46,420 58,320 50,853 39,644 58,424 45,349 69,594 87,416 94,876 82,774 100,413 104,011 93,236 78,979 21,987 497 0 0 716 1,119 0 0 0 612 748 14,135 0 3,611 25,707 38,901 32,636 FFI cooling tower city water makeup based on Flow Rate 87,762 67,013 83,126 63,909 65,341 89,836 72,206 82,079 100,391 104,606 92,665 103,278 110,716 93,596 87,306 24,787 498 22 9 681 1,137 53 13 18 643 688 23,333 0 6,801 40,953 71,286 46,692 FFI cooling tower Blowdown baed on running total 8,924 4,735 10,239 6,469 6,817 7,042 1,967 14,480 27,992 33,312 35,026 36,007 33,126 34,895 17,039 2,047 0 0 29 5 33 86 1,124 3,163 3,252 4,977 4,161 4,496 9,200 18,374 0 0 FFI cooling tower Blowdown baed on flow rate 11,850 9,534 12,603 7,025 7,392 12,236 2,477 13,797 31,643 36,494 36,444 36,343 36,370 36,532 18,374 2,123 6 11 120 51 99 153 1,232 3,768 4,120 7,328 6,823 5,359 8,816 21,992 5 1 i {k Delta FHG Cooling FHG cooling tower city tower city j water make up water makeup Ned on based on flow running total rate i -2,9261 0 -267,693 -4,8001 0 -267,962' -2,3641 0 -268,0561. -556; 0 -267,793. -574i 0 -268,034 -5,194{ 0 -267,754' -510` 0 -267,624 683' 0 -267,890 -3,651, 0 -267,955. -3,183! 0 -267,919 -1,4181 0 -267,927 -33& 0 -268,099 -3,244' 0 -268,040' -1,637` 0 -267,990 -1,335iF 0 -267,974 -76E 0 -267,721. -6; 0 -267,282 -11 0 -267,3241 -91', 0 -267,532 -46` 0 -267,016 -66` 0 -261,696 -67 0 -201,728, -108: 98,544 46,888 ; -605r 131,952 156,740 -869i 312 -119,898; -2,3503 0 -46,114' -2,66Z 272 36,359 -863 206,080 411,574, 384� 752,200 1,080,000 -3,618j 752,528 1,080,000 -5, 752,832 1,080,000� -1; 751,848 1,080,000 Delta FHG cooling i tower Blowdown baed on running total 267,693 267,962' 268,0561 267,793 268,034 267,754 2 67, 624 267,890. 267,955. 267,919 267,9271 268,099' 2681040' 267,990' 267,974, 267,721 267,282; 267,324; 267,532. 267,016; 261,696 201,728' 51,656: -24,788 120,210! 46,114 -36,087 -205,494- -327,800; -327,472: -327,16& -328,152' 3,249 4,833 2,529 4,795 4,304 2,812 2,393 4,745 3,763 4,080 4,497 4,635 7,623 3,271 5,343 7,785 7,021 5,387 6,101 3,654 0 10,416 1,418 6,855 6,135 8,549 7,113 5,458 8,213 6,939 0 0 FHG cooling tower Blowdown baed on flow rate 3,524 5,231 2,7611 5,216; 4,668; 3,102, 2,574: 5,060, 4,064 4,4681 4,9271 5,0451 8,176, 3,308 5,393, 7,795 6,841 5,296 5,986 3,543 -4 10,084 1,3711 6,586 i 5,887 8,252 7,144 5,253 7,993; 6,857 -4, -4 delta 1 -274�1 -3981 -232 -421 1 -364: -290 -1$11 -316 -301 -388 -4301 -410 -553 -37 -50 i -101 180 91! 115< 111 4 332 47 270' 248. 298 -31, 205 221' 82 i 41 4 Permit # NCS000115 Month: December. Year: 2010 Facility: NOVO mes, NA, Inc. Class: County: Franklin ORC: Grade: ORC Certification # Has,ORC Clanged?: i' Phone: (919) 494-3000 Certifed.Lab Name: Prism Laboratories Lab#: Person(s) Collecting samples: Houston,Cash, Joe Ladd Comments: Effluent -collected fromFEG cooling tower at 1308; analyzed at 1310. Sampling Location: Effluent Discharge # VEO DER ,71e1ghgeaSN rnfl w ` ' w w � • • ' . � � � � � ■�■■■ ■■■�� �■■■■� ■tee ��■�■■ �■ Monthly Average: ► _ ����� I Permit # NCS000115 • Month: December Year: 2D10 Facility: Novoz mes,'NA, Inc. Class: County: Franklin ORC: Grade: ORC Certification # Has ORC Changed?: r Phone: 919 494-3000 Certifed Lab Name: Prism Laboratories tab#: Person(e) Collecting samples: Houston Cash, Joo Ladd Comments: Effluent collected from FHG cooling tower at 1338, analyzed at 1341. Sampling Location: Effluent Discharge # t"IECEIVE® FEB 1 12011 NO DENR RaNgh Reaional Of f ®tee �■■ ■�� �� �� �■ �� �� � �■■■�■ �� Monthly :._�� , Dally Maximum: �■�ca��■■■o�� Permit # NCS000115 • Month: December, Year: 2010 • Facility: Novozyi-nes, NA, Inc, Class: County: Franklin ORC: Grade: �ORC Certification #` Has ORC Changed?; r Phone: (919) 494-3000 Certifed Lab Name: Prism Laboratories Lab#: Pereon(s) Collecting samples: Houston Cosh, Joe Ladd Comments: Effluent collected from FEH cooling tower at 1320, analyzed at 1322. Sampling Location: Effluent Discharge # RECE1 VED EER 1 12011 Nclati '?*k Rea on i nfgce ----- 1 1 1 1 1 1 1 1 11 1 i l: l � 1 •. 1 i � �■■�■ �■■ � �� �■� s �� � � �■ ■ter < < ������ Penmit #' NCSOOO115 Month: June Year: 2010 Facility: Novozymes; NA, Inc. Class: County: Franklin ORC: Grade: ORC Certification # Has ORC Changed?: r Phone: (919) 494-30M Certifed Lab Name: Prism Laboratories Lab#: Person(s) Collecting samples: Houston Cash, Joe Ladd Comments: Effluent collected'from Cooling Tower FHG at 1449, analyzed at 1458 Sampling Location: Effluent Discharge # :.:��. Daily �rn�����■r� Permit # NCS000115 Month: June Year. 2010 Facility_ Nnvo mes„NA, Inc. Class: County: Franklin ORC: Grade: ORC Certincatlon # Has O.ft.0 Changed?: . 17, Phone: 1919) 494300D Certifed Lab Name: Prism Laboratories LabO-. Person(ej Collecting samples: Houston Cash. Joe Ladd Comments: Effluent collected from Cooling Tower FEH at 1411. analyzed'at 1422 .-... Samplirig,Location: Effluent Discharge #. RECEIVED FEB 1 12011 Rafeigh eaionaloft ■■ice � � �� �� � ■�■ ■■�� ■■�� �■ � Mon*WAVerag: Daily Maximum: ■�����v� .:�����© Permit # NC5UU0115 MOrIthr June. Year: 2010 Facility: Novozymes, NA, Inc. Class: County: Franklin ORC: Grade: ORC Certification # KOM Has ORC Changed: r Phone: (919) 494-3000 FEB I 17011 Certifed'L.ab Name: Prism Laboratorles Lab#: HOW Person(s) Collecting samples: 'Houston Cash, Joe Ladd �e4elah �aafanal ilt�cs Comments: 9#16ont collected from Cooling Tower FEG at 1355, analyzed at 1402 Sampling Location: Effluent Discharge # Aver -age Limit DailyMonthly : 1 Monthly Avg . : ---- - ! 1 W Emergencies — Ext. 2222 Site Map 1 Evacuation Gathering Areas Security — Ext. 3220 LEGEND A Evacuation Area for FIH B Evacuation Area for FHG. FGH. FFF. and FFG C Evacuation Area for FHI and FFI D Evacuation Area for FFK E Evacuation Area for FEI. Eng. & Env. Ops. ................ F Evacuation Area for G Site -Wide Evacuatioa Are H Emergency Evacuation Crates Ammonia Alarm "Shelter in Place" Locations Coaling Tower Chiller Buildin A-oi� (FF ) T i Receiving Warehouse Receiving Office Ext. # 3248 Contractor "Trailers utility Control (FFG) Room Fermentation Co"trc Room Lt. 4 4300 trol Roo E t. # 4370 (FGH) . Pilot Plant (Fence Line) .................... Waste Water Lagoons Utilities Building Control Room Ext. # 4600 ❑ O Recovery . (FFI) Control Room Ext. # 4400 * conaol Shipping Warehouse / Granulation Tower (FFK) 07 �I L .. . ............... (P Production Admin & Employee Sv Building � . Business (FHG) ■■■■■■ ................ From Lobby ................................ Control Room r;st. # 3225 Ext. # 4700 Operations ..................................... ...... (FH) (F) Administration Building Front Hall BOB Man Coe[ w Room f Ext, # 4214 rr Ii dldd I Visitor's Safety Information novozymes® Rethink Tomorrow Welcome! This Safety Information sheet contains important information which is vital to your health and safety. Please read it before entering. General Plant Information 1. In case of an emergency dial 2222, give the location of the emergency and state your name clearly. 2. While on the Novozymes site, visitors must remain with Novozymes personnel who will inform them of potential hazards. Please stay alert and avoid moving traffic and machinery. In the unlikely event of an evacuation or shelter in place, your Novozymes contact will instruct you on the proper procedures. Eye wash and safety showers are located throughout the facility for emergency use. 3. Visitors are only allowed in authorized locations. 4. ABSOLUTELY NO TOBACCO USE OR SMOKING is allowed on Novozymes company property S. Alcohol, drugs and weapons are not permitted on Novozymes property. 6. Safety glasses, hearing protection, and hard hats are required in designated areas. 7. No film photography, digital photography, or video recording is allowed in the facility unless authorized in writing by a member of NZNA site management. 8. Novozymes !North America maintains a certified environmental management system called EQS (Environmental Quality System) to assure compliance and continually Improve environmental performance, A copy of the Novozymes Environment and Bioethics Policy is available upon request 9. Always return your visitors pass to the Receptionist, Weigh Station, or the Security Console to ensure proper head count in the event of an emergency. VISITOR EMERGENCY PROCEDURES Fire Alarm • Fire alarms are identified by the loud continuous horn and strobe lights. If the alarm sounds during your visit, walk directly to the nearest exit and use the map on the reverse side of this document to identify your evacuation assembly area. Each area is identified by a red circular sign with an accompanying letter. Assemble with your Novozymes contact for the headcount and return to the building only when the all clear is given. Ammonia Alarm • Novozymes uses anhydrous ammonia in its production process. In the unlikely event of a large ammonia release, please proceed to the closest shelter -in -place location marked on the map. The ammonia alarms can be recognized by the outdoor sirens, announcements made over the plant paging and radio systems, and by the on/off sequence from the building fire alarms. Each shelter area is marked by a green star hanging from the ceiling. Make sure to identify yourself as a visitor when gathering in the shelter area for the headcount and await further instructions from emergency officials. Plant -Wide Evacuation • if a plant evacuation is ordered via the paging and radio systems, please proceed to the evacuation assembly area marked by a blue circle on your emergency map. Severe Weather • If a tornado or other significant severe weather is reported in close proximity to the facility, a severe weather shelter order will be given via the paging and radio systems. Severe weather shelter areas are identified by the projecting wall signs with a tornado on them and are located at interior restrooms and stairwells throughout the facility. When in the shelter, crouch down low to the floor and protect your head/face with your arms. Environmental Conservation Labolories, Inc. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone; 919.467.3090 FAX: 919.467.3515 Thursday, December 16, 2010 Novozymes North America (N0008) Attn: Joe Ladd 77 Perry Chapel Church Road Franklinton, NC 27525 RE: Laboratory Results for Project Number: 12110, Project Name/Desc: Outfall Sampling ENCO Workorder: C014251 Dear Joe Ladd, • www.encolabs.com Enclosed is a copy of your laboratory report for test samples received by our laboratory on Thursday, December 2, 2010. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, s Chuck Smith Project Manager Enclosure(s) The total number of pages in this report, including this page is 19. RECEIVED FFp 1 11011 NO DER 4�a1e1g1�Rantonal D�CB ! RECEIVE[* EEB 1 12011 E,N MM) NC DENR www.encolabs.com Raleigh Regional fjf ce l Parameter ----------------------------------------- Hold Date/Time(s) --------------------- Prep Date/Time(s) ---------------------------------- Analysis Date/Time(s) ------- ------ --------------------- EPA 200.7 05/30/11 12/02/10 14:51 12/8/2010 13:59 EPA 350.1 12/29/10 12/09/10 07:49 12/9/2010 11:11 EPA 351.2 - 12/29/10 12/09/10 11:12 12/10/2010 14:00 EPA 353.2 12/29/10 12/03/10 07:16 12/3/2010 12:31 EPA 353.2 12/29/10 12/06/10 10:41 12/6/2010 10:58 EPA 365.4 12/29/10 12/09/10 11:12 12/10/2010 16:57 SM 2540C 12/08/10 12/07/10 16:28 12/7/2010 16:28 SM 5210B 12/03/10 11:50 12/02/10 16:07 12/2/2010 16:07 Parameter Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) ...................... . ...................... ................. EPA 300.0 12/29/10 12/06/10 07:27 12/7/2010 06:51 Parameter ....................................... Hold Date/Time(s) Prep Date/Time(s) ---- -- -- Analysis Date/Time(s) ... ........................... EPA 200.7 . 05/30/11 12/02/10 ................. 14:51 12/8/2010 14:02 EPA 300.0 12/29/10 12/06/10 07:27 12/6/2010 18:00 EPA 350.1 12/29/10 12/09/10 07:49 12/9/2010 11:17 EPA 351.2 12/29/10 12/09/10 11:12 12/10/2010 14:03 EPA 353.2 12/29/10 12/03/10 07:16 12/3/2010 12:33 EPA 353.2 12/29/10 12/06/10 10:41 12/6/2010 10:58 EPA 365.4 12/29/10 12/09/10 11:12 12/10/2010 16:58 SM 2540C 12/08/10 12/07/10 16:28 12/7/2010 16:28 SM 5210B 12/03/10 13:35 12/02/10 16:07 12/2/2010 16:07 Parameter Hold Date/Tlme(s) Prep Date/Time(s) Analysis Date/Time(s) ......................................... ................. ... ------------ ..................... EPA 300.0 12/29/10 M06/10 07:27 12/7/2010 07:10 Parameter Hold Date /Tlme(s) Prep Date/Tlme(s} Analysis Date/Time(s) EPA 200.7 05/30/11 12/02/10 14:51 12/8/2010 14:05 EPA 300.0 12/29/10 12/06/10 07:27 12/6/2010 18:18 EPA 350.1 12/29/10 12/09/10 07:49 12/9/2010 11:19 EPA 351.2 12/29/10 12/09/10 11:12 12/10/2010 14:05 EPA 353.2 12/29/10 12/03/10 07:16 12/3/2010 12:35 EPA 353.2 12/29/10 12/06/10 10:41 12/6/2010 10:58 EPA 365.4 12/29/10 •12109110 11:12 12/10/2010 17:00 SM 2540C 12/08/10 12/07/10 16:28 12/7/2010 16:28 SM 5210B 12/03/10 12:50 12/02/10 16:07 12/2/2010 M07 Page 2 of 19 CSN9 - - www.enwlabs.com Parameter Mold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 200,7 05/30/11 12/02/10 14:51 12/8/2010 14:09 RECEIVED FFR 1 1 101 NC DENh RaleighReainnai("cG Page 3 of 19 • MOVED FEB 1 12011 EEJNO r` AIG DENR www.encolabs.com Raleigh Replonal Me@ SAMPLE DETECTION SUMMARY Analyte . ....................... Results Flag MDL ..... ........ PQL Units --.... Method Notes ............... Barium - Total . ............... 87.9 3 10.0 .... 100 ug/L EPA 200.7 Calcium - Total 73500 200 1000 ug/L EPA 200.7 Magnesium - Total 20300 230 1000 ug/L EPA 200.7 Manganese - Total 15.4 JB 11.0 100 tog/L EPA 200.7 QB-01 Nitrate as N 3.4 0.025 0.10 mg/L EPA 353.2 Nitrate/Nitrite as N 3.7 D 0.25 1.0 mg/L EPA 353.2 Phosphorus 2.5 0.021 0.10 mg/L EPA 365.4 Potassium -Total 29300 1500 5000 ug/L EPA 200.7 Sodium - Total 132000 4000 5000 ug/L EPA 200.7 Total Dissolved Solids 730 10 10 mg/L SM 2540C Total Kjeldahl Nitrogen 1.7 0.14 0.48 mg/L EPA 351.2 Zinc - Total 88.5 3 38.0 100 ug/L EPA 200.7 Analyte Results Flag MDL PQL Units Method Notes Chloride 100 D 0.072 20 mg/L EPA 300.0 Fluoride 6.7 D 0.017 0.80 mg/L EPA 300.0 Sulfate as SO4 140 D 0.48 20 mg/L EPA 300.0 Ilent ID: OF Up 13TI-D-3 Wg14251=UX Analyte Results Flag MDL PQL Units Method Notes ........ .... ........ ......... Ammonia as N ................. 0.45 ..................... ................. 0.0096 0.10 I...... mg/L ................ --------- EPA 350.1 Barium - Total 72.9 3 10.0 100 ug/L EPA 200.7 Biochemical oxygen Demand 2.0 2.0 2.0 mg/L SM 52108 Calcium - Total 57400 200 1000 ug/L EPA 200.7 Chloride 84 0.018 5.0 mg/L EPA 300.0 Copper - Total 54.7 3 16.0 100 ug/L EPA 200.7 Magnesium - Total 15400 230 1000 ug/L EPA 200.7 Manganese - Total 41.6 JB 11.0 100 ug/L EPA 2003 QB-01 Nitrate as N 3.0 0.025 0.10 mg/L EPA 353.2 Nitrate/Nitrite as N 3.1 D 0.25 1.0 mg/L EPA 353.2 Phosphorus 2.0 0.021 0.10 mg/L EPA 365.4 Potassium -Total 24900 1500 5000 ug/L EPA 200.7 Sodium - Total 101000 4000 5000 uglL EPA 200.7 Total Dissolved Solids 600 10 10 mg/L SM 2540C Total Kjeldahl Nitrogen 1.9 0.14 0.48 mg/L EPA 351.2 Zinc - Total 330 38.0 100 ug/L EPA 200.7 Analyte Results Flag MDL PQL Units Method Notes ..... .... ................ -... ...... .............. .. Fluoride 5.1 D 0.017 0.80 mg/L EPA 300.0 Sulfate as SO4 120 D 0.48 20 mg/L EPA 300.0 Analyte Results Flag MDL PQL Units Method Notes ......... ........ ..... ............ Barium - Total ............................ 66.5 J ...... 10.0 ... ....................... 100 ug/L ......-------------- EPA 200.7 Calcium - Total 9100 200 1000 ug/L EPA 200.7 Chloride 14 0.018 5.0 mg/L EPA 300.0 Fluoride 0.092 ] �0.0043 0.20 mg/L EPA 300.0 Page 4 of 19 • i www.encolahs.com Analyte ........ ........... Results Flag MDL PQL Units Method Notes ............ Magnesium -Total ........ ............................... 2540 230 ........ 1000 ---- ................................... ug/L . EPA 200.7 Manganese- Totai 18.3 ]B 11.0 100 ug/L EPA 200.7 QB-01 Nitrate as N 2.4 0.025 0.10 mg/L EPA 353.2 Nitmte/Nitrite as N 2.4 D 0.25 1.0 mg/L EPA 353.2 Phosphorus 0.076 1 0.021 0.10 mg/L EPA 365.4 Potassium -Total 5510 1500 5000 ug/L EPA 200.7 Sodium - Total 13700 4000 5000 ug/L EPA 200.7 Sulfate as SO4 3.3 3 0.12 5.0 mg/L EPA 300.0 Total Dissolved Solids 100 10 10 mg/L SM 2540C Total Kjeldahl Nitrogen 0.58 0.14 0.48 mg/L EPA 351.2 Analyte Results Flag MDL PQL Units Method Notes ................................................................ ....... ................................ ................... Potassium -Total 583000 1500 5000 ug/L EPA 200.7 Sodium - Total 127000 4000 5000 ug/L EPA 200,7 RECEIVED FEB 1 12011 NC DENh Raleigh Replonal NO Page 5 of 19 Ce Nhk' :d�� - www.encolabs.com Description: FEH BD Lab Sample ID: C014251-01 Received: 12/02/10 09:32 Matrix: Waste Water Sampled: 12/01/10 11:50 Work Order: C014251 Project: Outfall Sampling Sampled By: Joe Ladd Metals by EPA 200 Series Methods ........ ................... .......... ^ - ENCO Cary -rbrAE d a-" [NC 591] Eeslllta flag !lulu DE MU HU Batch Meths Anal Notes Barium [7440-39-31 ^ 67.9 ] u91L 1 10.0 too OL02030 EPA 200.7 12/08/10 13:59 )DH Calcium [7440-70-21 ^ 73500 ug/L 1 200 1000 OL02038 EPA 200.7 12/08110 13:59 JDH Copper [7440-W8] ^ 16.0 U upfL 1 16.0 l00 OL02D38 EPA 200.7 12/08/10 13:59 )DH Magnesium [7439-95-41 ^ 20300 ug/L 1 230 1000 OL0203B EPA 200.7 12/08/10 13:59 3DH Manganese [7439-96.51 ^ 15.4 313 ug/L 1 11.0 100 OL02038 EPA 200.7 12/08/10 13:59 JDH QB-CI PoUsslum [7440-09-71 ^ 29300 ug/L 1 1500 5000 OL02038 EPA 200.7 12/08110 13:59 JDH Sodium [7440-23-S] ^ 132000 ug1L 1 4000 5000 OL02038 EPA 200.7 12/08/10 13:59 4H Zinc [7440-66-6] ^ 98.5 J u911. 1 38.0 160 OL02038 EPA 200.7 12/08/10 13:59 )DH - 'RECEIVED FEB 1 12011 NO DENR Raleigh Realollal Office Page 6 of 19 EN r www.encolabs.com Description. FEH BD Lab Sample ID: C014251-01 Received: 12/02/10 09:32 Matrix: Waste Water Sampled: 12/01/10 11:50 Work Order: CO14251 Project: Outfali Sampling Sampled By: Joe Ladd Classical Chemistry Parameters ............................... ........... ^ - ENCO Cary certified a-&W [NC 591] Analft [CAS Numbed Resull EAU units RE K" HU A=b Method AnIlZ d ft Note Ammonia as N [7664-41.7] A 0.0096 U mg/L 1 0.0096 010 OL09004 EPA 350.1 12/09/10 11:11 CCB Blochemiml Oxygen Demand [ECL-0017] ^ 2.0 U mg/L 1 2.0 2.0 OL02031 SM 5210B 12/02/20 16:07 ]OC Chloride [16867-00-6] ^ 100 D mgiL 4 0.072 20 OL06002 EPA 300.0 12/07/10 06:51 PEV Fluoride [16984-48.8] ^ 6.7 D mg/L 4 0.017 0.80 OL06002 EPA 300.0 12/07i10 06:51 PEV Nitrate as N [14797-SS-B] A 3.4 mg/L 1 0.025 0AC CLC6016 EPA 353.2 12/06/10 10:5B PEV Nitrate/Nitrite as N [ECL-0010] ^ 3.7 D mg/L 10 0.25 1.0 CLC3003 EPA 353.2 12/03/10 12:31 PEV Phosphorus [7723-14-0] ^ 2.S mg/L 1 0.021 0.10 048027 EPA 365.4 12/10/10 16:57 CCB Sulfate as SO4 (14808.79.81 ^ 140 D mg/L 4 0.48 20 OL06002 EPA 300.0 12/07/10 06:51 PEV Total Dissolved Solids [ECL-0156] ^ 730 mg/L 1 10 10 OL03019 SM 2S40C 12/07/10 16:28 CCB Total Kjeldahl Nitrogen [ECL-01621 ^ 1.7 mg/L 1 0.14 0.48 OWS026 EPA 351.2 12/10/10 14:00 CCB This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 7 of 19 www.encolabs.00m Description; OF Lab Sample ID: C014251-02 Received: 12/02/10 09:32 Matrix: Surface Water Sampled: 12/01/10 13:35 Work Order: C014251 Project:-Outfall Sampling Sampled By: Joe Ladd Metals by EPA 200 Series Methods ......................................................................... . .. ......... ........... . ..........----....--........ ^ - ENCO Cary C-tfied analyte (NC 591] Analvte [CAS Numberl gesu11g EhQ Unlu QF MIZL HU @= McUwd Analyzed Jay )fig Barium [7440-39.3] ^ 72.9 J ug/L 1 10.0 100 OLD2038 EPA 200.7 12/08/10 14:02 JDH Calcium [7440-70-2] ^ 57400 ug/L 1 200 1000 OL02038 EPA 200.7 12/08/10 14:02 JDH Copper [7440-50-a] ^ 54.7 3 ugtL 1 16.0 100 OL02038 EPA 200.7 12/08/10 14:02 JDH Magneslum [7439-95-4] ^ 15400 ug/L 1 23D 1000 OL02038 EPA 200.7 12/08/10 14:02 JDH Manganese [7439-96-51 ^ 41.6 38 ugtL 1 11.0 100 OL02038 EPA 200.7 12/08/10 14:02 JDH QB-01 Potasslom [7440.09-7] ^ 24900 ug/L 1 1500 5000 OL02038 EPA 200.7 12/08/10 14:02 JDH 5odlum [7440.23.5] ^ 101000 ug/L 1 4000 5000 OL02038 EPA 200.7 12/08/10 14:02 JDH Zinc [7440-66-6] ^ 330 ug/L 1 38.0 100 OL02038 EPA 200.7 12/08/10 14:02 JDH �Eg���p11 �alelah�n°lanai Page 8 of 19 EN WWW.enCD]abs.com Description: OF Lab Sample ID: C014251-02 Received: 12/02/10 09:32 Matrix: Surface Water Sampled: 12/01/10 13:35 Work Order: C014251 Project: Outfall Sampling Sampled By: )De Ladd Classical Chemistry Parameters .--.-- . • ..........................................I........_..... --.--.--.I-.-- ----.--.--.--..... ..................... ........ ^ - ENCC Cary certified,3n,7 a ANC 591] AnalM MAS Numberl gesul Ems gnb DE HU HU A=b M Analyzed fx fi= Ammonia as N [7664-41-7] ^ 0.45 mg/L 1 0.0096 0.10 OL09004 EPA 350.1 12/09/10 11717 CCB Biochemical Oxygen Demand 2.0 mp/L 1 2.0 2.0 OL02031 SM 5210B 12/02/10 16:07 30C [ECL-0017] ^ Chloride [16887-00-6] ^ 84 mg/L 1 0.018 5.0 OL06002 EPA 300.0 12/06/10 18:00 PEV Fluoride [16984-48-8] ^ 5.1 D mg/L 4 0.017 0.80 OL06002 EPA 30C.0 12/07/10 07:10 PEV Nitrate as N [14797-55-81 ^ 3.0 mg/L 1 0.025 0.10 OL06016 EPA 353.2 12/06/10 10:58 PEV Nitrate/Nitrite as N [ECL-0010] ^ 3.1 D mg/L 10 0.25 1.0 OL03003 EPA 353.2 12/03/10 12:33 PEV Phosphorus [7723-14-0] ^ 2.0 mg/L 1 0.021 0.10 OL08027 EPA 365A 12/10/10 16:58 CM Sulrata as SD4 [1480B-79-8] ^ 120 D mg/L 4 0.48 20 OL06002 EPA 300.0 12/07/10 07:10 PEV Total Dissolved Solids [ECL-0156] ^ 500 mg/L 1 10 10 OL03019 SM 2540C 12/07/10 16:28 CCB Total Kjeldahl Nitrogen [ECL-0162] ^ 1.9 mg/L 1 0.14 0.48 OLD8026 EPA 351.2 12/10/10 14:03 CCB IntleVED ���9hgeaional This report relates only to the sample as received by tlx laboratory, and may only be reproduced In full. Page 9 of 19 Ce Nhk' www.encolabs.com Description: Creek Lab Sample ID: C014251-03 Received: 12/02/10 09:32 Matrix: Surface Water Sampled: 12/01/10 12:50 Work Order: C014251 Project: Outfall Sampling Sampled By: he Ladd Metals by EPA 200 Series Methods ^ - ENCO Cary ceRified ana4dr (NC 5911 Analvte rCAS Numbed Results fig UAIA pE MU MILL fig,[] Method Armed By Note Barium [7440-39-3] ^ 66.5 3 ug/L 1 10.0 100 OL02038 EPA 200.7 12/08/10 14:OS ]DH Uldum [7440.70-2] ^ 9100 ug/L 1 200 1000 OL02038 EPA 200.7 12108/10 KOS 3DH Copper [7440-W8] ^ 16.0 u ug/L 1 16.0 100 OL02038 EPA 200.7 12/08/10 14:05 ]DH Magnesium [7439-95-4] ^ 2540 ug/L 1 230 LOW OL02038 EPA 200.7 12/08/10 14:05 IDH Manganese [7439-96-5] ^ 18.3 13 ugA 1 11.0 100 OL02038 EPA 200.7 12/08/10 14:05 ]DH QB-01 Potassium [7440.09-7] ^ 5510 ug/L 1 1500 5000 OL02038 EPA 200.7 12/08/10 14:05 )DH Sodium [7440.23.5] A 13700 ug/L 1 4000 5000 OL02038 EPA 200.7 12/08/10 14:05 7DH Zinc [7440.66.6] A 38.0 u ug/L 1 38.0 100 OL02038 EPA 200.7 12/08/10 14:05 7DH RsEWED FEB 2011 A1C UENR Raleigh Reaialial ("flee Page 10 of 19 www.encDlabs.com Description: Creek lab Sample ID: C014251-03 Received: 12/02/10 09:32 Matrix: Surface Water Sampled: 12/01/10 12:50 Work Order: C014251 Project: Outfall Sampling Sampled By: Joe Ladd Classical Chemistry Parameters ^ - t VC0 Cary CerBW atw#te [NC S911 Analvte rCAS Number] Results flag Sf= jE MIX MU Batch fJgltliod Analyzed AX Noteg Ammonia as N (7664 41.7] ^ 0.0096 u mg/L 1 0.0096 0.10 OL09004 EPA 350.1 12/09/10 1 L19 CCB Biochemical Oxygen Demand [ECL-00171 ^ 2.0 V mg/4 1 2.0 2.0 OL02031 Sr4 5210E 12/02/10 16:07 30C Chloride [16887-00-6] ^ 14 mg/L 1 0.018 5.0 OL06002 EPA 300.0 12/06/10 18:18 PEV Fluoride [16984-48-8] ^ 0.092 1 m91L 1 0.0043 0.20 OL06002 EPA 300.0 12/06/10 18:18 PEV Nitrate as N [14797-55-8] ^ 2.4 mgJL 1 0.025 0.10 OL06016 EPA 353.2 12/06/10 10:58 PEV Nitrate/Nitrite as N [ECL-0010] ^ 2.4 D mg/L l0 0.25 1.0 OL03003 EPA 353.2 L2/03/10 12:35 PEV phosphorus [7723-14-0] ^ 0.076 ) mg/L 1 0.021 0.10 OL08027 EPA 365.4 12/10/10 17:00 CCB Sulfate as 504 [1480a-79-8] ^ 3.3 1 mgJL : O.12 5.0 OL06002 EPA 300.0 12/06/10 18:18 PEV Total Dissolved Solids [ECL-0156] ^ 100 mgJL 1 10 LO OL03019 SM 2540C 12/07/10 16:28 CCB Total xjeldahl Nitrogen [ECL-0162] ^ 0.58 mg/L 1 0.14 0.48 OL08026 EPA 351.2 12/10/10 14:05 CCB rn REGEWCU fE81 12011 RaleighR a�a alOf�ic� This report relates only to the sample as received b/ the laboratory, and may only be reproduced in full. Page I 1 of 19 www.encolabs.com Description: Lagoon 2 Lab Sample ID: C014251-04 Received: 12/02/10 09:32 Matrix: Surface Water Sampled: 12/01/10 14:00 Work Order: CO14251 Project: Outfall Sampling Sampled By: Joe Ladd Metals by EPA 200 Series Methods ^ ENCO Cary [ertlW a-lyte (NC 5911 Analvte [CAS Humberl Resull!g fin MEILU pE HU MU AlItch Method Auall13sd 1r dole, Potassium [7440.09-71 ^ 583000 ug/L 1 1500 5000 CLO2038 EPA 200.7 12/08/10 14:09 JDH WJum [7440-23-5] ^ 127000 ug/L 1 4000 5000 OL02038 EPA 200.7 12/OB/10 14:09 JDH RECEIVED � R 1 11011 NC OENk 331eigil Regional1lifice This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 12 of 19 RREIVED �__ www.encDlabs.com NC DENH QUALM CONTROL +Raleiah Regional Wee Metals by EPA 200 Series Methods - Quality Control Batch OL02038 - EPA 300M Blank (OL02038-BLK1) Prepared: 12/02/2010 14:51 Analyzed: 12/08/2010 12:44 Barium 1.00 U 10.0 ug/L Calcium 20.0 U 100 ug/L Copper 1.60 U 10.0 ug/L Magnesium 23 U 100 ug/L Manganese 1.4 3 10.0 uglL Potassium 150 U 500 ug/L Sodium 400 U Soo ug/L Zinc 3.8 U 10.0 ug/L LCS (01.02038-651) . ............ .................................................................. ...... ' Prepared: 12102/2010 14:51 Analyzed: 12/08/2010 12:56 Barium 485 10.0 ug/L 500 97 85.115 Calcium 4910 100 ug/L 5000 98 85-115 Copper 249 10.0 ug/L 250 99 85.115 Magnesium 4770 100 ug/L 5000 95 85-115 Manganese 239 B 10.0 ug/L 250 96 85-115 Potassium 24700 S00 ug/L 25000 99 85-115 Sodium 24900 500 ug/L 25000 100 65-115 Zinc ......... .----- ................... 487 .'---'--........-..-........................... 10.0 ug/L 500 97 SS-115 ...---......................... ............ .... Matrix Spike (OL02038-MS1) ......... Prepared: 12/02/2010 M51 Analyzed: 12/08/2010 13:11 Source: C013611-05 Barium 556 10.0 ug/L 500 71.1 97 75-125 Caidum 27200 l00 u9A 5000 21500 112 75.125 Copper 314 10.0 ug/L 250 66.5 99 75.125 Magnesium 20500 too ug/L 5000 i5700 96 75.125 Manganese 800 B 10.0 ug/L 250 562 95 75.125 Potassium 28100 S00 ug/L 25000 2950 101 75.125 Sodium 46300 500 ug/L 25000 22000 97 75-125 Zinc 611 10.0 ug/L 500 136 95 75.123 ........-'--'-.................'--'--..-'-- Matrix Spike Dup (OL02038-MSD1) ..--'--'--'--'--'--'--'-- .. ----...........--................................................. Prepared: 12/02/2010 14:51 Analyzed: 12/08/2010 13:13 Source, C013611-05 Barium 559 10.0 ug/L 500 71.1 98 75-125 0.7 25 Caldum 28100 100 ug/L 5000 21500 132 75-125 4 25 QM-07 Copper 312 10.0 ug/L 250 663 98 75.125 0.7 25 Magnesium 21400 100 ug/L 5000 15700 114 75.125 4 25 Manganese 809 B 10.0 ug/L 250 562 99 75-125 1 25 Potassium 28400 500 u911- 26000 2950 102 75-125 1 25 Sodium 4690C 500 ug/L 25000 22000 100 75-125 1 25 Zinc 619 10.0 ug/L 500 136 97 75-125 1 25 Page 13 of 19 RECEIVED N6 9) FFR 1 12011 www.encolabs.com NC DENn QUALITY CONTROL NC Reaianal Office Classical Chemistry Parameters - Quality Control Batch OL02031 - NO PREP Blank (OL02031-BLK1) Prepared & Analyzed: 12(02/2010 16:07 Biochemical Oxygen Demand 2.0 U 2.0 mglL • ........................................................................................................................... LCS (OL02031-BS1) Prepared & Analyzed: 12/02/2010 16:07 Biochemical Oxygen Demand l80 2.0 mg/L 198 92 85-115 .................... .......... ........................................... .......... -.............. ------.............--.--'- - Duplicate (OL02031-DUP1) Prepared & Analyzed: 12/02/2010 16:07 Source: C012812-01 Biochemical Oxygen Demand 320 2.0 mg/L 330 2 25 .................................... -........ -........................... ----....................... ..................................... Ba" OL03003 - NO PREP Blank (OL03003-BLK3) Prepared: 1403/2010 07:16 Analyzed: 12/031201G 10:49 Nltrate/Nitrtte as N 0.025 U 0.10 mg/L LCS (OL03003-BSI) Prepared: 12/03/2o10 07:16 Analyzed: 12/03/2010 11:17 Nitrate/Nb ite as N 1.2 0.10 mg/L 1.25 93 90-110 - ----" ....-" ..............'-----'- "......... .......................--------.................'--.'-------..--.--.--.--......-------." Matrix Spike (OL03003-MS1) Prepared: 12/03/2010 07:16 Analyzed: 12/03/2010 11:21 Source: COIIS19-01 NiVaWNWte as N 0.043 0.10 mg/L 0.513 0.006 7 90-110 QM-05 Matrix Spike Dup (OL03003-MSDI) Prepared: 12/03/2010 07:16 Analyzed: 12/03/2010 11:23 Source: C011819-01 ' l a Spike' 5ouroea „ iV9raREC § & RPD /lnalytell za _ �) di' ,Result Flap.,, .? MRL Onitsry .".Level -. a�Result��.d,.°JaRBC r,i<;Llmits7.;�a.RpD ,; Limit'.;' Nobel, Nitrate/Nitrite as N 0.040 0.10 mg/L 0-513 0.006 7 90-110 7 10 QM-05 Batch OL03019 - NO PREP Blank (OL03019-BLK1) Prepared & Analyzed: 12/07/2010 16:28 Total Dissolved Solids 10 U 10 mg/L .............."'.............................-" -" .... ------ .......----" ..........--" '-'......-----....--.--.--.-...-•.••.-- LCS (OL03019-BSI) Prepared & Analyzed: 12/07/2010 16:28 ' ike �'�i Source , 4�ICEC P r RPD s Lfr Ana[yte Rewlt Flap MRL Units Cevel Rewlt l 9 REC - Limits RPD L mlt KaEes7 Page 14 of 19 • � VED REc CS N FEB1 I �U� ! www.encolabs.com NO UENR QUALITY CONTROL RaWighReoionaInft Classical Chemistry Parameters -Quality Control Batch OL03019 - NO PREP r LCS (OL03019-BSI) Continued Prepared & Analyzed: 12/07/2010 16:28 Total Dissolved Solids 290 10 mg/L 300 96 90-110 ................... ........................ -------------- ........... ........ ................ Duplicate (OL03019-DUPl) Prepared & Analyzed: 12J07/2010 16:28 Source: C011969-02 Total Dissolved Solids 110 10 mg/L 110 6 10 Batch OL06002 - NO PREP Blank (OL06002-BLKI) Prepared: 12/06/2010 07:27 Analyzed: 12/06/2010 12:42 Chlodde 0.018 U 5.0 mg/L Fluoride 0,0043 U 0.20 mg/L Sulfate as SO4 C.12 U 5.0 mg/L --.......... ...................... --............................................. -........................ .. ........................ . LCS (OL0600Z-BSI) Prepared: 12/06/2010 07:27 Anayzed: 12 O612010 13:01 Chloride 53 510 mg/L 50.0 106 90-110 Fluoride 1.0 0.20 mg/L 1.00 101 90-110 Sulfate as SO4 48 5.0 mg/L 50.0 96 90-110 ...... ...... ................................. ....... Matrix Spike (OL06002-MS1) ...'- "-..................... ........... ........... ....................... ....... I — Prepared: 12/06/2010 07:27 Analyzed: 12/06/2010 13:20 Source: C014465-02 Chloride 21 5.0 mg/L 20.0 2.5 94 90-110 Fluoride 0.47 0.20 mg/L 0.400 0.063 101 90-110 Sulfate as SO4 20 5.0 mgIL 20.0 2.3 87 90-110 QM -OS Matrix Spike Dup (OL06002-MSD1) Prepared: 12/06/2010 07:27 Analyzed: 12J06/2010 13:38 Source: C014465-02 Chloride 21 5.0 mg/L 20.0 2.5 94 90-I10 0.5 10 Fluoride 0.46 0.20 mg/L 0.400 0.063 100 90-110 0.8 10 Sulfate as SO4 ...................--'--'--'--'--'--'-...........'--'--....-----............................'-------..................-'----.....,....... 19 5.0 mg/L 20.0 2.3 86 90-110 1 10 QM-05 Batch OL08016 - Same Blank (OL08026-BLKI) Prepared: 12/09/2010 1IAZ Analyzed: 1211012010 13:32 Total Kjeldahl Nitrogen 0.14 U 0.48 mg/L DECEIVED Page 15 of 14 SCR 1 � Vi %G OEN"A nut -,_r..l�h Rani111i1I1111'�� 0 QUALITY CONTROL Classical Chemistry Parameters - Quality Control Batdr 0L08026 - Same www.encolabs.com LCS (OL08026-BSI) Prepared: 12/09/2010 11:12 Analyzed: 12/10/2010 13:34 Total Kjddahl Nltrogen 12 0.48 mg/L 12.0 101 90-110 .......... -"................................"'....-......---'••." ...........-"...........................................-.....---' Matrix Spike (OL08026-MS1) Prepared: 12/09/2010 11:12 Analyzed: 12/10/2010 13:36 Source:C0013988-01 Totak Kjeldahl Nitrogen 5.4 0.48 mg/L 4.80 0.87 94 90-110 ................................... ..................... ......................... '....... ...................................... .......... Matrix Spike Dup (OL08026-MSD1) Prepared: 12/09/2010 11:12 Analyzed: 12/10/2010 13:39 Source: C013988-01 Total Kjeldahl Nitrogen 5.7 0.48 mg/L 4.80 0.07 101 90-110 6 10 """'---""...............'--"""'----------""'---"""'-----.....--"•......................--.......-'-""""""" Batch OL08027 - Same Blank (OL08027-BLKI) Prepared: 12/09/2010 11:12 Analyzed: 12/10/2010 16:48 Phosphorus 0.021 U 0.10 mg/L .... I............................... •-'--- ..'- .. " .............."'.......---...." --- " - ".............. I............................. LCS (OLOS027-BS1) Prepared: 12/09/2010 11:12 Analyzed: 12/10/2010 16:50 Phosphorus 1.7 0.10 mg/L 1.60 103 80.120 ......................................................................................................................... .... --......... Matrix Spike (01.08027-114S1) Prepared: 12/09/2010 11:12 Analyzed: 1ZI10/2010 16:51 Source;C013988-01 Phosphorus 0.98 0.10 mg/L 0.640 0.34 101 80-120 ............................................................................................................................... ..... Matrix Spike Dup (OL08027-MSD1) Prepared: 12/09/2010 11:12 Analyzed: 12/10/2010 16:53 Source:C013988-OL Phosphorus 0.96 0.10 mg/L 0.640 0.34 97 80.120 3 25 —.—..... .-""""'-"-"-""'-""""""....."-""-'--- ........ --- .""""""-""'--.-............... ............. Batch OL09004 - NO PREP Blank (OL09004-BLK1) Prepared: 12/09/2010 07:49 Analyzed: 12/09/2010 10:27 Ammonia as N 0.0096 U 0.10 mg/L LCS (OL09004-BSI) Prepared: 12/09/2010 07:49 Analyzed: 12/09/2010 10:29 Page 16 of 19 a � www.encolabs.com Classical Chemi= Parameters - Quality Control Batch OL09004 - NO PREP LCS (01-09004-130) Continued Prepared: 12/09/2010 07:49 Analyzed: 12/09/2010 10:29 Ammonia as N 1.1 0.10 mg/L 1.00 106 90.110 Matrix Spike (OL09004-MSi) Prepared: 12/09/2010 07:49 Analyzed: 12/09/2010 13:58 Source: C013984-02RE1 Ammonia as N 0.58 0.10 mg/L 0.400 0.18 100 90-110 ..---• ............ ........ ........................................ ............... --- ........................ ..................... Matrix Spike Dup (OL09004-MSD1) Prepared: 12/09/2010 07:49 Analyzed: 12/09/2010 14:00 Source: C013984-02RE1 Ammonia as N 0.62 0.10 mg/L 0.400 0.16 110 90.110 7 10 '- ....-'..........'-'........................ ........................."'....................._.............._............... Page 17 of 19 www.entolabs.com B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. ] The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution . factor, and, in the case of soil samples, moisture content. QB-01 The method blank had a positive result for the analyte; however, the concentration in the method blank is less than 10% of the sample result, which minimizes the impact of the deviation. QM-05 The spike recovery was outside acceptance limits for the HIS and/or MSD due to matrix interference. The LCS and/or LCSD were within acceptance limits showing that the laboratory is in control and the data is acceptable. QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. RECEIVE® FFR 11 201 1 I G DENR Page 18 of 19 Ralefoh Reolonal ON 0 . 0 I Page 19 of 19 IS Nh," www.encolabs.com 41 T 3, FtEcovElD �Odtf�illl#j'Oie,, D6td�&lr,"Dutatibn/Hdfj'it -TotalTio* IABOM� �V,:2fCOMY'T P WIMTKNIR,11 NO3*-NO2'(N) �Tbtal.,(P)l WWTSS'JL`,J.ot6l.Ri1fi; XMMITPI IOVOMPRIVI:�ll 811011995 0.0296 43)v� 183 12.8 2.00 5.2 154 1.00" 1112111996 0.0296 98 V 157 2.5 0.70 1.2 184 1.00" 912411997 0.0237 14 so 18 2.00 0.5 19.5 0.80.. 101811998 1.75 "0.0444 37 36 1.88 0.50 0.4 34 1.501, 91412003 2.00 0.0296 22 75 0.95 0.80 0.4 11.3 1.001, 411212004 3.25 0.0222 6.1 65 1.21 0.82 0.5 25 0.75" 6/412004 .3.00 0.0592 9.3 51.1 2.63 1.56 0.5 188 2.00" 8112/2004 1.00 0.0444 16.7 57.3, 0.90 0.42 0.3 55.7 1.501, #OUtfillll �;76MVFIO* sAOD&V MIC00,61' V2TKN;;N',l. NO3'!,NO2',,(N)IJ6taV(P)J �MSSWI'76taliR61n. ilXl' h1i 8/10/1995 0.2873 95 636 8.4 1.00 4.20 120 1.00" 11/21/1996 0.2873 35 157 3.8 1.00 1.20 184 ✓ 1.001, 9/24/1997 0.2298 62 V 213 11 2.00 1.00 136 s/ 0.80" 101811998 1.75 0.4309 20 -82 3.76 0.96 0.85 76 1.501, 9/4/2003 2.00 0.2873 35 be 48 1.34 1.33 0.40 24 1.0011 3.25 0.2155 32 Le 19 1.40 1.13 0.37 11 0.75" �E4/12120041 6/412004 1 3.00 0,5746 5.4 25.8 0.97 0.53 0.05 18.6 2.00" 8112120041 1.00 0.4309 1 34.8 i,-1 265 1 7.23 1.38 1.09 168 wl 1.50" err �lcr�) r, r RO(J Novozymes North America, Inc. General Location Map Scale 1:62,500 (at center) 1 Miles 2 KM Secondary SA, Road, Hwy Major Connector State Route US Highway Railroad Town, Small Clty U.T. Populalfon Center Lake, Ocean, Large River River, Canal Intermittent River Y �r Permit No. NCS000115 SECTION C: LOCATION MAP Part I Page 2 of 2 Permit No, NCS000115 PART 11 MONITORING, CONTROLS, AND LIMITATIONS FOR PERMITTED DISCHARGES SECTION A: STORMWATER POLLUTION PREVENTION PLAN The permittee shall develop a Stormwater Pollution Prevention Plan, herein after referred to as the Plan. This Plan shall be considered public information in accordance with Para 1II, Standard Conditions, Section E, Paragraph 3 of this individual permit. The Plan shall include, at a minimum, the following items: Site Plan. The site plan shall provide a description of the physical facility and the potential pollutant sources which may be expected to contribute to contamination of stormwater discharges. The site plan shall contain the following: (a) A general location map (USGS quadrangle map or appropriately drafted equivalent map), showing the facility's location in relation to transportation routes and surface waters, the name of the receiving waters) to which the Stormwater outfall(s) discharges, or if the discharge is to a municipal separate storm sewer system, the name of the municipality and the ultimate receiving waters; and accurate latitude and longitude of the point(s) of discharge. _ (bl A narrative description of storage practices, loading and unloading activities, outdoor. process areas, dust or pantculite generating or control processes, and waste disposal practices. (c) A site map drawn to scale with the distance legend indicating location of industrial activities (including storage of materials, disposal areas, process areas and loading and unloading areas), drainage structures, drainage areas for each outfall and activities occurring in the drainage area, building locations, existing BMPs and impervious surfaces, and the percentage of each drainage area that is impervious. For each outfall, a narrative description of the potential pollutants which could be expected to be present in the stormwater discharge. (d) ::A list of significant spills or leaks of pollutants that have occurred at the facility during the 3 previous years and any corrective actions taken to mitigate spill impacts. (e) Certification that the Stormwater outfalls have been evaluated. for, the presence of non-Stormwater discharges:' The certification statement will be signed in accordance with the requirements found in Pan III, Standard Conditions, Section B, Paragraph 3. 2. Stormwater Management Plan. The stormwater management plan shall contain a narrative description of the materials management practices employed which control or minimize the exposure of, significant materials to stormwater, including structural and nonstructural measures. The stormwater management plan, at a minimum, shall incorporate the following: (a) Feasibility Study. A review of the technical and economic feasibility of changing the methods of operations and/or storage practices to eliminate or reduce exposure of materials and processes to stormwater. Wherever practical, the permittee shall prevent exposure of all storage areas, material handling operations, and manufacturing or fueling operations. In areas where elimination of exposure is not practical, the stormwater management plan shall document the feasibility of diverting the stormwater runoff away from areas of potential contamination. (h) Secondary Containm rit Schedule. A schedule to provide secondary containment for bulk storage of liquid materials, storage of Section 313 of Title III of the Superfund Amendments and Reauthorization Act (SARA) water priority chemicals, or storage of haiardous substances to prevent leaks and spills from contaminating stormwater runoff. if the secondary containment devices are connected directly to stormwater conveyance systems, the connection shall be controlled by manually activated valves or other similar devices [which shall be secured with a locking mechanism] and any stormwater that accumulates in the containment area shall be at a Part II Page 1 of 5 Permit No. NCSOOO115 minimum visually observed for color, foam, outfall staining, visible sheens and dry weather flow, pi for to release of the accumulated stormwater. Accumulated stormwater shall be released if found to be uncontaminated by the material stored within the containment area, Records documenting the individual making the observation, the description of the accumulated stormwater and the date and time of the release shall be kept for a period of five years. (c) BMP Summary. A narrative description shall be provided of Best Management Practices (BMPs) to be considered such as, but not limited to, oil and grease separation, debris control, vegetative filter strips, infiltration and stormwater detention or retention, where necessary. The need for structural BMPs shall be based on the assessment of potential of sources to contribute significant quantities of pollutants to stormwater discharges and data collected through monitoring of stormwater discharges. 3. Spill Prevention and Response Plan. The Spill Prevention and Response Plan (SPRP) shall incorporate an assessment of potential pollutant sources based on iii ateTials inventory of the facility. Facility personnel (or team) responsible for implementing the SPRP shall be identified. A responsible person shall be on -site at all times during facility operations that have the potential to contaminate stormwater runoff through spills or exposure of materials associated with the facility operations. The SPRP must be site stormwater specific. efoi e, a SPCC plan may be a component of the SPRP, but may not be suf iciem to completely address the stormwater aspects of the SPRP. The common elements of the SPCC with the SPRP may be incorporated by reference into the SPRP. 4. Preventative Maintenance and Good Housekeeping Program. A preventative maintenance program shall be developed. The program shall document schedules of inspections and maintenance activities of stormwater control systems, plant equipment and systems. Inspection of material handling areas and regular cleaning schedules of these areas shall be incorporated into the program. 5. Employee Training. Training schedules shall be developed and training provided at a minimum on an annual basis on proper spill response and cleanup procedures and preventative maintenance activities for all personnel involved in any of the facility's operations that have the potential to contaminate stormwater runoff. Facility personnel (or team) responsible for implementing the training shall be identified. 6. Responsible Party. The Stormwater Pollution Prevention Plan shall identify a specific position(s) responsible for the overall coordination, development, implementation, and revision to the Plan. Responsibilities for all components of the Plan shall be documented and position assignments provided. 7. Plan Amendment. The permittee shall amend the Plan whenever there is a change in design, construction, operation, or maintenance which has a significant effect on the potential for the discharge of pollutants to surface waters. The Stormwater Pollution Prevention Plan shall be reviewed and updated on an annual basis. The Director may notify the perrrtittee when the Plan does not meet one or more of the minimum requi-ements of the permit. Within 30 days of such notice, the permittee shall submit a time schedule to the Director for modifying the Plan to meet minimum requirements. The permittee shall provide certification in writing (ire accordance with Part I11, Standard Conditions, Section B. Paragraph 3) to the Director that the changes have been made. 8. Facility Inspection Program. Facilities are required to inspect all stormwater systems on at least a semiannual schedule, once in the fall (September -November) and once in the spring (April - June). The inspection and any subsequent maintenance activities performed shall be documented, recording date and time of inspection, individual(s) making the inspection and a narrative description of the facility's stormwater control systems, plant equipment and systems. Records of these inspections shall be incorporated into the Stormwater Pollution Prevention Plan. Stormwater discharge characteristic monitoring as required in Part II of this permit shall be performed in addition to facility inspections. Part II Page 2 of 5 Permit No. NCS000115 9. Implementation. The permittee shall document all monitoring, measurements, inspections and maintenance activities and training provided to employees, including the log of the sampling data and of activities taken to implement BMPs associated with the industrial activities, including vehicle maintenance activities. Such documentation shall be kept on -site for a period of five years and made available to the Director or his authorized representative immediately upon request. SECTION B. ANALYTICAL MONITORING REQUIREMENTS During the period beginning on the effective date of the permit and lasting until expiration, the permittee is authorized to discharge stormwater subject to the provisions of this permit. Analytical monitoring of stormwater discharges shall be performed as specified below in Table 1. All analytical monitoring shall be performed during a representative storm event. 'The required monitoring will result in a minimum of 4 analytical satiiplings being conducted over the term of the permit at each stormwater. discharge outfall (SDO). ' The permittee shall complete the minimum 4 analyticaI samplings�in accordance with the schedule specified below in Table 2. Tal,le 1. Analytical Monitorine Reauirements Discharge Characteristics 41 units Measurement n 1 Sample 2 .8ample ., AX8tion3 BOD5 PM/1 Quarterly- 4's year Grab SDO Chemical Ox .en Demand mg/1 Quarterly- 4's year Grab SDO Total Suspended Solids me 1 Quarterly- 4`s year Grab SDO Total K'eldahl Nitro en m Quarterly- Wh year Grab SDO Nitrate -Nitrite Nitrogen m I Quarterly- 41e year Grab SDO Total Phosphorus m Quarterly- 4's year Grab SDO Total Rainfall4 inches Quarterly- 0 year Event Duration4 minutes Quarterly- Wh year Total Flow4 MG Quarterly- 4's year _ SDO Footnotes: 1 Measurement Frequency: Once per quarter during the 40' year of the'permit term. A year is defined as the 12 month period beginning on the month and day of issuance of the Permit. See Table 2 for schedule of monitoring periods. 2 If the stormwater runoff is controlled by a stormwater detention pond, a grab sample of the discharge from the pond shall be collected within the first 30 minutes of discharge. If the detention pond discharges only in response to a storm event exceeding a ten year design storm, then no analytical monitoring is required and only qualitative monitoring shall be performed. 3 Sample Location: Samples shall be collected at each stormwater discharge outfall (SDO) unless represettative outfall status has been granted. 4 For each sampled representative storm event the total precipitation, storm duration, and total flow must be monitored. Total flow shall be either, (a) measured continuously, (b) calculated based on the amount of area draining to the outfall, the amount of built -upon (impervious) area, and the total amount of rainfall, or (c) estimated by the measurement of flow at 20 minute intervals during the rainfall event. Part II Page 3 of 5 Permit No. NCS000115 Table 2. Monitorin schedule Monitoring period Sample Number Start End Year 4 - I" quarter 1 October 1, 2002 December 31, 2002 Year 4 - 2"0 quarter 2 January 1, 2003 March 31, 2003 Year 4 - 3"' quarter 3 April 1, 2003 June 30. 2003 Year 4 - 4's quarter 4 July 1, 2003 September 30, 2003 SECTION C: QUALITATIVE MONITORING REQUIREMENTS Qualitative monitoring requires a visual inspection of each stormwater outfall regardless of representative outfall status and shall be performed as specified below in Table 3. Qualitative monitoring is for the purpose of evaluating the effectiveness of the Stormwater Pollution Prevention Plan (SPPP) and assessing new sources of stormwater pollution. No analytical tests are mquircd. 'Qualitative monitoring of stormwater outfalls does not.need to be performed during apresent reative storm event. In the event an atypical condition is noted at a stormwater discharge outfall, the Permittee shall document the suspected cause of the condition and any actions taken in response to the discovery. This documentation will be maintained with the Stormwater Pollution Prevention Plan. All ,qualitative. monitoring .will be perfortiied.ftwice: per' -year; once in the spring (April"= June) aid once in the fall (September` November). Table 3. unlitative Mo Itorine Requirements Discharge Characteristics Frequency Monitoring Locationl Color Semi -Annual SDO Odor Semi -Annual SDO Clarity Semi -Annual SDO Floating Solids Semi -Annual SDO Suspended Solids Semi -Annual SDO Foam Semi -Annual SDO Oil Sheen Semi -Annual SDO Other obvious indicators of stormw'ater pollution Semi -Annual SDO Footnotes: 1 Monitoring Location: Qualitative monitoring shall be performed at each stormwater discharge outfall (SDO) regardless of representative outfall status. SECTION D: ON -SITE VEHICLE MAINTENANCE MONITORING REQUIREMENTS Facilities which have any vehicle maintenance activity occurring on -site which uses more than 55 gallons of new motor oil per month when averaged over the calendar year shall perform analytical monitoring as specified below in Table 4. This monitoring shall be performed at all outfalls which discharge stormwater runoff from ,vehicle maintenance areas., - + All analytical monitoring shall be performed during a representative storm event. The required monitoring will result in a minimum of 4 analytical samplings being conducted over the term of the permit at each stormwater Pan II Page 4 of 5 Permit No. NCS000115 discharge outfall (SDO) which discharges stormwater runoff from vehicle maintenance areas. The permittee shall complete the minimum 4analytical samplings in accordance with the schedule specified in Table 2 (Part Il, Section B). Table 4. Analvtical Monitoring Requirements for On -Site Vehicle Maintenance Discharge Characteristics units Measurement Frequencyl Sample TYE±2 Sample L&Mtion3 H standard Quarterly- 0 year Grab SDO Oil and Grease mo Quarterly- 0 year Grab SDO Total suspended Solids m&2 Quarterly- 0 year Grab SDO . New Motor Oil Usage allonslmonth Quarterly- 0 year Estimate - Total Flow4 MG Quarterly- 40s year Grab I SDO Footnotes: Measurement Frequency: Once per quarter during the 4's year of the permit term. A year is defined as the 12 month period beginning on the month and day of issuance of the Permit. See Table 2 for schedule of monitoring periods. 2 If the stormwater runoff is controlled by a stormwater detention pond, a grab sample of the discharge from the pond shall be collected within the first 30 minutes of discharge. If the detention pond discharges only in response to a storm event exceeding a ten year design storm, then no analytical monitoring is required and only qualitative monitoring shall be performed. 3 Sample Location: Samples shall be collected at each stormwater discharge outfall (SDO) that discharges stormwater runoff from area(s) where vehicle maintenance activities occur. 4 Total flow shall be; (a) measured continuously, (b) calculated based on the amount of area draining to the outfall, the amount of built -upon (impervious) area, and the total amount of rainfall, or (c) estimated by the measurement of flow at 20 minute intervals during the rainfall event. Total precipitation ind duration of the rainfall event measured shall result from the sampled representative storm event. Part I1 Page 5 of 5 Permit No. NCS000115 PART III STANDARD CONDITIONS FOR NPDES STORMWATER INDIVIDUAL PERMITS SECTION A: COMPLIANCE AND LIABILITY Compliance Schedule The permittee shall comply with Limitations and Controls specified for stormwater discharges in accordance with the following schedule: Existing Facilities The Stohrwater Pollution Prevention Plan shall be developed and implemented within 12 months of the effective date of the initial permit and updated thereafter on an annual basis. Secondary containment, as specified in Part I1, Section A, Paragraph 2(b) of this permit, shall be accomplished within 12 months of the effective date of the initial permit issuance. Proposed Facilities: The Stormwater Pollution Prevention Plan shall be developed and implemented prior to the beginning of discharges from the operation of the industrial activity and be updated thereafter on an annual basis. Secondary containment, as specified in Part II, Section A, Paragraph 2(b) of this permit shall oc accomplished prior to the beginning of discharges from the operation of in; industrial actiViiy. Duty to ComI213 The permittee must comply with all conditions of this individual permit. Any permit noncompliance constitutes a violation of the Clean Water Act and is grounds for enforcement action; for permit termination, revocation and reissuance, or modification; or denial of a permit upon renewal application. a. The permittee shall comply with standards or prohibitions established under section 307(a) of the Clean Water Act for toxic pollutants within the time provided in the regulations that establish these standards or prohibitions, even if the permit has not yet been modified to incorporate the requirement. b. The Clean Water Act provides that any person who violates a permit condition is subject to a civil penalty not to exceed $25,000 per day for each violation. Any person who negligently violates any permit condition is subject to criminal penalties of $2,500 to $25,000 per day of violation, or imprisonment for not more than 1 year, or both. Any person who knowingly violates permit conditions is subject to criminal penalties of $5,000 to $50,000 per day of violation. or imprisonment for not more than 3 years, or both. Also, any person who violates a perinit condition may be assessed an administrative penalty not to exceed $10.000 per violation with the maximum amount not to exceed $125,000. [Ref: Section 309 of the Federal Act 33 USC 1319 and 40 CFR 122.41(a).] Under state law, a daily civil penalty of not more than ten thousand dollars ($10,000) per violation may be assessed against any person who violates or fails to act in accordance with the terms, conditions, or requirements of a permit. [Ref: North Carolina General Statutes 143-215.6A] d. Any person may be assessed an administrative penalty by the Director for violating section 301, 302, 306, 307, 308, 318, or 405 of the Act, or any permit condition or limitation implementing any of such sections in a permit issued under section 402 of the Act. Administrative penalties for Class I violations are not to exceed $10,000 per violation, with the maximum amount of any Class I penalty assessed not to exceed $25,000. Penalties for Class 11 violations are not to exceed $10,000 per day for each day during which the violation continues, with the maximum amount of any Class Il penalty not to exceed $125,000. Part III Page I of 8 Pages Permit No. NCS000115 Duty to Mitigate The permittee shall take all reasonable steps to minimize or prevent any discharge in violation of this individual permit which has a reasonable likelihood of adversely affecting human health or the environment. Civil and Criminal Liability Except as provided in Part III, Section C of this permit regarding bypassing of stormwater control facilities, nothing in this individual permit shall be construed to relieve the permittee from any responsibilities, liabilities, or penalties for noncompliance pursuant to NCGS 143-215.3,143-215.6A, 143-215,6B, 143- 215.6C,or. Section .309,of the Federal�Act, 33-USC•1319:-4Furthermore, the permittee is respotislble'for consequential damages, such as fish kills, even though the responsibility for effective compliance may be temporarily suspended. S. Oil and Hazardous Substance Liability , Nothing in this individual permit shall be construed to preclude the institution of any legal action or relieve the permittee from any responsibilities, liabilities, or penalties to which the permittee is or may be subject to --reer'+?CGS 143-215.75 et seq. or Section 311 of th`e Fed al�ct;'33 LTSC-I3_^ 6. Property Rights The issuance of this individual permit does not convey any property rights in either real or personal property, or any exclusive privileges, not does it authorize any injury to private property or any invasion of personal rights, nor any infringement of Federal, State or local laws or regulations. 7. Severability The provisions of this individual permit are severable, and if any provision of this individual permit, or the application of any provision of this individual permit to any circumstances, is held invalid, the application of such provision to other circumstances, and the remainder of this individual permit, shall not be affected thereby. Duty_ to Provide Information The permittee shall furnish to the Director, within a reasonable time, any information which the Director may request to determine whether cause exists for modifying, revoking and reissuing, or terminating the permit issued pursuant to this individual permit or to determine compliance with this individual permit. The permittee shall also furnish to the Director upon request, copies of records required to be kept by this individual perniit. 9. Penalties for Tam erin The Clean Water Act provides that any person who falsifies, tampers with, or knowingly renders inaccurate, any monitoring device or method required to be maintained under this individual permit shall, upon conviction, be punished by a fine of not more than $10,000 per violation, or by imprisonment for not more than two years per violation, or by both. If a conviction of a person is for a violation committed after a first conviction of such person under this paragraph, punishment is a fine of not more that $20,000 per day of violation, or by imprisonment of not more than 4 years, or both. 10. Penalties for Falsification of Reports The Clean Water Act provides that any person who knowingly makes any false statement, representation, or certification in any record or other document submitted or required to be maintained under this individual Part III Page 2 of 8 Pages Permit No. NCS000115 permit, including monitoring reports or reports of compliance or noncompliance shall, upon conviction, be punished by a fine of not more than $10,000 per violation, or by imprisonment for not more than two years per violation, or by both. SECTION B: GENERAL CONDITIONS Individual Permit Expiration The permittee is not authorized to discharge after the expiration date. In order to receive automatic authorization to discharge beyond the expiration date, the permittee shall submit forms and fees as are required by the agency authorized to issue permits no later than 180 days prior to the expiration date. Any permittee that has not requested renewal at least 180 days prior to expiration, or any permittee that does not have a permit after the expiration and has not requested renewal at least 180 days prior to expiration, will be subjected to enforcement procedures as provided in NCGS § 143-2153.6 and 33 USC 1251 et. seq. 2. Transfers This permit is not transferable to any person except after notice to and approval by the Director. The Director may require modification or revocation and reissuance of the permit to change the name and incorporate such other requirements as may be necessary under the Clean Water Act. Permittee is required to notify the Division in writing in the event the permitted facility is sold or closed. Signatoryequirements All applications, reports, or information submitted to the Director shall be signed and certified. a. All applications to be covered under this individual permit shall be signed as follows: (I) For a corporation: by a responsible corporate officer. For the purpose of this Section, a responsible corporate officer means: (a) a president, secretary, treasurer or vice president of the corporation in charge of a principal business function, or any other person who performs similar policy or decision making functions for the corporation, or (b) the manager of one or more manufacturing production or operating facilities employing more than 250 persons or having gross annual sales or expenditures exceeding 25 million (in second quarter 1980 dollars), if authority to sign documents has been assigned or delegated to the manager in accordance with corporate procedures. (2) For a partnership or sole proprietorship; by a general partner or the proprietor, respectively; or (3) ' For a municipality, State, Federal, or other public agency: by either a principal executive officer or ranking elected official. h. All reports required by the individual permit and other information requested by the Director shall be signed by a person described above or by a duly authorized representative of that person. A person is a duly authorized representative only if: (1) The authorization is made in writing by a person described above;' (2) The authorization specified either an individual or a position having responsibility for the overall operation of the regulated facility or activity, such as the position of plant manager, operator of a well or well field, superintendent, a.position of equivalent responsibility, or an individual or position having overall responsibility for environmental Part III Page 3 of 8 Pages Ll Permit No. NCS000115 matters for the company. (A duly authorized representative may thus be either a named individual or any individual occupying a named position.);,and (3) The written authorization is submitted to the Director. Any person signing a document under paragraphs a. or b. of this section shall make the following certification: "I certify, under penalty of law, that this document and all attachmeints were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 4. Individua]_Permit Modification, Revocation and Reissuance, or Termination T ��- issuance of this individual permit does not prohibit the Director from reopening and modifying the individual permit, revoking and reissuing the individual permit, or terminating the individual permit as allowed by the laws, rules, and regulations contained in Title 40, Code of Federal Regulations, Parts 122 and 123; Title 15A of the North Carolina Administrative Code, Subchapter 2H .0100; and North Carolina General Statute 143-215.1 et. al. After public notice and opportunity for a hearing, the individual permit may be terminated for cause. The filing of a request for a individual permit modification, revocation and reissuance, or termination does not stay any individual permit condition. The permit shall expire when the individual permit is terminated. 5. Fern -tit Actions The permit may be modified, revoked and reissued, or terminated for cause. The notification of planned changes or anticipated noncompliance does not stay any individual permit condition. SECTION C: OPERATION AND MAINTENANCE OF POLLUTION CONTROLS i . Proper QReTatio and Maintenance The permittee shall at all times properly operate and maintain all facilities and systems of treatment and control (and related appurtenances) which are installed or used by the permittee to achieve compliance with the conditions of this individual permit. Proper operation and maintenance also includes adequate laboratory controls and appropriate quality assurance procedures. This provision requires the operation of back-up or auxiliary facilities or similar systems which are installed by a permittee only when the operation is necessary to achieve compliance with the conditions of this individual permit. Need to Halt or Reduce Not a Defense It shall not be a defense for a permittee in an enforcement action that it would have been necessary to halt or reduce the permitted activity in order to maintain compliance with the condition of this individual permit. 3. 13yipassin&of Stormwater Control Facilities Bypass is prohibited and the Director may take enforcement action against a permittee for bypass unless: Part III Page 4 of 8 Pages Permit No. NCS000115 a. Bypass was unavoidable to prevent loss of life, personal injury or severe property damage; and b. There were no feasible alternatives to the bypass, such as the use of auxiliary control facilities, retention of stormwater or maintenance during normal periods of equipment downtime or dry weather. This condition is not satisfied if adequate backup controls should have been installed in the exercise of reasonable engineering judgment to prevent a bypass which occurred during normal periods of equipment downtime or preventive maintenance; and C. The permittee submitted notices as required. under, Part III, Section E of this permit. If the Director determines that it will meet the three conditions listed above, the Director may approve an anticipated bypass after considering its adverse effects. SECTION D: MONITORING AND RECORDS 1. Representative Sampling Samples collected and measurements taken, as required herein, shall be characteristic of the volume and nature of the permitted discharge. Analytical sampling shall be performed during a representative storm event. Samples shall be taken on a day and time that is characteristic of the discharge,, All samples shall be taken before the discharge joins or is diluted by any other waste stream, body of water, or substance. Monitoring points as specified in this. permit shall not be changed without notification to and approval of the Director. 2. R_ecordinp, Results For each measurement, sample, inspection or maintenance activity performed or collected pursuant to the requirements of this individual permit, the permittee shall record the following information: a. The date, exact place, and time of sampling, measurements, inspection or maintenance activity, b. The individual(s) who performed the sampling, measurements, inspection or maintenance activity; C. The date(s) analyses were performed; d. The individual(s) who performed the analyses; e. The analytical techniques or methods used; and f. The results of such analyses. low Measurements Where required, appropriate flow measurement devices and methods consistent with accepted scientific practices shall be selected and used to ensure the accuracy and reliability of measurements of the volume of monitored discharges. Test Procedures Test procedures for the analysis of pollutants shall conform to the EMC regulations published pursuant to NCGS 143-215.63 et. seq, the Water and Air Quality Reporting Acts, and to regulations published pursuant to Section 304(g), 33 USC 1314, of the Federal Water Pollution Control Act, as Amended, and Regulation 40 CFR 136. Part III Page 5 of 8 Pages *, Permit No. NCS000115 To meet the intent of the monitoring required by this individual permit, all test procedures must produce nir.?mutn detection and reporting levels and all data generated must be reported down to the minimum detection or lower reporting level of the procedure. 5. Representative Outfall If a facility has multiple discharge locations with substantially identical stormwater discharges that are required to be sampled, the permittee may petition the Director for representative outfall status. If it is established that the stormwater discharges are substantially identical and the permittee is granted representative outfall status, then sampling requirements maybeperforated at a reduced number of outfalls. 6. Records Retention Visual monitoring shall be documented and records maintained at the facility along with the Stormwater Pollution Prevention Plan. Copies of analytical monitoring results shall also be maintained on -site. The permittee shall retain records of all monitoring information, including all calibration and maintenance records and all original strip chart recordings for continuous monitoring instrumentation, and copies of all reports required by this individual permit for a period of at least 5 years from the date of the sample, wcasurement, report or application. This period may be extended by request of the Director at anytime: 7. inspection and Entry The permittee shall allow the Director, or an authorized representative (including an authorized contractor acting as a representative of the Director), or in the case of a facility which discharges through a municipal separate storm sewer system, an authorized representative of a municipal operator or the separate storm sewer system receiving the discharge, upon the presentation of credentials and other documents as may be required by law, to; Enter upon the pern-duee's premises where a regulated facility or activity is located or conducted, or where records must be kept under the conditions of this individual permit; Have access to and copy, at reasonable times, any records that must be kept under the conditions of this individual permit; C. Inspect at reasonable times any facilities, equipment (including monitoring and control equipment), practices, or operations regulated or required under this individual permit; and d. Sample or monitor at reasonable times, for the purposes of assuring individual permit compliance or as otherwise authorized by the Clean Water Act, any substances or parameters at any location. SECTION E: REPORTING REQUIREMENTS Discharge Monitoring Resorts Samples analyzed in accordance with the terms of this permit shall be submitted to the Division on Discharge Monitoring Report forms provided by the Director. Submittals shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory. Part III Page 6 of 8 Pages Permit No. NCS0001 15 Submitting Reports Duplicate signed copies of all reports required herein, shall be submitted to the following address: Division of Water Quality Water Quality Section ATTENTION: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 3. Availability of Reports Except for data determined to be confidential under NCGS 143-215.3(a)(2) or Section 308 of the Federal Act, 33 USC 1318, all reports prepared in accordance with the terms shall be available for public inspection at the offices of the Division of Water Quality. As required by the Act, analytical data shall not be considered confidential. Knowingly making any false statement on any such report may result in the imposition of criminal penalties as provided for in NCGS 143-215.613 or in Section 309 of the Federal Act. 4. Non-Stormwater Discharges - If the storm event monitored in accordance with this individual permit coincides with a non-stormwater discharge, the permittee shall separately monitor all parameters as required under the non-stormwater discharge permit and provide this information with the stormwater discharge monitoring report. 5. finned Changes The permittee shall give notice to the Director as soon as possible of any planned changes at the permitted facility which could significantly alter the nature or quantity of pollutants discharged. This notification requirement includes pollutants which are not specifically listed in the individual permit or subject to notification requirements under 40 CFR Part 122.42 (a). 6. Antici ated Noncom li nc The permittee shall give notice to the Director as soon as possible of any planned changes at the permitted facility which may result in noncompliance with the individual permit requirements. a55 a. Anticipated bypass. If the permittee knows in advance of the need for a bypass, it shall submit prior notice, if possible at least ten days before the date of the bypass, including an evaluation of the anticipated quality and affect of the bypass. b. Unanticipated bypass, The permittee shall submit notice within 24 hours of becoming aware of an unanticipated bypass. Twenty-four Hour Reportins' The permittee shall report to the ceatral office or the appropriate regional office any noncompliance which may endanger health of the environment. Any infonwtion shall be provided orally m ithin 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. The written submission shall contain a description of the noncompliance, and its causes, the period of noncompliance, including exact dates and times, and if the noncompliance has not been corrected, the Part Ill Page 7 of 8 Pages C . I Permit No. NCSOOOJ 15 anticipated time compliance is expected to continue; and steps taken or planned to reduce, eliminate, and prevent reoccurrence of the noncompliance. The Director may waive the written report on a case -by -case basis if the oral report has been received within 24 hours. 9. Other Noncompliance The permittee shall report all instances of noncompliance not reported under 24 hour reporting at the time monitoring reports are submitted. 10, Other Information Where the permittee becomes aware that it failed to submit any relevant facts in an application for an individual permit or in any report to the Director, it shall promptly submit such facts or information. Part III Page 8 of 8 Pages Permit No. NCS000115 PART IV LIMITATIONS REOPENER This individual permit shall be modified or alternatively, revoked and reissued, to comply with any applicable effluent guideline or water quality standard issued or approved under Sections 302(b) (2) (c), and (d), 304(b) (2) and 307(a) of the Clean Water Act, if the effluent guideline or water quality standard so issued or approved: a. Contains different conditions or is otherwise more stringent than any effluent limitation in the individual permit; or b. Controls any pollutant not limited in the individual permit. The individual permit as modified or reissued under this paragraph shall also contain any other requirements in the Act then applicable. PART V ADMINISTERING AND COMPLIANCE MONITORING FEE REQUIREMENTS The pernuttee must pay the administering and compliance monitoring fee within 30 (thirty) days after being billed by the Division. Failure to pay the fee in timely manner in accordance with 15A NCAC 2H .0105(b)(4) may cause this Division to initiate action to revoke the Individual Permit. PART VI DEFINITIONS Act See Clean Water Act. Arithmetic Mean The arithmetic mean of any set of values is the summation of the individual values divided by the number of individual values. Allowable Non-Stormwater Discharges This permit regulates stormwateridischarges. Nan-stormwater discharges which shall be allowed in the stormwater conveyance system are: (a) All other discharges that are authorized by a non-stormwater NPDES permit, (b) Uncontaminated groundwater, foundation drains, air -conditioner condensate without added chemicals, springs, discharges of uncontaminated potable water, waterline and fire hydrant flushings, water from footing drains, flows from riparian habitats and wetlands. (c) Discharges resulting from fire -fighting or fire -fighting training. BestManagementPractices (BMPs) Measures or practices used to reduce the amount of pollution entering surface waters. BMPs may take the form of a process, activity, or physical structure. Parts IV, V and VI Page 1 of 5 Permit No. NCS000115 5. Bypass A bypass is the known diversion of stormwater from any portion of a stormwater control facility including the collection system, which is not a designed or established operating mode for the facility. 6. Bulk Storagg of Li uid Produw Liquid raw materials, manufactured products, waste materials or by-products with a single above ground storage container having a capacity of greater than 660 gallons or with multiple above ground storage containers located in close proximity to each other having a total combined storage capacity of greater than 1,320 gallons. 7. Clean Water Act The Federal Water Pollution Control Act, -also known as the Clean Water Act (CWA), as amended, 33 USC 1251, et. seq. E. ' -—DrjsionorDWO The Division of Water Quality, Department of Environment and Natural Resources. 9. Director The Director of the Division of Water Quality; the permit issuing authority. 10. EMC The North Carolina Environmental Management Commission. 11, Grab Sample An individual sample collected instantaneously. Grab samples that will be directly analyzed or qualitatively monitored must be taken within the first 30 minutes of discharge. 12. Hazardous Substance Any substance designated under 40 CFR Part 116 pursuant to Section 311 of the Clean Watei Act. 13. Landfill A disposal facility or part of a disposal facility where waste is placed in or on land and which is not a land treatment facility, a surface impoundment, an injection well, a hazardous waste long-term storage facility or a surface storage facility. 14, Municipal -Separate Storm Sewer System A stormwater collection system within an incorporated area of local self-government such as a city or town. 15. Overburden Any material of any nature, consolidated or unconsolidated, that overlies a mineral deposit, excluding topsoil or similar naturally -occurring surface materials that are not disturbed by mining operations. Part VI Page 2 of 5 Pages 71/ Tar Pamlico River Basin Subbasin 03-03-01 Assessment Impaired Year WNaterbody and Description Unit (AU) Class Subbasin Use liPotential Source(s) Category and Reason for Listing e(s) Miles or Acres Tar Pamlico River Basin Subbasin 03-03-01 Fishing Creek 28-11a C NSW 03-03-01 6 2.4 FW Miles From source to SR 1649 AL 1998 6 Impaired biological integrity Fishing Creek 2841b C NSW 03-03-01 6 0.5 FW Miles From SR 1649 to #1 outfall AL 1998 6 Impaired biological integrity Fishing Creek 2841c C NSW 03-03-01 6 0.9 FW Miles From #1 outfall to SR 1608 AL 1998 6 Impaired biological integrity Major Municipal Point Source Urban Runoff/Stone Sewers Major Municipal Point Source Fishing Creek 28-11d C NSW 03-03-01 6 1.0 FW Miles From SR 1608 to Coon Creek AL 1998 6 Impaired biological integrity Major Municipal Point Source Urban Runoff/Storm Sewers Tar Pamlico River Basin Subbasin 03-03-02 Sandy Creek 28-78-1-(8)b S NSW 03-03-02 6 11.3 FW Miles From NC 401to N.C. Hwy, 561 O 2000 6 Impaired biological integrity Stony Creek (Boddies 28-Rb C NSW 03-03-02 6 5.9 FW Miles Millpond) From Lassilers Creek to Tar River AL 1998 6 impaired biological integrity TAR RIVER 28{66.5) WSaV 03-03-02 5 0.7 FW Miles NSW CA From Maple Creek to a point 100 feet downstream from Old Rocky Mount Water FC 2006 5 Fish Advisory- Mercury intake, downstream from U.S. Hwy. 64 North Carolina 303(d) List 2006 Tuesday, June 19, 2007 Tar Pamlico Basin 03-03-02 Page 81 of 125 Tar Pamlico River Basin Subbasin 03-03-03 Assessment Class Subbasin Impaired Year Miles or Acres Waterbody and Description Unit (AU} USe Listed Category and Reason for Lisfing Potential Source(s) Tar Pamlico River Basin Subbasin 03-03-03 Ballahack Canal 28-87-1.2 C NSW 03-03-03 6 8.4 FW Miles From source to Conetoe Creek AL 2006 6 Impaired biological integrity Agriculture Agriculture Synums Mill Creek 28-83.4 C NSW 03-03-03 6 9.7 FW Miles From source to Town Creek - AL 2006 6 Impaired biological integrity Source Unknown Minor Municipal Point Source Cokey Swamp 28-833a C NSW 03-03-03 6 8.6 FW Miles From source to Dickson Branch AL 2006 6 Impaired biological integrity Urban Runoff/Storm Sewers Conetoe Creek 28-87{0.5)a C NSW 03-03-03 6 3.9 FW Miles From source to SR 1516 AL 1998 6 Impaired biological integrity Channelization Agriculture Concentrated Animal Feeding Operations (permitted, point source) Conetoe Creek 28-0740.5)b C NSW 03-03-03 6 6.9 FW Miles From SR 1516 to 1350 meters North of NC 42 AL 1998 6 Impaired biological integrity Channelization Agriculture Concentrated Animal Feeding Operations (permitted, point source) Conetoe Creek 28-87{0.5)d C NSW 03-03-03 6 6.7 FW Miles From Crisp Creek to Pitt County SR 1404 AL 1998 6 Impaired biological integrity Channelization Agriculture Concentrated Animal Feeding Operations (permitted, point source) North Carolina 303(co List 2006 Tuesday, June 19, 2007 Tar Pamlico Basin 03-03-03 Page 82 of.125 NCNHP Virtual Workroom V � E7 i U �'t Page I of I Legend r r-t Element Occurrences hJ (show after queried) fY EO Source Points F ,' EO Source Lines III L.I EO Source Polygons F Submitted EOs r Significant Natural Heritage Areas Managed Areas r•1 Primary Roads F I" Secondary Roads 1 Municipalities F Rivers and Lakes (Lines) Rivers and Lakes (Polygons) r ©© �7 Topo Images r Aerial Images (2006) r Aeriai Images (199a) F Topo Boundaries F t� 1 County Boundaries 10 Redraw Map NC Natural Heritage Program Virtual Workroom 0 1 2 3 4 ei GIS Data SourCes: NCNHP, CGIA, NCDOT, USGS. NCNHP data updated on: 2067-Nov-20 Powered By:, a WebGD r DM Solutions ■ MaoServer ■ EffE ■ PostareSDL ■ PostGIS a Home ■ "IV Locator Map Map Size; 600 x 450 Functions ( A Zoom In r, Q Zoom out r + Pan 0-- Query Point C Query Area [) Submit EO C; Show Coordinates Query Database Clear Query Quick View —Select Region — Problems or n��P[ti>�ns3 http:Hl 0.251.149.2231nhislpartnerlgmap75_main.phtml?grp_eo_py=Y&grp_eosrc_pt=Y,.. 11 /20/2007 Tar River, 1.1 Subbasin Overview Subbasin 03-03-01 at a Glance Land and Water Area Total area: 642 mil Land area: 635 mil Water area: 7 miz Population 2000 Est. Pop.: 65,205 people Pop. Density: 101 persons/miz Land Cover [vercent Forest/Wetland: 76 Water: 1 Urban: 2 Cultivated Crop: 12 Pasture/ Managed Herbaceous: 9 Counties Franklin, Granville, Person and Vance r - Section B - Chapter 1 Tar -Pamlico River Subbasin 03-03-01 :reek. Cedar Creek, Coon Creek and Tabbs Creek Population growth in this subbasin is occurring between Franklinton and Louisburg on the border with the Neuse River basin and along the I-85 corridor near Oxford and Henderson. Population growth from 1990 to 2000 in the four counties with land area in this subbasin ranges from 10 percent in Vance County to nearly 30 percent in Franklin County. The population in these four counties is expected to increase by 60,000 people (34%) by 2020. There are 10 individual NPDES wastewater discharge . permits in this subbasin with a total permitted flow of 6.8 MGD (Figure B-1). The largest are Franklin County WWTP (3 MGD), Louisburg WWTP (1.37 MGD) and City of Oxford WWTP (2.7 MGD). There arc also ten general NPDES wastewater discharge permits, five individual NPDES stormwater permits, and 30 general NPDES stormwater permits issued in this subbasin. Refer to Appendix I for more information on NPDES permit holders. The Town of Henderson and Nash County will be required to develop stormwater programs under Phase 11 (page 75). Henderson and Oxford, and Franklin and Nash counties will also have to submit model stormwater ordinances as required by the Tar -Pamlico NSW strategy stormwater rules (page 61). Issues related to compliance with NPDES permit conditions are discussed below in Part 1.3 or Part 1.4 for Impaired waters and in Part 1.5 for other waters. There is also one registered animal operation in this subbasin. There were seven benthic macroinveitebrate community samples and 12 fish community samples (Figure 13-1 and Table B-1) collected during this assessment period. Four sites improved, 1 I sites remained the same, one site had a lower bioclassification, and three sites were sampled for the first time during this assessment period. Data were also collected from four ambient monitoring stations as well. Refer to 2003 Tar=Pamlico River Basinwide Assessment Report at http://www.esb.enr.state.nc.us/bar.html and Section A, Chapter 3 for more information on monitoring. Section B: Chapter 1— Tar -Pamlico River Subbasin 03-03-01 96 PERSON oSubbasm cow Boundary Wnbwd MmftmV Station © Fish c«m w* Stabon NPDES DWchwgm ♦ Minor Use Support Rating A/ SUPPD" Ntmpawd NO Rayed No Data Primary Raads o J LumvpItay Figure B-1 Tar -Pamlico III r Subbasin 03-03 1 GRANWLLE VANCE SF-t Henderson SF-2 Oxfo SF-3 ti ta� F SS-1 � F-1' B� `S 0 1 �nr2 Kittrell I A-t ; B-1 SF� F3 -f SF-7' r Franfdinton 1 QouisbuA-S F-4-- .� 1a o ra goes WARREN FRANKUN NASH A-4 ! B-4 r AMA NCDEM Planning Branch Basinwide Planning Program Unit April 22, 2004 Table B-1 DWQ Assessment and Use Support Ratings Summary for Monitored Waters in Subbasin 03-03-01 Waterbody Assessment Unit Number DWQ Classification Length/ Area Category Data Type with Map Number and Data Results Use Sup rt Rahn 2004 1998 Biological Ambient Other TAR RIVER 28-(1) WS-rV NSW 20.1 mi AL SF-1 E--99 S ST Shelton Creek 28-4 WS-IV NSW 13.9 mi AL SF-2 E-99 S .FS North Fork Tar River 28-5 WS-IV NSW 8.8 mi AL SF-3 G-99 S ST TAR RIVER 28-(5.3) WS-IV NSW CA 0.5 mi AL SF-5 E--97 A-1 nce. S FS TAR RIVER 28-(5.7) WS-V NSW 20.5 nu AL SF-5 E--97 B-1 G--02 A-1 nce S FS Fishing Creek 28-1le CNSW 6.1 mi AL F-1 G--02 S PS Fishing Creek 28-11c C NSW 0.9 mi AL SB-I P-99 I NS Fishing Creek 28-1 ld C NSW 1.0 mi AL SB-1 P--99 I PS Hachers Run (Devin Lake) 28-11-3-(1) WS-II NSW CA 98.9 ac AL L-1 nce S FS Coon Creek 28-11-5 C NSW 10.1 mi. AL F-2 E--02 S NR Middle Creek 28-15 C NSW 8.4 mi. AL F-3 G-02 S FS TAR RIVER 28-(15.5) WS-IV NSW 14.8 nu. AL SF-6 G--97 S FS Tabbs Creek 28-17-(0.5)b C NSW 12.0 mi. AL SF-4 G-99 SB-2 GF-99 S ST Lynch Creek 28-21-(0.7) WS-IV NSW 9.2 mi. AL SF-7 G-99 S FS TAR RIVER 28-(24.3) WS-IV NSW CA 0.6 mi. AL B-3 GF-02 A-3 nce S ST TAR RIVER 28-(24.7)a WS-V NSW 20.3 mi. AL B-3 GF--02 B-4 G- 02 A4 nce S ST TAR RIVER 28-(24.7)a . WS-V NSW 20.3 mi. REC A-3 nce A4 nce S N/A Cedar Creek 28-29-(2)b C NSW 12.1 mi. AL F-4 E-02 B-5 GF--02 S ST Crooked Creek 28-30b IC NSW 1 5.4 mi. I AL I F-5 GF-02 I I S ST TAR RIVER 28-(5.7) WS-V NSW 1 20.5 mi. I REC I I A-1 nce S N/A Fishing Creek 28-1 le IC NSW 1 6.1 mi. I REC A-2 nce S NIA Assessment Unit Number - Portion of DWQ Classified Index where monitoring is applied to assign a use support rating. Use'Categories: Monitoring data type: AL - Aquatic Life F - Fish Community Survey REC - Recreation B - Benthic Community Survey FC - Fish SF - Special Fish Community Study Consumption SB - Special Benthic Community Study A - Ambient Monitoring Site L - Lakes Assessment FT - Fish Tissue Site sioctassitcations: E - Excellent N - Natural G - Good MS - Moderate Stress GF - Good -Fair SS - Severe Stress F - Fair P - Poor nce - no criteria exceeded ce - criteria exceeded S - Supporting, I - impaired, NR - Not Rated Use Support Ratings 1998: FS - fully supporting, ST - supporting but threatened, PS - partially supporting, NS - not supporting, NR - not rated, N/A - not applicable Section B: Chapter 1 - Tar -Pamlico River Subbasin 03-03-01 98 r' Use support ratings for all waters. in subbasin 03-03-01 are summarized in Part 1.2 below. Recommendations, current status and future recommendations for waters that were Impaired in 1999 are discussed in Part 1.3 below. Current status and future recommendations for newly Impaired waters are discussed in Part 1.4 below. Waters with noted water quality impacts are discussed in Part 1.5 below. Water quality issues related to the entire subbasin are discussed in Part 1.6. Refer to Appendix III for a complete list of monitored waters and for more information on Supporting monitored waters. 1.2 Use Support Assessment Summary Use support ratings were assigned for waters in subbasin 03-03-01 in the aquatic life, recreation, fish consumption and water supply categories. All waters are Impaired on an evaluated basis in the fish consumption category because of statewide fish consumption advice for mercury that is applied in this category to basins east and south of 1-85 (page 90). In the water supply category, all waters are Supporting on an evaluated basis based on reports from DEH regional water treatment plant consultants. There were 469.3 stream miles (35 percent) and 98.9 freshwater acres (100 percent) monitored during this assessment period in the aquatic life category. Approximately 1.9 stream miles (L'. percent) are Impaired. Refer to Table B-2 for a summary of use support ratings for waters in subbasin 03-03-01. Section B: Chapter I - Tar -Pamlico River Subbasin 03-03-01 99 1. 14 Table B-2 Summary of Use Support Ratings by Category in Subbasin 03-03-01 Use Support Rating Aquatic Life Fish Consumption Recreation Water Supply f Monitored Waters Supporting 162.8 mi 98.9 ac 0 469 mi 0 Impaired 1.9 mi 0 0 0 Not' Rated 0 0 0 0 Total 164.8 mi 98.9 ac 0 46.9 mi. 0 Unmonitored Waters Supporting 15.2 mi 0 0 182.7 mi 98.9 ac Impaired 0 469.3 mi 98.9 ac _ 0 0 Not Rated 18.5 mi 0 0 0 No Data 270.7 mi 0 422.4 mi 98.9 ac 0 Total 304.5 mi 469.3 mi 98.9 ac 422.4 mi 98.9 ac 182.7 mi 98.9 ac Totals All Waters* 469.3 mi 98.9 ac 469.3 mi 98.9 ac 469.3 mi 98.9 ac 182.7 mi 98.9 ac ' Total Monitored + Total Unmonitored = Total All Waters. 1.3 Status and Recommendations of Previously Impaired Waters Waters in the following section are identified by assessment unit number (AU#). This number is used to track defined segments in the water quality assessment database, 303(d) Impaired waters list, and the various tables in this basin plan. The assessment unit number is a subset of the DWQ index number. (classification identification number). A letter attached to the end of the AU# indicates that the assessment is smaller than the DWQ index segment. No letter indicates that the assessment unit and the DWQ index segment are the same. 1.3.1 Fishing Creek [AU# 28-11a through 28-11e] 1999 Recommendations It was recommended that no new or expanding wastewater dischargers be connected to the Oxford wastewater treatment plant. Current Status Fishing Creek (1.9 miles) is currently Impaired from the Oxford WWTP outfall #1 to Coon Creek [AU# 2 8-1lc] because of a Poor bioclassification at site SB-1 in 1999. SB-I was also Section B: Chapter 1, - Tar -Pamlico River Subbasin 03-03-01 100 Poor in 1990. The entire length (I I miles) of Fishing Creek was Impaired in 1999. In 1997, the Oxford WWTP was upgraded and water quality improvements were observed downstream. Site F-1 improved from Good -Fair in 1997 to Good in 1999 and 2002. Site B-1 also improved from Fair in 1999 to Good -Fair in 2002. Above the WWTP, Fishing Creek and Foundry Branch are impacted by urban runoff from the City of Oxford. Oxford WWTP was placed under a moratorium after the Poor bioclassification in 1999. The requirements of a prior Special Order by Consent (SOC) have been met and the associated moratorium has been lifted. Overflows from the collection system have been reduced due to pipe replacement/rehabilitation work. However, Oxford WWTP has continued to have problems with overflows, specifically at the headworks of the WWTP. For approximately 11 months of the assessment period, Oxford WWTP exceeded permit limits for selenium. An industrial user was determined to be the source of selenium. Oxford also modified a pretreatment permit of a significant industrial user to address selenium violations. The industrial user is now using a chemical that does not contain selenium. 2004 Recommendations DWQ will continue to monitor water quality in the Fishing Creek watershed. DWQ Raleigh Regional Office staff will continue to work with Oxford WWTP to remedy plant problems that may be adversely impacting water quality in Fishing Creek including influent overflows and infiltration and inflow in the Foundry Branch watershed. Oxford WWTP is expanding from 2.17 MGD to 3.5 MGD and will ,receive permit limits of 5 mg/1 BOD5 and 1 mg/1 NH3-N down from 15 mg/l BOD5 and 4 mg/l NH3-N, representing a decrease in loading of these two parameters. The new limits as well as those improvements being implemented by Oxford (see below) should further reduce impacts to Fishing Creek. Oxford is also required to address nutrients in stormwater as part of the Tar -Pamlico NSW strategy (page 73) and should take the opportunity to address the more acute impacts to Fishing Creek when developing a stormwater program. Current Water Quality Initiatives Oxford WWTP received a state -revolving loan of $813,514 in January 2001 to rehabilitate the outfall to Fishing Creek and is awaiting a loan of $10,000,000 to upgrade and expand the plant. The proposed upgrade will include biological nutrient removal as well as upgrades to the Coon Creek lift station. 1.4 Status and Recommendations of Newly Impaired Waters There are no newly Impaired waters in subbasin 03-03-01. Refer to Part 1.5 below for information on waters with noted water quality impacts. 1.5 Status and Recommendations for Waters with Noted Impacts The surface waters discussed in this section are not Impaired. However, notable water quality problems and concerns have been documented for some waters based on this assessment. While these waters are not Impaired, attention and resources should be focused on these waters to prevent additional degradation or facilitate water quality improvement. Section B: Chapter I - Tar -Pamlico River Subbasin 03-03-01 101 Waters in the following section are identified by assessment unit number (AU#). This number is used to track defined segments in the water quality assessment database, 303(d) Impaired waters list, and the various tables in this basin plan. The assessment unit number is a subset of the DWQ index number (classification identification number). A letter attached to the end of the AU# indicates that the assessment is smaller than the DWQ index segment. No letter indicates that the assessment unit and the DWQ index segment are the same. 1.5.1 Cedar Creek [AU# 28-29-(2)b] Current Status and 2064 Recommendations The benthic bioclassification of lower Cedar Creek (12.15 miles) has been Good -Fair at site 13-5 since 1990. The fish community bioclassification at site F-4 improved to Excellent in 2002. The upper segment of Cedar Creek [AU# 28-29-(2)a] receives a discharge from the Franklin WWTP which had three WET test failures during the assessment period. This segment (6.18 miles) is currently Not Rated. A pretreatment audit was performed in 2002 by DWQ staff to determine if the one significant industrial user was the source of toxicity. There has not been a WET test fail since 2002. DWQ will continue to work with the Franklin WWTP. Cedar Creek also crosses the rapidly growing area of NC 401 between Raleigh and Louisburg. Water quality should be considered during planning and development activities in this watershed. 1.5.2 Hatchers Run (Devin Lake) [AU# 28-11-3-(1)] Current Status and 2004 Recommendations Hatchers Run (Devin Lake) is a 98.9-acre impoundment west of Oxford that was a water supply until 1993. During lake monitoring in 2002, the reservoir was stratified with hypoxic conditions three meters from the surface. Chemical monitoring and observed green water color suggested that algal blooms were occurring although the chlorophyll a criterion was not exceeded. Nutrient levels were greater than observed in 1997, and copper was higher than the action level. Water quality in Hatchers Run should be considered during land development activities, and BMPs should be implemented on all land use activities to reduce the potential for algal blooms. 1.5.3 Tar River [AU# 28-(24.7)a] Current Status and 2004 Recommendations This 20.3-mile segment of the Tar River is currently Supporting because of Good -Fair and Good bioclassification at sites B-3 and B-4, respectively. The change in bioclassification at site B-3 (from Good in 1997) is likely related to the drought of 1998 to 2002 and does not indicate any real changes in water quality. Water quality standards were not exceeded at sites A-3 and A-4. DWQ will continue to monitor this segment of the Tar River. This area is experiencing growth from the Neuse River basin to the south. Louisburg received a $252,000 CWMTF grant to acquire 50 acres to add to the existing greenway system at Joyner Town Park. Louisburg has also been offered a $2,295,500 grant through DWQ Construction Grants and Loans for rehabilitation of the existing WWTP and a wastewater reuse project. Section B: Chapter I - Tar -Pamlico River Sabbasin 03-03-01 102 1.5.4 Billys Creek [AU# 28-201 Current Status and 2004 Recommendations The current use support rating of Billys Creek is No Data. Billys Creek has never been monitored by DWQ; however, EEP (page 168) has a planned project in this local watershed. This is one of 27 local watersheds in the Tar -Pamlico River basin that has been identified by EEP as an area with the greatest need and opportunity for stream and wetland restoration efforts. This watershed will be given higher priority than nontargeted watersheds for implementation of EEP restoration projects. 1.5.5 Bear Swamp Creek JAU# 28-231 Current Status and 2004 Recommendations The current use support rating of Bear Swamp Creek is No Data. Bear Swamp Creek has never been monitored by DWQ; however, EEP (page 168) has a planned project in this local watershed. This is one of 27 local watersheds in the Tar -Pamlico River basin that has been identified by EEP as an area with the greatest need and opportunity for stream and wetland restoration efforts. This watershed will be given higher priority than nontargeted watersheds for implementation of EEP restoration projects. 1.5.6 Wolfpen Creek [AU# 28-271 Current Status and 2004 Recommendations The current use support rating of Wolfpen Creek is No Data. Wolfpen Creek has never been monitored by DWQ; however, EEP (page 168) has a planned project in this local watershed. This is one of 27 local watersheds in the Tar -Pamlico River basin that has been identified by EEP as an area with the greatest need and opportunity for stream and wetland restoration efforts. This watershed will be given higher priority than nontargeted watersheds for implementation of EEP restoration projects. Section 6: Chapter 1 - Tar -Pamlico River Subbasin 03-03-01 103 2.1 Subbasin Overview Subbasin 03-03-02 at a Glance Land and Water Area Total area: 663 mil Land area: 654 miz Water area: 9 mi2 1 Population Statistics 2000 Est. Pop.: 91,606 people Pop. Density: 101 persons/Mi2 Land Cover {percents f `E Forest/ Wetland: 64 Surface Water: 1 Urban: 3 Cultivated Crop: 27 Pasture/ Managed Herbaceous: 4.6 Counties Edgecombe, Franklin, Nash, Vance, Warren and Wilson Municipalities Centerville, Nashville, Henderson, ` Rocky Mount, Spring Hope, Tarboro and Whitakers Section B - Chapter 2 Tar -Pamlico River Subbasin 03-03-02 ($lms Tar River Creek and Swift Creek S� c cc �ccc�s� i Population growth is occurring around Rocky Mount, which is the largest urbanized area in the subbasin. The fastest growing area is Franklin County near the boundary with subbasin 03-03-01. Much of the subbasin, which includes the Swift Creek watershed, is rural and little development is occurring. There are 12 individual NPDES wastewater discharge permits in this subbasin with a permitted flow of 23 MGD (Figure B-2). The largest is the Tar River Regional WWTP (21 MGD). There are also 15 general NPDES wastewater permits, two individual NPDES stormwater permits, and 58 general NPDES stormwater permits in the subbasin. Refer to Appendix i for identification and more information on individual NPDES permit holders. Henderson, Nashville, Rocky Mount, Tarboro, as well as Edgecombe, Franklin and Nash counties, will be required to develop stormwater programs under Phase II (page 75). Henderson, Nashville, Rocky Mount, Tarboro, and Edgecombe, Nash and Franklin counties will also have to submit model stormwater ordinances as required by the Tar -Pamlico NSW strategy (page 61) stormwater rules. Significant issues related to compliance with NPDES permit conditions are discussed below. There are also 32 registered animal operations in this subbasin. There were eight benthic macroinvertebrate community samples and seven fish community samples (Figure B-2 and Table B-3) collected in 2002 as part of basinwide monitoring. Two sites improved; one site remained the same, and three sites had lower bioclassifications. Seven sites were monitored for the first time, and there were two special study samples collected in the subbasin during the assessment period. Data were collected from nine ambient monitoring stations and one lake was monitored as well. Refer to 2003 Tar -Pamlico Raver Basinwide Assessment Report at http://www.esb.dnr.state.nc.us/bar.html and Section A, Chapter 3 for more information on monitoring. Section B: Chapter 2 — Tar -Pamlico River Suhbasin 03-03-02 104 Henderson SS-2 VANCE f� L .- LTi Figure B 2 Tar -Pamlico Riveo Subbasin 03-03-02 WARREN HAUFAX Pr8 it Castakia_, WhitaKers L� wRedf Oak t cogerra F-2 - ' 7 Dortrhes Rocky Qsu n Bwwary -- Mount , m Amniem Monitoring Station Spring Momeyer B-1 i Hope Nash ville♦1 �a © Fieh Communo Station - r F-I MIMES OWchargas A major 5j use support Rang L. ICI SUPPAV NASH Nimpalmd Not Rated No Date MLSON PrAwyRoads O Cy Municipal ty 10 0 10 Mlles Leggett ,- iarbaro EDGECOMSE Piginfiing Branch asinwide Planning Program Unit April 22, 2004 aI Table B-3 DWQ Assessment and Use Sunnort Ratings Summary for Monitored Waters in Subbasin 03-03-02 Waterbody Assessment Unit Number DWQ Classification Length/ Area Category Data Type with Map Number and Data Results Use Support Ratio 2004 1998 Biological Ambient Other Sapony Creek 28-55-(1) C NSW 7.7 nu AL F-1 NR--02 S NR TAR RIVER (Reservoir) 28-(63) WS-IV NSW CA 98.8 ac. AL L-1 nee S ST TAR RIVER 28-(66.5) WS-IV NSW CA 0.7 mi. FC FT-1 ce I N/A Stony Creek 28-68a C NSW 19.4 mi AL B-1 GF-02 S PS Pigbasket Creek 28-68-3-(2) C NSW 11.2 mi AL F-2 NR--02 NR NR TAR RIVER 28-(69) C NSW 11.3 mi AL B-2 GF--02 A-5 nee S ST TAR RIVER 28-(69) C NSW 11.3 mi. REC A-5 nee S NIA TAR RIVER 28-(74)a WS-IV NSW 21.0 mi AL B-3 GF--02 A-6 nee S FS TAR RIVER 28-(74)a WS-IV NSW 21.0 mi. REC A-6 nee S NIA Beech Branch 28-75-(4) WS-IV NSW 1.0 mi AL F-3 NR--02 NR FS Swift Creek 28-78-(0.5) C NSW 37.7 ac AL A-8 nee A-9 nee S FS Swift Creek 28-78-(0.5) C NSW 37.7 mi. REC A-8 nee A-9 nee S N/A Martin Creek 28-78-1-3 C NSW 4.2 mi. AL SB-1 NR-02 NR NR Weaver Creek 28-78-1-7 C NSW 6.5 mi. AL SB-2 NR--02 NR ST Sandy Creek 28-78-1-(8)b B NSW 11.3 mi. AL A-7 nee S PS Sandy Creek 28-78-1-(8)b B NSW 11.3 nu. REC A-7 nee S N/A Sandy Creek 28-78-1-(8)a B NSW 3.8 mi, AL F-4 GF--02 S PS Flatrock Creek 28-78-1-12 B NSW 9.1 mi. AL F-5 G--02 S NR Sandy Creek 28-78-1-(14) C NSW 20.3 mi. AL B-4 GF-02 S FS Red Bud Creek 28-78-1-17 C NSW 10.6 mi. AL F-6 G--02 S FS Swift Creek 28-78-(6.5) WS-IV NSW 10.0 mi. AL B-5 G- 02 S FS Whiteoak Swam 28-78-7-(2) WS-IV NSW 1 2.8 mi. AL B-6 MS--02 F-7 NR- 02 S FS Assessment Unit Number - Portion of DWQ Classified Index where monitorine is annlied to assign a use sunnort ratine. Use Categories: Monitoring data type: AL - Aquatic Life F - Fish Community Survey REC - Recreation B - Benthic Community Survey FC - Fish SF - Special Fish Community Study Consumption SB - Special Benthic Community Study A - Ambient Monitoring Site L - Lakes Assessment FT - Fish Tissue Site - Excellent N - Natural - Good MS - Moderate Stress F - Good -Fair SS - Severe Stress - Fair - Poor Ambient Data - no criteria exceeded - criteria exceeded - - se Support Ratings 2004: - Supporting, I - impaired, NR - Not Rated se Support Ratings 1998: 5 - fully supporting, ST - supporting but threatened, S - partially supporting, NS - not supporting, R - not rated, NIA - not anolicable Section B: Chapter 2 - Tar -Pamlico River Subbasin 03-03-02 106 Use support ratings for all waters in subbasin 03-03-02 are summarized in Part 2.2 below. Recommendations, current status and future recommendations for waters that were Impaired in 1999 are discussed in Part 2.3 below. Current status and future recommendations for newly Impaired waters are discussed in Part 2.4 below. Waters with noted water quality impacts are discussed in Part 2.5 below. Water quality issues related to the entire subbasin are discussed in Part 2.6. Refer to Appendix III for a complete list of monitored waters and more information on Supporting monitored waters. 2.2 Use Support Assessment Summary Use support ratings were assigned for waters in subbasin 03-03-02 in the aquatic life, recreation, fish consumption and water supply categories. All waters are Impaired on an evaluated basis in the fish consumption category because of statewide fish consumption advice for mercury that is applied in this category to basins east and south of I-85 (page 90). Also, 0.7 miles of the Tar River are Impaired in the fish consumption category based on fish tissue monitoring data. In the water supply category, all waters are Supporting on an evaluated basis based on reports from DEH regional water treatment plant consultants. There were 187.9 stream miles (37 percent) and 717.6 freshwater acres (99 percent) monitored during this assessment period in the aquatic life category. There were no Impaired waters in this use category. Refer to Table B-4 for a summary of use support ratings for waters in subbasin 03- 03-02. Section B: Chapter 2 — Tar -Pamlico River Subbasin 03-03-02 107 Table B-4 Summary of Use Support Ratings by Category in Subbasin 03-03-02 Use Support Rating Aquatic Life Fish Consumption Recreation Water Supply Monitored Waters Supporting 165.0 mi 717.6 ac 0 81.2 0 Impaired 0 0.7 0 0 Not Rated 22.9 0 0 0 Total 187.9 mi 717.6 ae 0.7 j 81.2 mi j 0 Unmonitored Waters Supporting 0 0 0 129.3 mi 722.0 ac Impaired 0 510.5 722.0 0 0 Not Rated 0 0 0 0 No Data 323.3 mi 4.4 ac 0 430.0 mi 722 ac 0 Total 323.3 mi 4.4 ac 510.5 722.0 422.4 98.9 129.3 mi 722.0 ae Totals All Waters 511.2 mi 722 ae 511.2 mi 722 ac 511.2 mi 722 ac 129.3 mi 722.0 ae 2.3 Status and Recommendations of Previously Impaired Waters Waters in the following section are identified by assessment unit number (AU#). This number is used to track defined segments in the water quality assessment database, 303(d) Impaired waters list, and the various tables in this basin plan. The assessment unit number is a subset of the DWQ index number (classification identification number). A letter attached to the end of the AU# indicates that the assessment is smaller than the DWQ index segment. No letter indicates that the assessment unit and the DWQ index segment are the same. 2.3.1 Sandy Creek [AU# 28-78-1-(8)a, b and 28-78-1-(14)] 1999 Recommendations It was recommended that Sandy Creek be resampled to determine if the water Quality impacts noted in 1997 were related to the 1996 Hurricane Fran. Current Status Sandy Creek (35.4 miles) from NC 401 to Swift Creek is currently Supporting in the aquatic life category because of Good -Fair bioclassifications at sites B-4 and F-4 in 2002. No criteria were Section B: Chapter 2 - Tar -Pamlico River Subbasin 03-03-02 108 exceeded at site A-7. Based on bacteriological monitoring (site A-7), Sandy Creek [AU# 28-78- 1-(8)b only] is Supporting in the recreation category. In the 1999 plan, Sandy Creek was Impaired from NC 401 to NC 561 (15.1 miles). Possible causes of the impairment were thought to be related to the hurricane and possibly to logging and a milldam just upstream of site B-4. Intolerant species were collected in 2002, indicating reduced impact to the stream. The biological community may also have been adversely impacted by the four-year drought, although nonpoint source runoff impacts may have been minimized during this time. The High Roost Poultry Farm has been an inactive operation since 1998. The farm lagoon has had overflows during some rain events and there have been civil penalty assessments against the farm. 2004 Recommendations DWQ will continue to monitor water quality in Sandy Creek to determine if the cause of the depressed biological community is from extreme meteorological events or land use activities. Land -disturbing activities should implement BMPs to minimize or prevent future impacts to water quality in the Sandy Creek watershed. The Sandy Creek watershed is also part of a proposed ORW management strategy to protect water quality in downstream portions of Swift Creek. The Raleigh Regional Office staff will continue to monitor the High Roost farm. Additionally, DWQ will continue to work with the Office of the Attorney General in pursuit of obtaining corrective actions to cease the overflows and will also work with farm owners and other agencies to find a permanent solution. 2.3.2 Stoney Creek [AU## 28-68a] 1999 Recommendations Because of low flow in 1997, Stoney Creek was not resampled in 1997, although it remained on the 303(d) list of Impaired waters. No recommendations were made to address water quality issues in the 1999 plan. Current Status Stoney Creek (Boddies Mill Pond 19.4 miles) from the source to Lassiters Creek is currently Supporting because of Good -Fair bioclassification at site B-1. No data were collected on the lower segment from Lassiters Creek to the Tar River (segment runs through urban areas in southwest Rocky Mount). Although most of the watershed is in forest and agricultural land use, there is development occurring both upstream and downstream of site B-1. The cause of the depressed bioclassification is likely habitat degradation, as there was little riparian area and moderate to severe bank erosion noted at site B-1. Also, drought conditions limited available habitat in Stoney Creek during monitoring (page 82). 2004 Recommendations DWQ will continue monitoring Stoney Creek to determine if the cause of the depressed biological community is from extreme meteorological events or land use activities. Water quality should be considered during land -disturbing activities, and BMPs should be implemented to minimize or prevent future impacts to water quality in the Stoney Creek watershed. Section B: Chapter 2 — Tar -Pamlico River Subhasin 03-03-02 109 Current Water QuafiU Initiatives Because of previous impairment and current water quality degradation, this is one of 27 local watersheds in the Tar -Pamlico River basin that has been identified by EEP as an area with the greatest need and opportunity for stream and wetland restoration efforts. 2.4 Status and Recommendations of Newly Impaired Waters Waters in the following section are identified by assessment unit number (AU#). This number is used to track defined segments in the water quality assessment database, 303(d) Impaired waters list, and the various tables in this basin plan. The assessment unit number is a subset of the DWQ index number (classification identification number). A letter attached to the end of the AU# indicates that the assessment is smaller than the DWQ index segment. No letter indicates that the assessment unit and the DWQ index segment are the same. 2.4.1 Tar River ]AU# 28-(66.5)] Current Status The Tar River (0.7 miles) is currently Impaired in the fish consumption category from Maple Creek to Old Rocky Mount water intake because fish tissue collected in this segment exceeded the state criterion of 0.4 µg of methylmercury per gram of fish tissue. Five of 13 large mouth bass collected in this segment also exceeded this criterion. There is also statewide consumption advice for mercury in fish tissue that is applied to waters east and south of I-85. 2002 Recommendations Contamination of fish tissue with mercury is a regional issue. Refer to page 90 for more information on plans to address mercury. 2.5 Status and Recommendations for Waters with Noted Impacts The surface waters discussed in this section are not Impaired. However, notable water quality problems and concerns have been documented for these waters based on this assessment. While these waters are not Impaired, attention and resources should be focused on these waters to prevent additional degradation or facilitate water quality improvement. Waters in the following section are identified by assessment unit number (AU#). This number is used to track defined segments in the water quality assessment database, 303(d) Impaired waters list, and the various tables in this basin plan. The assessment unit number is a subset of the DWQ index number (classification identification number). A letter attached to the end of the AU# indicates that the assessment is smaller than the DWQ index segment. No letter indicates that the assessment unit and the DWQ index segment are the same. Section B: Chapter 2 -- Tar -Pamlico River Subbasin 03-03-02 110 2.5.1 White Oak Swamp [AU# 28-78-7-(2)] Current Status and 2004 Recommendations White Oak Swamp (2.8 miles) is currently Supporting because of a moderate stress bioclassification at site B-6 in 2002. The stream was channelized in the past, but habitat is good and the stream appears to be recovering. DWQ will continue to monitor White Oak Swamp to assess further recovery. Water quality should be considered during land -disturbing activities, and BMPs should be implemented to minimize or prevent future impacts to water quality in the White Oak Swamp watershed. 2.5.2 Beech Branch [AU# 28-75-(4)] Current Status and 2004 Recommendations The current use support rating of Beech Branch is Not Rated because site F-3 could not be rated as criteria for assigning bioclassifications to fish community samples have riot been developed for coastal plain streams (page 73). Past channelization was noted at site F-3 and the area had been recently logged. The fish community was diverse; however, and more fish were collected here than at other coastal plain sites. DWQ will continue to monitor Beech Branch to assess changes in the fish community that might be related to land -disturbing activities. Water quality should be considered during land - disturbing activities, and BMPs should be implemented to minimize or prevent future impacts to water quality in the Beech Branch watershed. DWQ will continue to develop criteria to assign bioclassifications for coastal plain fish communities. 2.5.3 Tar River Reservoir [AU# 28-(63) and 28-(36)] Current Status and 2004 Recommendations The Tar River Reservoir is Supporting in the aquatic life category based on monitoring during the summer of 2002. Because of the drought, water levels dropped four feet during the summer, and nutrients and chlorophyll a increased during the summer. Increased turbidity levels were likely (from 1997 levels) related to the lower lake levels. DWQ will continue to monitor the lake. Because of the potential water quality problems noted above and because the Tar River Reservoir is a public water supply, it has been identified by EEP as one of 27 local watersheds in the basin with the greatest need and opportunity for stream and wetland restoration efforts. This watershed will be given higher priority than nontargeted watersheds for implementation of EEP restoration projects. 2.5.4 Tar River [AU# 28-(69) and 28-(74)a] Current Status and 2004 Recommendations The current use support rating of the Tar River from Rocky Mount Mills to the subbasin boundary is Supporting because of Good -Fair bioclassifications at sites B-2 and B-3 in 2002. Both of these bioclassifications are lower than in 1997. Trash was noted as well as eroding Section B: Chapter 2 — Tar -Pamlico River Suhhasin 03-03-02 H ] streambanks at site B-2. The lower bioclassification at site B-3 is attributed to drought. No stoneflies were present at site B-2, indicating some water quality problems in this segment. No criteria were exceeded at sites A-5 and A-6, although total suspended solids and total phosphorus were elevated at both sites. DWQ will continue to monitor the Tar River to determine if the lower bioclassifications were because of drought or other water quality problems related to land disturbances or discharges. 2.5.5 Pig Basket Creek [AU# 28-68-3-(1) and (2)] Current Status and 2004 Recommendations The lower portion of Pig Basket Creek is currently Not Rated because a bioclassification could not be assigned at site F-2 in 2002. Low dissolved oxygen levels were noted at F-2 as well. There is currently no data available to assign use support ratings to the upper portion of Pig Basket Creek. Production Enterprises poultry farm has had overflows of the treatment lagoon near the source of Pig Basket Creek. The facility is presently abandoned by its owners and has had no poultry since 2001. The Raleigh Regional Office staff will continue to monitor the Production Farm. Additionally, DWQ will continue to work with the Office of the Attorney General in pursuit of obtaining corrective actions to cease the overflows and will also work with farm owners and other agencies to find a permanent solution. 2.5.6 Red Bud Creek [AU# 28-78-1-171 Current Status and 2004 Recommendations Red Bud Creek (10.6 miles) from the source to Sandy Creek is currently Supporting in the aquatic life category because of Good bioclassification at site F-6 in 2002. The Yang Poultry Farm has had overflows of the treatment lagoon near an unnamed tributary to Red Bud Creek. The facility was assessed a civil penalty for a discharge in 2000. This farm was depopulated of birds in October of 2003 and is presently abandoned. The Raleigh Regional Office staff will continue to monitor the Yang Farm. Additionally, DWQ will continue to work with the Office of the Attorney General in pursuit of obtaining corrective actions to cease the overflows and will also work with farm owners and other agencies to find a permanent solution. 2.6 Additional Water Quality Issues within Subbasin 03-03-05 2.6.1 Swift Creek and Sandy Creek Portions of these two creeks have been reclassified to ORW because of excellent water quality. Refer to page 41 for more information on this reclassification. Section B: Chapter 2 — Tar -Pamlico River Subbasin 03-03-02 112 Date: January 31, 2015 Novozymes, NA Inc. 77 Perry's Chapel Church Rd. Franklinton, N.C. 27525 NCDENR Division Of Water Quality 1617 Mail Service Center Raleigh, N.C. 27699-1617 Attn: Division Of Water Quality Storm Water Sampling, NPDES Permit No. NCS000115 Dear Sir/Madam novozy mes� Rethink Tomorrow Per our Tier Two requirements, regarding the exceeded benchmark in Total Suspended Solids, (TSS), our implementation of a monthly monitoring in area of concern, "Outfall 1", beginning in January have resulted in "No Flow" for the month of January. We therefore were unable to collect a sample for this moth. We plan to continue to diligently with our monthly monitoring for parameter of TSS until we obtain three consecutive sample results within the benchmark range. Kind Regar Joe Ladd Environmental Compliance Coordinator Environmental Services NJ" RECEIVED MAY 10t5 DENR-LAND QUALITY STORMWATER PERMITTING � . . . -.��. . � � • � \/ � / �\ ) - � � \\ } ¥ ! f� . \. -x Date: December 31, 2014 Novozymes, NA Inc. 77 Perry's Chapel Church Rd. Franklinton, N.C. 27525 NCDENR Division Of Water Quality 1617 Mail Service Center Raleigh, N.C. 27699-1617 Attn: Division Of Water Quality Storm Water Sampling, NPDES Permit No. NCS000115 Dear Sir/Madam novozy mes• �: ) Rethink Tomorrow During review of storm water sampling results, it was observed that there was an exceeded benchmark in Total Suspended Solids, (TSS) deriving from Outfall 1. Upon immediate investigation, per Tier One requirements, it was concluded that recent construction on site has created much exposed soil in areas of close proximity to storm drains. Works being performed using heavy equipment, dump trucks, and tracked vehicles for example, have resulted in exposed soil in high traffic areas as well. Also, there have been multiple projects taking place on site during recent months, along with frequent heavy rains directly impacting turbidity readings. Environmental Services will be updating and replacing current BMP's placed throughout site including more strategic locations the current construction areas are impacting. Upgrades made from previous sampling lowered TSS readings however not below benchmark standards. Therefore, per Tier Two requirements, we will begin monthly monitoring of Outfall 1 until three consecutive sample results are below benchmark values. Continued monitoring by Environmental Services Department will take place in order to prevent future exceeded benchmarks in Total Suspended Solids, (TSS). Kind Regards, Joe Lad Environmental Compliance Coordinator Environmental Services EFFLUENT NPDES PERMIT NO. NCS000115 DISCHARGE NO. 1 MONTH December YEAR 2014 FACILITY NAME NOVOzymes, NA Inc. CLASS COUNTY: Franklin OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA PHONE (919) 494-3001 _ CERTIFIED LABORATORIES (1) Enco (2) CHECK BOX IF ORC HAS CHANGED 17 PERSONS) COLLECTING SAMPLES Joe Ladd Mail ORIGINAL and ONE COPY to: ATTN: CENTRAL FILES x NIA DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) '1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY RALEIGH, NC 27699-1617 KNOWLEDGE. mom DWQ Form MR-1 (11/04) Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) Compliant Ail monitoring data and sampling frequencies do NOT meet permit requirements Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.6 of the NPDES permit. -I certity, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Randy Green _ Permittee (Please print or type) SignatuLQ,df Per t to * Date (Required unless su itted electronically) Permittee Address Phone Number e-mail address Permit Expiration Date ADDITIONAL CERTIFIED LABORATORIES Certified Laboratory (2) Certification No. Certified Laboratory (3) Certification No. Certified Laboratory (4) Certified Laboratory (5) PARAMETER CODES Certification No. Certification No. Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.enr.state.nc.us/was and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. •* ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204, *** Signature of Permittee: if signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per 15A NCAC 2B .0506(b)(2)(D). Page 2 EFFLUENT NPDES PERMIT NO. NCS000115 DISCHARGE NO. 2 FACILITY NAME Novozymes, NA Inc. CLASS OPERATOR IN RESPONSIBLE CHARGE (ORC) NIA CERTIFIED LABORATORIES (1) Enco (2) CHECK BOX IF ORC HAS CHANGED =0 PERSON(S) COLLECTING SAMPLES Mail ORIGINAL and ONE COPY to: MONTH December YEAR Joe Ladd COUNTY: Franklin PHONE 919 494-3001 A I I N: CENTRAL FILES x NIA DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) 1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY RALEIGH, NC 27699-1617 KNOWLEDGE. 2014 MEMO mmmgwffl� imummosmaw DWQ Form MR -I (11104) :'W7 JW Facility Status: (Please check one of the following) All monitoring data and sampling frequencies meet permit requirements (including weekly averages, if applicable) Compliant All monitoring data and sampling frequencies do NOT meet permit requirements Noncompliant The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by Part II.E.b of the NPDES permit. "I certity, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Randy Green Permittee (Please print or type) —:: - Sign a of ittee*** Date (Required submitted electronically) Permittee Address Phone Number c-mail address Permit Expiration Date ADDITIONAL CERTIFIED LABORATORIES Certified Laboratory (2) Certification No. Certified Laboratory (3) Certification No. Certified Laboratory (4) Certification No. Certified Laboratory (5) Certification No. PARAMETER CODES Parameter Code assistance may be obtained by calling the NPDES Unit at (919) 733-5083 or by visiting the Surface Water Protection Section's web site at h2o.ennstate.nc.us/LALgs and linking to the unit's information pages. Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for the entire monitoring period. ** ORC On Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204, *** Signature of Permittee: If signed by other than the permittee, then the delegation of the signatory authority must be on file with the state per I SA NCAC 2B .0506(b)(2)(D). Page 2 1p ENCO Laboratories Accurate. Timely. Responsive. Innovative. 102-A woodwinds Industrial Court Cary NC, V511 Phone: 919.467.3090 FAX: 919.467.3M Wednesday, December 24, 2014 Novorymes North America (N0008) Attn: Joe Ladd 77 Perry Chapel Church Road Franklinton, NC 27525 RE: Laboratory Results for Project Number: [none], Project Name/Desc: Stormwater Testing ENCO Workordler(s): C415936 Dear Joe Ladd, Enclosed Is a copy of your laboratory report for test samples received by our laboratory on Wednesday, December 10, 2014. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed In accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained In this report are in compliance with NELAC standards, except as noted in the project narrative. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Stephanie Franz For Chuck Smith Project Manager Enclosure(s) FD AL This report relates onty to the sample as reaWed ty the laboratory, and may any he reproduced in ma. Pagel of 11 WwW.encolabo.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: OutfAO -1 Lab ID: C415036-01 Sampled: 12/09/14 15:45 Reodved: 12/10►14 08:03 parameter EPA 351.2 Held beteMme(ai 01/06/15 Prep Date171mel:1 12/19/14 10:52 12/22/14 12:34 EPA 353.2 12/11/14 15:45 12/10/14 14:39 12/10/14 15:46 EPA 353.2 01/06/15 12/18/14 12:01 12/18/14 12:01 EPA 353.2 09/03/17 12/24/14 10:10 12/24/14 10:15 EPA 365.4 01/06/15 12/19/14 10:52 12/22/14 14:18 SM 2540D-1997 12/16/14 12/15/14 08:45 12/15/14 0B:45 SM 5210B-2001 12/11/14 15:45 12/10/14 12:36 12/10/14 12:36 SM 5220D-1997 01/06/15 12/15/14 11:05 12/15/14 15:33 Client ID: Outfa0.2 Lab ID: 041593"2 Sampled: 12/02/14 16:20 Received: 12/10/14 08:03 Ponsmater EPA 351.2 Hold Data/71me(sl 01/06/15 12/12/14 10:39 12/16/14 19:22 EPA 353.2 12/11/14 16:20 IVIO/14 14:39 12/10/14 15:47 EPA 353.2 01/06/15 12/18/14 12:03 12/18/14 12:03 EPA 353.2 09/03/17 12/24/14 10:10 12/24/14 10:15 EPA 365.4 01/06/15 12/17/14 10:39 12/16/14 19:58 SM 2540D-1997 12/16/14 12/15/14 08:45 Q/15/14 08:45 SM 521OB-2001 12/11/14 16:20 12/10/14 12:36 12/10/14 12.35 SM 5220D-1997 01/06/15 12j15/14 11:05 12/15/14 15:33 MAL This report rdeus a* to ft sample as revel by me may, and may ony be reprodumd In AA. Paps 2 of 1 t 00 s� ttir www.enoolaba=m SAMPLE DETECTION SUMMARY client ID: Outta9 -1 lab IDr C415936-01 6Dpdt>A 112W l6 an Ha ML lWlt memo M21M Biochemical Oxygen Demand 3.5 2.0 2.0 mg/L SM 5210E-2001 Chemical Oxygen Demand 54 10 10 mg/L SM 5220D-1997 Nitrate as N 0.41 0.025 0.10 mg/L EPA 353.2 Nitra*Nft to as N 0.41 0.041 0.10 mg/L EPA 353.2 Phosphorus 0.29 0.025 0.10 mg/L EPA 365.4 Total igeldaht Nitrogen 1.2 0.26 0.48 rrg/L EPA 351.2 Total Suspended Solids 120 1.0 1.0 L SM 2540D-1997 Client ID: Outfall - 2 Lab ID: C415236-02 An w n 81111illib on Ma ML mum NeUmd flow Chemical Oxygen Demand 12 10 10 mg/L SM 5220D-1997 Nitrate as N 0.080 ] 0.025 0.10 mg/L EPA 353.2 Nbate/Nttrtte as N 0.080 1 0.041 0.10 mg/L EPA 353.2 Total Kjeldahi Nitrogen 0.30 1 0.26 0.48 mg/L EPA 351.2 FINAL This report ndapes only to the sample as reed by dm Iabara0ory, and may only be reproduced In full. Paps 3 of 11 www.encolabs.com ANALYTICAL RESULTS DGMAptlon. Ounil - 1 Lob Sample ID: C41593601 Received: 12/10/14 09:05 Matrix: Surface Water Sampled:12/09/14 15:45 Work Order: C415936 Projed: Stormwater Tesdng Sampled By:]oe Ladd Classical Chemistry Parameters ^ - E7VX Cbr mVkder *M (AC S911 Andyte MM Numbed Rumb an lithe DE MRL EM AWMh Medwd ADW=d ft ham Modiverniral Oxygen Demand- 3.S mg/L 1 2.0 2.0 4L10013 SM 52108-2001 12/10/14 12:36 30C Chemical Oxygen Demand^ 54 mg/L 1 10 10 4L15008 SM 522OD-1997 12/15/14 15:33 10C N11 I I as N [14797-3S-E]^ 0.41 mg/L 1 0.025 0.10 4LZ4018 EPA 353.2 IV24114 10:15 AM NNrote/NNiibe w N^ 0.41 mg/L 1 0.041 0.10 4L18005 EPA 353.2 12/18/14 12:01 AM Nftrihe as N [14797-65-0]^ 0.017 U mg/L 1 0.017 0.10 4L10030 EPA 353.2 12/10/14 15:46 SHA Phosphorus [7723-14.01^ 0.29 rtg/L 1 0.025 0.10 4L19003 EPA 365.4 12/22/14 14:18 SHA Total KjeWahl Nlhogen^ 1.2 ng/L 1 0.26 0.48 4L19001 EPA 351.2 12/22/14 12:34 SHA Total Suspended Sollds^ 120 rtg/L 1 1.0 1.0 4L15002 SM 2MOD-1997 12/15/14 08:45 MR Description: Outrall - 2 Lab Sample ID:C415936-02 Remind: 12/10/14 08:05 Matrbc: Surface Water Sampled:12/09/14 16:20 Ware Order: C415936 Project: Stormwater Tesdng Sampled By:]oe Ladd Classical Chemistry Parameters f ^•MX CIWY avlk m*ftPC 5911 Anahft MAS Numberl Baum an linill of Mu 12L IBM Mfdtmd hnwmd MR ado Biochemical 0xygen Demand- 2.0 u mg/L 1 2.0 2.0 4L10013 SM 5210f1-2001 12/10/14 12:36 3oC Chamkel Oxygen bamand^ 12 mg/L 1 10 10 41,15008 SM 522OD-1997 12/15/14 15:33 30C Nitrate as N [14797-5S-a]^ 0A80 1 mg/L 1 0.025 0.10 4LZ4018 EPA 353.2 12/24/14 10:15 AM Nitrate/Na21te as N^ 0.080 1 mg/L 1 0.041 0.10 4L18005 EPA 353.2 12/18/14 12:03 A38 Nitrite as N [14797-05-0]^ 0.017 U ng/L 1 0.017 0.10 4L1D030 EPA 353.2 12/10/14 15:47 SHA Phosphorus [7723-14-0]^ 0.025 U mg/L 1 0.025 0.10 4L12009 EPA 365.4 12/16/14 19:58 A18 Total KjeidaM Nldogen^ 0." 3 mg/L 1 0.26 0.48 4L12008 EPA 351.2 IV16/14 19:22 A1B Totat Suspended Sands^ 1.0 U mg/L 1 1.0 1.0 4LIS002 SM 25MD•1997 12/15/14 08:45 MMR FINAL This Report mdaonly m me woe as reorhra by the iabarahmy. and may o* be reprv6xzd In ruff. Pegs 4 of 1 I www.ancolabo.com QUALITY CONTROL DATA Clasalml Chemistry Paramabero - QualltY Control Bach 4LIP013 -IUD P1RM Blank (41.1001"Ll(1) Prepared & AnoWecl: 12/10/2014 12:36 Spike Source %REC RPD 1 RAIUM Beg POL UBlle Level gCEM %REC UmBi RPD Limit NotelL Bl diemlcal Oxygen Demand 2.0 U 2.0 mg/L 0-03 LCS (4L10013-BSl) Prepared & Analyzed: 12/10/2014 12:36 Spike Source %REC RPD An Besl1B Bea POL Units Level ggaft %REC Umb RPD L(mlt M20 Bkidiernlal Oxygen Demand 180 2.0 mg/L 198 93 85-115 Duplicate (4L10013-DUP3) Prepared & Anayzed: 12/10/2014 12:36 Source: C413466-01 Spike Source %REC RPD �nehde Bawa Ben POL Units Laval gpnig %REC Llmile RPD LM not" Bbdiemlal Oxygen Demand 1800 2.0 mg/L law 1 30 Be" 4110WO-AV MID ZZ (41.10030-111M) Prepared: 12110/2014 14:39 Analyzed: 12/10/2014 ISM Spice Source %REC RPD JDehme Remo Beg PAL Units Level g2aft %REC UMMI RPD Limit Not"L Nitrite as N 0.017 U 0.10 mp/L LCS (4L10030-BSI) Prepared: 12/10/2014 14:39 Analyzed: 12/10/2014 15:41 Spike Source %REC RPD Ana Lda Bamit Beg ML llnlsi Level gAM& %REC UMM RPD Limit Notes Nitrite as N 1.0 0.10 mg/L 1.00 101 90-110 LCS (4L10030-BS2) Prepared: 12/10/2014 14:39 Analyzed: 12/10/2014 15:49 Spike Source %REC RPD Ana hda 911111911 Beg POL UBlts Leval goo %REC LWIM RPO Limit Notes, Nllrlte as N 1.0 0.10 rrrg/L 1.00 100 90-110 LCS (4L10030-BS3) Prepared: 12/10/2014 14:39 Analyzed: 12/10/2014 16:53 Spike Source %REC RPD Ana hd11 Raub Beg PAL UDlte Level 8oiyg %REC Limits RPD Limit Notea, Nitrite as N 0.96 0.10 mg/L 1.00 98 90-110 LCS (41.10030-111S4) Prepared: 12/10/2014 14:39 Analyzed: 12/10/2014 17:01 SPUN Source %REC RPD �oanda Result Beg POL UDlti Level BIM& %REC Limits RPD Limit Notes, Nitrite as N 1.0 0.10 mg/L 1.00 101 90-110 Matrix Spike (4L10030-MSl) Prepared: 12/10/2014 14:39 Analyzed: 12/10/2014 15:43 Source: C415177-01 $Oka Source %RRC RPD Am Haigh Bea ML Units Level golift %REC Limits RPD Limit Notes Nitrite as N 0.76 0.10 mg/L 1.00 0.023 74 90-110 QM-05 Matrix Spike Dup (4L10030-MSD1) Prepared: 12/30/2014 14:39 Analyzed: 12/10/2014 15:44 Source. C413177-01 Spica Source %REC RPD Ana hda Rena Bea POL Unks Leval gaM %REC Limits RPD Limit Notes FINAL This report relates only t0 the sample as remtvW by the laboratory, and may only be nVroducad In full. Page 5 of 11 www.ancelabo.com QUALITY CONTROL DATA Claealcal Chemistry Parameters - Quality Control Anldl 4LIOV" - NO PREP - Condnued Matrix Splice Will (4110030-11SD1) Coat Ued Prepared: 12/10/201414:39 Analyzed: 12/10/201415:44 Source: C419177-01 Spike Source %REC RPD Ann BEilllt gad pal 11BBa Lard g&ng %REC Limits RPD L(mlt NotaL NItrft as N 0.76 0.10 mg/L 1.00 0.023 74 90-110 0.4 10 QM-05 Bald► 4L.920M - Soma Blank (411.12008-0LRl) Prepared: 12/12/201410:39 Analyzed: 12/16/201419:08 Spike Source %REC RPD .Au011t% BagIB Had ML 1111111231 Lard gll& %REC Limns RPD Llm11 Notes Total Kjeldahl Nitrogen 0.26 U 0.48 MWL LCS (4L12008-BSk) Prepared: 12/12/201410:39 Analyzed: 12/16/2014 19:11 Spike Source %REC RPD �tlanda Bradt Has E41 Units Lord good %REC 1,(m(ta RPD Llmlt notes Total i(leklahl Nitrogen 12 0.48 mg/l. 12.0 98 90.110 Matrtx Spike (4L12008-MS1) Prepared: 12/12/2014 10:39 Analyzed: 12/16/2014 19:15 Source: C411111-01 Spike Source %REC RPD Anaba BdWR Had E4L Unbs Lord fthdt %RFC USM RPD Limit Kotft Total igeldahl Nib ow 5.8 0.48 mg/L 4.79 1.3 94 90-110 Matrix Spike Dup (4L32008-MSDl) Prepared: IV12/2014 10:39 Analyzed: 12/16/2014 19:17 Source: C411111-01 Spike Source %REC RPD ADahtta Beloit Had P9L 111ft Laval g§Ug %REC Limits RPD LIMB Fiats". Total I(jeldahl Nitrogen 5.9 0.48 mg/L 4.79 1.3 95 90.110 1 10 Batrli 4L12Wg - SNIM Blank (4L11008-SM) Prepared: 12/12/2014 10:39 Analzed: 12/16/2014 19:50 Spike Source %REC RPD �da!ffi Result Had e91 Lined Lmd ggSift %REC LMM RPD Limit NON Phosphorus 0,025 U 0.10 mg/L LCS (4L12009-BS1) Prepared: 12/12/2014 10:39 Analyzed: 12/16/2014 19:51 Spike Source %REC RPD Aoanda Result Elad P91 UnIL1 Level gMM %REC Nmlta RPD 1llllit Notes Phosphorus 1.7 0.10 mg/L 1.60 103 80.120 Mstrhc SpBoe (4111.12000-Ml) Prepared: 12/12/2014 10:39 Analyzed: 12/16/2014 19:54 Source: C411111-01 Bpika Source %REC RPD Ananda Result Elan FOL 1,11111113 Lavd gM %REC LlMB& RPD Llmlt Hates Phosphorus 0.68 0.10 mg/L 0.640 0.051 98 80-120 Matrix Spike Dup (411.12009-MSD1) Prepared: 12/12/2014 10:39 Analyzed: 12/16/2014 19:56 Source: C411111-01 Phosphoms Adtr,:h 4U50102 - NO PREP spike source %REC Begin Had EQL 1111111131 Level SMU %REC L MUR RPD 0.69 0.10 M91L 0.640 0.051 99 80-120 1 RPD Limit Not" 25 FINAL This report ml3tas any to the sonpie as rwdved by the laeoretory, and may only be reproduced In full. Page a of 11 www,enmlahs.mm QUALITY CONTROL DATA Classiml Chemistry Paramobars - Quality Control Aetcli 4 X VD2 - NO PAW - CamObLed Blank (4L18002-ELKS) Prepared & Analyzed: 12/15/2014 0BAS Spike Source %REC RPD Analvia Bend BaR e41 UDltt Lord gAWR %REC Umaa RPO I.IB1it BRiIw- Total Suspended Solids 1.0 U 1.0 mg/L LCS (41.18002-BS1) Prepared & Analyzed: 12/15/2014 08:45 Spike Source %REC RPD AmbW gonft an P" Unlis Level Remit %REC Umat RPD LIIDi! motes, Total Suspended Solids 93 1.0 mg/L 100 93 80.120 Duplicate (41.15002-DUP1) Prepared & Analyzed: 12/15/2014 08:45 Source: C416385.01 Spike Source C116REC RPD ADands Basalt EiaO eOI. Unite Level BEWR %REC UMU RPD U" Notes Total Suspended Solids 1600 1.0 mg/L 1800 12 10 QM-12 Duplicate (411.15002-DUP2) Prepared & Analyzed: 12/15/2014 08:45 Source: C416383-02 Space Source %REC RPD ABanda Bailie Emu eQL U1111a Level gang %REC Umb RPD Llmlt Notes Total Suspended Solids Astrb 4USM - Sww 140 1.0 mg/L 140 0 10 Blank (411.1500"UU) Prepared: i2/15/2014 11:05 Analyzed: 12/15/2014 15:33 Spike Source %REC RPD Anabu HOWU iials F4L UBa6 Level gaBift %REC Nmlti RPD lima AW Chemical Oxygen Demand 10 U 10 mg/L LCS (41.15008-11381) Prepared: 12/15/2014 11:05 Analyzed: 12/15/2014 15:33 Spike Source %REC RPD Anahtta Baas$ Ertl $QL Untla Lard g2j& %REC NMb RPD lba Notes. Chemical Oxygen Demand 490 10 mg/L 500 98 90-110 Matrix Spike (41.15008-MSl) Prepared: 12/15/2014 11:05 Analyzed: 12/15/2014 15:33 Source: C414995-01 Spike Source %REC RPD ADahte BBslilt Flan RM Untie Lend ROM %REC Limas RIND Lfmlt Notes Chemical Oxygen Demand 520 10 mg/L 500 10 U 103 90-110 Matrht SpUro Dup (41.15008-111111SDl) Prepared: 12/15/2014 11:05 Analyzed: 12/15/2014 15:33 Source: C414993-01 Spike Source %REC RPD Ana hdel Boault Elm POI. Ulm Level 920d %REC UMU RPD 1.111111(1 Nome Chemical oxygen Demand 510 10 mg/L 500 10 U 101 90.110 2 10 Batt* AIRMS - NO AW Blank (411.18005-BLK1) Prepared: 12/18/2014 11:13 Analyzed: 12/18/2014 11:13 Spike Source %REC RPD Aoahttla Basalt Flan MI. Lb al Level AMA %REC Llmltt RPD Limit motet Nitrate/Nitrtte as N 0.041 U 0.10 mg/L r I1Hu This report relates only to the sample as recall vetl by tee laboratory, and may only to reprodLx etl In Ice. Pegs 7 of 11 www.emcolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Befd1l &18" - AND PREP - Coaffh W LCS (41.18003-01) Prepared: 12/18/2014 11:11 Analyzed: 12/18/2014 11:11 Spike Source %REC RPD �ndhma Biel$ Elm M1 Milne, Lard B4i& %REC MmU RPD LIMB W. Nltrate/Nroft as N 1.3 0.10 mg/L 1.25 101 90-110 Matrix Spike (41.18009-MS1) Prepared: 12/18/2014 11:18 Analyzed: 12/18J2014 11.18 Mae Source: C414405-01 Spike Source %REC. RPD Anahtta Ralad Ella PQL U»ila Laval Be811L %REC 1(mMit RPD U11111: NoW Nitrate/Nitrtte as N 1.0 0.10 mg/L 0,513 0.53 96 9o-110 Matrix Spike Dup (41.18003-MS01) Prepared: 12/18/2014 11:20 Analyzed: 12/18/2014 11:20 Source: C41491113.01 Spike Source %REC RPD boande Sta t Elea PQL llalti Level Besllt %REC 1rlmft RPD Lump; n0W NitrateMb1te as N 1.0 0.10 mg/L 0.513 0.53 92 90.110 2 10 ffatch 4L Owl - sSama Blank (4L19001-51.1(1) Prepared: 12/19/2014 10:52 Analyzed: 12/22/2014 11:50 Spike Source %REC RPD Anlllllt0 Secant an 241 Usti Laval Ralilt %REC Lkab RPD LIMM Notm Total lyeldahl Nitrogen 0.26 U 0.48 mg/L LCS (41.19001$Sl) Prepared: 12/19/2014 10:52 Analyzed: 12/22J2014 11:52 Spike. Source %REC RPD �0ab�a Result ila0 Pak UnH2 Level BOsu)t %REC Limb RPD 1.111111; 02W Total Kjeldahl Nitrogen 13 0.48 mg/L 12.0 104 90-110 Matrix Spike (4L39001-MS1) Prepared: 12/19/2014 10:52 Analyzed: 12/22J2014 11:56 Source. C413281-01 Spike source %REC RPD llnabma ftaltt In P" lhnita Laval goij& %REC 1W RPD LWO W Total K)eldahl Nitrogen 7.0 0.48 mg/L 4.79 2.1 101 90-110 Matrix Spike Dup (4L19001-MSDl) Prepared: 12/19/2014 10:52 Analyzed; 12/22J2014 11:58 Source: C413261-01 Spike Source %REC RPD llnabma Basil! !%e POL UAL Lard MW= %REC UMM RPD 1.181ift Not" Total K)eldahl Nitrogen 6.8 0.48 MWL 4.79 2.1 97 90-110 3 10 OafCh 4" 003 - Samp Blank (4L39003-BLKl) Prepared: 12/19/2014 10:52 Analyzed: 12122/2014 13:56 Spike Source %REC kpb Anah[4e Result Ha0 PQl Ualfa Lend goNft %REC Umb RPD Limit d9W. Phosphorus 0.025 u 0.to mglL LCB (4L3900343Sl) Prepared: 12/19/201410:52 Analyzed: 12/22/2014 13:58 Spike Source %REC RPD Anahtm Bait$ Ha0 ML Units Level BaW t %REC Nmbs RPD 1f110 notes Phosphorus 1.6 0.10 mg/L 1.60 49 W120 FINAL ThIS report relates ,niy to the Sample as =04A d by the labaratury, and may Only be reproduced in rul. Paps 9 or 11 wwwAnoolabs.00m QUALITY CONTROL DATA (laas al CbemWy Parameters -Quality Control Bated+ 4110= -'raise - CwWnrned Matrix Spike (41.19003-MSi) Prepared: 12/19/2014 10:52 Melyzed: 12/27/2014 14:01 Source: C415291-01 Spike Source %REC RPD �nabda BEBIIt EIM PQL UjMb Leval $gaft %REC lMIM RPD Lwa Motu Phosphorus 1.4 0.10 M91L 0.640 0.78 101 80.120 Mabft Spike Dup (41.19003-MSD1) Prepared: 12/19/2014 10:52 ArmWed: 12/22/2014 14:03 Source: C4152e1-01 Spike Source %REC RPD AnEhSE BMWH 9dd 201 Ilnlia Loral gMM %REC i MJ%g RPD UmS l Phosphorus 1.4 0.10 mp/L 0.640 0.78 101 80.120 0.1 25 FUM This report rNaCes ordy to the sample as mWved by the laboft", end may only be reproduced in full. Pages d 11 www.encoU ba mm FLAGS/NOTES AND DEFINMONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. ] . The reported value Is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte Is an estimated value above the calibration range of the Instrument This value is considered an estimate. MILL Method Reporting Umit The MRL Is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content N The analysis indicates the presence of an anatyts for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. B-03 Blank exceeds the method required oxygen depletion of < 0.2 mg/L. QM-05 The spike recovery was outside acceptance limits for the MS and/or MSD due to matrix interference. The LCS and/or LCSD were within acceptance limits showing that the laboratory is in control and the data is acceptable. QM-12 Precision between duplicate samples was outside acceptance limits. FINAL This report relabes only t0 the Sample as IeCNVed tH the laboratory, and may only be reproduced In Nil. Page 10 of 11 ENVIRONMENTAL CONSERVATION LABORATORIES CHAIN -OF -CUSTODY RECORD www.encolabs.corn IDM QnUM FW Dr- 48t0EmKLgffwPWkCori, Suite Ill i 02-A Woodwinft kskmaiad CL Odmlck% FL 32924 JwkwMle. FL 32216-O69 ' ci". "c 775I1 1407)&W6 W14 Fex(407jsw-ss4 (904)29E3007 Fas(9D4)2966M0 (9191467-3M Fa.(919)4C.7.3-315 Paw -L- of Cfiwd Name fr,144 , I. Ar of'r -I Proi41 Nuffter P-*msW An*j— Requested Turnaround Times Nois:Rush requests subjecito aomplaff— by a- twmlv Standard Expedited Due 7 I Z CEI Z 11�4 Lf c� Z C:) -i �j, . / I I Addnm pmro Nwavew CftysTmp f31 k rl), PO P I Bftrg hft 1,10.3op Tel Fax Reporbng CmW S&TOM40 Nan& Ammon jPeav) N lie, Car"d S" Lotawn l To* lone LabL*M159 - Pl.&.IVXbM r� 'o "29/ cem 0 SW W18 ID IFLeld WnWicpfionj ComooDn Date corocim Une ConT I GFab matrix (sm codes; Tow # of GDntanm Sample Comments )e y X X —15Y y --r F Total of Containers Smtj* Kd Prepaied ft QatdTme pAfinw%tw -12- PalrqumhodBy Datarrime am Rmoamd By Oafdfime ConnwftGpwka1 ReponrQ PAW CI&W all PR 's 7 , Cf cvf,CQ iieceivad By Daftrrome FMOrqLabod By Dawr"m I o so a Tomps p1mov k o j- i, c- k4w Recoo AcceptableJ Unacceptable Umm. UW-GF0EB1ftdRK su-5o1 uw-urtnkWQ WaW SE-SM..— t sw-zkffuo& wacoF Ni-vftssw4mw A-Aff o6uuw idetbl wi conwrmnft? VfOOMMUM "Do H+4G1 M41MU3 S+V--734 UD44aEJH 0-UVw (OMDA 0 oommtlltst NoW : AN samples submthad ho ERM Laps are m accordance mite ftC corms and con*U*Ls WOd On OW mmme eg " Wm. arAms print warmer agFeeffmmis exig