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NCS000528_MONITORING INFO_20180815
-----STORNIWATER-DIVISION-CODING-SHEET -- --- PERMIT NO. NLS P0p52$ DOC TYPE ❑FINAL PERMIT f�.. MONITORING INFO ❑ APPLICATION ❑ COMPLIANCE ❑ OTHER DOC DATE 2018 00 15 YYYYMMDD W akW ATERS EDGE ENVIRONMENTAL, LLC 1434 C,HESTER ROAD • RALEIGH, NC 27608 • PHONE 919.219.5820 August 15, 2018 NCDEQ Division of Water Quality Central Files RECEIVED 1617 Mail Service Branch Raleigh, North Carolina 27699-1617 AUG 1 Zla�a CENTRAL FILES Reference: Year 4- Period 2 Stormwater Monitoring Report DWR SECTION Premiere Fibers Facility Ansonville, North Carolina Stormwater Permit No. NCS000528 Waters Edge Job No. 119-21 To Whom It May Concern: We are presenting the stormwater monitoring; report for Year 4- Period 2 in 2018. All results are within required parameters with the exception of Outfall 003 which had benchmark exceedances for pH (5.5 mg/L versus 6-9 mg/L benchmark). We have performed a Tier II inspection and will resampled that location on the next representative event. It is felt that with acid rain, the pH across North Carolina and the remainder of the country is decreasing and is not due to any anthropogenic activities at the site. We have attached the DMR, SDO, and laboratory analytical results -see Appendix A and B). If you have any questions, or if we may be of further assistance, please contact me at prahn Rwatersedaeenv.com or 919.859.9987. Sincerely, Waters Edge Environmental, LLC Phillip L. Rahn President cc: Mr. Dewey Fulton and Mr. Kevin Bowers- Premier Fibers 18-065 STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT Permit Number: NCS 000528 or Certificate of Coverage Number: NCG e SAMPLES COLLECTED DURING CALENDAR YEAR: 2018 (This monitoring report shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) FACILITY NAME Premiere Fibers COUNTY Anson PERSON COLLECTING SAMPLE(S) T. Haynes PHONE NO. 704 826.8321 CERTIFIED LABORATORY(S) Pace Lab # 633 79 O Lab # (SIGNATURE OF PERMITTEE OR DESIGNEE) By this signature, I certify that this report is accurate complete to the best of my knowledge. Part A: Specific Monitoring Requirements Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes ✓ no (if yes, complete Part B) Form SWU-246-112608 Page 1 of 2 Part B: Vehicle Maintenance Activity Monitoring Requirements Outfa!! No - Date" Sample 50450; ` °„, , . _:.. Y : h:.< .. _0055G 00530 '; 004[i0 Total Elow : Total Ra�nfaU' ` Oiir& Grease t� Totals pH`T New Motor"Oils ,:. Collected (if applicatilej:,. v Suspen„ded ; r Uisage r� ano/dd/yr MGf inches., mill `mg71 Units STORM EVENT CHARACTERISTICS - Date 8.2.18� Total Event Precipitation (inches): 4rG440A-6 1. 3 s' Event Duration (hours): N/A (only if applicable — see permit.) (if more than one storm event was sampled) Date NIA Total Event Precipitation (inches): Event Duration (hours): (only if applicable — see permit.) Mail Original and one copy to: Division of Water Quality Attn: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of lines and imprisonment for knowing violations." Signs re of Permittee Date Form SWU-246-112608 Page 2 of 2 Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance on filling out this form, please visit: httn:Hh2o.enr.state.nc.us/su/Forms Doc uments.htm#miscforms Permit No.: I N I C I S{ 0; 0 10 15 12 18 1 or Certificate of Coverage No.: Facility Name: Premiere Fibers County: Anson Inspector: Thomas Haynes Date of inspection: 8.2.18 Time of Inspection: 11:00-12:00/10:30 AM Total Event Precipitation (inches): 1,38 Phone No. 704.826.8321 Was this a Representative Storm Event? (See information below) ® Yes ❑ No Please check your permit to verify if Qualitative Monitoring must be performed during a representative storm event (requirements vary). A "Representative Storm Event" is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no precipitation. By this signature, I certify that this report isaccurateand complete to the best of my knowledge: . ;Z/ (Signature of Permittee or Designee) 1 Outfall Description: OutfallNo. 001-005 Structure (pipe, ditch, etc.) Pipe to Ditch Receiving Stream: Buffalo Creek Describe the industrial activities that occur within the outfall drainage area: Textile Manufacturing 2 Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: Page 1 of 2 S WU-242-1 l 2608 3 Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): No odor noted 4 Clarity: Choose the number which best describes the clarity of the discharge, where I is clear and 5 is very cloudy: 1 O 3 4 5 5 Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where I is no solids and 5 is the surface covered with floating solids: 1 O 3 4 5 6 Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where I is no solids and 5 is extremely muddy: lO 2 3 4 5 7 Is there any foam in the stormwater discharge? Yes No 8 Is there an oil sheen in the stormwater discharge? Yes No 9 Is there evidence of erosion or deposition at the outfall? Yes No 10 Other Obvious Indicators of Stormwater Pollution: List and describe None Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 S WU-242-1 12608 C6Analytical s waw.Pacslabacom August 15, 2018 Mr. Phil Rahn Waters Edge Environmental 1434 Chester Road Raleigh, NC 27606 RE: Project: Premiere Fibers R9-21 Pace Project No.: 92394362 Dear Mr. Rahn: Pace Analytical Services, LLC 265 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Enclosed are the analytical results for sample(s) received by the laboratory on August 03, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNIINELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Clayton McCrickard clayton.mccrickard@pacelabs.com (336)623-8921 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not he reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 15 C8'l k 0121 www.paarlabs.com Project: Premiere Fibers R9-21 Pace Project No.: 92394362 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623.8921 Asheville Certification lDs 2225 Riverside Drive, Asheville, NC 28804 FloridalNELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 VrginiaNELAP Certification #: 460222 Eden Certification IDs 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Wastewater Certification #: 633 North Carolina Drinking Water Certification #: 37738 VrginiaNELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 15 � !a ceAnalytical wirw.peoefabscom Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 SAMPLE SUMMARY Project: Premiere Fibers R9-21 Pace Project No.: 92394362 Lab ID Sample ID Matrix Date Collected Date Received 92394362001 Outfaii 001 Water 08/02/18 13:00 08/03/18 13:20 92394362002 Outfall002 Water 08/0211813:15 0810311813:20 92394362003 Outfall003 Water 08102/1813:30 0810311813:20 92394362004 Outfail004 Water 08/0211813:45 08/0311813:24 92394362005 Outfall005 Water 08102/1814:00 08/0311813:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 15 IeAnalximl e wwW:psoolwa om 0 SAMPLE ANALYTE COUNT Project: Premiere Fibers R9-21 Pace Project No.: 92394362 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92394362001 Outfall 001 SM 2540D-2011 NMH 1 PASI-E SM 4500-H+B-2011 RAY 1 PASI-E SM 5220D-2011 GC 1 PASI-A 92394362002 Outfall 002 SM 2WD-2011 NMH 1 PASI-E SM 4500-H+B-2011 RAY 1 PASI-E SM 52200-2011 GC 1 PASI-A 92394362003 Outfall 003 SM 254OD-2011 NMH 1 PASI-E SM 4500-H+B-2011 RAY 1 PASI-E SM 522OD-2011 GC 1 PASI-A 92394362004 Outfall 004 SM 25400-2011 NMH 1 PASI-E SM 4500-H+8-2011 RAY 1 PASI-E SM 5220D-2011 GC 1 PASI-A 92394362006 Outfall 005 SM 2WD-2011 NMH 1 PASI-E SM 4500-H+8-2011 RAY 1 PASI-E SM 52200-2011 GC 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC, Page 4 of 15 PacoAnalyttcal Services, LLC aceARalytrcal • 205 East Meadow Road - Suite A Eden, NC 27288 www.ps awmcom (336)623-8921 ANALYTICAL RESULTS Project: Premiere Fibers R9-21 Pace Project No.: 92394362 Sample: Outfall 001 Lab ID: 92394362001 Collected: 08/02/18 13:00 Received: 08/03/18 13:20 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 254OD-2011 Total Suspended Solids 2.8 mg1L 2.5 2.5 1 08106/18 10:11 4500H+ pH, Electrometric EDN Analytical Method: SM 4500-H+B-2011 pH at 25 Degrees C 6.0 Std. Units 1.0 0,10 1 08/03/18 1&05 H3,1-16 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 52200-2011 Chemical Oxygen Demand NO mg1L 25.0 12.5 1 08/06/18 17:00 08/07/18 17:00 Sample: Outfall 002 Lap ID: 92394362002 Collected: OB102118 13:15 Received: 08/03/18 13:20 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 25401) Total Suspended Solids Analytical Method: SM 254OD-2011 Total Suspended Solids ND mg1L 2.5 2.5 1 08/06/18 10:11 4500H+ pH, Electrometric EDN Analytical Method: SM 4500-H+B-2011 pH at 25 Degrees C 6.3 Std, Units 1.0 0.10 1 08/03/18 15:11 H3,1-16 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Chemical Oxygen Demand NO mg1L 25.0 12.5 1 08/06/18 17:00 08/07/18 17:00 Sample: Outfall 003 Lab ID: 92394362003 Collected: 08/02/18 13:30 Received: 08/03/18 13:20 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 2640D Total Suspended Solids Analytical Method: SM 254OD-2011 Total Suspended Solids 10.1 mglL 2.5 2.5 1 08/06/18 10:12 4500H+ pH, Electrometric EDN Analytical Method: SM 4500-H+B-2011 pH at 25 Degrees C 5.5 Std. Units 1.0 0.10 1 08/03/18 15:19 H3,H6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Chemical Oxygen Demand NO mg1L 25.0 12.5 1 08/06/18 17:00 08/07/18 17:00 Sample: Outfall 004 Lab iU: 92394362004 Collected: 08102118 13:45 Received: 08103118 13:20 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 2640D Total Suspended Solids Analytical Method: SM 254OD-2011 Total Suspended Solids 24.6 mg1L 2.5 2.5 1 08/06/18 10:12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08115/2018 01:53 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 15 cemalyiiml' wwwpa ebucom ANALYTICAL RESULTS Project: Premiere Fibers R9-21 Pace Project No.: 92394362 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: Outfall 004 Lab lD: 92394362004 Collected: 08/02/18 13:45 Received: 08/03/18 13:20 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 4500H+ pH, Electrometrlc EDN Analytical Method: SM 4500-H+B-2011 pH at 25 Degrees C 6.3 Std, Units 1.0 0,10 1 08/03/18 15:23 H3,1-16 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Chemical Oxygen Demand 37.9 mg1L 25.0 12.5 1 08/06/18 17:00 08/07/18 17:00 Sample: Outfall 005 Parameters Lab ID: 92394362005 Collected: 08/02/18 14:00 Report Results Units Limit MDL OF Received: 08103118 1120 Matrix: Water Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 254OD-2011 Total Suspended Solids 27.5 mg1L 2.5 2.5 1 08/06/18 14:18 4500H+ pH, Electrometrlc EDN Analytical Method: SM 4500-H+B-2011 pH at 25 Degrees C 6.3 Std. Units 1.0 0.10 1 08/03/18 15:24 H3,1-16 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Chemical Oxygen Demand 28.4 mg1L 25.0 12.5 1 08/06118 17:00 08/07/18 17:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/15/2018 01:53 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 15 Pace Analytical Services, LLC C��aa�i^'� • 205 East Meadow Road - Suite A G 4LJ Eden, NC 27288 www.pacNabo.com (336)623-8921 QUALITY CONTROL DATA Project: Premiere Fibers R9-21 Pace Project No.: 92394362 QC Batch: 423246 Analysis Method: SM 254OD-2011 QC Batch Method: SM 254OD-2011 Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92394362001, 92394362002, 92394362003, 92394362004 METHOD BLANK: 2341681 Matrix: Water Associated Lab Samples: 92394362001, 92394362002, 92394362003, 92394362004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 2.5 08/06/18 10:03 LABORATORY CONTROL SAMPLE: 2341682 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 264 106 90-110 SAMPLE DUPLICATE: 2341683 92394134001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg/L 49.4 96.0 64 5 D6 SAMPLE DUPLICATE: 2341684 92394134002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg/L ND ND 5 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 0811512018 01:53 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 15 aceAnalXiml e www.paodaQacam QUALITY CONTROL DATA Project: Premiere Fibers R9-21 Pace Project No.: 92394362 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 QC: Batch: 423304 Analysis Method: SM 254OD-2011 QC Batch Method: SM 254OD-2011 Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92394362005 METHOD BLANK: 2341976 Matrix: Water Associated Lab Samples: 92394362005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Suspended Solids mg1L ND 2.5 2.5 08/06/18 14:10 LABORATORY CONTROL SAMPLE: 2341977 T Spike LCS LCS % Rec Parameter Units Conc. Result %Rec Limits Qualifiers Total Suspended Solids mg1L 250 274 110 90-110 SAMPLE DUPLICATE: 2341978 Parameter Total Suspended Solids SAMPLE DUPLICATE: 2341979 Parameter Total Suspended Solids 92394043001 Dup Max Units Result Result RPD RPD Qualifiers mg1L 104 97,8 6 5 D6 92394043002 Dup Units Result Result mg1L ND ND Max RPD RPD Qualifiers 5 Results presented on this page are In the units Indicated by the "Units" column except where an attemate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08115/2018 01:53 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 15 i Y aceAnalytica! wwwpecsfeftcom QUALITY CONTROL DATA Project: Premiere Fibers R9-21 Pace Project No.: 92394362 QC Batch: 422991 Analysis Method: SM 4500-H+B-2011 QC Batch Method: SM 4500-H+B-2011 Analysis Description: 4500H+B PH EDEN Associated Lab Samples: 92394362001, 92394362002, 92394362003, 92394362004, 92394362005 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 SAMPLE DUPLICATE: 2340568 92394181001 Dup Max Parameter Units Result Result RPD RPD Qualifiers PH at 25 Degrees C Std. Units 7.9 7.9 0 10 H3,H6 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the resutt. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/15/2018 01:53 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 15 r Pace Analytical Services, LLC CA r� 1, l�n�� 205 East Meadow Road - Suite A Bem l Vr� Eden, NC 27288 wompnobscara (336)623-8921 QUALITY CONTROL DATA Project: Premiere Fibers R9-21 Pace Project No.: 92394362 QC Batch: 423337 Analysis Method: SM 5220D-2011 QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD Associated Lab Samples: 92394362001, 92394362002, 92394362003, 92394362004, 92394362005 METHOD BLANK: 2342126 Matrix: Water Associated Lab Samples: 92394362001, 92394362002, 92394362003, 92394362004, 92394362005 Blank Reporting Parameter Units Result Limit MOL Analyzed Qualifiers Chemical Oxygen Demand mg1L ND 25.0 12.5 08/07/18 16:59 LABORATORY CONTROL SAMPLE: 2342127 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg1L 750 766 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2342128 2342129 MS MSD 92394225002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc, Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand mg/L NO 100 100 102 121 100 119 90.110 17 3 M1,R1 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/15/2018 01:53 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 15 ceAnalytical www,pwetsbs.com Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-6921 QUALIFIERS Project: Premiere Fibers R9-21 Pace Project No.: 92394362 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL- Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyle is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TN accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services -Asheville PASI-E Pace Analytical Services - Eden ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. H3 Sample was received or analysis requested beyond the recognized method holding time. H6 Analysis initiated outside of the 15 minute EPA required holding time. M1 Matrix spike recovery exceeded OC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not pe reproduced, except in full, Date: 08/15/2018 01:53 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 15 a aceAnalytical' zi pecefab:oom QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Premiere Fibers R9-21 Pace Project No.: 92394362 Lab 1D Sample ID QC Batch Method QC Batch 92394382001 Outfall 001 SM 254OD-2011 423246 92394362002 Outfall 002 SM 254OD-2011 423246 92394362003 Outfall 003 SM 254OD-2011 423246 92394362004 Outfall 004 SM 254OD-2011 423246 92394362005 Outfall 005 SM 254OD-2011 423304 92394362001 Outfall 001 SM 4500-H+B-2011 422991 92394362002 Outfall 002 SM 4500-H+B-2011 422991 92394362003 Outfall 003 SM 4500-H+B-2011 422991 92394362004 Outfall 004 SM 4500-H+B-2011 422991 92394362006 Outfall 005 SM 4500-H+B-2011 422991 92394362001 Outfall 001 SM 5220D-2011 423337 92394362002 Outfall 002 SM 5220D-2011 423337 92394362003 Outfall 003 SM 5220D-2011 423337 92394362004 Outfall 004 SM 5220D-2011 423337 92394362005 Outfall 005 SM 5220D-2011 423337 Date: 08/15/2018 01:53 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent or Pace Analytical Services, LLC. Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623.8921 Analytical Analytical Method Batch SM 5220D-2011 SM 5220D-2011 SM 5220D-2011 SM 5220D-2011 SM 5220D-2011 423350 423350 423350 423350 423350 Page 12 of 15 Document Name: .ond1don 6pon Racal Document No 5-CAR-CS-033-Rev.06 Laboratory receiving samples: Asheville ❑ Eden[ Greenwood ❑ Huntersville ❑ Client Name; t uli � ti Project - - Courier: ❑Fed Fat ❑UPS EIUSPsS Clem ❑ Commercial ❑Pace ❑other: Custody Seal Present? QYes Seats Intact? ❑Yes ONO Document Revised, February 7, 2019 Page 1 of 2 lssu€ng AuthorNY: Raleigh❑ Mechanicsville❑ Date/initlals Parson Esamininl contenti:� 0-3-ocd Packing Material: ❑Bubble Wrap ❑Bubble Bags one ❑ Other Blalogical Time Frozen? Thermometer. �} []Yes []No L;W ❑1R Gun It� 61 type of lcr!;t ❑Blue ❑Nana Cooler Temp ('C):._ 4. S^ Correction Factor, Add/Subtract ('Cj " b- (') � Temp should be above freezing to 6'C Cooler TempCorrected C : Samples out of temp criteria. Samples on ice, cooling process has begun USDA Regulated Soll (2"0, water sompie) Did samples orig€na quarantine zone within the United States: CA, IYY, or 5C (check maps)? Did samoesoriglnate from a foreign source (internatispally, ❑Yes 24o indudiegNawa7 and Puerto Ricol7 []Yes( CAain or LUStOdy Present? enYes N* N/A J L Samples Arrived within Hold TIme7 21 es ❑No NIA 1 2. Short NoW Time Analysis (a72 hr.)? Yes ON. N/A 1 3. Rush Turn Around Time Requested? Ely. a C. N A 4. Sufficient Volume? es ONO N/A S. Correct Containers Used? -Pace Containers used? 45es es ❑No No QN/A N/A 6. Containers Intact? es No NIA 7. Dissolved analysis: 5arn lesF€eldFiltered? ❑Yes No ❑N/A 8. Sample Libels Match COC7 -IncludesDatelrime/ID/Analysis Matrix: es Elmo ©N/A 9. Heads ace in VOA Vials (>5-6mm)? Yes No NJA 10. Trip Blank Present? ©Yes ❑No N/A 1! Trip BlankCuslody Seals Present? fires ONo N/A COMMENTS/SAMPLE DISCREPANCY Field Data Required? []Yes []No Lot ID of Olt containers: CLIERT NOTIFICA-VON/RESOULInON Person contacted: Date/Time: Project Manager SCURF Review: Data: 0 D Project Manager SRF Review: f 0ate: �� Page 13 of 15 CHAIN -OF -CUSTODY 1 Analytical Request Document 1!;aceAaalgq!1 The Chain -of -Custody Is a LEGAL DOCUMENT. A9 relevant fields must be concpletedl ccurately. 31 Section A Section a Section C Pago: of 1 Required Client Inlonnalion: Required Project Information: Invoice Infomtaborr. pY• Report To: J Aiteni pn: 2178019 `_ /v AddreSS: VGA Copy To. I Company Name: 4EGULATORY AGENCY ( r NPDES GROUND WATER F INKING WATER 4�" UST (" RCRA F- OTHER EmitlTo: _f PurchaseOrderrNo.: lv Rorerenc : Far: Project Name: Pr Site Location F-I—tedDue DaterrAT: Project Pace ROW 9, Requested ' alysls Filtered (YIN) Section D Matrix Codes z Repieed Crerd k0mmnrim MAT'r7[X r eeoE Drinking Wither OW M U COLLECTED o Preservathres > Water wr water 1MVy m c rrF COMPOWE Este w Z SOWSosd SL SAMPLE ID aI oL - $ �_ er m a q Wipe WP (A-Z 0-9 I r) Air AR p lu a z H Sample, Ma MUST BE UNIQUE Tissue TS O V a 12 F {u V Other OT cr LU O e m 0 m ~ a a <L d O N m t p F DATE TIME f]ATE TIME y _ z z o y race Project koJ Lab I.D. 1 CtLv D o i 2 3 all I I I art cc 3 L- 3 i 1 d DOLL3 i i S. -- 1 s ( l 7 I 9 10 1 11 12 ADDITIONAL COMMENTS RELINOWS ED BY I AFFILIATION DATE TIME ACCEPTED BY i AFFILIATION DATE TIME SAMPLE CONDITIONS , l3.2b y $ 13 N ORIGINAL SAMPLER NAME AND SIGNATURE PRINT Name of SAMPLER: Sit S } SIGNATURE of SAMPLER:DATE Signed 162H E w V u -- V m r {MMIDD -. "I'MmUnt NOW By rigWng U" loan you are acMptine Pam's NET 30 day payment terms one *Wft rg to Im aerges of h.s% per month K arry iteroirns not paW wldj days. I/ / F-ALL-"20rev_07. 1 SMay-2007 Document Name: Document No.: •Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Emptlam: VOA, Coliform, MC, Oil and Grease, DRO/8015 (water) Doc, LLHg "Bottom half of box is to fist number of bottle Revised: February issuing Office m u a v V V A y V Z ¢ tl ►9 QT 18 Ln t9 is a 7 a z 4 Q c S A Z i v Ln 4 a r c QQC z y� d > d Z 7 7 _u u u T3 ,"d Z; .A aE aEE gE S 4 a a. a '� ° E d d t,J O O ,'3n � p. Q J 5 > b y In J E � Q. E}! N�E C©EJ ;, �yyE� t/E� yEr y °: :: ;; {�E E E Eno " yNEy 4lQE� IfQE� `Q�-' E E ^ N ul M r7 N 3 6 3 z A M w, ur m m i� m m m m m 3 a' �a a a a o i o >> (A 0 ; a :c a 12 __..... _ _ ___.. _ _ _ ._._ . _.._..__._.._......._._.._....pH Adjustment.Log.for.Preserved.Samples __ . _-_----....._ .__-- •.---,._. _ _..__...._ Sample ID Type of Preservative pH upon receipt Date preservation adjusted I Time presenndan adjusted Amount of Preservative added Lot if Note: wnenever mere is a orscrepancy anecung Nonn uarmma compuance samples, a copy or mis rorm wm oe sent w cne Norm r.arouna ucne,n rerunauon unite p.e. Out of bold, incorrect greservrt0e, out of temp, In<°mect containers. Page 15 of 16 �TERS EDGE ENVIRONMENTAL, LLC 1434 CHESTER ROAD ► RALEIGH, NC 27608 ► PHONE 919,219.5820 May 3, 2018 NCDEQ Division of Water Quality Central Files 1617 Mail Service Branch Raleigh, North Carolina 27699-1617 Reference: Year 4- Period I Stormwater Monitoring Report Premiere Fibers Facility Ansonville, North Carolina Stormwater Permit No. NCS000528 Waters Edge Job No. R9-21 To Whom It May Concern: RECEIVIED MAY 0 9 2018 CENTRAL F! DWR SECTION We are presenting the stormwater monitoring report for Year 4- Period I in 2018. All results are within required parameters with the exception of Outfall 001 which had benchmark exceedances for TSS (159 mg/L versus 100 mg/L benchmark). We have performed a Tier lI inspection and plan to resampled that location on April 24, 2018 and results, were ND. We have attached the DMR. SDO, and laboratory analytical results -see Appendix A and B). If you have any questions, or if we may be of further assistance, please contact me at prahn a,watersedceenv.com or 919.859.9987. Sincerely, Waters Edge Environmental, LLC Phillip L. Rahn President cc: Mr. Dewey Fulton and Mr. Kevin Bowers- Premier Fibers 18-026 STORMWATER DISCHARGE OUTFALL (SOO) MONITORING REPORT Permit Number: NCS 000528 or SAMPLES COLLECTED DURING CALENDAR YEAR: 2018 Certificate of Coverage Number: NCG (This monitoring report shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) FACILITY NAME Premiere Fibers COUNTY Anson PERSON COLLECTING SAMPLE(S) T. Haynes PHONE NO. (704) 826.8321 CERTIFIED LABORATORY(S) Pace Lab # 633 7' O Lab # (SIGNATURE OF PERNIITI'EE OR DESIGNEE) By this signature, I certify that this report is accurate complete to the best of my knowledge. Part A: Specific Monitoring Requirements .Ou#fall `°D tee ff ^ . '-'7' iToTtalrg Total Collected Rainfall SuspendedSol Solids (TUSS),S.s . y Permit Beech NIA I I00 120 6-9 Lzl� mold�lyr'_ aches nigh mgll . ; Units K 1 3.1.18 See Below 159 ND 6.2 2 3.1.18 ND ND 6.3 3 3.1.18 26.8 ND 6.2 4 3.1.18 16.9 88.0 6.9 5 3.1.18 27.9 107 6.5 1 4.24.18 See Below ND Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes ✓ no (if yes, complete Part B) Form SWU-246-112608 Page 1 of 2 Part B: Vehicle Maintenance Activity Monitoring Requirements outran No. Hate Sample oo sso. ooas3o ooaoo Total Flow Total Rainfall Qil &Grease "'Total pH New Motor Oil Collected (if appllcalile)` ,� _ IF Suspended Usage - �naolddlyr MG - ' ,inches j. MgA mg t Units aUcno ' STORM EVENT CHARACTERISTICS: Date 3.1.1814.24.18 Total Event Precipitation (inches): 0.31 /0.45 Event Duration (hours): N/A (only if applicable — see permit.) (if more than one storm event was sampled) Date NIA Total Event Precipitation (inches): Event Duration (fours): (only if applicable — see permit.) Mail Original and one copy to: Division of Water Quality Attn: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly 'responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." a 206 Signabke of Permittee Date Form SWU-246-112608 Page 2 of 2 4 Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance on filling out this form, please visit: httn:Hh2o.enr,state.ne.us/su/Forms Documents.htm#miscforms Permit No.: IN i C I S� 0.1 0 j o j 512 � 8 or Certificate of Coverage No.: I I I_ I I 1 i i Facility Name: Premiere Fibers County: Anson Phone No. 704.826.8321 Inspector: Thomas Haynes Date of inspection: 3.1.18/4.24.18 Time of Inspection: 11:00-12:00/10:30 AM Total Event Precipitation (inches): 0.31/0.45 Was this a Representative Storm Event? (See information below) ® Yes ❑ No Please check your permit to verify if Qualitative Monitoring must be performed during a representative storm event (requirements vary). A "Representative Storm Event" is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no precipitation. By this signature, I certify that this report is accurate and complete to the best of my knowledge: .;i� �&_ ;Z/- (Signature of Permittee or Designee) 1 Outfall Description: Outfall No. 001-005 Receiving Stream Buffalo Creek Structure (pipe, ditch, etc.) Pipe to Ditch Describe the industrial activities that occur within the outfall drainage area: Textile Manufacturi 2 Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: Light brown Page 1 of 2 S WU-242-1 12608 3 Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): No odor noted 4 Clarity: Choose the number which best describes the clarity of the discharge, where I is clear and 5 is very cloudy: O[ 2 3 4 5 5 Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where I is no solids and 5 is the surface covered with floating solids: 1 Q 3 4 5 6 Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where I is no solids and 5 is extremely muddy: l (D 3 4 5 7 Is there any foam in the stormwater discharge? Yes No 8 Is there an oil sheen in the stormwater discharge? Yes No 9 Is there evidence of erosion or deposition at the outfall? Yes No 10 Other Obvious Indicators of Stormwater Pollution: List and describe None Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 S W U-242-1 12608 aceAnalyti{cale wmpaaelabaoom March 15, 2018 Mr. Phil Rahn Waters Edge Environmental 1434 Chester Road Raleigh, NC 27606 RE: Project: Premiere Fibers Pace Project No.: 92375307 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Dear Mr. Rahn: Enclosed are the analytical results for sample(s) received by the laboratory on March 01, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNIINELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Clayton McCrickard clayton.mccrickard@pacelabs.com (336)623-8921 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not he reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 16 acieAnalximl WWwpaoelabs,rom Project: Premiere Fibers Pace Project No.: 92375307 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28604 Florida/NEIAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 Eden Certification IDs 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certiflcation #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 VrginialVELAP Certification #: 460222 North Carolina Wastewater Certification #: 633 VrginiaNELAP Certification M 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of pace Analytical Services, LLC. Page 2 of 16 Pace Analytical Services, LLC aceAnalytical • 205 East Meadow Road - Suite A Eden, NC 27288 www.pscelehacnrs (336)623-8921 SAMPLE SUMMARY Project: Premiere Fibers Pace Project No.: 92375307 Lab ID Sample ID Matrix Date Collected Date Received 92375307001 OutfallI Water 03/0111812:00 03/01/1816:45 92375307002 Outfall2 Water 03101/1812:15 03101/1816:45 92375307003 Outfall 3 Water 03/01/18 12:30 03/01/18 M45 92375307004 Outfall4 Water 03/01/1812:45 0310111816:45 92375307005 Outfall5 Water 03/01/1813:00 03/01/1816:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 16 Iac ( e Analytical' www.pacwBUCam SAMPLE ANALYTE COUNT !. Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Premiere Fibers Pace Project No.: 92375307 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92375307001 Outfall 1 SM 2540D WCP 1 PAS!-E SM 4500-H+B SAM1 1 PASI-E SM 5220D NAL 1 PASI-A 92375307002 Outfall 2 SM 25400 WCP 1 PASI-E SM 4500-H+B SAM1 1 PASI-E SM 5220D NAL 1 PASI-A 92375307003 Outfall 3 SM 2540D WCP 1 PASI-E SM 4500-H+B SAM1 1 PASI-E SM 5220D NAL 1 PASI-A 92375307004 Outfall 4 SM 2540D WCP 1 PASI-E SM 4500-H+B SAM1 1 PASI-E SM 5220D NAL 1 PASI-A 92375307006 Outfall 5 SM 2540D WCP 1 PASI-E SM 4500-H+B SAM1 1 PASI-E SM 5220D NAL 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 16 r r aceAnalytical www psoewmcam ANALYTICAL RESULTS Project: Premiere Fibers Pace Project No.: 92375307 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623.8921 Sample: Outfall 1 Lab ID: 92376307001 Collected: 03/01/18 12:00 Received: 03/01/18 16:45 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 159 mg1L 3.4 3.4 1 03/02/18 12:24 4500H+ pH, Electrometric EDN Analytical Method: SM 4500-1-1+13 pH at 25 Degrees C 6.2 Std. Units 1.0 0.10 1 03102/1810:00 H6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand NO mg1L 25.0 12.5 1 03/14/18 18:06 Sample: Outfall 2 Lab ID: 92375307002 Collected: 03/01/18 12:15 Received: 03/01/18 16:45 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2640D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids NO mg/L 6.2 6.2 1 03/02/18 10:38 4500H+ pH, Electrometric EDN Analytical Method: SM 4500-H+B pH at 25 Degrees C 6.3 Sid. Units 1.0 0.10 1 03/02/18 10:00 H6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand NO mg1L 25.0 12.5 1 03/14/18 18:06 Sample: Outfall 3 Lab ID: 92375307003 Collected: 03/01/18 12:30 Received: 03/01/18 16:45 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 26.8 mg/L 6.2 6.2 1 03/02/18 12:24 06 4500H+ pH, Electrometric EDN Analytical Method: SM 4500-H+B pH at 25 Degrees C 6.2 Std. Units 1.0 0.10 1 03/02/18 10:00 H6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand NO mg/L 25.0 12.5 1 03/14/18 18:06 Sample: Outfall4 Lab ID: 92375307004 Collected: 03/01/18 12:45 Received: 03/01/18 16:45 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Quat 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 16.9 mg1L 5.2 5.2 1 03/02/18 12:25 Date: 03/15/2018 04:34 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 16 IceAnalytical' www.paoelaftcom ANALYTICAL RESULTS Project: Premiere Fibers Pace Project No.: 92375307 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: Outfall4 Lab ID: 92375307004 Collected: 03/01/18 12:45 Received: 03/01/18 16:45 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 4500H+ pH, Electrometrlc EDN Analytical Method: SM 4500-H+B pH at 25 Degrees C 6.9 Std. Units 1.0 0.10 1 03/02/18 10:00 H6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 88.0 mglL 25.0 12.5 1 03/14/18 18:06 Sample: Outfall 5 Lab lD: 92375307005 Collected: 03/01/18 13:00 Received: 03/01/18 16:45 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 27.9 mg/L 8.6 8.6 1 03/05/18 13:38 4500H+ pH, Electrometric EDN Analytical Method: SM 4500-H+B pH at 25 Degrees C 6.5 Std. Units 1.0 0.10 1 03/02/18 10:00 H6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 107 mg/L 25.0 12.5 1 03/14/18 18:06 Date: 03/1512018 04:34 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Ul, without the written consent of Pace Analytical Services, LLC. Page 6 of 16 aceAnalytical www.pac labs cunt Project: Premiere Fibers Pace Project No.: 92375307 QC Batch: 400423 QC Batch Method: SM 2540D Associated Lab Samples: 92375307002 METHOD BLANK: 2220595 Associated Lab Samples: 92375307002 Parameter Units Total Suspended Solids mglL QUALITY CONTROL DATA Analysis Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Matrix: Water Blank Reporting Result Limit MDL Analyzed ND 2.5 2.5 0310211810:33 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Qualifiers LABORATORY CONTROL SAMPLE: 2220596 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg1L 250 232 93 90-110 SAMPLE DUPLICATE: 2220597 92376071001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mglL ND ND 5 SAMPLE DUPLICATE: 2220598 92375307002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg1L ND ND 5 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 0311512018 04:34 PM without the written consent of Pare Analytical Services, LLC. Page 7 of 16 ac"Analyiical. wwwpacebtutoom QUALITY CONTROL DATA Project: Premiere Fibers Pace Project No.: 92375307 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 QC Batch: 400479 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92375307001, 92375307003, 92375307004 METHOD BLANK: 22209V Matrix: Water Associated Lab Samples: 92375307001, 92375307003, 92375307004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Suspended Solids mglL ND 2.5 2.5 03/02118 12:20 LABORATORY CONTROL SAMPLE: 2220918 Parameter Units Total Suspended Solids mg/L SAMPLE DUPLICATE: 2221068 Parameter Units Total Suspended Solids mg1L SAMPLE DUPLICATE: 2221069 Parameter Total Suspended Solids Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 232 93 90-110 92375071004 Dup Max Result Result RPD RPD Qualifiers ND ND 5 92375307003 Dup Max Units Result Result RPD RPD Qualifiers mg/1- 26.8 14.2 61 5 D6 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/1512018 04:34 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 16 � a ceAnalytrcal e wwwpacslabscom QUALITY CONTROL DATA Project: Premiere Fibers Pace Project No.: 92376307 QC Batch: 400672 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92375307005 METHOD BLANK: 2222076 Associated Lab Samples: 92375307005 Parameter Units Total Suspended Solids mg1L LABORATORY CONTROL SAMPLE: Parameter 2222077 Units Total Suspended Solids mglL SAMPLE DUPLICATE: 2222078 Parameter Units Total Suspended Solids mglL SAMPLE DUPLICATE: 2222079 Parameter Units Total Suspended Solids mglL Matrix: Water Blank Reporting Result Limit ND 2.5 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 MDL Analyzed Qualifiers 2.5 03/05/18 13:33 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 234 94 90-110 92375211001 Dup Max Result Result RPD RPD Qualifiers 320 351 9 5 06 92375202001 Dup Max Result Result RPD RPD Qualifiers 43.7 46.9 7 5 D6 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/15/2018 04:34 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 16 CeAnalytfcal www.pscefabaoom QUALITY CONTROL DATA Project: Premiere Fibers Pace Project No.: 92375307 QC Batch: 400451 Analysis Method: SM 4500-H+B QC Batch Method: SM 4500-H+B Analysis Description: 4500H+B pH EDEN Associated Lab Samples: 92375307001, 92375307002, 92375307003, 92375307004, 92375307005 SAMPLE DUPLICATE: 2220705 92375307001 Dup Max Parameter Units Result Resuit RPD RPD pH at 25 Degrees C Sid. Units 6.2 6.3 1 { Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Qualifiers 10 HIS Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the nght of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/15/2018 04:34 PM without the written consent of Pace Analytical Services, LI.C. Page 10 of 16 aceAnalytical wwwpatxfabscom QUALITY CONTROL DATA Project: Premiere Fibers Pace Project No.: 92375307 QC Batch: 401883 Analysis Method: SM 5220D QC Batch Method: SM 5220D Analysis Description: 5220D COD Associated Lab Samples: 92375307001, 92375307002, 92375307003, 92375307004, 92375307005 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27286 (336)623-8921 METHOD BLANK: 2229021 Matrix: Water Associated Lab Samples: 92375307001, 92375307002, 92375307003, 92375307004, 92375307005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand mg1L ND 25.0 12.5 03/14/18 18:06 LABORATORY CONTROL SAMPLE: 2229022 Spike Parameter Units Cone. Chemical Oxygen Demand mg1L 750 LCS LCS % Rec Result % Rec Limits Qualifiers 762 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2229023 2229024 MS MSD 92375897001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand mg1L ND 100 100 116 102 107 93 90-110 13 3 R1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2229025 2229026 MS MSD 92376112001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand mg1L 51.0 100 100 154 154 103 103 90-110 0 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/15/2018 04:34 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 16 Pace Analytical Services, LLC CeAna ical 205 East Meadow Edenn,, NC 27288 fi � ro*416&=" (336)623-8921 QUALIFIERS Project: Premiere Fibers Pace Project No.: 92375307 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL-Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-E Pace Analytical Services - Eden ANALYTE QUALIFIERS 06 The precision between the sample and sample duplicate exceeded laboratory control limits. H6 Analysis initiated outside of the 15 minute EPA required holding time. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/15/2018 04:34 PM without the written consent of Pace Analytical Services, LLC, Page 12 of 16 aceAnalytiM/6 www,pwsbba.corn QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Premiere Fibers Pace Project No.: 92375307 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92375307001 Outfall 1 SM 2540D 400479 92375307002 Outfall 2 SM 2540D 400423 92376307003 Outfall 3 SM 2540D 400479 92376307004 Outfall 4 SM 2540D 400479 92375307006 Outfall 5 SM 25400 400672 92376307001 Outfall 1 SM 4500-H+B 400451 92376307002 Outfall 2 SM 4500-1-1+8 400451 92376307003 Outfall 3 SM 4500-1-1+13 400451 92376307004 Outfall 4 SM 4500-H+B 400451 92376307006 Outfall 5 SM 4500-H+B 400451 92376307001 Outfall 1 SM 5220D 401883 92375307002 Outfall 2 SM 5220D 401883 92375307003 Outfall 3 SM 5220D 401883 92375307004 Ouffall 4 SM 52200 401883 92375307005 Outfall 5 SM 5220D 401883 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/15/2018 04:34 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 16 Document Name: Document Revised: February 7, 3 Condition U on Recei t(SCUR) PaLe 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 pace Carolinas Qualfty Office Laboratory receiving samples: Asheville ❑ Eden Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville[] aleq Name: Wf, Project �YL, L� ✓r r_�_l� Courier: ❑Fed Ex ❑UPS ' ❑USPS �ZycHent ❑ Commercial ❑Pace Other Custody Seal Present? ❑Yes t19 . Seals Intact? Dyes ❑No Packing Material: []Bubble Wrap ❑Bubble Bags ZNone ❑ Other Biological Tissue Frozen? P Thermometer. ❑Yes ❑No []N/A❑IR Gun fi60001 Type of lce: kTW'et ❑Blue ❑None Cooler Temp ('C): Correction Factor: Add/Subtract ('C) Temp should be above freezing to 6'C Cooler Temp Corrected ('C): ❑Samples out of temp criteria. Samples on Ice, cooling process has begun USDA Regulated Soil (❑ N/A, water sample) Did samples originate In a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, rites nNo Indodina Hawaii and Puerto Rkol? rlYes riNo Comments/Discrepancy: Chain of Custody Present? Yes ©No ONIA 1 1. Samples Arrived within Hold Time? Yes [:]No ONJA 1 2. Short Hold Time Analysis M hr. Yes Na N/A 3, Rush Turn Around Time Requested? OYes Na N/A 4. Sufficient Volume? UfYes ON. ONJA S. Correct Containers Used? -Pace Containers Used? es Yes ON. ❑No ❑NJA NJA 6. Containers Intact? Yes []No N//A 7, Dissolved analysis: Samples Field Filtered? ElVes Na N A 8. Sample Labels Match COC? -Includes Date/time/ID/Analysis Matrix: es ONO ❑N/A 9. Headspace in VOA Vials (>5-6mm)? Qyes ONo A 10. Trip Blank Present? Trip Blank Custody Seals Present? Oyes Oyes ONO []No IA CJ41A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTTON Field Data Required? ❑Yes []NO Person contacted: Date/nme: Project Manager SCURF Review: V Date: 1 ~( Project Manager SRF Review: Date: t _-.. _...- ... _._. _... Page 14 of 16 to CHAIN -OF -CUSTODY 1 Analytical Request Document -' The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section A Section B section C g� Jo g� 96ed siaumv0.1 VajjooW •dwal;o lno 'anpe"asajd 130Ji02ul'pl04 Jo 1n0 ,oA wmun U013 anllla1 wNwin euFEOJen u1JON a41 of 3uas aQ IEI+e uuol slyl to Adoa a `saldwes aauelldLaw ellllOJe] El1JoN 9uElo23le A3ued2pslp a sl maul jahaua4AA :alaN 103 L poppe anµeA0994 Jo lunowy I palsnfpe uol7elumsaid awl I palrnfpr uollmarard ales 1djam uodn Hd aallewSnJd Jo vdA11 al aldwes saldures pa►uasasd Jo) 301 3uau►lsnfpd Hd ■moons 060 M kE Skins 11 ME 0 0 1 MEN 164L MEN ONE nommosookikikinkiL On 000 011110111M '16 164L NOOSE Monsoon OEM 1IL40 0101101 ME NO Nomem M0 EMEN no so m 0 M 0 Ll E M 0 0 0 0 0 0 0 S S Eq 0 kil Ml 0 S D S E 0 0 0 M 0 Mmmm 0 0 MEN, 61, 0 m m OEM IN Na 0 so 0 Monsoons 0400 001 ski EMEND Sk NEEM IN smommossommon 11 ki k1k 10 D Z 40 1811841 SICZ '4 Aje-gad :paSIAay lua Wn7Q a J, W A hb+ N A Nb O O 4 D T r 3 3 r r r b v r r CN Q = m z C a n 7 3 A Z 2 D N Z D m in O ? 9 9 ° O ¢ x 2 tNif W 0 7 yVq �pn A D = 2 n ^ N z 2 N Z 2 ry2 12mp z N �, z c „�,, }, _ f� V a z D z z D 38 D D h � Q elaoq }o jaqulnu pil o; sl xoq jo 11e4 wouog** SH19'�OU ($93 M) STUB/CV0'asealD pug 110'DOl'U"01ll* bOA:ruohdv=q Il� -saldules uoflemasaid jo; 98uea wue3dwn OW u1411m pue PRAJaA (M= 1�1 # PDfOJd $1 u011eulJ01439p JO/pue Hd p xoq;o jje4 do; VBLU 1pa4), sa•�aa-ssro�a-av�•a :'ON luawnaoa '„ �,P� �4 brDS� iaaaa ua n uapjpu03 el oars . :aweN luawrooO L � aceAnalytical e wwwPKetebs.carn April 27, 2018 Mr. Phil Rahn Waters Edge Environmental 1434 Chester Road Raleigh, NC 27606 RE: Project: Premiere Fibers Pace Project No.: 92382133 Dear Mr. Rahn: Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Enclosed are the analytical results for sample(s) received by the laboratory on April 25, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Clayton McCrickard clayton.mccrickard@pacelabs.com (336)623-8921 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 aceAnalytical" www.perxr'abcGorn Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)823-8921 CERTIFICATIONS Project: Premiere Fibers Pace Project No.: 92382133 Eden Certlflcatlon IDS 206 East Meadow Road Suite A, Eden, NC 27288 North Carolina Wastewater Certification #: 633 North Carolina Drinking Water Certification #: 37738 VirginiaNELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 , y acemaIxical WmPacakftcom SAMPLE SUMMARY Project: I Premiere Fibers Pace Project No.: 92382133 Lab ID Sample ID Matrix Date Collected Date Received 92382133001 Outliall 001 Water 04/24118 11:30 04/25/18 09:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623.8921 Page 3 of 11 aceAnalytical WWW..parblsbacom SAMPLE ANALYTE COUNT Project: Premiere Fibers Pace Project No.: 92382133 P Pace Analy0cal Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Analytts Lab ID Sample ID Method Analysts Reported Laboratory 92382133001 Outfall 001 SM 2540D RAY 1 PASI-E REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 11 G! H aceAnalWale www.pW84bas0m ANALYTICAL RESULTS Project: Premiere Fibers Pace Project No.: 92382133 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: Outfall 001 Lab lD: 92382133001 Collected: 04/24/18 11:30 Received: 04/25/18 09:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids ND mg1L 2.5 2.5 1 04/25/18 13:54 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2018 12:44 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 11 ac"Analytical" rww.pacatsh, oom QUALITY CONTROL DATA Project: Premiere Fibers Pace Project No.: 92382133 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 QC Batch: 407866 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92382133001 METHOD BLANK: 2263021 Matrix: Water Associated Lab Samples: 92382133001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Suspended Solids mg1L ND 2.5 2.5 04/25/18 13:46 LABORATORY CONTROL SAMPLE: 2263022 Parameter Units Total Suspended Solids mg]L SAMPLE DUPLICATE: 2263023 Parameter Total Suspended Solids SAMPLE DUPLICATE: 2263024 Parameter Total Suspended Solids Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 250 258 103 90-110 92382043002 Dup Units Result Result mg1L 157 152 92382019001 Dup Units Result Result mg1L 746 437 Max RPD RPD Qualifiers 3 5 Max RPD RPD Qualifiers 52 5 D6 Results presented on this page ere In the units Indicated by the -Units" column except where an alternate unit to presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2018 12:44 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 11 ceAnalytical Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8821 QUALIFIERS Project: Premiere Fibers Pace Project No.: 92382133 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL- Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270, The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute, LABORATORIES PASI-E Pace Analytical Services - Eden ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. REPORT OF LABORATORY ANALYSIS This report shag not be reproduced, except in full, Date: 04/27/2018 12:44 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 11 ceAnalytric'al wwrvpecefebs.cam QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Premiere Fibers Pace Project No.: 92382133 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Analytical Lab ID Sample 10 QC Batch Method QC Batch Analytical Method Batch 92382133001 Outfall 001 SM 2540D 407866 Date: 04/27/2018 12:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, exoept in fuU, without the written consent of Pace Analytical Services, LLC. Page 8 of 11 Document Name: Document Revised: February 7, 2018 Document NO.: Laboratory receiving samples: Asheville ❑ Ede at Greenwood ❑ Issuing Autharlty: Huntersvllle ❑ Raleigh❑ Mechanicsville[] Client Name: Project Courier: ed Fx UPS USPS Client Commercial ❑pace [3Other: Custody Seal Present? []Yes 4N6'.' Seals Intact? []Yes [3No Packing Material: []Bubble Wrap E]Bubble Sags [3 ane ] Other Thermometer. s� n (r) rj t lres �+.� urn ❑ A Gun Iad Type ar ice: et QEilue of),. Cooler Temp (*Q: - ----- �^--i- Correction Factor: Add/Subtract ('Cj `—"— Temp should be above Freezing to VC Cooler Temp Corrected ('C): _ Osamples out of temp criteria. Samples on ice, coaling process has begun USDA Regulated Soil (❑ N/A, water sample] Did sa mples oil mate in a quarantine zone within the United States: CA, NY, or SC {check maps)7 old samples originate from a foreign source (internationally, e7 r IYRS INn 0-1- m. Fi is anA Ouorm Riml? r1Vea r1Nn Cammersts Diacr nty: Chain of Cost Present? es Na N/A L Sam lee Arrived within Hold Time? V. Na NIA 2. Shari Hold Time Analis (<72 hr.)? Yes No NIA 3. Rush Turn Around Time Requested? Yes ONIA 4. Sufficient Volume? es No ON A S. Correct Containers Used? -Pace Containers used? e' ❑No ON. QN/A N/A S. Containers Intact? res NoON/1k. 7, Dissolved anaiysls: Sa imples Field Filtered? QY. ON. N A S. Sample Labels Klatch COC? -Indudes oate/Time/ID/Anafysis Matrix: Yes ' "'% 4- ONO ©H/A 9. Heads ate In VOA Vials O"mm)? ❑Yes QNa % N JN 10. Trip Stank Present? Trip Blank Custodt Seals Present? ❑Yes 0Yes ONO No N/A f rINIA 11. COMMENTS/SAMPLE DISCREPANCY / Field Data Required? ❑Yes ONO Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Date/Time: Project Manager SCURF Review: Date: ✓ Project Manager SAF Review: Date: Page 9 of 11 CHAIN -OF -CUSTODY / Analytical Request Document 2ax:if afyAal - The Chain of-Custady is a LEGAL DOCUMENT- All relevant fields must be completed accurately,o rrw.mntahs.mnt Section A Suction B 5ettian G page: o1 Requtred Client Information; Required Project Iniarmatm: IrmoiceWometiom, CDmP Report To: Attention: r 2228184 / Add [aC. Y TO: r Comte Nam' REGULATORY AGENCY Addrr ( NPDES r GROUND WATER I— DRINKING WATER `-UST r RCRA j✓r-OTHER Erroll To: l Purchase Order ND.: / / Pace Ouse Retcra>ca: Phone: Fax: lorcied Name: / axe PrDjaa w Site Location SMarloTATE: 1 Requested Due DatelfAT: Project Number: Q 7 Paco Pmfns u: _itequested Anaiyisis Filtered (YIN) Section O Matrix COdea : z Requir"CfieraW minim MATRD((�OOE 9 O COLLECTED Preservatives .F- - Orl" Water DW n z later WT U Praste Water W P W Product START E eNCOPRAB oduct soiltslosd w SAMPLE ID l� OL .5 CC fAx.09l;) Air AR 0 Sample IDS M1JST BE UNIQUE Tissue TS 0 w a it � C H '0}' m a t U Other OT U r - cc 0. a U N i O a S z z i O DATE TIME PATE TIME Cr Pace Project Nod Lab I.D. 41 k2 3 4 5 - 8 7 S 16 11 12 ADDITIONAL COMMENTS RELINf21.111SHED BY f AFFILIATION DATE 76AF ACCEPTED BY f AFFILIATION DATE TIME SAMPLE CONDITIONS SAMPLER NAME AND SIGNATURE F ° ORIGINAL 8 PRINT Nano of SAMPLER: - �. a - DATE Sil3rrod SIGNATURE of SAMPLER: `—' v m .r n MlDDlYYi: GO ti W m a •WVW am Nato: By soling this tom You are aceep" Paao NET. 30 day pWonem ferma and &W** rq to tale drergex d 1.S% per month fob tnronces nW Paid wits- t / i" F-ALE-0-020rev.07, 15-May-2007 a6ed -siauleium 17iJJp7tq 'dwai )o ono 'enpeeJosaJd jiaJJwu1 'Pfoit10 ino i uUoN all of cues aq 11w wJoi siVa fo Ado] a 'faidwes metidwoo SUROJ6] LIVON 2UI12DUB huedoopo a s1 ajow wousum mow p 301 PePPi anlie>1JUDAd l0lunourV PeisniPe uageuasald auryl Paisn{Pe uonewasoid aie4 idle»J uodn lid OARCUM-Id 0 eddl 01 aldmas saidwe$ Pa►uasaM ao; 901 juawasn(pb yd 6 8 L f s [\\N I I � I-\\[\ N I NNNN I I 4 N I 1\�t N I N I j v y 3 r r n 3 3 a a g Q s I~ c � m n 9 G 7 N n vi ; A u' D p !p A Ti' yy rp Aj Q D D Y ai»oq jo aagtunu isp a3 s{ xoq 10 llay ui0408,• RH77'700 (JagM) SI48/ob0'aseaJg Pue 110 70I'WXYno3'V0A' uopda a� •saidwes �60% a0' •�afl and=_ 3 _ WHO. uoijamosaid jo) aluej aaueydom aye U19MM PUB PalllJan a= era - sl uoueulioIyaP �o/Aue H d p xoq; 1194 doh r�euaso* Apotonv Fulnssl I:'oh auownjoa z;o j dud vn,7s 7 .,ag uo umopuo] BJoZ'L Aaenagad :P;KIAUV ILMWtY7od .OWL ivawmop V WATERS EDGE ENVIRONMENTAL, LLC 34 CHESTER ROAD • RALEIGH, NC 27608 • PHONE 919.219.5820 November 3, 2017 NCDEQ Division of Water Quality Central Files 1617 Mail Service Branch Raleigh, North Carolina 27699-1617 RFt „1=111F_D JAN 02 2018 DIN" 3ECTUrl 1i`'r4RIMATIW PRQCESSI`€G MR Reference: Year 3- Period 2 Stormwater Monitoring Report Addendum Premiere Fibers Facility Ansonville, North Carolina Stormwater Permit No. NCS000528 Waters Edge Job No. R9-21 To Whom It May Concern: We are presenting the stormwater monitoring report for Year 3- Period 2 in 2017. All results are within required parameters with the exception of Outfall 005 which had benchmark exceedances for TSS (115 mg/L versus 100 mg/L benchmark) and COD (176 mg/L versus 120 mg/L benchmark). We have performed a Tier II inspection and have resampled that location. The TSS results were now below the 100 mg/L benclunark (24,7 mg/L); however, the COD was even more elevated at 310 mg/L versus its benchmark at 120 mg/L. We believe this is due to construction activities which should considerable subside during the next sampling period. We have attached the DMR, SDO, and laboratory analytical results -see Appendix A and B). If you have any questions, or if we may be of further assistance, please contact me at rahn watersed eenv.com or 919.859.9987. Sincerely, Waters Edge Environmental, LLC Phillip L. Rahn President cc: Mr. Dewey Fulton and Mr. Kevin Bowers- Premier Fibers 17-063 w STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT Permit Number: NCS 000528 or SAMPLES COLLECTED DURING CALENDAR YEAR: 2017 Certificate of Coverage Number: NCG (This monitoring report shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) FACILITY NAME Premiere Fibers COUNTY Anson PERSON COLLECTING SAMPLE(S) T. Haynes PHONE NO. (704) 826.8321 CERTIFIED LABORATORY(S) Pace Lab # 633 Lab # (SIGNATURE OF PERNIITTEE OR DESIGNEE) By this signature, I certify that this report is accurate complete to the best of my knowledge. Part A: Specific Monitoring Requirements ,Oei#fall Noyes -"°•. aar-`3.0 1 :Date _ mple M .._re'.S^,4,L`�.� - _ - giMm M50 EKE,�` :_ gam-` z n€ 2.1^`»'«C'_ 3'm _To[ 1� SSollds,c�-N`�Z.'-i:x-A. mow. v.smn,w.,wa.\yT.... �::C©D .�.-_ ^S. - pH� - .gym. F,ac.. can't -rye '�,�. - .. RAM `1-T. g .. �- 1 9.12.17 See Below 39.2 ND 6.5 2 9.12.17 ND ND 6.6 3 9.12.17 5.3 ND 6.5 4 9.12.17 ND 68.0 7.2 5 9.12.17 115 176 6.8 5 10.23.17 24.7 310 6.8 Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?, yes ✓no (if yes, complete Part B) Farm SWU-246-112608 Page l of 2 r Part B: Vehicle Maintenance Activity Monitoring Requirements :Ontfall�'.. Bate ��- � • 50o5D -...,t - _ � � V:, ...� ;00556 � �`-1105313� -"' 0o4Ulf � t.�-�T� �,,:�`- No Sample; GTotal>Flow Total Rainfall Od& GreaseTo#al;�� pH ` r New-l4iotor�{?hl' ,Collected - (if appl�cabie) ;SospeadedUsage+ STORM EVENT CHARACTERISTICS: Date 9.12.17/10.23.17 Total Event Precipitation (inches): 0.2310.34 Event Duration (hours): NIA (only if applicable — see permit_) (if more than one storm event was sampled) Date N/A Total Event Precipitation (inches): Event Duration (hours): (only if applicable — see permit_) Mail Original and one copy to: Division of Water Quality Attn. Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Sign re of Permittee ate Form SWU-246-112608 Page 2 of 2 i Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance on filling out this form, please visit, http://h2o.enr.state.ne.us/su/Forms Documents.htm#miscforms Permit No.: � W C S 10 10 1 0� 5 1 2 L or Certificate of Coverage No.: I I ) J I 4 j Facility Name: Premiere Fibers County: Anson Phone No. 704.826.8321 Inspector: Thomas Haynes Date of Inspection: 9.12.17/10.23.17 Time of Inspection: 11:00-12:00 Total Event Precipitation (inches): 0.23/0.34 Was this a Representative Storm Event? (See information below) ® Yes ❑ No Please check yo ur perm it to verify if Qualitative Monitoring must he performed during a representative storm event (requirements vary). A "Representative Storm Event' is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred.,- A single storm event may contain up to 10 consecutive hours of no precipitation. By this signature, I certify that this report is accurate and complete to the best of my knowledge: V2 (Signature of Permittee or Designee) 1 Outfall Description: Outfall No. 001-005 Receiving Stream: Buffalo Creek Structure (pipe, ditch, etc.) Pipe to Ditch Describe the industrial activities that occur within the outfall drainage area: Textile Manufacturing Z Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: Light brown Pagel of 2 S WU-242-112608 3 Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): No odor noted 4 Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: 1 0 3 4 5 5 Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is'the surface covered with floating solids: 1 2O 3 4 5 6 Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy: lO 2 3 4 5 7 Is there any foam in the stormwater discharge? Yes No 8 Is there an oil sheen in the stormwater discharge? Yes No 9 Is there evidence of erosion or deposition at the outfall? Yes No 10 Other Obvious Indicators of Stormwater Pollution: List and describe None Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. 0 Page 2 of 2 SWU-242-112608 aceAnalytical e wxm•Aa4vpleds.com i September 22, 2017 Mr. Phil Rahn Waters Edge Environmental 1434 Chester Road Raleigh, NC 27606 RE: Project: Premiere Fibers Pace Project No.: 92354922 Dear Mr. Rahn: Pace Analytical Services, LLG 205 East Meadow Road - Suite A Enclosed are the analytical results for sample(s) received by the laboratory on September 12, 2017. The results relate only to the samples included in this report. Results reported h erein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me Sincerely, Clayton McCrickard clayton.mccrickard@pacelabs.com (336)623-8921 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, LLC. Eden, NC 27288 (336)623.8921 Page 1 or 15 I eAnalytical wwwpacelebs.com i Project: Premiere Fibers Pace Project No.: 92354922 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)62$.8921 Asheville Certification Il]s 2225 Riverside Drive, Asheville, NC 28804 FloridalNELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 Eden Certification IDS 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Yrginia/VELAP Certification #: 460222 North Carolina Wastewater Certification #: 633 Vrginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shell not be reproduced, except In full, without the wrlden consent of Pace Analytical Services, LLC. Page 2 of 15 Pace Analytical Services, LLC 1ceM1alXicalo 2[}5 East Meagow Road -Suite A Eden, NC 27288 www.paosl ftC0m {336}623-6921 SAMPLE SUMMARY Project: Premiere Fibers Pace Project No.: 92354922 Lab ID Sample ID Matrix Date Collected Date Received 92354922001 Outfall001 Water 09/12/1711:30 09112/1715:30 92364922002 Outfall002 Water 09/1211711:45 09/12/1715:30 92354922003 Outfall003 Water 0911211712:00 0911211715:30 92364922004 Outfall004 Water 09/1211712:15 0911211715:30 92354922006 Outfail005 Water 0911211712:30 0911211715:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Without the written consent of Pace Analytical Services, LLC. Page 3 of 15 acMnalytical e wmpacelabs.mm i SAMPLE ANALYTE COUNT Project: Premiere Fibers Pace Project No.: 92354922 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Lab ID Sample ID Method Analysts Analytts Reported Laboratory 92364922001 Outfall 001 SM 2540D CTB 1 PASI-E EPA 9040 SAM1 1 PASI-E SM 5220D NAL 1 PASI-A 92364922002 Outfall 002 SM 2540D CTB 1 PASI-E EPA 9040 SAM1 1 PASI-E SM 5220D NAL 1 PASI-A 92354922003 Outfali 003 SM 2540D CT8 1 PASI-E EPA 9040 SAM1 1 PASI-E SM 5220D NAL 1 PASI-A 92364922004 Outfall 004 SM 2540D CTB 1 PASI-E EPA 9040 SAM1 1 PASI-E SM 5220D NAL 1 PASI-A 92354922005 Outfall 005 SM 2540D CTB 1 PASI-E EPA 9040 SAM1 1 PASI-E SM 5220D NAL 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Lull, without the written consent of Pace Analytical Services, LLC. Page 4 of 15 aceAnalytical e%W-pawaftcom ANALYTICAL RESULTS Project: Premiere Fibers Pace Project No.; 92354922 Pate Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: Outfall 001 Lab ID: 92364922001 Collected: 09/12/17 11:30 Received: 09/12/17 15:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 39.2 mg/L 2.5 2.5 1 09/13/17 15:08 9D40 pH Analytical Method: EPA 9040 pH 6.6 Std. Units 0.10 0.10 1 09/13/17 13:28 H1,1-16 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand ND mg1L 25.0 12.5 1 09/20/17 20:24 Sample: Outfall 00P Parameters Lab ID: 92354922002 Collected: 09/12/17 11:45 Report Results Units Limit MDL DF Received: 09112/17 15:30 Matrix: Water Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids ND mg/L 2.5 2.5 1 09/13/17 15:08 9040 pH Analytical Method: EPA 9040 pH 6.6 Std. Units 0.10 0.10 1 09/13/1713:28 H1,H6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand NO mg1L 25.0 12.5 1 09/20/17 20:24 Sample: Outfall 003 Lab ID: 92364922003 Collected: 09/12117 12:00 Received; 09/12/17 15:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 25400 Total Suspended Solids 5.3 mg1L 2.5 2.5 1 09/14/17 12:20 9040 pH Analytical Method: EPA 9040 pH 6.5 Std. Units 0.10 0.10 1 09/13/17 13:28 H1,H6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand NO mg/L 25.0 12.5 1 09/20/17 20:24 Sample: Outfall 004 Lab ID: 92364922004 Collected: 09/12/17 12:15 Received: 09/12/17 15:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2640D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids ND mg/L 2.5 2.5 1 09/14/17 12:21 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 09/22/2017 01:44 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 15 aceAnalytica!' wwx:psceleba.com ANALYTICAL RESULTS Project, Premiere Fibers Pace Project No.: 92354922 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: Outfall 004 Lab ID: 92354922004 Collected: 09/12/17 12:15 Received: 09/12/17 15:30 Matrix: Water Report Parameters Results Units Limit MOIL OF Prepared Analyzed CAS No. Qual 9040 pH Analytical Method: EPA 9040 ' pH 7.2 Sid. Units 0.10 0.10 1 09/13/17 13:28 1-11,1-16 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 68.0 mg/L 25.0 12.5 1 09/20/17 20:24 Sample: Outfall 005 Lab ID: 92364922005 Collected: 09/12/17 12:30 Received: 09/12/17 15:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 25400 Total Suspended Solids 116 mg/L 11.4 11.4 1 09/13/17 15:09 9040 pH Analytical Method: EPA 9040 pH 6.8 Std, Units 0.10 0.10 1 09/13/17 13:28 H1,H6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 176 mg/L 25.0 12.5 1 09/20/17 20:24 Date: 09/22/21317 01:44 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, LLC, Page 6 of 15 aceAnalytical e www.pacafapa,00m i QUALITY CONTROL DATA Project: Premiere Fibers Pace Project No.: 92354922 QC Batch'. 377539 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92354922001, 92354922002, 92354922005 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)e23-8921 METHOD BLANK: 2091869 Matrix: Water Associated Lab Samples: 92354922001, 92354922002, 92354922005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 2.5 09/13/17 15:01 LABORATORY CONTROL SAMPLE: 2091870 Spike LCS LCS % Roc Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg1L 250 248 99 90-110 SAMPLE DUPLICATE: 2091872 92354922005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg1L 115 119 3 5 SAMPLE DUPLICATE: 2094026 92354840001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg1L 360 354 2 5 Results presorted on this page are In the units Indicated by the "Units" column exceptwhere an alternate unit Is presented to the right or the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 09122/2017 01:44 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 15 aceAnalytical www.pacelehs.com Project: Premiere Fibers Pace Project No.: 92354922 QC Batch: 377697 QC Batch Method: SM 2540D Associated Lab Samples: 92354922003, 92354922004 METHOD BLANK: 2092616 Associated Lab Samples: 92354922003, 92354922004 Parameter Units Total Suspended Solids mglL Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-9921 QUALITY CONTROL DATA Analysis Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Matrix: Water Blank Reporting Result limit MDL Analyzed Qualifiers ND 2.5 2.5 09/141171216 LABORATORY CONTROL SAMPLE: 2092617 Spike LCS LCS % Rec Parameter Units Conc. Result %Rec Limits Qualifiers Total Suspended Solids mglL 250 258 103 90-110 SAMPLE DUPLICATE: 2092618 92354978003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mglL 5380 4850 10 5 D6 SAMPLE DUPLICATE: 2092619 92355122001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg/L 343 336 2 5 Results presented on this page are In the units Indicated by he "Units" column except where an alternate unit Is presented to the right of the rosulL REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/22/2017 01:44 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 15 /5aceAnalyfical' j www.Aacela(u,tam f QUALITY CONTROL DATA Project: Premiere Fibers Paco Project No.: 92354922 QC Batch: 377537 Analysis Method: EPA 9040 QC Batch Method: EPA 9040 Analysis Description: 9040 pH EDEN Associated Lab Samples: 92354922001, 92354922002, 92354922003, 92354922004, 92354922005 SAMPLE DUPLICATE: 2091860 Parartieter pH Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 92354922001 Dup Max Units Result Result RPD RPD Qualifiers Std, Units 6.5 6.6 1 9 H1,H6 Results presented on this page am In the units indicated by the "Units" column except where an alternate unit Is presented to the right or the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/22/2017 01:44 AM without the written consent of Pace Analytical Services, I.I.C. Page 9 of 15 accAnalytical e www.pecelsbe.com t QUALITY CONTROL DATA Project: Premiere Fibers Pace Project No.: 92354922 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 QC Batch: 378465 Analysis Method: SM 5220D QC Batch Method: SM 5220D Analysis Description: 5220D COD Associated Lab Samples: 92354922001, 92354922002, 92354922003, 92354922004, 92354922005 METHOD BLANK: 2097002 Matrix: Water Associated Lab Samples: 92354922001, 92354922002, 92354922003, 92354922004, 92354922005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand mg/L ND 25.0 12.5 09/20/17 20:24 LABORATORY CONTROL SAMPLE: 2097003 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg/L 750 754 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2097004 2097005 MS MSD 92354922001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Cone. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand mg/L NO 750 750 688 683 90 90 90-110 1 3 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2097006 2097007 MS MSD 92355015001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand mg/L 80.0 750 750 777 768 93 92 90-110 1 3 Results presented on this page are In the units indicated by he "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/22/2017 01:44 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 15 Z wwwpacelabx= Pace Analytical Services, LLC 206 East Meadow Road • Suite A Eden, NC 27288 (336)623-8921 QUALIFIERS Project: Premiere Fibers Pace Project No.: 92354922 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzeno using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethyiv[nyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acroleln and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PAS [-A Pace Analytical Services -Asheville PASI-E Pace Analytical Services - Eden ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. H6 Analysis initiated outside of the 15 minute EPA required holding time. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 09/22/2017 01:44 AM without the written consent of Pace Analytical Services, I.I.C. Page 11 of 15 /Ice Analytical e www.paoslabacoM QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Premiere Fibers Pace Project No.: 92354922 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Lab ID Sample 1D QC Batch Method QC Batch Analytical Method 92354922001 Outfall 001 SM 2540D 377539 92364922002 Outfall 002 SM 2540D 377539 92364922003 Outfall 003 SM 2540D 377697 92354922004 Outfall 004 SM 2540D 377697 92354922005 Outfall 006 SM 2540D 377539 92364922001 Outfall 001 EPA 9040 377537 92364922002 Outfall 002 EPA 9040 377537 92354922003 Outfall 003 EPA 9040 377537 92354922004 Outfall 004 EPA 9040 377537 92364922005 Outfall 005 EPA 9040 377537 92364922001 Outfall 001 SM 5220D 378465 92354922002 Outfall 002 SM 5220D 378465 92364922003 Outfall 003 SM 5220D 378465 92354922004 Outfal1004 SM 5220D 378465 92364922005 Outfall 006 SM 5220D 378465 Date: 09/22/2017 01:44 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, LLC. Analytical Batch Page 12 of 15 Document Name: Document Revised: August 4, 2017 �acefil1r71�XiCal" Sam le Condition Upon Recel t SCUR Page 1 of 2. Document No.: Issuing Authority; F-CAR-CS-633-Rev.04 Pace Quality Office Laboratory receiving sarnples: Asheville ❑ Edeng Greenwood ❑ Huntersville le t Name: r- Project 0: Courier: []FedEx ❑UPS USPS Client ❑ Commercial ❑Pace ❑Other: Custody Seal Preterit? ❑Yes E: N' Seals Intact? Dyes ❑No Packing Material: ❑Bubble Wrap ❑Bubble Bags 4None Thermometer: [% IRGun ID: -�b �— Type of Ice: �"re Correction Factor: Cooler Temp Corrected ('Cl: Date/initials Person Examining Contents: ❑ Other Biological Tissue Frozen? ❑Blue Done []Yes []NO ❑N/A Temp should be above freezing to 6'C ❑Samples out of temp criteria. Samples on Ice, cooling process has begun USDA Regulated Soil (❑ N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC )check maps)? Did samples originate from a foreign source (internationally, Mync MAJ. Inrludlnn HA-11 and Puerto Rlenl? I_IYAz I77INn CommentsJGlsere one : ChalnofCustod Present? Yes QNo NIA 1. Samples Arrived within Hold Time? Yes ot,. N A 2. Short Hold.TimeAnai sIs 1<72 hr.)? Yes o ONIA 3. Rush Turn Around Time Requested? Yef No N/A 4. Suffl6ent Volume? ffies ONO N A S. Correct Containers Used? -pace Containers Used? es ONO QNO ❑N/A N/A 6. Containers Intact? Yet ONO NIA 7. g.. Dissolved analysis; Samples Field Filtered? es No A Sample Labels Match COC? -includes Date/Time/ID/Analysis Matr{x: y Yes !� ✓ (:]No ❑NIA 9. Heads are in VOA Vials ?S-6mm)? Yes ONO C A to.. Trip. Blank Present? Trip Blank Custody Seals present? []Yes ❑Yes ❑Na ONO ❑ JA N a ' 11. CLIENT NOTIFICATION/RESOLUTION Person Contacted: Date/Time: Comments/Sample Discrepancy: Field Data Required? ❑Yes []NO Lot ID of split containers; u Project Manager SCURF Review: Date: / 1 Z 'I l Project Manager SRF Review-, Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, Incorrect preservative, out of temp, incorrect containers) Page 13 of 15 CHAIN -OF -CUSTODY / Analytical Request Document - The Chairs -of -Custody is a LEGAL DOCUMENT. Alt relevant fields must be completed accurately. Section A Section a Section C Requited Gient Information: Required Project Information: Imam Information: page : T Of T Company. Waters Edge Environmental Report To: Thomas I Atlentiarc Address: 4901 Watefs Edge Dr. Copt. To: Cor:pany Name: Suits 201, R'aWigk NC 27506 Mare= Email: Purchase order F. Pace Quote. i Prom: Fax Pro>eS;t Name= Premiere Fbers Pace Project Wmuvjor MfiSti.tltr55 lat>s.mrr>, Requested Due Date: Pmjed 9. - f Paco Profire is: - NC �3 ;, T t cow � COLLECTED x Preservatives 4 01"Wear rw Wa. WT a 3 • V O J Wean Wa. WW SAMPLE ID aw a 's t7 STARTcw ENa Q�js {°iZZ tine character Per bey. Wk- wp v w w a ? r� o IA-7- 0.9 1. -j O&ti or U i` ? $ n 1 SampleU Ids nvM be unique T_ T6 X W a w a pppe. Q. y O N C '_ ail- is tY r 6 h t] U ~ i DATE TIME DATE TIME r 7 2 S S 2 Z 1 6 H n r4� �t s z: 4 r G' l %� f-� �L� f r�1 3 ,� I .r 1 ; ate=, :ia =<i:1 ntArtatoaT M.— ... t]ATE:� �-�TtA!�t�n - SJWPLECOFIOti1DN3� .,�.Y-�..-.�...�. r._z !..;iAcurrbNALwrs _,-�rAr �...,;�.._, .. -...._ �.,,•c::�,e:��4 .�� :<'-� �_=�"ACI�P?Eq•�r�-=s:.r��-�r�-.<>�.�,a`�.._^ _.sP- ��_IIAL.as-s•..s.. ?tCaNATtII�`,"w� ' S S s a„�' .,�, �".-x' °.-ail- -a- , ,.t _ � PRiNT Name of SAMPLER_ to a a CL Z 3 z SIGNATORE of SAMPLER: t DATE Signer „ w io K 3v 3 a? m^ t? r , I r "Ut N C`. f 0 R R 2 a s 3 o� Y s a � � n � o o a � Y 0 W � n � f0 tD M CL 'o ; tn o fb V/ D 0 C Y O• n m v a S N CC n EME MEN ■■■■■■■���.1;� ■■■■■■■©©==C ■■■■■■■■■■ NMI n MEN ■■■■■■■■■ ■■■■■■■■■■■■ 1 • ��� IR 1 .- . ■■■ . ■■■■■ ONE ■■■ 1 • ■■■■■■■■■■■■ ill 1 ' 1 emni ■■■■■■■■■■■■ j ■■■■■■■■■■■■ ` ) ONE ■■■■■■■■■ ■■■■■■■■■■■■ o, n 7' 7 nC—Son C �^ c n W w G W O � .. R o ^ A m A aceAnalyrical ` { www[paoslabscom October 28, 2017 Mr. Phil Rahn Waters Edge Environmental 1434 Chester Road Raleigh, NC 27606 RE: Project: Premiere Fibers R9-21 Pace Project No.: 92360219 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Dear Mr. Rahn: Enclosed are the analytical results for sample(s) received by the laboratory on October 23, 2017. The results relate only to the samples included in this report. Results reported h erein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Clayton McCrickard clayton.mccrickard@pacelabs.com (336)623-8921 Project Manager Endosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 13 5aceAnaljdical 1�lwsrw.pacelabacam Project: .,Premiere Fibers R9-21 Pace Project No.: 92360219 Pace Analytical Services, LLC 205 East Meadow Road - Suits A Eden, NC 27288 (336)623.8921 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #; M-NC030 North Carolina Drinking Water Certification #: 37712 Eden Certification IDs 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 VirginiafVELAP Certification #: 460222 North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification M 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, LLC. Page 2 of 13 aceAnalytical Iwwwpacelabs.=n f Project: Premiere Fibers R9-21 Pace Project No,: 92360219 Lab 11;) Sample 10 SAMPLE SUMMARY Matrix Date Collected Date Received 92360219001 OUTFALL 006 Water 10/23/17 12:30 10/23/17 16:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, I.I.C. Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 3 of 13 aceAnalyircal / www.pecelabs.com { SAMPLE ANALYTE COUNT Project: Premiere Fibers R9-21 Pace Project No.: 92360219 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92360219001 OUTFALL 005 SM 2540D CTS 1 PASI-E EPA9040 SAM1 1 PASI-E SM 5220D NAL 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the wriHen consent of Pace Analytical Services, LLC, Page 4 of 13 aC`Analytical e www.pacefehs.mm ANALYTICAL RESULTS Project: Premiere Fibers R9-21 Pace Project No.: 92360219 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)823-8921 Sample: OUTFALL 006 Lab lD: 92360219001 Collected: 10/23/17 12:30 Received: 10/23/17 16:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. dual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 24.7 mg1L 3.5 3.5 1 10/25/17 13:19 9040 pH Analytical Method: EPA 9040 pH 6.8 Std. Units 0.10 0.10 1 10/24/17 09:15 Fib 5220D COD Analytical Method: SM 52200 Chemical Oxygen Demand 310 mg1L 25.0 12.5 1 10/27/17 20:49 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 10/28/2017 10:38 AM wrthout the written consent of Pace Analytical Services, LLC. Page 5 of 13 /5a'ceAnalytical' waw.patx7aDa.rxwn QUALITY CONTROL DATA Project: Premiere Fibers R9-21 Pace Project No.: 92360219 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 QC Batch: 383874 Analysis Method: SM 2540D OC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92360219001 METHOD BLANK: 2127441 Matrix: Water Associated Lab Samples: 92360219001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Suspended Solids mg1L ND 2.5 2.5 10/25/17 13:13 LABORATORY CONTROL SAMPLE: 2127442 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg1L 250 242 97 90-110 SAMPLE DUPLICATE: 2127443 92360156001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg1L ND 91.5 5 SAMPLE DUPLICATE: 2127444 92360312001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg1L 604 597 17 5 D6 Results presented on this page are In the units Indicated by the "Units" colurm except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 10/28/2017 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 13 1eAnalyficale —pacalabacdm Project: Premiere Fibers R9-21 Pace Project No.: 92360219 QC Batch: 383677 QC Batch Method: EPA 9040 Associated Lab Samples: 92360219001 SAMPLE DUPLICATE: 2120260 Parameter Units PH Std. Units QUALITY CONTROL DATA Analysis Method: EPA 9040 Analysis Description: 9040 pH EDEN 92360219001 Dup Result Result RPD 6.8 6.9 1 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27268 (336)623.8921 Max RPD Qualifiers 9 H6 Results presented on this page are In the units Indicated by the "units" column except where an ahamate unit Is presented to the right or the result REPORT OF LABORATORY ANALYSIS This report shO not be reproduced, except In full, Date: 10/28/2017 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 13 aceAnalytical 1 www.pmlabs.com II QUALITY CONTROL DATA Project: Premiere Fibers R9-21 Pace Project No.: ''92360219 QC Batch: 384021 Analysis Method: SM 5220D QC Batch Method: SM 5220D Analysis Description: 5220D COD Associated Lab Samples: 92360219001 METHOD BLANK: 2128397 Matrix: Water Associated Lab Samples: 92360219001 Blank Reporting Pace Analytical Services, I.LC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand mg1L NO 25.0 12.5 10/27/17 20:49 LABORATORY CONTROL SAMPLE: 2128398 Spike LCS LCS % Rec Parameter Units Cane. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg1L 750 754 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2128399 2128400 MS MSD 92359949002 Spike Spike MS MSD MS MSD % Reo Max Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand mg1L ND 750 750 794 792 105 105 90-110 0 3 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2128401 2128402 MS MSD 92360289001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Cone. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand mg1L 65.0 750 750 866 859 107 106 90-110 1 3 Results presented on this page are In the units Indicated by he "Units" column except where an alternate unit Is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 10/28/2017 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 13 W aceAnalytical e www.paaalabs.com Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-6921 QUALIFIERS Project: Premiere Fibers 129-21 Pace Project No.: 92360219 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL- Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte Is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC institute. LABORATORIES_, PASI-A Pace Analytical Services - Asheville PAST-E Pace Analytical Services - Eden ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. H6 Analysis initiated outside of the 15 minute EPA required holding time. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/2&2017 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 13 Pace Analytical Services, LLC aceAnalytical a 205 East Meadow Road - Suite A Eden, NC 27288 wwwpacslabs.oam (336)623-8921 I QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Premiere Fibers R9-21 Pace Project No.: �'92360219 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92360219001 OUTFALL 005 SM 2540D 383874 92360219001 OUTFALL 005 EPA 9040 383677 92360219001 OUTFALL 006 SM 5220D 384021 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 10/28/2017 10:38 AM without the written consent of Pace Analytical Services, LLC, Page 10 of 13 aceAnalylrcal Document Name: Sample Condition Upon Recei t SCUR Document Revised: August 4, 2017 Page 1 of 2 Document No.: F-CAR-CS-033•Rev,04 Issuing Authority: Pace Q"!q Office Laboratory receiving samples: _.. ............ Ashevifltr.❑ _Edeng Greenwood ❑ Huntersville ❑ Raleigh[❑ Mechanicsville❑ Courier: ❑ Commercial Custody Seal Present? Packing Material: Thermometer: IR Gun ID: Correction Factor: Client Name: Protect Nfvcifos Uf C. ❑Fed Ex F-]UPV CUSPS Client ❑Pace ❑0lher; ❑Yes eNo Seals intact? ❑Yes ONO Date/Initials Parton Exam€ningContents:�7/ 7 ❑Bubble Wrap ❑Bubble Bags one El other Biological Tissue Frozen? �� �Type of r wet ❑Blue ❑None ❑Yes ❑Na ❑N/A I Cooler Temp Corrected J'CJ; ( Temp should be above freezing to 6T []Samples out of tamp criteria, Samples on Ice, cooling process has begun USDA Regulated Soil i ❑ NIA, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? aid samples originate from a foreign source {internationally; Flyes f—INn Includina Haarall and Puerto Rlcol? f-IYes nNo Comments/Discrepancy; Chain or Custody Presents Yes fING N/A 1, Samples Arrived within Hold rime? Yes CINO N A 2. Short Hold Time Analysis 02 hr.)? Yes -ONO N/A 3. Rush Turn Around Time Requested? JJY. o N/A 4. Sufficient Volume? Aives []NO N A 5. Correct Containers Used? -Pace Containers Used? -fJYes 17yes ❑No No ❑N1A N/A 6. Containers Intact? QYes r1N. N/A 7. Dissolved analysis: Samples Field Filtered? OVes No ZEJNLA 8. Sample Labels Match COO -Includes Date/Time ID Anal sis Matrix: �©` Yes 1 ❑No ❑N/A 9. Heads ace in VOA Vials P5.6mmJ? OYeS ND A 10. Trip Blank Present? Trip Blank Custody Seals Present? []Yes 0Yes []No 0 No N/A VfNJA 11. CLIENT NOTOICATIDN/RESOLUTION Person Contacted: Comments/Sample Discrepancy: Date/Time: Field Data Required? ❑Yes []NO Lot ID of split containers: Project Manager SCURF Revlew: Date: 10 2 �s + Project Manager SRF Review: v Date: _ I O Z'71% % Note: whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Cffice (Le. Out of hold, incorrect pteservative, out of temp, incorrect containers) Page 11 of 13 0 ;ZeLa& icat' .I mm CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. AN relevant fields must be completed a=rately. Page. Section A Section B Section C a Required Client Information: - Required Projw lodomoa5on'. .Invoice Information: Company Report To: f Attention: % 2177514 t-' titir• / / ess: Copy To: 1 Company Name: REGULATORY AGENCY Address. F NPDEs r GROUNDWATER r DRINKING WATER r UST (RCRA OTHER Emal To: Z _ % y PetrrhaSQ Order NO.: � I Pam oude , r �C._(1�jAf C�� Reform : Phone: Fax: Project Name: /� y r'.�� tP Freida flr Site Locatlriti STATE j r ^ Requested Duo 0atefTAT: Project mmtn r: �.V ^^t x Pxe Prem x Requested AnalysisFittered (YIN) Section D Matrix Codes RgWredGkint k>krrnsren MATRoc r CODE ' COLLECTED PreservativesDrInb >`.. ViateIrlg Water OW Wast WT U Y it.JlPl f1 Waste Water WWII Produa P m STYE UJ z 1 f sawso� SL SAMPLE ID 00 L � v cc � Mpe , (A-Z. 0-g f :) Air AR w o0 - a a Z as Fn o Sample Ds MUST BE LINIQUE Tissue TS V a �: i Other OT p x w r w r m v 0 S C iR 5+ LJ m LL `a h O L C C "on ~ y DATE TIME DATE TtA+E V x 2 x z z M O a* Pace Project NoJ Lab I.D. 1 6107 ,t,C..- 0_5— ILT - - 2. f 3 4' 5 fi 7' 8 g i 1Q tt Tz - `-ADDITIONALCIDNME TS - F(EtAQUISHEDBY1AFFILIATION - .. ",DATE- TIME --ACCE4ED0i4FILIATiON- .. -'DATE, . =TUNE SAMPLECONDITIONS SAMPLER NAME AND SIGNATURE ' , :::.PRWT U o U ORIGINAL_._... 4 — a Naof SAMPLER_^ Nam > } o S a U V N m SIGNATURE of SAMPLER. %C f Z ^1 J/I MMlDDIYYJ- ' l y •rnpodam rasa: By s pnleg gW Sure, YVU am aneepoN PaW$ NET 30 dW oars IV= mid ac eerg to loam dmrgas eI m.sx per egreh r« any r,, , o p f3a / F-ALL-0-020rev.07. 15-May200y 0 w In Ol v K s b A A n 7 a � o C 9 3 n n � 'y �^ O a n a O ~ 5 n � a {n fb A Q 9 n 3 o �p 7 N D 3 O G n aro am w S L. C w Irian OEM M.- 1�NEON ME ENE MEereserved a WE rii�i n , ,■■■■■■■■■■■ on an 1 mL VOA '■■■■■■■■■■■ / r mL V0A H3PO4 MEN ,■■■■■■■ ■■ ■■ 'M■..■■■■■�■ p WATERS EDGE ENVIRONMENTAL, LLC 1434 CHESTER ROAD • RALEIGH, NC 27608 • PHONE 919.219.6820 April 21, 2017 NCDEQ Division of Water Quality Central Files 1617 Mail Service Branch Raleigh, North Carolina 27699-1617 RECEIVED Reference: Year 3- Period I Stormwater Monitoring Report Premiere Fibers Facility APR 2 6 2017 Ansonville, North Carolina Stormwater Permit No. NCS000528 CENTRAL AL FILES D1NR SECTION Waters Edge Job No. R9-21 To Whom It May Concern: We are presenting the stormwater monitoring report for Year 3- Period 1 in 2017. All results are within required parameters We have attached the DMR, SDO, and laboratory analytical results -see Appendix A and B). If you have any questions, or if we may be of further assistance, please contact me at prahn c�r�,watersedgeenv.com or 919.859.9987. Sincerely, Waters Edge Environmental, LLC - � � 9_j_�e ; � � /_'_ - Phillip L. Rahn President cc: Mr. Dewey Fulton and Mr. Kevin Bowers- Premier Fibers 17-028 I Permit Number: NCS 000528 Certificate of Coverage Number: NCG STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT or SAMPLES COLLECTED DURING CALENDAR YEAR: 2017 (This monitoring report shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) FACILITY NAME Premiere Fibers PERSON COLLECTING SAAWLE(S) T. Haynes CERTIFIED LABORATORY(S) Pace Lab## 633 Lab ## Part A: Specific Monitoring Requirements COUNTY Anson PHONE NO. (704) 826.8321 (SIGNATURE OF PERNUTrEE OR DESIGNEE) By this signature, I certify that this report is accurate complete to the best of my knowledge. Outfall Y s" Date �; % sP 4¢ �s de' ' '�p't- I. •: P € q I �` _ i°S.'. . NoR 4 Sample ' :xT01al Collected:' :# Rainfall Total- Saspenaed a Salads '160 COD"`6 3 f- � ,124 -` :. :# - C �; , molddiyr m mP� _ Unfts o 1 4.6.17 See Below 5.0 N-D 6.4 2 4.6.17 5.5 ND 6.5 3 4.6.17 2.6 ND 5.9 4 4.6.17 23.2 34.0 6.3 5 4.6.17 51.3 63 6.4 Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month.? _ yes ✓ no (if yes, complete Part B) Form SWU-246-112608 Page 1 of 2 Part R: Vehicle Maintenance Activity Monitoring Requirements %,Outfalt Date tC�4 ,! 1Ycr tiSQC1o4�i SaR�ple SAT©tai Flow Total Ra6fall ?4 , Q1 Sc Crease Total i 'H New`t4tator 6i1 Coilectd (rf applicble) ; j : i Sus eRsfed P, i Usage z t':.p a E - �'- fir' � € II k € E �€ ^i� $ - � •l:_;p .!� . -: ¢{g„ 4:,:il::. rtRty/dd - -Inches - ...�. iSl�•_' - RI UIiILS _li 9UR10; I STORM EVENT CHARACTERISTICS: Date 4-6-17 Total Event Precipitation (inches): 0.22 Event Duration (hours): N/A (only if applicable — see permit.) (if more than one storm event was sampled) Date NIA Total Event Precipitation (inches). Event Duration (hours): (only if applicable — see.permit-) Mail Original and one copy to: Division of Water Quality Attn: Central piles 1617 Mail Service Center Raleigh, North Carolina 27699-161.7 "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signa r of Permittee � 2r7 t Date Form SV U-246-112608 Page 2 of 2 Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report Forguidance on filling out this form, please visit: htt :1/h2o.enr.state,nc,us/su/Forms DOCuments.htm#miscforms Permit No.: I N 1C C i S 10 i 0; 0 5 i 2; 8 or Certificate of Coverage No.: Facility Name: Premiere Fibers County: Anson Inspector: Thomas Haynes Date of Inspection: 4.6.17 Time of Inspection: 11:00-12:00 Total Event Precipitation (inches): 0.22 Phone No. 704.826.8321 Was this a Representative Storm Event? (See information below) ® Yes ❑ No Please check your permit to verify if Qualitative Monitoring must be performed during a representative storm event (requirements vary). A "Representative Storm Event' is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no precipitation. By this signature, I certify that this report is accurate and complete to the best of my knowledge: (Signature of Permittee or Designee) l Outfall Description: Outfall No. 001-005 Receiving Stream: Buffalo Creek Structure (pipe, ditch, etc.) Pipe to Ditch Describe the industrial activities that occur within the outfall drainage area: Textile Manufacturina 2 Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: _Light brown Page I of 2 S W U-242-112608 3 Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): No odor noted 4 Clarity: Choose the number which best describes the clarity of the discharge, where I is clear and 5 is very cloudy: O 2 3 4 5 5 Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where I is no solids and 5 is the surface covered with floating solids: O 2 3 4 5 6 Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where I is no solids and 5 is extremely muddy: O 2 3 4 5 7 Is there any foam in the stormwater discharge? Yes No 8 Is there an oil sheen in the stormwater discharge? Yes No 9 Is there evidence of erosion or deposition at the outfall? Yes No 10 Other Obvious Indicators of Stormwater Pollution: List and describe None Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 S W U-242-1 12608 5ac 16 A na ly fical www.pacelabs.crom 1 1 April 13, 2017 Mr. Phil Rahn Waters Edge Environmental 1434 Chester Road Raleigh, NC 27606 RE: Project: PREMIERE FIBERS R9-21 Pace Project No.: 92336232 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Dear Mr. Rahn: Enclosed are the analytical results for sample(s) received by the laboratory on April 06, 2017. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, I�'��v/" Clayton McCrickard clayton.mccrickard@pacelabs.com (336)623-8921 Project Manager Enclosures ACC$ REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 14 aceAnalytical www.pace%bs.cam li Project: PREMIERE FIBERS 119-21 Pace Project No.: 92336232 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Asheville Certification IDs 2225 Riverside Drive, Asheville, INC 28804 Florida/NELAP Certification #. E87648 Massachusetts Certification* M-NC030 North Carolina Drinking Water Certification #: 37712 Eden Certification IDs 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification * 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 40 South Carolina Cerfification #. 99030001 VirginiaNELAP Certification M 460222 North Carolina Wastewater Certification M 633 VirginiaNELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 14 11ceAnalyfical'D Hwwpacelabs.mm I i SAMPLE SUMMARY Project: PREMIERE FIBERS R9-21 Pace Project No.: 92336232 Lab ID Sample Io Matrix Date Collected Date Received 92336232001 OUTFALL 001 Water 04/06/17 11:00 04/06/17 14A0 92336232002 OUTFALL 002 Water 04/06/17 11:15 04/06/17 14:40 92336232003 OUTFALL 003 Water 04/06/17 11:30 04/06/17 14:40 92336232004 OUTFALL 004 Water 04/06/17 11:45 04/06/17 14:40 92336232005 OUTFALL 005 Water 04/06/17 12:00 04/06/17 14:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)823-8921 Page 3 of 14 15a'ce Analytical" www.pweiabs.com 1 SAMPLE ANALYTE COUNT Project: PREMIERE FIBERS R9-21 Pace Project No.: 92336232 Pace Analytical Services, LI.0 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Lab ID Sample ID Method Analysts Anaiytes Reported Laboratory 92336232001 OUTFALL 001 SM 2540D CTB 1 PASI-E EPA 9040 RAY 1 PASI-E SM 5220D MDW 1 PASI-A 92336232002 OUTFALL 002 SM 2540D CTB 1 PASI-E EPA 9040 RAY 1 PASI-E SM 52201D MDW 1 PASI-A 92336232003 OUTFALL 003 SM 2540D CTB 1 PASI-E EPA 9040 RAY 1 PASI-E SM 5220D MDW 1 PASI-A 92336232004 OUTFALL 004 SM 2540D CTB 1 PASI-E EPA 9040 RAY 1 PASI-E SM 5220D MDW 1 PASI-A 92336232005 OUTFALL 006 SM 2540D CTB 1 PASI-E EPA 9D40 RAY 1 PASI-E SM 5220D MDW 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shell not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 14 aceAnalytical ""acelabs.com ANALYTICAL RESULTS Project: PREMIERE FIBERS R9-21 Pace Project No.: 92336232 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden,NC 27288 (336)623-8921 Sample: OUTFALL 001 Lab ID: 92336232001 Collected: 04/06/17 11:00 Received: 04106M7 14:40 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 5.0 mg1L 2.5 2.5 1 04/11/17 13:37 9040 pH Analytical Method: EPA 9040 pH 6.4 Sid. Units 0.10 0.10 1 04/07/17 14:55 H1,H6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand ND mg1L 25.0 12.5 1 04/13/17 22:18 Sample: OUTFALL 002 Parameters Lab ID: 92336232002 Collected: Report Results Units Limit 04106/17 11:15 - MDL DF Received: 04/06/17 14:40 Matrix: Water Prepared Analyzed CAS No. Qual 2640D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 5.5 mg1L 2.5 2.5 1 04/11/17 13:37 9040 pH Analytical Method: EPA 9040 pH 6.5 Std. Units 0,10 0.10 1 04/07/17 14:55 H1.H6 5220D COD Analytical Method: SM 52200 Chemical Oxygen Demand ND mg1L 25.0 12.5 1 04/13/17 22:18 Sample: OUTFALL 003 Lab ID: 92336232003 Collected: 04/06/17 11:30 Received: 04/06/17 14:40 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2640D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 2.6 mg1L 2.5 2.5 1 04/11/17 13:37 9040 pH Analytical Method: EPA 9040 pH 5.9 Sid. Units 0.10 0.10 1 04/0711714:55 1-11,1-16 52200 COD Analytical Method: SM 5220D Chemical Oxygen Demand ND mg1L 25.0 12.5 1 04/13/17 22:18 Sample: OUTFALL 004 Lab ID: 92336232004 Collected: 04106/17 11:45 Received: 04/06/17 14:40 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 23.2 mg1L 6.2 6.2 1 04111/17 13:38 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2017 11:08 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 14 2aceAnalyfical' � www.perelabs.crom r ANALYTICAL RESULTS Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: PREMIERE FIBERS R9-21 Pace Project No.: 92336232 Sample: OUTFALL 004 Lab ID: 92336232004 Collected: 04/06/17 11:45 Received: 04/06/17 14:40 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 9040 pH Analytical Method: EPA 9040 pH 6.3 Sid. Units 0.10 0.10 1 04/0711714:55 H1,1-16 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 34.0 mg/L 25.0 12.5 1 04/13/17 22:18 Sample: OUTFALL 005 Lab ID: 92336232005 Collected: 04/06/17 12:00 Received: 04/06/17 14:40 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 2640D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 51.3 mg1L 5.9 5.9 1 04111/17 13:39 9040 pH Analytical Method: EPA 9040 pH 6.4 Sid. Units 0.10 0.10 1 04/07/17 14:55 H1,H6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 63.0 mg1L 25.0 12.5 1 04/13/17 22:18 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/1312017 11:08 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 14 aceAnalytical ~.pacelabs.com 1 1 QUALITY CONTROL DATA Project: PREMIERE FIBERS R9-21 Pace Project No.: 92336232 QC Batch: 356168 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92336232001, 92336232002, 92336232003, 92336232004, 92336232005 METHOD BLANK: 1975713 Matrix: Water Associated Lab Samples: 92336232001, 92336232002, 92336232003, 92336232004, 92336232005 Blank Reporting Parameter Units Result Limit MDL Analyzed Total Suspended Solids mg1L ND 2.5 2.5 04/11/17 13:29 LABORATORY CONTROL SAMPLE: 1975714 Spike LCS LCS Parameter Units Cone. Result % Rec Total Suspended Solids mg1L 250 240 96 SAMPLE DUPLICATE: 1975715 Parameter Total Suspended Solids 92336187001 Dup Units Result Result RPD mg1L 118 112 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Qualifiers % Rec Limits Qualifiers 90-110 Max RPD Qualifiers 5 5 SAMPLE DUPLICATE: 1975716 92336232005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg1L 51.3 51.9 1 5 Results presented art this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04113/2017 11:08 PM without the written consent of Pace Analytical Services, LLC, Page 7 of 14 aXAnalytical ' www.pecolabs.com 1 QUALITY CONTROL DATA Project: PREMIERE FIBERS R9-21 Pace Project No.: 92336232 QC Batch: 355796 Analysis Method: EPA 9040 QC Batch Method: EPA 9040 Analysis Description: 9040 pH EDEN Associated Lab Samples: 92336232001, 92336232002, 92336232003, 92336232004, 92336232005 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 SAMPLE DUPLICATE: 1973772 92336158001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH Std. Units 5.9 5.9 0 9 N1,W6 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presanted to the right of the resuh. REPORT OF LABORATORY ANALYSIS This report shO not be reproduced, except in full, Date: 04/13/2017 11 i08 PM without the written consent of Pace Analytical Services, LLC, Page 8 of 14 aceAnalytical 1 www.pacelabs.com QUALITY CONTROL DATA Project: PREMIERE FIBERS R9-21 Pace Project No.: 92336232 QC Batch: 356633 Analysis Method: SM 5220D QC Batch Method: SM 5220D Analysis Description: 52200 COD Associated Lab Samples: 92336232001, 92336232002, 92336232003, 92336232004, 92336232005 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 METHOD BLANK: 1978556 Matrix: Water Associated Lab Samples: 92336232001, 92336232002, 92336232003, 92336232004, 92336232005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand mg/L ND 25.0 12.5 04/13/17 22:18 LABORATORY CONTROL SAMPLE: 1978557 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg/L 750 751 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1978568 1978559 MS MSD 92336187001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand mg1L 50.0 750 750 831 829 104 104 90-110 0 3 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1978560 1978561 MS MSD 92336174002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits 'RPD RPD Qual Chemical Oxygen Demand mg/L ND 750 750 810 795 107 105 90-110 2 3 Results presented on this page are In the units Indicated by the-UrIlts" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/1312017 11:08 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 14 Pace Analytical Services, LLC ® 205 East Meadow Road - Suite A aceAnalytical Eden, NC 27288 www.pacWabs.com (336)623-8921 QUALIFIERS Project: PREMIERE FIBERS R9-21 Pace Project No.: 92336232 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL- Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte Is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenyiamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute, LABORATORIES PASI-A Pace Analytical Services -Asheville PASI-E Pace Analytical Services - Eden ANALYTE QUALIFIERS H1 Analysis conducted outside the EPA method holding time. H6 Analysis initiated outside of the 15 minute EPA required holding time. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 04/13/2017 11:08 PM without the written consent of Pace Analytical Services, I.I.C. Page 10 of 14 aceAnalyticalm wxw.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: PREMIERE FIBERS R9-21 Pace Project No.: 92336232 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92336232001 OUTFALL 001 SM 25400 356168 92336232002 OUTFALL 002 SM 2540D 356168 92336232003 OUTFALL 003 SM 25400 356168 92336232004 OUTFALL 004 SM 2540D 356168 92336232005 OUTFALL 005 SM 2540D 356168 92336232001 OUTFALL 001 EPA 9040 355796 92336232002 OUTFALL 002 EPA 9040 355796 92336232003 OUTFALL 003 EPA 9040 355796 92336232004 OUTFALL 004 EPA 9040 355796 92336232005 OUTFALL 005 EPA 9040 355796 92336232001 OUTFALL 001 SM 5220D 356633 92336232002 OUTFALL 002 SM 5220D 356633 92336232003 OUTFALL 003 SM 5220D 356633 92336232004 OUTFALL 004 SM 5220D 356633 92336232005 OUTFALL 005 SM 5220D 356633 Date: 04/13/2017 11:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC, Page 11 of 14 "� Document.M1[art?fl:': Document Revised:4ept,21,2016. J J SAlhnle fnhF�rflnh ffa:�i,'be,•n:,.frccunl ' .. Paae 1 eE2 F•CAtt 'Pace Qual€ty Office Laboratory receiving samples: ;. =r' _ Asheville ❑ Eden Greenwood HuntersV1110 Q - ' Rale.l h Mechankstfllle Client Name: W0 9 6123 .. "t 1hI. II � �3 I hI Courier: Fe�Ex UPS StS . Client" ❑ commerciai (]Pace . other: 923 Ba32. Cult*Seal.Ptgtertt? - ..OYes_ ..... Of(lo :..:Sesisintact? [�No _:... " ^ Date/Initials Person Examining Contents., 1 Packing Materlal:: j]BOble Wrap' ' []Bubble Bags ;• atie': `. [�otlmr: Thermometer, .' Qi 6t : afue ; QNone . - Q5amplesonice;coo€€n$protasshas Wun OR Gun ID: ��� 7ypeoftces . CorrectlonFactor; OoaierTempCorrected('CJ; BiofagfcpiTissue.Frozen? []Yes .: CNo. QN/A Temp should be above (ree;ingto WC .' USDA Regulated Soil(j] N/A, water Ample) Did samplei. odehate,In a 4uaran6e zone ivithin the UnitedStates: CA, NY, ar SC (chgck maps)? • Did samptes'ortginate from a forel n sourcetlnternattanalty, QYe&❑No indudiiiiiHawailand PuertoAfsOl]Yes -- UNti Chain Short RhId lime Anal sis Rush Turn AroOnd Time Re SuffZdentVolume? Correct Containers Used? -Pace t:ontalners Used?' Container's Intact? i ;Sam les Field F€ltered? Yes .: ' No Yes bNO .' NLA. 2• ' ? ' Yes No" • .. •h.A, 3, � '" .: .. - .: .. .. ,. • . .' • Q Yes " do.' -QNiA 4. ' Yes Np N A S. . Yes • . ©Nri :CIN/A, Yes .' NO Ng es No N A- 71 Do .' IN6, ' rNlx. 8; Notelfsedliientisvisible inthedlssolvedcontafner " ' Sample labels Match COC7 Wt Yes .QNo . • bN/A 9. � • ' -Includes Date/rfine/ID&a€ sis .Matrix71 € Heads ace in VOAViafs Trip Blank Present? ©Yes Trstody Seals Present? Yea .:QIVo N/a f CLIENT NOTIFICATIOVOSOLUTION Field tiataRequfred? Yes ONo, Person Contacted: Date/time: ' -CommentsAample — — — - 3 Discrepancy: t , Project Manager SCURF Review:' ✓ Date: Ll Project Manager SRFReview, '' . Date.. f Note: •Whenavertliefe Is a discrepancy affecting North Carofina compliance samples, a cop of this form will h6 sont to the North Carolina D1:RNR Certiflcatlon pf{ke (Le. Out ofhp1d,Ineorrectpreservative,out oftemp, incormetcdntalners) Pagej 12,of 14 Owl CHAIN -OF -CUSTODY / Analytical Request Document o :' >aceArralytical The �ln-of-Custody is a LEGAL DOCUMENT. AN relevant fields must be completed accurately. 2, m csr Section A ^^_ r T ^x Section B Section C Page: of ` o_ Required Mont Inforawtion: Required Project Information: Imo;ce Information'. CampanY' / R"r To: Attention: 3 �� �,V ,,I V s /�J Address:/ • , N Copy To: r r ComPa<+Y Nanx': REGULATORY AGENCY Address: ! NPOES F GROUNDWATER j— DRINKING WATER — UST E— RCRA OTHER • Emeil To: /� Purchase Osier No.: /J '1 ` i Pace Reti-m ! i/� / L 1.. .� ermonee: IK Phone: Fwc Project Name: . ,mot e ,� Baca Pooled uanaaar Site Location STA TE. E"--t.d Due DateLTAT: Protect Number. ft J Paco Pilo e: Requested Analysis Filtered (YIN) . section D Matrix Codes _ � ~ z RsRuirod C4err, 3re=Tm5m MATRIX J cotm X. COLLECTED Preservatives � Drinking Water OW U zo SIY Water T Waste Water WW 6 w <on ; ' z PrednC P a ART ENDICRAS . SoiYSoNtl St. SAMPLE 11] wipe p to C , WZ- D-9I r) Air AR p w a w z f! o Sample IDs MUST BE UNIQUE issue TS O a Omer OT X Lu Lu r Z O O kn O c T F- J U u_ avOiO Ors.ct K az -� w ~ h 2 z z Z :� HATE TIME DATE TIME T q Pace Project NoJ Lab LD. •77 V-1, ZVI & C1 -7 ACC 2 u� CQ S 1 7.4e. [..C�`.J r !1 r 4 s L(c z �` r e 7 s 9 10 11 12 ADDITIONAL. COMMENTS RELINQUISHED BY f AFFILIATION DATE TIME ACCEPTED BY I AFF LIATION DATE TIME SAMPLE CONDITIONS .- �h mac. t r.._ ! o �� f SAMPLER NAME AND SIGNATURE ti z a 0 w PRINT Name of SAMPLER: r.X G v,f c a J a �, o j O m E y /'' DATE Signed SIGNATURE of SAI IVER: �! 7 _ Dfyy)- : fn •trpOrar.[ Non: Br sig"Cris `arm you aru ambGtkV Pa s NET 30 day oaymont •arms and agreeing to fate GkmrWz of I.s% aer marks nor arty n.eices nt aa•a 3o odays. I / F-ALL-0.820rev.07. 15-May-20D7 r ✓uW rncl 11 ncvACU: Jaf lr, L11 IWAD I i � c{�n+rtr{yerutr[ •�,.,•,-f53UI�IgAUtfiOrlty: i :Do4ii�tant=No.- . Qu4 11!y O 1��CAR=iC&BAeifO''' PacOffice *O ck mafktop half of box if pH Ondf ordechlorinatIon . G'roOO � t 1s'uor1fled and within the acceptance ran,ge.far.' .:;{ :, 92•'��6232 preseriratian samples, :CHIC Due- nate'6 04/20/1°7 ? : ! **Bdtt6M half of box Is to Nst number of -bottles I C XENT 93=Wat er.s Eel i ro� v A' s A r a Y l 12 pH Adjgstment I.qf rPreservedSa#1es SamplelD :Type ofPreservative PRUPOnreaeipt Datepreai:ivatfQu FWJ.Wted Timapfeserraildn adJus�e Amdu_ntofPreservatiue added !olff -------------- Page 14 of 14 I s STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT Permit Number: NCS 000528 or SAMPLES COLLECTED DURING CALENDAR YEAR: 2016 Certificate of Coverage Number. NCG (This monitoring report shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) FACILITY NAME Premiere Fitters COUNTY Anson PERSON COLLECTING SAMPLE(S) : T. Haynes PHONE NO. (704)_ 826.8321 .. _ CERTIFIED LABORATORY(S) Pace Lab # 633 Lab # _ (SIGNATURE OF PERNIITTEE OR DESIGNEE) By this signature, 1 certify that this report is accurate complete to the best of my knowledge. Part A: Specific Monitoring Requirements ' 4 d � i�� V D OC` 4 4 2.Oi6 DWALFILES R SECTION Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes ✓no (if yes, complete Part B) Form SWU-246-112608 Page i of 2 . ) Part B: Ve6. Maintenance Activity Monitoring Requirements Outfall Date 5(i458 110556 ai53o ©040(3 ' x r No �- Sample � e ; Total blow- nTaial RaEnfalf 01f &�Grease`�; 'fatal � � �pH��.���� New Motor QilF -`: 'a"'.- ...�--sue-`. -T. _.r ti+.,..;". .✓'A�.A. `,F.: 9:a .. 'f: inches }:4:-- wv y q, ): =�3mg11� �mWddlyr * .. MGM : ��. v _ ;;:r:Ua►ts ElaUmo STORM EVENT CHARACTERISTICS: Date 9.21.16 Total Event Precipitation (inches): . Q.57 Event Duration (hours): NIA (only if applicable — see permit.) (if more than one storm event was sampled) Date NIA Total Event Precipitation (inches): Event Duration (hours): (only if applicable — see permit.) Mail Original and one copy to: Division of Water Quality Attn: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 1 Simi_ . re of Permittee (%AZO/2-04, Date Form SWU-246-112608 Page 2 of 2 Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance on filling out this form, please visit.• httn://h2o.enr.state.ne.us/suUMs Documents.htm#miscfotms Permit No.: I N I C I S 101010 Lb 121 j or Certificate of Coverage No.: I I� I I I I I I Facility Name: Premiere Fibers County: Anson Inspector: Thomas Haynes Date of Inspection: 9.21,16 Time of Inspection: 10:00-10:30 Total Event Precipitation (inches): 0.57 Phone No. 704.826.8321 Was this a Representative Storm Event? (See information below) ® Yes ❑ No Please check your permit to verify if Qualitative Monitoring must be performed during a representative storm event (requirements vary). A "Representative Storm Event" is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may_ contain up to 10 consecutive hours of no precipitation. By this signature, I certify that this report is accurate and complete to the best of my knowledge: ES? (Signature of Permince or Designee) Outfall Description: Outfall No. 001-005 Structure (pipe, ditch, etc.) Pipe to Ditch Receiving Stream: Buffalo Creek Describe the industrial activities that occur within the outfall drainage area: Textile Manufacturing 2 Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: Light brown Page 1 of 2 SWU-242-112608 • .. Mry � . � _ s ' � ', T' I'r�. iif !�{)l ill S' + jr•�p, ' � + . .i. r, t .. �. •I. ' r � � r .. ' i- - .Y� ! I r ,�� �� :.+ .. '(�. �I _, � 11 + �. ` !i :�'I . .'' .t •I! � - .i'. _ �. �._.rk�: r! C r. is t ' i:; i_i .�. , • ! �� � ,r �.i p ' r _` • ,i 3 Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): No odor noted ` 4 Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: 1 Q 3 4 5 5 Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: 1 2O 3 4 5 6 Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy: 1 0 3 4 5 7 Is there any foam in the stormwater discharge? Yes No S Is there an oil sheen in the stormwater discharge? Yes No 9 Is there evidence of erosion or deposition at the outfall? Yes No 10 Other Obvious Indicators of Stormwater Pollution: List and describe None Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 SWU-242-112608 5aceAnalytical 1 ' wwwPacelebs.com September 27, 2016 Mr. Phil Rahn Waters Edge Environmental 4901 Water's Edge Drive Suite 201 Raleigh, NC 27606 RE: Project: R9-21 Premiere Fibers Pace Project No.: 92313257 Dear Mr. Rahn: Pace Analytical Services, Inc. 205 East Meadow Road- Sulte A Eden, NC 27288 (336)623-8921 Enclosed are the analytical results for sample(s) received by the laboratory on September 22, 2016. The results relate only to the samples included in this report. Results reported h erein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Clayton McCrickard clayton.mccrickard@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shaft not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 13 /5a'ceAnalytical' www.p&coabs.cnm t I Project: R0-21 Premiere Fibers Pace Project No.: 92313257 Pace Analytical Services, Inc. 205 East Meadow Road - 5ulte A Eden, NC 272a388 (336)623-8921 Asheville Certification IDS 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87848 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 Eden Certification IDS 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In cull, without the written consent of Pace Analytical Services, Inc.. Page 2 of 13 aceAnalyilcal wwwpacslebs.com SAMPLE SUMMARY Project: R9-21 Premiere Fibers Pace Project No.: 92313257 Lab ID Sample ID Matrix Date Collected Date Received 92313257001 Outfall 001 Water 09/21/16 12:00 09/22/16 08:53 92313257002 Outfall 002 Water 09/21/16 12:30 09/22/16 08:53 92313257003 Outfall 003 Water 09/21/16 13:00 09/22/16 08:53 92313257004 Outfatl 004 Water 09/21/16 13:30 09/22/16 08:53 92313267006 Outfatl 005 Water 09/21/16 13:45 09/22/16 08:53 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623.8921 Page 3 of 13 aceAnalytical wwwpaeelabs'wm SAMPLE ANALYTE COUNT Project: R9-21 Premiere Fibers Pace Project No.: 92313257 Pace Analytical Sorvlces, Inc. 205 East Meadow Road- Suite A Eden, NC 27288 (336)623.8921 Lab ID Sample ID Method Analysts Ana lytes Reported Laboratory 92313257001 Outfall 001 SM 2540D KCE 1 PASI-E EPA 9040 DWJ 1 PASI-E SM 5220D MDW 1 PASI-A 92313257002 Outfall 002 SM 25400 KCE 1 PASI-E EPA 9040 DWJ 1 PASI-E SM 5220D MDW 1 PASI-A 92313257003 Outfall 003 SM 2540D KCE 1 PASI-E EPA 9040 DWJ 1 PASI-E SM 5220D MDW 1 PASI-A 92313267004 Outfall 004 SM 2540D KCE 1 PASI-E EPA 9040 DWJ 1 PASI-E SM 52200 MDW 1 PASI-A 92313257005 Outfall 005 SM 2540D KCE 1 PASI-E EPA 9040 DWJ 1 PASI-E SM 5220D MDW 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shell not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 13 5aceAnalytical1�le w wpac lift oom E i ANALYTICAL RESULTS Project: R9-21 Premiere Fibers Pace Project No.: 92313257 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A , Eden, NC 27288 (336)623-8921 Sample: Outfall 001 Lab ID: 92313257001 Collected: 09/21/16 12:00 Received: 09/22/16 08:53 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 2640D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 2.9 mg1L 2.5 2.5 1 09/23/16 12:13 9040 pH Analytical Method: EPA 9040 PH 5.9 Std. Units 0.10 0.10 1 09/22/16 16:00 H1,H6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 46.0 mg1L 25.0 12.6 1 09/26/16 22:00 Sample: Outfall 002 Lab ID: 92313267002 Collected: 09/21/16 12:30 Received: 09/22/16 08:53 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids NO mg1L 2.5 2.5 1 09/23/16 12:13 9040 pH Analytical Method: EPA 9040 PH 6.6 Std. Units 0.10 0.10 1 09/22/16 16:00 H1,H6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand ND mg1L 25.0 12.5 1 09/26/16 22:00 Sample: Outfall 003 Lab ID: 92313257003 Collected: 09/21116 13:00 Received: 09/22/16 08:53 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed GAS No. Qual 2540D Total Suspended Solids Analytioal Method: SM 2540D Total Suspended Solids 67.9 mg/L 6.6 6.6 1 09123/16 12:15 D6 9040 pH Analytical Method: EPA 9040 PH 6.2 Std. Units 0.10 0.10 1 09/22/16 16:00 H1,1-16 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand NO mg1L 26.0 12.5 1 09/26116 22:00 Sample: Outfall 004 Lab ID: 92313257004 Collected: 09121/16 13:30 Received: 09/22/16 08:53 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 36.2 mg/L 2.8 2.8 1 09/23/16 12:i6 REPORT OF LABORATORY ANALYSIS This report shell not be reproduced, except in full, Date: 09/27/2016 08:24 AM without the written consent of Pace Analytical Services, Inc.. Page 5 of 13 Paco Analytical Services, Inc. 1acAnaB�ytical a 205 East Meadow Road - Suite A Eden, NC 27288 11-7mrwpscefabs svm (336j923-8921 1 f ANALYTICAL RESULTS Project: R9-21 Premiere Fibers Pace Project No.: 92313257 Sample: Outfall 004 Lab ID: 92313257004 Collected: 09/21/16 13:30 Received: 09/22/16 08:53 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9040 pH Analytical Method: EPA 9040 pH 6.9 Std. Units 0.10 0.10 1 09/22/16 16:00 H1,H6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 97.0 mg1L 25.0 12.5 1 09/26/16 22:00 Sample: Outfall 006 Lab ID: '92313257006 Collected: 09/21/16 13:45 Received: 09/22/16 08:53 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 15.9 mg/L 2.8 2.8 1 09/23/16 12:17 9040 pH Analytical Method: EPA 9040 pH 6.9 Std. Units 0.10 0.10 1 09/22/16 16:00 1-11,146 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 107 mg1L 25.0 12.5 1 09/26/16 22:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 09/27/2016 08:24 AM without the written consent of Pace Analytical Services, Inc.. Page 6 of 13 aXAnalytical' wwwpereleDs.cam i QUALITY CONTROL DATA Project: 119-21 Premiere Fibers Pace Project No.: 92313257 QC Batch: 330075 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92313257001, 92313257002, 92313257003, 92313257004, 92313257005 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A , Eden, NC 27288 (336)623-8921 METHOD BLANK: 1828809 Matrix: Water Associated Lab Samples: 92313257001, 92313257002. 92313257003, 92313257004, 92313257005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Suspended Solids mg1L ND 2.5 2.5 09/23/16 12:05 LABORATORY CONTROL SAMPLE: 1828810 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg1L 250 266 106 90-110 SAMPLE DUPLICATE: 1828811 92313179001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg/L 132 138 4 5 SAMPLE DUPLICATE: 1828812 92313257003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg1L 67.9 120 55 5 D6 Results presorted on this page are In the unite Indicated by the "Unite" column exceplwhers an alternate unit Is presented to the right of the result, REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 09/27/2016 08:24 AM without the written consent of Pace Analytical Services, Inc.. Page 7 of 13 iceAnalj6calv a ww.pscwlaba.cW I QUALITY CONTROL DATA Project: R9-21 Premiere Fibers Pace Project No.: 92313257 QC Batch: 329920 Analysls Method: EPA 9040 QC Batch Method: EPA 9040 Analysls Description: 9040 pH EDEN Associated Lab Samples: 92313257001, 92313257002, 92313257003, 92313257004, 92313257005 SAMPLE DUPLICATE: 1828105 92313307001 Dup Max Parameter Units Result Result RPD RPD pH Std. Units 4.5 4.5 0 Pace Analytical Services, Inc. 205 East Meadow Road - Sulte A Eden, NC 27288 (336)623-8921 Qualifiers 9 H6 Results presented on this page am In the units Indicated by the "Units' coluen except where an alternate unit Is presented to the Might at the msuX REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/27/2016 08:24 AM without the written consent of Pace Analytical Services, Inc.. Page 8 of 13 aceAnalytical www.pacelatia.com QUALITY CONTROL DATA Project: R9-21 Premiere Fibers Pace Project No.: 92313257 QC Batch: 330263 Analysis Method: SM. 52200 QC Batch Method: SM 5220D Analysis Description: 5220D COD Associated Lab Samples: 92313257001, 92313257002, 92313257003, 92313257004, 92313257005 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8821 METHOD BLANK: 1829894 Matrix: Water Associated Lab Samples: 92313257001, 92313257002, 92313257003, 92313257004, 92313257005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand mglL ND 25.0 12.5 09/26/16 22:00 LABORATORY CONTROL SAMPLE: 1829895 Spike Parameter Units Cone. Chemical Oxygen Demand mglL 750 LCS LCS % Rec Result % Rec Limits Qualifiers 794 106 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1829896 1829897 MS MSD 92313205002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Cone. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand mglL 348 750 750 1090 1090 98 99 90-110 0 3 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1829898 1829899 MS MSD 92313487001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand rrtglL 13500 750 750 13200 13200 -45 -45 90-110 0 3 M6 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the fight of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/27/2016 08:24 AM without the written consent of Pace Analytical Services, Inc.. Page 9 of 13 Pace Analytical Services, Inc. 15ceAnalXical' 205 East Meadow Road- Suite A Eden, NC 27288 www.pacefabacnm (338)623-8921 i I QUALIFIERS Project: RS-21 Premiere Fibers Pace Project No.: 92313257 DEFINITIONS OF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit, MDL-Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydraz€ne decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values, LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 Is recommended In SW846 Chapter 4 for the analysis of Acroleln and Acrylonitdle by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Dlphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services -Asheville PASI-E Pace Analytical Services - Eden ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. H6 Analysis initiated outside of the 15 minute EPA required holding time. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 09/27/2016 08:24 AM without the written consent of Pace Analytical Services, Inc.. Page 10 of 13 IooAnalytical e —psoels"Com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: R9-21 Premiere Fibers Pace Project No.: 92313257 Lab ID Sample ID QC Batch Method QC Batch 92313257001 Outfall 001 SM 2540D 330075 92313257002 Outfall 002 SM 2540D 330075 92313257003 Outfall 003 SM 2540D 330075 92313257004 Outfall 004 SM 2540D 330075 92313257005 Outfall 006 SM 2540D 330075 92313257001 Outfall 001 EPA 9040 329920 92313267002 Outfall 002 EPA 9040 329920 92313267003 Outfall 003 EPA 9040 329920 92313257004 Outfall 004 EPA 9040 329920 92313257005 Outfall005 EPA 9040 329920 92313257001 Outfall 001 SM 5220D 330263 92313267002 Outfall 002 SM 5220D 330263 92313257003 Outfall 003 SM 52200 330263 92313267004 Outfall 004 SM 5220D 330263 92313267005 Outfall 005 SM 5220D 330263 Date: 09/27/2016 08:24 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Analytical Method Analytical Batch Page 11 of 13 E]bt umeet Namei!' Document Revised: May 24, 2016 • 20'6k�'Cal Sim le°Colittitlon 6 ott Recei t SCUR t Pe e l of.2, ;-5 • DocumerttNo '. isiuingAuthority. F4DNb03=Rev:14' • Pace Eden 0.uoli Olfice 2 of 2for Internal Use ONLY I Client Name: project li a ecl S i �d �1 Courier. Fed Ex UPS I USPS CiEeett � � � E l (l, I;-€„ 511 r -1 Cl Commercial ❑Pace I Othe r ' �' " f, ❑ r. $ 1 2l _ 7, Custody Seal Present? ❑Yes �fo 5oalslntact? Yes ❑No -� Date/Initials Person Examining Co tentsL Packing Material: []Bubble Wrap ❑(ubble' Bags ❑None' Bother.' Thermometer. E0007 Type of ice Rwwet:. ❑Blue [)None []Samples on Ice, cooling process has begun Correction factor: 0.0'C Cooler Temp Corrected ('Cji Hlaloglcal Tissue Frozen? []Yes. []No []N/A Temp should be above freezing to VC USDA Reguiatttd Soil (❑ N/A; water semple) Did samples originate In a quarantine zone within the UnitedStates: CA, NY, oi.$C(check maps)? Did samples originato from a foreign source (internationally, Myes FINo indudlnQ Unwalr and Ruerts R.eol? rives I-'•INo Comments Discrepancy.* Chain of Custody Present? Yes'' No N A' • 1. Sam les Arrived within Hold Time? Yes.: No QLA ,:2. Short Hold Time Analysis <72 hr.)? byes No N A.. r3. Rush Turn Around Time Reg uasted? OYes a , A .4. Sufficient Yes • No M NA FS. Correct Containers Used? Yes ❑No 'f QN/A 6. .Pace Containers Used? Yds ONo N A Containers intact? Yes - No ONYA, 7. Samples Field Filtered? Yes No A :8. Note If sediment is visible in the dissolved container. Sample Labels Match CDC? , I_ ,: Yes ❑No O A 9. .. :...,. ; ....._.. , ... r,.... VVTInclude s Date im ID Ana sis. Matd: .. „ ...> ,. r... .... .. . . . __ ,....... :...-......,. All contelners needing acid/base preservation have been 10. H„asHn checked?. - Pals ❑No ❑N/A All'tontalners needing preservation are found to be in Haan: compliance with EPA recommendation? HeroiPHa (HNOa, HISOs, HCIc2; NoOH >9 Sulfide, NoOH>12 Cyanide) Ves ❑No ❑N/A a;oHProu Exceptions: VOA, Coliform, TOC, Oil and Grease, .DRO 8015 water DOC,LLH Yet No 136' Sam lei checked for dechlorinatlon? Ya,. No NIA- '11. Heads ace In VOA Vials >5.6mm ? Ekes No I Trip Blank Present? []Yes ❑No IIIA 13: Trip Blank Custody Seals Present? ❑Yes. ❑No .t2NN/A Pace Trip Blank Lot#(ifpurchased): i CLIENT NOTIFICATION/RESOLUTION Flald Data Required? []Yes []No Person Contacted: Date/Tlme: Comments/Sample Discrepancy: Project Manager SCURF Revlew: q 0=4 Date: Project Manager SRF Review: Date: Note:; Whenever there Is a discrepancy affecting North Carolina compliance samples, a copy,of this form will be sent to the Mart rollna li�A-14R Certificatlon OHiee (i.e. Out of hold, Incorrect preservative, out ottemp, Incorrect containers) Page 12 of 13 ')12.... aoca CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT- All feWvarrt fields must be awn~ accurately. Section A Section B Section CPaw °t / Required Client tnformaaon: Roquimd ProjecL.Uftma5an:. Mvoice tdormalim - CanvaaY C /3L G�J F4VartTa: /d 216.8 2a0 7�r Address: OPYo: CaPayNam: REGJf.bk(AGENCY '` - r NPDES GROUNDWATER F DRINKING WATER j` UST !- RCRA OTHER EMM TO: Purchase Order Na. Quaee ! !� - Phone: Fax ?reject Name: - PNiea SrLe L.oraliOri -- Requested Due DaU iAT:. . Proiw NumDer.- �e9�r -> Requested:Analyses-FittterNd (YlN} ,�� � '' Sectwa D Codas .Matrix negreradOliwd anro4on MAt•rax r COOOi= : COLLECTED Presen+aawes - 0m*ing WMw DW Water WT p tl wulawater vpN wcsm= t wPossE ar�ur emrcAea LuSawsolid Z 00 SAMPLE ID Wipe, (A2 Os/r1 Air- AR Sa lift IDS YU5f.8E tll0Qt1E Ta:srre TS p p m a = H M - - a -- - OBrx -Ly7-' -U Lu �. 'Z O :' a - 0 - `DATE �:..ul p.IN�- o�,� a �: x' ; = Z z O r - DATE TIi11E _ - .Tl! (E .y , EEC <.s_ Paee Project NoJ Lab 1D: 2 • z f - 3 o.l - - - - - - 4 3 If s s - - 12 - - - ,ADDiTIONAiCDAiMENTS'- -' ?-, RELINQUMEABYIAMLIA N - :"-.DATE:-� ': TIME _ r:ACCEp1FABYlAFF]ltAT10H` "_ .➢ATEi -. TIIYIE...- SANPiE00NDITIMS c ED SAMPLER NANE AND SIGNATURE PRINT Name of UMPLER: S cC a o. u z ire o i< o E 3 SIGNATURE of SAtIPLER DATE SWml '"Vwtam Norc By at➢urig rM re rn you am aocepwg Pace & NET M d y PWMere terms and 9 ro 1= ciWM C9 I,5% car Moran for." rnvekes!+a dm. / F-ALL-Q-020rev o7. 15-K a 200T 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 C Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance on filling out this form, please visit: http://h2o.enr.state.nc.us/su/Forms Doc uments.htm#miscforms Permit No.: 1 N 1 C� Si 0 10 1 0[ 5 12 1 8! or Certificate of Coverage No.: Facility Name: Premiere Fibers County: Anson Inspector: Thomas Haynes Date of Inspection: 5.5.16 Time of Inspection: 11-00-11.30 Total Event Precipitation (inches): 0.16 Phone No. 704.826.8321 Was this a Representative Storm Event? (See information below) ® Yes ❑ No Please check your permit to verify if Qualitative Monitoring must be performed during a representative storm event (requirements vary). A "Representative Storm Event" is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no precipitation. By this signature, I certify that this report is accurate and complete to the best of my knowledge: (Signature of Permittee or Designee) Outfall Description: Outfall No. 001-005 Structure (pipe, ditch, etc.) Pipe to Ditch Receiving Stream: Buffalo Creek Describe the industrial activities that occur within the outfall drainage area: Textile Manufacturina 2 Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: Medium brown Page I of 2 SWU-242-I 12608 1 1 f 1 1 1 1 1 1 1 s Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): No odor noted 4 Clarity: Choose the number which best describes the clarity of the discharge, where I is clear and 5 is very cloudy: 1 O 3 4 5 5 Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where I is no solids and 5 is the surface covered with floating solids: Q 2 3 4 5 6 Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where I is no solids and 5 is extremely muddy: l Q 3 4 5 7 Is there any foam in the stormwater discharge? Yes No 8 is there an oil sheen in the stormwater discharge? Yes No 9 is there evidence of erosion or deposition at the outfail? Yes No 10 Other Obvious Indicators of Stormwater Pollution: List and describe None Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition maybe indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 S WU-242- l i 2608 Pace Analytical Services, Inc. aceAnalytJcal • 205 East Meadow Road - Suite A Eden, NC 27288 www-pac wacom (336)623-8921 May 19, 2016 Mr. Phil Rahn Waters Edge Environmental 4901 Water's Edge Drive Suite 201 Raleigh, NC 27606 RE: Project: PREMIERE FIBERS R9-21 Pace Project No.: 92296545 Dear Mr. Rahn: Enclosed are the analytical results for sample(s) received by the laboratory on May 05, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, '8&tag. &4m - Brittany Gibson brittany.gibson@pacelabs.com Project Coordinator Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc„ Page 1 of 13 ' Pace Analytical Services, Inc. aceArralytrcal • 205 East Meadow Road - Suite A Eden, NC 27288 ' www•pacelabs com (336)623-8921 CERTIFICATIONS Project: PREMIERE FIBERS R9-21 Pace Project No.: 92296545 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 North Carolina Wastewater Certification M 40 FloridalNELAP Certification #: E87648 Massachusetts Certification #: M-NC030 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 North Carolina Drinking Water Certification #: 37712 Eden Certification IDs 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Wastewater Certification M 633 North Carolina Drinking Water Certification #: 37738 VrginiaNELAP Certification #: 460025 1 1 1 1 1 1 1 1 1 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 13 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 SAMPLE SUMMARY rtuyecc rr«mir-rtr- rmr-mo rra-n Pace Project No.: 92296545 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Lab ID Sample ID Matrix Date Collected Date Received 92296545001 OUTFALL 001 Water 05/05/16 10:45 05/05/16 15:20 92296646002 OUTFALL 002 Water 05/05116 11:00 05/05/16 15:20 92296546003 OUTFALL 003 Water 05/05116 11:30 05/05/16 15:20 92296545004 OUTFALL 004 Water 05/05/16 12:00 05/05/16 15:20 92296646006 OUTFALL 005 Water 05/05/16 12:15 05/05/16 15:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 13 1 to a ce Analytical www.paca'abs.caM 1 SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 205 East Meadow Road - Suite Eden, NC 27288 (336)623-8921 Project: PREMIERE FIBERS R9-21 Pace Project No.: 92296545 ' Analytes Lab ID Sample ID Method Analysts Repotted Laboratory ' 92296545001 OUTFALL 001 SM 2540D KCE 1 PASI-E EPA 9040 KCE 1 PASI-E SM 5220D WRC 1 PASI-A i 92296546002 OUTFALL 002 SM 2540D KCE 1 PASI-E EPA 9040 KCE 1 PASI-E SM 5220D WRC 1 PASI-A ' 92296545003 OUTFALL 003 SM 2540D KCE 1 PASI-E EPA 9040 KCE 1 PASI-E SM 5220D WRC 1 PASI-A 92296646004 OUTFALL 004 SM 2540D KCE 1 PASI-E EPA 9040 KCE 1 PASI-E SM 5220D WRC 1 PASI-A ' 92296645005 OUTFALL 005 SM 2540D KCE 1 PASI-E EPA 9040 KCE 1 PASI-E SM 5220D WRC 1 PASI-A 1 1 1 1 1 1 1 i 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 13 Pace Analytical Services, Inc. accAnalytrcal • 205 East Meadow Road - Suite A Eden, NC 27288 WWWP&CN&bswm (336)623-8921 ' ANALYTICAL RESULTS Project: PREMIERE FIBERS R9-21 Pace Project No.: 92296545 1 Sample: OUTFALL 001 Lab ID: 92296645001 Collected: 05/05/16 10:45 Received: 05/05/16 15:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ' Analytical Method: SM 2540D 2640D Total Suspended Solids Total Suspended Solids 57.0 mg1L 2.5 2.5 1 05/10/16 13:07 1 9040 pH Analytical Method: EPA 9040 pH 6.3 Std. Units 0.10 0.10 1 05/06/16 09:30 H6 5220D COD Analytical Method: SM 52200 Chemical Oxygen Demand ND mg/L 25.0 12.5 1 05/18/16 20:00 Sample: OUTFALL 002 Lab ID: 92296646002 Collected: 05/05/16 11:00 Received: 05/05/16 15:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ' 2640D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids ND mg/L 2.6 2.6 1 05/10/16 13:08 9040 pH Analytical Method: EPA9040 PH 6.3 Std. Units 0,10 0.10 1 05106/16 09:30 H6 1 5220D COD Chemical Oxygen Demand Analytical Method: SM 5220D ND mg/L 25.0 12.5 1 05/18/16 20:00 Sample: OUTFALL 003 Lab ID: 92296646003 Collected: 05/05/16 11:30 Received: 05/05/16 15:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2640D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 12.3 mg/L 2.6 2.5 1 05/10/16 13:08 9040 pH Analytical Method: EPA 9040 pH 6.0 Std. Units 0.10 0.10 1 05/06/16 09:30 H6 5220D COD Analytical Method: SM 52200 Chemical Oxygen Demand ND mg/L 25.0 12.5 1 05/18/16 20:00 Sample: OUTFALL 004 Parameters 25400 Total Suspended Solids Total Suspended Solids Date: 05/191201611:24 AM 1 Lab iD: 92296545004 Collected: 05/05/16 12:00 Received: 05/05/16 15:20 Matrix: Water Report Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Analytical Method: SM 2540D 54.8 mg1L 3.3 3.3 1 0511011613:09 REPORT OF LABORATORY ANALYSIS This report shall not t>e reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 13 leAnalytical ' wwwpeteiabs_com 1 ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: PREMIERE FIBERS R9-21 Pace Project No.: 92296545 Sample: OUTFALL004 Lab ID: 92296545004 Collected: 05105/161Z00 Received: 05105116 1520 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual t9040 Analytical Method: EPA 9040 pH pH 6.8 Sid. Units 0.10 0.10 1 05/06/16 09:30 H6 52200 COD Analytical Method: SM 5220D Chemical Oxygen Demand ".0 mglL 25.0 12.5 1 05/18/16 20:00 Sample: OUTFALL 005 Lab ID: 92296646006 Collected: 05/05/16 12:16 Received: 05/05/16 15:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ' 2640D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 33.0 mg1L 2.5 2.5 1 05/10/16 13:09 ' 9040 pH Analytical Method: EPA 9040 pH 7.1 Sid. Units 0A 0 0,10 1 05/06/16 09:30 H6 t 5220D COD Analytical Method: SM 52200 Chemical Oxygen Demand 97.0 mg1L 25.0 12.5 1 05/18/16 20:00 ' REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 05/19/2016 11:24 AM without the written consent of Pace Analytical Services, Inc.. Page 6 of 13 1 ' Pace Analytical Services, Inc. ® 205 East Meadow Road - Suite A aceAnalytical Eden. NC 27288 ' wwwpacelabe awrr (336)823-6921 QUALITY CONTROL DATA Project: PREMIERE FIBERS R9-21 . Pace Project No.: 92296545 QC Batch: EDEN122755 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids . Associated Lab Samples: 92296545001, 92296545002, 92296545003, 92296545004, 92296545005 METHOD BLANK: 1729704 Matrix: Water Associated Lab Samples: 92296545001, 92296545002, 92296545003, 92296545004, 92296545005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 2.5 05/10/16 13:06 . LABORATORY CONTROL SAMPLE: 1729705 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 238 95 90-110 SAMPLE DUPLICATE: 1731808 92296922001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg/L 17.4 79A 128 5 D6 SAMPLE DUPLICATE: 1731821 92296874001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg/L 141 161 14 5 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/19/2016 11:24 AM without the written consent of Pace Analytical Services, Inc.. Page 7 of 13 aceAnalytrcal ' www.pacsla"Oom QUALITY CONTROL DATA Project: PREMIERE FIBERS R9-21 iPace Project No.: 92296545 QC Batch: EDEN122737 Analysis Method: EPA 9040 QC Batch Method: EPA 9040 Analysis Description: 9040 pH EDEN ' Associated Lab Samples: 92296545001, 92296545002, 92296545003, 92296545004, 92296545005 SAMPLE DUPLICATE: 1727808 92296545005 Dup Parameter Units Result Result RPD �m 1 1 1 1 1 1 1 1 1 Std. Units 7.1 7A Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Max RPD Qualifiers 0 9 H6 Results prevented on this page are in the units Indicated by the "Units" column except where an a8emate unh Is presented to the right of the result. Date: 0511912016 11:24 AM 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 13 ' Pace Analytical Services, Inc. �rQ���_ ire® Vi J1 /`� r 205 East Meadow Road - Suite A Eden, NC 27288 ' w".paosulcom (336)623-8921 ' QUALITY CONTROL DATA Project: PREMIERE FIBERS R9-21 Pace Project No.: 92296545 ' QC Batch: WETA127648 Analysis Method: SM 5220D OC Balch Method: SM 5220D Analysis Description: 5220D COD Associated Lab Samples: 92296545001, 92296545002, 92296545003, 92296545004, 92296545005 ' METHOD BLANK: 1736167 Matrix: Water Associated Lab Samples: 92296545001, 92296545002, 92296545003, 92296545004, 92296545005 Blank Reporting ' Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand mg/L ND 25.0 12.5 05/18/16 20:00 ' LABORATORY CONTROL SAMPLE: 1736168 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers ' Chemical Oxygen Demand mg/L 750 750 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1736169 1736170 ' MS MSD 92296421009 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual ' Chemical Oxygen Demand mg1L ND 750 750 725 725 97 97 90-110 0 3 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1736171 1736172 MS MSD 92296603001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual ' Chemical Oxygen Demand mg1L 209 750 750 911 911 94 94 90-110 0 3 t 1 ' Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right or the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/19/2016 11:24 AM without the written consent of Pace Analytical Services, Inc.. Page 9 of 13 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 acoAnalytt+cal QUALIFIERS Project: PREMIERE FIBERS R9-21 Pace Project No.: 92296545 DEFINITIONS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27298 (336)623-8921 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines. unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TN accredited. Contact your Pace PM for the current list of accredited anelytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-E Pace Analytical Services - Eden ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. lib Analysis initiated outside of the 15 minute EPA required holding time. IaF3ia[i>ryf E•IP�r);[."tiflF�l1►1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc - Page 10 of 13 acemalxical www.pKwbs.com Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 ' Project: Pace Project No.: QUALITY CONTROL DATA CROSS REFERENCE TABLE PREMIERE FIBERS R9-21 92296545 Analytical Lab ID Sample la QC Batch Method QC Batch Analytical Method Batch 92296645001 OUTFALL 001 SM 2540D EDENI22755 ' 92296645002 OUTFALL 002 SM 2540D EDENI22755 92296WO03 OUTFALL 003 SM 2540D EDENI22755 92296545004 OUTFALL 004 SM 2540D EDENI22755 92296645005 OUTFALL 005 SM 2540D EDEN122755 t 92296545001 OUTFALL 001 EPA 9040 EDENI22737 92296545002 OUTFALL 002 EPA 9040 EDEN122737 ' 92296545003 92296545004 OUTFALL 003 OUTFALL 004 EPA 9040 EPA 9040 EDENI22737 EDEN122737 92296646005 OUTFALL 005 EPA 9040 EDENI22737 92296545001 OUTFALL 001 SM 5220D WETA127648 92296645002 OUTFALL 002 SM 5220D WETA127648 92296646003 OUTFALL 003 SM 52200 WETA127648 92296545004 OUTFALL 004 SM 5220D WETAl27648 92296545005 OUTFALL 005 SM 5220D WETAl27648 1 1 1 1 1 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/1912016 11:24 AM without the written consent of Pace Analytical Services, Inc.. Page 11 of 13 1 ae�Analytical' ,.R , CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed 20rUrat*. - Section A Section B Section C Page: at f d Required Client Irdamadan: Required Project Information: Invoice Infptmation: - Company. Report TO: tle N ntion: - 2038611 Address: Copy To: Company Name: R_ EGULATORY AGEH.CY rew f NPOES r . GROUNDWATER DRINKING WATER_ r UST f RCFW OTHER Fanal To: PyrT/te5e Order NO.: rj / +PWN� Phone: Fax: Project Name: Prajetl SkeLoe8ltdn /e, ! .S S7ATF: - 5 Requested Due DatprrAT: Project Number: / Profile A[ Requestsd Anatysis Fiita'eif;{Y1N) ' Section D Matrix Codes Raclrrt aaCfient inrarrr,etton MATRlx r CODE 9 COLLECTED Preservatives a' _ Ddradnp water Ow g L) zz water VO T waste water WW y a 11 ty �n V - - Product P START FJyOnGFL4S 9 St>iI15OWd . SL g i c9. p �► �' SAMPLE ID w� cc W WOL I (AMUSTB) Air AR p (L a Semple IDS MUST BE UNIQUE TLssua TS O - [] a Fm j(00 Other OT X m w Z O m O c - n < yr d E; ut ~ m O n fn _ _ = a z Z 7 L rn DATE TIME DATE TIME O say IY PACs Project NOJ Lab I.D. ;'-00 :x. O /!dd B: =9: 10 12 - ADDITIONAL COMMENTS , - - RELINQUISHED BY./ AFFILIATION DATE - , - �.TmE ACCEPTED BY 1 AFFILIATION - _ DATE . ' . -- TIME SAMPLE CONDITIONS l 3261 SAMPLER NAME AND SIGNATURE _ v o a z ORIGINAL s 8 8 c PRINT flame of SAMPLER: m " SIGNATURE of SAMPLER: �/} DATE Signed v N E J 'Important Note, By sWhV tNs tarns you we aompting Parana NET 30 day payment terms and agreemg to late Charges d 1.5% per uOrM for any krd0i;es not 30 days. F-ALL-0-020rev.07, 15-May-2007 1 1 1 1 1 1 s Doc(tmf I�[arre: ; 5 le<;Cond(tton; 90_016co!ptfscug . Document Revised, 26FEB2016 Page. I of 2 ', Docur7i4ntN6.:,. •IssufngAu�hority:`•. cgnaica!•. FER1yI-05=Q0jli a 13. Pace Eden Qua Office RBceiiH - outer: e ULIPS BUSPS ',jCffe ❑ Commercial Pace]Other CustodySeal Present? Yes jto Seals Intact? : , . ElYes ❑fVo Date/initials Peraan Examining CanDe� 1? 11 4P Packing Material: j]Bubble Wrap . []Bubble Bagsipna �Oxher; ►� Theirttome4er.' [j IR Gun E.DOD7. Type of I .�": ' et ❑8fue.,; None [�$ampieson fc `cgoling process has beg Correction Factor. 0.0'C .. Cooler Temp Corrected ('Cj. / `.. Biological Tissue Froren?.: ,Yes ❑No,' . ❑N/A .: »l Temp should be above freexfng to VC USDA Regulated Soi! ([f N/A, ,hater sample} Did samples originate In a quaMntlne zone within the United States CA, NY, or SC (check maps}? Dfd samples originate from a foreign source {fntematlonaliy, .. _ ' .IriYax No � .: ...... . :. .. inciudine itawall and Diierto Ricoi&:. Yes No, CGMMFM[S: Chain of Cuskil y Present? Yes Na N A 1 Chain of Cusco Filled Out? Yes . NN o A' .2. Chaln.of CustodyRelln wished? Yes'EINO. ONIA 3 Sam Ier.EVama`an orSl ature.onCDC? es No NA 4, -'Sam IesAMvedwithIn Hold•Tlme? • .,•.., Yes... . No,: A: ,S:.:: : . -Short 101d -nme Ana[ s A2 hr ?.: hush 7urridroundTtnie R" "ue+`tcd? .:.: : :Yes' ' o= N Sufticlentvolume? t: es No 0 N A 8. Correct Coiztalners Used? as ©No... ©NIA 9. , -Pace Containers Used? Cho N A Containers Intact? Yes No Filtered volume.Recelved for Dissolved Tests? Yes QNo A 11 Note If sediment is visible In the dissolved container'. . Sample Labels Match CDC? Yes" j F o r f 110k,. in, - .. ::-Includes Aate/11rn D/Ana . fs.. Matrix: :VIA Al containers needing;add/base preservation have been chgckea? . pYes �No ©NIA ' Ali containers needing preservation ere found to be in compllanoewfth EPA recomrnendation?,, 'ONO (HNOs, 1`12SOy HCId, NaOH>9 Sulfide, NaOHn12 Cyanide) jes ©WA Fxceptlons: VOA, Coliforr irTOC,'DII and.Grease, E DRO/8015 water DOC,LLH 13Yes No N A Sam les shedted for dechlorination Yes No : NIA : 14 Hea dspace in .V•f}A Vlais Trip Blarik Preseint7 ©V s J []No N 16. Pace Trl Blank Lut# (ff urohased r � , Trip 81ankCustody$,ealsPresent? GdENf NOTlf117T014JRESDLUTION:, . FieldRequlred? s 1 Person Contacted, L Date/lime: 1 I °?• � Comments/Resolution: . Project Manager SCURF Review: Date:. i Project Manager SRO Review: Date: } Note: Whenever there is a discrepancy affecting North Carolina tompliance samples; a copy of this form will be sent to the North Carolina DEHNR Certificationf.13 of'13 . Out of hold, incorrect preservative, out ofternp, Incorrect contelners) 1 1 1 1 1 1 1 i 1 M4WZAT E R E ENVIRONMENTAL, LLC 401 WATERS EDGE DRIVE, SUITE 201 a RALEIGH, NC 27606 • PHONE 919.859.9987 • FAx 919.859.9930 November 18, 2015 A NCDEQ Division of Water Quality Central Files 1617 Mail Service Branch 00*b RECEIVED Raleigh, North Carolina 27699-1617 4;40 MAY S 1 2016 Reference: Year I - Period 2 Stormwater Monitoring Report Premiere Fibers Facility CENTRAL FILES DWR SECTION Ansonville, North Carolina Stormwater Permit No. NCS000528 Waters Edge Job No. 119-21 To Whom It May Concern: We are presenting the stormwater monitoring report for Year I- Period 2 in . All results are within required parameters We have attached the DMR, SDO, and laboratory analytical results -see Appendix A and B). If you have any questions, or if we may be of further assistance, please contact me at prahn@watersedaeenv.com or 919.859.9987. Sincerely, Waters Edge Environmental, LLC Phillip L. Rahn President cc: Mr. Dewey Fulton and Mr. Kevin Bowers- Premier Fibers 15-090 rs am 111111110 ILIUM r WON r MW r am r 11110r � 11111101 ■r- ■r 111110M ■ter Permit Number: NCS 000528 Certificate of Coverage Number: NCG FACILITY NAME Premiere Fibers STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT or SAMPLES COLLECTED DURING CALENDAR YEAR: 2016 (This monitoring report shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) PERSON COLLECTING SAMPLE(S) T. Haynes CERTIFIED LARORATORY(S) Pace Lab # 633 Lab # Part A: Specific Monitoring Requirements COUNTY Anson PHONE NO. (704) 826.8321 ; (SIGNATURE OF PERMITI'EE OR DESIGNEE) By this signature, I certify that this report is accurate complete to the best of my knowledge. Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes ✓ no (if yes, complete Part B) Form SWU-246-112608 Page 1 of 2 � NMI M r N.M � � zlw r .ter .�■� .� �■�. Part B: Vehicle Maintenance Activity Monitoring Requirements STORM EVENT CHARACTERISTICS: Date 5.5.16 Total Event Precipitation (inches): 0.16 Event Duration (hours): NIA (only if applicable — see permit.) (if more than one storm event was sampled) Date NIA Total Event Precipitation (inches): Event Duration (hours): (only if applicable — see permit.) Mail Original and one copy to: Division of Water Quality Attn: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the 'information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." a��- V-S—iiwture of Permittee Zv Zc7l (V Date Form SWU-246-112608 Page 2 of 2 STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT Permit Number: NCS 000528 Certificate of Coverage Number: NCG FACILITY NAME Premiere Fibers PERSON COLLECTING SAMPLES) T. Haynes T or SAMPLES COLLECTED DURING CALENDAR YEAR: 2015 (This monitoring report shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) CERTIFIED LABORATORY(S) Pace Lab # 633 E❑ zPb # CENTRAL_ ALES Part A: Specific Monitoring Requirements DINR SECTION COUNTY Anson PHONE NO. (704) 826.8321 0. -3 (SIGNATURE OF PERNIITTEE OR DESIGNEE�-" By this signature, I certify that this report is accurate comillete the best of my knowledge. ,;Outfall_ No.,:--- ._.Date Sample e Collectd. ,Total Ratnfall� r Total,. Suspended ti _ CODP - _ _. w -- -0 '�_- _ �� mo/d�f�r�- =' inches—".� '--• mg/l : 1 11.3.15 See Below 5.5 ND 6.7 2 11.3.15 38.2 ND 6.5 3 11.3.15 15.1 ND 6.0 4 11.3.15 6.5 ND 6.3 5 11.3.15 5.9 ND 6.3 _ Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes ✓ no (if yes, complete Part B) Form SWU-246-112608 Page 1 of 2 Part B: Vehicle Maintenance Activity Monitoring Requirements a=0utfa[I� 1Vo�'��_ WN mute �S$inp�� s„mColieCted _ a �vfsFlow p`i5nspen " TotalRainfall Oilrfi. Gr a m Total �� ieu _ n pH N w Mnto Oif rn,0- Units il/i�a STORM EVENT CHARACTERISTICS: Date 11.3.15 Total Event Precipitation (inches): 0.14 Event Duration (hours): NIA (only if applicable — see permit.) (if more than one storm event was sampled) Date NIA Total Event Precipitation (inches): Event Duration (hours): (only if applicable -- see permit.) Mail Original and one copy to: Division of Water Quality Attn: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Si tore of Permittee 1r 19 Z�15 Date Form SWU-246-112608 Page 2 of 2 WATERS EDGE ENVIRONMENTAL., LLC 4901 WATERS EDGE DRIVE, SUITE 201 • RAI.EIGH, NC 27606 • PHONE 919.859.99$7 9 FAx 919.859.9= November 18, 2015 NCDEQ Division of Water Quality Central Files 1617 Mail Service Branch Raleigh, North Carolina 27699-1617 Reference: Year 1- Period 2 Stormwater Monitoring Report Premiere Fibers Facility Ansonville, North Carolina Stormwater Permit No. NCS000528 Waters Edge Job No. 119-21 To Whom It May Concern: RECEIVED NOV 2 3 2015 CENTRAL FILES DWR SECTION We are presenting the stormwater monitoring report for Year 1- Period 2 in 2014-2015. All,results are within required parameters We have attached the DMR, SDO, and laboratory analytical results -see Appendix A and B). If you have any questions, or if we may be of further assistance, please contact me at prahnnwatersedReenv.com or 919.859.9987. Sincerely, Waters Edge Environmental, LLC Phillip L. Rahn President cc: Mr. Dewey Fulton and Mr. Kevin Bowers- Premier Fibers 15-090 4�•�l Stormwater Discharge Outfall (SD4) Qualitative Monitoring Report Forguidance onflling out Loris form, please visit: htta:/1h2o.enr.state. nc.us&Oorms Documents.hu0misdorms Permit No.: I NJ C1 S1 0 10 10 15 12 8 or Certificate of Coverage No.: Facility Name: Premiere Fibers County: Anson Phone No. 704.826.8321 Inspector: Thomas Haynes Date of inspection: 11.3.15 Time of Inspection: 10:30-11:30 Total Event Precipitation (inches): 0.14 Was this a Representative Storm Event? (See information below) ® Yes ❑ No Please checkyour permit to verify if Qualitative Monitoring must be performed during a representative storm event (requirements vary). A "Representative Storm Event" is a storm event that measures greater than 0.1 inches of rainfall and that - is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has;, occurred. A single storm event ma contain gp to 10 consecutive hours of no precipitation. By this signature, I certify that this report is accurate and complete to the best of my knowledge: UZ (Signature of Permittee or Designee) outfali Description: Qutfall No. 001-005 Receiving Stream: Buffalo Creek Structure (pipe, ditch, etc.) Pipe to Ditch Describe the industrial activities that occur within the outfall drainage area: Textile Manufacturing 2 Color. Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: Medium brown Pagel of 2 SWU-242-112608 L .,. ,ter: :i I al s ��.. :,� .I f..�i � �� � i _ r �r. .,. ii i. � �1 r i, . , r• 3 Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): No odor noted 4 Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: O 2 3 4 5 5 Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: 1 0 3 4 5 6 Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy: 1 O 3 4 5 7 Is there any foam in the stormwater discharge? Yes No 8 Is there an oil sheen in the stormwater discharge? Yes No 9 Is there evidence of erosion or deposition at the outfall? Yes No 10 Other Obvious Indicators of Stormwater Pollution: List and describe None Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 SWU-242-112608 /55'ceAnalytical" rwww.pawlabs.com I November 12, 2015 Mr, Phil Rahn Waters Edge Environmental 4901 Water's Edge Drive Suite 201 Raleigh, NC 27606 RE: Project: PREMIERE FIBERS R9-21 Pace Project No.: 92274714 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Dear Mr. Rahn: Enclosed are the analytical results for sample(s) received by the laboratory on November 04, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sam ple anaiyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, "au*N- cal . AJ d�YU Brittany Gibson brittany.gibson@pacelabs.com Project Coordinator Enclosures REPORT OF LABORATORY ANALYSIS This report shell not be reproduced, except in full, Without the written consent of Pace Analytical Services, Inc,. Page 1 of 15 a xftlytical � www.pscefaOs.00m E Project: PREMIERE FIBERS R9-21 Pace Project No.: 92274714 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Asheville Certification IDS 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #; E87648 Massachusetts Certification #: M•NCO30 North Carolina Drinking Water Certification #: 37712 Eden Certification IDS 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 40 South Carolina Certification M 99030001 West Virginia Certification #: 356 VirginiaNELAP Certification #: 460222 North Carolina Wastewater Certification #: 633 VirginiaNELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shaft not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 15 aceAnalytical www.peoelaba.00m SAMPLE SUMMARY Project: PREMIERE FIBERS R9-21 Pace Project No.: 92274714 Pace Analytical Services, Inc. 205 East Meadaw Road - Suite A Eden, NC 27288 (336)623-8921 Lab ID Sample ID Matrix Date Collected Date Recelved 92274714001 OUTFALL 001 Water 11/03/15 12:00 11/04/15 16:15 92274714002 OUTFALL 002 Water 11/03/15 12:15 11/04/15 16:15 92274714003 OUTFALL 003 Water 11/03/15 12:30 11/04/15 16:15 92274714004 OUTFALL004 Water 11/0311612:45 11104/1616:15 92274714005 OUTFALL 005 Water 11/03/15 13:00 11/04/15 16:15 REPORT OF LABORATORY ANALYSIS This report shall not De reproduced, except in full, without the written consent of PaceAnalytical Services, Inc.. Page 3 of 15 aceAnalytical° www.pac&Mbs.com SAMPLE ANALYTE COUNT Project: PREMIERE FIBERS R9-21 Pace Project No.: 92274714 Pate Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Analytts Lab ID Sample ID Method Analysts Reported Laboratory 92274714001 OUTFALL D01 SM 2540D DWJ 1 PASI-E EPA 9040 KCE 1 PASI-E SM 5220D WRC 1 PASI-A 92274714002 OUTFALL 002 SM 2540D DWJ 1 PASI-E EPA 9040 KCE 1 PASI-E SM 52201) WRC 1 PASI-A 92274714003 OUTFALL 003 SM 2540D DWJ 1 PASI-E EPA 9040 KCE 1 PASI-E SM 5220D WRC 1 PASI-A 92274714004 OUTFALL 004 SM 2540D DWJ 1 PASI-E EPA 9040 KCE 1 PASI-E SM 5220D WRC 1 PASI-A 92274714005 OUTFALL 005 SM 2540D DWJ 1 PASI-E EPA 9040 KCE 1 PASI-E SM 5220D WRC 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Without the written consent of Pace Analytical Services, Inc.. Page 4 of 15 aceAnalj6cal www.pacefabs.com ANALYTICAL RESULTS Project: PREMIERE FIBERS R9-21 Pace Project No.: 92274714 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27280 (336)623-8921 Sample: OUTFALL 001 Lab ID: 92274714001 Collected: 11/03/15 12:00 Received: 11/04/15 16:15 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2640D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 6.6 MOIL 2.5 2.5 1 11/05/15 10:25 9040 pH Analytical Method: EPA 9040 pH 6.7 Std. Units 0.10 0.10 1 11/05/15 10:35 H3,H6 6220D COD Analytical Method: SM 62200 Chemical Oxygen Demand ND mg/L 25.0 12.5 1 11/09/15 13:40 Sample: OUTFALL 002 Lab ID: 92274714002 Collected: 11103/15 12:15 Received: 11/04/15 16:15 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 38.2 MOIL 2.5 2.5 1 11/06/15 10:25 9040 pH Analytical Method: EPA 9040 pH 6.5 Std. Units 0.10 0.10 1 11/05/15 10:35 1-13,146 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand ND mg/L 25.0 12.5 1 11/09/15 13:40 Sample: OUTFALL 003 Lab ID: 92274714003 Collected: 11/03/15 12:30 Received: 11/04/15 16:15 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Quaff 2640D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 16.1 mg1L 2.5 2.5 1 11/05/15 10:26 9040 pH Analytical Method: EPA 9040 pH 6.0 Std. Units 0.10 0.10 1 11/05/15 10:35 H3,1-16 6220D COD Analytical Method: SM 5220D Chemical Oxygen Demand NO mg/L 25.0 12.5 1 11/09/15 13:40 Sample: OUTFALL 004 Lab ID: 92274714004 Collected: 11 /03115 12:45 Received: 11/04/15 16:15 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2640D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 6.6 mg/L 2.5 2.5 1 11/05/15 10:26 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 1111212015 08:07 AM without the written consent of Pace Analytical Services, Inc.. Page 5 of 15 aceAnalytical o Www.pecelab�.com ANALYTICAL RESULTS Project: PREMIERE FIBERS R9-21 Pace Project No.: 92274714 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: OUTFALL 004 Lab ID: 92274714004 Collected: 11/03/15 12:45 Received: 11/04/15 16:15 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No, Qual 9040 pH Analytical Method: EPA 9040 PH 6.3 Std. Units 0.10 0.10 1 11/05/15 10:35 1-13,1-16 6220D COD Analytical Method: SM 5220D Chemical Oxygen Demand ND mg1L 25.0 12.5 1 11/09/15 13:40 Sample: OUTFALL 006 Lab ID: 92274714005 Collected: 11/03/15 13:00 Received: 11/04/15 16:15 Matrix: Water Report Parameters Results Units Limit MIX DF Prepared Analyzed CAS No. Qual 2640D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 6.9 mg1L 2.5 2.5 1 11/05/15 10:26 9040 pH Analytical Method: EPA 9040 PH 6.3 Std. Units 0.10 0.10 1 11/05/15 10:35 H3,H6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand ND mg1L 25.0 12.5 1 11/11/15 18:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date'. 11112/2015 08'.07 AM without the written consent of Pace Analytical Services, tne.. Page 6 of 15 aCeAnaIJ601 wwwpacelabscom QUALITY CONTROL DATA Project: PREMIERE FIBERS R9-21 Pace Project No.: 92274714 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 OC Batch: EDEN120636 Analysis Method: SM 2540D OC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92274714001, 92274714002, 92274714003, 92274714004, 92274714005 METHOD BLANK: 1599405 Matrix: Water Associated Lab Samples: 92274714001, 92274714002, 92274714003, 92274714004, 92274714005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Suspended Solids mg1L ND 2.5 2.5 11/05/15 10:19 LABORATORY CONTROL SAMPLE: 1599406 Spike LCS LCS % Rec Parameter Units Conc. Result %Rec Limits Qualifiers Total Suspended Solids mg1L 250 258 103 90-110 SAMPLE DUPLICATE: 1599407 92274792001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg1L 114 121 6 5 D6 SAMPLE DUPLICATE: 1599408 92274797001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg1L 106 124 16 5 D6 Results presaged on this page are In the units Indlcsted by fie "Units" column except where an alternate unit Is presented to the right of the resulL REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Cult, Date: 11/12/2015 08:07 AM without the written consent of Pace Analytical Services, Inc.. Page 7 of 15 aceAnalyrical o WW..patele8a.com QUALITY CONTROL DATA Project: PREMIERE FIBERS 139-21 Pace Project No.: 92274714 QC Batch: EDEN120639 Analysis Method: EPA 9040 QC Batch Method: EPA 9040 Analysis Description: 9040 pH EDEN Associated Lab Samples: 92274714001, 92274714002, 92274714003, 92274714004, 92274714005 SAMPLE DUPLICATE: 1699660 92274714005 Dup Parameter Units Result Result PH Sid. Units 6.3 6.3 Pace Analytical Services, Inc, 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Max RPD RPD Qualifiers 0 9 H3,H6 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit In presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /12/2015 08i07 AM without the written consent of Pace Analytical Services, Inc.. Page 8 of 15 ZAnalj cal o r W&Wpacelabs.com f QUALITY CONTROL DATA Project: PREMIERE FIBERS R9-21 Pace Project No.: 92274714 QC Batch: WETN25312 Analysis Method: SM 5220D QC Batch Method: SM 5220D Analysis Description: 5220D COD Associated Lab Samples: 92274714001, 92274714002, 92274714003, 92274714004 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 METHOD BLANK: 1602017 Matrix: Water Associated Lab Samples: 92274714001, 92274714002, 92274714003, 92274714004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand mg1L ND 25.0 12.5 11/09/15 13:40 LABORATORY CONTROL SAMPLE: 1602018 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg1L 750 742 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1602019 1602020 MS MSD 92274934001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone, Cone. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand mg1L 1740 3000 3000 4350 4350 67 87 90-110 0 3 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1602021 1602022 MS MSD 92274982001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc, Cone. Result Result %Rec %Rec Limits RPD RPD Qual Chemical Oxygen Demand mg1L 40.0 750 750 729 729 92 92 90-110 0 3 Results presented on this page are in the units Indicated by he "Units" colunm except where an alternate unit Is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 11 /1212015 08:07 AM without the written consent of Pace Analytical Services, Inc.. Page 9 of 15 /55'ceAna1jNca19 ! www.pacelab3.com QUALITY CONTROL DATA Project: PREMIERE FIBERS R9-21 Pace Project No.: 92274714 OC Batch: WETA125361 Analysis Method: SM 5220D QC Batch Method: SM 5220D Analysis Description: 5220D COD Associated Lab Samples: 92274714005 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 METHOD BLANK: 1604129 Matrix: Water Associated Lab Samples: 92274714005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand mg1L ND 25.0 12.5 11/11/15 18:00 LABORATORY CONTROL SAMPLE: 1604130 Spike LCS LCS % Rec Parameter Units Cone, Result % Rec Limits Qualifiers Chemical Oxygen Demand mg/L 750 771 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1604131 1604132 MS MSD 92275179002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD RPD Oual Chemical Oxygen Demand mg/L 8350 15000 15000 23900 23900 104 104 90-110 0 3 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1604133 1604134 MS MSD 92275004001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Cone. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand mg1L 5660 30000 30000 36600 36600 103 103 90-110 0 3 Results presented on this page are In the units indicated by the "Units" column except where an altemate unit Is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/12/2015 08:07 AM without the written consent of Paceanalytical Services, inc.. Page 10 of 15 11ce Analytical / wwwpeoslabacom QUALIFIERS Project: PREMIERE FIBERS R9-21 Pace Project No,: 92274714 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL- Reporting Limit. Pace Analytical services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 S - Surrogate 1,2-Diphenyihydrazine decomposes to and cannot be separated from Azobenzene using Method 8270, The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270, The result reported for each analyte is a combined concentration. Pace Analytical is TN accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-E Pace Analytical Services - Eden ANALYTE QUALIFIERS D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H3 Sample was received or analysis requested beyond the recognized method holding time. H6 Analysis initiated outside of the 15 minute EPA recommended holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/12/2015 08:07 AM without the written consent of Pace Analytical Services, Inc.. Page 11 of 15 aceAnalytical' wWWpace/aw-cam ) QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: PREMIERE FIBERS R9-21 Pace Project No.: 92274714 Lab ID Sample ID QC Batch Method 92274714001 OUTFALL 001 SM 2540D 92274714002 OUTFALL 002 SM 2540D 92274714003 OUTFALL 003 SM 2540D 92274714004 OUTFALL 004 SM 2540D 92274714005 OUTFALL 006 SM 2540D 92274714001 OUTFALL 001 EPA 9040 92274714002 OUTFALL 002 EPA 9040 92274714003 OUTFALL 003 EPA 9040 92274714004 OUTFALL 004 EPA 9040 92274714006 OUTFALL 005 EPA 9040 92274714001 OUTFALL 001 SM 5220D 92274714002 OUTFALL 002 SM 5220D 92274714003 OUTFALL 003 SM 5220D 92274714004 OUTFALL 004 SM 5220D 92274714005 OUTFALL 006 SM 5220D QC Batch EDEN/20636 EDEN/20636 EDEN/20636 EDEN/20636 EDEN120636 EDEN/20639 EDEN/20639 EDEN/20639 EDEN120639 EDEN/20639 WETA/25312 WETA125312 WETA/25312 WETA125312 WETA/25361 Pate Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Analytical Method Analytical Batch REPORT OF LABORATORY ANALYSIS • This report shall not be reproduced, except in full, Date: 11/12/2015 08:07 AM without the wrdlen consent of Pace Analytical Services, Inc.. Page 12 of 15 %, r a.a. CHAIN -OF -CUSTODY I Am"cal Request Document mnwLew.e seYewnwPewm4 wdn�nnwuwwwYwde4 Ypwpn wow4w w4wwe.a YriYNaa uwo Own e4 4Ne w a�ww4 Hale eew a •.epuw e wwN a e.w+�ewewn :eeeN :+wawa s-tYi • � OH dal l,IaM1a7 wwA+n �r1u M, yea wwwrd ' _ N Y A aw4d w-m;;"A _ -.. yw�wea :wwP4wry N^aweLIPwNLwMl7 - ' enQ •Ap - ilw-w RM AP PM X.M dill 'm 4+O NAb ,. 4UW-d IN11G OKL 4q w'U Y Whop w11N ewe•wren -AD PpA14pIWePxy WO-W "OOA9 . MD+Yo wU �wwr�Ir+uv"gp 4ee4/a4aa e>—&e U-M-lv 7� . ('7 h mwua�wmMmur -LL woo eNo �aoaw>4POwn-Am e.. 'LL wyfi..MD ." .neq PWa110 YN PO4--14-Pw4Pd 'a�w4q�4+G e•Y!q_� :MVIUWr14e'S s>Wea� wY-ew.eu :w1ua 11rnlL NwawleY a '4ml"waPww" w - e - u .O PdUntlPPv+weliwroa.Nooduwl . - �w.e wauea a wow w ewe 1 mbrM ❑ WON OW(iR:wgWMAL Iaaa3WWPWIAewww4Pw� . nla6 Iens7{' Aaggg4rp❑ duASdiPX� Nwlwlwl✓swell d ou [y wwA ❑ p11wI11rB e 7w11ati:wYwllwaa Nw 111214 MLIwa rn--wwa I td111 tdM1 nPld :IK+4+lww�nwa :oWeN }uet{o APeO rM1 Pr+Pi wW 4 CP i edad, awWp 1110 WP9 ON LL' 'Caa'BffsiO}e - ""PDwv Aulnrl I :,ON Wlwree4 .Z W l d Ra rwaaa PlaihLAePSAaayra Lulwnxq waAfl uwAVAD alp' P4u1nw0 Permit Number: NCS 000528 Certificate of Coverage Number: NCG FACILITY NAME Premiere Fibers PERSON COLLECTING SAMPLE(S) T. H CERTIFIED LABORATORY(S) Pace Part A: Specific Monitoring Requirements STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT or SAMPLES COLLECTED DURING CALENDAR YEAR: 2015 (This monitoring report shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) COUNTY Anson PHONE NO. (704) 826.8321 Lab # 633 Lab # (SIGNATURE OF PERMITTEE OR DESIGNEE) By this signature, l certify that this report is accurate=*plete to the best of my knowledge. Outfall Date No. Sample Collected Total Rainfall Total Suspended Solids (TSS) COD pH Permit Bench NIA 100 .120 6-9 mo/dd/yr inches mg/I mg/l units 1 5.1.15 See Below ND NA 6.5 =7 ■W --gel Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes ✓ no (if yes, complete Part B) Form SWU-246-112608 Page 1 of 2 Part _B.- Vehicle Maintenance Activity Monitoring Requirements i - - Total F[ow 4S1 Rsiiia.; .:.Q�1&:Greaser : - Toiai pH =11FeiT plQtor O':: :... .:....:.....:... 1lected : • --a tiealife� �l - tt�p y:S nded` - gsllio: STORM EVENT CHARACTERISTICS: Date 5.1,15 Total Event Precipitation (inches): Event Duration (hours): NIA 0.12 (if more than one storm event was sampled) Date NIA Total Event Precipitation (inches): Event Duration (hours): (only if applicable — see permit.) (only if applicable — see permit.) Mail Original and one copy to: Division of Water Quality Attn: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Sign re of Permittee i Z/b Date Form SWU-246-112608 Page 2 of 2 d4WATERS EDGEENVIRONMENTAL, LLC 4901 WATERS EDGE DRIVE, SUITE 201 • RALEIGH, NC 27606 • PHONE 919.859.9987 • FAx 919.859.9930 May 14, 2015 NCDENR Division of Water Quality RECEIVED Central Niles May 2 r 2015 1617 Mail Service Branch Raleigh, North Carolina 27699-1617 CEN-rPAL FILES DWR SECTIQN Reference: Year 1- Period 1 Stormwater Monitoring Report Premiere Fibers Facility Ansonville, North Carolina Stormwater Permit No. NCS000529 Waters Edge Job No. R9-21 To Whom It May Concern: We had originally reported the stormwater monitoring; report for Year 1- Period 1 in 2014-2015. All results are within required parameters with the exception of a TSS exceedances for Outfall #1 (TSS detected at 231 mg/L versus a 100 mglL benchmark) and a pH exceedance at Outfall #1 pH detected at 4.0 versus a benchmark at 6-9). However, we conducted a Tier 1 inspection on March 3, 2015 and had a crew clean out trash that had accumulated in the Outfall. Subsequent to this cleanup, a 6.0 pH was detected using Litmus paper. On May 1, 2015, we remobilized and resampled Outfall #1 for TSS and pH. Both parameters were below benchmark levels (DMR, SDO, and laboratory analytical results -see Appendix A and B). If you have any questions, or if we may be of further assistance, please contact me at prahn@watersedpeenv.com or 919.859.9987, Sincerely, Waters Edge Environmental, LLC Phillip L. Rahn President cc: Mr. Dewey Fulton and Mr. Kevin Bowers- Premier Fibers 15-050 Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance on filling out thisform, please visit: ligp://li2o.enr.state.nc.us/su/Forms Documents.htm#miscforms Permit No.: LN J C! S 1 0 10 10 15 12 18 or Certificate of Coverage No.: _ Facility Name: Premiere Fibers County: Anson Inspector: Thomas Haynes Date of Inspection: 5.1.15 Time of Inspection: 10:3D-11:30 Total Event Precipitation (inches): 0.12 Phonc No. 704.826.8321 Was this a Representative Storm Event? (See information below) ® Yes ❑ No Please check your permit to verify if Qualitative Monitoring must be performed during a representative storm event (requirements vary). A "Representative Storm Event" is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0. l inches has occurred_ A single storm event may contain up to 10 consecutive hours of no precipitation. By this signature, I certify that this report is accurate and complete to the best of my knowledge: (Signature of Permitter or Designee) 1 Outfall Description: Outfall No. 001-005 Structure (pipe, ditch, etc.) Pipe to Ditch Receiving Stream: Buffalo Creek Describe the industrial activities that occur within the outfall drainage area: Textile Manufacturina 2 Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: Medium brown T%___ 1 _rn 1 1 3 Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): No odor noted 4 Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: 1 0 3 4 5 5 Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: 1 O 3 4 5 6 Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy: O 2 3 4 5 7 Is there any foam in the stormwater discharge? Yes No 8 is there an oil sheen in the stormwater discharge? Yes No 9 Is there evidence of erosion or deposition at the outfall? Yes No 10 Other Obvious Indicators of Stormwater Pollution: List and describe None Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 SWU-242-112608 r ceAnalyical May 08, 2015 Mr. Phil Rahn Waters Edge Environmental 4901 Water's Edge Drive Suite 201 Raleigh, NC 27606 RE: Project: PREMIER FIBERS Pace Project IVo.: 92248039 Dear Mr. Rahn: Pace Analytical Services, Inc. 205 East Meadow Road • Suite A Eden, NC 27288 (336)623-8921 Enclosed are the analytical results for sample(s) received by the laboratory on May 04, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Terri Page terri.page spacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 12 eeAnalytr'eal wxw.paoalabs:com Project: PREMIER FIBERS Pace Project No.: 92248039 Pace Ana VicaI Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-6821 Eden Certification IDS 205 East Meadow Road Sufte A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification X: 633 Virgin"ELAP Certification 4: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of PamAnaMical ServbM Inc, Page 2 of 12 eeAnalylical www.patxNde.ram Project: PREMIER FIBERS Pace Project No.: 92248039 Lab ID Sample 10 92248039001 Ot.1TFALL 001 SAMPLE SUMMARY Matrix Date Collected Date Received Water 05/0111612,00 05/04/1511:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, wMuxd the written content of Pere Analytical Services, Inc., pace Analytical Services, Inc. 205 East Meadow Road - 50e A Eden, NC 27288 J336)623-N21 Page 3 of 12 ceAnaVical wrvw.paoelels.can SAMPLE ANALYTE COUNT Project, PREMIER FIBERS Pace Project No.: 92248039 Pace Anayttcat Services, Inc: 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Analyses Lab tD Sample ID Method Analysts Reported Laboratory 92240039001 OUTFALL 001 SM 2540D JTF 1 PASI-E EPA9040 DWJ 1 PASI-E REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In Tull, without the written consent of Pace Analytical ServloM Inc,. Page 4 of 12 aceAnalytrcal wnryaceleLtcom ANALYTICAL RESULTS Project: PREMIER FIBERS Pace Project No.: 92248039 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623489z1 Sample: OUTFALL 001 Lab lD: 92248039001 Collected; 05101115 12:00 Received: OS10411511:45 Matrix: Alater Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 25 0D Total Suspended Solids Anatylical Method: SM 2540D Total Suspended Solids ND mg1L 2.5 2.5 1 05/05115 09:34 9040 pH Analytical Method: EPA9040 PH 6.6 Sid, Units 0.10 0.10 1 0510411514AS 1-13,1-16 Date: 05108►2015 04:02 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analyhcal Services, Inc, Pags5of12 wAnaly ical' www.pxalebe.com QUALITY CONTROL DATA Project: PREMIER FIBERS Pace Project No.: 92248039 QC Batch: EDEN118370 Analysis Method: SfM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92248039001 METHOD BLANK: 1449910 Matrix: Water Associated Lab Samples: 92248039001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg1L NO 2.5 05105/15 09:27 Pace Ana tytical Services, Inc: 205 East Meadow Read - Suite A Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE: 1449911 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Total Suspended Solids mglL 250 224 90 90-110 SAMPLE DUPLICATE: 1449912 92247745M Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg/L 32.6 28.2 15 5 D6 Results presented on this page are in the unRs hrdlcated by the "Unks" column except where an akemMe unR Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 0510812015 04:02 PM witt*ut the written consent of Pace Analytical Services, Ina. Page 6 of 12 IeArralytical twnxpt owshtwn 14111141fatial011 Mal 49L-iEl Project: PREMIER FIBERS Pace Project No.: 92245039 QC Batch: EDENl18361 Analysis Method: EPA9040 QC Batch Method: EPA9040 Analysis Descriptlon: 9040 pH EDEN Associated Lab Samples: 92248039001 SAMPLE DUPLICATE: 1449559 Parameter PH Pace Analytical Services, Inc. 205 East Meadow Road - 8Oe A Eden, NC 27288 (336)623-8921 92248039001 Dup Max Units Result Result RPD RPD Qualifiers Std, Units 6.5 6.6 0 9 H3,H6 Results presented on thfa papa an to the unite fndkatsd by the " 11nlh" catumn except when an alternate unit Is presented to thedpht of theresult. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except fn full, Date: 05108=15 04:02 PM wfthout the wr ten consent of Pace Analytical Services, Inc . Page 7 of 12 I f Pace Analytical Services, Inc: e/'!nalytka'e 205 East MeadowEden, NC 27288 rKva' mn (335)623Z921 QUALIFIERS Project: PREMIER FIBERS Pace Project No.: 92248039 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection Iimit and below the adjusted reporting limit, MDL -Adjusted Method Detection Limit. PQL - Practical Quantftatfon Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenythydrazine decomposes to and cannot be separated from Azobonzone using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guldelines, unrounded data are displayed and have been used to calculate % recovery and RPD values, LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD- Relative Percent Difference NO - Not Calculable. SG - Silica t,yel- Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethytvinyt ether, Styrene, and Vinyl chloride, A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acro lain and Acrylonitr€le by EPA Method 8260. N-Nitrosodlphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte Is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Inst€t w. LABORATORIES PASI-E Pace Analytical Services - Eden ANALYTE QUALIFIERS DO The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits, M3 Sample was received or analysis requested beyond the recognized method holding time. H6 Analysts initiated outside of the IS minute EPA recommended holding time. Data: 0510812015 04:02 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of pace AnalyN l Servicea, Inc. Page 8 of 12 i P9ce Analytical Services, Inc. �t __ f, 1f,,,, f 205 East Meadow Road -Sulfa A Ce�f�jl�/�0 VEdon, NC 27288 www.P9Wbba0om (336)623-8921 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: PREMIER FIBERS Pace Project No.: 92248039 Analytical Lab tD Sample ID QC Batch Method QC Batch Analytical Method Batch 92248039001 OUTFALL 001 SM 2540D EDEN/18370 92249039001 Ot1TFALL 001 EPA 9040 EDENl18381 Data: OW81201 S O4:02 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. Page 9 0112 • . . ,CE�;/lai}ItICc� b�� etie CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain-of-GRrAndy Is a LEGAL DOCUMENT. M mleveMSelds must be completed a=rately. Seetbat A section a Section G Pagei of Required Client Irlforrrratlon: RoClubed Prpjept lnfomratlnn: Irivoic a trove sttam: • - �. RcpanTo: 1913 5 0 3 - Copy TO: (, Cam Nmne: pant EGl11A70RY RAddrem r NPDES r GROUNID WATER {' DRINKING WATER r UST r RCRA OTHER -44 Email To; PUrdu a Order No-, l + Pace CA$06B Phone: Fax ProjectNama:.Plac�a.A.n�lsct < w r % V 4_ ..00ll.• Srl ♦ - `6. EI i� ;} r _4 '�' -. fi ReqLawaeed Duo DaWTAT; Fro Number. Pace Pwme - t�6gUB5YCC AnalyslS 11�D[ti •,1 t<}��s � - r' l 1 :l D Section ltetrts code, Mo*med CSaat htknyddkm FMTRUc 1 00�� s COLLECTED Preservatives- DriokinB Water DW U- Water WT- V4aste Water WW Product P -_ Solusadd SL . 8 m ¢� U CONFosrrE araxT Catposrm ENDPO M w .._: , ,:',; Z . SAMPLE ID CHI OL IMepe us z im: C (A 2 o-91: 1 Air AR AR Sample IDS MUST FIF UNIQUE Tissue TS p LU a • Other OT I< X La d Op ern 2 = L Z O W. - DATE TIME tM1>: TIME # Pace Project No.i Lab I.D. fa 2 La`�` — Vz" c-: ^.z_ - CBI '}' - - AaBITIQNIII EN'f3 :'l _.2- ti RFJJPtQlASttHb B`F:7y1FFt[.W1107f '. i 1-t7AiTE a ASxEP�ED 61!r.AFFtL!!4T1C�Mr'",. D�7E-.- i11AE - SAKPLP CONDRIONS ,� { . ,-TWE _ �C•.NATHBE 7 "r•"•'T L-AND -. t ..l - n' ` x '.7. '� _ M1 �-. u_ :n<!� U C 0 g Y! a ;��.� .as :�_,a ,�_,+r._ __, i�_ �z .�:, rid.... ORIGINAL 3 � PRINT Name of SAMPLER: SIGNATURE of SAK: � TE S!Wwd rM 'W%XWtary Nate: By spog 7hsfraas Vow are vm*pWV Pain's NET W day payr*" tame and agreakg to 4te Charon eI 1,9% per.—.d iX erry i oat pact rrt days. f /' F-AU.-0-020mv_07.1544ay-2007 CHAIN -OF -CUSTODY 1-Analytical Ret�uest'Wcument ace 1�,� r.. The Ctwk.os.cusMdr o a LEGAL DOCUM84T. an relevant dales Muir be, a=UtafetY Ssotlorl A SacLion B Sestlon C. . Pope "°} f aqui" Clfmtlnbmrenon- - .. ..---RegU_ d, jerslnlomzeUon_ �: Irnalce,IrNarit>atlorK - - Ad Copy TO: Company Name: Il3lf1 A_ai%1[ A(sEl1GY, b w x 1 Ad": - < F ;,NPi7ES" is'. GROUND WATER . -T- : '- DRINMNG WATER E�: UST - �' . RGRA � �' OTHER Email To: : - Purctme Order No.: Pace OuoY Phone: _ Fmr: Frojeef Name: rrpwe- e RegrrestsQ Dw DatefTAT: - - ;?roJect Number- . ,. Pace P"%=t'' 3 1 ?. . smc D -iAatriz Codes _ - ` ' - `. r ' lq�t..uienrt Sr97Slx r eOOE COLLECTED : Preservatives" v, _ �. DAnkW q water DVV - _ water- WT ' wails - water 4YSftr Sa7US°Id : - -' SL- SAMPLE ID wipe u P o . mQ Aft AR a Sampfe lCs MUST HEUNIQUE - Tissue TS Cj .O w a m % - -.Other - OT � .. X W .� - W. L.1�- O nzcx� m �, DATE 7ltufE DATE- ' T1N[E 2 2 m Z O ':: -. .tit+ =' Gt MiOa('i:ab lA: - ilfa : n: --; - - - - - SAMILEGbllil[TIONS , - _ •2 "s..i iiTr.' � � .Z4 __ T.. 4-._6s.. 1 .4,-- S-_.�uF li U =i r\ _ >` y POW" me of SAMPLER-�Y r �j 4 - .� ? � . ' • src;WaTifttE of si►11tx.� � � DATE • .. - �,. ry u ai F-f.ILd1-o2orev.o7.5-W 1.zoo7'- _ :' 'mipaRaac rbm: By r$>wq tMa farm yon Net 3D day axr-0iirq Pacaf payrirat fame mid apraeeip b Sate tLerges.d 19Y. permpnth trN e!ry Irnnlcar,rwt Pa1d days. _ . Y - - Raourment Name; �aBnpQl C[yaitf[a;U[a~p.; Recei L SCUR .: Y - ,:. i�vcu�neh D[e�Rvised; March 13, 2013 P6 f aft ._ . Elocumeiit No.., Issuing',4iathorr#Fes F-EE)N-G3-0Q3-rev-6,,. -:.:.:..;,:. .. Pace Edeti Q"Ry Oitice Client Name..- 1 ka .. -' k More Received: H'UnteraAfie n -As he Mle Eden Ralei h Courier {circle): Fod Ex UPS LISPS la Commercial pace offier ; 0,stody Seal on Gooier/Sox Presarw Eyes do :' 5eais intact: ❑ yes ❑ no Packing MaterIal: [Duhble Wrap ° ❑Bubble Bags 2None ❑ Other 7hermamefer used: lR Guri.EDOQ7:: -; : _ Type of ice Wet flue hlone 0Sarrtples an ice, oaal process}ias o . _. �.. Temp Carrectien Faotari Acid / '[�[}tr ct Correctedo0mbQr Um ..' C Blofolcal Tissue is Froaen ,< 1 ea' No NIAfe`atd'fMl person ' p 'contents: TaV dio0ba above haezing Chain et GuLtoPresent:.: ' Yea :'qNo .`iIwA f.: '. Chain of:Ctra ' FIRM Qut . ea QNa CIA Chain of Cti e8` ulshad: es ©too•,• Sa } er N a & Si Net # on GOC: I'es �.lnta CiNli4 4: es° �wlihlCi Nald.Tlm@' s Yes., CiNa. Short Noid.T a is: 42fu : QYea,. Ka... C]t r/.4 Tuip Arourid.Tinta esteds. CIO ); 6uf iden4 Voktme: es; pNe CIWA owed t oritalnere,E3ssd: es CINo ;' oi�n g. -geae,GQiital in Used:, xres : ©No ':13w GonTa lrEtac Yes:,Ch@o i to 10. Ffliered vohane recalved for plssolved tests C7Yes E]Na tv1A 11: r . ; w ., Yr K ; �c 's .,Y • • Satnple labsls metch 000: a .,.. O wA. 12-, . -... ....._.. ,. •.:.... , .. , . .. 4noludes daielthnall s MaMx` _ . ... _ ...... .. :.: �.. . +arsW" pteaa have been oheo" l pin are found to ba In , CIYes NO i�NlA 4 Mmpllanoa V�tit I:PA rocamtnerrc�lon.. Y4A, oordosm, UkCi,1Nt R OY4gONa INQatwhen s ` .... tar de�Eoiln�fEatfr .. • , pYBs:G]No-` A •��: >. � �",•�;:�;n,:;>.;;.:.. Trip Bfank Present:..... Clrae . Utso.. ifi.... _ . Do Bunk ftcistCdY8et preiettt _ P'aw TO Btankt.dt• ,. rceias` :.•.. :_ ..._. Citant Notiflcadonl Resotudon: Reid Data R%MW? Y Sew Ftevl SRC ii9YieW. Daft 4 Note: V lag ffi Il(j N"', ' ss piea, &Q7py0(till3 foim wiN bo ae� to th6 Re[th DEHMR ;+ s • ;. rmloadon Oft (Le out 01 h*, anoonsot prewm%,% out of temp; ';� { 4 c hmmaotoonts sm) ge 12 of 12 WATERS EDGE ENVIRONMENTAL. LLC 901 WATERS EDGE DRIVE, SUITE 201 • RALEIGH, NC 27606 • PHONE 919.859.9987 • FAX 919.859.9930 MEMORANDUM Date February 3, 2015 To Mr. Dewey Fulton and Ted Kalamatas - Premiere Fibers From Mr. Phil Rahn - Waters Edge Subject April -September 2014 Stormwater Sampling Problems Premiere Fibers Ansonville, North Carolina Stormwater Permit No. NCS000528 Waters Edge performs the Stormwater sampling for the Premiere Fibers facility located in Ansonville, North Carolina (Stormwater Permit No. NCS000528). We conducted the Year 5- Period 2 sampling on March 18, 2014 and had several exceedances of benchmark standards. Based on the permit, a Tier I inspection was conducted and then an additional sampling round was conducted on April 15, 2014. Since the permit had expired, our sampler believed that the sampling conducted on April 15, 2014 would suffice for the April - September 2014 period of the new permit which we had not received. Based on additional conversations with Premiere, it is our understanding that NCDENR disagrees that this April 2014 sampling would suffice since it was for a subset of the required analytical parameters. This was an error by our sampler and we regret the oversight. We are being forwarded a copy of the new permit and will comply with the sampling requirements for October 2014-March 2015 time period. If there are any questions, please contact me at prahn@watersedgeenv.com or 919.219.5820. MWAT,�ERS EDGE ENVIRONMENTAL, LLC 4901 WATERS EDGE DRIVE, SUITE 201 • RALEIGH, NC 27606 •PHONE 919.859.9987 • FAx 919.859.9930 April 28, 2014 NCDENR Division of Water Quality Central Files 1617 Mail Service Branch Raleigh, North Carolina 27699-1617 Reference: Year 5- Period 2 Stormwater Monitoring Report Premiere Fibers Facility Ansonville, North Carolina Stormwater Permit No. NCS000528 Waters Edge Job No. R9-21 To Whom It May Concern: We have previously submitted a stormwater monitoring report for Year 5- Period 2 in 2013-2014. All results were within required benchmark parameters with the exception of a TSS exceedances for Outfall #1 (TSS detected at 366 mg/L versus a 100 mg/L benchmark) and several pH exceedances (Outfall #1 at 5.9, Outfall #2 at 5.9, Outfall #3 at 5.8, and Outfall 44 at 2.8.. It was concluded that the TSS exceedances was due to significant construction activities associated with a building expansion in that area of the site. Most of the pH exceedances were near the lower 6.0 lower benchmark and could be due to causes that are beyond the control of the facility (e.g. acid rain). However, the 2.8 reading at Outfall #4 was considered to be anomalously low. During the sampling, we saw no unusual characteristics (color, turbidity, etc.) that would indicate anything out of the ordinary. However, we conducted a Tier 1 inspection on April 9, 2014 and there wasn't anything unusual noted at the Outfall. On April 15, 2014, we returned to the facility and resampied Outfall 41 (TSS) as well as Outfall #144 (pH) and all parameters were within the benchmark parameters (SDO, DMR, and analytical results contained in Appendix A and B). This was conducted subsequent to the expiration of the stated permit on March 31, 2014. We have applied for a permit renewal. We will record the Tier One response in the Stormwater Pollution Prevention Plan (SPPP). If you have any questions, or if we may be of further assistance, please contact me at prahnnwatersedgeenv.com or 919.859.9987. Sincerely, Waters Edge Environmental, LLC -;;� 4 74,o�e, Phillip L. Rahn President cc: Mr. Dewey Fulton and Mr. Kevin Bowers- Premier Fibers 14-037A Permit Number: NCS 000528 Certificate of Coverage Number: NCG STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT SAMPLES COLLECTED DURING CALENDAR YEAR: 2014 (This monitoring report shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) FACILITY NAME Premiere Fibers COUNTY Anson PERSON COLLECTING SAMPLE(S) T. Haynes PHONE NO. 704 826.8321 CERTIFIED LABORATORY(S) Pace Lab # 633 Part A: Specific Monitoring Requirements or Lab # (SIGNATURE OF PERMITTEE OR DESIGNEE) By this signature, I certify that this report is accurate complete to the best of my knowledge. Outfall �1Vo Date Sample Collected ' ; Total z 's Rautfall dotal - Sus endues :COD pII=" F h Permit Bench- _- `-N/A -,AJ _; . � i20 -41 014 ` 11 1.. . _� mo/ddtyr ::. finches; . u m 64 imo: i. 9 W 1 3.18.14 0.28 366 ND 5.9 2 3.18.14 0.28 37.6 ND 5.9 3 3.18.14- 0.28 5.8 26.0 5.8 4 3.18.14 0.28 47.0 42 2.8 5 3.18.14 0.28 14.5 ND 6.2 1 4.15.14 0.34 66.9 NA 6.2 2 4.15.14 0.34 NA NA 6.4 3 4.15.14 0.34 NA NA 6.3 4 4.15.14 0.34 NA NA 6.5 Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes ✓ no (if yes, complete Part B) Form SWU-246-112608 Page 1 of 2 Part B: Vehicle Maintenance Activity Monitoring Requirements Outfall No : • . Date "Sample _ 5005©. 00556 . -00530 00400 a Tafal F[ow Total Rawfal! O�i &,Grease,- Total pH r:New Motor 0�l .: Colletteds (if appl cable) ;, k 5uspend'ed : , Usage MG-" inches;` Uiaolddvr ui- oMe STORM EVENT CHARACTERISTICS: Date 3.18.14 Total Event Precipitation (inches): Event Duration (hours): NIA 0.28 (March)10.34 (April) (only if applicable — see permit.) (if more than one storm event was sampled) Date 3.18.14/4.15.14 Total Event Precipitation (inches): 0.28/0.34 Event Duration (hours): (only if applicable — see permit.) Mail Original and one copy to: Division of Water Quality Attn: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Permittee Date Form S W U-246-112608 Page 2 of 2 Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance on filling out this form, please visit: httt)://h2o.enr.state.nc.tislsip/Forms_ Documents.hini4miscforms Permit No.: 31 N C I S `:. 0 0 10 r 5 2 18 or Certificate of Coverage No.: Facility Name: Premiere Fibers County: Anson inspector: Thomas Haynes Date of Inspection: 3.18.14 Time of Inspection: 10:00-1100 Total Event Precipitation (inches): 0.28 Phone No. 704.826.8321 Was this a Representative Storm Event? (See information below) ® Yes ❑ No Please check your permit to verify if Qualitative Monitoring must be performed during a representative storm event (requirements vary). A "Representative Storm Event' is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may contain up to_10 consecutive hours of no precipitation. ----- By this signature, I certify that this report is accurate and complete to the best of my knowledge: — — z ;�K/_ (Signature of Permittee or Designee) 1 Outfall Description: Outfall No. on1-nn5 Structure (pipe, ditch, etc.) . Pipe to Ditch Receiving Stream: Buffalo Creek Describe the industrial activities that occur within the outfall drainage area: Textile Manufacturina 2 Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: Medium brown Page 1 of 2 S WU-242- l 12608 3 Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): No odor noted 4 Clarity: Choose the number which best describes the clarity of the discharge, where I is clear and 5 is very cloudy: 1 O2 3 4 5 5 Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: Q 2 3 4 5 6 Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy: 1 Q 3 4 5 7 Is there any foam in the stormwater discharge? Yes No 8 Is there an oil sheen in the stormwater discharge? Yes No 9 Is there evidence of erosion or deposition at the outfall? Yes No 10 Other Obvious Indicators of Stormwater Pollution: List and describe None Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 SWU-242-112608 0 Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance on filling out this form, please visit: http://h2o.enr.state.nc.us/sit/Fonns Docunients.htm#niisefonns Permit No.: i N' C i S' 0 10 i 0 i 5: 2# 8 j or Certificate of Coverage No.: { j Facility Name: Premiere Fibers County: Anson Inspector: Thomas Haynes Date of inspection: 4.15.14 Time of Inspection: 10:15-11:00 Total Event Precipitation (inches): 0.34 Phone No. 704.826.8321 Was this a Representative Storm Event? (See information below) ® Yes ❑ No Please check your permit to verify if Qualitative Monitoring must be performed during a representative storm event (requirements vary). A "Representative Storm Event" is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no�recipitation. By this signature, I certify that this report is accurate and complete to the best of my knowledge: - � xt,/_ (Signature of Permittee or Designee) l Outfall Description: Outfall No. 001-005 Receiving Stream: Buffalo Creek Structure (pipe, ditch, etc.) Pipe to Ditch Describe the industrial activities that occur within the outfall drainage area: Textile Manufacturinq 2 Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: Medium brown Page I of 2 S W U-242-112608 3 Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): No odor noted 4 Clarity: Choose the number which best describes the clarity of the discharge, where I is clear and 5 is very cloudy: 1 3 4 5 5 Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: l (2 3 4 5 6 Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy: I Q 3 4 5 7 Is there any foam in the stormwater discharge? Yes No 8 Is there an oil sheen in the stormwater discharge? Yes No 9 Is there evidence of erosion or deposition at the outfall? Yes No IU Other Obvious Indicators of Stormwater Pollution: List and describe None Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 S W U-242-112608 aceftlydml w+►w.psoe(a6s.can April 01, 2014 Mr. Phil Rahn Waters Edge Environmental 4901 Water's Edge Drive Suite 201 Raleigh, NC 27606 RE: Project: PREMIERE FIBERS R9-21 Pace Project No.: 92193713 Dear Mr. Rahn: Pace Analytical Services, Inc. 265 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Enclosed are the analytical results for sample(s) received by the laboratory on March 18, 2014, The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Terri Page terri.page@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Ino.. Page 1 of 14 _ 2ce Analytical` www.pacelahs.own I Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden. NC 27288 (336)623.8921 CERTIFICATIONS Project: PREMIERE FIBERS R9-21 Pace Project No.: 92193713 Asheville Certification IDs 2225 Riverside Dr., Asheville, NC 28804 North Carolina Wastewater Certification #: 40 Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001 Massa chusetts'Certifrcation #: M-NC030 West Virginia Certification #: 356 North Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222 Eden Certification IDs 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 North Carolina Wastewater Certiflcation #: 633 VirginiaNELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 14 aceAnalytical wxwpecelaba.cam i SAMPLE SUMMARY Project: PREMIERE FIBERS 139-21 Pace Project No.: 92193713 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623.8921 Lab ID Sample ID Matrix Date Collected Date Received 92193713001 OUTFALL 001 Water 03/18/14 11:00 03/18/14 15:05 92193713002 OUTFALL 002 Water 03/18/14 11:15 03/18/14 15:05 92193713003 OUTFALL 003 Water 03/18/14 11:30 03/18/14 15:05 92193713004 OUTFALL 004 Water 03/18/14 11:45 03/18/14 15:05 92193713005 OUTFALL 005 Water 03/18/14 12:00 03/18/14 15:05 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 14 ace ldmlytrcal' I` wwxpacelabs.com f SAMPLE ANALYTE COUNT Project: PREMIERE FIBERS R9-21 Pace Project No.: 92193713 Pace Analyticat Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92193713001 OUTFALL 001 EPA 9040 JTF 1 PASI-E SM 2540D MAB 1 PASI-A SM 5220D EWS 1 PASI-A 92193713002 OUTFALL 002 EPA 9040 JTF 1 PASI-E SM 25400 MAB 1 PASI-A SM 5220D EWS 1 PASI-A 92193713003 OUTFALL 003 EPA 9040 JTF 1 PASI-E SM 2540D MAB 1 PASI-A SM 5220D EWS 1 PASI-A 92193713004 OUTFALL 004 EPA 9040 JTF 1 PASI-E SM 2540D MAB 1 PASI-A SM 5220D EWS 1 PASI-A 92193713005 OUTFALL 005 EPA 9040 JTF 1 PASI-E SM 2540D MAB 1 PASI-A SM 5220D EWS 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shatl not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 14 Pace Analytical Services, Inc. ;aceAnalytical* 205 East Meadow Road -Suite A Eden, NC 27288 ' wwwcpsc&bd.eorn (338)623-8921 ANALYTICAL RESULTS Project: PREMIERE FIBERS R9-21 Pace Project No.: 92193713 Sample: OUTFALL 001 Lab ID: 92193713001 Collected: 03/18/14 11:00 Received: 03/18/14 15:05 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 9040 pH Analytical Method: EPA 9040 pH 5.9 Std. Units 0.10 0.10 1 03/19/14 09:36 H6 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 366 mg/L 25.0 25.0 1 03/25/14 07:17 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand NO mg/L 25.0 25.0 1 03/24/14 17;00 Sample: OUTFALL 002 Lab ID: 92193713002 Collected: 03/18/14 11:15 Received: 03/18/14 15:05 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 9040 pH Analytical Method: EPA 9040 pH 6.9 Std. Units 0.10 0.10 1 03/19/14 09:36 H6 25400 Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 37.6 mg1L 5.0 5.0 1 03/25/14 07:17 D6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand NO mg1L 25.0 25.0 1 03/31/14 14:41 Sample: OUTFALL 003 Lab ID: 92193713003 Collected: 03/18/14 11:30 Received: 03/18/14 15:05 Matrix; Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 9040 pH Analytical Method: EPA 9040 pH 5.8 Std. Units 0.10 0.10 1 03/19/14 09736 H6 2540D Total Suspended Solids Analytical Method; SM 2540D Total Suspended Solids 5.8 mg1L 2.9 2.9 1 03/25/14 07:17 52200 COD Analytical Method: SM 5220D Chemical Oxygen Demand 26.0 mg/L 25.0 25.0 1 03/31/14 14741 Sample: OUTFALL 004 Lab ID: 9219371300.4 Collected: 03/18/14 11:45 Received: 03/18114 15:05 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 9040 pH Analytical Method: EPA 9040 pH 2.8 Std. Units 0.10 0.10 1 03/19/14 09:36 H6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/01/2014 05:17 PM without the written consent of Pace Analytical Services, Inc.. Page 5 of 14 aceAnalyfrcal` ' WWW.paCef9hacorrr 1 ANALYTICAL RESULTS Project: PREMIERE FIBERS R9-21 Pace Project No.: 92193713 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-B921 Sample: OUTFALL 004 Lab ID: 92193713004 Collected: 03/18/14 11:45 Received: 03/18/14 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 47.0 mg/L 2.8 2.8 1 03/25/14 07:18 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 42.0 mg/L 25.0 25.0 1 03/31/14 14:41 Sample: OUTFALL 005 Parameters Lab ID: 92193713005 Collected: Report Results Units Limit 03/18/14 12:00 MDL DF Received: 03/18/14 16'05 Matrix: Water Prepared Analyzed CAS No. Qual 9040 pH Analytical Method: EPA 9040 pH 6.2 Sid, Units 0.10 0.10 1 03/19/14 09:36 H6 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 14.5 mg1L 2.6 2.6 1 03/25/14 07:18 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand ND mg/L 25.0 25.0 1 03/31/14 14:41 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/01/2014 05:17 PM without the wntten consent of Pace Analytical Services, Inc.. Page 6 of 14 aceAnalytical ' www.pacalabscom I QUALITY CONTROL DATA Project: PREMIERE FIBERS R9-21 Pace Project No.: 92193713 QC Batch: EDEN114014 Analysis Method: EPA9040 QC Batch Method: EPA9040 Analysis Description: 9040 pH EDEN Associated Lab Samples: 92193713001, 92193713002, 92193713003, 92193713004, 92193713005 SAMPLE DUPLICATE: 1159991 Parameter pH Date: 04/01/2014 05:17 PM 92193713001 Dup Units Result Result Std. Units 5.9 5.8 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623.6921 Max RPD RPD Qualifiers 1 20 H6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 14 aceAnalytical www pecefahs.cam QUALITY CONTROL DATA Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: PREMIERE FIBERS R9-21 Pace Project No.: 92193713 QC Batch: WET130154 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92193713001, 92193713002, 92193713003, 92193713004, 92193713005 METHOD BLANK: 1163771 Matrix: Water Associated Lab Samples: 92193713001, 92193713002, 92193713003, 92193713004, 92193713005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg1L NO 2.5 03/25/14 07:14 LABORATORY CONTROL SAMPLE: 1163772 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mglL 250 254 102 80-120 SAMPLE DUPLICATE: 1163773 92193672006 Dup Max Parameter Units Result Result RFD RPD Qualifiers Total Suspended Solids mg/L NO NO 10 SAMPLE DUPLICATE: 1163774 92193713002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mglL 37.6 47.8 24 10 D6 Date: 04/01/2014 05�17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, inc.. Page 8 of 14 ace Ana,(Xical o www.peoelebs.wm Project: PREMIERE FIBERS R9.21 Pace Project No.: 92193713 QC Batch: WETA118458 QC Batch Method: SM 5220D Associated Lab Samples: 92193713001 METHOD BLANK: 1163154 Associated Lab Samples: 92193713001 Parameter Units Chemical Oxygen Demand mg1L QUALITY CONTROL DATA Analysis Method: SM 52201) Analysis Description: 5220D COD Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 25.0 03/24/1417:00 Pace Anatytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-6921 LABORATORY CONTROL SAMPLE: 1163155 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg1L 750 776 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1163156 1163157 MS MSD 92193424001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand mg/L 4220 7500 7500 11200 11200 93 93 75-125 0 20 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1163158 1163159 MS MSD 92193441003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand mg/L 7830 7500 7500 15000 14800 95 93 75-125 1 20 Date: 04/01/2014 05:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 14 Pace Analytical Services, Inc. m 205 East Meadow Road - Suite A aceAnalytrcal Eden, NC 27288 r www.peWabscom (336)623-8921 I QUALITY CONTROL DATA Project: PREMIERE FIBERS R9-21 Pace Project No.: 92193713 QC Batch: WETA/18509 Analysis Method: SM 52201D QC Batch Method: SM 5220D Analysis Description: 5220D COD Associated Lab Samples: 92193713002, 92193713003, 92193713004, 92193713005 METHOD BLANK: 1166807 Matrix: Water Associated Lab Samples: 92193713002, 92193713003, 92193713004, 92193713005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chemical Oxygen Demand mg/L ND 25.0 03/31/14 14:41 LABORATORY CONTROL SAMPLE: 1166808 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg/L 750 743 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1166809 1166810 MS MSD 92194855001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand mg/L 477 750 750 1210 1210 97 98 75-125 0 20 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1166811 1166812 MS MSD 92194629001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand mg/L 2640 15000 15000 16800 16900 95 95 75-125 0 20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/01/2014 05A7 PM without the written consent of Pace Analytical Services, Inc.. Page 10 of 14 /ice Analytical 1 www.pacefabs.mm QUALIFIERS Project: PREMIERE FIBERS R9-21 Pace Project No.: 92193713 DEFINITIONS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623.8921 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. NO - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PRL - Pace Reporting Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes toAzobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(0) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-E Pace Analytical Services - Eden ANALYTE QUALIFIERS D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H6 Analysis initiated outside of the 15 minute EPA recommended holding time. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/01/2014 05A 7 PM without the written consent of Pace Analytical Services, Inc.. Page 11 of 14 aceAnalytical f %Wpecela5aoom QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: PREMIERE FIBERS R9-21 Pace Project No.: 92193713 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92193713001 OUTFALL 001 EPA 9040 EDEN/14014 92193713002 OUTFALL 002 EPA 9040 EDEN/14014 92193713003 OUTFALL 003 EPA 9040 EDEN/14014 92193713004 OUTFALL 004 EPA 9040 EDEN/14014 92193713005 OUTFALL 005 EPA 9040 EDEN/14014 92193713001 OUTFALL 001 SM 2540D WET130154 92193713002 OUTFALL 002 SM 2540D WET/30154 92193713003 OUTFALL 003 SM 2540D WET/30154 92193713004 OUTFALL 004 SM 2540D WET130154 92193713005 OUTFALL 005 SM 2540D WET/30154 92193713001 OUTFALL 001 SM 5220D WETA/18458 92193713002 OUTFALL 002 SM 5220D WETA/18509 92193713003 OUTFALL 003 SM 5220D WETA/18509 92193713004 OUTFALL 004 SM 5220D WETA/18509 92193713005 OUTFALL 005 SM 5220D WETA/18509 Date: 04/01/2014 05:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc„ Page 12 of 14 I CHAIN -OF -CUSTODY 1 Analytical Request Document L�liU I'V IUJ✓ � '�y� • i The Chain -of -Custody Is a LEGAL DOCUMENT. NI relevant fields must be completed accurately. ww.paeslaks.aom Section A Section 8 Section C Page: % of I Required Client Information: Required Project Information: I Invoice Information: 1712796 Compan : YUZ-�� / Report To: Attention: .L 712 7 9 6 Address: �^J�f �/ Copy To: T Company Name: - I -. Fi ui ATOCX -: Address. r NPDES - r GROUNDWATER r DRINKING WATER Email To: �Fa Purchase Order No.: Para QuoinPhone: ( Reference: �'" UST RCRA OTHER ProjectNarrre: PnxPrged Sitel.ocatiori Requested Due DatdTAT: Project Nu Pem gPro{b ft y ^� STATEr ' _ .:Re4uested A,rld_lyS1s Filter! (YIN) _ - _ Section D MaMi odes g - - - Req¢IrWCI{entlydonnsllon nrArRlx ClCODE § o 'COLLECTED Preservatives >- _ E Drinking weir DW g Water WT Waste Water WW cc wpcd3m Product P �rcT ENDOW u� , SoillSoid SL U �� SAMPLE ID Oil � Wipe _ wP ? � w n: � 11 (RZ D9! } Air AR W ui ¢ Sample IDs MUST BE UNIQUE Tissue TS O a m : R' P �{ U i w z ZU (`Jjt, Other OT X UJ J a V CD1,51,5 , (r b a m O Y N -m p to Q df f Co nA ONE DATE TIME # � _ Z. C71 z z z 2 O ;,� 11 Pace Project NoJ Lab I.U. .5 B - -z, I a _ g. �11 - 12 -ADDfTIDNAI: COMMENTSRk_LINQUISwr:n Y! AFFILJATION QATE/7�1M`E - - 'ACCEPTEQ BY! AFFtLFATIQN-.aQATE . TIME SAMPLE CONDITIONS I 3AMPLEi #FAME A_ND SIGNATURE � * w ORIGINAL PRINT Name .ofSAMPLER- . J a _m E U — E SIGNATURE of SAMPLrR: DATE Signed rK Co — A 'Im Note: B nI this farm are mce Hn Pace's NET 30 and agreebw to late charges of 1.5% per month for any invam" not paid 3o days. F-ALL-Q. 420rev.07, i 5-M 2007 P Y �6 n9 Y� P g day Pa!' ay- f7 RVG/"U1a1Y111.PQl •wr...., vvw♦ Document No:: rEUV i VIA issuing AuthMties F->ADN7-CS-003-rev,09 Pace Eden Wit•Office G11ent Name:: .�;. ... . Where.Recelved: ❑ Huhtersville " ❑ Asheville Edon ❑ Raleigh Courier (circle): ' Fed Ex :UPS . USPS lie Commercial Pace Other Custody Seal on Cooierlt3ox Present: DyesPIrKo Seals Intact: ❑ yes ❑ no r .l, Packing Materlal: [3ubble Wrap "❑Bubble Bags ane ❑. Cther i Thermometer Used: IR Gun ED007 'j`ype of ice; a Blue None Ales on toe, pooling procBss has bsgun ', -... Temp Correction Factor0AMA ) Subttac# _C r carrected cooler Terizp.: C $lolpgirsal•Tfssue Is Frozen: Yes Na :NIA' pate and in , s of person nine . :" contents: Tempshould be above frgez€ng to siG _ .Coninfents:, .'.... . . Chain of OustPresent: , .... Yea ONO ". ]WA 1. Chafe of Cuk�Flfied Out:. .Urea, QNo . ONA Chain ofCustb Relin bished:. ...'.. Yea: ONa, ON/A 3. Sampler Nama & SI nature on COC: " , .. Yes. ONo, ❑WA, 4. Samples Antved.wlthin.Hold Time; ..: : " .: ea ❑No OWA. Short Hold Time Analysts ra72hr :. Yes .LINO Rush:TuM Around.Tlme Re nested: " ". ". ©Yee, I]Nq. R<A 7..,. Sufficient Volume: - .:• o... jatres ❑N ©WA 8. CorrectContalrim' 'Used: .fires. OIYo ,.F"1N1A 9. -Pace Contalners Used: 2ea ONo,. ©NA::. Containers Intake , ....... :" TYes dNo. 13WA 10.:.... Filtered volume reoelved.for Dissolved tests 'C1Yes ONO Lko 11. Sample Labels match COC: sea ©No I NrA 12, -Includes datehlmeAgL) nal sR Matltic All oontalners needing preeervallon have bean oheoked: No bWA r" �• All oontoom needing preservation are found to be In ONO ❑ WA oompllance With EPA recommendation. " lens: 1'bA, oolltorm roc k)&Q, Wf {iR0 wets I]Yes. 13 No Initial when dom mad. Samples chocked f6r'doohlorination: es ❑No ..DWA 14. Headsoe In VOA Vlals Amm :. ❑veo : C1No �WA 16. Trap Blank Present:: Oyes ONO MA 16.. Ttfp.Blank Custody Seals Present . ©Yes ❑No.. A Pace Trlp Blank Lot # if urchasa Client Notification/ Resolution: Field Data Required? Y" I N Person Contacted: DateMme: Comments/ Resolution; SCURF Review: Dater dDate.-` Place label here SRF Review: x1namplianoe OR Note: Whenever there is a disomwoy affecting North Ca samples; a copy of this form will be sent to the North Carolina DEHNR Handwrite project number n w jectavainumber Cenlfloatlon Offloe ( Le out of bald, incorrect preservattvs, out of temp, label incorrect oontalners) Page 14 of 14 _ 2ce Analytical � www.pecelebs.cam i I April 23, 2014 Mr. Phil Rahn Waters Edge Environmental 4901 Water's Edge Drive Suite 201 Raleigh, NC 2760E RE: Project: PREMIERE FIBERS R9-21 Pace Project No.: 92197489 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Dear Mr. Rahn: Enclosed are the analytical results for sample(s) received by the laboratory on April 15, 2014. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Terri Page terri.page@pacelabs.com Project Manager Endosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, . without the written consent of Pace Analytical Services, Inc.. Page 1 of 12 Pace Analytical Services, Inc. aceAllalytrca! b 205 East Meadow Road - Suite A Eden, NC 27288 wxwpeoeleba.com (336)623-8921 CERTIFICATIONS Project: PREMIERE FIBERS R9-21 Pace Project No.: 92197489 Eden Certification IDs 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Wastewater Certification #: 633 North Carolina Drinking Water Certification #: 37738 VrginiaNELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not he reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 12 0kialytrcal www.Paaelabs.cam ) Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 SAMPLE SUMMARY Project: PREMIERE FIBERS R9-21 Pace Project No.: 92197489 Lab ID Sample ID Matrix Date Collected Date Received 92197489001 OUTFALL 001 Water 04/15/14 12:15 04115/14 15:25 92197489002 OUTFALL 002 Water 04115/14 12:00 04/15/14 15:25 92197489003 OUTFALL 003 Water 04/15/14 11:45 04/15/14 15:25 92197489004 OUTFALL 004 Water 04/15/14 12:15 04/15/14 15:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 12 aceAnalyt#ical � www.paoefaes.ean I SAMPLE ANALYTE COUNT Project: PREMIERE FIBERS R9-21 Pace Project No.: 92197489 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Lab ID - Sample ID Method Analysts Analytts Reported Laboratory 92197489001 OUTFALL 001 SM 2540D JTF 1 PASI-E EPA 9040 JTF 1 PASI-E 92197489002 OUTFALL 002 EPA 9040 JTF 1 PASI-E 92197489003 OUTFALL 003 EPA 9040 JTF 1 PASI-E 92197489004 OUTFALL 004 EPA 9040 JTF 1 PASi-E REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 12 aceAnalyifical I - trwwpaceiabacom f i ANALYTICAL RESULTS Project: PREMIERE FIBERS R9-21 Pace Project No.: 92197489 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 272BB (336)623.8921 Sample: OUTFALL 001 Lab ID: 92197489001 Collected: 04/15/14 12:15 Received: 04/15/14 15:25 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No, Qual 2640D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 66.9 mg/L 2.8 2.8 1 04/18114 08:36 9040 pH Analytical Method: EPA 9040 pH 6.2 Std. Units 0.10 0.10 1 04/16/14 12:20 H3,H6 Sample: OUTFALL 002 Lab ID: 92197489002 Collected: 04/15/14 12:00 Received: 04/15/14 15:25 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 9040 pH Analytical Method: EPA 9040 pH 6.4 Std. Units 0.10 0,10 1 04/16/14 12:20 H3,H6 Sample: OUTFALL 003 Lab ID: 92197489003 Collected: 04/15/14 11:45 Received: 04115/14 15:25 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 9040 pH Analytical Method: EPA 9040 pH 6.3 Std. Units 0.10 0.10 1 04/16/14 12:20 H3,1-16 Sample: OUTFALL 004 Lab ID: 92197489004 Collected: 04/15/14 12:15 Received: 04/15/14 15:25 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 9040 pH Analytical Method: EPA 9040 pH 6.5 Std. Units 0.10 0.10 1 04/16/14 12:20 H3,H6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/23/2014 11:21 AM without the written consent of Pace Analytical Services, Inc.. Page 5 of 12 aceAnalytical wxw.pacetaes.cam r Project: PREMIERE FIBERS R9-21 Pace Project No.: 92197489 QC Batch: EDEN114351 QC Batch Method: SM 2540D Associated Lab Samples: 92197489001 METHOD BLANK: 1181046 Associated Lab Samples: 92197489001 Parameter Units Total Suspended Solids mglL LABORATORY CONTROL SAMPLE: 1181047 Parameter Units Total Suspended Solids mg1L SAMPLE DUPLICATE: 1181046 Parameter Total Suspended Solids SAMPLE DUPLICATE: 1181049 Parameter Total Suspended Solids Date: 04/23/2014 11:21 AM Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623.8921 QUALITY CONTROL DATA Analysis Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.5 04/18/14 08:34 Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 250 236 94 80-120 92197629001 Dup Units Result Result mg/L 97.7 78.0 92197707002 Dup Units Result Result mg1L 7520 6780 Max RPD RPD Qualifiers 22 10 R1 Max RPD RPD Qualifiers 10 10 REPORT OF LABORATORY ANALYSIS This report shalt not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 12 11eAnalyticale www.pacefeea.own QUALITY CONTROL DATA Project: PREMIERE FIBERS R9-21 Pace Project No.: 92197489 QC Batch: EDEN114321 Analysis Method: EPA 9040 QC Batch Method: EPA 9040 Analysis Description: 9040 pH EDEN Associated Lab Samples: 92197489001, 92197489002, 92197489003, 92197489004 SAMPLE DUPLICATE: 1179574 92197489001 Dup Parameter Units Result Result RPO pH Std. Units 6.2 6.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/23/2014 11:21 AM without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Max RPD Qualifiers 1 20 H3,H6 Page 7 of 12 aceAnalytrcal www.pecefehs.wm QUALIFIERS Project: PREMIERE FIBERS R9-21 Pace Project No.: 92197489 DEFINITIONS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 DF : Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PRL - Pace Reporting Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPO values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-E Pace Analytical Services - Eden ANALYTE QUALIFIERS H3 Sample was received or analysis requested beyond the recognized method holding time. H6 Analysis initiated outside of the 15 minute EPA recommended holding time. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/23/2014 11:21 AM without the written consent of Pace Analytical Services, Inc.. Page 8 of 12 lice Analyfica I ' www.pec"s.mm QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: PREMIERE FIBERS R9-21 Pace Project No.: 92197489 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 92197489001 OUTFALL 001 SM 2540D EDEN/14351 92197489001 OUTFALL 001 EPA 9040 EDEN114321 < 92197489002 OUTFALL002 EPA9040 EDEN114321 92197489003 OUTFALL003 EPA9040 EDEN114321 92197489004 OUTFALL004 EPA9040 EDEN114321 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 0412312014 11:21 AM without the written consent of Pace Analytical Services, Inc.. Page 9 of 12 72ce Ana ical' ' rrrw.pace-Isps,com CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section A Sectian B Section C Page_ ! of Required Client Information: Required Project Information: Invoice information; Company: To: Attention: 0 O /' fAy.Report ..L Address: Copy To: ff Company Name: - - REGULAT0RY AGENCY c r NPDES r GROUND WATER r DRINKING WATER r UST r RCRA OTHER' Email To: Purchase Order No.: �e emote Reference: Phone: Fax: Project Name: 7 �r� b Pace Prole -A Hammer ° S[te Location - _ - Requested Due Date/TAT: Project Number: � _ Pate Profile#: Requested -- Ailialysili`Filtered'{Y1N) _ - _ - - j Section D Matrtx Codes z '-3 RegrdredCKerdlnfwnra0on LdET31x1cCZpE COLLECTED Pneservaums _- Drinking water Dw g o - Water T WIT Waste Water WW c� COsr�� �r��' ' Product P - SOiVSD%d SAMPLE ID pa wP w a m, L� W d Ca (A-Z. D-9l:) Air AR p LU a a H Sample ]Ds MUST BE UNIQUE Tissue VS O a w U ^ /^i► 1 Other OT U X w" H w ZO i-1 m n O ._ y' Caj` 1V. � J d J U fl VVjj d cyl Q O�'. W fjt1 2 2 Z ~ 2 DATE TIME DATE TIME N # = Z 2 O ."ay PBCB Project T10J Lab I.D. -- 3 r s ,7- 16 11 12 - -:' AODFTIONAL COMLEENTS _ ` -i '-RELINQUISHED BY IAFFILWTIO#f -OATEN_ -; TIME I - ACCEPTED BY IAFFRIATION DATE--' TIME -.% SAMPLE CONDITIONS SAMPLER NAME AND SIGIEATIIRE _ t :_ U `a 6 9 c o ORlGINA1 PRINT Name wsAMPLt=R E � �_ _ DATE Signed 8 sICNATURs of SAMPLER: qr�{MMlDD0 ry ~ n ,1.. rtm Now, ay sW&V cos Term you me amapWnq Pace's NET 30 day paymoM terms and apreeMp m 181a rhaTM of 1.5% PM month oF�r eny invoices ra I g rr sa days. f / r F-Ai.i.41020ray.07, 15-May-2(l07 `. aceAnal ical e. : - www.;tacalabs.com Section A : Section 8 . Required GfeM Information:. Required Project ['-amPaR9"" Re •Tn- Address: / Copy To: , J r Ernad To: _ / / Purchase Odder I1 CHAIN -OF -CUSTODY The Chain-oi-Custody Is a LEGAL 0 - -- SectionC umation: Invoice inf,Dm . - Anartdon! - �! Company Nar - - ... Address: P*wQw a Reference: 'hone: Fax: Project Name: Para taquestad Due DatdTAT. - - Project Number. Pau - Section D _ Matrix Codas Rogvbvd Gent k4o"adon MATRIX r CODE —°o' g COLLECTED' - : Drirddng Water DW U zz : - ' Water -'. WT U ' Waste Water WW a Do�E coMPosrcP U Product P - T, WrAW � V40MRM w J - Soil/Solld SL SAMPLE ID Oil o ' ,OL uj - (A-Z, o-9l:) Air. AR - 0 -w - a z Sample IDs MUST BE UNIQUE -'. Tmaue - TS 0 IL - - E - Otter 07 U � z _ U tu a g _w O ~ g y L ,y DATE TIME DATE TIME V- ADDITIORAL COMMENTS .1 Analytical Request Document OCUMENT. AN retevam fields must he completed accurately. s' M®� W■■■■■■■■■■ ■■■■O■■■■■■■■■ SAMPLER NAME AND SIGNATURE U o m . - _ PRINT Name of SAMPLER: � �5 - �� -- - - - - - ' Q � t, . $ S Z_ • z - b - - - - DATE Signed m `—m' U E ` - ry SIGNATURE of SAMPLER: (MMloD!'rY): - rn 100 N •tmpwt&m Nate: By signing d83 f&m you are acceom Pace's NET,3U day payment temre and agreeing to late charges or 1.5% per month any 17nVDi= not pal n 3p days. - F-ALL-Q-020rev.07,, 45-May-2007 Document Name., Sample Condition Upon Document Revised: March l3, 2013 i�ARG31" `�- Recel t (SCUR) Page 1 of 2. Document No.:' issuing Authorities: F-EDN-CS-003-rev.09 Pace Eden Quail Office — ClientName: Where Received: ❑ Huntersville ❑ Asheville 2rEden ❑ Ralelgh Cauriar (circle): Fed Ex _ UPS , .LISPS Ilent Commercla! !� eusio eaI on-0oaledBox Pacirin .. Mate�lal: alibis W----Bub61eOther -- _ ....... 9 mP ❑ cgs Nona ❑ OtherThermometer Used: IR Gun ED007 Typo of ice: a Blue None - plas on ioe, cooling prooesa has begun Temp Correction Factor Ad ! Subtract�C - Corrected CoolerTem.: C Temp should be above freezing to 600 8biogica! Tissu® is Frozen: Yes Na NIA Comments: ' Date and Initials of person examining contents: Chain of Custody Present: Oyes ONO EINIA f. Chain of Custody Fllled Out: JffYes ❑No 0NVA 2, Chain of Custody Relinquished: ea ❑No. ❑WA 3. Sampler Name & Signature on COC: PYes. 014o ❑N/A 4. Samples Arrived within Hold Time: es ONO ❑NIA 5. Short Hold Time Analysis <72hr : ee ONO ❑WA 6. Rush Turn Around Time Requested: ❑Yes ONO ❑ A 7. . Sufficient Volume: ❑ ee ❑No ❑NIA 9: Correct Containers Used: Pace Containers Used: 0se ONO Yes ONO ❑N1A ❑NIA 9. Containers Intact: es ONO ❑wA 10, Filtered volume received for Dissolved tests OYea ONO AVA 11. Sample Labels match COC: AYes ONO ❑NIA 12. All containers needing preservation have been checked. All containers needing preservation are found to be In compliance with EPA recommendation, &M Clans: VO collform, TOO, o&Q, WE qR0 (wake ONO. ,3�'s ©Na �- �" ❑Yea ❑No ❑NIA ❑NlA 13. Initial when ocm sled �Js-- Samples checked for dechlorinatlori: es ONO ❑NIA 14. Heads ace In VOA Vials >6mm : ❑Yea .,❑No ../IA 15. Trip Blank Present: Trip Blank Custody Seals Present Pace Trig Blank Lot # if urchase ❑Yes ❑Nc ❑vas ❑No 0ydA iI_1 A 16, Client Notification/ Resolution: Field Data Required? Y / N. Person Contacted: DateMme: Comments/ Resolution: SCURF Review: L Data: Place label here SRF Review: Date: Note: Whenever tftere is a dis panty affecting North C I a mp lance OR samples, a copy of this form will be sent to the North Carolina DEHNR. Handwrite project number Gerll"catlon Office (1.9 out of hold, Incorrect preservative, out of temp, incorrect containers) (if no label available) Page 12 of 12 ,4 `WA"I"ER5 EDGE EN VERON,bfE�]TAL. LLC 4901 WATERS EDGE DRIVE, SUITE 201 • RALEIGH, NC 27606 • PHONE 919.859.9987 • FAx 919.859.9930 August 1, 2013 NCDENR Division of Water Quality Central Files 1617 Mail Service Branch Raleigh, North Carolina 27699-1617 Reference: Year 5- Period 1 Stormwater Monitoring Report (Fall 2013) Premiere Fibers Facility Ansonville, North Carolina Stormwater Permit No. NCS000528 Waters Edge Job No. 119-21 To Whom It May Concern: Please find enclosed the stormwater monitoring report for Year 5- Period I in 2013-2014. All results are within required parameters (DMR, SDO, and laboratory analytical results -see Appendix A and B). If you have any questions, or if we may be of further assistance, please contact me at prahn c watersedgeenv.com or 919.859.9987. Sincerely, Waters Edge Environmental, LLC Phillip L. Rahn President cc: Mr. Dewey Fulton and Mr. Kevin Bowers- Premier Fibers 13-108 Permit Number: NCS 000528 Certificate of Coverage Number: NCG FACILITY NAME Premiere Fibers STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT or SAMPLES COLLECTED DURING CALENDAR YEAR: .2013 (This monitoring report shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) PERSON COLLECTING SAMPLE(S) T. Haynes CERTIFIED LABORATORY(S) Pace Lab # 633 Part A: Specific Monitoring Requirements COUNTY Anson PHONE NO. (704) 826.8321 Lab # (SIGNATURE OF PERMITTEE OR DESIGNEE) By this signature, 1 certify that this report is accurate complete to the best of my knowledge. * Outfall No . f Ua ' Sample -Y.Collecte�d _ Totals' Rm a%tl d Total Suspended *lms'(T s COD H ;� _ _ - OermAi W nch , « ql l W Z6 ;� A': mo/dd/yr ,, ,. r � mg/1� � _ .. Umts l T2.13 See Below 32.5 37 7.1 2 7.2.13 See Below 10.7 79 7.2 3 T2.13 See Below 4.0 35 6.8 4 7.2.13 See Below 15.8 35 7.4 5 7.2.13 See Below 13 79 7.4 Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes ✓ no (if yes, complete Part B) Form SWU-246-112608 Page 1 of 2 Part B. Vehicle Maintenance Activity Monitoring Requirements �Outfsll No ,.. Date , Sample - S00SQ 00556. „g 00530 : ; 00400 ' Total+Flower Total Rainfall° O &�`Gr ae se' YTota , ` pN IVew M©tor Oil Collected (ef applicable} M ry Suspended Usage Shcids` moldd/yr MG inches 'a ff mom .. ...._ mal/mo 1 STORM EVENT CHARACTERISTICS: Date 7.2.13 Total Event Precipitation (inches): (0.9) Event Duration (hours): NIA (only if applicable — see permit.) (if more than one storm event was sampled) Date NIA Total Event Precipitation (inches): Event Duration (hours): (only if applicable — see permit.) Mail Original and one copy to: Division of Water Quality Attn: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Permittee Date Form SW U-246-112608 Page 2 of 2 Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance onfilling out thisform, please visit: htt ://h2o.enr.state.nc.uslsu/Forms Docunients.htm#miseforms Permit No.: 11 N! C i S 0 i 0 1 0 i 5 12 18 i or Certificate of Coverage No.: Facility Name: Premiere Fibers County: Anson Inspector: Thomas Haynes Date of Inspection: 7.2.13 Time of Inspection: 13:00-14:00 Total Event Precipitation (inches): 0.9 Phone No. 704.826.8321 Was this a Representative Storm Event? (See information below) ® Yes ❑ No Please checkyourpermit to verify if Qualitative Monitoring must be performed during a representative storm event (requirements vary). A "Representative Storm Event" is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no precipitation. By this signature, I certify that this report is accurate and complete to the best of my knowledge: �,�D,� 7 �/ (Signature of Permittee or Designee) 1 Outfall Description: Outfal I No. 001-005 Structure (pipe, ditch, etc.) Pipe to Ditch Receiving Stream: Buffalo Creek Describe the industrial activities that occur within the outfall drainage area: Textile Manufacturinq 2 Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: Medium brown Page l of 2 SWU-242-112608 3 Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): No odor noted 4 Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: ]O 2 3 4 5 5 Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where I is no solids and 5 is the surface covered with floating solids: 1 a2 3 4 5 6 Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where I is no solids and 5 is extremely muddy: 1 O 3 4 5 7 Is there any foam in the stormwater discharge? •Yes No 8 Is there an oil sheen in the stormwater discharge? Yes No 9 Is there evidence of erosion or deposition at the outfall? Yes No 10 Other Obvious Indicators of Stormwater Pollution: List and describe None Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 S W U-242-11260 & aca m ytical ' www.paoalobs.corn July 22, 2013 Mr. Phil Rahn Waters Edge Environmental 4901 Water's Edge Drive Suite 201 Raleigh, NC 27606 Pace Analytical Services; Inc. 205 East Meadow Road - Suite A Eden. NC 27288 RE: Project: Premiere Fibers Pace Project No.: 92163878 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Dear Mr. Rahn: Enclosed are the analytical results for sample(s) received by the laboratory on July 03, 2013. The results relate only to the samples included in this report. Results reported herein conform to the most current TNl standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, \-JX6 Terri'Page terri-page@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not he reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 13 aceAnalytical j wwwpecerehs.cnm Project: Premiere Fibers Pace Project No.: 92163878 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623.8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 CERTIFICATIONS (828)254-7176 Asheville Certification Ibs 2225 Riverside Dr., Asheville, NC 28804 North Carolina Wastewater Certification #: 40 FloridalNELAP Certification #: E87648 South Carolina Certification #: 99030001 Massachusetts Certification #: M-NC030 West Virginia Certification* 356 North Carolina Drinking Water Certification #: 37712 VirginiaNELAP Certification #: 460222 Eden Certification IDs 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 North Carolina Wastewater Certification #: 633 VirginiaNELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS Pace Analytical Services, Inc. 9600 Kincey Ave. Suite 100 Huntersville, NC 2BO78 (704)875-9092 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 13 r aceAnalyfical WW pscelafla coal I Project: Premiere Fibers Pace Project No.: 92163878 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE SUMMARY Lab ID Sample ID Matrix Date Collected Date Received 92163878001 Outfall001 Water 07102113 13:00 0710311315:35 92163878002 Outfall002 Water 07/02/1313:15 0710311315:35 92163878003 Outfall003 Water 07102/1313:30 0710311315:35 92163878004 Outfall004 Water 07102/1313:45 07/0311315:35 92163878005 Outfall005 Water 0710211314:00 0710311315:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc - Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875.9092 Page 3 of 13 aceAnalytical wrrwpecelahacom 1 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc, 2225 Riverside Or, Asheville, NC 28804 (B28)254-7176 SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Premiere Fibers Pace Project No.: 92163878 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92163878001 Outfall 001 SM 25401) CHM 1 PASI-E EPA9040 CHM 1 PASI-E SM 5220D EWS 1 PASI-A 92163878002 Outfall 002 SM 2540D CHM 1 PASI-E EPA9040 CHM 1 PASI-E SM 5220D EWS 1 PASI-A 92163878003 Outfall 003 SM 2540D CHM 1 PASI-E EPA 9040 CHM 1 PASI-E SM 5220D EWS 1 PASI-A 92163878004 Outfall 004 SM 2540D CHM 1 PASI-E EPA9040 CHM 1 PASI-E SM 5220D EWS 1 PASI-A 92163878006 Outfall 005 SM 2540D CHM 1 PASI-E EPA9.040 CHM 1 PASI-E SM 5220D EWS 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 13 aceAnalytkal® www.parxlehsoom 1 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 98001GnceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Premiere Fibers Pace Project No.: 92163878 Sample: Outtall 001 Lab ID: 92163878001 Collected: 07/02/13 13:00 Received: 07/03/13 15:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Quai 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 32.5 mg1L 2.7 2.7 1 07/08/13 14:25 9040 pH Analytical Method: EPA 9040 pH 7.1 Std. Units 0.10 0.10 1 07/08113 07:50 H6 6220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 37.0 mglL 25.0 25.0 1 07/18/13 16:00 Sample: Outfall 002 Lab ID: 92163878002 Collected: 07/02/13 13:15 Received: 07/03/13 15:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2640D Total Suspended Solids Analytical Method: SM 25400 Total Suspended Solids 10.7 mg/L 2.5 2.5 1 07/08/13 14:27 9040 pH Analytical Method: EPA 9040 pH 7.2 Std. Units 0.10 0.10 1 07/08/13 07:50 H6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 79.0 mg/L 25.0 25.0 1 07/18/13 16:00 Sample: Outfall 003 Lab ID: 92163878D03 Collected: 07/02/13 13:30 Received: 07/03/13 15:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 4.0 mg1L 2.6 2.6 1 07/08/13 14:34 9040 pH Analytical Method: EPA 9040 pH 6.8 Sid. Units 0.10 0.10 1 07/08/13 07:50 H6 52200 COD Analytical Method: SM 5220D Chemical Oxygen Demand 35.0 mg1L 25.0 25.0 1 07/18/13 16:00 Sample: Outfall 004 Lab ID: 92163878004 Collected: 07/02/13 13:45 Received: 07/03/13 15:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2640D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 15.8 mg/L 2.5 2.5 1 07/08/13 14:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in NO, Date: 07/22/2013 11:45 AM without the written consent of Pace Analytical Services, Inc.. Page 5 of 13 Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc. acek alytical 205 East Meadow Road - Suite A 2226 Riverside Dr. 9800 Kincey Ave, Suite 100 - wwwpecamb3.0" Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078 1 (336)623-8921 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: Premiere Fibers Pace Project No.: 92163878 Sample: Outfall 004 Lab ID: 92163878004 Collected: 07102/13 13:45 Received: 07/03/13 15:35 Matrix: Water Report Parameters Results Units Limit MOIL OF Prepared Analyzed CAS No. Qual - 9040 pH Analytical Method: EPA 9040 pH 7.4 Std. Units 0.10 0.10 1 07/08113 07:50 H6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 35.0 mg1L 25.0 25.0 1 07/18/13 16:00 Sample: Outfall 005 Parameters Lab ID: 92163878005 Collected: Report Results Units Limit 07/02/13 14:00 MDL OF Received: 07/03/13 15:35 Matrix: Water Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 13.0 mglL 2.5 2.5 1 07/08/13 14:44 9040 pH Analytical Method: EPA 9040 pH 7.4 Std. Units 0.10 0.10 1 07/08/13 07:50 H6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 79.0 mg/L 25.0 25.0 1 07/18/13 16:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 0712212013 11 A5 AM without the written consent of Pace Analytical Services, Inc- Page 6 of 13 ZaceAnalytical www.Pecatab.com J Project: Premiere Fibers Pace Project No.: 92163878 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA QC Batch: EDEN111978 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92163878001, 92163878002, 92163878003, 92163878004, 92163878005 METHOD BLANK: 1005927 Matrix: Water Associated Lab Samples: 92163878001, 92163878002, 92163878003, 92163878004, 92163878005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 07/08/13 14:22 LABORATORY CONTROL SAMPLE: 1005928 Parameter Units Total Suspended Solids mg1L Date: 07122/2013 11:45 AM Spike LCS Conc. Result 250 258 Pace Analytical Services, Inc. 9800 Kincey Ave. Su4e 100 Huntersville, NC 28078 (704)875-9092 LCS % Rec % Rec Limits Qualifiers 103 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Page 7 of 13 aceAnalytical` www.pawws.com f i Project: Premiere Fibers Pace Project No.: 92163878 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (338)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr, Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA QC Batch: EDEN/11973 Analysis Method: EPA 9040 QC Batch Method: EPA 9040 Analysis Description: 9040 pH EDEN Associated Lab Samples: 92163878001, 92163878002, 92163878003, 92163878004, 92163878005 SAMPLE DUPLICATE: 1005705 92163670001 Dup Parameter Units Result Result RPD pH Std. Units 7.7 7.5 2 Date: 07/22/2013 11:45 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875.9092 Max RPD Qualifiers 20 H6 Page 8 of 13 aceAnalytrcal w►vw.pacefahs.aom Project: Premiere Fibers Pace Project No.: 92163878 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. . Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA QC Batch: WETA116847 Analysis Method: SM 5220D QC Batch Method: SM 52200 Analysis Description: 5220D COD Associated Lab Samples: 92163878001, 92163878002, 92163878003, 92163878004, 92163878005 METHOD BLANK: 1010609 Matrix: Water Associated Lab Samples: 92163878001, 92163878002, 92163878003, 92163878004, 92163878005 Blank Reporting Parameter Units Result Limit Analyzed Chemical Oxygen Demand mg/L ND 25.0 07/18/13 16:00 Qualifiers Paco Analytical Services, Inc. 980D KinceyAve, Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1010610 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg/L 750 762 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1010611 1010612 MS MSD 92163700001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand mgtL 65.0 750 750 806 801 99 98 75-126 1 20 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1010613 1010614 MS MSD 92163878004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand mg1L 35.0 750 750 773 776 98 99 75-125 0 20 Date: 07/22/2013 11:45 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc., Page 9 of 13 e aceARalytical ' www.pac&bd.com I Project: Premiere Fibers Pace Project No.: 92163878 DEFINITIONS Pace Analytical Servicee, Inc. 205 East Meadow Road - Su�te A Eden. NC 27288 (336)623.8921 QUALIFIERS Pace Analytical Services, Inc. 2225 Riverside Or. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 OF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PRL - Pace Reporting Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenythydrazine (8270 listed anaiyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nilrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PAST -A Pace Analytical Services -Asheville PASI-E Pace Analytical Services - Eden ANALYTE QUALIFIERS H6 Analysis initiated outside of the 15 minute EPA recommended holding time. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/22/2013 11:45 AM without the written consent of Pace Analytical Services, inc.. Page 10 of 13 llceAnalyfical' www.pacelehaeem j Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Premiere Fibers Pace Project No.: 92163878 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92163878001 Outfall 001 SM 2540D EDEN111978 92163878002 Outfall 002 SM 2540D EDEN111978 92163878003 Outfall 003 SM 2540D EDEN111978 92163878004 Outfall 004 SM 2540D EDENI11978 92163878005 Outfall 005 SM 2540D EDEN111978 92163878001 Outfa11001 EPA 9040 EDEN/11973 92163878002 Outfall 002 EPA 9040 EDEN111973 92163878003 Outfall 003 EPA 9040 EDEN111973 92163878004 Outfall 004 EPA 9040 FDEN111973 92163878005 Outfall 005 EPA 9040 EDEN111973 92163878001 Outfall 001 I� ! SM 5220D WETA115847 92163878002 Outfall 002 SM 5220D WETA115847 92163878003 Outfall 003 SM 5220D WETA115847 92163878004 Outfall 004 SM 5220D WETA115847 92163878005 Outfall 005 SM 5220D WETA115847 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/22/2013 11:45 AM without the written consent of Pace Analytical Services, Inc.. Page 11 of 13 aceAnal'�}ical' CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Pape of Section A Section B Section C ( Rogrdred Cllent Information: Required Project Intwmetion: Invulce Imo: Report To: %7 _� Attendon: 1629790 Address: CapyTo: Company Name:Addrew REGU_LJKT(3RYAGENCY �ti'?_''k 1f ' r NPDES r: GROUND WATER r WATER ' /DRINKING r-, LIST r RCRA . j� OTHER ernal To: Ptudrase Order Na-: rJ / v` am Q1°�° �rersr�oe - Fax: Prged Name: PeOB Pf01e� Site Lxattan STAT#—,.' k LRAques]tld Due DetslTAT: Prvjad Number - Pere PIvPoe N: 'nested /[nafysia F�if%red;�lf1[+IJ 5. ..r ROMCodes ClInfont d>�n rt;oc� r ronE s COLLECTED PreservaWas jr:'i Drinkirg water DW Water WT t3 le oWaste o Ptaduct a6er NP SaillSoOd SL ;B ColrPoSrTE srNtr caewasrrE"` eroionna w p Z SAMPLE ID °i1 °L IA 4 0-9 1 ,-) wpe WP Air AR p lu a Z F O { J� Sample Do MUST BE UNIQUE 'T�� TS U 4- fib►: �. U " I f a a .Ut3� a =vi m (D `m � 9 mm Z U tc DATE TIME HATE TIME 0 Z 2 Y z z ;a' oc Pace Project NoJ Lab I.D. to Z I 2` Z t_= V Ir i 3ii z -9e AD�RIONAL COAAMEa1T8 ? RELaWl11SHED BY!AFFILIATION DATE yaT1ME ° ` { A_ ! OATEN TARE SAMPLE CONDI'MNS to ORIGINAL. SAtNP1 Bt�N/1AAE AND;itGNATURE r� .z K 4 ` - 3T ' EQ• � N PRINT Name of SAMP1 o SIGNATURE of SAMPLER: ed 111 E 12 s m m a w P rEmn -hWwtam Nate: By *Fitt Cie loan you ate a M*V Pne's NET 30 dry PeY+we hrve wW aWveep Eo Ift o rg m or 1.5% per mood or cry hrvalm Doi t v OM d.,L / / F-ALL-Q-020rev.07, 15-May2007 pocument Name: Sample Condition Upon lieael t SCIlR Documenf Revlsed: March 13, 2013 P e 1 eta Document No.:' . ; . F-EDN-CS-003-rev.09 issuing Athbri�as: race Eden Quality Office Client Name: W4. Where Roc6Wd: j] HuntersAlle ❑ Asheville den 0. ❑ Raleigh Courier (circle): Fed Esc LIPS LISPS Ilent Commorolal Pace Other...... Custody Seal on Cooler/Box Present: .❑yes ❑' no Seals intact: ❑ yes ❑ no Packing Material: 034bble Wrap ❑Bubble Bsas ❑ Nona Other Thermometer Used; IR faun ED007 Type of ice: et Sloe Nona , mples on Ice, 000iing process has begun Temo Correction Vactors. Addy Subtract 'hPek 0—A C Corrected CoolorTempr C Temp should be above freezing to B°C Biological Tissue Is Frozen: Yes No NIA Comments: Data and Initi. trip, Chain of Custod Present es ©No ClW'A 1, Chain of Cust6dy Filled Out: - es ❑No QwA 2, Chain of Custb& Relinquished. .0& QNo Elf iA 3. Sampler Name & Si nature on COO: 05m Elmo QWIA 4, Samples Arrived within Mold Time: ' -an's m. DNA 6. Short Hold Time Analysis 2hr : ❑Yes vo DWA 6. Rush Turn Around Tfine Re nested: bYea jb El N/A 7, Sufficient Volume. Rfe QNo DWA 18. Correct Containers Used: -Pace Containers Used: des QNo 'Dws ©No ©NIA 9. DWA Containers Intact: ]:]�No VWA 10. Filtered volume received for pissofved tests CIYes ❑No a1VA 11. Sample Labels match COO: -Includes date/timelID/Analyals Matrbc Yes ©No QwA 12. N oontalners needing preservation have been oheciced. If oontainers needing preservaflon are found to be In compliance with EPA recommendaWn. w000ns: VOA, oollfamm TOG, 640, WI-0RO �r �v es ❑No -- .lam pNo ©Yes ❑No faNIA 13. OWA Inifiei whw oDm feted . $am fes checked for dechiorination: pies Oleo IINIA 14. Pleads cs In VOA Vfais >Smm :.. DYes ❑No 016 16. Trip Flank Present: Trip Blank Custody Seals Present -Peas TO Blank Lot #f iY purchased), ©Yea 12No Dyes DNo 18. E I m Client Notlflaation! Resolution: Fleld•Data Required? Person Contacted: batelTime: . Commentsf Resolutlon:-- SCURF ReVIeW: �q Date: ' Place label here SRF Review: Date: % 3 OR Not% Whensver the VWOU86rropanoy affecting forth CaWr4fni oo pffanoe samples, a copy this form will be sent to the Norlh CaroMa DEHNR number num project Handwrite proj Certiffoaifon Offloe (I.e out of hold, Incorrect preservaft out of tomp, Han Inoorreot oontalners) _ — - ( no label ect num _ ) Y 1 N 13 of 13