WQ0000430_Residual Annual Report 2018_20190313

INITIAL REVIEW
Reviewer Williams, Kendall
Project Number* WQ0000430
SUBMITTAL DATED: 2/26/2019
Project Contact Information
Rease provide inforrration on the person to be contacted by MB Staff regarding electronic submittal, confirmation of receipt, and other issues.
......................................................................................................................................................................................................................................................................................................................................................................................................
Name * Lisa Finnerty
Email Address*
[e-mail]
Project Information
Application Type* r
New
r
Renewal
r
Annual Report
Permit Type * r
Wastewater Irrigation
r
Other Wastewater
•
Closed -Loop Recycle
r
Single -Family Residence
Wastewater Irrigation
Is a paper copy of the application being submitted?*
r Yes r Nor N/A
Permit Number* WQ0000430
Permittee *
Facility Name *
City of Cherryville
City of Cherryville
Phone Number*
4434899086
r Modification (Major or Minor)
• Additional Information
r Other
• High -Rate Infiltration
r Reclaimed Water
r Residuals
r Other
Please provide comments/notes on your current submittal below.
Please attach all information required or requested for this submittal to be review here.
Application Form Engineering Hans, Specifications, Calculations, Bc.)
City of Cherryville NC 2018 Annual Report.pdf 7.6MB
Upload only 1 RDF document. NUltiple documents must be corrbined into one RDF file.

For neiv and modif cation permit applications, the paper copy is required to be submitted to the
Di,,isiom Be advised, applications will not be considered complete until both the paper and electronic
applications. have been received_ The paper copy shall include the follm ping:
• Application Farm
• All relevant attachments (talcs, soils report, specs, etc_)
• 1 full-size engineering plan set
• 2 11-17" engineering plan sets
• 1 extras set of specifications (in addition to the set of specifications provided in the
attachments)
• Fee (if required)
This shall be mailed to the following address:
By US_ Postal Service-
Di,,ision of Water Resources- Non -Discharge Branch
1617 Mail Service Center Raleigh NC 27699-1617
By Courier, -Special Delivery:
Division of Water Resources- Non -Discharge Branch
Nathaniel Thornburg- 9th Floor, Office #942 M
512 N_ Salisbury St_ Raleigh, NC 27604
For questions or problems contact Tessa Monday at 919.7073660 or Tessa_X%nday(dncdem_gov or
Sonia Graves at 919.707.3657 or Sonia Graves(dpcdenr.gov.
* I40 By checking this box I am acknowledging that I have read the above statement and agree
to send these documents as required to one of the address given above.
Signature
Submission Date 2/26/2019

435 \Villiatns Court, Suite 100
Baltimore, 1v1D 21220
wwwsynagro.coin
FFBRUARY 22, 2019
NCDEQ
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: 2018 Annual Report for Permit No. WQ0000430
Dear NCDEQ:
SYNAGRO
Synagro is submitting one copy and one electronic copy of the above referenced report on
behalf of the City of Cherryville, NC.
If you have any questions or need additional information, please do not hesitate to contact Larry
Wright at [phone] or Erik Bruce at [phone].
Sincerely,
Derrick Shivar
Environmental Compliance Manager
Enclosures
cc: Larry Wright, City of Cherryville
Erik Bruce, Synagro
YOUR PARTNER FORA CLEANER, GREENERWORLD

CITY OF CHERRYVILLE, NC
RESIDUALS LAND APPLICATION PROGRAM
Permit No. WQ0000430
2018 ANNUAL REPORT

City of Cherryville, NC
Residuals Land Application Program
2018 Annual Report
TABLE OF CONTENTS
1. Certification Form and Annual Operations Summary
2. Annual Residual Sampling Summary Forms, Residuals
Analysis, & SAR Calculation Page
3. Annual Land Application Field Summary Forms
4. TCLP Analysis
5. Pathogen Reduction/Vector Attraction Reduction
6. Soil pii &Lime Application Records
7. Soil Analyses

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit #: WO0000430 County Gaston Year 2018
Facility Name (as shown on permit) City of Cherryville W WTP NPDES No. NC0044440
Land Application Operator Synagro Phone# [phone]
Land application of residuals as allowed by the above permit occurred during the past calendar year?
X YES NO. IF NO, skip Part A, and Part B and proceed to Part C. Also, if residuals were generated but not land applied,
please attach an explanation on how the residuals were handled.
Part A — Residuals Application Summary:
Total number of application fields in the permit: 7
Total number of fields utilized for land application during the year: 2
Total amount of dry tons applied during the year for all application sites: 7937
Total number of acres utilized for land application during the year: 38.6
Part B — Annual Compliance Statement:
Facility was compliant during calendar year 2018 with all conditions of the land application permit (including but not limited to items
1-13 below) issued by the Division of Water Quality X YES NO.
If no, please provide a written description why the facility was noY compliant, the dates, and explain corrective action taken.
I. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the
limit specified in the permit.
3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of
laboratory results are attached.
4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading
Rates in 15A NCAC 02T .1105(b) (Applicable to 40 CPR Part 503 regulated facilities).
7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503
regulated facilities).
8. All monitoring and reporting requirements in 15A NCAC 02T .I I I were complied with (applicable to 40 CFR Part 503
regulated facilities).
9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior -
authorization was received from the Division of Water Quality.
10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
it. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified
in the permit.
12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13. All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C — Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I
am aware that there are significant penalties for submitting false information, including the possjyi}ifyoffines.and imprisonment for
knowing violations."
Larry Wright Plant ORC & Plant Supervisor
Permittee Name and Title (type or print) �ignature of ennte Dat=
Signature oFPreparer* Date Signatur oil"and Applie" Date
(if different From Permittee) (iFdifferent from ermittee and Preparer)
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006)

2018 ANNUAL OPERATIONS SUMMARY - LAND APPLICATION IN NC
CHERRYVILLE, NC
CHERRYVILLE, NC LIQUID
MONTH/YEAR
June 2018
YEARLY TOTAL
AMOUNT UNIT
620,000.00 G
620,000.00 G
DRY TONS UNIT
79.37 D
79.37 D
DRY METRIC
TONS
72.00
72.00
1 /28/2019

a
m
co
m (
m � O
N N
L O
w a) >
3 mci
c
3.
C C O
0 O E Y N
C 0.
O 6
U
i O N C
W
�Ea
O a O
N n w
C Z N p.
C
O E
0 o N E m
T O M
c
J 2i g '- c_
U a)N Y
_ O
v
� N w
E � �
f6 N
N N
� a d
� m y
f6 C
o. :o
O- U
N C
U O N
� N �
Z
W W
J J y N
O J J
M o N Q m
V _
o d d tm
E E
� O L
� W O W �
�UZ U
co
W�
O N Y Ncc tm
co
N
E
a d w ci G o� V7 ? rn c o OR
E A .. E Q a-D W s oZ �a c
ZZ *bz Rig U) n.aao H a ?-o 'mac m
E:L)0 ��U)L) Qc �E0 E ° om coo X
N tO d 0 "O a� N 2' 2 -gyp o n� �• �c N U N Z E
O. LL Z 0 M d�owd dQU2UU �2Z U) Ff-QZ

i�
09
W6
C`
C
z
J
IL
a
U)
H
J
Q
W
J
7
z
a
s
L
O
N
E
E
N
9
0
N
3
O'
O
C
t
°O a
a) N
C
c O
c .0
Q O
G uJ
a a)
C N
O E
a
N a7
N CO
O °
U �
N C
ys
E m
N �
C
0
�E
Q E
a)
a
0
Oco
0
O
N
a
0 VV
N U
N C
O a7 0
3
N h ' (D
U U 3 .0
C C O O
cO 0 N y N
C o
U a
a7 m C
@ C E
C E
T 0.0 O
C
cQ C a
QoE
C O M
a
E c
O ° N
0 c U a) w
N L O
a N
N _
E � N
00 N O
C °-
�a °
a
a�.
Q�
m.
0
m ° a1
o S
E a€
U am oc0
Z
W W a N � � �- ,-i � y N ID
J J Y w
O J_ O J_ O
O
O a' p �' 'y M m E .a
C) W o W 3
azU = 3 cr
U Z C) w ° m
T fl w R
O ✓� Y N
N 0 01 a O }
we T a E v @
`m :a m E -°° N aci
9 CDN 0 C rn� y c 0 a
E E m E Q
Oz .. Z N a� F � m
'ZZy*a my E Eco W E E r rn
-W C! omoc 2'c Ea"i wE c°iNc
EV C .O O U
mma yamd �Eorn ;9a avi
amLL Z O N 0 m m m Q? m m 2 0 0
� aOa CL 0 as fn

Page: 1 of 2
Report Number: 18-023-0208
Account Number: 46442
Submitted By: Erik Bruce
Send To: Synagro Central LLC/ Cherryville
Mary Brewer
284 Boger Road
Mocksvllle . NO 27028
Lab Number: 58182
Sample Id : Cherryvllle. W W TP
Waypoint.®
ANALYTICAL
7621 Whltepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypolnMnalytical.com
Project : Cherryville W WTP
REPORT OF ANALYSIS Date Sampled: 1/22/2018 09:00:00
Date Received: 01/23/2018 00:00
Date Reported: 01/30/2018
Total Solids"
3.07
30700
100.0
R D
01/23/201814:30
SM-2540G
Moisture"
96.92
100.0
RD
01/23/201814:30
SM-2540G
Total Kjeldahl Nitrogen
0.94
9420
50.0
R D
01/24/2018
09:00
SM-4500-1\H3C-TKN
Total Phosphorus
1.60
16000
100
MOS
01/25/201817:18
6010C
Total Potassium
0.17
1680
100
MOS
01/251201817:18
6010C
Total Sulfur
1.02
10200
100
MOS
01/26/2018
13:59
6010C
Total Calcium
1.10
11000
100
MOS
01/25/2018
17:18
6010C
Total Magnesium
0.24
2420
100
MOS
01125/201817:18
6010C
Total Sodium
0.17
1700
100
MOS
01/251201817:18
6010C
Total Iron
27800
100
MOS
01125/201817:18
6010C.
Total Aluminum
8030
100
MOS
01/25/201817:18
6010C
Total Manganese
464
5.00
MOS
0112512018
17:18
6010C
Total Copper
471
5.00
MOS
01/25/201817:18
6010C
Total Zinc
786
5.00
MOS
01/25/2018
17:18
6010C
Ammonia Nitrogen
0.78
7790
50.0
R D
01/26/2018
08:45
SM-4500-NH3C
Organic N
0.16
1630
0.005
R ❑
01/301201811:03
CALCULATION
Nitrate+Nitrite-N
216
2.45
MMT
01/251201808:67
4500NO3F-2011
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
OurrEpmis and letters are for Ole exolusNe and wn(denllal use d our'clkn(s, and mey not be reprotluaed In whole or pad, nnrmeyany ra(omnce be made
to the mok. Me results, or the company In any advedivng. news ddaase. or Wherpubllc announcements without obtaining ourpdor %effen aulhedzalion.
Pauric McGroary
Agronomist

Page: 2 of 2
Report Number: 18-023-0208
Account Number: 46442
Submitted By: Erik Bruce
Send To: Synagro Cenral LLC/ Cherryville
Mary Brewer
284 Boger Road
Mockav'dle, NC 27028
Lab Number: 58182
Sample ld : Cherryville W WTP
a
Waypoint..
ANALYTICAL
7621 Whltepine Road, Richmond. VA 23237
Main 804-743-9401 ° Fax [phone]
w ww.waypointanalytial.com
Project: Charryvllle W W TP
REPORTOFANALYSIS Date Sampled: l/22/201809:00:00
Date Received: 01/23/2018 00:00
Date Reported: 01/30/2018
Total Cadmium
<2.00
2.00
MOS
01/26/201813:59
6070C
Total Chromium
52.3
5.00
MOS
01/25/2078
17:18
6010C
Total Nickel
25.6
5.00
MOB
01/25/2018
17:18
6010C
Total Lead
32.8
5.00
MOB
01/25/201817:1B
6010C
Total Arsenic
4.70
3.00
MOB
01/25/201817:18
60100
Total Mercury
0.941
0.400
MOS
01/29/201814:23
SW-7471B
Total. Selenium
<5.00
5.00
MOS
01/25/201817:18
6010C
pH*
7.1
1.0
JM
01/24/201809:00
9045D
Total Molybdenum
8.08
5.00
MOS
01/25/2018
17:18
6010C
Comments:
NC CERT#257, SC CERT#9300 7007
SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES.
All values are on a dry weight basis except es noted by asterisk. Detection limit on all N sedes is on a wet basis.
rrepnrtssM let2rs am fop the emluslve and cnnrideMhl use ofeurclisn(s. and Piny not be reproduced In ivM1ole or pod, normay any reference be made
bnlM1e wnrk the rssalta, orrhe company In any atluerllaing, neµe reloase, orolherpubllc errnouneenrenrs wNhoul oDtelninp our prlpr wAtten aulhods+lion.
Pauric McGroary
Agronomist

w
BS
\4ZIC
� \\ §k
§e k\ kk
a@
/7\ \LUIL
�\ ` 2k
MENOMINEE
£ !u
co< cn
: �; k
LL §
2 2K
_!! §
06CM
«rEm } u
�°
�
\
q
2§ ae
\ k§
&2 -
M
(2
/ Cc �]
m ¥ <
] ® < a
\ ( (, �-
F / \§
\ ( Enƒ
cI
.4
\
)
/
/
$°
/w&
k
k\`/M
I�
e
~
IN
0
.
�
£
�
�
]E
r
a
�
§
£
�
��
#
.,
§
..af
k
�
«
9,00
z
�
aRz
2
.
z
2
2
CL
®
u

Sodium Absorption Ratio Calculation (SAR)
Product Code
Product Name
Sample Date
Report Range
Ratio
200M1-LIQ-NC
CHERRYVILLE,
NC LIQUID
1/22/2018
1/1/2018-12/31/2018
0,6680
Na mg/I = (Na mg/kg x %Solids) = 100 = (1700 x 3.0700) + 100 = 52.19
Ca mg/I = (Ca mg/kg x %Solids) + 100 = (11000 x 3.0700) = 100 = 337.7
Mg mg/I = (mg mg/kg x %Solids) _ 100 = (2420 x 3.0700) + 100 = 74.294
Na meq = Na mg/I > Molec.Wgt.Na = 52.19 : 23 = 2.26913
Ca meq = Ca mg/I + Molec.WgLCa = 337.7: 20 = 16.885
Mg meq = Mg mg/I + Molec.Wgt.Mg = 74.294 + 12 = 6.19117
SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 2.26913 - SgrRoot[0.5(16.885+6.19117)] = 0.668025
Printed: 1/30/2019
Page 1 14:45

SECTION 3

I
a
a
E
a'
A
W
U
W
o
W
a
�33
a
W
w
w
O
o
r^
d
U
�
E
z
a�
'a
a
a
�
y
�
w
�
w
d
�
U
C7
N
o
U
W
�
O3
Q
Q
W
W
�Wq
O
O
O
O
b
Iz
N
N
N
N
R
R
R
R
C
z
Rao
R
H
a
a
0
o00
z
N
1
?•
o
0
h
N
N
¢aA�
Saw
x
z
z
a
�3
ca
W
Q
o
nU0
�
u
u
u
u
U
U
U
U
a
V
�
b
o
"
L
WHw
[n
>4
�Nm
0
0
c3
°
rn
y
\
W�
r
a
�
N
z
x
a
q
rn
U
ry
ry
U
N
U
U°
a
�
OH
q7
¢
U
N
a
O
U
0
U
22
a
feu
a
�
pc
5
W
w
a.

m
w"
a
a
6
a-
Q
U
�
W
�Wy
o
y
C7
o
�
�33
�o
W
W
a
a
O
d
Q
C
W
W
W
coo
U
a
a
v
W
a
„
b
b
N
c
Fi
�
z
n
r
ao
0
O
o
N
O
Wi
vn
V�
0
?+=
N
�oGG
y0�
ca"5
Na.7
Q
u
�
y
6N
U
V
5aa
o
v
U
Ll
�
U
U
U
C4
09
ALL.
W
c
m
m
m
U
m
✓'
P
P.
�
U
C7
C7
C�
C7
so
r
�
r
a�
m
a
w
�
N
N
0
z
M
.fin
�r
a
0
U
U
A
H
�
F
O
U
U
a
_
R
U
m
a
�
P.
C1
a
W
YC

NUMMIT Summit Enniromnenta7 Teehxo7agies, InC.
TI3310 Win St.
rO;VIRONPAEN'rALTEr Or4OLOeI�s, INC Cuyahoga Falls, Ohio 44223
Anal yNORI LahpratoOns TEL: [phone] FAX-: [phone]
Website: him:f/mmv.settek.com
January 315 2018
Erik Bruce
Synagro
284 Boger Rd.
Mocksville, NC 27028
TEL: [phone]
FAX: [phone]
RE: Cherryville WWTP
Dear Erik Bruce:
Order No.: 18011035
Summit Environmental Technologies, Inc. received 1 sample(s) on 1/23/2018 for the
analyses presented in the following report.
There were no problems with the analytical events associated with this report unless noted
in the Case Narrative.
Quality control data is within laboratory defined or method specified acceptance limits.
except where noted.
If you have any questions regarding these tests results, please feel free to call the
laboratory.
Sincerely,
ar
Jennifer Woolf
Project Manager
3310 Win St.
Cuyahoga Falls, Ohio 44223
Arkaysas 88-0735, Califrmia 07256CA, Colomdq Connecticut PH-0108, Delaware, Florida NELAC E87686, Georgia E87688, Idaho OH00923, Illinois
200061, Indima C-OH-13, Kansas E-10347, Kentucky (Uudergromd Storage Tank) 3, Kenucky 9014G, Louisiana 04067, Maryland 339, Minnesota
409711, New Hampshve 2996, New Jersey OH006, New York 11777, Nnrth Carolina 39705'and 631, NarN Dakota R-201, Oklahoma 9940, Oregou
O112O0001, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-11-5, Crab OH009232011-1, Virginia VELAP 9456, Washington
C891
Page 1 of 27

si
SUMMIT '"'itEn,bonme„to,Tehao331Win ro0Tilin St. Case Narrative
R1
rf3VIRONMEN'I'AL IECHNOL001E5, rc- Cuyahoga Falls, Ohio 49223 WO#: 18011035
rinalytiral f.ahmahvmq TEL: [phone] FAY. [phone] Date: 1Y31/2018
Website: huy.-Mvwiv settekcom
CLIENT: Synagro
Project: Cherryville WWTP
WorkOrder Narrative:
18011035: This report in its entirety consists of the following documents: Cover Letter, Case Narrative,
Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody,
Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit
Environmental Technologies, Inc., Work Order Number assigned to this report.
Summit Environmental Technologies, Inc.,. holds the accreditations/certifications listed at the bottom of
the cover letter that may or may not pertain to this report. State Certificates and Scopes of Accreditation
are attached as applicable. Results provided in this report for any parameter not listed on the Scope of
Accreditation should be considered "not certified."
The information contained in this analytical report is the sole property of Summit Environmental
Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of
Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results
contained in this report are only representative of the samples received. Conditions can vary at different
times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible
for use or interpretation of the data included herein.
All results for Solid Samples
are reported
on
an
"as received" or "wet weight" basis unless indicated as
"dry weight" using the "-dry"
designation
on
the
reporting units.
This report is
believed
to meet all of the requirements of the
accrediting agency,
where applicable. Any
comments or
problems
with the analytical events associated
with this report are
noted below.
Analytical Sequence Sample Notes:
18011035-OOlA SVOC-BNA_TCLP(8270D): Sample exhibited low recovery for Surrogate: phenol-d6
due to matrix effect.
Analytical Sequence QC Notes:
ccv 40ng S8- svoc-mstr_s(8270): CCV exhibited high recovery for Hexachloroethane. Associated
samples are ND for these analytes.
Original
Page 2 of 27

suftimixt summit Environmental Technologies, In Qualifiers and Acronyms
33/0 Win E
MVIRONMEN1'AL tet BNOLO©Iesr INC. Cuyahoga Falls, Ohio 4422 WO#: 18011035
AnalyNeal LahcoamOes TEL [phone] FAX, (330) 253-446 Date: 1/31/2018
Wehslte: httn:11niurn.settekco
These Commonly used Quaers and Acronyms may or may not be present in this report
Qualifiers
U
The compound was analyzed for but wasnot detected.
7
The reported value is greater than the Method Detection Limit but less than the Reporting Limit.
n
The hold time for sample preparation and/or analysis was exceeded.
D
The result is reported from a dilution.
Di
The result exceeded the linear range of the calibration or is estimated due to interference,
MC
The result is below the Minimum Compound Limit.
*
The result exceeds the Regulatory Limit or Maximum Contamination Limit.
m
Manual integration was used to determine the area response.
d
Manual integration in which peak was deleted
N
The result is: presumptive based on a Mass Spectral library search assuming a 1:1 response.
P
The second column confirmation exceeded 25 % difference.
C
The result bas been confirmed by GC/MS.
X
The result was not confirmed when GUMS Analysis was performed.
BIRO+
The analyte was detected in the associated blank.
G
The ICB or CCB contained reportable amounts of analyte.
QC-/+
The CCV recovery failed low (-) or high (+).
R/QDR
The RPD was outside of accepted recovery limits.
QL-/+
The LCS or LCSD recovery failed low (-) or high (+),
QLR
The LCS/LCSD RPD was outside of accepted recovery limits.
QM-/+
The MS or MSD recovery failed low (-) or high (+).
QMR
The MS/MSD RPD was outside of accepted recovery limits.
QV-/+
The ICV recovery failed low (-) or high (+),
S
The spike result was outside of accepted recovery limits.
Z
Deviation; A deviation from the method was performed; Please refer to the Case Narrative for
additional information
Acronyms
ND
Not Detected RL ReportingLimit
QC
Quality Control MDL Method Detection Limit
MB
Method Blank LOD Level of Detection
LCS
Laboratory Control Sample LOQ Level of Quamitation
LCSD
Laboratory Control Sample Duplicate PQL Practical Quantitation Limit
QCS
Quality Control Sample CRQL Contract Required Cumulation Limit
DUP
Duplicate PL Permit Limit
MS
Matrix Spike RegLvl Regulatory Limit
MSD
Matrix Spike Duplicate MCL Maximum Contamination Limit
RPD
Relative Percent Different MinCL Minimum Compound Limit
ICV
Initial Calibration Verification RA Reanalysis
ICB
Initial Calibration Blank RE Reextraction
CCV
Continuing Calibration Verification TIC Tentatively Identified Compound
CCB
Continuing Calibration Blank RT Retention Time
RLC
Reporting Limit Check CF Calibration Factor
DF
Dilution Factor RF Response Factor
This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting.
Please refer to the Analytical Notes. in the Case Narrative for any Qualifiers or Acronyms that do not appear in this
list or for additional information regarding the use of these Qualifiers on reported data.
Original
Page 3 of 27

5u ill Summit Environmental Technologies, Inc. WOrkorder
3310 Win St.
MVIRONWNUL IBCNNO LOG IES, INC Cuyahoga Falls, Ohio 44223 Sample Summary
Artafytiral taho+'atorles TEL: [phone] FAX. [phone] WO#: 18011035
Websile: hun lAvrnv.settek.com 31-Jan-18
CLIENT: Synagro
Project: CherryvilleWWTP
Lab SampleID Client Sample TD Tag No Date Collected Date Received Matrix
18011035-001 Chenyville W WTP (2017 t/22/2018 10:00:00 AM 1/23/2018 7:45:00 AM Sludge
Material)
Page 4 of 27

® SUMMIT sm,n»i,andn„menml n„n310WhySt. nATEs REroxT
331011'ns S).
NVIHO N MENTAL 1`ECHNOL001ES, INC. C,Onhoga Falls, Ohio 44223 WO&: 18011035
ArralyNoel LaWrafaries TV,: (330) 2534211 FAX..- [phone]
w aa;,e: hW.1Ae,rw..cenok,rnn 31-✓nn-IS
Client: Synagro
Project: Cherryville WWTP
Samplem Client Sample lD Collection Date Matrix 'test Name Leadate Date Prep Date Analysis Date
180I1035AOIA
ChenyvilleWW33'(2017
1/22I20181000:00
AM
Sludge ignitability of Solids (BW-846: 1030)
1/25/2018 I:00;00 PM
pH(SW9045D)
I/30/201810800PM
Aeactrve Cyanide (9014n33 )-Solid
1/25/201812:04:00
PM
Reecfive Sulfide (9034)/7.3.4.2
1/25/2018 12:04D0
PM
TCLP Herbicides Analysis(SWI311/e 1/25/20186:00:00
PM
1126/201812300OPM
1/30/20182:49:OOPM
TCLP Mercury Analysis(SW1311/7471125/20186:00:00
PM
1/26/201812:45:00 PM
1/26120184:
18.00
PM
TCLP Metals Analysis (SW1311160101R5/20186:00:00
PM
1/26/201812:WOO PM
1131/201912:46:16
AM
TCLP Pesticides Analysis (SW1311/8(1/25/20186U0.00
PM
1129=189.00:00 AM
1129/20188:32:00
PM
TCLP Semi-Volatiles Analysis 1/25/20186:00:00
PM
129/20187:OUR) AM
1/29/2018 9
20:00
PM
(SW1311/8270)
TCLP Vclatiles Analysis
1/2912018600:00 PM
1/30/20187.2900
PM
Original
Page 5 of 27

snn,m;SEnvfronmenra/Technom0Wi St. Analytical Report
3310 Win St.
ffisummilt
, Cuyahoga Falls, Ohio 44223 (base report)
Analytical tabaaturles TEL: [phone] FLY: [phone] WO#: 18011035
Websile: hity.Jliiviviv.seirek.com Date Reported: 1/31/2018
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 1/22/2018 10:00:00 AM
Lab ID: 18011035-OOIA.
Project: CherryvilleWWTP
Client Sample ID Cherryville W WTP (2017 Material)
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW7470A SW7470A Analyst: EAM
TCLP MERCURY ANALYSIS (SW131117470)
TCLP Mercury ND 0.00200 mg/L 1 1/26/2018 4:18:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW6010D SW3010A Analyst: KMS
TCLP METALS ANALYSIS (SW131116010)
TCLP Arsenic(As) ND 0,500 mg/L 1 1/31/2018 12:46:16 AM
TCLP Barium(Ba) ND 5.00 mg/L 1 11311201812:46:16 AM
TCLP Cadmium(Cd) ND 0A00 mg/L 1 1131/201812:46:16 AM
TCLP Chromium(Cr) ND 0.200 mg/L 1 1/311201812:46:16 AM
TCLP Lead(Pb) ND 0.500 mg/L 1 1/311201812:46:16 AM
TCLP Selenium(Se) ND 0.0500 mg/L 1 1/31/201812:46:16 AM
TCLP Silver(Ag) ND 0.500 mg/L 1 1/31/2018 12:46:16 AM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270D SW351OC Analyst: BJH
TCLP SEMI-VOLATILES. ANALYSIS (SW1311/8270)
1,4-Dichlorobenzene ND 0.0800 mg/L 2 1/29/2018 9:20:00 PM
2,4,5-Trichlorophenol ND 0.200 mg/L 2 1/29/2018 9:20:00 PM
2,4,6-Trichlorophenol ND 0.200 mg/L 2 1/29/2018 9:20:00 PM
2,4-Dinitrotoluene ND 0.0400 mg1L 2 1/29/2018 9:20:00 PM
o-Cresol ND 0.200 mg/L 2 1129120189:20:00 PM
m/p-Cresol(s) ND 0.200 mg/L 2 1/29/2018 9:20:00 PM
Cresols, Total ND 4.00 mg/L 2 1/29/2018 9:20:00 PM
Hexachloro-1,3-butadiene ND 0.0160 mg/L 2 1/29/2018 9:20:00 PM
Hexachlorobenzene ND 0.0400 mg/L 2 1/29/2018 9:20:00 PM
Hexachloroethane ND 0.0800 QC+ mg/L 2 1/29/2018 9:20:00 PM
Nitrobenzene ND 0.0800 mg/L 2 1/29/2018 9:20:00 PM
Pentachlorophenol ND 0.200 mg/L 2 1/29/2018 9:20:00 PM
Pyridine ND 0.200 mg1L 2 1/29/2018 9:20:00 PM
Surr. 2-Fluorophenol 19.9 10 - 109 %Rec 2 1/29/2018 9:20:00 PM
Surr Phenol-d6 9.28 10 - 109 S %Rec 2 1/29/2018 9:20:00 PM
Surr. Nitrobenzene-d5 44.9 19 - 120 %Rec 2 1/29/2018 9:20:00 PM
Surr. 2,4,6-Tribromophenol 24.0 10- 120 %Rec 2 1/2912018 9:20:00 PM
Surr: 2-Fluorobiphenyl 59.8 22 - 117 %Rec 2 1/29/2018 9:20:00 PM
Qualifies; ' Value exceeds Maximum Contaminant Level..
H Holding times Car preparation or
E Value above quan[itation range
Page 6 of 27

Summit Environmental Technologies,nSc.t. Analytical Report
SUMMIT
33J0s, St.
nNYnRONh1ENTAL IECHNOLOOIE5, mc; Cuyahoga Falls, Ohio 44223 (base report)
Ao3fyfirar Laba'acorlas TEL: [phone] FAzK [phone] WO#: 18011035
Website: htto://ujiruo.settekcom Date Reported: 1/31/2018
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 1/22/2018 10:00:00 AM
Lab ID: 18011035-OOIA
Project: Cherryville WWTP
Client Sample ID Chenyville W WTP (2017 Material)
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB*SOLID SW8270D SW3510C Analyst: BJH
TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270)
Surr: p-Terphenyl-dl4 63.8 34 - 116 % Rec 2 1/29/2018 9:20:00 PM
NOTES:
Sample exhibited low recovery for Surrogate: phenol-d6 due to matrix effect.
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8081 SW3510C Analyst: JBN
TCLP PESTICIDES ANALYSIS (SW131118081)
Chlordane, total ND 0.0200 mg/L 2 1/29/2018 8:32:00 PM
Toxaphene NO 0.0400 mg/L 2 1/29/2018 8:32:00 PM
Endrin ND 0.00200 mg/L 2 1/29/2018 8:32:00 PM
gamma-BHC ND a00200 mg/L 2 1/29/2018 8:32:00 PM
Heptachlor NO 0.00200 mg/L 2 1/29/2018 8:32:00 PM
Heptachlor epoxide ND 0.00200 mg/L 2 1/29/2018 8:32:00 PM
Methoxychlor NO 0.00200 mg/L 2 1/29/2018 8:32:00 PM
Surr: TCMX 76.6 10 - 119 % Rec 2 1/29/2018 8:32:00 PM
Surr: DCB 62.6 10 - 119 % Rec 2 1/29/2018 8:32:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8151A SW8151A Analyst: JBN
TCLP HERBICIDES ANALYSIS (SW1311/8151)
214-D ND 1.00 mg/L 1 1/30/2018 2:49:00 PM
2,4,5-TP ND 0,500 d mg/L 1 1/30120182:49:00 PM
Surr. DCAA ill 20 - 140 % Rec 1 1/30/2018 2:49:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8260B SW1311M Analyst: MES
TCLP VOLATILES ANALYSIS
1,1-Dichloroethene ND 0.0500 mg/L 10 1/30/2018 7:29:00 PM
1,2-Dichloroethane ND 0.0500 mg/L 10 1/30/2018 7:29:00 PM
MEK NO 0.250 mg/L 10 1/30/2018 7:29:00 PM
Benzene ND 0.0500 mg/L 10 1/30120187:29:00 PM
Carbon tetrachloride NO 0.0500 mg/L 10 1130/2018 7:29:00 PM
Chlorobenzene ND 0.0500 mg/L 10 1/30/2018 7:29:00 PM
Chloroform ND 0.0500 mg/L 10 1/30/2018 7:29:00 PM
Tetrachloroethene NO 0.0500 mg/L 10 1/30/2018 7:29:00 PM
Qualifiers: ' Value exceeds Maximum Contaminant Level. E Value above quantitation range
H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response
MC Value is below Minimum Compound Limit. N Tentatively identified compounds
NO Not Detected O RSD is greater than RSDlimit
P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 7 of 27

u ,•r Summit Envtronmenta/Techno,WSt. Analytical Report
331010 Win St.
ffi
1-tdVIRONM€N7AL 7fCBNOLOCleS,,NC Ceryahoga Falls, Ohio 44223 (base report)
Analytical Laboratories TEL: [phone] FAX: [phone] WO#: 18011035
Welsite: Lga/Anow settekcoin Date Reported: 1/31/2018
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 1/22/2018 10:00:00 AM
Lab ID: 18011035-OOIA
Project: Cherryville WWTP
Client Sample ID Cherryville W WTP (2017 Material)
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
RCI-SOLID-WI IG N ITAB ILITY1030
REACTNE CYANIDE (9014/7.3.3.2)-SOLID
Cyanide, Reactive ND
W8260B SW7311M Analyst: MES
0.0500
mglL
10
1/30/20187:29:00
PM
0.0200
mg/L
10
1/30/2018 7:29:00
PM
70 - 130
% Rec
10
1/30/2018 7:29:00
PM
70 - 130
%Rec
10
1/30/2018 7:29:00
PM
70 - 130
%Rec
10
1/30/2018 7:29:00
PM
SW9014
Analyst:
MS
0.500 mg/Kg 1 1/25/2018 12:04:00 PM
RCI-SOLID-'All IGNITABILITY1030 SW1030 Analyst: AJT
IGNITABILITY OF SOLIDS {SW-846: 1030)
Ignitability non -Flammable 1 1/25/2018 1:00:00 PM
RC6S0LID-WI IGNITABILITY1030 SW9045D Analyst: DHC
PH (SW9045D)
pH 7.2 s.u.@19.4C 1 1/30120181:08:00 PM
RCI-SOLID-W/ IGNITABILITY1030 SW9034 Analyst: MS
REACTIVE SULFIDE (9034)17.3.4.2
Sulfide, Reactive 30.0 25.0 mg/Kg 1 1/25/2018 12:04:00 PM
Qualifiers: ' Value exceeds Maximum Contaminant Level.
H Holding times for preparation or analysis exceeded
MC Value is below Minimum Compound Limit.
ND Not Detected
P Second column confirmation exceeds
R RPD outside accepted recovery limits
E Value above quantitafion range
M Manual Integration used to determine azea response.
N Tentatively idontified compounds
O RSD is greater than RSDlimit
PL Permit Limit Original
RL Reporting Detection Limit
Page 8 of 27

frSUMMIEF
summttEnnironmental r chnologies, Inc. Accreditation Program
3310 Win St. Anal tes Report
RWIROM IENTAL rfCRNOLOalE5, INC Cuyahoga Falls, Ohio 44223 y p
Analyffeal Labo+'atoohn; TEL: [phone] FAX: [phone] WO#: 18011035
Website: htto.lAj�wii� settek.coni 314ttn48
Client: Synagro. State: NW
Project: CherryvilleWWTP Program Name: NC—WW—SCM
Sample ID Matrix Test Name Aoalyte Status
18011035-001A Sludge.
Ignitability of Solids(SW-846:1030)
lgiitabiliry
A
Sludge
pH(SW9045D)
Hydrogen Ion (pH)
A
Sludge
Reactive Cyanide (9014/7.3.3 2)-Solid
Cyanide, Reactive
U
Sludge
Reactive Sulfide (9034)/7.3.4 2
Sulfide, Reactive
U
Sludge
TCLP Herbicides Analysis(SW1311/8151)
22475-TP
A
Sludge
TCLP Herbicides Analysis(SW1311/8151)
2,4-D
A
Sludge
TCLP Herbicides Analysis (SWI311/8151)
DCAA
A
Sludge
TCLP Mercury Analysis(SWI 311/7470)
Mercury
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Arsenic
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Barium
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Cadmium
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Chromium
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Lead
A
Sludge
TCLP Metals Analysis (SW 1311/6010)
Selenium
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Silver
A
Sludge
TCLP Pesticides Analysis(SW1311/8081)
222,23,3154,4%5,5',6,6'-
A
Decachlorobiphenyl
Sludge
TCLP Pesticides Analysis(SW1311/8081)
Chlordane, total
A
Sludge
TCLP Pesticides Analysis (SW1311/808 1)
Enddn
A
Sludge
TCLP Pesticides Analysis(SWI 311/8081)
gamma-BHC
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Heptachlor
A
Sludge
TCLP Pesticides Analysis (SW1311/808 1)
Heptachlor epoxide
A
Sludge
TCLP Pesticides Analysis (SW13l t/8081)
Metboxychlor
A
Sludge
TCLP Pesticides Analysis (SWI 311/808 1)
Tetrachloro-m-xyiene
A
Sludge
TCLP Pesticides Analysis (SW1311/808 1)
Toxaphene
A
Sludge
TCLP Semi-Volatiles Analysis(SW1311/8270)
1,4-Dichlorobenzene
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
2,4,5-Trichlorophenol
A
Sludge
TCLP Semi-Volatiles Analysis(SW1311/8270)
2,4,6-Tribromophenol
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
2,4,6-Trichlorophenol
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
2,4-Dinitrotoluene
A
Sludge
TCLP Semi-Volatiles Analysis(SW1311/8270)
2-Fluombiphenyl
A
Sludge
TCLP Semi-Volatiles Analysis(SW1311/8270)
2-171uomphenol
A
Key
Key
NC WW SCM A Accredited
NC WW SCM U Unavailable
Original #1
Page 9 of 27

UMM111 Summit Environmental Technologies, Inc. Accreditation Program
MnS3310 Win St. Anal teS Report
rPWIRONNIENTAL IECWNGLOGIES, INC Cuyahoga Falls, Ohio 44223 Y p
Anafyfiral Labormorles TEL: [phone] FAX: [phone] WO#: 18011035
Website: htro.-//www.settekcom 31-Jan-18
Client: Synagro State: NW
Project: Cherryv111cWWTP Program Name: NC_WW_SCM
SampleID Matrix
'Pest Name
Analyte
S[atus
18011035-OOIA Sludge
TCLP
Semi-Volatiles Amlysis(SW1311/8270)
2-Methylphenol
A
Sludge
TCLP
Semi-Volatiles Analysis(SW1311/8270)
3A-Methylphenol
A
Sludge
TCLP
Semi-Volatiles Analysis(SW1311/8270)
Cresols, Total
A
Sludge
TCLP
Semi-Volatiles Analysis(SW1311/8270)
Hexachlorobenzene
A
Sludge
TCLP
Semi-Volatiles Analysis (SW131118270)
Hexachlorobutadiene
A
Sludge
TCLP
Semi-Volatiles Analysis (SW1311/8270)
Hexachloroethane
A
Sludge
TCLP
Semi-Volatiles Analysis(SW13I1/8270)
Nitrobenzene
A
Sludge
TCLP
Semi-Volatiles Analysis(SW1311/8270)
Nitrobenzene-d5
A
Sludge
TCLP
Semi-Volatiles Analysis(SW1311/8270)
Pentaeblorophenol
A
Sludge
TCLP
Semi-Volatiles Analysis(SW1311/8270)
Phenol-d6
A
Sludge
TCLP
Semi-Volatiles Analysis(SW1311/8270)
p-Terphenyl-dl4
A
Sludge
TCLP
Semi-Volatiles Analysis(SW1311/8270)
Pyridine
A
Sludge
TCLP Volatiles Analysis
1,1-Dichloroethene
A
Sludge
TCLP Volatiles Analysis
1,2-Dichloroethane
A
Sludge
TCLP Volatiles Analysis
2-Butanone
A
Sludge
TCLP Volatiles Analysis
4-Bromofluorobenzene
A
Sludge
TCLP Volatiles Analysis
Benzene
A
Sludge
TCLP Volatiles Analysis
Carbon tetrachloride
A
Sludge
TCLP Volatiles Analysis
Chlorobenzene
A
Sludge
TCLP Volatiles Analysis
Chloroform
A
Sludge
TCLP Volatiles Analysis
Dibromofluoromethane
A
Sludge
TCLP Volatiles Analysis
Tetrachloroethene
A
Sludge
TCLP Volatiles Analysis
Toluene-d8
A
Sludge
TCLP Volatiles Analysis
Trichlmoethene
A
Sludge
TCLP Volatiles Analysis
Vinyl chloride
A
I{¢y
Key
NC WW SCM A Accredited
NC_WW_SCM U Unavailable
Original #1
Page 10 of 27

SUMMIT s,mnall�rn „me,,,alreh„alas;WinS. QC SUMMARY REPORT
3310 {i'r'n St.
Er ENVI90MMCNTAL TFC11NOLC IES, INC CuyahmaTalls, Ohio 44223 WOB: 18011035
Arrayf1ea11,ebAnfofles ZEL:(330) 25.34211 PLY.'[phone]
greaser: Ime lAlwo'_w1hocfnm 31-Jma48
Client: Synagro
Project: Chenyville WWTP EatchID: 30581
RunNo: 79934
Sample lD MB-30581
SampType:
MBLK
TestCotle:
HG_TCLP(]4 Units: mg/L
Prep Date: 1126/2018
Client ID: PBS
Batch ID:
30581
TestNo;
SW7470A SW7470A
Analysis Date: 1/26/2018
SegNo: 1392423
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC Lowl-imit HighLimit RPDRef Val
%RPD RPDLimit Qual
P Mercury
ND 0.00200
mpie lD
LCS-30581
SampType:
LCS
TestCotle:
HG_TCLP(74 Units: mg/L
Prep Dete: 1/26/2018
RunNo: ]9934
entlD:
LCSS
Batch to
30581
TesNo:
SW7470A SW7470A
Analysis Data: 1/26/2018
SegNo: 139M24
alyte
Result
PQL
SPKvalue SPKRef Val
%REC LowUnnit HighLimil RPDRef Val
%RPD RPDLimit oust
.P Mercury 0.00467 0.00200 0.O0400 0 117 80 12D
Sample ID
18017013-001AM5
SampType:
MS
TestCode:
HG_TCLP(74 Units: mg/L
Prep Date: 1/26/2018
RunNo: 79934
Client ID:
BatchQC
Batch ID:
30581
TestNo:
SW7470A 81gDr470A
Analysis Date: 1/26/2018
SegNo: 1392426
Analyte
Result
PQL
SPKvalue SPKRefVal
%REC LowLimit HighLimil RPDRef Val
%RPD RPDLimit Qual
-P Mercury 0.00541 0.00200 0.00400 0.0000600 134 75 125
RunNo: 79934
Sample ID
18011013-001AMSD
SampType:
MSD
TestCode:
HG_TCLP(]4 Units: mg/L
Prep Dale: 1126/2018
Client ID:
BatchQC
Balch ID:
30681
TestNo:
SW7470A SW7470A
Analysis Oate: 1/26120te
SegNo: 1392427
Analyte
Result
PQL
SPKvalue SPKRaf Val
%REC LowLimit HighUmit RPDRef Val
%RPD RPDLImit Qual
TGIF Mercury
0.00513 0.00200
0.00400 0.0000600 127 75
125
0.00541 5.31
Qualifiers: "
20 S
Original
Page 11 of 27

®SuMMM'f s,»»»nFnaro»»,e»r»11beh»3310Wi)El.
ENVIRONIAFNTAL TCCHNOLOGI=_S, INC Curpaoga Falle', Ohio. 41223
WO#: 18011035
ANelyV"I Labcra c(nv5 In: [phone] FAX.[phone]
W bule: hh»./MF re senekcw 31-✓an-18
Client: Synagro
Project: Chenyville WWTP BatchID: 30581
RunNo: 79934
Sample lD
18071013401AMS0
SampType:
MSD
TestCotla:
HG_TCLP(74 Units'. mglL
Prep Date: 7/26/2018
Client ID:
BatchQC
Batch ID:
30581
TestNo:
SW7470A SW7470A
Analysis Date: 1/26/2018
SegNo: 139M27
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLimit HghLimit RPDRef Val
%RPD RPDLimit Qual
Qualifiers: • Value exceeds Maximum Contaminan[Level. B Analye detected in the associated McNod Hlank E Value above quanritatien range
H Holdingtimes forprepamtion or analysis exceeded I Analyte detected below quaimtation limits M Manual ]n[egration used to determine
MC Value isba owMiaam onainm mit. ND Not Detected O RSD is greater than RSDlimit Original
P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits
Page 12 of 27

®SIlMMIt s ,n1f mirmm,enfalrnnnaoges,Inu. Q'C 6i]MMARYREPORT
3310 Wi0 Sf.
ENVIRCINIMUNTALTECtIN(I INC Gryahoga Fala,, Ohio 44223 WOk: 18011035
Arcalpllcel fabOr'alsol TEL: [phone] FAX[phone]
Websife bur. -/A seftekcon 31.ZrtN-18
Client: Synagro
Project: Chertyville WWTP BatchlD: 30592
RunNo: 80052
mple ID
m630592
SampType:
mink
TestCode:
tclp-svoc-her
Units: mglL
Prep Date: 1/26/2018
ant 10:
PBS
Batch ID:
30592
TestNo:
SW8161A
SW8161A
Analysis Date: 1/30/2016
SegNc: 1397310
ialyte
Result
PQL
SPKvalua
SPKRef Val
%REC LowLimit Highl-imll RPDRef Val
%RPD RPDUmd Qual
2,4-D
mire
ND
1.00
0
0
5-TP
ND
0.500
0
0
Sun: DCAA
542
500.0
108 20 140
RunNo: 80062
ID
Ics30592
SampType:
Ics
TeslCode:
tclp-svoc-her
Units: mg/L
Prep Dale: 1/26/2018
ant ID:
LCSS
Batch ID:
30592
TestNo:
SW8161A
SW8151A
Analysis Dale: 113012018
SegNo: 1397311
elyte
Result
PQL
SPK value
SPK Ref Val
%REC LowLimit Highl-imit RPD Ref Val
%RPD RPDLimlt Qual
2,40
ND
1.00
0.500
0
94.3
62.6
125
5-TP
NO
0.500
0.500
0
94.3
52.5
128
Sort DCAA
539
500.0
108
20
140
Qualifiers: * Veluc exceeds Maximum Contamina¢tlevel.
Original
Page 13 of 27
H Analyze detected in the associated McNad Hlank
E
Value above quentila5on ren6e
13 Holdin8 times for preparation or analysis exceeded
1 Analyze detected below quaatiUti¢n limits
M
Manual Integration used to determine
MC Value is below Minimum Compmnd limit
ND Not Detected
Q
RSD is Bmater than RSDlimit
P Second column con8mm0on exceeds
PL Penwt Limit
R
RPD outside accepted recovery limits

®SUNI1Vl17 sa»„rlFarr,»»,e»nitre»meal» QCSi7MMARYREPORT
3310WR'i» wS Sl.
ENVIRQN1AFNTAL TECHNOLOGIES, INC Clryan08aFalG', Ohio 44223
Ahal yflcal l a5orsra,'les WO#: 18011035
M: (330) 2534211 FAX' [phone]
Wehxile: bap.-Iimm..mnekemn 314an-18
CHeat: Synagro
Project: CherryvilleWWTP BatchID: 30600
Sample ID
18011034.001AMS
SampType:
MS
TeslCode:
SVOC-BNA_T Units: mg/L
Prep Date: 112912018
RunNo: 80053
Client to
BalCNQO
Batch ID:
30600
TeslNo:
SW82700 SW3510C
Analysis Date: 1129/2018
SegNo: 1397326
Analyte
Result
PQL
SPKvalua SPK Ref Val
%REC LowLlmit Highl-lmit RPDRef Val
%RPD RPDLimit Qual
1,4-Dichlorobenzene
0.684
0.080D
O.8000
0
85.6
15.2
124
OC+
S
Qnnlifiers. ' Value ceeds Maximum Contaminant Level. B Analytic detected in the associated Method Blank E Velrie above quantitation range
H Holdingtimes for preparation or analyais exceeded I Analylede[ecled below quanetazion limits M Manual Alegratien usedmdetermine Original
MC Value is below Miniivum Compound Limit. ND No[Derected D RS➢is greeterihen RSDlimit
P Second column confirmation exceeds PL Permit Limit R RPDoutsideaccepledrecovery limits
Page 14 of 27

SUMMIT sm m;rDnmm„nwllalTechn3100 Wm gi.W rSt. QG SUMMARY REPORT
ENVIRONMENTAL TECHNOLOOI�9, INC Cuyahoga Falls, Ohio 44223 WON: 18011035
Analytical Laborstarle5 TEL: [phone] F• ... [phone]
Websim: h/m YFnvertek aor 31-✓an-18
Client: Synagro
Project: Cherryville WWTP Batchll): 30600
RunNo: 80053
Sample 10
18077034401AMS0
SampType:
MSO
TestCode:
SVOC-BNA_T Units: mglL
Prep Date: 112912018
ClientlD:
BatchQC
Batch ID:
30600
TestNo:
SW8270D SW3610C
Analysis Date: 1/29/2018
SegNo: 1397327
Anayyes
Result
PQL
SPKvalue SPKRef Val
%REC LowLimit HighLlmll RPDRMVal
%RPD RPDUmit Qual
1,4-Dichlorobenzene
0.627
0.0800
Qualifiers: • Value exceeds Maximum Contaminantlevel.
H 13oldin8times for preparadan or analysis exceeded
MC Valueis below Minimum Compound Limit.
P Second column confirmed on exceeds
0.8000
0
78.4
15.2
124
0.6844
8.72
30
B
Mely[edetected in the asieciated Method Hlank
E
Value nbove quandmdan range
1
Meiy[e detected below quandtetioo limits
M
Manual integretionused Wdetermine Qriginal
Ira
Not Deemed
O
RSD is 6materthen RSDlimil
PL
Permit Limit
R
RPD outside accepted recovery limits
Page 15 of 27

®SUMMIt 3310 Nsa,m;,Fa,i.armrenalTaha,mS, QC SUMMARY REPORT
101frria Sl.
ENVIRONFIaWAL TECNNO1,00tE3,tNC Caychuga Falls, Ohio 44223 WOR: 18011035
ArYalidmol 4aban, fades Ta: [phone] NAX: [phone]
Websue: hap/Ann elrekrvm 31-✓rat-18
Client: Synagro
Project: Cherryville W WTP BatchID: 30617
RunNo: 80054
Sample ID
mb�30617
SampType:
MBLK
TesFCotle:
tclp-voo-mstr Units: mg/L
Prep Date: 712912018
ClienllD:
PBS
Batch ID:
30617
Teslo:
SW8260B Si
Analysis Dale: 1/30/2018
SegNo: 1397357
Analyle
Result
PQL
SPKvalue SPKRef Val
%REC LoWLimit Highl-imit RPDRef Val
%RPD RPDLimit Qua[
1,1-Dlchloroethene
ND
0.0500
1,2-Dichlaroethane
NO
0.0500
MEK
ND
0.250
Benzene
ND
0.0500
Carbon tetrachloride
No
0.0500
Chlcrobenzene
ND
0,0500
Chloroform
ND
0,0500
Torachloroethene
NO
0.0500
Trichloroethene
NO
0,0500
Vinyl chloride
ND
0.0200
Burr: 4-Bromof[uorobenzene
496
Burr. Dlbromofluoromelhane
482
Burr. ToluenedB
499
Qonlifiers: ° Valueexceeds Maximum Contaminant Level.
H Holdingtimes Forprepa a4ion oranalYsis exceeded
MC Vetue is below Minimum Compound Limi[.
P Second column confirmation exceWs
500.0
99.1
70
130
500.0
96.4
70
130
500.0
99.9
70
130
B Analyte detected in the associated Medtod Dlemk E Velue above quan0tadon range.
! MalYte detested below quantitafion limits M. Manual integration used to determine
ND Not Detected Q RB➢is greatarthan RSDllmi[ Original
PL Permit Limit R RPD outside acceptedrecovery limits
Page 16 of 27

310 � lIlN1/V117 3 s„»a.unnmm»„mna1T m310 „ . QC SiJ1VIMARY REPORT
May.ny.5l.
ENVIIONb1CN-Nd. TECNNOLOaregr INe_ C»yahoga Falls, Ohio 44223 WO#: 18011035
®
Arealyllcal tabooef sdrs TEL: [phone] FAA:' (330) 253-448P
Webale: ] ttp /M cow re,takcn»r 3&7air-18
Client: Synagro
Project: Chersyville WWTP BatehID: 30617
Sample lD
18010967-001ams
SampType:
MS
TestCotle:
tclp-voc-MST Units: mg/L
Prep Date:
RunNo: 80027
ClientlD:
BatchQC
Balch to
30617
TestNo:
SW82608 SW1311M
Analysis Date: 1/3012018
SegNo: 1397295
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC Lowl-lrnit HighLimit RPDRef Val
%RPD RPDLImd Qual
1,1-Dichloroethene
0.221
0.0500
0.200
0
110
39.9
1fi0
1,2-Dichloroethane
0.191
0.0500
0200.
0
95.3
42.5
157
MEK
1.02
0.250
1.00
0.0476
96.8
10.6
227
Benzene
0.195
0.05DO
0,200
0
97.6
38.1
155
Carbon tetrachloride
0.195
0.0500
0.200
0
98.1
40.8
162
Chlorobenzene
0.191
0.0500
0.200
0
956
35.7
168
Chloroform
0,199
0.0500
0.200
0
99.3
18.3
199
Tetrachleroethene
0.205
0.0500
0.200
0
102
10
261
Trichlaroethene
0.194
0.0500.
0,200
0
97.0
23.8
175
Vinyl chloride
0.171
002M
0.200
0
85.6
10
165
Sun. 4-Bromofiuorobenzene
526
5OS0
105
84.6
130
Surr: Dibromofluoromethane
505
500.0
101
71A
127
Sort Toluene -dB
515
500.0
103
74.6
127
Sample ID
1801096]-0Otamsd
SampType:
MSD
TeslCode:
tclp-voc-MST Units: mglL
Prep Dale:
RunNo: 80027
Client ID:
BatchQC
Batch ID:
30617
TesWo:
SW8260B SW1311M
Analysis Date: 1130Y2018
SegNo: 1397297
Analya
Result
PQL
SPKvalue SPKRef Val
%REC LowUrnit HighLimit RPDRef Val
%RPD RPDLImt Qual
1,1-Dichloroelhene
0.227
0.0500
0.200
0
113
39.9
H Analyze detected in the associated Method Blank
I Melyte detected below retardation limits
ND Nat Detected
PL Permit Limit
160
0221
1.54
25
E Value above 9uantiiation range
M Manual Integration used to determine
0 RSD is greeterihen RSDlimi[
R RSD outside accepted recovery limits
Original
Page 17 of 27

®SVMMt=-,ra„,a,;r ,;.a„mearalraem3310;WINSt. QC SUMMARY REPORT
3vo wm sr.
ENVIHONIAENrAI, TECHNOLOGIES, INC OryanogurFalln', Ohio 44223
IVOd: 18011035
Ahalylfcal Isbaratamev ]EL:(330) 2534211 FAX'[phone]
Websire: Intn'//wow serrekcm 31-Tnn-18
Client: Synagro
Project: Cherryville WWTP BatchiD: 30617
RunNo: 80027
Sample l0
18010967-00tamstl
SampType:
MSD
TesfCode:
tclp-vvc-MST Units: mg/L
Prep Dale:
Mentor
BatchQD
Batch ID:
30617
TestNo:
SW8260B SW1311M
Analysis Dale: 1/30/2018
SegNo: 1397297
Analyte
Result
PQL
SPK value SPK Ref Val
%REC LowLimil Highl-imit RPD Ref Val
%RPD RPDLimil Qual
Carbon tetrachloride
0.198
0.0500
0.200
0
99.1
40.8
162
0.196
1.03
2s
Chlorob enzene
0.192
0.0500
0200.
0
96.1
35.7
168
0,191
0,600
25
Chloroform
0.201
0.0500
0.200
0
100
16.3
199
0.199
1.04
25
Tetrachlomelhene
0209
0,0500
0.200
0
105
10
261
0.205
2.18
25
Trichloroethene
0.197
0.0500
0.200
0
98.7
M.8
175
0.194
1.79
25
Vinyl chloride
0.198
0.02W
0.200
0
98.9
10
165
0.171
14.4
25
Sort. 4-13rcmoflusrabenzene
522
500.0
104
84.6
130
0
25
Sun: Dlbromafluaromeihane
505
500.0
101
71.4
127
0
25
Surr: Toluen"13
514
500C
103
74C
127
0
25
rjuelifiere: `
Value exceeds Maximum Contaminant Level.
B
Analyte detected in the associated Method Blank
E
Value above quentitation range
H
Holding timesfor preparation or analysis exceeded
!
Analy[e detected below quentitation limits
M
Manuel lnteylation used to determine Original
MC
Value is below Minimum Compound Limit
ND
Na[Deteaed
D
RSD is greater than RSDlimit
P
Second column conilrmation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits
Page 18 of 27

uMMLr Sane.,rE,H,a,nnenra,Tcha310WinSt. QC SiJMMARYREPORT
i 33I0 Win St.
ENVIRONMENTAL TWIMOLOGIES, INC Cityaboga Falls, Ohio 44223 WOk: 18011035
Anity0val Lebcdefnrles TFI.:(330) 2534211 FAX:[phone]
Wehsile: hom.lA, to crrek.eom 31-11'pn-18
Client: Syhagro
Project: Cherryville WWTP BatCLID: R79880
mple ID MB-R79B80
SampType:
MBLK
TestCode:
Cyanitle,Rea Units: mg/L
Prep Date:
RunNo: 79880
ant ID: PBW
Batch ID:
R79880
TestNo:
SW9014
Analysis Dale: 1/25/2018
SegNo: 1390960
style
Result
PQL
SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDUmit Qual
Inide, Reactive
NO 0.500
mple ID LCS-R79880
SampType:
LCB
TestCode:
Cyanide,Rea Units: mg/L
Prep Date:
RunNo: 79880
.nt ID: LCSW
Batch ID:
R79880
Te$INo:
SW9014
Analysis Date: 1/2512018
SegNo: 1390962
alyte
Result
PQL
SPKValue SPKRef Val
%REC LowLimit HlghLimit RPDRef Val
%RPD RPDLimit Qual
Cyanide, Reactive 0.987 0.500 1.000 0 96/ ab 11e
mple l❑
18010875401AM5
SampType:
MS
TestCode:
Cyanide,Rea Units: mglL
Prep Date:
RunNo: 79880
ant ID:
BatchQC
Batch ID:
R798M
TestNo:
SW9014
Analysis Date: 125/2018
SegNo: 1390965
alyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLlmit HighLimit RPDRef Val
%RPD RPDLlmit Qual
Cyanide, Reactive 1.08 0.500 1.000 0 tun b1 e. 110
NOTES:
Sample was received not meeting proper temperature requirements.
RunNo: 79880
nple l0
18010875-001AM50
SampType:
MSD
TestCode:
Cyanitle,Rea Units: mglL
Prep Dale:
ant ID:
BatchQC
Batch ID:
R79880
TestNo:
SW9014
Analysis. Dale: 1/25/2018
SegNo: 1390966
alyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLlmit HighLimit RPDRef Val
%RPD RPDLimil Qual
Qunlifiera: '
Original
Page 19 of 27
Value exceeds Maximum Contaminant Level.
B
Acolyte detected in the associated Method Blank
E
Valueabove quantitation mo&e
H
Holdinytimes for preparation or analysis exceeded
I
Melyte detected below rumination limits
M
Manual integnation used to deteonine
MC
Value is belowMinian Compound limit
ND
Not Detected
D
RSD is greaterthan RSDlimit
P
Second column confirmation exceeds
PL
Pemit Limit
R
RPD outside accepledrecoveylimits

®!i�UMM��sna,a;l Fat a„a,enmlTeahn 3100 lWai 51. QC SUMMARY REPORT
limmROHMENTAL TGCHROLOGIE9, INC Cityabo8a halls, OMo 44223 WO9: 18011035
Anni l,ahvratnrles TT;L: [phone] FAX: [phone]
Wcbsile: h,m /Ann e,lek co 31_Jmr-18
Client: 8ynagro
Pr0iect: Chemville WWTP BetchED: R79880
RunNo: 79860
Sampla ID 18010076-001AMSD SampType: MSD
TestCode: Cyen itle,Ras Units: mg/L
Prep Date:
Client ID: BatchQC Batch ID: R79880
TestNo: SW9014
Analysis Date: 1/25/2018
SegNo: 1390966
Analyte Result
PQL SPKvalue SPKReFVaI
%REC Lowl-imit Highl-imil RPDRef Val
%RPD RPDLImit Qual
Cyanide, Reactive 4.07 o.uoo 2.uuu u one 0110 l q� ; —7
NOTES:
Sample was received not meeting proper temperature requirements.
Qnnlifierx. '
Value eeds Maxim mCova sot Level.
B
Analy[e detected in We associated McNod Blank
H
Holding times forprepam ranalysis ceeded
I
Mely[e detected belmv qua utsaon limits
MC
Valucisbelow MimirmintCommond Limit
ND
NO[Delected
P
Second column confirmation exceeds
PL
Permitl.imit
E Value shove quentitalion rary;e
M Manuel lntegralionused to. determine Original
0 R8D is 8reater dsen RSDlimit
R RPD outside accepted recovery limits
Page 20 of 27

s111101!7S 3310 wm SI.MM�� 3 sm �r,Finaraa:e,oarl�cn 10W, QC SUMM[1tRYREPORT
,.
CKWIPONIdENTAL TECHNCLA01ES, iHC Cagvahaga Falls, Ohio 44223
WON: 18011035
Aaah:Odal Laboratories lFL:[phone] FAX.[phone]
Webrlle: IOo 11w senelrco, 31-Tnn-l8
Client: Synagro
Project: Chercyville W WTP BatebID: R79884
RunNo: 79884
Sample ID
LCS-R]9aa4
SampType:
LCS
TestCode:
Ignitability_S Units:
Prep Date:
Client ID:
LOSS
Balch to:
R79884
TestNo:
SWI030
Analysis Date: 1126/2010
SegNo: 1391034
Analyte
Result
PQL
SPKvalue SPKRaf Val
%REC LowUnnit HghLimit RPDRef Val
%RPD RPDUmit Qual
1gn8ablllly
6.22
QPnlifiers: ' Value exceeds Maximum Covtaminantievel.
H Holding times for preparation or analysis exceeded
MC Value is below Minimum Compouvd limit.
P Second column condonation exceeds
7.240 0 85.9 70 130
H
MelNe detected in the associated McNod Blank
B
Value above quantitarion range
I
Analyze detected below quevtitation limits
M
Mavual ]ntegation used to determine
Original
ND
Not Detected
0
RSD is greeter than RSDlimit
PL
Permit Limit
R
RPD outside accepted recovery limits
Page 21 of 27

® SuMM17 3gm m„e,ra,anralTecle3370W,hre. QCSUNIMARYREPORT
waSi.
NVIRONIAEN7AL TECHHOLOOIES, INC C,n,ahaga Falls, Ohm 44223 WOR: 18011035
Anelpllcal Cabnrntories M: (330) 2534211 FAX.[phone]
Websile: hlro/An vserrekca 314/ -18
Client: Synago
Project: Chenyville WWTP BatchID: R79888
RunNo: 79888
male ID MB.R79888
SampType:
MILK
TestCode:
Sulfide Units: mglL
Prep Date:
ant ID: PBW
Batch ID:
R79888
TestNo:
SW9034
Analysis Oate: 1/25/2018
Segl4o: 1391078
alyte
Result
PQL
SPKvalue SPKRef Val
%REC Lowl-imil HighLimit RPDRef Val
%RPD RPDUmit Qual
ide, Reactive
ND 25.0
male ID LCS-R]9888
SampType:
LCS
TestCode:
Sultide,React Units: mglL
Prep Date:
RunNo: 79888
enl ID: LCSW
Batch ID:
R79888
TestNo:
SW9034
Analysis Date: 112512018
SegNo: 1391079
alyle
Result
PQL
SPKvalue SPKRef Val
%REC LowLimit HighLimit RPDRef Val
%RPD RPDLimil Qual
'Ida, Reactive 4770 25.0 RtlW u su. i ao i io
pie ID
vv
18010875-001AMS
SampType:
MS
TestCode:
Su1Fde, React Units: mglL
Prep Date:
RunNo:
79888
snt ID:
BatchQC
Batch ID:
R79888
TestNo:
SW9034
Analysis Date: 1/25/2018
SegNo:
1391081
alyte
Result
PQL
SPKvalue SPK Ref Val
%REC LowLlmit HighLimit RPD Ref Val
%RPD
RPDLImit Qual
Sulfite, Reactive 4860 25.0 4800 0 101 75 125
NOTES:
Sample was received not meeting proper temperature seen reaments.
male 10
18010875-001AMSD
SampType:
MSD
TestCode:.
Sulfide,React Units: mglL
Prep Data:
RunNo: 79888
ant ID:
BatchOC
Balch ID:
R79888
TestNo:
SW9D34
Analysis Dale: 1/2512018
SegNo: t391082
alyte
Result
PQL
SPKvalue SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Qualifiers: * Value exceeds Maximum Contamineot level.
vaginal
Page 22 of 27
H
Anelytedetected in the associated Method Blank
E
Value above quandtatton range
H Heidinetimesfor preparation or analysis exceeded
3
Maly[e detected M1elow quantization limits
M
Manuel lntegratlon used to determine
MC Value is below Minimum Compound Limit
ND
Not Detected
O
RSD is greeter than RSDlimit
P Second column con0anati on exceeds
PL
Permit Limit
R
RPD Dutside accepted recoverylimits

�um"W"M0 sm;,c,.one»lalreh,3310lVl„t. QCSi71VIMARYREPORT
3310 {V'n St.
Et:v19VNsIENThI. TECHNOLOGIES, iNc C,yabogoFalls, Ohio 44223 WOd: 18011035
A.nalyllcal L.n6Jla(atles TEL:[phone] FAX. [phone]
Welarte: ] np /h ran sercakeam 314 r-I8
Client: Synagro
Project: Chenyville WWTP BatchlD: R79838
RunNo: 79888
xample ID
18010875-001AM50
SampType:
MSD
TesiQotle:
Sulfitle,React Units: mglL
Prep Dale:
:lient ID:
BatchQC
Batch ID:
R79888
TestNo:
SW9034
Analysis Date: 1126/201B
SegNo: 1391082
knalyte
Result
PQL
SPKvmue SPKRef Val
%REC LowLimit HighLimil RPDRef Val
%RPD RPDUmit Qual
Sulfide, Reactive 4700 25.0 4800 0 97.9 75 125 4860 3.35 30 W
NOTES:
Sample was received not meeting proper temperature requirements.
Qnalifera: • Velne exceeds Maximum Conlaminvn[level.
H
Analyte detected iv theassociated Me[hod Hlank
E
Velue above quanti[ativn range
H Holding times forpreparation or melysis exceeded
J
Avalytc detected below quantilation limits
M
Manual Ategration used to detmmive
Original
MC. Vahmisbelow IsImmum Compound Limit
ND
Not Detected
0
RSD is greeter Non RSDlimit
P Second column confirmation exceeds
PL
Permitiimit
R
RPD outside accepted recovery limits
Page 23 of 27

® S lA M M l sm,rnnr� no-o o� rechnnrag Wi Sf. QC SiJMMARY REPORT
33ro win sr.
1gBON1,W"AL TECHNOLOGIES,;NC Cu3nhoga Folly, Ohio 4J223 WOW: 18011035
Analy0onl Laboralcars TEL: [phone] FAX.. [phone]
Webme: hllo lA n senek.conr 31-Jtni-18
Client: Synagro
Project: Chenyville WWTP B81chED: R80006
RunNo: 80008
iamplebr 1801142MOIADUP Samplyro DUP
TestCode: pH_Oil(9045 Units: s.u.@18.6C
Prop Date:
C lien[ID: BatchQG Balch ID: R80006
TestNo: SW9045D
Analysis Dale: 1/30/2018
Snobs: 1395686
Malyte Result
PQL SPKValue SPKR&Val %REC
LowLimlt HlghLimit RPDRef Val
%RPD RPDLimit Qual
pH
5.5
Qualifiers: ` Value execeds Maximum Contaminant Level. B Analytedetected in the associated Melhad Blank
H Holding times For prepamtipn or analysis exceeded I Analyze detected below quantita0on limits
MC Value is below Minimum Compound Limit ND Not DetectM
P Second column confirmation exceeds PI, Permit Limit
E Value above quandtation mn8e
M Mavual lntegavon usei to detemdne Original
D RSD is gmatariban R6Dllmlt
R RPD outside accepted recovery limits
Page 24 of 27

®S�MMii "r;l,m;.mnaema, �oages?SI. QCSIIMMARYREPORT
3310I�iSI.
ENVIROWNENTa1. TEC1iNOVJOIES, INC Cuyahoga Palls, Ohuo 44223 wo#: 18011035
AhalyllcnlInbdfnmrles 72M:(330) 2534211 FAX.'(330) 2534489
Websne: per 1Avsi,w.seI1ekcmn31-Jnn-]8
Client: Synago
Project: Chenyville WWTP BatchlU: R80006
RunNo: 80006
ample ID
LCS-R80006
SampType:
LCS
TestCotle:
pH OW(4500- Units: s.u.@21.7C
Prep Date:
'cant ID:
LCSW
Batch ID:
11801106
TestNo:
SW9045D
Analysis Date: 1/30/2018
SegNo: 1395673
lalyte
Result
PQL
SPKvalue SPK Ref Val
%REC
LOWLimlt Highl-lmit RPD Ref Val
%RPD RPDLimit Qual
pH 7.0 !.0 Is Mu so.o iu i.R
RunNo: 80006
tmple l0
18011149-001BDUP
SampType;
DUP
TeslCade:
pH_DW(4500- Units: s.u.&9.e0
Prep Dale:
iant ID:
BatchQC
Batch ID:
R80006
TestNo:
SW9045D
Analysis Date: 1120 18
SegNo: 1395675
salyte
Result
PQL
SPKvalue SPKRd Val
%REC
Lowl-mit HighlUmit RPDRef Val
%RPD RPDUmlt Qual
7.2
Qrrnliliers: ' E Value above qumrtitetion mnge
M Manual tv[egretion used to detemdnc
OLlginal
0 RSD is greater than RSDSmit
R RPD outside accepted recovery limits
Page 25 of 27
Value exceeds Maumum Contaminnnt Level
B
Melyte de[acted in theassociated Method Blank
H
13oldingtimes for prcpamtion or analysis exceeded
1
Malyte de[acted below quanNtafion limits
MC
Value is betow Minimum Compound Limit
!ID
Not Detected
P
Second column coMrmaaonexceds
PL
Perron Limit

® Summit L'nvimnmental'1'echnologies,
3310W Sheet
Cuyahoga FaHs Ohio44223
Inc. Analysis Request/Chain of Custody
For Summit Environmental T hnologies, Ino. use only
W:330,253.8211 Fn:330.253.4489
Page_of_. SET Nu
Company Name (Please Ainq
�j
Pmjxt Name
tp
y
a
gg
'a
h
x
''•%'
cal:Parameters
and
Methods
Company s
09S 'er A
rckstiC. GZ8
Project Address
C.herr vtIl
C
.,
F
S.y
d
bm
� f�
Y
A
t
1" I
l
Z
n7J
lE
Client Phone No.
337 7u3 2691
Report to
cuem r No. >h va. Rea l J ❑
Pou
Client Email Awe W J
v e 5 •,:qM
Quote No.
Contact Pe+son
Sol by Est k
Cheek if Oldo 4AP aamplea ✓
❑
#
. Siu@tlyq ldmtifiradon
Date
Colleckd
'l9ma
Coaected
Ctierr
P�
16 rn
St.
IQ
I
Ai
1
Gli M4v%V
Noledcommeem
I State of Semple Origin:
ReA1�zs
S �c:y f Cheek if FOR COMPLIANCE
I
<lientnivns ute PNt wRa 126458
_'-
Thee
I aeceimd :
I Date
mrT
I
�Rdfidarvuleh
z2
�00
-. Aecel.edklabSyi'�'a
15me
Rnah RequeslW ny, G '�,a" bevplor<u
h la
v ^peer
While and Yellow peg" should accompany Sampler ur dm lWwal0q. 1w
Gaya 1 of 1
Page 26 of 27

frSUMMIT Summit Environmental Technologies, Inc.
3310 w)r St.
rNVIRONIAENTAL TECHNO LOCI Es, INC; Cuyahoga Falls, Ohio 44223 Sample Log -In Check List
.4nail tieal LahoratoI TEL: [phone] FAX. [phone]
Website: hlln //ivivir setlekeom
Client Name: SYN-NC-27028 Work Order Number: 18011035 RcptNo: 1
Logged by: Christopher Livengood 1/23/2018 7:45:00 AM !•.,,.,�,/
Completed By: Christopher Livengood 1/23/20181:35:15 PM -,,-LL^ _OI
�{-
Reviewed By: Jennifer Woolf 1/26/2018 6:22:22 PM lh fil )7101
Chain of Custody
1, Is Chain of Custody complete? Yes 0 No ❑ Not Present ❑
2, How was the sample delivered? FeclEx
Loq In
3, Coolers are present? Yes No ❑ NA ❑
4. Shipping container/cooler in good condition? Yes © No ❑
Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present ❑�
No. Seal Date: Signed By:
5. Was an attempt made to cool the samples? Yes 0 No ❑ NA ❑
6, Were all samples received at a temperature of >00 C to 6.0°C Yes No ❑ NA ❑
7, Sample(s) in proper coniainer(s)? Yes © No ❑
8, Sufficient sample volume for indicated test(s)? Yes No ❑
9, Are samples (except VOA and ONG) properly preserved? Yes © No ❑
10. Was preservative added to bottles? Yes ❑ No ❑ NA W
NA
11. Is the headspace in the VOA vials less than 1/4 inch or 6mm? Yes ❑ No ❑ No VOA Vials
12. Were any sample containers received broken? Yes ❑ No V
13, Does paperwork match bottle labels? Yes No ❑
(Note discrepancies on chain of custody)
14, Are matrices correctly identified on Chain of Custody? Yes No ❑
15. Is it clear what analyses were requested? Yes © No ❑
16, Were all holding times able to be met? Yes 0 No ❑
(If no, notify customer for authorization.)
Special Handling (if applicable)
17. Was client notified of all discrepancies with this order? Yes ❑ No ❑ NA ❑�
Person Notified: Date
By Whom: Via: ❑ entail ❑ Phone ❑ Fax ❑ In Person
Regarding:
Client Instructions:
1g. Additional remarks:
Cooler Information
Cooler No
Temp °C
Condition
Seal Intact
Seal No
Seal Date
Signed B
1
3.8
Good
Not Present
Page 27 of 27

SECTION 5

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Cherryville WQ Permit Number: W00000430
WWTP Name: City of Cherryville WWTP NPDES Number: NCO044440
Monitoring Period: From Jan 1, 2018 To Dec 31, 2018
Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. 1/A (time/temp)
Alt. 4/13 (No Prior Test)
Alt. 2/B (Allc Treatment)
Alt. 5/Process to Further Reduce Pathogens
Alt. 3/C (Prior Testing)
Alt. 6 (Equivalent to PFRP)
If applicable to
alternative performed (Class A only)
indicate "Process to Further
Reduce Pathogens":
Compost
Heat Drying
Heat Treatment
Thermophilic
Beta Ray
Gamma Ray _
Pasteurization
Class B:
Alt. (1) Fecal Density X Alt (2) Process to Significantly Reduce Pathogens
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Air Drying Composting Aerobic Digestion
Anaerobic Digestion
Parameter
Allowable Level in Sludge
Pathogen Density
No. of
Frequency
Sample
Analytical
Excee-
of
Type
Technique
Minimum Geo. Mean Maximum Units
dances
Analysis
Fecal
'
MPN
2676
4607
7473
MPN/g
0
Annual
Grab
SM9221C
Coliform
E-2006
CFU/g
7solids
CFU
er gram of
MPN/g
ry weight)
Salmonella
3 MPN per 4 grams total
bacteria (in
solids (dry weight)
lieu of fecal
coliform)
Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) -Please indicate option/alternative performed:
Option/Alt L
(VS reduction)
Option/Alt. 2
(40-day bench)
Op tion I.
(30-day bench)
Option/ALt. 4
X (Spec. 02 uptake)
Option/Alt. 5
Option/Alt. 6
Option/Alt. 7
Option/Alt. 8
(14-Day Aerobic)
(Alk Stabilization)
(Drying —Stable)
(Drying —Unstable)
Option/Alt. 9
(Injection)
Option/Alt. 10
(Incorporation)
No vector attraction
reduction alternatives were performed
CERTIFICATION STATEMENT (please check the appropriate statement)
X reduction requiramenttrao40 Cthat PR 503h33%15A NCAC 02T.1107 haCFR ve been meC32/15A NCAC 02T1106 and fire veotor attraction
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 50332/15A NCAC 02T.1106 and the vector attraction
reduction requirement in 40 CFR 503.33/15A NCAC 02T. 1107 have not been met." (Please note if you check this statement attach an
explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified
personnel properly gather and evaluate the information used to determine that the ppathogen and vector attraction reduction requirements have
been met. I am aware that there are significant penalties for false certification inert ding fine and imprisonment."
and Title
Land Applier Name and Title (if applicable) (type or print)
Date Signature of Land Applier (if applicable)
Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26)

Analytical Results
Synagro
284 Boger Rd.
Mocksviile, NC 27028
Receive Date: 06/13/2018
Reported: 06/14/2018
For: Cherryville WWTP
Comments: Geometric Mean= 4607 MPN/g
Q�
O
TL11UTE�SSV+IIL�TE
A C11 ICAL
Sample Number
parameter
Sample ID
Result
Unit
Method
Analyzed
Analyst
180613.15-01
Fecal Coliforms
C-1
3963
MPN/g
sM9121cE-2005
06/13/2018
CL
180613-15-01
Percent Solids
C-1
3.26
%
SM2540B-1997
06/13/2018
CL
180613-15-02
Fecal Coliforms
C-2
6962
MPN/g
SM92210E-2006
06/13/2018
CL
180613-15-02
Percent Solids
G-2
3.16
%
SM25403AB97
06/13/2018
CL
180613-15-03
Fecal Coliforms
C-3
5140
MPN/g
SM92210E-20m
06/13/2018
CL
180613-15-03
Percent Solids
C-3
2,14
%
SM2540B-1NT
06/13/2018
CL
180613-15-04
Fecal Coliforms
C-4
7473
MPN/g
SM92210E-2006
06/13/2018
CL
180613-15-04
Percent Solids
C-4
2.81
%
SM254OB-1997
06/13/2018
CL
180613-15-05
Fecal Coliforms
C-5
4348
MPN/g
SM92210E-2006
06/13/2018
CL
180613-15-05
Percent Solids
C-5
2.99
ry
SM2540B-19W
06/13/2018
CL
180613-15-06
Fecal Coliforms
C-6
3571
MPN/g
SM92210E-20
06/13/2018
CL
180613-15-06
Percent Solids
C-6
3.64
%
SM2540&1997
06/13/2018
CL
180613-15-07
Fecal Coliforms
C-7
2676
MPN/g
SM92210E-2006
06/13/2018
CL
180613-15-07
Percent Solids
C-7
2.99
%
SM2640e-1s97
06/13/2018
CL
'Op,
submitted,
Dena Myers
NC Cart #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 •Statesville, NC 28687 • 704/872/4697
Page 1 of4

Condition of Receipt
Sample Number 180613-15-01 Temp on Arrival: 6.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Focal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180613-15-02 Temp on Arrival: 6.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180613-15-03 Temp orrArrival: 6.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule; Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180613-15-04 Temp on Arrival: 6.0
Parameter Schedule: Percent Solids
Received onlce
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180613-15-05. Temp on Arrival: 6.0
Parameter Schedule: Percent Solids
Received do Ice
PO Box 228 •Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180613-15-06 Temp on Arrival: 6.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180613-15-07 Temp on Arrival: 6.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

�
{
/
-\Ĥ_F z
%
�
!
S
(
\\ \\
3J$7a\a
c
f;
2\»\30
!,
<
`
.
\
�!!
\/
3
3 / \
/
&
p
.
�-
%
3 3
3 3
\ /
:
&/
}
f \
/
}
l�
®
^ ® !
■
,`\§
Gaa

%VSR
(older, more conservative method)
%VS in 0.5551 - Enter in
%VS out 0.4842 decimal form
%VSR= (%VS in - %VS out)
((%VS in - (%VS in x %VS out))
%VSR= 24.76
(method from p.732 of WH manual)

Analytical Results
Synagro
284 Boger Rd.
Mooksvi.11e, NC 27028
Receive Date: 04/20/2018
Reported: 0513012018
For: Cherryville WWTP
Comments:
Sample Number Parameter Sample ID Result Unit Method
Analyzed Analyst
180420-12-01 30 6ay Benchscale Cherryville 25 % [PA625-R-9210 04I19/2018 WC
WWTP
Respectfully submitted,
AP
if
Dena Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 •Statesville, NC 28687 • 704/872/4697
Page 1 of 3

Condition of Receipt
Sample Number 180420-1M I Temp on Arrival: 3.2
Parameter Schedule:
Received on Ice
Chemicals in containers, lab
PO Box 228 •Statesville, NC 28687 • 704/872/4697
Page 2 of 3

�~
-`
/ ± E
E \ ƒ
r�
.Gf
DIE:
/\#
§
/
\
-
«
>
_
©
�
\
» r
`
; &
-
)
Ge m

0

Agricultural Lime Application Log
Year: 2017
Project: Cherryville
Field
(state -county -site -field)
Soll
pH
Lime Requirement
(from soil analysis)
Tons/Acre
Applied(CCE Eq.)
Date Applied
LT-120-2
5.1
1.3T/Ac
LT-120-3
6.0
O.OT/Ac.
0.OT/Ac.
O.OT/Ac.
O.OT/Ac.
'lime will be applied when field dries up

SECTION 7

NCDA&CS Agronomic Division Phone: [phone]
Wobsite: s Ww.ncagr.gov/agronomi/
Report No.
FY18-SL037943
Predictive
Client:
Wayne Gilbert
Advisor:
EBruce
884 Cat Square Rd
Synagro
Soil Report
Mehlich-3
Extraction
Vale, NC:28168
284 Boger Rd
Mocksville, NC 27028
`s
Sampled County: Linccln
Links to Helpful Information
Sampled:
06/16/2018
arm'
Received:
06/2812018
Farm: LT-120
Completed:
07/09/2018
Client ID: 289124
Advisor ID: 475821
Sample B: 12002
Recommendations:
Lime
Nutrients(Ib/acre)
More
Crop
(tonslacre)
N P205
K2O Mg S
Mn
Zn
Cu a
Information
Lime History:
1-Soybean
1.3
0 0
50 0 0
0
0
0 0
Note: 3
2-
Test Results [units - WN in glcma; CEC and No in
maq/100 cnta; NO3-N in mgldm']:
Soil class;
Mineral
HM% W/V CEC BS% Ac pH
P-1 K-I
Ca% Mg%
S4 Mn-I Mn-AH Mn-AI2
Zn-I
Zn-AI
Cu-I No ESP
SS4 NOa-N
0.71 1.10 6.2 66 2.1 5.1
224 46
47 15
62 136 92
246
246
372 0.2 3
Sample ID: 12003
Recommendations:
Lime
Nutrients (lb/acre)
More
Crop
(tonslacre)
N P205
K20 Mg S
Mn
Zn
Cu B
Information
Lime History:
1-Soybean
0.0
0 0
20 0 0
0
0
0 0
Note: 3
2-
Results [units - WN In g/cma; CEC and No In
meq/100 crma; NOa-N In mgldma]:
Soil Class:
Mineral
% WN CEC BS% Ac pH
rH,
P-1 K4
Ca% Mg%
S4 Mn-I Mn-AI1 Mn-AI2
Zn-I
Zn-AI
Cu-I No ESP
SS -I NOa-N
66 1.06 9.8 86 1.4 6.0
179 64
63 19
47 96 66
324
324
413 0.1 1
r North Carolina
I Tobacco Trust Fund
Reprogramming of the lahoratory-information-management system that makes this report possible is
peing funded through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you For using agronomic services to manage nutrients and safeguard environmental quality.
- Sfeve Troxler, Commissioner of Agriculture

NCOAB,CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/
Report No. FY16-SLg37943
Wayne Gilbert
Page 2 of 2
Understanding the Soil Report: explanation of measurements, abbreviations and units
Recommendations
Report Abbreviations
Lime
Ac
exchangeable acidity
If testing finds that soil pH is too low for the crop(s) indicated, a time recommendation will be given in units of either
B
boron
ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting.
BS %
% CEC occupied by basic cations
For no -till or established plantings where this Is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at on
Ca%
% CEC occupied by calcium
time, even if the report recommends more. You can apply the rest in similar increments everysix months until the full rate
CEC
cation exchange capacity
is applied. If MG is recommended and lime is needed, use dolomitric lime.
Cu-I
copper index
ESP
exchangeable sodium percent
Fertilizer
HM%
percent humic matter
Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of
K-I
potassium index
lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies
KZG
potash
for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they
Mg%
% CEC occupied by magnesium
are not, fallow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) Is
MIN
mineral soil class
an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear
Mn
manganese
Mn-A
Mn-availability index for crop 1
only on reports for greenhouse soil or problem samples.
Mn-Al2
Mn-availability index for crop
Mn-I
manganeseindex
Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z
M-Omineral-organic
soil class
notations appear on the soil report, refer to $Note Secwndary Nutrients and Micronuhtenfs In general, homeowners do not
N
nitrogen
need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit
Na
sodium
nmgr.gov/agronomi/pubs.htm.
NOa-N
nitrate nitrogen
ORG
organic soil Gass
Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find
pH
current soil pH
the exact fertilizer grade recommended on the report, visit ncaaraov/aoronomi/oboart4.hM*isind information that
P-1
phosphorus index
may help you choose a comparable alternate. For more information, read AHomeowner's Guide to Fertilizer.
P2O5
phosphate
Sri
sulfur index
Test Results
SS-1
soluble salt index
WIV
weight per volume
Zn-AI
nc availability index
The first seven values [soil. class, HIM, WN, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The
Zn-I
zinc index
remaining 16 [P-1, K-1, Ca%, Mg%, Mn-1, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NOa-N (not routine)
available)] indicate levels of plant nutrients or other fertility measurement. Visit www ncaaraovv/aaronom7uvrst hfm