Loading...
HomeMy WebLinkAboutSoilStockpile_PLMResults_2017091419 0 20 21 22 23 24 25 26 27 28 29 30 31 32 33 w DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Vendor QC Data Review Summary Report Order Number: J17080661 Project Name: RIVERBEND - PLM ANALYSIS Customer Name(s): Ron Cobb; Bristol Grohol; Sean DeNeale Lab Contact: Peggy Kendall Phone: 980-875-5848 Report Authorized By: (Signature) Program Comments: Please review all vendor data for case narratives with explanations of quality control failures and data qualifiers. 9-14-17 Page 1 of 37 Any analytical tests or individual analytes within a test flagged with a qualifier indicate a deviation from the method quality system or quality control requirement. Certified vendor results and QC qualifiers can be found in the vendor lab final report. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Vendor Data Review Criteria: This vendor data package has been reviewed at the Duke Analytical Laboratory for the following applicable criteria: • Required QC samples collected and analyzed • Required tests performed for all samples • Vendor Laboratory utilized required test methods for all analyses • Vendor Laboratory met all requested Reporting Limits (RL) • QC Results reviewed for outlying recovery values Case Narrative: No QC issues found during vendor QC data review. 9-14-17 Page 2 of 37 RJ LEE GROUP DELIVERING SCIENTIFIC RESOLUTION September 12, 2017 Peggy Kendall Duke Energy Analytical Laboratory 13339 Hagers Ferry Rd. Building 7405, MG30A2 Huntersville, NC 28078 RE: Duke Energy Project — J17080661 RJ Lee Group Project Number AOH1046601-0 Dear Ms. Kendall, The RJ Lee Group, Inc. Monroeville laboratory received 106 samples on August 29, 2017 associated with Duke Energy job number J17080661. The samples were logged into RJ Lee Group project number AOH1046601-0 and assigned RJLG sample numbers as indicated in Appendix A. The samples were received in good condition with all custody seals in place and intact. Attached in Appendix A is the signed sample receipt confirmation form, COC, and sample receipt check list. These results are submitted pursuant to RJ Lee Group's current terms and conditions of sale, including the company's standard warranty and limitation of liability provisions. No responsibility or liability is assumed for the manner in which the results are used or interpreted. Unless notified to return the samples covered in this report, RJ Lee Group will store them for a period of ninety (90) days before discarding. Should you have any questions regarding this information, please do not hesitate to contact us. Sincerely, Bryan R. Bandli, PhD Principal Investigator Attachments: Chain of Custody Forms Mineral Identification Report 350 Hochberg Road, Monroeville PA,15146r I P 724.325:1776 F 724.733.1799 9-14-17 Page 3 of 37 Appendix A Chain of Custody Forms WWW.RJLG.COM 9-14-17 Page 4 of 37 J LEE GROUP Original Issue: 09/16/2005 Effective Date: May 2014 Approved By: Quality Assurance Form A FOR.002.4 Supersedes: Form FOR-002A Rev. 03 Page 1 of 4 Chain of Custody RJ Lee Group Work Order #: AOH1046601-0 Project Name/Case #: Riverbend PLM Testing Received From: Relinquished To: Peggy Kendall RJLee Group, Inc. Customer Support 350 Hochberg Road Duke Energy Central Lab Monroeville, PA 15146 United States 13339 Hagers Ferry Road Main: 724-325-1776 Fax: 724-325-1775 Hunterville, NC 28078 United States Email: peggy.kendall@duke-energy.com Main: 980-875-5848 Sample ID Client Sample ID Date Received 10414129 2017029573 08/29/2017 9:10 AM EDT 10414130 2017029574 08/29/2017 9:10 AM EDT 10414131 2017029575 08/29/2017 9:10 AM EDT 10414132 2017029576 08/29/2017 9:10 AM EDT 10414133 2017029577 08/29/2017 9:10 AM EDT 10414134 2017029578 08/29/2017 9:10 AM EDT 10414135 2017029579 08/29/2017 9:10 AM EDT 10414136 2017029580 08/29/2017 9:10 AM EDT 10414137 2017029581 08/29/2017 9:10 AM EDT 10414138 2017029582 08/29/2017 9:10 AM EDT 10414139 2017029583 08/29/2017 9:10 AM EDT 10414140 2017029584 08/29/2017 9:10 AM EDT 10414141 2017029585 08/29/2017 9:10 AM EDT 10414142 2017029586 08/29/2017 9:10 AM EDT 10414143 2017029587 08/29/2017 9:10 AM EDT 10414144 2017029588 08/29/2017 9:10 AM EDT 10414145 2017029589 08/29/2017 9:10 AM EDT 10414146 2017029590 08/29/2017 9:10 AM EDT 10414147 2017029591 08/29/2017 9:10 AM EDT 10414148 2017029592 08/29/2017 9:10 AM EDT 10414149 2017029593 08/29/2017 9:10 AM EDT 10414150 2017029594 08/29/2017 9:10 AM EDT 10414151 2017029595 08/29/2017 9:10 AM EDT 10414152 2017029596 08/29/2017 9:10 AM EDT 10414153 2017029597 08/29/2017 9:10 AM EDT 10414154 2017029598 08/29/2017 9:10 AM EDT 10414155 2017029599 08/29/2017 9:10 AM EDT 10414156 2017029600 08/29/2017 9:10 AM EDT 10414157 2017029601 08/29/2017 9:10 AM EDT Aug 29, 2017 1:46 PM EDT 350 Hochberg Road, Monroeville, PA 15146 Page 1 of 4 Phone: (724) 325-1776 1 Fax: (724) 733-1799 9-14-17 Page 5 of 37 Sample ID Client Sample ID Date Received 10414158 2017029602 08/29/2017 9:10 AM EDT 10414159 2017029603 08/29/2017 9:10 AM EDT 10414160 2017029604 08/29/2017 9:10 AM EDT 10414161 2017029605 08/29/2017 9:10 AM EDT 10414162 2017029606 08/29/2017 9:10 AM EDT 10414163 2017029607 08/29/2017 9:10 AM EDT 10414164 2017029608 08/29/2017 9:10 AM EDT 10414165 2017029609 08/29/2017 9:10 AM EDT 10414166 2017029610 08/29/2017 9:10 AM EDT 10414167 2017029611 08/29/2017 9:10 AM EDT 10414168 2017029612 08/29/2017 9:10 AM EDT 10414169 2017029613 08/29/2017 9:10 AM EDT 10414170 2017029614 08/29/2017 9:10 AM EDT 10414171 2017029615 08/29/2017 9:10 AM EDT 10414172 2017029616 08/29/2017 9:10 AM EDT 10414173 2017029617 08/29/2017 9:10 AM EDT 10414174 2017029618 08/29/2017 9:10 AM EDT 10414175 2017029619 08/29/2017 9:10 AM EDT 10414176 2017029620 08/29/2017 9:10 AM EDT 10414177 2017029621 08/29/2017 9:10 AM EDT 10414178 2017029622 08/29/2017 9:10 AM EDT 10414179 2017029623 08/29/2017 9:10 AM EDT 10414180 2017029624 08/29/2017 9:10 AM EDT 10414181 2017029625 08/29/2017 9:10 AM EDT 10414182 2017029626 08/29/2017 9:10 AM EDT 10414183 2017029627 08/29/2017 9:10 AM EDT 10414184 2017029628 08/29/2017 9:10 AM EDT 10414185 2017029629 08/29/2017 9:10 AM EDT 10414186 2017029630 08/29/2017 9:10 AM EDT 10414187 2017029631 08/29/2017 9:10 AM EDT 10414188 2017029632 08/29/2017 9:10 AM EDT 10414189 2017029633 08/29/2017 9:10 AM EDT 10414190 2017029634 08/29/2017 9:10 AM EDT 10414191 2017029635 08/29/2017 9:10 AM EDT 10414192 2017029636 08/29/2017 9:10 AM EDT 10414193 2017029637 08/29/2017 9:10 AM EDT 10414194 2017029638 08/29/2017 9:10 AM EDT 10414195 2017029639 08/29/2017 9:10 AM EDT 10414196 2017029640 08/29/2017 9:10 AM EDT 10414197 2017029641 08/29/2017 9:10 AM EDT 10414198 2017029642 08/29/2017 9:10 AM EDT 10414199 2017029643 08/29/2017 9:10 AM EDT 10414200 2017029644 08/29/2017 9:10 AM EDT 10414201 2017029645 08/29/2017 9:10 AM EDT 10414202 2017029646 08/29/2017 9:10 AM EDT 10414203 2017029647 08/29/2017 9:10 AM EDT 10414204 2017029648 08/29/2017 9:10 AM EDT 10414205 2017029649 08/29/2017 9:10 AM EDT 10414206 2017029650 08/29/2017 9:10 AM EDT Aug 29, 2017 1:46 PM EDT 350 Hochberg Road, Monroeville, PA 15146 Page 2 of 4 Phone: (724) 325-1776 1 Fax: (724) 733-1799 9-14-17 Page 6 of 37 Sample ID Client Sample ID Date Received 10414207 2017029651 08/29/2017 9:10 AM EDT 10414208 2017029652 08/29/2017 9:10 AM EDT 10414209 2017029653 08/29/2017 9:10 AM EDT 10414210 2017029654 08/29/2017 9:10 AM EDT 10414211 2017029655 08/29/2017 9:10 AM EDT 10414212 2017029656 08/29/2017 9:10 AM EDT 10414213 2017029657 08/29/2017 9:10 AM EDT 10414214 2017029658 08/29/2017 9:10 AM EDT 10414215 2017029659 08/29/2017 9:10 AM EDT 10414216 2017029660 08/29/2017 9:10 AM EDT 10414217 2017029661 08/29/2017 9:10 AM EDT 10414218 2017029662 08/29/2017 9:10 AM EDT 10414219 2017029663 08/29/2017 9:10 AM EDT 10414220 2017029664 08/29/2017 9:10 AM EDT 10414221 2017029665 08/29/2017 9:10 AM EDT 10414222 2017029666 08/29/2017 9:10 AM EDT 10414223 2017029667 08/29/2017 9:10 AM EDT 10414224 2017029668 08/29/2017 9:10 AM EDT 10414225 2017029669 08/29/2017 9:10 AM EDT 10414226 2017029670 08/29/2017 9:10 AM EDT 10414227 2017029671 08/29/2017 9:10 AM EDT 10414228 2017029672 08/29/2017 9:10 AM EDT 10414229 2017029673 08/29/2017 9:10 AM EDT 10414230 2017029674 08/29/2017 9:10 AM EDT 10414231 2017029675 08/29/2017 9:10 AM EDT 10414232 2017029676 08/29/2017 9:10 AM EDT 10414233 2017029677 08/29/2017 9:10 AM EDT 10414234 2017029678 08/29/2017 9:10 AM EDT 10414235 QC01_2017029582 08/29/2017 9:10 AM EDT 10414236 QCO2_2017029592 08/29/2017 9:10 AM EDT 10414237 QC03_2017029602 08/29/2017 9:10 AM EDT 10414238 QC04_2017029612 08/29/2017 9:10 AM EDT 10414239 QC05_2017029622 08/29/2017 9:10 AM EDT 10414240 QC06_2017029632 08/29/2017 9:10 AM EDT 10414241 QC07_2017029642 08/29/2017 9:10 AM EDT 10414242 QC08_2017029652 08/29/2017 9:10 AM EDT 10414243 QC09_2017029662 08/29/2017 9:10 AM EDT 10414244 QC10_2017029672 08/29/2017 9:10 AM EDT Aug 29, 2017 1:46 PM EDT 350 Hochberg Road, Monroeville, PA 15146 Page 3 of 4 Phone: (724) 325-1776 1 Fax: (724) 733-1799 9-14-17 Page 7 of 37 Received From: Peggy Kendall Method of Shipment: Federal Express Company: Duke Energy Central Lab Date: 08/29/2017 Received By: Monica Carse Package Condition Upon Receipt: Sealed Company: RJ Lee Group, Inc. Date: 08/29/2017 Relinquished Method of Shipment: Company: Date: Received By: Package Condition Upon Receipt: Company: Date: Relinquished Method of Shipment: Company: Date: Received By: Package Condition Upon Receipt: Company: Date: Aug 29, 2017 1:46 PM EDT 350 Hochberg Road, Monroeville, PA 15146 Page 4 of 4 Phone: (724) 325-1776 1 Fax: (724) 733-1799 9-14-17 Page 8 of 37 I RJ Lee Group Ij Sample Receipt and Log in Check List �ietlfti� Duke Energy 812912017 Tirne�Recenietl 9:10 AM B'M t � � Monica Came ��. 8l2912017 GOC . J17080661 3 L^ �3a�jl- =edExAOHi046601-0 , earl e ?ur Bail'<< H 7437 9390 2495, 7437 9390 2600, & 7437 9390 2510 As Received Screen Yes No Comments Were the Coolers received in good condition? f Was there evidence of tam edn Are Custody Seals intact and in good condition? Were Coolers received between 2 and 4 degrees C? Were all sam des intact? Were all samples accurate) labeled? Was the CDC received in good condition? Did the sam le ID on COC match the ID on the sam le cars? J Were there an discrepancies among samples and COC? Is the COC completely filled out? Was the COC relinquished ro erl . iadNio-le' r�0iw0 CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM 9-14-17 age of 4 DUKE i ENE RGYR - - - -t Analytical Laboratory Services j Mail Code MG03A2 (Building 7405) ! 13339 liagers Ferry Rd ! Wuntersville, N. C. 28078 i {980) 875-5245 r---------------.-._._._--.---•---------•-----------------_---- Analytical Laboratory Use Only Page Of DISTRIBUTION ORIGINAL to LAB, COPY t0 CLIENT I t C��, `� ! 1 Matrix: SOLID Samples NC j Originating sC j From OH i 6' G- 6' f Zq 1 1-7 ' Lf Z SAMPLE PROGRAM i Ground Water i Fazsg80) 675.4349 _ - - - - I ffJJ r NPDF5 I 0 E 0 U E E m U t )Project Name 704-263-3226 RIVERBEND PLM TESTING 3)Client 4jFax No: Ron Cobb, Bristol Grohol, Sean DeNeale 5)eusiness Unit: 6)Project to: A1zo�L�>b�t 7lAccount: 8) Operating Unit: 9)Activity ID: 10)Process ID Re) OP40 cT 'Sure e ftia- re -sr Imn9r�aL#i : When specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, or 2) Provide correct accounting for Operating Unit and Process ID. �— LA8 USE ONLY i 12Chem I 1 "Lab io _fir DesktopNo. �, i2ef7o2tll✓73' i o E 295)5!0 0 i 215 17 i o j 9 7' i EL ro c2 5-7q Q u i ZR5f 7 i7 i o N i Za5'U i Zy�7f r, i -I 13Sampie Description or ID .Vendor Other I Plant j Cooler TernC RGRA Waste I PO k Lee 5Pr serv.:1=H Po 5021798 2=ti Or 3=FI I 4-I - e 5 N d) zslJlli'f.)I}r1i11(: �t1'E:;1` a y a a � a A U. a 14Goilection Information E E o 5 Date Time Signature U a hSICY I2on ^-" - +C 704 i 35 jv Z f`f 2S a / s 1 I`Too r 2 /5 1 I lv IS 7.-/K iTot7 40"V/0y6,�,10!-CS 4 U "'Sample Descri Vendor Other I Plant t RJ Lee Cooler Tem C RCRA Waste I :PO# PO 50��� 15P serv.:1=H 2=H O4 3=H 4=1----------------- 1~t.l�ttryl�t��s Cry ecjlt)Ialr^f� <tll 14C011ection Information Date Time Signature 7- 1 11-S— 9-14-17 Page of Page 1 of DISTRIBUTION ORIGINAL to LAB. COPY to CLIENT N LU m a s C b ra) > o Q o _1 LL a N u 0 a CHAIN OF CUSTODY _RE_ CORD AND ANALYSIS REQUEST FORM - - -�r-.-._--------------._._._._.-.------._ -- ----------•--- DUKE Analytical Laboratory Services i Analytical Laboratory Use Only Samples NC_— j Mail Code MG03A2 (Building 7405) i i t } y (`,� f� ! _ r Matrix: SOLID Originating SC_ j F. 13339 Hagers Ferry Rd \J 4 14 L 11 Lt 1 From Orf__ E N E RGY�, N Huntersville, N. C. 28078 i i 0 7 SAMPLE PROGRAM i Fax98980�t375 Ground NPDESa1er. 1)Project Name 704-263.3226 RIVERSEND PLM TESTING 3)Client 4)Fax No: Ron Cobb, Bristol Grohol, Sean DeNeale 5)eusiness Unit: 6)Project ID: 7)Account: f-R$ 0 t e) operating unit: B)Activlty ID: 10)Pnece5s ID f��,<6 Gi -SI1 JL)CCPCsT- Imuortant: When specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or 2) Provide correct accounting for Operating Unit and Process ID. ly LAS USE ONLY "Chem "Lab IV ; = Desktop No. - rn E �• 1 o E cy !_ L , !C i o U I� L9.592- a ! c,i�� 1.a .� , I LrfS`��l m mac, a 1 2 jfJ10 u E 2-r15 i 9 i i�7 r i 2`IL�Ls i iorID I9 �o - tj 2 3 ts- Z9 -dG 30 E c E ar E 0 U 9-14-17 Page 11 of 37 CHAIN O_F_CUSTODY _ _RE_CORD AND ANALYSIS REQUEST FORM S A F -t r--------------------------------------•---•-•---------------'7 DUKE Analytical Laboratory Services i Analytical Laboratory Use Only Pa e Mail Code MG03A2 (Building 7405) I t i / Matrix: SOLID Samples NC_ _ I g 1 of ? , 1 , -7 c i- C L, i originating SC 13339 Hagers Ferry Rd I I _' C g I DISTRIBUTION ENERYR H Huntersville. N. C. 28078 I From Oh ORIGINAL t0 LAB, 1 SAMPLE PROGRAM (980) 675-5245i i IZ'I COPY to CLIENT rl5 71 Ground Water F NPDES I 1)Projeci Name RNERBEND PLM TESTING 704-263-3226 3)Clieni 4)Fax No: Ron Cobb, Bristol Grohol, Sean DeNeale 5)13usiness Unit: 6)Project to 7)Account: p424L)c1_Fa 1� r 6) Operating Unit: 9)Activiiy ID: 10)Procoss ID V,v, L' r S 1-1-IF Pez-FCSii Imh�: When specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or 2) Provide correct accounting for Operating Unit and Process ID. TAB USE ONLY 12Chem "Lab ID 1= Desktop No rn ZI z-elt i E I 9 I� i LI I v 'n o �a I_ L.I L I E 1�1 .Vendor Other I Plant _� I i RJ Lee Cooler Temp G RCRA Waste I :PO M 15Pr sa--" H PO 5021798 2=H Oq 3=H a -I - e 5 N T U.J � � C a � � 14Col1ection Information 13Sam le Description or ID Date Time Signature -'12moo lli� t7i►C� # 31 .211-1 1 5j;, a1ti�/.r '#-L f:-i2d :M 101mr. VIM mmv 1 T tiff O > t o U a e f° 0 W m � 21)Relinquished 8y Datefrime iE16.61 Accepted By: r t� Dete iN -7 `W r 22Requested T rna�Ound Relinquished By p r �p �7-DsterTime Accepted By: Daterrime �--o 10 flays t la f V U L 1. t g - Z - 19 91 /C Re nqui it By DateRlme Accepted By: DatetTime 5 Days Sealed/Locked By Dateffime Sealecill-ock Opened By ❑ateffime •48Hr 24)Commants /`0///oyG&C)/--a U CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM - - --i r--._-_-_.-.-.-.-.------------------------------------------- ^' +�� Analytical Laboratory Services j Analytical Laboratory Use Only i, DUKE I ! Matri�r: Samples NC_ Mail Code MG03A2 (Building 7405) I SOLID 13339 Hagers Ferry Rd I r �/ [ Frlomineting OOy_ I E N E RGY'±' Huntersville, N. C. 28078 i j n SAMPLE PROGRAM (980) 875-5245 f �).5 + ? }' E ZGj Ground Water Fax:�980) 875.4349-_ I I 1 `7 NpoEs— 1 )Project Name RIVERBEND PLM TESTING 7D4-263-3226 3)Client 4)Fax No: Ron Cobb, Bristol Grohol, Sean DeNeale 5)13usiness Unit: 6)Projecl ID: 71AccounH f' D a- oI i B) Opereling Unit: 9)Activity rD: 10)Process ID 04r.1C4C Itt tf4t't, n : When specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, Of 2) Provide correct accounting for Operating Unit and Process Id. -I LAB USE ONLY 12Chem "Lot)ID Desktop No. 77nn -7 ] rn E o 1 zgLz is Z (I Z7, ; a 'del Z L4 .a ) v I L f L., L cc., t 29 I (a! 1 771 F i Zr,�LfL �i 13Sample Description or ID E2tot=MATE kYCL * LI LP 14COIlection Information Date Time Si na ltre ,119 rpm 41 W,FEN/IN1M MEAN .. WI �M • =Man= Cooler CL n E Other_ plant RCRA Waste 9-14-17 PT 12 of 37 of �> Page 1 of I j DISTRIBUTION ORIGINAL to LAB, 1 COPY to CLIENT j I 1 i 21)RelinquishedBy /J - DotetfimeZ f q0Ct Accepted by: Dae2rn t�( iCl t 22 Requested T rnarouujnd Fiat'uished By Dalerrime Accepted By: Dalerrime 9 i r PlIltY Lot 1 �' - ! C / 10 Days r Rolinquishlosy 1 1 Daterrime Accepted By: DaterTime 5 Days Sealed/Locked By ❑aterrime SeeledrLock Opened By Daterrime • 48 Hr 24)Comments 46N10yG60/-0 L 9-14-17 P e1 f CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM -�' 6 Dl.1K� I t/�,/,TY 'ENERGY.g --- ---, Analytical Laboratory Services i Mail Code MG03A2 (Building 7405) 1 Ferry 80 I inter Hlle, N. Huntersville, N. C. 28070 I (980) 875-5245 i Fax: 980 875-4349 I — — — — — ——.�._.� — —---•---------- r--------------•-------------------------------------.-.-.---., Analytical Laboratory Use Only page 1 of DISTRIBUTION ORIGINAL to LAB, COPY to CLIENT l y /) I� + I J) 7 Ci c t �p f SOLID Matrix: SOLII] Samples NC— ! Originatin SC g GH i FramSAMPLE i p I 65 1 [n5 1 zLI11 7 l -75 PROGRAM i Ground Water i NPDES _ Vendor Other Plant _ l i RJ Lee Cooler Temn (C) RCAA Waste I 1)Projocl Name RIVERBEND PLM TESTING 704-263-3226 3)Client 4)17ax No: Ron Cobb, Bristol Grohol, Sean DeNeale 5)Business Unit: 6)Project to: 7)Account: Aac,e-L-49,60 f 8) Operaling Unit: 9)Activlly to: IO)Process ID CL'uQSc� �_ S ITrc. ,sCcPcs-T I, pg=: When specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or 2) Provide correct accounting for Operating Unit and Process ID. LAB USE ONLY I 12Chem l l "Lab ID i Desktop No. I Zei 7c2i o i 29L..4 E I U 1 q (11 j J 1 O r a l 7— ty ���,I m —7 N a o i vg2i o 21)Relinquishad By ay 13Sample Description or ID N DateFrime iPon PO5021798 "Pr sere-:1 24 O, 3= l 4.I ------- r i 11.'nsi77Ff}f.' ad�r'.�3`:. C 14Collection Information Date I Time I Signature 2 --V t i t I 1 �-3 r -45 21;-121 . 7W Accepted By: Accepted By: Accepted By DateFrime -* - _,.z 7- Daterrime Datelrime tt`tQ 22Requested T rn round 10 Days (� 5 Days 48 Hr /70///6�fr'G0 /- C) CHAIN yticab IN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM ---1 r"-------------------- --•-•-•-----.-.-.-..-.------•----------- DUKE�� Analat LoratoryServices i • Analytical Laboratory Use Only UMail Code MG03A2 (Building 7405) i 1 SOLID Samples NG- 13339 Hagers Ferry Rd I I j 1-7 0 �' C U U: 1 Matrix: Originating OH E RGY N Huntersville, N. C. 28078 1 (980) 875-5245 I I r 1 1+ / r SAMPLE PROGRAM Fax: 980 875-4349 I I s') e 1 ZU 1 i% i � Ground Water_ ----5--� ------------ -..-.a NPDES.� !Vendor - — Other I Plant a Canter Temn fC) RCRA Waste 1)Project Name 704-283-3226 RIVERBEND PLM TESTING 3)01lent 4)Fax No: Ron Cobb, Bristol Grohol, Sean DeNeaie 5)Business Unit: 6)Project ID: 7)Account: AyZOe--t-f-60 1 8) Operating Unit: (2'q00 9)Activlty 10: S I -re 10)Process In NCC-(�r-ST. Important: When specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, or 2) Provide correct accounting for Operating Unit and Process ID. LAB USE ONLY 12Chem "Lab IA_ ; Desktop No. i 26 171J 2 fc>NC i o E 2q (r��C' .I• p l 4r119 )21 O L'7 ! p i Z977L io i� 2�9U/Y.i �t'; wi Description or ID Lee tSPr serv.:1=1 PO 5021798 2=H 04 3=H `:u,fcalalcr tip �;atrll)!c s,• t,l i3j.�13i'C1IJ61�It_C"::1t'L?J �. 14Collection Information Date Time Signature 1as 1 11 So r r� ME C I mm, MMMM M. IMM�yM�■tl N MOM rA ■■ M EMM 9-14-17 Page 14 of 37 -, & CFI --� Page 1 of I i DISTRIBUTION —I ORIGINAL to LAB, i COPY to CLIENT 21)Retinquished By - Date/l'ime �q lY"GI 1 Y- Accepted By: pat igt�y / ,0 22Requested T r around Relinquished By •� DatelTime t Accepted By: Dalorriinto 8 io 10 flays : 1 Relinqui ed By Date/Time Accepted By: a efrime 5 Days Sealed/Locked By Dateffime Saaled(i.ock Opened By Dale/Time • 46 Hr 24)Comments /901-116y�,60/ —0 m CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM DUKE Analytical Laboratory Services i Analytical Laboratory Use Only r--__ Samples NC j Mail Code MG03A2 (Building 7405) I I i3 / Matrix: 50LIIa 13339 Hagers Ferry Rd l 1 L 7 �) ir) V" F Originating OH i ENERGY Hunte(980)875-5245 rsville, N.C. 26078 I I SAMPLE PROGRAM g' L� % 17 Ground Water Fax:S980) 875.4349 - I I NPNES T 1)Project Name 704-263-3226 RIVERBEND PLM TESTING 3)Cllent 41Fax No: Ron Cobb, Bristol Grohol, Sean DeNeale 5)Business Unit: 6)Project ID: 7}Account: Nice—L on?,1,f 0) Operating Unit: 9)Activity ID: 10)Process ID G"1 < S f -T-e I t..SCLIeC 511— I nrt n : When specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or 2) Provide correct accounting for Operating Unit and Process ID. LAB USE ONLY ! 12Chem I I "Lab ID Desktop No . rn _o 1 � '�E77 r77!l 6 �c:' 1 E u 20 20 6-70 I o 7-cl&7 I I Li&'-7L-- I P j 79rL�� G6)iC;� l iC7 Ui i L�Cs-77i 13Sam ion or ID 2 .vendor Other I Plant l j Cooler Temp C R1 Lee RCRA Waste I IPO # 'Spr serv.:1=H t iP0 SQz179,9 2=H 04 3=H ( 4=1 - e 5 N ,l)rlf3i�f>ri,ticltre;.i�. a m ¢ ¢ al t N a a o ii 0 a 14Collectlon Information Date I Time Signature ly .7 } +< 13, 9-14-17 Pag 15 of7 cam, Page 1 of DISTRIBUTION ORIGINAL to LAB, COPY to CLIENT 21)Relinquished By Dniefrime Z woo Accepted By: D.lpl a (7 111L' t 22 Requestedr�s3T rrlarourtd Relinquished By r Date/Time Accepted By: DataMme y i p [3 Z[� )-7 970 dy'-.9-i7 ;io 6t 10Jays 1 6 Plelingti hed By Datefrime Accept By: Date/Time 5 Days Sealed/Locked By Datef rime Sealed/Lock Opened By Datefrima •48Hr 24)Commenls 1-90H/64Cv66/- 0 CHAIN IN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM --- ---1---------------------------------------------------------- DUKE Analytical Laboratory Services i i Analytical Laboratory Use Only Samples NC i Mail Code MG03A2 (Building 7405) I I / f Metri s: SOLID II I ��-��{���-'(��tr f Origineling SC_ 13339 Hagers Ferry Rd J From OH_ I' Huntersville, N. C. 28078 SAMPLE PROGRAM ENERGY, E RGY� � {980J 875-5245 J / I I 6 S 8 1 Zy ! 17 , q'25 Ground Water Fax: 980 875-4349 I I NPOES i W e E r0 E E O U 1)Project Name RIVERBEND PLM TESTING 704-263-3226 3)Client 4)Faz No: Ron Cobb, Bristol Grohol, Sean DeNeale 5)8usiness Unit: 6))Project ID::'' 7)Account: P,,e c i..-a-� &, 8) Operating Unit: 9)Activlty ID: 16)Process IO ?- t (2-r- S I'Ck=� we (- ce-5 -r Important: When specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields alcove, or 2) Provide correct accounting for Operating Unit and Process ID. LAB USE ONLY I I 12Chem "Lab ID ; ; DesktopNo. m 2'(1[L"'7p,I o I I� E I I� 0 I I� ii I Ia a I I� I I� I IE 0 V D I �1 OE I 1� :U I 1 I I I i I I 13Sample Description or ID Zis��� tl.A Nb r �1i� ►�11� #r` � .vendor Other I Plant Cooler Temp C i R1 Lee FicnA Wasle I 'SPrLs�e2=FI..—..—..—..----.-------- iPorr POS1721798 e 5 � LOOK-4= a) , _.--w T V ul L•�1r;t�3inct' tsf t olripletf' all. - - -+ apprCJwialO aroas. Q Cr w 4 a E Q c cc 4 U. .P P 14Collection Information I Date Time Signature 9-14-17 Page 16 of 37 8 6)Fe Page 1 of DISTRIBUTION ORIGINAL to LAB, COPY to CLIENT 21)Relinqui5hed By Daterrime [ Accepted By: o t dime 22Requested Tu naround Relinquished By Datelrime 2ulikiA 1-7 .� C) Accepted By: I Daterrime a8- 1/7 51 a C 10 pays Re inqui ed Daterrime Accepted By: Dalerrime 5 Days Seared/Locked By Datelrime Sealed/Lock Opened By Daterrime •48 Hr 24)Comments 9-14-17 Page 17 of 37 Appendix B Mineral Identification Report WWW.RJLG.COM Mineral Identification Page 18 of 37 IR RJ ieeGroreF. Yac. Polarized Light Microscopy (PLM) Laboratory Report Peggy Kendall Report Date: 09/11/2017 Duke Energy Central Lab Sample Received Date: 08/29/2017 13339 Hagers Ferry Road RJLG Project: AOH1046601-0 Hunterville, NC 28078 United States Customer COC: J17080661 Email: peggy.kendall@duke-energy.com Purchase Order: J17080661 / 5021798 Main: 980-875-5848 Analytical Method: Fly Ash Determination by PLM Customer Date Date Area % Non -Fly Ash Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017029573 10414129 09/08/2017 02/13/2017 ND Clay Brown fine grain sediment Opaques Quartz 2017029574 10414130 09/08/2017 02/13/2017 ND Clay Brown fine grain sediment Mica Opaques Quartz 2017029575 10414131 09/10/2017 02/13/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz 2017029576 10414132 08/31/2017 02/13/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029577 10414133 09/08/2017 02/14/2017 ND Clay Tan fine grain sediment Mica Opaques Quartz 2017029578 10414134 09/05/2017 02/14/2017 ND Clay Brown fine grain sediment Mica Opaques Quartz AOH1046601-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 1 of 12 9-14-17 Customer Date Date Area % Non -Fly Ash Page 19 of 37 Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017029579 10414135 09/08/2017 02/14/2017 1 % Opaques Tan Fine Grain Sediment. Quartz 2017029580 10414136 08/31/2017 02/14/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029581 10414137 09/08/2017 02/14/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029582 10414138 08/31/2017 02/14/2017 ND Opaques Tan Fine Grain Sediment. Quartz 2017029583 10414139 08/31/2017 02/14/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz 2017029584 10414140 08/31/2017 02/14/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029585 10414141 08/31/2017 02/15/2017 2% Clay Tan Fine Grain Sediment. Opaques Quartz 2017029586 10414142 09/05/2017 02/15/2017 ND Clay Brown fine grain sediment Mica Opaques Quartz 2017029587 10414143 09/05/2017 02/15/2017 ND Clay Brown fine grain sediment Mica Opaques Quartz 2017029588 10414144 09/05/2017 02/15/2017 ND Clay Brown fine grain sediment Mica Opaques Quartz 2017029589 10414145 09/08/2017 02/16/2017 ND Clay Brown fine grain sediment Mica Opaques Quartz AOH1046601-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 2 of 12 9-14-17 Customer Date Date Area % Non -Fly Ash Page 20 of 37 Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017029590 10414146 09/08/2017 02/16/2017 ND Clay Red fine grain sediment Opaques Quartz 2017029591 10414147 09/10/2017 02/16/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz 2017029592 10414148 09/08/2017 02/16/2017 ND Clay Brown fine grain sediment Mica Opaques Quartz 2017029593 10414149 09/05/2017 02/16/2017 ND Clay Brown fine grain sediment Mica Opaques Quartz 2017029594 10414150 08/31/2017 02/16/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029595 10414151 08/31/2017 02/16/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029596 10414152 08/31/2017 02/16/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029597 10414153 09/08/2017 02/17/2017 ND Clay Red fine grain sediment Mica Opaques Quartz 2017029598 10414154 08/31/2017 02/17/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029599 10414155 09/08/2017 02/17/2017 ND Clay Brown fine grain sediment Mica Opaques Quartz 2017029600 10414156 08/31/2017 02/17/2017 ND Clay Tan Fine Grain Sediment. Quartz AOH1046601-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 3 of 12 9-14-17 Customer Date Date Area % Non -Fly Ash Page 21 of 37 Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017029601 10414157 08/31/2017 02/17/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029602 10414158 08/31/2017 02/17/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029603 10414159 09/05/2017 02/17/2017 ND Clay Red fine grain sediment Mica Opaques Quartz 2017029604 10414160 09/08/2017 02/17/2017 ND Clay Red fine grain sediment Opaques Quartz 2017029605 10414161 09/08/2017 02/17/2017 ND Clay Red fine grain sediment Opaques Quartz 2017029606 10414162 09/10/2017 02/17/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz 2017029607 10414163 09/08/2017 02/18/2017 ND Clay Red fine grain sediment Opaques Quartz 2017029608 10414164 09/10/2017 02/18/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029609 10414165 09/07/2017 02/18/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz 2017029610 10414166 09/08/2017 02/18/2017 1 % Clay Tan Fine Grain Sediment. Opaques Quartz 2017029611 10414167 09/07/2017 02/18/2017 ND Clay Tan Fine Grain Sediment. Quartz AOH1046601-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 4 of 12 9-14-17 Customer Date Date Area % Non -Fly Ash Page 22 of 37 Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017029612 10414168 09/07/2017 02/18/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz 2017029613 10414169 09/07/2017 02/18/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029614 10414170 09/07/2017 02/18/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029615 10414171 09/07/2017 02/18/2017 ND Quartz Tan Fine Grain Sediment. 2017029616 10414172 09/08/2017 02/19/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029617 10414173 09/08/2017 02/19/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029618 10414174 09/05/2017 02/19/2017 ND Clay Red -Brown Fine Grain Sediment Opaques Quartz Coal 2017029619 10414175 09/05/2017 02/19/2017 ND Clay Red -Brown Fine Grain Sediment Opaques Quartz Coal 2017029620 10414176 09/05/2017 02/18/2017 ND Clay Orange -Brown Fine Grain Sediment Opaques Quartz Coal 2017029621 10414177 09/07/2017 02/19/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz 2017029622 10414178 09/08/2017 02/20/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz AOH1046601-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 5 of 12 9-14-17 Customer Date Date Area % Non -Fly Ash Page 23 of 37 Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017029623 10414179 09/08/2017 02/20/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz 2017029624 10414180 09/07/2017 02/20/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz 2017029625 10414181 09/08/2017 02/20/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz 2017029626 10414182 09/07/2017 02/20/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz 2017029627 10414183 09/07/2017 02/20/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz 2017029628 10414184 09/05/2017 02/21/2017 ND Clay Light Brown Fine Grain Sediment Opaques Quartz Coal 2017029629 10414185 09/05/2017 02/21/2017 ND Clay Red -Brown Fine Grain Sediment Opaques Quartz 2017029630 10414186 09/05/2017 02/21/2017 ND Clay Red -Brown Fine Grain Sediment Opaques Quartz 2017029631 10414187 09/05/2017 02/21/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029632 10414188 09/01/2017 02/21/2017 ND Clay Red -Brown Fine Grain Sediment Opaques Quartz 2017029633 10414189 09/05/2017 02/22/2017 ND Clay Tan Fine Grain Sediment. Quartz AOH1046601-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 6 of 12 9-14-17 Customer Date Date Area % Non -Fly Ash Page 24 of 37 Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017029634 10414190 09/01/2017 02/22/2017 ND Clay Orange Fine Grain Sediment Opaques Quartz 2017029635 10414191 08/31/2017 02/22/2017 1% Clay Tan Fine Grain Sediment Opaques Quartz 2017029636 10414192 08/31/2017 02/22/2017 ND Clay Tan Fine Grain Sediment Mica Opaques Quartz 2017029637 10414193 09/01/2017 02/22/2017 ND Clay Red -Brown Fine Grain Sediment Opaques Quartz 2017029638 10414194 09/10/2017 02/23/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz 2017029639 10414195 09/05/2017 02/23/2017 ND Clay Red -Brown Fine Grain Sediment Opaques Quartz 2017029640 10414196 09/05/2017 02/27/2017 ND Clay Red -Brown Fine Grain Sediment Opaques Quartz Coal 2017029641 10414197 09/05/2017 02/27/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz 2017029642 10414198 09/05/2017 02/27/2017 ND Clay Red -Brown Fine Grain Sediment Opaques Quartz 2017029643 10414199 09/05/2017 02/27/2017 ND Clay Red -Brown Fine Grain Sediment Opaques Quartz AOH1046601-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 7 of 12 9-14-17 Customer Date Date Area % Non -Fly Ash Page 25 of 37 Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017029644 10414200 09/05/2017 02/27/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029645 10414201 09/05/2017 02/27/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz 2017029646 10414202 09/05/2017 02/28/2017 ND Clay Red -Brown Fine Grain Sediment Opaques Quartz 2017029647 10414203 09/05/2017 02/28/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029648 10414204 09/01/2017 02/28/2017 ND Clay Tan Fine Grain Sediment Mica Opaques Quartz 2017029649 10414205 09/05/2017 02/28/2017 ND Clay Red -Brown Fine Grain Sediment Opaques Quartz Coal 2017029650 10414206 09/05/2017 02/28/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz 2017029651 10414207 09/05/2017 03/01/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz 2017029652 10414208 09/05/2017 03/01/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029653 10414209 09/05/2017 03/01/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029654 10414210 09/05/2017 03/01/2017 ND Clay Red -Brown Fine Grain Sediment Opaques Quartz AOH1046601-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 8 of 12 9-14-17 Customer Date Date Area % Non -Fly Ash Page 26 of 37 Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017029655 10414211 09/05/2017 03/01/2017 ND Clay Red -Brown Fine Grain Sediment Opaques Quartz 2017029656 10414212 09/05/2017 03/01/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029657 10414213 09/05/2017 03/01/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz 2017029658 10414214 09/01/2017 03/03/2017 ND Clay Orange Fine Grain Sediment Opaques Quartz 2017029659 10414215 09/01/2017 03/03/2017 1% Clay Tan Fine Grain Sediment Mica Opaques Quartz 2017029660 10414216 09/05/2017 03/03/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029661 10414217 09/01/2017 03/03/2017 1% Clay Tan Fine Grain Sediment Mica Opaques Quartz 2017029662 10414218 08/31/2017 03/04/2017 ND Clay Tan Fine Grain Sediment Opaques Quartz 2017029663 10414219 09/01/2017 03/04/2017 ND Clay Tan Fine Grain Sediment Mica Opaques Quartz 2017029664 10414220 09/01/2017 03/04/2017 ND Clay Tan Fine Grain Sediment Mica Opaques Quartz AOH1046601-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 9 of 12 9-14-17 Customer Date Date Area % Non -Fly Ash Page 27 of 37 Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017029665 10414221 09/05/2017 03/04/2017 ND Clay Red -Brown Fine Grain Sediment Opaques Quartz 2017029666 10414222 09/01/2017 03/04/2017 ND Clay Tan Fine Grain Sediment Mica Opaques Quartz 2017029667 10414223 09/01/2017 03/05/2017 ND Opaques Red -Brown Fine Grain Sediment Organic Particulate Quartz 2017029668 10414224 09/05/2017 03/05/2017 ND Clay Light Brown Fine Grain Sediment Opaques Quartz Coal 2017029669 10414225 09/01/2017 03/05/2017 ND Clay Orange Fine Grain Sediment Opaques Quartz 2017029670 10414226 09/05/2017 03/06/2017 ND Clay Tan Fine Grain Sediment. Quartz 2017029671 10414227 09/05/2017 03/06/2017 ND Clay Red -Brown Fine Grain Sediment Opaques Quartz Coal 2017029672 10414228 09/01/2017 03/06/2017 ND Clay Red -Brown Fine Grain Sediment Opaques Quartz 2017029673 10414229 09/05/2017 03/06/2017 ND Clay Red -Brown Fine Grain Sediment Opaques Quartz Coal 2017029674 10414230 09/01/2017 03/06/2017 ND Opaques Red -Brown Fine Grain Sediment Organic Particulate Quartz AOH1046601-0 350 Hochberg Road, Monroeville, PA 15146 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 10 of 12 9-14-17 Customer Date Date Area % Non -Fly Ash Page 28 of 37 Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017029675 10414231 09/01/2017 03/10/2017 2% Clay Tan Fine Grain Sediment Mica Opaques Quartz 2017029676 10414232 09/10/2017 03/10/2017 ND Clay Tan Fine Grain Sediment. Opaques Quartz 2017029677 10414233 09/01/2017 03/10/2017 ND Clay Red -Brown Fine Grain Sediment Opaques Organic Particulate Quartz 2017029678 10414234 09/01/2017 03/10/2017 ND Clay Tan Fine Grain Sediment Mica Opaques Quartz QC01 2017029582 10414235 09/08/2017 02/14/2017 ND NA Tan Fine Grain Sediment. QCO2 2017029592 10414236 09/01/2017 02/16/2017 1% NA Tan Fine Grain Sediment QC03 2017029602 10414237 09/05/2017 02/17/2017 ND NA Brown Fine Grain Sediment QC04 2017029612 10414238 09/08/2017 02/18/2017 1 % NA Tan Fine Grain Sediment. QC05_2017029622 10414239 09/11/2017 02/20/2017 ND NA Red fine grain sediment QC06 2017029632 10414240 09/10/2017 02/21/2017 ND NA Tan Fine Grain Sediment. QC07 2017029642 10414241 09/10/2017 02/27/2017 ND NA Tan Fine Grain Sediment. QC08 2017029652 10414242 09/05/2017 03/01/2017 ND NA Brown Fine Grain Sediment QC09 2017029662 10414243 09/05/2017 03/04/2017 ND NA Brown Fine Grain Sediment. QC10 2017029672 10414244 09/08/2017 03/06/2017 ND NA Tan Fine Grain Sediment. AOH1046601-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 11 of 12 9-14-17 Page 29 of 37 Disclaimer Notes * Samples will be returned to client immediately upon the release of final report. * These results are submitted pursuant to RJ Lee Group's current terms and conditions of sale, including the company's standard warranty and limitation of liability provisions. No responsibility or liability is assumed for the manner in which these results are used or interpreted. • This test report relates to the items tested. " Any reproduction of this document must include the entire document in order for the report to be valid. * This report may not be used to claim product endorsement by NVLAP Lab Code 101208-0 or any agency of the U.S. Government. " Sample(s) for this project were analyzed at our: Monroeville, PA (AIHA # 100364, NVLAP # 101208-0, NY ELAP # 10884) facility. * If RJ Lee Group, Inc. did not collect the samples analyzed, the verifiability of the laboratory's results is limited to the reported values. * For the purposes of this method, Fly Ash is defined as any particle consistent with Coal Ash. * The method reporting level is 1 % and anything <1 % is considered a not -detected. Quartz — Angular anisotropic particulate with low relief. Feldspar — Angular to blocky anisotropic particulate, low to moderate relief, biaxial, can have polysynthetic twinning. Clay —Sheet silicates with polycrystalline or display non -uniform extinction with low to moderate relief, and zero to low birefringence. Clay also refers to particles that are less than 2.0 microns. Opaques — Opaque is a generic term for a particle that does not transmit light. Opaque minerals are distinguished from opaque bottom ash based on morphology of fracture. Fly Ash — Isotropic to opaque spheres, agglomeration of spheres, and angular ash particles. Organic Particulate — Pollen, plant and insect matter, and carbonaceous matter. Carbonates — High birefringent, can be rhombohedral, with high relief. Diatoms — Silica rich isotropic particles with various morphologies. Mica — Sheet silicate with moderate to high relief and low birefringence, mono -crystalline, and normal extinction. Miscellaneous Silicate — Isotropic and anisotropic silicates, with low to high relief, identification unsure and beyond the scope of the method to identify. Amphibole — Elongated anisotropic particulate with moderate to high relief. Coal — Irregular to angular particles with moderate opacity, edges and thin particles are reddish brown in color. <1 % Fly Ash — Fly Ash observed, none counted. ND — No Flv Ash detected. AOH1046601-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 12 of 12 9-14-17 Page 0 of 7 CHAIN OF_ CUSTODY RECORD AND ANALYSIS REQUEST FORM 0 DUKE Analytical Laboratory Services I Analytical Laboratory Use Only Mail Code MG03A2 (Building 7405) Matrix. SOLID Samples NC— Page i 1 of 13339 Hegers Ferry Rd�^] originating Sc- . I DISTRIBUTION ENERGY Hunteraville, H.C. 28078 From QH— Y 1 I SAMPLE PROGRAM ORIGINAL toLAB, COPY 10 CLIENT (980) 875-5245 c^ p�j arou+d water _ � � S O � r � 1 �z I — _ _ Fax: (980) 075-4349 _----------' NPOES _ 1)Project Name 7a4-�226 •Vendor Other _ RIVERBEND PLM TESTING PlantCooler — I 1 e E 3)Client 4)Feallo: :PO R.J Lee 1SP ;H C RCRAWade I zH Ron Cobb, Bristol Grohol, Sean DeNeale PO 5021798 2=H 0, 3■H 7 t 4-1 5 E S)BuainessUnit: e)Pro)ect10: 7)Aceoanl: _••_,._._._ ._ to E IL�G� t LOOK— w e C,rtSloR�@r tylnlytall. —'' � ) Operating UMI: Y}AcNvity lD: 10)Process It) - - m U +Q�(3 GT�St-rE NFL PGSr aPprooriate areas. Q g X. e a ¢ o Important: When specific accounting has been established and is not indicated above U we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or q o 2) Provide correct accounting for Operating Unit and Process ID. u i5 ems° LAB USE ONLY - 12Chem f 4Collection Information E 4 --] "Lab to s DesktO No. 13Sample Description or ID Data Time signature v nJ . 61 fe !ZOOOP573 i.o Q-1T tur ' 1 83 zoo >< l r z E r r '.. 2g575 o z Gzv f 2�15�►., : s sj- �{ ?it31 t boo !J sl - t)itaiinqulatted ay Datalriete �, I 14O �E Accepted eY: 20a I 'n° aO Requested Turnaround 1D Days 5 Days • 48 Hr Relinquished By Deism $ Z$ 7 U Accepted By: Datemma � BI onu mrime Accepted By: Daterrime SeahmMocked By Detamme Sssl WU=k Opened By osldrima 4)Commenis CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM -•- -� r•-•-•-•-•---------•---._._._._._._._._._._._._._._._._.� _. DUKE Analytical Laboratory Services I Analytical Laboratory Use Only I I �� O I Matrix: SOLID Bamphs NC Map Code f14G03A2 (Building 7405) originating SC- 13339 Hagers Ferry Rd From 0H ENERGY.9 Hunte196 )875. 24528078 j 8 g1 Z�f 1 r i - S SAMPLE PROGRAM Ground Wafer F.... ........_._._._._._: I NPDES t)ProjeotNams .......... _ 704-285,1426 !Y°ndm pgwr RIVER BEND PLM TESTING ! P u Ron Cobb, Bristol Grohol, Sean DeNeale � E S)Business Unit: e)Projset ID: LRS l 7)Account: I Operating Unil K3 9)Aetivily ID: GT_ s I'i 10 jPraceas ID ucc cs-r When specific accounting has been established end is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or 2) Provide correct accounting for Operating Unit and Process ID. LAB USE ONLY "labor i 1ki70N5$810 1 ZQ589 ! in E I 90iu �Z95q"l 2G5g2; 0 i 2-95931; 12Chem Deskto No. "Sam le Description or ID 1" i 1'1 f 19 20 7-1t ZqJ� 1 '7 a o. 1 2 5g51•o u I 295q4•. c) wo i i nbo ; i Z91o07_ i z .21 z 9 -bk 30 9-14-17 Page 31 of 37 2 of i Pegs 1 of I i DISTRIBUTION i ORIGINAL to LAB, i COPY to CLIENT KJ Lee cooler Tamp C RCRA Waste I is Po 5021798 15P rv.:1aH 2a 04 3sH 4al 5 tw ^ ���4ElLY5-yQ,1�1J�.�Sri�illi •— J m 7 .0 p U m ¢ a E eL ro 14Collection Information Data Time ,. signature Dom. t)RelinWahW By Datemme / y00 Accepted By: Date rime /S/ U 22Requested Turnaround 10 Days 5 Days •4a Hr By Da "* f Accepted By: Dawn"* Reli.WiShfd 8, Detaftne Accepted By: Oatdrlme SaefedfLocked By Deteffime Seakd ack Opened By Datafrlrm )Comments CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM _. _I r._._._._._._._._.W._._.W._._._._._._._._...._._._._._._._._. DUKE Analytical Laboratory Services I Analytical Laboratory Use Only ,.` . I Maud: SOLID 9-01- NC— I _ Mall Code MG03A2 (Building 7405) j 1-7 U 8 Q O (a { Orkonsting Sc- 13339 Hagare Ferry Rd ! Frew OH_ Hunteraville, N. C. 28078 ! 4 ENERGY. g (950) 875-5245 I 1 SAMPLE pROORAr,I g 12L111 ? 14"Z5 Ground Water _ RIVERBEND PLM TESTING Ron Cobb, Bristol Grohot, Sean DeNeale *r VZI4,g5gS CT_ S r—re- s Important: When specific accounting has been established and Is not Indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or 2) Provide correct accounting for Operating Unit and Process 10. ! LAB USE ONLY ! 12Chem I 1 "Lab ID it Desktopn i20170Z9(P03 i o 2cl (004! 1 to (00LOE o i 2q {pO�S i 1 ' ZG&M I2- (of Q i Zq i 1 q !3 ' 29fn1�•'. 2glnr�v; i 71511n1- i or ID Other Plant Ri LeeCooler Tema C RCRA Waste PO 502179$ 2=H O v3 HU I I I F7 9-14-17 Page 32 ofrb Papta 1 of DISTRIBUTION ORIGINAL to LAB, COPY to CLIENT LOOK... m W I~t i;ij12 t@1' 1Q G4fZ1p�@t+?s3„ -r m Mpp ropriateareas. a g w m Q o .0 U Q o a � ua m 14Callection Information E It!] "0 21)R@Nmwkdwd By DOOM me Iwo Accepted By: Ba LZ z�f 11 � iy 22 Requested Turnaround ReXquiatwd By DatelTlme Accepted By: I oatamme @ O 2 ri O 10 Days — By Betemme Accepted By: Delemme 5 Days SealedlLoekerl By Datemme Sealedtock Opened By Downroe • 48 Hr }i 24)Cammenta (c, DUKE ENERGY.. CHAIN OF CUSTODY _ _RE_C_ORD AND ANALYSIS _R_E_Q_U_E_ST_ _FORM •Ma[ytical Laboratory Services r---------------------- Analytical Laboratory Use Only ._•_•_.—.—� i l M■bt:: SOLID samples NC — Mail Code MG03A2 (Building 74051 110 n O j r„ 1 Originating Sc_ 13339 Hagers Ferry Rd 1 1 �j (p tU From OH_ Huntereville, N. C. 28078 (980) 87"245 I t C Q SAMPLE PROD M Fax:950 875-4349 L3V O 1� 1 S f l q ZS G b waterNPOES RIVERBEND PLM TESTING Ron Cobb, Bristol Grohol, Sean DeNeale e i SITS ! R! Lee L !PO s �rPI PO 5o2z7s$ 2=H t 4:i �QOK eslD �t1121' , corral,all �LST appropriate areas. portan : When specific accounting has been established and is not indicated above need the following: 1) Enter correct accounting In all 5 accounting fields above, Or Provide correct accounting for Operating Unit and Process to. I LAa USE ONLY l "LablD i .m i Zo g„Z n 17 roz9 cad t' 2°llolg� Q u a a a 0 a a m 0 a a E 0 u a a` E 0 n U 12Chem iskton No. or ID R*1 14C011ectlon Information ut Lu r rL SE 9-14-17 Page 33 of 37 _Q! df8 Page 1 of DISTRIBUTION ORIGINAL to LAB, COPY to CLIENT a It 1)Relinquished By Detarrktle c f(,�J Ampled By: Det f "Requested Turnaround By DeteJTime Accepted By: DalelTims Aad 53 10 Days y1 f Detarr ms Accepted ey: Datamme 5 Days . Sealedkoc$" By Datomme SeaiedN k opened By OalelTims • 48 Hr 24)Gommenls 9-14-17 CHAIN OF_ CUSTODY_ RECORD AND ANALYSIS REQUEST FORM Pa54,qf�7 --- —1 r----------•---•---•-------------------------------._._._.......� c.JJ o fDUKE Analytical Laboratory services i Analytical Laboratory Use Only Mail Code MGO3A2 (Building 7405) i ! aa ! ltatri=: SOLID SampNa NC t 1,89111 of ,n. 13339 Hagers Ferry Rd ! ! J 17 D a 0 �A b i o ""u"B 4— ! DISTRIBUTION ENERGY,Hameravllle, N. 28078 ! From °".R ORIGINAL to LAB, Y 1980) 875.5245 I I pr, p I �, i } +Z 5 Gnxffd Water AM i COPY to CLIENT Far 9B0 87_s-4349 {�J O v'I r ll �Z Ground water i PR L. 1 NPDES t)Pr°jecl Name ............ 704 �7 2728 _ _ _ _ Wandor QUM3r— 1 RIVERBEND PLM TESTING ! Plant— ! I RJ Lee Cooler Tam C RCRA waste 1 s)ctta°` ')F°' "°' ,Poe PO 5021798 "P .:1=H Ron Cobb, Bristol GroW, Sean DeNeale 2aH 0, 3.H 1 4W 5 S)Bual essUnit: 8)Pro)set10: 7)Aoc°unt: .._.._.._.._.._.._......»..— m fA w 1 ��9 unit: 9)AcNvky iD: 19)Proceas l0 �uslarlle�(�� �It t� �I I �' � to m (�'� �I ./ ITS 13CCPCCr nronriateareas. o > o ImMrtant: When specific accounting has been established and is not indicated above r U we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or Q o 2) Provide correct accounting for Operating Unit and Process to. a '� LL ! LAB USE ONLY ! 12CifietYl 1400IIBCtIQn IOtOrl118tlOn a � E a "Lab l0 � t Desktop No. "Sam le Description or ID Data Time Signature � � d i Z01702�(o�s i o i 2$(n?_gi 4l ar ! o LO 3 1320 I 1 � r 24636 2 06 i ZR 63R i m a 1 7qbshvs- t ZRrOyD, ErL (PS t zataw ;.q 2g�4z o o ( -73 ap I S 2%OD9001 i ZRlnu7i --Ft :5 2 1035571 21)netinquished By °°tarn"'° +rock Br• "1° �10 uested Turnaround 171 rfi..nuuy Datsrrima By A _ / , nI--1. tsRime n ., ` Accepted By e n n.L Days -- I 5 Days Opened By Datemme •48Hr_ CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM f DUKE Analytical Laboratory Services i Analytical Laboratory Use Only i t rwetrl:: SOLID gaffe NC_ Mau code INGD3ll2 (Building 7aasy l i Li 1 D 0 {�� i 13239 Hagers Ferry Rd Friginatln9 Sc ENERGY, Huntersville, N.C. 29078 Fran Q►t (980) 675-5245 1 1 SWPI E PROGRAM Fax 980 075.4349 `5 S 1 V4 i i-7 1 Z5 GroendWaler_ —----------------------• t NPDES 1)ProjWN4mo 704.263-226 •Vendor Other_ RIVERBEND PLM TESTING PIMA J� Cooler Tam C RCRA waste No: Ron Cobb, Bristol Grohol, Sean DeNeale U i)BuskNm Unit: slProject In: e p 7)Account: 1 Operating Unit, ajActiviy to, toWnx*se ID u g� 1✓T s i� �c�txsT lMp2rto . When sWi is accounting has been established and is not Indicated above we need the following: 1 j Enter correct accounting in all 5 accounting fields above, or 2) Provide correct accounting for Operating Unit and Process ID. LAB USE ONLY 12Chem "Lab ID �L Desktop No. m i2hl?172 Ia�is i 2q(PLirl c l q 1050 � o Z9 &51 i 24Co5Zi o i zgta53i� 2Q(,54� e b ' ZQLOJ�S� o tO s i q (a i o i Zi(c3 ' ZA (PIT •. i A WoZi Description or ID 'C'%tiEk �! 0 9-14-17 Page 35 of 37 % OF 8 '9e 1 of I j DISTRIBUTION ORIGINAL to LAB, i COPY to CLIENT I I i • Lee PO S021798 2-PHo. a=3�H __ 5 LOKI— ,�tolrLCr_tt�cv�rlaleie._alI � `— J m aPnroDriate areas. a n - -- a a:o t U `o T # o v W aR ii 14Collection Information Date I Time Signature CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM — — __—t r---------------------- f DUKEalytical Laboratory Services i Analytical Laboratory Use Only — Mail Co HOageem (BuildingF74t)5) i I iJ 1 7 08 0b `-) Ieeui:: SOLID Samples iati oH_ 1 Cv Originating SC_ Huntersville, H. C. 28070 SAMPLE PROGRAM ENERGY,............. Fax�980787_25.4_349 _ 13 8' 2 LI / � , `t Z� Ground water — .i._-. NPOES — I)PrejeetName 704•2634= — — — •vendor Ogler RIVERBEND PLM TESTING ! PWrd — Ron Cobb, Bristol Grohol, Sean DeNeale ie 3 E S)Business Unit: BIAProjjecttIID: o A�aL.L.12� 71Accounl: I Operatlng Unit 91Aetivky Id: SI-rE 10j?roeeea Id oe-cAoe-ST' When specific accounting has been established and is not Indicated above we need the following: 1 j Enter correct accounting in all 5 accounting fields above, or 2} Provide correct accounting for Operating Unit and Process 10. . 1 tAS USE ONLY 12Chem _ "Labli) s i20J 702Q k, Deskto No. 13Sample Description or ID -bib<LF A#' 1 Z ' 22b4l E a 49.5 V 00 Zq web! m i 2Q icing ! s ' Z4 (070 •, a � u i Zq(0� 1 i jop j za(O72 j E z '-Zq&75! 3 Date R1 Lee PO 5021798 LQ2K.. U owoo—COm-tete,alI, APPrQP iatC_arua, Information 9-14-17 Page 37 0 r Page t of DISTRIBUTION ORIGINAL to LAB, COPY to CLIENT B m c cc 0 U O a Ca r )Relinquiahed By Oatdmma 2 +�U Accepted By: Da t 7 W 22 Requested Turnaround 10 Days 5 Days .. -48 Hr Relin"Ished By Oelelmmej 8 zs a 83 0 Accepted By: I V Data/mma r Rellnqufhed By Datemme Accepted By: Datemme Sealedli-ocked By DateMme Saated =k Opened By OaIOMM —771 gCommana CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM DUKE -, .-.-.-•-•-•-.-.-.-.-•-.- -.- - - .-.-.-.-.-.- -Analytical I�boratary Services I Analytical Laboratory Use Only Mail Code MG03A2 (Building 7405) ! ! a�)/� II-- Matrix: SOLID samples NC =39 Hagers Ferry Rd I t ' J 1 70CJU(Ot,v IOriginatingENERGY.1111 Huntereville, N. C. 28078 From OH (980)875-5245 I t Ground Water sr Grourd Water Faxs980�ti75 4349_ 1 �s 8 Zy ,% q�S NPDES 1)Prooct Name RIVERBEND PLM TESTING 704.20- 28 .Vendor ! L— RI Lee Cooler rem C 'PO a .:1- PO 502I79$ 2-H' O. 3-HI i 4=) e LOOK... N t¢I1ie� 4Q �S�IL .2 OAAfaR�i�t�Cea. a rc RC Other Plard— Waste ` )Client Ron Cobb, Bristol Grohol, Sean DeNsele )Fax No, 5 6uslnsss Unit: j operatlng UnR: _ �Zt3 B)Pro)eot IQ: 1&oGLa-S 0t 7)Account:- Uj J r 9)Aetivhy ID: r C — 5 I'T� 10)Procoss IQ n» %►lt`� 1 GS'r : When specific accounting has been established and is not Indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or 2) Provide correct accounting for Operating Unit and Process ID. �+ � a • LAB USE ONLY ! "LW m t i 20170 2gto7yi 12Chem Desktop No. Y3Sam le Description or ID 14Gallection Information Hate iilne nature O �'' 2v -- JIL f+C I is 1 I� .e ii i ro ii 1 In 1 IE �a �9 o I I O1 I I 9-14-17 Page 37 of 37 8 0F8 PA$ I of DISTRIBUTION ORIGINAL to LAB. COPY to CLIENT )Rslingnlshed By Oatarnme �P� By: L �RegUEBted TUmBfOlfnd looayg s Days • 48 Hr RNinwished By Detarrlme dbg 1 "4&, A 813011 � 8 � D Accepted By: Calelrime lnw Detalrime Accepted By: oalelnma Sesled?Locked By Detamme Seeledtoek Opened By Oalelrima s)Comrnerna DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Vendor QC Data Review Summary Report Order Number: J17100183 Project Name: RIVERBEND - PLM ANALYSIS Customer Name(s): Ron Cobb; Bristol Grohol; Sean DeNeale Lab Contact: Peggy Kendall Phone: 980-875-5848 Report Authorized By: (Signature) Program Comments: Please review all vendor data for case narratives with explanations of quality control failures and data qualifiers. 10-11-17 Page 1 of 16 Any analytical tests or individual analytes within a test flagged with a qualifier indicate a deviation from the method quality system or quality control requirement. Certified vendor results and QC qualifiers can be found in the vendor lab final report. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Vendor Data Review Criteria: This vendor data package has been reviewed at the Duke Analytical Laboratory for the following applicable criteria: ' Required QC samples collected and analyzed Required tests performed for all samples Vendor Laboratory utilized required test methods for all analyses Vendor Laboratory met all requested Reporting Limits (RL) QC Results reviewed for outlying recovery values Case Narrative: No QC issues found during vendor QC data review. RJ LEE GROUP DELIVERING SCIENTIFIC RESOLUTION October 11, 2017 Peggy Kendall Duke Energy Analytical Laboratory 13339 Hagers Ferry Rd. Building 7405, MG30A2 Huntersville, NC 28078 RE: Duke Energy Project — J17100183 RJ Lee Group Project Number AOH1047111-0 Dear Ms. Kendall, 10-11-17 Page 2 of 16 The RJ Lee Group, Inc. Monroeville laboratory received 24 samples on October 6, 2017 associated with Duke Energy job number J17100183. The samples were logged into RJ Lee Group project number AOH1047111-0 and assigned RJLG sample numbers as indicated in Appendix A. The samples were received in good condition with all custody seals in place and intact. Attached in Appendix A is the signed sample receipt confirmation form, COC, and sample receipt check list. These results are submitted pursuant to RJ Lee Group's current terms and conditions of sale, including the company's standard warranty and limitation of liability provisions. No responsibility or liability is assumed for the manner in which the results are used or interpreted. Unless notified to return the samples covered in this report, RJ Lee Group will store them for a period of ninety (90) days before discarding. Should you have any questions regarding this information, please do not hesitate to contact us. Sincerely, t�y � Bryan R. Bandli, PhD Principal Investigator Attachments: Chain of Custody Forms Mineral Identification Report 350 Hochberg Road, Monroeville PA,15146 1 P 724.325.1776 F 724.733.1799 WWW.RJLG.COM 10-11-17 Page 3 of 16 Appendix A Chain of Custody Forms WWW.RJLG.COM 10-11-17 Page 4 of 16 J LEE GROUP Original Issue: 09/16/2005 Effective Date: May 2014 Approved By: Quality Assurance Form A FOR.002.4 Supersedes: Form FOR-002A Rev. 03 Page 1 of 2 Chain of Custody RJ Lee Group Work Order #: AOH1047111-0 Project Name/Case #: Riverbend PLM Testing Received From: Relinquished To: Peggy Kendall RJLee Group, Inc. Customer Support 350 Hochberg Road Duke Energy Central Lab Monroeville, PA 15146 United States 13339 Hagers Ferry Road Main: 724-325-1776 Fax: 724-325-1775 Hunterville, NC 28078 United States Email: peggy.kendall@duke-energy.com Main: 980-875-5848 Sample ID Client Sample ID Date Received 10417050 2017035111 10/06/2017 9:17 AM EDT 10417051 2017035112 10/06/2017 9:17 AM EDT 10417052 2017035113 10/06/2017 9:17 AM EDT 10417053 2017035114 10/06/2017 9:17 AM EDT 10417054 2017035115 10/06/2017 9:17 AM EDT 10417055 2017035116 10/06/2017 9:17 AM EDT 10417056 2017035117 10/06/2017 9:17 AM EDT 10417057 2017035118 10/06/2017 9:17 AM EDT 10417058 2017035119 10/06/2017 9:17 AM EDT 10417059 2017035120 10/06/2017 9:17 AM EDT 10417060 2017035121 10/06/2017 9:17 AM EDT 10417061 2017035122 10/06/2017 9:17 AM EDT 10417062 2017035123 10/06/2017 9:17 AM EDT 10417063 2017035124 10/06/2017 9:17 AM EDT 10417064 2017035125 10/06/2017 9:17 AM EDT 10417065 2017035126 10/06/2017 9:17 AM EDT 10417066 2017035127 10/06/2017 9:17 AM EDT 10417067 2017035128 10/06/2017 9:17 AM EDT 10417068 2017035129 10/06/2017 9:17 AM EDT 10417069 2017035130 10/06/2017 9:17 AM EDT 10417070 2017035131 10/06/2017 9:17 AM EDT 10417071 2017035132 10/06/2017 9:17 AM EDT 10417072 2017035133 10/06/2017 9:17 AM EDT 10417073 2017035134 10/06/2017 9:17 AM EDT 10417074 QC01_2017035120 10/06/2017 9:17 AM EDT 10417075 QCO2_2017035130 10/06/2017 9:17 AM EDT Oct 06, 2017 10:41 AM EDT 350 Hochberg Road, Monroeville, PA 15146 Page 1 of 2 Phone: (724) 325-1776 1 Fax: (724) 733-1799 10-11-17 Page 5 of 16 Received From: Peggy Kendall Method of Shipment: Federal Express Company: Duke Energy Central Lab Date: 10/06/2017 Received By: Monica Carse Package Condition Upon Receipt: Sealed Company: RJ Lee Group, Inc. Date: 10/06/2017 Relinquished Method of Shipment: Company: Date: Received By: Package Condition Upon Receipt: Company: Date: Relinquished Method of Shipment: Company: Date: Received By: Package Condition Upon Receipt: Company: Date: Oct 06, 2017 10:41 AM EDT 350 Hochberg Road, Monroeville, PA 15146 Page 2 of 2 Phone: (724) 325-1776 1 Fax: (724) 733-1799 10-11-17 Page 6 of 16 RJ Lee Group Sample Receipt and Log in Check List Ghent , rr Duke Energydate kie eived E 1016I2017 1016/2017 Time Recetvetl 9:17AM WR 5, _ Monica Carse COC :MO J17100183 Project'..' z AOH1047111-0 a a;cti, #,Cool"ers.ReceEved : 1 MUMMY'-ofwShi me t' FedEx 7437 9390 3930 As Received Screen Yes No Comments Were the Coolers received in good condition? ✓ Was there evidence of tampering? Are Custody Seals intact and in good condition? ✓ Were Coolers received between 2 and 4 degrees C? Were all sam les intact? f Were all samples accurate) labeled? ✓ Was the COC received in good condition? Did the sample ID on COC match the ID on the sample tars? ✓ Were there any discrepancies amcng samples and COC? ✓ Is the COC completely filled out? ✓ Was the COC relinquished properly? List any anomalies associated with Sam ple Receipt Analyst Signature: �� „ a / 6 - [5 L - 1,7 Manager Signature: / r 10-11-17 CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM Page 7 of 16 DUKE ENERGY } W _ --- ---t Analytical Laboratory Services i Mail Code MG03A2 (Building 7405) I 13339 Hagers Ferry Rd I Huntersville, N. C. 28078 I (900 875-5245 I Fax: 980 875-4349 I - - - - - - - - - - - - r----------- --- - nalyti al - - Laboratory Analytical Laboratory Use Only Page 1 Of DISTRIBUTION OHfGINAL to LAB, COPY to CLIENT I I �`j Matrix: SOLID Samples NC _ j Frogmnaling OH = j I �(t� I VV -- 4 I�. l � � SAMPLE PROGRAM j Ground Water NPDES � I 1)Project Name RIVERBEND PLIVI TESTING 704-263-3226 3)Client Ron Cobb, Bristol Grohoi, Sean DeNeate 4)Fax No: 5)13usiness Unit: 6)Project ID: 7)Account: 6) Operating Unit: 9)Activity ID: 10)Process ID IMA4rtnt: When specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or 2) Provide correct accounting for Operating Unit and Process ID. LAB USE ONLY 12Chem I i "Lab ID ; r Desktop No. rn i�l�n3Sl I I i a i I f L t, i9 fly R ,4 �o (20 i 121 U I�z �i 13Samole Description or ID .Ver Other I E Plant_ I j_ RI ��� Cooler Temp C RCRA Waste I iPC 'SPr serv.:1=H Po 5021798 2=H Ok 3=H 4=1 - e 5 ----------------------------- LOOK... alstorner to_coalwew oil appropriate area's 14COIlection Information e I Time I Signature N N � C T cc > � Q o U o L o ~ O W J a 21)neiinquished By /!,7/: V` 2p L `T [ Y Jr Accepted ay Da! l7��� � 22Requestod Turnaround Relinqu ed,B,y _ f� O i'" DatetTime 162 S /2 1 Z Accepted ime /�[' � S "�aJ 10 Days Relinquish y Datelrime _ Acc p! Date ime /OaateUTiGm 17 04;1 un� 5 Days SeeledLOckedB Date/Time SealedlLeck Opened By e 4B Hr 24IComments 14zi 1� �aNia� 7/1/-0 1��1�o�4h CHAIN OF CUSTODY RECORD A D ANALYSIS REQUEST FORM - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - i DUKE Analytical Laboratory Services i Analytical Laboratory Use Qnly, Mail Code MG03A2 (Building 7405) I i , „-6'g1i� Matrix: SOLID samples NC i i �l lrl"i it Originating SC i E N E RGYR rater Hlle, N. Ferry 80 I I From OH Huntersvillo, N. C. 28078 I SAMPLE PROGRAM x: (9 0) 8 5 -45 1 ()1 3 Ground Water _ Fax: {980) 875-4349 I I ! NP[]ES I L t)Project Name RIVERBEND PLM TESTING 7134-263-3226 3)Cilant Ron Cobb, Bristol Grohol, Sean DeNeale 4)Fax No: 5)Buainess Unit: 6)Project to: ])Account: 6) Operating Unit: 9)Activity ID: IO)Procese ID m rtant: When specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or 2) Provide correct accounting for Operating Unit and Process ID. LAD USE ONLY ! 12Chem "Lab ID � � Desktop No. i7�i�f�3�PZ�" i•o r 2ic I Or CL 0 u I j 2 V E u ! m q I 13� I m (32 ' o �I} o IIi s y o ! ! 13Sample Description or ID 10-11-17 Page 8 of 16 Page 1 of DISTRIBUTION ORIGINAL- to LAB, COPY to CLIENT yen �!..^� other Plant RI LL-e Cooler Temp C RCRA Waste I PO@���9g 5Pr serv.:i-H 24=1 3=H ... ..—..—..—..—..—..—..—.....e 5 w N LO{?lf,..---- ..-_ - -- A h Cost [,Iner tit colli fete 3- l — _ Lu � ` m appropriate -areas. a ¢ m a: L o U N � a a LL a o 14COIlection Information I Date Time Signature V d 21)Relinquished By Date171 a r'I Accepted !me �.{. 22Requested Turnaround Relinquished By Daterrime Accep a y: DatwTime / 10 days Relinquished By Daterrime Aceepled By: Dater a 5 Days Sealed/Locked By Date/Time Seal"Cock Opened By Daterrime • 48 H r Immmi 241Comments 10-11-17 Page 9 of 16 Appendix B Mineral Identification Report WWW.RJLG.COM Mineral Identification Page 10 of 16 IR RJ ieeGroreF. Yac. Polarized Light Microscopy (PLM) Laboratory Report Peggy Kendall Report Date: 10/11/2017 Duke Energy Central Lab Sample Received Date: 10/06/2017 13339 Hagers Ferry Road RJLG Project: AOH1047111-0 Hunterville, NC 28078 United States Customer COC: J17100183 Email: peggy.kendall@duke-energy.com Purchase Order: J17100183 / 5021798 Main: 980-875-5848 Analytical Method: Fly Ash Determination by PLM Customer Date Date Area % Non -Fly Ash Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017035111 10417050 10/10/2017 10/04/2017 ND Clay Red fine grain sediment Mica Opaques Quartz 2017035112 10417051 10/10/2017 10/04/2017 ND Clay Red fine grain sediment Mica Opaques Quartz 2017035113 10417052 10/10/2017 10/04/2017 ND Clay Red fine grain sediment Mica Opaques Quartz 2017035114 10417053 10/10/2017 10/04/2017 ND Clay Brown fine grain sediment Mica Opaques Quartz 2017035115 10417054 10/10/2017 10/04/2017 ND Clay Red fine grain sediment Mica Opaques Quartz AOH1047111-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 1 of 5 10-11-17 Customer Date Date Area % Non -Fly Ash Page 11 of 16 Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017035116 10417055 10/10/2017 10/04/2017 ND Clay Red fine grain sediment Mica Opaques Quartz 2017035117 10417056 10/10/2017 10/04/2017 ND Clay Red fine grain sediment Mica Opaques Quartz 2017035118 10417057 10/10/2017 10/04/2017 ND Clay Red Coarse Grain Sediment. Opaques Quartz 2017035119 10417058 10/10/2017 10/04/2017 ND Clay Red Coarse Grain Sediment. Opaques Quartz 2017035120 10417059 10/11/2017 10/04/2017 ND Clay Red Coarse Grain Sediment. Opaques Quartz 2017035121 10417060 10/11/2017 10/04/2017 ND Clay Red Coarse Grain Sediment. Opaques Quartz 2017035122 10417061 10/10/2017 10/04/2017 ND Clay Red Coarse Grain Sediment. Opaques Quartz 2017035123 10417062 10/10/2017 10/04/2017 ND Clay Brown Fine Grain Sediment Opaques Organic Particulate Quartz Coal 2017035124 10417063 10/11/2017 10/04/2017 ND Clay Red Coarse Grain Sediment. Opaques Quartz AOH1047111-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 2 of 5 10-11-17 Customer Date Date Area % Non -Fly Ash Page 12 of 16 Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017035125 10417064 10/10/2017 10/05/2017 1 % Clay Red- Brown Fine Grain Sediment Opaques Quartz Coal 2017035126 10417065 10/10/2017 10/05/2017 ND Clay Dark Red- Brown Fine Grain Sediment Opaques Organic Particulate Quartz Coal 2017035127 10417066 10/10/2017 10/05/2017 ND Clay Red- Brown Fine Grain Sediment Opaques Organic Particulate Quartz Coal 2017035128 10417067 10/10/2017 10/05/2017 ND Clay Red- Brown Fine Grain Sediment Opaques Organic Particulate Quartz Coal 2017035129 10417068 10/10/2017 10/05/2017 ND Clay Red fine grain sediment Mica Opaques Quartz 2017035130 10417069 10/11/2017 10/05/2017 ND Clay Red Coarse Grain Sediment. Opaques Quartz 2017035131 10417070 10/11/2017 10/05/2017 ND Clay Red Coarse Grain Sediment. Opaques Quartz AOH1047111-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 3 of 5 10-11-17 Customer Date Date Area % Non -Fly Ash Page 13 of 16 Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017035132 10417071 10/10/2017 10/05/2017 ND Clay Light Brown Fine Grain Sediment Opaques Organic Particulate Quartz Coal 2017035133 10417072 10/11/2017 10/05/2017 ND Clay Red Coarse Grain Sediment. Opaques Quartz 2017035134 10417073 10/11/2017 10/05/2017 ND Clay Red- Brown Fine Grain Sediment Opaques Organic Particulate Quartz Coal QC01 2017035120 10417074 10/11/2017 10/04/2017 ND NA Red- Brown Fine Grain Sediment QCO2 2017035130 10417075 10/11/2017 10/05/2017 ND NA Red- Brown Fine Grain Sediment AOH1047111-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 4 of 5 10-11-17 Page 14 of 16 Disclaimer Notes * Samples will be returned to client immediately upon the release of final report. * These results are submitted pursuant to RJ Lee Group's current terms and conditions of sale, including the company's standard warranty and limitation of liability provisions. No responsibility or liability is assumed for the manner in which these results are used or interpreted. * This test report relates to the items tested. * Any reproduction of this document must include the entire document in order for the report to be valid. * This report may not be used to claim product endorsement by NVLAP Lab Code 101208-0 or any agency of the U.S. Government. * Sample(s) for this project were analyzed at our: Monroeville, PA (AIHA # 100364, NVLAP # 101208-0, NY ELAP # 10884) facility. * If RJ Lee Group, Inc. did not collect the samples analyzed, the verifiability of the laboratory's results is limited to the reported values. * For the purposes of this method, Fly Ash is defined as any particle consistent with Coal Ash. * The method reporting level is 1 % and anything <1 % is considered a not -detected. Quartz — Angular anisotropic particulate with low relief. Feldspar — Angular to blocky anisotropic particulate, low to moderate relief, biaxial, can have polysynthetic twinning. Clay — Sheet silicates with polycrystalline or display non -uniform extinction with low to moderate relief, and zero to low birefringence. Clay also refers to particles that are less than 2.0 microns. Opaques — Opaque is a generic term for a particle that does not transmit light. Opaque minerals are distinguished from opaque bottom ash based on morphology of fracture. Fly Ash — Isotropic to opaque spheres, agglomeration of spheres, and angular ash particles. Organic Particulate — Pollen, plant and insect matter, and carbonaceous matter. Carbonates — High birefringent, can be rhombohedral, with high relief. Diatoms — Silica rich isotropic particles with various morphologies. Mica — Sheet silicate with moderate to high relief and low birefringence, mono -crystalline, and normal extinction. Miscellaneous Silicate — Isotropic and anisotropic silicates, with low to high relief, identification unsure and beyond the scope of the method to identify. Amphibole — Elongated anisotropic particulate with moderate to high relief. Coal — Irregular to angular particles with moderate opacity, edges and thin particles are reddish brown in color. <1 % Fly Ash — Fly Ash observed, none counted. ND — No Fly Ash detected. AOH1047111-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 5 of 5 e E c°t E `e 0 U CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM --- i r ------------------------•-•-•-•--------- DUKE Analytical Laboratory Services — I Analytical Laboratory Use Onlyejail,, — Mail Code MG03A2 {Building 7405) I T j Matrix: SOLID Samples NC ENEnt'%v 13339 Hagers Ferry Rd ; i �'� V `� S Originating _ . Huntersvllle, N. C. 26070 From OH_ Y (9B0)875-5245 I 1 Groun1A11d E Water III �ti �c Grand Water - -Fax:j9ti0)_875:4349 - - - - - i I L?l� ,7 ��� NPDES _. . )proJ.etN.ma RIVERBEND PLM TESTING ZM II )Client Ron Cobb, Bristol Grottol, Seen DeNeale 4)Fax No: : 5)Busirms Unit: S)Projecl 10: 7)Acccunl: Operating unit: g)Aetivky 10: 10)Proeass 10 apt: When specific accounting has been established and is not indicated above we need the following; 1) Enter correct accounting in ail 5 accounting fields above, Or 2) Provide correct accounting for Operating Unit and Process to. LAB USE ONLY - 12Chem 'Lab ID i Deskto No. '35am le Description or ID E t lid I 0 3 l IIS io i a r �g rx 11q i 121. 3 12� I Or- Other E PIMA RJ Lee CoolerTem C I RCRA Waste HP Po 5021798 2=TOI.L H e._.._.._.._.._.._.._.._.._ 4 5 LOOK.,. � x411tS,oft�r�o_�cl,nRlete_all. — � appropriat�•a.rcaj, a g ii > t a a. li "Collection Information CL c m Date I Time Sianature ? 2 a 10-11-17 Page 15 of 16 pegs 1 of DISTRIBUTION ORIGINAL to LAB, COPY to CLIENT 12 m C O U 0 0 t 1)RatbrquisMd By _--+ DaMlnma 1d _( f-?7 .3t7 Accepted By- 6et 22Requeated Turnaround 10 Days _. 5Days — • 48 Hr RslMqu By 0alerrima Aecaptau me �� Reg Eah Oslefnme 132p / I AC As ime SasledlLay oeked DatoMme Seeledfl ock Opened By Datemme 24)Comments tiro i OS CHAIN OF C_US_TOD_Y_ RECORD A b ANALYSIS REQUEST FORM —� r._._..-----•—•-----------------------------------._._._._.. f DUKE »Analytical Laboratory Services i Analytical Laboratory Use Only Mail Code MG03A2 (Building 7405) �, � ok(4 wlavts: SOLID NC O mon SC 13339 Hagen: Ferry Rd 4L�r— � off ENERGYHuntaraville, N. C. 29070 ! �� �� �� 13fl�- SAMPLE PROGRAM % (988) 975.5245 � � Ground Water NPDES .van Other 704-263-=t}Pro}eettwme RIVERBEND PLM TESTING ! 2� Plant oilCooler rem C RCRA waste Ron Cobb, Bristol Grohol, Sean DeNeale IO: lean : When specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or 2) Provide correct accounting for Operating Unit and Process ID. LAB USE ONLY 12Chem "LabtO i,2011{17�"t25 1 s DesktopNo. 13Sample Descri tion or ID �t r Z� 1 �� I m �ZO t 13Z 1 a c 2'2_ o I 1� By r_ ee iP° Po 5021798 2=H o. 3=H 4al 5 _.._.._..—•LOOK_ .. .. �+ w QistomedQ&�tml�l$ttJ 3-1 appropriate areas. a g M d a U. "Collection Information E o � � Date I Time Siansture V a. 10-11-17 Page 16 of 16 Page 1 of DISTRIBUTION ORIGINAL to LAB. COPY to CLIENT al N 'Requested Turnaround 10 Days 5 Days DalaMme 3SMM*'Lxk Opened By Daiernma I I -46 Hr DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Vendor QC Data Review Summary Report Order Number: J17110314 Project Name: RIVERBEND - PLM ANALYSIS Customer Name(s): Ron Cobb; Bristol Grohol; Sean DeNeale Lab Contact: Peggy Kendall Phone: 980-875-5848 Report Authorized By: pltVr-y,- � F14 Date (Signature) Peggy Kendall Program Comments: 11/21/2017 Please review all vendor data for case narratives with explanations of quality control failures and data qualifiers. 11-21-17 Page 1 of 12 Any analytical tests or individual analytes within a test flagged with a qualifier indicate a deviation from the method quality system or quality control requirement. Certified vendor results and QC qualifiers can be found in the vendor lab final report. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Vendor Data Review Criteria: This vendor data package has been reviewed at the Duke Analytical Laboratory for the following applicable criteria: ' Required QC samples collected and analyzed Required tests performed for all samples Vendor Laboratory utilized required test methods for all analyses Vendor Laboratory met all requested Reporting Limits (RL) QC Results reviewed for outlying recovery values Case Narrative: No QC issues found during vendor QC data review. 11-21-17 Page 2 of 12 RJ LEE GROUP DELIVERING SCIENTIFIC RESOLUTION November 21, 2017 Peggy Kendall Duke Energy Analytical Laboratory 13339 Hagers Ferry Rd. Building 7405, MG30A2 Huntersville, NC 28078 RE: Duke Energy Project — J 17110314 RJ Lee Group Project NumberAOH1047656-0 Dear Ms. Kendall, The RJ Lee Group, Inc. Monroeville laboratory received 17 samples on November 14, 2017 associated with Duke Energy job number J17110314. The samples were logged into RJ Lee Group project number AOH1047656-0 and assigned RJLG sample numbers as indicated in Appendix A. The samples were received in good condition with all custody seals in place and intact. Attached in Appendix A is the signed sample receipt confirmation form, COC, and sample receipt check list. These results are submitted pursuant to R1 Lee Group's current terms and conditions of sale, including the company's standard warranty and limitation of liability provisions. No responsibility or liability is assumed for the manner in which the results are used or interpreted. Unless notified to return the samples covered in this report, RJ Lee Group will store them for a period of ninety (90) days before discarding. Should you have any questions regarding this information, please do not hesitate to contact us. Sincerely, Bryan R. Bandli, PhD Principal Investigator Attachments: Chain of Custody Forms Mineral Identification Report 350 Hochberg Road, Monroeville PA, 15146 1 P 724.325.1776 F 724.733.1799 W W W.RJLG.COM 11-21-17 Page 3 of 12 Appendix A Chain of Custody Forms WWW.RJLG.COM 11-21-17 Page 4 of 12 cO J LEE GROUP Original Issue: 09/16/2005 Effective Date: May 2014 Approved By: Quality Assurance Form A FOR.002.4 Supersedes: Form FOR-002A Rev. 03 Page 1 of 2 Chain of Custody RJ Lee Group Work Order #: AOH1047656-0 Project Name/Case #: Riverbend PLM Testing Received From: Relinquished To: Peggy Kendall RJLee Group, Inc. Customer Support 350 Hochberg Road Duke Energy Central Lab Monroeville, PA 15146 United States 13339 Hagers Ferry Road Main: 724-325-1776 Fax: 724-325-1775 Hunterville, NC 28078 United States Email: peggy.kendall@duke-energy.com Main: 980-875-5848 Sample ID Client Sample ID Date Received 10419600 2017039014 11/14/2017 7:33 AM EST 10419601 2017039015 11/14/2017 7:33 AM EST 10419602 2017039016 11/14/2017 7:33 AM EST 10419603 2017039017 11/14/2017 7:33 AM EST 10419604 2017039018 11/14/2017 7:33 AM EST 10419605 2017039019 11/14/2017 7:33 AM EST 10419606 2017039020 11/14/2017 7:33 AM EST 10419607 2017039021 11/14/2017 7:33 AM EST 10419608 2017039022 11/14/2017 7:33 AM EST 10419609 2017039023 11/14/2017 7:33 AM EST 10419610 2017039024 11/14/2017 7:33 AM EST 10419611 2017039025 11/14/2017 7:33 AM EST 10419612 2017039026 11/14/2017 7:33 AM EST 10419613 2017039027 11/14/2017 7:33 AM EST 10419614 2017039028 11/14/2017 7:33 AM EST 10419615 2017039029 11/14/2017 7:33 AM EST 10419616 2017039030 11/14/2017 7:33 AM EST 10419617 QC01_2017039023 11/14/2017 7:33 AM EST 10419618 QCO2_2017039030 11/14/2017 7:33 AM EST Nov 14, 2017 11:11 AM EST 350 Hochberg Road, Monroeville, PA 15146 Page 1 of 2 Phone: (724) 325-1776 1 Fax: (724) 733-1799 11-21-17 Page 5 of 12 Received From: Peggy Kendall Method of Shipment: Federal Express Company: Duke Energy Central Lab Date: 11/14/2017 Received By: Monica Carse Package Condition Upon Receipt: Sealed Company: RJ Lee Group, Inc. Date: 11/14/2017 Relinquished Method of Shipment: Company: Date: Received By: Package Condition Upon Receipt: Company: Date: Relinquished Method of Shipment: Company: Date: Received By: Package Condition Upon Receipt: Company: Date: Nov 14, 2017 11:11 AM EST 350 Hochberg Road, Monroeville, PA 15146 Page 2 of 2 Phone: (724) 325-1776 1 Fax: (724) 733-1799 11-21-17 Page 6 of 12 Sample Receipt and Log in Check List Client F : Duke EnergyDaet2 ceiveii'" 11M412017 Lo �in�D,a�e �,� 1111412017 Came Receroed .':` 7:33 AM B ;; Monica Carse COC#,.W v�MS d171103t4 Pro ect� AOH9047656-0 # Coole r Re ei`�red ' 1 i111eans fShi me �� FedEx i4ir Bllj, 7437 9390 5347 As Received Screen Yes No Comments Were the Coolers received in good condition? / Was there evidence of tampering? Are Custody Seals intact and in good condition? Were Coolers received between 2 and 4 degrees C? Were all samples intact? Were all samples accurate) labeled? a% Was the COC received in good condition? / Did the sam !e ID on COC match the ID on the sample "ars? ✓ Were there any discrepancies amonq samples and COO? Is the COC com letel filed out? Was the COC relinquished properly? with oil Analyst Signature: Manager Signature: %a i/iay'7t, 66-G 11-21-17 Page 7 of 12 CHAIN OF CUSTODY R_E_ __ CORD AND ANALYSIS REQUEST FORM _ Analytical Laboratory Services j Analytical Laboratory Use Only DUKEMail Code MGO3A2 (Building 7405) I I Matrix: SOLID Samples NC_ j F _ 13339 Hagers Ferry Rd I I U 7 �' �7✓ l 9 SC From Originating OH_ ' ENERGY' k Huntersville, N. C. 28078 i SAMPLE PROGRAM (980) 875-5245 1 j 7 5 L r I Fax: 980 875-4349 I I r � I �3 Ground Water_ i d _m NPDFS U E a ■ 1)Project {game a 704-263-3226 SIVERBEND PLM TESTING 3)Crient 4)Fex No: Ron Cobb, Bristol Grohol, Sean DeNeale 6)Business unit: 6)Project IIDD:: 7)Account ' 8) Operating Unit: 9)Activity ID: 10)Process ID TL Mm 9. 0—r W hen specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or 2) Provide correct accounting for Operating Unit and Process 113. LAB USE ONLY "Chem I j Lab to i Z Desktop No. n — ' 32901 S j ' E a 5 q � 2f im ',I„LryL4_tSJ 2 Ct�� ' w a �a u j 9W `q f; t; qC2 i 9607 j i Cl6"1 i 13Sample Description or ID 7- 'vend Other_ Plant _ I j1 %00 Cooler TernC RCRA Waste I :PO a Pa 50:21;,98 SPr Ra5e = 2=H= 4=1 5 N it 7 J 14COIlection Information Date I Time I Signature MIMM M© MM ®m ME �(G tl4b 5 ( ( IiOD'� g t o 11 `1 113c, 1Lqf4S S 13 Ilia i(o 0 S 1(4 o h t> I o,6' S I +kru N144 1i E R � m Page 1 of DISTRIBUTION ORIGINAL to LAB, COPY to CLIENT By ( Datertime 1/�f'1�gd Accepted By: Daterri 14�) 22Requested Turnaround By ❑atolrimelac B DatelTimei/D 10 ❑aysed 42flRelinquished (� Hy tlTi E'[DateMrne Ac opted By:zCeL,� 5Days i/ /y- 7 1,33 eked By _ SealedlLock Opened By Daterrime • 48 Hr 24)Camments 'tller'_.•_� Add Cost Will Apply Aor/�ay7rc�iF._ p 11-21-17 Page 8 of 12 f C CHAIN___ OF CUSTODY RECORD AND ANALYSIS REQUEST FORM DUKE - -, r — _ —cal — — atory — Analytical Laboratory Services j Analytical Laboratory Use Only Samples NC_ i page of I I Matrix: Mail Code MG03A2 (Building 7405) SOLID Originating SC_ 13339 Hagers Ferry Rd I I r i s �� rf y g 9 i DISTRIBUTION ENERGY, N Huntersville, N. C. 28078 I F From OHORIGINAL to LAB, 980 875-5245 I SAMPLE PROGRAM() rj117Ground Water GOPY to GLIENT Faz:S980) 875 4349 _ I NPDES !)Project Name 704-263-3226 RIVERBEND PLM TESTING 3)Client 4)Fax No: Ron Cobb, Bristol Grohol, Sean DeNeale 5)Business Llnit: 6)Project ID: 7)Account: Ai,v(, 0 Operating Unit: 9)Activity ID: 10)Proceas ID R8� ,✓� 5i7 NCG �5r fln : When specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or 2) Provide correct accounting for Operating Unit and Process ID. ! LAB USF ONLY 12Chem � I "Lab ID ; _ Desktop No. I �-O+%Lrs�lCl}}I o 6 v �o ;CL C �-------- V 4 I � W E I 1 � :U I I 1 I I I I I Description or ID 0- S IC NV, CLR` !Vendor Other Plant _� I j RJ Lee Cooler Tam C RCRA Waste _ I :Po rt Po 5021798 5pr sere.-1=H 2=H Oa 3-H 4=1 e 5 LOO .. (;u�,torner to_complotg.s',Il a PPropri,ate.,.treas;, 14COIlection Information Date Time Signature t Ire Nr: t 3A N U, llt N N L7 _ C ro r Q a 7 u, 0 o T U C1 o N U C m IL 21)Relinquished By !! �o I Daterrime (�I[-I"t (f Ancepled ay: Dalafrime Lr .fi�1 22 Requested Turnaround Relinqulsf4 d y �t Datefrimo c tad By: - D telTim�a 10 Days 11 120f 1 ) /17 el h d B ❑atefrlme A epted By: Datefrime r I 3 17 1-355 5 Days 5 dfLocked Hy Daterrime SealecilLack Opened By Datafrime • 48 Hr 24)Comments 11-21-17 Page 9 of 12 Appendix B Mineral Identification Report WWW.RJLG.COM 11-21-17 Mineral Identification Page 10of12 Rk--3 RJ LeeGroup, Inc. Polarized Light Microscopy (PLM) Laboratory Report Peggy Kendall Report Date: 11/16/2017 Duke Energy Central Lab Sample Received Date: 11/14/2017 13339 Hagers Ferry Road RJLG Project: AOH1047656-0 Hunterville, NC 28078 United States Customer COC: J17110314 Email: peggy.kendall@duke-energy.com Purchase Order: J17110314 / 5021798 Main: 980-875-5848 Analytical Method: Fly Ash Determination by PLM Customer Date Date Area % Non -Fly Ash Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017039014 10419600 11/16/2017 11/02/2017 ND Quartz Red Fine Grain Sediment. 2017039015 10419601 11/16/2017 11/02/2017 2% Clay Orange Fine Grain Sediment. Opaques Quartz 2017039016 10419602 11/16/2017 11/03/2017 ND Clay Red Fine Grain Sediment. Opaques Quartz 2017039017 10419603 11/16/2017 11/03/2017 ND Clay Red Fine Grain Sediment. Opaques Quartz 2017039018 10419604 11/16/2017 11/03/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017039019 10419605 11/16/2017 11/03/2017 ND Clay Red Fine Grain Sediment. Opaques Quartz 2017039020 10419606 11/16/2017 11/03/2017 ND Clay Red Fine Grain Sediment. Opaques Quartz AOH1047656-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 1 of 3 11-21-17 Customer Date Date Area % Non -Fly Ash Page 11 of 12 Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017039021 10419607 11/16/2017 11/06/2017 1% Opaques Orange Fine Grain Sediment Quartz 2017039022 10419608 11/16/2017 11/06/2017 1% Opaques Orange Fine Grain Sediment Quartz 2017039023 10419609 11/16/2017 11/07/2017 2% Opaques Orange Fine Grain Sediment Quartz 2017039024 10419610 11/16/2017 11/08/2017 ND Opaques Tan Fine Grain Sediment Quartz 2017039025 10419611 11/16/2017 11/08/2017 1% Opaques Orange Fine Grain Sediment Quartz 2017039026 10419612 11/16/2017 11/09/2017 1% Opaques Tan Fine Grain Sediment Quartz 2017039027 10419613 11/16/2017 11/10/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017039028 10419614 11/16/2017 11/10/2017 1% Clay Orange Fine Grain Sediment. Opaques Quartz 2017039029 10419615 11/16/2017 11/10/2017 ND Quartz Red Fine Grain Sediment. 2017039030 10419616 11/16/2017 11/07/2017 15% Opaques Gray Coarse Grain Sediment. Quartz Coal QC01 2017039023 10419617 11/16/2017 11/07/2017 2% NA Tan Fine Grain Sediment QCO2 2017039030 10419618 11/16/2017 11/07/2017 14% NA Brown Fine Grain Sediment AOH1047656-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 2 of 3 11-21-17 Page 12 of 12 Disclaimer Notes • Samples will be returned to client immediately upon the release of final report. * These results are submitted pursuant to RJ Lee Group's current terms and conditions of sale, including the company's standard warranty and limitation of liability provisions. No responsibility or liability is assumed for the manner in which these results are used or interpreted. * This test report relates to the items tested. * Any reproduction of this document must include the entire document in order for the report to be valid. • This report may not be used to claim product endorsement by NVLAP Lab Code 101208-0 or any agency of the U.S. Government. • Sample(s) for this project were analyzed at our: Monroeville, PA (AIHA # 100364, NVLAP # 101208-0, NY ELAP # 10884) facility. • If RJ Lee Group, Inc. did not collect the samples analyzed, the verifiability of the laboratory's results is limited to the reported values. • For the purposes of this method, Fly Ash is defined as any particle consistent with Coal Ash. . The method reporting level is 1 % and anything <1 % is considered a not -detected. Quartz — Angular anisotropic particulate with low relief. Feldspar — Angular to blocky anisotropic particulate, low to moderate relief, biaxial, can have polysynthetic twinning. Clay — Sheet silicates with polycrystalline or display non -uniform extinction with low to moderate relief, and zero to low birefringence. Clay also refers to particles that are less than 2.0 microns. Opaques — Opaque is a generic term for a particle that does not transmit light. Opaque minerals are distinguished from opaque bottom ash based on morphology of fracture. Fly Ash — Isotropic to opaque spheres, agglomeration of spheres, and angular ash particles. Organic Particulate — Pollen, plant and insect matter, and carbonaceous matter. Carbonates — High birefringent, can be rhombohedral, with high relief. Diatoms — Silica rich isotropic particles with various morphologies. Mica — Sheet silicate with moderate to high relief and low birefringence, mono -crystalline, and normal extinction. Miscellaneous Silicate — Isotropic and anisotropic silicates, with low to high relief, identification unsure and beyond the scope of the method to identify. Amphibole — Elongated anisotropic particulate with moderate to high relief. Coal — Irregular to angular particles with moderate opacity, edges and thin particles are reddish brown in color. <1 % Fly Ash — Fly Ash observed, none counted. ND — No Fly Ash detected. AOH1047656-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 3 of 3 DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Vendor QC Data Review Summary Report Order Number: J17110610 Project Name: RIVERBEND - PLM ANALYSIS Customer Name(s): Ron Cobb; Bristol Grohol; Sean DeNeale Lab Contact: Peggy Kendall Phone: 980-875-5848 Report Authorized By: (Signature) P1tVV,,,-- dot, a to Program Comments: Please review all vendor data for case narratives with explanations of quality control failures and data qualifiers. 12-8-17 Page 1 of 15 Any analytical tests or individual analytes within a test flagged with a qualifier indicate a deviation from the method quality system or quality control requirement. Certified vendor results and QC qualifiers can be found in the vendor lab final report. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Vendor Data Review Criteria: This vendor data package has been reviewed at the Duke Analytical Laboratory for the following applicable criteria: ' Required QC samples collected and analyzed Required tests performed for all samples Vendor Laboratory utilized required test methods for all analyses Vendor Laboratory met all requested Reporting Limits (RL) QC Results reviewed for outlying recovery values Case Narrative: No QC issues found during vendor QC data review. 12-8-17 Page 2 of 15 RJ LEE GROUP DELIVERING SCIENTIFIC RESOLUTION December 8, 2017 Peggy Kendall Duke Energy Analytical Laboratory 13339 Hagers Ferry Rd. Building 740S, MG30A2 Huntersville, NC 28078 RE: Duke Energy Project—J17110610 RJ Lee Group Project Number AOH1047804-0 Dear Ms. Kendall, The RJ Lee Group, Inc. Monroeville laboratory received 24 samples on December 1, 2017 associated with Duke Energy job number J17110610. The samples were logged into RJ Lee Group project number AOH1047804-0 and assigned RJLG sample numbers as indicated in Appendix A. The samples were received in good condition with all custody seals in place and intact. Attached in Appendix A is the signed sample receipt confirmation form, COC, and sample receipt check list. These results are submitted pursuant to RJ Lee Group's current terms and conditions of sale, including the company's standard warranty and limitation of liability provisions. No responsibility or liability is assumed for the manner in which the results are used or interpreted. Unless notified to return the samples covered in this report, RJ Lee Group will store them for a period of ninety (90) days before discarding. Should you have any questions regarding this information, please do not hesitate to contact us. Sincerely, lam% / ✓li1 Bryan R. Bandli, PhD Principal Investigator Attachments: Chain of Custody Forms Mineral Identification Report 350 Hochberg Road, Monroeville PA, 15146 1 "724.325.1776 F 724.733.1799 WW W.RJLG.COM 12-8-17 Page 3 of 15 Appendix A Chain of Custody Forms WWW.RJLG.COM 12-8-17 Page 4 of 15 cO J LEE GROUP Original Issue: 09/16/2005 Effective Date: May 2014 Approved By: Quality Assurance Form A FOR.002.4 Supersedes: Form FOR-002A Rev. 03 Page 1 of 2 Chain of Custody RJ Lee Group Work Order #: AOH1047804-0 Project Name/Case #: Riverbend PLM Testing Received From: Relinquished To: Peggy Kendall RJLee Group, Inc. Customer Support 350 Hochberg Road Duke Energy Central Lab Monroeville, PA 15146 United States 13339 Hagers Ferry Road Main: 724-325-1776 Fax: 724-325-1775 Hunterville, NC 28078 United States Email: peggy.kendall@duke-energy.com Main: 980-875-5848 Sample ID Client Sample ID Date Received 10420526 2017040138 12/01/2017 9:05 AM EST 10420527 2017040139 12/01/2017 9:05 AM EST 10420528 2017040140 12/01/2017 9:05 AM EST 10420529 2017040141 12/01/2017 9:05 AM EST 10420530 2017040142 12/01/2017 9:05 AM EST 10420531 2017040143 12/01/2017 9:05 AM EST 10420532 2017040144 12/01/2017 9:05 AM EST 10420533 2017040145 12/01/2017 9:05 AM EST 10420534 2017040146 12/01/2017 9:05 AM EST 10420535 2017040147 12/01/2017 9:05 AM EST 10420536 2017040148 12/01/2017 9:05 AM EST 10420537 2017040149 12/01/2017 9:05 AM EST 10420538 2017040150 12/01/2017 9:05 AM EST 10420539 2017040151 12/01/2017 9:05 AM EST 10420540 2017040152 12/01/2017 9:05 AM EST 10420541 2017040153 12/01/2017 9:05 AM EST 10420542 2017040154 12/01/2017 9:05 AM EST 10420543 2017040155 12/01/2017 9:05 AM EST 10420544 2017040156 12/01/2017 9:05 AM EST 10420545 2017040157 12/01/2017 9:05 AM EST 10420546 2017040158 12/01/2017 9:05 AM EST 10420547 2017040159 12/01/2017 9:05 AM EST 10420548 2017040160 12/01/2017 9:05 AM EST 10420549 2017040161 12/01/2017 9:05 AM EST 10420550 QC01_2017040147 12/01/2017 9:05 AM EST 10420551 QCO2_2017040157 12/01/2017 9:05 AM EST Dec 01, 2017 9:57 AM EST 350 Hochberg Road, Monroeville, PA 15146 Page 1 of 2 Phone: (724) 325-1776 1 Fax: (724) 733-1799 12-8-17 Page 5 of 15 Received From: Peggy Kendall Method of Shipment: Federal Express Company: Duke Energy Central Lab Date: 12/01/2017 Received By: Monica Carse Package Condition Upon Receipt: Sealed Company: RJ Lee Group, Inc. Date: 12/01/2017 Relinquished Method of Shipment: Company: Date: Received By: Package Condition Upon Receipt: Company: Date: Relinquished Method of Shipment: Company: Date: Received By: Package Condition Upon Receipt: Company: Date: Dec 01, 2017 9:57 AM EST 350 Hochberg Road, Monroeville, PA 15146 Page 2 of 2 Phone: (724) 325-1776 1 Fax: (724) 733-1799 12-8-17 Page 6 of 15 RJ Lee Group Sample Receipt and Log in Check List Cta�ehC r� afr. Duke Energy Date, -dery 12N12017 L. _ 121112017 9:05 AM Monica Carle C06ZINISM J17110610 AOH1047804-0 #Coolers Eiecelved.m i Mean `s ofzShl meat~. FedE. fir Sili „4� : 7437 9390 5932 As Received Screen Yes No Comments Were the Coolers received in good condition? Was there evidence of tampering? ✓ Are Custody Seals intact and in good condition? ✓ Were Coolers received between 2 and 4 degrees C? Were all samples intact? ✓ Were all samples accurately labeled? ✓ Was the COC received in good condition? ✓ Did the sample 1D on COC match the ID on the sample "ars? ✓ Were there any discrepancies among samples and COC? ✓ Is the COC completely filled out? ✓ Was the COC relinquished properly? List any anomalies associated with Sample Receipt Analyst Signature: Manager Signature: r 190///01' 7 RQy-0 12-8-17 Page 7 of 15 CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM �� ���� Analytical Labaratory Services i � Analytlt:al LaboratoryElse Only �� sam les NC_ Pegg 1 of 2- NEetl Code MG03A2 (Building 7405) i i // Ma+rIY: SOLID � I 13339 Hagers Ferry Rd I I t originating SC_ �� � � i DISTRIBUTION ���.+�� Huntersville, N. C. 2887E i From off ORIGINAL to LAB, I L. SAMPLE PROGRAM [?' N (988) 875-5245 1 // p .,� „�I t COPY to CLIENT /f Q Ground Waler�, Fax:---- ---- --- I t (� 17 I NPDES d E a E u E 0 U 1)Project Name RIVERBEND PLM TESTING a 704-263-3226 3)Cllont 4)Far No: Ron Cobb, Bristol Grohol, Sean DeNeale 5)Businese Unit: e)Project Id: 7)Account: A-goGt-(Zg 0 11 6) Operating Unit: 9}Activity la; 10)Process Io Od CT S/ rL= NcGPGST When specific accounting has boon established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, or' 2) Provide correct accounting for operating Unit and Process ID. LAB USE ONLY 12Chem Lab to �� Desktop No. Sp I to U I- d1 -1 ju I C o aJ�S' 0 - i-�il'—�- i o t, i ljJS'% i 1 13Sample Description or ID 0 e 5'Z( �S~ ZZ S - 2C, 5-3 Venda Other_ I Plant _ I i RI lee Cooler Temp C RCRA Waste I :PO # Poua 5�pHrLe'rv.,1==1H1CHPo 502179$24=1r` 2Ue 5 W C'-tt'ato141.�rtc�„cr3Rr[�f[;tr�_-�fl '' a LLJ ' � C t ztppr'uPri tte:�rs:a�;, a tr m 14Collection Information Date I Time Siqnature 0 x v Q o A � U. 21 yRellnquished By C I t LO C + Detefrlme { 17 pr ! k AcceDaterTime // 22 Requested Turnarou d Rplinqu' d By Oale ima -r. � /7 D telTlme - (J Lo� J �1 10 Days / t Relinquish y, efT P❑alelTima Y} Id-01- C+9. C 5 Days Seale ocked By DateFrime enled/Lock Opened By GatelTlme • 48 Hr 24)Commems igG,Il10y%l�,()`f-0 12-8-17 Page 8 of 15 CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM DUKE k/^�-•lVi` L. N ENER*r/ 1 . -- -._) Analytical Laboratory Services i Mail Code MG03A2 (Building 7405) i3339HaltersFerry Rd I Huntersviiie, N. C. 2RO78 j {980) 875-5245 f raw:_(980)875.4349 I r--------._._._.-.------------------� Analytical Laboratory Use Only Pegs !g„Of DISTRIBiITiON to LAB, -COPY COPY to CLIENT I '�-r IV i//r ��� Matrix: SOLID Samples NC_ j Originating SC_ j From OH_ I �� I /l / / ` ] 6Zf� SAMPLE PROGRAM Ground Water _ I NPDES I 1)Pruject Name RIVERBEND PLM TESTING � 6 3)Ctiont Ran Cobb, Bristol Grohol, Sean DeNeale E4)FaxNo: 5)Business Unit: 61Project ID: 7)Account: 81 Operating Unit! 9)Activity ID: 10}Process Ill I pgrtB.A: When specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, or 2) Provide correct accounting for Operating Unit and Process ID. LAB USE ONLY 12Chen7 Lab 11) Desktop No. i�� Ili i o In I � a u w a1� .a Pi CL 0 v I Q o I 15 !� 3 1 1 13Sarnole Description or ID .Vendor Olher I Plant I RJ Lee Cooler TempC RCRA Waste i iPo on PO 5021798 2a Hr s0e,v.31 H t7 4-1 e 5 - •- al T i ti:.0 tcrnlcr to +:rIrtPlr,.t.,�r11 — - m ul ,1'.)t't3l)1'it31.E.Clt'r'it`;. Q � a rC a c 0 r � N � 4 � A U. 16 14Collection Information EL o Date Time Si nature a 25nelinquishad By (r7 (�O r y n Date/Tim � r f 7 O - Q JA5A�� Accepted Daterrj 12 RequestedTurnaround Ralin uished6 9 y ,,�f� Datefrime ��!r ^- /7� W11 Accepfed Oat Im .y �/ W7 -'vc. 10 Days � 17 Relinquished By DatelTime Accepted By: atcs7lme �. ee 5 Days • 4l3 Hr Sealed/Locked By Dater line Sealadkock Opened By / Daterrime 24)Comments 12-8-17 Page 9 of 15 Appendix B Mineral Identification Report WWW.RJLG.COM Identification Page 10 of 15 R�Mineral RJ LeeGroup, Inc. Polarized Light Microscopy (PLM) Laboratory Report Peggy Kendall Report Date: 12/07/2017 Duke Energy Central Lab Sample Received Date: 12/01/2017 13339 Hagers Ferry Road RJLG Project: AOH1047804-0 Hunterville, NC 28078 United States Customer COC: J17110610 Email: peggy.kendall@duke-energy.com Purchase Order: J17110610 / 5021798 Main: 980-875-5848 Analytical Method: Fly Ash Determination by PLM Customer Date Date Area % Non -Fly Ash Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017040138 10420526 12/05/2017 11/14/2017 ND Clay Red Fine Grain Sediment. Opaques Quartz 2017040139 10420527 12/05/2017 11/14/2017 ND Clay Orange Fine Grain Sediment. Opaques Quartz 2017040140 10420528 12/05/2017 11/14/2017 ND Clay Orange Coarse Grain Sediment. Quartz 2017040141 10420529 12/05/2017 11/15/2017 ND (quartz Orange Coarse Grain Sediment. 2017040142 10420530 12/05/2017 11/15/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017040143 10420531 12/05/2017 11/15/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017040144 10420532 12/05/2017 11/16/2017 ND Quartz Orange Coarse Grain Sediment. 2017040145 10420533 12/05/2017 11/16/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz AOH1047804-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 1 of 4 12-8-17 Customer Date Date Area % Non -Fly Ash Page 11 of 15 Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017040146 10420534 12/05/2017 11/16/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017040147 10420535 12/05/2017 11/17/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017040148 10420536 12/05/2017 11/17/2017 ND Quartz Orange Coarse Grain Sediment. 2017040149 10420537 12/05/2017 11/17/2017 ND Quartz Orange Coarse Grain Sediment. 2017040150 10420538 12/05/2017 11/17/2017 ND Quartz Orange Coarse Grain Sediment. 2017040151 10420539 12/05/2017 11/20/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017040152 10420540 12/05/2017 11/20/2017 ND Quartz Orange Coarse Grain Sediment. 2017040153 10420541 12/05/2017 11/20/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017040154 10420542 12/05/2017 11/20/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017040155 10420543 12/05/2017 11/21/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017040156 10420544 12/05/2017 11/21/2017 ND Opaques Orange Coarse Grain Sediment. Quartz 2017040157 10420545 12/05/2017 11/22/2017 ND Clay Tan Coarse Grain Sediment. Quartz 2017040158 10420546 12/05/2017 11/22/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz AOH1047804-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 2 of 4 12-8-17 Customer Date Date Area % Non -Fly Ash Page 12 of 15 Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017040159 10420547 12/05/2017 11/27/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017040160 10420548 12/05/2017 11/27/2017 1% Quartz Tan Coarse Grain Sediment. 2017040161 10420549 12/05/2017 11/27/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz QC01_2017040147 10420550 12/06/2017 11/17/2017 1% NA Orange Coarse Grain Sediment. QCO2 2017040157 10420551 12/06/2017 11/22/2017 ND NA Tan Coarse Grain Sediment. AOH1047804-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 3 of 4 12-8-17 Page 13 of 15 Disclaimer Notes • Samples will be returned to client immediately upon the release of final report. * These results are submitted pursuant to RJ Lee Group's current terms and conditions of sale, including the company's standard warranty and limitation of liability provisions. No responsibility or liability is assumed for the manner in which these results are used or interpreted. * This test report relates to the items tested. * Any reproduction of this document must include the entire document in order for the report to be valid. • This report may not be used to claim product endorsement by NVLAP Lab Code 101208-0 or any agency of the U.S. Government. • Sample(s) for this project were analyzed at our: Monroeville, PA (AIHA # 100364, NVLAP # 101208-0, NY ELAP # 10884) facility. • If RJ Lee Group, Inc. did not collect the samples analyzed, the verifiability of the laboratory's results is limited to the reported values. • For the purposes of this method, Fly Ash is defined as any particle consistent with Coal Ash. . The method reporting level is 1 % and anything <1 % is considered a not -detected. Quartz — Angular anisotropic particulate with low relief. Feldspar — Angular to blocky anisotropic particulate, low to moderate relief, biaxial, can have polysynthetic twinning. Clay — Sheet silicates with polycrystalline or display non -uniform extinction with low to moderate relief, and zero to low birefringence. Clay also refers to particles that are less than 2.0 microns. Opaques — Opaque is a generic term for a particle that does not transmit light. Opaque minerals are distinguished from opaque bottom ash based on morphology of fracture. Fly Ash — Isotropic to opaque spheres, agglomeration of spheres, and angular ash particles. Organic Particulate — Pollen, plant and insect matter, and carbonaceous matter. Carbonates — High birefringent, can be rhombohedral, with high relief. Diatoms — Silica rich isotropic particles with various morphologies. Mica — Sheet silicate with moderate to high relief and low birefringence, mono -crystalline, and normal extinction. Miscellaneous Silicate — Isotropic and anisotropic silicates, with low to high relief, identification unsure and beyond the scope of the method to identify. Amphibole — Elongated anisotropic particulate with moderate to high relief. Coal — Irregular to angular particles with moderate opacity, edges and thin particles are reddish brown in color. <1 % Fly Ash — Fly Ash observed, none counted. ND — No Fly Ash detected. AOH1047804-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 4 of 4 a u E E c C CHAIN O_F _CUS_T_ODY RECORD AND ANALYSIS REQUEST FORM - - - —1 r---------------- - -------- -•-------•-•-------•-•-•-.----- �� Analytical Laboratory Services i Analytical Laboratory Use Only ' Mail Code MG03A2 (Building 7405) ! ! `� / /� Matrix: SOLID Samples NC___ 13339 Hagers Ferry Rd ! !o/ `-7 10 � 0 From ogmnating SC OH _ ' ENERGY,Huntersville, N.C. 28078 ! SAMPLE PROGRAM - B (980) 875-5245 i ; Q..�/ /` ?� Ground Water Fax: 980 875-4349 r_— (J NPDES 1)Project Name RIVERBEND PLM TESTING 704-263-3226 3)Client 4)Fax No: Ron Cobb, Bristol Grohol, Sean DeNeale 5)Business Unit: 6)Project ID: 7)Account: n 11 �VC.Q.B 1 8) Operating Unit: 9)Activity ID: 10)Process ID � jcZP6sr ` 3Rz C-r- S rn.- -[=-9 AW: When specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or 2) Provide correct accounting for Operating Unit and Process to. LAB USE ONLY 72Chem I I i "Lab ID ; ,� Desktop No eT I to v d�/ I E - �—' `�-I o -- U I�1 13Sample n or ID .Vendo Other Plant _ i.J RJ Lee kmr olerTem(ClRCRA Waste iPDa PO 5021798 erv.:i=Hn n_u j 4=16-_%N"e - I I 15 N cc t N a T o 1 m LL 0 a 14COIlection Information I Date Time Siqnature ^ r� I7 15290 12-8-17 Page 14 of 15 i Page 1 of 2— i DISTRIBUTION ORIGINAL to LAB, i COPY to CLIENT I I I Date/Time 21)Relinquished BY C I R t L.0 r ,��Q A , r o �� !'l IJ Jt/ Accepted By: Dalerrime �� 22Re nested Turnarou d q Relin u' d B Date ime q Y Jr/ c J Aj Acce d By: / DatelTime /�. ...—'� 10 Days .- �� n _ Relinquish y- erri - •�.y.� iSealed7l-ockid Aepted y: Date rime oc 5 Days By Date(Time Sealed/Lock Opened By Date/Time • 48 Hr t � x? 24)Comments CHAIN OF _C_U_S_T_OD_Y_ RECORD AND ANALYSIS REQUEST S__T_ FORM --- ---1 r----------------------------------' ---------------i DUKE Analytical Laboratory Services j Analytical Laboratory Use Only Mail Code MG03A2 (Building 7405 ! I �� Matrix: SOLID Samples NC_ j ( 9 ) // II Originating SC_ t^� 13339 Hagers Ferry Rd ! ! V From OH-.—_ E N E R V Huntersville, N. C. 28078 ! / SAMPLE PROGRAM I N (960) 875-5245 I ! •�, l / Ground Water,_ Fax: (980) 875-4349-------- ! j !!! i7 NPDES__.. 2 0 0 v E E 0 C 1)Project Name RIVERBEND PLM TESTING 704-263-3226 3)Client Ron Cobb, Bristol Grohol, Sean DeNeale 4)Fax No: 5)Business Unit: 6)Project ID: 7)Account: 8) Operating Unit: 9)Activity ID: 10)Process ID JMjV. =: When specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or 2) Provide correct accounting for Operating Unit and Process ID. LAB USE ONLY .I 12Chem I I "Lab ID •, ,� Desktop No. E — -- .a I I � I � I E jE :U I 1 I I 13Sample Description or ID �-3 I j RJ Lee Cooler Ten :PO u 'Spr serv.:1=1 PO 5021798 2=1-!04 3=H 4=1 =Ns Q 14Collection Information E O Date Time Si nature U 1171)11.3211 & Other _ Plant RCRA Waste _ 1 'iMMME 12-8-17 Page 15 of 15 Page of 2 DISTRIBUTION ORIGINAL to LAB, COPY to CLIENT 21)Relinquished By f J Datelrime (' O Accepted By Date fl! �7Cpgl zsRequested Turnaround Relinquished By Datelri �� //•'J Accepted B� / Dat im 10 Days Relinquished By Date/rime Accepted By: aterrime 5 Days Sealed/Locked By Date/Time Sealed/Lock Opened By Datelrime 48 Hr r•^ � - 24)Comments ' � W DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Vendor QC Data Review Summary Report Order Number: J17120297 Project Name: RIVERBEND - PLM ANALYSIS Customer Name(s): Ron Cobb; Bristol Grohol; Sean DeNeale Lab Contact: Peggy Kendall Phone: 980-875-5848 Report Authorized By: e � & F� (Signature)U re Program Comments: Please review all vendor data for case narratives with explanations of quality control failures and data qualifiers. 12-22-17 Page 1 of 15 Any analytical tests or individual analytes within a test flagged with a qualifier indicate a deviation from the method quality system or quality control requirement. Certified vendor results and QC qualifiers can be found in the vendor lab final report. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Vendor Data Review Criteria: This vendor data package has been reviewed at the Duke Analytical Laboratory for the following applicable criteria: ' Required QC samples collected and analyzed Required tests performed for all samples Vendor Laboratory utilized required test methods for all analyses Vendor Laboratory met all requested Reporting Limits (RL) QC Results reviewed for outlying recovery values Case Narrative: No QC issues found during vendor QC data review. 12-22-17 Page 2 of 15 RJ LEE GROUP DELIVERING SCIENTIFIC RESOLUTION December 22, 2017 Peggy Kendall Duke Energy Analytical Laboratory 13339 Hagers Ferry Rd. Building 7405, MG30A2 Huntersville, NC 28078 RE: Duke Energy Project — J 17120297 R1 Lee Group Project Number AOH1047985-0 Dear Ms. Kendall, The RJ Lee Group, Inc. Monroeville laboratory received 23 samples on December 15, 2017 associated with Duke Energy job number J17120297. The samples were logged into RJ Lee Group project number AOH1047985-0 and assigned RJLG sample numbers as indicated in Appendix A. The samples were received in good condition with all custody seals in place and intact. Attached in Appendix A is the signed sample receipt confirmation form, COC, and sample receipt check list. These results are submitted pursuant to RJ Lee Group's current terms and conditions of sale, including the company's standard warranty and limitation of liability provisions. No responsibility or liability is assumed for the manner in which the results are used or interpreted. Unless notified to return the samples covered in this report, RJ Lee Group will store them for a period of ninety (90) days before discarding. Should you have any questions regarding this information, please do not hesitate to contact us. Sincerely, Bryan R. Bandli, PhD Principal Investigator Attachments: Chain of Custody Forms Mineral Identification Report 350 Hochberg Road, Monroeville PA,15146 1 P 724.325.1776 F 724.733.1799 WWW.RJLG.COM 12-22-17 Page 3 of 15 Appendix A Chain of Custody Forms WWW.RJLG.COM 12-22-17 Page 4 of 15 cO J LEE GROUP Original Issue: 09/16/2005 Effective Date: May 2014 Approved By: Quality Assurance Form A FOR.002.4 Supersedes: Form FOR-002A Rev. 03 Page 1 of 2 Chain of Custody RJ Lee Group Work Order #: AOH1047985-0 Project Name/Case #: Riverbend PLM Testing Received From: Relinquished To: Peggy Kendall RJLee Group, Inc. Customer Support 350 Hochberg Road Duke Energy Central Lab Monroeville, PA 15146 United States 13339 Hagers Ferry Road Main: 724-325-1776 Fax: 724-325-1775 Hunterville, NC 28078 United States Email: peggy.kendall@duke-energy.com Main: 980-875-5848 Sample ID Client Sample ID Date Received 10421728 2017041565 12/15/2017 9:25 AM EST 10421729 2017041566 12/15/2017 9:25 AM EST 10421730 2017041567 12/15/2017 9:25 AM EST 10421731 2017041568 12/15/2017 9:25 AM EST 10421732 2017041569 12/15/2017 9:25 AM EST 10421733 2017041570 12/15/2017 9:25 AM EST 10421734 2017041571 12/15/2017 9:25 AM EST 10421735 2017041572 12/15/2017 9:25 AM EST 10421736 2017041573 12/15/2017 9:25 AM EST 10421737 2017041574 12/15/2017 9:25 AM EST 10421738 2017041575 12/15/2017 9:25 AM EST 10421739 2017041576 12/15/2017 9:25 AM EST 10421740 2017041577 12/15/2017 9:25 AM EST 10421741 2017041578 12/15/2017 9:25 AM EST 10421742 2017041579 12/15/2017 9:25 AM EST 10421743 2017041580 12/15/2017 9:25 AM EST 10421744 2017041581 12/15/2017 9:25 AM EST 10421745 2017041582 12/15/2017 9:25 AM EST 10421746 2017041583 12/15/2017 9:25 AM EST 10421747 2017041584 12/15/2017 9:25 AM EST 10421748 2017041585 12/15/2017 9:25 AM EST 10421749 2017041586 12/15/2017 9:25 AM EST 10421750 2017041587 12/15/2017 9:25 AM EST 10421751 QC01_2017041574 12/15/2017 9:25 AM EST 10421752 QCO2_2017041584 12/15/2017 9:25 AM EST Dec 15, 2017 1:42 PM EST 350 Hochberg Road, Monroeville, PA 15146 Page 1 of 2 Phone: (724) 325-1776 1 Fax: (724) 733-1799 12-22-17 Page 5 of 15 Received From: Peggy Kendall Method of Shipment: Federal Express Company: Duke Energy Central Lab Date: 12/15/2017 Received By: Monica Carse Package Condition Upon Receipt: Sealed Company: RJ Lee Group, Inc. Date: 12/15/2017 Relinquished Method of Shipment: Company: Date: Received By: Package Condition Upon Receipt: Company: Date: Relinquished Method of Shipment: Company: Date: Received By: Package Condition Upon Receipt: Company: Date: Dec 15, 2017 1:42 PM EST 350 Hochberg Road, Monroeville, PA 15146 Page 2 of 2 Phone: (724) 325-1776 1 Fax: (724) 733-1799 12-22-17 Page 6 of 15 �o�liay75�� Q CHAIN OF RECORD AND ANALYSIS REQUEST FORM 12-22-17 Page 7 of 15 �� r tK\ ENERGY, B i? _C_U_S_TODY - _ "t Analytical Laboratory Seryice s j Mail Code MG03A2 (Building 7405) I 13339HegersFerryRd I Huntersville, N. C. 28078 j (900 875-5245 I Fax: 980 875-4349 I r-------•--------_.-•-•-•-•-•-•-•-•-•-.-...-._.� - - - - - - - Analytical Laboratory Use Only Sam les NG I Matrix: SOLID P I I 7 V.7 Originating 5Gj From oH_ ' I SAMPLE PROGRAM 7 I�'�17 JIJ ILI ` Ground Water_ I I I Pagg I Ot DISTRIBUTION ORIGINAL to LAD, DOPY to CLIENT C 1 )Pro)ect Name RIVERBEND PLM TESTING 704-263-3226 ' 31Cliont Ron Cobb, Bristol Grohol, Sean DeNeale 4)FaxNo: 5)Buslness Unit: 6)Pro)ect 113; ])Account: B) Operating Unit: 9)Activily ID: 1q)Process ID Imo: When specific accounting has been established and Is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or 2) Provide correct accounting for Operating Unit and Process to. LAB USE ONLY f I "Lab ID L m I 1 a 13 0 u I� m o i S69 j M i 5 io vane /V I rl Omer_ PJ tee..,. Plant — I I Cooler Temp C RGRA Waste I +pO: D 5a2I79.8serv.:1=N 2=H O,ZH _ 4=1 - e1 5 LOOK'. y W Gu tplxl r_?t?_ 1rrlPlPtr.411 -t 0 ikB, ➢�r0 )r1e tE' iri i5. ,a cc 'rp 'i O (n O u ro 12Chem 14Collection Information E o Desktop No. 13Sam le Description or ID Date Time Signature tIIeK �t �►-in- cliK u s - y�i it 2� IZo 21)Relinqulahed Ely C L -- - oatelrime z , !p Accepted ay ��� Datam a 22Requested Turnaround Rail n ' had By D tofrle Ace Dar Imp �J/ 10 Days bN `DJ� /`- j Relinquished By Dale/Time Accepted ey; Datefrime - 5 Days Sealed/Locked By liarrme SualedlLock Opened By DaterTime • 48 Nr 24)comments �aftz ��� �aH101 17r�� CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM Page 8 of 15 Page ��� --------------------------------------- Analytical1 Laboratory Services i t r..-...-..-•-•-•-•-•-•-•-•-•-•-•-•-•-•-•-•----�....._._._.-....._.-.-.� Analytical Laboratory Use Qnly page 1 Of I SLID Samples NC— Mail Code MG03A2 (Building 7405) 13339 Hegers Ferry Rd I I� � [ Matrix: t Originating SC_ i 9 g DISTRIBUTION Huntersville, N. C. 28078 i From OH i PROGRAM ORIGINAL to LAB, t� H 4y' (980) 875-5245 t I f .�(! c I '/ [2 rr3�l�- f -f 2Z GroundSAMPL Ground wafer i I COPY to CLIENT Fax: 900 875-4349 C 1)Project Name RIVERBEND PLM TESTING 704-263-3226 3)Cllent Ron Cobb, Bristol Grohol, Sean DeNeale 4)Fax No: 5)Busine5s unit: B)Prolect ID: 7)AccouM: a) Operating Unit: 91Activity ID: 10)Process ID 1I1lP2L nt: When specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, or 2) Provide correct accounting for Operating Unit and Process ID. --------------- LAB USE ONLY I• 12Chem I f Lab11) i:�5 Desktop No. I o i� u 2 f IE I I � �U I I ! � I i--- i E I 13Sample Description or ID S -5 e- r C ,Vol Other ,A/fl-I Plant_ L RJ Lee Cooler Tomp RCRA Waste iPO PO5021798 'sPr serv.:1=H 6 5 --------------- L.00)i<_...... _.. .. 14C0Ilection Information Date I Time Signature 7 k 10q 3551 ( i to 1 n 1( 10 5=N4 e N K<D LU cc cc 7 a a a LL tl M ei U m R ar C 0 U 0 4t m 0 21)Rellnquiahad By �, RK� a SA %,� Daterrime 2 �� Accepted By: bh/ Dataf m �� y rd 22 Requested Turnaround Relinquished B DatelTima J Accepted D telfime 1$Days Relinquished Da efrime c ed�9. Datelrlme /z- /,- C- / J r /d -/ -/ % 09. A 5 Days Sealed/Locked Sy Daterrime Seeledli-ock Opened By DatwTima • 4$ Hr 24)Comments f /.Z z l T -7 12-22-17 Page 9 of 15 Appendix B Mineral Identification Report WWW.RJLG.COM Identification 12-22-17 Page 10 of 15 R�Mineral RJ LeeGroup, Inc. Polarized Light Microscopy (PLM) Laboratory Report Peggy Kendall Report Date: 12/21/2017 Duke Energy Central Lab Sample Received Date: 12/15/2017 13339 Hagers Ferry Road RJLG Project: AOH1047985-0 Hunterville, NC 28078 United States Customer COC: J17120297 Email: peggy.kendall@duke-energy.com Purchase Order: J17120297 / 5021798 Main: 980-875-5848 Analytical Method: Fly Ash Determination by PLM Customer Date Date Area % Non -Fly Ash Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017041565 10421728 12/20/2017 11/27/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017041566 10421729 12/20/2017 11/28/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017041567 10421730 12/20/2017 11/28/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017041568 10421731 12/20/2017 11/28/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017041569 10421732 12/20/2017 11/29/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017041570 10421733 12/20/2017 11/29/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017041571 10421734 12/20/2017 11/29/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz AOH1047985-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 1 of 4 12-22-17 Customer Date Date Area % Non -Fly Ash Page 11 of 15 Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017041572 10421735 12/20/2017 11/29/2017 1% Clay Orange Coarse Grain Sediment. Opaques Quartz 2017041573 10421736 12/20/2017 11/30/2017 ND Clay Red Coarse Grain Sediment. Opaques Quartz 2017041574 10421737 12/20/2017 11/30/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017041575 10421738 12/20/2017 12/01/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017041576 10421739 12/20/2017 12/01/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017041577 10421740 12/20/2017 12/04/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017041578 10421741 12/20/2017 12/04/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017041579 10421742 12/20/2017 12/05/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017041580 10421743 12/20/2017 12/05/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017041581 10421744 12/20/2017 12/06/2017 ND Clay Tan Coarse Grain Sediment. Opaques Quartz AOH1047985-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 2 of 4 12-22-17 Customer Date Date Area % Non -Fly Ash Page 12 of 15 Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017041582 10421745 12/20/2017 12/07/2017 ND Clay Tan Coarse Grain Sediment. Opaques Quartz 2017041583 10421746 12/20/2017 12/07/2017 ND Clay Tan Coarse Grain Sediment. Opaques Quartz 2017041584 10421747 12/20/2017 12/08/2017 ND Clay Tan Coarse Grain Sediment. Opaques Quartz 2017041585 10421748 12/20/2017 12/11/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017041586 10421749 12/20/2017 12/11/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017041587 10421750 12/21/2017 12/11/2017 ND Clay Tan Coarse Grain Sediment. Opaques Quartz QC01_2017041574 10421751 12/21/2017 11/30/2017 ND NA Orange Coarse Grain Sediment. QCO2 2017041584 10421752 12/21/2017 12/08/2017 ND NA Tan Coarse Grain Sediment. AOH1047985-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 3 of 4 12-22-17 Page 13 of 15 Disclaimer Notes • Samples will be returned to client immediately upon the release of final report. * These results are submitted pursuant to RJ Lee Group's current terms and conditions of sale, including the company's standard warranty and limitation of liability provisions. No responsibility or liability is assumed for the manner in which these results are used or interpreted. * This test report relates to the items tested. * Any reproduction of this document must include the entire document in order for the report to be valid. • This report may not be used to claim product endorsement by NVLAP Lab Code 101208-0 or any agency of the U.S. Government. • Sample(s) for this project were analyzed at our: Monroeville, PA (AIHA # 100364, NVLAP # 101208-0, NY ELAP # 10884) facility. • If RJ Lee Group, Inc. did not collect the samples analyzed, the verifiability of the laboratory's results is limited to the reported values. • For the purposes of this method, Fly Ash is defined as any particle consistent with Coal Ash. . The method reporting level is 1 % and anything <1 % is considered a not -detected. Quartz — Angular anisotropic particulate with low relief. Feldspar — Angular to blocky anisotropic particulate, low to moderate relief, biaxial, can have polysynthetic twinning. Clay — Sheet silicates with polycrystalline or display non -uniform extinction with low to moderate relief, and zero to low birefringence. Clay also refers to particles that are less than 2.0 microns. Opaques — Opaque is a generic term for a particle that does not transmit light. Opaque minerals are distinguished from opaque bottom ash based on morphology of fracture. Fly Ash — Isotropic to opaque spheres, agglomeration of spheres, and angular ash particles. Organic Particulate — Pollen, plant and insect matter, and carbonaceous matter. Carbonates — High birefringent, can be rhombohedral, with high relief. Diatoms — Silica rich isotropic particles with various morphologies. Mica — Sheet silicate with moderate to high relief and low birefringence, mono -crystalline, and normal extinction. Miscellaneous Silicate — Isotropic and anisotropic silicates, with low to high relief, identification unsure and beyond the scope of the method to identify. Amphibole — Elongated anisotropic particulate with moderate to high relief. Coal — Irregular to angular particles with moderate opacity, edges and thin particles are reddish brown in color. <1 % Fly Ash — Fly Ash observed, none counted. ND — No Fly Ash detected. AOH1047985-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 4 of 4 CHAIN OF_ CUSTODY RECORD AND ANALYSIS REQUEST FORM 12-22-15 --Page 14 of 15 DUKE Analytical Laboratory Services iAnalytical Laboratory Use Only Mail Code MG03A2 (Building 7405) ! I Matrix: SOLID Samples NC._ j Page 1 Of 'L j `) Originating Sc_ I DISTRIBUTION rater Hlle, N.C.Ferry Rd ! ! �� i 12 v !�( From OH___ Huntersville, N28078 ! SAMPLE PROGRAM ORIGINAL to LAB, E N (980) 875-5245 I I (`t 1) 3I I1 %y'Z'L I COPY to CLIENT i Ground Water_ Fax: 980) 875-4349 NPDES ----- d a E U E E N U 1)Project Name RIVERBEND PLM TESTING 704-263-3226 3)Client Ron Cobb, Bristol Grohol, Sean DeNeale 4)Fax No: 5)Business Unit: 6)Project ID: 7)Account: 8) Operating Unit: 9)Activity ID: 10)Process ID IrMQrt@t: When Specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or 2) Provide correct accounting for Operating Unit and Process ID. LAB USE ONLY •1 12Ohern I I "Lab ID ; t Desktop No. rn i io I l 0 -- Srv,a ; o — i �- U S�Z i S ii o i 5K 1 1 � I 7 ; -- i le Description or ID .VenC /V�!� Other_ i i R1 Lee Plant Cooler Temo (C) RCRA Waste Ipp: PO 5021798 15pr 2=H 4=1 14COIlection Information Date Time Signature 12� t�l o I :1=H 3=H 5=Noe 5 N N uj J QCT Ir dD t to B T U. o. -0 °o 2 a 21)Relinquished By Z /D C 1l .o sA P�Ar . Date/Time Accepted By O� /1 „� ate a ('�� - 22Requested Turnaround Relin shed By D /Ti a n rbti1 Accep y: c-� Dale imo /- 10 Days j Z �Z X� _ Relinquished ByData/rime, Accepted By: Date rime 5 Days Sealed/Locked By Dat ime Sealed/Lock Opened By Date rime 48 Hr ran;., 24)Comments CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM 12-22-17 _,_,_,i Page 15 of 15 DUKE Analytical Laboratory Services j Analytical Laboratory Use Only Mail Code MG03A2 (Building 7405 SOLID Samples NC_ j Page 1 of ( g ) ; I Matrix: iOri Originating SC— I DISTRIBUTION ENERGY,,, 13339 Hagers Ferry Rd ! ! J` I L�� G� i SFr m 9 OR-_._ Y HuntersVllle, N. C. 28078 I SAMPLE PROGRAM ORIGINAL to LAB, i t„ (980) 875-5245 ; ; TI1L t i /1 y(1} �L'' 7 Z Ground Water_ ! COPY to CLIENT Fax: 980 875-4349 I !� NPDES m E c ( E C c, 1)Project Name RIVERBEND PLfli1 TESTING 704-263-3226 3)Client Ron Cobb, Bristol Grohol, Sean DeNeale 4)Fax No: 6)Buslness Unit: ID: 7)dccount: 8) Operating Unit: 9)Activity ID: 10)Process ID jjpjjl ant: When specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or 2) Provide correct accounting for Operating Unit and Process ID. LAB USE ONLY - ! 12Chem "Lab ID L Desktop No. I JT r I o I 5 IE I �r7 I 0 � o -- : ,D is 1 SLiID I E �.-10 22 G i -- —� E I la :U 1 I I I 13Sample Description or ID S -5 L .Vet Other a�)�1 Plant I_ KJ Lee Cooler Temp C I RCRA Waste 'PO PO 5024798 15Prrv.:1=H=34OH ¢es 2=H S 4=1 5 I — — — — — — — — — rn 14COIlection Information Date I Time I Siqnature MFA 4f e •� W W J � Q m Cc > t c ro o U N Q Q � T LL O CL .0 F N 0 a 21)Relinquished By Cl R LL-0 C A A Date/Tim �2 2 '� / J F'l /�t Accepted By: bAj Date/i'� 2 . 4) �J ZZRequested Turnaround Relinquished B DaterFime dN (�ar�3 1 /-? y Accepted D ta/Time _ /,., -� v 10 Days Relinquished - Dae/Time c ted Datafrime r/�Z�� 5 Days Sealed/Locked By Date/Time Sealed/Lock opened By Date/Time • 48 H r 24)Comments DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Vendor QC Data Review Summary Report Order Number: J17120575 Project Name: RIVERBEND - PLM ANALYSIS Customer Name(s): Ron Cobb; Bristol Grohol; Sean DeNeale Lab Contact: Peggy Kendall Phone: 980-875-5848 Report Authorized By: 0- (Signature) 1-12-18 Page 1 of 12 Program Comments: Please review all vendor data for case narratives with explanations of quality control failures and data qualifiers. Any analytical tests or individual analytes within a test flagged with a qualifier indicate a deviation from the method quality system or quality control requirement. Certified vendor results and QC qualifiers can be found in the vendor lab final report. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Vendor Data Review Criteria: This vendor data package has been reviewed at the Duke Analytical Laboratory for the following applicable criteria: • Required QC samples collected and analyzed • Required tests performed for all samples • Vendor Laboratory utilized required test methods for all analyses • Vendor Laboratory met all requested Reporting Limits (RL) • QC Results reviewed for outlying recovery values Case Narrative: No QC issues found during vendor QC data review. 1-12-18 Page 2 of 12 RJ LEE GROUP DELIVERING SCIENTIFIC RESOLUTION January 10, 2018 Peggy Kendall Duke Energy Analytical Laboratory 13339 Hagers Ferry Rd. Building 7405, MG30A2 Huntersville, NC 28078 RE: Duke Energy Project J17120575 RJ Lee Group Project NumberAOH1048086-0 Dear Ms. Kendall, The RJ Lee Group, Inc. Monroeville laboratory received 13 samples on December 28, 2017 associated with Duke Energy job number J17120575. The samples were logged into RJ Lee Group project number AOH1048086-0 and assigned RJLG sample numbers as indicated in Appendix A. The samples were received in good condition with all custody seals in place and intact. Attached in Appendix A is the signed sample receipt confirmation form, COC, and sample receipt check list. These results are submitted pursuant to RJ Lee Group's current terms and conditions of sale, including the company's standard warranty and limitation of liability provisions. No responsibility or liability is assumed for the manner in which the results are used or interpreted. Unless notified to return the samples covered in this report, RJ Lee Group will store them for a period of ninety (90) days before discarding. Should you have any questions regarding this information, please do not hesitate to contact us. Sincerely, t� Bryan R. Bandli, PhD Principal Investigator Attachments: Chain of Custody Forms Mineral Identification Report 350 Hochberg Road, Monroeville PA,15146 1 P 724,325.1776 F 724.733,1799 W W W.RJLG.COM 1-12-18 Page 3 of 12 Appendix A Chain of Custody Forms WWW.RJLG.COM 1-12-18 Page 4 of 12 cO J LEE GROUP Original Issue: 09/16/2005 Effective Date: May 2014 Approved By: Quality Assurance Form A FOR.002.4 Supersedes: Form FOR-002A Rev. 03 Page 1 of 2 Chain of Custody RJ Lee Group Work Order #: AOH1048086-0 Project Name/Case #: Riverbend PLM Testing Received From: Relinquished To: Peggy Kendall RJLee Group, Inc. Customer Support 350 Hochberg Road Duke Energy Central Lab Monroeville, PA 15146 United States 13339 Hagers Ferry Road Main: 724-325-1776 Fax: 724-325-1775 Hunterville, NC 28078 United States Email: peggy.kendall@duke-energy.com Main: 980-875-5848 Sample ID Client Sample ID Date Received 10422554 2017042677 12/28/2017 9:30 AM EST 10422555 2017042678 12/28/2017 9:30 AM EST 10422556 2017042679 12/28/2017 9:30 AM EST 10422557 2017042680 12/28/2017 9:30 AM EST 10422558 2017042681 12/28/2017 9:30 AM EST 10422559 2017042682 12/28/2017 9:30 AM EST 10422560 2017042683 12/28/2017 9:30 AM EST 10422561 2017042684 12/28/2017 9:30 AM EST 10422562 2017042685 12/28/2017 9:30 AM EST 10422563 2017042686 12/28/2017 9:30 AM EST 10422564 2017042687 12/28/2017 9:30 AM EST 10422565 2017042688 12/28/2017 9:30 AM EST 10422566 2017042689 12/28/2017 9:30 AM EST 10422567 QC_2017042686 12/28/2017 9:30 AM EST Dec 28, 2017 10:25 AM EST 350 Hochberg Road, Monroeville, PA 15146 Page 1 of 2 Phone: (724) 325-1776 1 Fax: (724) 733-1799 1-12-18 Page 5 of 12 Received From: Peggy Kendall Method of Shipment: Federal Express Company: Duke Energy Central Lab Date: 12/28/2017 Received By: Monica Carse Package Condition Upon Receipt: Sealed Company: RJ Lee Group, Inc. Date: 12/28/2017 Relinquished Method of Shipment: Company: Date: Received By: Package Condition Upon Receipt: Company: Date: Relinquished Method of Shipment: Company: Date: Received By: Package Condition Upon Receipt: Company: Date: Dec 28, 2017 10:25 AM EST 350 Hochberg Road, Monroeville, PA 15146 Page 2 of 2 Phone: (724) 325-1776 1 Fax: (724) 733-1799 1-12-18 Page 6 of 12 RJ Lee Group Sample Receipt and Log in Check List bent �A Duke EnerLta a'cei4 12/2812017 '...._ 12I2812017 TimerRecei�e ,,.. 9:30 AM B e Monica Carse CfG a . : „h, r ; J17120575 AOH1048086-0 �#"CooisrszF�eceiJe'd�,?' 7 9eans4pf,5h sVI FedEc +ir Bilil r r r 7437 9390 6803 As Received Screen Yes No Comments Were the Coolers received in good condition? Was there evidence of tampering? Are Custody Seals intact and in good condition? ✓ Were Coolers received between 2 and 4 de rees C? ice' Were all samples intact? ✓ Were all samples accurate) labeled? Was the COC received in good condition? Did the sample ID on COG match the ID on the sample jars? t✓ Were there any discrepancies among samples and COC? ✓ Is the CDC completely filled out? Was the COC relinquished properly?a% List any anomalies associated with Sample Receipt Analyst Signature: Manager Signatu - 1 /7 C b/ / 0 -Y ''CJ §�6 - O 1-12-18 Page 7 of 12 CHAIN CUSTODY RECORD AND ANALYSIS REQUEST FORM to DUKE - -Anal IcalLaborato Services t r - - - - - - - - - - - - - - - _._._._._._.-.-.-.-__--•� Yt ry j Analytical Laboratory Use Only Page Mail Code MGO3A2 (Building 7405) I I Matrix: SOLID Samptes NG i 1 of 13339 Ha ers Ferry Rd I i %� Originating sC_ E�EI \ � e From oH_ t ORIGINAL toLDISTRIBUTION t G V H 13339 Hag s e 2Rd ORIGINAL to LAB, ®N 984 875-5245 I I SAMPLE PROGRAM Ground water_I COPY to CLIENT — NPDES e v E U a E E U 1)Project Name a 704-263-3225 RIVERBEND PLIVI TESTING 3)Client 4}Fex No: Ron Cobb, Bristol Grohol, Sean DeNeale 5)Buaines5 Unit: 6)Project ID: 7)Account: t"GL (1-8 00 1 9) Operating Unit: 9)Activity to: 10)Process 10 �Za 0,6 Cr_s, NccP�sf 9 t]S: When specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, or 2) Provide correct accounting for Operating Unit and Process ID. LAB USE ONLY '• 12Chem "Lob to i = Desktop No o o t`CL iE -2 Io I�i U I 1 I I I Y3Sample Description or ID r 2 —•—/ 5-0 S-Gal .Vendor j Other_ Ptant I I Rj Lee Cooler TempC RCRA Waste I :Po rr PO ���� $ 15Pr serv.A=H 2=H Oa 3=H 4=1 - e 5 _L15 In r t p_I1lR� 't4AL- -- _ ru a_tapro,priate areas, a 0 m oC } c U 0 0 0 N 14COIlection Information Date Time Signature 12 IZ L(4 b 17-1 «sA 7 1-12-18 Page 8 of 12 Appendix B Mineral Identification Report WWW.RJLG.COM Identification Page 9 of 12 R�Mineral RJ LeeGroup, Inc. Polarized Light Microscopy (PLM) Laboratory Report Peggy Kendall Report Date: 01/10/2018 Duke Energy Central Lab Sample Received Date: 12/28/2017 13339 Hagers Ferry Road RJLG Project: AOH1048086-0 Hunterville, NC 28078 United States Customer COC: J17120575 Email: peggy.kendall@duke-energy.com Purchase Order: J17120575 / 5021798 Main: 980-875-5848 Analytical Method: Fly Ash Determination by PLM Customer Date Date Area % Non -Fly Ash Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017042677 10422554 01/10/2018 12/12/2017 ND Opaques Tan Coarse Grain Sediment. Quartz Coal 2017042678 10422555 01/10/2018 12/12/2017 ND Clay Tan Coarse Grain Sediment. Opaques Quartz 2017042679 10422556 01/10/2018 12/13/2017 ND Clay Tan Coarse Grain Sediment. Opaques Quartz 2017042680 10422557 01/10/2018 12/13/2017 ND Clay Tan Coarse Grain Sediment. Opaques Quartz 2017042681 10422558 01/10/2018 12/14/2017 ND Clay Tan Coarse Grain Sediment. Opaques Quartz 2017042682 10422559 01/10/2018 12/14/2017 ND Clay Tan Coarse Grain Sediment. Opaques Quartz 2017042683 10422560 01/10/2018 12/14/2017 ND Clay Tan Coarse Grain Sediment. Opaques Quartz AOH1048086-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 1 of 3 1-12-18 Customer Date Date Area % Non -Fly Ash Page 10 of 12 Sample # : RJLG ID Analyzed Collected Fly Ash Components Comments 2017042684 10422561 01/10/2018 12/14/2017 ND Clay Tan Coarse Grain Sediment. Opaques Quartz 2017042685 10422562 01/10/2018 12/15/2017 ND Clay Tan Coarse Grain Sediment. Opaques Quartz 2017042686 10422563 01/10/2018 12/15/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017042687 10422564 01/10/2018 12/15/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017042688 10422565 01/10/2018 12/18/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz 2017042689 10422566 01/10/2018 12/18/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz QC_2017042686 10422567 01/10/2018 12/15/2017 ND Clay Orange Coarse Grain Sediment. Opaques Quartz AOH1048086-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 2 of 3 1-12-18 Page 11 of 12 Disclaimer Notes • Samples will be returned to client immediately upon the release of final report. * These results are submitted pursuant to RJ Lee Group's current terms and conditions of sale, including the company's standard warranty and limitation of liability provisions. No responsibility or liability is assumed for the manner in which these results are used or interpreted. * This test report relates to the items tested. * Any reproduction of this document must include the entire document in order for the report to be valid. • This report may not be used to claim product endorsement by NVLAP Lab Code 101208-0 or any agency of the U.S. Government. • Sample(s) for this project were analyzed at our: Monroeville, PA (AIHA # 100364, NVLAP # 101208-0, NY ELAP # 10884) facility. • If RJ Lee Group, Inc. did not collect the samples analyzed, the verifiability of the laboratory's results is limited to the reported values. • For the purposes of this method, Fly Ash is defined as any particle consistent with Coal Ash. . The method reporting level is 1 % and anything <1 % is considered a not -detected. Quartz — Angular anisotropic particulate with low relief. Feldspar — Angular to blocky anisotropic particulate, low to moderate relief, biaxial, can have polysynthetic twinning. Clay — Sheet silicates with polycrystalline or display non -uniform extinction with low to moderate relief, and zero to low birefringence. Clay also refers to particles that are less than 2.0 microns. Opaques — Opaque is a generic term for a particle that does not transmit light. Opaque minerals are distinguished from opaque bottom ash based on morphology of fracture. Fly Ash — Isotropic to opaque spheres, agglomeration of spheres, and angular ash particles. Organic Particulate — Pollen, plant and insect matter, and carbonaceous matter. Carbonates — High birefringent, can be rhombohedral, with high relief. Diatoms — Silica rich isotropic particles with various morphologies. Mica — Sheet silicate with moderate to high relief and low birefringence, mono -crystalline, and normal extinction. Miscellaneous Silicate — Isotropic and anisotropic silicates, with low to high relief, identification unsure and beyond the scope of the method to identify. Amphibole — Elongated anisotropic particulate with moderate to high relief. Coal — Irregular to angular particles with moderate opacity, edges and thin particles are reddish brown in color. <1 % Fly Ash — Fly Ash observed, none counted. ND — No Fly Ash detected. AOH1048086-0 350 Hochberg Road, Monroeville, PA 15146 1 Phone: (724) 325-1776 1 Fax: (724) 733-1799 Page 3 of 3 1-12-18 Page 12 of 12 CHAIN OF_ CUSTODY RECORD AND ANALYSIS REOUE T FORM ...... - - -� r - �._._ -.�._ -, J4nalytical LaboraiOry Usni e +{ Analytira# Le ratori Services - 7 of l Alai[ Co" MGp3A2 {1}u11C1Wq 7An5i .. 1 I Nalri�: SOLID — C— I I7ri jinbYln $C_ pG$TRi@l}TI ON JJ � � R 13399 H0gft3 Ferry Rd I k Hunlergvllle, N. C- 26078 . 1 1 # } Fr°n' - — SAdAG1-B PROCl131iM {ilauhd 4Ye6a� _ — QRkG I NAL to LAB, i COPY Co CLIENT {994� 875-6246 IJ ! fjpor=s _ — — — — — —I'ax_ 9b0 87S�17 9.—._.—.—..... � •Yandor {}IYueF_ I l 1 jPr(*ct We" 74+k26d,a� FLsnt — RIVERBEND PLM TEST1NCs I� Leer, CoalerTs.Y`' C RCRAV SSW — E 9yClieid gjFaX Mom:,. 'pO i PQ PF yo, % $ H� u° Cobb, Flon C, BlistOi GY4]holr Soon DeNeale M ❑. 3=H I 4=1 e _ IL}ae�neasLimi: E e)p(llo= j Oporedng Unit9)Aclirily ILI: 1Uipratsea lD ¢ � Wjlen Specific accounting has ti en nabbLlshed and 46 rY6t indloalud nbvG wa rYO lha loElowing' 11 Enler GOFFCGt Z1CGOUFj1jFYg' ip Ed 5 xm)nrhhng fields above, or }+ 2 j 1xl OUide eorF2Ct sceounling for QpeFeling Unll and FlF4C28s IC . ri LAB------LY T 12 Chem "Collection InfMMOI iun d 9 {{Fern Desktop No. Sample Descriplion or ID w1a rme Si nnuue l 2 LL 5 1 71 I�c - it 45> 1 2 fJ D t LL 9, I E x O / ! ICI � I I r'7 + f -J M i jI llnqu411od Hy nnmlTln7 ,. +7 � AcceW4d BY: fFJI'*� de6Yff a - ppfj�4l�EtCTs�CI r AM i- •. _ .. 9y- Rulinqul� d By DeIL�e TO c6 � r Irm }' t0 Days � aal�nqubnad H _ 1� .ABEepi4 My: 1 Yeltime 6 Days — Sool..dn rsa Or IIYe $edeA'I.O�I� 4pinW By OatdfTime ' 48 1 it — —