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Home My WebLink AboutWQ0036723_Residual Annual Report 2018_20190115Town of Mooresville NORTH CAROLINA 2018 ROCKY RIVER W.W.T.P TELEPHONE (704) 662-8470 FAX (704) 662-8473 POST OFFICE BOX 878 MOORESVILLE, NC 28115 RECEIVED JAN 15 2019 AL ,y I'R. W1 •�- RECENT DINCDEQIDWR JAN 1 2019 Non -Discharge Permitting Unit Annual Class A Report, WQ0036723 Rocky River Wastewater Treatment Facility Mooresville, N.C. 28115 Town of Mooresville NORTH CAROLINA ROCKY RIVER W.W.T.P TELEPHONE (704) 662-8470 FAX (704) 662-8473 POST OFFICE BOX 878 MOORESVILLE, NC 28115 01 /7/19 NCDENR-DWQ Information Processing Unit RECEIVED 1617 Mail Service Center Raleigh, NC 27699 JA N 1 5 2019 Subject: 2018 Annual Sludge Report, W00036723 Distribution of Class A Residuals DWQeM Following is the information requested to accompany our Class "A" Annual report. 1) Facility - Rocky River Wastewater Treatment Facility 369 Johnson Dairy RD. Mooresville, N.C. 28115 Phone: 704-663-2840 2) Responsible official and facility contact — Larry Hendren, Bio-solids Coordinator P.O. Box 878 Mooresville, NC 28115 Phone:704-799-4063 3) Class "A" dried biosolids were distributed under Town of Mooresville permit # WQ0036723 4) (Part A) and (Part B) Distribution of Class "A" Residuals for 2017 were transported to, Joe Hampton in Mt. Ulla, NC, and Doug Carrigan in Mooresville, NC. Total = 363.11 dry metric tons (See Attached Hauling Summary Sheets). Laboratory data from quarterly TCLP analyses have been included in this report. 5)(Part C) I certify, under penalty of law that the above information is, to the best of my knowledge and belief, true and accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Prepared by: Larry Hendren, Bio-solids Coordinator Reviewed by: Jamie Levis, W WTP Plant Manager Signature: J Date Signa Date Town of Mooresville 2018 Hauling Summary Sheet DATE TONS TRANSPORTER DESTINATION COMMENTS 4/1/2018 11.5 Garrin Klutz Farm Mt. Ulla 1 Load 4/29/2018 19.8 Garrin Klutz Farm Mt. Ulla 2 Loads 4/30/2018 10.8 Garrin Klutz Farm Mt. Ulla 1 Load 5/2/2018 54.4 Garrin Klutz Farm Mt. Ulla 5 Loads 7/18/2018 60.4 Garrin Klutz Farm Mt. Ulla 5 Loads 7/19/2018 61.7 Garrin Klutz Farm Mt. Ulla 5 Loads 10/22/2018 32.4 Carrigan Farms Mooresville 8 Loads 10/23/2018 29.6 Carrigan Farms Mooresville 8 Loads 10/24/2018 28.9 Carrigan Farms Mooresville 8 Loads 10/2S/2018 28.1 Carrigan Farms Mooresville 8 Loads 11/29/2018 30.1 Carrigan Farms Mooresville 8 Loads 11/30/2018 34.4 Carrigan Farms Mooresville 10 Loads 11/30/2018 11.7 Town of Mooresville Carrigan Farms - Mooresville 2 Loads Total tons 413.71 Avg. % solids 0.9675 Drytons 400.3 Conversion factor 0.907184 Metric tons 375.31 Dry metric tons 363.11 Calculation: Dry metric tons= total tons * avg.% solids* conversion factor TOWN OF MOORESVILLE CLASS A BIOSOLID PELLETS UTILIZATION AGREEMENT DISTRIBUTED UNDER NC DWQ PERMIT # WQ0036723 I. CONTACT INFORMATION THIRD PARTY INFORMATION Name Doug Car an Mailing .address 1261 Oak Ridge Farm Highway Mooresville. NC 28115 Phone Number 704-664-1450 or 704-662-2014 Email douug@carriganfarms.com TOWN OF MOORESVILE INFORMATION Larry Hendren (Permittee Designee) P.O. Box 878, Mooresville NC 28115 704-799-4063 ]hendren@mooresvillenc.gov II . DESCRIPTION This is pelletized material produced from the heat treatment of residuals from municipal wastewater. This product meets the standards for a Class A biosolid product according to the EPA's 40 CFR Part 503 regulations. III. RESTRICTIONS Residual land application is prohibited except in accordance with the instructions on this Utilization Agreement: 1. If the residuals are likely to adversely affect a threatened or endangered species listed under section 4 of the Endangered Species Act or its designated critical habitat 2. If the application causes prolonged nuisance conditions 3. If the land fails to assimilate the bulk residuals or the application causes the contravention of surface water or groundwater standards 4. If the land is flooded, frozen, or snow-covered, or is otherwise in a condition such that runoff of the residuals would occur 5. Within the 100 year flood elevation, unless the bulk residuals are injected or incorporated within a 24- hour period following a residuals land application event 6. During a measurable precipitation event (i.e. greater than 0.01 inch per hour), or within 24 hours following a rainfall event of 0.5 inches or greater in a 24-hour period 7. If the soil pH is not maintained at 6.0 or greater, unless sufficient amounts of lime are applied to achieve a final soil pH of at least 6.0, or if an agronomist provides information indicating that the pH of the soil, residuals and lime mixture is suitable for the specified crop 8. If the land does not have an established vegetative cover unless the residuals are incorporated or injected within a 24-hour period following a residuals land application event 9. If the vertical separation between the seasonal high water table and the depth of residuals application is less than one foot 10. If the vertical separation of bedrock and the depth of residuals application is less than one foot 11. Biological Residuals shall not be stockpiled for more than 30 days prior to distribution 12. The Third Party accepting the residuals shall provide the Permittee with all other nutrient applications (i.e. organic and/or inorganic fertilizers) 13. A copy of this Utilization agreement shall be maintained at the site when bulk residuals are being applied 14. The residuals shall be prevented from entering any public or private water supply source (including wells) and any surface waters (e.g. streams, lake, river, wetland) 15. Residuals should be land applied at agronomic rates © 2016 Town of.Mooresville 16. Submission of Soil Samples prior to distribution of product 17. The Perm ittee shall not distribute bulk residuals to any person or entity known to be applying residuals contrary to the condition of the signed Utilization Agreement IV. SETBACKS Applicable setbacks in accordance with 15A NCAC 02T .1108(b): Description of Setback Setback by type of application (feet) Cake Residuals Private or public water supply 100 Surface Waters (streams — intemtittent and perennial, perennial waterbodies, and wetlands) 25 Surface water diversions (ephemeral streams, waterways, ditches 0 Groundwater lowering ditches (where the bottom of the ditch intersects the S 0 Wells with exception to monitoring wells 100 Bedrock outcrops 0 V. APPLICATION RATES Application Rates should not exceed the calculated nitrogen requirements based on the Realistic Yield Expectation for a particular crop and the predominant soil series within the application area. This product has a North Carolina Fertilizer label of 5% Nitrogen — 1% Phosphorus — 0% Potassium ratio, but given that it is generated from aerobically digested residual biosolids it is assumed that a 30% mineralization rate (Organic Nitrogen to Plant Available Nitrogen) is used to calculated the Plant Available Nitrogen (PAN). The PAN listed below should be used along with other nutrient application to determine agronomic rates. NUTRIENT RANGES Percent Solids: 4 ° Total Nitrogen: 60-112 lbs/ton Ammonia Nitrogen: 3-6 lbs/ton Nitrate/Nitrite Nitrogen: 0 - 0.01 lbs/ton PAN: 1340 lbs/ton Total Phosphorus: Total Potassium: V.AGREEMENT 20-28 lbs/ton (as P," l O • 1\0 -% Larry Hen , Town of Mooresville Date Approximate Density:15 - 20lbs/fe Third Party (Printed Name) Tr=d Party (Signature) f5ate 0 2016 Town of Mooresville a,.IR I IS M I Full -Service Analytical Environmental Solutions U130PATOPIM INC. Town of Mooresville/RR WWiP Whitney Munroe P. O. Box 878 Mooresville, NC 28115 NC Certification No. 402 NC Drinking Water Can No. 37735 SC Cenification No. 99012 Project: Class A Dried Sludge Lab Submittal Date: 01/16/2018 Prism Work Order: 8010222 Case Narrative 01/07/2019 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: This is a revised report and supersedes the original report dated 2/1/2018. The calculations for SAR and PAN have been added to the case narrative. This is a revised report and supersedes the original revised report dated 03/27/18. The SAR and PAN calculation worksheets have been added to the report. Analysis note for SAR: SAR =[Na]/SORT{ ([Ca]+[Mg])/2} SAR = [ 124/23 ] / SORT { ( [126/20] + [59.6/12.2]) / 2 } SAR = 2.2 Concentrations for Na, Ca, and Mg are expressed in milliequivalents per liter, and SORT designates taking the square root of the operand in parentheses. PAN Equation = 0.3 * (TKN — Ammonia) + 0.5 * (Ammonia) + Nitrate —Nitrite PAN Equation = 0.3 * (49700 - 1890) + 0.5 * (1890) + 5.62 PAN = 15000 Equation uses Mineralization Rate (MR) for Aerobically Digested Solids (0.3) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. "a Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041629-6364 - Toll Free Number: 1-8001629-6364 - Fax: 704/625-0409 Page 1 of 17 Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. 5, 10A E CAN 1 H Terri W. Cole Project Manager Reviewed By Terri W. Cole Project Manager Data Qualifiers Key Reference: B Analyte is found in the associated blank at a concentration >1/2 RL. BH MB greater than one half of the RL, but the sample concentrations are greater than IN the MB. CCV CCV result is above the control limits. Analyte not detected in the sample. No further action taken. SE Surrogate recovery outside the QC limits due to emulsion. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 704/629E364-Toll Free Number: 1-8001929-6364- Fax: 704/626-M9 Page 2 of 17 P R ISM I Fuvionmlen al Solutions s BOR rss n,c Environmental Solutions Sample Receipt Summary 01/07/2019 Prism Work Order 8010222 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received Class 8010222-01 Solid 01/16/18 8:30 01/16/18 12:55 Samples were received in good condition at 4.0 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O, box 240643 -Charlotte, NC 28224-0643 Phone: 7041629-6364 - Toll Free Number, 1-800/629-6364 - Fax: 704/6264"9 Page 3 of 17 -Selvice l' S 1 Y I I FW Environmental al Solutions s Environmental Solutions Town of Mooresville/RR W WTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 0110712019 Client Sample ID: Class A Prism Sample ID: 8010222-01 Prism Work Order: 8010222 Time Collected: 01/16/18 08:30 Time Submitted: 01/16/18 12:55 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Analyst DateTme Batch ID General Chemistry Parameters Plant Available Nitrogen 15000 mg/kg dry 1600 330 20 'Calculation 1/22118 10:49 CLB [CALCI % Solids 97.0 % by 0.100 0.100 1 'SM2540 G 1/22118 14:16 TJV PSA0320 Weight Ammonia as N 1900 mg/kg dry 9.6 2.4 1 'SM460044143 C 1/18/18 14:00 BMS PSA0246 Nitrate/Nitrite as N 5.6 mg/kg dry 5.2 0.57 1 'SM4600-NO3 F 1/18/18 10:02 CLB PIIA0226 PH 6.2 pH Units 1 '9046D 1/17118 13:33 EGC P8A0220 Phosphorus -Total 11000 mg/kg dry 260 37 100 'SM4600-P F IM9/18 9:20 CLB P8A0226 Total Kjeldahl Nitrogen s0000 mg/kg dry 6200 1100 20 '361.2 1122 IS 10:49 CLB P8A0239 Microbiological Parameters Fecal Coliforms 0.6 MPN/g dry 0.2 1 'SM9221 E 1116119 14:07 EGC P8A0222 TCLP Extraction by EPA 1311 TCLP Extraction Complete N/A 1 '1311 1/24118 8:30 JAB P8A0331 TCLP Extraction Complete N/A 1 '1311 ZHE 1/26118 900 ANC PSA0378 TCLP Metals Mercury BRL mg/L 0.010 0.000030 1 '7470A 1/24118 1629 JAB PBA0344 Arsenic 0.22 mg/L 0.060 0.016 1 '601013 1/26/18 13:21 JAB PSA0399 Barium 22 mg/L 6.0 0.0040 1 '6010D 1/26/18 13:21 JAB PSA0399 Cadmium 0.081 mg/L 0.026 0.00076 1 '6010D 1/26/18 13:21 JAB PSA0399 Chromium 2.2 mg/L 0.26 0.0018 1 '6010D 1126/18 13:21 JAB PSA0399 Lead BRL mg/L 0.050 0.0040 1 '6010D 1/26118 18:52 JAB PSA0399 Selenium 0.42 mg/L 0.10 0.028 1 '6010D 1126118 13:21 JAB PSA0399 Silver BRL mg/L 0.25 0.0020 1 '6010D 1/26118 1852 JAB PBA0399 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mg/L 0.0025 0.00086 1 '8081B 1/29118 18:41 JMC PBA0353 Dieldnn BRL mg/L 0.00050 0.000070 1 '8081B 1/29/18 18:41 JMC PBA0353 Endnn BRL mg/L 0.00050 0.000075 1 '8081B 1/29/18 18:41 JMC PSA0353 gamma-BHC BRL mg/L 0.00050 0.000065 1 '8081B 1129/18 18:41 JMC PSA0353 Heptachlor BRLCCV mg/L 0.00050 0.000085 1 '8081B 1/29/18 18:41 JMC PSA0353 Heptachlor Epoxide BRL mg/L 0.00050 0.000065 1 '8081B 1/29118 18:41 JMC PSA0353 Methoxychlor BRLCCV mg/L 0.00050 0.00020 1 '8081B 1/29/18 18:41 JMC P8A0353 Toxaphene BRL mg/L 0.025 0.00037 1 '8081B 1129/18 18:41 JMC PBA0353 Surrogate Recovery Control Limits Decachiorobiphanyl 29 % 13-186 Tetmchloro-m-xylene 25 % 40-134 SE TCLP Semivolatile Organic Compounds by GC/MS 2,4,5-Tnchlorophenol BRL mg/L 0.25 0.0016 1 '8270D 1/29118 19:26 JMV PSA0411 2,4,6-Tnchlorophenol BRL mg/L 0.10 0.0018 1 '8270D 1/29118 19:26 JMV PSA0411 2,4-Dinitrotoluene BRL mg/L 0.050 0.0014 1 '8270D 1/29118 19:26 JMV P8A0411 2-Methylphenol BRL mg/L 0.050 0.0018 1 '8270D 1/29118 19:26 JMV PBA0411 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 704/5296364-Toll Free Number: 11-800/529-6364- Fax: 704/626-0409 Page 4 of 17 Laboratory Report PRISM Fun -service Anaqutio s 01/07I2019 ' Environmental Solutions uaw�x,ni[S �'c Town of Mooresville/RR WVVTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 8010222-01 P. O. Box 878 Prism Work Order: 8010222 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 01/16/18 08:30 Time Submitted: 01/16/18 12:55 Parameter Result Units Report MDL Limit Dilution Factor Method Analysis Analyst Date/Time Batch ID 3/4-Methylphenol BRL mg/L 0.050 0.0015 1 '8270D 1/29118 19:26 JMV PBA0411 Hexachlorobenzene BRL mg/L 0.050 0.0013 1 '8270D 1/29118 19:26 JMV P8A0411 Hexachlorobutadiene BRL mg/L 0.050 0.0021 1 '8270D 1129118 19:26 JMV P8A0411 Hexachlorcethane BRL mg/L 0.050 0.0017 1 '8270D 1129118 19:26 JMV P8A0411 Nitrobenzene BRL mg/L 0.050 0.0026 1 '8270D 1129118 19:26 JMV P8A0411 Pentachlorophenol BRL mg/L 0.25 0.0012 1 '8270D 1/29118 19:26 JMV P8A0411 Pyridine BRL mg/L 0.25 0.0010 1 '82701) 1/29118 19:26 JMV P8A0411 Surrogate Recovery Control Limits 2,4,6-Tdbromophencl 44 % 43-140 2-Fluorobiphenyl 44 % 44-119 2-Fluorophenol 42 % 19-119 Nitrobenzene -CS 41 % 44-120 SE Phenol-ds 30 % 11-52 Terphenyl-114 44 % 50-134 SE TCLP Volatile Organic Compounds by GC/MS 1,1-Dichloroethylene BRL mg/L 0.035 0.00083 1 '8260B 1/27118 2:16 KDM P8A0420 1,2-Dichloroemane BRL mg/L 0.025 0.00066 1 '8260B 1/27118 2:15 KDM P8A0420 1,4-Dichlorobenzene BRL mg/L 0.38 0.00050 1 '8260B 1/27/18 2:15 KDM P8A0420 Benzene BRL mg/L 0.025 0.00048 1 '8260B 1127/18 215 KDM P8A0420 Carbon Tetrachloride BRL mg/L 0.025 0.0011 1 '8260B 1127/18 2:15 KDM P8A0420 Chlorobenzene BRL mg/L 5.0 0.00062 1 '8260B 1/27/18 2:15 KDM P8A0420 Chloroform BRL mg/L 0.30 0.00076 1 '8260B 1/27/18 2:15 KDM P8A0420 Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.0024 1 '82608 1/27118 2'15 KOM P8A0420 Tetrachlomethylene BRL mg/L 0.035 0.00098 1 '8260B 1127118 2:15 KDM PSA0420 Trichloroethylene BRL mg/L 0.025 0.00078 1 '8260B 1/27/13 2:15 KDM PBA0420 Vinyl chloride BRL mg/L 0.020 0.00097 1 '8260B 1/27118 2:15 KDM P8A0420 Surrogate Recovery Control Limits 4-Bromofluorobenzene 95 % 80-124 Dibromofluoromethane 98 % 75-129 Toluene-d8 95 % 77-123 Total Metals Calcium 130 BR, B mg/L 0.10 0.010 1 '6010D 1/26/18 17:27 JAB PSA0266 Magnesium 60 mg/L 0.10 0.0086 1 '6010D 1123118 12:09 JAB PSA0266 Sodium 120 B mg/L 50 1.8 100 '6010D 1123/18 12:02 JAB PSA0266 Aluminum 9100 mg/kg dry 2.6 0.76 1 '6010D 1126118 0:08 JAB P8A0396 Mercury 0.26 mg/kg dry 0.067 0.0054 3 '74710 1129118 14:10 JAB P8A0418 SAR Soil Preparation Complete g 1 '2-78-054 1119118 9:20 JAB P8A0238 SAR Percent Moisture Complete %by 0.100 0.100 1 -2-78-054 1/2311815:20 JAB PBA0333 Weight Arsenic 1.2 mgrkg dry 0.26 0.032 1 '60101) 1126/18 13:21 JAB P8A0395 Sodium Absorption Ratio 2.2 [blank) 0.30 0.016 1 -2.78-064 1126/18 16:69 JAB PBA0256 Cadmium 0.41 marks dry 0.26 0.0069 1 '6010D 1126/18 0:08 JAB PSA0395 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/626-0409 Page 5 of 17 &P-IR I S ni[a iMC M Full -Service Analytical a Environmental Solutions uew�ro Town of Mooresville/RR WWTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Laboratory Report 01/07/2019 Project: Class A Dried Sludge Client Sample ID: Class A Prism Sample ID: 8010222-01 Prism Work Order: 8010222 Sample Matrix: Solid Time Collected: 01/16/18 08:30 Time Submitted: 01/16/18 12:55 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Calcium 9700 mg/kg dry 10 0.24 1 '6010D 1126118 0:08 JAB P8A0395 Chromium 11 mg/kg dry 0.26 0.043 1 '6010D 1126118 0:08 JAB P8A0395 Copper 160 mg/kg dry 62 4.7 100 '6010D 1126118 15:22 JAB PSA0395 Lead 6.8 mg/kg dry 0.26 0.048 1 '6010D 1126118 0:08 JAB PBA0395 Magnesium 1800 ni dry 2.6 0.24 1 '6010D 1126118 0:08 JAB PSA0396 Molybdenum 5.9 mg/kg dry 0.52 0.015 1 *60100 1126118 0:08 JAB P8A0395 Nickel 8.7 mg/kg dry 0.52 0.019 1 '6010D 1/26/18 0:08 JAB P8A0396 Potassium 2700 mglkg dry 1300 47 100 -6010D 1126118 15:22 JAB P8A0395 Selenium 2.4 ni dry 0.52 0.12 1 '6010D 1126118 0:08 JAB PBA0396 Sodium 990 mg/kg dry 16 0.51 1 '6010D 1/26118 0:08 JAB P8A0395 Zinc 360 mg/kg dry 260 9.3 100 '6010D 1/26118 16:22 JAB PBA0395 This report should not be reproduced except in its entirety, without the written consent of Pnsm Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529E364-Toll Free Number: 1-80016296364-Fax: 7041626-0409 Page 6 of 17 Sample Extraction Data Prep Method: 351.2 I Lab Number Batch Initial Final Date/Time 8010222-01 P8A0239 0.05 g 25 mL 01/18/18 10:00 1 Prep Method: SM4500-NH3 B Lab Number Batch Initial Final Date/Time 8010222-01 P8A0246 1.09 g 50 mL 01/18/18 12:00 Prep Method: SM4500-PB5 ,+ Lab Number Batch Initial Final Date/Time 8010222-01 P8A0225 1 g 50 mL 01/18/18 7:08 Prep Method: Solids, Dry Weight Lab Number Batch Initial Final Date/Time 8010222-01 P8A0320 30 g 30 g 01/22/18 14:16 Prep Method: 1311 Lab Number Batch Initial Final Date/Time 8010222-01 P8A0331 100 g 2000 mL 01/23/18 14:08 8010222-01 P8A0378 12.5 g 250 mL 01/25/18 15:45 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 8010222-01 P8A0399 10 mL 50 mL 01/26/18 10:20 8010222-01 P8A0399 10 mL 50 mL 01/26/18 10:20 Prep Method:7470A Lab Number Batch Initial Final Date/Time 8010222-01 P8A0344 20 mL 30 mL 01/24/18 10:10 Prep Method: 3510C GC Lab Number Batch Initial Final Date/Time 8010222-01 P8A0353 200 mL 10 mL 01/25/18 11:00 Prep Method: 3510C MS Lab Number Batch Initial Final Date/Time 8010222-01 P8A0411 200 mL 1 mL 01/29/18 11:30 Prep Method: 5030E J Lab Number Batch Initial Final Date/Time 8010222-01 P8A0420 1 mL 10 mL 01/26/18 11:46 ` Prep Method: 3010A Lab Number Batch Initial Final Date/Time 8010222-01 P8A0256 50 mL 50 mL 01/19/18 9:20 `- 8010222-01 P8A0256 50 mL 50 mL 01/19/18 9:20 8010222-01 P8A0256 50 mL 50 mL 01/19/18 9:20 8010222-01 P8A0256 50 mL 50 mL 01/19/18 9:20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/525-0409 Page 7 of 17 Sample Extraction Data Prep Method: 3050B Lab Number Batch Initial Final Date/Time -, 8010222-01 P8A0395 1.99 g 50 mL 01/23/18 9:40 8010222-01 P8A0395 1.99 g 50 mL 01/23/18 9:40 8010222-01 P8A0395 1.99 g 50 mL 01/23/18 9:40 Prep Method: 7471E Lab Number Batch Initial Final Date/Time 8010222-01 P8A0418 0.65 g 50 mL 01/29/18 11:42 Prep Method: SAR 2-78-054 Lab Number Batch Initial Final Date/Time 8010222-01 P8A0238 250 g 250 g 01/18/18 9:20 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Number Analysis 8010222-01 Herbicides TCLP (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/629-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/52"409 Page 8 of 17 P R I S M Full -Service Anaiytica Environmental Solutic:: . ' ItC'IKA-�MlCi. dlC ::9 SPringhmok Road- Charlotte, NC 28247 "'1,vo 7041529-6004 - Fax: 7ONS25-0409 Client Company Name: 0 OA'!6'N�it Report TD/Contact Name: Whikinilliq t4rll(trt. Reporting Address: lf,D. A i1 Na- 2$11 Phone: "L:P6-3 Fax (Yes)(No): Email Address: EDD Type: PDF ✓Excei_Other Site Location Name: Site Location Physical Address: TIME I MATRIX CLIENT GATE COLLECTED (SOIL, SAMPLE DESCRIPTION COLLECTED MILITARY WATER OR HOURS SLWOE) I Iln i$ I nq: 30 1 Soll Sampler's Signature.- �0.-1-�•NJ'^r"��er—� SamF Upon relinquishing, this Chain 6f4usindy Is your authorizalb submitted In writing to the Prism Project Manager. There will CHAIN 1 OF CUSTODY RECORD PAGE-1 OF �oDUTc a TO O(nn UM 11OPM/erLL`lN`a� 1� Project Name: 04.4 A- �I A J I HdLaL � Short Hold Analysis: -es (No) - UST Project: EQ ((� -Please ATTACH any project specific reporting (OC LEV�1 gl IV) provisions and/or OC Requirements Invoice To: d AA, 1V /V�OprC6NIIR, Address: Purchase Order No./Billing Reference Renuesled Due Date 01 Day ❑ 2 Days 08 Days 04 Days ❑ 5 Dar "Working Days" ❑ 6-9 Days,;V(.d.Id 10 days 0 Rush Wo&. Must Be roved Samples received after 14:00 will be processed next business day. Turnaround time is based on business days, excluding weekends and holidays. (SEE REVERSE FOR TERMS A CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES. INC. TO CLIENT) SAMPLE CONTAINER 'TYPE I ND. SRS SEE BELOW for Prism to proceed with charges for Changes MTV; enMU BY( ") ayF/rd�Pmm UaorM9n� PRESERVA- TIVES Somoles INTACT upan am -mil Ronrvod ON WET!CE° PROPER PRESERVATIVES nw,Cated i Received WITHIN HOLDING r!kES? CUSTODY SEALS INTACT' VOLATILES roc l yviou'r HEADSPACE? PROPER CONTAINERS need': TEMP. Ire"ID In. / QQZs ived n a NO Ol e) W 0_ "Ce Con Ll,<1' TO BE RILLED IN BY CLIENTISAMPLING PERSONNEL Certification: NELAC_ DoD_ FL_ NC SC_ OTHER NIA Water CNorinated: YES_ NO Sample Toed Upon Collection: YES ✓O_ as requested above. Any changes must be s have been initialized. /nl PRISM REMARKS LAB ID NO. f6 Additional Comme is: *�N wl�thv IDr/1 TY�e�M;�ds $21p 01h.27-o SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST CDC UNTIL RECEIVED AT THE LABORATORY. P Fog, D UPS O Hw"elbemd mm FiW Se. ❑ Dire, NODES: UST. G O NDWATER: DRINKING WATER : II``SOLID WASTE: 1 ORCRA: CERCLA LANDFILL OTHER: ❑NCOSC ONC 0SC ONC ❑SC El NC OSC TUC ❑SC i ONCOSC ANC OSC 000 NC OSC 0NC OSC a o o a *CONTAINER TYPE CODES: A= Amber C = Clear G= Glass P = Plastic; TL = Teton -Lined Cap VOA = Volahle Organics Analysis (Zero Head Space) PRISM 1 Full -Service Analytical 8 Environmental Solutions .ii3O.11cs. etc 449 Springbrook Road • Charlene, INC 28217 Phone 7041529-6364 Fax 704/S25-0409 Client Company Name: Report TolContaot Name: Reporting Address: a• a cl "a nl Ni CHAIN OF CUSTODY RECORD Nee OF Z QO a TO er01111e PIUMM 2"L _-- Project Name: AYS IT 29M oi' tr Short Hold Analysis: es (1 UST Pro a '(Yes) O `Please ATTACH any pr6jWspeclflc reporting (QK LEVEIQI DI provisions and/or 2-Cr-Requlremente� �� y Invoice To: IDDWL, u�- �APR�d'eLs�i Address: Samples INTACT upon amr ail / Receiver. ON WE'" ICE? /. PROPER ?RESERVATI4'ES mdicaled' Receives WITHIN HOLDING TIrdES? - CI)STODISLALG INTACT? VOLAT ILES rec'd P110011ico73aACE'1 PROPER;LCId TTAII IEf: Phone: %04-10(A-318110' Fax (Yes (No): Purchase Order NoJBilling Reference ITO Email Address: '� Requested Due Date O 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days O 5 Days EDD Type: FIDE Excel Other "working Days" Cl 6-9 Days Cl Standard 10 days O Rush Work Be Site Location Name: Samples received after 14:00 will be processed next business day. Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. (SEE REVERSE FOR TERMS a CONDITIONS REGARDING SERVICES BE FILLED IN BY CLIENT/SAMPLING PERSONNEL CertiflwtiOn: NELAC DOD_ FL NC-4f" Sic OTHER NIA Water Chlorinated: YES_ NO ✓ RENDERED BY PRISM LABOMTORIES, INC. TO CLIENT) Sample Iced Upon Collection: YES O CLIENT SAMPLE DESCRIPTION DATE COLLECTED TIME COLLECTED MILITARY HOURS MATRIX (SOIL, WATER OR SLUDGE) SAMPLE CONTAINER PRESERVA- TIVES AW4LYSM REQUESTED p, T`�to / Q.%i,Dll�� % IA REMARKS / I7`, i PRISM U18 No. ITYpE SEE BELOW _ NO. S� Chic fE i I Sampler's Signature( Sampled ��- Sartpled By (Print Name)r\ Affiliation IONu`" Upon relinquishing, this Chain o stody is your authorization for Prism to proceed with the analyses Be requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges foFanyghanges after analyses have been initialized. or yl re ecovod y.('gamvr¢i Additional Comments: ! 3"AinA l5i is rbky • Rexeli y ( rumrel r Silo Departure Tema: /T.. tli l:ti l'�A —I y. - ar ism atroexarlx`y; / �/ y (� � � ( ( pjL)� /f�� Field iecn Fee' -. ice» /-'- - % / /J f�:.!-�� /�rw l�D !r1l : ALL SAMPLE COOLERS SHOULD BE TAPED SHUT UST SEALS FOR RANSPORTATION TO THE LABORATORY. ( ) "SAMPLESARE NOTACCEPTEDAND VERIFIED AGAINST CDC UNTIL RECEIVEDAT THE LABORATORY. _ gfadblO UPS ❑HaM4ii1 eied "+m Red Servke OONer Lt ��n/T��— NPDES: UST: GROUNDWATER: DRINKING WATER: SOLID WASTE: RCRA: CERCLA LANDFILL OTHER: O NC O SC ❑ NC El SC I O❑ NC ❑ SC NC O SC C O SC O❑ NC O SC 13 NC ❑ SID NC ❑ SC O❑ NC O SC ❑O 'A❑ *CONTAINER TYPE CODES: A =Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) Main Office: 449 Springbrook Road PRISM En EnvirServiconmental AnalyticalandP.O. Boi, 40543 NC28 i En vi ron montal Solutions Charlotte, NC 28224-0543 �= s++••+•cne.+� Phone: 7041529-6364 1/800152"364 Fax: 7041525-0409 w .prismlabs.com Sodium Absorption Ratio The amount of exchangeable sodium ions versus the amount of exchangeable calcium & magnesium ions in a given material. Sample Numberl 8010222 1 Sample Name I Class A Na: Sodium (mg/L) Equivalent weight: 23 Ca: Calcium (mg/L) Equivalent weight: 20 Mg : Magnesium (mg/L) Equivalent weight: 12 Milli Equivalent (ME) = mg/L / Equivalent weight Nam !L Cam IL M m /L 120.0 130.0 60.0 Na (ME) Ca (ME l Ma (MEI 1 5.00 5.22 1 6.50 SAR= Na Milli Equivalent([0.5 X (Ca Milli Equivalent + Mg Milli equivalent)]0.5 power SAR = 2.2 (From mg/L entered above) Page 11 of 17 Main Offlce: Full Satvieu Analytical and 449 Springbrook Road "PRISM Environrnowal Solutions P.O. Box 240543 _ mwirw< Charlotte; NC 28224-0543 Phone: 7041529-6364 118001529-6364 Fax: 7041525-0409 www.prismiabs.com Plant Available Nitrogen Sample Number 8010222 1 Sample Namel Class A Mineralization Rate TKN NH3 NOX mglkg ma/kg ma/kta 0.3 50000 1900 5.6 PAN 15,000 'mgtkg Calculated By.-�__ i MR(TKN-NH3)+ 0.5(NH3)+NOX = PAN mg/kg Page 12 of 17 ACCEs,$ ANALY11CAL, INC. ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte NC 282240543 ATTENTION Terri W. Cole PROJECTID 8010222 LABORATORY REPORT NUMBER 1801F47 DATE January 30, 2018 Prhnary Data Review By Secondary Data Review By Ashley Amick Chris Pafford Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com 1J11ty.F7 o8:D] Ion Unless otherrrbe noted, all analysis an this report performed at Analytical EavironmeotoI Services Inc. (AES TUC), 3090 Presidcofial Drive, At Issue, GA 30340. AES is SCDHEC certified laboratory 8 98016, NCDENR certified tab 8 562, GA cer ified lob 0 PL-E87582, NELAP certified laboratory 8 E87582 AIHA-LAP,LLC Laboratory ID: 1 011671 For Industrial Hygiene samples (Organics, Metab, PCM Asbestos, Gravimetric), Environmental Lead (Point, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Fee ruination. Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SCINCIGA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 993.315.4243 Page 1 of 5 Page 13 of 17 ::::�TM6\:: a........� 'v �:.,...a.:: ::-::.>:ao..-:::....v :>s::IDw:.:::.:r'.u>:v::; �.r:: t?s>:c.,5ori:.]s:;.p:: :: r..:4s: ..r;.c.:::.•.p;.2.:.}s:•r_a _v:::a ea.•S':\^ilw�c u.:;vmx:.:f: Ajis. �jIfull-Servbe Analytical & V' Environmental Solutions IaCIFzj-q SUBCONTRACT ORDER ICaVNELAC= USAGEPrism Laboratories, Ine SC Other 8010222 SENDING LABORATORY: RECEIVING LABORATORY: Prism Laboratories, Inc. Analytical Environmental Services, Inc. P. O. Box 240543 3080 Presidential Parkway Charlotte, NC 28224-0543 Adants, GA 30340 Phone: 800-529-6364 Phone:(770)457.8177 Fax: 704-525-0409 Fax: NA Project Managor. Terri W. Cole Analysis Due Expires Laboratory Comments m: 9010222-01 Solid Sae,pted:01116/18 08:30 Herbicides T(9P (Sub) O1/23/19 08:30 r1 Relca:;cd By Date Received By Date Page I of 1 Page 2 or 5 Page 14 of 17 Analytical Environmental Services, Inc Date: 30-1em18 Client: Prism Laboratories Client Sample ID: CLASS A Lab Order 180047 Tag Number: 8010222-01 Project Name: 8010222 Collection Date: 1/16/2019 8:30:00 AM Lab ID: 190IF47-OOIA Matrix: Solid Analyses Result Quit MDL Reporting Batches) DF Date Anslysed Analyst UnitUnits HERBICIDBS,TCLP SW1311/9151A (SW3510C) 2,4,5-7P(Silvex) BRL 0.030 020 mg/L 254629 1 01/1W10181854 Ei 2.4-D BRL 0.051 020 ma�L. 254629 1 0112*201918:54 EI Sum. DCAA 76.4 0 50.4-133 %REC 254629 1 DI/2W201818:54 El Qu.lifen. a %W.-w ,s... wnnmi..n k,<I BHL NUD.WmN L H Hdd,., limn for gepnYw anrnlTY v k N Analym ml VELAC cerlifid B Melp+e dnu.ed in N. ue.ei.M m.IM1od bbnk E �iaukd nitro eb.le punlinli<n 'n S SpikeR Q,M<vuidc@nin du. I. mane > GmunlunR 01-Im 1 Enimaee-due dunned below Re ,<ine Limb c LW Ibn R.wk.1. Page 3 of 5 Page 15 0( 17 Clear 0Iv mcm IASgft%lcE5,tu.. SAMPLE/COOLER RECEIPT CHECKLIST AGS �SsrtzcGs.lxc. L cbent Name: Access Analytical, Inc. AES Work Order Number: 280IF47 2. Carrier: FedExff] UPS❑ LISPS❑ Client❑ Courler❑ Othei ., ,a nereu• Comments 3. J. 5. 6. 7. 8. 9. 10. 1L 1 Save as 2 Shipping container/moler received in good condition? nodamaged El leaking Elr❑ othe Custody seals present on shipping container? Custody seals intact on shipping container? Temperature blanks present? Cooler temperature(s) within limits of 0$0 [See item 13 and 14 for O ® O Cooling initiated for recently collected samples/ice temperature recordings] present ❑ Chain of Custody (CAC) present? Chain of Custody signed,dated, and timed when relinquished and received? Sampler name and/or signature on COC? •' Were all samples received within holding time? TAT marked on the COC7 • If no TAT Intlicamd, proceeded with standard TAT pef Terms & Condidons. 13. Cooleri Temperaterel.7 14. Couler5 Temperature 15 Comments: 16. 17. is. 19. 24 tl. 22. 23. 24. 25. 26. DC Cooler 2 Temperature °C Cooler 3 Temperature °C Cooler 4 Temperature °C °C Cooler 6 Temperature °C Cooler 7 Temperature °C CoolerflTemperatpre °C I certify that I have completed sections 1-15 (dated initial4 TO 1/22/18 ..rr Comments Were sample containers Intact upon receipt? Custody seals present an sample conainers? Custody seals intact on sample containers? Do sample container labels match the COC? ®i © © Incompleteinfo 0 illegible no label ❑ other ❑ Are analyses requested indicated on the CDC? Were all of the samples listed on the CDC received? Q O O samples received but not ot received COC samples listed On ADC not recelVltl Cl Was the sample collection date/time noted? Did we receive sufficient sample volume for indicated analyses? Were samples received in a ppropriate containers? Were VOA samples received without headspace (c 1/4" bubble)? Were trip blanks submitted? • listed on COC ❑ not listed an COC ❑ 27. Comments: This sachon only applies to samples where pH can be Icertify that I have completed sections 16-27 (dated initials). cheU.ed at Sample Receipt. Yes No N/A Details Comments 28. 29. 30 Was pH adjusted at Sample Receipt? Nale: Certain analyses require chemical preservationth but must be checked in e labomlory and not upon Semple R•cept such as Cadorms. VOCs and Oil a Grease/rPH. I certify that I have completed sections 28-30 (dated initials). Checklist 6.9.17 Rev 2 '�Lockpd. guidelines? ."time TR 1/22118 Haveical preservation been checked? Connivercontainerss meet preservation chem TR 1/22/19 Page 4 of 5 13. Cooleri Temperaterel.7 14. Couler5 Temperature 15 Comments: 16. 17. is. 19. 24 tl. 22. 23. 24. 25. 26. DC Cooler 2 Temperature °C Cooler 3 Temperature °C Cooler 4 Temperature °C °C Cooler 6 Temperature °C Cooler 7 Temperature °C CoolerflTemperatpre °C I certify that I have completed sections 1-15 (dated initial4 TO 1/22/18 ..rr Comments Were sample containers Intact upon receipt? Custody seals present an sample conainers? Custody seals intact on sample containers? Do sample container labels match the COC? ®i © © Incompleteinfo 0 illegible no label ❑ other ❑ Are analyses requested indicated on the CDC? Were all of the samples listed on the CDC received? Q O O samples received but not ot received COC samples listed On ADC not recelVltl Cl Was the sample collection date/time noted? Did we receive sufficient sample volume for indicated analyses? Were samples received in a ppropriate containers? Were VOA samples received without headspace (c 1/4" bubble)? Were trip blanks submitted? • listed on COC ❑ not listed an COC ❑ 27. Comments: This sachon only applies to samples where pH can be Icertify that I have completed sections 16-27 (dated initials). cheU.ed at Sample Receipt. Yes No N/A Details Comments 28. 29. 30 Was pH adjusted at Sample Receipt? Nale: Certain analyses require chemical preservationth but must be checked in e labomlory and not upon Semple R•cept such as Cadorms. VOCs and Oil a Grease/rPH. I certify that I have completed sections 28-30 (dated initials). Checklist 6.9.17 Rev 2 '�Lockpd. guidelines? ."time TR 1/22118 Haveical preservation been checked? Connivercontainerss meet preservation chem TR 1/22/19 Page 4 of 5 27. Comments: This sachon only applies to samples where pH can be Icertify that I have completed sections 16-27 (dated initials). cheU.ed at Sample Receipt. Yes No N/A Details Comments 28. 29. 30 Was pH adjusted at Sample Receipt? Nale: Certain analyses require chemical preservationth but must be checked in e labomlory and not upon Semple R•cept such as Cadorms. VOCs and Oil a Grease/rPH. I certify that I have completed sections 28-30 (dated initials). Checklist 6.9.17 Rev 2 '�Lockpd. guidelines? ."time TR 1/22118 Haveical preservation been checked? Connivercontainerss meet preservation chem TR 1/22/19 Page 4 of 5 TR 1/22/19 Page 4 of 5 n g 10 9 a6ed O n auawmaup Y!M aD!sea 4a"e+aYa+ld9 S Vwil BvewEaY w��#Y ?Oaw maM A!u!IM�e Odl Y PTA^JY19A Ao elY°Y H liii•r�.Lny°6iY n`°W Pua�ap an�m Nn��na3 (P Ppe®w{Im:o wnaNadM wulfm,VNH A (afuu �anv!Wsa^^T^la^)Pb�?4 8 vw��8u�wda. nwla0 NA L a ieR9 pwPm Pa�vawaq uPamaaOWAV a �NN^mtl uwy.el new iliva4 ue�imm�p xuuf^U s£1 4'05 L-Z8 0005'0 0 PE14'0 vvJO wnS 8£1 Sb4 916 OOOS'O OZ'O 1884'0 (1-b'Z SZI Z'84 6'9L 0005'0 OZ'O 448£'0 (x'^I!S) dL-5`4`Z IeOa 1!mT QdN Qd21% leAdaii (Id11 1!M!T 4EE!TI 1!w!T ^sO7 39)1% flA3a2T NdS a^leA NdS 7!m!'1.LdN 7lus22l a7LIoW 91SZ66L :ON bOS STOZ/6UI0 :*P(Is!SLIeOv 6Z9P9Z:47go1ee vlslvllflM a Lv molavaH :apooml SA .ad•(I.aldumS Z6819£ :ON°n11 810Z/SZIIO :awa dwj '1/8w :sl!ufl :cu luallo swv100-S4d1081 :(ualdumS ££1 4'05 66L 0005'0 0 L66£'0 WJQ AMS 6Z1 6'05 618 0005'0 OZ'O £60VO Q-4'Z 611 1'64 l'ZL OOOS'0 (EVE) E09S0 (�a•4!S),IJ.-5`4`Z lend 7!®T (Idu Qd11% TOAdaN Ga I!w!T Ift 1!WI fto l D311% TOMON MIS =Ph XIS 1!MIT JAN JIM211 21AT v OTSZ66L :ON baS BTOZ/6vlo :a1SQS!Sa(flav 6Z9KZ:(IIgO1eE vlslwvnas d'lal'$aHIJMaail WOOMI SJT :od,(laldums Z6919£ :ONOOTI 810Z/6Z/IO :2p(l dald TEEM :s7M11 :Ql luagD 6Z9KZ-SJ'I :(]I0ldums EEI 4'OS 6'6L 0009'0 0 E66£'0 vvJQ wns OZ'O Tee a-V z OZ'O TNe (-AI!S) lend 1!urtT cl" (an% IeA3a1I G" I!M!T gSIH 3!"'I MOT Dail% IBAl21l )[CIS MIUA NdS gw!T I" 1lnsay avlUoy Usz66L :ox baS BTOZ/6Z/TO :ONG SIs.Geuv 6Z9KZ:Glgolee vlslvurims amu'samalauaH :9PODMI N'1eiN .WAjolduleS Z6819£ :ON urra 810Z/SU10 mea dwd TEEM :S)Mn w(Il 3uallD 6Z96SZ-Q11I :(lioldumS 6Z94SZ :UT93le8 .LHOJHH AHVNWfIS 30 r[VJLLArIVW Lod 1081 :uap.loyjo,L{ ZZZOIOg :—Voj laa(o.ld sg.uolwogwI wild auall:} 8I-WPO£ Mgo alll'MIAAaS Ie;vamvoalAuN leay,Tleuy PRISM rAEOMroalE9,114G Full -Service Analytical 8 Environmental Solutions Town of Mooresville/RR WWTP Whitney Munroe P. O. Box 878 Mooresville, NC 28115 NC Certification No. 402 NC Drinking Water Gen No. 37735 SC Certification No. 99012 Project: Class A Dried Sludge Lab Submittal Date: 04/30/2018 Prism Work Order: 8040569 Case Narrative 05/23/2018 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: This is a Revised Report and supercedes the original laboratory report dated 05/18/2018. Correction made to units on PAN calculation sheet. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. 0, , � 1- 0 M ft ME � Terri W. Cole Project Manager Data Qualifiers Key Reference SE Surrogate recovery outside the CC limits due to emulsion. BRL Below Reporting Limit MDL Method Detection Limit PD Relative Percent Difference Reviewed By Terri W. Cole Project Manager Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the wntten consent of Prism Laboratories, Inc. 449 Spnngbrook Road - P.O. Box 240643 - Charlotte, NC 20224-0643 Phone: 704/529.6364-Toll Free Number: 1-8001529-6364 - Fax: 7041525.0409 Page 1 of 16 .H ,& R I S M I FuO s.raoo AnalyticalAnalyticalAnalyticala �4 a9u -aflmarlt&ISolution& Sample Receipt Summary 05/23/2018 Prism Work Order: 8040569 ^lient Sample ID Lab Sample ID Matrix Date Sampled Date Received Class A 8040569-01 Solid 04/30/18 04/30/18 Samples were received in good Condition at 2.0 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0549 Phone: 7641629-6384-Toll Free Number: l-0O01529-6364-Fax: 7041525-WO Page 2 of 16 ~ ISM /� Fus-service Analytical a I J M Environmental Solutions ,..murw,u u,o Laboratory Report 05/23/2018 Town of Mooresville/RR W WTP Project: Class A Dried Sludge Client Sample ID: Class A tttn: Whitney Munroe Prism Sample ID: 8040569-01 P. O. Box 878 Prism Work Order: 8040569 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 04/30/18 08:00 Time Submitted: 04/30/18 12:19 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters Plant Available Nitrogen 9700 mglkg dry 1500 330 20 'Calculation 5/9118 9:11 CLB [CALCI %Solids 97.7 %by 0.100 0.100 1 'SM2640 G 4130/18 14:55 TJV PBE0002 Weight Ammonia as N 220 rr lkg dry 9.5 2.4 1 'SM4500.NH3 C SMMS 14:08 BMS POED162 Nitrate/Nitma as N BRL mglkg dry 5.1 1.4 1 'SM4500-NO3 F 5/9118 911 CLB P8E0174 PH 6.4 pH Units 1 '9045D 511/18 16:35 CBP P8E0035 Phosphorus -Total 12000 mglkg dry 260 37 100 'SM4600-P F starts 10:31 CLB PSE0084 Total Kjeldahl Nitrogen 32000 mglkg dry 5100 1100 20 '351.2 514118 8:21 CLB PBE0071 Microbiological Parameters Fecal Coliforms BRL MPN/g dry 0.2 1 'SM9221 E 4/30/18 13 00 BMS P8E0024 TCLP Extraction by EPA 1311 TCLP Extraction Complete WA 1 '1311 5/8118 720 MMR PBE0134 TCLP Extrri Complete WA 1 '1311 ZHE 5/15/18 9:00 ANG P8E0322 TCLP Metals -4ercury BRL mgA 0.010 0.000030 1 '7470A 5/10118 11.26 JAB P8E0192 genic BRL mg/L 0.10 0.016 1 '6010D W9118 17:11 JAB PSE0148 Barium BRL mg/L 5.0 0.0040 1 '6010D 5/9/18 17:11 JAB PBE0148 Cadmium BRL mg/L 0.025 0.00075 1 '6010D SM118 1711 JAB PBED148 Chromium BRL mg/L 0.25 0.0018 1 '601DD R9/18 1711 JAB PBED148 Lead BRL mg/L 0,050 0.0040 1 '6010D 5/9/18 17:11 JAB P8E0148 Selenium BRL mg/L 0.10 0,028 1 '6010D 5/9118 1711 JAB PSE0148 Silver BRL mg/L 0.25 0.0020 1 '6010D 5/9/18 17:11 JAB PBE0148 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mg& 0.0025 0,00086 1 18081B 5110118 2214 JMV P8E0139 Dieldrin BRL mg/L 0,00050 0.000070 1 '80818 5/10118 22:14 JMV P8E0139 Endrin BRL mg/L 0.00050 0.000075 1 '8081B 5/10/18 2214 JMV PBE0139 gamma-BHC BRL mg/L 0.00050 0.000065 1 '8081B 5110118 22:14 JMV P8E0139 Heptachlor BRL mg/L 0.00050 0.000085 1 '8081B 5110/18 22:14 JMV P8E0139 Heptachlor Epoxide BRL mg/L 0.00050 0.000065 1 '8081B 5110/18 22:14 JMV P8E0139 Methoxychlor BRL mg/L 0.D0050 0.00020 1 '8081B 5110/18 22:14 JMV P8E0139 Toxaphene BRL mg/L 0.025 0.00037 1 '8081B 5110/18 22:14 JMV PBE0139 Surrogate Recovery Control Limits Decachlorobiphenyl 221 % 13-186 SE Tetrachloio-m-xylene 164 % 40-134 SE TCLP Semivolatile Organic Compounds by GC/MS 2,4,5-Trichlomphenol BRL mg/L 0.25 0.0016 1 '8270D 5111118 14:32 JMV P8E0208 2,4,6-Trichlorophenol BRL mg/L 0.10 0.0018 1 '8270D 5/11118 14:32 JMV P8ED208 .-Dinerotoluene BRL mg/L 0.050 0.0014 1 '8270D 5111/18 14:32 JMV P8E0208 2-Methyiphenol BRL mg/L 0.050 0.0018 1 '8270D 5/11118 14 32 JMV PBE0208 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-4543 Phone: 704/529.6364-Toll Free Number: l-000/529-6364.Fax:7041525-0409 r Page 3 of 16 Laboratory Report �''] FRM IS I Fun-servme Analytical a /D '7f% 1 Environmental 6uU olone uww.wex ixc 05/23/2018 Town of Mooresville/RR WWiP Project: Class A Dried Sludge Client Sample ID: Class A tttn: Whitney Munroe Prism Sample ID: 8040569-01 P. O. Box 878 Prism Work Order: 8040569 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 04/30/18 08:00 Time Submitted: 04/30/18 12:19 Parameter Result Units Report MDL Limit Dilution Factor Method Analysis Ana"t Dale/Time Batch ID 3/4-Methylphend BRL mg/L 0.050 0.0015 1 '8270D 5/11118 14:32 JMV PSED208 Hexachlorobenzene BRL mg/L 0.050 0.0013 1 '8270D 5/11118 14:32 JMV P8E0208 Hexachlorobutadlene BRL mg/L 0,050 0.0021 1 '8270D 5111/18 14:32 JMV P8E0208 Hexachloroethana BRL mg/L 0.050 0.0017 1 '8270D 5/11118 14:32 JMV P8E0208 Nitrobenzene BRL mg/L 0.050 0.0026 1 '8270D 5111118 14:32 JMV P8E0208 Pamachkxophenol BRL mg/L 0.25 0.0012 1 '8270D 5111118 1432 JMV PSE0208 Pyndine BRL mg/L 0.25 0.0010 1 '8270D 5/11/18 1432 JMV P8E0208 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 29 % 43-140 SE 2-Fluorobiphenyl 29 % 44-119 SE 2-Fluorophenoi 36 % 19-119 Nitrobenzene-d5 30 % 44-120 SE Pherold5 26% 11-52 Terphenyl-dl4 32 % 50-134 SE TCLP Volatile Organic Compounds by GC/MS 1,1-Dichloroethylene BRL mg/L 0.035 0.00083 1 '8260B 5116118 15.07 KDM P8E0333 '-Dichloroethane BRL mg/L 0.025 0.00066 1 '8260B 5116/18 15.07 KDM PSE0333 .A-Dichlorobenzene BRL mg/L 0.38 0.00050 1 '8260B S/18/18 15:07 KDM PBED333 Benzene BRL mg/L 0.025 0,00048 1 '8260B 5116/18 15:07 KDM PBE0333 Carbon Tetrachloride BRL mg/L 0.025 0,0011 1 '82608 SMS/18 1507 KDM PSE0333 Chlorobenzene BRL mg/L 5.0 0,00062 1 '8260B 5116118 15:07 KDM P8E0333 Chloroform BRL mg1- 0.30 0,00076 1 '82608 5/16/18 15:07 KDM PSE0333 Methyl Ethyl Ketone (2-Butenone) BRL mg/L 10 0.0024 1 '8260B 5116/18 15:07 KDM P8E0333 Tetrachloroethylene BRL mg/L 0.035 0,00098 1 '8260B 5116/18 15:07 KDM PSED333 Trichlomethylene BRL mg/L 0.025 0.00078 1 '8260B 5116/18 15'.07 KDM PBE0333 Vinyl chloride BRL mg/L 0.020 0.00097 1 '8260B 5116/18 16.07 KDM P8E0333 Surrogate Recovery Control Limits 4-Bromolluombenzene 99 % 60-124 Dibromolluoromethane 103 % 75-129 Toluall 95 % 77-123 Total Metals Aluminum 15000 mg/kg dry 61 7.6 10 '6010D 61411814:50 JAB PBE0073 Mercury BRL mg/kg dry 0.30 0.029 15 '7471B SR/18 12:56 JAB PBE0114 SAR Soil Preparation Complete 9 1 '2-78-054 5/4/18 11:00 MMR P8E0089 SAR Percent Moisture Complete %by oloo 0.100 1 •2-78-054 6/711810:40 MMR P8E0131 Weight Arsenic 2.0 mg/kg dry 0.51 0.031 1 -60100 513118 14:59 JAB PSE0073 Sodium Absorption Ratio 2.3 [blank] 0.30 0.016 1 '2-78-064 518118 9:48 JAB PBED104 Cadmium 0.42 mglkg dry 0.25 0.0068 1 '6010D 513/18 14:69 JAB PSE0073 'Icium 10000 mg/kg dry 10 0.23 1 '6010D 513/18 14:59 JAB P8E0073 ,alctum, BAR 220 hill 1.0 0.10 10 '6010D 518118 9:48 JAB PSE0104 Chromium 14 mg/kg dry 0.25 0.043 1 '6010D 5/3/18 14:59 JAB PSE0073 This report should not be reproduced, except in its entirely, without the written consent of Pnsm Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 7041629-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/625-0409 Page 4 Df 16 ZRR I S M I Full -Service Analytical s EnvironmentalrviceAAna6olucal & Laboratory Report 05/2312018 Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A lttn: Whitney Munroe Prism Sample ID: 8040569-01 P. O. Box 878 Prism Work Order: 8040569 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 04/30/18 08:00 Time Submitted: 04/30/18 12,19 Parameter Result Units Report MOIL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Copper 180 mg/kg dry 5.1 0.46 10 '6010D 514118 14:50 JAB PSE0073 Lead 7.5 ni dry 0.25 0.047 1 '6010D 5/3118 14:59 JAB PBE0073 Magnesium 2200 mg/kg dry 2.5 0.24 1 -60100 5/3118 14:59 JAB PBE0073 Magnesium, SAR 130 ni 1.0 0,086 10 '6010D 5/8/18 9:48 JAB P8E0104 Molybdenum 7A mg/kg dry 0.51 0.015 1 -60100 513118 14:59 JAB P6E0073 Nickel 10 mi dry 0.51 0.018 1 '6010D 513118 14:59 JAB PBE0073 Potassium 2900 It dry 13 0.46 1 `6010D 513118 14,59 JAB PBE0073 Selenium 3.2 mglkg dry 0.51 0.12 1 '6010D 5/3118 14:59 JAB P8E0073 Sodium 900 mglkg dry 15 0.50 1 '6010D 5/3/18 14:69 JAB P8E0073 Sodium, SAR 170 mglL 5.0 0.18 10 '60100 5/8/18 9:48 JAB PBE0104 Zinc 320 mg/kg dry 25 0.91 10 '60101) 5/4118 14:50 JAB PSE0073 This repot should not be reprod iced except in its entirety, wihout the wrilen consent of Prism Laboratories. Inc. 449 Spnngbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/529-6364-Toll Free Number: l-800/62"364- Fax: 7041525-0409 Page 5 Df 76 Sample Extraction Data 1 Prep Method: 351.2 1 ab Number Batch Initial Final Date/Time .40569-01 P8E0071 0.05 g 25 mL 05103/18 9:00 Prep Method: SM4500-NH3 B Lab Number Batch Initial Final DatelTime 8040569-01 P8E0162 1.08 g 50 mL 05/07/18 10:50 Prep Method: SM4500-PB5 Lab Number Batch Initial Final DateMme 8040569-01 P8E0084 1 g 50 mL 05/08/18 6:15 Prep Method: Solids, Dry Weight Lab Number Batch Initial Final Date/Time 8040569-01 P8E0002 30 g 30 g 04/30/18 14:55 Prep Method: 1311 Lab Number Batch initial Final Date/Time 8040569-01 P8E0322 25 mL 500 mL 05/14/18 14:30 8040569-01 P8E0134 100 g 2000 mL 05/07/18 14:12 Prep Method: 3010A Lab Number Batch Initial Final DatelTime 8040669-01 P8E0148 10 mL 50 mL 05/08/18 8:55 ±p Method: 7470A Lab Number Batch Initial Final DatelTime 8040569-01 P8E0192 20 mL 30 mL 05/09/18 14:00 Prep Method: 3610C GC Lab Number Batch Initial Final DatelTime 8040569-01 P8E0139 200 mL 10 mL 05/08/18 8:45 Prep Method: 3510C MS Lab Number Batch initial Final DatelTime 8040569-01 P8E0208 200 mL 1 mL 05/10/18 8:37 Prep Method: 5030E Lab Number Batch Initial Final DatelTime 8040569-01 P8E0333 1 mL 10 mL 05/15/18 14:04 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 8040569-01 P8E0104 50 mL 50 mL 05/04/18 11:00 8040569-01 P8E0104 50 mL 50 mL 05/04/18 11:00 Prep Method: 3050B ab Number Batch Initial Final DatelTime ..040569-01 P8E0073 2.01 g 50 mL 05/03/18 8:45 8040569-01 P8E0073 2.01 g 50 mL 05/03/18 8:45 This report should not be reproduced, except in Its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 7041629-6364 - Toll Free Number: 1-8001629-6364 - Fax: 7D4/525-0409 Page 6 of 16 Sample Extraction Data Prep Method: 7471B Lab Number Batch Initial Final Date/Time 10569-01 P8E0114 0.61 g 50 mL 05/07/18 8:30 Prep Method: SAR 2-78-054 Lab Number Batch Initial Final Date/Time 8040569-01 P8E0089 250 g 250 g 05/03/18 11:00 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Number Analysis 8040569-01 Herbicides TCLP (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 7041629-6364 • Toll Free Number: 1.800/629-6364 - Fax: 704/525-0409 Page 7 of 16 P R I M I Full -Service Analytical J Envnonmental Solutions u6O 10niES INC 149 Springbrook Road • Charlotte, NC 28217 Phone 7041529.6364 • Fax: 7041525-0409 -1 Client Company Name: 0b.n-e� iter"FiV, Report To/Contact Name: WAt'Zw� Reporting Address: Q Dlxesu>•4.t L a-811� CHAIN OF CUSTODY RECORD PAGE OF At W OTE N TO ENSURE PRYER BILLING, _ .. I _ A .G . A _ I -- Project Name: Short Hold Analysis: *Please ATTACH any I provisions and/or QC Invoice To: Address: (No) UST Project: (Yes( (NI specific reporting (QC LEVEC)II III IV) YE$/ NO Samples INTACT upon arrival?� Received ON WET ICE? PROPER PRESERVATIVES indicated? Recaived WITHIN HOLDING TIMES? CUSTODY SEALS INTACT' VOLATILES reed W/OUT HEADSPACE? _ PROPER CONTAINER$ Wed7 Phone:704-440-524110 Fax (Yes) (No): Purchase Order No./Silling Reterence Email M1►^WYDG{6i U. *, nLUj TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Address: MWe4 Requested Due Date O 1 Day ❑!/pa ys 03 Days ❑ 4 Days ❑ 5 Days Certification: NELAC_ DOD FL_ NC ✓ EDD Type: PDF Excel Other "Working Days" O 6-9 Daysl�slandard 10 days O P e Work Must Be SC OTHER NIA Site Location Name: Samples received after 14:00 von a processed nee business day. Turnaround is business Water Chlorinated: YES V NO_ Site Location Physical Address: time based on days, exduding weekends and holidays. (SEE REVERSE FOR TERMS a CONDITIONS REGARDING SERVICES I., RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sample Iced Upon Collection: YES NO I TIME ! MATRIX SAMPLE CONTAINER ANALYSIS REQUESTED CLIENT DATE ! COLLECTED (SOIL, I PRESERVA. 1L,�, ey �'1� Q � RY SAMPLE DESCRIPTION COLLECTED i MILITAWATER OR `TYPE MQ SEE TIMES evY a �l•,'y� REMARKS HOURS SLUDGE)I SEE BELOW PRISM LAB O to . •• I ! i I V\Ie� I �c b �' Sampler's Signature Sampled By (Print Name) r,cr Affiliation Upon relinquishing, this Chain Is your authorization for Prism to proceed with the analyses as requested above. Any changes must be e submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. .shed By.. (SOnowreN :1 w nnunn aayrhu s Additional Comments: Site Arinal Time: �pD I /$bit R.sn - ( oleo. By: (SLy m) Site Departure 7I1j,., I VyyH� Time. Field Tech Fee' Re (Bgnatu,e) te5matoday By. -ipnon ��L .Ip 0/g.'L�•Q __�� dla0at RAMP COOLERS LD UT WTm F S ATOM TO THE lA190R1170RY. NR A UNTIL SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST COC UNTIL RECENED AT THE LABORATORY. x�) O Fed 6 O UPS O HMNFd livmee darn Fleur Sm O ONm V tf : y^' S / NPOES: a UST: GROUNDWATER: DRINKING WATER: SOLID WASTE: ' RCRA: CERCLA LANDFILL n ern n on � �..1 ' OTHER: nun non ..,..... n_ nl...., o- eN - r, - T..a,,.. I I,..•w r.,.• .inA - yw.,w. n,,.., 1— A.h.iNt n— we„n Q.. % CHAIN OF CUSTODY RECORD LAB USE ONLY e' rr�� PRISM I Full -Service Analytical 8 Environm¢nTdl �" NO WA rD SGIUt10R5 PAGE OF QUOTE %TO ENSURE P R BILLING: �- 7,T_ Y u.eaa.Tuani„w /''1 S� /yI Q a(W �It%K f Samples INTACT upon arrival? � O Project Name: t/l�s 449 Springbrook Road • Charlotte, NC 28217 Phone 7041529-6364 • Fax! Short Hold Analysis: � (No) UST Project: ) O Received ON WET ICE? PROPER PRESERVATIVES indicated? __�[_ / T r77�041525-0409 Client Company Name: ONAA. OT- OQ�'6N1� Please ATTACH any project specific reporting (OC LEVEaI III 1 Received WITHIN HOLDING TIMES? _ _ to provisions and!oT QC Re Irements Report To/Contact Name: 1 U41 Mk- Bw7`0 M►elCEN7� CUSTODY SEALS INTACT? — Il Reporting Address: O. Invoice To: 1 P 9 Od+Y.6N tLl uC. .�l)$' Address: VOLATILES rec'a wroUT HEAOSPACE? PROPER CONTAINERS used?— TEMP: Therm ID: I li i ( 7 observed Z�°C I Coro. °C Phone:—b D^3�.Y)/Fax(Yes)(No): Email Address: WMNr11'DKgG•MwNta/•� • Purchase Order No./Billing Reference n Q" TO BE FILLED IN BY CLIENTlSAMPLiNG PERSONNEL Requested Due Date O 1 Day ❑ 2 Days O 3 Days O 4 Days ❑ 5 Days EDD ✓Excel Certification: NELAC_ DOD FL_ NC ✓ T PDF Other Rush Work Must Be Type: "Working Days" ❑6-9 Days tendertl f0 days ❑ Pre -Approved Site Location Name: Samples received after 14:DD will be processed next business day. SC OTHER — N/A Site time as e Location Physical Address: Turnaround e is bed on business days, excluding weekends and holidays. Water Chlorinated: YES_ NOV (SEE REVERSE FOR TERMS 8 CONDITIONS REGARDING SERVICES RENDERED I3Y PRISM LABORATORIES, INC. TO CLIENT) Sample Iced Upon Collection: YES_ NO— TIME MATRIX SAMPLE CONTAINER - CUBIT DATE COLLECTED (SOIL, i—..—._____ —_ __ PRTIVES ANALYSIS REQUESTED �Yj'�. - REMARKS (�c� PRISM LAB MI SAMPLE DESCRIPTION COLLECTED j MILITARY WATER OR -TYPE NO. SIZE 7NE$ HOURS SLUDGE) O•. W r � Q� `C"� � r ID NO. SEE BELOW _. t I Sampler's Signature C Sampled By (Print Name) L��'�' irke,c, C-C Affiliation MAr Upon relinquishing, this Chain Gf tody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been In[ti d. I u -:(Signenrel React I 'n" a� 6 3D I0: Additional Comments: Site Arrival Time RYinqubhed By: (Si I gridor I V saTer e Departure re: Rai ed. y (Signatures a®rvad Fq^p LetvxalonM By _ a L /� �Z 1I rTLr 1.41(i;et I �/CAP Field Tech Fed /7 / -42 .' ciU Mileage: Undo ipnlmC NEE: ALL AMPLE COOLER SHOULD BE TAPED SHUT WITH CUSTODY SEALS S ATIONTOTHEIABORATORY. Gro Na SAMPLES ARE NOTACCEPTEDAND VERIflEDAGAINST CDC UMILRECEIVED ATTHE LABORATORY. �/'JtO) I�) IJa) AI/• ,� • -a `l ❑ Fed Ex ❑ lR5 D Herld4egvered Prism Field Service 3 Olher �� NPDES: UST: GROUNDWATER: DRINKING WATER: S ID WASTE: RCRA: CERCLA I LANDFlLL OTNEfi: "• ❑ NC ❑ SC C ❑ hir ❑ SC ❑ NC ❑ SC ❑ N C ❑ SC NC ❑ SC ❑ NC O SC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC O 3C ❑ C ❑ ❑----- El . ❑ _ _ ❑ ❑ ❑ er.nMTAIMFR T .. F rnnFR• A = Amhar r. = rdaar r� "AAA P = Plano.- TI = TaMn-I ideal Cat. .OA = Volatile Onannir_c Anaivsk !Zero Head Snei Main Office: ' 449 Springbrook Road PRISMFull Sauvler- Analytical and Gnvironrnantal Solutions P.O. Box 240543 Charlotte, NC 28224-0543 — - - on<rr, Phone: 704/629-8364 118001629.6364 Fax: 704/525-0409 v .prismlabs.eorn Sodium Absorption Ratio The amount of exchangeable sodium ions versus the amount of exchangeable calcium & magnesium ions in a given material. Sample Number 8040569-01 1 Sample Name Class Na: Sodium (mg/L) Equivalent weight:23 Ca: Calcium (mg/L) Equivalent weight: 20 Mg: Magnesium (mg/L) Equivalent weight 12 Milli Equivalent (ME) = mg/L / Equivalent weight Nam /L Cam /L) M m /L 173 223 130 Na (ME) Ca (ME) 1 11.15 Mq IMU 10 83 7.52 SAR= Na Milli Equivalent/[0.5 X (Ca Milli Equivalent + Mg Milli equivalent)]0.5 power SAR = 2.27 (From mg/L entered above) Calculated By:_ O' I Page 10 of 16 Main Office: / PRISM I Fult Sorvico Analytical and 449 Springbrook Road �j Envlronmantal SoWUono P.O. Box240543 ..- OUTIMIE51NC Charlotte, NC 28224-0543 Phone: 704162M364 11800/529.6364 Fax: 704/525-0409 www.prismiabs.com Plant Available Nitrogen Sample Number so4o5ss-o1 Sample Name Class A Mineralization Rate TKN NH3 NOX ma/ka malka mg/ka 0.3 32200 1 223 2.3 PAN Surface 9,707 mg/kg Calculated By: MR(TKN-NH3)+ 0.5(NH3)+NOX = PAN mg/kg Page I of 16 ACCESS ANALYnCAL, INC. ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte NC 282240543 ATTENTION Terri W. Cole PROJECT ID 8040569 LABORATORY REPORT NUMBER 1805073 DATE May 07, 2018 Primary Data Review By Secondary Data Review By C Ashley Amick Chris Pafford Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com PLEASE NOTE: Unless otherwise noted, all analysis on this report performed at Analytical Environmental See -vices Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 AIIIA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCM Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page Page 12 of 16 [' M I mFull-Service AnalyticalR IS Envlronenial Solutions SUBCONTRACT ORDER CcriiR do NELAC USACE Prism Laboratories, Ine. C SC_ Odier 8040569 N SENDING LABORATORY: RECEIVING LABORATORY: Prism Laboratories, Inc. Analytical Environmental Services, Inc. P. O. Box 240543 3080 Presidential Parkway Charlotte, NC 28224-0543 Atlanta, GA 30340 Phone: 800-529-6364 Phone ;(770) 457-8177 Fax; 704-525-0409 Fax: NA Project Manager: Terri W. Cole - - - Analysis Due Expires Laboratory ID Comments Rmmnle M! 8n40569-01 Solid Sampled:04/30/IB 08:00 Herbicides TCLP (Sub) 05/07/18 08:00 Conlalners Supplied, to Ttefenscd 135, Dnie Received 13y Uinc Page 1 of 1 f) Page Page 13 of 16 Analytical Environmental Services, Inc Date 7-May-18 Client: Priam Laboratories Client Sample ID: Clan Lab Order 1805073 Tag Number: 8040569-01 Project Name: 8040569 Collection Date: 4/302018 8:00:00 AM Lab ID: 1805073-OOIA Matrix: Solid Analyses Result Qual MDL Reporting Units BatcblD DF Date Analyzed Analyst Limit HERBICIDES,TCLP SW1311/8151A (SW3510C) 2,4,5-TP (Silvex) BRL 0.030 0.20 m&/L 260118 1 05I042018 14:38 UH 2,4-D BRL 0.051 0.20 ma/L 260118 1 05,04/201814:38 UH Surf: DCAA 63.5 0 504-133 %REC 260119 1 05/04201814:39 UH Qnklinen: • VAlus omwr4 mamvm aonrsminuil lsvN aRL Nm DmcW n MDL N Haldlny trout rot prapRrelron w vnvlyu, euwdW N AaIylen NELAC cem(ed a Awlyl, dneeed in the umcrNM rruvbd blwk E Ennnand rklw vkove 9vanumwn rayo S soke Rem g aw.ra, I'mm Me In mnmx > Dreercr rlien Rvfull rdw 1 R,Rymny Lunn I L. rhun R.11 uNw Papa Page 14 of 16 ' E\TIRO\1tFAT.\I. {F.S StIR\9Ce3.6C. 1. client Name: Access Analytical, Inc. SAMPLE/COOLER RECEIPT CHECKLIST 2 Cattle,. FeclEz ❑• UPS ❑ USPS❑ Client❑ CounerM Olhei Yes No N/A 3. 4. 5 6, 7 8. 9. 10. 11. 12. Clear Save as AES Work Order Number: 1805073 Shipping container/cooler received in good condition? • damaged ❑ leaking ❑ other❑ Custody seals present on shipping container? Custody seals intact on shipping container? Temperature blanks presents Cooler temperatures)within limits of 040(See item 13 and 14 for temperature recordings.) ® © O Coding initiated for recently collected samples ice present ❑ Chain of Custody (CDC) present? Chain of Custody signed, ive dated, and timed when relinquished and reced? Sampler name and/or signature on COC7 Were all samples received within holding time? TAT marked on the COC? • IFno TAT indicated, proceeded with standard TAT per Terms&Conditions. li 13 Cooler 1 Temperature 0.4 °C Cooler 2 Temperature 14. Cooler 5 Temperature °C Cooler 6 Temperature 15. Comments: 16. 17 18 19. 20. 21. 22. 23. 2, . 25 26. °C Cooler 3 Temperature °C Coder 4 Temperature °c °C Cooler 7 Temperature °C Cooler 8 Temperature °C I certify that I have completed sections 1.15 (dated Initials). All 5/1/18 V.. an. .1. .....rL Were sample containersintact upon receipt? Custody seals present on sample containers? Custody seals intact on sample containers? Do sample container labels match the COC? © O O incomplete info illegible k 8 ❑ no label other ❑ Are analyses requested indicated on the COC? Were all of the samples listed on the COC received? O © O samples received but not listed on CDC samples listed on CDC not received _ Was the sample collection date/time noted? Did we receive suf8cien[samplevolume for indicated analyses? Were samples received in appropriate containen? ill Were VDA samples received without headspace (<1/4" bubble)? Were trip blanks submitted? listed.. COC ❑ not listed on COC ❑ 27. Comments: This section only applies to samples where pH can be 1 certify that 1 have completed sections 16-27 )dated Initials). P1M 5/02/11 checked at Sample Receipt. Yes No N/A Details Commems 28. Have containers needing chemical preservation been checked? 29 Containers meet preservation guidelines? rn 30. Was pH adjusted at Sample Receipt? t0 ' Note: Certain analyzes requve chemical pres•rvalion but must be clucked in the laboratory and not upon Sample Receipt such as Cdikams, vOCe and Od a Grease/TPH. N I certify that I have completed sections 29-30 (dated initials). Checklist 6.9.17 Rev 2 Locked C0 PIM 5/02/I8 Page 4 of 5 Analytical Environmental Services, Inc Date: 7-May-18 Client: Prism Laboratories ANALYTICAL QC SUMMARY REPORT Project Name: 8040569 Vvorkolyder. 1805073 BatchID: 260118 Sample TD: MB-260118 Client ID: Units: mg/L Prep Date: 05/0312018 Run No: 369542 SampleType: MBLK TestCode: HERBICIDES,TCLP SW131118151A BatchID: 260118 Analysis Date: 05/04/2018 Seq No: 8I86724 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5.1? (Silvex) BRL 0.20 2,4-D BRL 0.20 Surr. DCAA 0.3280 0 0.5000 65.6 50.4 133 Sample ID: LCS-260118 Client ID: Units: mg/L Prep Date: 05/03/2019 Run No: 369542 SampleType: LCS TestCode: HERBICIDES,TCLP SW131118151A BatchID: 260118 Analysis Date: 05/04/2018 Seq No: 8186725 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 1,4,5=1 P (Silvex) 03468 0.20 0.5000 69.4 49.1 119 2.4-D 03771 0.20 0.5000 754 50.9 129 Suer: DCAA 03366 0 0.5000 67.3 50.4 133 Sample ID: 1804R35-001 EMS Client )D: Units: mg/L Prep Date: 05/03/2018 Run No: 369542 SampleType: MS TestCode: HERBICIDES,TCLP SWI31118151A BatchID: 260118 Analysis Date: 05/04/2018 Seq No: 8186727 l Analyte Result RPT Limit SPK value SPK Ref Val %RFC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual G.4,J-1 r (Silvex) 02996 0.20 0.5000 59.9 48.2 125 2A-D 03250 0.20 0.5000 65.0 445 139 Surr: DCAA 0.2927 0 0.5000 58.5 50.4 133 Qnalirmrs: I Greater than Result value (D BRL Below reporting limit 1 J Estimated value delccted below Reporting Omit O) O Rpt Lim Reporting Limit L33 1 < Less than Result value E Estimated (value above quantilation range) N Analylenot NELACocnificd S Spike Recovery outside limits due to matrin B Analyle detected in theassociared method blank H Holding times for preparation or analysis exceeded R RPD outside limits due to matrix Page 5 of 5 "/ PRISM I Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Town of Mooresville/RR WWTP Whitney Munroe P, O. Box 878 Mooresville, NC 28115 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Class A Dried Sludge Lab Submittal Date: 07/16/2018 Prism Work Order: 8070199 Case narrative 08/03/2018 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: This is a Revised Report and supercedes the original laboratory report dated 08/01/2018. Fecal coliform result has been recalculated and corrected. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. Terri W. Cole Project Manager Data Qualifiers Key Reference: Reviewed By Terri W. Cole Project Manager B Analyte is found in the associated blank at a concentration >1/2 RL. BH MB greater than one half of the RL, but the sample concentrations are greater than 10x the MB. MC Sample concentration too high for recovery evaluation. SE Surrogate recovery outside the QC limits due to emulsion. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road -P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529.6364 -Toll Free Number: 1-8001529-6364 - Fax: 7041525-0409 Page 1 of 16 PRISMi Full-Sece Analytical Environmental Solutions Sample Receipt Summary 08/03/2018 Prism Work Order: 8070199 Client Sample ID Lab Sample ID Matrix DatefTime Sampled Date/Time Received Class A 8070199-01 Solid 07/16/18 6:35 07/16/18 11:10 Samples were received in good condition at 2.4 degrees C unless otherwise noted. This report should not be reproduced, except In its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529.6364 - Tali Free Number: 1-8001529-6364 - Fax: 7041525.0409 Page 2 of 16 P R I S M I Full -Service Analytical d Envbonmentel aolunona ..aoa: .w.- Laboratory Report 08/03/2018 Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 8070199-01 P. O. Box 878 Prism Work Order: 8070199 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 07/16/18 06:35 Time Submitted: 07/16/18 11:10 Parameter Result Units Report MOIL Dilution Method Analysis Analyst Batch Limit Factor Datenrane ID General Chemistry Parameters Plant Available Nitrogen 3700 mglkg dry 390 85 5 'CNculeeon 7/27118 20:10 CLB [CALC] %Solids 97.0 %by 0.100 0,100 1 'SM2640G 7117118 15:40 BJC POG0248 Weight Ammonia as N 1700 mglkg dry 10 2.5 1 'BM4500-NH3 C 727118 20:10 BMS P11100433 Nitrate/Nitnte as N BRL mg/kg dry 5.2 1.4 1 'SM45DD-NO3 F 7/17/18 7:51 CLB P8G0218 PH 6.3 PH Units 1 '90450 711N78 15:17 CSP PSGO228 Phosphorus -Total 14000 mg/kg dry 260 57 10O 'SM SOO-PF 71119111111 8:27 CLB P8430221 Total Kjeldahl Nitrogen 11000 mg/kg dry 1300 280 5 '351.2 7/18118 10:28 CLB PSGO230 Microbiological Parameters Fecal Collforms 2 MPN/9 dry 0.2 1 '8M9221 E 7MG118 13:54 SMS P8GD280 TCLP Extraction by EPA 1311 TCLP Extraction Complete N/A 1 '1311 7/20118 7:35 MMR P8G0281 TCLP Extraction Complete N/A 1 '1311 ZHE 7/30/18 9:39 KDM P8GO465 TCLP Metals Mercury BRL mg/L 0.010 0.000030 1 '7470A 720/18 15:16 JAB P8G0301 Arsenic BRL m98- BAB 0.016 1 '6010D 723/1814:21 JAB P8G0307 Barium BRL mg/L 5.0 0.0040 1 '601013 723/18 14:21 JAB P8GD307 Cadmium BRL mg/L 0.025 0.0D075 1 '601 DO 723118 14:21 JAB P000307 Chromium BRL mg/L 025 0.0018 1 '60101) 723118 14:21 JAB P8G0307 Lead BRL mg/L 0.050 O.OD40 1 '601011) 723118 14:21 JAB P8G0307 Solarium BRL mg/L 0.10 0.028 1 '6010D 71=18 14:21 JAB P8GO307 Silver BRL mg/L 0.25 0.0020 1 '6010D 71=18 14:21 JAB PSGO307 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mglL 0.0025 0.00017 1 '8081B 7/30118 13:11 JMV PBG0414 Dieldnn BRL mg/L 0.00050 0.000014 1 '80818 7130/18 13:11 JMV P8GO414 Endun BRL mg/L 0.00050 0.000015 1 '80818 7/30/18 13:11 JMV PBGD414 gamma-BHC BRL MA 0.00050 0.000013 1 '80818 7/30118 13:11 JMV PBG0414 Heptachlor BRL mg/L 0,00050 0.000017 1 '80818 7/3011013:11 JMV PSGD414 Heptachlor Epoxide BRL rl 0.00050 0.000013 1 18081B 7130/18 13:11 JMV PSGO414 Mettloxychlor BRL mg/L 0.00050 0.000039 1 'B081B 7/30/1813:11 JMV POG0414 Toxaphene BRL mg/L 0.025 0.000074 1 180818 7/30/1813.11 JMV P8G0414 Surrogate Recovery Control Limits Decachiorobiphenyl 18 % 13-186 Tatrachlwo-m-xylene 5 % 40.134 SE TCLP Sem[volatile Organic Compounds by GC/MS 2,4B.TridNorephenol BRL ri 0.26 0.0016 1 '827013 7/26118 11:17 JMV P8G0380 2,4,6-Tdchlorophenol BRL am& 0.10 0.0018 1 '8270D 7/26118 11:17 JMV P8G0380 2,4-Dinitrotoluene BRL 1,1198. 0.050 0.0014 1 '8270D 7I28I1811:17 JMV P8G0380 2-Methylphenol BRL mg/L 0.050 0.0018 1 '82700 7/26118 11:17 JMV PSG0380 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Read - P.O. Be, 240543 - Charlotte, NC 28224-0643 Phone: 7041529.6364-Toll Free Number: 1-8001529-6364 - F.: 70415254409 Page of 16 Laboratory Report y' R I S� f� I Full-ServiceAnalytical 8 ff i V 0 P ! :A3GM:9R*1 WG Environmental Solutions 08/03/2018 ' Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 8070199-01 P. O. Box 878 Prism Work Order: 8070199 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 07/16/18 06:35 Time Submitted: 07/16/18 11:10 Parameter Result Units Report MOIL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3/4-Methylphenol BRL mg/L 0.050 0.0015 1 '8270D 7/26118 11:17 JMV 138G0380 Hexachlorobenzene BRL mg/L 0.050 0.0013 1 "8270D 7/26118 11:17 JMV PBG0380 Hexachlorobutadlene BRL mg/L 0.050 0.0021 1 *82700 7/26/18 11:17 JMV P8G0380 Hexachloroethane BRL mg/L 0.050 0.0017 1 '8270D 7/26/18 11:17 JMV PBG0380 Nitrobenzene BRL mg/L 0.060 0.0026 1 '8270D 7/26118 11:17 JMV P8G0380 Pentachlorophenol BRL mg/L 0.25 0.0012 1 '8270D 7/26/18 11:17 JMV P8G0380 Pyridine BRL mg/L 0.25 0.0010 1 '8270D 7126118 11:17 JMV P8G0380 Surrogate Recovery Control Limits 2,4,6-Tribromaphenol 34 % 43-140 SE 2-Fluoroblphenyl 28 % 44-119 SE 2-Fluorophenol 28 % 19-119 Nitrobenzene-d5 32 % 44-120 SE Phenol-d5 26 % 11-52 Terphenyl-d14 34 % 50-134 SE TCLP Volatile Organic Compounds by GClMS 1,1-Dichloroethylene BRL mg/L 0.035 0.000083 1 '8260B 7/27/18 18:12 KDM P8G0468 1,2-Dichloroethane BRL mg/L 0.025 0.000066 1 '8260B 7/27118 18:12 KDM P8G0468 1,4-Dichlorobenzene BRL mglL 0.38 0.000050 1 •8260B 7/27118 18:12 KDM P8G0468 Benzene BRL mg/L 0.025 0.000048 1 '8260B 7127118 18:12 KDM P8G0468 Carbon Tetrachloride BRL mg/L 0.025 0.00011 1 "8260B 7/27118 18:12 KDM P8G0468 Chlorobenzene BRL mg/L 5.0 0.000062 1 '8260B 7127118 18:12 KDM P8G0468 Chloroform BRL mg/L 0.30 0.000076 1 `8260B 7127118 18:12 KDM P8G0468 Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.00024 1 '8260B 7127118 18:12 KDM P8G0468 Tetrachloroethylene BRL mg/L 0.035 0.000098 1 '8260B 7127/18 18:12 KDM P8G0468 Trichloroethylene BRL mg/L 0.025 0.000078 1 *82608 7/27/18 18:12 KDM P8G0468 Vinyl chloride BRL mg/L 0.010 0.000097 1 '8260B 7/27/18 18:12 KDM P8G0468 Surrogate Recovery Control Limits 4-Bromofluorobenzene 100 % 80-124 Dibromofluoromethane 100 % 75-129 Toluene-d8 99 % 77-123 Total Metals Aluminum 20000 mg/kg dry Mercury 0.63 mg/kg dry SAR Soil Preparation Complete g SAR Percent Moisture 81.1 % by Weight Arsenic 2.0 mg/kg dry Sodium Absorption Ratio 1.6 (blank] Cadmium 0.65 mg/kg dry Calcium 25000 mglkg dry Calcium, SAR 250 B mg/L 52 7.6 10 '6010D 7/24M8 12:31 JAB PSG0303 0.31 0.029 15 •7471 B 7118/18 14:13 JAB PBG0245 1 '2-78-054 7/24118 13:40 MMR P6G0362 0.100 0.100 1 •2-78.054 7125118 13:45 MMR P8G0393 0.52 0.031 1 16010D 7123118 12:35 JAB PSGO303 0.30 0.016 1 '2-78-054 7126118 0:37 JAB PBG0369 0.26 0.0069 1 `6010D 7/23/18 12:35 JAB PBG0303 100 2.4 10 •6010D 7124118 12:31 JAB PBG0303 0.10 0.010 1 '6010D 7/26118 0:37 JAB PBG0369 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529.6364 - Fax: 7041525-0409 Page 4 of 16 PRISM I Euvirc man Anxtytical 4 F H-S aural Solulmn. Laboratory Report 08/03/2018 Town of Mooresvillei WWTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project. Class A Dried Sludge Sample Matrix: Solid Client Sample ID: Class A Prism Sample ID: 8070199-01 Prism Work Order: 8070199 Time Collected: 07/16/18 06:35 Time Submitted: 07/16/18 11:10 Parameter Result Units Report MDL Dilution Method Analysis Analyst Balch Limit Factor Dateffime ID Chromium 24 mglkg dry 0.26 0.043 1 '60101) 7/23118 12:35 JAB PBG0303 Copper 330 bri dry 5.2 0.47 10 '6010D 7/24118 12:31 JAB PSGO303 Lead 14 mglkg dry 0.26 0.048 1 '60101) 7/23118 12:35 JAB P8G0303 Magnesium 2600 mg/kg dry 2.6 0.24 1 '6010D 7123118 12:35 JAB P8130303 Magnesium, SAR 76 mg/L 0.10 0.0086 1 -60100 7126118 0:37 JAB PBG0369 Molybdenum 9.5 ni dry 0.52 0.015 1 '6010D 7123118 12:35 JAB PSG0303 Nickel 16 ni dry 0.52 0.019 1 '6010D 7123118 12:35 JAB P8G0303 Potassium 30,00 ri dry 13 0.46 1 -6010D 7123118 12:35 JAB PSG0303 Selenium BRL mglkg dry 52 1.2 to '6010D 7/24/18 1231 JAB P8G0303 Sodium a50 mill dry 15 0.51 1 '6010D 7123118 12:35 JAB PSGO303 Sodium, SAR 110 6 mg/L 0.50 0.018 1 '50100 7126118 0:37 JAB PSG0369 Zinc 620 m9/kg dry 26 0.92 10 '60101) 7/24118 12:31 JAB PBG0303 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road -P.O. Box 240543 -Charlotte, NC 282244W Phone: 704/529-6364 - Toll Free Number: l-800/529-6364- Fax- 7041525-0409 Page 5of16 Sample Extraction Data Prep Method: 351.2 Lab Number i Batch Initial Final Datefrime 8070199 01 P8G0230 0.05 g 25 mL 07/17/18 9:25 Prep Method: SM4500-NH3 B Lab Number Batch Initial Final Daterrime 8070199-01 P8G0433 1.02 g 50 mL 07/26/18 13:00 Prep Method: SM4500-PBS i Lab Number Batch Initial Final DatefTime 807019MI P8G0221 1 g 50 mL 07/18/18 11:00 Prep Method: Solids, Dry Weight Lab Number Batch Initial Final Date/Time 8070199-01 PBG0248 30 g 30 g 07/17/18 15:40 Prep Method: 1311 Lab Number Batch Initial Final Date/Time 8070199-01 P8130281 100 g 2000 mL 07/19/18 14:15 8070199-01 P8G0465 25 g 500 mL 07/26/18 8:34 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 8070199-01 P8G0307 10 mL 50 mL 07/20/18 9:55 Prep Method: 7470A Lab Number Batch Initial Final Daterrime 8070199-01 PSG0301 20 mL 30 mL 07/20/18 9:50 Prep Method: 3510C GC Lab Number Batch Initial Final DatefTime 8070199-01 P8G0414 1000 mL 10 mL 07/26/18 9:48 Prep Method: 3510C MS Lab Number Batch Initial Final Date[Time 8070199-01 P8G0380 200 mL 1 mL 07/25/18 9:27 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 8070199-01 P8G0468 10 mL 10 mL 07/27/18 8:41 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 8070199-01 PBG0369 50 mL 50 mL 07/24/18 13:40 8070199-01 PBG0369 50 mL 50 mL 07/24/18 13:40 8070199-01 P8G0369 50 mL 50 mL 07/24/18 13:40 Prep Method: 30508 Lab Number Batch Initial Final DateMme 8070199-01 PBG0303 2 g 50 mL 07/20/18 9:00 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-8001629-6364 - Fax: 704/525-0409 Page 6 of 16 Sample Extraction Data Prep Method: 30508 Lab Number Batch Initlal Final DatelTime 6070199-01 PBG0303 2 c 50 mL 07/20118 900 Prep Method: 7471B Lab Number Batch Initial Final ❑atefTime 8070199-01 P8G0245 0.6 g 50 mL 07/18118 9:05 Prep Method: SAR 2-78-054 Lab Number Batch Initial Final Daterrime M70199-01 P8G0362 250 g 250 g 07/23/18 13,40 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Number Analyse X070199-01 Herbicides TCLP(Sub) This report should not be reproduced, except In Its entirety, without the written consent of Prism Laboratories, Inc. "9 Springbrook Road -P.O. Box 240543 - Charlotte, NC 28224-0543 Phone7041529-63U -Toll Free Number 1-800/529.6364- Fax: 7041525-0409 Page 7 of 16 CHAIN OF CUSTODY' REWORD ; o `fRISM I Full -Service Analytical o j' NO ALA Environmental Solution, PAGE OF QUOTE TO ENSURE PROPjiR B1LL/NGt - - - - - Surnplas 1+1rACT upar, et r s17 449 Springbrook Road • Charlotte, NC 20217 Project Name: I Reoaivzd ON WET ICE? � < __ o0 Phone 7041629-6364 • Fax: 7041525•0410e Short Hold Analysis: (No) UST Project: (Yes O YftOYER. r'iiL=SLR iATsvi s Ind, :-A? / 0) Client Company Name: ED —� aF%�I�ODCL'hu 'Please ATTACH any project specific reporting (QC LEVER III IV) Received W!THIN HOi.OING-MAES? '�_-___-_. _._ (a provisions and/or QC Requirements CUSTODY SELLS INrACT7 n Report To/Contact Name: JA Invoice To: `�t>wl d� %�/�ep�$p VOLATILESw61W10UTHEADSRAGE, Reporting Ad ss: a.B PROPER •.r„ •, �LI+= / r Address: IEMP: Therm ,;)_ (i' - Obacn•4�' 1..(J CJ :,mL__ Phoned- &&0-3PICIo Fax (Yes) (No): Purchase Order NoMiliing Reference TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Email Address:Wr6P.&e&Yk?b(MLe t11r . ' $v Requested Due Date ❑ 1 Day Q 2 Days O 3 Days ❑ 4 Days ❑ 5 Days Certification: NELAC_ DOD FL NC EDD Type: PDF_Excel—other "WorWng Days" Q 6-9 Days�tandard 10 days []Rush Vvor Mdust HePre-ApproveSC OTHER � NIA Site Location Name: Samples received after 14:00 will be processed next business day. Site Location Physical Address: Turnaround time Is based on business days, excluding weekends and holidays. Water Chlorinated: YES— NO V (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES. INC. To CLIENT) Sample Iced Upon Collection: YES VIVO_ I TIME I MATRIX ANALYSIS ESTEO SAMPLE CONTAINER � �* CLIENT DATE COLLECTED (SOIL, i PRESERVA- +tiV� jV PRISM i T[VES \� Ea` �` `�/ , / REMARKS LAB SAMPLE DESCRIPTION COLLECTED MILITARY WATER OR -TYPE NO. SIZE \��. • �/ \�pr ID NO. HOURS SLUDGE) SEE BELOW - —---_-r,�p ,\ -Ito it 6i;l Sampler's Signature - Sampled By (Print Name) Ly- r-- -\ 4e.4cl r` Affiliation _ t U L1iIn Upon relinquishing, this Chain of ustody Is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted In writing to the Prism Project Manager. There will be ciZarges for any changes after analyses have been Initialized. r' Additional Comments: V0 i f S¢ri mod oiSnlpmenL NOTE: ALL aAMPLE COOLERS SHOULD BE TAPED SHUTWITH-CUSTODY SEALS FOR TRANSPORTATION TO THE LABORATORY. No. SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST CDC UNTIL RECEIVED AT THE LABORATORY. (� ❑ Fed Ex ❑ UPS ❑ HandileUvered d. Ffeld Service J Olher + /` ` NPDES: UST: GROUNDWATER: DRINKING WATER: `SO ID WASTE: RCRA: ; CERCLA LANDFILL OTHER: >rI C❑SCI CI NC ❑SC I ❑NC ❑SC ❑NC ❑SC C ❑SC ❑NC❑SC ❑NC ❑SC ❑NC El SC ❑NC Cl SC ❑ ❑ : ❑ _ J J J _ ❑ - ❑ "CONTAIN. (PE CODES: A = Amber C. = Clear G= Glass P = Plastic; TL = Teflon -Lined Ca, -)A = Volatile Organics Analysis (Zero Head Space) Sde A,tival Time. ) Sito Departure Tan:, 1 IField Tech Fee. � ____.1 Additional Comments: A14 A-st C-e'i C41 84�) N. I A01 Pbl SAMPLES ARE NOTACCEPTED AND VERIFIED AGAINST CDC UNTIL RECEIVEDATTIiE LABORATORY. fl(� j�1NJ O Fed Ex CUPS ❑ Hand-deliveredrism Field Service ❑ C;nnr _ I. ---- _ `' r�"t 1 NP ES: UST GROUNDWATER: DRINKING WATER: SOLID WASTE: RCRA: CERCLA LANDFILL OTHER: Nit KNC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC { ❑ NC 11,9C XNC ❑ SC ❑ NC Cl SC ❑ NC ❑ SC' ❑ NC ❑ SCI ❑ NC ❑ SC °CONTAINr VPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Ca -)A= Volatile organics Analysis (Zero Head Space) CHAIN (OF CUSTODY RECORD _ —, P, Full -Service nnlyr,c�r! � PRISMi Envuanrnun"al :.yciuticrt9 ENSURE c J - rd0 eo PAGE-aOF� QUOTE #TO PR EKBILLING: Szrng'.; iNr; navr,::r7 % P I J� r - ^ 4:1 Springbrncy Road + Charlotte, 17C 282ii Project Name 5 r�IXii �1 Fic e,�e:! C;i KIE1 tCF7 rrr p Phone 70�1529-6;Tb-i + For: 7041525-0409 Short HO1d Analysis: Q) (No) UST Project: ( S) PROP —ER PRESERUAt ivF = me ' . + --rt ,u`� `Please ATTACH any project specific reporting (QC LEVE Il III IV) Hc- Iry :a wrTNlra HOLD ti� ? ir.+F S % i� Cr Wes Client Company Name: D /yw provisions and/or QC Requirements iJL'S1a4JV ci r� :N r.,C r f' CU Report To/Contact Name: fit— --�-411 invoice To: ra�,+i!.[=a �•;;r�curr.,.� P: .F- Reporting Address: �u�� Address:Uowte�klu' Wrenn` Phone: M -{0( —3110 Fax (Yes) No: Purchase Order No.IBilling Reference _TFR.Y TO BE FILLED 1N BY CLIENTISAMPLING PERSONNEL Email Address: WVhtLn 1,t V Regoa!3IPd Due Date ❑ 1 Day ❑ 2 Days Q 3 Days Ct 4 Days Q 5 Days Certification: NELAC 'DOD FL NC—Z EDD Type: PDF Excel_Other "Working Days" Ll &9 Days�tandard 10 days Cl Rush Work Must Be Site Location Name: Samples received after 14.00 will be processed next business day. days, holidays. Sc OTHER NIA — dilater Chlorinated: YES_ NO — Site Location Physical Address: Turnaround time is based on business excluding weekends and (SEE RENDERED BYPRISMRLABORATORES, NC.TOiNnSERViCES Sample Iced Upon Collection: YES NO_ p I TIME CLIENT DATE COLLECTED SAMPLE DESCRIPTION COLLECTED MILITARY l MATRIX SAMPLE CONTAINER r ANALYSIS REQUESTED (SOIL, PRESERVA- WATER OR E - - TIVES v -A REMARKS � Vp PRISM LAB ID NO. HOURS SLUDGE) NO. SIZE ! r _yp � SEE BELOW . - - ( uD%- 1 Sampler's Signature. l c, 14v---c l----.Sampled By (Print Name) i,�a�* �. �P� rEr Affiliation�- Upon relinquishing, this Chai Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been Initialized. C Main Office: F449 Springbrook RoadPRISM P.O. Box 240543 Charlotte, NC 29224-0643 Phone: 704/529-6364 1/600/52946364 Fax: 704l525-0409 w .prismlaba.com Plant Available Nitrogen Sample Numberl 8070199-01 1 Sample Namel Class A Mineralizatiott Rate TKN NH3 NOX �� mnlL mall 0.3 11200 1680 0 PAN Surface 3.700 m /k Calculated By MR(TKN-NH3)+ 0.5(NH3)+NOX = PAN mg/kg Page 10 of 16 Main Office: 449 Springbrook Road P R I I Full Sar•-ict- h:+alyllcal .-nd P.O. Box 240643 r' Environni.zmal Solutions Charlotte, NC28224-0543 t Phone: 7041629-6364 118001529-6364 Fax: 704/525-0409 www,prismiabs.com Sodium Absorption Ratio The amount of exchangeable sodium ions versus the amount of exchangeable calcium & magnesium ions in a given material. Sample Humberl 8070199-01 Sample Name Class A NpLniq l.} C_q[rrtg/L) Mg.(m /L) Na : Sodium (mg/L) Equivalent weight: 23 113 252 75,7 Ca: Calcium (mg/L) Equivalent weight: 20 Mg: Magnesium (mglL) Equivalent weight: 12 Na (,MEN Mg_(MEJ 491 1 12.6 1 631 Milli Equivalent (ME) = mg/L / Equivalent weight SAR= Na Milli Equivalentl(0.5 X (Ca Milli Equivalent + Mg Milli equivalent)]0.5 power TSAR = 1.60 (From mg/L entered above) Calculated By - Page 11 of 16 Acass ANALYTICAL, 1-NC. ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte NC 282240543 ATTENTION Terri W. Co1e PROJECTID 8070199 LABORATORY REPORT NUMBER 1807F77 DATE July 26, 2018 Primary Data Review By Chris Pafford Project Manager, AES PLEASE NOTE., Secondary Data Review By Ashley Amick Project Manager, Access Analytical aumick@axs-ine.com Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 AII1A-LAP,LLC Laboratory ID:100671 for Industrial Hyglane samples (Organics, Nietais, PCM Asbestos, Gr•avimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NClGAareas. All questions regarding this report should be directed to your local Access Analytical representative at 803 781.4243 or toll fee at 883.315.4243 Page Page 12 of 16 ` Full -Service Analytical & PRISM I Environmental Solutions I k-7F-t-1 SUBCONTRACT ORDER C@rtifi tin , NELAE USACE Prism Laboratories, Inc. VCV SC_ Other 8070199 SENDING LABORATORY: RECEIVING LABORATORY: Prism Laboratories, Inc. Analytical Environmental Services, Inc, P. O. Box 240543 3080 Presidential Parkway Charlotte, NC 28224-0543 Atlanta, GA 30340 Phone: 800-529-6364 Phone :(770) 457-8177 Fax: 704-525-0409 Fax: NA ProJectManager. Terri W. Cole Analysis Due Expires LaboratorylD Comments 1D. 8070199-0.1 Solid Samplcd:07/16/18 06:35 Herbicides TCLP (Sub) 07/23/ 18 06:35 Containers Supplied. L /7-7' 1 7 -1$ J Ii:fiC Rnrniwrl Skv h..�n px Released By Date Received By m` Dal (e _._._ Rele .ce 3y Date Received By Date Page 1 of 1 Rage Page 13 of 16 Analytical Environmental Services, Inc Client: Prism Laboratories lab Order 1807F77 Project Name: 8070199 Lab ID: 18O7F77-0O1A Analysts HERBICIDES, TCLP SW131118151A 2,4.5-TP (Silvex) 2,4-D Surr: DCAA Date: 26-3u1-18 Client Sample ID: Class A —� Tog Number. 8070199-01 Collection Date: 7/1620186:35:00 AM Matrix: Solid Reporting Result Qual MDL ,,is BatcblD DF Data Anslynd Analyst limit (SW351OC) BRL 0.030 0.20 a*/l. 264460 1 0725I201813:49 UH BRL 0051 0.20 Ads 264460 1 07M2Ol813:45 UH 63.7 0 50.4-133 %REC 264460 1 0725201813:48 UH - iiX:. W. u.w:nJ.xmL S tp.L anam/awd, bvuaw'"� a �Mplylgq �a M,p(YPN WyJ,@aLld C-.Tile. MRmWI Yilue N Na rs.«wtt ♦f..�2i di+ 1 tn.;ai «IwdsaNkr. a,ro.i:e Lmi, B A.',, �. is rwrir:a n bN Pa0e Page 14 of 16 r,�l)rl\ q.yTll tt. 4ESIt �nTgDcrtt�.'ry $e8s[ns t\r 1. alert Name: Access Analytical, Inc. 2. Carrier: feclEg ❑• UPS❑ LISPS❑ Client❑ Courier❑ Other 3, 4. 5 6 7 9 9. 10. 11. 12. SAMPLE/COOLER RECEIPT CHECKLIST Yes No N/A AES Work Order Number. 18071`77 n°rant Clear Save as n.°,,.,°,. . Shipping container/cooler received in good condition? • damaged ❑ leaking iJ other❑ Custody seals present on shipping container? Custody seals Intact on shipping container? 4# Temperature blanks present? Cooler [emperaturels) within limits of 0$C? [see Rem 13 and 14 for temperature mwrdlogs.] Q O © Cooling Initiated for recently collected samples / ice present ❑ Chain of Custody(COC) present? 3Z of Custodysigned, dated, and timed when relinquished and received? • signature & date only Sampler name and/or signature on COC? Were all samples received within holding time? TAT marked on the COO • tf noTAT Indicated, proceeded with standard TAT per Terms & Conditions. 13. Cooler l Temperature 4.3 °C Cooler 2 Temperature °C Coo1er3 Temperature °C Cooler 4 Temperature °C 14. Cooler 5 Temperature °C Cooler 6 Te mperatu re °C Cooler 7 Temperature °C Cooler 9 Temperature °C 15. Comments: 16. 17. Ia. 19. 20. 21. 22. 23. 24. 25. 26. I certify that l have completed sections 1-15(dated initials). MI 7118/18 yes No N/A Details Comments Were sample containers intact upon receipt? Custody seals present on sample containers? Custody seals intact an sample containers? Do sample container labels match the COC? O O O incomplete info LJ illegible tJ no label ❑ other ❑ Are analyses requested in di ated on the COC7 Were all of the samples Ils[etl an the COC received? O © samples received but not listed on COC r samples listed an COC not received Was the sample collection date/time noted? Did we receive sufficsent sample volume for ndicated analyses? Were samples received In appropriate containers? Were VOA samples received vAthout headspace (c 1/4" bubble)? Were trip blanks submitted? I • ilsted on COC ,, not listed on [OCI 27. Comments: This section only applies to samples where pH can be el I certhly that l have Completed sections 16-27(dated Initials). Ail 7/18/19 UMCD�Note: Denan analy era require darni°al prawn Lion but mustbe checked in dw laboratory and notupon sample Rewrm pt such as GoVor, VCCs and Oil & Gmasm/ li. I certify that I have completed sections 28.30 (dated initials).Checklist 6.9.17 Rev 2 Looked Page 4 of 5 Analytical Environmental Services, Inc Date: 26-Jul-18 Client: Prism Laboratories ANALYTICAL QC SUMMARY REPORT Project Name: 8070199 Workorder: 1807F77 BOOM 264460 Sample ID: MB-264460 Client ID: Units: mg/L Prep Date: 07/252018 Run No: 376124 SampleType: MBLK TcstCode: HERBIaoES.TCLP stv13184151A Batch@: 264460 Analysis Date 0725/2018 Seq No: 9365919 ' Analylc Result RPT Limit SPK value SPK Ref Val %REC Low Limit High limit RPD Ref Val %RPD RPD Limit Qual 2A,5-TP (Silvex) BRL 0.20 2,4-D BRL 0.20 Surr. DCAA 0.3454 0 0.5000 69.1 50.4 133 I SwplelD: LCS-26446D Client lD: Units: mg/L Prep Dare: 07f25=18 Run No: 376124 SampleType: LCS TMICode: HERSICIDTB,TCLP SW131118151A BatchTD: 264460 Analysis Dam; 07f25f2018 Seq No: 9365920 Analyse Result RPT Limit SPKvalue SPKRefVal %REC Low Limit High limit RPD RefVd %RPD RPDLimit Qud 2,4,5-TP(Silvcx) 0.4206 0.20 0.5,C 94.1 49.1 119 2.4-131 0A666 0.20 0.5000 93.3 509 129 Sum. DCAA (0866 0 05000 77.3 50.4 133 Sample tD: 1807M BOIAMS Chent lD: CIMA SampleType: MS Tes"is: HEaarcnuMTcLP SM31108151A Analytc Result _ 2,4,5-TP(Silvex, 0.4494 2A-15 0.4935 Sum. DCAA 02960 ID Hy ai,: aalaw «roaieeLm, � , 6nmrid.niwdersped bi-w Fepor ., L. n:i O Ro, um a.w,rrr t,mn Units: m6/L Prep Date: 07/252018 Run No: 376124 BatchlD: 264460 Analysis Dale: 0712=19 Seq No: 9365922 RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPDLimil QaJ 0.20 D.5000 99.7 482 125 0.20 09.00 94.7 44.5 138 0 P.5600 5'I.2 50.4 133 < Lap Cyv RuitvYm E FsimNrd (vJ�e Soreq m��:.n: .ige) N M:)'smt NFlAcC mrrd a Spi4a0.mrery omide t'�r�i�•wuie mpir B M,.�x dusud in Wa rpooaetl meQedalmk :t Ho, <:nerimpfa wroptdm of rdyws ncpde! R aPn wuidelimipdueb moor Page 5 of 5 LbReISM �uepMlpa Full-Service Analytical & Environmental Solutions Town of Mooresville/RR VWVfP Whitney Munroe P. O. Box 878 Mooresville, NC 28115 NC certification No. 402 NC Drinking Water Cart No. 37735 SC Certification No. 99012 Project: Class A Dried Sludge Lab Submittal Date: 10/08/2018 Prism Work Order: 8100149 Case Narrative 10/26/2018 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: This is a Revised Report and supercedes the original laboratory report dated 10/25/18. SAR and PAN calculation sheets are now attached. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. Terri W. Cole Project Manager Data Qualifiers Key Reference Reviewed By Terri W. Cole Project Manager A LLICV recovery (125%) is greater than the upper control limit (120%). Low results might have a high bias. B Analyte is found in the associated blank at a concentration >1/2 RL. BH MB greater than one half of the RL, but the sample concentrations are greater than 10x the MB. DM Sample diluted and RL increased due to the matrix. MC Sample concentration too high for recovery evaluation. SE Surrogate recovery outside the QC limits due to emulsion. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 704/529E364-Toll Free Number: l-800/52M364- Fax: 704/626-0409 Page 1 of 16 It P R I S M I FW Environmental al Solutions s Environmental 9auuone n nwmni[g �xc Sample Receipt Summary 10/26/2018 Prism Work Order: 8100149 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received Class A 8100149-01 Solid 10/08/18 8.05 10/08/18 12:40 Samples were received in good condition at 3.0 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/629.6364 - Toll Free Number: 1-8001629-6364 - Fax: 7041626-0409 Page 2 of 16 Laboratory Report ISM I Fullironmee Anelrr 6 do !8! Envbonmantal Soletione ua 10/26/2018 Town of Mooresville/RR VWVTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 8100149-01 P. O. Box 878 Prism Work Order: 8100149 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 10/08/18 08:05 Time Submitted: 10/08/18 12:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters Plant Available Nitrogen 3900 mgtkg dry 3200 930 20 'Calculation 10M8/18 8:13 CLB [CALC1 % Solids 96.3 % by 0.100 0.100 1 'SM2640 G 10/17/18 16:42 TJY P8J0357 Weight Ammonia as N 1400 mgtkg dry 10 2.5 1 'SM4600-NH3 C 10/9/18 15:66 BMS P8J0171 Nitrate/Nitrite as N BRL mg/kg dry 5.2 1.4 1 'SM4500-NO3 F 10/17/18 9:21 CLB P8J0296 pH 6.4 pH Units 1 '9045D 10/12/18 16:49 CBP P8J0279 Phosphorus -Total 12000 mg/kg dry 260 58 100 'SM4500-P F 10/16/18 7:41 CLB PSJ0260 Total Kjeldahl Nitrogen 12000 mane dry 10000 3100 20 -351.2 10/18/18 8:13 CLB P9J0308 Microbiological Parameters Fecal Colifomrs 5 MPN/g dry 0.2 1 'SM9221 E 10/8118 13:28 Bills P&J0169 TCLP Extraction by EPA 1311 TCLP Extraction Complete N/A 1 '1311 10/12/18 8:45 MMR P8J0220 TCLP Extraction Complete N/A 1 '1311 ZHE 10/19/18 10:30 KDM PSJ0395 TCLP Metals Mercury BRL mg/L 0.010 0.000030 1 '7470A 10/16/18 1627 MMR PBJ0277 Arsenic BRL mg/L 0.050 0.0031 1 '60101) 10/16/18 14:37 JAB P6J0230 Barium BRL mg/L 5.0 0.00080 1 '60100, 10/15/18 14:37 JAB PBJ0230 Cadmium BRL mg/L 0.025 0.00015 1 '6010D 10/15/18 14:37 JAB P8J0230 Chromium BRL mg/L 0.25 0.00036 1 '6010D 10/15/18 14:37 JAB P8J0230 Lead BRL mg/L 0.050 0.00080 1 '6010D 10/15/18 14:37 JAB P8J0230 Selenium BRL mg/L 0.050 0.0056 1 '6010D 10/15/18 14:37 JAB P8J0230 Silver BRL mg/L 0.25 0.00039 1 '6010D 10/15/18 14:37 JAB P8J0230 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mg/L 0.0025 0.00017 1 '8081B 10/15/18 16:26 JMC P8J0249 Dieldnn BRL mg/L 0.00050 0.000014 1 '8081B 10115118 16:26 JMC PBJ0249 Endnn BRL mg/L 0.00050 0.000015 1 '8081B 10/15/18 16:26 JMC P8J0249 gamma-BHC BRL mg/L 0.00050 0.000013 1 '8081B 10/15/18 16:26 JMC P8J0249 Heptachlor BRL mg/L 0.00050 0.000017 1 '8081B 10/15/18 16:26 JMC P8.10249 Heptachlor Epoxide BRL mg/L 0.00050 0.000013 1 '8081B 10/15/18 1626 JMC P8J0249 Methoxychlor BRL mg/L 0.00050 0.000039 1 180818 10/15/18 1626 JMC P8J0249 Toxaphene BRL mg/L 0.025 0.000074 1 '8081B 10/15/18 16:26 JMC P8J0249 Surrogate Recovery Control Limits Decachlorobiphenyl 30 % 13-186 Tetraohloro-m-xylene 29 % 40-134 SE TCLP Semivolatile Organic Compounds by GC/MS 2,4,5-Tdchlorophenol BRL mg/L 0.25 0.0016 1 '8270D 10/16/18 18:37 JMV P8J0264 2,4,6-Tnchlorophenol BRL mg/L 0.10 0.0018 1 '8270D 10/16/18 18:37 JMV PBJ0264 2,4-Dinitrotoluene BRL mg/L 0.050 0.0014 1 '8270D 10/16/18 18:37 JMV PBJ0264 2-Methylphenol BRL mg/L 0.050 0.0018 1 '8270D 10/1a/18 18:37 JMV PBJ0264 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road -P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 7041529-6364 - Toll Free Number: 1-8001529.6364- Fax: 704/625-0409 Page 3 of 16 I ^ A Full -Service Analytical a 1 V' Environmental Solutions Apooviswumewsec Town of Mooresville/RR WWTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 10/26/2018 Client Sample ID: Class A Prism Sample ID: 8100149-01 Prism Work Order: 8100149 Time Collected: 10/08/18 08:05 Time Submitted: 10/08/18 12:40 Parameter Result Units Report Limit MOIL Dilution Factor Method Analysis Analyst Dalerrime Batch ID 3/4-Methylphenol 0.36 mg/L 0.050 0.0016 1 '8270D 10MG118 18:37 JMV P8J0264 Hexachlorobenzene BRL mg/L 0.050 0.0013 1 '8270D 10/16/18 18:37 JMV P8J0264 Hexachlorobutadiene BRL mg/L 0.050 0.0021 1 '82701) 10/16/18 18:37 JMV P8J0264 Hexachloroethane BRL mg/L 0.050 0.0017 1 '8270D 10/16/18 18:37 JMV PBJ0264 Nitrobenzene BRL mg/L 0.050 0.0026 1 '8270D 10/16/18 18:37 JMV P8J0264 Pentachlorophenol BRL mg/L 0.25 0.0012 1 '8270D 10/16/18 18:37 JMV P8J0264 Pyridine BRL ni 0.25 0.0010 1 '8270D 10/16/18 18:37 JMV P8J0264 TCLP Volatile Organic Compounds by GC/MS Surrogate Recovery Control Limits 2,4,6-Tdbromophenol 57 % 43-140 2-Fluorobiphenyl 51 % 44-119 2-Fluorophenol 39 % 19-119 Nitrobenzen"5 49 % 44-120 Phenol-d5 32 % 11-52 Terphenyl-014 58 % 50-134 1,1-Dichloroethylene BRL mg/L 0.035 0.00083 1 '8260B 10/19/18 17:57 KOM P8J0397 1,2-Dichloroethane BRL mg/L 0.025 0.00066 1 '8260B 10/19/18 17:57 KDM P8J0397 1,4-Dichlorobenzene BRL mg/L 0.38 0.00050 1 '8260B 10/19/18 1757 KDM P8J0397 Benzene BRL mg/L 0.025 0.00048 1 '8260B 10/19/18 1757 KDM P8J0397 Carbon Tetrachloride BRL ml 0.025 0.0011 1 '8260B 10/19/18 17:57 KDM PSJ0397 Chlorobenzene BRL mg/L 5.0 0.00062 1 '8260B 10/19/18 1757 KDM PSJ0397 Chloroform BRL mg/L 0.30 0.00076 1 '8260B 10/19/18 1757 KDM PSJ0397 Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.0024 1 '8260B 10/19/18 1757 KDM P8J0397 Tetrachloroethylene BRL mg/L 0.035 0.00098 1 '8260B 10/19/18 17:57 KDM P8J0397 Trichloroethylene BRL mg/L 0.025 0.00078 1 '82608 10/19/18 17:57 KDM P8J0397 Vinyl chloride BRL mg/L 0.020 0.00097 1 '8260B 10/19/18 17:57 KDM PBJ0397 Surrogate Recovery Control Limits 4-Bromolluorobenzene 100 % 80-124 Dibromo0uoromethane 99 % 75-129 Toluene-d8 93 % 77-123 Total Metals Aluminum 22000 DM mg/kg dry 620 76 100 '6010D 10/23/18 18:23 JAB P8J0276 Mercury 0.62 mg/kg dry 0.062 0.0059 3 '747113 10/23/18 11:01 MMR P8J0414 SAR Soil Preparation Complete 9 1 '2-78-054 10/16/18 12:15 MMR PBJ0289 BAR Percent Moisture 74.8 % by 0.100 0.100 1 -2.78-064 10/17/18 16:64 MMR P8J0322 Weight Arsenic BRLDM mg/kg dry 52 3.2 100 '6010D 10/23/18 18:23 JAB P8J0276 Sodium Absorption Ratio 0.80 [blank) 0.30 0.016 1 '2-78-064 10/24/18 11:29 JAB PBJ0286 Cadmium BRLDM mg/kg dry 26 0.70 100 -6010D 10/23/18 18:23 JAB PBJ0276 Calcium 19000 DM mg/kg dry 1000 24 100 '6010D 10/23/18 18:23 JAB PIIJ0276 Calcium, BAR 47 B mg/L 0.10 0.010 1 '6010D 10/24/18 11:29 JAB PSJ0286 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 -Charlotte, NC 28224-0643 Phone: 704I629-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/626-0409 Page 4 of 16 ISM Full-9ervlce AnelY lcal 6 Environmental solutions �newnrosirx isc Laboratory Report 10/26/2018 Town of Mooresville/RR VWVfP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 8100149-01 P. O. Box 878 Prism Work Order: 8100149 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 10/08/18 08:05 Time Submitted: 10/08/18 12:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date rime ID Chromium 29 DM mg/kg dry 26 4.3 100 '6010D 10/23/18 18:23 JAB P8J0276 Copper 270 DM mg/kg dry 52 4.7 100 '601013 10/23/18 18:23 JAB PSJ0276 Lead BRLA, DM mg/kg dry 26 4.8 100 '6010D 10/23/18 18:23 JAB P8J0276 Magnesium 2900 DM mg/kg dry 260 24 100 '6010D 10/23/18 18:23 JAB P8J0276 Magnesium, SAR 12 mg/L 0.10 0.0086 1 '6010D 10/2M18 11:29 JAB PSJ0286 Molybdenum BRLDM mg/kg dry 52 1.5 100 '6010D 10/23/18 18:23 JAB PBJ0276 Nickel BRLDM mg/kg dry 52 1.9 100 '6010D 10/23/18 1823 JAB PBJ0276 Potassium 3800 DM mglkg dry 1300 47 100 '601013 10/23/18 18:23 JAB PSJ0276 Selenium BRLDM mg/kg dry 52 12 100 '6010D 10/23/18 18:23 JAB P8J0276 Sodium BRLDM mg/kg dry 1600 51 100 '6010D 10/23/18 18'.23 JAB P8J0276 Sodium, SAR 23 B mg/L 0.60 0.018 1 `6010D 10/24/18 11:29 JAB PBJ0285 Zinc 670 DM mgikg dry 260 9.3 100 '6010D 10/23/18 18:23 JAB P8J0276 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 7041629-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 5 of 16 Sample Extraction Data Prep Method: 361.2 Lab Number Batch Initial Final Date/Time 8100149-01 P8J0308 0.05 g 25 mL 10/17/18 10:35 Prep Method: SM4500-NH3 B Lab Number Batch Initial Final Date/Time 8100149-01 P8J0171 1.05 g 50 mL 10/09/18 13:00 Prep Method: SM4500-PBS ,I Lab Number Batch Initial Final Date/Time 8100149-01 P8J0260 1 g 50 mL 10/15/18 10:57 Prep Method: Solids, Dry Weight I Lab Number Batch Initial Final Date/Time 8100149-01 P8J0357 30 g 30 g 10/17/18 16:42 Prep Method: 1311 Lab Number Batch Initial Final Date/Time 8100149-01 P8J0395 12.5 g 250 mL 10/18/18 16:30 8100149-01 P8J0220 100 g 2000 mL 10/11/18 15:46 Prep Method:3010A Lab Number I_ Batch Initial Final Date/Time 8100149-01 P8J0230 50 mL 50 mL 10/12/18 11:05 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 8100149-01 P8J0277 20 mL 30 mL 10/16/18 9:15 Prep Method: 3510C GC Lab Number Batch Initial Final Date/Time 8100149-01 P8J0249 1000 mL 10 mL 10/15/18 8:59 Prep Method: 3510C MS Lab Number i Batch Initial Final Date/Time 8100149-01 P8J0264 200 mL 1 mL 10/16/18 9:12 Prep Method: 6030B i Lab Number Batch Initial Final Date/Time 8100149-01 P8J0397 1 mL 10 mL 10/19/18 11:01 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 8100149-01 P8J0285 50 mL 50 mL 10/16/18 11:52 8100149-01 P8J0285 50 mL 50 mL 10/16/18 11:52 Prep Method: 3050B Lab Number Batch Initial Final Date/Time ' 8100149-01 I � P8J0276 2.02 g 50 mL 10/16/18 8:20 I This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 704/629-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/626-0409 Page 6 of 16 Sample Extraction Data Prep Method: 7471 B Lab Number Batch Initial Final DataMnie 8100149-01 P8J0414 0.61 g 50 mL 10/23/18 7:35 Prep Method: SAR 2.78-064 Lab Number Batch Initial Final Datenrima 8100149-01 PSJ0289 250 g 250 9 10/15/18 12:15 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Number Analysis 8100149-01 Herbicides TCLP(Sub) This report should not be reproduced, except in its entirety, without the wntten consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 -Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041525-0409 041525-0409 Page 7 of 16 -PRISM 1...1oleES,N4 Full -Service Analytical & Environmental Solutions 449 Springbrook Road - Charlotte, NC 28217 Phone 704/5296364 - Fax: 7041525-0409 Client Company Name: quw, oih-uvMt Report To/Contact Name: Reporting Address: P-D SUtiiL d$ CHAINnn OF CUSTODY RECORD PAGE I OF r2 OUOTE 0 TO ENSUP PROPER SILLIN : Project Name: } ItiSft ti'd �w Z Short Hold Analysis: es (No UST Pr act: (Yee) O) *Please ATTACH any prOJIFIR specific reporting (OC LEVFOII III rvr provisions andlor OC Requirements Invoice To: TtMti of MDU(75v1� Address: Samples INTACT upon arrival? Received ON WET ICE? PROPER PRESERVATIVES indicated? Received WITHIN HOLDING TIMES? CUSTODY SEALS INTACT? VOLAT/LES need WlOUT HEADSPACE? PROPER CONTAINERS used? YES NO WA -_°C / Con: —I- a -- Phone: Tug -taus- -,Xow taxIyes) trio): Purchase Order No.IBilling Reference Email Address: W mvifkA•YYVGOKbU �L :NC - In8 Requested Due Date O 1 Day ❑ 2 D ys ❑ 3 Days 0 a Days O 5 Days EDD Type: PDF_Excel_Other Rush Work Must Be YP "Working Days" ❑ 6-9 Days Stantlard 70 days ❑ pre -Approved Site Location Name: Samples recelved after 14:00 will be processed next business day. Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. (SEE REVERSE FOR TERMS a CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) TO BE FILLED IN BY CLIENTISAMPLING PERSONNEL Certification: NEIAC_ DOD FL NC_ SC 071'IER NIA Water Chlorinated: YES_ N-O-Z� Sample Iced Upon Collection: YES ✓NO CLIENT DESCRIPTION DATE COLLECTED TIME COLLECTED MILITARY H3JSAMPLE URS MATRD( (SOIL, WATER OR SLUD11G� SAMPLE CONTAINER PRTrVES - TNES ANALYSIS REQUESTED L ` �° �F� % Es99 ,Q y PRISM �sj' y ��(((V p�/ _ .[+y REMARKS LAB tg°/j�` yo�, i fij ID NO. gypE � SEE BELOW NO. SIZE n n Sampler's Signatu Sampled By (Print Name) �-� r Affiliation Tout.. Upon relinquishing, this Chainlif Custody Is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be chkrges for any changes after analyses have been initialized. ( neN a y (Ignalu eta pp. AddRlDnal Comments. site Arrival Time: 9 0-(5 Wy% ReMy By (Sigd By: (Signature) Date Site Departure Time ReflaQuideed By: (Signature) Recelved For Pdsm Lahw By ate Field Tech Fee'. C 6 W � � ( I-b Mileage: MaarodafSNpmenl NO LL A LE COOLERS SHOULD BE TAPED SHUT WITH CUSTODY SEALS FOR TRRR��#NNNSP ATION TO THE ORATORY. c5uilrm SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST CDC UNTIL RECEIVED AT THE I/ABORATORY. r)- 'I/( �00I� P ❑ Fed Ex D UPS ❑ HandEElivered rism Field Service ❑ OIMr / •)I(NC L3 UST. GROUNDWATER: DRINKING WATER: � ifNCSal U SWASC E. ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC LANDFILL❑ SC ❑ OTHER: ❑ SC 7�1C U SC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC j5( ERWRWRO *CONTAINER TYPE CODES: A = Amber C = Clear Get Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) SO ,�N(�EB: CHAIN OF CUSTODY RECORD LAB USE ONLY YES NO � WA o /PRISM I Full -Service Analytical 8 Solutions � OF � QUOTE a TO ENSURE PROPER BILLING: Environmental PAGE Samples INTACT upon arrival? .& wowaoase iac Project Name: R2K 61VDj!4 Received ON WET ICE? m 449 Springbrook Road • Charlotte, INC 28217 Short Hold Analysis: (Yes) (NO UST Pro (Yes) (NO) Phone 704)529-6364 • Fax: 704I525-0409 PROPER PRESERVATIVES indicated? N `` A� 'Please ATTACH any project specific reporting (QC LEVEL 1 II III IV) Received WITHIN HOLDING TIMES? Client Company Name: S�uH. •t NlOQKSTA� provisions and/or QC Requlr.=menfs p CUSTODY SEALS INTACT? a Report To/Contact Name: � �zV.w Yill.tflftrQ.- Invoice To: uW1,yA' iV 1 OL�L�h' � VOLATILES i W/OUT HEADSPACE? Reporting Address: LS�S�-- Address' PROPER CONTAINERS used? �C kl��1i �Z— Z�1 1 TEMP: Therm I I RI-1 Observed: 3 • I °C I COrr t Phone:101,1 0W-3 4b Fax(Yes) (No): Purchase Order No./Billing Reference TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL AA Email Address: WMLtY♦f�'eF� CA•rW:OCat,;LNi . I �- tAS Requested Due Date 01 Day ❑ 2 Days ❑ 3 Days 04 Days 05 Days Certification: NELAC_ DoD_ FL_ NC� EDD Type: PDF Excel Other Rush Work Must Be _ "Working Days" 06-9 Days ❑ Standard 10 days O PreApproved SC_ OTHER N/A Site Location Name: Samples received after 14:00 will be processed next business day. business days, and holidays T Water Chlorinated: YES_ NO v Site Location Physical Address: Turnaround time is based on excluding weekends (SEE REVERSE FOR TERMS S CONDITIONS REGARDING SERVICES �O RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sam le Iced Upon Collection: YES p P CLIENT DATE TIME COLLECTED MATRIX ($OIL, SAMPLE CONTAINER PRESERVA- 'TYPE TIVES PSIS REQUESTED • r ' REMARKS PRISM LAB SAMPLE DESCRIPTION COLLECTED MILITARY WATER OR NO. SIZE ID NO. HOURS SLUDGE) SEE BELOW Ass g FS:D Soil Oc Sampler's Signature Sampled By (Print Name) P ra c t Affiliation O6tM.i Upon relinquishing, this Chain 6fbistody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. Re wen By: I i9nawre) e y ( onaw aN � Additional Comments: f/ She Arrival Time: In i agnature) e o-� ,V IA2y y: Dee, Site Departure Time: Field Tech Fee: Relin - ed By: (Signaw Rocoived er Pdsm Labatatoriez'By a y-- It-8-1$ IttiV Mileage: MetxA of ShipmenC NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH CUSTOOYSEALS FOR TYANbFUN TO LABORATORY701NI—M N. SAMPLES ARE NOTACCEPTED AND VERIFIED AGAINST CDC UNTIL RECEIVED AT TX LABORATORY. 11'0o I YXVU. O Fed Ex CUPS O Hand4elivered Pram Field Service O Omer 1 1 UST. GROUNDWATER: DRINKING WATER: I R . LANDFILL OTHER: C❑SC ❑NC El SC ❑NC ❑SC ❑NC ❑SC N ❑SCE. ❑ SC ❑ERCLA NC O SC ❑ SC i ❑ ❑ SC *CONTAINER TYPE CODES: A=Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA= Volatile Organics Analysis (Zero Head Space) Main Office: 449 Springbrook Road P:R I S M Full Sorvica Analytical and P.O. Box 240543 Environmvnial Solutions Charlotte, NC 28224-0543 i WIAraieawa Phone: 704/529-6364 1/800/529-6364 Fax: 7041525-0409 www.prismiabs.com Sodium Absorption Ratio The amount of exchangeable sodium ions versus the amount of exchangeable calcium & magnesium ions in a given material. Sample Number 8100149-01 Sample Nannel Class A Na: Sodium (mg/L) Equivalent weight: 23 Ca: Calcium (mg/L) Equivalent weight: 20 Mg : Magnesium (mg/L) Equivalent weight: 12 Milli Equivalent (ME) = mg/L / Equivalent weight Nam /L Cam !L M m !L 23.4 47.4 12.4 Na (ME) Ca (ME) Ma (ME) 1.02 1 2.37 1 1.03 SAR= Na Milli Equivalent/[0.5 X (Ca Milli Equivalent+ Mg Milli equivalent)]0.5 power SAR = 0.8 (From mg/L entered above) Calculated By:ie'44-d Page 10 of 16 Main Office: ! ' Full Servico Analytical and 449 Springbrook Road �1 i Environmental Solutions P.O. Box 240543 ' l ur nr.r,.; :c_ aic. Charlotte, NC 28224-0543 Phone: 704/529.6364 118001529-6364 Fax: 704/525-0409 www.prismiabs.com Plant Available Nitrogen Sample Number s1oo14s-o1 Sample Name Class A Mineralization Rate TKN NH3 NOX mg/kg mglkg mg/kg 0.3 12000 1 1400 1.7 PAN 3,900 1 mglkg MR(TKN-NH3)+ 0.5(NH3)+NOX = PAN mg/kg Calculated By: Page 11 of 16 ACCESS ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte NC 282240543 ATTENTION Terri W. Cole PROJECTID 8100149 LABORATORY REPORT NUMBER 1810954 DATE October 18, 2018 Primary Data Review By Secondary Data Review By % Ashley Amick Chris Pafford Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com axs-inc.com PLEASE NOTE: Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, CA 30340. AES is SCDHEC certified laboratory N 98016, NCDENR certified lab N 562, CA certified lab N FL-E87582, NELAP certified laboratory N E87582 AI1IA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCM Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781 4243 or toll fee at 883.315.4243 Page Page 12 of 16 PRISM I Full -Service Analytical 8 p�frf//T Environmental Solutions SENDING LABORATORY: Prism Laboratories, Inc. P. O. Box 240543 Charlotte, NC 23224-0543 Phone:800-529-6364 Fax: 704.525.0409 Project Manage- Terri W. Cole I�10gq SUBCONTRACT ORDER rliftcntion NELAC._ USACE Prism Laboratories, Inc. NCSC^ Other 8100149 N/A_ RECEIVING LABORATORY: Analytical Environmental Services, Inc. 3080 Presidential Parkway Atlanta, GA 30340 Phone :(770) 457-8177 Fax: NA Analysis Due Expires Laboratory ID Comments Sample ID: 8100149-01 Solid Sampled:l0/08/1808:05 CI�S.S Herbicides TCLP (Sub) 10/15/18 09:05 Containers Supplied: 1 L'i--i;Ar Cyt a'r Ruleased By Dote Rceeive d By Date Page I oft Page Page 13 of 16 Analytical Environmental Services, Inc Due: IS-Oct-18 Client: Prism Laboratories Client Sample ID: CLASS A Lab Order 1910954 Tug Number: 8100149-01 Project Name: 8100149 Collection Date: 10/8/2018 8:05:00 AM Lab ID: 1810954-OOIA Matrix: Solid Analyses Result Reporting y Qual MOL Limit Units BetchlD DF Date Analyzed Analyst HERBICIDES,TCLP SW1311/9151A 2,4,5-TP (Silvex) BRL 2,4-D BRL Surr. DCAA 87 Q„Yiae.v • Nlue nendsmnimum e.mamimni levA aRL Nn Dmened.,MUL H Hddina limn l.r pmpmnim m... I,.. neeedml N Arolya n., NELAC ttmried B Anodyne de..IM in tine Hammed nisei dbink (SW3510C) 0.030 0.20 mall. 268729 1 10/162O18 15:56 HB 0.051 0.20 myL 268729 1 10/16201815:56 HB 0 50.4-133 %REC 268729 1 10/16201815:56 HB E ENimnled tali. nbnw..... i,..— ran, S Spike Re ,nmad. l imila duel. mp,nx > Grener,hen Rnuli value 1 Ealimeed value dne W.w Rep.ninR L,mi, < L. dun Rn.11 W. Page Page 14 of 16 (SIANALITICAI. $NITRONatGNTAt. AES SERVICES. INC. 1. Client Name: Access Analytical, Inc. SAMPLE/COOLER RECEIPT CHECKLIST 2. Carrier: FedEv❑e UPS El USPs❑ Client Courier[—] Other Yes No N/A Details AES Work Order Number: 1810954 Clear Save as Comments Shipping container/cooler received in good condition? • damaged [] leaking ❑ other[] Custody seals present on shipping container? Custody seals intact on shipping container? Temperature blanks present? Cooler temperature(s) within limits of 0-IYC? [See item 13 and 14 for temperature recordings,] O ® O Cooling initiated for recently collected samples / ice present ❑ Chain of Custody (CDC) present? Chain of Custody signed, dated, and timed when relinquished and received? Sampler name and/or signature on COC? Were all samples received within holding time? TAT marked on the CDC? • D no TAT indicated, proceeded with standard TA7 per Terms & Conditions. Ll 13. Cooler 1 Temperature 0.5 °C Cooler 2 Temperature oC Cooler 3 Temperature oC Cooler 4 Temperature °C 14. Cooler 5 Temperature DC Cooler 6 Temperature oC Cooler 7 Temperature °C Cooler 8 Temperature °C 15. Comments: 16. 1T 18. 19. 20. 21. 22 23. 24. 25. 26. certify that I have completed sections 1-15 (dated initials). All 10/10/18 Yes No N/A Details Comments Were sample containers Intact upon receipt? Custody seals present on sample containers? Custody seals intact on sample containers? Do sample container labels match the CDC? O O O incomplete info ❑ Illegible ❑ no label ❑ other ❑ Are analyses requested indicated on the CDC? Were all of the samples listed on the COC received? O O O amples received but not listed on CDC El Samples listed on COC not received ❑ Was the sample collection date/time noted? Did we receive sufficient sample volume for Indicated analyses? Were samples received in appropriate containers? Were VOA samples received without headspace I< 1/4" bubble)? Were trip blanks submitted? • listed on CDC ❑ not listed on CDC ❑ 27 Comments. This section only applies to samples where pH can be certify that I have completed sections 16-27 (dated initials). AP 10/10/18 CD ' Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms. VOCs and Oil & Grease/1-PH. !n I certify that I have completed sections 28-30 (dated initials). AP 10/10/18 Checklist 6S.17 Rev 2 Locked M Page 4 of 5 Analytical Environmental Services, Inc Client: Prism Laboratories Project Name: 8100149 Workorder: 1810954 Date: 18-Oct-18 ANALYTICAL QC SUMMARY REPORT BatchID: 268729 Sample TD: NIB-268729 Client ID: Units: mg/L Prep Date: 10/15/2018 Run No: 382404 SampleType: NIBLK TestCode: HERBICIDES, TCLP SW1311/8151A BatchID: 268729 Analysis Date: 10/16/2018 Seq No: 8530650 Analyte Result RPT Limit ' SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) BRL 0.20 2,4-D BRL 0.20 Surr: DCAA 0.3772 0 0.5000 75.4 50.4 133 Sample ID: LCS-268729 Client ID: Units: mg/L Prep Date: 10/15/2018 Run No: 382404 SampleType: LCS TestCode: HERBICIDES, TCLP SW1311/8151A BatchID: 268729 Analysis Date: 10/16/2018 Seq No: 8530651 Analyte Result RPT Limit SPK value SPK Ref Val %RFC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) 0.5181 0.20 0.5000 104 49.1 119 2.4-D 0.4757 0.20 0.5000 95.1 5019 129 Surr: DCAA 0.4876 0 0.5000 97-5 50A 133 Sample 1D: 1810954-001ANIS Client ID- CLASS A Units: mg/L Prep Date: 10/15/2018 Run No: 382404 SampleType: NIS TestCode HERBICIDES,TCLP SWI31118151A BatchlD: 268729 Analysis Date: 10/16/2018 Seq No: 8530653 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qua[ 2,4,5-TP (Silvex) 04125 0.20 0.5000 82.5 48.2 125 2.4-D 0.4034 020 0.5000 807 44,5 138 Surr: DCAA 0A065 0 0.5000 813 50A 133 Qualifiers: - Greater than Result value c Less Than Result value B Analyte defected in the associated method blank (Q BRL Below re rim • limit E Estimated value above uantitaiian ran e H Holding times for preparation or analysis -ded CD Po b � 9 g) g P Pa Y J Estimated value detected below Reporting Limit N Analyte not NELAC certified R RPD outside limits due to matrix 0 Rpt Lim Reporting Limit S Spike Recovery outside limits due to matrix JPage 5 of 5