DEQ-CFW_00088481

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DEQ CFW-0 0088 a]

Form D: Process Information (Page 1 of 2) Facility ID# 0900009
North Carolina Department of Environment and Natural Resources
Division of Air Quality
1998 Annual Air Pollutant Emissions Inventory
1. Source ID No(s): Waste Hydrocarbon Storage Tank 2. Permit Item No(s): Insignificant Activity
3. Process Description: "Nafion"Waste Hydrocarbon Storage Tank
4. Operational Schedule:
Hour per
Day
Day per
Week
5. Start Hour of Process: Continuous
6. Percentage Annual Throughput:
Dec -Feb 25
7. Maximum Process
Rate per Hour: (ex:
gal/hr, mmcf/hr)
Mar -May 25
180 lb/hr
include units
Weeks per
Year
June -Aug 25
8. Annual Process
Throughput:
(ex: lb/yr, gal/yr)
9. Capture Efficiency (% of Process Emissions Vented Through Control Device): n/a
10. Control Device Descriptions Primary None
Secondary
11. Combined Control Device Efficiency (%): n/a
12. ANNUAL FUEL USAGE (e.g. Coal, oil, wood, natural gas, etc.) - Use additional sheets if necessary
•
Hours per g,760
Year
Sept -Nov 25
22,951 lb
include units
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DEQ-CFW 00088482

a •
Form D: Process Information (Page 2 of 2)
Facility ID# 0900009 Source ID # Waste hydrocar
•
0
0
Actual Emissions per Pollutant Listed for Source Described Above:
Attach calculations and documentation of emission factors or other estimation methods used.
"Per Ton" Pollutant:
TSP
PM-10
SO2
NOx
VOC
CO
0%
ual Emissions: Tons/year
F
0.05
***All Other HAPs/TAPs as listed in Appendix C or Appendix D (use additional sheets if necessary)***
n 3q..
y•`s; S ;sz:. 3x ... ..:.. ::: x:�
Chlorine
: x ar �^y r1 �" .L.;. s •r .{
a 1., s� .::..�P � � .&� .�& 3�
7782-50-5
_ 3fa��-.r,
��: , ..,aa`� Z u,.,�11� ti, o.:w ?
xt...F.S x�S�N�a m. ' .. t �6.�. s� W
Fluorine
7782-41-4
Hydrazine
302-01-2
Hydrogen Chloride
7647-01-0
Hydrogen Fluoride
7664-39-3
Hydrogen Sulfide
7783-06-4
Lead Compounds
LEADCPDS
Methyl Chloroform
71-55-6
Methylene Chloride
75-09-2
Ozone
10028-15-6
Perchloroethylene
127-18-4
Phosphine
7803-51-2
Toluene
108-88-3
0
Acetonitrile
75-05-8
11.4
Diethylene glycol ether
GLYCOLETHERS
0.4
IL
Information on Page 2 of Form D cannot be held confidential.
DEQ-CFW 00088483

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1998 WASTE HYDROCARBON STORAGE TANK EMISSIONS
BASIS: Direct Vent to Atmosphere
Tank Volume = 400 gallons = 53.5 ft3
Cool/Heat Range = 707 (night) to 1407 (day)
DISPLACED VOLUME FOR WASTE TRANSFERS
22,951 lb. I gallon 1 ft3 12 transfers = 736 ft3
year 1 8.33 lb 1 7.48 gal I year
Note: (2 transfers = 1 •to tank and 1 to drum)
BREATHING LOSS FROM HEAT/COOL CYCLES
Assume tank averages half full
V1 = V2 or 26.7 ft3 = V2
Tl T2 70 + 460 OR 140 + 460 OR
Breathing Loss = (30.3 — 26.7) ft3 1 365 day = 1314 ft3
day I year year
Total Volume Loss = 736 ft3 + 1314 ft3 = 2050 ft3
year year
EMISSIONS:
Acetonitrile:
1359 ft' 1 760 mm Hg I mole 1 22,951 lb Total
.•. V2 = 30.3 ft3
= 11.4 lb. AN
Toluene:
Toluene waste is drummed out directly from the operating equipment and does not
pass through the waste hydrocarbon tank.
DiGlyme: -
2050 ft3 1 mole 1 1.7 mm Hg 1 134 lb 1 5392 lb DG = 0.4 lb DG
359 ft3 1 760 mm Hg I mole 122,951 lb Total
Adiponitrile:
1 359 ft' 1 760 mm Hg I
VOC Emissions = 12.01 lb.
Fugitive Emissions = 85.15 lb.
Total Emissions = 97.16 lb.
34 lb 1 5,891 lb ADN = 0.21 lb ADN
mole 122,951 lb Total
DEQ-CFW 00088484

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Fl1;PPIVE ENISSICM FUN W%E WKS P1•RIP1Oft
WMW ((8/YR)
wr F/C
S'mG Im WST F/C RX 4X Wgr F/C
SHIP 7K
NH*R
OGSSICNS 1a144m
E1MLSSICNS NIM
FMI55 O S
MAN VW 48
At1l0 VLV 2
163.987 24
6.833
81.994
27
92.243
U4( Vl.V 4
1
13.666
3.416
0.000
1
3.416
WM FIB 25
1.577 14
3.154
10
0.000
Ift m971•R.S 3
3.154 2
1.577
0.000
Ft (IUFIMH I
'1
1.577 2
0.000
1
3.154
F1.1'1'1N, 100
RM 1
1.5lI 24
10.074
0.000
2
10
1.577
0.000
EZL'�R 2
1
0.000
10.074
0.000
1
10.074
TfENHXDJPIE 1
RUP`W DIX IUD 2
0.000 2
0.000
0.000
0.000
0.000
3 VAY VLV 1
1
3.416
0.000
0.000
2
.
PRESS GAL£ 1
0.000
0.000
1
33.441616
PIPE LNICN
0.000
1
0.000
KL9C M P
o.000
o.000
0.000
c�vATTCN VFMP
0.000
70ft (1B/YR)
205.860
100.214
111M MW/YMO
0.1029
0.0501
113.880
0.0569
WIE: LXfXX►t WU.VIld►c
factors were used for all emission
Flame enissior>s factors were used for all
calculation.
equip eooept valves
and pulps.
0
m
p
C�
m
I
0
0
0
00
00
00
Ti � • •gar
37
126.407
3
10.249
2
6.833
1
3.154
7
0.000
0.000
44
0.000
1
10.074
1
4.730
2
0.000
0.000
0.000
0.000
1
0.000
3
0.000
161.447
0.0807
H/C S1G 7K
WN R
EKISSIC c
12
40.997
2
6.833
0.000 j
7
1.577
1
0.000
0.000
j
0.000
0.000 '
1
1.577 ;
0.000
0.000
1
0.000
0.000
0.000
1
32.587
85.147
0.0426
•
[I'm sin N '11;
18
61. 4q ;
0.M
2
6.831
4
o,oW
1
O.Ux►
u .1x,u
U. u►x►
1
IU.UIi
1.5'l7
1.571
O.000
O.Ow
O.000
O.Ow
1
O.000
1
•32.5b7
114.143
u.o.�11