HomeMy WebLinkAboutDEQ-CFW_00088255DEQ-CFW-00088255
Form D: Process Information (Page 1 of 2) Facility ID# 0900009
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Calendar 2000 Air Pollutant Point Source Emissions Inventory
1. Source ID No. (same as in permit) Waste DMSO Storage Tank
Nafion® Waste DMSO Storage Tank
2. Process Description:
4. Maximum Process Rate: 4. CY 2000 Process Throughput:
(Ex: gal/hr, mmcf/hr) Confidential (Ex: lb, gal)
include units
5. Normal Operating Schedule:
Hours per Days per
Day Week
6. Typical Start & End Times For Process:
7. Percentage Annual Throughput:
Dec -Feb 25 Mar -May
Weeks
per Year
Hours per
Year
Start: Continuous End:
Confidential
include units
Confidential
25 June -Aug 25 Sept -Nov 25
8. Capture Efficiency (% of Emissions from this Process Vented Through Control Device): N/A
9. Control Device Descriptions Primary None
Secondary:
10. Combined (Net) Control Device Efficiency (%):
(Control efficiency is pollutant specific)
PM
PM-10
PM-2.5
SO2
NOx
VOC
N/A
1 1 _ ANNIIAL FI1FL IISAGF For This Process (Coal- oil_ wood_ natural gas. etc.) -Use additional sheets as needed.
Type of Fuel Used in This Process/Source Amount (gal, tons, mmcf/year) % Sulfur % Ash
If you do not provide annual throughput your inventory will be deemed incomplete and returned to you
To review instructions or get a new copy, go to web page: htti)://dag.state.ne.us/Ofrices/Planniniz/Attainment/est.html or
http: //d ag.state.ne. us/Offices/Plann in2/Attainment/ 1999/99forms.htmi
Information on Form D cannot be held confidential.
DEQ-CFW 00088256
C
Form D: Process Information (Page 2 of 2)
CY 2000 Facility ID# 0900009
Actual Emissions per Pollutant Listed for Source/Process Identified Above:
Attach calculations and documentation of emission factors or other estimation methods used.
Source Waste DMSO
ID# Storage Tank
"Per Ton" Pollutant:
PM
PM-10
PM-2.5
S02
Nox
VOC
CO
Actual Emissions: Tons/year
0.08
***All Other HAPs/TAPS Per Instructions (use additional sheets if necessary)***
Pollutant
CAS #
Emitted
lbs./ r.
Comments
Chlorine
7782-50-5
Fluorine
7782-41-4
Hydrazine
302-01-2
Hydrogen Chloride (As weight of HCl in solutions)
7647-01-0
Hydrogen Fluoride (As weight of HF in solutions)
7664-39-3
Hydrogen Sulfide
7783-06-4
Lead (As metal or compounds -mass of total)
LEADCPDS
Methyl Chloroform (Not a VOC, by rule)
71-55-6
Methylene Chloride (Not a VOC, by rule)
75-09-2
Ozone (Not expected as a facility emission)
10028-15-6
Perchloroethylene (Not a VOC, by rule)
127-18-4
Phosphine
7803-51-2
List all other HAP/TAPS below IN ALPHABETICAL
ORDER, Per Instructions.
Use more sheets, as needed
E
Information on Form D cannot be held confidential.
DEQ-CFW 00088257
iWASTE DMSO STORAGE TANK EMISSIONS
BASIS: Direct vent to atmosphere
Tank volume = 6,000 gallons = 802 ft3
DMSO vapor pressure = 0.5 mmHg at 20°C
Assume one complete tank volume turnover per day
Mole fraction DMSO in vapor: 0.5 mmHg = 0.00066 mole DMSO
760 mmHg mole gas in tank
Pounds of DMSO per tank volume:
802 ft3 I lb mole 1 0.00066 mole DMSO 1 78 lb DMSO = 0.11 lb DMSO
tank volume 1 359 ft3 ( mole gas in tank I mole DMSO tank volume
Total DMSO emissions per year from tank volume turnovers:
0.11 lb DMSO I tank volume 1 365 days = 42 lb DMSO per year
tank volume I day I year
Total Emissions = Turnover Emissions + Fugitive Emissions
42 lb/yr + 1141b/yr = 1561b/yr = 0.08 ton/yr VOC Emissions
•
DEQ-CFW 00088258
i
FucrrM D41S'S'(M FM4 *ME TMM PEPIMMI. WROM (IBIWJ
WT F/C SIG TK
WSr F/C RX 9K
t4t4O
EMSSIQyS
NM M
E?WICNS
11M1 Vi1/
48
163.987
24
81.994
AM vW
2
6.833
1
3.416
Cm AM
4
13.666
0.000
WO FIG
7 WOOT
25
1.577
14.
3.154
RS
Fitti1(> uylCE
3
l
3.154
1.577
2
1.577
'w Fn'IM
100
1.577
2
24
0.000
RM
1
10.074
1
0.000
10.074
FLTM
2
0.000
0.000
li m
1
0.000
2
0.000
talt?'I M DISC 1111)
2
0.000
1
0.000
3 MAY VW
1
3.416
0.000
FMS GM£
1
0.000
0.000
PIPE tmn
m9` SUP
0.000
0.000
Iw vEt�rr
0.000
WST F/C SQP 4K
27
92.243
1
3.416
0.000
10
0.WO
1
3.154
2
1.577
10
0.000
1
10.074
0.000
0.000
2
0.000
1
3.416
0.000
1
0.000
0.000
IOM• «ems 205.860 l00.214
IML �m1 0.1029 0.0501 113.880
0.0569
KM U{xtit ewtilleft factors were %yeti for all emission calculations.
Flange eaimicos factors were used for all equip evept ve1vw and pqx.
0
m
p
C�
m
I
0
0
0
00
00
N
�: _
37
13.407
3
10.249
2
6.833
1
3.154
7
0.000
0.000
44
0.000
1
10.074
1
4.730
2
0.000
0.000
0.000
0.000
1
0.000
3
0.000
161.447
0.OW7
WC = 7K
UMM EMSSICNS
12 40.997
2 6.831
0.000
7 1.577
1 0.000
0.000
1.577
0.000
0.000
1 1.577
0.000
0.000
1 0.000
0.000
0.000
1 32.587
85.147
0.0426
18 61.44,,
O.UUU
2 6.811
4 0.000
1 O.UOu
U.000
0.000
1 10.014
1. ` TI
1. `S7)
u.OW
O.Ow
0.000
O.Ow
1 0.000
1 32.5b1
114.141
U.U911
A 8
C
OUPONT EX:SS:ON FACTORS
COMPONENT
SERVICE
PUMP SEALS
LIGHT LIQ.
HEAVY LIQ.
VALVES
GAS
LIGHT LIQ
HEAVY LIQ
PRESSURE
GAS/VAPOR
RELIEF SEALS
OPEN END LINES
ALL
FLANGES
ALL
SAMPLING
ALL
CONNECTIONS
COMPRESSOR
GAS/VAPOR
SEALS
jWRALL EMISSION
FACTOR
0 E
F
G
H
I
so
EXISSION.FACTORS
(Ld/HR)
SUPERIOR
EXCELLE
GOOD
EPA
.XN-X=
0.00115
0.0075
0.109
55
. XY-X=
0.00115
0.0075
0.047
.xxxxx
0.00039
0.00542
0.012
.xxxux
0.00036
0.00352
0.016
.XXXXX
0.00036
0.00352
0.00051
60
.xxxxx
0.00012
0.00013
0.23
.XX3=
0.001
0.0215
0.0037
65
.)cxxxx
0.00018
0.00031
0.0018
.XXXXX
0.00018
0.00031
0.033
70
N/A
N/A
N/A
0.50
1/10000
1/20
1/3
1/1
75
V
DEQ-CFW 00088260