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Laboratory Emissions
A. VOC Emissions
Permitted limit (lb)
Density
kg/L.
12-month
Total
Reporting
Quarter
Air Emission Compound
1 Q05
2005
3Q05
4Q05
Bromine
2.92lb/hr
3.12
8.8
4.4
4.4
Chloroform
6,882 Ib/yr
1.3
1.3
Ethyl Acetate
2,046 Ib/hr
0.902
11.9
11.9
n-Hexane
965lb/day
0.6594
2.9
2.9
Hydrogen Chloride
10 Ib/hr
1.16
15.3
15
Triethylamine
n/a
0.726
73.5
73.5
Total VOC emissions (lb) 113.7
Total VOC emissions (tons) 0.06
B. TAP Emissions
Permitted limit (lb)
Density
kg/L
12-month
Total
Reporting
Quarter
Air Emission Compound
1Q05
2Q05
3Q05
4Q05
Bromine
2.92lb/hr
3.12
8.8
4.4
4.4
Chloroform
6,882 lb/yr
1.3
1.3
Ethyl Acetate
2,046 Ib/hr
0.902
11.9
11.9
n-Hexane
965 lb/day
0.6594
2.9
2.9
Hydrogen Chloride
10 Ib/hr
1.16
15.3
1
1 15
Riverwater Chlorine Fugitive Emissions Basis
Equipment Component
River
Water
Service
Domestic
Water
Service
Total
Components
Excellent Rating
(lb/hr/component)
Service
(hr/yr)
Emissions
(Ib/yr)
Angle Valves
1
1
2
0.00039
8760
7
Pressure Relief Seals
0
0
0
0
Open Ended Lines
0
0
0
0
Connections including fusible plugs
33
3
36
0.00018
8760
57
Sampling Connections
0
0
0
0
Total Pounds of Chlorine 64
7-1
QUESTIONS FOR DETERMINING UNIT -SPECIFIC FACTOR CATEGORY
1. Are techniques available and used to routinely locate specific leaks? Examples include SO2 bombs, ammonia solution, special detectors (such
as those for HCN or phosgene), chemical badges, and sniff testers.
Yes
2. Do you perform leak checks in this process area at least once per day?
Yes, Continous Monitor.
3. Are specific procedures used on each start-up to minimized fugitive emissions? Examples include hydrostatic tests, special leak tests, etc.
Yes
4. Do you have a documented check list startup procedure that helps locate routine leaks?
Yes
5. Do you have a formal procedure that requires leaks be repaired in a timely manner, including use of overtime if necessary?
Yes