DEQ-CFW_00087405

Nafion(R) Membrane Treatment
Emission source/Operating Scenario Data
1. Emission Source ID No.
Air Emissions Inventory
Actual emissions per pollutant listed for source/process identified on page 1:
Page 2 of 4
Criteria NAAQSpollutants
Pollutant
code
Emissions -Criteria pollutants tons/
Emission
estimation
method
code
control
efficiency
2001
2002
2003
2004
2005
Carbon Monoxide
CO
0
0
0
0
0
8
NOx
NOx
0
0
0
0
0
8
TSP
TSP
0
0
0
0
0
8
PM 2.5
PM-2.5
0
0
0
0
0
8
PM 10
PM-10
0
0
0
0
0
8
SO2
SO2
0
0
0
0
0
8
VOC
VOC
18.8
9.3
9.6
5.1
1 13.0
8
0%
HAPITAP pollutants
CAS #
Emissions HAPPTAPs Ibs/ yr
Acetic Acid
64-19-7
50.1
78.3
166.0
257.9
353.8
8
0%
[Hydrogen Fluoride
7664-39-03
96
89
66
89
88
8
0%

Nafion(R) Membrane Treatment Air Emissions Inventory
Page 3 of 4
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•
•
NS-H Membrane treatment (extrusion & hydrolysis) summary report.
DMSO Emissions yr Units 2004 values 2005
Waste Shipped Ibs/yr 1 0 77420 1
Waste in storage tk yr end gallons 1734 591.6
Waste in storage tk yr end Ibs 17687 6034
Waste % in storage tk yr end % 29% 10%
DMSO Waste Content wt% 11 % 11 %
DMSO Shipped as Waste liquid Ibs/yr 1946 9180
% change -90.9 371.8
DMSO pumped to waste treatment Ibs/yr
DMSO Inventory
inv. Begin year
drums,
inv. End year
drums
DMSO Drums Rec
drums
Wt/Drum
lb/drum
total DMSO consumed
Ibs
% consumption change
%
DMSO Emissions into air
Ibs/yr
DMSO Emissions into air
tons/yr
% change
Acetic Acid Emissions air
1 st Quarter
hrs
2nd Quarter
hrs
3rd Quarter
hrs
4th Quarter
hrs
Total
hrs
Acetic Acid Emissions Rate
Ibs/hr
Acetic Acid HAP/TAP Emissions
Ibs/yr
% change
Total VOC Emissions Ibs/yr
Total VOC Emissions tons/yr
% change
13599 13599
16
21
21
12
56
84
5uu
Ozu
25500
48360
-48%
90%
9956
25581
5.0
12.8
-47.5
156.9
68.5
28.6
93.3
154.8
9U.2
198.88
103.0
104.7
355.0
46 (.0
0.727
0.727
257.9
353.8
55.4
37.2
10214 25935
5.1 13.0
-46.6 153.9
DEQ-CFW 00087406

Nafion(R) Membrane Spraybooth Air Emissions Inventory Page 2 of 4
Emission source/Operating Scenario Data
1. Emission Source ID No. NS-1
Actual emissions per pollutant listed for sourcelprocess identified on page 1:
Criteria (NAAQS) pollutants
Pollutant
code
Emissions -Criteria pollutants tons/
Emission
estimation
method
code
control
efficiency
2002
2003
2004
2005
Carbon Monoxide
CO
0
0
0
0
8
NOx
NOx
0
0
0
0
8
TSP
TSP
0.13
0.15
0.17
0.15
8
0%
PM 2.5
PM-2.5
0.13
0.15
0.17
0.15
8
0%
PM 10
PM-10
0.13
0.15
0.17
0.15
8
0%
S02
S02
0
0
0
0
8
VOC
VOC
10.9
13.1
1 15.1
12.8
8
0%

Naflon(R) Membrane Spraybooth Air Emissions Inventory
Page 3 of 4
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P-j
NS-I Membrane Spraybooth summary.
Coating Process yr
Max Spray Coat Rate (2 guns) cc/min
Max Process Rate gal/hr
Paint Batches batch
Gallons/batch gals
Gallons from Original batches gals
2002
2003
2004
2005
400
400
400
400
6.3
6.3
6.3
6.3
137 169 193 166
25 25 25 25
3425 4225 4825 4150
Remade batches
batchs
Gallons added/batch
gals
5
5
5
5
Gallons added to remake batchs
gals
110
0
50
0
Annual Process Throughput
gals/yr
3535
4225
4875
4150
Coating Density
lb/gal
7.928
7.928
7.928
7.928
Coating Consumed
ibs/yr
28025
33496
38649
32901
% change
-13.78
19.52
16.38
-14.87
VOC Emissions
Ethanol
wt %
69%
69%
69%
69%
Methanol
wt %
1 %
1 %
1
1 %
1 %
1-Pro anol
wt %
8%
8%
8%
8%
Annual VOC Emissions Ibs/yr 21860 26127 30146 25663
tons/yr 10.9 13.1 15.1 12.8
tom spraywating
Taint & binder lab
esuits
rom sprays eating
mint & binder lab
asuits NG first
amples.
DEQ-CFW 00087408

0 0 0
Nafion(R) Membrane Spraybooth Air Emissions Inventory Page 1 of 4
Emission source/Operating Scenario Data for year 2005
1. Emission Source ID No.
NS-I
2. Emission Source Description:
NafionO Resin Membrane Coating process
3. Operating Scenario Description:
OS-19 Nafion® Resin Membrane coating process
4. SCC Number/Description:
301 999 98 / * other organic chemical manufacture not listed.
5. Through put in CY kgs:
4150 gal
6. Fuel Information:
None
7: Capture Efficiency:
100%
8. Control Device Information
None
9. Stack or emission release point information:
stack
stack height
diameter
temperature
velocity
volume flow
release point
ERP
stack ID
feet
feet
deg. F.
feet/sec
rate (acim)
description
description
Nafion®
membrane
NEP-1
50
2
ambient
0.4
75
Vertical
coating
10. Operating Schedule: OS-19
1 Hours per last year
2116.946
1hours/day 24
1 da s/wk 7 lwks/yr 52
11. Typical Start & End times for Operating Scenarl Continuous when used
12. Seasonal periods percent annual Jan -Mar 29% April -June 24% Jul -Set 27% 1 Oct -Dec 120%