DEQ-CFW_00087375

Vinyl Ethers North Air Emissions Inventory Accidental Releases
Pagel of 3
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2005 Accidental Releases to Atmosphere
A. 2005-032
Material Released:
Quantity Released:
Total VOC
Date: 3/14/2005
Perfluoropropyl vinyl ether (PPVE)
0.1 lbs
0.1 lbs VOC
BF Potential:
PPVE is a VOC without the potential to form HF
B. 2005-081
Date: 7/15/2005
CAS No.1623-5-8
B1 Material Released: Diadduct (DA) CAS No. 4089-58-1
Quantity Released: 74 kgs
Total VOC 163 lbs VOC
HF Potential:
Each mole of DA (MW = 512) can generate 1 mole of HF (MW = 20).
1 kg DA.1 mole DA 20 g HF 1 mole HF _ 0.039 kg HF
512 g DA 1 mole HF 1 mole DA
Therefore, each 1 kg of DA generates 0.039 kg of HF
HF Equivalent Emissions
74 kg DA
x 0.039 kg HF/kg DA
= 2.89 kg BF = 6.36 lb. HF
E
DEQ-CFW 00087375

Vinyl Ethers North
Air Emissions Inventory
Accidental Releases
Page 2 of 3
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B2 Material Released:
Quantity Released:
Total VOC
HF Potential:
Monoadduct (MA)
64 kgs
141 lbs VOC
CAS No. 4089-57-0
Each mole of MA (MW = 346) can generate 1 mole of HF (MW = 20).
1kgMA•lmoleMA 20gHF lmoleHF_0.058kgHF
346 g MA 1 mole HF 1 mole MA
Therefore, each 1 kg of MA generates 0.058 kg HF
HF Equivalent Emissions
64 kg MA
x 0.058 kg HF/kg MA
3.71 kg BF =
0
8.18 lb. HF
B3 Material Released: Perfluoropropionyl fluoride (PPF)
Quantity Released: 8 kgs
Total VOC 17.6 Is VOC
HF Potential:
CAS No. 422-61-7
Each mole of PPF (MW =166) can generate 1 mole of HF (MW = 20).
1 kg PPF- 1 molePPF 20g HF . 1 moleHF = 0.120k9HF
166g PPF 1 moleHF 1 molePPF
Therefore, each 1 kg of PPF generates 0.120 kg HF
HF Equivalent Emissions
8 kg PPF
x 0.058 kg HF/kg PPF
= 0.46 kg HF =
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1.02 lb. HF
DEQ-CFW 00087376

Vinyl Ethers North
Air Emissions Inventory
0
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B4 Material Released:
Quantity Released:
Total VOC
BF Potential:
HFPO Trimer
52 kgs
115 lbs VOC
Accidental Releases
Page 3 of 3
CAS No. 2641-34-1
Each mole of BFPO Trimer (MW = 498) can generate 1 mole of BF (MW = 20).
l kgMA• 1 moleTYimer 20g HF 1 moleHF = 0.0402kgHl
498g Trimer 1 moleHF 1 molei nmer
Therefore, each 1 kg of BFPO Trimer generates 0.0402 kg BF
BF Equivalent Emissions
52 kg BFPO Trimer
x 0.0402 kg BF/kg BFPO Trimer
= 2.09 kg BF = 4.61 lb. HF
C. Total Emissions from Accidental Releases
* Note when new chemical added to table below you must update Summary Tab
Source
PPVE
b
DA
b
MA
b)
PPF
(lb)
HFPO
Trimer b)
VOC
HF
A.2005-032
0.1
0.1
0.0
B.2005-081
1
1 163
1 141 1
18 1
115 1
437
20.2
Total
1 0.1 1
163 1
141 1
18 1
115 1
437
20.2
DEQ-CFW 00087377