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Vinyl Ethers North Air Emissions Inventory PSEPVE Process Emissions
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0 2005 AIR EMISSIONS INVENTORY SUPPORTING DOCUMENTATION
Emission Source ID No: NS-B
Emission Source Description: VE-North PSEPVE Manufacturing Process
Process & Emission Description: The VE-North PSEPVE manufacturing process is a continuous chemical
reaction. All emissions from the process are vented through the Naflon Division Waste Gas Scrubber (Control
Device ID No. NCD-Hdr) which has a documented control efficiency of 99.6% for all acid fluoride compounds.
Some emitted compounds are assumed to pass completely through the scrubber, so the control efficiency for
those compounds is assumed to be 0%. The control of emissions of specific compounds will be addressed and
detailed in the following pages.
The PSEPVE process in VE-North emits compounds in the acid fluoride family. In the presence of water (such
as in atmospheric moisture), these acid fluorides can eventually hydrolyze to hydrogen fluoride. For the purpose
of this emissions inventory, a conservative approach will be taken and the acid fluorides will be reported both as
a VOC and as the equivalent quantity of hydrogen fluoride.
Basis and Assumptions:
- The PSEPVE process flowsheet is the basis for relative concentrations of before -control emissions of gaseous
wastes.
- Calculations ofpoint source emissions are based on actual vent flow totals taken from the IP21 Historian.
- All emission determination calculations are available on the EXCEL spreadsheet found at
S:/Everyone/martinas/VEN Air Emissions 2005 Annual Summary.xls.
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Vinyl Ethers North
Air Emissions Inventory
PSEPVE Process Emissions
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11
Point Source Emission Determination
A. HFP
Hexafluoropropylene
HF Potential:
HFP is a VOC without the potential to form BF
Quantity Released
HFP is a byproduct present in the BFPO feed. It is an inert in VE-North that is
vented to the WGS.
HFP vented per the process flowsheet
Vented from the Condensation Reactor:
Vented from the Crude Receiver
Vented from the Foreshots Receiver
HFP vented based on
HFP vented based on
HFP vented based on
HFP vented from Condensation Reactor:
0.15 kg HFP x
3.66 kg CndRx
HFP vented from Crude Receiver
3.12 kg HFP x
18.76 kg CrRec
HFP vented from Foreshots Receiver
0.00 kg HFP x
0.33 kg FsRec
VOC Emissions 29 kg from Condensation Reactor
+ 4,025 kg from Crude Receiver
+ 0 kg from Foreshots Receiver
= 4,054 kg HFP =
CAS No.116-15-4
O 15kgU.FP
3.667cgCcndZxVend77o
3.12 kg HFP
118.76 kg Crude Receiver Vent
0 kg HFP
0.33 kg Foresho&ReceiverVen
740 kg total Condensation Reactor vent stream (22266FG).
24,218 kg total Crude Receiver vent stream (22701FG).
43 kg total Foreshots Receiver vent stream (22826FG).
740 kg CndRx = 29 kg HFP
24,218 kg CrRec = 4,025 kg HFP
43 kg FsRec = 0 kg HFP
4,054 kg VOC
8,919 lb VOC
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40 B. B PO CAS No. 428-59-1
Hexafluoropropylene oxide
HF Potential:
HFPO is a VOC without the potential to form HF
Quantity Released
HFPO is a byproduct present in the HFPO feed. It is an inert in VE-North that is
vented to the WGS.
HFPO vented per the process flowsheet
3.28 kg HFPO
Vented from the Condensation Reactor.
3.66 kg Cond Rx Vent Flow
Vented from the Crude Receiver
O kg HFPO
18.76 kg Crude Receiver Vent
0 kg HFPO
Vented from the Foreshots Receiver
0.33 kg ForeshotsRecezverVen
BFPO vented based on
740 kg total Condensation Reactor vent stream (22266FG).
BFPO vented based on
24,218 kg total Crude Receiver vent stream (22701FG).
BFPO vented based on
43 kg total Foreshots Receiver vent stream (22826FG).
BFPO vented from Condensation Reactor:
3.28 kg BFPO x
740 kg CndRx = 663 kg HFPO
3.66 kg CndRx
HFPO vented from Crude Receiver
0.00 kg BFPO x
24,218 kg CrRec = 0 kg BFPO
18.76 kg CrRec
BFPO vented from Foreshots Receiver
0.00 kg BFPO x
43 kg FsRec = 0 kg BFPO
0.33 kg FsRec
VOC Emissions
663 kg from Condensation Reactor
+
0 kg from Crude Receiver
+
0 kg from Foreshots Receiver
=
663 kg HFPO = 663 kg VOC
1,458 Ib VOC
r�
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Air Emissions Inventory
PSEPVE Process Emissions
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C. PPF
Perfluoropropionyl fluoride
HF Potential:
Ea
CAS No. 422-61-7
i mole of PPF (MW =166) can generate 1 mole of HF (MW = 20).
1 molePPF 20g HF 1 moleHF
kgPPF• = 0.120kgHl
166g PPF 1 moleHF 1 molePPF
Therefore, each 1 kg of PPF generates
Quantity Released
Before -control PPF vented per the process flowsheet
Vented from the Condensation Reactor:
Vented from the Crude Receiver
Vented from the Foreshots Receiver
PPF vented based on
PPF vented based on
PPF vented based on
Before control PPF vented from Condensation Reactor:
0.120 kg of HF
0.20 kg PPF
13.66 kg Cond Rx Vent Flow
0 kg PPF
18.76 kg CrudeReceiver Vent
0 kg PPF
0.33 kg ForeshotsReceiverVen
740 kg total Condensation Reactor vent stream (22266FG).
24,218 kg total Crude Receiver vent stream (22701FG).
43 kg total Foreshots Receiver vent stream (22826FG).
0.20 kg PPF x
740 kg CndRx =
3.66 kg CndRx
PPF vented from Crude Receiver
0.00 kg PPF x
24,218 kg CrRec =
18.76 kg CrRec
PPF vented from Foreshots Receiver
0.00 kg PPF x
43 kg FsRec =
0.33 kg FsRec
Total before -control PPF vented
=
After -control emissions utilizing the 99.6% control
efficient Waste Gas Scrubber (WGS):
VOC Emissions
41 kg PPF
Waste Gas Scrubber
x (1000/6-99.6%) Control Efficiency
= 0.17 kg PAF —
41 kg PPF
0 kg PPF
0 kg PPF
41 kg PPF
0.17 kg VOC
0.36 lb. VOC
HF Eaulvalent Emissions 0 kg PPF
x 0.120 kg HF/kg PPF
= 0.02 kg HF 0.04 lb. HF
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D. TFE
Tetrafluoroethylene
HF Potential:
TFE is a VOC without the potential to form BF
Quantity Released
TFE is a byproduct present in the TFE feed. It is an inert in VE-North that is
vented to the WGS.
TFE vented per the process flowsheet
CAS No.116-14-3
0 kg TFE
Vented from the Condensation Reactor. 3.66 kg Cond .Rx Vent Flow
0.01 kg TFE
Vented from the Crude Receiver
18.76 kg CrudeRe ceiver Vent
0 kg TFE
Vented from the Foreshots Receiver 0.33 kg ForeshotsReceiverVen
TFE vented based on
740 kg total Condensation Reactor vent stream (22266FG).
TFE vented based on
24,218 kg total Crude Receiver vent stream (22701 FG).
TFE vented based on
43 kg total Foreshots Receiver vent stream (22826FG).
TFE vented from Condensation Reactor.
0.00
—
x 740 kg CndRx — 0 kg TFE
3.66 kg TFE
kg CndRx
TFE vented from Crude Receiver
0.01
x 24,218 kg CrRec = 12 kg TFE
18.76 kg TFE
kg CrRec
TFE vented from Foreshots Receiver
0.00
x 43 kg FsRec = 0 kg TFE
0.33 kg TFE
kg FsRec
VOC Emissions
0 kg from Condensation Reactor
+ 12 kg from Crude Receiver
+ 0 kg from Foreshots Receiver
=
12 kg TFE = 12 kg VOC
26 lb VOC
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E. PSEPVE
Perfluoro-2-(2-Fluorosulfonylethoxy) Propyl Vinyl Ether
HF Potential:
PSEPVE is a VOC without the potential to form BF
Quantity Released
PSEPVE vented per the process flowsheet
CAS No.1623-5-8
0 kg PSEPVE
Vented from the Condensation Reactor: 3.66 kg Cond Rx Vent Flow
0 kg PSEPVE
Vented from the Crude Receiver 18.76 kg Crude Receiver Vent
0.07 kg PSEPVE
Vented from the Foreshots Receiver 0.33 kg ForeshotsReceiverVen
PSEPVE vented based on 740 kg total Condensation Reactor vent stream (22266FG).
PSEPVE vented based on 24,218 kg total Crude Receiver vent stream (22701FG).
PSEPVE vented based on 43 kg total Foreshots Receiver vent stream (22826FG).
PSEPVE vented from Condensation Reactor:
0.00 x
740 kg CndRx =
0 kg PSEPVE
3.66 kg PSEPVE
kg CndRx
PSEPVE vented from Crude Receiver
0.00 is
24,218 kg CrRec =
0 kg PSEPVE
18.76 kg PSEPVE
kg CrRec
PSEPVE vented from Foreshots Receiver
0.07 x
43 kg FsRec =
8.78 kg PSEPVE
0.33 kg PSEPVE
kg FsRec
VOC Emissions
0 kg from Condensation Reactor
+
0 kg from Crude Receiver
+
8.78 kg from Foreshots Receiver
=
8.78 kg PSEPVE =
8.78 kg VOC
1931 lb VOC
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Vinyl Ethers North Air Emissions Inventory
F. C4
Perfluoro-2-butene
HF Potential:
C4s are VOCs without the potential to form HF
Quantity Released
C4s are pertluorobutenes that are byproducts from the Agitated Bed Reactor system.
They are inerts in VE-North that is vented to the WGS.
C4s vented per the process flowsheet
PSEPVE Process Emissions
Page 7 of 17
CAS No. 360-894
0kgC4
Vented from the Condensation Reactor:
3.66 kg Cond Rx Vent Flow
0.46 kg C4
Vented from the Crude Receiver
118.76 kg Crude Receiver Vent
0.10 kg C4
Vented from the Foreshots Receiver
0.33 kg ForeshotsReceiverVen
C4s vented based on
740 kg total Condensation Reactor vent stream (22266FG).
C4s vented based on
24,218 kg total Crude Receiver vent stream (22701FG).
C4s vented based on
43 kg total Foreshots Receiver vent stream (22826FG).
C4s vented from Condensation Reactor:
0.00
x 740 kg CndRx = 0 kg C4s
3.66 kg C4s
kg CndRx
C4s vented from Crude Receiver
0.46
x 24,218 kg CrRec = 593 kg C4s
18.76 kg C4s
kg CrRec
C4s vented from Foreshots Receiver
0.10
x 43 kg FsRec = 12 kg C4s
0.33 kg C4s
kg FsRec
VOC Emissions
0 kg from Condensation Reactor
+ 593 kg from Crude Receiver
+ 12 kg from Foreshots Receiver
=
605 kg C4s = 605 kg VOC
1,331 lb VOC
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G. MTO Trimer
Pertluoro-2,5-Dimethyl-3,6-Dioxanonanoyl
HF Potential:
Each mole of HFPO Trimer (MW = 498) can generate 1 mole of HF (MW = 20).
. kgMA-1 moleTrimer 20g HF 1 moleHF _ 0.0402kgHl
498g Trimer 1 moleHF 1 moleTrimer
Therefore, each 1 kg of HFPO Trimer generates 0.040 kg of HF
Quantity Released
BFPO Trimer is a byproduct formed in the Condensation Reactor system.
CAS No. 2641-34-1
BFPO Trimer vented per the process flowsheet 0 kg HFPO Trimer
Vented from the Condensation Reactor 13.66 kg Cond Rx Vent Flow
0 kg HFPOTrimer
Vented from the Crude Receiver:
18.76 kg CrudeReceiver Vent
0.01 kg HFPO Trimer
Vented from the Foreshots Receiver: 0.33 kg ForeshotsR eceiverYen
BFPO Trimer vented based on 740 kg total Condensation Reactor vent stream (22266FG).
BFPO Trimer vented based on 24,218 kg total Crude Receiver vent stream (22701FG).
BFPO Trimer vented based on 43 kg total Foreshots Receiver vent stream (22826FG).
Before control HFPO Trimer vented from Condensation Reactor:
0.00 x 740 kg CndRx = 0 kg HFPO Trimer
3.66 kg HFPO Trimer
kg CndRx
HFPO Trimer vented from Crude Receiver
0.00 x 24,218 kg CrRec = 0 kg HFPO Trimer
18.76 kg BFPO Trimer
kg CrRec
HFPO Trimer vented from Foreshots Receiver
0.01 x 43 kg FsRec = 1.76 kg BFPO Trimer
0.33 kg BFPO Trimer
kg FsRec
Total before -control HFPO Trimer vented 1.76 kg VOC
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
VOC Emissions 1.76 kg HFPO Trimer
Waste Gas Scrubber x (100%-99.6%) Control Efficiency
0.0070 kg HFPO Trimer = 0.0070 kg VOC
0.015 Ib. VOC
HF Equivalent Emissions 0.0070 kg HFPO Trimer
x 0.040 kg HF/kg HFPO Trimer
= 0.00028 kg HF 0.00062 lb. HF
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Air Emissions Inventory
P,SEPVE Process Emissions
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Ol
0-
H. Monoadduct (MA)
Tetrafluoro-2-[Tetrafluoro-2-(Fluorosulfonyl)Ethoxy]-Propanoyl Fluoride
HF Potential:
CAS No. 4089-57-0
i mole of MA (MW = 346) can generate 1 mole of HF (MW = 20).
1 moleMA 20 g HF 1 moleHF
kg MA - =0.058kgHI
346 g MA 1 moleHF 1 mole MA
Therefore, each 1 kg of MA generates
Quantity Released
Before -control MA vented per the process flowsheet
Vented from the Condensation Reactor:
Vented from the Crude Receiver
Vented from the Foreshots Receiver
MA vented based on
MA vented based on
MA vented based on
Before control MA vented from Condensation Reactor.
0.058 kg of HF
0kgMA
13.66 kg Cond Rx Vent Flow
0kgMA
18.76 kg Crude Receives- Vent
0.0045kg MA
0.33 kg ForerhotsReceiverVen
740 kg total Condensation Reactor vent stream (22266FG).
24,218 kg total Crude Receiver vent stream (22701FG).
43 kg total Foreshots Receiver vent stream (22826FG).
0.00 kg MA x 740 kg CndRx 0 kg MA
3.66 kg CndRx
MA vented from Crude Receiver
0.00 kg MA x 24,218 kg CrRec = 0 kg MA
18.76 kg CrRec
MA vented from Foreshots Receiver
0.0045 kg MA x 43 kg FsRec = 0.585 kg MA
0.33 kg FsRec
Total before -control MA vented = 0.585 kg MA
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
VOC Emissions 0.665 kg MA
Waste Gas Scrubber x (100%-99.6%) Control Efficiency
0.00234 kg MA = 0.00234 kg VOC
0.005 lb. VOC
HF Eauivalent Emissions 0.00234 kg MA
x 0.058 kg HF/kg MA
0.00 kg HF 0.00 lb. HF
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I. Diadduct (DA) CAS No. 4089.58-1
Tetrafluoro-2[Hexafluoro-2-(Tetrafluoro-2-(Fluorosulfonyl)Ethoxy) Propoxy Propionyl Fluoride
HF Potential:
1 moleDA 20 g HF 1 moleHF
1kgMA•=0.039kgHl
512g DA 1 moleHF 1 moleDA
Therefore, each 1 kg of DA generates
Quantity Released
Before -control DA vented per the process flowsheet
Vented from the Condensation Reactor:
Vented from the Crude Receiver
Vented from the Foreshots Receiver
0.039 kg of HF
0kgDA
3.66 kg Cond Rx Vent Flow
0kgDA
18.76 kg CrudeRe ceiver Vent
0.13 kg DA
0.33 kg ForeshotsReceiverVen
DA vented based on
740 kg total Condensation Reactor vent stream (22266FG).
DA vented based on
24,218 kg total Crude Receiver vent stream (22701FG).
DA vented based on
43 kg total Foreshots Receiver vent stream (22826FG).
Before control DA vented from Condensation Reactor:
0.00 kg DA x
740 kg CndRx = 0 kg DA
3.66 kg CndRx
DA vented from Crude Receiver
0.00 kg DA x
24,218 kg CrRec = 0 kg DA
18.76 kg CrRec
DA vented from Foreshots Receiver
0.13 kg DA x
43 kg FsRec = 16.97 kg DA
0.33 kg FsRec
Total before -control DA vented
= 16.97 kg DA
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
VOC Emissions
16.97 kg DA
Waste Gas Scrubber
x (100%-99.6%) Control Efficiency
= 0.0679 kg DA = 0.068 kg VOC
0.150 lb. VOC
HF Equivalent Emissions 0.0679 kg DA
x 0.039 kg HF/kg DA
0.00266 kg HF = 0.01 Ib. HF
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J. Hydro PSEPVE
Tetrafluoro-2-[Trifluoro-2-(1;2,2,2-Tetra-fluoroethoxy)-1-(Trifluoromethyl) Ethoxy]-
Ethane Sulfonyl Fluoride
CAS No. 755-02-9
HF Potential:
Hydro-PSEPVE is a VOC without the potential to form HF
Quantity Released
Hydro-PSEPVE vented per the process flowsheet
0 kg Hydro —PSEPVE
Vented from the Condensation Reactor:
13.66 kg Cond Rx Vent Flow
0 kg Hydro—PSEPVE
Vented from the Crude Receiver
18.76 kg Crude Receiver Vent
Vented from the Foreshots Receiver
0.0045 kg Hydro—PSEPVE
10.33
kg ForeshotsReceaverVen
Hydro-PSEPVE vented based on 740 kg total Condensation Reactor vent stream (22266FG).
Hydro-PSEPVE vented based on 24,218 kg total Crude Receiver vent stream (22701FG).
Hydro-PSEPVE vented based on 43 kg total Foreshots Receiver vent stream (22826FG).
Hydro-PSEPVE vented from Condensation Reactor.
0.00 kg Hydro-PSEPVE x
740 kg CndRx = 0 kg Hydro-PSEPVE
3.66 kg CndRx
Hydro-PSEPVE vented from Crude Receiver
0.00 kg Hydro-PSEPVE x
24,218 kg CrRec = 0 kg Hydro-PSEPVE
18.76 kg CrRec
Hydro-PSEPVE vented from Foreshots Receiver
0.0045 kg Hydro-PSEPVE x
43 kg FsRec = 0.585 kg Hydro-PSEPVE
0.33 kg FsRec
VOC Emissions
0 kg from Condensation Reactor
+
0 kg from Crude Receiver
+
0.585 kg from Foreshots Receiver
=
0.585 kg Hydro-PSEPV = 0.585 kg VOC
1.287 lb VOC
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Air Emissions Inventory
PSEPVE Process Emissions
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K. Iso-PSEPVE
Perfluoro-1-Methyl-2-(2 Fiuorosulfonyl Ethoxy) Ethyl Vinyl Ether
HF Potential:
Iso-PSEPVE is a VOC without the potential to form BF
Quantity Released
Iso-PSEPVE vented per the process flowsheet
0 kg Iso — PSEPVE
Vented from the Condensation Reactor: 3.66 kg Cond Rx Yent Flow
0 kg Iso — PSEPVE
Vented from the Crude Receiver 118.76 kg CrudeRe ceiver Vent
0.014 kg rso — PSEPVE
Vented from the Foreshots Receiver 0.014 kg Foreshots Receiver Vent
Iso-PSEPVE vented based on 740 kg total Condensation Reactor vent stream (22266FG).
Iso-PSEPVE vented based on 24,218 kg total Crude Receiver vent stream (22701 FG).
Iso-PSEPVE vented based on 43 kg total Foreshots Receiver vent stream (22826FG).
Iso-PSEPVE vented from Condensation Reactor:
0.00 kg Iso-PSEPVE x
3.66 kg CndRx
Iso-PSEPVE vented from Crude Receiver
0.00 kg Iso-PSEPVE x
18.76 kg CrRec
Iso-PSEPVE vented from Foreshots Receiver
0.014 kg Iso-PSEPVE x
0.33 kg FsRec
VOC Emissions
CAS No. 34805-58-8
740 kg CndRx = 0 kg Iso-PSEPVE
24,218 kg CrRec = 0 kg Iso-PSEPVE
43 kg FsRec = 1.755 kg Iso-PSEPVE
0 kg from Condensation Reactor
0 kg from Crude Receiver
1.755 kg from Foreshots Receiver
1.755 kg Iso-PSEPVE _
1.755 kg VOC
3.861 lb VOC
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1-1
L. Glycol Ethers (GE)
GLYET-Other
The emissions of glycol ethers is based on a mass balance of glycol ethers consumed in the process.
The only GE emissions in PSEPVE is DiGlyme
Quantity Released
= 2,100 kg GE introduced into processes
= 700 kg GE transferred to H/C waste tank
= 1,400 kg GE unaccounted for and assumed emitted
= 3086 lb. Glycol Ethers
Assume that the emissions of glycol ethers is split evenly between the three
processes of Vinyl Ethers North.
Therefore:
Emissions of glycol ether from PSEPVE = 3086 lb. Glycol Ethers
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M. Sulfonyl Fluoride (SOF2)
HF Potential:
Each mole of SOF2 (MW = 86) can generate 2 mole of HF (MW = 20).
CAS No. 7783-42-8
kgMA• 1 moleSOF2 20g HF 2 moleHF _ 0.465kgHI
86g SOF2 1 moleHF 1 moleSOF2
Therefore, each 1 kg of SOF2 generates
Quantity Released
Before -control SOF2 vented per the process flowsheet
Vented from the Condensation Reactor:
Vented from the Crude Receiver
Vented from the Foreshots Receiver
SOF2 vented based on
SOF2 vented based on
SOF2 vented based on
0.465 kg of HF
0 kg SOF2
13.66 kg Cond Rx Vent Flow
2.04 kg SOF2
18.76 kg Crude Receiver Vent
0 kg SOP2
10.33 kg ForeshotsReceiverVen
740 kg total Condensation Reactor vent stream (22266FG).
24,218 kg total Crude Receiver vent stream (22701 FG).
43 kg total Foreshots Receiver vent stream (22826FG).
Before control SOF2 vented from Condensation Reactor:
0.00 kg SOF2 x 740 kg CndRx = 0 kg SOF2
3.66 kg CndRx
80172 vented from Crude Receiver
2.04 kg SOF2 x 24,218 kg CrRec = 2,634 kg SOF2
18.76 kg CrRec
SOF2 vented from Foreshots Receiver
0.00 kg SOF2 x 43 kg FsRec = 0 kg SOF2
0.33 kg FsReb
Total before -control SOF2 vented = 2,634 kg SOF2
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
SOF2 Emissions 2,634 kg SOF2
Waste Gas Scrubber x_ (100%-99.6%) Control Efficiency
11 kg SOF2 23 lb. SOF2
HF Equivalent Emissions 11 kg SOF2
x 0.465 kg HF/kg SOF2
4.90 kg HF 10.80 lb. HF
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Is
N. Carbon Monoxide (CO)
CO is a criteria pollutant
Quantity Released
CO are perfluorobutenes that are byproducts from the Agitated Bed Reactor system.
They are inerts in VE-North that are vented to the WGS.
CO vented per the process flowsheet
CAS No. 630-08-0
0kgCO
Vented from the Condensation Reactor:
3.66 kg Cond Rx Vent Flow
1.30 kg CO
Vented from the Crude Receiver
118.76 kg Crude Re ceiver Vent
0kgCO
Vented from the Foreshots Receiver
0.33 kg ForeshotsReceiverVen
CO vented based on
740 kg total Condensation Reactor vent stream (22266FG).
CO vented based on
24,218 kg total Crude Receiver vent stream (22701FG).
CO vented based on
43 kg total Foreshots Receiver vent stream (22826FG).
CO vented from Condensation Reactor.
0.00
x 740 kg CndRx = 0 kg CO
3.66 kg CO
kg CndRx
CO vented from Crude Receiver
1.30
x 24,218 kg CrRec = 1,684 kg CO
18.76 kg CO
kg CrRec
CO vented from Foreshots Receiver
0.00
x 43 kg FsRec = 0 kg CO
0.33 kg CO
kg FsRec
CO Emissions
0 kg from Condensation Reactor
+ 1,684 kg from Crude Receiver
+ 0 kg from Foreshots Receiver
= 1,684 kg CO = 3,712 lb CO
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9 O. VOC Summary
Nafion Compound Name
Before Control
Generated
After Control
Stack Emissions
VOC
HF
k /
Ib/ r
lb/yr
lblyr
A.
HFP
4,054
8,919
8,919
B•
I HFPO
663
1,458
1,458
C.
I PPF
41
91
0.36
0
D•
TFE
12
26
26
E.
PSEPVE
9
19
19
F.
C4
605
1,331
1,331
G.
HFPO Trimer
1.76
3.86
0
0
H.
MA
0.59
1.29
0.01
0
I.
DA
16.97
37.41
0.15
0
J.
Hydro PSEPVE
0.59
1 1.29
1.29
K.
Iso PSEPVE
1.76
3.87
3.86
L.
Glycol Ethers46,805805
,400
3,086
3,086
Total
14,978
14,845
0
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0 P. Point Source Summary
•
•
Nafion Compound Name
Stack
Emissions
lb/
Equipment
Emissions (Note')
lb/
Maintenance
Emissions (Note2)
lb/
Total
Emissions
lb/yr
A.
HFP
8,919
356
118
9,393
B.
MO
1,458
58
19
1,536
C.
PPF
0.36
0.01
0.00
0.4
D.
TFE
26
1.0
0.3
27
E.
PSEPVE
19.31
0.77
0.26
20.3
F.
C4
1,331
53
18
1,401
G.
BFPO Trimer
0.015
0
0.000
0
H.
MA
0.005
0
0.000
0
I.
DA
0.150
0.006
0.0020
0.158
J.
Hydro-PSEPVE
1.287
0.051
0.017
1.36
K.
Iso-PSEPVE
3.861
0.15
0.051 '
4.1
L.
Glycol Ethers
3,086
123.19
40.861
3,250
M.
SOF2
23
0.9
0.31
24
N
CO
3,712
0
0
3,712
r
Total
18,580
593
197
19,371
Note 1 - See section titled "Equipment hxmssions" tor aetaiis
Note 2 - See section titled "Maintenance Emissions" for details
BF Equivalent Emissions
Nafion Compound Name
Stack
Emissions
lbtyr
Equipment
Emissions
lb&
Maintenance
Emissions
lb/ r
Total
Emissions
lb/yr
C.
PPF
0.04
0.00
0.00
0.05
G.
BFPO Trimer
0.00
0.00
0.00
0.00
H.
MA
0.00
0.00
0.00
0.00
I.
DA
0.01
0.00
0.00
0.01
M.
SOF2
10.80
0.43
0.14
11.38
Total
10.85
0.43
0.14
11.43
The estimated BF equivalent emissions from Equipment Emissions were determined by multiplying the
PPF BF Potential (0.12 lb. BF/lb. PPF) by the PPF Equipment Emissions (0.041b./yr) for the Compound
0.12 lb/yr BF x 0.01 lb/yr Equipment PPF = 0.002 lb/yr HF
lb/yr PPF
The estimated BF equivalent emissions from Maintenance Emissions were determined by multiplying the
PPF BF Potential (0.12 lb. BF/lb. PPF) by the PPF Maintenance Emissions (0.001 lb./yr) for the Compound
0.12 lb/yr BF X 0.005 lb/yr Maintenance PPF = 0.001 lb/yr BF
lb/yr PPF
DEQ-CFW 00087366