HomeMy WebLinkAboutDEQ-CFW_00077536o0o-J/ IX5
e t DuPont Automotive
P.O. Drawer Z
Fayetteville, NC 28302
aUPONT
DuPont Automotive
DUPONT - FAYETTEVILLE WORKS
RENEWAL APPLICATION
FOR
NPDES PERMIT - NC0003573
J�It 1996
NOVEMBER 29,1995
E. I. du Pont de Nemours and Company ® Printed on Recycled Paper
FF-9522 Rev 5/93
DEQ-CFW 00077536
1
NORTH CAROLINA DEPT. OF ENVIRONMENT, HEALTH, AND NATURAL RESOURCES
ENVIRONMENTAL MANAGEMENT COMMISSION
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM
APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER
STANDARD FORM C - MANUFACTURING AND COMMERCIAL
SECTION I. APPLICATION AND FACILITY DESCRIPTION
Unless otherwise specified on this form all Hems are to be completed. if an Kern Is riot applicable Indicate 'NA'.
ADDITIONAL INSTRUCTIONS FOR SELECTED ITEMS APPEAR IN SEPARATE INSTRUCTION BOOKLET AS INDICATED. REFER TO BOOKLET
BEFORE FILLING OUT THESE ITEMS.
1. Legal Name of Applicant
(see instructions)
2 Mailing Address of Applicant
(see Instructions)
Number & Street
City
State
Zp Code
3. Applicants Authorized Agent
(see Instructions)
Name and Title
Number & Street
City
State
Zip Code
Telephone
4. Previous Application
If a previous application for a
' permit under the National
Pollutant Discharge Elimination
System has been made, give
the date of application.
I 1
11
101
Pit..
sic
-
•c
iL•M
Please Print or Type
E. I. DUPONT DE NEMOURS & CO., INC.
FAYETTEVILLE WORKS
P. 0. DRAWER Z
FAYETTEVILLE
NC
98302
Michael E. Johnson
Environmental Coordinator
P. 0 —rawer 7.
Fayetteville
NC
28302
910 678-1155
Area Number
Code
90 11 28
YR MO DAY
I certify that I am familiar with the information contained in this application and that to the best of my knowledge and belief such information is true, complete,
and accurate. 4116►r.. _.
Michael E. Mayberry 102e Plant Manager
Printed Name o rson Signing Title
1o2r �� / / 2�I' JUL Spa 1996
Signature of Applicant A horized Agent YR MO DAY
Date Application Signed fly'
North Carolina General Statue 143-215.6 (b)(2) provides that Any person who knowingly makes any false statement represennttaaBorf, any
application, record, report, plan, or other document files or required to be maintained under Article 21 or regulations Qf the Environmental Manage
Commission implementing that Article, or who falsifies, tampers with, or knowingly renders inaccurate any recording or rh6nitoring,device or method required
to be operated or maintained under Article 21 or regulations of the Environmental Management Commission implementing that Article, shalrbe sfuilt�,Qf.a
misdemeanor punishable by a fine not to exceed $10,000, or by imprisonment not to exceed sot months, or by both. (18 U.S.C. Section loot provides 1 . 4*
punishment by a fine or not more than $10,000 or imprisonment not more than 5 years, or both, for a similar offense.)
E
DEQ-CFW 00077537
[FOR AGLM;Y Ut�i:
5. Facility (see instructions)
Give the name, ownership, and
physical location of the plant or
other operating facility where
discharge(s) presently occur(s)
or will occur.
Name
tl
8.
1
1
1
1
1
1
Ownership (Public, Private
or both Public and Private)
Check block if a Federal
facility
and give GSA Inventory
Control Number
Location:
Number & Street
city
County
State
Nature of Business State the nature
of the business conducted at the
plant or operating facility.
Facility Intake Water (see
instructions) Indicate water intake
volume per day by sources.
Estimate average volume per day
in thousand gallons per day.
Municipal or private water system
Surface water
Groundwater
Other
Total Item 7
' If there is intake water from 'other,
speaiy, thq source.
Facility Water Use Estimate average
volume per day in thousand gallons
per day for the following types of
water usage at the facility.
(See instructions)
Noncontact cooling water
Baler feed water
Process water (including contact
cooling water)
Sanitary water
Other
Total Item 8
If there are discharges to 'other',
specify
If there is 'Sanitay water use,
give the number of people served.
r
105b
105c
105d
lose
105f
1059
105h
106a
ism
107a
107b
107c
107d
107e
107f
108a
106b
108c
108d
1088
loaf
toeg
108h
E. I. DUPONT DE NEMOURS & CO., INC.
FAYETTEVILLE WORKS
PUB 15PRV BPP
FED
State Highway 87 South
Duart
Bladen
North Carolina
Plastic Sheeting, Film. and Resins-
Industrial Organic Chemical Mantifacturing
AGENCY USE
0 thousand gallons per day
15,100 thousand gallons per day
6 thousand gallons per day
thousand gallons per day
15 ,10 6 thousand gallons per day
13 , 4 8 3 thousand gallons per day
730 thousand gallons per day
837 thousand gallons per day
h thousand gallons per day
5 0 thousand gallons per day
15.10 6 thousand gallons per day
River Water Treatment Backw
738 people served
JUL 30 1996
CENTRAL FILES
DEQ-CFW 00077538
r r ,
' 9. All Facility Discharges and other Losses. Number
Specify
and Discharge (See insWxbons)Volume the
number of discharge points and the volume of water
discharged or lost from the facility according In the
categories below. Estimate average volume per day in
'
thousand gallons per day
Number of
Total Volume Discharged,
Discharge Points
Million Gallons Per Day
Surface Water 109a1 9
109a2
'
Sanitary wastewater transport systen 109b1 1
109b2
. 0.006 (inc. in 109a2 )
Storm water transport system 109c1 2
109c2
0.052 (inc. in 109a2)
' Combined sanitary and storm water 109d1
109d2
transport system
Surface impoundment with no 109e1
109e2
' effluent
Underground percolation 1091`1
109f2
Well injection 109g1
109g2
'
Waste acceptance firm 109h1
109h2
Evaporation 1090 �_
109i2
0.293
Consumption 109j 1
109j2
Other' 109k1
1091<2
' Facility dischargers and volume
Total Item 9 10911
10912
15.168
'If there are discharges to'other', 109m1
specify.
' 10. Permits, Licenses and Applications
List all existing, pending or denied permits, licenses and applications related to discharges from this facility (see instructions)
Issuing For Type of Date
Date
Date Expiration
Agency Agency Permit or Filed
I
Issued
Denied Data
Use License ID Number YR/MO/DA
YR/MO/DA YR/MO/DA YR/MO/DA
a c e
1. NC—
NCDEHNR
11. Maps and Drawings
Attach all required maps and drawings to the back of this application. (see instructions)
12. Additional Information
1,7v
CENTRAL FILES
DEQ-CFW 00077539
STANDARD FORM C - MANUFACTURING AND COMMERCIAL
SECTION 11. BASIC DISCHARGE DESCRIPTION
Complete this section for each discharge Indicated in Sedior
which the waste water does not go through a treatment works
also discharges to surface waters from this facility. SEPARA'
ORIGINATE IN THE SAME FACILITY. All values for an exist
discharge, values should reflect best engineering estimates.
ADDITIONAL INSTRUCTIONS FOR SELECTED ITEMS
BEFORE FILLING OUT THESE ITEMS.
1. Discharge Serial No. and Name
a Discharge Serial No. 201a
(see instructions)
b. Discharge Name 201b
Give the name of discharge, if
any (see instructions)
c. Previous Discharge Serial No 201c
If a previous permit
application was made for this dis
charge (item 4, Section 1) provide
previous discharge serial
number.
2. Discharge Operating Dates
a Discharge Began Date 202a
If the discharge described below
is in operation, give the date
(within best estimate) the
discharge began
b. Discharge to Begin Date 202b
If the discharge has never
occurred but is planned for some
future date, give the date the
discharge will begin.
c. Discharge to End Date If the 202c
discharge is scheduled to be
discontinued within the next 5
years, give the date (within best
estimate) the discharge will and.
3. Engineering Report Available
Check if an engineering report is
available to reviewing agency
upon request (see instructions) 203
4. Discharge Location Name the
political boundaries within which
the point of discharge is located:
State
County
(If applicable) City or Town
' S. Discharge Point Description
(see instructions)
Discharge into (check one)
Stream (includes ditches, arroyos,
and other watercourses
Lake
Ocean
Municipal Sanitary Wastewater
Transport System
Municipal Combined Sanitary
and Storm Transport System
E'er
i, Items 9,r to beintghat Is torgsurface waters. This Includes ed to surface waters.Discharges surface to municipal sewerage systems In
must be described where there
'E DESCRIPTIONS OF EACH DISCHARGE RE REQUIRED (ls EVEN IF SEVERAL DISCHARGES e
ng discharge should be representative of the twelve previous months of operation. II this Is a proposed
APPEAR IN SEPARATE INSTRUCTION BOOKLET AS INDICATED. REFER TO BOOKLET
001
Treated Process Wastewater and Process Stormwater
001
71 02
N/A
YR MO
N/A
YR MO
en Use
North Carolina 204d
Bladen 204e
Duart 204f
USTR
❑ LKE
OCE
MTS krr f x
MCS JUL 3U 1996
CENTRAL FIEF
DEQ-CFW 00077540
3111111111
L
Municipal Storm Water Transport
System
Well (injection)
Other
If 'other' is checked, specify type
6. Discharge Point - Lat/Long.
Give the precise location of the
point of discharge to the nearest
second.
Latitude
Longitude
7. Discharge Receiving Water Name
Name the waterway at the point of
discharge. (see instructions)
If the discharge is through an outfall that extends
beyond the shoreline or is below the mean low
water line, complete item 8,
=y, Aae^ 'use
Mar• M��• SuD
W-7—s-Z-2
M
208b
207a
1 207c
For Acemev Use
CM t
8. Offshore Discharge
a. Discharge Distance from Shore
b. Discharge Depth Below Water
9 Discharge Type and Occurrence
a Type of Discharge Check
whether the discharge is
continuous or intermittent
(See instructions)
b. Discharge Occurrence Days
per Week. Enter the average
number of days per week
(during periods of discharge)
this discharge occurs.
c. Discharge Occurrence- Months
If this discharge normally oper-
ates (either intermittently or
continuously) on less than a yea
around basis (excluding shut-
downs for routine maintenance),
check the months during the ye
when the discharge is operating
(see instructions)
Complete Items 10 and 11 if 'intermittent' is
checked in Item 9.a. Otherwise, proceed to
Item 12.
10. Intermittent Discharge Quantity
State the average volume per dis-
charge occurrence in thousands of
gallons
it. Intermittent Discharge Duration
and Frequency
a Intermittent Discharge Duration
Per Day State the average
number of hours per day the
discharge is operating
b. Intermittent Discharge
Frequency State the average
number of discharge occurrence
per day during days when
discharging
12. Maximum Flow Period Give the
time period in which the maximum
flow of this discharge occurs
210
211a
211b
212
DISCHARGE, Ff RIAL NUMBER
❑ STS
❑ WEL
❑ OTH
934 DEG. 50 MIN. 00 SEC
W78 DEG. 50 MIN. 00 SEC
Unnamed stream to Cape Fear River
(discharges as part of outfall 002)
N / A feet
N/A feet
® (oon) Continuous
❑ (int) Intermittent
_ 7 days per week
❑ JAN
❑ FEB
❑ MAR
❑ APR
❑ MAY
❑ JUN
❑ JUL
❑ AUG
❑ SEP
[]OCT
[]NOV
❑ DEC
*Continuous discharge
N/A thousandgallons per day
N/A hours per day
N/A discharge occurrences per day
From N/A to N/A
month month
w�.
DEQ-CFW 00077541
DISCHARGE'SERIAL NUMBER
001
13. Activity Description Give a 213a Manufacturing of Polyvinyl nyl BLtyral (PVB)
narrative description ofactivity Resin and Sheeting
producing this discharge (see
instructions) Manufacturing of Polyvinyl Big yra (PVB)
Resin (SIC Code 2821) and sheeting
(SIC Code 3081).
14. Activity Causing Discharge For each SIC Code which
describes the activity causing this discharge, supply the
type and maximum amount of either the raw material
consumed (Item 14a) or the product produced (Item 14b)
in the units specified in Table I of the Instruction Booklet..
For SIC Codes not listed in Table I, use raw material or
production units normally used for measuring production
(see instructions)
a Raw Materials
Maximum Unit Shared Discharges
ere, P -A- u.Te e..,n, int/r)n Mm Tahle 11 (Serial Numberl
21j
a -- -
i
a
2821
But raldeh
e
L-1
002
2821
Aydin yl
b. Products
Maximum Unit Shared Discharges
DEQ-CFW 00077542
DISCHARGE SERIAL NUMBER
001
13. Activity Description Give a 213a Manufacture of Hexaf 1 uoroproFvl ane
narrative description of activity Epoxide (HFPO) from the oxidation
producing this discharge (see of hexaf luoropropvlene (HFP)
instructions)
14. Activity Causing Discharge For each SIC Code which
describes the activity causing this discharge, supply the
type and maximum amount of either the raw material
consumed (Item 14a) or the product produced (Item 14b)
in the units specified in Table I of the Instruction Booklet.
For SIC Codes not listed in Table I, use raw material or
production units normally used for measuring production
(see instructions)
a Raw Materials
b. Products
CENTRAL FILES
DEQ-CFW 00077543
e"
e �
DISCHARGE SERIAL NUMBER
001
13. Activity Description Give a 213a _Manufacture of serf luoronated intermediates
narrative description of activity -(SIC Code 2869) . verf luoronated resins (SIC
producing this discharge (see Code 2821). and perfluoronarad 1am;,3ated film
instructions) (SIC Code 3093)
14. Activity Causing Discharge For each SIC Code which
describes the activity causing this discharge, sup the
type and maximum amount of either the raw material
consumed (Item 14a) or the product produced (Item 14b)
in the units specified In Table I of the Instruction Booklet.
For SIC Codes not fisted in Table I, use raw material or
production units normally used for measuring production
(see instructions)
a Raw Materials
Maximum Unit Shared Discharges
SIC Coda Name Omnuntln2v fqe M2hln 11 rcea�i rv, �. k—N
214
9
a 11)(2)
a
2869
HFPO
P-1
002
2869
Intermediat
s
P-1
002
2821
Resin
L-1
002
b. Products
;-4
DEQ-CFW 00077544
■z•1a_�a ayn�y�
15 Waste Abatement
' a Waste Abatement Practices
Describe the waste abatement
' practices used on this dis-
charge with a brief narrative
(see instructions)
DISCHARGE SERIAL NUMBER
001
215a I Narrative: See Below
b. Waste Abatement Codes 215b (1) ESEPAR (2)ESEGRE _(3)LOCALS
' Using the codes listed in Table (4) OMONIT (5)CNEUTR (6)EMERGE
II of the Instruction Booklet, (7)PEQUAL (e)BAERAT (9)CHUTRI
describe the waste abatement (10RAERAT (11) BACTIV (12) PSKIMC
' processes for this discharge in (13) PFLOAT (14) STHICK (15) SPRESS
the order in which they occur (16) SOTHER (1) 07) SOTHER M (18)
if possible. (19) (20) (21)
' (22) (23) (24)
(25)
' SOTHER(1) — SLUDGE DRYING
SOTHER (2) — SLUDGE LANDFILLING
NARRATIVE: Wastewater collected from area sumps are sent to a 750,000 gal
Equalization Basin (biological activity with aeration). A 175,000
' gal Emergency Retention Tank is available for temporary storage of
unsuitable wastewaters. Waters enter a 250,000 gal Pre —digester Tank
(biological activity with aeration), followed by a 1,700,000 gal Aeration
' Tank where the main biodegradation occurs.. The treated water then goes
to two clarifiers (120,000 and 168,000 gal) in parallel. The clarified
' treated effluent is discharged through Outfall 001.
The wasted sludge is sent to a Dissolved Air Floatation (DAF) unit and
' then a Rotary Filter for thickening. The thickened sludge is dewatered
in a Screw Press, and then dried -in steam heated dryers. The dried
' sludge is transported off —site to a commercial landfill
' JUL SU 1996
UNNAL FILES
DEQ-CFW 00077545
F-7
DISCHARGE SERIAL NUMBER
001
16. Wastewater Characteristics
Check the box beside each constituent which is present in the effluent (discharge water). This determination is to
based on actual analysis or best estimate -(see instructions)
arameter
resent
Parameter
Present
216
216
color
Copper
00060
X
01042
Ammonia
I ron
00610
X
01045
rganic nitrogen
Lew
00605
X
01051
Nitrate
Magnesium
00620
X
00927
Nitrite
Manganese
00615
01055
Phosphorus
Mercury
00665
X
71900
I ate
Molybdenum
00945
X
01062
I oe
Nickel
00745
01067
5ultite
enium
00740
01147
eromi a
auver
71870
01077
Uhlonde
Potassium
00940
X
00937
X
C;yanide
50alum
00720
00929
X
muonoe
i riallium
00951
X
01059
uminum
TiLanium
01105
X
01152
Antimony
i in
01097
X
01102
Arsenic
Zinc
01002
01092
X
beryllium
igia s
01012
74051
num
Unlonnatedorganic compounds'
01007
74052
l3oron
Pesticides*
01022
74053
aomium
Uil and grease
01027
00550
X
aicium
PhenoiS
00916 :
32730
(.;ot)alt
burlactants
01037
38M
X
C;hromium
C;nlonde
01034
50060
ecal ooliform bacteria
Hacioactivity
74055
X
74050
be
Specify substances, compounds and/or elements in Item 26.
Pesticides (insecticides, fungicides, and rodenDcides) must be reported in terms of the acceptable common names specified in Acceptable Common Names
and Chemical names for Oe /n vedent Statement on Pestade Labels, 2nd Edition, Environmental Protection Agency, Washington, D.C. 20250, June 1972, as
required by Subsection 162.7('I of the Regulations for the Enforcement of the Federal Insecticide, Fungicide, and Rodenticide Act
CENTRAL FILES
DEQ-CFW 00077546
DISCHARGE SERIAL NUMBER
001
17. Description of Intake and Discharge
For each of the parameters listed below, enter in the appropriate box the value or code letter answer called for (see instructions)
In addition, enter the parameter name and code and aP required values for any of the following parameters if they ere checked in Item 16:
ammonia, cyanide, aluminum, arsenic, beryllium, cadmium, chromium, copper, lead, mercury, nickel, selenium, zinc, phenols, oil and grease, and
chlorine (residual).
n uent
Effluent
Untreatecl
in-Plantai
y
minimum
Maximum
n3quency
Numbero
5ample
Parameter and Code
Intake
Treated
Average
Value
Value
of Analysis
Analyses
Type
Water
Intake
Observed or
Observed or
217
(Daily
Water
Expected
F�ected
average)
(Daily
During
During
average)
Discharge
Discharge
Activity
Activity
(1)
(2)
(3)
(4
(5)
(6
(7)
8
iow
MGD
50050
N/A
N/A
0.85
0.049
1.79
CONT.
1278
N/A
p
Units
00400
N/A
N/A
6.3
8.3
3/7
546
G
emperature (winter)
�C
N/A
N/A
23.7
18
33
3/7
546
G
emperature (summer)
C
74025
N/A
N/A
29.4
20
36
3/7
546
G
Biochemcial Uxygen
Demand
(BOO 5-Day)
mg/l
00310
N/A
N/A
5.3
BDL
120
3/7
546
C
—M—micai uxygen
Demand (COD)
mgA
00=
N/A
N/A
45
45
45
N/A
1
C
ME Suspenoeo
(nonfilterable) Solids
mgA
005M
N/A
N/A
117.6
1 BDL
440
3/7
546
C
peG Conductance
micromhos/cm at 25'C
00095
N/A
N/A
4600
4600
N/A
1
C
Settleable Matter
(residue)
ml/1
::N/A
LT
LT
LT
00545
N/A
0.1
0.1
0.1
N/A
1
C
Other discharges sharing intake flow (serial numbers) (see instructions)
DEQ-CFW 00077547
d
1
' 17. (Conrd)
r , e
DISCHARGE SERIAL NUMBER
001
Parameter and Code
217
Innuent
Emuent
Untreatedin-man
Intake
Water
(Daily
average)
lt)(2)
Treated
Intake
Water
(Daily
average)
ai y
Average
mg/L
(3)
minimum
Value
Observed or
Expected
During
Discharge
Activity
(4
maximum
Value
Observed or
Expected
During
Discharge
Activity
5
d Analysis
(6
Number
of
Analyses
7
e
Type
8)
See
-rpm
17.
t18. Plant Controls Check if the following
plant controls are available for this
discharge 218
' Alternate power source for major
pumping facility APS
' Alarm or emergency procedure for
power or equipment failure ALM
Complete Item 19 if discharge is frorr
cooling andior steam water
' generation and water treatment
additives are used
19. Water Treatment Additives If the
discharge is treated with any
' conditioner, inhibitor, or algicide,
answer the following:
a Name of Material(s) 219a
b. Name and address of 219b
' manufacturer
c, Quantity (pounds added per 219c
' million gallons of water treated)
' JUL 30 1996
CENTRAL FILES
DEQ-CFW 00077548
FOR AGENCY USE
DISCHARGE SERIAL NUMBER
001
17 (rnnt,d)
Effluent
Daily
Average
(all values
are mg/LDuring
Mimimum
Value
Observed
Du
Discharge
Activity
Maximum
Value
Observed
During
Discharge
Activity
Frequency
of Analysis
Number of
Analyses
Sanple
Type
Organic Nitrogen 00605
20.45
1.7
62.4
1/30
41
C
Phosphorus 00665
3.02
0.2
8.1
1/30
41
C
Oil & Grease W550
6.99
<1
41
4/YR
18
G
Color 00080
25 units
25 units
25 units
NA
1
C
Ammonia 00610
0.1
0.1
0.1
NA
1
C
Nitrate 00620
35
35
35
NA
1
C
Nitrite 00615
0.10
0.10
0.10
NA
1
C
Sulfate 00945
1500
1500
1500
NA
1
C
Chloride 00940
59
59
59
NA
1
C
Aluminum 01105
740
740
740
NA
1
C
Fecal Coliform Bacteria 74055
2100 col/dl
2100 col/dl
2100 col/dl
NA
1
G
Surfactants 38260
0.446
0.446
0.446
NA
1
C
Total Iron 01045
0.423
0.423
0.423
NA
1
C
Fluoride 00951
180
180
180
NA
1
C
CENTRAL FILE$
DEQ-CFW 00077549
FOR AGENCY USE
17. (Cont'd)
DISCHARGE SERIAL NUMBER
001
Effluent
Daily
Mimimum
Maximum
Frequency
Number of
Sanple
Average
Value
Value
of Analysis
Analyses
Type
(all values
Observed
Observed
are ug/L)
During
Discharge
During
Discharge
Activitv
Activity
Acrolein 34210
LT 50
LT 50
LT 50
1/YR
5
G
Acrylonitrile 34215
LT 50
LT 50
LT 50
1/YR
6
G
Benzene 34030
LT 5
LT 5
LT 5
1/YR
6
G
Bromoform 32104
LT 5
LT 5
LT 5
1/YR
6
G
Carbon Tetrachloride 32102
LT 5
LT 5
LT 5
1/YR
6
G
Chlorobenzene 34301
LT 6
LT 6
LT 6
1/YR
5
G
Chlorodibromomethane 32105
LT 5
LT 5
LT 5
1/YR
6
G
Chloroethane 34311
LT 10
LT 10
LT 10
1/YR
6
G
2-Chloroeth lvin 1 ether 34576
LT 10
LT 10
LT 10
1/YR
5
G
Chloroform 32106
LT 5
LT 5
LT 5
1 /YR
6
G
Dichlorobmmomethane 32101
LT 5
LT 5
LT 5
1/YR
5
G
1 1-Dichloroethane 34496
LT 5
LT 5
LT 5
1/YR
6
G
1,2-Dichloroethane 34531
LT 5
LT 5
LT 5
1/YR
6
G
1,1-Dichloroethlene 34501
LT 5
LT 5
LT 5
1/YR
6
G
1,2-Dichloropropane 34541
LT 6
LT 6
LT 6
1/YR
5
G
1,3-Dichloropropylene 34699
LT 5
LT 5
LT 5
1/YR
6
G
Ethlbenzene 34371
LT 8
LT 8
LT 8
1/YR
6
G
Methyl Bromide 34413
LT 10
LT 10
LT 10
1/YR
5
G
Methyl Chloride 34418
LT 10
LT 10
LT 10
1/YR
6
G
Methylene Chloride 34423
LT 5
LT 5
LT 5
1/YR
6
G
1,1,2,2-Tetrachloroedme 34516
LT 7
LT 7
LT 7
1/YR
5
G
Tetrachloroethlene 34475
LT 5
LT 5
LT 5
1/YR
6
G
Toluene 34010
LT 6
LT 6
LT 6
1/YR
6
G
1,2-trans-dichloroethlene 34546
LT 5
LT 5
LT 5
1/YR
5
G
1,1,1-Trichloroethane 34506
LT 5
LT 5
LT 5
1/YR ..
_..- b _
1,1,2-Trichloroedme 34511
LT 5
LT 5
LT 5
1/YR
1/YR
Trichlorodh lene 39180
LT 10
LT 10
LT 10
6
Vinyl Chloride 39175
LT 10
LT 10
LT 10
1/YR
JWL 3
096
CENTRAL FILES
DEQ-CFW 00077550
FOR AGENCY USE
DISCHARGE SERIAL NUMBER
001
17. (Cont'd)
Effluent
Daily
Average
(all values
are ug/L)
Mimimum
Value
Observed
During
Discharge
Activity
Maximum
Value
Observed
During
Discharge
Activity
Frequency
of Analysis
Number of
Analyses
Sanple
Type
2-Chloro henol 34586
LT 10
LT 10
LT 10
1/YR
6
C
2,4-Dichloro henol 34601
LT 10
LT 10
LT 10
1/YR
6
C
2,4-Dimeth 1 henol 34606
LT 10
LT 10
LT 10
1/YR
6
C
4,6-Dinitro-o-cresol 34657
LT 50
LT50
LT 50
1/YR
6
C
2,4-Dinitro henol 34616
LT 50
LT 50
LT 50
1/YR
6
C
2-Nitrophenol 34591
LT 10
LT 10
LT 10
1/YR
6
C
4-Nitrophenol 34646
LT 50
LT 50
LT 50
1/YR
6
C
P-chloro-m-cresol 34452
LT 10
LT 10
LT 10
1/YR
5
C
Pentachlorophenol 39032
LT 50
LT 50
LT 50
1/YR
5
C
Phenol 34694
LT 10
LT 10
LT 10
1/YR
6
C
2,4,6-Trichlorophenol 34621
LT 10
LT 10
LT 10
1/YR
5
C
Acena hthene 34205
LT 10
LT 10
LT 10
1/YR
6
C
Acena hth lene 34200
LT 10
LT 10
LT 10
1/YR
6
C
Anthracene 34220
LT 10
LT 10
LT 10
1/YR
6
C
Benzidine 39120
LT 50
LT 50
LT 50
UYR
5
C
Benz a thracene 34526
LT 10
LT 10
LT 10
1/YR
6
C
Benz a ene 34247
LT 10
LT 10
LT 10
1/YR
6
C
3,4-benzofluoranthene 34230
LT 10
LT 10
LT 10
1/YR
6
C
Benz lene 34521
LT 10
LT 10
LT 10
1/YR
5
C
Benz k fluoranthene 34242
LT 10
LT 10
LT 10
1/YR
6
C
Bi 2-chloroetho ethane 34278
LT 10
LT 10
LT 10
1/YR
5
C
Bi 2-chloroeth 1 ther 34273
LT 10
LT 10
LT 10
1/YR
5
C
Bi 2-chloroi 1 er 34283
LT 10
LT 10
LT 10
1/YR
5
C
Bis 2-eth the 1 hthalate 39100
16.3
LT 10
81
1/YR
6
C
4-Bromophenyl phenyl ether 34636
LT 10
LT 10
LT 10
1/YR
Bu i 1 hthalate 34292
LT 10
LT 10
LT 10
1/YR
PUL.
2-Chlorona hthalene 34581
LT 10
LT 10
LT 10
1/YR
4-Chloro hen 1 phenyl ether 34641
LT 10
LT 10
LT 10
1/YR
5
�Cq
C96
i
CENTRAL FILES
DEQ-CFW 00077551
FOR AGENCY USE e
17. (Cont'd)
DISCHARGE SERIAL NUMBER
001
Daily Mimimum Maximum Frequency Number of Sanple
Average Value Value of Analysis Analyses Type
(all values Observed Observed
are ug/L) During During
Discharge Discharge
Activity Arti Atv
Chrysene 34320
LT 10
LT 10
LT 10
I/YR
6
C
Dibenz a,h thracene 34556
LT 10
LT 10
LT 10
I/YR
6
C
1,2-dichlorobenzene 34536
LT 10
LT 10
LT 10
I/YR
6
C
1,3-dichlorobenzene 34566
LT 10
LT 10
LT 10
I/YR
6
C
1,4-dichlorobenzene 34571
LT 10
LT 10
LT 10
I/YR
6
C
3,3'-dichlorobenzidine 34631
LT 20
LT 20
LT 20
I/YR
6
C
Diethyl phthalate 34336
LT 10
LT 10
LT 10
I/YR
6
C
Dimeth 1 phthalate 34341
LT 10
LT 10
LT 10
I/YR
6
C
Di-n-butyl phthalate 39110
LT 10
LT 10
LT 10
I/YR
6
C
2,4-dinitrotoluene 34611
LT 10
LT 10
LT 10
I/YR
6
C
2,6-dinitrotoluene 34626
LT 10
LT 10
LT 10
1/YR
6
C
Di-n-octyl phthalate 34596
LT 10
LT 10
LT 10
I/YR
5
C
1,2-di hen lh drazine 34346
LT 10
LT 10
LT 10
I/YR
6
C
Fluroranthene 34376
LT 10
LT 10
LT 10
I/YR
6
C
Fluorene 34381
LT 10
LT 10
LT 10
UYR
6
C
Hexachlorobenzene 39700
LT 10
LT 10
LT 10
I/YR
6
C
Hexachlorobutadiene 34391
LT 10
LT 10
LT 10
I/YR
5
C
Hexachlorocyclopentadiene 34386
LT 10
LT 10
LT 10
I/YR
6
C
Hexachloroethane 34396
LT 10
LT 10
LT 10
I/YR
6
C
Inden 1,2,3-cd ene 34403
LT 10
LT 10
LT 10
I/YR
6
C
Iso horone 34408
LT 10
LT 10
LT 10
I/YR
5
C
Na thalene 34696
LT 10
LT 10
LT 10
I/YR
6
C
Nitrobenzene 34447
LT 10
LT 10
LT 10
I/YR
6
C
N-mtrosodimeth lamme 34438
LT 10
LT 10
LT 10
I/YR
6
C
N-mtrosodi-n-propylamme 34428
LT 10
LT 10
LT 10
I/YR
5.;.:.:..
C
N-nitrosodi hen lamine 34433
LT 10
LT 10
LT 10
I/YR
Phenanthrene 34461
LT 10
LT 10
LT 10
I/YR
C
Pyrene 34469
LT 10
LT 10
LT 10
I/YR
6
1,2,4-trichlorobenzene 34551
LT 10
LT 10
LT 10
I/YR
6 1
C
CENTRAL FILE$
DEQ-CFW 00077552
FOR AGENCY USE
DISCHARGE SERIAL NUMBER
001
17 (rnnt'r1)
Effluent
Daily
Average
(all values
are ug/L)
Mimimum
Value
Observed
During
Discharge
Activity
Maximum
Value
Observed
During
Discharge
Activity
Frequency
of Analysis
Number of
Analyses
Sanple
Type
Aldrin 39330
LT 0.050
LT 0.050
LT 0.050
NA
1
C
Al ha-BHC 39337
LT 0.050
LT 0.050
LT 0.050
NA
1
C
Beta-BHC 39338
LT 0.050
LT 0.050
LT 0.050
NA
1
C
Gamma-BHC 39340
LT 0.050
LT 0.050
LT 0.050
NA
1
C
Delta-BHC 34259
LT 0.050
LT 0.050
LT 0.050
NA
1
C
Chlordane 39350
LT 0.50
LT 0.50
LT 0.50
NA
1
C
4,4'-DDT 39300
LT 0.10
LT 0.10
LT 0.10
NA
1
C
4,4'-DDE 39320
LT 0.10
LT 0.10
LT 0.10
NA
1
C
4,4'-DDD 39310
LT 0.10
LT 0.10
LT 0.10
NA
1
C
Dieldrin 39380
LT 0.10
LT 0.10
LT 0.10
NA
1
C
Al ha-Endosulfan 34361
LT 0.050
LT 0.050
LT 0.050
NA
1
C
Beta-Endosulfan 34356
LT 0.10
LT 0.10
LT 0.10
NA
1
C
Endosulfan Sulfate 34351
LT 0.10
LT 0.10
LT 0.10
NA
1
C
Endrin 39390
LT 0.10
LT 0.10
LT 0.10
NA
1
C
Endrin Aldehyde 34366
LT 0.10
LT 0.10
LT 0.10
NA
1
C
Heptachlor 39410
LT 0.050
LT 0.050
LT 0.050
NA
1
C
Heptachlor Epoxide 39420
LT 0.050
LT 0.050
LT 0.050
NA
1
C
PCB-1242 39496
LT 0.50
LT 0.50
LT 0.50
NA
1
C
PCB-1254 39504
LT 1.0
LT 1.0
LT 1.0
NA
1
C
PCB-1221 39488
LT 0.50
LT 0.50
LT 0.50
NA
1
C
PCB-1232 39492
LT 0.50
LT 0.50
LT 0.50
NA
1
C
PCB-1248 39500
LT 0.50
LT 0.50
LT 0.50
NA
1
C
PCB-1260 39508
LT 1.0
LT 1.0
LT 1.0
NA
1
C
PCB-1016 34671
LT 0.50
LT 0.50
LT 0.50
NA
1
C
Toxa hene 39400
LT 5.0
1 LT 5.0
LT 5.0
NA
1
C
n
I
CENTRAL FILES
. _.r
DEQ-CFW 00077553
FOR AGENCY USE
DISCHARGE SERIAL NUMBER
001
17 (Cnnt'd)
Effluent
Daily
Average
(all values
are ug/L)
Mimimum
Value
Observed
During
Discharge
Activity
Maximum
Value
Observed
During
Discharge
Activity
Frequency
of Analysis
Number of
Analyses
Sanple
Type
Antimony, Total 01097
LT 50
LT 50
LT 50
NA
1
C
Arsenic, Total 01002
LT 10
LT 10
LT 10
NA
1
C
Beryllium, Total 01012
LT 25
LT 25
LT 25
NA
1
C
Cadmium Total 01027
LT 2
LT 2
LT 2
NA
1
C
Chromium, Total 01034
LT 5
LT 5
LT 5
NA
1
C
Copper, Total 01042
4.03
4.03
4.03
NA
1
C
Lead, Total 01051
LT 10
LT 10
LT 10
NA
1
C
Mercury, Total 71900
LT 0.200
LT 0.200
LT 0.200
NA
1
C
Nickel, Total 01067
LT 10
LT 10
LT 10
NA
1
C
Selenium, Total 01147
LT 5
LT 5
LT 5
NA
I
C
Silver Total 01077
LT 5
LT 5
LT 5
NA
1
C
Thallium, Total 01059
LT 10
LT 10
LT 10
NA
1
C
Zinc, Total 01092
64.1
64.1
64.1
NA
1
C
Cyanide, Total 00720
LT 0.010
LT 0.010
LT 0.010
NA
1
G
Phenols Total 32730
LT 0.005
LT 0.005
LT 0.005
NA
1
G
JUL ZA) 1996
CENTRAL FILES
DEQ-CFW 00077554
1
1
1
1
1
d Chemical composition of these I 219d
ns additives (see instructio)
Complete Items 20-25 if there is a thermal discharge
(e.g., associated with a steam and/or power generation
plant, steel mill, petroleum refinery, or any other
manufacturing process) and the total discharge flow is
10 million gallons per day or more. (see instructions)
20. Thermal Discharge Source_ Check 220
the appropriate item(s) incicating
the source of the discharge (see
instructions)
Boiler Blowdown
Boiler Chemical Cleaning
Ash Pond Overflow
Boiler Water Treatment -
Evaporator Slowdown
Oil and Coal Fired Plants -Effluent
from Air Pollution Control Devices
Condense Cooling Water
Cooling Tower Blowdown
Manufacturing Process
Other
21. Discharge/Receiving Water
Temperature Difference
Give the maximum temperature
difference between the discharge
and receiving waters for summer
and winter operating conditions
(see instructions)
Summer 221a
Winter 221b
22. Discharge Temperature , Rate of
Change Per Hour 222
Give the maximum possible rate of
temperature change per hou r of
discharge under operating
conditions (see instructions)
23. Water Temperature, Percentile
Repo rt(F requency of Occum3nce)
In the table below, enter the
temperature which is exceeded 10%
of the year, 5% of the year, 1 % of
the year and not at all (maximum
yearly temperature). (see
instructions)
Frequency of occurrence
a. Intake Water Temperature 223a
(subject to natural changes
b. Discharge Water Temperature 223b
24. Water Intake Velocity 224
(see instructions)
25. Retention Time Give the length of 225
time, in minutes, from start of
water temperature rise to discharge
of cooling water. (see instructions)
DISCHARGE SERIAL NUMBER
001
BLBD
[� BCCL
APOF
EPBD
M OCFP
Ll COND
CTBD
[] MFPR
7 OTHR
'F
OF
OF./hour
1 /o
io
1 re
Maximum
OF
OF
OF
OF
OF
OF
OF
OF
teet/sec.
minutes
JUL 30 1996
CENTRAL FILE$
DEQ-CFW 00077555
DISCHARGE SERIAL NUMBER
001
Additional Information
JUL 3"" 1996
CENTRAL FILES
DEQ-CFW-00077556
STANDARD FORM C - MANUFACTURING AND COMMERCIAL
SECTION II. BASIC DISCHARGE DESCRIPTION
Complete this section for each discharge Indicated In Section
which the waste water does not go through a treatment works
also discharges to surface waters from this facility. SEPARAI
ORIGINATE IN THE SAME FACILITY. All values for an exists
discharge, values should reflect best engineering estimates.
ADDITIONAL INSTRUCTIONS FOR SELECTED ITEMS
BEFORE FILLING OUT THESE ITEMS.
1. Discharge Serial No. and Name
a Discharge Serial No. 201a
(see instructions)
b. Discharge Name 201b
Give the name of discharge, if
any (see instructions)
c. Previous Discharge Serial No 2D1c
If a previous permit
application was made for this dis-
charge (Item 4, Section 1) provide
previous discharge serial
number.
2 Discharge Operating Dates
a Discharge Began Date 202a
If the discharge described below
is in operation, give the date
(within best estimate) the
discharge began
b. Discharge to Begin Date 202b
If the discharge has never
occurred but is planned for some
future date, give the date the
discharge III begin.
c. Discharge to End Date If the 202c
discharge is scheduled to be
discontinued within the next 5
years, give the date (within best
estimate) the discharge will end.
3. Engineering Report Available
Check If an engineering report is
available to reviewing agency
upon request (see instructions) 203
4. Discharge Location Name the
political boundaries within which
the point of discharge is located:
State
County
'
(If applicable) City or Town
Discharge Point Description
(see instructions)
Discharge into (check one)
Stream (Includes ditches, arroyos,
and other wateroourses
Lake
Ocean
Municipal Sanitary Wastewater
Transport System
Municipal Combined Sanitary
and Storm Transport System
1, Items Dischares 9,ntghat is torged surface waters. This Includes gdiischarges, to municipal sewerage systems in
e omust be described where there DESCRIPT ONS OF EACH DISCHARGE to surface wateni. RE REQUIRED (ls EVEN IF SEVERAL DI CHA GES e
ig discharge should be representative of the twelve previous months of operation. M this is a proposed
iPPEAR IN SEPARATE INSTRUCTION BOOKLET AS INDICATED. REFER TO BOOKLET
002
Final Facility Effluent D;GrhargP
002
71 02
N/A
YR MO
N/A
YR MO
en Use
North Carolina 204d
Bladen 204e
Duart 204f
205a I ® STR
LKE
OCE
MTS
MCS
titt�
JUL 30 1996
I
CENTRAL FILE$
DEQ-CFW 00077557
L
h
Municipal Storm Water Transport
System
Well (injection)
Other
If'other' is checked, specify type
6. Discharge Point - Lat/Long.
Give the precise location of the
point of discharge to the nearest
second.
Latitude
Longitude
7. Discharge Receiving Water Name
Name the waterway at the point of
discharge. (see instructions)
If the discharge is through an outfall that extends
beyond the shoreline or is below the mean low
water line, complete item 8,
pf AOe^_ IJSe
Mao• M^7
Suo
For Aae^cv Use
e
8. Offshore Discharge
a. Discharge Distance from Shore
b. Discharge Depth Below Water
9 Discharge Type and Occurrence
a Type of Discharge Check
whether the discharge is
continuous or intermittent
(See instructions)
b. Discharge Occurrence Days
per Week. Enter the average
number of days per week
(during periods of discharge)
this discharge occurs.
c. Discharge Occurrence- Months
If this discharge normally oper-
ates (either intermittently or
continuously) on less than a yea
around basis (excluding shut-
- downs for routine maintenance)
check the months during the ye4
when the discharge is operating
(see instructions)
Complete Items 10 and 11 if 'intermittent' is
checked in Item 9.a. Otherwise, proceed to
Item 12.
10. Intermittent Discharge Quantity
State the average volume per dis-
charge occurrence in thousands of
gallons
11. Intermittent Discharge Duration
and Frequency
a Intermittent Discharge Duration
Per Day State the average
numberof hours perday the
discharge is operating
b. Intermittent Discharge
Frequency State the average
number of discharge occurBno
per day during days when
discharging
12. Maximum Flow Period Give the
time period in which the maximum
flow of this discharge occurs
205b
206a
206b
207a
207b
207c I
mp�_
�7
F•'
210
211a
21lb
212
DISCHARG�8FRIAL NUMBER
STS L
WEL
OTH
3_ DEG. U_MIN. _SEC
W78 DEG. 50 MIN. 00 SEC
Un—named stream to Cape Fear River
N/A feet
N/A feet
(con) Continuous
(int) Intermittent
7 days per week
:E�JAN
FEB
f3 MAR
JaAPR
MAY
igJUN
aJUL
AUG
SEP
JaOCT
NOV
DEC
thousand gallons per day
hours per day
discharge occurrences per day
From N/A to N/A
month month
L
CENTRAL FfLES
DEQ-CFW 00077558
DISCHARGE SERIAL NUMBER
002
13. Activity Description Give a 213a 1— Perfluorinated sheeting Drocess — neutralized
narrative description of activity nitric acid
producing this discharge (see 2— Boiler blowdown and condensate
instructions) 3— Cooling Tower blowdown
4— StolMater
5— Non —contact cooling water (filtered
water and raw river water)
14. Activity Causing Discharge For each SIC Code which
describes the activity causing this discharge, supply the
type and maximum amount of either the raw material
consumed (Item 14a) or the product produced (Item 14b)
in the units specified in Table I of the Instruction Booklet..
For SIC Codes not listed in Table I, use raw material or
production units normally used for measuring production
(see instructions)
a Raw Materials
Maximum Unit Shared Discharges
CIr` el-4. Ahme Omnunr/rtav (See Table Il (Serial Number)
214
#1
#2
#3
#4
#5
21
a nl
4
4939
Water
0.133
MGD
001
4939
Water
0.08
M
N/A
Water
2.647
MGD
001
2821,2969
Water
3081, 3083
b. Products
O NTRAL FILES '
DEQ-CFW 00077559
jj
DISCHARGE SERIAL NUMBER
002
13. Activity Description Give a 213a 6— Treated wastewater effluent
narmtrve description of activity from Facility's Wastewater Treatment
producing this discharge (see Plant (Outfall 001)
instructions)
14. Activity Causing Discharge For each SIC Code which
descnbes the activity causing this discharge, supply the
type and maximum amount of either the raw material
consumed (Item 14a) or the product produced (Item 14b)
in the units specified in Table I of the Instruction Booldet..
For SIC Codes not listed in Table 1, use raw material or
production units normally used for measuring production
(see instructions)
a Raw Materials
Maximum Unit Shared Discharges
SIC reyirt Name Ameunt/r)av fq" Tahla 11 lSpnal Ni,rnhorl
219
21
a (1)
)
4
#6 N/A
Outfall 001
1.79
MGD
001
b. Products
Maximum Unit Shared Discharges
JUL !a
DEQ-CFW-00077560
' 15 Waste Abatement
a Waste Abatement Practices
Describe the waste abatement
' practices used on this dis-
charge with a brief narrative
(see instructions)
' b. Waste Abatement Codes
Using the codes listed in Table
II of the Instruction Booklet,
' describe the waste abatement
processes for this discharge in
the order in which they occur
if possible.
DISCHARGE SERIAL NUMBER
002
215a Narrative; Dilute nitric
acid is neutralized with
Potassium hydroxide.
215b (1) CNEUTR (2)
(3)
(4} (5)
(6)
(7) (8)
(9)
(10) (11)
(12)
(13) (14)
(15)
(16) (1
(18)
(19) (20)
(21)
(22) (23)
(24)
(25)
JUL 30 1996
CENTRAL FI►,E$
DEQ-CFW 00077561
DISCHARGE SERIAL NUMBER
002
16. Wastewater Characteristics
Check the box beside each constituent which is present in the effluent (discharge water). This determination is to
based on actual analysis or best estimate. (see instructions)
arameter
Present
Parameter
Present
216
216
olor
pper
00080
X
0102
Ammonia
on
00610
X
0145
0
X
nitrogen
�1c
5
X
01051
Nitrate
00620
X
Magnesium
00927
Nitrite
manganese
00615
01056
Phosphorus
Mercury
00665
71900
Sulfate
Molybdenum
00945
X
01062
buinde
ICKe
00745
01067
501te
Selenium
00740
01147
oroml a
anver
71870
01077
Ion e
r otasswm
00940
X
00937
X
Uyanicle
Soclum
00720
00929
rluon e
I nalhurn
00951
X
01059
Aluminum
I itanium
01105
X
01152
Antimony
hn
01097
X
01102
Arsenic
01002
inc
01092
X
Beryllium
igiCi s
01012
74051
X
num
Cnionnated organic compounds'
01007
74052
ion
Pesticides
01022
74063
a mium
Oil and grease
01027
00650
X
alcwm
en
00916 .
32730
Surfactants;
X
01037
3&260
Chromium
X
01034
5M
ecai cc I orm bacteria
Haciioactivity
74055
X
74050
be
Specify substances, compounds and/or elements in Item 26.
Pesticides (insecticides, fungicides, and rodenticiddes) must be reported in terms of the acceptable common names specified in Acceptable Common Names
and Chemical names for Cie In_gedenf Statement on PesUdde Labels, 2nd Edition, Environmental Protection Agency, Washington, D.C. 20250, June 1972, as
required by Subsection 162.7(b]i of the Regulations for the Enforcement of the Federal Insecticide, Fungicide, and Rodenticide Act
t
a t
Wit
3 c , 190
r,ft4TRAL
DEQ-CFW 00077562
1111111111
DISCHARGE SERIAL NUMBER
002
17. Description of Intake and Discharge
For each of the parameters listed below, enter in the appropriate box the value or code letter answer called for (see instructions)
In addition, enter the parameter name and code and all required values for any of the following parameters if they ere chocked in Item 16:
ammonia, cyanide, aluminum, arsenic, beryllium, cadmium, chromium, copper, lead, mercury, nickel, selenium, zinc, phenols, oil and grease, and
chlorine (residual).
Influent
Effluent
Untreated
In -Plant
ai y
minimum
Maximum
nequency
um r o
Sample
Parameter and Code
Intake
Treated
Average
Value
Value
of Analysis
Analyses
Type
Water
Intake
Observed or
Observed or
217
(Daily
Water
Expected
Expected
average)
(Daily
During
During
average)
Discharge
Discharge
Activity
Activity
(i) 1
(2)
(3) 1
J4
5
6
(7)
(8
low
MGD
50050
15.10
3.10
15.10
12.96
21.91
CONT
1278
N/A
P
Units
00400
6.7
N/A
6.0
8.8
3/7
546
G
i (venter)
Cmperature
74026
10.8
N/A
17.6
8
26
7/7
1278
G
�mperature summer)
::
74025
22.9
N/A
26.9
15
36
7/7
1278
G
ioc emcia xygen
Demand
(BOD 5-Day)
mg/I
00310
LT 2.0
LT 2. C
6.6
T 1
70
4/YR
14
C
-Me—mical uxygen
Demand (COD)
ODUO
109
LT 25
55.4
T 5
392
4/YR
14
C
Totalspen
(nonfilterable) Solids
mg/I
005M
27
LT 6
LT 6
LT 6
LT 6
N/A
1
C
Speahc Qonductance
micromhos/cm at 25'C
00095
109
1140
540
540
N/A
1
C
Settle -able Matter
(residue)
mIA
00545
LT 0.1
LT 0.1ILTO.LT
0.1
1 LT 0.1
N/A
1
C
Other discharges sharing intake flow (serial numbers) (see instructions)
Fit ;
'; T!
1996
CENTRAL FILES
DEQ-CFW 00077563
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
DISCHARGE SERIAL NUMBER
002
17 (Conrd)
Parameter and Code
217
Innuent
Emuent
untreatedIn-plant
Intake
Water
(Daily
average)
(1)
Treated
Intake
Water
(Daily
average)
2)
ai y
Average
1(3)
Minimum
Value
Observed or
Expected
During
Discharge
Activity
4
maximum
Value
Observed or
Expected
During
Discharge
Activity
5
requency
of Analysis
6
Number
of
Analyses
7
e
Type
8)
See attached
page for Item
18. Plant Controls Check if the following
plant controls are available for this
discharge
218
Alternate power source for major
pumping facility
X APS
Alarm or emergency procedure for
power or equipment failure
® ALM
Complete Item 19 if discharge is frorr
cooling and/or steam water
generation and water treatment
additives are used
19. Water Treatment Additives If the
discharge is treated with any
conditioner, inhibitor, or algicide,
answer the following:
a Name ofMaterial(s)
219a
*Note: Outfall 002 discharge is not treated
with any chemicals. However. the BCH Energy
Project's Boiler and Cooling Tower waters contain
b. Name and address of
219b
treatment additives. which are discharged through
manufacturer
Outf all 002.
See attached paste for Item 19.
c, Quantity (pounds added per
219c
million gallons of water treated)
A
jUL 30 1996
Cr�JTRAL FlLF a
DEQ-CFW 00077564
FOR AGENCY USE
1
1
1
1
1
1
1
1
1
1
DISCHARGE SERIAL NUMBER
002
17 trnnt,d)
Effluent
Daily
Average
(all values
are mg/L)
Mimimum
Value
Observed
During
age
Activity
Maximum
Value
Observed
During
Discharge
Activity
Frequency
of Analysis
Number of
Analyses
Sariple
Type
Fluoride 00951
6.85
0.02
86
1/7
178
C
Color 00080
100 units
100 units
100 units
NA
1
C
Ammonia 00610
0.1
0.1
0.1
NA
1
C
Nitrate 00620
2.3
2.3
2.3
NA
1
C
Nitrite 00615
0.04
0.04
0.04
NA
1
C
Sulfate 00945
130
130
130
NA
1
C
Chloride 00940
14
14
14
NA
1
C
Aluminum 01105
1950
1950
1950
NA
1
C
Fecal Coliform Bacteria 74055
690 col/d1
690 col/dl
690 col/dl
NA
1
C
Surfactants 38260
0.252
0.252
0.252
NA
1
C
Organic Nitrogen 00605
0.8
0.8
0.8
NA
1
C
Total Phosphorus 00665
0.17
0.17
0.17
NA
1
C
Total Iron 01045
1.44
1.44
1.44
NA
1
C
Total Sodium 00929
44.8
44.8
44.8
NA
1
C
Total Potassium 00937
82.5
82.5
82.5
NA
1
C
Oil & Grease 00550
LT 5
LT 5
LT 5
NA
1
C
CENTRP►� FILES
DEQ-CFW 00077565
FOR AGENCY USE
DISCHARGE SERIAL
NUMBER
'
002
17. (Cont'd)
Effluent
'
Daily
Mimimum
Maximum
Frequency
Number of Sanple
Average
Value
Value
of Analysis
Analyses Type
Observed
Observed
'
(all values
During
During
are ug/L)
Discharge
Discharge
Activity
Activity
'
Acrolein
34210
LT 5
LT 5
LT 5
NA
1
G
Acrylonitrile
34215
LT 5
LT 5
LT 5
NA
1
G
'
Benzene
34030
LT 5
LT 5
LT 5
NA
1
G
Bromoform
32104
LT 5
LT 5
LT 5
NA
1
G
'
Carbon Tetrachloride
32102
LT 5
LT 5
LT 5
NA
1
G
Cblorobenzene
34301
LT 5
LT 5
LT 5
NA
1
G
Chlorodibromometime
32105
LT 5
LT 5
LT 5
NA
1
G
'
Chloroedme
34311
LT 10
LT 10
LT 10
NA
1
G
2-Chlometh lvin 1 ether
34576
LT 10
LT 10
LT 10
NA
1
G
'
Chloroform
32106
LT 5
LT 5
LT 5
NA
1
G
Dichlorobromomethane
32101
LT 5
LT 5
LT 5
NA
1
G
'
1,1 Dichloroethane
34496
LT 5
LT 5
LT 5
NA
1
G
1,2-Dichloroedme
34531
LT 5
LT 5
LT 5
NA
1
G
1,1-Dichloroeth lene
34501
LT 5
LT 5
LT 5
NA
1
G
'
1,2-Dichloropropane
34541
LT 5
LT 5
LT 5
NA
1
G
1,3-Dichloro lene
34699
LT 5
LT 5
LT 5
NA
1
G
'
Eth lbenzene
34371
LT 5
LT 5
LT 5
NA
1
G
Methyl Bromide
34413
LT 10
LT 10
LT 10
NA
1
G
'
Methyl Chloride
34418
LT 10
LT 10
LT 10
NA
1
G
Methylene Chloride
34423
LT 5
LT 5
LT 5
NA
1
G
1,1,2,2-Tetrachloroethane
34516
LT 5
LT 5
LT 5
NA
1
G
'
Tetrachloroeth lene
34475
LT 5
LT 5
LT 5
NA
1
G
Toluene
34010
LT 5
LT 5
LT 5
NA
1
G
'
1,2-trans-dichloroeth lene
34546
LT 5
LT 5
LT 5
NA
1
G
1,1,1-Trichloroethane
34506
LT 5
LT 5
LT 5
NA
1
G
'
1,1,2-Trichloroethane
34511
LT 5
LT 5
LT 5
NA
Trichloroeth lene
39180
LT 5
LT 5
LT 5
NA
t
Vinyl Chloride
39175
LT 10
LT 10
LT 10
NA
Ila
Jul
CENI�AL FILES
'
DEQ-CFW 00077566
FOR AGENCY USE
DISCHARGE SERIAL NUMBER
002
17 trnnt'Al
Effluent
Daily
Average
(all values
are ug/L)
Mimimum
Value
Observed
During
Discharge
Activity
Maximum
Value
Observed.
Dung
Discharge
Activity
Frequency
of Analysis
Number of
Analyses
Sanple
Type
2-Chloro henol 34586
LT 10
LT 10
LT 10
NA
1
C
2,4-Dichlor henol 34601
LT 10
LT 10
LT 10
NA
1
C
2,4-Dimeth 1 henol 34606
LT 10
LT 10
LT 10
NA
1
C
4,6-Dinitro-o-cresol 34657
LT 50
LT50
LT 50
NA
1
C
2,4-Dinitrophenol 34616
LT 50
LT 50
LT 50
NA
1
C
2-Nitrophenol 34591
LT 10
LT 10
LT 10
NA
1
C
4-Nitrophenol 34646
LT 50
LT 50
LT 50
NA
1
C
p-chloro-m-cresol 34452
LT 10
LT 10
LT 10
NA
1
C
Pentachloro henol 39032
LT 50
LT 50
LT 50
NA
1
C
Phenol 34694
LT 10
LT 10
LT 10
NA
1
C
2,4,6-Trichlorophenol 34621
LT 10
LT 10
LT 10
NA
1
C
Acena hthene 34205
LT 10
LT 10
LT 10
NA
1
C
Acena hthlene 34200
LT 10
LT 10
LT 10
NA
1
C
Anthracene 34220
LT 10
LT 10
LT 10
NA
1
C
Benzidine 39120
LT 50
LT 50
LT 50
NA
1
C
Benz a thracene 34526
LT 10
LT 10
LT 10
NA
1
C
Benz a ene 34247
LT 10
LT 10
LT 10
NA
1
C
3,4-benzofluoranthene 34230
LT 10
LT 10
LT 10
NA
1
C
Benz lene 34521
LT 10
LT 10
LT 10
NA
1
C
Benz fluoranthene 34242
LT 10
LT 10
LT 10
NA
1
C
Bi 2-chloroetho ethane 34278
LT 10
LT 10
LT 10
NA
1
C
Bi 2-chloroeth 1 ther 34273
LT 10
LT 10
LT 10
NA
1
C
Bi 2-chloroi 1 er 34283
LT 10
LT 10
LT 10
NA
1
C
Bis 2-eththe 1 hthalate 39100
LT 10
LT 10
LT 81
NA
1
C
4-Bromophenyt phenyl ether 34636
LT 10
LT 10
LT 10
NA
1
C
Butylbenzyl phthalate 34292
LT 10
LT 10
LT 10
NA
C
2-Chlorona hthalene 34581
LT 10
LT 10
LT 10
NA
4-Chloro hen 1 phenyll ether 34641
LT 10
LT 10
LT 10
NA
30C1996
�EN�RAt. F11.ES
DEQ-CFW 00077567
FOR AGENCY USE
1
DISCHARGE SERIAL
NUMBER
'
002
17. (Cont'd)
Effluent
Daily
Mimimum
Maximum
Frequency
Number of
Sanple
Average
Value
Value
of Analysis
Analyses
Type
Observed
Observed
'
(all values
Daring
During
are ualu
Discharge
Discharge
Activity
Activity
'
Chrysene
34320
LT 10
LT 10
LT 10
NA
1
C
Dibenz a,h thracene
34556
LT 10
LT 10
LT 10
NA
1
C
'
1,2-dichlorobenzene
34536
LT 5
LT 5
LT 5
NA
1
C
1,3-dichlorobenzene
34566
LT 5
LT 5
LT 5
NA
1
C
'
1,4-dichlorobenzene
34571
LT 5
LT 5
LT 5
NA
1
C
3,3'-dichlorobenzidine
34631
LT 10
LT 10
LT 10
NA
1
C
Diethyl plithalate
34336
LT 10
LT 10
LT 10
NA
1
C
Dimeth 1 phthalate
34341
LT 10
LT 10
LT 10
NA
1
C
Di-n-butyl plithalate
39110
LT 10
LT 10
LT 10
NA
1
C
'
2,4-dimtrotoluene
34611
LT 10
LT 10
LT 10
NA
1
C
2,6-dinitrotoluene
34626
LT 10
LT 10
LT 10
NA
1
C
Di-n-octyl phthalate
34596
23
23
23
NA
1
C
1,2-di hen lh drazine
34346
LT 10
LT 10
LT 10
NA
1
C
Fluroranthene
34376
LT 10
LT 10
LT 10
LT
NA
NA
1
1
C
C
Fluorene
34381
LT 10
LT 10
10
Hexachlorobenzene
39700
LT 10
LT 10
LT 10
NA
1
C
'
Hexachlorobutadiene
34391
LT 10
LT 10
LT 10
NA
1
C
Hexachlorocyclopentadiene
34386
LT 10
LT 10
LT 10
NA
1
C
Hexachloroethane
34396
LT 10
LT 10
LT 10
NA
1
C
Inden 1,2,3-cd a
34403
LT 10
LT 10
LT 10
NA
1
C
'
Iso horone
34408
LT 10
LT 10
LT 10
LT 10
NA
NA
1
1
C
C
Na thalene
34696
LT 10
LT 10
Nitrobenzene
34447
LT 10
LT 10
LT 10
NA
1
C
N-nitrosodimeth lamine
34438
LT 10
LT 10
LT 10
NA
1
C
N-nitrosodi-n-propylamine
34428
LT 10
LT 10
LT 10
NA
1
C
'
N-nitrosodi hen lamine
34433
LT 10
LT 10
LT 10
NA
Phenauthrene
34461
LT 10
LT 10
LT 10
NA
C
Pyrene
34469
LT 10
LT 10
LT 10
NA
1 Jul
3 ®CI996
'
1,2,4-dichlorobenzene
34551
LT 10
LT 10
LT 10
NA
1
C
CENTRAL
FILES
DEQ-CFW
00077568
• , a
FOR AGENCY USE
DISCHARGE SERIAL NUMBER
002
17. Wont'd)
Effluent
Daily
Average
(all values
are ug/L)
Mmumum
Value
Observed
Discharge During
Activity
Maximum
Value
Observed
During
Discharge
Activity
Frequency
of Analysis
Number of
Analyses
Sanple
Type
Antimony, Total 01097
LT 50
LT 50
LT 50
NA
1
C
Arsenic, Total 01002
LT 10
LT 10
LT 10
NA
1
C
Beryllium, Total 01012
LT 25
LT 25
LT 25
NA
1
C
Cadmium Total 01027
LT 2
LT 2
LT 2
NA
1
C
Chromium, Total 01034
LT 5
LT 5
LT 5
NA
1
C
Copper, Total 01042
6.83
6.83
6.83
NA
1
C
Lead, Total 01051
LT 10
LT 10
LT 10
NA
1
C
Mercury, Total 71900
LT 0.200
LT 0.200
LT 0.200
NA
1
C
Nickel, Total 01067
LT 10
LT 10
LT 10
NA
1
C
Selenium, Total 01147
LT 5
LT 5
LT 5
NA
1
C
Silver, Total 01077
LT 5
LT 5
LT 5
NA
1
C
Thallium, Total 01059
LT 10
LT 10
LT 10
NA
1
C
Zinc, Total 01092
18.8
18.8
18.8
NA
1
C
Cyanide, Total 00720
LT 0.010
LT 0.010
LT 0.010
NA
1
C
Phenols, Total 32730
LT 0.005
LT 0.005
LT 0.005
NA
1
C
mi
JUL 30 1996
UNTRAL FILES
DEQ-CFW 00077569
FOR AGENCY USE t
1
1
1
1
1
1
1
1
1
1
1
1
DISCHARGE SERIAL NUMBER
002
19. Water Treatment Additives. If the discharge is treated with any conditioner,
inhibitor, or algicide, answer the following:
219b Name and address
291 c Quantity (pounds added per
291 d Chemical
219a Name of Material
of manufacturer
million anon of water treated)
composition
Betz Industrial Corp
Bio-Trol 88P
Landmark Plaza
5 lb/day at the BCH Facility
See attached
4303-8 Oleander Dr.
(0.33 lb/million gal at Outfall 002)
DEM Form 101
Wilmington, NC
28403
Betz Industrial Corp
Cor-Trot 778P
Landmark Plaza
0.069 lb/day at the BCH Facility
See attached
4303-8 Oleander Dr.
(0.0046 lb/million gal at Outfall 002)
DEM Form 101
Wilmington, NC
29403
Betz Industrial Corp
Balanced Polymer 54400
Landmark Plaza
0.154 lb/day at the BCH Facility
See attached
4303-8 Oleander Dr.
(0.010 lb/million gal at Outfall 002)
DEM Form 101
Wilmington, NC
28403
Betz Industrial Corp
Opti-Meen
Landmark Plaza
0.038 lb/day at the BCH Facility
See attached
4303-8 Oleander Dr.
(0.0025 lb/million gal at Outfall 002)
DEM Form 101
Wilmington, NC
28403
Betz Industrial Corp
Continuum 29000
Landmark Plaza
3.60 lb/day at the BCH Facility
See attached
4303-8 Oleander Dr.
(0.238 lb/million gal at Outfall 002)
DEM Form 101
Wilmington, NC
29403
Note: The above additives are used solely in the BCH Energy Project Facility located at the Dupont Fayetteville
Works and which ultimately discharges through the DuPont Outfall 002.
DEQ-CFW 00077570
' d Chemical composition of these I 219d
additives (see instructions)
Complete Items 20-25 if there is a thermal discharge
' (e.g., associated with a steam and/or power generation
plant, steel mill, petroleum refinery, or any other
manufacturing process) and the total discharge flow is
10 million gallons per day or more. (see instructions)
' 20. Thermal Discharge Source_ Check 220
the appropriate items) indicating
the source of the discharge (see
instructions)
Boiler Blowdown
' Boiler Chemical Cleaning
Ash Pond Overflow
' Boiler Water Treatment -
Evaporator Blowdown
Oil and Coal Fired Plants -Effluent
from Air Pollution Control Devices
Condense Cooling Water
Cooling Tower Blowdown
' Manufacturing Process
Other
21. Discharge,'Receiving Water
Temperature Difference
' Give the maximum temperature
difference between the discharge
and receiving waters for summer
and winter operating conditions
' (see instructions)
Summer 221a
Winter 221b
' 22. Discharge Temperature, Rate of
Change Per Hour 222
Give the maximum possible rate of
temperature change per hour of
discharge under operating
conditions (see instructions)
23. Water Temperature, Percentile
Report(Frequency of Occurrence)
' In the table below, enter the
temperature which is exceeded 10%
of the year, 5% of the year, 1 % of
the year and not at all (maximum
yearly temperature). (see
instructions)
' Frequency of occurrence
a. Intake Water Temperature 223a
' (subject to natural changes
b. Discharge Water Temperature 223b
DISCHARGE SERIAL NUMBER
002
See attached D.E.M. Form 101
for compositions.
® BLBD
BCCL
APOF
EPBD
OCFP
COND
® CTBD
® MFPR
OTHR
10.8 OF
23.4 OF
0.5 °F./hour
1 /o
/0
1 /e
Maximum
84.6 OF
85.50F
87.2 OF
88.8°F
87.8 OF
I 91.40E
95 OF
I 96.8°F
' 24. Water Intake Velocity 224 1.6 feettsec.
(see instructions)
25. Retention Time Give the length of 225 35 minutes
' time, in minutes, from start of
water temperature rise to discharge
of cooling water. (see instructions)
JUL 1996
CENTRAL FILES
DEQ-CFW 00077571
26.
DISCHARGE SERIAL NUMBER
002
Additional Informabon
Item
intormalmn
16
Biocide used in the BCH Energy Project's Cooling Tower is
BETZ Bio-Trol 88P. For all the treatment chemicals used in
the facility, a D.E.M. Form 101 is attached.'
JUL 30 1996
DEQ-CFW-00077572
Facility Name: DuPont Comnanv - Fayetteville Works NPDES #: NC nnn A523
BIOCIDE/CHEMICAL TREATMENT
WORKSHEET-FORM 101
The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of
North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet is to be
returned with all appropriate data entered into the designated areas with calculations performed as indicated.
I. Facility Name DuPont Company - Fayetteville Works
NPDES # NC 0003573 --
County Bladen -
Receiving Stream Cape Fear River 7010 791 (cfS)
(All above information suppled by the Division of Environmental Management)
What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water body?
A.D.D. - 12.2 (in M.G.D.)
Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered
above.
IWC - (A.D.D.) X 100 _ (12.2 ) X 100 = 2.3 %
(7Q10)(0.646) — (791 )(0.646) + (A.D.D.)
This value (IWC) represents the waste concentration to the receiving stream during low flow conditions.
What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I?
8E 2- C'or— To / '7W P
Please fist the active ingredients and percent composition: Py„P,•�s7wy
=%
rr %
%
What feed or dosage rate (D.R.) is used in this application? The units must be converted to grams of whole
' product used per day.
D.R.= L grams/day
' JUL 30 1996
D.E.M. Form 101 (7/92) 1 � �
DEQ-CFW 00077573
•.Facility Name:
DuPont Company - Fayetteville Works NPDES M NC 0003573
'
' Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge
point. On an attached sheet please provide justification for this estimate (system volume, average cycles per
' blowdown, holding lagoon size, etc.)
Volume- 0.16 million gallons
' What is the pH of the handling system prior to biocide addtion? If unknown, enter N/A. 6-9
' What is the decay rate (D.K.) of the product? N unknown, assume no decay (D.K.=0) and proceed to asterisk.
The degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the half
' life (Half Life is the time required for the initial product to degrade to half of its original concentration). Please
provide copies of the sources of this data.
' H.L. = Unknown Days
' The decay rate is equal to H1L X 0.69 = 0 --Decay Rate (D.K.)
Calculate degradation factor (D.F.). This is the first order loss coefficient.
' D.F. = AS-= . D.D.)- + (D.K.) (12.2 ) + ( 0 ) = 76
(Volume) ( 0.16 )
' Calculate Steady State Discharge Concentration: ////
Dischg Conc. (D.R.) = ( 3 /• T ) = 0, 00 ( mg/I
' (D.F.)(Volume)(3785) ( 76 ) ( 0.16 ) (3 78 5 )
Calculate concentration of biocide instream during low flow conditions.
(Receiving Stream Concentration)
(Discho. Conc.) x (IWC%) (0. 04107 ) x ( 2. 3 ) ' MOO l �; �I 100 = 100 = `
Receiving Stream Concentration
I
In.
Calculate regulated limitation.
List all LC50 data available for the whole product according to the following columns. (Note that units should be
in mg/1). Please provide copies of the sources of this data.
Organism
_ f ._ AeA MNftO&I
�G/PAMI-A to►tw—
D.E.M. Form 101 (7/92) 2
VA
CrN- RAL FILES
DEQ-CFW 00077574
Facility Name: DuPont Company - Fayetteville Works NPDES M NC 0003573
Choose the lowest LC50 fisted above:
Enter the LC50: 6.3
•If the half life (H.L.) is less than 4 days, perform the following calculation.
Regulated Limitation = 0.05 x LC50 = mg/l
If the half life (H.L.) is greater than 4 days or unknown, perform the following calculation.
Regulated Limitation = 0.01 x LC50 = 0. OG 3 mgA
Choose the appropriate regulated Imitation from the calculations immediately above and place in this blank:
0 dw/'3 mg/liter
From Part ii enter the receiving stream concentration:
0.0000 o mg/liter
IV. Analysis.
N the receiving stream concentration is greater than the calculated regulated Imitation, then this biocide is
unacceptable for use.
We
Person in Responsible Charge
� t ,
JUL 30 1996
D.E.M. Form 101 (7)92) 3 CENTRAL FILES
DEQ-CFW 00077575
BET4 LABORATORIES, INC.
4636 SOMERTON ROAD, TREVOSE, PA 19053
PRODUCT: COR-TROL 778-P
August 19, 1994
AQUATIC TOXICOLOGY
Rainbow Trout 96 Hour Static acute Bioassay
LC50: 6.3 mg/L
No Effect Level: 3.7
Fathead Minnow 96 Hour Static Renewal Bioassay
LC50: 8-:2 mg/L -
No Effect Level: 3.1
Daphnia magna 48 Hour Static Renewal Bioassay
LC50: 8.7 mg/L
No Effect Level: 4.9
BIODEGRADATION
COD (mg/gm): 47 Calculated
TOC (mg/gm): 16 Calculated
BOD-5 (mg/gm): 27 Calculated
BOD-28 (mg/gm): 27 Calculated
Closed Bottle Test
$ Degradation in 28 days: 83 Calculated
Zahn-Wellens Test
$ Degradation in 28 days: 65 Calculated
MAMMALIAN TOXICOLOGY
Oral LD50 RAT: >5,000 MG/KG
• Note - ESTIMATED VALUE
Dermal LD50 RABBIT: >5,000 MG/KG
Note - ESTIMATED VALUE
DEQ-CFW 00077576
' Facility Name: DuPont Comvanv - Faygttevjlie Works NPDES #: NC nnn357't
BIOCIDE/CHEMICAL TREATMENT
WORKSHEET-FORM 101
' The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of
North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet is to be
returned with all appropriate data entered into the designated areas with calculations performed as indicated.
I. Facility Name DuPont Company - Fayetteville Works
' NPDES # NC 0003573
County Bladen
' Receiving Stream Cave Fear River 7010 1a1 (cfs)
(Ail above information supplied by the Division of Environmental Management)
' What is the Average Daily Discharge (A.D.D.) volume of the water handing systems to the receiving water body?
' A.D.D. = 12.2 (in M.G.D.)
Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered
' above.
IWC = (A.D.D.) X 100 _ (12.2) X 100 _ 2.3 _coo
(7Q10)(0.646) - (791 )(0.646) + (A.D.D.)
This value (IWC) represents the waste concentration to the receiving stream during low flow conditions.
II. What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part i?
18Ere B o-To1 29P
Please list the active ingredients and percent composition:
_%
-----%
What feed or dosage rate (D.R.) is used in this application? The units must be converted to grams of whole
' product used per day.
D.R.= 2242 grams/day
L
D.E.M. Form 101 (7/92) 1
CENTRAL FILE.
DEQ-CFW 00077577
Facility Name: DuPont Company -Fayetteville. Works NPDES #: NC 0003573
' Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge
point. On an attached sheet please provide justification for this estimate (system volume, average cycles per
' blowdown, holding lagoon size, etc.)
Volume= 0.16 million gallons
' What is the pH of the handling system prior to biocide addition? If unknown, enter N/A. 6-9
' What is the decay rate (D.K.) of the product? N unknown, assume no decay (D.K.=0) and proceed to asterisk.
The degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the half
' life (Half Ufe is the time required for the initial product to degrade to half of its original concentration). Please
provide copies of the sources of this data.
' H.L. = Unknown Days
The decay rate is equal to 1 X 0.69 = 0 —.Decay Rate (D.K.)
' H.L.
Calculate degradation factor (D.F.). This is the first order loss coefficient.
' D.F. = AS--D.D.) + (D.K.) _ (12.2 ) + ( 0 ) 76
(Volume) ( 0.16 ) _
I
C
Calculate Steady State Discharge Concentration: 0. CO."(D.R.) ( Q , ) _ mg/I
Dischg Cont. _ (D.F.)(Volume)(3785) ' ( 76 ) ( 0.16 ) (3 7 8 5 )
Calculate concentration of biocide instream during low flow conditions.
(Receiving Stream Concentration)
(Discho. Conc.) x (IWC%) _ (� t 00x ( 2.3 ) = d' �� l mg/l
100
Receiving Stream Concentration
Calculate regulated limitation.
List all LC50 data available for the whole product according to the following columns. (Note that units should be
in mg/1). Please provide copies of the sources of this data.
pp y�sm
11Q+k� 7;;- -
.�D Kt � .twkst
D.E.M. Form 101 (7/92) 2
Test Duration LC50 (M-A
9 - Ah _ 2,
DEQ-CFW 00077578
' DuPont Company - Fayetteville Works NPDES M NC 0003573
Facility Name:
J
Choose the lowest LC50 listed above:
Enter the LC50: 0. *'r
' •lf the half life (H.L.) is less than 4 days, perform the following calculation.
Regulated Limitation - 0.05 x LC50 mgA
If the half life (H.L.) is greater than 4 days or unknown, perform the following calculation.
' Regulated Limitation - 0.01 x LC50 - 0, 004- �mg/I
' Choose the appropriate regulated limitation from the rdculations immediately above and place in this blank:
mg/liter
tFrom Part II enter the receiving stream concentration:
mg/liter
IV. Analysis.
' If the receiving stream concentration is greater than the calculated regulated Imitation, then this biocide is
unacceptable for use.
' Date
Person in Responsible Charge
' Y
D.E.M. Form 101 (7/92)
DEQ-CFW 00077579
•BETZ. LABORATORIES, INC.
4636 SOMERTON ROAD, TREVOSE, PA 19053
PRODUCT: BIO-TROL 88P
AQUATIC TOXICOLOGY
Rainbow Trout 96 Hour Static Acute Bioassay
LC50: .87 mg/L
Fathead Minnow 96 Hour Static Acute Bioassay
LC50: 2..19 mg/L
Daphnia magna 48 Hour Static Acute Bioassay.
LC50: .45 mg/L
Sheepshead Minnow 96 Hour Static Acute Bioassay
LC50: 19.5 mg/L
BIODEGRADATION
NO DATA AVAILABLE
MAMMALIAN TOXICOLOGY
August 19, 1994
Oral LD50 RAT: 578 MG/KG
Note - 600 MG/KG PER ALT. SOURCE; DEHALOGENATED BYPRODUCT
RAT ORAL LD50: >4,000 MG/KG
Dermal LD50 RABBIT: >2,000 MG/KG
. Note - ALTERNATE SOURCE CONCURS
Inhalation LC50 RAT: 1.88 MG/L/4HR
Note - >_3.2 MG/L/4HR AT 100 PPM (NO DEATHS) PER ALTERNATE
SOURCE
Skin Irritation Score RABBIT: 6.1
Note - 6.98 PER ALTERNATE SOURCE: REVERSIBLE;
DEHALOGENATED BYPRODUCT SCORE: 0.8
Eye Irritation Score RABBIT: 103
' Note - 14 DAY-IRREVERSIBLE-MAX.AT DAY 3; DEHALOGENATED
BYPRODUCT SCORE: 12.8-REVERSIBLE
90 Day Feed Study RAT: NO DATA .
' Note - DEHALOGENATED BYPRODUCT 90-DAY ORAL LD50 >2,000
Dui �0 106
FILES
DEQ-CFW 00077580
Facility Name: DuPont Company - Fayetteville Works NPDES #: NC nnn-As73
BIOCIDE/CHEMICAL TREATMENT
WORKSHEET-FORM 101
The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of
North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet is to be
returned with all appropriate data entered into the designated areas with calculations performed as indicated.
1. Facility Name DuPont Company - Fayetteville Works
NPDES # NC 0003573
County Bladen
Receiving Stream Cape Fear River 7010 71 (cfS)
(All above information supplied by the Division of Environmental Management)
What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water body?
A.D.D. - 12.2 (in M.G.D.)
Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered
above.
IWC - (A.D.D.) X 100 _ (12.2 ) X 100 = 2.3 %
(7Q10)(0.646) - (791 )(0.646) + (A.D.D.)
This value (IWC) represents the waste concentration to the receiving stream during low flow conditions.
il. What is the name of the whole
Please list the active
chemical treatment proposed for use in the discharge identified in Part 1?
Fel- s�
and percent composition:
What feed or dosage rate (D.R.) is used in this application? The units must be converted to grams of whole
product used per day.
D.R.= lo% 7 grams/day
JUL 30 1996
D.E.M. Form 101 (7/92) 1 'CENTRAL FILES
DEQ-CFW 00077581
'Facility Name: DuPont Company - Fayetthville Works NPDES #: NC 0003573
' Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge
point. On an attached sheet please provide justification for this estimate (system volume, average cycles per
' biowdown, holding lagoon size, etc.)
Volume- 0.16 million gallons
' What is the pH of the handling system prior to biocide addition? If unknown, enter WA. 6-9
' What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.-0) and proceed to asterisk.
The degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the half
' life (Half Life is the time required for the initial product to degrade to half of its original concentration). Please
provide copes of the sources of this data.
H.L. = Unknown Days
' The decay rate is equal to H L. X 0.69 = 0 -.Decay Rate (D.K.)
Calculate degradation factor (D.F.). This is the first order loss coefficient.
' D.F. = AS ( ) D.D.) + D.K. (12.2 ) + ( 0 ) = 76
D (Volume) ( 0.16 )
Calculate Steady State Discharge Concentration:
Dischg Conc. _ (D.RJ = ( (q• 7 ) = D, Oct/ mg/I
' (D.F.)(Volume)(3785) ( 76 ) ( 0.16 ) (3 7 8 5 )
Calculate concentration of biocide instream during low flow conditions.
' (Receiving Stream Concentration)
(Discho. Conc.) x (IWC%) _ ( 0.00/ir ) x ( 2.3 QOGl�,3.r mg/I
' 100 100
Receiving Stream Concentration
In. Calculate regulated limitation.
List all LC50 data available for the whole product according to the following columns. (Note that units should be
in mg/1). Please provide copies of the sources of this data.
' purism Test Duration LC50 (M-A
�ADftK/lilt. MQ�tNQ
> �Dloo
P
P
D.E.M. Form 101 (7/92) 2
JJL 30 1996
rEIVT1RAL FILES
11
DEQ-CFW 00077582
Facility Name: DuPont Company - Fayatteville Works NPDES M NC 0003573
Choose the lowest LC50 fisted above:
Enter the LC50: i 2000
•f1 the half fife (H.L.) is less than 4 days, perform the following calculation.
Regulated Umitation = 0.05 x LC50 mg/I
lf the half Ife (H.L.) is greater than 4 days or unknown, perform the following calculation.
Regulated Umitation = 0.01 x LC50 = i 2 O M9A
Choose the appropriate regulated Imitation from the calculations immediately above and place in this blank:
> 20 mg/liter
From Part it enter the receiving stream concentration:
D, 000435 mg/liter
IV. Analysis.
If the receiving stream concentration is greater than the calculated regulated Imitation, then this biocide is
unacceptable for use.
14;4444 / � �NSv A.,.
s-3G-9s-
Date
Person in Responsible Charge
D.E.M. Form 101 (7/92)
CENTRAL FILES
DEQ-CFW 00077583
'BETZ` LABORATORIES, INC.
4636 SOMERTON ROAD, TREVOSE, PA 19053
PRODUCT: BALANCED POLYMER 54401
AQUATIC TOXICOLOGY August 19• 1994
Daphnia magna 48 Hour Static Screen
PH of test solutions were adjusted to a level of 6-9.
0% Mortality: 2000 mg/L
Fathead Minnow 96 Hour Static Screen with 48-Hour Renewal
PH of.test solutions were adjusted to a level of 6-9.
04 Mortality: 2000 ma/L
BIODEGRADATION
COD (mg/gm): 93 calculated
TOC(mg/gm): 28 Calculated
BOD-5, (mg/gm) : 0 Calculated
BOD-28 (mg/gm): 0 Calculated
Closed Bottle Test
% Degradation in 28 days:
Zahn-Wellens Test
$ Degradation in 28 days:
ALIAN TOXICOLOGY
Oral LD50 RAT: >5,000 MG/KG
Note - ESTIMATED VALUE
Dermal LD50 RABBIT: >5,000 MG/KG
• Note - ESTIMATED VALUE
2 Calculated
0 Calculated
DEQ-CFW 00077584
' Facility Name: DuPont Company - Fayetteville Wbrks NPDES #: NC 13001s73
' BIOCIDE/CHEMICAL TREATMENT
WORKSHEET-FORM 101
' The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of
North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet is to be
' returned with all appropriate data entered into the designated areas with calculations performed as indicated.
Facility Name DuPont CoID any - Fayetteville Workc
NPDES # NC 0003573
County Bladen
' Receiving Stream Cave Fear River 7010 791 (CfS)
(All above information suppled by the Division of Environmental Management)
' What is the Average Daily Discharge (A.D.D.) volume of the water handing systems to the receiving water body?
' A.D.D. = 12.2 (in M.G.D.)
Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered
' above.
IWC s (A.D.D.) X 100 _ (12.2 ) X 100 = 2.3 96
(7Q10)(0.646) - (791 )(0.646) + (A.D.D.)
This value (IWC) represents the waste concentration to the receiving stream during low flow conditions.
n
11
C
Ci
r
What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I?
$E 72- OPrl - MI15EV
Please fist the active ingredients and percent composition: pp, r%rr .
_t&�;_°�
It°/
°
What feed or dosage rate (D.R.) is used in this application? The units must be converted to grams of whole
product used per day.
D.R.= 1. grams/day
P,
JUL 30 1996
D.E.M. Form 101 (7/92) 1
CENTRAL FILES
DEQ-CFW 00077585
Facility Name: DuPont Company - Fayettetrille Works NPDES M NC 0002 7
' Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge
point. On an attached sheet please provide justification for this estimate (system volume, average cycles per
' blowdown, holding lagoon size, etc.)
Volume- 0.16 million gallons
' What is the pH of the handling system prior to biocide addition? If unknown, enter WA. 6-9
' What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.-0) and proceed to asterisk.
The degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the halt
' life (Half Ufe is the time required for the initial product to degrade to halt of its original concentration). Please
provide copies of the sources of this data.
' H.L. = Unknown Days
' The decay rate is equal to H1L X 0.69 = 0 —.Decay Rate (D.K.)
Calculate degradation factor (D.F.). This is the first order loss coefficient.
I
in.
r
C
D.F. _ (V�e + (D.K.) _ ( (12.2 ) + ( 0 ) 76
0.16 ) _
Calculate Steady State Discharge Concentration:
Dischg Conc. _ (D.R.) ( /? -� ) mg/I
(D.F.)(Volume)(3785) _ ( 76 ) ( 0.16 ) (3 7 8 5 )
Calculate concentration of biocide instream during low flow conditions.
(Receiving Stream Concentration)
(Discha. Conc.) x (iWC%) _ (0,0494 ) x ( 7 -1 ) = 0, 00000 °% mg/I
100 100
Receiving Stream Concentration
Calculate regulated limitation.
List all LC50 data available for the whole product according to the following columns. (Note that units should be
in mg/1). Please provide copies of the sources of this data.
D.E.M. Form 101 (7/92) 2
Test Duration LC50 (M)
*F-#9 >s4�
*¢ At > /00
DEQ-CFW 00077586
'Facility Name:
DuPont Company - Fayetteville Works NPDES M NC 0003573
J
Choose the lowest LC50 listed above:
' Enter the LC50: �'Jr40 1xS�L-
-11 the half life (H.L.) is less than 4 days, perform the following calculation.
Regulated Limitation - 0.05 x LC50 - mgA
1
If the half We (H.L.) is greater than 4 days or unknown, perform the following calculation.
' Regulated Limitation - 0.01 x LC50 - i a. 5 mg/l
' Choose the appropriate regulated imitation from the calculations immediately above and place in this blank:
> 4. 5 mg/liter
1
' From Part II enter the receiving stream concentration:
67, 005W9_mg/liter
IV. Analysis.
' 0 the receiving stream concentration is greater than the calculated regulated limitation, then this biocide is
unacceptable for use.
0�4
' We
Person in Responsible Charge
p
y
JUL 3C t996
I N-'RAL FILES
CE
D.E.M. Form 101 (7/92) 3 =
rk --
DEQ-CFW 00077587
BETZ LABORATORIES, INC.
4636 SOMERTON ROAD, TREVOSE, PA 19053
' PRODUCT: OPTI-MEEN SERIES PROPOSED
AQUATIC TOXICOLOGY
' Daphnia magna 48 Hour Static
Screen
' 0% Mortality: 50 mg/L
Rainbow Trout 48 Hour Static Screen
' 100% Mortality: 500 mg/L
0$ Mortality: 100
' BIODEGRADATION
COD (mg/9m): 733 Calculated
' TOC (mg/gm) : 287 Calculated
HOD-5 (mg/gm): 2 Calculated
BOD-28 (mg/gm): 187 Calculated
' Closed Bottle Test
$ Degradation in 28 days: 37 Calculated
Zahn-Wellens Test
' $ Degradation in 28 days: 47 Calculated
MAMMALIAN TOXICOLOGY
August 19, 1994
Oral LD50 RAT: 675 MG/KG
Note - ESTIMATED VALUE
Dermal LD50 RABBIT: 890 MG/KG
Note - ESTIMATED VALUE
' Eye'Irritation Score RABBIT: CORROSIVE
Note - 15% CYCLOHEXyyAMINE SCORE:
CONSTANT IRRITATION, NO V-'B101, +/-RINSING,
' Skin Irritation Score RABBIT:•6.3IBLE
Note - EPA CATEGORY I: CORROSIVE;
60 MINUTES BUT NOT 3 SIVE; DOT HM181 CORROSIVE IN
DEQ-CFW 00077588
' Facility Name: DuPont Company - Fayetteville W6rka_ NPDES #: NC nnn3,57't
' BIOCIDE/CHEMICAL TREATMENT
WORKSHEET-FORM 101
' The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of
North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet is to be
' returned with all appropriate data entered into the designated areas with calculations performed as indicated.
I. Facility Name DuPont Company - Fayettevi l i p Wnrkre
' NPDES # NC 0003573
County Bladen -
Receiving Stream Cape Fear River 7010 291 (Cfs)
(All above information supplied by the Division of Environmental Management)
' What is the Average Daily Discharge (A.D.D.) volume of the water handing systems to the receiving water body?
' A.D.D. = 12.2 (in M.G.D.)
Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered
' above.
IWC = (A.D.D.) X 100 _ (12 2) X 100 = 2.3 6�'
' (7Q10)(0.646) — (791 )(0.646) + (A.D.D.)
This value (IWC) represents the waste concentration to the receiving stream during low flow conditions.
II. What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I?
' $E'T.& 214WO
Please list the active ingredients and percent composition: ,,,,,�,
E
E
L
11
U
U
to °/
0
WA i iLffIt
What feed or dosage rate (D.R.) is used in this application? The units must be converted to grams of whole
product used per day.
D.R.= grams/day-''
_Mj,j -3x
1996
D.E.M. Form 101 (7/92) 1
DEQ-CFW 00077589
• DuPont Company - Fayetteville? Works NPDES M NC 0003573
1 Facility Name: P Y Y
' Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge
point. On an attached sheet please provide justification for this estimate (system volume, average cycles per
' blowdown, holding lagoon size, etc.)
Volume- 0.16 million gallons
What is the pH of the handling system prior to biocide addition? If unknown, enter WA. 6-9
' What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.-O) and proceed to asterisk.
The degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the half
' Me (Half Life is the time required for the initial product to degrade to half of its original concentration). Please
provide copies of the sources of this data.
' H.L. = Unknown Days
The decay rate is equal to H1L X 0.69 = 0 =Decay Rate (D.K.)
Calculate degradation factor (D.F.). This is the first order loss coefficient.
' A( D•D.) (12.2 )
D.F. _ (Volume) + (D.K.) _ ( 0.16 ) + ( 0 ) _. 76
Calculate Steady State Discharge Concentration:
(D.R.) ( IG33 ) O, d3S mgA
' Drschg Conc. ' (D. F.) (Volume) (3785) _ ( 76 ) ( 0.16 ) (3 7 8 5) _
Calculate concentration of biocide instream during low flow conditions.
' (Receiving Stream Concentration)
(Discho. Conc.) x (IWCOM (a•a35) x ( 2.3 ) G a008/ mgl/I
' 100 = 100 =
Receiving Stream Concentration
I
In.
Calculate regulated limitation.
List all LC50 data available for the whole product according to the following columns. (Note that units should be
in mg/1). Please provide copies of the sources of this data.
LL Organis
m Test Duration
'�O TAX%CO�K�1Cr►I GG��/ �'/� ToV'
_ �tiS D�17�a1�a�aT . // ���.1'Std ioc di�Cll/sfi��
.� �e7� 7t!�liw;u� I'teD/'CS�,•�r�vG�
Ro /19LtA7i`G ibX g ZV M L �G4144
LC50 (MA
�RAL FILES
D.E.M. Form 101 (7/92) 2 C��
DEQ-CFW 00077590
Facility Name:
DuPont Company - Fayetteville Works NPDES #: NC 0003573
'
Choose the lowest LC50 listed above:
' Enter the LC50: >►/L-
-ff the had life (H.L.) is less than 4 days, perform the following calculation.
' Regulated Limitation = 0.05 x LC50 = mg/I
If the had Me (H.L.) is greater than 4 days or unknown, perform the following calculation.
' Regulated Limitation = 0.01 x LC50 i 0 O/ mg/l
' Choose the appropriate regulated Imitation from the calculations immediately above and place in this blank:
1> mg/Iter
1
' From Part II enter the receiving stream concentration:
0. GO8 / mg/liter
IV. Analysis.
' d the receiving stream concentration is greater than the calculated regulated Imitation, then this biocide is
unacceptable for use.
Signalise Date
Person in Responsible Charge
JUL 30 1996
��NTRA1.'-F1LES
D.E.M. Form 101 (7/92) 3
DEQ-CFW 00077591
rl BET; LABORATORIES, INC.
4636 SOMERTON ROAD, TREVOSE, PA 19053
' PRODUCT: CONTINUUM 29000 SERIES PROPOSED
i
AQUATIC TOXICOLOGY
NO DATA AVAILABLE
1
IBIODEGRADATION
' COD (mg/gm): 212 Calculated
TOC (mg/gm): 81 Calculated
BOD-5 (mg/gm): 3 Calculated
' BOD-28 (mg/gm): 13 Calculated
Closed Bottle Test
% Degradation in 28 days: 0 Calculated
' Zahn-Wellens Test
$ Degradation in 28 days: 6 Calculated
' MAMMALIAN TOXICOLOGY
Oral LD50 RAT: 4,800 MG/KG
' Note - ESTIMATED VALUE
Dermal LD50 RABBIT: )5,000 MG/KG
Note - ESTIMATED VALUE
t
i
1
August 19, 1994
ra.z
v
JUL
CENTRN �a
C.'
DEQ-CFW 00077592
NPDES PERMIT NO. NC0003573
ADDENDUM TO D.E.M. FORM 101
Estimation of total volume of the water handling system between entry of biocidal product
'
and NPDES discharge point:
'
Basis: Discharge from BCH Energy Project enters the DuPont non -contact wastewater
conveyance ditch and flows to Outfall 002.
'
1
1
Conveyance Ditch Volume = 5 ft x 2 ft x 2200 ft = 22,000 ft3 =
165,000 gallons
1
1
1
1
1
'
JUL SO 1996
CENTRAL FILES
DEQ-CFW 00077593
r
STANDARD FORM C - MANUFACTURING AND COMMERCIAL
SECTION III. WASTE ABATEMENT REQUIREMENTS & IMPLEMENTATION (CONSTRUCTION) SCHEDULE
This section requires information on any uncompleted implementation schedule which may have been imposed for construction of waste treatment facilities.
Such requirements and implementation schedules may have been established by local. State, or Federal agenoes or by court action. In addition to leting
the following items, a copy of an official implementation schedule should be attached to this apprcation. IF YOU ARE SUBJECT TO SEVERAL DIFFERENT
IMPLEMEAND/OR STAGED CONSTRUCTION TATION SCHEDULES, ITHER OF SEPARATE OPERATIONAL UNITS (ITEMOF DIFFERENT LEVELS c), SUBM TrA SEPARNG ATE EIFFERENT SECTIONS FORE EACH CHEDULES ONE. TEM 1a)
Sdhed I+ia
1. Improvements
a Discharge Serial Numbers 300 N/A
Affected List the discharge
serial numbers, assigned in
Section II, that are covered by
this implementation schedule
b. Authority Imposing Require- 301a
ment Check the appropriate
item indicating the authority
for the implementation schedule
If the identical implementation
schedule has been ordered by
more than one authority, check
the appropriate items. (see
instructions)
Locally developed plan 301b ❑ LOC
Areawide Plan ❑ARE
Basin Plan ❑ BAS
State approved implementation ❑ SQS
schedule
Federal approved water quality ❑ WQS
standards implementation plan
Federal enforcement procedure ❑ ENF
or action
State court order ❑ CRT
Federal court order ❑ FED
c. Facility Requirement Specify
the 3character code of those
listed below that best describes
in general terms the require-
ment of the implementation
schedule and the applicable sbc-
character abatement oodes(s) .
from Table II of the instruction
booklet If more than one
schedule applies to the facility
because of a staged constructor
schedule, state the stage of oon-
struction being described here
with the appropriate general
action code. Submit a separate
Section III for each stage of
construction planned.
301c
301d
3-character
(general)
6-character
specific)
see Table II)
New Facility
NEW
'
Modification (no increase in capacity or treatment)
MOD
Increase in Capacity
INC
Increase in Treatment Level
I NT
Both Increase in Treatment Level and Capacity
ICT
'
Process Change
PRO
Elimination of Discharge
ELI
�1�fYr -
L �1,?
30 1996
CENTRAL FILES
DEQ-CFW 00077594
■ 2 Implementation Schedule and 3. Actual Completion
Dates
Provide dates imposed by schedule and any actual dates of oompledon
for implementation steps listed below.
Indicate dates as accurately as possible. (see instructions)
' Implementation Steps 2. Schedule
(yr/Mo/Day)
3. Actual Completion (Yr/Mo/Day)
a Preliminary plan complete
302a
1. J
303a
b. Final plan submission
302b
_/_J_
303b
'
c. Final plan complete
302c
303c
d Financing complete & oontract
302d
303d
_J_J
awarded
'
e. Site acquired
302e
303e—J
f. Begin construction
302f
_(_J
303f
g. End construction
302g
303g
'
h Begin discharge
302h
303h
_1_J
i. Operational level attained
302
_!�
303i
JUL 30 1996
s
CENTRAL FILES
DEQ-CFW 00077595
N. C. DEPARTMENT OF NATURAL RESOURCES & COMMUNITY DEVELOPMENT
ENVIRONMENTAL MANAGEMENT COMMISSION
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM
APPLICATION FOR PERMIT TO DISCHARGE
ADDITIONAL REQUIRED INFORMATION
APPLICATION NUMBER
DISCHARGE SERIAL NUMBER
REFER TO DIRECTIONS ON REVERSE SIDE BEFORE ATTEMPTING TO COMPLETE THIS FORM
Parameter
(Code)
(501)
UntreatedIn-Plant
Intake
Water
(Daily
average)
Treated
Intake
Water
(Daily
avers
ai y
Average
Minimum
Value
Maximum
Value
Frequency
of Analysis
Number
of
Analyses
5arpple
Type
REMARKS:
I certify that I am familiar with the information contained in this report and that to t e
best of my knowledge and belief such information is true, complete and accurate.
ate corm Comoieted Name ot AUMOrizedn i a re
JUL 1996
CENTRAL FILES
DEQ-CFW 00077596
6 (
Direcdons - For each parameter listed, complete the information
requested in each column in the units specified according to the instructions
given below.
Column 1- Enter the daily average value of the intake water at the
point it enters the facility. If intake water if from more than one source, and
enters the facility at separate entry points, the value given in column 1 should
be weighted proportional to the quantity of flow oontnbuted from each source.
If water is treated before use, completion of this column is not required (see
instructions for column 2). Values of intake are not required for mining
activities.
Column 2- If all or part of intake water is treated before use,
provide values for total intake here instead on in Column 1, Also describe
briefly in item 26 'additional information,' the type of treatment performed on
intake water (e.g., rapid sand filtration, coagulation, flocculation, ion
exchange, etc.) and the percent of intake water contributing to this discharge
that has been treated.
Column 3 - Supply daily average value for the days when
discharge is actually operating or is expected to be operating (a new
discharge). Daily average values are to be computed by weighing the daily
value in proportion to the daily flow. If a discharge occurs irregularly, the
value supplied in the column marked 'Daily Average' should represent an
average for the average for the days the discharge actually occurs. Average
values are not to be supplied for pH, specific conductance, and
bacteriological parameters (e.g., coliform bacteria).
Columns 4 and 5 - Supply minimum and maximum value
observed (or expected for new discharge) over any one day when the
discharge is operating.
Column 6 - Specify the average frequency of analysis for each
parameter as number analyses per number of days (e.g., '317' is equivalent
to three analyses performed every 7 days). If continuous, enter'CONT.'
When analyses are conducted on more than one individual grab sample
collected during the same day, the analysis frequency should reflect one
analysis whose value is the average of the individual grab sample
measurements. Average frequency should be based on an operating month.
Column 7- Specify the number of analyses performed at the
average frequency specified in column 6, up to 365.
Column 8 - Specify sam le type as follows:
G For grab sample (individual sample collected in less than 15
minutes).
#C - For composite sample # is to be replaced by the average
number of hours over which the composite sample was collected.
Composite samples are combinations of individual samples
obtained at intervals over a time period, either the volume of
each individual sample is directly proportional to discharge flow
rates or the sampling interval (for constant volume samples) is
inversely proportional to the flow rates over the time period
used to produce the composite.
' NA If 'CONT' was entered in column 6.
Analytical methods - Appendix A contains all parameters with
their reporting levels, test descriptions, and references. The parameter
values can be determined either by use of the standard analytical methods as
described in table A or by methods previously approved by the EPA Regional
' Administrator or Director of a federally approved State program (or their
authorized representative) who has jurisdiction over the State in which the
discharge occurs. If the test used is not one shown in table A, the test
procedure should be referenced in 'Remarks' or on a separate sheet. If
values are determined to be less than the detectable limits (as determined by
referenced standard analytical techniques and/or instrument manufacturers
literature), specify 'LT(Value of detectable limit)' in the appropriate space.
For example, if the detectable limit is .005 mq4 and quantities of less than
this are determined, speciy 'LT.005.' Do not enter descriptors such as
'NIL,' 'TRACE,' 'NEG,' etc. for this purpose. If it is your reasoned
judgment that one or more of the required parameters is not present in the
initial untreated or treated process water and/or the discharge, enter an 'A'
(meaning 'absent') in the appropriate space.
In order for values reported to be representative, it is
recommended that they be based on from at least five to seven analyses of
' composite samples(if applicable). Each of the composite samples should be
obtained by compositing frequent samples in proportion to flow over an
operating day. Samples should be taken during period of maximum
production, if possible. If samples are taken at periods of less than
maximum production, state in 'Remarks' the percent of maximum
' production that was obtained during the sampling period.
I --
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JUL 30 1996
CENTRAL FILES
L
DEQ-CFW 00077597
UNITED STATES DUART QUADRANGLE STATE OF NORTH CAROLINA
NORTH CAROLINA DEPARTMENT OF NATURAL REWUR
DEPARTMENT OF THE INTERIOR 7.5 MINUTE SERIES (TOPOGRAPHIC) AND COMMUNITY DEVELOPMENT
N
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CENTRAL, tr)Vl��
DEQ-CFW 00077599
AVERAGE FLOWS IN TN0.ISAIOS OF GALLONS PER OAY.
SOME FLOWS ARE ESTN4ITEO TO GIVE INTAKE ANO
DISCWAIE TOTALS.
SCHEMATIC WATER FLOW
E.I. DU PONT DE NEMOURS & CO.
FAYETTEVILLE WORKS
PAGE 1 OF 2
STORM WATER
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DEQ-CFW 00077600
]o 810-TFFnr7ENT
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SCHEMATIC WATER FLOW
PROCESS USES
E.I. DU PONT DE NEMOURS & CO.
FAYETTEVILLE WORKS
PAGE 2 OF 2
767
�a
JUL 30 1996
CENTRAL FILES '•f
DEQ-CFW 00077601
DUPONT - FAYETTEVH LE WORKS
' NCD0003573
Sludge Management Plan
The DuPont - Fayetteville Works operates a Class 3 Wastewater Treatment Plant which is
' comprised of a single -stage activated sludge biological system.
Excess sludge is removed from the system by diverting part of the Recycled Activated Sludge
' (at approximately 0.6% solids) from the clarifiers to a Dissolved Air Floatation (DAF) unit for
initial thickening.
' The sludge from the DAF (at approximately 3% solids) is transferred to a Mix Tank where
polymer agents are added to enhance the dewatering process.
' The semi -thickened sludge is transferred from the Mix Tank to a Rotary Filter for final
thickening, whereby the sludge is thickened to 6% solids.
' The thickened sludge is then transferred to a Screw Press where it is dewatered to a
concentration of 9-20% solids.
' Following the Screw Press, the sludge is dried in steam heated dryers to a concentration of
40-55% solids.
On the average, the weekly quantity of generated dried sludge is 13,000 lb.
' The dried, non -hazardous sludge is transported off -site to a commercial Subtitle D landfill.
This sludge is currently being disposed of at the Sampson County Landfill near Roseboro, NC.
1
JUL 30 1996
' CEMTPAL FILES
DEQ-CFW 00077602