DEQ-CFW_00087314

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HFPO Manufacturing Process
Emission Summary
A. VOC Compound Summary
Air Emissions Inventory
Emission Summary
Page 1 of 2
Nafion®
CAS Chemical Name
CAS No.
Point Source and Non -point
Accidental
Total
.Compound
Source Emissions (Ibs)
Emissions
Emissions (Ibs
COF2
Carbonyl Fluoride
353-50-4
1,855
1,855.36
PAF
Trifluoroacetyl Fluoride
354-34-7
1,795
1,795.18
A/F Solvent (TFF)
Perluoro-3,5,7,9,1I- entaoxadodecano I fluoride
690-43
486
486.26
A/F Solvent (TAF)
Trifluorometh I ester of carbonofluoridic acid
3299-24-9
486
486.26
HFP
Hexafluoro ro I ene
116-15-4
42,016
5
42,020.55
HFPO
Hexafluoro ro I ene Epoxide
428-59-1
41,509
952
42,461.18
Benzene
Benzene
71-43-2
1
1.24
Toluene
Meth lbenzene
108-88-3
10,356
10,356.00
Total VOC Emissions (Ibs)
99,462
Total VOC Emissions (tons)
49.73
VOCs Generated
VOCs Emitted from Stack
Point Source
Equipment Emissions Inside
Total VOC
Point Source
Non -point Source
Total VOC
Generated Ibs
Buildings Ibs
Generated
Emissions Ibs
Emissions (Ibs)
Emitted Ibs
859,423
3,420
862,843
59,576
2,183
61,759
862,843 Ib VOC generated
61,759 Ib VOC emitted
801,084 Ib VOC removed in control device
C. Toxic Air Polluntant Summary
Nafion® Point Source
Com ound CAS Chemical Name CAS No.
Ib:
HF Hydrogen Fluoride 7664-39-3 1,200
Benzene Benzene 71-43-2
Toluene Meth lbenzene 108-88-3
801,084 Ib VOC removed in control device
862,843 Ib VOC generated
92.84% VOC control efficiency
Ion -point Source
Emissions (Ibs)
153.64
1.24
10.356.00
Accidental
Emissions
Total
Emissions Ibs
1,354.19
1.24
10,356.00
HO

HFPO Manufacturing Process
D. HF Control Efficiency
Air Emissions Inventory
1,201 lb HF emitted from Point Sources
(100%-99.6%) Stack Efficiency
300,135 lb HF sent to control device from Point Sources
300,135 lb HF sent to control device from Point Sources
1,354 lb HF emitted
= 298,781 lb HF removed in control device
300,135 lb HF sent to control device from Point Sources
+ 154 lb HF from Non -point Sources inside buildings
300,289 lb HF generated
298,781 lb HF removed in control device
300,289 lb HF generated
99.50% HF control efficiency
Emission Summary
Page 2 of 2
Total Emissions (tons) 55.59