DEQ-CFW_00076450

11r__
ANNUAL POLLUTANT ANALYSIS MONITORING REQUIREMENT
Report Form A
I. Facility Information:
Page 1 of 6
NPDES Permit No: Discharge (Pipe) No: Year:
Facility Name: Class: County:
Person(s) Collecting Samples:
Analytical Laboratory: Industrial and Environmental Analysts, Inc.
GC/MS Library Size (number of chemicals catalogued): 42,224 OWA
43,002 Extrel
II. Sampling:
24 hr composite for main sample/grab sample for purgeable fraction
Date Sampled: (composite sample)
Sampling begun (date, time):
Sampling finished (date, time) : 5a$ (2l (SvS
Date and time sampled (grab sample):
1
DEQ-CFW 00076450

f
EffiueatAcuatic T02dcity Report Form/Chronic Pass/Fall and LC50
Date
• 1C l u Po N r NPDES#NC D o0 3 S73 Pipe # CmmtY DEN
• oratory Perfo Test--ARFLif0A E*11,MWJ#fEnrr�t— CommCIItS
Signature, of Operator/Lab Supervisor
North GaTelina Ceriodaphnia Chronic Pass/Fall Re�rod +coon Bioassay5��
Orca, ism#
• - �`'•'' 1 2 .S 4 5 6 ?' 8 9 10 11 12. ,..
QbIgnic
,2o Calculated t " a'
# Young Produced 1 i a v !3 l6 a a 19 I6 t 7 l6 �� 19 %M ortali Avg.Repro .
Adult (L)ive (D )ead (. L L L t- L L L
L L Control: - Control
�anism# ��J� ' g• qy
y •-^ent 2 prpanism Reproduction-- ��eat 2 Treatment 2
Muent% • 3% 1 2 3 4 5 6 7 8 9 10 11 12 % control
�6� PASS FAIL
# Young Produced t8 16 t �� !q t �� 9 �l III 101V rdd
Adult (L)ive (D )cad L I— L L L L L L L t°-0 Check One
2nd sample uor Ft _her Test Test Start Date
1st sample 1st sample complete This /s�►/9�
Control 7.7. B is 'j-9 g•l i ...
pg SampleI S/1z/9a Sample2 S/3y/Qo
f 43 1•i9 0,1 .0 g.9 - �
Treatment 2 7• Q c.,..,..1.7�,•oe/Duration
s e t e Grab oTfi . Duratio •-3 �o
t n a n •� x
r d i d r d Sample 1 ti/ ='`f C7 =
t t t C O8
1st sample 1st sample 2nd sample Sample 2 V
n n
Control 8 $ 9 14 q •17 $•3 q'3 Hardness(mg/1) !f7
D.O. 6 a!]
�. • r Spec.Cond.4=hos) 47 12l.S Ali
Treatment 2 >� `I g•
Chlorine(mgM o./Q e•/
Sample temp. at receipt 3 SG 3.A C
_ • �_y t _ l• ,• y s
•
LC50•_______%
95g6 Confidence Limits Moving Average ElProbit ❑
Spearman Harber ❑ Other-
-94'--------- `l4
Mail original to:
ATr: Environmental Sciences Branch
Div.of Environmental Management
N.C. Department of EHNR
P.O. Box 27687 / organism Tested
Raleigh, N.C. 27611
DEM form AT-1 (3/87) rev.9/89
Note: Please
Concentration Complete This
Section Also
Mortality start/end
k
ol.
PH D.O.
DEQ-CFW 00076451

ort Form/Chronic Pass/Fail and LC50 Date
Effluent A
Performing Test
. n,, a
Lure of Operator
NPDES#NC --Pipe # Q=V LA m ber-land
Comments TmT9 rea_-4ucl-tcn_7Co�r�rol
--
n�t�lO-OS-b209—OI TEA sa,nple,
control Organism Reproduce on Qr anism;f
1 2 3 4 5 6 7 8 9 10 11 12.
# Young Produced s as a3132
Adult (L)ive (D )ead L' L
'IYPatment 2 Organism Reproduction Organism#
Effluent% , 3 1 2 3 4 5 6 7 8 9 10 11 .12
R
# Young Produced
ea bent 2
% control
organisms p
producing
K brood
Adult (L)ive (D )ead I I I `` L L U L—I � I I
L 10 L-114 LI HL LLQ2—
Ist sample 1st sample 2nd sample Complete This For Either Test Test
Control 7 �� Collection (Star Dalt
pH Sample 1 Q PW 0 Sample 2
Treatment 2 �� .� �' •� Sample Twe/Duration
ss e t
t e
a d r d r d
r t t Sample 1
t
1st sample 1st sample 2nd sample ample 2
O
c
0
u
Control SLI 8 S g 4 Hardness(mg/1) ' 5
D.O. _
o / �S g• ��� g Spec.Cond.(µmhos) /
Treatment 2 O �D r 5 •
'K
Chlorine(mg/1) ;��� ,,fi,,,
1 Sample temp. at receipt
Comp.
Duration
M
qv,*'
a4 hr.
N hr•
Treatment 2
ASS,/FAIL
Check One
Note: Please
concentration Complete This
Section Also
Mortality
start/end start/end
Method of Determination Control
FL C 5 0=----------%
95% Confidence Limits Moving Average ❑ Probit ❑ High
° % Spearman Karber [] Other--------- Conc.
/o- DO
Mail original to:
ATT: Environmental Sciences Branch
Div.of Environmental Management
N.C. Department of EHNR
P.O. Box 27687
Raleigh, N.C. 27611
DEM form AT-1 (3/87) rev.9/89
LQ5 �ar„tr, Toxicity Test
rw w,...a.,v&— e.,T,rnecE. rl ac %,_ combininLr replicates)
To
%
%
%
%
%
%
°
PH
Organism Tested ceri'AmAnla a 61 a
DEQ-CFW 00076452

ATTACHMENT 3
PRIORITY POLLUTANT RESULTS
DEQ-CFW 00076453

r
Industrial & Environmental Analysts, Inc.--
P.O.sox ii s
l Rosearon LrOM1 Park. Nord, cammv 2770i — - •
November 28, 1990
James Wallwork
$.i. duPont de Neumors, Inc.
Polymer Products Dopartment
P.O. Drawer Z
Fayetteville, NC 28302
Referewc TEA Report No.s 951004, 951004(S)
Dear Mr. Wallwork,
Transmitted herewith are the result# gf awlyApn nn nne namplo oubed.ttod
to our laboratory.
Please note that thallium results will follow in a separate report.
Please see the enclosed reports for your results.
Very truly yours,
TIMUSfiY "L4 a ENVIRONMENTAL ANALYSTS, INC.
Lin F, i[itcheli
Director, Technical support Services
State certification:
AXabama - 440210 Now aersey - #67719 south Carolina - #99021
Geo:"qJ& - #811i Tonn000ee - #00296 forth uaroiina - #37720
Kansas - #E-158 Virginia - #00179 #84
DEQ-CFW 00076454

1EA LABORATORY RESULTS
TEA Project #: 951-004 (�
Client Name: E.I. duPont de Neumcre, Inc.
Irate
sample Client ID Parameter Results Analyzed
TOTAL METALS:
7 wautewatee 001 Aluminum 0.26 mg/L 11/17/90
1 Wastewater 001 Antimony <0.20 mg/L 11/25/50
1 Wastewater 001 Arsenic <0.005 mg/L 11/15/90
1 Wastewater 001 Beryllium <0.01 mg/L 11/25/90
1 Wastewater 001 Cadmium <0.01 mg/L 11/25/90
1 Wastewater 001 Chromium <0.03 mg/L 11/25/90
1 Wastewater 001 Copper <0.02 mg/L 11/26/90
1 wastewater 001 Iron 0.24 mg/L 11/17/90
1 Wastewater 001 Mercury <0.0005 mg/L 11/18/90
1 Wastewater 001 Nickel <0.03 mg/L 11/25/90
1 Wastewater 001 Selenium <0.005 mg/L 11/16/90
1 Wastewater 001 silver co.0r &%L 11/db/yU
1 Wastewater 001 Zinc 0.10 mg/L 11/17/90
1 Wastewater 001 Molybdenum -U.0 mg/L 12/18/90
1 Wastewater 001 Ammonia-N 0.7 mg/L 11/19/90
1 Wastewater 001 Chloride 18 mg/L 11/14/90
1 Wastewater 001 Cyanide <0.01 mg/L 11/21/90
1 Wastewater 001 Color 20 units 21/16/90
1 Wastewater 001 Fecal Coliform 43 Col/100ml 11/14/90
1 Wastewater 001 MSAS 0.04 mg/L 11/15/90
1 Wastewater 001 Total Phenols 006 UVIL 11/18/55
1 nawLewarer uui Sulfate 810 mg/L 11/20/90
1 Wastewater 001 Oil & Grease 19 mg/L 11/26/90
LI-Q, �J �SZ (L
vi
1
C� I
Z �t q of ��� 0
' j t" c
DEQ-CFW 00076455

ACROLIIN / AMU%W2TR.TTZ
EPA 603 COMPOMM LIST
CC
IRA sample Number: 951-004.1
Sample Identification: stavater 001
Date Analysed: 11/1 Sys Averili
Quantitation I Results
Limit concentration
Number Compound (ug/L) (ug/L)
1 Acrolein 5.0 SQL
Z Acrylonitrile 3.0 ]SQL
00mme1%to s
BQL m Below Quantitation Limit
FORM 603-OC Rev. 111990
DEQ-CFW 00076456

IEA LASOMTORY RESMT5
'.L'!E!, i-ro 3 ect : 9 51-004 (S )
Client Name: E.I_ duPont de Neumors, Inc.
Date
saM:Ple # Client ID Parameter Results Analyzed
1 Wastewater 001 Fluoride
1 Wastewater 001 Nitrite/Nitrate
130 mg/L 11/20/90
4.0 mg/L 11/16/90
DEQ-CFW 00076457

Industrial & Environmental Analysts, Inc.
♦ • Y.V. box 1Ztf4tl
Research Triangle Park, North
November 2, 1990
James Waliwork
E.I. dupont de Neumors Inc.
Polymer Products Department
P.O. Drawer Z
Fayetteville, NC 28302
Reference IBA Report No.: 951003, 951003(S)
Dear Mr. Wallwork,
Transmitted herewith are the results of analyses on one sample submitted
to our laboratory.
Please see the enclosed reports for your results.
Very truly yours,
INDUSTRIAL & ENVIRONMENTAL ANALYSTS, INC.
Li da F. itchell
Director, Technical Support Services
State Certification:
Alabama - #40210 New Jersey - #67719 South Carolina - #99021
Georgia - #816 Tennessee - #00296 North Carolina - #37720
Kansas - 0-158 Virginia - #00179 #84
DEQ-CFW 00076458

Ab
IEA Project #:
Client Name:
IEA LABORATORY RESULTS
951-003
E.I. dupont de Neumors Inc.
Date
parameter Results Analyzed
Sample � Client ID ----------- --------- _ _____ _--
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
1 Effluent
002
TOTAL METALS:
0.76
mg/L
10/31/90
Aluminum
Antimony
<0.20
mg/L
10/29/90
Arsenic
<0.005
mg/L
10/23/90
Beryllium
<0.01
mg/L
10/29/90
Cadmium
<0.01
mg/L
10/29/90
Chromium
<0.03
mg/L
10/29/90
Copper
<0.02
mg/L
10/29/90
Iron
0.68
mg/L
10/31/90
Molybdenum
<1.0
mg/L
10/29/90
Mercury
<0.0005
mg/L
10/26/90
Nickel
<0.03
mg/L
10/29/90
Selenium
<0.01
mg/L
10/18/90
Silver
<0.05
mg/L
10/29/90
Thallium
<0.005
mg/L
10/22/90
Zinc
0.03
mg/L
10/31/90
Chloride
30
mg/L
10/19/90
Cyanide
<0.01
mg/L
10/23/90
Color
40
units
10/18/90
Fecal Coliform
270
Col/100ml
10/12/90
Fluoride
8.4
mg/L
10/22/90
MBAS
<0.03
mg/L
10/12/90
Total phenols
<0.005
mg/L
10/26/90
Sulfate
79
mg/L
10/24/90
Oil & Grease
<5.0
mg/L
10/31/90
PH
7.27
10/12/90
Temperature
27.8
C
10/12/90
DEQ-CFW 00076459

•
IEA LABORATORY RESULTS
IEA Project #: 951-003(S)
Client Name: E.I. duPont de Neumors Inc.
Date
Sample # Client ID Parameter - ------ Results - - Analyzed
1 Effluent 002 Nitrite
1 Effluent 002 Nitrate
<0.05 mg/L 10/16/90
2.0 mg/L 10/16/90
DEQ-CFW 00076460

r 0
iwe;ii
ACROLEIN / ACRYLONITRILE
EPA 603 COMPOUND LIST
IEA Sample Number: 951-003-1
Sample Identification: Effluent 002
Date Analyzed: 10/23/90 By: Cox
Number Compound
1 Acrolein
2 Acrylonitrile
Quantitation
Limit
(ug/L)
5.0
5.0
Comments:
BQL = Below Quantitation Limit
FORM 603 Rev. 071390
Results
Concentration
(ug/L)
BQL
BQL
1
DEQ-CFW 00076461

GC/MS PURGEABLES
SW-846 METHOD 8240
IEA Sample Number:
Sample Identification:
Date Analyzed:
Number Compound
951-003-1
Effluent 002
10/25/90 By: Stephenson
Quantitation Results
Limit Concentration
(ug/L) (ug/L)
1
Acetone
100
BQL
2
Benzene
5
5
BQL
BQL
3
Bromodichloromethane
4
Bromoform
5
BQL
5
Bromomethane
10
BQL
6
2-Butanone
100
BQL
7
Carbon disulfide
5
BQL
8
Carbon tetrachloride
5
BQL
9
Chlorobenzene
5
BQL
10
Dibromochloromethane
5
BQL
11
Chloroethane
10
BQL
12
2-Chloroethylvinyl ether
10
BQL
13
Chloroform
5
BQL
14
Chloromethane
10
BQL
15
1,1-Dichloroethane
5
BQL
16
1,2-Dichloroethane
5
BQL
17
1,1-Dichloroethene
5
BQL
18
1,2-Dichloroethene (total)
5
BQL
19
1,2-Dichloropropane
5
BQL
20
cis-1,3-Dichloropropene
5
BQL
21
trans-1,3-Dichloropropane
5
BQL
22
Ethylbenzene
5
BQL
23
2-Hexanone
50
BQL
24
Methylene chloride
5
BQL
25
4-Methyl-2-pentanone
50
BQL
26
Styrene
5
BQL
27
1,1,2,2-Tetrachloroethane
5
BQL
28
Tetrachloroethene
5
BQL
29
Toluene
5
BQL
30
1,1,1-Trichloroethane
5
BQL
31
1,1,2-Trichloroethane
5
BQL
32
Trichloroethene
5
BQL
33
Vinyl acetate
50
BQL
34
Vinyl chloride
10
BQL
35
Xylenes (total)
5
BQL
Comments:
BQL = Below Quantitation Limit
DEQ-CFW 00076462

•db
BASE/NEUTRAL/ACID EXTRACTABLES
SW-846 METHOD 8270
IEA Sample Number: 951-003-1
Sample Identification: Effluent 002
Date Extracted: 10/18/90
Date Analyzed: 10/25/90 By: Mace
Quantitation
IResults
Limit
Concentration
Number
Compound
(ug/L)
(ug/L)
1
Acenaphthene
10
BQL
2
Acenaphthylene
10
BQL
3
Anthracene
10
BQL
4
Benzoic acid
50
BQL
5
Benzo(a)anthracene
10
BQL
6
Benzo(b)fluoranthene
10
BQL
7
Benzo(k)fluoranthene
10
BQL
8
Benzo(g,h,i)perylene
10
BQL
9
Benzo(a)pyrene
10
BQL
10
Benzyl alcohol
20
BQL
11
bis(2-Chloroethoxy)methane
10
BQL
12
bis(2-Chloroethyl)ether
10
BQL
13
bis(2-Chloroisopropyl)ether
10
BQL
14
bis(2-Ethylhexyl)phthalate
10
BQL
15
4-Bromophenyl phenyl ether
10
BQL
16
Benzyl butyl phthalate
10
BQL
17
4-Chloroaniline .
20
BQL
18
2-Chloronaphthalene
10
BQL
19
4-Chloro-3-methylphenol
20
BQL
20
2-Chlorophenol
10
BQL
21
4-Chlorophenyl phenyl ether
10
BQL
22
Chrysene
10
BQL
23
Dibenzo(a,h)anthracene
10
BQL
24
Dibenzofuran
10
BQL
25
Di-n-butylphthalate
10
BQL
26
1,3-Dichlorobenzene
10
BQL
27
1,4-Dichlorobenzene
10
BQL
28
1,2-Dichlorobenzene
10
BQL
29
3,31-Dichlorobenzidine
20
BQL
30
2,4-Dichlorophenol
10
BQL
31
Diethyl phthalate
10
BQL
32
2,4-Dimethylphenol
10
BQL
33
Dimethyl phthalate
10
BQL
34
4,6-Dinitro-2-methylphenol
50
BQL
35
2,4-Dinitrophenol
50
BQL
36
2,4-Dinitrotoluene
10
BQL
37
2,6-Dinitrotoluene
10
BQL
38
Di-n-octylphthalate
10
BQL
39
Fluoranthene
10
BQL
FORM 8270 (1) Rev. 050589
DEQ-CFW 00076463

BASE/NEUTRAL/ACID E%TRACTABLES
SW-846 METHOD 8270
SEA Sample Number: 951-003-1
Sample Identification: Effluent 002
Date Extracted: 10/18/90
Date Analyzed: 10/25/90
Number Compound
40
Fluorene
41
Hexachlorobenzene
42
Hexachlorobutadiene
43
Hexachlorocyclopentadiene
44
Hexachloroethane
45
Indeno(1,2,3-cd)pyrene
46
Isophorone
47
2-Methylnaphthalene
48
2-Methylphenol (o-cresol)
49
4-Methylphenol (p-cresol)
50
Naphthalene
51
2-Nitroaniline
52
3-Nitroaniline
53
4-Nitroaniline
54
Nitrobenzene
55
2-Nitrophenol
56
4-Nitrophenol
57
N-Nitroso-di-n-propylamine
58
N-Nitrosodiphenylamine
59
Pentachlorophenol
60
Phenanthrene
61
Phenol
62
Pyrene
63
1,2,4-Trichlorobenzene
64
2,4,5-Trichlorophenol
65
2,4,6-Trichlorophenol
Azobenzene
Comments:
BQL = Below Quantitation Limit
FORM 8270 (2)
Rev. 050589
By: Mace
Quantitation
Limit
(ug/L)
10
10
10
10
10
10
10
10
10
10
10
50
50
50
10
10
50
10
10
50
10
10
10
10
10
10
10
Results
Concentration
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
DEQ-CFW 00076464

PESTICIDES / PCBs
SW-846 METHOD 8080
IEA Sample Number: 951-003-1
Sample Identification: Effluent 002
Date Extracted: 10/18/90
Date Analyzed: 10/25/90 By: Travis
Quantitatidn
Results
Limit
Concentration
Number
Compound
(ug/L)
(ug/L)
1
alpha-BHC
0.05
BQL
2
beta-BHC
0.05
BQL
3
delta-BHC
0.05
BQL
4
gamma-BHC (Lindane)
0.05
BQL
5
Heptachlor
0.05
BQL
6
Aldrin
0.05
BQL
7
Heptachlor epoxide
0.05
BQL
8
Endosulfan I
0.05
BQL
9
Dieldrin
0.10
BQL
10
4,4'-DDE
0.10
BQL
11
Endrin
0.10
BQL
12
Endosulfan II
0.10
BQL
13
4,4'-DDD
0.10
BQL
14
Endosulfan sulfate
0.10
BQL
15
4,4'-DDT
0.10
BQL
16
Toxaphene
1.0
BQL
17
Aroclor 1016
0.50
BQL
i8
Aroclor 1221
0.50
BQL
19
Arocior 1232
0.50.
BQL
20
Aroclor 1242
0.50
BQL
21
Aroclor 1248
0.50
BQL
22
Aroclor 1254
1.0
BQL
23
Aroclor 1260
1.0
BQL
24
Chlordane (technical)
0.50
BQL
25
Endrin aldehyde
0.10
BQL
Additional Compounds:
26 Endrin ketone 0.10 BQL
- 27 alpha -Chlordane 0.50 BQL
28 gamma -Chlordane 0.50 BQL
Comments:
BQL = Below Quantitation Limit
FORM 8080 Rev. 092690
DEQ-CFW 00076465