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HomeMy WebLinkAboutDEQ-CFW_00086069• • • Vinyl Ethers North Air Emissions Inventory 2008 AIR EMISSIONS INVENTORY SUPPORTING DOCUMENTATION Emission Source ID No: NS-B Emission Source Description: VE-North PSEPVE Manufacturing Process PSEPVE Process Emissions Page 1 of 18 Process & Emission Description: The VE-North PSEPVE manufacturing process is a continuous chemical reaction. All emissions from the process are vented through the Nafion Division Waste Gas Scrubber (Control Device ID No. NCD-Hdr) which has a documented control efficiency of 99.6% for all acid fluoride compounds. Some emitted compounds are assumed to pass completely through the scrubber, so the control efficiency for those compounds is assumed to be 0%. The control of emissions of specific compounds will be addressed and detailed in the following pages. The PSEPVE process in VE-North emits compounds in the acid fluoride family. In the presence of water (such as in atmospheric moisture), these acid fluorides can eventually hydrolyze to hydrogen fluoride. For the purpose of this emissions inventory, a conservative approach will be taken and the acid fluorides will be reported both as a VOC and as the equivalent quantity of hydrogen fluoride. Basis and Assumptions: - The PSEPVE process flowsheet is the basis for relative concentrations of before -control emissions of gaseous wastes. - Calculations of point source emissions are based on actual vent flow totals taken from the IP21 Historian. - All emission determination calculations are available on the EXCEL spreadsheet found at S:/Everyone/martinas/Emissions/20081VEN Air Emissions 2008.xls. DEQ-CFW 00086069 • • • Vinyl Ethers North Point Source Emission Determination A. HFP Hexafluoropropylene Air Emissions Inventory HF Potential: HFP is a VOC without the potential to form HF Quantity Released HFP is a byproduct present in the HFPO feed. It is an inert in VE-North that is vented to the WGS. HFP vented er the process flowsheet PSEPVE Process Emissions Page 2 of 18 CAS No.116-15-4 P 0.15kgHFP Vented from the Condensation Reactor: 3.66kQCond?xVendF7oii Vented from the Crude Receiver Vented from the Foreshots Receiver HFP vented based on HFP vented based on HFP vented based on HFP vented from Condensation Reactor: 0.15 kg HFP x 3.66 kg CndRx HFP vented from Crude Receiver 3.12 kg HFP x 18.76 kg CrRec HFP vented from Foreshots Receiver 0.00 kg HFP x 0.33 kg FsRec VOC Emissions 3.12 kg HFP 18.76 kg Crude Receiver Vent 0 kg HFP 0.33 kg Foreshotaeceiver Vent 866 kg total Condensation Reactor vent stream (22266FG). 27,329 kg total Crude Receiver vent stream (22701FG). 21 kg total Foreshots Receiver vent stream (22826FG). 866 kg CndRx = 34 kg HFP 27,329 kg CrRec = 4,542 kg HFP 21 kg FsRec = 0 kg HFP 34 kg from Condensation Reactor 4,542 kg from Crude Receiver 0 kg from Foreshots Receiver 4,576 kg HFP = 4,576 kg VOC 10,067 lb VOC DEQ-CFW 00086070 • Vinyl Ethers North B. BFPO Hexafluoropropylene oxide Air Emissions Inventory HF Potential: HFPO is a VOC without the potential to form HF Quanta Released HFPO unreacted in condensation is vented to the WGS. HFPO vented per the process flowsheet Vented from the Condensation Reactor: Vented from the Crude Receiver Vented from the Foreshots Receiver HFPO vented based on HFPO vented based on HFPO vented based on BFPO vented from Condensation Reactor: 3.28 kg HFPO x 3.66 kg CndRx HFPO vented from Crude Receiver 0.00 kg HFPO x 18.76 kg CrRec HFPO vented from Foreshots Receiver 0.00 kg HFPO x 0.33 kg FsRec VOC Emissions PSEPVE Process Emissions Page 3 of 18 CAS No. 428-59-1 3.28 kg HFPO 3.66 kg Cond Rx Vent Flow 0 kg HFPO 18.76 kg Crude Receiver Vent 0 kg HFPO 0.33 kg Foresh otsRe ceiver Ven 866 kg total Condensation Reactor vent stream (22266FG). 27,329 kg total Crude Receiver vent stream (22701FG). 21 kg total Foreshots Receiver vent stream (22826FG). 866 kg CndRx = 776 kg HFPO 27,329 kg CrRec = 0 kg HFPO 21 kg FsRec = 0 kg BFPO 776 kg from Condensation Reactor 0 kg from Crude Receiver 0 kg from Foreshots Receiver 776 kg HFPO — 776 kg VOC 1,706 lb VOC DEQ-CFW 00086071 Vinyl Ethers North Air Emissions Inventory PSEPVE Process Emissions Page 4 of 18 C. PPF Perfluoropropionyl fluoride HF Potential: Ea CAS No. 422-61-7 ch mole of PPF (MW = 166) can generate 1 mole of HF (MW = 20). FkgPPF-1molePPF20gHF 1moleHF = 0.120kg HF 166g PPF 1 moleHF 1 molePPF Therefore, each 1 kg of PPF generates Quantity Released Before -control PPF vented per the process flowsheet Vented from the Condensation Reactor: Vented from the Crude Receiver Vented from the Foreshots Receiver 0.120 kg of HF 0.20 kg PPF 3.66 kg Cond Rx Vent Flow 0 kg PPF 18.76 kg Crude Receiver Vent 0 kg PPF 0.33 kg ForeshobReceiver Vent PPF vented based on 866 kg total Condensation Reactor vent stream (22266FG). PPF vented based on 27,329 kg total Crude Receiver vent stream (22701FG). PPF vented based on 21 kg total Foreshots Receiver vent stream (22826FG). Before control PPF vented from Condensation Reactor: 0.20 kg PPF x 866 kg CndRx = 48 kg PPF 3.66 kg CndRx PPF vented from Crude Receiver 0.00 kg PPF x 27,329 kg CrRec = 0 kg PPF 18.76 kg CrRec PPF vented from Foreshots Receiver 0.00 kg PPF x 21 kg FsRec = 0 kg PPF 0.33 kg FsRec Total before -control PPF vented = 48 kg PPF After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS): VOC Emissions 48 kg PPF Waste Gas Scrubber x (100%-99.6%) Control Efficiency = 0.19 kg PAF = 0.19 kg VOC 0.43 Ib. VOC HF Equivalent Emissions 0 kg PPF x 0.120 kg HF/kg PPF = 0.02 kg HF 0.05 Ib. HF • DEQ-CFW 00086072 • • Vinyl Ethers North Air Emissions Inventory PSEPVE Process Emissions Page 5 of 18 D. TFE Tetrafluoroethylene HF Potential: TFE is a VOC without the potential to form HF Quanta Released TFE is a byproduct that can be formed in the ABR system. It is an inert in VE-North that is vented to the WGS. TFE vented per the process flowsheet CAS No.116-14-3 0 kg TFE Vented from the Condensation Reactor: 3.66 kg Cond Rx Vent Flow 0.01 kg TEE Vented from the Crude Receiver 18.76 kg Crude Receiver Vent 0 kg TFE Vented from the Foreshots Receiver 0.33 kg ForeshotSReceiver Ven TFE vented based on 866 kg total Condensation Reactor vent stream (22266FG). TFE vented based on 27,329 kg total Crude Receiver vent stream (22701FG). TFE vented based on 21 kg total Foreshots Receiver vent stream (22826FG). TFE vented from Condensation Reactor: 0.00 x 866 kg CndRx = 0 kg TFE 3.66 kg TFE kg CndRx TFE vented from Crude Receiver 0.01 x 27,329 kg CrRec = 13 kg TFE 18.76 kg TFE kg CrRec TFE vented from Foreshots Receiver 0.00 x 21 kg FsRec — 0 kg TFE 0.33 kg TFE kg FsRec VOC Emissions 0 kg from Condensation Reactor + 13 kg from Crude Receiver + 0 kg from Foreshots Receiver 13 kg TFE = 13 kg VOC 29 Ib VOC DEQ-CFW 00086073 • Vinyl Ethers North Air Emissions Inventory PSEPVE Process Emissions Page 6 of 18 E. PSEPVE CAS No.1623-5-8 Perflaoro-2-(2-Fluorosulfonylethoxy) Propyl Vinyl Ether HF Potential: PSEPVE is a VOC without the potential to form HF Quantity Released PSEPVE vented per the process flowsheet 0 kg PSEPVE Vented from the Condensation Reactor: 3.66 kg Cond Rx Vent Flow 0 kg PSEP VE Vented from the Crude Receiver 18.76 kg Crude Re ceiver Vent 0.07 kg PSEPVE Vented from the Foreshots Receiver 0.33 kg ForeshotsReceiveYVen PSEPVE vented based on 866 kg total Condensation Reactor vent stream (22266FG). PSEPVE vented based on 27,329 kg total Crude Receiver vent stream (22701FG). PSEPVE vented based on 21 kg total Foreshots Receiver vent stream (22826FG). PSEPVE vented from Condensation Reactor: 0.00 x 866 kg CndRx = 0 kg PSEPVE 3.66 kg PSEPVE kg CndRx PSEPVE vented from Crude Receiver 0.00 x 27,329 kg CrRec = 0 kg PSEPVE 18.76 kg PSEPVE kg CrRec PSEPVE vented from Foreshots Receiver 0.07 x 21 kg FsRec = 4.38 kg PSEPVE 0.33 kg PSEPVE kg FsRec VOC Emissions 0 kg from Condensation Reactor + 0 kg from Crude Receiver + 4.38 kg from Foreshots Receiver 4.38 kg PSEPVE = 4.38 kg VOC 9.64 lb VOC DEQ-CFW 00086074 • • Vinyl Ethers North Air Emissions Inventory PSEPVE Process Emissions Page 7 of 18 F. C4 Perfluoro-2-butene HF Potential: Cos are VOCs without the potential to form SF Quantity Released C4s are perfluorobutenes that are byproducts from the Agitated Bed Reactor system. They are inerts in VE-North that is vented to the WGS. C4s vented per the process flowsheet CAS No. 360-89-4 0kgC4 Vented from the Condensation Reactor: 3.66 kg Cond Rx Vent Flow 0.46 kg C4 Vented from the Crude Receiver 18.76 kg Crude Re ceiver Vent 0.10kgC4 Vented from the Foreshots Receiver 0.33 kg EoreshotSReceiver Ven C4s vented based on 866 kg total Condensation Reactor vent stream (22266FG). C4s vented based on 27,329 kg total Crude Receiver vent stream (22701FG). C4s vented based on 21 kg total Foreshots Receiver vent stream (22826FG). C4s vented from Condensation Reactor: 0.00 x 866 kg CndRx = 0 kg C4s 3.66 kg C4s kg CndRx C4s vented from Crude Receiver 0.46 x 27,329 kg CrRec = 669 kg C4s 18.76 kg C4s kg CrRec C4s vented from Foreshots Receiver 0.10 x 21 kg FsRec = 6 kg C4s 0.33 kg C4s kg FsRec VOC Emissions 0 kg from Condensation Reactor + 669 kg from Crude Receiver + 6 kg from Foreshots Receiver 675 kg C4s = 675 kg VOC 1,485 lb VOC DEQ-CFW 00086075 Vinyl Ethers North Air Emissions Inventory PSEPVE Process Emissions Page 8 of 18 G. HFPO Trimer Perfluoro-2,5-Dimethyl-3,6-Dioxanonanoyl HF Potential: Each mole of HFPO Trimer (MW = 498) can generate 1 mole of HF (MW = 20). k MA• 1 moleTrimer 20g HF 1 moleHF _ 0.0402kgHl g 498g Trimer 1 moleHF 1 moleTrimer Therefore, each 1 kg of HFPO Trimer generates 0.040 kg of HF Quantity Released HFPO Trimer is a byproduct formed in the Condensation Reactor system. HFPO Trimer vented per the process flowsheet 0 kg HFPO Trimer Vented from the Condensation Reactor: 3.66 kg Cond Rx Vent Flow 0 kg HFPOTrimer Vented from the Crude Receiver: 18.76 kg Crude Receiver Vent 0.01 kg HFPO Trimer Vented from the Foreshots Receiver: 0.33 kg ForeshotsReceiverVen CAS No. 2641-34-1 HFPO Trimer vented based on 866 kg total Condensation Reactor vent stream (22266FG). HFPO Trimer vented based on 27,329 kg total Crude Receiver vent stream (22701FG). HFPO Trimer vented based on 21 kg total Foreshots Receiver vent stream (22826FG). Before control BFPO Trimer vented from Condensation Reactor: 0.00 x 866 kg CndRx — 0 kg BFPO Trimer 3.66 _kg BFPO Trimer kg CndRx HFPO Trimer vented from Crude Receiver 0.00 x 27,329 kg CrRec = 0 kg HFPO Trimer 18.76 kg HFPO Trimer kg CrRec HFPO Trimer vented from Foreshots Receiver 0.01 x 21 kg FsRec = 0.88 kg BFPO Trimer 0.33 kg HFPO Trimer kg FsRec Total before -control BFPO Trimer vented 0.88 kg VOC After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS): VOC Emissions 0.88 kg HFPO Trimer Waste Gas Scrubber x (100%-99.6%) Control Efficiency = 0.0035 kg HFPO Trimer = 0.0035 kg VOC = 0.008 Ib. VOC HF Equivalent Emissions 0.0035 kg HFPO Trimer x 0.040 kg HF/kg HFPO Trimer 0.00014 kg HF 0.00031 Ib. HF DEQ-CFW 00086076 Vinyl Ethers North Air Emissions Inventory PSEPVE Process Emissions Page 9 of 18 H. Monoadduct (MA) Tetrafluoro-2-[Tetrafluoro-2-(Fluorosulfonyl)Ethoxy]-Propanoyl Fluoride HF Potential: Ea CAS No. 4089-57-0 ch mole of MA MW = 346 can generate 1 mole of HF MW = 20). 1 moleMA . 20 g HF 1 mole HF 1kgMA•=0.058kgHF 346 g MA 1 moleHF 1 moleMA Therefore, each 1 kg of MA generates Quantity Released Before -control MA vented per the process flowsheet Vented from the Condensation Reactor: Vented from the Crude Receiver Vented from the Foreshots Receiver 0.058 kg of HF 0kgMA 3.66 kg Cond Rx Vent Flow 0 kg MA 18.76 kg Crude Re ceiver Vent 0.0045 kg MA 0.33 kg ForeshotsReceiverVentl MA vented based on 866 kg total Condensation Reactor vent stream (22266FG). MA vented based on 27,329 kg total Crude Receiver vent stream (22701FG). MA vented based on 21 kg total Foreshots Receiver vent stream (22826FG). Before control MA vented from Condensation Reactor: 0.00 kg MA x 866 kg CndRx = 0 kg MA 3.66 kg CndRx MA vented from Crude Receiver 0.00 kg MA x 27,329 kg CrRec = 0 kg MA 18.76 kg CrRec MA vented from Foreshots Receiver 0.0045 kg MA x 21 kg FsRcc = 0.292 kg MA 0.33 kg FsRec Total before -control MA vented = 0.292 kg MA After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS): VOC Emissions 0.292 kg MA Waste Gas Scrubber x (100%-99.6%) Control Efficiency = 0.00117 kg MA = 0.00117 kg VOC = 0.003 Ib. VOC HF Equivalent Emissions 0.00117 kg MA x 0.058 kg HF/kg MA 0.00 kg HF 0.00 lb. HF • DEQ-CFW 00086077 • • Vinyl Ethers North Air Emissions Inventory PSEPVE Process Emissions Page 10 of 18 1. Diadduct (DA) CAS No. 4089-58-1 Tetrafluoro-2[Hexafluoro-2-(Tetrafluoro-2-(Fluorosulfonyl)Ethoxy) Propoxy Propionyl Fluoride HF Potential: i h molp of no (MW = 512) can aenerate 1 mole of HF (MW = 20) 1 mole DA 20 g HF I mole HF 1 kg MA - =0.039kgH] 512gDA ImoleHF lmoleDA Therefore, each 1 kg of DA generates Quantity Released Before -control DA vented per the process flowsheet Vented from the Condensation Reactor: Vented from the Crude Receiver Vented from the Foreshots Receiver 0.039 kg of HF 0kgDA 3.66 kg Cond Rx Vent Flow 0kgDA 18.76 kg Crude Receiver Vent 0.13kgDA 0.33 kg ForeshotsReceiver Vent DA vented based on 866 kg total Condensatron Reactor vent stream (22266FG). DA vented based on 27,329 kg total Crude Receiver vent stream (22701FG). DA vented based on 21 kg total Foreshots Receiver vent stream (22826FG). Before control DA vented from Condensation Reactor: 0.00 kg DA x 866 kg CndRx = 3.66 kg CndRx DA vented from Crude Receiver 0.00 kg DA x 27,329 kg CrRec = 18.76 kg CrRec DA vented from Foreshots Receiver 0.13 kg DA x 21 kg FsRec = 0.33 kg FsRec Total before -control DA vented = After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS): VOC Emissions 8.47 kg DA Waste Gas Scrubber x (100%-99.60/6) Control Efficiency 0.0339 kg DA HF Equivalent Emissions 0.0339 kg DA x 0.039 kg HF/kg DA 0.00132 kg HF = 0 kg DA 0 kg DA 8.47 kg DA 8.47 kg DA 0.034 kg VOC = 0.075 Ib. VOC 0.00 Ib. HF DEQ-CFW 00086078 • • • Vinyl Ethers North Air Emissions Inventory J. Hydro PSEPVE Tetrafluoro-2-[Trifluoro-2-(1,2,2,2-Tetra-fluoroethoxy)-1-(Trifluoromethyl) Ethoxyj- Ethane Sulfonyl Fluoride HF Potential: Hydro-PSEPVE is a VOC without the potential to form BF Quantity Released H '---PSEPVE vented Y er the process flowsheet P 0 kg Hydro — PSEPVE Vented from the Condensation Reactor: 6 k C d Rx V t FZ Vented from the Crude Receiver Vented from the Foreshots Receiver 3.6 g on en ow 0 kg Hydro—PSEPVE 18.76 kg Crude Receiver Vent 0.0045 kg Hydro—PSEPVE 0.33 kg Foreshot.5ReceiverVentl PSEPVE Process Emissions Page 11 of 18 CAS No. 755-02-9 Hydro-PSEPVE vented based on 866 kg total Condensation Reactor vent stream (22266FG). Hydro-PSEPVE vented based on 27,329 kg total Crude Receiver vent stream (22701FG). Hydro-PSEPVE vented based on 21 kg total Foreshots Receiver vent stream (22826FG). Hydro-PSEPVE vented from Condensation Reactor: 0.00 kg Hydro-PSEPVE x 866 kg CndRx = 0 kg Hydro-PSEPVE 3.66 kg CndRx Hydro-PSEPVE vented from Crude Receiver 0.00 kg Hydro-PSEPVE x 18.76 kg CrRec Hydro-PSEPVE vented from Foreshots Receiver _ 0.0045 kg Hydro-PSEPVE x 0.33 kg FsRec VOC Emissions 27,329 kg CrRec = 21 kg FsRec = 0 kg from Condensation Reactor 0 kg from Crude Receiver 0.292 kg from Foreshots Receiver 0.292 kg Hydro-PSEPV = 0 kg Hydro-PSEPVE 0.292 kg Hydro-PSEPVE 0.292 kg VOC 0.643 lb VOC DEQ-CFW 00086079 • • • Vinyl Ethers North Air Emissions Inventory K. Iso-PSEPVE Perfluoro-1-Methyl-2-(2 Fluorosulfonyl Ethoxy) Ethyl Vinyl Ether HF Potential: Iso-PSEPVE is a VOC without the potential to form BF Quantity Released Iso-PSEPVE vented per the process flowsheet PSEPVE Process Emissions Page 12 of 18 CAS No. 34805-58-8 0 kg Iso — PSEPVE Vented from the Condensation Reactor: 3.66 kg Cond Rx Vent Flow 0 kg Iso — PSEPVE Vented from the Crude Receiver 18.76 kg Crude Re ceiver Vent 0.014 kg Iso — PSEPVE Vented from the Foreshots Receiver 0.014 kg Foreshots Re ceiver Vent Iso-PSEPVE vented based on 866 kg total Condensation Reactor vent stream (22266FG). Iso-PSEPVE vented based on 27,329 kg total Crude Receiver vent stream (22701FG). Iso-PSEPVE vented based on 21 kg total Foreshots Receiver vent stream (22826FG). Iso-PSEPVE vented from Condensation Reactor: 0.00 kg Iso-PSEPVE x 866 kg CndRx = 0 kg Iso-PSEPVE 3.66 kg CndRx Iso-PSEPVE vented from Crude Receiver 0.00 kg Iso-PSEPVE x 18.76 kg CrRec Iso-PSEPVE vented from Foreshots Receiver 0.014 k2 Iso-PSEPVE x 0.33 kg FsRec VOC Emissions 27,329 kg CrRec = 21 kg FsRec = 0 kg from Condensation Reactor 0 kg from Crude Receiver 0.877 kg from Foreshots Receiver 0.877 kg Iso-PSEPVE _ 0 kg Iso-PSEPVE 0.877 kg Iso-PSEPVE 0.877 kg VOC 1.928 Ib VOC DEQ-CFW 00086080 Vinyl Ethers North Air Emissions Inventory PSEPVE Process Emissions Page 14 of 18 • 4 M. Suifonyl Fluoride (SOF2) HF Potential: Each mole of SOF2 (MW = 86) can generate 2 mole of HF (MW = 20). CAS No. 7783-42-8 lmoleSOF2 20gHF 2moleHF 1 kgMA•=0.465kgHF 86g SOF2 1 moleHF l moleSOF2 Therefore, each 1 kg of SOF2 generates Quantity Released Before -control SOF2 vented per the process flowsheet Vented from the Condensation Reactor: Vented from the Crude Receiver Vented from the Foreshots Receiver 0.465 kg of HF 0 kg SOF2 3.66 kg Cond Rx Vent Flow 2.04 kg SOF2 18.76 kg Crude Receiver Vent 0 kg SOF2 0.33 kg ForeshotsReceiverVen SOF2 vented based on 866 kg total Condensarion Reactor vent stream (22266FG). SOF2 vented based on 27,329 kg total Crude Receiver vent stream (22701FG). SOF2 vented based on 21 kg total Foreshots Receiver vent stream (22826FG). Before control SOF2 vented from Condensation Reactor: 0.00 kg SOF2 x 866 kg CndRx = 0 kg SOF2 3.66 kg CndRx SOF2 vented from Crude Receiver 2.04 kg SOF2 x 27,329 kg CrRec = 2,973 kg SOF2 18.76 kg CrRec SOF2 vented from Foreshots Receiver 0.00 kg SOF2 x 21 kg FsRec = 0 kg SOF2 0.33 kg FsRec Total before -control SOF2 vented = 2,973 kg SOF2 After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS): SOF2 Emissions 2,973 kg SOF2 Waste Gas Scrubber x (100%-99.6%) Control Efficiency = 12 kg SOF2 26 lb. SOF2 HF Equivalent Emissions 12 kg SOF2 x 0.465 kg HF/kg SOF2 = 5.53 kg HF 12.19 Ib. HF SOF2 is not a VOC (no carbon) DEQ-CFW 00086081 • • Vinyl Ethers North N. Carbon Monoxide (CO) Air Emissions Inventory CO is a criteria pollutant Quantity Released CO are perfluorobutenes that are byproducts from the Agitated Bed Reactor system. They are inerts in VE-North that are vented to the WGS. CO vented per the process flowsheet PSEPVE Process Emissions Page 15 of 18 CAS No. 630-08-0 0kgCO Vented from the Condensation Reactor: 3.66 kg Cond Rx Vent Flow 1.30 kg CO Vented from the Crude Receiver 18.76 kg Crude Receiver Vent 0kgCO Vented from the Foreshots Receiver 0.33 kg Foreshot. Receiver Vent CO vented based on 866 kg total Condensation Reactor vent stream (22266FG). CO vented based on 27,329 kg total Crude Receiver vent stream (22701FG). CO vented based on 21 kg total Foreshots Receiver vent stream (22826FG). CO vented from Condensation Reactor: 0.00 x 866 kg CndRx = 0 kg CO 3.66 kg CO kg CndRx CO vented from Crude Receiver 1.30 x 27,329 kg CrRec = 1,900 kg CO 18.76 kg CO kg CrRec CO vented from Foreshots Receiver 0.00 x 21 kg FsRec = 0 kg CO 0.33 kg CO kg FsRec CO Emissions 0 kg from Condensation Reactor + 1,900 kg from Crude Receiver + 0 kg from Foreshots Receiver = 1,900 kg CO = 4,189 lb CO (not a VOC) DEQ-CFW 00086082 Vinyl Ethers North Air Emissions Inventory PSEPVE Process Emissions Page 16 of 18 0 O. VOC Smmriary LI 0 • Nefion Compound Name Before Control Generated After Control Stack Emissions VOC HF kg/yr Ib/yr Ib/yr Ib/ r A. HFP 4,576 10088 10,088 B. HFPO 776 1710 1,710 C. PPF 48 107 0.43 1 0.05 D. TFE 13 29 29 E. PSEPVE 4 10 10 F. C4 675 1489 1,489 G. HFPO Trimer 0.88 2 0.01 0.00 H. MA 0.29 1 0.003 0.00 L DA 8.47 19 0.07 0.01 J. Hydro PSEPVE 0.29 0.6 0.6 K. Iso PSEPVE 0.88 2 2 L. Diglyme 505 1113 1,113 M. SOF2 (not a VOC) N. CO (not a VOC) Total 6,608 14,568 14,440 0.1 DEQ-CFW 00086083 Vinyl Ethers North Air Emissions Inventory PSEPVE Process Emissions Page 17 of 18 40 P. Total Emission Summary** 40 • ** All Emissions in this table represent "After Control' emissions. Nafion Compound Name Stack Emissions lb/yr Equipment Emissions (N.w1) lb/yr Maintenance Emissions (Now 2) lb/yr Total Emissions lb/yr A. HFP 10,088 23 26 10,138 B. BFPO 1,710 107 6 1,824 C. PPF 0.43 0 0 0 D. TFE 29 0 0 29 E. PSEPVE 10 210 0 219 F. C4 1,488 16 19 1,522 G. HFPO Trimer 0.01 0 0 0 H. MA 0.00 0 5 6 I. DA 0.07 2 12 13 J. Hydro-PSEPVE 0.6 0 0 1 K. Iso-PSEPVE 1.9 0 0 2 L. Diglyme 53 3 1,113 M. SOF2 (not a VOC) 26.2 26 N. CO (not a VOC) 4,189 * TA 0 0 0 * RSU 0 0 0 * BFPO -Diener 0 0 0 Total 13,354 412 73 19,083 Note 1 - See section titled "Equipment Emissions" for details Note 2 - See section titled "Maintenance Emissions" for details N CO not realistically expected through equipment or maintenance emissions L. Diglyme total based on material balance, see section L * Not normally emitted from the process as a routine stack emission DEQ-CFW 00086084 • 17J • Vinyl Ethers North HF Equivalent Emissions Air Emissions Inventory PSEPVE Process Emissions Page 18 of 18 Nafion Compound Name Stack Emissions lb/yr Equipment Emissions lb/yr Maintenance Emissions lb/yr Total Emissions lb/yr C. PPF 0.05 0.00 0.01 0.06 G. BFPO Trimer 0.00 0.00 0.01 0.01 H. MA 0.00 0.02 0.30 0.32 I. DA 0.00 0.06 0.46 0.52 M. SOF2 12.19 12.19 * TA 0.00 0.01 0.01 * RSU 0.00 0.00 0.01 * BFPO -Diener 0.00 1 0.02 0.02 Total 12.25 0.09 1 0.78 13.11 The estimated 11F equivalent emissions were determined by multiplying the total emission quantity of an acid fluoride by the ratio of the molecular weight of HF divided by the molecular weight of the specific acid fluoride. This is based on the fact that one mole of an acid fluoride will generate one mole of HF. For example, if 100 lb. of PPF was emitted: 20 lb/mol BF 166 lb/mol PPF X 100 lb/yr Equipment PPF = 12.0 lb/yr BF DEQ-CFW 00086085