DEQ-CFW_00072517

e
Cou PONT
FAYETTEVILLE WORKS
APPLICATION TO MODIFY
THE TITLE V AIR PERMIT
(PERMIT NO.03735T32)
TO CONSTRUCT
AND OPERATE
THE POLYVINYL FLUORIDE =
MANUFACTURING FACILITY NO.2 y
�l3
APRIL 2, 2008
DEQ-CFW 00072517

Zoning Consistency Determination
Facility Name DuPont Company - Fayetteville Works
Facility Street Address 22828 NC Highway 87 W
Facility City Duart Township, Bladen County, North Carolina
Description of Process Polyvinyl Fluoride Manufacturing Facility No. 2
SIC Code/NAICS 3081 / 326113
Facility Contact Michael E. Johnson
Phone Number [phone]
Mailing Address 22828 NC Highway 87 W
Mailing City, State Zip Fayetteville, NC 28306-7332
Based on the information given above:
Q I have received a copy of the air permit application (draft or final) AND...
Q The proposed operation IS consistent with applicable zoning and subdivision ordinances
Agency Bladen County Planning Department
Name of Designated Official Greg Elkins
Title of Designated Official Planning Director
Signature
Date y-3 - 0 5?
Please forward to the mailing address listed above and the air quality offices listed below:
Attn: Major Source Review Branch Supervisor
NCDENR - Division of Air Quality
Permitting Section
1641 Mail Service Center
Raleigh, NC 27699-1641
Mr. Steven F. Vozzo
NCDENR - Division of Air Quality
Fayetteville Regional Office
225 Green Street - Suite 714
Fayetteville, NC 28301
DEQ-CFW 00072518

FORM Al
FACILITY (General Information)
REVISED 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate Al
El Local Zoning Consistency Determination (if required) 0 Facility Reduction & Recycling Survey Form (Form A4) IM Application Fee
0 Responsible Official/Authorized Contact Signature ❑x Appropriate Number of Copies of Application ❑ P.E. Seal (if required)
Legal Corporate/OwnerName: E.I. du Pont de Nemours & Company
Site Name: DuPont Company - Fayetteville Works
Site Address (911 Address) Line 1: 22828 NC Highway 87 W
Site Address Line 2:
City: Fayetteville
State: North Carolina
Zip Code: 28306-7332
County: Bladen
Permit/Technical Contact.
Facility/Inspection Contact;
Name/Title: Michael E. Johnson, Environmental Manager
Name/Title: (Same as Permit/Technical Contact)
Mailing Address Line 1: 22828 NC Hwy 87 W
Mailing Address Line 1:
Mailing Address Line 2:
Mailing Address Line 2:
City: Fayetteville State: NC Zip Code: 28306
City: State: Zip Code:
Phone No. 910.678.1155
Fax No. 910.678.1247
Phone No. ( )
Fax No. ( )
Email Address: [e-mail]
Email Address:
Responsible Official/Authorized Contact.
Invoice Contact.
Name/Title: Karen B. Wrigley / Plant Manager
Name/Title: (Same as Permit/Technical Contact)
Mailing Address Line 1: 22828 NC Hwy 87 W
Mailing Address Line 1:
Mailing Address Line 2:
Mailing Address Line 2:
City: Fayetteville State: NC Zip Code: 28306
City: State: Zip Code:
Phone No. 910-678-1546
Fax No. 910-678-1247
Phone No. ( )
Fax No. ( )
Email Address: [e-mail]�pont.c(oomA
Email Address:
y N
❑ New (non -permitted) Facility/Greenfield Modification of Facility (permitted) ❑ Renewal With Modification
❑ Renewal (TV Only)
❑ General ❑ Small ❑ Prohibitory Small ❑ Synthetic Minor Title V (Must include Form(s) E)
3���� w � �_� �.�A�.�����>RE�nt- e� IN�a�,GtQ�ky•��:� �� . _� ..:�� s � � r. �: �k
Describe nature of (plant site) operation(s): Chemical manufacturing facility.
Primary SIC/NAILS Code: 3081, 3083, 2821, 2869
Current/Previous Air Permit No. 03735T32
Facility Coordinates: Latitude: 34 deg. 50 min. 30 sec. Longitude: -74 deg. 50 min. 10 sec.
Does this application contain confidential data? ❑ No 0 Yes (See Instructions)
r ° PERSQQ E R>I~tRh�l_THAT PR
---a e 4.
PAI�t�© 1PP YMAK JO ` .; ;� >
:. =�.a a 5+.. ',l
Person Name: Michael E. Johnson
Firm Name:
Mailing Address Line 1: 22828 NC Hwy 87 W
Mailing Address Line 2:
City: Fayetteville
State: NC
Zip Code: 28306-7332
county: Bladen
Phone No. 910-678-1155
Fax No. 910-678-1247
Email Address: [e-mail]
`"' XSIG[4TURE
OF RESPQNS[BLE QFFtCYALI�U
�EfIiZE C9CAC� Y
Name (typed): Karen B. Wrigley Title: Plant Manager
X Signature(Blue Ink): Date: Oq jo /0
Attach Additional Sheets As Necessary
DEQ-CFW 00072519

FORMS; A2, A3
EMISSION SOURCE LISTING FOR THIS APPLICATION - A2
112r APPLICABILITY INFORMATION - A3
REVISED 04/10/07 NCDENR/Division of Air Quality -Application for Air Permit to Construct/Operate
EMISSION SOURCE LISTING: New, Modified, Previously Unpermitted, Replaced, Deleted
EMISSION SOURCE
ID NO.
EMISSION SOURCE
DESCRIPTION
CONTROL DEVIC CONTROL DEVICE
ID NO. DESCRIPTION
EEMi
PAM R[t
10
�rI!►�� e�a R- NOW
FS-C
Polyvinyl Fluoride Manufacturing
Facility No.2
None
t�9=Pearltedqu�pitto:Dpgq
TtttsPptr�alron
a�pent Tad Be F�ELLTy�Tr$�pprat�o
rP`
3
Is your facility subject to 40 CFR Part 68 "Prevention of Accidental Releases"- Section 112(r) of the Federal Clean No 0
Air Act? Yes ❑
If No, please specify in detail how your facility avoided applicability:
If your facility is Subject to 112(r), please complete the following:
A. Have you already submitted a Risk Management Plan (RMP) to EPA Pursuant to 40 CFR Part 68.10 or Part 68.150?
Yes No ❑ Specify required RMP submittal date: June 30, 1999
If submitted, RMP submittal date: June 8, 1999 RMP resubmitted on June 3, 2004
B. Are you using administrative controls to subject your facility to a lesser 112(r) program standard?
Yes ❑ No IN] If yes, please specify:
Attach Additional Shppts As_Npceccary
DEQ-CFW 00072520

FORM A4
'.Sh 'Nid •"aY �.'.
.II. iw1W' 3� ',i VL f •S•w •�v i'W':LfMY. fltw
DATE: 04/02/2008 Does facility'have an environmental mangement system in place?( ) YES (X) NO If so, is facility ISO 14000 Certified?( ) YES ( ) NO
Facility Name: DuPont Company -Fayetteville Works
Permit Number: 03735T32
Facility ID: 0900009
County: Bladen
Environmental Contact: Michael E. Johnson
Mailing Address Line 1: 22828 NC Highway 87 W
Phone No. [phone]
Fax No. [phone]
Mailing Address Line 2:
Zip Code: 28306.7332
County: Bladen
City: Fayetteville State: NC
Email Address: [e-mail]
EMISSIONSAIR •
•
Any Air Emissions Source Reductions in the past year? ( ) YES (X) NO
Enter Code for
Date Reduction
Quantity Emitted
Quantity Emitted
Has reduction actNity been
Source Description and ID
Air Pollutant Emission Reduction
Option Implemented
from prior annual
from current annual
discontinued? If so, when
Addition detail about source
Option (See Codes)
(molyr)
report to DAQ IIblyr)
report to DAQ (Iblyr)
was it discontinued? (molyr
'r�R4le�fs�`�, ��
�+s �;r.y ''(+:
'�r�� '
a �6..,:.:
tii� ' i3C-0''(a
�flBe g p
;�, ,,,x. �. ,.:: ,.,.. a� d4'�,a
•v:v1,%� .tin ,.
s,�,;�,'•'' b.. ? U.
re
,b
n i";r.
d(
1
"�((�ir11
t�^7yyqqt
f• ��;"�Jl.
rH�ila'wt'f�tiL� Eki1a,"a�
Comments:
FACILITY WIDE REDUCTIONSAny
Reductions
or Recycling Activities
in the past year?
( )YES (X) NO
Enter Code for
Pollutant or Recycled or
Date Reduction Emitted
Quantity Emitted
Has reduction activhy been
Source Description or Activity
p y Reduced Materials Emission Reduction
[-&Q-u-antity
Option Implemented from prior annual
from currant annual
discontinued) N so, when
Addition detail about source
Option (See Codes)
(mo/yr) report
report
was it discontinued? (molyr
Vc':y' Pdl,'..A � 1r 1 i ;t > W J• t .:"
"P
�rter Oi%tis� atl0n nd , ' e ae v,�+le t 1 � �
S '
a' �snp
4
1
.:. ;.
N
� f
'-
.
tt
P
�r ��, � • ;�
� ' - , I;
��
::..� -... ,YS., :...Y ; '� .,o •i:, w � "! :.,w
.S; '�iie0�'e�I:EI�IS
,,::,'S 3 �, ,�..± y ,�y ✓:..:�'+ nf.,v. ,. a4, :� � ' �'( <h S f ' 3� ' i'. . s
ri Y} �h. �' I b'��X,.Y ��. d"`,J ! .: ' s� y�y
st' 'i�'t: h fv
:. ; ',
r� ;
� + Ai"". ie'
, s' �h," .
�� n�/p
�
hyif �. ! a. �� .l;• 7�M� Yl!
till .:5 �: � �r. . rn 1
� y.,,�I !v, rTi.i � i
'"j'rEVWu Q�YJ ,H
l
p� ..� ': yaY^d 'n,�,?y t ,�(,',.,rr '1 �1" ':wct i" `ST,p, ,�
�'f."� �•.�.. '. ( .�� �: r41
ai{�
...1 �
.IY' A w14 �.1?Iti '. ��hnev,�.: ��. 19 w'if"�NWF';R' R'f, ) •11 �
:: �'^' �'f:, „ e .Y�`4"w Pw r. r 4� M•"�k, r� � ;. n`� -
.' YD�yQn v
l fr �'d' S
- .� 3 . :. ,...-. R "� �'l
,.
�..'.1 � k
: �. 4l' <,+'. �,p
. .
5( L AV.. 1) l i jM M1
u w ,, b..,;;n ,dti.,f, +Y
... :Y^� .;: .
A T,�f: .i}. �i ,4�17^�3" r �.. � '1�
I tea? ,� :::. .L:,, 1"' .,' n. +
�----
Comments:
The requested information above shall be used for
fulfillin
the requirements of North Carolina General Statute 3-215.108(g). The permit holder shall submit tothe:
D• projected1%source•• 1 • I I I aii
••
shall ••
051
1 • permit and for each annual air quality permit fee payment. Source reduction9
defined as reducing the amount of any hazardous$Q
anyotherw • the environment Cm
0. C
(including fugitive emissions) prior to recycling, treatment, or disposal. If no has taken
R
activity place since the previous report, simply indicate so by checking the '81
no box in that section. Once completed, this form• be first
are.I on the line ofsection each we
for your benefit. �:
Om
"""S°°— ch n ls^
For assistance with FORM A4, please contact the North Carolina DivisionAttaoftVoitWu IonShVrevenAsNetionssa Wnd Environmental Assistance at 1-800-763-0136 or nowaste(cbp2pays.org

FORM B
SPECIFIC EMISSIONS SOURCE INFORMATION (REQUIRED FOR ALL SOURCES)
REVISED 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate f
EMISSION SOURCE DESCRIPTION: polyvinyl Fluoride
Manufacturing Facility N0.2
EMISSION SOURCE ID NO: FS-C
CONTROL DEVICE ID NO(S): None
OPERATING SCENARIO 1 OF 1
EMISSION POINT (STACK) ID NO(S) FEP-C1,C2,C3,104
DESCRIBE IN DETAILTHE EMISSION SOURCE PROCESS (ATTACH FLOW DIAGRAM):
Vinyl fluoride (VF) reacts in a continuous reactor to form crude polyvinyl fluoride (PVF). The
PVF is then isolated in a separator system followed by a filter press and a dryer. The final
product is a solid powder.
TYPE OF EMISSION SOURCE (CHECK AND COMPLETE APPROPRIATE FORM 131-139 ON THE FOLLOWING PAGES):
❑ Coal,wood,oil, gas, other burner (Form B1) '❑ Woodworking (Form B4) ❑ Manufact. of chemicals/coatings/inks (Form B7)
❑ Int.combustion engine/generator (Form B2) ❑ Coating/finishing/printing (Form 65) ❑ Incineration (Form B8)
❑ Liquid storage tanks (Form B3) ❑ Storage silos/bins (Form B6) IR Other (Form 69)
START CONSTRUCTION DAT duly 08
1OPERATION DATE Aug 09 IDATE
MANUFACTURED: July 2008
MANUFACTURER / MODEL NO.: n/a 1EXPECTED OP. SCHEDULE: 24 HR/DAY 7 DAY/WK 50 WK/YR
IS THIS SOURCE SUBJECT TO? NSPS (SUBPART?): NO NESHAP (SUBPART?): NO MACT (SUBPART?): No
PERCENTAGE ANNUAL THROUGHPUT (%): JAN-MAR 25 APR-JUN 25 JUL-SEP 25 OCT-DEC 25
EXPECTED ANNUAL HOURS OF OPERATION: —8300 IVISIBLE STACK EMISSIONS UNDER NORMAL OPERATION: —0 % OPACITY
L s�cAr�ae�z�rM�s�ossr�r�1
�a�nrorissor..: Y .
AIR POLLUTANT EMITTED
SOURCE
OF
EMISSION
FACTOR
EXPECTED ACTUAL
(AFTER CONTROLS/LIMITS)
POTENTIAL EMISSIONS
(BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS)
Ib/hr
tons/ r
Ib/hr
tons/ r
Ib/hr
tons/ r
PARTICULATE MATTER (PM)
Vendor
0.3
1.1
0.4
1.7
0.4
1.7
PARTICULATE MATTER<10 MICRONS (PM10)
Vendor
0.3
1.1
0.4
1.7
0.4
1.7
PARTICULATE MATTER<2.5 MICRONS (PM2.1)
Vendor
0.3
1.1
0.4
1.7
0.4
1.7
SULFUR DIOXIDE (S02)
0
1 0
0
0
0
0
NITROGEN OXIDES (NOx)
0
0
0
0
0
0
CARBON MONOXIDE (CO)
0
0
0
0
0
0
VOLATILE ORGANIC COMPOUNDS (VOC)
Model
4.7
16.3
6.1
26.8
6.1
26.8
LEAD
0
0
0
0
0
0
OTHER
1 0
1 0
0
0
0
0
HAZARDOUS AIR POLLUTANT
AND CAS NUMBER
SOURCE
OF
EMISSION
FACTOR
EXPECTED ACTUAL
(AFTER CONTROLS/LIMITS)
POTENTIAL EMISSIONS
(BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS)
Ib/hr
tons/ r
Ib/hr
tons/ r
Ib/hr
tons/ r
None
} �.X!4uT�Eiss�o�ir.tnr�.Ri4lroorrocr
INDICATE EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS
TOXIC AIR POLLUTANT AND CAS NO.
EF SOURCE
Ib/hr
Ibida
Ib/ r
None
ttachments: (1) emissions calculations and supporting documentation; (2) indicate all requested state and federal enforceable permit limits (e.g. hours of operation, emission
rates) and describe how these are monitored and with what frequency: and (3) describe any monitoring devices, gauges, or test ports for this source.
COMPLETE THIS FORM AND COMPLETE AND ATTACH APPROPRIATE B1 THROUGH B9 FORM FOR EACH SOURCE
Attach Additional Sheets As Necessary
DEQ-CFW 00072522

FORM 139 - Confidential
EMISSION SOURCE (OTHER)
REVISED: 12/01/01 NCDENR/Division of Air Qualitv - Aoolication for Air Permit to Construct/Ooerate B9
EMISSION SOURCE DESCRIPTION: Polyvinyl Fluoride
Manufacturing Facility No. 2
EMISSION SOURCE ID NO: FS-C
CONTROL DEVICE ID NO(S): None
OPERATING SCENARIO: 1 OF 1
EMISSION POINT (STACK) ID NO(S; FEP-C1, C2, C3, C4
DESCRIBE IN DETAIL THE PROCESS (ATTACH FLOW DIAGRAM):
Vinyl fluoride (VF) reacts in a continuous reactor to form crude polyvinyl fluoride (PVF). The
PVF is then isolated in a separator system followed by a filter press and a dryer. The final
product is a solid powder.
MAX. DESIGN
CAPACITY UNIT/HR
REQUESTED CAPACITY
LIMITATION UNIT/HR
TYPE
UNITS
Vinyl Fluoride
lb.
Confidential
d-Linonene (inhibitor)
lb.
Confidential
Propylene (modifier)
lb.
Confidential
Water soluable salt (inhibitor)
lb.
Confidential
V
MAX. DESIGN
CAPACITY UNIT/BATCH
REQUESTED CAPACITY
LIMITATION UNIT/BATCH
TYPE
UNITS
MAXIMUM DESIGN BATCHES / HOUR):
REQUESTED LIMITATION (BATCHES / HOUR): (BATCHES/YR):
FUEL USED: Not applicable (NA)
TOTAL MAXIMUM FIRING RATE (MILLION BTU/HR): NA
MAX. CAPACITY HOUF NA
REQUESTED CAPACITY ANNUAL FUEL USE: NA
COMMENTS:
Process flow diagram attached as separate page.
Attach Additional Sheets as Necessary
DEQ-CFW 00072523

POLYVINYL FLUORIDE MANUFACTURING FACILITY NO.2
EMISSION SOURCE ID NO. FS-C
PROCESS FLOWCHART
INHIBITED VINYL FLUORIDE
�►
VINYL-A
STORAGE TANK
FLUORIDE
IF
MODIFIER
FEED SYSTEM
REMOVED
INHIBITOR
INITIATOR 10
FEP-C4
ANALYTICAL
---- EQUIPMENT
CRUDE
PVF REACTOR I PVF
FEP-C3
PRODUCT
COLLECTION PVF ISOLATION FLASH
SYSTEM EQUIPMENT TANK
-♦ FEP-Cl
SEPARATOR
SYSTEM
PRODUCT
FEP-C2
MAINTENANCE
HEADER------------v
E
GITIVE---------- FROM PROCESS
EQUIPMENT
DEQ-CFW 00072524

FORM D1
FACILITY -WIDE EMISSIONS SUMMARY
REVISED.12/01101 NCDENR/Division of Air Qualitv - AnDlication for Air Permit to Construct/Onerate D1
EXPECTED ACTUAL EMISSIONS
POTENTIAL EMISSIONS
POTENTIAL EMISSIONS
(AFTER CONTROLS /
(BEFORE CONTROLS /
(AFTER CONTROLS /
LIMITATIONS)
LIMITATIONS)
LIMITATIONS
AIR POLLUTANT EMITTED
tons/ r
tons/ r
tons/ r
PARTICULATE MATTER (PM)
-50
Unchanged (site is
Unchanged (site is
Major Source)
Major Source)
PARTICULATE MATTER < 10 MICRONS (PM,,)
—50
Unchanged (site is
Unchanged (site is
Major Source)
Major Source)
PARTICULATE MATTER < 2.5 MICRONS (PM2.5)
—50
Unchanged (site is
Unchanged (site is
Major Source)
Major Source)
SULFUR DIOXIDE (S02)
—600
Unchanged (site is
Unchanged (site is
Major Source)
Major Source)
NITROGEN OXIDES (NOx)
—100
Unchanged (site is
Unchanged (site is
Major Source)
Major Source)
CARBON MONOXIDE (CO)
-15
Unchanged (site is
Unchanged (site is
Major Source)
Major Source)
VOLATILE ORGANIC COMPOUNDS (VOC)
—215
Major Source
Major Source
LEAD
OTHER
�I?tUT4.�sst�r4
,RE 2 l
EXPECTED ACTUAL EMISSIONS
POTENTIAL EMISSIONS
POTENTIAL EMISSIONS
(AFTER CONTROLS /
(BEFORE CONTROLS /
(AFTER CONTROLS /
LIMITATIONS)
LIMITATIONS)
LIMITATIONS
HAZARDOUS AIR POLLUTANT EMITTED
CAS NO.
tons/ r
tons/ r
tons/ r
Total HAPs[>25
(site is Major Source)
>25 (site is Major
>25 (site is Major
Source)
Source)
INDICATE REQUESTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS. EMISSIONS ABOVE THE TOXIC PERMIT EMISSION RATE (TPER) IN
15A NCAC 2Q .0711 MAY REQUIRE AIR DISPERSION MODELING. USE NETTING FORM D2 IF NECESSARY.
Modeling Required ?
TOXIC AIR POLLUTANT EMITTED
CAS NO.
Ib/hr
lb/day
lb/year
Yes
No
No TAPs will be emitted from this
modification.
X
COMMENTS:
As indicated above, the site is a major source for criteria pollutants and HAPs..The proposed operation of the
Polyvinyl Fluoride Manufacturing Facility No. 2 (ID No. FS-C) will not change any of the current classifications.
VOC is the only pollutant emitted from this process. The Polyvinyl Fluoride Manufacturing Facility No. 2 does not
emit any HAPs or any TAPS.
Attach Additional Sheets as Necessary
DEQ-CFW 00072525

FORM D2
AIR POLLUTANT NETTING WORKSHEET
Revised:12/01101 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate D2
PURPOSE OF NETTING: ❑ AIR TOXICS ❑ PSD (100/250 tons per year) ❑ PSD SIGNIFICANT LEVELS
AIR POLLUTANT: None CAS NO.:
EMISSION SOURCE ID NOS.:
y
EMISSIONS - USE APPROPRIATE COLUMNS ONLY
LBNEAR
LB/DAY
LB/HR
MODIFICATION
INCREASE
- MINUS -
- MINUS -
- MINUS -
- MINUS -
MODIFICATION
DECREASE
= EQUALS =
= EQUALS =
= EQUALS =
= EQUALS =
NET CHANGE
FROM MODIFICATION
-. ,f G•
�t +F
-.SAif`v`b 3 - -' fy Y X .S, v' .31
:r�" 4,_ tg' ,ifi' :�.
fU�faNA
i, s3.', '� j
"� ' '
s1F-'Tk�s.?�Siri.�
..�4`1Jj'-E$").=MfS
3'.a..3<S�a.�_z-1'r
e 3 -z wr �s.'Tx.S.;,..'�'�`.
.r
s�W
CREDITABLE
INCREASE
- MINUS -
- MINUS -
- MINUS -
- MINUS -
CREDITABLE
DECREASE
= EQUALS =
= EQUALS =
= EQUALS =
= EQUALS =
NET CREDITABLE
CHANGE
3_
L_�s..<..ir'v
5�t.., •4Y.,.n.
TOTAL FACILITY
EMISSIONS
TPER LEVELS (2Q .0711)
CHECK HERE IF AN AIR DISPERSION MODELING ANALYSIS IS REQUIRED ❑
COMMENTS: The Polyvinyl Fluoride Manufacturing Facility No. 2 will have no emissions of Toxic
Air Pollutants. The combined potential emissions of VOCs from the Polyvinyl Fluoride
Manufacturing Facility No. 1 and the Polyvinyl Fluoride Manufacturing Facility No. 2 will be
greater than the 40 ton per year significant level for PSD applicability. A PSD avoidance
condition of 40 tons VOC per year is being requested for the combined VOC emissions from
these two facilities.
Attach Additional Sheets As Necessary
DEQ-CFW 00072526

FORM D3
MODELING REQUEST FORMS (3 pages)
REVISED: 02/20/03 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate D3
If the applicant desires, the NCDAQ/AQAB will perform the initial modeling compliance demonstration using EPA approved screening
and, if applicable and where possible, refined models. If the model results indicate the facility will be unable to demonstrate compliance
with applicable Acceptable Ambient Level(s) the applicant will be notified and will be required to perform the compliance demonstration
using established modeling protocol and modeling analysis requirements as defined in the North Carolina Administrative Code 15A
NCAC 2D .1100 and 2Q .0700 and in the Guidelines for Evaluating the Impacts of Toxic Pollutants in North Carolina.
To perform the dispersion modeling compliance demonstration, the AQAB will require the following data:
Provide a brief description of the modification and/or addition necessitating the toxic modeling request:
The Polyvinyl Fluoride Manufacturing Facility No. 2 will have no emissions of Toxic Air
Pollutants. Therefore, modeling is neither needed nor requested. Subsequently, pages 2 and 3
of this form are not included in this application.
�,
xik�1i.In:iiSJO#..it74.L`SlY�
ft3f F "L.'u�m-.N
TOXIC AIR POLLUTANT (TAP)
MAXIMUM TOXIC AIR POLLUTANT TAP EMISSIONS (After Controls)
Emission Point ID
Ibs/ ear
Ibs/da
Ibs/hr
I
Attach Additional Sheets As Necessary Page 1 of 3
DEQ-CFW 00072527

FORM D4
EXEMPT AND INSIGNIFICANT ACTIVITIES SUMMARY
REVISED: 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate
D4
rs
SIZE OR
PRODUCTION
BASIS FOR EXEMPTION OR
DESCRIPTION OF EMISSION SOURCE
RATE
INSIGNIFICANT ACTIVITY
Per AP-42 Section 13.2.6, particulate
emission factors for abrasive blasting
Less than 100
of mild steel panels with a five mile per
tons abasive is
hour wind speed, total particulate
Abrasive blasting building
used
matter emissions would be 27 pounds
per year
per 1,000 pounds of abrasive. Based
on this, 100 tons of abrasive would
generate 5400 lb. or 2.7 ton PM.
2.
3.
4.
5.
6.
7.
8.
Attach Additional Sheet As Necessary
DEQ-CFW 00072528

FORM D
TECHNICAL ANALYSIS TO SUPPORT PERMIT APPLICATION
REVISED: 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate D5
PROVIDE DETAILED TECHNICAL CALCULATIONS TO SUPPORT ALL EMISSION, CONTROL, AND REGULATORY
DEMONSTRATIONS MADE IN THIS APPLICATION. INCLUDE A COMPREHENSIVE PROCESS FLOW DIAGRAM AS
NECESSARY TO SUPPORT AND CLARIFY CALCULATIONS AND ASSUMPTIONS. ADDRESS THE
FOLLOWING SPECIFIC ISSUES ON SEPARATE PAGES:
A.
SPECIFIC EMISSIONS SOURCE (EMISSION INFORMATION) (FORM B) - SHOW CALCULATIONS USED, INCLUDING EMISSION FACTORS,
MATERIAL BALANCES, AND/OR OTHER METHODS FROM WHICH THE POLLUTANT EMISSION RATES IN THIS APPLICATION WERE DERIVED.
INCLUDE CALCULATION OF POTENTIAL BEFORE AND, WHERE APPLICABLE, AFTER CONTROLS. CLEARLY STATE ANY ASSUMPTIONS MADE
AND PROVIDE ANY REFERENCES AS NEEDED TO SUPPORT MATERIAL BALANCE CALCULATIONS.
B.
SPECIFIC EMISSION SOURCE (REGULATORY INFORMATION)(FORM E2 - TITLE V ONLY) - PROVIDE AN ANALYSIS OF ANY REGULATIONS
APPLICABLE TO INDIVIDUAL SOURCES AND THE FACILITY AS A WHOLE. INCLUDE A DISCUSSION OUTING METHODS (e.g. FOR TESTING
AND/OR MONITORING REQUIREMENTS) FOR COMPLYING WITH APPLICABLE REGULATIONS, PARTICULARLY THOSE REGULATIONS LIMITING
EMISSIONS BASED ON PROCESS RATES OR OTHER OPERATIONAL PARAMETERS. PROVIDE JUSTIFICATION FOR AVOIDANCE OF AN
FEDERAL REGULATIONS (PREVENTION OF SIGNIFICANT DETERIORATION (PSD), NEW SOURCE PERFORMANCE STANDARDS (NSPS),
NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS (NESHAPS), TITLE V), INCLUDING EXEMPTIONS FROM THE FEDERAL
REGULATIONS WHICH WOULD OTHERWISE BE APPLICABLE TO THIS FACILITY. SUBMIT ANY REQUIRED TO DOCUMENT COMPLIANCE WITH
ANY REGULATIONS. INCLUDE EMISSION RATES CALCULATED IN ITEM "A" ABOVE, DATES OF MANUFACTURE, CONTROL EQUIPMENT, ETC.
TO SUPPORT THESE CALCULATIONS.
C.
CONTROL DEVICE ANALYSIS (FORM C) - PROVIDE A TECHNICAL EVALUATION WITH SUPPORTING REFERENCES FOR ANY CONTROL
EFFICIENCIES LISTED ON SECTION C FORMS, OR USED TO REDUCE EMISSION RATES IN CALCULATIONS UNDER ITEM "A" ABOVE. INCLUDE
PERTINENT OPERATING PARAMETERS (e.g. OPERATING CONDITIONS, MANUFACTURING RECOMMENDATIONS, AND PARAMETERS AS
APPLIED FOR IN THIS APPLICATION) CRITICAL TO ENSURING PROPER PERFORMANCE OF THE CONTROL DEVICES). INCLUDE AND
LIMITATIONS OR MALFUNCTION POTENTIAL FOR THE PARTICULAR CONTROL DEVICES AS EMPLOYED AT THIS FACILITY. DETAIL
PROCEDURES FOR ASSURING PROPER OPERATION OF THE CONTROL DEVICE INCLUDING MONITORING SYSTEMS AND MAINTENANCE TO
BE PERFORMED.
D.
PROCESS AND OPERATIONAL COMPLIANCE ANALYSIS - (FORM E3 - TITLE V ONLY) - SHOWING HOW COMPLIANCE WILL BE ACHIEVED
WHEN USING PROCESS, OPERATIONAL, OR OTHER DATA TO DEMONSTRATE COMPLIANCE. REFER TO COMPLIANCE REQUIREMENTS IN
THE REGULATORY ANALYSIS IN ITEM "B" WHERE APPROPRIATE. LIST ANY CONDITIONS OR PARAMETERS THAT CAN BE MONITORED AND
REPORTED TO DEMONSTRATE COMPLIANCE WITH THE APPLICABLE REGULATIONS.
E.
PROFESSIONAL ENGINEERING SEAL - PURSUANT TO 15A NCAC 2Q .0112 "APPLICATION REQUIRING A PROFESSIONAL ENGINEERING SEAL,"
A PROFESSIONAL ENGINEER REGISTERED IN NORTH CAROLINA SHALL BE REQUIRED TO SEAL TECHNICAL PORTIONS OF THIS
APPLICATION FOR NEW SOURCES AND MODIFICATIONS OF EXISTING SOURCES. (SEE INSTRUCTIONS FOR FURTHER APPLICABILITY).
1, attest that this application for
has been reviewed by me and is accurate, complete and consistent with the
information supplied in the engineering plans, calculations, and all other supporting documentation to the best of my knowledge. I
further attest that to the best of my knowledge the proposed design has been prepared in accordance with the applicable regulations.
Although certain portions of this submittal package may have been developed by other professionals, inclusion of these materials
under my seal signifies that I have reviewed this material and have judged it to be consistent with the proposed design. Note: In
accordance with NC General Statutes 143-215.6A and 143-215.6B, any person who knowingly makes any false statement,
representation, or certification in any application shall be guilty of a Class 2 misdemeanor which may include a fine not to exceed
$10,000 as well as civil penalties up to $25,000 per violation.
(PLEASE USE BLUE INK TO COMPLETE THE FOLLOWING) PLACE NORTH CAROLINA SEAL HERE
NAME:
DATE:
COMPANY:
ADDRESS:
TELEPHONE:
SIGNATURE:
PAGES CERTIFIED:
(IDENTIFY ABOVE EACH PERMIT FORM AND ATTACHMENT
THAT IS BEING CERTIFIED BY THIS SEAL)
Attach Additional Sheets As Necessary -- See Attached Calculation Sheet
DEQ-CFW 00072529

FORM E1
TITLE V GENERAL INFORMATION
REVISED: 12/01/01 Division of Air Quality - Application for Air Permit to Construct/Operate
E1
Indicate here if your facility is subject to Title V by: EI Emissions ❑ Other
If subject to Title V by other, check or specify: ❑ NSPS ❑ NESHAPS (MACT) ❑ TITLE IV
Other, specify:
If you are or will be subject to any maximum achievable control technology standards (MACT) issued pursuant to section
112(d) of the Clean Air Act, specify below:
EMISSION SOURCE
EMISSION SOURCE ID DESCRIPTION MACT
BS-D Butacite Tinting "Printing MACT" (40 CFR Part 63 Subpart KK
Throughout Facilitl Facility Wide "MON MACT" (40 CFR Part 63 Subpart FFFF)
List any additional regulation which are requested to be included in the shield and provide a detailed explanation as to why
the shield should be granted:
REGULATION EMISSION SOURCE (Include ID) EXPLANATION
Comments:
Attach Additional Sheets As Necessary
DEQ-CFW 00072530

FORM E2
EMISSION SOURCE APPLICABLE REGULATION LISTING
REVISED 12/( Division of Air Qualitv - AnDlication for Air Permit to Construct/Onerate E2
EMISSION
EMISSION
OPERATING SCENARIO
SOURCE
SOURCE
INDICATE PRIMARY (P)
APPLICABLE
ID NO.
DESCRIPTION
OR ALTERNATIVE (A)
POLLUTANT
REGULATION
s
_
Polyvinyl Fluoride
FS-B
Manufacturing
NCAC 2Q.0317 - Avoidance
FS-C
Facilities No. 1 and
p
VOC
conditions for 15A NCAC 2D.0530
No.2
Polyvinyl Fluoride
FS-C
Manufacturing
p
PM
NCAC 2D.0515 -Particulate matter
Facilities No.2
for vent FEP-C4 only
Polyvinyl Fluoride
FS-C
Manufacturing
P
VE
NCAC 2D.0521 - Visible emissions
Facilities No.2
for vent FEP-C4 only
Polyvinyl Fluoride
FS-C
Manufacturing
P
Odor
NCAC 2D.1806 - Odor (State -Only
Facilities No.2
Requirement)
Attach Additional Sheets As Necessary
DEQ-CFW 00072531

FORM E3
EMISSION SOURCE COMPLIANCE METHOD
REVISED 12/01/01 NCDENR/Division Of Air Quality - Application for Air Permit to Construct/Operate F E3
Regulated Pollutant VOC
Emission Source ID NO. FS-B and FS-C Applicable Regulation NCAC 2Q.0317
Alternative Operating Scenario (AOS) NO:
ATTACH A SEPARATE PAGE TO EXPAND ON ANY OF THE BELOW COMMENTS
Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes rX-1 No
If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes ❑x No
Describe Monitoring Device Type: Not applicable
Describe Monitoring Location: Not applicable
Other Monitoring Methods (Describe In Detail): Not applicable
Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous
readings taken to produce an hourly average):
,.*�� ..
Data (Parameter) being recording: VOC emissions will be determined via engineering calculations
Frequency of recordkeeping (How often is data recorded?): Monthly
Generally describe what is being reported: Monthly VOC emissions will be determined monthly and
will be reported to N.C. Division of Air Quality every six months.
Frequency: ❑ MONTHLY ❑ QUARTERLY 0 EVERY 6 MONTHS
❑ OTHER (DESCRIBE):
.1 6�
" HMO;y�4S_.u, v. 3 AMA.-K't�.._ie� Y 1
Specify proposed reference test method: Not applicable
Specify reference test method rule and citation: Not applicable
Specify testing frequency: Not applicable
NOTE - Proposed test method subject to approval and possible change during the test protocol process
Attach Additional Sheets As Necessary
DEQ-CFW 00072532

FORM E3
EMISSION SOURCE COMPLIANCE METHOD
REVISED 12/01/01 NCDENR/Division Of Air Quality - Application for Air Permit to Construct/Operate 1 FA 1
Regulated Pollutant Particulate matter
Emission Source ID NO. FS-C Applicable Regulation NCAC 2D.0515
Alternative Operating Scenario (AOS) NO:
ATTACH A SEPARATE PAGE TO EXPAND ON ANY OF THE BELOW COMMENTS
WIRE x..v. a_. ... Y r,,.Jrtr-.sue' •� 3
ir`:eS: .#+%sz x"�A4-• .r� N 4e-3`a. a ... � & i -i t °':+ ".., .:a P i , c..-#fd`.,. :v,° ` ✓,=�!`3? '*Rx
Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes No
If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes No
Describe Monitoring Device Type: Not applicable
Describe Monitoring Location: Not applicable
Other Monitoring Methods (Describe In Detail): Not applicable
Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous
readings taken to produce an hourly average):
.a f�,.Z'4"§..: ✓'�: _t' a`.Yi..%9. _..?`tirr�. .`_*�: .R,� _�?k fir. %Fisi#��l "aw yf � �6'X._O .. �a+V .k ai„ _.."�_y s�`. .;-., z'§.�i,... -.a .`rv'� 'fia; ,,�-w_
Data (Parameter) being recording: Production reocords will be maintained and will be available to
a DAQ representative upon request.
Frequency of recordkeeping (How often is data recorded?): Annual
*"
Generally describe what is being reported: Norte
Frequency: ❑ MONTHLY ❑ QUARTERLY ❑ EVERY 6 MONTHS
❑ OTHER (DESCRIBE):
Specify proposed reference test method: Not applicable
Specify reference test method rule and citation: Not applicable
Specify testing frequency: Not applicable
NOTE - Proposed test method subject to approval and possible change during the test protocol process
Attach Additional Sheets As Necessary
DEQ-CFW 00072533

FORM E3
EMISSION SOURCE COMPLIANCE METHOD
REVISED 12/01/01 NCDENR/Division Of Air Quality - Application for Air Permit to Construct/Operate E3
Regulated Pollutant Visible emissions
Emission Source ID NO. FS-B and FS-C Applicable Regulation NCAC 2D.0521
Alternative Operating Scenario (AOS) NO:
ATTACH A SEPARATE PAGES TO EXPAND ON ANY OF THE BELOW COMMENTS
Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes ❑X No
If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes 0 No
Describe Monitoring Device Type: Not applicable
Describe Monitoring Location: Not applicable
Other Monitoring Methods (Describe In Detail): Not applicable -- This process does not produce
visible emissions as demonstrated by the existing PVF Manufacturing Facility No. 1 that has
has been in operation since Setember 2007.
Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous
readings taken to produce an hourly average):
BWi.
Data (Parameter) being recording: Visible emissions will be determined via visual observation
Frequency of recordkeeping (How often is data recorded?): Monthly
Generally describe what is being reported: None
Frequency: ❑ MONTHLY ❑ QUARTERLY ❑ EVERY 6 MONTHS
❑ OTHER (DESCRIBE):
Specify proposed reference test method: Not applicable
Specify reference test method rule and citation: Not applicable
Specify testing frequency: Not applicable
NOTE - Proposed test method subject to approval and possible change during the test protocol process
Attach Additional Sheets As Necessary
DEQ-CFW 00072534

FORM E3
EMISSION SOURCE COMPLIANCE METHOD
REVISED 12/01/01 NCDENR/Division Of Air Quality - Application for Air Permit to Construct/Operate E3
Regulated Pollutant Odor
Emission Source ID NO. FS-C Applicable Regulation NCAC 2D.1806
Alternative Operating Scenario (AOS) NO:
ATTACH A SEPARATE PAGE TO EXPAND ON ANY OF THE BELOW COMMENTS
Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes M No
If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes ❑X No
Describe Monitoring Device Type: Not applicable
Describe Monitoring Location: Not applicable
Other Monitoring Methods (Describe •In Detail): Not applicable
Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous
readings taken to produce an hourly average):
Data (Parameter) being recording: Not applicable
Frequency of recordkeeping (How often is data recorded?):
Generally describe what is being reported: Not applicable
Frequency: ❑ MONTHLY ❑ QUARTERLY ❑ EVERY 6 MONTHS
❑ OTHER (DESCRIBE):
Specify proposed reference test method: Not applicable
Specify reference test method rule and citation: Not applicable
Specify testing frequency: Not applicable
NOTE - Proposed test method subject to approval and possible change during the test protocol process
Attach Additional Sheets As Necessary
DEQ-CFW 00072535

FORM E4
EMISSION SOURCE COMPLIANCE SCHEDULE
Revised 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate ' E4
COMPLIANCE STATUS WITH RESPECT TO ALL APPLICABLE REQUIREMENTS
Will each emission source at your facility be in compliance with all applicable requirements at the time of permit
issuance and continue to comply with these requirements?
0 Yes ❑ No If NO, complete A through F below for each requirement for
which compliance is not achieved.
Will your facility be in compliance with all applicable requirements taking effect during the term of the permit and
meet such requirements on a timely basis?
El Yes ❑ No If NO, complete A through F below for each requirement for
which compliance is not achieved.
If this application is for a modification of existing emissions source(s), is each emission source currently in
compliance with all applicable requirements?
21 Yes ❑ No If NO, complete A through F below for each requirement for
which compliance is not achieved.
A. Emission Source Description (Include ID NO.)
B. Identify applicable requirement for which compliance is not achieved:
C. Narrative description of how compliance will be achieved with this applicable requirements:
D. Detailed Schedule of Compliance:
Step(s)
E. Frequency for submittal of progress reports (6 month minimum):
Not applicable
F. Starting date of submittal of progress reports: Not applicable
Date Expected
Attach Additional Sheets As Necessary
DEQ-CFW 00072536

r Revised 01/01/07
FORM E5
TITLE V COMPLIANCE CERTIFICATION (Required)
NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate
In accordance with the provisions of Title 15A NCAC 2Q .0520 and .0515(b)(4),
the responsible company official of.
SITE NAME: DuPont Fayetteville Works
SITE ADDRESS: 22828 NC Highway 87 W
CITY, NC: Fayetteville, NC 28306
COUNTY: Bladen
PERMIT NUMBER: 03735T32
CERTIFIES THAT (Check the appropriate statement):
Fx_1 The facility is in compliance with all applicable requirements
E5
❑ In accordance with the provisions of Title 15A NCAC 2Q .0515(b)(4) the responsible
company official certififies that the proposed minor modification meets the criteria for using
the procedures set out in 2Q .0515 and requests that these procedures be used to process
the permit application.
❑ The facility is not currently in compliance with all applicable requirements
If this box is checked, you must also complete form E4 "Emission Source Compliance Schedule"
The undersigned certifies under the penalty of law, that all information and statements provided
in the application, based on information and belief formed after reasonable inquiry, are true,
accurate, and complete.
K)
Karen B. Wrigley, Plant Manager
Name, Title of responsible company official (Type or print)
Date: OWf Gajo8
Attach Additional Sheets As Necessary
DEQ-CFW 00072537