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DEQ-CFW_00071607
FORM B SPECIFIC EMISSIONS SOURCE INFORMATION (REQUIREDtib Att �' Es) REVISED 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate B EMISSION SOURCE DESCRIPTION: Diesel Engine for Emergency Electrical Generator EMISSION SOURCE ID NO: RICE-03 CONTROL DEVICE ID NO(S): None OPERATING SCENARIO -1-OF-1 EMISSION POINT (STACK) ID NO(S): EP-RICE-03 DESCRIBE IN DETAILTHE EMISSION SOURCE PROCESS (ATTACH FLOW DIAGRAM): This emission source is a stationary emergency generator that is powered by a 197 HP (147 kW) diesel engine. The diesel engine is subject to the Part 63 Subpart ZZZZ RICE MACT. An emergency stationary RICE may be operated for a maximum of 100 hours per calendar year for maintenance checks and readiness testing. There is no time limit on the use of emergency stationary RICE in emergency situations. Per NC-DAQ policy for emergency engines, potential emissions are based on 500 hr/yr of operation. TYPE OF EMISSION SOURCE (CHECK AND COMPLETE APPROPRIATE FORM B1-B9 ON THE FOLLOWING PAGES): ❑ Coal,wood,oil, gas, other burner (Form B1) ❑ Woodworking (Form B4) ❑ Manufact. of chemicals/coatings/inks (Form B7) © Int.combustion engine/generator (Form B2) ❑ Coating/finishing/printing (Form 65) ❑ Incineration (Form 68) ❑ Liquid storage tanks (Form 63) ❑ Storage silos/bins (Form B6) ❑ Other (Form 69) START CONSTRUCTION DATE: Sept 2014 OPERATION DATE: Oct 2014 I DATE MANUFACTURED: July 2014 MANUFACTURER / MODEL NO.: John Deere / Model4045HF285 EXPECTED OP. 0.5 HR/DAY 1 DAY/WK 52 WK/YR SCHEDULE: IS THIS SOURCE SUBJECT TO? NSPS (SUBPART?): YES (1111) NESHAP (SUBPART?): Yes (ZZZZ) MACT (SUBPART?): YES (ZZZZ) PERCENTAGE ANNUAL THROUGHPUT (%): JAN-MAR 25 APR-JUN 25 JUL-SEP 25 OCT-DEC 25 EXPECTED ANNUAL HOURS OF OPERATION: <100 IVISIBLE STACK EMISSIONS UNDER NORMAL OPERATION: -0 % OPACITY CRITERIA AIR POLLUTANT EMISSIONS INFORMATION FOR THIS SOURCE AIR POLLUTANT EMITTED SOURCE of EMISSION FACTOR EXPECTED ACTUAL (AFTER CONTROLS/LIMITS) POTENTIAL EMISSIONS (BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS) Whir tons/yr Ib/hr tons/yr Ib/hr tons/yr PARTICULATE MATTER (PM) NSPS IIII 0.06 0.003 0.06 0.02 0.06 0.02 PARTICULATE MATTER<10 MICRONS (PMio) NSPS IIII 0.06 0.003 0.06 0.02 0.06 0.02 PARTICULATE MATTER<2.5 MICRONS (PM2.5) NSPS IIII 0.06 0.003 0.06 0.02 0.06 0.02 SULFUR DIOXIDE (S02) NCDAQ 0.24 0.01 0.24 0.06 0.24 0.06 NITROGEN OXIDES (NOx) NSPS IIII 1.20 0.06 1.20 0.3 1.20 0.30 CARBON MONOXIDE (CO) NSPS IIII 1.13 0.06 1.13 0.28 1.13 0.28 VOLATILE ORGANIC COMPOUNDS (VOC) NSPS IIII 0.10 0.005 0.10 0.02 0.10 0.02 LEAD NCDAQ 1.2E-05 6.2E-07 1.E-05 3.1 E-06 1.E-05 3.1 E-06 OTHER NCDAQ 0 0 0 0 1 0 1 0 HAZARDOUS AIR POLLUTANT EMISSIONS INFORMATION FOR THIS SOURCE HAZARDOUS AIR.POLLUTANT AND CAS NUMBER SOURCE OF EMISSION FACTOR EXPECTED ACTUAL (AFTER CONTROLS/LIMITS) POTENTIAL EMISSIONS (BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS) Ib/hr tons/yr Ib/hr tons/yr Ib/hr tons/yr See attached "Supporting Documentation for Form D" TOXIC AIR POLLUTANT EMISSIONS INFORMATION FOR THIS SOURCE INDICATE EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS TOXIC AIR POLLUTANT AND CAS NO. EF SOURCE Ib/hr lb/day Ib/yr See attached "Supporting Documentation for Form D" Attachments: (1) emissions calculations and supporting documentation; (2) indicate all requested state and federal enforceable permit limits (e.g. hours of operation, emission rates) and describe how these are monitored and with what frequency; and (3) describe any monitoring devices, gauges, or test ports for this source. COMPLETE THIS FORM AND COMPLETE AND ATTACH APPROPRIATE B1 THROUGH B9 FORM FOR EACH SOURCE Attach Additional Sheets As Necessary DEQ-CFW 00071607 SUPPORTING DOCUMENTION FOR FORM D TECHNICAL ANALYSIS TO SUPPORT PERMIT APPLICATION The Actual and Potential Emissions of nonmethane hydrocarbon plus oxides of nitrogen (NMHC+NOx), carbon monoxide (CO), and particulate matter (PM) are determined below using the emission limitations specified in Table 1 of 40 CFR 89.112(a) and the NC Division of Air Quality policy to calculate the potential emissions of emergency engines based on 500 hours per year of operation. NMHC Carbon Particulate + NOx VOC Monoxide matter NOx (CO) (PM) NSPS Subpart IIII Emission Limit (g/kW-hr) 4.0 3.5 0.2 Table 1 of 40 CFR 89.112(a) Engine Power Rating (kW) 147 147 147 Maximum Engine (hr/yr) 100 100 100 Actual Operation Emergency Engines Potential Operation (hr/yr) 500 500 500 Mass Conversion (g/lb) 453.6 453.6 453.6 (Ib/hr) 1.30 1.20 0.10 1.13 0.06 Actual Emissions (tons/yr) 0.065 0.060 0.005 0.057 0.003 (lb/hr) 1.30 1.20 0.10 1.13 0.06 Potential Emissions (tons/yr) 0.32 0.30 0.02 0.28 0.02 * nonmethane hydrocarbon (NMHC) plus oxides of nitrogen (NOx) Note: The actual and potential emissions of NOx and VOC were estimated using the relative fraction of those two components from the DAQ GAS & DIESEL INTERNAL COMBUSTION ENGINES EMISSIONS CALCULATOR spreadsheet, namely 92.5% NOx and 7.5% VOC, and applying those fractions to the calculated emissions of nonmethane hydrocarbon plus oxides of nitrogen (NMHC+NOx). DEQ-CFW 00071608 SUPPORTING DOCUMENTION FOR FORM D TECHNICAL ANALYSIS TO SUPPORT PERMIT APPLICATION The actual and potential emissions of sulfur dioxide (S02) and the below listed Toxic and Hazardous Ari Pollutants are estimated using the respective emission factors from the DAQ GAS & DIESEL INTERNAL COMBUSTION ENGINES EMISSIONS CALCULATOR spreadsheet, and using the 100 hr/yr limit of Part 63 Subpart ZZZZ for the Actual Emissions and using the NC- DAQ policy of 500 hr/yr of operation for emergency engines for the Potential Emissions. CRITERIA AIR POLLUTANT EMISSIONS INFORMATION AIR POLLUTANT EMITTED ACTUAL EMISSIONS POTENTIAL EMISSIONS EMISSION FACTOR CAS (AFTER CONTROLS( LIMITS) (BEFORECONTROLS/LIMITS) (AFTER CONTROLS/LIMITS) Ib/hp-hr NUMBER Ib/hr tons/yr Ib/hr tons/yr Ib/hr tons/yr uncontrolled SULFUR DIOXIDE (S02) 75070 0.24 1 0.01 0.24 0.06 0.24 1 0.06 1.21 E-03 TOXIC 1 HAZARDOUS AIR POLLUTANT EMISSIONS INFORMATION TOXIC / HAZARDOUS AIR POLLUTANT ACTUAL EMISSIONS POTENTIAL EMISSIONS EMISSION FACTOR CAS (AFTER CONTROLS/LIMITS) (BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS) Ib/hp-hr NUMBER Ib/hr Ib/yr Ib/hr Ib/yr Ib/hr Ib/yr uncontrolled Acetaldehyde (H,T) 75070 1.06E-03 1.06E-01 1.06E-03 5.29E-01 1.06E-03 5.29E-01 5.37E-06 Acrolein (H,T) 107028 1.28E-04 1.28E-02 1.28E-04 6.38E-02 1.28E-04 6.38E-02 6.48E-07 Arsenic unlisted compounds (H,T) ASC-Other 5.52E-06 5.52E-04 5.52E-06 2.76E-03 5.52E-06 2.76E-03 2.80E-08 Benzene (H,T) 71432 1.29E-03 1.29E-01 1.29E-03 6.43E-01 1.29E-03 6.43E-01 6.53E-06 Benzo(a)pyrene (H,T) 50328 2.59E-07 2.59E-05 2.59E-07 1.30E-04 2.59E-07 1.30E-04 1.32E-09 Beryllium metal (unreacted) (H,T) 7440417 4.14E-06 4.14E-04 4.14E-06 2.07E-03 4.14E-06 2.07E- 33 2.10E-08 1,3-Butadiene (H,T) 106990 5.39E-05 5.39E-03 5.39E-05 2.70E-02 5.39E-05 2.70E-02 2.74E-07 Cadmium metal (elemental unreacted) (H,T) 7440439 4.14E-06 4.14E-04 4.14E-06 2.07E-03 4.14E-06 2.07E-03 2.10E-08 Chromic Acid (VI) (H,T) 7738945 4.14E-06 4.14E-04 4.14E-06 2.07E-03 4.14E-06 2.07E-03 2.10E-08 Formaldehyde (H,T) 50000 1.63E-03 1.63E-01 1.63E-03 8.14E-01 1.63E-03 8.14E-01 8.26E-06 Lead unlisted compounds (H) PBC-Other 1.24E-05 1.24E-03 1.24E-05 6.21E-03 1.24E-05 6.21E-03 6.30E-08 Manganese unlisted compounds (H,T) MNC-Other 8.27E-06 8.27E-04 8.27E-06 4.14E-03 8.27E-06 4.14E-03 4.20E-08 Mercury vapor (H,T) 7439976 4.14E-06 4.14E-04 4.14E-06 2.07E-03 4.14E-06 2.07E-03 2.10E-08 Napthalene (H) 91203 1.17E-04 1.17E-02 1.17E-04 5.85E-02 1.17E-04 5.85E-02 5.94E-07 Nickel metal (H,T) 7440020 4.14E-06 4.14E-04 4.14E-06 2.07E-03 4.14E-06 2.07E-03 2.10E-08 Selenium compounds (H) SEC 2.07E-05 2.07E-03 2.07E-05 1.03E-02 2.07E-05 1.03E-02 1.05E-07 Toluene (H,T) 108883 5.64E-04 5.64E-02 5.64E-04 2.82E-01 5.64E-04 2.82E-01 2.86E-06 Xylene (H,T) 1330207 3.93E-04 3.93E-02 3.93E-04 1.97E-01 3.93E-04 1.97E-01 2.00E-06 Highest HAP (Formaldehyde) 50000 1 1.63E-03 1.63E-01 1.63E-03 8.14E-01 1.63E-03 8.14E-01 8.26E-06 Total HAPs 5.29E-03 5.29E-01 5.29E-03 2.600 5E+ 5.29E-03 2.65E+00 TOXIC AIR POLLUTANT EMISSIONS INFORMATION (FOR PERMITTING PURPOSES) EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS EMISSION FACTOR Ib/hp-hr TOXIC AIR POLLUTANT CAS Num. Ib/hr lb/day Ib/yr uncontrolled Acetaldehyde (H,T) 75070 1.06E-03 2.54E-02 5.29E-01 5.37E-06 Acrolein (H,T) 107028 1.28E-04 3.06E-03 6.38E-02 6.48E-07 Arsenic unlisted compounds (H,T) ASC-Other 5.52E-06 1.32E-04 2.76E-03 2.80E-08 Benzene (H,T) 71432 1.29E-03 3.09E-02 6.43E-01 6.53E-06 Benzo(a)pyrene (H,T) 50328 2.59E-07 6.22E-06 1.30E-04 1.32E-09 Beryllium metal (unreacted) (H,T) 7440417 4.14E-06 9.93E-05 2.07E-03 2.10E-08 1,3-Butadiene (H,T) 106990 5.39E-05 1.29E-03 2.70E-02 2.74E-07 Cadmium metal (elemental unreacted) (H,T) 7440439 4.14E-06 9.93E-05 2.07E-03 2.10E-08 soluble chromate compounds, as chromium (VI) E SOLCR6 4.14E-06 9.93E-05 2.07E-03 2.10E-08 Formaldehyde (H,T) 50000 1.63E-03 3.91E-02 8.14E-01 8.26E-06 Manganese unlisted compounds (H,T) MNC-Other 8.27E-06 1.99E-04 4.14E-03 4.20E-08 Mercury vapor (H,T) 7439976 4.14E-06 9.93E-05 2.07E-03 2.10E-08 Nickel metal (H,T) 7440020 4.14E-06 9.93E-05 2.07E-03 2.10E-08 Toluene (H,T) 108883 5.64E-04 1.35E-02 2.82E-01 2.86E-06 Xylene (H,T) 1330207 3.93E-04 9.43E-03 1.97E-01 2.00E-06 DEQ-CFW 00071609