DEQ-CFW_00069073

2015 Emissions Inventory Review / Data Tracking Form
-
Facility Name: Chemours Company - Fayetteville Works Facility Ill: 0900009
Facility
Assigned to:
Bladen County
Confidential Copy Submitted?
Classification:
Gregory Reeves
Title V
A�V YES
❑ NO
Initial Review / Data Entry
Enter date received into ED. Date Received:
Assigned to appropriate individual. Date Assigned: Date Due:
❑ Paper copy submitted: One copy received with supporting documentation, certification form signed by responsible official, and
appears generally complete; OR
Electronic copy submitted: All supporting documentation and certification form (with time/date stamp) signed by responsible
official has been received.
Comments:
Inventory Review
e All forms and supporting documentation appear to be complete if paper submission (check ED OS data if electronic).
p' Contact, address, phone number changes entered into I-Beam/Facilities if necessary.
[9' All known operating scenarios, control devices, and emission release points have been entered for each emission source (permitted,
insignificant, and unpermitted) or note that the emission source was not operated or not required to report.
E'7 Check if SCC codes for each OS are accurate and update if needed.
Evaluate "U" sources for significance and address according to policy.
Calculations / forms appear to add up correctly.
All compliance issues are being addressed (e.g. Toxics limits, above TV thresholds, large emissions increase/decrease, installation
without a permit).
l" All volatile HAPs/TAPS were included in the VOC total.
[E' Calculations and control efficiencies appear correct. Emission factors are the best available and most current factors appropriate
for the reporting facility (e.g. stack testing, AP-42, etc.).
Y, � Review facility comments and address any issues.
J�q%GY Update ED (Data Entry Main) if additional information is required (corrections due date and date received).
lti7' Check all ED QA/QC reports.
M"' Comparison with previous emission inventory must be made and outliers (> 10%) must be investigated and explained.
if"Put inventory review comments and summarize any changes in ED - Data Entry Main "DAQ internal comments".
iPrint and attach the facility total report.
Date Info Requested: Il% Date Info Received: /N R'' Total Days on Hold: _N A
Date Review Complete: (%(r �lG_ Signature:
Date Submitted to EI Coordinator:
Date Approved: &�Z4(t
Initials:
DEQ-CFW 00069073

Facility Total CY 2015 Emission Summary Recorded in ED Facility ID #: 0900009
Facility Name: Chemours Company - Fayetteville Works Permit #(s): 03735T42
Green House Gases Pollutants (GHG)
Pollutant
CAS
Actual Emissions
Tons/Yr
Change
CY 2015
from ED
CY 2014
from Fees
Demini-
mus
Hydrofluorocarbons (HFCs
8.44
HFC
Not
Reported
Not
Reported
N/A
HFC-23 (Trafluoromethane)
75467
8.44
7.23
0.05
16.7%
Carbon Dioxide (CO2)
124389
38,536.26
38,348.44
5,000.0
0.5%
Nitrous Oxide (N20)
10024972
0.072600
0.075700
1.0
-4.1%
Methane (CH4)
74-82-8
0.726000
0.734300
10.0
-1.1%
CO2 equivalent (sum of individual GHG pollutant emission
times their 1995 IPCC Global Warming Potential (GWP),
converted to metric tons)
124,578.53
metric tons
Criteria Pollutants
Pollutant
CAS
Actual Emissions
(Tons/Year)
%
Change
CY 2015
from ED
CY 2014
from Fees
Demini-
mus
CO
Co
42.10
38.10
0.5
10.5%
NOx
Nox
55.45
76.26
0.5
-27.3%
PM(TSP)
TSP
8.94
8.60
0.5
4.0%
PM10
PM10
8.94
8.60
0.5
4.0%
PM2.5
PM2.5
8.94
8.60
0.5
4.0%
S02
SO2
5.50
1.95
0.5
182.1%
VOC
voC
290.39
332.17
0.5
1-12.6-/l.
Hazardous Air Pollutants (HAPs)
and/or Toxic Air Pollutants (TAPS)
Pollutant
CAS
Actual Emissions
(Pounds/Year)
%
Change
CY 2015 CY 2014
from ED from Fees
Demini-
mus
Antimony & Compounds (total mass, inc elemental SB)
0.000000
1 0.000000
10.0
N/A
Antimony Unlisted Compounds - Specify Compounc
(Component of SBC)
SBC-other
0.000000
Not
Reported
10.0
N/A
06/21/2016 Page 1 of 6
DEQ-CFW 00069074

Facility Total CY 2015 Emission Summary Recorded in ED Facility ID #: 0900009
Facility Name: Chemours Company- Fayetteville Works Permit #(s): 03735T42
Hazardous Air Pollutants (HAPs)
Actual Emissions
and/or Toxic Air Pollutants (TAPs)
(Pounds/Year)
CY 2015
from ED
CY 2014
from Fees
Demini-
mus
Pollutant CAS
%
Change
Arsenic & Compounds (total mass of elemental AS, arsine and
0.128060
0.152730
0.01 I
-16.2%
all inorganic compounds)
Arsenic Unlisted Compounds - Specify Compound ASC-Other
0.128060
0.152730
0.01
-16.2%
(Component of ASC)
Beryllium & compounds (Total mass)
0.007730
0.023240
1.0 1-66.7%
Beryllium Metal (unreacted) (Component of BEC) 7440-41-7
0.007730
0.023240
1.0
-66.7%
Beryllium Unlisted Compounds - Specify Compounc BEC-Other
Not
Not
1.0
N/A
(Component of BEC)
Reported
Reported
Cadmium & compounds (total mass includes elemental metal)
0.704230
0.712020
0.1
Cadmium Metal, elemental, unreacted (Component ( 7440-43-9
0.704230
0.712020
0.1
-1.1%
CDC)
Cadmium Unlisted Compounds - Specify Compounc CDC -Other
Not
Not
0.1
N/A
(Component of CDC)
Reported
Reported
Chromium-AlllTotal (includes Chromium (VI) categories,
0.896280
0.901020
0.1
0.5%
metal and others)
Chromic acid (VI) (Component of So1CR6 & CRC) 7738-94-5
0.896280
0.901020
0.01
-0.5%
Chromium Unlisted Compounds - Specify Compoun CRC -Other
Not
Not
0.1
N/A
(Component of CRC)
Reported
Reported
Chromium (VI) Soluble Chromate Compounds (Component of
0.896280
0.901020
0.01
I -0.5%
CRC)
Chromic acid (VI) (Component of So1CR6 & CRC) 7738-94-5
0.896280
0.901020
0.01
-0.5%
Cobalt & compounds
0.053790
0.052800
1.0
11.9%
Cobalt Unlisted Compounds - Specify Compound COC-other
0.053790
0.052800
1.0
1.9%
(Component of COC)
Glycol ethers (total all individual glycol ethers -See
Not
0.000000
100.0
I N/A
http✓/daq.state nc. us/toxics/glycol9
Reported
Glycol Ethers, Unlisted - Specify Compound GLYET-Other
Not
Not
100.0
N/A
(component of GLYET) (See
Reported
Reported
http://daq.state.nc.us/toxics
Lead & compounds
0.060210
1 0.129860
1.01-53.6%
06/21/2016 Page 2 of 6
DEQ-CFW 00069075

Facility Total CY 2015 Emission Summary Recorded in ED Facility ID #: 0900009
Facility Name: Chemours Company - Fayetteville Works Permit #(s): 03735T42
Hazardous Air Pollutants (HAPs)
and/or Toxic Air Pollutants (TAPs)
Pollutant CAS
Actual Emissions
(Pounds/Year)
%
Change
CY 2015
from ED
CY 2014
from Fees
Demini-
mus
Lead Unlisted Compounds - Specify Compound PBC-Other
(Component of PBC)
0.060210
0.129860
10.0
-53.6%
Manganese & compounds
0.243750
0.279520
10.0
r2.8%
Manganese Unlisted Compounds - Specify Compoui MNC-Other
(Component of MNC)
0.243750
0.279520
10.0
-12.8%
Mercury & Compounds - all total mass includes Hg Vapor
0.166510
0.184220
0.001
I -9.6%
Mercury Unlisted Compounds - Specify Compound HGC-Other
(Component of HGC)
Not
Reported
Not
Reported
0.001
N/A
Mercury, vapor (Component of HGC) 7439-97-6
0.166510
0.184220
0.001
-9.6%
Nickel & Compounds, sum total mass includes elemental
1.34
1.34
1.0
10.0%
Nickel metal (Component of NIC) 7440-02-0
1.34
1.34
1.0
0.5%
Nickel Unlisted Compounds (Component of NIC - NIC-Other
Specify)
Not
Reported
Not
Reported
1.0
N/A
Nickel, soluble compounds as nickel (Component of NICKSOLCPDS
NIC)
Not
Reported
Not
Reported
1.0
N/A
Polycyclic Organic Matter (7 PAH Compounds for NIF)
0.000760
0.000750
1.0
I
N/A
Benzo(a)pyrene (Component of 83329/POMTV & 50-32-8
56553/7PAH)
0.000760
0.000750
1.0
N/A
Polycyclic Organic Matter (Specific Compounds from OAQPS
for Tip
0.391130
0.400470
1, 0 I
-2.3 %
Benzo(a)pyrene (Component of 83329/POMTV & 50-32-8
56553/7PAH)
0.000760
0.000750
1.0
N/A
Naphthalene (Component of 83329/POMTV) 91-20-3
0.390370
0.399720
1.0
-2.3%
Total Reduced Sulfur (TRS as total mass)
180.60
180.60
0.0%
Dimethyl sulfide 75-18-3
37.50
37.50
1.0
0.0%
Hydrogen sulfide 7783-06-4
140.00
140.00
1.0
0.0%
Methyl mercaptan 74-93-1
3.10
3.10
1.0
0.0%
Acetaldehyde 75-07-0
0.001830
0.002060
10.0
N/A
06/21/2016 Page 3 of 6
DEQ-CFW 00069076

Facility Total CY 2015 Emission Summary Recorded in ED Facility ID #: 0900009
Facility Name: Chemours Company - Fayetteville Works Permit #(s): 03735T42
Hazardous Air Pollutants (HAPs)
and/or Toxic Air Pollutants (TAPs)
Pollutant CAS
Actual Emissions
(Pounds/Year)
%
Change
CY 2015 iCY
from ED
2014
from Fees
Demini-
mus
Acetic acid 64-19-7
1,008.00
950.00
100.0
6.1%
Acetonitrile 75-05-8
1,839.00
1,859.00
100.0
-1.1%
Acrolein 107-02-8
1.00
1.00
10.0
0.0%
Ammonia (as NH3) 7664-41-7
2,056.70
1,862.80
100.0
10.4%
Benzene 71-43-2
9.34
9.45
1.0
-1.1%
Bromine 7726-95-6
26.00
26.00
10.0
0.0%
CFC- 113 (1,1,2-trichloro-1,2,2-trifluoroethane) 76-13-1
2,305.50
1,354.70
100.0
70.2%
CFC-12 (Dichlorodifluoromethane) 75-71-8
Not
Reported
Not
Reported
100.0
N/A
Chlorine 7782-50-5
1,628.00
1,244.00
100.0 130.9%
Chloroform 67-66-3
1.00
1.00
100.0
0.0%
Dimethyl formamide 68-12-2
Not
Reported
Not
Reported
1.0
N/A
Dioxane, 1,4- 123-91-1
Not
Reported
Not
Reported
0.01
N/A
Ethyl acetate 141-78-6
17.00
17.00
10.0
0.0%
Ethyl benzene 100-41-4
2,540.00
1,446.04
100.0
75.7%
Ethylene dichloride (1,2-dichloroethane) 107-06-2
541.00
541.00
1.0
0.0%
Ethylene glycol 107-21-1
205.00
134.00
100.0
53.0%
Fluorides (sum of all fluoride compounds as mass of 16984-48-8
ion)
2,335.81
2,445.95
10.0
-4.5%
Formaldehyde 50-00-0
48.04
12.87
10.0
1273.2%
Hexamethylene-1,6-diisocyanate 822-06-0
19.00
Not
Reported
1.0
N/A
Hexane, n- 110-54-3
1,248.29
1,226.00
100.0
1.8%
Hydrogen chloride (hydrochloric acid) 7647-01-0
12.60
11.49
100.0
9.7%
Hydrogen fluoride (hydrofluoric acid as mass of HF) 7664-39-3
(Component of 16984488/Fluorides)
2,335.81
2,444.15
100.0
-4.4%
MEK (methyl ethyl ketone, 2-butanone) 78-93-3
1,031.00
586.00
1 100.0
06/21/2016 Page 4 of 6
DEQ-CFW 00069077

Facility Total CY 2015 Emission Summary Recorded in ED Facility ID #: 0900009
Facility Name: Chemours Company - Fayetteville Works Permit #(s): 03735T42
Hazardous Air Pollutants (HAPs)
and/or Toxic Air Pollutants (TAPs)
Pollutant CAS
Actual Emissions
(Pounds/Year)
%
Change
CY 2015
from ED
CY 2014
from Fees
Demini-
mus
Methanol (methyl alcohol) 67-56-1
34,123.00
39,138.00
1,000.fl
1-12.8%
Methyl chloroform 71-55-6
0.000020
0.012010
100.0
-99.8%
Methylene chloride 75-09-2
21,694.00
13,938.00
1.0
55.6%
Nitric acid 7697-37-2
109.00
109.00
100.0
0.0%
Phosphorus Metal, Yellow or White 7723-14-0
Not
Reported
Not
Reported
1.0
N/A
Polycyclic Organic Matter (Inc PAH, dioxins, etc. N pom
& AP 42 historic)
0.000360
0.160170
1.0
1-99.8%
Selenium Compounds SEC
0.015610
0.115160
10.0
1-86.4%
Sulfur trioxide 7446-11-9
0.000000
0.000000
100.0
N/A
Sulfuric acid 7664-93-9
198.10
227.40
100.0
-12.9%
Toluene 108-88-3
3,564.19
2,656.05
100.0
34.2%
Vinylidene chloride 75-35-4
Not
Reported
Not
Reported
0.1
N/A
Xylene (mixed isomers) 1330-20-7
3,835.00
2,500.07
100.0
53.4%
Largest Individual HAP
Methanol (methyl alcohol)
34,123.00 lbs
Total HAP Emissions
3,648.28 lbs
06/21/2016 Page 5 of 6
DEQ-CFW 00069078

DAQ's Comments Regarding Inventory
CO emission increased by 10% due to a 200% increase in production of vinyl ethers. SO2 emission increased due to higher usage of
SO2 in the nafion RSU process. VOC emissions were reduced by 12.6% due to the sale of the Butacite and SentryGlas facilities to
Kuraray, removing these processes from the Chemours permit Arsenic emissions decreased by 16.2%, beryllium metal emissions
decreased by 66.7%, lead emissions decreased 53.6%, manganese emissions decreased by 12.8%, methyl chloroform emissions
decreased by 99.8%, polycyclic organic matter emissions decreased by 99.8%, and selenium emissions decreased by 86.4% due to
the boilers not firing #6 fuel oil during 2015. Ammonia emissions increased 10.4% due to somewhat higher usage of ammonia in th,
wastewater treatment process. CFC-113 emissions increased by 70% due to higher production levels in the Nafion semiworks
process. Chlorine emissions increased by 31% due to higher chlorine usage in the wastewater treatment process. Methanol
emissions decreased 12.8% due to reduction of the amount of wastewater handled during 2015. Methylene Chloride emissions
increased due to more leakage and spills from the Nafion membrane coolant systems. Sulfuric acid emissions decreased by 12.9%
due to decreased production levels in the nafion RSU process and the polymer processing aid process Ethyl Benzene emissions
increased by 76%, ethylene glycol emissions increased by 53%, MEK emissions increased by 75.8%, toluene emissions increased by
34.2%, and xylene emissions increased by 53.4% due to higher paint usage by the maintenance department Formaldehyde
emissions showed an apparent emissions increase of273%, but it appears there was an error in the input of the emissions for 2014
that accounts for this increase.
06/21/2016 Page 6 of 6
DEQ-CFW 00069079

r RECEIVES
JUN 16 2015
UtiNn
FAYETTEVILLE REGIONAL OFFICE
Chemours TM
3
CHEMOURS COMPANY
FAYETTEVILLE WORKS
AIR PERMIT NUMBER 03735T42
FACILITY ID 0900009
2015
AIR
EMISSIONS
INVENTORY
REPORT
l�J
DEQ-CFW 00069080

COPY of RECORD Date Submitted: 6/14/2016 11:34:43
Inventory Certification Form(Title V)
Facility Name: Chemours Company — Fayetteville Works Facility ID : 0900009
22828 NC Highway 87 West Permit: 03735
Fayetteville, NC 28306 County: Bladen
DAQ Region: FRO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory — Calendar Year 2015
These forms must be completed and returned even if the facility did not operate or emissions were zero
The legally defined "Responsible Official" of record for your facility is Ellis McGaughv
This person or one that meets the definition below must sign this certification form.
The official submitting the information must certify that he/she complies with the requirements as specified in i iue I _)ti
NCAC 2Q.0520(b) which references and follows the federal definition. 40 CFR Part 70.2 defines a responsible as meaning one
of the following:
1. For a corporation: a president, secretary, treasurer, or vice—president of the corporation in charge of a principal
business function, or any other person who performs similar policy or decision making functions for the overall
operation of one or more manufacturing, production, or operating facilities applying for a or subject to a permit and
either
i. the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding $25
million(in second quarter 1980 dollars); or
ii. the delegation of authority to such representatives is approved in advance by the permitting authority;
2. For partnership or sole propietorship; a general partner or the proprietor, respectively;
3. for a muncipality, state, federal, or other public agency includes the chief executive officer having responsibility for the
overall operations of a principal geographic unit of the agency (e.g., a Regional Administrator of EPA).
CERTIFICATION STATEMENT
(Important: Legally Responsible Official read and sign after all submissions are fin 1
certify that I am the responsible official for this facility, as described above, and hereby certify that the information contained
in this air emissions report, including attached calculations and documentation, is true, accurate and complete. (Subject to legal
enalities of up to $25,000 per occurrence and possible imprisonment as outlined in G.S.§ 143-215.3(a)(2))
Responsible Official's Signature Below use blue ink): Date Signed: 4Z o
Printed Name: Ellis McGaughy 0&1
Sign e:
This form applies to Title V facilities. If thisV,*ility s not classified as Title V, please telephone your regional office Emission
Inventory contact at once for proper forms.
RECEIVED
Email address of Responsible Official:
[e-mail] JUN 16 2016
ULIVh
FAYETfEVILLE REGIONAL OFFICE
Information on this Form cannot be held confidential
COPY of RECORD Date Submitted: 6/14/2016 11:34:43
DEQ-CFW 00069081

•
Wastewater Sludge Dryers
(Title V ID Nos. WTS-B and WTS-C)
(AERO ID G-42)
•
•
DEQ-CFW 00069082

Y'
1
WWTP Sludge Dryers Air Emissions Inventory1 h Page 1 of 2
Supportin2 Documentation for WWTP Slud e Dryers (WTS-B and WTS-C
The Specific Conditions for the Impingement Type Wet Scrubber (ID No. WTCD-1) is discussed
in Part 1 Section 2.1(E) of the site's Title V Air Permit. The Permit states that the scrubber is to
control the "odorous emissions from the wastewater treatment sludge dryers (Nos. WTC-B and
WTS-C)."
Major categories of offensive odors from the drying of activated sludge could generally be
grouped into the following:
Odor Category
Common Chemical in
Odor Category
Odor Threshold of
Common Chemical
( mv)
Amines
Methyl amine
0.021
Ammonia
Ammonia
1.5
Hydrogen sulfide
Hydrogen sulfide
0.13
Merca tans
Methyl merca tan
0.002
Organic sulfides
Dimethyl sulfide
0.001
Skatole
3-Methyl-1 H-indole
0.019
Based on the lack of odors coming from the discharge of the WWTP Sludge Dryer scrubber, and
the low odor threshold of the possible odorous compounds coming from the scrubber, it is
believed that only an insignificant amount of VOCs could be emitted from this source.
To quantify the worst -case scenario, it will be assumed that the scrubber is running continuously
during the entire year with the above compounds being vented at their odor threshold
concentration. This is an obvious overstatement of actual emissions since the WWTP Scrubber
normally operates with no detectable odors.
Conversion of concentration expressed as ppmv to mg/m3 is via the following equation:
mg _ ppmv x 12.187 x Molecular Weight
m3 (273.15 + Temperature)-C
For the purpose of this concentration conversion, it will be assumed that the actual scrubber
discharge temperature is a constant 27 'C. Therefore, the above equation reduces to:
mg in = 0.0406 x ppmv x Molecular Weight
For example, converting 0.021 ppmv of methyl amine (MW = 31) to mg/m3 follows:
0.0406 x 0.021 my x 31 grams = 0.026 mg
pp mole In
DEQ-CFW 00069083

W WTP Sludge Dryers
Air Emissions Inventory
Page 2 of 2
u
•
•
•
Conversion of concentration from ppmv to mg/m3
Compound
Molecular
Weight
(grams per mole
Odor Threshold
(ppmv)
Odor Threshold
(mg/m3)
Methyl amine
31
0.021
0.026
Ammonia
17
1.5
1.035
Hydrogen sulfide
34
0.13
0.179
Methyl mercaptan
48
0.002
0.004
Dimethyl sulfide
62
0.001
0.048
3-Methyl-lH-indole
131
0.019
0.101
Scrubber (ID No. WTCD-3) design air flow rate is 23,850 cubic feet per minute.
This flow rate is converted to cubic meters per year by the following:
ft 3 3min 3
23,850 min x 0.0283 ft3 x 60 x 8,760 hr = 354,756,350 In
hr yr yr
Emissions Determination:
Multiplied by:
Multiplied by:
Equals:
Compound
Odor
Threshold
(mg/m3)
Scrubber
Flow Rate
(m3/yr)
Mass
Conversion
(lb/mg)
Emission
Rate
(lb/yr)
Methyl amine
0.026
354,756,350
2.2046 x 10"6
20.3
Ammonia (Note 1)
1.035
354,756,350
2.2046 x 10-6
809.5
Hydrogen sulfide (Note 1)
0.179
354,756,350
2.2046 x 10-6
140.0
Methyl mercaptan (Note 1)
0.004
354,756,350
2.2046 x 10-6
3.1
Dimethyl sulfide (Note 1)
0.048
354,756,350
2.2046 x 10-6
37.5
3-Methyl-lH-indole
0.101
354,756,350
2.2046 x 10-6
79.0
Note 1: These compounds are listed as HAPs and/or TAPS
VOC Emissions Determination:
Methyl amine
20.3 lb/yr
Methyl mercaptan
3.1 lb/yr
Dimethyl sulfide
37.5 lb/yr
3-Methyl-IH-indole
79.0 lb/yr
Total VOC
139.9 lb/yr
Total VOC
0.07 TPY
DEQ-CFW 00069084

•
Polymer Processing Aid Process
AS -A
•
•
DEQ-CFW 00069085

•
•
2015 AIR EMISSIONS SUMMARY
POLYMER PROCESSING AID PROCESS
VOC Emisions
Ib/yr
FRD901
0.3
Dimer
28.2
Dimer Acid
4.1
Total VOC emissions Ib/ r
32.6
Total VOC emissions ton/ r
0.02
Particulate (PM) Emisions Iblyr
FRD902 2.5
Total PM emissions Ib/ r 2.5
Total PM emissions (ton/yr) 0.001
Toxic Air Pollutant (TAP) Emisions
lb/yr
Ammonia
61.7
HF
3.8
H2SO4
45.8
Note: NCDAQ requires that Acid Fluorides be reported as
"Fluorides" as well as HF.
DEQ-CFW 00069086

Ammonia (NH3)
Definitions
Assumptions
PT= Total Pressure
Ideal Gas Laws apply and all solutions are
VP; = Vapor Pressure of Component i
considered Ideal Solutions
P; = Partial Pressure of Component i
Vapor Pressure is constant over temperature
X; = Mole Fraction of Component i in the Liquid
range. Value used is for worst case ie. max
Y; = Mole Fraction of Component i in the Vapor
ambient temp (90 F) from Tanner Industries table
for Aqua Ammonia
K; = Henry's Law Constant
Constants
Conversions
Molecular Weight of NH3 17
1 gallon = 3.785 liters = 3,785 cm3 = 231 in
Molecular Weight of Water 18
1 atm = 760 mm Hg = 14.7 psi
Molecular Weight of pure 902 347
1 lb = 454 grams
VP of 19% solution [mm Hg] 382
1 ft3 =28.3 liters
Specific Gravity of 19% solution 0.94
Specific Gravity of 70% 902 1.47
Density of Water [g/cm3] 0.995
KNH3 [atm] 0.95
Leak Rates fib/hour] (using "Good" factor for DuPont facilities)
Pump Seals 0.00750
Valves 0.00352
Flanges 0.00031
Equations
P;=X;*K; Henry's Law (used for dilute solutions)
P;=X;*Vpi Raoult's Law
Y; = P;/PT
Assumptions & Notes
Tote Filling
Tote is filled from 55 gallon drums and
Number of drums added to tote during fill 4
displaced vapors exit into atmosphere
Total vapor displaced during fill [liters] 832.7
Number of fills per year 88
Total vapor displaced during year [liters] 73,278
PNH3 (mm Hg] 64.097
YNH3 0.08434
Total NH3 vapor displaced during year[literi, 6180.1
Total NH3 vapor displaced during year [Ibs] 10.3309
902 Reactor Charging
Number of batches per year 328
Average pump run time per batch (min) 30
Line is liquid -filled during entire charging
Number of flanges in line 15
time and empty during non -charging time
Number of open valves in line 4
Number of pump seals (air diaphragm) 0
Total pump time for year [hours] 164
Total fugitive emmisions jibs] 3.0717
PPA - NH3 - Page 1 of 2
DEQ-CFW 00069087

•
905 Reactor Charging
Number of batches per year
Average drop time per batch (min)
Number of flanges in line
Number of open valves in line
Number of pump seals (air diaphragm)
Total drop time for year [hours]
Total fugitive emmisions [Ibs]
902 Reactor Emissions
Vessel Capacity [gal]
Additions between fallout
Avg. 903 addition from Rec Tk [Ibs]
% 903 in Addition
Total 903 addition [Ibs]
Water Charge from 903 [Ibs]
19% Ammonia Charge [Ibs]
Vapor space of 902 Reactor minus heel,
% Ammonia after Dilution
VP after dilution [mm Hg]
Moles of. 902
Moles of Water
Moles of NH3
XNH3
PNH3 [mm Hg]
PNH3
Total NH3 vapor to scrubber [lb mol/batch]
Total NH3 vapor to scrubber [Ibs/batch]
Total NH3 vapor to Scrubber [Ibs/year]
Assumed Efficiency of Scrubber
Ammonia exiting Stack [lbs/year]
18
360
15
10
0
108
13.8024
1,000
3
1,800
90%
4,860
486
1,215.00
390.33
0.035
90
1271.72
110,322
6,165
0.05235
37.7990
0.04974
0.00619
0.10528
34.5307
0
34.5307
Total Ammonia Emissions jibs/year] 1 61.7
Ammonia gas, through vapor pressure,
fills entire available vapor space of
Reactor. This entire volume is then vented
to the Scrubber before 903 is charged and
reaction to 902 instantly occurs.
Ammonia VP is reduced after dilution.
Value used is from table for 2% at
standard operating temp (100F)
0.019 psi / mm Hg
10.73 - gas constant in ft3 psi / OR lb mole
7.48 gal / ft3
PPA - NH3 - Page 2 of 2
DEQ-CFW 00069088

•
•
•
Sulfuric Acid (H2SO4)
Constants
Molecular Weight of H2SO4 98.1 Leak Rates [lb/hour]
Molecular Weight of Water 18 Pump Seals
VP of Sulfuric [mm Hg] 0.01 Valves
KH2so4 [atm] -> 0 [atm] therefore Raoult's Law will only be used Flanges
Sulfuric Acid Storage Tank Filling
Average fill size [gallons] 3000
Number of fills per year 7
Total vapor displaced during year [liters] 79485
PH2so4 [mm Hg] 0.00986
YH2504 1.298E-05
Total H2SO4 vapor displaced during year [liters] 1.03161
Total H2SO4 vapor displaced during year [Ibs] 0.00995
Good
Excellent
0.0075
0.00115
0.00352
0.00036
0.00031
0.00018
Assumptions & Notes
Oleum Storage Tank contains no flanges/valves below
liquid line and because the VP of H2SO4 is so low,
any vapor leaks out of flanges above liquid line are
negligible as well as vapor losses to Scrubber during
Oleum Storage Tank filling and hose blow -down.
H2SO4 Storage Tank Emmisions
Because Sulfuric has such a low VP, leaks out of
Avg time vessel is inventoried [days/yr]
335
vessel above the liquid line are negligible
Number of vessel flanges (below inventory line)
4
Number of open valves (below inventory line)
1
Fugitive H2SO4 emissions [Ibs/year]
38.2704
Hydrolysis Reactor Charging
Number acid
328
of charges per year
Average pump run time per batch (min)
15
Line is liquid -filled during entire charging time and
Number of flanges in line
25
empty during non -charging time
Number of open valves in line
9
Number of pump seals
1
Total pump time for year [hours]
82
Total fugitive emmisions [Ibs]
3.84826
Hydrolysis Reactor Emissions
Vessel capacity [gal]
600
Worst Case - liquid molar ratio of H2SO4 at time of
Hydro Reactor Charge of water [Ibs]
2000
venting is same as initial charge
Hydro Reactor Charge of H2SO4 [Ibs]
590
Avg pressure at time of vent = atmosphere
Batches per year
9841
Entire available head space is vented to the Scrubber
Avg Level of Vessel at Vent [gallons]
490
XH2so4
0.59431
PH2so4 [mm Hg]
0.00594
YH2so4
7.820E-06
0.019 psi / mm Hg
H2SO4 vapor vented to Scrubber [Ib mol/batch]
2.744E-07
10.73 - gas constant in ft3 psi / °R lb mole
H2SO4 vapor vented to Scrubber [Ibs/year]
0.026488
7.48 gal / ft3
Assumed Efficiency of Scrubber
0.95
H2SO4 exiting Stack [Ibs/year]
0.001324
Avg time vessel is inventoried [days/yr]
335
Closed valves and instruments connections
Number of vessel flanges (below inventory line)
7
considered flanges
Number of open valves (below inventory line)
0
Because Sulfuric has such a low VP, leaks out of
Fugitive H2SO4 emissions [Ibs/year]
3.66383
vessel above the liquid line are negligible
PPA - H2SO4 - Page 1 of 2
DEQ-CFW 00069089

U
Dilution Tank Emissions (Mix and Settle)
Vessel capacity [gal]
1,963
Avg Level of Vessel at Vent [gallons]
1 800
Batches per year
0
Mass fraction of H2SO4
0.2
Pressure of Vessel at Vent [mm Hg]
760
XH2so4
0.57672
PH2so4 [mm Hg]
0.00577
YH2so4
7.588E-06
H2SO4 vapor vented to Scrubber [liters/batch]
0.03340
H2SO4 vapor vented to Scrubber [Ibs/year]
0.00000
Assumed Efficiency of Scrubber
0.95
H2SO4 exiting Stack [Ibs/year]
0.00000
Dilution Trailer Loadout Emissions
Number of transfers per year 00
Average pump run time per transfer (min) 60
Number of flanges in line 30
Number of open valves in line 11
Number of pump seals 1
Total pump time for year [hours] 0
Total fugitive emmisions [Ibs] 0.00000
Total H2SO4 Emissions [Ibs/year] 45 8
Entire available head space is vented to the Scrubber
Line is liquid -filled during entire charging time and
empty during non -charging time
PPA - H2SO4 - Page 2 of 2
DEQ-CFW 00069090

Hydrofluoric Acid (HF)
Equipment Leak Rates jib/hr]
Molecular Weight of HF
20
Good Excellent
Molecular Weight of DAF
332
Pump Seal 0.0075 0.00115
Molecular Weight of H2SO4
98.1
Valves O.00352 0.00036
Molecular Weight of Dimer Acid
330
Flanges 0.00031 0.00018
Molecular Weight of Water
18
VP at 600C [mm Hg]
2
KHF
0.006
Hydrolysis Reactor Emissions
Assumptions & Notes
Vessel capacity [gal]
600
Worst Case -100% conversion
Water Charge [Ibs]
2040
resulting in maximum HF
93% Sulfuric Charge [Ibs]
600
generation
DAF Charge [Ibs]
1700
HF (post reaction) [Ibs]
102.41
VP listed is for 10% solution
Dimer Acid (post reaction) [Ibs]
1689.76
which is an over -estimation.
Water (post reaction) [Ibs]
1947.83
Sulfuric (post reaction) [Ibs]
600
Avg Level of Vessel at Vent [gal]
490
Gas Constant
Mass Fraction of HF
0.0236
10.73 ft3 psi / °R lb mol
XHF
0.0411
0.019 psi / mmHg
PHF (mm Hg]
0.1874
7.48 gal / ft3
YHF
0.000247
HF vapor vented to Scrubber [lb mol/batch]
8.65E-06
HF vapor vented to Scrubber [Ibs/year]
0.0479
Because HF has a low VP, leaks
Assumed Efficiency of Scrubber
0.95
out of vessel above the liquid line
HF exiting Stack [Ibs/year]
0.00240
are negligible
Avg time vessel contains Virgin material [days/yr]
150
Emissions from Dilution Tank are
Number of vessel flanges (below inventory line)
7
negligible based on the
Number of open valves (below inventory line)
0
concentration, time in vessel, and
Fugitive HF emissions [Ibs/year]
2.093
VP of HF
Trailer Loadout Emissions
Number of transfers per year
L0
Average pump run time per transfer (min)
60
Number of flanges in line
30
Accounting for Hydrolysis of DAF
Number of open valves in line
11
in the atmoshpere into FRD903
Number of pump seals
1
which releases HF on a one mole
Total pump time for year [hours]
0
to one mole basis
Total fugitive emmisions [Ibs]
0.00000
Emissions based on DAF 1.699
Total HF Emissions jibs/year] 3.s
•
PPA - HF - Page 1 of 1
DEQ-CFW 00069091

J
9 Perfluoro-2-Propoxy Propionyl Fluoride (W1202) (Dimer)
Emissons based on data collected during stack testing in 2006.
Virgin Campaign Emission Rate [Ibs/hr]
Amount of Annual Time dedicated to FRD Production [fraction]
Fraction of Emissions that are Dimer
Total DAF Emissions [Ibs/year]
Assumptions & Notes
Note 1
0.008 Note 2
0.47
0.85626 Note 3
28.2
Note 1 Calculations will be based on the air emissions conducted for the combined
PFOF,PFOA, and APFO molecules noting that this Dimer molecule will be
modeled as the PFOF molecule.
Note 2 Emission Rates are based on previously conducted stack testing and
represent the combined output of PFOF, PFOA, and APFO.
0 Note 3 Based on 2006 analysis.
•
PPA - Dimer - Page 1 of 1
DEQ-CFW 00069092

Ol
Perfluoro-2-Propoxy Propionic Acid (C617,1031-1) (Dimer Acid GX903)
•
Emissons based on data collected during stack testing in 2006. Note 1
Virgin Campaign Emission Rate [Ibs/hr] 0.008 Note 2
Purified Campaign Emission Rate [Ibs/hr] 0.0024
Amount of Annual Time dedicated to GX Virgin Production [fraction] 0.47
Amount of Annual Time dedicated to GX Purified Production [fraction] 0.10
Fraction of Emissions that are Dimer Acid 0.0896 Note 3
Total Dimer Acid Emissions [Ibs/year] 4.1
Assumptions & Notes
Note 1 Calculations will be based on the air emissions conducted for the combined
PFOF,PFOA, and APFO molecules noting that this Dimer molecule will be modeled
as the PFOF molecule.
Note 2 Emission Rates are based on previously conducted stack testing and represent the
Note 3 Based on 2006 analysis.
PPA - Dimer Acid - Page 1 of 1
DEQ-CFW 00069093

X
FRD901
Definitions
PT= Total Pressure
VP; = Vapor Pressure of Component i
P; = Partial Pressure of Component i
X; = Mole Fraction of Component i in the Liquid
Y; _ Mole Fraction of Component i in the Vapor
K; = Henry's Law Constant
Constants
Molecular Weight of FRD901: 1533
Equipment Leak Rates [lb/hr] (using "Good" factor)
Pump Seals 0.00750
Valves 0,00352
Flanges 0.00031
Equations
P;=X;*K; Henry's Law (used for dilute solutions)
P;=X;*Vpi Raoult's Law
Y;=P;-PT
Assumptions
Ideal Gas Laws apply and all solutions are
considered Ideal Solutions
Vapor Pressure is constant over
temperature range. Value used is for worst
case ie. max ambient temp (90 F)
Conversions
1 gallon = 3.785 liters = 3,785 cm3 = 231 in
1 atm = 760 mm Hg = 14.7 psi
1 lb = 454 grams
1 ft3 =28.3 liters
Assumptions & Notes
Tote is filled from 14 gallon drums and
displaced vapors exit into atmosphere
Line is liquid -filled during entire charging
time and empty during non -charging time
FRD901 Tank Filling
Number of drums added to tote during fill
2
Total vapor displaced during fill [liters]
Number of fills per year
105.98
14
Total vapor displaced during year [liters]
1,484
P901(mm Hg]
0.004
Y901
0.00000
Total 901 vapor displaced during year[liters]
0.0071
Total 901 vapor displaced during year [Ibs]
0.0011
Average pump run time per batch (min)
10
Number of flanges in line
10
Number of open valves in line
2
Number of pump seals (air diaphragm)
1
Total pump time for year [hours]
4.7
Total fugitive emmisions [Ibs]
0.0834
901 Reactor Charging
Number of batches per year
18
Average drop time per batch (min)
45
Number of flanges in line
6`
Number of open valves in line
4
Number of pump seals (air diaphragm)
0
Total drop time for year [hours]
13.5
Total fugitive emmisions [Ibs]
0.2152
Total FRD901 Emissions (lb/year] 1 0.3
•
PPA - FRD901 - Page 1 of 1
DEQ-CFW 00069094

0 Propanoic acid, 2,3,3,3-tetrafluoro-2-(heptafluoropropoxy)-, ammonium salt (GX902)
I ]l
Emissons based on data collected during stack testing in 2006.
Note 1
Virgin Campaign Emission Rate [Ibs/hr]
0.008 Note 2
Purified Campaign Emission Rate [Ibs/hr]
0.0024
Amount of Annual Time dedicated to GX Virgin Production [fraction]
0.47
Amount of Annual Time dedicated to GX Purified Production [fraction]
1 0.10
Fraction of Emissions that are GX902
0.05413 Note 3
Total GX902 Emissions [lb/year] 2.5
Assumptions & Notes
Note 1 Calculations will be based on the air emissions conducted for the combined
PFOF,PFOA, and APFO molecules noting that this Dimer molecule will be
modeled as the PFOF molecule.
Note 2 Emission Rates are based on previously conducted stack testing and
represent the combined output of PFOF, PFOA, and APFO.
Note 3 Based on 2006 analysis.
PPA - FRD902 - Page 1 of 1
DEQ-CFW 00069095

�1
Polyvinyl Fluoride Process No. 1
FS-B
•
•
DEQ-CFW 00069096

•
0
•
AIR EMISSIONS INVENTORY SUPPORTING DOCUMENTATION
Emission Source ID No.:
Emission Source Description:
Process a
FS-B
Polyvinyl Fluoride Process No. 1
nd Emission Description:
The PVF process is a continuous manufacturing process. All emissions from this
process vent to the atmosphere, some via a vertical stack. The calculation of emissions
of VOCs will be addressed in the attached spreadsheet.
Basis and Assumptions:
FEP-131 (Analytical Equipment) emissions are calculated using the flowmeters feeding
the analyzers and the rotometers in the GC bypass loops (which are not routinely valved
to the stack).
FEP-132 (Maintenance Header) is only in operation when equipment is vented for
maintance. A flowmeter is installed immediately upstream of the VF Dispersion Stack.
Procedure requires the line to be purged with N2, then vent VF and then purged with N2
at least 3 times to remove low concentrations of VF. After maintenance air is removed
by purging the equipment with N2 an additional 3 times (min). In July of 2011, a
densitometer was installed, calibrated and verified. The densitometer accurately
measures the percent of VF in the gas leaving via the maintenance vent header, giving
an accurate emission total for that source. The year's Maintenance Header emissions
FEP-133 (Flash Tank) emissions are based on the operating pressure, temperature, and
flow through the Low Pressure Slurry Separator. It is assumed that if VF Flow to the
PVF reactor is less than 1000 pph, then there is no VF leaving the Flash Tank.
FEP-134 (Product Collection System) emissions are based on the operating time and
production rate of the baghouse and the bag efficiency. According to the manufacturer,
W.L. Gore, the Baghouse bags have a 99.97% efficiency rating on 0.3 micron
particulate. We don't expect to have any particles smaller than that, so emissions will
be 0.488 lb. PVF particulate emission per Polymer Production Unit (PPU).
Information Inputs and Source of Info.:
Point Source Emissions Determination:
Equipme
IP.21 and rotometers:
Point source emissions for individual components are given in the attached
spreadsheet.
nt Emissions and Yugitive Emissionsyetermmation:
Emissions from equipment leaks will be individually indentified. True fugitive (non -point
(source) emissions have been determined using equipment component emission factors
established by DuPont. The determination of those emissions are shown in a separate
section of this supporting documentation.
DEQ-CFW 00069097

PVF-1 Process VOC Determination (Emission Source ID Nos. FS-B)
Year 2015
Analytical Equipment Vent Flow Rates
Vent No. FEP-131 flow rate (QFEP_Bl)
Analytical Equipment VOC emissions (EFEP-Bi)
Maintenance Header Vent Flow Rates
Vent No. FEP-132 flow rate (QFEP_B2)
Maintenance Headers VOC emissions (EFEP_B2)
Flash Tank Vent Flow Rates
Emissions from Vent No. FEP-B3 flow rate (QFEP_B3)
Flash Tanks VOC emissions (EFEP-B3)
Fugitive Emissions
Fugitive emissions from FS-B (EF_B)
Total fugitive emissions (EF)
Accidental Releases
Accidental releases from FS-B (QA_B)
Total accidental releases (EA)
VOC emissions (E) from the PVF-1 facility
Analytical Equipment VOC emissions (EFEP_BI)
Maintenance Headers VOC emissions (EFEP_s2)
Flash Tanks VOC emissions (EFEP_B3)
Total fugitive emissions (EF)
Total accidental releases (EA)
Total VOC emissions (E) from the PVF-1 facility
* Note: VOC emissions are exclusively vinyl fluoride
4,338 pounds
4,338 pounds
40,777 pounds
40,777 pounds
3,613 pounds
3,613 pounds
1,886 pounds
1,886 1pounds
1 pounds
1 pounds
4,338
po
po
po
po
po
po
to
40,777
3,613
1,886
1
60,616
26.31
unds
unds
unds
unds
unds
unds
is
DEQ-CFW 00069098

0
•
0
PVF-1 Process PM Determination (Emission Source ID Nos. FS-B)
Year 2015
Basis and Assumptions:
FEP-64 (Product Collection System) emissions are based on the operating time and
production rate of the baghouse and the bag efficiency. According to the manufacturer,
W.L. Gore, the Baghouse bags efficiency rating on 0.3 micron particulate indicates the
potential particulate emissions would be 0.488 lb. particulate matter ("PM") per Polymer
Production Unit ("PPU°). It is not expected that any particles would be smaller than 0.3
micron.
Determination of Particulate Matter Emissions
Production during reporting year
PM Emission Factor
Total PM emissions from the PVF-1 facility
3,418
JPPU
0.488
lb -PM / PPU
1,669
pounds
0.83
tons
DEQ-CFW 00069099

Polyvinyl Fluoride Process No. 2
FS-C
•
•
DEQ-CFW 00069100

•
•
•
AIR EMISSIONS INVENTORY SUPPORTING DOCUMENTATION
Emission Source ID No.:
Emission Source Description:
Process a
FS-C
Polyvinyl Fluoride Process No. 2
nd Emission Description:
The PVF process is a continuous manufacturing process. All emissions from this
process vent to the atmosphere, some via a vertical stack. The calculation of emissions
of VOCs will be addressed in the attached spreadsheet.
Basis and Assumptions:
FEP-C1 (Analytical Equipment) emissions are calculated using the flowmeters feeding
the analyzers and the rotometers in the GC bypass loops (which are not routinely valved
to the stack).
FEP-C2 (Maintenance Header) is only in operation when equipment is vented for
maintance. A flowmeter is installed immediately upstream of the VF Dispersion Stack.
Procedure requires the line to be purged with N2, then vent VF and then purged with N2
at least 3 times to remove low concentrations of VF. After maintenance air is removed
by purging the equipment with N2 an additional 3 times (min). It is therefore
conservatively assumed that 50% of the flow is VOC (VF or Propylene) when
densitometer data is not available (January -April). In May of 2012, a densitometer was
installed, calibrated and verified. The densitometer accurately measures the percent of
VF in the gas leaving via the maintenance vent header, giving an accurate emission
total for that source. The year's Maintenance Header emissions are calculated using
data from the densitometer from May through December and in January through April,
50% of the flow was assumed to be VOC.
FEP-C3 (Flash Tank) emissions are based on the operating pressure, temperature, and
flow through the Low Pressure Slurry Separator. It is assumed that if VF Flow to the
PVF reactor is less than 1000 pph, then there is no VF leaving the Flash Tank.
FEP-C4 (Product Collection System) emissions are based on the operating time and
production rate of the baghouse and the bag efficiency. According to the manufacturer,
W.L. Gore, the Baghouse bags have a 99.97% efficiency rating on 0.3 micron
particulate. We don't expect to have any particles smaller than that, so emissions will
be 0.488 lb. PVF particulate emission per Polymer Production Unit (PPU).
Information Inputs and Source of Info.:
Point Source Emissions Determination:
Equipme
IP.21 and rotometers.
Point source emissions for individual components are given in the attached
spreadsheet.
nt Emissions and -Fugitive Emissions Determination:
'Emissions from equipment leaks will be individually indentified. True fugitive (non -point
source) emissions have been determined using equipment component emission factors
established by DuPont. The determination of those emissions are shown in a separate
isection of this supporting documentation.
DEQ-CFW 00069101

•
•
•
PVF-2 Process VOC Determination (Emission Source ID Nos. FS-C)
Year 2015
Analytical Equipment Vent Flow Rates
Vent No. FEP-Cl flow rate (QFEP_c1) 1,802 pounds
Analytical Equipment VOC emissions (EFEP_cl) 1,802 pounds
Maintenance Header Vent Flow Rates
Vent No. FEP-C2 flow rate (QFEP_C2) 19,438 1pounds
Maintenance Headers VOC emissions (EFEP-c2) 19,438 pounds
Flash Tank Vent Flow Rates
Emissions from Vent No. FEP-C3 flow rate (QFEP_C3) 2,824 pounds
Flash Tanks VOC emissions (EFEP-C3) 2,824 pounds
Fugitive Emissions
Fugitive emissions from FS-C (EF_C) 1,886 pounds
Total fugitive emissions (EF) 1,886 pounds
Accidental Releases
Accidental releases from FS-C (QA_c) 0 pounds
Total accidental releases (EA) 0 pounds
VOC emissions (E) from the PVF-2 facility
Analytical Equipment VOC emissions (EFEP-cl)
Maintenance Headers VOC emissions (EFEP_c2)
Flash Tanks VOC emissions (EFEP-C3)
Total fugitive emissions (EF)
Total accidental releases (EA)
Total VOC emissions (E) from the PVF-2 facility
* Note: VOC emissions are exclusively vinyl fluoride
1,802
19,438
2,824
1,886
X
25,950
12.98
pounds
pounds
pounds
pounds
pounds
pounds
tons
DEQ-CFW 00069102

V
PVF-2 Process PM Determination (Emission Source ID Nos. FS-C)
Year 2015
Basis and Assumptions:
FEP-C4 (Product Collection System) emissions are based on the operating time and
production rate of the baghouse and the bag efficiency. According to the manufacturer,
W.L. Gore, the Baghouse bags efficiency rating on 0.3 micron particulate indicates the
potential particulate emissions would be 0.488 lb. particulate matter (" PM") per Polymer
Production Unit ("PPU"). It is not expected that any particles would be smaller than 0.3
micron.
Determination of Particulate Matter Emissions
Production during reporting year 3,202 PPU
PM Emission Factor 0.488 Ib-PM / PPU
Total PM emissions from the PVF-2 facility 1,564 pounds
0.78 tons
Completed By: Christopher A. Chanelli
Date Completed: January 25, 2016
•
DEQ-CFW 00069103

�J
HFA-Hydrate Reactor System
GHG-HDR
•
•
DEQ-CFW 00069104

•
•
2015 Air Emissions Inventory Supporting Documentation
Emission Source ID No.: GHG-HDR
Emission Source Description: HFA-Hydrate Destruction Reactor System
Process and Emission Description:
The HFA-Hydrate Destruction Reactor System (HDR) consists of a thermal -alkaline
reactor that decomposes HFA-hydrate to trifluoromethane (HFC-23 or fluoroform) and
trifluoroacetate. The trifluoroacetate is water soluble and leaves the HDR system in the
wastewater stream. The HFC-23 is vented to the atmosphere via the Nafion® Process'
main vent stack (NEP-1).
HFC-23 is not a VOC, HAP, or North Carolina TAP. As such, HFC-23 is not a regulated
air pollutant. Because of this, the HDR is not listed on the site's Title V Air Permit.
Therefore, for the purpose of this report, HFC-23 is reported as a greenhouse gas emission.
Basis and Assumptions:
The basis of the HFC-23 emissions is the formation of HFA-hydrate in the HFPO Process.
In the HDR system, the HFA-hydrate is chemically decomposed to HFC-23. Per the HFPO
Process flowsheet (W1208078), 0.4 kg of HFC-23 is formed and emitted for every 30.48
HFP Units fed into the HFPO Process. Therefore, the emission of HFC-23 is proportional
to the quantity of HFP make-up fed to the HFPO Process. Vent testing of the HFPO
Process has established the HFC-23 emission factor for that process. Therefore the
emissions of the HFC-23 from the HDR system is simply the difference between the total
HFC-23 emissions and the HFPO Process' HFC-23 emissions.
Information Inputs and Source of Inputs:
Information Inputs
Source of Inputs
HFPO Process' fresh HFP make-up
quantity
SAP financial records
Point Source Emissions Determination:
All air emissions from the HDR system are point source. The estimate of the emission of
fluoroform (HFC-23) is given on the following page.
DEQ-CFW 00069105

•
E
HFA-Hydrate Destruction Reactor System
A. Trifluoromethane (CHF3; fluoroform; HFC-23; R-23)
Quantity Generated:
Before -control CHF3 generation per the process flowsheet (W1208078):
0.4 kg CHF3
30.48 HFP Units
Page 1 of 1
CAS No. 75-46-7
Before -control CHF3 generation based on 583,653 HFP Units
0.4 kg CHF3 x 583,653 HFP Units = 7,658 kg CHF3
30.48 HFP Units
16,884 lb. CHF3
The amount of CF3H emitted from the HFPO Process is based on the before -control CHF3
emissions factor documented in TA NF-11-1824 from the stripper column vent.
ECF3H= 0.0114 kg CHF3 / HFP Units fed to process
Therefore the amount emitted from the HFPO process is:
0.0114 kg CHF3 x 583,653 HFP Units = 6,672 kg CHF3
1.00 HFP Units
14,709 lb. CHF3
Therefore the quantity of trifluoromethane emitted from the HFA-hydrate Destruction Reactor
System (GHG-HDR) would be the difference between the total CHF3 emissions and the quantity
emitted from the HFPO Process (NS-A).
16,884 lb. CHF3 minus 14,709 lb. CHF3
= 2,175 lb. CHF3
= 1.09 ton CF3H
DEQ-CFW 00069106

Polyvinyl Fluoride Process No. 1 House Vacuum System
I-01 A
•
•
DEQ-CFW 00069107

PVF-1 House Vacuum System (I-01A)
Page 1 of 2
DuPont PVF Manufacturing Facility
Determination of Actual PM-10 Emissions: PVF-1 House Vacuum System
Particulate Matter Emissions Determination
For general good housekeeping purposes, the DuPont PVF-1 Process uses a vacuum system
(ID No. PVF-Vac-A) to remove any PVF resin powder (particulate matter) from the building's
floor and equipment. The emission of particulate matter from this vacuum system is
controlled by a two -stage fabric filter.
The 1st -stage fabric filter (Control Device ID No. CD-PVF-Al) is a TDC Filter QX blended
cellulous / synthetic fiber paper filter. Its efficiency for capturing / controlling particles is 48%
for 0.3 - 1.0 micron size, 88% for 1.0 - 3.0 micron size, and 99% for 3.0 - 10.0 micron size.
The 2nd-stage fabric filter (Control Device ID No. CD-PVF-A2) is a TDC Filter SB-ME
heavy-duty spunbond 100% polyester metalized spunbond filter media with a conductive
coating to prevent static buildup. Its MERV Test results shows the filter's efficiency for
capturing / controlling particles is 38% for 0.3 - 1.0 micron size, 72% for 1.0 - 3.0 micron
size, and 98% for 3.0 - 10.0 micron size.
Determination of before -control particulate matter is based on the conservative estimate of
8,160 lb/yr collected from the 1st -stage filter, the capture efficiencies of that filter, and the
particle size distribution of the PVF resin powder.
Results of particle size distribution testing of batches of PVF resin powder during August
through October 2013 showed the worst -case situation of 68% being less than 1.0 µm. To be
conservative, assume 70% is less than 1.0 µm and 30% is greater than 1.0 µm.
Vendor literature from TDC Filter states the capture / control efficiency of their QX Filter is
48% for particles less than 1.0 µm and 88% for particles greater than 1.0 µm.
The quantity of particulate emissions that is captured / controlled by the 1st -stage filter is
8,160 lb. per year and is equal to the following:
Uncontrolled Fraction Efficient Uncontrolled Fraction EfficientEmissions <1µm <1µm y 1+1 Emissions I I>IIAMI I> 1 µm y
I II 11
Uncontrolled Uncontrolled
X 70% X 48% + X 30% X 88%
Emissions Emissions
Uncontrolled
Emissions
8,160 lb.
70% X 48% + 30% X 88%
= 8160 lb.
= 13,600 lb. PVF
DEQ-CFW 00069108

•
PVF-I House Vacuum System (I-01A)
Page 2 of 2
DuPont PVF Manufacturing Facility
Determination of Actual PM-10 Emissions: PVF-1 House Vacuum System
(continued)
Particulate Matter less than 1.0 µm
13,600 lb. PVF
X 70%
= 9,520 lb. PVF
< 1 µm
9,520 lb. PVF
X 48%
= 4,570 lb. PVF
< 1 µm captured / controlled
9,520 lb. PVF
X 52%
= 4,950 lb. PVF
< 1 µm sent to 2nd-stage
Vendor literature from TDC Filter states the capture / control efficiency of their SB-ME Filter
media is 38% for particles less than 1.0 µm.
4,950 lb. PVF
X
38% • =
1,881 lb. PVF
< 1 µm captured / controlled
4,950 lb. PVF
X
62% =
3,069 lb. PVF
< 1 µm emitted to atmosphere
Particulate Matter greater than 1.0 µm
13,600 lb. PVF
X
30% =
4,080 lb. PVF
> 1 µm
4,080 lb. PVF
X
88% —
3,590 lb. PVF
> 1 µm captured / controlled
4,080 lb. PVF
X
12% =
490 lb. PVF
> 1 µm sent to 2nd-stage
Vendor literature from TDC Filter states the capture / control efficiency of their SB-ME Filter
Media is 72% for particles between 1.0 µm and 3.0 µm, and 98% for particles greater than 3.0
µm. To be conservative, it will be assumed the efficiency is 72% for particles greater than 1.0
µm.
490 lb. PVF
X
72% =
353 lb. PVF
> 1 µm captured / controlled
490 lb. PVF
X
28% =
137 lb. PVF
> 1 µm emitted to atmosphere
PVF-1 House Vacuum System: Total Annual Actual Particulate Matter Emissions
Total actual PVF resin emissions — 3,069 IN PVF < 1 lam emitted to atmosphere
137 lb. PVF > 1 µm emitted to atmosphere
3,206 lb. PVF emitted to atmosphere
Assume vacuum is operated 2 hour/day 4.39 lb/hour Particulate Matter
3,206 lb/year Particulate Matter
1.603 ton/year Particulate Matter
DEQ-CFW 00069109

Polyvinyl Fluoride Process No. 2 House Vacuum System
1-01 B
•
DEQ-CFW 00069110

•
PVF-2 House Vacuum System (I-01B)
Page 1 of 2
DuPont PVF Manufacturing Facility
Determination of Actual PM-10 Emissions: PVF-2 House Vacuum System
Particulate Matter Emissions Determination
For general good housekeeping purposes, the DuPont PVF-2 Process uses a vacuum system
(ID No. PVF-Vac-B) to remove any PVF resin powder (particulate matter) from the building's
floor and equipment. The emission of particulate matter from this vacuum system is
controlled by a two -stage fabric filter.
The 1 st-stage fabric filter (Control Device ID No. CD-PVF-B 1) is a TDC Filter QX blended
cellulous / synthetic fiber paper filter. Its efficiency for capturing / controlling particles is 48%
for 0.3 - 1.0 micron size, 88% for 1.0 - 3.0 micron size, and 99% for 3.0 - 10.0 micron size.
The 2nd-stage fabric filter (Control Device ID No. CD-PVF-B2) is a TDC Filter SB-ME
heavy-duty spunbond 100% polyester metalized spunbond filter media with a conductive
coating to prevent static buildup. Its MERV Test results shows the filter's efficiency for
capturing / controlling particles is 38% for 0.3 - 1.0 micron size, 72% for 1.0 - 3.0 micron
size, and 98% for 3.0 - 10.0 micron size.
Determination of before -control particulate matter is based on the conservative estimate of
8,160 lb/yr collected from the 1st -stage filter, the capture efficiencies of that filter, and the
particle size distribution of the PVF resin powder.
Results of particle size .distribution testing of batches of PVF resin powder during August
through October 2013 showed the worst -case situation of 68% being less than 1.0 µm. To be
conservative, assume 70% is less than 1.0 µm and 30% is greater than 1.0 µm.
Vendor literature from TDC Filter states the capture / control efficiency of their QX Filter is
48% for particles less than 1.0 µm and 88% for particles greater than 1.0 µm.
The quantity of particulate emissions that is captured / controlled by the 1st -stage filter is
8,160 lb. per year and is equal to the following:
Uncontrolled Fraction Efficiency + Uncontrolled 1>1�imj
FracoonI Efficiµncy
Emissions I<1 I I <1 m Emissions > 1 m
i I
Uncontrolled Uncontrolled
X 70% X 48% + X 310% X 88% = 81601b.
Emissions Emissions
Uncontrolled = 8,160 lb. = 13,600 lb. PVF
Emissions 70% X 48% + 30% X 88%
DEQ-CFW 00069111

•
PVF-2 House Vacuum System (I-01B)
Page 2 of 2
DuPont PVF Manufacturing Facility
Determination of Actual PM-10 Emissions: PVF-2 House Vacuum System
(continued)
Particulate Matter less than 1.0 µm
13,600 lb. PVF X 70% = 9,520 lb. PVF < 1 µm
9,520 lb. PVF X 48% = 4,570 lb. PVF < 1 µm captured / controlled
9,520 lb. PVF X 52% = 4,950 lb. PVF < 1 µm sent to 2nd-stage
Vendor literature from TDC Filter states the capture / control efficiency of their SB-ME Filter
media is 38% for particles less than 1.0 µm.
4,950 lb. PVF
X
38% =
1,881 lb. PVF
< 1 µm captured / controlled
4,950 lb. PVF
X
62% =
3,069 lb. PVF
< 1 µm emitted to atmosphere
Particulate Matter greater than 1.0 µm
13,600 lb. PVF
X
30% =
4,080 lb. PVF
> 1 µm
4,080 lb. PVF
X
88% =
3,590 lb. PVF
> 1 µm captured / controlled
4,080 lb. PVF
X
12% =
490 lb. PVF
> 1 µm sent to 2nd-stage
Vendor literature from TDC Filter states the capture / control efficiency of their SB-ME Filter
Media is 72% for particles between 1.0 µm and 3.0 µm, and 98% for particles greater than 3.0
µm. To be conservative, it will be assumed the efficiency is 72% for particles greater than 1.0
µm.
490 lb. PVF X 72% = 353 lb. PVF > 1 µm captured / controlled
490 lb. PVF X 28% = 137 lb. PVF > 1 µm emitted to atmosphere
PVF-2 House Vacuum System: Total Annual Actual Particulate Matter Emissions
Total actual PVF resin emissions = 3,069 lb. PVF < 1 µm emitted to atmosphere
137 lb. PVF > 1 µm emitted to atmosphere__
3,206 lb. PVF emitted to atmosphere
Assume vacuum is operated 2 hour/day 4.39 lb/hour Particulate Matter
3,206 lb/year Particulate Matter
0 1.603 ton/year Particulate Matter
DEQ-CFW 00069112

•
Waste DMSO Storage Tank
1-02
•
•
DEQ-CFW 00069113

•
Waste DMSO Storage Tank (I-02)
Page 1 of 3
3�
AIR EMISSIONS INV
ENTORY SUPPORTING DOCUMENTATION
Emission Source ID No.: I-02
Emission Source Description: Waste DMSO Storage Tank
Process Description:
This tank is used as an intermediate storage space for disposal of DMSO (dimethyl
sulfoxide) offsite. DMSO is used in the Hydrolysis process and can not currently be disposed of
offite. When the material in Hydrolysis can no longer be used for the process, the chemical is
transferred to the Waste DMSO Storage Tank. From this tank, the waste DMSO solution is
pumped to the facility's NPDES permitted wastewater treatment plant for disposal. The tank is
vents to the atmosphere through a gooseneck pipe with a conservation vent coming off the top
that ends 12" above the diked area.
Basis and Assumptions:
- Direct vent to atmosphere
- Tank volume = 6000 gallons or 802 ft3
- DMSO vapor pressure = 0.46 mm Hg @ 20°C
Molar volume of an Ideal Gas @ 0°C and 1 atm = 359 ft3/(lb-mole)
- Molecular Weight of DMSO = 78 (78 lb DMSO / lb -mole DMSO)
- Assume one complete tank volume turnover per day for point source emissions.
- Assume "Good" Emission Factor on Equipment Leaks for fugitive emissions (See
Appendix A).
- Flange emissions were used for all equipment except valves and pumps.
Information Inputs and Source of Inputs:
Information
Source
Waste DMSO generated
Waste Shipping Specialist, Global Supply
(lb/yr)
Support
Vapor pressure
CAS Number 67-68-5
Tank volume
Procedure PR-70, W1535321, or
NBPF000351
N-umber of Each Type of
W1535321 and verifying at source
Equipment
Master Production Scheduler via SAP BW
% Production / Quarter
Reporting
DEQ-CFW 00069114

Waste DMSO Storage Tank (I-02)
Page 2 of 3
•
Dimethyl sulfoxide (DMSO)
Point Source Emissions Determination:
Vapor pressure of DMSO = 0.46 mm Hg at 20°C
Mole fraction DMSO in vapor (using Dalton's law):
CAS No. 67-68-5
Mole fraction DMSO = Vapor pressure DMSO = 0.46 mm Ha = 0.000605 mole DMSO
Total pressure in tank 760 mm Hg mole gas in tank
Molar volume at 0°C and 1 atm. = 359 ft3
Pounds of DMSO per tank volume:
Molar volume at 20°C and 1 atm = 385 ft3
802 ft3 * lb -mole * 0.000605 mole DMSO * 78 lb DMSO = 0.098 lb DMSO
tank volume 385 ft3 lb -mole gas in tank mole DMSO tank volume
Total DMSO emissions per year from tank volume:
0.098 lb DMSO * 1 tank volume * 365 days * I ton = 0.018 ton DMSO / yr
tank volume day year 2000 lbs
Fugitive Emissions Determination:
Equipment
Component
Number of
Coin onents
Good Factor
(lb/hr/com onent)
Emissions
lb/hr)
Emissions
ton/yr)
Pump Seal
1
0.0075
0.0075
0.033
Heavy Liquid Valve
20
0.00352
0.0704
0.308
Open-ended Line
1
0.0215
0.0215
0.094
Flange/Connection
9
0.00031
0.00279
0.012
Total
0.447
Good factor (lb/hr/component) x Number of Components = Emissions (lb/hr)
Emissions (lb/hr) x 1 ton / 20001bs x 24 hr/day x 365 days/year = Emissions (ton/yr)
Total fugitive DMSO emissions per year = 0.447 ton DMSO / year
Emissions Summary:
Point Source Emissions + Fugitive Emissions = Total Emissions
0.018 ton DMSO / year - + 0.447 ton DMSO / year = 0.47 ton DMSO / year
DEQ-CFW 00069115

Waste DMSO Storage Tank (I-02)
Page 3 of 3
Ply
APPENDIX A: FUGITIVE EMISSION LEAK RATES FOR PROCESS EQUIPMENT
Fugitive emission studies have been done on a number of DuPont facilities and the measurements
were considerable lower than emission factors recommended by the EPA for SOCMI chemical
processes. These screening and bagging data have been used to establish "typical" emission
factors from DuPont facilities. The data separated into three categories of emission levels for "as
found" emissions form plants who were not involved in LDAR programs.
As a result of this effort, three sets of DuPont factors were developed: "superior", "excellent", and
"good." The superior factors are typical of processes that contain extremely hazardous materials,
i.e. phosgene (COC 12), chlorine (C 12), and hydrogen fluoride (HF). A set of example questions
to help guide DuPont sites as to when to use the different categories was also developed and is
discussed in the next section. The three categories represent the range found at DuPont facilities,
but still are much lower than EPA SOCMI factors. All three sets of factors are listed below.
EMMISION FACTORS (Ib/hr/component)
COMPONENT
SERVICE
SUPERIOR
EXCELLENT
GOOD
EPA
SOCMI
Pump Seals
Light Liquid
.xxxxx
0.00115
0.0075
0.109
Pump Seals
Heavy Liquid
xxxxx
0.00115
0.0075
0.047
Valves
Gas
xxxxx
0.00039
0.00549
0.012
Valves
Light Liquid
xxxxx
0.00036
0.00352
1 0.016
Valves
Heavy Liquid
xxxxx
0.00036
0.00352
0.00051
Pressure Relief
Seals
Gas/Vapor
xxxxx
0.00012
0.00013
0.23
Open Ended
Lines
All
xxxxx
0.001
0.0215
0.0037
Flanges
All
xxxxx
0.00018
0.00031
0.0018
Sampling
Connections
All
xxxxx
0.00018
0.00031
0.033
Compressor Seals
Gas/Vapor
N/A
N/A
N/A
0.50
Overall Emission
Factor
1/10,000
1/20
1/3
1/1
Heavy liquid means a liquid with a true vapor pressure of less than 0.3 kPa (0.04 Asia) at a
temperature of 294.3 °K (70 °F); or which has 0.1 Reid Vapor Pressure; or which when distilled
requires a temperature of 421.95 °K (300 °F); or greater to recover 10 percent of the liquid as
determined by ASTM method D86-82.
Light liquid means a liquid that is not a heavy liquid.
DEQ-CFW 00069116

•
Fugitive Emissions of Methylene Chloride
1-03
•
•
DEQ-CFW 00069117

Methylene Chloride Fugitive Emissions (1-03)
i
•
•
•
2015 AIR EMISSIONS INVENTORY SUPPORTING DOCUMENTATION
Emission Source ID No.: I-03
Emission Source Description: Fugitive emissions of Methylene Chloride
Process & Emission Description:
Methylene Chloride is, used as a heat exchanging fluid in many of the Fluoromonomers
and Nafion Membrane processes. It is a closed loop system. All emissions from this
system are a result of equipment leaks or spills.
Basis and Assumptions:
A material balance is used for calculating fugitive emissions.
Information Inputs and Source Inputs:
Information Input
ISource of Inputs
Methylene Chloride Emissions
I SARA 313 Report from Waste Shipment Clerk
Point Source Emissions Determination:
None
Fugitive Emissions Determination:
Shown on the following page.
DEQ-CFW 00069118

Methylene Chloride (1-03)
Page 1 of 1
•
Air Emissions InventorJ' Supporting Su ortin Documentation
Emission Source ID No.: I-03
Emission Source Description: Fugitive Emissions of Methylene Chloride
1Q15
2Q15
3Q15
4Q15
TOTAL
Methylene Chloride
13,121
4,002
553
4,018
21,694
Losses (lb)
DEQ-CFW 00069119

•
Chlorination of Riverwater to Control Mussel Growth in Equipment
1-04
•
DEQ-CFW 00069120

•
•
•
1-04
Page 1 of 1
Air Emissions Inventory Supporting Documentation
Emission Source ID No.: I-04
Emission Source Chlorination of River -water to Control Mussel Growth in
Description: Equipment
Sodium Hypochloritea (as Chlorine) Fugitive Emissions (Equipment Leaks)
EPA
Equipment
Total
SOCMI b
Service
Emissions
Emissions
Component
Compo-
(kg / hr /
(hr / yr)
(kg / yr)
( lb / yr )
vents
component
Pump Seals in light
1
0.0199
8760
174.3
384
liquid service
Valves in light
1
0.00403
8760
35.3
78
liquid service
Connections in light
33
0.00183
8760
529.0
1,166
liquid service
Total Emissions as Chlorine 1 564 J 1,628
Note a: Sodium hypochorite has a vapor pressure of 17 mmHg (2.26 Kpa) at 20 degrees C. Per
40 CFR 63 Subpart H, "light liquid service" means equipment whose contents have a vapor
pressure of greater than 0.3 kilopascals at 20 degrees C. Therefore, for the purpose of
determining fugitive emissions from the river water chlorination system, the soduim hypochlorite
equipment is considered to be in 'light liquid service" even though sodium hypochlorite is not an
organic compound.
Note b : Source: EPA, November 1995, Table 2-1.
DEQ-CFW 00069121

•
Sitewide Laboratory Emissions
1-05
•
•
DEQ-CFW 00069122

•
Sitewide Laboratory Emissions (1-05)
Page 1 of 1
2015 Air Emissions Inventory Supporting Documentation
Emission Source ID No.: I-05
Emission Source Description: Sitewide Laboratory Emissions
Process and Emission Description:
The Chemours Company - Fayetteville Works has several laboratories located throughout
the site. The use of normal laboratory chemicals result in assumed emissions of these
compounds.
Basis and Assumptions:
The amount of the laboratory chemicals used in the various laboratories is not easily
quantified due to the current procurement procedures. In previous years these quantities
could and were determined. During those years, it was assumed that 100% of the
laboratory chemicals purchased were emitted as air emissions.
To be conservative, it will be assumed that the annual emission of laboratory chemicals is
the summation of the emissions that occurred in the four (4) year period from 2003 to
2006.
Information Inputs and Source of Inputs:
Information Inputs Source of Inputs
Total pounds of laboratory chemicals Assumed conservative high estimates
reported from 2003 through 2006.
Point Source Emissions Determination:
For the purpose of this report, it is assumed that all emissions are point source via the lab
hoods.
Equipment Emissions and Fugitive Emissions Determination:
For the purpose of this report, it is assumed that all emissions are point source via the lab
hoods.
DEQ-CFW 00069123

11
•
Abrasive Blasting Building (1-06)
Page 1 of 1
Air Emissions Inventory Supporting Documentation
Emission Source ID No.: I-06
Emission Source Description: Outdoor abrasive blasting operation for items exceeding 8-feet
in any dimension
PM Emissions Determination
The emission of particulate matter is determined by multiplying the total estimate of
abrasive media consumed by the AP-42 Section 13.2.6 particulate emission factors.
AP-42 Section 13.2.6 particulate emission 27 pounds total particulate matter
factors for abrasive blasting of mild steel (PM) emissions per 1,000 pounds of
panels with a five mile per hour wind speed abrasive
Input:
Abrasive media consumed during reporting year 4,000 pounds
4,000 lb. abrasive X
year
27 lb. PM =
1,000 lb. abrasive
108 lb. PM
year
0.05 ton PM
year
Pollutant
Emissions
(ton/year)
Particulate Matter (TSP)
0.05
PM10 (< 10 micron)
0.05
PM2.5 (< 2.5 micron)
0.05
DEQ-CFW 00069124

•
•
Sitewide Laboratory Emissions (1-05)
Page 1 of 1
Air Emissions Inventory Supporting Documentation
Emission Source ID No.: I-05
Emission Source Description: Sitewide Laboratory Emissions
VOC Emissions Determination
The emission of VOC is determined by summing the total laboratory emissions
reported in the air emissions inventories from 2003 to 2006.
The Chemours Company - Fayetteville Works has several laboratories located
throughout the site. The use of normal laboratory chemicals result in assumed
emissions of these compounds.
2003-2006 Summation Sitewide Laboratory Chemicals
Compounds
2003
2004
2005
2006
48-month
Total
Acetic Acid
252
258
403
913
Acrolein
1
1
Benzene
1
2
2
5
Bromine
17
9
26
Chloroform
1
1
Ethyl Acetate
5
12
17
Ethylene Dichloride
262
132
147
541
Hydrogen Chloride
80
15
95
n-Hexane
3
3
Nitric Acid
22
87
109
Toluene
31
31
1� 742
Total VOC emissions would be the sum of the above compounds except for
bromine, hydrogen chloride, and nitric acid.
Total VOC emissions 1,512 lb. VOC
0.756 tons VOC
DEQ-CFW 00069125

•
Outdoor Abrasive Blasting Operation for
Items Exceeding 8-Feet in Any Dimension
M.
•
DEQ-CFW 00069126

Abrasive Blasting Building (1-06)
Page 1 of 1
2015 Air Emissions Inventory Supporting Documentation
Emission Source ID No.: I-06
Emission Source Description: Outdoor abrasive blasting operation for items exceeding 8-
feet in any dimension
Process and Emission Description:
The Chemours Company - Fayetteville Works has a free-standing structure that is used to
abrasive blast large metal parts prior to painting.
Basis and Assumptions:
The abrasive blasting activity in this structure is infrequent. Purchasing records of the
abrasive media used in this operation is the basis of the abrasive media consumption.
Per the AP-42 Section 13.2.6 particulate emission factors for abrasive blasting of mild
steel panels with a five mile per hour wind speed, total particulate matter emissions
would be 27 pounds per 1,000 pounds of abrasive. The choice of this low wind speed is
appropriate since the blasting operation is conducted inside an enclosure.
Information Inputs and Source of Inputs:
Information Inputs
Source of Inputs
Total pounds of abrasive media
Fluor Daniels personnel responsible for the
abrasive blasting operation.
Point Source Emissions Determination:
For the purpose of this report, it is assumed that all emissions are fugitive.
Equipment Emissions and Fugitive Emissions Determination:
For the purpose of this report, it is assumed that all emissions are fugitive.
•
DEQ-CFW 00069127

•
Paint Shop
1-07
•
DEQ-CFW 00069128

�Y
•
El
Paint Shop'
0
2015 Air Emissions Inventor3' Supporting Su ortin Documentation
Emission Source ID No.: I-07
Emission Source Description: Paint Shop
Process and Emission Description:
The Chemours Company - Fayetteville Works operates a Paint Shop in which product
cylinders and assorted metal parts are painted.
Basis and Assumptions:
1-07
Page 1 of 1
The painting activity at this souirce is fairly frequent. Most of the painting is of the
Fluoromonomer product cylinders. The basis of the emissions determination is the
historical actual consumption records of paints and primers used at this source.
This activity results in very low overall emissions of both VOC and HAP/TAP emissions.
In addition, the type and brand of paints consumed varies dramatically each year. As such,
the effort to accurately quantify and qualify the emissions from this activity is much greater
than the relative scale of the emissions.
Therefore, a conservative approach will be used to determine the air emissions, in which it
will be assumed that all the paint consumed was 100% VOC by mass, that all of the paints'
density is 12.71 lb/gal which is the greatest known density of a previously used paint, and
that each paint has the highest concentration of HAP/TAP of any previously used paint.
During the period from 2008 through 2014, the Paint Shop averaged 681 gallons per year.
Therefore, to be conservative it will be assumed that 750 gallons of the above described
worst -case paint was consumed during the reporting year.
Information Inputs and Source of Inputs:
Information Inputs
Source of Inputs
KBR personnel responsible for the Paint
Total gallons of paint consumed
Shop
Point Source Emissions Determination:
For the purpose of this report, it is assumed that all emissions are fugitive.
Equipment Emissions and Fugitive Emissions Determination:
For the purpose of this report, it is assumed that all emissions are fugitive.
DEQ-CFW 00069129

L-1
Paint Shop
Emission Source ID No.: I-07
VOC Emissions Determination
Worst -case Desity of Paint
Worst -case VOC Content
Paint Consumed in Year
12.71 lb/gal
100%
750 gallons (assumed)
750 gal. paint X 12.7 lb. paint X 1.0 lb. VOC
gal. paint lb. paint
HAP / TAP Emissions Determination
1-07
Page 1 of 1
9,533 lb. VOC
4.77 ton VOC
HAP /TAP
Worst-
case *
Conc.
Volume of
Paint
Consumed
(gal)
Worst-
case *
Density
(lb/gal)
Mass of
HAP/TAP
Emitted
(lb)
Eth 1 benzene
24.6%
750
12.71
2,345
Methyl ethyl ketone
10.0%
750
12.71
953
Toluene
17.0%
750
12.71
1,621
X lene
30.0%
750
12.71
2,860
Hexameth lene-diisoc anate
0.2%
750
12.71
19
Ethylene glycol
2.0%
750
12.71
191
* Worst -case HAP / TAP concentration is based on the following paints:
• DuPont T-8805 Thinner contains 24.6% ethyl benzene
• Krylon Orange contains 10.0% methyl ethyl ketone
• Krylon Acrylic Spray contains 17.0% toluene
• Krylon Orange contains 30.0% xylene
• DuPont Imron Accelerator 389-S contains 0.2% hexamethylene diioscyanate
• Latex Exterior Paint contains 2.0% ethylene glycol
DEQ-CFW 00069130

Self -Contained Abrasive Blasting Cabinets
M
•
E
DEQ-CFW 00069131

2015 Air Emissions Inventory Supporting Documentation
Emission Source ID No.:
Emission Source Description:
I-08
Abrasive Blasting Cabinets
1-08 r/{`
Page 1 of 2
Process and Emission Description:
The Chemours Company - Fayetteville Works has several self-contained abrasive blasting
cabinets located throughout the site. The function of these cabinets is to perform abrasive
blasting of metal parts prior to painting.
Basis and Assumptions:
The abrasive blasting activity in these cabinets is very infrequent. Some cabinets are used
once or twice a year. However, for the purposes of this air emissions inventory, it will be
assumed that a extremely conservative high estimate exists where one ton of abrasive
media is consumed in each cabinet each month.
Per the AP-42 Section 13.2.6 particulate emission factors for abrasive blasting of mild steel
panels with a five mile per hour wind speed, total particulate matter emissions would be 27
pounds per 1,000 pounds of abrasive. The choice of this low wind speed is appropriate
since the blasting operation is conducted inside a cabinet.
Information Inputs and Source of Inputs:
Information Inputs
Source of Inputs
Total pounds of abrasive media
Assumed conservative high estimates
Point Source Emissions Determination:
For the purpose of this report, it is assumed that all emissions are fugitive.
Equipment Emissions and Fugitive Emissions Determination:
For the purpose of this report, it is assumed that all emissions are fugitive.
•
DEQ-CFW 00069132

Abrasive Blasting Cabinets 1-08
2 of 2
Fugitive Emission Determination
PM Emissions Determination
The emission of particulate matter is determined by multiplying the total estimate of
abrasive media consumed by the AP-42 Section 13.2.6 particulate emission factors.
AP-42 Section 13.2.6 particulate emission 27 pounds total particulate matter
factors for abrasive blasting of mild steel emissions per 1,000 pounds of
panels with a five mile per hour wind speed abrasive
Assumptions:
Abrasive Blasting Cabinets on -site
4 cabinets
Abrasive consumed per cabinet
1 ton / month
Abrasive consumed per cabinet
12 ton / year
Sitewide abrasive consumed
48 ton / year
48 tons abrasive
year
X
1.3 ton PM
1,000 ton abrasive year
27 ton PM
Pollutant
Emissions
(ton/year)
Particulate Matter (TSP)
1.3
PMIo (< 10 micron)
1.3
PM2 5 (< 2.5 micron)
1.3
DEQ-CFW 00069133

•
Paint Spray Booths
O
•
DEQ-CFW 00069134

1-09
Y� Page 1 of 2
�5
2015 Air Emissions Inventory Supporting Documentation
Emission Source ID No.: I-09
Emission Source Description: Spray Paint Booths
Process and Emission Description:
The Chemours Company - Fayetteville Works has several small paint booths located
throughout the site. The function of these spray booths is to perform occasional painting of
metal parts using aerosol spray cans.
Basis and Assumptions:
The painting activity in these spray booths is very infrequent. Some spray paint booths are
used once or twice a year. However, for the purposes of this air emissions inventory, it will
be assumed that a extremely conservative high estimate exists:
(1) While most if not all of the paint spray booths are used less than one day per
month, it will be assumed that each spray booth has five (5) aerosol cans of paint
emptied into it each day, five days per week.
(2) Most commercial spray paints contain 60% to 65% VOC. However, for the
purpose of this report, it will be assumed that the paint is 100% VOC by weight.
(3) To account for the emission of hazardous air pollutants, it will be assumed that the
paint contains the highest concentration of the individual HAPs per the Material
Safety Data Sheets for Krylon and Rust-oleum paints.
Information Inputs and Source of Inputs:
Information Inputs
Source of Inputs
Total pounds of paint, VOC content, and
HAP content
Assumed conservative high estimates
Point Source Emissions Determination:
For the purpose of this report, it is assumed that all emissions are fugitive.
Equipment Emissions and Fugitive Emissions Determination:
For the purpose of this report, it is assumed that all emissions are fugitive.
0
DEQ-CFW 00069135

Paint Spray Booths
•
Emission Determination
VOC Emissions Determination
Spraybooths on -site
4 spraybooths
Cans of paint per day per booth
5 cans / day / booth
Cans of paint per day
20 cans / day
Net weight of contents per can
0.75 pounds
Weight of paint per day
15 lb. paint / day
Days per week spraybooth is used
5 days / week
Days per year spraybooth is used
260 days / year
Weight of paint per year
3,900 lb. paint / year
VOC content of paint
100% VOC content
Weight of VOC per year (Ib.)
3,900 lb. VOC / year
Weight of VOC per year (ton)
1.95 tons VOC / year
HAP Emissions Determination
The emission of hazardous air pollutants is determined by multiplying the total
estimate of paint consumed by the HAP content of the paint.
Example: Determination of the emission of ethyl benzene
1-09
Page 2 of 2
3,900 lb. paint X 5 lb. ethyl benzene — 195 lb. ethyl benzene
year 100 lb. paint
Total
Hazardous Air
CAS Number
HAP
Emissions
Pollutant
Content
(lb)
Ethyl benzene
100-41-4
5%
195
Methyl ethyl ketone
78-93-3
2%
78
Toluene
108-88-3
45%
1,755
Xylene
1330-20-7
25%
975
•
DEQ-CFW 00069136

ram,
Dispersion Process
1-12
•
DEQ-CFW 00069137

Nafion Dispersions (1-12)
•
•
•
Nafion Dispersions Process (1-12)
Product
Amount
(L)
D0521
0
D520
117
D521
1,605
D1020
0
D1021
472
D1031
0
D2020
1,462
D2021
137
D2029
21
D2820
0
TOTAL 1 3,814
Vapor density of n-propanol =
2.46 g/I
oh�v
Assume containers are filled with 100% n-propanol vapor at start of filling.
Then emissions are the displaced headspace of the containers as a result of their filling.
3,814 Liters 2.46 grams NPA _ 9,369 grams
year X Liter — year
21 lb. VOC
year
0.01 ton VOC
year
DEQ-CFW 00069138

•
Hexfluoropropylene Oxide (HFPO) Process
NS-A
0
•
DEQ-CFW 00069139

9 9 0
2015 Emissions NS-A HFPO Manufacturing Process (NS-A)
Emission Summary
Page 1 of 1
Emission Summary
A. VOC Compound Summary
Nafion®
Compound
CAS Chemical Name
CAS No.
Point Source and Non -point
Source Emissions
(lb.)
Accidental
Emissions
lb.
Total
Emissions
lb.
COF2
Carbonyl Fluoride
353-50-4
547
0
547
PAF
Trifluoroacetyl Fluoride
354-34-7
556
0
556
A/F Solvent (TFF)
Perfluoro-3,5,7,9,1 1 -entaoxadodecano I fluoride
690-43
1,045
0
1,045
A/F Solvent (TAF)
Trifluorometh I ester of carbonofluoridic acid
3299-24-9
1,584
0
1,584
HFP
Hexafluoropropl ene
116-15-4
49,439
0
49,439
HFPO
Hexafluoropropl ene Epoxide
428-59-1
29,022
5
29,027
Benzene
Benzene
71-43-2
3
0
3
Toluene
IMethylbenzene
108-88-3
155
1
156
Total VOC Emissions (lbs)
Total VOC Emissions (tons)
82,357
41.18
B. Toxic Air Polluntant Summary
Nafion®
Point Source
Non-pt Source
Accidental
Total
Compound
CAS Chemical Name
CAS No.
Emissions
Emissions
Emissions
Emissions
(lb.)
lb.
lb.
lb.
Benzene
Benzene
71-43-2
3
0
3
Fluorides (as HF)
Fluorides (sum of all fluoride compounds)
16984-48-8
1,218
100
0
1,317
HF
Hydrogen Fluoride
7664-39-3
1,218
100
0
1,317
Methylene Chloride
Methylene Chloride
75-09-2
0
0
0
0
Toluene
Meth (benzene
108-88-3
155
1
155
C. GHG Pollutants Summary
Nafion®
Point Source
Total
Total
Compound
CAS Chemical Name
CAS No.
Emissions
Emissions
Emissions
lb.
lb.
ton
CO2
Carbon Dioxide
124-38-9
106,308
106,308
53.15
Fluoroform
Trifluoromethane (HFC-23)
75-46-7
14,709
14,709
7.35

NS-A HFPO
HFPO Manufacturing Process (NS-A) V
Point Source Emission Determination
Page 1 of 7
Point Source Emission Determination
A. Carbonyl Fluoride (COF2)
HF Potential:
Each mole of COF2 (MW = 66) can generate 2 moles of HF (MW = 20)
1 lb COF2 • 1 moleCOF 201b HF 2 molesHF = 0.6061b HF�
661b COF 1 moleHF 1 moleCOF
Therefore, each 1 lb of COF2 generates 0.606 lb of HF
Quantity Generated:
Before -control COF2 generation :
CAS No. 353-50-4
Vented from A/F Column: Total AF column vent flow (lb]' Average COF2 mass fraction in AF column vent [lb COF2/lb]
From "Vent Flows" Tab = 222,773.43 x 0.4715 = 105,038 lb COF2
Vented from Stripper Column: Total Stripper col vent flow [lb] " Average COF2 mass fraction in Stripper column vent [lb COF2/lb]
From "Vent Flows" Tab = 234,240.56 X 0 = 0 lb COF2
Vented from Solvent Recycle
Tank: Total Solvent tank vent flow [lb]' Average COF2 mass fraction in Solvent tank vent [lb COF2/lb]
From "Vent Flows" Tab = 408,275.44 X 0 = 0 lb COF2
COF2 sent to VE-South Process when VE-S shutdown (from "VE-S Flow" Tab): = 8,418 lb COF2
Total COF2 Emitted from Process = 105,038 lb COF2 from A/F Column
(sent to WGS) + 0 lb COF2 from Stripper Column
+ 0 lb COF2 from Solvent Recycle Tank
+ 8,418 lb COF2 sent to VE-South Process when VE-S shutdown
113,456 lb COF2 sent to WGS
After -control emissions utilizing the Waste Gas Scrubber (WGS): Efficiency= 99.10%
VOC Emissions 113,456 lb COF2
Waste Gas Scrubber x 0.90%
454 lb COF2 (VOC)
HF Equivalent Emissions 454 lb COF2
x 0.606 lb HF/lb COF2
= 275 lb HF (Equivalent HF)
DEQ-CFW 00069141

NS-A HFPO
HFPO Manufacturing Process (NS-A)
Point Source Emission Determination
Page 2 of 7
B. Perfluoroacetyl Fluoride (PAF)
Trifluoroacetyl Fluoride (CF3COF)
HF Potential:
Each mole of PAF (MW = 116) can generate 1 mole of HF (MW = 20).
1 lb PAF- 1 mole PAF 201b HF 1 moleHF = 0.172lb HF
I
116lb PAF 1 moleHF 1 molePAF
Therefore, each 1 lb of PAF generates 0.172 lb of HF
Quantity Generated:
Before -control PAF vented
CAS No. 354-34-7
Vented from A/F Column:
Total AF column vent flow fib] "Average PAF mass fraction in AF column vent [lb PAF/lb]
From "Vent Flows" Tab =
222,773.43 X 0.5009 = 111,587 lb PAF
Vented from Stripper Column:
Total Stripper column vent flow jib] * Average PAF mass fraction in Stripper column vent [lb PAF/lb]
From "Vent Flows" Tab =
234,240.56 X 0.0038 = 890 lb PAF
Vented from Solvent Recycle
Total Solvent tank vent flow [lb] * Average PAF mass fraction in Solvent tank vent [lb PAF/lb]
From "Vent Flows" Tab =
408,275.44 X 0 = 0 lb PAF
PAF sent to VE-South Process when VE-S shutdown (from "VE-S Flow" Tab): = 7,155 lb PAF
Total COF2 Emitted from Process = 111,587 lb PAF from A/F Column
(sent to WGS) + 890 lb PAF from Stripper Column
+ 0 lb PAF from Solvent Recycle Tank
+ 7,155 lb PAF sent to VE-South Process when VE-S shutdown
119,633 lb PAF sent to WGS
After -control emissions utilizing the Waste Gas Scrubber (WGS): Efficiency= 99.10%
VOC Emissions 119,633 lb PAF
Waste Gas Scrubber x 0.90%
479 lb PAF (VOC)
HF Equivalent Emissions 479 lb PAF
x 0.172 lb HF/lb PAF
82 lb HF (Equivalent HF)
•
DEQ-CFW 00069142

NS-A HFPO
HFPO Manufacturing Process (NS-A)
Point Source Emission Determination
Page 3 of 7
•
•
1]
C. Acid Fluoride Solvent- mixture of TAF and TFF
Perfluoro-3,5,7,9,11-pentaoxadodecanoyl fluoride (TFF)
Trifluoromethyl ester of carbonofluoridic acid (TAF)
HF Potential:
The acid fluoride solvent is a mixture of telomeric acid fluorides (TAF) and telomeric fluoroformates (TFF).
TAF behaves as typical acid fluorides, however an average molecular weight must be used since chain length varies.
Each mole of TAF (avg MW = 330) can generate one mole of HF (MW = 20).
1 lb TAF . 1 mole TAF 20 lb HF 1 mole HF = 0.0606 lb HF
1
330 Ib TAF mole HF 1 mole TAF
Therefore, each 1 lb of TAF generates 0.061 kg of HF
Telomeric Fluoroformates break down into multiples of COF2 (MW = 66), which in turn generate 2 moles of HF (MW =20).
Using n=4 would mean for every mole of TFF, 6 moles of COF2 can be generated. MW of n=4 TFF is 396.
Nlnct TFF is helieved to be of chain length less than n=4 based on recent analysis.
l lb TFF . mole TFF 6 mole COF 2 20 lb HF 2 moles HF = 0.606 lb HF
396 lb TFF 1 mole TFF 1 mole HF 1 mole COF 2
CAS Nos. 690-43-7
3299-24-9
Therefore, each 1 lb of TFF generates 0.606 lb of HF
For the purpose of HF Potential, it will be conservatively assumed that all of the Acid Fluoride Solvent is TFF, since the potential HF is greater.
Quantity Generated:
The only processs vent where TAF/TFF may be vented to atmosphere is the solvent recycle tank vent.
Before -control Acid Fluoride solvent (AF) vented
Vented from Solvent Recycle Total Solvent tank vent flow [lb] " Average AF mass fraction in Solvent tank vent [lb AF/lb]
From "Vent Flows" Tab = 408,275.44 X 0.8691 = 354,832 lb TAF/TFF
Total AF Emitted from Process = 354,832 lb AF sent to WGS
(sent to WGS)
After -control emissions utilizing the Waste Gas Scrubber (WGS): Efficiency= 99.10%
VOC Emissions 354,832 lb AF
Waste Gas Scrubber x 0.90%
= 1,419 lb total AF (VOC)
69% TAF and 31 % TFF, based on May 2012 estimate
VOC Emissions
For TFF: 109,998 lb TFF 31 % TFF
x 0.90% Waste Gas Scrubber
= 440 lb TFF 440 lb VOC
For TAF: 244,834 lb TAF 69% TAF
x 0.90% Waste Gas Scrubber
979 lb TAF 979 lb VOC
HF Eouivalent Emissions As explained above, assume all solvent is TFF for conservative calculation of HF generation.
= 1,419 lb AF solvent, assumed all TFF X 0.606 lb HF/lb TFF = 860 lb. HF
DEQ-CFW 00069143

NS-A HFPO HFPO Manufacturing Process (NS-A) V.
Point Source Emission Determination
Page 4 of 7
•
D. Hexafluoroproplyene (HFP)
HF Potential:
HFP is a VOC without the potential to form HF.
Quantity Released:
CAS No. 116-15-4
Vented from A/F Column:
Total AF column vent flow [lb] * Average HFP mass fraction in AF column vent [lb HFP/lb]
From "Vent Flows" Tab =
222,773.43 X 0.0193 = 4,300 lb HFP
Vented from Stripper Column:
Total Stripper column vent flow [lb] * Average HFP mass fraction in Stripper column vent [lb HFP/lb]
From "Vent Flows" Tab =
234,240.56 X 0.1112 = 26,048 lb HFP
Vented from Solvent Recycle
Total Solvent tank vent flow [lb] * Average HFP mass fraction in Solvent tank vent [lb HFP/lb]
From "Vent Flows" Tab =
408,275.44 X 0.0079 = 3,225 lb HFP
HFP sent to VE-South Process when VE-S shutdown (from "VE-S Flow" Tab): = 310 lb HFP
Additional HFP is emitted from the unloading of HFP, specifically the decontamination of hoses and compressor after each trailer is unloaded.
The decontamination involves venting the contents of the two hoses and compressor piping to the WGS.
Each hose is 2" diameter x 20 feet long.
Volume of each hose = 753.98 in = 12.36 L
The density of HFP liquid at 16C is 1.42 kg/L Determined from physical property data
The density of HFP vapor at 16C is 0.0281 kg/L Determined by ideal gas law @ 16C and vapor press of 450 kPa abs.
(pressure from H27457PG on iso container, after H27451 HV closes)
HFP vented from Liquid Hose: (assumes hose volume is filled with li uid
Volume of hose X liquid density = 17.54 1 kg from Liquid Hose
HFP vented from Vapor Hose: (assumes hose volume is filled with va or)
Volume of hose X vapor density = 0.35 kg from Vapor Hose
There is an additional estimated 20' of 1 1/2" piping between the hose and 27460HV, also decontaminated, volume = 7 L
HFP vented from vapor piping= 7 L X vapor density = 0.20 kg from Vapor Piping
HFP vapor vented from compressor & associated piping
Suction bottle volume is 30.2 L, typical temperature is 27C and pressure is 270 kPa(g) at time of decontamination.
Vapor density of HFP= 0.0223 kg/L Determined by ideal gas law @ 27C and 371.3 kPa (a)
Reference H27454TG & H27453PG
Additional vapor in 10' of V diameter pipe, estimated volume is 1.5 L. Total volume is 31.7 L
Suction side volume X vapor density= 0.71 kg
Discharge bottle volume is 30.2 L, typical temperature is 37C, 370 kPa (g) at time of decontamination.
Vapor density of HFP= 0.0274 kg/L Determined by ideal gas law @ 37C and 471.3 kPa (a)
Reference H27456TG & H27455PG
Discharge side volume x vapor density= 0.83 kg
Total volume form compressor & piping = 1.54 kg from Compressor & Piping
The number of decontamination events required is based on the HFP consumed divided by the typical transfer amount, rounded up.
3,032,751 / 13,500 = 225
Total HFP from decontamination of unloading hoses = Number of events * (vented from liquid hose + vapor hose + compressor + piping)
225 X 20 = 4,410 kg HFP
9,722 lb HFP from hose decon
DEQ-CFW 00069144

NS-A HFPO HFPO Manufacturing Process (NS-A)
Point Source Emission Determination
Page 5 of 7
HFP is also vented from the Crude Dryers each time a dryer is changed. The basis for this calculation assumes the composition of vapor
in the dryer is 50 %HFP and 50 %HFPO,
and the vapor density is 3.3 Ib/ft3 (reference ASPEN model)
The molecular sieves have a bulk density of 47 lb per ft3 of bed volume
The density of the sieves themselves is 57 lb per ft3 according to a recent Certificate of Analysis.
Therefore the void fraction of a bed of sieves would be 0.175 ft3 void volume per ft3 total bed volume
From BPF dimensions of the dryer, it is estimated that 10' height of 10" diameter space is filled with sieves, plus 2' of a 6" diameter section.
The remaining space at the top containing no sieves consists of 6" high x 10" diameter section plus a 8" high x 6" dia. section.
Vapor volume in dryer= 1.429 ft3 of vapor
X vapor density of 3.3 Ib/ft3
4.72 lb VOC vapor released per dryer change
Dryer changes occur every 48 hours. The number of dryer changes is estimated to be 147
HFP vented = %HFP x lb of VOC per dryer change x number of dryer changes in the year= 347 lb HFP
After -control emissions from the Waste Gas Scrubber with an assumed efficiency of zero percent (0%) (HFP is not scrubbed out)
VOC Emissions 4,300 lb HFP from A/F Column
+ 26,048 lb HFP from Stripper Column
+ 3,225 lb HFP from Solvent Recycle Tank
+ 9,722 lb HFP from Unloading Hoses
+ 347 lb HFP from crude dryer changes
+ 310 lb HFP sent to VE-South Process when VE-S shutdown
43,951 lb HFP 43,951 lb VOC
•
DEQ-CFW 00069145

NS-A HFPO HFPO Manufacturing Process (NS-A) 'r
Point Source Emission Determination
Page 6 of 7
E. Hexafluoroproplyene Oxide (HFPO)
HF Potential:
HFPO is a VOC without the potential to form HF.
Quantity Released:
CAS No. 428-59-1
Vented from A/F Column:
Total AF column vent flow [lb] * Average HFPO mass fraction in AF column vent [lb HFPO/lb]
From "Vent Flows" Tab =
222,773.43 X 0.0019 = 423 lb HFPO
Vented from Stripper Column:
Total Stripper col vent flow [lb] * Average HFPO mass fraction in Stripper column vent [lb HFPO/lb]
From "Vent Flows" Tab =
234,240.56 X 0.0496 = 11,618 lb HFPO
Vented from Solvent Recycle
Total Solvent tank vent flow [lb] * Average HFPO mass fraction in Solvent tank vent [lb HFPO/lb]
From "Vent Flows" Tab =
408,275.44 X 0.0216 = 8,819 lb HFPO
HFPO sent to VE-South Process when VE-S shutdown (from "VE-S Flow" Tab): = 30 lb HFPO
Additional HFPO is emitted from the decontamination of hoses after each HFPO ISO is loaded.
The decontamination involves venting the contents of the two hoses to the WGS via a service manifold.
The liquid hose is 1" diameter x 20 feet long. The vapor hose is 0.5' diameter x 20 feet long. (BPF 346333).
Volume of liquid hose = 188.5 in = 3.09 L
Volume of vapor hose= 47.124 in3 = 0.77 L
The density of HFPO liquid at -25C is 1.58 kg/L Determined from physical property data
The density of HFPO vapor at -25C is 0.0563 kg/L Determined by ideal gas law @ -25C and max press of 700 kPa abs.
(max pressure observed H10765PG on iso container, after filling)
HFPO vented from Liquid Hose: (assumes hose volume is filled with liquid
Volume of hose X liquid density = I 4.88 kg from Liquid Hose
HFPO vented from Vapor Hose: (assumes hose volume is filled with va or)
Volume of hose X vapor density = I kg from Vapor Hose
The amount of piping involved in the decontamination is negligible (isolation valves are in close proximity to hoses).
Total HFPO from decontamination of loading hoses = Number of events * (vented from liquid hose + vapor hose)
52 X 4.92 = 256 kg HFPO
564 lb HFPO
As in the HFP section above, HFPO is vented from the crude dryers during each dryer change.
HFPO vented = %HFPO x lb of VOC per dryer change x number of dryer changes in the year= 347 ib HFPO
from dryers
After -control emissions from the Waste Gas Scrubber with an assumed efficiency of zero percent (0%) (HFPO is not scrubbed out)
VOC Emissions 423 lb HFPO from A/F Column
+ 11,618 lb HFPO from Stripper Column
+ 8,819 lb HFPO from Solvent Recycle Tank
+ 564 lb HFPO from Unloading Hoses
+ 347 lb HFPO from dryer changes
+ 30 lb HFPO sent to VE-South Process when VE-S shutdown
21,801 lb HFP 21,801 lb VOC
DEQ-CFW 00069146

NS-A HFPO
HFPO Manufacturing Process (NS-A)
Point Source Emission Determination
Page 7 of 7
F. Perfluoromethylcyclopropane (PMCP)
Oxygen (OZ)
Fluoroform (CF3H)
Carbon Dioxide (CO2)
PMCP, OZ, CF3H, and COz are not VOCs nor do they have potential to make HF. Since they are not
reportable emissions, the calculations are not shown here.
G. Annual Point source emissions summary -Process Vents (after control)
VOC(lb) Equiv HF(lb)
A.
COF2
454
275
B.
PAF
479
82
C.
Acid Fluoride Solvent (TFF)
440
860
Acid Fluoride Solvent TAF
979
D.
HFP
43,951
0
E.
HFPO
21,801
0
Total for year Ib
68,104
1,218
•
•
CAS No. 379-16-8
CAS No. 7782-44-7
CAS No. 7546-7
CAS No. 124-38-9
Equiv HF represents conservative estimate total for TFF+TAF
DEQ-CFW 00069147

HFPO Manufacturing Process (NS-A)
Non -Point Source Emissions
Page 1 of 4
•
•
I. Equipment Emissions
Equipment Emissions are a function of the number of emission points in the plant (valves, flanges, pump seals). For the equipment emission
calculations the inventory shown below is conservative and based on plant and process diagrams. Note that the emission types are as
follows: Equipment Emissions (EE) inside buildings = Stack Emissions (SE)
Equipment Emissions (EE) outside buildings = Equipment Fugitive Emissions (FE)
Maintenance Fugitive Emissions (ME)
A. Equipment Emissions Inside Buildings (Stack Emissions)
1. Equipment Emissions (EE) from Barricade:
Emissions are vented from equipment located in the barricade and are vented through the barricade scrubber. Barricade
r"hh=r ic 95 efficient fnr r.nntrnl of arirl flunrirlec. From ASPEN Model:
- Reactor/Solvent Recycle/Solvent Column &Associated Equipment
Material
VOC
HFA
Avg. Contents (kg/hr)
%of
contents
%VOC
%HF
HF
Potential
%Overall HF Potential
Line 207E
Line255
I Line305
Total
0.6061
0.1721
0.11
0.081
HFPO
x
1491.169
10.387361
277.0774
1778.634
6.02
6.02
COF2
x
x
223.8143
01
43.16596
266.9803
0.90
0.90
0.90
0.606
0.90
PAF
x
x
206.9447
0.069376
39.84183
246.8559
0.84
0.84
0.94
0.172
0.84
HFP
x
1916.528
3.5050451
366.0799
2286.113
7.74
7.74
F23
1 5.084826
01
0.980683
6.0655091
0.02
021
26,42446
0
5.096328
31.52079
0.11
CO2
0
0
0
0
0.00
PMAF
x
x
17.91142
0.074824
3.378695
21.36494
0.07
0.07
0.071
0.11
0.07
TAFN=1
x
x
5230.229
1005.205
0
6235.434
21.11
21.11
21.11
0.606
21.11
TAFN=2
x
x
11378.11
2192.731
0
13570.94
45.94
45.941
45.94
0.606
45.94
TAFN_2.
x
x
3753.999
723.9967
0
4477.996
15.16
15.16
15.16
0.606
15.16
Dimer
x
x
7.260958
01
0
7.2609581
0.02
0.02
0.02
0.606
0.02
Trimer
x
x
9.359539
0
0
9.359539
0.03
0.03
0.03
0.081
0.03
PMCP
476.0362
79.94006
0.015
555.9913
1.88
HFA
x
6.427688
0
1.233058
7.660746
0.03
0.03
Benzene
14.78905
2.867976
0
17,65703
0.06
Toluene
14.88
2.87
0
17.75035
0.06
Total
22537.47
100.00
97.87
84.08
83.1
0.8
0.1
0.0
_ _ . '_ .. ..
Average HF Potential
0.505393
84 --- acid -:d__ With ---'•-d Jill ---------- sc --
ow io are eau uu�nuea wnn yo io uunu uneu Jill tile uan uauc �ci uuuei ,
16% are non-acid fluorides with 0% controlled in the barricade scrubber.
100% of the liquid is 0.505 weight fraction HF.
Barricade:
Valve emissions:
219 valves x 0.00039 Ib/hr/valve
= 0.085 Ib/hr EE
Flange emissions:
438 flanges x 0,00018 Ib/hr/flange
= 0.079 Ib/hr EE
Pump emissions:
2 pump x 0.00115 Ib/hrlpump
= 0.002 Ib/hr EE
Total equipment emission rate
= 0.167 Ib/hr EE
Barricade VOC:
From acid fluorides:
0.167 lb. EE/hr
987.551 lb VOC generated
x 7058.9 operating hr/year
x (100%-95%) scrubber efficiency
x 0.840 lb. A/F VOC/lb. EE
= 49.378 lb VOC emitted
= 987.551 lb VOC generated
From non-acid fluorides: 0.167 lb. EE/hr
Total Barricade VOC Emissions:
x 7058.9 operating hr/year
49.378 lb VOC
x 0.160 lb. Non-A/F VOC/lb. EE
+ 188.105 lb VOC
= 188.105 lb VOC
= 237.483 lb VOC
Barricade HF:
0.167 lb. EE/hr
x 7059 operating hr/year
x 0.505 lb. HF/lb. EE
x (100%-95%) scrubber efficiency
= 29.685 lb HF
DEQ-CFW 00069148

HFPO Manufacturing Process (NS-A)
Non -Point Source Emissions
Page 2 of 4
•
•
•
2. Equipment Emissions (EE) From HFPO Tower
Emissions are vented from equipment located in tower and are vented through stack.
F ASPEN Model:
rom
A/FColumn, Scrubbers, Dryers, Strip er Column&Associated Equipment
Material
VOC
HFA
Av . Contents k /hr
% of
contents
% VOC
% HF
HF
Potential
%Overall HF
Potential
Line 405
Line 572
Line 605
Line 652
Total
0.606
0.172
0.11
0.081
HFPO
x
0.089511
0
0.1175291
271,2223
271.4293
37.18
37.18
COF2
x
x
43.11259
0
0
0
43.11259
5.91
5.91
5.91
0.606
5.91
PAF
x
x
33.16642
0
01
01
33.16642
4.54
4.54
4.54
0.172
4.54
HFP
x
0.327155
0
0.265321
361.82331
362.4158
49.64
49.64
F23
0.978137
0
0.489234
0.0331791
1.50055
0.21
Oz
5.096328
0
0
01
5.096328
0.70
COz
0
0
1.449218
0.0352431
1.483461
0.20
PMAF
x
x
0
0
0
0
0
0.00
0.00
0.00
0.11
0.00
TAFN=1
x
x
0
0
0
0
0
0.00
0.00
0.00
0.606
0.00
TAFN_Z
x
x
0
0
0
0
0
0.00
0.00
0.00
0.606
0.00
TAFN_I
x
x
0
0
0
0
0
0.00
0.00
0.00
0.606
0.00
Dimer
x
x
0.585265
0
0
0
0.585265
0.08
0.08
0.08
0.606
0.08
Trimer
x
x
0
0
0
0
0
0.00
0.00
0.00
0.081
0.00
PMCP
0
0
0
11.2638
11.2638
1.54
HFA
x
0
0
0
0
0
0.00
0.00
Water
0
129.8095
0
Benzene
0
0
0
0
0
0.00
Toluene
0
0
0
0
0
0.00
Total
730. 351
100.00
97.351
10.53
6.0
4.5
0.01
0.0
Afhof • 07 -f 04 of fho rvnroee mnfnrial qra VnCc•
Avera a HF Potential
1 0.044087
100% of the liquid is 0.044 weight fraction HF.
Valve emissions: 298 valves x 0.00039 Ib/hr/valve = 0.116 Ib/hr EE
Flange emissions: 596 flanges x 0.00018 Ib/hr/flange = 0.107 Ib/hr EE
Pump emissions: 2 pumps x 0.00115 Ib/hr/pump = 0.002 Ib/hr EE
Total equipment emission rate = 0.226 Ib/hr EE
VOC: 0.226 lb. EE/hr
x 7059 operating hr/year
x 0.970 lb. VOC/lb. EE
1546.078 lb VOC
HF: 0.226 lb. EE/hr
x 7059 operating hr/year
x 0.044 lb. HF/lb. EE
70.131 Ib HF
DEQ-CFW 00069149

HFPO Manufacturing Process (NS-A)
Non -Point Source Emissions
Page 3 of 4
•
•
B. Equipment Emissions Outside Buildings (Fugitive Emissions)
1. Fugitive Emissions (FE) From Outside Unit Operations
From ASPEN Model:
Reactor/Solvent Recycle/Solvent Column & Associated Equipment
Material
VOC
HFA
Avg. Contents (kg/hr)
% of
contents
%VOC
%HF
HF
I Potential
%Overall HF
Potential
Line 706
Line 805
Line 812
ITotal
0.606
0.172
0.111
0.081
HFPO
x
238.6887
32.53355
0.0149131
271.2372
3.97
3.97
COF2
x
x
0
0
0
0
0.00
0.00
0.00
0.606
0.00
PAF
x
x
0
0
0
0
0.00
0.00
0.00
0.172
0.00
HFP
IX
0.08421
361.7391
0.181291
362.0046
5.30
5.30
F23
1
0
0.033124
0
0.033124
0.00
02
0
0
0
0
0.00
CO2
0.0351941
0
0
0.095184
0.00
PMAF
Ix
x
0
0
01
0
0.00
0.001
0.00
0.11
0.00
TAFN_i
Ix
x
0
0
0
0
0.00
0,00
0.00
0.606
0.00
TAFa_2
x
x
0
0
0
0
0.00
0.00
0.00
0.606
0.00
TAFN_2,
x
x
0
0
0
0
0.00
0.00
0.00
0.606
0.00
Dimer
x
x
0
0
0
0
0.00
0.001
0.00
0.606
0.00
Trimer
x
x
0
0
0
0
0.00
0,001
0.00
0.081
0.00
PMCP
0
11.2536
6.755249
18,00885
0.26
HFA
x
0
0
0
0
0.00
0.00
Benzene
x
0
0
0
0
0.00
0,00
Toluene
x
0
0.016223
6180.06
6180.076
90.47
90.47
Total
6831.395
100.00
99.74
0.001
0.0
0.0
0.0
0.0
Alai imp- that ' inn wt_ % of the nrocess material
are VOCs
Average HF Potential
0
0 vat. % of the liquid is HF.
Valve emissions: 317 valves x 0.00039 Ib/hr/valve = 0.124 Ib/hr FE
Flange emissions: 634 flanges x 0.00018 Ib/hr/flange = 0.114 Ib/hr FE
Pump emissions: 3 pump x 0.00115 Ib/hr/pump = 0.003 Ib/hr FE
Total fugitive emission rate = 0.241 Ib/hr FE
VOC: 0.241 lb. FE/hr HF: 0.241 lb. FE/hr
x 7059 opearting hr/year x 7059 operating hr/year
x 1.00 lb. VOC/lb. FE x 0.0 lb. HF/lb. FE
1703 lb VOC = 0.00 lb HF
1547 lb VOC excluding toluene, which is calculated below by mass balance
2. Fugitive Emissions From HFP Storage and Feed
Assume that : This system contains only HFP, so 100 wt. % of the process material are VOCs
HFP has no potential to form HF, so 0 wt. % of the liquid is HF.
Valve emissions: 120 valves x 0.00039 Ib/hr/valve = 0.047 Ib/hr FE
Flange emissions: 135 flanges x 0.00018 Ib/hr/flange = 0.024 Ib/hr FE
Total fugitive emission rate = 0.071 Ib/hr FE
VOC: 0.071 lb. FE/hr
x 7059 operating hr/year
x 1.00 lb. VOC/lb. FE
502 lb VOC
HF: 0.071 lb. FE/hr
x 7058.88 operating hr/year
x 0.0 lb. HF/lb. FE
= 0.00 lb HF
DEQ-CFW 00069150

HFPO Manufacturing Process (NS-A)
Non -Point Source Emissions
Page 4 of 4
•
•
•
3. Fugitive Emissions From Benzene
Basis: Fugitive emissions are determined via mass balance, i.e. any mass of benzene unaccounted for in the mass balance will be
assumed to be air emissions.
Assume that: Benzene introduced into the process is mostly destroyed by reaction.
Ratio of emissions to benzene used = 1.9 lb emission/368 lb benzene used
Calculations:
Benzene introduced to process:
Benzene emissions:
560.228571 Ibs
560.23 Ibs
x 1.90 lb emission = 2.89 lb benzene emission
368 lb benzene
4. Fugitive Emissions of Toluene by Mass Balance
Basis: Fugitive emissions are determined via mass balance, i.e. any mass of toluene unaccounted for in the mass balance will be
assumed to be air emissions.
Assume that: 95% of raw ingredient becomes waste
Mass Balance:
Toluene inventory in process as first day of month ('User E
Toluene added to process:
Toluene inventory in process as of last day of month ('Use
Toluene destroyed in process:
Toluene shipped off with product:
Toluene removed from process as a solid waste:
Toluene released to air via permitted stack:
Toluene released to process wastewater:
Toluene released to the ground (spill):
Unaccounted for difference in mass:
5. Total Equipment Emissions (Fugitive)
+ 3935.20lb 1-Jan
+ 20026lb
- 5480.00lb 1-Jan
- 0 lb
- 0 lb injected into product
- 18326 lb
- 0lb
- 0lb
- 0 lb
155 lb toluene = 155 lb VOC
Emission Source
Inside Emissions
Outside Emissions
(Stack Emissions)
(Fugitive Emissions)
lb VOC
lb HF
lb VOC
lb HF
A-1
Barricade
237.48
29.69
A-2
HFPO Tower
1546.08
70.13
B-1
Outside operations(excluding toluenes stem)
1547
B-2
HFP Storage and Feed
501.89
B-3
Benzenes stem
2.89
B-4
Toluene mass balance
155,20
Total
1783.56
99.821
2207.381
0.00
6. Speciated Equipment and Fugitive Emissions for annual reporting
For speciated reporting, the following assumptions are made:
Al AF VOCs from the barricade (J42) are reported as 50% TAF and 50% TFF
Al Non-AF VOCs from the barricade (E48) are reported as 50% HFP and 50% HFPO
A2 Tower VOCs (H177) are reported as 38% HFPO, 51% HFP, 6% COF2, and 5% PAF.
B1 Toluene emissions are included in B-4. The remaining VOC (J178) is reported as 60% HFP and 40% HFPO.
B2 HFP system VOCs are 100% HFP
B3 VOCs calculated in B3 are 100% benzene
B4 Toluene system emissions are 100% toluene
r:n iind Ih VOr
COF2
92.76
PAF
77.30
A/F Solvent (TFF)
24.69
A/F Solvent (TAF)
24.69
HFP
2312.88
HFPO
1300.52
Benzene
2.89
Toluene
155.20
i otai vuu jvvu.v4
DEQ-CFW 00069151

HFPO Manufacturing Process (NS-A)
Maintenance Emissions
Page 1 of 1
Equipment Cleaned/
Decontaminated
HFP
(lb/yr)
HFPO
(lb)
TAF
(lb/yr)
TFF
(lb/yr)
COF2
(lb/yr)
PAF
(lb/yr)
TOTAL
3175.23
5920.32
580.11
580.11
0.05
0.05
Total VOC (lb/yr)l 10259.87
Data summed from monthly report worksheets. Calculations based on vessel
volumes and compositions at time of decontamination.
•
DEQ-CFW 00069152

•
•
•
HFPO Manufacturing Process (NS-A)
Accidental Releases
Page 1 of 1
Accidental Releases to Atmosphere
There were 3 accidental releases to the atmosphere recorded in 2015. Refer to incident reports for more information
I. Total Emissions from Accidental Releases
Source (Incident date)
11
1 11..
1 11
��00000
1 11
1 11
1 1� 1
1 1/
1
1 11
11
00000��
DEQ-CFW 00069153

•
Vinyl Ethers North Process
11
•
DEQ-CFW 00069154

•
•
Air Emissions Inventory
2015 Emissions Summary
A. VOC Emissions Summary
0
l
Vinyl Ethers North (NS-B)
Summary
Page 1 of 2
EVE
PPVE
PSEPVE
Accid'1
Total Vinyl
Nation®
CAS Chemical Name
CAS No.
Process
Process
Process
Releases
Ethers North
Compound
Emission
Emission (lb.)
Emission (lb.)
(lb.)
Emissions (lb.)
(lb.)
HFP
Hexafluoroproplyene
116-15-4
147
11,247
296
11,691
BFPO
Hexafluoropropylene oxide
428-59-1
145
22,803
1,205
24,152
HFPO-Dimer
2,3,3,3-tetrafluoro-2-(1,1,2,2,3,3,3-
2062-98-8
1
38
0
39
(Trifluoroethenyl oxy] Methyl]-1,2,2,2
EVE
Tetrafluoroethoxyl-2,2,3,3-
63863-43-4
Tetrafluoro-, Methyl Ester
71
0
0
71
PPVE
Perfluoroprop 1 vinyl ether
1623-05-8
0
2,868
0
2,868
Perfluoro-2-(2-Fluorosulfonylethoxy)
PSEPVE
Propyl Vinyl Ether
16090-14-5
0
0
277
277
PPF
Perfluoropropionyl fluoride
422-61-7
0
79
0
79
TEE
Tetrafluoroethylene
116-14-3
63
20
478
561
C4
Perfluoro-2-butene
360-89-4
0
440
1,095
1,535
C5
Perlluoropentene
376-87-4
0
38
0
38
Diglyme
Dieth lene Glycol Dimethyl Ether
111-96-6
0
0
0
0
AN
Acetonitrile
75-05-8
0
375
0
375
ADN
Adiponitrile
111-69-3
0
0
0
0
TTG
Tetra lyme
143-24-8
2
0
0
2
Tetr afluoro-2 [Hexafluoro-2-
DA
(Tetrafluoro-2-
4089-58-1
(Ftuorosutfonyl)Ethoxy) Propoxy
0
0
14
14
Tetrafluoro-2-[Tefluoro-2-(1,2,2,2-
755-02-9
Hydro-PSEPVE
Tetra-fluoroe0roxy)-1-
0
0
0
0
MA
Tetrafluoro-2-[Tetrafluoro-2-
4089-57-0
6
(Fluorosulfonyl)Ethoxy]-Propanoyl
0
0
6
Methyl Perfluoro (5-(Fluorofonnyl)-4-
69116-72-9
MAE
Oxahexanoate)
2
0
0
2
DAE
Methyl Perfloro (8-(Fluorofonnyl)-5-
69116-73-0
methyl-4,7-Dioxanonanoate)
3
0
0
3
Methyl Perfluoro (I I-(Fluorofonnyl)-
69116-67-2
TAE
5,8-Dimethyl-4,7,10-
0
0
0
0
hydro -EVE
Methyl Perfloro-5-methyl-4.7-
87483-34-9
dioxanon-8-hydroaneoate
6
0
0
6
iso-EVE
Methyl Perfluoro-6-Methyl-4,7-
73122-14-2
Dioxanon-8 Eneoate
10
0
0
10
Methyl-2,2-Difluoromalonyl Fluoride
69116-71-8
MMF
0
0
0
0
HFPO Trimer
Perfluoro-2,5-Dimethyl-3,6-
2641-34-1
0
1
0
1
Iso-PSEPVE
Perfluoro-l-Methyl-2-(2
34805-58-8
0
0
0
0
Total VOC Emissions (Ibs)
448
37,908
3,372
0
41,728
Total VOC Emissions (toni
0.2
19.0
1.7
1 0
20.9
B. VOC Control Device Efficiency
VOCs Generated Before Control (Ibs)
VOCs After Control (Ibs)
Equip't
Maint.
Accid'1
Total VOC
Process
Emiss'n
Emiss'n
Releases
Generated
Emissions (lb.)
(lb.)
(lb.)
(lb,)
(Ibs)
Total VOC Emitted (Ibs)
48,073
2,888
1,301
0
52,262
41,728
52,262 lb VOC generated 10,533 lb VOC removed in control device
41,728 lb VOC emitted 52,262 lb VOC generated
10,533 lb VOC removed in control device = 20.16 % VOC control efficiency
DEQ-CFW 00069155

Air Emissions Inventory Vinyl Ethers North (NS-B)
Summary J
Page 2 of 2
•
C. Toxic Air Pollutant and Hazardous Air Pollutant Summary (TAPSIHAPS)
EVE
PPVE
PSEPVE
Total
Nafon®
CAS Chemical Name
CAS No.
Emissions
Emissions
Emissions
Accidental
Emissions
Compound
(Ibs)
(Ibs)
(Ibs)
Releases (Ibs)
(lbs)
HF
Hydrogen Fluoride
7664-39-3
0.27
11.8
0.9
0
13.0
Diglyme
Diethylene Glycol
111-96-6
0
0
Acetomtnle
Acetonitnie
75-05-8
233
233
D. Carbon Monoxide (CO) Emissions Summary
EVE
PPVE
PSEPVE
Total
Total
Nafion®
CAS Chemical Name
CAS No.
Emissions
Emissions
Emissions
Emissions
Emissions
Compound
(Ibs)
(lbs)
(Ibs)
(Ibs)
(tons)
CO
Carbon Monoxide
630-08-0
211
30,163
0
30,374
15.2
Report Created By: Broderick Locklear
Report Created: 2/4/2016
•
•
DEQ-CFW 00069156

•
•
Air Emissions Inventory Vinyl Ethers North (NS-B)
PSEPVE Process Emissions
Page 1 of 18
2015 AIR EMISSIONS INVENTORY SUPPORTING DOCUMENTATION
Emission Source ID No: NS-B
Emission Source Description: VE-North PSEPVE Manufacturing Process
Process & Emission Description: The VE-North PSEPVE manufacturing process is a continuous chemical
reaction. All emissions from the process are vented through the Nafion Division Waste Gas Scrubber (Control
Device lD No. NCD-Hdr) which has a documented control efficiency of 99.6% for all acid fluoride compounds.
Some emitted compounds are assumed to pass completely through the scrubber, so the control efficiency for
those compounds is assumed to be 0%. The control of emissions of specific compounds will be addressed and
detailed in the following pages.
The PSEPVE process in VE-North emits compounds in the acid fluoride family. In the presence of water (such
as in atmospheric moisture), these acid fluorides can eventually hydrolyze to hydrogen fluoride. For the purpose
of this emissions inventory, a conservative approach will be taken and the acid fluorides will be reported both as
a VOC and as the equivalent quantity of hydrogen fluoride.
Basis and Assumptions:
- The PSEPVE process flowsheet is the basis for relative concentrations of before -control emissions of gaseous
wastes.
- Calculations of point source emissions are based on actual vent flow totals taken from the IP21 Historian.
DEQ-CFW 00069157

Air Emissions Inventory
0 Point Source Emission Determination
A. HFP
Hexafluoropropylene
HF Potential:
HFP is a VOC without the potential to form HF
Quantity Released
HFP is a byproduct present in the HFPO feed. It is an inert in VE-North that is
vented to the WGS.
HFP vented per the process flowsheet
Vented from the Condensation Reactor:
Vented from the Crude Receiver
Vented from the Foreshots Receiver
HFP vented based on
HFP vented based on
HFP vented based on
HFP vented from Condensation Reactor:
0.15 kg HFP x
3.66 kg CndRx
HFP vented from Crude Receiver
0.08 kg HFP x
18.76 kg CrRec
HFP vented from Foreshots Receiver
0.00 kg HFP x
0.33 kg FsRec
VOC Emissions
•
Vinyl Ethers North (NS-B)
PSEPVE Process Emissions
Page 2 of 18
CAS No. 116-15-4
0.15 kgHFP
3.66kgCond2xTVentFZo
0.08 kg HFP
18.76 kg Crude Receiver Vent
0 kg HFP
0.33 kg ForeshotAeceiverVent
535 kg total Condensation Reactor vent stream (22266FG).
21,690 kg total Crude Receiver vent stream (22701FG).
4 kg total Foreshots Receiver vent stream (22826FG).
535 kg CndRx = 21 kg HFP
21,690 kg CrRec = 87 kg HFP
4 kg FsRec = 0 kg HFP
21 kg from Condensation Reactor
87 kg from Crude Receiver
0 kg from Foreshots Receiver
108 kg HFP = 108 kg VOC
238 lb VOC
DEQ-CFW 00069158

•
•
11
Air Emissions Inventory
B. HFPO
Hexafluoropropylene oxide
HF Potential:
HFPO is a VOC without the potential to form HF
Quanta Released
HFPO unreacted in condensation is vented to the WGS.
HFPO vented per the process flowsheet
Vented from the Condensation Reactor:
Vented from the Crude Receiver
Vented from the Foreshots Receiver
HFPO vented based on
HFPO vented based on
HFPO vented based on
HFPO vented from Condensation Reactor:
3.28 kg HFPO x
3.66 kg CndRx
HFPO vented from Crude Receiver
0.00 kg HFPO x
18.76 kg CrRec
HFPO vented from Foreshots Receiver
0.00 kg HFPO x
0.33 kg FsRec
VOC Emissions
Vinyl Ethers North (NS-B)
PSEPVE Process Emissions
Page 3 of 18
CAS No. 428-59-1
3.28 kg HFPO
3.66 kg Cond Rx Vent Flow
0 kg HFPO
18.76 kg Crude Receiver Vent
0gHFPO
tRe0.33 kg FOrh
535 kg total Condensation Reactor vent stream (22266FG).
21,690 kg total Crude Receiver vent stream (22701FG).
4 kg total Foreshots Receiver vent stream (22826FG).
535 kg CndRx = 480 kg HFPO
21,690 kg CrRec = 0 kg HFPO
4 kg FsRec = 0 kg HFPO
480 kg from Condensation Reactor
0 kg from Crude Receiver
0 kg from Foreshots Receiver
480 kg HFPO =
480 kg VOC
1,055 lb VOC
DEQ-CFW 00069159

•
•
•
C. PPF
Perfluoropropionyl fluoride
HF Potential:
Ea
Air Emissions Inventory
Vinyl Ethers North (NS-B)
PSEPVE Process Emissions
Page 4 of 18
CAS No. 422-61-7
ch mole of PPF (MW = 166) can generate 1 mole of HF (MW = 20).
1 k PPF,.1 molePPF 20 g HF 1 moleHF = 0.120kg HF
g 166g PPF 1 moleHF 1 molePPF
Therefore, each 1 kg of PPF generates
Quantity Released
Before -control PPF vented per the process flowsheet
Vented from the Condensation Reactor:
Vented from the Crude Receiver
Vented from the Foreshots Receiver
0.120 kg of HF
0.20 kg PPF
3.66 kg Cond Rx Vent Flow
0 kg PPF
18.76 kg Crude Re ceiver Vent
0 kg PPF
0.33 kg ForeshotsReceiver Vent
PPF vented based on
535 kg total Condensation Reactor vent stream (22266FG).
PPF vented based on
21,690 kg total Crude Receiver vent stream (22701 FG).
PPF vented based on
4 kg total Foreshots Receiver vent stream (22826FG).
Before control PPF vented from Condensation Reactor:
0.20 kg PPF x
535 kg CndRx = 30 kg PPF
3.66 kg CndRx
PPF vented from Crude Receiver
0.00 kg PPF x
21,690 kg CrRec = 0 kg PPF
18.76 kg CrRec
PPF vented from Foreshots Receiver
0.00 kg PPF x
4 kg FsRec = 0 kg PPF
0.33 kg FsRec
Total before -control PPF vented
= 30 kg PPF
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
VOC Emissions
30 kg PPF
Waste Gas Scrubber
x (100%-99.6%) Control Efficiency
= 0.12 kg PAF = 0.12 kg VOC
0.26 Ib. VOC
HF Equivalent Emissions 0 kg PPF
x 0.120 kg HF/kg PPF
= 0.01 kg HF 0.03 lb. HF
DEQ-CFW 00069160

Ej
•
Air Emissions Inventory
D. TFE
Tetrafluoroethylene
HF Potential:
TFE is a VOC without the potential to form HF
Quantity Released
TFE is a byproduct that can be formed in the ABR system. It is an inert in VE-North that is
vented to the WGS.
TFE vented per the process flowsheet
Vinyl Ethers North (NS-B)
PSEPVE Process Emissions
Page 5 of 18
CAS No. 116-14-3
0 kg TFE
Vented from the Condensation Reactor: 3.66 kg Cond Rx Vent Flow
0.19 kg TFE
Vented from the Crude Receiver 18.76 kg Crude Receiver Vent
0 kg TFE
h .� Y
Vented from the Foreshots Receiver 0.33 kg Fores of ecezver en
TFE vented based on 535 kg total Condensation Reactor vent stream (22266FG).
TFE vented based on 21,690 kg total Crude Receiver vent stream (22701FG).
TFE vented based on 4 kg total Foreshots Receiver vent stream (22826FG).
TFE vented from Condensation Reactor:
0.00 x
3.66 kg TFE
kg CndRx
TFE vented from Crude Receiver
0.19 x
18.76 kg TFE
kg CrRec
TFE vented from Foreshots Receiver
0.00 x
0.33 kg TFE
kg FsRec
VOC Emissions
535 kg CndRx = 0 kg TFE
21,690 kg CrRec = 217 kg TFE
4 kg FsRec = 0 kg TFE
0 kg from Condensation Reactor
217 kg from Crude Receiver
0 kg from Foreshots Receiver
217 kg TFE = 217 kg VOC
477 lb VOC
DEQ-CFW 00069161

Air Emissions Inventory
Vinyl Ethers North (NS-B)
PSEPVE Process Emissions
Page 6 of 18
E. PSEPVE CAS No. 1623-5-8
Perfluoro-2-(2-Fluorosulfonylethoxy) Propyl Vinyl Ether
HF Potential:
PSEPVE is a VOC without the potential to form HF
Quantity Released
PSEPVE vented per the process flowsheet
0 kg PSEPVE
Vented from the Condensation Reactor: 3.66 kg Cond Rx Vent Flow
0 kg PSEP VE
Vented from the Crude Receiver 18.76 kg Crude Receiver Vent
0.07 kg PSEP VE
Vented from the Foreshots Receiver 0.33 kg ForeshotsReceiverVen
PSEPVE vented based on 535 kg total Condensation Reactor vent stream (2226617G).
PSEPVE vented based on 21,690 kg total Crude Receiver vent stream (22701FG).
PSEPVE vented based on 4 kg total Foreshots Receiver vent stream (22826FG).
PSEPVE vented from Condensation Reactor:
0.00 x 535 kg CndRx = 0 kg PSEPVE
3.66 kg PSEPVE
kg CndRx
PSEPVE vented from Crude Receiver
0.00 x 21,690 kg CrRec = 0 kg PSEPVE
18.76 kg PSEPVE
kg CrRec
PSEPVE vented from Foreshots Receiver
0.07 x 4 kg FsRec = 0.84 kg PSEPVE
0.33 kg PSEPVE
kg FsRec
VOC Emissions 0 kg from Condensation Reactor
+ 0 kg from Crude Receiver
+ 0.84 kg from Foreshots Receiver
0.84 kg PSEPVE = 0.84 kg VOC
1.84 lb VOC
DEQ-CFW 00069162

Air Emissions Inventory
F. C4
Perfluoro-2-butene
HF Potential:
C4s are VOCs without the potential to form HF
Quantity Released
C4s are perfluorobutenes that are byproducts from the Agitated Bed Reactor system.
They are inerts in VE-North that is vented to the WGS.
C4s vented per the process flowsheet
Vinyl Ethers North (NS-B)
PSEPVE Process Emissions
Page 7 of 18
CAS No. 360-89-4
0 C4
Vented from the Condensation Reactor:
3.66 kg Cond Rx Vent Flow
0.41 kg C4
Vented from the Crude Receiver
18.76 kg Crude Receiver Vent
0.10 kg C4
Vented from the Foreshots Receiver
0.33 kg Foreshot3Receiver Vent
C4s vented based on
535 kg total Condensation Reactor vent stream (22266FG).
C4s vented based on
21,690 kg total Crude Receiver vent stream (22701FG).
C4s vented based on
4 kg total Foreshots Receiver vent stream (22826FG).
C4s vented from Condensation Reactor:
0.00
x 535 kg CndRx = 0 kg C4s
3.66 kg C4s
kg CndRx
C4s vented from Crude Receiver
0.41
x 21,690 kg CrRec = 477 kg C4s
18.76 kg C4s
kg CrRec
C4s vented from Foreshots Receiver
0.10
x 4 kg FsRec = 1 kg C4s
0.33 kg C4s
kg FsRec
VOC Emissions
0 kg from Condensation Reactor
+ 477 kg from Crude Receiver
+ 1 kg from Foreshots Receiver
=
478 kg C4s = 478 kg VOC
1,052 lb VOC
DEQ-CFW 00069163

Air Emissions Inventory Vinyl Ethers North (NS-B)
PSEPVE Process Emissions
Page 8 of 18
G. HFPO Trimer
Perfluoro-2,5-Dimethyl-3,6-Dioxanonan oyl
HF Potential:
Each mole of HFPO Trimer (MW = 498) can generate 1 mole of HF (MW = 20).
k MA• 1 moleTrimer 20 g HF 1 moleHF _ 0.0402kg Hf
g 498g Trimer 1 moleHF 1 moleTrimer
Therefore, each 1 kg of HFPO Trimer generates
Quantity Released
HFPO Trimer is a byproduct formed in the Condensation Reactor system
0.040 kg of HF
CAS No. 2641-34-1
HFPO Trimer vented per the process flowsheet 0 kg HFPO Trimer
Vented from the Condensation Reactor: 3.66 kg Cond Rx Vent Flow
0 kg HFPOTrimer
Vented from the Crude Receiver:
18.76 kg Crude Re ceiver Vent
0.01 kg HFPOTrimer
Vented from the Foreshots Receiver: 0.33 kg ForeshotsReceiverVen
HFPO Trimer vented based on 535 kg total Condensation Reactor vent stream (22266FG).
HFPO Trimer vented based on 21,690 kg total Crude Receiver vent stream (22701FG).
HFPO Trimer vented based on 4 kg total Foreshots Receiver vent stream (22826FG).
Before control 14FPO Trimer vented from Condensation Reactor:
0.00 x 535 kg CndRx — 0 kg HFPO Trimer
3.66 kg HFPO Trimer
kg CndRx
HFPO Trimer vented from Crude Receiver
0.00 x 21,690 kg CrRec — 0 kg HFPO Trimer
18.76 kg HFPO Trimer
kg CrRec
HFPO Trimer vented from Foreshots Receiver
0.01 x 4 kg FsRec = 0.17 kg HFPO Trimer
0.33 kg 14FPO Trimer
kg FsRec
Total before -control HFPO Trimer vented 0.17 kg VOC
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
VOC Emissions 1 0.17 kg HFPO Trimer
Waste Gas Scrubber x (100%-99.6%) Control Efficiency
= 0.0007 kg HFPO Trimer = 0.0007 kg VOC
0.001 Ib. VOC
HF Equivalent Emissions 0.0007 kg HFPO Trimer
x 0.040 kg HF/kg HFPO Trimer
0 0.00003 kg HF 0.00006 Ib. HF
DEQ-CFW 00069164

r�
�J
Air Emissions Inventory
H. Monoadduct (MA)
Tetrafluoro-2-[Tetrafluoro-2-(Fluorosulfonyl)Ethoxy]-Propanoyl Fluoride
HF Potential:
Vinyl Ethers North (NS-B)
PSEPVE Process Emissions
Page 9 of 18
CAS No. 4089-57-0
ach mole of MA MW = 346) can generate 1 mole of HF (MW = 20).
1kgMA•
1 mole MA 20 g HF 1 mole HF
=0.058kgHl
346 g MA 1 mole HF 1 mole MA
Therefore, each 1 kg of MA generates
Quantity Released
Before -control MA vented per the process flowsheet
Vented from the Condensation Reactor:
Vented from the Crude Receiver
Vented from the Foreshots Receiver
MA vented based on
MA vented based on
MA vented based on
Before control MA vented from Condensation Reactor:
0.00 kg MA x
3.66 kg CndRx
MA vented from Crude Receiver
0.00 kg MA x
18.76 kg CrRec
MA vented from Foreshots Receiver
0.0045 kg MA x
0.33 kg FsRec
Total before -control MA vented
0.058 kg of HF
0 kg MA
3.66 kg Cond Rx Vent Flow
0kgMA
18.76 kg Crude Receiver Vent
0.0045 kg MA
0.33 kg ForeshotsR ceiverVen
535 kg total Condensation Reactor vent stream (22266FG).
21,690 kg total Crude Receiver vent stream (22701FG).
4 kg total Foreshots Receiver vent stream (22826FG).
535 kg CndRx = 0 kg MA
21,690 kg CrRec = 0 kg MA
4 kg FsRec = 0.056 kg MA
= 0.056 kg MA
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
VOC Emissions 0.056 kg MA
Waste Gas Scrubber x (100%-99.6%) Control Efficiency
0.00022 kg MA = 0.00022 kg VOC
= 0.000 lb. VOC
HF Equivalent Emissions
0.00022 kg MA
x 0.058 kg HF/kg MA
= 0.00 kg HF 0.00 lb. HF
DEQ-CFW 00069165

•
•
•
Air Emissions Inventory
Vinyl Ethers North (NS-B)
PSEPVE Process Emissions
Page 10 of 18
I. Diadduct (DA) CAS No. 4089-58-1
Tetrafluoro-2[Hexafluoro-2-(Tetrafluoro-2-(Fluorosulfonyl)Ethoxy) Propoxy Propionyl Fluoride
HF Potential:
E _
1 k MA-1 mole DA 20 g HF 1 mole HF _ 0.039 kg HF
g 512 g DA 1 mole HF 1 mole DA
Therefore, each 1 kg of DA generates
Quantity Released
Before -control DA vented per the process flowsheet
Vented from the Condensation Reactor:
Vented from the Crude Receiver
Vented from the Foreshots Receiver
0.039 kg of HF
0 kg DA
3.66 kg Cond Rx Vent Flow
0kgDA
18.76 kg Crude Re ceiver Vent
0.13 kg DA
0.33 kg Foreshot ReceiverVen
DA vented based on 535 kg total Condensation Reactor vent stream (22266FG).
DA vented based on 21,690 kg total Crude Receiver vent stream (22701FG).
DA vented based on 4 kg total Foreshots Receiver vent stream (22826FG).
Before control DA vented from Condensation Reactor:
0.00 kg DA x 535 kg CndRx =
3.66 kg CndRx
DA vented from Crude Receiver
0.00 kg DA x 21,690 kg CrRec =
18.76 kg CrRec
DA vented from Foreshots Receiver
0.13 kg DA x 4 kg FsRec =
0.33 kg FsRec
Total before -control DA vented =
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
VOC Emissions 1.62 kg DA
Waste Gas Scrubber x (100%-99.6%) Control Efficiency
0.0065 kg DA
HF Equivalent Emissions 0.0065 kg DA
x 0.039 kg HF/kg DA
0.00025 kg HF =
0 kg DA
0 kg DA
1.62 kg DA
1.62 kg DA
= 0.006 kg VOC
= 0.014 lb. VOC
0.00 lb. HF
DEQ-CFW 00069166

•
Air Emissions Inventory Vinyl Ethers North (NS-B)
PSEPVE Process Emissions
Page 11 of 18
J. Hydro PSEPVE
Tetrafluoro-2-[Trifluoro-2-(1,2,2,2-Tetra-fluoroethoxy)-1-(Trifluoromethyl) Ethoxy)-
Ethane Sulfonyl Fluoride
HF Potential:
Hydro-PSEPVE is a VOC without the potential to form HF
Quantity Released
Hydro-PSEPVE vented per the process tlowsheet
Vented from the Condensation Reactor:
Vented from the Crude Receiver
Vented from the Foreshots Receiver
0 kg Hydro — PSEPVE
3.66 kg Cond Rx Vent Flow
0 kg Hydro— PSEPVE
18.76 kg Crude Receiver Vent
0.0045 kg Hydro— PSEPVE
0.33 kg ForeshotsReceiver Vent
CAS No. 755-02-9
Hydro-PSEPVE vented based on 535 kg total Condensation Reactor vent stream (22266FG).
Hydro-PSEPVE vented based on 21,690 kg total Crude Receiver vent stream (22701FG).
Hydro-PSEPVE vented based on 4 kg total Foreshots Receiver vent stream (22826FG).
Hydro-PSEPVE vented from Condensation Reactor:
0.00 kg Hydro-PSEPVE x 535 kg CndRx = 0 kg Hydro-PSEPVE
3.66 kg CndRx
Hydro-PSEPVE vented from Crude Receiver
0.00 kg Hydro-PSEPVE x 21,690 kg CrRec = 0 kg Hydro-PSEPVE
18.76 kg CrRec
Hydro-PSEPVE vented from Foreshots Receiver
0.0045 kg Hydro-PSEPVE x 4 kg FsRec = 0.056 kg Hydro-PSEPVE
0.33 kg FsRec
VOC Emissions 0 kg from Condensation Reactor
+ 0 kg from Crude Receiver
+ 0.056 kg from Foreshots Receiver
0.056 kg Hydro-PSEPV = 0.056 kg VOC
0.123 lb VOC
DEQ-CFW 00069167

•
•
Air Emissions Inventory
K. Iso-PSEPVE
Perfluoro-1-Methyl-2-(2 Fluorosulfonyl Ethoxy) Ethyl Vinyl Ether
HF Potential:
Iso-PSEPVE is a VOC without the potential to form HF
Quantity Released
Iso-PSEPVE vented per the process flowsheet
0 kg Iso — PSEPVE
Vented from the Condensation Reactor: I 3.66 kg Cond Rx Vent Flow
0 kg Iso — PSEP VE
Vented from the Crude Receiver 18.76 kg Crude Receiver Vent
0.014 kg Iso — PSEPVE
0 014 kg Foreshots Receiver Vent
Vinyl Ethers North (NS-B)
PSEPVE Process Emissions
Page 12 of 18
Vented from the Foreshots Receiver
Iso-PSEPVE vented based on 535 kg total Condensation Reactor vent stream (22266FG).
Iso-PSEPVE vented based on 21,690 kg total Crude Receiver vent stream (22701FG).
Iso-PSEPVE vented based on 4 kg total Foreshots Receiver vent stream (22826FG).
Iso-PSEPVE vented from Condensation Reactor:
0.00 kg Iso-PSEPVE x
3.66 kg CndRx
Iso-PSEPVE vented from Crude Receiver
0.00 kg Iso-PSEPVE x
18.76 kg CrRec
Iso-PSEPVE vented from Foreshots Receiver
0.014 kg Iso-PSEPVE x
0.33 kg FsRec
VOC Emissions
CAS No. 34805-58-8
535 kg CndRx = 0 kg Iso-PSEPVE
21,690 kg CrRec = 0 kg Iso-PSEPVE
4 kg FsRec = 0.168 kg Iso-PSEPVE
0 kg from Condensation Reactor
0 kg from Crude Receiver
0.168 kg from Foreshots Receiver
0.168 kg Iso-PSEPVE = 0.168 kg VOC
0.369 Ib VOC
DEQ-CFW 00069168

Air Emissions Inventory Vinyl Ethers North (NS-B) ✓
PSEPVE Process Emissions
Page 13of18
L. Diglyme
The emissions of diglyme is based on a mass balance
(Quantity Released
CAS No. 111-96-6
= 4,631 kg diglyme introduced into processes
= 4,631 kg diglyme transferred to H/C waste tank
0 kg diglyme unaccounted for and assumed emitted
0 lb.Diglyme
Emissions of diglyme from PSEPVE = 0 lb. Diglyme
•
•
DEQ-CFW 00069169

•
•
•
Air Emissions Inventory
M. Sulfonyl Fluoride (SOF2)
HF Potential:
Each mole of SOF2 (MW = 86) can generate 2 mole of HF (MW = 20).
kgMA• 1 moleSOF2 20g HF 2 moleHF _ 0.465kgH1
86 g SOF2 1 moleHF 1 moleSOF2
Therefore, each 1 kg of SOF2 generates 0.465 kg of HF
Quantity Released
Before -control SOF2 vented per the process flowsheet
Vinyl Ethers North (NS-B)
PSEPVE Process Emissions
Page 14 of 18
CAS No. 7783-42-8
Vented from the Condensation Reactor:
0 kg SOF2
13.66
kg Cond Rx Vent Flow
Vented from the Crude Receiver
0 kg SOF2
18.76 kg Crude Receiver Vent
0 kg SOF2
Vented from the Foreshots Receiver
0.33 kg Foreshots ReceiverVen
SOF2 vented based on
535 kg total Condensation Reactor vent stream (22266FG).
SOF2 vented based on
21,690 kg total Crude Receiver vent stream (22701FG).
SOF2 vented based on
4 kg total Foreshots Receiver vent stream (22826FG).
Before control SOF2 vented from Condensation Reactor
0.00 kg SOF2 x
535 kg CndRx =
0 kg SOF2
3.66 kg CndRx
SOF2 vented from Crude Receiver
0.00 kg SOF2 x
21,690 kg CrRec =
0 kg SOF2
18.76 kg CrRec
SOF2 vented from Foreshots Receiver
0.00 kg SOF2 x
4 kg FsRec =
0 kg SOF2
0.33 kg FsRec
Total before -control SOF2 vented
=
0 kg SOF2
After -control emissions utilizing the 99.6% control
efficient Waste Gas Scrubber (WGS):
SOF2 Emissions
0 kg SOF2
Waste Gas Scrubber
x (100%-99.6%) Control Efficiency
= 0 kg SOF2
0 lb. SOF2
HF Equivalent Emissions 0 kg SOF2
x 0.465 kg HF/kg SOF2
= 0.00 kg HF 0.00 lb. HF
S0172 is not a VOC (no carbon)
DEQ-CFW 00069170

Air Emissions Inventory Vinyl Ethers North (NS-B)
PSEPVE Process Emissions
Page 15 of 18
N. Carbon Dioxide (CO2)
Quantity Released
CO2 is a byproduct from the Agitated Bed Reactor system.
They are inerts in VE-North that are vented to the WGS.
CO2 vented per the process flowsheet
CAS No. 124-38-9
0 CO2
Vented from the Condensation Reactor:
3.66 kg Cond Rx Vent Flow
17.45 kg CO2
Vented from the Crude Receiver
18.76 kg Crude Receiver Vent
0 kg CO2
Vented from the Foreshots Receiver
0.33 kg ForeshotReceiverVen
CO vented based on
535 kg total Condensation Reactor vent stream (22266FG).
CO vented based on
21,690 kg total Crude Receiver vent stream (22701FG).
CO vented based on
4 kg total Foreshots Receiver vent stream (22826FG).
CO2 vented from Condensation Reactor:
0.00
x 535 kg CndRx — 0 kg CO2
3.66 kg CO
kg CndRx
CO2 vented from Crude Receiver
17.45
x 21,690 kg CrRec = 20,171 kg CO2
18.76 kg CO2
kg CrRec
CO2 vented from Foreshots Receiver
0.00
x 4 kg FsRec = 0 kg CO2
0.33 kg CO2
kg FsRec
CO2 Emissions Exit WGS
0 kg from Condensation Reactor
+ 81 kg from Crude Receiver
+ 0 kg from Foreshots Receiver
= 81 kg CO2 = 178 lb CO2
(not a VOC)
DEQ-CFW 00069171

O. VOC Summary
C
Air Emissions Inventory Vinyl Ethers North (NS-B)
PSEPVE Process Emissions
Page 16 of 18
Nafion Compound Name
Before Control
Generated
After Control
Stack Emissions
VOC
HF
kg/yr
Ib/yr
Ib/yr
Ib/yr
A.
HFP
108
238
238
B.
HFPO
480
1057
1,057
C.
PPF
30
66
0.26
0.03
D.
TFE
217
1 478
478
E.
PSEPVE
1
2
2
F.
C4
478
1055
1,055
G.
HFPO Trimer
0.17
0
0.00
0.00
H.
MA
0.06
0
0.000
0.00
I.
DA
1.62
4
0.01
0.00
J.
Hydro PSEPVE
0.06
0.1
0.1
K.
Iso PSEPVE
0.17
0
0
L.
Diglyme
0
0
0
M.
SOF2 (not a VOC)
N.
CO2 (not a VOC)
0
Total
1,316
1 2,901
1 2,831
0.0
DEQ-CFW 00069172

•
Air Emissions Inventory Vinyl Ethers North (NS-B) V
PSEPVE Process Emissions
Page 17 of 18
P. Total Emission Summary**
** All Fm;cc;nnc ;n th;c tahlP re.nre,eent "After Control" emissions
Naf►on Compound Name
Stack
Emissions
lb/yr
Equipment
Emissions (Noft1)
lb/yr
Maintenance
Emissions (Note 2)
lb/yr
Total
Emissions
lb/yr
A. JHIFP
238
31
27
296
B. jHFPO
1,057
141
6
1,205
C. JPPF
0.26
0
0
0
D.
TFE
478
0
0
478
E.
PSEPVE
2
275
0
277
F.
C4
1;055
21
20
1,095
G.
BFPO Trimer
0.00
0
0
0
H.
MA
0.00
0
5
6
I.
DA
0.01
2
12
14
J.
Hydro-PSEPVE
0.1
0
0
0
K.
Iso-PSEPVE
0.4
0
0
0
L.
IDiglyme
70
3
0
M.
I SOF2 (not a VOC)
0.0
0
0
0
N.
I CO2 (not a VOC)
0
0
178
*
ITA
0
0
0
*
RSU
0
0
0
*
HFPO-Dimer
0
0
0
Total
2,831
0
0
3,550
Note 1 - See section titled "Equipment Emissions" for details
Note 2 - See section titled "Maintenance Emissions" for details
N CO not realistically expected through equipment or maintenance emissions
L. Diglyme total based on material balance, see section L
* Not normally emitted from the process as a routine stack emission
Total Non AF 2,831
Total AF 0.28
DEQ-CFW 00069173

•
•
Air Emissions Inventory
HF Equivalent Emissions
Vinyl Ethers North (NS-B) v
PSEPVE Process Emissions
Page 18 of 18
Nafion Compound Name
Stack
Emissions
lb/yr
Equipment
Emissions
lb/yr
Maintenance
Emissions
tb/yr
Total
Emissions
tb/yr
C.
PPF
0.03
0.00
0.01
0.04
G.
HFPO Trimer
0.00
0.00
0.01
0.01
H.
IMA
0.00
0.03
0.30
0.33
I.
1 DA
0.00
0.08
0.46
0.54
M.
I SOF2
0.00
0.00
*
*
ITA
RSU
0.00
0.00
0.01
0.00
0.01
0.01
*
HFPO-Dimer
0.00
0.02
0.02
Total
0.03
0.11
0.78
0.92
The estimated HF equivalent emissions were determined by multiplying the total emission quantity of an acid
fluoride by the ratio of the molecular weight of HF divided by the molecular weight of the specific acid fluoride.
This is based on the fact that one mole of an acid fluoride will generate one mole of HF.
For example, if 100 lb. of PPF was emitted:
20 lb/mol HF
166 lb/mol PPF
X 100 lb/yr Equipment PPF
= 12.0 lb/yr HF
DEQ-CFW 00069174

Air Emissions Inventory Vinyl Ethers North (NS-B)
PPVE Process Emissions
Page 1 of 13
0 2015 AIR EMISSIONS INVENTORY SUPPORTING DOCUMENTATION
•
Emission Source ID No: NS-B
Emission Source Description: VE-North PPVE Manufacturing Process
Process & Emission Description: The VE-North PPVE manufacturing process is a continuous chemical
reaction. All emissions from the process are vented through the Nafton Division Waste Gas Scrubber
(Control Device lD No. NCD-Hdr) which has a documented control efficiency of 99.1% for all acid fluoride
compounds. Some emitted compounds are assumed to pass completely through the scrubber, so the control
efficiency for those compounds is assumed to be 0%. The control of emissions of specific compounds will
be addressed and detailed in the following pages.
The PPVE process in VE-North emits compounds in the acid fluoride family. In the presence of water (such
as in atmospheric moisture), these acid fluorides can eventually hydrolyze to hydrogen fluoride. For the
purpose of this emissions inventory, a conservative approach will be taken and the acid fluorides will be
reported both as a VOC and as the equivalent quantity of hydrogen fluoride.
Basis and Assumptions:
- The PPVE process flowsheet is the basis for relative concentrations of before -control emissions of
gaseous wastes.
- Calculations of point source emissions are based on actual vent flow totals taken from the IP21 Historian.
DEQ-CFW 00069175

Vinyl Ethers North NS-B
Air Emissions Inventory Y ( )
PPVE Process Emissions
Page 2 of 13
Point Source Emission Determination
A. Hexafluoropropylene (HFP)
HF Potential:
HFP is a VOC without the potential to form HF
Quantity Released
HFP is a byproduct present in the HFPO feed. It is an inert in VE-North that is
vented to the WGS.
CAS No. 116-15-4
HFP vented per the process flowsheet
0.05 kg HFP
Vented from the Condensation Reactor: 2.35 kg CondRxVentFlO
0.00 kg HFP
Vented from the Crude Receiver
3.97 kg Crude Re ceiver Vent
0.01 kg HFP
Vented from the Foreshots Receiver FO6 Fore shotsReceiverVen
30 kg HFP
100 kg Stripper Vent
Vented from the Stripper
HFP vented based on
2,450 kg total Condensation Reactor vent stream (22266FG).
HFP vented based on
15,726 kg total Crude Receiver vent stream (22701FG).
HFP vented based on
1,021 kg total Foreshots Receiver vent stream (22826FG).
HFP vented based on
16,780 kg in the Stripper vent stream (22231FC).
HFP vented from Condensation Reactor:
0.05 kg HFP x
2,450 kg CndRx = 57 kg HFP
2.35 kg CndRx
HFP vented from Crude Receiver
0.00 kg HFP x
15,726 kg CrRec = 0 kg HFP
3.97 kg CrRec
HFP vented from Foreshots Receiver
0.01 kg HFP x
1,021 kg FsRec = 9 kg HFP
1.06 kg FsRec
HFP vented from Stripper
30 kg HFP x
16,780 kg Strpr = 5,034 kg HFP
100 kg Strpr
VOC Emissions
57 kg from Condensation Reactor
+
0 kg from Crude Receiver
+
9 kg from Foreshots Receiver
5,034 kg from Stripper
—
—
5,099 kg HFP 5,099 kg VOC
11,242 lb VOC
DEQ-CFW 00069176

E
•
LJ
Air Emissions Inventory
B. Hexafluoropropylene oxide (HFPO)
HF Potential:
HFPO is a VOC without the potential to form HF
Quantity Released
HFPO unreacted in condensation is vented to the WGS.
HFPO vented per the process flowsheet
Vinyl Ethers North (NS-B)
PPVE Process Emissions
Page 3 of 13
CAS No. 428-59-1
0.11 kg HFPO
Vented from the Condensation
Reactor:
2.35 kg Cond Rx Vent Flow
Vented from the Crude Receiver
13.97
0 kg HFPO
kg Crude Receiver Vent
0 kg HFPO
Vented from the Foreshots Receiver
1.06 kg Foreshots3ZeceiverVen
Vented from the Stripper
60 kg HFPO
100 kg Stripper Vent
HFPO vented based on
2,450 kg total Condensation Reactor vent stream (22266FG).
HFPO vented based on
15,726 kg total Crude Receiver vent stream (22701FG).
HFPO vented based on
1,021 kg total Foreshots Receiver vent stream (22826FG).
HFP vented based on
16,780 kg in the Stripper vent stream (22231FC).
HFPO vented from Condensation Reactor:
0.11 kg HFPO x
2,450 kg CndRx = 118 kg HFPO
2.35 kg CndRx
HFPO vented from Crude Receiver
0.00 kg HFPO x
15,726 kg CrRec =
0 kg HFPO
3.97 kg CrRec
HFPO vented from Foreshots Receiver
0.00 kg HFPO x
1,021 kg FsRec =
0 kg HFPO
1.06 kg FsRec
HFP vented from Stripper
60 kg HFPO x
16,780 kg Strpr =
10,068 kg HFPO
100 kg Strpr
VOC Emissions
118 kg from Condensation Reactor
+
0 kg from Crude Receiver
+
0 kg from Foreshots Receiver
+
10,068 kg from Stripper
=
10,186 kg HFPO =
10,186 kg VOC
22,457 lb VOC
DEQ-CFW 00069177

•
•
C. Perfluoropropionyl fluoride (PPF)
HF Potential:
EE
Air Emissions Inventory
h mole of PPF (MW = 166) can generate 1 mole of HF (MW = 20).
1 molePPF 20 g HF 1 moleHF
kgPPF- = 0.120kg H1
166g PPF 1 moleHF 1 molePPF
Therefore, each 1 kg of PPF generates 0.120 kg of HF
Quantity Released
Before -control PPF vented per the process flowsheet
Vented from the Condensation Reactor:
2.14 kg PPF
2.35 kg Cond Rx Vent Flow
Vented from the Crude Receiver
0 kg PPF
3.97 kg Crude Receiver Vent
0 kg PPF
Vented from the Foreshots Receiver
1.06 kg ForeshotsReceiverVen
Vented from the Stripper
10 kg PPF
100 kg Stripper Vent
PPF vented based on
2,450 kg total Condensation Reactor vent stream (22266FG).
PPF vented based on
15,726 kg total Crude Receiver vent stream (22701FG).
PPF vented based on
1,021 kg total Foreshots Receiver vent stream (22826FG).
PPF vented based on
16,780 kg in the Stripper vent stream (22231FC).
Before control PPF vented from Condensation Reactor:
2.14 kg PPF x
2,450 kg CndRx = 2,227 kg PPF
2.35 kg CndRx
PPF vented from Crude Receiver
0.00 kg PPF x
15,726 kg CrRec = 0 kg PPF
3.97 kg CrRec
PPF vented from Foreshots Receiver
0.00 kg PPF x 1,021 kg FsRec = 0 kg PPF
L06 kg FsRec
PPF vented from Stripper
10 kg PPF x 16,780 kg Strpr = 1,678 kg PPF
100 kg Strpr
Total before -control PPF vented = 3,905 kg PPF
After -control emissions utilizing the 99.1 % control efficient Waste Gas Scrubber (WGS):
Vinyl Ethers North (NS-B)
PPVE Process Emissions
Page 4 of 13
CAS No. 422-61-7
VOC Emissions 3,905 kg PAF
Waste Gas Scrubber x (100%-99.1%)
35 kg PAF = 35 kg VOC
77 lb. VOC
HF Equivalent Emissions 35 kg PAF
x 0.120 kg HF/kg PAF
4 kg HF = 9.3 lb. HF
DEQ-CFW 00069178

V
Air Emissions Inventory Vinyl Ethers North (NS-B)
PPVE Process Emissions
Page 5 of 13
D. Tetrafluoroethylene (TFE)
HF Potential:
TFE is a VOC without the potential to form HF
Quantity Released
TFE is a byproduct that can be formed in the ABR system. It is an inert in VE-North that is
vented to the WGS.
TFE vented per the process flowsheet
0 kg TFE
Vented from the Condensation Reactor: 2.35 kg Cond Rx Vent Flow
0.0012 kg TFE
Vented from the Crude Receiver 3.97 kg Crude Receiver Vent
0.0045 kg TFE
Vented from the Foreshots Receiver 1.06 kg Foreshot.Receiver Vent
0 kg TFE
Vented from the Stripper 100 kg Stripper Vent
TFE vented based on 2,450 kg total Condensation Reactor vent stream (22266FG).
TFE vented based on 15,726 kg total Crude Receiver vent stream (22701FG).
TFE vented based on 1,021 kg total Foreshots Receiver vent stream (22826FG).
TFE vented based on 16,780 kg in the Stripper vent stream (22231FC).
TFE vented from Condensation Reactor:
0.00 kg TFE x 2,450 kg CndRx = 0 kg TFE
2.35 kg CndRx
TFE vented from Crude Receiver
0.0012 kg TFE x 15,726 kg CrRec = 5 kg TFE
3.97 kg CrRec
TFE vented from Foreshots Receiver
0.0045 kg TFE x 1,021 kg FsRec = 4 kg TFE
1.06 kg FsRec
TFE vented from Stripper
0 kg TFE x 16,780 kg Strpr = 0 kg TFE
100 kg Strpr
VOC Emissions 0 kg from Condensation Reactor
+ 5 kg from Crude Receiver
+ 4 kg from Foreshots Receiver
+ 0 kg from Stripper
9 kg TFE = 9 kg VOC
20 lb VOC
•
CAS No. 116-14-3
DEQ-CFW 00069179

J
Air Emissions Inventory
E. Pertluoropropyl vinyl ether (PPVE)
HF Potential:
PPVE is a VOC without the potential to form HF
Quantity Released
Vinyl Ethers North (NS-B)
PPVE Process Emissions
Page 6 of 13
CAS No. 1623-5-8
PPVE vented per the process flowsheet
0 kg PPVE
Vented from the Condensation Reactor: 2.35 kg Cond Rx Vent Flow
0.002 kg PPVE
Vented from the Crude Receiver 3.97 kg Crude Receiver Vent
0.88 kg PPVE
Vented from the Foreshots Receiver 1.06 kg ForeshotsReceiver Vent
0 kg PPVE
Vented from the Stripper 100 g k RiriPP er Vent
PPVE vented based on
2,450 kg total Condensation Reactor vent stream (22266FG).
PPVE vented based on
15,726 kg total Crude Receiver vent stream (22701FG).
PPVE vented based on
1,021 kg total Foreshots Receiver vent stream (22826FG).
PPVE vented based on
16,780 kg in the Stripper vent stream (22231FC).
PPVE vented from Condensation
Reactor:
0.00 kg PPVE
—
x 2,450 kg CndRx 0 kg PPVE
2.35 kg CndRx
PPVE vented from Crude Receiver
0.0020 kg PPVE
x 15,726 kg CrRec = 8 kg PPVE
3.97 kg CrRec
PPVE vented from Foreshots
Receiver
0.88 kg PPVE
x 1,021 kg FsRec = 847 kg PPVE
1.06 kg FsRec
PPVE vented from Stripper
0 kg PPVE
x 16,780 kg Strpr = 0 kg PPVE
100 kg Strpr
VOC Emissions 0 kg from Condensation Reactor
+ 8 kg from Crude Receiver
+ 847 kg from Foreshots Receiver
+ 0 kg from Stripper
854 kg PPVE = 854 kg VOC
1,884 lb VOC
L,
DEQ-CFW 00069180

Air Emissions Inventory Vinyl Ethers North (NS-B)
PPVE Process Emissions
Page 7 of 13
isF. Perfluoro-2-butene (C4)
HF Potential:
C4s are VOCs without the potential to form HF
Quantity Released
C4s are perfluorobutenes that are byproducts from the Agitated Bed Reactor system.
They are inerts in VE-North that are vented to the WGS.
C4s vented per the process flowsheet
0 kg C4s
Vented from the Condensation Reactor: 2.35 kg Cond Rx Vent Flow
0.0012 kg C4s
Vented from the Crude Receiver 3.97 kg Crude Re ceiver Vent
0.15 kg C4s
Vented from the Foreshots Receiver 1.06 kg ForeshotsReceiver Vent
0 kg C4s
Vented from the Stripper 100 kg Stripper Vent
C4s vented based on 2,450 kg total Condensation Reactor vent stream (22266FG).
C4s vented based on 15,726 kg total Crude Receiver vent stream (22701FG).
C4s vented based on 1,021 kg total Foreshots Receiver vent stream (22826FG).
C4s vented based on 16,780 kg in the Stripper vent stream (22231FC).
C4s vented from Condensation Reactor:
0.00 kg C4s x 2,450 kg CndRx = 0 kg C4s
2.35 kg CndRx
C4s vented from Crude Receiver
0.0012 kg C4s x 15,726 kg CrRec = 5 kg C4s
3.97 kg CrRec
C4s vented from Foreshots Receiver
0.15 kg C4s x 1,021 kg FsRec = 144 kg C4s
1.06 kg FsRec
C4s vented from Stripper
0 kg C4s x 16,780 kg Strpr = 0 kg C4s
100 kg Strpr
VOC Emissions 0 kg from Condensation Reactor
+ 5 kg from Crude Receiver
+ 144 kg from Foreshots Receiver
+ 0 kg from Stripper
149 kg C4s = 149 kg VOC
328 lb VOC
•
CAS No. 360-89-4
DEQ-CFW 00069181

•
•
0
Air Emissions Inventory
G. Perfluoropentene (C5)
HF Potential:
C5s are VOCs without the potential to form HF
Quantity Released
C5s are perfluoropentenes that are byproducts from the Agitated Bed Reactor system.
They are inerts in VE-North that are vented to the WGS.
C5s vented per the process flowsheet
0 kg C5s
Vented from the Condensation Reactor:
2.35 kg Cond P.x Vent Flow
0kgC5s
Vented from the Crude Receiver
3.97 kg Crude Re ceiver Vent
0.02 kg C5s
Vented from the Foreshots Receiver
1.06 kg ForeshokReceiver Vent
Vented from the Stripper
0 kg C5s
100 kg Stripper Vent
C5s vented based on 2,450
kg total Condensation Reactor vent stream (22266FG).
CSs vented based on 15,726
kg total Crude Receiver vent stream (22701FG).
C5s vented based on 1,021
kg total Foreshots Receiver vent stream (22826FG).
C5s vented based on 16,780
kg in the Stripper vent stream (22231FC).
C5s vented from Condensation Reactor:
0.00 kg C5s x
2,450 kg CndRx = 0 kg C5s
2.35 kg CndRx
C5s vented from Crude Receiver
0.00 kg C5s x
15,726 kg CrRec = 0 kg C5s
3.97 kg CrRec
C5s vented from Foreshots Receiver
0.02 kg C5s x
1,021 kg FsRec = 17 kg C5s
1.06 kg FsRec
C4s vented from Stripper
0 kg C5s x
16,780 kg Strpr = 0 kg C5s
100 kg Strpr
VOC Emissions
0 kg from Condensation Reactor
+ 0 kg from Crude Receiver
+ 17 kg from Foreshots Receiver
+ 0 kg from Stripper
17 kg C5s = 17 kg VOC
38 lb VOC
Vinyl Ethers North (NS-B)
PPVE Process Emissions
Page 8 of 13
CAS No. 376-87-4
DEQ-CFW 00069182

•
•
Air Emissions Inventory
H. Carbon Dioxide (CO2)
HF Potential:
CO2 can not form HF
Quantity Released
CO2 is a byproduct from the Agitated Bed Reactor system.
They are inerts in VE-North that are vented to the WGS.
CO2 vented per the process flowsheet
0kgCO
Vented from the Condensation Reactor: 2.35 kg Cond Rx Vent Flow
1.27 kg CO
Vented from the Crude Receiver 3.97 kg Crude Re ceiver Vent
0 kg CO
Vented from the Foreshots Receiver 1.06 kg ForeshooReceiver Vent
0 kg CO
Vented from the Stripper [TO 0 kg Stripper Vent
CO2 vented based on 2,450 kg total Condensation Reactor vent stream (22266FG).
CO2 vented based on 15,726 kg total Crude Receiver vent stream (22701FG).
CO2 vented based on 1,021 kg total Foreshots Receiver vent stream (22826FG).
CO2 vented based on 16,780 kg in the Stripper vent stream (22231FC).
CO2 vented from Condensation Reactor:
0.00 kg CO2 x 2,450 kg CndRx = 0 kg CO2
2.35 kg CndRx
CO2 vented from Crude Receiver
3.45 kg CO2 x 15,726 kg CrRec = 13,682 kg CO2
3.97 kg CrRec
Vinyl Ethers North (NS-B)
PPVE Process Emissions
Page 9 of 13
CAS No. 124-38-9
CO2 vented from Foreshots Receiver
0.00 kg CO2 x 1,021 kg FsRec = 01kg CO2
1.06 kg FsRec
CO2 vented from Stripper
0 kg CO2 x 16,780 kg Strpr = 0 kg CO2
100 kg Strpr
CO2 Emissions 0 kg from Condensation Reactor
+ 13,682 kg from Crude Receiver
+ 0 kg from Foreshots Receiver
+ 0 kg from Stripper
13,682 kg CO2 = 30,163 lb CO2 (not a VOC)
DEQ-CFW 00069183

Air Emissions Inventory Vinyl Ethers North (NS-B) .✓_
PPVE Process Emissions
Page 10 of 13
0 I. Acetonitrile (AN)
HF Potential
AN is a VOC and Hazardous Air Polluntant without the potential to form HF.
Quantity Released
AN emissions based on 11,776 kg AN fed
Hydrocarbon waste sent to Hydrocarbon waste tank = 11,776 kgs H/C waste
PPVE generated during the year 202,957 kg PPVE
Assume that: 5% of spent acetonitrile are fluorocarbons.
AN portion of hydrocarbon waste stream:
11,776 kg to H/C waste
x 0-(.1))
11,187 kg AN to H/C waste
Material Balance
Based on total Vinyl ether produced 202,957 kg PPVE
Assume 90% Crude is needed to generage that amount of PPVE
40 70% of AF going to ABR is needed to create the Crude
Feed going to ABR is 1,500 ppm AN
1,000,000
Therefore: 202,957 kg PPVE
\ 0.90 Crude
\ 0.70 AF
x 0.0015 ppm AN
483 kg AN in Feed to ABR
VOC Emission 11,776 kg AN fed
11,187 kg AN to H/C waste
483 kg AN to ABR
106 kg AN
106 kg VOC
233 lb VOC
AN only used during a PPVE Campaign
Total AN 233 lb VOC
•
CAS No. 75-05-8
DEQ-CFW 00069184

Air Emissions Inventory Vinyl Ethers North (NS-B)
PPVE Process Emissions
Page 11 of 13
0 J. VOC Summary
Nafion Compound Name
Before Control
Generated
After Control
Stack Emissions
kglyr Iblyr
VOC
Iblyr
A.
HFP
5,099
11,242
11,242
B.
HFPO
10,186
22,457
22,457
C.
PPF
3,905
8,610
77
D.
TFE
9
20
20
E.
PPVE
854
1,884
1,884
F.
IC4
149
328
328
G.
C5
17
38
38
I.
AN
106
233
233
Total
20,326
44,812
36,279
•
DEQ-CFW 00069185

Air Emissions Inventory Vinyl Ethers North (NS-B)
PPVE Process Emissions
Page 12 of 13
K. Total Emission Summary**
** All Emissions in this table represent "After Control" emissions.
Nafon Compound Name
Process
Emissions
lb/yr
Equipment
Emissions (Note 1)
lb/yr
Maintenance
Emissions (Note2)
lb/yr
Total
Emissions
lb/yr
A.
HFP
11,242
5
0
11,247
B.
HFPO
22,457
331
15
22,803
C.
PPF
77
0
1
79
D.
TFE
20
0
0
20
E.
PPVE
1,884
543
441
2,868
F.
C4
328
53
59
440
G.
C5
38
0
0
38
H.
CO2 (not a VOC)
30,163
0
0
30,163
1.
IAN
233
136
6
375
*
HFPO-Dimer
7
31
38
*
HFPO Trimer
0
1
1
Total
66,443
1,075
555
68,072
Note 1 - See section titled "Equipment Emissions" for details
Note 2 - See section titled "Maintenance Emissions" for details
CO not realistically expected through equipment or maintenance emissions
AN total based on material balance, see section K.
0 * Not normally emitted from the process as a routine stack emission
•
DEQ-CFW 00069186

Air Emissions Inventory
•
L. HF Equivalent Emissions
Vinyl Ethers North (NS-B)
PPVE Process Emissions
Page 13 of 13
Naflon Compound Name
Process
Emissions
lb/yr
Equipment
Emissions
lb/yr
Maintenance
Emissions
lb/yr
Total
Emissions
lb/yr
C.
PPF
9.3
0.0
0.13
9.47
*
HFPO-Dimer
0.4
1.86
2.27
*
HFPO Trimer
0.0
0.03
0.03
Total
9.3
0
2.01
11.77
* Not normally emitted from the process as a routine stack emission
The estimated HF equivalent emissions were determined by multiplying the total emission quantity of an acid
fluoride by the ratio of the molecular weight of HF divided by the molecular weight of the specific acid
fluoride. This is based on the fact that one mole of an acid fluoride will generate one mole of HF,
For example, if 100 lb. of PPF was emitted:
20 lb/mol HF X 100 lb/yr Equipment PPF
166 lb/mol PPF
•
I-]
= 12.0 lb/yr HF
DEQ-CFW 00069187

1
•
0
•
Air Emissions Inventory
2015 AIR EMISSIONS INVENTORY SUPPORTING DOCUMENTATION
Emission Source ID No: NS-B
Emission Source Description: VE-North EVE Manufacturing Process
Vinyl Ethers North (NS-B)
EVE Process Emissions
Page 1 of 13
Process & Emission Description: The VE-North EVE manufacturing process is a continuous chemical reaction.
All emissions from the process are vented through the Nafion Division Waste Gas Scrubber (Control Device 1D No.
NCD-Hdr) which has a documented control efficiency of 99.1 % for all acid fluoride compounds. Some emitted
compounds are assumed to pass completely through the scrubber, so the control efficiency for those compounds is
assumed to be 0%. The control of emissions of specific compounds will be addressed and detailed in the following
pages.
The EVE process in VE-North emits compounds in the acid fluoride family. In the presence of water (such as in
atmospheric moisture), these acid fluorides can eventually hydrolyze to hydrogen fluoride. For the purpose of this
emissions inventory, a conservative approach will be taken and the acid fluorides will be reported both as a VOC and
as the equivalent quantity of hydrogen fluoride.
Basis and Assumptions:
- The EVE process flowsheet is the basis for relative concentrations of before -control emissions of gaseous
wastes.
- Calculations of point source emissions are based on actual vent flow totals taken from the IP21 Historian.
DEQ-CFW 00069188

Air Emissions Inventory
0 Point Source Emission Determination
A. Hexafluoropropylene (HFP)
HF Potential:
HFP is a VOC without the potential to form HF
OgantiV Released
HFP is a byproduct present in the HFPO feed. It is an inert in VE-North that is
vented to the WGS.
HFP vented per the process flowsheet
Vented from the Condensation Reactor:
Vented from the Crude Receiver
Vented from the Foreshots Receiver
HFP vented based on
HFP vented based on
HFP vented based on
HFP vented from Condensation Reactor:
0.17 kg HFP x
0.50 kg CndRx
HFP vented from Crude Receiver
0.00 kg HFP x
15.91 kg CrRec
HFP vented from Foreshots Receiver
0.00 kg HFP x
0.14 kg FsRec
VOC Emissions
•
Vinyl Ethers North (NS-B)
EVE Process Emissions
Page 2 of 13
CAS No. 116-15-4
O 17kgHFP
Q50kgCond2xVenlFlo
0 kg HFP
15.91 kg Crude Receiver Vent
0 kg HFP
0.14 kg ForeshohReceiverVen
190 kg total Condensation Reactor vent stream (22266FG).
2,589 kg total Crude Receiver vent stream (22701FG).
2 kg total Foreshots Receiver vent stream (22826FG).
190 kg CndRx = 66 kg HFP
2,589 kg CrRec = 0 kg HFP
2 kg FsRec = 0 kg HFP
66 kg from Condensation Reactor
0 kg from Crude Receiver
0 kg from Foreshots Receiver
66 kg HFP =
66 kg VOC
146 lb VOC
DEQ-CFW 00069189

•
•
Air Emissions Inventory
B. Hexafluoropropylene oxide (HFPO)
HF Potential:
HFPO is a VOC without the potential to form HF
Quantity Released
HFPO unreacted in condensation is vented to the WGS.
HFPO vented per the process flowsheet
Vented from the Condensation Reactor:
Vented from the Crude Receiver
Vented from the Foreshots Receiver
HFPO vented based on
HFPO vented based on
HFPO vented based on
HFPO vented from Condensation Reactor:
0.13 kg HFPO x
0.50 kg CndRx
HYPO vented from Crude Receiver
0.00 kg HFPO x
15.91 kg CrRec
HFPO vented from Foreshots Receiver
0.00 kg HFPO x
0.14 kg FsRec
VOC Emissions
Vinyl Ethers North (NS-B)
EVE Process Emissions
Page 3 of 13
CAS No. 428-59-1
0.13 kg HFPO
0.50 kg Cond Rx Vent Flow
0 kg HFPO
F�591 kg Crude Receiver Vent
0 kg HFPO
0.14 kg ForeshotsReceiver Vent
190 kg total Condensation Reactor vent stream (22266FG).
2,589 kg total Crude Receiver vent stream (22701FG).
2 kg total Foreshots Receiver vent stream (22826FG).
190 kg CndRx = 49 kg HFPO
2,589 kg CrRec 0 kg HFPO
2 kg FsRec = 0 kg HFPO
49 kg from Condensation Reactor
0 kg from Crude Receiver
0 kg from Foreshots Receiver
49 kg HFPO =
49 kg VOC
108 lb VOC
DEQ-CFW 00069190

11
•
•
Air Emissions Inventory
C. Perfluoro-2-Propoxy Propionyl Fluoride (HFPO Dimer)
HF Potential:
E;
ach mole of HFPO Dimer MW = 332 can generate 1 mole of HF MW = 20).
1 moleDimer 20g HF 1 moleHF
FDimer=0.06kgH
3329Dimer 1 moleHF l moleDimer
I nereTOre, eacn I Kg w nrr-v ujmui ywmiadca
Quantity Released
Before -control HFPO Dimer vented per the process flowsheet
Vented from the Condensation Reactor: 0.05 kg HFPODimer
0.50 kg Cond Rx Vent Flow
0 kg HFPODimer
15.91 kg Crude Receiver Vent
0 kg HFPODimer
0.14 kg ForeshotsReceiver Vent
190 kg total Condensation Reactor vent stream (22266FG).
2,589 kg total Crude Receiver vent stream (22701FG).
2 kg total Foreshots Receiver vent stream (22826FG).
Before control HFPO Dimer vented from Condensation Reactor:
Vinyl Ethers North (NS-B)
EVE Process Emissions
Page 4 of 13
Vented from the Crude Receiver
Vented from the Foreshots Receiver
HFPO Dimer vented based on
HFPO Dimer vented based on
HFPO Dimer vented based on
CAS No. 2062-98-8
0.060 kg of HF
0.05 kg HFPO Dimer x
190 kg CndRx =
19 kg HFPO Dimer
0.50 kg CndRx
HFPO Dimer vented from Crude Receiver
0.00 kg HFPO Dimer x
2,589 kg CrRec =
0 kg HFPO Dimer
15.91 kg CrRec
HFPO Dimer vented from Foreshots Receiver
0.00 kg HFPO Dimer x
2 kg FsRec =
0 kg HFPO Dimer
0.14 kg FsRec
Total before -control HYPO Dimer vented
=
19 kg HFPO Dimer
After -control emissions utilizing the 99.1 % control efficient Waste Gas Scrubber (WGS):
VOC Emissions
19 kg Dimer
Waste Gas Scrubber
x (100%-99.1%)
= 0.17 kg Dimer
0.17 kg VOC
=
0.38 lb. VOC
HF Equivalent Emissions
0.17 kg Dimer
x 0.060 kg HF/kg Dimer
= 0.01 kg HF
0.02 lb. HF
J
DEQ-CFW 00069191

Air Emissions Inventory Vinyl Ethers North (NS-B)
EVE Process Emissions
Page 5 of 13
D. Tetrafluoroethylene (TFE) CAS No. 116-14-3
HF Potential:
TFE is a VOC without the potential to form HF
Quantity Released
TFE is a byproduct that can be formed in the ABR system. It is an inert in VE-North that is
vented to the WGS.
TFE vented per the process flowsheet
0 kg TFE
Vented from the Condensation Reactor: 0.50 kg Cond Rx Vent Flow
0.18 kg TFE
Vented from the Crude Receiver 15.91 kg Crude Receiver Vent
0 kg TFE
Vented from the Foreshots Receiver 0.14 kg ForeshotsReceiver Vent
TFE vented based on 190 kg total Condensation Reactor vent stream (22266FG).
TFE vented based on 2,589 kg total Crude Receiver vent stream (22701FG).
TFE vented based on 2 kg total Foreshots Receiver vent stream (22826FG).
TFE vented from Condensation Reactor: —
0.00 x 190 kg CndRx 0 kg TFE
0.50 kg TFE
kg CndRx
TFE vented from Crude Receiver
0.18 x 2,589 kg CrRec = 28 kg TFE
15.91 kg TFE
kg CrRec
TFE vented from Foreshots Receiver
0.00 x 2 kg FsRec = 0 kg TFE
0.14 kg TFE
kg FsRec
VOC Emissions 0 kg from Condensation Reactor
+ 28 kg from Crude Receiver
+ 0 kg from Foreshots Receiver
28 kg TFE = 28 kg VOC
63 lb VOC
DEQ-CFW 00069192

•
•
•
Air Emissions Inventory
E. Methyl Perfluoro (5-(Fluoroformyl)
-4-Oxahexanoate) (MAE)
HF Potential:
ch mole of MAE (MW = 322) can generate 1 mole of HF (MW = 20).
1 molellMAE 20g HF 1 moleHF
kg MAE- = 0.062kgH1
322g MAE 1 moleHF 1 moleMAE
I IICI Glul G, OC[l..I1 I my v] Ivi— yo —aw
Quantity Released
Before -control MAE vented per the process flowsheet
Vented from the Condensation Reactor:
Vented from the Crude Receiver
Vented from the Foreshots Receiver
MAE vented based on
MAE vented based on
MAE vented based on
Before control MAE vented from Condensation Reactor:
0.00 kg MAE x
0.50 kg CndRx
MAE vented from Crude Receiver
0.00 kg MAE x
15.91 kg CrRec
MAE vented from Foreshots Receiver
0.04 kg MAE x
0.14 kg FsRec
Vinyl Ethers North (NS-B)
EVE Process Emissions
Page 6 of 13
CAS No. 69116-72-9
0.062 kg of HF
0 kg MAE
0.50 kg Cond Rx Vent Flow
0kgMAE
15.91 kg Crude Receiver Vent
0.04 kg MAE
0.14 kg ForeshotsReceiverVen
190 kg total Condensation Reactor vent stream (22266FG).
2,589 kg total Crude Receiver vent stream (22701FG).
2 kg total Foreshots Receiver vent stream (22826FG).
190 kg CndRx = 0 kg MAE
2,589 kg CrRec = 0 kg MAE
2 kg FsRec = I kg MAE
Total before -control MAE vented = I kg MAE
After -control emissions utilizing the 99.1 % control efficient Waste Gas Scrubber (WGS):
VOC Emissions 1 kg MAE
Waste Gas Scrubber x (100%-99.1%)
0.00 kg MAE 0.00 kg VOC
HF Equivalent Emissions
0.01 Ib. VOC
0.00 kg MAE
x 0.062 kg HF/kg MAE
= 0.00 kg HF 0.00 lb. HF
DEQ-CFW 00069193

Air Emissions Inventory Vinyl Ethers North (NS-B)
EVE Process Emissions
Page 7 of 13
F. Propanoic Acid, 3-[I-[Difluoro [ (Trifluoroethenyl) CAS No. 63863-43-4
oxy] Methyl]-1,2,2,2-Tetrafluoroethoxy]-2,2,3,3
-Tetrafluoro-, Methyl Ester (EVE)
HF Potential:
EVE is a VOC without the potential to form HF
Quantity Released
EVE vented per the process flowsheet
0kgEVE
Vented from the Condensation Reactor:
0.50 kg Cond Rx Vent Flow
0 kg EVE
Vented from the Crude Receiver
15.91 kg Crude Receiver Vent
0.005kg EVE
Vented from the Foreshots Receiver
0.14 kg Foreshot.5ReceiverVen
EVE vented based on 190 kg total Condensation Reactor vent stream (22266FG).
EVE vented based on 2,119 kg total Crude
Receiver vent stream (22701FG).
EVE vented based on 2 kg total Foreshots Receiver vent stream (22826FG).
EVE vented from Condensation Reactor:
0.00 x
190 kg CndRx = 0 kg EVE
0.50 kg EVE
kg CndRx
EVE vented from Crude Receiver
0.00 x
2,589 kg CrRec = 0 kg EVE
15.91 kg EVE
kg CrRec
EVE vented from Foreshots Receiver
0.005 x
2 kg FsRec = 0 kg EVE
0.14 kg EVE
kg FsRec
VOC Emissions
0 kg from Condensation Reactor
+
0 kg from Crude Receiver
+
0 kg from Foreshots Receiver
=
0 kg EVE = 0 kg VOC
0 lb VOC
DEQ-CFW 00069194

Air Emissions Inventory
•
G. Tetraglyme (TTG)
The emissions of Tetraglyme is based on a mass balance.
Quantily Released
Vinyl Ethers North (NS-B)
EVE Process Emissions
Page 8 of 13
CAS No. 143-24-8
148 kg TTG introduced into processes
148 kg TTG transferred to H/C waste tank
0 kg TTG unaccounted for and assumed emitted
0 1b. Tetraglyme
Emissions of TTG from EVE =
•
to
0 Ib. Tetraglyme
DEQ-CFW 00069195

•
Air Emissions Inventory Vinyl Ethers North (NS-B)
EVE Process Emissions
Page 9 of 13
H. Carbon Monoxide (CO) CAS No. 630-08-0
HF Potential:
CO can not form HF
Quantity Released
CO is a byproduct from the Agitated Bed Reactor system.
vented to the WGS.
CO vented per the process flowsheet
0 kg CO
0.50 kg Cond Rx Vent Flow
Vented from the Condensation Reactor:
0.59 kg CO
Vented from the Crude Receiver 14.91 kg Crude Receiver Vent
0 kg CO
Vented from the Foreshots Receiver 0.14 kg ForeshotsReceiverVen
CO vented based on 190 kg total Condensation Reactor vent stream (22266FG).
CO vented based on 2,589 kg total Crude Receiver vent stream (22701FG).
CO vented based on 2 kg total Foreshots Receiver vent stream (22826FG).
CO vented from Condensation Reactor:
0.00 kg CO x 190 kg CndRx = 0 kg CO
0.50 kg CndRx
CO vented from Crude Receiver
0.59 kg CO x 2,589 kg CrRec = 96 kg CO
15.91 kg CrRec
CO vented from Foreshots Receiver
0.00 kg CO x 2 kg FsRec = 0 kg CO
0.14 kg FsRec
CO Emissions 0 kg from Condensation Reactor
+ 96 kg from Crude Receiver
+ 0 kg from Foreshots Receiver
96 kg CO = 211 lb CO
(not a VOC)
DEQ-CFW 00069196

Air Emissions Inventory Vinyl Ethers North (NS-B)
EVE Process Emissions
Page 10 of 13
•
I. Adiponitrile
HF Potential
ADN is a VOC and Hazardous Air Polluntant without the potential to form HF.
Quantitv Released
ADN emissions based on 1,479 kg ADN fed
CAS No. 111-69-3
VE North ADN Sent to waste Hydrocarbon tank = 1,479 kgs H/C waste
VOC Emission
1,479 kg ADN fed
1,479 kg ADN to [PC waste
0 kg ADN lost = 0 kg VOC
0 lb VOC
ADN only used during an EVE Campaign
Ej
DEQ-CFW 00069197

I/
Air Emissions Inventory Vinyl Ethers North (NS-B)
EVE Process Emissions
Page 11 of 13
•
J. VOC Summary
Nafion Compound Name
Before Control
Generated
After Control
Stack Emissions
VOC
lblyr
kglyr
lblyr
A.
HFP
66
146
146
B.
HFPO
49
108
108
C.
HFPO-Dimer
19
42
0
D.
TFE
28
63
63
E.
N AE
1
1
0.0
F.
EVE
0
0
0.1
G.
TTG
0
0
0
K.
ADN
0
1 0
0
Total
163
1 360
317.4
•
DEQ-CFW 00069198

J
0 K. Total Emission Summary"*
•
•
Air Emissions Inventory Vinyl Ethers North (NS-B)
EVE Process Emissions
Page 12 of 13
** All Emissions in this table represent "After Control' emissions.
Nafion Compound Name
Process
Emissions
lb/yr
Equipment
Emissions
lb/yr
Maintenance
Emissions
lb/yr
Total
Emissions
lb/yr
A.
HFP
146
1
0
147
B.
HFPO
108
35
2
145
C.
HFPO-Dimer
0
0
0
1
D.
TFE
63
0
0
63
E.
MAE
0
0
1
2
F.
EVE
0
70
0
71
G.
TTG
0
2
0
2
H.1
CO (not a VOC)
211
I.
1 ADN
15
1
0
*
JDAE
0
2
3
*
ITAE
0
0
0
*
JMMF
0
0
0
*
hydro -EVE
3
3
6
*
iso-EVE
6
4
10
Total
317
133
13
659
Note 1 - See section titled "Equipment Emissions" for details
Note 2 - See section titled "Maintenance Emissions" for details
H. CO not realistically expected through equipment or maintenance emissions. Not a VOC
I. ADN total based on material balance, see section I.
* Not normally emitted from the process as a routine stack emission
Total Non AF ##
Total AF
DEQ-CFW 00069199

•
•
Pi
Air Emissions Inventory
L. HF Equivalent Emissions
Vinyl Ethers North (NS-B)
EVE Process Emissions
Page 13 of 13
Nafion Compound Name
Process
Emissions
lb/yr
Equipment
Emissions
lb/yr
Maintenance
Emissions
lb/yr
Total
Emissions
lb/yr
C.
HFPO-Dimer
0.000
0.001
0.014
0.015
E.
MAE
0.000
0.008
0.091
0.099
*
DAE
0.019
0.092
0.111
*
TAE
0.000
0.003
0.003
*
MMF
0.003
0.037
0.041
Total
0.00
1 0.03
1 0.24
1 0.27
* Not normally emitted from the process as a routine stack emission
The estimated HF equivalent emissions were determined by multiplying the total emission quantity of an
acid fluoride by the ratio of the molecular weight of HF divided by the molecular weight of the specific
acid fluoride. This is based on the fact that one mole of an acid fluoride will generate one mole of HF.
For example, if 100 lb. of MAE was emitted:
20 lb/mol HF X 100 lb/yr Equipment MAE = 6.0 lb/yr HF
332 lb/mol MAE
DEQ-CFW 00069200

•
•
•
Air Emissions Inventory Vinyl Ethers North (NS-B)
Maintenance Emissions
Page 1 of 4
2015 Maintenance Emission Determination
A. Background
Periodically, the process vessels in the VE-North plant are emptied for campaign switches and for
maintenance. During the deinventory process, the liquid is transferred to another process vessel and
then the gases are evacuated to the division waste gas scrubber. The amount of gasses from the
condensation reactor, crude receiver and foreshots receiver are already included in the vent flowmeter
readings used to calculate emissions in previous sections. This section estimates maintenance emissions
for the rest of the major process vessels.
B. Condensation Tower
Assume the following:
(a) void fraction in distillation columns is 40%
(b) ideal gas behavior
(c) vessels are at atmospheric pressure
(d) ambient temperature (25 deg C)
(e) gases are 68% acid fluorides and 32% non-acid fluorides
(f) average molecular weight (MW) for acid fluoride component based on the average
computed from composite composition as shown on "Vessel Compositions" worksheet.
Therfore the average molecular weight for condensation is 354
(g) average MW for non-acid fluoride component = 166 (average of HFPO & HFP)
(h) number of deinventory events = 7
DEQ-CFW 00069201

•
Air Emissions Inventory Vinyl Ethers North (NS-B)
Maintenance Emissions
Page 2 of 4
List of Process Vessels
Condensation Tower
Volume
( ft3)
Volume
(gallons)
Reactor Decanter
5
41
Stripper Feed Decanter
7
51
Stripper Overhead Receiver
5
40
A/F Column
27
203
A/F Overhead Receiver
14
106
A/F Tails Decanter
1
10
ABR Feed Tank
27
202
Total Volume
87
654
VOC Emissions
n = PV/RT, where P = 14.7 psia R = 10.73 psia-ft3/lb-mol degR
V = 87 ft3 T = 537 degrees R
n = PV = 14.7 psia x 87 ft3 = 0.22 lb -cool gas
RT 10.73 psia-ft3 x 537 deg R deinventory event
lb-mol degR
0.22 lb-mol gas x 7 deinventory events = 1.56 lb-mol gas
deinventory event year year
1.56 lb-mol gas x 32% non-acid fluorides x 166 lb non-A/F = 83.8 lb non-A/F
year lb-mol gas year
Before -control A/F vented from Condensation:
1.56 lb-mol gas x 68% acid fluorides x 354 lb A/F = 373 lb A/F
year lb-mol gas year
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
373 lb/yr A/F VOC Total VOC: 83.8 lb/yr non-A/F VOC
x (100%-99.6%) control efficiency + 1.5 lb/yr A/F VOC
1.5 lb/yr A/F VOC 85.3 lb/yr VOC
DEQ-CFW 00069202

•
•
Air Emissions Inventory
C. Refining
Assume the following:
Vinyl Ethers North (NS-B)
Maintenance Emissions
Page 3 of 4
(a) void fraction in distillation columns is 40%
(b) ideal gas behavior
(c) vessels are at atmospheric pressure
(d) ambient temperature (25 deg C)
(e) gases are 100% vinyl ethers which are 100% VOC
(f) average molecular weight (MW) for vinyl ether component based on the average
computed from composite composition as shown on "Vessel Compositions" worksheet.
Therfore the average molecular weight for refining is 290
(g) number of deinventory events = 7
HF Potential
Vinyl ethers are VOCs without the potential to form HF
List of Process Vessels
Refining
Volume
s
( ft)
Volume
(gallons)
Ether Still
107
803
Ether Still Overhead Receiver
9
69
Product Receiver
46
348
Total Volume
1 163
1220
VOC Emissions
n = PV/RT, where P = 14.7 psia R = 10.73 psia-ft3/lb-mol degR
V = 163 ft3 T = 537 degrees R
n = PV = 14.7 psia x 163 ft3 = 0.42 lb-mol gas
RT 10.73 psia-ft3 x 537 deg R deinventory event
lb-mol degR
0.42 lb-mol gas x 7 deinventory events = 2.91 lb-mol gas
deinventory event year year
2.91 lb-mol gas x 290 lb VOC = 844.3 lb VOC
year lb-mol gas year
DEQ-CFW 00069203

:i
Air Emissions Inventory Vinyl Ethers North (NS-B)
Maintenance Emissions
Page 4 of 4
0 D. Component Summary - All maintenance emissions
E,
•
Component
EVE
PPVE
PSEPVE
lb
lb
lb
HFP
0
0
27
HFPO
2
15
6
HFPO-Dimer
0
31
0
PPF
0
1
0
Diglyme
0
0
3
AN
0
6
0
ADN
1
0
0
TTG
0
0
0
DA
0
0
12
MA
0
0
5
TA
0
0
0
RSU
0
0
0
MAE
1
0
0
MMF
0
0
0
DAE
2
0
0
TAE
0
0
0
HFPO Trimer
0
1
0
EVE *
0
0
0
PPVE
0
441
0
PSEPVE **
0
0
0
hydro -EVE
3
0
0
iso-EVE
4
0
0
C4
0
59
20
Composite compositions for each area,
Condensation, ABR, and Refining, were
determined on the Vessel Composition
worksheet, taking into account run hours on
each campaign and approximate
compositions. The mass fraction for each
component was then multiplied by the VOC
from these areas.
Campaign
EVE
PPVE
PSEPVE
Campaign Fract'n
0.08
0.60
0.32
Cond VOC
7
51
28
Refining VOC
67
504
274
Pre -control VOC 1 103 1 776 1 422
Total before control VOC (lb.) 1301
Total after control VOC 928
* this is very conservative, since EVE will be
liquid at ambient temp
** this is very conservative, since PSEPVE
will be liquid at ambient temp
DEQ-CFW 00069204

Air Emissions Inventory Vinyl Ethers North (NS-B)
Equipment Emissions
Page 1 of 4
2015 Equipment Emissions Determination
Equipment Emissions (EE) are a function of the number of emission points in the plant (valves, flanges, pump seals). For the
equipment emission calculations the inventory shown below is conservative and based on plant and process diagrams. Note
that the division scrubber efficiency is 99.6% for control of acid fluorides.
A. Equipment Emissions from Condensation Reactor System
Condensation Tower (vents to stack) * Emission Factors found on Fugitive Emission Leak rates worksheet
Valve emissions: 462 valves X
0.00039 lb/hr/valve =
0.180
Ib/hr VOC from EE
Flange emissions: 924 flanges X
0.00019 lb/hr/flange =
0.166
lb/hr VOC from EE
Pump emissions: 0 pumps X
0.00115 lb/hr/pump =
0.000
Ib/hr VOC from EE
Total fugitive emission rate =
0.347
lb/hr VOC from EE
Condensation Tower VOC by campaign
Campaign
EVE
PPVE
PSEPVE
Operating Hours
431
3,240
1,760
Total VOC generated per campaign
149
1123
610
Component
EVE
After
control"
PPVE
After control"
PSEPVE
After
control"
lb
lb
lb
lb
lb
lb
HFP
1
1
5
5
1
1
HFPO
35
35
331
331
141
141
HFPO-Dimer
5
0
613
2
8
0
PPF
1
0
23
0
1
0
Diglyme
0
0
0
0
70
70
AN
0
0
136
136
0
0
ADN
15
15
0
0
0
0
TTG
2
2
0
0
0
0
DA
0
0
0
0
257
1
MA
0
0
0
0
115
0
TA
0
0
0
0
9
0
RSU
0
0
0
0
1
0
MAE
32
0
0
0
0
0
MMF
6
0
0
0
0
0
DAE
49
0
0
0
0
0
TAE
2
0
0
0
0
0
HFPO Trimer
0
0
15
0
6
0
Total
149
53
1,123
474
610
214
Note: Speciated equipment emissions were estimated by assuming typical volumes of each component in the system,
and applying the fraction of each component to the total estimated emissions. The worksheet "vessel
compositions" shows the factors used in this calculation.
DEQ-CFW 00069205

V
•
11
•
Air Emissions Inventory
B. Equipment Emissions from Agitated Bed Reactor System
Valve emissions: 85 valves X 0.00039 lb/hr/valve =
Flange emissions: 170 flanges X 0.00018 lb/hr/flange =
Pump emissions: 0 pumps X 0.00115 lb/hr/pump =
Total fugitive emission rate =
ABR/crude VOC by campaign
Vinyl Ethers North (NS-S)
Equipment Emissions
Page 2 of 4
0.033 lb/hr VOC from EE
0.031 lb/hr VOC from EE
0.000 lb/hr VOC from EE
0.064 lb/hr VOC from EE
Campaign
EVE
PPVE
PSEPVE
Operating Hours
430,7345
3,240
1,760
Total VOC per campaign
27.45932
207
112
Component
EVE
PPVE
PSEPVE
lb
lb
lb
HFP
0
0
8
HFPO-Dimer
0
2
0
EVE
23
0
0
PPVE
0
198
0
DA
0
0
1
DAE
0
0
0
PSEPVE
0
0
98
hydro -EVE
1
0
0
iso-EVE
2
0
0
C4
0
6
6
Total
27
207
112
Worst case, assume all acid fluorides are released in
the portion of the feed line outside the ABR room
and are not removed by the WGS.
DEQ-CFW 00069206

•
Air Emissions Inventory
C. Equipment Emissions from Refining System
Valve emissions: 162 valves X 0.00039 lb/hr/valve =
Flange emissions: 324 flanges X 0.00018 lb/hr/flange =
Pump emissions: 0 pumps X 0.00115 lb/hr/pump =
Total fugitive emission rate =
Refining System VOC by campiagn
Vinyl Ethers North (NS-B)
Equipment Emissions
Page 3 of 4
0.063 lb/hr VOC from EE
0.058 lb/hr VOC from EE
0.000 lb/hr VOC from EE
0.122 lb/hr VOC from EE
Campaign
EVE
PPVE
PSEPVE
Operating Hours
430.7345
3,240
1,760
Total VOC per campaign
52.33424
394
214
Component
EVE
PPVE
PSEPVE
lb
lb
lb
HFP
0
0
21
HFPO-Dimer
0
2
0
EVE
47
0
0
PPVE
0
345
0
PSEPVE
0
0
177
hydro -EVE
2
0
0
iso-EVE
3
0
0
C4
0
46
Total
52
394TZ]
All Refining equipment is located outside of
the tower so releases will be directly to
atmosphere.
DEQ-CFW 00069207

Air Emissions Inventory Vinyl Ethers North (NS-B)
Equipment Emissions
Page 4 of 4
IsD. Component Summary - All equipment emissions
Component
EVE
PPVE
PSEPVE
Total
lb
lb
lb
lb
HFP
1
5
31
36
HFPO
35
331
141
507
HFPO-Dimer
0
7
0
7
PPF
0
0
0
0
Diglyme
0
0
70
70
AN
0
136
0
136
ADN
15
0
0
15
TTG
2
0
0
2
DA
0
0
2
2
MA
0
0
0
0
TA
0
0
0
0
RSU
0
0
0
0
MAE
0
0
0
0
MMF
0
0
0
0
DAE
0
0
0
0
TAE
0
0
0
0
HFPO Trimer
0
0
0
0
EVE
70
0
0
70
PPVE
0
543
0
543
PSEPVE
0
0
275
275
hydro -EVE
3
0
0
3
iso-EVE
6
0
0
6
C4
0
53
21
74
1747
•
DEQ-CFW 00069208

•
Vinyl Ethers South Process
NS-C
DEQ-CFW 00069209

E
Air Emissions Inventory
2015 Emission Summary
A. VOC Emissions Summary
Vinyl Ethers South (NS-C)
Summary
Page 1 of 1
Nafion®
Compound
CAS Chemical Name
CAS No.
PE/PM
Emissions
lb.
PPVE
Emissions
Ib.)
Accidental
Releases (lb.)
Total Emissions
lb.
COF2
Carbonyl Fluoride
353-50-4
644
0
0
644
PAF
Perfluoroacetyl Fluoride
354-34-7
772
0
0
772
PMPF
Perfluoromethoxypropionyl fluoride
2927-83-5
1,090
0
0
1,090
PEPF
Perfluoroethoxypropionyl fluoride
1682-78-6
407
0
0
407
PMVE
Perfluoromethyl vinyl ether
1187-93-5
20,482
0
0
20,482
PEVE
Perfluoroeth I vinyl ether
10493-43-3
1,177
0
0
1,177
HFP
Hexafluoro ro I ene
116-15-4
4,087
0
0
4,087
HFPO
Hexafluoro ro lyene Epoxide
428-59-1
4,425
0
0
4,425
AN
Acetonitrile
75-05-8
1,606
0
0
1,606
HFPO Dimer
Perfluoro-2-Pro oxy Propionyl Fluoride
2062-98-8
6
0
0
6
MD
56
0
0
56
HydroPEVE
11
0
0
11
PPVE
Perfluoropropyl vinyl ether
1623-05-8
11
0
0
11
PPF
Perfluoropro ion I fluoride
422-61-7
0
0
0
0
TFE
Tetrafluoroeth lene
116-14-3
0
0
0
0
C4
Perfluoro-2-butene
360-89-4
0
0
0
0
C5
Perfluoro entene
376-87-4
0
0
0
0
Total VOC Emissions (Ib.)
Total VOC Emissions (tons)
34,776
17.39
B. Criteria Pollutant Summary
Nafion®
Compound
CAS Chemical Name
CAS No.
Process
Emissions
lb.
Accidental
Releases lb.
Total
Emissions
lb.
CO
Carbon Monoxide
630-08-0
0
0
0
Total CO Emissions (lb.)
Total CO Emissions (tons)
0
0.0
C. Toxic Air Pollutant and Hazardous Air Pollutant Summary (TAPS/RAPS)
Process
Total
Nafion@
CAS Chemical Name
CAS No.
Emissions
Accidental
Emissions
Compound
lb.)
Releases (lb.)
(lb.)
HF
Hydrogen Fluoride
7664-39-3
648
0
648
Acetonitrile
Acetonitrile
75-05-8
1,606
0
1,606
DEQ-CFW 00069210

Air Emissions Inventory
Vinyl Ethers South (NS-C) /
PE -PM Emissions
Page 1 of 8
2015 AIR EMISSIONS INVENTORY SUPPORTING DOCUMENTATION
isEmission Source ID No: NS-C
r�
Emission Source Description: VE-South PEVE / PMVE Manufacturing Process
Process & Emission Description: The VE-South PEPM manufacturing process is a continuous chemical reaction. All
emissions from the process are vented through the VE-South Waste Gas Scrubber (Control Device ID No. NCD-Hdr2) which has
a documented control efficiency of 99.6% for all acid fluoride compounds. Some emitted compounds are assumed to pass
completely through the scrubber, so the control efficiency for those compounds is assumed to be 0%. The control of emissions of
specific compounds will be addressed and detailed in the following pages.
The PEPM process in VE-South emits compounds in the acid fluoride family. In the presence of water (such as in atmospheric
moisture), these acid fluorides can eventually hydrolyze to hydrogen fluoride. For the purpose of this emissions inventory, a
conservative approach will be taken and the acid fluorides will be reported both as a VOC and as the equivalent quantity of
hydrogen fluoride.
Basis and Assumptions:
A process flowsheet, developed from operating data during a typical month, May 2005, is the basis for relative concentrations of before -
control emissions of gaseous wastes.
The flowsheet is available under the "flowsheet" tab for reference and includes the basis for ratios used in this calculation.
Because an overall material balance for the year is used for calculation of emissions, "maintenance emissions" related to turnarounds are
assumed to be included with the calculated emissions. The usual practice is to deinventory liquids and then vent vessels to the Waste Gas
Scrubber.
All emission determination calculations are available on the EXCEL spreadsheet found at:
HEinissions/VE-S Emissions
DEQ-CFW 00069211

•
lJ
Air Emissions Inventory Vinyl Ethers South (NS-C)
PE -PM Emissions
Page 2 of 8
Point Source Emissions Determination
A. Carbonyl Fluoride (COF2) CAS No. 353-50-4
HF Potential:
Each mole of COF2 (MW = 66) can generate 2 moles of HF (MW = 20).
F1kgCOF2 .1 moleCOF 20 g HF 2 molesHF — 0.606 kg H
66 g COF 1 moleHF 1 moleCOF
Therefore, each kg of COF2 generates 0.606 kg HF
Quantity Generated
COF2 is vented from the PAF column and condensation process. Because amount vented depends on the product split,
the composition exit the PAF column is calculated using the following relationship from the flowsheet, which relates
COF2 in feed to condensation to the overall amount of PMVE produced:
kg COF2 in Condensation feed = 0.555
kg PMVE produced
X 275,769 kg PMVE produced
153,061 kg COF2 fed to condensation
COF2 vented from PAF column is determined from a material balance on the column:
COF2 vented from PAF column = COF2 fed to PAF column - COF2 fed to condensation
COF2 fed to PAF column = 61.85 kg/h average precursor feed, (1066FC)
X 5992 hours of operation (from uptime data)
X 55% typical COF2 in precursor feed to PAF column
203,833 kg COF2 fed to PAF column
COF2 vented from PAF column = 203,833 153,061 = 50,772 kg
COF2 vented from condensation (primarily the reactor vent) will also vary with product split, and is therefore estimated using
a relationship from the flowsheet:
kg COF2 vented = 0.059
kg PMVE produced
X 275,769 kg PMVE produced
COF2 vented from condensation = 16,315
Total COF2 vented from process vents to WGS = 50,772 +
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS)
VOC emissions: 67,086 kg COF2 emitted to WGS
x (100% - 99.6%)
268 kg VOC
HF Equivalent Emissions 268 lb COF2
x 0.606 kg HF/kg COF2
163 kg HF
16,315 = 67,086 kg
= 268 kg VOC
690 lb VOC
= 358 lb HF
DEQ-CFW 00069212

Air Emissions Inventory Vinyl Ethers South (NS-C)
PE -PM Emissions
Page 3 of 8
B. Perfluoroacetyl Fluoride (PAF) CAS No. 354-34-7
HF Potential:
Each mole of PAF (MW = 116) can generate 1 mole of HF (MW = 20).
1 molePAF 20g HF 1 moleHF
1 kg PAF• = 0.172kg HF
116g PAF 1 moleHF 1 molePAF
Therefore, each kg of PAF generates 0.172 kg HF
Quantity Generated
PAF is vented from the PAF column and condensation process. Because amount vented depends on the product split,
the composition exit the PAF column is calculated using the following relationship from the flowsheet, which relates
PAF in feed to condensation to the overall amount of PEVE produced:
kg PAF in Condensation feed = 0.716
kg PEVE produced
X 120,978 kg PEVE produced
86,580 kg PAF fed to condensation
PAF vented from PAF column is determined from a material balance on the column:
PAF vented from PAF column = PAF fed to PAF column - PAF fed to condensation
PAF fed to PAF column = 61.85 kg/h average precursor feed, (1066FC)
X 5992 hours of operation (from uptime data)
X 44% typical PAF in precursor feed to PAF column
163,066 kg PAF fed to PAF column
PAF vented from PAF column = 163,066 86,580 = 76,486 kg
PAF vented from condensation (primarily the reactor vent) will also vary with product split, and is therefore estimated using
a relationship from the flowsheet:
kg PAF vented = 0.044
kg PEVE produced
X 120,978 kg PEVE produced
PAF vented from condensation = 5,323
Total PAF vented from process vents to WGS = 76,486 + 5,323 = 81,809 kg
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS)
VOC emissions 81,809 kg PAF =
x (100% - 99.6%)
327 kg PAF = 327 kg VOC
720 lb VOC
HF Equivalent Emissions 327 kg PAF
x 0.172 kg HF/kg PAF
56 kg HF = 124 lb HF
DEQ-CFW 00069213

Air Emissions Inventory
C. Perfluoromethoxypropionyl fluoride (PMPF)
CAS No. 2927-83-5
HF Potential:
Each mole of PMPF (MW = 232) can generate 1 mole of HF (MW = 20)
1 molePMPF 20g HF 1 moleHF
1kgPMPF=0.086kgH
232gPMPF ImoleHF ImolePMPF
Therefore, each kg of PMPF generates 0.086 kg HF
Vinyl Ethers South (NS-C) /
PE -PM Emissions
Page 4 of 8
Quantity Generated
PMPF is emitted from the Agitated Bed Reactor system. Because amount vented depends on the product split,
the composition of the waste gas is estimated using the following relationship from the flowsheet, which relates
PMPF in the vent stream to the overall amount of PMVE produced:
kg PMPF vented = 0.21
kg PMVE produced
X 275,769 kg PMVE produced
PMPF vented from ABR system = 56,893 kg
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS)
VOC emissions 56,893 kg PMPF
x (100% - 99.6%)
228 kg PMPF = 228 kg VOC
501 lb VOC
HF Equivalent Emissions 228 kg PMPF
x 0.086 kg HF/kg PMPF
20 kg HF = 43 lb HF
DEQ-CFW 00069214

Air Emissions Inventory
D. Perfluoroethoxypropionyl fluoride (PEPF) CAS No. 1682-78-6
HF Potential:
Each mole of PEPF (MW = 282) can generate 1 mole of HF (MW = 20).
1 molePEPF 20g HF 1 moleHF
1kgPEPE'=0.071kgH
282g PEPF 1 moleHF 1 molePEPF
Vinyl Ethers South (NS-C)
PE -PM Emissions
Page 5 of 8
Therefore, each kg of PEPF generates 0.071 kg HF
Quantity Generated
PEPF is emitted from the Agitated Bed Reactor system. Because amount vented depends on the product split,
the composition of the waste gas is estimated using the following relationship from the flowsheet, which relates
PEPF in the vent stream to the overall amount of PEVE produced:
kg PEPF vented =1 0.15
kg PEVE produced
X 120,978 kg PEVE produced
PEPF vented from ABR system = 18,311 kg
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS)
VOC emissions: 18,311 kg PEPF
x 100% - 99.6%
73 kg PEPF — 73 kg VOC
161 lb VOC
HF Equivalent Emissions 73 kg PEPF
x 0.071 kg HF/kg PEPF
5 kg HF = 11 Ib HF
E. Perfluoromethyl vinyl ether (PMVE) CAS No. 1187-93-5
HF Potential:
PMVE is a VOC without the potential to form HF.
Quantity Released
PMVE is a compoonent in the vent from the Low Boiler Column. Composition of this vent stream is based on the flow sheet.
The low boiler column vented at a rate of 2.940 kg/h vent rate, (1830FG)
X 5,992 hours of operation (from uptime data)
17,616 kg vented from low boiler column
PMVE in the low boiler column vent stream = 49% X 17,616 = 8,685 kg
After -control emissions from the Waste Gas Scrubber with an assumed efficiency of zero percent (0%)
VOC Emissions = 8,685 kg VOC
19,107 lb VOC
•
DEQ-CFW 00069215

•
•
•
Air Emissions Inventory Vinyl Ethers South (NS-C)
PE -PM Emissions
Page 6 of 8
F. Perfluoroethyl vinyl ether (PEVE) CAS No. 1049343-3
HF Potential:
PEVE is a VOC without the potential to form HF.
Quantity Released
There are no point source emissions identified which contain PEVE.
VOC Emissions = 0 kg VOC
0 lb VOC
G. Hexafluoropropylene (HFP) CAS No. 116-15-4
HF Potential:
HFP is a VOC without the potential to form HF.
Quantity Released
HFP is an inert in the process that is vented from the PAF column and from the low boiler column.
HFP in the LBC vent stream is based on the flow sheet and estimated total vented.
The low boiler column vented at a rate of 2.940 kg/h vent rate, (1830FG)
X 5,992 hours of operation (from uptime data)
17,616 kg vented from low boiler column
HFP in the low boiler column vent stream = 9% X 17,616 = 1,533 kg
The HFP vented from the PAF column is estimated from a material balance on the PAF column.
HFP vented from PAF column = HFP fed to PAF column - HFP left in system (later removed in LBC)
HFP fed to PAF column = 61.85 kg/h average precursor feed, (1066FC)
X 5992 hours of operation (from uptime data)
X 0.5% typical HFP in precursor feed to PAF column
1,853 kg HFP fed to PAF column
HFP vented from PAF column = 1,853 1,533 = 320 kg
After -control emissions from the Waste Gas Scrubber with an assumed efficiency of zero percent (0%)
VOC Emissions
1,533 kg HFP from PAF Vent
+ 320 kg HFP from LBC Vent
1,853 kg HFP = 1,853 kg VOC
4,077 lb VOC
DEQ-CFW 00069216

•
•
Air Emissions Inventory Vinyl Ethers South (NS-C) j
PE -PM Emissions
Page 7 of 8
H. Hexafluoropropylene oxide (HFPO) CAS No. 428-59-1
HF Potential:
HFPO is a VOC without the potential to form HF.
Quantity Released
HFPO is an inert in the process that is vented from the PAF column. It is assumed that all HFPO fed to the PAF column is vented.
HFPO fed to PAF column = 61.85 kg/h average precursor feed, (1066FC)
X 5992 hours of operation (from uptime data)
X 0.5% typical HFPO in precursor feed to PAF column
1,853 kg HFPO fed to PAF column
= 1,853 kg HFPO vented from PAF column
After -control emissions from the Waste Gas Scrubber with an assumed efficiency of zero percent (0%)
VOC Emissions
1,853 kg HFPO = 1,853 kg VOC
4,077 Ib VOC
1. VOC Summary - Point Source Emissions
Nafion Compound. Name
Before Control
After Control
VOC Generated
Stack Emissions
k / r VOC
Ib/ r VOC
Ib/ r VOC
Ib/ r HF
A.
COF2
67,086
147,590
590
358
B.
PAF
81,809
179,981
720
124
C.
PMPF
56,893
125,165
501
43
D.
PEPF
18,311
40,283
161
11
E.
PMVE
8,685
19,107
19,107
0
F.
PEVE
0
0
0
0
G.
HFP
1,853
4,077
4,077
0
H.
HFPO
1,853
4,077
4,077
0
Total
236,490
520,279
29,2321
537
DEQ-CFW 00069217

Air Emissions Inventory Vinyl Ethers South (NS-C) ✓
PE -PM Emissions
Page 8 of 8
0 J. VOC Summary - All sources
Nation Compound Name
After Control
Equipment
Emissions (N°"')
Total
Emissions
Stack Emissions
Ib/ r VOC
Ib/ r HF
Ib/ r VOC
Ib/ r HF
Ib/ r VOC
Ib/ r HF
A.
COF2
590
358
54
33
644
390
B.
PAF
720
124
53
9
772
133
C.
JPMPF
501
43
589
50
1090
93
D.
PEPF
161
11
246
17
407
28
E.
PMVE
19,107
0
1375
0
20482
0
F.
PEVE
0
0
1177
0
1177
0
G.
HFP
4,077
0
11
0
4087
0
H.
HFPO
4,077
0
348
0
4425
0
HFPO Dimer
6
0
6
0
MD
56
3
56
3
HydroPEVE
11
0
11
0
PPVE
11
0
11
0
AN
1606
0
1606
0
Total
29,232
537
5,544
112
34,776
648
Note 1 - See section titled "Equipment Emissions" for details
•
•
DEQ-CFW 00069218

•
Air Emissions Inventory
2015 Fugitive Emissions Determination
Vinyl Ethers South (NS-C)
Fugitive Emissions
Page 1 of 4
Fugitive Emissions (FE) are a function of the number of emission points in the plant (valves, flanges, pump seals). For
the fugitive emission calculations the inventory shown below is conservative and based on plant and process
diagrams.
Note that the division scrubber efficiency is 99.6% for control of acid fluorides.
A. Fugitive Emissions from Condensation Reactor System
Condensation Tower (vents to stack
Valve emissions: 322 valves x 0.00039 Ib/hr/valve = 0.126 Ib/hr VOC from FE
Flange emissions: 644 flanges x 0.00018 Ib/hr/flange = 0.116 Ib/hr VOC from FE
Pump emissions: 6 pump x 0.00115 Ib/hr/pump = 0.007 Ib/hr VOC from FE
Total fugitive emission rate = 0.248 Ib/hr VOC from FE
Condensation Tower VOC
Total Condensation Fugitive Emissions:
VOC 0.248 Ib/hr FE
x 5992 Operating hr/yr
= 1488 lb FE
Composition of Condensation Tower Fugitive Emissions is estimated based on typical process inventory:
PAF column:
Inventoried with 30 gal fluorocarbon
Equivalent mass FC 375.75 lb fluorocarbon
Component Mass fraction lb
COF2 0.45 169
PAF 0.54 203
HFP 0.005.005 2
HFPO 0.005 2
Reactor loop
Inventoried with
Equivalent mass HC
Inventoried with
Equivalent mass FC
51 gal hydrocarbon
383.265 lb hydrocarbon
9 gal fluorocarbon
112.725 lb fluorocarbon
Component
Mass fraction lb
COF2
0.09
10
PAF
0.04
5
HFP
0.03
3
PMPF
0.59
67
PEPF
0.23
26
Dimer
0.01
1
MD
0.01
1
AN
383
Reactor decanter
Inventoried with
Equivalent mass HC
Inventoried with
Equivalent mass FC
25 gal hydrocarbon
187.875 lb hydrocarbon
25 gal fluorocarbon
313.125 lb fluorocarbon
Component
Mass fraction lb
COF2
0.09
28
PAF
0.04
13
HFP
0.03
9
PMPF
0.
1
PEPF
0.23 23
72 72
Dimer
0.01
3
MD
0.01
3
AN
188
assumes 60 gallons, 85% hydrocarbon, 15% fluorocarbon
Hydrocarbon
assumes 50 gal, 50% HC, 50% FC
Hydrocarbon
DEQ-CFW 00069219

Ol
Stripper column
Inventoried with
Equivalent mass FC
Component
COF2
PAF
HFP
PMPF
PEPF
Dimer
MD
AF column
Inventoried with
Equivalent mass FC
Component
PMPF
PEPF
Dimer
MD
AF overhead
Inventoried with
Component
PMPF
PEPF
AF decanter
Inventoried with
Equivalent mass FC
Component
PMPF
PEPF
HFPO tank
Waste FC tank
Inventoried with
Equivalent mass FC
Component
Dimer
MD
ED
Hydro PEVE
PPVE
PEPF
•
Air Emissions Inventory
Vinyl Ethers South (NS-C)
Fugitive Emissions
Page 2 of 4
30 gal fluorocarbon
375.75 lb fluorocarbon
Mass fraction lb
0.09 34
0.04 15
0.03 11
0.59 222
0.23 86
0.01 4
0.01 4
all FC (70% PMPF, 27% PEPF, 1.5% dimer, 1.5% MD)
30 gal fluorocarbon
375.75 lb fluorocarbon
Mass fraction lb
0.7 263
0.27 101
0.015 6
0.015 6
1000 kg FC
2200 lb FC
Mass fraction lb
0.72 1,584
0.28 616
30 gal fluorocarbon
375.75 lb fluorocarbon
Mass fraction lb
0.72 271
0.28 105
135 gal HFPO
1555.605 lb HFPO 1.38 SG
40 gal fluorocarbon
501 30% refining waste (?), 70% is condensation waste (4% dimer, 67%
MD, 29% ED)
Mass fraction lb
0.028 14.028 assumes 70% is condensation waste (4% dimer, 67% MD, 29% ED)
0.469 234.969
0.203 101.703
0.099 49.599
0.099 49.599
0.099 49.59.9 assumes 30% is waste from refining purges, high boilers PEPF, hydro
PEVE, and PPVE
DEQ-CFW 00069220

•
•
B.
Air Emissions Inventory
Average system composition - Condensation
lb
%
VOC
emissions
(lb)
Equivalent
HF (lb)
COF2
241
3.63%
54
33
PAF
235
3.53%
53
9
HFP
26
0.39%
6
0
HFPO
1,557
23.41%
348
0
PMPF
2,591
38.94%
580
50
PEPF
1,057
15.88%
236
17
Dimer
28
0.42%
6
0.4
MD
249
3.74%
56
3
AN
571
8.58%
128
0
HydroPEVE
50
0.75%
11
0
PPVE
50
0.75%
11
0
total
6,653
1488
112
Fugitive Emissions from Agitated Bed Reactor System & Refining
Vinyl Ethers South (NS-C)
Fugitive Emissions
Page 3 of 4
Valve emissions: 555 valves x 0.00039 lb/hr/valve = 0.216 Ib/hr FE
Flange emissions: 1110 flanges x 0.00018 Ib/hr/flange = 0.200 Ib/hr FE
Pump emissions: 12 pump x 0.00115 Ib/hr/pump = 0.014 Ib/hr FE
Total fugitive emission rate = 0.430 Ib/hr FE
ABR & Refining VOC
Total ABR & Refining Fugitive Emissions:
0.43 Ib/hr FE
x 5,992 Operating hr/yr
= 2,577 lb FE
ABR/Crudes stem
Inventoried with 1500 kg FC
3300 lb FC
Component
Mass fraction lb
CO2
0.33
1,089 Not a VOC
PMPF
0.01
33
PEPF
0.01
33
HFP
0.005
17
PEVE
0.22
726
PMVE
0.425
1,403
Refining
Inventoried with
3000 kg FC
6600 lb FC
Component Mass fraction lb
PMVE 0.5 3300
PEVE 0.5 3300
Average System Composition. -ABR/Refinin
lb
%
VOC
emissions
(lb)
Equivalent
HF (lb)
PMPF
33
0.37%
10
1
PEPF
33
0.37%
10
1
HFP
17
0.19%
5
0
PEVE
4,026
45.69%1
1177
0
PMVE
1 4,703
53.37%1
1375
0
total
1 8,811
1 2,577
2
DEQ-CFW 00069221

L`
C. Acetonitrile fugitive emissions
D.
Air Emissions Inventory Vinyl Ethers South (NS-C) ✓
Fugitive Emissions
Page 4 of 4
No normal process vents of AN to stack. Equipment emissions are estimated above for normal process composition and
leaks.
A material balance is also done to ensure all AN losses are accounted for. When material balance shows negative loss,
only the estimated equipment emissions are included.
VOC Emission
AN to hydrocarbon waste from VE-S = 13,440
Assume that: 5% of spent acetonitrile are fluorocarbons.
AN portion of hydrocarbon waste stream:
13,440 kg to H/C waste
x (1-(.05))
12,768 kg AN to H/C waste
13,440 kg AN fed
12,768 kg AN to waste
672 kg AN lost = 672 kg VOC
1,478 lb VOC additional AN loss
Note: Based on this material balance, it is assumed that no AN is emitted to atmosphere from fugitive emissions, other than
what is determined above.
The amount of hydrocarbon sent to waste is probably overestimated due to inaccuracies in calculation of VE-N portion of the
waste.
Tn4.1 Fnnifhic Fmiccinnc
Emission Source
Total Emissions
lb VOC
Condensation Tower
1,361
Agitated Bed Reactor & Refining
2,577
AN
1,606
Total
5,544
E. Speciated Equipment Emissions Summary
Nafion®
Compound
Equipment Emissions
lb VOC
lb HF
COF2
54
33
PAF
53
9
HFP
11
0
HFPO
348
0
PMPF
589
50
PEPF
246
17
HFPO Dimer
6
0.4
MD
56
3
HydroPEVE
11
0
PPVE
11
0
PEVE
1,177
0
PMVE
1,375
0
AN
1,606
0
TOTAL
5,544
112
DEQ-CFW 00069222

RS U Process
NS-D
•
•
DEQ-CFW 00069223

9
2015 Air Emissions Inventory Supoorting Documentation
Emission Source ID No.: NS-D
Emission Source Description: Nation RSU Process
Process and Emission Description:
The RSU process is a continuous manufacturing process. All emissions from this process vent to
the Nafion Division Waste Gas Scrubber (WGS),Control Device ID No. NCD-Hdrl, which has a
documented efficiency of 99.6%. The control of emissions of certain compounds will be
addressed in the attached spreadsheet. Certain components (i.e. TFE) pass completely through
the scrubber, therefore the efficiency is assumed to be 0%.
Basis and Assumptions:
The RSU process flowsheet 44 (W1207831) is used as a basis for relative compositions and flow
rates of vent streams to the division WGS. A 30 kg/hr maximum RSU production rate is used as
the basis for maximum vent rates.
Information Inputs and Source of Inputs:
Information Input
Source of Inputs
RSU production quantity
RSU Production Facilitator
Speciated emission rates
RSU Process Flowsheet #4 (W1207831)
Point Source Emissions Determination:
Point source emissions for individual components are given in the following pages. A detailed
explanation of the calculations are attached.
Equipment Emissions and Fugitive Emissions Determination:
Emissions from equipment leaks which vent as stack (point source) emissions and true fugitive
(non -point source) emissions have been determined using equipment component emission factors
established by DuPont. The determination of those emissions are shown in a separate section of
this supporting documentation. Per PHA 07-12 Rec# 3, a Scrubber was installed in the RSU
process that would scrub any RV release from equipment inside the tower and also any leak that
occured inside the RSU tower. Therefore, any equipment emissions from equipment inside the
RSU tower will be scrubbed. However since the efficiency of the Scrubber has not been
documented and the fact that the equipment emissions are extremely small for the RSU process,
we have elected not to take credit for the Scrubber in regards to equipment emissions.
DEQ-CFW 00069224

•
•
2015 Emission Summary - RSU Process (NS-D)
A. VOC Emissions by Compound and Source
RSU Process (NS-D)
Emission Summary
Page 1 of 1
Nafion®
Compound
CAS Chemical Name
CAS No.
Point
Source
Emissions
Fugitive
Emissions
Ibs
Equipment
Emissions
(Ibs)
Accidental
Emissions
(Ibs)
Total VOC
Emissions
(Ibs)
TFE
Tetrafluoroeth lene
116-14-3
3500.0
0
240.8
0
3740.8
PAF
Trifluoroacet I Fluoride
354-34-7
9.7
0
0.7
0
10.3
RSU
Difluoro(Fluorosulfon I)Acet I Fluoride
677-67-8
3.3
0
0.2
0.0
3.5
SU
2-H drox tetrafiuoroethane Sulfonic Acid Sultone
697-18-7
9.7
0
0.7
0
10.3
EDC
1,2-Dichloroethane
107-06-2
0
16.2
0
0
16.2
Total for 2015
3522.6
16.2
242.4
0.0
3781.2
Tons
1.89
B. Toxic Air Pollutant Summary
Nafion®
Point
Fugitive
Equipment
Accidental
Total TAP
Compound
CAS Chemical Name
CAS No.
Source
Emissions
Emissions
Emissions
Emissions
Emissions
Ibs
Ibs
(Ibs)
(Ibs)
HF
Hydrogen Fluoride
7664-39-3
3.10
0
31.5
0.0
31.51
H2SO4
Sulfuric Acid
7664-93-9
13.4
138.9
0
0
152.3
C. Criteria Air Pollutant Summary
Nafion®
Point
Fugitive
Equipment
Accidental
Total VOC
Compound
CAS Chemical Name
CAS No.
Source
Emissions
Emissions
Emissions
Emissions
Emissions
Ibs)
(Ibs)
(Ibs)
(Ibs
SO2
Sulfur dioxide
7446-09-5
5.3
0
0
0
5.3

•
•
RSU Manufacturing Process Point Source Emission Determination
Page 1 of 6
Point Source Emission Determination
A. Tetrafluoroethylene (TFE)
HF Potential:
TFE is a VOC without the potential to form HE
TFE Quantity Generated:
Before -control TFE generation per the Process Flowsheet #4 (W1207831):
CAS No. 116-14-3
Source
TFE Vent Rate
Reactor
0.05171
kg TFE vented per RSU unit
Rearranger
0.19559
kg TFE vented per RSU unit
Still
0.02206
kg TFE vented per RSU unit
Total
10.26936
kg TFE vented per RSU unit
The before -control TFE generation is based on 5,893.8 RSU units in 2015
TFE vented from the RSU Process in the reporting year:
0.2694 kg TFE x 5,893.8 RSU units = 1,588 kg TFE
RSU unit
After -control emissions utilizing the 0% control efficient Waste Gas Scrubber (WGS):
VOC Emissions 1,588 kg TFE
Waste Gas Scrubber x (100% - 0%) control efficiency
1588 TFE = 1588 kg VOC
3500.0 1b. VOC
DEQ-CFW 00069226

•
•
•
RSU Manufacturing Process
B. Perfluoroacetyl Fluoride (PAF)
Point Source Emission Determination
Page 2 of 6
HF Potential:
Each mole of PAF (MW = 116) can generate 1 mole of HF (MW = 20).
CAS No. 354-34-7
1 kg PAF x
1 mole PAF 20 g HF 1 mole HF
x x = 0.172 kg HF
116 g PAF 1 mole HF 1 mole PAF
Therefore, each 1 kg of PAF generates 0.172 kg of HF
PAF Quantity Generated:
Before -control PAF generation per the Process Flowsheet #4 (WI 207831):
Source
PAF Vent Rate
Reactor
0
kg PAF vented per RSU unit
Rearranger
0.16755
kg PAF vented per RSU unit
Still
0.01862
kg PAF vented per RSU unit
Total
0.186
kg PAF vented per RSU unit
The before -control PAF generation is based on 5,893.8 RSU units in 2015
PAF vented from the RSU Process in the reporting year:
0.186 kg PAF x 5,893.8 RSU units = 1,097 kg PAF
RSU unit
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
VOC Emissions 1,097 kg PAF
Waste Gas Scrubber x (100%-99.6%) control efficiency
= 4.39 kg PAF = 4.39 kg VOC
9.7 lb. VOC
HF Equivalent Emissions 4.39 kg PAF
x 0.172 kg HF/kg PAF
= 0.75 kg HF = 1.66
lb. HF
DEQ-CFW 00069227

r
is
•
RSU Manufacturing Process Point Source Emission Determination
Page 3 of 6
C. Rearranged Sultone (RSU)
Difluoro(Fluorosulfonyl) Acetyl Fluoride
HF Potential:
Each mole of RSU (MW = 180 ) can generate 1 moles of HF (MW = 20).
CAS No. 677-67-8
1 kg RSUx I mole RSU x 20gUF x 1mole IV=0.111kgFIF
180 g RSU 1 mole HF 1 mole RSU
Therefore, each 1 kg of RSU generates 0.111 kg of HF
RSU Quantity Generated:
Before -control RSU generation per the Process Flowsheet #4 (W1207831):
Source
RSU Vent Rate
Reactor
0
kg RSU vented per RSU unit
Rearranger
0.05677
kg RSU vented per RSU unit
Still
0.00644
kg RSU vented per RSU unit
Total
0.063
kg RSU vented per RSU unit
The before -control RSU generation is based on 5,893.8 RSU units in 2015
RSU vented from the RSU Process in the reporting year:
0.063 kg RSU x 5,893.8 RSU units = 373
RSU unit
kg RSU
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
VOC Emissions 373 kg RSU
Waste Gas Scrubber (100%-99.6%) control efficiency
1.49 kg RSU = 1.49 kg VOC
3.3 lb. VOC
HF Equivalent Emissions
1.49 kg RSU
0.111 kg HF/kg RSU
0.17 kg HF = 0.36
lb. HF
DEQ-CFW 00069228

1
•
0
El
RSU Manufacturing Process
D. Sultone (SU)
TFE Sultone (2-Hydroxytetrafluoroethane Sulfonic Acid)
Point Source Emission Determination
Page 4 of 6
HF Potential:
Each mole of SU (MW = 180) can generate 1 mole of HF (MW = 20).
1 kg SU x
1 mole SU 20 g HF 1 mole HF
x x = 0.111 kg HF
180gSU Imole IHF Imole SU
Therefore, each 1 kg of SU generates 0.111 kg of HF
SU Quantity Generated:
Before -control SU generation per the Process Flowsheet #4 (W1207831):
CAS No. 697-18-7
Source
SU Vent Rate
Reactor
0
kg SU vented per RSU unit
Rearranger
0.16755
kg SU vented per RSU unit
Still
0.01862
kg SU vented per RSU unit
Total
0.186
kg SU vented per RSU unit
The before -control SU generation is based on 5,893.8 RSU units in 2015
SU vented from the RSU Process in the reporting year:
0.186 kg SU x 5,893.8 RSU units = 1,097 kg SU
RSU unit
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
VOC Emissions 1,097 kg SU
Waste Gas Scrubber x (100%-99.6%) control efficiency
4.39 SU = 4.39 kg VOC
9.7 lb. VOC
HF Equivalent Emissions
4.39 kg SU
0.111 kg HF/kg SU
0.5 kg HF =
1.07 lb. HF
DEQ-CFW 00069229

RSU Manufacturing Process Point Source Emission Determination
Page 5 of 6
E. Sulfur dioxide (S02) CAS No. 354-34-7
Air Pollutant Description:
Sulfur dioxide is a criteria pollutant and will be reported as such on the NC DAQ forms.
S02 Quantity Generated:
Before -control S02 generation per the Process Flowsheet #4 (W1207831):
Source
S02 Vent Rate
Reactor
0
kg S02 vented per RSU unit
Rearranger
0.09124
kg S02 vented per RSU unit
Still
0.00988
kg S02 vented per RSU unit
Total
0.101
kg S02 vented per RSU unit
The before -control S02 generation is based on 5,893.8 RSU units in 2015
S02 vented from the RSU Process in the reporting year:
0.101 kg S02 x 5,893.8 RSU units = 596 kg S02
RSU unit
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
S02 Emissions 596 kg S02
Waste Gas Scrubber x (100%-99.6%) control efficiency
2.38 kg S02 = 5.3 lb. S02
r�
DEQ-CFW 00069230

•
•
•
RSU Manufacturing Process Point Source Emission Determination
Page 6 of 6
F. Sulfur trioxide (S03) CAS No. 7446-11-9
H2SO4 Potential:
Each mole of S03 (MW = 80) can generate 1 mole of H2SO4 (MW = 98).
1 kg S03 x 1 mole S03 x 98 g H2SO4 x 1 mole H2SO4 _ 1.225 kg H2SO4
80 g S03 1 mole H2SO4 1 mole S03
Therefore, each 1 kg of S03 generates 1.225 kg of H2SO4
S03 Quantity Generated:
Before -control S03 generation per the Process Flowsheet #4 (W1207831):
Source
S03 Vent Rate
Reactor
0.00115
kg S03 vented per RSU unit
Rearranger
0.188
kg S03 vented per RSU unit
Still
0.02114
kg S03 vented per RSU unit
Total
0.211
kg S03 vented per RSU unit
The before -control S03 generation is based on 5,893.8 RSU units in 2015
S03 vented from the RSU Process in the reporting year:
0.211 kg S03 x 5,893.8 RSU units = 1,242 kg S03
RSU unit
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
S03 Emissions 1,242 kg S03
Waste Gas Scrubber x (100%-99.6%) control efficiency
4.97 kg S03 = 11.0 lb. S03
H2SO4 Equivalent Emissions 4.97 kg S03
x 1.225 kg H2SO4 ! kg S03
6.09 kg H2SO4 =
13.4 lb. H2SO4
DEQ-CFW 00069231

RSU Process
0 Fugitive and Equipment Emissions Determination (Non -point Source):
•
Fugitive Emission Determination
Page 1 of 2
Fugitive (FE) and Equipment Emissions (EE) are a function of the number of emission points in the
plant (valves, flanges, pump seals). The inventory shown below is conservative and based on plant
and process diagrams. Note that the calculations below include equipment emissions inside
as well as equipment emissions outside (fugitive emissions).
A. Equipment emissions from 5U Reactor, Rearranger, R5U 5till and R5U Hold Tank:
Emissions are vented from equipment located inside the RSU barricade and are vented to a vent
stack.
Barricade:
Valve emissions: 250 valves x 0.00036 Ib/hr/valve = 0.090 Ib/hr EE
Flange emissions: 550 flanges x 0.00018 Ib/hr/flang, = 0.045 Ib/hr EE
Total equipment emission rate = 0.135 Ib/hr EE
Days of operation = 75
On average 0.13 Ibs of HF are produced for every 1 lb of RSU, SU or PAF.
VOC: 0.135 Ib/hr EE HF: 0.135 Ib/hr EE
x 24 hours/day x 24 hours/day
x 75 days/year x 75 days/year
242.4 Ib/yr VOC from EE x U.13 lb FIF per lb VOU
31.5 Ib/yr HF from EE
B. Fugitive Emissions From S03 Storage Tank and Vaporizer
This equipment is not inside a building, therefore emissions are true Fugitive Emissions
Valve emissions: 85 valves x 0.00036 Ib/hr/valve = 0.031 Ib/hr FE
Flange emissions: 180 flanges x 0.00018 Ib/hr/flang, = 0.032 Ib/hr FE
Total fugitive emission rate = 0.063 Ib/hr FE
S03: 0.063 lb. FE/hr H2SO4: 0.063 lb. FE/hr
x 24 hours/day x 24 hours/day
x 75 days/year x 75 days/year
113.4 Ib/yr S03 from EE x 1.225 lb H2SO4 per lb S03
= 138.9 Ib/yr H2SO4 from FE
C. Fugitive Emissions From EDC Tank
This equipment is not inside a building, therefore emissions are true Fugitive Emissions
Valve emissions: 20 valves x 0.00036 Ib/hr/valve = 0.007 Ib/hr FE
Flange emissions: 10 flanges x 0.00018 Ib/hr/flange = 0.002 Ib/hr FE
Total fugitive emission rate = 0.009 Ib/hr FE
VOC: 0.009 Ib/hr FE HF:
x 24 hours/day
x 75 days/year
- 16.2 Ib/yr VOC from FE
DEQ-CFW 00069232

•
•
•
RSU Process
D. Total RSU Plant Non -Point Source Emissions
Fugitive Emission Determination
Page 2 of 2
Equipment
Fugitive
Emissions
Emissions
VOC
HF
VOC
SO3
H2SO4
Ib/yr
Ib/yr
Ib/yr
Ib/yr
Ib/yr
mission Source
A. Equipment Emissions from SU Reactor,
242.4
31.5
0
0
0
Rearran er, Still and Hold Tank
B. Fugitive Emissions From SO3 Storage
0
0
0
113.4
138.9
Tank and Vaporizer
C. Fugitive Emissions From EDC Tank
0
0
16.2
0
0
Total for 2016
242.4
31.5
1 16.2
113.4
138.9
E. VOC Emission by Source Type
C
t�
C C
d C
W N
N
C
U! fn
E N S
"= W
C
Q
_C
Q -
..
d
N
~
z 0
6 2
E
� W
Q�
W
W
TFE
1 3500.0
240.8
0
0
3740.8
PAF
9.7
0.7
0
0
10.3
RSU
3.3
0.2
0
0.0
3.5
SU
9.7
0.7
0
0
10.3
EDC
0
0
16.2
0
16.2
Total
3522.E
242.4
16.2
0.0
3781.2
Note: Speciated equipment emissions were estimated by assuming that each
compound's equipment emission concentration was equal to that compound's
stack emission fraction of the total stack emission.
Example: The TFE equipment emissions were determined by the ratio of the
TFE stack emission (1,997.9 lb) divided by the total stack emission (2,010.8 lb),
multiplied by the total equipment emissions (229.4 lb).
Specifically: 3500.0 242.4 = 240.8 lb. TFE
3522.6
DEQ-CFW 00069233

1]
Liquid Waste Stabilization
NS-E
DEQ-CFW 00069234

•
•
2015
Emission Source ID No.:
Emission Source Description:
Process & Emission Description:
Air Emissions Inventory
NS-E
Nafion Liquid Waste Stabilization
Nafion Liquid Waste (NS-E)
Page 1 of 13
f�
r, h
The Nafion liquid waste stabilization is a continuous system of storage with batch
neutralization. To comply with the regulatory requirements of RCRA SubPart CC, neither the
storage tank nor the reactor vent during normal operating conditions. All venting from this
system occurs as a non -routine maintenance activity, which is detailed in the following pages.
All emissions from this system are vented through the Nafion Division Waste Gas Scrubber
(Control Device ID No. NCD-Hdrl) which has a documented control efficiency of 99.6%
for acid fluoride compounds. The control of emissions of specific compounds will be
addressed and detailed in the following pages.
The Nafion liquid waste stabilization process emits compounds in the acid fluoride family.
In the presence of water, these acid fluorides will eventually hydrolyse to hydrogen fluoride.
For the purpose of this emissions inventory, a conservative approach will be take and the acid
fluorides will be reported both as a VOC and as the equivalent quantity of hydrogen fluoride.
Basis and Assumptions:
- For the HF emissions the entire gas flow is assumed to be HF
- The VOC emissions are assumed to be 30% COF2 and 70% TAF for the Reactor
- The VOC emissions are calculated based on Trimer and RSU for the Storage Tank
- The ideal gas law is used.
Information Inputs and Source Inputs:
Information Input
Source of Inputs
Weight of Tank
IP21 (W0345OWG and W03606WG)
Category and Reason for Emission
Waste Mechanical Facilitator
Point Source Emissions Determination:
Shown on the following pages
Fugitive Emissions Determination:
Shown on the following pages.
Prepared by Dianne L. Fields 6/7/2016
DEQ-CFW 00069235

Air Emissions Inventory
Nafion Liquid Waste (NS-E)
Page 2 of 13
u
•
•
•
Stack Emissions from Maintenance Activity or Emergency Activity
for the Reactor
Background
Before performing maintenance on the reactor or storage tank, the pressure from the system
is vented to the Division WGS. Each vent is recorded in IP21 by the weight before and after
the vent. There can be times when the pressure in either the reactor or storage tank rises rapidly
due to reaction. During these times if the pressure rises above 700 kpa in either tank, a pressure
control valve can be opened to vent the tank to avoid the relief valve opening. See chart below.
Date
Tank
Category
Reason
Tank Weight
Initial
(kg)
Final
(kg)
6/5/15
Reactor
Maintenance
pump maintenance
411
0
9/19/15
Reactor
Maintenance
Annual Shutdown
74
15
Sample calculation using maintenance activity dated 6/5/15
Initial Weight minus
411 kg minus
Final Weight equals kg vented to Division WGS
0 kg equals 411 kg vented to WGS
Assume that all of the above is VOC emissions This assumption also overstates the true emissions
as inerts, such as nitrogen are not counted.
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
Percentage of acid fluoride VOCs removed by the WGS =
99.6%
Percentage of acid fluoride VOCs vented from the WGS
= 100% minus 99.6%
Percentage of acid fluoride VOCs vented from the WGS =
0.4%
Therefore, VOCs vented to the atmosphere from the 6/5/15 maintenance activity is equal to:
Amount of VOCs vented to WGS: 411 kg of VOC
Percentage of VOCs vented from the WGS: x 0.4%
Quantity of VOCs vented from the WGS: = 1.644 kg VOC
= 3.62436 lb VOC
Prepared by Dianne L. Fields 6/7/2016
DEQ-CFW 00069236

Air Emissions Inventory Nafion Liquid Waste (NS-E)
Page 3 of 13
•
Stack Emissions from Maintenance Activity (cont.)
for the Reactor
VOC Emissions by Compound
Assume that the vapor is 30% COF2 and 70% TAF. This assumption is based on process
knowledge of the system.
Quantity of VOCs vented from the WGS (see previous page) = 3.6244 lb VOC
COF2 (carbonyl fluoride) CAS No. 353-50-4
Sample calculation using maintenance activity dated 6/5/15
VOC emissions would be equal to:
3.624 lb VOC 0.30 lb COF2 = 1.0873 lb COF2
lb VOC
TAF (telomeric acid fluoride) CAS No. 690-43-7
(perfluoro-3,5,7, 9,11-pentaoxadodecanoyl fluoride)
Sample calculation using maintenance activity dated 6/5/15
VOC emissions would be equal to:
3.624 lb VOC0.70 lb TAF = 2.5371 lb VOC
lb VOC
Prepared by Dianne L. Fields 6/7/2016
DEQ-CFW 00069237

Air Emissions Inventory
Nafion Liquid Waste (NS-E)
Page 4 of 13
•
•
Stack Emissions from Maintenance Activity (cont.)
for the Reactor
HF Potential
Assume that the vapor is 30% COF2 and 70% TAF. This assumption is based on process
knowledge of the system.
COF2 (carbonyl fluoride)
CAS No. 353-50-4
Each mole of COF2 ( MW = 66) can generate 2 moles of HF (MW =20)
1 lb COF2 1 mole COF2 20 lb HF 2 moles HF = 0.606 lb of HF
66 lb COF2 mole HF 1 mole COF2
Therefore, each 1 lb of COF2 generates 0.606 lb of HF
TAF (telomeric acid fluoride)
(perfluoro-3,5,7, 9,11-pentaoxadodecanoyl fluoride)
CAS No. 690-43-7
Each mole of TAF ( MW = 330) can generate 1 mole of HF (MW =20)
1 lb TAF 1 mole TAF 20 lb HF 1 moles HF = 0.061 lb of HF
330 lb TAF mole HF 1 mole TAF
Therefore, each 1 lb of TAF generates 0.061 lb of HF
Sample calculation using maintenance activity dated 6/5/15
Quantity of VOCs vented from the WGS (see Page 2) = 3.6244 lb VOC
HF equivalent emissions would be equal to:
3.624 lb VOC 0.30 lb COF2 0.606 lb HF = 0.659 lb HF
lb VOC lb COF2
3.624 lb VOC 0.70 lb TAF 0.061 lb HF = 0.1538 lb HF
lb VOC lb TAF
Therefore, HF vented to the atmosphere from the 6/5/15 maintenance activity is equal to:
0.659 lb HF + 0.1538 lb HF = 0.8127 lb HF
Prepared by Dianne L. Fields 6/7/2016
DEQ-CFW 00069238

Air Emissions Inventory Nafion Liquid Waste (NS-E)
Page 5 of 13
•
Stack Emissions from Maintenance Activity (cont.)
for the Reactor
Calculation page
Date
Tank
Category
Reason
Weight of Tank
Emitted
VOC
(lb)
Emitted
HF
(lb)
Initial
(kg)
Final
(kg)
6/5/15
Reactor
Maintenance
pump maintenanc
411
0
3.624
0.813
9/19/15
Reactor
Maintenance
jAnnual Shutdown
1 74
15
0.520
0.117
Total Emissions 1 4.14 10.93
Total VOC = 4.14 lb
VOC = 0.0021 ton STACK EMISSIONS
Total JHF = 0.93 lb STACK EMISSIONS
Speciated VOC Stack Emissions
The VOC emissions from the Waste Liquid Stabilization process is assumed to be comprised
of 30% by weight of COF2 and 70% by weight of TAF. The emission of these compounds
from each of the following events is determined simply by multiplying the total emitted VOC
by 30% to determine the COF2 emission and 70% to determine the TAF emission.
Date
Tank
Category
Reason
Emitted
VOC
(lb)
Emitted
COF2
(lb)
Emitted
TAF
(lb)
6/5/15
Reactor
Maintenance
pump maintenanc
3.624
1.087
2.537
9/19/15
Reactor
Maintenance
Annual Shutdown
0.520
0.156
0.364
Total Emissions 1 4.14 1 1.24 12.90
Prepared by Dianne L. Fields 6/7/2016
DEQ-CFW 00069239

Air Emissions Inventory
Nafion Liquid Waste (NS-E)
Page 6 of 13
•
•
Fugitive Emissions Leak Rates for Process Equipment
for the Reactor
Using the following table, the Fugitive Emissions Rates will be calculated:
Emission Factors
Component Service (lb/hr/component)
Pump Seals Light Liquid 0.00115
Valves Light Liquid 0.00036
Flanges All 0.00018
VOC Fugitive Emissions from Equipment Components
1 Pump Seals x 0.00115 lb/hr/pumpseal =
96 Valves x 0.00036 lb/hr/valve =
55 Flanges x 0.00018 lb/hr/flange =
Total VOC Emissions from Equipment Leaks =
Total Annual Fugitive VOC Emissions:
0.00115 lb/hr VOC
0.0346 lb/hr VOC
0.0099 lb/fir VOC
0.0456 lb/hr VOC
0.0456 lb/hr VOC x 8760 hr/year = 399.54 lb VOC
0.1998 tons VOC
Speciated Fugitive VOC Emissions by Compound:
Assume that the emissions are 30% COF2 and 70% TAF. This assumption is based
on process knowledge of the system.
399.5 lb VOC 0.30 lb COF2 = 119.86 lb COF2
lb VOC
399.5 lb VOC 0.70 lb TAF = 279.68 lb TAF
lb VOC
See Page 3 for HF equivalents calculation:
399.5 lb VOC I 0.30 lb COF2 0.606 lb HF = 72.644 lb HF
t lb VOC lb COF2
399.5 lb VOC 0.70 lb TAF 0.061 lb HF = 16.95 lb HF
lb VOC lb TAF
72.644 lb HF + 16.95 lb HF = 89.6 lb HF
Prepared by Dianne L. Fields 6/7/2016
DEQ-CFW 00069240

Air Emissions Inventory
Nafion Liquid Waste (NS-E)
Page 7 of 13
•
•
Stack Emissions from Maintenance Activity or Emergency Activity
for the Storage Tank
Background
Before performing maintenance on the reactor or storage tank, the pressure from the system
is vented to the Division WGS. Each vent is recorded in IP21 by the weight before and after
the vent. There can be times when the pressure in either the reactor or storage tank rises rapidly
due to reaction. During these times if the pressure rises above 700 kpa in either tank, a pressure
control valve can be opened to vent the tank to avoid the relief valve opening. See chart below.
Date
Tank
Category
Reason
Tank Weight
Initial
(kg)
Final
(kg)
9/18/15
Storage
Maintenance
Annual Shutdown
231
143
Sample calculation using maintenance activity dated 9/18/15
Initial Weight minus Final Weight equals kg vented to Division WGS
231 kg minus 143 kg equals 88 kg vented to WGS
Assume that all of the above is VOC emissions This assumption also overstates the true emissions
as inerts, such as nitrogen are not counted.
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
Percentage of acid fluoride VOCs removed by the WGS = 99.6%
Percentage of acid fluoride VOCs vented from the WGS = 100% minus 99.6%
Percentage of acid fluoride VOCs vented from the WGS = 0.4%
Therefore, VOCs vented to the atmosphere from the 9/18/15 maintenance activity is equal to:
Amount of VOCs vented to WGS: 88 kg of VOC
Percentage of VOCs vented from the WGS: x 0.4%
Quantity of VOCs vented from the WGS: = 0.352 kg VOC
= 0.776019 lb VOC
Prepared by Dianne L. Fields 6/7/2016
DEQ-CFW 00069241

Air Emissions Inventory
Nafion Liquid Waste (NS-E) l
Page 8 of 13
•
Ol
•
Stack Emissions from Maintenance Activity (cont.)
for the Storage Tank
VOC Emissions by Compound
Assume that the vapor is 100% Trimer. This assumption is based on process
knowledge of the system.
Quantity of VOCs vented from the WGS (see previous page) =
HFPO Trimer (perfluoro-2,5-dimethyl-3,6-dioxanonanoyl fluoride)
Sample calculation using maintenance activity dated 9/18/15
VOC emissions would be equal to:
0.78 lb VOC
CAS No. 2641-34-1
0.776 lb VOC 1 1.00 lb Trimer = 0..776 lb HFPO Trimer
lb VOC
Prepared by Dianne L. Fields 6/7/2016
DEQ-CFW 00069242

Nafion Liquid Waste NS-E
Air Emissions Inventory q i )
Page 9 of 13
Ol Stack Emissions from Maintenance Activity (cont.)
for the Storage Tank
HF Potential
I]
Assume that the vapor is 100% Trimer. This assumption is based on process
knowledge of the system.
HFPO Trimer (perfluoro-2,5-dimethyl-3,6-dioxanonanoyl fluoride)
2490 lb HFPO Trimer = 100 lb of HF
1 lb HFPO Trimer = 0.0402 lb of HF
Therefore, each 1 lb of Trimer generates 0.04 lb of HF
Sample calculation using maintenance activity dated 9/18/15
Quantity of VOCs vented from the WGS (see Page 2) = 0.78 lb VOC
HF equivalent emissions would be equal to:
0.776 lb VOC 1.00 lb Trimer 0.040 lb HF = 0.031 lb HF
lb VOC lb Trimer
Prepared by Dianne L. Fields 6/7/2016
DEQ-CFW 00069243

Air Emissions Inventory Nafion Liquid Waste (NS-E)
Page 10 of 13
Stack Emissions from Maintenance Activity (cont.)
for the Storage Tank
Calculation page
Date
Tank
Category
Reason
Weight of Tank
Emitted
VOC
(lb)
Emitted
HF
(lb)
Initial
(kg)
Final
(kg)
9/18/15
Storage
Maintenance
Annual Shutd
231
143
0.776
0.031
Total Emissions 1 0.78 10.03
Total VOC = 0.78 1b
VOC = 0.0004 ton STACK EMISSIONS
Total I HF = 0.03 lb STACK EMISSIONS
Speciated VOC Stack Emissions
The VOC emissions from the Waste Liquid Stabilization Storage Tank
is assumed to be comprised of 100% by weight of HFPO Trimer.
Date
Tank
Category
Reason
Emitted
VOC
(lb)
Emitted
Trimer
(lb)
9/18/15
Storage
Maintenance
inualShutdov
0.776
0.776
Total Emissions 1 0.78 1 0.78 1 0.00
Prepared by Dianne L. Fields 6/7/2016
DEQ-CFW 00069244

Air Emissions Inventory
Nafion Liquid Waste (NS-E)
Page 11 of 13
•
•
•
Fugitive Emissions Leak Rates for Process Equipment
for the Storage Tank
Using the following table, the Fugitive Emissions Rates will be calculated:
Emission Factors
Component Service (lb/hr/component)
Pump Seals Light Liquid 0.00115
Valves Light Liquid 0.00036
Flanges All 0.00018
VOC Fugitive Emissions from Equipment Components
1 Pump Seals x 0.00115 lb/hr/pumpseal =
60 Valves x 0.00036 lb/hr/valve =
35 Flanges x 0.00018 lb/hr/flange =
Total VOC Emissions from Equipment Leaks =
Total Annual Fugitive VOC Emissions:
0.00115
lb/hr VOC
0.0216
lb/hr VOC
0.0063
lb/hr VOC
0.0291 lb/hr VOC
0.0291 lb/hr VOC x 8760 hr/year = 254.48 lb VOC
0.1272 tons VOC
Speciated Fugitive VOC Emissions by Compound:
Assume that the emissions are 100% Trimer. This assumption is based
on process knowledge of the system.
254.5 lb VOC 1.00 lb COF2
lb VOC
See Page 3 for HF equivalents calculation:
= 254 lb HFPO Trimer
399.5 lb VOC 1.00 lb Trimer 0.040 lb HF = 16.0 lb HF
lb VOC lb Trimer
Prepared by Dianne L. Fields 6/7/2016
DEQ-CFW 00069245

Air Emissions Inventory Nation Liquid Waste (NS-E)
Page 12 of 13
r-�
•
Emissions from One Time Release
None
Prepared by Dianne L. Fields 6/7/2016
DEQ-CFW 00069246

Air Emissions Inventory Nafion Liquid Waste (NS-E)
Page 13 of 13
0 Emission Summary
•
•
A. VOC Emissions by Compound and Source
Stack
Fugitive
Total
Nafion®
CAS Chemical Name
CAS No.
Emissions
Emissions
Emissions
Compound
(lbs)
(lbs)
(lbs)
COF2
Carbonic difluoride
353-50-4
1.24
119.9
121.1
HFPO
Perfluoro-2,5-dimethyl-3,6-
2641-34-1
0.78
254.5
255.3
Trimer
dioxanonanoyl fluoride
TAF
Trifluoromethyl
3299-24-9
2.90
279.7
282.6
carbonofluoridate
Total VOC (lb)
658.9
Total VOC (ton)
0.33
B. Toxic Air Pollutant Summary
Stack
Fugitive
Total
Nafion®
CAS Chemical Name
CAS No.
Emissions
Emissions
Emissions
Compound
(lbs)
(lbs)
(lbs)
HF
Hydrogen fluoride
7664-39-3
16.98
89.6
106.6
Prepared by Dianne L. Fields 6/7/2016
DEQ-CFW 00069247

•
MMF Process
NS-F
•
•
DEQ-CFW 00069248

0 0 9
MMF Process Emission Summary
Page 1 of 1
Emission Summary
A. VOC Emissions by Compound and Source
Nafion®
Compound
CAS Chemical Name
CAS No.
Point Source
Emissions
(lbs)
Fugitive
Emissions
(lbs)
Equipment
Emissions
(lbs)
Accidental
Emissions
(lbs)
Total VOC
Emissions
(lbs)
DMC
Carbonic Acid, Dimethy Ester
616-38-6
168.7
164.1
0
0
332.9
DME
Dimeth I ether
115-10-6
0.1
0.1
0
0
0.1
MTVE
Methyl Trifluorovinyl Ether
3823-94-7
0.01
0.01
0
0
0.0
MTFE
1 -methoxy-1, 1,2,2-tetrafluoroethane
425-88-7
0.01
0.01
0
0
0.0
MTP
Methyl-3-methoxy-
755-73-7
0.01
0.01
0
0
0.0
BMTK
Bis(2-methoxytetrafl uoroethyl) ketone
1422-71-5
0.00
0.001
0
0
0.0
MTP Acid
MTP Acid
93449-21-9
0.00
0.000
0
0
0.0
TFE
Tetrafluoroethylene
116-14-3
25.8
25.1
0
0
50.8
CH3F
Methyl Fluoride
593-53-3
8.6
8.4
6.7
0
23.7
MMF
Propanoic Acid, 2,2,3-Trifluoro-3-
oxo,methyl ester
69116-71-8
0
0.0
23.8
0
23.8
Total VOC for 2015
203.2
197.6
30.5
0
431.3
VOC (Tons)
0.22
B. Toxic Air Polluntant Summary
Point Source
Fugitive
Equipment
Accidental
Total
Nafion®
CAS Chemical Name
Emissions
Emissions
Emissions
Emissions
Emissions
Compound
CAS No.
(lbs)
(lbs)
(lbs)
(lbs)
(lbs)
HF
Hydrogen Fluoride
7664-39-3
0
25.7
4
0
29.7
L
V

MMF Process Point Source Emission Determination
Page 1 of 9
•
Point Source Emission Determination
A. TFE
Tetrafluoroethylene
HF Potential:
TFE is a VOC without the potential to form HF.
TFE Quantity Generated:
Before -control TFE emission rate per the Process Flowsheet #5600:
CAS No. 116-14-3
Source
TFE Vent Rate
MTP Rx
0.0182
kg TFE vented per MMF unit
Neutralizer
0
kg TFE vented per MMF unit
Wash Tk
0
kg TFE vented per MMF unit
Crude MTP Tk
0
kg TFE vented per MMF unit
Crude DMC Tk
0
kg TFE vented per MMF unit
DMC Still
0
kg TFE vented per MMF unit
Total
0.0182
kg TFE vented per MMF unit
0
The before -control TFE emission is based of 642.2 MMF units in 2015
TFE vented from the MMF Process in the reporting year:
0.0182 kg TFE x 642.2 MMF unit = 11.69 kg TFE
MMF unit
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
VOC Emissions
11.69 kg TFE
Waste Gas Scrubber x (100%-0%) control efficiency
11.69 kg TFE = 25.77 lb. THE
25.77 lb. VOC
•
DEQ-CFW 00069250

MMF Process Point Source Emission Determination
Page 2 of 9
•
B. DMC CAS No. 616-38-6
Carbonic acid, dimethyl ester
HF Potential:
DMC is a VOC without the potential to form HF
DMC Quantity Generated:
Before -control DMC emission rate per the Process Flowsheet #5600:
Source
DMC Vent Rate
MTP Rx
0.0249
kg DMC vented per MMF unit
Neutralizer
0.0315
kg DMC vented per MMF unit
Wash Tk
0.0057
kg DMC vented per MMF unit
Crude MTP Tk
0.0075
kg DMC vented per MMF unit
Crude DMC Tk
0.0099
kg DMC vented per MMF unit
DMC Still
0.0396
kg DMC vented per MMF unit
Total
0.1192
kg DMC vented per MMF unit
The before -control DMC emission is based on 642.2 MMF units in 2015
DMC vented from the MMF Process in the reporting year:
0.1192 kg DMC x 642.2 MMF unit = 76.53 kg DMC
MMF unit
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
VOC Emissions
76.53 kg DMC
Waste Gas Scrubber x (100%-0%) control efficiency
= 76.53 kg DMC = 168.72 lb. DMC
168.72 1b. VOC
•
DEQ-CFW 00069251

•
•
•
MMF Process
C. DME
Dimethyl ether
HF Potential:
DME is a VOC without the potential to form HF
DME Quantity Generated:
Point Source Emission Determination
Page 3 of 9
Before -control DME emission rate per the Process Flowsheet #5600:
CAS No. 115-10-6
Source
DME Vent Rate
MTP Rx
0
kg DME vented per MMF unit
Neutralizer
0.000214
kg DME vented per MMF unit
Wash Tk
0.000138
kg DME vented per MMF unit
Crude MTP Tk
0.000221
kg DME vented per MMF unit
Crude DMC Tk
0
kg DME vented per MMF unit
DMC Still
0.00860
kg DME vented per MMF unit
Total
0.00917
kg DME vented per MMF unit
The before -control RSU emission is based on 642.2 MMF units in 2015
DME vented from the MMF Process in the reporting year:
0.00917 kg DME x 642.2 MMF unit =
MMF unit
5.89 kg DME
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
VOC Emissions
5.89 kg DME
Waste Gas Scrubber x (100%-99.6%) control efficiency
0.02 kg DME = 0.05 lb. DME
0.05 1b. VOC
DEQ-CFW 00069252

•
•
MMF Process Point Source Emission Determination
Page 4 of 9
D. MTVE CAS No. 3823-94-7
Methyl Trifluorovinyl Ether
HF Potential:
MTVE is a VOC without the potential to form HF
MTVE Quantity Generated:
Before -control MTVE emission rate per the Process Flowsheet #5600:
Source
MTVE Vent Rate
MTP Rx
0.00057
kg MTVE vented per MMF unit
Neutralizer
0.00049
kg MTVE vented per MMF unit
Wash Tk
0.00019
kg MTVE vented per MMF unit
Crude MTP Tk
0.00042
kg MTVE vented per MMF unit
Crude DMC Tk
0
kg MTVE vented per MMF unit
DMC Still
0
kg MTVE vented per MMF unit
Total
0.00166
kg MTVE vented per MMF unit
The before -control MTVE emission is based on 642.2 MMF units in 2015
MTVE vented from the MMF Process in the reporting year:
0.00166 kg MTVE x 642.2 MMF unit = 1.07 kg MTVE
MMF unit
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
VOC Emissions
1.0679 kg MTVE
Waste Gas Scrubber x (100%-99.6%) control efficiency
0.0043 kg MTVE = 0.009 lb. MTVE
= 0.009 lb. VOC
DEQ-CFW 00069253

•
MMF Process Point Source Emission Determination
Page 5 of 9
E. MTFE (Methyl tetrafluoroethyl ether) CAS No. 425-88-7
1-methoxy-1,1,2,2-tetrafluoroethane
HF Potential:
MTFE is a VOC without the potential to form HE
MTFE Quantity Generated:
Before -control MTFE emission rate per the Process Flowsheet #5600:
Source
MTFE Vent Rate
MTP Rx
0.001269
kg MTFE vented per MMF unit
Neutralizer
0.000489545
kg MTFE vented per MMF unit
Wash Tk
0.00019306
kg MTFE vented per MMF unit
Crude MTP Tk
0.000420595
kg MTFE vented per MMF unit
Crude DMC Tk
0
kg MTFE vented per MMF unit
DMC Still
0
kg MTFE vented per MMF unit
Total
0.00237
kg MTFE vented per MMF unit
The before -control MTFE emission is based on 642.2 MMF units in 2015
MFTE vented from the MMF Process in the reporting year:
0.00237 kg MTFE x 642.2 MMF unit = 1.52 kg MTFE
MMF unit
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
VOC Emissions
1.523 kg MTFE
Waste Gas Scrubber x (100%-99.6%) control efficiency
0.006 kg MTFE = 0.013 lb. MTFE
0.013 Ib. VOC
DEQ-CFW 00069254

Ci
MMF Process Point Source Emission Determination
Page 6 of 9
F. MTP
Methyl-3-methoxy-tetrafluoropropionate
HF Potential:
MTP is a VOC without the potential to form HF
MTP Quantity Generated:
Before -control MTP emission rate per the Process Flowsheet 45600:
CAS No. 755-73-7
Source
MTP Vent Rate
MTP Rx
0.0000028
kg MTP vented per MMF unit
Neutralizer
0.001041
kg MTP vented per MMF unit
Wash Tk
0.000365
kg MTP vented per MMF unit
Crude MTP Tk
0.000503
kg MTP vented per MMF unit
Crude DMC Tk
0.0000007
kg MTP vented per MMF unit
DMC Still
0
kg MTP vented per MMF unit
Total
0.00191
kg MTP vented per MMF unit
The before -control MTP emission is based on 642.2 MMF units in 2015
MTP vented from the MMF Process in the reporting year:
0.00191 kg MTP x 642.2 MMF unit = 1.23 kg MTP
MMF unit
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
MTP Emissions
1.229 kg MTP
Waste Gas Scrubber x (100%-99.6%) control efficiency
0.005 kg MTP = 0.011 lb. MTP
0.011 lb. VOC
DEQ-CFW 00069255

•
I*
MMF Process Point Source Emission Determination `f
Page 7 of 9
G. BMTK CAS No. 1422-71-5
Bis(2-methoxytetrafluoroethyl)ketone
HF Potential:
BMTK is a VOC without the potential to from HF.
BMTK Quantity Generated:
Before -control BMTK emission rate per the Process Flowsheet #5600:
Source
BMTK Vent Rate
MTP Rx
0
kg BMTK vented per MMF unit
Neutralizer
0.000089635
kg BMTK vented per MMF unit
Wash Tk
0.000034475
kg BMTK vented per MMF unit
Crude MTP Tk
0.00004137
kg BMTK vented per MMF unit
Crude DMC Tk
0
kg BMTK vented per MMF unit
DMC Still
0
kg BMTK vented per MMF unit
Total
0.00016548
kg BMTK vented per MMF unit
The before -control BMTK emission is based on 642.2 MMF units in 2015
BMTK vented from the MMF Process in the reporting year:
0.000165 kg BMTK x 642.2 MMF unit = 0.11 kg BMTK
MMF unit
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
BMTK Emissions
0.10627 kg BMTK
Waste Gas Scrubber x (100%-99.6%) control efficiency
0.00043 kg BMTK = 0.001 lb. BMTK
0.001 lb. VOC
DEQ-CFW 00069256

�J
•
MMF Process Point Source Emission Determination
Page 8 of 9
H. MTP Acid CAS No. 93449-21-9
HF Potential:
MTP Acid is a VOC without the potential to form HE
MTP Acid Quantity Generated -
Before -control MTP Acid emission rate per the Process Flowsheet #5600:
Source
MTP Acid Vent Rate
MTP Rx
0.000000
kg MTP Acid vented per MMF unit
Neutralizer
0
kg MTP Acid vented per MMF unit
Wash Tk
0.000020685
kg MTP Acid vented per MMF unit
Crude MTP Tk
0.000034475
kg MTP Acid vented per MMF unit
Crude DMC Tk
0
kg MTP Acid vented per MMF unit
DMC Still
0
kg MTP Acid vented per MMF unit
Total
0.00005516
kg MTP Acid vented per MMF unit
The MTP Acid emission* is based on 642.2 MMF units in 2015
* before -control emissions
MTP Acid vented from the MMF Process in the reporting year:
0.000055 kg MTP Acid x 642.2 MMF unit = 0.035 kg MTP Acid
MMF unit
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
MTP Acid Emissions
0.035 kg MTP Acid
Waste Gas Scrubber x (100%-99.6%) control efficiency
0.00014 kg MTP Acid = 0.0003 lb. MTP Acid
0.0003 lb. VOC
DEQ-CFW 00069257

•
•
•
MMF Process
I. CHM
Methyl fluoride
HF Potential:
CH3F is a VOC without the potential to form HE
Point Source Emission Determination
Page 9 of 9
CH3F Quantity Generated:
Before -control CH317 emission rate per the Process Flowsheet #9599:
CAS No. 593-53-3
Source
CH3F Vent Rate
MTP Reactor
0
kg CH3F vented per MMF unit
Neutralizer
0
kg CH317 vented per MMF unit
Wash Tk
0
kg CH3F vented per MMF unit
Crude MTP Tk
0
kg CH317 vented per MMF unit
Crude DMC Tk
0
kg CH317 vented per MMF unit
DMC Still
MMF Reactor
0
kg CH317 vented per MMF unit
1.52
kg CH317 vented per MMF unit
Total
1.52
kg CH317 vented per MMF unit
The before -control CH317 emission is based on 642.2 MMF units in 2015
CH3F vented from the MMF Process in the reporting year:
1.52 kg CH317 x 642.2 MMF unit =
MMF unit
974.2 kg CH3F
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
CH3F Emissions
974.2 kg CH3F
Waste Gas Scrubber x (100%-99.6%) control efficiency
3.9 kg CH317 = 8.6 lb. CH3F
8.6 1b. VOC
DEQ-CFW 00069258

•
•
•
MMF Process Fugitive / Equipment Emissions
Page 1 of 2
Fugitive and Equipment Emissions Determination (Non -point Source):
Fugitive (FE) and Equipment Emissions (EE) are a function of the number of emission points in the
plant (valves, flanges, pump seals). The inventory shown below is conservative and based on plant
and process diagrams. Note that the calculations below include the following: (1) equipment
emissions not inside buildings, which are "fugitive" in nature and will be reported as such, and
(2) equipment emissiion in side buildings, which are not "fugitive" in nature and will be reported as
equipment emissions only.
A. Fugitive emissions from MMF equipment outside of the barricade:
Emissions from this equipment are not inside a building and are therefore "fugitive" in nature.
Valve emissions: 552 valves x 0.00036 Ib/hr/valve = 0.199 Ib/hr EE
Flange emissions: 100 flanges x 0.00018 Ib/hr/flange = 0.018 Ib/hr EE
Total equipment emission rate = r
Days of operation = 38
On average 0.13 Ibs of HF are produced for every 1 pound of process material released
VOC: 0.217 Ib/hr EE HF: 0.217 Ib/hr EE
x 24 hours/day x 24 hours/day
x 38 days/year x 38 days/year
= 197.6 Ib/yr VOC from EE x 0.13 lb HF per lb VOC
= 25.7 Ib/yr HF from EE
B. Equipment Emissions From MMF Reactor and Transfer Tank
This equipment is inside a building, therefore emissions are not true Fugitive Emissions
Valve emissions: 88 valves x 0.00036 Ib/hr/valve = 0.032 Ib/hr FE
Flange emissions: 10 flanges x 0.00018 Ib/hr/flange = 0.002 Ib/hr FE
Total fugitive emission rate = 0.033 Ib/hr FE
VOC: 0.033 lb. FE/hr HF:
x 24 hours/day
x 38 days/year
= 30.5 Ib/yr VOC from EE
0.033 lb. FE/hr
x 24 hours/day
x 38 dayslyear
x 0.13 lb HF per lb VOC
4.0 Ib/yr HF from EE
DEQ-CFW 00069259

•
•
MMF Process
C. Total MMF Plant Non -Point Source Emissions
Fugitive
Emissions
VOC HF
Emission Source Ib/yr Ib/yr
A. Fugitive emissions from MMF equipment 197.6 25.7
outside of the barricade:
B. Equipment Emissions From MMF 0 0
Reactor and Transfer Tank
Total for 2015 197.6 25.7
E. VOC Emission by Source Type
Fugitive / Equipment Emissions
Page 2 of 2
Equipment
Emissions
VOC HF
Ib/yr Ib/yr
0 0
30.5 4.0
30.5 4.0
® C
C V
d C
Q C
M
a+
N
C
Q
C'n
'Da)F-
0r �
(
�
0
Z
U
O
L L.
li
W
W
DMC
168.7
164.1
0
0
332.9
DME
0.1
0.1
0
0
0.1
MTVE
0.01
0.01
0
0
0.02
MTFE
0.01
0.01
0
0
0.03
MTP
0.01
0.01
0
0
0.02
BMTK
0.001
0.001
0
0
0.002
MTP Acid
0.0003
0.000
0
0
0.001
TFE
25.8
25.1
0
0
50.8
CHY
8.6
8.4
6.7
0
23.7
MMF
0
0
23.8
0
23.8
Total
203.2
197.6
30.5
0.0
431.3
Note: Speciated equipment emissions were estimated by assuming that each
compound's equipment emission concentration was equal to that compound's
stack emission fraction of the total stack emission.
Example: The DMC equipment emissions were determined by the ratio of the
DMC stack emission (254.7 lb) divided by the total stack emission (306.7 lb),
multiplied by the total equipment emissions (358.9 lb).
Specifically: 168.7 197.E = 164.1 lb. DMC
203.2
DEQ-CFW 00069260

•
Resins Process
NS-G
•
•
DEQ-CFW 00069261

J
[I
0
•
Air Emissions Inventory
Yearly Emission Summary
A. VOC Compound Summary
Resins Process (NS-G)
Emission Summary
Page 1 of 1
NS-G SR/CR Resins Manufacturing Process
Compound
CAS Chemical Name
CAS No.
Emission
(Ib)
PSEPVE
Perfluoro(4-methyl-3,6-dioxaoct-7-ene) sulfonyl
fluoride
16090-14-5
1,513
EVE
methyl2,2,3,3-tetrafluoro-3-({1,1,1,2,3,3-hexafluoro-3-
[(trifluoroethenyl)oxy]propan-2-yl}oxy)propanoate
63863-43-4
1,372
TFE
Tetrafluoroethylene
116-14-3
12,153
E-2
2H-Perfluoro(5-Methyl-3,6-Dioxanonane)
3330-14-1
3,492
McOH
Methanol
67-56-1
149
Total VOC Emissions (lb.)
18,679
Total VOC Emissions (tons)
9.34
B. Toxic Air Pollutant Summary
NS-G SR/CR Resins Manufacturing Process
Compound
CAS Chemical Name
CAS No.
Emission
(lb)
F-113
Trichloro-1,2,2-trifluoro-1,1,2 Ethane
76-13-1
0
HF
Hydrogen Fluoride
7664-39-3
0.6
McOH
Methanol
67-56-1
149
DEQ-CFW 00069262

•
•
0
Air Emissions Inventory Resins Process (NS-G)
Emissions Determination
Page 1 of 2
Total raw materials fed (M) , kgs
E-2
Solution
Addition
PSEPVE
Solution
Addition
Totalized
PSEPVE
Feed
EVE
Solution
Addition
Totalized
EVE Feed
Totalized
TFE Make-
up
Totalized
DP
Addition
SR
Consumpt
ion
CR
Consumpt
ion
M
(kg)
Jan-15
561
1,944
4,230
0
0
5,717
484
8,559
1,375
22,870
Feb-15
601
764
5,033
0
0
6,197
425
7,640
441
21,101
Mar-15
1,533
1,333
3,499
0
0
4,553
428
4,743
2,233
18,322
Apr-15
4,177
2,101
1,204
0
0
1,556
141
8,319
1,880
19,378
May-1 5
1,192
1,213
4,006
0
0
4,696
510
7,114
1,268
19,999
Jun-15
280
318
3,480
0
0
3,958
244
6,323
0
14,603
Jul-15
1,796
288
3,439
0
0
3,951
231
6,119
2,843
18,667
Aug-15
276
1,632
5,280
0
0
6,471
393
10,071
442
24,565
Sep-15
1,769
189
1,750
0
0
1,984
120
4,114
0
9,926
Oct-15
5,162
0
0
1,905
2,993
4,611
208
0
450
15,329
Nov-15
2,573
2,556
4,596
0
0
5,559
232
9,005
2,158
26,679
Dec-15
1,488
0
5,792
0
0
7,471
401
9,186
2,678
1 27,016
Total transformed materials collected (P) , kgs
Polymer
N/S
Polymer
Purge &
Adhesion
s
Purge
Vent Port
Juice
P
(kg)
Jan-15
7,445
746
242
452
246
9,132
Feb-15
10,025
48
160
175
0
10,409
Mar-15
6,833
49
0
61
0
6,942
Apr-15
2,095
0
239
401
165
2,900
May-15
7,472
207
86
39
0
7,803
Jun-15
6,251
0
195
418
285
7,148
Jul-15
6,656
0
0
211
0
6,867
Aug-15
10,526
0
302
262
187
11,277
Sep-15
3,063
0
0
257
0
3,320
Oct-15
1 6,982
0
0
10
0
6,992
Nov-15
1 8,532
0
416
244
35
9,227
Dec-15
1 11,812
0
0
0
0
11,812
Total untransformed materials collected (W) , kgs
SR
Issued
CR
Issued
Solution
Increase
VE to
Filters/Sie
ves
E2 to
Filters/Sie
ves
W
(kg)
Jan-15
8,370
1,290
2,881
448
493
13,483
Feb-15
7,594
398
947
877
761
10,577
Mar-15
6,375
2,161
2,077
290
341
11,245
Apr-15
8,100
1,703
3,000
1,710
1,486
15,999
May-15
6,842
1,224
3,321
200
183
11,770
Jun-15
6,091
0
-95
436
376
6,809
Jul-15
6,320
2,751
1,837
85
73
11,067
Aug-15
10,249
420
1,098
752
721
13,240
Sep-15
4,187
0
1,869
175
150
6,381
Oct-15
0
441
6,611
0
1 0
11 1052
Nov-15
7,891
2,065
5,192
378
326
15,853
Dec-151
9,820
1 2,146
150
411
355
12,882
DEQ-CFW 00069263

Air Emissions Inventory Resins Process (NS-G) v'
Emissions Determination
Page 2 of 2
•
VOC emissions from the filling of storage tanks (S)
Total
PSEPVE
loss from
Tank
Total EVE
loss from
Tank
Total E-2
loss from
Tank
Total
McOH
Emissions
(kg)
S
(kg)
Jan-15
0
0
1
22
23
Feb-15
1 0
0
1
25
27
Mar-15
0
0
1
15
17
Apr-15
0
0
1
7
8
May-15
0
0
1
15
16
Jun-15
0
0
1
19
20
Jul-15
0
0
1
19
20
Aug-15
0
0
1
21
23
Sep-15
0
0
1
8
9
Oct-15
0
0
1
12
14
Nov-15
0
0
1
21
22
Dec-15
0
0
1
21
23
Total VOC Emissions (lb) : E = ( M - P - W + S ) x 2.2
M
(kg)
P
(kg)
W
(kg)
S
(kg)
E
(kg)
E
(lb)
Jan-15
22,870
9,132
13,483
23
278
612
Feb-15
21,101
10,409
10,577
27
141
311
Mar-15
18,322
6,942
11,245
17
152
333
Apr-15
19,378
2,900
15,999
8
487
1,071
May-15
19,999
7,803
11,770
16
443
1 974
Jun-15
14,603
7,148
6,809
20
667
1,467
Jul-15
18,667
6,867
11,067
20
754
1,658
Aug-15
24,565
11,277
13,240
23
71
156
Sep-15
9,926
3,320
6,381
9
234
515
Oct-15
15,329
6,992
7,052
14
1,299
2,857
Nov-15
26,679
9,227
15,853
22
1,621
3,566
Dec-15
27,016
11,812
12,882
23
2,344
5,158
Total VOC Emissions (lb)
18,679
Total VOC Emissions (ton)
9.34
•
DEQ-CFW 00069264

•
Nafion® Membrane Process
NS-H
•
•
DEQ-CFW 00069265

a
Membrane Treatment (NS-H)
Page 1 of 3
Emission source/Operating Scenario Data f�
1. Emission Source ID No. NS-H
Actual emissions per pollutant listed for source/process identified on page 1:
Criteria (NAAQS) pollutants
Pollutant
code
missions-
Criteria
pollutants
(tons/yr)
Emission
estimation
method
code
control
efficiency
2015
Carbon Monoxide
CO
0
2
NOx
NOx
0
2
TSP
TSP
0
2
PM 2.5
PM-2.5
0
2
PM 10
PM-10
0
2
SO2
SO2
0
2
VOC
VOC
14.7
2
0%
Criteria (NAAQS) pollutants
Pollutant
code
Emissions-
Criteria
pollutants
(lb/yr)
Emission
estimation
method
code
control
efficiency
2015
HAP/TAP pollutants
CAS #
2
0%
Acetic Acid
64-19-7
95
2
0%
Hydrogen Fluoride
7664-39-03
1 119
1 2
1 0%
DEQ-CFW 00069266

•
Membrane Treatment (NS-H)
Page 2 of 3
NS-H Membrane treatment (extrusion & hydrolysis) summary report.
DMSO Emissions yr
Units
2015
Waste Shipped
Ibs/yr
38100
Waste in storage tk yr end
gallons
5293
Waste in storage tk yr end
Ibs
53992
Waste % in storage tk yr end
%
88%
DMSO Waste Content
wt%
11 %
DMSO in Waste liquid
Ibs/yr
10130
DMSO Shipped as Waste liquid
Ibs/yr
4191
KOH/DMSO waste pumped to waste treatment
gal/yr
18108
Ibs/yr
184705
DMSO pumped to waste treatment
Ibs/yr
20318
DMSO Inventory
inv. Begin year
drums
12
inv. End year
drums
16.668
DMSO Drums Rec
drums
124
Wt/Drum
lb/drum
500
total DMSO consumed
Ibs
59666
DMSO Emissions into air Ibs/ r 29218
DMSO Emissions into air tons/yr 14.61
Acetic Acid Emissions air
1st Quarter
hrs
17.7
2nd Quarter
hrs
9.5
3rd Quarter
hrs
39.8
4th Quarter
hrs
63.2
Total
hrs
130.2
Acetic Acid Emissions Rate Ibs/hr 0.727
Acetic Acid HAP/TAP Emissions Ibs/yr 94.6
Acetic Acid HAP/TAP Emissions tons/yr 0.047
Total VOC Emissions Ibs/yr 29313
Total VOC Emissions Itonslyr 14.66
DEQ-CFW 00069267

Throughput (production)
Hydrolysis product produced.
Hydrolysis surface treatment
1st qrt % hrs of operations
2nd qrt % hrs of operations
3rd qrt % hrs of operations
4th qrt % hrs of operations
HF Emissions
•
•
m2
m2
SR Resin Extruded kg/yr
CR Resin Extruded kg/yr
total polymer extruded kg/yr
kgHF/kg SR@275deg C
kg HF / kg CR @ 275 deg C
201136.89
30745.65
26.49%
20.31 %
27.15%
26.05%
78,981
7,834
86,815
im
kg SR Resin extruded per year 78,981
kg HF / kg SR @ 275 deg C 0.00068
kg HF emitted per yearl 53.3
kg SR Resin extruded per year 7,834
kg HF / kg SR @ 275 deg C 0.00008
kg HF emitted per yearl 0.6
Total HF Formed kgiyr 54
Total HF HAP/TAP Emissions Ibs/yr 119
Membrane Treatment (NS-H)
Page 3 of 3
DEQ-CFW 00069268

•
Nafion® Membrane Coating
NS-1
•
•
DEQ-CFW 00069269

•
•
Emission source/Operating Scenario Data
1. Emission Source ID No.
Membrane Spraybooth (NS-1)
Page 1 of 2
D
NS-1
Actual emissions per pollutant listed for source/process identified on page 1:
Criteria (NAAQS) pollutants
Pollutant
code
Emissions -Criteria
pollutants tons/ r
Emission
estimation
control
efficient
2015
Carbon Monoxide
CO
0
8
NOx
NOx
0
8
TSP
TSP
0.34
8
0%
PM 2.5
PM-2.5
0.34
8
0%
PM 10
PM-10
0.34
8
0%
S02
S02
0
8
VOC
VOC
29.68
8
0%
DEQ-CFW 00069270

Coating Process yr 2015
Max Spray Coat Rate cc/min (2 guns) 400
Max Process Rate gal/hr 6.3
Paint Batches batch 192
Gallons/batch gals 50
Gallons from Original batches gals 9600
Remade batches batchs 0
Gallons added/batch gals 5
Gallons added to remake batchs gals 0
Annual Process Throughput gals/yr 9600
Coating Density lb/gal 7.928
Coating Consumed Ibs/yr 76109
VOC Emissions
Ethanol wt % 69%
Methanol wt % 1 %
1-Pro anol wt % 8%
Annual VOC Emissions Ibs/yr 59365
F—tons/yr 29.68
TSP Emissions
Coating Solids wt % 18%
Paint Arrestor Effic % 95%
Solids Produced Ib/yr 13700
Annual TSP Emissions Ibs/yr 685.0
total suspended particles tons/yr 0.34
NS-1 Membrane Spraybooth (NS-1)
Page 2 of 2
DEQ-CFW 00069271

•
E-2 Process
NS-K
•
•
DEQ-CFW 00069272

•
•
1]
E-2 Process (NS-K) �.
Page 1 of 1
2015 AIR EMISSIONS INVENTORY SUPPORTING DOCUMENTATION
Emission Source ID No.:
Emission Source Description:
Process and Emission Description:
NS-K
Nafion E-Fluids Production Process
The E2 process is a batch manufacturing process. All emissions from this process
vent to the atmosphere, some via a vertical stack. The control of emissions of
certain compounds will be addressed in the attached spreadsheet.
Basis and Assumptions:
Engineering calculations using compositions, volumes and paritial pressures are used
to determine amounts vented. See attached information for assumptions made for
each vessel.
Information Inputs and Source of Info.:
Information Input
Source of Inputs
E2 production quantity
E2 Production Facilitator
Speciated emission rates
Attached calculations
Point Source Emissions Determination:
Point source emissions for individual components are given in the attached
spreadsheet
Equipment Emissions and Fugitive Emissions Determination:
Emissions from equipment leaks which vent as stack (point source) emissions and
true fugitive (non -point source) emissions have been determined using equipment
component emission factors established by DuPont. The determination of those
emissions are shown in a separate section of this supporting documentation.
DEQ-CFW 00069273

•
E-Fluids Process (NS-K)
Emission Summary
Page 1 of 1
2015 Emission Summary
A. VOC Emissions by Compound and Source
Point Source
Fugitive
Equipment
Accidental
Total VOC
Emissions
Emissions
Emissions
Emissions
Emissions
Compound
CAS Chemical Name
CAS No.
(lb.)
(lb.)
(lb.)
(lb.)
(lb.)
E1
Propane, 1,1,1,2,2,3,3-heptafluoro-
3330-15-2
260.7
24.1
0
0
284.8
3-(1,2,2,2- tetrafluoroethoxy)-
E2
2H-perfluoro(5-methyl-3,6-
3330-14-1
199.1
18.2
0
0
217.3
dioxanonane)
E3
2H-perfluoro-5,8-dimethyl-3,6,9-
3330-16-3
1.7
0.2
0
0
1.9
trioxadodecane
TOTAL 461.6 42.4
0
0
504.0
TOTAL (TON)
0.25

•
Point Source Emission Determination
A. "Freon" E1
Propane, 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2,2- tetrafluoroethoxy)-
HF Potential:
E1 is a VOC without the potential to form HE
El Quantity Generated:
E-Fluids Process (NS-K)
Point Source Emission Determination
Page 1 of 3
CAS No. 3330-15-2
E1 emissions are calculated on a "per batch" basis from Detailed Point Source worksheet
Source
E1 Emissions
Transfer Tank
2.00
lbs E 1 vented per batch
Interface Tank
0.29
lbs E 1 vented per batch
55 gal. drum
0.53
lbs E1 vented per batch
Total
2.82
lbs E1 vented per batch
The quantity (pounds) of E 1 vented is based on 42 batches of produced Crude E-fluids
2015 annual E1 emissions vented from the E-Fluids Process are calculated by the following:
2.82 lb E1 x
batch
•
42 batches = 118.25 kg E 1
= 260.7 lb El
= 260.7 lb VOC
DEQ-CFW 00069275

•
•
•
B. "Freon" E2
2 H-perfluoro(5-m ethyl-3,6-dioxano na ne)
HF Potential:
E2 is a VOC without the potential to form HF.
E2 Quantity Generated:
E-Fluids Process (NS-K)
Point Source Emission Determination
Page 2 of 3
CAS No. 3330-14-1
E2 emissions are calculated on a "per batch" basis from Detailed Point Source worksheet
Source
E2 Emissions
Transfer Tank
1.54
lbs E2 vented per batch
Interface Tank
0.22
lbs E2 vented per batch
55 gal. drum
0.40
lbs E2 vented per batch
Total
2.15
lbs E2 vented per batch
The quantity (pounds) of E2 vented is based on 42 batches of produced Crude E-fluids
2015 annual E2 emissions vented from the E-Fluids Process are calculated by the following:
2.15 lb E2 x
batch
42 batches = 90.32 kg E2
= 199.1 lb E2
= 199.1 lb VOC
DEQ-CFW 00069276

•
L---A
E-Fluids Process (NS-K)
Point Source Emission Determination
Page 3 of 3
C. "Freon" E3
2 H-perfluoro-5,8-dimethyl-3,6,9-trioxad odeca n e
HF Potential:
E3 is a VOC without the potential to form HF.
E3 Quantity Generated_
E3 Emissions calculated on per batch basis from Detailed Point Soure worksheet
CAS No. 3330-16-3
Source
E3 Emissions
Transfer Tank
0.01
lbs E3 vented per batch
Interface Tank
0.002
lbs E3 vented per batch
55 gal. drum
0.004
lbs E3 vented per batch
Total
0.02
lbs E3 vented per batch
The quantity (pounds) of E3 vented is based on 42 batches of produced Crude E-fluids
2015 annual E3 emissions vented from the E-Fluids Process are calculated by the following:
0.02 lb E3 x
batch
42 batches = 0.79 kg E3
1.7 lb E3
1.7 lb VOC
DEQ-CFW 00069277

•
•
•
E-2 Process (NS-K)
Detailed Point Source Calculations
Page 1 of 3
Detailed Point Source Calculations
Background
Three vessels inside the E2 Building vent to the E2 Bldg. stack (EP-NEP-1). The vessels are the Transfer
Tank, Interface Tank and a polypropylene 55 gal. drum. The crude E-fluids tote is filled on the outside on the
E2 building, therefore vented emissions from this tote are true "Fugitive Emissions" and will be reported as
such.
A. Transfer Tank
The Transfer tank is a 150 gallon vessel that is filled at a rate of 7.3 gal/min. The operating temperature
during the filling is 40 degrees C. The tank is filled with 125 gallons of material. We will assume that entire
tank volume (20 ft) is vented on filling.
Calculations:
PV = nRT (assumes the Ideal Gas Law)
Tank Volume = 150 gallons / 7.48 gal/ft3 = 20.05 ft3
Contents of vessel :
Component
MW
Kgs
Moles
Mol %
Vapor
Pressure
(psia)
Partial
Pressure*
(psia)
E1
286
22.00
0.08
15.09
14.00
2.11
E2
452
189.20
0.42
82.12
1.25
1.03
E3
618
8.80
0.01
1 2.79
1 0.23
1 0.01
Total
220.60
0.51
1 100%
* Partial Pressure = Vapor Pressure multiplied by Mol% divided by 100%
Tank temperature = 40 degrees Celsius is equal to 563.69 degrees R
R = 10.73 psia-ft3/lb-mol/degR
For E1: n = moles of E1 = (Partial pressure of E1) * (Volume) / (R) / (Temperature)
n = 2.11 psia x 20.05 ft3 = 0.0070 Ib-mol E1
10.73 psia-ft3/lb-mol/degR 563.69 degrees R
0.0070 Ib-mol E1 x 286 Ib E1 = 2.00 Ib El/batch
Ib-mol E1
For E2: n = moles of E2 = (Partial pressure of E2) * (Volume) / (R) / (Temperature)
n = 1.03 psia x 20.05 ft3 = 0.0034 Ib-mol E2
10.73 psia-ft3/lb-mol/degR 563.69 degrees R
0.0034 Ib-mol E2 x 452 Ib E2 = 1.54 Ib E2/batch
Ib-mol E2
For E3: n = moles of E3 = (Partial pressure of E3) * (Volume) / (R) / (Temperature)
n = 0.01 psia x 20.05 ft3 - 0.000021 Ib-mol E3
10.73 psia-ft3/lb-mol/degR 563.69 degrees R
0.000021 Ib-mol E3 x 618 Ib E3 = 0.01 Ib E3/batch
Ib-mol E3
1
DEQ-CFW 00069278

E-2 Process (NS-K)
Detailed Point Source Calculations
Page 2 of 3
B. Interface Tank
The Interface Tank is a 30 gallon vessel. The E-fluids are seperated from aqueous material in the Transfer
Tank and are sent to the Interface Tank. Once the Interface Tank is close to full, material is taken from the
Interface Tank to a 55 gallon drum. Assume temperature is 30 degrees C and entire tank volume is vented
during filling.
Calculations:
PV = nRT (assumes the Ideal Gas Law)
Tank Volume = 30 gallons / 7.48 gal/ft3 = 4.01 ft3
Contents of vessel :
Component
MW
Kgs
Moles
Mol %
Vapor
Pressure
(psia)
Partial
Pressure*
(psia)
E1
286
22.00
0.08
15.09
9.70
0.85
0.17
1.46
E2
452
189.20
0.42
82.12
0.70
E3
618
8.80
0.01
2.79
0.00
Total
220.00
0.51
100%
* Partial Pressure = Vapor Pressure multiplied by Mol% divided by 100%
Tank temperature = 30 degrees Celsius is equal to
545.69 degrees R
R =
10.73 psis-ft3/lb-mol/degR
For E1:
n = moles of E1 = (Partial pressure of E1) *
(Volume) / (R) / (Temperature)
n = 1.46 Asia x
4.01 ft3 = 0.0010 lb-mol E1
10.73 psia-ft3/lb-mol/degR
545.69 degrees R
0.0010 lb-mol E1 x
286 lb E1 = 0.29 Ib El/batch
lb-mol E1
For E2:
n = moles of E2 = (Partial pressure of E2) *
(Volume) / (R) / (Temperature)
n = 0.70 psis x
4.01 ft3 = 0.0005 lb-mol E2
10.73 psia-ft3/lb-mol/degR
545.69 degrees R
0.0005 lb-mol E2 x
452 lb E2 = 0.22 Ib E2/batch
lb-mol E2
For E3:
n = moles of E3 = (Partial pressure of E3) *
(Volume) / (R) / (Temperature)
n = 0.00 psia x
4.01 ft3 = 0.000003 lb-mol E3
10.73 psia-ft3/lb-mol/degR
545.69 degrees R
0.000003 lb-mol E3 x
618 lb E3 = 0.002 Ib E3/batch
lb-mol E3
•
DEQ-CFW 00069279

E-2 Process (NS-K)
Detailed Point Source Calculations ✓
Page 3 of 3
C. 55 gallon drum
This drum receives material from the Interface Tank. The E-fluids are pumped from this drum through the
dryer to remove any moisture that is present, before final loading into the Crude E-fluids tote. Assume filling
temerature is 30 degrees C and entire drum volume vents during filling.
Calculations:
PV = nRT (assumes the Ideal Gas Law)
Tank Volume = 55 gallons / 7.48 gal/ft3 = 7.35 ft3
Contents of vessel :
Component
MW
Kgs
Moles
Mol %
Vapor
Pressure
(psia)
Partial
Pressure'
(psia)
E1
286
22.00
0.08
15.09
9.70
0.85
0.17
1.46
E2
452
189.20
0.42
82.12
0.70
E3
618
8.80
0.01
1 2.79
0.00
Total
220.00
0.51
1 100%
* Partial Pressure = Vapor Pressure multiplied by Mol% divided by 100%
Tank temperature = 30 degrees Celsius is equal to
545.69 degrees R
R =
10.73 psia-ft3/lb-mol/degR
For El:
n = moles of E1 = (Partial pressure of E1) "
(Volume) / (R) / (Temperature)
n = 1.46 psia x
7.35 ft3 = 0.0018 lb-mol E1
10.73 psia-ft3/lb-mol/degR
545.69 degrees R
0.0018 lb-mol E1 x
286 lb E1 = 0.53 lb El/batch
lb-mol E1
For E2:
n = moles of E2 = (Partial pressure of E2)
(Volume) / (R) / (Temperature)
n = 0.70 psia x
7.35 ft3 = 0.0009 lb-mol E2
10.73 psia-ft3/lb-mol/degR
545.69 degrees R
0.0009 lb-mol E2 x
452 lb E2 = 0.40 lb E2/batch
lb-mol E2
For E3:
n = moles of E3 = (Partial pressure of E3)'
(Volume) / (R) / (Temperature)
n = 0.00 psia x
7.35 ft3 = 0.000006 lb-mol E3
10.73 psia-ft3/lb-mol/degR
545.69 degrees R
0.000006 lb-mol E3 x
618 lb E3 = 0.004 lb E3/batch
lb-mol E3
•
D. Total Point Source Emissions from E2-Fluids process
Chemical
lb/batch
No. of batches
Ibs
E1
2.82
42
118.3
E2
2.15
42
90.3
E3
0.02
42
0.8
Total
209.4
DEQ-CFW 00069280

•
E-2 Process (NS-K)
Fugitive/Equipment Emissions
Page 1 of 2
Fuaitive and Equipment Emissions Determination (Non -point Source):
Fugitive Emissions(FE) and Equipment Emissions (EE) are a function of the number of emission points in the
plant (valves, flanges, pump seals). For the equpiment emission calculations the inventory shown below is
conservative and based on plant and process diagrams. Note that the calculations below include equipment
emissions inside buildings as well as vessel emissions outside (fugitive emissions).
A. Fugitive Emissions from Crude E-fluids tote:
This 180-gallon tote is filled with dry crude E-fluids from the 55 gallon drum. This material then gets
transported to the Polymers area for use. This tote can hold several batches of material. This filling activity
occurs on the outside of the E2 building. Assume the filling is at 30 degrees Celsius and assume that one
batch of E-fluids displaces 33% of the tote, or 60 gallons of volume, during filling. These emissions will be
"Fugitive" in nature.
Calculations:
PV = nRT (assumes the Ideal Gas Law)
33% Tote Volume = 60 gallons / 7.48 gal/ft3 = 8.02 ft3
Contents of vessel
Component
MW
Kgs
Moles
Mol %
Vapor
Pressure
(psia)
Partial
Pressure*
(psia)
El
286
22.00
0.08
15.09
9.70
1.46
E2
452
189.20
0.42
82.12
0.85
0.70
E3
1 618
1 8.80
1 0.01
1 2.79
1 0.17
1 0.0047
Total
1
1 220.00
1 0.51
1 100%
* Partial Pressure = Vapor Pressure multiplied by Mol% divided by 100%
Tank temperature = 30 degrees Celsius is equal to 545.69 degrees R
R = 10.73 psia-ft3/lb-mol/degR
For E1: n = moles of E1 = (Partial pressure of E1) * (Volume) / (R) / (Temperature;
- - - -.
n = 1.46 psia
10.73 psia-ft3/lb-mol/degR
0.0020 Ib-mol E1
For E2
For E3
x
545.69 degrees R
x 286 Ib E1 =
Ib-mol E1
n = moles of E2 = (Partial pressure of E2) * (Volume) / (R) / (Temperature
n = 0.70 psia
10.73 psia-ft3/lb-mol/degR
0.0010 Ib-mol E2
x
545.69 degrees R
x 452 Ib E2 =
Ib-mol E2
0.0020 Ib-mol E1
0.57 Ib El/batch
0.0010 Ib-mol E2
0.43 Ib E2/batch
n = moles of E3 = (Partial pressure of E3) * (Volume) / (R) / (Temperature)
n = 0.0047 psia x 8.02 ft3 = 0.000007 Ib-mol E3
10.73 psia-ft3/lb-mol/degR
0.000007 Ib-mol E3 x
545.69 degrees R
618 Ib E3 =
Ib-mol E3
0.004 Ib E3/batch
DEQ-CFW 00069281

•
•
•
E-2 Process (NS-K)
Fugitive/Equipment Emissions
Page 2 of 2
Total Fugitive Emissions from E2-Fluids process
Chemical
lb/batch
No. of batches
Ibs
El
0.57
42
24.1
E2
0.43
42
18.2
E3
0.004
42
0.2
Total
42.4
B. Equipment Emissions From Valves, Pumps and Flanges
The emission rates for valves, flanges, etc. have been established by the DuPont Company. The emission
rates from these types of equipment in the E-fluids process is considered "Excellent' and therefore the
following rates are use: valve = (0.00039 Ib/hr), flange = (0.00018 Ib/hr)
Calculations:
Valve emissions: 134 valves x 0.00039 Ib/hr/valve =
Flange emissions: 20 flanges x 0.00018 Ib/hr/flange =
Total equipment emission rate
VOC: 0.0559 Ib/hr VOC
x 0 operating hrs/year
0.0 Ib/yr VOC
0,0523 Ib/hr VOC
0.0036 Ib/hr VOC
0.0559 Ib/hr VOC
8760
By Component:
We will assume that equipment emissions are the same composition as the crude E-fluids (Le. 10% E1,
86% E2, and 4% E3)
Total Equipment Emissions from E-fluids process:
Chemical
Chemical
Fraction
Total Equipment
Emission Rate
(lb/ r)
Total Equipment
Emission Rate
(lb/yr)
E1
10%
0.0
0.0
E2
86%
0.0
0.0
E3
4%
0.0
0.0
Total
0.0
Where the Chemical Emission Rate equals the Total Equipment Emission Rate
multiplied by the Chemical Fraction
DEQ-CFW 00069282

TFE/CO2 Separation Process
•
DEQ-CFW 00069283

TFE / CO2 Separation Process (NS-M)
Page 1 of 1 f
2015 Air Emissions Inventory Supporting Documentation
Emission Source ID No.: NS-M
Emission Source Description: TFE/CO2 Separation Process
Process and Emission Description:
The TFE/CO2 separation process is a continuous process. All emissions from this process vent
to either the Nafion Division Waste Gas Scrubber (WGS) or the area vent stack. The control of
emissions of the TFE compound will be addressed in the attached spreadsheet. TFE will pass
completely through the scrubber, therefore the efficiency is assumed to be 0%.
Basis and Assumptions:
A mass balance is used as the basis for the TFE/CO2 area emissions. The TFE/CO2 emissions
includes the TFE/CO2 area as well as the Polymers LJC and dryers. The flow of TFE/CO2 into
the area is divided by two in order to determine the amount of TFE fed to the system. Then each
of the end users (which includes polymers, semi -works, MMF and RSU) determine how much
they have consumed and these numbers are subtracted from the total TFE into the system to
determine the emissions. Mass flowmeters in each area are used to determine the total input and
output flows.
Information Inputs and Source of Inputs:
Information Input
Source of Inputs
TFE/CO2 consumption
Precursor Production Facilitator/IP21
Polymers Consumption
Polymers Production Facilitator/IP21
Semiworks Consumption
Semiworks Production Facilitator/IP21
MMF Consumption
Precursor Production Facilitator/IP21
RSU Consumption
Precursor Production Facilitator/IP21
Point Source Emissions Determination:
Point source emissions for individual components are given in the following pages. A detailed
explanation of the calculations are attached.
Equipment Emissions and Fugitive Emissions Determination:
Emissions from equipment leaks which vent as stack (point source) emissions and true fugitive
(non -point source) emissions have been determined using equipment component emission
factors established by DuPont. The determination of those emissions are shown in a separate
section of this supporting documentation.
DEQ-CFW 00069284

•
1]
•
TFE/CO2 Separation Process (NS-M)
Emission Summary J
Page 1 of 1
2015 Emission Summary
A. VOC Emissions by Compound
Point
Fugitive
Accidental
Total VOC
Naflon®
CAS Chemical
CAS No.
Source
Emissions
Emissions
Emissions
Compound
Name
Emissions
(lb)
(lb)
(lb)
(lb)
TFE
ITetrafluoroethylene
116-14-3
12720.5
38.0
1 0
12758.5
Total VOC Emissions
(lb)
12758
Total VOC Emissions (tons)
6.38
B. Additional Emissions by Compound
Point
Fugitive
Accidental
Total
Naflon®
CAS Chemical
CAS No.
Source
Emissions
Emissions
Emissions
Compound
Name
Emissions
(lb)
(lb)
(lb)
(lb)
CO2
Carbon dioxide
124-38-9
105.4
38.0
1 0
143.4
Total Emissions (lb)
143.4
Total Emissions (tons)
0.07
DEQ-CFW 00069285

•
11
is
TFE/CO2 Separation Process (NS-M)
Point Source Emission Determination
Page 1 of 2
Point Source Emission Determination
A. Tetrafluoroethylene (TFE)
HF Potential:
TFE is a VOC without the potential to form HF.
TFE Quantity Generated:
From Precursor area facilitator (mixture is 50% TFE and 50% CO2):
Source
Quantity
TFE/CO2 fed to area
191,270 kg TFE/CO2
Total
95,635 kg TFE fed to area
From area facilitators:
Source
Quantity Consumed
Polymers consumption
56,956 kg TFE
Semiworks consumption
1,159 kg TFE
MMF consumption
5,720 kg TFE
RSU consumption
26,030 kg TFE
Total
89,865 kg TFE consumed
TFE vented from the TFE/CO2 area in the reporting year:
95635 kg TFE fed
- 89865 kg TFE consumed
5770 kg TFE vented
VOC Emissions
5770.0 kg VOC
12720.5 lb. VOC
CAS No. 116-14-3
DEQ-CFW 00069286

TFE/CO2 Separation Process (NS-M)
Point Source Emission Determination
Page 2 of 2
•
B. Carbon dioxide (CO2) CAS No. 124-38-9
CO2 Quantity Generated:
From Precursor area facilitator (mixture is 50% TFE and 50% CO2):
Source
Quantity
TFE/CO2 fed to area
191;270 kg TFE/CO2
Total
95,635 kg CO2 sent to Separator
The separator is assumed to remove 99.95% of the CO2. Therefore, the CO2 in the exit strean
Source
I Quantity
CO2 in Product
1 47.8 kg CO2 exiting separator
Assume all CO2 in exit stream is vented.
CO2 Emissions
47.8 kg CO2
105.4 lb. CO2
•
DEQ-CFW 00069287

•
TFE/CO2 Separation Process (NS-M)'
Fugitive Emission Determination
Page 1 of 2
Fugitive and Equipment Emissions Determination (Non -point Source):
Fugitive emissions (FE) are a function of the number of emission points in the plant (valves,
flanges, pump seals). The inventory shown below is conservative and based on plant and
process diagrams. Note that the calculations below include only the equipment upstream of
the TFE/CO2 mass meter. All other fugative emissions are included in the system mass
balance.
A. Fugative emissions from TFE/CO2 truck unloading area to vaporizer:
This equipment is not inside a building, therefore emissions are true Fugitive Emissions
Valve emissions: 15 valves x 0.00036 Ib/hr/valve = 0.005 Ib/hr FE
Flange emissions: 24 flanges x 0.00018 Ib/hr/flange = 0.004 Ib/hr FE
Total TFE/CO2 emission rate = r
Days of operation = 251
VOC: 0.005 Ib/hr TFE FE
x 24 hours/day
x 251 days/year
= 29.3 Ib/yr VOC from EE
CO2: 0.0051b/hr CO2 FE
x 24 hours/day
x 251 days/year
= 29.3 Ib/yr CO2 from EE
B. Fugitive Emissions From TFE/CO2 Vaporizer to TFE/CO2 mass meter:
This equipment is not inside a building, therefore emissions are true Fugitive Emissions
Valve emissions: 2 valves x 0.00036 Ib/hr/valve
Flange emissions: 12 flanges x 0.00018 Ib/hr/flange
Total TFE/CO2 emission rate
Days of operation = 251
VOC: 0.0014 Ib/hr TFE FE
x 24 hours/day
x 251 days/year
= 8.7 Ib/yr VOC from EE
CO2: 0.0014 Ib/hr CO2 FE
x 24 hours/day
x 251 days/year
= 8.7 Ib/yr CO2 from EE
= 0.001 Ib/hr FE
= 0.002 Ib/hr FE
0.003 Ib/hr FE
DEQ-CFW 00069288

D. Total Non -Point Source Fugative Emissions
VOC
Emission Source Ib/yr
A. Fugative emissions from TFE/CO2 Truck 29 3
Unloading area:
B. Fugitive Emissions From TFE/CO2 8.7
Vaporizer
Total for 2015 38.0
Note: All VOC emissions are TFE. There are no other
VOC's used in the TFE/CO2 area.
CO2
Emission Source Ib/yr
A. Fugative emissions from TFE/CO2 Truck 29.3
Unloading area:
B. Fugitive Emissions From 8.7
Vaporizer
Total for 2015 38.0
•
TFE/CO2 Separation Process (NS-M)
Fugitive Emission Determination
Page 2 of 2
DEQ-CFW 00069289

L. J
HFPO Product Container Decontamination Process
NS-N
•
DEQ-CFW 00069290

HFPO Product Container Decontamination Process (NS-N)
Summary
Page 1 of 1
2015 Annual VOC Emissions Summary Q{j
HFPO Product Container Decontamination Process
Nafion®
Compound
CAS Chemical Name
CAS No.
VOC Emissions
(lbs)
HFPO
Hexafluoroproplyene oxide
428-59-1
19,406
HFA
Hexafluoroacetone
1 684-16-2
0
Total VOC Emissions (lb)
19,406
Total VOC Emissions (tons)
9.70
•
DEQ-CFW 00069291

HFPO Container Decontamination Process (NS-N)
1 of 2
0
•
•
Emission Unit ID: NS-N
Emission Source Description:
Emission Calculation Basis:
HFPO Product Container Decontamination Process
HFPO product containers returned from customers are decontaminated by venting residual
hexafluoropropylene oxide ("HFPO") to the Nafion Division Waste Gas Scrubber (WGS). To
determine the amount emitted from this process, the vapor density of HFPO is used along with the
volume of the container.
Vapor density is based on Aspen process simulation data at 13°C, which is 0.0377 kg/L.
130C was chosen based on the average 24 hour temperature for Audubon, NJ, which is located 30
miles northeast of Deepwater, NJ, the location of the primary customer of ISO containers and ton
cylinders, i.e. where containers are emptied. (determined from www.worldcli mate. com).
The mass of vapor in a container emptied of liquid is equal to the volume of the container multiplied by
the vapor density.
Mvap = V Nap
Volumes of the containers currently in use are as follows:
Container
Volume (L)
ISO Container
17,000
LINT Cylinder
1,000
1-Ton cylinder
760
3AA Cylinder
50
Reference
NBPF-0460 p. 10
BPF 353454
Columbiana Boiler Co. Literature
222.c-f-c.com/gaslink/cyl/hp3AAcyl.htm
Estimated mass of HFPO vapor emitted from the decontamination of each container is estimated to
be:
ISO Container
17,000 L X
0.0377 kg/L =
641 kg = 1,413 lb
UNT Cylinder
1,000 L X
0.0377 kg/L =
38 kg = 83 lb
1-Ton cylinder
760 L X
0.0377 kg/L =
29 kg = 63 Ib
3AA cylinder
50 L X
0.0377 kg/L =
2 kg = 4 lb
All containers are assumed to contain HFPO vapor. Occasionally some containers may contain
rearranged HFPO in the form of hexafluoroacetone ("HFA"), however this should not affect vapor
density since HFA has the same molecular weight as HFPO.
DEQ-CFW 00069292

HFPO Container Decontamination Process (NS-N)
2of2
•
Emission Calculation for 2015
Container Type
Quantity of
Containers
VOC per
container
(lb)
VOC
Emissions
(Ib)
F-GHG
Emissions
(mT)
ISO Container
9
1,413
12,716
5.768
LINT Cylinder
15
83
1,247
0.566
1-Ton cylinder
28
63
1,769
0.802
3AA Cylinder
18
4
75
0.034
Total VOC Emission for All Containers
15,807
7.170
Total VOC Emission for All Containers
7.90 tons
Total Containers Decontaminated 1 70
•
DEQ-CFW 00069293

Vinyl Ethers North Product Container Decontamination Process
NS-O
0
DEQ-CFW 00069294

VE North Container Decontamination (NS-O)
Page 1 of 3
Emission Unit IDs: NS-O
Emission Source Description: Vinyl Ethers North (VE-N) Product Container
Decontamination Process
Container Emission Estimation Basis:
Dimer, PPVE, PSPEVE and EVE are the products that are produced in the VEN facility. Usually
only PPVE is shipped to customers in 1-ton cylinders from the VE Nouth Manufacturing
Process. Prior to filling the containers, they are decontaminated by pressurizing with Nitrogren,
venting to the Waste Gas Scrubber (WGS) and evacuating for numerous cycles. TA NF-11-1821
has been written to fill on top of heels in cylinders without the need to decontaminate. This will
greatly reduce the emissions as a result of decontaminating product shipping containers. This
reduction should be reflected in the 2012 VE-N product container emissions report
To determine the amount emitted from this process, the vapor density of each component is used
along with the volume of the container.
Approximately 50°F (10°C) average year round temperature for Parkersburg, WV where
containters are emptied (use this temperature as worse case for all products). Assume when
containers are emptied they remain full of vapors.
All emissions from the process are vented through the Nafion Division Waste Gas Scrubber
(Control Device ID No. NCD-Hdr) which has a documented control efficiency of 99.6% for all
acid fluoride compounds. Dimer is an acid fluoride.
Vapor density is based on data from PM Report #231, PM Report PM-E-487 extrapolated to
10°C and the ideal gas equation.
Product
Vapor Density (lb/gal) @ 10°C
Dimer
0.020
PSEPVE
0.001
PPVE
0.034
EVE
0.010
The mass of vapor ("Mvap") in a container emptied of liquid is equal to the volume of the
container ("V") multiplied by the vapor density ("pvap").
Mvap = V * Pvap
•
DEQ-CFW 00069295

VE North Container Decontamination (NS-0)
Page 2 of 3
Volumes of the containers currently in use are as follows:
Container
Volume (gall
ISO
3828
UNT
264
1 ton cylinder
200
413W cylinder
57
4BA/3AA cylinder
15
Estimated emissions:
Before
After
Dimer
Control
Control
ISO
### gal
X
0.020 lb/gal =
76.56 lb
0.30624 lb
UNT
264 gal
X
0.020 lb/gal =
5.28 lb
0.02112 lb
1 ton cylinder
200 gal
X
0.020 lb/gal =
4 lb
0.016 lb
413W cylinder
57 gal
X
0.020 lb/gal =
1.14 lb
0.0046 lb
4BA/3AA cylinder
15 gal
X
0.020 lb/gal =
0.3 lb
0.0012 lb
PSEPVE
1 ton cylinder
200 gal
X
0.001 lb/gal =
0.2 lb
0.2 lb
413W cylinder
4BA/3AA cylinder
57 gal
15
X
X
0.001 lb/gal =
0.001 lb/gal =
0.057 lb
0.015 lb
0.057 lb
0.015 lb
gal
PPVE
1 ton cylinder
200 gal
X
0.034 lb/gal =
6.8 lb
6.8 lb
413W cylinder
57 gal
X
0.034 lb/gal =
1.938 lb
1.938 lb
4BA/3AA cylinder
15 gal
X
0.034 lb/gal =
0.51 lb
0.51 lb
EVE
1 ton cylinder
200 gal
X
0.010 lb/gal =
2 lb
2 lb
413W cylinder
57 gal
X
0.010 lb/gal =
0.57 lb'
0.57 lb
4BA/3AA cylinder
15 gal
X
0.010 lb/gal =
0.15 lb
0.15 lb
Emission Calculation:
Quantity
of
VOC per
VOC
Dimer
Containers
container
Emissions
ISO
1
X
0.306lb =
0.306lb
UNT
10
X
0.021 lb =
0.211 lb
1 ton cylinder
0
X
0.016 lb =
0 lb
413W cylinder
0
X
0.005 lb =
0 lb
16
4BA/3AA cylinder
0
X
0.001 lb =
0 lb
DEQ-CFW 00069296

VE North Container Decontamination (NS-0)
Page 3 of 3
•
PSEPVE
1 ton cylinder
0
X
0.2 lb =
0 lb
413W cylinder
0
X
0.1 lb =
0 lb
4BA/3AA cylinder
0
X
0.0 lb =
0 lb
PPVE
1 ton cylinder
25
X
6.8 lb =
170 lb
413W cylinder
28
X
1.9 lb =
54.26 lb
4BA/3AA cylinder
0
X
0.5 lb =
0 lb
EVE
1 ton cylinder
0
X
2.0 lb =
0 lb
413W cylinder
0
X
0.6 lb =
0 lb
4BA/3AA cylinder
0
X
0.2 lb =
0 lb
•
is
DEQ-CFW 00069297

.7
•
•
VE North Container Decontamination (NS-O)
Summary
Page 1 of 1
Year 2015
VE-North Product Container Decontamination Process Emission Summary:
Nafion®
Compound
CAS Chemical Name
CAS No.
Total
Emissions
(lb.)
DIMER
Perfluoro-2-Propoxy Propionyl Fluoride
2062-98-8
0.5
PSEPVE
Perfluorinated Sulfonyl Vinyl Ether
16090-14-5
0.0
PPVE
Perfluoropropyl Vinyl Ether
1623-05-8
224.3
EVE
Ester Vinyl Ether
63863-43-4
0.0
Total VOC Emissions (lb.) 225
Total VOC Emissions (tons) 0.11
DEQ-CFW 00069298

•
Pi
•
Vinyl Ethers South Product Container Decontamination Process
DEQ-CFW 00069299

•
VE South Container Decontamination (NS-P)
Emissions Determination
Page 1 of 2
Emission Unit IDs: NS-P
Vinyl Ethers South(VE-S) Product Container
Emission Source Description: Decontamination Process
Container Emission Estimation Basis:
PMVE, PEVE and PPVE are the products that are shipped to customers in 1-ton cylinders,
413W cylinders, 4BA/3AA cylinders and ISO tank containers from the VE South
Manufacturing Process. Prior to filling the containers, they are decontaminated by
pressurizing with Nitrogren, venting to the Waste Gas Scrubber(WGS) and evacuating for
numerous cycles. TA's(NF-09-1737 & NF-11-1821) have been written to fill on top of heels
in ISO containers as well as cylinders without the need to decontaminate. This will greatly
reduce the emissions as a result of decontaminating product shipping containers. This
reduction should be reflected in the 2012 VE-S product container emissions report
It is assumed that the product split between PMVE and PEVE is 70 to 30 by weight and
remains unchanged. PPVE is produced very infrequently in VE-S and is not used in the max
to emit calculations shown below.
It is assumed that the container split between cylinders and ISO's remains unchanged. For
PMVE, 48% to Iso and 52% to ton cylinders. Assume all PEVE is placed into 1 ton cylinders
At design capacity rates of the VE South Manufacturing Process, a maximum of 1,500 kg per
day at 70%/30% PM/PE split can be produced. For 365 operating days per year and 100%
uptime(worse case), this equates to 383,250 kgs of PMVE and 164,250 kgs of PEVE.
Approx. 50°F(101C) average year round temperature for Dordrecht Plant in the
Netherlands,where PMVE ISO containers are emptied(use this temp as worse case for all
products). Assume when containers are emptied they remain full of vapors. Vapor density
for PMVE at this temp is 0.2258 lb/gal and for PEVE 0.0901 lb/gal. These densities were
computed using the Peng-Robinson modification of the Redlich-Kwong equation of state.
Iso volume is 4,480 gallons. 1 ton container volume is 200 gallons
To calculate the amount of product vented per container, the container volume is multiplied
by the vapor density
DEQ-CFW 00069300

•
•
0
VE South Container Decontamination (NS-P)
Emissions Determination
Page 2 of 2
Maximum Potential Emissions Calculations
Decontaminated PMVE 1-ton cylinders (potential) : 243 cylinders
PMVE Product vented per 1-ton cylinder: 45 lb. VOC per cylinder
PMVE Emissions from 1-ton cylinders (potential) : 10,976 lb. VOC per year
Decontaminated PMVE ISO tank containers (potential) : 12 containers
PMVE Product vented per ISO tank container: 1,012 lb. VOC per container
PMVE Emissions from ISO tank containers (potential) : 12,406 lb. VOC per year
Decontaminated PEVE 1-ton cylinders (potential) : 205 cylinders
PEVE Product vented per I -ton cylinder: 18 lb. VOC per cylinder
PEVE Emissions from 1-ton cylinders (potential) : 3,700 IN VOC per year
Total potential emissions: 27,081 lb. VOC per year
Total potential emissions : 13.5 tons VOC per year
DEQ-CFW 00069301

VE South Container Decontamination (NS-P)
Summary
Page 1 of 1
•
Year 2015
VE-South VOC Container Emission Summary:
Nafion®
Compound
CAS Chemical Name
CAS No.
Total
Emissions
(TPY)
PMVE
Perfluoromethyl vinyl ether
1187-93-5
2.43
PEVE
Perfluoroeth I vinyl ether
10493-43-3
0.03
PPVE
IPerfluoropropyl vinyl ether
1 1623-05-8
0.00
Actual TPY Emitted from Containers 2.46
•
•
DEQ-CFW 00069302

Natural Gas/No. 2 Fuel Oil Fuel Oil -Fired Boiler
(139.4 Million BTU Per Hour Maximum Heat Input)
PS -A
•
•
DEQ-CFW 00069303

PS -A Natural Gas
•
•
•
NATURAL GAS COMBUSTION EMISSIONS CALCULATOR REVISION M 06/22/2015 - OUTPUT SCREEN
r" TT
i•
Instructions: Enter emission source I facility data on the "INPUT tab/screen. The air emission results and summary of input data are viewed I
printed on the "OUTPUT' tablscreen. The different tabs are on the bottom of this screen.
hICDENR
This spreadsheet is for your use only and should be used with caution. DENR does not guarantee the accuracy of the information contained. This
spreadsheet is subject to continual revision and updating. It is your responsibility to be aware of the most current information available. DENR is
not responsible for errors or omissions that may be contained herein.
SOUR E/FACILITY/ USER INPUT SUMMARY ROM INPUT SCREEN
COMPANY: Chemours Company Fayetteville Works
p Y " y
FACILITY ID
PERMIT NUMBER: 03735T42
EMISSION SOURCE DESCRIPTION: 139.4 MMBTU/HR NATURAL GAS -FIRED BOILER
EMISSION SOURCE ID NO.: PS -A
FACILITY CITY-1 Fayetteville
FACILITY COUNTY: Bladen
CONTROL DEVICE: I NO CONTROL
POLLUTANT
CONTROL EFF.
SPREADSHEET PREPARED BY: Michael E. Johnson
NOX
CALCD AS 0%
ACTUAL FUEL THROUGHPUT: 520.34 10-SCF/YR
FUEL HEAT VALUE: 1,020 BTU/SCF
POTENTIAL FUEL THROUGHPUT: 1,197.20 106 SCF/YR
BOILER TYPE: LARGE WALL -FIRED BOILER (> 100 mmBTU/HR) JNOSNCRAPPLIED
REQUESTED MAX. FUEL THRPT: 1,197.20 106 SCFlYR
1HOURS OF OPERATIONS: 24
CRITERIA AIR POLLUTANT EMISSIONS INFORMATION
AIR POLLUTANT EMITTED
ACTUAL EMISSIONS
(AFlERCONTROL6/LIMITS)
POTENTIAL
EMSSIONS
EMISSION FACTOR
Ib/mmBtu
(BEFORE CONTROLS/LIMITS)
(AFlERCONTROL6/LIMITS)
Ib/hr
tons/ r
Ib/hr
tons/ r
Ib/hr
tons! r
Nn oontrolled
contrded
PARTICULATE MATTER Total
1.04
1.98
1.04
4.55
1.04
4.55
0.007
0.007
PARTICULATE MATTER Condensable
0.78
1.48
0.78
3.41
0.78
3.41
0.006
0.006
PARTICULATE MATTER Filterable
0.26
0.49
0.26
1.14
0.26
1.14
0.002
0.002
SULFUR DIOXIDE S02
0.08
0.16
0.08
0.36
0.08
0.36
0.001
0.001
NITROGEN OXIDES NOx
25.97
49.43
25.97
113.73
25.97
113.73
0.186
0.186
CARBONMONOXIDECO
11.48
21.85
11.48
50.28
11.48
50.28
0.082
0.082
VOLATILE ORGANIC COMPOUNDS OC
0.75
1.43
0.75
3.29
0.75
3.29
0.005
0.005
TOXIC/HAZARDOUS
AIR POLLUTANT EMISSIONS INFORMATION
TOXIC / HAZARDOUS AIR POLLUTANT
ACTUAL EMISSIONS
POTENTIAL
EMSSIONS
EMISSION FACTOR
(AFTERCONTROLS/LIMITS)
(BEFORE CONTROL6/LINITS)
(AFlER CIXTTROL6IL)M)TS7
fbimmBN
Ib/hr
Ibs/yr
Ib/hr
Ibs/ r
Ib/hr
Ibslyr
conirolletl
un0.00E+00
wntro!led
Acetaldehyde TH
0.00E+00
0.00E+00
O.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
Acrolein TH
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
O.00E+OO
0.00E+00
Ammonia T
j766441
4.37E-01
1.67E+03
4.37E-01
3.83E+03
4.37E-01
3.83E+03
3.14E-03
3.14E-03
Arsenic unlisted com ounds TH
2.73E-05
1.04E-01
2.73E-05
2.39E-01
2.73E-05
2.39E-01
1.96E-07
1.96E-07
Benzene TH
2.87E-04
1.09E+00
2.87E-04
2.51E+00
2.87E-04
2.51E+00
2.06E-06
2.06E-06
Benzo a rene TH
1.64E-07
6.24E-04
1.64E-07
1.44E-03
1.64E-07
1.44E-03
1.18E-09
1.18E-09
Be Ilium metal unreacted TH
1.64E-06
6.24E-03
1.64E-06
1.44E-02
1.64E-06
1.44E-02
1.18E-08
1.18E-08
Cadmium metal elemental unreacted TH
7440439
1.50E-04
5.72E-01
1.50E-04
1.32E+00
1.50E-04
1.32E+00
I 1.08E-06
LOSE -Os
Chromic acid I TH
7738945
1.91E-04
7.28E-01
1.91E-04
1.68E+00
1.91E-04
1.68E+00
1.37E-06
1.37E-06
Cobalt unlisted com ounds H
COC-other
1.15E-05
4.37E-02
1.15E-05
1.01E-01
1.15E-05
1.01E-01
8.24E-08
8.24E-08
Formaldehyde TH
50000
1.03E-02
3.90E+01
1.03E-02
8.98E+01
1.03E-02
8.98E+01
7.35E-05
735E-05
Hexane, n- TH
110543
2.46E-01
9.37E+02
2.46E-01
2.15E+03
2.46E-01
2.15E+03
1.76E-03
1.76E-03
Lead unlisted compounds H
PBC-other
6.83E-05
2.60E-01
6.83E-05
5.99E-01
6.83E-05
5.99E-01
4.90E-07
4.90E-07
Manganese unlisted com ounds TH
MNC-other
5.19E-05
1.98E-01
5.19E-05
4.55E-01
5.19E-05
4.55E-01
3.73E-07
3.73E-07
Mercury vapor TH
7439976
3.55E-05
1.35E-01
3.55E-05
3.11E-01
3.55E-05
3.11E-01
2.55E-07
2.55E-07
Na thalene H
91203
8.34E- 55
3.17E-01
8.34E-05
7.30E-01
8.34E-05
7.30E-01
5.95E-07
5.98E-07
Nickel metal TH
7440020
2.87E-04
1.09E+00
2.87E-04
2.51E+00
2.87E-04
2.51E+00
2.06E-0s
2.06E-06
Selenium com ounds H
SEC
3.28E-06
1.25E-02
3.28E-06
2.87E-02
3.28E-06
2.87E-02
2.35E-08
2.35E-08
Toluene TH
1"I",.
4.65E-04
I 1.77E+00
I 4.65E-04
I 4.07E+00
4.65E-04
I 4.07E+00
I 3433E-061
3.33E-06
Total HAPs
2.58E-01
9.82E+02 I 2.58E-01 I 2.26E+03
2.58E-01
I 2.26E+03 t.85E-03 1.85E-03
Highest HAP Hexane
TOXIC AIR POLLUTANT
2.46E-01
9.37E+02 2.46E-01 2.15E+03
2.46E-01
2.15E+03 1.76E-03 1.76E-03
EMISSIONS INFORMATION
FOR PERMITTING PURPOSES
EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS
EMISSION FACTOR
IblmmBiu
TOXIC AIR POLLUTANT
CAS Num.n4.37E-rO
Ib/da
Ib/ r
unconvored
ccntroued
Acetaldehyde TH
7507000
0.00E+00
0.00E+00
0.00E+00
O.o0E+00
Acrolein TH
10702800
0.00E+00
0.00E+00
O.00E+OO
0.00E+00
Ammonia T
76644171
1.05E+01
1.67E+03
3.14E-03
Arsenic unlisted com ounds TH
ASC-other5
6.56E-04
1.04E-Ot
tssE-07
Benzene TH
7143204
6.89E-03
1.09E+00
2.06E-06
6Benzo
a rene TH
5032807
3.94E-06
6.24E-04
1.18E-0s
9Be
Ilium metal unreacted TH
74404176
3.94E-05
6.24E-03
1.18E-08
BCadmium
J7.35E-CM5
metal elemental unreacted TH
7440439.04
3.61E-03
5.72E-61
1.08E-06
6
Soluble chromate compounds, as chromium equivalent
S0CR6
1.91E-04
4.59E-03
7.28E-01
1.37E-06
Formaldehyde TH
50000
1.03E-02
2.46E-01
3.90E+01
7.35E-05
sHexane,
n- TH
110543
2.46E-01
5.90E+00
9.37E+02
1.76E-03
3
Manganese unlisted compounds TH
MNC-other
5.19E-05
1.25E-03
1.98E-01
3.73E-07
3.73E-07
Mercury vapor TH
7439976
3.55E-05
6.53E-04
1.35E-01
2.55E-07
2.55E-07
Nickel metal TH
7440020
2.87E-04
6.89E-03
1.09E+00
2.06E-06
2.05E-0s
Toluene (TH)
108883
4.65E-04
1.12E-02
1.77E+00
3.33E-06
3.33E-06
GREENHOUSE GAS EMISSIONS INFORMATION (FOR EMISSIONS INVENTORY PURPOSES) -CONSISTENT WITH EPA MANDATORY REPORTING RULE
(MRR) METHOD
GHG - PO
NOT BASED O
GREENHOUSE GAS POLLUTANT
ACTUAL EMISSIONS
POTENT
EPA MRR CALCULATION METHOD: TIER 1
metric tons/yr
metric tons/yr, CO2e
short tons/yr
short tons/yr
CARBON DIOXIDE (CO2)
28360.70
28,360.70
31,262.29
71,369.12
METHANE (CH4)
5.35E-01
1.34E+01
5.90E-01
1.35E+00
NITROUS OXIDE (NzO)
5.35E-02
1.59E+01
5.90E-02
1.35E-01
28,390.01
(metric tons)
NOTE: CO2e means CO2 equivalent
NOTE: The DAQ Air Emissions Reporting Online (AERO) system requires short tons be reported. The EPA MRR requires metric tons be reported.
NOTE: Do not use greenhouse gas emission estimates from this spreadsheet for PSD (Prevention of Significant Deterioration) purposes.
J
rENTIA4 TO EMIT
N EPA MRR METHOD
IAL EMISSIONS
71369.12
3.37E+01
4.01 E+01
TOTAL CO2e 1 71,442.89
DEQ-CFW 00069304

PS -A Fuel Oil
•
•
FUEL OIL COMBUSTION EMISSIONS CALCULATOR REVISION G 11/5/2012 - OUTPUT SCREEN
Instructions: Enter emission source / facility data on the "INPUT" tab/screen. The air emission results and summary of input data
are viewed I printed on the "OUTPUT" tablscreen. The different tabs are on the bottom of this screen.
This spreadsheet is for your use only and should be used with caution. DENR does not guarantee the accuracy of the information contained. This spreadsheet is
subject to continual revision and updating. It is your responsibility to be aware of the most current information available. DENR is not responsible for errors or
NCDENRomissions
that may be contained herein.
SOURCE/FACILITY/ USER INPUT SUMMARY
FROM OVPUr S(:RtL-M
MAX HEAT INPUT: 139.40 MMBTU/HR
COMPANY: Chemours Company - Fayetteville Works
FACILITY ID NO.: 0900009
FUEL HEAT VALUE: 140,000 BTU/GAL
PERMIT NUMBER: 037351-42
HHV for GHG CALCULATIONS: 0.138 mm BT(J/GAL
FACILITY CITY: Fayetteville
ACTUAL ANNUAL FUEL USAGE: 59 GAL/YR
FACILITY COUNTY: Bladen
MAXIMUM ANNUAL FUEL USAGE: 8,722,457 GAL/YR
USER NAME: Michael E. Johnson
MAXIMUM SULFUR CONTENT: 0.5 IN
EMISSION SOURCE DESCRIPTION: No. 2 oil -fired Boiler
REQUESTED PERMIT LIMITATIONS
EMISSION SOURCE ID NO.: PS -A
MAX. FUEL USAGE: 8,722,457 GAL/YR
MAX. SULFUR CONTENT:
0.5 %
TYPE OF CONTROL DEVICES
POLLUTANT
CONTROL EFF-
NONE/OTHER
PM
0
NONE/OTHER
S02
0
NONE/OTHER
NOx
0
METHOD USED TO COMPUTE ACTUAL GHG EMISSIONS: TIER 1: DEFAULT HIGH HEAT VALUE AND DEFAULT EF
CARBON CONTENT USED FOR GHGS (kg C/gal): CARBON CONTENT NOT USED FOR CALCULATION TIER CHOSEN
CRITERIA AIR POLLUTANT EMISSIONS INFORMATION
ACTUAL EMISSIONS
POTENTIAL EMSSIONS
EMISSION FACTOR
(FFfER CONTROLS LMITE)
(BEFORE CONTROLS I LIMITS) (AFTER CONTROLS/LIMITS)
(I1,/103gal)
Ib/hr
tons/yr
Ib/hr
tons/yr
Ib/hr
tons/ r
uncontrolled
controlled
AIR POLLUTANT EMITTED
TOTAL PARTICULATE MATTER PM FPM+CPM)
3.29
0.00
3.29
14.39
3.29
14.39
3.30E+00
3.30E+00
FILTERABLE PM FPM
1.99
0.00
1.99
8.72
1.99
8.72
2.00E+00
2.00E+00
CONDENSABLE PM(GPM)
1.29
0.00
1.29
5.67
1.29
5.67
1.30E+00
1.30E+00
FILTERABLE PM-10 MICRONS (PM1o)
1.00
0.00
1.00
4.36
1.00
4.36
1.00E+00
1.00E+00
FILTERABLE PM<2.5 MICRONS (PM2.5)
0.25
0.00
0.25
1.09
0.25
1.09
2.50E-01
2.50E-01
SULFUR DIOXIDE (SO2)
70.70
0.00
70.70
309.65
70.70
309.65
7.10E+01
7.10E+01
NITROGEN OXIDES (NO,)
23.90
0.00
23.90
104.67
23.90
104.67
2.40E+01
2.40E+01
CARBON MONOXIDE (CO)
4.98
0.00
4.98
1 21.81
1 4.98
21.81
5.00E+00
5.00E+00
VOLATILE ORGANIC COMPOUNDS (VOC)
0.20
0.00
0.20
0.87
0.20
0.87
2.00E-01
2.00E-01
LEAD
0.00
1 0.00
0.00
0.01
0.00
0.01
1.26E-03
1.26E-03
/ILMWROOUS
WEQE
UT EI�SSIONS;/NFORMA7/ON
.:"'
ACTUAL EMISSIONS
POTENTIAL EMSSIONS
EMISSION FACTOR
CAS
(AFTER CONTROLS I LIMITS)
(BEFORE CONTROLS / LIMITS)
(AFTER CONTROLS / LIMITS))
(1111 0 n.1)
Ib/hr
Ib/yr
Ib/hr
Ib/yr
Ib/hr I
Ib/yr
uncontrolled
Icontrolled
TOXIC / HAZARDOUS AIR POLLUTANT
NUMBER
Antimony Unlisted Compounds (H)
SBC-other
0.0E+00
O.0E+00
0.0E+00
0.0E+00
0.0E+00 I
0.0E+00
0.00E+00
0.00E+00
Arsenic Unlisted Compounds (TH)
ASC-Other
5.6E-04
3.3E-05
5.6E-04
4.9E+00
5.6E-04 I
4.9E+00
5.60E-04
5.60E-04
Benzene (TH)
71432
2.7E-03
1.6E-04
2.7E-03
2.4E+01
2.7E-03
2.4E+01
2.75E-03
2.75E-03
Beryllium Metal (unreacted) (TH)
7440417
4.2E-04
2.5E-05
4.2E-04
3.7E+00
4.2E-04 I
3.7E+00
4.20E-04
4.20E-04
Cadium Metal (elemental unreacted) (TH)
7440439
4.2E-04
2.5E-05
4.2E-04
3.7E+00
4.2E-04 I
3.7E+00
4.20E-04
4.20E-04
Chromic Acid (VI) (TH)
7738945
1 4.2E-04
2.5E-05
4.2E-04
3.7E+00
4.2E-04
I 3.7E+00
4.20E-04
4.20E-04
Cobalt Unlisted Compounds (H)
COC-other
O.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.00E+00
0.00E+00
Ethylbenzene (H)
100414
8.1E-04
4.8E-05
8.1 E-04
7.1E+00
8.1 E-04
7.1 E+00
I 8.17E-04
8.17E-04
Fluorides (sum fluoride compounds) (T)
16984488
3.7E-02
2.2E-03
3.7E-02
3.3E+02
3.7E-02
3.3E+02
3.73E-02
3 73E-02
Formaldehyde (TH)
50000
4.8E-02
2.8E-03
4.8E-02
I 4.2E+02
4.8E-02
4.2E+02
4.80E-02
4.80E-02
Lead Unlisted Compounds (H)
PBC-Other
1.3E-03
7.4E-05
1.3E-03
1.1E+01
1.3E-03
1.1E+01
1.26E-03
1.26E-03
Manganese Unlisted Compounds (TH)
MNC-Other
BAE-04
5.0E-05
8.4E-04
7.3E+00
8.4E-04
7.3E+00
8.40E-04
8.40E-04
Mercury, vapor (TH)
7439976
4.2E-04
2.5E-05
4.2E-04
3.7E+00
4.2E-04
3.7E+00
4.20E-04
4.20E-04
Methyl chloroform IT
71566
2.3E-04
1.4E-05
2.3E-04
2.1E+00
2.3E-04
2.1E+00
2.36E-04
2.36E-04
Napthalene (H)
91203
3.3E-04
2.0E-05
3.3E-04
2.9E+00
3.3E-04
2.9E+00
3.33E-04
3.33E-04
Nickle Metal (TH)
7440020
4.2E-04
2.5E-05
4.2E-04
3.7E+00
4.2E-04
3.7E+00
4.20E-04
4.20E-04
Phosphorus Metal, Yellow or White (H)
7723140
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.00E+00
0.00E+00
POM rates uncontrolled (H)
POM
3.3E-03
1.9E-04
3.3E-03
2.9E+01
3.3E-03
2.9E+01
3.30E-03
3.30E-03
Selenium (H)
SEC
2.1E-03
1.2E-04
2.1E-03
I .8E+01
2.1E-03
1.8E+01
2.10E-03
2.10E-03
compounds
Toluene (TH)
108883
7.9E-02
4.7E-03
7.9E-02
6.9E+02
7.9E-02
I 6.9E+02
7.97E-02
7.97E-02
Xylene (TH)
1330207
1.4E-03
8.3E-05
1.4E-03
I 1.2E+01
1.4E-03
1.2E+01
1.40E-03
1.40E-03
Total HAP (H)
1.4E-01
8.5E-03
1.4E-01
I 1.3E+03
1.4E-01
1.3E+03
1.4E-01
1.4E-01
Largest HAP (H)
7.93E-02
4.70E-03
7.93E-02
6.95E+02
7.93E-02 6.95E+02
7.97E-02
7.97E-02
IITANiiE6ASStONSWFARMATiOK
. R'PERWTTING
PURPOSES
EXPECTED ACTUAL EMISSIONS AFTER CONTROLS I LIMITATIONS
EMISSION FACTOR
(I1,/103 gal)
TOXIC AIR POLLUTANT
CAS Num.
Ib/hr
Ib/day
Ib/yr
uncontrolled
controlled
Arsenic Unlisted Compounds (TH)
ASC-other
5.58E-04
1.34E-02
4.88E+00
5.60E-04
5.60E-04
Benzene (TH)
71432
2.74E-03
6.57E-02
2.40E+01
2.75E-03
2.75E-03
Beryllium Metal (unreacted) (TH)
7440417
4.18E-04
1.00E-02
3.66E+00
4.20E-04
4.20E-04
Cadium Metal (elemental unreacted) (TH)
7440439
4.18E-04
1.00E-02
3.66E+00
4.20E-04
4.20E-04
soluble chromate compounds, as chromium I\ (TH)
SOICR6
4.18E-04
1.00E-02
3.66E+00
4.20E-04
4.20E-04
Fluorides (sum fluoride compounds) IT)
16984488
3.71 E-02
8.91E-01
3.25E+02
3.73E-02
3.73E-02
Formaldehyde (TH)
50000
4.78E-02
1.15E+00
4.19E+02
4.80E-02
4.80E-02
Manganese Unlisted compounds (TH)
MNC-Other
8.36E-04
2.01E-02
7.33E+00
8.40E-04
8.40E-04
Mercury, vapor (TH)
7439976
4.18E-04
1.00E-02
3.66E+00
4.20E-04
4.20E-04
Methyl chloroform ITH)
71566
2.35E-04
5.64E-03
2.06E+00
2.36E-04
2.36E-04
Nickle Metal (TH)
7440020
4.18E-04
1.00E-02
3.66E+00
4.20E-04
4.20E-04
Toluene (TH)
108883
7.93E-02
1.90E+00
6.95E+02
7.97E-02
7.97E-02
Xylene (TH)
1330207
1.39E-03
3.35E-02
1.22E+01
1.40E-03
1.40E-03
GREENHOUSE GAS EMISSIONS INFORMATION (FOR EMISSIONS INVENTORY PURPOSES) -
GHG - POTENTIAL TO EMIT
CONSISTENT WITH EPA MANDATORYREPORT/NG RULE (MRR) METHOD
NOT BASED ON EPA MRR METHOD
POTENTIAL EMISSIONS With
Distillate Fuel Oil No. 2
ACTUAL EMISSIONS
POTENTIAL EMISSIONS - utilize max heat
input capacity and EPA MRR Emission
Requested Emission Limitation -
utilize requested fuel limit and EPA
Factors
MRR Emission Factors
GREENHOUSE GAS
EPA MRR CALCULATION METHOD: TIER 1
POLLUTANT
short tons/yr,
short tons/yr,
metric tons/yr
metric tons/yr, CO2e
short tons/yr
short tons/yr
CO2e
short tons/yr
CO2e
CARBON DIOXIDE (CO2)
0.60
0.60
0.66
99,556.02
99,556.02
99,556.02
99,556.02
METHANE (CH4)
2.44E-05
5.13E-04
2.69E-05
4.04E+00
8.48E+01
4.04E+00
8.48E+01
NITROUS OXIDE (N20)
4.89E-06
1.51 E-03
5.39E-06
8.08E-01
2.50E+02
8.08E-01
2.50E+02
TOTAL
0.60
TOTAL
99, 91.19
TOTAL
99,891.19
NOTES: 1) CO2e means CO2 equivalent
2) The DAQ Air Emissions Reporting Online (AERO) system requires short tons and the EPA MRR requires metric tons
DEQ-CFW 00069305

•
0
Boiler PS -A
Hydrogen Chloride (HCl)
Boiler (PS -A)
HCl Emissions
Page 1 of 1
CAS No. 7647-01-0
The EPA Industrial Boiler MACT rulemaking emission factor for uncontrolled residual
and distillate oil firing is given as 7.1 E-5 lb/MMBtu in Docket Document Number 11-B-8,
Development of Average Emission Factors and Baseline Emission Estimates for the
Industrial, Commercial, and Institutional Boilers and Process Heaters NESHAP, October
2002; so that figure is used as the latest information from EPA.
EPA emission factor = 7.1E-05 pounds of HCI per million BTUs generated in the boiler.
From the memo from Christy Burlew and Roy Oommen, Eastern Research Group to Jim
Eddinger, U.S. EPA, OAQPS, October, 2002, Development of Average Emission Factors
and Baseline Emission Estimates for the Industrial, Commercial, and Institutional Boilers
and Process Heaters National Emission Standard for Hazardous Air Pollutants, Appendix
A, the HCI emission factor for natural gas combustion is 1.24 x 10-5 lb. per MM-BTU.
Emission factor = 1.24E-05 pounds of HCI per million BTUs generated in the boiler.
PS -A emissions of HCI:
59 gallons of No. 2 fuel oil were burned in 2015
59 gal. No. 2 F.O. X
8.26E+00 MM-BTU X
0.140 MM-BTU _
gal. No. 2 F.O.
7.1 E-05 lb HCl _
MM-BTU
520.34 MM-scf of Natural Gas were burned in 2015
520.340 MM-scf Natural Gas X 1,028 BTU
scf Natural Gas
534,910 MM-BTU
Total HCl emissions:
X 1.2E-05 lb HCI _
MM-BTU
8.26E+00 MM-BTU
0.0 lb HCl
534,910 MM-BTU
6.6 lb HCl
0.0 lb HCl from No. 2 F.O.
+ 6.6 lb HCI from Natural Gas
6.6 lb. HCl emissions
DEQ-CFW 00069306

Natural gas/No. 2 fuel oil /No. 6 fuel oil -fired boiler
(88.4 Million BTU Per Hour Maximum Heat Input)
•
0
DEQ-CFW 00069307

PS-B Natural Gas
NATURAL GAS COMBUSTION EMISSIONS CALCULATOR REVISION M 06/22/2015 - OUTPUT SCREEN
Instructions: Enter emission source I facility data on the "INPUT" tablscreen. The air emission results and summary of input data are viewed I
printed on the "OUTPUT" tab/screen. The different tabs are on the bottom of this screen.
_4,
NCDENR
This spreadsheet is for your use only and should be used with caution. DENR does not guarantee the accuracy of the information contained. This
spreadsheet is subject to continual revision and updating. It is your responsibility to be aware of the most current information available. DENR is
not responsible for errors or omissions that may be contained herein.
SOURCE1 FACILITYT.USER INPUT SUR F <S 1't1,Ts
COMPANY: The Chemours Company FC, LLC
FACILITY ID NO.:
PERMIT NUMBER: 03735T42
EMISSION SOURCE DESCRIPTION: 88.4 MMBTU/HR NATURAL GAS -FIRED BOILER
FACILITY CITY: Fayetteville
EMISSION SOURCE ID NO.: PS-B
FACILITY' COUNTY: Bladen
CONTROL DEVICE: I NO CONTROL
POLLUTANT
CONTROL EFF.
SPREADSHEET PREPARED BY: Michael E. Johnson
NOX
CALC'D AS 0%
ACTUAL FUEL THROUGHPUT: 120.16 10 SCF/YR
FU EL HEAT VALUE: 1,020 BTU/SCF
POTENTIAL FUEL THROUGHPUT: 759.20 106 SCF/YR
I BOILER TYPE: SMALL BOILER <100 mmBTU/HR) NO SNCR APPLIED
REQUESTED MAX. FUEL THRPT: 759.20 106 SCFNR
IHOURS OF OPERATIONS: 24
_ CRITERIA
AIR POLLUTANTEMISSIONS
INFURMAT/ONA" ,-a, -
AIR POLLUTANT EMITTED
ACTUAL EMISSIONS
(AFTER CONTROLS/LIMITS)
POTENTIAL
EMISSIONS
EMISSION FACTOR
IbhT.Btu
(BEFORE-TROLS/LIMITS)
(AFTER-TROLS/LIMITS)
Whir
I tons/ r
Ib/hr
tons/ r
Whir
tons/ r
uncontrolled
controlled
PARTICULATE MATTER Total
0.66
0.46
0.66
2.88
0.66
2.88
0.007
0.007
PARTICULATE MATTER Condensable
0.49
0.34
0.49
2.16
0.49
2.16
0.006
0.006
PARTICULATE MATTER Filterable
0.16
0.11
0.16
0.72
0.16
0.72
0.002
0.002
SULFUR DIOXIDE S02
0.05
0.04
0.05
0.23
0.05
0.23
0.001
0.001
NITROGEN OXIDES NOx
8.67
6.01
8.67
37.96
8.67
37.96
0.098
0.098
CARBON MONOXIDE CO
7.28
5.05
7.28
31.89
7.28
31.891
0.082
0,082
VOLATILE ORGANIC COMPOUNDS (VOC)
0.48
0.33
0.48
2.09
0.48
2.091
0.005
0.005
TOXIC/HAZARDOUSA/R POLLUTANT EMISSIONS INFORMATION "' - .";'-• ""•'= - '
TOXIC / HAZARDOUS AIR POLLUTANT
CAS
NUMBER
ACTUAL EMISSIONS
POTENTIAL
EMISSIONS
EMISSION FACTOR
(AFTER CONTROLS/LIMITS)
(BEFORE CMTROLS/LIMITS)
(AFTER CONTROLS/LIMITS)
Ib/InmBiu
Ib/hr
Ibs/yr
Ib/hr
Ibe/yr
Ib/hr
Ibs/yr
uncontrolled
controlled
Acetaldehyde TH
75070
1.32E-06
1.83E-03
1.32E-06
1.15E-02
1.32E-06
1.15E-02
1.49E-08
1.49E08
Acrolein H
107028
1.56E-06
2.16E-03
1.56E-06
1.37E-02
1.56E-06
1.37E-02
1.76E-08
1.76E-08
Ammonia T
7664417
2.77E-01
3.85E+02
2.77E-01
2.43E+03
2.77E-01
2.43E+03
3.14E-03
3.14E-03
Arsenic unlisted compounds TH
ASC-other
1.73E-05
2.40E-02
1.73E-05
1.52E-01
1.73E-05
1.52E-01
1.96E-07
1.96E-07
Benzene TH
71432
1.82E-04
2.52E-01
1.82E-04
1.59E+00 -
1.82E-04
1.59E+00
2.06E-06
2.06E-06
Benzo a rene H
50328
1.04E-07
1.44E-04
1.04E-07
9.11E-04
1.04E-07
9.11E-04
1.18E-09
1.18E-09
Beryllium metal unreacted TH
7440417
1.04E-06
1.44E-03
1.04E-06
9.11E-03
1.04E-06
9.11E-03
1.18E-08
1.18E-08
Cadmium metal elemental unreacted TH
7440439
9.53E-05
1.32E-01
9.53E-05
8.35E-01
9.53E-05
8.35E-01
1.08E-06
1.08E-06
Chromic acid (VI) (TH
7738945
1.21E-04
1.68E-01
1.21E-04
1.06E+00
1.21E-04
1.06E+00
1.37E-06
1.37E-06
Cobalt unlisted compounds H
COC-other
7.28E-06
1.01E-02
7.28E-06
6.38E-02
7.28E-06
6.38E-02
8.24E-08
8.24E-08
Formaldehyde TH
50000
6.50E-03
9.01E+00
6.50E-03
5.69E+01
6.50E-03
5.69E+01
7.35E-05
7.35E-05
Hexane, n- TH
110543
1.56E-01
2.16E+02
1.56E-01
1.37E+03
1.56E-01
1.37E+03
1.76E-03
1.76E-03
Lead unlisted compounds H
PBC-other
4.33E-05
6.01E-02
4.33E-05
3.80E-01
4.33E-05
3.80E-01
4.90E-07
4.90E-07
Manganese unlisted compounds TH
MNC-other
3.29E-05
4.57E-02
3.29E-05
2.88E-01
3.29E-05
2.88E-01
3.73E-07
3.73E-07
Mercury vapor TH
7439976
2.25E-05
3.12E-02
2.25E-05
1.97E-01
2.25E-05
1.97E-01
2.55E-07
2.55E-07
Na thalene H
91203
5.29E-05
7.33E-02
5.29E-05
4.63E-01
5.29E-05
4.63E-01
5.98E-07
5.98E-07
Nickel metal H
7440020
1.82E-04
2.52E-01
1.82E-04
1.59E+00
1.82E-04
1.59E+00
2a6E-06
2.06E-06
Selenium compounds H
SEC
2.08E-06
2.88E-03
2.08E-06
1.82E-02
2.08E-06
1.82E-02
2.35E-08
2.35E-08
Toluene TH
108883
2.95E-04
4.09E-01
2.95E-04
2.58E+00
I 2.95E-04
2.58E+00
I 3.33E-06
3.33E-06
Total HAPs
I 1.64E-01
2.27E+02
1.64E-01 1.43E+03
1 1.64E-01
1.43E+03
1.85E-03
I 1.85E-03
Highest HAP IHexane
TOXIC AIR POLLUTANT.EWSSIONS
I 1.56E-01
2.16E+02
I 1.56E-01 1.37E+03
I 1.56E-01
I 1.37E+03
1.76E-03
I 1.76E-03
INFORMATION
FOR PERMITTING. PURPOSES
EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS
EMISSION FACTOR
W-Btu
TOXIC AIR POLLUTANT
CAS Num.
Whir
lb/day
Ib/ r
uncontrolled
controlled
Acetaldehyde TH
75070
1.32E-06
3.16E-05
1.83E-03
1.49E-08
1.49E-08
Acrolein TH
107028
1.56E-06
3.74E-05
2.16E-03
1.76E-0e
1.76E-0e
Ammonia
7664417
2.77E-01
6.66E+00
3.85E+02
3.14E-03
3.14E-03
Arsenic unlisted compounds TH
ASC-other
1.73E-05
4.16E-04
2.40E-02
1.96E-07
1.96E-07
Benzene TH
71432
1.82E-04
4.37E-03
2.52E-01
2.06E-06
2.06E-06
Benzo a rene H
50328
1.04E-07
2.50E-06
1.44E-04
1.18E-09
1.18E-09
Beryllium metal unreacted TH
7440417
1.04E-06
2.50E-05
1.44E-03
1.18E-08
1.18E-08
Cadmium metal elemental unreacted TH
7440439
9.53E-05
2.29E-03
1.32E-01
1.08E-06
1.08E-06
Soluble chromate compounds, as chromium I equivalent
SoICR6
1.21 E-04
2.91E-03
1.68E-01
1.37E-06
1.37E-06
Formaldehyde TH
50000
6.50E-03
1.56E-01
9.01E+00
7.35E-05
7.35E-05
Hexane, n- TH
110543
1.56E-01
3.74E+00
2.16E+02
1.76E-03
1.76E-03
Manganese unlisted compounds TH
MNC-other
3.29E-05
7.90E-04
4.57E-02
3.73E-07
3.73E-07
Mercury vapor TH
7439976
2.25E-05
5.41E-04
3.12E-02
2.55E-07
2.55E07
Nickel metal H
7440020
1.82E-04
4.37E-03
2.52E-01
2.06E-06
2.06E-06
Toluene(TH)
108883
-2.95E-04
7.07E-03
4.09E-01
3.33E-06
3.33E-06
GREENHOUSE GAS EMISSIONS /NFORMATION (FOR EMISSIGNS INVENTORYPURPOSES) - CONSISTENT WITH EPA MANDATORYREPORTING RULE
(MRR) INETHOD "" - .�
< :: GHG = PO
`NOTBASED 0
GREENHOUSE GAS POLLUTANT
ACTUAL EMISSIONS
POTENT
EPA MRR CALCULATION METHOD: TIER 1
metric tons/yr
metric tons/yr, CO2e
short tons/yr
short ions/yr
CARBON DIOXIDE (CO0
6549.45
6.549.45
7,219.53
45,258.47
METHANE (CH4)
1.24E-01
3.09E+00
1.36E-01
8.54E-01
NITROUS OXIDE (1,120)
1.24E-02
3.68E+00
1.36E-02
8.54E-02
�15
IAL EMISSIONS
(melnc t os) I 6,556.22 I I T(short loos)6 I 45,305.25
NOTE: CO2e means CO2 equivalent
NOTE: The DAQ Air Emissions Reporting Online (AERO) system requires short tons be reported. The EPA MRR requires metric tons be reported.
NOTE: Do not use greenhouse gas emission estimates from this spreadsheet for PSD (Prevention of Significant Deterioration) purposes.
DEQ-CFW 00069308

PS-B Fuel Oil
FUEL OIL COMBUSTION EMISSIONS CALCULATOR REVISION G 11/5/2012 - OUTPUT SCREEN
Instructions: Enter emission source / facility data on the "INPUT" tablsomen. The air emission results and summary of input data
i'V��y.
are viewed / printed on the "OUTPUT' tab/screen. The different tabs are on the bottom of this screen.
This spreadsheet is for your use only and should be used with caution. DENR does not guarantee the accuracy of the Information Contained. This spreadsheet is
��
subject to continual revision and updating. It is your responsibility to be aware of the most current information available. DENR is not responsible for errors or
NCDENRomissions
that may be contained herein.
SOURCE/FACILITY/USER INPUT SUMMARY IfffQg INPUT SCREEN
COMPANY: Chemours Company - Fayetteville Works
MAX HEAT INPUT: 88.40 MMBTU/HR
FACILITY ID NO.: 0900009
FUEL HEAT VALUE: 140,000 BTU/GAL
PERMIT NUMBER: 03735T42
HHV for GHG CALCULATIONS: 0.138 mm BTU/GAL
FACILITY CITY: Fayetteville
ACTUAL ANNUAL FUEL USAGE: 50 GALNR
FACILITY COUNTY: Bladen
MAXIMUM ANNUAL FUEL USAGE: 5,531,314 GALNR
USER NAME: Michael E. Johnson
MAXIMUM SULFUR CONTENT: 0.5
EMISSION SOURCE DESCRIPTION: No. 2 oil -fired Boiler
REQUESTED PERMIT LIMITATIONS
EMISSION SOURCE ID NO.: PS-B
MAX. FUEL USAGE: 5,531,314 GALNR
TYPE OF CONTROL DEVICES
POLLUTANT
CONTROL EFF.
NONE/OTHER
PM
0
NONE/OTHER
S02
0
NONE/OTHER
NOx
0
METHOD USED TO COMPUTE ACTUAL GHG EMISSIONS: TIER 1: DEFAULT HIGH HEAT VALUE AND DEFAULT EF
CARBON CONTENT USED FOR GHGS (kg C/gal): CARBON CONTENT NOT USED FOR CALCULATION TIER CHOSEN
CRITERIA AIR POLLUTANT EMISSIONS
INFORMATION
AIR POLLUTANT EMITTED
ACTUAL EMISSIONS
(AFTER CONTROLS LIMITS)
POTENTIAL EMSSIONS
(BEFORE CONTROLS/LIMITS)
(AFTER CONTROLS I LRAITS)
EMISSION FACTOR
(lb/10'gal)
Ib/hr
tons/yr
Ib/hr
tons/yr
Ib/hr
tons/yr
uncontrolled
controlled
TOTAL PARTICULATE MATTER (PM) FPM+CPM
2.08
0.00
2.08
9.13
2.08
9.13
3.30E+00
3.30E+00
FILTERABLE PM (FPM)
1.26
0.00
1.26
5.53
1.26
5.53
2.00E+00
2.00E+00
CONDENSABLE PM (CPM)
0.82
0.00
0.82
3.60
0.82
3.60
1.30E+00
1.30E+00
FILTERABLE PM<10 MICRONS (PM1o)
0.63
0.00
0.63
2.77
0.63
2.77
1.00E+00
1.00E+00
FILTERABLE PM<2.5 MICRONS (PM2.5)
0.16
0.00
0.16
0.69
0.16
0.69
2.50E-01
2.50E-01
SULFUR DIOXIDE (S02)
44.83
0.00
44.83
196.36
44.83
196.36
7.10E+01
7.10E+01
NITROGEN OXIDES (NO,)
12.63
0.00
12.63
55.31
12.63
55.31
2.00E+01
2.00E+01
CARBON MONOXIDE (CO)
3.16
0.00
3.16
13.83
3.16
13.83
5.00E+00
5.00E+00
VOLATILE ORGANIC COMPOUNDS (VOC)
0.13
0.00
0.13
o.55
0.13
0.65
2.00E-01
2.00E-01
LEAD
0.00
0.00
0.00
0.00
0.00
0.00
1.26E-03
1.26E-03
: ic. ,= . , • : TOJOCI HAZARDOUS
AIR POLLUTANT
EMISSIONS
INFORMATION;_
' W, ?�r V,>$1 *41
�4, '
TOXIC / HAZARDOUS AIR POLLUTANT
CAS
NUMBER
ACTUAL EMISSIONS
(AFTER CONTROLS/LIMITS)
POTENTIAL EMSSIONS
(BEFORE CONTROLS I LUTS)
(AFTER CONTROLS I LIMITS)
EMISSION FACTOR
(I1,/10'gal)
Ib/hr
Ib/yr
Ib/hr
Ib/yr
Ib/hr
Ib/yr
uncontrolled
controlled
Antimony Unlisted Compounds (I)
SBC-other
0.0E+00
0.0E+00
17.0E+00
0.0E+00
0.0E+00
0.0E+00
0.00E+00
0.00E+00
Arsenic Unlisted Compounds (TH)
ASC-other
3.5E-04
2.8E-05
3.5E-04
3.1E+00
3.5E-04
3.1E+00
5.60E-04
5.60E-04
Benzene (TH)
71432
1.7E-03
1.4E-04
1.7E-03
1.5E+01
1.7E-03
1.5E+01
2.75E-03
2.75E-03
Beryllium Metal (unreacted) (TH)
7440417
2.7E-04
2.1 E-05
2.7E-04
2.3E+00
2.7E-04
2.3E+00
4.20E-04
4.20E-04
Cadium Metal (elemental unreacted) (TH)
7440439
2.7E-04
2.1 E-05
2.7E-04
2.3E+00
2.7E-04
2.3E+00
4.20E-04
4.20E-04
Chromic Acid (VI) (TH)
7738945
2.7E-04
2.1E-05
2.7E-04
2.3E+00
2.7E-04
2.3E+00
4.20E-04
4.20E-04
Cobalt Unlisted Compounds (H)
COC-Other
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.00E+00
0.00E+00
Ethylbenzene (H)
100414
5.2E-04
4.1E-05
5.2E-04
4.5E+00
5.2E-04
I 4.5E+00
8.17E-04
8.17E-04
Fluorides (sum fluoride compounds) (T)
16984488
2.4E-02
1.9E-03
2.4E-02
I 2.1E+02
2.4E-02
2.1E+02
3.73E-02
3.73E-02
Formaldehyde (TH)
50000
3.0E-02
2.4E-03
3.0E-02
2.7E+02
3.0E-02
2.7E+02
4.80E-02
4.80E-02
Lead Unlisted Compounds (H)
PBC-other
8.0E-04
6.3E-05
8.0E-04
7.0E+00
8.0E-04
7.0E+00
1.26E-03
1.26E-03
Manganese Unlisted Compounds (TH)
MNC-other
5.3E-04
4.2E-05
5.3E-04
4.6E+00
5.3E-04
4.6E+00
8.40E-04
8.40E-04
Mercury, vapor (TH)
7439976
2.7E-04
2.1E-05
2.7E-04
2.3E+00
2.7E-04
2.3E+00
4.20E-04
4.20E-04
Methyl chloroform (TH)
71566
1.5E-04
1.2E-05
1.5E-04
1.3E+00
1.5E-04
1.3E+00
2.36E-04
2.36E-04
Napthalene (H)
91203
2.1E-04
1.7E-05
2.1E-04
1.8E+00
2.1E-04
1.8E+00
3.33E-04
3.33E-04
Nickle Metal (TH)
7440020
2.7E-04
2.1E-05
2.7E-04
2.3E+00
2.7E-04
2.3E+00
4.20E-04
4.20E-04
Phosphorus Metal, Yellow or White (H)
7723140
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.00E+00
0.00E+00
POM rates uncontrolled (H)
POM
2.1E-03
1.7E-04
2.1E-03
1.8E+01
2.1E-03
1.8E+01
3.30E-03
3.30E-03
Selenium compounds (H)
SEC
1.3E-03
1.1E-04
1.3E-03
L 1.2E+01
1.3E-03
1.2E+01
2.10E-03
2.10E-03
Toluene (TH)
108883
5.0E-02
4.0E-03
5.0E-02
4.4E+02
5.0E-02
4.4E+02
7.97E-02
7.97E-02
Xylene (TH)
1330207
8.8E-04
7.0E-05
8.8E-04
7.7E+00
8.8E-04
7.7E+00
1.40E-03
1.40E-03
Total HAP (H)
9.1E-02
7.2E-03
9.1E-02
7.9E+02
9.1E-02
7.9E+02
1AE-01
1.4E-01
Largest HAP (H)
5.03E-02
3.98E-03
5.03E-02
4.41E+02
5.03E-02
4.41E+02
7.97E-02
7.97E-02
TOXIC AIR POLL
EMISSIONS
INFORMATION
OR PERMITTING
EURFOSES
EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS
EMISSION FACTOR
(lb/10' gal)
TOXIC AIR POLLUTANT
CAS Num,
Ib/hr
lb/day
Ib/yr
uncontrolled
controlled
Arsenic Unlisted Compounds (TH)
ASC-Other
3.54E-04
8.49E-03
3.10E+00
5.60E-04
5.60E-04
Benzene (TH)
71432
1.74E-03
4.17E-02
1.52E+01
2.75E-03
2.75E-03
Beryllium Metal (unreacted) (TH)
7440417
2.65E-04
6.36E-03
2.32E+00
4.20E-04
4.20E-04
Cadium Metal (elemental unreacted) (TH)
7440439
2.65E-04
6.36E-03
2.32E+00
4.20E-04
4.20E-04
Soluble chromate compounds, as chromium I\ (TH)
SolCR6
2.65E-04
6.36E-03
2.32E+00
4.20E-04
4.20E-04
Fluorides (sum fluoride compounds) (T)
16984488
2.36E-02
5.65E-01
2.06E+02 I
3.73E-02
3.73E-02
Formaldehyde (TH)
50000
3.03E-02
7.27E-01
2.66E+02
4.80E-02
4.80E-02
Manganese Unlisted Compounds (TH)
MNC-Other
5.30E-04
1.27E-02
4.65E+00
8.40E-04
8.40E-04
Mercury, vapor (TH)
7439976
2.65E-04
6.36E-03
2.32E+00
4.20E-04
4.20E-04
Methyl chloroform (TH)
71566
1.49E-04
3.58E-03
1.31E+00
2.36E-04
2.36E-04
Nickle Metal (TH)
7440020
2.65E-04
6.36E-03
2.32E+00
4.20E-04
4.20E-04
Toluene (TH)
108883
5.03E-02
1.21E+00
4.41E+02
7.97E-02
7.97E-02
Xylene (TH)
1330207
8.84E-04
2.12E-02
7.75E+00
1.40E-03
1.40E-03
GREENHOUSE GAS EMISSIONS INFORMATION (FOR EMISSIONS INVENTORY PURPOSES) -
CONSISTENT WITH EPA MANDATORY REPORTING RULE (MRR) METHOD
GHG - POTENTIAL TO EMIT
NOT BASED ON EPA MRR METHOD
Distillate Fuel Oil No. 2
ACTUAL EMISSIONS
POTENTIAL EMISSIONS - utilize max heat
input capacity and EPA MRR Emission
Factors
POTENTIAL EMISSIONS With
Requested Emission Limitation -
utilize requested fuel limit and EPA
MRR Emission Factors
GREENHOUSE GAS
EPA MRR CALCULATION METHOD: TIER 1
POLLUTANT
metric tons/yr
metric tons/yr, CO2e
short tons/yr
short tons/yr
short tons/yr,
CO2e
short tons/yr
short tons/yr,
CO2e
CARBON DIOXIDE (CO2)
0.51
0.51
0.56
63,133.09
63,133.09
63,133.09
63,133.09
METHANE (CH4)
2.07E-05
4.35E-04
2.28E-05
2.56E+00
5.38E+01
2.56E+00
5.38E+01
NITROUS OXIDE (1\120)
4.14E-06
1.28E-03
4.56E-06
5.12E-01
1.59E+02
5.12E-01
1.59E+02
TOTAL
0.51
TOTAL
63,346.64
TOTAL
63,345.64
NOTES: 1) CO2e means CO2 equivalent
2) The DAQ Air Emissions Reporting Online (AFRO) system requires short tons and the EPA MRR requires metric tons
DEQ-CFW 00069309

•
•
•
Boiler PS-B
Hydrogen Chloride (HCl)
Boiler (PS-B)
HCI Emissions
Page 1 of 1
CAS No. 7647-01-0
The EPA Industrial Boiler MACT rulemaking emission factor for uncontrolled residual
and distillate oil firing is given as 7.1E-5 lb/MMBtu in Docket Document Number I1-13-8,
Development of Average Emission Factors and Baseline Emission Estimates for the
Industrial, Commercial, and Institutional Boilers and Process Heaters NESHAP, October
2002; so that figure is used as the latest information from EPA.
EPA emission factor = 7.1E-05 pounds of HCI per million BTUs generated in the boiler.
From the memo from Christy Burlew and Roy Oommen, Eastern Research Group to Jim
Eddinger, U.S. EPA, OAQPS, October, 2002, Development of Average Emission Factors
and Baseline Emission Estimates for the Industrial, Commercial, and Institutional Boilers
and Process Heaters National Emission Standard for Hazardous Air Pollutants, Appendix
A, the HCI emission factor for natural gas combustion is 1.24 x 10-5 lb. per MM-BTU.
Emission factor = 1.24E-05 pounds of HCI per million BTUs generated in the boiler.
PS-B emissions of HCI:
50 gallons of No. 2 fuel oil were burned in 2015
50 gal. No. 2 F.O. X
7.00E+00 MM-BTU X
0.140 MM-BTU
gal. No. 2 F.O.
7.1E-05 lb HCI _
MM-BTU
120.16 MM-sef of Natural Gas were burned in 2015
120.160 MM-scf Natural Gas X 1,028 BTU =
scf Natural Gas
123,524 MM-BTU
Total HCl emissions:
X 1.2E-05 lb HCI
MM-BTU
7.00E+00 MM-BTU
0.00 lb HCl
123,524 MM-BTU
1.5 lb HCI
0.0 lb HCI from No. 2 F.O.
+ 1.5 lb HCI from Natural Gas
1.5 lb. HCl emissions
DEQ-CFW 00069310

Semiworks Polymerization Operation
SW-1
•
DEQ-CFW 00069311

9 0 0
Semiworks (SW-1)
Summary
SEMIWORKS SUMMARY
Campaign Starts:
Campaign Ends:
Month
Chemours
CAS Chemical Name
CAS No.
TOTAL
15-SXF-1.0
15-SXF-2.0
15-SXF-3.0
15-SXF-4.0
Compound
TFE
Tetrafluoroethylene
116-14-3
201.6
34.1
62.1
39.7
65.8
PSEPVE
Perfluoro-2-(2-fluorosulfonyl
16090-14-5
483.3
140.7
111.7
98.5
132.4
ethoxy) propyl vinyl ether
E 2
2H-perfluoro(5-methyl-3,6-
3330-14-1
876.5
207.5
239.5
207.6
221.9
dioxanonane)
PAF
Trifluoroacetyl Fluoride
354-34-7
66.8
17.7
15.4
14.7
19.0
Initiator
Perfluoro-2-methyl-3-
56347-79-6
36.5
8.7
10.7
8.6
8.4
oxahexanoyl peroxide
CAMPAIGN TOTAL VOC (lb.)
408.7
439.5
369.0
447.4
TOTAL ANNUAL VOC (Ib.) 1664.7
TOTAL ANNUAL VOC (ton) 0.83
HAP and TAP COMPOUNDS
Chemours
CAS Chemical Name
CAS No.
TOTAL
15-SXF-1.0
15-SXF-2.0
15-SXF-3.0
15-SXF-4.0
Compound
1,1,2-trichloro-1,2,2-
F-113
trifluoroethane
76-13-1
2305.5
524.5
656.5
522.1
602.6
HCI
Hydrogen chloride
7647-01-0
0
0
0
0
0
HF
Hydrogen fluoride
7664-39-3
66.8
17.7
15.4
14.7
19.0

Semiworks (Sw-11
,,-pa gn Information
•
17J
Campaign ID- 15-SXF-1.0
� 1a onn� s
start ware:
ttmcufo
Starting Material
Additions to the system
Addition
Addition
Addition
Addition
Addition (TFE) Addition (E2)
Addition
Addition
(condensate)
Item
(initiator)
(PSEPVEI
1F1'131
(condensate)
(condensate)
FC-8763
FC-8764
Weight (Kg):
116.5
300.36
0
183.8
177.3
253.60
304.20
0.00
Compositions:
%E2
96.60%
0.00%
100.00%
0.00%
0.00%
1673330
15.00%
1673331
15.27%
0.00%
%PSEPVE
0.00%
0.00%
0.00%
100.00%
0.00%
7.97%
5.67%
0.00%
%TFE
0.00%
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
%F113
0.00%
0.00%
0.00%
0.00%
100.00%
75.77%
78.26%
0.00%
%Inititiator
3.40%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
Totals
Weights
E2
112.54
0.00
0.00
0.00
0.00
38.04
46.45
0.00
1�
197.0
PSEPVE
0.00
0.00
0.00
183.80
0.00
20.21
17.25
0.00
221.3
TFE
0.00
300.36
0.00
0.00
0.00
0.00
0.00
0.00
300.4
F113
0.00
0.00
0.00
0.00
177.30
192.15
238.07
0.00
607.5
Inititiator
3.96
0.00
0.00
0.00
0.00
_
0.00
0.00
0.00
4.0
Ending Material
Return
Return
Return
Return
Return
Item
Recovery Tank
(condensate)
(condensate)
(condensate)
)condensate)
(condensate)
"-
FC-8788
FC-8789
Weight (Kg):
0.00
296.00
222.80
Compositions
1680731
1680732
%E2
0.00%
18.88%
21.06%
0.00%
0.00%
0.00%
%PSEPVE
0.00%
7.76%
7.77%
0.00%
0.00%
0.00%
%TFE
0.00%
0.00%
0.00%
0.00°%
0.00%
0.00%
%F113
0.00%
71.85%
70.35%
0.00%
0.00%
0.00%
%Inititiator
O.00%
0.00%
0.00%
0.00%
0.00%
0.00%
Totals
Weights
E2
_
0.00
0.00
0.00
0.00
0.00
55.88
46.92
0.00
0.00
0.00
lkM
102.8
PSEPVE
0.00
0.00
0.00
0.00
0.00
22.97
17.31
0.00
0.00
0.00
40.3
TFE
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.0
F113
0.00
0.00
0.00
0.00
0.00
212.68
156.74
0.00
0.00
0.00
369.4
Inititiator
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.0
Production
Item
POIVmer
Throw Away
Slurry
Weight (Kg):
402.00
0.00
0.00
Compositions
EW
1531
0
%Polymer
100.00%
100.00%
0.00%
%E2
0.00%
%PSEPVE
0.00%
%TFE
0.00%
Totals
%F113
0.00%
Weights
Lk91
402.0
Polymer
402.00
0.00
0.00
0.0
E2
0.00
0.00
0.00
PSEPVE
117.11
0.00
0.00
84.9
284.
TFE
284.89
0.00
0.00
0.0
F113
0.00
0.00
0.00
VE in Polymer
1 117.11
0.00
0.00
Totals
Material Balance Summary
Compound
Added
Remaining
Used
Production
Other
M
94.2
E2
197.0
102.8
94.2
0.0
63.9
PSEPVE
221.3
40.3
181.0
117.1
15.5
TFE
300.4
0.0
300.4
284.9
238.1
F113
607.5
369.4
238.1
0.0
4.0
Inititiator
4.0
0.0
4.0
0.0
VE Yield
Vinyl Ether =
PSEPVE
MW = 446
VE in polymerl
117.1
%in polymer= 64.7%
VE used
Air Emissions (lb.)
SW-1
Sw-2
TFE
34.1 lb.
# of MF samples
0.0 All run in mfg lab
PSEPVE
140.7 lb.
grams emissions
0.0 g
E-2
207.5 lb.
Ibs of emissions
0.0 lb
PAF
17.7 lb.
Inititiator
8.7 lb.
F-113
524.5 lb.
DEQ-CFW 00069313

SemP;:orks
Campaign Information
•
•
•
Campaign ID: 15-SXF-2.0
Pnd nat.- : MA12015
acan uaie:
Starting Material
orr nco ra
Additions to the system
Addition
Addition
Addition
Addition
Addition
Addition
Item
)initiator)
Addition (TFE)
Addition (E2)
(PSEPVE)
(F113)
(condensate)
(condensate)
(condensate)
Weight (Kg):
130
277.3
0
159.2
300.1
FC-8788
296.20
FC-8789
222.80
0.00
Compositions:
1680731
1680732
%E2
96.25%
0,00%
100.00%
0.00%
0.00%
18,88%
21.06%
0.00%
%PSEPVE
0.00%
0.00%
0.00%
100.00%
0,00%
7.76%
7.77%
0.00%
%TFE
0.00%
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
%F113
0.00%
0.00%
0.00%
0.00°%
100.00%
71.85%
70.35%
0,00%
Totals
%Inititiator
3.75%
0.00%
0.00%
0.00%
0.00%
0.00%
0,00%
0,00%
tkg)
Weights
E2
125.13
0.00
0.00
0.00
0.00
55.92
46.92
0.00
228.0
PSEPVE
0.00
0.00
0.00
159.20
0.00
22.99
17.31
0.00
199.5
TFE
0.00
277.30
0.00
0.00
0.00
0.00
0,00
0.00
277.3
F113
0.00
0.00
0.00
0.00
300.10
212.82
156.74
0.00
669.7
Inititiator
4.88
0.00
0.00
0.00
0.00
0.00
0.00
0.00
4.9
Ending Material
Return
Return
Return
Return
Return
Item
Recovery Tank
(condensate)
(condensate)
(condensate)
(condensate)
(condensate)
FC-8801
FC-8802
Weight (Kg):
0.00
300.00
244.00
Compositions
1705016
20.70%
1705017
23.42%
0.00%
0.00%
0.00%
%E2
%PSEPVE
0.00%
0.00%
SAO%
8.06%
0.00%
0.00%
0.00%
%TFE
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
%F113
0,00%
68.69%
67.85%
0.00%
0.00%
0.00%
%Inititiator
0.00%
0.00%
0.00%
0.00%
0.00%
0,00%
Totals
Weights
E2
0.00
0.00
0.00
0.00
0.00
62.10
57.14
0.00
0.00
0.00
L9
119.2
PSEPVE
0.00
0.00
0.00
0.00
0.00
28.20
19.67
0.00
0.00
0.00
47.9
TFE
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.0
LF113
0.00
0.00
0.00
0.00
0.00
206.07
165.55
0.00
0.00
0.00
371.E
In
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.0
Production
Item
Polymer
Throw Away
Slurry
Weight (Kg):
350.00
0.00
0.00
Compositions
EW
1547
0
%Polymer
100.00%
100.00%
0.00%
%E2
0.00%
%PSEPVE
0.00%
%TFE
0.00%
Totals
%F113
0.00%
Weights
350.
Polymer
350.00
0.00
0.00
0.0
E2
0.00
0.00
0.00
0.
PSEPVE
100.90
0.00
0.00
2491
TFE
249.10
0.00
0.00
0.0
0.0
F113
0.00
0.00
0.00
VE in Polymer
100.90
0.00
0.00
Material Balance Summary
Totals
Compound
Added
Remaining
Used
Production
Other
108.7
7
E2
228.0
119.2
108.7
0.0
50.7
PSEPVE
199.5
47.9
151.6
100.9
28.2
TFE
277.3
0.0
277.3
249.1
298.0
F113
669.7
371.6
298.0
0.0
4.9
Inititiator
4.9
0.0
4.9
0.0
VE Yield
Vinyl Ether=
PSEPVE
MW = 446
VE in polymer
100.5
% in polymer = 66.5%
VE used
151.6
Air Emissions
SW-1
SW 2
TFE
62.1 Ib.
# of MF samples
0.0 All run in mfg lab
PSEPVE
111.7 Ib.
grams emissions
0.0 g
E-2
239.5 Ib.
Ibs of emissions
0.0 lb
PAF
15.4 Ib.
Inititiator
10.7 lb.
F-113
656.5 Ib.
DEQ-CFW 00069314

Semivrorks (SW-1)
Camr algn Information
C7
•
•
Campaign ID: 15-SXF-3.0
slay[ ua[e:
ari-vau w
Starting Material
Additions to the system
Addition
Addition
Addition
Item
Addition
Addition (TFE)
Addition (E2)
Addition
Addition
(condensate)
(condensate)
(condensate)
(initiator)
(PSEPVE)
(F113)
FC-8801
FC-8802
Weight (Kg):
105.8
251
0
140.2
213.9
300.00
244.00
0.00
Compositions:
%E2
96,30%
0.00%
100.00%
0.00%
0.00%
1705016
20.70%
1705017
23.42%
0.00%
%PSEPVE
0.00%
0.00%
0.00%
100.00%
0.00%
9.40%
8.06%
0.00%
%TFE
0.00%
100.00%
0.00%
0.00%
0.00%
0,00%
0.0 %
0.00%
%F113
0.00%
0.00%
0.00%
0.00%
100.00%
68.69%
67,85%
0.00%
%Inititiator
3.70%
0,00%
0.00%
0.00%
0.00%
0,00%
0.00%
0.00%
Totals
Weights
E2
101.89
0.00
0.00
0.00
0.00
62.10
57A4
0.00
1KM
221.1
PSEPVE
0.00
0.00
0.00
140.20
0.00
28.20
19.67
0.00
188.1
TFE
0,00
251.00
0.00
0.00
0.00
0.00
0.00
0.00
251.0
F113
0.00
0.00
0.00
0,00
213.90
206.07
165.55
0.00
585.5
Inititiator
3.91
0.00
0.00
0.00
0.00
0.00
0.00
0.00
3.9
Ending Material
Return
Return
Return
Return
Return
Item
Recovery Tank
(condensate)
(condensate)
(condensate)
(condensate)
(condensate)
FC-8813
FC-8814
Weight (Kg):
0.00
300.00
223.00
Compositions
1723215
23.70%
1723216
25.02%
0.00%
0.00%
0.00%
%E2
%PSEPVE
0.00%
0.00%
9.14%
7.14%
0.00%
0.00%
0.00%
%TFE
0.00%
0.00%
0.00%
0,00%
0.00%
0.00%
%F113
0.00%
66.13%
67.31%
0.00%
0.00%
0.00%
%Inititiator
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
Totals
Weights
E2
0.00
0.00
0.00
0.00
0.00
71.10
55.79
0.00
0.00
0.00
126.9
PSEPVE
0.00
0.00
0.00
0.00
0.00
27.42
15.92
0.00
0.00
0.00
43.3
TFE
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
MID
0.00
0.0
F113
0,00
0.00
0.00
0.00
0.00
198.39
150.10
0.00
0.00
0.00
348.5
Inititiator
1 0,00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.0
Production
Item
Polymer
Throw Away
Slurry
Weight (Kg):
333.00
0.00
0.00
Compositions
EW
1485
0
%Polymer
100.00%
100.00%
0,00%
%E2
0.00%
%PSEPVE
0.00%
%TFE
0.00%
Totals
F113
0.00%
Weights
333.0
Polymer
333.00
0.00
0.00
0.0
E2
0.00
0.00
0.00
100.0
PSEPVE
100,01
0.00
0.00
233.0
TFE
232,99
0.00
0.00
0.0
F113
0.00
0.00
0.00
VE I" Polymer
100.01
0.00
0.00
Totals
Material Balance Summary
Compound
Added
Remaining
Used
Production
Other
ik91
94.2
E2
221.1
126.9
94.2
0.0
�'7
PSEPVE
188.1
43.3
144.7
100.0
18.0
TFE
251.0
0.0
251.0
233.0
237.0
F113
585.5
348.5
237.0
0.0
3.9
Inititiator
3.9
0.0
3.9
0.0
VE Yield
Vinyl Ether=
PSEPVE
MW =
446
VE in polymer
100.0
% in polymer =
69.1
VE used
144.7
Lbs of Emissions
Sw-1
SW-2
TFE
39.7 lb.
# of MF samples
0.0 All run in mfg lab
PSEPVE
98.5 lb.
grams emissions
0.0 g
E-2
207.6 lb.
Ibs of emissions
0.0 lb
PAF
14.7 Ib.
Inititiator
8.6 Ib...
F 113
5221 lb
DEQ-CFW 00069315

Semiworks (SW-i)
Campaign Information
�J
•
Campaign ID: 15-SXF-4.0
-d rm- 42/1ennts
-an uare:
Starting Material
Additions to the system
-
Addition
Addition
Addition
Addition
Addition
Addition (E2)
Addition
Addition
Item
(initiator)
(TFE)
(PSEPVE)
(F113)
(condensate)
(condensate)
(condensate)
FC-8813
FC-8814
Weight (Kg):
105.6
332.28
0
187.3
331.8
300.00
223.00
0.00
Compositions:
%E2
96.40%
0.00%
100.00%
0.00%
0.00%
1723215
23.70%
1723216
25.02%
0.00%
%PSEPVE
0.00%
0.00%
0.00%
100.00%
0.00%
9.14%
7.14%
0.00%
%TFE
0.00%
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
%F113
0.00%
0.00%
0.00%
0.00%
100.00%
66.13%
37.31%
0.00%
%Inititiator
3.60%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
Totals
Weights
E2
_
101.80
0.00
0.00
0.00
0.00
71.10
55.79
0.00
(kM
228.7
PSEPVE
0.00
0.00
0.00
187.30
0.00
27.42
15.92
0.00
230.6
TFE
0.00
332.28
0.00
0.00
0.00
0.00
0.00
0.00
332.3
IF
0.00
0.00
0.00
0.00
331.80
198.39
83.20
0.00
613.4
Inititiator
3.80
0.00
0.00
0.00
0.00
0.00
0.00
0.00
3.8
Ending Material
Return
Return
Return
Return
Return
Item
Recovery Tank
(condensate)
(condensate)
(condensate)
(condensate)
(condensatel
FC-8837
FC-8838
Weight (Kg):
0.00
302.00
212.00
Compositions
1799538
1799539
%E2
0.00%
21.92%
29.13%
0.00%
0.00%
0.00%
%PSEPVE
0.00%
7.48%
9.13%
0.00%
0.00%
0.00%
%TFE
0.00%
0.00 %
0.00%
0.00%
0.00%
0.00%
%F113
0.00%
69.70 %
61.02 %
0.00 %
0.00%
0.00%
Inititiator
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
Totals
Weights
E2
0.00
0.00
0.00
0.00
0.00
66.20
61.76
0.00
(3.00
0.00
(k9)
128.0
PSEPVE
0.00
0.00
0.00
0.00
0.00
22.59
19.36
0.00
0.00
0.00
41.9
TFE
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.0
F113
0.00
0.00
0.00
0.00
0.00
210.49
129.36
0.00
0.00
0.00
339.9
Inititiator
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.0
Production
Item
Polymer
Throw Awav
Slurry
Weight (Kg):
431.00
0.00
0.00
Compositions
EW
1495
0
%Polymer
100.00%
100.00%
0.00%
%E2
0.00%
%PSEPVE
0.00%
%TFE
0.00%
Totals
%F113
0.00%
Weights
431.0
Polymer
431.00
0.00
0.00
0.0
E2
0.00
0.00
0.00
128.6
PSEPVE
128.58
0.00
0.00
302.4
TFE
302.42
0.00
0.00
0.0
F113
0.00
0.00
0.00
VE in Polymer
128.58
0.00
0.00
Material Balance Summary
Totals
Compound
Added
Remaining
Used
Production
Other
1kg)
100.7
E2
228.7
128.0
100.7
0.0
60.1
PSEPVE
230.6
41.9
188.7
128.6
29.9
TFE
332.3
0.0
332.3
302.4
273.5
F113
613.4
339.9
273.5
0.0
3.8
3.8
Inititiator
3.8
0.0
3.8
0.0
VE Yield
Vinyl Ether =
PSEPVE
MW =
446
VE in polymer
128.6
%in polymer=
68.1%
VE used
188.7
Air Emissions (lb.)
SW-1
SW 2
TFE
65.8 lb.
# of MF samples 0.0 All run in Mfg lab
PSEPVE
132.4 lb.
grams emissions 0.0 g
E-2
221.9 lb.
We of emissions 0.0 lb
PAF
19.0 lb.
Inititiator
8.4 Ib.
F-113
602.51b.
DEQ-CFW 00069316

•
Extended Aeration Biological Wastewater Treatment Facility
WTS-A
11
•
DEQ-CFW 00069317

Wastewater Treatment Plant (WTS-A)
Source Description
Page 1 of 2
2015 Air Emissions Inventory Supporting Documentation
Emission Source ID No.: WTS-A
Emission Source Description: Central Wastewater Treatment Plant
Process and Emission Description:
The Wastewater Treatment Plant (WWTP) consists of the biological treatment of process
and sanitary wastewater utilizing extended aeration. The WWTP is comprised of an open
equalization basin and open -top tanks and clarifiers. The basin is mixed using floating
mixers and the tanks are aerated primarily with diffused air.
Emissions from the WWTP result from the volatilization of solubilized compounds which
are air stripped via the aeration of the wastewater. The extent of the volatilization is a
function of the specific compound's solubility in water and its vapor pressure, typically
expressed as the compound's Henry's Law Constant. Also, the volatilization of an organic
compound is dependent on its rate of biodegradability. For example, methanol which is a
Hazardous Air Pollutant (HAP), is highly biodegradable, and as such its biodegradation
rate is much faster than its volatilazation rate, thereby limiting the air emissions of
Basis and Assumptions:
The three major compounds that are treated in the WWTP are butyraldehyde, ethylene
glycol, and methanol.
The emissions of methanol from the WWTP were determined using the EPA WATER8
model. This modeling takes into account the specific operational units of the WWTP to
predict the ultimate fate of specific compounds.
The Henry's Law Constant for ethylene glycol is 6.0 x 10e-08 atm-m3/mole. Not
surprisingly, ethylene glycol is exempt from the wastewater control requirements of 40
CFR 63 Subpart G as ethylene glycol is excluded from Table 9 of that subpart.
Because of the above, it will be assumed that the WWTP unit operation's emission factors
for ethylene glycol are the same as those for dimethylformamide. However, the
biodegradation rate of ethylene glycol will be assumed to be the same as that of methanol,
since the technical literature found in the Handbook of Environmental Data on Organic
Chemicals indicates that for an acclimated system, ethylene glycol is biodegraded at twice
the rate of methanol. To be conservative, the slower methanol rate will be used.
DEQ-CFW 00069318

•
Wastewater Treatment Plant (WTS-A)
Source Description �
Page 2 of 2
The Henry's Law Constant for butyraldehyde is 1.15 x 10e-04 atm-m3/mole which is
higher than the Henry's Law Constant for methanol of 4.55 x 10e-06 atm-m3/mole,
meaning the quantity that is air stripped from the wastewater would be expected to be
higher than that for methanol. According to the Handbook of Environmental Data on
Organic Chemicals, butyraldehyde is biodegraded at the same rate of methanol in an
acclimated system.
Because of the above, it will be assumed that the WWTP unit operation's emission factors
for butyraldehyde are twice as those for methanol.
The WWTP is fed 30% aqueous ammonia as a nutrient for the biological microbes.
Typically the WWTP consumes 69,000 lb/yr of this solution, which equates to 20,010 lb/yr
of 100% ammonia. To be conservative, the emissions of ammonia from the WWTP will
assume that none of the NH3 is utilized by the microbes, who would convert the ammonia
into nonvolatile nitrate. The emissions of ammonia is determined using Henry's Law.
Information Inputs and Source of Inputs:
Information Inputs
Source of Inputs
Estimated quantity of compounds entering
the WWTP for the year
SARA 313 Report and other Air Emission
Inventory inputs
Fugitive Emissions Determination:
All air emissions from the Wastewater Treatment Plant are fugitive. Estimates of the
emission for individual components are given in the following pages.
DEQ-CFW 00069319

Wastewater Treatment Plant (WTS-A)
Emissions Summary
Page 1 of 1
2015 Air Emissions Summary
WTS-A Central Wastewater Treatment Plant
A. VOC Compound Summary
Chemours
Compound
CAS Chemical Name
CAS No.
Emission
(lb.)
BA
Butyraldehyde
123-72-8
139,869
EtGly
Ethylene Glycol
107-21-1
14
McOH
Methanol
67-56-1
33,974
Total VOC Emissions (lb.)
173,857
Total VOC Emissions (tons)
86.93
B. Hazardous / Toxic Air Pollutant Summary
Chemours
Compound
CAS Chemical Name
CAS No.
Emission
(lb.)
EtGly
Ethylene Glycol
107-21-1
14
McOH
Methanol
67-56-1
33,974
NH3
Ammonia
7664-41-7
801
•
DEQ-CFW 00069320

•
•
•
Wastewater Treatment Plant (WTS-A)
VOC Emissions
Page 1 of 1
2015 Emissions from Wastewater Treatment Plant (WTS-A)
BA
EtGly
McOH
To WWTP from Kuraray Butacite (lb)
467,969
3,515
190,442
To WWTP from Chemours IXM Resins (lb)
-
-
29,573
Total to Chemours WWTP (lb)
467,969
3,515
220,015
Quantity entering EQB (lb)
467,969
3,515
220,015
Percent of compound volatilized
23.42%
0.29%
11.71 %
Quantity volatilized from EQB (lb)
109,598
10
25,764
Quantity leaving EQB (lb)
358,371
3,505
194,251
Quantity entering Predigester (lb)
358,371
3,505
194,251
Percent of compound volatilized
8.30%
0.10%
4.15%
Quantity volatilized from Predigester (lb)
29,745
4
8,061
Quantity leaving Predigester (lb)
328,626
3,501
186,190
Quantity entering Aeration Tank (lb)
328,626
3,501
186,190
Percent of compound volatilized
0.16%
0.002%
0.08%
Quantity volatilized from Aeration Tank (lb)
526
0
149
Percent of compound biodegraded
85.00%
85.00%
85.00%
Quantity biodegraded in Aeration Tank (lb)
279,332
2,976
158,261
Quantity leaving to Cape Fear River (lb)
48,768
525
27,780
Kuraray Quantity to Cape Fear River (lb)
48,768
525
24,046
Chemours Quantity to Cape Fear River (lb)
-
-
3,734
Total Quantity to Cape Fear River (Ib)
48,768
525
27,780
Butacite Fraction Volatilized to Air (lb)
139,869
14
29,408
Nafion Fraction Volatilized to Air (lb)
-
-
4,567
Total Volatilized to Air (lb)
139,869
14
33,974
Source of Reduction Factors: EPA WATER8 computer model
BA = Butyraldehyde
EtGly = Ethylene Glycol
McOH = Methanol
See Note 1
Note 1: Based on best professional judgement of Ken W. Cook, PE (DuET Wastewater Consultant)
the "Percent of compound biodegraded" was reduced from 94+% to 85% for the reports beginning
calendar year 2012. It is believed that an acclimated biological system would be able to biodegrade
85% of these simple organic compounds during the 18-hour residence period.
DEQ-CFW 00069321

Wastewater Treatment Plant (WTS-A)
Ammonia (NH3) Emissions
Page 1 of 3
•
2015 Air Emissions Inventory Supporting Documentation
Emission Source ID No.: WTS-A
Emission Source Description: Central Wastewater Treatment Plant
Ammonia (NH3) Emissions
The wastewater treatment plant ("WWTP") is fed aqueous ammonia (30% NH3) as a
nutrient for the biological microbes.
In 2015, the WWTP consumed 69,706 pounds of 30% aqueous ammonia, which equates to
20,912 pounds of 100% ammonia (100% NH3).
The aqueous ammonia is fed directly into the WWTP Aeration Tank that is aerated via
2,000 cubic feet per minute of diffused air injected into the bottom of the tank.
The aqueous ammonia is fed directly into the WWTP Aeration Tank that is aerated via
2,000 cubic feet per minute of diffused air injected into the bottom of the tank. To be
conservative, the emissions of ammonia from the WWTP will assume that none of the
NH3 is utilized by the microbes, who would convert the ammonia into nonvolatile nitrate.
The WWTP influent averages approximately one (1) million gallons of water per day,
which is equal to 3,044,100,000 lb. of water per year.
Concentration of NH3 in the Aeration Tank
20,912 lb. NH3
year
year
x
3,044,100,000 lb. water
0.00000687 lb. NH3
lb. water
•
453.6 g NH3
x lb. NH3
0.00000687 lb. NH3
lb. water
2,204.6 lb. water
x
m water
6.87 g NH3
m water
DEQ-CFW 00069322

C
•
•
Wastewater Treatment Plant (WTS-A)
Ammonia (NH3) Emissions
Page 2of3
Henry's Law Constant for Ammonia in water at 30 deg C ( see Note 1 )
K,, = (t1.2138/T)1tln.i23-ls2'7;.
_ 0.000888 g NH3 / m3 air
Kh _ g NH3 / m3 water
Note l: Montes, F., C. A. Rotz, H. Chaoui. (2009). "Process Modeling of Ammonia
Volatilization from Ammonium Solution and Manure Surfaces: A Review with Recommended
Models." Transactions of the American Society of Agricultural and Biological Engineers
(ASABE). 52(5): 1707-1720.
Concentration of NH3 in the Aeration Tank's Diffused Air
0.000888 g NH3 / m3 air 6.87 g NH3 0.00610 g NH3
x =
g NH3 / m3 water m3 water m3 air
Emission of NH3 from the Aeration Tank's Diffused Air
Basis: Diffused air injection rate of 2,000 ft3 air per minute
2,000 ft3 air X m3 X 525,600 min -
minute 35.315 ft3 year
29,766,388 m3 air
year
0.00610 g NH3 X 29,766,388 m3 air X lb. _ 400.3 1b. NH3
m3 air year 453.6 g year
DEQ-CFW 00069323

•
Wastewater Treatment Plant (WTS-A)
Ammonia (NH3) Emissions
Page 3 of 3
Emission of NH3 from the WWTP Clarifiers
The final wastewater treatment unit operation are the clarifiers in which the biomass is
separated from the treated process wastewater through gravity settling. The clarifiers are
quiessent tanks with no mixing or aeration. Any emissions of ammonia from the
clarifiers would be a small fraction of the estimated ammonia emissions from the
Aeration Tank. To be conservative, it will be assumed that the emissions of ammonia
from the clarifiers are equal to the ammonia emissions from the Aeration Tank.
Emission of NH3 from the WWTP Clarifiers = 400.3 lb. NH3 / year
Total Emission of NH3 from the WWTP System (ID No. WT-A)
Emission of NH3 from the WWTP Aeration Tank = 400.3 lb. NH3 / year
Emission of NH3 from the WWTP Clarifiers = 400.3 lb. NH3 / year
Emission of NH3 from the WWTP System = 800.6 lb. NH3 / year
DEQ-CFW 00069324