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HomeMy WebLinkAboutDEQ-CFW_00065898A 0M. v100�� lam= DuPont Chemicals & Fluoroproducts Fayetteville Works Plant 22828 NC Hwy 87 West Fayetteville, NC 28306-7332 CERTIFIED MAIL ARTICLE NUMBER 7007-0710-0005-1455-9225 RETURN RECEIPT REQUESTED Mr. Steven F. Vozzo NCDENR — Division of Air Quality 225 Green Street — Suite 714 Fayetteville, NC 28301 F SUBJECT: Title V Air Permit Modification Air Quality Permit No. 03735T37 DuPont Company — Fayetteville Works Facility ID: 03/09/00009 Dear Mr. Vozzo: November 12, 2013 Enclosed are an original and two copies of an application to modify the DuPont Company — Fayetteville Works' ("DuPont") Title V Air Permit. The requested modifications are the following: • remove No. 6 fuel oil as a fuel option for the two permitted boilers (ID Nos. PS -A and PS-B) • add avoidance conditions for the Temporary Boiler (ID No. PS -Temp) • add / modify two insignificant activities To expedite the permit modification process, two copies of this application and the check for the required application fee have been sent directly to the attention of Dr. Donald R. van der Vaart in the Division of Air Quality's central office. E.I. du Pont de Nemours and Company DEQ-CFW 00065898 Mr. Steven F. Vozzo Page 2 of 5 NCDENR — Division of Air Quality November 12, 2013 DESCRIPTION OF REQUESTED MODIFICATIONS Natural Gas / No. 2 fuel oil / No. 6 fuel oil -fired boilers Section 2.1(A) and Section 2.2(A) of the subject permit currently list the following emission sources: • Natural Gas/No. 2 fuel oil/No. 6 fuel oil -fired boiler (ID No. PS -A), 139.4 million Btu per hour maximum heat input • Natural Gas/No. 2 fuel oil/No. 6 fuel oil -fired boiler (ID No. PS-B), 88.4 million Btu per hour maximum heat input DuPont has not burned No. 6 fuel oil in these boilers since March 2008 and the decision has been made that this fuel will never again be burned. Also, to comply with the requirements of the federal Spill Prevention, Control, and Countermeasure regulations, the No. 6 fuel oil storage tank was permanently removed from service on February 25, 2011. Therefore, with the requested permit modification, Section 2.1(A) and Section 2.2(A) of the subject permit should both show the following listing of emission sources: • Natural Gas/No. 2 fuel oil -fired boiler (ID No. PS -A), 139.4 million Btu per hour maximum heat input, • Natural Gas/No. 2 fuel oil -fired boiler (ID No. PS-B), 88.4 million Btu per hour maximum heat input, and • Natural Gas/No. 2 fuel oil -fired boiler (ID No. PS-C) equipped with a low-NOx burner, 97 million Btu per hour maximum heat input With the removal of No. 6 fuel oil as a fuel option for the DuPont boilers, the following sections, which are based on the use of No. 6 fuel oil, should also be modified as indicated: • Section 1 — Remove the reference to No. 6 fuel oil for PS -A and PS-B. • Section 2.1(A) — Remove the reference to No. 6 fuel oil for PS -A and PS-B. • Section 2.1(A) — Remove the No. 6 fuel oil section from the summary table. • Section 2.1(A)(1)(a) — Remove the reference to No. 6 fuel oil. • Section 2.1(A)(1)(d) — Remove the reference to No. 6 fuel oil. DEQ-CFW 00065899 r Mr. Steven F. Vozzo Page 3 of 5 NCDENR — Division of Air Quality November 12, 2013 • Section 2.1(A)(2)(d) — Delete. • Section 2.1(A)(2)(e) — Delete. • Section 2.1(A)(2)(f) — Delete. • Section 2.1(A)(3)(d) — Delete. • Section 2.1(A)(3)(e) — Delete. • Section 2.1(A)(3)(f) — Renumber the section as 2.1(A)(3)(d). • Section 2.1(A)(3)(g) — Delete. • Section 2. 1 (A)(5)(c)(ii) — Remove the reference to No. 6 fuel oil. • Section 2.1(A)(5)(d)(i) — Remove the reference to No. 6 fuel oil. • Section 2.1(A)(5)(e)(i) — Remove the reference to No. 6 fuel oil. • Section 2.1(A)(6)(b) — Delete. • Section 2.1(A)(6)(c) — Delete. • Section 2.1(A)(6)(d) — Renumber the section as 2.1(A)(6)(b). • Section 2.1(A)(6)(e) — Renumber the section as 2.1(A)(6)(c). • Section 2.1(A)(6)(f) — Renumber the section as 2.1(A)(6)(d). • Section 2.1(A)(6)(g) — Renumber the section as 2.1(A)(6)(e). • Section 2.2(A) — Remove the reference to No. 6 fuel oil for PS -A and PS-B. • Section 2.2(A)(1)(c)(ii) — Remove the reference to No. 6 fuel oil. • Section 2.2(A)(5)(d)(i) — Remove the reference to No. 6 fuel oil. DEQ-CFW 00065900 Mr. Steven F. Vozzo Page 4 of 5 NCDENR — Division of Air Quality November 12, 2013 Temporary Boiler (ID No. PS -Temp) DuPont requests the following language be added Section 2.1(F) of the subject permit: 2. 15A NCAC 2Q. 0317: AVOIDANCE CONDITIONS for 15A NCAC 2D .0524: NEW SOURCE PERFORMANCE STANDARDS a. In order to avoid the applicability of 15A NCAC 2D .0524, the Temporary Boiler shall combust natural gas or distillate oil with a potential sulfur dioxide emission rate no greater than 0.060 lbIMMBtu, be capable of being moved from one location to another, and remain onsite for no longer than 180 consecutive days as defined in 40 CFR 60.41 c. b. The Permittee shall notify the Regional Office in writing within ten days of exceeding the 180 day period. 4. 15A NCAC 2Q. 0317: AVOIDANCE CONDITIONS for 15A NCAC 2D .1109: CAA § 1120); Case -by -Case MACT for Boilers & Process Heaters 15A NCAC 2D .1111: 40 CFR 63 Subpart DDDDD; MACT for Boilers & Process Heaters a. In order to avoid the applicability of 15A NCAC 2D .1109 and 15A NCAC 2D .I 111, the Temporary Boiler shall not remain on site for more than 180 consecutive days. b. If the boiler remains on site for longer than 180 consecutive days, the Permittee shall notify the Regional Office in writing within ten days of exceeding the 180 day period. New and Modified Insignificant Activities Attachment II of the subject permit is a listing of the insignificant activities at this facility. Emission Source ID No. I-01 is the house vacuum system in the Polyvinyl Fluoride Process No. 1 (ID No. FS-B), which is used for housekeeping cleaning purposes. The Polyvinyl Fluoride Process No. 2 (ID No. FS-C) has the identical house vacuum system, but it is not included in the Attachment II list. Both house vacuum systems have two parallel filters, with the second filter having a 99.99% efficiency for 0.3 µm to 1.0 µm particles. Per the vendor information, the total combined particle removal efficiency is 99.995%. Historically, no more than 1074 pounds of solids are collected from each vacuum system per month. Therefore, emissions of particulate matter to the atmosphere would be approximately 0.05 pounds per month, which is less than one pound per year. DEQ-CFW 00065901 Mr. Steven F. Vozzo NCDENR — Division of Air Quality November 12, 2013 Page 5 of 5 To update Attachment II, the current ID No. I-01 should be changed to ID No. I-01 A and its description should be modified as shown below. A new insignificant activity, ID No. I-01 B, should be added with the description shown below. Emission Source Emission Source Description ID No. I-01A Polyvinyl Fluoride Process No. 1 house vacuum system I-01B Polyvinyl Fluoride Process No. 2 house vacuum system If you should have any questions additional or need additional information regarding this permit modification request, please contact me at (910) 678-1155. n 1- Environmental Manager Enclosures DEQ-CFW 00065902 FORM Al FACILITY (General Information) REVISED 05/25/12 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate Al NOTE- APPLICATION WILL NOT BE PROCESSED WITHOUT THE FOLLOWING: ❑ Local Zoning Consistency Determination (if required) 121 Facility Reduction & Recycling Survey Form (Form A4) El Application Fee 21 Responsible Official/Authorized Contact Signature 2Appropriate Number of Copies of Application ❑ P.E. Seal (if required) GENERAL INFORMATION Legal Corporate/Owner Name: E.I. du Pont de Nemours & Company Site Name: DuPont Company - Fayetteville Works Site Address (911 Address) Line 1: 22828 NC Highway 87 W Site Address Line 2: City: Fayetteville state: North Carolina Zip Code: 28306-7332 County: Bladen CONTACT INFORMATION Permit/Technical Contact: Facility/Inspection Contact. Name/ritle: Michael E. Johnson / Environmental Manager Namerritle: Michael E. Johnson / Environmental Manager Mailing Address Line 1: 22828 NC Highway 87 W Mailing Address Line 1: 22828 NC Highway 87 W Mailing Address Line 2: Mailing Address Line 2: City: Fayetteville State: NC Zip Code: 28306-7332 city: Fayetteville State: NC Zip Code: 28306-7332 Phone No. (area code) (910) 678-1155 1 Fax No. (area code) (910) 678-1267 Phone No. (area code) (910) 678-1154 Fax No. (area code) (910) 678-1267 Email Address: michael.e.johnson@dupont.com Email Address: michael.e.johnson@dupont.com Responsible Official/Authorized Contact: Invoice Contact: Name/Title: Ellis H. McGaughy / Plant Manager Name/Title: Michael E. Johnson /Environmental Manager Mailing Address Line 1: 22828 NC Highway 87 W Mailing Address Line 1: 22828 NC Highway 87 W Mailing Address Line 2: Mailing Address Line 2: City: Fayetteville State: INC Zip Code: 28306-7332 City: Fayetteville State: NC Zip Code: 28306-7332 Phone No. (area code) (910) 678-1224 1 Fax No. (area code) (910) 678-1267 Phone No. (area code) (910) 678-11 5Fax No. (area code) (910) 678-1267 Email Address: ellis.h.mcgaughy@dupont.com Email Address: michael.e.johnson@dupont.com APPLICATION IS BEING MADE FOR ❑ New Non -permitted Facility/Greenfield 21 Modification of Facility (permitted) ❑ . Renewal with Modification ❑ Renewal (TV Only) FACILITY CLASSIFICATION AFTER APPLICATION (Check Only One) ❑ General ❑ Small ❑ Prohibitory Small ❑ Synthetic Minor 0 Title V FACILITY (Plant Site) INFORMATION Describe nature of (plant site) operation(s): Facility ID No.: 0900009 Chemical and plastic resin manufacturing. Primary SIC/NAICS Code: 326113 Curr mt/Previous Air Permit No. 03735T37 Expiration Date 01/31/2015 Facility Coordinates: Latitude: 34 deg. 50 min. 38 sec. Longitude: -78 deg. 50 min. 13 sec. Does this application contain confidential ' If yes, please contact the DAQ Regional Office prior to submitting this application.— pp YES ❑ NO C� See Instructions) data? ( rucons ) PERSON OR FIRM THAT PREPARED APPLICATION Person Name: Michael E. Johnson Firm Name: Mailing Address Line 1: 22828 NC Highway 87 W Mailing Address Line 2: City: Fayetteville State: NC Zip Code: County: Phone No. (area code) (910) 678-1155 1Fax No. (area code) (910) 678-1267 Email Address: SIGNATURE OF RESPONSIBLE OFFICIAL/AUTHORIZED CONTACT Name (typed): Ellis H. McGaughy A Title: Plant Manager , ( - s, P X Signature(Blue Ink): �, Date: 013 /ri o�� r Attach Additional Sheets As Necessary DEQ-CFW 00065903 FORMS A2, A3 EMISSION SOURCE LISTING FOR THIS APPLICATION - A2 112r APPLICABILITY INFORMATION - A3 REVISED 04/1 Nn7 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate A2 EMISSION SOURCE LISTING: New, Modified, Previously Unpermitted, Replaced, Deleted EMISSION SOURCE ID NO. EMISSION SOURCE DESCRIPTION CONTROL DEVICE ID NO. CONTROL DEVICE DESCRIPTION Equipment To Be ADDED, By This Application (New, PreviouslyUnpermitted, or:Replacement), Existing Permitted Equipment To Be MODIFIED By This Application PS -A Natural Gas/No. 2 fuel oil/ No. 6 fuel oil -fired boiler None PS-B Natural Gas/No. 2 fuel oil/ No. 6 fuel oil -fired boiler None PS -Temp Natural Gas/No. 2 fuel oil -fired boiler None Equipment To Be DELETED, By This Application 112(r) APPLICABILITY INFORMATION A3 Is your facility subject to 40 CFR Part 68 'Prevention of Accidental Releases" -Section 112(r) of the Federal Clean Air Yes RI No ❑ Act? If No, please specify in detail how your facility avoided applicability: If your facility is Subject to 112(r), please complete the following: A. Have you already submitted a Risk Management Plan (RMP) to EPA Pursuant to 40 CFR Part 68.10 or Part 68.150? Yes No ❑ Specify required RMP submittal date: June 30, 1999 If submitted, RMP submittal date: June 8, 1999 RMP resubmitted on Feb. 1, 2011 B. Are you using administrative controls to subject your facility to a lesser 112(r) program standard? Yes ❑ No ❑x If yes, please specify: Attach Additional Sheets As Necessary DEQ-CFW 00065904 FORM A4 ,URVLY OF AIR EMISSIONS"AND FACILITY -WIDE REDUCTION & RECYCLING ACTIVITIES DATE: 11-01-2013 Does facility have an environmental mangement system in place? (X) YES ( ) NO If so, is facility ISO 14000 Certified? (X ) YES ( ) NO Facility Name: DUPONT COMPANY - FAYETTEVILLE WORKS Permit Number: 03735T37 Facility ID: 0900009 S- County: BLADEN Environmental Contact: MICHAEL E. JOHNSON Mailing Address Line 1: 22828 NC HIGHWAY 87 W Phone No. ( 910 ) 678-1155 Fax No. ( 910 ) 678-1247 Mailing Address Line 2: Zip Code: 28306-7332 County: BLADEN City: FAYETTEVILLE State: NORTH CAROLINA Email Address: MICHAEL.E.JOHNSON@DUPONT.COM Any Air Emissions Source Reductions in the past year? ( X ) YES ( ) NO Enter Code for Data Reduction Quantity Emitted Quantity Emitted Has reduction activity been Source Description and ID Air Pollutant Emission Reduction Option Implemented from prior annual from current annual discontinued? If so, when Addition detail about source O lion See Codes mo/yr) report to DAQ (lb/yr) report to DAQ (Ib/yr) was It discontinued? (molyr coal fired boiler ES1 and fleets NOx C16 & C10 Jun-04 1.98E+06 1.87E+66 Dec-04 Fleet'idling improvements and boiler improvements. NATURAL GAS / FUEL 0.008 LB/ 0.001 LB/ OIL FIRED BOILER (ID S02 C11 / C12 Jan-11 MMBTU USING MMBTU USING NO THIS FACILITY SWITCHED FROM NO. 2 FUEL OIL TO NATURAL GAS AS THE PRIMARY FUEL FOR THIS NO. PS -A) NO.2 FUEL OIL NATURAL GAS BOILER IN JANUARY 2011. NATURAL GAS / FUEL 0.008 LB/ 0.0(I LB/ OIL FIRED BOILER (ID S02 C11 / C12 Nov-10 MMBTU USING MMBTU USING NO THIS FACILITY SWITCHED FROM NO. 2 FUEL OIL TO NATURAL GAS AS THE PRIMARY FUEL FOR THIS NO. PS-B) NO.2 FUEL OIL NATURAL GAS BOILER IN NOVEMBER 2010. Comments: Any Reductions or Recycling Activities in the past year? ( ) YES ( X) NO Pollutant Enter Code for Date Reduction Quantity Emitted Quantity Emitted Has reduction activity been Source Description or Activity or Emission Reduction Option Implemented from prior annual from current annual discontinued? If so, when Addition detail about source Recycled or Reduced Materials O lion See Codes (mo/ r) report report was it discontinuetl? (mo/ r Energy Conservation Reduced Electric and ,: kWh/500y000 r raw 300,000 kWhlyr and Implemented EMS raw material usage C14 8 C18 Jan-05 materials 100 raw materials NO Through implementation of an EMS reduced energy use tons/ r 80 tons/yr Comments: �� PDLLVTION � PREVENTION Ravlsao — Attach Additional Sheets As Necessary For assistance with FORM A4, please contact the North Carolina Division of Pollution Prevention and Environmental Assistance at 1-800-763-0136 or nowaste@p2pays.org FORM B SPECIFIC EMISSIONS SOURCE INFORMATION (REQUIRED FOR ALL SOURCES) REVISED 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate I B EMISSION SOURCE DESCRIPTION: Natural Gas / No. 2 fuel oil -fired boiler EMISSION SOURCE ID NO: PS -A CONTROL DEVICE ID NO(S): None OPERATING SCENARIO 1 OF 2 EMISSION POINT (STACK) ID NO(S): PEP-1 DESCRIBE IN DETAILTHE EMISSION SOURCE PROCESS (ATTACH FLOW DIAGRAM): This emission source is a natural gas / No. 2 fuel oil -fired boiler with a maximum heat input of 139.4 million Btu per hour. The purpose for this permit modification is to remove No. 6 fuel oil as an optional fuel for this boiler. This operating scenario is based on firing exclusively natural gas. TYPE OF EMISSION SOURCE (CHECK AND COMPLETE APPROPRIATE FORM B1-139 ON THE FOLLOWING PAGES): 0 Coal,wood,oil, gas, other burner (Form 131) ❑ Woodworking (Form 64) ❑ Manufact. of chemicals/coatings/inks (Form 67) ❑ Int.combustion engine/generator (Form 132) ❑ Coating/finishing/printing (Form B5) ❑ Incineration (Form B8) ❑ Liquid storage tanks (Form 63) ❑ Storage silos/bins (Form 136) ❑ Other (Form Bg) START CONSTRUCTION DATE: 1970 1OPERATION DATE: 1971 JDATE MANUFACTURED: 1969 MANUFACTURER / MODEL NO.: Zurn 19M Keystone 1EXPECTED OP. SCHEDULE: 24 HR/DAY 7 DAY/WK 52 WK/YR IS THIS SOURCE SUBJECT TO? NSPS (SUBPART?): NO NESHAP (SUBPART?): 1120) MACT (SUBPART?): 1120) PERCENTAGE ANNUAL THROUGHPUT (%): JAN-MAR 25 APR-JUN 25 JUL-SEP 25 OCT-DEC 25 EXPECTED ANNUAL HOURS OF OPERATION: -8700 VISIBLE STACK EMISSIONS UNDER NORMAL OPERATION: -0 % OPACITY CRITERIA AIR POLLUTANT EMISSIONS INFORMATION FOR THIS SOURCE AIR POLLUTANT EMITTED SOURCE OF EMISSION FACTOR EXPECTED ACTUAL (AFTER CONTROLS/LIMITS) POTENTIAL EMISSIONS (BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS) Ib/hr tons/yr Ib/hr tons/yr lblhr tons/yr PARTICULATE MATTER (PM) NCDAQ 1.04 4.55 1.04 4.55 1.04 4.55 PARTICULATE MATTER<10 MICRONS (PM10) NCDAQ 1.04 4.55 1.04 4.55 1.04 4.55 PARTICULATE MATTER<2.5 MICRONS (PM2.5) NCDAQ 1.04 4.55 1.04 4.55 1.04 4.55 SULFUR DIOXIDE (S02) NCDAQ 0.08 0.36 0.08 0.36 0.08 0.36 NITROGEN OXIDES (NOx) NCDAQ 38.27 167.61 38.27 167.61 38.27 167.61 CARBON MONOXIDE (CO) NCDAQ 11.48 50.28 11.48 50.28 11.48 50.28 VOLATILE ORGANIC COMPOUNDS (VOC) NCDAQ 0.75 3.29 0.75 3.29 0.75 3.29 LEAD NCDAQ 7E-05 0.599 0.00007 0.599 0.00007 0.599 OTHER NCDAQ 10 1 0 1 0 0 0 0 HAZARDOUS AIR POLLUTANT EMISSIONS INFORMATION FOR THIS SOURCE HAZARDOUS AIR POLLUTANT AND CAS NUMBER SOURCE OF EMISSION FACTOR EXPECTED ACTUAL (AFTER CONTROLS/LIMITS) POTENTIAL EMISSIONS (BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS) Whir tons/yr Ib/hr tons/yr Ib/hr tons/yr See attached NCDAQ "Natural Gas Combustion Emissions Calc." TOXIC AIR POLLUTANT EMISSIONS INFORMATION FOR THIS SOURCE INDICATE EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS TOXIC AIR POLLUTANT AND CAS NO. EF SOURCE Ib/hr Ib/day Ib/yr See attached NCDAQ "Natural Gas Combustion Emissions Calc." Attachments: (1) emissions calculations and supporting documentation; (2) indicate all requested state and federal enforceable permit limits (e.g. hours of operation, emission rates) and describe how these are monitored and with what frequency; and (3) describe any monitoring devices, gauges, or test ports for this source. COMPLETE THIS FORM AND COMPLETE AND ATTACH APPROPRIATE B1 THROUGH B9 FORM FOR EACH SOURCE Attach Additional Sheets As Necessary DEQ-CFW 00065906 NATURAL GAS COMBUSTION EMISSIONS CALCULATOR REVISION L 10/08/2013 - OUTPUT SCREEN A=4*A Instructions: Enter emission source / facility data on the "INPUT" tab/screen. The air emission results and summary of input data are viewed / printed on the "OUTPUT" tab/screen. The different tabs are on the bottom of this screen. NCDENR This spreadsheet is for your use only and should be used with caution. DENR does not guarantee the accuracy of the information contained. This spreadsheet is subject to continual revision and updating. It is your responsibility to be aware of the most current information available. DENR is not responsible for errors or omissions that may be contained herein. SOURCE/ FACILITY1 USER INPUTSUMMARY FROMINPUT SCREEN COMPANY: DuPont Company Fayetteville Works i� Y " Y FACILITY ID NO.: 900009 PERMIT NUMBER: 03735T37 EMISSION SOURCE DESCRIPTION: 139.4 MMBTU/HR NATURAL GAS -FIRED BOILER FACILITY CITY: Fayetteville EMISSION SOURCE ID NO.: PS -A FACILITY COUNTY: Bladen CONTROL DEVICE: I NO CONTROL POLLUTANT CONTROL EFF. SPREADSHEET PREPARED BY: Michael E. Johnson NOX CALC'D AS 0% ACTUAL FUEL THROUGHPUT: 1,197.20 1 Ou SCF/YR IFUEL HEAT VALUE: 1,020 BTU/SCF POTENTIAL FUEL THROUGHPUT: 1,197.20 10e SCFNR BOILER TYPE: LARGE WALL -FIRED BOILER (> 100 mmBTU/HR) INO SNCR APPLIED REQUESTED MAX. FUEL THRPT: 1,197.20 108 SCFNR HOURS OF OPERATIONS: 24 CRITER/A AIR POLLUTANT EMISSIONS INFORMATION - AIR POLLUTANT EMITTED ACTUAL EMISSIONS (AFTERCONTROLS/LIMITS) POTENTIAL EMISSIONS EMISSION FACTOR Ib/mmBtu (BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS) b/hr tons/ r Ib/hr tons/ r Ib/hr tons/ r uncontroled controlled PARTICULATE MATTER Total 1.04 4.55 1.04 4.55 1.04 4.55 0.007 0.007 PARTICULATE MATTER Condensable 0.78 3.41 0.78 3.41 0.78 3.41 0.006 0.006 PARTICULATE MATTER Filterable 0.26 1.14 0.26 1.14 0.26 1.14 0.002 0.002 SULFUR DIOXIDE (S02) NITROGEN OXIDES NOx 0,08 38.27 0.36 167.61 0.08 38.27 0.36 167.61 0.08 38.27 0.36 167.61 0.001 0.275 0.001 0.275 CARBON MONOXIDE CO 11.48 50.28 11.48 50.28 11.48 50.28 0.082 0.082 VOLATILE ORGANIC COMPOUNDS VOC 0.75 3.29 0.75 3.291 0.75 3.29 0.005 0.005 TOXIC f HAZARDOUS AIR POLLUTANT EMISSIONS INFORMATION" TOXIC / HAZARDOUS AIR POLLUTANT CAS NUMBER ACTUAL EMISSIONS POTENTIAL EMISSIONS EMISSION FACTOR (AFTERCONTROLS/LIMITS) (BEFORECONTROLVUMITS) (AFTERCONTROLS/LIMITS) Ib/mmBtu Ib/hr Ibs/ r Ib/hr Ibs/ r Ib/hr Ibs/yr uncontrolled controlled Acetaldehyde TH 75070 0.00E+00 I 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Acrolein TH 107028 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Ammonia T 7664417 4.37E-01 3.83E+03 4.37E-01 3.83E+03 4.37E-01 3.83E+03 3.14E-03 3.14E-03 Arsenic unlisted compounds TH ASC-other 2.73E-05 2.39E-01 2.73E-05 2.39E-01 2.73E-05 2.39E-01 1.96E-07 1.96E-07 Benzene TH 71432 2.87E-04 2.51E+00 2.87E-04 2.51E+00 2.87E-04 2.51E+00 2.06E-06 2.06E-06 Benzo a rene TH 50328 1.64E-07 1.44E-03 1.64E-07 1.44E-03 1.64E-07 1.44E-03 1 1.18E-09 1.19E-09 Beryllium metal unreacted TH 7440417 1.64E-06 1.44E-02 1.64E-06 1.44E-02 I 1.64E-06 1.44E-02 1.18E-08 1.18E-08 Cadmium metal elemental unreacted TH 7440439 1.50E-04 1.32E+00 1.50E-04 1.32E+00 1.50E-04 1.32E+00 1.08E-06 1.08E-06 Chromic acid VI TH 7738945 1.91E-04 1.68E+00 1.91E-04 1.68E+00 1.91E-04 1.68E+00 1.37E-06 1.37E-06 Cobalt unlisted compounds H COC-other 1.15E-05 1.01E-01 1.15E-05 1.01E-01 I 1.15E-05 1.01E-01 8.24E-08 8.24E-08 Formaldehyde TH 50000 1.03E-02 8.98E+01 1.03E-02 8.98E+01 1.03E-02 8.98E+01 7.35E-05 7.35E-05 Hexane, n- TH 110543 2.46E-01 2.15E+03 2.46E-01 2.15E+03 2.46E-01 2.15E+03 1.76E-03 1.76E-03 Lead unlisted compounds H PBC-other 6.83E-05 5.99E-01 6.83E-05 5.99E-01 6.83E-05 5.99E-01 4.90E-07 4.90E-07 Manganese unlisted compounds TH MNC-other 5.19E-05 4.55E-01 5.19E-05 4.55E-01 5.19E-05 4.55E-01 I 3.73E-07 3.73E-07 Mercury vapor TH 7439976 3.55E-05 3.11E-01 3.55E-05 3.11E-01 3.55E-05 3.11E-01 2.55E-07 2.55E-07 Na thalene H 91203 8.34E-05 7.30E-01 8.34E-05 7.30E-01 8.34E-05 7.30E-01 5.98E-07 5.98E-07 Nickel metal TH 7440020 2.87E-04 2.51E+00 2.87E-04 2.51E+00 2.87E-04 2.51E+00 2.06E-06 2.06E-06 Selenium compounds H SEC 3.28E-06 2.87E-02 3.28E-06 2.87E-02 3.28E-06 2.87E-02 2.35E-08 2.35E-08 Toluene TH 108883 4.65E-04 4.07E+00 4.65E-04 4.07E+00 4.65E-04 4.07E+00 3.33E-06 3.33E-06 Total HAPs I 2.58E-01 I 2.26E+03 I 2.58E-01 2.26E+03 2.58E-01 I 2.26E+03 1.85E-03 I 1.85E-03 Highest HA_ P Hexane I 2.46E-01 I 2.15E+03 I 2.46E-01 2.15E+03 2.46E-01 2.15E+03 1.76E 03 1.76E-03 TOXIC AIR POLLUTANT'EMISSIONS INFORMATION' FOR PERMITTING EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS EMISSION FACTOR Ib/mmBtu TOXIC AIR POLLUTANT CAS Num. Ib/hr lb/day Ib/ r uncontrolled controlled Acetaldehyde TH 75070 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Acrolein TH 107028 0.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E+00 Ammonia T 7664417 4.37E-01 1.05E+01 3.83E+03 3.14E-03 3.14E-03 Arsenic unlisted compounds TH ASC-other 2.73E-05 6.56E-04 2.39E-01 1.96E-07 1.96E-07 Benzene TH 71432 2.87E-04 6.89E-03 2.51E+00 2.06E-06 2.06E-06 Benzo a rene TH 50328 1.64E-07 3.94E-06 1.44E-03 1.18E-09 Beryllium meta{ unreacted TH 7440417 1.64E-06 3.94E-05 1.44E-02 1.18E-08 Cadmium metal elemental unreacted TH 7440439 1.50E-04 3.61E-03 1.32E+00 1.08E-06 Soluble chromate compounds, as chromium VI equivalent SoICR6 1.91 E-04 4.59E-03 1.68E+00 V2565E-07 1.37E-06 Formaldehyde TH 50000 1.03E-02 2.46E-01 8.98E+01 7.35E-05 Hexane n- TH 110543 2.46E-01 5.90E+00 2.15E+03 1.76E-03 Manganese unlisted compounds TH MNC-other 5.19E-05 1.25E-03 4.55E-01 3.73E-07 Mercuryvapor TH 7439976 3.55E-05 8.53E-04 3.11 E-01 2.55E-07 Nickel metal TH 7440020 2.87E-04 6.89E-03 2.51E+00 2.06E-06 2.06E-06 Toluene (TH) 108883 4.65E-04 1.12E-02 4.07E+00 I 3.33E-06 3.33E-06 DEQ-CFW 00065907 FORM B SPECIFIC EMISSIONS SOURCE INFORMATION (REQUIRED FOR ALL SOURCES) REVISED 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate 1 " 1 EMISSION SOURCE DESCRIPTION: Natural Gas / No. 2 fuel oil -fired boiler EMISSION SOURCE ID NO: PS -A CONTROL DEVICE ID NO(S): None OPERATING SCENARIO 2 OF 2 EMISSION POINT (STACK) ID NO(S): PEP-1 DESCRIBE IN DETAILTHE EMISSION SOURCE PROCESS (ATTACH FLOW DIAGRAM): This emission source is a natural gas / No. 2 fuel oil -fired boiler with a maximum heat input of 139.4 million Btu per hour. The purpose for this permit modification is to remove No. 6 fuel oil as an optional fuel for this boiler. This operating scenario is based on firing exclusively No. 2 fuel oil. TYPE OF EMISSION SOURCE (CHECK AND COMPLETE APPROPRIATE FORM B1-B9 ON THE FOLLOWING PAGES): Coal,wood,oil, gas, other burner (Form 131) ❑ Woodworking (Form 134) ❑ Manufact. of chemicals/coatings/inks (Form 137) ❑ Int.combustion engine/generator (Form 132) ❑ Coating/finishing/printing (Form B5) ❑ Incineration (Form 138) ❑ Liquid storage tanks (Form B3) ❑ Storage silos/bins (Form 136) ❑ Other (Form 139) START CONSTRUCTION DATE: 1970 1OPERATION DATE: 1971 JDATE MANUFACTURED: 1969 MANUFACTURER / MODEL NO.: Zurn 19M Keystone 1EXPECTED OP. SCHEDULE: 24 HR/DAY 7 DAY/WK 52 WK/YR IS THIS SOURCE SUBJECT TO? NSPS (SUBPART?): NO NESHAP (SUBPART?): 1120) MACT (SUBPART?): 1120) PERCENTAGE ANNUAL THROUGHPUT (%): JAN-MAR 25 APR-JUN 25 JUL-SEP 25 OCT-DEC 25 EXPECTED ANNUAL HOURS OF OPERATION: -8700 IVISIBLE STACK EMISSIONS UNDER NORMAL OPERATION: -0 % OPACITY CRITERIA AIR POLLUTANT EMISSIONS INFORMATION FOR THIS SOURCE AIR POLLUTANT EMITTED SOURCE OF EMISSION FACTOR EXPECTED ACTUAL (AFTER CONTROLS/LIMITS) POTENTIAL EMISSIONS (BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS) Ib/hr tons/yr Iblhr tonslyr Ib/hr tons/yr PARTICULATE MATTER (PM) NCDAQ 3.29 14.39 3.29 -14.39 3.29 14.39 PARTICULATE MATTER<10 MICRONS (PM1o) NCDAQ 3.29 14.39 3.29 14.39 3.29 14.39 PARTICULATE MATTER<2.5 MICRONS (PM2.5) NCDAQ 3.29 14.39 3.29 14.39 3.29 14.39 SULFUR DIOXIDE (S02) NCDAQ 70.70 309.65 70.70 309.65 70.70 309.65 NITROGEN OXIDES (NOx) NCDAQ 23.90 104.67 23.90 104.67 23.90 104.67 CARBON MONOXIDE (CO) NCDAQ 4.98 21.81 4.98 21.81 4.98 21.81 VOLATILE ORGANIC COMPOUNDS (VOC) NCDAQ 0.20 0.87 0.20 0.87 0.20 0.87 LEAD NCDAQ 0.0013 10.99 0.0013 10.99 0.0013 10.99 OTHER NCDAQ 0 0 0 1 0 0 0 HAZARDOUS AIR POLLUTANT EMISSIONS INFORMATION FOR THIS SOURCE HAZARDOUS AIR POLLUTANT AND CAS NUMBER SOURCE OF EMISSION FACTOR EXPECTED ACTUAL (AFTER CONTROLS/LIMITS) POTENTIAL EMISSIONS (BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS) Whir tons/yr Ib/hr tons/yr Whir tons/yr See attached NCDAQ "Fuel Oil Combustion Emissions Calculator" TOXIC AIR POLLUTANT EMISSIONS INFORMATION FOR THIS SOURCE INDICATE EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS TOXIC AIR POLLUTANT AND CAS NO. EF SOURCE Ib/hr lb/day Ib/yr See attached NCDAQ "Fuel Oil Combustion Emissions Calculator" Attachments: (1) emissions calculations and supporting documentation; (2) indicate all requested state and federal enforceable permit limits (e.g. hours of operation, emission rates) and describe how these are monitored and with what frequency; and (3) describe any monitoring devices, gauges, or test ports for this source. COMPLETE THIS FORM AND COMPLETE AND ATTACH APPROPRIATE 81 THROUGH B9 FORM FOR EACH SOURCE Attach Additional Sheets As Necessary DEQ-CFW 00065908 Instructions: Enter emission source / facility data on the "INPUT" tab/screen. The air emission results and summary of input data are viewed / printed on the "OUTPUT' tab/screen. The different tabs are on the bottom of this screen. 1• This spreadsheet is for your use only and should be used with caution. DENR does not guarantee the accuracy of the information contained. This spreadsheet R subject to continual revision and updating. It is your responsibility to be aware of the most current information available. DENR is not responsible for errors or NCDEN� omissions that may be contained herein. SOURCE/FACILITY/USER INPUT SUMMARY(FROM INPUTSCREEN . COMPANY: DuPont Company - Fayetteville Works MAX HEAT INPUT: 139.40 MMBTU/HR FACILITY ID NO.: 900009 FUEL HEAT VALUE: 140,000 BTU/GAL PERMIT NUMBER: 03735T37 HHV for GHG CALCULATIONS: 0.138 mm BTU/GAL FACILITY CITY: Fayetteville ACTUAL ANNUAL FUEL USAGE: 8,722,457 GAL/YR FACILITY COUNTY: Bladen MAXIMUM ANNUAL FUEL USAGE: 8,722,457 GAL/YR USER NAME: Michael E. Johnson MAXIMUM SULFUR CONTENT: 0.5 % EMISSION SOURCE DESCRIPTION: No. 2 oil -fired Boiler REQUESTED HERMIT LIMITATIONS EMISSION SOURCE ID NO.: PS -A MAX. FUEL USAGE: 8,722,457 GAL/YR MAX. SULFUR CONTENT: 0.5 % TYPE OF CONTROL DEVICES POLLUTANT CONTROL EFF. NONE/OTHER PM 0 NONE/OTHER S02 0 NONE/OTHER NOx 0 METHOD USED TO COMPUTE ACTUAL GHG EMISSIONS: TIER 1: DEFAULT HIGH HEAT VALUE AND DEFAULT EF CARBON CONTENT USED FOR GHGS (kg C/gal): CARBON CONTENT NOT USED FOR CALCULATION TIER CHOSEN CRITERIA AIR POLLUTANT EMISSIONS INFORMATION AIR POLLUTANT EMITTED ACTUAL EMISSIONS (AFTER CONTROLS/LIMITS) POTENTIAL EMSSIONS (BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS) EMISSION FACTOR Ib/103 gal) Ib/hr tons/yr Ib/hr I tons/yr Ib/hr tons/ r uncontrolled controlled TOTAL PARTICULATE MATTER (PM) (FPM+CPM) 3.29 14.39 3.29 1 14.39 3.29 14.39 3.30E+00 3.30E+00 FILTERABLE PM (FPM) 1.99 8.72 1.99 1 8.72 1.99 8.72 2.00E+00 2.00E+00 CONDENSABLE PM (CPM) 1.29 5.67 1.29 5.67 1.29 5.67 1.30E+00 1.30E+00 FILTERABLE PM<10 MICRONS (PM10) 1.00 4.36 1.00 4.36 1.00 4.36 1.00E+00 1.00E+00 FILTERABLE PM<2.5 MICRONS (PM2.5) 0.25 1.09 0.25 1.09 0.25 1.09 2.50E-01 2.50E-01 SULFUR DIOXIDE (S02) 70.70 309.65 70.70 309.65 70.70 309.65 7.10E+01 7.10E+01 NITROGEN OXIDES (NOx) 23.90 104.67 23.90 104.67 23.90 104.67 2.40E+01 2.40E+01 CARBON MONOXIDE CO 4.98 21.81 4.98 21.81 4.98 21.81 5.00E+00 5.00E+00 VOLATILE ORGANIC COMPOUNDS VOC 0.20 0.87 0.20 0.87 0.20 0.87 2.00E-01 2.00E-01 LEAD 0.00 0.01 0.00 0.01 0.00 0.01 1.26E-03 1.26E-03 .. ,OXI.C�D/1H.gZ�IRD17�fS�'i P _ _ ` TA !SS`C,O711 /LiIF �INECTIQ . .. TOXIC IfHAZARDOUS AIR POLLUTANT CAS NUMBER ACTUAL EMISSIONS (AFTER CONTROLS/LIMITS) POTENTIAL EMSSIONS (BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS) EMISSION FACTOR (Ib/103 gal) Ib/hr Ib/yr Ib/hr Ib/yr Ib/hr Ib/yr uncontrolled controlled Antimony &compounds (H) SBC 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.00E+00 0.00E+00 Arsenic & compounds.. (TH) ASC 5.6E-04 4.9E+00 5.6E-04 4.9E+00 5.6E-04 4.9E+00 5.60E-04 5.60E-04 Benzene (TH) 71432 2.7E-03 2.4E+01 2.7E-03 2,4E+01 2.7E-03 2.4E+01 2.75E-03 2.75E-03 Beryllium & compounds (H) BEC 4.2E-04 3.7E+00 4.2E-04 3.7E+00 4.2E-04 3.7E+00 4.20E-04 4.20E-04 Cadium & compounds (TH) CDC 4.2E-04 3.7E+00 4.2E-04 3.7E+00 3.7E+00 4.20E-04 4.20E-04 Chromium - AII/Total (H) CRC 4.2E-04 3.7E+00 4.2E-04 3.7E+00 3.7E+00 4.20E-04 4.20E-04 Cobalt compounds (H) CDC 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.00E+00 0.00E+00 Ethylbenzene (H) 100414 8.1E-04 7.1E+00 8.1 E-04 7.1 E+00 K4.8E-02 7.1 E+00 8.17E-04 8.17E-04 Fluorides (sum fluoride compounds) (T) 16984488 3.7E-02 3.3E+02 3.7E-02 3.3E+02 3.3E+02 3.73E-02 3.73E-02 Formaldehyde (TH) 50000 4.8E-02 4.2E+02 4.8E-02 4.2E+02 4.2E+02 4.80E-02 4.80E-02 Lead and Lead compounds (H) PBC 1.3E-03 1.1E+01 1.3E-03 1.1E+01 1.1E+01 1.26E-03 1.26E-03 Manganese & compounds (TH) MNC 8.4E-04 7.3E+00 8.4E-04 7.3E+00 7.3E+00 8.40E-04 8.40E-04 Mercury & compounds (TH) HGC 4.2E-04 3.7E+00 4.2E-04 3.7E+00 4.2E-04 3.7E+00 4.20E-04 4.20E-04 Methyl chloroform (TH) 71566 2.3E-04 2.1E+00 2.3E-04 2.1E+00 2.3E-04 2.1E+00 2.36E-04 2.36E-04 Napthalene (H) 91203 3.3E-04 2.9E+00 3.3E-04 2.9E+00 3.3E-04 2.9E+00 3.33E-04 3.33E-04 Nickle & compounds (H) NIC 4.2E-04 3.7E+00 4.2E-04 3.7E+00 4.2E-04 3.7E+00 4.20E-04 4.20E-04 Phosphorus Metal, Yellow or White (H) 7723140 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.00E+00 0.00E+00 POM rates uncontrolled (H) POM 3.3E-03 2.9E+01 3.3E-03 2.9E+01 3.3E-03 2.9E+01 3.30E-03 3.30E-03 Selenium compounds (H) SEC 2.1 E-03 1.8E+01 2.1 E-03 1.8E+01 2.1 E-03 1.8E+01 2.10E-03 2.10E-03 Toluene (TH) 108883 7.9E-02 6.9E+02 7.9E-02 6.9E+02 7.9E-02 6.9E+02 7.97E-02 7.97E-02 Xylene (TH) 1330207 1.4E-03 1.2E+01 1.4E-03 1.2E+01 1.4E-03 1.2E+01 1.40E-03 1.40E-03 Total HAP (H) 1.4E-01 1.3E+03 1.4E-01 1,3E+03 1.4E-01 1.3E+03 1.4E-01 1.4E-01 Larget HAP (H) 7.93E-02 6.95E+02 7.93E-02 6.95E+02 7.93E-02 6.95E+02 7.97E-02 7.97E-02 vT,OJFIC+AIRtROIIL'UT9NTy�M/SSIONS 1VFQ AlI,OIi(I F,ORiPERMI. INCIRORPOSES EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS EMISSION FACTOR (Ib/103 gal) TOXIC AIR POLLUTANT CAS Num. Ib/hr lb/day Ib/yr uncontrolled controlled Arsenic & compounds (TH) ABC 5.58E-04 1.34E-02 4.88E+00 5.60E-04 5.60E-04 Benzene (TH) 71432 2.74E-03 6.57E-02 2.40E+01 2.75E-03 2.75E-03 Cadium & compounds (TH) CDC 4.18E-04 1.00E-02 3.66E+00 4.20E-04 4.20E-04 Fluorides (sum fluoride compounds) (T) 16984488 3.71E-02 8.91E-01 3.25E+02 3.73E-02 3.73E-02 Formaldehyde (TH) 50000 4.78E-02 1.15E+00 4.19E+02 4.80E-02 4.80E-02 Manganese & compounds (TH) MNC 8.36E-04 2.01 E-02 7.33E+00 8.40E-04 8.40E-04 Mercury & compounds (TH) HGC 4.18E-04 1.00E-02 3.66E+00 4.20E-04 4.20E-04 Methyl chloroform (TH) 71566 2.35E-04 5.64E-03 2.06E+00 2.36E-04 2.36E-04 Toluene (TH) 108883 7.93E-02 1.90E+00 6.95E+02 7.97E-02 7.97E-02 Xylene (TH) 1330207 1.39E-03 3.35E-02 1.22E+01 1.40E-03 1.40E-03 DEQ-CFW 00065909 v FORM B SPECIFIC EMISSIONS SOURCE INFORMATION (REQUIRED FOR ALL SOURCES) REVISED 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate EMISSION SOURCE DESCRIPTION: Natural Gas / No. 2 fuel oil -fired boiler EMISSION SOURCE ID NO: PS-B CONTROL DEVICE ID NO(S): None OPERATING SCENARIO 1 OF 2 EMISSION POINT (STACK) ID NO(S): PEP-1 DESCRIBE IN DETAILTHE EMISSION SOURCE PROCESS (ATTACH FLOW DIAGRAM): This emission source is a natural gas / No. 2 fuel oil -fired boiler with a maximum heat input of 88.4 million Btu per hour. The purpose for this permit modification is to remove No. 6 fuel oil as an optional fuel for this boiler. This operating scenario is based on firing exclusively natural gas. TYPE OF EMISSION SOURCE (CHECK AND COMPLETE APPROPRIATE FORM B1-B9 ON THE FOLLOWING PAGES): N Coal,wood,oil, gas, other burner (Form B1) ❑ Woodworking (Form 134) ❑ Manufact. of chemicals/coatings/inks (Form 137) ❑ Int.combustion engine/generator (Form 132) ❑ Coating/finishing/printing (Form B5) ❑ Incineration (Form 138) ❑ Liquid storage tanks (Form B3) ❑ Storage silos/bins (Form B6) ❑ Other (Form B9) START CONSTRUCTION DATE: 1982 1 OPERATION DATE: Oct 1982 1 DATE MANUFACTURED: 1982 MANUFACTURER / MODEL NO.: Zurn / 2-Drum I EXPECTED OP. SCHEDULE: 24 HR/DAY 7 DAY/WK 52 WK/YR IS THIS SOURCE SUBJECT TO? NSPS (SUBPART?): NO NESHAP (SUBPART?): 1120) MACT (SUBPART?): 1120) PERCENTAGE ANNUAL THROUGHPUT (%): JAN-MAR 25 APR-JUN 25 JUL-SEP 25 OCT-DEC 25 EXPECTED ANNUAL HOURS OF OPERATION: -8700 VISIBLE STACK EMISSIONS UNDER NORMAL OPERATION: -0 % OPACITY CRITERIA AIR POLLUTANTEMISSIONS /NFORMA;T/ON.FOR:TH/S SOURCE, ">. AIR POLLUTANT EMITTED SOURCE OF EMISSION FACTOR EXPECTED ACTUAL (AFTER CONTROLS/LIMITS) POTENTIAL EMISSIONS (BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS) lb/hr tons/yr Ib/hr tons/yr Ib/hr tons/yr PARTICULATE MATTER (PM) NCDAQ 0.66 2.88 0.66 2.88 0.66 2.88 PARTICULATE MATTER<10 MICRONS (PM10) NCDAQ 0.66 2.88 0.66 2.88 0.66 2.88 PARTICULATE MATTER<2.5 MICRONS (PM2.5) NCDAQ 0.66 2.88 0.66 2.88 0.66 2.88 SULFUR DIOXIDE (S02) NCDAQ 0.05 0.23 0.05 0.23 0.05 0.23 NITROGEN OXIDES (NOx) NCDAQ 8.67 1 37.96 8.67 37.96 8.67 37.96 CARBON MONOXIDE (CO) NCDAQ 7.28 31.89 7.28 31.89 7.28 31.89 VOLATILE ORGANIC COMPOUNDS (VOC) NCDAQ 0.48 2.09 0.48 2.09 1 0.48 1 2.09 LEAD NCDAQ 4E-05 0.38 4.E-05 0.38 4.E-05 0.38 OTHER NCDAQ 0 0 0 0 0 0 HAZARDOUS AIR POLLUTANT EMISSIONS INF,ORMATIOMFOR THIS -SOURCE HAZARDOUS AIR POLLUTANT AND CAS NUMBER SOURCE OF EMISSION FACTOR EXPECTED ACTUAL (AFTER CONTROLSILIMITS) POTENTIAL EMISSIONS (BEFORE CONTROLSILIMITS) (AFTER CONTROLS/LIMITS) Whir tons/yr Ib/hr tons/yr Ib/hr tons/yr See attached NCDAQ "Natural Gas Combustion Emissions Calc." TOXIC AIR POLLUTANT EMISSIONS INFORMATION FOR THIS SOURCE INDICATE EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS TOXIC AIR POLLUTANT AND CAS NO. EF SOURCE Whir lb/day Ib/yr See attached NCDAQ "Natural Gas Combustion Emissions Calc." Attachments: (1) emissions calculations and supporting documentation; (2) indicate all requested state and federal enforceable permit limits (e.g. hours of operation, emission rates) and describe how these are monitored and with what frequency; and (3) describe any monitoring devices, gauges, or test ports for this source. COMPLETE THIS FORM AND COMPLETE AND ATTACH APPROPRIATE B1 THROUGH B9 FORM FOR EACH SOURCE Attach Additional Sheets As Necessary DEQ-CFW 00065910 I, w NATURAL GAS COMBUSTION EMISSIONS CALCULATOR REVISION L 10/08/2013 - OUTPUT SCREEN 4• Instructions: Enter emission source / facility data on the "INPUT' tab/screen. The air emission results and summary of input data are viewed / printed on the "OUTPUT' tab/screen. The different tabs are on the bottom of this screen. 'A NCDEhIR This spreadsheet is for your use only and should be used with caution. DENR does not guarantee the accuracy of the information contained. This spreadsheet is subject to continual revision and updating. It is your responsibility to be aware of the most current information available. DENR is not responsible for errors or omissions that may be contained herein. SOURCE/FACILITY/USER INPUT SUMMARY FROM INPUT SCREEN COMPANY: DuPont Company Fayetteville Works p y " i1 FACILITY ID NO.: 900009 PERMIT NUMBER: 03735T37 EMISSION SOURCE DESCRIPTION: 88.4 MMBTU/HR NATURAL GAS -FIRED BOILER FACILITY CITY: Fayetteville EMISSION SOURCE ID NO.: PS-B FACILITY COUNTY: Bladen CONTROL DEVICE: I NO CONTROL POLLUTANT CONTROL EFF. SPREADSHEET PREPARED BY: Michael E. Johnson NOX CALUD AS 0 ACTUAL -FUEL THROUGHPUT: 759.20 10 SCF/YR FUELHEATVALUE: 1.020 BTU/SCF POTENTIAL FUEL THROUGHPUT: 759.20 106 SCF/YR BOILER TYPE: SMALL BOILER (<100 mmBTU/HR) NO SNCR APPLIED REQUESTED MAX. FUEL THRPT: 759.20 10s SCF/YR HOURS OF OPERATIONS: 24 CRITERIA AIR POLLUTANT EMISSIONS INFORMATION AIR POLLUTANT EMITTED ACTUAL EMISSIONS (AFTERCONTROLS/LIMITS) POTENTIAL EMISSIONS EMISSION FACTOR Ib/mmBtu (BEFORE CONTROLS r LIMITS) (AFTER CONTROLS/LIMITS) Ib/hr I tons/yr Ib/hr tons/ r Ib/hr tons/ r uncontrolled controlled PARTICULATE MATTER (Total) 0.66 2.88 0.66 2.88 0.66 2.88 0.007 0.007 PARTICULATE MATTER Condensable 0.491 2.16 0.49 2.16 0.49 2.16 0.006 0.006 PARTICULATE MATTER (Filterable) 0.161 0.72 0.16 0.72 0.16 0.72 0.002 0.002 SULFUR DIOXIDE S02 0.05 0.23 0.05 0.23 0.05 0.23 0.001 0.001 NITROGEN OXIDES NOx) 8.67 37.96 8.67 37.96 8.67 37.96 0.098 0.098 CARBON MONOXIDE CO) 7.281 31.89 7.28 31.89 _ 7.28 31.89 0.082 0.082 VOLATILE ORGANIC COMPOUNDS VOC) 0.481 2.091 0.48 2.091 0.48 2.09 0.005 0.005 TOXIC ✓ HAZARDOUS AIR POLLUTANT EMISSIONS INFORMATION TOXIC I HAZARDOUS AIR POLLUTANT CAS NUMBER ACTUAL EMISSIONS POTENTIAL EMSSIONS EMISSION FACTOR (AFTERCONTROLS/LIMITS! (BEFORECONTROLS/LIMITS) (AFTERCCNTROLS/LIMITS) .IblmmBtu Ib/hr Ibs/yr Ib/hr Ibs/ Ib/hr Ibslyr uncontrolled controlled Acetaldehyde TH 75010 1.32E-06 1.15E-02 1.32E-06 1.15E-02 1.32E-06 1.15E-02 1.49E-08 1.49E-08 Acrolein TH 107028 1.56E-06 1.37E-02 1.56E-06 1.37E-02 1.56E-06 1.37E-02 1.76E-08 1.76E-08 Ammonia T 7664417 2.77E-01 2.43E+03 2.77E-01 2.43E+03 2.77E-01 2.43E+03 3.14E-03 3.14E-03 Arsenic unlisted compounds TH ASC-other 1.73E-05 1.52E-01 1.73E-05 1.52E-01 1.73E-05 1.52E-01 1.96E-07 1.96E-07 Benzene TH 71432 1.82E-04 1.59E+00 1.82E-04 1.59E+00 1.82E-04 1.59E+00 2.06E-06 2.06E-06 Benzo a rene TH 50328 1.04E-07 9.11E-04 1.04E-07 9.11E-04 1.04E-07 9.11E-04 1.18E-09 1.18E-09 Beryllium metal unreacted TH 7440417 1.04E-06 9.11E-03 1.04E-06 9.11E-03 1.04E-06 9.11E-03 1.16E-08 1.18E-08 Cadmium metal elemental unreacted TH 7440439 9.53E-05 8.35E-01 9.53E-05 8.35E-01 9.53E-05 8.35E-01 1.08E-06 1.08E-06 Chromic acid VI TH 7738945 1.21E-04 1.06E+00 1.21E-04 1.06E+00 1.21E-04 1.06E+00 1.37E-06 1.37E-06 Cobalt unlisted compounds H COG -other 7.28E-06 6.38E-02 7.28E-06 6.38E-02 7.28E-06 6.38E-02 8.24E-08 8.24E-08 Formaldehyde TH 50000 6.50E-03 5.69E+01 6.50E-03 5.69E+01 6.50E-03 5.69E+01 7.35E-05 7.35E-05 Hexane, n- TH 110543 1.56E-01 1.37E+03 1.56E-01 1.37E+03 1.56E-01 1.37E+03 1.76E-03 _ 1.76E-03 Lead unlisted compounds H PBC-other 4.33E- 55 3.80E-01 4.33E-05 3.80E-01 4.33E-05 3.80E-01 4.90E-07 4.90E-07 Manganese unlisted compounds TH MNC-other 3.29E-05 2.88E-01 3.29E-05 2.88E-01 3.29E-05 2.88E-01 . 3.73E-07 3.73E-07 Mercury vapor TH 7439976 2.25E-05 1.97E-01 2.25E-05 1.97E-01 2.25E-05 1.97E-01 2.55E-07 2.55E-07 Na thalene H 91203 5.29E-05 4.63E-01 5.29E-05 4.63E-01 5.29E-05 4.63E-01 5.98E-07 5.98E-07 Nickel metal TH 7440020 1.82E-04 1.59E+00 1.82E-04 1.59E+00 1.82E-04 1.59E+00 2.06E-96 2.06E-06 Selenium compounds H SEC 2.08E-06 1.82E-02 2.08E-06 1.82E-02 2.08E-06 1.82E-02 2.35E-08 2.35E-08 Toluene (THI) 108883 2.95E-04 2.58E+00 2.95E-04 2.58E+00 2.95E-04 2.58E+00 3.33E-06 3.33E-06 Total HAPs 1.64E-01 1.43E+03 I 1.64E-01 1.43E+03 1.64E-01 1.43E+03 1.85E-03 1.85E-03 Highest HAP Nexan I 1.56E-01 1.37E+03 I 1.56E-01 1.37E+03 1.56E-01 1.37E+03 1.76E-03 I 1.76E-03 TOXIC AIR POLLUTANT EMISSIONS INFORMATION FOR PERMITTING PURPOSES EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS EMISSION FACTOR Ib/mmBtu TOXIC AIR POLLUTANT CAS Num. Ib/hr IbIda Ib/ r uncontrolled controlled Acetaldehyde TH 75070 1.32E-06 3.16E-05 1.15E-02 1.49E-08 1.49E-08 Acrolein TH 107028 1.56E-06 3.74E-05 1.37E-02 1.76E-08 1.76E-08 Ammonia T 7664417 2.77E-01 6.66E+00 2.43E+03 3.14E-03 3.14E-03 Arsenic unlisted compounds TH ASC-other 1.73E-05 4.16E-04 1.52E-01 1.96E-07 1.96E-07 Benzene TH 71432 1.82E-04 4.37E-03 1.59E+00 2.06E-06 2.06E-06 Benzo a rene TH 50328 1.04E-07 2.50E-06 9.11E-04 1.18E-09 1.18E-09 Beryllium metal unreacted TH 7440417 1.04E-06 2.50E-05 9.11E-03 1.18E-08 1.18E-08 Cadmium metal elemental unreacted TH 7440439 9.53E-05 2.29E-03 8.35E-01 1.08E-06 1.08E-06 Soluble chromate compounds, as chromium VI a uivalent SoICR6 1.21E-04 2.91E-03 1.06E+00 1.37E-06 1.37E-06 Formaldehyde TH 50000 6.50E-03 1.56E-01 5.69E+01 7.35E-05 7.35E-05 Hexane, n- TH 110543 1.56E-01 3.74E+00 1.37E+03 1.76E-03 1.76E-03 Man anese unlisted com ounds TH MNC-other 3.29E-05 7.90E-04 2.88E-01 3.73E-07 3.73E-07 Mercur va or TH 7439976 2.25E-05 5.41E-04 1.97E-01 2.55E-07 2.55E-07 Nickel metal TH 7440020 1.82E-04 4.37E-03 1.59E+00 2.06E-06 2.06E-06 Toluene (TH) 1108883 1 2.95E-04 7.07E-03 2.58E+00 3.33E-06 3.33E-06 DEQ-CFW 00065911 1. as FORM B SPECIFIC EMISSIONS SOURCE INFORMATION (REQUIRED FOR ALL SOURCES) REVISED 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate l u l EMISSION SOURCE DESCRIPTION: Natural Gas / No. 2 fuel oil -fired boiler EMISSION SOURCE ID NO: PS-B CONTROL DEVICE ID NO(S): None OPERATING SCENARIO 2 OF 2 EMISSION POINT (STACK) ID NO(S): PEP-1 DESCRIBE IN DETAILTHE EMISSION SOURCE PROCESS (ATTACH FLOW DIAGRAM): This emission source is a natural gas / No. 2 fuel oil -fired boiler with a maximum heat input of 88.4 million Btu per hour. The purpose for this permit modification is to remove No. 6 fuel oil as an optional fuel for this boiler. This operating scenario is based on firing exclusively No. 2 fuel oil. This boiler has a PSD avoidance limit of 40 TPY S02 and 40 TPY NOx. To comply with the NOx limit, the maximum fuel oil consumption would be 3,990,000 gal/year at a 0.14% sulfur content. To comply with the S02 limit, the maximum fuel oil consumption would be 1,125,000 gal/year using fuel oil at a maximum 0.5% sulfur content. TYPE OF EMISSION SOURCE (CHECK AND COMPLETE APPROPRIATE FORM B1-B9 ON THE FOLLOWING PAGES): l� Coal,wood,oil, gas, other burner (Form 131) ❑ Woodworking (Form 64) ❑ Manufact. of chemicals/coatings/inks (Form 137) ❑ Int.combustion engine/generator (Form 62) ❑ Coating/finishing/printing (Form B5) ❑ Incineration (Form 68) ❑ Liquid storage tanks (Form 133) ❑ Storage silos/bins (Form 136) ❑ Other (Form 69) START CONSTRUCTION DATE: 1982 OPERATION DATE: Oct 1982 JDATE MANUFACTURED: 1982 MANUFACTURER / MODEL NO.: Zurn / 2-Drum I EXPECTED OP. SCHEDULE: 24 HR/DAY 7 DAY/WK 52 WK/YR IS THIS SOURCE SUBJECT TO? NSPS (SUBPART?): No NESHAP (SUBPART?): 1120) MACT (SUBPART?): 1120) PERCENTAGE ANNUAL THROUGHPUT (%): JAN-MAR 25 APR-JUN 25 JUL-SEP 25 OCT-DEC 25 EXPECTED ANNUAL HOURS OF OPERATION: -8700 IVISIBLE STACK EMISSIONS UNDER NORMAL OPERATION: -0 % OPACITY CRITERIA AIR POLLUTANT EMISSIONS INFORMATION FOR THIS SOURCE AIR POLLUTANT EMITTED SOURCE OF EMISSION FACTOR EXPECTED ACTUAL (AFTER CONTROLS/LIMITS) POTENTIAL EMISSIONS (BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS) Ib/hr T tons/yr Iblhr tons/yr Ib/hr tonslyr PARTICULATE MATTER (PM) NCDAQ 2.08 6.58 2.08 9.13 2.08 9.13 PARTICULATE MATTER<10 MICRONS (PMic) NCDAQ 2.08 6.58 2.08 9.13 2.08 9.13 PARTICULATE MATTER<2.5 MICRONS (PM2.5) NCDAQ 2,08 6.58 2.08 9.13 2.08 9.13 SULFUR DIOXIDE (S02) NCDAQ 44.83 39.94 44.83 196.36 44.83 196.36 NITROGEN OXIDES (NOx) NCDAQ 12.63 1 39.90 12.63 55.31 12.63 55.31 CARBON MONOXIDE (CO) NCDAQ 3.16 9.98 3.16 13.83 3.16 13.83 VOLATILE ORGANIC COMPOUNDS (VOC) NCDAQ 0.13 0.40 0.13 0.55 0.13 0.55 LEAD NCDAQ 0.0008 5.03 0.0008 6.97 0.0008 6.97 OTHER NCDAQ 0 0 0 0 0 0 HAZARDOUS AIR POLLUTANT EMISSIONS INFORMATION FOR THIS SOURCE HAZARDOUS AIR POLLUTANT AND CAS NUMBER SOURCE OF EMISSION FACTOR EXPECTED ACTUAL (AFTER CONTROLS/LIMITS) POTENTIAL EMISSIONS (BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS) Ib/hr tons/yr Ib/hr tons/yr Ib/hr tons/yr See attached NCDAQ "Fuel Oil Combustion Emissions Calculator" TOXIC AIR POLLUTANT EMISSIONS INFORMATION FOR THIS SOURCE INDICATE EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS TOXIC AIR POLLUTANT AND CAS NO. EF SOURCE Ib/hr lb/day Ib/yr See attached NCDAQ "Fuel Oil Combustion Emissions Calculator" Attachments: (1) emissions calculations and supporting documentation; (2) indicate all requested state and federal enforceable permit limits (e.g. hours of operation, emission rates) and describe how these are monitored and with what frequency; and (3) describe any monitoring devices, gauges, or test ports for this source. COMPLETE THIS FORM AND COMPLETE AND ATTACH APPROPRIATE B1 THROUGH B9 FORM FOR EACH SOURCE Attach Additional Sheets As Necessary DEQ-CFW 00065912 I Il V Instructions: Enter emission source / facility data on the "INPUT" tab/screen. The air emission results and summary of input ATT� data are viewed / printed on the "OUTPUT" tab/screen. The different tabs are on the bottom of this screen. AW This spreadsheet is for your use only and should be used with caution. DENR does not guarantee the accuracy of the information contained. This spreadsheet', subject to continual revision and updating. It is your responsibility to be aware of the most current information available. DENR is not responsible for errors or NCDENw omissions that may be contained herein. SOURCE/FACILITY/USER INPUT SUMMARY FROM INPUT SCREEN' COMPANY: DuPont Company - Fayetteville Works MAX HEAT INPUT:. 88.40 MMBTU/HR FACILITY ID NO.: 900009 FUEL HEAT VALUE: 140,000 BTU/GAL PERMIT NUMBER: 03735T37 HHV for GHG CALCULATIONS: 0.138 mm BTU/GAL FACILITY CITY: Fayetteville ACTUAL ANNUAL FUEL USAGE: 3,990,000 GAL/YR FACILITY COUNTY: Bladen MAXIMUM ANNUAL FUEL USAGE: 5,531,314 GAL/YR USER NAME: Michael E. Johnson MAXIMUM SULFUR CONTENT: 0.1 % EMISSION SOURCE DESCRIPTION: No. 2 oil -fired Boiler REQUESTEDPERMIT' LIMITATIONS EMISSION SOURCE ID NO.: PS-B MAX. FUEL USAGE: 3,990,000 GAL/YR MAX. SULFUR CONTENT: 0.5 % TYPE OF CONTROL DEVICES POLLUTANT CONTROL EFF. NONE/OTHER PM 0 NONE/OTHER S02 0 NONE/OTHER NOx 0 METHOD USED TO COMPUTE ACTUAL GHG EMISSIONS: TIER 1: DEFAULT HIGH HEAT VALUE AND DEFAULT EF CARBON CONTENT USED FOR GHGS (kg C/gal): CARBON CONTENT NOT USED FOR CALCULATION TIER CHOSEN CRITERIA AIR POLLUTANT EMISSIONS INFORMATION AIR POLLUTANT EMITTED ACTUAL EMISSIONS (AFTER CONTROLS/LIMITS) POTENTIAL EMSSIONS (BEFORE CONTROLS LIMITS) (AFTER CONTROLS/LIMITS) EMISSION FACTOR (16/103 gal) Whir tons/yr Whir tons/yr Ib/hr tons/yr uncontrolled controlled TOTAL PARTICULATE MATTER (PM) FPM+CPM) 2.08 6.58 2.08 9.13 1.50 6.58 3.30E+00 3.30E+00 FILTERABLE PM (FPM) 1.26 3.99 1.26 5.53 0.91 3.99 2.00E+00 2.00E+00 CONDENSABLE PM (CPM) 0.82 2.59 0.82 3.60 0.59 2.59 1.30E+00 1.30E+00 FILTERABLE PM<10 MICRONS (PMIo) 0.63 2.00 0.63 2.77 0.46 2.00 1.00E+00 1.00E+00 FILTERABLE PM<2.5 MICRONS (PM2.5) 0.16 0.50 0.16 0.69 0.11 0.50 2.50E-01 2.50E-01 SULFUR DIOXIDE (SO,) 12.55 39.66 12.55 54.98 32.34 141.65 1.99E+01 1.99E+01 NITROGEN OXIDES (NOX) 12.63 39.90 12.63 55.31 9.11 39.90 2.00E+01 2.00E+01 CARBON MONOXIDE CO 3.16 9.98 3.16 13.83 2.28 9.98 5.00E+00 5.00E+00 VOLATILE ORGANIC COMPOUNDS VOC 0.13 0.40 0.13 0.55 0.09 0.40 2.00E-01 2.00E-01 LEAD 0.00 0.00 0.00 0.00 0.00 0.00 1.26E-03 1.26E-03 f. , . �... T,OXIG�/dH/ffi�4'RD"OU,5iA7R�f3;0 LCI :' TiPMIS'S"f_ONS�IVF RIN�I�iff TOXIC / HAZARDOUS AIR POLLUTANT CAS NUMBER ACTUAL EMISSIONS (AFTER CONTROLS/LIMITS) POTENTIAL EMSSIONS (BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS) EMISSION FACTOR (Ib/103 gal) Iblhr Ib/yr Ib/hr Ib/yr Ib/hr Ib/yr uncontrolled controlled Antimony&compounds (H) SBC 0.0E+00 0.0E+00 0.0E+00 O.oE+00 0.0E+00 0.0E+00 0.00E+00 0.00E+00 Arsenic &compounds (TH) ASC 3.5E-04 2.2E+00 3.5E-04 3.1E+00 2.6E-04 2.2E+00 5.60E-04 5.60E-04 Benzene (TH) 71432 1.7E-03 1.1E+01 1.7E-03 1.5E+01 1.3E-03 1.1E+01 2.75E-03 2.75E-03 Beryllium & compounds (H) BEC 2.7E-04 1.7E+00 2.7E-04 2.3E+00 1.9E-04 1.7E+00 4.20E-04 4.20E-04 Cadium&compounds (TH) CDC 2.7E-04 1.7E+00 2.7E-04 2.3E+00 1.9E-04 1.7E+00 4.20E-04 4.20E-04 chromium-All/Total (H) CRC 2.7E-04 1.7E+00 2.7E-04 2.3E+00 1.9E-04 1.7E+00 4.20E-04 4.20E-04 Cobalt compounds (H) COC 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.00E+00 0.00E+00 Ethylbenzene (H) 100414 5.2E-04 3.3E+00 5.2E-04 4.5E+00 3.7E-04 3.3E+00 8.17E-04 8.17E-04 Fluorides (sum fluoride compounds) IT) Formaldehyde (TH) 16984488 50000 2.4E-02 3.0E-02 1.5E+02 1.9E+02 2.4E-02 3.0E-02 2.1 E+02 2.7E+02 1.7E-02 2.2E-02 1.5E+02 1.9E+02 3.73E-02 4.80E-02 3.73E-02 4.80E-02 Lead and Lead compounds (H) PBC 8.0E-04 5.0E+00 8.0E-04 7.0E+00 5.7E-04 5.0E+00 1.26E-03 1.26E-03 Manganese & compounds (TH) Mercury & compounds (TH) Methyl chloroform (TH) MNC HGC 71566 5.3E-04 2.7E-04 1.5E-04 3.4E+00 1.7E+00 9.4E-01 5.3E-04 2.7E-04 1.5E-04 4.6E+00 2.3E+00 1.3E+00 3.8E-04 1.9E-04 1.1E-04 3.4E+00 1.7E+00 9.4E-01 8.40E-04 4.20E-04 2.36E-04 8.40E-04 4.20E-04 2.36E-04 Napthalene (H) Nickle & compounds (H) 91203 NIC 2.1E-04 2.7E-04 1.3E+00 1.7E+00 2.1E-04 2.7E-04 1.8E+00 2.3E+00 1.5E-04 1.9E-04 1.3E+00 1.7E+00 3.33E-04 4.20E-04 3.33E-04 4.20E-04 Phosphorus Metal, Yellow or White (H) POM rates uncontrolled (H) 7723140 POM 0.0E+00 2.1E-03 0.0E+00 1.3E+01 0.0E+00 2.1E-03 0.0E+00 1.8E+01 0.0E+00 1.5E-03 0.0E+00 1.3E+01 0.00E+00 3.30E-03 0.00E+00 3.30E-03 Selenium compounds (H) SEC 1.3E-03 8.4E+00 1.3E-03 1.2E+01 9.6E-04 8.4E+00 2.10E-03 2.10E-03 Toluene (TH) 108883 5.0E-02 3.2E+02 5.0E-02 4.4E+02 3.6E-02 3.2E+02 7.97E-02 7.97E-02 Xylene (TH) 1330207 8.8E-04 5.6E+00 8.8E-04 7.7E+00 6.4E-04 5.6E+00 1.40E-03 1.40E-03 Total HAP (H) 9.1E-02 5.7E+02 9.1E-02 7.9E+02 6.5E-02 1 14E-01 14E-01 Larget HAP TOJ[IG?AIRtP.OVEU.TAN,TdEMISSCOJiCSill�IFORIN I7LOMF0 2iP,ERM1[nJli[GIPLJRP.OSESi 4.41+02 3.63E-02503E02 35.87E+02 E+ 7.97E-02 7.97E-02 EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS EMISSION FACTOR (Ib1103 gal) TOXIC AIR POLLUTANT CAS Num. Ib/hr lb/day Ib/yr uncontrolled controlled Arsenic & compounds (TH) ASC 2.55E-04 6.12E-03 2.23E+00 5.60E-04 5.60E-04 Benzene (TH) 71432 1.25E-03 3.01E-02 1.10E+01 2.75E-03 2.75E-03 Cadium & compounds (TH) CDC 1.91E-04 4.59E-03 1.68E+00 4.20E-04 4.20E-04 Fluorides (sum fluoride compounds) IT) 16984488 1.70E-02 4.08E-01 1.49E+02 3.73E-02 3,73E-02 Formaldehyde (TH) 50000 2.19E-02 5.25E-01 1.92E+02 4.80E-02 4.80E-02 Manganese & compounds (TH) MNC 3.83E-04 9.18E-03 3.35E+00 8.40E-04 8.40E-04 Mercury & compounds (TH) HGC 1.91E-04 4.59E-03 1.68E+00 4.20E-04 4.20E-04 Methyl chloroform (TH) 71566 1.07E-04 2.58E-03 9.42E-01 2.36E-04 2.36E-04 Toluene (TH) 10SlI. 3.63E-02 8.71E-01 3.18E+02 7.97E-02 7.97E-02 Xylene (TH) 1330207 6.38E-04 1.53E-02 5.59E+00 1.40E-03 1.40E-03 DEQ-CFW 00065913 ' FORM B1 RF\/EMISSIONS SOURCEISED 12!01!01 D'('WOOD -qion of Air oCOAL, O L, GASon for H'OT OTHEt to R FUEL -FIRED BURNERerate B1 EMISSION SOURCE DESCRIPTION: Natural Gas / No. 2 fuel oil -fired boiler EMISSION SOURCE ID NO: PS -A CONTROL DEVICE ID NO(S): None OPERATING SCENARIO 1 OF 2 EMISSION POINT (STACK) ID NO(S): PEP-1 DESCRIBE USE: N PROCESS HEAT ❑ SPACE HEAT ❑ ELECTRICAL GENERATION ❑ CONTINUOUS USE ❑ STANDBY/EMERGENCY ❑ OTHER (DESCRIBE) HEATING MECHANISM: ❑x INDIRECT ❑ DIRECT MAX. FIRING RATE (MMBTU/HR): 139.4 .WOOD -FIRED BURNER WOOD TYPE: ❑ BARK ❑ WOOD/BARK ❑ WET WOOD ❑ DRY WOOD ❑ OTHER (DESCRIBE) PERCENT MOISTURE OF FUEL: N/A ❑ UNCONTROLLED ❑ CONTROLLED WITH FLYASH REINJECTION ❑ CONTROLLED W/O REINJECTION FUEL FEED METHOD: N/A HEAT TRANSFER MEDIA: ❑ STEAM ❑ AIR ❑ OTHER METHOD OF TUBE CLEANING: N/A CLEANING SCHEDULE: N/A COAL-FIRED BURNER TYPE OF BOILER N/A IF OTHER DESCRIBE: PULVERIZED ❑ WET BED ❑ DRY BED OVERFEED STOKER ❑ UNCONTROLLED ❑ CONTROLLED UNDERFEED STOKER ❑ UNCONTROLLED ❑ CONTROLLED SPREADER STOKER ❑ UNCONTROLLED ❑ FLYASH REINJECTION ❑ NO FLYASH REINJECTION FLUIDIZED BED ❑ CIRCULATING ❑ RECIRCULATING METHOD OF LOADING: ❑ CYCLONE ❑ HANDFIRED ❑ TRAVELING GRATE ❑ OTHER (DESCRIBE) METHOD OF TUBE CLEANING: N/A CLEANING SCHEDULE: N/A -OIL/GAS-FIRED BURNER TYPE OF BOILER: ❑ UTILITY 9 INDUSTRIAL ❑ COMMERCIAL ❑ RESIDENTIAL TYPE OF FIRING: Normal TYPE OF CONTROL (IF ANY): None FUEL FEED METHOD: Pressure feed METHOD OF TUBE CLEANING: Tube blowing I CLEANING SCHEDULE: As needed OTHER FUEL -FIRED BURNER TYPE OF FUEL: N/A PERCENT MOISTURE: TYPE OF BOILER: ❑ UTILITY ❑ INDUSTRIAL ❑ COMMERCIAL ❑ RESIDENTIAL TYPE OF FIRING TYPE OF CONTROL (IF FUEL FEED METHOD: METHOD OF TUBE CLEANING: CLEANING SCHEDULE: FUEL USAGE INCLUDE STARTUP/BACKUP FUELS) FUEL TYPE UNITS MAXIMUM DESIGN CAPACITY (UNIT/HR) REQUESTED CAPACITY LIMITATION (UNITIHR) Natural Gas Std. cubic feet 136,667 136,667 No. 2 Fuel Oil gallons 995 995 FUEL CHARACTERISTICS COMPLETE ALL THATARE APPLICABLE FUEL TYPE SPECIFIC BTU CONTENT SULFUR CONTENT (% BY WEIGHT) ASH CONTENT (% BY WEIGHT) Natural Gas 1020 BTU/SCF 0.00003 Negligible No. 2 Fuel Oil 140,000 BTU/gal less than 0.5 Negligible SAMPLING PORTS, COMPLIANT WITH EPA METHOD 1 WILL BE INSTALLED ON THE STACKS: ❑ YES 0 NO COMMENTS: Attach Additional Sheets As Necessary DEQ-CFW 00065914 FORM B1 EMISSIONS SOURCE (WOOD, COAL, OIL, GAS, OTHER FUEL -FIRED BURNER) REVISED 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate r B'I EMISSION SOURCE DESCRIPTION: Natural Gas / No. 2 fuel oil -fired boiler EMISSION SOURCE ID NO: PS-B CONTROL DEVICE ID NO(S): None OPERATING SCENARIO 1 OF 2 EMISSION POINT (STACK) ID NO(S): PEP-1 DESCRIBE USE: ❑X PROCESS HEAT ❑ SPACE HEAT ❑ ELECTRICAL GENERATION ❑ CONTINUOUS USE ❑ STANDBY/EMERGENCY ❑ OTHER (DESCRIBE) HEATING MECHANISM: 0 INDIRECT ❑ DIRECT MAX. FIRING RATE (MMBTU/HR): 139.4 WOOD -FIRED BURNER WOOD TYPE: ❑ BARK ❑ WOOD/BARK ❑ WET WOOD ❑ DRY WOOD ❑ OTHER (DESCRIBE) PERCENT MOISTURE OF FUEL: N/A ❑ UNCONTROLLED ❑ CONTROLLED WITH FLYASH REINJECTION ❑ CONTROLLED W/O REINJECTION FUEL FEED METHOD: N/A HEAT TRANSFER MEDIA: ❑ STEAM ❑ AIR ❑ OTHER METHOD OF TUBE CLEANING: N/A CLEANING SCHEDULE: N/A COAL-FIRED BURNER TYPE OF BOILER N/A IF OTHER DESCRIBE: PULVERIZED ❑ WET BED ❑ DRY BED OVERFEED STOKER ❑ UNCONTROLLED ❑ CONTROLLED UNDERFEED STOKER ❑ UNCONTROLLED ❑ CONTROLLED SPREADER STOKER ❑ UNCONTROLLED ❑ FLYASH REINJECTION ❑ NO FLYASH REINJECTION FLUIDIZED BED ❑ CIRCULATING ❑ RECIRCULATING METHOD OF LOADING: ❑ CYCLONE ❑ HANDFIRED ❑ TRAVELING GRATE ❑ OTHER (DESCRIBE) METHOD OF TUBE CLEANING: N/A CLEANING SCHEDULE: N/A OIL/GAS-FIRED "BURNER:" TYPE OF BOILER: ❑ UTILITY N INDUSTRIAL ❑ COMMERCIAL ❑ RESIDENTIAL TYPE OF FIRING: Normal TYPE OF CONTROL (IF ANY): None FUEL FEED METHOD: Pressure feed METHOD OF TUBE CLEANING: Tube blowing CLEANING SCHEDULE: As needed OTHER FUEL=FIRED'BURNER TYPE OF FUEL: N/A PERCENT MOISTURE: TYPE OF BOILER: ❑ UTILITY ❑ INDUSTRIAL ❑ COMMERCIAL ❑ RESIDENTIAL TYPE OF FIRING TYPE OF CONTROL (IF FUEL FEED METHOD: METHOD OF TUBE CLEANING:. CLEANING SCHEDULE: FUEL USAGE INCLUDE; START UP/BACKUP: FUELS' FUEL TYPE UNITS MAXIMUM DESIGN CAPACITY (UNIT/HR) REQUESTED CAPACITY LIMITATION (UNIT/HR) Natural Gas Std. cubic feet 86,667 86,667 No. 2 Fuel Oil gallons 631 631 FUEL CHARACTERISTICS' COMPLETE ALL THAT-AREAP,PLICABLE ,..:<` FUEL TYPE SPECIFIC BTU CONTENT SULFUR CONTENT (% BY WEIGHT) ASH CONTENT (% BY WEIGHT) Natural Gas 1020 BTU/SCF 0.00003 Negligible No. 2 Fuel Oil 140,000 BTU/gal less than 0.5 Negligible SAMPLING PORTS, COMPLIANT WITH EPA METHOD 1 WILL BE INSTALLED ON THE STACKS: ❑ YES I] NO COMMENTS: This source has a PSD avoidance limit of 40 TPT S02 and 40 TPY Nox. To comply with these limits, the No. 2 fuel consumption is limited to 3,990,000 gal/yr with a maximum concentration of 0.14% sulfur and/or 1,125,000 gal/yr with a maximum concentration of 0.5% sulfur. Attach Additional Sheets As Necessary DEQ-CFW 00065915 4 e } FORM D1 FACILITY -WIDE EMISSIONS SUMMARY o❑xnccn , oini mi ivrnFNRmivisinn of Air Oualitv - Anolication for Air Permit to Construct/Operate D1 CRITERIA AIR-P.OLLUTANTEMI$SIONS,INFORMATIQN,,FAGILITY=WIDE, EXPECTED ACTUAL EMISSIONS POTENTIAL EMISSIONS POTENTIAL EMISSIONS (AFTER CONTROLS / (BEFORE CONTROLS / (AFTER CONTROLS / LIMITATIONS) LIMITATIONS) LIMITATIONS) AIR POLLUTANT EMITTED tons/yr tons/yr tons/yr Unchanged (site is Unchanged (site is PARTICULATE MATTER (PM) — 50 Major Source) Major Source) Unchanged (site is Unchanged (site is PARTICULATE MATTER < 10 MICRONS (PM10) — 50 Major Source) Major Source) Unchanged (site is Unchanged (site is PARTICULATE MATTER <2.5 MICRONS (PM2.5) ^- 50 Major Source) Major Source) Unchanged (site is Unchanged (site is SULFUR DIOXIDE (S02) — 600 Major Source) Major Source) Unchanged (site is Unchanged (site is NITROGEN OXIDES (NOx) — 100 Major Source) Major Source) Unchanged (site is Unchanged (site is CARBON MONOXIDE (CO) — 15 Major Source) Major Source) Unchanged (site is Unchanged (site is VOLATILE ORGANIC COMPOUNDS (VOC) — 215 Major Source) Major Source) LEAD < 0.006 OTHER HAZARDOUS AIR POLLUTANT. EMISSIONS:INFORMATION =FACILITY -WIDE ' EXPECTED ACTUAL EMISSIONS POTENTIAL EMISSIONS POTENTIAL EMISSIONS (AFTER CONTROLS / (BEFORE CONTROLS / (AFTER CONTROLS / LIMITATIONS) LIMITATIONS) LIMITATIONS) HAZARDOUS AIR POLLUTANT EMITTED CAS NO. tons/yr tons/yr tons/yr >25 (site is Major >26 (site is Major Total HAPs >25 (site is Major Source) 1 Source) Source) TOXIC AIR POLLUTANT EMISSIONS INFORMATION -'FACILITY-WIDE INDICATE REQUESTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS. EMISSIONS ABOVE THE TOXIC PERMIT EMISSION RATE (TPER) IN 15A NCAC 2Q .0711 MAY REQUIRE AIR DISPERSION MODELING. USE NETTING FORM D2 IF NECESSARY. Modeling Required ? TOXIC AIR POLLUTANT EMITTED CAS NO. Ib/hr lb/day lb/year Yes No No additional TAPs will be emitted as X a result of this modification. COMMENTS: As indicated above, the site is a major source for criteria pollutants and HAPs. The current and post -modification operation of Boilers No. 1 (ID No.. PS -A) and No. 2 (ID No. PS-B) does not change any of the current classifications. With the elimiation of No. 6 fuel oil as a fuel option, the potential emissions from the site boilers (ID Nos. PS -A, PS-B, PS-C, and PS -Temp) decreases to 606.1 TPY S02. Compared to the PSD avoidance limit of 702.6 TPY S02 for these sources is a net reduction of 97.4 TPY S02. Attach Additional Sheets as Necessary DEQ-CFW 00065916 FORM D2 AIR POLLUTANT NETTING WORKSHEET oe.,;.4611)mi mi NcnFNR/nivision of Air Qualitv - Aoolication for Air Permit to Construct/operate FD2 PURPOSE OF NETTING: ❑ AIR TOXICS ❑ PSD (100/250 tons per year) ❑ PSD SIGNIFICANT LEVELS AIR POLLUTANT: None CAS NO.: EMISSION SOURCE ID NOS.: SECTION A- EMISSION OFFSETTING ANALYSIS.FOR.MODIFIED/NEW..SOURCES Summarize m this'sechon usingahe B forms EMISSIONS - USE APPROPRIATE COLUMNS ONLY LBNEAR LB/DAY LB/HR MODIFICATION INCREASE - MINUS - - MINUS - MINUS - - MINUS - MODIFICATION DECREASE = EQUALS = = EQUALS = = EQUALS = = EQUALS = NET CHANGE FROM MODIFICATION SECTION B - FACILITY -WIDE EMISSION NETTINGANALYSIS CREDITABLE INCREASE - MINUS - - MINUS - MINUS - - MINUS - CREDITABLE DECREASE = EQUALS = = EQUALS = = EQUALS = = EQUALS = NET CREDITABLE CHANGE SECTION C -. FACILITY.WIDE, EMISSIONS TOTAL FACILITY EMISSIONS TPER LEVELS (2Q .0711) CHECK HERE IF AN AIR DISPERSION MODELING ANALYSIS IS REQUIRED ❑ COMMENTS: The requested modification to eliminate No. 6 fuel oil as a fuel option for the site boilers (ID Nos. PS -A and PS-B) would not result in an increase of any pollutant. The modification would result in a reduction of 97.4 TPY of potential S02 emissions. Attach Additional Sheets As Necessary DEQ-CFW 00065917 FORM D4 EXEMPT AND INSIGNIFICANT ACTIVITIES SUMMARY 1'Y. A.1/AA /Ad klf%r%CKI ,..,::.,- -f Air M—Hh, - Anniientinn fnr Air Parmit to Construct/Onerate D4 ACTI�%ITIES EXETE PER 2Q .002 ®RMR ITh.rf' i I,NSIG.NIFICANT ACTIUITIES1PER2Q FORTITLE VS�®UR�CS a®50;3 SIZE OR PRODUCTION BASIS FOR EXEMPTION OR DESCRIPTION OF EMISSION SOURCE RATE INSIGNIFICANT ACTIVITY 1.1 Per vendor information, the duel filters' Less than five total particle removal efficiency is tons of 99.995%. Captured solids are less than ID No. I-01A : Polyvinyl Fluoride Process ID particulate per 1200 lb/month. Therefore particulate 1 house vacuum system year emissions are estimated as less than 1 Ib/yr. 2. Per vendor information, the duel filters' Less than five total particle removal efficiency is tons of 99.995%. Captured solids are less than ID No. 1-01 B : Polyvinyl Fluoride Process particulate per 1200 lb/month. Therefore particulate No. 2 house vacuum system year emissions are estimated as less than 1 lb/yr. 3. 4. 5. 6. 7. 8. Attach Additional Sheet As Necessary DEQ-CFW 00065918 FORM E1 TITLE V GENERAL INFORMATION ocviecn• 41)MI ma nivisinn of Air Oijality - Annlication for Air Permit to construct/Operate E1 IF YOUR FACILITY IS ..CLASSIFIED A_S "MAJOR" FOR TITLE VYOU MUST COMPLETE THtS FORM"AND ALL OTHER,REQUIRED "E" FORMS�(E2RTHROUGH;ES AS APPLICABLE ) Indicate here if your facility is subject to Title V by: Emissions ❑ Other If subject to Title V by other, check or specify: ❑ NSPS ❑ NESHAPS (MACT) ❑ TITLE IV Other, specify: If you are or will be subject to any maximum achievable control technology standards (MACT) issued pursuant to section 112(d) of the Clean Air Act, specify below: EMISSION SOURCE EMISSION SOURCE ID DESCRIPTION MACT Throughout "MON MACT" Facility Facility Wide (40 CFR Part 63 Subpart FFFF) PS -A, PS-B, Natural Gas I No. 2 fuel oil- CAA § 1120); Case -by -Case MACT for PS-C, PS -Temp fired boilers Boilers & Process Heaters List any additional regulation which are requested to be included in the shield and provide a detailed explanation as to why the shield should be granted: REGULATION EMISSION SOURCE (Include ID) EXPLANATION Comments: Attach Aaaltlonal Jneeis As Necessary DEQ-CFW 00065919 FORM E2 EMISSION SOURCE APPLICABLE REGULATION LISTING REVICFr1 19/f Division of Air Qualitv - Anolication for Air Permit to Construct/Operate I E2 EMISSION EMISSION OPERATING SCENARIO SOURCE SOURCE INDICATE PRIMARY (P) APPLICABLE ID NO. DESCRIPTION OR ALTERNATIVE (A) POLLUTANT REGULATION ES 1 Coal/Wood Boiler P -Coal PM NCAC'2D .0503 A - Wood PM NCAC`2D .0504 PS -A NCAC NCAC 2D .0503 PS-B Natural Gas / No. 2 P - Natural gas PM Particulates from fuel burning PS -Temp fuel oil -fired boilers A - No. 2 fuel oil indirect heat exchangers NCAC NCAC 2D .0516 PS -A Natural Gas / No. 2 P - Natural gas S02 Sulfur dioxide emissions from PS-B fuel oil -fired boilers A - No. 2 fuel oil combustion sources PS -A Natural Gas / No. 2 P - Natural gas VE NCAC NCAC 2D .0521 PS-B fuel oil -fired boilers A - No. 2 fuel oil Control of visible emissions NCAC 2Q.0317 PS-B Natural Gas / No. 2 P -Natural gas NOx Avoidance conditions for fuel oil -fired boiler A - No. 2 fuel oil 15A NCAC 2D.0530 NCAC 7 PS-B Natural Gas / No. 2 P - Natural gas S02 Avoidanncece conditions for PS -Temp fuel oil -fired boiler A - No. 2 fuel oil 15A NCAC 2D.0531 PS -A Natural Gas / No. 2 P - Natural gas HAP NCAC 2D .1109 PS-B fuel oil -fired boilers A - No. 2 fuel oil Case -by -case MACT PS -Temp Natural Gas / No. 2 P - Natural gas VE NCAC 2D .0524 PS -Temp fuel oil -fired boiler A - No. 2 fuel oil S02 NSPS 40 CFR 60, Subpart Dc Attach Additional Sheets As Necessary DEQ-CFW 00065920 FORM E3 EMISSION SOURCE COMPLIANCE METHOD pc%neGn i9mj mj NrnFNRinivwnn of Air Qualitv - Application for Air Permit to Construct/Operate E3 Regulated Pollutant S02 Emission Source ID NO. PS -A, PS-B, PS -Temp Applicable Regulation NCAC 2D.0516, 2D.0524, 2Q.0317 Alternative Operating Scenario (AOS) NO: 2 ATTACH A SEPARATE PAGE TO EXPAND ON ANY OF THE BELOW COMMENTS - MONITORING.REQUIREMENTS> Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes M No If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes 0 No Describe Monitoring Device Type: Not applicable Describe Monitoring Location: Not applicable Other Monitoring Methods (Describe In Detail): Not applicable Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous readings taken to produce an hourly average): RECORDKEEPING REQUIREMENTS , Data (Parameter) being recording: NO. 2 fuel oil consumption and sulfur content Frequency of recordkeeping (How often is data recorded?): Monthly REPORTING REQUIREMENTS Generally describe what is being reported: Monthly S02 emissions will be determined monthly and will be reported to N.C. Division of Air Quality every six months. Frequency:_ ❑ MONTHLY ❑ QUARTERLY ❑X EVERY 6 MONTHS ❑ OTHER (DESCRIBE): TESTING Specify proposed reference test method: Not applicable Specify reference test method rule and citation: Not applicable Specify testing frequency: Not applicable NOTE - Proposed test method subject to approval and possible change during the test protocol process Attach Additional Sheets As Necessary DEQ-CFW 00065921 _1 0, FORM E3 EMISSION SOURCE COMPLIANCE METHOD oC%necn ,)/n, ml NrnFmRinivisinn Of Air Oualitv - Aoolication for Air Permit to Construct/Operate E3 Regulated Pollutant Particulate matter Emission Source ID NO. PS -A, PS-B, PS -Temp Applicable Regulation NCAC 2D.0503 Alternative Operating Scenario (AOS) NO: 2 ATTACH A SEPARATE PAGE TO EXPAND ON ANY OF THE BELOW COMMENTS MONITORINGREQUIREMENTS. Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes No If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes No Describe Monitoring Device Type: Not applicable Describe Monitoring Location: Not applicable Other Monitoring Methods (Describe In Detail): Not applicable _ Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous readings taken to produce an hourly average): RECORDKEEPING REQUIREMENTS Data (Parameter) being recording: None Frequency of recordkeeping (How often is data recorded?): Not applicable REPORTING REQUIREMENTS Generally describe what is being reported: Natural gas and No. 2 fuel oil burning cannot exceed the particulate matter emission rate stated in the current permit Frequency: ❑ MONTHLY ❑ QUARTERLY ❑ EVERY 6 MONTHS ❑ OTHER (DESCRIBE): TESTING Specify proposed reference test method: Not applicable Specify reference test method rule and citation: Not applicable Specify testing frequency: Not applicable NOTE - Proposed test method subject to approval and possible change during the test protocol process Attach Additional Sheets As Necessary DEQ-CFW 00065922 FORM E3 EMISSION SOURCE COMPLIANCE METHOD ,o,n„n, urnGniamiw!ainn of Air (Ninlity - Annliration for Air Permit to Construct/Overate E3 Regulated Pollutant Visible Emissions Emission Source ID NO. PS -A, PS-B, PS -Temp Applicable Regulation NCAC 21111.0521 Alternative Operating Scenario (AOS) NO: 2 ATTACH A SEPARATE PAGE TO EXPAND ON ANY OF THE BELOW COMMENTS MONITORING REQUIREMENTS Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes No If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes No Describe Monitoring Device Type: Not applicable Describe Monitoring Location: Not applicable Other Monitoring Methods (Describe In Detail): Not applicable Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous readings taken to produce an hourly average): RECORDKEEPING REQUIREMENTS Data (Parameter) being recording: Norte Frequency of recordkeeping (How often is data recorded?): Not applicable REPORTING REQUIREMENTS Generally describe what is being reported: Natural gas and No. 2 fuel oil burning would not be expected to result in any visible emissions Frequency: ❑ MONTHLY ❑ QUARTERLY ❑ EVERY 6 MONTHS ❑ OTHER (DESCRIBE): TESTING Specify proposed reference test method: Not applicable Specify reference test method rule and citation: Not applicable Specify testing frequency: Not applicable NOTE - Proposed test method subject to approval and possible change during the test protocol process Attach Additional Sheets As Necessary DEQ-CFW 00065923 FORM E4 EMISSION SOURCE COMPLIANCE SCHEDULE Revised 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate E4 COMPLIANCE STATUS WITH RESPECT TO ALL APPLICABLE REQUIREMENTS Will each emission source at your facility be in compliance with all applicable requirements at the time of permit issuance and continue to comply with these requirements? FRI Yes ❑ No If NO, complete A through F below for each requirement for which compliance is not achieved. Will your facility be in compliance with all applicable requirements taking effect during the term of the permit and meet such requirements on a timely basis? (] Yes ❑ No If NO, complete A through F below for each requirement for which compliance is not achieved. If this application is for a modification of existing emissions source(s), is each emission source currently in compliance with all applicable requirements? 0 Yes ❑ No If NO, complete A through F below for each requirement for which compliance is not achieved. A. Emission Source Description (Include ID NO.) B. Identify applicable requirement for which compliance is not achieved: C. Narrative description of how compliance will be achieved with this applicable requirements: D. Detailed Schedule of Compliance: Ste s Date Expected E. Frequency for submittal of progress reports (6 month minimum): Not applicable F. Starting date of submittal of progress reports: Not applicable Attach Additional Sheets As Necessary DEQ-CFW 00065924 FORM E5 TITLE V COMPLIANCE CERTIFICATION (Required) Revised 01/01/07 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate I E5 In accordance with the provisions of Title 15A NCAC 2Q .0520 and .0515(b)(4), the responsible company official of.• SITE NAME: DuPont Company - Fayetteville Works SITE ADDRESS: 22828 NC Highway 87 W CITY, NC: Fayetteville, NC 28306-7332 COUNTY: Bladen PERMIT NUMBER: 03735T37 CERTIFIES THAT (Check the appropriate statement): FX-1 The facility is in compliance with all applicable requirements ❑ In accordance with the provisions of Title 15A NCAC 2Q .0515(b)(4) the responsible company official certififies that the proposed minor modification meets the criteria for using the procedures set out in 2Q .0515 and requests that these procedures be used to process the permit application. ❑ The facility is not currently in compliance with all applicable requirements If this box is checked, you must also complete form E4 Emission Source Compliance Schedule" The undersigned certifies under the penalty of law, that all information and statements provided in the application, based on information and belief formed after reasonable inquiry, are true, accurate, and complete. � I /11d f� Date: {.b ).3 10.Signature of responsib a comptofficial (R UIRED, 1= BLUE INK) Ellis H. McGaughy, Plant Manager Name, Title of responsible company official (Type or print) Attach Additional Sheets As Necessary DEQ-CFW 00065925