HomeMy WebLinkAboutDEQ-CFW_00064543DuPont Automotive
P.O. Drawer Z
Fayetteville, NC 28302
aUPONT
DuPont Automotive
r
DUPONT - FAYETTEVILLE WORKS
RENEWAL APPLICATION
FOR
NPDES PERMIT - NC0003573
`DEC 05
ENV, Mp,�&Ac�r-:mr T
VAYETTEVILLE REG- q F-iCp-
NOVEMBER 29, 1995
E. I. du Pont de Nemours and Company ® Printed on Recycled Paper
FF-9522 Rev 5/93
DEQ-CFW 00064543
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NORTH CAROLINA DEPT. OF ENVIRONMENT, HEALTH, AND NATURAL RESOURCES
ENVIRONMENTAL MANAGEMENT COMMISSION
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM
APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER
STANDARD FORM C - MANUFACTURING AND COMMERCIAL
SECTION 1. APPLICATION AND FACILITY DESCRIPTION
Unless otherwise specified on this form all Items are to be completed. it an item is not applicable Indicate 'PIA'.
ADDITIONAL INSTRUCTIONS FOR SELECTED ITEMS APPEAR IN SEPARATE INSTRUCTION BOOKLET AS INDICATED, REFER TO BOOKLET
BEFORE FILLING OUT THESE ITEMS.
1. Legal Name of Applicant
(see instructions)
2 Mailing Address of Applicant
(see Instructions)
Number& Street
City
State
Zip Code
3. Applicant's Authorized Agent
(see Instructions)
Name and Title
Number & Street
Ci ty
State
Zip Code
Telephone
4. Previous Application
If a previous application for a
permit under the National
Pollutant Discharge Elimination
System has been made, give
the date of application.
Niel
•cL1
X.
Please Print or Type
E. I. DUPONT DE NEMOURS & CO., INC.
FAYETTEVILLE WORKS
P. 0. DRAWER Z
FAYETTEVILLE
NC
29102
Michael E. Johnson
Environmental Coordinator /
P _ t) Drawpr 7.
Fayetteville
NC
28302
910 678-1155
Area Number
Code
90 11 28
YR MO DAY
I certify that I am familiar with the information contained in this application and that to the best of my knowledge and belief such information is true, complete,
and accurate.
Michael E. Ma rry 102e Plant Manager
Printeg Name a son Signi Title
102f 9S If Z%
Signature of Applican r uthoriz!d nt YR MO DAY
Date Application Signed
North Carolina General Statue 1 -21 SA (b)(2) provides that Any person who knowingly makes any false statement representation, or certification in any
application, record, report, plan, or other document files or required to be maintained under Article 21 or regulations of the Environmental Management
Commission implementing that Article, or who falsifies, tampers with, or knowingly renders inaccurate any recording or monitoring device or method required
to be operated or maintained under Article 21 or regulations of the Environmental Management Commission implementing that Article, shall be guilty of a
misdemeanor punishable by a fine not to exceed $10,000, or by imprisonment not to exceed sic months, or by both. (18 U.S.C. Section 1001 provides a
punishment by a fine or not more than $10,000 or imprisonment not more than 5 years, or both, for a similar offense.)
1
DEQ-CFW 00064544
11
0
Id
5 Facility (see instructions)
Give the name, ownership, and
physical location of the plant or
other operating facility where
discharge(s) presently occurs)
or will occur.
Name
Ownership (Public, Private
or both Public and Private)
Check block if a Federal
facility
and give GSA Inventory
Control Number
Location:
Number & Street
City
County
State
6. Nature of Business State the nature
of the business conducted at the
plant or operating facility.
7, Facility Intake Water (see
instructions) Indicate water intake
volume per day by sources.
Estimate average volume per day
in thousand gallons per day.
Municipal or private water system
Surface water
Groundwater
Other'
Total Item 7
' If there is intake water from 'other',
Specify th@ Source.
8. Facility Water Use Estimate average
volume per day in thousand galbns
per day for the following types of
water usage at the facility.
(See instructions)
Noncontact cooling water
Baler feed water
Process water (including contact
cooling water)
Sanitary water
other
Total Item 8
If there are discharges to 'other',
specify
If there is 'Sanitary' water use,
give the number of people served.
ir.
105b
105C
105d
105e
105f
105g
105h
106a
rT•R
107a
107b
107c
107d
107e
107f
r.,
E. I. DUPONT DE NEMOURS & CO., INC.
FAYETTEVILLE WORKS
❑ PUB 15PRv C3 6PP
FED
State Highway 87 South
Duart
Bladen
North Carolina
Plastic Sheeting, Film, and R sing-
Industrial Organic Chemical Manufacturing
AGENCY USE
0
0
thousand gallons per day
15,100
thousand gallons per day
6
thousand gallons per day
thousand gallons per day
15,106
thousand gallons per day
13,483 thousand gallons per day
7 3 0 thousand gallons per day
8 3 7 thousand gallons per day
6 thousand gallons per day
50 thousand gallons per day
15 ,10 6 thousand gallons per day
River Water Treatment Backwash & Sediment
738 people served
DEQ-CFW 00064545
i rliLl i �-fii I
9. All Facility Discharges and other Losses. Number
Specify the
and Discharge (See instructions)Volume
number of discharge points and the volume of water
discharged or lost from the facility according b the
categones below. Estimate average volume per day in
'
thousand gallons per day
Number of
Total Volume Discharged,
Discharge Points
Million Gallons Per Day
'
Surface Water 109a1
Sanitary wastewater transport systen 109b1 1
109a2
1092
0.006 ( inc . in 109 a2 )
Stone water transport system 109cl _ 2
109c2
0.052 (inc. in 109a2 )
'
Combined sanitary and storm water 109d1
109d2
transport system
Surface impoundment with no 109e1
109e2
effluent
'
Underground percolation 109f1
10912
Well injection 109g1
109g2
Waste acceptance firm 109h1
109h2
Evaporation 1090 1
109Q
0.293
Consumption 109j 1
109j2
Other 109kt
109k2
'
Facility dischargers and volume
Total Item 9 10911
10912
15.168
'If there are discharges to'other', 109m1
specify.
'
10. Permits, Licenses and Applications
discharges
from this facility instructions)
List all existing, pending or denied permits, licenses and applications related to
(see
Issuing For Type of Date
Date
Date Expiration
Agency Agency Permit or Filed
Issued
Denied Date
'
Use License ID Number YR/MO/DA
YR/MO/DA YR/MO/DA YR/MO/DA
a ,;;_- c e
1. NC—
NCDEHNR N
11. Maps and Drawings
Attach all required maps and drawings to the back of this application. (see instructions)
12. Additional Information
L
P
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DEQ-CFW 00064546
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STANDARD FORM C - MANUFACTURING AND COMMERCIAL
SECTION II. BASIC DISCHARGE DESCRIPTION
Complete this section for each discharge Indicated in Section
which the waste water does not go through a treatment works
also discharges to surface waters from this facility. SEPARAT
ORIGINATE IN THE SAME FACILITY. All values for an exists
discharge, values should reflect best engineering estimates.
ADDITIONAL INSTRUCTIONS FOR SELECTED ITEMS)
BEFORE FILLING OUT THESE ITEMS.
1. Discharge Serial No. and Name
a Discharge Serial No. 201a
(see instructions)
b. Discharge Name 201b
Give the name of discharge, if
any (see instructions)
c. Previous Discharge Serial No 201c
If a previous permit
application was made for this dis-
charge (Item 4, Section 1) provide
previous discharge serial
number.
2 Discharge Operating Dates
a Discharge Began Date 202a
If the discharge described below
is in operation, give the date
(within best estimate) the
discharge began
b. Discharge to Begin Date 202b
If the discharge has never
occurred but is planned for some
future date, give the date the
discharge will begin.
c. Discharge to End Date If the 202c
discharge is scheduled to be
discontinued within the next 5
years, give the date (within best
estimate) the discharge will end.
3. Engineering Report Available
Check if an engineering report is
available to reviewing agency
upon request (see instructions) 203
4. Discharge Location Name the
political boundaries within which
the point of discharge is located:
State
County
'
(if applicable) City or Town
5. Discharge Point Description
(see instructions)
'
Discharge into (check one)
Stream (includes ditches, arroyos,
and other watercourses
Lake
Ocean
Municipal Sanitary Wastewater
'
Transport System
Municipal Combined Sanitary
and Storm Transport System
I, Items 9,nthat Is to surface waters. This Includes discharges to municipal sewerage systems In
ftr to gdisDischargescharged
DESCRIPTIONS OF EACH DISCHARGE RE REQUIREDIEVEN IF SEVERAL DI CHA GrES�
rg discharge should be representative of this twelve previous months of operation. 9 this is a proposed
OPEAR IN SEPARATE INSTRUCTION BOOKLET AS INDICATED. REFER TO BOOKLET
001
Treated Process Wastewater and P_ror-ass Stormwater
001
71 02
N/A
YR MO
N/A
YR MO
A2LCy Use
North Carolina toad
B1 aden 204e
Duart 204f
205a I jgSTR
❑LKE
❑ OCE
❑ MTS
❑ MCS
DEQ-CFW 00064547
1 Munici Storm Water Transport
P� Po
System
' Well (injection)
Other
If'other' is checked, specify type
205b
6. Discharge Point - Lat/Long.
'
Give the precise location of the
pant of discharge to the nearest
second.
Latitude
206a
Longitude
2D6b
7. Discharge Receiving Water Name
Name the waterway at the point of
207a
discharge. (see instructions)
'
If the discharge is through an outfall that extends
beyond the shoreline or is below the mean low
207b
water line, complete item 8,
o Aa se
'
Mzrr I May Suo
207c
Fo, A,,.^cv U!e
8. Offshore Discharge
a. Discharge Distance from Shore
208a
' b. Discharge Depth Below Water
208b
9 Discharge Type and Occurrence
a Type of Discharge Check
' whether the discharge is
continuous or intermittent
209a
(See instructions)
b. Discharge Occurrence Days
per Week. Enter the average
number of days per week
209b
'
(during periods of discharge)
this discharge occurs.
c. Discharge Occurrence- Months
M
If this discharge normally oper-
ates (either intermittently or
continuously) on less than a yea
around basis (excluding shut-
downs for routine maintenance),
check the months during the yea r
when the discharge is operating
` (see instructions)
' Complete Items 10 and 11 9'intermittent' is
checked in Item 9.a. Otherwise, proceed to
Item 12.
10. Intermittent Discharge Quantity
State the average volume per dis-
210
charge occurrence in thousands of
'
gallons
11. Intermittent Discharge Duration
and Frequency
a Intermittent Discharge Duration
'
Per Day State the average
211a
number of hours per day the
discharge is operating
b. Intermittent Discharge
Frequency State the average
211b
number of discharge occurrence
per day during days when
discharging
12. Maximum Flow Period Give the
time period in which the maximum
212
flow of this discharge occurs
DISCHARI ff RIAL NUMBER
❑ STS V
❑ WEL
❑ OTH
N34 DEG. 50 MIN. 00 SEC
W78 DEG. 50 MIN. 00 SEC
Unnamed stream to Cape Fear River
(discharges as part of outfall 002)
N/A feet
N/A feet
® (con) Continuous
❑ (int) Intermittent
7 jays per week
❑ JAN
❑ FEB
❑ MAR
❑ APR
❑ MAY
❑ JUN
❑ JUL
❑ AUG
❑ SEP
❑ OCT
❑ NOV
❑ DEC
*Continuous discharge
N/A thousandgallons per day
N / A hours per day
N/A discharge occurrences per day
From N/A to N/A
month month
0
DEQ-CFW 00064548
�1e _C[e1�►[yL�l't�
13. Activity Description Give a
narrative description of activity
producing this discharge (see
instructions)
14.
21,
21
DISCHARGE SERIAL NUMBER
001
213a Manufacturing, of Polyvinyl BLtyral_ (PVB)
Resin and Sheeting
Manufacturing of Polyvinyl Bury al (PVB)
Resin (SIC Code 2821) and sheeting
(SIC Code 3081).
Activity Causing Discharge For each SIC Code which
describes the activity causing this discharge, supply the
type and maximum amount of either the raw material
consumed (Item 14a) or the product produced (Item 14b)
in the units specified in Table I of the Instruction Booklet.
For SIC Codes not listed in Table I, use raw material or
production units normally used for measuring production
(see instructions)
a Raw Materials
Maximum Unit Shared Discharges
crr- r+.,.- MMMA en,nint/nav rSee Table 1) (Serial Number)
a -----
4
2821
But raldeh
a
L-1
002
2821
KT119Kio'tyl
-002
b. Products
DEQ-CFW 00064549
DISCHARGE SERIAL NUMBER
001
13. Activity Description Give a 213a Manufacture of Hexafluoropropylene
narrative description of activity Epoxide (HFPO) from the oxidation
producing this discharge (see of hexaf luoropropylene (HFP)
instructions)
14. Activittyy Causing Discharge For each SIC Code which
descn'bes the activity causing this discharge, supply the
type and maximum amount of either the raw material
consumed (Item 14a) or the product produced (Item 14b)
in the units specified in Table I of the Instruction Booklet..
For SIC Codes not fisted in Table I, use raw material or
production units normalty used for measuring production
(see instructions)
a Raw Materials
b. Products
DEQ-CFW 00064550
13. Activity Description Give a
narrative description of activity
producing this cscharge (see
instructions)
DISCHARGE SERIAL NUMBER
001
213a Manufacture of uerfluoronated intermediates
(SIC Code 2869). uerfluoronated resins (SIC
Code 2821). and rig fl,oronated laminated film
(STC: Code 1083)
14. Activity Causing Discharge For each SIC Code which
describes the activity causing this discharge, supply the
type and maximum amount of either the raw material
consumed (Item 14a) or the product produced (Item 14b)
in the units specified in Table I of the Instruction Booklet.
For SIC Codes not listed in Table 1, use raw material or
production units normally used for measuring production
(see instructions)
a Raw Materials
Maxdmum Unit Shared Discharges
Cl(. (I via Nama amnuntMov (Saa Tabla 1) (Serial Number)
21�
3
a 11)
)
4
2869
HFPO
P-1
002
2869
Intermediat
s
P-1
002
2821
Resin
L-1
002
b. Products
DEQ-CFW 00064551
I I I I IT
DISCHARGE SERIAL NUMBER
001
15 Waste Abatement
' a Waste Abatement Practices 215a Narrative: See Below
Describe the waste abatement
' practices used on this dis-
charge with a brief narrative
(see instructions)
b. Waste Abatement Codes 215b (1) ESEPAR (2)ESEGRE .3)T,0 A ,S
' Using the codes listed in Table (4)OMONIT (5)CNEUTR (6)EMERGE
II of the Instruction Booklet, (7)PEQUAL (8)BAERAT (9)CHUTRI
describe the waste abatement (1OPAERAT ji1) BACTIV (12) PSKIMC
' processes for this discharge in (13) PFLOAT (14) STHICK (15) SPRESS
the order in which they occur (16) SOTHER (1) 07) SOTHER (2) (18)
if possible. (19) (20) (21)
' (22) (23) (24)
(25)
' SOTHER(1) — SLUDGE DRYING
SOTHER (2) — SLUDGE LANDFILLING
' NARRATIVE: Wastewater collected from area sumps are sent to a 750,000 gal
Equalization Basin (biological activity with aeration). A 175,000
' gal Emergency Retention Tank is available for temporary storage of
unsuitable wastewaters. Waters enter a 250,000 gal Pre —digester Tank
(biological activity with aeration), followed by a 1,700,000 gal Aeration
' Tank where the main biodegradation occurs.. The treated water then goes
to two clarifiers (120,000 and 168,000 gal) in parallel. The clarified
' treated effluent is discharged through Outfall 001.
The wasted sludge is sent to a Dissolved Air Floatation (DAF) unit and
' then a Rotary Filter for thickening. The thickened sludge is dewatered
in a Screw Press, and then dried in steam heated dryers. The dried
' sludge is transported off —site to a commercial landfill.
DEQ-CFW 00064552
1
1
1
1
1
1
1
1
1
1
1
Es
111111101
DISCHARGE SERIAL NUMBER
001
16. Wastewater Characteristics
Check the box beside each constituent which is present in the effluent (discharge water). This determination is to
based on actual analysis or best estimate.(see instructions)
arameter
Wresent
Parameter
Present
216
216
C;oior
peer
00080
X
01042
Ammonia
I ron
00610
X
01045
rganic nitrogen
00605
X
01051
Nitrate
agnesium
00620
X
00927
itnte
Manganese
00615
01055
Phosphorus
Mercury
00665
X
71900
-mllate
olybdenum
00945
X
01062
5uitloe
Nickel
00745
01067
buffite
beienlum
00740
01147
bromide
oliver
71870
01077
Chloride
otassium
00940
X
00937
X
ani
wm
X
00720
00929
won a
nallium
00951
X
01059
Aluminum
itanwm
01105
X
01152
Aritmony
i in
01097
X
01102
Arsenic
zinc
01002
01092
X
ryllium
lgicides,
01012
74051
num
Crilorinated organic compounds'
01007
74052
Boron
Pesticides'
01022
74053
Cadmium
and grease
01027
00550
X
aicwm
Phenois
00916:
32730
5uriactants
01037
36260
X
Chromium
Mlonde
01034
50050
ecai colitorm bacteria
cavity
74055
X
7a�0
be
' Specify substances, compounds and/or elements in Item 26.
Pesticides (insecticides, fungicides, and mdenticides) must be reported in terms of the acceptable common names specified in Acceptable Common Names
and Chemical names for the In mdent SMWnent on PesUcide Labels, 2nd Edition, Environmental Protection Agency, Washington, D.C. 20250, June 1972, as
required by Subsection 162.7(bof the Regulations for the Enfownent of the Federal Insecticide, Fungicide, and Rodenticide Act
DEQ-CFW 00064553
DISCHARGE SERIAL NUMBER
001
17. Description of Intake and Discharge
For each of the parameters listed below, enter in the appropriate box the value or code letter answer called for (see instructions)
In addi bon, enter the parameter name and code and all required values for any of the following parametersif they are checked in Item 16:
ammonia, cyanide, aluminum, arsenic, beryllium, cadmium, chromium, copper, lead, mercury, nickel, selenium, zinc, phenols, oil and grease, and
chlorine (residual).
Influent
uen
Untreated
In -Flan
ai y
Minimum
Maximum
Frequency
Numbero
Sample
Parameter and Code
Intake
Treated
Average
Value
Value
of Analysis
Analyses
Type
Water
Intake
Observed or
Observed or
217
(Daily
Water
Expected
Expected
average)
(Daily
During
During
average)
Discharge
Discharge
Activity
Activity
(1)
(2)
(3
4)
(5)
(6
(7)
8
Flow'
MGD
10.049
50050
N/A
N/A
0.85
1.79
CONT.
1278
N/A
P
Units
004M
N/A
N/A
6.3
8.3
3/7
546
G
emperature twnnterl
�C
N/A
N/A
23.7
18 1
33
3/7
546
G
emperature (summer)
C
74025
N/A
N/A
129.4
20
36
3/7
1 546
G
hoc emaa xygen
Demand
(BOO 5-Day)
mgA
00310
N/A
N/A
5.3
BDL
120
1 3/7
546
C
emicai uxygen
Demand (COD)
mgA
oo3ao
N/A
N/A
45
45
45
N/A
1
C
Totalspen
(nonfilterable) Solids
mgA
117.6
005M
N/A
N/A
1 BDL
440
3/7
546
1 C
Specific on Fiance
micromhos/cm at 252C
00095
N/A
N/A
4600
4600
N/A
1
C
a e Maur
(residue)
mIA
LT
LT
LT
00545
N/A
N/A
0.1
0.1
0.1
N/A
1
C
Other discharges sharing intake flow (serial numbers) (see instructions)
DEQ-CFW 00064554
17
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DISCHARGE SERIAL NUMBER
001
-
Parameter and Code
217
Innuilint
hilluent
ntmatecl
Intake
Water
(Daily
average)
(1)
in-mant
Treated
Intake
Water
(Daily
average)
2)
uailyin-man
Average
g/L
(3) 1(4
minimum
Value
Observed or
Expected
During
Discharge
Activity
aximum
Value
Observed or
Expected
During
Discharge
Activity
5
Frequency
of Analysis
(8
Number
of
Analyses
7
Type
8)
See
17.
18. Plant Controls Check if the following
plant oontrols are available for this
discharge 218
Alternate power source for major
pumping facility APS
Alarm or emergency pmcedure for
power or equipment failure ALM
Complete Item 19 if discharge is frOrr
cooling andior steam water
generation and water treatment
additives are used
19. Water Treatment Additives If the
discharge is treated with arty,
conditioner, inhibitor, or algicide,
answer the following:
a. Name of Material(s) 219a
b. Name and address of 219b
manufacturer
c, Quantity (pounds added per 219c
million gallons of water treated)
DEQ-CFW 00064555
' FOR AGENCY USE
17 Wnnt'dl
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1
L
0
E
DISCHARGE SERIAL NUMBER
001
Effluent
Daily
Average
(all values
are mg/L)
Mimimum
Value
Observed
During
Discharge
Activity
Maximum
Value
Observed
During
Discharge
Activity
Frequency
of Analysis
Number of
Analyses
Sanple
Type
Organic Nitrogen 00605
20.45
1.7
62.4
1/30
41
C
Phosphorus 00665
3.02
0.2
8.1
1/30
41
C
Oil& Grease 00550
6.89
<1
41
4/YR
18
G
Color 00080
25 units
25 units
25 units
NA
I
C
Ammonia 00610
0.1
0.1
0.1
NA
1
C
Nitrate 00620
35
35
35
NA
1
C
Nitrite 00615
0.10
0.10
0.10
NA
1
C
Sulfate 00945
1500
1500
1500
NA
1
C
Chloride 00940
59
59
59
NA
1
C
Aluminum 01105
740
740
740
NA
1
C
Fecal Coliform Bacteria 74055
2100 col/dl
2100 col/dl
2100 col/dl
NA
1
G
Surfactants 38260
0.446
0.446
0.446
NA
I
C
Total Iron 01045
0.423
0.423
0.423
NA
1
C
Fluoride 00951
180
180
180
NA
1
C
L
DEQ-CFW 00064556
' FOR AGENCY USE
DISCHARGE SERIAL NUMBER
p
I'.
C
r
I
001
17 (rnnt'dl
Effluent
Daily
Average
(all values
are ug/L)
Mimimum
Value
Observed
During
Discharge
-Activity
Maximum
Value
Observed
During
Discharge
Activity
Frequency
of Analysis
Number of
Analyses
Sample
Type
Acrolein 34210
LT 50
LT 50
LT 50
1/YR
5
G
Acrylonitrile 34215
LT 50
LT 50
LT 50
1/YR
6
G
Benzene 34030
LT 5
LT 5
LT 5
1/YR
6
G
Bromoform 32104
LT 5
LT 5
LT 5
1/YR
6
G
Carbon Tetrachloride 32102
LT 5
LT 5
LT 5
1/YR
6
G
Chlorobenzene 34301
LT 6
LT 6
LT 6
1/YR
5
G
Chlorodibromomethane 32105
LT 5
LT 5
LT 5
1/YR
6
G
Chloroethane 34311
LT 10
LT 10
LT 10
1/YR
6
G
2-Chloroethlvin 1 ether 34576
LT 10
LT 10
LT 10
l/YR
5
G
Chloroform 32106
LT 5
LT 5
LT 5
1/YR
6
G
Dichlorobromomethane 32101
LT 5
LT 5
LT 5
1/YR
5
G
1,1-Dichloroethane 34496
LT 5
LT 5
LT 5
1/YR
6
G
1,2-Dichloroetime 34531
LT 5
LT 5
LT 5
l/YR
6
G
1,1-Dichloroethlene 34501
LT 5
LT 5
LT 5
1/YR
6
G
1,2-Dichloropropane 34541
LT 6
LT 6
LT 6
1/YR
5
G
1,3-Dichloropropylene 34699
LT 5
LT 5
LT 5
1/YR
6
G
Ethlbenzene 34371
LT 8
LT 8
LT 8
1/YR
6
G
Methyl Bromide 34413
LT 10
LT 10
LT 10
1 /YR
5
G
Methyl Chloride 34418
LT 10
LT 10
LT 10
1/YR
6
G
Methylene Chloride 34423
LT 5
LT 5
LT 5
1/YR
6
G
1,1,2,2-Tetrachloroethane 34516
LT 7
LT 7
LT 7
1/YR
5
G
Tetrachloroethlene 34475
LT 5
LT 5
LT 5
1/YR
6
G
Toluene 34010
LT 6
LT 6
LT 6
1/YR
6
G
1,2-trans-dichloroeth lene 34546
LT 5
LT 5
LT 5
1/YR
5
G
1,1,1-Trichloroethane 34506
LT 5
LT 5
LT 5
1/YR
6
G
1,1,2-Trichloroethane 34511
LT 5
LT 5
LT 5
1/YR
6
G
Trichloroethlene 39180
LT 10
LT 10
LT 10
1/YR
6
G
Vinyl Chloride 39175
LT 10
LT 10
LT 10
1/YR
6
G
DEQ-CFW 00064557
FOR AGENCY USE
DISCHARGE SERIAL NUMBER
' 001
17 (Cont'd)
I
L
0
L
U
L
Effluent
Daily
Average
(all values
are ug/L)
Mimimum
Value
Observed
During
Discharge
Activity
Maximum
Value
Observed
During
Discharge
Activity
Frequency
of Analysis
Number of
Analyses
Sanple
Type
2-Chloro henol 34586
LT 10
LT 10
LT 10
I/YR
6
C
2,4-Dichloro henol 34601
LT 10
LT 10
LT 10
I/YR
6
C
2,4-Dimeth 1 henol 34606
LT 10
LT 10
LT 10
I/YR
6
C
4 6-Dinitro-o-cresol 34657
LT 50
LT50
LT 50
I/YR
6
C
2,4-Dinitro henol 34616
LT 50
LT 50
LT 50
I/YR
6
C
2-Nitrophenol 34591
LT 10
LT 10
LT 10
I/YR
6
C
4-Nitrophenol 34646
LT 50
LT 50
LT 50
I/YR
6
C
p-chloro-m-cresol 34452
LT 10
LT 10
LT 10
I/YR
5
C
Pentachloro henol 39032
LT 50
LT 50
LT 50
I/YR
5
C
Phenol 34694
LT 10
LT 10
LT 10
I/YR
6
C
2,4,6-Trichlorophenol 34621
LT 10
LT 10
LT 10
I/YR
5
C
Acena hthene 34205
LT 10
LT 10
LT 10
I/YR
6
C
Acena hth lene 34200
LT 10
LT 10
LT 10
I/YR
6
C
Anthracene 34220
LT 10
LT 10
LT 10
I/YR
6
C
Benzidine 39120
LT 50
LT 50
LT 50
I/YR
5
C
Benz a thracene 34526
LT 10
LT 10
LT 10
I/YR
6
C
Benz a ene 34247
LT 10
LT 10
LT 10
I/YR
6
C
3,4-benzofluoranthene 34230
LT 10
LT 10
LT 10
I/YR
6
C
Benz lene 34521
LT 10
LT 10
LT 10
I/YR
5
C
Benz fluoranthene 34242
LT 10
LT 10
LT 10
I/YR
6
C
Bi 2-chloroetho ethane 34278
LT 10
LT 10
LT 10
I/YR
5
C
Bi 2-chloroeth 1 ther 34273
LT 10
LT 10
LT 10
I/YR
5
C
Bi 2-chloroi 1 er 34283
LT 10
LT 10
LT 10
I/YR
5
C
Bis 27eth the 1 hthalate 39100
16.3
LT 10
81
1/YR
6
C
4-Bromo hen 1 phenyl ether 34636
LT 10
LT 10
LT 10
I/YR
5
C
Butylbenzyl phthalate 34292
LT 10
LT 10
LT 10
I/YR
5
C
2-Chlorona hthalene 34581
LT 10
LT 10
LT 10
YYR
5
C
4-Chloro hen 1 phenyl ether 34641
LT 10
LT 10
LT 10
I/YR
5
C
F
DEQ-CFW 00064558
' FOR AGENCY USE
DISCHARGE SERIAL NUMBER
' 001
17 (rnnt'dl
F
F
Effluent
Daily
Average
values
(all v
are ualu
Mimimum
Value
Observed
Daring
Discharge
Activity
Maximum
Value
Observed
During
Discharge
Activity
Frequency
of Analysis
Number of
Analyses
Sanple
Type
Chrysene 34320
LT 10
LT 10
LT 10
1/YR
6
C
Dibenz ah thracene 34556
LT 10
LT 10
LT 10
I/YR
6
C
1,2-dichlorobenzene 34536
LT 10
LT 10
LT 10
1/YR
6
C
1 3-dichlorobenzene 34566
LT 10
LT 10
LT 10
1/YR
6
C
1,4-dichlorobenzene 34571
LT 10
LT 10
LT 10
l/YR
6
C
3,3'-dichlorobenzidine 34631
LT 20
LT 20
LT 20
1/YR
6
C
Diethyl phthalate 34336
LT 10
LT 10
LT 10
1/YR
6
C
Dimeth 1 phthalate 34341
LT 10
LT 10
LT 10
1/YR
6
C
Di-n-butyl phthalate 39110
LT 10
LT 10
LT 10
1/YR
6
C
2,4-dinitrotoluene 34611
LT 10
LT 10
LT 10
1/YR
6
C
2,6-dinitrotoluene 34626
LT 10
LT 10
LT 10
1/YR
6
C
Di-n-octyl phthalate 34596
LT 10
LT 10
LT 10
1/YR
5
C
1,2-di hen ih drazine 34346
LT 10
LT 10
LT 10
1/YR
6
C
Fluroranthene 34376
LT 10
LT 10
LT 10
1/YR
6
C
Fluorene 34381
LT 10
LT 10
LT 10
1/YR
6
C
Hexachlorobenzene 39700
LT 10
LT 10
LT 10
1/YR
6
C
Hexachlorobutadiene 34391
LT 10
LT 10
LT 10
l/YR
5
C
Hexachlorocyclopentadiene 34386
LT 10
LT 10
LT 10
1/YR
6
C
Hexachloroethane 34396
LT 10
LT 10
LT 10
1/YR
6
C
Inden 1,2,3-cd ene 34403
IT 10
LT 10
LT 10
1/YR
6
C
Iso horone 34408
LT 10
LT 10
LT 10
1/YR
5
C
Na thalene 34696
LT 10
LT 10
LT 10
1/YR
6
C
Nitrobenzene 34447
LT 10
LT 10
LT 10
1/YR
6
C
N-nitrosodimeth lamine 34438
LT 10
LT 10
LT 10
1/YR
6
C
N-nitrosodi-n-propylamine 34428
LT 10
LT 10
LT 10
1/YR
5
C
N-nitrosodi hen lamine 34433
LT 10
LT 10
LT 10
1/YR
5
C
Phenanthrene 34461
LT 10
LT 10
LT 10
1/YR
6
C
Pvrene 34469
1 LT 10
LT 10
LT 10
1/YR
6
C
1,2,4-trichlorobenzene 34551
1 LT 10
LT 10
LT 10
1/YR
6
C
DEQ-CFW 00064559
' FOR AGENCY USE
DISCHARGE SERIAL NUMBER
' 001
17 (('nnt'ch
n
1
i
E
Effluent
Daily
Average
(all values
are ug/L)
Mimimum
Value
Observed
During
Discharge
Activity
Maximum
Value
Observed
During
Discharge
Activity
Frequency
of Analysis
Number of
Analyses
Sanple
Type
Aldrin 39330
LT 0.050
LT 0.050
LT 0.050
NA
1
C
Al ha-BHC 39337
LT 0.050
LT 0.050
LT 0.050
NA
I
C
Beta-BHC 39338
LT 0.050
LT 0.050
LT 0.050
NA
1
C
Gamma-BHC 39340
LT 0.050
LT 0.050
LT 0.050
NA
1
C
Delta-BHC 34259
LT 0.050
LT 0.050
LT 0.050
NA
1
C
Chlordane 39350
LT 0.50
LT 0.50
LT 0.50
NA
1
C
4,4'-DDT 39300
LT 0.10
LT 0.10
LT 0.10
NA
1
C
4,4'-DDE 39320
LT 0.10
LT 0.10
LT 0.10
NA
1
C
4,4'-DDD 39310
LT 0.10
LT 0.10
LT 0.10
NA
1
C
Dieldrin 39380
LT 0.10
LT 0.10
LT 0.10
NA
1
C
Al ha-Endosulfan 34361
LT 0.050
LT 0.050
LT 0.050
NA
1
C
Beta-Endosulfan 34356
LT 0.10
LT 0.10
LT 0.10
NA
1
C
Endosulfan Sulfate 34351
LT 0.10
LT 0.10
LT 0.10
NA
1
C
Endrin 39390
LT 0.10
LT 0.10
LT 0.10
NA
1
C
Endrin Aldehyde 34366
LT 0.10
LT 0.10
LT 0.10
NA
1
C
Heptachlor 39410
LT 0.050
LT 0.050
LT 0.050
NA
1
C
Heptachlor Epoxide 39420
LT 0.050
LT 0.050
LT 0.050
NA
1
C
PCB-1242 39496
LT 0.50
LT 0.50
LT 0.50
NA
1
C
PCB-1254 39504
LT 1.0
LT 1.0
LT 1.0
NA
1
C
PCB-1221 39488
LT 0.50
LT 0.50
LT 0.50
NA
1
C
PCB-1232 39492
LT 0.50
LT 0.50
LT 0.50
NA
1
C
PCB-1248 39500
LT 0.50
LT 0.50
LT 0.50
NA
1
C
PCB-1260 39508
LT 1.0
LT 1.0
LT 1.0
NA
1
C
PCB-1016 34671
LT 0.50
LT 0.50
LT 0.50
NA
1
C
Toxa hene 39400
LT 5.0
LT 5.0
LT 5.0
NA
1
C
DEQ-CFW 00064560
FOR AGENCY USE
DISCHARGE SERIAL NUMBER
' 001
17 Wont'dl
11
0
11
Effluent
Daily
Average
values
(all v
are ualu
Mimimum
Value
Observed
Ong
Discharge
Activity
Maximum
Value
Observed
During
Discharge
Activity
Frequency
of Analysis
Number of
Analyses
Sanple
Type
Antimony, Total 01097
LT 50
LT 50
LT 50
NA
1
C
Arsenic, Total 01002
LT 10
LT 10
LT 10
NA
1
C
Beryllium, Total 01012
LT 25
LT 25
LT 25
NA
1
C
Cadmium, Total 01027
LT 2
LT 2
LT 2
NA
1
C
Chromium, Total 01034
LT 5
LT 5
LT 5
NA
1
C
Copper, Total 01042
4.03
4.03
4.03
NA
1
C
Lead, Total 01051
LT 10
LT 10
LT 10
NA
1
C
Mercury, Total 71900
LT 0.200
LT 0.200
LT 0.200
NA
1
C
Nickel, Total 01067
LT 10
LT 10
LT 10
NA
i
C
Selenium, Total 01147
LT 5
LT 5
LT 5
NA
1
C
Silver, Total 01077
LT 5
LT 5
LT 5
NA
1
C
Thallium, Total 01059
LT 10
LT 10
LT 10
NA
1
C
Zinc, Total 01092
64.1
64.1
64.1
NA
1
C
C snide, Total 00720
LT 0.010
LT 0.010
LT 0.010
NA
1
G
Phenols, Total 32730
LT 0.005
LT 0.005
LT 0.005
NA
1
G
1l
DEQ-CFW 00064561
L
11
E
d. Chemical composition of these 219d
additives (see instructions)
Complete Items 20-25 if there is a thermal discharge
(e.g., associated with a steam and/or power generation
plant, steel mill, petroleum refinery, or any other
manufacturing process) and the total discharge flow is
10 million gallons per day or more. (see instructions)
20. Thermal Discharge Source- Check 220
the appropriate item(s) indicating
the source of the discharge (see
instructions)
Boiler Blowdown
Boiler Chemical Cleaning
Ash Pond Overflow
Boiler Water Treatment -
Evaporator Slowdown
Oil and Coal Fired Plants -Effluent
from Air Pollution Control Devices
Condense Cooling Water
Cooling Tower Blowdown
Manufacturing Process
Other
21. Discharge/Receiving Water
Temperature Difference
Give the maximum temperature
difference between the discharge
and receiving waters for summer
and winter operating conditions
(see instructions)
Summer 221a
Winter 221b
22. Discharge Temperature, Rate of
Change Per Hour 222
Give the maximum possible rate of
temperature change per hourof
discharge under operating
conditions (see instructions)
23. Water Temperature, Percentile
Repo rt(F requency of Occurrence)
In the table below, enter the
temperature which is exceeded 10%
of the year, 5°b of the year, 1% of
the year and not at all (maximum
yearly temperature). (see
instructions)
Frequency of occurrence
a. Intake Water Temperature 223a
(subject to natural changes
b. Discharge Water Temperature 223b
24. Water Intake Velocity 224
(see instructions)
25. Retention Time Give the length of 225
time, in minutes, from start of
water temperature rise to discharge
of cooling water. (see instructions)
DISCHARGE SERIAL NUMBER
001
BLBD
BCCL
APOF
EPBD
❑ OCFP
[f COND
CTBD
MFPR
OTHR
°F./hour
1 /o
/o
ire
Maximum
OF
OF
OF
OF
'F
OF
OF
OF
feet/sec.
minutes
DEQ-CFW 00064562
DISCHARGE SERIAL NUMBER
001
Additional Information
DEQ-CFW 00064563
I
STANDARD FORM C - MANUFACTURING AND COMMERCIAL
SECTION 11. BASIC DISCHARGE DESCRIPTION
Complete this section for each discharge Indicated
which the waste water does not go through a treatn
also discharges to surface waters from this facility.
ORIGINATE IN THE SAME FACILITY. All values t
discharge, values should reflect best engineering
ADDITIONAL INSTRUCTIONS FOR SELECTE
BEFORE FILLING OUT THESE ITEMS.
1. Discharge Serial No. and Name
a Discharge Serial No.
(see instructions)
b. Discharge Name
Give the name of discharge, if
any (see instructions)
c. Previous Discharge Serial No
If a previous permit
application was made for this dis-
charge (Item 4, Section 1) provide
previous discharge serial
number.
2 Discharge Operating Dates
a Discharge Began Date
If the discharge described below
is in operation, give the date
(within best estimate) the
discharge began
b. Discharge to Begin Date
If the discharge has never
occurred but Is planned for some
future date, give the date the
discharge will begin.
c. Discharge to End Date If the
discharge is scheduled to be
discontinued within the next 5
years, give the date (within best
estimate) the discharge will end.
3. Engineering Report Available
Check if an engineering report is
available to reviewing agency
upon request (see instructions)
4. Discharge Location Name the
political boundaries within which
the point of discharge is located:
State
County
'
(if applicable) City or Town
Discharge Point Ocscription
(see instructions)
Discharge into (check one)
Stream (Includes ditches, arroyos,
and other watercourses
Lake
Ocean
Municipal Sanitary Wastewater
Transport System
Municipal Combined Sanitary
and Storm Transport System
In Section
ent works
SEPARAT
)r an existl
estimates.
D ITEMS
201a I
201b
201c
=1
20Pb
2t72c
203
I, Items 9, that Is to surface waters. This Includes discharges to municipal sewerage systems In
Nior to being discharged to surface waters. Discharges to wells must be described wl." there are
E DESCRIPTIONS OF EACH DISCHARGE ARE REQUIRED EVEN IF SEVERAL DISCHARGES
ig discharge should be representative of do twelve previous months of operation. If this Is a proposed
1PPEAR IN SEPARATE INSTRUCTION BOOKLET AS INDICATED. REFER TO BOOKLET
002
Final Facility Effbient DiG hargP
002
71 02
N/A
YR MO
N/A
YR MO
Aq2Lcy Use
North Carolina 204d
B1 aden _ 204e
Duart 204f
2o5a I ® STR
LKE
OCE
rl MTS
MCS
DEQ-CFW 00064564
DISCHARGE BTIAL NUMBER
'
Municipal Storm Water Transport
STS
System
Well (injection)
WEL
'
Other
❑ OTH
If'othee is checked, specify type
205b
Discharge Point - Lat/L.ong.
Give the precise location of the
point of discharge to the nearest
second.
Latitude
206a
134 DEG. _MIN.
_SEC
i-o^9it
2D6b
W78 DEG. 50 MIN.
00 SEC
'
7. Discharge Receiving Water Name
Name the waterway at the point of
207a
Un—named stream to Cape
Fear River
discharge. (see instructions)
'
It the discharge is through an outfall that extends
beyond the shoreline or is below the mean low
207b
water line, complete item 8,
or Aoe^_ '-;Ile
'I
Na0, 1 V-7 t Suo
207c
For Aoe^cv Use
'
8. Offshore Discharge
a. Discharge Distance from Shore
208a
N/A feet
b. Discharge Depth Below Water
208b
N/A feet
'
9 Discharge Type and Occurrence
a Type of Discharge Check
whether the discharge is
209a
a(oon) Continuous
continuous or intermittent
(int) Intermittent
'
(See instructions)
b. Discharge Occurrence Days
per Week. Enter the average
number of days per week
209b
7 days per week
'
(during periods of discharge)
this discharge occurs.
c. Discharge Occurrence- Months
209c
aJAN 35 FEB
1B MAR
If this discharge normally oper-
JaAPR JR MAY
ig J U N
ates (either intermittently or
JJJUL IER AUG
]B SEP
continuously) on less than a yea
JaOCT JR NOV
]a DEC
around basis (excluding shut-
downs for routine maintenance),
check the months during the ye
when the discharge is operating
(see instructions)
Complete Items 10 and 11 if'internittent' is
checked in Item 9.a. Otherwise, proceed to
'
Item 12.
10. Intermittent Discharge Quantity
State the average volume per dis-
210
thousand gallons per day
charge occurrence in thousands of
'
gallons
11. Intermittent Discharge Duration
and Frequency
'
a Intermittent Discharge Duration
Per Day State the average
211a
hours per day
numberof hours perday the
discharge is operating
b. Intermittent Discharge
Frequency State the average
211b
discharge occurrences per day
'
number of discharge occurrence
per day during days when
discharging
12. Maximum Flow Period Give the
time period in which the maximum
212
From N/A to N/A
'
flow of this discharge occurs
month month
1
DEQ-CFW 00064565
DISCHARGE SERIAL NUMBER
002
13. Activity Description Give a 213a 1— Perfluorinated sheeting process — neutralized
narrative description of activity nitric acid
producing this discharge (see 2— Boiler blowdown and condensate
instructions) 3— Cooling Tower blowdown
4— Stormwater
5— Non —contact cooling water (filtered
water and raw river water-
14. Activity Causing Discharge For each SIC Code which
describes the activity causing this discharge, supply the
type and maximum amount of either the raw material
consumed (Item 14a) or the product produced (Item 14b)
in the units specified in Table I of the Instruction Booklet.
For SIC Codes not listed in Table I, use raw material or
production units normally used for measuring production
(see instructions)
a Raw Materials
Maximum Unit Shared Discharges
erg r+.,,4. tUame Omni,nt/nav (Sea Table Il (Serial Number)
21,
#1
#2
#3
#4
#5
a 1)
)
4
Nitric Acid
0-001
Nn-np
4939
Water
0.133
MGD
001
4939
Water
0.08
XQD
-None_
N/A
Water
2.647
MGD
001
2821,2869
Water
3081, 3083
b. Products
DEQ-CFW 00064566
DISCHARGE SERIAL NUMBER
002
13. Activity Description Give a 213a 6— Treated wastewater effluent
narrative description of activity from Facility's Wastewater Treatment
producing fis discharge (see Plant (Outfall 001)
instructions)
14. Activity Causing Discharge For each SIC Code which
describes the activity causing this discharge, supply the
type and maximum amount of either ft raw material
consumed (Item 14a) or the product produced (Item 14b)
in the units specified in Table I of the Instruction Scoldet..
For SIC Codes not fisted in Table I, use raw material or
production units normally used for measuring production
(see instructions)
a Raw Materials
Maximum Unit Shared Discharges
cir rr^vin Noma AmnunMw (See Table 1) (Serial Number)
214
21
a 11}
)
4
#6 N/A
Outfall 001
1.79
MGD
001
b. Products
DEQ-CFW 00064567
15 Waste Abatement
a Waste Abatement Practices
Describe the waste abatement
practices used on this dis-
charge with a brief narrative
(see instructions)
b. Waste Abatement Codes
Using the codes listed in Table
II of the Instruction Booklet,
describe the waste abatement
processes for this discharge in
the order in which they occur
if possible.
DISCHARGE SERIAL NUMBER
002
215a Narrative: Dilute
nitric
acid is neutralized with
potassium hydroxide
215b (1) CNEUTR
(2)
(3)
(41
(5)
(6)
(7)
(6)
(9)
(10)
(11)
(12)
(13)
(14)
(15)
(16)
(17)
0
(19)
(20)
(21)
(22)
(23)
(24)
(25)
DEQ-CFW 00064568
111111111
DISCHARGE SERIAL NUMBER
002
16. Wastewater Characteristics
Check the box beside each constituent which is present in the effluent (discharge water). This determination is to
based on actual analysis or best estimate. (see instructions)
arameter
Present
fdarameter
Present
216
216
�oior
pper
00060
X
01042
Ammonia
iron
00610
X
01045
X
org00605icnr en
Lew
X
01051
Nitrate
00620
X
magnesium
00927
itnte
Manganese
00615
01055
Phosphorus
mercury
00665
X
71900
Sulfate
-Molybdenum
00945
X
01062
icke
00745
01067
5ultite
belenium
00740
01147
eromi a
anver
71670
01077
Qhlonde
Potassium
00940
X
00937
X
an,de
aocwm
00720
00929
muon e
i nallium
00951
X
01059
Aluminum
faanium
01105
X
01152
Antimony
i in
01097
X
01102
Arsenic
n092
X
0100002
01
rylliurn
1gicis
01012
74M1
_X
'ranum
rnonnate organic compounds'
01007
74052
Boron
Pesticides'
01022
74063
L;aCJMium
Qii and grease
01027
00550
X
aicwm
Phenois
00916 .
32730
Surfactants
X
01037
38260
Chromde
rum
n=
X
01034
5
ecai oo i orm bacteria
HaOlOaCUVIty
74055
X
74050
be
Specify substances, compounds and/or elements in Item 26.
Pesticides (insecticides, fungicides, and rodentirades) must be reported in terms of the acceptable common names specified in Acceptable Common Names
and Chemical names for the ingrafent Statemenf on Pesbade Labels, 2nd Edition, Environmental Protection Agency, Washington, D.C. 20250, June 1972, as
required by Subsection 162.7(b of the Regulations for the Enforcement of the Federal Insecticide, Fungicide, and Rodenticide Act
DEQ-CFW 00064569
�at:tr_[na.[yn�7�
1
1
1
1
1
1
1
1
1
DISCHARGE SERIAL NUMBER
002
17. Description of Intake and Discharge
For each of the parameters listed below, enter in the appropriate box the value or code letter answer called for (see instructions)
In addition, enter the parameter name and code and all required values for any of the following parameters it they ere checked in Item 1e:
ammonia, cyanide, aluminum, arsenic, beryllium, cadmium, chromium, copper, lead, mercury, nickel, selenium, zinc, phenols, oil and grease, and
chlorine (residual).
n ueIn
uent
Untreated
n-ai
y
inimum
aximum
requenry
um r o
p e
Parameter and Code
Intake
TrAverage
Value
Value
of Analysis
Analyses
Type
Water
In
Observed or
Observed or
217
(Daily
W
Expected
Expected
average)
(D
During
During
av
Discharge
Discharge
Activity
Activity
1
2)
(3)
J4
(5)
(6
(7) 1
(8
How.
MGD
50050
15.10
3.10
15.10
12.96
21.91
CONT
1278
N/A
P
Units
00400
6.7
N/A
6.0
8.8
3/7
546
G
Temperature (wnnter)
.0
74026
10.8
N/A
17.6
8
26
7/7
1278
G
emperature (summer)
cc
74025
22.9
N/A
126.9
15
36
7/7
1278
G
biochemcial Oxygen
Demand
(BOD 5-Day)
mg/l
00310
ILT 2.0
IT 2-C
6.6
LT 1
70
4/YR
14
C
—CFemica xygen
Demand (COD)
mgA
00W
109
LT 25
55.4
LT 5
392
4/YR
14
C
Totalspen
(nonfilterable) Solids
mgA
ILT
005W
27
LT 6
6
LT 6
LT 6
N/A
1
C
Speafic Conductance
micromhos/cm at 25'C
00095
109
1140
540
540
N/A
1
C
Settleable a r
(residue)
mIA
00W
LT 0.1
LT 0.1
T 0.
LT 0.1
LT 0.1
N/A
1
C
' Other discharges sharing intake flow (serial numbers) (see instructions)
DEQ-CFW 00064570
Is• crr_taSt ins A
j11111111
DISCHARGE SERIAL NUMBER
002
17 (Conrd)
Parameter and Code
217
Innuent
Emuent
n
Intake
Water
(Daily
average)
(1)
in -Plant
Treated
Intake
Water
(Daily
average)
2)
ai y
Average
1(3)
Minimum
Value
Observed or
Expected
During
Discharge
Activity
14
aximum
Value
Observed or
Expected
During
Discharge
Activity
5
requency
of Analysis
8
Number
of
Analyses
7
Sample
Type
8)
See attached
Daize for Item
18. Plant Controls Check if the following
plant controls are available for this
discharge
218
Alternate power source for major
pumping facility
x❑ APS
Alarm or emergency procedure for
power or equipment failure
® ALM
Complete Item 19 if discharge is frorr
cooling and/or steam water
generation and water treatment
addiWes are used
19. Water Treatment Additives If the
discharge is treated with any
conditioner, inhibitor, or algicide,
answer the following:
a Name ofMaterial(s)
219a
*Note: Outfall 002 discharge is not treated
with any chemicals. However. the BCH Energy
Proiect's Boiler and Cooling Tower waters contain
b. Name and address of
219b
treatment additives. which are discharged through
manufacturer
Out f all 002.
See attached page for Item 19.
c, Quantity (pounds added per
219c
million gallons of water treated)
DEQ-CFW 00064571
' FOR AGENCY USE
' DISCHARGE SERIAL NUMBER
' 002
17 (Cnnt'dl
1
r
C
C
p
11
L
L
C
Effluent
Daily
Average
(all values
are mg/L)
Mimimum
Value
Observed
During
Discharge
Activity
Maximum
Value
Observed
Ding
Discharge
Activity
Frequency
of Analysis
Number of
Analyses
Sanple
Type
Fluoride 00951
6.85
0.02
86
1/7
178
C
Color 00080
100 units
100 units
100 units
NA
1
C
Ammonia 00610
0.1
0.1
0.1
NA
1
C
Nitrate 00620
2.3
2.3
2.3
NA
1
C
Nitrite 00615
0.04
0.04
0.04
NA
1
C
Sulfate 00945
130
130
130
NA
1
C
Chloride 00940
14
14
14
NA
1
C
Aluminum 01105
1950
1950
1950
NA
1
C
Fecal Colifonm Bacteria 74055
690 col/dl
690 col/dl
690 col/dl
NA
1
C
Surfactants 38260
0.252
0.252
0.252
NA
1
C
Organic Nitrogen 00605
0.8
0.8
0.8
NA
1
C
Total Phosphorus 00665
0.17
0.17
0.17
NA
1
C
Total Iron 01045
1.44
1.44
1.44
NA
1
C
Total Sodium 00929
44.8
44.8
44.8
NA
1
C
Total Potassium 00937
82.5
82.5
82.5
NA
1
C
Oil & Grease 00550
LT 5
LT 5
LT 5
NA
1
C
DEQ-CFW 00064572
FOR AGENCY USE
DISCHARGE SERIAL NUMBER
' 002
17 ((`nnt'dl
L
I
I
L
Effluent
Daily
Average
values
(all v
are ualu
Minimum
Value
Observed
During
Discharge
Activity
Maximum
Value
Observed
During
Discharge
Activity
Frequency
of Analysis
Number of
Analyses
Sanple
Type
Acrolein 34210
LT 5
LT 5
LT 5
NA
1
G
Acrylonitrile 34215
LT 5
LT 5
LT 5
NA
1
G
Benzene 34030
LT 5
LT 5
LT 5
NA
1
G
Bromoform 32104
LT 5
LT 5
LT 5
NA
1
G
Carbon Tetrachloride 32102
IT 5
LT 5
LT 5
NA
I
G
Chlorobenzene 34301
LT 5
LT 5
LT 5
NA
1
G
Chlorodibromomethane 32105
LT 5
LT 5
LT 5
NA
1
G
Chloroethane 34311
LT 10
LT 10
LT 10
NA
1
G
2-Chloroeth lvin 1 ether 34576
LT 10
LT 10
LT 10
NA
1
G
Chloroform 32106
LT 5
LT 5
LT 5
NA
1
G
Dichlorobromomethane 32101
LT 5
LT 5
LT 5
NA
1
G
1,1-Dichloroethane 34496
LT 5
LT 5
LT 5
NA
1
G
1,2-Dichloroedme 34531
LT 5
LT 5
LT 5
NA
1
G
1,1-Dichloroeth lene 34501
LT 5
LT 5
LT 5
NA
1
G
1,2-Dichloropropane 34541
LT 5
LT 5
LT 5
NA
1
G
1,3-Dichloropropylene 34699
LT 5
LT 5
LT 5
NA
1
G
Eth lbenzene 34371
LT 5
LT 5
LT 5
NA
1
G
Methyl Bromide 34413
LT 10
LT 10
LT 10
NA
1
G
Methyl Chloride 34418
LT 10
LT 10
LT 10
NA
1
G
Methylene Chloride 34423
LT 5
LT 5
LT 5
NA
1
G
1,1,2,2-Tetrachloroethane 34516
LT 5
LT 5
LT 5
NA
1
G
Tetrachloroeth lene 34475
LT 5
LT 5
LT 5
NA
1
G
Toluene 34010
LT 5
LT 5
LT 5
NA
1
G
1,2-trans-dichloroeth lene 34546
LT 5
LT 5
LT 5
NA
1
G
1,1,1-Trichloroethane 34506
LT 5
LT 5
LT 5
NA
1
G
1,1,2-Trichloroethane 34511
LT 5
LT 5
LT 5
NA
1
G
Trichloroeth lene 39180
LT 5
LT 5
LT 5
NA
1
G
Vinyl Chloride 39175
LT 10
LT 10
LT 10
NA
1
G
1
DEQ-CFW 00064573
' FOR AGENCY USE
1
I !
I
L
r
k
U
n
C
DISCHARGE SERIAL NUMBER
002
17 (rnnt,d)
Effluent
Daily
Average
(all values
are ug/L)
Mimimum
Value
Observed
DuringDuring
Discharge
Activity
Maximum
Value
Observed
Discharge
Activity
Frequency
of Analysis
Number of
Analyses
Sanple
Type
2-Chloro henol 34586
LT 10
LT 10
LT 10
NA
1
C
2,4-Dichlorohenol 34601
LT 10
LT 10
LT 10
NA
1
C
2,4-Dimeth 1 henol 34606
LT 10
LT 10
LT 10
NA
1
C
4,6-Dinitro-o-cresol 34657
LT 50
LT50
LT 50
NA
1
C
2,4-Dinitrophenol 34616
LT 50
LT 50
LT 50
NA
1
C
2-Nitrophenol 34591
LT 10
LT 10
LT 10
NA
1
C
4-Nitrophenol 34646
LT 50
LT 50
LT 50
NA
1
C
p-chloro-m-cresol 34452
LT 10
LT 10
LT 10
NA
1
C
Pentachloro henol 39032
LT 50
LT 50
LT 50
NA
1
C
Phenol 34694
LT 10
LT 10
LT 10
NA
1
C
2,4,6-Trichl henol 34621
LT 10
LT 10
LT 10
NA
1
C
Acena hthene 34205
LT 10
LT 10
LT 10
NA
1
C
Acena hth lene 34200
LT 10
LT 10
LT 10
NA
1
C
Anduacene 34220
LT 10
LT 10
LT 10
NA
1
C
Benzidine 39120
LT 50
LT 50
LT 50
NA
1
C
Benz a thracene 34526
LT 10
LT 10
LT 10
NA
1
C
Benz a ene 34247
LT 10
LT 10
LT 10
NA
1
C
3,4-benzofluoranthene 34230
LT 10
LT 10
LT 10
NA
1
C
Benz lene 34521
LT 10
LT 10
LT 10
NA
1
C
Benz fluoranthene 34242
LT 10
LT 10
LT 10
NA
1
C
Bi 2-chloroetho ethane 34278
LT 10
LT 10
LT 10
NA
1
C
Bi 2-chloroeth 1 ther 34273
LT 10
LT 10
LT 10
NA
1
C
Bis(2-chloroisopropylXther 34283
LT 10
LT 10
LT 10
NA
1
C
Bis 2-eth the 1 hthalate 39100
LT 10
LT 10
LT 81
NA
1
C
4-Bromophenyl phenyl ether 34636
LT 10
LT 10
LT 10
NA
1
C
Butylbenzyl plithalate 34292
LT 10
LT 10
LT 10
NA
1
C
2-Chlorona hthalene 34581
LT 10
LT 10
LT 10
NA
1
C
-T 4-Chlorohen 1 phenyl ether 34641
LT 10
LT 10
LT 10
NA
1
C
DEQ-CFW 00064574
' FOR AGENCY USE
DISCHARGE SERIAL NUMBER
' 002
17. (Cont'd)
E
-1
C
LI
Effluent
Daily
Average
values
(all v
are ualu
Mimimum
Value
Observed
During
Discharge
Activity
Maximum
Value
Observed
During
Discharge
Activity
Frequency
of Analysis
Number of
Analyses
Sanple
Type
Chrysene 34320
LT 10
LT 10
LT 10
NA
1
C
Dibenz a,h thracene 34556
LT 10
LT 10
LT 10
NA
1
C
1,2-dichlorobenzene 34536
LT 5
LT 5
LT 5
NA
1
C
1,3-dichlombenzene 34566
LT 5
LT 5
LT 5
NA
1
C
1,44chlorobenzene 34571
LT 5
LT 5
LT 5
NA
1
C
3,3'-dichlorobenzidine 34631
LT 10
LT 10
LT 10
NA
1
C
Diethyl phthalate 34336
LT 10
LT 10
LT 10
NA
1
C
Dimeth 1 plithalate 34341
LT 10
LT 10
LT 10
NA
1
C
Di-n-butyl phthalate 39110
LT 10
LT 10
LT 10
NA
1
C
2,44initrotoluene 34611
LT 10
LT 10
LT 10
NA
1
C
2,6-dinitrotoluene 34626
LT 10
LT 10
LT 10
NA
1
C
Di-n-octyl phthalate 34596
23
23
23
NA
1
C
1,2-di hen lh drazine 34346
LT 10
LT 10
LT 10
NAJ
1
C
Fluroranthene 34376
LT 10
LT 10
LT 10
NA
1
C
Fluorene 34381
LT 10
LT 10
LT 10
NA
1
C
Hexachlombenzene 39700
LT 10
LT 10
LT 10
NA
1
C
Hexachlorobutadiene 34391
LT 10
LT 10
LT 10
NA
1
C
Hexachlorocyplopentadiene 34386
LT 10
LT 10
LT 10
NA
1
C
Hexachloroethane 34396
LT 10
LT 10
LT 10
NA
1
C
Inden 1,2,3-cd ene 34403
LT 10
LT 10
LT 10
NA
1
C
Iso horone 34408
LT 10
LT 10
LT 10
NA
1
C
Na thalene 34696
LT 10
LT 10
LT 10
NA
1
C
Nitrobenzene 34447
LT 10
LT 10
LT 10
NA
1
C
N-nitrosodimeth lamine 34438
LT 10
LT 10
LT 10
NA
1
C
N-nitrosodi-n- o lamine 34428
LT 10
LT 10
LT 10
NA
1
C
N-nitrosodi hen lamine 34433
LT 10
LT 10
LT 10
NA
1
C
Phenanthrene 34461
LT 10
LT 10
LT 10
NA
1
C
Pyrene 34469
LT 10
LT 10
LT 10
NA
1
C
1,2,4-trichlorobenzene 34551
LT 10
LT 10
LT 10
NA
1
C
1
DEQ-CFW 00064575
' FOR AGENCY USE
DISCHARGE SERIAL NUMBER
' 002
I
11
Effluent
Daily
Average
(all values
are
Mimftn=
Value
Observed
During
Discharge
Activity
Maximum
Value
Observed
During
Discharge
Activity
Frequency
of Analysis
Number of
Analyses
Sanple
Type
Antimony, Total 01097
LT 50
LT 50
LT 50
NA
1
C
Arsenic, Total 01002
LT 10
LT 10
LT 10
NA
1
C
Beryllium, Total 01012
LT 25
LT 25
LT 25
NA
1
C
Cadmium Total 01027
LT 2
LT 2
LT 2
NA
1
C
Chromium, Total 01034
LT 5
LT 5
LT 5
NA
1
C
Copper, Total 01042
6.83
6.83
6.83
NA
1
C
Lead, Total 01051
LT 10
LT 10
LT 10
NA
1
C
Mercury, Total 71900
LT 0.200
LT 0.200
LT 0.200
NA
1
C
Nickel, Total 01067
LT 10
LT 10
LT 10
NA
1
C
Selenium, Total 01147
LT 5
LT 5
LT 5
NA
1
C
Silver, Total 01077
LT 5
LT 5
LT 5
NA
1
C
Thallium, Total 01059
LT 10
LT 10
LT 10
NA
1
C
Zinc, Total 01092
18.8
18.8
18.8
NA
1
C
Cyanide, Total 00720
LT 0.010
LT 0.010
LT 0.010
NA
1
C
Phenols, Total 32730
LT 0.005
LT 0.005
LT 0.005
NA
1
C
F
DEQ-CFW 00064576
FOR AGENCY USE
DISCHARGE SERIAL NUMBER
002
' 19. Water Treatment Additives. If the discharge is treated with any conditioner,
inhibitor, or algicide, answer the following:
I
C
219b Name and address
291 c Quantity (pounds added per
291 d Chemical
219a Name of Material
of manufacturer
million gallon of water treated)
composition
Betz Industrial Corp
Bio-Trol 88P
Landmark Plaza
5 lb/day at the BCH Facility
See attached
4303-8 Oleander Dr.
(0.33 lb/million gal at Outfall 002)
DEM Form 101
Wilmington, NC
28403
Betz Industrial Corp
Cor-Trol 778P
Landmark Plaza
0.069 lb/day at the BCH Facility
See attached
4303-8 Oleander Dr.
(0.0046 lb/million gal at Outfall 002)
DEM Form 101
Wilmington, NC
29403
Betz Industrial Corp
Balanced Polymer 54400
Landmark Plaza
0.154 lb/day at the BCH Facility
See attached
4303-8 Oleander Dr.
(0.010 lb/million gal at Outfall 002)
DEM Form 101
Wilmington, NC
28403
Betz Industrial Corp
Opti-Meer
Landmark Plaza
0.038 lb/day at the BCH Facility
See attached
4303-8 Oleander Dr.
(0.0025 lb/million gal at Outfall 002)
DEM Form 101
Wilmington, NC
28403
Betz Industrial Corp
Continuum 29000
Landmark Plaza
3.60 lb/day at the BCH Facility
See attached
4303-8 Oleander Dr.
(0.238 lb/million gal at Outfall 002)
DEM Form 101
Wilmington, NC
29403
Note: The above additives are used solely in the BCH Energy Project Facility located at the Dupont Fayetteville
Works and which ultimately discharges through the DuPont Outfall 002.
DEQ-CFW 00064577
L'
I
I
I
d Chemical composition of these I 219d
additions ves (see instructi)
Complete Items 20-25 if there is a thermal discharge
(e.g., associatedwith a steam and/or power generation
plant, steel mill, petroleum refinery, or any other
manufacturing process) and the total discharge flow is
10 million gallons per day or more. (see instructions)
20. Thermal Discharge Source_ Check . 220
the appropriate item(s) indicating
the source of the discharge (see
instructions)
Boiler Slowdown
Boiler Chemical Cleaning
Ash Pond Overflow
Boiler Water Treatment -
Evaporator Slowdown
Oil and Coal Fired Plants -Effluent
from Air Pollution Control Devices
Condense Cooling Water
Cooling Tower Slowdown
Manufacturing Process
Other
21. Discharge,'Receiving Water
Temperature Difference
Give the maximum temperature
difference between the discharge
and receiving waters for summer
and winter operating conditions
(see instructions)
Summer 221a
Winter 221b
22. Discharge Temperature , Rate of
Change Per Hour 222
Give the maximum possible rate of
temperature change per hour of
discharge under operating
conditions (see instructions)
23. Water Temperature, Peroentile
Report(Frequency of Occurrence)
In the table below, enter the
temperature which is exceeded 10%
of the year, 5% of the year, 1 % of
the year and not at all (maximum
yearly temperature). (see
instructions)
Frequency of occurrence
a. Intake Water Temperature 223a
(subject to natural changes
b. Discharge Water Temperature 223b
24. Water Intake Velocity 224
(see instructions)
25. Retention Time Give the length of 225
time, in minutes, from start of
water temperature rise to discharge
of cooling water. (see instructions)
DISCHARGE SERIAL NUMBER
002
See attached D.E.M. Form 101
for compositions.
® BLBD
p BCCL
APOF
EPBD
OCFP
k7 COND
® CTBD
® MFPR
OTHR
10.8 of
23.4 OF
0.5 0FJhour
1 /o
/0
1 /e
maximum
84.6 OF
85.5OF
87.2 OF
88.8°F
87.8 OF
91.4°F
95 OF
I 96.80F
1.6 feettsec.
_35 minutes
DEQ-CFW 00064578
111UM
DISCHARGE SERIAL NUMBER
002
Additional I nfomiabon
Item
n ormabon
16
Biocide used in the BCH Energy Pro'ect's Cooling Tower is
BETZ Bio-Trol 88P. For all the treatment chemicals used in
the facility, a D.E.M. Form 101 is attach
DEQ-CFW 00064579
' Facility Name: DuPont Company - Fayetteville Works NPDES #: NC nnn-573
' BIOCIDE/CHEMICAL TREATMENT
WORKSHEET-FORM 101
' The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of
North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet is to be
returned with all appropriate data entered into the designated areas with calculations performed as indicated.
I. Facility Name DuPont Comuanv - Favettevil le_ Wnrka
NPDES # NC 0003573
County Baden
' Receiving Stream Cape Fear River 7010 791 (cfS)
(Ail above information suppled by the Division of Environmental Management)
' What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water body?
' A.D.D. = 12.2 (in M.G.D.)
Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered
' above.
IWC = (A.D.D.) X 100 _ (12.2) X 100 = 2.3 %
(7Q10)(0.646) - (791 )(0.646) + (A.D.D.)
This value (IWC) represents the waste concentration to the receiving stream during low flow conditions.
What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I?
3E 2- Cor- T l '77,?P
Please list the active ingredients and percent composition:
�-`r� %
rr %
%
What feed or dosage rate (D.R.) is used in this application? The units must be converted to grams of whole
' product used per day.
D.R.= grams/day
D.E.M. Form 101 (7/92) 1
DEQ-CFW 00064580
' Facility Name: DuPont Company - Fayetteville Works NPDES #: NC 0003573
' Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge
point. On an attached sheet please provide justification for this estimate (system volume, average cycles per
' blowdown, holding lagoon size, etc.)
Volume- 0.16 million gallons
' What is the pH of the handling system prior to biocide addtfon? If unknown, enter WA. 6-9
' What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.-O) and proceed to asterisk.
The degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the half
' fife (Half Life is the time required for the initial product to degrade to half of its original concentration). Please
provide copies of the sources of this data.
H.L. - Unknown Days
The decay rate is equal to H�L X 0.69 = 0 =Decay Rate (D.K.)
Calculate degradation factor (D.F.). This is the first order loss coefficient.
' D.F. = A( D.D.) + (D.K.) _ (12.2 ) + ( 0 ) 76
(Volume) ( 0.16 )
F
C
I
In.
C
11
11
Calculate Steady State Discharge Concentration: (31.4 ) _ �� pia 7 rr,g/I
(D.R.)
Dischg Conc. _ (D.F.)(Volume)(3785) _ ( 76 ) ( 0.16 ) (3 7 8 5 )
Calculate concentration of biocide instream during low flow conditions.
(Receiving Stream Concentration)
(Discho. Conc.) x (IWC010) _ (0. D007 ) x ( 2.3 ) = Q QODD �� myI
too too
Receiving Stream Concentration
Calculate regulated limitation.
List all LC50 data available for the whole product according to the following columns. (Note that units should be
in mg/1). Please provide copies of the sources of this data.
Q L _Organism
7wo.Aow 7s-�OK7-
/�
l�i�Ll
Yh//end �'(��Nhotd
Gt.ONNi� Qgh�t,.
Test Duration
'-A;-
t C50 (MA
D.E.M. Form 101 (7/92) 2
DEQ-CFW 00064581
s
Facility Name: DuPont Company - Fayetteville Works NPDES #: NC 0003573
Choose the lowest LC50 listed above:
Enter the LC50: 6.3 J "�
•If the haff life (H.L.) is less than 4 days, perform the following calculation.
Regulated Limitation = 0.05 x LC50 = MgA
B the half life (H.L.) is greater than 4 days or unknown, perform the following calculation.
Regulated Limitation = 0.01 x LC50 = O, 04e;3 mg/I
Choose the appropriate regulated limitation from the kalCufations immediately above and place in this blank:
0 Ag _2 mg/liter
From Part II enter the receiving stream concentration:
0 0000 mg/liter
IV. Analysis.
If the receiving stream concentration is greater than the calculated regulated Irritation, then this biodde is
unacceptable for use.
1q1:: rL e �• '7 oKKSOiL
Person in Responsible Charge
5 -- 9s'
We
D.E.M. Form 101 (7/92)
3
DEQ-CFW 00064582
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
BETZ LABORATORIES, INC.
4636 SOMERTON ROAD, TREVOSE, PA 19053
PRODUCT: COR-TROL 778-P
August 19, 1994
AQUATIC TOXICOLOGY
Rainbow Trout 96 Hour Static Acute Bioassay
LC50: 6.3 mg/L
No Effect Level: 3.7
Fathead Minnow 96 Hour Static Renewal Bioassay
LC50: 8•:2 mg/L No Effect Level: 3.1
Daphnia magna 48 Hour Static Renewal Bioassay
LC50: 8.7 mg/L
No Effect Level: 4.9
BIODEGRADATION
COD (mg/gm): 47 Calculated
TOC (mg/gm): 16 Calculated
BOD-5 (mg/gm): 27 Calculated
BOD-28 (mg/gm): 27 Calculated
Closed Bottle Test
$ Degradation in 28 days: 83 Calculated
Zahn-Wellens Test
% Degradation in 28 days: 65 Calculated
MAMLIAN TOXICOLOGY
Oral LD50 RAT: >5,000 MG/KG
• Note - ESTIMATED VALUE
Dermal LD50 RABBIT: >5,000 MG/KG
Note - ESTIMATED VALUE
DEQ-CFW 00064583
' Facility Name: DuPont Company - Fayetteville Works NPDES #: NC nnn357,A
BIOCIDE/CHEMICAL TREATMENT
WORKSHEET-FORM 101
' The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of
North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet is to be
returned with all appropriate data entered into the designated areas with calculations performed as indicated.
1. Facility Name DuPont Company - Fayettevilla Works
' NPDES # NC 0003573
County Bl aden
' Receiving Stream Cave Fear River _ 7010 7g1 (cfS)
(Ail above information supplied by the Division of Environmental Management)
' What is the Average Daily Discharge (A.D.D.) volume of the water handing systems to the receiving water body?
A.D.D. = 12.2 (in M.G.D.)
Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered
' above.
IWC = (A.D.D.) X 100 _ (12.2) X 100 = 2.3 ryo
(7Q10)(0.646) — (791 )(0.646) + (A.D.D.)
This value (IWC) represents the waste concentration to the receiving stream during low flow conditions.
II. What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I
&7-9 &0-7,v-,/ 29P
Please list the active ingredients and percent composition:
// /L P•
l ' b►oofe -; -�vo 5 S � a�wst+�r�`iy�nTb�K r*�S+_%
' _%
' %
What feed or dosage rate (D.R.) is used in this application? The units must be converted to grams of whole
' product used per day.
D.R.= L.GIo grams/day
D.E.M. Form 101 (7/92) 1
DEQ-CFW 00064584
• Facility Name: DuPont Company - Fayetteville Works NPDES #: NC 0003573
' Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge
point. On an attached sheet please provide justification for this estimate (system volume, average cycles per
' blowdown, holding lagoon size, etc.)
Volume= 0.16 million gallons
' What is the pH of the handling system prior to biocide addition? If unknown, enter NIA. 6-9
What is the decay rate (D.K.) of the product? 0 unknown, assume no decay (D.K.-0) and proceed to asterisk.
The degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the half
' life (Half Life is the time required for the initial product to degrade to half of its original concentration). Please
provide copies of the sources of this data.
' H.L. = Unknown Days
The decay rate is equal to H1L X 0.69 = 0 =Decay Rate (D.K.)
Calculate degradation factor (D.F.). This is the first order loss coefficient.
' D.F. = AS- .D.D.)- + (D.K.) _ (12.2 ) + ( 0 ) 76
(Volume) ( 0.16 )
I
in.
C
Calculate Steady State Discharge Concentration: 22
. D�
(� ) omg/I
Dtschg Cont. ' (D.R.) (D.F.)(Volume)(3785) ' ( 76 ) ( 0.16 ) (3 78 5 )
Calculate concentration of biocide instream during low flow conditions.
(Receiving Stream Concentration)
(Discho. Conc.) x (IWCOM _ (10. 049 1) x ( 2.3 ) _ �j, G?�/ mg/l
100
Receiving Stream Concentration
Calculate regulated limitation.
List all LC50 data available for the whole product according to the following columns. (Note that units should be
in mg/1). Please provide copies of the sources of this data.
ru-wk.... -%yrwf
D4DK641'R- A11094Nst.
Test DuJJration
%- /y
9 - AA
TO -Ae
LC50 (M-A
O. YI
D.E.M. Form 101 (7/92) 2
DEQ-CFW 00064585
' Facility Name: DuPont Company - Fayetteville Works NPDES #: NC 0003573
Choose the lowest LC50 listed above:
Enter the LC50: O• 4,5--
' •ff the half life (H.L.) is less than 4 days, perform the following calculation.
Regulated Umitation = 0.05 x LC50 1mgA
If the half Ife (H.L.) is greater than 4 days or unknown, perform the following calculation.
Regulated Umitation = 0.01 x LC50 0. 004��mg/l
' Choose the appropriate regulated Imitation from the calculations immediately above and place in this blank:
O. GAS mg/titer
' From Part 11 enter the receiving stream concentration:
O. GY>/ l mg/liter
IV. Analysis.
' If the receiving stream concentration is greater than the calculated regulated Imitation, then this biocide is
unacceptable for use.
........
I
' we
Person in Responsible Charge
D.E.M. Form 101 (7/92) 3
DEQ-CFW 00064586
'I
E
L
BETZ LABORATORIES, INC.
4636 SOMERTON ROAD, TREVOSE, PA 19053
PRODUCT: BIO-TROL 88P
AQUATIC TOXICOLOGY
Rainbow Trout 96 Hour Static Acute Bioassay
LC50: .87 mg/L
Fathead Minnow 96 Hour Static Acute Bioassay
LC50: 2..19 mg/L
Daphnia magna 48 Hour Static Acute Bioassay.
LC50: .45 mg/L
Sheepshead Minnow 96 Hour Static Acute Bioassay
LC50: 19.5 mg/L
BIODEGRADATION
NO DATA AVAILABLE
NUOMLIAN TOXICOLOGY
August 19, 1994
Oral LD50 RAT: 578 MG/KG
Note - 600 MG/KG PER ALT. SOURCE; DEHALOGENATED BYPRODUCT
RAT ORAL LD50: >4,000 MG/KG
Dermal LD50 RABBIT: >2,000 MG/KG
. Note - ALTERNATE SOURCE CONCURS
Inhalation LC50 RAT: 1.88 MG/L/4HR
Note - X3.2 MG/L/4HR AT 100 PPM (NO DEATHS) PER ALTERNATE
SOURCE
Skin Irritation Score RABBIT: 6.1
Note - 6.98 PER ALTERNATE SOURCE.- REVERSIBLE;
DEHALOGENATED BYPRODUCT SCORE: 0.8
Eye Irritation Score RABBIT: 103
Note - 14 DAY-IRREVERSIBLE-MAX.AT DAY 3; DEHALOGENATED
BYPRODUCT SCORE: 12.8-REVERSIBLE
90 Day Feed
Study RAT: NO
DATA
'
Note -
DEHALOGENATED
BYPRODUCT 90-DAY ORAL LD50: >2,000-
DEQ-CFW 00064587
' Facility Name: DuPont Comoanv - Fayetteville Works NPDES #: NC nonis7'i
' BIOCIDE/CHEMICAL TREATMENT
WORKSHEET-FORM 101
' The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of
North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet is to be
returned with all appropriate data entered into the designated areas with calculations performed as indicated.
I. Facility Name DuPont Company,- Fayetteville Works
' NPDES # NC 0003573 -
County Baden
Receiving Stream Cave Fear River 7010 Zg 1 (cfs)
(All above information supplied by the Division of Environmental Management)
' What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water body?
' A.D.D. = 12.2 (in M.G.D.)
Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered
' above.
IWC = (A.D.D.) X 100 _ (12 2) X 100 = 2.3 %
(7Q10)(0.646) - (791 )(0.646) + (A.D.D.)
This value (IWC) represents the waste concentration to the receiving stream during low flow conditions.
II. What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I?
Please fist the active ingredients and percent composition:
e'`o
1 ;
1 -
What feed or dosage rate (D.R.) is used in this application? The units must be converted to grams of whole
' product used per day.
D.R.= lo% 7 grams/day
E
D.E.M. Form 101 (7/92) 1
DEQ-CFW 00064588
I Facility Name:
DuPont Company - Fayetteville Works NPDES #: NC 0003573
' Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge
point. On an attached sheet please provide justification for this estimate (system volume, average cycles per
' blowdown, holding lagoon size, etc.)
Volume- 0.16 million gallons
' What is the pH of the handling system prior to biocide addition? If unknown, enter N/A. 6-9
tWhat is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.-0) and proceed to asterisk.
The degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the half
' We (Hag Life is the time required for the initial product to degrade to half of its original concentration). Please
provide copies of the sources of this data.
' H.L. = Unknown Days
' The decay rate is equal to HiL X 0.69 = 0 =Decay Rate (D.K.)
Calculate degradation factor (D.F.). This is the first order loss coefficient.
' = A_(D.D.)( ) - + D.K. (12.2 ) + 0 ) 76
D.F. (Volume) ( 0.16 )
Calculate Steady State Discharge Concentration:
Dischg Conc. _ (D.R.) = ( fig• 7 ) = O. 00/ mg/l
' (D.F.)(Volume)(3785) ( 76 ) ( 0.16 ) (3 78 5 )
Calculate concentration of biocide instream during low flow conditions.
' (Receiving Stream Concentration)
(Discha. Conc.) x (IWC0%6 _ (O.00�S) x ( 2.3 ) = a. 00A:::>3s mgA
' 100 100
Receiving Stream Concentration
' Ill. Calculate regulated limitation.
List all LC50 data available for the whole product according to the following columns. (Note that units should be
in mg/1). Please provide copies of the sources of this data.
' Organism Test Duration LC50 (ram)
�ADftKiQ l�CQ�thQ �O �!r > z& e
1 - -���� Nl,•,,kew 9 �� - > �o�oa
D.E.M. Form 101 (7/92) 2
DEQ-CFW 00064589
Facility Name: DuPont Company - Fayetteville Works NPDES #: NC 0003573
Choose the lowest LC50 listed above:
Enter the LC50: > ZDDD
•8 the half life (H.L.) is less than 4 days, perform the following calculation.
Regulated Limitation = 0.05 x LC50 1m9A
N the halt life (H.L.) is greater than 4 days or unknown, perform the following calculation.
Regulated Umitation = 0.01 x LC50 = i 2 mgA
Choose the appropriate regulated limitation from the calculations immediately above and place in this blank:
i ZG mg/liter
From Part II enter the receiving stream concentration:
O, 0000.3-5 mg/liter
IV. Analysis.
It the receiving stream concentration is greater than the calculated regulated Imitation, then this biocide is
unacceptable for use.
gie-44, e l z =---. l.Y'o A-t-
Person in Responsible Charge
Date
D.E.M. Form 101 (7/92)
3
DEQ-CFW 00064590
C
1
BETZ
4636 SOMERTON�RO D, TREVOSE, PA 19053
PRODUCT:
BALANCED POLYMER 54401
AQUATIC TOXICOLOGY August 19, 1994
Daphnia magna 48 Hour Static Screen
PH of test solutions were adjusted to a level of 6-9.
0$ Mortality: 2000 mg/L
Fathead Minnow 96 Hour Static Screen with 48-Hour Renewal
PH of.test solutions were adjusted to a level of 6-9.
0% Mortality: 2000 mQ/L
BIODEGRADATION
COD (mg/gm): 93 Calculated
TOC (mg/gm): 28 Calculated
BOD-5-(mg/gm): 0 Calculated
BOD-28 (mg/gm): 0 Calculated
Closed Bottle Test
$ Degradation in 28 days:
Zahn-Wellens Test
$ Degradation in 28 days:
MAMMALIAN TOXICOLOGY
Oral LD50 RAT: >5,000 MG/KG
Note - ESTIMATED VALUE
Dermal LD50 RABBIT: >5,000 MG/FCG
• Note - ESTIMATED VALUE
2 Calculated
0 Calculated
11
DEQ-CFW 00064591
Facility Name: DuPont Company - Fayetteville Works_ NPDES M NC 000-1523
BIOCIDE/CHEMICAL TREATMENT
WORKSHEET-FORM 101
The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of
North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet is to be
returned with all appropriate data entered irno the designated areas with calculations performed as indicated.
I. Facility Name DuPont Comvanv - Fayette illp Works
NPDES # NC, 0003573
County Baden
Receiving Stream Cave Fear River 7010 791 (cfs)
(All above information suppled by the Division of Environmental Management)
What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water body?
A.D.D. = 12.2 (in M.G.D.)
Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered
above.
IWC - (A.D.D.) X 100 _ (12.2 ) X 100 = 2.3 96
(7Q10)(0.646) - (791 )(0.646) + (A.D.D.)
This value (IWC) represents the waste concentration to the receiving stream during low flow conditions.
What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I?
96 711- OPT-1 - A1641Y
Please list the active ingredients and percent composition:
°/
°
What feed or dosage rate (D.R.) is used in this application? The units must be converted to grams of whole
product used rper day.
D.R.= 7 grams/day
D.E.M. Form 101 (7/92) 1
DEQ-CFW 00064592
• Facility Name: DuPont Company - Fayetteville Works NPDES #: NC 0003573
' Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge
point. On an attached sheet please provide justification for this estimate (system volume, average cycles per
' blowdown, holding lagoon size, etc.)
Volume= 0.16 million gallons
What is the pH of the handling system prior to biocide addition? If unknown, enter N/A. 6-9
What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.-0) and proceed to asterisk.
The degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the halt
' life (Hal Life is the time required for the initial product to degrade to halt of its original concentration). Please
provide copies of the sources of this data.
H.L. = Unknown Days
' The decay rate is equal to 1 HL. X 0.69 = 0 =Decay Rate (D.K.)
.
Calculate degradation factor (D.F.). This is the first order loss coefficient.
' D.F. = A( D.D.) + ) ( D.K. _ (12.2 ) + ( 0 ) = 76
(Volume) ( 0.16 )
Calculate Steady State Discharge Concentration:
' Dischg Conc. _ (D.F.)(Volume)(3785) _ ( 76 ) ( 0.16 ) (3 7 8 5 )
Calculate concentration of biocide instream during low flow conditions.
' (Receiving Stream Concentration)
Mischa. Conc.) x (IWC%) (0. ) x ( 2-1 ) = 0, Moo mg/I
' 100 100
Receiving Stream Concentration
' in. Calculate regulated limitation.
List all LC50 data available for the whole product according to the following columns. (Note that units should be
in mg/I). Please provide copies of the sources of this data.
' Orgarlism Test Duration LC50 (MGM
D.E.M. Form 101 (7/92) 2
DEQ-CFW 00064593
1 Facility Name: DuPont Company - Fayetteville Works NPDES M NC 0003573
1 ,
Choose the lowest LC50 listed above:
1 Enter the LC50: y�
•ff the half life (H.L.) is less than 4 days, perform the following calculation.
1 Regulated Limitation = 0.05 x LC50 MgA
ff the half ife (H.L.) is greater than 4 days or unknown, perform the following calculation.
1 Regulated Limitation = 0.01 x LC50 = > 0, 5 mgA
1 Choose the appropriate regulated imitation from the calculations immediately above and place in this blank:
> d• s —mg/liter
1
1 From Part ii enter the receiving stream concentration:
a OXW'_mg/liter
1
IV. Analysis.
1 If the receiving stream concentration is greater than the calculated regulated imitation, then this taWde is
unacceptable for use.
1
1 Date
Person in Responsible Charge
1
1 D.E.M. Form 101 (7/92) 3
DEQ-CFW 00064594
p
BETZ LABORATORIES, INC.
4636 SOMERTON ROAD, TREVOSE, PA 19053
PRODUCT: OPTI-MEEN SERIES PROPOSED
AQUATIC TOXICOLOGY
Daphnia magna 48 Hour Static Screen
0% Mortality: 50 mg/L
Rainbow Trout 48 Hour Static Screen
100$ Mortality: 500 mg/L
0% Mortality: 100
BIODEGRADATION
COD (Mg/gm): 733 Calculated
TOC (mg/gm): 287 Calculated
BOD-5 (mg/gm): 2 Calculated
BOD-28 (mg/gm): 187 Calculated
Closed Bottle Test
% Degradation in 28 days:
Zahn-Wellens Test
$ Degradation in 28 days:
MAMMALIAN TOXICOLOGY
Oral LD50 RAT: 675 MG/KG -
Note - ESTIMATED VALUE
Dermal LD50 RABBIT: 890 MG/KG
Note - ESTIMATED VALUE
August 19, 1994
37 Calculated
47 Calculated -
Eye•Irritation Score RABBIT: CORROSIVE
Note - 154 CYCLOHEXyLAMINE SCORE:
CONSTANT IRRITATION, NO 101. +/-RINSING,B
Skin Irritation Score RABBIT:•6.3 IBLE
Note - EPA CATEGORY I: CORROSIVE;
60 MINUTES BUT NOT 3 MINUTEST HM181 CORROSIVE IN
DEQ-CFW 00064595
Facility Name: DuPont Company - Fayetteville Works NPDES #: NC 0001573
BIOCIDE/CHEMICAL TREATMENT
WORKSHEET-FORM 101
The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of
North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet is to be
returned with all appropriate data entered into the designated areas with calculations performed as indicated.
I. Facility Name DuPont Company - Fayettevill - Workc
NPDES # NC 0003573 —
County Bladen
Receiving Stream Cayce Fear River 7010 791 (CfS)
(All above information suppled by the Division of Environmental Management)
What is the Average Daily Discharge (A.D.D.) volume of the water handing systems to the receiving water body?
A.D.D. - 12. 2 (in M.G.D.)
Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered
above.
IWC (A.D.D.) X 100 _ (12.2 ) X 100 = 2.3 %
(7Q10)(0.646) - (791 )(0.646) + (A.D.D.)
This value (IWC) represents the waste concentration to the receiving stream during low flow conditions.
Ii. What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I?
$,CTsZ CoAt i(A aorc Z%O
Please list the active ingredients and percent composition:
n o/
°
If
What feed or dosage rate (D.R.) is used in this application? The units must be converted to grams of whole
product used per day.
D.R.= 16-33 grams/day
D.E.M. Form 101 (7/92) 1
DEQ-CFW 00064596
•Facility Name:
DuPont Company - Fayetteville Works NPDES M NC 0003573
' Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge
point. On an attached sheet please provide justification for this estimate (system volume, average cycles per
' biowdown, holding lagoon size, etc.)
Volume- 0.16 million gallons
' What is the pH of the handling system prior to biocide addition? if unknown, enter WA. 6-9
1 What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.=O) and proceed to asterisk.
The degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the half
' life (Half Lffe is the time required for the initial product to degrade to half of its original concentration). Please
provide copies of the sources of this data.
' H.L. = Unknown Days
The decay rate is equal to 1 X 0.69 = 0 =Decay Rate (D.K.)
' H.L.
Calculate degradation factor (D.F.). This is the first order loss coefficient.
A( D.D.) _ (12.2 ) + 0 76
D.F. _ (Volume) + (D.K.) ( 0.16 ) ( ) _.
I
C�
1
I
E
Calculate Steady State Discharge Concentration:
Dischg Conc. _ 7 (D.R.) _ ( IG33 ) = O.03.5 mg/I
(D.F.)(Volume)(3785) ( 76 ) ( 0.16 ) (3 8 5) L
Calculate concentration of biocide instream during low flow conditions.
(Receiving Stream Concentration)
Mischa. Conc.) x (IWC%) = (O.d35 ) x ( 2.3 ) _ G QD08/ mg/I
100 100
Receiving Stream Concentration
Calculate regulated Imitation.
List all LC50 data available for the whole product according to the following columns. (Note that units should be
in mg/1). Please provide copies of the sources of this data.
,�/ / Orgarism Test Durdon
/yo a44 PX/373 1_e
Yftr'S Di�aa��ta'� . / �/iKtd iat d�i�utff�i�S
'W IV, 2?'e7
D.E.M. Form 101 (7/92) 2
DEQ-CFW 00064597
Facility Name: DuPont Company - Fayetteville Works NPDES #: NC 0003573
1 ,
Choose the lowest LC50 fisted above:
' Enter the LC50:_
-If the hall life (H.L.) is less than 4 days, perform the following calculation.
1 Regulated Limitation = 0.05 x LC50 mg/l
If the half life (H.L.) is greater than 4 days or unknown, perform the following calculation.
' Regulated Limitation = 0.01 x LC50 > MgA
1 Choose the appropriate regulated Imitation from the calculations immediately above and place in this blank:
0• D/ mg/fiter
1
' From Part II enter the receiving stream concentration:
d. "8 mg/liter
1
IV. Analysis.
' 0 the receiving stream concentration is greater than the calculated regulated Imitation, then this biocide is
unacceptable for use.
1
' Sigro" Date
Person in Responsible Charge
1
1
1
i
D.E.M. Form 101 (7/92) 3
1
DEQ-CFW 00064598
IBETZ LABORATORIES, INC.
4636 SOMERTON ROAD, TREVOSE, PA 19053
' PRODUCT: CONTINUUM 29000 SERIES PROPOSED
i
AQUATIC TOXICOLOGY
I NO DATA AVAILABLE
IBIODEGRADATION
COD (mg/gm): 212 Calculated
TOC (mg/gm): 81 Calculated
BOD-5 (mg/gm): 3 Calculated
BOD-28 (mg/gm): 13 Calculated
Closed Bottle Test
4 Degradation in 28 days: 0 Calculated
' Zahn-Wellens Test
$ Degradation in 28 days: 6 Calculated
tMAMMALIAN TOXICOLOGY
Oral LD50 RAT: 4,800 MG/KG
' ! Note - ESTIMATED VALUE
!; Dermal LD50 RABBIT: >5,000 MG/KG
Note - ESTIMATED VALUE
August 19, 1994
DEQ-CFW 00064599
NPDES PERMIT NO. NC0003573
ADDENDUM TO D.E.M. FORM 101
Estimation of total volume of the water handling system between entry of biocidal product
and NPDES discharge point:
Basis: Discharge from BCH Energy Project enters the DuPont non -contact wastewater
conveyance ditch and flows to Outfall 002.
Conveyance Ditch Volume = 5 ft x 2 ft x 2200 ft = 22,000 ft3 = 165,000 gallons
DEQ-CFW 00064600
' STANDARD FORM C - MANUFACTURING AND COMMERCIAL
SECTION ill. WASTE ABATEMENT REQUIREMENTS & IMPLEMENTATION (CONSTRUCTION) SCHEDULE
' This section requires information on any uncompleted implementation schedule which may have been imposed for construction of waste treatment facilities.
Such requirements and implementation schedules may have been established by local, State, or Federal agencies or by court action, In addition to feting
the following items, a copy of an official implementation schedule should be attached to this application. IF YOU ARE SUBJECT TO SEVERAL DIFFERENT
IMPLEMENTATION SCHEDULES, EITHER BECAUSE OF DIFFERENT LEVELS OF AUTHORITY IMPOSING DIFFERENT SCHEDULES (ITEM 1a)
AND/OR STAGED CONSTRUCTION OF SEPARATE OPERATIONAL UNITS (ITEM 1c), SUBMIT A SEPARATE SECTION Ill FOR EACH ONE.
FOR AUhNUY US
Sdhed. No,_
Improvements
a Discharge Serial Numbers 300 N/A
' Affected List the discharge
serial numbers, assigned in
Section II, that are covered by
this implementation schedule
' b. Authorittyy Imposing Require- 301a
ment Check the appropriate
item indicating the authority
for the implementation schedule
If the identical implementation
' schedule has been ordered by
more than one authority, check
the appropriate items. (see
instructions)
Locally developed plan 301b ❑ LOC
' Arsawide Plan ❑ ARE
Basin Plan ❑ BAS
State approved implementation ❑ SQS
' schedule
Federal approved water quality ❑ WQS
standards implementation plan
Federal enforcement procedure ❑ ENF
' or action
State court order ❑ CRT
Federal court order ❑ FED
c. Facility Requirement Specify
the 3-character code of those 3-character
listed below that best describes (general)
in general terms the require-
ment of the implementation 301c
' schedule and the applicable sb(-
character abatement oodes(s) .
from Table II of the instruction
booklet If more than one 301d 6-character
schedule applies to the facility specific)
because of a staged constructio see Table II)
' schedule, state the stage of con-
struction being described here
with the appropriate general
' action code. Submit a separate
Section III for each stage of
construction planned.
' New Facility NEW
Modification (no increase in capacity or treatment) MOD
Increase in Capacity INC
Increase in Treatment Level INT
' Both Increase in Treatment Level and Capacity ICT
Process Change PRO
Elimination of Discharge EU
1
DEQ-CFW 00064601
Implementation Schedule and 3. Actual Completion Dates
Provide dates imposed by schedule and any actual dates of completion for implementation steps listed below.
Indicate dates as accurately as possible. (see instructions)
Implementation Steps 2. Schedule
(yr/Mo/Day)
3. Actual Completion (Yr/Mo/Day)
a Preliminary plan complete
302a
_lam
303a
—1
b. Final plan submission
302b
303b
c. Final plan complete
302c
303c
d Financing complete & contract
302d
300d
_l_!
awarded
e. Site acquired
302e
_/_!
303e
f. Begin construction
302f
303f
g. End construction
302g
—1
303g
—lam
h. Begin discharge
302h
_(�
303h
—/-1
i. Operational level attained
302
/ I
303i
1 /
1
1
1
1
1
1
1
1
1
1
1
1
DEQ-CFW 00064602
N. C. DEPARTMENT OF NATURAL RESOURCES & COMMUNITY DEVELOPMENT
ENVIRONMENTAL MANAGEMENT COMMISSION
' NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM
APPLICATION FOR PERMIT TO DISCHARGE
ADDITIONAL REQUIRED INFORMATION
APPLICATION NUMBER
' DISCHARGE SERIAL NUMBER
C
r
L
E
REFER TO DIRECTIONS ON REVERSE SIDE BEFORE ATTEMPTING TO COMPLETE THIS FORM
Parameter
(Code)
(501)
UntreatedIn-Flan
Intake
Water
(Daily
average)
Treated
Intake
Water
(Daily
avers
of y
Average
Minimum
Value
maximum
Value
requency
of Analysis
Number
of
Analyses
SaMP16
Type
REMARKS:
I certify that I am familiar with the information contained in this report and that to go
hest of my knowledge and belief such information is true, complete and accurate.
a*,e r-ofm me of i are ot AuLhonzedn m a re
DEQ-CFW 00064603
0
0
C
1
I
11
r
I
Direct ons - For each parameter listed, complete the information
requested in each column in the units specified according to the instructions
given below.
Column 1- Enter the daily average value of the intake water at the
point it enters the facility. If intake water if from more than one source, and
enters the facility at separate entry points, the value given in column 1 should
be weighted proportional to the quantity of flow contributed from each source.
If water is treated before use, completion of this column is not required (see
instructions for column 2). Values of intake are not required for mining
activities.
Column 2 - If all or part of intake water is treated before use,
provide values for total intake here instead on in Column 1, Also describe
briefly in item 26'additional information,' the type of treatment performed on
intake water (e.g., rapid sand fiftration, coagulation, flocculation, ion
exchange, etc.) and the percent of intake water contributing to this discharge
that has been treated.
Column 3 - Supply daily average value for the days when
discharge is actually operating or is expected to be operating (a new
discharge). Daily average values are to be computed by weighing the daily
value in proportion to the daily flow. If a discharge occurs irregularly, the
value supplied in the column marked 'Daily Average' should represent an
average for the average for the days the discharge actually occurs. Average
values are not to be supplied for pH, specific conductance, and
bacteriological parameters (e.g., ooliforn bacteria).
Columns 4 and 5 - Supply minimum and maximum value
observed (or expected for new discharge) over any one day when the
discharge is operating.
Column 6 - Specify the average frequency of analysis for each
parameter as number analyses per number of days (e.g., '3(7' is equivalent
to three analyses performed every 7 days). If continuous, enter'C.ONT.'
When analyses are conducted on more than one individual grab sample
collected during the same day, the analysis frequency should reflect one
analysis whose value is the average of the individual grab sample
measurements. Average frequency should be based on an operating month.
Column 7-Specify the number of analyses performed at the
average frequency specified in column 6, up to 365.
Column a - Specify sam le type as follows:
G For grab sample (individual sample collected in less than 15
minutes).
uC • For composite sample # is to be replaced by the average
number of hours over which the composite sample was collected.
Composite samples are combinations of individual samples
obtained at intervals over a time period, either the volume of
each individual sample is directly proportional to discharge flow
rates or the sampling interval (for constant volume samples) is
inversely proportional to the flow rates over the time period
used to produce the composite.
NA If 'CONT' was entered in column 6.
Analytical methods - Appendix A contains all parameters with
their reporting levels, test descriptions, and references. The parameter
values can be determined either by use of the standard analytical methods as
described in table A or by methods previously approved by the EPA Regional
Administrator or Director of a federally approved State program (or their
authorized representative) who has jurisdiction over the State in which the
discharge occurs. If the test used is not one shown in table A, the test
procedure should be referenced in 'Remarks' or on a separate sheet. If
values are determined to be less than the detectable limits (as determined by
referenced standard analytical techniques and/or instrument manufacturers
literature), specify 'LT(Value of detectable limit)' in the appropriate space.
For example, if the detectable limit is .005 mg/I and quantities of less than
this are determined, specify 'LT.005.' Do not enter descriptors such as
'NIL,' 'TRACE,' 'NEG,' etc. for this purpose. If it is your reasoned
Judgment that one or more of the required parameters is not present in the
initial untreated or treated process water and/or the discharge, enter an 'A'
(meaning 'absent ') in the appropriate space.
In order for values reported to be representative, it is
recommended that they be based on from at least five to seven analyses of
composite samples(if applicable). Each of the composite samples should be
obtained by oompositing frequent samples in proportion to flow over an
operating day. Samples should be taken during period of maximum
production, if possible. If samples are taken at periods of less than
maximum production, state in 'Remarks" the percent of maximum
production that was obtained during the sampling period
DEQ-CFW 00064604
i i i i it it i i i i_ i'---i---•i i i i i i i
UNITED STATES DUART QUADRANGLE STATE OF NORTH CAROLINA
`sNORTH CAROLINA
ow DEPARTMENT OF NATURAL RESOUR
z
DEPARTMENT OF THE INTERIOR 7.5 MINUTE SERIES (TOPOGRAPHIC) AND COMMUNITY DEVELOPMENT
4`1a GEOLOGICAL SURVEY SFA SARff PAULS 15' QUADRANGIE N RALEIGH, N. C.
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5253 IV NE
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DEQ-CFW 00064606
1
1
1
1
1
1
1
1
1
1
1
1
1
1
AVERAGE BOYS IN THGISNUS OF GALLONS PER DAY.
SOME FLOWS ARE ESTIMATED TO GIVE INTAKE AND
DISMARGE TOTALS.
SCHEMATIC WATER FLOW
E.I. DU PONT DE NEMOURS & CO.
FAYETTEVILLE WORKS
PAGE 1 OF 2
STORM WATER
a
U
O
DEQ-CFW 00064607
1
1
1
1
1
' SCHEMATIC WATER FLOW
PROCESS USES
t E.I. DU PONT DE NEMOURS & CO.
FAYETTEVILLE WORKS
PAGE 2 OF 2
TO 810-TFEATMENT
�. N
97
1
DEQ-CFW 00064608
IDUPONT - FAYETTEVILLE WORKS
NCD0003573
Sludge Management Plan
The DuPont - Fayetteville Works operates a Class 3 Wastewater Treatment Plant which is
comprised of a single -stage activated sludge biological system.
Excess sludge is removed from the system by diverting part of the Recycled Activated Sludge
(at approximately 0.6% solids) from the clarifiers to a Dissolved Air Floatation (DAF) unit for
initial thickening.
The sludge from the DAF (at approximately 3% solids) is transferred to a Mix Tank where
polymer agents are added to enhance the dewatering process.
The semi -thickened sludge is transferred from the Mix Tank to a Rotary Filter for final
thickening, whereby the sludge is thickened to 6% solids.
The thickened sludge is then transferred to a Screw Press where it is dewatered to a
concentration of 9-20% solids.
Following the Screw Press, the sludge is dried in steam heated dryers to a concentration of
40-55% solids.
On the average, the weekly quantity of generated dried sludge is 13,000 lb.
The dried, non -hazardous sludge is transported off -site to a commercial Subtitle D landfill.
This sludge is currently being disposed of at the Sampson County Landfill near Roseboro, NC.
DEQ-CFW 00064609